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{{#Wiki_filter:FOGINERTINGCRITERIAFORHYOROGEN/ | {{#Wiki_filter:FOGINERTINGCRITERIAFORHYOROGEN/AIR MIXTURESS.S.Tsai,andN.J.LiparuloRiskAssessment Technology Westinghouse ElectricCorporation Presented atSecondInternational WorkshopontheImpactoff{ydrogen onWaterReactorSafetyAlbuquerque, NewMexicoOctober3-7,1982(83i0140046 831010lPDRADOCK05000315PPDR2693/:1 | ||
FOGINERTIHGCRITERIAFORHYDROGEN/ | FOGINERTIHGCRITERIAFORHYDROGEN/AIR MIXTURESS.S.Tsai,andN.J.LiparuloRiskAssessment Technology Mestinghouse ElectricCorporation ABSTRACTAdistributed ignitionsystemhasbeenproposedtoignitehydrogenatlowconcentration intheicecondenser containment duringsevereaccidents. | ||
Thepost-accident containment atmosphere couldbemistyduetofoggeneration fromthebreakflowandcondensation intheicebed.Thusitisimportant toestablish afoginertingcriterion foreffective performance o'ftheignitionsystem.Thispaperpresentssuchacriterion thatspecifies thenecessary foggingconditions, i.e.,fogconcentration anddropsize,forinertingahydrogen/air mixture.Thecriterion showsthattheminimumfoginertingconcentration varieswiththesquareofthevolumemeanfogdropsize.Thepresentfoginertingcriterion isshowntobeingeneralagreement withtheFactoryMutualtestdata.1.INTRODUCTION Adistributed ignitionsystemhasbeenproposedtoignitehydrogenatlowconcentration intheicecondenser containment duringsevereacci-dents.Thepost-accident containment atmosphere maybemistybecauseoffoggeneration bythebreakflowandcondensation intheicebed.Thusitisofimportant toestablish afoginertingcriterion foreffective performance oftheignitionsystem.ZaloshandBajpai(>) | |||
haverecentlyconducted hydrogenflamaability teststodetermine theeffectofwaterfoggingonthehydrogenlowerflammability limit.Inthetests,theminimumfoginertingconcentra-tionsforvariousvolumemeandropsizesandtpdrogenconcentrations weremeasured. | |||
Itwasfoundthatan8volpercenthydrogenmixturecouldbeinertedathighfogconcentration. | |||
Fogformation mayalsohavebeenresponsible forfailureofthetwoLawrenceLivermore tests(2)athighsteamconcentrations to'gnitetpdrogenduringthetestvesselcool-down period.Thecapability offogdropletsin.,inhibiting combustion orquenching flamesisduetotheirheatabsorbing capability | |||
-highheatofvapor-izationandsmalldropsizes(ontheorderof10p).Duetothesmalldropsizes,fogdropletscouldvaporizerapidly(ontheorderofmili-seconds)withinapropagating flamefront("Immthick).Ifasub-stantialamountofthesedropletsarepresent,theflamemaybequenched. | |||
Thecriticaldropletdiameterforquenching ahydrogenflamehasbeenestimated bySandiaNationalLaboratories(>). | |||
Itwasassumedthatthemeasured"quenching distance" forahydrogenflamepropagating througha2693/:I | |||
tubeorbetweenplatescouldbeusedforfogdroplets. | tubeorbetweenplatescouldbeusedforfogdroplets. | ||
Thismodeldoesnotconsiderheattransferandcombustion occurring betweentheburnedgasandthesuspended droplets. | |||
Thispaperpresentsafoginertingcriterion thatspecifies thenecessary foggingconditions, i.e.,fogconcentration anddropsize,forinertingahydrogen/air mixture.2.FOGINERTINGCRITERIARecenthydrogenburnexperiments(2) conducted atLawrenceLivermore Laboratory indicated thatsubstantial fogformation couldoccurwhensaturated steamisdischarged intoanunheatedvessel.Itappearedthatthisfogprevented aglowplugigniterfromsuccessfully ignitingthehydrogenmixtureinthevessel.Theabilityoffogininhibiting andquenching ahydrogencombustion canbeexplained asfollows.Thefogdropletssuspended inthehydrogen-air-steam mixtureactasaheatsinkthatcouldabsorbalargeamountofcombustion heatbyvaporization, greatlyreducingthepressureandtemperature risesresulting fromhydrogencombustion. | |||
Ifdropletsaresufficiently smallsuchthattheycouldvaporizeinsidethethin(1mm)flamefront,theflamemaybequenchedorinhibited. | |||
Foraflamespeedof2m/s,thedropresidence timeisoftheorderof0.5x1Q-3seconds.(3) | |||
Insuchashortperiodoftime,thedropletsofinitialradiuslessthanabout4pwillvaporizeentirelyintheflam'efront.Thequenching ofapropagating flameisalsogovernedbythedistancebetweendroplets. | |||
Asthedropletsbecomecloselypacked,thetota1dropletsurfaceareaavailable forenergylossincreases. | |||
Acriticalspacingbetweendropletsexistssuchthatalargefractionoftheheatreleasedisabsorbed, Thuspreventing | |||
.flamepropagation. | |||
Thiscriticalspacingisknownasthe"quenching distance", | |||
whichisusuallydetermined bypropagating flamesintubes.2.1PREVIOUSMORKTheeffectiveness offogdropletsininhibiting orquenching aflamedependsonitsquenching | |||
: distance, whichwasdetermined byBermanetal.(3)asq=L4V/Sjcrit whereVisthegasvolumeandSistheheattransfersurfacearea.Inthesuspended fogdroplets, thisvolume-to-surface ratio(i.e.,V/S)isequaltod(1-n)/6q, wheredisthemeandropletdiameterandqisthevolumefractionofthedroplets. | |||
Mhenfourtimesthisratioapproaches thequenching | |||
: distance, acriticaldropletdiametercanbeobtainedasndc=Y~q(2)2693':I Usingthequenching distancedataforagivenvolumefractionofwaterandgascomposition, thecriticaldropletdiametercanbedetermined fromEquation(2).Thedropsizeslessthanthecriticaldropsizearecapableofquenching aflame.2.2PRESENTTHEORYTheprevioustheoriesdonotmodeltheheattransferandcombustion processes occurring betweentheburned'gasandthesuspended droplets. | |||
Anewtheoryhasbeendeveloped, whichmodelstheheatlossandcombustion withinathinflamefront.1+.K!plwhereeiConsiderahydrogen/air/steam/mist dropletsmixtureinwhichaflameispropagating. | |||
Theflamemaybedividedintothreezones:heatingzone,reactionzone,andpost-reaction zoneasshowninFigure1.Theunburnedgasattemperature TumovesinthereactionzonewiththelaminarburningvelocitySu.Iftheunburnedgasdensityispu,thentheconstantmassflowratemisequaltopuSu.Theunburnedgasisheatedtoignitiontemperature Tiandburnedinthereactionzonetoreachtheflametemperature Tf.Thefogdropletswillactasaheatsinkthatreducestheflametemperature. | |||
Theproblemhasbeenformulated andsolvedbyvonKarmani4). | |||
Inhisformulation, threeenergyequations, whichincorporate theheatlossterms,werewrittenforthethreezonesdescribed above.Thesolutiontotheseequations yieldsthefollowing relationship 2KG.1-exp(-~p)(Y-Yf)x'ft(3)Ll+1+(4K/)]x1-uC(Ti-T)/qpiuKei(S/C')e.p1,theratioofheatlossrateperunitvolumeto'theheatreleaserateby'chemical reactionperunitvolumeheatofcombustion Cmeanspecificheatmeanheatconductivity reactionrate(massoffuelconsumedper:unittimeperunitvolume)II2693/:I | |||
hydrogenmassfractionintheheatingzone"f=hydrogenmassfractioninthereactionzone>uSuAplotofEq.(3)isshowninFigure2.Itisseenthatforagiven<oi,thereisaminimumvalueof(Yu-Yf1/ei.Belowthisminimumvalue,thereisnosolutionforthee;.Therefore, | hydrogenmassfractionintheheatingzone"f=hydrogenmassfractioninthereactionzone>uSuAplotofEq.(3)isshowninFigure2.Itisseenthatforagiven<oi,thereisaminimumvalueof(Yu-Yf1/ei.Belowthisminimumvalue,thereisnosolutionforthee;.Therefore, thisvalueisconsidered astheflamsability limit.Attheflamsability limit,thevalueofKelcanbedetermined fromFigure2orfromEq.3as(K)ite.=f((Yfei\sAplotof(K)criteiasafunctionof(Yu-Yf)/eiisshowninFigure3.Equation4maybeexpressed as2ufY-YqpuSu(Yu-Yf)fe;d-212i(TiTu)(4)(5)Detailedderivation procedure forEq.(5)isgiveninAppendixA.UsingthedataonSufromReference (5)wecancalculate therighthandsideofEq.(5)foragivencomposition andinitialgastemperature. | ||
3-VERIFICATION OFTHEORIESBYEXPERIMENTS Experiments havebeenconducted atfactoryMutualtostudytheeffectsofwaterfogdensity,dropletdiameter, andtemperature onthelowerflaranability limitofhydrogen-air-steam mixtures(2). | |||
Theresultsindicated thatmostofthefognozzlestestedat20Conlychangedthelimitfrom4.03volumepercentto4.76percent,corresponding tofogconcentration intherangeof0.028-0.085 volumepercent,andvolumemeandropsizerangingfrom45-90microns.Forthe50Ccase,thelowerflammability limitincreases to7.2percent,corresponding to0.01-0.04 volumepercentoffogand20-50micronvolumemeandropsizes.Theresultsdemonstrated thatthefoginertingeffectismorepronounced atreduceddropsizesandincreased temperature. | |||
Figures4through6showthecomparison betweenthetestdataandthetheoretical predictions. | |||
Forthiscomp'arison, thepresenttheoryusedthefreestreamtemperature tocalculate thethermodynamic properties usedinEquation(5).Thisyieldedsomewhathigherfogconcentrations thanthosecalculated byuseofthemeanoftheflameandfreestreamtemperatures. | |||
InFigures4and5,thedatasuggestsalinearrelation-shipbetweenthevolumeconcentration andvolumemeandropsizeonthelog-logplot.Italsosuggeststhattheminimumfoginertingconcentra-tionvariesapproximately withthesquareofthevolumemeandropsize.2693Q:I | |||
Thepresenttheoryisingoodagreement withtheFactoryMutualdataat4.76percentH2;however,itoverpredicts theminimumfoginertingconcentration at7.2percentH2.Thecauseofthisdiscrepancy isstillunknown.Thediscrepancy maybecausedbytheuncertainty ofthedata.Thefollowing discussion supportsthisview.Thefogdropletsareverysmallandtheyvaporizeveryfastinaflame.Therefore, thefogdropletsbehaveassteamexceptfortheirlargerheatabsorption capability. | |||
@henthefogdropletsvaporize, theyabsorbtheheatofvaporization whichismuchlargerthanthesteamsensibleheat.Typically, theheatofvaporization ofwaterisabout1000Btu/lbandtheaveragespecificheatofsteaminthetemperature rangeofinterestisabout0.48Btu/lb.Itiswellknownthatahydrogenflamecannotpropagate insteamhigherthanabout64percentinasteam-air mixture.At7.9percentH2,theadiabatic flametemperature isabout1240Fandtherefore theincreaseofthesteamsensibleheatisabout540Btu/lb.Consequently,.for thesameamountoffogdropletsandsteam,thefogdropletsheatabsorption capability isabout1.9timeshigher.Thismeansthatthefogconcentration whichisequivalent to22.1percentsteaminasteam-air mixtureiscapableofinerting7.9percentH2.Thisfoginertingvolumetric concentration wascalculated tobe1.61x10-4ft~H20/ft3mixfor7.9percentH2.Toinert7.2'ercent H2,aminimumfogconcentration of1.56x10-4ft3H20/ft3mix,equivalent toabout21.3percentsteaminasteam-air mixtureisrequired. | |||
Theseestimates showthatthepresentpredictions arereasonable andconservative. | |||
Theestimates areconsistent withFactoryMutualdataon7.9percentH2butnoton7.2percentH2-Itshouldbenotedthatintheteststhreefogconcentration measuring techniques wereused.Thesethreetechniques gavesubstantially dif-ferentresults.Thediscrepancy isatleastoneorderofmagnitude difference. | |||
Thefogconcentration datapresented inFigures4through6wereobtainedfromoneofthetechniques. | |||
Invie'woftheuncertainty ofthedata,caremustbeexercised inusingthemforfoginertinganalysispurposes. | |||
Theyshouldbeusedinconjunction withthepresentfoginertingcriterion intheassessment offoginertingpotential intheicecondenser plants.Someuncertainty alsoexistsinthepresentfoginertingtheory.Themaximumuncertairity associated withtheunder-prediction oftheheatlossandtemperature dependence ofthethermo-physicalproperties isestimated tobe+63percent.4.SUMMARYAkDCONCLUSIOkS Afoginertingcriterion hasbeendeveloped topredicttheminimumfogconcentration requiredtoinertagivenhydrogenconcentration andvolumemeanfogdropsize.Thepresentfoginertingcriterion hasbeenshowntobeingeneralagreement withtheFactoryMutualtestdata.Thecriterion showsthattheminimumfoginertingconcentration varieswiththesquareofthevolumemeanfogdropsize.2693':I | |||
ACKNOWLEDGMENTS Theauthorswishtoexpresstheirsinceregratitude toDrs.V.Srinivas, B.Lewis,andB.Karlovitz forassistance, suggestions, andhelpfuldiscussions, toMessrs.D.F.Paddleford, R.8ryan,F.G.Hudson,D.Renfro,andK.Shiuforvaluablecomments. | |||
TheyalsowouldliketothankTYA,DukePower,andAEPforproviding thefinancial support.REFERENCES 1.R.G.ZaloshandS.N.Bajpai,"MaterFogInertingofHydrogen-AirMixtures,i", | |||
EPRIProjectPreliminary Rpt.1932-1,September, 1981.2.B.Lowry,"Preliminary Results:AStudyofHydrogenIgniters, "ENN80-45, LawrenceLivermore NationalLaboratory, November17,1980.3.M.Berman,etal.,"Analysis off{ydrogen Mitigation forDegradedCoreAccidents intheSequoyahNuclearPowerPlant,"Sandiadraftreport,December1,1980.4.T.vonKarman,unpublished notes,1956.5.S.S.Tsai,andN.D.Liparulo, "FlameTemperature CriteriaTests,"acceptedforpresentation attheSecondInt.WorkshopontheImpactofHydrogenonMaterReactorSafety,Albuquerque, NewMexico,October3-7,1982.2693/:1 | |||
\> | \> | ||
APPEHDIXADERIYATIOH OFEQUATIOH(5)Thisappendixgivesdetailedprocedures toderiveEq.(5),startingfromEq.(4)<<)cr;t<;=f<<~u-~f)/oj)(4)wheretheratioofheat.lossrateperunitvolumetotheheatreleaseratebychemicalreactionperunitvolume,(K)crit,isdefinedasKcrit=S/Cpw(A-I)andtheratioofsensibleheattoheatofcombustion, ei,isdefinedase;=Cp(Ti-Tu)/q(A-2)ToarriveatEq.(5),itisnecessary toassumethatalltheheatlossisattributed toconvection heattransfertofogdropletsofonlyonedropsize.Underthisassumption, therateofheatlossperunitvolumeperdegree,S,maybee'xpressed asS=nxd2h(A-3)wheren=numberofdropsperunitvolumedvolumemeandropsizeh=heattransfercoefficient Itisfurtherassumedthattherelativevelocitybetweenthedropletsandthemixtureflowissosmallthatheattransfercoefficient, h,canbeapproximated bytheconduction limit.Infact,itcanbeshownthatforsmalldropsizes,convection andradiation areunimportant heattransfermechanisms atthedropsurface.Underthisassumption, Eq.(A-3)reducesto12'=~d(A-4)where7=meanheatconductivi tynvolumefractionofmistdroplets(-id)n362693Q:I Theofheatgeneration perunitvolume,w,isrelatedtothelaminarburingveloc>ty, Su,andthethickness ofthereactionzone,x,byS(Y-Yf)w=Thethickness ofthereactionzonemaybeapproximated bypSZ'A-6) | |||
Combining Eqs.(A-l),(A-4),(A-5),and(A-6),wehave12',SZ(Yu-Yf)Substituting Eqs.(A-2)and(A-7)intoEq.(4),wehaveYu-Yfd127(T.-T)(Y-Y)f(u)1u1(5)Q.E.D.2693Q:1,B 4 | |||
FIGUREjSCHEMATIC REPRESENTATION OFTEMPERATURE PROFILETHROUGHTHEFLAMEFRONT0'd,a%5gsO3002.<~v~rV+iFIGURE2THEPARAMETER A.pASAFUNCTIONOF(Y-Y~)/e.FORDIFFERENT VALUESOFK9. | |||
0.30.20.i3(Yu-Yfj/0/FIGURE3(K)8. | 0.30.20.i3(Yu-Yfj/0/FIGURE3(K)8.ATTHEFLAMMABILITY LIMITASAFUNCTIONOF(Y-Yf)/8.cr)tiufi 2147310.175x2PlI-10-2P4I-5z0I-LL2IzO0103CJU0tL50SPRACO2163SPRACO1405-0604 QSPRAGO2020-1704 0SPRACO1806-1605 NON-FLAMMABLE ZONEBERMANETAL.THEORYPRESENTTHEORYFLAMMABLE ZONE10410100200VOLUMEMEANDIAMETER(MICRONS) | ||
2147.1NON- | Figure4.Comparison betweenTheoriesandFactoryMutuaiFoginertingExperiments on4.76PercentH2 2147.$0SPRACO2163-7604 DSPRACO2020-1704 QSONICORE035HX0C4FlI-ROI-lEI-RLuORO2C9OVNON-FLAMMABLE'ONEPRESENTTHEORYFLAMMABLE ZONE7.2%H2INAIRAT-50C102030405060708090100VOLUMEMEANDIAMETER(MICRONS) | ||
Figure5.Comparison betweenthePresentTheoryandFactoryMutualFoglnertingExperiments on7.2PercentH2 V | |||
2147.1NON-FLAMMABLE ZONEx5X1030xR10-3I-I-zRo5X10.40OU0PRESENTTHEORYFLAMMABLE ZONE6FACTORYMUTUALDATAON7.9%H2INAIR10450100VOLUMEMEANDIAMETER(MICRONS) 1000Figure6.Comparison betweenthePresentTheoryandFactoryMutualFogtnertingExperiments on7.9PercentH213 | |||
,~}} | ,~}} |
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FOGINERTINGCRITERIAFORHYOROGEN/AIR MIXTURESS.S.Tsai,andN.J.LiparuloRiskAssessment Technology Westinghouse ElectricCorporation Presented atSecondInternational WorkshopontheImpactoff{ydrogen onWaterReactorSafetyAlbuquerque, NewMexicoOctober3-7,1982(83i0140046 831010lPDRADOCK05000315PPDR2693/:1
FOGINERTIHGCRITERIAFORHYDROGEN/AIR MIXTURESS.S.Tsai,andN.J.LiparuloRiskAssessment Technology Mestinghouse ElectricCorporation ABSTRACTAdistributed ignitionsystemhasbeenproposedtoignitehydrogenatlowconcentration intheicecondenser containment duringsevereaccidents.
Thepost-accident containment atmosphere couldbemistyduetofoggeneration fromthebreakflowandcondensation intheicebed.Thusitisimportant toestablish afoginertingcriterion foreffective performance o'ftheignitionsystem.Thispaperpresentssuchacriterion thatspecifies thenecessary foggingconditions, i.e.,fogconcentration anddropsize,forinertingahydrogen/air mixture.Thecriterion showsthattheminimumfoginertingconcentration varieswiththesquareofthevolumemeanfogdropsize.Thepresentfoginertingcriterion isshowntobeingeneralagreement withtheFactoryMutualtestdata.1.INTRODUCTION Adistributed ignitionsystemhasbeenproposedtoignitehydrogenatlowconcentration intheicecondenser containment duringsevereacci-dents.Thepost-accident containment atmosphere maybemistybecauseoffoggeneration bythebreakflowandcondensation intheicebed.Thusitisofimportant toestablish afoginertingcriterion foreffective performance oftheignitionsystem.ZaloshandBajpai(>)
haverecentlyconducted hydrogenflamaability teststodetermine theeffectofwaterfoggingonthehydrogenlowerflammability limit.Inthetests,theminimumfoginertingconcentra-tionsforvariousvolumemeandropsizesandtpdrogenconcentrations weremeasured.
Itwasfoundthatan8volpercenthydrogenmixturecouldbeinertedathighfogconcentration.
Fogformation mayalsohavebeenresponsible forfailureofthetwoLawrenceLivermore tests(2)athighsteamconcentrations to'gnitetpdrogenduringthetestvesselcool-down period.Thecapability offogdropletsin.,inhibiting combustion orquenching flamesisduetotheirheatabsorbing capability
-highheatofvapor-izationandsmalldropsizes(ontheorderof10p).Duetothesmalldropsizes,fogdropletscouldvaporizerapidly(ontheorderofmili-seconds)withinapropagating flamefront("Immthick).Ifasub-stantialamountofthesedropletsarepresent,theflamemaybequenched.
Thecriticaldropletdiameterforquenching ahydrogenflamehasbeenestimated bySandiaNationalLaboratories(>).
Itwasassumedthatthemeasured"quenching distance" forahydrogenflamepropagating througha2693/:I
tubeorbetweenplatescouldbeusedforfogdroplets.
Thismodeldoesnotconsiderheattransferandcombustion occurring betweentheburnedgasandthesuspended droplets.
Thispaperpresentsafoginertingcriterion thatspecifies thenecessary foggingconditions, i.e.,fogconcentration anddropsize,forinertingahydrogen/air mixture.2.FOGINERTINGCRITERIARecenthydrogenburnexperiments(2) conducted atLawrenceLivermore Laboratory indicated thatsubstantial fogformation couldoccurwhensaturated steamisdischarged intoanunheatedvessel.Itappearedthatthisfogprevented aglowplugigniterfromsuccessfully ignitingthehydrogenmixtureinthevessel.Theabilityoffogininhibiting andquenching ahydrogencombustion canbeexplained asfollows.Thefogdropletssuspended inthehydrogen-air-steam mixtureactasaheatsinkthatcouldabsorbalargeamountofcombustion heatbyvaporization, greatlyreducingthepressureandtemperature risesresulting fromhydrogencombustion.
Ifdropletsaresufficiently smallsuchthattheycouldvaporizeinsidethethin(1mm)flamefront,theflamemaybequenchedorinhibited.
Foraflamespeedof2m/s,thedropresidence timeisoftheorderof0.5x1Q-3seconds.(3)
Insuchashortperiodoftime,thedropletsofinitialradiuslessthanabout4pwillvaporizeentirelyintheflam'efront.Thequenching ofapropagating flameisalsogovernedbythedistancebetweendroplets.
Asthedropletsbecomecloselypacked,thetota1dropletsurfaceareaavailable forenergylossincreases.
Acriticalspacingbetweendropletsexistssuchthatalargefractionoftheheatreleasedisabsorbed, Thuspreventing
.flamepropagation.
Thiscriticalspacingisknownasthe"quenching distance",
whichisusuallydetermined bypropagating flamesintubes.2.1PREVIOUSMORKTheeffectiveness offogdropletsininhibiting orquenching aflamedependsonitsquenching
- distance, whichwasdetermined byBermanetal.(3)asq=L4V/Sjcrit whereVisthegasvolumeandSistheheattransfersurfacearea.Inthesuspended fogdroplets, thisvolume-to-surface ratio(i.e.,V/S)isequaltod(1-n)/6q, wheredisthemeandropletdiameterandqisthevolumefractionofthedroplets.
Mhenfourtimesthisratioapproaches thequenching
- distance, acriticaldropletdiametercanbeobtainedasndc=Y~q(2)2693':I Usingthequenching distancedataforagivenvolumefractionofwaterandgascomposition, thecriticaldropletdiametercanbedetermined fromEquation(2).Thedropsizeslessthanthecriticaldropsizearecapableofquenching aflame.2.2PRESENTTHEORYTheprevioustheoriesdonotmodeltheheattransferandcombustion processes occurring betweentheburned'gasandthesuspended droplets.
Anewtheoryhasbeendeveloped, whichmodelstheheatlossandcombustion withinathinflamefront.1+.K!plwhereeiConsiderahydrogen/air/steam/mist dropletsmixtureinwhichaflameispropagating.
Theflamemaybedividedintothreezones:heatingzone,reactionzone,andpost-reaction zoneasshowninFigure1.Theunburnedgasattemperature TumovesinthereactionzonewiththelaminarburningvelocitySu.Iftheunburnedgasdensityispu,thentheconstantmassflowratemisequaltopuSu.Theunburnedgasisheatedtoignitiontemperature Tiandburnedinthereactionzonetoreachtheflametemperature Tf.Thefogdropletswillactasaheatsinkthatreducestheflametemperature.
Theproblemhasbeenformulated andsolvedbyvonKarmani4).
Inhisformulation, threeenergyequations, whichincorporate theheatlossterms,werewrittenforthethreezonesdescribed above.Thesolutiontotheseequations yieldsthefollowing relationship 2KG.1-exp(-~p)(Y-Yf)x'ft(3)Ll+1+(4K/)]x1-uC(Ti-T)/qpiuKei(S/C')e.p1,theratioofheatlossrateperunitvolumeto'theheatreleaserateby'chemical reactionperunitvolumeheatofcombustion Cmeanspecificheatmeanheatconductivity reactionrate(massoffuelconsumedper:unittimeperunitvolume)II2693/:I
hydrogenmassfractionintheheatingzone"f=hydrogenmassfractioninthereactionzone>uSuAplotofEq.(3)isshowninFigure2.Itisseenthatforagiven<oi,thereisaminimumvalueof(Yu-Yf1/ei.Belowthisminimumvalue,thereisnosolutionforthee;.Therefore, thisvalueisconsidered astheflamsability limit.Attheflamsability limit,thevalueofKelcanbedetermined fromFigure2orfromEq.3as(K)ite.=f((Yfei\sAplotof(K)criteiasafunctionof(Yu-Yf)/eiisshowninFigure3.Equation4maybeexpressed as2ufY-YqpuSu(Yu-Yf)fe;d-212i(TiTu)(4)(5)Detailedderivation procedure forEq.(5)isgiveninAppendixA.UsingthedataonSufromReference (5)wecancalculate therighthandsideofEq.(5)foragivencomposition andinitialgastemperature.
3-VERIFICATION OFTHEORIESBYEXPERIMENTS Experiments havebeenconducted atfactoryMutualtostudytheeffectsofwaterfogdensity,dropletdiameter, andtemperature onthelowerflaranability limitofhydrogen-air-steam mixtures(2).
Theresultsindicated thatmostofthefognozzlestestedat20Conlychangedthelimitfrom4.03volumepercentto4.76percent,corresponding tofogconcentration intherangeof0.028-0.085 volumepercent,andvolumemeandropsizerangingfrom45-90microns.Forthe50Ccase,thelowerflammability limitincreases to7.2percent,corresponding to0.01-0.04 volumepercentoffogand20-50micronvolumemeandropsizes.Theresultsdemonstrated thatthefoginertingeffectismorepronounced atreduceddropsizesandincreased temperature.
Figures4through6showthecomparison betweenthetestdataandthetheoretical predictions.
Forthiscomp'arison, thepresenttheoryusedthefreestreamtemperature tocalculate thethermodynamic properties usedinEquation(5).Thisyieldedsomewhathigherfogconcentrations thanthosecalculated byuseofthemeanoftheflameandfreestreamtemperatures.
InFigures4and5,thedatasuggestsalinearrelation-shipbetweenthevolumeconcentration andvolumemeandropsizeonthelog-logplot.Italsosuggeststhattheminimumfoginertingconcentra-tionvariesapproximately withthesquareofthevolumemeandropsize.2693Q:I
Thepresenttheoryisingoodagreement withtheFactoryMutualdataat4.76percentH2;however,itoverpredicts theminimumfoginertingconcentration at7.2percentH2.Thecauseofthisdiscrepancy isstillunknown.Thediscrepancy maybecausedbytheuncertainty ofthedata.Thefollowing discussion supportsthisview.Thefogdropletsareverysmallandtheyvaporizeveryfastinaflame.Therefore, thefogdropletsbehaveassteamexceptfortheirlargerheatabsorption capability.
@henthefogdropletsvaporize, theyabsorbtheheatofvaporization whichismuchlargerthanthesteamsensibleheat.Typically, theheatofvaporization ofwaterisabout1000Btu/lbandtheaveragespecificheatofsteaminthetemperature rangeofinterestisabout0.48Btu/lb.Itiswellknownthatahydrogenflamecannotpropagate insteamhigherthanabout64percentinasteam-air mixture.At7.9percentH2,theadiabatic flametemperature isabout1240Fandtherefore theincreaseofthesteamsensibleheatisabout540Btu/lb.Consequently,.for thesameamountoffogdropletsandsteam,thefogdropletsheatabsorption capability isabout1.9timeshigher.Thismeansthatthefogconcentration whichisequivalent to22.1percentsteaminasteam-air mixtureiscapableofinerting7.9percentH2.Thisfoginertingvolumetric concentration wascalculated tobe1.61x10-4ft~H20/ft3mixfor7.9percentH2.Toinert7.2'ercent H2,aminimumfogconcentration of1.56x10-4ft3H20/ft3mix,equivalent toabout21.3percentsteaminasteam-air mixtureisrequired.
Theseestimates showthatthepresentpredictions arereasonable andconservative.
Theestimates areconsistent withFactoryMutualdataon7.9percentH2butnoton7.2percentH2-Itshouldbenotedthatintheteststhreefogconcentration measuring techniques wereused.Thesethreetechniques gavesubstantially dif-ferentresults.Thediscrepancy isatleastoneorderofmagnitude difference.
Thefogconcentration datapresented inFigures4through6wereobtainedfromoneofthetechniques.
Invie'woftheuncertainty ofthedata,caremustbeexercised inusingthemforfoginertinganalysispurposes.
Theyshouldbeusedinconjunction withthepresentfoginertingcriterion intheassessment offoginertingpotential intheicecondenser plants.Someuncertainty alsoexistsinthepresentfoginertingtheory.Themaximumuncertairity associated withtheunder-prediction oftheheatlossandtemperature dependence ofthethermo-physicalproperties isestimated tobe+63percent.4.SUMMARYAkDCONCLUSIOkS Afoginertingcriterion hasbeendeveloped topredicttheminimumfogconcentration requiredtoinertagivenhydrogenconcentration andvolumemeanfogdropsize.Thepresentfoginertingcriterion hasbeenshowntobeingeneralagreement withtheFactoryMutualtestdata.Thecriterion showsthattheminimumfoginertingconcentration varieswiththesquareofthevolumemeanfogdropsize.2693':I
ACKNOWLEDGMENTS Theauthorswishtoexpresstheirsinceregratitude toDrs.V.Srinivas, B.Lewis,andB.Karlovitz forassistance, suggestions, andhelpfuldiscussions, toMessrs.D.F.Paddleford, R.8ryan,F.G.Hudson,D.Renfro,andK.Shiuforvaluablecomments.
TheyalsowouldliketothankTYA,DukePower,andAEPforproviding thefinancial support.REFERENCES 1.R.G.ZaloshandS.N.Bajpai,"MaterFogInertingofHydrogen-AirMixtures,i",
EPRIProjectPreliminary Rpt.1932-1,September, 1981.2.B.Lowry,"Preliminary Results:AStudyofHydrogenIgniters, "ENN80-45, LawrenceLivermore NationalLaboratory, November17,1980.3.M.Berman,etal.,"Analysis off{ydrogen Mitigation forDegradedCoreAccidents intheSequoyahNuclearPowerPlant,"Sandiadraftreport,December1,1980.4.T.vonKarman,unpublished notes,1956.5.S.S.Tsai,andN.D.Liparulo, "FlameTemperature CriteriaTests,"acceptedforpresentation attheSecondInt.WorkshopontheImpactofHydrogenonMaterReactorSafety,Albuquerque, NewMexico,October3-7,1982.2693/:1
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APPEHDIXADERIYATIOH OFEQUATIOH(5)Thisappendixgivesdetailedprocedures toderiveEq.(5),startingfromEq.(4)<<)cr;t<;=f<<~u-~f)/oj)(4)wheretheratioofheat.lossrateperunitvolumetotheheatreleaseratebychemicalreactionperunitvolume,(K)crit,isdefinedasKcrit=S/Cpw(A-I)andtheratioofsensibleheattoheatofcombustion, ei,isdefinedase;=Cp(Ti-Tu)/q(A-2)ToarriveatEq.(5),itisnecessary toassumethatalltheheatlossisattributed toconvection heattransfertofogdropletsofonlyonedropsize.Underthisassumption, therateofheatlossperunitvolumeperdegree,S,maybee'xpressed asS=nxd2h(A-3)wheren=numberofdropsperunitvolumedvolumemeandropsizeh=heattransfercoefficient Itisfurtherassumedthattherelativevelocitybetweenthedropletsandthemixtureflowissosmallthatheattransfercoefficient, h,canbeapproximated bytheconduction limit.Infact,itcanbeshownthatforsmalldropsizes,convection andradiation areunimportant heattransfermechanisms atthedropsurface.Underthisassumption, Eq.(A-3)reducesto12'=~d(A-4)where7=meanheatconductivi tynvolumefractionofmistdroplets(-id)n362693Q:I Theofheatgeneration perunitvolume,w,isrelatedtothelaminarburingveloc>ty, Su,andthethickness ofthereactionzone,x,byS(Y-Yf)w=Thethickness ofthereactionzonemaybeapproximated bypSZ'A-6)
Combining Eqs.(A-l),(A-4),(A-5),and(A-6),wehave12',SZ(Yu-Yf)Substituting Eqs.(A-2)and(A-7)intoEq.(4),wehaveYu-Yfd127(T.-T)(Y-Y)f(u)1u1(5)Q.E.D.2693Q:1,B 4
FIGUREjSCHEMATIC REPRESENTATION OFTEMPERATURE PROFILETHROUGHTHEFLAMEFRONT0'd,a%5gsO3002.<~v~rV+iFIGURE2THEPARAMETER A.pASAFUNCTIONOF(Y-Y~)/e.FORDIFFERENT VALUESOFK9.
0.30.20.i3(Yu-Yfj/0/FIGURE3(K)8.ATTHEFLAMMABILITY LIMITASAFUNCTIONOF(Y-Yf)/8.cr)tiufi 2147310.175x2PlI-10-2P4I-5z0I-LL2IzO0103CJU0tL50SPRACO2163SPRACO1405-0604 QSPRAGO2020-1704 0SPRACO1806-1605 NON-FLAMMABLE ZONEBERMANETAL.THEORYPRESENTTHEORYFLAMMABLE ZONE10410100200VOLUMEMEANDIAMETER(MICRONS)
Figure4.Comparison betweenTheoriesandFactoryMutuaiFoginertingExperiments on4.76PercentH2 2147.$0SPRACO2163-7604 DSPRACO2020-1704 QSONICORE035HX0C4FlI-ROI-lEI-RLuORO2C9OVNON-FLAMMABLE'ONEPRESENTTHEORYFLAMMABLE ZONE7.2%H2INAIRAT-50C102030405060708090100VOLUMEMEANDIAMETER(MICRONS)
Figure5.Comparison betweenthePresentTheoryandFactoryMutualFoglnertingExperiments on7.2PercentH2 V
2147.1NON-FLAMMABLE ZONEx5X1030xR10-3I-I-zRo5X10.40OU0PRESENTTHEORYFLAMMABLE ZONE6FACTORYMUTUALDATAON7.9%H2INAIR10450100VOLUMEMEANDIAMETER(MICRONS) 1000Figure6.Comparison betweenthePresentTheoryandFactoryMutualFogtnertingExperiments on7.9PercentH213
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