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{{#Wiki_filter:EDO Principal Correspondence Control FROM: DUE: 05/30/07 EDO CONTROL: G20070273 DOC DT: 04/25/07 FINAL REPLY: Mark Edward Leyse TO: Reyes, EDO FOR SIGNATURE OF :** GRN **CRC NO: Dyer, NRR DESC: ROUTING: 2.206 -Indian Point Units 2 and 3 Reyes Virgilio Kane Silber Ordaz Cyr/Burns Collins, RI Cyr, OGC Mensah, NRR Jones, OGC | {{#Wiki_filter:EDO Principal Correspondence Control FROM: DUE: 05/30/07 EDO CONTROL: G20070273 DOC DT: 04/25/07 FINAL REPLY: | ||
To: <cej@nrc.gov>, <pdr@nrc.gov> | Mark Edward Leyse TO: | ||
Date: 04/25/2007 1:30:11 AM | Reyes, EDO FOR SIGNATURE OF : ** GRN ** CRC NO: | ||
Dyer, NRR DESC: ROUTING: | |||
2.206 - Indian Point Units 2 and 3 Reyes Virgilio Kane Silber Ordaz Cyr/Burns DATE: 04/25/07 Collins, RI Cyr, OGC ASSIGNED TO: CONTACT: Mensah, NRR Jones, OGC NRR Dyer SPECIAL INSTRUCTIONS OR REMARKS: | |||
`eý ýoke~ -£ bO -OOý E-6S-(( Eh -DI | |||
JIaegrs - Attn: Ms. Jaegers; Petition for an Enforcement Action Page7l From: <mel2005@columbia.edu> | |||
To: <cej@nrc.gov>, <pdr@nrc.gov> | |||
Date: 04/25/2007 1:30:11 AM | |||
==Subject:== | ==Subject:== | ||
Attn: Ms. Jaegers; Petition for an Enforcement Action | Attn: Ms. Jaegers; Petition for an Enforcement Action | ||
==Dear Mr. Reyes:== | ==Dear Mr. Reyes:== | ||
Attached to this email in a PDF file is a petition for an enforcement action, submitted pursuant to 10 C.F.R. 2.206. This petition has already been faxed to you at 301-415-2162. Additional copies will promptly be mailed to your office and the NRC Public Document Room. | |||
Sincerely, Mark Edward Leyse CC: <gov.spitzer@chamber.state.ny.us>, <GeriShapiro@clinton.senate.gov>, | |||
<josephine_jacob@schumer.senate.gov>, <rangel@mail. house.gov>, <ceo@westchestergov.com>, | |||
<lisa@riverkeeper.org>, <phillip@riverkeeper.org>, <elyman@ucsusa.org>, <dlochbaum@ucsusa.org>, | |||
<jim.riccio@wdc.greenpeace.org> | |||
EDO -- G20070273 | |||
April 24, 2007 Before the UNITED STATES NUCLEAR REGULATORY COMMISSION Washington, D.C. 20555-0001 In the Matter of:- TO: LUIS A. REYES EXECUTIVE DIRECTOR ENTERGY CORPORATION : FOR OPERATIONS (Indian Point Nuclear Generating Units No. 2 and 3; Facility Operating Licenses DPR-26 and DPR-64) : Docket No. | |||
MARK EDWARD LEYSE, Petitioner 10 | |||
The transcript of proceedings of NRC, ACRS, Reactor Fuels Subcommittee Meeting, April 4, 2001, relates the opinions of two experts regarding hydrogen content's role in reducing cladding ductility: | The transcript of proceedings of NRC, ACRS, Reactor Fuels Subcommittee Meeting, April 4, 2001, relates the opinions of two experts regarding hydrogen content's role in reducing cladding ductility: | ||
Hee Chung [of Argonne National Laboratory] now points out that for Zircaloy, that there seems to be a threshold around 600 or 700 ppm hydrogen. When you get that much hydrogen in the specimen, then it also contributes to the reduction of ductility..... Griger [of KFKI Atomic Energy Research Institute] believes that he sees a threshold [for a reduction of ductility 78 for Zircaloy] at a much lower level, down around 150 to 200 [ppm]. | |||
It is also significant that rod 011 was perforated by oxidation and that it had a 111.1 ýtm oxide layer at the 118.5 inch elevation, because there is "a decrease in Zr-4 79 cladding ductilities when oxide thicknesses begin to exceed 100 ýtm." | |||
75 R. Tropasso, J. Willse, B. Cheng, | |||
==Subject:== | ==Subject:== | ||
Attn: Ms. Jaegers; Petition for an Enforcement Action Creation Date 04/25/2007 1:29:24 AM From: <me12005@columbia.edu> | Attn: Ms. Jaegers; Petition for an Enforcement Action Creation Date 04/25/2007 1:29:24 AM From: <me12005@columbia.edu> | ||
Created By: mel2005@columbia.edu Recipients nrc.gov OWGWPOO4.HQGWDOOI CEJ (Cathy Jaegers)nrc.gov TWGWPO04.HQGWDOO1 PDR 0 wdc.greenpeace.org jim.riccio CC ucsusa.org dlochbaum CC elyman CC riverkeeper.org phillip CC lisa CC westchestergov.com ceo CC mail.house.gov rangel CC schumer.senate.gov josephinejacob CC clinton.senate.gov Geri-Shapiro CC chamber. state.ny.us gov.spitzer CC Post Office Route | Created By: mel2005@columbia.edu Recipients nrc.gov OWGWPOO4.HQGWDOOI CEJ (Cathy Jaegers) nrc.gov TWGWPO04.HQGWDOO1 PDR 0 wdc.greenpeace.org jim.riccio CC ucsusa.org dlochbaum CC elyman CC riverkeeper.org phillip CC lisa CC westchestergov.com ceo CC mail.house.gov rangel CC schumer.senate.gov josephinejacob CC clinton.senate.gov Geri-Shapiro CC chamber. state.ny.us gov.spitzer CC Post Office Route | ||
Standard ReplyRequested: | |||
No Return Notification: | 11cAtemp\GW)00001.TMP Paae 21II c:\temp\GW}OOOO1 .TMP - | ||
None Concealed | Paae 211 OWGWPOO4.HQGWDO01 nrc.gov TWGWPO04.HQGWDOO1 nrc.gov wdc.greenpeace.org ucsusa.org riverkeeper.org westchestergov.com mail.house.gov schumer. senate.gov clinton. senate.gov chamber. state.ny.us Files Size Date & Time MESSAGE 321 04/25/2007 1:29:24 AM Petition for Enforcement IV.pdf250363 Mime.822 345068 Options Expiration Date: None Priority: Standard ReplyRequested: No Return Notification: None Concealed | ||
==Subject:== | ==Subject:== | ||
No Security: | No Security: Standard Junk Mail Handling Evaluation Results Message is eligible for Junk Mail handling This message was not classified as Junk Mail Junk Mail settings when this message was delivered Junk Mail handling disabled by User Junk Mail handling disabled by Administrator Junk List is not enabled Junk Mail using personal address books is not enabled Block List is not enabled}} | ||
Standard Junk Mail Handling Evaluation Results Message is eligible for Junk Mail handling This message was not classified as Junk Mail Junk Mail settings when this message was delivered Junk Mail handling disabled by User Junk Mail handling disabled by Administrator Junk List is not enabled Junk Mail using personal address books is not enabled Block List is not enabled}} |
Latest revision as of 08:06, 23 November 2019
ML071150299 | |
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Site: | Indian Point ![]() |
Issue date: | 04/25/2007 |
From: | Leyse M - No Known Affiliation |
To: | Reyes L NRC/EDO |
Boska J, NRR, 301-415-2901 | |
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Text
EDO Principal Correspondence Control FROM: DUE: 05/30/07 EDO CONTROL: G20070273 DOC DT: 04/25/07 FINAL REPLY:
Mark Edward Leyse TO:
Reyes, EDO FOR SIGNATURE OF : ** GRN ** CRC NO:
Dyer, NRR DESC: ROUTING:
2.206 - Indian Point Units 2 and 3 Reyes Virgilio Kane Silber Ordaz Cyr/Burns DATE: 04/25/07 Collins, RI Cyr, OGC ASSIGNED TO: CONTACT: Mensah, NRR Jones, OGC NRR Dyer SPECIAL INSTRUCTIONS OR REMARKS:
`eý ýoke~ -£ bO -OOý E-6S-(( Eh -DI
JIaegrs - Attn: Ms. Jaegers; Petition for an Enforcement Action Page7l From: <mel2005@columbia.edu>
To: <cej@nrc.gov>, <pdr@nrc.gov>
Date: 04/25/2007 1:30:11 AM
Subject:
Attn: Ms. Jaegers; Petition for an Enforcement Action
Dear Mr. Reyes:
Attached to this email in a PDF file is a petition for an enforcement action, submitted pursuant to 10 C.F.R. 2.206. This petition has already been faxed to you at 301-415-2162. Additional copies will promptly be mailed to your office and the NRC Public Document Room.
Sincerely, Mark Edward Leyse CC: <gov.spitzer@chamber.state.ny.us>, <GeriShapiro@clinton.senate.gov>,
<josephine_jacob@schumer.senate.gov>, <rangel@mail. house.gov>, <ceo@westchestergov.com>,
<lisa@riverkeeper.org>, <phillip@riverkeeper.org>, <elyman@ucsusa.org>, <dlochbaum@ucsusa.org>,
<jim.riccio@wdc.greenpeace.org>
EDO -- G20070273
April 24, 2007 Before the UNITED STATES NUCLEAR REGULATORY COMMISSION Washington, D.C. 20555-0001 In the Matter of:- TO: LUIS A. REYES EXECUTIVE DIRECTOR ENTERGY CORPORATION : FOR OPERATIONS (Indian Point Nuclear Generating Units No. 2 and 3; Facility Operating Licenses DPR-26 and DPR-64) : Docket No.
MARK EDWARD LEYSE, Petitioner 10 C.F.R. § 2.206 REQUEST FOR EMERGENCY SHUTDOWN OF INDIAN POINT UNITS 2 AND 3 I. REQUEST FOR ACTION This petition for an enforcement action is submitted pursuant to 10 C.F.R. § 2.206 by Mark Edward Leyse. Petitioner requests that the United States Nuclear Regulatory Commission ("NRC") either 1) revoke the operating license of Indian Point Units 2 and 3
("IP-2 and -3"), 2) order the licensee of IP-2 and -3 to immediately suspend the operations of IP-2 and -3, or 3) temporarily shutdown IP-2 and -3, per 10 C.F.R. § 2.202.
In the event of option 3, Petitioner requests that the NRC order the licensee to correct the current deficiencies of the emergency-core-cooling-system ("ECCS") design basis and reconfigure the power production levels of both plants, making IP-2 and -3 compliant with 10 C.F.R. § 50.46(b); and, in the event of a license renewal process, conduct reviews for the license renewal of IP-2 and -3 that encompass conservative ECCS evaluation calculations, modeling scenarios where one-cycle fuel would have heavily crudded1 and/or oxidized fuel rods ("cladding") or would have crud-induced corrosion failures (operating conditions experienced at pressurized water reactors ("PWRs") in recent "Crud" is a term meaning corrosion products.
years) at the onset of postulated loss-of-coolant accidents ("LOCAs"). Petitioner makes this request on account of the fact that the current power levels of both plants are based on non-conservative ECCS evaluation calculations.
The ECCS evaluation calculations done to qualify the recent IP-2 and -3 stretch power uprates of 3.26%2 and 4.85%,3 respectively (authorized by the NRC in 2004 and 2005, respectively), were non-conservative, because such calculations did not model scenarios where one-cycle fuel would have heavily crudded and oxidized cladding or would have crud-induced corrosion failures. In the event of a LOCA such fuel would yield significantly higher peak cladding temperatures ("PCTs") than the fresh, beginning of life ("BOL") fuel modeled by the licensee of IP-2 and -3 in the ECCS evaluation calculations done to qualify the IP-2 and -3 stretch power uprates. 4 Furthermore, the cladding, in scenarios where crud-induced corrosion failures would occur, would be substantially more oxidized than the maximum oxidation values claimed by the licensee in the ECCS evaluation calculations. Hence, it is highly probable that IP-2 and -3 are currently operating at unsafe power levels, because the current power levels of 3216 megawatts thermal ("MWt") and 3216 MWt, respectively, were qualified by the results of non-conservative ECCS evaluation calculations. It is also highly probable that IP-2 and -3 were operating at unsafe power levels prior to the 2004 and 2005 stretch power uprates, at 3114.4 MWt and 3067.4 MWt, respectively, because ECCS evaluation calculations done to qualify power levels prior to 2004 and 2005 also did not model scenarios where one-cycle fuel would have heavily crudded and oxidized cladding or crud-induced corrosion failures.
2 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 - Issuance of Amendment Re: 3.26 Percent Power Uprate," October 27, 2004, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML042960007, p. 1.
3 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 3 - Issuance of Amendment Re: 4.85 Percent Stretch Power Uprate and Relocation of Cycle-Specific Parameters," March 24, 2005, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML050600380, p. 1.
4 The PCTs were calculated with Westinghouse's WCOBRA/TRAC computer code.
Westinghouse maintains that BOL fuel is the most limiting condition of fuel during LOCAs. See Westinghouse, "Code Qualification Document for Best Estimate Small Break LOCA Analysis; Volume 3: PWR Uncertainties and Sensitivities for Small Break LOCA," 2003, located at:
www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
ML031570508, Section 29, p. 2 5 .
2
II. STATEMENT OF PETITIONER'S INTEREST 10 C.F.R. § 2.206(a) states that "[a]ny person may file a request to institute a proceeding pursuant to § 2.202 to modify, suspend, or revoke a license, or for any other action as may be proper." Petitioner submits this petition on account of the fact that the current power levels of IP-2 and -3 are based on non-conservative ECCS evaluation calculations.
III. FACTS CONSTITUTING THE BASIS FOR PETITIONER'S REQUEST The low thermal conductivity of crud and/or oxide layers on cladding inhibits heat transfer, causing local cladding surface temperatures to increase during the operation of nuclear power plants (sometimes in excess of 3007F or even 6007F); 5 temperatures also increase in the fuel sheathed within the cladding (i.e., the stored energy in the fuel increases). In the event of a LOCA, the thermal resistance of insulating layers of crud and/or oxide on cladding, and increased fuel temperatures, would cause the PCT to be higher than it would be if the cladding were clean. If a large break ("LB") LOCA had occurred at several nuclear power plants that operated with heavy crud and oxide layers in recent years, there is a high probability that their PCTs would have exceeded 2200'F, in violation of the parameter set forth in 10 C.F.R. § 50.46(b)(1), Peak cladding temperature.
Furthermore, at the onset of a LOCA, at plants that experienced crud-induced corrosion fuel failures (like Three Mile Island Unit 1 Cycle 10), the percentage of maximum local cladding oxidation would already be 100%, because these plants operated with fuel rods that had been perforated by oxidation. This is significant, because "NRC Information Notice 98-29: Predicted Increase in Fuel Rod Cladding Oxidation" states that the "[t]otal oxidation [of cladding] includes both pre-accident oxidation and oxidation 5 See R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-l Cycle 10," American Nuclear Society, Proceedings of the 2004 InternationalMeeting on L WR FuelPerformance,Orlando, Florida, September 19-22, 2004, p. 342; see also NRC, "River Bend Station - NRC Problem Identification and Resolution Inspection Report 0500458/2005008,"
02/28/06, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML060600503, Report Details, pp. 10-12. River Bend, a boiling water reactor
("BWR"), operated with local cladding temperatures approaching 12007F during cycles 8 and 11.
3
occurring during a LOCA.' 6 (This is a NRC recommendation for guidance; it is not a legally binding regulation. But it is being considered for regulation status for a new revised version of 10 C.F.R. § 50.46, due in 2009.)7 This NRC information notice applies to C.F.R. § 10 50.46(b)(2), Maximum cladding "oxidation,which dictates the rule for the maximum allowed value of the equivalent cladding reacted ("ECR") calculated by severe accident analysis programs (codes) when simulating LOCAs. C.F.R. § 10 50.46(b)(2) states: "[t]he calculated total oxidation of the cladding shall nowhere exceed 0.17 times the total cladding thickness before oxidation." Concerning this 17% limit NRC Information Notice 98-29 warns: "[i]f this.. .oxidation limit [of 17%] were to be exceeded during an accident, the cladding could become embrittled. The cladding could then fracture and fragment during the reflood period and lose structural integrity. This in turn could compromise the structural soundness and coolable geometry of the core and ultimately the ability to keep the core cooled."'
It is highly probable that if a LB LOCA were to occur at either IP-2 or -3 under circumstances where one-cycle fuel would have heavily crudded and oxidized cladding or crud-induced corrosion failures, the parameters set forth in 10 C.F.R. § 50.46(b) would be violated, because the current power levels of IP-2 and -3 are based on non-conservative ECCS evaluation calculations. In its entirety 10 C.F.R. § 50.46(b) states:
(1) Peak cladding temperature. The calculated maximum fuel element cladding temperature shall not exceed 2200'F.
(2) Maximum cladding oxidation. The calculated total oxidation of the cladding shall nowhere exceed 0.17 times the total cladding thickness before oxidation. As used in this subparagraph total oxidation means the total thickness of cladding metal that would be locally converted to oxide if all the oxygen absorbed by and reacted with the cladding locally were converted to stoichiometric zirconium dioxide. If cladding rupture is 6NRC, "NRC Information Notice 98-29: Predicted Increase in Fuel Rod Cladding Oxidation,"
August 3; 1998, located at: http://www.nrc.gov/reading-rm/doc-collections/gen-comm/info-notices/1998/in98029.html (accessed on 01/21/07).
7 See NRC, Advisory Committee on Reactor Safeguards, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting Transcript, January 19, 2007, located at:
http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/subcommittee/2007/mmO 11907.pdf (accessed on 02/27/07), p. 245; see also NRC, Advisory Committee on Reactor Safeguards 539th Meeting Transcript, February 2, 2007, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/fullcommittee/2007/acO20207.pdf (accessed on 02/27/07), p. 10.
8 NRC, "NRC Information Notice 98-29: Predicted Increase in Fuel Rod Cladding Oxidation."
4
calculated to occur, the inside surfaces of the cladding shall be included in the oxidation, beginning at the calculated time of rupture. Cladding thickness before oxidation means the radial distance from inside to outside the cladding, after any calculated rupture or swelling has occurred but before significant oxidation. Where the calculated conditions of transient pressure and temperature lead to a prediction of cladding swelling, with or without cladding rupture, the unoxidized cladding thickness shall be defined as the cladding cross-sectional area, taken at a horizontal plane at the elevation of the rupture, if it occurs, or at the elevation of the highest cladding temperature if no rupture is calculated to occur, divided by the average circumference at that elevation. For ruptured cladding the circumference does not include the rupture opening.
(3) Maximum hydrogen generation. The calculated total amount of hydrogen generated from the chemical reaction of the cladding with water or steam shall not exceed 0.01 times the hypothetical amount that would be generated if all of the metal in the cladding cylinders surrounding the fuel, excluding the cladding surrounding the plenum volume, were to react.
(4) Coolable geometry. Calculated changes in core geometry shall be such that the core remains amenable to cooling.
(5) Long-term cooling. After any calculated successful initial operation of the ECCS, the calculated core temperature shall be maintained at an acceptably low value and decay heat shall be removed for the extended period of time required by the long-lived radioactivity remaining in the core.
A. Entergy's Non-Conservative ECCS Evaluation Calculations Used to Qualify the Stretch Power Uprates for Indian Point Units 2 and 3.
When Entergy, the licensee of IP-2 and -3, did LOCA related calculations to qualify the stretch power uprates for IP-2 and -3 (authorized by the NRC in 2004 and 2005, respectively), the calculated maximum cladding oxidation percentages were calculated for fresh, BOL fuel, with Westinghouse's WCOBRA/TRAC code. 9 These ECCS evaluation calculations were done for the safety evaluations that helped qualify the 9 Entergy, Attachment 1 to NL 100, "Reply to NRC Request for Additional Information Regarding Proposed License Amendment Request for Indian Point 2 Stretch Power Uprate,"
August 12, 2004, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML042380253, pp. 6-7. These calculations were also done for BOL fuel at IP-3.
5
recent plant stretch uprates of 3.26 % for IP-2 and of 4.85% for IP-3. The percentage of maximum local cladding oxidation occurring in the event of a LB LOCA at IP-2 was calculated at 13.2%,1° and for IP-3 it was calculated at 7.6%.11 However, scenarios where one-cycle fuel would have heavily crudded and oxidized cladding or crud-induced corrosion failures, operating conditions experienced at PWRs in recent years, were not modeled in these calculations. Because of the omission of such scenarios, the ECCS evaluation calculations done to qualify the recent plant stretch uprates of IP-2 and -3 are non-conservative.
Additionally, Entergy claimed that the pre-accident oxidation and transient oxidation would "always be below 15%,"'12 at both IP-2 and -3, in the event of LOCAs.
This claim is also non-conservative: in recent years at three PWRs in the United States (Three Mile Island Unit 1 (1995), Seabrook (1997), and Palo Verde Unit 2 (2000)) local oxidation was 100% during operation, where oxidation perforated cladding.
- 1. Entergy's Non-Conservative ECCS Evaluation Calculations of the Maximum Cladding Oxidation that could Occur during a LB LOCA at Indian Point Unit 2.
Discussing ECCS evaluation calculations of the maximum local oxidation that could occur during a LB LOCA at IP-2 (to qualify the 2004 stretch power uprate of 3.26%), Entergy, states:
The maximum local oxidation was calculated for fresh fuel, at the beginning of the cycle. This represents the maximum amount of transient oxidation that could occur at any time in life. As burnup increases, the transient oxidation decreases for the following reasons:
- 1) The cladding creeps down towards the fuel pellets, due to the system pressure exceeding the rod internal pressure. This will reduce the average internal stored energy at the hot spot by several hundred degrees
[Fahrenheit] relatively early in the first cycle of operation. Accounting only for this change, which occurs early in the first cycle, reduces the transient oxidation significantly.
10 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 - Issuance of Amendment Re: 3.26 Percent Power Uprate," Enclosure 2, p. 18.
11NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 3 - Issuance of Amendment Re: 4.85 Percent Stretch Power Uprate and Relocation of Cycle-Specific Parameters," Enclosure 2, p. 16.
12 See Id.; see also NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 -
Issuance of Amendment Re: 3.26 Percent Power Uprate," Enclosure 2, p. 18.
6
- 2) Later in life, the clad creep-down benefit still remains in effect. In addition, with increasing irradiation, the power production from the fuel will naturally decrease as a result of depletion of the fissionable isotopes.
Reductions in achievable peaking factors in the burned fuel relative to the fresh fuel are realized before the middle of the second cycle of operation.
The achievable linear heat rates decrease steadily from this point until the fuel is discharged, 13 at which point the transient oxidation will be negligible.
As Entergy states, fresh, BOL or one-cycle fuel with low burnups are usually the conditions of the fuel that are considered to have the maximum stored energy, and during postulated LOCAs to yield the maximum amount of transient oxidation (and the highest PCTs) that could occur at any time in the fuel's life. At the January 2007, NRC, Advisory Committee on Reactor Safeguards ("ACRS"), Subcommittee Meeting on Materials, Metallurgy, and Reactor Fuels, Mitch Nissley of Westinghouse cited data from sample LOCA calculations that showed that one-cycle fuel from burnups of zero to approximately 20 or 25 GWd/MTU yield the highest PCTs (and have the maximum stored energy). He also stated that at burnups of around 30 GWd/MTU there is an approximate 10% reduction in achievable power, which yields PCTs that are approximately 100°C (180'F) lower than those of fresher fuel.14 However, Entergy's claim that "the average internal stored energy [will decrease]
at the hot spot by several hundred degrees [Fahrenheit] relatively early in the first cycle of operation"' 15 is misleading: burnups of 25 GWd/MTU occur in fuel well past the early part of its first cycle of operation. Furthermore, for conditions where cladding would be crudded and oxidized it is highly probable that the cladding would not "[creep] down towards the fuel pellets, due to the system pressure exceeding the [fuel] rod internal 13Entergy, Attachment I to NL-04-100, "Reply to NRC Request for Additional Information Regarding Proposed License Amendment Request for Indian Point 2 Stretch Power Uprate," p. 6.
Fuel-cladding gap closure typically takes place within 500 days of operation for M5 cladding; see "Safety Evaluation by the Office of Nuclear Reactor Regulation, Topical Report BAW-10231 P,
'COPERNIC Fuel Rod Design Computer Code,' Framatome Cogema Fuels, Project No. 693,"
2002, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML020070158, p. 7.
14 NRC, Advisory Committee on Reactor Safeguards, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting Transcript, January 19, 2007, pp. 251-252.
15Entergy, Attachment 1 to NL-04-100, "Reply to NRC Request for Additional Information Regarding Proposed License Amendment Request for Indian Point 2 Stretch Power Uprate," p. 6.
7
pressure.. .relatively early in the first cycle of operation,"' 16 because crud and oxide layers on cladding increase fuel rod internal pressure.
Regarding this phenomenon, NRC document, "Safety Evaluation by the Office of Nuclear Regulation, Topical Report WCAP-15604-NP. REV. 1, 'Limited Scope High Burnup Lead Test Assemblies' Westinghouse Owners Group, Project No. 694," states:
Clad[ding] oxidation can lead to significantly increased fuel rod internal pressures. Above certain oxidation levels, the impacts on rod internal pressure and the significant impacts on the cladding pressure limit characteristics could result in the rod internal pressure criterion being exceeded. Therefore, if oxidation is kept to a minimum, the fuel rod internal pressure criterion is less limiting than simply the oxidation criterion by itself. Also, at higher levels of oxidation, spalling of the oxide layer can lead to the formation of hot spots forming on the bare cladding surface. Accelerated oxidation at the hot spots can produce through-wall holes. In addition to oxidation causing increases in rod internal pressures, crud deposition has a similar effect since crud is a poor conductor of heat.
Keeping crud deposition 7
to a minimum also reduces the impact on rod internal pressures.'
It is significant, that, in some cases, thick crud and oxide layers have quickly accumulated on one-cycle cladding sheathing high-duty fuel. At Three Mile Island Unit 18 1 Cycle 10, such cladding was perforated by oxidation only 121 days into the cycle.
Therefore, it is highly probable that quickly formed layers of crud and oxide would either slow down or stop the cladding from creeping down towards the fuel pellets, not reducing the average stored energy in the fuel or the average temperature "at the hot spot by 19 several hundred degrees [Fahrenheit] relatively early in the first cycle of operation."'
And even more significantly, Entergy does not consider that the stored energy in one-cycle fuel sheathed within heavily crudded and oxidized cladding would increase to levels greater than that of BOL fuel sheathed within clean cladding.
16 Id.
17 NRC, "Safety Evaluation by the Office of Nuclear Regulation, Topical Report WCAP-15604-NP. REV. 1, 'Limited Scope High Burnup Lead Test Assemblies' Westinghouse Owners Group, Project No. 694," 2003, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML070740225 (See Section A), p. 4.
18 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 339.
19 Entergy, Attachment I to NL-04-100, "Reply to NRC Request for Additional Information Regarding Proposed License Amendment Request for Indian Point 2 Stretch Power Uprate," p. 6.
8
To clarify how a heavy crud layer would affect the stored energy in the fuel during a LOCA is a citation from a letter from James F. Klapproth, Manager, Engineering and Technology at GE Nuclear Energy, to the NRC:
The primary effects of [a] heavy crud layer during a postulated LOCA would be an increase in the fuel stored energy at the onset of the event, and a delay in the transfer of20that stored energy to the coolant during the blowdown phase of the event.
The fact that a heavy crud layer would: 1) increase the stored energy in the fuel at the onset of a LOCA; and 2) delay the transfer of that stored energy to the coolant during the blowdown phase of a LOCA, is very significant for how cladding would be affected during a LOCA.
The increase of the stored energy in the fuel caused by a heavy crud layer is substantial (in some cases, enough to increase local cladding temperatures in excess of 3007F or even 6007F during operation).1 This increase raises the stored energy in the fuel to levels higher than that of fresh, BOL fuel, or fuel with burnups between 30 to 35 GWd/MTU, which are considered the times of life or burnups that represent the maximum stored energy that fuel has during operation. (Fresh, BOL fuel is generally considered to have the maximum stored energy in fuel; however,' COPERNIC and FRAPCON-3 (computer codes, programs that simulate LOCAs) calculate that mid-life 22 fuel with burnups of about 30 to 35 GWd/MTU have the maximum stored energy.)
- a. How the Stored Energy in the Fuel Affects the Oxidation.
The increased stored energy (caused by a heavy crud layer) and the delay in the transfer of that stored energy to the coolant during the blowdown phase would increase 20 Letter from James F. Klapproth, Manager, Engineering and Technology, GE Nuclear Energy to Annette L. Vietti-Cook, Secretary of the Commission, NRC, April 8, 2002, located at:
www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
21 See R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-l Cycle 10," p. 342; see also NRC, "River Bend Station - NRC Problem Identification and Resolution Inspection Report 0500458/2005008," Report Details pp.10-12. River Bend, a BWR, operated with local cladding temperatures approaching 1200'F during cycles 8 and 11.
22 "Safety Evaluation by the Office of Nuclear Reactor Regulation, Topical Report BAW- 10231 P,
'COPERNIC Fuel Rod Design Computer Code,' Framatome Cogema Fuels, Project No. 693," p.
10.
9
the PCT and cause the cladding to be subjected to extremely high temperatures for a substantially longer time duration than if the cladding where clean at the onset of the LOCA. This would provide more time for heatup and degradation of the fuel and cladding, including rapid oxidation and embrittlement of the cladding. When the cladding reacts with steam, an exothermic reaction occurs which generates heat, additionally heating up the cladding. Regarding the significance of time and temperature during a LOCA, NRC staff member, Ralph Meyer, states:
[I]n 10 CFR 50.46, part [b]... [t]here is an oxidation limit of 17[%]. This is really a time limit because it was understood at the beginning and we know it now that the embrittling process does not take place on the surface where the oxide is accumulating [during a LOCA]. It is related to the diffusion of oxygen in the metal. The diffusion process and the oxidation process run at about the same speed. And so an oxidation limit was used.
It [is] very convenient. ... It gives you a nearly constant number that you can use as a limit. ... [A] basic LOCA transient calculation is just time and temperature. And then you run along with that some equation for oxidation and get a calculated oxidation amount during the transient
[emphasis added].2 3 Regarding oxidation-induced cladding embrittlement, "Compendium of ECCS Research for Realistic LOCA Analysis" states:
Embrittled cladding can fragment upon introduction of the emergency cooling water in a severe accident. During a high-temperature transient accident, the cladding becomes embrittled by steam oxidation of the zircaloy cladding and the formation of thick reaction layers of brittle oxide and oxygen-stabilized alpha zircaloy. The extent of cladding oxidation, and hence embrittlement, is a function of temperature, time, and the supply of steam and zircaloy. Embrittlement of the cladding may lead to loss of coolable geometry and is thus relevant to the safety analysis of fuel rods [emphasis added]. 24 The increase of the stored energy in the fuel (caused by a heavy crud layer) and the delay in the transfer of that stored energy to the coolant would also increase the time until quench. "Compendium of ECCS Research for Realistic LOCA Analysis" states, 23 NRC, Advisory Committee on Reactor Safeguards 539th Meeting Transcript, February 2, 2007, pp. 15-16.
24 NRC, NUREG-1230, "Compendium of ECCS Research for Realistic LOCA Analysis," 1988, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
ML053490333, p. 6.14-6.
10
"[t]he amount of residual thermal energy [in the fuel rod] influences the time required to quench the reactor core with emergency cooling water [emphasis added]." 25 It is significant that the ECCS evaluation calculations that helped qualify the 2004 power uprate of IP-2 did not model scenarios where cladding would be heavily crudded and oxidized, even though suchlike cladding conditions have been experienced at PWRs in recent years. Regarding the time until quench, Entergy's "Reply to Request for Additional Information Regarding Indian Point 2 Stretch Power Uprate," states:
In order to demonstrate stable and sustained quench, the WCOBRA/TRAC calculation for the maximum local oxidation analysis was extended. Figure 1 shows the peak cladding temperatures for the five rods modeled in WCOBRA/TRAC. This figure indicates that quench occurs at approximately 275 seconds for the low power rod (rod 5), 400 seconds for the core average rods (rods 3 and 4), and 500 seconds for the hot rod (rod 1) and hot assembly average rod (rod 2). Once quench is predicted to occur, the rod temperatures remain slightly above the fluid saturation temperature for the remainder of the simulation. ... This is consistent with the expected result based on the removal of the initial core stored energy [emphasis added]... 2 6 The time period until quench for each of the five rods modeled in Entergy's ECCS evaluation calculations would have been significantly increased if scenarios where cladding would be heavily crudded and oxidized had been modeled, because the removal of the initial core stored energy would have taken more time. Because such scenarios were not modeled, Entergy's results for the time period until quench are non-conservative. And because heavy crud and oxide layers on cladding would cause the cladding to be subjected to extremely high temperatures for a substantially longer time duration than the rods modeled in the ECCS evaluation calculations, there would be substantially more degradation of the fuel and cladding, including rapid oxidation and embrittlement of the cladding. Therefore, the results of Entergy's ECCS evaluation calculations for the maximum cladding oxidation that could occur during a LB LOCA at 25 Id., p. 6-14-2.
26 Entergy, Attachment I to NL-04-121, "Reply to NRC Request for Additional Information Regarding Proposed License Amendment Request for Indian Point 2 Stretch Power Uprate,"
September 24, 2004, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML042720432, Attachment 1, p. 8.
11
IP-2 (13.2%)27 are substantially non-conservative. For these reasons, it is probable that IP-2 will operate in violation of the parameters set forth in 10 C.F.R. § 50.46(b)(2).
- b. Entergy's Non-Conservative Conclusion that the Sum of the Pre-Accident and Transient Oxidation would Remain Below 15%.
Discussing calculations of the maximum local oxidation that could occur during a LB LOCA and the maximum sum of the pre-accident and transient oxidation that could occur at IP-2, Entergy, states:
[T]he transient oxidation decreases from a very conservative maximum of 13.2% at BOL to a negligible value at EOL [(end of life)], while the pre-transient oxidation increases from zero at BOL to a very conservative maximum at EOL of <15%. Additional WCOBRA/TRAC and HOTSPOT [(with oxidation calculations using "corresponding WCOBRA/TRAC transient boundary conditions") 2 8] calculations were performed at intermediate burnups, accounting for burnup effects on fuel performance data (primarily initial stored energy and rod internal pressure). These calculations support the conclusion that the sum of the transient and pre-transient oxidation remains below 15% at all times in life. This conclusion is applicable to each of the fuel designs that will be included in the SPU [(stretch power uprate)] cores, and confirms IP-2 conformance29 with the 10 CFR 50.46 acceptance criterion for local oxidation.
Entergy's statement that its "calculations support the conclusion that the sum of the transient and pre-transient oxidation remains below 15% at all times in life," is non-conservative. Entergy's analysis omits cladding conditions experienced at PWRs in recent years in the United States where there were crud-induced corrosion fuel failures.
In such cases the pre-transient oxidation would have been 100%, because local oxidation perforated cladding at the affected plants. Furthermore, at non-perforated cladding locations there were thick oxide layers on cladding at the affected plants.
27 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 - Issuance of Amendment Re: 3.26 Percent Power Uprate," Enclosure 2, p. 18.
28 Entergy, Attachment I to NL-04-100, "Reply to NRC Request for Additional Information Regarding Proposed License Amendment Request for Indian Point 2 Stretch Power Uprate," p. 6.
29 Id., p. 7.
12
- 2. Recent Peak Cladding Temperatures Calculated for Indian Point Unit 2.
- a. The PCT Calculated in 2001 with Westinghouse's 1996 WCOBRA/TRAC computer code.
In 2001, IP-2 had a PCT of 2188'F in a computer simulated LB LOCA-only 12'F shy the requirements of 10 C.F.R. § 50.46(b)(1). 3 °
- b. PCTs Calculated with WCOBRA/TRAC to Help Qualify the 2004 Stretch Power Uprate.
The ECCS evaluation calculations that helped qualify IP-2's 2004 stretch power uprate, calculated IP-2's PCT at 21371F for ZIRLO cladding in Vantage assemblies and at 2115'F for fuel in 15x 15 assemblies during a postulated LB LOCA.3 (The ECCS evaluation calculations that helped qualify IP-3's 2005 stretch power uprate, calculated 32 IP-3's PCT at 19440 F during a postulated LB LOCA.)
- c. PCTs Calculated in 2005 with Westinghouse's ASTRUM Methodology, Bounded in the 1996 WCOBRA/TRAC Code.
In 2006, IP-2 was issued an amendment to its operating license for its LB LOCA analysis methodology; it converted to the "Realistic Large Break LOCA Evaluation Methodology using the Automated Statistical Treatment of Uncertainty Method
("ASTRUM")."3 3 With the ASTRUM methodology, bounded in the 1996 30 Consolidated Edison Company of New York, Inc., "Indian Point Unit 2 - 30 Day and Annual 10 CFR 50.46 Report," April 10, 2001, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: MLO 11150434, p. 1.
31 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 - Issuance of Amendment Re: 3.26 Percent Power Uprate," Enclosure 2, p. 18.
32 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 3 - Issuance of Amendment Re: 4.85 Percent Stretch Power Uprate and Relocation of Cycle-Specific Parameters," Enclosure 2, p. 16.
33 NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 - Issuance of Amendment Re: Large Break Loss-of-Coolant Accident (LBLOCA) Analysis Methodology," July 24, 2006, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
13
WCOBRA/TRAC code, 34 IP-2's PCT was calculated at 1962°F for ZIRLO cladding in 35 422 Vantage assemblies and at 1814'F for ZIRLO cladding in 15x15 assemblies.
- d. Why Recent PCTs Calculated for IP-2, Using the 1996 WCOBRA/TRAC Computer Code and the ASTRUM methodology, are Non-Conservative.
It is significant that, in 1995, Three Mile Island Unit 1 ("TMI-I") Cycle 10 (a PWR) operated with crud deposits on the surface of fuel rods that caused regions of the cladding to be "subjected to temperatures in the range 450 to 500'C or greater." 36 Under 37 typical operating conditions at TMI-1 the maximum cladding temperature is 346°C, meaning that crud deposits raised local cladding temperatures by over 100 or 150'C (180 or 270 0 F) or greater, during cycle 10. Hence, if IP-2 had operated with heavy crud and oxide layers on its cladding in recent years, the calculated PCT in a computer simulation of a LB LOCA would have with high probability increased, from recently calculated values of 1962 0 F to 2188 0 F, by hundreds of degrees Fahrenheit, and violated 10 C.F.R. § 50.46(b)(1) by exceeding 2200'F (if the thermal resistance of such layers were taken into account in the calculation).
- 3. Why Recent ECCS Evaluation Calculations for IP-2, Using the 1996 WCOBRA/TRAC Computer Code and the ASTRUM methodology, are Non-Conservative for All Requirements of 10 C.F.R. § 50.46(b).
Recent ECCS evaluation calculations for IP-2, using the WCOBRA/TRAC code, dating from 1996,, and the ASTRUM methodology, 38 bounded in the 1996 34 Cesare Frepoli, Katsuhiro Ohkawa, Robert M. Kemper, "Realistic Large Break LOCA Analysis of AP 1000 with ASTRUM," The 6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety, Nara, Japan, October 4-8, 2004, pp. 7-8.
31 See NRC, letter to Entergy, "Indian Point Nuclear Generating Unit No. 2 - Issuance of Amendment Re: Large Break Loss-of-Coolant Accident (LBLOCA) Analysis Methodology," , p. 3; see also Entergy, Attachment I to NL-05-058, "Reanalysis of Large Break Loss of Coolant Accident Using ASTRUM," April 22, 2005, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML051230311, pp. 1-2.
36 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 342.
37 World Nuclear Industry Handbook, 1995, Nuclear Engineering International (England), p. 80.
38 "The ASTRUM method is based on a non-parametric (distribution free) statistics. For the same conditions this technique is expected to reduce the final PCT estimate (95/95 PCT) by about 150°F. This is achieved because of the elimination of the superposition penalty." See Cesare 14
WCOBRA/TRAC code, are non-conservative, because they did not model scenarios where one-cycle fuel would have heavily crudded and oxidized cladding or would have crud-induced corrosion failures (operating conditions experienced at PWRs in recent years).
For this reason the design basis (modeled with the WCOBRA/TRAC code) for the emergency core cooling system (ECCS) of IP-2 is substantially non-conservative in regard to 10 C.F.R. § 50.46(b), because it is based on clean cladding: the most limiting ECCS evaluation calculations were done for fresh, BOL fuel. This is standard for modeling fuel with the WCOBRA/TRAC code, despite the fact that heavy crud and oxide layers on cladding increase the stored energy in the fuel to quantities greater than that of fresh, BOL fuel.
Discussing the WCOBRA/TRAC code, Westinghouse's "Code Qualification Document for Best Estimate Small Break LOCA Analysis" states:
Hot assembly burnup affects fuel average temperature during normal operation. Fuel temperatures and steady-state peaking factors are typically highest early in the [first] fuel cycle. Because this results in higher calculated PCT during large break LOCAs, the hot rod and the39 hot assembly rod are assumed at BOL conditions in the scoping analysis.
This is significant because heavy crud and oxide layers on cladding have been documented to increase local cladding temperatures in excess of 300'F or even 600'F during operation; 40 temperatures also increase in the fuel sheathed within the cladding (i.e., the stored energy in the fuel increases). And even though such layers on cladding would substantially increase a plant's PCT in the event of LOCA, there is little or no evidence that crud has ever been properly factored into PCT calculations for postulated LOCAs. An attachment to a letter dated June 17, 2003 from Gary W. Johnsen, RELAP5-Frepoli, Katsuhiro Ohkawa, Robert M. Kemper, "Realistic Large Break LOCA Analysis of AP1000 with ASTRUM," p. 17.
39 Westinghouse, "Code Qualification Document for Best Estimate Small Break LOCA Analysis; Volume 3: PWR Uncertainties and Sensitivities for Small Break LOCA," 2003, located at:
www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
ML031570508, Section 29, p. 25.
40 See R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 342; see also NRC, "River Bend Station - NRC Problem Identification and Resolution Inspection Report 0500458/2005008," Report Details pp.10-12. River Bend, a BWR, operated with local cladding temperatures approaching 12007F during cycles 8 and 11.
15
3D Program Manager, Idaho National Engineering and Environmental Laboratory
("INEEL"), to Robert H. Leyse states:
[W]e are not aware of any user who has modeled crud on fuel elements with SCDAP/RELAP5-3D. ... We suspect that none of the other [severe accident analysis] codes have been applied to consider [fuel crud buildup]
(because it has not been demonstrated conclusively that this effect should be considered). ... SCDAP/RELAP5-3D can be used to consider this effect, it is simply that users have 41 not chosen to consider this phenomen[on] [emphasis not added].
As in the cases of other nuclear power plants, it is a serious oversight that recent IP-2 ECCS evaluation calculations have not modeled conditions of heavy crud and oxide layers on cladding. For situations where one-cycle fuel would have heavily crudded and oxidized cladding or would have crud-induced corrosion failures, the ECCS design basis for IP-2 is substantially non-conservative in at least the following aspects: 1) heavily crudded and oxidized cladding surface temperatures (at some locations) would be higher at the onset of a LOCA than the licensing basis for temperatures based on clean cladding;
- 2) the stored energy in the fuel sheathed within cladding with heavy crud and oxide layers would be substantially greater than that of fuel sheathed within clean cladding at the onset of a LOCA; 3) the amount of coolant in the vicinity of cladding with heavy crud and oxide layers at the onset of a LOCA would be substantially less than if the cladding were clean; 4) during blowdown and also during reflood the amount of coolant flow past cladding with heavy crud and oxide layers would be substantially less than the flow past clean cladding; 5) the increased quantity of the stored energy in the fuel and the delay in the transfer of that stored energy to the coolant caused by a heavy crud layer would cause the cladding to be subjected to extremely high temperatures for a substantially longer time duration than the time duration used in the licensing basis, providing more time for heatup and degradation of the fuel and cladding; 6) the severity of the fuel and cladding degradation occurring in the event of a LOCA and its effect on obstructing coolant flow would be -substantially greater than those calculated by an ECCS design based on clean cladding; 7) the increased quantity of the stored energy in the fuel and the delay in the 41 From an attachment of a letter from Gary W. Johnsen, RELAP5-3D Program Manager, INEEL to Robert H. Leyse, June 17, 2003, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML032050508.
16
transfer of that stored energy to the coolant would increase the time until quench; 8) at the onset of a LOCA, there would already be severe cladding degradation, massive oxidation and absorption of hydrogen at some locations, which would contribute to a loss of cladding ductility.
Therefore, it is probable that IP-2 will operate, in violation of 10 C.F.R. § 50.46(b). (It is also probable that IP-3 will operate in violation of 10 C.F.R. § 50.46(b),
because its ECCS evaluation calculations also did not model scenarios where one-cycle fuel would have heavily crudded and oxidized cladding or would have crud-induced corrosion failures.)
B. An Example of Crud-Induced Cladding Corrosion Failures: Three Mile Island Unit 1 Cycle 10.
In 1995, Three Mile Island Unit I ("TMI-I"), a PWR, operated with crud deposits on the surface of fuel rods that caused regions of the cladding to be "subjected to temperatures in the range 450 to 500'C or greater." 42 Under typical operating conditions at TMI-1 the maximum cladding temperature is 346'C, 43 meaning that crud deposits raised local cladding temperatures. by over 100 or 150'C (180 or 270'F) or greater.
Therefore, it is highly probable that if a LB LOCA had occurred at TMI-1 during a significant period of cycle 10, the heavy crud and oxide layers on the cladding would have caused the PCT to exceed 2200'F.
Discussing crud and its effect on increasing cladding temperature, the paper "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10" states:
The cause of the higher temperature on the outer face of the peripheral rods is believed to result from local deposition of a crud layer, which impeded heat transfer. Steam blanketing within a layer of dense crud could significantly increase local temperatures, and it has been implicated in past fuel failures in low duty PWRs, and more recently in failures in higher duty plants. The effect of steam blanketing would be similar to a 42 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," American Nuclear Society, Proceedings of the 2004 InternationalMeeting on L WR Fuel Performance, Orlando, Florida, September 19-22, 2004, p. 342.
43 World Nuclear Industry Handbook, 1995, Nuclear Engineering International (England), p. 80.
17
dryout, both would preclude water to effectively44 remove heat from the fuel rod surface, causing the fuel rod to over-heat.
At TMI-1 Cycle 10, the first leaking rod (a symptom of a cladding perforation) was detected 121 days into the cycle. 45 When cladding is perforated by corrosion, increases in offgas activity are detected in the coolant. Different steps can be taken: the power can be suppressed at the assemblies where leaking rods are detected or the fuel cycle can be terminated in order to remove the failed fuel rods. But because corrosion is not detected during plant operation, there is often a significant length of time before corrosion progresses and perforates cladding and causes an increase in offgas activity, meaning that heavily corroded fuel rods are often operated at full power for significant periods of time. It is hypothesized that at TMI-1 Cycle 10 cladding temperatures of a range of 450 to 500'C or greater lasted "for an indeterminate time, but within the range 46 of -1000 to 10 hours1.157407e-4 days <br />0.00278 hours <br />1.653439e-5 weeks <br />3.805e-6 months <br /> for the respective temperature limits."
In 1995, TMI-1 had PWR Zr-4 fuel-rod cladding with a thickness of .67 mm or 670 jIm (microns).4 After cycle 10, 38 fuel assemblies were observed with a Distinctive Crud Pattern ("a mottled appearance of a dark, nearly black surface with jagged patches of white showing through").48 Additionally, after cycle 10, the maximum oxide thickness measured on a fuel rod was 111.1 Jim, at an axial elevation of 118.5 inches. 49 Therefore, the equivalent cladding reacted ("ECR"); that is, the percentage of the cladding of that rod that had oxidized, was 10.6% (this percentage is calculated by dividing the oxide thickness (111.1 jim) by the oxide to metal ratio of 1.5650 (the value 1.56 is derived from the atomic weights of the elements involved in the chemical reaction of oxygen and Zircaloy cladding) and then dividing that value (71.2 gm) by the cladding thickness (670 Pim)).
44 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 343.
45 Id., p. 339.
46 Id., p. 342.
47 World Nuclear Industry Handbook 1995, p. 80.
48 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 340.
49 Id., p. 344.
50 NRC, Advisory Committee on Reactor Safeguards, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting Transcript, January 19, 2007, p. 243.
18
It is pertinent that, "Evaluation of Advanced Cladding and Structural Material (M5) in PWR Reactor Fuel," from 2000, states, "[r]ecent out-of-reactor measured elastic and plastic cladding strain values from high burnup cladding from two PWR fuel vendors have shown a decrease in Zr-4 cladding ductilities when oxide thicknesses begin to exceed 100 ýtm. As a result, the NRC staff has encouraged fuel vendors to establish a maximum oxide thickness limit of 100 gm."51 (This is a NRC recommendation for guidance; it is not a legally binding regulation.) (It is also significant, that the TMI-1 Cycle 10 cladding-because of the low thermal conductivity of the crud layer-had an oxide thickness measured at over 100 ptm (on one-cycle cladding), and that one-cycle 52 cladding was initially perforated by oxidation only 121 days into the cycle.)
If there had been a LOCA at TMI-1 Cycle 10, it is highly probable that the ECR, at the location where oxide thickness was measured at 111.1 ýtm, would have increased from a pre-accident value of 10.6% to a during-accident value exceeding 17%.
Petitioner's point, however, is not to make an issue out of this supposition about the 53 ECR; after all, during cycle 10, fuel rods had failed due to local corrosion perforations, and at the cladding perforations the ECR was already 100%. The point is rather to focus on the role that the thermal resistance of heavy layers of oxide and crud on cladding would play during a LOCA.
The maximum observed crud thickness from TMI-1 Cycle 10 was measured at 33
[tm.
54 However, the analysis of the crud deposits on the cladding conducted after cycle 10 could not be thorough because most of the crud samples that had been collected disappeared into a storage pool, with a pH of about 4.5, before they were examined.5 5 Typically, a great deal of PWR crud comes off the cladding during reactor shutdown: as much as four kilograms of crud can depart from cladding surfaces during reactor 51 David B. Mitchell and Bert M. Dunn, "Evaluation of Advanced Cladding and Structural Material (M5) in PWR Reactor Fuel," February 2000, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML003686365, p. xviii.
52 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 339.
53 Id., p. 343.
54 Id., p. 340.
55 NRC, Advisory Committee on Reactor Safeguards, Reactor Fuels Subcommittee Meeting Transcript, September 30, 2003, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/subcommittee/2003/rf093003.pdf (accessed on 01/21/07), p. 241.
19
shutdown. Hence, the thickness of the crud that deposits on the cladding during plant operation is often unknown. 56 Thus, in the case of TMI-1 Cycle 10, the crud thicknesses were almost certainly much thicker than the values measured; perhaps they were 100 vtm or greater. In fact, crud deposits on cladding in PWRs have been measured at up to 125 ptm thick.5 7
- 1. The Thermal Conductivities of Crud and Zirconium Dioxide.
As already mentioned, crud layers increased local cladding surface temperatures by over 180 or 270'F or greater during cycle 10 because the thermal conductivity of the crud was very low. Pertaining to the thermal conductivity of crud, Bo Cheng of Electric Power Research Institute ("EPRI"), at the NRC's Advisory Committee on Reactor Safeguards ("ACRS"), Reactor Fuels Subcommittee, September 30, 2003, stated:
[T]he thermal conductivity of the crud all depends on the morphology more than from the type, the chemical composition because the crud, say, it comes as a solid, the solid iron oxide conductivity is better than zirconium by maybe a factor of two to five. ... If the morphology is such that it would cause a steam blanketing, then your steam has extremely poor conductivity, maybe two orders of magnitude lower than the... The crud is so difficult to characterize.
58 And the conductivities all so much depend on the morphology.
The thermal conductivity of crud is reported to be 0.8648 W/mK in volume two of the code manual, "Frapcon-3: A Computer Code for the Calculation of Steady-State, Thermal-Mechanical Behavior of Oxide Fuel Rods for High Burnup."5 9 This same value for the thermal conductivity of crud is given in NUREG-1230, dating back to 1988.60 So it is evident that-although 0.8648 W/mK is a very low thermal conductivity-Cheng thought a crud layer with steam blanketing would have an even lower thermal conductivity than 0.8648 W/mK. He stated that steam trapped within a crud layer (with 56 Id., pp. 241-242.
57 Id., p. 133.
58 Id., p. 240.
59 Pacific Northwest National Laboratory, NUREG/CR-6534, Volume 2, "Frapcon-3:
A Computer Code for the Calculation of Steady-State, Thermal-Mechanical Behavior of Oxide Fuel Rods for High Burnup," 1997, p. 2.8.
60 NRC, NUREG-1230, "Compendium of ECCS Research for Realistic LOCA Analysis,"
1988, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
ML053490333, p. 6.14-4.
20
steam blanketing) would have "extremely poor conductivity." (This is because the thermal conductivity of steam is extremely low: it has been measured between values of 0.0154 and 0.0678 Btu/hrftF (0.0267 and 0.1173 W/mK) between temperatures of 250 and 1500'F (394.26 and 1088.7°K) and pressures of 20 and 2000 psia.) 6 I And he also stated that "crud is.. .difficult to characterize" and that its thermal "conductivities... depend on [its] morpholog[ies].,, 62 (For example, a -100 ýtm crud flake, from a boiling water reactor ("BWR") that experienced crud-induced fuel failures, has been described as having a 50% porosity with voids and plugged up steam chimneys.) 63 Therefore, it is clear that certain morphologies of crud have thermal conductivities that are less than 0.8648 W/mK and of unknown values.
In fact, EPRI currently (to be completed in 2008) has a goal to "[p]erform crud 64 simulation tests to determine the effect of tenacious crud on fuel surface heat transfer."
This study is for BWR crud but its results could also be applied to PWRs. As the article "Fuel Crud Formation and Behavior," describing a project for sampling BWR crud flakes, claims: "methods developed to determine the number and distribution of chimneys and capillaries on fuel crud surface, essential in understanding the adequacy of heat transfer within.. .crud deposit[s] have large applications for both PWR and BWR fuel depositions.'" 65 Whether or not the findings of this research will be applied to modeling crud for calculations of PCTs during postulated LOCAs is open to conjecture.
Zirconium dioxide (ZrO2) or zirconia also has a low thermal conductivity, and is used industrially as an insulating material. 66 The thermal conductivity of zircaloy-61 C. A. Meyer, R. B. McClintock, G. J. Silvestri, R. C. Spencer, Jr., ASME Steam Tables, The American Society of Mechanical Engineers, 1983, p. 281.
6' NRC, Advisory Committee on Reactor Safeguards, Reactor Fuels Subcommittee Meeting Transcript, September 30, 2003, p. 240.
63 Rosa Yang, Odelli Ozer, Kurt Edsinger, Bo Cheng, Jeff Deshon, "An Integrated Approach to Maximizing Fuel Reliability," American Nuclear Society, Proceedings of the 2004 International Meeting on L WR Fuel Performance,Orlando, Florida, September 19-22, 2004, p. 14.
64 EPRI, "2007 Portfolio, AP41.02 Fuel Reliability," located at:
http://mydocs.epri.com/docs/Portfolio/PDF/2007_P041-002.pdf (accessed on 01/21/07), p. 5.
65 Charles Turk, "Fuel Crud Formation and Behavior," NuclearPlant Journal,January-February 2006, located at:
http://npj.goinfo.com/NPJMain.nsf/504ca249c786e20f85256284006da7ab/89609e29 1af0b7b286 257194007576c I ?OpenDocument (accessed on 01/21/07).
66 The following is from a description of the "Hot Spot 110: 1700'C Lab Furnace": "The zirconia insulation incorporated in the Hot Spot 110 has the lowest thermal conductivity of any 21
cladding oxide has been measured between 1.354 and 1.586 W/mK at temperatures between 297 and 1450'K, dipping as low as 0.955 W/mK at 668°K.67 Additionally, volume one of the code manual, "Frapcon-3" (published in 1997) states that the current MATPRO function for ZrO2, uses values of approximately 2.0 W/mK for the thermal conductivity of ZrO2 at typical LWR operating cladding temperatures. But it also states that in 1995 an EPRI-sponsored Halden Reactor experiment gave indications that the value for the thermal conductivity of ZrO2 at the same temperatures may be much lower, at values close to 1.0 W/mK.6 8 Like crud, oxide also impedes heat transfer:
Crud inhibits heat transfer, increasing clad temperature and oxide layer growth rate. ... Oxide can form, with or without the benefit of crud, in the presence of sustained elevated cladding temperatures. Like crud, formation of an oxide layer inhibits heat transfer 69 causing accelerated corrosion which can potentially lead to fuel failure.
- 2. A Discussion of an Individual Fuel Rod at TMI-1 Cycle 10.
Fuel rod (rod 011) was one of the fuel rods that failed at TMI-1 Cycle 10. As already mentioned, the maximum oxide thickness measured on rod 011 was 111.1 pim, and elsewhere on the same rod oxidation had perforated the cladding. There is a high probability that during cycle 10, on rod 011 there had been a crud layer that was approximately 100 ýtm thick on top of the 111.1 ýtm oxide layer. Such a crud layer would have been the primary cause of the 111.1 ýtm oxide layer, as well as the perforations, on rod 011. Therefore, it is highly probable that rod 011 had an approximately 200 ptm layer of oxide and crud combined; that is, a heavy layer with a very low thermal conductivity (with plausible values of approximately 1.4 W/mK or less commercially available high temperature insulation," located at:
http ://www.zircarzirconia.com/doc/F-HS.pdf (accessed on 01/21/07).
67 K. E. Gilchrist, "Thermal Property Measurements on Zircaloy-2 and Associated Oxide Layers,"
Journalof NuclearMaterials,62, 1976, pp. 257-264.
68 Pacific Northwest National Laboratory, NUREG/CR-6534, Volume 1, "Frapcon-3:
Modifications to Fuel Rod Material Properties and Performance Models for High-Burnup Application," 1997, p. 8.3.
69 Yovan D. Lukic and Jeffery S. Schmidt, "Taming the Crud Problem: The Evolution," Advances in Nuclear Fuel Management III Conference, Hilton Head Island, South Carolina, October 2003.
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for the oxide portion of the layer and a value less than 0.8648 W/mK-most li.kely, substantially less-for the crud portion).
If a LB LOCA had occurred at TMI-1 Cycle 10, the very low thermal conductivity of the 200 ptm layer of oxide and crud combined would have inhibited effective heat transfer and with high probability caused the PCT to exceed 22007F
(-1204'C), in violation of the parameter set forth in 10 C.F.R. § 50.46(b)(1).
The 111.1 [tm oxide layer and the crud layer of a possible thickness of approximately 100 [tm were on rod 011 at an elevation 118.5 inches above the bottom of the end plug, or about 80% above the base of the active core. At TMI-1 Cycle 10, the crud layer was observed to be heaviest in span six of the fuel assemblies, which was "the hottest span" of the assemblies during cycle 10.71 Additionally, the transcript of proceedings from NRC ACRS, Reactor Fuels Subcommittee, September 30, 2003, states that nine fuel rods failed at the span-six elevation. 72 Crud was also observed in spans five and seven7 3 or at elevations from around 80 to 120 inches above the bottom of the end plug7 4 (around 55 to 80% above the base of the active core). Typically, during a postulated LOCA the PCT occurs approximately 60% above the base of the active core.
(At TMI-1 Cycle 10, the PCT would have most likely occurred in span six: "the hottest span.") Therefore, for clean cladding at TMI-1, during a postulated LOCA, it seems highly probable that at an elevation of 118.5 inches, the temperature would have been calculated within 1007F of the PCT. (Of course, this is a simple assessment: the phenomena occurring during a LOCA are very complex; the actual elevation of the PCT for clean cladding at TMI-1, around 1995, can be researched, as well as what the temperature would have been at the 118.5 inch elevation for clean cladding.) Therefore, during cycle 10, it is highly probable that the cladding temperature would have exceeded 70 World Nuclear Industry Handbook 1995, p. 80. At Three Mile Island during cycle 10 the active core height was 3.6 meters or 143.9 inches.
" See R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 340; see also NRC, Advisory Committee on Reactor Safeguards, Reactor Fuels Subcommittee Meeting Transcript, September 30, 2003, p. 236.
72 Id., p. 236.
13 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 340.
74 Id., p. 344.
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22007F during a postulated LB LOCA at the 118.5 inch elevation' on rod 011, as well as at the span-six elevation where rod 011 failed.
It is significant that in rod 011 there was massive absorption of hydrogen, to the extent that "hydrided material seems to have broken away from the outer portions of the 76 cladding." 75 Cladding hydrogen content was measured on a non-failed rod at 700 ppm.
Therefore, it is highly probable that rod 011 absorbed at least 700 ppm of hydrogen at locations of its upper elevation. Incidentally, this value for hydrogen content in one-cycle cladding is similar to values that have been measured in high-burnup cladding: at (PWR) H. B. Robinson-2, high-burnup cladding hydrogen content was measured at 800 ppm.77 An increase in cladding hydrogen content contributes to cladding embrittlement.
The transcript of proceedings of NRC, ACRS, Reactor Fuels Subcommittee Meeting, April 4, 2001, relates the opinions of two experts regarding hydrogen content's role in reducing cladding ductility:
Hee Chung [of Argonne National Laboratory] now points out that for Zircaloy, that there seems to be a threshold around 600 or 700 ppm hydrogen. When you get that much hydrogen in the specimen, then it also contributes to the reduction of ductility..... Griger [of KFKI Atomic Energy Research Institute] believes that he sees a threshold [for a reduction of ductility 78 for Zircaloy] at a much lower level, down around 150 to 200 [ppm].
It is also significant that rod 011 was perforated by oxidation and that it had a 111.1 ýtm oxide layer at the 118.5 inch elevation, because there is "a decrease in Zr-4 79 cladding ductilities when oxide thicknesses begin to exceed 100 ýtm."
75 R. Tropasso, J. Willse, B. Cheng, "Crud-Induced Cladding Corrosion Failures in TMI-1 Cycle 10," p. 342.
76 Id., p. 347.
77 NRC, Advisory Committee on Reactor Safeguards, Reactor Fuels Subcommittee Meeting Transcript, July 27, 2005, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/subcommittee/2005/rf072705.pdf (accessed on 01/21/07), p. 99.
78 NRC, Advisory Committee on Reactor Safeguards, Reactor Fuels Subcommittee Meeting Transcript, April 4, 2001, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/subcommittee/200 1/rfO 10404.html (accessed on 01/21/07).
79 David B. Mitchell and Bert M. Dunn, "Evaluation of Advanced Cladding and Structural Material (M5) in PWR Reactor Fuel," p. xviii.
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Because rod 011 was degraded from substantial oxidation and massive absorption of hydrogen it would have been somewhat embrittled during cycle 10. Therefore, if a real-life LB LOCA had occurred during cycle 10, rod 011 would have with high probability been subjected to temperatures exceeding 22007F and also with high probability fractured and fragmented during the reflood period (of the LOCA) and lost structural integrity.
C. The Stored Energy in Fuel Sheathed within Crudded and Oxidized Cladding.
When cladding temperatures are increased by layers of crud and oxide, there is also an increase in the stored energy in the fuel, because the thermal resistance of insulating layers of crud and oxide increase fuel temperatures. Describing how the quantity of stored energy in the fuel is partly related to heat transfer through cladding NUREG-1230, "Compendium of ECCS Research for Realistic LOCA Analysis," states:
The amount of stored energy [in the fuel] is directly related to the temperature of the fuel center and the temperature gradient from the fuel center to the fuel surface. The temperature of the fuel center and the temperature gradient are a function of thermal conduction within the pellet, fuel pellet cracking, heat transfer through the fuel cladding gap, and conduction through the cladding [emphasis added]. 8 ° It is significant that the quantity of stored energy in the fuel is partly related to heat transfer through cladding, because crud and oxide layers impede heat transfer through cladding. For this reason, the stored energy in the fuel increases when the cladding sheathing it is heavily crudded and oxidized. And the stored energy in the fuel at the onset of a LOCA is significant for determining the PCT during a LOCA; "Compendium of ECCS Research for Realistic LOCA Analysis," states, "[d]uring the blowdown period, fuel and cladding temperatures are in part determined by the initial 81 stored thermal energy in the fuel rods."
NRC, NUREG-1230, "Compendium of ECCS Research for Realistic LOCA Analysis," p. 6.14-2.
"1id.., p. 6.14- 1.
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Concerning the effect that fuel temperatures (or stored energy), at the onset of a LOCA, have on the PCT (during a postulated LOCA), the NRC, discussing Westinghouse's PAD 4.0 code, states:
The PAD 4.0 code is used to provide initial thermal conditions (fuel centerline and volume average temperatures) and rod pressures for the start of the LOCA analysis. The fuel volume average temperature is the primary PAD input that impacts the calculation of maximum peak cladding temperatures (PCTs) to verify that Westinghouse meets the 10 CFR 50.46 requirement of PCT not exceeding 22007F. Traditionally, the NRC has required that a best estimate code such as PAD 4.0 maintain a 95 percent bounding estimate of centerline and volume average temperatures at a 95 percent confidence level for input to LOCA analysis. ... From the example LOCA calculation provided by Westinghouse, the maximum fuel temperatures (generally corresponds to maximum PCTs) calculated by PAD 4.0 are consistent with the FRAPCON-3 code results [emphasis added] .82 Furthermore, concerning stored energy in the fuel at the onset of a LOCA, "Compendium of ECCS Research for Realistic LOCA Analysis" states:
The amount of stored energy in the fuel at the start of a reactor transient plays an important role in the response of the fuel rod during the transient.
A portion of the stored energy (typically more than 50%) is removed during the blowdown period of LOCA. The residual thermal energy is in the fuel rod at the beginning of the adiabatic heatup phase of the LOCA.
The amount of residual thermal energy influences the 83 time required to quench the reactor core with emergency cooling water.
And to clarify how a heavy crud layer would affect the stored energy in the fuel during a LOCA is a citation from a letter from James F. Klapproth, Manager, Engineering and Technology at GE Nuclear Energy, to the NRC:
The primary effects of [a] heavy crud layer during a postulated LOCA would be an increase in the fuel stored energy at the onset of the event, 82 NRC, "Safety Evaluation by the Office of Nuclear Reactor Regulation, Topical Report WCAP-15063-P, Revision 1, 'Westinghouse Improved Performance Analysis and Design Model (PAD 4.0)'," April 24, 2000, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML003706392, pp. 7-8.
83 NRC, NUREG-1230, "Compendium of ECCS Research for Realistic LOCA Analysis," p. 6-14-2.
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and a delay in the transfer of84that stored energy to the coolant during the blowdown phase of the event.
The fact that a heavy crud layer would: 1) increase the stored energy in the fuel at the onset of a LOCA; and 2) delay the transfer of that stored energy to the coolant during the blowdown phase of a LOCA, is very significant for how cladding would be affected during a LOCA.
The increase of the stored energy in the fuel caused by a heavy crud layer is substantial (in some cases, enough to increase local cladding temperatures in excess of 300'F or even 600'F during operation).8 5 This increase raises the stored energy in the fuel to levels higher than that of fresh, BOL fuel, or fuel with burnups between 30 to 35 GWd/MTU, which are considered the times of life or burnups that represent the maximum stored energy that fuel has during operation. (Fresh, BOL fuel is generally considered to have the maximum stored energy in fuel; however, COPERNIC and FRAPCON-3 (computer codes, programs that simulate LOCAs) calculate that mid-life fuel with burnups of about 30 to 35 GWd/MTU have the maximum stored energy.) 86 The quantities of the stored energy in BOL fuel or fuel with bumups between 30 to 35 GWd/MTU are what are used to calculate PCTs during postulated LOCAs by computer codes because the maximum stored energy in the fuel corresponds to the maximum PCT.87 The increased stored energy (caused by a heavy crud layer) and the delay in the transfer of that stored energy to the coolant during the blowdown phase would increase the PCT and cause the cladding to be subjected to extremely high temperatures for a 84 Letter from James F. Klapproth, Manager, Engineering and Technology, GE Nuclear Energy to Annette L. Vietti-Cook, Secretary of the Commission, NRC, April 8, 2002, located at:
www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
85 NRC, "River Bend Station - NRC Problem Identification and Resolution Inspection Report 0500458/2005008," Report Details, pp.10-12. River Bend, a BWR, operated with local cladding temperatures approaching 12007F during cycles 8 and 11.
86 "Safety Evaluation by the Office of Nuclear Reactor Regulation, Topical Report BAW-10231P,
'COPERNIC Fuel Rod Design Computer Code,' Framatome Cogema Fuels, Project No. 693,"
2002, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
87 NRC, ML020070158, p. 10.
"Safety Evaluation by the Office of Nuclear Reactor Regulation, Topical Report WCAP-15063-P, Revision 1, 'Westinghouse Improved Performance Analysis and Design Model (PAD 4.0)'," pp. 7-8.
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substantially longer time duration than if the cladding where clean at the onset of the LOCA. This would provide more time for heatup and degradation of the fuel and cladding, including rapid oxidation and embrittlement of the cladding. When the cladding reacts with steam, an exothermic reaction occurs which generates heat, additionally heating up the cladding. Regarding the significance of time and temperature during a LOCA, NRC staff member, Ralph Meyer, states:
[I]n 10 CFR 50.46, part [b]... [t]here is an oxidation limit of 17[%]. This is really a time limit because it was understood at the beginning and we know it now that the embrittling process does not take place on the surface where the oxide is accumulating [during a LOCA]. It is related to the diffusion of oxygen in the metal. The diffusion process and the oxidation process run at about the same speed. And so an oxidation limit was used.
It [is] very convenient. ... It gives you a nearly constant number that you can use as a limit.... [A] basic LOCA transient calculation is just time and temperature. And then you run along with that some equation for oxidation and get a calculated oxidation amount during the transient
[emphasis added]. 88 Regarding oxidation-induced cladding embrittlement, "Compendium of ECCS Research for Realistic LOCA Analysis" states:
Embrittled cladding can fragment upon introduction of the emergency cooling water in a severe accident. During a high-temperature transient accident, the cladding becomes embrittled by steam oxidation of the zircaloy cladding and the formation of thick reaction layers of brittle oxide and oxygen-stabilized alpha zircaloy. The extent of cladding oxidation, and hence embrittlement, is a functioný of temperature, time, and the supply of steam and zircaloy. Embrittlement of the cladding may lead to loss of coolable geometry and is thus relevant to the safety analysis of fuel rods [emphasis added]. 89 The increase of the stored energy (caused by a heavy crud layer) and the delay in the transfer of that stored energy to the coolant would also increase the time until quench.
As cited before, "Compendium of ECCS Research for Realistic LOCA Analysis" states, 88 NRC, Advisory Committee on Reactor Safeguards 539th Meeting Transcript, February 2, 2007, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/fullcommittee/2007/ac020207.pdf (accessed on 02/27/07), pp. 15-16.
89 NRC, NUREG-1230, "Compendium of ECCS Research for Realistic LOCA Analysis," p. 6.14-6.
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"[t]he amount of residual thermal energy [in the fuel rod] influences the time required to quench the reactor core with emergency cooling water [emphasis added]." 90 Furthermore (not mentioned by Klapproth), at the onset of the LOCA, there would already be severe cladding degradation, massive oxidation and absorption of hydrogen at some locations, which would also contribute to a loss of cladding ductility.
D. There is Little or No Evidence that Crud has Ever been Properly Factored into PCT Calculations for Postulated LOCAs.
As already discussed, the increased stored energy in the fuel and its effect on increasing cladding temperatures during a LOCA, and its effect on delaying the transfer of stored energy to the coolant during the blowdown phase, is very significant for how cladding would be affected during a LOCA. However, there is little or no evidence that crud has ever been properly factored into PCT calculations for postulated LOCAs for nuclear power plants. An attachment to a letter dated June 17, 2003 from Gary W.
Johnsen, RELAP5-3D Program Manager, Idaho National Engineering and Environmental Laboratory ("INEEL"), to Robert H. Leyse states:
[W]e are not aware of any user who has modeled crud on fuel elements with SCDAP/RELAP5-3D. ... We suspect that none of the other [severe accident analysis] codes have been applied to consider [fuel crud buildup]
(because it has not been demonstrated conclusively that this effect should be considered). ... SCDAP/RELAP5-3D can be used to consider this effect, it is simply that users have not chosen to consider this phenomen[on] [emphasis not added]. 9 1 An example of not properly factoring the thermal conductivity of crud into a PCT calculation for a postulated LOCA is in "Callaway Plant, 10 CFR 50.46 Annual Report, ECCS Evaluation Model Revisions," dating from 2002. It states, "+4.0'F Cycle 6 crud deposition penalty has been deleted. A PCT penalty of 0°F has been assessed for 4 mils
[(-100 ptm)] of crud, provided BOL conditions remain limiting. In the event that the 90 Id., p. 6-14-2.
91 From an attachment of a letter from Gary W. Johnsen, RELAP5-3D Program Manager, INEEL to Robert H. Leyse, June 17, 2003, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML032050508.
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SBLOCA cumulative PCT becomes > 1700'F, this issue must be reassessed."92 Clearly, little attention was given to the thermal resistance of the heavy crud layer at Callaway Cycle 6 (1993), which affected high-duty, one-cycle cladding, at the upper spans 4, 5, 93 and 6 of the fuel assembly.
A recent paper, "The Chemistry of Fuel Crud Deposits and its Effect on AOA in PWR Plants," describing computer codes that model chemical conditions and heat transfer within crud deposits, helps clarify the magnitude of the error of the Callaway Cycle 6 ECCS evaluation: it states that a crud layer that is 59 lam thick is modeled so that "the rise in temperature [from the water side to the fuel side of the layer] is dramatic, reaching temperatures near 400'C [at the fuel side]," up from around 345'C at the water side of the layer. 94 This means, according to the calculations of these codes, that a 59 Pm crud layer increases cladding surface temperatures by approximately 55°C or 100°F during operation. And also, according to the calculations of these codes, that a 100 ltm crud layer would increase cladding temperatures by more than 100°F during operation.
Therefore, according to these codes, at onset of a postulated LOCA, at Callaway Cycle 6, the temperature of the cladding, at some locations, would be over 100°F higher than it would be if the cladding were clean: this would result in a substantially higher than
"+4.0°F... crud deposition penalty"' 95 for the Cycle 6 calculated PCT.
It is significant that "The Chemistry of Fuel Crud Deposits and its Effect on AOA in PWR Plants" states that the "rise in temperature [across crud layers] was not accounted for in previous models [of crud layers]." 9 6 And significant that these computer codes that model chemical conditions and heat transfer within crud deposits do not seem to model 92 Union Electric Company, "Callaway Plant, 10 CFR 50.46 Annual Report, ECCS Evaluation Model Revisions," October 14, 2002, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML023010263, Attachment 2, p. 6, note 3.
93 Bo Cheng, David Smith, Ed Armstrong, Ken Turnage, Gordon Bond, "Water Chemistry and Fuel Performance in LWRs."
9' Jim Henshaw, John C. McGuire, Howard E. Sims, Ann Tuson, Shirley Dickinson, Jeff Deshon "The Chemistry of Fuel Crud Deposits and Its Effect on AOA in PWR Plants," 2005/2006, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
ML063390145, p. 8.
95 Union Electric Company, "Callaway Plant, 10 CFR 50.46 Annual Report, ECCS Evaluation Model Revisions," Attachment 2, p. 6, note 3.
96 Jim Henshaw, John C. McGuire, Howard E. Sims, Ann Tuson, Shirley Dickinson, Jeff Deshon "The Chemistry of Fuel Crud Deposits and Its Effect on AOA in PWR Plants," p. 8.
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morphologies of crud that have been documented to increase local cladding temperatures by over 180 or 270'F or greater during PWR operation. Therefore, it is possible that the actual thermal resistance of the crud at Callaway Cycle 6 was greater than what these computer codes would predict. In reality, the increase in temperature across the 100 [tm crud layer might have been significantly greater than what these codes would have calculated in 2005/2006, when the paper was written.
E. The Non-Conservatism of Not Factoring Crud into PCT Calculations.
The fact.that a heavy crud layer would increase the quantity of stored energy in the fuel at the onset of a LOCA is significant; it means that the value of the PCT would also increase, above that of fuel with the same burnup, sheathed within clean cladding.
(Of course, this does not hold for fresh, BOL fuel, because such fuel has clean cladding at the beginning of its use.) And heavily crudded one-cycle fuel has a higher quantity of stored energy in the fuel than BOL fuel; crud has caused local cladding temperatures to increase by over 300 or 600'F during the operation of nuclear power plants.
Furthermore, the effects of crud can be quick; e.g., at TMI-1 Cycle 10, one-cycle fuel had a cladding perforation, caused by corrosion, detected only 121 days into the cycle. It is also significant that most of the cladding that experienced crud-induced corrosion failures recently at PWRs was high-power, one-cycle cladding, 97 and that crud layers approximately 100 Vm thick at Callaway Cycle 6 were on high-power, one-cycle 98 cladding.
BOL fuel or fuel with burnups between 30 to 35 GWd/MTU (sheathed within clean cladding) are the times of life or burnups considered to have the maximum stored energy that fuel has during operation. For this reason, the quantities of stored energy in BOL fuel or fuel with burnups between 30 to 35 GWd/MTU are what are used to 97 NRC, Advisory Committee on Reactor Safeguards, Reactor Fuels Subcommittee Meeting Transcript, September 30, 2003, p. 235.
98 See Bo Cheng, David Smith, Ed Armstrong, Ken Tumage, Gordon Bond, "Water Chemistry and Fuel Performance in LWRs," see also Union Electric Company, "Callaway Plant, 10 CFR 50.46 Annual Report, ECCS Evaluation Model Revisions," 2002, Attachment 2, p. 6, note 3.
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calculate PCTs during postulated LOCAs by computer codes, because the maximum stored energy in the fuel corresponds to the maximum PCT. 99 (Fresh, BOL or one-cycle fuel with low burnups are usually the conditions of the fuel that are considered to have the maximum stored energy, and to yield the highest PCTs for postulated LOCAs. At the January 2007, NRC, ACRS, Subcommittee Meeting on Materials, Metallurgy, and Reactor Fuels, Mitch Nissley of Westinghouse cited data from sample LOCA calculations that showed that one-cycle fuel from burnups of zero to approximately 20 or 25 GWd/MTU yield the highest PCTs. He also stated that at burnups of around 30 GWd/MTU there is an approximate 10% reduction in achievable power, which yields PCTs that are approximately 100°C (180'F) lower than those of fresher fuel.) 100 It is significant that the stored energy of fuel (high-power, one-cycle fuel) sheathed within heavily crudded and oxidized cladding is substantially greater than the BOL quantities of stored energy that are factored into calculating PCTs during postulated LOCAs. PCT calculations that helped qualify power uprates at a number of PWRs (including IP-2 and -3) were not calculated with the maximum stored energy that fuel can attain during operation: recent experiences with fuel at TMI-1, Palo Verde Unit 2, Seabrook, and Callaway were not modeled. Hence, the values of the PCTs generated by these ECCS evaluation calculations are non-conservative. Furthermore, the power uprates that these non-conservative PCTs helped qualify make it highly probable that nuclear power plants will operate in violation of 10 C.F.R. § 50.46(b)(1).
F. Crud and Axial Offset Anomaly.
Axial offset anomaly ("AOA") or CIPS (crud induced power shift) is a phenomenon caused by crud deposition on cladding; it helps provide an indication of 99 "Safety Evaluation by the Office of Nuclear Reactor Regulation, Topical Report BAW-10231 P,
'COPERNIC Fuel Rod Design Computer Code,' Framatome Cogema Fuels, Project No. 693," p.
- 10. WCOBRA/TRAC calculates that fresh, BOL fuel has the maximum stored energy in fuel; COPERNIC and FRAPCON-3 calculate that mid-life fuel with burnups of about 30 to 35 GWd/MTU have the maximum stored energy.
100 NRC, Advisory Committee on Reactor Safeguards, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting Transcript, January 19, 2007, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/subcommittee/2007/mmO 11907.pdf (accessed on 02/27/07), pp. 251-252.
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how frequently crud affects the operation of PWRs. AOA occurs in PWRs when crud deposits on cladding have a level of boron sufficient to reduce the rate of fission in the vicinity of the crud. "NRC Information Notice 97-85: Effects of Crud Buildup and Boron Deposition on Power Distribution and Shutdown Margin" provides a brief description of AOA and how it occurs:
High core power results in increased subcooled nucleate boiling in the upper core, which, in turn, causes greater crud accumulation on the fuel assemblies. Lithium borate is absorbed and concentrated in the crud layer, reducing the fission rate in the upper portion of the core. ... As a result of the reduced fissioning in the10 upper 1
core, the power distribution shifts toward the bottom of the core.
AOA is caused by crud deposits on fuel rods; therefore, the number of occurrences of AOA helps provide an indication of how often PWR fuel rods have crud deposits that are at least 35 ýtm thick, which is approximately the minimum thickness of crud that enables AOA to occur.102 However, there can also be crud deposits on fuel rods thicker than 35 ptm that do not cause AOA, because not all crud deposits have the quantity of boron that causes AOA. As mentioned before, the thickest layer of crud to be measured in a PWR was 125 urm thick (it caused AOA but not cladding perforations). As 03 of 2003 more than 30 fuel cycles in 16 U.S. PWRs had exhibited AOA.1 Current problems caused by crud at PWRs-AOA among them-are discussed in EPRI document "2006 Portfolio, 41.002 Fuel Reliability" as follows:
Extended fuel cycle operation and power up-rates have increased fuel duty appreciably since the 1980s. Accompanying this transition to higher duty cores have been many crud-related incidents causing anomalous and unanticipated core behavior in pressurized water reactors, fuel integrity problems, and adverse radiological events. These included axial offset anomaly as well as fuel failure cases in which crud played a significant role. ... [AOA] is a phenomenon where anomalous neutron flux behavior has been observed at many plants operating with high-energy cores.
'01 NRC, "NRC Information Notice 97-85: Effects of Crud Buildup and Boron Deposition on Power Distribution and Shutdown Margin," December 11, 1997, located at:
http://www.nrc.gov/reading-rm/doc-collections/gen-comm/info-notices/1997/in97085 .html (accessed on 01/21/07).
102 Jim Henshaw, John C. McGuire, Howard E. Sims, Ann Tuson, Shirley Dickinson, Jeff Deshon "The Chemistry of Fuel Crud Deposits and Its Effect on AOA in PWR Plants," p. 7.
103 U. S. Department of Energy, Nuclear Energy Plant Optimization ("NEPO"), "Current NEPO Projects," located at: http://nepo.ne.doe.gov/NEP02002projects.asp (accessed on 01/21/07).
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Excessive crud deposition creates operational difficulties for plant operators and has safety implications. [AOA] bears an immediate threat to nuclear power's competitiveness; 1 4 utilities would like to solve this problem as soon as possible. ° AOA is detectable during the operation of PWRs; if necessary, after it is detected, a plant can be operated at a lower power level, as H. A. Sepp of Westinghouse points out:
Several PWRs have experienced [AOAs] due to buildup of boron within crud deposits, in portions of the reactor core which experience subcooled boiling. AOA is characterized by axial power distributions that are more skewed to the bottom of the core than would be expected. These AOA are detectable, and are closely monitored to ensure that adequate shutdown margins can be maintained. In extreme cases, reductions in operating power level have been required to maintain adequate shutdown margin.°5 What Sepp describes is a case of reducing operating power according to the severity of AOAs, not according to the thickness of crud deposits. In PWRs there can be heavy crud deposits with low levels of boron; in such cases there would only be slight AOAs or no AOAs at all. For example, TMI-1 Cycle 10 had only a slight AOA even though it had enough crud to induce corrosion fuel failures. In common practice, if a heavy crud layer was detected during plant operation that did not cause an AOA, it is unlikely that the operating power level would be reduced, because the thermal resistance of the crud and how it would raise the PCT in the event of a LOCA would most likely not be considered problematic.
IV. CONCLUSION After decades of operating experience, heavy crud and/or oxide layers on cladding or crud-induced corrosion failures remain within the realm of possible operating conditions for nuclear power plants. Moreover, power uprates and longer fuel cycles increase the likelihood of heavy crud and/or oxide layers on cladding. Discussing current 04 EPRI, "2006 Portfolio, 41.002 Fuel Reliability," located at:
http://www.epriweb.com/public/2006_P041-002.pdf (accessed on 01/21/07), pp. 2-3.
105Attachment of a letter from H. A. Sepp, Manager, Regulatory and Licensing Engineering, Westinghouse Electric Company to Annette L. Vietti-Cook, Secretary of the Commission, NRC, December 17, 2001, located at: www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number: ML020530290.
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trends in the nuclear industry for both PWRs and BWRs (crud or corrosion related fuel failures occurred at BWRs in six of the yeais from 1997 to 2004)106 an EPRI document, "2006 Portfolio, 41.002 Fuel Reliability," states:
[T]he overall industry fuel failure rate has risen in the last couple of years as increased fuel duty and new water chemistry environments have presented increasing challenges to cladding integrity in today's extended fuel cycle operation. [Additionally], front-end economics and reliability are not always harmonious. Fuel vendor research and development, for example, has been significantly scaled back to keep the business competitive,10while 7
utilities are operating the fuel more aggressively than ever before.
This EPRI document also refers to the "many operational surprises utilities have experienced recently"' 10 8 at nuclear power plants, stating that among the operational 10 9 surprises were "higher than expected [levels of] cladding corrosion and hydriding."'
(Petitioner would add higher than expected levels of crud.) Meanwhile, in recent years, numerous power uprates and license renewals, largely based on non-conservative ECCS evaluation calculations (like those that helped qualify the recent power uprates of IP-2 and -3), have been granted for nuclear power plants.
At the NRC's 539th ACRS Meeting, in February 2007, Jennifer Uhle, Deputy Division Director of Materials Engineering in the Office of Nuclear Regulatory Research, stated that the current criteria of 10 C.F.R. § 50.46 are non-conservative.1 "0 When discussing possible revisions to 10 C.F.R. § 50.46 at the same meeting, and at the NRC's ACRS, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting, in January 2007, there was concern that high-burnup fuel with cladding degradation-high levels of oxidation and hydriding-would exceed the 17% oxidation limit in the event of LOCAs at nuclear power plants. The guideline of "NRC Information Notice 98-29," stipulating that the "[t]otal oxidation [of cladding] includes both pre-accident oxidation and 106 Rosa Yang, Odelli Ozer, Kurt Edsinger, Bo Cheng, Jeff Deshon, "An Integrated Approach to Maximizing Fuel Reliability," p. 11.
107 EPRI, "2006 Portfolio, 41.002 Fuel Reliability," p. 1.
108 Id., p. 2.
109 Id.
110 NRC, Advisory Committee on Reactor Safeguards 539th Meeting Transcript, February 2, 2007, located at: http://www.nrc.gov/reading-rm/doc-collections/acrs/tr/fullcommittee/2007/ac020207.pdf (accessed on 02/27/07), pp. 8, 10.
35
oxidation occurring during a LOCA" 111 is being considered for regulation status for a new revised version of 10 C.F.R. § 50.46, due in 2009.112 At the January 2007 meeting, NRC staff member Ralph Meyer stated that the purpose of the 17% limit (and the 2200'F limit) was to ensure that cladding ductility was retained, by remaining below those limits, in the event of a LOCA.113 He also provided examples regarding cladding ductility where the value 1.2 (the F factor)1 14 was multiplied by the pre-accident ECR in order to calculate the remaining percentage of oxidation allowed to occur during a LOCA.11 5 He explained that the F factor "depends most strongly on the temperature transient, on heat-up rates and cool-down rates," and that there could be "several different.. .transients that [would] have different heat-up rates and cool-down rates, and [that 1.2] is sort of a middle of the road value."' 116 (A NRC regulatory guide states that the F factor can vary from 1 to 1.6.117 The F factor's use in 1 18 LOCA calculations is also being considered for regulation status.)
At the January 2007 meeting, Meyer cited the following "worst case zircaloy,"
postulated-LOCA example:
[W]e have a de facto corrosion limit [that is] used in safety analyses of 100 microns, and zircaloy can get that much corrosion on it if you push it hard enough. And so [I have] taken this example right at the limit. So this would be what I call a worst case zircaloy example, and the 100 microns is about [10%] ECR, and you multiply that by 1.2,11 subtract 9
the 12 from 17, and you get five percent, a fairly small number."
NRC, "NRC Information Notice 98-29: Predicted Increase in Fuel Rod Cladding Oxidation."
112 See NRC, Advisory Committee on Reactor Safeguards, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting Transcript, January 19, 2007, p. 245; see also NRC, Advisory Committee on Reactor Safeguards 539th Meeting Transcript, February 2, 2007, p. 10.
113 NRC, Advisory Committee on Reactor Safeguards, Materials, Metallurgy, and Reactor Fuels Subcommittee Meeting Transcript, January 19, 2007, p. 13.
114 Id., pp. 179-182.
5 Id., pp. 31-33.
116 Id., p. 31.
117 Id., pp. 181-182.
"' Id., p. 246.
119 Id., p. 33.
36
At the same meeting, in response to Meyer's "worst-case zircaloy" example, Mitch Nissley of Westinghouse Electric Company, stated:
[W]e anticipated an F factor on the order of 1.5 or 1.6, and I went through and did a shorthand calculation just to show this was similar to Dr.
Meyer's use of the 100 micron Zr-4 design limit. One hundred microns.. .is effectively a design limit at least for Westinghouse fuel, for all of our cladding types. ... If you use a large F factor, 0
[you have] got no room to work with with curb design limits on fuel.12 Then to argue that high-burnup fuel would not be subjected to extremely high temperatures in the event of a LOCA, Nissley added:
Once [the fuel] starts to burn down in terms of its achievable power levels, achievable peak cladding temperatures and the corresponding transient oxides drop off dramatically, and that comment is valid for all break sizes, both large and small beaks. The important conclusion from this [is that]
high burnup fuel [used in the U.S.] cannot [have PCTs that] approach 1200['C].yfl Then, after citing data from sample LOCA calculations that demonstrated that one-cycle fuel from burnups of zero to approximately 20 or 25 GWd/MTU yield the highest PCTs,122 Nissley concluded:
I showed you in that one example [LB LOCA] calculation that even using more or less an upper bound for the high burnup fuel in terms of relative power, it was more than 1000[°F], less limiting than the fresh fuel. I think the real message here is [we have] done a lot of testing at 1200['C] with high burnup fuel. The double-sided [oxidation] reaction is also a limit that I know of to [occur at] very high temperature[s, above approximately 1 100°C123]. [A]nd [with high burnup fuel] you just [cannot reach temperatures that high].' 2 4 The conclusion to be drawn from Nissley's argument is that the F factor would only apply to cladding sheathing high-burnup fuel that would not have enough power (or stored energy) to reach PCTs above temperatures where rapid oxidation occurs. Hence, pre-accident oxidation (and the phenomena the F factor accounts for) would not cause a 120 Id., p. 243.:
121 Id., pp. 250-25 1.
122 Id., p. 251.
123 Id.
124 Id., p. 261.
37
loss of cladding ductility for properly managed high-burnup fuel in the event of a 125 LOCA.
However, Nissley did not mention scenarios involving one-cycle fuel of burnups between zero and 25 GWd/MTU, with heavily crudded cladding. Such fuel would yield substantially higher PCTs than the examples he cited. Furthermore, the cladding, in such scenarios, where there are crud-induced corrosion failures, would be substantially more degraded than that of Meyer's "worst-case zircaloy" example, where cladding had an ECR value of 10%. At TMI-1 Cycle 10, cladding was measured with approximately 10%
ECR; however, there were also cladding perforations due to corrosion at TMI-1 Cycle 10, so its maximum ECR was actually 100% on one-cycle, high-powered fuel. The fuel at TMI-1 Cycle 10 (and any other nuclear power plant with crud-induced corrosion failures on one-cycle, high power fuel rods) would yield higher PCTs than fresh, BOL fuel; and this fuel was sheathed within cladding that was more degraded than that of Meyer's "worst case zircaloy" example. Hence, such fuel is similar to BOL fuel but it yields even higher PCTs, and such cladding is similar to high-burnup cladding but it is even more degraded.
Uhle is certainly correct that the current criteria of 10 C.F.R. § 50.46 are non-conservative, though the NRC still has not addressed the extent of this non-conservatism.
For example, the NRC has not addressed the role that the thermal resistance of crud and oxide layers on cladding play in determining the quantity of stored energy in the fuel at the onset of a postulated LOCA. (Petitioner recently submitted a petition for rulemaking (PRM-50-84), requesting that the NRC amend Appendix K to Part 50-ECCS Evaluation Models I(A)(1), The Initial Stored Energy in the Fuel, to require that the steady-state temperature distribution and stored energy in the fuel at the onset of a postulated LOCA be calculated by factoring in the role that the thermal resistance of crud and/or oxide 126 layers on cladding plays in increasing the stored energy in the fuel.)
125 This is discussed in more detail in NRC, Advisory Committee on Reactor Safeguards 539th Meeting Transcript, February 2, 2007, pp. 60-64.
126 Mark Edward Leyse, Petition for Rulemaking 50-84, March 15, 2007, located at:
www.nrc.gov, Electronic Reading Room, ADAMS Documents, Accession Number:
38
It is significant that Westinghouse as well as other vendors have not modeled fuel and cladding conditions experienced at nuclear power plants in recent years for their NRC approved best-estimate ECCS evaluation models (like the WCOBRA/TRAC code),
used in lieu of Appendix K to Part 50 calculations. 127 In the case of IP-2 and -3, less than 40 miles north of New York City, this lack of ECCS evaluation model conservatism puts millions of people at risk. It is highly probable that if a LB LOCA were to occur at either IP-2 or -3 under circumstances where one-cycle fuel would have heavily crudded and oxidized cladding or crud-induced corrosion failures, the parameters set forth in 10 C.F.R. § 50.46(b) would be violated.
For conditions where one-cycle fuel would have heavily crudded and/or oxidized cladding or would have crud-induced corrosion failures the current ECCS design basis for either IP-2 or -3 is substantially non-conservative in at least the following aspects: 1) heavily crudded and oxidized cladding surface temperatures (at some locations) would be higher at the onset of a LOCA than the licensing basis for temperatures based on clean cladding; 2) the stored energy in the fuel sheathed within cladding with heavy crud and oxide layers would be substantially greater than that of fuel sheathed within clean cladding at the onset of a LOCA; 3) the amount of coolant in the vicinity of cladding with heavy crud and oxide layers at the onset of a LOCA would be substantially less than if the cladding were clean; 4) during blowdown and also during reflood the amount of coolant flow past cladding with heavy crud and oxide layers would be substantially less than the flow past clean cladding; 5) the increased quantity of the stored energy in the fuel and the delay in the transfer of that stored energy to the coolant caused by a heavy crud layer would cause the cladding to be subjected to extremely high temperatures for a substantially longer time duration than the time duration used in the licensing basis, providing more time for heatup and degradation of the fuel and cladding; 6) the severity of the fuel and cladding degradation occurring in the event of a LOCA and its effect on obstructing coolant flow would be substantially greater than those calculated by an ECCS 127 NRC, "10 CFR Part 50: Risk-Informed Changes to Loss-of-Coolant Accident Technical Requirements," 2005, located at: http://www.nrc.gov/reading-rm/doc-collections/commission/secys/2005/secy2005-0052/2005-0052scy.pdf (accessed on 01/21/07), p.
- 11. Best-estimate ECCS evaluation models used in lieu of Appendix K calculations are described in NRC Regulatory Guide 1.157.
39
design based on clean cladding; 7) the increased quantity of the stored energy in the fuel and the delay in the transfer of that stored energy to the coolant would increase the time until quench; 8) at the onset of a LOCA, there would already be severe cladding degradation, massive oxidation and absorption of hydrogen at some locations, which would contribute to a loss of cladding ductility.
To uphold its congressional mandate to protect the lives, property, and environment of the people of New York, the NRC must not allow the current power production levels of IP-2 and -3 to be based on non-conservative ECCS evaluation calculations. Petitioner requests that the NRC either 1) revoke the operating license of IP-2 and -3, 2) order the licensee of IP-2 and -3 to immediately suspend the operations of IP-2 and -3, or 3) temporarily shutdown IP-2 and -3, per 10 C.F.R. § 2.202. In the event of option 3, Petitioner requests that the NRC order the licensee to correct the current deficiencies of the ECCS design basis and reconfigure the power production levels of both plants, making IP-2 and -3 compliant with 10 C.F.R. § 50.46(b). If implemented, the enforcement actions proposed in this petition would improve public and plant worker safety.
To: Luis A. Reyes Executive Director for Operations U.S. Nuclear Regulatory Commission Washington, D.C. 20555-0001 Respectfully submitted, Mark Edward Leyse P.O. Box 1314 New York, NY 10025 me12005@columbia.edu Dated: April 24, 2007 40
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