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| issue date = 06/21/1983
| issue date = 06/21/1983
| title = Rev 0 to Chemistry Procedure 12.10.3, Post-Accident Sampling & Analysis,Determination of Chlorides.
| title = Rev 0 to Chemistry Procedure 12.10.3, Post-Accident Sampling & Analysis,Determination of Chlorides.
| author name = MARTIN J
| author name = Martin J
| author affiliation = WASHINGTON PUBLIC POWER SUPPLY SYSTEM
| author affiliation = WASHINGTON PUBLIC POWER SUPPLY SYSTEM
| addressee name =  
| addressee name =  
Line 17: Line 17:


=Text=
=Text=
{{#Wiki_filter:s cL HINGTON PUBLIC PO)VER SUPPLY SYSTEM PI.AiT PRO(:EL)i RE'II:hi LAI.O'I P-PROCEDURE NUMBER<<12e10.3 APPRO ED DATE 06/21/83 VOLUME NAME 12 CHEMISTRY PROCEDURES SECTION 12.10 POST ACCIDENT SAMPLING AND ANALYSIS TITLE+12.10.3 DETERMINATION OF CHLORIDES 12.10.3.1 P~uz oee This procedure describes a method of determining low level chloride con-centrations on post accident liquid sample diluted 1 ml to 10 ml final volume.12.10.3.2 Precautions/Prere uisites A.Analysis are to be performed when conditions are Al ARA.B.Direct waste lines from the ion chromatograph to shielded con-tainer in a hood.C.Dionex System 2 valves must be toggled to: 1.Separator 2 2.Suppressor 2 Eluent 2 D.Dionex System 2 flow rate should be approximately 3.0 mls/min.E.HP 3390 Integrator Settings 1.Run'arameters setting Zero=0 ATT2=8 Cht.SP=Oe5 Pk.WD.=0.40 830705015b 830b23 PDR ADOCK 05000397 E'DR WP.S97 Rl 12.10.3 0 PROCEDURE NUMBER REVISION NUMBER+AGE NUMBER 12.10.3-1 of 4 8JJg Sf'~)g~'l I I V'hrsh=7 Ar Rej=0 2.Report Optns Settings RF UNC PKS=0.0 E+0 Mul Factor=Scale Setting from Dionex conductivity meter Pk Height Mode Yes Extend.RT RPRT UNC Pks Yes 3.Time TBL 20.00 STOP F.Appropriate dose rate meters must be present and calibrated.
{{#Wiki_filter:s cL     HINGTON PUBLIC PO)VER SUPPLY SYSTEM PI.AiT PRO(:EL)i   RE 'II:hiLAI.
Survey all equipment for exposure rates continuously during analysis and sample handling.12.10.3.3 R~ea enta-(Prepare when required)A.Eluent 2-0.0015 M NaHC03 Dissolve 0.5040 gms NaHC03 in one liter demineralized water then dilute to 4 liters.Label as per PPM 12.2.6.4.B.Regeneration Solution-1N H2S04 to approximately 800 mls of demineralized water add slowly ill mls concentrated sulfuric acid.Allow to cool to room temperature then dilute to 4 liters.Label as per PPM 12.2.6.4.C.Chloride Standard-10 ppb From a stock 1000 ppm standard dilute serially to 10 ppb.Label as per 12.2.6.4.,12.10.3.4 E~ui ment A.Fast run anion separator column B.Anion suppressor C.3cc or larger, disposable syringes D.Evacuated 14cc gas vial W~98 ROCKDUAK NUM8KA REVISION NUM8KA PAGE NUM8KA 12.10.3 0 12.10.3-2 of 4 e l2.10.3.5 Procedure A.Fill a disposable syringe with air and attach to the system 2 injection port.B.Place the load/inject switch to load.C.Inject air into the sample loop to remove any liquid from the sample line.D.Place the sample needle into the 10 ppb chloride standard solution.E.F.Using the syringe, draw the standard into the sample loop until liquid is seen entering the syringe.Enter the conductivity scale setting into the integrator multiplica-tion factor.Push OP then 6, enter scale setting number, then press enter.Simultaneously place the load/inject switch to inject and press the integrator start button.Place the load/inject switch to load after approximately 10 seconds.After the chromatogram has run calibrate the integrator using the following steps: Del Calib Calib ESTD Ref RTW RTW Cal 1 RT=(enter Cl retension time in minutes)AMT=(enter Cl standard amount, 10 ppb)ENTER With the load/inject switch in load, flush the sample loop with demineralized water.K.L.Flush the sample loop with air.Place the sample needle into the post accident sample.Enter scale setting times 10 into the integrator multiplication factor.Push OP then 6, enter conductivity meter scale setting titles 10, then press enter.W~90 PROCEDURE NUM8KR 12.10.3 REVISION NUM8KR!PAGE NUM BKR 12.10.3-3 of 4 M.Draw sample into sample loop until liquid is detected entering into the syringe.N.Sioultaneously switch load/inject switch to inject and press inte-grator start.Switch load/inject to load position after 10 seconds'.The integrator will report ppb Cl.0.Remove syringe and dispose of as high level radioactive waste.P.Carefuly remove the'yringe needle from the sample vial'and insert into the 14 ml evacuated vial.Dispose of vial as high level radioactive waste after excess liquid has been drawn from the sample room.W~98 PRQCEDURE NUMBER PREVISION NUMBER 12.10.3 0!PAGE NUMBER 12.10.3-4 of 4}}
O'I P-PROCEDURE NUMBER           APPRO ED                      DATE
                          <<12e10.3                                                       06/21/83 VOLUME NAME 12       CHEMISTRY PROCEDURES SECTION 12.10     POST ACCIDENT SAMPLING AND ANALYSIS TITLE
                          +12. 10. 3 DETERMINATION OF CHLORIDES 12.10.3.1     P~uz oee This procedure describes a method of determining low level chloride con-centrations on post accident liquid sample diluted 1 ml to 10 ml final volume.
12.10.3. 2 Precautions/Prere       uisites A. Analysis are to be performed       when conditions are     Al ARA.
B. Direct waste lines from the ion chromatograph to shielded con-tainer in a hood.
C. Dionex System 2 valves must be toggled       to:
: 1. Separator 2
: 2. Suppressor 2 Eluent 2 D. Dionex System 2 flow rate should be approximately 3.0 mls/min.
E. HP   3390 Integrator Settings
: 1. Run'arameters   setting Zero = 0 ATT2 = 8 Cht. SP = Oe5 Pk. WD. = 0.40 E'DR 830705015b 830b23 PDR ADOCK 05000397 WP.S97 Rl PROCEDURE NUMBER 12.10.3 REVISION NUMBER 0
                                                                                        +AGE NUMBER 12.10.3-1 of 4
 
8JJg Sf'~)g~
              'l I
 
I V'hrsh                         = 7 Ar Rej = 0
: 2. Report Optns Settings RF UNC PKS =   0.0 E + 0 Mul Factor = Scale     Setting from Dionex conductivity meter Pk Height Mode       Yes Extend. RT RPRT UNC Pks         Yes
: 3. Time TBL 20.00   STOP F. Appropriate dose rate meters must be present and calibrated. Survey all equipment for exposure rates continuously during analysis and sample handling.
12.10.3.3     R~ea enta (Prepare when required)
A. Eluent 2   0.0015   M NaHC03 Dissolve 0.5040   gms NaHC03   in one liter   demineralized water then dilute to   4 liters. Label as per   PPM 12.2.6.4.
B. Regeneration Solution 1N H2S04 to approximately 800 mls of demineralized water add slowly       ill mls concentrated sulfuric acid.
Allow to cool to room temperature then dilute to 4 liters. Label as per PPM 12.2.6.4.
C. Chloride Standard   - 10 ppb From a stock 1000   ppm standard   dilute serially to   10 ppb. Label as per 12.2.6.4.
      ,12.10. 3. 4 E~ui ment A. Fast run anion separator column B. Anion suppressor C. 3cc or larger, disposable syringes D. Evacuated 14cc gas     vial ROCKDUAK NUM8KA     REVISION NUM8KA     PAGE NUM8KA 12.10.3                 0           12.10.3-2 of 4 W~98
 
e l2.10.3.5   Procedure A. Fill a   disposable syringe with     air and attach to the system     2 injection port.
B. Place the   load/inject switch to load.
C. Inject air into the     sample loop   to remove any   liquid from the sample line.
D. Place the sample needle     into the   10 ppb   chloride standard solution.
E. Using the syringe, draw the standard         into the   sample loop   until liquid is   seen entering the syringe.
F. Enter the conductivity scale setting into the integrator multiplica-tion factor.     Push OP then 6, enter scale setting number, then press enter.
Simultaneously place the load/inject switch to inject and press the integrator start button. Place the load/inject switch to load after approximately 10 seconds.
After the chromatogram     has run   calibrate the integrator using the following steps:
Del Calib Calib   ESTD Ref RTW RTW Cal 1   RT =   (enter Cl retension time in minutes)
AMT =   (enter Cl standard amount,     10 ppb)
ENTER With the   load/inject switch in load, flush the       sample loop with demineralized water.
Flush the sample loop with       air.
K. Place the sample needle     into the post accident sample.
L. Enter scale setting times 10 into the integrator multiplication factor. Push OP then 6, enter conductivity meter scale setting titles 10, then press enter.
PROCEDURE NUM8KR     REVISION NUM8KR        PAGE NUMBKR 12.10. 3                               12.10.3-3 of 4 W~90                                                                            !
 
M. Draw sample     into sample loop   until liquid is     detected entering into the syringe.
N. Sioultaneously switch load/inject switch to inject and press inte-grator start. Switch load/inject to load position after 10 seconds'. The integrator will report ppb Cl.
: 0. Remove   syringe and dispose of   as high level radioactive waste.
P. Carefuly remove the'yringe needle from the sample vial 'and insert into the 14 ml evacuated vial. Dispose of vial as high level radioactive waste after excess liquid has been drawn from the sample room.
PRQCEDURE NUMBER     PREVISION NUMBER      PAGE NUMBER 12.10. 3                   0           12.10.3-4 of 4 W~98                                                                    !}}

Latest revision as of 15:56, 29 October 2019

Rev 0 to Chemistry Procedure 12.10.3, Post-Accident Sampling & Analysis,Determination of Chlorides.
ML17277A626
Person / Time
Site: Columbia Energy Northwest icon.png
Issue date: 06/21/1983
From: Martin J
WASHINGTON PUBLIC POWER SUPPLY SYSTEM
To:
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ML17277A623 List:
References
12.10.3, NUDOCS 8307050156
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Text

s cL HINGTON PUBLIC PO)VER SUPPLY SYSTEM PI.AiT PRO(:EL)i RE 'II:hiLAI.

O'I P-PROCEDURE NUMBER APPRO ED DATE

<<12e10.3 06/21/83 VOLUME NAME 12 CHEMISTRY PROCEDURES SECTION 12.10 POST ACCIDENT SAMPLING AND ANALYSIS TITLE

+12. 10. 3 DETERMINATION OF CHLORIDES 12.10.3.1 P~uz oee This procedure describes a method of determining low level chloride con-centrations on post accident liquid sample diluted 1 ml to 10 ml final volume.

12.10.3. 2 Precautions/Prere uisites A. Analysis are to be performed when conditions are Al ARA.

B. Direct waste lines from the ion chromatograph to shielded con-tainer in a hood.

C. Dionex System 2 valves must be toggled to:

1. Separator 2
2. Suppressor 2 Eluent 2 D. Dionex System 2 flow rate should be approximately 3.0 mls/min.

E. HP 3390 Integrator Settings

1. Run'arameters setting Zero = 0 ATT2 = 8 Cht. SP = Oe5 Pk. WD. = 0.40 E'DR 830705015b 830b23 PDR ADOCK 05000397 WP.S97 Rl PROCEDURE NUMBER 12.10.3 REVISION NUMBER 0

+AGE NUMBER 12.10.3-1 of 4

8JJg Sf'~)g~

'l I

I V'hrsh = 7 Ar Rej = 0

2. Report Optns Settings RF UNC PKS = 0.0 E + 0 Mul Factor = Scale Setting from Dionex conductivity meter Pk Height Mode Yes Extend. RT RPRT UNC Pks Yes
3. Time TBL 20.00 STOP F. Appropriate dose rate meters must be present and calibrated. Survey all equipment for exposure rates continuously during analysis and sample handling.

12.10.3.3 R~ea enta (Prepare when required)

A. Eluent 2 0.0015 M NaHC03 Dissolve 0.5040 gms NaHC03 in one liter demineralized water then dilute to 4 liters. Label as per PPM 12.2.6.4.

B. Regeneration Solution 1N H2S04 to approximately 800 mls of demineralized water add slowly ill mls concentrated sulfuric acid.

Allow to cool to room temperature then dilute to 4 liters. Label as per PPM 12.2.6.4.

C. Chloride Standard - 10 ppb From a stock 1000 ppm standard dilute serially to 10 ppb. Label as per 12.2.6.4.

,12.10. 3. 4 E~ui ment A. Fast run anion separator column B. Anion suppressor C. 3cc or larger, disposable syringes D. Evacuated 14cc gas vial ROCKDUAK NUM8KA REVISION NUM8KA PAGE NUM8KA 12.10.3 0 12.10.3-2 of 4 W~98

e l2.10.3.5 Procedure A. Fill a disposable syringe with air and attach to the system 2 injection port.

B. Place the load/inject switch to load.

C. Inject air into the sample loop to remove any liquid from the sample line.

D. Place the sample needle into the 10 ppb chloride standard solution.

E. Using the syringe, draw the standard into the sample loop until liquid is seen entering the syringe.

F. Enter the conductivity scale setting into the integrator multiplica-tion factor. Push OP then 6, enter scale setting number, then press enter.

Simultaneously place the load/inject switch to inject and press the integrator start button. Place the load/inject switch to load after approximately 10 seconds.

After the chromatogram has run calibrate the integrator using the following steps:

Del Calib Calib ESTD Ref RTW RTW Cal 1 RT = (enter Cl retension time in minutes)

AMT = (enter Cl standard amount, 10 ppb)

ENTER With the load/inject switch in load, flush the sample loop with demineralized water.

Flush the sample loop with air.

K. Place the sample needle into the post accident sample.

L. Enter scale setting times 10 into the integrator multiplication factor. Push OP then 6, enter conductivity meter scale setting titles 10, then press enter.

PROCEDURE NUM8KR REVISION NUM8KR PAGE NUMBKR 12.10. 3 12.10.3-3 of 4 W~90  !

M. Draw sample into sample loop until liquid is detected entering into the syringe.

N. Sioultaneously switch load/inject switch to inject and press inte-grator start. Switch load/inject to load position after 10 seconds'. The integrator will report ppb Cl.

0. Remove syringe and dispose of as high level radioactive waste.

P. Carefuly remove the'yringe needle from the sample vial 'and insert into the 14 ml evacuated vial. Dispose of vial as high level radioactive waste after excess liquid has been drawn from the sample room.

PRQCEDURE NUMBER PREVISION NUMBER PAGE NUMBER 12.10. 3 0 12.10.3-4 of 4 W~98  !

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