ML17277A938
| ML17277A938 | |
| Person / Time | |
|---|---|
| Site: | Columbia  |
| Issue date: | 09/27/1983 |
| From: | WASHINGTON PUBLIC POWER SUPPLY SYSTEM |
| To: | |
| Shared Package | |
| ML17277A937 | List: |
| References | |
| 12.10.8, NUDOCS 8310180453 | |
| Download: ML17277A938 (24) | |
Text
I I
p<
pl/ I
~\\
PROCKOURE NUMBKR
+12.10.8 VOLUME 4AME 12 SECTION 12.10 TITI E
+12.10.8 WASHINGTON PUBLIC POWER SUPPLY SYSTFDI P{.AITPR()(:EI)l RES 'I:DL:EL CONTRQILILEE)
OATE 09/27/83
'A" CHEMISTRY FROCEDURES POST ACCIDENT SAMPLING AM3 ANALYSIS DISSOLVED GAS ANALYSIS 12.10.8.1
~Pur oee This procedure gives instructions for sampling and analysis of dissolved gas from the post accident sampling station.
12.10.8.2 Precautions/Prereauisites A.
Lab personnel shall be issued extremity monitoring devices per Health Physics policy.
Lead shielding must be set up prior to removing the sample from the cask.
C.
Appropriate dose rate meter must be available and in calibration.
Use continuously to assure personnel exposure is ALARA.
D.
TIhe gamma spectrometer must be operable.
Appropriate remote handling tools must be available and used during handling of highly radioactive samples.
- 12. 10. 8. 3 Ecruioment A.
14 ml gas-sample bottle S.
Gas sample bottle holder C.
Stopwatch 83i0180453 83iOi3 PDR ADOCK 050003'2I7 A
'/I/+ 597 R'ROCKOURE NUMBER
)REVISION NUMBER 2.10. 8 1
0 O'AG K NUMBER 12.10.8-1 or 19
J l t
k ~ wg'g"$
b
~~ q""> ~'. >
~'
12.10.8. 4 Procedure A.
Identification of Symbols.
The following section identifies the symbols which are used in the procedure:
G = total dissolved gas:in gas
- phase, gm-mol L = total dissolved gas in liquid phase, cm-mol PF = final pressure of gas, psia PG = partial pressure of total dissolved
- gas, psia Pi = initial pressure of gas, psia PRG = partial pressure of residual expanded gases from liquid loop, psia PV = pressure of water vapor at temperature of liquid, psia (psia) (cc)
SH = solubility of hydrogen at temperature of liquid sample, gm-mol Hz/gm-mol H20 TG = temperature of gas collection volume, oR (oR = 460 + oF)
TL = temperature of liquid sample, oR (oR = 460 + oF)
VG = volume of gas collection area, cc VL = volume of liquid in liquid collection cylinder, cc p = density of water at temperature of liquid sample, g/cc B.
Oeterminin Standard Parameters Prior to using the dissolved oas sampling system for collecting
- samples, the volume of the gas and liquid must be determined.
(See Attachment A.)
'fVP 59$
PRQCKOURK NUM8KR RKVISIONNUMBKR 12.10.8 PAQK NUMKKP 12.10.8-2 of 19
J l
C.
Dbtaininq Total Dissolved Gas Measurements 1.
Turn "Liq/Gas" switch to liquid.
2.
turn "Liq Sample Source Selector" switch to RI-R on bypass or Jet Punp on bypass.
3.
Turn PCV-627 to control flow to approximately 1
gpm or less as displayed cn FI-664.
4.
Turn RI iq Sample Source Selector" switch to RFR or Jet Pump.
5.
Use gas sample bottle holder tool to place a gas sample bottle on the needle.
Check to see that the green light below "Gas Bottle In" is on.
6.
Turn "Dissolved Gas and Liquid Sample" switch to Position 1 for 10 minutes.
Reduce flow rate to 0.1 gpm to minimize pressure drop.
7.
Turn "Dissolved Gas and Liquid Sample" switch to Position 2 for 10 minutes.
8.
Turn to Position 3.
When PI662 is stable, record value as Pi on Data Sheet 1.
9.
Turn quickly to Position 6 for 30 seconds.
10.
Turn to Position 7 for 30 seconds.
ll.
Turn to Position 8 for 15 seconds; turn back to Position 7 for seconds; repeat 3 times.
12.
Turn to Position 9.
Record final pressure as PF (from PI-662) on Data Sheet 1.
13.
Turn "Lower Pressure/Gas Sample" switch to "lower pressure".
14.
Record water temperature from TI-660 and gas temperature frcm TI-724.
D.
Remove trapped water in dissolved gas collection volume.
NOTE:
After a dissolved gas test is performed, liquid is assumed to be trapped in the gas collection volume.
When the valve CV653 opens small gas bubbles come out of solution throughout the liquid phase.
As the bubbles expand and rise, entrained water is carried with them into the gas collection space.
Valve CV 653 is a solenoid valve with small parts and a tortuous flow path, and therefore water can-not drain back.
Assemble apparatus in Figure l.
'IVP 59$
PROCEDURE NUMBER
]REVISION NUMBER
[PAGE NUMBER 12.10.8 0
12.10.8-3 of 19
H ITROGF ti SUPPLY TRfIK Note 1
z 3
5 6
7 8
tarot all Fittings are shovn in this illustration shutoff valve for the tank pressure gage for the tank second stage pressul e gage second stage pressure regulator valve shutof f valve metering valve (control valve) pressure gage (range; 0 to 50 PSIG)
Swagelok 8 inch. union,:;ith outer end fitted with a septum 4 inch. tubing FIGURE '..
APPARATUS FOR GRS COLLECTIOtl CHÃlPFR MATER DRRIlfAGE F1cure 1
'AP 594 PROC-QVRE HVAn8KR R
VIS>ON hUMBc.rl 12.10. 8 i~4Qf 'IVu86P I
12.10.8-4 or '.'
~
~
t 1.
If the last dissolved gas test had a final pressure greater than atmospheric, depressurize the liquid lines as follows; ir not go to 2.
a.
Turn "Liquid Sample Source Selector" switch to Jet Pump (2) on RHR (4).
b.
Turn "Liq/Gas" switch to liquid.
c.
Turn "Dissolved Gas and Liquid Sample" switch to Position 8.
d.
e.
Turn power switch ON.
I TurnI "Dissolved Gas and Liquid Sample" switch to Position 9.
f.
Turn "Lower Press/Gas Sample" switch to lower pressure.
g.
Repeat from c until PI 662 reads atmospheric at Step C.
2.
Turn- "Liquid Sample Source Selector" switch to Jet Pump or RHR.
3.Turn "Liquid/Gas" switch to liquid.
Turn "Dissolved Gas and Liquid Sample" switch to Position 9.
5.
Place septum end of tube on dissolved gas sample needle.
Be sure that green light below "gas bottle in" is on.
Set 2nd stage of 2 stage regulator for 45 psig.
6.
Turn "lower press/gas samples" switch to gas sample.
Have a second person turn on the small control valve on the nitrogen supply.
Release gas sample switch when pressure, as indicated on PI-662, is approximately 50 psia.
7.
Turn power switch OFF.
8.
Turn "dissolved gas and liquid sample" switch to Position 6.
9.
Turn power switch ON.
10.
Nhen pressure is reduced, water should be forced into liquid space.
11.
Complete Data Sheet l.
WP 594 PROCEDURE NUMBER REVISIdN i'%UMBER 12.10.8 0
12 10 8 5 of 19
E.
To Calculate Dissolved Gas Concentrations 1.
The following values must be obtained prior to calculating gas concentrations:
VL = volume of liquid sample (cc) from 12.10.8.4.B VG = volume of gas collection area (cc) from 12.10.8.4.B TG = temperature of gas collection volume (oR) from 12.10.8.4.C TL = temperature of liquid sample (oR) from 12.10.8.4.C PF
= final pressure of gas (psia) from 12.10.8.4.C Pi = initial pressure of gas (psia) from 12.10.8.4.C SH = solubility of H2 at temperature of liquid sample (gm-mol/gm H20-atm)
(see Attachment B) p = density of water at temperature of liquid sample (gm/ml)
(see Attachment D)
PV = pressure of water vapor at temperature of liquid (psia)
(see Attachment C)
= partial pressure gases from liquid loop, (psia) from 12.10.8.4. B 2.
Determination of partial pressure of total dissolved
- gas, PG PG
Determination of'issolved gas concentration in the iquid.
Total dissolved gas
=.Gas in liquid phase
+ gas "in gas phase (gm-mols )
(gmmols)
L = SH x VL x P x PG/14.4 for liquid phase G
=, PG x VG/(RX TG) for gas phase Total dissolved gas per cc water = L + g vt WP 594 PRQCEQVRE NUMBER 12.10.8 REVISION NVMBER PAGE NUMBER 12w10.8-6 of 19
12.10.8.5 Attachments A.
Volume Determination B.
Solubility of Gases C.
Vapor Pressure of Hater D.'ensity of Mercury and 'Hater E.
Data Sheets 1,
2 and 3
WP 598 PRQCKbURE NUM8fR
)RKVISlON NUM8ER 12.10.8 I
0 Pa@a NUM88P 12.10.8-7 of 19
TENTATIVE VOLUME OETERMINATION PROCEOURE FOR THE PASS SYSTEM DISSOLVED GAS SAMPLING CHAMBERS The purpose for the procedure is to determine the volumes of the dissolved gas collection chamber
{expansion volume) and the liquid circulation chamber (liquid sample volume).
The principle of the method is based on gas expansions and pressure measure-ments performed against a known standard reference volume.
The pressure read-ings are taken at ambient, conditions in quick succession and the simple gas law pressure-volume relationship is applied without temperature corrections.
The procedure is meant to be applied to PASS Systems that have not been put into operation, i.e. dry, without any liquid in the lines.
Attachment A
Page 1 of 6 WP 55d PROCEDURE NUMBER 12.1 REVISION NUMBER PAGE NUMBER 19 1
n 1
PASS SYSi=M VQLUME ET==MiNAT~0N
.-RGC" URE
( T~W7'-.T:VE)
EwU'5FME'iT R
rence Volund Cacsule, 5 - 20 c" nominal (sketch).
Vacuum Porno Vacuum Gage flexible Vacuum arose
('6 I t.)
- -nut-oi f Valve o
Rucoer Seotums
- SKETC."i - Pyrex G'ass Capsule Rufbe Seotum Valve (Tef'on Pluo)
Attachment A
Page 2 of 6 WP 598 paQQKCURK numaKR
- 12. 10. 8 RKVISIQPV i t&iVIOER 0
(PAGE NUA46FR I 12.10.8-9 of 19
1.
Standard Reference Volume (V )
1.2 1.3 Weigh reference capsule to the nearest 0.1 gram.
With valve closed, fillthe reference capsule with distilled wat r thru the septum port.
Seal the port of the capsule with a rubber septum allowing some of the water to overflow.
Remove the excess water with tissue or oaper towels.
1.4 1.6 Weigh reference capsule and its content of water to the nearest 1
gram.
Record difference on Data Sheet 2.
Note ambient temperature and from Attachment B obtain the density of water in grams per cubic centimeter at the temperature not d.
Re-cord ambient temperature and density on Data Sheet l.
Calculate the volume of the reference capsule (Vs) as follows:
(Record on Data Sheet 1) 1.7 1.8 Vs=
~W P
Where:
LW = weight difference between the empty capsule and the capsule fil-led with water (grams)
P = density of water (gram/cc)
Vs = standard reference volume (cc)
Drain and thoroughly dry the reference capsule.
Reseal the capsule with a new rubber septum.
2.
Determination of the Dissolved Gas Collection Chamber Volume, V-622 (f'ASS
~Ss ten 2.1 2.2 2.3 On the PASS system control panel set switches as follows:
Mode Selector Switch to "LlgJIO" Sequencing Switch HC-601 to Position 10 Evacuate the standard reference capsule thru its valve to 50 microns or better.
Record pressure as Po on Data Sheet 1.
insert an open vial (without rubber septum) into the dissolved gas sampling station such that the limit switch near the needle is depressed and the "Vial Position" status light on the panel changes from red to green.
Attachment A
Page 3 of 6 WP 398 I ROCEDURE NUMBER REVISION NUMBER 12.10.8 0
RAGE NUMBER 12.10.8-10 of 19
2.4 Turn switch HC-652 clockwise to "Gas Sample" and hold.
2.5 Record pressure from PI-662 as Pl (should be atmospheric) on Data Sheet 1.
2.6 Release switch HC-652, then remove open vial from the samoling station.
2.7 Close the valve on the standard reference capsule to isolate it from the vacua pvnp.
2.8 Inser the standard reference capsule into the dissolved gas sampling station such that the needle punctures the rubber septum and the limit switch is depressed.
Note the status light changing from red to green.
2.9 Turn switch HC-652 clockwise to "Gas Sample" and hold.
2.10 Record pressure from PI-662 as P2 on Data Sheet 1.
2.11 Calculate VT as follows:
(Record on Data Sheet 1) p - p V
=
2 0
V T
P P
S 1
2 Where:
VS = standard reference capsule volume (cc)
VT = volume of dissolved gas collection chamber
+ the vol-ume of tubing, needle block and needle (cc) 2.12 Install a new rubber septum on the standard reference capsule.
2.13 Repeat Steps 2.2 through 2.12 three or more times and then calculate an average value for VT.
2.14 Insert an open vial (no rubber septum) into the dissolved gas samp-ling station.
Note that the limit is depressed and the "Vial Po i-tion" status light changes from red to green.
2.15 Turn switch HC-652 clockwise to "Gas Sample" and hold.
2.16 Record pressure from PI-662 as P3 (should be atmospheric) on Data Sheet l.
2.17 Release switch HC-652, then remove the open vial from the dissolved gas sampling station.
2.18 Insert the standard reference capsule into the dissolved gas samp-ling station as was done in Step 2.8.
Attachment A
Page 4 of 6 PROCEDURE NUMBER REVISION NUMBER PAGE NUMBER
'IHIP 598
- 12. 10. 8 0
12.10.8-11 of 1
2.19 Connect the valved end of the reference caosule to the vacuum
- oump, open the valve and evacuate to 50 microns or better, then close the valve.
Record pressure as Po on Data Sheet l.
2.20 Turn switch HC-652 clockwise to "Gas Sample" and hold.
2.21 Record pressure frcm PI-662 as P4.
2.22 Calculate VG as follows:
(and record on Data Sheet 1) p p
V =(V+V) 4 0
G T
S P - P 3
0
'Hhere:
VT = the average value obtained from Step 2.12 (cc)
VS = standard reference capsule volume (cc)
VG = dissolved gas collection chamber
- volume, V-662 (cc) 2.23 Install a new rubber septum on the standard reference capsule.
2.24 Repeat Steps 2.14 through 2.23 three or more times and then calcu-late an average value VG (V-662).
I 3.
Determination of the Li uid Circulation Chamber Volume V-610 3.1 Disconnect sample source lines (BET PUMP, Rf%, etc.)
from the PASS System.
3.2 On the control panel set switches as follows:
Mode Selector Switch to "LIQJID" Sequencing Switch HC-601 to Position 10 Liquid Sample Source Selector Switch HC-626 to Position 2
3.3 Insert an open vial (without rubber septum) into the dissolved gas sampling station.
Make sure the limit switch near the needle is depressed and green indicator light is on.
3.4 Turn switch HC-652 clockwise to "Gas Sample" and hold.
3.5 Record pressure from PI-662 as Pl (atmospheric pressure) on Data Sheet 3.
3.6 Release switch H-652, then remove the open vial from the sampling station.
Attachment A
Page 5 of 6 VIP 598 PROCKOURK NUM8KR RKVISIQN NUMBKR
[PACK NUMBKR 12.10.8 0
12.10.8-12 of 19
3.7 Insert a vial with rubber septum into the dissolved gas sampling station.
Note that the needle punctures the septum and that the vial is inserted far enough to depress the limit switch.
"Vial Position" status light on the panel should change from red to green.
3.8 Turn sequencing switch HC-601 from Position 10, quickly thru Posi-ticn ll to OFF.
3.9 Turn sequencing switch HC-601 to Position 2.
Observe that P-701 starts and the pressure reading on Pl-662 decreases.
3.10 Allow the pressure reading from PI-662 to stabilize then record the pressure as P2 (partial vacuum) on Data Sheet 3.
3.11 Turn sequencing switch HC-601 from Position 2 very quickly thru Positions 3, 4, 5 and 6 to Position 7.
3.12 Record pressure from PI-662 as P3 on Data Sheet 3.
3.13 Calculate VL as follows:
(on Data Sheet 3)
P
- P V
=
3 2.V L
P
- P G
1 3
Where:
VG = average value for the dissolved gas collection chamber volume (V-662) obtained previously (cc)
VL = liquid circulation loop volume, V-610 (cc) 3.14 Turn sequencing switch HC-601 to Position 10 and remove the vial with rubber septum from the dissolved gas sampling station.
3.15 Repeat Steps 3.
through 3.14 three or more times and then calculate an average value VL (V-610).
Attachment A
Page 6 of 6 WP 598 PROCEDURE NUMBER REVISION NUMBER 12.10.8 0
PACE NUMBER 12.10.8-13 of 19
~ ~
Table 10-1 Table 10- l I Cunfinu~(i)
~i)LLBlLITYI)F I'ASKS j.'i WATCR v(((((.i CARBON OIG.JDEif CABBOib SIONOXTDFI CHLORro.
~o... UTE ij
=. siYLB'.IL
<<YDP 0<v =. ~
rr I
I i
I I
I 7
5 9
- 4 ri
~ 4
- 8:7
~ 3 I
!9 20
~ a n3
(
rr5 i
5 7
2$
9 3$
~
I 60 70
~o l
- O)
I I.r <<3 I. 346
~
~ $4
- 1. 327
!.+73 I, 424 32 0.)346 3.3213 0.3091 029 8
J.ZSTt n
J.oesf
).2539 J.
492 r.'.94
- 1. !17
- .033 n'rf 5 Q
<<). 09$
- 1. )19
- 3. 985 0.)5$
O.sis 0.902 0.87S
- 0. $54 0.$ 29 O'.304 0..31 3.759 o'.-.
a 0.
~ 1$
- 0. 599 Oi 682
- 0. 3$5 O. 592 Q. 530
- 0. 479 0.438 0.19. 0 0.:903 0
').'.739 Q.1737 0.16$ $
Q.:540 O.r 90
- 0. 1540
).1493
- 0. I449
- 0. 1406 J.!.5$
0.13"7 0.1292
- 0. t 257
- 0. 1105 0.0973 Q.ceoo 0, 07dl
- 0. 359
- 0. 0578 Q.v3537 0.03455
'). 3375
~ (
Q.; 3207
/(
J n3 lrvr
!I
- 0. v3 ~ 49 0 "o073
- 0. 0"')42 j
0 3 ~ 3 i).'231$
>>).rro. 37 Q.J
. Jl I
Q. 02543
- 0. in24 94
.'.02446 0.024)3 0.02350 0.023'l9 0.02"35 Q.v2244 0 Qrrrrn 5 0.02174 0.02142 0.0 'Ifo 0.
2CSO 0.02051 0.02024 0.01998 O.Clare 0.01SQO 0.01515 J. Qt 488 Q,of 444 0.01434 Or 014'2
- 0. 0141 i.'rr 0.004Z93 O.JG4(91
(
0.004092 0.003998 O.CC3903 0.002313 r
Q.v03725 i
0.003640 0.003559 r
O.C03479 0.003405 rt O. r!033 32 Q.)03255 0.003'I94 0,003'(30 0.003C6$
0.003007 0.002947 O.COZSQI 0.002338 0.0027S9 O.C02.39 0.00259t 4 ~ 002848
- 0. CC2803
- 0. G025f 0 000 559 j
- 0. 002479 Q.O)2442 0.002405 Q.C02231 4 ~ CCZQTS 0.001933 O.C01797 i
0 001522 I
0.005275 Q.JCGQSO 0.00057 4.00000
- 3. r4'f
- 3. 047 2.95O "38
- 2. 787 2.680
~ Q7 2.357 n, 444
- 2. 3S8 n99'.1 to Irr3
- 2. CTO
- n. 019 1.970 1.923 1.5$ 0 1.339 1..99
- 1. 602
- 1. 43S 1.3 2
- 1. 225 0.9972 0.9654
). 934$
Q. 9050 o'J. Sa 0.8495 0.3232 0.7)79 O.ir 3
0.75(0 0.
~ Z93 Q.TICO 0.691S 0.5733
(
0,$ 572 I
0.5413 I
0.5259 I
0.6112 I
0.$ 975:
0 5847 I
4.57 3
- 0. SIC4
- 0. 4590 Q
4 lrra
- 0. 3925 I. 023
- 0. 3295 0.$ 52 4.2793 4.6S3 0.2227 Q. 39
- 0. 127 Q. Co
- 0. QO4 0,(.)674 0.09476 Q.29093 O.C8725 0.'083-'2 0.08033
).077)9 OrQT400
'J.QTI"5 3.0632$
- 0. 08551 0.3532$
0.0310$
0.05S94 0.05694
). 05504
). 05325 Q. 051 &
0.05003 3.04858 0.04559 0.04459 0.04335 0 04217
- 0. 041 C4
- 0. 03997
- 0. 03895 0.03799 0.03709 0.03524 0.03234 0.029!5 0.02664 0.02459
- 0. C2177i 0.01948 0.0182d Q,JITd 0.0172 a
).QIJI r
).01253 I
O.ot2!2
(
Q.'J(152; Q.31114 r
(
Q.CIC89 0.01025 j
Q.v09$ 3
(
O.00943; O.C0906 n.00870 9.'00$ 3a,:
O.CCSCS
- ).C07$ 0 !
0 "0753
'.CCTrZT
(
0.00703 I
Q.r'0680
(
rJ.CCS59
'.'00639i 0.008"0 i
O.00802 r
O.G05$ 4 Q.CQSo7
- 0. COSSI O.C0535 0.')0520 Q.QQSCS 0.00493 j
0.'004eo
- 0. 004da 0.00412 0.003SS O.CC327
(
0.00 94
(
- 0. 00239 0, 00185 0.00134
- 0. CCCS Q. vCGO a
0 023(
- 0. 027'2 3.0252 0.0253 0
0.0237 0 C""8 C.J'220 0.02'I4 0.0207
(
a O. 2"5 0.2! 9 0 r97 Q.'rol 0 '34 0.17$
O. I. 3
- 0. 157
- 0. I S2 i).:JT
').152 Q. (48 0 '43 0).:36
'J. 132
). 123 0
0, I iW Q.rf9 0.118 0.114
- 0. 111 O. 108
- 0. IGd
- 0. 104
- 0. 102
- 0. 100 0.)
0 O.JI94 Q.otss Q,ot$ 3
'). 0178 0.0571 Q. vl67 0.0!62 O.3138
- 0. 0153 Q.otao 0.01<6 0.5142 Q.ot.9 Q. i)135 0.053t
- 0. O'(29 0.0125 0.0123 0.0121 0.098 0.011$
~
~
a Jio 544
) n 025
- j J.O "CC7
( Q.J(939
- r. O.vl97
((
Q. 35955 Il )'.nt54n
'i~ Qrr 5 0.0(95'.
j C.Jies3 O.oted) j 3.01855
'1344 O.3 ~ S31 0.01519 Q.otrt05
{ O.otr92 0.017.9 I
Q.OITS6 I
0.01 T54 0.01 42 O.ol r 31
- 0. 01 r 0 O.oi709 0 01 cQQ O.QIS66 0.05844 O.Ct624 0 ~ 0160$
3.01600 0.3160 0.0160 O.'0164 0.0164 I
J. MOI922 O. v001905
- 0. Jrol 8$ 1 Q. M~0186
- 0. Cr)ut 643
'). CO!8 4
- 0. 0.0 I aCS i).
)17!9 Q.vGr)1755
(
Q. JOn5 744 O.v&)(7 5 O.ixo17! 0
- 3. Co(696 0
C"'682 Q. QC.)565$
Q. COO(!54 0.3005515 Q. CCC: 6 r)3 Q.'OC)i.'SS 0 r)(r) 7 O. 0001 561
). CCO! 548 0 0001~5 O.GCOI '
O. QCO ISv9
- 0. 0005496 J. 0005464
- 0. CCQ!4. 4 Q.GCC1425 O.CCQIorfo Q."CQI34(
0."001 ST O. CGOI t 7$ ;
- 0. COOC 79
- 0. CGOCrod 3 ~ GC OOOO g
= weight in g ams per 100 arams H20 wnen ".otal pressUre
= 760 mm Attachment 2
'rNP59 8 P AQC - DVAE rNVMBKR 12.10.8 jrIBV(6(O(r(r'V(vMBKA I
0
,PAQB VVMBKR 12i10.8-14 of 19
1
~ ~
Table 10-'1 Table If)-I (Cunfinusdl
'f)LL'BILITYVF CA E'i ~'ATER SC Ta
$0 90
)00
'.aRBO)f DIGXZDF:I CAR CO)f SfO.fOX'DF ~
CHLO ca) o. I
,s 0.3346 1
ss II'I 0 h 74 Q.2539 n49n I'
" '8 Zn,9
!I o.'=
5 ii 0 "h98 I ~
C. 2032 l
Q.ISTO 011903 0.1737 II I
0.1 535 0 '640
~C I
I 5
I 5
I 9
I ln 3
1 14
~
il 6
(l
~ 8 19
(
o
- 1. 546
~
484 i.527 O.C9674 0.09476 Q.C9093 O.C8725 0.083T2 O.vc4397 0.004293 C.CQ4191 O.CO4OZ"-
0.003996 O.C3537 0.23375 o.cec33 0.077Q9 0.07450 C.OT)0$
0.06826, I
C.C66)
Q.
6325 0.06106 0.05S94 c.05694 O.C03903 0.003$ )3 G.C03725
- 0. N3640 0.003559 I
C.CC3479 I
O.CQ3405 0.003332 0.003281 O.Q03194 I
O.CC3130 C.Q03066 0.003007 0.002947 l
Q F 002891 I
0 '02438 0.002T$ 9 l
O.CQ2739 0.002691 O.GG2646 Q.CC2603 I
0.0025oo 0.002519 0.002479 Q.C02442 0.03149 C.03009 0.02442 1.424 Q.C2S16 Q.CZ. 57
<<. 22593
- 3. 148
- 3. 047
- n. 95O
- 2. 856
- 2. TST 0,99T2 0.9654 0.9346 0.9Q50 O,$76$
I 194
- . )54
'I. 1)7
- .083
).JA
- 0. 05c5a4 Q.C5326 Q.051 &
0.05G03 0.'04858 0.8495 0.8232 0.7979 Q.sr33 0.7510 C. C2543 0.02494 Q.C2448 0 024"n O.CZ360
- 2. 680 497 2.5)7 440
- 2. 388 1.0)9 0.985 0.95o 0.928 0.502 Q. 7293
- c. 7100 0.69) 8 0.8739 0.6572 0.04724 0.04589 0.04459 0.04335 0.042) 7 n9 9 2.) do
- 2. 123 2.070 0.023)9 O.CZn3) 0.02244 G.CZZQS 0
C 174 Q.STS 0.$ 54 0.829 0.$ 04
- 0. 731 I) h3 hh C.
Is 590 0.
)s 540 C.)493
- 0. 6413 0.6259
- 0. Sl 'I 2 0 c975 Q 5847 O.ohsa4
- 0. 03997 0.03895 0.03T99 0.03709 0.03624 0.03230 0.02915 O.Q2660 0.02459 2.019 1.970 1.923 1.SSO
'I. S39
- 0. 021 42
- 0. C2i '0 O. 02080 0.02051 0.020'24 0.759 0.738 0.1)5
- 0. 699 0.6$ 2
~s5 26 h7 2$
29
- 0. 1449 0 '406 Q.)ZS6 0.1327 0.1292 0.5723 0.5)ah 0.4590 0.4228 0.3925
- 0. 68S
- 0. 592 a.530 0.479 0.436
- 0. f257
- 0. I IC5 G. 0973 O.OSSO
- 0. 0761 30 3
ss 40 459) 0.002405 O.N223)
O.Q02075 c.aoi933 l
0.001797 0 Co)522 0.00)276 0.000980 0 '0057 Q.caooo ll 0.01998 0.018rs Q.ala 75
- 0. 01690
- a. 01615
- 1. 799
- 1. 602
).43$
- 1. 322
- 1. 225
- 0. 359
- 0. 0578 0 0'48S 0.01440 Q. O'I430
- o. 0142
- 0. 0141
'1.023 0.3295 0.862 0.2793
- 0. SMC
- 0. 2227 0.39 0.)27
- a. Go C. Qco O.C2)TT I
0.01948 0.01826 Q.Q176 I
O.O)72 rI I
O.ai317 I
0.01253 I
- 0. 0s212; 0.01152 O.s))))4 C.C)069 0.0)025 0.00983 0.00943 Q.C0906 0.00870 0'.00838 Q.CQSQS 0.00780 0
C075c3 0.00727 0.00703 0.00680 Q.ocs59 0.00639
- 0. 0062Q 0.00602 0.00584 0.00567 Q.CC55I O.C0535 0.00520 0.005CS 0.00493 0.00480 0.00488 0.00412 0.00366
- 0. N327
- 0. 0(V'94
- 0. 00234 0.00185 O.QGI34 O.CQQS O.QQGQ
-.)P-'L~.fE I
h&DROO:-.'f a
0.027'.Q2 2 O.i0262 C.025t O.C244 I
I I
3,02148 I O.oci"6 si 0.02105 lI C.Q2084 I! O.CZQ64
\\
sl is 0.02025 0 Cnacs C.31949
',! Q,v1972 I('0.0!954 Il 0.01940 Q hi9'sc
'! O.C19!i 0.01897 a
- 0. ZZS 0.2')9 0.19T
- a. aooss O. Qs)o) 901 0.00018SI 0 000)S6 O.cc)0184 C, CCIS24 I
0 ivo)7'o I
Q.)91 0.184 0.179
- 0. 173
- 0. 167 I
0.'162 0.152
- 0. i48 O.)43 I
O.:39 C.'.36
- 0. 'I32 0.)) 9
- 0. 116
- 0. )14
- 0. 111 O.C237 O.C"28 O.v220 0.02!c 0.0207 O.oic'740 0
GGGI ~ "5 O.GCQ)696 I
O.'QGCISez
'.Y.)lddSI Q.GGQ)454 C.CN:C"3
- 0. vN1515 O.aacids)3 l
0 GNI Sd Q.Coo)5. 5 0 0001561 O.'Ocoi 546 Q.C200 C.Q194 0.018$
0.0183
- 0. 0176 0.0171 O.v167 0.0162 0.0)5$
- 0. 0153 C.01883 0.0)$ 89 0.01856 0 OI$44 ll 0.0(831
- 0. 01819 O'.OISO5 I
0.01792 0.01779 0.01766 0.01754 0.01742 0.01731
- 0. 01720 O. 01709
- 0. 0149 0.0146 0.0142 0.0139
- 0. 0135 ON '53
- 0. GC41 0001509
- 0. Qao 1 496
- 0. 000)484
- 0. 108 0.106
- 0. 104
- 0. 102
- 0. 100
- 0. 0131
- 0. 0129
- 0. 0126 0.0123
- 0. 0121 0.01699 0.0166$
0.0)644
- a. 0) 624 0.0)SOS 0.098 0.0118 Q,QQC)4rh
- 0. GGC)4"5 0.000)34 84 0.000134)
Q.GOO)287
~ ~
0.0)SQQ 0.0160 0.016C I O.OISO s Csa)60 0.0001)TS O,QQQ)02 CCCC79 I>>
, C ~ CCOG46 I
0 ~ GQGGQQ
~ ~ ~ ~ ~
o = weicht in orams pe 100 grams H20 when iotal pressure
= 760 mm At"achment B
WP 598 PROCEDURE NUMBER lREV!SION NUMBER lPAGE NUMBEP,
- 12. 10. 8 ll 0
I 12.10.8-14 of
P
<A esslu
¹ luis(s's(s'<s<
us<le'I'ss i ~ <<<i<(< I <a((is (I<'s(< W vss(assr.
EL Iss (a'lsv <iufs'I (<
'il ¹ ls'w<(¹ i<ills(~
I I>> II<<'>>(la<<<(s<t;
~ ss<( ~ a'I(ww sass<>>l lsv us(<!>> (:
asti<'s stw(s'eo s<( ~ I¹ III':( -= (s(l).7 (;s - ~ Ii.t(l)(l:II:I I)/I(III;<'ii((s' liwii i<lsiww!i(l'I;(::(>till)!a.sI.IIIUIII)I'( fs ((/(t)tl.
'I (s< ~ < ¹lass'w (Ii Isl
~ ' >ill ss I Is((ls ¹(
1:su s ~ s 1isiii t I ~ir la i tfsss Ii ws(irs¹lwi ~ >>
'I'¹lels. III (s
'\\ ll'(lit ('llI::i'lilt(:(Il( I'( (:lI l's( hill.l.lhll ('(;It!I tll'll:It(.taitV I'iiv'ls ss>(>> s¹li(ri>> Irwsw II) l<i I'l i.
0nNn C
~
2 C
c) z
~
Us Oa 7(
m (sl 0
2 2
C
((s m
Is 0
m 2
C O
~
g CO (sll(
I(s s)
~(s(
Is 's Uuls I s)
<ib r>0
~ o e>
!s ss 4!e 4 (s
(!~
- I ()
~ >a 2u I !i I s(
os
(( u 05 I <)
IS 2u 75
- I u 4u 45
!a u 55 (i 0 ns 1(s IS 8 la U!s ula US I(( u Iu!a II U I I !i Io'
(
~ >i I,I (s I 'I!>
I 4 i(
(
~
>o ~ ~ ((>'
I(!(
7?' <<'sia 2 u.'1l
.I w((i
.1 I('i.l
- I 'UI
.).I I<(
'I 'e (u
- I (>IJ
.I (( I.I I e(>54 4 Is)5
( 2!>u 4 'l(6 4 519 4 1!>u 4 526 5 Ior 4?f<i
!. 4<<G
!e (o<<5 4 U<<9 4 IUI
(:II8 (e!>43 4 IIS 1 <<11 1 2!>9 1 bta
( r)5
(<<((5 u '!I?3
<<ri<<<J 4 9<<b u 2<<9 9 521
¹U(l (w I I(s (u Sin Iw u/u II PJI II I <<4 I I!<<<1 145 Isa 0 I!s 2 IS 4 Irili I!> 0 I(iu I(i7 ln 4 l(i(i I(i 0 Iru lr 7 11 I IIli II 8 In>>
In 2 IU 4 Ia 6 IU U IiJ 0 (9 2 I<J 4 liJ 6 IJU e'0 0 202
?u 4
?0 li 2<<n
?In
- 2) 2
- 2) 4 216 21 8
?? 0 PP 2 2? 4 22 ri 2?.n
?30 73 2 234 23 0 7;I 0
'7l u Pl 7 r-s>>>> (((,
12,3<<P 12 1<<n Iz Qs I:I 12)
I:I?<Ju 13 4(il I.'I Cia 4 I:Iuw')
13 >J<<I 14 l(in 13 a(1 14!i;Ul ll 1I!s
) I esu:(
I!s W'(('.!j
?ul 15 4)r Ib fil:I I!ior I I(~ 011 Ifi212 in 471 to tn'.s 16 594 lr loss Ir 319 Ir!o I!a tr 153 11 914 Ia 191 15 472 18 GSQ IS Bnn I') 113 1<J 14'I I((!sur I'( 0'1
~ O U(u Pn 31(i
- ~) rin!.
20 0 IS 21 Urn 21 374 21.bu1 pl uis 77 I lu 7p aul 7740'I 7's <J' '
~.
(
24 0 74 0 2.!i 0 ps ~
~
?!s 4 25 6 75i 0 s'6 U 26 2
- rii Pa G
?rn pro 71 2 e'1 I Pl 6 PI U 290 pu 2 zni 29 G 25 6 2>l 0 292
?94
?<J Ci 2>J 0 3(( U 30 2 aoi an a a<<a 310 J)2
- II 4 3(6
- 11 8
- I? u 3>'
- 17 4 an a
- )e' 310 332
- )
- ) l
.!s') Ci
'( I t(
- I I I)
(12
)o. s>>e>> lip 2:( I<JU 7:I 47G 23 )5(i 24 u 19 2>4:lzn 24 411 24 912 25 -(<<J sri 50<J 25 5 IP 2G I i) 26 426 PCi 139 21 uses 21:I)i 20 (4? I
?n 319 20 Gno 29 015 zoasi 2<J 691
- In U43 30:192 3u 145 31.1<<2 31 4(il al 524 32 IOI 32 561 32.934 31312
- i'1 G95 3$ (<52 34 411 31uai
- IS 261
'IS 4(>1 ari uce
- ui 411 36 591
- )1 308 31 129 36 Isb
- (9 sul
- (9 UIU J<< 451
'.I') (u(n Iu.I 4 4
~.'(:
)o 34 4 345 348 Jb 0 352
- (!i I 356
- I!> 0 am Jsi 2
- IG 4 3(i 6 Je0
- 11 0 el! ei 31 4 31 n 318 ano 362 39 4 38S Jn0 39 0 J92
- )9 I
- 1<J 6 an a 400 405 41,0 415 42 0 425 430 43 5 440 415 450 455 460 4(i 5 41 tl 41 5 4(( 0 4<< Ilg 4<) 1<Un 41 25) 41 110 4? 115 42 644 43 111 4:) 595 41 Oru 44 563 45 054 45 54<J innso 48 556 41 Uf>r 41 tsu?
iu toz 40 (izr 49 151 49 li92 Su 23) 50 711 Sl 323 51 619 52 442 53 no9 53 580 54.158 64 131 ss a?i Sn 61 55 34 5<J Qu 6 I (os) 63 Ia 64 80 GG rsl 65 ra rn (i5 11 nn 13 ri 15 GS 11.81 19 (iU ul ai 01 11 (sb Us
<<5 U2 9<)?4 ss' 51 bu 5 Gl 0 515 520 525 530 r¹1 ri slu 545 450 5
5G0 5G5 51,0 ri),5 bun 55!a
!su 0 495 ruo Gu 5 bl 0 6 I 5 820 li2 5 Gin li.l4 640 645 CS0 65.5 Geo fili5 a)0 to. a>>>>s II ui <<ri 01.2(l OQ r>55 IU2 09 i<<I bri Iul.zo I(UJ nn 112 bi 115 2U I IU 04 120 <J2 I?3 au 12(i 81 129 uz I:12 95 I:14 uu 139:li 14P Csu 144 iJ9 149 30 lri2 9 I i'i(. 4) l(io Io IGJ 11 (67 SO 111:ln II!~ '!I!>
119 31 Ia:I 43 101 54 IiJ I 82 19<i Uu o'UU 53 2<<l 96
~
s ~
I
~ o>eoa II(
lir!.s Gnu rie 5 GUU G9 4 10 0
)us 1)u 7)5 120 125 1;I U 73 5 140 1)5 I!e u 1!s 5 I(i0 rub II0 715 ru<<
10!i rno r<J 5 I¹) u U(l '.>
UI 0 Ul 5 520 824 (s) u 5'I 4 el o o'u!I t>1 21'r 2)u us 223 13 z;nr?
2.)3 1 plu o 24:I 0 249 3 zbi u 2f>u 2 265 I 211 5 211 2 2<<1 2 7<<!( I
?<Jb 3
- u(I 4 awl I
- II I I 3pu 1 171 J J.)4 2
- )41 0 3)U I 3'a!i I
- uo',! 4 34'I 1 Jll 3
- tnl 9 J'(
0 4N) 6 iwn 1 4)4 8 5 I ri USU (Lri 5 nou 5(i 5 610 01 5 UU 0 nn 5 590 595 Qo 0 uns Ul 0 015 07 O UP ru t)'.I 0 035 uiu 94 5
>Jb O 952 954 iJS 6 9!i n 9(i 0 On?
>J(i 4 Qan u(i U 91 U 91 2 Ql 4 (p.aeallr<)
'n.696 760 httaclu!ient C
(e see>> lln 47!s 7 41J 6 44? a 450 9 I!>9 n 469.1 411 9 40'I.l 49Ci 0 rsuu 51! 0 425 )6 4:15 Ua
~s44 naq 5'>6 41 bli(i >J!I blr rl
!inu Iiu (s>JU 4I li2 l>(iz 15 li(irJl Car) 2u 411 12 a<<7 Ur 4((r UI 497 ub
))5 I a s,
(
Qr (i 91 U un 0 992 nn.I 98 ii un u
<JU U U') 2 99 4 09 li
<JQ U Iun U inl u 102 0 Io:I u IIII w I(('> I(
tule u Iul 0 Iuu u I(<u (I I IU U I I I u It au 113 u 114 Is 1(b u I iliu 111 sl I IW ss I lu is Io'u >see> II!
(>'(1 In 1<<2 Ir ru1 21 112 4<)
111!>6 127 )5 rzl Qu I:(:I 24 I'ls( SJ 14'I Ub rl>J 2<<
154 SU rfo <<O ru) 51 0 1 5 5(i 01!> IP 0/4 (Hi iJ<<4 ul
>J (I >JP
!(lu 4<)
Iue(t 42 I<<Is( >J?
lur4 44 I I I I ~ 0 I llu II I lur 42 I'1 o>,
IP<<l 4<l I:(ssu ') I I:(.>2 >J! ~
I:I's( (ss ll< e 4<
I Wr( I (
CD C)
I (0
l~
C)
I Ox
~ a o
Table 10-28
't'((l>t(( Il)-"ol DEBSlTY Ot'lEKCUKY A,"iO O'ATElL The density of mercury and. pure air free water under 4 pr~>>ure ot lOl 325 Pa (1 atm) i>> given in units of 'ofan(>>
i>o>c cub(I( I'I'et(in(.'tcc iItl I). For n(I>rcurv. Ii(o values are based on the densitv at 20'I'!>ning l3.545 834 x. ctn ". Tater attains its maximum lensity of 0.999 973 r(n 't 3.98 C.
FI r (rater. the tc(((t>rcaturc it,.
1.)
a>l'axiu(um Ikn>>ity ut (iiikre((t i>nw un~ ip) in atn(o>>t>heres i>> "iven by I= 3.98 ().0""SiP l)
Dw>ai(y of (t'4(rr r
~ (
t>WI I(V oof 55a(aurv
'I IIo'IIMIv of Ws(rr
'I'a mlo..
~ I Owoi(y
~o(
novo oorv 0,999 84 0.999 94 0.999 97 0.999 94 0.999 85 0.999 70 0.999 50 0.999 24 0.998 94 0.998 60 0.998 20 0.997 77 0.997 30 0.996 78 0.996 23 0.995 65 0.995 03 0.994 37 0.993 69 0.992 97 0.992 22 0.991 44 0.990 63 0.989 79 0.988 93 0.988 04
-20
-18 16
-14
~ 2
-10
-8
-6
-2 0
2 4
6 8
10
~ 2 14 16 56 20 22 26 28 10 32 34
'>6, 18 40 42 44 46 48 co 53.644 13.639 53.634 13.629 13.624 13.619 13.614 13.609 13.604 13.600 13.595 13,590 53.58S 13.580 13.575 13.570 t3.565 13.560 13.555 53.550 13.S45 13.540 13.536
'I 3.531 53.526 13.521 13.516 13.511 13.506 13.501 53.496 13.492 13.487 13.482 13.477 13.4 72 S9 62
'I 46
>0 75 oi 79 85 90 96 02 08 15 22 I'
I 36 52 60 10 79 88 97 06
'o 17 26 3'a 47 s6 70 82 93 0716,I 29 42 56 0.987 12 0,986 18 0.985 21 0.984 22 0.983 ZO 0 F82 16 0.981 09 0.980 01 0.978 90 0.977 77 0.976 61 0.975 44 0.974 24 0.973 03 0.975 79 0.970 53 0.969 26 0.967 98 0.966 65 0.965 31 0.963 96 0.962 S9 0.961 ZO 0.9S9 79 0.958 36 52 54 c6 58 SO 62 54 66 68 70 72 74 76 78 80 82 84 86 88 90 92 94 96 98 500 120 140 160 180 200 220
'>4Q 260 280 300 o3.467 68 t3.462 82 53.457 96
- 3 453 09 13.448 23 53.443'7 13.438 52 53.433 67 13.428 82
'13.423 97 53.419
'I3 13.414 28 13.409 43 13.404 60 13.399 77 13.394 92 53.390 09 13.385 26 IL360 42
- 3375 60 13.370 77 53.36S 94 13.365 12 13.356 30 I3.351 48 13,303 4 13.255 4
13.207 6 13.559 I) 13.512 0 13064 S
53.016 9 52.469 2 12.921 5
12.873 7
Attachment 0
IvP 596 PR(aCBOVRB NVMBBR
- 12. 10. 8 RBV(S(ON oVUMBBR 0
~>oa(ooB VVMBBP 12a10.8-16 Of 19
DATA SHEET 1
(PI 662) 2.
PF =
(Pi 662)
Water Temperature (oF) 4.
Gas Temperature (oF)
(Tl 660)
(TZ - 724)-
5.
6.
)
7 ~
VL =
VG' SH =
(cc)
(cc)
(
m
-" mol) 8.
9.
10; PV =
PRG =
(gm/ml)
(psia)
(psia) ll.
Total Dissolved gas
=
~mal CC H20 (from 12.10.8.4.3.2 and 12.10.8.4.E.3)
Reviewed by ATTACl+IBIT E Page 1 of 3 WP 59S PROCEDURE NUMBER
'REVISION NVMBER 12;10.8 0
PAGE NUMBKR 12.10.8-17 of l.
DATA SHEET 2 1.
Weight difference 2.
Ambient temperatUre gms oC 3.
Density 4.
Vs =
5.
Po
=
6.
Pl =
7.
P2
=
8.
VT =
CC psia psia psia CC CC CC CC 9.
Average VT =
10.
P3
=
ll.
Po 12.
VG psia psia CC CC CC CC CC 13.
Average VG =
CC Reviewed by ATTACHMENT E Page 2 of 3 PROCEDURE NUMBER REVISION NUMBER PAGE NUMBER VN 594 12.10.8 0
12.10.8-18 of 19
DATA SHEET 3 1.
Pl =
2.
P2 =
3.
P3
=
4.
VL =
(psia)
(psia)
(psia)
(cc)
(cc)
(cc)
(cc) 5.
Average value of VL =
(cc)
Reviewed by ATTACHMENT E Page 3 of 3 WP 598 PROCEOURE NUM8ER 12.10.8 REVISION NUMBER 0
PAGE NUMBER 12.10.8-19 of 19
g