ML18075A015

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Westinghouse Hematite Decommissioning Project - Final Status Survey Final Report Vol. 3, Chapter 21, Survey Area Release Record for Land Survey Area 08, Survey Units 09, 12 and 13, Rev. 1, J16732-2 Uds Level 2 Report Final Report
ML18075A015
Person / Time
Site: 07000036
Issue date: 04/25/2016
From:
TestAmerica Labs - St. Louis, Westinghouse
To:
Office of Nuclear Material Safety and Safeguards
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ML18074A285 List:
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HEM-18-6
Download: ML18075A015 (17)
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.

TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-16732-2 Client Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

For:

Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Mr. Martin Swanson Authorized for release by:

4/25/2016 4:57:39 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

TestAmerica Job ID: 160-16732-2 Page 2 of 17 Cover Page..............................................

1 Table of Contents.........................................

2 Case Narrative...........................................

3 Chain of Custody..........................................

5 Receipt Checklists.........................................

6 Definitions/Glossary.......................................

7 Method Summary.........................................

8 Sample Summary.........................................

9 Client Sample Results......................................

10 QC Sample Results........................................

15 QC Association Summary...................................

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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-16732-2 Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Job ID: 160-16732-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: HDP RFP-CBA-022 (7 DAY TAT)

Report Number: 160-16732-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %

solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT The samples were received on 3/31/2016 11:10 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperatures of the 2 coolers at receipt time were 1.5º C and 20.0º C.

RADIUM-226 BY GAMMA SPEC (21 DAY INGROWTH)

Samples L08-12-19-T-R-B-00 (160-16732-1), L08-12-20-T-R-B-00 (160-16732-2), L08-12-21-T-R-B-00 (160-16732-3),

L08-12-21-T-R-Q-00 (160-16732-4), L08-12-22-T-R-B-00 (160-16732-5), L08-12-23-T-R-B-00 (160-16732-6), L08-12-24-T-E-B-00 (160-16732-7), L08-12-25-T-E-B-00 (160-16732-8), L08-12-26-T-R-B-00 (160-16732-9) and L08-12-27-T-R-B-00 (160-16732-10) were analyzed for Radium-226 by gamma spec (21 day ingrowth) in accordance with EPA GA_01_R. The samples were leached on 03/31/2016, prepared on 04/01/2016 and analyzed on 04/22/2016.

Preparation Batch 160-243343:

The samples, analyzed by gamma spectroscopy, resulted in an RPD/RER (relative percent difference/replicate error ratio) outside of the acceptance criteria of 40%/1 for protactinium-231. Both the sample and sample duplicates activity are less than the MDC. The data have been qualified and reported. L08-12-19-T-R-B-00 (160-16732-1), L08-12-20-T-R-B-00 (160-16732-2), L08-12-21-T-R-B-00 (160-16732-3),

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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-16732-2 Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Job ID: 160-16732-2 (Continued)

Laboratory: TestAmerica St. Louis (Continued)

L08-12-21-T-R-Q-00 (160-16732-4), L08-12-22-T-R-B-00 (160-16732-5), L08-12-23-T-R-B-00 (160-16732-6), L08-12-24-T-E-B-00 (160-16732-7), L08-12-25-T-E-B-00 (160-16732-8), L08-12-26-T-R-B-00 (160-16732-9), L08-12-27-T-R-B-00 (160-16732-10), (LCS 160-243343/2-A), (MB 160-243343/1-A) and (160-16732-A-1-G DU)

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

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10 11 Procedure HDP-PR-QAt006, Chain of Custody Hematite Decommissioning Project !Revision: 4 I

I Page 1 ofll Westinghouse Non-ProJlrietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a per4 n from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly.identified before the sample is released for use or analysis and send the completed CoC to,P.

Chain of Cutody ID No. I F-032916-02 Page 1/1 Project Name:

Westinghouse Electric Company Contact Person:

Clark Evers Phone Number:

314-810-3336 SampJer Name Donte Love Sample ID

  • L08-12-19-T-R-B-OO L08-12-20-T-R-B-OO L08-12-21-T-R-B-OO L08-12-2 l-T-R-Q-OO L08-12-22-T-R-B-OO L08-I 2-23-T-R-B-OO L08-12-24-T-E-B-OO L08-12-25-T-E-B-OO L08-12-26-T-R-B-OO L08-12-27-T-R-B-OO Date 3/28/2016 3/28/2016 3/28/2016 3/28/2016 3/28/2016 3/28/2016 3/28/2016 3/28/2016 3/29/2016 3/29/2016 Relinquished by: G.,,.c.. "'IV-'\\.

Company Name:

~(..,

Received by:

Company Name:

dby
3 ~ l 5

~:~t\\.'

Time 16:00 16:05 16:10 16:10 16:15 16:20 16:30 16:35 16:25 16:30 Date/Time 3/=>! / 11..,

o4to Dateffime Matrix s

s s

s s

s s

s s

s C,Cj r C Laboratory Name:

TA-MO Laboratory Address:

13715 Rider Trail North

~ "~-------------------,

j ~f :-~~r~566 e Laboratory Contact Person:

~ Ivan Vania Phone No.

708-870-8453 Turn Aroun..d.Time Rush (7 days)

Remarks l ILSA 08-12 Bias LSA 08-12 Bias l ILSA 08-12 Bias 1 ILSA 08-12 Bias 1 ILSA 08-12 Bias l ILSA 08-12 Bias l ILSA 08-12 Bias l ILSA 08-12 Bias 160-16732 Chain of Custody 1 ILSA 08-12 Bias l ILSA 08~12 Bias Cooler Temperature:

Ambient Shipper and Number:

0329-01~ 0330-01 Date/Time I Comments: NI A VerifiedBy: ~

~

3/3, h(.,

Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-16732-2 Login Number: 16732 Question Answer Comment Creator: Dedner, Connie L List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.

True The cooler's custody seal, if present, is intact.

N/A Sample custody seals, if present, are intact.

True The cooler or samples do not appear to have been compromised or tampered with.

True Samples were received on ice.

True Cooler Temperature is acceptable.

True Cooler Temperature is recorded.

True COC is present.

True COC is filled out in ink and legible.

True COC is filled out with all pertinent information.

True Is the Field Sampler's name present on COC?

True There are no discrepancies between the containers received and the COC.

True Samples are received within Holding Time (excluding tests with immediate HTs)

True Sample containers have legible labels.

True Containers are not broken or leaking.

True Sample collection date/times are provided.

True Appropriate sample containers are used.

True Sample bottles are completely filled.

True Sample Preservation Verified.

True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is

<6mm (1/4").

True Multiphasic samples are not present.

True Samples do not require splitting or compositing.

N/A Residual Chlorine Checked.

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Definitions/Glossary TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Qualifiers Rad Qualifier Description U

Result is less than the sample detection limit.

Qualifier F

Duplicate RPD exceeds the control limit Glossary These commonly used abbreviations may or may not be present in this report.

Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation

%R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)

NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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Method Summary TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS)

TAL SL Protocol

References:

DOE = U.S. Department of Energy Laboratory

References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 17 1

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Sample Summary TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Lab Sample ID Client Sample ID Received Collected Matrix 160-16732-1 L08-12-19-T-R-B-00 Solid 03/28/16 16:00 03/31/16 11:10 160-16732-2 L08-12-20-T-R-B-00 Solid 03/28/16 16:05 03/31/16 11:10 160-16732-3 L08-12-21-T-R-B-00 Solid 03/28/16 16:10 03/31/16 11:10 160-16732-4 L08-12-21-T-R-Q-00 Solid 03/28/16 16:10 03/31/16 11:10 160-16732-5 L08-12-22-T-R-B-00 Solid 03/28/16 16:15 03/31/16 11:10 160-16732-6 L08-12-23-T-R-B-00 Solid 03/28/16 16:20 03/31/16 11:10 160-16732-7 L08-12-24-T-E-B-00 Solid 03/28/16 16:30 03/31/16 11:10 160-16732-8 L08-12-25-T-E-B-00 Solid 03/28/16 16:35 03/31/16 11:10 160-16732-9 L08-12-26-T-R-B-00 Solid 03/29/16 16:25 03/31/16 11:10 160-16732-10 L08-12-27-T-R-B-00 Solid 03/29/16 16:30 03/31/16 11:10 TestAmerica St. Louis Page 9 of 17 1

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Client Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-16732-1 Client Sample ID: L08-12-19-T-R-B-00 Matrix: Solid Date Collected: 03/28/16 16:00 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.18 (2+/-)

0.190 (2+/-)

1 04/22/16 08:47 04/01/16 14:08 pCi/g 0.103 RL MDC 0.147 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.374 0.425 0.404 1.27 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.0616 0.170 0.108 1.26 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.0626 0.163 0.0789 1.11 Lead 212 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.0751 0.172 0.0978 1.37 Lead 214 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.316 2.40 1.19 20.4 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 08:47 1

1.12 0.687 0.684 U

-0.648 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.0616 1.00 0.170 0.108 1.26 Radium 226 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.103 0.190 0.147 1.18 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.893 0.582 0.563 1.38 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.246 0.239 0.212 1.07 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 08:47 1

0.108 0.0649 0.0648 U

0.0331 Americium 241 pCi/g 04/01/16 14:08 04/22/16 08:47 1

5.22 3.27 3.20 6.68 Protactinium 234m Tl-208 0.391 0.0540 0.0675 0.0411 pCi/g 04/01/16 14:08 04/22/16 08:47 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

Lab Sample ID: 160-16732-2 Client Sample ID: L08-12-20-T-R-B-00 Matrix: Solid Date Collected: 03/28/16 16:05 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 0.581 (2+/-)

0.145 (2+/-)

1 04/22/16 08:37 04/01/16 14:08 pCi/g 0.380 RL MDC 0.132 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.646 0.459 0.447 0.978 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.0745 0.170 0.124 1.11 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.0911 0.166 0.101 1.01 Lead 212 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.0831 0.159 0.111 1.09 Lead 214 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.234 2.41 1.35 19.5 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.995 0.602 0.600 U

0.431 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.0745 1.00 0.170 0.124 1.11 Radium 226 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.380 0.145 0.132 0.581 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 08:37 1

1.28 1.47 0.985 10.4 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.354 0.566 0.378 4.15 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 08:37 1

0.144 0.0888 0.0880 U

0.108 Americium 241 pCi/g 04/01/16 14:08 04/22/16 08:37 1

3.44 5.18 4.84 18.3 Protactinium 234m Tl-208 0.351 0.0463 0.0589 0.0258 pCi/g 04/01/16 14:08 04/22/16 08:37 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

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Client Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-16732-3 Client Sample ID: L08-12-21-T-R-B-00 Matrix: Solid Date Collected: 03/28/16 16:10 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 0.452 (2+/-)

0.0766 (2+/-)

1 04/22/16 09:31 04/01/16 14:08 pCi/g 0.0448 RL MDC 0.0611 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.205 0.212 0.206 0.502 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.0310 0.103 0.0667 0.758 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.0382 0.0629 0.0416 0.365 Lead 212 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.0438 0.0994 0.0572 0.782 Lead 214 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.160 0.873 0.559 6.55 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.585 0.197 0.193 U

0.375 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.0310 1.00 0.103 0.0667 0.758 Radium 226 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.0448 0.0766 0.0611 0.452 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.593 0.541 0.438 3.03 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.149 0.175 0.146 0.962 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 09:31 1

0.0738 0.0437 0.0437 U

0.000149 Americium 241 pCi/g 04/01/16 14:08 04/22/16 09:31 1

2.82 1.74 1.72 U

2.75 Protactinium 234m Tl-208 0.140 0.0258 0.0296 0.0206 pCi/g 04/01/16 14:08 04/22/16 09:31 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

Lab Sample ID: 160-16732-4 Client Sample ID: L08-12-21-T-R-Q-00 Matrix: Solid Date Collected: 03/28/16 16:10 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 0.572 (2+/-)

0.132 (2+/-)

1 04/22/16 09:30 04/01/16 14:08 pCi/g 0.112 RL MDC 0.119 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.451 0.293 0.290 U

0.366 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.0593 0.129 0.0955 0.838 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.0602 0.0885 0.0626 0.483 Lead 212 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.0561 0.123 0.0784 0.909 Lead 214 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.208 1.19 0.832 8.30 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.711 0.422 0.421 U

0.224 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.0593 1.00 0.129 0.0955 0.838 Radium 226 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.112 0.132 0.119 0.572 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.745 0.626 0.539 3.05 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.204 0.209 0.182 1.01 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 09:30 1

0.0595 0.0364 0.0363 U

0.0315 Americium 241 pCi/g 04/01/16 14:08 04/22/16 09:30 1

3.01 3.74 3.61 9.47 Protactinium 234m Tl-208 0.180 0.0373 0.0417 0.0296 pCi/g 04/01/16 14:08 04/22/16 09:30 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

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Client Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-16732-5 Client Sample ID: L08-12-22-T-R-B-00 Matrix: Solid Date Collected: 03/28/16 16:15 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 0.903 (2+/-)

0.134 (2+/-)

1 04/22/16 10:13 04/01/16 14:08 pCi/g 0.0913 RL MDC 0.0967 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.319 0.417 0.389 1.45 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.0590 0.126 0.0879 0.874 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.0662 0.142 0.0766 0.923 Lead 212 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.0663 0.136 0.0841 1.03 Lead 214 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.159 1.93 0.924 16.6 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.582 0.353 0.351 U

0.256 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.0590 1.00 0.126 0.0879 0.874 Radium 226 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.0913 0.134 0.0967 0.903 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.876 0.887 0.775 4.14 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.215 0.208 0.189 0.857 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 10:13 1

0.106 0.0628 0.0628 U

0.000990 Americium 241 pCi/g 04/01/16 14:08 04/22/16 10:13 1

3.01 3.40 3.30 8.17 Protactinium 234m Tl-208 0.307 0.0472 0.0569 0.0366 pCi/g 04/01/16 14:08 04/22/16 10:13 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

Lab Sample ID: 160-16732-6 Client Sample ID: L08-12-23-T-R-B-00 Matrix: Solid Date Collected: 03/28/16 16:20 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.25 (2+/-)

0.169 (2+/-)

1 04/22/16 10:14 04/01/16 14:08 pCi/g 0.112 RL MDC 0.111 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.329 0.314 0.288 1.21 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0629 0.131 0.0898 0.918 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0588 0.182 0.0765 1.28 Lead 212 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0642 0.139 0.0872 1.04 Lead 214 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.356 2.13 1.03 18.2 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 10:14 1

1.16 0.714 0.710 U

-0.730 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0629 1.00 0.131 0.0898 0.918 Radium 226 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.112 0.169 0.111 1.25 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 10:14 1

1.21 1.42 1.07 8.95 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.263 0.515 0.277 4.27 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.134 0.0804 0.0804 U

-0.00340 Americium 241 pCi/g 04/01/16 14:08 04/22/16 10:14 1

3.94 4.78 4.54 14.8 Protactinium 234m Tl-208 0.394 0.0409 0.0579 0.0278 pCi/g 04/01/16 14:08 04/22/16 10:14 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

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Client Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-16732-7 Client Sample ID: L08-12-24-T-E-B-00 Matrix: Solid Date Collected: 03/28/16 16:30 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.11 (2+/-)

0.174 (2+/-)

1 04/22/16 10:14 04/01/16 14:08 pCi/g 0.121 RL MDC 0.133 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.438 0.511 0.490 1.42 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0729 0.172 0.114 1.26 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0880 0.172 0.0979 1.09 Lead 212 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0917 0.180 0.119 1.30 Lead 214 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.349 2.31 1.15 19.9 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 10:14 1

1.21 0.225 0.221 U

0.385 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.0729 1.00 0.172 0.114 1.26 Radium 226 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.121 0.174 0.133 1.11 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 10:14 1

1.18 0.870 0.778 3.72 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.392 0.979 0.338 9.01 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 10:14 1

0.144 0.0885 0.0878 U

0.109 Americium 241 pCi/g 04/01/16 14:08 04/22/16 10:14 1

3.86 4.32 4.21 9.61 Protactinium 234m Tl-208 0.367 0.0433 0.0574 0.0325 pCi/g 04/01/16 14:08 04/22/16 10:14 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

Lab Sample ID: 160-16732-8 Client Sample ID: L08-12-25-T-E-B-00 Matrix: Solid Date Collected: 03/28/16 16:35 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.01 (2+/-)

0.198 (2+/-)

1 04/22/16 10:16 04/01/16 14:08 pCi/g 0.193 RL MDC 0.169 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.541 0.577 0.559 1.39 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.111 0.196 0.156 1.13 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.0800 0.170 0.0943 1.09 Lead 212 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.0799 0.186 0.123 1.34 Lead 214 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.420 2.38 1.43 18.6 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 10:16 1

1.47 0.284 0.281 U

0.345 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.111 1.00 0.196 0.156 1.13 Radium 226 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.193 0.198 0.169 1.01 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 10:16 1

1.29 0.572 0.523 2.21 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.335 0.670 0.346 5.63 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 10:16 1

0.168 0.100 0.100 U

-0.00125 Americium 241 pCi/g 04/01/16 14:08 04/22/16 10:16 1

6.87 3.90 3.90 U

1.57 Protactinium 234m Tl-208 0.422 0.0620 0.0759 0.0435 pCi/g 04/01/16 14:08 04/22/16 10:16 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

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Client Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-16732-9 Client Sample ID: L08-12-26-T-R-B-00 Matrix: Solid Date Collected: 03/29/16 16:25 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 0.901 (2+/-)

0.140 (2+/-)

1 04/22/16 11:10 04/01/16 14:08 pCi/g 0.0748 RL MDC 0.106 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.415 0.307 0.295 0.799 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.0603 0.132 0.0884 0.941 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.0624 0.138 0.0719 0.915 Lead 212 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.0682 0.145 0.0926 1.07 Lead 214 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.403 2.34 1.10 20.2 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 11:10 1

1.00 0.614 0.611 U

-0.583 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.0603 1.00 0.132 0.0884 0.941 Radium 226 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.0748 0.140 0.106 0.901 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.776 0.318 0.294 1.16 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.170 0.139 0.137 0.247 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 11:10 1

0.0947 0.0572 0.0571 U

0.0337 Americium 241 pCi/g 04/01/16 14:08 04/22/16 11:10 1

4.11 2.50 2.49 U

2.25 Protactinium 234m Tl-208 0.311 0.0427 0.0535 0.0305 pCi/g 04/01/16 14:08 04/22/16 11:10 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

Lab Sample ID: 160-16732-10 Client Sample ID: L08-12-27-T-R-B-00 Matrix: Solid Date Collected: 03/29/16 16:30 Date Received: 03/31/16 11:10 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.15 (2+/-)

0.179 (2+/-)

1 04/22/16 11:12 04/01/16 14:08 pCi/g 0.114 RL MDC 0.136 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.499 0.534 0.520 1.20 Bismuth 212 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.0861 0.150 0.0976 1.11 Bismuth 214 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.0686 0.181 0.0830 1.24 Lead 212 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.0752 0.174 0.105 1.33 Lead 214 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.265 2.66 1.19 23.7 Potassium 40 pCi/g 04/01/16 14:08 04/22/16 11:12 1

1.22 0.370 0.362 U

0.676 Protactinium 231 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.0861 1.00 0.150 0.0976 1.11 Radium 226 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.114 0.179 0.136 1.15 Thorium 232 pCi/g 04/01/16 14:08 04/22/16 11:12 1

1.03 0.890 0.718 5.01 Thorium 234 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.247 0.326 0.238 2.18 Uranium 235 pCi/g 04/01/16 14:08 04/22/16 11:12 1

0.129 0.450 0.450 U

-0.0134 Americium 241 pCi/g 04/01/16 14:08 04/22/16 11:12 1

3.52 3.62 3.51 8.70 Protactinium 234m Tl-208 0.403 0.0519 0.0664 0.0405 pCi/g 04/01/16 14:08 04/22/16 11:12 1

(2+/-)

(2+/-)

MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.

Uncert.

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QC Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Client Sample ID: Method Blank Lab Sample ID: MB 160-243343/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 247453 Prep Batch: 243343 Actinium 228 Analyte U

1 04/22/16 08:10 04/01/16 14:08 pCi/g 0.0255 MDC RL 0.0133 0.0133 (2+/-)

(2+/-)

MB 0.007195 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.

Count Uncert.

Total 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.185 0.0941 0.0941 U

0.0001185 Bismuth 212 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0332 0.0163 0.0163 U

0.001417 Bismuth 214 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0207 0.0105 0.0105 U

0.001625 Lead 212 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0301 0.0150 0.0150 U

-0.001769 Lead 214 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.304 2.45 2.45 U

-0.08523 Potassium 40 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.293 0.161 0.160 U

0.03406 Protactinium 231 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0332 1.00 0.0163 0.0163 U

0.001417 Radium 226 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0255 0.0133 0.0133 U

0.007195 Thorium 232 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.272 0.0839 0.0838 U

0.03040 Thorium 234 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0595 0.0326 0.0325 U

0.01509 Uranium 235 1

04/22/16 08:10 04/01/16 14:08 pCi/g 0.0234 0.0132 0.0132 U

-0.002853 Americium 241 1

04/22/16 08:10 04/01/16 14:08 pCi/g 1.94 0.937 0.937 U

0.1765 Protactinium 234m Other Detected Radionuclide None MB (2+/-)

(2+/-)

MDC RL pCi/g 04/01/16 14:08 04/22/16 08:10 1

MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.

Count Uncert.

Total Radionuclides Other Detected Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-243343/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 247452 Prep Batch: 243343 Americium 241 Analyte 116 87 97 97.63 101 10.2 0.492 RL MDC (2+/-)

LCS LCS pCi/g Unit Result Qual

%Rec Added Spike Limits

%Rec.

Uncert.

Total Cesium 137 34.0 32.48 3.40 0.137 pCi/g 95 87 - 120 Cobalt 60 31.5 29.39 2.97 0.129 pCi/g 93 87 - 115 Client Sample ID: L08-12-19-T-R-B-00 Lab Sample ID: 160-16732-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 247452 Prep Batch: 243343 Actinium 228 Analyte 1

0.11 1.142 1.18 0.169 0.116 RL MDC (2+/-)

DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.

Total RER RER Bismuth 212 1.27 1.483 0.581 0.472 pCi/g 0.21 1

Bismuth 214 1.26 1.174 0.166 0.0734 pCi/g 0.25 1

Lead 212 1.11 1.138 0.167 0.0643 pCi/g 0.1 1

Lead 214 1.37 1.232 0.160 0.0708 pCi/g 0.40 1

Potassium 40 20.4 19.91 2.36 0.442 pCi/g 0.10 1

Protactinium 231

-0.648 U 0.4577 U F 0.223 1.17 pCi/g 1.21 1

Radium 226 1.26 1.174 0.166 1.00 0.0734 pCi/g 0.25 1

Thorium 232 1.18 1.142 0.169 0.116 pCi/g 0.11 1

Thorium 234 1.38 1.030 0.341 0.881 pCi/g 0.38 1

Uranium 235 1.07 0.9659 0.214 0.254 pCi/g 0.23 1

Americium 241 0.0331 U 0.01634 U 0.0697 0.117 pCi/g 0.12 1

TestAmerica St. Louis Page 15 of 17 1

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QC Sample Results TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)

Client Sample ID: L08-12-19-T-R-B-00 Lab Sample ID: 160-16732-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 247452 Prep Batch: 243343 Protactinium 234m Analyte 1

0.73 U

2.096 6.68 2.98 5.01 RL MDC (2+/-)

DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.

Total RER RER Tl-208 1

0.17 0.3689 0.391 0.0602 0.0356 RL MDC (2+/-)

DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.

RER RER Total Other Detected Radionuclides TestAmerica St. Louis Page 16 of 17 1

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QC Association Summary TestAmerica Job ID: 160-16732-2 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)

Rad Leach Batch: 243044 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-16732-1 L08-12-19-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-1 DU L08-12-19-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-2 L08-12-20-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-3 L08-12-21-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-4 L08-12-21-T-R-Q-00 Total/NA Solid Dry and Grind 160-16732-5 L08-12-22-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-6 L08-12-23-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-7 L08-12-24-T-E-B-00 Total/NA Solid Dry and Grind 160-16732-8 L08-12-25-T-E-B-00 Total/NA Solid Dry and Grind 160-16732-9 L08-12-26-T-R-B-00 Total/NA Solid Dry and Grind 160-16732-10 L08-12-27-T-R-B-00 Total/NA Prep Batch: 243343 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 243044 160-16732-1 L08-12-19-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-1 DU L08-12-19-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-2 L08-12-20-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-3 L08-12-21-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-4 L08-12-21-T-R-Q-00 Total/NA Solid Fill_Geo-21 243044 160-16732-5 L08-12-22-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-6 L08-12-23-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-7 L08-12-24-T-E-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-8 L08-12-25-T-E-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-9 L08-12-26-T-R-B-00 Total/NA Solid Fill_Geo-21 243044 160-16732-10 L08-12-27-T-R-B-00 Total/NA Solid Fill_Geo-21 LCS 160-243343/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-243343/1-A Method Blank Total/NA TestAmerica St. Louis Page 17 of 17 1

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