ML031690028

Emergency Plan Implementing Procedures Manual Volume B, Revision 2003-05

ML031690028
Person / Time
Site:	Oconee
Issue date:	06/10/2003
From:	Rosalyn Jones Duke Power Co
To:	Document Control Desk, Office of Nuclear Reactor Regulation
References
Download: ML031690028 (27)

Text

POPowere Duke R. A. JONES Vice President A Duke Energy Company Duke Power 29672 / Oconee Nuclear Site 7800 Rochester Highway Seneca, SC 29672 864 885 3158 864 885 3564 fax June 10, 2003 U. S. Nuclear Regulatory Commission Document Control Desk Washington, D. C. 20555

Subject:

Oconee Nuclear Station Docket Nos. 50-269, -270, -287 Emergency Plan Implementing Procedures Manual Volume B, Revision 2003-05 Please find attached for your use and review copies of the revision to the Oconee Nuclear Station Emergency Plan:

Volume B Revision 2003-05 June 2003 This revision is being submitted in accordance with 10 CFR 50-54 (q) and does not decrease the effectiveness of the Emergency Plan or the Emergency Plan Implementing Procedures.

Any questions or concerns pertaining to this revision please call Rodney Brown, Emergency Planning Manager at 864-885-3301.

By copy of this letter, two copies of this revision are being provided to the NRC, Region II, Atlanta, Georgia.

Very t s, R. A.

VP, Oconee Nuclear Site xc: (w/2 copies of attachments)

Mr. Luis Reyes, Regional Administrator, Region II U. S. Nuclear Regulatory Commission 61 Forsyth St., SW, Suite 24T23 Atlanta, Georgia 30303 w/copy of attachments Mr. James R. Hall Rockville, Maryland (w/o Attachments, Oconee Nuclear Station)

NRC Resident Inspector M. D. Thorne, Manager, Emergency Planning 0o L4j www. duke-energy. com

June 10, 2003 OCONEE NUCLEAR SITE

SUBJECT:

Emergency Plan Implementing Procedures Volume B, Revision 2003-05 Please make the following changes to the Emergency Plan, Volume B by following the below instructions.

REMOVE INSERT Cover Sheet Rev. 2003-04 Cover Sheet Rev. 2003-05 Table of Contents, page 1 & 2 Table of Contents page 1 & 2 Chemistry Manual 5.2 - 09/25/02 Chemistry Manual 5.2 - 05/29/03

DUKE POWER EMERGENCY PLAN IMPLEMENTING PROCEDURES VOLUME B APPROVED:

44J9CU W. W. Foster, Manager Safety Assurance 06/10/03 Date Approved 06/10103 Effective Date VOLUME B REVISION 2003-05 JUNE 2003

VOLUME B TABLE OF CONTENTS Chemistry Lab Determination Of Boron By Manual Colorimetric Titration 11/06/02 LM-O-P003C Chemistry Lab Boron Analysis by Mettler DL 58 Boron Titration 10/28/02 LM-O-P919 CPIl/A12002/004C Operating Procedure For The Post Accident Liquid Sampling 01/10/03 System (PALSS)

CP/1&2/A/20021005 Post Accident Caustic Injection Into The Low Pressure 07/24/02 Injection System CP12/A120021004C Operating Procedure For The Post Accident Liquid Sampling 01/10/03 System (PALSS)

CP/3/A12002/004C Operation Procedure For The Post-Accident Liquid Sampling 01/10/03 System (PALSS)

CP/3/A/20021005 Post Accident Caustic Injection Into The Low Pressure 07/24/02 Injection System HP/O/B/1009/009 Procedure For Determining The Inplant Airbome Radioiodine 12/03/97 Concentration During Accident Conditions HP/0/B/1009/012 Distribution Of Potassium Iodide Tablets In The Event Of A 01/09/01 Radioiodine Release HP/0/B110091015 Procedure For Sampling And Quantifying High Level 07/23/01 Gaseous Radioiodine And Particulate Radioactivity HP/O/BI1009/016 Procedure For Emergency Decontamination Of Personnel 12129/97 And Vehicles On-Site And From Off-Site Remote Assembly Area HP/l/A/1009/017 Operating Procedure For Post-Accident Containment Air 09/13/00 Sampling System HP/2/A/1009/017 Operating Procedure For Post-Accident Containment Air 09/13/00 Sampling System HP13/A/1009/017 Operating Procedure For Post-Accident Containment Air 09/13/00 Sampling System RP/O/B/10001011 Planned Emergency Exposure 02/01/94 RP/0/B/1000/025 Operational Support Center Manager Procedure 04/29103 RP/A/B/1000/027 Re-Entry Recovery Procedure 05/30100 Revision 2003-05 June 2003 1

VOLUME B TABLE OF CONTENTS Chemistry Manual Emergency Response Guidelines 05/09/03 5.1 Chemistry Manual Post Accident Procedure Use Guidelines 05/29/03 5.2 I Maintenance Emergency Preparedness Plan Activation 08/06/02 Directive 9.1 WPG 1.5 Emergency Plan for Work Control Group 03/31/03 OMP 1-7 Operations Emergency Response Organization 08/31/00 Radiation Protection Radiation Protection Emergency Response 09/01/98 Manual 11.1 Radiation Protection Radiation Protection Site Assembly 06105100 Manual 11.4 Safety Services Safety Services Emergency Response Procedure 2.1 03/14/00 Procedure 2.1 Revision 2003-05 June 2003 2

It INFORMATION ONLY CHEMISTRY MANUAL 5.2 POST ACCIDENT PROCEDURE USE GUIDELINES

~~~~~~~~~~~~~~~~~

REVISION NUMBER ISSUE DATE Oxiginal 07/15/82 1 10/25/95 2 01/20/97 3 04/07/97 4 11/20/97 5 08/17/98 6 03/16/99 7 . - 12/28/99 8 09/18/00 9 04/11/02 10 07/29/02 11 09/25/02 12 5/7/p Prepared by:4 )t Date:_________

10CFR0.59 req red: Yes _ No_

Approval: /_______Date:_________

Control Copies delivered to Emergency Planning: 4 n n> t Date: 5/ag/03 DUKE POWER COMPANY OCONEE CHEMISTRY MANUAL

Chemistry Manual 5.2 Page 2 of 13 Post Accident Procedure Use Guidelines

1. Purpose NOTE: 1. NSD 228 Applicability Determination and a 50.59 screening is required to make major changes to this section. Minor changes per NSD 703 can be made without a Applicability Determination.

2. Seven Control copies and one Information Only copy of this CSM shall be routed to the Emergency Preparedness Team within three (3) working days following any approved changes/modifications.

This section provides guidelines on the administration and use of chemistry post accident procedures and the precautions that should be observed during the use of these procedures.

Special attention is given to limits and precautions associated with the execution of a procedure during a projected accident. Personnel requirements and procedure work locations will be given for personnel exposure consideration. Also, a listing of RIAs of interest to Chemistry for planning and assessment activities is included in Enclosures 6.1 and 6.2. This information is intended only as guidelines with the knowledge that an actual accident situation may deviate greatly from a projected scenario.

2. Guidelines 2.1 Limits and Precautions NOTE: These Limits and Precautions do not apply to the task for Addition of Caustic to the LPI (RCS) System. This task is a "time critical task" and therefore is not subject to the below Limits and Precautions.

2.1.1 Valve alignments should NOT be made and samples should NOT be taken without prior authorization from the TSC/OSC.

2.1.2 Do NOT attempt any phase of sampling or-analysis without Radiation Protection coverage.

2.1.3 ALL personnel will need prior authorization from the OSC to exceed any exposure limit.

Chemistry Manual 5.2 Page 3 of 13 2.1.4 Radiation levels of the sampling and analysis area should be measured continuously during all phases of sampling, sample preparation, and analysis.

2.1.4.1 Air activity should be determined by use of installed air monitors or through the use of portable air sampling equipment.

2.1.4.2 Area dose rates should be established by the use of installed radiation monitors or by portable radiation survey instruments.

2.1.4.3 Portable shielding, remote handling equipment, video equipment, etc., should be used where practical during sample preparation and sample analysis.

2.1.4.4 All personnel working in the lab area and transporting samples shall monitor their personaf dosimetry frequently to avoid exceeding maximum dose limits.

2.1.5 The post accident analysis should be done in a fume hood and/or other precautions should be taken to avoid the release of gaseous activity.

2.1.6 Radiation exposure to an individual during all phases of sampling should be limited so as not to exceed an annual accumulative exposure of 2 rem whole body; 50 rem skin of whole body; 50 rem extremities; or 15 rem eye respectively. All personnel will need prior authorization from the TSCIOSC to knowingly exceed any exposure limit. The exposure received may require an occupational exposure penalty and/or a medical decision as to whether an individual can continue in radiation work.

2.2 Waste Disposal 2.2.1 Determine by detailed planning meeting, the exact course of action to be taken. Under no condition should liquid or solid wastes be disposed of without prior specific RP directions.

2.2.2 Designate a sealable carboy as the "Post Accident Lab Waste" container. This container should be shielded and used as an interim liquid waste disposal container for all liquid analytical waste.

2.2.3 Request RP to designate an area where the "RCS Hlush" bottle(s), "RCS Sample" bottle(s) and "Post Accident Lab Waste" container may be stored until final disposal.

2.2.4 In the event an area is grossly contaminated and cannot be decontaminated, evaluate the need for shielding or protective covering to prevent the spread of airborne activity.

Chemistry Manual 5.2 Page 4 of 13 2.3 Procedures 2.3.1 CP/1,2,3/A12002/001 - Unit One, Two, or Three Primary Sampling System Description - Defines the steps neces§ary to sample tanks, systems, etc.,

associated with the primary system to determine various chemical concentrations and radioactive isotopes.

Personnel - One (1) Chemistry technician - to sample One (1) RP technician Precautions - Personnel should expect high dose rates and possible airborne activity. Use applicabre RIA's listed in Enc. 6.1 and 6.2.

Some sample points will be at system pressure.

z Use - This procedure-should be used to obtain reactor coolant samples when possible. Other primary systems and tanks such as LPI, BWST, SFP, etc. can be sampled using these procedures.

Location - Third floor Aux building - Primary sample hoods; First floor Aux building - Waste sample hoods

Chemistry Manual 5.2 Page 5 of 13 2.3.2 CP11,2,31A120021004 C - Operating Procedure for the Post Accident Liquid Sampling System (PALSS)

Description - Outlines method to sample primary coolant using the remotely operated PALSS sampling system. System can sample from RCS "J-Leg", LPI Pump Discharge, and HPI Letdown.

Personnel - One (1) Chemistry technician - panel operation One (1) person to communicate with control room for LP-65 (if required)

One (1) Radiation Protection technician.

Precautions - Because of location of sample panels, personnel may be in high radiation area with airborne activity. Evaluate shuttle of personnel to and from lower dose areas. Use the readings from applicable RIAs listed in Enc. 6.1 and 6.2 to plan sampling activities.

Use - This procedure should be used to sample primary coolant when significant fuel damage is expected. System is designed to limit personnel exposure during sampling. Sample point for RCS "J-Leg" needs flow through that loop to ensure representative sample. If significant loss of coolant has occurred, need to'also sample LPI Pump Discharge.

Location - First floor auxiliary building Near 1 & 2 Waste Disposal Hood - Units 1 & 2; Near 3 Waste Disposal Hood - Unit 3

Chemistry Manual 5.2 Page 6 of 13 2.3.3 CP/1,2,3/A/2002/004E - Unit One, Two or Three Reactor Coolant Sampling During an Appendix "R" Accident Description - This procedure provides instruction on sampling the RCS via an ice cooled sampler i'nstalled on the discharge side of valve 1, 2, 3 RC-179 of the affected unit during an Appendix "R" accident situation.

Personnel - Two (2) Chemistry Technicians One (1) Radiation Protection Technician Two (2) I&E Technicians Precautions - Personnel should expect normal dose rates and a high probability of airbome activity due to fission gas release during sample flush to floor drain. Sample temperature &

pressure will be very high & if not cooled properly will flash to steam.

Use - This procedure should only be used during an Appendix R" fire when all power is lost. It should be considered the last alternative for Reactor coolant sampling.

Location - Unit 1, 2, 3 LPI Pump roms

Chemistry Manual 5.2 Page 7 of 13 2.3.4 CP/1&2,3/A/20021005 - Post Accident Caustic Injection Into the Low Pressure Injection System NOTE: This is a "time critical task" and must be initiated immediately when recirculation mode off the RBES has been established.

Description - Outlines the method used to raise the pH of the primary coolant to 7.0 - 8.0 following a LOCA. Caustic additions will improve the iodine liquid partition factor and inhibit hydrogen gas formation. Use Enc. 6.3 to calculate quantity of caustic required for addition.

Personnel - Two (2) Chemistry technicians (desirable, but not required)

One (1) Radiation Prote-tion tech (desirable, but not required)

Two (2) additional OSC personnel to move Caustic (desirable, but not required)

Precautions - High radiation areas and airborne activity may be a concern.

Use readings from applicable RIAs listed in Enc. 6.1 and 6.2 to plan addition. Establish Low Dose Waiting Areas as needed. Heat Stress conditions-may also be a concern.

Use - This procedure should be used when a significant loss of coolant to the Reactor Building has occuned and there is concem about an Iodine release and/or hydrogen gas formation. The LPI System MUST be in service and taking suction from the emergency sump.-

Location - Units 1&2 - 2nd floor of the Aux. Bldg, Chemical Addition Area Unit 3 - 1st floor of the Aux Bldg, Chemical Addition Area

Chemistry Manual 5.2 Page 8 of 13 2.3.5 LMIO/P003C - Determination of Boron by Manual Colorimetric Titration Using Phenolphthaline Indicator Description - Outlines the use of manual potentiometric titrations to determine boron concefitration. The range for this analysis is between 100 and 2500 ppm. Samples with concentrations greater than 1000 ppm must be diluted for dose and time considerations.

Personnel - One (1) Chemistry technician One (1) Radiation Protection technician Precautions - Personnel should expect high dose rates and possible airborne activity. Use the readings from applicable RIAs listed in Enc. 6.1 and 6.2 to deteine if the Primary Lab is available for use.

Use - This procedure should be used to analyze for boron whenever conditions have resulted in the loss of the normal analytical instrumentation, such as an Appendix "R" Accident.

Location - Rooms 329 and 330.

2.3.6 LMIOtP9l9 - Boron Analysis By MettlerDL-58 Titration Description - This method covers the precise determination of boron concentration in the 0.2 - 10,000 ppm range in high purity water (RCS) using the Mettler DL-58 Titration System.

Personnel - One (1) Chemistry technician One (1) Radiation Protection technician Precautions - Personnel should expect high dose rates and possible airborne activity. Use the readings from applicable RIAs listed in*

Enc. 6.1 and 6.2 to determine if the Primary Lab is available for use.

Use - This procedure should be used as the primary method for determining boron concentration.

Location - Rooms 329 and 330.

Chemistry Manual 5.2 Page 9 of 13 2.3.7 LMO/P914 - Ion Analysis - DX-500 IC Description - Outlines the use of ion chromatograph in deternination of chloride concentration in primary coolant when fuel failure is expected. "

Personnel - One (1) Chemistry technician One (1) Radiation Protection technician Precautions - Personnel should expect high dose rates and possible airborne activity. If too much dilution is required based on dose consideration, then this procedure could not be utilized. Use the readings from applicable RIAs listed in Enc. 6.1 and 6.2 to determine if the Dionex Lab is available for use.

Use - This procedure should be used when dose consideration allows a reasonable expectancy of being able to detect chloride at the dilution required.

Location - Room 330.

2.3.8 L OM/OP008 - The Determination of Hydrogen Using the Carle or SRI Gas Chromatographs Description - This procedure covers the use of the Carle Series and the SRI

- Series Analytical Gas Chromatographs to determine the concentration of hydrogen in gas samples.

Personnel - One (1) Chemistry technician One (1) Radiation Protection technician Precautions - Personnel should expect high dose rates and possible airborne -

activity. Use the readings from applicable RIAs listed in Enc. 6.1 and 6.2 to determine if the Primary Lab is available for use.

Use - This procedure should be used in an accident situation to analyze for hydrogen concentration.

Location - Rooms 329 and 330.

Chemistry Manual 5.2 Page 10 of 13 2.3.9 LM/O/G004 - Determination of Gamma Isotopic Activity Description - Outline of method used to prepare sample for gamma isotopic analysis.

Personnel - One (1) Chemistry technician One (1) Radiation Protection technician Precautions - Personnel should expect high dose rates and possible airborne activity. Utilize -remote handling when possible. Use the readings from applicable RIAs listed in Enc. 6.1 and 6.2 to determine if the Primary Lab and Count Room are available for use.

Use - This procedure should be used when a gamma isotopic analysis is required.

Location - Rooms 329 and 330.

-3. Additional Information 3.1 Tank volumes:

Quench Tank 5,834 gallons

-- BWST 388,000 gallons .

. CBAST 22,440 gallons BANIT 2,500 gallons BHUT 82,000 gallons LDST 4,488 gallons (31.26 gal/in)

CFT 10,470 gallons (total)

SFP (1&2) 546,000 gallons SFP (3) 374,000 gallons LiOH 30 gallons NaOH 100 gallons MWT 20,200 gallons HAWT 2,000 gallons LAWT 3,000 gallons CT I 1,300,000 gallons CTP 2 1,100,000 gallons CTP 3 3,000,000 gallons CTP 3 (weir down) 4,900,000 gallons

Chemistry Manual 5.2 Page 11 of 13 3.2 System Volumes:

RCS (cold/hot) 88,000160,000 gallons Reactor Building 1,910,000 ft 3 free volume CST 30,000 gallons Waste Gas 23,800 ft3 Hotwell 150,000 gallons OTSG (Secondary Side) 28,000 gallons 3.3 Cooler Supplies:

Quench Tank - CC Decay Heat - LPSW Letdown - CC Seal Return - RCW RBCU - LPSW CC - LPSW RCW - CCW Pri Sample - RCW PALSS - RCW

4. Suggested Actions 4.1 Nonnal Operating Conditions: -

Observation: Loose part or mechanical failure has caused suspected loss of some fuel integrity.

Actions:

• Do not over react, close coordination with OPS and RP will be necessary to understand where and how to sample coolant.

• First find out exact status of unit (subcritical, pressure, temperature, # of RCP on, letdown flow rate, area monitor readings?)

• If the unit is shutdown, then remember that samples will show normal coolant fission product spiking - must compare to earlier unit trip results.

• Have RP survey letdown piping (if in service) and compare to normal values before deciding which method to use in sampling.

Chemistry Manual 5.2 Page 12 of 13

• For truly mechanical damage, gap activity isotope should increase (xenons, kryptons, iodines) with much smaller increases in (strontium, barium, cesium, less mobile isotopes).

• With gap activity release, degassing of coolant tission gases will be much more pronounced. Appropriate respiratory protection should be considered while sampling.

4.2 Overheat Condition Without Fuel Melt Observation: RB pressure and temperature increase. Suspect loss of coolant to Reactor Building.

Actions:

• If ES actuation occurs, then letdown will be automatically secured thus rendering normal sample point useless (Ops may-manually override)

• Make immediate plans to move necessary equipment to RW facility or Environmental lab for chemical analysis of boron and pH. Dose rates may render Primary lab useless.

• Before deciding which sample location to use, a careful evaluation of all data should be perforned.

1. Boron concentration can be calculated based on injection volumes and known concentrations.

2. RIA readings from RIA 57, 58 cani closely estimate failed fuel percentage without need for sampling.

3. If recirculation of water through vessel is not available, the PALS J-leg sample will not be representative.

4. Core exit thermocouple readings and mapping can aid in estimating area and extent of core damage.

• If electrical system load shed has occurred, then many of the normal power supplies to the Chemistry group may be unavailable without Operations assistance.

Chemistry Manual 5.2 Page 13 of 13 4.3 Fuel Melt Actions:

• All of Section 4.2 action items are applicable.'

• Expect higher levels of barium, strontium and praseodyium from fuel matrix loss.

• Expect high suspended solids in any sampling attempted.

• Both hydrogen percentage and RIA 57, 58 readings can and should be used in lieu of sampling, at least until dose levels have significantly dropped.

• Boron as a criticality concern should be minimal - weighing the small benefit of a sample versus the extreme risk to an individual(s) should be considered.

5. References 5.1 ONS.Post Accident Procedures 5.2 ONS OFD Drawings 5.3 ONS FSAR 5.4 ONS lTS 5.5 BWNS Water Chemistry Manual for 177 F.A. Plants, BAW-1385, Revision 6. 1/27/93 5.6 Calculation OSC-7337, "Post-Accident Reactor Building Sump pH Analysis", Revision 0, October 1999 5.7 OP/0/A/1108/001, "Curves and General Information"

6. Enclosures 6.1 RIAs of Interest to Chemistry 6.2 Location of Sample Points for Multipoint RIAs 6.3 Caustic Addition Calculations 6.4 E, A and R Values for 1% Failed Fuel and DBA 6.5 Caustic Addition Calculations 6.6 Quarterly Inspection of Post Accident Equipment

Enclosure 6.1 Chemistry Manual 5.2 RIAs of Interest to Chemistry Page 1 of 2 RIA # RANGE LOCATION INFORMATION USED FOR 1RIA4 0.1 - 10e7 mR/hr Reactor Building Entrancel Indicates a LOCA with moderate to severe 2RIA4 Personnel Hatch fuel damage; 2RIA4 is located near the 3RIA4J Primary Lab and Count Room - Readings used to assess the need to prepare alternate labs RIA-8 0.1 - 10e7 mR/hr Primary Chemistry Lab Used to assess the need to prepare the alternate Primary Lab and/or Count Room 2RIA-10 0.1 - 10e7 mRZ/hr Unit 1 Primary Sample Hood Used for planning sampling. Readings will 2RIA-10 Unit 2 Primary Sample Hood be high once sampling is started if significant 3RIA-10 Unit 3 Primary Sample Hood fuel damage has occurred IRIA-12 0.1 - 10e7 mRlhr Unit 1&2 Boric Acid Mix Tank Readings used for planning chemical 3RIA-12 Unit 3 Boric Acid Mix Tank additions (ie: Caustic Additions)

IRlA-13 0.1 - 10e7 mR/hr Unit 1&2 Waste Sample Hood - Used for planning sampling activities from 3RIA-13 Unit 3 Waste Sample Hood the PALS. Readings may be high if significant fuel damage has occurred 1RIA-15 0.1 - 10e7 nRJir Unit 1&2 HPI Pump Room Provide preliminary indications of significant 3RIA-15 Unit 3 HPI Pump Room fuel damage lRIA-16,17 0.01 - 10e3 mR/hr - Unit 1 'A & B' Main Steam Lines Readings > background from these RLAs are 2RIA-16,17 Unit 2 'A & B' Main Steam Lines indications of primarylsecondary steam 3RIA-16,17 Unit 3 'A & B' Main Steam Lines generator tube leaks 3RIA-19 0.1 - 10e7 mnR/hr Laundry and Hot Shower Tank Room Used for planning Unit 3 caustic; readings may be high if significant fuel damage has occurred due to being near LDST IRIA-31 10 - 10e6 CPM Behind air compressors in Turbine Multipoint RIA that monitors LPSW .

Building Basement, west of Unit 2 effluents from LPI Cooler, and CC Cooler.

Powdex - Readings > background indicate a primary coolant leak into the LPSW System. See 3RIA-31 North of sewage ejectors at Unit 3, Enc. 6.2 for sample point locations.

west wall of Turbine Building IRIA-32 10 - 10e6 CPM Monitor on first floor of Aux Multipoint RIA that measures airborne 3RIA-32 Building; sample points are located activity levels in various locations (ip to 24) in various room/areas throughout the through the Aux Building. Used to plan Aux Building sampling and chemical addition activities.

See Enc. 6.2 for sample point locations.

Enclosure 6.1 Chemiistry Manual 5.2 RIAs of Interest to Chemistry Page 2 of 2 RIA # RANGE LOCATION INFORMATION USED FOR lRIA-35 10 - 10e6 CPM Behind air compressors in Turbine Monitors LPSW discharge from the 2RIA-35 Building Basement, west of Unit 2 Building. Readings > background are Powdex indicators of primary coolant leak into the 3RIA-35 Same location as 3RIA-31 LPSW System; RIA-31 readings will increase also.

lRIA40 10 1e6 CPM Unit 1 CSAE Off Gas Discharge Monitors CSAE Off Gas effluent to each unit 2RIA40 Unit 2 CSAE Off Gas Discharge vent. Indicates steam generator tube leaks.

3RIA40 Unit 3 CSAE Off Gas Discharge 1,2,3 RIA 10e7 RJhr Unit 1 Reactor Building Measures activity in the Rx building during a 57&58 Unit 2 Reactor Building LOCA. Readings from these RIAs can be Unit 3 Reactor Building related to % failed fuel.

Enclosure 6.2 Chemistry Manual 5.2 Location of Sample Points Page 1 of 2 for Multipoint RIAs 1RIA-31 SAMPLE POINTS IRIA-31-1 LPI/Decay Heat Cooler A Outlet 1RIA-31-2 LPI/Decay Heat Cooler B Outlet 1RIA-31-3 RB Component Cooler A Outlet 1RIA-31-4 RB Ventilation (Cooling) Unit A Outlet IRIA-31-5 RB Ventilation (Cooling) Unit B Outlet 1RIA-31-6 RB Ventilation (Cooling) Unit C Outlet IRIA-31-7 LPI/Decay Heat Cooler 2A Outlet 1RIA-31-8 LPI/Decay Heat Cooler 2B Outlet 1RIA-31-9 RB Component Cooler 2B Outlet 1RIA-31-10 RB Ventilation (Cooling) Unit 2A Outlet lRIA-31-11 RB Ventilation (Cooling) Unit 2B Outlet 1RIA-31-12 RB Ventilation (Cooling) Unit 2C Outlet' 3RIA-31 SAMPLE POINTS 3RIA-31-1 LPI/Decay Heat Cooler 3A Outlet 3RIA-31-2 LPI/Decay Heat Cooler 3B Outlet 3RIA-31-3 RB Component Cooler 3B Outlet 3RIA-31-4 RB Ventilation (Cooling) Unit 3B Outlet 3RIA-31-5 RB Ventilation (Cooling) Unit 3A Outlet 3RIA-31-6 RB Ventilation (Cooling) Unit 3C Outlet IRI-32 SAMPLE POINTS; IRIA-32-1 Unit 1 Pipe Rooms; Elevation 758 and 771 1RIA-32-2 Unit 2 Pipe Rooms; Elevation 758 and 771 1RIA-32-3 Spent Resin Storage Tanks, Condensate Test Tanks, Unit Letdown Storage Tank, Boric Acid Mix Tank IRIA-32-4 RC Bleed Evaporator Room, Unit 1&2 Miscellaneous Waste Holdup Tank, Unit 2Letdown Storage Tank IRIA-32-5 Waste Drumming Area 1RIA-32-6 Miscellaneous Waste Evaporator Room 1RIA-32-7 Unit RC Bleed Transfer Pump, Unit 1 RC Bleed Holdup Tanks, Unit 1 Concentrated Boric Acid Storage Tank 1RIA-32-8 Unit 2 RC Bleed Transfer Pump, Unit 2 RC Bleed Holdup Tanks, Unit 2 Concentrated Boric Acid Storage Tank 1RIA 10 Waste Gas Compressor, RC Bleed Evaporator Feed Tank IRIA-32-11 Unit I Pipe Rooms; Elevations 783-796 1RIA-32-12 Unit 2 Pipe Rooms; Elevations 783-796

Enclosure 6.2 Chemistry Manual 5.2 Location of Sample Points Page 2 of 2 for Multipoint RIAs 3RIA-32 SAMPLE POINTS 3RIA-32-1 Unit 3 Pipe Rooms; Elevation 758 and 771 3RIA-32-2 Unit 3 Pipe Rooms; Elevations 783-796 .,

3RIA-32-3 RB Component Coolers, Letdown Filters, Hatches, Waste Gas Compressor Room, Waste Gas Decay Tanks 3RIA-324 Unit 3 RC Bleed Holdup Tanks, Unit 3 Concentrated Boric Acid Storage Tank,

. Unit 3 Miscellaneous Waste Holdup Tank Area 3RIA-32-5 High Activity Spent Resin Storage Tank, Boric Acid Mix Tank and Pumps, Spent Resin Storage Tank Area

Enclosure 6.3 Chemistry Manual 5.2 Caustic Addition Calculations Page 1 of 2

1. Initial Conditions for Injection 1.1 An emergency is in effect due to a LOCA.

1.2 The Low Pressure Injection LPI) system is in operation with the LPI pumps taking suction from the BWST.

1.3 The Reactor Building Emergency Spray system may or may not be in operation from the BWST through the spray headers.

1.4 The addition of caustic SHALL begin W1THIN thirty (30) minutes AFTER switchover to the recirculation mode of core cooling. The recirculation mode is in effect whenever the suction for the LPI pumps' is aligned to the Reactor Bldg. Emergency Sump.

1.5 The addition of caustic will be made upon authorization of the TSC/OSC, or upon notification by Operations when the TSC/OSC has not yet been activated.

2. Bases for Caustic Addition Calculations 2.1 Calculations for the amount of caustic required for neutralization of the borated water are dependent on:

2.1.1 An reasonable estimate of the volume of borated water being used as the core flooding coolant; 2.1.2 The boron concentration of the sources of water prior to addition.

2.2. If the total volumes of the CFTs and BWST are used, then the maximum amount of caustic required for neutralization of the borated water to a pH of 7.5 is 500 gallons.

This amount has been calculated with the following considerations:

2.2.1 Both CFTFs and the BWST have a total volume of 403,000 gallons with a boron concentration of 2300 ppm; 2.2.2 The RCS has a volume of 88,000 gallons with a boroD conceiitration of 1000 ppm.

Enclosure 6.3 Chemistry Manual 5.2 Caustic Addition Calculations Page 2 of 2

3. Determination of the amount of Caustic for pH 7.0 to 8.0 based on calculated Boron Concentration Date Time Unit By CF1 'A' Boron, ppm CFT 'B' Boron RCS Boron BWST Boron INOTE: Volume of BWST is 7608 gallons/ft.

I BWST volume added to RCS, gallons (obtain estimate from Operations) 3.1 Calculate the average boron concentration in the recirculating coolant to be neutralized.

(ACFr bomon ppm +bDCF borogpp (RCS bomX88,000 gl)+ (BWSTb ppmXVolune, ga)

Av-rge Baron,Avaage ppm =

ppm = B . ) gal +88,OOOgal+BWST volwne,gal)

~~~~(IS,OOO ppmAOume,gal,IUM'gW

- 3.2 From Enclosure 6.5, using the average-boron concentration, determine the B/Na ratio for the target pH.

NOTE: Target pH is typically 7.5.

L__ _.

. Target pH_ ____ B/Na Ratio. _

3.3 Calculate the Na concentration required for neutralization:

Na.rop-Average Borort ppm)

B/Na Ratio )

3.4 Calculate the amount of 35% NaOH to be added to achieve the target Na concentration:

NaOH, gal = (Na, ppmX1.74XCoolant Volume, gal) 483,000 ppm NaOH where:

• 1.74 is the gravimetric conversion factor for Na to NaOH ([40. FW N° 1) and; L23,FW Na j)ad

• 35% wt. NaOH contains 483 gn/I or 483,000 ppm NaOH.

Enclosure 6.4 Chemistry Manual 5.2 E, A and R Values for Page of 1% Failed Fuel and DBA 1% Failed Fuel:

E - 0.34 MeV/dis.

A - 0.293 mCi/ml R = 0.18 mR/hr-mCi at Im for E 0.34 MeV 100% Failed Fuel or Design Basis Accident (DBA):

E - 1.14 MeV/dis.

A - 1.324 x 105 uCi/mL R = 0.58 R/hr-Ci at Im for E - 1.14 MeV A direct proportion should exist between E and R for any failed fuel value > 1% and < 100%.

( Enclosm( Chemistry Manual .I Caustic Addition Calculations Page 1 of 1 Sump pH at 25C as a Function of Boron and Sodium Concentrations 26 rX~_l 24 -- *-pH ~~~~~~~~~~~~~~~~~7.00 22 2 >4l 0t =pH 725l z 20__--_*.-pH__7 50 Q18 - . pH 7.75 _

B 16 _

E 14 -__

.2 10lo_ _ _ _ _ _ _

~8 4

1700 1800 1900 2000 2100 2200 2300 2400 2500 2600 2700 2800 2900 3000 Boron concentration (ppm B)

Enclosure 6.6 Chemistry Manual 5.2 Quarterly Inspection of Page 1 of 1 Post Accident Equipment

1. Caustic addition equipment stored in the brown cabinet in AB, 2nd floor -10 ft North of 1 & 2 Chemical Addition Area:

Goggles Face shield Bung Wrench Corrosive suit Gloves Flashlight Boots Stainless steel flex hose Tank to valve adapter Tape measure

2. Appendix 'R' sampling apparatus stationed in each units respective LPI room:

UNITS 1 (RM-61) 2 (RM-63) 3 (RM-82)

Sample cooler Ice container (30 gal. drum)

Glass thermometer Plastic liter bottles (3) .

Tygon tubing for cooler (1 3/4", 2 1/4") .. _ -

Adjustable wrench ..

250 mL disposable beaker - __. __ .

Hose isolation clamp ;___-__