ML18074A221
| ML18074A221 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 02/24/2015 |
| From: | Barry Miller, Vania I Perma-Fix Environmental Services, Testamerica Labs, Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18074A285 | List: |
| References | |
| HEM-18-6 | |
| Download: ML18074A221 (16) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-10521-1 Client Project/Site: HDP For:
Perma-Fix Environmental Services Inc.
2800 Solway Road Knoxville, Tennessee 37931 Attn: Brian Miller Authorized for release by:
2/24/2015 5:01:12 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP TestAmerica Job ID: 160-10521-1 Page 2 of 16 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
12 QC Association Summary...................................
15 Tracer Carrier Summary....................................
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Case Narrative Client: Perma-Fix Environmental Services Inc.
TestAmerica Job ID: 160-10521-1 Project/Site: HDP Job ID: 160-10521-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Perma-Fix Environmental Services Inc.
Project: HDP Report Number: 160-10521-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 02/17/2015; the samples arrived in good condition, properly preserved and, where required, on ice. The temperature of the coolers at receipt was 18.0 C.
TECHNETIUM-99 (ICPMS)
Samples L10-12-13-B-E-B-00 (160-10521-1) and L10-12-14-B-E-B-00 (160-10521-2) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 02/17/2015 and analyzed on 02/19/2015.
Preparation Batch 174849:
Radium-226 is reported in these samples at the clients request. Radium-226 is reported from the 609.31 keV line of bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between radium-226 and bismuth-214 by the loss of radon-222 during sample preparation.
(160-10521-1 DU), (LCS 160-174849/2-A), (MB 160-174849/1-A), L10-12-13-B-E-B-00 (160-10521-1), L10-12-14-B-E-B-00 (160-10521-2)
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Case Narrative Client: Perma-Fix Environmental Services Inc.
TestAmerica Job ID: 160-10521-1 Project/Site: HDP Job ID: 160-10521-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
PERCENT SOLIDS Samples L10-12-13-B-E-B-00 (160-10521-1) and L10-12-14-B-E-B-00 (160-10521-2) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 02/18/2015.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L10-12-13-B-E-B-00 (160-10521-1) and L10-12-14-B-E-B-00 (160-10521-2) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were leached on 02/17/2015, and prepared and analyzed on 02/19/2015.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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10 11 12 TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 phone 314.298.8566 fax Client Contact Per.ma-Fix Environmental Services 2800 Solway Road Knoxville, TN 37931 (8_§_5) 690"0501 Phone (865) 539-9868 FAX Project Name: Hematite Decommissioming Project Site: Westinghouse Hematite, MO P0#832953 Sample Identification L 10-12-13-B-E-B-OO L 10-12°14-B-E-B-00 I~
Chain of Custody Record Test America THE LEADER !N ENVIRONMENT AL TESTlNG Regulatory Program: D ow D NPDES D RCRA 0 other:
TestAmerica Laboratories, Inc.
Project Manager: Brian Miller
!Site
Contact:
Ellen Jakob Date: 02/17/2015 COC No: 021715-FSS1 Tel/Fax: (314) 810-3333
!Lab
Contact:
Ivan Vanya
'Carrier: Courier
,Page 1 of 1 Analysis Turnamund Time Sampler.
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Sample Disposal (.A fee may be assessed if samples are retained longer than 1 :
Are any samples from a listed EPA Hazardous Waste? P lease List any EPA Waste Codes for the sample in the Comments Section if the lab is to dispose of 1f:te sample.
0 Non-Hazard D Flammable Oskin Irritant D Poison B D Unknown 0 Return to Client D rnsposa1 by lab 0 Archive fbr Months Special Instructions/QC Requirements & Comments: Potential for Radiological Contamination Custody Seals ~
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Login Sample Receipt Checklist Client: Perma-Fix Environmental Services Inc.
Job Number: 160-10521-1 Login Number: 10521 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
N/A The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
N/A Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
False Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Qualifiers Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 16 1
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Sample Summary TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID Client Sample ID Received Collected Matrix 160-10521-1 L10-12-13-B-E-B-00 Solid 02/13/15 15:30 02/17/15 10:00 160-10521-2 L10-12-14-B-E-B-00 Solid 02/13/15 15:00 02/17/15 10:00 TestAmerica St. Louis Page 9 of 16 1
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Client Sample Results TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-10521-1 Client Sample ID: L10-12-13-B-E-B-00 Matrix: Solid Date Collected: 02/13/15 15:30 Percent Solids: 69.5 Date Received: 02/17/15 10:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000076 0.000023 mg/Kg
02/17/15 14:20 02/19/15 21:03 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.375 (2+/-)
0.169 (2+/-)
1 02/19/15 21:03 02/17/15 14:20 pCi/g 0.261 1.53 RL MDC 0.166 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 02/17/15 14:20 02/19/15 21:03 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.19 (2+/-)
0.172 (2+/-)
1 02/19/15 20:05 02/19/15 16:57 pCi/g 0.127 RL MDC 0.122 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.113 0.0669 0.0669 U
0.00355 Americium 241 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.306 0.475 0.435 1.85 Bismuth 212 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0737 0.124 0.0950 0.773 Bismuth 214 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0625 0.182 0.0815 1.26 Lead 212 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0653 0.132 0.0854 0.963 Lead 214 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.263 2.16 1.16 17.9 Potassium 40 pCi/g 02/19/15 16:57 02/19/15 20:05 1
5.00 2.84 2.84 U
1.25 Protactinium 234m pCi/g 02/19/15 16:57 02/19/15 20:05 1
1.14 0.356 0.349 U
0.632 Protactinium 231 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0737 0.124 0.0950 0.773 Radium 226 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.866 0.669 0.645 1.72 Thorium 234 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.211 0.170 0.166 0.337 Uranium 235 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.127 0.172 0.122 1.19 Thorium 232 Tl-208 0.446 0.0499 0.0680 0.0303 pCi/g 02/19/15 16:57 02/19/15 20:05 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-10521-2 Client Sample ID: L10-12-14-B-E-B-00 Matrix: Solid Date Collected: 02/13/15 15:00 Percent Solids: 71.9 Date Received: 02/17/15 10:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000075 0.000023 mg/Kg
02/17/15 14:20 02/19/15 21:15 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0237 U
(2+/-)
0.0269 (2+/-)
1 02/19/15 21:15 02/17/15 14:20 pCi/g 0.257 1.50 RL MDC 0.0268 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 02/17/15 14:20 02/19/15 21:15 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 92 TestAmerica St. Louis Page 10 of 16 1
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Client Sample Results TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-10521-2 Client Sample ID: L10-12-14-B-E-B-00 Matrix: Solid Date Collected: 02/13/15 15:00 Date Received: 02/17/15 10:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.31 (2+/-)
0.185 (2+/-)
1 02/19/15 20:05 02/19/15 16:57 pCi/g 0.104 RL MDC 0.128 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0757 0.0531 0.0529 U
0.0453 Americium 241 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.365 0.467 0.428 1.81 Bismuth 212 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0591 0.121 0.0895 0.789 Bismuth 214 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0918 0.196 0.105 1.28 Lead 212 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0663 0.123 0.0868 0.834 Lead 214 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.322 1.99 1.07 16.3 Potassium 40 pCi/g 02/19/15 16:57 02/19/15 20:05 1
4.73 2.79 2.78 U
1.69 Protactinium 234m pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.647 0.384 0.383 U
0.211 Protactinium 231 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.0591 0.121 0.0895 0.789 Radium 226 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.875 0.558 0.546 1.07 Thorium 234 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.254 0.146 0.145 U
0.113 Uranium 235 pCi/g 02/19/15 16:57 02/19/15 20:05 1
0.104 0.185 0.128 1.31 Thorium 232 Tl-208 0.435 0.0575 0.0731 0.0431 pCi/g 02/19/15 16:57 02/19/15 20:05 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-174463/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 174922 Prep Batch: 174463 RL MDL Technetium 99 ND 0.000057 0.000017 mg/Kg 02/17/15 14:20 02/19/15 20:56 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-174463/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 174922 Prep Batch: 174463 Technetium 99 0.00123 0.00113 mg/Kg 92 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: L10-12-13-B-E-B-00 Lab Sample ID: 160-10521-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 174922 Prep Batch: 174463 Technetium 99 ND 0.00178 0.00171 mg/Kg 96 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: L10-12-13-B-E-B-00 Lab Sample ID: 160-10521-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 174922 Prep Batch: 174463 Technetium 99 ND 0.00176 0.00166 mg/Kg 95 75 - 125 3
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-174463/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 174923 Prep Batch: 174463 Technetium 99 Analyte U
1 02/19/15 20:56 02/17/15 14:20 pCi/g 0.196 MDC 1.15 RL 0.00694 0.00686 (2+/-)
(2+/-)
MB 0.01117 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 02/17/15 14:20 02/19/15 20:56 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 87 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-174463/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 174923 Prep Batch: 174463 Technetium 99 Analyte 120 80 92 19.27 21.0 1.82 1.10 0.188 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 91 LCS TestAmerica St. Louis Page 12 of 16 1
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QC Sample Results TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: L10-12-13-B-E-B-00 Lab Sample ID: 160-10521-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 174923 Prep Batch: 174463 Technetium 99 Analyte 125 75 95 29.20 30.4 0.375 2.81 1.53 0.262 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 94 MS Client Sample ID: L10-12-13-B-E-B-00 Lab Sample ID: 160-10521-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 174923 Prep Batch: 174463 Technetium 99 Analyte 1
0.14 125 75 93 28.44 30.1 0.375 2.64 1.53 0.261 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 94 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-174849/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 174816 Prep Batch: 174849 Actinium 228 Analyte U
1 02/19/15 20:03 02/19/15 16:57 pCi/g 0.0322 MDC RL 0.0159 0.0159 (2+/-)
(2+/-)
MB 0.006571 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0174 0.00996 0.00995 U
0.004707 Americium 241 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.208 0.0390 0.0390 U
0.0000 Bismuth 212 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0438 0.0367 0.0367 U
-0.004837 Bismuth 214 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0261 0.671 0.671 U
-0.01069 Lead 212 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0295 0.0178 0.0178 U
0.01304 Lead 214 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.213 2.70 2.70 U
-0.06756 Potassium 40 1
02/19/15 20:03 02/19/15 16:57 pCi/g 2.89 0.880 0.880 U
0.3176 Protactinium 234m 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.305 0.174 0.174 U
0.07982 Protactinium 231 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0438 0.0367 0.0367 U
-0.004837 Radium 226 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.218 0.129 0.129 U
0.1050 Thorium 234 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0660 0.0362 0.0362 U
-0.004137 Uranium 235 1
02/19/15 20:03 02/19/15 16:57 pCi/g 0.0322 0.0159 0.0159 U
0.006571 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 02/19/15 16:57 02/19/15 20:03 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 13 of 16 1
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QC Sample Results TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-174849/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 174819 Prep Batch: 174849 Americium 241 Analyte 116 87 99 100.3 101 10.4 0.527 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 35.0 34.33 3.59 0.200 0.163 pCi/g 98 87 - 120 Cobalt 60 36.7 35.47 3.58 0.109 pCi/g 97 87 - 115 Client Sample ID: L10-12-13-B-E-B-00 Lab Sample ID: 160-10521-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 174816 Prep Batch: 174849 Actinium 228 Analyte 1
0.29 1.302 1.19 0.213 0.142 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241 0.00355 U
-0.01732 U
0.0621 0.104 pCi/g 0.16 1
Bismuth 212 1.85 1.933 0.583 0.446 pCi/g 0.08 1
Bismuth 214 0.773 0.9379 0.150 0.0778 pCi/g 0.60 1
Lead 212 1.26 1.297 0.190 0.0697 pCi/g 0.10 1
Lead 214 0.963 0.8962 0.132 0.0764 pCi/g 0.26 1
Potassium 40 17.9 16.32 2.09 0.278 pCi/g 0.37 1
Protactinium 234m 1.25 U
1.858 U
3.81 6.50 pCi/g 0.09 1
Protactinium 231 0.632 U
0.2665 U
0.236 1.36 pCi/g 0.62 1
Radium 226 0.773 0.9379 0.150 0.0778 pCi/g 0.60 1
Thorium 234 1.72 2.073 0.651 0.923 pCi/g 0.27 1
Uranium 235 0.337 0.1763 U
0.140 0.258 pCi/g 0.52 1
Thorium 232 1.19 1.302 0.213 0.142 pCi/g 0.29 1
Tl-208 1
0.03 0.4407 0.446 0.0761 0.0453 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
RER RER Total Other Detected Radionuclides TestAmerica St. Louis Page 14 of 16 1
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QC Association Summary TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Metals Prep Batch: 174463 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-10521-1 L10-12-13-B-E-B-00 Total/NA Solid None 160-10521-1 MS L10-12-13-B-E-B-00 Total/NA Solid None 160-10521-1 MSD L10-12-13-B-E-B-00 Total/NA Solid None 160-10521-2 L10-12-14-B-E-B-00 Total/NA Solid None LCS 160-174463/2-A Lab Control Sample Total/NA Solid None MB 160-174463/1-A Method Blank Total/NA Analysis Batch: 174922 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 174463 160-10521-1 L10-12-13-B-E-B-00 Total/NA Solid 6020A 174463 160-10521-1 MS L10-12-13-B-E-B-00 Total/NA Solid 6020A 174463 160-10521-1 MSD L10-12-13-B-E-B-00 Total/NA Solid 6020A 174463 160-10521-2 L10-12-14-B-E-B-00 Total/NA Solid 6020A 174463 LCS 160-174463/2-A Lab Control Sample Total/NA Solid 6020A 174463 MB 160-174463/1-A Method Blank Total/NA General Chemistry Analysis Batch: 174524 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-10521-1 L10-12-13-B-E-B-00 Total/NA Solid Moisture 160-10521-1 DU L10-12-13-B-E-B-00 Total/NA Solid Moisture 160-10521-2 L10-12-14-B-E-B-00 Total/NA Rad Prep Batch: 174463 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-10521-1 L10-12-13-B-E-B-00 Total/NA Solid None 160-10521-1 MS L10-12-13-B-E-B-00 Total/NA Solid None 160-10521-1 MSD L10-12-13-B-E-B-00 Total/NA Solid None 160-10521-2 L10-12-14-B-E-B-00 Total/NA Solid None LCS 160-174463/2-A Lab Control Sample Total/NA Solid None MB 160-174463/1-A Method Blank Total/NA Leach Batch: 174481 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-10521-1 L10-12-13-B-E-B-00 Total/NA Solid Dry and Grind 160-10521-1 DU L10-12-13-B-E-B-00 Total/NA Solid Dry and Grind 160-10521-2 L10-12-14-B-E-B-00 Total/NA Prep Batch: 174849 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 174481 160-10521-1 L10-12-13-B-E-B-00 Total/NA Solid Fill_Geo-0 174481 160-10521-1 DU L10-12-13-B-E-B-00 Total/NA Solid Fill_Geo-0 174481 160-10521-2 L10-12-14-B-E-B-00 Total/NA Solid Fill_Geo-0 LCS 160-174849/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-174849/1-A Method Blank Total/NA TestAmerica St. Louis Page 15 of 16 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-10521-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 94 160-10521-1 Percent Yield (Acceptance Limits)
L10-12-13-B-E-B-00 94 160-10521-1 MS L10-12-13-B-E-B-00 94 160-10521-1 MSD L10-12-13-B-E-B-00 92 160-10521-2 L10-12-14-B-E-B-00 91 LCS 160-174463/2-A Lab Control Sample 87 MB 160-174463/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 16 of 16 1
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