Text

2013 Annual Radiological Environmental Operating Report
	ML14139A159
Person / Time
Site:	Catawba
Issue date:	05/14/2014
From:	Henderson K; Duke Energy Carolinas
To:	; Document Control Desk, Office of Nuclear Reactor Regulation
References
	CNS-14-063
	Download: ML14139A159 (155)
	v • d • e

Kelvin Henderson DUKE Vice President

ENERGY, Catawba Nuclear Station Duke Energy CN01VP I 4800 Concord Road York, SC 29745 CNS-14-063 o: 803.701.4251 f: 803.701.3221 May 14, 2014 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, D.C. 20555-0001

Subject:

Duke Energy Carolinas, LLC Catawba Nuclear Station, Units 1 and 2 Docket Nos. 50-413 and 50-414 2013 Annual Radiological Environmental Operating Report Pursuant to Catawba Nuclear Station Technical Specification 5.6.2 and Selected Licensee Commitment 16.11-16, please find attached the 2013 Annual Radiological Environmental Operating Report. This report covers operation of Catawba Units 1 and 2 during the 2013 calendar year.

Any questions concerning this report should be directed to Randy Hart at (803) 701-3622.

Kelvin Henderson Vice President, Catawba Nuclear Station Attachment www.duke-energy.com

U.S. Nuclear Regulatory Commission 2013 Annual Radiological Environmental Operating Report May 14, 2014 Page 2 xc (with attachment):

V. M. McCree Regional Administrator U.S. Nuclear Regulatory Commission - Region II Marquis One Tower 245 Peachtree Center Ave., NE Suite 1200 Atlanta, GA 30303-1257 G. Edward Miller NRC Project Manager (CNS)

U.S. Nuclear Regulatory Commission One White Flint North Mail Stop 8 G9A Rockville, MD 20852 xc (with CD only):

G. A. Hutto, Ill, Senior Resident Inspector U.S. Nuclear Regulatory Commission Catawba Nuclear Station

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0 SENERGY.

Catawba Nuclear Station Units 1 and 2 AREOR An~nual Radlalogicai F,,ii Operating~ Fv ý ýort 2 (),13

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1. ENERGY ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT DUKE ENERGY CORPORATION CATAWBA NUCLEAR STATION Units 1 and 2 2013

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TABLE OF CONTENTS 1.0 Executive Summary 2.0 Introduction 2.1 Site Description and Sample Locations 2.2 Scope and Requirements of the REMP 2.3 Statistical and Calculational Methodology.

2.3.1 Estimation of the Mean Value.

2.3.2 Lower Level of Detection and Minimum Detectable Activity 2.3.3 Trend Identification.

1-1 2-1 2-1

2-1 2-2 2-2 2-3 2-3 3.0 Interpretation of Results 3.1 Airborne Radioiodine and Particulates 3.2 Drinking Water.

3.3 Surface Water 3.4 Ground Water 3.5 Milk.

3.6 Broadleaf Vegetation.

3.7 Food Products 3.8 Fish.

3.9 Shoreline Sediment 3.10 Direct Gamma Radiation 3.10.1 Environmental TLD 3.10.2 ISFSI 3.11 Land Use Census 4.0 Evaluation of Dose 4.1 Dose from Environmental Measurements 4.2 Estimated Dose from Releases 4.3 Comparison of Doses.

5.0 Quality Assurance 5.1 Sample Collection 3-1 3-2 3-5 3-7 3-9 3-10 3-11 3-13 3-14 3-17 3-20 3-20 3-20 3-23 0

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0 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 5.10 5.11 Sample Analysis Dosimetry Analysis Laboratory Equipment Quality Assurance 5.4.1 Daily Quality Control 5.4.2 Calibration Verification 5.4.3 Batch Processing Duke Energy Intercomparison Program Eckert & Ziegler Analytics Cross Check Program ERA Proficiency Testing Duke Energy Audits.

U.S. Nuclear Regulatory Commission Inspections State of South Carolina Intercomparison Program TLD Intercomparison Program.

5.11.1 Nuclear Technology Services Intercomparison Program 5.11.2 Internal Crosscheck (Duke Energy).

4-1 4-1 4-1 4-2 5-1 5-1 5-1 5-1 5-1 5-1 5-1 5-1 5-1 5-2 5-2 5-2 5-2 5-2 5-3 5-3 5-3 6-1 6.0 References

Appendices Appendix A: Environmental Sampling and Analysis Procedures I.

Change of Sampling Procedures II.

Description of Analysis Procedures III.

Change of Analysis Procedures.

IV. Sampling and Analysis Procedures A.1 Airborne Particulate and Radioiodine A.2 Drinking Water A.3 Surface Water A.4 Ground Water.

A.5 Milk A.6 Broadleaf Vegetation A.7 Food Products.

A.8 Fish A.9 Shoreline Sediment.

A.10 Direct Gamma Radiation (TLD)

A.11 Annual Land Use Census V.

Global Positioning System (GPS) Analysis.

Appendix B: Radiological Env. Monitoring Program - Summary of Results Air Particulate Air Radioiodine.

Drinking Water.

Surface Water Ground Water Milk.

Broadleaf Vegetation Food Products Fish.

Shoreline Sediment Direct Gamma Radiation (TLD)

Appendix C: Sampling Deviations and Unavailable Analyses C.A Sampling Deviations C.2 Unavailable Analyses Appendix D: Analytical Deviations D.1 Analytical Deviations Appendix E: Radiological Environmental Monitoring Program Results Appendix F: Errata to Previous Reports LIST OF FIG URES A-1 A-2 A-2 A-3 A-3 A-3 A-3 A-4 A-4 A-4 A-4 A-4 A-5 A-5 A-5 A-5 A-6 B-I B-2 B-2 B-2 B-2 B-2 B-3 B-3 B-3 B-3 B-3 B-3 C-1 C-2 C-2 D-1 D-2 E-1 F-I 0

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0 2.1-1 2.1-2 3.1 3.2 3.3 3.6 3.8-1 3.8-2 3.8-3 3.9-1 3.9-2 3.9-3 3.10 3.11 Sampling Locations Map (One Mile Radius)

Sampling Locations Map (Ten Mile Radius)

Concentration of Gross Beta in Air Particulate Concentration of Tritium in Drinking Water Concentration of Tritium in Surface Water.

Concentration of Cs-137 in Broadleaf Vegetation Concentration of Co-58 in Fish.

Concentration of Co-60 in Fish.

Concentration of Cs-137 in Fish.

Concentration of Co-58 in Shoreline Sediment Concentration of Co-60 in Shoreline Sediment Concentration of Cs-137 in Shoreline Sediment Direct Gamma Radiation (TLD) Results 2013 Land Use Census Map 2-4 2-5 3-2 3-5 3-7 3-11 3-14 3-15 3-15 3-17 3-18 3-18 3-21 3-24 ii

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0 LIST OF TABLES 2.1-A 2.1-B 2.2-A 2.2-B 2.2-C 3.1-A 3.1-B 3.2 3.3 3.5 3.6 3.7 3.8 3.9 3.10 3.11 4.1-A 4.1-B 5.0-A 5.0-B 5.0-C 5.0-D Radiological Monitoring Program Sampling Locations Radiological Monitoring Program Sampling Locations (TLD Sites)

Reporting Levels for Radioactivity Concentrations in Environmental Samples REMP Analysis Frequency Maximum Values for the Lower Limits of Detection.

Mean Concentration of Gross Beta in Air Particulate.

Mean Concentration of Air Radioiodine (1-13 1).

Mean Concentrations of Radionuclides in Drinking Water Mean Concentrations of Radionuclides in Surface Water Mean Concentration of Radionuclides in Milk Mean Concentration of Radionuclides in Broadleaf Vegetation Mean Concentration of Radionuclides in Food Products Mean Concentrations of Radionuclides in Fish Mean Concentrations of Radionuclides in Shoreline Sediment Direct Gamma Radiation (TLD) Results Land Use Census Results.

Catawba Nuclear Station 2013 Environmental and Effluent Dose Comparison Maximum Individual Dose for 2013 based on Environmental Measurements for Catawba Nuclear Station Duke Energy Interlaboratory Comparison Program Eckert & Ziegler Analytics Cross Check Program Environmental Resource Associates (ERA) Proficiency Testing 2013 Environmental Dosimeter Cross-Check Results.

2-6 2-7 2-8 2-8 2-9 3-3 3-4 3-6 3-8 3-10 3-12 3-13 3-16 3-19 3-22 3-23 4-3 4-5 5-4 5-5 5-7 5-8 LIST OF ACRONYMS USED IN THIS TEXT (in alphabetical order)

BW BiWeekly C

Control CNS Catawba Nuclear Station DHEC Department of Health and Environmental Control ERA Environmental Resource Associates GI-LLI Gastrointestinal - Lower Large Intestine GPS Global Positioning System JSFSI Independent Spent Fuel Storage Installation LLD Lower Limit of Detection M

Monthly MDA Minimum Detectable Activity MOA Memorandum of Agreement mrem Millirem NIST National Institute of Standards and Technology NRC Nuclear Regulatory Commission ODCM Offsite Dose Calculation Manual pCi/kg picocurie per kilogram pCi/l picocurie per liter pCi/m3 picocurie per cubic meter PIP Problem Investigation Program Q

Quarterly REMP Radiological Environmental Monitoring Program SA Semiannually SLCs Selected Licensee Commitments SM Semimonthly TECH SPECs Technical Specifications TLD Thermoluminescent Dosimeter gtCi/ml microcurie per milliliter UFSAR Updated Final Safety Analysis Report W

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1.0 EXECUTIVE

SUMMARY

This Annual Radiological Environmental Operating Report describes the Catawba Nuclear

Station Radiological Environmental Monitoring Program (REMP), and the program results

for the calendar year 2013.

Included are the identification of sampling locations, descriptions of environmental sampling 0and analysis procedures, comparisons of present environmental radioactivity levels and pre-0operational environmental data, comparisons of doses calculated from environmental measurements and effluent data, analysis of trends in environmental radiological data as 0potentially affected by station operations, and a summary of environmental radiological 0sampling results. Quality assurance practices, sampling deviations, unavailable samples, and program changes are also discussed.

0Sampling activities were conducted as prescribed by Selected Licensee Commitments

(SLCs).

Nine-hundred thirty-four samples were analyzed comprising 960 test results in order to compile data for the 2013 report. Based on the annual land use census, the current number of sampling sites for Catawba Nuclear Station is sufficient.

0 Concentrations observed in the environment in 2013 for station related radionuclides were generally within the ranges of concentrations observed in the past. Inspection of data showed that radioactivity concentrations in fish are higher due to surface water tritium levels than the 0activities reported for samples collected prior to the operation of the station. Measured concentrations were not higher than expected and all positively identified measurements attributable to station operation were within limits as specified in SLCs.

Additionally, environmental radiological monitoring data is consistent with effluents 0introduced into the environment by plant operations. The total body dose estimated to the maximum exposed member of the public as calculated by environmental sampling data,

excluding TLD results, was 1.63E-02 mrem for 2013. Background radiation dose in the

United States is approximately 620 mrem per year (approximately half from naturally occurring sources such as radon and half from man-made sources such as medical processes)

(reference 6.13). It is therefore concluded that station operations has had no significant

radiological impact on the health and safety of the public or the environment.

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2.0 INTRODUCTION

2.1 SITE DESCRIPTION AND SAMPLE LOCATIONS 0Duke Energy Corporation's Catawba Nuclear Station is a two-unit facility located on the shore

of Lake Wylie in York County, South Carolina. Each of the two essentially identical units employs a pressurized water reactor nuclear steam supply system furnished by Westinghouse

Electric Corporation. Each generating unit is designed to produce a net electrical output of approximately 1145 MWe. Units 1 and 2 achieved initial criticality on January 7, 1985, and

May 8, 1986, respectively.

Condenser cooling is accomplished utilizing a closed system incorporating cooling towers, instead of using lake water directly. Liquid effluents are released into Lake Wylie via the station discharge canal and are not accompanied by the large additional dilution water flow associated with "once-through" condenser cooling. This design results in greater radionuclide concentrations in the discharge canal given comparable liquid effluent source terms.

Figures 2.1-1 and 2.1-2 are maps depicting the Thermoluminescent Dosimeter (TLD) 0monitoring locations and the sampling locations. The location numbers shown on these maps

correspond to those listed in Tables 2.1-A and 2.1-B.

Figure 2.1-1 comprises all sample

locations within a one mile radius of CNS. Figure 2.1-2 comprises all sample locations within a 10 mile radius of CNS.

2.2 SCOPE AND REQUIREMENTS OF THE REMP 0An environmental monitoring program has been in effect at Catawba Nuclear Station since

1981, four years prior to operation of Unit 1 in 1985. The preoperational program provides

data on the existing environmental radioactivity levels for the site and vicinity which may be used to determine whether increases in environmental levels are attributable to the station. The operational program provides surveillance and backup support of detailed effluent monitoring 0which is necessary to evaluate the significance, if any, of the contributions to the existing 5environmental radioactivity levels that result from station operation.

This monitoring program is based on NRC guidance as reflected in the Selected Licensee SCommitments Manual, with regard to sample media, sampling locations, sampling frequency and analytical sensitivity requirements. Indicator and control locations were established for comparison purposes to distinguish radioactivity of station origin from natural or other "man-made" environmental radioactivity. The environmental monitoring program also verifies Sprojected and anticipated radionuclide concentrations in the environment and related exposures 0from releases of radionuclides from Catawba Nuclear Station. This program satisfies the requirements of Section IV.B.2 of Appendix I to 1 OCFR50 and provides surveillance of all appropriate critical exposure pathways to man and protects vital interests of the company, public and state and federal agencies concerned with the environment. Reporting levels for 0

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activity found in environmental samples are listed in Table 2.2-A. Table 2.2-B lists the REMP analysis and frequency schedule.

The Annual Land Use Census, required by Selected Licensee Commitments, is performed to ensure that changes in the use of areas at or beyond the site boundary are identified and that modifications to the REMP are made if required by changes in land use. This census satisfies the requirements of Section IV.B.3 of Appendix I to 1 OCFR50. Results are shown in Table 3.11.

Participation in an interlaboratory comparison program as required by Selected Licensee Commitments provides for independent checks on the precision and accuracy of measurements of radioactive material in REMP sample matrices. Such checks are performed as part of the quality assurance program for environmental monitoring in order to demonstrate that the results are valid for the purposes of Section IV.B.2 of Appendix I to 10CFR50. A summary of the results obtained as part of this comparison program are in Section 5 of this annual report.

2.3 STATISTICAL AND CALCULATIONAL METHODOLOGY 2.3.1 ESTIMATION OF THE MEAN VALUE There was one (1) basic statistical calculation performed on the raw data resulting from the environmental sample analysis program.

The calculation involved the determination of the mean value for the indicator and the control samples for each sample medium. The mean is a widely used statistic. This value was used in the reduction of the data generated by the sampling and analysis of the various media in the Radiological Environmental Monitoring Program. "Net activity (or concentration)" is the activity (or concentration) determined to be present in the sample. No "Minimum Detectable Activity", "Lower Limit of Detection", "Less Than Level", or negative activities or concentrations are included in the calculation of the mean. The following equation was used to estimate the mean (reference 6.8):

N

= Exi X

i=1 N

Where:

x = estimate of the mean, i = individual sample, N = total number of samples with a net activity (or concentration),

Xj = net activity (or concentration) for sample i.

Section 2 - Page 2

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0 2.3.2 LOWER LEVEL OF DETECTION AND MINIMUM 0DETECTABLE ACTIVITY

The Lower Level of Detection (LLD), and Minimum Detectable Activity (MDA) are

used throughout the REMP.

LLD

- The LLD, as defined in the Selected Licensee Commitments Manual is the smallest concentration of radioactive material in a sample that will yield a net count,

above the system background, that will be detected with 95% probability with only 5%

probability of falsely concluding that a blank observation represents a "real" signal.

The LLD is an a priori lower limit of detection. The actual LLD is dependent upon the

standard deviation of the background counting rate, the counting efficiency, the sample size (mass or volume), the radiochemical yield and the radioactive decay of the sample

between sample collection and counting.

The "required" LLDs for each sample medium and selected radionuclides are given in the Selected Licensee Commitments

and are listed in Table 2.2-C.

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MDA

- The MDA is the net counting rate (sample after subtraction of background) that must be surpassed before a sample is considered to contain a scientifically measurable amount of a radioactive material exceeding background amounts.

The MDA is 0calculated using a sample background and may be thought of as an "actual" LLD for a particular sample measurement.

0 2.3.3 TREND IDENTIFICATION 0One of the purposes of an environmental monitoring program is to determine if there is a buildup of radionuclides in the environment due to the operation of the nuclear station.

Visual inspection of tabular or graphical presentations of data (including preoperational) is used to determine if a trend exists.

A decrease in a particular radionuclide's concentration in an environmental medium does not indicate that reactor operations are removing radioactivity from the environment but that reactor operations are not adding that radionuclide to the environment in quantities exceeding the preoperational level and that the normal removal processes (radioactive decay, 0deposition, resuspension, etc.) are influencing the concentration.

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Substantial increases or decreases in the amount of a particular radionuclide's release from the nuclear plant will greatly affect the resulting environmental levels; therefore, a knowledge of the release of a radionuclide from the nuclear plant is necessary to 0completely interpret the trends, or lack of trends, determined from the environmental data. Factors that may affect environmental levels of radionuclides include prevailing

weather conditions (periods of drought, solar cycles or heavier than normal precipitation), construction in or around either the nuclear plant or the sampling 0location, and addition or deletion of other sources of radioactive materials (such as the 0Chernobyl accident). Some of these factors may be obvious while others are sometimes

unknown.

Therefore, how trends are identified will include some judgment by plant personnel.

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Figure 2.1-1 Catawba Nuclear Station Sampling Locations Map (One Mile Radius)

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TLD Locations A

All Other Locations

/N,./ CNSRailroads CNSRoads U-States r*

Counties NHDWaterbody Approximate location of features shown 0

0.25 0.5j Miles Projection NCSP NAD27 Section 2 - Page 4

Figure 2.1-2 Catawba Nuclear Station Sampling Locations Map (Ten Mile Radius)

Legend TLDLocations All Other Locations

/\\/

CNS_Railroads NavteqHwys

--7--States L7 Counties NHDWaterbody Incorporated Areas Approximate location of features shown N

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TABLE 2.1-A CATAWBA RADIOLOGICAL MONITORING PROGRAM SAMPLING LOCATIONS 00 0

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Week].

SM Semimonthly BW BiWeekly Q

Quarterly M

Monthly SA Semiannually C

Control I

Indicator Site Measure Location De t

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Surface Drinking Shoreline Food Fish Milk Broad Ground Type escription Water Water Sediment Products Leaf Water

Type Pat.

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Veg. (b) 200 I

Site Boundary (0.63 mi NNE)

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201 1

Site Boundary (0.53 mi NE)

W M

205 1

Site Boundary (0.25 mi SW)

W 208 1

Discharge Canal (0.45 mi S)

M SA SA 210 1

Ebenezer Access (2.31 mi SE)

SA 211 1

Wylie Dam (4.06 mi ESE)

M 212 1

Tega Cay (3.32 mi E)

W 214 1

Rock Hill Water Supply (7.30 ni SSE)

M 215 C

River Pointe - Hwy 49 (4.21 mi NNE)

M SA 216 C

Hwy 49 Bridge (4.19 mi NNE)

SA 218 C

Belmont Water Supply (13.5 mi NNE)

M 221 C

Dairy (14.5 mi NW)

SM 222 i

Site Boundary (0.70 mi N)

M 226 1

Site Boundary (0.48 mi S)

M 254 1

Residence (0.82 imi N) 258 C

Fairhope Road (9.84 mi W)

W M

260 I

Irrigated Gardens (2.00 mi SSE)

M(a)

(a) During Harvest Season (b) When Available

GPS data reflect approximate accuracy to within 2-5 meters. GPS field measurements were taken as close as possible to the item of interest.

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TABLE 2.1-B CATAWBA RADIOLOGICAL MONITORING PROGRAM SAMPLING LOCATIONS (TLD SITES)

Table 2.1-B3 Codes IR Inner Ring OR Outer Ring C

Control SI Special Interest 00 0

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Distance Sector Site Measure Location*

Distance Sector Type (miles)

Type (miles) 200 IR SITE BOUNDARY 0.63 NNE 234 OR WELLS FARGO BANK 4.50 E

201 IR SITE BOUNDARY 0.53 NE 235 OR LAKE WYLIE DAM 4.07 ESE SC WILDLIFE 203 IR SITE BOUNDARY 0.38 ESE 236 OR FEDERATION OFFICE 4.25 SE TWIN LAKES ROAD AND 204 IR SITE BOUNDARY 0.48 SSW 237 OR HOMESTEAD ROAD 4.75 SSE PENNINGTON ROAD 205 IR SITE BOUNDARY 0.25 SW 238 OR AND WEST OAK ROAD 4.02 S

CARTER LUMBER 206 IR SITE BOUNDARY 0.67 WNW 239 OR COMPANY 4.49 SSW 207 IR SITE BOUNDARY 0.95 NNW 240 OR PARAHAM ROAD 4.07 SW 212 SI TEGA CAY AIR SITE 3.32 E

241 OR CAMPBELL ROAD 4.58 WSW OLD ROCK HILL TRANSMISSION TOWER 217 C

AIR SITE 10.3 SSE 242 OR ON PARAHAM ROAD 4.56 W

222 IR SITE BOUNDARY 0.71 N

243 OR KINGSBURRY ROAD 4.39 WNW BETHEL 223 IR SITE BOUNDARY 0.57 E

244 OR ELEMENTARY SCHOOL 4.02 NW CRO WDERS CREEK 225 IR SITE BOUNDARY 0.68 SE 245 OR BOAT LANDING 4.01 NNW CAROWINDS 226 IR SITE BOUNDARY 0.48 S

246 SI GUARD HOUSE 7.87 ENE 227 IR SITE BOUNDARY 0.52 WSW 247 C

FORT MILL 7.33 ESE PIEDMONT 228 IR SITE BOUNDARY 0.61 W

248 SI MEDICAL CENTER 6.54 S

YORK COUNTY 229 IR SITE BOUNDARY 0.84 NW 249 SI OPERATIONS CENTER 7.17 S

RIVER HILLS YORK 230 OR CHURCH 4.37 N

250 SI DUKE ENERGY OFFICE 10.4 WSW RIVER HILLS 231 OR FRONT ENTRANCE 4.21 NNE 251 C

CLOVER 9.72 WNW PLEASANT HILL 232 OR ROAD 4.18 NE 255 IR SITE BOUNDARY 0.61 ENE ZOAR ROAD AND 233 OR THOMAS DRIVE 3.95 ENE 256 IR SITE BOUNDARY 0.58 SSE 258 S1 FAIRHOPE ROAD 9.84 W

GPS data reflect approximate accuracy to within 2-5 meters. GPS field measurements were taken as close as possible to the item of interest.

Section 2 - Page 7

TABLE 2.2-A REPORTING LEVELS FOR RADIOACTIVITY CONCENTRATIONS IN ENVIRONMENTAL SAMPLES Analysis Water Air Particulates Fish Milk Food Products (pCi/liter) or Gases (pCi/kg-wet)

(pCi/liter)

(pCi/kg-wet)

(pCi/m3)

H-3 20,000(a)(b)"

Mn-54 1,000 30,000 Fe-59 400 10,000 Co-58 1,000 30,000 Co-60 300 10,000 Zn-65 300 20,000 Zr-Nb-95 400 1-131 2

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100 Cs-134 30 10 1,000 60 1,000 Cs-137 50 20 2,000 70 2,000 Ba-La-140 200 300 66 6

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(a) If no drinking water pathway exists, a value of 30,000 pCi/liter may be used.

(b) H-3 Reporting level not applicable to surface water TABLE 2.2-B REMP ANALYSIS FREQUENCY Sample Analysis Gamma Tritium Low Gross TLD Medium Schedule Isotopic Level Beta 1-131 Air Radioiodine Weekly X

Air Particulate Weekly X

X Quarterly Composite X

Direct Radiation Quarterly X

Surface Monthly Composite X

Water Quarterly Composite X

Drinking Monthly Composite X

(a)

X Water Quarterly Composite X

Ground Water Quarterly X

X Shoreline Sediment Semiannually X

Milk Semimonthly X

X Fish Semiannually X

Broadleaf Vegetation Monthly(b)

X Food Products Monthly""

X (a) Low-level 1-131 analysis will be performed if the dose calculated for the consumption of drinking water is

> 1 mrem per year. An LLD of I pCi/liter will be required for this analysis.

(b) When Available 60 6

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Particulates or (pCi/kg-wet)

(pCi/liter)

(pCi/kg-wet)

(pCi/kg-dry)

Gases (pCi/mr3)

Gross Beta 4

0.01 H-3 2000 lal Mn-54 15 130 Fe-59 30 260 Co-58, 60 15 130 Zn-65 30 260 Zr-Nb-95 15 1-131 1(b) 0.07 1

60 Cs-134 15 0.05 130 15 60 150 Cs-137 18 0.06 150 18 80 180 Ba-La-140 15 15 (a) If no drinking water pathway exists, a value of 3000 pCi/liter may be used.

(b) If no drinking water pathway exists, the LLD of gamma isotopic analysis may be used.

Section 2 - Page 9

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3.0 INTERPRETATION OF RESULTS S

Review of all 2013 REMP analysis results was performed to identify changes in environmental levels as a result of station operations. The following section depicts and explains the review of these results. Sample data for 2013 was compared to preoperational and historical data. Over the years of operation, analysis and collection changes have taken

place that do not allow direct comparisons for some data collected from 1984 (preoperational) through 2013.

Summary tables containing 2013 information required by Technical

Specification Administrative Control 5.6.2 are located in Appendix B.

0Evaluation for significant trends was performed for radionuclides that are listed as required

within Selected Licensee Commitments 16.11-13. The radionuclides include: H-3, Mn-54,

Fe-59, Co-58, Co-60, Zn-65, Zr-95, Nb-95, 1-131, Cs-134, Cs-137, Ba-140 and La-140.

Gross beta analysis results were trended for drinking water and gross beta trending for air

particulates was initiated in 1996. Other radionuclides detected that are the result of plant operation, but not required for reporting, are trended.

A comparison of annual mean concentrations of effluent-based detected radionuclides to 0historical results provided trending bases. Frequency of detection and concentrations related

to SLC reporting levels (Table 2.2-A) were used as criteria for trending conclusions. All 2013 maximum percentages of reporting levels attributed to CNS operation were well below the 100% action level.

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Selected Licensee Commitment section 16.11-13 addresses actions to be taken if radionuclides other than those required are detected in samples collected. The occurrences of these radionuclides are the result of CNS liquid effluents which contained the radionuclides.

During 1984-1986, all net activity results (sample minus background), both positive and negative were included in calculation of sample mean. A change in the EnRad gamma spectroscopy system on September 1, 1987, decreased the number of measurements yielding

detectable low-level activity for indicator and control location samples. It was thought that Sthe method used by the previous system was vulnerable to false-positive results.

S All 2013 sample analysis results were reviewed to detect and identify any significant trends.

Tables and graphs are used throughout this section to display data from effluent-based

radionuclides identified since the system change in late 1987. All negative concentration 5values were replaced with zero for calculation purposes. Any zero concentrations used in tables or graphs represent activity measurements less than detectable levels.

SReview of all 2013 data presented in this section supports the conclusion that there were no 5significant changes in environmental sample radionuclide concentrations of samples collected and analyzed from CNS site and surrounding areas that were attributable to plant operations.

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3.1 AIRBORNE RADIOIODINE AND PARTICULATES In 2013, 260 radioiodine and particulate samples were analyzed, 208 from four indicator locations and 52 at the control location. Particulate samples were analyzed weekly for gross beta. A quarterly gamma analysis was performed on the quarterly filter composite (by location).

Radioiodine samples received a weekly gamma analysis.

Figure 3.1 shows individual sample gross beta results for the indicator location with highest annual mean and the control location samples during 2013. The two sample locations' results are similar in concentration and have varied negligibly since preoperational periods.

There were no detectable gamma emitters identified for particulate filters analyzed during 2013. Table 3.1-A shows the highest indicator annual mean and control location annual mean for gross beta in air particulate.

There was no detectable 1-131 in air radioiodine samples analyzed in 2013. Table 3.1-B shows the highest indicator annual mean and control location annual mean for 1-131 since 1984 (preoperational period). The table shows similar concentrations for both the indicator and control locations and the activities decreasing from early in the operational history of the plant. No 1-131 activity due to CNS plant operations has been detected since 1987.

K-40 and Be-7 that occur naturally were routinely detected in charcoal cartridges collected during the year.

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0 1.00E 9.OOE-02 8.OOE-02 7.OOE-02 6.OOE-02 5.00E-02 4.00E-02 3.O0E-02 2.OOE-02 1.00E-02 Concentration of Gross Beta in Air Particulate O.OOE+00 1984 1987 1990 1993 1996 1999 2002 2005 2008 2011 Indicator Location Control Location Th ere is no reporting level for gross beta in air particulate Section 3 - Page 2

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Table 3.1-A Mean Concentration of Gross Beta in Air Particulate 0

Year Indicator Location (pCi/m)

Control Location (Ci/m 3) 0 1984 2.25E-2 1.82E-2 1985 2.12E-2 1.53E-2 1986 3.62E-2 3.41E-2 1987 2.67E-2 2.32E-2 1988 2.29E-2 2.30E-2 1989 2.11E-2 2.13E-2 1990 2.39E-2 2.72E-2 1991 2.19E-2 2.51E-2 1992 1.90E-2 2.01E-2 1993 1.87E-2 1.94E-2 1994 2.03E-2 2.03E-2 1995 4.88E-2 3.23E-2 1996 3.49E-2 2.60E-2 1997 2.83E-2 2.28E-2 1998 2.69E-2 2.12E-2 1999 2.53E-2 2.04E-2 2000 2.28E-2 1.86E-2 2001 1.76E-2 1.78E-2 2002 1.60E-2 1.57E-2 2003 1.54E-2 1.42E-2 2004 1.65E-2 1.49E-2 2005 1.66E-2 168E-2 2006 1.74E-2 1.74E-2 2007 1.88E-2 1.86E-2 2008 1.80E-2 1.90E-2 2009 1.78E-2 1.72E-2 2010 2.03E-2 1.90E-2 2011 1.98E-2 1.92E-2 2012 2.09E-2 1.97E-2 Average (2003 - 2012) 1.82E-2 1.76E-2 2013 1.92E-2 1.82E-2 00 0

0 0

0 Section 3 -Page 3 0

0

Table 3.1-B Mean Concentration of Air Radioiodine (1-131)

Year Indicator Location (pCi/m3)

Control Location (pCi/m3) 1984 1.30E-3 1.46E-2 1985 4.75E-3 2.38E-2 1986 1.43E-2 1.02E-2 1987 1.38E-2 O.OOEO 1988 0.OOEO O.OOEO 1989 0.00E0 0.00E0 1990 0.00E0 0.00E0 1991 O.OOEO 0.00E0 1992 O.OOEO O.OOEO 1993 0.00E0 0.OOEO 1994 0.00E0 0.00E0 1995 0.00E0 0.00E0 1996 0.00E0 0.00E0 1997 0.00E0 0.00E0 1998 0.00E0 0.OOEO 1999 O.OOEO O.OOEO 2000 0.OOEO 0.00E0 2001 0.OOEO 0.OOEO 2002 0.OOEO 0.OOEO 2003 0.OOEO 0.00E0 2004 O.OOEO O.OOEO 2005 0.OOEO 0.00E0 2006 0.OOEO 0.003E0 2007 0.00E0 0.00E0 2008 0.OOEO 0.OOEO 2009 0.OOEO 0.OOEO 2010 0.OOEO 0.OOEO 2011 5.53E-2 5.65E-2 2012 0.OOEO 0.OOEO 2013 0.OOEO 0.OOEO 0.00E0= no detectable measurements 2011 concentration affected by Fukushina Daiichi S0 0

0 0

0 Section 3-Page 4 0

0 0

00 0

0 S

0 0

0 S

S 0

0 S

S 0

0 0

3.2 DRINKING WATER Gross beta and gamma spectroscopy were performed on 26 drinking water samples. The samples were composited to create 8 quarterly samples that were analyzed for tritium. One indicator location was sampled, along with one control location.

No gamma emitting radionuclides were identified in 2013 drinking water samples. There have been no gamma emitting radionuclides identified in drinking water samples since 1988.

Table 3.2 shows highest annual mean gross beta concentrations for the indicator location and control location since preoperation. The indicator location (downstream of the plant effluent release point) average concentration was 1.79 pCi/I in 2013 and the control location concentration was 1.59 pCi/l. The 2012 indicator mean was 1.89 pCi/l. The table shows that current gross beta levels are not statistically different from preoperational concentrations.

Tritium was detected in the four indicator samples and in two of the four control samples during 2013. The mean indicator tritium concentration for 2013 was 622 pCi/1, 3.11% of reporting level. The mean control tritium concentration for 2013 was 664 pCi/1, 3.32% of reporting level. Figure 3.2 and Table 3.2 display the highest indicator and control location annual mean concentrations for tritium since 1984.

The concentration of tritium in drinking water is affected by releases from the Catawba plant and the McGuire Nuclear Station, located approximately 40 miles upstream of the Catawba plant on the Catawba River.

The dose for consumption of water was less than one mrem per year, historically and for 2013; therefore low-level iodine analysis is not required.

Figure 3.2 pCi/liter 5000 4500 4000 3500 3000 2500 2000 1500 1000 Concentration of Tritium in Drinking Water 1999 2002 2005 2008 2011 1984 1987 1990 I

1993 1996 Indicator Location Control Location 20% Reporting Level I

Section 3 - Page 5

Table 3.2 Mean Concentration of Radionuclides in Drinking Water Gross Beta (pCi/1)

Tritium (pCi/l)

YEAR Indicator Control Indicator Control Location Location Location Location 1984 4.72 1.83 3.1OE-2 3.1OE-2 1985 2.70 2.24 4.13E2 4.00E2 1986 3.11 2.26 7.23E2 7.33E2 1987 3.10 2.40 7.80E2 4.80E2 1988 3.60 2.60 6.64E2 0.OOEO 1989 3.60 2.90 8.91 E2 5.72E2 1990 4.50 3.20 7.03E2 O.00E0 1991 3.70 2.20 7.04E2 0.00E0 1992 3.20 2.40 7.65E2 5.38E2 1993 3.50 2.50 7.06E2 0.OOEO 1994 3.30 2.70 O.OOEO 0.OOEO 1995 4.80 4.50 4.28E2 2.21 E2 1996 3.08 3.14 3.71E2 3.27E2 1997 3.74 3.15 3.54E2 2.28E2 1998 2.51 2.44 5.07E2 1.83E2 1999 3.55 2.48 6.71E2 2.70E2 2000 3.04 2.27 5.87E2 3.26E2 2001 3.49 2.30 8.66E2 4.50E2 2002 3.44 2.36 1.22E3 4.11 E2 2003 2.27 2.02 6.36E2 2.88E2 2004 1.88 1.69 5.47E2 2.54E2 2005 2.05 1.84 7.69E2 4.50E2 2006 2.30 2.17 1.59E3 7.70E2 2007 2.34 2.21 1.65E3 9.18E2 2008 2.81 2.16 1.25E3 9.16E2 2009 2.07 1.99 6.34E2 6.81 E2 2010 1.84 1.80 7.05E2 4.27E2 2011 2.01 1.71 9.73E2 6.36E2 2012 1.89 1.84 9.54E2 5.02E2 2013 1.79 1.59 6.22E2 6.64E2 O.OOEO no detectable measurements 1984 - 1986 mean based on all net activity 00 0

0 0

S 0

00 0

0 0

S 0

0 0

0 Secton3-age60 0

0

0S 0

0 0

3.3 SURFACE WATER A total of 39 monthly surface water samples were analyzed for gamma emitting radionuclides.

The samples were composited to create 12 quarterly samples for tritium analysis.

Two indicator locations and one control location were sampled.

One indicator location (208) is located near the liquid effluent discharge point.

All 2013 indicator location samples contained tritium with an average concentration of 4,618 pCi/l. Indicator Location 208 (Discharge Canal) showed a range of activities from 4,490 to 14,800 pCi/I which had the highest mean concentration of 8,615 pCi/l. Tritium was detected in three of the four control samples during 2013 with an average concentration of 402 pCi/l.

No gamma emitting radionuclides were identified in 2013 surface water samples. Table 3.3 summarizes the indicator annual means of radionuclides detected since the change in the gamma spectroscopy analysis system in 1987. Visual inspection of the tabular data did not reveal any increasing trends.

Figure 3.3 displays the highest indicator and control annual means for tritium since 1984.

Table 3.3 lists the highest indicator annual means.

The concentration of tritium in surface water is affected by releases from the Catawba plant and the McGuire Nuclear Station, located approximately 40 miles upstream of the Catawba plant on the Catawba River.

Figure 3.3 pCi/liter Concentration of Tritium in Surface Water 40000 35000 30000 25000 20000 15000 10000 1984 1987 1990 1993 1996 1999 2002 20'a5 2008 2011 I

-A-Indicator Location Control Location There is no reporting level for tritium in surface water, however, ifno drinking water pathway exists, a value of30,OOO pCi/l may be used. A drinking water pathway exists for Catawba Nuclear Station, so this limit does not apply for surface water. See section 3.2for drinking water results.

Section 3 - Page 7

Table 3.3 Mean Concentrations of Radionuclides in Surface Water (pCi/l)

YEAR Co-58 Co-60 Nb-95 Cs-137 H-3 Indicator H-3 Control 1984 4.59E-1 5.71E-1 6.48E-1 9.08E-1 3.35E2 3.18E2 1985 3.46E0 4.83E-2 2.70E0 8.19E-1 1.19E3 5.05E2 1986 3.1OE-1

-4.12E-2 2.05E0 4.85E-1 2.34E3 5.05E2 1987 0.OOEO 3.1OEO 4.30E0 9.90E0 4.17E3 6.20E2 1988 9.20E0 0.OOEO 0.OOEO 0.OOEO 6.03E3 6.07E2 1989 0.00EO 0.00E0 0.00E0 0.OOEO 5.27E3 0.00E0 0

1990 6.50E0 0.OOEO 0.00E0 0.OOEO 3.98E3 7.73E2 1991 0.OOEO 0.00E0 0.OOEO 0.OOEO 4.87E3 0.OOEO 1992 0.00E0 0,00E0 0.00E0 0.00E0 6.91 E3 6.64E2 0

1993 4.70E0 1.80E0 0.OOEO 0.00E0 5.98E3 0.OOEO 1994 0.00E0 0.00E0 0.00E0 0.00E0 8.42E3 0.00E0 1995 0.00E0 0,00E0 0.00E0 0.00E0 5.13E3 2.89E2 1996 0.00E0 0,00EO 0.00E0 0.00E0 7.36E3 2.61 E2 1997 0.00E0 0.00E0 0.00E0 0.00EO 7.77E3 2.20E2 0

1998 0.00E0 0,00E0 0.00E0 0.00E0 6.61E3 0.00E0 1999 0.00E0 0.00E0 0.00E0 0.00E0 8.13E3 2.41 E2 2000 0.OOEO 0.OOEO O.OOEO 0.OOEO 7.19E3 2.56E2 2001 0,OOEO 0.OOEO 0.OOEO 0.00E0 7.13E3 3.28E2 2002 0.OOEO 0.00E 0 0.OOEO

.OOEO 1.00E4 3.80E2 2003 0.00E0 0.00E0 0.00E0 0.OOEO 1.31E4 2.37E2 2004 0.00E0 0.OOEO 0.OOEO 0.00E0 9.43E3 2.60E2 2005 0.OOEO 0.OOEO 0.OOEO 0.OOEO 1.40E4 3.78E2 2006 0.OOEO 0.OOEO 0.OOEO 0.OOEO 1.67E4 5.83E2 2007 0.OOEO 0.OOEO 0.OOEO 0.OOEO 1.01E4 7.82E2 2008 6.80E0 1.16El 0.OOEO 0.OOEO 6.02E3 6.31 E2 2009 9.40E0 1.06E1 0.OOEO 0.OOEO 3.93E3 5.29E2 2010 0.OOEO 0.OOEO 0.OOEO 0.OOEO 7.26E3 2.94E2 S

2011 8.75E0 1.96E1 0.OOEO 0.OOEO 8.29E3 5.41 E2 2012 0.OOEO 0.OOEO 0.OOEO 0.OOEO 1.21E4 3.71 E2 2013 0.OOEO 0.OOEO 0.OOEO 0.OOEO 8.62E3 4.02E2 0.OOEO = no detectable measurements 1984-1986 mean based on all net activity SS S

S S

S 0

S S

Section 3 -Page 8 5

0 S

0 0

0 3.4 GROUND WATER A total of three ground water samples was collected and analyzed for gamma emitters and tritium. There is one indicator location and no control location.

Naturally occurring K-40 was the only radionuclide identified during 2013. There have been no radionuclides identified in ground water samples since 1988.

Section 3 - Page 9

SS 0

3.5 MILK A total of 25 milk samples was analyzed by gamma spectroscopy and 26 by low level iodine during 2013 (reference 6.16).

There was one control location sampled.

No 0

indicator dairies were identified by the 2013 land use census.

There were no gamma emitting radionuclides due to CNS plant operations identified in milk samples in 2013. Cs-137 is the only radionuclide, other than naturally occurring, reported in milk samples since 1996. Cs-137 in milk is not unusual. It is a constituent of nuclear weapons test fallout and nuclear plant accidents and has been observed periodically in samples from indicator and control locations since the preoperational period. Airborne Cs-137 has not been released from the plant since 1992.

Table 3.5 lists highest indicator location annual mean and control location annual mean for Cs-137 since the preoperational period. K-40 is a naturally occurring radionuclide observed in milk samples in 2013.

Table 3.5 Mean Concentration of Radionueides in Milk YEAR Cs-137 Indicator (pCi/l)

Cs-137 Control (pCi/1) 1984 2.95E0 2.98E0 1985 2.1 IEO 2.12E0 1986 3.76E0 4.54E0 1987 5.OOEO 5.50E0 S

1988 3.20E0 3.80E0 1990 8.00E0 6.70E0 1991 0.00E0 0.OOEO 1992 3.40E0 5.OOEO 1993 5.OOEO 0.OOEO 0

1994 2.80E0 0.00E0 1995 8.60E0 0.00E0 1996 6.05E0 0.00E0 2001 0.OOEO 0.OOEO 2002 0.OOEO 0.OOEO 2003 0.OOEO 0.OOEO 2004 NO INDICATOR LOCATION 0.00E0 2005 NO INDICATOR LOCATION 0.00E0 2006 NO INDICATOR LOCATION 0.0OEO 2007 NO INDICATOR LOCATION 0.OOEO 2008 NO INDICATOR LOCATION 0.OOEO 2009 NO INDICATOR LOCATION O.OOEO 2010 NO INDICATOR LOCATION 0.OOEo 2011 NO INDICATOR LOCATION 0.OOEO 2012 NO INDICATOR LOCATION 0.OOEO 2013 NO INDICATOR LOCATION 0.OOEO 0.OOEO = no detectable measurements 1984 - 1986 mean based on all net activity 0

S0 Section 3 -Page 10 0

0

00 0

0 0

0 S

0 0

3.6 BROADLEAF VEGETATION Gamma spectroscopy was performed on 60 broadleaf vegetation samples during 2013.

Four indicator locations and one control location were sampled. There were no gamma emitting radionuclides identified in vegetation samples during 2013.

Cs-137 is the only radionuclide, other than naturally occurring, reported in vegetation samples since the change in gamma spectroscopy analysis systems in 1987. It is not unusual for Cs-137 to be present in vegetation. It is a constituent of nuclear weapons test fallout and nuclear plant accidents and has been observed in samples from indicator and control locations since the preoperational period. Table 3.6 lists the highest indicator location annual mean and control location annual mean for Cs-137 since early in the station's operational history. Visual inspection of the tabular data did not reveal any increasing trends.

S 0

0 0

Figure 3.6 shows indicator and control annual means for Cs-137 in vegetation since 1984.

Values shown from 1984 to 2013 show a stable trend for Cs-137 in vegetation. No airborne Cs-137 has been released from the plant since 1992.

K-40 and Be-7 are naturally occurring radionuclides that were observed in broadleaf vegetation samples in 2013.

Figure 3.6 pCi/kg 1200 1000 800 600 400 200 1984 Concentration of Cs-137 in Broadleaf Vegetation I -

I -

1987 1990 1993 1996 1999 2002 rnt,~

W w

W W W -

W W 2005 2008 2011 I

Indicator Location Control Location

-50%Reporting Level I

Section 3 - Page 11

SS 0

0 Table 3.6 Mean Concentration of Radionuclides in Broadleaf Vegetation YEAR Cs-137 Indicator (pCi/kg)

Cs-137 Control (pCi/kg) 1984 3.76E1 1.30El 1985 5.48E1 4.16E1 1986 7.42EI 2.22EI 1987 6.10El 5.10El 1988 9.10E1 7.40E1 1989 1.00E2 4.80E1 1990 7.70E1 5.80E1 1991 1.98E2 8.60E1 1992 9.70E1 0.00E0 1993 1.13E2 3.20E1 1994 7.OOEl 0.00E0 1995 3.60E1 0.OOEO 1996 2.23E2 6.22E1 1997 7.57E1 0.OOEO 1998 6.53E1 0.OOEO 1999 1.08E2 0.00E0 2000 1.04E2 0.OOEO 2001 3.76E1 0.00E0 2002 7.02E1 0.00E0 2003 4.96E1 2.40E1 2004 5.45E1 0.00E0 2005 5.48E1 0.00E0 2006 5.79E1 0.00E0 2007 6.31E1 0.00E0 2008 4.44E1 0.00E0 2009 4.25E1 0.00E0 2010 3.77E1 0.OOEO 2011 2.62E1 0.OOEO 2012 O.OOEO O.OOEO 2012 0.00E0 0.00E0 2013 0.OOEO 0.OOEO O.OOEO = no detectable measurements 1984 - 1986 mean based on all net activity 2011 concentration affected by Fukushima Dalichi SS 0

0 0

S 0

0 0

0 Section 3 -Page 12 5

0 0

0 3.7 FOOD PRODUCTS Collection of food product samples (crops) from an irrigated garden began in 1989. The irrigated garden is located on Lake Wylie downstream from CNS, Location 260. During 0the 2013 growing season, ten samples were collected and analyzed for gamma radionuclides. There is no control location for this media type.

0Table 3.7 shows Cs-137 indicator location highest annual mean concentrations since

1989.

S K-40 and Be-7 are naturally occurring radionuclides that were observed in food product samples in 2013.

Table 3.7 Mean Concentration of Radionuclides in Food Products YEAR Cs-137 Indicator (pCi/kg) 1989 0.00E0 1990 0.00E0 1991 0.OOEO 1992 0.00E0 1993 2.50E1 1994 0.OOEO 1995 0.OOEO 1996 0.OOEO 1997 0.OOEO 1998 0.OOEO 1999 0.OOEO 2000 0.OOEO 2001 0.OOEO 2002 0.00E0 2003 0.OOEO 2004 0.OOEO 2005 0.OOEO 2006 0.OOEO 2007 0.OOEO 2008 0.OOEO 2009 0.OOEO 2010 0.OOEO 2011 0.OOEO 2012 0.OOEO 2013 0.OOEO 0

O.OOEO = no detectable measurements There is no control location for Food Products.

00 0

0 0

0 O

~Section 3 -Page 13 0

0

3.8 FISH Gamma spectroscopy was performed on 12 fish samples collected during 2013. One downstream indicator location and one control location were sampled.

Co-58, Co-60, and Cs-137 are normally the predominant radionuclides identified in fish samples.

There were no gamma emitting radionuclides identified in any indicator location or control location fish samples during 2013.

Figures 3.8-1, 3.8-2, and 3.8-3 are graphs displaying annual mean concentrations for Co-58, Co-60, and Cs-137. Table 3.8 depicts the highest indicator location annual mean for radionuclides detected.

In addition, radionuclides identified in fish samples since 1988 have been included in the table. Overall, radionuclides have not shown a significant trend or accumulation.

K-40 was observed in some fish samples collected during 2013.

Figure 3.8-1 pCi/kg Concentration of Co-58 in Fish 2000 1800 1600 1400 1200 1000 800 600 400 200 0

S 0

S S

0 S

S S

S 0

S S

1984 1987 1990 1993 1996 1999 2002 2005 2008 S

Indicator Location Control Location 5% Reporting Level 2011 Section 3 - Page 14

00 0

0 0

S S

0 0

S 0

0 0

S Figure 3.8-2 pCI/kg 700 600 500 400 300 200 100 1984 Concentration of Co-60 in Fish I

I I

-I

~-m--~ mm-n m-m-~u s mm-u ~. rn-rn--.

1987 1990 1993 1 9 9

2 2

2008 2 0 1 1996 1999 2002 200S 2008 2011

-.1I-Indicator Location Control Location 5%Reporting Level

]

Figure 3.8-3 pCi/kg 600 500 400 300 200 100 1984 Concentration of Cs-137 in Fish S -

S -

1987 1990 1993 1996 1999 2002 I

w 2005 2 0 w -

2008 2011 w

Indicator Location

- Control Location 20% Reporting Level Section 3 - Page 15

Table 3.8 Mean Concentrations of Radionuclides in Fish (pCi/ka)

Year Mn-54 Co-58 Co-60 Cs-134 Cs-137 Nb-95 Fe-59 Sb-122 Sb-125 1984 3.07E0 3.OOEO 6.11E-1

-5.32E0 1.83E0 O.OOEO 0.OOEO 0.OOEO 0.OOEO 1985 7.68E-1 3.40E1 9.11EO 3.22E0 1.28E1 5.07E0 O.OOEO 0.OOEO 0.OOEO 1986 2.01EI 1.86E2 4.01El 3.51EI 9.29E1 0.OOEO 7.30E0 O.OOEO 0.OOEO 1987 7.24E0 7.57E1 4.81E1 3.83E0 4.27E1 5.40E0 0.OOEO O.OOEO 0.OOEO 1988 2.85E1 1.40E2 9.70E1 1.67E1 8.24E1 0.OOEO 0.OOEO 0.OOEO 0.OOEO 1989 8.28E0 1.33E2 3.83EI 1.47EI 4.37EI 8.58E-I 0.00E0 0.00E0 0.00E0 1990 2.51E1 1.75E2 7.77E1 1.32E1 4.66E1 3.33E0 0.OOEO 7.00E0 9.25E0 1991 3.15E1 1.46E2 1.29E2 1.03E1 4.60E1 7.90E-1 2.30E0 0.00E0 7.45E0 1992 1.34EI 9.02EI 6.20EI 1.27E1 4.61E1 0.00E0 0.00E0 0.00E0 0.00E0 1993 2.14E1 3.58E2 1.21E2 2.73E0 2.56E1 0.OOEO 0.OOEO 0.00E0 0.00E0 1994 1.91E0 4.75E1 1.81El 0.00E0 1.75E1 0.00E0 0.00E0 0.00E0 1.45E1 1995 5.65E1 8.90E2 2.66E2 0.00E0 6.77E1 1.38E1 0.00E0 0.00E0 0.00E0 1996 0.00E0 5.95E1 6.68E1 0.OOEO 3.02E1 0.00E0 0.00E0 0.00E0 0.00E0 1997 0.00E0 4.93E1 9.88E0 O.OOEO 2.74E1 0.OOEO 0.00E0 0.OOEO 0.OOEO 1998 0.OOEO 6.44EI 2.86EI 0.00E0 1.58E1 0.00E0 0.00E0 0.00E0 0.OOEO 1999 0.OOEO 3.12E1 2.71E1 0.00E0 1.87E1 0.00E0 0.OOEO 0.00E0 0.OOEO 2000 0.OOEO 2.13E2 2.69E2 0.00E0 1.52E1 0.00E0 0.OOEO 0.OOEO 0.OOEO 2001 0.00E0 4.66EI 0.00E0 0.OOEO 2.08E]

0.OOEO 0.00E0 0.00E0 0.00E0 2002 0.OOEO 5.23E1 7.OOE1 0.00E0 1.73E1 0.OOEO 0.OOEO 0.OOEO 0.00E0 2003 0.00E0 1.43E2 2.61E1 0.00E0 1.19El 0.OOEO 0.OOEO 0.00E0 0.OOEO 2004 4.92E1 I.81E1 0.00E0 0.00E0 0.00E0 0.00E0 0.00E0 0.00E0 0.OOEO 2005 0.00E0 0.OOEO 0.00E0 0.00E0 0.00E0 0.OOEO 0.00E0 0.OOEO 0.00E0 2006 0.OOEO 0.OOEO 0.OOEO 0.00E0 1.44E1 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2007 0.OOEO 0.OOEO 0.00E0 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2008 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2009 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2010 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2011 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2.16E1 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2012 0.OOEO 0.OOEO 0.OOEO 0.OOEO 1.84E1 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2013 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO O.OOEO

= no detectable measterements 0

0 0

Section 3 -Page 16 0

S 0

0 0

0 3.9 SHORELINE SEDIMENT During 2013, a total of 6 shoreline sediment samples was analyzed, four from two indicator locations and two from the control location.

Co-58, Co-60, and Cs-137 are normally the predominant radionuclides identified shoreline sediment samples. There were no gamma emitting radionuclides identified any indicator location or control location shoreline sediment samples during 2013.

in in 0

0 0

S 0

0 S

Table 3.9 lists highest indicator location annual mean since 1984. Included in the table are radionuclides that have been identified in shoreline sediment samples since 1988.

Figures 3.9-1, 3.9-2, and 3.9-3 are graphs displaying annual mean concentrations for Co-58, Co-60, and Cs-137.

Naturally occurring K-40 was observed in some shoreline sediment samples collected during 2013.

Figure 3.9-1 pCi/kg 2000 1800 1600 1400 I

1200 1000 800 600 400 200 0

l Concentration of Co-58 in Shoreline Sediment 1984 1987 1990 1993 1996 1999 2002 2005 2008 2011 1

Indicator Location Control Location There is no reporting level for Co-58 in Shoreline Sediment Section 3 - Page 17

Figure 3.9-2 pCi/kg 2000 1800 1600 1400 1200 1000 800 600 400 200 0

1984 1987 Concentration of Co-60 in Shoreline Sediment V/J

ýw -ý-- -

1990 w

v 1993 w

1996 w

w 1 99 w200 1999 2002 2005 2008 2011

-5M-Indicator Location Control Location There is no reporting level for Co-60 in Shoreline Sediment Figure 3.9-3 0

0 0

S 0

0 0

S S

pCi/kg 500 450 400 350 300 250 200 150 100 50 0 '

191 Concentration of Cs-137 in Shoreline Sediment 1987 1990 847.

1993 1996 1999 2002 2005 2008 2011 I- - Indicator Location Control Location There is no reporting level for Cs-137 in Shoreline Sediment Section 3 - Page 18

Table 3.9 Mean Concentrations of Radionuclides in Shoreline Sediment (pCi/k2)

Year Mn-54 Co-58 Co-60 Nb-95 Zr-95 Cs-134 Cs-137 Co-57 Sb-125 1984 1.03E0 4.40E0

-2.34E0 0.OOEO 0.OOEO 3.19E1 1.07E2 0.OOEO 0.OOEO 1985

-3.12E0 1.16E2 5.18E0 0.OOEO 0.OOEO 2.11E2 2.97E2 0.OOEO 0.OOEO 1986 1.09E2 3.79E2 2.05E2 0.OOEO 3.96E1 6.50E1 1.61E2 0.OOEO 0.OOEO 1987 8.83E1 4.08E2 1.61E2 4.22E1 0.OOEO 6.08E1 1.26E2 0.OOEO 0.OOEO 1988 1.07E2 3.29E2 2.63E2 2.28E1 7.54E0 2.59E1 1.07E2 7.65E-1 3.68E0 1989 4.58E1 1.94E2 1.21E2 5.02E0 0.OOEO 1.65E1 5.77E1 0.OOEO 1.57E1 1990 5.39E1 2.08E2 1.77E2 0.00E0 0.00E0 1.66E1 8.18E1 0.00E0 7.15E0 1991 8.50E1 3.70E2 4.19E2 5.30E0 0.00E0 1.82E1 8.33E1 1.20E0 1.50El 1992 1.17E2 1.13E3 5.80E2 3.50E0 0.00E0 1.69E1 1.07E2 3.00E0 2.70E1 1993 1.33E2 1.07E3 1.04E3 0.00E0 0.00E0 2.80E1 1.26E2 2.47E1 2.16E2 1994 4.93E1 7.98E2 5.73E2 0.00E0 0.00E0 5.67E0 1.07E2 4.38E0 4.60E1 1995 1.02E2 1.33E3 8.65E2 1.13E2 0.00E0 0.OOEO 8.50E1 3.69E1 1.49E2 1996 8.73E1 3.39E2 5.81E2 0.OOEO 0.OOEO 0.00E0 8.30E1 0.OOEO 1.96E2 1997 6.96E1 5.90E2 7.64E2 0.OOEO 0.00E0 0.OOEO 1.43E2 0.00E0 1.76E2 1998 3.07E1 1.88E2 2.30E2 0.OOEO 0.OOEO 0.OOEO 7.11EI 0.OOEO 0.00E0 1999 7.28E1 2.29E2 4.39E2 0.00E0 0.00E0 0.OOEO 9.42E1 0.OOEO 1.40E2 2000 0.OOEO 3.90E1 1.03E2 0.OOEO 0.OOEO 0.OOEO 4.96E1 0.OOEO 0.OOEO 2001 3.86E1 8.27E1 3.29E2 0.00E0 0.OOEO 0.OOEO 5.58E1 0.00E0 0.OOEO 2002 3.51 E1 2.41 E2 2.22E2 0.00E0 0.00E0 0.OOEO 8.83E]

0.OOEO 0.OOEO 2003 2.17E1 8.75E1 1.08E2 0.OOEO 0.OOEO 0.OOEO 2.69E1 0.OOEO 0.OOEO 2004 6.60E1 2.67E2 3.83E2 0.00E0 0.00E0 0.00E0 3.79E1 0.00E0 O.00E0 2005 0.00E0 1.61E2 1.41E2 0.OOEO 0.OOEO 0.OOEO 3.04E1 0.OOEO 0.OOEO 2006 0.OOEO 5.40E1 1.11 E2 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 2007 0.OOEO 8.77E1 9.46E1 0.OOEO 0.OOEO 0.OOEO 6.13E1 0.OOEO 0.OOEO 2008 0.OOEO 1.48E2 6.24E1 0.OOEO 0.OOEO 0.OOEO 2.57E1 0.OOEO 0.OOEO 2009 0.OOEO 1.10E2 1.04E2 0.OOEO 0.OOEO 0.OOEO 2.27E1 0.OOEO 0.OOEO 2010 0.OOEO 6.56E1 1.37E2 0.OOEO 0.OOEO 0.OOEO 2.56E1 0.OOEO 0.OOEO 2011 0.OOEO 8.36EI 2.36E2 0.OOEO 0.OOEO 3.62E1 4.33E1 1.05E1 0.OOEO 2012 0.OOEO 5.59E1 1.70E2 0.OOEO 0.OOEO 0.OOEO 3.15E1 0.OOEO 0.OOEO 2013 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO 0.OOEO O.OOEO

= no detectable measurements 1984 - 1986 mean based on all net activity Negative values are calculated as zeroes 00 0

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Section 3

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IIII II 3.10 DIRECT GAMMA RADIATION 3.10.1 ENVIRONMENTAL TLD II In 2013, 164 TLDs were analyzed, 152 at indicator locations and 12 at control locations. TLDs are collected and analyzed quarterly. A transit background for environmental TLDs is determined based on ANSI N545. The highest annual mean exposure for an indicator location was 96.7 milliroentgen. The annual mean exposure for the control locations was 58.0 milliroentgen.

II Figure 3.10 and Table 3.10 show TLD inner ring (site boundary), outerRing (4-5 miles), and control location annual averages in milliroentgen per year.

Preoperational data and rolling ten year operational data averages are also given.

As shown in the graph, inner ring, outer ring, and control data averages historically compare closely. Inner and outer ring averages comprise a number of data points with control averages representing only three locations.

The calculated total body dose (from gaseous effluents) for 2013 was 1.96E0 mrem, which is 2.51% of the average inner ring TLD values. Therefore, it can be concluded that discharges from the plant had very little impact upon the measured TLD values.

0 A TLD intercomparison program is conducted as part of the quality assurance program. Results of this program are included in section 5.10.

3.10.2 ISFSI The Catawba Independent Spent Fuel Storage Installation (ISFSI) is a secured area constructed to provide dry storage for spent nuclear fuel.

The principal components of the ISFSI are concrete vertical storage modules that hold stainless steel dry storage canisters containing irradiated fuel assemblies.

S The ISFSI is located approximately 300 meters north of the Unit 2 reactor building. TLD results are evaluated quarterly to identify trends and demonstrate compliance with dose and dose rate limits at the ISFSI boundaries, the Owner Controlled fence north of ISFSI and at the Exclusion Area Boundary in the west sector. Catawba began storage of spent fuel at the ISFSI in 2007.

Doses measured by environmental TLDs show little or no change since the current TLD system was implemented.

30 0

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S Section 3 - Page 20 0

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0 0

Figure 3.10 mR/year 250 Direct Gamma Radiation (TLD) Results 200 150 100 50 0

1984 1987 1990 1993 1996 1999 2002 2005 2008 2011 Inner Ring Outer Ring

-'-- ContEol There is no reporting level for Direct Radiation (TLD) 00 0

0 0

0 Section 3 - Page 21

60 0

6 Table 3.10 Direct Gamma Radiation (TLD) Results Inner Ring Average Outer Ring Average Control Average Year (mR/yr)

(IR/wyr)

(mR/yr) 1984*

87.5 82.6 79.3 1985 117 109 109 1986 104 98.5 94.4 1987 97.0 87.4 84.7 1988 74.6 70.3 67.1 1989 67.1 60.8 60.0 1990 52.0 44.5 39.1 1991 62.0 54.1 46.7 1992 80.4 72.5 64.5 1993 70.3 60.9 53.6 1994 76.3 69.3 63.9 1995 99.6 89.7 80.8 1996 84.3 73.9 63.6 1997 82.4 71.9 57.4 1998 85.3 74.2 64.6 1999 80.0 68.1 57.8 2000 75.0 63.0 52.4 2001 81.0 70.5 55.2 2002 78.8 69.5 55.2 2003 81.7 72.6 56.0 2004 78.6 73.8 55.6 2005 79.8 75.2 57.7 2006 76.9 73.6 57.2 2007 80.5 76.4 59.2 2008 81.5 77.1 60.4 2009 79.9 71.9 58.0 2010 81.4 71.6 57.2 2011 78.9 70.3 58.3 2012 80.1 71.6 61.3 Average (2003 - 2012) 79.9 73.4 58.1 2013 78.2 71.2 58.0

Preoperational Data SS 0

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Section 3 - Page 22 5

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0 3.11 LAND USE CENSUS The 2013 Annual Land Use Census was conducted July 10, and July 11, 2013 as required by SLC 16.11-14. Table 3.11 summarizes census results. A map indicating identified locations is shown in Figure 3.11.

During the 2013 census no irrigated gardens (superior to existing gardens) or milk locations were identified. The nearest residence is located in the NE sector at 0.56 miles.

No environmental program changes were required as a result of the 2013 land use census.

Table 3.11 Catawba 2013 Land Use Census Results Sector Distance Sector Distance (Wes)

(Miles)

Nearest Residence 0.63 Nearest Residence 0.63 N

Nearest Garden (irrigated) 1.55 S

Nearest Garden 1.25 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.66 Nearest Residence 0.81 NNE Nearest Garden 4.47 SSW Nearest Garden 1.34 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.56 Nearest Residence 0.63 NE Nearest Garden 0.68 sw Nearest Garden 2.02 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.61 Nearest Residence 0.57 ENE Nearest Garden 2.73 WSW Nearest Garden 2.03 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.65 Nearest Residence 0.68 E

Nearest Garden 3.52 w

Nearest Garden 0.96 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.84 Nearest Residence 1.10 ESE Nearest Garden 3.70 WNW Nearest Garden 1.26 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.97 Nearest Residence 1.39 SE Nearest Garden (irrigated) 2.55 NW Nearest Garden 1.54 Nearest Milk Animal Nearest Milk Animal Nearest Residence 0.74 Nearest Residence 0.86 SSE Nearest Garden 1.64 NNW Nearest Garden 2.13 Nearest Milk Animal Nearest Milk Animal indicates no occurrences within the 5 mile radius Section 3 - Page 23

Figure 3.11 V

Catawba Nuclear Station 2013 Land Use Census Map Legend A

CNSGardens CNSResidence CNSRairoads NavteqHwys NavteqStreets States Counties NHDWaterbody Approximate location of features shown 0

0.5 1

2Miles Projection NCSP NA027 Section 3 - Page 24

S 0

0 4.0 EVALUATION OF DOSE 0

4.1 DOSE FROM ENVIRONMENTAL MEASUREMENTS 0Annual doses to maximum exposed individuals were estimated based on measured

concentrations of radionuclides in 2013 CNS REMP samples. The primary purpose of estimating doses based on sample results is to allow comparison to effluent program dose estimates.

0Doses based on sample results were calculated using the methodology and data

presented in NRC Regulatory Guide 1.109.

Measured radionuclide concentrations, averaged over the entire year for a specific radionuclide, indicator location and sample

type, were used to calculate REMP-based doses. Where applicable, average background concentration at the corresponding control location was subtracted. Regulatory Guide 01.109 consumption rates for the maximum exposed individual were used in the

calculations.

When the guide listed "NO DATA" as the dose factor for a given radionuclide and organ, a dose factor of zero was assumed.

Maximum dose estimates (Highest Annual Mean Concentration) based on fish sample

results are reported in Table 4.1-A. The individual critical population and pathway dose

calculations are reported in Table 4.1-B.

0REMP-based dose estimates are not reported for airborne radioiodine, airborne 0particulate, milk, or ground water sample types because no radionuclides attributable to

CNS operations were detected. Naturally occurring K-40 and Be-7 were detected in

some samples but were not included in any REMP-based dose estimates.

Dose estimates are not reported for surface water because sampled surface water is not 0considered to be a potable drinking water source although surface water tritium 0concentrations are used in calculating doses from fish. Exposure estimates based upon

REMP TLD results are discussed in Section 3.10.

0The maximum environmental organ dose estimate for any single sample type (excluding

TLD results) collected during 2013 was 1.63E-2 mrem to the adult liver, total body,

thyroid, kidney, lung, and GI-LLI from consuming fish.

0 4.2 ESTIMATED DOSE FROM RELEASES

Throughout the year, dose estimates were calculated based on actual 2013 liquid and gaseous effluent release data. Effluent-based dose estimates were calculated using the RETDAS computer program which employs methodology and data presented in NRC Regulatory Guide 1.109.

These doses are shown in Table 4.1-A along with the

corresponding REMP-based dose estimates. Summaries of RETDAS dose calculations

are reported in the Annual Radioactive Effluent Release Report (reference 6.6).

00 O

~Section 4 -Page 1 0

0

I6 6

The effluent-based liquid release doses are summations of the dose contributions from the drinking water, fish, and shoreline pathways. For iodine, particulate, and tritium exposure the effluent-based gaseous release doses are summations of the dose 6

contributors from ground/plane, inhalation, milk and vegetation pathways.

6 4.3 COMPARISON OF DOSES The environmental and effluent dose estimates given in Table 4.1-A agree reasonably well. The similarity of the doses indicate that the radioactivity levels in the environment do not differ significantly from those expected based on effluent measurements and modeling of the environmental exposure pathways. This indicates that effluent program dose estimates are both valid and reasonably conservative.

There are some differences in how effluent and environmental doses are calculated that affect the comparison.

Doses calculated from environmental data are conservative because they are based on a mean that includes only samples with a net positive activity versus a mean that includes all sample results (i.e. zero results are not included in the mean). Also, airborne tritium is not measured in environmental samples but is used to calculate effluent doses.

Additionally, in 2010 Catawba began reporting estimated dose from effluent Carbon 14 (C-14). This change came about with the issuing of Regulatory Guide 1.21, Revision 2, Measuring, Evaluating and Reporting Radioactive Material in Liquid and Gaseous Effluents and Solid Waste. A description of this change is found in the 2010 Annual Radiological Effluent Release Report. C-14 is not measured in the environment and therefore, environmental and effluent doses from C-14 cannot be compared directly.

In calculations based on liquid release pathways, shoreline sediment, drinking water, and fish were the predominant dose pathways based on environmental and effluent data.

The maximum total organ dose based on 2013 environmental sample results was 1.63E-2 mrem to the adult liver, total body, thyroid, kidney, lung, and GI-LLI. The maximum total organ dose of 1.09E-1 mrem for liquid effluent-based estimates was to child liver.

0 In calculations based on gaseous release pathways, vegetation was the predominant dose pathway for effluent samples. The maximum total organ dose for gaseous effluent estimates was 4.82E0 mrem to the child bone.

No radioactivity was detected from gaseous pathways in environmental samples; therefore, there is no calculated dose.

S The doses calculated do not exceed 40CFRI90 or IOCFR50 dose commitment limits for members of the public. Doses to members of the public attributable to the operation of CNS are being maintained well within regulatory limits.

SS 0

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Section 4 - Page 2 0

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0 TABLE 4.1-A Page 1 of 2 CATAWBA NUCLEAR STATION 2013 ENVIRONMENTAL AND EFFLUENT DOSE COMPARISON 0

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LIQUID RELEASE PATHWAY Organ Environmental or Critical Critical Maximum Dose (3)

Effluent Data Age (1)

Pathway (2)

Location (mrem)

Skin Environmental 0.00E+00 Skin Effluent Teen Shoreline Sediment Discharge Pt.

3.18E-03 Bone Environmental 0.OOE+00 Bone Effluent Teen Shoreline Sediment Discharge Pt.

4.42E-03 Liver Environmental Adult Fish 208 (0.45 mi S) 1.63E-02 Liver Effluent Child Drinking Water 7.30 mi SSE 1.09E-01 T. Body Environmental Adult Fish 208 (0.45 mi S) 1.63E-02 T. Body Effluent Child Drinking Water 7.30 mi SSE 1.08E-01 Thyroid Environmental Adult Fish 208 (0.45 mi S) 1.63E-02 Thyroid Effluent Child Drinking Water 7.30 mi SSE 1.07E-01 Kidney Environmental Adult Fish 208 (0.45 mi S) 1.63E-02 Kidney Effluent Child Drinking Water 7.30 mi SSE 1.08E-01 Lung Environmental Adult Fish 208 (0.45 mi S) 1.63E-02 Lung Effluent Child Drinking Water 7.30 mi SSE 1.07E-01 GI-LLI Environmental 0.OOE+00 GI-LLI Effluent Child Drinking Water 7.30 mi SSE 1.08E-01 (1) Critical Age is the highest total dose (all pathways) to an age group.

(2) Critial Pathway is the highest individual dose within the identified Critical Age group.

(3) Maximum dose is a summation of the fish, drinking water and shoreline sediment pathways.

Section 4 - Page 3

Page 2 of 2 GASEOUS RELEASE PATHWAY IODINE, PARTICULATE, and TRITIUM Environmental or Critical Critical Maximum Dose (3)

Organ Effluent Data Age "1 Pathway (2)

Location (mrem)

Skin Environmental 0.OOE+00 Skin Effluent 0.OOE+00 Bone Environmental 0.OOE+00 Bone Effluent Child Vegetation 0.5 mi NE 4.82E+00 Liver Environmental 0.00E+00 Liver Effluent Child Vegetation 0.5 mi NE 1.96E+00 T. Body Environmental O.00E+00 T. Body Effluent Child Vegetation 0.5 mi NE 1.96E+00 Thyroid Environmental 0.OOE+00 Thyroid Effluent Child Vegetation 0.5 mi NE 1.96E+00 Kidney Environmental 0.OOE+00 Kidney Effluent Child Vegetation 0.5 mi NE 1.96E+00 Lung Environmental O.OOE+00 Lung Effluent Child Vegetation 0.5 mi NE 1.96E+00 GI-LLI Environmental 0.OOE+00 GI-LLI Effluent Child Vegetation 0.5 mi NE 1.96E+00 6

6 6

6 S

S S

S 0

0 S

S (1) Critical Age is the highest total dose (all pathways) to an age group.

(2) Critial Pathway is the highest individual dose within the identified Critical Age group.

(3) Maximum dose is a summation of the ground/plane, inhalation, milk and vegetation pathways.

Section 4 - Page 4

TABLE 4.1-B Maximum Individual Dose for 2013 based on Environmental Measurements (tnrem)for Catawba Nuclear Station Age Sample Medium Bone Liver T. Body Thyroid Kidney Lung GI-LLI Skin Infant Airborne 0.00E+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+O0 Drinking Water O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Milk O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 TOTAL O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Child Airborne O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Drinking Water O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Milk O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Broadleaf Vegetation O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Fish O.OOE+00 1.04E-02 1.04E-02 1.04E-02 1.04E-02 1.04E-02 1.04E-02 O.OOE+00 Shoreline Sediment O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 TOTAL O.OOE+00 1.04E-02 1.04E-02 1.04E-02 1.04E-02 1.04E-02 1.04E-02 O.OOE+00 Teen Airborne O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Drinking Water O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Milk O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Broadleaf Vegetation O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Fish O.OOE+00 1.25E-02 1.25E-02 1.25E-02 1.25E-02 1.25E-02 1.25E-02 O.OOE+00 Shoreline Sediment O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 TOTAL O.OOE+00 1.25E-02 1.25E-02 1.25E-02 1.25E-02 1.25E-02 1.25E-02 O.OOE+00 Adult Airborne O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Drinking Water 0.00E+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Milk O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Broadleaf Vegetation O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Fish O.OOE+00 1.63E-02 1.63E-02 1.63E-02 1.63E-02 1.63E-02 1.63E-02 O.OOE+00 Shoreline Sediment O.OOE+00 O.OOE+00 O.OOE+00 0.00E+00 O.OOE+00 O.OOE+00 0.00E+00 O.OOE+00 TOTAL 0.OOE+00 1.63E-02 1.63E-02 1.63E-02 1.63E-02 1.63E-02 1.63E-02 O.OOE+00 Note: Dose tables are provided for sample media displaying positive nuclide occurrence.

Section 4 - Page 5

Catawba Nuclear Station Dose from Fish Pathway for 2013 Data Maximum Exposed Child Child Dose from Fish Pathway (mrem) = Usage (kg) x Dose Factor (mrem/pCi ingested) x Concentration (pCi/kg)

H-3 Concentration in Fish = Surface Water pCi/l x Bioaccumulation Factor 0.9 pCi/kg per pCi/I = 8213 pCi/I x 0.9 = 7392 pCi/kg Usage (intake in one year) =

6.9 kg Radionuclide Mn-54 Co-58 Fe-59 CO-60 Zn-65 Cs-134 Cs-137 H-3 Bone NO DATA NO DATA 1.65E-05 NO DATA 1.37E-05 2.34E-04 3.27E-04 NO DATA Liver 1.07E-05 1.80E-06 2.67E-05 5.29E-06 3.65 E-05 3.94E-04 3.13E-04 2.03E-07 T. Body 2.85E-06 5.1E-06 1.33E-05 1.56E-05 2.2713-05 8.10E-05 4.62E-05 2.03E-07 Ingestion Dose Factor Thyroid Kidney Lung NO DATA 3.00E-06 NO DATA NO DATA NO DATA NO DATA NO DATA NO DATA 7.74E-06 NO DATA NO DATA NO DATA NO DATA 2.30E-05 NO DATA NO DATA 1.19E-04 4.27E-05 NO DATA 1.02E-04 3.67E-05 2.03E-07 2.03E-07 2.03E-07 GI-LLI 8.98E-06 1.05E-05 2.78E-05 2.93E-05 6.41E-06 2.07E-06 1.96E-06 2.03E-07 Highest Annual Net Mean Concentration Indicator Fish Location (pCi/kg)

ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 208 7392 Bone 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 Liver 0.OOE+00 0.0013+00 0.00E+00 0.OOE+00 0.OOE+O0 0.00E+00 0.OOE+00 1.0413-02 T. Body 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 O.O0E400 0.OOE+00 0.OOE+00 1.04E-02 Dose (mrem)

Thyroid Kidney 0.00E+00 0.00E+00 O.OOE+00 O.OOE+00 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 O.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 0.00E+00 1.04E-02 1.04E-02 Lung 0.OOE+00 0.OOE+00 0.0013+00 0.OOE+00 O.O0EfO0 0.00E+00 0.OOE+00 1.04E-02 GI.LLI 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 O.OOE+00 0-OOE+00 0.OOE+00 1.04E-02 Dose Commitment (mrem) =

0.00E+00 1.04E-02 1.04E-02 1.04E-02 1.04E-02 1.04E-02 1.04E-02 Section 4 - Page 6 lee ee 4

0 00 0 400 400 0 401 0 00 000 00 00 0 0 000 0 00

Catawba Nuclear Station Dose from Fish Pathway for 2013 Data Maximum Exposed Teen Teen Dose from Fish Pathway (mrerm) = Usage (kg) x Dose Factor (mren/pCi ingested) x Concentration (pCi/kg)

H-3 Concentration in Fish = Surface Water pCiil x Bioaccumulation Factor 0.9 pCi/kg per pCi/I = 8213 pCi/I x 0.9 = 7392 pCifkg Usage (intake in one year) =

16 kg Radionuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 H-3 Bone NO DATA NO DATA 5.87E-06 NO DATA 5.76E-06 8.37E-05 1.12E-04 NO DATA Liver 5,90E-06 9,72E-07 1.37 E-05 2.81 E-06 2.OOE-05 1.97E-04 1,49E-04 1.06E-07 T. Body 1.17E-06 2.24E-06 5.29E-06 6-33E-06 9.33E-06 9.14E-05 5.19E-05 1.06E-07 Ingestion Dose Factor Thyroid Kidney Lung NO DATA 1.76E-06 NO DATA NO DATA NO DATA NO DATA NO DATA NO DATA 4.32E-06 NO DATA NO DATA NO DATA NO DATA 1.28E-05 NO DATA NO DATA 6.26E-05 2.39E-05 NO DATA 5.07E-05 1.97E-05 1.06E-07 1.06E-07 1.06E-07 GI-LLI 1.21E-05 1.34E-05 3.24E-05 3.66E-05 8.47E-06 2.451E-06 2.12E-06 1.06E-07 Highest Annual Net Mean Concentration Location (pCi/kg)

ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 208 7392 Bone 0.OOE+00 0.OOE+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 Liver 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 1.25E-02 T. Body 0.O0E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25E-02 Dose (mrem)

Thyroid Kidney 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25E-02 1.25E-02 Lung 0.OOE+00 0.OOE+00 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 1.25E-02 Gl-LUI 0.00E+00 000OE+00 0.00E+00 0.00E+O0 0.00E+00 O.OOE+00 000OE+00 1.25E-02 Dose Commitment (mrem) =

0.OOE+00 1.25E-02 1.25E-02 1.25E-02 1.25E-02 1.25E-02 1.25E-02 Section 4 - Page 7

Catawba Nuclear Station Dose from Fish Pathway for 2013 Data Maximum Exposed Adult Adult Dose from Fish Pathway (mrem) = Usage (kg) x Dose Factor (mrem/pCi ingested) x Concentration (pCi/kg)

H-3 Concentration in Fish = Surface Water pCi/I x Bioaccumulation Factor 0.9 pCi/kg per pCi/I = 8213 pCi/I x 0.9 = 7392 pCi/kg Usage (intake in one year) =

21 kg Radionuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 H-3 Bone NO DATA NO DATA 4.34E-06 NO DATA 4.84E-06 6.22E-05 7.97E-05 NO DATA Liver 4.57E-06 7.45E-07 1.02E-05 2.14E-06 1-54E-05 1.4813-04 1.09E-04 1.05E-07 In2estion Dose Factor T. Body Thyroid Kidney Lung 8.72E-07 NO DATA 1.36E-06 NO DATA 1.67E-06 NO DATA NO DATA NO DATA 3.91E-06 NO DATA NO DATA 2.85E-06 4.72E-06 NO DATA NO DATA NO DATA 6.96E-06 NO DATA 1.03E-05 NO DATA 1.21E-04 NO DATA 4.79E-05 1.59E-05 7.14E-05 NO DATA 3.70E-05 1.23E-05 1.05E-07 1.05E-07 1.05E-07 1.05E-07 GI-LLI 1.40E-05 1.51E-05 3.40E-05 4.02E-05 9.70E-06 2.59E-06 2.11E-06 1.05E-07 Highest Annual Net Mean Concentration Location (pCi/kg)

ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 ALL 0.00 208 7392 Bone O.OOE+O0 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+O0 0.OOE+O0 0.OOE-t00 0.OOE+00 Liver 0.OOE+00 0.OOE+00 O.OOE+00 0.OOE+00 0.OOE+OO O.OOE+00 0.OOE+O0 1.63E-02 T. Body 0.OO11+00 0.OOE+OO 0.OOE+00 O.OOE+O0 0.OO13+00 O.OOE+OO 0.OOE+00 1.63E-02 Dose (mrem)

Thyroid Kidney 0.OOE+00 0.OOE+00 0.OOE+00 O.OOE+00 0.00E+00 0.OOE+00 0.OOE+00 O.OOE+00 O.OOE+00 0.OOE+00 O.OOE+00 O.OOE+00 0.OOE+00 0.OOE+00 1.63E-02 1.63E-02 Lung O.OOE+00 O.OOE+00 0.OOE+00 0.OOE+00 O.OOE+00 0.OOE+00 0.0011+00 1.63E-02 GI-LLI 0,O0E+00 O.OOE+00 0.OOE+00 O.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 1.63E-02 Dose Commitment (mrem) =

O.OOE+00 1.63E-02 1.63E-02 1.63E-02 1.63E-02 1.63E-02 1.63E-02 Section 4 - Page 8 0090000000000000000000000000000004000000000000

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0 5.1 SAMPLE COLLECTION 0EnRad Laboratories, Fisheries, and Aquatic Ecology performed the environmental sample 0collections as specified by approved sample collection procedures.

5.2 SAMPLE ANALYSIS S

EnRad Laboratories performed the environmental sample analyses as specified by approved analysis procedures.

EnRad Laboratories is located in Huntersville, North 0Carolina, at Duke Energy's Environmental Center.

5.3 DOSIMETRY ANALYSIS The Radiation Dosimetry and Records group performed environmental dosimetry measurements as specified by approved dosimetry analysis procedures.

5.4 LABORATORY EQUIPMENT QUALITY ASSURANCE 5.4.1 DAILY QUALITY CONTROL 0EnRad Laboratories has an internal quality assurance program which monitors

each type of instrumentation for reliability and accuracy. Daily quality control checks ensure that instruments are in proper working order and these checks are

used to monitor instrument performance.

5.4.2 CALIBRATION VERIFICATION

National Institute of Standards and Technology (NIST) standards that represent

counting geometries are analyzed as unknowns at various frequencies ranging from weekly to annually to verify that efficiency calibrations are valid. The frequency is dependent upon instrument use and performance. Investigations are

performed and documented should calibration verification data fall outside of the

acceptable limits.

5.4.3 BATCH PROCESSING 0

Method quality control samples are analyzed with sample analyses that are processed in batches. These include gross beta in drinking water and tritium analyses.

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5.5 DUKE ENERGY INTERCOMPARISON PROGRAM

EnRad Laboratories participated in the Duke Energy Fleet Scientific Services (FSS)

Intercomparison Program during 2013.

Interlaboratory cross-check standards, 0

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including gamma in water (Marinelli beakers), and tritium in water samples were analyzed during 2013. A summary of the EnRad Laboratory program results for 2013 is documented in Table 5.0-A.

5.6 ECKERT & ZIEGLER ANALYTICS CROSS CHECK PROGRAM EnRad Laboratories participated in the Eckert & Ziegler Analytics Cross Check Program during 2013. Cross-check standards including Marinelli beakers, air filters, tritium in water, and Iodine in milk samples were analyzed at various times of the year. A summary of the EnRad Laboratory program results for 2013 is documented in Table 5.0-B.

5.7 ERA PROFICIENCY TESTING EnRad Laboratories performed method proficiency testing through a program administered by Environmental Resource Associates (ERA) of Arvada, CO. ERA supplied requested method proficiency samples for analysis and nuclide concentration determination.

ERA reported proficiency test results to the North Carolina Department of Health and Human Services, North Carolina Public Health Drinking Water Laboratory Certification Program. A summary of these proficiency test data for 2013 is documented in Table 5.0-C.

5.8 DUKE ENERGY AUDITS The Catawba Nuclear Station Radiological Environmental Monitoring Program was not audited by the Quality Assurance Group in 2013 but was audited in 2012 (reference 6.14). No environmental monitoring issues were identified.

5.9 U.S. NUCLEAR REGULATORY COMMISSION INSPECTIONS The Catawba Nuclear Station Radiological Environmental Monitoring Program was audited by the NRC in 2013 (reference 6.12). No findings were noted in the 2013 audit report.

5.10 STATE OF SOUTH CAROLINA INTERCOMPARISON PROGRAM 0

Catawba Nuclear Station routinely participates with the Bureau of Radiological Health of the State's Department of Health and Environmental Control (DHEC) in an intercomparison program. The Memorandum of Agreement (MOA) between SC DHEC and Duke Energy describes the sampling frequency and analysis parameters for drinking water, surface water, milk, fish, vegetation, and shoreline sediment samples collected by EnRad Laboratories.

Samples are routinely split with DHEC for intercomparison analysis. DHEC collects air samples near two of the locations sampled for air by CNS.

Results of the analyses performed on split and duplicate samples are sent to DHEC.

This program was discontinued late in the year at the request of SC DHEC (Reference 6.15) and was replaced by a similar program with a vendor laboratory.

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0 5.11 TLD INTERCOMPARISON PROGRAM 5.11.1 NUCLEAR TECHNOLOGY SERVICES INTERCOMPARISON PROGRAM Radiation Dosimetry and Records participates in a quarterly TLD intercomparison program administered by Nuclear Technology Services, Inc. of Roswell, GA. Nuclear Technology Services irradiates environmental dosimeters quarterly and sends them to the Radiation Dosimetry and Records group for analysis of the unknown estimated delivered exposure.

A summary of the Nuclear Technology Services Intercomparison Report is documented in Table 5.0-D.

5.11.2 INTERNAL CROSSCHECK (DUKE ENERGY)

Radiation Dosimetry and Records participates in a

quarterly TLD intracomparison program administered internally by the Dosimetry Lab. The Dosimetry Lab Staff irradiates environmental dosimeters quarterly and submits them for analysis of the unknown estimated delivered exposure. A summary of the Internal Cross Check (Duke Energy) Result is documented in Table 5.0-D.

Section 5 - Page 3

TABLE 5.0-A DUKE ENERGY INTERLABORATORY COMPARISON PROGRAM 2013 EnRad Fleet Scientific Services Cross Check Performance Summary Cross check samples were distributed by Fleet Scientific Services (FSS) in accordance with Duke Energy Nuclear Generation Procedure SRPMP 9-2. Six water samples were analyzed for tritium and gamma emitters. The below table lists results for specific analyses. All 27 results were evaluated as prescribed in procedure SRPMP 9-2 and passed the acceptance criteria for the program.

Sample Sample ID Nuclide Quarter Units Ealued Va EnRad/FSS Evaluation Value Value Ratio Tritium in Water QI31TWRI H-3 1

pCi/L 7.48E+02 7.27E+02 1.03 Pass 7.53E+02 7.27E+02 1.04 Pass 7.1 1E+02 7.27E+02 0.98 Pass QI31TWR2 H-3 I

pCi/L 7.51E+05 7.85E+05 0.96 Pass 7.52E+05 7.85E+05 0.96 Pass 7.49E+05 7.85E+05 0.95 Pass Q131TWR3 H-3 I

pCi/L 6.23E+03 5.86E+03 1.06 Pass 6.36E+03 5.86E+03 1.09 Pass 6.32E+03 5.86E+03 1.08 Pass Gamma in Water Q131GWR- 0.5 L Mn-54 1

pCiiL 4.16E+03 3.85E+03 1.08 Pass Co-57 I

pCi/L 7.42E+03 6.86E+03 1.08 Pass Co-60 I

pCi/L 5.94E+03 5.84E+03 1.02 Pass Sn-113 1

pCi/L 7.15E+03 7.23E+03 0.99 Pass Ba-133 I

pCi/L 5.86E+03 5.70E+03 1.03 Pass Cs-137 I

pCi/L 3.38E+03 3.46E+03 0.98 Pass Q131GWR - 1.0 L Mn-54 1

pCi/L 4.21E+03 3.85E+03 1.09 Pass Co-57 I

pCi/L 7.68E+03 6.86E+03 1.12 Pass Co-60 1

pCi/L 5.90E+03 5.84E+03 1.01 Pass Sn-113 1

pCi/L 6.94E+03 7.23E+03 0.96 Pass Ba-133 1

pCi/L 5.58E+03 5.70E+03 0.98 Pass Cs-137 1

pCi/L.

3.38E+03 3.46E+03 0.98 Pass Q131GWR-3.5 L Mn-54 1

pCi/L 4.38E+03 3.85E+03 1.14 Pass Co-57 1

pCi/L 7.91E+03 6.86E+03 1.15 Pass Co-60 1

pCi/L

6. 18E+03 5.84E+03 1.06 Pass Sn-113 1

pCi/L 7.52E+03 7.23E+03 1.04 Pass Ba-133 1

pCi/L 5.93E+03 5.70E+03 1.04 Pass Cs-137 I

pCi/L 3.48E+03 3.46E+03 1.00 Pass 0

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TABLE 5.0-B ECKERT & ZIEGLER ANALYTICS CROSS CHECK PROGRAM 2013 Cross Check Results for EnRad Laboratories Cross check samples are received, prepared, and analyzed in all four quarters of 2013. Results are reported directly to Eckert & Ziegler Analytics. Environmental cross check samples were analyzed in replicate, and the average result reported to Eckert & Ziegler Analytics. The acceptance criteria for the program was based on the NRC Inspection Manual Procedure 84750 (IP 84750). Fifty-seven environmental results were reported, of which 57 (100%) met the acceptance criteria based on IP 84750.

EnRad EZA EnRad/EZA Sample Sample ID Nuclide Quarter Units Value Value Ratio Evaluation Beta Filter E10509 Gross Beta I

pCi 86.5 94.2 0.92 Agreement E10606 Gross Beta 3

pCi 187 215 0.87 Agreement Gamma Filter E 10508 Ce-141 I

pCi 97.3 107 0.91 Agreement Cr-51 i

pCi 256 269 0.95 Agreement Cs-134 I

pCi 113 122 0.93 Agreement Cs-137 1

pCi 144 151 0.95 Agreement Co-58 1

pCi 109 119 0.92 Agreement Mn-54 1

pCi 121 119 1.02 Agreement Fe-59 I

pCi 149 144 1.04 Agreement Zn-65 I

pCi 179 171 1.04 Agreement Co-60 I

pCi 224 228 0.98 Agreement 1-131 in Milk E10531 1-131 2

pCi/L 91.8 97.3 0.94 Agreement 1-131 in Water E10709 1-131 4

pCi/L 98.6 99 1.00 Agreement Beta in Water E10532 Gross Beta 2

pCi/L 304 293 1.04 Agreement E10708 Gross Beta 4

pCifL 291 279 1.04 Agreement 1-131 Cartridge E10533 1-131 2

pCi 94 89.7 1.05 Agreement E10707 1-131 4

pCi 77.2 76.5 1.01 Agreement Gamma Composite E10534 Ce-141 2

pCi 80.6 77.1 1.05 Agreement Filter Cr-51 2

pCi 240 214 1.12 Agreement Cs-134 2

pCi 107 107 1.00 Agreement Cs-137 2

pCi 122 129 0.95 Agreement Co-58 2

pCi 76.6 80.2 0.96 Agreement Mn-54 2

pCi 149 147 1.01 Agreement Fe-59 2

pCi 105 102 1.03 Agreement Zn-65 2

pCi 196 186 1.06 Agreement Co-60 2

pCi 152 150 1.02 Agreement Section 5 - Page 5

TABLE 5.0-B (Cont.)

Units EnRad EZA EnRad/EZA Sample Sample ID Nuclide Quarter Unis Value Value Ratio Evalation Tritium in Water E10535 H-3 2

pCi/L 9690 9890 0.98 Agreement E10705 H-3 4

pCiL 13800 14500 0.95 Agreement Gamma Composite E10706 Ce-141 4

pCi 107 117 0.91 Agreement Filter Cr-51 4

pCi 332 317 1.05 Agreement Cs-134 4

pCi 145 152 0.96 Agreement Cs-137 4

pCi 126 135 0.93 Agreement Co-58 4

pCi 118 120 0.98 Agreement Mn-54 4

pCi 177 180 0.99 Agreement Fe-59 4

pCi 140 118 1.19 Agreement Zn-65 4

pCi 781 793 0.99 Agreement Co-60 4

pCi 155 157 0.99 Agreement Gamma in Milk E10536 1-131 2

pCi/L 96.2 95.5 1.01 Agreement Ce-141 2

pCi/L 92 90.4 1.02 Agreement Cr-51 2

DCi/L 238 250 0.95 Agreement Cs-134 2

pCi/L 122 125 0.98 Agreement Cs-137 2

pCi/L 145 151 0.96 Agreement Co-58 2

pCi/L 93.1 94 0.99 Agreement Mn-54 2

pCi/L 180 172 1.05 Agreement Fe-59 2

pCi/L 129 120 1.08 Agreement Zn-65 2

pCi/L 239 217 1.10 Agreement Co-60 2

pCi/L 177 175 1.01 Agreement Gamma in Water E10704 1-131 4

pCi/L 95.4 92.4 1.03 Agreement Ce-141 4

pCi/L 89.3 88.8 1.01 Agreement Cr-51 4

pCi/L 243 240 1.01 Agreement Cs-134 4

pCi/L 109 115 0.95 Agreement Cs-137 4

pCi/L 104 102 1.02 Agreement Co-58 4

pCi/L 91.5 90.6 1.01 Agreement Mn-54 4

pCi/L 141 136 1.04 Agreement Fe-59 4

pCi/L 92.6 89.1 1.04 Agreement Zn-65 4

pCi/L 629 600 1.05 Agreement Co-60 4

pCi/L 123 119 1.04 Agreement S

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TABLE 5.0-C ENVIRONMENTAL RESOURCE ASSOCIATES (ERA)

PROFICIENCY TESTING 2013 Proficiency Test Results for EnRad Laboratories North Carolina Department of Health and Human Services Laboratory Certification EnRad Laboratories Proficiency test samples are received, prepared, and analyzed in second and fourth quarters of 2013. Results are reported directly to Environmental Resource Associates as described in the instruction package within the study period. Proficiency test data are reported to ERA for evaluation. The acceptance criteria for the program was based on the National Environmental Laboratory Accreditation Conference (NELAC) Field of Proficiency Testing criteria.

Fourteen results were reported of which 12 (85.7%) met the acceptance criteria. ERA reports proficiency test results to the North Carolina Department of Health and Human Services, North Carolina Public Drinking Water Laboratory Certification Program. This testing is to satisfy the North Carolina state drinking water radiochemistry certification requirements. The individual measurements were evaluated and results falling outside the acceptable ratio criteria had an evaluation performed to identify any recommended remedial actions and to reduce anomalous errors. Complete documentation of any evaluation will be available and provided to the NRC upon request.

Sample Sample ID Nuclide Quarter Units EnRad ERA Acceptance Evaluation Value Value Limits Gamma Emitters fin Wa ter RAD-93 Ba-133 2

pCi/L 82.5 82.1 69.0-90.3 Acceptable Water Cs-134 2

pCi/L 41.9 42.8 34.2-47.1 Acceptable Cs-137 2

pCi/L 42.1 41.7 37.0-48.8 Acceptable Co-60 2

pCi/L 71 65.9 59.3 - 75.0 Acceptable Zn-65 2

pCi/L 207 189 170 - 222 Acceptable Gamma Emitters i RAD-95 Ba-133 4

pCi/L 48.3 54.2 44.7 - 59.9 Acceptable Water Cs-134 4

pCi/L 81.5 86.7 71.1 -95.4 Acceptable Cs-137 4

pCi/L 180 206 185 - 228 Not Acceptable

Co-60 4

pCi/L 103 102 91.8-114 Acceptable Zn-65 4

pCi/L 337 333 300 - 389 Acceptable Tritium in Water RAD-93 H-3 2

pCi/L 6620 4050 3450 - 4460 Not Acceptable #

RAD-95 H-3 4

pCi/L 17000 17700 15500- 19500 Acceptable Iodine-131 in RAD-93 1-131 2

pCi/L 26.9 23.8 19.7-28.3 Acceptable Water RAD-95 1-131 4

pCi/L 21.4 23.6 19.6-28.0 Acceptable

See PIP G-13-02152

See PIP G-13-00925 Section 5 - Page 7

TABLE 5.0-D 2013 ENVIRONMENTAL DOSIMETER CROSS-CHECK RESULTS Nuclear Technology Services 1st Quarter 2013 2nd Quarter 2013 TLD Reported Delivered Bias Pass/Fail TLD Reported Delivered Bias Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail 102432 83.6 79.19 5.61

<+/-15%

Pass 102104 91.10 90.22 0.98

<+/-15%

Pass 102452 83.0 79.19 4.84

<+/-15%

Pass 102359 91.20 90.22 1.09

<+/-15%

Pass 102453 83.8 79.19 5.77

<+/-15%

Pass 102099 92.44 90.22 2.46

<+/-15%

Pass 102455 82.6 79.19 4.34

<+/-15%

Pass 102294 93.25 90.22 3.36

<+/-15%

Pass 102473 85.2 79.19 7.59 1 <+/-15%

Pass 102420 1 93.88 90.22 4.06

<+/-15%

Pass Average Bias (B) 5.63 Average Bias (B) 2.39 Standard Dex4ation (S) 1.24 Standard Deviation (S) 1.36 Measure Performance IBI+S 6.87

<15%

Pass Measure Performance IBI+S 3.75

<15%

Pass 3rd Quarter 2013 4th Quarter 2013 TLD Reported Delivered Bias Pass/Fail TLD Reported Delivered Bias Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail 103363 82.62 79.0 4.53

<+/-15%

Pass 103138 90.70 89.2 1.68

<+/-15%

Pass 103661 86.78 79.0 9.79

<+/-15%

Pass 103139 91.28 89.2 2.33

<+/-15%

Pass 103414 83.02 79.0 5.04

<+/-15%

Pass 103140 92.38 89.2 3.57

<+/-15%

Pass 103154 87.35 79.0 10.51

<+/-15%

Pass 103747 90.97 89.2 1.98

<+/-15%

Pass 103145 85.45 79.0 8.11

<+/-15%

Pass 103676 1 90.97 89.2 1.98

<+/-15%

Pass Average Bias (B) 7.60 Average Bias (B) 2.31 Standard Deviation (S) 2.72 Standard Deviation (S) 0.74 Measure Performance JBJ+S 10.31

<15%

Pass Measure Performance JBJ+S 3.05

<15%

Pass 6

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1st Quarter 2013 2nd Quarter 2013 TLD Reported Delivered Bias Pass/Fail TLD Reported Deliv'ered Bias Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail Number (mR)

(mR)

(% diff)

Crtera Pass/Fail 103725 36.4 35.0 3.89

<+/-15%

Pass 103279 27.6 28.0

-1.54

<+1-15%

Pass 103726 37.6 35.0 7.43

<+/-15%

Pass 102457 27.8 28.0

-0.61

<+/-15%

Pass 103259 35.8 35.0 2.26

<+/-15%

Pass 102497 27.4 28.0

-2.29

<+/-15%

Pass 103761 34.5 35.0

-1.51

<+/-15%

Pass 102005 27.7 28.0

-1.04

<+1-15%

Pass 102729 36.8 35.0 5.00

<+/-15%

Pass 102492 27.1 28.0

-3.29

<+/-15%

Pass 102728 34.8 35.0

-0.46

<+/-15%

Pass 102102 27.4 28.0

-2.11

<+/-15%

Pass 103258 33.4 35.0

-4.54

<+/-15%

Pass 102345 27.0 28.0

-3.43

<+1-15%

Pass 102727 37.1 35.0 6.09

<+/-15%

Pass 101378 27.3 28.0

-2.61

<+1-15%

Pass 103724 34.9 35.0

-0.37

<+/-15%

Pass 102400 28.5 28.0 1.79

<+/-15%

Pass 102726 35.7 35.0 1.94

<+/-15%

Pass 103257 28.6 28.0 2.21

<+/-15%

Pass Average Bias (B) 1.97 Average Bias (B)

-1.29 Standard Deviation (S) 3.74 Standard Deviation (S) 1.95 Measure Performance IBI+S 5.71

<15%

Pass Measure Performance IBI+S 3.24

<15%

Pass 3rd Quarter 2013 4th Quarter 2013 TLD Reported Delivered Bias Pass/Fail TLD Reported Delivered Bias Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail Number (mR)

(mR)

(% diff)

Criteria Pass/Fail 103370 32.0 31.0 3.35

<+/-15%

Pass 103581 57.2 51.0 12.14

<+/-15%

Pass 103610 32.0 31.0 3.10

<+/-15%

Pass 102905 56.8 51.0 11.37

<+/-15%

Pass 103597 32.4 31.0 4.35

<+/-15%

Pass 103134 56.0 51.0 9.88

<+/-15%

Pass 103553 31.6 31.0 1.87

<+/-15%

Pass 120802 56.9 51.0 11.59

<+/-15%

Pass 103369 32.5 31.0 4.90

<+/-15%

Pass 103118 57.3 51.0 12.25

<+/-15%

Pass 103750 32.2 31.0 3.87

<+/-15%

Pass 120703 55.7 51.0 9.12

<+/-15%

Pass 103578 33.3 31.0 7.35

<+/-15%

Pass 102521 56.1 51.0 9.92

<+/-15%

Pass 103136 32.4 31.0 4.55

<+/-15%

Pass 103582 55.5 51.0 8.90

<+/-15%

Pass 103368 32.6 31.0 5.13

<+1-15%

Pass 102826 57.9 51.0 13.61

<+1-15%

Pass 103552 32.5 31.0 4.74

<+/-15%

Pass 102702 56.1 51.0 10.06

<+/-15%

Pass Average Bias (B) 4.32 Average Bias (B) 10.88 Standard De\\iation (S) 1.46 Standard Deviation (S) 1.54 Measure Performance IBI+S 5.78

<15%

Pass Measure Performance IBI+S 12.42

<15%

Pass Section 5 - Page 9

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6.0 REFERENCES

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6.1 Catawba Selected Licensee Commitment Report 6.2 Catawba Technical Specifications 0

6.3 Catawba Updated Final Safety Analysis Review 6.4 Catawba Offsite Dose Calculation Manual 6.5 Catawba Annual Environmental Operating Report 1985 - 2012 6.6 Catawba Annual Effluent Report 1985 - 2013 6.7 Probability and Statistics in Engineering and Management Science, Hines and

Montgomery, 1969, pages 287-293.

0 6.8 Practical Statistics for the Physical Sciences, Havilcek and Crain, 1988, pages 83-93.

6.9 Nuclear Regulatory Commission Regulatory Guide 1.109, Calculation of Annual Doses to Man from Routine Releases of Reactor Effluents for the Purposes of

Evaluating Compliance with IOCFR50, Appendix I.

6.10 EnRad Laboratories Operating Procedures 6.11 RETDAS, Radiological Effluent Tracking and Dose Assessment Software, Canberra

Version 3.5.1, DPC Revision #4.0 S

6.12 NRC Integrated Inspection Report 05000413/2013002 and 05000414/2013002 6.13 NCRP (2009). National Council on Radiation Protection and Measurements. Ionizing

Radiation Exposure of the Population of the United States, NCRP Report No. 160 (National Council on Radiation Protection and Measurements, Bethesda, Maryland).

6.14 Radiological Effluents Control Audit 12-18 (NOS)(REC)(CNS) 6.15 Problem Investigation Program Database, V 3.4.3, Duke Energy Company, G-13-02184 0

6.16 Problem Investigation Program Database, V 3.4.3, Duke Energy Company, G-13-00892 00 0

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0 APPENDIX A ENVIRONMENTAL SAMPLING ANALYSIS PROCEDURES Appendix A - Page I

APPENDIX A 66 6

ENVIRONMENTAL SAMPLING AND ANALYSIS PROCEDURES Adherence to established procedures for sampling and analysis of all environmental media at Catawba Nuclear Station was required to ensure compliance with Station Selected Licensee Commitments.

Analytical procedures were employed to ensure that Selected Licensee Commitments detection capabilities were achieved.

Environmental sampling and analyses were performed by EnRad Laboratories, Dosimetry and Records, Fisheries and Aquatic Ecology.

This appendix describes the environmental sampling frequencies and analysis procedures by media type.

I. CHANGE OF SAMPLING PROCEDURES 00 No changes were made to the sampling procedure during 2013.

II. DESCRIPTION OF ANALYSIS PROCEDURES 00 Gamma spectroscopy analyses are performed using high purity germanium gamma detectors and Canberra analytical software. Designated sample volumes are transferred to appropriate counting geometries and analyzed by gamma spectroscopy. Perishable samples such as fish and broadleaf vegetation are ground to achieve a homogeneous mixture. Soils and sediments are dried, sifted to remove foreign objects (rocks, clams, glass, etc.) then transferred to appropriate counting geometry.

Low-level iodine analyses are performed by passing a designated sample aliquot through a pre-weighed amount of ion exchange resin to remove and concentrate any iodine in the aqueous sample (milk). The resin is then dried, mixed thoroughly, and a net resin weight determined before being transferred to appropriate counting geometry and analyzed by gamma spectroscopy.

Tritium analyses are performed quarterly by using low-level environmental liquid scintillation analysis technique on a Packard 2550 liquid scintillation system or Perkin-Elmer 2900TR liquid scintillation system.

Tritium samples are distilled and batch processed with a laboratory fortified blank, matrix spike, matrix spike duplicate, and blank to verify instrument performance and sample preparation technique are acceptable.

00 0

S Appendix A -Page 2 S

w*

Gross beta analysis is performed by concentrating a designated aliquot of sample precipitate and analyzing by Tennelec XLB Series 5 gas-flow proportional counters.

0Samples are batch processed with a blank to ensure sample contamination has not occurred.

III. CHANGE OF ANALYSIS PROCEDURES SQuarterly gamma spectroscopy analysis of airborne particulate filter composite (by

location) was implemented during 2013; elective weekly gamma spectroscopy of the

airborne particulate individual filter was discontinued.

0 IV. SAMPLING AND ANALYSIS PROCEDURES A.1 AIRBORNE PARTICULATE AND RADIOIODINE 0

Airborne particulate and radioiodine samples at each of five locations were composited continuously by means of continuous air samplers. Air particulates

were collected on a particulate filter and radioiodines were collected in a

charcoal cartridge positioned behind the filter in the sampler. The samplers are

designed to operate at a constant flow rate (in order to compensate for any filter loading) and are set to sample approximately 2 cubic feet per minute. Filters and cartridges were collected weekly.

A separate weekly gamma analysis was

performed on each charcoal cartridge.

A weekly gross beta analysis was

performed on each filter. A quarterly gamma analysis was performed on the

quarterly filter composite (by location).

The continuous composite samples were collected from the locations listed below.

0 Location 200

=

Site Boundary (0.63 mi. NNE)

Location 201

=

Site Boundary (0.53 mi. NE)

Location 205

=

Site Boundary (0.25 mi. SW)

Location 212

=

Tega Cay (3.32 mi. E)

Location 258

=

Fairhope Road (9.84 mi. W)

A.2 DRINKING WATER

Monthly composite drinking water samples were collected at each of two locations. A gross beta and gamma analysis was performed on monthly

composites.

Tritium analysis was performed on the quarterly composites. The composites were collected monthly from the locations listed below.

Location 214

=

Rock Hill Water Supply (7.30 mi. SSE)

Location 218

=

Belmont Water Supply (13.5 mi. NNE) 0S 0

0 0

O Appendix A - Page 3 0

A.3 SURFACE WATER Monthly composite samples were collected at each of three locations. A gamma analysis was performed on the monthly composites.

Tritium analysis was performed on the quarterly composites. The composites were collected monthly from the locations listed below.

Location 208 Location 211 Location 215 Discharge Canal (0.45 mi. S)

Wylie Dam (4.06 mi. ESE)

River Pointe - Hwy 49 (4.21 mi. NNE)

A.4 GROUND WATER Grab samples were collected quarterly from a residential well at one location. A gamma analysis and tritium analysis were performed on each sample. The samples were collected from the location listed below.

Location 254

=

Residence (0.82 mi. N)

A.5 MILK Biweekly grab samples were collected at one location. A gamma and low-level Iodine-131 analysis was performed on each sample. The biweekly grab samples were collected from the location listed below.

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Location 221

=

Dairy (14.5 mi. NW)

A.6 BROADLEAF VEGETATION Monthly samples were collected at each of five locations. A gamma analysis was performed on each sample. The samples were collected from the locations listed below.

Location 200 Location 201 Location 222 Location 226 Location 258 Site Boundary (0.63 mi. NNE)

Site Boundary (0.53 mi. NE)

Site Boundary (0.70 mi. N)

Site Boundary (0.48 mi. S)

Fairhope Road (9.84 mi. W)

A.7 FOOD PRODUCTS Monthly samples were collected when available during the harvest season at one location. A gamma analysis was performed on each sample. The samples were collected from the location listed below.

Location 260

=

Irrigated Gardens (2.00 mi. SSE)

Appendix A - Page 4

S0 0

0 A.8 FISH 0

Semiannual samples were collected at each of two locations. A gamma analysis was performed on the edible portions of each sample. Boney fish (i.e. Sunfish) were prepared whole minus the head and tail portions.

The samples were

collected from the locations listed below.

0

Location 208

=

Discharge Canal (0.45 mi. S)

Location 216 Hwy 49 Bridge (4.19 mi. NNE) 0 A.9 SHORELINE SEDIMENT 0

Semiannual samples were collected at each of three locations.

A gamma analysis was performed on each sample following the drying and removal of 0

rocks and clams. The samples were collected from the locations listed below.

0

Location 208

=

Discharge Canal (0.45 mi. S)

Location 210

=

Ebenezer Access (2.31 mi. SE)

Location 215

=

River Pointe - Hwy 49 (4.21 mi. NNE)

A.10 DIRECT GAMMA RADIATION (TLD)

Thermoluminescent dosimeters (TLD) were collected quarterly at forty-one

locations.

A gamma exposure rate was determined for each TLD. TLD locations

are listed in Table 2.1-B. The TLDs were placed as indicated below.

An inner ring of 16 TLDs, one in each meteorological sector in the

general area of the site boundary.

0 An outer ring of 16 TLDs, one in each meteorological sector in the 6 to 8 kilometer range.

S*

The remaining TLDs were placed in special interest areas such as population centers, residential areas, schools, and at three

control locations.

A.11 ANNUAL LAND USE CENSUS 0

An Annual Land Use Census was conducted to identify within a distance of 8 kilometers (5.0 miles) from the station, the nearest location from the site boundary in each of the sixteen meteorological sectors, the following:

The Nearest Residence The Nearest Garden greater than 50 square meters or 500 square feet As Appendix A - Page 5

The Nearest Milk-giving Animal (cow, goat, etc.)

The census was conducted during the growing season from 7/10 - 7/11/2013.

Results are shown in Table 3.11.

No changes were made to the sampling procedures during 2013 as a result of the 2013 census.

V.

GLOBAL POSITIONING SYSTEM (GPS) ANALYSIS The Catawba site centerline used for GPS measurements was referenced from the Catawba Nuclear Station Updated Final Safety Analysis Report (UFSAR), section 2.1.1.1, Specification of Location.

Waypoint coordinates used for CNS GPS measurements were latitude 35°-3'-5"N and longitude 81'-4'-10"W.

Maps and tables were generated using North American Datum (NAD) 27. Data normally reflect accuracy to within 2 to 5 meters from point of measurement. All GPS field measurements were taken as close as possible to the item of interest. Distances for the locations are displayed using three significant figures.

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0 APPENDIX B RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

OF RESULTS 2013 Appendix B - Page 1

CATAWBA NUCLEAR STATION RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM DATA

SUMMARY

Catawba Nuclear Station Docket Numbers 50-413, 414 York County, South Carolina Calendar Year 2013 Location w/Highest Annual Mean Medium or Pathway Type and Lower Limit All Indicator Control Locations No. of Sampled or Measured Total No. of of Detection Locations(2) (3)

Name, Distance, Mean Mean Non-Routine (Unit of Measurement)

Measurements (LLD)(')

Mean and Direction Range(2 ) (3)

Range(2) (3)

Report Performed Range Meas.

258 (9.84 mi W)

Air Particulate Gross Beta 1.88E-2 (208/208) 212 1.91E-2 (52/52) 1.82E-2 (52/52) 0 (pCi/m3) 260 See Table 2.2-C 6.45E 3.73E-2 (3.32 E) 6.45E 3.27E-2 6.17E 3.20E-2 Gamma See Table 2.2-C All less than LLD All less than LLD 0

20 Air Radioiodine Gamma 0

(pCi/m3) 260 See Table 2.2-C All less than LLD All less than LLD 218 (13.5 mi NNE)

Drinking Water Gross Beta 4

1.79 (13/13) 214 1.79 (13/13) 1.59 (13/13) 0 (pCi/I) 26 0.89-3.03 (7.30 mi SSE) 0.89 -3.03 0.73 -2.30 Gamma All less than LLD 0

26 See Table 2.2-C All less than LLD 26 218 (13.5 mi NNE) 0 Tritium 2000 622 (4/4) 214 622 (4/4) 664 (2/4) 8 233 - 890 (7.30 mi SSE) 233 - 890 656-672 Surface Water Gamma See Table 2.2-C All less than LLD All less than LLD 0

(pCi/l) 39 Tritium 2000 4618 (8/8) 208 8615 (4/4) 215 (4.21 mi NNE) 0 12 308-14800 (0.45 mi S) 4490- 14800 402 (3/4) 159-568 Ground Water Gamma See Table 2.2-C All less than LLD All less than LLD 0

(pCi/I) 3(4)

Tritium 2000 All less than LLD No Control Location 0

3(4)

Appendix B - Page 2 OOOOOOOOOO OOOOOO0OOOOOOOO*OOOOOOOOOO0Ois

CATAWBA NUCLEAR STATION RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM DATA

SUMMARY

Catawba Nuclear Station York County, South Carolina Docket Numbers 50-413, 414 Calendar Year 2013 Location w/Highest Annual Mean Medium or Pathway Type and Lower Limit All Indicator Control Locations No. of Sampled or Measured Total No. of of Detection Locations(2 )(3 Name, Distance, Mean Mean Non-Routine (Unit of Measurement)

Measurements (LLD)"'

Mean and Direction Range(2) 3)

Range(2) (3 Report Performed Range Meas.

Milk Gamma See Table 2.2-C No Indicator Location All less than LLD 0

(pCi/l) 25(4)

M-131 See Table 2.2-C No Indicator Location All less than LLD 0

26 Broadleaf Vegetation Gamma See Table 2.2-C All less than LLD All less than LLD 0

(pCi/kg, wet) 60 Food Products Gamma See Table 2.2-C All less than LLD No Control Location 0

(pCi/kg, wet) 10 Fish Gamma See Table 2.2-C All less than LLD 0All less than LLD (pCi/kg, wet) 12 Sediments--Shoreline Gamma See Table 2.2-C All less than LLD All less than LLD (pCi/kg, dry) 6 217 (10.3 mi SSE) 0 247 (7.33 mi ESE) 251 (9.72 mi WNW)

TLD TLD Readout 18.4 (152/152) 229 24.2 (4/4) 14.5 (12/12)

(mR per quarter) s 164 12.0-26.7 (0.84 mi NW) 22.0-26.7 11.0-19.3 Appendix B - Page 3

Footnotes to Appendix B

1.

The Lower Limit of Detection (LLD) is the smallest concentration of radioactive material in a sample that will yield a net count above system background which will be detected with 95 percent probability and with only 5 percent probability of falsely concluding that a blank observation represents a "real" signal. Due to counting statistics and varying volumes, occasionally lower LLDs are achieved. Refer to Section 2.3.2 for an explanation of how LLD values were derived.

2.

Mean and range are based on detectable measurements only.

3.

The fractions of all samples with detectable activities at specific locations are indicated in parentheses.

4.

Missing samples or surveillances are discussed in Appendix C or Appendix D.

5.

TLD exposure is reported in milliroentgen (mR) per standard quarter (91 days).

Appendix B - Page 4 IIII II II II II II II II II 6

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0 APPENDIX C SAMPLING DEVIATIONS UNAVAILABLE ANALYSES Appendix C - Page 1

APPENDIX C CATAWBA NUCLEAR STATION SAMPLING DEVIATIONS & UNAVAILABLE ANALYSES DEVIATION & UNAVAILABLE REASON CODES BF Blown Fuse PO Power Outage FZ Sample Frozen PS Pump out of service / Undergoing Repair 1W Inclement Weather SL Sample Loss/Lost due to Lab Accident LC Line Clog to Sampler SM Motor / Rotor Seized OT Other TF Tom Filter P1 Power Interrupt VN Vandalism PM Preventive Maintenance CN Construction C.1 SAMPLING DEVIATIONS There were no sampling deviations noted for 2013.

C.2 UNAVAILABLE ANALYSES Ground Water Scheduled Description &

Corrective Location Collection Dates Code Action to Prevent Recurrence Action Identity Sample failed to be collected due to laboratory scheduling error. Scheduled 254 5/29/2013 OT tests were not performed.

G-13-00892 66 6

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0 APPENDIX D ANALYTICAL DEVIATIONS Appendix D - Page 1

APPENDIX D I

CATAWBA NUCLEAR STATION ANALYTICAL DEVIATIONS DEVIATION & UNAVAILABLE REASON CODES BF Blown Fuse PO Power Outage FZ Sample Frozen PS Pump out of service / Undergoing Repair 1W Inclement Weather SL Sample Loss/Lost due to Lab Accident LC Line Clog to Sampler SM Motor/ Rotor Seized OT Other TF Tom Filter PI Power Interrupt VN Vandalism PM Preventive Maintenance CN Construction AD Analytical Deviation D.1 ANALYTICAL DEVIATIONS Milk Scheduled Actual Description &

Corrective Action Location Collection Dates Collection Dates Code Action to Prevent Recurrence Identity Sample collected but not fully analyzed. Gamma spectroscopy analysis was not performed due to laboratory processing error.

221 4/9/2013 4/9/2013 AD LLI-131 analysis was performed.

G-13-00892 a0 6

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0 APPENDIX E RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM RESULTS 2013 This appendix includes sample analysis report summaries and supportive data generated from each sample medium for 2013.

Appendix E - Page 1

CATAWBA Radiological Environmental Monitoring Analysis Report-2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pClIm3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

250434 Sample Dates: 11212013.11812013 Nuclide Activity I Sigma Error LLD Beta 2.62E-02 1.72E-03 3.47E-03 Sample ID:

260664 Sample Dates: 11812013 - 111512013 Nuclide Activity I Sigma Error LLD Beta 1.58E-02 1.39E-03 3.23E-03 Sample ID:

250733 Sample Dates: 111512013 -112212013 Nuclide Activity 1 Sigma Error LLD Beta 1.36E-02 1.30E-03 3.11 E-03 Sample ID:

250981 Sample Dates: 112212013 - 1/2912013 Nuclide Activity I Sigma Error LLD Beta 2.97E-02 1.64E-03 2.94E-03 Sample ID:

251267 Sample Dates: 1/29/2013 - 2/512013 Nuclide Activity 1 Sigma Error LLD Beta 1.63E-02 1.31 E-03 2.86E-03 Sample ID:

251597 Sample Dates: 21/612013 -2112/2013 Nuclide Activity I Sigma Error LLD Beta 1.72E-02 1.33E-03 2.75E-03 Sample ID:

252063 Sample Dates: 2112/2013.211912013 Nuclide Activity i Sigma Error LLD Beta 1.85E-02 1.38E-03 2.87E-03 Sampie ID:

262680 Sample Dates: 2/1912013.212612013 Nuclide Activity 1 Sigma Error LLD Beta 1.69E-02 1.34E-03 2.95E-03 Sample ID:

253066 Sample Dates: 2126/2013 - 31512013 Nuclide Activity I Sigma Error LLD Beta 1.23E-02 1.22E-03 2.85E-03 Sample ID:

253874 Sample Dates: 31512013 -311212013 Nuclide Activity 1 Sigma Error LLD Beta 1.04E-02 1.21E-03 3.09E-03 Sample ID:

254196 Sample Dates: 3/1212013.311912013 Nuclide Activity I Sigma Error LLD Beta 1.80E-02 1.37E-03 2.93E-03 Sample ID:

254731 Sample Dates: 3/19/2013.312612013 Nuclide Activity 1 Sigma Error LLD Beta 1.86E-02 1.40E-03 2.97E-03 Sample ID:

256291 Sample Dates: 3/26/2013 - 4/212013 Nuclide Activity I Sigma Error LLD Beta 1.66E-02 1.39E-03 3.19E-03 Sample ID:

255820 Sample Dates: 412/2013 - 4/9/2013 Nuclide Activity I Sigma Error LLD Beta 2.01E-02 1.44E-03 3.01E-03 Sample ID:

256054 Sample Dates: 4/9/2013.4/1612013 Nuclide Activity I Sigma Error LLD 0

Beta 1.60E-02 1.38E-03 3.21 E-03 Sample ID:

256322 Sample Dates: 4/16/2013.4/2312013 Nuclide Activity I Sigma Error LLD Beta 1.54E-02 1.39E-03 3.26E-03 Sample ID:

256398 Sample Dates: 11212013 - 4/2/2013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.26E-02 0.00E+00 2.26E-02 Cs-134

<4.12E-04 0.00+E00 4.12E-04 S

Cs-137

<4.07E-04 0.00E+00 4.07E-04 Be-7 1.46E-01 6.87E-03 6.34E-03 0

K-40 1.07E-02 2.49E-03 5.05E-03 Sample ID:

266589 Sample Dates: 4/23/2013 - 4/3012013 Nuclide Activity 1 Sigma Error LLD Beta 1.56E-02 1.30E-03 2.84E-03 Sample ID:

267112 Sample Dates: 413012013 - 617/2013 Nuclide Activity I Sigma Error LLD Beta 8.51E-03 1.05E-03 2.59E-03 Sample ID:

257266 Sample Dates: 5/7/2013 - 5/14/2013 Nuclide Activity 1 Sigma Error LLD Beta 1.81E-02 1.36E-03 2.80E-03 Sample ID:

267712 Sample Dates: 6/14/2013 -6/21/2013 Nuclide Activity I Sigma Error LLD Beta 2.77E-02 1.61 E-03 2.97E-03 Sample ID:

257956 Sample Dates: 5/21/2013 - 6129/2013 Nuclide Activity 1 Sigma Error LLD 0

Beta 1.85E-02 1.26E-03 2.56E-03 Sample ID:

258191 Sample Dates: 5/29/2013 -6/4/2013 Nuclide Activity 1 Sigma Error LLD Beta 1.15E-02 1.44E-03 3.79E-03 S

Report Generated @ 5/1/2014 09:22:67 EnRad Laboratories Appendix E - Page 2 of 80 Duke Energy Annual Report-Appendix E E

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CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCilm3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles I Sample ID:

258538 Sample ID:

259008 Sample ID:

289656 Sample ID:

260190 Sample ID:

260650 Sample ID:

261613 Sample ID:

262115 Sample ID:

262660 Sample ID:

262949 Sample ID:

263368 Sample ID:

264016 Sample ID:

266147 Sample ID:

266456 Sample ID:

267142 Sample ID:

267692 Sample ID:

268447 Sample ID:

269570 Sample ID:

270713 Sample ID:

271438 Sample ID:

272046 Sample ID:

272428 Sample ID:

2725654 Sample Dates: 61412013 -611112013 Sample Dates: 611V2013-611812013 Sample Dates: 6/18/2013 - 6125/2013 Sample Dates: 6125/2013 -7212013 Sample Dates: 712/2013 -7/9/2013 Sample Dates: 71912013 -711612013 Sample Dates: 711612013 -712312013 Sample Dates: 412/2013 -71212013 Sample Dates: 712312013 -713012013 Sample Dates: 713012013-81612013 Sample Dates: 8/6/2013 -811312013 Sample Dates: 8/1312013 - 8/20/2013 Sample Dates: 8/20/2013 -8/27/2013 Sample Dates: 8/27/2013.91412013 Sample Dates: 91412013 -9110/2013 Sample Dates: 911012013 -9/1712013 Sample Dates: 911712013 -9/2412013 Sample Dates: 9/24/2013 -101112013 Sample Dates: 101112013 - 101812013 Sample Dates: 10/8/2013 - 10116/2013 Sample Dates: 10115/2013 - 10/22/2013 Sample Dates: 7/2/2013 - 10/112013 Nuclide Activity Beta 1.37E-02 Nuclide Activity Beta 1.67E-02 Nuclide Activity Beta 1.43E-02 Nuclide Activity Beta 1.68E-02 Nuclide Activity Beta 7.09E-03 Nuclide Activity Beta 9.41 E-03 Nuclide Activity Beta 1.02E-02 Nuclide Activity 1-131

<2.18E-02 Cs-134

<2.40E-04 Cs-137

<3.97E-04 Be-7 1.52E-01 K-40 1.56E-02 Nuclide Activity Beta 1.84E-02 Nuclide Activity Beta 2.41E-02 Nuclide Activity Beta 1.66E-02 Nuclide Activity Beta 9.72E-03 Nuclide Activity Beta 1.51E-02 Nuclide Activity Beta 3.19E-02 Nuclide Activity Beta 3.52E-02 Nuclide Activity Beta 3.03E-02 Nuclide Activity Beta 2.10E-02 Nuclide Activity Beta 2.28E-02 Nuclide Activity Beta 3.31 E-02 Nuclide Activity Beta 1.34E-02 Nuclide Activity Beta 2.91 E-02 Nuclide Activity 1-131

<2.67E-02 Cs-134

<2.52E-04 Cs-137

<2.73E-04 Be-7 1.04E-01 K-40 6.02E-03 I Sigma Error 1.30E-03 1 Sigma Error 1.39E-03 I Sigma Error 1.29E-03 1 Sigma Error 1.34E-03 1 Sigma Error 1.09E-03 I Sigma Error 1.15E-03 I Sigma Error 1.18E-03 I Sigma Error 0.OOE+00 0.00E+00 0.00E+00 5.32E-03 2.36E-03 1 Sigma Error 1.39E-03 1 Sigma Error 1.52E-03 1 Sigma Error 1.34E-03 1 Sigma Error 1.21 E-03 1 Sigma Error 1.31 E-03 1 Sigma Error 1.54E-03 1 Sigma Error 1.87E-03 I Sigma Error 1.64E-03 1 Sigma Error 1.42E-03 1 Sigma Error 1.51E-03 I Sigma Error 1.67E-03 I Sigma Error 1.26E-03 I Sigma Error 1.64E-03 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 5.02E-03 1.42E-03 LLD 3.06E-03 LLD 3.17E-03 LLD 2.95E-03 LLD 2.88E-03 LLD 2.96E-03 LLD 2.92E-03 LLD 2.98E-03 LLD 2.18E-02 2.40E-04 3.97E-04 4.88E-03 2.53E-03 LLD 2.95E-03 LLD 2.94E-03 LLD 2.94E-03 LLD 3.15E-03 LLD 2.98E-03 LLD 2.48E-03 LLD 3.13E-03 LLD 2.90E-03 LLD 2.73E-03 LLD 3.04E-03 LLD 2.71 E-03 LLD 2.96E-03 LLD 3.02E-03 LLD 2.67E-02 2.52E-04 2.73E-04 4.55E-03 2.45E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E fl

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CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCi/m3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles I Sample ID:

272829 Sample ID:

273921 Sample ID:

274368 Sample ID:

274882 Sample ID:

276436 Sample ID:

278791 Sample ID:

278862 Sample ID:

279102 Sample ID:

279730 Sample ID:

280219 Sample ID:

280591 Sample Dates: 1012212013-1012912013 Sample Dates: 1012912013 -111512013 Sample Dates: 1115/2013 - 11112/2013 Sample Dates: 11/1212013.1111912013 Sample Dates: 11/19/2013 -1112512013 Sample Dates: 1112512013.12/312013 Sample Dates: 12/312013.1211012013 Sample Dates: 1211012013 -1211712013 Sample Dates: 12/1712013 -1212312013 Sample Dates: 1212312013 - 1213112013 Sample Dates: 10/112013 - 12131/2013 Nuclide Activity Beta 2.82E-02 Nuclide Activity Beta 2.79E-02 Nuclide Activity Beta 2.19E-02 Nuclide Activity Beta 1.35E-02 Nuclide Activity Beta 1.82E-02 Nuclide Activity Beta 2.63E-02 Nuclide Activity Beta 1.22E-02 Nuclide Activity Beta 2.47E-02 Nuclide Activity Beta 1.36E-02 Nuclide Activity Beta 1.51 E-02 Nucilde Activity Cs-134

<3.72E-04 Cs-137

<3.75E-04 Be-7 1.18E-01 K-40 9.58E-03 1 Sigma Error 1.60E-03 I Sigma Error 1.62E-03 I Sigma Error 1.43E-03 I Sigma Error 1.30E-03 1 Sigma Error 1.52E-03 I Sigma Error 1.44E-03 1 Sigma Error 1.19E-03 I Sigma Error 1.58E-03 I Sigma Error 1.43E-03 I Sigma Error 1.20E-03 I Sigma Error 0.00E+00 O.00E+00 6.24E-03 2.17E-03 LLD 2.89E-03 LLD 3.07E-03 LLD 2.70E-03 LLD 3.1OE-03 LLD 3.42E-03 LLD 2.56E-03 LLD 2.78E-03 LLD 3.12E-03 LLD 3.49E-03 LLD 2.66E-03 LLD 3.72E-04 3.75E-04 4.78E-03 4.25E-03 S0 S

0 0

0 6

0 S

0 0

0 S

0 0

S Sample Point 2011 Sample ID:

250435 Sample ID:

250565 Sample ID:

250734 Sample ID:

250982 Sample ID:

251268 Sample ID:

251598 Sample ID:

252064 Sample ID:

252681 Sample ID:

253067 Sample ID:

263875 Sample ID:

254197 Sample ID:

254732 INDICATOR - NE @ 0.53 miles I Sample Dates: 112/2013 -1/812013 Sample Dates: 1/8/2013 -1115/2013 Sample Dates: 1/1512013.1/22/2013 Sample Dates: 1/2212013.112912013 Sample Dates: 1/2912013 -21512013 Sample Dates: 2/5/2013.2/1212013 Sample Dates: 2/12/2013.2119/2013 Sample Dates: 2/19/2013.2/2612013 Sample Dates: 2/26/2013.3/5/2013 Sample Dates: 3/5/2013.3/1212013 Sample Dates: 3112/2013.3/19/2013 Sample Dates: 3119/2013 - 3/2612013 Nuclide Activity Beta 2.43E-02 Nuclide Activity Beta 1.95E-02 Nuclide Activity Beta 9.88E-03 Nuclide Activity Beta 3.21 E-02 Nuclide Activity Beta 2.OOE-02 Nuclide Activity Beta 1.30E-02 Nuclide Activity Beta 1.60E-02 Nuclide Activity Beta 1.60E-02 Nuclide Activity Beta 1.23E-02 Nuclide Activity Beta 1.07E-02 Nuclide Activity Beta 1.85E-02 Nuclide Activity Beta 2.08E-02 1 Sigma Error 1.69E-03 1 Sigma Error 1.47E-03 I Sigma Error 1.21E-03 1 Sigma Error 1.68E-03 1 Sigma Error 1.41E-03 1 Sigma Error 1.21E-03 1 Sigma Error 1.32E-03 1 Sigma Error 1.32E-03 I Sigma Error 1.23E-03 I Sigma Error 1.22E-03 I Sigma Error 1.40E-03 I Sigma Error 1.44E-03 LLD 3.49E-03 LLD 3.20E-03 LLD

3. 15E-03 LLD 2.91 E-03 LLD 2.88E-03 LLD 2.72E-03 LLD 2.87E-03 LLD 2.94E-03 LLD 2.88E-03 LLD 3.07E-03 LLD 2.98E-03 LLD 2.92E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EI 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 4 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCIIm3 Sample Point 201 [INDICATOR - NE @ 0.53 miles ]

00 0

0 S

0 0

S 0

0 0

0 S

Sample ID:

255292 Sample ID:

255821 Sample ID:

256055 Sample ID:

256323 Sample ID:

256399 Sample ID:

256590 Sample ID:

257113 Sample ID:

257266 Sample ID:

257713 Sample ID:

257957 Sample ID:

258192 Sample ID:

258539 Sample ID:

269009 Sample ID:

259557 Sample ID:

260191 Sample ID:

260651 Sample ID:

261614 Sample ID:

262116 Sample ID:

262661 Sample ID:

262950 Sample ID:

263359 Sample ID:

264017 Sample Dates: 312612013 -41212013 Sample Dates: 41212013 -4/912013 Sample Dates: 41912013 -4/1612013 Sample Dates: 4/16/2013 - 4/2312013 Sample Dates: 112/2013 -42/2013 Sample Dates: 4/2312013 -413012013 Sample Dates: 413012013 - 51712013 Sample Dates: 517/2013 -5/14/2013 Sample Dates: 511412013 -512112013 Sample Dates: 5/21/2013 -5/2912013 Sample Dates: 6/2912013 -61412013 Sample Dates: 6/4/2013 - 6/11/2013 Sample Dates: 6111/2013 -6118/2013 Sample Dates: 6/18/2013 -6/2612013 Sample Dates: 6126/2013 - 712/2013 Sample Dates: 7/2/2013 - 7/9/2013 Sample Dates: 71912013 -7/16/2013 Sample Dates: 711612013 -7/2312013 Sample Dates: 4/212013 - 7/2/2013 Sample Dates: 7/23/2013 -7/30/2013 Sample Dates: 7/30/2013 -8/612013 Sample Dates: 816/2013 -8/13/2013 Nuclide Activity Beta 1.65E-02 Nuclide Activity Beta 1.88E-02 Nuclide Activity Beta 1.13E-02 Nuclide Activity Beta 1.51E-02 Nuclide Activity 1-131

<1.96E-02 Cs-134

<2.75E-04 Cs-137

<2.93E-04 Be-7 1.28E-01 K-40 1.6SE-02 Nuclide Activity Beta 1.47E-02 Nuclide Activity Beta 9.81 E-03 Nuclide Activity Beta 1.57E-02 Nuclide Activity Beta 2.69E-02 Nuclide Activity Beta 1.71E-02 Nuclide Activity Beta 1.15E-02 Nuclide Activity Beta 1.24E-02 Nuclide Activity Beta 1.56E-02 Nuclide Activity Beta 1.29E-02 Nuclide Activity Beta 1.68E-02 Nuclide Activity Beta 7.12E-03 Nuclide Activity Beta 7.37E-03 Nuclide Activity Beta 1.36E-02 Nuclide Activity 1-131

<2.42E-02 Cs-134

<2.52E-04 Cs-137

<2.92E-04 Be-7 1.44E-01 K-40 8.08E-03 Nuclide Activity Beta 2.07E-02 Nuclide Activity Beta 2.79E-02 Nuclide Activity Beta 1.87E-02 1 Sigma Error 1.40E-03 I Sigma Error 1.41E-03 i Sigma Error 1.28E-03 i Sigma Error 1.36E-03 1 Sigma Error 0.00E+00 0.00E+00 0.OOE+00 4.86E-03 2.15E-03 1 Sigma Error 1.29E-03 I Sigma Error 1.09E-03 1 Sigma Error 1.30E-03 I Sigma Error 1.58E-03 I Sigma Error 1.24E-03 I Sigma Error 1.42E-03 I Sigma Error 1.26E-03 1 Sigma Error 1.37E-03 1 Sigma Error 1.25E-03 1 Sigma Error 1.35E-03 I Sigma Error 1.09E-03 1 Sigma Error 1.09E-03 1 Sigma Error 1.28E-03 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 5.79E-03 2.50E-03 1 Sigma Error 1.44E-03 1 Sigma Error 1.60E-03 1 Sigma Error 1.39E-03 LLD 3.21 E-03 LLD 3.02E-03 LLD 3.27E-03 LLD 3.20E-03 LLD 1.96E-02 2.75E-04 2.93E-04 4.61 E-03 2.67E-03 LLD 2.88E-03 LLD 2.57E-03 LLD 2.80E-03 LLD 2.95E-03 LLD 2.59E-03 LLD 3.71E-03 LLD 3.05E-03 LLD 3.17E-03 LLD 2.94E-03 LLD 2.90E-03 LLD 2.96E-03 LLD 2.94E-03 LLD 2.99E-03 LLD 2.42E-02 2.52E-04 2.92E-04 4.24E-03 4.43E-03 LLD 2.93E-03 LLD 2.96E-03 LLD 2.95E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E1

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 5 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pClIm3 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

Sample ID:

265148 Sample ID:

Sample ID:

266457 267143 267593 268448 269571 270714 271439 272046 272429 272555 272830 273922 274369 274883 276437 278766 278837 279077 279705 280194 280592 Sample Dates: 811312013 -812012013 Sample Dates: 8/2012013-812712013 Sample Dates: 812712013 - 914/2013 Sample Dates: 914/2013 -911012013 Sample Dates: 9/1012013 -9/1712013 Sample Dates: 9117/2013 - 9124/2013 Sample Dates: 9124/2013 - 101112013 Sample Dates: 101112013 -101812013 Sample Dates: 10/812013 -10115/2013 Sample Dates: 10115/2013 -10122/2013 Sample Dates: 7/2/2013-1011/2013 Sample Dates: 10/22/2013 -10129/2013 Sample Dates: 10/29/2013 - 1116/2013 Sample Dates: 1115/2013 -11112/2013 Sample Dates: 11/12/2013 -11119/2013 Sample Dates: 11/19/2013 - 11/25/2013 Sample Dates: 11125/2013 - 12/312013 Sample Dates: 12/312013 - 12110/2013 Sample Dates: 12/1012013 - 12/17/2013 Sample Dates: 12/17/2013 - 1212312013 Sample Dates: 12/2312013 - 12/31/2013 Sample Dates: 10/1/2013 - 12/31/2013 Nuclide Activity 1 Sigma Error Beta 8.61E-03 1.19E-03 Nuclide Activity 1 Sigma Error Beta 1.40E-02 1.27E-03 Nuclide Activity 1 Sigma Error Beta 3.24E-02 1.56E-03 Nuclide Activity I Sigma Error Beta 3.73E-02 1.92E-03 Nuclide Activity 1 Sigma Error Beta 2.95E-02 1.63E-03 Nuclide Activity i Sigma Error Beta 2.46E-02 1.49E-03 Nuclide Activity I Sigma Error Beta 1.80E-02 1,39E-03 Nuclide Activity 1 Sigma Error Beta 2.78E-02 1.56E-03 Nuclide Activity 1 Sigma Error Beta 9.71E-03 1.17E-03 Nuclide Activity I Sigma Error Beta 2.31E-02 1.51E-03 Nuclide Activity I Sigma Error 1-131

<2.75E-02 0.OOE+00 Cs-134

<3.88E-04 0.OOE+00 Cs-137

<3.37E-04 O.OOE+O0 Be-7 1.01E-01 5.82E-03 K-40 1.25E-02 2.14E-03 Nuclide Activity I Sigma Error Beta 2.94E-02 1.63E-03 Nuclide Activity 1 Sigma Error Beta 2.84E-02 1.63E-03 Nuclide Activity I Sigma Error Beta 2.10E-02 1.41E-03 Nuclide Activity 1 Sigma Error Beta 1.65E-02 1.37E-03 Nuclide Activity 1 Sigma Error Beta 1.37E-02 1.41E-03 Nuclide Activity 1 Sigma Error Beta 2.53E-02 1.42E-03 Nuclide Activity I Sigma Error Beta 1.21E-02 1.20E-03 Nuclide Activity 1 Sigma Error Beta 2.55E-02 1.58E-03 Nuclide Activity I Sigma Error Beta 1.66E-02 1.50E-03 Nuclide Activity I Sigma Error Beta 1.73E-02 1.27E-03 Nuclide Activity 1 Sigma Error Cs-134

<2.53E-04 O.OOE+00 Cs-137

<2.97E-04 O.OOE+00 Be-7 1.27E-01 4.70E-03 K-40 1.93E-02 2.31E-03 LLD 3.17E-03 LLD 2.94E-03 LLD 2.49E-03 LLD 3.13E-03 LLD 2.90E-03 LLD 2.72E-03 LLD 3.04E-03 LLD 2.71 E-03 LLD 2.98E-03 LLD 3.01 E-03 LLD 2.75E-02 3.88E-04 3.37E-04 5.37E-03 4.24E-03 LLD 2.89E-03 LLD 3.06E-03 LLD 2.72E-03 LLD 3.07E-03 LLD 3.44E-03 LLD 2.54E-03 LLD 2.83E-03 LLD 3.07E-03 LLD 3.48E-03 LLD 2.71 E-03 LLD 2.53E-04 2.97E-04 3.63E-03 3.OOE-03 I

6 6

0 0

0 S

S S

0 0

0 S

0 4

4 4

is is is 4

4 is Is 4

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 6 of 80

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR PARTICULATE Concentration (Activity): pCI/m3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

00 0

0 S

0 0

0 S

0 0

S 0

0 0

Sample ID:

250436 Sample ID:

260566 Sample ID:

250735 Sample ID:

260983 Sample ID:

251269 Sample ID:

251599 Sample ID:

252065 Sample ID:

252682 Sample ID:

253068 Sample ID:

253876 Sample ID:

254198 Sample ID:

254733 Sample ID:

255293 Sample ID:

255822 Sample ID:

266056 Sample ID:

256324 Sample ID:

256400 Sample ID:

266591 Sample ID:

257114 Sample ID:

257267 Sample ID:

257714 Sample ID:

257958 Sample ID:

258193 Sample Dates: 112/2013 - 11812013 Sample Dates: 11812013 - 1/1512013 Sample Dates: 111512013 -1/22/2013 Sample Dates: 1/22/2013 - 112912013 Sample Dates: 1129(2013 - 2(5/2013 Sample Dates: 2/5/2013 - 2/1212013 Sample Dates: 2/12/2013 - 2/19/2013 Sample Dates: 2/19/2013 - 2126/2013 Sample Dates: 212612013-31512013 Sample Dates: 315/2013 - 3112/2013 Sample Dates: 3112/2013 -311912013 Sample Dates: 3119/2013.312612013 Sample Dates: 3/26/2013.4/2/2013 Sample Dates: 4/2/2013.41912013 Sample Dates: 419/2013.4/1612013 Sample Dates: 4/16/2013.4/23/2013 Sample Dates: 11212013 -4/2/2013 Sample Dates: 4/23/2013 -413012013 Sample Dates: 4(3012013 - 5/7/2013 Sample Dates: 5/7/2013 - 5/14/2013 Sample Dates: 6/14/2013 - 6/21/2013 Sample Dates: 5/2112013 -6/29/2013 Sample Dates: 6/29/2013 -61412013 Nuclide Activity Beta 2.76E-02 Nuclide Activity Beta 2.02E-02 Nuclide Activity Beta 1.17E-02 Nuclide Activity Beta 3.07E-02 Nuctide Activity Beta 1.51 E-02 Nuclide Activity Beta 1.66E-02 Nuclide Activity Beta 1.83E-02 Nuclide Activity Beta 1.62E-02 Nuclide Activity Beta 1.39E-02 Nuclide Activity Beta 1.22E-02 Nuclide Activity Beta 2.1OE-02 Nuclide Activity Beta 1.91E-02 Nuclide Activity Beta 1.61E-02 Nuclide Activity Beta 1.83E-02 Nuclide Activity Beta 1.27E-02 Nuclide Activity Beta 1.70E-02 Nuclide Activity 1-131

<2.03E-02 Cs-134

<3.13E-04 Cs-137

<2.75E-04 Be-7 1.38E-01 K-40 7.12E-03 Nuclide Activity Beta 1.65E-02 Nuclide Activity Beta 9.26E-03 Nuclide Activity Beta 1.76E-02 Nuclide Activity Beta 2.74E-02 Nuclide Activity Beta 1.74E-02 Nuclide Activity Beta 1.05E-02 I Sigma Error 1.76E-03 1 Sigma Error 1.49E-03 I Sigma Error 1.25E-03 1 Sigma Error 1.66E-03 I Sigma Error 1.29E-03 I Sigma Error 1.31E-03 I Sigma Error 1.37E-03 I Sigma Error 1.33E-03 1 Sigma Error 1.26E-03 1 Sigma Error 1.26E-03 I Sigma Error 1.46E-03 I Sigma Error 1.40E-03 1 Sigma Error 1.38E-03 1 Sigma Error 1.40E-03 1 Sigma Error 1.33E-03 1 Sigma Error 1.41 E-03 1 Sigma Error O.OOE+00 0.00E+00 0.00E+00 5.91 E-03 2.11E-03 I Sigma Error 1.32E-03 I Sigma Error 1.08E-03 I Sigma Error 1.35E-03 1 Sigma Error 1.59E-03 I Sigma Error 1.24E-03 I Sigma Error 1.42E-03 LLD 3.46E-03 LLD 3.23E-03 LLD 3.11E-03 LLD 2.94E-03 LLD 2.86E-03 LLD 2.75E-03 LLD 2.87E-03 LLD 2.96E-03 LLD 2.85E-03 LLD 3.09E-03 LLD 2.98E-03 LLD 2.91 E-03 LLD 3.19E-03 LLD 3.03E-03 LLD 3.32E-03 LLD 3.20E-03 LLD 2.03E-02 3.13E-04 2.75E-04 4.32E-03 4.44E-03 LLD 2.84E-03 LLD 2.61 E-03 LLD 2.80E-03 LLD 2.96E-03 LLD 2.55E-03 LLD 3.79E-03 Report Generated @ 5/112014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ED 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 7 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCilm3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

Sample ID:

258540 Sample ID:

259010 Sample ID:

2695658 Sample ID:

260192 Sample ID:

260652 Sample ID:

261615 Sample ID:

262117 Sample ID:

262662 Sample ID:

262951 Sample ID:

263360 Sample ID:

264018 Sample ID:

266149 Sample ID:

265468 Sample ID:

267144 Sample ID:

267594 Sample ID:

268449 Sample ID:

269572 Sample ID:

270715 Sample ID:

271440 Sample ID:

272047 Sample ID:

272430 Sample ID:

272556 Sample Dates: 61412013.611112013 Sample Dates: 611112013-611812013 Sample Dates: 611812013 -6/2512013 Sample Dates: 6125/2013 -712/2013 Sample Dates: 712/2013 -71912013 Sample Dates: 71912013 - 711612013 Sample Dates: 711612013 -712312013 Sample Dates: 41212013 -71212013 Sample Dates: 7/23/2013 -713012013 Sample Dates: 713012013 -81612013 Sample Dates: 8/612013 -8/1312013 Sample Dates: 8/13/2013 - 8/20/2013 Sample Dates: 8/2012013 -8/27/2013 Sample Dates: 8127/2013 -914/2013 Sample Dates: 914/2013 -9/1012013 Sample Dates: 9/10/2013 -9117/2013 Sample Dates: 9/17/2013 - 9124/2013 Sample Dates: 9124/2013 -101112013 Sample Dates: 1011/2013 -10/812013 Sample Dates: 10/8/2013 - 10115/2013 Sample Dates: 10/15/2013 - 10/22/2013 Sample Dates: 712/2013 - 10/1/2013 Nuclide Activity i Sigma Error LLD Beta 1.22E-02 1.25E-03 3.05E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.61E-02 1.38E-03 3.16E-03 Nuclide Activity I Sigma Error LLD Beta 1.59E-02 1.34E-03 2.98E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.46E-02 1.28E-03 2.86E-03 Nuclide Activity 1 Sigma Error LLD Beta 8.53E-03 1.13E-03 2.95E-03 Nuclide Activity I Sigma Error LLD Beta 8.79E-03 1.13E-03 2.93E-03 Nuclide Activity I Sigma Error LLD Beta 1.08E-02 1.20E-03 2.97E-03 Nuclide Activity 1 Sigma Error LLD 1-131

<2.23E-02 0.00E+00 2.23E-02 Cs-134

<2.40E-04 0.OOE+00 2.40E-04 Cs-137

<2.95E-04 0.00E+00 2.95E-04 Be-7 1.41E-01 5.29E-03 4.02E-03 K-40 2.28E-02 2.52E-03 2.85E-03 Nuclide Activity I Sigma Error LLD Beta 2.06E-02 1.45E-03 2.95E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.35E-02 1.50E-03 2.94E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.63E-02 1.34E-03 2.94E-03 Nuclide Activity 1 Sigma Error LLD Beta 8.01E-03 1.16E-03 3.14E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.67E-02 1.35E-03 2.98E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.91E-02 1.48E-03 2.47E-03 Nuclide Activity I Sigma Error LLD Beta 3.50E-02 1.87E-03 3.14E-03 Nuclide Activity 1 Sigma Error LLD Beta 3.22E-02 1.68E-03 2.90E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.53E-02 1.52E-03 2.73E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.92E-02 1.43E-03 3.04E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.80E-02 1.57E-03 2.71E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.12E-02 1.20E-03 2.96E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.95E-02 1.65E-03 3.02E-03 Nuclide Activity I Sigma Error LLD 1-131

<2.00E-02 0.00E+00 2.00E-02 Cs-134

<2.54E-04 0.00E+00 2.54E-04 Cs-137

<2.35E-04 0.00E+00 2.35E-04 Be-7 9.96E-02 4.24E-03 3.87E-03 K-40 2.53E-02 2.67E-03 3.09E-03 00 6

6 0

0 0

S S

0 0

0 S

0 0

0 S

0 Appendix E - Page 8 of 80 S

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories IEn 13339 Hagers Ferry Road Huntersville, North Carolina 28078

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCIlm3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles I 00 S

0 0

S 0

0 S

0 0

0 Sample ID:

272831 Sample ID:

273923 Sample ID:

274370 Sample ID:

274884 Sample ID:

276438 Sample ID:

278758 Sample ID:

278829 Sample ID:

279069 Sample ID:

279697 Sample ID:

280186 Sample ID:

280593 Sample Point 212 [

Sample ID:

250437 Sample ID:

250567 Sample ID:

250736 Sample ID:

250984 Sample ID:

251270 Sample ID:

251600 Sample ID:

252066 Sample ID:

252683 Sample ID:

253069 Sample ID:

253877 Sample ID:

254199 Sample ID:

254734 Sample Dates: 1012212013 -1012912013 Sample Dates: 1012912013 -111512013 Sample Dates: 1116/2013 - 11112/2013 Sample Dates: 11112/2013 -1111912013 Sample Dates: 11/19/2013 -1112512013 Sample Dates: 1112512013-12/312013 Sample Dates: 121312013 - 12110/2013 Sample Dates: 1211012013 - 1211712013 Sample Dates: 1211712013-12/2312013 Sample Dates: 12/2312013 -1213112013 Sample Dates: 1011/2013 - 12131/2013 INDICATOR - E @ 3.32 miles ]

Sample Dates: 11212013 -1/8/2013 Sample Dates: 1/812013 - 1/15/2013 Sample Dates: 1115/2013 -112212013 Sample Dates: 1122/2013 - 112912013 Sample Dates: 1/29/2013 - 2/52013 Sample Dates: 2/512013 - 2/12/2013 Sample Dates: 211212013 - 2/1912013 Sample Dates: 2/19/2013 - 2/26/2013 Sample Dates: 2/26/2013 - 35/2013 Sample Dates: 3/5/2013 - 3/1212013 Sample Dates: 3/12/2013. 3/19/2013 Sample Dates: 3/19/2013 - 3/26/2013 Nuclide Activity Beta 2.78E-02 Nuclide Activity Beta 3.08E-02 Nuclide Activity Beta 2.29E-02 Nuclide Activity Beta 1.82E-02 Nuclide Activity Beta 1.35E-02 Nuclide Activity Beta 2.27E-02 Nuclide Activity Beta 1.28E-02 Nuclide Activity Beta 2.85E-02 Nuclide Activity Beta 1.81E-02 Nuclide Activity Beta 2.09E-02 Nuclide Activity Cs-134

<2.60E-04 Cs-137

<3.42E-04 Be-7 1.25E-01 K-40 1.04E-02 1 Sigma Error 1.59E-03 1 Sigma Error 1.68E-03 I Sigma Error 1.45E-03 I Sigma Error 1.42E-03 1 Sigma Error 1.40E-03 i Sigma Error 1.35E-03 1 Sigma Error 1.23E-03 1 Sigma Error 1.64E-03 I Sigma Error 1.55E-03 1 Sigma Error 1.34E-03 I Sigma Error 0.00E+00 0.00E+00 6.35E-03 1.86E-03 LLD 2.89E-03 LLD 3.07E-03 LLD 2.70E-03 LLD 3.10E-03 LLD 3.42E-03 LLD 2.51 E-03 LLD 2.87E-03 LLD 3.08E-03 LLD 3.51 E-03 LLD 2.69E-03 LLD 2.60E-04 3.42E-04 4.45E-03 3.18E-03 Nuclide Activity Beta 2.89E-02 Nuclide Activity Beta 1.92E-02 Nuclide Activity Beta 1.16E-02 Nuclide Activity Beta 3.17E-02 Nuclide Activity Beta 2.05E-02 Nuclide Activity Beta 1.59E-02 Nuclide Activity Beta 1.77E-02 Nuclide Activity Beta 1.71E-02 Nucllde Activity Beta 1.40E-02 Nuclide Activity Beta 1,12E-02 Nuclide Activity Beta 2.32E-02 Nuclide Activity Beta 1.88E-02 I Sigma Error 1.78E-03 i Sigma Error 1.48E-03 1 Sigma Error 1.25E-03 1 Sigma Error 1.68E-03 1 Sigma Error 1.41 E-03 1 Sigma Error 1.30E-03 1 Sigma Error 1.36E-03 I Sigma Error 1.35E-03 1 Sigma Error 1.26E-03 I Sigma Error 1.24E-03 1 Sigma Error 1.49E-03 1 Sigma Error 1.41 E-03 LLD 3.46E-03 LLD 3.25E-03 LLD 3.11E-03 LLD 2.94E-03 LLD 2.85E-03 LLD 2.77E-03 LLD 2.87E-03 LLD 2.96E-03 LLD 2.84E-03 LLD 3.11E-03 LLD 2.93E-03 LLD 2.97E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 9 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCi/m3 Sample Point 212 [ INDICATOR - E @ 3.32 miles ]

Sample ID:

255294 Sample ID:

255823 Sample ID:

256057 Sample ID:

256325 Sample ID:

256401 Sample ID:

256592 Sample ID:

257115 Sample ID:

257268 Sample ID:

257715 Sample ID:

257959 Sample ID:

258194 Sample 10:

258541 Sample ID:

259011 Sample ID:

259559 Sample ID:

260193 Sample ID:

260653 Sample ID:

261616 Sample ID:

262118 Sample ID:

262663 Sample ID:

263134 Sample ID:

263361 Sample ID:

264019 Sample Dates: 3/2612013 - 4/2/2013 Sample Dates: 412/2013 - 4/912013 Sample Dates: 4/912013 -4/16/2013 Sample Dates: 4/1612013 -4/2312013 Sample Dates: 112/2013 -4/2/2013 Sample Dates: 4/23/2013 -4/3012013 Sample Dates: 413012013 - 5/7/2013 Sample Dates: 5/712013 - 5114/2013 Sample Dates: 6/1412013 - 5/2112013 Sample Dates: 512112013 - 5/2912013 Sample Dates: 6129/2013 -61412013 Sample Dates: 614/2013 - 611112013 Sample Dates: 6/11/2013 -6/18/2013 Sample Dates: 6/18/2013 -6/25/2013 Sample Dates: 6125/2013 -712/2013 Sample Dates: 712/2013 -719/2013 Sample Dates: 7/9/2013 -711612013 Sample Dates: 7116/2013 -7123/2013 Sample Dates: 4/212013 -71212013 Sample Dates: 712312013 -713012013 Sample Dates: 713012013-8/6/2013 Sample Dates: 816/2013 -8/13/2013 Nuclide Activity I Sigma Error LLD Beta 1.71E-02 1.40E-03 3.18E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.06E-02 1.46E-03 3.02E-03 Nuclide Activity I Sigma Error LLD Beta 1.41E-02 1.34E-03 3.24E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.50E-02 1.38E-03 3.27E-03 Nuclide Activity I Sigma Error LLD 1-131

<5.54E-02 0.00E+00 5.54E-02 Cs-134

<7.93E-04 0.00E+00 7.93E-04 Cs-137

<5.96E-04 O.OOE+00 5.96E-04 Be-7 1.43E-01 9.30E-03 1.08E-02 K-40 1.66E-02 4.75E-03 8.65E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.68E-02 1.32E-03 2.82E-03 Nuclide Activity I Sigma Error LLD Beta 1.13E-02 1.14E-03 2.61E-03 Nuclide Activity I Sigma Error LLD Beta 1.84E-02 1.36E-03 2.80E-03 Nuclide Activity I Sigma Error LLD Beta 2.83E-02 1.62E-03 2.97E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.80E-02 1.25E-03 2.55E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.34E-02 1.50E-03 3.80E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.35E-02 1.29E-03 3.07E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.78E-02 1.41E-03 3.16E-03 Nuclide Activity I Sigma Error LLD Beta 1.44E-02 1.29E-03 2.95E-03 Nuclide Activity I Sigma Error LLD Beta 1.41E-02 1.27E-03 2.89E-03 Nuclide Activity 1 Sigma Error LLD Beta 6.45E-03 1.07E-03 2.96E-03 Nuclide Activity I Sigma Error LLD Beta 1.02E-02 1.17E-03 2.93E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.00E-02 1.17E-03 2.96E-03 Nuclide Activity 1 Sigma Error LLD 1-131

<2.73E-02 0.00E+00 2.73E-02 Cs-134

<1.60E-04 0.OOE+00 1.60E-04 Cs-137

<1.58E-04 0.00E+00 1.58E-04 Be-7 1.47E-01 3.43E-03 2.42E-03 K-40 8.01E-03 1.23E-03 2.07E-03 Nuclide Activity I Sigma Error LLD Beta 2.20E-02 1,48E-03 2.97E-03 Nuclide Activity I Sigma Error LLD Beta 2.39E-02 1.52E-03 2.94E-03 Nuclide Activity 1 Sigma Error LLD 6

0 0

0 6

0 S

0 0

S S

0 S

0 0

0 o

0 0

S 0

0 0

0 Beta 1.64E-02 1.34E-03 2.95E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EI n 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 10 of 80 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCIlm3 Sample Point 212 [ INDICATOR - E @ 3.32 miles ]

0 0

S 0

0 0

0 S

0 0

0 Sample ID:

265180 Sample ID:

266459 Sample ID:

267145 Sample ID:

267895 Sample ID:

268450 Sample ID:

269873 Sample ID:

270716 Sample ID:

271441 Sample ID:

272048 Sample ID:

272431 Sample ID:

272557 Sample ID:

272832 Sample ID:

273924 Sample ID:

274371 Sample ID:

274885 Sample ID:

276439 Sample ID:

278759 Sample ID:

278830 Sample ID:

279070 Sample ID:

279698 Sample ID:

280187 Sample ID:

280595 Sample Dates: 811312013 -812012013 Sample Dates: 812012013 - 812712013 Sample Dates: 812712013 -914/2013 Sample Dates: 91412013 -911012013 Sample Dates: 9110/2013 - 9/17/2013 Sample Dates: 911712013 - 9/24/2013 Sample Dates: 9/24/2013 - 1011/2013 Sample Dates: 101112013 -101812013 Sample Dates: 1018/2013 - 1011512013 Sample Dates: 1011512013 -1012212013 Sample Dates: 712120`13.101112013 Sample Dates: 10/22/2013 - 1012912013 Sample Dates: 10/2912013 -11/512013 Sample Dates: 11/5/2013 -1111212013 Sample Dates: 11112/2013-1111912013 Sample Dates: 1111912013 - 11/2612013 Sample Dates: 11126/2013 -12/312013 Sample Dates: 12/3/2013 - 1211012013 Sample Dates: 12/10/2013 - 12/17/2013 Sample Dates: 12/17/2013 - 12/23/2013 Sample Dates: 12/23/2013 - 12/3112013 Sample Dates: 10/1/2013-12/31/2013 Nuclide Activity Beta 1.01 E-02 Nuclide Activity Beta 1.40E-02 Nuclide Activity Beta 3.01 E-02 Nuclide Activity Beta 3.27E-02 Nuclide Activity Beta 2.72E-02 Nuclide Activity Beta 2.71 E-02 Nuclide Activity Beta 1.93E-02 Nuclide Activity Beta 3.13E-02 Nuclide Activity Beta 1.15E-02 Nuclide Activity Beta 2.79E-02 Nuclide Activity 1-131

<2.22E-02 Cs-134

<2.59E-04 Cs-137

<2.95E-04 Be-7 1.02E-01 K-40 7.70E-03 Nuclide Activity Beta 2.78E-02 Nuclide Activity Beta 2.75E-02 Nuclide Activity Beta 2.56E-02 Nuclide Activity Beta 1.36E-02 Nuclide Activity Beta 1.57E-02 Nuclide Activity Beta 2.76E-02 Nuclide Activity Beta 1.20E-02 Nuclide Activity Beta 2.64E-02 Nuclide Activity Beta 1.59E-02 Nuclide Activity Beta 1.79E-02 Nuclide Activity Cs-134

<2.54E-04 Cs-137

<2.20E-04 Be-7 1.20E-01 K-40 1.68E-02 I Sigma Error 1.22E-03 I Sigma Error 1.30E-03 i Sigma Error 1.50E-03 1 Sigma Error 1.82E-03 1 Sigma Error 1,57E-03 I Sigma Error 1.56E-03 I Sigma Error 1.43E-03 1 Sigma Error 1.64E-03 I Sigma Error 1.21E-03 1 Sigma Error 1.62E-03 I Sigma Error 0.00E+00 O.OOE+00 0.OOE+00 4.81 E-03 2.35E-03 I Sigma Error 1.59E-03 1 Sigma Error 1.61 E-03 1 Sigma Error 1.50E-03 1 Sigma Error 1.32E-03 1 Sigma Error 1.45E-03 I Sigma Error 1.47E-03 I Sigma Error 1.18E-03 1 Sigma Error 1.62E-03 1 Sigma Error 1.47E-03 I Sigma Error 1.27E-03 I Sigma Error 0.OOE+00 0.OOE+00 4.63E-03 2.36E-03 LLD 3.14E-03 LLD 3.03E-03 LLD 2.45E-03 LLD 3.13E-03 LLD 2.88E-03 LLD 2.75E-03 LLD 3.04E-03 LLD 2.71 E-03 LLD 2.93E-03 LLD 3.05E-03 LLD 2.22E-02 2.59E-04 2.95E-04 4.OOE-03 4.82E-03 LLD 2.88E-03 LLD 3.08E-03 LLD 2.68E-03 LLD 3.13E-03 LLD 3.42E-03 LLD 2.55E-03 LLD 2.77E-03 LLD 3.14E-03 LLD 3.46E-03 LLD 2.68E-03 LLD 2.54E-04 2.20E-04 4.18E-03 3.38E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ED 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 11 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCi/m3 Sample Point 258 [ CONTROL - W @ 9.84 miles ]

Sample ID:

250438 Sample ID:

250568 Sample ID:

250737 Sample ID:

250985 Sample ID:

251271 Sample ID:

251601 Sample ID:

252067 Sample ID:

252684 Sample ID:

253070 Sample ID:

253878 Sample ID:

254200 Sample ID:

254735 Sample ID:

256295 Sample ID:

255824 Sample ID:

256058 Sample 10:

256326 Sample ID:

256402 Sample ID:

256593 Sample ID:

267116 Sample ID:

257269 Sample ID:

267716 Sample ID:

257960 Sample ID:

268195 Sample Dates: 112/2013 -11812013 Sample Dates: 11812013 - 1/15/2013 Sample Dates: 1/16/2013 - 1122/2013 Sample Dates: 1122/2013 -1/29/2013 Sample Dates: 1/29/2013 -2/512013 Sample Dates: 215/2013 -2/12/2013 Sample Dates: 2112/2013 - 211912013 Sample Dates: 2/1912013 - 2/26/2013 Sample Dates: 212612013-315/2013 Sample Dates: 31512013-3112/2013 Sample Dates: 3/12/2013 -3/19/2013 Sample Dates: 3/19/2013 -3/2612013 Sample Dates: 312612013.412/2013 Sample Dates: 41212013 -41912013 Sample Dates: 4/912013 -4/1612013 Sample Dates: 4/1612013 -4/2312013 Sample Dates: 11212013 -41212013 Sample Dates: 4/2312013 - 4/3012013 Sample Dates: 4/30/2013 -5/712013 Sample Dates: 6/7/2013 -5/14/2013 Sample Dates: 6/14/2013 -5/2112013 Sample Dates: 5/21/2013 - 512912013 Sample Dates: 6/29/2013 -6/412013 Nuclide Activity Beta 2.60E-02 Nuclide Activity Beta 1.61E-02 Nuclide Activity Beta 1.06E-02 Nuclide Activity Beta 2.81E-02 Nuclide Activity Beta 1.78E-02 Nuclide Activity Beta 1.53E-02 Nuclide Activity Beta 1.71E-02 Nuclide Activity Beta 1.56E-02 Nuclide Activity Beta 1.25E-02 Nuclide Activity Beta 9.25E-03 Nuclide Activity Beta 2.16E-02 Nuclide Activity Beta 1.81E-02 Nuclide Activity Beta 1.55E-02 Nuclide Activity Beta 1.95E-02 Nuclide Activity Beta 1.44E-02 Nuclide Activity Beta 1.61E-02 Nuclide Activity 1-131

<2.36E-02 Cs-134

<3.48E-04 Cs-137

<3.57E-04 Be-7 1.42E-01 K-40 1.66E-02 Nuclide Activity Beta 1.42E-02 Nuclide Activity Beta 1.08E-02 Nuclide Activity Beta 1.58E-02 Nuclide Activity Beta 2.55E-02 Nuclide Activity Beta 1.63E-02 Nuclide Activity Beta 1.31E-02 1 Sigma Error 1.73E-03 1 Sigma Error 1.39E-03 1 Sigma Error 1.24E-03 1 Sigma Error 1.60E-03 1 Sigma Error 1.36E-03 I Sigma Error 1.27E-03 I Sigma Error 1.35E-03 I Sigma Error 1.33E-03 I Sigma Error 1.21E-03 1 Sigma Error 1.17E-03 I Sigma Error 1.47E-03 1 Sigma Error 1.37E-03 1 Sigma Error 1.37E-03 I Sigma Error 1.42E-03 I Sigma Error 1.36E-03 1 Sigma Error 1.38E-03 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 5.36E-03 2.48E-03 1 Sigma Error 1.27E-03 1 Sigma Error 1.12E-03 1 Sigma Error 1.30E-03 1 Sigma Error 1.55E-03 I Sigma Error 1.23E-03 1 Sigma Error 1.47E-03 LLD 3.48E-03 LLD 3.20E-03 LLD 3.15E-03 LLD 2.91 E-03 LLD 2.90E-03 LLD 2.71E-03 LLD 2.88E-03 LLD 3.01 E-03 LLD 2.82E-03 LLD 3.06E-03 LLD 2.99E-03 LLD 2.92E-03 LLD 3.20E-03 LLD 2.99E-03 LLD 3.29E-03 LLD 3.18E-03 LLD 2.36E-02 3.48E-04 3.57E-04 4.64E-03 3.50E-03 LLD 2.88E-03 LLD 2.58E-03 LLD 2.79E-03 LLD 2.95E-03 LLD 2.59E-03 LLD 3.72E-03 I

6 6

6 0

0 0

6 0

0 6

0 S

0 0

0 S

0 0

S 0

0 0

Report Generated @ 51112014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 12 of 80 SS

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pClIm3 Sample Point 258 [ CONTROL - W @ 9.84 miles I 00 S

0 S

S 0

0 S

0 0

0 S

0 0

0 Sample ID:

258542 Sample ID:

259012 Sample ID:

259560 Sample ID:

260194 Sample ID:

260654 Sample ID:

261617 Sample ID:

262119 Sample ID:

262664 Sample ID:

263135 Sample ID:

263362 Sample ID:

264020 Sample ID:

265151 Sample ID:

265460 Sample ID:

267146 Sample ID:

267596 Sample ID:

268451 Sample ID:

269574 Sample ID:

270717 Sample ID:

271442 Sample ID:

272049 Sample ID:

272432 Sample ID:

272558 Sample Dates: 61412013-611112013 Sample Dates: 6/11/2013-611812013 Sample Dates: 6/18/2013 -6/25/2013 Sample Dates: 6125/2013-712/2013 Sample Dates: 712/2013 -71912013 Sample Dates: 71912013.711612013 Sample Dates: 711612013 -712312013 Sample Dates: 4/2/2013 -7/2/2013 Sample Dates: 712312013 -713012013 Sample Dates: 713012013 -81612013 Sample Dates: 81612013 -811312013 Sample Dates: 8/13/2013 -812012013 Sample Dates: 8/20/2013 -8/27/2013 Sample Dates: 8/27/2013 -91412013 Sample Dates: 914/2013 -9/1012013 Sample Dates: 9110/2013 -911712013 Sample Dates: 9/17/2013 - 9/24/2013 Sample Dates: 9124/2013 - 10/112013 Sample Dates: 10/1/2013 - 10/8/2013 Sample Dates: 10/8/2013 - 10/16/2013 Sample Dates: 10/15/2013 - 10/2212013 Sample Dates: 71212013 -10/112013 Nuclide Activity Beta 1.13E-02 Nuclide Activity Beta 1.79E-02 Nuclide Activity Beta 1.28E-02 Nuclide Activity Beta 1.57E-02 Nuclide Activity Beta 6.17E-03 Nuclide Activity Beta 8.93E-03 Nuclide Activity Beta 1.13E-02 Nuclide Activity 1-131

<6.95E-02 Cs-134

<8.84E-04 Cs-137

<9.39E-04 Be-7 1.45E-01 K-40 2.26E-02 Nuclide Activity Beta 1.91 E-02 Nuclide Activity Beta 2.41 E-02 Nuclide Activity Beta 1.44E-02 Nuclide Activity Beta 9.96E-03 Nuclide Activity Beta 1.65E-02 Nuclide Activity Beta 3.11E-02 Nuclide Activity Beta 3.20E-02 Nuclide Activity Beta 3.09E-02 Nuclide Activity Beta 2.37E-02 Nuclide Activity Beta 2.09E-02 Nuclide Activity Beta 2.93E-02 Nuclide Activity Beta 1.23E-02 Nuclide Activity Beta 2.56E-02 Nucilde Activity 1-131

<6.77E-02 Cs-I 34

<9.75E-04 Cs-137

<8.85E-04 Be-7 1.13E-01 K-40 1.71E-02 i Sigma Error 1.23E-03 1 Sigma Error 1.42E-03 I Sigma Error 1.25E-03 1 Sigma Error 1.31E-03 I Sigma Error 1.06E-03 1 Sigma Error 1.144E-03 I Sigma Error 1.22E-03 1 Sigma Error 0.00E+00 0.00E+00 0.001+00 9.95E-03 4.84E-03 1 Sigma Error 1.40E-03 1 Sigma Error 1.52E-03 I Sigma Error 1.29E-03 1 Sigma Error 1.22E-03 I Sigma Error 1.35E-03 1 Sigma Error 1.52E-03 1 Sigma Error 1.802-03 1 Sigma Error 1.66E-03 1 Sigma Error 1.48E-03 1 Sigma Error 1.47E-03 I Sigma Error 1.59E-03 1 Sigma Error 1.24E-03 1 Sigma Error 1.56E-03 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 8.92E-03 4.27E-03 LLD 3.04E-03 LLD 3.17E-03 LLD 2.97E-03 LLD 2.87E-03 LLD 2.95E-03 LLD 2.94E-03 LLD 2.99E-03 LLD 6.95E-02 8.84E-04 9.39E-04 1.27E-02 1.05E-02 LLD 2.92E-03 LLD 2.95E-03 LLD 2.94E-03 LLD 3.17E-03 LLD 2.99E-03 LLD 2.46E-03 LLD 3.12E-03 LLD 2.90E-03 LLD 2.72E-03 LLD 3.04E-03 LLD 2.70E-03 LLD 2.99E-03 LLD 3.01E-03 LLD 6.77E-02 9.75E-04 8.85E-04 1.16E-02 1.14E-02 Report Generated @ 5/11/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 13 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR PARTICULATE Concentration (Activity): pCI/m3 Sample Point 258 [ CONTROL - W @ 9.84 miles ]

Sample ID:

272833 Sample ID:

273925 Sample ID:

274372 Sample ID:

274886 Sample ID:

276440 Sample ID:

278760 Sample ID:

278831 Sample ID:

279071 Sample ID:

279699 Sample ID:

280188 Sample ID:

280596 Sample Dates: 10122/2013 -1012912013 Sample Dates: 1012912013 - 1115/2013 Sample Dates: 11/5/2013 -11112/2013 Sample Dates: 11112/2013 -1111912013 Sample Dates: 11/19/2013 - 11/25/2013 Sample Dates: 1112612013-12/312013 Sample Dates: 1213/2013 - 1211012013 Sample Dates: 1211012013 -1211712013 Sample Dates: 12/17/2013 - 1212312013 Sample Dates: 12/23/2013 - 1213112013 Sample Dates: 101112013 - 1213112013 Nuclide Activity I Sigma Error LLD Beta 2.45E-02 1.52E-03 2.88E-03 Nuclide Activity 1 Sigma Error LLD Beta 2.80E-02 1.63E-03 3.07E-03 Nuclide Activity I Sigma Error LLD Beta 1.88E-02 1.36E-03 2.72E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.73E-02 1.39E-03 3.06E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.98E-02 1.57E-03 3.45E-03 Nuclide Activity I Sigma Error LLD Beta 2.24E-02 1.36E-03 2.54E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.23E-02 1.21E-03 2.82E-03 Nuclide Activity I Sigma Error LLD Beta 2.75E-02 1.62E-03 3.06E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.54E-02 1.48E-03 3.52E-03 Nuclide Activity 1 Sigma Error LLD Beta 1.82E-02 1.28E-03 2.68E-03 Nuclide Activity I Sigma Error LLD Cs-134

<3.84E-04 0.00E+00 3.84E-04 Cs-137

<3.92E-04 0.00E+00 3.92E-04 Be-7 1.14E-01 6.11E-03 5.22E-03 K-40 9.50E-03 2.26E-03 3.81 E-03 00 0

0 0

0 S

0 Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles I Sample ID:

260444 Sample ID:

250574 Sam pie ID:

250743 Sample ID:

250991 Sample ID:

251277 Sample Dates: 112/2013 - 1/812013 Sample Dates: 1/812013 - 1/1612013 Sample Dates: 1115/2013.1122/2013 Sample Dates: 1/22/2013.1/2912013 Sample Dates: 1/2912013 -2/612013 Nuciide Activity 1 Sigma Error 1-131

<6.11E-03 0.OOE+0O Cs-134

<6.49E-03 O.OOE+00 Cs-137

<8.33E-03 0.OOE+00 Be-7

<4.42E-02 O.00E+00 K-40 3.51E-01 6.52E-02 Nucilde Activity I Sigma Error 1-131

<1.92E-02 0.OOE+00 Cs-134

<1.73E-02 O.00E+00 Cs-137

<1.82E-02 O.00E+00 Be-7

<1.30E-01 0.00E+00 K-40 3.54E-01 9.15E-02 Nuclide Activity I Sigma Error 1-131

<1.37E-02 0.00E+00 Cs-134

<1.33E-02 0.00E+00 Cs-137

<1.57E-02 0.00E+00 Be-7

<1.03E-01 0.00E+00 K-40 4.34E-01 9.71E-02 Nuclide Activity I Sigma Error 1-131

<1.15E-02 0.00E+00 Cs-134

<8.41E-03 0.00E+00 Cs-137

<9.55E-03 O.00E+00 Be-7

<7.16E-02 0.00E+00 K-40 3.40E-01 8.51E-02 Nuciide Activity 1 Sigma Error 1-131

<1.84E-02 O.OOE+00 Cs-134

<1.44E-02 0.OOE+00 Cs-137

<1.85E-02 0.OOE+00 Be-7

<1.29E-01 0.00E+00 LLD 6.11E-03 6.49E-03 8.33E-03 4.42E-02 1.04E-01 LLD 1.92E-02 1.73E-02 1.82E-02 1.30E-01 2.47E-01 LLD 1.37E-02 1.33E-02 1.57E-02 1.03E-01 1.57E-01 LLD 1.15E-02 8.41 E-03 9.55E-03 7.16E-02 5.75E-02 LLD 1.84E-02 1.44E-02 1.85E-02 1.29E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En j 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 14 of 80 0

0 0

0

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR RADIOIODINE Concentration (Activity): pCilm3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

251277 Sample ID:

251607 S

0 Sample ID:

252073 0

0 Sample ID:

252690 0

0 Sample ID:

253076 0

0 Sample ID:

253884 0

O Sample ID:

254206 0

0 0

Sample ID:

264741 0

0 Sample ID:

255301 00 O

Sample ID:

255830 S

e Sample ID:

256064 Sample Dates: 1129/2013-.215/2013 Sample Dates: 21512013 -2112/2013 Sample Dates: 211212013-211912013 Sample Dates: 211912013.2/2612013 Sample Dates: 212612013.31512013 Sample Dates: 315/2013 -311212013 Sample Dates: 3/12/2013 -311912013 Sample Dates: 3119/2013 -3/2612013 Sample Dates: 312612013 -412/2013 Sample Dates: 4/212013 -4/9/2013 Sample Dates: 419/2013.4/16/2013 Nuclide Activity i Sigma Error K-40 3.43E-01 8.86E-02 Nuclide Activity I Sigma Error 1-131

<1.11E-02 0.00E+00 Cs-134

<1.22E-02 0.00E+00 Cs-137

<1.21E-02 0.00E+00 Be-7

<7.92E-02 0.OOE+00 K-40 6.15E-01 9.16E-02 LLD 1.98E-01 LLD 1.11E-02 1.22E-02 1.21 E-02 7.92E-02 1.49E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.47E-02 0.00E+00 1.47E-02 Cs-134

<1.23E-02 0.00E+00 1.23E-02 Cs-137

<1.36E-02 0.00E+00 1.36E-02 Be-7

<9.16E-02 0.00E+00 9.16E-02 K-40

<4.56E-01 0.00E+00 4.56E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.46E-02 0.00E+00 1.46E-02 Cs-134

<8.68E-03 0.00E+00 8.68E-03 Cs-137

<1.04E-02 0.00E+00 1.04E-02 Be-7

<8.88E-02 0.0OE+00 8.88E-02 K-40 5.39E-01 8.42E-02 1.18E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.91E-02 0.00E+00 1.91E-02 Cs-134

<1.63E-02 0.00E+00 1.63E-02 Cs-137

<1.57E-02 0.00E+00 1.57E-02 Be-7

<1.20E-01 0.00E+00 1.20E-01 K-40 3.97E-01 1.18E-01 2.79E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.02E-02 0.00E+00 2.02E-02 Cs-134

<1.42E-02 0.00E+00 1.42E-02 Cs-137

<1.38E-02 0.00E+00 1.38E-02 Be-7

<1.26E-01 0.00E+00 1.26E-01 K-40 5.47E-01 1.14E-01 2.07E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.69E-02 0.00E+00 1.69E-02 Cs-134

<1.62E-02 0.00E+00 1.62E-02 Cs-137

<1.36E-02 0.00E+00 1.36E-02 Be-7

<1.28E-01 0.OOE+00 1.28E-01 K-40 2.46E-01 1.06E-01 2.10E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.76E-02 0.00E+00 1.76E-02 Cs-134

<1.22E-02 0.00E+00 1.22E-02 Cs-137

<1.73E-02 0.00E+00 1.73E-02 Be-7

<8.40E-02 O.00E+00 8.40E-02 K-40

<4.96E-01 0.00E+00 4.96E-01 Nuclide Activity 1 Sigma Error 1-131

<1.12E-02 O.OOE+00 Cs-134

<1.16E-02 0.00E+00 Cs-137

<1.40E-02 0.00E+00 Be-7

<9.93E-02 0.00E+00 K-40 4.79E-01 1.22E-01 Nuclide Activity I Sigma Error 1-131

<1.52E-02 0.00E+00 Cs-134

<1.90E-02 0.00E+00 Cs-137

<1.38E-02 0.00E+00 Be-7

<1. 19E-01 0.00E+00 K-40

<5.58E-01 0.00E+00 LLD 1.12E-02 1.16E-02 1.40E-02 9.93E-02

2. 23E-01 LLD 1.52E-02 1.90E-02 1.38E-02 1.19E-01 5.58E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.26E-02 O.OOE+00 2.26E-02 Cs-134

<1.36E-02 0.00E+00 1.36E-02 Cs-137

<9.21E-03 0.00E+00 9.21E-03 Be-7

<9.46E-02 0.00E+00 9.46E-02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Enl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 15 of 80

6I 6I 6

6 6

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCIlm3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

256064 Sample ID:

256332 Sample ID:

266599 Sample ID:

257122 Sample ID:

267275 Sample ID:

257722 Sample ID:

257966 Sample ID:

268201 Sample ID:

258548 Sample ID:

259018 Sample ID:

259566 Sample Dates: 419/2013 - 411612013 Sample Dates: 411612013 -4123/2013 Sample Dates: 4/23/2013 -4/3012013 Sample Dates: 4/3012013 -51712013 Sample Dates: 5/7/2013-5/1412013 Sample Dates: 6/1412013 -5/2112013 Sample Dates: 5/2112013 -5/2912013 Sample Dates: 5/29/2013 -6/4/2013 Sample Dates: 6/412013 - 611112013 Sample Dates: 6/11/2013 -6/18/2013 Sample Dates: 6/18/2013 -6/25/2013 Nuclide Activity i Sigma Error K-40

<5.43E-01 0.00E+00 LLD 5.43E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.56E-02 0.00E+00 1.56E-02 Cs-134

<8.66E-03 0.00E+00 8.66E-03 Cs-137

<8.14E-03 O.OOE+00 8.14E-03 Be-7

<9.34E-02 0.00E+00 9.34E-02 K-40 2.74E-01 9.65E-02 1.81E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.OOE-02 0.00E+00 2.00E-02 Cs-134

<7.84E-03 0.OOE+00 7.84E-03 Cs-137

<2.29E-02 0.00E+00 2.29E-02 Be-7

<9.70E-02 0.00E+00 9.70E-02 K-40 2.66E-01 1.02E-01 2.11E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.79E-02 0.00E+00 1.79E-02 Cs-134

<1.52E-02 0.00E+00 1.52E-02 Cs-137

<1.19E-02 0.002E+0 1.19E-02 Be-7

<1.21E-01 0.00E+00 1.21E-01 K-to 5.24E-01 1.12E-01 1.76E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.19E-02 0.00E+00 1.19E-02 Cs-134

<8.29E-03 0.00E+00 8.29E-03 Cs-1 37

<1.43E-02 0.OOE+00 1.43E-02 Be-7

<6.56E-02 0.00E+00 6.56E-02 K-40 3.30E-01 8.24E-02 1.53E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.30E-02 0.OOE+00 1.30E-02 Cs-134

<6.71E-03 O.OOE+00 6.71E-03 Cs-137

<1.42E-02 0.00+E00 1.42E-02 Be-7

<7.88E-02 0.00E+00 7.88E-02 K-40

<3.56E-01 0.00E+00 3.56E-01 0

I6 6

0 0

0 S

S 0

Nuclide Activity I Sigma Error 1-131

<2.36E-02 0.OOE+00 Cs-134

<1.50E-02 0.00E+00 Cs-137

<1.83E-02 0.00E+00 Be-7

<1.39E-01 0.00E+00 K-40 3.432-01 9.16E-02 Nuclide Activity 1 Sigma Error 1-131

<2.00E-02 0.00E+00 Cs-134

<2.02E-02 0.00E+00 Cs-137

<2.34E-02 0.00E+00 Be-7

<2.13E-01 0.00E+00 K-40

<6.19E-01 0.00E+00 Nuclide Activity 1 Sigma Error 1-131

<1.14E-02 0.00E+00 Cs-134

<7.62E-03 0.00E+00 Cs-137

<8.95E-03 0.00E+00 Be-7

<7.10E-02 0.00E+00 K-40 4.37E-01 9.35E-02 Nuclide Activity 1 Sigma Error 1-131

<1.87E-02 0.00E+00 Cs-134

<2.14E-02 0.00E+00 Cs-137

<7.97E-03 0.00E+00 Be-7

<1.79E-01 0.00E+00 K-40

<4.51E-01 0.00E+00 Nuclide Activity 1 Sigma Error 1-131

<2.26E-02 0.00E+00 Cs-134

<1.97E-02 0.00E+00 Cs-137

<1.942-02 0.00E+00 Be-7

<1.22E-01 0.00E+00 LLD 2.36E-02 1.50E-02 1.83E-02 1.39E-01 2.86E-01 LLD 2.00E-02 2.02E-02 2.34E-02 2.13E-01 6.19E-01 LLD 1.14E-02 7.62E-03 8.95E-03 7.10E-02 1.46E-01 LLD 1.87E-02 2.14E-02 7.97E-03 1.79E-01 4.51 E-01 LLD 2.26E-02 1.972-02 1.94E-02 1.22E-01 S

0 0

Apedi

-Pge1 o 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ERn 13339 Hagers Ferry Road Huntersville, North Carolina 28078

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR RADIOIODINE Concentration (Activity): pCIlm3 Sample Point 200 j INDICATOR - NNE Q 0.63 miles I Sample ID:

269666 O

Sample ID:

260200 0

O Sample ID:

260660 0

0 Sample ID:

261623 0

Sample ID:

262125 0

0 Sample ID:

263141 O

Sample ID:

263368 S

Sample ID:

264026 Sample ID:

265157 0

O Sample ID:

265466 00 0

O Sample ID:

267162 Sample Dates: 6W1812013 -62612013 Sample Dates: 612512013 -71212013 Sample Dates: 71212013 -71912013 Sample Dates: 7/9/2013 -71612013 Sample Dates: 7/16/2013 -7123/2013 Sample Dates: 712312013 -713012013 Sample Dates: 7130/2013 - 81612013 Sample Dates; 8/6/2013 -811312013 Sample Dates: 8/1312013 -812012013 Sample Dates: 8/20/2013 - 8/2712013 Sample Dates: 8/2712013 -91412013 Nuclide Activity I Sigma Error LLD K-40 5.18E-01 1.48E-01 2.69E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.98E-02 0.00E+00 1.98E-02 Cs-134

<1.21E-02 0.OOE+00 1.21E-02 Cs-137

<1.60E-02 0.00E+00 1.60E-02 Be-7

<7.72E-02 0.00E+00 7.72E-02 K-40 3.87E-01 9.69E-02 6.54E-02 Nuclide Activity I Sigma Error LLD 1-131

<2.31E-02 0.00E+00 2.31E-02 Cs-134

<1.72E-02 0.00E+00 1.72E-02 Cs-137

<2.08E-02 0.00E+00 2.08E-02 Be-7

<1.59E-01 0.00E+00 1.59E-01 K-40 4.14E-01 1.39E-01 2.75E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.39E-02 0.00E+00 1.39E-02 Cs-1 34

<6.99E-03 0.00E+00 6.99E-03 Cs-137

<1.36E-02 0.00E+00 1.36E-02 Be-7

<7.78E-02 0.0OE+00 7.78E-02 K-40 3.88E-01 8.72E-02 1.22E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.08E-02 0.OOE+00 2.08E-02 Cs-134

<1.54E-02 0.O0E+00 1.54E-02 Cs-137

<1.96E-02 0.OOE+00 1.96E-02 Be-7

<9.92E-02 0.OOE+00 9.92E-02 K-40 4.83E-01 1.17E-01 2.14E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.60E-02 0.OOE+00 1.60E-02 Cs-134

<1.62E-02 0.002+00 1.62E-02 Cs-137

<2.52E-02 0.OOE+00 2.52E-02 Be-7

<1.31E-01 0.002+00 1.31 E-01 K-40 6.64E-01 1.38E-01 3.21 E-01 Nuclide Activity I Sigma Error 1-131

<2.20E-02 O.OOE+00 Cs-134

<2.12E-02 O.OOE+00 Cs-137

<2.15E-02 O.OOE+00 Be-7

<1.48E-01 0.00E+00 K-40 3.69E-01 1.28E-01 LLD 2.20E-02 2.12E-02 2.15E-02 1.48E-01 7.72E-02 Nuclide Activity I Sigma Error LLD 1-131

<1.97E-02 0.00E+00 1.97E-02 Cs-134

<1.74E-02 0.00E+00 1.74E-02 Cs-137

<2.35E-02 0.00E+00 2.35E-02 Be-7

<1.69E-01 0.00E+00 1.69E-01 K-40 3.41E-01 9.85E-02 2.98E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.562-02 0.00E+00 1.56E-02 Cs-134

<1.62E-02 0.00E+00 1.62E-02 Cs-137

<1.20E-02 0.00+E00 1.20E-02 Be-7

<1.05E-01 0.00E+00 1.05E-01 K-40 3.83E-01 1.15E-01 1.99E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.58E-02 0.00E+00 2.58E-02 Cs-134

<1.84E-02 0.00E+00 1.84E-02 Cs-137

<2.31E-02 0.00E+00 2.31E-02 Be-7

<1.572-01 0.00E+00 1.57E-01 K-40 4.28E-01 1.10E-01 2.58E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.27E-02 0.OOE+00 1.27E-02 Cs-134

<1.10E-02 0.00E+00 1.10E-02 Cs-137

<1.23E-02 0.00E+00 1.23E-02 Be-7

<8.30E-02 0.00E+00 8.30E-02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ED 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 17 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCIlm3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

267152 Sample ID:

267602 Sample ID:

268457 Sample ID:

269580 Sample ID:

270723 Sample ID:

271448 Sample ID:

272055 Sample ID:

272438 Sample ID:

272839 Sample ID:

273931 Sample ID:

274378 Sample Dates: 812712013 -91412013 Sample Dates: 91412013-911012013 Sample Dates: 9110/2013 - 9M17/2013 Sample Dates: 911712013.912412013 Sample Dates: 9/24/2013 - 1011/2013 Sample Dates: 1011/2013.10/812013 Sample Dates: 10/8/2013.1011512013 Sample Dates: 10/1512013 -10122/2013 Sample Dates: 1012212013 - 1012912013 Sample Dates: 10/2912013 -111512013 Sample Dates: 11/5/2013 - 11112/2013 Nuclide Activity I Sigma Error LLD K-40 2.66E-01 7.12E-02 5.15E-02 Nuclide Activity 1 Sigma Error 1-131

<1.89E-02 0.00E+00 Cs-134

<2.02E-02 0.00E+00 Cs-137

<2.33E-02 0.00E+00 Be-7

<1.68E-01 0.OOE+00 K-40

<6.OOE-01 0.OOE+00 LLD 1.89E-02 2.02E-02 2.33E-02 1.68E-01 6.OOE-01 Nuclide Activity I Sigma Error LLD 1-131

<2.10E-02 O.00E+00 2.10E-02 Cs-134

<1.66E-02 0.00E+00 1.66E-02 Cs-137

<2.05E-02 0.OOE+00 2.05E-02 Be-7

<1.00E-01 0.00E+00 1.00E-01 K-40

<4.75E-01 0.00E+00 4.75E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.27E-02 O.OOE+00 2.27E-02 Cs-134

<1.70E-02 0.00E+00 1.70E-02 Cs-137

<1.86E-02 0.00E+00 1.86E-02 Be-7

<1.46E-01 0o.00E+0 1.46E-01 K-40

<5.43E-01 0.00E+00 5.43E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.00E-02 0.OOE+00 2.00E-02 Cs-134

<2.23E-02 0.00E+00 2.23E-02 Cs-137

<1.46E-02 0.00E+00 1.46E-02 Be-7

<1.99E-01 0.00E+00 1.99E-01 K-40 4.23E-01 1.42E-01 2.46E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.06E-02 0.00E+00 2,06E-02 Cs-134

<2.12E-02 0.00E+00 2.12E-02 Cs-137

<2.59E-02 O.00E+00 2.59E-02 Be-7

<1.17E-01 O.00E+00 1.17E-01 K-40 5.16E-01 1.22E-01 2.58E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.84E-02 O.00E+00 1.84E-02 Cs-134

<1.58E-02 0.00E+00 1.58E-02 Cs-137

<2.05E-02 0.00E+00 2.05E-02 Be-7

<1.48E-01 0.00E+00 1.48E-01 K-40 4.51E-01 1.36E-01 2.13E-01 Nuclide Activity I Sigma Error 1-131

<2.34E-02 0.00E+00 Cs-134

<9.78E-03 0.00E+00 Cs-137

<2.06E-02 0.00E+00 Be-7

<1.03E-01 0.00E+00 K-40 5.14E-01 1.49E-01 LLD 2.34E-02 9.78E-03 2.06E-02 1.03E-01 3.80E-01 I0 6

6 6

6 0

O O

S 0

6 0

0 0

Apeni 2Pae18of8 0

0 Nuclide Activity 1 Sigma Error LLD 1-131

<1.78E-02 0.00E+00 1.78E-02 Cs-134

<1.57E-02 0.00E+00 1.57E-02 Cs-137

<2.45E-02 0.00E+00 2.45E-02 Se-7

<1.15E-01 0.00E+00 1.15E-01 K-40 5.18E-01 1.22E-01 7.77E-02 Nuclide Activity 1 Sigma Error 1-131

<2.28E-02 0.00E+00 Cs-134

<1.73E-02 0.00E+00 Cs-137

<1.69E-02 0.00E+00 Be-7

<1.62E-01 0.00E+00 K-40

<5.56E-01 0.00E+00 Nuclide Activity 1 Sigma Error 1-131

<2.32E-02 0.002+00 Cs-134

<1.88E-02 0.00E+00 Cs-137

<2.47E-02 0.00E+00 Be-7

<1.53E-01 0.00E+00 LLD 2.28E-02

1. 73E-02 1.69E-02 1.62E-01 5.56E-01 LLD 2.32E-02 1.88E-02 2.47E-02 1.53E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories END 13339 Hagers Ferry Road Huntersville, North Carolina 28078

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

274378 Sample ID:

274892 0

0 Sample ID:

276446 0

S Sample ID:

278761 0

0 Sample ID:

278832 0

S 0

Sample ID:

279072 S

0 O

Sample ID:

279700 0

0 0

O Sample ID:

280189 0

Sample Dates: 111512013 - 1111212013 Sample Dates: 11112/2013 -1111912013 Sample Dates: 1111912013 - 1112512013 Sample Dates: 1112512013.121312013 Sample Dates: 12)3/2013 - 12/1012013 Sample Dates: 12110/2013 -1211712013 Sample Dates: 12117/2013 -1212312013 Sample Dates: 12/23/2013 -1213112013 Nuclide Activity 1 Sigma Error K-40

<6.31E-01 O.OOE+00 Nuclide Activity 1 Sigma Error 1-131

<2.34E-02 0.00E+00 Cs-134

<1.43E-02 0.00E+00 Cs-137

<2.00E-02 0.OOE+00 Be-7

<1.74E-01 0.00E+00 K-40 3.86E-01 1.42E-01 Nuclide Activity 1 Sigma Error 1-131

<2.20E-02 0.00E+00 Cs-134

<1.71E-02 O.OOE+00 Cs-137

<7.56E-03 0.00E+00 Be-7

<9.93E-02 0.00E+00 K-40 3.20E-01 1.71E-01 Nuclide Activity 1 Sigma Error 1-131

<1.21E-02 0.00E+00 Cs-134

<1.12E-02 0.OOE+00 Cs-137

<1.06E-02 0.00E+00 Be-7

<6.52E-02 0.00E+00 K-40 2.31E-01 1.10E-01 LLD 6.31E-01 LLD 2.34E-02 1.43E-02 2.00E-02 1.74E-01 2.64E-01 LLD 2.20E-02 1.71E-02 7.56E-03 9.93E-02 2.87E-01 LLD 1.21 E-02 1.12E-02 1.06E-02 6.52E-02 2.25E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.07E-02 0.00E+00 2.07E-02 Cs-134

<1.40E-02 0.00E+00 1.40E-02 Cs-137

<2.02E-02 0.00E+00 2.02E-02 Be-7

<1.21E-01 0.OOE+00 1.21E-01 K-40 3.46E-01 1.29E-01 2.65E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<8.54E-03 0.OOE+00 8.54E-03 Cs-134

<8.28E-03 0.00E+00 8.28E-03 Cs-137

<1.34E-02 0.00E+00 1.34E-02 Be-7

<7.85E-02 0.00E+00 7.85E-02 K-40 5.23E-01 8.38E-02 1.00E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.99E-02 0.00E+00 1.99E-02 Cs-134

<2.00E-02 0.00E+00 2.00E-02 Cs-137

<2.31E-02 0.OOE+00 2.31E-02 Be-7

<2.06E-01 0.00E+00 2.06E-01 K-40 6.87E-01 1.50E-01 3.46E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.10E-02 0.00E+00 2.10E-02 Cs-134

<1.74E-02 0.00E+00 1.74E-02 Cs-137

<1.92E-02 0.00E+00 1.92E-02 Be-7

<1.66E-01 0.00E+00 1.66E-01 K-40 3.96E-01 9.91E-02 6.70E-02 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

Sample ID:

260445 0

0 Sample ID:

250575 Sample ID:

260744 Sample Dates: 1/212013 - 1/812013 Sample Dates: 1/812013 - 1/15/2013 Sample Dates: 1115/2013 -1/22/2013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.28E-02 0.00E+00 1.28E-02 Cs-134

<1.05E-02 0.00E+00 1.05E-02 Cs-137

<1.06E-02 0.00E+00 1.06E-02 Be-7

<8.03E-02 0.00E+00 8.03E-02 K-40 3.21E-01 6.70E-02 9.94E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.13E-02 0.00E+00 1.13E-02 Cs-134

<6.62E-03 0.00E+00 6.62E-03 Cs-137

<9.50E-03 0.00E+00 9.50E-03 Be-7

<7.36E-02 0.00E+00 7.36E-02 K-40 4.06E-01 7.53E-02 1.00E-01 Nuclide Activity 1 Sigma Error 1-131

<1.72E-02 0.00E+00 Cs-134

<1.77E-02 0.00E+00 LLD 1.72E-02 1.77E-02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Eli

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 19 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media "Type: AIR RADIOIODINE Concentration (Activity): pCilm3 Sample Point 201 [ INDICATOR - NE @ 0.53 miles I Sample ID:

250744 Sample ID:

250992 Sample ID:

261278 Sample ID:

251608 Sample ID:

252074 Sample ID:

252691 Sample ID:

253077 Sample ID:

253885 Sample ID:

254207 Sample ID:

254742 Sample ID:

255302 Sample Dates: 111512013 - 1122/2013 Sample Dates: 112212013 - 112912013 Sample Dates: 1/29/2013-21512013 Sample Dates: 2/512013 -2112/2013 Sample Dates: 211212013 -2/1912013 Sample Dates: 211912013 -2/2612013 Sample Dates: 2/2612013 -31512013 Sample Dates: 3/5/2013-311212013 Sample Dates: 3/12/2013 - 3/1912013 Sample Dates: 3/1912013 - 3/26/2013 Sample Dates: 3/26/2013 -41212013 Nuclide Activity I Sigma Error LLD Cs-137

<9.24E-03 0.OOE+00 9.24E-03 Be-7

<1.10E-01 O.OOE+00 1.10E-01 K-40 5.11E-01 1.09E-01 6.28E-02 Nuclide Activity I Sigma Error LLD 1-131

<1.78E-02 0.00E+00 1.78E-02 Cs-134

<1.45E-02 0.00E+00 1.45E-02 Cs-137

<1.47E-02 0.OOE+00 1.47E-02 Be-7

<1.20E-01 0.OOE+00 1.20E-01 K-40 3.66E-01 1.14E-01 2.17E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.14E-02 0.00E+00 1.14E-02 Cs-134

<9.45E-03 0.00E+00 9.45E-03 Cs-137

<7.53E-03 0.00E+00 7.53E-03 Be-7

<7.06E-02 0.00E+00 7.06E-02 K-40 4.34E-01 1.11E-01 1.93E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.66E-02 0.00E+00 1.66E-02 Cs-134

<1.52E-02 O.00E+00 1.52E-02 Cs-137

<1.48E-02 O.00E+00 1,48E-02 Be-7

<9.84E-02 0.00E+00 9.84E-02 K-40

<4.76E-01 0.OOE+00 4.76E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.09E-02 0.OOE+00 1.09E-02 Cs-134

<1.01E-02 0.OOE+00 1.01E-02 Cs-137

<1.05E-02 O.OOE+00 1.05E-02 Be-7

<5.17E-02 0.00E+O0 5.17E-02 K-40 2.35E-01 1.16E-01 1.95E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.15E-02 0.OOE+00 1.15E-02 Cs-134

<1.52E-02 0.OOE+00 1.52E-02 Cs-137

<1.45E-02 0.OOE+00 1.45E-02 Be-7

<1.26E-01 0.00E+00 1.26E-01 K-40

<4.78E-01 0.OOE+00 4.78E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.19E-02 0.OOE+00 2.19E-02 Cs-134

<9.84E-03 0.00E+00 9.84E-03 Cs-137

<1.70E-02 0.00E+00 1.70E-02 Be-7

<1.18E-01 0.OOE+00 1.18E-01 K-40

<4.38E-01 0.00+E00 4.38E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.93E-02 0.00E+00 1.93E-02 Cs-134

<1.30E-02 O.OOE+00 1.30E-02 Cs-137

<1.70E-02 0.00E+00 1.70E-02 Be-7

<7.75E-02 0.00E+00 7.75E-02 K-40 6.16E-01 1.21E-01 6.40E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.86E-02 0.00E+00 1.86E-02 Cs-134

<1.16E-02 0.OOE+00 1.16E-02 Cs-137

<1.57E-02 0.00E+00 1.57E-02 Be-7

<1.21E-01 0.00E+00 1.21E-01 K-40 3.08E-01 1.12E-01 2.02E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.60E-02 0.00E+00 1.60E-02 Cs-134

<9.78E-03 0.00E+00 9.78E-03 Cs-137

<1.40E-02 0.OOE+00 1.40E-02 Be-7

<8.80E-02 0.OOE+00 8.80E-02 K-40 6.73E-01 1.27E-01 6.50E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<8.88E-03 0.00E+00 8.88E-03 Cs-134

<1.12E-02 0.00E+00 1.12E-02 00 6

0 0

0 6

0 0

S 0

0 0

0 S

0 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Enl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 20 of 80 S

0 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOJODINE Concentration (Activity): pCI/m3 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

Sample ID:

255302 0

Sample ID:

255831 S

Sample ID:

256066 0

0 Sample ID:

256333 S

0 Sample ID:

256600 S

0 Sample ID:

257123 0

O Sample ID:

257276 0

0 S

Sample ID:

257723 0

Sample ID:

257967 0

0 O

Sample I0:

258202 0

S S

Sample ID:

258549 Sample Dates: 312612013 - 41212013 Sample Dates: 41212013.41912013 Sample Dates: 419/2013 -4/1612013 Sample Dates: 411612013 -4/2312013 Sample Dates: 4/2312013 - 413012013 Sample Dates: 4/30/2013 -51712013 Sample Dates: 5/712013 - 5114/2013 Sample Dates: 5114/2013-512112013 Sample Dates: 5/21/2013 -5/2912013 Sample Dates: 5/2912013

6/412013 Sample Dates: 6/4/2013 - 611/2013 Nuclide Activity I Sigma Error Cs-137

<1.28E-02 0.OOE+00 Be-7

<7.59E-02 0.00E+00 K-40 5.46E-01 8.86E-02 LLD 1.28E-02 7.59E-02 1.55E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.28E-02 0.00E+00 2.28E-02 Cs-134

<1.49E-02 0.00E+00 1.49E-02 Cs-137

<1.48E-02 0.00E+00 1.48E-02 Be-7

<1.09E-01 0.OOE+00 1.09E-01 K-40

<5.1OE-01 0.00E+00 5.10E-01 Nuclide Activity 1 Sigma Error 1-131

<1.08E-02 0.OOE+00 Cs-134

<9.87E-03 0.00E+00 Cs-137

<1.29E-02 0.00E+00 Be-7

<5.37E-02 0.00E+00 K-40

<4.10E-01 0.00E+00 Nuclide Activity 1 Sigma Error 1-131

<1.01E-02 0.OOE+00 Cs-134

<1.03E-02 0.OOE+00 Cs-137

<1.33E-02 0.00E+00 Be-7

<7.71E-02 O.00E+00 K-40 4.88E-01 8.38E-02 Nuclide Activity i Sigma Error 1-131

<2.13E-02 0.00E+00 Cs-134

<1.00E-02 0.00E+00 Cs-137

<1.79E-02 O.00E+00 Be-7

<1.14E-01 0.00E+00 K-40 3.32E-01 8.86E-02 LLD 1.08E-02 9.87E-03 1.29E-02 5.37E-02 4.10E-01 LLD 1.01E-02 1.03E-02 1.33E-02 7.71 E-02 1.07E-01 LLD 2.13E-02 1.00E-02 1.79E-02 1.14E-01 2.03E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.59E-02 0.00E+00 1.59E-02 Cs-134

<1.14E-02 0.00E+00 1.14E-02 Cs-137

<6.74E-03 0.00E+00 6,74E-03 Be-7

<1.45E-01 0.00E+00 1.45E-01 K-40 5.42E-01 1.13E-01 2.54E-01 Nuclide Activity i Sigma Error LLD 1-131

<1.35E-02 0.00E+00 1.35E-02 Cs-134

<7.98E-03 0.00E+00 7.98E-03 Cs-137

<1.33E-02 0.00E+00 1.33E-02 Be-7

<6.75E-02 0.00E+00 6.75E-02 K-40 3.76E-01 7.36E-02 1.32E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<9.77E-03 0.00E+00 9.77E-03 Cs-134

<1 17E-02 0.00E+00 1.17E-02 Cs-137

<1.54E-02 0.00E+00 1.54E-02 Be-7

<7.11E-02 0.00E+00 7.11E-02 K-40 3.57E-01 8.86E-02 1.05E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.31E-02 0.00E+00 2.31E-02 Cs-134

<1.97E-02 0.00E+00 1.97E-02 Cs-137

<1.76E-02 0.00E+00 1.76E-02 Be-7

<1.24E-01 O.00E+00 1.24E-01 K-40 3.95E-01 1.23E-01 2.26E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.23E-02 0.00E+00 2.23E-02 Cs-134

<1.98E-02 0.00E+00 1.98E-02 Cs-I37

<1.90E-02 0.00E+00 1.90E-02 Be-7

<1.45E-01 0.00E+00 1.45E-01 K-40

<4.70E-01 0.00E+00 4.70E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.10E-02 0.00E+00 1.10E-02 Cs-134

<8.45E-03 0.00E+00 8.45E-03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories El

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 21 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

S 0

0 0

0 Sample ID:

258549 Sample ID:

259019 Sample ID:

259567 Sample ID:

260201 Sample ID:

260661 Sample ID:

261624 Sample ID:

262126 Sample ID:

263142 Sample ID:

263369 Sample ID:

264027 Sample ID:

265158 Sample Dates: 614/2013 -611112013 Sample Dates: 611112013-611812013 Sample Dates: 611812013 -612512013 Sample Dates: 612512013 -712/2013 Sample Dates: 712/2013 - 71912013 Sample Dates: 719/2013 -711612013 Sample Dates: 7116/2013 -712312013 Sample Dates: 7123/2013 -7130/2013 Sample Dates: 7/3012013 - 81612013 Sample Dates: 8/612013.8113/2013 Sample Dates: 8/13/2013 - 8/2012013 Nuclide Activity I Sigma Error LLD Cs-137

<1.48E-02 0.OOE+00 1.48E-02 Be-7

<5.20E-02 0.00E+00 5.20E-02 K-40 8.22E-02 7.35E-02 1.00E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.29E-02 0.00E+00 2.29E-02 Cs-134

<1.59E-02 0.00E+00 1.59E-02 Cs-137

<9.74E-03 0.OOE+00 9.74E-03 Be-7

<1.55E-01 0.00E+00 1.55E-01 K-40

<5.55E-01 0.00E+00 5.55E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.71E-02 0.00E+00 1.71E-02 Cs-134

<1.01E-02 0.00E+00 1.01E-02 Cs-137

<1.55E-02 O.OOE.00 1.55E-02 Be-7

<1.10E-01 0.OOE+00 1.10E-01 K-40 4.06E-01 9.85E-02 1.71 E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.14E-02

.O00E+00 1.14E-02 Cs-134

<6.79E-03 0.00E+00 6.79E-03 Cs-137

<9.54E-03 0.00E+00 9.54E-03 Be-7

<7.76E-02 0.OOE+0O 7.76E-02 K-40 4.49E-01 7.49E-02 1.13E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.36E-02 O.00+E00 2.36E-02 Cs-134

<2.01E-02 0.00E+00 2.01E-02 Cs-137

<2.81E-02 0.00E+00 2.81E-02 Be-7

<1.72E-01 0.00E+00 1.72E-01 K-40

<5.OOE-01 0.00E+00 5.00E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.44E-02 0.OOE+00 1.44E-02 Cs-134

<1.29E-02 0.00E+00 1.29E-02 Cs-137

<8.53E-03 0.OOE+00 8.53E-03 Be-7

<9.10E-02 0.00E+00 9.10E-02 K-40 4.48E-01 1.16E-01 1.92E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.50E-02 0.00E+00 1.50E-02 Cs-134

<1.22E-02 0.00E+00 1.22E-02 Cs-137

<1.46E-02 0.00E+00 1.46E-02 Be-7

<1.64E-01 0.00E+00 1.64E-01 K-40 4.85E-01 1.18E-01 7.72E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.24E-02 0.OOE+00 2.24E-02 Cs-134

<9.77E-03 0.00E+00 9.77E-03 Cs-137

<1.98E-02 0.00E+00 1.98E-02 Be-7

<1.57E-01 0.00E+00 1.57E-01 K-40 4.61E-01 1.43E-01 2.16E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.31 E-02 0.00E+00 2.31 E-02 Cs-134

<1.56E-02 0.00E+00 1.56E-02 Cs-137

<2.34E-02 0.00E+00 2.34E-02 Be-7

<1.15E-01 0.00E+00 1.15E-01 K-40 4.59E-01 1.15E-01 7.76E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.15E-02 0.00E+00 2.15E-02 Cs-134

<2.10E-02 0.OOE+00 2.10E-02 Cs-137

<1.69E-02 0.00E+00 1.69E-02 Be-7

<1.02E-01 0.00E+00 1.02E-01 K-40 5.70E-01 1.27E-01 3.14E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.84E-02 0.00E+00 1.84E-02 Cs-134

<1.60E-02 0.00E+00 1.60E-02 00 0

0 0

Apedi Pae22o 0

0 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EnI 13339 Hagers Ferry Road Huntersville, North Carolina 28078

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Wype: AIR RADIOIODINE Concentration (Activity): pCI/m3 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

O Sample ID:

265158 0

O Sample ID:

265467 S

0 0

S Sample ID:

267153 0

S S

Sample ID:

267603 0

0 Sample ID:

268458 S

0 0

S Sample ID:

269581 0

0 S

Sample ID:

270724 0

0 0O Sample ID:

271449 0

S 5

Sample ID:

272046 0S S

Sample ID:

272439 0

S S

O Sample ID:

272840 0

Sample Dates: 8113/2013 - 8/2012013 Sample Dates: 812012013 - 812712013 Sample Dates: 8127/2013 -91412013 Sample Dates: 914/2013 - 911012013 Sample Dates: 911012013 -911712013 Sample Dates: 9/17/2013 -9/24/2013 Sample Dates: 9124/2013 -101112013 Sample Dates: 1011/2013.101812013 Sample Dates: 10/812013 - 10116/2013 Sample Dates: 10/15/2013 -1012212013 Sample Dates: 10/22/2013 - 1012912013 Nuclide Activity 1 Sigma Error Cs-137

<1.82E-02 0.00E+00 Be-7

<1.93E-01 0.00E+00 K-40 3.45E-01 1.25E-01 Nuclide Activity I Sigma Error 1-131

<1.30E-02 0.00E+00 Cs-134

<1.08E-02 0.00E+00 Cs-137

<1.06E-02 0.OOE+00 Be-7

<7.46E-02 0.00E+00 K-40

<3.37E-01 0.00E+00 Nuclide Activity I Sigma Error 1-131

<1.68E-02 0.00E+00 Cs-134

<1.62E-02 0.00E+00 Cs-137

<1.68E-02 O.OOE+00 Be-7

<1.21E-01 0.OOE+00 K-40

<6.34E-01 0.00E+00 Nuclide Activity 1 Sigma Error 1-131

<1.41E-02 0.00E+00 Cs-134

<1.57E-02 O.00E+00 Cs-137

<1.63E-02 0.00E+00 Be-7

<1.11E-01 0.00E+00 K-40

<4.56E-01 O.00E+00 LLD 1.82E-02 1.93E-01 2.72E-01 LLD 1.30E-02 1.08E-02 1.06E-02 7.46E-02 3.37E-01 LLD 1.68E-02 1.62E-02 1.68E-02 1.21 E-01 6.34E-01 LLD 1.41 E-02 1.57E-02 1.63E-02 1.11E-01 4.56E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.25E-02 0.00E+00 1.25E-02 Cs-134

<1.18E-02 0.00E+00 1.18E-02 Cs-137

<8.45E-03 0.00E+00 8.45E-03 Be-7

<1.01E-01 0.OOE+00 1.01E-01 K-40

<4.27E-01 O.OOE+00 4.27E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.03E-02 0.00E+00 2.03E-02 Cs-134

<1.92E-02 0.00E+00 1.92E-02 Cs-137

<1.85E-02 0.00E+00 1.85E-02 Be-7

<1.01E-01 0.00E+00 1.01E-01 K-40 4.88E-01 1.18E-01 3.19E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.76E-02 O.00E+00 2.76E-02 Cs-134

<1.87E-02 0.00E+00 1.87E-02 Cs-137

<2.02E-02 0.00E+00 2.02E-02 Be-7

<1.45E-01 0.00E+00 1.45E-01 K-40

<6.56E-01 0.00E+00 6,56E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.54E-02 0,00E+00 1.54E-02 Cs-1 34

<1.87E-02 0.00E+00 1.87E-02 Cs-137

<2.01 E-02 0.00E+00 2.01E-02 Be-7

<1.27E-01 0.00E+00 1.27E-01 K-40 2.91E-01 1.60E-01 3.32E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.49E-02 0.00E+00 2.49E-02 Cs-134

<2.00E-02 0.00E+00 2.00E-02 Cs-137

<1.46E-02 0.00E+00 1.46E-02 Be-7

<8.48E-02 0.00E+00 8.48E-02 K-40 5.72E-01 1.28E-01 3.29E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.62E-02 0.00E+00 1.62E-02 Cs-134

<1.05E-02 0.00E+00 1.05E-02 Cs-137

<9.31E-03 0.00E+00 9.31E-03 Be-7

<8.69E-02 0.00E+00 8.69E-02 K-40 4.94E-01 1.03E-01 5.80E-02 Nuclide Activity 1 Sigma Error 1-131

<1.47E-02 0.00E+00 Cs-134

<1.32E-02 0.00E+00 LLD 1.47E-02 1.32E-02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ENl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 23 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCilm3 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

Sample ID:

272840 Sample ID:

273932 Sample ID:

274379 Sample ID:

274893 Sample ID:

276447 Sample ID:

278762 Sample ID:

278833 Sample ID:

279073 Sample ID:

279701 Sample ID:

280190 Sample Dates: 1012212013 -1012912013 Sample Dates: 1012912013 -111512013 Sample Dates: 11/512013 -1111212013 Sample Dates: 11/1212013 - 11/19/2013 Sample Dates: 11/19/2013 -11/2512013 Sample Dates: 11/26/2013 -1213/2013 Sample Dates: 12/312013 -12110/2013 Sample Dates: 12/10/2013 *12/1712013 Sample Dates: 12/17/2013 -1212312013 Sample Dates: 12/2312013.12/3112013 Nuclide Activity I Sigma Error LLD Cs-137

<2.21E-02 0.00E+00 2.21E-02 Be-7

<1.15E-01 0.00E+00 1.15E-01 K-40

<4.36E-01 0.OOE+00 4.36E-01 Nuclide Activity 1 Sigma Error LLD 1.131

<1.59E-02 0.OOE+00 1.59E-02 Cs-134

<1.23E-02 0.00E+00 1.23E-02 Cs-137

<1.29E-02 O.OOE+00 1.29E-02 Be-7

<8.06E-02 0.00E+00 8.06E-02 K-40 4.45E-01 1.02E-01 1.94E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.17E-02 0.OOE+00 2.17E-02 Cs-134

<1.97E-02 0.OOE+00 1.97E-02 Cs-137

<1.88E-02 O.00E+00 1.88E-02 Be-7

<1.60E-01 0.OOE+00 1.60E-01 K-40 2.98E-01 1.27E-01 3.15E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.41E-02 0.00E+00 2.41E-02 Cs-134

<1.31E-02 0.OOE+00 1.31E-02 Cs-137

<1.80E-02 0.OOE+00 1.80E-02 Be-7

<8.87E-02 0.00E+00 8.87E-02 K-40

<6.02E-01 0.OOE+00 6.02E-01 66 6

6 6

6 0

0 S

S 0

0 Nuclide Activity I Sigma Error 1-131

<1.31E-02 0.OOE+00 Cs-134

<1.25E-02 0.00E+00 Cs-137

<1.30E-02 0.OOE+00 Be-7

<8.77E-02 0.002+00 K-40 8.77E-01 1.14E-01 Nuclide Activity 1 Sigma Error 1-131

<1.45E-02 0.00E+00 Cs-134

<8.77E-03 0.00E+00 Cs-137

<9.57E-03 0.OOE+00 Be-7

<8.31 E-02 0.00E+00 K-40

<3.96E-01 0.OOE+00 Nuclide Activity 1 Sigma Error 1-131

<2.47E-02 0.00E+00 Cs-134

<1.68E-02 0.OOE+00 Cs-137

<1.68E-02 0.00E+00 Be-7

<1.70E-01 0.00E+00 K-40 3.07E-01 1.17E-01 LLD 1.31E-02 1.25E-02 1.30E-02 8.77E-02 1.06E-01 LLD 1.45E-02 8.77E-03 9.57E-03 8.31E-02 3.96E-01 LLD 2.47E-02 1.68E-02 1.68E-02 1.70E-01 7.68E-02 00 S

S 0

0 S

0 0

0 Nuclide Activity I Sigma Error LLD

-131

<2.69E-02 0.00E+00 2.69E-02 Cs-134

<1.08E-02 0.00E+00 1.08E-02 Cs-137

<2.16E-02 0.00E+00 2.16E-02 Be-7

<1.35E-01 0.00E+00 1.35E-01 K-40 5.20E-01 1.23E-01 3.03E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.88E-02 0.00E+00 2.88E-02 Cs-134

<1.41E-02 0.00E+00 1.41 E-02 Cs-137

<2.16E-02 0.00E+00 2.16E-02 Be-7

<1.80E-01 0.00E+00 1.80E-01 K-40 5.55E-01 1.35E-01 8.83E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.16E-02 0.00E+00 2.16E-02 Cs-134

<1.67E-02 0.00E+00 1.67E-02 Cs-137

<2.06E-02 0.00E+00 2.06E-02 Be-7

<1.04E-01 0.00E+00 1.04E-01 K-40

<5.51E-01 0.00E+00 5.51E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E fl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 0

Appendix 2 - Page 24 of 80 0

0 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCI/m3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

Sample ID:

250446 0

0 O

Sample ID:

250576 0

S O

Sample ID:

250746 0

2 Sample ID:

250993 Sample ID:

261279 S

0 0

O Sample ID:

251609 0

S O

Sample ID:

252075 0

Sample ID:

252692 0

Sample ID:

253078 0

S Sample ID:

253886 0

S Sample Dates: 112/2013 -1/812013 Sample Dates: 118/2013 - 1115/2013 Sample Dates: 1115/2013-1122/2013 Sample Dates: 1122/2013 - 1129/2013 Sample Dates: 112912013 -21512013 Sample Dates: 2V512013 - 2112/2013 Sample Dates: 2/12/2013 -2/19/2013 Sample Dates: 211912013 -2/2612013 Sample Dates: 2/2612013 -3/512013 Sample Dates: 3/512013 -3/12/2013 Nuclide Activity I Sigma Error LLD 1-131

<1.43E-02 0.OE+O0 1.43E-02 Cs-134

<1,16E-02 0.OOE+00 1.16E-02 Cs-137

<1.05E-02 O.OOE+00 1.05E-02 Be-7

<8,36E-02 0.OOE+00 8.36E-02 K-40 2.60E-01 7.77E-02 2.02E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.85E-02 0.OOE+00 1.85E-02 Cs-134

<1.41E-02 0.OOE+O0 1.41E-02 Cs-137

<1.27E-02 0.OOE+00 1.27E-02 Be-7

<9.66E-02 O.OOE+00 9.66E-02 K-40 4.02E-01 9.74E-02 2.47E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.30E-02 0.OOE+00 1.30E-02 Cs-134

<1.71E-02 0.OOE+00 1.71E-02 Cs-137

<1.69E-02 0.OOE+O0 1.69E-02 Be-7

<6.21E-02 0.OOE+O0 6.21E-02 K-40 5.74E-01 1.60E-01 2.46E-01 Nuclide Activity I Sigma Error 1-131

<1.78E-02 O.OOE+00 Cs-134

<1.45E-02 O.OOE+O0 Cs-137

<1.49E-02 0.OOE+00 Be-7

<1.03E-01 0.00E+00 K-40 3.08E-01 1.10E-01 Nuclide Activity Sigma Error 1-131

<1.12E-02 O.OOE+O0 Cs-1 34

<8.46E-03 O.OOE+O0 Cs-137

<9.43E-03 0.OOE+00 Be-7

<7.82E-02 O.OOE+O0 K-40 4.38E-01 9.55E-02 Nuclide Activity 1 Sigma Error 1-131

<1.08E-02 0.00E+00 Cs-1 34

<4.49E-03 O.OOE+00 Cs-137

<1.30E-02 O.OOE+00 Be-7

<6.35E-02 O.OOE+00 K-40 3.22E-01 6.72E-02 LLD 1.78E-02 1.45E-02 1.49E-02 1.03E-01 2.20E-01 LLD 1.12E-02 8.46E-03 9.43E-03 7.82E-02 5.63E-02 LLD 1.08E-02 4.49E-03 1.30E-02 6.35E-02 1.02E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.05E-02 0.OOE+00 1.05E-02 Cs-134

<1.38E-02 0.OOE+00 1.38E-02 Cs-137

<1.18E-02 0.OOE+00 1.18E-02 Be-7

<7.41E-02 0.00E+00 7.41E-02 K-40 5.32E-01 8.74E-02 1.06E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<8.35E-03 0.OOE+O0 8,35E-03 Cs-134

<6.78E-03 O.OOE+00 6.78E-03 Cs-137

<1.OOE-02 0.OOE+00 1.OOE-02 Be-7

<5.86E-02 O.OOE+00 5.86E-02 K-40 4.59E-01 7.88E-02 9.67E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.18E-02 0.OOE+00 1.18E-02 Cs-134

<8.89E-03 O.OOE+00 8.89E-03 Cs-137

<9.82E-03 0.OOE+00 9.82E-03 Be-7

<8.08E-02 O.00E+00 8.08E-02 K-40 2.96E-01 7.59E-02 1.19E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.86E-02 0.OOE+00 1.86E-02 Cs-134

<1.30E-02 0.00E+O0 1.30E-02 Cs-137

<9.46E-03 0.OOE+00 9.46E-03 Be-7

<1.26E-01 0.00E+00 1.26E-01 K-40

<4.93E-01 0.00E+00 4.93E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories In 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 25 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCilm3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

Sample ID:

254208 Sample ID:

254743 Sample ID:

256303 Sample ID:

255832 Sample ID:

256066 Sample ID:

256334 Sample ID:

256601 Sample ID:

257124 Sample ID:

257277 Sample ID:

257724 Sample Dates: 311212013 -3/1912013 Sample Dates: 311912013 -312612013 Sample Dates: 312612013 -4/212013 Sample Dates: 4/212013 -41912013 Sample Dates: 41912013 - 411612013 Sample Dates: 411612013 -4/2312013 Sample Dates: 4/2312013 -4/3012013 Sample Dates: 4/30)2013 - 517/2013 Sample Dates: 517/2013 -5114/2013 Sample Dates: 5114/2013-512112013 Nuclide Activity I Sigma Error LLD 1-131

<9.71E-03 O.OOE+0O 9.71E-03 Cs-134

<7.05E-03 0.OOE+00 7.05E-03 Cs-1 37

<8.00E-03 0.00E+00 8.00E-03 Be-7

<8.82E-02 0.00E+00 8.82E-02 K-40 6.33E-01 8.87E-02 9.11E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.29E-02 0.00E+00 1.29E-02 Cs-134

<1.04E-02 O.OOE+00 1.04E-02 Cs-1 37

<7.29E-03 0.00E+00 7.29E-03 Be-7

<6.67E-02 0.00E+00 6.67E-02 K-40 1.20E-01 6.96E-02 8.91E-02 Nuclide Activity I Sigma Error LLD 1-131

<9.14E-03 0.00E+00 9.14E-03 Cs-134

<8.02E-03 0.00E+00 8.02E-03 Cs-137

<8.90E-03 0.00E+00 8.90E-03 Be-7

<7.20E-02 0.00E+00 7.20E-02 K-40 4.54E-01 8.32E-02 1.05E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.91E-02 0.00E+00 1.91E-02 Cs-134

<1.45E-02 O.0OE+00 1.45E-02 Cs-137

<1.94E-02 0.00E+00 1.94E-02 Be-7

<1.24E-01 0.00E+00 1.24E-01 K-40 5.25E-01 1.12E-01 1.72E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.57E-02 0.00E+00 1.57E-02 Cs-134

<1.18E-02 O.00E+00 1.18E-02 Cs-137

<1.20E-02 0.00E+00 1.20E-02 Be-7

<9.16E-02 0.OOE+00 9.16E-02 K-40 2.69E-01 9.90E-02 2.56E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<9.98E-03 0.OOE+00 9.98E-03 Cs-134

<6.46E-03 0.OOE+00 6.46E-03 Cs-137

<8.92E-03 0.00E+00 8.92E-03 Be-7 7.77E-02 2.75E-02 5.79E-02 K-40 2.10E-01 7.99E-02 9.96E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.32E-02 0.OOE+00 1.32E-02 Cs-134

<9.33E-03 O.0OE+00 9.33E-03 Cs-137

<8.14E-03 0.00E+00 8.14E-03 Be-7

<6.91E-02 0.00E+00 6.91E-02 K-40 4.68E-01 8.39E-02 1.11E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.07E-02 0.00E+00 2.07E-02 Cs-134

<1.67E-02 0.00E+00 1.67E-02 Cs-137

<9.90E-03 0.00E+00 9.90E-03 Be-7

<1.26E-01 0.00E+00 1.26E-01 K-40 3.82E-01 9.55E-02 2.62E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.14E-02 0.00E+00 1.14E-02 Cs-134

<1.02E-02 0O02E+00 1.02E-02 Cs-137

<1.10E-02 O.OOE+00 1.10E-02 Be-7

<6.68E-02 0.00E+00 6.68E-02 K-40 3.52E-01 8.75E-02 1.34E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.33E-02 0.00E+00 1.33E-02 Cs-134

<1.05E-02 0.00E+00 1.05E-02 Cs-137

<1.72E-02 0.00E+00 1.72E-02 Be-7

<7.93E-02 0.00E+00 7.93E-02 K-40 3.29E-01 8.50E-02 2.77E-01 00 0

0 0

S 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EnR 13339 Hagers Ferry Road Huntersville, North Carolina 28078 0

Appendix 2 - Page 26 of 80 0

0 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOJODINE Concentration (Activity): pCi/m3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

Sample ID:

257968 O

Sample ID:

258203 0

0 Sample ID:

258550 0

0 O

Sample ID:

259020 Sample ID:

269568 0

0 S

Sample ID:

260202 0

0 O

Sample ID:

260662 0

0 0

Sample ID:

261625 S

0 Sample ID:

262127 0

0 Sample ID:

253143 S

0 Sample Dates: 612112013 - 612912013 Sample Dates: 512912013 -61412013 Sample Dates: 614/2013 -611/2013 Sample Dates: 611/2013 -611812013 Sample Dates: 6/1812013 -6/25/2013 Sample Dates: 6/2512013-71212013 Sample Dates: 712/2013 -71912013 Sample Dates: 71912013 -711612013 Sample Dates: 7/16/2013 -7/2312013 Sample Dates: 7/23/2013 - 7/30/2013 Nuclide Activity I Sigma Error LLD 1-131

<2.45E-02 0.00E+00 2.45E-02 Cs-134

<1.33E-02 0.OOE+00 1.33E-02 Cs-137

<9.91E-03 0.00E+00 9,91E-03 Be-7

<1.18E-01 0.OOE+00 1.18E-01 K-40 5.87E-01 1.20E-01 2.10E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.70E-02 0.00E+00 2.70E-02 Cs-134

<1.81E-02 O.00E+00 1.81E-02 Cs-137

<1.74E-02 0.00E+00 1.74E-02 Be-7

<1.61E-01 O.OOE+00 1.61E-01 K-40 6.81E-01 1.52E-01 3.92E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.47E-02 O.OOE+00 1.47E-02 Cs-134

<1.06E-02 O.00E+00 1.06E-02 Cs-137

<1.32E-02 O.00E+00 1.32E-02 Be-7

<8.44E-02 0.00E+00 8.44E-02 K-40 6.99E-01 1.11E-01 1.31E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.16E-02 O.00E+00 2.16E-02 Cs-134

<2.06E-02 O.OOE+00 2.06E-02 Cs-137

<1.98E-02 0.00E+00 1.98E-02 Be-7

<1.23E-01 0.00E+00 1.23E-01 K-40 2.78E-01 1.30E-01 2.04E-01 Nuclide Activity I Sigma Error 1-131

<9.25E-03 0.00E+00 Cs-134

<8.39E-03 0.00E+00 Cs-137

<8.17E-03 O.0OE+00 Be-7

<5.86E-02 0.OOE+00 K-40 4.83E-01 7.74E-02 Nuclide Activity 1 Sigma Error 1-131

<1.11E-02 0.OOE+00 Cs-134

<9.76E-03 O.00E+00 Cs-137

<1.43E-02 0.00E+00 Be-7

<8.99E-02 0.00E+00 K-40 2.44E-01 7.05E-02 LLD 9.25E-03 8.39E-03 8.17E-03 5.86E-02 1.12E-01 LLD 1.11E-02 9.76E-03 1.43E-02 8.99E-02 2.25E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.31E-02 0.00E+00 2.31E-02 Cs-134

<1.56E-02 0.OOE+00 1.56E-02 Cs-137

<4.28E-03 0.00E+00 4.28E-03 Be-7

<1.57E-01 0.00E+00 1.57E-01 K-40

<4.56E-01 0.00E+00 4.56E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.01E-02 0.00E+00 1.01E-02 Cs-134

<8.82E-03 0.OOE+00 8.82E-03 Cs-137

<8.38E-03 0.00E+00 8.38E-03 Be-7

<7.47E-02 0.00E+00 7.47E-02 K-40 4.95E-01 8.24E-02 1.27E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.23E-02 0.00E+00 2.23E-02 Cs-134

<1.85E-02 0.OOE+00 1.85E-02 Cs-137

<1.54E.02 O.00E+00 1.54E-02 Be-7

<1.47E-01 0.00E+00 1.47E-01 K-40 5.102-01 1.20E-01 7.66E-02 Nuclide Activity I Sigma Error LLD 1-131

<2.34E-02 0.00E+00 2.34E-02 Cs-134

<2.19E-02 0.00E+00 2.19E-02 Cs-137

<2.01E-02 0.00E+00 2.01E-02 8e-7

<1.46E-01 0.00E+00 1.46E-01 K-40

<5.07E-01 0.00E+00 5.07E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories jjj 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 27 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

Sample ID:

263370 Sample ID:

264028 Sample ID:

265159 Sample ID:

265468 Sample ID:

267154 Sample ID:

267604 Sample ID:

268469 Sample ID:

269582 Sample ID:

270726 Sample ID:

271450 Sample Dates: 7130/2013 -81612013 Sample Dates: 8/6/2013 -811312013 Sample Dates: 8113/2013-812012013 Sample Dates: 8120/2013.812712013 Sample Dates: 812712013 -9/412013 Sample Dates: 9/4/2013 -911012013 Sample Dates: 9/10/2013-9/17/2013 Sample Dates: 9/17/2013 -9124/2013 Sample Dates: 9/24/2013 - 101112013 Sample Dates: 10/1/2013 -10/8/2013 Nuclide Activity i Sigma Error LLD 1-131

<1.73E-02 0.00E+00 1.73E-02 Cs-134

<1.63E-02 0.00E+00 1.63E-02 Cs-137

<2.03E-02 O.00E+00 2.03E-02 Be-7

<1.23E-01 0.00E+00 1.23E-01 K-40

<5.37E-01 0.OOE+00 5.37E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.66E-02 0.OOE+00 2.66E-02 Cs-134

<1.91E-02 0.00E+00 1.91E-02 Cs-137

<1.98E-02 0.O0E+00 1.98E-02 Be-7

<1.62E-01 0.00E+00 1.62E-01 K-40

<5.89E-01 0.00E+00 5.89E-01 Nucilde Activity 1 Sigma Error LLD 1-131

<2.20E-02 0.OOE+00 2.20E-02 Cs-134

<1.52E-02 0.00E+00 1.52E-02 Cs-137

<2.57E-02 0.00E+00 2.57E-02 Be-7

<1.51E-01 0.00E+00 1.51E-01 K-40

<5.87E-01 0.00E+00 5.87E-01 Nuclide Activity i Sigma Error 1-131

<7.45E-03 0.00E+00 Cs-134

<1.13E-02 O.00E+00 Cs-137

<1.01E-02 0.00E+00 Be-7

<8.82E-02 0.00E+00 K-40 3.02E-01 8.07E-02 LLD 7.45E-03 1.13E-02 1.01 E-02 8.82E-02 1.90E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<9.51E-03 O.OOE+00 9.51E-03 Cs-134

<7.25E-03 0.00E+00 7.25E-03 Cs-137

<8.82E-03 0.00E+00 8.82E-03 Be-7

<5.45E-02 0.00E+00 5.45E-02 K-40 3.36E-01 6.76E-02 9.44E-02 Nuclide Activity I Sigma Error LLD 1-131

<2.50E-02 0.OOE+00 2.50E-02 Cs-134

<2.03E-02 0.00E+00 2.03E-02 Cs-137

<2.25E-02 0.00E+00 2.25E-02 Be-7

<1.70E-01 0.00E+00 1.70E-01 K-40 4.67E-01 1.25E-01 9.01 E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.54E-02 0.00E+00 2.54E-02 Cs-1i34

<1.66E-02 0.00E+00 1.66E-02 Cs-137

<1.45E-02 0.00E+00 1.45E-02 Be-7

<1.50E-01 0.00E+00 1.50E-01 K-40

<6.22E-01 0.00E+00 6.22E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.44E-02 0.00E+00 2.44E-02 Cs-134

<1.71E-02 0.00E+00 1.71E-02 Cs-137

<1.90E-02 0.00E+00 1.90E-02 Be-7

<1.39E-01 0.00E+00 1.39E-01 K-40 4.02E-01 1.07E-01 3.56E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.16E-02 0.00E+00 2.16E-02 Cs-134

<1.55E-02 0.00E+00 1.55E-02 Cs-137

<1.79E-02 O.OOE+00 1.79E-02 Be-7

<1.09E-01 0.00E+00 1.09E.01 K-40

<3.43E-01 0.00E+00 3.43E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.87E-02 0.00E+00 1.87E-02 Cs-134

<1.79E-02 0.00E+00 1.79E-02 Cs-137

<1.96E-02 0.00E+00 1.96E-02 Be-7

<1.65E-01 0.00E+00 1.65E-01 K-40 5.16E-01 1.22E-01 7.74E-02 66 6

6 6

0 S

6 0

S 0

0 0

S S

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories R

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 28 of 80 S

S

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR RADIOIODINE Concentration (Activity): pCl/m3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

O Sample ID:

272057 0

0 Sample ID:

272440 0

0 Sample ID:

272841 0

O Sam pie ID:

273933 0

Sample ID:

274380 0

0 0

Sample ID:

274894 0

O Sample ID:

278448 S

0 O

Sample ID:

278763 0

S Sample ID:

278834 0

O Sample ID:

279074 0

S Sample Dates: 101812013 - 1011512013 Sample Dates: 1011812013 -1012212013 Sample Dates: 10/2212013 -1012912013 Sample Dates: 1012912013 -11/512013 Sample Dates: 111512013 - 1111212013 Sample Dates: 1111212013-1111912013 Sample Dates: 11/19/2013 - 11/2512013 Sample Dates: 1112512013-12/312013 Sample Dates: 121312013 - 12/10/2013 Sample Dates: 12/10/2013 -1211712013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.45E-02 0.00E+00 2.45E-02 Cs-134

<2.26E-02 0.002+00 2.26E-02 Cs-137

<1.15E-02 O.OOE+00 1.15E-02 Be-7

<1.39E-01 0.00E+00 1.39E-01 K-40 2.50E-01 1.36E-01 3.13E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.75E-02 0.OOE+00 1.75E-02 Cs-134

<2.43E-02 O.00E+00 2.43E-02 Cs-137

<2.16E-02 0.00E+00 2.16E-02 Be-7

<1.43E-01 0.00E+00 1.43E-01 K-40 5.14E-01 1.21E-01 2.13E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.14E-02 0.00E+00 1.14E-02 Cs-134

<1.05E-02 0.00E+00 1.05E-02 Cs-137

<1.12E-02 0.00E+00 1.12E-02 Be-7

<4.95E-02 0.00E+00 4.95E-02 K-40 5.17E-01 9.03E-02 1.10E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.24E-02 0.00E+00 1.24E-02 Cs-134

<9.78E-03 0.00E+00 9.78E-03 Cs-137

<1.25E-02 0.00E+00 1.25E-02 Be-7

<8.55E-02 0.00E+00 8.55E-02 K-40 3.49E-01 8.23E-02 1.41 E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.92E-02 0.00E+00 1.92E-02 Cs-134

<1.88E-02 O.00E+00 1.88E-02 Cs-137

<1.76E-02 0.00E+00 1.76E-02 Be-7

<1.31E-01 0.00E+00 1.31E-01 K-40 6.76E-01 1.38E-01 3.49E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.25E-02 0.00E+00 2.25E-02 Cs-134

<2.03E-02 O.OOE+00 2.03E-02 Cs-137

<2.11E-02 0.00E+00 2.11E-02 Be-7

<1.29E-01 0.00E+00 1.29E-01 K-40 3.202-01 9.65E-02 3.40E-01 Nuclide Activity I Sigma Error 1-131

<2.56E-02 0.00E+00 Cs-134

<2.12E-02 0.00E+00 Cs-137

<2.46E-02 0.00E+00 Be-7

<1.95E-01 0.00E+00 K-40 6.16E-01 1.41E-01 Nuclide Activity 1 Sigma Error 1-131

<1.25E-02 0.00E+00 Cs-134

<8.19E-03 0.00E+00 Cs-i 37

<9.75E-03 0.00E+00 Be-7

<5.19E-02 O.00E+00 K-40 4.44E-01 7.12E-02 Nuclide Activity 1 Sigma Error 1-131

<2.60E-02 0.00E+00 Cs-134

<2.15E-02 0.00E+00 Cs-137

<2.24E-02 O.OOE+00 Be-7

<1.52E-01 0.00E+00 K-40

<6.14E-01 0.002+00 Nuclide Activity 1 Sigma Error 1-131

<2.39E-02 0.00E+00 Cs-134

<1.74E-02 0.00E+00 Cs-137

<2.09E-02 0.00E+00 Be-7

<1.81E-01 0.00E+00 K-40 5.26E-01 1.64E-01 LLD 2.56E-02 2.12E-02 2.46E-02 1.95E-01 2.79E-01 LLD 1.25E-02 8.19E-03 9.75E-03 5.19E-02 1.09E-01 LLD 2.60E-02 2,15E-02 2.24E-02 1.52E-01 6.14E-01 LLD 2.39E-02 1.74E-02 2.09E-02 1.81E-01 3.04E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 29 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCilm3 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

Sample ID:

279702 Sample Dates: 1211712013 - 1212312013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.80E-02 0.00E+00 2.80E-02 Cs-134

<2.07E-02 O.OOE+00 2.07E-02 Cs-137

<2.51E-02 0.OOE+O0 2.51E-02 Be-7

<1.60E-01 O.OOE+00 1.60E-01 K-40 4.94E-01 1.28E-01 3.00E-01 Sample ID:

280191 Sample Dates: 1212312013 - 1213112013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.61E-02 0.OOE+O0 1.61E-02 Cs-134

<1.21E-02 O.OOE+00 1.21E-02 Cs-137

<1.31E-02 0.OOE+00 1.31 E-02 Be-7

<1.36E-01 O.OOE+00 1.36E-01 K-40 6.12E-01 1.37E-01 1.57E-01 Sample Point 212 [ INDICATOR - E @ 3.32 miles I Sample ID:

250447 Sample Dates: 11212013.11812013 Nuclide Activity 1 Slama Error LLD 60 6

6 0

0 0

6 0

0 0I S

S 0

Sample ID:

250577 Sample ID:

260746 Sample ID:

250994 Sample ID:

251280 Sample ID:

251610 Sample ID:

252076 Sample ID:

252693 Sample Dates: 11812013 -1115/2013 Sample Dates: 111512013 -112212013 Sample Dates: 112212013.112912013 Sample Dates: 1129/2013 - 21512013 Sample Dates: 21512013 -211212013 Sample Dates: 211212013 -211912013 Sample Dates: 2/1912013 -2/2612013 1-131

<8.31E-03 O.OOE+00 Cs-134

<9.14E-03 O.OOE+00 Cs-137

<1.23E-02 O.OOE+00 Be-7

<6.31 E-02 0.OOE+00 K-40 5.15E-01 7.77E-02 Nuclide Activity I Sigma Error 1-131

<2.06E-02 0.OOE+00 Cs-134

<1.82E-02 0.00E+00 Cs-137

<1.44E-02 O.00E+00 Be-7

<8.98E-02 O.00E+00 K-40 1.90E-01 6.70E-02 Nuclide Activity 1 Sigma Error 1-131

<1.01E-02 0.00E+00 Cs-134

<9.32E-03 0.00E+00 Cs-137

<1.42E-02 0.OOE+00 Be-7

<7.53E-02 0.OOE+00 K-40

<3.36E-01 0.OOE+00 Nuclide Activity I Sigma Error 1-131

<1.86E-02 0.OOE+00 Cs-134

<1.50E-02 0.00E+00 Cs-137

<1.69E-02 0.OOE+00 Be-7

<1.22E-01 0.OOE+00 K-40 2.73E-01 1.08E-01 8.31 E-03 9.14E-03 1.23E-02 6.31 E-02 3.17E-02 LLD 2.06E-02 1.82E-02 1.44E-02 8.98E-02 6.41 E-02 LLD 1.01 E-02 9.32E-03 1.42E-02 7.53E-02 3.36E-01 LLD 1.86E-02 1.50E-02 1.69E-02 1.22E-01 1.74E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.72E-02 0.OOE+00 1.72E-02 Cs-134

<1.62E-02 0.OOE+00 1.62E-02 Cs-137

<1.57E-02 0.OOE+00 1.57E-02 Be-7

<1.21E-01 O.OOE+00 1.21E-01 K-40 2.29E-O1 1.19E-01 2.08E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.67E-02 0.OOE+00 1.67E-02 Cs-134

<1.47E-02 0.00E+00 1.47E-02 Cs-137

<1.14E-02 0.00E+00 1.14E-02 Be-7

<1.10E-01 0.OOE+00 1.10E-01 K-40 5.14E-01 1.07E-01 6.04E-02 Nuclide Activity I Sigma Error LLD 1-131

<9.94E-03 0.OOE+00 9,94E-03 Cs-134

<8.71E-03 0.OOE+00 8.71E-03 Cs-137

<1.03E-02 0.OOE+00 1.03E-02 Be-7

<6.44E-02 0.OOE+00 6.44E-02 K-40 3.75E-01 7.22E-02 1.46E-O1 Nuclide Activity 1 Sigma Error LLD 1-131

<1.02E-02 O.OOE+00 1.02E-02 Cs-134

<7.89E-03 O.OOE+00 7.89E-03 Cs-137

<1.62E-02 O.OOE+00 1.62E-02 Be-7

<8.32E-02 0.OOE+00 8.32E-02 K-40 5.17E-01 1.10E-01 1.68E-01 00 0

0 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 30 of 80 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 212 [ INDICATOR - E @ 3.32 miles ]

S Sample ID:

253079 0

0 S

Sample ID:

253887 0

0 0

-Sample ID:

254209 0

0 S

Sample ID:

254744 0

S S

Sample ID:

255304 0

0 0S Sample ID:

255833 0

0 S

Sample ID:

256067 00 0

S Sample ID:

256335 S

0 S

Sample ID:

256602 S

S S

Sample ID:

257125 S

0 S

Sample Dates: 212612013 - 31/62013 Sample Dates: 31512013 -3112/2013 Sample Dates: 311212013.3/1912013 Sample Dates: 311912013 -3126/2013 Sample Dates: 312612013 -41212013 Sample Dates: 412/2013.419/2013 Sample Dates: 4/912013 -4/16/2013 Sample Dates: 411612013 -4/2312013 Sample Dates: 4/23/2013 -4/3012013 Sample Dates: 4/30/2013 -51712013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.54E-02 0.00E+00 1.54E-02 Cs-134

<1.40E-02 0.OOE+00 1.40E-02 Cs-137

<1.64E-02 O.00E+00 1.64E-02 Be-7

<6.87E-02 0.00E+00 6.87E-02 K-40 5.26E-01 1.12E-01 2.62E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.95E-02 0.00E+00 1.95E-02 Cs-134

<1.64E-02 0.OOE+00 1.64E-02 Cs-137

<1.38E-02 0.00E+00 1.38E-02 Be-7

<1.08E-01 0.OOE+00 1.08E-01 K-40

<3.96E-01 0.00E+00 3.96E-01 Nuclide Activity I Sigma Error LLD 1-131

<7.73E-03 0.00E+00 7.73E-03 Cs-134

<6.54E-03 0.00E+00 6.54E-03 Cs-137

<6.11E-03 O.OOE+00 6.11E-03 Be-7

<4.92E-02 0.0OE+00 4.92E-02 K-40 3.87E-01 5.67E-02 6.27E-02 Nuclide Activity 1 Sigma Error 1-131

<1.15E-02 0.00E+00 Cs-134

<1.43E-02 O.00E+00 Cs-137

<1.18E-02 0.00E+00 Be-7

<6.87E-02 O.OOE+00 K-40

<4.72E-01 O.00E+00 Nuclide Activity I Sigma Error 1-131

<1.48E-02 O.00E+00 Cs-134

<1.60E-02 0.OOE+00 Cs-137

<9.74E-03 0.00E+00 Be-7

<1.06E-01 0.OOE+00 K-40 3.53E-01 9.12E-02 Nuclide Activity 1 Sigma Error 1-131

<1.42E-02 0.OOE+00 Cs-134

<2.05E-02 0.00E+00 Cs-137

<1.92E-02 0.OOE+00 Be-7

<1.11E-01 0.00E+00 K-40 3.39E-01 1.18E-01 LLD 1.15E-02 1.43E-02 1.18E-02 6.87E-02 4.72E-01 LLD 1.48E-02 1.60E-02 9.74E-03 1.06E-01 1.77E-01 LLD 1.42E-02 2.05E-02 1.92E-02 1.11E-01 2.80E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.02E-02 0.00E+00 1.02E-02 Cs-134

<6.56E-03 O.00E+00 6.56E-03 Cs-137

<1.70E-02 0.00E+00 1.70E-02 Be-7

<8.55E-02 0.00E+00 8.55E-02 K-40 4.80E-01 9.80E-02 5.41 E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.19E-02 0.00E+00 1.19E-02 Cs-134

<1.41E-02 0.00E+00 1.41E-02 Cs-I 37

<1.76E-02 0.00E+00 1.78E-02 Be-7

<1.19E-01 O.00E+00 1.19E-01 K-40 3.37E-01 8.71E-02 6.08E-02 Nuclide Activity I Sigma Error LLD 1-131

<1.12E-02 0.00E+00 1.12E-02 Cs-134

<5.97E-03 0.00E+00 5.97E-03 Cs-137

<9.50E-03 0.00E+00 9.50E-03 Be-7

<6.03E-02 0.00E+00 6.03E-02 K-40 2.31E-01 5.60E-02 9.61 E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.56E-02 0.00E+00 1.56E-02 Cs-1 34

<1.59E-02 0.00E+00 1.59E-02 Cs-137

<1.55E-02 0.00E+00 1.55E-02 Be-7

<1.14E-01 0.00E+00 1.14E-01 K-40 3.34E-01 1.10E-01 3.04E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En jj* 13339 Hagers Ferry Road Huntersville. North Carolina 28078 Appendix E - Page 31 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 212 [ INDICATOR - E @ 3.32 miles ]

Sample ID:

257278 Sample ID:

267725 Sample ID:

257969 Sample ID:

258204 Sample ID:

258551 Sample ID:

259021 Sample ID:

259569 Sample ID:

260203 Sample ID:

260663 Sample ID:

261626 Sample Dates: 5/712013 - 5/1412013 Sample Dates: 5/1412013 - 5121/2013 Sample Dates: 512112013 -8/2912013 Sample Dates: 5129/2013 -614/2013 Sample Dates: 5/4/2013 - 611112013 Sample Dates: 6/1112013 -6/1812013 Sample Dates: 6/18/2013 -6/26/2013 Sample Dates: 612512013 -712/2013 Sample Dates: 712/2013 - 7/912013 Sample Dates: 7/9/2013 -7/16/2013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.35E-02 0.00E+00 1.35E-02 Cs-134

<1.50E-02 0.00E+00 1.50E-02 Cs-137

<1.81E-02 0.00E+00 1.81E-02 Be-7

<1.20E-01 0.00E+00 1.20E-01 K-40 4.77E-01 1.30E-01 1.74E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.18E-02 0.OOE+00 1.18E-02 Cs-134

<8.16E-03 0.00E+00 8.16E-03 Cs-137

<1.27E-02 0.00E+00 1.27E-02 Be-7

<8.59E-02 0.00E+00 8.59E-02 K-40 5.46E-01 1.05E-01 1.46E-01 Nuclide Activity I Sigma Error 1-131

<1.79E-02 0.OOE+00 Cs-134

<7.40E-03 0.00E+00 Cs-137

<2.05E-02 0.00E+00 Be-7

<1.59E-01 0.00E+00 K-40 4.14E-01 1.OOE-01 Nuclide Activity 1 Sigma Error 1-131

<2.28E-02 0.00E+00 Cs-134

<2.29E-02 0.00E+00 Cs-137

<2.65E-02 O.00E+00 Be-7

<1.56E-01 0.00E+00 K-40 8.18E-01 1.67E-01 Nuclide Activity 1 Sigma Error 1-131

<1.34E-02 O.OOE+00 Cs-134

<1.03E-02 O.00E+00 Cs-1 37

<1.58E-02 O.00E+00 Be-7

<1.12E-01 0.OOE+00 K-40 3.29E-01 1.12E-01 Nuclide Activity 1 Sigma Error 1-131

<1.92E-02 0.OOE+00 Cs-134

<1.74E-02 0.00E+00 Cs-137

<1.93E-02 0.00E+00 Be-7

<7.72E-02 0.00E+00 K-40 5.40E-01 1.24E-01 LLD 1.79E-02 7.40E-03 2.05E-02 1.59E-01 2.20E-01 LLD 2.28E-02 2.29E-02 2.65E-02 1.56E-01 3.78E-01 LLD 1.34E-02 1.03E-02 1.58E-02 1.12E-01 6.58E-02 LLD 1.92E-02 1.74E-02 1.93E-02 7.72E-02 2.04E-01 00 S

0 0

Nuclide Activity I Sigma Error LLD 1-131

<8.31E-03 0.00E+00 8.31E-03 Cs-134

<1.08E-02 0.00E+00 1.08E-02 Cs-137

<1.15E-02 0.00E+00 1.15E-02 Be-7

<8.18E-02 0.00E+00 8.18E-02 K-40

<3.78E-01 0.00E+00 3.78E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<9.42E-03 O.OOE+00 9.42E-03 Cs-134

<8.86E-03 0.OOE+00 8.86E-03 Cs-137

<1.17E-02 0.00E+00 1.17E-02 Be-7

<5.43E-02 0.00E+00 5.43E-02 K-40 4.59E-01 7.99E-02 1.25E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.13E-02 0.00E+00 2.13E-02 Cs-134

<1.33E-02 0.00E+00 1.33E-02 Cs-137

<1.89E-02 0.00E+00 1.89E-02 Be-7

<1.71E.01 0.00E+00 1.71E-01 K-40 6.06E-01 1.32E-01 2.75E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.12E-02 0.00E+00 1.12E-02 Cs-134

<1.04E-02 0.00E+00 1.04E-02 Cs-137

<1.17E-02 0.00E+00 1.17E-02 Be-7 5.54E-02 2.68E-02 6.93E-02 K-40 4.82E-01 8.76E-02 1.30E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 0

Appendix E - Page 32 of 80 0

0 0

00 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR RADIOIODINE Concentration (Activity): pCIlm3 Sample Point 212 [ INDICATOR - E @ 3.32 miles I Sample ID:

262128 00 Sample ID:

263144 0

Sample ID:

263371 0

0 O

Sample ID:

264029 00 Sample ID:

265469 0

Sample ID:

267156 0

0 Sample ID:

268460 0

0 O

Sample ID:

269158 0

0 0

Sample Dates: 7/1612013 - 7/2312013 Sample Dates: 7/23/2013 - 7/3012013 Sample Dates: 7130/2013 -81612013 Sample Dates: 81612013 -811312013 Sample Dates: 811312013-812012013 Sample Dates: 812012013 -8/2712013 Sample Dates: 8/27/2013 -914/2013 Sample Dates: 9/4/2013 - 9/10/2013 Sample Dates: 9/10/2013 -911712013 Sample Dates: 9/17/2013-9124/2013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.21E-02 0.OOE+00 2.21E-02 Cs-134

<1.42E-02 0.OOE+00 1.42E-02 Cs-137

<1.95E-02 o.00E+00 1.95E-02 Be-7

<1.79E-01 0.00E+00 1.79E-01 K-40

<5.50E-01 0.00E+00 5.50E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.29E-02 O.OOE+O0 2.29E-02 Cs-134

<1.83E-02 0.00E+00 1.83E-02 Cs-137

<2.64E-02 0.00E+00 2.64E-02 Be-7

<1.42E-01 0.OOE+00 1.42E-01 K-40

<5.65E-01 O.OOE+00 5.65E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.78E-02 0.00E+00 1.78E-02 Cs-134

<1.52E-02 0.00E+00 1.52E-02 Cs-137

<1.34E-02 0.00E+00 1.34E-02 Be-7

<1.30E-o01 O.00E+00 1.30E-01 K-40 5.70E-01 1.27E-01 7.70E-02 Nuclide Activity I Sigma Error 1-131

<2.23E-02 0.OOE+00 Cs-134

<1.95E-02 0.00E+00 Cs-137

<1.46E-02 0.00E+00 Be-7

<1.54E-01 0.00E+00 K-40

<4.68E-0i 0.00E+00 Nuclide Activity I Sigma Error 1-131

<2.70E-02 0.00E+00 Cs-134

<2.17E-02 O.OOE+00 Cs-137

<2.22E-02 0.00E+00 Be-7

<1.78E-01 O.OOE+00 K-40 4.15E-01 1.36E-01 LLD 2.23E-02 1.95E-02 1.46E-02 1.54E-01 4.68E-01 LLD 2.70E-02 2.17E-02 2.22E-02 1.78E-01 2.13E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.86E-02 0.00E+00 1.86E-02 Cs-134

<1.69E-02 0.OOE+00 1.69E-02 Cs-137

<2.25E-02 0.00E+00 2.25E-02 Be-7

<1.62E-01 0.00E+00 1.62E-01 K-40

<5.05E-01 O.OOE+00 5.05E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.30E-02 0.00E+00 2.30E-02 Cs-134

<1.42E-02 0.OOE+00 1.42E-02 Cs-137

<2.26E-02 0.OOE+00 2.26E-02 Be-7

<1.38E-01 0.00E+00 1.38E-01 K-40

<5.00E-01 0.00E+00 5.00E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.09E-02 O.00E+00 1.09E-02 Cs-134

<1.46E-02 0.OOE+00 1.46E-02 Cs-137

<1.60E-02 0.00E+00 1.60E-02 Be-7

<1.20E-01 0.OOE+00 1.20E-01 K-40 3.50E-01 9.37E-02 6.77E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.05E-02 0.00E+00 1.05E-02 Cs-134

<1.26E-02 0.OOE+00 1.26E-02 Cs-137

<1.06E-02 0.00E+00 1.06E-02 Be-7

<9.25E-02 0.00E+00 9.25E-02 K-40 3.84E-01 9.06E-02 5.77E-02 Nuclide Activity I Sigma Error LLD 1-131

<2.14E-02 0.00E+00 2.14E-02 Cs-134

<1.45E-02 0.00E+00 1.45E-02 Cs-137

<1.72E-02 0.00E+00 1.72E-02 Be-7

<1.58E-01 0.00E+00 1.58E-01 K-40 3.48E-01 1.00E-01 2.78E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 33 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCIlm3 Sample Point 212 [ INDICATOR - E @ 3.32 miles ]

Sample IDM 270726 Sample ID:

271451 Sample ID, 272058 Sample ID:

272441 Sample ID:

272842 Sample ID:

273934 Sample ID:

274381 Sample ID:

274895 Sample ID:

276449 Sample ID:

278764 Sample Dates: 9124/2013 - 101112013 Sample Dates: 101112013 -101812013 Sample Dates: 101812013-1011512013 Sample Dates: 1011512013 -1012212013 Sample Dates: 1012212013.1012912013 Sample Dates: 1012912013 - 111512013 Sample Dates: 111512013-1111212013 Sample Dates: 1111212013-1111912013 Sample Dates: 1111912013 -1112512013 Sample Dates: 1112512013.121312013 Nuclide Activity I Sigma Error LLD 1-131

<2.OOE-02 0.00E+00 2.00E-02 Cs-134

<2.18E-02 0.00E+00 2.18E-02 Cs-1 37

<2.01E-02 0.00E+00 2.01 E-02 Be-7

<1.35E-01 0.00E+00 1.35E-01 K-40 3.85E-01 1.51E-01 2.60E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.03E-02 0.00E+00 2.03E-02 Cs-134

<1.83E-02 O.OOE+00 1.83E-02 Cs-137

<1.89E-02 0.00E+00 1.89E-02 Be-7

<1.50E-01 0.00E+00 1.502-01 K-40 4.30E-01 1.11E-01 2.17E-01 Nuclide Activity Sigma Error LLD 1-131

<2.41E-02 0.0OE+00 2.41E-02 Cs-134

<1.12E-02 0.00E+00 1.12E-02 Cs-137

<2.76E-02 O.00E+00 2.76E-02 Be-7

<1.47E-01 0.00E+00 1.47E-01 K-40 5.61 E-01 1.26E-01 2.50E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.07E-02 0.OOE+00 1.07E-02 Cs-134

<1.11E-02 O.00E+00 1.11E-02 Cs-137

<9.79E-03 0.00E+00 9.79E-03 Be-7

<9.40E-02 0.00E+00 9.40E-02 K-40 5.29E-01 9.00E-02 8.90E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.30E-02 O.00E+00 1.30E-02 Cs-134

<1.15E-02 0.00E+00 1.15E-02 Cs-137

<1.06E-02 0.00E+00 1.06E-02 Be-7

<1.03E-01 0.00E+00 1.03E-01 K-40 5.84E-01 1.12E-01 1.58E-01 0

0 0

Nuclide Activity 1 Sigma Error 1-131

<2.53E-02 0.00E+00 Cs-134

<1.32E-02 0.00E+00 Cs-137

<2.15E-02 0.00E+00 Be-7

<1.81E-01 0.00E+00 K-40 7.44E-01 1.46E-01 LLD 2.53E-02 1.32E-02 2.15E-02 1.81 E-01 2.06E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.90E-02 0.00E+00 1.90E-02 Cs-134

<1.85E-02 O.00E+00 1.85E-02 Cs-137

<2.01E-02 0.00E+00 2.01E-02 Be-7

<1.43E-01 0.00E+00 1.43E-01 K-40 2.79E-01 1.37E-01 3.10E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.50E-02 0.00E+00 1.50E-02 Cs-134

<1.91E-02 0.OOE+00 1.91E-02 Cs-137

<2.21E-02 0.00E+00 2.21E-02 Be-7

<1.21E-01 0.00E+00 1.21E-01 K-40 4.68E-01 1.41E-01 3.08E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.46E-02 0.00E+00 1.46E-02 Cs-134

<1.59E-02 0.00E+00 1.59E-02 Cs-137

<9.06E-03 0.00E+00 9.06E-03 Be-7

<1.43E-01 0.OOE+00 1.43E-01 K-40 5.07E-01 1.16E-01 1.92E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.07E-02 0.00E+00 2.07E-02 Cs-134

<9.82E-03 0.00E+00 9.82E-03 Cs-137

<1.50E-02 0.00E+00 1.50E-02 Be-7

<1.61E-01 0.00E+00 1.61E-01 K-40

<4.41E-01 0.00E+00 4.41 E-01 0

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En I 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 34 of 80 0

0 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 212 [ INDICATOR - E @ 3.32 miles ]

Sample ID:

278835 0

Sample ID:

279075 S Sample ID:

279703 0

S Sample Dates: 12J312013 - 1211012013 Sample Dates: 12/1012013 -1211712013 Sample Dates: 1211712013 - 1212312013 Nuclide Activity I Sigma Error LLD 1-131

<2.39E-02 0.00E+00 2.39E-02 Cs-134

<2.08E-02 0.00E+00 2.08E-02 Cs-137

<2.01 E-02 0.00E+00 2.01 E-02 Be-7

<1.58E-01 0.00E+00 1.58E-01 K-40 5.56E-01 1.24E-01 2.64E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.16E-02 O.00E+00 1.16E-02 Cs-134

<8.59E-03 0.00E+00 8.59E-03 Cs-137

<1.09E-02 0.00E+00 1.09E-02 Be-7

<8.42E-02 0.00E+00 8.42E-02 K-40 6.81E-01 9.18E-02 3.35E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.42E-02 0.00E+00 2.42E-02 Cs-134

<2.06E-02 0.OOE+00 2.06E-02 Cs-137

<2.14E-02 0.00E+00 2.14E-02 Be-7

<1.35E-01 0.00E+00 1.35E-01 K-40 4.86E-01 1.26E-01 8.76E-02 Nuclide Activity I Sigma Error LLD 1-131

<2.24E-02 0.00E+00 2.24E-02 Cs-134

<1.75E-02 0.00E+00 1.75E-02 Cs-137

<1.28E-02 0.00E+00 1.28E-02 Be-7

<1.38E-01 0.00E+00 1.38E-01 K-40 5.24E-01 1.14E-01 1.80E-01 Sample ID:

280192 Sample Dates: 12/231201 0

Sample Point 258 [ CONTROL - W @ 9.84 miles]

Sample ID:

250448 Sample Dates: 1021201 00 Sample ID:

250578 Sample Dates: 1181201:

0 3 -12/3112013 3 -1/812013 Nuclide Activity I Sigma Error LLD 1-131

<6.86E-03 0.00E+00 6.86E-03 Cs-134

<7.21E-03 0.00E+00 7.21E-03 Cs-137

<9.16E-03 0.00E+00 9.16E-03 Be-7

<4.20E-02 0.00E+00 4.20E-02 K-40 3.23E-01 7.35E-02 8.94E-02 3 - 111512013 Nuclide Activity 1 Sigma Error 1-131

<1.62E-02 0.00E+00 Cs-134

<1.01E-02 0.00E+00 Cs-137

<1.54E-02 0.00E+00 Be-7

<1.23E-01 0.00E+00 K-40 3.51E-01 9.05E-02 LLD 1.62E-02 1.01E-02 1.54E-02 1.23E-01 2.72E-01 Sample ID:

260747 0

Sample ID:

2509965 0

Sample ID:

261281 Sample ID:

261811 S

0 Sample Dates: 1/1652013-112212013 Sample Dates: 1/22/2013 -1/2912013 Sample Dates: 1/29/2013 -21512013 Sample Dates: 2/612013-2/12/2013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.22E-02 0.00E+00 1.22E-02 Cs-134

<9.60E-03 0.00E+00 9.60E-03 Cs-137

<1.14E-02 0.00E+00 1.14E-02 Be-7

<6.33E-02 0.00E+00 6.33E-02 K-40 3.39E-01 8.94E-02 1.47E-01 Nuclide Activity Sigma Error LLD 1-131

<1.68E-02 O.OOE+00 1.68E-02 Cs-134

<1.58E-02 0.00E+00 1.58E-02 Cs-137

<1.50E-02 0.00E+00 1.50E-02 Be-7

<1.26E-01 0.00E+00 1.26E-01 K-40

<5.23E-01 0.00E+00 5.23E-01 Nuclide Activity I Sigma Error LLD 1-131

<9.32E-03 0,00E+00 9.32E-03 Cs-134

<1.11E-02 0.00E+00 1.11E-02 Cs-137

<1.24E-02 0.00E+00 1.24E-02 Be-7

<3.49E-02 0.00E+00 3.49E-02 K-40 3.37E-01 8.43E-02 1.79E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<8.83E-03 0.00E+00 8.83E-03 Cs-134

<1.06E-02 0.00E+00 1.06E-02 Cs-137

<1.62E-02 0.00E+00 1.62E-02 Be-7

<5.83E-02 0.00E+00 5.83E-02 K-40 4.28E-01 9.35E-02 5.51E-02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 35 of 80

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCilm3 Sample Point 258 [ CONTROL - W @ 9.84 miles )

Sample ID:

252077 Sample ID:

252694 Sample ID:

253080 Sample ID:

253888 Sample ID:

254210 Sample ID:

254745 Sample ID:

255306 Sample ID:

255834 Sample ID:

256068 Sample ID:

256336 Sample Dates: 2112/2013-2/1912013 Sample Dates: 2/1912013 - 2126/2013 Sample Dates: 2/2612013 -31512013 Sample Dates: 3/5/2013 -3/12/2013 Sample Dates: 3112/2013 -311912013 Sample Dates: 3119/2013 -3126/2013 Sample Dates: 3/26/2013 -41212013 Sample Dates: 412/2013 -4/912013 Sample Dates: 4/9/2013 -4/1612013 Sample Dates: 4/16/2013 -4/2312013 Nuclide Activity I Sigma Error 1-131

<9.46E-03 0.OOE+00 Cs-134

<2.78E-03 O.OOE+00 Cs-137

<1.10E-02 0.OOE+00 Be-7

<1.05E-01 0.OOE+00 K-40 3.09E-01 8.25E-02 LLD 9.46E-03 2.78E-03 1.10E-02 1.05E-01 5.96E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.02E-02 O.OOE+0 1.02E-02 Cs-134

<1.23E-02 O.OOE+00 1.23E-02 Cs-137

<1.09E-02 0.OOE+00 1.09E-02 Be-7

<6.51 E-02 O.OOE+00 6.51E-02 K-40

<4.29E-01 O.OOE+00 4.29E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.26E-02 0.OOE+00 1.26E-02 Cs-134

<7.45E-03 0.OOE+00 7.45E-03 Cs-137

<1.17E-02 0.OOE+O0 1.17E-02 Be-7

<8.87E-02 0.OOE+00 8.87E-02 K-40 4.66E-01 1.02E-01 1.79E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.69E-02 0.OOE+00 1.69E-02 Cs-134

<1.41E-02 O.OOE+00 1.41 E-02 Cs-137

<1.36E-02 0.OOE+00 1.36E-02 Be-7

<8.80E-02 O.OOE+0O 8.80E-02 K-40 4.68E-01 1.34E-01 1.73E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.92E-02 0.OOE+0O 1.92E-02 Cs-134

<1.43E-02 0.OOE+O0 1.43E-02 Cs-137

<1.69E-02 0.OOE+00 1.69E-02 Be-7

<1.10E-01 0.OOE+O0 1.10E-01 K-40

<5.18E-01 O.OOE+00 5.18E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.38E-02 0.OOE+00 1.38E-02 Cs-134

<1.22E-02 O.OOE+0O 1.22E-02 Cs-137

<1.09E-02 O.OOE+00 1.09E-02 Be-7

<6.42E-02 O.OOE+00 6.42E-02 K-40 3.35E-01 9.48E-02 1.33E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.34E-02 0.OOE+00 1.34E-02 Cs-134

<8.07E-03 0.OOE+00 8.07E-03 Cs-137

<1.35E-02 0.OOE+00 1.35E-02 Be-7

<7.16E-02 0.OOE+00 7.16E-02 K-40 4.36E-01 9.28E-02 1.OOE-01 Nuclide Activity I Sigma Error LLD 1-131

<2.37E-02 O.OOE+0O 2.37E-02 Cs-134

<1.16E-02 O.OOE+00 1.16E-02 Cs-137

<1.38E-02 O.OOE+00 1.38E-02 Be-7

<1.09E-01 0.OOE+00 1.09E-01 K-40

<4.90E-01 0.OOE+00 4.90E-01 Nuclide Activity I Sigma Error LLD 1-131

<8.80E-03 0.OOE+00 8.80E-03 Cs-134

<6.29E-03 0.OOE+00 6.29E-03 Cs-137

<7.70E-03 O.OOE+O0 7.70E-03 Be-7

<5.70E-02 O.OOE+00 5.70E-02 K-40 4.16E-01 6.75E-02 8.OOE-02 Nuclide Activity I Sigma Error LLD 1-131

<1.12E-02 O.OOE+00 1.12E-02 Cs-134

<8.89E-03 0.OOE+00 8.89E-03 Cs-137

<1.26E-02 0.OOE+00 1.26E-02 Be-7

<8.55E-02 0.OOE+O0 8.S5E-02 K-40 5.01E-01 9.75E-02 9.69E-02 00 0

S 6

0 0

00 0

0 S

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E

13339 Hagers Ferry Road Huntersville, North Carolina 28078 0

Appendix E - Page 36 of 80 0

S 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCi/m3 Sample Point 258 [ CONTROL - W @ 9.84 miles ]

Sample ID:

256603 00 Sample ID:

257126 0

0 S.

Sample ID:

257279 0

S O

Sample ID:

257726 0

0 O

Sample ID:

257970 0

0 0

0 Sample ID:

25922 0

Sample ID:

259570 0

0 O

Sample ID:

269022 00 0

Sample ID:

269570 0

0 0

Sample 10:

260204 0

0 0

Sample Dates: 412312013 -4/3012013 Sample Dates: 413012013-51712013 Sample Dates: 51712013 - 5/1412013 Sample Dates: 5114/2013 - 512112013 Sample Dates: 512112013 - 512912013 Sample Dates: 5/29/2013.61412013 Sample Dates: 6/4/2013 -6/11/2013 Sample Dates: 6/11/2013 -6118/2013 Sample Dates: 6/18/2013 -6/2512013 Sample Dates: 6/25/2013 - 1212013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.68E-02 0.00E+00 1.68E-02 Cs-134

<1.10E-02 O.00E+00 1.10E-02 Cs-137

<1.59E-02 0.OOE+00 1.59E-02 Be-7

<9.57E-02 0.00E+00 9.57E-02 K-40

<4.13E-01 O.OOE+00 4.13E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.91E-02 O.OOE+00 1.91E-02 Cs-134

<1.51E-02 0.00E+00 1.51E-02 Cs-137

<1.20E-02 O.OOE+00 1.20E-02 Be-7

<1.21E-01 0.00E+00 1.21E-01 K-40 3.78E-01 1.14E-01 1.70E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.08E-02 0.00E+00 1.08E-02 Cs-134

<1.25E-02 0.00E+00 1.25E-02 Cs-137

<8.19E-03 0.OOE+0O 8.19E-03 Be-7

<7.43E-02 O.OOE+00 7.43E-02 K-40 4.24E-01 9.23E-02 1.16E-01 Nuclide Activity I Sigma Error LLD 1-131

<9.74E-03 0.00E+00 9.74E-03 Cs-134

<9.36E-03 0.00E+00 9.36E-03 Cs-137

<1.05E-02 0.00E+00 1.05E-02 Be-7

<7.53E-02 0.00+E00 7.53E-02 K-40 3.45E-01 6.89E-02 1.47E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.28E-02 0.OOE+00 2.28E-02 Cs-134

<1.97E-02 0.00E+00 1.97E-02 Cs-137

<1.01E-02 o.OOE+O0 1.01E-02 Be-7

<1.32E-01 0.00E+00 1.32E-01 K-40 2.87E-01 1.20E-01 2.75E-01 Nuclide Activity 1 Sigma Error 1-131

<2.46E-02 0.00E+00 Cs-134

<2.62E-02 0.00E+00 Cs-137

<2.83E-02 O.OOE+00 Be-7

<1.93E-01 0.00E+00 K-40 5.34E-01 1.34E-01 LLD 2.46E-02 2.62E-02 2.83E-02 1.93E-01 2.52E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.53E-02 0.OOE+00 2.53E-02 Cs-134

<2.OOE-02 O.OOE+00 2.OOE-02 Cs-137

<2.59E-02 0.00E+00 2.59E-02 Be-7

<9.30E-02 0.OOE+00 9.30E-02 K-40

<5.74E-01 0.OOE+00 5.74E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.24E-02 0.00E+00 2.24E-02 Cs-134

<1.60E-02 0.00E+00 1.60E-02 Cs-137

<2.77E-02 0.00E+00 2.77E-02 Be-7

<1.86E-01 0.00E+00 1.86E-01 K-40

<5.13E-01 0.00E+00 5.13E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.08E-02 0.00E+00 1.08E-02 Cs-1 34

<8.96E-03 O.OOE+00 8.96E-03 Cs-137

<8.49E-03 O.OOE+00 8.49E-03 Be-7

<4.19E-02 0.00E+00 4.19E-02 K-40 3.13E-01 7.74E-02 1.28E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.38E-02 O.OOE+00 1.38E-02 Cs-134

<8.26E-03 0.00E+00 8.26E-03 Cs-137

<9.96E-03 0.00E+00 9.96E-03 Be-7

<8.82E-02 0.00E+00 8.82E-02 K-40 4.86E-01 8.09E-02 9.60E-02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EIn 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 37 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCI/m3 Sample Point 258 [ CONTROL - W @ 9.84 miles I Sample ID:

260664 Sample ID:

261627 Sample ID:

262129 Sample ID:

263145 Sample ID:

263372 Sample ID:

264030 Sample ID:

266161 Sample ID:

265470 Sample ID:

267156 Sample ID:

267606 Sample Dates: 7/2/2013 - 7/9)2013 Sample Dates: 71912013-711612013 Sample Dates: 7116/2013 -712312013 Sample Dates: 712312013 -7/3012013 Sample Dates: 7/30/2013 - 816/2013 Sample Dates: 8/612013 -811312013 Sample Dates: 8/13/2013 -812012013 Sample Dates: 8/20/2013 -812712013 Sample Dates: 8/27/2013 -9/412013 Sample Dates: 914/2013 -911012013 Nuclide ActMty 1 Sigma Error LLD 1-131

<2.01E-02 0.00E+00 2.01 E-02 Cs-134

<1.27E-02 0.00E+00 1.27E-02 Cs-137

<1.79E-02 0.00E+00 1.79E-02 Be-7

<1.80E-01 0.OOE+00 1.80E-01 K-40 3.73E-01 1.04E-01 2.74E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.35E-02 0.00E+00 1.35E-02 Cs-134

<1.10E-02 0.00E+00 1.10E-02 Cs-137

<1.29E-02 0.00E+00 1.29E-02 Be-7

<8.21E-02 0.00E+00 8.21 E-02 K-40 2.48E-01 9.01E-02 1.58E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.40E-02 0.00E+00 2.40E-02 Cs-134

<1.74E-02 0.00E+00 1.74E-02 Cs-137

<1.16E-02 0.00E+00

.116E-02 Be-7

<1.38E-01 0.OOE+00 1.38E-01 K-40 4.OOE-01 1.07E-01 3.29E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.72E-02 0.OOE+00 2.72E-02 Cs-134

<1.87E-02 0.00E+00 1.87E-02 Cs-137

<2.29E-02 0.00E+00 2.29E-02 Be-7

<1.48E-01 0.00E+00 1.48E-01 K-40

<5.37E-01 0.OOE+00 5.37E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.01E-02 0.OOE+00 2.01E-02 Cs-134

<2.17E-02 0.OOE+00 2.17E-02 Cs-1 37

<2.45E-02 0.00E+00 2.45E-02 Be-7

<1.15E-01 0.OOE+00 1.15E-01 K-40

<5.58E-01 0.OOE+00 5.58E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.24E-02 0.00E+00 2.24E-02 Cs-134

<9.70E-03 0.00E+00 9.70E-03 Cs-137

<1.99E-02 0.00E+00 1.99E-02 Be-7

<1.62E-01 0.00E+00 1.62E-01 K-40 5.10E-01 1.20E-01 2.04E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.37E-02 0.00E+00 2.37E-02 Cs-134

<1.24E-02 O.OOE+00 1.24E-02 Cs-137

<1.40E-02 0.00E+00 1.40E-02 Be-7

<1.75E-01 0.00E+00 1.75E-01 K-40 6.OOE-01 1.31E-01 7.73E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.11E-02 0.00E+00 1.11E-02 Cs-134

<9.95E-03 0.00E+00 9.95E-03 Cs-137

<1.08E-02 0.OOE+00 1.08E-02 Be-7

<9.20E-02 O.00E+00 9.20E-02 K-40

<4.34E-01 0.00E+00 4.34E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.26E-02 0.00E+00 2.26E-02 Cs-134

<1.55E-02 0.00E+00 1.55E-02 Cs-137

<1.48E-02 0.OOE+00 1.48E-02 Be-7

<1.48E-01 0.00E+00 1.48E-01 K-40 3.50E-01 9.37E-02 6.77E-02 Nuclide Activity I Sigma Error LLD 1-131

<2.08E-02 0.00E+00 2.08E-02 Cs-134

<1.78E-02 0.00E+00 1.78E-02 Cs-137

<1.96E-02 O.OOE+0O 1.96E-02 Be-7

<1.73E-01 0.00E+00 1.73E-01 K-40 4.31E-01 1.20E-01 2.51E-01 66 0

0 0

0 6

00 0

S 0

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E gjI 13339 Hagers Ferry Road Huntersville, North Carolina 28078 0

Appendix E - Page 38 of 80 0

0 00

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: AIR RADIOIODINE Concentration (Activity): pCI/m3 Sample Point 258 [ CONTROL - W @ 9.84 miles ]

O Sample ID:

268461 0

0 O

Sample ID:

269584 0

00 Sample ID:

270727 00 Sample 10:

271452 0

0 Sample ID:

272059 0

S Sample ID:

272442 00 Sample ID:

272843 0

0 S ample ID:

273935 0

Sample ID:

274382 0S Sample ID:

274896 0

Sample Dates: 9/1012013 - 9117/2013 Sample Dates: 9/17/2013 -9/24/2013 Sample Dates: 9/2412013 - 101112013 Sample Dates: 1011/2013.1018/2013 Sample Dates: 1018/2013 -1011512013 Sample Dates: 10/1512013.1012212013 Sample Dates: 10/2212013 - 1012912013 Sample Dates: 10/29/2013 -111512013 Sample Dates: 1115/2013 -11112/2013 Sample Dates: 1111212013 - 11/1912013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.12E-02 0.OOE+00 2.12E-02 Cs-134

<1.11E-02 0.00E+00 1.11E-02 Cs-137

<1.46E-02 O.OOE+00 1.46E-02 Be-7

<1.41E-01 0.00E+00 1.41E-01 K-40

<6.39E-01 0.OOE+00 6.39E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<2.05E-02 0.OOE+00 2.05E-02 Cs-134

<2.38E-02 0.OOE+00 2.38E-02 Cs-137

<1.70E-02 0.00E+00 1.70E-02 Be-7

<1.11E-01 O.OOE+00 1.11E-01 K-40 2.86E-01 1.15E-01 2.74E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.40E-02 0.001+00 2.40E-02 Cs-134

<2.08E-02 0.OOE+00 2.08E-02 Cs-137

<1.64E-02 0.00E+00 1.64E-02 Be-7

<1.55E-01 0.00E+00 1.55E-01 K-40 4.86E-01 1.18E-01 7.73E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.32E-02 O.00E+00 2.32E-02 Cs-134

<1.70E-02 0.0OE+00 1.70E-02 Cs-137

<2.04E-02 0.00E+00 2.04E-02 Be-7

<1.03E-01 0.00E+00 1.03E-01 K-40 5.71E-01 1.28E-01 2.16E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.52E-02 0.00E+00 2.52E-02 Cs-134

<1.53E-02 0.00E+00 1.53E-02 Cs-137

<2.47E-02 0.00E+00 2.47E-02 Be-7

<1.47E-01 O.OOE+00 1,47E-01 K-40 4.91E-01 1.40E-01 2.55E-01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.39E-02 0.00E+00 1.39E-02 Cs-134

<1.24E-02 0.00E+00 1.24E-02 Cs-137

<1.52E-02 0.OOE+00 1.52E-02 Be-7

<9.60E-02 0.00E+00 9.60E-02 K-40 3.19E-0i 1.01E-01 1.83E-01 Nuclide Activity 1 Sigma Error 1-131

<1.24E-02 0.00E+00 Cs-134

<9.51E-03 0.00E+00 Cs-137

<1.13E-02 0.00E+00 Be-7

<7.85E-02 0.00E+00 K-40 6.14E-01 8.95E-02 LLD 1.24E-02 9.51 E-03 1.13E-02 7.85E-02 3.53E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.07E-02 0.00E+00 2.07E-02 Cs-134

<1.98E-02 0.00E+00 1.98E-02 Cs-137

<1.56E-02 0.00E+00 1.56E-02 Be-7

<9.1OE-02 O.00E+00 9.10E-02 K-40 4.57E-01 1.14E-01 7.72E-02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.85E-02 0.00E+00 1.85E-02 Cs-134

<1.98E-02 0.OOE+00 1.98E-02 Cs-137

<1.45E-02 O.OOE+00 1.45E-02 Be-7

<1.30E-01 0.00E+00 1.30E-01 K-40 3.10E-01 1.32E-01 2.14E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.06E-02 0.00E+00 2.06E-02 Cs-134

<1.34E-02 0.OOE+00 1.34E-02 Cs-137

<1.34E-02 0.00E+00 1.34E-02 Be-7

<1.215-01 0.OOE+00 1.21E-01 K-40

<5.46E-01 0.00E+00 5.46E-01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 39 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: AIR RADIOIODINE Concentration (Activity): pCIlm3 Sample Point 258 [ CONTROL - W @ 9.84 miles ]

Sample ID:

276460 Sample ID:

278765 Sample ID:

278836 Sample ID:

279076 Sample ID:

279704 Sample ID:

280193 Sample Dates: 1111912013-1112512013 Sample Dates: 11126/2013 - 12/312013 Sample Dates: 12/312013 - 12110/2013 Sample Dates: 12)1012013 -1211712013 Sample Dates: 1211712013.1212312013 Sample Dates: 1212312013.12131/2013 Nuclide Activity I Sigma Error LLD 1-131

<1.49E-02 0.00E+00 1.49E-02 Cs-134

<1.32E-02 0.00E+00 1.32E-02 Cs-137

<1.64E-02 0.OOE+00 1.64E-02 Be-7

<9.34E-02 0.00E+00 9.34E-02 K-40 6.54E-01 9.86E-02 1.06E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.16E-02 0.00E+00 1.16E-02 Cs-134

<7.62E-03 0.00E+00 7.62E-03 Cs-137

<1.08E-02 0.00E+00 1.08E-02 Be-7

<6.74E-02 0.00E+00 6.74E-02 K-40 6,14E-01 9.60E-02 8.72E-02 Nuclide Activity I Sigma Error LLD 1-131

<1.90E-02 0.00E+00 1.90E-02 Cs-134

<9.71E-03 0.00E+00 9.71 E-03 Cs-137

<2.48E-02 0.00E+00 2.48E-02 Be-7

<1.22E-01 0.00E+00 1.22E-01 K-40 3.21E-01 1.20E-01 2.13E-01 Nuclide Activity I Sigma Error LLD 1-131

<1.39E-02 0.00E+00 1.39E-02 Cs-134

<1.07E-02 0.00E+00 1.07E-02 Cs-137

<3.18E-03 0.00E+00 3.18E-03 Be-7

<1.09E-01 0.00E+00 1.09E-01 K-40

<4.35E-01 0.00E+00 4.35E-01 Nuclide Activity I Sigma Error LLD 1-131

<2.63E-02 0.00E+00 2.63E-02 Cs-134

<1.98E-02 O.OOE+00 1.98E-02 Cs-137

<1.96E-02 0.00E+00 1.96E-02 Be-7

<2.49E-01 0.OOE+00 2.49E-01 K-40

<6.21E-01 0.OOE+00 6.21E-01 Nuclide Activity i Sigma Error LLD 1-131

<1.20E-02 0.00E+00 1.20E-02 Cs-134

<9.868E-03 0.00E+00 9.88E-03 Cs-137

<9.83E-03 0.00E+00 9.83E-03 Be-7

<6.51E-02 0.00E+00 6.51 E-02 K-40

<3.56E-01 0.00E+00 3.56E-01 06 6

0 0

0 6

S 6

0 0

0 S

0 0

0 Media Type: CROPS Concentration (Activity): pCilkg Sample Point 260 [ INDICATOR - SSE @ 2 miles ]

Sample ID:

250201 Sample ID:

251131 Sample ID:

266665 Sample ID:

268104 Sample Dates: 11212013 - 11212013 Sample Dates: 21S/2013 - 2/512013 Sample Dates: 5/7/2013-5/712013 Sample Dates: 614/2013 -6/412013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.73E+01 0.00E+00 1.73E+01 Cs-134

<1.96E+01 0.00E+00 1.96E+01 Cs-137

<2.28E+01 0.00E+00 2.28E+01 Be-7 3.84E+02 1.06E+02 2.16E+02 K-40 2.49E+03 2.76E+02 3.16E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.86E+01 0.00E+00 1.86E+01 Cs-134

<1.69E+01 0.00E+00 1.69E+01 Cs-137

<1.51E+01 0.00E+00 1.51E+01 Be-7 4.34E+02 7.69E+01 1.21E+02 K-40 4.22E+03 2.65E+02 1.64E+02 Nuclide Activity I Sigma Error LLD 1-131

<1.54E+01 0.00E+00 1.54E+01 Cs-134

<1.92E+01 0.00E+00 1.92E+01 Cs-137

<2.27E+01 0.00E+00 2.27E+01 Be-7 2.75E+02 7.80E+01 1.73E+02 K-40 3.83E+03 2.89E+02 2.53E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.34E+01 0.00E+00 1.34E+01 Cs-134

<1.58E+01 0.00E+00 1.58E+01 Cs-137

<1.37E+01 0.00E+00 1.37E+01 Be-7

<1.33E+02 0.00E+00 1.33E+02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 S

Appendix 2 - Page 40 of 80 0

S S

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: CROPS Concentration (Activity): pCilkg Sample Point 260 [ INDICATOR - SSE @ 2 miles ]

0 0

0 S

0 0

S 0

0 0

S 0

Sample ID:

258104 Sample ID:

260172 Sample ID:

263217 Sample Dates: 614/2013 - 61412013 Sample Dates: 71212013 - 71212013 Sample Dates: 81612013 -81612013 Nuclide Activity K-40 2.69E+03 Sample ID:

266737 Sample ID:

270658 Sample ID:

272877 Sample 10:

276931 Sample Dates: 914/2013 - 91412013 Sample Dates: 1011/2013 -101112013 Sample Dates: 111512013 -111512013 Sample Dates: 121312013 -1213/2013 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-1 34 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-I 34 Cs-137 Be-7 K-40 Activity

<8.47E+00

<1.07E+01

<1.17E+01

<9.74E+01 2.21E+03 Activity

<1.44E+01

<1.12E+01

<1.75E+01

<1.10E+02 1.93E+03 Activity

<1.36E+01

<1.42E+01

<1.15E+01

<1.20E+02 3.06E+03 Activity

<9.90E+00

<8.50E+00

<9.47E+00 1.13E+02 2.09E+03 Activity

<1.88E+01

<1.61E+01

<2.22E+01 1.51E+02 3.63E+03 Activity

<2.76E+01

<2.46E+01

<3.28E+01 4.78E+02 4.14E+03 1 Sigma Error 1.96E+02 I Sigma Error 0.OOE+00 0.00E+00 O.00E+00 O.OOE+00 1.36E+02 1 Sigma Error O.OOE+00 0.00E+00 0.OOE+00 O.OOE+00 1.94E+02 I Sigma Error 0.OOE+00 0.OOE+00 O.OOE+00 0.OOE+00 1.72E+02 I Sigma Error O.OOE+00 0.00E+00 0.OOE+O0 2.97E+01 1.14E+02 1 Sigma Error 0.OOE+0O 0.OOE+00 0.OOE+00 7.12E+01 3.18E+02 1 Sigma Error 0.OOE+00 0.00E÷00 0.OOE+00 1.34E+02 3.36E+02 LLD 1.55E+02 LLD 8.47E+00 1.07E+01 1.17E+01 9.74E+01 9.85E+01 LLD 1.44E+01 1.12E+01 1.75E+01 1.10E+02 1.93E+02 LLD 1.36E+01 1.42E+01 1.15E+01 1.20E+02 1.74E+02 LLD 9.90E+00 8.50E+00 9.47E+00 6.16E+O1 7.95E+01 LLD 1.88E+O1 1.61E+01 2.22E+01 1.38E+02 3.42E+02 LLD 2.76E+01 2.46E+01 3.28E+01 2.18E+02 3.19E+02 Media Type: DRINKING WATER Concentration (Activity): pCill Sample Point 214 [(INDICATOR - SSE @ 7.3 miles ]

Sample ID:

250617 Sample ID:

251674 Sample Dates: 1211112012 -11812013 Sample Dates: 118/2013. 2/512013 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-1 34 Cs-137 BaLa-140 Be-7 K-40 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Activity 1.9gE+00

<3.41 E+00

<3.49E+00

<7.67E+00

<3.62E+00

<8.66E+00

<7.27E+00

<4.77E+00

<1.23E+01

<3.53E+00

<4,47E+00

<7.83E+00

<3.49E+01

<4.95E+O1 Activity 1.68E+00

<3.73E+00

<6.54E+00

<1.40E+01

<7.OOE+00

<1.05E+01 1 Sigma Error 4.15E-01 O.OOE+00 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 O.OOE+00 0.00E+O0 0.OOE+00 0.OOE+00 0.00E+00 0.OOE+00 0.OOE+00 0.00E+00 i Sigma Error 3.92E-01 0.OOE+00 0.OOE+00 O.OOE+O0 0.OOE+00 0.OOE+00 LLD 1.27E+00 3.41E+00 3.49E+00 7.67E+00 3.62E+00 8.66E+00 7.27E+00 4.77E+00 I1.23E+01 3.53E+00 4,47E+00 7.83E+00 3.49E+01 4,95E+01 LLD 1.20E+00 3.73E+00 6.54E+00 1.40E+01 7.OOE+00 1.05E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E* fl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 41 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCi/I Sample Point 214 [ INDICATOR - SSE @ 7.3 miles I Sample ID:

251674 Sample ID:

253084 Sample ID:

253945 Sample ID:

255945 Sample ID:

257197 Sample ID: " 268173 Sample ID:

258325 Sample Dates: 1V812013-2/512013 Sample Dates: 12/1112012 - 31512013 Sample Dates: 2/5/2013. 31512013 Sample Dates: 315/2013-412/2013 Sample Dates: 4/2/2013-4/30/2013 Sample Dates: 3/5/2013.5/29/2013 Sample Dates: 4/30/2013 - 612912013 Nuclide Activity I Sigma Error Zr-95

<1.02E+01 0.00E+00 Nb-95

<6.62E+00 O.00E+00 1-131

<1.43E+01 0.00E+00 Cs-134

<5.40E+00 0.00E+00 Cs-137

<6.08E+00 0.00E+00 BaLa-140

<8.71E+00 0.OOE+00 Be-7

<4.20E+01 0.00E+00 K-40 6.60E+01 2.10E+01 Nuclide Activity I Sigma Error H3DW 8.90E+02 6.41 E+01 Nuclide Activity 1 Sigma Error Beta 8.88E-01 4.50E-01 Mn-54

<4.29E+00 0.00E+00 Co-58

<4.34E+00 0.00E+00 Fe-59

<1.03E+01 0.00E+00 Co-60

<5.28E+00 0.00E+00 Zn-65

<7.78E+00 0.002E+0 Zr-95

<8.56E+00 0.00E+00 Nb-95

<5.09E+00 0.001+00 1-131

<1.34E+01 0.OOE+00 Cs-134

<3.11E+00 0.00E+00 Cs-137

<4.21E+00 0.00E+00 BaLa-140

<6.05E+00 0.00E+00 Be-7

<3.49E+01 0.00E+00 K-40 7.74E+01 2.53E+01 Nuclide Activity 1 Sigma Error Beta 1.38E+00 4.07E-01 Mn-54

<2.44E+00 0.00E+00 Co-58

<6.22E+00 0.00E+00 Fe-59

<1.14E+01 0.00E+00 Co-60

<7.08E+00 0.00E+00 Zn-65

<1.15E+01 0.00E+00 Zr-95

<9.07E+00 0.00E+00 Nb-95

<5.80E+00 0.00E+00 1-131

<1.43E+01 0.00E+00 Cs-134

<3.87E+00 0.00E+00 Cs-137

<4.74E+00 0.00E+00 BaLa-140

<1.41E+01 0.00E+00 Be-7

<3.86E+01 0.00E+00 K-40 5.92E+01 1.74E+01 Nuclide Activity I Sigma Error Beta 2.03E+00 4.25E-01 Mn-54

<3.88E+00 0.00E+00 Co-58

<4.78E+00 0.00E+00 Fe-59

<9.39E+00 0.00E+00 Co-60

<4.62E+00 O.00E+00 Zn-65

<1.11E+01 O.00E+00 Zr-95

<6.57E+00 0.00E+00 Nb-95

<4.35E+00 0.00E+00 1-131

<1.17E+01 O.00E+00 Cs-134

<3.72E+00 0.00E+00 Cs-137

<4.08E+00 0.00E+00 BaLa-140

<1.04E+01 0.00E+00 Be-7

<3.19E+01 O.00E+00 K-40

<7.38E+01 0.00E+00 Nuclide Activity 1 Sigma Error H3DW 5.69E+02 6.31 E+01 Nuclide Activity I Sigma Error Beta 1.15E+00 4.45E-01 Mn-54

<3.78E+00 0.00E+00 Co-58

<4.38E+00 0.00E+00 Fe-59

<8.09E+00 0.00E+00 Co-60

<4.67E+00 0.00E+00 Zn-65

<7.83E+00 0.00E+00 LLD 1.02E+01 6.62E+00 1.43E+01 5.40E+00 6.08E+00 8.71E+00 4.20E+01 4.77E+01 LLD 1.63E+02 LLD 1.48E+00 4.29E+00 4.34E+00 1.03E+01 5.28E+00 7.78E+00 8.56E+00 5.09E+00 1.34E+01 3.11E+00 4.21E+00 6.05E+00 3.49E+01 4.85E+01 LLD 1.29E+00 2.44E+00 6.22E+00 1.14E+01 7.08E+00 1.15E+01 9.07E+00 5.80E+00 1.43E+01 3.87E+00 4.74E+00 1.41E+01 3.86E+01 4.67E+01 LLD 1.30E+00 3.88E+00 4.78E+00 9.39E+00 4.62E+00 1.11E+01 6.57E+00 4.35E+00 1.17E+01 3.72E+00 4.08E+00 1.04E+01 3.19E+01 7.38E+01 LLD 1.77E+02 LLD 1.43E+00 3.78E+00 4.38E+00 8.09E+00 4.67E+00 7.83E+00 I

6 6

0 S

S 0

0 0

S 0

0 0

0 Apeni E-ae 2 of8 0

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EU I7* 13339 Hagers Ferry Road Huntersville, North Carolina 28078

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCIll Sample Point 214 [ INDICATOR - SSE @ 7.3 miles ]

Sample ID:

258325 S

Sample ID:

260429 0

0 0

S Sample ID:

263225 0

0 S

S Sample ID:

266736 S

S 0

0 S

Sample ID:

267117 0S Sample ID:

269856 0

S 0

0 Sample Dates: 4/3012013 -512912013 Sample Dates: 512912013 - 612512013 Sample Dates: 612612013 -712312013 Sample Dates: 712312013 -812012013 Sample Dates: 512912013 -812012013 Sample Dates: 812012013 -911712013 Nuclide Activity Zr-95

<9.07E+00 Nb-95

<5.06E+00 1-131

<1.42E+01 Cs-134

<3.66E+00 Cs-137

<5.05E+00 BaLa-140

<9.08E+00 Be-7

<4.01E+01 K-40 1.85E+02 Nuclide Activity Beta 1.46E+00 Mn-54

<4.26E+00 Co-58

<4.28E+00 Fe-59

<9.17E+00 Co-60

<5.16E+00 Zn-65

<9.46E+00 Zr-95

<7.16E+00 Nb-95

<5.84E+00 1-131

<1.31E+01 Cs-134

<3.88E+00 Cs-137

<5.27E+00 BaLa-140

<1.35E+01 Be-7

<3.49E+01 K-40 i.99E+02 Nuclide Activity Beta 2.13E+00 Mn-54

<3.44E+00 Co-58

<3.54E+00 Fe-59

<5.83E+00 Co-60

<2.68E+00 Zn-65

<7.38E+00 Zr-95

<7.24E+00 Nb-95

<4.40E+00 1-131

<1.11E+01 Cs-134

<3.41E+00 Cs-137

<3.69E+00 BaLa-140

<6.80E+00 Be-7

<3.04E+01 K-40 7.73E+01 Nuclide Activity Beta 2.56E+00 Mn-54

<3.46E+00 Co-58

<4.43E+00 Fe-59

<8.92E+00 Co-60

<4.62E+00 Zn-65

<6.44E+00 Zr-95

<8.69E+00 Nb-95

<4.22E+00 1-131

<1.37E+01 Cs-134

<3.25E+00 Cs-137

<4.40E+00 BaLa-140

<8.55E+00 Be-7

<3.14E+01 K-40 1.672+02 Nuclide Activity H3DW 2.33E+02 Nuclide Activity Beta 1.53E+00 Mn-54

<3.56E+00 Co-58

<3.98E+00 Fe-59

<8.18E+00 Co-60

<4.78E+00 Zn-65

<8.87E+00 Zr-95

<7.37E+00 Nb-95

<3.94E+00 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.OOE+00 2.77E+01 I Sigma Error 3.89E-01 0.001+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.57E+01 1 Sigma Error 4.05E-01 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00+E00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.33E+01 I Sigma Error 4.21E-01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.59E+01 LLD 9.07E+00 5.06E+00 1.42E+01 3.66E+00 5.05E+00 9.08E+00 4.01E+01 2.75E+01 LLD 1.22E+00 4.26E+00 4.28E+00 9.17E+00 5.16E+00 9.46E+00 7.16E+00 5.84E+00 1.31E+01 3.88E+00 5.27E+00 1.35E+01 3.49E+01 3.89E+01 LLD 1.21E+00 3.44E+00 3.54E+00 5.83E+00 2.68E+00 7.38E+00 7.24E+00 4.40E+00 1.11E+01 3.41E+00 3.69E+00 6.80E+00 3.04E+01 2.02E+01 LLD 1.24E+00 3.46E+00 4.43E+00 8.92E+00 4.62E+00 6.44E+00 8.69E+00 4.22E+00 1.37E+01 3.25E+00 4.40E+00 8.55E+00 3.14E+01 3.10E+01 I Sigma Error LLD 5.22E+01 1.58E+02 1 Sigma Error 4.12E-01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 1.28E+00 3.56E+00 3.98E+00 8.18E+00 4.78E+00 8.87E+00 7.37E+00 3.94E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En j* i 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 43 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCili Sample Point 214 [ INDICATOR - SSE @ 7.3 miles ]

Sample ID:

269856 Sample ID:

272545 Sample ID:

274975 Sample ID:

277099 Sample ID:

279122 Sample Dates: 812012013 - 911712013 Sample Dates: 911712013.1011512013 Sample Dates: 10/15/2013 - 11/12/2013 Sample Dates: 812012013-12110/2013 Sample Dates: 11/12/2013-1211012013 Nuclide Activity 1 Sigma Error 1-131

<1.44E+01 0.00E+00 Cs-134

<3.51E+00 0.00E+00 Cs-137

<4.01E+00 0.00E+00 BaLa-140

<8.73E+00 0.OOE+00 Be-7

<3.75E+01 0.00E+00 K-40 2.04E+02 2.53E+01 Nuclide Activity I Sigma Error Beta 3.03E+00 4.41E-01 Mn-54

<4.90E+00 0.OOE+00 Co-58

<4.65E+00 O.OOE+O0 Fe-59

<7.19E+00 0.00E+00 Co-60

<4.63E+00 0.OOE+00 Zn-65

<8.17E+00 0.OOE+00 Zr-95

<6.32E+00 0.OOE+00 Nb-95

<4.91E+00 0.00E+00 1-131

<1.20E+01 0.00E+00 Cs-134

<3.72E+00 0.OOE+00 Cs-137

<4.06E+00 0.OOE+0O BaLa-140

<1.10E+01 0.OOE+O0 Be-7

<3.61E+01 O.00E+00 K-40

<6.82E+01 0.00E+00 Nuclide Activity 1 Sigma Error Beta 1.64E+00 4.10E-01 Mn-54

<4.63E+00 0.00E+00 Co-58

<4.34E+00 0.OOE+00 Fe-59

<6.84E+00 0.OOE+00 0o-60

<3.66E+00 0.00E+00 Zn-65

<9.34E+00 0.00E+00 Zr-95

<8.28E+00 0.00E+00 Nb-95

<5.62E+00 0.00+E00 1-131

<1.40E+01 0.00E+00 Cs-134

<4.41E+00 0,O0E+00 Cs-137

<3.62E+00 0.OOE+00 BaLa-140

<1.39E+01 0.00E+00 Be-7

<3.68E+01 0.00E+00 K-40 8.85E+01 2.07E+01 Nuclide Activity I Sigma Error H3DW 7.94E+02 8.41E+01 Nuclide Activity 1 Sigma Error Beta 1.84E+00 4.09E-01 Mn-54

<3.82E+00 0.00E+00 Co-58

<3.88E+00 0.00E+00 Fe-59

<1.01E+01 O.OOE+00 Co-60

<3.70E+00 0.00E+00 Zn-65

<7.45E+00 0.00E+00 Zr-95

<6.78E+00 0.00E+00 Nb-95

<4.91E+00 0.00E+00 1-131

<1.42E+01 O.OOE+00 Cs-134

<4.02E+00 0.00E+00 Cs-137

<3.36E+00 0.00E+00 BaLa-140

<1.00E+01 0.00E+00 Be-7

<3.64E+01 0.00E+00 K-40 1.98E+02 2.52E+01 S

LLD 1.44E+01 5

3.51E+00 4.01E+00 8.73E+00 3.75E+01 4.24E+01 5

LLD 1.28E+00 4.90E+00 4.65E+00 7.19E+00 4.63E+00 8.17E+00 6.32E+00 4.91E+00 1.202+01 0

3.72E+00 4.06E+00 0

1.10E+01 3.61E+01 S

6.82E+01 LLD 1.27E+00 5

4.63E+00 4.34E+00 6.84E+00 3.66E+00 9.34E+00 8.28E+00 5.62E+00 1.40E+01 4.41E+00 3.62E+00 1.39E+01 3.68E+01 4.44E+01 LLD 2.42E+02 0

LLD 1.25E+00 3.82E+00 3.88E+00 1.01E+01 3.70E+00 5

7.45E+00 6.78E+00 4.91E+00 1.42E+01 0

4.02E+00 3.36E+00 0

1.00E+01 3.64E+01 0

3.91E+01 Sample Point 218 [ CONTROL - NNE @ 13.5 miles ]

Sample ID:

260618 Sample Dates: 12/11/2012.1/8/2013 Nuclide Activity 1 Sigma Error LLD Beta 2.30E+00 4.18E-01 1.25E+00 Mn-54

<4.27E+00 O.00E+00 4.27E+00 Co-58

<5.07E+00 0.00E+00 5.07E+00 Fe-59

<8.32E+00 0.00E+00 8.32E+00 Co-60

<5.74E+00 0.00E+00 5.74E+00 Zn-65

<8.12E+00 0.00E+00 8.12E+00 Zr-95

<7.86E+00 0.00E+00 7.86E+00 Nb-95

<5.77E+00 0.00E+00 5.77E+00 1-131

<1.44E+01 0.00E+00 1.44E+01 S

0 0a Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ED 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 44 of 80 5

S 0

0 0

0 S

0 0

S 0

0 S

0 0

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCi/i Sample Point 218 [ CONTROL - NNE @ 13.5 miles ]

Sample ID:

250618 Sample ID:

251669 Sample ID:

253085 Sample ID:

253940 Sample ID:

265939 Sample ID:

257192 Sample Dates: 1211112012-11812013 Sample Dates: 11812013 -2/512013 Sample Dates: 1211112012-31512013 Sample Dates: 21512013 -31512013 Sample Dates: 316/2013 -4/212013 Sample Dates: 4/2/2013 -413012013 Nuclide Cs-t34 Cs-137 BaLa-140 Be-7 K-40 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-1 34 Cs-137 BaaLa-140 Be-7 K-40 Activity

<2.95E+00

<4.91E+00

<1.17E+01

<3.81E+01

<8.59E+01 Activity 2.24E+00

<3.57E+00

<3.28E+00

<8.94E+00

<4.72E+00

<6.90E+00

<6.70E+00

<4.67E+00

<1.15E+01

<2.97E+00

<3.67E+00

<7.55E+00

<3.21E+01 8.94E+01 I Sigma Error 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 1 Sigma Error 4.03E-01 0.00E+00 0.00E+00 O.OOE+00 O.00E+00 0.00E+00 0.OOE+00 O.00E+00 0.00E+00 O.00E+00 0.OOE+00 0.00E+00 0.00E+00 1.60E+01 LLD 2.95E+00 4.91E+00 1.17E+01 3.81E+01 8.59E+01 LLD 1.19E+00 3.57E+00 3.28E+00 8.94E+00 4.72E+00 6.90E+00 6.70E+00 4.67E+00 1.15E+01 2.97E+00 3.67E+00 7.55E+00 3.21E+01 3.50E+01 Nuclide Activity H3DW 6.72E+02 1 Sigma Error LLD 6.14E+01 1.65E+02 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 Activity 1.46E+00

<4.79E+00

<4.60E+00

<1.09E+01

<9.66E+00

<1.06E+01

<1.09E+01

<7.05E+00

<1.42E+01

<4.86E+00

<4.91E+00

<1.13E+01

<4.95E+01

<8.20E+01 Activity 1.94E+00

<3.09E+00

<4.16E+00

<7.67E+00

<4.69E+00

<5.24E+00

<6.48E+00

<4.77E+00

<1.23E+01

<3.37E+00

<3.58E+00

<7.71E+00

<3.11E+01 4.93E+01 Activity 1.41E+00

<3.30E+00

<4.83E+00

<1.07E+01

<6.02E+00

<6.61E+00

<7.74E+00

<5.41E+00

<9.89E+00

<3.69E+00

<4.48E+00 I Sigma Error 4,62E-01 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1 Sigma Error 4.17E-01 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.05E+01 1 Sigma Error 4.08E-01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 1.48E+00 4.79E+00 4.60E+00 1.09E+01 9.66E+00 1.06E+01 1.09E+01 7.05E+00 1.42E+01 4.86E+00 4.91E+00 1.13E+01 4.95E+01 8.20E+01 LLD 1.27E+00 3.09E+00 4.16E+00 7.67E+00 4.69E+00 5.24E+00 6.48E+00 4.77E+00 1.23E+01 3.37E+00 3.58E+00 7.71E+00 3.11E+01 3.74E+01 LLD 1.28E+00 3.30E+00 4.83E+00 1.07E+01 6.02E+00 6.61 E+00 7.74E+00 5.41E+00 9.89E+00 3.69E+00 4.48E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 45 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCiI Sample Point 218 [ CONTROL - NNE @ 13.5 miles ]

Sample ID:

257192 Sample ID:

258172 Sample ID:

258320 Sample ID:

260423 Sample ID:

263220 Sample ID:

266731 Sample Dates: 4/212013 -4/3012013 Sample Dates: 315/2013 -5/2912013 Sample Dates: 4/3012013. 512912013 Sample Dates: 612912013 - 612512013 Sample Dates: 6/2512013 -712312013 Sample Dates: 7/23/2013 - 8/20/2013 Nuclide Activity 1 Sigma Error BaLa-140

<1.32E+O1 0.00E+00 Be-7

<3.18E+01 0.00E+00 K-40 6.86E+01 1.76E+01 Nuclide Activity I Sigma Error H3DW 6.56E+02 6.45E+01 Nuclide Activity I Sigma Error Beta 7.31E-01 4.34E-01 Mn-54

<3.86E+00 0.00E+00 Co-58

<4.37E+00 O.OOE+00 Fe-59

<1.15E+01 0.OOE+00 CO-60

<4.81E+00 0.00E+00 Zn-65

<9.04E+00 0.OOE+00 Zr-95

<7.39E+00 0.00E+00 Nb-95

<5.36E+00 0.00E+00 1-131

<1.38E+01 0.00E+00 Cs-134

<3.74E+00 0.00E+00 Cs-137

<4.12E+00 0.00E+00 BaLa-140

<1.16E+01 0.00E+00 Be-7

<3.63E+01 0.00E+00 K-40

<7.99E+01 0.00E+00 Nuclide Activity 1 Sigma Error Beta 1.24E+00 3.83E-01 Mn-54

<3.07E+00 0.00E+00 Co-58

<4.12E+00 0.00E+00 Fe-59

<8.71E+00 0.00E+00 Co-60

<3.15E+00 0.00E+00 Zn-65

<8.09E+00 0.00E+00 Zr-95

<7.18E+00 0.00E+00 Nb-95

<5.22E+00 0.00E+00 1-131

<1.27E+01 0.00E+00 Cs-134

<3.44E+00 0.00E+00 Cs-137

<4.24E+00 0.OOE+00 BaLa-140

<8.38E+00 0.00E+00 Be-7

<3.40E+01 0.00E+00 K-40 1.81E+02 2.49E+01 Nuclide Activity 1 Sigma Error Beta 1.84E+00 3.98E-01 Mn-54

<3.65E+00 0.OOE+00 C0-58

<3.60E+00 0.00E+00 Fe-59

<8.70E+00 0.00E+00 Co-60

<3.70E+00 0.00E+00 Zn-65

<7.41E+00 0.00E+00 Zr-95

<5.33E+00 0.00E+00 Nb-95

<4.OOE+00 0.00E+00 1-131

<1.20E+01 0.00E+00 Cs-134

<3.18E+00 0.00E+00 Cs-137

<4.48E+00 0.00E+00 BaLa-140

<1.15E+01 0.00E+00 Be-7

<3.14E+01 0.00E+00 K-40 1.67E+02 2.18E+01 Nuclide Activity I Sigma Error Beta 1.46E+00 3.95E-01 Mn-54

<3.48E+00 0.00E+00 Co-58

<4.39E+00 0.00E+00 Fe-59

<7.52E+00 0.00E+00 Co-60

<5.73E+00 0.00E+00 Zn-65

<1.03E+01 0.00E+00 Zr-95

<8.79E+00 0.00E+00 Nb-95

<5.46E+00 0.00E+00 1-131

<1.36E+01 0.00E+00 Cs-134

<3.17E+00 0.00E+00 Cs-137

<4.30E+00 0.OOE+00 BaLa-140

<1.36E+01 0.00E+00 Be-7

<3.84E+01 0.00E+00 LLD 1,32E+01 3.18E+01 3,67E+01 LLD 1.77E+02 LLD 1.42E+00 3.86E+00 4.37E+00 1.15E+01 4.81E+00 9.04E+00 7.39E+00 5.36E+00 1,38E+01 3.74E+00 4.12E+00 1.16E+01 3.63E+01 7.99E+01 LLD 1.21E+00 3.07E+00 4.12E+00 8.71E+00 3.15E+00 8.09E+00 7.18E+00 5.22E+00 1.27E+01 3.44E+00 4.24E+00 8.38E+00 3.40E+01 3.82E+01 LLD 1.21E+00 3.65E+00 3.60E+00 8.70E+00 3.70E+00 7.41E+00 5.33E+00 4.00E+00 1.20E+01 3.18E+00 4.48E+00 1.15E+01 3.14E+01 3.40E+01 LLD 1.23E+00 3.48E+00 4.39E+00 7.52E+00 5.73E+00 1.03E+01 8.79E+00 5.46E+00 1.36E+01 3.17E+00 4.30E+00 1.36E+01 3.84E+01 06 0

0 0

0 S

0 0

0S S

S Appendix E - Page 46 of 80 0

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCi/I S*Sample Point 218 [ CONTROL - NNE Q 13.5 miles ]

00 0

0 0

0 S

0 0

0 S

0 0

S 0

0 S

S 0

0 0

0 Sample ID:

266731 Sample ID:

267116 Sample ID:

269850 Sample ID:

272546 Sample ID:

274970 Sample ID:

277098 Sample ID:

279116 Sample Dates: 712312013 -812012013 Sample Dates: 512912013 -812012013 Sample Dates: 812012013 - 911712013 Sample Dates: 9/1712013 - 10/15t2013 Sample Dates: 10/1512013 -1111212013 Sample Dates: 812012013-1211012013 Sample Dates: 1111212013 - 1211012013 Nuclide Activity K-40 8.62E+01 Nuclide Activity H3DW

<1.13E+02 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-1 34 Cs-137 BaLa-140 Be-7 K-40 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-1 34 Cs-137 BaLa-140 Be-7 K-40 Activity 1.08E+00

<3.36E+00

<4.79E+00

<1.03E+01

<6.67E+00

<7.70E+00

<7.81E+00

<5.37E+00

<1.24E+01

<3.54E+00

<3.72E+00

<3.99E+00

<3.34E+01 5.98E+01 Activity 1.63E+00

<4.02E+00

<3.53E+00

<7.49E+00

<3.84E+00

<7.32E+00

<7.62E+00

<4.58E+00

<1.42E+01

<3.30E+00

<3.72E+00

<6.74E+00

<4.04E+01 1.87E+02 Activity 1.64E+00

<3.30E+00

<4.08E+00

<8.35E+00

<3.60E+00

<8.49E+00

<7.21E+00

<6.31E+00

<1.36E+01

<3.68E+00

<3.77E+00

<1.09E+01

<3.31E+01 1.71E+02 I Sigma Error 2.19E+01 I Sigma Error 0.OOE+00 I Sigma Error 4.OOE-01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 2.40E+01 I Sigma Error 4.09E-01 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 0.00E+00 O.00E+00 0.00E+00 0.OOE+00 2.03E+01 1 Sigma Error 4.04E-01 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 0.00E+00 0.00E+00 O.OOE+00 O.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 2.98E+01 LLD 5.86E+01 LLD 1.56E+02 LLD 1.28E+00 3.36E+00 4.79E+00 1.03E+01 6.67E+00 7.70E+00 7.81E+00 5.37E+00 1.24E+01 3.54E+00 3.72E+00 3.99E+00 3.34E+01 5.28E+01 LLD 1.27E+00 4.02E+00 3.53E+00 7.49E+00 3.84E+00 7.32E+00 7.62E+00 4.58E+00 1.42E+01 3.30E+00 3.72E+00 6.74E+00 4.04E+01 3.67E+01 LLD 1.25E+00 3.30E+00 4.08E+00 8.35E+00 3.60E+00 8.49E+00 7.21E+00 6.31E+00 1.36E+01 3.68E+00 3.77E+00 1.09E+01 3.31E+01 2.87E+01 Nuclide Activity H3DW

<-6.1E+01 Nuclide Activity I Sigma Error LLD 0.00E+00 2.42E+02 Beta Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7

1. 73E +00

<2.50E+00

<3.82E+00

<8.73E+00

<3.99E+00

<6.48E+00

<8.13E+00

<5.79E+00

<1.38E+01

<2.98E+00

<3.15E+00

<1.05E+01

<3.58E+01 I Sigma Error 4.05E-01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 1.25E+00 2.50E+00 3.82E+00 8.73E+00 3.99E+00 6.48E+00 8.13E+00 5.79E+00 1.38E+01 2.98E+00 3.15E+00 1.05E+01 3.58E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En1

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 47 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: DRINKING WATER Concentration (Activity): pCI/i Sample Point 218 [ CONTROL - NNE @ 13.5 miles ]

Sample ID:

279116 Sample Dates: 1111212013.12)1012013 Nuclide Activity 1 Sigma Error LLD K-40 5.82E+01 1.49E+01 2.85E+01 Media Type: FISHBTMFEEDER Concentration (Activity): pCi/kg Sample Point 208 [ INDICATOR - S @ 0.45 miles ]

Sample ID:

255048 Sample Dates: 41812013 - 41812013 Nuclide Activity I Sigma Error LLD Mn-54

<2.05E+01 0.00E+00 2.05E+01 Co-58

<1.48E+01 0.00E+00 1.48E+01 Fe-59

<3.07E+01 0.00E+00 3.07E+01 Co-60

<2.54E+01 0.00E+00 2.54E+01 Zn-65

<2.50E+01 0.00E+00 2.50E+01 Nb-95

<1.69E+01 0.00E+00 1.69E+01 1-131

<1.97E+01 0.00E+00 1.97E+01 Cs-134

<1.35E+01 0.00E+00 1.35E+01 Cs-137

<2.24E+01 0.OOE+00 2.24E+01 Be-7

<1.41E+02 0.00E+00 1.41E+02 K-40 2.49E+03 2.60E+02 2.51E+02 Ag-110M

<1.96E+01 O.00E+00 1.96E+01 Sb-122

<2.68E+01 0.00E+00 2.68E+01 Sb-125

<4.71E+01 0.00E+00 4.71E+01 Sample ID:

269599 Sample Dates: 101712013 - 101712013 Nuclide Activity I Sigma Error LLD Mn-54

<2.05E+01 O.00E+00 2.05E+01 Co-58

<2.15E+01 0.00E+00 2.15E+01 Fe-59

<5.06E+01 0.00E+00 5.06E+01 Co-60

<2.90E+01 0.00E+00 2.90E+01 Zn-65

<5.52E+01 0.00E+00 5.52E+01 Nb-95

<2.63E+01 O.00E+00 2.63E+01 1-131

<2.13E+01 0.00E+00 2.13E+01 Cs-134

<2.29E+01 0.00E+00 2.29E+01 Cs-137

<1.73E+01 0.00E+00 1.73E+01 Be-7

<1.43E+02 0.002+00 1.43E+02 K-40 2.50E+03 2.43E+02 2.61 E+02 Ag-110M

<1.58E+01 0.00E+00 1.58E+01 Sb-122

<5.83E+01 0.00E+00 5.83E+01 Sb-125

<3.802+01 0.00E+00 3.80E+01 Sample Point 216 [CONTROL - NNE @ 4.19 miles]

Sample ID:

255049 Sample Dates: 418/2013 -4/812013 Nuclide Activity 1 Sigma Error LLD Mn-54

<7.61E+00 0.00E+00 7.61E+00 Co-58

<9.50E+00 0.00E+00 9.50E+00 Fe-59

<2.45E+01 0.OOE+00 2.45E+01 Co-60

<1.20E+01 0.00E+00 1.20E+01 Zn-65

<2.02E+01 0.00E+00 2.02E+01 Nb-95

<9.95E+00 0.00E+00 9.95E+00 1-131

<1.07E+01 0.00E+00 1.07E+01 Cs-134

<7.58E+00 0.00E+00 7.58E+00 Cs-137

<1.15E+01 0.00E+00 1.15E+01 Be-7

<6.92E+01 0.00E+00 6.92E+01 K-40 3.02E+03 1.57E+02 1.04E+02 Ag-IlOM

<8.48E+00 O.OOE+00 8.48E+00 Sb-122

<1.54E+01 0.00E+00 1.54E+01 Sb-125

<2.59E+01 0.00E+00 2.59E+01 Sample ID:

269600 Sample Dates: 1017/2013 -10/7/2013 Nuclide Activity I Sigma Error LLD Mn-54

<1.65E+01 0.00E+00 1.65E+01 Co-58

<1.28E+01 0.00E+00 1.28E+01 Fe-59

<3.42E+01 0.00E+00 3.42E+01 Co-60

<2.41E+01 0.00E+00 2.41E+01 Zn-65

<3.82E+01 0.OOE+00 3.82E+01 Nb-95

<1.80E+01 0.00E+00 1.80E+01 1-131

<1.87E+01 0.00E+00 1.87E+01 Cs-134

<1.58E+01 0.00E+00 1.58E+01 Cs-137

<1.48E+01 0.00E+00 1.48E+01 Be-7

<1.25E+02 0.00E+00 1.25E+02 K-40 2.39E+03 2.06E+02 1.78E+02 Ag-110M

<9.17E+00 0.00+E00 9.17E+00 Sb-122

<3.32E+01 0.00E+00 3.32E+01 0I 0

0I 0

6 0

0 0

0 6

0 0

6 S

0 0

S 0

a Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EN 13339 Hagers Ferry Road D Huntersville, North Carolina 28078 Appendix E - Page 48 of 80 0

0 S

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

W Media Type: FISHBTMFEEDER Concentration (Activity): pCi/kg Sample Point 216 [CONTROL - NNE @ 4.19 miles I 0

0 0

0 S

0 0

S 0

0 0

Sample ID:

269600 Sample Dates: 1017/2013 - 1017/2013 Nuclide Activity I Sigma Error LLD Sb-125

<3.83E+01 0.00E+00 3.83E+01 Media Type: FISHJORAGER Concentration (Activity): pCi/kg Sample Point 208 [ INDICATOR - S @ 0.45 miles ]

Sample ID:

255050 Sample Dates: 41812013 - 41812013 Nuclide Activity I Sigma Error LLD Mn-54

<1.72E+01 0.00E+00 1.72E+01 Co-58

<1.39E+01 0.00E+00 1.39E+01 Fe-59

<2.92E+01 0.00E+00 2.92E+01 Co-60

<2.39E+01 0.OOE+00 2.39E+01 Zn-65

<3.94E+01 0.OOE+00 3.94E+01 Nb-95

<1.48E+01 0.00E+00 1.48E+01 1-131

<1.40E+01 0.00E+00 1.40E+01 Cs-134

<1.12E+01 O.00E+00 1.12E+01 Cs-137

<1.77E+01 0.00E+00 1.77E+01 Be-7

<1.06E+02 0.00E+00 1.06E+02 K-40 2.74E+03 1.87E+02 1.28E+02 Ag-110M

<1.12E+01 0.00E+00 1.12E+01 Sb-122

<2.15E+01 0.00E+00 2.15E+01 Sb-125

<3.54E+01 0.00E+00 3.54E+01 Sample 1D:

269601 Sample Dates: 101712013.10/712013 Nuclide Activity I Sigma Error LLD Mn-54

<2.06E+01 0.00E+00 2.06E+01 Co-58

<1.49E+01 0.00E+00 1.49E+01 Fe-59

<2.61E+01 0.00E+00 2.61E+01 Co-60

<1.91E+01 0.00E+00 1.91E+01 Zn-65

<4.10E+01 0.00E+00 4.10E+01 Nb-95

<1.33E+01 0.00E+00 1.33E+01 1-131

<1.45E+01 0.00E+00 1.45E+01 Cs-134

<1.52E+01 0.00E+00 1.52E+01 Cs-137

<1.76E+01 0.00E+00 1.76E+01 Be-7

<1.07E+02 0.00E+00 1.07E+02 K-40 1.99E+03 1.75E+02 1.64E+02 Ag-110M

<1.66E+01 0.00E+00 1.66E+01 Sb-122

<2.97E+01 0.00E+00 2.97E+01 Sb-125

<3.83E+01 0.00E+00 3.83E+01 Sample Point 216 [CONTROL - NNE @ 4.19 miles]

Sample ID:

255051 Sample Dates: 4/8/2013 - 4/8/2013 Nuclide Activity I Sigma Error LLD Mn-54

<1.02E+01 0.00E+00 1.02E+01 Co-58

<1.13E+01 0.00E+00 1.13E+01 Fe-59

<1.70E+01 0.00E+00 1.70E+01 Co-60

<1.53E+01 0.00E+00 1.53E+01 Zn-65

<3.08E+01 0.00E+00 3.08E+01 Nb-95

<1.09E+01 0.00E+00 1.09E+01 1-131

<1.16E+01 0,OOE+00 1.16E+01 Cs-134

<9.44E+00 0,00E+00 9.44E+00 Cs-137

<1.44E+01 0,00E+00 1.44E+01 Be-7

<9.30E+01 0.00E+00 9.30E+01 K-40 3.05E+03 1.72E+02 1.03E+02 Ag-110M

<1.08E+01 0.00E+00 1.08E+01 Sb-122

<1.24E+01 0.00E+00 1.24E+01 Sb-125

<2.34E+01 0.00E+00 2.34E+01 Sample ID:

269602 Sample Dates: 1017/2013 - 10/7/2013 Nuclide Activity I Sigma Error LLD Mn-54

<6.28E+00 0.00E+00 6.28E+00 Co-58

<6.94E+00 0.00E+00 6.94E+00 Fe-59

<1.56E+01 0.00E+00 1.56E+01 Co-60

<6.69E+00 0.00E+00 6.69E+00 Zn-65

<1.21E+01 0.00E+00 1.21E+01 Nb-95

<7.67E+00 0.00E+00 7.67E+00 1-131

<1.87E+01 0.00E+00 1.87E+01 Cs-134

<5.50E+00 0.00E+00 5.50E+00 Cs-137

<6.15E+00 0.00E+00 6.15E+00 Be-7

<5.22E+01 0.OOE+00 5.22E+01 K-40 3.29E+03 9.38E+01 5.21E+01 Ag-110M

<5.68E+00 0.00E+00 5.68E+00 Sb-122

<3.02E+02 0.00E+00 3.02E+02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories

[fl

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 49 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: FISHFORAGER Concentration (Activity): pCi/kg Sample Point 216 [ CONTROL - NNE @ 4.19 miles ]

Sample ID:

269602 Sample Dates: 101712013 - 101712013 Nuclide Activity I Sigma Error LLD Sb-125

<1.40E+01 0.00E+00 1.40E+01 Media Type: FISHPREDATOR Concentration (Activity): pCi/kg Sample Point 208 [ INDICATOR - S @ 0.46 miles ]

Sample ID:

265052 Sample Dates: 4/812013 - 41812013 Nuclide Activity 1 Sigma Error LLD Mn-54

<2.05E+01 0.00E+00 2.05E+01 Co-58

<2.09E+01 0.00E+00 2.09E+01 Fe-59

<4.24E+01 0.00E+00 4.24E+01 Co-60

<2.36E+01 0.00E+00 2.36E+01 Zn-65

<4.28E+01 0.00E+00 4.28E+01 Nb-95

<2.03E+01 0.002+00 2.03E+01 1-131

<1.80E+01 0.00E+00 1.80E+01 Cs-134

<1.80E+01 0.00E+00 1.80E+01 Cs-137

<2.07E+01 0.00E+00 2.07E+01 Be-7

<1.48E+02 0.00E+00 1.48E+02 K-40 5.63E+03 3.02E+02 1.73E+02 Ag-110M

<1.74E+01 0.00E+00 1.74E+01 Sb-I122

<3.29E+01 0.00E+00 3.29E+01 Sb-125

<4.91E+01 0.00E+00 4.91E+01 Sample ID:

269603 Sample Dates: 101712013 - 101712013 Nuclide Activity 1 Sigma Error LLD Mn-54

<1.18E+01 o.OOE+00 1.18E+01 Co-58

<1.36E+01 0.OOE+00 1.36E+01 Fe-59

<2.70E+01 0.00E+00 2.70E+01 Co-60

<1.94E+01 0.00E+00 1.94E+01 Zn-65

<3.61E+01 0.0OE+00 3.61E+01 Nb-95

<1.43E+01 0.00E+00 1.43E+01 1-131

<1.62E+01 0.OOE+00 1.62E+01 Cs-134

<1.56E+01 0.OOE+00 1.56E+01 Cs-137

<1.58E+01 0.00E+00 1,58E+01 Be-7

<1.05E+02 0.OOE+00 1.05E+02 K-40 2.40E+03 1.61 E+02 1.27E+02 Ag-110M

<1.32E+01 0.00E+00 1.32E+01 Sb-122

<2.35E+01 O.00E+00 2.35E+01 Sb-125

<4.18E+01 0.00E+00 4.18E+01 Sample Point 216 [CONTROL - NNE @ 4.19 miles]

Sample ID:

255053 Sample Dates: 41812013 -41812013 Nuclide Activity 1 Sigma Error LLD Mn-54

<8.73E+00 0.00E+00 8.73E+00 Co-58

<1.22E+01 0.00E+00 1.22E+01 Fe-59

<2.21E+01 0.OOE+00 2.21E+01 Co-60

<1.72E+01 0.00E+00 1.72E+01 Zn-65

<3.17E+01 0.00E+00 3.17E+01 Nb-95

<1.36E+01 0.00E+00 1.36E+01 1-131

<1.07E+01 0.00E+00 1.07E+01 Cs-134

<1.12E+01 0.00E+00 1.12E+01 Cs-137

<1.47E+01 0.00E+00 1.47E+01 Be-7

<8.75E+01 0.00E+00 8.75E+01 K-40 3.10E+03 1.60E+02 1.15E+02 Ag-110M

<1.01E+01 0.00E+00 1.01E+01 Sb-122

<1.83E+01 0.00E+00 1.83E+01 Sb-125

<2.46E+01 0.00E+00 2.46E+01 Sample ID:

269604 Sample Dates: 1017/2013 - 1017/2013 Nuclide Activity I Sigma Error LLD Mn-54

<1.49E+01 0.00E+00 1.49E+01 Co-58

<1.62E+01 O.00E+00 1.62E+01 Fe-59

<2.71E+01 0.00E+00 2.71E+01 Co-60

<2.55E+01 0.00E+00 2.55E+01 Zn-65

<4.43E+01 0.00E+00 4.43E+01 Nb-95

<1.91E+01 0.00E+00 1.91E+01 1-131

<1.19E+01 O.OOE+00 1.19E+01 Cs-134

<1.21E+01 0.00E+00 1.21E+01 Cs-137

<7.24E+00 0.00E+00 7.24E+00 Be-7

<1.39E+02 0.00E+00 1.39E+02 K-40 2.60E+03 2.01E+02 1.71E+02 Ag-i10M

<1.49E+01 0.00E+00 1.49E+01 Sb-122

<3.41E+01 0.00E+00 3.41E+01 66 6

0 6

6 0

0 0

0 6

0 S

6 0

0 0

0 S

0 a

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Enl

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 50 of 80 0

0 S

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E) e Media Type: FISH-PREDATOR Concentration (Activity): pCi/kg

Sample Point 216 [ CONTROL - NNE @ 4.19 miles ]

Sample ID:

269604 Sample Dates: 10/M2013 -101712013 Nuclide Activity I Sigma Error LLD Sb-125

<3.29E+01 O.OOE+00 3.29E+01 Media Type: GROUND WATER Concentration (Activity): pCill Sample Point 254 [INDICATOR - N @ 0.82 miles ]

Sample ID:

250623 Sample Dates: 31/12013 - 31512013 Nuclide Activity I Sigma Error LLD 0

0 S

0 0

0 S

0 0

S 0

0 0

0 Sample ID:

269855 Sample ID:

279121 Sample Dates: 911712013 - 911712013 Sample Dates: 1211012013 -12/1012013 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 H3GW Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 H3GW Nuclide Mn-54 CO-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 H3GW

<7.64E+00

<1.39E+01

<7.90E+00

<1.56E+01

<1.35E+01

<8.53E+00

<8.80E+00

<7.41E+00

<1.05E+01

<6.03E+01 2.19E+02

<4.51E+00 Activity

<7.26E+00

<7.28E+00

<1.41E+01

<9, 15E+00

<1.73E+01

<1.43E+01

<8.81E+00

<8.22E+00

<7.43E+00

<7.33E+00

<1.04E+01

<6.22E+01 1.02E+02

<-3.8E+01 Activity

<6.49E+00

<6.47E+00

<1.18E+01

<9.99E+00

<1.88E+01

<1.43E+01

<7.29E+00

<1.16E+01

<5.76E+00

<6.61E+00

<7.OOE+00

<6.38E+01 2.94E+02

<2.37E+01 0.002+00 0.00E+00 0.00E+00 O.OOE+0O 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+O0 0.00E+00 4.18E+01 0.00E+00 I Sigma Error O.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+O0 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.76E+01 0.00E+00 1 Sigma Error 0.00E+00 0.00E+00 0.002+00 0.00E+00 0.00E+00 0.OOE+00 0.O+00 0.00E+00 0.OOE+00 0.OOE+00 0.OOE+00 0.00E+00 4.45E+01 0.OOE+00 7.64E+00 7.64E+00 1.39E+01 7.90E+00 1.56E+01 1.35E+01 8.53E+00 8.80E+00 7.41E+00 7.41E+00 1.05E+01 6.03E+01 6.68E+01 1.69E+02 LLD 7.26E+00 7.28E+00 1.41E+01 9.15E+00 1.73E+01 1.43E+01 8.81E+00 8.22E+00 7.43E+00 7.33E+00 1.04E+01 6.22E+01 8.85E+01 1.54E+02 LLD 6.49E+00 6.47E+00 1.18E+01 9.99E+00 1.88E+01 1.432+01 7.29E+00 1.16E+01 5.76E+00 6.61E+00 7.00E+00 6.38E+01 3.98E+01 2.31E+02 Media Type: MILK Concentration (Activity): pCi/I Sample Point 221 [ CONTROL - NW @ 14.5 miles ]

Sample ID:

250462 Sample Dates: 112/2013 -112/2013 Nuclide Activity 1 Sigma Error LLD Be-7

<4.13E+00 0.00E+00 4.13E+00 K-40 2.44E+01 4.22E+00 7.81E+00 LLi-131

<5.98E-01 0.00E+00 5.98E-01 1-131

<7.22E+00 0.00E+00 7.22E+00 Cs-134

<6.98E+00 0.00E+00 6.98E+00 Cs-137

<9.54E+00 0.00E+00 9.54E+00 SaLa-140

<2.71E+00 0.00E+00 2.71E+00 Be-7

<5.952+01 0.00E+00 5.95E+01 K-40 1.84E+03 1.36E+02 1.11E+02 Sample ID:

260761 Sample Dates: 1/1612013 - 1/16/2013 Nuclide Activity 1 Sigma Error LLD Be-7

<5.00E+00 0.00E+00 5.00E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnID EnRad Laboratories 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 51 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: MILK Concentration (Activity): pCI/I Sample Point 221 [CONTROL - NW @ 14.5 miles ]

Sample ID:

250761 Sample ID:

251295 Sample ID:

252109 Sample ID:

253118 Sample ID:

254243 Sample ID:

265339 Sample ID:

256096 Sample Dates: 1/15/2013 - 1/15/2013 Sample Dates: 1/2912013 -1129/2013 Sample Dates: 2/12/2013 -2112/2013 Sample Dates: 212612013 - 212612013 Sample Dates: 3/12/2013-3/1212013 Sample Dates: 3/26/2013 -3/2612013 Sample Dates: 4/912013 -41912013 Nuclide Activity I Sigma Error LLD K-40 4.29E+01 5.35E+00 6.70E+00 LLI-131

<6.46E-01 0.00E+00 6.46E-01 1-131

<8,14E+00 0.00E+00 8.14E+00 Cs-134

<7.81E+00 0.OOE+00 7.81E+00 Cs-137

<8.26E+00 O.OOE+O0 8.26E+00 BaLa-140

<1,30E+01 0.00E+00 1.30E+01 Be-7

<6.41E+01 0.OOE+00 6.41E+01 K-40 1,80E+03 1.20E+02 1.07E+02 Nuclide Activity I Sigma Error LLD Be-7

<7.09E+00 0.00E+00 7.09E+00 K-40 9.02E+00 4.66E+00 1.24E+01 LLI-131

<6.42E-01 0.00E+00 6.42E-01 1-131

<6.73E+00 0.OOE+00 6.73E+00 Cs-134

<7.33E+00 0.00E+00 7.33E+00 Cs-137

<1.10E+01 O.OOE+00 1.10E+01 BaLa-140

<9.86E+00 0.00E+00 9.86E+00 Be-7

<5.47E+01 0.00E+00 5.47E+01 K-40 1.67E+03 1.17E+02 8.01E+01 Nuclide Activity 1 Sigma Error LLD Be-7

<5.22E+00 0.00E+00 5.22E+00 K-40 4.97E+01 4.70E+00 7.29E+00 LLI-131

<6.17E-01 0.00E+00 6.17E-01 1-131

<9.18E+00 O.00E+00 9.18E+00 Cs-134

<8.01E+00 0.00E+00 8.01E+00 Cs-137

<9.29E+00 0.00E+00 9.29E+00 BaLa-140

<4.99E+00 0.00E+00 4.99E+00 Be-7

<7.96E+01 0.00E+00 7.96E+01 K-40 1.58E+03 1.14E+02 1.06E+02 Nuclide Activity 1 Sigma Error LLD Be-7

<4.36E+00 0.00E+00 4.36E+00 K-40 2.25E+00 3.14E+00 4.47E+00 LLI-131

<6.31E-01 0.00E+00 6.31E-01 1-131

<7.90E+00 0.OOE+00 7.90E+00 Cs-134

<8.20E+00 0.00E+00 8.20E+00 Cs-137

<1.12E+01 0.00E+00 1.12E+01 BaLa-140

<7.64E+00 0.00E+00 7.64E+00 Be-7

<7.34E+01 0.00E+00 7.34E+01 K-40 1.48E+03 1.23E+02 1.04E+02 Nuclide Activity Sigma Error LLD Be-7

<5.04E+00 0.OOE+00 5.04E+00 K-40 1.79E+01 3.97E+00 1.02E+01 LLI-131

<6.09E-01 0.00E+00 6.09E-01 1-131

<7.08E+00 0.00E+00 7.08E+00 Cs-134

<5.58E+00 0.00E+00 5.58E+00 Cs-137

<9.09E+00 0.00E+00 9.09E+00 BaLa-140

<8.79E+00 0.00E+00 8.79E+00 Be-7

<5.80E+01 0.00E+00 5.80E+01 K-40 1.60E+03 1.11E+02 6.90E+01 Nuclide Activity 1 Sigma Error LLD Be-7

<4.30E+00 0.00E+00 4.30E+00 K-40 1.76E+01 4.53E+00 8.74E+00 LLI-131

<6.48E-01 0.00E+00 6.48E-01 1-131

<6.43E+00 0.00E+00 6.43E+00 Cs-134

<7.40E+00 0.00E+00 7.40E+00 Cs-137

<6.67E+00 0.00E+00 6.67E+00 BaLa-140

<4.26E+00 0.00E+00 4.26E+00 Be-7

<5.55E+01 0.00E+00 5.55E+01 K-40 1.63E+03 1.17E+02 9.91E+01 Nuclide Activity 1 Sigma Error LLD Be-7

<4.45E+00 0.00E+00 4.45E+00 K-40 2.07E+01 4.78E+00 7.89E+00 LLI-131

<6.10E-01 0.00E+00 6.10E-01 66 0

0 0

S 6

0 0

0 S

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E l 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 52 of 80 0

0 0

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

O Media Type: MILK Concentration (Activity): pCIli Sample Point 221 [ CONTROL - NW @ 14.5 miles ]

Sample ID:

256656 0

0 Sample ID:

257335 S

0 S

0 Sample ID:

258026 0

0 0

Sample ID:

258608 0

S S

O Sample ID:

259629 0

0 0

Sample ID:

260750 00 0

Sample ID:

262199 0

S Sample Dates: 4/23/2013 - 412312013 Sample Dates: 51712013 -51712013 Sample Dates: 512112013 -512112013 Sample Dates: 61412013 -61412013 Sample Dates: 611812013 - 611812013 Sample Dates: 71212013.71212013 Sample Dates: 711612013 *711612013 Nuclide Activity Be-7

<5.24E+00 K-40 1.18E+01 LLI-131

<6.10E-01 1-131

<6.00E+00 Cs-134

<4.54E+00 Cs-137

<5.57E+00 BaLa-140

<3.89E+00 Be-7

<4.61E+01 K-40 1.87E+03 Nuclide Activity Be-7

<5.33E+00 K-40 4.27E+01 LL1-131

<6.45E-01 1-131

<5.57E+00 Cs-134

<5.52E+00 Cs-137

<6.14E+00 BaLa-140

<6.93E+00 Be-?

<4.06E+01 K-40 1.78E+03 Nuclide Activity Be-7

<4.52E+00 K-40 4.74E+01 LLI-131

<6.50E-01 1-131

<5.20E+00 Cs-134

<4.84E+00 Cs-137

<5.66E+00 BaLa-140

<5.98E+00 Be-7

<4.28E+01 K-40 1.46E+03 Nuclide Activity Be-7

<5.05E+00 K-40 5.43E+01 LL1-131

<6.47E-01 1-131

<4.98E+00 Cs-134

<4.59E+00 Cs-137

<6.33E+00 BaLa-140

<6.17E+00 Be-7

<3.76E+01 K-40 1.81E+03 Nuclide Activity Be-7

<4.58E+00 K-40 2.31E+01 LL1-131

<5.78E-01 1-131

<3.76E+00 Cs-134

<3.13E+00 Cs-137

<3.98E+00 BaLa-140

<4.41E+00 Be-7

<3.21E+01 K-40 1.66E+03 Nuclide Activity Be-7

<5.59E+00 K-40 2.31E+01 LLI-131

<6.43E-01 1-131

<5.49E+00 Cs-134

<5.38E+00 Cs-137

<5.97E+00 BaLa-140

<4.53E+00 Be-7

<3.95E+01 K-40 1.79E+03 Nuclide Activity Be-7

<5.25E+00 K-40 1.48E+01 LLi-131

<6.37E-01 1-131

<4.78E+00 I Sigma Error 0.00E+00 4.53E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 8.80E+01 1 Sigma Error 0.00E+00 5.15E+00 0.00E+00 O.OOE+00 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 8.80E+01 1 Sigma Error 0.OOE+00 4.54E+00 0.00E+00 O.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 8.70E+01 I Sigma Error 0.00E+00 5.47E+00 0.00E+00 0.00E+00 0.00E+00 0.00+E00 0.00+E00 O.OOE+00 8.90E+01 I Sigma Error 0.00E+00 4.42E+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.26E+01 1 Sigma Error 0.00E+00 4.81E+00 0.OOE+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 9.10E+01 1 Sigma Error 0.00E+00 4.90E+00 O.00E+00 O.00E+00 LLD 5.24E+00 6.12E+00 6.10E-01 6.00E+00 4.54E+00 5.57E+00 3.89E+00 4.61E+01 5.22E+01 LLD 5.33E+00 7.77E+00 6.45E-01 5.57E+00 5.52E+00 6.14E+00 6.93E+00 4.06E+01 5.19E+01 LLD 4.52E+00 4.18E+00 6.50E-01 5.20E+00 4.84E+00 5.66E+00 5.98E+00 4.28E+01 5.65E+01 LLD 5.05E+00 6.42E+00 6.47E-01 4.98E+00 4.59E+00 6.33E+00 6.17E+00 3,76E+01 4.54E+01 LLD 4.58E+00 7.44E+00 5.78E-01 3.76E+00 3.13E+00 3.98E+00 4.41E+00 3.21E+01 3.27E+01 LLD 5.59E+00 7.98E+00 6.43E-01 5.49E+00 5.38E+00 5.97E+00 4.53E+00 3.95E+01 6.46E+01 LLD 5.25E+00 8.71E+00 6.37E-01 4.78E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E fl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 53 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: MILK Concentration (Activity): pCill Sample Point 221 [ CONTROL - NW @ 14.5 miles ]

Sample ID:

262199 Sample ID:

263432 Sample ID:

265221 Sample ID:

267216 Sample ID:

268526 Sample ID:

270805 Sample Dates: 711612013 -711612013 Sample Dates: 7130/2013 -713012013 Sample Dates: 811312013 - 8/1312013 Sample Dates: 812712013 - 812712013 Sample Dates: 9/10/2013 -9/1012013 Sample Dates: 9/2412013 -9/24/2013 Nuclide Activity I Sigma Error Cs-1 34

<5.30E+00 0.00E+00 Cs-137

<7.45E+00 0.00E+00 BaLa-140

<7.33E+00 0.00E+00 Be-7

<4.55E+01 0.00E+00 K-40 1.82E+03 9.29E+01 Nuclide Activity I Sigma Error Be-7

<4.89E+00 0.OOE+00 K-40 2.97E+01 5.14E+00 LLI-131

<6.49E-01 0.00E+00 1-131

<5.33E+00 0.00E+00 Cs-134

<5.63E+00 0.OOE+00 Cs-137

<6.97E+00 0.00E+00 BaLa-140

<6.00E+00 0.00E+00 Be-7

<4.36E+01 O.00E+00 K-40 1.86E+03 8.94E+01 Nuclide Activity i Sigma Error Be-7

<3.62E+00 0.00E+00 K-40 1.74E+01 3.26E+00 LLI-131

<5.91E-01 0.OOE+00 1-131

<6.45E+00 0.OOE+00 Cs-134

<5.51E+00 O.00E+00 Cs-137

<7.29E+00 0.00E+00 BaLa-140

<5.29E+00 O.00E+00 Be-7

<4.19E+01 0.OOE+00 K-40 1.82E+03 8.40E+01 Nuclide Activity 1 Sigma Error Be-7

<4.18E+00 0.OOE+00 K-40 1.17E+01 4.44E+00 LLI-131

<5.81E-01 0.00E+00 1-131

<5.25E+00 0.00E+00 Cs-134

<7.37E+00 0.00E+00 Cs-137

<1.04E+01 0.00E+00 BaLa-140

<1.11E+01 0.00E+00 Be-7

<6.16E+01 0.00E+00 K-40 1.60E+03 1.10E+02 Nuclide Activity 1 Sigma Error Be-7

<4.45E+00 0.00E+00 K-40 1.35E+01 3.90E+00 LLI-131

<6.35E-01 0.00E+00 1-131

<7.03E+00 0.00E+00 Cs-134

<3.22E+00 O.OOE+00 Cs-137

<3.94E+00 O.OOE+00 BaLa-140

<5.28E+00 O.OOE+00 Be-7

<2.80E+01 O.OOE+00 K-40 1.40E+03 5.73E+01 Nuclide Activity 1 Sigma Error Be-7

<4.35E+00 0.00E+00 K-40 2.46E+01 3.45E+00 LLI-131

<5.68E-01 O.00E+00 1-131

<4.73E+00 0.OOE+00 Cs-134

<5.21E+00 0.00E+00 Cs-137

<5.78E+00 0.00E+00 BaLa-140

<6.92E+00 0.00E+00 Be-7

<4.50E+01 O.OOE+00 K-40 1.56E+03 8.43E+01 LLD 5.30E+00 7.45E+00 7.33E+00 4.55E+01 5.71E+01 LLD 4.89E+00 9.47E+00 6.49E-01 5.33E+00 5.63E+00 6.97E+00 6.00E+00 4.36E+01 4.48E+01 LLD 3.62E+00 5.69E+00 5.91E-01 6.45E+00 5.51E+00 7.29E+00 5.29E+00 4.19E+01 1.05E+01 LLD 4.18E+00 6.55E+00 5.81E-0 1 5.25E+00 7.37E+00 1.04E+01 1.11E+01 6.16E+01 7.07E+01 LLD 4.45E+00 7.08E+00 6.35E-01 7.03E+00 3.22E+00 3.94E+00 5.28E+00 2.80E+01 3.87E+01 LLD 4.35E+00 4.23E+00 5.68E-01 4.73E+00 5.21E+00 5.78E+00 6.92E+00 4.50E+01 5.56E+01 U0 0

0 6

6 0

0 6

0 0

S 0

0 0

0 Apenix2Pae 4 of8 0

S Sample ID:

272123 Sample Dates: 1018/2013 - 10/812013 Nuclide Activity I Sigma Error LLD Be-7

<4.40E+00 0.00E+00 4.40E+00 K-40 5.64E+01 4.73E+00 6.43E+00 LLI-131

<6.30E-01 0.00E+00 6.30E-01 1-131

<8.77E+00 0.00E+00 8.77E+00 Cs-134

<9.98E+00 0.00E+00 9.98E+00 Cs-137

<9.74E+00 0.00E+00 9.74E+00 BaLa-140

<2.90E+00 0.00E+00 2.90E+00 Be-7

<7.98E+01 0.00E+00 7.98E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: MILK Concentration (Activity): pCi/I Sample Point 221 [ CONTROL - NW @ 14.5 miles I O

Sample ID:

272123 Sample ID:

272906 0

0 Sample ID:

274444 0

S 0

0 Sample ID:

276512 0

0 0

0 O

Sample ID:

278816 0

0 0

0 Sample ID:

279664 00 0

Sample 10:

280691 0

0 0

Sample Dates: 101812013.101812013 Sample Dates: 10122J2013 - 1012212013 Sample Dates: 11112013-111512013 Sample Dates: 1111912013 - 1111912013 Sample Dates: 121312013-121312013 Sample Dates: 12/17/2013 - 1211712013 Sample Dates: 12/31/2013 -12131/2013 Nuclide Activity I Sigma Error K-40 1.39E+03 1.11E+02 Nuclide Activity 1 Sigma Error Be-7

<3.75E+00 0.00E+00 K-40 4.20E+01 4.67E+00 LLi-131

<5.42E-01 0.OOE+00 1-131

<6.24E+00 0.00E+00 Cs-134

<5.90E+00 0.O0E+00 Cs-137

<7.69E+00 0.OOE+00 BaLa-140

<9.23E+00 0.00E+00 Be-7

<5.29E+01 0.OOE+00 K-40 1.73E+03 8.47E+01 Nuclide Activity I Sigma Error Be-7

<4.95E+00 0.00E+00 K-40 5.61E+01 5.82E+00 LLI-131

<6.35E-01 0.00E+00 1-131

<5.59E+00 0.OOE+00 Cs-134

<5.62E+00 0.OOE+00 Cs-137

<7.16E+00 0.O0E+00 BaLa-140

<5.61E+00 0.OOE+00 Be-7

<4.41E+01 0.OOE+00 K-40 1.45E+03 7.92E+01 Nuclide Activity I Sigma Error Be-7

<4.41E+00 0.00E+00 K-40 5.30E+01 5.16E+00 LLI-131

<5.60E-01 0.OOE+00 1-131

<9.01E+00 0.00E+00 Cs-134

<1.00E+01 0.00E+00 Cs-137

<1.01E+01 0.OOE+00 BaLa-140

<8.98E+00 o.O0E+00 Be-7

<7.49E+01 0.00E+00 K-40 1.50E+03 1.22E+02 Nuclide Activity 1 Sigma Error Be-7

<2.99E+00 0.00E+00 K-40 2.04E+01 3.29E+00 LLI-131

<6.15E-01 0.00E+00 1-131

<9.23E+00 0.O0E+00 Cs-134

<9.59E+00 0.00E+00 Cs-137

<8.89E+00 0.00E+00 BaLa-140

<6.38E+00 0.00E+00 Be-7

<5.20E+01 0.00E+00 K-40 1.48E+03 1.29E+02 Nuclide Activity 1 Sigma Error Be-7

<4.32E+00 0.00E+00 K-40 4.03E+01 4.62E+00 LLI-131

<6.13E-01 0.00E+00 1-131

<8.52E+00 0.00E+00 Cs-134

<9.58E+00 0.00E+00 Cs-137

<1.042+01 0.00E+00 BaLa-140

<7.91E+00 0.00E+00 Be-7

<6.16E+01 O.OOE+00 K-40 1.49E+03 1.18E+02 Nuclide Activity 1 Sigma Error Be-7

<3.16E+00 0.00E+00 K-40 1.02E+01 2.13E+00 LLi.131

<5.98E-01 0.00E+00 i-131

<7.46E+00 0.00E+00 Cs-134

<6.15E+00 0.00E+00 Cs-137

<7.11E+00 0.00E+00 BaLa-140

<7.00E+00 O.00E+00 8e-7

<4.09E+01 0.00E+00 K-40 1.68E+03 8.42E+01 LLD 9.14E+01 LLD 3.75E+00 6.11E+00 5.42E-01 6.24E+00 5.90E+00 7.69E+00 9.23E+00 5.29E+01 5.15E+01 LLD 4.95E+00 7.61E+00 6.35E-01 5.59E+00 5.62E+00 7.16E+00 5.61E+00 4.41E+01 3.97E+01 LLD 4.41E+00 6.24E+00 5.60E-01 9.01E+00 1.00+E01 1.01E+01 8.98E+00 7.49E+01 1.12E+02 LLD 2.99E+00 3.96E+00 6.15E-01 9.23E+00 9.59E+00 8.89E+00 6.38E+00 5.20E+01 1.12E+02 LLD 4.32E+00 7.12E+00 6.13E-01 8.52E+00 9.58E+00 1.04E+01 7.91E+00 6.16E+01 7.93E+01 LLD 3.16E+00 3.90E+00 5.98E-01 7.46E+00 6.15E+00 7.11E+00 7.00E+00 4.09E+01 6.16E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EN*

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 55 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SEDIMENT-SHORE Concentration (Activity): pCIIkg Sample Point 208 [ INDICATOR - S @ 0.45 miles I Sample ID:

265063 Sample ID:

269614 Sample Dates: 411612013-411612013 Sample Dates: 1012212013 -1012212013 Nuclide Activity 1 Sigma Error Mn-54

<2.56E+01 0.O0E+00 Co-58

<2.47E+01 0.00E+00 Fe-59

<5.53E+01 0.00E+00 Co-60

<3.54E+01 O.OOE+00 Zn-65

<6.10E+01 0.00E+00 Zr-95

<3.91E+01 0.00E+00 Nb-95

<2.04E+01 0.OOE+00 1-131

<1.90E+01 O.OOE+00 Cs-134

<2.04E+01 O.OOE+00 Cs-137

<2.55E+01 O.OOE+00 Be-7 2.34E+02 8.93E+01 K-40 1.36E+04 4.52E+02 Co-57

<1.36E+01 0.00E+00 Mo-99

<2.09E+02 O.OOE+00 Ag-110M

<1.85E+01 0.00E+00 Sb-122

<3.29E+01 0.00E+00 Sb-125

<4.87E+01 0.00E+00 Nuclide Activity I Sigma Error Mn-54

<2.46E+01 0.00E+00 Co-58

<2.55E+01 0.OOE+00 Fe-59

<5.51E+01 0.00E+00 Co-60

<3.83E+01 O.OOE+O0 Zn-65

<6.08E+01 O.00E+00 Zr-95

<3.62E+01 O.OOE+O0 Nb-95

<2.50E+01 0.00E+00 1-131

<2.80E+01 0.OOE+00 Cs-134

<1.96E+01 O.00E+00 Cs-137

<2.64E+01 0.OOE+O0 Be-7 2.21E+02 8.29E+01 K-40 1.44E+04 4.49E+02 Co-57

<1.33E+01 0.00E+00 Mo-99

<7.26E+02 0.00E+00 Ag-110M

<2.10E+01 0.00E+00 Sb-122

<1.11E+02 O.OOE+00 Sb-125

<5.65E+01 O.OOE+00 LLD 2.56E+01 2.47E+01 5.53E+01 3.54E+01 6.10E+01 3.91E+01 2.04E+01 1.90E+01 2.04E+01 2.55E+01 1.52E+02 2.05E+02 1.36E+01 2.09E+02 1.85E+01 3.29E+01 4.87E+01 LLD 2.46E+01 2.55E+01 5.51E+01 3.83E+01 6.08E+01 3.62E+01 2.50E+01 2.80E+01 1.96E+01 2.64E+01 1.44E+02 2.OOE+02 1.33E+01 7.26E+02 2.10E+01 1.11E+02 5.65E+01 Sample Point 210 [ INDICATOR - SE @ 2.31 miles ]

Sample ID:

255064 Sample ID:

269615 Sample Dates: 411612013.411612013 Sample Dates: 1012212013 -1012212013 Nuclide Activity I Sigma Error Mn-54

<1.34E+01 0.00E+00 Co-58

<1.25E+01 0.00E+00 Fe-59

<2.71E+01 0.00E+00 Co-60

<1.76E+01 0.00E+00 Zn-65

<3.35E+01 0.OOE+00 Zr-95

<1.94E+01 0.OOE+00 Nb-95

<1.26E+01 0.00E+00 1-131

<1.16E+01 0.00E+00 Cs-134

<1.04E+01 0.00E+00 Cs-137

<1.25E+01 O.OOE+00 Be-7 1.28E+02 3.32E+01 K-40 8.87E+03 2.69E+02 Co-57

<8.76E+00 0.OOE+00 Mo-99

<1.15E+02 0.00E+00 Ag-110M

<1.21E+01 0.00E+00 Sb-122

<1.85E+01 0.OOE+00 Sb-125

<2,93E+01 0.OOE+00 Nuclide Activity I Sigma Error Mn-54

<1,84E+01 0.OOE+00 Co-58

<1,79E+01 0.00E+00 Fe-59

<3.95E+01 0.00E+00 Co-60

<2.26E+01 0.00E+00 Zn-65

<4.93E+01 0.00E+00 Zr-95

<3.06E+01 0.OOE+00 Nb-95

<1.83E+01 O.OOE+00 1-131

<2.58E+01 0.00E+00 Cs-134

<1.67E+01 0.00E+00 Cs-137

<0.85E+01 O.OOE+00 LLD 1.34E+01 1.25E+01 2.71E+01 1.76E+01 3.35E+01 1.94E+01 1.26E+01 1.16E+01 1.04E+01 1.25E+01 7.96E+01 1.10E+02 8.76E+00 1.15E+02 1.21E+01 1.85E+01 2.93E+01 LLD 1.84E+01 1.79E+01 3.95E+01 2.26E+01 4.93E+01 3.06E+01 1.83E+01 2.58E+01 1.67E+01 1.85E+01 00 0

0 6

0 S

S 0

0 0

0 S

0 Apedi

-Pge5 o 0

S Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ER 13339 Hagers Ferry Road Huntersville, North Carolina 28078

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SEDIMENTSHORE Concentration (Activity): pCI/kg Sample Point 210 [ INDICATOR - SE @ 2.31 miles I Sample ID:

269615 Sample Dates: 1012212013 - 10122/2013 S

0 0

O Sample Point 215 [ CONTROL - NNE @ 4.21 miles ]

Nuclide Activity Be-7

<1.63E+02 K-40 8.11 E+03 Co-57

<1.53E+01 Mo-99

<5.53E+02 Ag-110M

<1.64E+01 Sb-1 22

<1.07E+02 Sb-125

<4.14E+01 I Sigma Error 0.00E+00 3.28E+02 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 1.63E+02 2.02E+02 1.53E+01 5.53E+02 1.64E+01 1.07E+02 4.14E+01 O

Sample ID:

255065 0

0 S

0 Sample ID:

269616 0

0 0

S 0

Sample Dates: 4/16/2013.411612013 Sample Dates: 10/2212013 -10122/2013 Nuclide Activity Mn-54

<2.66E+01 C0-58

<2.26E+01 Fe-59

<6.34E+01 CG-60

<3.04E+01 Zn-65

<7.07E+01 Zr-95

<3.73E+01 Nb-95

<2.87E+01 1-131

<3.08E+01 Cs-134

<1.92E+01 Cs-137

<2.40E+01 Be-7 1.84E+02 K-40 1.85E+04 Co-57

<1.57E+01 Mo-99

<8.28E+02 Ag-10M

<2.22E+01 Sb-122

<1.48E+02 Sb-125

<5.36E+01 Nuclide Activity Mn-54

<1.36E+01 Co-58

<1.44E+01 Fe-59

<3.86E+01 Co-60

<1.77E+01 Zn-65

<3.96E+01 Zr-95

<2.66E+01 Nb-95

<1.76E+01 1-131

<2.12E+01 Cs-134

<1.24E+01 Cs-137

<1.38E+01 Be-7

<1.15E+02 K-40 1.64E+04 C0-57

<1.17E+01 Mo-99

<4.74E+02 Ag-110M

<1.36E+01 Sb-122

<7.30E+01 Sb-125

<3.50E+01 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 6.77E+01 5.11E+02 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 I Sigma Error O.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.13E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 2.66E+01 2.26E+01 6.34E+01 3.04E+01 7.07E+01 3.73E+01 2.87E+01 3.08E+01 1.92E+01 2.40E+01 1.92E+02 2.61E+02 1.57E+01 8.28E+02 2.22E+01 1.48E+02 5.36E+01 LLD 1.36E+01 1.44E+01 3.86E+01 1.77E+01 3.96E+01 2.66E+01 1.76E+01 2.12E+01 1.24E+01 1.38E+01 1.15E+02 1.17E+02 1.17E+01 4.74E+02 1.36E+01 7.30E+01 3.50E+01 Media Type: SURFACE WATER Concentration (Activity): pCIII Sample Point 208 [ INDICATOR - S @ 0.45 miles ]

Sample ID:

250619 Sample Dates: 12/11/2012 - 118/2013 0

0 0

Nuclide Activity Mn-54

<2.37E+00 Co-58

<2.41E+00 Fe-59

<5.70E+00 Co-60

<3.56E+00 Zn-65

<4.74E+00 Zr-95

<4.67E+00 Nb-95

<2.98E+00 1-131

<8.70E+00 Cs-134

<2.32E+00 Cs-137

<2.72E+00 BaLa-140

<6.35E+00 Be-7

<2.10E+01 K-40 8.78E+01 Nuclide Activity Mn-54

<5.05E+00 Co-58

<5.05E+00 1 Sigma Error 0.00E+00 0.OOE+00 0.OOE+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.16E+01 I Sigma Error O.OOE+00 0.00E+00 LLD 2.37E+00 2.41E+00 5.70E+00 3,56E+00 4.74E+00 4.67E+00 2.98E+00 8.70E+00 2.32E+00 2.72E+00 6.35E+00 2.10E+01 2.56E+01 LLD 5.05E+00 5.05E+00 O

Sample ID:

251670 0

Sample Dates: 1/8/2013 - 2/6/2013 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report-Appendix E EnRad Laboratories Efl

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 57 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SURFACE WATER Concentration (Activity): pCI/i Sample Point 208 [ INDICATOR - S @ 0.45 miles I Sample ID:

251670 Sample Dates: 11812013 -21512013 Nuclide Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-1 37 BaLa-140 Be-7 K-40 Activity

<1.18E+01

<7.23E+00

<1.45E+01

<8.88E+00

<5.51E+00

<1.43E+01

<4.00E+00

<5.64E+00

<1.22E+01

<4.20E+01 6.20E+01 Sample ID:

253086 Sample ID:

253941 Sample ID:

255940 Sample ID:

257193 Sample Dates: 1211112012 -3/512013 Sample Dates: 2/512013 -3/612013 Sample Dates: 315/2013 -4/2)2013 Sample Dates: 4/2/2013.4/3012013 Nuclide Activity H3SW 5.18E+03 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Activity

<4.30E+00

<4.29E+00

<9.57E+00

<4.32E+00

<8.45E+00

<8.32E+00

<5.15E+00

<1.39E+01

<3.97E+00

<4.26E+00

<9.51 E+00

<3.91E+01 1.43E+02 Activity

<3.88E+00

<4.59E+00

<1.08E+01

<4.90E+00

<9.94E+00

<9.45E+00

<4.48E+00

<1.30E+01

<3.93E+00

<5.14E+00

<8.63E+O0

<3.95E+01 3.92E+01 Activity

<3.57E+00

<3.25E+00

<8.32E+00

<3.05E+00

<6.04E+00

<6.55E+00

<4.20E+00

<1.34E+01

<2.59E+00

<3.33E+00

<7.86E+00

<3.44E+01 1.56E+02 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 1.90E+01 1 Sigma Error 1.11E+02 1 Sigma Error O.0OE+00 0.00E+00 0.00E+00 0.0OE+00 O.00E+00 O.00E+00 0.00E+00 O.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 3.04E+01 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.89E+01 1 Sigma Error 0.00E+00 0.OOE+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.O0E+00 0.00E+00 0.00E+00 0.00E+00 1.94E+01 1 Sigma Error 1.08E+02 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 1.18E+01 7.23E+00 1.45E+01 8.88E+00 5.51E+00 1.43E+01 4.00E+00 5.64E+00 1.22E+01 4.20E+01 5.45E+01 LLD 1.64E+02 LLD 4.30E+00 4.29E+00 9.57E+00 4.32E+00 8.45E+00 8.32E+00 5.15E+00 1.39E+01 3.97E+00 4.26E+00 9.51E+00 3.91E+01 4.60E+01 LLD 3.88E+00 4.59E+00 1.08E+01 4.90E+00 9.94E+00 9.45E+00 4.48E+00 1.30E+01 3.93E+00 5.14E+00 8.63E+00 3.95E+01 4.56E+01 LLD 3.57E+00 3.25E+00 8.32E+00 3.05E+00 6.04E+00 6.55E+00 4.20E+00 1.34E+01 2.59E+00 3.33E+00 7.86E+00 3.44E+01 3.19E+01 LLD 1.77E+02 LLD 2.79E+00 3.25E+00 8.24E+00 4.87E+00 6.23E+00 5.41E+00 6a 6

0 6

0 0

6 0

0 0

6 6

6 0

0 0

0 S

0 0

Sample ID:

268169 Sample ID:

258321 Sample Dates: 3/6/2013.5/2912013 Sample Dates: 413012013 -5/29/2013 Nuclide Activity H3SW 4.49E+03 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Activity

<2.79E+00

<3.25E+00

<8.24E+00

<4.87E+00

<6.23E+00

<5.41E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories

[fl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 58 of 80

0 CATAWBA Radiological Environmental Monitoring Analysis Report-2013 (Appendix E)

W Media Type: SURFACE WATER Concentration (Activity): pCI/I Sample Point 208 [ INDICATOR - S @ 0.45 miles I 00 0

0 0

S 0

0 0

0 Sample ID:

258321 Sample Dates: 4130/2013.5/29/2013 Nuclide Activity Sample ID:

260424 Sample ID:

263221 Sample ID:

266732 Sample ID:

267113 Sample ID:

269851 Sample Dates: 612912013 -612512013 Sample Dates: 6/2512013-7123/2013 Sample Dates: 7/23/2013 -8120/2013 Sample Dates: 6/29/2013 -8/2012013 Sample Dates: 8/20/2013 -9/17/2013 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-1 37 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 SaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40

<3.78E+00

<1.03E+01

<3.07E+00

<3.08E+00

<7.02E+00

<3.07E+01 8.63E+01 Activity

<4.28E+00

<3.83E+00

<9.14E+00

<5.58E+00

<5.99E+00

<6.88E+00

<4.81E+00

<1.37E+01

<4.OOE+00

<4.27E+00

<7.54E+00

<4.39E+01 1.32E+02 Activity

<3.34E+00

<3.97E+00

<7.10E+00

<3.90E+00

<6.43E+00

<6.32E+00

<5.34E+00

<1.40E+01

<3.54E+00

<4.06E+00

<9.08E+00

<3.84E+01 1.47E+02 Activity

<4.08E+00

<5.28E+00

<9.53E+00

<5.32E+00

<6.22E+00

<7.30E+00

<5.59E+00

<1.40E+01

<3.50E+00

<4.78E+00

<1.32E+01

<4,88E+01 2.12E+02 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.53E+01 I Sigma Error 0.00E+00 0.00E+00 0.0OE+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 O.OOE+00 0.00E+00 0.00E+00 0.OOE+00 1.80E+01 I Sigma Error 0.00E+00 0.00E+00 0.0OE+00 O.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 2.43E+01 I Sigma Error 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.OOE+00 2.73E+01 LLD 3.78E+00 1.03E+01 3.07E+00 3.08E+00 7.02E+00 3.07E+01 3.17E+01 LLD 4.28E+00 3.83E+00 9.14E+00 5.58E+00 5.99E+00 6.88E+00 4.81E+00 1.37E+01 4.00E+00 4.27E+00 7.54E+00 4.39E+01 3.44E+01 LLD 3.34E+00 3.97E+00 7.10E+00 3.90E+00 6.43E+00 6.32E+00 5.34E+00 1.40E+01 3.54E+00 4.06E+00 9.08E+00 3.84E+01 4.12E+01 LLD 4.08E+00 5.28E+00 9.53E+00 5.32E+00 6.22E+00 7.30E+00 5.59E+00 1.40E+01 3.50E+00 4.78E+00 1.32E+01 4.88E+01 3.54E+01 Nuclide Activity H3SW 9.99E+03 1 Sigma Error LLD 1.42E+02 1.58E+02 Nuclide Mn-54 Co-58 Fe-59 C0-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 Activity

<5.52E+00

<5.03E+00

<1.05E+01

<1.00E+01

<1.12E+01

<7.29E+00

<6.05E+00

<1.43E+01

<3.91E+00

<5.88E+00

<1.42E+01

<5.29E+01 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 LLD 5.52E+00 5.03E+00 1.05E+01 1.00E+01 1.12E+01 7.29E+00 6.05E+00 1.43E+01 3.91E+00 5.88E+00 1.42E+01 5.29E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report -Appendix E EnRad Laboratories Enl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 59 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SURFACE WATER Concentration (Activity): pCi/i Sample Point 208 [ INDICATOR - S @ 0.45 miles ]

Sample ID:

269861 Sample ID:

272647 Sample ID:

274971 Sample ID:

277096 Sample ID:

279117 Sample Dates: 8120/2013 -911712013 Sample Dates: 9117/2013 - 10115/2013 Sample Dates: 1011512013-1111212013 Sample Dates: 812012013 - 1211012013 Sample Dates: 11/12/2013 -1211012013 Nuclide Activity 1 Sigma Error K-40

<7.86E+01 0.00E+00 Nuclide Activity I Sigma Error Mn-54

<1.96E+00 0.00E+00 Co-58

<2.54E+00 0.00E+00 Fe-59

<4.68E+00 0.00E+00 Co-60

<3.63E+00 O.OOE+00 Zn-65

<3.83E+00 0.00E+00 Zr-95

<3.65E+00 0.00E+00 Nb-95

<2.98E+00 0.00E+00 1-131

<8.35E+00 0.002+00 Cs-134

<2.11E+00 0.00E+00 Cs-137

<2.56E+00 0.OOE+00 BaLa-140

<3.47E+00 0.00E+00 Be-7

<2.33E+01 0.00E+00 K-40 9.36E+01 1.29E+01 Nuclide Activity I Sigma Error Mn-54

<3.72E+00 0.OOE+00 Co-58

<4.34E+00 0.00E+00 Fe-59

<9.11 E+00 0.00E+00 Co-60

<3.04E+00 0.00E+00 Zn-65

<6.80E+00 0.0OE+00 Zr-95

<6.16E+00 0.00E+00 Nb-95

<5.31E+00 O.OOE+O0 1-131

<1.42E+01 O.OOE+00 Cs-134

<3.56E+00 0.00E+00 Cs-137

<4.32E+00 0.00E+00 BaLa-140

<6.OOE+00 0.00E+00 Be-7

<4.05E+01 0.00E+00 K-40 2.06E+02 2.16E+01 Nuclide Activity 1 Sigma Error H3SW 1.48E+04 1.91E+02 Nuclide Activity I Sigma Error Mn-54

<3.83E+00 0.00E+00 Co-58

<4.01E+00 0.00E+00 Fe-59

<7.77E+00 0.00E+00 Co-60

<5.23E+00 0.00E+00 Zn-65

<8.14E+00 0.00E+00 Zr-95

<6.35E+00 0.00E+00 Nb-95

<4.67E+00 O.OOE+00 1-131

<1.20E+01 0.00E+00 Cs-134

<3.23E+00 0.00E+00 Cs-137

<4.18E+00 0.OOE+00 BaLa-140

<1.37E+01 0.00E+00 Se-7

<3.82E+01 0.00E+00 K-40 7.14E+01 1.40E+01 LLD 7.86E+01 LLD 1.96E+00 2.54E+00 4.68E+00 3.63E+00 3.83E+00 3.65E+00 2.98E+00 8.35E+00 2.11E+00 2.56E+00 3.47E+00 2.33E+01 1.87E+01 LLD 3.72E+00 4.34E+00 9.11E+00 3.04E+00 6.80E+00 6.16E+00 5.31E+00 1.42E+01 3.56E+00 4.32E+00 6.00E+00 4.05E+01 3.32E+01 LLD 2.41E+02 LLD 3.83E+00 4.01E+00 7.77E+00 5.23E+00 8.14E+00 6.35E+00 4.67E+00 1.20E+01 3.23E+00 4.18E+00 1.37E+01 3.82E+01 3.88E+01 Sample Point 211 [ INDICATOR - ESE @ 4.06 miles ]

Sample ID:

260620 Sample ID:

251671 Sample Dates: 12/1112012-1/812013 Sample Dates: 118/2013 -21/512013 Nuclide Activity 1 Sigma Error Mn-54

<4.23E+00 0.00E+00 Co-58

<5.60E+00 0.00E+00 Fe-59

<1.00E+01 0.00E+00 Co-60

<5.97E+00 0.00E+00 Zn-65

<8.02E+00 0.00E+00 Zr-95

<8.33E+00 0.00E+00 Nb-95

<6.66E+00 0.00E+00 1-131

<1.39E+01 0.OOE+00 Cs-134

<3.37E+00 0.00E+00 Cs-137

<5.05E+00 0.00E+00 BaLa-140

<8.98E+00 0.00E+00 Se-7

<3.47E+01 0.00E+00 K-40 1.28E+02 2.00E+01 Nuclide Activity 1 Sigma Error Mn-54

<4.25E+00 0.00E+00 Co-58

<4.05E+00 0.OOE+00 LLD 4.23E+00 5.60E+00 1.00E+01 5.97E+00 8.02E+00 8.33E+00 6.66E+00 1.39E+01 3.37E+00 5.05E+00 8.98E+00 3.47E+01 4.93E+01 LLD 4.25E+00 4.05E+00 06 6

0 0

o Appendix E - Page 60 of 80 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories E fl 13339 Hagers Ferry Road Huntersville, North Carolina 28078

0 CATAWBA Radiological Environmental Monitoring Analysis Report -2013 (Appendix E)

Media Type: SURFACE WATER Concentration (Activity): pCill Sample Point 211 [INDICATOR - ESE @ 4.06 miles I Sample ID:

251671 0

0 0

0

~

Sample ID:

253087 S

Sample ID:

253942 0

0 0

S S

Sample ID:

255941 0

0 0

O Sample ID:

257194 00 0

0 Sample ID:

258170 Sampie ID:

258322 0

0 Sample Dates: 118/2013 - 21512013 Sample Dates: 12111/2012-31512013 Sample Dates: 215/2013 - 3/512013 Sample Dates: 315/2013 -4/212013 Sample Dates: 4/212013.4/3012013 Sample Dates: 3/5/2013 - 5/2912013 Sample Dates: 4/3012013 - 512912013 Nuclide Activity Fe-59

<i.OOE+01 Co-60

<5.06E+00 Zn-65

<9.21E+00 Zr-95

<6.96E+00 Nb-95

<5.79E+00 1-131

<1.25E+01 Cs-134

<3.49E+00 Cs-137

<4.34E+00 BaLa-140

<1.09E+01 Be-7

<3.69E+01 K-40

<6.07E+01 Nuclide Activity H3SW 9.23E+02 Nucilde Activity Mn-54

<3.78E+00 Co-58

<4.48E+00 Fe-59

<9.58E+00 Co-60

<5.26E+00 Zn-65

<8.24E+00 Zr-95

<7.05E+00 Nb-95

<4.40E+00 1-131

<1.28E+01 Cs-134

<3.92E+00 Cs-137

<3.96E+00 BaLa-140

<1.02E+01 Be-7

<3.83E+01 K-40 6.91E+01 Nuclide Activity Mn-54

<3.95E+00 Co-58

<3.93E+00 Fe-59

<8.32E+00 Co-60

<4.40E+00 Zn-65

<8.40E+00 Zr-95

<8.19E+00 Nb-95

<4.79E+00 1-131

<1.30E+01 Cs-134

<3.55E+00 Cs-137

<4.13E+00 BaLa-140

<9.25E+00 Be-7

<4.02E+01 K-40 1.45E+02 Nuclide Activity Mn-54

<2.96E+00 Co-58

<5.37E+00 Fe-59

<1.07E+01 Co-60

<6.71E+00 Zn-65

<1.08E+01 Zr-95

<1.20E+01 Nb-95

<6.34E+00 1-131

<1.22E+01 Cs-134

<4.05E+00 Cs-137

<6.16E+00 BaLa-140

<1.40E+01 Be-7

<4.56E+01 K-40 8.30E+01 Nuclide Activity H3SW 6.02E+02 Nuclide Activity Mn-54

<5.58E+00 Co-58

<4.61E+00 Fe-59

<9.00E+00 Co-60

<8.80E+00 Zn-65

<9.73E+00 Zr-95

<9.51E+00 I Sigma Error 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 O.00E+O0 0.OOE+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1 Sigma Error 6.52E+01 1 Sigma Error 0.OOE+00 O.OOE+00 O.OOE+00 O.OOE+O0 0.OOE+00 0.OOE+00 O.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+OO 11.89E+01 1 Sigma Error 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.34E+01 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.34E+01 LLD 1.00E+01 5.06E+00 9.21E+00 6.96E+00 5.79E+00 1.25E+01 3.49E+00 4.34E+00 1.09E+01 3.69E+01 6.07E+01 LLD 1.65E+02 LLD 3.78E+00 4.48E+00 9.581+00 5.26E+00 8.24E+00 7.05E+00 4.40E+00 1.28E+01 3.92E+00 3.96E+00 1.02E+01 3.83E+01 4.32E+O1 LLD 3.95E+00 3.93E+00 8.32E+00 4.40E+00 8.40E+00 8.19E+00 4.79E+00 1.30E+01 3.55E+00 4.13E+00 9.25E+00 4.02E+01 3.46E+01 LLD 2.96E+00 5.37E+00 1.07E+01 6.71E+00 1.08E+01 1.20E+01 6.34E+00 1.22E+01 4.05E+00 6.16E+00 1.40E+01 4.56E+01 3.28E+01 1 Sigma Error LLD 6.39E+01 1.77E+02 1 Sigma Error 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 LLD 5.58E+00 4.61E+00 9.00E+00 8.80E+00 9.73E+00 9.51E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En I* 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 61 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SURFACE WATER Concentration (Activity): pCill Sample Point 211 [INDICATOR - ESE @ 4.06 miles ]

0 0

Sample ID:

258322 Sample ID:

260426 Sample ID:

263222 Sample ID:

266733 Sample Dates: 4/3012013.512912013 Sample Dates: 512912013 - 612512013 Sample Dates: 612512013 -712312013 Sample Dates: 7/2312013 - 8120/2013 Nuclide Activity 1 Sigma Error Nb-95

<6.48E+00 0.00E+00 1-131

<1.43E+01 0.00E+00 Cs-134

<4.00E+00 0.00E+00 Cs-137

<4.02E+00 0.00E+00 BaLa-140

<7.82E+00 0.00E+00 Be-7

<3.35E+01 0.00E+00 K-40

<6.78E+01 0.00E+00 Nuclide Activity 1 Sigma Error Mn-54

<5.12E+00 0,00E+00 Co-58

<5.42E+00 0.OOE+00 Fe-59

<9.42E+00 0.00E+00 Co-60

<6.57E+00 0.OOE+00 Zn-65

<9.56E+00 0.OOE+00 Zr-95

<1.06E+01 0.00E+00 Nb-95

<5.13E+00 0.OOE+00 1-131

<1.37E+01 0.00E+00 Cs-134

<3.20E+00 O.OOE+00 Cs-137

<5.38E+00 0.00E+00 BaLa-140

<1.23E+01 0.00E+00 Be-7

<4.07E+01 0.OOE+00 K-40 5.24E+01 2.62E+01 Nuclide Activity 1 Sigma Error Mn-54

<3.54E+00 0.00E+00 Co-58

<4.51E+00 0.00E+00 Fe-59

<1.15E+01 0.00E+00 Co-60

<5.80E+00 0.00E+00 Zn-65

<7.55E+00 0.00E+00 Zr-95

<6.46E+00 O.OOE+00 Nb-95

<5.04E+00 0.00E+00 1-131

<1.39E+01 0.00E+00 Cs-134

<3.42E+00 0.00E+00 Cs-137

<4.15E+00 0.OOE+00 BaLa-140

<9.92E+00 0.00E+00 Be-7

<3.74E+01 0.00E+00 K-40 1.18E+02 2.13E+01 Nuclide Activity 1 Sigma Error Mn-54

<3.20E+00 0.00E+00 Co-58

<3.52E+00 0.00E+00 Fe-59

<7.20E+00 0.00E+00 Co-60

<3.44E+00 0.00E+00 Zn-65

<6.73E+00 O.00E+00 Zr-95

<5.77E+00 0.00E+00 Nb-95

<3.41E+00 0.00E+00 1-131

<1.10E+01 0.00E+00 Cs-134

<3.00E+00 0.00E+00 Cs-137

<3.41E+00 O.OOE+00 BaLa-140

<7.53E+00 0.00E+00 Be-7

<2.64E+01 0.OOE+00 K-40 6,36E+01 1.68E+01 Nuclide Activity I Sigma Error H3SW 3.08E+02 5.31 E+01 Nuclide Activity 1 Sigma Error Mn-54

<3.97E+00 0.OOE+00 Co-58

<3.35E+00 0.00E+00 Fe-59

<9.64E+00 0.00E+00 Co-60

<4.58E+00 0.00E+00 Zn-65

<8.77E+00 0.00E+00 Zr-95

<6.08E+00 0.00E+00 Nb-95

<5.09E+00 0.00E+00 1-131

<1.29E+01 0.00E+00 Cs-134

<3.50E+00 0.00E+00 Cs-137

<4.32E+00 0.00E+00 BaLa-140

<9.14E+00 0.OOE+00 Be-7

<3.95E+01 0.OOE+00 LLD 6.48E+00 1.43E+01 4.00E+00 4.02E+00 7.82E+00 3.35E+01 6.78E+01 LLD 5.12E2-00 5.42E+00 9.42E+00 6.57E+00 9.56E+00 1.06E+01 5.13E+00 1.37E+01 3.20E+00 5.38E+00 1.23E+01 4.07E+01 6.11E+01 LLD 3.54E+00 4.51E+00 1.15E+01 5.80E+00 7.55E+00 6.46E+00 5.04E+00 1.39E+01 3.42E+00 4.15E+00 9.92E+00 3.74E+01 4.96E+01 LLD 3.20E+00 3.52E+00 7.20E+00 3.44E+00 6.73E+00 5.77E+00 3.41E+00 1.10E+01 3.00E+00 3.41E+00 7.53E+00 2.64E+01 2.43E+01 LLD 1.57E+02 LLD 3.97E+00 3.35E+00 9.64E+00 4.58E+00 8.77E+00 6.08E+00 5.09E+00 1.29E+01 3.50E+00 4.32E+00 9.14E+00 3.95E+01 0

0 0

0 S

0 Apenix2Pae 2 of8 S

0 0

Sample ID:

267114 Sample ID:

269852 Sample Dates: 5/29/2013 - 8/2012013 Sample Dates: 8/20/2013 -9/1712013 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EnR 13339 Hagers Ferry Road Huntersville, North Carolina 28078

0 0

S 0

0 0

S 0

0 0

0 S

0 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SURFACE WATER Concentration (Activity): pC/Ii Sample Point 211 [ INDICATOR - ESE @ 4.06 miles ]

Sample ID:

269852 Sample ID:

272648 Sample ID:

274972 Sample ID:

277096 Sample ID:

279118 Sample Dates: 812012013 -911712013 Sample Dates: 911712013 -1011512013 Sample Dates: 10/1612013-1111212013 Sample Dates: 812012013 - 1211012013 Sample Dates: 11112/2013 - 12/1012013 Nuclide Activity K-40 9.31E+01 1 Sigma Error LLD 2.70E+01 4.13E+01 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nucilde Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Activity

<5.81E+00

<3.58E+00

<6.46E+00

<5.03E+00

<6.26E+00

<7.48E+00

<3.76E+00

<1.36E+01

<3.86E+00

<4.69E+00

<7.52E+00

<3.56E+01 1.OOE+02 Activity

<3.17E+00

<3.58E+00

<8.78E+00

<4.85E+O0

<7.54E+00

<7.37E+00

<4.23E+00

<1.41E+01

<3.56E+00

<4.16E+00

<1.06E+01

<3.60E+01 3.34E+01 1 Sigma Error 0.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.OOE+00 O.OOE+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 1.89E+01 1 Sigma Error 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.OOE+00 O.OOE+00 0.00E+00 0.00+E00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 1.41 E+01 LLD 5.81 E+00 3.58E+00 6.46E+00 5.03E+00 6.26E+00 7.48E+00 3.76E+00 1.36E+01 3.86E+00 4.69E+00 7.52E+00 3.56E+01 3.08E+01 LLD 3.17E+00 3.58E+00 8.78E+00 4.85E+00 7.54E+00 7.37E+00 4.23E+00 1.41E+01 3.56E+00 4.16E+00 1.06E+01 3.60E+01 4.44E+01 Nuclide Activity 1 Sigma Error LLD H3SW 6.49E+02 8.23E+01 2.42E+02 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Activity

<4.04E+00

<4.03E+00

<8.45E+00

<4.50E+00

<8.29E+00

<6.86E+00

<4.57E+00

<1.36E+01

<3.57E+00

<3.80E+00

<6.65E+00

<3.92E+01 2.04E+02 1 Sigma Error 0.OOE+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 2.65E+01 LLD 4.04E+00 4,03E+00 8.45E+00 4.50E+00 8.29E+00 6.86E+00 4.57E+00 1.36E+01 3.57E+00 3.80E+00 6.65E+00 3.92E+01 4.04E+01 Sample Point 215 [ CONTROL - NNE @ 4.21 miles ]

Sample ID:

250621 Sample ID:

251672 Sample Dates: 12/11/2012-118/2013 Sample Dates: 11812013 - 21512013 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Activity

<4.07E+00

<4.14E+00

<1.03E+01

<5.06E+00

<8.95E+00

<8.04E+00

<5.99E+00

<1.34E+01

<3.40E+00

<4.33E+00

<1.12E+01

<3.40E+01 7.17E+01 Activity

<4.50E+00

<4.91E+00 1 Sigma Error 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.93E+01 I Sigma Error 0.00E+00 0.00E+00 LLD 4.07E+00 4.14E+00 1.03E+01 5.06E+00 8.95E+00 8.04E+00 5.99E+00 1.34E+01 3.40E+00 4.33E+00 1.12E+01 3.40E+01 3.72E+01 LLD 4.50E+00 4.91E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories In 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 63 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E) 0 Media Type: SURFACE WATER Concentration (Activity): pCill Sample Point 215 [ CONTROL - NNE @ 4.21 miles ]

Sample ID:

251672 Sample Dates: 11812013-21512013 Nucilde Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Activity

<1.11E+01

<5.59E+00

<1.30E+01

<8.38E+00

<6.30E+00

<1.39E+01

<2.65E+00

<4.67E+00

<1.40E+01

<4.14E+01 8.14E+01 1 Sigma Error 0.00E+00 0.OOE+00 O.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 0.00E+00 1.82E+01 LLD 1.11E+01 5.59E+00 1.30E+01 8.38E+00 6.30E+00 1.39E+01 2.65E+00 4.67E+00 1.40E+01 4.14E+01 4.33E+01 Sample ID:

253088 Sample ID:

253943 Sample ID:

255942 Sample ID:

257195 Sample Dates: 12/1112012 -3/512013 Sample Dates: 2/512013 - 31512013 Sample Dates: 31512013 -41212013 Sample Dates: 4/2/2013.4/3012013 Nuclide Activity H3SW 5.68E+02 I Sigma Error LLD 5.96E+01 1.64E+02 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Activity

<5.26E+00

<5.41E+00

<1.10E+01

<6.28E+00

<1.01E+01

<8.79E+00

<5.28E+00

<1.38E+01

<4.67E+00

<5.63E+00

<8.53E+00

<4.29E+01 1.13E+02 Activity

<4.20E+00

<4.93E+00

<1.01E+01

<5.84E+00

<7.35E+00

<8.OOE+00

<3.65E+00

<1.29E+01

<3.66E+00

<3.55E+00

<1.12E+01

<3.61E+01 6.64E+01 Activity

<4.39E+00

<4.64E+00

<9.96E+00

<5.60E+00

<8.24E+00

<8.92E+00

<4.97E+00

<1.43E+01

<4.39E+00

<4.49E+00

<1.38E+01

<3.83E+01 1.60E+02 1 Sigma Error O.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.96E+01 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.O0E+00 2.19E+01 1 Sigma Error O.00E+00 0.00E+00 0.O0E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.70E+01 1 Sigma Error 6.19E+01 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LLD 5.26E+00 5.41E+00 1.10E+01 6.28E+00 11.01E+01 8.79E+00 5.28E+00 1.38E+01 4.67E+00 5.63E+00 8.53E+00 4.29E+01 4.44E+01 LLD 4.20E+00 4.93E+00 1.01E+01 5.84E+00 7.35E+00 8.00E+00 3.65E+00 1.29E+01 3.66E+00 3.55E+00 1.12E+01 3.61E+01 4.72E+01 LLD 4.39E+00 4.64E+00 9.96E+00 5.60E+00 8.24E+00 8.92E+00 4.97E+00 1,43E+01 4.39E+00 4.49E+00 1.38E+01 3.83E+01 4.81E+01 LLD 1.77E+02 LLD 2.96E+00 3.99E+00 9.31E+00 5.04E+00 8.09E+00 6.91E+00 00 0

S S

0 0

S 0

0 0

Sample ID:

258171 Sample ID:

258323 Sample Dates: 3/6/2013 -5129/2013 Sample Dates: 413012013 -512912013 Nuclide Activity H3SW 4.78E+02 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Activity

<2.96E+00

<3.99E+00

<9.31E+00

<5.04E+00

<8.09E+00

<6.91E+00 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories El a 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 64 of 80

0 CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: SURFACE WATER Concentration (Activity): pCill S

Sample Point 215 [ CONTROL - NNE @ 4.21 miles ]

Sample ID:

258323 0

0 Sample ID:

260426 0

0 S

Sample ID:

263224 0

0 0

0 S

Sample ID:

266735 0

0 0

0 O

Sample ID:

267115 Sample ID:

269863 0

Sample Dates: 4/3012013. 512912013 Sample Dates: 612912013 -612512013 Sample Dates: 612612013 -712312013 Sample Dates: 7/2312013 - 812012013 Sample Dates: 5/29/2013 - 812012013 Sample Dates: 8120/2013 - 911712013 Nuclide Activity 1 Sigma Error Nb-95

<4.43E+00 0.00E+00 1-131

<1.42E+01 0.00E+00 Cs-134

<3.26E+00 O.OOE+00 Cs-137

<4.46E+00 O.OOE+00 BaLa-140

<9.41E+00 0.00E+00 Be-7

<3.86E+01 O.OOE+00 K-40 1.22E+02 1.92E+01 Nuclide Activity 1 Sigma Error Mn-54

<4.13E+00 0.006+00 C0-58

<4.68E+00 O.OOE+00 Fe-59

<8.29E+00 0.00E+00 Co-60

<4.14E+00 0.00E+00 Zn-65

<8.48E+O0 O.OOE+00 Zr-95

<9.76E+00 0.00E+00 Nb-95

<5.12E+00 0.00E+00 1-131

<1.44E+01 0.00+E00 Cs-134

<3.30E+00 0.00-E+00 Cs-1 37

<4.05E+00 O.OOE+00 BaLa-140

<1.19E+01 0.00E+00 Be-7

<4.22E+01 0.OOE+O0 K-40 1.79E+02 2.74E+01 Nuclide Activity I Sigma Error Mn-54

<3.27E+00 0.00E+00 Co-58

<3.70E+00 0.00E+00 Fe-59

<1.11E+01 0.00E+00 Co-60

<5.71E+00 0.00E+00 Zn-65

<8.16E+00 0.00E+00 Zr-95

<7.72E+00 0.00E+00 Nb-95

<4.93E+00 0.00E+00 1-131

<1.45E+01 O.00E+00 Cs-134

<3.45E+00 0.OOE+00 Cs-137

<2.76E+00 0.OOE+00 BaLa-140

<8.05E+00 0.00E+00 Be-7

<3.37E+01 0.00E+00 K-40 6.89E+01 1.77E+01 Nuclide Activity 1 Sigma Error Mn-54

<5.08E+00 0.00E+00 Co-58

<5.88E+00 0.00E+00 Fe-59

<1.16E+01 0.OOE+00 Co-60

<5.87E+00 0.00E+00 Zn-65

<9.06E+00 0.00E+00 Zr-95

<9.29E+00 0.00E+00 Nb-95

<6.57E+00 0.OOE+00 1-131

<1.45E+01 0.OOE+00 Cs-134

<4.05E+00 0.00E+00 Cs-137

<5.92E+00 0.OOE+O0 BaLa-140

<1.12E+01 0.OOE+00 Be-7

<4.36E+01 0.00E+00 K,40 1,78E+02 3.24E+01 Nuclide Activity 1 Sigma Error H3SW 1.59E+02 5.08E+01 Nuclide Activity 1 Sigma Error Mn-54

<3.75E+00 0.OOE+00 Co-58

<3.64E+00 0.OOE+00 Fe-59

<9.03E+00 O.OOE+00 Co-60

':3.17E+00 0.00E+00 Zn-65

<8.57E+00 0.00E+00 Zr-95

<8.33E+00 0.00+E00 Nb-95

<5.25E+00 0.00E+00 1-131

<1.41E+01 O.OOE+00 Cs-134

<3.53E+00 0.006+00 Cs-137

<4.09E+00 0.00E+00 BaLa-140

<1.02E+01 O.00E+00 Be-7

<3.38E+01 0.00E+00 LLD 4.43E+00 1.42E+01 3.26E+00 4.46E+00 9.41E+00 3.86E+01 3.17E+01 LLD 4.13E+00 4.68E+00 8.29E+00 4.14E+00 8.48E+00 9.76E+00 5.12E+00 1.44E+01 3.30E+00 4.05E+00 1.19E+01 4.22E+01 4.42E+01 LLD 3.27E+00 3.70E+00 1.11E+01 5.71E+00 8.16E+00 7.72E+00 4.93E+00 1.45E+01 3.45E+00 2.76E+00 8.05E+00 3.37E+01 2.43E+01 LLD 5.08E+00 5.88E+00 1.16E+01 5.87E+00 9.06E+00 9.29E+00 6.57E+00 1.45E+01 4.05E+00 5.92E+00 1.12E+01 4.36E+01 3.61E+01 LLD 1.58E+02 LLD 3.75E+00 3.64E+00 9.03E+00 3.17E+00 8.57E+00 8.33E+00 5.25E+00 1.41E+01 3.53E+00 4.09E+00 1.02E+01 3.38E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EN1i~ 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 65 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media lType: SURFACE WATER Concentration (Activity): pCill Sample Point 215 [ CONTROL - NNE @ 4.21 miles I Sample ID:

269853 Sample ID:

272551 Sample ID:

274974 Sample Dates: 812012013 -911712013 Sample Dates: 911712013 - 1011612013 Sample Dates: 1011612013 -1111212013 Nuclide Activity K-40 2.06E+02 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-1 34 Cs-137 BaLa-140 Be-7 K-40 Activity

<4.42E+00

<4.62E+00

<1.11E+01

<4.70E+00

<9.46E+00

<8.52E+00

<6.30E+00

<1.42E+01

<3.80E+00

<4.84E+00

<9.26E+00

<3.72E+01 6.28E+01 Activity

<2.41E+00

<2.80E+00

<7.96E+00

<4.40E+00

<8.63E+00

<6.18E+00

<3.94E+00

<1.07E+01

<2.80E+00

<3.61 E+00

<9.59E+00

<3.24E+01 9.42E+01 1 Sigma Error 2.68E+01 I Sigma Error O.OOE+00 O.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.OOE+00 O.OOE+00 0.00E+00 1.92E+01 I Sigma Error 0.00E+00 0.00E+00 0.OOE+00 0.OOE+00 O.00E+00 O.OOE+00 0.OOE+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 1.44E+01 LLD 2.93E+01 LLD 4.42E+00 4.62E+00 1.11E+01 4.70E+00 9.46E+00 8.52E+00 6.30E+00 1.42E+01 3.80E+00 4.84E+00 9.26E+00 3.72E+01 4.87E+01 LLD 2.41E+00 2.80E+00 7.96E+00 4.40E+00 8.63E+00 6.18E+00 3.94E+00 1.07E+01 2.80E+00 3.61E+00 9.59E+00 3.24E+01 3.40E+01 Sample ID:

277097 Sample ID:

279119 Sample Dates: 812012013 - 1211012013 Sample Dates: 11112/2013 -12110/2013 Nuclide Activity H3SW

<1.532+01 i Sigma Error LLD 0.00E+00 2.43E+02 Nuclide Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-95 Nb-95 1-131 Cs-134 Cs-137 BaLa-140 Be-7 K-40 Activity

<2.49E+00

<2.56E+00

<6.75E+00

<3.69E+00

<5.85E+00

<5.09E+00

<3.44E+00

<8.76E+00

<2.23E+00

<2.78E+00

<7.83E+00

<2.77E+01 1.07E+02 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 1.62E+01 LLD 2.49E+00 2.56E+00 6.75E+00 3.69E+00 5.85E+00 5.09E+00 3.44E+00 8.76E+00 2.23E+00 2.78E+00 7.83E+00 2.77E+01 1.90E+01 06 6

6 6

0 0

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

TLD RING TLDINNER Sample ID:

254474 Sample Dates: 12/12/2012 -3/21/2013 Nuclide Activity mR/Std Qtr 20.2 Sample ID:

259343 Sample Dates: 3/2112013 - 6120/2013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

269017 Sample Dates: 6120/2013 - 9/19/2013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279296 Sample Dates: 911912013 - 12119/2013 Nuclide Activity mR-Std Qtr 16.0 Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

TLD RING TLDINNER Sample ID:

254478 Sample Dates: 12/1212012 - 3121/2013 Nuclide Activity mR/Std Qtr 19.3 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories

[fl* 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 66 of 80 0

0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 201 [ INDICATOR - NE @ 0.53 miles ]

TLD RING TLDINNER 0

0 0

S 0

0 0

Sample ID:

259344 Sample Dates: 3/21/2013-612012013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

269018 Sample Dates: 6/2012013 - 9/19/2013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279297 Sample Dates: 911912013-1211912013 Nuclide Activity mR/Std Qtr 17.0 Sample Point 203 [ INDICATOR - ESE @ 0.38 miles ]

TLD RING TLDJINNER Sample ID:

254476 Sample Dates: 12112/2012 - 312112013 Nuclide Activity mR/Std Qtr 20.2 Sample ID:

259345 Sample Dates: 312112013 -612012013 Nuclide Activity mRIStd Qtr 20.0 Sample ID:

269019 Sample Dates: 6120/2013 - 9/1912013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

279298 Sample Dates: 9119/2013 - 1211912013 Nuclide Activity mRJStd Qtr 19.0 Sample Point 204 [ INDICATOR - SSW @ 0.48 miles ]

TLD RING TLD_INNER Sample ID:

254477 Sample Dates: 12112/2012 - 312112013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

259346 Sample Dates: 312112013 -612012013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

269020 Sample Dates: 612012013 - 911912013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279299 Sample Dates: 911912013 - 12/1912013 Nuclide Activity mR/Std Qtr 15.0 Sample Point 205 [ INDICATOR - SW @ 0.25 miles ]

TLD RING TLDINNER Sample ID:

254478 Sample Dates: 12/12/2012 - 3/21/2013 Nuclide Activity mRJStd Qtr 21.1 Sample ID:

259347 Sample Dates: 312112013 -6/2012013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

269021 Sample Dates: 6120/2013 - 9/1912013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

279300 Sample Dates: 9/1912013 - 1211912013 Nuclide Activity mR/Std Qtr 18.0 Sample Point 206 [ INDICATOR - WNW @ 0.67 miles ]

TLD RING TLDINNER Sample ID:

264479 Sample Dates: 1211212012. 312112013 Nuclide Activity mR/Std Qtr 22.1 Sample ID:

259348 Sample Dates: 3121/2013 -6120/2013 Nuclide Activity mR/Std Qtr 24.0 Sample ID:

269022 Sample Dates: 6/20/2013 - 911912013 Nuclide Activity mR/Std Qtr 22.0 Sample ID:

279301 Sample Dates: 9/19/2013 -12/19/2013 Nuclide Activity mR/Std Qtr 20.0 Sample Point 207 [ INDICATOR - NNW @ 0.95 miles ]

TLD RING TLD_INNER Sample ID:

254480 Sample Dates: 12112/2012 - 3121/2013 Nuclide Activity mR/Std Qtr 23.0 Sample ID:

259349 Sample Dates: 312112013 - 6/2012013 Nuclide Activity mR/Std Qtr 23.0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 67 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 207 [ INDICATOR - NNW @ 0.95 miles I TLD RING TLDINNER Sample ID:

269023 Sample Dates: 612012013.911912013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

279302 Sample Dates: 9119/2013 -1211912013 Nuclide Activity mR/Std Qtr 19.0 Sample Point 212 [ INDICATOR - E @ 3.32 miles I TLD RING TLD SPEC Sample ID:

254481 Sample Dates: 12112/2012 - 312112013 Nuclide Activity mR/Std Qtr 17.5 Sample ID:

259350 Sample Dates: 3/21/2013.612012013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

269024 Sample Dates: 6120/2013 -911912013 Nuclide Activity

.mR/Std Qtr 16.0 Sample ID:

279303 Sample Dates: 911912013 -1211912013 Nuclide Activity mR/Std Qtr 15.0 Sample Point 217 [ CONTROL - SSE @ 10.3 miles ]

TLD RING TLD CTRL Sample ID:

254482 Sample Dates: 12)12)2012 -312112013 Nuclide Activity mRJStd Qtr 12.9 Sample ID:

259351 Sample Dates: 312112013. 62012013 Nuclide Activity mR/Std Qtr 13.0 Sample ID:

269025 Sample Dates: 612012013.911912013 Nuclide Activity mR/Std Qtr 12.0 Sample ID:

279304 Sample Dates: 9)1912013-12/1912013 Nuclide Activity mR/Std Qtr 11.0 Sample Point 222 [ INDICATOR - N @ 0.7 miles ]

TLD RING TLD_INNER Sample ID:

264459 Sample Dates: 12/12/2012 -3/21/2013 Nuclide Activity mR/Std Qtr 17.5 Sample ID:

259328 Sample Dates: 3/21)2013 -6120/2013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

269002 Sample Dates: 6)20)2013 -9)19/2013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279281 Sample Dates: 9/19/2013.12119)2013 Nuclide Activity mRIStd Qtr 16.0 Sample Point 223 [ INDICATOR - E @ 0.57 miles ]

TLD RING TLOINNER Sample ID:

254460 Sample Dates: 12)12/2012 - 3/21/2013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

259329 Sample Dates: 3/21/2013 - 6/2012013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

269003 Sample Dates: 6)20)2013 -9)19/2013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

279282 Sample Dates: 9)19)2013.12)19)2013 Nuclide Activity mR/Std Qtr 20.0 Sample Point 225 [ INDICATOR - SE @ 0.68 miles ]

TLD RING TLD_INNER Sample ID:

254461 Sample Dates: 12112/2012. 3121/2013 Nuclide Activity mR/Std Qtr 20.2 Sample ID:

269330 Sample Dates: 3)21/2013 - 6)2012013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

269004 Sample Dates: 6/20)2013 -9/1912013 Nuclide Activity mR/Std Qtr 21.0 06 6

0 0

6 0

0 6

S 0

0 0

0 S

0 0

o 0

0 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E ED DI EnRad Laboratories 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 68 of 80

00 0

0 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 225 [ INDICATOR - SE @ 0.68 miles ]

TLD RING TLDINNER Sample ID:

279283 Sample Dates: 911912013 - 1211912013 Nuclide Activity mR/Std Qtr 18.0 Sample Point 226 [ INDICATOR - S @ 0.48 miles]

TLD RING TLD_INNER Sample ID:

254483 Sample Dates: 12112/2012 - 312112013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

259352 Sample Dates: 312112013 -612012013 Nuclide Activity mRPStd Qtr 19.0 Sample ID:

269026 Sample Dates: 612012013 -911912013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

279305 Sample Dates: 911912013.1211912013 Nuclide Activity mR/Std Qtr 17.0 Sample Point 227 [ INDICATOR - WSW @ 0.52 miles ]

TLD RING TLDINNER Sample ID:

254462 Sample Dates: 12112/2012-312112013 Nuclide Activity mRJStd Qtr 20.2 Sample ID:

259331 Sample Dates: 312112013 - 612012013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

269005 Sample Dates: 612012013 - 911912013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279284 Sample Dates: 9119/2013 - 12/19/2013 Nuclide Activity mR/Std Qtr 17.0 Sample Point 228 1 INDICATOR - W @ 0.61 miles ]

TLD RING TLDjNNER Sample ID:

254463 Sample Dates: 12/1212012 - 312112013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

259332 Sample Dates: 312112013 -612012013 Nuclide Activity mnRStd Qtr 18.0 Sample ID:

269006 Sample Dates: 612012013 -911912013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279285 Sample Dates: 9/19/2013 - 12119/2013 Nuclide Activity mR/Std Qtr 16.0 Sample Point 229 1 INDICATOR - NW @ 0.84 miles ]

TLD RING TLDINNER Sample ID:

254464 Sample Dates: 1211212012 -312112013 Nuclide Activity mR/Std Qtr 26.7 Sample ID:

259333 Sample Dates: 312112013-6/2012013 Nuclide Activity mRJStd Qtr 25.0 Sample ID:

269007 Sample Dates: 6120/2013 -9/19/2013 Nuclide Activity mR/Std Qtr 23.0 Sample ID:

279286 Sample Dates: 9/19/2013 -1211912013 Nuclide Activity mR/Std Qtr 22.0 Sample Point 230 [ INDICATOR - N @ 4.37 miles ]

TLD RING TLDOUTER Sample ID:

264465 Sample Dates: 12/12/2012-3/21/2013 Nuclide Activity mR/Std Qtr 13.8 Sample ID:

259334 Sample Dates: 3/21/2013 - 6/20/2013 Nuclide Activity mR/Std Qtr 14.0 Sample ID:

269008 Sample Dates: 6/2012013 - 9/19/2013 Nuclide Activity mR/Std Qtr 13.0 Sample ID:

279287 Sample Dates: 9/1912013 -12/19/2013 Nuclide Activity mR/Std Qtr 12.0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En ~

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 69 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mRPStandard Quarter Sample Point 231 [ INDICATOR - NNE @ 4.21 miles I TLD RING TLD OUTER Sample ID:

254466 Sample Dates: 12/12/2012 - 312112013 Nuclide Activity mR/Std Otr 21.1 Sample ID:

259335 Sample Dates: 312112013-612012013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

269009 Sample Dates: 6120/2013 -9/1912013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

279288 Sample Dates: 911912013 - 12119/2013 Nuclide Activity mR/Std Qtr 19.0 Sample Point 232 [ INDICATOR - NE @ 4.18 miles ]

TLD RING TLDOUTER Sample ID:

254467 Sample Dates: 12/12/2012 - 3121/2013 Nuclide Activity mR/Std Qtr 23.9 Sample ID:

259336 Sample Dates: 3/2112013 -612012013 Nuclide Activity mR/Std Qtr 24.0 Sample ID:

269010 Sample Dates: 6120/2013-911912013 Nuclide Activity mR/Std Qtr 21.0 Sample ID:

279289 Sample Dates: 911912013 -12/1912013 Nuclide Activity mR/Std Qtr 21.0 Sample Point 233 [ INDICATOR - ENE @ 3.95 miles ]

TLD RING TLDOUTER Sample ID:

254468 Sample Dates: 12/12/2012-312112013 Nuclide Activity mR/Std Qtr 17.5 Sample ID:

259337 Sample Dates: 3121/2013 -6120/2013 Nuclide Activity mRJStd Qtr 15.0 Sample ID:

269011 Sample Dates: 6/20/2013 -911912013 Nuclide Activity mR/Std Qtr 14.0 Sample ID:

279290 Sample Dates: 9/19/2013 -1211912013 Nuclide Activity mR/Std Qtr 15.0 Sample Point 234 [ INDICATOR - E @ 4.5 miles ]

TLD RING TID_OUTER Sample ID:

264469 Sample Dates: 12/12/2012-3121/2013 Nuclide Activity mR/Std Qtr 20.2 Sample ID:

259338 Sample Dates: 3/21/2013 -612012013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

269012 Sample Dates: 6120/2013 - 9119/2013 Nuclide Activity mR/Std Qtr 16.0 Sample ID:

279291 Sample Dates: 911912013-12/1912013 Nuclide Activity mR/Std Qtr 17.0 Sample Point 235 [ INDICATOR - ESE @ 4.07 miles ]

TLD RING TLDOUTER Sample ID:

254470 Sample Dates: 12/12/2012-3121/2013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

269339 Sample Dates: 3/21/2013 - 6/20/2013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

269013 Sample Dates: 6/20/2013 -9/19/2013 Nuclide Activity mR/Std Qtr 16.0 Sample ID:

279292 Sample Dates: 9/19/2013.12/1912013 Nuclide Activity mR/Std Qtr 17.0 Sample Point 236 [ INDICATOR - SE @ 4.25 miles ]

TLD RING TLDOUTER Sample ID:

264471 Sample Dates: 12/12/2012 -3/21/2013 Nuclide Activity mR/Std Qtr 23.9 II II II II II II II II II II II II 0

6 6

6 S

6 0

SI S

S S

0 0

0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Efl

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 70 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 236 [ INDICATOR - SE @ 4.25 miles ]

TLD RING TLD OUTER 0

0 0

S S

0 0

0 S

0 0

S 0

0 0

0 Sample ID:

269340 Sample Dates: 312112013-612012013 Nuclide Activity mR/Std Qtr 22.0 Sample ID:

269014 Sample Dates: 612012013 -911912013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

279293 Sample Dates: 9/1912013 -1211912013 Nuclide Activity mR/Std Qtr 22.0 Sample Point 237 [ INDICATOR - SSE @ 4.75 miles ]

TLD RING TLD.OUTER Sample ID:

254472 Sample Dates: 1211212012 -312112013 Nuclide Activity mR/Std Qtr 23.0 Sample ID:

259341 Sample Dates: 312112013 - 6120/2013 Nuclide Activity mR/Std Qtr 24.0 Sample ID:

269015 Sample Dates: 612012013 -911912013 Nuclide Activity mR/Std Qtr 21.0 Sample ID:

279294 Sample Dates: 911912013 -1211912013 Nuclide Activity mR/Std Qtr 22.0 Sample Point 238 [ INDICATOR - S @ 4.02 miles ]

TLD RING TLDOUTER Sample ID:

254473 Sample Dates: 12112/2012 - 312112013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

259342 Sample Dates: 312112013.6120/2013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

269016 Sample Dates: 6/20/2013 -9/19/2013 Nuclide Activity mR/Std Qtr 16 Sample ID:

279295 Sample Dates: 9119/2013 -1211912013 Nuclide Activity mR/Std Qtr 17.0 Sample Point 239 [ INDICATOR - SSW @ 4.49 miles ]

TLD RING TLDOUTER Sample ID:

264484 Sample Dates: 1211212012 - 312112013 Nuclide Activity mR/Std Qtr 23.0 Sample ID:

259353 Sample Dates: 312112013 - 612012013 Nuclide Activity mRJStd Qtr 19.0 Sample ID:

269027 Sample Dates: 6120/2013 - 911912013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

279306 Sample Dates: 9/19/2013 -12/19/2013 Nuclide Activity mR/Sid Qtr 20.0 Sample Point 240 [ INDICATOR - SW @ 4.07 miles ]

TLD RING TLDOUTER Sample ID:

254485 Sample Dates: 12112/2012-3121/2013 Nuclide Activity mR/Std Qtr 13.8 Sample ID:

269354 Sample Dates: 3/2112013 -6/20/2013 Nuclide Activity mR/Std Qtr 13.0 Sample ID:

269028 Sample Dates: 6/20/2013 -9/1912013 Nuclide Activity mR/Sid Qtr 12.0 Sample ID:

279307 Sample Dates: 9/19/2013 - 12/19/2013 Nuclide Activity mR/Std Qtr 12.0 Sample Point 241 [ INDICATOR - WSW @ 4.58 miles ]

TLD RING TLDOUTER Sample ID:

264486 Sample Dates: 12/12/2012*3121/2013 Nuclide Activity mR/Std Qtr 13.8 Sample ID:

259355 Sample Dates: 3/21/2013 -612012013 Nuclide Activity mR/Std Qtr 14.0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road

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CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 241 [ INDICATOR - WSW @ 4.58 miles ]

TLD RING TLDOUTER Sample ID:

269029 Sample Dates: 612012013-911912013 Nuclide Activity mR/Std Qtr 12.0 Sample ID:

279308 Sample Dates: 911912013 -1211912013 Nuclide Activity mR/Std Qtr 13.0 Sample Point 242 [ INDICATOR - W @ 4.56 miles ]

TLD RING TLDOUTER Sample ID:

254487 Sample Dates: 1211212012-312112013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

259356 Sample Dates: 3/21/2013-612012013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

269030 Sample Dates: 6/20/2013 -911912013 Nuclide Activity mR/Std Qtr 16.0 Sample ID:

279309 Sample Dates: 911912013.12/1912013 Nuclide Activity mR/Std Qtr 16.0 Sample Point 243 [ INDICATOR - WNW @ 4.39 miles ]

TLD RING TLDOUTER Sample ID:

254488 Sample Dates: 1211212012 -312112013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

259357 Sample Dates: 3121/2013-6/2012013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

269031 Sample Dates: 6120/2013.911912013 Nuclide Activity mR/Std Qtr 16.0 Sample ID:

279310 Sample Dates: 9/1912013 - 1211912013 Nuclide Activity mR/Std Qtr 16.0 Sample Point 244 [ INDICATOR - NW @ 4.02 miles ]

TLD RING TLD OUTER Sample ID:

254489 Sample Dates: 12/12/2012 - 3121/2013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

259358 Sample Dates: 312112013 -6/20/2013 Nuclide Activity mRJStd Qtr 19.0 Sample ID:

269032 Sample Dates: 6/2012013 -9/1912013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

279311 Sample Dates: 9119/2013 -12119/2013 Nuclide Activity mR/Std Qtr 19.0 Sample Point 245 [ INDICATOR - NNW @ 4.01 miles I TLD RING TLDOUTER Sample ID:

264490 Sample Dates: 12/12/2012 - 3121/2013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

259369 Sample Dates: 3121/2013 -612012013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

269033 Sample Dates: 612012013 - 911912013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279312 Sample Dates: 9/19/2013-12/1912013 Nuclide Activity mR/Std Qtr 18.0 Sample Point 246 [ INDICATOR - ENE @ 7.87 miles ]

TLD RING TLDSPEC Sample ID:

254541 Sample Dates: 12/1212012. 312112013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

259410 Sample Dates: 3/21/2013 -6/20/2013 Nuclide Activity mR/Std Qtr 16 Sample ID:

269085 Sample Dates: 6/2012013 -9/19/2013 Nuclide Activity mR/Std Qtr 14.0 00 0

6 0

0 0

0 S

S S

0 S

0 0

S 0

S S

0 S

S 0

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En

13339 Hagers Ferry Road Appendix E - Page 72 of 80

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I

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 246 [ INDICATOR - ENE @ 7.87 miles ]

TLD RING TLDSPEC 0

0 0

0 S

0 0

Sample ID:

279361 Sample Dates: 911912013 - 12/1912013 Nuclide Activity mR/Std Qtr 15.0 Sample Point 247 [ CONTROL - ESE @ 7.33 miles ]

TLD RING TLDCTRL Sample ID:

264374 Sample Dates: 1211212012-312112013 Nuclide Activity mR/Std Qtr 14.7 Sample ID:

259243 Sample Dates: 312112013 -6120/2013 Nuclide Activity mRPStd Qtr 14.0 Sample ID:

268917 Sample Dates: 6/2012013 - 911912013 Nuclide Activity mR/Std Qtr 14.0 Sample ID:

279196 Sample Dates: 911912013.1211912013 Nuclide Activity mR/Std Qtr 13.0 Sample Point 248 [ INDICATOR - S @ 6.54 miles ]

TLD RING TLD.SPEC Sample ID:

254373 Sample Dates: 1211212012 -3121/2013 Nuclide Activity mR/Std Qtr 16.5 Sample ID:

259242 Sample Dates: 3121/2013.612012013 Nuclide Activity mR/Std Qtr 15.0 Sample ID:

268916 Sample Dates: 6120/2013 - 911912013 Nuclide Activity mR/Std Qtr 14.0 Sample ID:

279195 Sample Dates: 9119/2013 - 12119(2013 Nuclide Activity mR/Std Qtr 15.0 Sample Point 249 [ INDICATOR - S @ 7.17 miles ]

TLD RING TLDSPEC Sample ID:

254376 Sample Dates: 12112/2012 - 3121/2013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

259244 Sample Dates: 3/2112013 -612012013 Nuclide Activity mR/Std Qtr 18.0 Sample ID:

268918 Sample Dates: 612012013 -9119/2013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279197 Sample Dates: 9119/2013 -12119/2013 Nuclide Activity mR/Std Qtr 18.0 Sample Point 250 [ INDICATOR - WSW @ 10.4 miles ]

TLD RING TLDSPEC Sample ID:

264378 Sample Dates: 12112/2012 - 312112013 Nuclide Activity mR/Std Qtr 18.4 Sample ID:

269247 Sample Dates: 3/2112013 - 6120/2013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

268921 Sample Dates: 6/20/2013 - 9119/2013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

279200 Sample Dates: 9/19/2013 -2119/2013 Nuclide Activity mR/Std Qtr 16.0 Sample Point 261 [ CONTROL - WNW @ 9.72 miles ]

TLD RING TLDCTRL Sample ID:

254376 Sample Dates: 12/12/2012-312112013 Nuclide Activity mR/Std Qtr 19.3 Sample ID:

259246 Sample Dates: 3/21/2013 - 612012013 Nuclide Activity mR/Std Qtr 17.0 Sample ID:

268919 Sample Dates: 6/2012013 -9119/2013 Nuclide Activity mR/Std Qtr 16.0 Sample ID:

279198 Sample Dates: 9/19/2013 -12/19/2013 Nuclide Activity mR/Std Qtr 17.0 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E In D EnRad Laboratories 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 73 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: TLD Concentration (Activity): mR/Standard Quarter Sample Point 255 [ INDICATOR - ENE @ 0.61 miles I TLD RING TLDINNER Sample ID:

254377 Sample Dates: 12112/2012 -312112013 Nuclide Activity mR/Std Qtr 22.1 Sample ID:

259246 Sample Dates: 312112013-612012013 Nuclide Activity mR/Std Qtr 21.0 Sample ID:

268920 Sample Dates: 612012013-9119/2013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

279199 Sample Dates: 911912013-1211912013 Nuclide Activity mRIStd Qtr 21.0 Sample Point 256 [ INDICATOR - SSE @ 0.58 miles ]

TLD RING TLD_INNER Sample ID:

254386 Sample Dates: 12/12/2012 - 312112013 Nuclide Activity mRIStd Qtr 22.1 Sample ID:

269255 Sample Dates: 312112013.612012013 Nuclide Activity mRIStd Qtr 22.0 Sample ID:

268929 Sample Dates: 612012013-9/19/2013 Nuclide Activity mR/Std Qtr 20.0 Sample ID:

279208 Sample Dates: 911912013-1211912013 Nuclide Activity mR/Std Qtr 21.0 Sample Point 258 [ CONTROL - W @ 9.84 miles ]

TLD RING TLDSPEC Sample ID:

254379 Sample Dates: 12/12)2012.312112013 Nuclide Activity mR/Std Qtr 22.1 Sample ID:

259248 Sample Dates: 3/21/2013 -6120/2013 Nuclide Activity mRJStd Qtr 21.0 Sample ID:

268922 Sample Dates: 6120/2013-911912013 Nuclide Activity mR/Std Qtr 19.0 Sample ID:

279201 Sample Dates: 9119/2013-12119/2013 Nuclide Activity mR/Std Qtr 20.0 Sample Point 269 [ SPECIAL - SW @ 0.38 miles I TLD RING TLD SPEC Sample ID:

254499 Sample Dates: 12/12/2012 -3121/2013 Nuclide Activity mR/Std Qtr 20.2 Sample ID:

259368 Sample Dates: 3121/2013 - 612012013 Nuclide Activity mRJStd Qtr 19.0 Sample ID:

269042 Sample Dates: 6/20/2013 - 9/19/2013 Nuclide Activity mR/Std Qtr 17.0 Media Type: VEGETATION Concentration (Activity): pCI/kg Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

249999 Sample Dates: 1/212013 - 1/212013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.23E+01 O.00E+00 2.23E+01 Cs-134

<2.30E+01 O.00E+00 2.30E+01 Cs-137

<2.18E+01 0.00E+00 2.18E+01 Be-7 9.58E+02 1.18E+02 1.64E+02 K-40 4.22E+03 2.65E+02 1.49E+02 Sample ID:

250957 Sample Dates: 2/5/2013 - 2/5/2013 Nucilde Activity I Sigma Error LLD 1-131

<2.05E+01 O.00E+00 2.05E+01 Cs-134

<1.74E+01 0.OOE+00 1.74E+01 Cs-137

<3.00E+01 O.OOE+00 3.OOE+01 Be-7 9.18E+02 1.08E+02 2.05E+02 K-40 3.65E+03 2.60E+02 2.20E+02 Sample ID:

252702 Sample Dates: 315/2013 -3/512013 Nuclide Activity 1 Sigma Error LLD 1-131

<2.53E+01 0.00E+00 2.53E+01 Cs-134

<3.37E+01 0.002+00 3,37E+01 Cs-137

<3.02E+01 0.00E+00 3.02E+01 66 6

6 6

6 0

0 6

0 0

S 6

0 6

0 0

S 0

0 0

Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories EI Ri 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 74 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: VEGETATION Concentration (Activity): pCilkg Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

O Sample ID:

252702 S

Sample ID:

255044 0

0 Sample ID:

256533 S

0 0

S ample ID:

257932 S

S Sample ID:

259625 0

0 S

Sample ID:

262855 S

0 0

Sample ID:

266432 S

0 Sample ID:

269592 0S Sample ID:

272540 S

S 0

S Sample ID:

274046 0

0 S

Sample ID:

275282 S

0 Sample Dates: 315/2013 - 315/2013 Sample Dates: 4/2/2013 -4/212013 Sample Dates: 5/7/2013 -51712013 Sample Dates: 61412013 - 6/4/2013 Sample Dates: 7/2/2013 -71212013 Sample Dates: 816/2013.8/612013 Sample Dates: 914/2013 -91412013 Sample Dates: 1011/2013 - 101112013 Sample Dates: 11/512013 -11/512013 Sample Dates: 10/22/2013 - 1012212013 Sample Dates: 1213/2013 -1213/2013 Nuclide Activity I Sigma Error LLD Be-7 8.82E+02 1.23E+02 1.77E+02 K-40 4.36E+03 3.17E+02 3.09E+02 Nuclide Activity I Sigma Error LLD 1-131

<1.94E+01 0.OOE+00 1.94E+01 Cs-134

<1.82E+01 0.OOE+00 1.82E+01 Cs-137

<2.27E+01 0.O0E+00 2.27E+01 Be-7 5.89E+02 1.21E+02 1.59E+02 K-40 4.32E+03 2.63E+02 1.82E+02 Nuclide Activity i Sigma Error LLD 1-131

<1.83E+01 O.OOE+00 1.83E+01 Cs-134

<2.07E+01 0.00E+00 2.07E+01 Cs-137

<2.38E+01 0.00E+00 2.38E+01 Be-7 4.60E+02 8.77E+01 1.74E+02 K-40 4.21E+03 2.92E+02 2.33E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<3.39E+01 0.00E+00 3.39E+01 Cs-134

<3.05E+01 0.00E+00 3.05E+01 Cs-137

<3.50E+01 0.00E+00 3.50E+01 Be-7 7.60E+02 1.34E+02 2.57E+02 K-40 8.24E+03 5.13E+02 3.77E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.12E+01 0.00E+00 1.12E+01 Cs-134

<8.90E+00 O.00E+00 8.90E+00 Cs-137

<1.09E+01 0.00E+00 1.09E+01 Be-7 6.42E+02 4.94E+01 8.57E+01 K-40 4.80E+03 1.52E+02 9.60E+01 Nuclide Activity I Sigma Error LLD 1-131

<2.35E+01 O.00E+00 2.35E+01 Cs-1 34

<2.28E+01 0.00E+00 2.28E+01 Cs-137

<2.23E+01 0.002+00 2.23E+01 Be-7 5.27E+02 9.91E+01 1,68E+02 K-40 3.40E+03 2.91 E+02 2.67E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.93E+01 0.00+E00 1.93E+01 Cs-134

<1.84E+01 0.00E+00 1.84E+01 Cs-137

<2.08E+01 O.OOE+00 2.08E+01 Be-7 4.89E+02 9.51E+01 1.78E+02 K-40 4.76E+03 3.06E+02 1.92E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<2.35E+01 0.OOE+00 2.35E+01 Cs-134

<2.28E+01 0.00E+00 2.28E+01 Cs-137

<2.91E+01 0.00E+00 2.91E+01 Be-7 3.20E+02 1.20E+02 1.81E+02 K-40 4.31E+03 3.45E+02 2.88E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<3.80E+01 0.00E+00 3.80E+01 Cs-134

<4.57E+01 0.00E+00 4.57E+01 Cs-137

<4.20E+01 0.00E+00 4.20E+01 Be-7 1.02E+03 1.82E+02 4.37E+02 K-40 4.41E+03 5.42E+02 6.73E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<3.51E+01 0.00E+00 3.51E+01 Cs-134

<3.24E+01 0.00E+00 3.24E+01 Cs-137

<4.46E+01 0.00E+00 4.46E+01 Be-7 6.56E+02 1.44E+02 2.73E+02 K-40 3.93E+03 3.95E+02 1.07E+02 Nuclide Activity I Sigma Error LLD 1-131

<2.42E+01 0.00E+00 2.42E+01 Cs-134

<2.47E+01 0.00E+00 2.47E+01 Cs-137

<2.71E+01 0.00E+00 2.71E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories In 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 75 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: VEGETATION Concentration (Activity): pCi/kg Sample Point 200 [ INDICATOR - NNE @ 0.63 miles ]

Sample ID:

275262 Sample Dates: 121312013.1213/2013 Nuclide Activity 1 Sigma Error LLD Be-7 4.98E+02 1.17E+02 2.23E+02 K-40 4.52E+03 3.15E+02 2.17E+02 Sample Point 201 [INDICATOR - NE @ 0.53 miles ]

Sample ID:

280000 Sample ID:

250958 Sample ID:

252703 Sample ID:

255045 Sample ID:

256534 Sample ID:

257933 Sample ID:

259626 Sample ID:

262856 Sample ID:

266433 Sample Dates: 11212013.11212013 Sample Dates: 215/2013 -21512013 Sample Dates: 315/2013 - 3/5/2013 Sample Dates: 412/2013.4/212013 Sample Dates: 5/7/2013 -51712013 Sample Dates: 614/2013 -61412013 Sample Dates: 71212013 -7/2/2013 Sample Dates: 81612013 - 81612013 Sample Dates: 9/4/2013 -9/412013 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Activity

<2.97E+01

<3.23E+01

<3.70E+01 1.44E+03 3.94E+03 Activity

<2.61E+01

<2.81E+01

<3.52E+01 1.55E+03 5.26E+03 Activity

<2.85E+01

<2.47E+01

<3.20E+01 1.15E+03 6.00E+03 Activity

<2.18E+01

<2.48E+01

<3.15E+01 1.72E+03 4.56E+03 Activity

<2.57E+01

<1.91E+01

<3.00E+01 1.24E+03 3.94E+03 Activity

<2.88E+01

<2.70E+01

<4.10E+01 6.33E+02 4.25E+03 Activity

<2.28E+01

<1.95E+01

<2.47E+01 8.43E+02 4.11 E+03 Activity

<1.05E+01

<9.43E+00

<1.01E+01

<8.09E+01 1.22E+03 Activity

<3.57E+01

<2.93E+01

<4.44E+01 9.89E+02 4.18E+03 I Sigma Error 0.OOE+00 0.00E+00 0.00E+00 1.66E+02 2.94E+02 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 1.80E+02 3.41E+02 1 Sigma Error 0.00E+00 0.OOE+00 0.00E+00 1.33E+02 3.62E+02 I Sigma Error O.OOE+00 0.OOE+00 0.OOE+00 1.58E+02 3.21 E+02 1 Sigma Error 0.O0E+00 0.00E+00 0.00E+00 1.67E+02 3.61E+02 1 Sigma Error 0.00E+00 0.OOE+00 0.00E+00 1.68E+02 3.86E+02 I Sigma Error 0.00E+00 O.OOE+00 0.00E+00 9.76E+01 2.88E+02 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 O.OOE+00 1.06E+02 1 Sigma Error 0.OOE+00 0.OOE+00 O.OOE+00 1.86E+02 3.91 E+02 I Sigma Error 0.OOE+00 LLD 2.97E+01 3.23E+01 3.70E+01 2.39E+02 3.35E+02 LLD 2.61E+01 2.81E+01 3.52E+01 2.26E+02 3.03E+02 LLD 2.85E+01 2.47E+01 3.20E+01 2.16E+02 2.64E+02 LLD 2.18E+01 2.48E+01 3.15E+01 1.68E+02 2.06E+02 LLD 2.57E+01 1.91E+01 3.OOE+01 2.70E+02 3.46E+02 LLD 2.88E+01 2.70E+01 4.10E+01 2.70E+02 4.20E+02 LLD 2.28E+01 1.95E+01 2.47E+01 1.64E+02 1.99E+02 LLD 1.05E+01 9.43E+00 1.01E+01 8.09E+01 8.24E+01 LLD 3.57E+01 2.93E+01 4.44E+01 2.72E+02 3.34E+02 LLD 2.29E+01 00 6

0 6

0 0

S 0

0 0

0 S

0 0

Sample ID:

269593 Sample Dates: 101112013 - 101112013 Nuclide Activity 1-131

<2.29E+01 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories El jI 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 76 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: VEGETATION Concentration (Activity): pCi/kg Sample Point 201 [INDICATOR - NE @ 0.53 miles I 00 0

0 0

0 S

0 0

0 Sample ID:

269593 Sample ID:

272641 Sample ID:

274047 Sample ID:

275263 Sample Dates: 101112013 -101112013 Sample Dates: 11/512013-111612013 Sample Dates: 10/22)2013 -1012212013 Sample Dates: 121312013 - 121312013 Nuclide Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Activity

<2.46E+01

<3.21E+01 9.56E+02 3.09E+03 Activity

<3.53E+01

<3.37E+01

<5.97E+01 1.12E+03 3.12E+03 Activity

<2.73E+01

<2.26E+01

<3.25E+01 8.12E+02 2.44E+03 I Sigma Error 0.00E+00 0.00E+00 1.32E+02 2.77E+02 1 Sigma Error 0.00E+00 0.0OE+00 0.OOE+00 2.03E+02 4.42E+02 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 1.44E+02 2.44E+02 I Sigma Error 0.00E+00 0.00E+00 O.00E+00 1.65E+02 3.98E+02 LLD 2.46E+01 3.21E+01 1.83E+02 2.64E+02 LLD 3.53E+01 3.37E+01 5.97E+01 3.60E+02 4.59E+02 LLD 2.73E+01 2.26E+01 3.25E+01 1.64E+02 2.23E+02 LLD 3.06E+01 2.72E+01 3.41E+01 2.31E+02 4.69E+02 Nuclide Activity 1-131 Cs-134 Cs-137 Be-7 K-40

<3.06E+01

<2.72E+01

<3.41E+01 1.80E+03 4.02E+03 Sample Point 222 [ INDICATOR - N @ 0.7 miles ]

Sample ID:

250001 Sample ID:

250959 Sample ID:

252704 Sample ID:

255046 Sample ID:

256535 Sample Dates: 112/2013 - 11212013 Sample Dates: 215/2013 - 2/612013 Sample Dates: 315/2013.3/5/2013 Sample Dates: 412/2013 -4/2/2013 Sample Dates: 617/2013 -51712013 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 C:-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Activity

<1.87E+01

<1.65E+01

<2.44E+01 1.16E+03 2.85E+03 Activity

<2.35E+01

<2.26E+01

<3.06E+01 1.06E+03 3.88E+03 Activity

<5.52E+01

<5.23E+01

<7.24E+01 1.16E+03 4.12E+03 Activity

<2.74E+01

<3.49E+01

<2.86E+01 1.27E+03 4.50E+03 1 Sigma Error 0.00E+00 0.OOE+00 0.00E+00 1.08E+02 2.45E+02 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 1.16E+02 2.87E+02 1 Sigma Error 0.O0E+00 0.00E+00 0.00E+00 2.61E+02 4.82E+02 1 Sigma Error 0.00E+00 0.00E+00 0.00E+00 1.40E+02 3.25E+02 1 Sigma Error O.OOE+00 0.00E+00 0.00E+00 1.09E+02 3.03E+02 I Sigma Error 0.00E+00 0.00E+00 0.00E+00 1.25E+02 3.53E+02 LLD 1.87E+01 1.65E+01 2,44E+01 1.54E+02 2.63E+02 LLD 2.35E+01 2.26E+01 3.06E+01 1.86E+02 2.04E+02 LLD 5.52E+01 5.23E+01 7.24E+01 4.24E+02 5.89E+02 LLD 2.74E+01 3.49E+01 2.86E+01 2.46E+02 1.71E+02 LLD 2.28E+01 2.34E+01 2.44E+01 2.13E+02 2.77E+02 LLD 2.75E+01 2.37E+01 3.62E+01 2.70E+02 4.25E+02 Nuclide Activity Sample ID:

257934 Sample Dates: 61412013 - 61412013 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40

<2.28E+01

<2.34E+01

<2.44E+01 5.56E+02 4.43E+03 Activity

<2.75E+01

<2.37E+01

<3.62E+01 5.23E+02 3.20E+03 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Inl 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 77 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: VEGETATION Concentration (Activity): pCi/kg Sample Point 222 [ INDICATOR - N @ 0.7 miles ]

Sample ID:

259627 Sample ID:

262857 Sample ID:

265434 Sample ID:

269594 Sample ID:

272542 Sample ID:

275264 Sample Dates: 71212013 - 7/2/2013 Sample Dates: 816/2013 -8/612013 Sample Dates: 914/2013 -91412013 Sample Dates: 101112013 - 10/1/2013 Sample Dates: 111512013 -111512013 Sample Dates: 1213/2013.121312013 Nuclide Activity 1 Sigma Error LLD 1-131

<3.09E+01 0.O0E+00 3.09E+01 Cs-134

<3.09E+01 0.OOE+00 3.09E+01 Cs-137

<3.46E+01 0.OOE+00 3.46E+01 Be-7 7.32E+02 1.19E+02 2.34E+02 K-40 3.04E+03 3.53E+02 3.82E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.74E+01 0.00E+00 1.74E+01 Cs-134

<1.75E+01 0.00E+00 1.75E+01 Cs-137

<2.48E+01 O.OOE+O0 2.48E+01 Be-7 1.50E+03 1.15E+02 1.15E+02 K-40 2.34E+03 2.05E+02 1.92E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<3.69E+01 0.00E+00 3.69E+01 Cs-134

<3.14E+01 0.00E+00 3.14E+01 Cs-137

<4.46E+01 O.OOE+00 4.46E+01 Be-7 1.92E+03 2.32E+02 3.59E+02 K-40 3.50E+03 4.06E+02 3.80E+02 Nuclide Activity I Sigma Error LLD 1-131

<5.53E+01 0.0OE+00 5.53E+01 Cs-134

<3.85E+01 0.OOE+00 3.85E+01 Cs-137

<4.82E+01 0.00E+00 4.82E+01 Be-7 1.44E+03 2.23E+02 4.13E+02 K-40 2.85E+03 4.54E+02 5.52E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<4.96E+01 0.OOE+00 4.96E+01 Cs-134

<5.73E+01 0.00E+00 5.73E+01 Cs-137

<4.62E+01 0.00E+00 4.62E+01 Be-7 7.58E+02 2.00E+02 4.35E+02 K-40 2.57E+03 5.22E+02 9.10E+02 Nuclide Activity I Sigma Error LLD 1-131

<3.94E+01 0.00E+00 3.94E+01 Cs-134

<4.19E+01 0.00E+00 4.19E+01 Cs-137

<4.41E+01 0.00E+00 4.41E+01 Be-7 7.49E+02 1.25E+02 2.78E+02 K-40 1.97E+03 3.28E+02 4.05E+02 06 0

0 0

0 S

0 0

Sample Point 226 [ INDICATOR - S @ 0.48 miles ]

Sample ID:

250002 Sample ID:

250960 Sample ID:

252705 Sample Dates: 112/2013 -11212013 Sample Dates: 21512013 - 2/512013 Sample Dates: 315/2013 - 3/512013 Nuclide Activity I Sigma Error LLD 1-131

<2.26E+01 0.00E+00 2.26E+01 Cs-134

<2.97E+01 0.00E+00 2.97E+01 Cs-137

<3.27E+01 0.00E+00 3.27E+01 Be-7 7.78E+02 1.67E+02 2.22E+02 K-40 3.33E+03 3.15E+02 2.18E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.58E+01 0.00E+00 1.58E+01 Cs-134

<1.95E+01 O.00E+00 1.95E+01 Cs-137

<2.39E+01 0.00E+00 2.39E+01 Be-7 9.03E+02 1.05E+02 1.77E+02 K-40 3.94E+03 2.90E+02 2.10E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<3.47E+01 0.00E+00 3.47E+01 Cs-134

<3.97E+01 0.00E+00 3.97E+01 Cs-137

<3.91E+01 0.00E+00 3.91E+01 Be-7 7.49E+02 1.64E+02 2.77E+02 K-40 2.65E+03 4.31 E+02 6.44E+02 Nuclide Activity I Sigma Error LLD 1-131

<2.83E+01 0.00E+00 2.83E+01 Cs-134

<1.92E+01 0.OOE+00 1.92E+01 Cs-137

<2.18E+01 0.00E+00 2.18E+01 Be-7 7.92E+02 1.35E+02 2.17E+02 K-40 5.07E+03 3.42E+02 2.12E+02 Sample ID:

265047 Sample Dates: 4/212013-4/2/2013 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories ER-13339 Hagers Ferry Road Huntersville, North Carolina 28078 0

Appendix 2 - Page 78 of 80 0

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: VEGETATION Concentration (Activity): pCI/kg Sample Point 226 [ INDICATOR - S @ 0.48 miles I S

0 0

S 0

S S

0 0

S 0

0 S

0 0

0 Sample ID:

256536 Sample ID:

257935 Sample ID:

259628 Sample ID:

262858 Sample ID:

265435 Sample ID:

269595 Sample ID:

272543 Sample ID:

275266 Sample Dates: 617/2013 - 51712013 Sample Dates: 6/4/2013 -6/412013 Sample Dates: 712/2013-.71212013 Sample Dates: 816/2013 -81612013 Sample Dates: 91412013 - 91412013 Sample Dates: 101112013 -101112013 Sample Dates: 1115/2013 -11/512013 Sample Dates: 121312013 - 121312013 Nuclide 1-131 Cs-1 34 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-1 34 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Nuclide 1-131 Cs-134 Cs-137 Be-7 K-40 Activity

<2.84E+01

<1.82E+01

<2.41E+01 6.89E+02 3.56E+03 Activity

<2.03E+01

<1.69E+01

<2.08E+01 5.06E+02 3.63E+03 Activity

<1.59E+01

<2.09E+01

<2.58E+01 6.26E+02 3.87E+03 Activity

<1.94E+01

<1.40E+01

<2.24E+01 7.46E+02 3.52E+03 Activity

<2.66E+01

<2.02E+01

<2.98E+01 9.58E+02 4.98E+03 Activity

<2.33E+01

<1.66E+01

<2.16E+01 8.41E+02 5.64E+03 Activity

<3.62E+01

<4.05E+01

<4.56E+01 8.28E+02 4.86E+03 Activity

<4.18E+01

<3.69E+01

<4.67E+01 6.66E+02 4.08E+03 I Sigma Error 0.OOE+00 O.OOE+00 0.00E+00 1.26E+02 3.62E+02 1 Sigma Error 0.00E+00 0.OOE+00 O.00E+00 1.05E+02 2.75E+02 1 Sigma Error 0.OOE+00 0.00E+00 0.00E+00 8.94E+01 2.87E+02 I Sigma Error O.OOE+00 0.00E+00 O.OOE+00 1.29E+02 3.11E+02 1 Sigma Error O.OOE+00 0.00E+00 0.00E+00 1.22E+02 3.66E+02 I Sigma Error O.OOE+00 0.00E+00 O.OOE+00 1.08E+02 2.94E+02 I Sigma Error 0.00E+00 O.OOE+00 0.00E+00 2.08E+02 4.77E+02 1 Sigma Error O.00E+00 0.00E+00 O.00E+00 1.80E+02 4.92E+02 LLD 2.84E+01 1.82E+01 2.41E+01 2.44E+02 3.75E+02 LLD 2.03E+01 1.69E+01 2.08E+01 1.52E+02 1.74E+02 LLD 1.59E+01 2.09E+01 2.58E+01 1.47E+02 1.80E+02 LLD 1.94E+01 1.40E+01 2.24E+01 1.90E+02 3.26E+02 LLD 2.66E+01 2.02E+01 2.98E+01 1.64E+02 1.95E+02 LLD 2.33E+01 1.66E+01 2.16E+01 1.57E+02 1.70E+02 LLD 3.62E+01 4.05E+01 4.56E+01 2.66E+02 5.54E+02 LLD 4.18E+01 3.69E+01 4.67E+01 2.77E+02 4.92E+02 Sample Point 258 1 CONTROL - W @ 9.84 miles I Sample ID:

250003 Sample Dates: 11212013.11212013 Nuclide Activity I Sigma Error LLD 1-131

<2.69E+01 0.00E+00 2.69E+01 Cs-134

<2.13E+01 0.00E+00 2.13E+01 Cs-137

<3.17E+01 0.00E+00 3.17E+01 Be-7 1.10E+03 1.42E+02 1.89E+02 K-40 4.45E+03 4.19E+02 4.48E+02 Sample ID:

260961 Sample Dates: 215/2013 - 2/512013 Nuclide Activity 1 Sigma Error LLD 1-131

<1.89E+01 0.00E+00 1.89E+01 Cs-134

<2.11E+01 0.00E+00 2.11E+01 Cs-137

<2.64E+01 0.00E+00 2.64E+01 Be-7 1.31E+03 1.25E+02 1.52E+02 K-40 5.84E+03 3.32E+02 1.56E+02 Report Generated @ 5/1/2014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories Eli

13339 Hagers Ferry Road Huntersville, North Carolina 28078 Appendix E - Page 79 of 80

CATAWBA Radiological Environmental Monitoring Analysis Report - 2013 (Appendix E)

Media Type: VEGETATION Concentration (Activity): pCi/kg Sample Point 258 [ CONTROL - W @ 9.84 miles ]

Sample ID:

252706 Sample ID:

255075 Sample ID:

256537 Sample ID:

257936 Sample ID:

259635 Sample ID:

262860 Sample ID:

265437 Sample ID:

269596 Sample ID:

272544 Sample ID:

275267 Sample Dates: 315/2013.31512013 Sample Dates: 412)2013 -41212013 Sample Dates: 617/2013.5/712013 Sample Dates: 61412013 -6/4/2013 Sample Dates: 712/2013 - 7/212013 Sample Dates: 81612013 -81612013 Sample Dates: 9/4/2013 -9/412013 Sample Dates: 1011/2013-10/112013 Sample Dates: 111612013-11/6/2013 Sample Dates: 121312013 -121312013 Nuclide Activity

1. Sigma Error LLD 1-131

<2.25E+01 0.00E+00 2.25E+01 Cs-134

<2.61E+01 0.00E+00 2.61E+01 Cs-137

<2.69E+01 0.00E+00 2.69E+01 Be-7 1.77E+03 1.38E+02 2.02E+02 K-40 5.43E+03 3.24E+02 2.94E+02 Nuclide Activity I Sigma Error LLD 1-131

<1.98E+01 0.00E+00 1.98E+01 Cs-134

<2.15E+01 0.OOE+00 2.15E+01 Cs-137

<2.27E+01 0.00E+00 2.27E+01 Be-7 1.86E+03 1.29E+02 1.42E+02 K-40 6.18E+03 3.34E+02 2.18E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<1.70E+01 0.00E+00 1.70E+01 Cs-1 34

<1.64E+01 0.00E+00 1.64E+01 Cs-137

<1.81E+01 0.00E+00 1.81E+01 Be-7 1.33E+03 1.15E+02 1.24E+02 K-40 3.14E+03 2.33E+02 1.51E+02 Nuclide Activity I Sigma Error LLD 1-131

<1.97E+01 0.00E+00 1.97E+01 Cs-134

<1.40E+01 0.002E+0 1.40E+01 Cs-137

<2.60E+01 0.00E+00 2.60E+01 Be-7 5.02E+02 9.59E+01 1.67E+02 K-40 3.952+03 2.40E+02 2.02E+02 Nuclide Activity 1 Sigma Error LLD 1-131

<6.74E+00 0.00E+00 6.74E+00 Cs-134

<6.61E+00 0.OOE+00 6.61E+00 Cs-137

<7.97E+00 0.00E+00 7.97E+00 Be-7 5.67E+02 3.92E+01 5.24E+01 K-40 4.56E+03 1.35E+02 7.05E+01 Nuclide Activity 1 Sigma Error LLD 1-131

<1.88E+01 0.00E+00 1.88E+01 Cs-134

<1.58E+01 0.002+00 1.58E+01 Cs-137

<1.74E+01 0.00E+00 1.74E+01 Be-7 9.32E+02 1.10E+02 1.62E+02 K-40 4.02E+03 2.93E+02 2.12E+02 Nuclide Activity I Sigma Error LLD 1-131

<2.16E+01 0.00E+00 2.16E+01 Cs-134

<1.92E+01 0.00E+00 1.92E+01 Cs-137

<2.43E+01 0.00E+00 2.43E+01 Be-7 1.02E+03 1.16E+02 1.73E+02 K-40 5.48E+03 3.26E+02 1.98E+02 Nuclide Activity I Sigma Error LLD 1-131

<2.74E+01 0.00E+00 2.74E+01 Cs-134

<2.24E+01 0.00E+00 2.24E+01 Cs-137

<2.26E+01 0.00E+00 2.26E+01 Be-7 1.25E+03 1.27E+02 1.57E+02 K-40 4.69E+03 3.10E+02 2.69E+02 Nuclide Activity I Sigma Error LLD 1-131

<2.88E+01 0.00E+00 2.88E+01 Cs-134

<2.95E+01 0.00E+00 2.95E+01 Cs-137

<3.48E+01 0.00E+00 3.48E+01 Be-7 1.67E+03 1.66E+02 2.95E+02 K-40 3.49E+03 3.90E+02 3.45E+02 Nuclide Activity I Sigma Error LLD 1-131

<3.02E+01 0.00E+00 3.02E+01 Cs-134

<2.82E+01 0.00E+00 2.82E+01 Cs-137

<4.20E+01 0.00E+00 4.20E+01 Be-7 8.74E+02 1.47E+02 2.40E+02 K-40 3.86E+03 4.03E+02 2.66E+02 00 0

6 0

0 0

S 0

0 0

0 Report Generated @ 5/112014 09:22:57 Duke Energy Annual Report - Appendix E EnRad Laboratories En 13339 Hagers Ferry Road Huntersville, North Carolina 28078 S

Appendix E - Page 80 of 80 0

0 0

0 APPENDIX F ERRATA TO PREVIOUS REPORTS Appendix F - Page 1

I APPENDIX F ERRATA TO THE 2013 AREOR There are no errata to be appended to the 2013 AREOR.

0 0

0 S

S S

S 0

S S

0 S

S 0

Appendix F - Page 2

CNS-14-063, 2013 Annual Radiological Environmental Operating Report

Contents

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Subject:

SUMMARY

2.0 INTRODUCTION

6.0 REFERENCES

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CNS-14-063, 2013 Annual Radiological Environmental Operating Report

Text

Subject:

SUMMARY

2.0 INTRODUCTION

6.0 REFERENCES

SUMMARY

SUMMARY

SUMMARY

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