ML20352A247
| ML20352A247 | |
| Person / Time | |
|---|---|
| Site: | La Crosse File:Dairyland Power Cooperative icon.png |
| Issue date: | 11/02/2020 |
| From: | La CrosseSolutions |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML20356A041 | List:
|
| References | |
| LC-2020-0023 | |
| Download: ML20352A247 (115) | |
Text
LA CROSSE BOILING WATER REACTOR FINAL STATUS SURVEY RELEASE RECORD STORM DRAIN 2 SURVEY UNIT S3-012-109 B REVISION 1
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 1
PREPARED BY / DATE:
R. F. Yetter III, FSS Specialist REVIEWED BY / DATE:
M. D. Uz, FSS Specialist REVIEWED BY / DATE:
R. Yetter, Director, Radiological Site Closure REVIEWED BY / DATE:
S. Roberts, VP Radiological Programs APPROVED BY / DATE:
S. Zoller, FSS Manager
~~
9wl,.e,ttg..'lj.etwt,
~
LACROSSESOLUTIONS Robert F. Yetter III Oct 25 2020 1 :58 PM Mitchell Uz Oct 27 2020 8:04 AM Robert F. Yetter Oct 27 2020 11:10 AM Sarah Roberts Oct 27 2020 I :00 PM Scott G. Zoller Oct 29 2020 9:42 AM cosign cosign cosign
~~/tf
,.::1-c.dft.p,,, ~p..,___
c:.._ __.,..
1/
cosign
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 2
TABLE OF CONTENTS
- 1.
EXECUTIVE
SUMMARY
................................................................................................................................. 5
- 2.
SURVEY UNIT DESCRIPTION....................................................................................................................... 5
- 3.
CLASSIFICATION BASIS................................................................................................................................. 5
- 4.
DATA QUALITY OBJECTIVES...................................................................................................................... 6
- 5.
SURVEY DESIGN............................................................................................................................................... 9
- 6.
SURVEY IMPLEMENTATION...................................................................................................................... 13
- 7.
SURVEY RESULTS.......................................................................................................................................... 14
- 8.
QUALITY CONTROL...................................................................................................................................... 16
- 9.
INVESTIGATIONS AND RESULTS.............................................................................................................. 16
- 10. REMEDIATION AND RESULTS................................................................................................................... 16
- 11. CHANGES FROM THE FINAL STATUS SURVEY PLAN........................................................................ 16
- 12. DATA QUALITY ASSESSMENT................................................................................................................... 17
- 13. ANOMALIES..................................................................................................................................................... 17
- 14. CONCLUSION.................................................................................................................................................. 17
- 15. REFERENCES................................................................................................................................................... 17
- 16. ATTACHMENTS.............................................................................................................................................. 18 ATTACHMENT 1 FIGURES AND MAPS............................................................................................................. 19 ATTACHMENT 2 MEASUREMENT DATA.......................................................................................................... 21 ATTACHMENT 3 SIGN TEST............................................................................................................................... 25 ATTACHMENT 4 QUALITY CONTROL ASSESSMENT...................................................................................... 28 ATTACHMENT 5 GRAPHICAL PRESENTATIONS............................................................................................. 30 ATTACHMENT 6 SAMPLE ANALYTICAL REPORTS......................................................................................... 34 ATTACHMENT 7 GEL LABORATORIES REPORTS........................................................................................... 54
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 3
LIST OF TABLES Table 4 Dose Significant Radionuclides and Mixture for Buried Pipe............................................................... 7 Table 4 Base Case DCGLs for Buried Pipe Group.............................................................................................. 8 Table 4 Operational DCGLs for Buried Pipe Group........................................................................................... 9 Table 5-1 Soil/Buried Pipe Surrogate Ratio............................................................................................................ 9 Table 5-2 Investigation Levels................................................................................................................................ 12 Table 5-3 Synopsis of Survey Design...................................................................................................................... 12 Table 7 Summary of Systematic, Judgmental, and QC Measurements........................................................... 15 Table 7 Basic Statistical Properties of the Systematic Measurement Population............................................ 15 Table 16-1 Survey Unit S3-012-109 B Static Measurements Data Assessment.................................................. 22 Table 16-2 Survey Unit S3-012-109 B Sign Test................................................................................................... 26 Table 16-3 Survey Unit S3-012-109 B QC Assessment......................................................................................... 29 LIST OF FIGURES Figure 16-1 Survey Unit S3-012-109 B Drawing................................................................................................... 20 Figure 16 Quantile Plot for Gross Gamma Activity.......................................................................................... 31 Figure 16 Histogram for Gross Gamma Activity............................................................................................... 32 Figure 16 Retrospective Power Curve for Survey Unit S3-012-109 B.............................................................. 33
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 4
LIST OF ACRONYMS AND ABBREVIATIONS ALARA As Low As Reasonably Achievable CWD Circulating Water Discharge DQO Data Quality Objective DCGL Derived Concentration Guideline Level DCGLBP Buried Pipe Base Case Derived Concentration Guideline Level FSS Final Status Survey HSA Historical Site Assessment IC Insignificant Contributors ID Internal Diameter LACBWR La Crosse Boiling Water Reactor LTP License Termination Plan LPSW Low Pressure Service Water MARSSIM Multi-Agency Radiation Survey and Site Investigation Manual MCNP Monte Carlo Neutral Particle MDC Minimum Detectable Concentration NaI Sodium Iodide OpDCGLBP Buried Pipe Operational Derived Concentration Guideline Level QAPP Quality Assurance Project Plan QC Quality Control ROC Radionuclides of Concern SD2 Storm Drain 2 SOF Sum of Fractions TEDE Total Effective Dose Equivalent TSD Technical Support Document UCL Upper Confidence Limit
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 5
- 1.
EXECUTIVE
SUMMARY
This Final Status Survey (FSS) Release Record for survey unit S3-012-109 B, Storm Drain 2 (SD2), has been generated in accordance with LaCrosseSolutions procedure LC-FS-PR-009, Final Status Survey Data Reporting (Reference 1) and satisfies the requirements of Section 5.11 of the La Crosse Boiling Water Reactor License Termination Plan (LACBWR LTP) (Reference 2).
An FSS sample plan for this survey unit was developed in accordance with LaCrosseSolutions procedures LC-FS-PR-002, Final Status Survey Package Development (Reference 3) and LC-FS-PR-018, Radiation Surveys of Pipe Interiors Using Sodium/Cesium Iodide Detectors (Reference 4) the LACBWR LTP, and with guidance from NUREG-1575, Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM)
(Reference 5).
Survey unit S3-012-109 B has a MARSSIM classification of 3. A survey plan was designed based upon use of the Sign Test as the nonparametric statistical test for compliance. Both the Type I ( ) and Type II ( ) decision error rates were set at 0.05. As a systematic measurement population, sixty (60) static gamma measurements were acquired from the survey unit. The data assessment results for survey unit S3-012-109 B indicate that the maximum Sum of Fractions (SOF), considering the concentration of all applicable Radionuclides of Concern (ROC) either by direct measurement or by inference, is equal to 0.1254 when applying the respective Operational Derived Concentration Guideline Levels (OpDCGLBP) for buried pipe. The mean SOF when applying the respective Base Case DCGLs (DCGLBP) is 0.0213. This SOF equates to a dose for the survey unit of 0.5317 mrem/yr.
- 2.
SURVEY UNIT DESCRIPTION S3-012-109 B is an impacted Class 3 buried pipe survey unit. The survey unit consists of the interior surface of the SD2 pipe, which is 48 Internal Diameter (ID) concrete pipe that runs approximately 624. The interior surface area of the SD2 Pipe is 728.51 m2 (7,285,097.01 cm2). Refer to Attachment 1 of this report for figures and maps depicting survey unit S3-012-109 B.
- 3.
CLASSIFICATION BASIS Based on the La Crosse Boiling Water Reactor Historical Site Assessment (HSA)
(Reference 6), the SD2 pipe was identified as a Class 3 system.
~
LACROSSESOLUTIONS a
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 6
Based upon review of the historical information and completion of a final Survey Unit Classification Worksheet from LC-FS-PR-006, Survey Unit Classification (Reference 7),
the correct final classification of survey unit S3-012-109 B was determined to be Class 3.
- 4.
DATA QUALITY OBJECTIVES FSS planning and design relies on a properly executed Data Quality Objective (DQO) process to ensure, through compliance with explicitly defined inputs and boundaries, that the primary objective of the survey is satisfied. The DQO process is described in the LACBWR LTP in accordance with MARSSIM. The appropriate design for a given survey was developed using the DQO process as outlined in Appendix D of MARSSIM.
The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would indicate that residual activity within the survey unit does not exceed the release criteria. Therefore, the survey unit would satisfy the primary objective of the FSS sample plan.
The primary objective of the FSS sample plan is to demonstrate that the level of residual radioactivity in survey unit S3-012-109 B did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).
EnergySolutions Technical Support Document (TSD) RS-TD-313196-001, Radionuclides of Concern during LACBWR Decommissioning (Reference 8) established the basis for an initial suite of potential ROC for decommissioning. Insignificant contributors (IC) were determined consistent with the guidance contained in Section 3.3 of NUREG-1757, Volume 2, Revision 1, Consolidated Decommissioning Guidance Characterization, Survey, and Determination of Radiological Criteria, Final Report (Reference 9). In all soil and concrete scenarios, Cs-137, Co-60, Sr-90, Eu-152 and Eu-154 contribute nearly 100% of the total dose. The remaining radionuclides were designated as IC and are eliminated from further detailed evaluation. Therefore, the final ROCs for LACBWR soil, basement concrete, and buried piping are Cs-137, Co-60, Sr-90, Eu-152 and Eu-154.
LTP, Section 6.14.1 discusses the process used to derive the ROC for the decommissioning of LACBWR, including the elimination of IC from the initial suite. Table 4-1 presents the
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 7
ROC for the decommissioning of buried pipe at LACBWR and the normalized mixture fractions based on the radionuclide mixture.
Table 4 Dose Significant Radionuclides and Mixture for Buried Pipe Radionuclide Fraction of Total Activity (normalized)(1)
Co-60 0.064 Sr-90 0.098 Cs-137 0.829 Eu-152 0.005 Eu-154 0.003 (1) Based on maximum percent of total activity from Table 22 of RS-TD-313196-001, normalized to one for the dose significant radionuclides.
The LTP, Section 5.2, states that each radionuclide-specific Base Case DCGL is equivalent to the level of residual radioactivity (above background levels) that could, when considered independently, result in a Total Effective Dose Equivalent (TEDE) of 25 mrem/yr to an Average Member of the Critical Group. To ensure that the summation of dose from each source term is 25 mrem/yr or less after all FSS is completed, the Base Case DCGLs are reduced based on an expected, or a priori, fraction of the 25 mrem/yr dose limit from each
, can be related to the Base Case DCGLs as an expected fraction of dose based on an a priori assessment of what the expected dose should be based on the results of site characterization, process knowledge, and the extent of planned remediation. The Operational DCGL is then used as the DCGL for the FSS design of the survey unit (i.e., calculation of surrogate DCGLs and investigations levels). Details of the Operational DCGLs derived for each dose component and the basis for the applied a priori dose fractions are provided in LC-FS-TSD-002, Operational Derived Concentration Guideline Levels for Final Status Survey (Reference 10).
The dose contribution from each ROC is accounted for using the SOF to ensure that the total dose from all ROC does not exceed the dose criterion. A Base Case DCGL that is established for the average residual radioactivity in a survey unit is equivalent to a DCGLW.
The DCGLW can be multiplied by Area Factors to obtain a Base Case DCGL that represents the same dose to an individual for residual radioactivity over a smaller area within a survey unit.
At LACBWR, compliance is demonstrated through the summation of dose from five (5) distinct source terms for the end state (basements, soils, buried pipe, above-ground structures, and groundwater). When applied to buried pipe, the DCGLs are expressed in units of activity per surface area (dpm/100 cm2).
~
LACROSSESOLUTIONS source term. The reduced DCGLs, or "Operational" DCGLs
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 8
Buried piping is defined as below ground pipe located outside of structures and basements.
The dose assessment methods and resulting DCGLs for buried piping are described in detail in LTP, Section 6.20. The buried piping was separated into two categories. The first category included the summation and grouping of all impacted buried pipe other than the Circulating Water Discharge (CWD) Pipe The second category consisted of the CWD Pipe only. The separation of the Circulating Water pipe was necessary because the geometry of the CWD pipe was significantly different than the other pipes, and the pipes are located in distinctly different parts of the site.
EnergySolutions TSD RS-TD-313196-004, LACBWR Soil DCGL, Basement Concrete DCGL, and Buried Pipe DCGL (Reference 11) and LTP, Section 6.20, provide the exposure scenarios and modeling parameters that were used to calculate the site-specific buried pipe DCGLs. The final DCGLs to be used during FSS account for the fact that the dose from the In Situ and Excavation scenarios must be summed in the conceptual model for buried pipe dose assessment (i.e., the In Situ and Excavation scenarios occur in parallel). The summed Buried Pipe Base Case DCGLs are reproduced in Table 4-2 below. The IC dose percentages for each of the buried pipe scenarios were used to adjust each buried pipe Base Case DCGL to account for the dose from the eliminated IC radionuclides. The Operational DCGLs for the SD2 Pipe are provided in Table 4-3.
Table 4 Base Case DCGLs for Buried Pipe Group Radionuclide DCGLBP (dpm/100 cm2)
Co-60 7.50E+04 Sr-90 5.16E+05 Cs-137 3.18E+05 Eu-152 1.64E+05 Eu-154 1.52E+05
~
LACROSSESOLUTIONS and is designated as the "Buried Pipe Group."
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 9
Table 4 Operational DCGLs for Buried Pipe Group Radionuclide OpDCGLBP (dpm/100 cm2)
Co-60 1.57E+04 Sr-90 1.08E+05 Cs-137 6.68E+04 Eu-152 3.44E+04 Eu-154 3.20E+04 Instrument DQOs included a verification of the ability of the survey instrument to detect the radiation(s) of interest relative to the Operational DCGL. Survey instrument response checks were required prior to issuance and after the instrument had been used. Control and accountability of survey instruments was required to assure the quality and prevent the loss of data.
In accordance with the LTP, the minimum acceptable MDC for measurements obtained using field instruments was 50% of the applicable Operational DCGL.
- 5.
SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey unit and nature of the hazards. Guidance for preparing FSS plans is provided in procedure LC-FS-PR-002, Final Status Survey Package Development.
The DQO process validated that Co-60, Sr-90, Cs-137, Eu-152, and Eu-154 would be the ROC in survey unit S3-012-109 B as presented in LTP Section 5.1. During the data analysis of the FSS results, concentrations for the HTD ROC Sr-90 are inferred using a surrogate approach. Cs-137 is the principle surrogate radionuclide for Sr-90. During characterization, both Sr-90 and Cs-137 was positively detected in all thirty (30) concrete core samples assessed in the Reactor Building, Tunnel, and Waste Treatment Building. The 95% Upper Confidence Limit (UCL) of the Cs-137 fractions was chosen to represent the overall nuclide mix for soils/buried pipe, the Reactor Building, and the Waste Gas Tank Vault. The surrogate ratio for soil/buried pipe is given in Table 5-1.
Table 5-1 Soil/Buried Pipe Surrogate Ratio Radionuclides Ratio Sr-90/Cs-137 0.502 The equation for calculating a surrogate DCGL is as follows:
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 10 Equation 1 Where:
DCGLSur
= Surrogate radionuclide DCGL DCGL
= DCGL for radionuclides to be represented by the surrogate Rn
= Ratio of concentration (or nuclide mixture fraction) of Using the Operational DCGLs presented in Table 4-3 and the ratio from Table 5-1, the following surrogate calculation was performed:
Equation 2 The surrogate Operational DCGL for Cs-137 is then used in the calculation of the gross gamma Operational DCGL, as calculated in Equation 3.
Equation 3 The action level for survey unit S3-012-109 B was equivalent to the calculated gross gamma Operational DCGL of 4.37E+04 dpm/100 cm2.
For the survey of interior pipe surfaces, areal coverage is achieved by the for each static measurement collected. Scanning, in the traditional context, is not applicable to the survey of pipe internal surfaces. For the survey of the SD2 Pipe, the detector was erroneously calibrated for a specific geometry of a 3,050 cm2 (1 ft x 1 m) area of contamination on the bottom of the pipe, resulting in inaccurate detector efficiencies and inaccurate calculations for activity per area. TSD LC-FS-TSD-005, MCNP Modeling of Water Discharge Pipes for the LaCrosse Boiling Water Reactor (Reference 12) was written
~
LACROSSESOLUTIONS 2,3... n radionuclide "n" to surrogate radionuclide 1
Surrogatevcci (cs-137) = [(
1
)
(
o 502
)]
6.68£ + 04(cs-l37) + 1.08£ +
0S(sr-90)
= 5.l0E + 04 dpm/100 cm2 SurrogatevcGL (gamma) 1
[(
0.071
) + (
0.919
) + (
0.006
) + (
0.003
)]
1.57£ + 04(co-60) 5.10£ + 04cs-137 3.44£ + 04(Eu-152) 3.20£ + 04(Eu-154)
= 4.37 E + 04 dpm/100 cm2 "area of detection"
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 11 to address the discrepancy in efficiency and area of detection. The TSD details the Monte Carlo Neutral Particle (MCNP) radiation transport code that modeled the response of a NaI detector to a calibration source for several different pipe sizes. The MCNP models resulted in efficiency correction factors. The calculated efficiency from original source calibration can be multiplied by the correction factors to obtain an efficiency that more realistically portrays the specific contamination geometry of the pipe. For a 48 measurement has a true Field-of-View (FOV) of 11,674.5 cm2.
The SD2 pipe contains 624 linear feet of 48 concrete piping, which equates to a surface area of 728.51 m2 (7,285,097.01 cm2). For survey unit S3-012-109 B, 10% survey coverage was selected. Therefore, one (1) measurement was to be collected every ten (10) linear feet traversed through the pipe, for a total of at least sixty-two (62) distinct measurements over the entire accessible pathway of the piping system. The last twenty feet was inaccessible due to sediment and river levels which resulted in a systematic population of sixty (60) distinct measurements.
Each static measurement represents the gamma activity in gross counts per minute (cpm) for each specific measurement location. Background is subtracted, then the value is converted to dpm using an efficiency factor based on the calibration source and the efficiency correction factors detailed in TSD LC-FS-TSD-005, MCNP Modeling of Water Discharge Pipes for the LaCrosse Boiling Water Reactor. The total activity in dpm is then adjusted for the assumed effective surface area commensurate with the pipe diameter, resulting in units of dpm/100 cm2. The total gamma surface activity for each measurement was converted to an activity concentration for each gamma-emitting ROC, based on the normalized gamma mixture from Table 4-1. Concentrations for the HTD ROC Sr-90 were inferred using the surrogate approach in accordance with LTP Chapter 5.
The implementation of quality control measures as referenced by LTP, Section 5.9 and LaCrosseSolutions LC-QA-PN-001, Final Status Survey Quality Assurance Project Plan (QAPP) (Reference 13) includes the collection of replicate static measurements on 5% of the systematic measurements collected in the survey unit, with the locations selected at random. Four (4) replicate static measurements were selected for Quality Control (QC) analysis for the FSS of this survey unit.
For this Class 3 buried pipe are those levels specified in LTP Chapter 5, Table 5-16, and are reproduced below in Table 5-2.
~
LACROSSESOLUTIONS
" ID pipe, each "ID survey unit, the "Investigation Levels" for measurement results
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 12 Table 5-2 Investigation Levels Classification Scan Investigation Levels Direct Investigation Levels Class 3
> Operational DCGL or >MDCscan if MDCscan is greater than Operational DCGL
> 0.5 Operational DCGL Table 5-3 provides a synopsis of the survey design for survey unit S3-012-109 B.
Table 5-3 Synopsis of Survey Design Feature Design Criteria Basis Survey Unit Surface Area 728.51 m2 (7,285,097.01 cm2) 624 48 concrete pipe Number of Systematic Measurements (N) 62 60 10% coverage (per sample plan) 9.62% coverage (actual number obtained as a of pipe was inaccessible)
Operational DCGLs (dpm/100 cm2)
Co-60: 1.57E+04 Sr-90: 1.08E+05 Cs-137: 6.68E+04 Eu-152: 3.44E+04 Eu-154: 3.20E+04 Operational DCGLs for buried pipe, LTP, Table 5-8, Release Record, Table 4-3 Action Level 4.37E+04 dpm/100 cm2 Gross Gamma Operational DCGL, Equation 3 Investigation Level
> 0.5 Operational DCGL LTP, Table 5-16 Scan Areal Coverage N/A LTP,Section 5.7.1.8 Number of Judgmental Measurements 1
Per Sample Plan QC 4 replicate measurements LTP, Section 5.9
~
LACROSSESOLUTIONS
'of "diameter pproximately 20'
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 13 Feature Design Criteria Basis Non-parametric Statistical Test Sign Test LTP, Section 5.6.4.2
- 6.
SURVEY IMPLEMENTATION FSS field activities were conducted under the FSS sample plan, which included DQOs, survey design, detailed FSS instructions, job safety analysis, and related procedures for reference. The survey unit was inspected and controlled in accordance with LC-FS-PR-010, Isolation and Control for Final Status Survey (Reference 14).
was used to document field activities and other information pertaining to the performance of the FSS.
FSS field activities commenced on August 14, 2019.
FSS field activities were projected to take four (4) working days to complete. Daily briefings were conducted to discuss the expectations for job performance and to review safety aspects of the job. The survey-required field activities were performed during normal working hours and concluded on August 21, 2019. The survey took longer than planned due to the amount of sediment that had to be removed in order to perform the survey.
Background measurements were acquired in the North Yard area of the site. A background study was performed by collecting measurements on a buried piece of 48 concrete pipe.
As a result of the background study, an average background value of 6,541 cpm was assigned to the 48 concrete pipe. This is the value subtracted from each measurement for compliance.
Daily, prior to and following use, each detector was subjected to an Operational Response Check in accordance with procedure LC-FS-PR-018, Radiation Surveys of Pipe Interiors Using Sodium/Cesium Iodide Detectors. The Daily Operational Response Check compared the background response and the response to check source ranges established for normal background and detector source response to ensure that the detector was working properly.
The survey design called for sixty-two (62) measurements but the last twenty feet of SD2 was inaccessible due to sediment and river levels; this resulted in a systematic population of sixty (60) distinct measurements. Although fewer measurements were taken, the scan coverage of 9.62% is within the scan requirement for a Class 3 survey unit.
The sixty (60) systematic 1-minute static measurements were collected using a Ludlum Model 2350-1 paired with a Model 44-10 NaI detector operated in the rate-meter mode and using audio response. The detector was fitted into a wheeled rig, which maintained a fixed detector geometry, an area of detection of 11,674.5 cm2. The static MDC was sufficient to detect residual radioactivity at the action level (adjusted gross gamma Operational DCGL of 4.37E+04 dpm/100 cm2). Complete measurement results are provided in Attachment 2.
~
LACROSSESOLUTIONS A "Field Log" "ID "ID
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 14 One (1) judgmental static measurement was collected during implementation of FSS, in accordance with the sample plan, due to discoloration of the concrete.
The implementation of survey specific QC measures included the collection of four (4) replicate static measurements for QC analysis.
Three (3) sediment samples were taken as part of the FSS of SD2 and all three were sent to the off-site laboratory for Sr-90 analyses.
- 7.
SURVEY RESULTS radiological criteria for license termination when more than one radionuclide has been determined to be potentially present. The equation for the unity rule is:
Equation 4 Where:
Cn
= concentration of radionuclide n DCGLn
= DCGL of radionuclide n.
The application of the unity rule serves to normalize the data to allow for an accurate comparison of the various data measurements to the release criteria. When the unity rule is applied, the DCGLW (used for the nonparametric statistical test) becomes one (1). The DCGLBP are directly analogous to the DCGLW as defined in MARSSIM. The use and application of the unity rule was performed in accordance with section 4.3.3 of MARSSIM.
As described in LTP, Section 5.10.3.2, the Sign Test was used to evaluate the measured residual radioactivity against the dose criterion. The SOF for each measurement was used as the sum value for the Sign Test. The Sign Test then demonstrated that the mean activity for each ROC was less than the OpDCGLBP at a Type I decision error of 0.05. The results of the Sign Test are presented in Attachment 3.
For buried pipe, areas of elevated activity were defined as any area identified by measurement (systematic or judgmental) that exceeded the OpDCGLBP but was less than the DCGLBP. The SOF (based on the OpDCGLB) for a systematic or judgmental measurement can exceed one (1) without remediation as long as the survey unit passes the Sign Test, and the mean SOF (based on the OpDCGLBP) for the survey unit does not exceed one (1). Once the survey data set passes the Sign Test (using Operational DCGLs), then the mean radionuclide activity for each ROC from systematic measurements along with any identified elevated areas from systematic and judgmental samples can be used with the Base
~
LACROSSESOLUTIONS The SOF or "unity rule" is the mathematical test used to evaluate compliance with Ci
+
C2
+............
Cn
- s; l DCGLi DCGL2 DCGLn
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 15 Case DCGLs to perform a mean SOFBP calculation. The dose from residual radioactivity assigned to the FSS unit is the mean SOFBP multiplied by 25 mrem/yr.
The systematic measurement population consisted of sixty (60) static measurements that were acquired using the Ludlum Model 2350-1 paired to a Model 44-10 detector. In total, sixty-five (65) static measurements were collected, including the systematic, judgmental, and QC measurements. A breakdown of the total static measurements and SOF for systematic measurements compared to the OpDCGLBP is provided in Table 7-1. A summary of the results of the systematic measurements taken for non-parametric statistical testing when compared to the DCGLBP is provided in Table 7-2. The complete results of the data assessment for survey unit S3-012-109 B are provided in Attachment 2.
Table 7 Summary of Systematic, Judgmental, and QC Measurements Total Number of Systematic Measurements 60 Number of Quality Control Measurements 4
Number of Judgmental Measurements 1
Total Number of Measurements 65 Mean Systematic Measurement SOF (1) 0.1014 Max Individual Systematic Measurement SOF (1) 0.1254 Number of Systematic Measurements with SOF > 1 (1) 0 Number of Judgmental Measurements with SOF > 1 (1) 0 (1) Based on the OpDCGLBP Table 7 Basic Statistical Properties of the Systematic Measurement Population ROC Mean Median Max.
Min.
Std. Dev.
BcDCGL Avg.
BcSOF per ROC Avg. Dose per ROC (mrem/yr)
(dpm/
100cm2)
(dpm/
100cm2)
(dpm/
100cm2)
(dpm/
100cm2)
(dpm/
100cm2)
(dpm/
100cm2)
Co-60 3.17E+02 3.30E+02 3.92E+02 2.29E+02 5.06E+01 7.50E+04 0.0042 0.1056 Cs-137 4.08E+03 4.25E+03 5.04E+03 2.95E+03 6.51E+02 3.18E+05 0.0128 0.3206 Eu-152 2.70E+01 2.81E+01 3.34E+01 1.95E+01 4.31E+00 1.64E+05 0.0002 0.0041 Eu-154 1.38E+01 1.44E+01 1.71E+01 9.99E+00 2.21E+00 1.52E+05 0.0001 0.0023 Sr-90 2.05E+03 2.13E+03 2.53E+03 1.48E+03 3.27E+02 5.16E+05 0.0040 0.0992 The on-site gamma analysis of the three (3) sediment samples shows that one sample was above MDC for Cs-137, at a concentration of 5.08E-02 pCi/g. No other ROC were detected in any of the sediment samples. The on-site analytical reports are provided in Attachment 6.
The off-site laboratory, GEL Laboratories, analyzed the three (3) sediment samples (S3-012-109B-FJGS-062-SM, S3-012-109B-FJGS-063-SM, and S3-012-109B-FJGS-064-SM) for the full suite of radionuclides. Only Cs-137 was identified in the off-site samples, at a maximum concentration of 4.97E-02 pCi/g. The maximum IC dose calculated for the
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 16 samples is 0.0791 mrem/yr, which is below the 2.5 mrem/yr limit provided in the LTP for DCGL adjustment. The GEL Laboratories report for the full-suite radionuclide analysis of the sediment samples is provided in Attachment 7.
The mean SOF for the SD2 pipe, based on the mean concentration for each ROC as measured by the systematic measurement population when compared against the DCGLBP, is 0.0213. This SOF equates to a dose of 0.5317 mrem/yr.
- 8.
QUALITY CONTROL The implementation of survey specific QC measures included the collection of four (4) replicate static measurements for QC analysis. The acceptance criteria for replicate static measurements is that the same conclusion is reached for each measurement. This is defined as the replicate measurement being within 20% of the standard measurement. In cases where the replicate measurement is not within 20% of the standard measurement, but both measurements are below the Operational DCGL, there is an acceptable agreement. The four (4) QC replicate measurement fell within the 20% criteria, and there is an acceptable agreement between standard and replicate results. Refer to Attachment 4 for QC analysis results.
- 9.
INVESTIGATIONS AND RESULTS No investigations were performed during the performance or analyses of the survey.
- 10.
REMEDIATION AND RESULTS No radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit. Chapter 4 of the LTP determined that remediation beyond that required to meet the release criteria is unnecessary and that the remaining residual radioactivity in buried pipe was ALARA.
- 11.
CHANGES FROM THE FINAL STATUS SURVEY PLAN TSD LC-FS-TSD-005, MCNP Modeling of Water Discharge Pipes for the LaCrosse Boiling Water Reactor, was developed in response to the inaccurate efficiency calibration geometry originally assumed in the sample plan and during survey implementation.
The survey design called for sixty-two (62) measurements but the last twenty feet of SD2 was inaccessible due to sediment and river levels; this resulted in a systematic population of sixty (60) distinct measurements. Although fewer measurements were taken, the scan coverage of 9.62% is within the scan requirement for a Class 3 survey unit.
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 17
- 12.
DATA QUALITY ASSESSMENT The DQO survey design and data were reviewed in accordance with LC-FS-PR-008, Final Status Survey Data Assessment (Reference 15) for completeness and consistency.
Documentation was complete and legible. Surveys were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 3. The survey design had adequate power as indicated by the Retrospective Power Curve (see Attachment 5).
All measurements were less than a SOF of one (1) when compared to the OpDCGLBP.
The Sign Test was performed on the data and compared to the original assumptions of the DQOs. The evaluation of the Sign Test results clearly demonstrates that the survey unit passes the unrestricted release criteria, thus, the null hypothesis is rejected.
The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation). All data was considered valid including negative values, zeros, values reported below the MDC, and values with uncertainties that exceeded two standard deviations. The mean and median values for each ROC were well below the respective Operational DCGLs. Also, the retrospective power curve shows that a sufficient number of measurements were collected to achieve the desired power. Therefore, the survey unit meets the unrestricted release criteria with adequate power as required by the DQOs.
- 13.
ANOMALIES No anomalies were observed during the performance or analyses of the survey.
- 14.
CONCLUSION Survey unit S3-012-109 B has met the DQOs of the FSS plan. The ALARA criteria as specified in Chapter 4 of the LTP were achieved.
The sample data passed the Sign Test. The null hypothesis was rejected. The Retrospective Power Curve showed that adequate power was achieved. The survey unit is properly classified as Class 3. Therefore, in accordance with LTP Section 5.11, the survey unit meets the release criteria.
The dose contribution from survey unit S3-012-109 B is 0.5317 mrem/yr TEDE, based on the average concentration of the ROC in measurements used for non-parametric statistical testing (mean SOF).
Survey unit S3-012-109 B is acceptable for unrestricted release.
- 15.
REFERENCES
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 18
- 1. LC-FS-PR-009, Final Status Survey Data Reporting
- 2. La Crosse Boiling Water Reactor License Termination Plan
- 3. LC-FS-PR-002, Final Status Survey Package Development
- 4. LC-FS-PR-018, Radiation Surveys of Pipe Interiors Using Sodium/Cesium Iodide Detectors
- 5. NUREG-1575, Revision 1, Multi-Agency Radiation Survey and Site Investigation Manual
- 6. La Crosse Boiling Water Reactor Historical Site Assessment
- 7. LC-FS-PR-006, Survey Unit Classification
- 8. RS-TD-313196-001, Radionuclides of Concern during LACBWR Decommissioning
- 9. NUREG-1757, Volume 2, Revision 1, Consolidated Decommissioning Guidance Characterization, Survey, and Determination of Radiological Criteria, Final Report
- 10. LC-FS-TSD-002, Operational Derived Concentration Guideline Levels for Final Status Survey DCGL
- 11. RS-TD-313196-004, LACBWR Soil DCGL, Basement Concrete DCGL, and Buried Pipe
- 12. LC-FS-TSD-005, MCNP Modeling of Water Discharge Pipes for the LaCrosse Boiling Water Reactor
- 13. LC-QA-PN-001, Final Status Survey Quality Assurance Project Plan
- 14. LC-FS-PR-010, Isolation and Control for Final Status Survey
- 15. LC-FS-PR-008, Final Status Survey Data Assessment
- 16.
ATTACHMENTS Figures and Maps Measurement Data Sign Test Quality Control Assessment Graphical Presentations Sample Analytical Reports GEL Laboratories Analytical Reports
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRIAIN 2 SURVEY UNIT S3-012-109 B 19 ATTACHMENT 1 FIGURES AND MAPS
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 20 Figure 16-1 Survey Unit S3-012-109 B Drawing Legend Buildings Storm Drain Pipes Other Piping
~
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 21 ATTACHMENT 2 MEASUREMENT DATA
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 22 Table 16-1 Survey Unit S3-012-109 B Static Measurements Data Assessment Measurement Population Measurement ID Gamma Result Activity1 (dpm/100 cm2)
Fraction of OpDCGL Measurement OpSOF dpm/100 cm2 Co-60 Cs-137 Eu-152 Eu-154 Sr-90 Co-60 Cs-137 Eu-152 Eu-154 Sr-90 S
1 3439 2.46E+02 3.16E+03 2.09E+01 1.07E+01 1.59E+03 0.0156 0.0473 0.0006 0.0003 0.0147 0.0786 S
2 5193 3.71E+02 4.77E+03 3.16E+01 1.62E+01 2.40E+03 0.0236 0.0715 0.0009 0.0005 0.0222 0.1187 S
3 4996 3.57E+02 4.59E+03 3.04E+01 1.56E+01 2.31E+03 0.0227 0.0688 0.0009 0.0005 0.0214 0.1142 S
4 5044 3.60E+02 4.64E+03 3.07E+01 1.57E+01 2.33E+03 0.0229 0.0694 0.0009 0.0005 0.0216 0.1153 S
5 5485 3.92E+02 5.04E+03 3.34E+01 1.71E+01 2.53E+03 0.0250 0.0755 0.0010 0.0005 0.0234 0.1254 S
6 4805 3.43E+02 4.42E+03 2.93E+01 1.50E+01 2.22E+03 0.0219 0.0661 0.0009 0.0005 0.0205 0.1098 S
7 4612 3.29E+02 4.24E+03 2.81E+01 1.44E+01 2.13E+03 0.0210 0.0635 0.0008 0.0004 0.0197 0.1054 S
8 5368 3.83E+02 4.94E+03 3.27E+01 1.67E+01 2.48E+03 0.0244 0.0739 0.0010 0.0005 0.0229 0.1227 S
9 4634 3.31E+02 4.26E+03 2.82E+01 1.44E+01 2.14E+03 0.0211 0.0638 0.0008 0.0005 0.0198 0.1059 S
10 5087 3.63E+02 4.68E+03 3.10E+01 1.59E+01 2.35E+03 0.0231 0.0700 0.0009 0.0005 0.0217 0.1163 S
11 5133 3.67E+02 4.72E+03 3.13E+01 1.60E+01 2.37E+03 0.0233 0.0706 0.0009 0.0005 0.0219 0.1173 S
12 5278 3.77E+02 4.85E+03 3.21E+01 1.64E+01 2.44E+03 0.0240 0.0726 0.0009 0.0005 0.0226 0.1206 S
13 5354 3.82E+02 4.92E+03 3.26E+01 1.67E+01 2.47E+03 0.0244 0.0737 0.0009 0.0005 0.0229 0.1224 S
14 4837 3.45E+02 4.45E+03 2.95E+01 1.51E+01 2.23E+03 0.0220 0.0666 0.0009 0.0005 0.0207 0.1106 S
15 5175 3.70E+02 4.76E+03 3.15E+01 1.61E+01 2.39E+03 0.0235 0.0712 0.0009 0.0005 0.0221 0.1183 S
16 5296 3.78E+02 4.87E+03 3.22E+01 1.65E+01 2.44E+03 0.0241 0.0729 0.0009 0.0005 0.0226 0.1211 S
17 5153 3.68E+02 4.74E+03 3.14E+01 1.61E+01 2.38E+03 0.0234 0.0709 0.0009 0.0005 0.0220 0.1178 S
18 4954 3.54E+02 4.55E+03 3.02E+01 1.54E+01 2.29E+03 0.0225 0.0682 0.0009 0.0005 0.0212 0.1132 S
19 5483 3.92E+02 5.04E+03 3.34E+01 1.71E+01 2.53E+03 0.0249 0.0755 0.0010 0.0005 0.0234 0.1253 S
20 4733 3.38E+02 4.35E+03 2.88E+01 1.47E+01 2.18E+03 0.0215 0.0651 0.0008 0.0005 0.0202 0.1082 S
21 4803 3.43E+02 4.42E+03 2.92E+01 1.50E+01 2.22E+03 0.0218 0.0661 0.0009 0.0005 0.0205 0.1098 S
22 5449 3.89E+02 5.01E+03 3.32E+01 1.70E+01 2.51E+03 0.0248 0.0750 0.0010 0.0005 0.0233 0.1246 S
23 4924 3.52E+02 4.53E+03 3.00E+01 1.53E+01 2.27E+03 0.0224 0.0678 0.0009 0.0005 0.0210 0.1126
~
LACROSSE SOLUTIONS
FSS RELEASE RECORD REVISION 1 LOW PRESSURE SERVICE WATER SURVEY UNIT S3-012-109 B 23 Measurement Population Measurement ID Gamma Result Activity1 (dpm/100 cm2)
Fraction of OpDCGL Measurement OpSOF dpm/100 cm2 Co-60 Cs-137 Eu-152 Eu-154 Sr-90 Co-60 Cs-137 Eu-152 Eu-154 Sr-90 S
24 4385 3.13E+02 4.03E+03 2.67E+01 1.37E+01 2.02E+03 0.0199 0.0603 0.0008 0.0004 0.0187 0.1002 S
25 4638 3.31E+02 4.26E+03 2.82E+01 1.45E+01 2.14E+03 0.0211 0.0638 0.0008 0.0005 0.0198 0.1060 S
26 4501 3.21E+02 4.14E+03 2.74E+01 1.40E+01 2.08E+03 0.0205 0.0620 0.0008 0.0004 0.0192 0.1029 S
27 4051 2.89E+02 3.72E+03 2.47E+01 1.26E+01 1.87E+03 0.0184 0.0558 0.0007 0.0004 0.0173 0.0926 S
28 3946 2.82E+02 3.63E+03 2.40E+01 1.23E+01 1.82E+03 0.0180 0.0543 0.0007 0.0004 0.0169 0.0902 S
29 4449 3.18E+02 4.09E+03 2.71E+01 1.39E+01 2.05E+03 0.0202 0.0612 0.0008 0.0004 0.0190 0.1017 S
30 4163 2.97E+02 3.83E+03 2.53E+01 1.30E+01 1.92E+03 0.0189 0.0573 0.0007 0.0004 0.0178 0.0952 S
31 4314 3.08E+02 3.97E+03 2.63E+01 1.34E+01 1.99E+03 0.0196 0.0594 0.0008 0.0004 0.0184 0.0986 S
32 4751 3.39E+02 4.37E+03 2.89E+01 1.48E+01 2.19E+03 0.0216 0.0654 0.0008 0.0005 0.0203 0.1086 S
33 4173 2.98E+02 3.84E+03 2.54E+01 1.30E+01 1.93E+03 0.0190 0.0574 0.0007 0.0004 0.0178 0.0954 S
34 4127 2.95E+02 3.79E+03 2.51E+01 1.29E+01 1.90E+03 0.0188 0.0568 0.0007 0.0004 0.0176 0.0943 S
35 3425 2.45E+02 3.15E+03 2.09E+01 1.07E+01 1.58E+03 0.0156 0.0471 0.0006 0.0003 0.0146 0.0783 S
36 3337 2.38E+02 3.07E+03 2.03E+01 1.04E+01 1.54E+03 0.0152 0.0459 0.0006 0.0003 0.0143 0.0763 S
37 3840 2.74E+02 3.53E+03 2.34E+01 1.20E+01 1.77E+03 0.0175 0.0528 0.0007 0.0004 0.0164 0.0878 S
38 3568 2.55E+02 3.28E+03 2.17E+01 1.11E+01 1.65E+03 0.0162 0.0491 0.0006 0.0003 0.0152 0.0816 S
39 3518 2.51E+02 3.23E+03 2.14E+01 1.10E+01 1.62E+03 0.0160 0.0484 0.0006 0.0003 0.0150 0.0804 S
40 4029 2.88E+02 3.70E+03 2.45E+01 1.26E+01 1.86E+03 0.0183 0.0554 0.0007 0.0004 0.0172 0.0921 S
41 3582 2.56E+02 3.29E+03 2.18E+01 1.12E+01 1.65E+03 0.0163 0.0493 0.0006 0.0003 0.0153 0.0819 S
42 3206 2.29E+02 2.95E+03 1.95E+01 9.99E+00 1.48E+03 0.0146 0.0441 0.0006 0.0003 0.0137 0.0733 S
43 3365 2.40E+02 3.09E+03 2.05E+01 1.05E+01 1.55E+03 0.0153 0.0463 0.0006 0.0003 0.0144 0.0769 S
44 3653 2.61E+02 3.36E+03 2.22E+01 1.14E+01 1.69E+03 0.0166 0.0503 0.0006 0.0004 0.0156 0.0835 S
45 3339 2.38E+02 3.07E+03 2.03E+01 1.04E+01 1.54E+03 0.0152 0.0460 0.0006 0.0003 0.0143 0.0763 S
46 3375 2.41E+02 3.10E+03 2.05E+01 1.05E+01 1.56E+03 0.0154 0.0464 0.0006 0.0003 0.0144 0.0772 S
47 3546 2.53E+02 3.26E+03 2.16E+01 1.11E+01 1.64E+03 0.0161 0.0488 0.0006 0.0003 0.0152 0.0811
~
LACROSSE SOLUTIONS
FSS RELEASE RECORD REVISION 1 LOW PRESSURE SERVICE WATER SURVEY UNIT S3-012-109 B 24 Measurement Population Measurement ID Gamma Result Activity1 (dpm/100 cm2)
Fraction of OpDCGL Measurement OpSOF dpm/100 cm2 Co-60 Cs-137 Eu-152 Eu-154 Sr-90 Co-60 Cs-137 Eu-152 Eu-154 Sr-90 S
48 3534 2.52E+02 3.25E+03 2.15E+01 1.10E+01 1.63E+03 0.0161 0.0486 0.0006 0.0003 0.0151 0.0808 S
49 3457 2.47E+02 3.18E+03 2.11E+01 1.08E+01 1.60E+03 0.0157 0.0476 0.0006 0.0003 0.0148 0.0790 S
50 3854 2.75E+02 3.54E+03 2.35E+01 1.20E+01 1.78E+03 0.0175 0.0530 0.0007 0.0004 0.0165 0.0881 S
51 3974 2.84E+02 3.65E+03 2.42E+01 1.24E+01 1.83E+03 0.0181 0.0547 0.0007 0.0004 0.0170 0.0909 S
52 3870 2.76E+02 3.56E+03 2.36E+01 1.21E+01 1.79E+03 0.0176 0.0533 0.0007 0.0004 0.0165 0.0885 S
53 3781 2.70E+02 3.48E+03 2.30E+01 1.18E+01 1.75E+03 0.0172 0.0520 0.0007 0.0004 0.0162 0.0864 S
54 5083 3.63E+02 4.67E+03 3.09E+01 1.58E+01 2.35E+03 0.0231 0.0700 0.0009 0.0005 0.0217 0.1162 S
55 5024 3.59E+02 4.62E+03 3.06E+01 1.57E+01 2.32E+03 0.0229 0.0691 0.0009 0.0005 0.0215 0.1149 S
4930 3.52E+02 4.53E+03 3.00E+01 1.54E+01 2.28E+03 0.0224 0.0678 0.0009 0.0005 0.0211 0.1127 S
57 5266 3.76E+02 4.84E+03 3.21E+01 1.64E+01 2.43E+03 0.0240 0.0725 0.0009 0.0005 0.0225 0.1204 S
58 4743 3.39E+02 4.36E+03 2.89E+01 1.48E+01 2.19E+03 0.0216 0.0653 0.0008 0.0005 0.0203 0.1084 S
59 4936 3.53E+02 4.54E+03 3.01E+01 1.54E+01 2.28E+03 0.0225 0.0679 0.0009 0.0005 0.0211 0.1128 S
60 5143 3.67E+02 4.73E+03 3.13E+01 1.60E+01 2.37E+03 0.0234 0.0708 0.0009 0.0005 0.0220 0.1176 J
61 5656 4.04E+02 5.20E+03 3.44E+01 1.76E+01 2.61E+03 0.0257 0.0778 0.0010 0.0006 0.0242 0.1293 Q
6 4964 3.55E+02 4.56E+03 3.02E+01 1.55E+01 2.29E+03 0.0226 0.0683 0.0009 0.0005 0.0212 0.1135 Q
17 4650 3.32E+02 4.28E+03 2.83E+01 1.45E+01 2.15E+03 0.0212 0.0640 0.0008 0.0005 0.0199 0.1063 Q
34 4453 3.18E+02 4.09E+03 2.71E+01 1.39E+01 2.06E+03 0.0203 0.0613 0.0008 0.0004 0.0190 0.1018 Q
52 3919 2.80E+02 3.60E+03 2.39E+01 1.22E+01 1.81E+03 0.0178 0.0539 0.0007 0.0004 0.0167 0.0896 (1) Sr-90 activity inferred from Cs-137
~
LACROSSE SOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 25 ATTACHMENT 3 SIGN TEST
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 26 Table 16-2 Survey Unit S3-012-109 B Sign Test SOF 1-Ws Sign (Ws) 1 0.0786 0.92
+1 2
0.1187 0.88
+1 3
0.1142 0.89
+1 4
0.1153 0.88
+1 5
0.1254 0.87
+1 6
0.1098 0.89
+1 7
0.1054 0.89
+1 8
0.1227 0.88
+1 9
0.1059 0.89
+1 10 0.1163 0.88
+1 11 0.1173 0.88
+1 12 0.1206 0.88
+1 13 0.1224 0.88
+1 14 0.1106 0.89
+1 15 0.1183 0.88
+1 16 0.1211 0.88
+1 17 0.1178 0.88
+1 18 0.1132 0.89
+1 19 0.1253 0.87
+1 20 0.1082 0.89
+1 21 0.1098 0.89
+1 22 0.1246 0.88
+1 23 0.1126 0.89
+1 24 0.1002 0.90
+1 25 0.1060 0.89
+1 26 0.1029 0.90
+1 27 0.0926 0.91
+1 28 0.0902 0.91
+1 29 0.1017 0.90
+1 30 0.0952 0.90
+1 31 0.0986 0.90
+1 32 0.1086 0.89
+1 33 0.0954 0.90
+1 34 0.0943 0.91
+1 35 0.0783 0.92
+1
,-:::::=
LACROSSE SOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 27 SOF 1-Ws Sign (Ws) 36 0.0763 0.92
+1 37 0.0878 0.91
+1 38 0.0816 0.92
+1 39 0.0804 0.92
+1 40 0.0921 0.91
+1 41 0.0819 0.92
+1 42 0.0733 0.93
+1 43 0.0769 0.92
+1 44 0.0835 0.92
+1 45 0.0763 0.92
+1 46 0.0772 0.92
+1 47 0.0811 0.92
+1 48 0.0808 0.92
+1 49 0.0790 0.92
+1 50 0.0881 0.91
+1 51 0.0909 0.91
+1 52 0.0885 0.91
+1 53 0.0864 0.91
+1 54 0.1162 0.88
+1 55 0.1149 0.89
+1 56 0.1127 0.89
+1 57 0.1204 0.88
+1 58 0.1084 0.89
+1 59 0.1128 0.89
+1 60 0.1176 0.88
+1 Number of positive differences (S+)
60 Critical Value 36 Survey Unit Meets the Acceptance Criteria
,-:::::=
LACROSSE SOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 28 ATTACHMENT 4 QUALITY CONTROL ASSESSMENT
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 29 Table 16-3 Survey Unit S3-012-109 B QC Assessment Standard Measurement Replicate ID Activity Value
+20%
-20%
ID Activity Value Acceptable (Y/N) 6 4805 5766 3844 QC6 4964 Y
17 5153 6184 4122 QC17 4650 Y
34 4127 4953 3302 QC34 4453 Y
52 3870 4644 3096 QC52 3919 Y
Comments/Corrective Actions: The replicate measurement results are in acceptable agreement The acceptance criteria for replicate static measurements and is that the same conclusion is reached for each measurement. This is defined as the replicate measurement being within 20% of the standard measurement. In cases where the replicate measurement is not within 20% of the standard measurement, but both measurements are below the Operational DCGL, there is an acceptable agreement.
~
LACROSSE SOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 30 ATTACHMENT 5 GRAPHICAL PRESENTATIONS
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 31 Figure 16 Quantile Plot for Gross Gamma Activity
~
LACROSSESOLUTIONS
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 32 Figure 16 Histogram for Gross Gamma Activity
~
LACROSSE SOLUTIONS 35 31 30 25 20 u z w
- , a w
a:
15
- u.
15 14 10 0
0 0
0 9.14E+02 1.83E+03 2.74E+03 3.66E+03 4.S7E+03 5.48E+03 UPPER END VALUE (DPM/100CM2)
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 33 Figure 16 Retrospective Power Curve for Survey Unit S3-012-109 B
~
LACROSSE SOLUTIONS Probability that the urvey -nit Pas e 1.0 0.8 0.6 0.4 0.2 0.0 lo..
1)%
3)%
5)%
0%
9)% 1 )0% 110%
1JO%
151 0%
True urve_
- nit Conceotr tion (percent of D GL)
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 34 ATTACHMENT 6 SAMPLE ANALYTICAL REPORTS
~
LACROSSESOLUTIONS
10/19/2020 Page 1 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 1:51 :13PM
~pex-Gamma Analysis Report for Sl-012-1098-FJGS-062-SM Sl-012-109 B GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels}
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- S3-012-1098-FJGS-062-SM
- S3-012-109 B
- 500 ml Marinelli 7.853E+02 grams
- Dairyland_NPP
- 8/22/2019 10:05:00AM
- 8/23/2019 1:20:54PM
- 500ml Marinelli
- Administrator
- HOTLAB
- 500ml Marinelli
- 1800.0 seconds
- 1805.5 seconds
- 0.30 %
- 3.00
- 100- 4096
- 100-4096
- 1.000 keV
- 7/8/2014
- 7/8/2014
- 7325 PEAK ANALYSIS REPORT Peak Analysis Performed on
- 8/23/2019 1 :51 :04PM Peak Analysis From Channel Peak Analysis To Channel
- 100
- 4096 Page 1 of6
10/19/2020 Page 2 LAC LTP - Final Status Survey Package - 8/14/2019 F
F F
F F
F F
F F
F 8/23/2019 1:51:13PM Page 2 of6 Analysis Report for S3-012-109B-FJGS-062-SM F
F F
F F
F F
F F
F S3-012-109 B Peak.
Energy ROI ROI No.
(keV) start end 1
76. 99 152 -
161 2
238. 51 473 -
481 3
295. 22 587 -
594 4
351. 89 698 -
711 5
582. 93 1160 - 1174 6
609. 27 1214 - 1226 7
910. 59 1816 - 1827 8
968. 99 1934 -
1 944 9
1120. 51 2237 -
224 6 10 1460.4 5 2913 - 2930 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma Peak Net Peak.
Net Area Continuum Centroid Area Uncertainty Counts 154. 53 5. 21E+Ol 18. 66 5. 32E+02 477. 50 1. 45E+02 31. 16 2. 36E+02 590. 89 4. 83E+Ol 19. 07 9. 55E+Ol 704. 20
- 1. 06E+02 24. 79 1. 32E+02 1166.21 5. 27E+Ol 17. 20 5. 87E+Ol 1218. 88 6. 55E+Ol 18. 62 6. 12E+Ol 1821. 42 2. 76E+Ol 14. 02 4. 80E+Ol 1938. 19 2.31E+Ol 12.8 8 4.03E+Ol 2241.19 l. 63E+Ol 10. 42 2. 14E+Ol 2921. 02 2. 63E+02 32. 98 l.60E+Ol BACKGROUND SUBTRACT REPORT
- 8/23/2019 1 :51 :04PM Peak Analysis Performed on Env. Background File
- C:\\Canberra\\Apex\\Root\\Dairyland_NPP\\Data\\0000001364. CNF Peak.
Energy Original Orig. Area Ambient Back.gr.
No.
(keV)
Area Uncertainty
Background
Uncert.
1 76. 99 5. 21E+Ol 1 8. 66 2
238. 51
- 1. 45E+02 31.16 3
295. 22 4. 83E+Ol 19. 07 4
351. 89 1.06E+02 24. 79 4. 18E+Ol l. 86E+Ol 5
582. 93 5. 27E+Ol 17. 20 6
609. 27 6. 55E+Ol 18. 62 2. 06E+Ol 1. 21E+Ol 7
910. 59 2. 76E+Ol 14. 02 8
968. 99 2. 31E+Ol 12. 88 9
11 20. 51
- 1. 63E+Ol 10.4 2 10 1 4 60. 45 2. 63E+02 32. 98 2. 82E+Ol 8. 57E+OO M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma Subtracted Area 5. 21E+Ol l. 45E+02 4. 83E+Ol 6. 38E+Ol 5. 27E+Ol 4. 49E+Ol 2. 76E+Ol 2. 31E+Ol
- 1. 63E+Ol 2. 35E+02 FWHM (keV) 0. 44
- 1. 29
- 1. 32
- 1. 76
- 1. 88
- 1. 54
- 1. 86
- 1. 69
- 1. 62 2. 60 Subtracted Uncert.
l. 87E+Ol 3. 12E+Ol 1. 91E+Ol 3. lOE+Ol 1. 72E+Ol 2. 22E+Ol 1. 40E+Ol l. 29E+Ol 1. 0 4E+Ol 3. 41E+Ol
10/19/2020 Page 3 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 1:51 :13PM Page 3 of6 Analysis Report for S3--012-109B-FJGS-062-SM S3--012-109 B NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Dairyland_NPP\\Library\\HOTLAB.NLB IDENTIFIED NUCLIDES Nucllde Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCVgrams)
Uncertainty K-40 0. 98 1460.75 10.67 6. 52E+OO
- 1. OlE+OO PB-212 0. 99 77. 11 17. 50 l. 87E-01 6. 82E-02 238. 63 44. 60 l.90E-Ol 4. 21E-02 BI-214 0. 58 609. 31 46. 30
- l. 63E-01 1238.11 5. 94 1377. 67 4. 11 1407. 98 2. 48 1509. 19 2. 19 1764. 49 15. 80 PB-214 1.00 77.11 10. 70 3. 06E-01 1. llE-01 295.21 19. 20 l. 76E-01 7. 00E-02 351. 92 37. 20
- 1. 40E-01 6. BSE-0 2
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence Index threshold = 0.30 Errors quoted at 2.000sigma INTERFERENCE CORRECTED REPORT Nucflde Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCi/grams)
Uncertainty K-40 0.986 6. 52E+OO 1.0lE+OO PB-212 0.9 98 1. 66£-01 3.66E-02 BI - 214 0.584
10/19/2020 Page 4 LAC LTP - Final Status Survey Package - 8/14/2019 I
Analysis Report for S3-012-1098-F JGS-062-SM S3-012-109 B Nuclide Name PB-214 Nuc/lde Id Confidence
- 1. 000
? = nuclide is part of an undetermined solution X
= nuclide rejected by the interference analysis 8/23/2019 1:51 :13PM Wt mean Wt mean Activity Activity (pCi/grams)
Uncertainty
- 1. 38E-01 4.59E-02
@ = nuclide contains energy lines not used In Weighted Mean Activity Errors quoted at 2.000s!gma Pagc4 of6 Comments
10/19/2020 Page 5 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 1:51 :13PM Analysis Report for S3-012-109B-FJGS-062-SM F
F F
+
+
+
+
+
+
+
+
S3-012-109 B Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV) 5 582. 93 7
910. 59 8
968. 99 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 8/23/2019 1 :51 :04PM
- 100
Uncertainty 16. 31 25. 36 27. 82 NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Dairyland_NPP\\Library\\HOTLAB.NLB Nuclide Energy Yield(%)
Activity NuclldeMDA Name (keV)
(pCUgrams)
(pCVgrams)
K-40 1460. 75 10. 67 6. 52E+00 8. 44E-01 AR-41 1293. 64 99. 16
- 1. 79E+03 3. 08E+03 CO-60 1173. 22 100. 00 4. 35£- 02 8. 27E- 02 1332. 49 100. 00
-1. 09E- 02 KR-85 513. 99 0. 43 1. 69E+0l l. 49E+0l Y-88 898. 04 93. 70
- 1. 13£- 02 5. 77£-02 1836. 06 99. 20
-6. 75E-02 NB-94 702. 63 100. 00 6. 86E-04 6. 09E- 02 871. 10 100. 00
- 7. 03E- 03 I-131 28 4. 30 6. 06 4.74E-01 6. 59E- 02 3 64.4 8
- 81. 20 4. 21E- 02 636. 97 7. 27 2. 58E- 01 CS-134 60 4. 70 97. 60
-3. 54E- 02 7. 09E- 02 795. 84 85. 40 2. 79E- 02 Peak Type Tol.
Tol.
LineMDA (pCUgrams) 8. 44E- 01 3. 08E+03 9. 78E- 02 8. 27E- 02 1. 49E+0l 7. 98E- 02 5. 77E- 02 6. 09E- 02 6. 87E- 02 8. 98E- 01 6. 59E-02 9. 41E- 01 7. 82E- 02 7. 09E-02 Page S of6 Tolerance Nuclide PA-228 AC-228
10/19/2020 Page 6 LAC LTP - Final Status Survey Package - 8/14/2019 8123/2019 1:51:13PM Page 6 of6 Analysis Report for S3-012-1 098-FJGS-062-SM S3-012-109 B Nuclide Energy Yield(%)
Activity Nucl/deMDA LlneMDA Name (keV)
(pCi/grams)
(pCVgrams)
(pC//grams)
+
CS-137 661. 65 85. 12 l. 15E-01 8. 31E- 02 8. 31E-02
+
CE-144 80. 12 1.36 7. 20E-02 3. 97E- 01 5. 17E+OO 133. 51 11.09
-4. 68E-02 3. 97E- 01
+
EU-152 121. 78 28. 40
-2.21E- 01
- 1. 53E-01
- 1. 53E- 01 344. 28 26. 60 2. 72E-02 2. lOE- 01 1408. 00 20.74 3. 46E- 02 3. 39E- 01
+
EU-154 123. 07 40. 40
-1.40E- 01
+
EU-155 86. 54 32. 80
-1. lOE- 01 l. 77E-01 l. 77E-01 105. 31
- 21. 80
-l. 58E- 01 2. 09E-01
+
BI-214 609.31 46. 30 l. 32E-01 1. 22E-01
- 1. 22E-Ol 1120. 29 15. 10 2.54E- 01 2. 95E- 01 1238. 11 5. 94
- 1. 36E+OO l. 93E+OO 1377. 67 4. 11 4. 40E- 01 1. 65E+OO 1407. 98 2. 48 2. 89E- 01 2. 84E+OO 1509. 19 2. 19 l. 67E+OO 2. 62E+OO 1764. 49 15. 80 1. 04E- 01 4. 55E-01
+
PB-214 77. 11 10. 70 3. 06E- 01 1. 27E-01 4. 98E- 01 295. 21 19. 20 l. 76E-01 l.27E-01 351. 92 37. 20 l.40E-01 1. 33E-01
+
PA-228 89. 95 22. 00 6. 31E-01 3. 64E- 01 6. 21E- 01 93. 35 35. 00
- 8. 45E-02 3. 64E- 01 105. 00 16. 30
- 3. 46E- 01 6. 70E- 01 129. 22 2. 97 2. 40E+OO 3. 55E+OO 338. 32 5. 30 4. 96E- 01 2. 36E+OO 463. 00 13. 80
- 3. 91E-Ol 8. 90E- 01 911. 23 16. 70 l. 45E+OO l.26E+OO
+
AM-241 59. 54 36. 30
+
CM-243 103. 76 23. 00 5. 86E-02 2. 05E- 01 2. 0SE-01 228. 18 10. 60 1. 72E- 01 4. 34£- 01 277. 60 14. 00
- l. 46E- 01 3. 41E-01
+ = Nuclide identified during the nuclide identification
= Energy line found in the spectrum
= MDA value not calculated
@ = Half-life too short to be able to perform the decay correction
? = CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level
10/19/2020 Page 7 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:24:54PM pex-Gamma Analysis Report for S3-012-109B-FJGS-063-SM Sl-012-109 8 GAMMA SPECTRUM ANALYSIS Sample Identification Sample Descfiption Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locale Range (In channels)
Peak Area Range (In channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Descfiption Sample Number
- S3-012-1098-FJGS-063-SM
- S3-012-109 B
- 500 ml Marinelli 7.990E+02 grams
- Dairyland_NPP
- 8/22/2019 10:14:00AM
- 8/23/2019 1 :54:35PM
- 500ml Marinelli
- Administrator
- HOTLAB
- 500ml Marinelli
- 1800.0 seconds
- 1805.6 seconds
- 0.31 %
- 3.00
- 100-4096
- 100-4096
- 1.000 keV
- 7/8/2014
- 7/8/2014
- 7326 PEAK ANALYSIS REPORT Peak Analysis Perfonned on
- 8/23/2019 2:24:45PM Peak Analysis From Channel Peak Analysis To Channel
- 100
- 4096 Page I of6
10/19/2020 Page 8 LAC LTP - Final Status Survey Package - 8/14/2019 F
F F
F F
F F
F 8/23/2019 2:24:54PM Page2 of 6 Analysis Report for S3-012-1098-FJGS-063-SM F
F F
F F
F F
F S3-012-109 B Peak Energy ROI ROI No.
(keV) start end 1
77. 08 152 -
158 2
186. 05 369 -
378 3
238. 55 471 -
481 4
294. 92 582 -
595 5
351. 60 697 -
709 6
583. 06 1161 -
1173 7
609. 14 1211 -
1224 8
1460.71 2913 -
2929 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma Peak Net Peak Net Area Continuum Centroid Area Uncertainty Counts 154. 71 8. 04£+01 31. 29 3. 69£+02 372. 60 3. 32£+01 14. 76 3. 12£ 02 477. 58 1. 15E+02 30. 76 3. 39£+02 590. 29 6. 35E+Ol 21. 53
- 1. 89£+02 703. 63 9. 82E+O l 24. 91 1. 43E+02 1166. 46 4. 00E+Ol 16.85 6. 77E+Ol 1218. 62 7. 36E+Ol 19. 71 6. 66£+01 2921. 53 2. 96E+02 34. 84 1. 70E+Ol BACKGROUND SUBTRACT REPORT
- 8/23/2019 2:24:45PM Peak Analysis Performed on Env. Background File
- C:\\Canberra\\Apex\\Root\\Dairyland_NPP\\Data\\0000001364.CNF Peak Energy Original Orig. Area Ambient Backgr.
No.
(keV)
Area Uncertainty
Background
Uncert.
1 77. 08 8. 04E+Ol 31. 29 2
186. 05 3. 32E+Ol 14. 76 3
238. 55 1.15E+02 30. 76 4
2 94. 92 6. 35E+Ol
- 21. 53 5
351. 60 9. 82E+Ol 24. 91 4. 18E+Ol
- 1. 86£+01 6
583. 06 4. 00E+Ol 16. 85 7
609. 14 7. 36E+Ol 19. 71 2.06E+Ol
- 1. 21E+Ol 8
1 460. 71 2. 96E+02 34. 84 2. 82E+Ol 8. 57E+OO M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma Subtracted Area 8. 04E+Ol 3. 32E+Ol l. 15E+02 6. 35E+Ol 5. 64E+Ol 4.00E+Ol 5. 30E+Ol 2. 68E+02 FWHM (keV) 1.24 0. 49 1.30
- 1. 20
- 1. 71 2. 13
- 1. 61 2. 32 Subtracted Uncert.
3. 13E+Ol 1.48£+01 3. 08E+Ol 2. 15E+Ol 3. llE+Ol 1. 69E+Ol 2. 31E+Ol 3. 59E+Ol
10/19/2020 Page 9 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:24:54PM Page l of6 Analysis Report for S3-012-109B-FJGS-063-SM S3-012-109 B NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Oairyland_NPP\\Llbrary\\HOTLAB.NLB IDENTIFIED NUCLIDES Nucllde Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCUgrams)
Uncertainty K-40 1.00 1460. 75 10. 67 7. 30E+OO
- 1. 06E+OO PB-212 0. 99 77. 11 17. 50 2. 83E- 01 l. 12E- 01 238. 63 44. 60 l.48E- 01 4. 04E- 02 BI-214 0. 34 609. 31 46. 30 l. 53E- 01 6. 72E- 02 1120. 29 15. 10 1238. 11 5. 94 1377. 67 4. 11 1407. 98 2. 48 1509. 19 2. 19 1764. 49 15. 80 PB-21 4 0. 98 77. 11 10. 70 4. 63E- 01 l. 83E-01 295. 21 19. 20 2. 27E- 01 7. 78E- 02 351. 92 37. 20
- 1. 22E- 01 6. 75E- 02 RA-226 0. 99 186. 21 3. 28
- 4. 90E- 01 2. 20E-Ol
- = Energy line found In the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy llne not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCl/grams)
Uncertainty K-40 1.000 7. 30E+OO 1. 06E+OO PB-212 0. 999 1. 52E- 01 3. 82E- 02
10/19/2020 Page 10 LAC LTP - Final Status Survey Package - 8/14/2019 Analysis Report for S3-012-109B-FJGS-063-SM S3-012-109 B Nuclide Nuclide Name Id Confidence BI-214 0.347 PB-214 0. 987 RA-226 0. 996
?
= nuclide is part of an undetermined solution X = nuclide rejected by the interference analysis 8/23/2019 Wt mean Activity (pCi/grams) 1.53E-Ol 1. 71E-Ol 4. 90E-01
=
nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 2:24:54PM Page 4 of6 Wt mean Comments Activity Uncertainty
10/19/2020 Page 11 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:24:54PM Analysis Report for S3-012-1098-FJGS-063-SM F
+
+
+
+
+
+
+
+
+
+
S3-012-109 B Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV) 6 583. 06 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 8/23/2019 2:24:45PM
- 100
- 4096 Peak CPS(%)
Peak Size (CPS)
Uncertainty 2. 22009E- 02 21.09 NUCLIDE MDA REPORT Peak Type Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Dairy1and_NPP\\Library\\HOTLAB.NLB Nuclide Energy Yleld(%)
Activity NuclldeMDA LlneMDA Name
{keV)
(pCVgrams)
(pCUgrams)
(pCi/grams)
K-40 1460. 75 10. 67 7. 30E+00 8. 41E- 01 8. 41E- 0l AR-41 1293. 64 99. 16 4. 53E+02 3. 54E+03 3. 54E+03 CO-60 1173. 22 100. 00 4. 75E- 02 8. 84E- 02 9. 75E- 02 1332. 49 100. 00 6. 0SE- 02 8. 84E- 02 KR-85 513. 99
- 0. 43 2. 02E+0l 1. 55E+0l
- 1. 55E+0l Y-88 898. 04
- 93. 70
- 5. 58E- 02 5. 96E-02 7. 06E- 02 1836. 06 99. 20
- 2. 05E- 02 5.9 6E- 02 NB-94 702. 63 100. 00
- 4. 89E-02 5.8 9E-02 5. 89E- 02 871. 10 100. 00 5. 29E- 02 7. 79E- 02 I-131 284. 30 6. 06
- 3. 06E- 01 6. 94E- 02 8. 38E- 0l 364. 48 81. 20
- 1. 06E- 02 6. 94E- 02 636. 97 7. 27 6. 87E- 0l 9. 48E- 0l CS-134 604. 70 97. 60
-5. l0E- 03 7. 30E- 02 8. 14E- 02 795. 84 85. 40
- 2. 56E- 02 7. 30E- 02 CS-137 661. 65 85. 12 1.1 9E- 0l 8. 78E- 02 8. 78E- 02 CE-14 4 80. 12
- 1. 36
- 6. 37E- 01
- 4. 07E- 01 5. 21E+00 133. 51 11.09 l.74 E- 0l 4. 07£- 01 Page S of 6 Tolerance Nuclide
10/19/2020 Page 12 LAC LTP - Final Status Survey Package - 8/14/2019 812312019 2:24:54PM Page 6 of6 Analysis Report for S3-012-1098-FJGS-063-SM S3-012-109 B Nuclide Energy Yield(%)
Activity Nucl/deMDA LlneMDA Name (keV)
(pCi/grams)
(pCl/grams)
(pCUgrams)
+
EU-152 121.78 28. 40
-1. 30E- 01
+
EU-154 123. 07 40.40
-7.40E-02 l. 06E- 01
- 1. 06E-01 723. 30 19. 70 9. 36E- 02 3. 63E- 01 1274.51 35.50
+
EU-155 86. 54 32. 80
-5. 59E-02 1. 81E-Ol 1. 81E-01 105. 31
- 21. 80
- 1. 93E- 01 2. 28E-01
+
BI - 214 609. 31 46. 30 1. 53E-01 1. 24E-Ol l. 24E-01 1120. 29 15. 10 2. 31E-Ol 6.20E-01 1238. 11 5. 94 9. 24E-Ol l.78E+OO 1377. 67 4. 11 5.28E-01 l. 95E+OO 1407. 98 2. 48 9. 41E-01 3.35E+OO 1509.19 2. 19
- 1. 33E+OO 2.75E+OO 1764. 49 15. 80 2. 15£-01 4. 47E-01
+
PB-214 77. 11 10. 70 4. 63E-01 1.33E-01 3. 74E- 01 295.21 19. 20 2. 27E-01 2. 04E-01 351. 92 37. 20 1. 22E-01 1.33E-01
+
PA-228 89.95 22. 00 8. 94£-01 3. 67£-01 6. 41E-01 93. 35 35. 00
- 1. 41E-Ol 3. 67E-01 105.00 16. 30 7. 78£-01 7. 38E-01 129. 22 2. 97
-l. 12E+OO 3. 52E+OO 338. 32 5. 30 2. 26E+OO 2. 49E+OO 463. 00 13. 80 6. 60E- 01 9. 44E- 01 911. 23 16. 70
- 1. 24E+OO 1.26E+OO
+
AM-241 59. 54 36. 30 6. 76E- 02 3. 27E-01 3. 27E- 01
+
CM-243 103.76 23.00 2. llE- 01 2. 17E- 01 2. 17E- 01 228. 18 10. 60 l. 48E-01 4. 17E- 01 277. 60 14. 00 1. 72E- 01 3. 56E- 01
+ = Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> = MDA value not calculated
@ = Half-life too short to be able to perform the decay correction
? = CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level
10/19/2020 Page 13 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:57:47PM pex-Gamma Analysis Report for S3-012-109B-FJGS-064-SM SJ-012-109 B GAMMA SPECTRUM ANALYSIS Sample Identification Sample Descnption Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Tlme Real Tlme Dead Tlme Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- SJ-012-1098-FJGS-064-SM
- S3-012-109 B
- 500 ml Marinelli 8.040E+02 grams
- Dairytand_NPP
- 8/22/2019 1 :12:00PM
- 8/23/2019 2:27:28PM
- 500ml Marinelli
- Administrator
- HOTLAB
- 500ml Marinelli
- 1800.0 seconds
- 1805.4 seconds
- 0.30%
- 3.00
- 100-4096
- 100
- 4096
- 1.000 keV
- 7/8/2014
- 7/8/2014
- 7327 PEAK ANALYSIS REPORT Peak Analysis Performed on
- 8/23/2019 2:57:38PM Peak Analysis From Channel Peak Analysis To Channel
- 100
- 4096 Page I of7
10/19/2020 Page 14 LAC LTP - Final Status Survey Package - 8/14/2019 F
F F
F F
F F
F F
E' E'
8/23/2019 2:57:47PM Page 2 of7 Analysis Report for S3-012-1 098-FJGS-064-SM F
F F
F F
F F
F F
F F
S3-012-109 B Peak Energy ROI No.
(keV) start 1
77. 03 147 -
2 186. 08 369 -
3 238. 53 472 -
4 295. 16 585 -
5 338. 53 674 -
6 351. 79 697 -
7 583. 18 1162 -
8 609. 45 1213 -
9 661. 44 1317 -
10 911. 08 1818 -
11 1460. 78 2914 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 159 377 483 597 681 708 1173 1224 1328 1829 2930 Peak NetPeak Net Area Continuum Centroid Area Uncertainty Counts 154. 61 8. 79E+01 32. 4 9 S. 99E+02 372. 66 3. 42E+01 20. 40 2. SOE+02 477. 54 l. 24E+02
- 31. OS 3. 42E+02 590. 77 5. 07E+Ol
- 21. 66 1. 90E+02 677. 49 l. 80E+Ol 13. 62 8. 63E+Ol 704. 00 9. 55E+Ol 24. 15
- 1. 29E+02 1166. 70 4. 04E+Ol 15. 51 5. 75E+01 1219. 24 4. 62E+Ol 17. 48 6. 61E+Ol 1323. 20 6. 33E+Ol 18. 46 6. 25E+Ol 1822. 40 2. 17E+01 11. 83 3. 60E+Ol 2921. 67 2. 96E+02 34. 51 4. 63E+OO BACKGROUND SUBTRACT REPORT
- 8/23/2019 2;57:38PM Peak Analysis Performed on Env. Background File
- C:\\Canberra\\Apex\\Root\\Dairyland_NPP\\Data\\0000001364.CNF Peak Energy Original Orig. Area Ambient Backgr.
No.
{keV)
Area Uncertainty
Background
Uncert.
1 77. 03 8. 79E+Ol 32. 49 2
186. 08 3. 42E+01 20. 40 3
238. 53 1. 24E+02
- 31. 05 4
295. 16 5. 07E+01
- 21. 66 5
338. 53
- 1. 80E+Ol 13. 62 6
351. 79 9. 55E+Ol 24. 15 4. 18E+Ol l. 86E+Ol 7
583. 18 4. 04E+Ol 15. 51 8
609. 45 4. 62E+Ol 17. 48 2. 06E+Ol
- 1. 21E+Ol 9
661. 44 6. 33E+Ol 18. 46 3. 31E+Ol 1. 27E+Ol 10 911. 08 2. 17E+Ol 11. 83 11 1460. 78 2. 96E+02 34. 51 2. 82E+Ol 8. 57E+OO M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma Subtracted Area 8. 79E+Ol 3. 42E+Ol
- 1. 24E+02 5. 07E+Ol
- 1. 80E+Ol 5. 37E+Ol 4. 04E+Ol 2. 57E+Ol 3. 02E+Ol 2.17E+Ol 2. 67E+02 FWHM (keV)
- 1. 47 0.96 1.50
- 1. 77 0. 99
- 1. 57
- 1. 48
- 1. 91
- 1. 48 1.56 2. 36 Subtracted Uncert.
3. 25E+Ol 2. 04E+01
- 3. llE+Ol 2. 17E+Ol l. 36E+Ol 3. 05E+Ol 1. SSE+Ol 2. 13E+01 2. 24E+01 l. lBE+Ol 3. 56E+Ol
10/19/2020 Page 15 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:57:47PM Page 3 of7 Analysis Report for S3-012-1098-FJGS-064-SM S3-012-109 B NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Dairyland_NPP\\Library\\HOTLAB.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCVgrams)
Uncertainty K-40 1.00 1460. 75 10. 67 7. 25E+OO l. 04E+OO CS-137 0. 99 661. 65 85. 12 5. 08E-02 3. 77E-02 PB-212 0.99 77. 11 17. 50 3. 08E-01
- 1. l 6E-01 238. 63 44. 60 1. 59E-01 4. 07E-02 BI-214 0. 34 609. 31 46. 30 7. 35E-02 6. llE-02 1120. 29 15. 10 1238. 11 5. 94 1377. 67 4. 11 1407. 98 2. 48 1509. 19 2. 19 1764.4 9 15. 80 PB-214 0. 99 77.11 10. 70 5. 04E-01
- 1. 89E-0 1 295. 21 19.20 1. 80E- 01 7. 76E- 02 351. 92 37.20 l.15E- 01 6. 57E-02 RA-226 0. 99 186. 21 3. 28 5. 02E-01 3. 0lE-01
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma INTERFERENCE CORRECTED REPORT
10/19/2020 Page 16 LAC LTP - Final Status Survey Package - 8/14/2019 Analysis Report for S3-012-1098-F JGS-064-SM S3-012-109 B Nuclide Nuclide Name Id Confidence K-40
?
= nuclide is part of an undetermined solution X
= nuclide rejected by the interference analysis 8/23/2019 Wt mean Activity (pCl/grams) 7. 25E+OO 5. 0BE- 02 l. 65E- 01 7. 35E- 02 1.49E- 01 5. 02E- 01
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 2:57:47PM Page 4 of7 Wt mean Comments Activity Uncertainty l. 04E+OO 3. 77E- 02 3. BSE-02 6. llE- 02 4. 87E-02 3. 0lE- 01
10/19/2020 Page 17 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:57:47PM Analysis Report for S3-012-1099-FJGS-064-SM F
F F
+
+
+
+
+
+
+
S3-012-109 B Peak locate Performed on Peak locate From Channel Peak locate To Channel Peak No.
Energy (keV) 5 338. 53 7
583. 18 10 911. 08 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000slgma UNIDENTIFIED PEAKS
- 8/23/2019 2:57:38PM
- 100
- 4096 Peak Size (CPS) l. 00048E-02 2. 24390E-02 l. 20315E-02 Peak CPS{%)
Uncertainty 37. 80 19. 20 27. 31 NUCLIDE MDA REPORT Peak Type Tol.
Tol.
Nuclide library Used
- C:\\Canberra\\Apex\\Root\\Dalryland_NPP\\Library\\HOTLAB.NlB Nuclide Energy Yield(3/4)
Activity NuclideMDA LlneMDA Name (keV)
(pCUgrams)
(pCUgrams)
(pCUgrams)
K-40 1460. 75 10. 67 7. 25E+00 7. 30E- 01 7. 30E-01 AR-41 1293. 64 99. 16
- 4. 62E+0l l. 39E+03 l.39E+03 CO-60 1173. 22 100. 00
-l. 74E- 02 8. 49E-02 l.00E- 01 1332. 49 100. 00 l. 27E- 02 8. 49E-02 KR-85 513. 99 0.4 3 9. 09E+00 l. 63E+0l l. 63E+0l Y-88 898. 04 93. 70
- 5. 4 6E-03 5. 92E-02 6. 59E- 02 1836. 06 99. 20
- 1. 68E- 02 5. 92E- 02 NB-94 702. 63 100. 00
-8. 82E- 03 5. 90E- 02 5. 90E- 02 871. 10 100. 00
- 2. 92E- 02 6. 71E- 02 I - 131 284. 30 6. 06 3. 97E- 01 6. 46E- 02 8. 54E- 01 364. 48
- 81. 20
-7. 81E- 03 6. 46E- 02 Page 5 of7 Tolerance Nuclide AC-228 PA-228 AC-228 PA-228
10/19/2020 Page 18 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:57:47PM Page 6 of7 Analysis Report for S3-01 2-109B-FJGS-064-SM S3-012-109 B Nuclide Energy Yleld(3/4)
Activity NuclldeMDA LlneMDA Name (keV)
(pCilgrams)
(pCi/grams)
(pCi/grams)
I-131 636. 97 7. 27
-1. 0lE- 01 6. 46E-02 8. 90E-01
+
CS-134 604. 70 97. 60
-6. 75E-03 7. 53E-02 7. 53E-02 795. 84 85. 40
- 3. 70£-02 7. 68£-02
+
CS-137 661. 65 85. 12 5. 08£-02 7. 26E- 02 7. 26E- 02
+
CE-144 80. 12
- 1. 36
-l.58E+OO 3. 92E-01 5. lOE+OO 133. 51 11. 09 2. 88E- 02 3. 92E-01
+
EU-152 121. 78 28. 40
-5. 39E-02
- 1. 53E- 01 l. 53E- 01 344. 28 26. 60
-9. 14E- 02 l. 95E-01 1408. 00 20. 74 1. 18£-01 2.80E-01
+
EU-154 123.07 40. 40
- 3. 69E-02 l. 07E-01 1. 07E-01 723. 30 19. 70
- 4. 35E-02 3. 17E-01 1274. 51 35. 50 2. 24E-01 2.70E-01
+
EU-155 86. 54 32. 80
-2. 39E- 02
- 21. 80
- 5. 60E- 02 2. 14E-Ol
+
BI-214 609. 31 46. 30 7. 35E-02 l. 19E-01 l.19E- 01 1120. 29 15. 10
- 1. 63E- 01 6.16E-01 1238. 11 5. 94 5. 94E- 01 1.77E+OO 1377. 67 4. 11
- 1. 14E+OO
- 1. 61E+OO 1407. 98 2. 48 9. 89E- 01 2. 34E+OO 1509. 19 2. 19
-2. 19E-01 2. 26E+OO 1764. 49 15. 80 6. 71E-02 4. 93E-Ol
+
PB-214 77. 11 10. 70 5. 04E- 01 l. 26E- 01 5. 46E-01 295. 21 19. 20
- 1. 80E- 01
- 1. 97E-01 351. 92 37. 20 1.15E- 01 l. 26E- 01
+
PA-228 89. 95 22. 00 3. 04E-Ol 3. 27E- 01 5. 59E-Ol 93. 35 35.00
- 6. 78E-02 3. 27E- 01 105. 00 16. 30 2. 15E- 01 6. 47E-01 129. 22 2. 97
- 6. 35E- 01 3. 24E+OO 338. 32 5. 30 2. 03E- 01 2. 08E+OO 463. 00 13. 80 2. 33E- 01 8. 58E-01 911. 23 16. 70 1. 07E+OO
- 1. 09E+OO
+
AM-2 41 59. 54 36. 30
- 9. 47E- 02 3. 18E-01 3. 18E- 01
+
CM-243 103. 76 23. 00
-3. 05E- 03 2. 05E- 01 2. 05E-Ol 228. 18 10. 60
-3. 76E- 02 4. 21E-Ol 277.60 14. 00
-1.12E- 01 3. 49E-01
+
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
= MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level
10/19/2020 Page 19 LAC LTP - Final Status Survey Package - 8/14/2019 8/23/2019 2:57:47PM Page 7 of7 Analysis Report for S3-012-109B-FJGS-064-SM S3-012-109 B
FSS RELEASE RECORD REVISION 1 STORM DRAIN 2 SURVEY UNIT S3-012-109 B 54 ATTACHMENT 7 GEL LABORATORIES ANALYTICAL REPORTS
~
LACROSSESOLUTIONS
[i]ij* I Laboratories LLc a member of The GEL Group INC PO Bex 30712 Charleston SC 29417 2040 Sa*1a,;ie Road Charleston. SC 29407 P 843 556.8171 F 84:;_766.117B October 13, 2020 Mr. Jason Q. Spaide LaCrosseSolutions S4601 State Hwy 35 Genoa, Wisconsin 54632 Re: LACBWR Site Restoration Project, Level 5 Package Work Order: 521724
Dear Mr. Spaide:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received on September 18, 2020. This original data report has been prepared and reviewed in accordance with GEL's standard operating procedures.
Test results for NELAP or ISO 17025 accredited tests are verified to meet the requirements of those standards, with any exceptions noted. The results reported relate only to the items tested and to the sample as received by the laboratory. These results may not be reproduced except as full reports without approval by the laboratory.
Copies of GEL' s accreditations and certifications can be found on our website at www.gel.com.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (843) 556-8171, ext. 4453.
Purchase Order: 672583 Enclosures Sincerely, Edith Kent Project Manager gel. com
Table of Contents Case Narrative....................................................................................3 Chain of Custody and Supporting Documentation.........................5 Laboratory Certifications..................................................................8 Radiological Analysis.......................................................................10 Case Narrative..........................................................................11 Sample Data Summary............................................................28 Quality Control Summary.......................................................53
Case Narrative Page 1 of 58 SDG: 521724
Page 2 of 58 SDG: 521724 October 13, 2020 Laboratory Identification:
GEL Laboratories LLC 2040 Savage Road Case Narrative for LaCrosseSolutions, LLC (672583)
SDG: 521724 Charleston, South Carolina 29407 (843) 556-8171 Summary Sample Receipt The samples arrived at GEL Laboratories LLC, Charleston, South Carolina on September 18, 2020 for analysis. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any visible signs of tampering or breakage. There are no additional comments concerning sample receipt.
Sample Identification The laboratory received the following samples:
Laboratory ID Client ID 521724001 Ll-SUB-TDS-CJGS-B0 1-SB 521724002 Ll-SUB-TDS-CJGS-B02-SB 521724003 Ll-SUB-TDS-CJGS-B04-SB 521724004 Ll-SUB-TDS-CJGS-B05-SB 521724005 Ll-SUB-TDS-CJGS-B07-SB 521724006 S3-012-109B-FJGS-062-SM 521724007 S3-012-109B-FJGS-063-SM 521724008 S3-012-109B-FJGS-064-SM Case Narrative Sample analyses were conducted using methodology as outlined in GEL Laboratories, LLC (GEL)
Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package.
Data Packaz:e The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, and data from the following fractions: Radiochemistry.
GEL Laboratories LLC Edith Kent Project Manager PO Box 30712 Char1eston, SC 29417 2040 Savage Road Charleston, SC 29407 P 843.556.8171 F 843.766.1178 www.gel.com
Chain of Custody and Supporting Documentation Page 3 of 58 SDG: 521724
Page 4 of 58 SDG: 521724 Page: ___ ! ___ of ___ l----J Project II LACBWR Site GEL Quote #: -------- - - -
---l tft #\\! I ~~£? ~~!eSrl ~Ra~~~l£y I Specialfy Anal~ics COC Number Cl>:
PO Number: 6725--:8:::3---------t;:G;;E;;L7,J;;;-V.or7,k:--O::::--rd7e'.'."r-;N.:;,u""in..,b:-e""'r'.'."f" --,:,:.:.:;:::,:,::,..::;:..;.==~;:,::;.,:.;_:~=::=.~:!:!.!!::::'.!.,.,,,,,, ________ ~
Client Name: La Crosse Solutions P
Project/Site Name: LACBWR-Genoa WI
,0 UJ z
N it ci "'
t i:!
'°
-i' 8
~ u UJ
'° sf z
~
UJ z a LI-SUB-TDS-CJGS-B02,SB LI-SUB-TDS-CJGS-B04-SB LI-SUB, TDSCCJGSCBOS-SB Relinquished By (Signed)
I, Kevin L Murra 9/ 17/2020 l2-3t>
2 GEL Laboratories, LLC 2040 Savage Road 00 0
M ST
~*
N N
e t
t
~ °'
st
'c1.
N N
t E
z 521'72-f-t 3
Use 011/y: Custody Seal Intact? [ ] Yes
[ ] No r
'),¢epiraJ ** *"
1 I.) Chain of Custody Number "" Client Determined 2.) QC Codes: N,,, Normal Sample. TB= Trip Blank. FD= Field Duplicate, EB= Equipment Blank. MS= Matrix Spike Sample. MSO = Matrix Spike Duplicate Sample, G = Grab, C = Composite 3.) Field Fihen.-d: For liquid matrices, indicate with a - Y - for yes the sample was field filtaedor-N- forsamplc1,1,'3S not field filtered.
4.) Matrix CO<ks: OW=Drinking Water, GW:=Groundwater, SW"'-Surface Water, WW=Wastc Water, W=Watcr. l\\'IL=Misc Liquid, SO=Soil, SD=Sedimcnt. SL=Sludge, SS=Solid Waste, (FQil, F=Filtcr. P,:,:\\Vipe. U=Urine. F=Fro1t, N=Nasal 5.) Sample Analysis Requested: Analytical mdhod requested (i.e. 82608, 6010017470A} and number of containers provided for each (i.e. 82608 v 3, 6010B/7470A - I).
6,) Pre:sa.*ativc Type HA = Hydrochloric Acid. N1 = Nitric Acid, SH = Sodium Hydroxide. SA = Sulfuric Acid, AA = Ascorbic Acid. HX "" Ho:ane. ST=== Sodium Thiosulfa!c_. lf no preservative is addc.d =- leave field blank 7,)
Page 5 of 58 SDG: 521724
~ mJ Ldioralo(es ur SAMPLE RECEIPT & REVIEW FORM Client:
SDG/AR/COC/Work Order. i
~. L / 7 2 Li Received B :
Date Received:
~
CC':k Ap:,li~blc:
( - Fcdfa faprc>>
!)edEx Grnund UPS Field Service; Courier Other Carrier and Tracking Num!Jcr Suspected Ha an! Infom1otion J!
- ,E 11[f Nl!t Counts> lOOcpm on sampll!S not m.1.rk.cd.. r.idio:ictivc:". cont:tet thi: R.idi~ion S3futy Group for furtl1\\!r inv~ ig:1tio11.
Haz:ird Class Shipped:
UN#:
V
[f UN29 IO. Ls the Radioactive Shipment Survey Compliant? Y ts_ No_
A)Shioood as * 'lOT H.lzardous?
ii'
,/
COC not3tio1t orradio.1ctivc stickers on com:Uncrs equ:ll client designation.
{
- 8) Did the clic:n dl!Sig:11ate the sampli:s an: to~
rccciwd as rad.ir :ictivt1 C) Did th< RSO l:,,.ssify the sampks,s t3tlio:ictivc'/
/
Ma.,imum Net Counts Ol>scrvcd' (Ol>scrvcd Coums - All!> Background Coums):
( f) CPM / mR/Hr Clossilicd as: Rad I Rod 2 Rad 3 D) Did the clitut Ui!sil!l1atc.: s:unr,ks.11"1.! h:iz:utlous'/ I./ CJC notation orh:it:trd l;ibels 011 a,nt:U11<::rs equ:1.I cli~11t d:sig1:1:itio11.
El Did the RSO it *11tifv oossiblc haz.mls?
./
f Dor Eis yes. sdect Hoz:uus b.!low.
PCB's A:unmoblc fo1\\!ign Soil RCRA Asb.!stos BcryUium Other.
Samp c R.ccci(lt Critcri:.:a
!}.
~ Z CommcnLqQu!llificrs (Required for Non*Conf'om1i11g ltcn1s) 1 Shipping co taincrs rci:ci vcd inlact and sc:llcd?
~.:;:
Circle Appli~bl>!:
Sc3ls brok1.:n Q3m3scd cont.liner L.c3king contlincr Other (describe) vJ 2
Chain of cui lldy d\\lcumenB included
~V ~ ;
!Circle Appticlbfc:
Cti<!nl con1:ic1eJ 3nd pro\\iJed COC COC crc31cd upon receipt t--1-w_i_1h_~_*1~ip~m_e,+?---------~
.:ft_
---=---
3 Samples rcqu ring cold preservation
~rv:ition Mi:thod: Wi:t (Cl!
Ice P:tcks Dr)' io.f None ) Othi:r.
TEMP:/!/ ~
V
"'all tcmf)-:r.atun:s :ire n:co,tl~d in Celsius
'-.-,./
within (0 < 6 ~e~. C)?*
i----t--===-e-F'"'-'=-------1--4.-J;':1!--jr.;::-=====.....,;--;-;-;i===== = =---------------'-----+---~
4 Daily check p ~rforo-,,,d and pa.sscd on IR
.*. ~
Temperature Device Serial 'lli@!IB$:id:9~
tcmpcrJture g n?
""' i-;t-St!cond:uy Tt!Jl\\(>.:l';UUI\\! D..:vitt Si:rfal # ([f Appticiblc):
t-5-t*S--a,-n-p-lc_c_*o_n_l_:ti+-c-r;_i_n_ta_c_t -a-n,-1-Sc-*a-* lc_d_*.!--.1..V~
. -lfr.J}f--i;::c:-:irc::!-:-c -:A-:-pp::U;-.c::,b-:k:-:*:-;Sc:c,-:l,-* b;-r-o:-kl!-n--:::Dc-,-111-,~-,c-:d-c-o,-u,'"'i.,.nc""r-L,:-*,"°kU:-,-S-<O-n-,a-,in_c_r _O"'t""hc-*,-(..,dc-,-cn-,*b-c-) ---------~---!
i~ -
6 Samples rcquir ng chemical prcscrvat ion
/
SJmpl:: iD"s 311d Con1:1incrs,\\ffcclt.id:
at proper pH?
\\/
r--1------+----------+--l.. *:/--f,17 rP~r::-c,:'c-'::":::~~,io;cn~*=J!!.dc:;*J":.!:l.o~*:.i:.:;-* =----::--::-:--:-:-:---:c:---:-:-.,--c-:---------**::.__.:. __ -4._~_j JJ
[f Y,:s, ore Encores or Soil Kits ptl!,Olll for solids? Yos No NA
([f yes, t:tlo: to VOA Fn:oz,er) 7 Du any s:10 lolesrequirc Volatile Analysis?
8 Samples rci:civl! within holding timt!?
Sample [D's on C OC ntllch [D's on 9 llottlcs?
~f I J/o l'.qu'.d ~OA v'.ols cont:ii11 oci<l prcscrvatio11? Yes No NA (If unknown, s-,ioa No)
-i/i V :\\n: hqu,d QA s1Jls f11:c ofheadspocc? Yes_ No_ NA_
~j~
!ilmplc ID':. aniJ cont.,incr:. j((cctcd:
~t lD's :iuct tl!Sts :Ufoctl!d:
lD's :Uld conlainc,s 3ffl!ctc<l:
10 Date & tirre on COC 1m1d1 d:itc & lime on bottles?
Ciit:ll! Applic:iUh:: No <btcs 011 cont:tin..:rs No tim..:s on cont:Unt.!rs COC mis.sin~ info Othl!r (di:scritx:)
11 Number of conrai ers recei vcd match
- v,;;;
Circle Applicable: No cmn:tini::r counl on COC Otl1,:r (di:sciib.!)
numllcr indicated bn COC'!
f\\
/
t---t-:------,---,;~----~
,,J*,l!,,.,1,L------------------------------1--1 12 Arc ;ample con1:u crs idcnli liable a;
~!,v" GEL orovided b1* se of GEL labels?
ftii:
13 COC form is prop rly signed in V ~
Circle Applic.,blc:
rclinqui~1ed/rccci, *d section;'!
Comments (Us* Co11tinuo ion Form if neodod):
PM (m* PMAl 1\\!vicw: lniti:tls _ M ~
Not n:linquishod Other (d,scxib.!)
1 GL-CHL-SR-OOt REs_v 1/4
Laboratory Certifications Page 6 of 58 SDG: 521724
Page 7 of 58 SDG: 521724 List of current GEL Certifications as of 13 October 2020 State Certification Alabama 42200 Alaska 17-018 Alaska Drinking Water SC00012 Arkansas 88-0651 CLIA 42D0904046 California 2940 Colorado SC00012 Connecticut PH-0169 DoD ELAP/ ISOl 7025 A2LA 2567.01 Florida NELAP E87156 Foreign Soils Permit P330-15-00283,P330-15-00253 Georgia SC00012 Georgia SDW A 967 Hawaii SC00012 Idaho SC00012 Illinois NELAP 200029 Indiana C-SC-01 Kansas NELAP E-10332 Kentucky SDW A 90129 Kentucky Wastewater 90129 Louisiana Drinking Water LA024 Louisiana NELAP 03046 (AI33904)
Maine 2019020 Maryland 270 Massachusetts M-SC012 Massachusetts PF AS Approv Letter Michigan 9976 Mississippi SC00012 Nebraska NE-OS-26-13 Nevada SC000122020-1 New Hampshire NELAP 2054 New Jersey NELAP SC002 New Mexico SC00012 New York NELAP 11501 North Carolina 233 North Carolina SDWA 45709 North Dakota R-158 Oklahoma 2019-165 Pennsylvania NELAP 68-00485 Puerto Rico SC00012 S. Carolina Radiochem 10120002 Sanitation Districts of L 9255651 South Carolina Chemistry 10120001 Tennessee TN 02934 TexasNELAP T104704235-20-17 UtahNELAP SC000122020-32 Vermont VT87156 Virginia NELAP 460202 Washington C780
Radiological Analysis Page 8 of 58 SDG: 521724
Case Narrative Page 9 of 58 SDG: 521724
Page 10 of 58 SDG: 521724 Radiochemistry Technical Case Narrative LaCrosseSolutions, LLC SDG #: 521724 Product: Alphaspec Isotopic Am241 Am243, Cm243/244, Solid Analytical Method: DOE EML HASL-300, Am-05-RC Modified Analytical Procedure: GL-RAD-A-011 REV# 28 Analytical Batch: 2042096 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB L l-SUB-TDS-CJGS-B02-SB L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204646784 1204646785 1204646786 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Quality Control (OC) Information Tracer/Carrier Yield The Cm-244 traced portion of sample, (see below), did not meet the client's yield requirement due to the matrix of the sample; however, the combined Am-243 & Cm-244 traced yields do meet the requirement.
Sample Analyte Value 521724004 (Ll-SUB-TDS-CJGS-B05-SB) Curium-243/244 Tracer 14.2* (15%-125%)
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Page 11 of 58 SDG: 521724 Sample Value 1204646785 (L 1-SUB-TDS-CJGS-B0 1-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Recounts The Cm-244 traced portion of sample 521724004 (Ll-SUB-TDS-CJGS-B05-SB) was recounted due to low tracer yield. The recount is reported. The Am-243 and Cm-244 traced portions of sample 1204646784 (MB) were recounted due to peak shifts. The recounts are reported.
Miscellaneous Information Additional Comments Sample 521724008 (S3-012-109B-FJGS-064-SM) did not meet the resolution requirement of having a full width half maximum of 100 keV or less for the Am-243 tracer; however, the tracer yield requirement was met and the tracer peak is within the tracer region of interest.
Product: Alphaspec Np, Solid Analytical Method: ASTM C 1475-00 Modified Analytical Procedure: GL-RAD-A-069 REV# 0 Analytical Batch: 2042097 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204646787 1204646788 Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB L l-SUB-TDS-CJGS-B02-SB L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB) 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Page 12 of 58 SDG: 521724 1204646789 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204646788 (Ll-SUB-TDS-CJGS-B0 1-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0I-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Recounts Samples 1204646788 (Ll-SUB-TDS-CJGS-B0I-SBDUP) and 1204646789 (LCS) were recounted to verify sample results. Recounts are reported. Sample 521724003 (Ll-SUB-TDS-CJGS-B04-SB) was recounted due to a suspected false positive. The recount is reported.
Product: Alphaspec Pu238, 239/240, Solid Analytical Method: DOE EML HASL-300, Pu-11-RC Modified Analytical Procedure: GL-RAD-A-011 REV# 28 Analytical Batch: 2042098 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
521724001 521724002 Client Sample Identification Ll-SUB-TDS-CJGS-B0 I-SB Ll-SUB-TDS-CJGS-B02-SB
Page 13 of 58 SDG: 521724 L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB) 521724003 521724004 521724005 521724006 521724007 521724008 1204646790 1204646791 1204646792 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204646791 (Ll-SUB-TDS-CJGS-B0 1-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Product: Dry Weight Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
521724001 521724002 521724003 Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB Ll-SUB-TDS-CJGS-B02-SB Ll-SUB-TDS-CJGS-B04-SB
Page 14 of 58 SDG: 521724 521724004 521724005 521724006 521724007 521724008 L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable.
Product: Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 Analytical Method: DOE HASL 300, 4.5.2.3/Ga-01-R Analytical Procedure: GL-RAD-A-013 REV# 27 Analytical Batch: 2042160 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204646946 1204646947 1204646948 Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB L l-SUB-TDS-CJGS-B02-SB L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB) 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Quality Control (OC) Information Duplication Criteria between QC Sample and Duplicate Sample The Sample and the Duplicate, (See Below), did not meet the relative percent difference requirement; however, they do meet the relative error ratio requirement with the value listed below.
Page 15 of 58 SDG: 521724 Sample Analyte Value 120464694 7 (L 1-SUB-TDS-CJGS-B0 1-SBDUP) Cesium-137 RPD 21.9* (0.00%-20.00%) RER 0.966 (0-3)
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204646947 (Ll-SUB-TDS-CJGS-B0l-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Qualifier Information Qualifier Reason Analyte Sample Client Sample Results are considered a Ul false positive due to low abundance.
Europium-155 521724002 Ll-SUB-TDS-CJGS-B02-SB Product: Gamma Ni59, Solid Analytical Method: DOE RESL Ni-1 Analytical Procedure: GL-RAD-A-022 REV# 19 Analytical Batch: 2044929 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
521724001 521724002 Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB L l-SUB-TDS-CJGS-B02-SB
Page 16 of 58 SDG: 521724 L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB) 521724003 521724004 521724005 521724006 521724007 521724008 1204653141 1204653142 1204653143 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204653142 (Ll-SUB-TDS-CJGS-B0l-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Product: GFPC, Sr90, Solid Analytical Method: EPA 905.0 Modified/DOE RP501 Rev. 1 Modified Analytical Procedure: GL-RAD-A-004 REV# 21 Analytical Batch: 2042511 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073
Page 17 of 58 SDG: 521724 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 I-SB L l-SUB-TDS-CJGS-B02-SB L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204647797 1204647798 1204647799 521724005(Ll-SUB-TDS-CJGS-B07-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Preparation Information Homogenous Matrix Samples were non-homogenous matrix. Sand Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 120464 7798 (Ll-SUB-TDS-CJGS-B07-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Recounts Sample 1204647799 (LCS) was recounted due to high recovery. The recount is reported. Sample 521724002 (Ll-SUB-TDS-CJGS-B02-SB) was recounted due to a suspected false positive. The recount is reported.
Page 18 of 58 SDG: 521724 Product: Liquid Scint Pu241, Solid Analytical Method: DOE EML HASL-300, Pu-11-RC Modified Analytical Procedure: GL-RAD-A-035 REV# 21 Analytical Batch: 2042099 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB Ll-SUB-TDS-CJGS-B02-SB Ll-SUB-TDS-CJGS-B04-SB Ll-SUB-TDS-CJGS-B05-SB Ll-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204646793 1204646794 1204646795 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204646794 (Ll-SUB-TDS-CJGS-B0l-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20
Page 19 of 58 SDG: 521724 Recounts Samples 521724002 (Ll-SUB-TDS-CJGS-B02-SB) and 521724003 (Ll-SUB-TDS-CJGS-B04-SB) were recounted due to a suspected false positive. The recounts are reported.
Product: Liquid Scint Fe55, Solid Analytical Method: DOE RESL Fe-1, Modified Analytical Procedure: GL-RAD-A-040 REV# 13 Analytical Batch: 2042294 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB Ll-SUB-TDS-CJGS-B02-SB Ll-SUB-TDS-CJGS-B04-SB Ll-SUB-TDS-CJGS-B05-SB Ll-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204647266 1204647267 1204647268 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 120464 7267 (Ll-SUB-TDS-CJGS-B0 1-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19
Page 20 of 58 SDG: 521724 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Product: Liquid Scint Ni63, Solid Analytical Method: DOE RESL Ni-I, Modified Analytical Procedure: GL-RAD-A-022 REV# 19 Analytical Batch: 2042296 Preparation Method: Dry Soil Prep Preparation Procedure: GL-RAD-A-021 REV# 24 Preparation Batch: 2042073 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB L l-SUB-TDS-CJGS-B02-SB L l-SUB-TDS-CJGS-B04-SB L l-SUB-TDS-CJGS-B05-SB L l-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204647269 1204647270 1204647271 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204647270 (Ll-SUB-TDS-CJGS-B0l-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0I-SB)
Received 18-SEP-20, out of holding 28-NOV-19
Page 21 of 58 SDG: 521724 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Product: Liquid Scint C14, Solid Analytical Method: EPA EERF C-01 Modified Analytical Procedure: GL-RAD-A-003 REV# 16 Analytical Batch: 2046296 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 I-SB Ll-SUB-TDS-CJGS-B02-SB Ll-SUB-TDS-CJGS-B04-SB Ll-SUB-TDS-CJGS-B05-SB Ll-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204656258 1204656259 1204656260 1204656261 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP) 521724001(Ll-SUB-TDS-CJGS-B01-SB) Matrix Spike (MS)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204656259 (Ll-SUB-TDS-CJGS-B0I-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 1204656260 (Ll-SUB-TDS-CJGS-B0I-SBMS)
Received 18-SEP-20, out of holding 28-NOV-19
Page 22 of 58 SDG: 521724 521724001 (Ll-SUB-TDS-CJGS-B0I-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Product: LSC, Tritium Distillation, Solid Analytical Method: EPA 906.0 Modified Analytical Procedure: GL-RAD-A-002 REV# 23 Analytical Batch: 2046317 The following samples were analyzed using the above methods and analytical procedure(s).
Client Sample Identification Ll-SUB-TDS-CJGS-B0 I-SB Ll-SUB-TDS-CJGS-B02-SB Ll-SUB-TDS-CJGS-B04-SB Ll-SUB-TDS-CJGS-B05-SB Ll-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB)
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204656318 1204656319 1204656320 1204656321 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP) 521724001(Ll-SUB-TDS-CJGS-B01-SB) Matrix Spike (MS)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Sample Value 1204656319 (Ll-SUB-TDS-CJGS-B0I-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19
Page 23 of 58 SDG: 521724 1204656320 (Ll-SUB-TDS-CJGS-B0l-SBMS)
Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Recounts Sample 1204656320 (Ll-SUB-TDS-CJGS-B0l-SBMS) was recounted due to low recovery. The recount is reported.
Product: Liquid Scint Tc99, Solid Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Procedure: GL-RAD-A-059 REV# 5 Analytical Batch: 2047687 The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
521724001 521724002 521724003 521724004 521724005 521724006 521724007 521724008 1204659473 1204659474 1204659475 Client Sample Identification Ll-SUB-TDS-CJGS-B0 1-SB Ll-SUB-TDS-CJGS-B02-SB Ll-SUB-TDS-CJGS-B04-SB Ll-SUB-TDS-CJGS-B05-SB Ll-SUB-TDS-CJGS-B07-SB S3-012-109B-FJGS-062-SM S3-012-109B-FJGS-063-SM S3-012-109B-FJGS-064-SM Method Blank (MB) 521724001(Ll-SUB-TDS-CJGS-B01-SB) Sample Duplicate (DUP)
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions.
Technical Information Holding Time Samples (See Below) were received and analyzed outside the hold time.
Page 24 of 58 SDG: 521724 Sample Value 12046594 74 (L 1-SUB-TDS-CJGS-B0 1-SBDUP) Received 18-SEP-20, out of holding 28-NOV-19 521724001 (Ll-SUB-TDS-CJGS-B0l-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724002 (Ll-SUB-TDS-CJGS-B02-SB)
Received 18-SEP-20, out of holding 30-NOV-19 521724003 (Ll-SUB-TDS-CJGS-B04-SB)
Received 18-SEP-20, out of holding 15-NOV-19 521724004 (Ll-SUB-TDS-CJGS-B05-SB)
Received 18-SEP-20, out of holding 26-NOV-19 521724005 (Ll-SUB-TDS-CJGS-B07-SB)
Received 18-SEP-20, out of holding 28-NOV-19 521724006 (S3-012-109B-FJGS-062-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724007 (S3-012-109B-FJGS-063-SM)
Received 18-SEP-20, out of holding 18-FEB-20 521724008 (S3-012-109B-FJGS-064-SM)
Received 18-SEP-20, out of holding 18-FEB-20 Sample Re-prep/Re-analysis Samples were reprepped due to the quench number being outside the calibration range. The re-analysis is being reported.
Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com ENRG070 LaCrosseSolutions, LLC (672583)
Client SDG: 521724 GEL Work Order: 521724 GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverables receive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
UI Gamma Spectroscopy--Uncertain identification h Preparation or preservation holding time was exceeded for Qualifier Definition Report Signature:
Name:
Date:
Title:
16 OCT 2020 Theresa Austin Group Leader Review/Validation Page 25 of 58 SDG: 521724
Sample Data Summary Page 26 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1417 0906 1830 0910 1101 1359 0628 0438 1141 1217 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/10/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/24/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724001 Misc Solid 01-JUN-19 12:23 18-SEP-20 L1-SUB-TDS-CJGS-B01-SB ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0191
+/-0.0192
+/-0.0134
+/-0.00348
+/-0.0126
+/-0.0104
+/-1.77
+/-1.25
+/-0.0275
+/-0.0178
+/-0.0325
+/-0.0473
+/-0.0389
+/-0.0105
+/-0.107
+/-4.22
+/-2.09
+/-0.946
+/-5.08 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.0311 0.0370 0.0337 0.00512 0.0219 0.0217 2.95 2.13 0.0218 0.0376 0.0647 0.111 0.0781 0.0224 0.229 7.26 3.62 1.67 7.03 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh Hh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.0107 0.00521
-0.00296 0.00267 0.00459 0.000994 1.88 0.0709 0.139 0.00459
-0.00733 0.0542 0.0104 0.00576
-0.141 1.66
-0.470
-0.958
-1.41 Uncertainty Page 27 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0539 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724001 L1-SUB-TDS-CJGS-B01-SB ENRG07002 Project:
ENRG070 Client ID:
+/-2.14 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.72 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.0490 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 68 73.2 84.5 74.6 74.6 91.3 63 96.2 57.3 81.8 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 28 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724001 L1-SUB-TDS-CJGS-B01-SB ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 29 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1417 0906 1407 0911 1558 1030 0730 0529 1218 1424 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/12/20 09/28/20 09/21/20 10/08/20 10/09/20 10/08/20 10/11/20 09/24/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724002 Misc Solid 03-JUN-19 09:34 18-SEP-20 L1-SUB-TDS-CJGS-B02-SB ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0167
+/-0.0131
+/-0.0153
+/-0.00283
+/-0.0189
+/-0.0217
+/-2.09
+/-1.53
+/-0.0299
+/-0.0292
+/-0.0710
+/-0.0694
+/-0.204
+/-0.0181
+/-0.153
+/-3.81
+/-2.01
+/-0.880
+/-5.29 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.0271 0.0319 0.0299 0.00390 0.0398 0.0308 3.63 2.45 0.0718 0.0595 0.153 0.133 0.182 0.0444 0.258 6.80 3.44 1.54 7.26 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUIh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.00839
-0.00190 0.00341 0.00204 0.00160 0.0167
-0.236
-1.23 0.0474
-0.00474 0.0594
-0.0294 0.000 0.0173 0.124
-1.54 0.486
-0.654 0.478 Uncertainty Page 30 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0555 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724002 L1-SUB-TDS-CJGS-B02-SB ENRG07002 Project:
ENRG070 Client ID:
+/-2.30 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.93 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.893 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 75.1 65.6 84.4 58.9 58.9 103 45.7 98 58.6 77.4 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 31 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724002 L1-SUB-TDS-CJGS-B02-SB ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 32 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1548 0906 1454 0912 1558 1359 0832 0620 1255 1631 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/12/20 10/09/20 10/12/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/24/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724003 Misc Solid 19-MAY-19 10:04 18-SEP-20 L1-SUB-TDS-CJGS-B04-SB ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0168
+/-0.0187
+/-0.0154
+/-0.00390
+/-0.0174
+/-0.0181
+/-1.67
+/-1.49
+/-0.0515
+/-0.0241
+/-0.0381
+/-0.0760
+/-0.0637
+/-0.0170
+/-0.152
+/-4.14
+/-2.11
+/-0.936
+/-5.86 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.0228 0.0489 0.0186 0.00623 0.0237 0.0363 2.87 2.82 0.0393 0.0354 0.0750 0.172 0.132 0.0409 0.286 7.15 3.63 1.62 8.32 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh Hh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.0123
-0.00424 0.0107 0.00159 0.0127 0.00338 0.530
-0.178 0.0909
-0.0255
-0.0187 0.0238 0.0243 0.0175
-0.0217 1.15
-0.0598
-0.190
-2.61 Uncertainty Page 33 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0612 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724003 L1-SUB-TDS-CJGS-B04-SB ENRG07002 Project:
ENRG070 Client ID:
+/-2.05 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.57 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected"
-0.104 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 72.2 40 81.7 81.4 81.4 94.3 47.8 95.5 43.7 84.7 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 34 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724003 L1-SUB-TDS-CJGS-B04-SB ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 35 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1418 0906 2049 0912 1559 1359 0935 0712 1333 1837 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/10/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/24/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724004 Misc Solid 30-MAY-19 15:18 18-SEP-20 L1-SUB-TDS-CJGS-B05-SB ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0693
+/-0.0550
+/-0.0376
+/-0.00260
+/-0.0140
+/-0.0174
+/-1.82
+/-1.59
+/-0.0936
+/-0.0348
+/-0.0721
+/-0.0848
+/-0.0738
+/-0.0218
+/-0.116
+/-5.22
+/-2.01
+/-1.09
+/-6.61 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.113 0.122 0.0980 0.00449 0.0243 0.0189 3.05 2.95 0.0385 0.0764 0.125 0.163 0.154 0.0460 0.212 9.11 3.57 1.91 9.13 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh Hh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.0349 0.000742
-0.00849 0.000937 0.00509 0.0148 1.65 0.885 0.615 0.0137
-0.0222
-0.0265 0.0441 0.0105 0.0219 0.378
-2.42
-0.640 0.0527 Uncertainty Page 36 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0628 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724004 L1-SUB-TDS-CJGS-B05-SB ENRG07002 Project:
ENRG070 Client ID:
+/-2.12 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.68 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.254 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 15.5 14.2 90.6 76.6 76.6 85.3 63 87.3 51.6 82.3 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 37 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724004 L1-SUB-TDS-CJGS-B05-SB ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 38 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1418 0912 2136 1035 1559 1400 1037 0803 1410 2044 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/10/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/24/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724005 Misc Solid 01-JUN-19 10:09 18-SEP-20 L1-SUB-TDS-CJGS-B07-SB ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0260
+/-0.0319
+/-0.0317
+/-0.00296
+/-0.0189
+/-0.0127
+/-1.66
+/-1.23
+/-0.157
+/-0.0411
+/-0.0754
+/-0.0997
+/-0.0831
+/-0.0227
+/-0.129
+/-4.53
+/-2.07
+/-0.924
+/-5.30 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.0578 0.0666 0.0503 0.00482 0.0276 0.0321 2.85 2.20 0.0577 0.0927 0.147 0.174 0.163 0.0474 0.237 7.73 3.51 1.63 7.40 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh Hh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.000351 0.00305 0.0138 0.00151 0.0127
-0.00282 0.509 0.502 1.86 0.0262 0.0325
-0.0725 0.0102 0.00737 0.0246 2.66 1.05
-0.745
-3.44 Uncertainty Page 39 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0644 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724005 L1-SUB-TDS-CJGS-B07-SB ENRG07002 Project:
ENRG070 Client ID:
+/-2.10 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.62 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.678 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 32.5 32.8 86.1 74.3 74.3 92.1 50 94.3 56.2 84.3 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 40 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724005 L1-SUB-TDS-CJGS-B07-SB ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 41 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1418 0912 2222 1036 1605 1405 1140 0854 1447 2250 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/10/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/24/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724006 Misc Solid 22-AUG-19 10:05 18-SEP-20 S3-012-109B-FJGS-062-SM ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0483
+/-0.0485
+/-0.0253
+/-0.00244
+/-0.00821
+/-0.0151
+/-1.61
+/-1.88
+/-0.0318
+/-0.0250
+/-0.0639
+/-0.125
+/-0.0836
+/-0.0210
+/-0.109
+/-4.02
+/-2.11
+/-0.982
+/-5.16 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.0784 0.0949 0.0586 0.00389 0.0253 0.0311 2.77 3.11 0.0653 0.0604 0.117 0.252 0.180 0.0401 0.228 7.19 3.58 1.73 7.11 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.0243 0.0108
-0.00293 0.00102
-0.00433 0.00215 0.331
-1.09 0.00766 0.00570
-0.0617
-0.00589 0.0507
-0.00710
-0.0520
-1.80 1.01
-0.968
-0.387 Uncertainty Page 42 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0701 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724006 S3-012-109B-FJGS-062-SM ENRG07002 Project:
ENRG070 Client ID:
+/-1.85 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.31 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected"
-1.24 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 24.4 28.3 86.1 80.6 80.6 85.3 45.7 89.1 57.1 91.2 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 43 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724006 S3-012-109B-FJGS-062-SM ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 44 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0912 1418 0912 2309 1037 1559 1405 1242 0945 1524 0057 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/10/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/25/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724007 Misc Solid 22-AUG-19 10:14 18-SEP-20 S3-012-109B-FJGS-063-SM ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0550
+/-0.0262
+/-0.0360
+/-0.00374
+/-0.0128
+/-0.00838
+/-1.59
+/-1.72
+/-0.0298
+/-0.0257
+/-0.0621
+/-0.0835
+/-0.0627
+/-0.0217
+/-0.0917
+/-4.29
+/-2.09
+/-0.942
+/-4.47 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.115 0.0684 0.0876 0.00579 0.0311 0.0290 2.62 2.94 0.0437 0.0523 0.131 0.150 0.125 0.0394 0.179 7.44 3.55 1.66 6.10 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh Hh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.00461
-0.00593
-0.00521 0.00242
-0.00297
-0.00803 2.39
-1.52 0.0497
-0.00453 0.0260
-0.0492 0.0191
-0.00882 0.00544 0.805 0.784
-0.851 0.125 Uncertainty Page 45 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0717 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724007 S3-012-109B-FJGS-063-SM ENRG07002 Project:
ENRG070 Client ID:
+/-2.06 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.57 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected" 0.335 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 24.1 30 74.4 83.1 83.1 84.8 52.2 88.3 66.8 85.1 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 46 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724007 S3-012-109B-FJGS-063-SM ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 47 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Liquid Scintillation Analysis 2042096 2042097 2042098 2042099 2044929 2042160 2042511 2046317 2046296 2047687 2042294 0919 2023 0912 2355 1037 1600 1405 1345 1037 1601 0537 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/09/20 10/10/20 10/09/20 10/10/20 09/28/20 09/21/20 10/07/20 10/09/20 10/08/20 10/11/20 09/25/20 BXA4 BXA4 BXA4 BXA4 RP1 MXR1 LXB3 TXJ1 EW3 JJ3 RP1 0.400 0.400 0.400 0.0100 0.400 0.400 5.00 5.00 1.00 0.400 10.0 5.00 2.00 10.0 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724008 Misc Solid 22-AUG-19 13:12 18-SEP-20 S3-012-109B-FJGS-064-SM ENRG07002 Project:
ENRG070 Client ID:
Client
+/-0.0535
+/-0.0506
+/-0.0449
+/-0.00246
+/-0.00967
+/-0.0125
+/-1.64
+/-1.62
+/-0.0389
+/-0.0378
+/-0.0652
+/-0.137
+/-0.0839
+/-0.0289
+/-0.119
+/-3.99
+/-2.08
+/-0.979
+/-4.91 Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
0.122 0.106 0.0832 0.00522 0.0308 0.0305 2.78 2.59 0.0912 0.0678 0.119 0.273 0.165 0.0517 0.195 7.15 3.57 1.73 6.80 1
2 3
4 5
6 7
8 9
10 11 HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HUh HU HU HU HUh Americium-241 Americium-243 Curium-243/244 Neptunium-237 Plutonium-238 Plutonium-239/240 Plutonium-241 Nickel-59 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Strontium-90 Tritium Carbon-14 Technetium-99 Iron-55 Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" Gamma, Cs137, Co60, Nb94, Eu152, Eu154, Eu155 "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" LSC, Tritium Distillation, Solid "As Received" Liquid Scint C14, Solid "As Received" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected"
-0.00738 0.00484 0.0131
-0.000725
-0.00600
-0.00182 1.03
-0.747 0.0881
-0.0208
-0.0336 0.100 0.0172 0.00475 0.122
-1.87 0.267
-1.04
-2.65 Uncertainty Page 48 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Rad Liquid Scintillation Analysis 2042296 0733 pCi/g 09/24/20 RP1 5.00 Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724008 S3-012-109B-FJGS-064-SM ENRG07002 Project:
ENRG070 Client ID:
+/-1.78 Sample ID:
Client Sample ID:
Surrogate/Tracer Recovery Recovery%
Test Acceptable Limits 3.15 12 HUh Nickel-63 Liquid Scint Ni63, Solid "Dry Weight Corrected"
-0.669 Americium-243 Tracer Curium-243/244 Tracer Americium-243 Tracer Plutonium-242 Tracer Plutonium-242 Tracer Nickel Carrier Strontium Carrier Technetium-99m Tracer Iron-59 Tracer Nickel Carrier Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Isotopic Am241 Am243, Cm243/244, Solid "Dry Weight Corrected" Alphaspec Np, Solid "Dry Weight Corrected" Alphaspec Pu238, 239/240, Solid "Dry Weight Corrected" Liquid Scint Pu241, Solid "Dry Weight Corrected" Gamma Ni59, Solid "Dry Weight Corrected" GFPC, Sr90, Solid "Dry Weight Corrected" Liquid Scint Tc99, Solid "As Received" Liquid Scint Fe55, Solid "Dry Weight Corrected" Liquid Scint Ni63, Solid "Dry Weight Corrected" 26.7 20.8 89.2 77.2 77.2 83.5 50 87.9 60 94.8 (15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
(25%-125%)
(15%-125%)
(15%-125%)
(25%-125%)
The following Prep Methods were performed:
Dry Soil Prep Dry Soil Prep GL-RAD-A-021 09/18/20 2042073 1233 LYT1 Method Description Analyst Date Time Prep Batch The following Analytical Methods were performed:
1 2
3 4
5 6
7 8
9 10 11 12 Method Description DOE EML HASL-300, Am-05-RC Modified ASTM C 1475-00 Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE RESL Ni-1 DOE HASL 300, 4.5.2.3/Ga-01-R EPA 905.0 Modified/DOE RP501 Rev. 1 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE EML HASL-300, Tc-02-RC Modified DOE RESL Fe-1, Modified DOE RESL Ni-1, Modified Analyst Comments Uncertainty Nominal Result Notes:
Page 49 of 58 SDG: 521724
Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: October 16, 2020 Parameter Result Units Qualifier Analyst Date Time DF Batch Method RL MDC PF Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions Company :
S4601 State Hwy 35 Genoa, Wisconsin 54632 Address :
LACBWR Site Restoration Project, Level 5 Package Project:
521724008 S3-012-109B-FJGS-064-SM ENRG07002 Project:
ENRG070 Client ID:
Sample ID:
Client Sample ID:
Uncertainty Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows:
DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 50 of 58 SDG: 521724
Quality Control Summary Page 51 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Alpha Spec 2042096 2042097 Batch Batch Americium-241 Americium-243 Curium-243/244 Americium-241 Americium-243 Curium-243/244 Americium-241 Americium-243 Curium-243/244 Neptunium-237 Neptunium-237 Neptunium-237 Parmname Mr. Jason Q. Spaide
Contact:
LaCrosseSolutions S4601 State Hwy 35 Genoa, Wisconsin October 16, 2020 Report Date:
Units pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g Anlst Date Time BXA4 BXA4 10/09/20 09:19 10/09/20 09:19 10/10/20 09:17 10/12/20 15:48 10/12/20 15:48 10/10/20 20:23 QC 0.00352 0.00263
-0.00312 1.17 0.0568 1.28 0.00482 0.00336 0.000 0.00152 1.21 2.12E-10 NOM Sample 0.0107 0.00521
-0.00296 0.00267 Range N/A N/A N/A (75%-125%)
(75%-125%)
(75%-125%)
N/A (75%-125%)
U U
HU U
QC1204646785 521724001 QC1204646786 QC1204646784 QC1204646788 521724001 QC1204646789 QC1204646787 N/A N/A N/A N/A REC%
122 118 113 0.962 1.09 1.08 DUP LCS MB DUP LCS MB 521724 Workorder:
HUh HUh HUh HUh
+/-0.0191
+/-0.0192
+/-0.0134
+/-0.00348
+/-0.0176
+/-0.0146
+/-0.00943
+/-0.143
+/-0.0548
+/-0.148
+/-0.0111
+/-0.0150
+/-0.00630
+/-0.00449
+/-0.0690
+/-0.00235 RPD%
Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 1 of 7 Page 52 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Alpha Spec Rad Gamma Spec 2042098 2042099 2042160 Batch Batch Batch Plutonium-238 Plutonium-239/240 Plutonium-238 Plutonium-239/240 Plutonium-238 Plutonium-239/240 Plutonium-241 Plutonium-241 Plutonium-241 Cesium-137 Cobalt-60 Europium-152 Parmname Units pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g Anlst Date Time BXA4 BXA4 MXR1 10/09/20 09:12 10/09/20 09:12 10/09/20 09:12 10/11/20 01:28 10/11/20 02:14 10/11/20 00:42 09/21/20 16:02 QC
-0.00441
-0.000909 0.0124 0.960
-0.000586 0.0102 2.06 78.3 0.811 0.174
-0.00320
-0.0102 NOM Sample 0.00459 0.000994 1.88 0.139 0.00459
-0.00733 Range N/A N/A (75%-125%)
N/A (75%-125%)
(0%-20%)
N/A N/A Qual HU HU U
U U
HU U
H HU HU QC1204646791 521724001 QC1204646792 QC1204646790 QC1204646794 521724001 QC1204646795 QC1204646793 QC1204646947 521724001 N/A N/A N/A 21.9 N/A N/A REC%
98.2 102 0.977 77.1 DUP LCS MB DUP LCS MB DUP 521724 Workorder:
HUh HUh HUh Hh HUh HUh
+/-0.0126
+/-0.0104
+/-1.77
+/-0.0275
+/-0.0178
+/-0.0325
+/-0.0102
+/-0.0136
+/-0.0185
+/-0.118
+/-0.0136
+/-0.0166
+/-2.00
+/-5.66
+/-1.54
+/-0.0598
+/-0.0253
+/-0.0558 RPD%
Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 2 of 7 Page 53 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Gamma Spec 2042160 Batch Europium-154 Europium-155 Niobium-94 Americium-241 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Niobium-94 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Parmname Units pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g Anlst Date Time MXR1 09/21/20 16:02 09/21/20 17:00 09/21/20 16:01 QC
-0.0164 0.0494
-0.0167 569 164 97.6 0.214 0.910 0.258 0.0670
-0.00274
-0.00837 0.00853
-0.0160 0.0162 NOM Sample 0.0542 0.0104 0.00576 Range N/A N/A N/A (75%-125%)
(75%-125%)
(75%-125%)
U U
U U
U U
U U
QC1204646948 QC1204646946 N/A N/A N/A REC%
117 101 103 486 164 95.2 LCS MB 521724 Workorder:
HUh HUh HUh
+/-0.0473
+/-0.0389
+/-0.0105
+/-0.0722
+/-0.0558
+/-0.0219
+/-12.1
+/-2.54
+/-2.32
+/-1.11
+/-0.741
+/-1.05
+/-0.294
+/-0.0164
+/-0.0160
+/-0.0368
+/-0.0463
+/-0.0419 RPD%
Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 3 of 7 Page 54 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Gamma Spec Rad Gas Flow Rad Liquid Scintillation 2042160 2044929 2042511 2042294 Batch Batch Batch Batch Niobium-94 Nickel-59 Nickel-59 Nickel-59 Strontium-90 Strontium-90 Strontium-90 Iron-55 Iron-55 Iron-55 Parmname Units pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g Anlst Date Time MXR1 RP1 LXB3 RP1 09/21/20 16:01 09/28/20 11:41 09/28/20 11:42 09/28/20 11:40 10/07/20 14:34 10/08/20 10:30 10/07/20 14:05 09/25/20 09:50 09/25/20 11:56 09/25/20 07:43 QC 0.00392
-2.20 76.5
-0.145
-0.0976 5.43 0.0706
-0.339 191 1.97 NOM Sample 0.0709 0.0246
-1.41 Range N/A (75%-125%)
N/A (75%-125%)
N/A (75%-125%)
Qual U
HU U
HU U
HU U
QC1204653142 521724001 QC1204653143 QC1204653141 QC1204647798 521724005 QC1204647799 QC1204647797 QC1204647267 521724001 QC1204647268 QC1204647266 N/A N/A N/A REC%
84.5 111 90.6 90.5 4.87 211 DUP LCS MB DUP LCS MB DUP LCS MB 521724 Workorder:
HUh HUh HUh
+/-1.25
+/-0.129
+/-5.08
+/-0.0167
+/-1.91
+/-5.86
+/-0.824
+/-0.123
+/-0.296
+/-0.144
+/-4.66
+/-5.46
+/-3.28 RPD%
Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 4 of 7 Page 55 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Liquid Scintillation 2042296 2046296 2046317 Batch Batch Batch Nickel-63 Nickel-63 Nickel-63 Carbon-14 Carbon-14 Carbon-14 Carbon-14 Tritium Tritium Tritium Tritium Parmname Units pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g Anlst Date Time RP1 EW3 TXJ1 09/24/20 08:06 09/24/20 08:22 09/24/20 07:50 10/08/20 12:19 10/08/20 13:27 10/08/20 11:28 10/08/20 13:11 10/09/20 15:51 10/09/20 17:57 10/09/20 14:47 10/12/20 03:27 QC 1.33 90.8 1.06 0.414 145
-1.36 154 2.10 93.8 1.44 109 NOM Sample 0.0490
-0.470
-0.470 1.66 1.66 Range N/A (75%-125%)
N/A (75%-125%)
(75%-125%)
N/A (75%-125%)
(75%-125%)
Qual HU U
HU U
H HU U
H QC1204647270 521724001 QC1204647271 QC1204647269 QC1204656259 521724001 QC1204656261 QC1204656258 QC1204656260 521724001 QC1204656319 521724001 QC1204656321 QC1204656318 QC1204656320 521724001 N/A N/A N/A REC%
96.4 99.5 100 76 79.4 94.1 145 154 123 137 DUP LCS MB DUP LCS MB MS DUP LCS MB MS 521724 Workorder:
+/-2.14
+/-2.09
+/-2.09
+/-4.22
+/-4.22
+/-2.42
+/-4.18
+/-1.97
+/-2.13
+/-7.74
+/-1.95
+/-8.08
+/-3.84
+/-6.91
+/-3.86
+/-15.7 RPD%
Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 5 of 7 Page 56 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Liquid Scintillation 2047687 Batch Technetium-99 Technetium-99 Technetium-99 Parmname Units pCi/g pCi/g pCi/g Anlst Date Time JJ3 10/11/20 17:15 10/11/20 17:53 10/11/20 16:38 QC
-0.533 34.0
-0.235 NOM Sample
-0.958 Range N/A (75%-125%)
Qual HU U
QC1204659474 521724001 QC1204659475 QC1204659473 The Qualifiers in this report are defined as follows:
N/A REC%
96.9 35.1 DUP LCS MB 521724 Workorder:
BD FA H
J J
K L
M M
N/A N1 ND NJ Q
R U
UI UJ UL X
Analyte is a Tracer compound Result is less than value reported Result is greater than value reported Results are either below the MDC or tracer recovery is low Failed analysis.
Analytical holding time was exceeded See case narrative for an explanation Value is estimated Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD REMP Result > MDC/CL and < RDL RPD or %Recovery limits do not apply.
See case narrative Analyte concentration is not detected above the detection limit Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification Gamma Spectroscopy--Uncertain identification Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier HU
+/-0.946
+/-0.921
+/-1.53
+/-0.819 RPD%
Uncertainty Uncertainty Uncertainty Notes:
Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).
Page 6 of 7 Page 57 of 58 SDG: 521724
QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Parmname Page 7 of 7 Units Anlst Date Time QC NOM Sample Range Qual REC%
521724 Workorder:
Y
^
h Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.
- Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 58 of 58 SDG: 521724