ML20094H370
| ML20094H370 | |
| Person / Time | |
|---|---|
| Site: | Perry  |
| Issue date: | 02/28/1992 |
| From: | CENTERIOR ENERGY |
| To: | |
| Shared Package | |
| ML20094H366 | List: |
| References | |
| NUDOCS 9203100054 | |
| Download: ML20094H370 (6) | |
Text
.__ __ _ _ _ . . _ . . _ _ _ _ _ _ _ _ _ _ .. ._ . _ . . _ ._ _
, PY-CEI/NRR-1388 L Attachment 3 Page I of 6
' INSTRUMENTATION 3/4.3.7 MONITORING INSTRUMENTATION RADIATION HONITORING INSTRUMENTATION
. LIMITING C,0NDITION FOR OPERATION 3.3.7.1 The radiation monitoring instrumentation channels shown in Table 3.3.7.1-1 shall be OPERABLE with their alarm / trip setpoints within the specified limits.
APPLICABILITY: As shown in Table 3.3.7.1-1.
ACTION:
- a. With a radiation monitoring instrumentation channel alarm / trip setpoint exceeding the value shown in Table 3.3.7.1-1, adjust the setpoint to within the limit within 4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br /> or declare the channel inoperable,
- b. With one or more radiation monitoring channels inoperable, take the ACTION required by Table 3.3.7.1-1.
- c. The provisions of Specifications 3.0.3 and 3.0.4 are not applicable.
SURVEILLANCE REQUIREMENTS 4.3.7.1 Each of the above required radiation monitoring instrumentation channels shall be demonstrated OPERABLE by the performance of the CHANNEL CHECK, CHANNEL FUNCTIONAL TEST and CHANNEL CALIBRATION operations for the conditions and at the frequencies shown in Table 4.3.7.1-1. '
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PERRY - UNIT 1 3/4 3-61 9203100054 920228 DR ADOCK0500g0
TABLE 3.3.7.1-1
- A
=
RADIATION MONITORING INSTRUMENTATION m
i MINIMUM CHANNELS APPLICABLE ALARM / TRIP g
i INSTRtMENTATION OPERABLE CONDITIONS SETPOINT ACTION
--4 i
~ 1. Fuel Handling 1 **
1 1500 cpm 70 Area Vent Exhaust Radiation Monitor (Noble Gas)
- 2. Offgas. 1
- 1 1 x 108 cpm ID) 71 Post-treatment Radiation Monitor
- 3. Control Room 1 All OPERATIONAL < 800 cpm 72 i' Ventilation Radiation CONDITIONS ano ***
w Monitor (N>ble Gas) k m 4. Offgas Pre-treatment 1 *
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At t achment 3 l Ynyo 4 of 6 TABLE 3.3.7.1-1 (Continued)
RADIATION MONITORING INSTRUMENTATlfN ACTION ACTION 70 -
With the required monitor inoperable, obtain and analyze at least one grab sample of the monitored parameter at least once per 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />. In addition, with the Unit 1 Vent noble gas monitor inoperable, restore the inoperable noble gas monitor to OPERABLE status within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or place the inoperable noble gas monitor in the tripped condition.
ACTION 71 - With the required monitor inoperable, release via this pathway may continue provided grab samples are taken at least once per 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> and these samples are analyzed for gross activity within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.
ACTION 72 -
With the required monitor inoperable, assure a portable con-tinuous noble gas monitor or the Control Room Area Radiation Monitor is OPERABLE in the control room within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />. Re-store the inoperable monitor to OPERABLE status within 7 days, otherwise, initiate and maintain operation of the control room emergency filtration system in the isolation mode of operation within 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br />.
ACTION 73 - With the number of channels OPERABLE less than required by Minimum Channels OPERABLE requirement, release via this pathway may continue for un to 30 days provided:
- a. The offgas system is not bypassed, and
- b. The offgas post-treatment monitor is OPERABLE, and
- c. Grab samples are taken at least once per 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> end analyzed within the following 4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br />; Otherwise, be in at least HOT SHUTDOWN within 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />._ U-
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ACTIONf!If- With
-T7%%v the required monitor inoperable, perform area surveys of l q' the monitored area with portable monitoring instrumentation at leart once per 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.
t
- PERRY - UNIT 1 2/4 3-64
TABLE 4.3.7.1-1 b RASIATION MONITORING'INSTRt1 MENTATION SURVEILLANCE REQUIREMENTS 5!
CHANNEL- CONDITIONS IN c WICH SURVEILLANCE 5 CHANNEL FUNCTT.ONAL CHANNEL CHECK TEST CALIBRATION REQUIRED
[ -INSTRlMENTATION '
- 1. Fuel Handling Area Vent Exhaust R Radiation Monitor 5 M (Noble Gas)
- 2. Offgas Post-treatment M R Radiation Monitor S
- 3. Control Room All DPERATIONAI.
Ventilation Radiation R CONDITIONS and ***
Monitor (Noble Gas) S M Y 4. Offgas Pre-treatment
- S Radiation Monitor S M R
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9 E
The attached Graphs 1 through 26 chart the water levels in the monitor Wils and Highland Aeservoir since data cGloction began. Many of the well water levels peaked shortly after pumping tailings to the basin ceased and havo boon dropping for about seven years.
Attachments 3A (complianco wells),3B (TDSS wells),3C (background wells),3D (oro sands wolls),3E (mino backfill wells) and 3F (Highland Reservoir) provide the 19881991 water quality data, Those attachments are transcribed from the monitoring data provided to the NRC in the semi annual monitoring reports. Annual averagos are provided for each paramotor. (
The data are discussed below by class of well.
~
Compli0nce Wells (125.175.176.177):
The water levels mntinue to fallin these wells, The lovels in 175 and 177 have been erratic sinco scopage ps nping began in 1989. Automatic star 1/stop operation of the pumps and replacement of wom pumps causes the drawn down levels of the pumped wolls to fluctuato.
(
There has been some improvement in water quality sinco pumping began. This is true for Cadm;um, Chromium, Lead and Solonium. The 1991 averago Uranium concentrntions from the wells still exceeded the 0 43 pCl/l standard in the licenso. However, only well 125 exceeds the EPA proposed 30 pCi/l standard for municipal drinking water, Chromo, Hadium 226 plus 228 and Thorium 230 sometimes exceed their respectivo license standards Chrome only exceeded the licenso standard one timo at one wellin 1991. All Radium values are well below the EPA proposed 20 pCi/lindividual staridards for Radium 226 and Radium 228 for municipal drinking water. The highest Thorium 230 values are below 100se that have occurred at the background wells. Following the EPA practice of assuming an analytical result below a detection limit equals one half the detection limit and averaging all the results from the compliance wcils fo,1991, the wells inct all the drinking water Tablo SC standards in Appendix A of 10CFR Part 40 in 1991.
Tha Nicke' concentration at well 175 romains well above the licenso standard of 0.02 mg/l which is based on background as thoro is no Tablo SC value for Nickel. The concentration appears to be increasing slow'y However, the average 1991 concentration of 1.145 mg/lis about the same as that P me t~ .g3 solution when the mill was in operation. Therefore, the concentration at well 175 is e acly to becomo much higher. The Nickel concentration at well 180, just a short distance further from the tailings basin, remains at or near the detection level (0.02 mg/l). The mine backt!!! at well 180 and between it and well 175 effectively removes Nickel from solution. The backfillis an effeuive bar to Nickel migration further away from the basin.
2
_ _ _ _ _ - _ - - _ - _ _ - _ _ _ _ _ _ _ - - - - . - - _ - - - - - - - . - - - - - - _ - . --- .a-
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Tr.ilinas Dam Sindstono Mo_rutor Wolls (TOSS) (015.112.114.117.120.127.178.179.181.
1E311 The water lovels continue to fall in those wells. The lovels in wolls 117 and 178 romain otratic.
Thoso are pumped mitigation wolls. Their water levels are affected by automatic pump start /stop and pump replacement. The averago declino of the walls was about 1.0 foot in 1991.
Lovels have fallon from 10 to 60 feet in the monitor wells since 1984. The water level at woll 015 has fallen so low that it can not be sampled The annual averago chemical and radionuclido concentrations have not changed very much sinco 1988 in the TDSS monitor wells. Somo smallimprovement has occurred in wo!! 112. The pH measurement has trended slightly downward in wells 179,181 and 183 to the north of the tallings basin.
TOSS Backoround Monitor Wells f134.172J74.182):
The water levels of wolls 134 and 174 show no trend. The lovols at wells 172 and 182 continue to fall. This is part of the general declino of water levels in the tailings basin area.
Obvious water quality trends are not seen at the wells. This relativo constancy is reasonable for background wells. The Thoriurn 230 and Uranium concentrations at the background wolls have regularly excooded the licenso standards without the tailings scopage being the cause. Well 182 was the only well used to establish background for the licenso standards, its Uranium concentration exceeded the standard in July,1991 which further indicatos the standard is set
- 9r the low ond of the span of the natural background.
Cu hads Monitor Wells (116.128.129.148):
Lee ; are slowly falling in those wells. The water elevations at the west end of the basin near e ntand Reservoir are far below the lovels to the east. The water levels remain well below those in the overlying TDSS. No trends are obvious in the water quality data.
Mine Bagkfill Wells (171.173.1EQ);
The water levels continue to fall. The rato of fallis loss than at the TDSS wells closest to the backfill which indicates the scopago mound is becoming flatter as expected. This flattening sr.ould express itself as a reduction in the seopage rato. '
The EPRCO 1982 study found that flighland shales and sandstones attenuato scopage constituents. The backfillis a mixture of shales and sandstones. This accounts for the generally.botter water quality in tho mino backfill than at the TDSS wells.
Since the mino backfill contains low grado mineralized materials, elevated Uranium, Thorium 230 and Radium concentraticns can be expected in some saturated zones. This is soon at well 180. The concentrations are higher than at wells 114 and 175 which are much closer to the 3
e .
g basin. The lower concentrations af the TDSS wells indicates that the higher well 180 concentrations are not due to radionuclides in the tailings soepago .
Highland Reservoir (167):
The reservoir water lovel continues to rise at nearly 6 foot por year. The water quality reflects no
- significant impact from tailings scopags.
Summarv; The application of significant resources to soepage mitigation sinco November 1989 has reduced the mass in the TDSS aqulfer of potentially hazardous constituents by about 16.5 kilograms of non-radioactivo and 594 microcuries of radioactivo material. Somo 80% of tho
- radioactive material is Natural Uranium of which 0.7 kilograms has boon removed. The average scopage water pumped to the evaporation lagoons in 1991 met all the Tablo SC limits found in Appendix A of 10CFR Part 40.
Most of the concentrations of potentially hazardous constituents are now below the licenso standards. Those that still exceed the standards regulany are at or below proposed EPA water protection standards for municipal drinking water, Nickel at well 175 is the one obvious exception. However, the Nickelis confined to the area betwoon the nearby mino backfill and the basin. The backfill servos as an offectivo barrior to further Nickel migration. The backfill has virtually no potential for water development because of low permeability.
The tailings seepage has not impacted the concontrations of potentially hazardous constituents in Highland Reservoir. The water levels in the TDSS, mine backfill and ore sand wolls are dropping.- The drop in the TDSS well water lovels since 1984 has boon quite large and continues at about one foot per year.
Please call me at (713) 978 5438 if there are any questions on this report.
Yours truly, kk>
David M. Rango Staff Environmental Engineer DMR:an Atachment -
c: L. Davis - VN/L J.D. Patton 01279201. doc _
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, e 182 (2) g7, p _ 174,(2) 172 (2)
183,(2) 97 , 3 _181,(2) 178,(2) [ 127 12 8 (3)
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^
s71,000 Eo:1emeral Drainage 13[f2) ,,
"tt Former Enhemeral 1 80 Orainage 4 sesAoo-(gh
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411.'000 413h 415.'o00 417.000 r
401.000 403N 40sh 407,'000 40s.000 MAD 1 Date: Januarv 1991 GROUND WATER MONITORING NETWORK Project: Hiah1and
s-t ATTACHMENT 1 Exxon Coal and Minerals Company liighland Reclamation Project-Seepage Mitigation Project Volume pumped from Mitigation Wells Monthly Total volume Pumped (K Gal.lont)
Date 114 117 175 177 178 Pre-Dec. 89 0 0 0 0 0 Dec. 89 _a 111 121 21 El Total 1989 and Total Project 2 111 124 93 97 Jan. 90 _a 98 111 2R 22 Total Project 2 209 237 191 196 Feb. 90 _2 99 93 87 72 Total Project 2 308 330 278 268 March 90 _2 11A 78 58 74 Total Project 2 422 408 336 342 April 90 _C _11 6 _11 7 Total Project 2 433 414 347 349 May 90 _Q 6 5 5 2 Total Project 2 439 419 352 351 June 90 _a 112 112- 95 45 Total Project 2 551 531 447 396 July 90 _D 116 112 94 -37 Total Project 2 667 643 541 433 I
O 4
1 i
ATTACHMENT 1 CONTINUED Volumo Pumped From-Mitigation Wells-Monthly Total Volume Pumped (K Gallons)
Date 114 117 175 177 178 Aug. 90 J 112 74 98 67 Total Project 2 779 717 639 500 Sept. 90 _.Q 95 111 95 111 Total Project 2 874 832 734 614 Oct. 90 0 47 112 56 34 Total Project 2 921 951 790 648 Nov. 90 _Q 73 1Q1 _21 _2d Total Project 2 944 1052 881 672 Dec. 90 _Q 1QQ 1Q.0Q E 24 Total 1990 0 983 1028 815 600 Total Project 2 1094 1152 908 697 Jan. 91 _Q 191 121 22 25 Total Project 2 1196 1277 935 772 Feb. 91 _q 31 10.1 21 12 Total Project 2 1262 1381 960 824 Mar. 91 _0 8J 112 25 12.
Total Project 2 1347 1493 1185 841
-Apr. 91 0 95 106 15 _Q Total Project 2 1442 1599 1201 849 2
j ATTACHMENT 1 CONTINUED Volume Pumped From Mitigation Wells Monthly Total Volume- Pumned (K Gallons)
Date 114 117 175 177 __128 May 91 _Q 49 94 11 11-Total Project 2 1491 1693 1216 861 June 91 _A 48 88 10 _li Total Project 2 1539 1781 1226 875 July 91 _Q 103 88 32 17 Total Project 2 1642 1869 1258 892 Aug 91 2 59 80 35 35 Total Project 2 1701 1949 1293 927 September 91 _A 44 117 54 60 Total Project 2- 1745 2066 1347 987 October 91 _Q 67 104 33 34
. Total Project 2- 1812 2170 -1380 1021 November 91 _Q 90 91 12 8 Total Project 2 1902 2261 1392 1029 December 91 _Q 14 _1ph 8- 0 Total 1991 0 933 1038 532 387 Total Project 2 1916 2367 1400 1035 011001. doc l
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3
- . a Attachment 2 Concentration And Mass Of Constituents Removed From Aquifer-1991 Well --
ll.2 121 122 12A Total
- Volume Liquid Removed (K Gallons)- 933 1038 532 387 2890 Arsenic-License Standard-(mg/1) 0.05 1991 Average (mg/1) <0.001 <0.001 <0.001 <0.001 Removed from Aquifer (gram) 0 0 0- 0- 0 Cadmium License Standard (mg/1) 0.01 1991 Average-(mg/1) <0.010 <0.010 <0.010 <0.010.
Removed from Aquifer (gram) 0 0 0 0 0 Chromium License Standard-(mg/1) 0.05 1991 Average (mg/1)- <0.05 <0.05 <0.055 <0.05 Removed'from Aquifer (gram) 0 0 <110 0 < 110 Gross-Alpha
' License Standard (pCi/l) 15.0 1991 Average (pCi/1) < 2.0 < 2.7 1.0 2.8 Removed from Aquifer (uCi) 0 0 0 0 0 Lead License Standard (mg/1)-0.05 1991 Average (mg/1) < 0.05 < 0.05 < 0.05 < 0.05 Removed from Aquifer (gram) 0 0 0 0 0 Nickel ,
-License Standard (mg/1) 0.02 1991 Average-(mg/1) < 0.035_ 1.145 <0.115 <0.035 Removed'from Aquifer (gram) < 124 4480 <240 <51 <4,895 Radium 226 &.228 License Standard (pCi/1) 5.0 1991-Average (pCi/1) < 3.35 6.4 <2.4 <3.45 Removal from Aquifer _(uC1) 0 25 0 0 25 Selenium
' License-Standard-(mg/1) 0.01 1991: Average (mg/1) <0.005 <0.001 <0.001 <0.001 Removed from Aquifer (gram) 0 0 0 0 0
Attachment 2 Continued Concentration-And Mass Of Constituents Removed From Aquifer 1991 Well Volume Liquid Removed 112 m m 178 T_otal (K-Gallons) 933 1038 532 387 2890 Thorium 230 License Standard (pCi/1) 0.55 1991 Average (pCi/1) <0.20 <0.2 <0.2 <0.2 Removed from Aquifer (uCi/1) 0 0 0 0 0 Uranium License Standard (pci/1) 0.43 1991 Average (pCi/1) 49 <1.0 28 1.2 Removed from Aquifer (uCl) 173 <4 56 2 <235 Total Dissolved Solids License Standard (mg/1) No Limit 1991 Average (ag/1) 4505 6049 4687 4525 '
Removed from Aquifer (Metric Tons)- 16 24 9 7 56 19_Q1 Total Kg Potentially Hazardous Constituents Removed 1991 < 5.1 Total uCi Potentially Hazardous Constituents Removed 1991 < 260 Total Metric Tons Total Dissolved Solids Removed 1991 56 Since Pumoinct Bectan in 1989 Total Kg Potentially Hazardous Constituents Removed < 16.5 Total uCi Potentially Hazardous Constituents Removed < 594 Total Metric Tons Total Dissolved Solids Removed 120 Please note that constituents are.only considered removed from the-aquifer in the 1991 data if their concentration exceeded the license standard. This is because it only necessary to remove them by pumping if they exceeded the standard.
011002'. doc 2
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