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{{#Wiki_filter:.CATEGORY1REGULATOINFORMATION DISTRIBUTION
{{#Wiki_filter:.CATEGORY 1 REGULATO INFORMATION DISTRIBUTION
'TEM(RIDS)ACCESSIONA'NBR:9710210233 DOC.DATE:
'TEM (RIDS)ACCESSIONA'NBR:9710210233 DOC.DATE: 97/10/10 NOTARIZED:
97/10/10NOTARIZED:
NO FACIL:50-244 Robert Emmet Ginna Nuclear Plant, Unit 1, Rochester G AUTH.NAME.;AUTHOR AFFILIATION MECREDY,R.C.
NOFACIL:50-244 RobertEmmetGinnaNuclearPlant,Unit1,Rochester GAUTH.NAME.;AUTHORAFFILIATION MECREDY,R.C.
Rochester Gas 6 Electric Corp.RECIP.NAME RECIPIENT AFFILIATION VISSINGIG.S.
Rochester Gas6ElectricCorp.RECIP.NAME RECIPIENT AFFILIATION VISSINGIG.S.
DOCKET I 05000244 I
DOCKETI05000244I


==SUBJECT:==
==SUBJECT:==
Forwardsresponsetoquestions fromNRCstaffonproposedmodofspentfuelstoragepool,dtd970331.DISTRIBUTION CODE:AOOIDCOPIESRECEIVED:LTR JENCLJSIZE:I+TITLE:ORSubmittal:
Forwards response to questions from NRC staff on proposed mod of spent fuel storage pool,dtd 970331.DISTRIBUTION CODE: AOOID COPIES RECEIVED:LTR J ENCL J SIZE: I+TITLE: OR Submittal:
GeneralDistribution NOTES:License Expdateinaccordance with10CFR2,2.109(9/19/72).
General Distribution NOTES:License Exp date in accordance with 10CFR2,2.109(9/19/72).
05000244ERECIPIENT IDCODE/NAME PD1-1LAVISSINGEG.
05000244 E RECIPIENT ID CODE/NAME PD1-1 LA VISSINGEG.
INTERN:FILECENTE/EMCBNRR/DSSA/SPLB NUDOCS-ABSTRACT EXTERNAL:
INTERN: FILE CENTE/EMCB NRR/DSSA/SPLB NUDOCS-ABSTRACT EXTERNAL: NOAC COPIES LTTR ENCL 1 1 1 1 1 1 1 1 1 1 1 1 1 1 RECIPIENT ID CODE/NAME PD1-1 PD NRR/DE/ECGB/A NRR/DRCH/HICB NRR/DSSA/SRXB OGC/HDS3 NRC PDR COPIES LTTR ENCL 1 1 1 1 1 1 1 1 1 0 1 1 0 R D N NOTE TO ALL NRIDS" RECIPIENTS:
NOACCOPIESLTTRENCL11111111111111RECIPIENT IDCODE/NAME PD1-1PDNRR/DE/ECGB/A NRR/DRCH/HICB NRR/DSSA/SRXB OGC/HDS3NRCPDRCOPIESLTTRENCL1111111110110RDNNOTETOALLNRIDS"RECIPIENTS:
PLEASE HELP US TO REDUCE WASTE.TO HAVE YOUR NAME OR ORGANIZATION REMOVED FROM DISTRIBUTION LISTS OR REDUCE THE NUMBER OF COPIES RECEIVED BY YOU OR YOUR ORGANIZATION, CONTACT THE DOCUMENT CONTROL DESK (DCD)ON EXTENSION 415-2083 TOTAL NUMBER OF COPIES REQUIRED: LTTR 13 ENCL 12 AND ROCHESTER GA9AND EIECTRIC CORPORATION
PLEASEHELPUSTOREDUCEWASTE.TOHAVEYOURNAMEORORGANIZATION REMOVEDFROMDISTRIBUTION LISTSORREDUCETHENUMBEROFCOPIESRECEIVEDBYYOUORYOURORGANIZATION, CONTACTTHEDOCUMENTCONTROLDESK(DCD)ONEXTENSION 415-2083TOTALNUMBEROFCOPIESREQUIRED:
~89 EAST AVENUE, ROCHESTER, N.Y 14649-0001 AREA CODE716 546-2700 ROBERT C.MECREDY Vice president Nuclear Operations October 10, 1997 U.S.Nuclear Regulatory Commission Document Control Desk Attn: Guy S.Vissing Project Directorate I-1 Washington, D.C.20555  
LTTR13ENCL12 ANDROCHESTER GA9ANDEIECTRICCORPORATION
~89EASTAVENUE,ROCHESTER, N.Y14649-0001 AREACODE716546-2700ROBERTC.MECREDYVicepresident NuclearOperations October10,1997U.S.NuclearRegulatory Commission DocumentControlDeskAttn:GuyS.VissingProjectDirectorate I-1Washington, D.C.20555


==Subject:==
==Subject:==
ResponsetoQuestions fromNRCStaffonProposedModification oftheGinnaSpentFuelStoragePool(TACNo.M95759)R.E.GinnaNuclearPowerPlantDocketNo.50-244Ref.(1):LetterfromG.S.Vissing(NRC)toR.C.Mecredy(RGGE),
Response to Questions from NRC Staff on Proposed Modification of the Ginna Spent Fuel Storage Pool (TAC No.M95759)R.E.Ginna Nuclear Power Plant Docket No.50-244 Ref.(1): Letter from G.S.Vissing (NRC)to R.C.Mecredy (RGGE),  


==Subject:==
==Subject:==
RequestforAdditional Information
Request for Additional Information
-SpentFuelPoolModifications (TACNo.M95759),datedAugust25,1997.
-Spent Fuel Pool Modifications (TAC No.M95759), dated August 25, 1997.


==DearMr.Vissing:==
==Dear Mr.Vissing:==
ByReference 1,theNRCstaffrequested additional information regarding theproposedModification oftheGinnaSpentFuelStoragePooldatedMarch31,1997.Enclosedareresponses toeachofthequestions submitted bytheNRCstaff.Veryrulyyours,RobertC.MecreJPO~'",fan97f02'f0233 97fOi0PDRADOCK05000244PPDRlllllllllllllllllllllllllllllllltlllllll Mr.GuyS.Vissing(MailStop14B2)SeniorProjectManagerProjectDirectorate I-1Washington, D.C.20555U.S.NuclearRegulatory Commission RegionI475Allendale RoadKingofPrussia,PA19406GinnaSeniorResidentInspector Mr.PaulD.EddyStateofNewYorkDepartment ofPublicService3EmpireStatePlaza',TenthFloorAlbany,NY12223-1350 U.S.NRCG.S.VissingA-1October10,1997uestionNo.1:Inthesubmittal youhaveindicated thatsomespentfuelrackswithBoraflex, usedpresently inthespentfitelpool(SFP),willberetained.
By Reference 1, the NRC staff requested additional information regarding the proposed Modification of the Ginna Spent Fuel Storage Pool dated March 31, 1997.Enclosed are responses to each of the questions submitted by the NRC staff.Very ruly yours, Robert C.Mecre JPO~'",f an 97f02'f0233 97fOi0 PDR ADOCK 05000244 P PDR lllllllllllllllllllllllllllllllltlllllll Mr.Guy S.Vissing (Mail Stop 14B2)Senior Project Manager Project Directorate I-1 Washington, D.C.20555 U.S.Nuclear Regulatory Commission Region I 475 Allendale Road King of Prussia, PA 19406 Ginna Senior Resident Inspector Mr.Paul D.Eddy State of New York Department of Public Service 3 Empire State Plaza', Tenth Floor Albany, NY 12223-1350 U.S.NRC G.S.Vissing A-1 October 10, 1997 uestion No.1: In the submittal you have indicated that some spent fuel racks with Boraflex, used presently in the spent fitel pool (SFP), will be retained.Although the analysis described in the submittal was based on a very conservative estimation of the degree of Boraflex degradation during its exposure in the SFP, experience has shown that this degradation depends on several factors which may be dificult to estimate.For example, maintaining low silica level in the SFP water may accelerate degradation of the polymer with consequential higher loss on boron carbide.Therefore, many, plants instituted surveillance programs consisting of inspection of coupons andlor measurement of silica concentration in the SFP water.Are you intending to have a Boraflex surveillance program in the reracked SFP?If so, describe the program.If not, provide your basis.R~es ense: RG&E has committed to monitor the reactive silica levels in the spent fuel pool on a monthly basis to detect and evaluate unusual trends of abnormal levels (Reference 1).RG&E is currently monitoring silica levels and will continue this surveillance after reracking of the spent fuel pool.Because the spent fuel racks with Boraflex do not have coupons which would allow periodic inspection, RG&E has outlined in Reference 1 several actions to monitor the potential for Boraflex degradation.
Althoughtheanalysisdescribed inthesubmittal wasbasedonaveryconservative estimation ofthedegreeofBoraflexdegradation duringitsexposureintheSFP,experience hasshownthatthisdegradation dependsonseveralfactorswhichmaybedificulttoestimate.
Some of these activities, as described in Reference 1, will continue after.the proposed reracking of the spent fuel pool.If there are any questions regarding this action plan, please provide a request for additional information.
Forexample,maintaining lowsilicalevelintheSFPwatermayaccelerate degradation ofthepolymerwithconsequential higherlossonboroncarbide.Therefore, many,plantsinstituted surveillance programsconsisting ofinspection ofcouponsandlormeasurement ofsilicaconcentration intheSFPwater.Areyouintending tohaveaBoraflexsurveillance programinthererackedSFP?Ifso,describetheprogram.Ifnot,provideyourbasis.R~esense:RG&Ehascommitted tomonitorthereactivesilicalevelsinthespentfuelpoolonamonthlybasistodetectandevaluateunusualtrendsofabnormallevels(Reference 1).RG&Eiscurrently monitoring silicalevelsandwillcontinuethissurveillance afterreracking ofthespentfuelpool.BecausethespentfuelrackswithBoraflexdonothavecouponswhichwouldallowperiodicinspection, RG&EhasoutlinedinReference 1severalactionstomonitorthepotential forBoraflexdegradation.
Someoftheseactivities, asdescribed inReference 1,willcontinueafter.theproposedreracking ofthespentfuelpool.Ifthereareanyquestions regarding thisactionplan,pleaseprovidearequestforadditional information.


==Reference:==
==Reference:==


11.I.etterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedOctober24,1996;
1 1.I.etter from R.C.Mecredy (RG&E)to G.S.Vissing (NRC), dated October 24, 1996;


==SUBJECT:==
==SUBJECT:==
RESPONSETONRCGENERICLETI'ER96-04,DATEDJUNE26,1996,ONBORAFLEXDEGRADATION INSPENTFUELRACKS.  
RESPONSE TO NRC GENERIC LETI'ER 96-04, DATED JUNE 26, 1996, ON BORAFLEX DEGRADATION IN SPENT FUEL RACKS.  


U.S.NRCG.S.Vis'singA-2October10,1997uestion.No.
U.S.NRC G.S.Vis'sing A-2 October 10, 1997 uestion.No.
2:1nthenewfuelracks,boratedstainless steelpanelswillremainincontactwiththecomponents madefromaregularstainless steel.Becauseoftheslightlydiferentchemicalcomposition ofthesematerials, galvaniccellsmayforminaboricacidsolutionandthismaybeasourceofcorrosion.
2: 1n the new fuel racks, borated stainless steel panels will remain in contact with the components made from a regular stainless steel.Because of the slightly diferent chemical composition of these materials, galvanic cells may form in a boric acid solution and this may be a source of corrosion.
Showthatthisphenomenon willnotcontribute toasignificant degradation ofthepoisonmaterial.
Show that this phenomenon will not contribute to a significant degradation of the poison material.R~es oose: Theoretically, the use of Borated Stainless Steel (BSS)panels as the absorber material in Spent Fuel Storage Racks is assessed as a much more benign condition than the use of porous aluminum-boron carbide panels.The latter, which are known to have a far greater potential for chemical reaction with the pool water under normal pool conditions, have been used in Spent Fuel Storage applications in the past.In order to verify the hypothesis that BSS will be essentially inert under pool conditions, a series of corrosion tests have been performed under very adverse conditions as discussed below.Corrosion tests of BSS coupons of various configurations and boron contents were conducted several years ago by Carpenter Technology Corp., Reading, PA under contract to EPRI.The results of these tests have been published in EPRI Report TR-100784, June 1992'.The test conditions were 2000 PPM boric acid at 154'F for an exposure time of six months.The 154'F test temperature was based on the maximum allowable bulk pool water temperature for spent fuel storage pools.Specimen configurations included simple immersion, creviced, air-purged and galvanically-coupled specimens.
R~esoose:Theoretically, theuseofBoratedStainless Steel(BSS)panelsastheabsorbermaterialinSpentFuelStorageRacksisassessedasamuchmorebenigncondition thantheuseofporousaluminum-boron carbidepanels.Thelatter,whichareknowntohaveafargreaterpotential forchemicalreactionwiththepoolwaterundernormalpoolconditions, havebeenusedinSpentFuelStorageapplications inthepast.Inordertoverifythehypothesis thatBSSwillbeessentially inertunderpoolconditions, aseriesofcorrosion testshavebeenperformed underveryadverseconditions asdiscussed below.Corrosion testsofBSScouponsofvariousconfigurations andboroncontentswereconducted severalyearsagobyCarpenter Technology Corp.,Reading,PAundercontracttoEPRI.Theresultsofthesetestshavebeenpublished inEPRIReportTR-100784, June1992'.Thetestconditions were2000PPMboricacidat154'Fforanexposuretimeofsixmonths.The154'Ftesttemperature wasbasedonthemaximumallowable bulkpoolwatertemperature forspentfuelstoragepools.Specimenconfigurations includedsimpleimmersion,
The galvanically-coupled specimens consisted of BSS coupled with Type 304.None of the twenty-six (26)simple immersion, creviced or air-purged specimens exhibited any measurable weight change with the exception of one specimen which had been welded.Two of the three galvanically-coupled specimens exhibited a very small weight loss, and the third no measurable weight change.Minor rusting was noted on the galvanically-coupled specimens.
: creviced, air-purgedandgalvanically-coupled specimens.
The results of these tests indicated that BSS exhibits excellent corrosion resistance to spent fuel pool water at maximum pool operating temperatures.
Thegalvanically-coupled specimens consisted ofBSScoupledwithType304.Noneofthetwenty-six (26)simpleimmersion, crevicedorair-purgedspecimens exhibited anymeasurable weightchangewiththeexception ofonespecimenwhichhadbeenwelded.Twoofthethreegalvanically-coupled specimens exhibited averysmallweightloss,andthethirdnomeasurable weightchange.Minorrustingwasnotedonthegalvanically-coupled specimens.
In addition to the above tests at 154'F, elevated temperature corrosion tests of BSS have recently been conducted in 2450 PPM boric acid solution at 239'F using a recirculating autoclave'.
Theresultsofthesetestsindicated thatBSSexhibitsexcellent corrosion resistance tospentfuelpoolwateratmaximumpooloperating temperatures.
The selection of the test temperature was based on the highest local pool water temperature which could occur in any cell in the Ginna SFP (saturation temperature based on minimum height of 23 feet of water over any cell).The BSS material used for these tests was ASTM A887-89, Grade B, Type B7 with 1.9%boron, which is slightly higher than the maximum boron content of 1.82%in the BSS material intended for use in the Ginna SFP, and therefore is conservatively representative of the Ginna material.Test specimens included l U.S.NRC G.S.Vidsing A-3 October 10, 1997 simple immersion (free corrosion), galvanically-coupled and artificially-creviced (ASTM G 78-89)configurations.
Inadditiontotheabovetestsat154'F,elevatedtemperature corrosion testsofBSShaverecentlybeenconducted in2450PPMboricacidsolutionat239'Fusingarecirculating autoclave'.
The galvanically-coupled specimens included BSS coupled with Type 304L and with Zircaloy 4.Specimens were exposed for total times of 30 and 60 days (720 and 1440 hours).The results of these tests showed that all specimens exhibited stable, passive behavior in the boric acid environment with very low corrosion rates.The average corrosion rate for the simple immersion and creviced BSS specimens was.0167 Mils Per Year (MPY)and.0320 MPY, respectively.
Theselection ofthetesttemperature wasbasedonthehighestlocalpoolwatertemperature whichcouldoccurinanycellintheGinnaSFP(saturation temperature basedonminimumheightof23feetofwateroveranycell).TheBSSmaterialusedforthesetestswasASTMA887-89,GradeB,TypeB7with1.9%boron,whichisslightlyhigherthanthemaximumboroncontentof1.82%intheBSSmaterialintendedforuseintheGinnaSFP,andtherefore isconservatively representative oftheGinnamaterial.
The average corrosion rate for the galvanically coupled BSS specimens was.033 MPY.These corrosion rates indicate that in the worst case condition (i.e.BSS galvanically coupled to 304L and Zircaloy 4 at a sustained water temperature of 239'F), the thickness loss over a 40 year exposure would be on the order of 1.3 mils (.0013"), or approximately 1%of the total thickness of a BSS sheet.The minimum required thickness of the BSS sheet material for the Ginna SFP racks was 2.5 mm (.098")or 3.0 mm (.118"), depending on rack type.The actual thickness of the finished sheets, however, exceeded the minimum thickness by a considerable margin.For the 2.5 mm sheets, the actual thickness values measured during final dimensional checks on the sheets (each sheet was measured)were in the range 2.65 mm-2.90 mm (.104"-.114")and for the 3.0 mm sheets, 3.15 mm-3.50 mm (.124"-.138").It cari be seen that a loss of thickness due to corrosion on the order of.001"-.002" is much less than the extra margin in thickness in the plates and therefore does not result in a violation of the assumptions in the licensing report.The loss of neutron absorber thickness due to galvanic corrosion is therefore negligible and cannot lead to degradation of the absorber material below minimum design criteria.It should be noted that exposure of the BSS material at such a high temperature (239'F)for prolonged periods of time is an extreme condition which does not represent normal pool operating conditions.
Testspecimens included lU.S.NRCG.S.VidsingA-3October10,1997simpleimmersion (freecorrosion),
The exit temperatures for local fuel bundle cooling, based on bounding conditions, are well below the temperature of 239'F.'s a result, the corrosion rates expected from exposure of the BSS panels to normal pool operating conditions would be significantly lower than those at the elevated temperatures.
galvanically-coupled andartificially-creviced (ASTMG78-89)configurations.
The corrosion rates measured in the elevated temperature tests, therefore, represent a bounding condition.
Thegalvanically-coupled specimens includedBSScoupledwithType304LandwithZircaloy4.Specimens wereexposedfortotaltimesof30and60days(720and1440hours).Theresultsofthesetestsshowedthatallspecimens exhibited stable,passivebehaviorintheboricacidenvironment withverylowcorrosion rates.Theaveragecorrosion rateforthesimpleimmersion andcrevicedBSSspecimens was.0167MilsPerYear(MPY)and.0320MPY,respectively.
~Reference 1.Smith, R.J., Loomis, G.W., Deltete, C.P., Borated tainless Steel A lication in S en-F iel tora e Racks, EPRI TR-100784, Project 2813-21, Final Report, June 1992, p.3-25.2.ATEA Technical Specification 2226.031.000, Borated Stainless Steel A licati n in~Fuel Rack.
Theaveragecorrosion rateforthegalvanically coupledBSSspecimens was.033MPY.Thesecorrosion ratesindicatethatintheworstcasecondition (i.e.BSSgalvanically coupledto304LandZircaloy4atasustained watertemperature of239'F),thethickness lossovera40yearexposurewouldbeontheorderof1.3mils(.0013"),
I'll+II a,.5 U.S.NRC G.S.Vidsing October 10, 1997 3.Letter from R.C.Mecredy (RG&E)to G.S.Vissing (NRC), dated March 31, 1997;
orapproximately 1%ofthetotalthickness ofaBSSsheet.Theminimumrequiredthickness oftheBSSsheetmaterialfortheGinnaSFPrackswas2.5mm(.098")or3.0mm(.118"),depending onracktype.Theactualthickness ofthefinishedsheets,however,exceededtheminimumthickness byaconsiderable margin.Forthe2.5mmsheets,theactualthickness valuesmeasuredduringfinaldimensional checksonthesheets(eachsheetwasmeasured) wereintherange2.65mm-2.90mm(.104"-.114")andforthe3.0mmsheets,3.15mm-3.50mm(.124"-.138").Itcaribeseenthatalossofthickness duetocorrosion ontheorderof.001"-.002" ismuchlessthantheextramargininthickness intheplatesandtherefore doesnotresultinaviolation oftheassumptions inthelicensing report.Thelossofneutronabsorberthickness duetogalvaniccorrosion istherefore negligible andcannotleadtodegradation oftheabsorbermaterialbelowminimumdesigncriteria.
ItshouldbenotedthatexposureoftheBSSmaterialatsuchahightemperature (239'F)forprolonged periodsoftimeisanextremecondition whichdoesnotrepresent normalpooloperating conditions.
Theexittemperatures forlocalfuelbundlecooling,basedonboundingconditions, arewellbelowthetemperature of239'F.'saresult,thecorrosion ratesexpectedfromexposureoftheBSSpanelstonormalpooloperating conditions wouldbesignificantly lowerthanthoseattheelevatedtemperatures.
Thecorrosion ratesmeasuredintheelevatedtemperature tests,therefore, represent aboundingcondition.
~Reference 1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedtainlessSteelAlicationinSen-FieltoraeRacks,EPRITR-100784, Project2813-21,FinalReport,June1992,p.3-25.2.ATEATechnical Specification 2226.031.000, BoratedStainless SteelAlicatinin~FuelRack.
I'll+IIa,.5 U.S.NRCG.S.VidsingOctober10,19973.LetterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedMarch31,1997;


==SUBJECT:==
==SUBJECT:==
APPLICATION FORAMENDMENT TOFACILITYOPERATING LICENSE,REVISEDSPENTFUELPOOLSTORAGEREQUIREMENTS.
APPLICATION FOR AMENDMENT TO FACILITY OPERATING LICENSE, REVISED SPENT FUEL POOL STORAGE REQUIREMENTS.
ATTACHMENT:
ATTACHMENT:
R.E.GINNANUCLEARPOWERPLANT,SPENTFUELPOOLRERACKING, LICENSING REPORT,SECTION5.0,THERMAL-HYDRAULIC EVALUATION.
R.E.GINNA NUCLEAR POWER PLANT, SPENT FUEL POOL RERACKING, LICENSING REPORT, SECTION 5.0, THERMAL-HYDRAULIC EVALUATION.
U.,S.NRCG.S.VissingA-5October10,1997uestionNo.3:Describetheinspection programofboratedstainless steelpanelsbeforetheirincorporation intothespentfuelracks.Re~once:~BackroundTheboratedstainless steelfortheGinnaSFPrackswasspecified asASTMA887-89,GradeB,TypeB6/B7withaminimumboroncontentof1.70%.Boratedstainless steel(BSS)heatswereelectric-furnace meltedandbottom-poured intoingotsattheBOHLER/UDDEHOLM meltfacilityinKapfenberg, Austria.Thesteelchemistry isbasedonType304stainless steel.Thecarboncontentisrestricted to.04%max.,andphosphorus, sulfur,andnitrogenarecontrolled atverylowlevels.Heatanalysesarecheckedbyextracting achillcastsamplefromeachmeltandanalyzing spectrographically priortopouringtheingots.TheheatanalysesforthefourheatsofmaterialmeltedfortheGinnaSFPracksarelistedinTable1.Ingotswerehot-reduced toslabs,andthenfurtherreducedbyhot-rolling tosheetsatBOHLERBlecheinHonigsberg, Austria.Therollingprocessconsisted ofreductions intheprincipal (longitudinal) rollingdirection toapproximately 10mmthickness, thenfurtherreduction bycross-rolling inthetransverse direction, andfinalrollingintheprincipal direction tofinalthickness.
U.,S.NRC G.S.Vissing A-5 October 10, 1997 uestion No.3: Describe the inspection program of borated stainless steel panels before their incorporation into the spent fuel racks.Re~once:~Back round The borated stainless steel for the Ginna SFP racks was specified as ASTM A887-89, Grade B, Type B6/B7 with a minimum boron content of 1.70%.Borated stainless steel (BSS)heats were electric-furnace melted and bottom-poured into ingots at the BOHLER/UDDEHOLM melt facility in Kapfenberg, Austria.The steel chemistry is based on Type 304 stainless steel.The carbon content is restricted to.04%max., and phosphorus, sulfur, and nitrogen are controlled at very low levels.Heat analyses are checked by extracting a chill cast sample from each melt and analyzing spectrographically prior to pouring the ingots.The heat analyses for the four heats of material melted for the Ginna SFP racks are listed in Table 1.Ingots were hot-reduced to slabs, and then further reduced by hot-rolling to sheets at BOHLER Bleche in Honigsberg, Austria.The rolling process consisted of reductions in the principal (longitudinal) rolling direction to approximately 10 mm thickness, then further reduction by cross-rolling in the transverse direction, and final rolling in the principal direction to final thickness.
Afterhotrolling,finishing operations wereperformed atBOHLERBleche,Murzzuschlag, Austria.Theseoperations includedrollerleveling, solutionannealing, surfacegrinding, lasercuttingtospecified sheetdimensions, andpickling.
After hot rolling, finishing operations were performed at BOHLER Bleche, Murzzuschlag, Austria.These operations included roller leveling, solution annealing, surface grinding, laser cutting to specified sheet dimensions, and pickling.Sheet product was divided into lots during the finishing operations.
Sheetproductwasdividedintolotsduringthefinishing operations.
A lot was defined as product from one heat, one heat-treatment batch, and one thickness.
Alotwasdefinedasproductfromoneheat,oneheat-treatment batch,andonethickness.
The BSS material for the Ginna SFP consisted of eleven (11)lots.Ins ections and Test Perf rmed at BOHLER Bleche The following inspections of the BSS sheets were performed at BOHLER Bleche prior to final acceptance of the material:~Visual Inspection Both sides of each sheet were visually inspected after grinding for the presence of U.S.NRC G.S.Vidsing A-6 October 10, 1997 burrs, scratches, or other surface blemishes which might interfere with or cause damage to fuel assemblies during insertion into, or removal from, the racks.Such surface conditions were dressed by buffing or light sanding.~Dimensional Inspections The length and width of each sheet was measured.The thickness of each sheet was measured at six different locations using calibrated micrometers.
TheBSSmaterialfortheGinnaSFPconsisted ofeleven(11)lots.InsectionsandTestPerfrmedatBOHLERBlecheThefollowing inspections oftheBSSsheetswereperformed atBOHLERBlechepriortofinalacceptance ofthematerial:
~Mechanical Properties Ultimate tensile strength, yield strength, elongation, and hardness were measured by destructive tensile testing on a sample cut from one sheet from each lot.The results of these tests all meet the mechanical properties requirements of ASTM A887-89 (see Table 2).The excellent ductility values (10%-16%, substantially above the minimum specification requirement of 6%)are indicative of homogeneous distribution of fine borides in the material.It should be noted that although the product fully meets the ASTM acceptance criteria, there are no design requirements for mechanical properties of BSS in the Ginna SFP application.
~VisualInspection Bothsidesofeachsheetwerevisuallyinspected aftergrindingforthepresenceof U.S.NRCG.S.VidsingA-6October10,1997burrs,scratches, orothersurfaceblemishes whichmightinterfere withorcausedamagetofuelassemblies duringinsertion into,orremovalfrom,theracks.Suchsurfaceconditions weredressedbybuffingorlightsanding.~Dimensional Inspections Thelengthandwidthofeachsheetwasmeasured.
Chemical Analyses (Product analyses by wet chemical analysis)Product chemical analyses were obtained from a sample cut from one sheet from each heat.In addition, samples were cut from one sheet from each lot and analyzed for carbon and boron.Boron analyses were performed by digestion of the sample into aqueous solution and analyzing by ICP (Inductively Coupled Plasma).The results of these analyses are presented in Table 3.All values meet the chemical requirements of ASTM A887-89 Type B6/B7.All boron values exceed the minimum requirement of 1.70%;-It should be noted that the product analyses in Table 3 are in excellent agreement with the heat analyses (Table 1).Chemical Analyses (Boron content by wet chemical analysis)Fifty (50)locations within one sheet from Heat C70780 were sampled and analyzed for boron to establish the homogeneity of boron distribution within one sheet.These values all fell within the range 1.78%to 1.82%boron (mean value 1.80%, standard deviation.0117%boron).Chemical Analyses (Boron content by wet chemical analysis)One sample was cut from each of 51 sheets selected from the total population of 380 sheets and analyzed for boron content.The number of samples selected from each of 0~'r U.S.NRC G.S.Vissing A-7 October 10, 1997 the four heats and the range of boron values for each sample set is as follows: Total Sheets~am le Size%Boron Heat B00021 Heat B04901 Heat C70780 Heat C70796 13 8 279 80 13 samples 8 samples 20 samples 10 samples 1.75-1.77%
Thethickness ofeachsheetwasmeasuredatsixdifferent locations usingcalibrated micrometers.
~Mechanical Properties Ultimatetensilestrength, yieldstrength, elongation, andhardnessweremeasuredbydestructive tensiletestingonasamplecutfromonesheetfromeachlot.Theresultsofthesetestsallmeetthemechanical properties requirements ofASTMA887-89(seeTable2).Theexcellent ductility values(10%-16%,substantially abovetheminimumspecification requirement of6%)areindicative ofhomogeneous distribution offineboridesinthematerial.
ItshouldbenotedthatalthoughtheproductfullymeetstheASTMacceptance
: criteria, therearenodesignrequirements formechanical properties ofBSSintheGinnaSFPapplication.
ChemicalAnalyses(Productanalysesbywetchemicalanalysis)
Productchemicalanalyseswereobtainedfromasamplecutfromonesheetfromeachheat.Inaddition, sampleswerecutfromonesheetfromeachlotandanalyzedforcarbonandboron.Boronanalyseswereperformed bydigestion ofthesampleintoaqueoussolutionandanalyzing byICP(Inductively CoupledPlasma).Theresultsoftheseanalysesarepresented inTable3.Allvaluesmeetthechemicalrequirements ofASTMA887-89TypeB6/B7.Allboronvaluesexceedtheminimumrequirement of1.70%;-It shouldbenotedthattheproductanalysesinTable3areinexcellent agreement withtheheatanalyses(Table1).ChemicalAnalyses(Boroncontentbywetchemicalanalysis)
Fifty(50)locations withinonesheetfromHeatC70780weresampledandanalyzedforborontoestablish thehomogeneity ofborondistribution withinonesheet.Thesevaluesallfellwithintherange1.78%to1.82%boron(meanvalue1.80%,standarddeviation
.0117%boron).ChemicalAnalyses(Boroncontentbywetchemicalanalysis)
Onesamplewascutfromeachof51sheetsselectedfromthetotalpopulation of380sheetsandanalyzedforboroncontent.Thenumberofsamplesselectedfromeachof 0~'r U.S.NRCG.S.VissingA-7October10,1997thefourheatsandtherangeofboronvaluesforeachsamplesetisasfollows:TotalSheets~amleSize%BoronHeatB00021HeatB04901HeatC70780HeatC707961382798013samples8samples20samples10samples1.75-1.77%
1.75-1.77%
1.75-1.77%
1.79-1.81
1.79-1.81%1.75-1.79%
%1.75-1.79%
~'EN-3 Neutron Attenuation Measurements Descri tion of JEN-3 Device and Te.Me h d The JEN-3 device is a solid state detector which contains a Cf-252 source.The device is shaped like a teapot with a handle.The front half of the device is the detector, and the back half contains the source.The handle is approximately 2 feet in length.The dose at the top of the device is 30 mrem/hour.
~'EN-3NeutronAttenuation Measurements DescritionofJEN-3DeviceandTe.MehdTheJEN-3deviceisasolidstatedetectorwhichcontainsaCf-252source.Thedeviceisshapedlikeateapotwithahandle.Thefronthalfofthedeviceisthedetector, andthebackhalfcontainsthesource.Thehandleisapproximately 2feetinlength.Thedoseatthetopofthedeviceis30mrem/hour.
The efficiency for neutrons is approximately 0.1%.A table which is used to reflect neutrons is made of polyethylene which is approximately 3" thick.The borated stainless steel (BSS)sheet to be analyzed is placed between the detector and the table.The neutrons which are emitted by the source pass through the stainless steel and are then reflected back by the plastic table.The energy of the neutrons is also reduced.Those thermalized neutrons are attenuated by the borated stainless steel.The fewer the counts recorded by the detector, the greater the boron loading in the BSS sheets.The boron loading calculations are influenced by the following factors: a)The actual percent boron;b)The thickness of the BSS sheet material;and c)The power supply for the detector.Initially, the power supply for the detector was a source of systematic error.After investigating the operating principles of the instrument, the source of error was eliminated and erroneous test results from the initial measurements were eliminated from consideration.
Theefficiency forneutronsisapproximately 0.1%.Atablewhichisusedtoreflectneutronsismadeofpolyethylene whichisapproximately 3"thick.Theboratedstainless steel(BSS)sheettobeanalyzedisplacedbetweenthedetectorandthetable.Theneutronswhichareemittedbythesourcepassthroughthestainless steelandarethenreflected backbytheplastictable.Theenergyoftheneutronsisalsoreduced.Thosethermalized neutronsareattenuated bytheboratedstainless steel.Thefewerthecountsrecordedbythedetector, thegreatertheboronloadingintheBSSsheets.Theboronloadingcalculations areinfluenced bythefollowing factors:a)Theactualpercentboron;b)Thethickness oftheBSSsheetmaterial; andc)Thepowersupplyforthedetector.
The ability of the JEN-3 instrument to function properly is influenced by both the thickness of the BSS material and the boron loading.The relationship between the counts recorded by the JEN-3 detector and boron loading is a negative exponential relationship.
Initially, thepowersupplyforthedetectorwasasourceofsystematic error.Afterinvestigating theoperating principles oftheinstrument, thesourceoferrorwaseliminated anderroneous testresultsfromtheinitialmeasurements wereeliminated fromconsideration.
All calibration curves were developed using log-log plots.
TheabilityoftheJEN-3instrument tofunctionproperlyisinfluenced byboththethickness oftheBSSmaterialandtheboronloading.Therelationship betweenthecountsrecordedbytheJEN-3detectorandboronloadingisanegativeexponential relationship.
U.S.NRC G.S.Vihsing A-8 October 10, 1997 Ins ection Pro ram Calibration Curve-A calibration curve for the statistical analysis of BSS was developed using destructive chemical testing and neutron albedo analysis with the JEN-3.The response of the JEN-3 device as a function of boron loading in BSS sheets of varying boron content and thickness was established using destructive chemical analysis.Boron content ranged from 1.2%to 1.9%, and sheet thickness from 2.0 mm to 3.5 mm.Boron analyses were performed by BOHLER at the corporate chemistry laboratory in Kapfenburg, Austria.Thickness was measured using a calibrated ultrasonic thickness meter (calibration records for the meter and technician training records were reviewed and found to be satisfactory).
Allcalibration curvesweredeveloped usinglog-logplots.
The JEN-3 device was response checked on a daily basis to verify instrument operability.
U.S.NRCG.S.VihsingA-8October10,1997InsectionProramCalibration Curve-Acalibration curveforthestatistical analysisofBSSwasdeveloped usingdestructive chemicaltestingandneutronalbedoanalysiswiththeJEN-3.TheresponseoftheJEN-3deviceasafunctionofboronloadinginBSSsheetsofvaryingboroncontentandthickness wasestablished usingdestructive chemicalanalysis.
These records were maintained for review and approval during all QA surveillance activities performed by FTI, ATEA, or RG&E.The resulting calibration curve was a negative exponential line (log-log plot)with a correlation confidence of approximately 99.9%.2)Verification of Boron Content-The neutron attenuation characteristics of all BSS sheets was measured at one randomly selected location using the JEN-3 device.Sheet thickness was also measured at the exact location where the JEN-3 measurement was taken.The boron loading in each sheet was calculated from the JEN-3 measurement using the equation developed from the calibration curve.In order to account for all of the statistical errors in the JEN-3 measurement process, the minimum acceptable level of boron for any sheet was established as 1.74%.This minimum limit provides an additional margin of safety in boron loading.With 1.74%as the minimum acceptable calculated boron loading, there is greater than 95%confidence that no BSS sheets contained less than 1.70%boron.This level of confidence provides a margin of safety in the criticality calculations.
Boroncontentrangedfrom1.2%to1.9%,andsheetthickness from2.0mmto3.5mm.Boronanalyseswereperformed byBOHLERatthecorporate chemistry laboratory inKapfenburg, Austria.Thickness wasmeasuredusingacalibrated ultrasonic thickness meter(calibration recordsforthemeterandtechnician trainingrecordswerereviewedandfoundtobesatisfactory).
Neutron attenuation data of all BSS sheets, as measured by JEN-3 at one randomly selected location in each sheet, was reviewed by an independent statistical consultant retained by RG&E;Joseph O.Voelkel, PhD., Assistant U.S.NRC G.S.Vidsing A-9 October 10, 1997 Professor of Statistics at the College of Engineering, Rochester Institute of Technology.
TheJEN-3devicewasresponsecheckedonadailybasistoverifyinstrument operability.
His conclusions, based on both parametric and non-parametric tolerance intervals, confirmed the acceptance criteria, described above.3)Boron Homogeneity
Theserecordsweremaintained forreviewandapprovalduringallQAsurveillance activities performed byFTI,ATEA,orRG&E.Theresulting calibration curvewasanegativeexponential line(log-logplot)withacorrelation confidence ofapproximately 99.9%.2)Verification ofBoronContent-Theneutronattenuation characteristics ofallBSSsheetswasmeasuredatonerandomlyselectedlocationusingtheJEN-3device.Sheetthickness wasalsomeasuredattheexactlocationwheretheJEN-3measurement wastaken.Theboronloadingineachsheetwascalculated fromtheJEN-3measurement usingtheequationdeveloped fromthecalibration curve.Inordertoaccountforallofthestatistical errorsintheJEN-3measurement process,theminimumacceptable levelofboronforanysheetwasestablished as1.74%.Thisminimumlimitprovidesanadditional marginofsafetyinboronloading.With1.74%astheminimumacceptable calculated boronloading,thereisgreaterthan95%confidence thatnoBSSsheetscontained lessthan1.70%boron.Thislevelofconfidence providesamarginofsafetyinthecriticality calculations.
-Thirty-four (34)BSS sheets were randomly chosen from the total population.
Neutronattenuation dataofallBSSsheets,asmeasuredbyJEN-3atonerandomlyselectedlocationineachsheet,wasreviewedbyanindependent statistical consultant retainedbyRG&E;JosephO.Voelkel,PhD.,Assistant U.S.NRCG.S.VidsingA-9October10,1997Professor ofStatistics attheCollegeofEngineering, Rochester Institute ofTechnology.
A neutron attenuation measurement was taken at five (5)randomly selected locations on each sheet using the JEN-3 device.This sampling plan was in accordance with the instructions of ASTM-E826,"Standard Practice for Testing Homogeneity of Materials for the Development of Reference Materials." Thickness measurements were taken at the exact locations where the JEN-3 measurements were taken.The data were then evaluated by statistical tests as follows: Ranges (maximum minus minimum measured value)were calculated for each of the 34 sets of 5 JEN-3 values.These were plotted against the calculated mean range and 2-sigma values.If no values fell outside the 2-sigma limits, this would be one indication of homogeneity within the population.
Hisconclusions, basedonbothparametric andnon-parametric tolerance intervals, confirmed theacceptance
This was indeed the case;i.e., all values were within 2-sigma limits.Analysis Of Variance under the random effects model was performed on the data.Residual model diagnostics demonstrated a random distribution of residuals, indicating homogeneity of boron distribution throughout the BSS population.
: criteria, described above.3)BoronHomogeneity
These results strongly indicate homogeneity of boron distribution throughout the BSS product.Ins ections and Tests Performed b Rochester Gas A, Electric Co~Chemical Analysis Overchecks (Boron content by wet chemical analysis)Chemical analysis overchecks on samples of BSS obtained from BOHLER were performed by two independent commercial testing laboratories in the US.These analyses were obtained to provide additional confidence in the boron analyses reported by BOHLER.Results of these tests are presented in Table 4.The results of the these overchecks indicate that the boron analyses reported by BOHLER are reliable.~Metallographic Examinations U,S.NRC G.S.Vissing A-10 October 10, 1997 Samples cut from one sheet from each lot of material in both the principal and transverse rolling directions were examined metallographically.
-Thirty-four (34)BSSsheetswererandomlychosenfromthetotalpopulation.
All specimens were polished and etched with Kallings reagent.The microstructures in both longitudinal and transverse cross-sections exhibit a fine,'niform dispersion of borides in an austenitic matrix.No evidence of banding or segregation are present.The boride homogeneity in the BOHLER material compares very favorably with published microstructures of Grade A material produced by powdered metallurgy methods'.ualit Assurance'Over i h Additional inspections were provided as part of Quality Assurance oversight.
Aneutronattenuation measurement wastakenatfive(5)randomlyselectedlocations oneachsheetusingtheJEN-3device.Thissamplingplanwasinaccordance withtheinstructions ofASTM-E826, "Standard PracticeforTestingHomogeneity ofMaterials fortheDevelopment ofReference Materials."
Bohler activities were subject to quality surveillance by personnel from the Bohler, ATEA, Framatome Technologies, and Rochester Gas&Electric Quality Assurance organizations.
Thickness measurements weretakenattheexactlocations wheretheJEN-3measurements weretaken.Thedatawerethenevaluated bystatistical testsasfollows:Ranges(maximumminusminimummeasuredvalue)werecalculated foreachofthe34setsof5JEN-3values.Thesewereplottedagainstthecalculated meanrangeand2-sigmavalues.Ifnovaluesfelloutsidethe2-sigmalimits,thiswouldbeoneindication ofhomogeneity withinthepopulation.
This oversight provided independent monitoring of the BSS manufacturing process and results of inspection activities at Bohler.~
Thiswasindeedthecase;i.e.,allvalueswerewithin2-sigmalimits.AnalysisOfVarianceundertherandomeffectsmodelwasperformed onthedata.Residualmodeldiagnostics demonstrated arandomdistribution ofresiduals, indicating homogeneity ofborondistribution throughout theBSSpopulation.
Theseresultsstronglyindicatehomogeneity ofborondistribution throughout theBSSproduct.InsectionsandTestsPerformed bRochester GasA,ElectricCo~ChemicalAnalysisOverchecks (Boroncontentbywetchemicalanalysis)
Chemicalanalysisoverchecks onsamplesofBSSobtainedfromBOHLERwereperformed bytwoindependent commercial testinglaboratories intheUS.Theseanalyseswereobtainedtoprovideadditional confidence intheboronanalysesreportedbyBOHLER.Resultsofthesetestsarepresented inTable4.Theresultsofthetheseoverchecks indicatethattheboronanalysesreportedbyBOHLERarereliable.
~Metallographic Examinations U,S.NRCG.S.VissingA-10October10,1997Samplescutfromonesheetfromeachlotofmaterialinboththeprincipal andtransverse rollingdirections wereexaminedmetallographically.
Allspecimens werepolishedandetchedwithKallingsreagent.Themicrostructures inbothlongitudinal andtransverse cross-sections exhibitafine,'niform dispersion ofboridesinanaustenitic matrix.Noevidenceofbandingorsegregation arepresent.Theboridehomogeneity intheBOHLERmaterialcomparesveryfavorably withpublished microstructures ofGradeAmaterialproducedbypowderedmetallurgy methods'.
ualitAssurance
'OverihAdditional inspections wereprovidedaspartofQualityAssurance oversight.
Bohleractivities weresubjecttoqualitysurveillance bypersonnel fromtheBohler,ATEA,Framatome Technologies, andRochester Gas&ElectricQualityAssurance organizations.
Thisoversight providedindependent monitoring oftheBSSmanufacturing processandresultsofinspection activities atBohler.~


==Reference:==
==Reference:==


1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedStainle.s SteelAlicationinen-FuelStoraeRack.,EPRITR-100784, Project2813-21,FinalReport,June1992,p.3-13.
1.Smith, R.J., Loomis, G.W., Deltete, C.P., Borated Stainle.s Steel A lication in en-Fuel Stora e Rack., EPRI TR-100784, Project 2813-21, Final Report, June 1992, p.3-13.
U.,S.NRCG.S.VissingA-11October10,1997TABLE1HeatAnalsesCSiMnPSCrNiBNC70780C70796B00021B04901ASTMA887TypeB6ASTMA887TypeB7.021.331.13.013,00119.8912.501.81.018.029.341.06.012.00119.9612.641.76.021.020.551.18.009.00219.6913.181.76.027.013.421.21.008.00119.5013.211.75.015.08'5'.0'45'3'8.0 12.01.510'20.015.01.740817512Pl045103l18P12Q1751PI20.015.02.25Note1:MaximumvalueTABLE2Mechanical ProertiesH~eatL~otC70796290C70796314C70780287C70780282C70780313C70780288C70780289B00021221B00021223B04901224B04901222UTS~Y~EIonationHardness~SI~KSI~oin2"~Brinell94.766.412.319596.062.111.721999.165.312.220993.161.214.123994.755.310.622997.563.811.219995.956.716.823994.462.810.922497.261.812.222993.058.313.823495.366.112.3229ASTMA887-8975Min30Min6.0Min241Max U.S.NRCG.S.VissingA-12October10,1997TABLE3~d~CSiMnPSCrNiBNCB00021221B00021223B04901222B04901224C70780282C70780287C70780288C70780289C70780313C70796290C70796314.021.551.18.008.00319.713~1.020.009.431.21.007.00219.413~1.01.024.321.10.012.00119.812.4.023.023.023.023.025.331.06.012.00119.912.5.0251.75.0321.741.73.0161.761.76.0221.811,801.801.801.78.0281.78TABLE4BoronAnalsisOvercheck
U.,S.NRC G.S.Vissing A-11 October 10, 1997 TABLE 1 Heat Anal ses C Si Mn P S Cr Ni B N C70780 C70796 B00021 B04901 ASTM A887 Type B6 ASTM A887 Type B7.021.33 1.13.013 ,001 19.89 12.50 1.81.018.029.34 1.06.012.001 19.96 12.64 1.76.021.020.55 1.18.009.002 19.69 13.18 1.76.027.013.42 1.21.008.001 19.50 13.21 1.75.015.08'5'.0'45'3'8.0 12.0 1.5 10'20.0 15.0 1.74 081 751 2 Pl 0451 03l 18 P 12 Q 1 75 1PI 20.0 15.0 2.25 Note 1: Maximum value TABLE 2 Mechanical Pro erties H~eat L~ot C70796 290 C70796 314 C70780 287 C70780 282 C70780 313 C70780 288 C70780 289 B00021 221 B00021 223 B04901 224 B04901 222 UTS~Y~EIon ation Hardness~SI~KSI~oin 2"~Brinell 94.7 66.4 12.3 195 96.0 62.1 11.7 219 99.1 65.3 12.2 209 93.1 61.2 14.1 239 94.7 55.3 10.6 229 97.5 63.8 11.2 199 95.9 56.7 16.8 239 94.4 62.8 10.9 224 97.2 61.8 12.2 229 93.0 58.3 13.8 234 95.3 66.1 12.3 229 ASTM A887-89 75 Min 30 Min 6.0 Min 241 Max U.S.NRC G.S.Vissing A-12 October 10, 1997 TABLE 3~d~C Si Mn P S Cr Ni B N C B00021 221 B00021 223 B04901 222 B04901 224 C70780 282 C70780 287 C70780 288 C70780 289 C70780 313 C70796 290 C70796 314.021.55 1.18.008.003 19.7 13~1.020.009.43 1.21.007.002 19.4 13~1.01.024.32 1.10.012.001 19.8 12.4.023.023.023.023.025.33 1.06.012.001 19.9 12.5.025 1.75.032 1.74 1.73.016 1.76 1.76.022 1.81 1,80 1.80 1.80 1.78.028 1.78 TABLE 4 Boron Anal sis Overcheck~Heat~Sheet C70780 105 C70780 105 C70780 105 Laboratory Bohler Ledoux M&P Labs%Boron 1.83%1.86%1.82%B00021 91 A B00021 371A B04901 11A B04901 171 A Ledoux M8cP Labs Ledoux MEcP Labs 1.82%1.84%1.82%1.85%
~Heat~SheetC70780105C70780105C70780105Laboratory BohlerLedouxM&PLabs%Boron1.83%1.86%1.82%B0002191AB00021371AB0490111AB04901171ALedouxM8cPLabsLedouxMEcPLabs1.82%1.84%1.82%1.85%
U.S.NRC G.S.Vilsing A-13 October 10, 1997 uestion¹4: Although tests with borated stainless steel have indicated that in the SFP environment no measurable corrosion degradation takes place, the importance of its role in reactivity control in the SFP makes it advisable to have a surveillance program which would provide additional assurance that at all times there will be enough poison material in the SFP.Are you planning to institute such a prograni in your plant?If so, describe the program.If not, provide your basis.~Res ense: RG&E plans to institute a surveillance program for borated stainless steel (BSS)in the SFP at the R.E.Ginna Nuclear Power Station.A coupon tree has been designed which consists of.a 304L stainless steel rack to which 36 BSS coupons (8" long X 6" wide)will be bolted.Each face and the edges of the coupons are exposed to the SFP boric acid environment.
U.S.NRCG.S.VilsingA-13October10,1997uestion¹4:Althoughtestswithboratedstainless steelhaveindicated thatintheSFPenvironment nomeasurable corrosion degradation takesplace,theimportance ofitsroleinreactivity controlintheSFPmakesitadvisable tohaveasurveillance programwhichwouldprovideadditional assurance thatatalltimestherewillbeenoughpoisonmaterialintheSFP.Areyouplanningtoinstitute suchaprograniinyourplant?Ifso,describetheprogram.Ifnot,provideyourbasis.~Resense:RG&Eplanstoinstitute asurveillance programforboratedstainless steel(BSS)intheSFPattheR.E.GinnaNuclearPowerStation.Acoupontreehasbeendesignedwhichconsistsof.a304Lstainless steelracktowhich36BSScoupons(8"longX6"wide)willbebolted.EachfaceandtheedgesofthecouponsareexposedtotheSFPboricacidenvironment.
Crevices and 304L/BSS galvanic couples are created on the tree at each bolt location.The coupons were selected so that material from each heat and lot of BSS sheet material to,be used as poison panels in the pool are represented on the tree.In comparison with surveillance programs for other neutron absorber materials, the design and construction of the coupon tree for the Ginna SFP provides a more accurate representation of the actual exposure conditions of BSS in the SFP.The tree will be removed and inspected after the first 18-month operating cycle, and every three operating cycles (approximately 4 1/2 years)thereafter.
Crevicesand304L/BSSgalvaniccouplesarecreatedonthetreeateachboltlocation.
The coupons will be removed from the tree, inspected visually for any evidence of corrosion, and thickness measurements taken on the exposed surfaces and in the creviced/galvanically coupled areas.These measurements will be compared with the original thickness measurements recorded for each coupon to determine if any measurable material loss has occurred.In addition, each coupon will be weighed and the weights compared with original weights to determine weight change.Any unusual surface condition suggestive of significant corrosion will be evaluated using appropriate analytical methods.
ThecouponswereselectedsothatmaterialfromeachheatandlotofBSSsheetmaterialto,beusedaspoisonpanelsinthepoolarerepresented onthetree.Incomparison withsurveillance programsforotherneutronabsorbermaterials, thedesignandconstruction ofthecoupontreefortheGinnaSFPprovidesamoreaccuraterepresentation oftheactualexposureconditions ofBSSintheSFP.Thetreewillberemovedandinspected afterthefirst18-monthoperating cycle,andeverythreeoperating cycles(approximately 41/2years)thereafter.
1~sl ir Cg-~I' s A U.S.NRC G.S.Vi~sing A-14 October 10, 1997 uestion¹5: With a larger number of fuel assemblies stored in the SFP it is expected that more corrosion products and other impurities will be generated in the SFP.Is the presently existing purtftcation system adequate to handle this increased amount of impurities?
Thecouponswillberemovedfromthetree,inspected visuallyforanyevidenceofcorrosion, andthickness measurements takenontheexposedsurfacesandinthecreviced/galvanically coupledareas.Thesemeasurements willbecomparedwiththeoriginalthickness measurements recordedforeachcoupontodetermine ifanymeasurable materiallosshasoccurred.
Provide your basis.Recense: The current purification system consists of: (a)a string-wound skimmer filter for surface cleanliness, and (b)a spent fuel pool mixed bed resin for liquid purification.
Inaddition, eachcouponwillbeweighedandtheweightscomparedwithoriginalweightstodetermine weightchange.Anyunusualsurfacecondition suggestive ofsignificant corrosion willbeevaluated usingappropriate analytical methods.
The resin bed pulls from the bottom of the pool for its cleaning process.It is a 15 cubic foot mixed bed resin filtration system.The frequency of change-out of the surface filtration system is currently approximately once every two years.This is a surface clarity maintenance system.The additional fuel will not affect its operating characteristics.
1~slirCg-~I' sAU.S.NRCG.S.Vi~singA-14October10,1997uestion¹5:Withalargernumberoffuelassemblies storedintheSFPitisexpectedthatmorecorrosion productsandotherimpurities willbegenerated intheSFP.Isthepresently existingpurtftcation systemadequatetohandlethisincreased amountofimpurities?
The frequency of change-out for the resin system is currently once per year.Historical records following the 1985 rerack project at Ginna Station showed no measurable increase in the change-out frequency.
Provideyourbasis.Recense:Thecurrentpurification systemconsistsof:(a)astring-wound skimmerfilterforsurfacecleanliness, and(b)aspentfuelpoolmixedbedresinforliquidpurification.
The 1985 change was larger in its work scope than the proposed modification.
Theresinbedpullsfromthebottomofthepoolforitscleaningprocess.Itisa15cubicfootmixedbedresinfiltration system.Thefrequency ofchange-out ofthesurfacefiltration systemiscurrently approximately onceeverytwoyears.Thisisasurfaceclaritymaintenance system.Theadditional fuelwillnotaffectitsoperating characteristics.
At that time, approximately 420 cells were added.By comparison, the proposed modification will increase the storage capacity by 305 cells in 1998 (an additional 48 storage cells may be added in the future if needed)~It is postulated that the upcoming rerack will not increase the cleaning system change-out.
Thefrequency ofchange-out fortheresinsystemiscurrently onceperyear.Historical recordsfollowing the1985rerackprojectatGinnaStationshowednomeasurable increaseinthechange-out frequency.
However, the system will be monitored to determine any changes to historical patterns.Therefore it can be concluded that the capacity of the purification system is adequate and can absorb the additional storage requirements without substantially affecting current plant maintenance capability to handle any increased amount of corrosion products and other impurities.
The1985changewaslargerinitsworkscopethantheproposedmodification.
0 1'I/'h JF P}}
Atthattime,approximately 420cellswereadded.Bycomparison, theproposedmodification willincreasethestoragecapacityby305cellsin1998(anadditional 48storagecellsmaybeaddedinthefutureifneeded)~Itispostulated thattheupcomingrerackwillnotincreasethecleaningsystemchange-out.
However,thesystemwillbemonitored todetermine anychangestohistorical patterns.
Therefore itcanbeconcluded thatthecapacityofthepurification systemisadequateandcanabsorbtheadditional storagerequirements withoutsubstantially affecting currentplantmaintenance capability tohandleanyincreased amountofcorrosion productsandotherimpurities.
01'I/'hJFP}}

Revision as of 12:42, 7 July 2018

Forwards Response to Questions from NRC Staff on Proposed Mod of Spent Fuel Storage Pool,Dtd 970331
ML17264B072
Person / Time
Site: Ginna Constellation icon.png
Issue date: 10/10/1997
From: MECREDY R C
ROCHESTER GAS & ELECTRIC CORP.
To: VISSING G S
NRC (Affiliation Not Assigned), NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
TAC-M95759, NUDOCS 9710210233
Download: ML17264B072 (22)


Text

.CATEGORY 1 REGULATO INFORMATION DISTRIBUTION

'TEM (RIDS)ACCESSIONA'NBR:9710210233 DOC.DATE: 97/10/10 NOTARIZED:

NO FACIL:50-244 Robert Emmet Ginna Nuclear Plant, Unit 1, Rochester G AUTH.NAME.;AUTHOR AFFILIATION MECREDY,R.C.

Rochester Gas 6 Electric Corp.RECIP.NAME RECIPIENT AFFILIATION VISSINGIG.S.

DOCKET I 05000244 I

SUBJECT:

Forwards response to questions from NRC staff on proposed mod of spent fuel storage pool,dtd 970331.DISTRIBUTION CODE: AOOID COPIES RECEIVED:LTR J ENCL J SIZE: I+TITLE: OR Submittal:

General Distribution NOTES:License Exp date in accordance with 10CFR2,2.109(9/19/72).

05000244 E RECIPIENT ID CODE/NAME PD1-1 LA VISSINGEG.

INTERN: FILE CENTE/EMCB NRR/DSSA/SPLB NUDOCS-ABSTRACT EXTERNAL: NOAC COPIES LTTR ENCL 1 1 1 1 1 1 1 1 1 1 1 1 1 1 RECIPIENT ID CODE/NAME PD1-1 PD NRR/DE/ECGB/A NRR/DRCH/HICB NRR/DSSA/SRXB OGC/HDS3 NRC PDR COPIES LTTR ENCL 1 1 1 1 1 1 1 1 1 0 1 1 0 R D N NOTE TO ALL NRIDS" RECIPIENTS:

PLEASE HELP US TO REDUCE WASTE.TO HAVE YOUR NAME OR ORGANIZATION REMOVED FROM DISTRIBUTION LISTS OR REDUCE THE NUMBER OF COPIES RECEIVED BY YOU OR YOUR ORGANIZATION, CONTACT THE DOCUMENT CONTROL DESK (DCD)ON EXTENSION 415-2083 TOTAL NUMBER OF COPIES REQUIRED: LTTR 13 ENCL 12 AND ROCHESTER GA9AND EIECTRIC CORPORATION

~89 EAST AVENUE, ROCHESTER, N.Y 14649-0001 AREA CODE716 546-2700 ROBERT C.MECREDY Vice president Nuclear Operations October 10, 1997 U.S.Nuclear Regulatory Commission Document Control Desk Attn: Guy S.Vissing Project Directorate I-1 Washington, D.C.20555

Subject:

Response to Questions from NRC Staff on Proposed Modification of the Ginna Spent Fuel Storage Pool (TAC No.M95759)R.E.Ginna Nuclear Power Plant Docket No.50-244 Ref.(1): Letter from G.S.Vissing (NRC)to R.C.Mecredy (RGGE),

Subject:

Request for Additional Information

-Spent Fuel Pool Modifications (TAC No.M95759), dated August 25, 1997.

Dear Mr.Vissing:

By Reference 1, the NRC staff requested additional information regarding the proposed Modification of the Ginna Spent Fuel Storage Pool dated March 31, 1997.Enclosed are responses to each of the questions submitted by the NRC staff.Very ruly yours, Robert C.Mecre JPO~'",f an 97f02'f0233 97fOi0 PDR ADOCK 05000244 P PDR lllllllllllllllllllllllllllllllltlllllll Mr.Guy S.Vissing (Mail Stop 14B2)Senior Project Manager Project Directorate I-1 Washington, D.C.20555 U.S.Nuclear Regulatory Commission Region I 475 Allendale Road King of Prussia, PA 19406 Ginna Senior Resident Inspector Mr.Paul D.Eddy State of New York Department of Public Service 3 Empire State Plaza', Tenth Floor Albany, NY 12223-1350 U.S.NRC G.S.Vissing A-1 October 10, 1997 uestion No.1: In the submittal you have indicated that some spent fuel racks with Boraflex, used presently in the spent fitel pool (SFP), will be retained.Although the analysis described in the submittal was based on a very conservative estimation of the degree of Boraflex degradation during its exposure in the SFP, experience has shown that this degradation depends on several factors which may be dificult to estimate.For example, maintaining low silica level in the SFP water may accelerate degradation of the polymer with consequential higher loss on boron carbide.Therefore, many, plants instituted surveillance programs consisting of inspection of coupons andlor measurement of silica concentration in the SFP water.Are you intending to have a Boraflex surveillance program in the reracked SFP?If so, describe the program.If not, provide your basis.R~es ense: RG&E has committed to monitor the reactive silica levels in the spent fuel pool on a monthly basis to detect and evaluate unusual trends of abnormal levels (Reference 1).RG&E is currently monitoring silica levels and will continue this surveillance after reracking of the spent fuel pool.Because the spent fuel racks with Boraflex do not have coupons which would allow periodic inspection, RG&E has outlined in Reference 1 several actions to monitor the potential for Boraflex degradation.

Some of these activities, as described in Reference 1, will continue after.the proposed reracking of the spent fuel pool.If there are any questions regarding this action plan, please provide a request for additional information.

Reference:

1 1.I.etter from R.C.Mecredy (RG&E)to G.S.Vissing (NRC), dated October 24, 1996;

SUBJECT:

RESPONSE TO NRC GENERIC LETI'ER 96-04, DATED JUNE 26, 1996, ON BORAFLEX DEGRADATION IN SPENT FUEL RACKS.

U.S.NRC G.S.Vis'sing A-2 October 10, 1997 uestion.No.

2: 1n the new fuel racks, borated stainless steel panels will remain in contact with the components made from a regular stainless steel.Because of the slightly diferent chemical composition of these materials, galvanic cells may form in a boric acid solution and this may be a source of corrosion.

Show that this phenomenon will not contribute to a significant degradation of the poison material.R~es oose: Theoretically, the use of Borated Stainless Steel (BSS)panels as the absorber material in Spent Fuel Storage Racks is assessed as a much more benign condition than the use of porous aluminum-boron carbide panels.The latter, which are known to have a far greater potential for chemical reaction with the pool water under normal pool conditions, have been used in Spent Fuel Storage applications in the past.In order to verify the hypothesis that BSS will be essentially inert under pool conditions, a series of corrosion tests have been performed under very adverse conditions as discussed below.Corrosion tests of BSS coupons of various configurations and boron contents were conducted several years ago by Carpenter Technology Corp., Reading, PA under contract to EPRI.The results of these tests have been published in EPRI Report TR-100784, June 1992'.The test conditions were 2000 PPM boric acid at 154'F for an exposure time of six months.The 154'F test temperature was based on the maximum allowable bulk pool water temperature for spent fuel storage pools.Specimen configurations included simple immersion, creviced, air-purged and galvanically-coupled specimens.

The galvanically-coupled specimens consisted of BSS coupled with Type 304.None of the twenty-six (26)simple immersion, creviced or air-purged specimens exhibited any measurable weight change with the exception of one specimen which had been welded.Two of the three galvanically-coupled specimens exhibited a very small weight loss, and the third no measurable weight change.Minor rusting was noted on the galvanically-coupled specimens.

The results of these tests indicated that BSS exhibits excellent corrosion resistance to spent fuel pool water at maximum pool operating temperatures.

In addition to the above tests at 154'F, elevated temperature corrosion tests of BSS have recently been conducted in 2450 PPM boric acid solution at 239'F using a recirculating autoclave'.

The selection of the test temperature was based on the highest local pool water temperature which could occur in any cell in the Ginna SFP (saturation temperature based on minimum height of 23 feet of water over any cell).The BSS material used for these tests was ASTM A887-89, Grade B, Type B7 with 1.9%boron, which is slightly higher than the maximum boron content of 1.82%in the BSS material intended for use in the Ginna SFP, and therefore is conservatively representative of the Ginna material.Test specimens included l U.S.NRC G.S.Vidsing A-3 October 10, 1997 simple immersion (free corrosion), galvanically-coupled and artificially-creviced (ASTM G 78-89)configurations.

The galvanically-coupled specimens included BSS coupled with Type 304L and with Zircaloy 4.Specimens were exposed for total times of 30 and 60 days (720 and 1440 hours0.0167 days <br />0.4 hours <br />0.00238 weeks <br />5.4792e-4 months <br />).The results of these tests showed that all specimens exhibited stable, passive behavior in the boric acid environment with very low corrosion rates.The average corrosion rate for the simple immersion and creviced BSS specimens was.0167 Mils Per Year (MPY)and.0320 MPY, respectively.

The average corrosion rate for the galvanically coupled BSS specimens was.033 MPY.These corrosion rates indicate that in the worst case condition (i.e.BSS galvanically coupled to 304L and Zircaloy 4 at a sustained water temperature of 239'F), the thickness loss over a 40 year exposure would be on the order of 1.3 mils (.0013"), or approximately 1%of the total thickness of a BSS sheet.The minimum required thickness of the BSS sheet material for the Ginna SFP racks was 2.5 mm (.098")or 3.0 mm (.118"), depending on rack type.The actual thickness of the finished sheets, however, exceeded the minimum thickness by a considerable margin.For the 2.5 mm sheets, the actual thickness values measured during final dimensional checks on the sheets (each sheet was measured)were in the range 2.65 mm-2.90 mm (.104"-.114")and for the 3.0 mm sheets, 3.15 mm-3.50 mm (.124"-.138").It cari be seen that a loss of thickness due to corrosion on the order of.001"-.002" is much less than the extra margin in thickness in the plates and therefore does not result in a violation of the assumptions in the licensing report.The loss of neutron absorber thickness due to galvanic corrosion is therefore negligible and cannot lead to degradation of the absorber material below minimum design criteria.It should be noted that exposure of the BSS material at such a high temperature (239'F)for prolonged periods of time is an extreme condition which does not represent normal pool operating conditions.

The exit temperatures for local fuel bundle cooling, based on bounding conditions, are well below the temperature of 239'F.'s a result, the corrosion rates expected from exposure of the BSS panels to normal pool operating conditions would be significantly lower than those at the elevated temperatures.

The corrosion rates measured in the elevated temperature tests, therefore, represent a bounding condition.

~Reference 1.Smith, R.J., Loomis, G.W., Deltete, C.P., Borated tainless Steel A lication in S en-F iel tora e Racks, EPRI TR-100784, Project 2813-21, Final Report, June 1992, p.3-25.2.ATEA Technical Specification 2226.031.000, Borated Stainless Steel A licati n in~Fuel Rack.

I'll+II a,.5 U.S.NRC G.S.Vidsing October 10, 1997 3.Letter from R.C.Mecredy (RG&E)to G.S.Vissing (NRC), dated March 31, 1997;

SUBJECT:

APPLICATION FOR AMENDMENT TO FACILITY OPERATING LICENSE, REVISED SPENT FUEL POOL STORAGE REQUIREMENTS.

ATTACHMENT:

R.E.GINNA NUCLEAR POWER PLANT, SPENT FUEL POOL RERACKING, LICENSING REPORT, SECTION 5.0, THERMAL-HYDRAULIC EVALUATION.

U.,S.NRC G.S.Vissing A-5 October 10, 1997 uestion No.3: Describe the inspection program of borated stainless steel panels before their incorporation into the spent fuel racks.Re~once:~Back round The borated stainless steel for the Ginna SFP racks was specified as ASTM A887-89, Grade B, Type B6/B7 with a minimum boron content of 1.70%.Borated stainless steel (BSS)heats were electric-furnace melted and bottom-poured into ingots at the BOHLER/UDDEHOLM melt facility in Kapfenberg, Austria.The steel chemistry is based on Type 304 stainless steel.The carbon content is restricted to.04%max., and phosphorus, sulfur, and nitrogen are controlled at very low levels.Heat analyses are checked by extracting a chill cast sample from each melt and analyzing spectrographically prior to pouring the ingots.The heat analyses for the four heats of material melted for the Ginna SFP racks are listed in Table 1.Ingots were hot-reduced to slabs, and then further reduced by hot-rolling to sheets at BOHLER Bleche in Honigsberg, Austria.The rolling process consisted of reductions in the principal (longitudinal) rolling direction to approximately 10 mm thickness, then further reduction by cross-rolling in the transverse direction, and final rolling in the principal direction to final thickness.

After hot rolling, finishing operations were performed at BOHLER Bleche, Murzzuschlag, Austria.These operations included roller leveling, solution annealing, surface grinding, laser cutting to specified sheet dimensions, and pickling.Sheet product was divided into lots during the finishing operations.

A lot was defined as product from one heat, one heat-treatment batch, and one thickness.

The BSS material for the Ginna SFP consisted of eleven (11)lots.Ins ections and Test Perf rmed at BOHLER Bleche The following inspections of the BSS sheets were performed at BOHLER Bleche prior to final acceptance of the material:~Visual Inspection Both sides of each sheet were visually inspected after grinding for the presence of U.S.NRC G.S.Vidsing A-6 October 10, 1997 burrs, scratches, or other surface blemishes which might interfere with or cause damage to fuel assemblies during insertion into, or removal from, the racks.Such surface conditions were dressed by buffing or light sanding.~Dimensional Inspections The length and width of each sheet was measured.The thickness of each sheet was measured at six different locations using calibrated micrometers.

~Mechanical Properties Ultimate tensile strength, yield strength, elongation, and hardness were measured by destructive tensile testing on a sample cut from one sheet from each lot.The results of these tests all meet the mechanical properties requirements of ASTM A887-89 (see Table 2).The excellent ductility values (10%-16%, substantially above the minimum specification requirement of 6%)are indicative of homogeneous distribution of fine borides in the material.It should be noted that although the product fully meets the ASTM acceptance criteria, there are no design requirements for mechanical properties of BSS in the Ginna SFP application.

Chemical Analyses (Product analyses by wet chemical analysis)Product chemical analyses were obtained from a sample cut from one sheet from each heat.In addition, samples were cut from one sheet from each lot and analyzed for carbon and boron.Boron analyses were performed by digestion of the sample into aqueous solution and analyzing by ICP (Inductively Coupled Plasma).The results of these analyses are presented in Table 3.All values meet the chemical requirements of ASTM A887-89 Type B6/B7.All boron values exceed the minimum requirement of 1.70%;-It should be noted that the product analyses in Table 3 are in excellent agreement with the heat analyses (Table 1).Chemical Analyses (Boron content by wet chemical analysis)Fifty (50)locations within one sheet from Heat C70780 were sampled and analyzed for boron to establish the homogeneity of boron distribution within one sheet.These values all fell within the range 1.78%to 1.82%boron (mean value 1.80%, standard deviation.0117%boron).Chemical Analyses (Boron content by wet chemical analysis)One sample was cut from each of 51 sheets selected from the total population of 380 sheets and analyzed for boron content.The number of samples selected from each of 0~'r U.S.NRC G.S.Vissing A-7 October 10, 1997 the four heats and the range of boron values for each sample set is as follows: Total Sheets~am le Size%Boron Heat B00021 Heat B04901 Heat C70780 Heat C70796 13 8 279 80 13 samples 8 samples 20 samples 10 samples 1.75-1.77%

1.75-1.77%

1.79-1.81%1.75-1.79%

~'EN-3 Neutron Attenuation Measurements Descri tion of JEN-3 Device and Te.Me h d The JEN-3 device is a solid state detector which contains a Cf-252 source.The device is shaped like a teapot with a handle.The front half of the device is the detector, and the back half contains the source.The handle is approximately 2 feet in length.The dose at the top of the device is 30 mrem/hour.

The efficiency for neutrons is approximately 0.1%.A table which is used to reflect neutrons is made of polyethylene which is approximately 3" thick.The borated stainless steel (BSS)sheet to be analyzed is placed between the detector and the table.The neutrons which are emitted by the source pass through the stainless steel and are then reflected back by the plastic table.The energy of the neutrons is also reduced.Those thermalized neutrons are attenuated by the borated stainless steel.The fewer the counts recorded by the detector, the greater the boron loading in the BSS sheets.The boron loading calculations are influenced by the following factors: a)The actual percent boron;b)The thickness of the BSS sheet material;and c)The power supply for the detector.Initially, the power supply for the detector was a source of systematic error.After investigating the operating principles of the instrument, the source of error was eliminated and erroneous test results from the initial measurements were eliminated from consideration.

The ability of the JEN-3 instrument to function properly is influenced by both the thickness of the BSS material and the boron loading.The relationship between the counts recorded by the JEN-3 detector and boron loading is a negative exponential relationship.

All calibration curves were developed using log-log plots.

U.S.NRC G.S.Vihsing A-8 October 10, 1997 Ins ection Pro ram Calibration Curve-A calibration curve for the statistical analysis of BSS was developed using destructive chemical testing and neutron albedo analysis with the JEN-3.The response of the JEN-3 device as a function of boron loading in BSS sheets of varying boron content and thickness was established using destructive chemical analysis.Boron content ranged from 1.2%to 1.9%, and sheet thickness from 2.0 mm to 3.5 mm.Boron analyses were performed by BOHLER at the corporate chemistry laboratory in Kapfenburg, Austria.Thickness was measured using a calibrated ultrasonic thickness meter (calibration records for the meter and technician training records were reviewed and found to be satisfactory).

The JEN-3 device was response checked on a daily basis to verify instrument operability.

These records were maintained for review and approval during all QA surveillance activities performed by FTI, ATEA, or RG&E.The resulting calibration curve was a negative exponential line (log-log plot)with a correlation confidence of approximately 99.9%.2)Verification of Boron Content-The neutron attenuation characteristics of all BSS sheets was measured at one randomly selected location using the JEN-3 device.Sheet thickness was also measured at the exact location where the JEN-3 measurement was taken.The boron loading in each sheet was calculated from the JEN-3 measurement using the equation developed from the calibration curve.In order to account for all of the statistical errors in the JEN-3 measurement process, the minimum acceptable level of boron for any sheet was established as 1.74%.This minimum limit provides an additional margin of safety in boron loading.With 1.74%as the minimum acceptable calculated boron loading, there is greater than 95%confidence that no BSS sheets contained less than 1.70%boron.This level of confidence provides a margin of safety in the criticality calculations.

Neutron attenuation data of all BSS sheets, as measured by JEN-3 at one randomly selected location in each sheet, was reviewed by an independent statistical consultant retained by RG&E;Joseph O.Voelkel, PhD., Assistant U.S.NRC G.S.Vidsing A-9 October 10, 1997 Professor of Statistics at the College of Engineering, Rochester Institute of Technology.

His conclusions, based on both parametric and non-parametric tolerance intervals, confirmed the acceptance criteria, described above.3)Boron Homogeneity

-Thirty-four (34)BSS sheets were randomly chosen from the total population.

A neutron attenuation measurement was taken at five (5)randomly selected locations on each sheet using the JEN-3 device.This sampling plan was in accordance with the instructions of ASTM-E826,"Standard Practice for Testing Homogeneity of Materials for the Development of Reference Materials." Thickness measurements were taken at the exact locations where the JEN-3 measurements were taken.The data were then evaluated by statistical tests as follows: Ranges (maximum minus minimum measured value)were calculated for each of the 34 sets of 5 JEN-3 values.These were plotted against the calculated mean range and 2-sigma values.If no values fell outside the 2-sigma limits, this would be one indication of homogeneity within the population.

This was indeed the case;i.e., all values were within 2-sigma limits.Analysis Of Variance under the random effects model was performed on the data.Residual model diagnostics demonstrated a random distribution of residuals, indicating homogeneity of boron distribution throughout the BSS population.

These results strongly indicate homogeneity of boron distribution throughout the BSS product.Ins ections and Tests Performed b Rochester Gas A, Electric Co~Chemical Analysis Overchecks (Boron content by wet chemical analysis)Chemical analysis overchecks on samples of BSS obtained from BOHLER were performed by two independent commercial testing laboratories in the US.These analyses were obtained to provide additional confidence in the boron analyses reported by BOHLER.Results of these tests are presented in Table 4.The results of the these overchecks indicate that the boron analyses reported by BOHLER are reliable.~Metallographic Examinations U,S.NRC G.S.Vissing A-10 October 10, 1997 Samples cut from one sheet from each lot of material in both the principal and transverse rolling directions were examined metallographically.

All specimens were polished and etched with Kallings reagent.The microstructures in both longitudinal and transverse cross-sections exhibit a fine,'niform dispersion of borides in an austenitic matrix.No evidence of banding or segregation are present.The boride homogeneity in the BOHLER material compares very favorably with published microstructures of Grade A material produced by powdered metallurgy methods'.ualit Assurance'Over i h Additional inspections were provided as part of Quality Assurance oversight.

Bohler activities were subject to quality surveillance by personnel from the Bohler, ATEA, Framatome Technologies, and Rochester Gas&Electric Quality Assurance organizations.

This oversight provided independent monitoring of the BSS manufacturing process and results of inspection activities at Bohler.~

Reference:

1.Smith, R.J., Loomis, G.W., Deltete, C.P., Borated Stainle.s Steel A lication in en-Fuel Stora e Rack., EPRI TR-100784, Project 2813-21, Final Report, June 1992, p.3-13.

U.,S.NRC G.S.Vissing A-11 October 10, 1997 TABLE 1 Heat Anal ses C Si Mn P S Cr Ni B N C70780 C70796 B00021 B04901 ASTM A887 Type B6 ASTM A887 Type B7.021.33 1.13.013 ,001 19.89 12.50 1.81.018.029.34 1.06.012.001 19.96 12.64 1.76.021.020.55 1.18.009.002 19.69 13.18 1.76.027.013.42 1.21.008.001 19.50 13.21 1.75.015.08'5'.0'45'3'8.0 12.0 1.5 10'20.0 15.0 1.74 081 751 2 Pl 0451 03l 18 P 12 Q 1 75 1PI 20.0 15.0 2.25 Note 1: Maximum value TABLE 2 Mechanical Pro erties H~eat L~ot C70796 290 C70796 314 C70780 287 C70780 282 C70780 313 C70780 288 C70780 289 B00021 221 B00021 223 B04901 224 B04901 222 UTS~Y~EIon ation Hardness~SI~KSI~oin 2"~Brinell 94.7 66.4 12.3 195 96.0 62.1 11.7 219 99.1 65.3 12.2 209 93.1 61.2 14.1 239 94.7 55.3 10.6 229 97.5 63.8 11.2 199 95.9 56.7 16.8 239 94.4 62.8 10.9 224 97.2 61.8 12.2 229 93.0 58.3 13.8 234 95.3 66.1 12.3 229 ASTM A887-89 75 Min 30 Min 6.0 Min 241 Max U.S.NRC G.S.Vissing A-12 October 10, 1997 TABLE 3~d~C Si Mn P S Cr Ni B N C B00021 221 B00021 223 B04901 222 B04901 224 C70780 282 C70780 287 C70780 288 C70780 289 C70780 313 C70796 290 C70796 314.021.55 1.18.008.003 19.7 13~1.020.009.43 1.21.007.002 19.4 13~1.01.024.32 1.10.012.001 19.8 12.4.023.023.023.023.025.33 1.06.012.001 19.9 12.5.025 1.75.032 1.74 1.73.016 1.76 1.76.022 1.81 1,80 1.80 1.80 1.78.028 1.78 TABLE 4 Boron Anal sis Overcheck~Heat~Sheet C70780 105 C70780 105 C70780 105 Laboratory Bohler Ledoux M&P Labs%Boron 1.83%1.86%1.82%B00021 91 A B00021 371A B04901 11A B04901 171 A Ledoux M8cP Labs Ledoux MEcP Labs 1.82%1.84%1.82%1.85%

U.S.NRC G.S.Vilsing A-13 October 10, 1997 uestion¹4: Although tests with borated stainless steel have indicated that in the SFP environment no measurable corrosion degradation takes place, the importance of its role in reactivity control in the SFP makes it advisable to have a surveillance program which would provide additional assurance that at all times there will be enough poison material in the SFP.Are you planning to institute such a prograni in your plant?If so, describe the program.If not, provide your basis.~Res ense: RG&E plans to institute a surveillance program for borated stainless steel (BSS)in the SFP at the R.E.Ginna Nuclear Power Station.A coupon tree has been designed which consists of.a 304L stainless steel rack to which 36 BSS coupons (8" long X 6" wide)will be bolted.Each face and the edges of the coupons are exposed to the SFP boric acid environment.

Crevices and 304L/BSS galvanic couples are created on the tree at each bolt location.The coupons were selected so that material from each heat and lot of BSS sheet material to,be used as poison panels in the pool are represented on the tree.In comparison with surveillance programs for other neutron absorber materials, the design and construction of the coupon tree for the Ginna SFP provides a more accurate representation of the actual exposure conditions of BSS in the SFP.The tree will be removed and inspected after the first 18-month operating cycle, and every three operating cycles (approximately 4 1/2 years)thereafter.

The coupons will be removed from the tree, inspected visually for any evidence of corrosion, and thickness measurements taken on the exposed surfaces and in the creviced/galvanically coupled areas.These measurements will be compared with the original thickness measurements recorded for each coupon to determine if any measurable material loss has occurred.In addition, each coupon will be weighed and the weights compared with original weights to determine weight change.Any unusual surface condition suggestive of significant corrosion will be evaluated using appropriate analytical methods.

1~sl ir Cg-~I' s A U.S.NRC G.S.Vi~sing A-14 October 10, 1997 uestion¹5: With a larger number of fuel assemblies stored in the SFP it is expected that more corrosion products and other impurities will be generated in the SFP.Is the presently existing purtftcation system adequate to handle this increased amount of impurities?

Provide your basis.Recense: The current purification system consists of: (a)a string-wound skimmer filter for surface cleanliness, and (b)a spent fuel pool mixed bed resin for liquid purification.

The resin bed pulls from the bottom of the pool for its cleaning process.It is a 15 cubic foot mixed bed resin filtration system.The frequency of change-out of the surface filtration system is currently approximately once every two years.This is a surface clarity maintenance system.The additional fuel will not affect its operating characteristics.

The frequency of change-out for the resin system is currently once per year.Historical records following the 1985 rerack project at Ginna Station showed no measurable increase in the change-out frequency.

The 1985 change was larger in its work scope than the proposed modification.

At that time, approximately 420 cells were added.By comparison, the proposed modification will increase the storage capacity by 305 cells in 1998 (an additional 48 storage cells may be added in the future if needed)~It is postulated that the upcoming rerack will not increase the cleaning system change-out.

However, the system will be monitored to determine any changes to historical patterns.Therefore it can be concluded that the capacity of the purification system is adequate and can absorb the additional storage requirements without substantially affecting current plant maintenance capability to handle any increased amount of corrosion products and other impurities.

0 1'I/'h JF P