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{{#Wiki_filter:. | {{#Wiki_filter:.CATEGORY1REGULATOINFORMATION DISTRIBUTION | ||
'TEM(RIDS)ACCESSIONA'NBR:9710210233 DOC.DATE: | |||
97/10/10NOTARIZED: | |||
NOFACIL:50-244 RobertEmmetGinnaNuclearPlant,Unit1,Rochester GAUTH.NAME.;AUTHORAFFILIATION MECREDY,R.C. | |||
Rochester Gas6ElectricCorp.RECIP.NAME RECIPIENT AFFILIATION VISSINGIG.S. | |||
DOCKETI05000244I | |||
==SUBJECT:== | ==SUBJECT:== | ||
Forwardsresponsetoquestions fromNRCstaffonproposedmodofspentfuelstoragepool,dtd970331.DISTRIBUTION CODE:AOOIDCOPIESRECEIVED:LTR JENCLJSIZE:I+TITLE:ORSubmittal: | |||
GeneralDistribution NOTES:License Expdateinaccordance with10CFR2,2.109(9/19/72). | |||
05000244ERECIPIENT IDCODE/NAME PD1-1LAVISSINGEG. | |||
INTERN:FILECENTE/EMCBNRR/DSSA/SPLB NUDOCS-ABSTRACT EXTERNAL: | |||
NOACCOPIESLTTRENCL11111111111111RECIPIENT IDCODE/NAME PD1-1PDNRR/DE/ECGB/A NRR/DRCH/HICB NRR/DSSA/SRXB OGC/HDS3NRCPDRCOPIESLTTRENCL1111111110110RDNNOTETOALLNRIDS"RECIPIENTS: | |||
PLEASEHELPUSTOREDUCEWASTE.TOHAVEYOURNAMEORORGANIZATION REMOVEDFROMDISTRIBUTION LISTSORREDUCETHENUMBEROFCOPIESRECEIVEDBYYOUORYOURORGANIZATION, CONTACTTHEDOCUMENTCONTROLDESK(DCD)ONEXTENSION 415-2083TOTALNUMBEROFCOPIESREQUIRED: | |||
LTTR13ENCL12 ANDROCHESTER GA9ANDEIECTRICCORPORATION | |||
~89EASTAVENUE,ROCHESTER, N.Y14649-0001 AREACODE716546-2700ROBERTC.MECREDYVicepresident NuclearOperations October10,1997U.S.NuclearRegulatory Commission DocumentControlDeskAttn:GuyS.VissingProjectDirectorate I-1Washington, D.C.20555 | |||
==Subject:== | ==Subject:== | ||
ResponsetoQuestions fromNRCStaffonProposedModification oftheGinnaSpentFuelStoragePool(TACNo.M95759)R.E.GinnaNuclearPowerPlantDocketNo.50-244Ref.(1):LetterfromG.S.Vissing(NRC)toR.C.Mecredy(RGGE), | |||
==Subject:== | ==Subject:== | ||
RequestforAdditional Information | |||
-SpentFuelPoolModifications (TACNo.M95759),datedAugust25,1997. | |||
==DearMr.Vissing:== | ==DearMr.Vissing:== | ||
ByReference 1,theNRCstaffrequested additional information regarding theproposedModification oftheGinnaSpentFuelStoragePooldatedMarch31,1997.Enclosedareresponses toeachofthequestions submitted bytheNRCstaff.Veryrulyyours,RobertC.MecreJPO~'",fan97f02'f0233 97fOi0PDRADOCK05000244PPDRlllllllllllllllllllllllllllllllltlllllll Mr.GuyS.Vissing(MailStop14B2)SeniorProjectManagerProjectDirectorate I-1Washington, D.C.20555U.S.NuclearRegulatory Commission RegionI475Allendale RoadKingofPrussia,PA19406GinnaSeniorResidentInspector Mr.PaulD.EddyStateofNewYorkDepartment ofPublicService3EmpireStatePlaza',TenthFloorAlbany,NY12223-1350 U.S.NRCG.S.VissingA-1October10,1997uestionNo.1:Inthesubmittal youhaveindicated thatsomespentfuelrackswithBoraflex, usedpresently inthespentfitelpool(SFP),willberetained. | |||
Althoughtheanalysisdescribed inthesubmittal wasbasedonaveryconservative estimation ofthedegreeofBoraflexdegradation duringitsexposureintheSFP,experience hasshownthatthisdegradation dependsonseveralfactorswhichmaybedificulttoestimate. | |||
Forexample,maintaining lowsilicalevelintheSFPwatermayaccelerate degradation ofthepolymerwithconsequential higherlossonboroncarbide.Therefore, many,plantsinstituted surveillance programsconsisting ofinspection ofcouponsandlormeasurement ofsilicaconcentration intheSFPwater.Areyouintending tohaveaBoraflexsurveillance programinthererackedSFP?Ifso,describetheprogram.Ifnot,provideyourbasis.R~esense:RG&Ehascommitted tomonitorthereactivesilicalevelsinthespentfuelpoolonamonthlybasistodetectandevaluateunusualtrendsofabnormallevels(Reference 1).RG&Eiscurrently monitoring silicalevelsandwillcontinuethissurveillance afterreracking ofthespentfuelpool.BecausethespentfuelrackswithBoraflexdonothavecouponswhichwouldallowperiodicinspection, RG&EhasoutlinedinReference 1severalactionstomonitorthepotential forBoraflexdegradation. | |||
Someoftheseactivities, asdescribed inReference 1,willcontinueafter.theproposedreracking ofthespentfuelpool.Ifthereareanyquestions regarding thisactionplan,pleaseprovidearequestforadditional information. | |||
==Reference:== | ==Reference:== | ||
11.I.etterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedOctober24,1996; | 11.I.etterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedOctober24,1996; | ||
==SUBJECT:== | ==SUBJECT:== | ||
RESPONSETONRCGENERICLETI'ER96-04,DATEDJUNE26,1996, | RESPONSETONRCGENERICLETI'ER96-04,DATEDJUNE26,1996,ONBORAFLEXDEGRADATION INSPENTFUELRACKS. | ||
U.S.NRCG.S.Vis'singA-2October10,1997uestion.No.2:1nthenewfuelracks, | U.S.NRCG.S.Vis'singA-2October10,1997uestion.No. | ||
2:1nthenewfuelracks,boratedstainless steelpanelswillremainincontactwiththecomponents madefromaregularstainless steel.Becauseoftheslightlydiferentchemicalcomposition ofthesematerials, galvaniccellsmayforminaboricacidsolutionandthismaybeasourceofcorrosion. | |||
Showthatthisphenomenon willnotcontribute toasignificant degradation ofthepoisonmaterial. | |||
R~esoose:Theoretically, theuseofBoratedStainless Steel(BSS)panelsastheabsorbermaterialinSpentFuelStorageRacksisassessedasamuchmorebenigncondition thantheuseofporousaluminum-boron carbidepanels.Thelatter,whichareknowntohaveafargreaterpotential forchemicalreactionwiththepoolwaterundernormalpoolconditions, havebeenusedinSpentFuelStorageapplications inthepast.Inordertoverifythehypothesis thatBSSwillbeessentially inertunderpoolconditions, aseriesofcorrosion testshavebeenperformed underveryadverseconditions asdiscussed below.Corrosion testsofBSScouponsofvariousconfigurations andboroncontentswereconducted severalyearsagobyCarpenter Technology Corp.,Reading,PAundercontracttoEPRI.Theresultsofthesetestshavebeenpublished inEPRIReportTR-100784, June1992'.Thetestconditions were2000PPMboricacidat154'Fforanexposuretimeofsixmonths.The154'Ftesttemperature wasbasedonthemaximumallowable bulkpoolwatertemperature forspentfuelstoragepools.Specimenconfigurations includedsimpleimmersion, | |||
: creviced, air-purgedandgalvanically-coupled specimens. | |||
Thegalvanically-coupled specimens consisted ofBSScoupledwithType304.Noneofthetwenty-six (26)simpleimmersion, crevicedorair-purgedspecimens exhibited anymeasurable weightchangewiththeexception ofonespecimenwhichhadbeenwelded.Twoofthethreegalvanically-coupled specimens exhibited averysmallweightloss,andthethirdnomeasurable weightchange.Minorrustingwasnotedonthegalvanically-coupled specimens. | |||
Theresultsofthesetestsindicated thatBSSexhibitsexcellent corrosion resistance tospentfuelpoolwateratmaximumpooloperating temperatures. | |||
Inadditiontotheabovetestsat154'F,elevatedtemperature corrosion testsofBSShaverecentlybeenconducted in2450PPMboricacidsolutionat239'Fusingarecirculating autoclave'. | |||
Theselection ofthetesttemperature wasbasedonthehighestlocalpoolwatertemperature whichcouldoccurinanycellintheGinnaSFP(saturation temperature basedonminimumheightof23feetofwateroveranycell).TheBSSmaterialusedforthesetestswasASTMA887-89,GradeB,TypeB7with1.9%boron,whichisslightlyhigherthanthemaximumboroncontentof1.82%intheBSSmaterialintendedforuseintheGinnaSFP,andtherefore isconservatively representative oftheGinnamaterial. | |||
Testspecimens included lU.S.NRCG.S.VidsingA-3October10,1997simpleimmersion (freecorrosion), | |||
galvanically-coupled andartificially-creviced (ASTMG78-89)configurations. | |||
Thegalvanically-coupled specimens includedBSScoupledwithType304LandwithZircaloy4.Specimens wereexposedfortotaltimesof30and60days(720and1440hours).Theresultsofthesetestsshowedthatallspecimens exhibited stable,passivebehaviorintheboricacidenvironment withverylowcorrosion rates.Theaveragecorrosion rateforthesimpleimmersion andcrevicedBSSspecimens was.0167MilsPerYear(MPY)and.0320MPY,respectively. | |||
Theaveragecorrosion rateforthegalvanically coupledBSSspecimens was.033MPY.Thesecorrosion ratesindicatethatintheworstcasecondition (i.e.BSSgalvanically coupledto304LandZircaloy4atasustained watertemperature of239'F),thethickness lossovera40yearexposurewouldbeontheorderof1.3mils(.0013"), | |||
orapproximately 1%ofthetotalthickness ofaBSSsheet.Theminimumrequiredthickness oftheBSSsheetmaterialfortheGinnaSFPrackswas2.5mm(.098")or3.0mm(.118"),depending onracktype.Theactualthickness ofthefinishedsheets,however,exceededtheminimumthickness byaconsiderable margin.Forthe2.5mmsheets,theactualthickness valuesmeasuredduringfinaldimensional checksonthesheets(eachsheetwasmeasured) wereintherange2.65mm-2.90mm(.104"-.114")andforthe3.0mmsheets,3.15mm-3.50mm(.124"-.138").Itcaribeseenthatalossofthickness duetocorrosion ontheorderof.001"-.002" ismuchlessthantheextramargininthickness intheplatesandtherefore doesnotresultinaviolation oftheassumptions inthelicensing report.Thelossofneutronabsorberthickness duetogalvaniccorrosion istherefore negligible andcannotleadtodegradation oftheabsorbermaterialbelowminimumdesigncriteria. | |||
ItshouldbenotedthatexposureoftheBSSmaterialatsuchahightemperature (239'F)forprolonged periodsoftimeisanextremecondition whichdoesnotrepresent normalpooloperating conditions. | |||
Theexittemperatures forlocalfuelbundlecooling,basedonboundingconditions, arewellbelowthetemperature of239'F.'saresult,thecorrosion ratesexpectedfromexposureoftheBSSpanelstonormalpooloperating conditions wouldbesignificantly lowerthanthoseattheelevatedtemperatures. | |||
Thecorrosion ratesmeasuredintheelevatedtemperature tests,therefore, represent aboundingcondition. | |||
~Reference 1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedtainlessSteelAlicationinSen-FieltoraeRacks,EPRITR-100784, Project2813-21,FinalReport,June1992,p.3-25.2.ATEATechnical Specification 2226.031.000, BoratedStainless SteelAlicatinin~FuelRack. | |||
I'll+IIa,.5 U.S.NRCG.S.VidsingOctober10,19973.LetterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedMarch31,1997; | I'll+IIa,.5 U.S.NRCG.S.VidsingOctober10,19973.LetterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedMarch31,1997; | ||
==SUBJECT:== | ==SUBJECT:== | ||
APPLICATION FORAMENDMENT TOFACILITYOPERATING LICENSE,REVISEDSPENTFUELPOOLSTORAGEREQUIREMENTS. | |||
U.,S.NRCG.S.VissingA-5October10,1997uestionNo.3: | ATTACHMENT: | ||
U.S.NRCG.S.VihsingA-8October10, | R.E.GINNANUCLEARPOWERPLANT,SPENTFUELPOOLRERACKING, LICENSING REPORT,SECTION5.0,THERMAL-HYDRAULIC EVALUATION. | ||
U.,S.NRCG.S.VissingA-5October10,1997uestionNo.3:Describetheinspection programofboratedstainless steelpanelsbeforetheirincorporation intothespentfuelracks.Re~once:~BackroundTheboratedstainless steelfortheGinnaSFPrackswasspecified asASTMA887-89,GradeB,TypeB6/B7withaminimumboroncontentof1.70%.Boratedstainless steel(BSS)heatswereelectric-furnace meltedandbottom-poured intoingotsattheBOHLER/UDDEHOLM meltfacilityinKapfenberg, Austria.Thesteelchemistry isbasedonType304stainless steel.Thecarboncontentisrestricted to.04%max.,andphosphorus, sulfur,andnitrogenarecontrolled atverylowlevels.Heatanalysesarecheckedbyextracting achillcastsamplefromeachmeltandanalyzing spectrographically priortopouringtheingots.TheheatanalysesforthefourheatsofmaterialmeltedfortheGinnaSFPracksarelistedinTable1.Ingotswerehot-reduced toslabs,andthenfurtherreducedbyhot-rolling tosheetsatBOHLERBlecheinHonigsberg, Austria.Therollingprocessconsisted ofreductions intheprincipal (longitudinal) rollingdirection toapproximately 10mmthickness, thenfurtherreduction bycross-rolling inthetransverse direction, andfinalrollingintheprincipal direction tofinalthickness. | |||
Afterhotrolling,finishing operations wereperformed atBOHLERBleche,Murzzuschlag, Austria.Theseoperations includedrollerleveling, solutionannealing, surfacegrinding, lasercuttingtospecified sheetdimensions, andpickling. | |||
Sheetproductwasdividedintolotsduringthefinishing operations. | |||
Alotwasdefinedasproductfromoneheat,oneheat-treatment batch,andonethickness. | |||
TheBSSmaterialfortheGinnaSFPconsisted ofeleven(11)lots.InsectionsandTestPerfrmedatBOHLERBlecheThefollowing inspections oftheBSSsheetswereperformed atBOHLERBlechepriortofinalacceptance ofthematerial: | |||
~VisualInspection Bothsidesofeachsheetwerevisuallyinspected aftergrindingforthepresenceof U.S.NRCG.S.VidsingA-6October10,1997burrs,scratches, orothersurfaceblemishes whichmightinterfere withorcausedamagetofuelassemblies duringinsertion into,orremovalfrom,theracks.Suchsurfaceconditions weredressedbybuffingorlightsanding.~Dimensional Inspections Thelengthandwidthofeachsheetwasmeasured. | |||
Thethickness ofeachsheetwasmeasuredatsixdifferent locations usingcalibrated micrometers. | |||
~Mechanical Properties Ultimatetensilestrength, yieldstrength, elongation, andhardnessweremeasuredbydestructive tensiletestingonasamplecutfromonesheetfromeachlot.Theresultsofthesetestsallmeetthemechanical properties requirements ofASTMA887-89(seeTable2).Theexcellent ductility values(10%-16%,substantially abovetheminimumspecification requirement of6%)areindicative ofhomogeneous distribution offineboridesinthematerial. | |||
ItshouldbenotedthatalthoughtheproductfullymeetstheASTMacceptance | |||
: criteria, therearenodesignrequirements formechanical properties ofBSSintheGinnaSFPapplication. | |||
ChemicalAnalyses(Productanalysesbywetchemicalanalysis) | |||
Productchemicalanalyseswereobtainedfromasamplecutfromonesheetfromeachheat.Inaddition, sampleswerecutfromonesheetfromeachlotandanalyzedforcarbonandboron.Boronanalyseswereperformed bydigestion ofthesampleintoaqueoussolutionandanalyzing byICP(Inductively CoupledPlasma).Theresultsoftheseanalysesarepresented inTable3.Allvaluesmeetthechemicalrequirements ofASTMA887-89TypeB6/B7.Allboronvaluesexceedtheminimumrequirement of1.70%;-It shouldbenotedthattheproductanalysesinTable3areinexcellent agreement withtheheatanalyses(Table1).ChemicalAnalyses(Boroncontentbywetchemicalanalysis) | |||
Fifty(50)locations withinonesheetfromHeatC70780weresampledandanalyzedforborontoestablish thehomogeneity ofborondistribution withinonesheet.Thesevaluesallfellwithintherange1.78%to1.82%boron(meanvalue1.80%,standarddeviation | |||
.0117%boron).ChemicalAnalyses(Boroncontentbywetchemicalanalysis) | |||
Onesamplewascutfromeachof51sheetsselectedfromthetotalpopulation of380sheetsandanalyzedforboroncontent.Thenumberofsamplesselectedfromeachof 0~'r U.S.NRCG.S.VissingA-7October10,1997thefourheatsandtherangeofboronvaluesforeachsamplesetisasfollows:TotalSheets~amleSize%BoronHeatB00021HeatB04901HeatC70780HeatC707961382798013samples8samples20samples10samples1.75-1.77% | |||
1.75-1.77% | |||
1.79-1.81 | |||
%1.75-1.79% | |||
~'EN-3NeutronAttenuation Measurements DescritionofJEN-3DeviceandTe.MehdTheJEN-3deviceisasolidstatedetectorwhichcontainsaCf-252source.Thedeviceisshapedlikeateapotwithahandle.Thefronthalfofthedeviceisthedetector, andthebackhalfcontainsthesource.Thehandleisapproximately 2feetinlength.Thedoseatthetopofthedeviceis30mrem/hour. | |||
Theefficiency forneutronsisapproximately 0.1%.Atablewhichisusedtoreflectneutronsismadeofpolyethylene whichisapproximately 3"thick.Theboratedstainless steel(BSS)sheettobeanalyzedisplacedbetweenthedetectorandthetable.Theneutronswhichareemittedbythesourcepassthroughthestainless steelandarethenreflected backbytheplastictable.Theenergyoftheneutronsisalsoreduced.Thosethermalized neutronsareattenuated bytheboratedstainless steel.Thefewerthecountsrecordedbythedetector, thegreatertheboronloadingintheBSSsheets.Theboronloadingcalculations areinfluenced bythefollowing factors:a)Theactualpercentboron;b)Thethickness oftheBSSsheetmaterial; andc)Thepowersupplyforthedetector. | |||
Initially, thepowersupplyforthedetectorwasasourceofsystematic error.Afterinvestigating theoperating principles oftheinstrument, thesourceoferrorwaseliminated anderroneous testresultsfromtheinitialmeasurements wereeliminated fromconsideration. | |||
TheabilityoftheJEN-3instrument tofunctionproperlyisinfluenced byboththethickness oftheBSSmaterialandtheboronloading.Therelationship betweenthecountsrecordedbytheJEN-3detectorandboronloadingisanegativeexponential relationship. | |||
Allcalibration curvesweredeveloped usinglog-logplots. | |||
U.S.NRCG.S.VihsingA-8October10,1997InsectionProramCalibration Curve-Acalibration curveforthestatistical analysisofBSSwasdeveloped usingdestructive chemicaltestingandneutronalbedoanalysiswiththeJEN-3.TheresponseoftheJEN-3deviceasafunctionofboronloadinginBSSsheetsofvaryingboroncontentandthickness wasestablished usingdestructive chemicalanalysis. | |||
Boroncontentrangedfrom1.2%to1.9%,andsheetthickness from2.0mmto3.5mm.Boronanalyseswereperformed byBOHLERatthecorporate chemistry laboratory inKapfenburg, Austria.Thickness wasmeasuredusingacalibrated ultrasonic thickness meter(calibration recordsforthemeterandtechnician trainingrecordswerereviewedandfoundtobesatisfactory). | |||
TheJEN-3devicewasresponsecheckedonadailybasistoverifyinstrument operability. | |||
Theserecordsweremaintained forreviewandapprovalduringallQAsurveillance activities performed byFTI,ATEA,orRG&E.Theresulting calibration curvewasanegativeexponential line(log-logplot)withacorrelation confidence ofapproximately 99.9%.2)Verification ofBoronContent-Theneutronattenuation characteristics ofallBSSsheetswasmeasuredatonerandomlyselectedlocationusingtheJEN-3device.Sheetthickness wasalsomeasuredattheexactlocationwheretheJEN-3measurement wastaken.Theboronloadingineachsheetwascalculated fromtheJEN-3measurement usingtheequationdeveloped fromthecalibration curve.Inordertoaccountforallofthestatistical errorsintheJEN-3measurement process,theminimumacceptable levelofboronforanysheetwasestablished as1.74%.Thisminimumlimitprovidesanadditional marginofsafetyinboronloading.With1.74%astheminimumacceptable calculated boronloading,thereisgreaterthan95%confidence thatnoBSSsheetscontained lessthan1.70%boron.Thislevelofconfidence providesamarginofsafetyinthecriticality calculations. | |||
Neutronattenuation dataofallBSSsheets,asmeasuredbyJEN-3atonerandomlyselectedlocationineachsheet,wasreviewedbyanindependent statistical consultant retainedbyRG&E;JosephO.Voelkel,PhD.,Assistant U.S.NRCG.S.VidsingA-9October10,1997Professor ofStatistics attheCollegeofEngineering, Rochester Institute ofTechnology. | |||
Hisconclusions, basedonbothparametric andnon-parametric tolerance intervals, confirmed theacceptance | |||
: criteria, described above.3)BoronHomogeneity | |||
-Thirty-four (34)BSSsheetswererandomlychosenfromthetotalpopulation. | |||
Aneutronattenuation measurement wastakenatfive(5)randomlyselectedlocations oneachsheetusingtheJEN-3device.Thissamplingplanwasinaccordance withtheinstructions ofASTM-E826, "Standard PracticeforTestingHomogeneity ofMaterials fortheDevelopment ofReference Materials." | |||
Thickness measurements weretakenattheexactlocations wheretheJEN-3measurements weretaken.Thedatawerethenevaluated bystatistical testsasfollows:Ranges(maximumminusminimummeasuredvalue)werecalculated foreachofthe34setsof5JEN-3values.Thesewereplottedagainstthecalculated meanrangeand2-sigmavalues.Ifnovaluesfelloutsidethe2-sigmalimits,thiswouldbeoneindication ofhomogeneity withinthepopulation. | |||
Thiswasindeedthecase;i.e.,allvalueswerewithin2-sigmalimits.AnalysisOfVarianceundertherandomeffectsmodelwasperformed onthedata.Residualmodeldiagnostics demonstrated arandomdistribution ofresiduals, indicating homogeneity ofborondistribution throughout theBSSpopulation. | |||
Theseresultsstronglyindicatehomogeneity ofborondistribution throughout theBSSproduct.InsectionsandTestsPerformed bRochester GasA,ElectricCo~ChemicalAnalysisOverchecks (Boroncontentbywetchemicalanalysis) | |||
Chemicalanalysisoverchecks onsamplesofBSSobtainedfromBOHLERwereperformed bytwoindependent commercial testinglaboratories intheUS.Theseanalyseswereobtainedtoprovideadditional confidence intheboronanalysesreportedbyBOHLER.Resultsofthesetestsarepresented inTable4.Theresultsofthetheseoverchecks indicatethattheboronanalysesreportedbyBOHLERarereliable. | |||
~Metallographic Examinations U,S.NRCG.S.VissingA-10October10,1997Samplescutfromonesheetfromeachlotofmaterialinboththeprincipal andtransverse rollingdirections wereexaminedmetallographically. | |||
Allspecimens werepolishedandetchedwithKallingsreagent.Themicrostructures inbothlongitudinal andtransverse cross-sections exhibitafine,'niform dispersion ofboridesinanaustenitic matrix.Noevidenceofbandingorsegregation arepresent.Theboridehomogeneity intheBOHLERmaterialcomparesveryfavorably withpublished microstructures ofGradeAmaterialproducedbypowderedmetallurgy methods'. | |||
ualitAssurance | |||
'OverihAdditional inspections wereprovidedaspartofQualityAssurance oversight. | |||
Bohleractivities weresubjecttoqualitysurveillance bypersonnel fromtheBohler,ATEA,Framatome Technologies, andRochester Gas&ElectricQualityAssurance organizations. | |||
Thisoversight providedindependent monitoring oftheBSSmanufacturing processandresultsofinspection activities atBohler.~ | |||
==Reference:== | ==Reference:== | ||
1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedStainle. | |||
U.,S.NRCG.S.VissingA-11October10,1997TABLE1HeatAnalsesCSiMnPSCrNiBNC70780C70796B00021B04901ASTMA887TypeB6ASTMA887TypeB7.021.331.13.013,00119.8912.501.81.018.029.341.06.012.00119.9612.641.76.021.020.551.18.009.00219.6913.181.76.027.013.421.21.008.00119.5013.211.75.015.08'5'.0'45'3'8. | 1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedStainle.s SteelAlicationinen-FuelStoraeRack.,EPRITR-100784, Project2813-21,FinalReport,June1992,p.3-13. | ||
U.S.NRCG.S.VilsingA-13October10,1997uestion¹4: | U.,S.NRCG.S.VissingA-11October10,1997TABLE1HeatAnalsesCSiMnPSCrNiBNC70780C70796B00021B04901ASTMA887TypeB6ASTMA887TypeB7.021.331.13.013,00119.8912.501.81.018.029.341.06.012.00119.9612.641.76.021.020.551.18.009.00219.6913.181.76.027.013.421.21.008.00119.5013.211.75.015.08'5'.0'45'3'8.0 12.01.510'20.015.01.740817512Pl045103l18P12Q1751PI20.015.02.25Note1:MaximumvalueTABLE2Mechanical ProertiesH~eatL~otC70796290C70796314C70780287C70780282C70780313C70780288C70780289B00021221B00021223B04901224B04901222UTS~Y~EIonationHardness~SI~KSI~oin2"~Brinell94.766.412.319596.062.111.721999.165.312.220993.161.214.123994.755.310.622997.563.811.219995.956.716.823994.462.810.922497.261.812.222993.058.313.823495.366.112.3229ASTMA887-8975Min30Min6.0Min241Max U.S.NRCG.S.VissingA-12October10,1997TABLE3~d~CSiMnPSCrNiBNCB00021221B00021223B04901222B04901224C70780282C70780287C70780288C70780289C70780313C70796290C70796314.021.551.18.008.00319.713~1.020.009.431.21.007.00219.413~1.01.024.321.10.012.00119.812.4.023.023.023.023.025.331.06.012.00119.912.5.0251.75.0321.741.73.0161.761.76.0221.811,801.801.801.78.0281.78TABLE4BoronAnalsisOvercheck | ||
1~slirCg-~I' sAU.S.NRCG.S.Vi~singA-14October10,1997uestion¹5: | ~Heat~SheetC70780105C70780105C70780105Laboratory BohlerLedouxM&PLabs%Boron1.83%1.86%1.82%B0002191AB00021371AB0490111AB04901171ALedouxM8cPLabsLedouxMEcPLabs1.82%1.84%1.82%1.85% | ||
U.S.NRCG.S.VilsingA-13October10,1997uestion¹4:Althoughtestswithboratedstainless steelhaveindicated thatintheSFPenvironment nomeasurable corrosion degradation takesplace,theimportance ofitsroleinreactivity controlintheSFPmakesitadvisable tohaveasurveillance programwhichwouldprovideadditional assurance thatatalltimestherewillbeenoughpoisonmaterialintheSFP.Areyouplanningtoinstitute suchaprograniinyourplant?Ifso,describetheprogram.Ifnot,provideyourbasis.~Resense:RG&Eplanstoinstitute asurveillance programforboratedstainless steel(BSS)intheSFPattheR.E.GinnaNuclearPowerStation.Acoupontreehasbeendesignedwhichconsistsof.a304Lstainless steelracktowhich36BSScoupons(8"longX6"wide)willbebolted.EachfaceandtheedgesofthecouponsareexposedtotheSFPboricacidenvironment. | |||
Crevicesand304L/BSSgalvaniccouplesarecreatedonthetreeateachboltlocation. | |||
ThecouponswereselectedsothatmaterialfromeachheatandlotofBSSsheetmaterialto,beusedaspoisonpanelsinthepoolarerepresented onthetree.Incomparison withsurveillance programsforotherneutronabsorbermaterials, thedesignandconstruction ofthecoupontreefortheGinnaSFPprovidesamoreaccuraterepresentation oftheactualexposureconditions ofBSSintheSFP.Thetreewillberemovedandinspected afterthefirst18-monthoperating cycle,andeverythreeoperating cycles(approximately 41/2years)thereafter. | |||
Thecouponswillberemovedfromthetree,inspected visuallyforanyevidenceofcorrosion, andthickness measurements takenontheexposedsurfacesandinthecreviced/galvanically coupledareas.Thesemeasurements willbecomparedwiththeoriginalthickness measurements recordedforeachcoupontodetermine ifanymeasurable materiallosshasoccurred. | |||
Inaddition, eachcouponwillbeweighedandtheweightscomparedwithoriginalweightstodetermine weightchange.Anyunusualsurfacecondition suggestive ofsignificant corrosion willbeevaluated usingappropriate analytical methods. | |||
1~slirCg-~I' sAU.S.NRCG.S.Vi~singA-14October10,1997uestion¹5:Withalargernumberoffuelassemblies storedintheSFPitisexpectedthatmorecorrosion productsandotherimpurities willbegenerated intheSFP.Isthepresently existingpurtftcation systemadequatetohandlethisincreased amountofimpurities? | |||
Provideyourbasis.Recense:Thecurrentpurification systemconsistsof:(a)astring-wound skimmerfilterforsurfacecleanliness, and(b)aspentfuelpoolmixedbedresinforliquidpurification. | |||
Theresinbedpullsfromthebottomofthepoolforitscleaningprocess.Itisa15cubicfootmixedbedresinfiltration system.Thefrequency ofchange-out ofthesurfacefiltration systemiscurrently approximately onceeverytwoyears.Thisisasurfaceclaritymaintenance system.Theadditional fuelwillnotaffectitsoperating characteristics. | |||
Thefrequency ofchange-out fortheresinsystemiscurrently onceperyear.Historical recordsfollowing the1985rerackprojectatGinnaStationshowednomeasurable increaseinthechange-out frequency. | |||
The1985changewaslargerinitsworkscopethantheproposedmodification. | |||
Atthattime,approximately 420cellswereadded.Bycomparison, theproposedmodification willincreasethestoragecapacityby305cellsin1998(anadditional 48storagecellsmaybeaddedinthefutureifneeded)~Itispostulated thattheupcomingrerackwillnotincreasethecleaningsystemchange-out. | |||
However,thesystemwillbemonitored todetermine anychangestohistorical patterns. | |||
Therefore itcanbeconcluded thatthecapacityofthepurification systemisadequateandcanabsorbtheadditional storagerequirements withoutsubstantially affecting currentplantmaintenance capability tohandleanyincreased amountofcorrosion productsandotherimpurities. | |||
01'I/'hJFP}} | 01'I/'hJFP}} |
Revision as of 11:40, 29 June 2018
ML17264B072 | |
Person / Time | |
---|---|
Site: | Ginna |
Issue date: | 10/10/1997 |
From: | MECREDY R C ROCHESTER GAS & ELECTRIC CORP. |
To: | VISSING G S NRC (Affiliation Not Assigned), NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM) |
References | |
TAC-M95759, NUDOCS 9710210233 | |
Download: ML17264B072 (22) | |
Text
.CATEGORY1REGULATOINFORMATION DISTRIBUTION
'TEM(RIDS)ACCESSIONA'NBR:9710210233 DOC.DATE:
97/10/10NOTARIZED:
NOFACIL:50-244 RobertEmmetGinnaNuclearPlant,Unit1,Rochester GAUTH.NAME.;AUTHORAFFILIATION MECREDY,R.C.
Rochester Gas6ElectricCorp.RECIP.NAME RECIPIENT AFFILIATION VISSINGIG.S.
DOCKETI05000244I
SUBJECT:
Forwardsresponsetoquestions fromNRCstaffonproposedmodofspentfuelstoragepool,dtd970331.DISTRIBUTION CODE:AOOIDCOPIESRECEIVED:LTR JENCLJSIZE:I+TITLE:ORSubmittal:
GeneralDistribution NOTES:License Expdateinaccordance with10CFR2,2.109(9/19/72).
05000244ERECIPIENT IDCODE/NAME PD1-1LAVISSINGEG.
INTERN:FILECENTE/EMCBNRR/DSSA/SPLB NUDOCS-ABSTRACT EXTERNAL:
NOACCOPIESLTTRENCL11111111111111RECIPIENT IDCODE/NAME PD1-1PDNRR/DE/ECGB/A NRR/DRCH/HICB NRR/DSSA/SRXB OGC/HDS3NRCPDRCOPIESLTTRENCL1111111110110RDNNOTETOALLNRIDS"RECIPIENTS:
PLEASEHELPUSTOREDUCEWASTE.TOHAVEYOURNAMEORORGANIZATION REMOVEDFROMDISTRIBUTION LISTSORREDUCETHENUMBEROFCOPIESRECEIVEDBYYOUORYOURORGANIZATION, CONTACTTHEDOCUMENTCONTROLDESK(DCD)ONEXTENSION 415-2083TOTALNUMBEROFCOPIESREQUIRED:
LTTR13ENCL12 ANDROCHESTER GA9ANDEIECTRICCORPORATION
~89EASTAVENUE,ROCHESTER, N.Y14649-0001 AREACODE716546-2700ROBERTC.MECREDYVicepresident NuclearOperations October10,1997U.S.NuclearRegulatory Commission DocumentControlDeskAttn:GuyS.VissingProjectDirectorate I-1Washington, D.C.20555
Subject:
ResponsetoQuestions fromNRCStaffonProposedModification oftheGinnaSpentFuelStoragePool(TACNo.M95759)R.E.GinnaNuclearPowerPlantDocketNo.50-244Ref.(1):LetterfromG.S.Vissing(NRC)toR.C.Mecredy(RGGE),
Subject:
RequestforAdditional Information
-SpentFuelPoolModifications (TACNo.M95759),datedAugust25,1997.
DearMr.Vissing:
ByReference 1,theNRCstaffrequested additional information regarding theproposedModification oftheGinnaSpentFuelStoragePooldatedMarch31,1997.Enclosedareresponses toeachofthequestions submitted bytheNRCstaff.Veryrulyyours,RobertC.MecreJPO~'",fan97f02'f0233 97fOi0PDRADOCK05000244PPDRlllllllllllllllllllllllllllllllltlllllll Mr.GuyS.Vissing(MailStop14B2)SeniorProjectManagerProjectDirectorate I-1Washington, D.C.20555U.S.NuclearRegulatory Commission RegionI475Allendale RoadKingofPrussia,PA19406GinnaSeniorResidentInspector Mr.PaulD.EddyStateofNewYorkDepartment ofPublicService3EmpireStatePlaza',TenthFloorAlbany,NY12223-1350 U.S.NRCG.S.VissingA-1October10,1997uestionNo.1:Inthesubmittal youhaveindicated thatsomespentfuelrackswithBoraflex, usedpresently inthespentfitelpool(SFP),willberetained.
Althoughtheanalysisdescribed inthesubmittal wasbasedonaveryconservative estimation ofthedegreeofBoraflexdegradation duringitsexposureintheSFP,experience hasshownthatthisdegradation dependsonseveralfactorswhichmaybedificulttoestimate.
Forexample,maintaining lowsilicalevelintheSFPwatermayaccelerate degradation ofthepolymerwithconsequential higherlossonboroncarbide.Therefore, many,plantsinstituted surveillance programsconsisting ofinspection ofcouponsandlormeasurement ofsilicaconcentration intheSFPwater.Areyouintending tohaveaBoraflexsurveillance programinthererackedSFP?Ifso,describetheprogram.Ifnot,provideyourbasis.R~esense:RG&Ehascommitted tomonitorthereactivesilicalevelsinthespentfuelpoolonamonthlybasistodetectandevaluateunusualtrendsofabnormallevels(Reference 1).RG&Eiscurrently monitoring silicalevelsandwillcontinuethissurveillance afterreracking ofthespentfuelpool.BecausethespentfuelrackswithBoraflexdonothavecouponswhichwouldallowperiodicinspection, RG&EhasoutlinedinReference 1severalactionstomonitorthepotential forBoraflexdegradation.
Someoftheseactivities, asdescribed inReference 1,willcontinueafter.theproposedreracking ofthespentfuelpool.Ifthereareanyquestions regarding thisactionplan,pleaseprovidearequestforadditional information.
Reference:
11.I.etterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedOctober24,1996;
SUBJECT:
RESPONSETONRCGENERICLETI'ER96-04,DATEDJUNE26,1996,ONBORAFLEXDEGRADATION INSPENTFUELRACKS.
U.S.NRCG.S.Vis'singA-2October10,1997uestion.No.
2:1nthenewfuelracks,boratedstainless steelpanelswillremainincontactwiththecomponents madefromaregularstainless steel.Becauseoftheslightlydiferentchemicalcomposition ofthesematerials, galvaniccellsmayforminaboricacidsolutionandthismaybeasourceofcorrosion.
Showthatthisphenomenon willnotcontribute toasignificant degradation ofthepoisonmaterial.
R~esoose:Theoretically, theuseofBoratedStainless Steel(BSS)panelsastheabsorbermaterialinSpentFuelStorageRacksisassessedasamuchmorebenigncondition thantheuseofporousaluminum-boron carbidepanels.Thelatter,whichareknowntohaveafargreaterpotential forchemicalreactionwiththepoolwaterundernormalpoolconditions, havebeenusedinSpentFuelStorageapplications inthepast.Inordertoverifythehypothesis thatBSSwillbeessentially inertunderpoolconditions, aseriesofcorrosion testshavebeenperformed underveryadverseconditions asdiscussed below.Corrosion testsofBSScouponsofvariousconfigurations andboroncontentswereconducted severalyearsagobyCarpenter Technology Corp.,Reading,PAundercontracttoEPRI.Theresultsofthesetestshavebeenpublished inEPRIReportTR-100784, June1992'.Thetestconditions were2000PPMboricacidat154'Fforanexposuretimeofsixmonths.The154'Ftesttemperature wasbasedonthemaximumallowable bulkpoolwatertemperature forspentfuelstoragepools.Specimenconfigurations includedsimpleimmersion,
- creviced, air-purgedandgalvanically-coupled specimens.
Thegalvanically-coupled specimens consisted ofBSScoupledwithType304.Noneofthetwenty-six (26)simpleimmersion, crevicedorair-purgedspecimens exhibited anymeasurable weightchangewiththeexception ofonespecimenwhichhadbeenwelded.Twoofthethreegalvanically-coupled specimens exhibited averysmallweightloss,andthethirdnomeasurable weightchange.Minorrustingwasnotedonthegalvanically-coupled specimens.
Theresultsofthesetestsindicated thatBSSexhibitsexcellent corrosion resistance tospentfuelpoolwateratmaximumpooloperating temperatures.
Inadditiontotheabovetestsat154'F,elevatedtemperature corrosion testsofBSShaverecentlybeenconducted in2450PPMboricacidsolutionat239'Fusingarecirculating autoclave'.
Theselection ofthetesttemperature wasbasedonthehighestlocalpoolwatertemperature whichcouldoccurinanycellintheGinnaSFP(saturation temperature basedonminimumheightof23feetofwateroveranycell).TheBSSmaterialusedforthesetestswasASTMA887-89,GradeB,TypeB7with1.9%boron,whichisslightlyhigherthanthemaximumboroncontentof1.82%intheBSSmaterialintendedforuseintheGinnaSFP,andtherefore isconservatively representative oftheGinnamaterial.
Testspecimens included lU.S.NRCG.S.VidsingA-3October10,1997simpleimmersion (freecorrosion),
galvanically-coupled andartificially-creviced (ASTMG78-89)configurations.
Thegalvanically-coupled specimens includedBSScoupledwithType304LandwithZircaloy4.Specimens wereexposedfortotaltimesof30and60days(720and1440hours).Theresultsofthesetestsshowedthatallspecimens exhibited stable,passivebehaviorintheboricacidenvironment withverylowcorrosion rates.Theaveragecorrosion rateforthesimpleimmersion andcrevicedBSSspecimens was.0167MilsPerYear(MPY)and.0320MPY,respectively.
Theaveragecorrosion rateforthegalvanically coupledBSSspecimens was.033MPY.Thesecorrosion ratesindicatethatintheworstcasecondition (i.e.BSSgalvanically coupledto304LandZircaloy4atasustained watertemperature of239'F),thethickness lossovera40yearexposurewouldbeontheorderof1.3mils(.0013"),
orapproximately 1%ofthetotalthickness ofaBSSsheet.Theminimumrequiredthickness oftheBSSsheetmaterialfortheGinnaSFPrackswas2.5mm(.098")or3.0mm(.118"),depending onracktype.Theactualthickness ofthefinishedsheets,however,exceededtheminimumthickness byaconsiderable margin.Forthe2.5mmsheets,theactualthickness valuesmeasuredduringfinaldimensional checksonthesheets(eachsheetwasmeasured) wereintherange2.65mm-2.90mm(.104"-.114")andforthe3.0mmsheets,3.15mm-3.50mm(.124"-.138").Itcaribeseenthatalossofthickness duetocorrosion ontheorderof.001"-.002" ismuchlessthantheextramargininthickness intheplatesandtherefore doesnotresultinaviolation oftheassumptions inthelicensing report.Thelossofneutronabsorberthickness duetogalvaniccorrosion istherefore negligible andcannotleadtodegradation oftheabsorbermaterialbelowminimumdesigncriteria.
ItshouldbenotedthatexposureoftheBSSmaterialatsuchahightemperature (239'F)forprolonged periodsoftimeisanextremecondition whichdoesnotrepresent normalpooloperating conditions.
Theexittemperatures forlocalfuelbundlecooling,basedonboundingconditions, arewellbelowthetemperature of239'F.'saresult,thecorrosion ratesexpectedfromexposureoftheBSSpanelstonormalpooloperating conditions wouldbesignificantly lowerthanthoseattheelevatedtemperatures.
Thecorrosion ratesmeasuredintheelevatedtemperature tests,therefore, represent aboundingcondition.
~Reference 1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedtainlessSteelAlicationinSen-FieltoraeRacks,EPRITR-100784, Project2813-21,FinalReport,June1992,p.3-25.2.ATEATechnical Specification 2226.031.000, BoratedStainless SteelAlicatinin~FuelRack.
I'll+IIa,.5 U.S.NRCG.S.VidsingOctober10,19973.LetterfromR.C.Mecredy(RG&E)toG.S.Vissing(NRC),datedMarch31,1997;
SUBJECT:
APPLICATION FORAMENDMENT TOFACILITYOPERATING LICENSE,REVISEDSPENTFUELPOOLSTORAGEREQUIREMENTS.
ATTACHMENT:
R.E.GINNANUCLEARPOWERPLANT,SPENTFUELPOOLRERACKING, LICENSING REPORT,SECTION5.0,THERMAL-HYDRAULIC EVALUATION.
U.,S.NRCG.S.VissingA-5October10,1997uestionNo.3:Describetheinspection programofboratedstainless steelpanelsbeforetheirincorporation intothespentfuelracks.Re~once:~BackroundTheboratedstainless steelfortheGinnaSFPrackswasspecified asASTMA887-89,GradeB,TypeB6/B7withaminimumboroncontentof1.70%.Boratedstainless steel(BSS)heatswereelectric-furnace meltedandbottom-poured intoingotsattheBOHLER/UDDEHOLM meltfacilityinKapfenberg, Austria.Thesteelchemistry isbasedonType304stainless steel.Thecarboncontentisrestricted to.04%max.,andphosphorus, sulfur,andnitrogenarecontrolled atverylowlevels.Heatanalysesarecheckedbyextracting achillcastsamplefromeachmeltandanalyzing spectrographically priortopouringtheingots.TheheatanalysesforthefourheatsofmaterialmeltedfortheGinnaSFPracksarelistedinTable1.Ingotswerehot-reduced toslabs,andthenfurtherreducedbyhot-rolling tosheetsatBOHLERBlecheinHonigsberg, Austria.Therollingprocessconsisted ofreductions intheprincipal (longitudinal) rollingdirection toapproximately 10mmthickness, thenfurtherreduction bycross-rolling inthetransverse direction, andfinalrollingintheprincipal direction tofinalthickness.
Afterhotrolling,finishing operations wereperformed atBOHLERBleche,Murzzuschlag, Austria.Theseoperations includedrollerleveling, solutionannealing, surfacegrinding, lasercuttingtospecified sheetdimensions, andpickling.
Sheetproductwasdividedintolotsduringthefinishing operations.
Alotwasdefinedasproductfromoneheat,oneheat-treatment batch,andonethickness.
TheBSSmaterialfortheGinnaSFPconsisted ofeleven(11)lots.InsectionsandTestPerfrmedatBOHLERBlecheThefollowing inspections oftheBSSsheetswereperformed atBOHLERBlechepriortofinalacceptance ofthematerial:
~VisualInspection Bothsidesofeachsheetwerevisuallyinspected aftergrindingforthepresenceof U.S.NRCG.S.VidsingA-6October10,1997burrs,scratches, orothersurfaceblemishes whichmightinterfere withorcausedamagetofuelassemblies duringinsertion into,orremovalfrom,theracks.Suchsurfaceconditions weredressedbybuffingorlightsanding.~Dimensional Inspections Thelengthandwidthofeachsheetwasmeasured.
Thethickness ofeachsheetwasmeasuredatsixdifferent locations usingcalibrated micrometers.
~Mechanical Properties Ultimatetensilestrength, yieldstrength, elongation, andhardnessweremeasuredbydestructive tensiletestingonasamplecutfromonesheetfromeachlot.Theresultsofthesetestsallmeetthemechanical properties requirements ofASTMA887-89(seeTable2).Theexcellent ductility values(10%-16%,substantially abovetheminimumspecification requirement of6%)areindicative ofhomogeneous distribution offineboridesinthematerial.
ItshouldbenotedthatalthoughtheproductfullymeetstheASTMacceptance
- criteria, therearenodesignrequirements formechanical properties ofBSSintheGinnaSFPapplication.
ChemicalAnalyses(Productanalysesbywetchemicalanalysis)
Productchemicalanalyseswereobtainedfromasamplecutfromonesheetfromeachheat.Inaddition, sampleswerecutfromonesheetfromeachlotandanalyzedforcarbonandboron.Boronanalyseswereperformed bydigestion ofthesampleintoaqueoussolutionandanalyzing byICP(Inductively CoupledPlasma).Theresultsoftheseanalysesarepresented inTable3.Allvaluesmeetthechemicalrequirements ofASTMA887-89TypeB6/B7.Allboronvaluesexceedtheminimumrequirement of1.70%;-It shouldbenotedthattheproductanalysesinTable3areinexcellent agreement withtheheatanalyses(Table1).ChemicalAnalyses(Boroncontentbywetchemicalanalysis)
Fifty(50)locations withinonesheetfromHeatC70780weresampledandanalyzedforborontoestablish thehomogeneity ofborondistribution withinonesheet.Thesevaluesallfellwithintherange1.78%to1.82%boron(meanvalue1.80%,standarddeviation
.0117%boron).ChemicalAnalyses(Boroncontentbywetchemicalanalysis)
Onesamplewascutfromeachof51sheetsselectedfromthetotalpopulation of380sheetsandanalyzedforboroncontent.Thenumberofsamplesselectedfromeachof 0~'r U.S.NRCG.S.VissingA-7October10,1997thefourheatsandtherangeofboronvaluesforeachsamplesetisasfollows:TotalSheets~amleSize%BoronHeatB00021HeatB04901HeatC70780HeatC707961382798013samples8samples20samples10samples1.75-1.77%
1.75-1.77%
1.79-1.81
%1.75-1.79%
~'EN-3NeutronAttenuation Measurements DescritionofJEN-3DeviceandTe.MehdTheJEN-3deviceisasolidstatedetectorwhichcontainsaCf-252source.Thedeviceisshapedlikeateapotwithahandle.Thefronthalfofthedeviceisthedetector, andthebackhalfcontainsthesource.Thehandleisapproximately 2feetinlength.Thedoseatthetopofthedeviceis30mrem/hour.
Theefficiency forneutronsisapproximately 0.1%.Atablewhichisusedtoreflectneutronsismadeofpolyethylene whichisapproximately 3"thick.Theboratedstainless steel(BSS)sheettobeanalyzedisplacedbetweenthedetectorandthetable.Theneutronswhichareemittedbythesourcepassthroughthestainless steelandarethenreflected backbytheplastictable.Theenergyoftheneutronsisalsoreduced.Thosethermalized neutronsareattenuated bytheboratedstainless steel.Thefewerthecountsrecordedbythedetector, thegreatertheboronloadingintheBSSsheets.Theboronloadingcalculations areinfluenced bythefollowing factors:a)Theactualpercentboron;b)Thethickness oftheBSSsheetmaterial; andc)Thepowersupplyforthedetector.
Initially, thepowersupplyforthedetectorwasasourceofsystematic error.Afterinvestigating theoperating principles oftheinstrument, thesourceoferrorwaseliminated anderroneous testresultsfromtheinitialmeasurements wereeliminated fromconsideration.
TheabilityoftheJEN-3instrument tofunctionproperlyisinfluenced byboththethickness oftheBSSmaterialandtheboronloading.Therelationship betweenthecountsrecordedbytheJEN-3detectorandboronloadingisanegativeexponential relationship.
Allcalibration curvesweredeveloped usinglog-logplots.
U.S.NRCG.S.VihsingA-8October10,1997InsectionProramCalibration Curve-Acalibration curveforthestatistical analysisofBSSwasdeveloped usingdestructive chemicaltestingandneutronalbedoanalysiswiththeJEN-3.TheresponseoftheJEN-3deviceasafunctionofboronloadinginBSSsheetsofvaryingboroncontentandthickness wasestablished usingdestructive chemicalanalysis.
Boroncontentrangedfrom1.2%to1.9%,andsheetthickness from2.0mmto3.5mm.Boronanalyseswereperformed byBOHLERatthecorporate chemistry laboratory inKapfenburg, Austria.Thickness wasmeasuredusingacalibrated ultrasonic thickness meter(calibration recordsforthemeterandtechnician trainingrecordswerereviewedandfoundtobesatisfactory).
TheJEN-3devicewasresponsecheckedonadailybasistoverifyinstrument operability.
Theserecordsweremaintained forreviewandapprovalduringallQAsurveillance activities performed byFTI,ATEA,orRG&E.Theresulting calibration curvewasanegativeexponential line(log-logplot)withacorrelation confidence ofapproximately 99.9%.2)Verification ofBoronContent-Theneutronattenuation characteristics ofallBSSsheetswasmeasuredatonerandomlyselectedlocationusingtheJEN-3device.Sheetthickness wasalsomeasuredattheexactlocationwheretheJEN-3measurement wastaken.Theboronloadingineachsheetwascalculated fromtheJEN-3measurement usingtheequationdeveloped fromthecalibration curve.Inordertoaccountforallofthestatistical errorsintheJEN-3measurement process,theminimumacceptable levelofboronforanysheetwasestablished as1.74%.Thisminimumlimitprovidesanadditional marginofsafetyinboronloading.With1.74%astheminimumacceptable calculated boronloading,thereisgreaterthan95%confidence thatnoBSSsheetscontained lessthan1.70%boron.Thislevelofconfidence providesamarginofsafetyinthecriticality calculations.
Neutronattenuation dataofallBSSsheets,asmeasuredbyJEN-3atonerandomlyselectedlocationineachsheet,wasreviewedbyanindependent statistical consultant retainedbyRG&E;JosephO.Voelkel,PhD.,Assistant U.S.NRCG.S.VidsingA-9October10,1997Professor ofStatistics attheCollegeofEngineering, Rochester Institute ofTechnology.
Hisconclusions, basedonbothparametric andnon-parametric tolerance intervals, confirmed theacceptance
- criteria, described above.3)BoronHomogeneity
-Thirty-four (34)BSSsheetswererandomlychosenfromthetotalpopulation.
Aneutronattenuation measurement wastakenatfive(5)randomlyselectedlocations oneachsheetusingtheJEN-3device.Thissamplingplanwasinaccordance withtheinstructions ofASTM-E826, "Standard PracticeforTestingHomogeneity ofMaterials fortheDevelopment ofReference Materials."
Thickness measurements weretakenattheexactlocations wheretheJEN-3measurements weretaken.Thedatawerethenevaluated bystatistical testsasfollows:Ranges(maximumminusminimummeasuredvalue)werecalculated foreachofthe34setsof5JEN-3values.Thesewereplottedagainstthecalculated meanrangeand2-sigmavalues.Ifnovaluesfelloutsidethe2-sigmalimits,thiswouldbeoneindication ofhomogeneity withinthepopulation.
Thiswasindeedthecase;i.e.,allvalueswerewithin2-sigmalimits.AnalysisOfVarianceundertherandomeffectsmodelwasperformed onthedata.Residualmodeldiagnostics demonstrated arandomdistribution ofresiduals, indicating homogeneity ofborondistribution throughout theBSSpopulation.
Theseresultsstronglyindicatehomogeneity ofborondistribution throughout theBSSproduct.InsectionsandTestsPerformed bRochester GasA,ElectricCo~ChemicalAnalysisOverchecks (Boroncontentbywetchemicalanalysis)
Chemicalanalysisoverchecks onsamplesofBSSobtainedfromBOHLERwereperformed bytwoindependent commercial testinglaboratories intheUS.Theseanalyseswereobtainedtoprovideadditional confidence intheboronanalysesreportedbyBOHLER.Resultsofthesetestsarepresented inTable4.Theresultsofthetheseoverchecks indicatethattheboronanalysesreportedbyBOHLERarereliable.
~Metallographic Examinations U,S.NRCG.S.VissingA-10October10,1997Samplescutfromonesheetfromeachlotofmaterialinboththeprincipal andtransverse rollingdirections wereexaminedmetallographically.
Allspecimens werepolishedandetchedwithKallingsreagent.Themicrostructures inbothlongitudinal andtransverse cross-sections exhibitafine,'niform dispersion ofboridesinanaustenitic matrix.Noevidenceofbandingorsegregation arepresent.Theboridehomogeneity intheBOHLERmaterialcomparesveryfavorably withpublished microstructures ofGradeAmaterialproducedbypowderedmetallurgy methods'.
ualitAssurance
'OverihAdditional inspections wereprovidedaspartofQualityAssurance oversight.
Bohleractivities weresubjecttoqualitysurveillance bypersonnel fromtheBohler,ATEA,Framatome Technologies, andRochester Gas&ElectricQualityAssurance organizations.
Thisoversight providedindependent monitoring oftheBSSmanufacturing processandresultsofinspection activities atBohler.~
Reference:
1.Smith,R.J.,Loomis,G.W.,Deltete,C.P.,BoratedStainle.s SteelAlicationinen-FuelStoraeRack.,EPRITR-100784, Project2813-21,FinalReport,June1992,p.3-13.
U.,S.NRCG.S.VissingA-11October10,1997TABLE1HeatAnalsesCSiMnPSCrNiBNC70780C70796B00021B04901ASTMA887TypeB6ASTMA887TypeB7.021.331.13.013,00119.8912.501.81.018.029.341.06.012.00119.9612.641.76.021.020.551.18.009.00219.6913.181.76.027.013.421.21.008.00119.5013.211.75.015.08'5'.0'45'3'8.0 12.01.510'20.015.01.740817512Pl045103l18P12Q1751PI20.015.02.25Note1:MaximumvalueTABLE2Mechanical ProertiesH~eatL~otC70796290C70796314C70780287C70780282C70780313C70780288C70780289B00021221B00021223B04901224B04901222UTS~Y~EIonationHardness~SI~KSI~oin2"~Brinell94.766.412.319596.062.111.721999.165.312.220993.161.214.123994.755.310.622997.563.811.219995.956.716.823994.462.810.922497.261.812.222993.058.313.823495.366.112.3229ASTMA887-8975Min30Min6.0Min241Max U.S.NRCG.S.VissingA-12October10,1997TABLE3~d~CSiMnPSCrNiBNCB00021221B00021223B04901222B04901224C70780282C70780287C70780288C70780289C70780313C70796290C70796314.021.551.18.008.00319.713~1.020.009.431.21.007.00219.413~1.01.024.321.10.012.00119.812.4.023.023.023.023.025.331.06.012.00119.912.5.0251.75.0321.741.73.0161.761.76.0221.811,801.801.801.78.0281.78TABLE4BoronAnalsisOvercheck
~Heat~SheetC70780105C70780105C70780105Laboratory BohlerLedouxM&PLabs%Boron1.83%1.86%1.82%B0002191AB00021371AB0490111AB04901171ALedouxM8cPLabsLedouxMEcPLabs1.82%1.84%1.82%1.85%
U.S.NRCG.S.VilsingA-13October10,1997uestion¹4:Althoughtestswithboratedstainless steelhaveindicated thatintheSFPenvironment nomeasurable corrosion degradation takesplace,theimportance ofitsroleinreactivity controlintheSFPmakesitadvisable tohaveasurveillance programwhichwouldprovideadditional assurance thatatalltimestherewillbeenoughpoisonmaterialintheSFP.Areyouplanningtoinstitute suchaprograniinyourplant?Ifso,describetheprogram.Ifnot,provideyourbasis.~Resense:RG&Eplanstoinstitute asurveillance programforboratedstainless steel(BSS)intheSFPattheR.E.GinnaNuclearPowerStation.Acoupontreehasbeendesignedwhichconsistsof.a304Lstainless steelracktowhich36BSScoupons(8"longX6"wide)willbebolted.EachfaceandtheedgesofthecouponsareexposedtotheSFPboricacidenvironment.
Crevicesand304L/BSSgalvaniccouplesarecreatedonthetreeateachboltlocation.
ThecouponswereselectedsothatmaterialfromeachheatandlotofBSSsheetmaterialto,beusedaspoisonpanelsinthepoolarerepresented onthetree.Incomparison withsurveillance programsforotherneutronabsorbermaterials, thedesignandconstruction ofthecoupontreefortheGinnaSFPprovidesamoreaccuraterepresentation oftheactualexposureconditions ofBSSintheSFP.Thetreewillberemovedandinspected afterthefirst18-monthoperating cycle,andeverythreeoperating cycles(approximately 41/2years)thereafter.
Thecouponswillberemovedfromthetree,inspected visuallyforanyevidenceofcorrosion, andthickness measurements takenontheexposedsurfacesandinthecreviced/galvanically coupledareas.Thesemeasurements willbecomparedwiththeoriginalthickness measurements recordedforeachcoupontodetermine ifanymeasurable materiallosshasoccurred.
Inaddition, eachcouponwillbeweighedandtheweightscomparedwithoriginalweightstodetermine weightchange.Anyunusualsurfacecondition suggestive ofsignificant corrosion willbeevaluated usingappropriate analytical methods.
1~slirCg-~I' sAU.S.NRCG.S.Vi~singA-14October10,1997uestion¹5:Withalargernumberoffuelassemblies storedintheSFPitisexpectedthatmorecorrosion productsandotherimpurities willbegenerated intheSFP.Isthepresently existingpurtftcation systemadequatetohandlethisincreased amountofimpurities?
Provideyourbasis.Recense:Thecurrentpurification systemconsistsof:(a)astring-wound skimmerfilterforsurfacecleanliness, and(b)aspentfuelpoolmixedbedresinforliquidpurification.
Theresinbedpullsfromthebottomofthepoolforitscleaningprocess.Itisa15cubicfootmixedbedresinfiltration system.Thefrequency ofchange-out ofthesurfacefiltration systemiscurrently approximately onceeverytwoyears.Thisisasurfaceclaritymaintenance system.Theadditional fuelwillnotaffectitsoperating characteristics.
Thefrequency ofchange-out fortheresinsystemiscurrently onceperyear.Historical recordsfollowing the1985rerackprojectatGinnaStationshowednomeasurable increaseinthechange-out frequency.
The1985changewaslargerinitsworkscopethantheproposedmodification.
Atthattime,approximately 420cellswereadded.Bycomparison, theproposedmodification willincreasethestoragecapacityby305cellsin1998(anadditional 48storagecellsmaybeaddedinthefutureifneeded)~Itispostulated thattheupcomingrerackwillnotincreasethecleaningsystemchange-out.
However,thesystemwillbemonitored todetermine anychangestohistorical patterns.
Therefore itcanbeconcluded thatthecapacityofthepurification systemisadequateandcanabsorbtheadditional storagerequirements withoutsubstantially affecting currentplantmaintenance capability tohandleanyincreased amountofcorrosion productsandotherimpurities.
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