L-2008-169, St. Lucie, Units 1 and 2 - Amended Annual Radiological Environmental Operating Report for Calendar Year 2007
ML082190738 | |
Person / Time | |
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Site: | Saint Lucie ![]() |
Issue date: | 07/28/2008 |
From: | Johnston G L Florida Power & Light Co |
To: | Document Control Desk, Office of Nuclear Reactor Regulation |
References | |
L-2008-169 | |
Download: ML082190738 (63) | |
Text
0 FPL Florida Power & Light Company, 6501 S. Ocean Drive, Jensen Beach, FL 34957 July 2"8, 2008 L-2008-169 10 CFR 50.4 10 CFR 50.36 U. S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, D.C. 20555 RE: St. Lucie Units 1 and 2 Docket Nos. 50-335 and 50-389 Amended Annual Radiological Environmental Operating Report for Calendar Year 2007 The amended report is being submitted pursuant to Technical Specification 6.9.1.8. The Annual Radiological Environmental Operating Report provides information summaries and analytical results of the Radiological Environmental Monitoring Program (REMP) for calendar year 2007.Enclosure replaces report submitted via FPL letter L-2008-091, dated April 28, 2008, in its entirety.
The previous report referenced incomplete results from the Department of Energy (DOE) Interlaboratory Comparison Program. The DOE issued a letter indicating a delay for the second cycle performance assessment results (MAPEP-18, December 2007). The amended report includes Florida Power & Light Company's receipt of this data.Please contact us should there be any questions regarding this report.GQfdon L. Johnston Site Vice President St. Lucie Plant Enclosure GLJ/tlt an FPL Group company 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT UNITS 1 & 2 LICENSE NOS. DPR-67, NPF-16 DOCKET NOS. 50-335, 50-389 Data Submitted by: Florida DOH Prepared by: Reviewed by:.
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 TABLE OF CONTENTS DESCRIPTION Introduction Radiological Environmental Monitoring Program Discussion and Interpretation of Results Environmental Radiological Monitoring Program Annual Summary Deviations
/ Missing Data Analyses with LLDs Above Required Detection Capabilities Land Use Census Key to Sample Locations Radiological Surveillance of Florida Power and Light Company's St. Lucie Site First Quarter 2007 Second Quarter 2007 Third Quarter 2007 Fourth Quarter 2007 Results from the Interlaboratory Comparison Program 2007 PAGE 1 1 4 TABLE 1 TABLE 1A TABLE 1 B TABLE 2 ATTACHMENT A ATTACHMENT B ATTACHMENT C
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 INTRODUCTION This report is submitted pursuant to Specification 6.9.1.8 of St. Lucie Unit 1 and St. Lucie Unit 2 Technical Specifications.
The Annual Radiological Environmental Operating Report provides information, summaries and analytical results pertaining to the radiological environmental monitoring program for the calendar year indicated.
This report covers surveillance activities meeting the requirements of Unit 1 and Unit 2 Technical Specifications.
This amendment involves the completion and reporting of cycle MAPEP-1 8 of the Interlaboratory Comparison Program results.II. RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM A. Purpose The purpose of the radiological environmental monitoring program is to provide representative measurements of radiation and of radioactive materials in those exposure pathways and for those radionuclides which lead to the highest potential radiation exposures to members of the public resulting from station operation.
The radiological environmental monitoring program also supplements the radiological effluent monitoring program by verifying that the measurable concentrations of radioactive materials and levels of radiation are not higher than expected on the basis of the effluent measurements and the modeling of the environmental exposure pathways.B. Progqram Description The radiological environmental monitoring program (REMP) for the St. Lucie Plant is conducted pursuant to the St. Lucie Units 1 and 2 Offsite Dose Calculation Manual (ODCM) Section 3/4.12.1., Monitoring Program.1. Sample Locations, Types and Frequencies:
- a. Direct radiation gamma exposure rate is monitored continuously at 27 locations by thermoluminescent dosimeters (TLDs). TLDs are collected and analyzed quarterly.
- b. Airborne radioiodine and particulate samplers are operated continuously at five locations.
Samples are collected and analyzed weekly. Analyses include Iodine-1 31, gross beta, and gamma isotopic measurements.
- c. Surface water samples are collected from two locations.
Samples are collected and analyzed weekly and monthly, respectively.
Analyses include gamma isotopic and tritium measurements.
1 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 d. Shoreline sediment samples are collected from two locations coinciding with the locations for surface water samples. Samples are collected and analyzed semi-annually.
Sediment samples are analyzed by gamma isotopic measurements.
- e. Fish and invertebrate samples are'collected from two locations.
Samples are collected and analyzed semi-annually.
Fish and invertebrate samples are analyzed by gamma isotopic measurements.
- f. Broad leaf vegetation samples are collected from three locations.
Samples are collected and analyzed monthly. Broad leaf vegetation samples are analyzed by gamma isotopic measurements.
- g. Ground Water, NEI Initiative; there were no ground water sampling locations in the REMP for 2007 Attachment A provides specific information pertaining to sample locations, types and frequencies.
- 2. Analytical Responsibility:
Radiological environmental monitoring for the St. Lucie Plant is conducted by the State of Florida, Department of Health (DOH), Bureau of Radiation Control (BRC).Samples are collected and analyzed by DOHpersonnel.
Samples are analyzed at the DOH BRC Environmental Radiation Control Laboratory in Orlando, Florida.C. Analytical Results Table 1, Environmental Radiological Monitoring Program Annual Summary provides a summary for all specified samples collected during the referenced surveillance period.Deviations from the sample schedule or missing data, if any, are noted and explained in Table 1A. Samples not meeting the specified "A PRIORI" LLD, if any, are noted and explained in Table 1 B. Analysis data for all specified samples analyzed during the surveillance period is provided in Attachment B.2 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 D. Land Use Census A land use census out to a distance of a five mile radius from the St. Lucie Plant is conducted annually to determine the location of the nearest milk animal, residence, and garden producing broad leaf vegetation, in each of the 16 meteorological sectors. A summary of the land use census for the surveillance year is provided in Table 2, Land Use Census Summary.E. Interlaboratory Comparison Program The intercomparison program consists of participating in the DOE Mixed Analyte Performance Evaluation Program (MAPEP).This program provides similar testing (matrices, nuclides, and levels) as the former EPA Interlaboratory Comparison Program and is referred to as the Mixed Analyte Performance Evaluation Program (MAPEP).The samples are analyzed using the methods applicable to the REMP (gamma spectroscopy, Gross Beta, and Tritium for water).From the MAPEP handbook: Acceptance criteria were developed from a review of precision and accuracy data compiled by other performance evaluation programs (PEPs), the analytical methods literature, from several MAPEP pilot studies, and from what is considered reasonable, acceptable, and achievable for routine analyses among the more experienced laboratories.
The results for nuclides associated with the REMP are listed in ATTACHMENT C, RESULTS FROM THE INTERLABORATORY COMPARISON PROGRAM.3 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 Ill. DISCUSSION AND INTERPRETATION OF RESULTS A. Reportingq of Results The Annual Radiological Environmental Operating Report contains the summaries, interpretations and information required by St. Lucie Plant ODCM. Table 1 provides a summary of the measurements made for the nuclides required by ODCM, Table 4.12-1, for all samples specified by Table 3.12-1. In addition, summaries are provided for other nuclides identified in the specified samples, including those not related to station operation.
These include nuclides such as K-40, Th-232, Ra-226, and Be-7, which are common in the Florida environment.
B. Interpretation of Results 1. Direct Radiation:
The results of direct radiation monitoring are consistent with past measurements for the specified locations.
The exposure rate data shows no indication of any trends attributed to effluents from the plant. The measured exposure rates are consistent with exposure rates that were observed during the pre-operational surveillance program. Direct radiation monitoring results are summarized in Table 1.2. Air Particulates/Radioiodine:
The results for radioactive air particulate and radioiodine monitoring are consistent with past measurements and indicate no trends attributed to plant effluents.
All samples for radioiodine yielded no detectable 1-131. Gamma isotopic measurements yielded no indication of any nuclides attributed to station operation.
The results for air particulate/radioiodine samples are consistent with measurements that were made during the pre-operational surveillance program. Air particulate and radioiodine monitoring results are summarized in Table 1.3. Surface Water: The results for radioactivity measurements in surface water are consistent with past measurements and with measurements made during the pre-operational surveillance program. There were no indications of any nuclides attributed to plant effluents.
Results for surface water samples are summarized in Table 1.4 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 4. Waterbome Sediment and Food Products: The results for radioactivity measurements in waterborne sediment, fish and crustacean samples are consistent with past measurements and with measurements made during the pre-operational surveillance program. There were no indications of any nuclides attributed to plant effluents.
Results for the waterborne sediment, fish and crustacean samples are summarized in Table 1.5. Broad Leaf Vegetation:
The results of radioactivity measurements in broad leaf vegetation are consistent with past measurements and with measurements made during the pre-operational surveillance program.There were no indications of any nuclides attributed to plant effluents.
Results for the broad leaf vegetation samples are summarized in Table 1.6. Land Use Census: No locations yielding a calculated dose or dose commitment greater than the values currently being calculated were identified by the land use census. No locations yielding a calculated dose or dose commitment (via the same exposure pathway)20 percent greater than locations currently being sampled in the radiological environmental monitoring program were identified by the land use census.7. Interlaboratory Comparison Program: The State laboratory participated in MAPEP 17 and 18.In MAPEP 17, the results for Water, Soil and Vegetation matrices forthose nuclides associated with nuclear power plant operation and using analytical methods used in the REMP are Acceptable.
The Air Filter matrix had a not acceptable for Co-57; the lab result was high. Co-57 is not a nuclide seen in the history of air sampling around the nuclear power plants in Florida. Review of assay methods did not reveal a definitive cause; repeat counting of the sample yielded what would be acceptable results. The Co-57 calibration standard is being replaced.For MAPEP 18, the State Laboratory received, analyzed & reported their results;however, DOE has reported a delay for issuance of the report that would contain the performance grade. The report was published late April / early May 2008.The results for Water, Air Filter and Vegetation matrices for those nuclides associated with nuclear power plant operation and using analytical methods used in the REMP are Acceptable with a warning for Am-241 in vegetation.
The Soil matrix had a not acceptable for Co-60. An evaluation was performed; the conservative result was due to interference from the presence of Cs-134 in a sample that has very little Co-60. The assay algorithm has been corrected to account for this in the future. The history of soil sampling was reviewed; as expected, there has not been a case of positive Cs-1 34 in a sample.5 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 Note in the Acceptance Range the entry "Sensitivity Eval.". These special evaluations are used by DOE to determine the range of LLDs, afforded by the participants The results are listed in Attachment C.6 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 C. Conclusions The data obtained through the St. Lucie Plant radiological environmental monitoring program verifies that the levels of radiation and concentrations of radioactive materials in environmental samples, representing the highest potential exposure pathways to members of the public, are not being increased.
The measurements verify that the dose or dose commitment to members of the public, due to operation of St. Lucie Units 1 and 2, during the surveillance year, are well within "as low as reasonably achievable (ALARA)" criteria established by 10 CFR 50, Appendix I.7 TABLE 1 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2 , Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)Page 1 of 8 PATHWAY: DIRECT RADIATION SAMPLES COLLECTED:
TLD UNITS: micro-R/hr Location with Highest Annual Mean Namec Mean (f)b Type and Total Number of Lower Limit of All Indicator Distance & Range Control Locations Analyses Performed Detection a (LLD) Locations Direction Mean (f)b Range Mean (fb Range Exposure Rate, 1 0 6 d 5.2 (102/102)4.3 -6.5 NW-10 10 mi., NW 6.3 (4/4)6.1 -6.4 5.4 (4/4)5.1 -5.9 Number of Non-Routine Reported Measurements
= 0 TABLE 1 Page 2 of 8 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2 , Docket No(s). 50-335 & 50-389 Location of Facility St. LucieFlorida , Reporting Period January 1 -December 31, 2007 (County, State)PATHWAY: AIRBORNE SAMPLES COLLECTED:
RADIOIODINE AND PARTICULATES UNITS: PICO -Ci/M 3 Location with Highest Annual Mean Name c Mean (f)b Type and Total Number of Lower Limit of All Indicator Distance & Range Control Locations Analyses Performed Detection a (LLD) Locations Direction Mean (f)b Range Mean (f)b Range 1311, 260 0.024 0.0025<MDA<MDA Gross Beta, 260 0.014 (205/208)0.003 -0.046 H-08 6 miles, WNW 0.014 (51/52)0.003 -0.029 0.015 (50/52)0.007 -0.027 Composite Gamma Isotopic, 20 7 Be 134cs 137cs 21 OPb 0.0052 0.00069 0.00066 0.1748 (16/16)0.1119 -0.2471 H-08 6 miles, WNW 0.1904 (4/4)0.1395 -0.2471 0.1974 (4/4)0.1276 -0.2419<MDA<MDA<MDA<MDA 0.0242 (8/16)0.0161 -0.0339 H-34 0.5 mi., N 0.0339 (1/4)0.0323 (3/4)0.0276 -0.0367 Number of Non-Routine Reported Measurements
= 0 TABLE 1 Page 3 of 8 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2, Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)PATHWAY: WATERBORNE SAMPLES COLLECTED:
SURFACE WATER UNITS: PICO -Ci/LITER Location with Highest Annual Mean Namec Mean (f)b Type and Total Number of Lower Limit of All Indicator Distance & Direction Range Control Locations Analyses Performed Detectiona (LLD) Locations Mean (f)b Range Mean (f)b Range Tritium, 64 Gamma Isotopic, 64 4 0 K 230<MDA<MDA 60 359 (52/52)225 -421 H-1 5<1 mi., ENE/E/ESE 359 (52/52)225 -421 327 (12/12)279 -392 5 4 Mn 5 9 Fe 5 8 Co 6 0 Co 6 5 Zn 9 5 Zr-Nb 1311 4 8 4 4 8 7 5 5 5<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA 1 3 4 cS 1 4 0 Ba-La 11 Number of Non-Routine Reported Measurements
= 0 TABLE 1 Page 4 of 8 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2, Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)PATHWAY: WATERBORNE SAMPLES COLLECTED:
SHORELINE SEDIMENT UNITS: PICO -Ci/Kg, DRY Location with Highest Annual Mean Namec Mean (f)b Type and Total Number Lower Limit of All Indicator Distance & Direction Range Control Locations of Analyses Performed Detectiona (LLD) Locations Mean (f)b Range Mean (f)b Range Gamma Isotopic, 4 7 Be 146 (1/2)488 (2/2)268 -707 140 5 8 co 60co 137cs 9 12 14 12 49<MDA<MDA<MDA<MDA H-1 5<1 mi, ENE/E/ESE H-1 5<1 mi, ENE/E/ESE H-15<1 mi., ENE/E/ESE H-15<1 mi., ENE/E/ESE 146 (1/2)488 (2/2)268 -707<MDA<MDA<MDA<MDA 88 (1/2)300 (2/2)220 -379 316 (2/2)198-434 157 (1/2)316 (2/2)198-434 157 (1/2)298 (2/2)194 -402 58 (1/2)2 3 2 Th Number of Non-Routine Reported Measurements
= 0 TABLE 1 Page 5 of 8 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2, Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)PATHWAY: INGESTION SAMPLES COLLECTED:
CRUSTACEA UNITS: PICO -Ci/Kg, WET Location with Highest Annual Mean Namec Mean (f)b Type and Total Number of Lower Limit of All Indicator Distance & Direction Range Control Locations Analyses Performed Detectiona (LLD) Locations Mean (f)b Range Mean (f)b Range Gamma Isotopic, 4 130 2387 (2/2)2272 -2502 H-1 5<1 mi., ENE/E/ESE 2387 (2/2)2272 -2502 1744 (2/2)1587- 1901 5 4 Mn 5 9 Fe 5 8 Co 6 0 Co 6 5 Zn 1 3 4 C s 1 3 7 Cs 2 2 6 Ra 2 2 8 Ra 9 16 9 19 17 9 9<MDA<MDA<MDA<MDA<MDA<MDA<MDA< MDA< MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA 450 (1/2)187 (1/2)Number of Non-Routine Reported Measurements
= 0 TABLE 1 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2, Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)Page 6 of 8 PATHWAY: INGESTION SAMPLES COLLECTED:
FISH UNITS: PICO -Ci/Kg, WET Location with Highest Annual Mean Namec Mean (f)b Type and Total Number of Lower Limit of All Indicator Distance & Direction Range Control Locations, Analyses Performed Detectiona (LLD) Locations Mean (f)b Range Mean (f)b Range Gamma Isotopic, 4 130 2812 (2/2)2347 -3277 H-1 5<1 mi., ENE/E/ESE 2812 (2/2)2347 -3277 3497 (2/2)2864-4130<MDA 54Mn 5 9 Fe 5 8 Co 6 0 co 6 5 Zn 1 3 4 cs 9 16 9 10 17<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA<MDA 9 9 Number of Non-Routine Reported Measurements
= 0 TABLE 1 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2, Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)Page 7 of 8 PATHWAY: INGESTION SAMPLES COLLECTED:
BROAD LEAF VEGETATION UNITS: PICO -Ci/Kg, WET Location with Highest Annual Mean Namec Mean (f)b Type and Total Number of Lower Limit of All Indicator Distance & Direction Range Control Locations Analyses Performed Detectiona Locations .Mean (f)b Range (LLD) Mean (f)b Range Gamma Isotopic, 36 7 Be 71 1385 (24/24)489-2096 4054 (24/24)2071 -5957 H-51 1 mi., N/NNW H-52 1 mi., S/SSE 1522 (12/12)899 -2096 4268 (12/12)2172-5975 100 1340 (12/12)895-1948 3035 (12/12)2016-4038<MDA 5 8 co 6 0 co 1311 6 8 9 8 8<MDA<MDA<MDA<MDA< MDA<MDA<MDA<MDA 1 3 7 cs<MDA 1157 (4/24)503 -2004 45 (6/24)16 -77 406 (1/24)H-51 1 mi., N/NNW H-52 1 mi., S/SSE H-51 1 mi., N/NNW 1245 (3/12)503-2004 64 (2/12)51 -77 406 (1/12)564 (2/12)502 -626 40(1/12)2 2 6 Ra<MDA Number of Non-Routine Reported Measurements
= 0.
TABLE 1 Page 8 of 8 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM ANNUAL
SUMMARY
Name of Facility St. Lucie Units 1 & 2, Docket No(s). 50-335 & 50-389 Location of Facility St. Lucie, Florida , Reporting Period January 1 -December 31, 2007 (County, State)NOTES a. The LLD is an "a priori" lower limit of detection which establishes the smallest concentration of radioactive material in a sample that will yield a net count above system background that will be detected with 95% probability with only 5% probability of falsely concluding that a blank observation represents a real signal.LLDs in this column are at time of measurement.
The MDAs reported in Attachment B for the individual samples have been corrected to the time of sample collection.
- b. Mean and range based upon detectable measurements only. Fraction of detectable measurements at specified locations is indicated in parentheses (f).c. Specific identifying information for each sample location is provided in Attachment A.d. Results were based upon the average net response of three elements in a TLD (thermoluminescent~dosimeter).
MDA refers to minimum detectable activity.
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 TABLE 1A (Page 1 of 21 DEVIATIONS
/ MISSING DATA A) Pathway: Location: Dates: Deviation:
Description of Problem: Corrective Action: B) Pathway: Location: Dates: Deviation:
Description of Problem: Corrective Action: C) Pathway: Location: Dates: Deviation:
Description of Problem: Direct Exposure, TLDs NNW-10, 9 miles North Northwest 7 MAR 07 to 12 JUN 07 Failure to perform continuous monitoring TLD holder (cricket cage) fell apart; TLD struck by lawnmower.
Repaired holder, replaced TLD.Direct Exposure, TLDs WNW-5, 5 miles West Northwest 7 MAR 07 to 12 JUN 07 Failure to perform continuous monitoring Utility pole where TLD mounted removed for road construction; TLD removed with pole.Located new utility pole away from construction area, mounted replacement TLD Airborne, Particulates
& Radioiodines H-14, 1 mile Southeast 17 JUL 07 to 24 JUL 07 Failure to perform continuous monitoring Apparent power interruption during sampling period;estimated sampling duration of 137.6 hours6.944444e-5 days <br />0.00167 hours <br />9.920635e-6 weeks <br />2.283e-6 months <br /> of 170 hour0.00197 days <br />0.0472 hours <br />2.810847e-4 weeks <br />6.4685e-5 months <br /> sampling period.Verified equipment as operable; no repairs needed.Corrective Action:
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 TABLE 1A (Page 2 of 2)DEVIATIONS
/ MISSING DATA D) Pathway: Location: Dates: Deviation:
Description of Problem: Corrective Action: E) Pathway: Location: Dates: Deviation:
Description of Problem: Corrective Action: F) Pathway: Location: Dates: Deviation:
Description of Problem: Airborne, Particulates
& Radioiodines H-34, 0.5 miles North 9 OCT 07 to 16 OCT 07 Failure to perform continuous monitoring Air sample pump not running properly; estimated run time of 69 hours7.986111e-4 days <br />0.0192 hours <br />1.140873e-4 weeks <br />2.62545e-5 months <br /> out of 168 hour0.00194 days <br />0.0467 hours <br />2.777778e-4 weeks <br />6.3924e-5 months <br /> sampling period Replaced air sampling pump; verified equipment as operable.Airborne, Particulates
& Radioiodines H-12,12 miles South 7 NOV 07 to 14 NOV 07 Failure to perform continuous monitoring Apparent power interruption during sampling period;estimated sampling duration of 133 hours0.00154 days <br />0.0369 hours <br />2.199074e-4 weeks <br />5.06065e-5 months <br /> of 163 hour0.00189 days <br />0.0453 hours <br />2.695106e-4 weeks <br />6.20215e-5 months <br /> sampling period Verified equipment as operable; no repairs needed.Airborne, Particulates
& Radioiodines H-30, 2 miles West 28 NOV 07 to 5 DEC 07 Failure to perform continuous monitoring Apparent power interruption during sampling period;estimated sampling duration of 145 hours0.00168 days <br />0.0403 hours <br />2.397487e-4 weeks <br />5.51725e-5 months <br /> of 171 hour0.00198 days <br />0.0475 hours <br />2.827381e-4 weeks <br />6.50655e-5 months <br /> sampling period Verified equipment as operable; no repairs needed.Corrective Action:
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 TABLE 1B ANALYSIS WITH LLDs ABOVE THE REQUIRED DETECTION CAPABILITIES (LLDs) Listed in ODCM TABLE 4.12-1 1/1/2007 -12/31/2007 The values specified in ODCM Table 4.12-1, Detection Capabilities, were achieved for all samples.
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 TABLE 2 LAND USE CENSUS (Page 1 of 2)Distance to Nearest (a, b)Sector N NNE NE ENE E ESE SE SSE S SSW SW WSW W WNW NW NNW 7/07 -8/07 Milk (c) Animal 0 (e)0 0 0 0 0 0 L (f)L L L L L L L L 7/07 -8/07 Residence 0 0 0 0 0 0 1.5/142 (g)3.3/152 (g)3.3/190 2.2/212 1.9/235 1.9/240 1.9/260 2.2/281 3.5/304 3.4/342 (g)7/07 -8/07 Garden (d)0 0 0 0 0 0 0 L L L L L L L L L 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 TABLE 2 LAND USE CENSUS (Page 2 of 2)NOTES a. All categories surveyed out to a 5-mile radius from the St. Lucie Plant.b. The following format is used to denote the location: distance (miles)/bearing (degrees)For example, a residence located in the southeast sector at a distance of 1.5 miles bearing 142 degrees is recorded as 1.5/142.c. Potential milk animal locations.
- d. Gardens with an estimated growing area of 500 square feet or more.e. 0 denotes that the sector area is predominantly an ocean area.f. L denotes that the sector area is predominantly a land area unoccupied by the category type.g. Non-residential occupied buildings in these sectors include the following:
Sector Distance Description SSE 1.8/147 Fire Station NNW 2.8/348 A new community is being developed.
At the current time, there are no houses available for occupancy.
2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 ATTACHMENT A KEY TO SAMPLE LOCATIONS 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 SITE AREA MAP & ENVIRONMENTAL SAMPLE LOCATIONS z htetetf /- 1J'A<E XCLUJSý0iý AR~EA (Q2C t~1).i tw.e* 2) DX.ete the s...,..e.,.
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2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 ENVIRONMENTAL SAMPLE LOCATIONS (10 MILES)IMarlin Hw (P/CHEM/C-200B-F2-RO) 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 ATTACHMENT A PAGE 1 OF 4 PATHWAY: DIRECT RADIATION SAMPLES COLLECTED:
TLD SAMPLE COLLECTION FREQUENCY:
QUARTERLY Location Name N-1 NNW-5 NNW-10 NW-5 NW-10 WNW-2 WNW-5 WNW-10 W-2 W-5 W-10 WSW-2 WSW-5 WSW-10 SW-2 SW-5 SW-10 SSW-2 SSW-5 SSW-10 S-5 S-10 S/SSE-1 0 SSE-5 SSE-10 SE-1 Control: H-32 Direction Sector N NNW NNW NW NW WNW WNW WNW W W W WSW WSW WSW SW SW SW SSW SSW SSW S S SSE SSE SSE SE Approximate Distance (miles)1 5 9 6 10 3 5 10 2 5 9 2 5 10 2 5 10 3 6 8 5 10 10 5 10 1 Description AlA, North of Blind Creek South of Pete Stone Creek Coast Guard Station Indian River Dr., at Rio Vista Dr.S.R. 68 at S.R. 607 Cemetery South of 7107 Indian River Dr.U.S. 1 at S.R. 712 S.R. 70, West of Turnpike 7609 Indian River Drive Oleander and Saqer Street Interstate 95 at S.R. 709 8503 Indian River Dr.Prima Vista at Yacht Club Del Rio at Davis Street 9207 Indian River Drive U.S. 1 at Villaqe Green Dr.Port St. Lucie Blvd. at Cairo Rd.10307 Indian River Drive U.S. 1 at Port St. Lucie Blvd.Pine Valley at Westmoreland Rd.13179 Indian River Drive U.S. 1 at S.R. 714 Indian River Dr. at Quail Run Lane Entrance to Nettles Island Elliot Museum South of Coolinq Canal NNW 19 University of Florida IFAS Vero Beach 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 ATTACHMENT A PAGE 2 OF 4 PATHWAY: AIRBORNE SAMPLES COLLECTED:
RADIOIODINE AND PARTICULATES SAMPLE COLLECTION FREQUENCY:
WEEKLY Location Direction Approximate Description Name Sector Distance (miles)H-08 WNW 6 FPL Substation, Weatherbee Rd.H-14 SE 1 On-Site, Near South Property Line H-30 W 2 Power Line, 7609 Indian River Drive H-34 N 0.5 On-Site at Meteorology Tower Control: H-1 2 S 12 FPL Substation, SR-76 Stuart 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 ATTACHMENT A PAGE 3 OF 4 PATHWAY: WATERBORNE SAMPLES COLLECTED:
SURFACE WATER (OCEAN)SAMPLE COLLECTION FREQUENCY:
H-15 WEEKLY, H-59 MONTHLY Location Name Direction Sector Approximate Distance (miles)<1 Description H-1 5 ENE/E/SSE Atlantic Ocean, Public Beaches East Side AlA South End, Hutchinson Island Control: H-59 S/SSE 10-20 SAMPLES COLLECTED:
SHORELINE SEDIMENT SAMPLE COLLECTION FREQUENCY:
SEMI-ANNUALLY Location Name Direction Sector Approximate Distance (miles)<1 Description H-15 ENE/E/ESE Atlantic Ocean, Public Beaches East Side AlA Control: H-59 S/SSE 10-20 South End, Hutchinson Island 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 ATTACHMENT A PAGE 4 OF 4 PATHWAY: INGESTION SAMPLES COLLECTED:
CRUSTACEA AND FISH SAMPLE COLLECTION FREQUENCY:
SEMI-ANNUALLY Location Name Direction Sector Approximate Distance (miles)<1 Description H-1 5 ENE/E/ESE Ocean Side, Vicinity of St. Lucie Plant South End, Hutchinson Island Control: H-59 S/SSE 10-20 SAMPLES COLLECTED:
BROAD LEAF VEGETATION SAMPLE COLLECTION FREQUENCY:
MONTHLY Location Name Direction Sector N/NNW Approximate Distance (miles)1 Description H-51 H-52 Off-Site Near North Property Line Off-Site Near South Property Line S/SSE 1 Control: H-59 S/SSE 10-20 South End, Hutchinson Island 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 ATTACHMENT B RADIOLOGICAL SURVEILLANCE OF'FLORIDA POWER AND LIGHT COMPANY ST. LUCIE SITE 2007 First Quarter 2007 Second Quarter 2007 Third Quarter 2007 Fourth Quarter 2007 SL QR 1Q-2007 ST. LUCIE SITE Offsite Dose Calculation Manual Sampling First Quarter, 2007 Sample Type 1. Direct Radiation Collection Frequency Locations Sampled Number of Samples 27 2. Airborne 2.a. Air lodines 2.b. Air Particulates
- 3. Waterborne 3.a. Surface Water Quarterly Weekly Weekly 27 5 5 65 65 13 3.b. Shoreline Sediment 4. Ingestion 4.a. Fish and Invertebrates 4.a.1. Crustacea 4.a.2. Fish 4.b. Broadleaf Vegetation Weekly Monthly Semiannually Semiannually Semiannually Monthly 1 2 2 2 3 3 2 1 2 1 9 Total: 187 NOTE: Measurement results having magnitudes that are significantly above the background of the measurement system are reported as net values plus or minus a one-standard-deviation error term. Measurement results that are not significantly above background are reported as less than a Lower Limit of Detection
(<LLD), which is an estimated upper limit (with at least 95%confidence) for the true activity in the sample.The marine fauna listed in this report were collected in part, under Florida FWC SAL030.1 of 7 SL QR I Q-2007 1. DIRECT RADIATION
-TLDs -(gR/hour)Sample Site N-i NNW-5 NNW- 10 NW-5 NW-10 WNW-2 WNW-5 WNW-10 W-2 W-5 W-10 WSW-2 WSW-5 WSW-10 Deployment 08-Dec-06 Collection 07-Mar-07 5.0 + 0.3 5.0 + 0.4 5.5 + 0.3 5.0 +/- 0.3 6.1+/- 0.5 5.2 +/- 0.3 5.2 +/- 0.4 6.0 -0.5 4.8 +/- 0.3 6.5 + 1.3 5.3 +/- 0.3 5.0 + 0.4 5.1 + 0.4 4.8 +/- 0.3 Sample Site SW-2 SW-5 SW-10 SSW-2 SSW-5 SSW-10 S-5 S-10 S/SSE-10 SSE-5 SSE-10 SE-I H-32 Deployment 08-Dec-06 Collection 07-Mar-07 4.8 +/- 0.4 5.9 -0.5 5.3 +/- 0.4 4.8 +/- 0.3 6.2 +/- 0.5 5.5 +/- 0.4 5.5 +/- 0.3 5.2 + 0.3 5.1 +/--0.3 4.7 + 0.3 5.7 +/- 0.3 5.4 +/- 0.3 5.9 +/- 0.3 2 of 7 SL QR 1Q-2007 2.a. IODINE-131 IN WEEKLY ArR CARTRIDGES
-(pCi/ M 3)Collection Date 02-Jan-07 10-Jan-07 18-Jan-07 23-Jan-07 02-Feb-07 08-Feb-07 14-Feb-07 22-Feb-07 01 -Mar-07 07-Mar-07 14-Mar-07 20-Mar-07 27-Mar-07 H08<0.02<0.01<0.01<0.03<0.01<0.03<0.03(A)<0.01<0.02<0.01<0.02<0.01<0.01 H12 H14 H30<0.02<0.01<0.01<0.03<0.01<0.03<0.03<0.01<0.02<0.01<0.02<0.02<0.01 H34<0.02<0.01<0.01<0.03<0.01<0.03<0.03<0.01<0.02<0.01<0.02<0.02<0.01<0.02<0.01<0.01<0.03<0.01<0.03<0.03<0.01<0.02<0.01<0.02<0.01<0.01<0.02<0.01<0.01<0.03<0.01<0.03<0.03<0.01<0.02<0.01<0.02<0.02<0.01 (A) Gas meter changed out. This was based report for the forth quarter of 2006.on review of data while compiling the quarterly 3 of 7 SL QR 1Q-2007 2.b. 1. AIR PARTICULATES
-GROSS BETA -(nCi/m 3)Collection Date 02-Jan-07 I0-Jan-07 18-Jan-07 23-Jan-07 02-Feb-07 08-Feb-07 14-Feb-07 22-Feb-07 01-Mar-07 07-Mar-07 14-Mar-07 20-Mar-07 27-Mar-07 Average: H08, 0.008 +/- 0.002 0.007 +/- 0.002 0.007 +/- 0.002 0.010 + 0.003 0.020 +0.002 0.017 + 0.003 0.025 + 0.003(A)0.020 +/- 0.002 0.016 +/- 0.002 0.012 +/- 0.002 0.017 +/- 0.002 0.016 +/- 0.002 0.016 + 0.002 0.015 G 0.001 H12 0.007 + 0.002 0.009 +/- 0.002 0.010 +/- 0.002 0.013 +/- 0.003 0.018 +/- 0.002 0.019 +/- 0.003 0.022 +/- 0.003 0.025 +/- 0.002 0.018 +/- 0.002 0.019 +/- 0.002 0.018 +/- 0.002 0.015 +/- 0.002 0.017 +/- 0.002 0.016 +/- 0.001 H14 0.007 + 0.002 0.008 +/- 0.002 0.007 +/- 0.002 0.006 +/- 0.002 0.017 +/- 0.002 0.019 +/- 0.003 0.018 +/- 0.002 0.018 + 0.002 0.015 +/- 0.002 0.018 +/- 0.002 0.007 +/- 0.002 0.019 +/- 0.003 0.016 +/- 0.002 0.014 +/- 0.001 H30 0.012 +/- 0.003 0.005 +/- 0.001 0.006 +/- 0.001 0.005 +/- 0.002 0.015 +/- 0.002 0.027 +/- 0.003 0.025 +/- 0.003 0.021 +/- 0.002 0.013 +/- 0.002 0.021 +/- 0.003 0.010 +/- 0.002 0.015 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.001 H34 0.006 + 0.002 0.004 +/- 0.001 0.006 +/- 0.002 0.015 + 0.003 0.018 +/- 0.002 0.023 + 0.003 0.017 + 0.003 0.017 + 0.002 0.014 # 0.002 0.015 +/- 0.002 0.013 +/- 0.002 0.018 +/- 0.003 0.015 + 0.002 0.014 +/- 0.001 ,(A) Gas meter changed out. This was based on review of data while compiling the quarterly report for the forth quarter of 2006.2.b.2. AIR PARTICULATES
-GAMMA ANALYSIS OF QUARTERLY COMPOSITES (pCi/m 3)Sample Site H08 H12 H14 H30 H34 Be-7 0.2105 +/- 0.0136 0.2497 +/- 0.0146 0.2137 +/- 0.0144 0.1752 +/- 0.0144 0.1819 +/-,0.0046 K-40<0.0162 Cs-134<0.0012 Cs-137<0.0008 Pb-210 0.0239 +/- 0.0046 0.0367 +/- 0.0046<0.0184 <0.0010 <0.0010<0.0191 <0.0011 <0.0010 0.0198 +/- 0.0051<0.0150 <0.0009 <0.0011<0.0076 <0.0005 <0.0004 0.0179 +/- 0.0039 0.0339 +/- 0.0073 4 of 7 SL QR 1Q-2007 3.a. SURFACE WATER -(DCi/L)Sample Site Collection Date H15 02-Jan-07 10-Jan-07 18-Jan-07 23-Jan-07 02-Feb-07 08-Feb-07 14-Feb-07 22-Feb-07 01-Mar-07 07-Mar-07 14-Mar-07 20-Mar-07 27-Mar-07 H59 02-Jan-07 15-Feb-07 07-Mar-07 H-3<140<144<144<144<147<147<146<146<143<143<145<145<145<145<146<143 Zr-95 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 (A)333 +/- 36 <3 <3 <6 <5 <8 <6 376 +/- 26 <3 <3 <7 <3 <8 <5 225 +/- 37 <4 <5 <10 <4 <11 K8 364 +/- 35 <3 <3 <5 <4 <7 <6 389 +/- 37 <3 <4 <8 <5 <6 <5 343 +/- 34 <4 <3 <8 <4 <8 <4 310 +/- 40 <4 <4 <9 <4 <10 <7 383 +/- 28 <2 <2 <5 <3 <6 <4 381 +/- 38 <4 <4 <7 <4 <8 <6 323 +/- 44 <4 <5 <12 <5 <12 <7 342 +/- 34 <4 <3 <6 <4 <8 <6 322 +/- 36 <3 <3 <8 <4 <9 <6 413 +/-36 <4 <3 <7 <4 <8 <5 347 +/- 32 <4 <3 <8 <4 <7 <7 332 +/- 38 <5 <4 <7 <5 <9 <7 282 +/- 44 <5 <5 <9 <6 <13 <8<5<5<6<4<5<6<6<3<5<7<4<5<4<4<6<6 Ba-140 1-131 Cs-134 Cs-137 La-140<5<3<5<5<4<4<5<3<4<5<4<4<4<5<4<6<3<3<4<4<3<3<5<2<4<5<4<3<4<3<4<5 (B)<13<5<8<14<6<6<7<4<6<8<.12<4<11<8<10<7 (A) -These tabulated LLD values for Zr/Nb-95 are the higher of the individual parent or daughter LLD's.(B) -These tabulated LLD values are for Ba- 140, either based on direct measurement of Ba- 140 or based on ingrowth of La-140, whichever method yields the greater sensitivity for a given sample.5 of 7 SL QR 1Q-2007 3.b. SHORELINE SEDIMENT -(pCi/kg, dry weight)Sample Site H15 H59 Collection Date 14-Feb-07 15-Feb-07 Be-7<209<77 K-40 268 +/- 54 220 +/- 49 Co-58<14<7 Co-60<8<7 Cs-134<11<9 Cs-137<7<8 Pb-210<463<486 Ra-226 198 +/- 91-402 +/- 87 Th-232<44<48 U-238<356<358 4.a. 1. CRUSTACEA
-Blue Crab -(pCi/kg, wet weight)Sample Site H15 H59 Collection Date K-40 Mn-54 This sample has not yet been collected.
08-Mar-07 1587 +/- 215 <27 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 Ra-226 Ra-228<26 <50 <28 <60 <30<27<476<105 4.a.2. FISH -Mixed Fish -(pCi/kg. wet weight)Sample Site H15 H59 Collection Date 08-Mar-07 15-Feb-07 K-40 2347 +/- 199 4130 + 155 Mn-54 Co-58<19 <19<13 <13 Fe-59<39<28 Co-60<26<16 Zn-65<50<29 Cs-134<21<16 Cs-137<23<15 Ra,-226<310<262 Ra-228<71<56 6 of 7 SL QR 1Q-2007 4.b. BROADLEAF VEGETATION
-Brazilian Pepper -(pCi/kg, wet weight)Sample Site H51 H52 H59 Collection Date 02-Jan-07 22-Feb-07 07-Mar-07 02-Jan-07 22-Feb-07 07-Mar-07 02-Jan-07 15-Feb-07 07-Mar-07 Be-7 2039 + 45 1748 +/- 42 1433 -106 1323 29 1825 +/- 55 993 + 87 1495 +/- 76 1948 -79 1093 -79 K-40 3042 +/- 90 4518 +/- 87 2817+/- 194 4128 -58 3508 -109 5551 +/-260 2033 + 134 2016- 112 3802+/- 160 1-131<11<9<23<6<11<24<20<14<21 Cs-134<7<6<20<4<9<21<11<10<13 Cs-137<6<5<18<3<6<17<13<9<11 Pb-210 1236 +/- 371 503 -160<2482 884 +/- 127<1096<2384<1577<718<783 Ra-226<140<124<359<79<153<351<243<242<269 Others: Pb-212 44 +/- 15 7 of 7 SL QR 2Q-2007 ST. LUCIE SITE Offsite Dose Calculation Manual Specifications Sampling Second Quarter, 2007 Collection Frequency Locations Sampled Sample Type 1. Direct Radiation 2. Airborne 2.a. Air lodines 2.b. Air Particulates Quarterly Weekly Weekly 27 Number of Samples 25 65 65 3. Waterborne 3.a. Surface Water 3.b. Shoreline Sediment 4. Ingestion 4.a. Fish and Invertebrates 4.a.1. Crustacea 4.a.2. Fish Weekly Monthly Semiannually Semiannually Semiannually 5 5 1 1 0 1 0 3 13 3 0 1 0 4.b. Broadleaf Vegetation Monthly 9 Total: 181 NOTE: Measurement results having magnitudes that are significantly above the background of the measurement system are reported as net values plus or minus a one-standard-deviation error term. Measurement results that are not significantly above background are reported as less than a Lower Limit of Detection
(<LLD), which is an estimated upper limit (with at least 95%confidence) for the true activity in the sample.The marine fauna listed in this report were collected in part, .under Florida FWC SAL030.1 of 7 SL QR 2Q-2007 1. DIRECT RADIATION
-TLDs -(,IR/hour)
Sample Site N-I NNW-5 NNW-10 NW-5 NW-10 WNW-2 WNW-5 WNW-10 W-2 W-5 W-10 WSW-2 WSW-5 WSW-10 Deployment 07-Mar-07 Collection 12-Jun-07 4.8 +/- 0.4 5.2 +/- 0.4 (A)4.8 +/- 0.5 6.2 + 0.4 5.4 +/- 0.4 (B)6.1++/-0.6 5.1 + 0.4 5.7 +/- 0.4 5.7 + 0.4 5.3 +/- 0.4.5.5 +/- 0.5 4.7 +/- 0.3 Sample Site SW-2 SW-5 SW-10 SSW-2 SSW-5 SSW-10 S-5 S-10 S/SSE-10 SSE--5 SSE-10 SE-I H-32 Deployment 07-Mar-07 Collection 12-Jun-07 4.8 +/- 0.3 5.7 +/-0.5 4.9 +/- 0.5 5.1 +/-0.6 6.0 +/- 0.4 5.6 +/- 0.3 5.1+ 0.4 5.1 +/-0.3 5.0 +/- 0.4 4.4 +/- 0.2 5.5 +/- 0.4 4.9 +/- 0.5 5.3 +/- 0.5 (A) Bottom of cricket cage fell off and TLD fell out. Found a few pieces of the TLD which appears to have been run over by a lawn mower. Wire basket for cricket cage installed.(B) TLD lost. Utility pole which held the TLD was removed due to road construction.
TLD location moved to a wooden utility pole behind the Mobil station.2 of 7 SL QR 2Q-2007 2.a. IODINE-1 31 IN WEEKLY AIR CARTRIDGES
-(pCi/ m 3)Collection Date H08 H12 H14 H30 H34 03-Apr-07
<0.01 <0.01 <0.01 <0.01 <0.01 12-Apr-07
<0.01 <0.01 <0.01 <0.01 <0.01 17-Apr-07
<0.01 <0.01 <0.01 <0.01 <0.01 25-Apr-07
<0.01 <0.01 <0.01 <0.01 <0.01 03-May-07
<0.01 <0.01 <0.01 <0.01 <0.01 10-May-07
<0.02 <0.02 <0.02 <0.02 <0.02 15-May-07
<0.02 <0.02 <0.02 <0.02 <0.02 22-May-07
<0.01 <0.01 <0.01 <0.01 <0.01 29-May-07*
<0.01 <0.01 <0.01 <0.01 <0.01 05-Jun-07
<0.01 <0.01 <0.01 <0.01 <0.01 12-Jun-07
<0.01 <0.01 <0.01 <0.01 <0.01 19-Jun-07
<0.02 <0.02 <0.02 <0.02 <0.02 27-Jun-07
<0.01 <0.01 <0.01 <0.01 <0.01 3 of 7 SL QR 2Q-2007 2.b.1. AIR PARTICULATES
-GROSS BETA -(pCi/m 3)Collection Date 03-Apr-07 12-Apr-07 17-Apr-07 25-Apr-07 03-May-07 10-May-07 15-May-07 22-May-07 29-May-07 05-Jun-07 12-Jun-07 19-Jun-07 27-Jun-07 Average: H08 0.014 +/- 0.002 0.017 +/- 0.002 0.020 +/- 0.003 0.020 + 0.002 0.016 +/- 0.002 0.010 +/- 0.002 0.014 + 0.003 0.016 +/- 0.002 0.015 + 0.002 0.019 +/- 0.002 0.015 + 0.002 0.011 +/- 0.002 0.015 +/- 0.002 0.016 + 0.001 H12 0.017 + 0.002 0.017 +/- 0.002 0.021 +/- 0.003 0.018 +/- 0.002 0.015 + 0.002 0.014 +/- 0.002 0.014 + 0.003 0.020 +/- 0.002 0.019 +/- 0.002 0.022 +/- 0.002 0.013 + 0.002 0.009 +/- 0.002 0.016 +/- 0.002 0.016 +/- 0.001 H14 H30 H34 0.016 +/- 0.002 0.017 +/- 0.002 0.017 + 0.003 0.017 +/- 0.002 0.017 +/- 0.002 0.010 +/- 0.002 0.012 + 0.002 0.020 +/- 0.002 0.013 +/- 0.002 0.017 +/- 0.002 0.014 +/- 0.002 0.015 +/- 0.002 0.017 +/- 0.002 0.015 +/- 0.001 0.016 +/- 0.002 0.019 +/- 0.002 0.019 +/- 0.003 0.013 +/- 0.002 0.012 + 0.002 0.013 +/- 0.002 0.015 +/-: 0.003 0.016 +/- 0.002 0.020 +/- 0.003 0.016 +/- 0.002 0.014 +/- 0.002 0.014 + 0.002 0.015 +/- 0.002 0.016 +/- 0.001 0.019 +/- 0.002 0.014 +/- 0.002 0.019 +/- 0.003 0.016 +/- 0.002 0.014 +/- 0.002 0.013 +/- 0.002 0.016 +/- 0.003 0.018 +/- 0.002 0.015 +/- 0.002 0.016 +/- 0.002 0.014 +/- 0.002 0.011 +/- 0.002 0.016 +/- 0.002 0.016 +/- 0.001 2.b.2. AIR PARTICULATES
-GAMMA ANALYSIS OF QUARTERLY COMPOSITES
-(pCi/m 3)Second Quarter, 2007 Sample Site H08 H12 H14 H30 H34 Be-7 0.2471 + 0.0140 0.2419 +/- 0.0142 0.2118 +/- 0.0146 0.2039 -+ 0.0148 0.2108 + 0.0142 K-40<0.0200<0.0205<0.0180<0.0187<0.0198 Cs-134<0.0015<0.0009<0.0015<0.0017<0.0020 Cs-137<0.0009<0.0010<0.0010<0.0010<0.0011 Pb-2 10 0.0307 +/- 0.0035 0.0276 +/- 0.0036<0.0514<0.0483<0.0476 4 of 7 SL QR 2Q-2007 3.a. SURFACE WATER (DCi/L'-........... ...... .. .... i Sample Site Collection Date H15 03-Apr-07 12-Apr-07 17-Apr-07 25-Apr-07 03-May-07 10-May-07 15-May-07 22-May-07 29-May-07 05-Jun-07 12-Jun-07 19-Jun-07 27-Jun-07 H59 03-Apr-07 03-May-07 05-Jun-07 Zr-95 H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 (A)<143 416 +/- 39 <3 <4 <9 <4 <10 <7<141 317 +/- 50 <4 <4 <10 <5 <11 <8<140 401 +/- 32 <3 <2 <7. <4 <6 <5<140 399 +/- 34 <3 <3 <7 <4 <7 <6<147 307 +/- 27 <2 <2 <5 <2 <4 <4<147 400 +/- 40 <4 <4 <8 <4 <9 <6<147. 417 +/- 42 <3 <4 <8 <5 <8 <7<147 377 +/- 33 <4 <4 <4 <4 <9 <7<147 360 +/- 38 <4 <4 <9 <5 <7, <5<136 347 +/- 45 <4 <4 <9 <4 <9 <8<139 397 +/- 28 <3 <3 <6 <4 <6 <5<139 409 +/- 44 <3 <5 <9 <4 <10 <7<139 345 +/- 13 <1 <1 <2 <1 <2 <2<143 300 +/- 49 <4 <4 <7 <4 <9 <7<147 321 +/- 31 <3 <4 <7 <5 <8 <6<136 366 +/- 46 <4 <4 <8 <5 <9 <7 1-131<4<5<6<5<3<5<4<4<5<5<5<4<1<4<5<4<4<5<4<4<3<4<5<4<4<4<4<6<1<5<4<5 Ba- 140 Cs-134 Cs-137 La-140<4<4<3<3<2<4<4<4<4<5<3<4<1<5<4<5 (B)<9<5<5<5<3<6<15<5<7<9<5<11<2<8<6<7 (A) -These tabulated LLD values for Zr/Nb-95 are the higher of the individual parent or daughter LLD's.(B) -These tabulated LLD values are for Ba-140, either based on direct measurement of Ba-140 or based on La-140, whichever method yields the greater sensitivity for a given sample.ingrowth of 5 of 7 SL QR 2Q-2007 3.b. SHORELINE SEDIMENT -(nCi/ka dry weight)Sample Collection Site Date Be-7 K-40 Co-58 Co-60 Cs-134 Cs-137 Pb-210 Ra-226 Th-232 These samples were previously collected.
4.a. 1. CRUSTACEA
-(pCi/kg, wet weight)Sample Site H15 Collection Date 06-Jun-07 K-40 2502 +/- 182 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 Ra-226 Ra-228<24<24<57<24<51<28<25<356<80 4.a.2. FISH -(pCi/kg. wet weight)Sample Site Collection Date K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 Ra-226 Ra-228 These samples were previously collected.
6 of 7 SL QR 2Q-2007 4.b. BROADLEAF VEGETATION
-Brazilian Pepper -(pCi/kg, wet weight)Sample Site H51 H52 H59 Collection Date 03-Apr-07 03-May-07 05-Jun-07 03-Apr-07 03-May-07 05-Jun-07 03-Apr-07 03-May-07 05-Jun-07 Be-7 1858 + 43 1809 + 80 899 37 1142 +59 1547 + 92 489 90 1652 + 89 930- 62 906 -29 K-40 3775 +/- 94 3367 153 4773 + 115 4082 -138 2668 + 179 5975 +/- 248 3415 +/- 161 3200 +/- 167 2770 +/- 57 1-131<11<15<11<15<17<24<24<16<8 Cs-134<7<10<8<9<15<17<15<11<4 Cs-137<6<10<6<8<12<16<14<13<4 Pb-2 10<936 2004 +/- 342<991<1301<1921<2358<830<1908 502 + 112 Pb-212<30<79 16 +/- 5<48<58<74<108<58<28 Ra-226<126<262<131<182<269<321<271<252<88 Ra-228 38 + 8<35<27<32<46<67<43<49<14 7 of 7 SL QR 3Q-2007 ST. LUCIE SITE Offsite Dose Calculation Manual Specification Sampling Third Quarter, 2007 Collection Frequency Locations Sampled Sample Type 1. Direct Radiation 2. Airborne 2.a. Air lodines 2.b. Air Particulates Quarterly Weekly Weekly 27 Number of Samples 27 65 65 3. Waterborne 3.a. Surface Water 3.b. Shoreline Sediment 4. Ingestion 4.a. Fish and Invertebrates 4.a.1. Crustacea 4.a.2. Fish 4.b. Broadleaf Vegetation Weekly Monthly Semiannually Semiannually Semiannually Monthly 5 5 1 2 2 2 3 13 3 2 2 1 9 Total: 187 NOTE: Measurement results having magnitudes that are significantly above the background of the measurement system are reported as net values plus or minus a one-standard-deviation error term. Measurement results that are not significantly above background and with greater than a 50% error term are reported as less than a Lower Limit of Detection
(<LLD), which is an estimated upper limit (with at least 95% confidence) for the true activity in the sample.The marine fauna listed in this report were collected in part, under Florida FWC SAL030.1 of 7 SL QR 3Q-2007 1. DIRECT RADIATION
-TLDs -(uRthour)Sample Site N-1 NNW-5 NNW-1O0 NW-5 NW-10 WNW-2 WNW-5 WNW-10 W-2 W-5 W-10 WSW-2 WSW-5 WSW-10 Deployment 12-Jun-07 Collection 05-Sep-07 5.1+/-0.6 4.9 +/- 0.6 5.4 +/- 0.6 4.8 +/- 0.7 6.4 +/- 0.8 4.8 +/- 0.7 4.3 +/- 0.6 6.1+/-0.7 4.9 +/-0.6 5.5 +/-0.7 5.4+/-0.6 5.5 0.5 5.2 +/-0.8 4.7 0.6 Sample Site SW-2 SW-5 SW-10 SSW-2 SSW-5 SSW-10 S-5 S-10 S/SSE-10 SSE-5 SSE-10 SE-1 H-32 Deployment 12-Jun-07 Collection 05-Sep-07 5.1+/- 0.6 6.4+/-0.7 5.3 +/- 0.5 4.9 +/- 0.5 5.9+0.4 5.3 +/- 0.4 5.0 +/- 0.5 5.2 +/- 0.5 5.6 +/- 0.3 4.4+/-0.4 5.2 +/- 0.4 4.6 +/- 0.5 5.3 +/- 0.4 2 of 7 SL QR 3Q-2007 2.a. IODINE-131 IN WEEKLY AIR CARTRIDGES
-(pCi/ in 3)Collection Date 02-Jul-07 09-Jul-07 17-Jul-07 24-Jul-07 31-Jul-07 09-Aug-07 16-Aug-07 21-Aug-07 05-Sep-07 12-Sep-07 19-Sep-07 26-Sep-07 02-Jul-07 H08<0.03<0..02<0.01<0.01<0.01<0.01<0.01<0.03<0.01<0.01<0.01<0.01<0.03 H12<0.03<0.02<0.01<0.01<0.01<0.01<0.01<0.03<0.01<0.01<0.01<0.01<0.03 H14<0.03<0.02<0.01<0.01(A)<0.01<0.01<0.01<0.03<0.01<0.01<0.01<0.01<0.03 H30<0.03<0.02<0.01<0.01<0.01<0.01<0.01<0.02<0.01<0.01<0.01<0.01<0.03 H34<0.03<0.02<0.01<0.01<0.01<0.01<0.01<0.03<0.01<0.01<0.01<0.01<0.03 (A) Based on previous weeks flow rate, pump may have Estimated run time 137.6 out of 169.6 hours6.944444e-5 days <br />0.00167 hours <br />9.920635e-6 weeks <br />2.283e-6 months <br />.been off for up to 32 hours3.703704e-4 days <br />0.00889 hours <br />5.291005e-5 weeks <br />1.2176e-5 months <br />.3 of 7 SL QR 3Q-2007 2.b.1. AIR PARTICULATES
-GROSS BETA -(nCi/m 3)Collection Date 02-Jul-07 09-Jul-07 17-Jul-07 24-Jul-07 31-Jul-07 09-Aug-07 16-Aug-07 21-Aug-07 27-Aug-07 05-Sep-07 12-Sep-07 19-Sep-07 26-Sep-07 Average: H08<0.008 0.003 +/- 0.001 0.003 +/- 0.001 0.006 +/- 0.002 0.012 +/- 0.002 0.018 +/- 0.002 0.012 + 0.002 0.016 +/- 0.003 0.012 +/- 0.002 0.015 + 0.002 0.009 +/- 0.002 0.011 +/- 0.002 0.007 + 0.002 0.010 +/- 0.001 H12<0.009 0.008 +/- 0.002 0.013 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 0.016 +/- 0.002 0.010 +/- 0.002 0.017 +/- 0.003 0.009 +/- 0.002 0.016 +/- 0.002 0.013 +/- 0.002 0.012 +/- 0.002<0.006 0.011 +/- 0.001 H14 0.005 +/- 0.002 0.003 +/- 0.001 0.006 +/- 0.001 0.009 + 0.002(A)0.011 +/- 0.002 0.017 +/- 0.002 0.009 +/- 0.002 0.012 +/- 0.003 0.011 +/- 0.002 0.016 +/- 0.002 0.009 +/- 0.002 0.018 +/- 0.002 0.008 +/- 0.002 0.010 +/- 01001 H30 0.005 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.011 +/- 0.002ý0.009 +/- 0.002 0.016 +/- 0.002 0.006 +/- 0.002 0.046 0.004 0.010 +/- 0.002 0.014 +/- 0.002 0.004 0.002 0.008 -0.002<0.007 0.011 +/- 0.001 H34 0.011 +/- 0.002 0.008 +/- 0.002 0.010 +/- 0.002 0.007 +/- 0.002 0.010 +/- 0.002 0.012 +/- 0.002 0.010 +/- 0.002 0.016 +/- 0.003 0.009 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.009 +/- 0.002 0.005 +/- 0.002 0.010 +/- 0.001 (A) Based on previous weeks flow rate, pump may have been off for up to 32 hours3.703704e-4 days <br />0.00889 hours <br />5.291005e-5 weeks <br />1.2176e-5 months <br />. Estimated run time 137.6 out of 169.6 hours6.944444e-5 days <br />0.00167 hours <br />9.920635e-6 weeks <br />2.283e-6 months <br />.2.b.2. AIR PARTICULATES
-GAMMA ANALYSIS OF QUARTERLY COMPOSITES
-(pCi/ms)Third Quarter, 2007 Sample Site H08 H12 H14 H30 H34 Be-7 0.1395 +/- 0.0105 0.1276 +/- 0.0146 0.1119 +/- 0.0112 0.1238 +/- 0.0164 0.1301 +/- 0.0138 K-40<0.0201<0.0229<0.0203 0.1455 -0.0198<0.0303 Cs-134<0.0012<0.0015<0.0009<0.0028<0.0014 Cs-137<0.0009<0.0015<0.0009<0.0020<0.0007 Pb-2 10 0.0161 +/- 0.0041<0.0606 0.0174 +/- 0.0036<0.1001<0.0510 4 of 7 SL QR 3Q-2007 3.a. SURFACE WATER -(pCi/L)Sample Site Collection Date H15 02-Jul-07 09-Jul-07 17-Jul-07 24-Jul-07 31-Jul-07 09-Aug-07 16-Aug-07 21-Aug-07 27-Aug-07 05-Sep-07 12-Sep-07 19-Sep-07 26-Sep-07 H59 02-Jul-07 09-Aug-07 12-Sep-07 H-3<167<167<166<139<139<139<139<138<133<133<133<133<128<167<139<133 Zr-95 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 (A)394 +/- 34 <3 <3 <8 <3 <7 <6 352 +/- 45 <4 <5 <6 <7 <11 <6 401 +/- 30 <2 <3 <6 <3 <6 <5 382 +/- 26 <3 <2 <4 <3 <6 <4 359 +/- 24 <2 <2 <4 <2 <5 <4 266 +/- 43 <4 <5 <9 <5 <11 <8 331 +/- 35 <3 <3 <8 <4 <8 <6 410 +/- 33 <3 <3 <8 <4 <7 <5 371 +/- 31 <3 <3 <6 <4 <7 <5 348 +/- 32 <3 <3 <6 <3 <8 <5 366 +/- 33 <2 <2 <5 <3 <5 <5 347 +/- 30 <3 <3 <7 <3 <8 <6 297 +/- 31 <4 <3 <5 <3 <7 <6 392 +/- 33 <2 <2 <5 <3 <5 <4 341 +/- 37 <4 <3 <6 <5 <8 <6 311 +/- 44 <4 <4 <8 <4 <8 <6<7<5<3<3<2<6<5<4<4<5<3<4<5<4<5<5 Ba- 140 1-131 Cs-134 Cs-137 La-140<4<5<3<3<3<6<4<4<4<4<3<3<4<3<5<4<4<5<3<3<2<4<3<4<4<4<2<4<4<3<4<4 (B)<4<7<6<7<5<6<4<10<7<5<4<10<5<3<6<7 (A) -These tabulated LLD values for Zr/Nb-95 are the higher of the individual parent or daughter LLD's.(B) -These tabulated LLD values are for Ba-140, either based on direct measurement of Ba-140 or based on ingrowth of La-140, whichever method yields the greater sensitivity for a given sample.5 of 7 SL QR 3Q-2007 3.b. SHORELINE SEDIMENT -(pCi/kg, dry weight)Sample Collection Site Date Be-7 K-40 Co-58 H15 13-Aug-07 146+ 55 707+111 <13 H59 13-Aug-07 88 32 379 +51 <7 Co-60<16<9 Cs-134<15<9 Cs-137<13<8 Pb-2 10<1114<383 Ra-226 434+/- 129 194 +/- 85 Th-232 157 19 58 +/- 10 Others: U-238 569 +/- 128 4.a. 1. CRUSTACEA
-(pCi/kg, wet weight)Sample Collection Site Date K-40 H15 27-Sep-07 2272 +/- 289 H59 27-Sep-07 1901 +/- 116 Mn-54<33<14 Co-58<29<15 Fe-59<63<31 Co-60<38<15 Zn-65<56<32 Cs-134<44<19 Cs-137<30<17 Ra-226<636 450 +/- 153 Ra-228<174 187 +/- 29 4.a.2. FISH -(pCi/kg, wet weight)Sample Collection Site Date K-40 Mn-54 H15 This sample was not yet collected.
H59 27-Sep-07 2864 +/- 261 <28 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 Ra-226 Ra-228<19<66<40<72<39<31<574<131 6 of 7 SL QR 3Q-2007 4.b. BROADLEAF VEGETATION
-Brazilian PeDper -(pCi/ka. wet weiaht)Sample Site H51 H52 H59 Collection Date 02-Jul-07 09-Aug-07 12-Sep-07'02-Jul-07 09-Aug-07 12-Sep-07 02-Jul-07 09-Aug-07 12-Sep-07 Be-7 973 + 97 1004 78 988 117 672 -71 911 40 873 -86 1180 106 895 +/- 36 899 +/--71 K-40 5035 +/- 259 5412 +/- 257 3863 +/- 257 4720 +/- 183 5277 +/- 135 5013 +/- 235 3207 +/- 213 4038 +/-78 3417 153 1-131<33<22<25<24<11<23<30<8<19 Cs-134<19<22<22<13<9<18<19<6<11 Cs-137<18<16<18<12<7<18<18<5<13 Pb-2 10<2549<2488<2406<841<1107<2178<2565<318<523 Pb-212<88<74<89<92<35 51 +/- 15<76<34<84 Ra-226<357 406 +/- 177<370<280<151<338<350<105<256 Ra-228<76<74<76<36,<31<67<59<18<37 7 of 7 SL QR 4Q-2007 ST. LUCIE SITE Offsite Dose Calculation Manual Specifications Sampling Fourth Quarter, 2007 Number of Samples Sample Type Collection Frequency Locations Sampled 1. Direct Radiation 2. Airborne 2.a. Air lodines 2.b. Air Particulates Quarterly Weekly Weekly 27 3. Waterborne 3.a. Surface Water 3.b. Shoreline Sediment 4. Ingestion 4.a. Fish and Invertebrates 4.a.1. Crustacea 4.a.2. Fish 4.b. Broadleaf Vegetation Weekly Monthly Semiannually Semiannually Semiannually Monthly 5 5 1 1 2 2 2 3 27 65 65 13 3 0 0 1 9 Total: 183 NOTE: Measurement results having magnitudes that are significantly above the background of the measurement system are reported as net values plus or minus a one-standard-deviation error term. Measurement results that are not significantly above background are reported as less than a Lower Limit of Detection
(<LLD), which is an estimated upper limit (with at least 95%confidence) for the true activity in the sample.The marine fauna listed in this report were collected in part, under Florida FWC SAL030.1 of 7 SL QR 4Q-2007 1. DIRECT RADIATION
-TLDs -(IARihour)
Sample Site N-i NNW-5 NNW-10 NW-5 NW-10 WNW-2 WNW-5 WNW-10 W-2 W-5 W-10 WSW-2 WSW-5 WSW-10 Deployment 05-Sep-07 Collection 12-Dec-07 4.3 +/- 0.4 4.6 +/- 0.4 5.2+/-0.3 4.8 +/- 0.3 6.4 +/- 0.6 5.0 +/- 0.4 4.5 +/- 0.4 5.3 +/- 0.4 4.6 +/- 0.3 4.9 +/- 0.5 4.5 +/- 0.5 5.1 +/- 0.6 4.7 +/- 0.4 4.4 +/- 0.4 Sample Site SW-2~SW-5 SW-10 SSW-2 SSW-5 SSW-10 S-5 S-10 S/SSE-10 SSE-5 SSE-10 SE-i H-32 Deployment 05-Sep-07 Collection 12-Dec-07 4.9 +/- 0.5 6.1+/- 0.5 4.7 +/- 0.4 4.9 +/- 0.4 6.2+/-0.6 5.9 +/- 0.6 5.3+/-0.4 5.1 +/- 0.5 4.9 +/- 0.4 4.3 +/- 0.4 5.0 +/- 0.6 4.7 +/- 0.4 5.1 +/- 0.4 2 of 7 SL QR 4Q-2007 2.a. IODINE-1 31 IN WEEKLY AIR CARTRIDGES
-(pCi/ i 3)Collection Date H08 H12 H14 H30 H34 02-Oct-07
<0.01 <0.01 <0.01 <0.01 <0.01 09-Oct-07
<0.02 <0.02 <0.02 <0.02 <0.02 16-Oct-07
<0.02 <0.02 <0.02 <0.02 <0.04(A)22-Oct-07
<0.02 <0.02 <0.02 <0.02 <0.02(B)29-Oct-07
<0.02 <0.02 <0.02 <0.02 <0.02 07-Nov-07
<0.01 <0.01 <0.01 <0.01 <0.01 14-Nov-07
<0.01 <0.01(C) <0.01 <0.01 <0.01 20-Nov-07
<0.01 <0.01 <0.01 <0.01 <0.01 28-Nov-07
<0.01 <0.01 <0.01 <0.01 <0.01 05-Dec-07
<0.01 <0.01 <0.01 <0.01(D) <0.01 10-Dec-07
<0.03 <0.03 <0.02 <0.03 <0.03 18-Dec-07
<0.02 <0.02 <0.02 <0.02 <0.02 26-Dec-07
<0.01 <0.01 <0.01 <0.01 <0.01 (A) Pump not running properly and was replaced.
Estimated run time 69 out of 168.5 hours5.787037e-5 days <br />0.00139 hours <br />8.267196e-6 weeks <br />1.9025e-6 months <br />.(B) Outlet was bad. Pump plugged into another outlet and ran fine. Outlet was replaced at a later date. Normal run time.(C) Pump running; possible power outage at some point during sampling period. Estimated run time 132.6 out of 163.3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />.(D) Pump running; possible power outage at some point during sampling period. Estimated run time 144.9 out of 170.8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />.3 of 7 SL QR 4Q-2007 2.b. 1. AIR PARTICULATES
-GROSS BETA -(pCi/m 3)Collection Date 02-Oct-07 09-Oct-07 16-Oct-07 22-Oct-07 29-Oct-07 07-Nov-07 14-Nov-07 20-Nov-07 28-Nov-07 05-Dec-07 10-Dec-07 18-Dec-07 26-Dec-07 Average: H08 H12 H14 H30 H34 0.010 +/- 0.002 0.005 +/- 0.002 0.021 +/- 0.002 0.010 +/- 0.002 0.013 +/- 0.002 0.020 + 0.002 0.023 + 0.002 0.029 + 0.003 0.018 +/- 0.002 0.011 + 0.002 0.018 +/- 0.003 0.014 +/- 0.002 0.011 +/- 0.002 0.016 +/- 0.001 0.007 + 0.002 0.007 +/- 0.002 0.020 +/- 0.002 0.011 +/- 0.002 0.013 +/- 0.002 0.009 +/- 0.002 0.027 -0.003(C)0.020+/- 0.002 0.020 +/- 0.002 0.016 +/- 0.002 0.021 +/- 0.003 0.012 +/- 0.002 0.011 +/- 0.002 0.015 +/- 0.001 0.009 +/- 0.002 0.007 +/- 0.002 0.014 +/- 0.002 0.008 +/- 0.002 0.014 +/- 0.002<0.005 0.024 +/- 0.003 0.020 +/- 0.003 0.021 +/- 0.002 0.012 +/- 0.002 0.017 +/- 0.003 0.010 +/- 0.002 0.006 +/- 0.002 0.012 + 0.001 0.008 +/- 0.002 0.007 +/- 0.002 0.020 +/- 0.002 0.004 + 0.002 0.015 +/- 0.002 0.017 +/- 0.002 0.025 +/- 0.002 0.016 +/- 0.002 0.017 +/- 0.002 0.012 +/- 0.002(D)0.021 +/- 0.003 0.011 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.001 0.011 + 0.002 0.005 -0.002 0.023 +/- 0.005(A)0.008 +/- 0.002(B)0.013 +/- 0.002 0.013 +/- 0.002 0.021 +/- 0.002 0.018 +/- 0.002 0.017 +/- 0.002 0.014 + 0.002 0.014 +/- 0.003 0.009 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.001 (A) Pump not running properly and was replaced.
Estimated run time 69 out of 168.5 hours5.787037e-5 days <br />0.00139 hours <br />8.267196e-6 weeks <br />1.9025e-6 months <br />.(B) Outlet was bad. Pump plugged into another outlet and ran fine. Outlet was replaced at a later date. Normal run time.(C) Pump running; possible power outage at some point during sampling period. Estimated run time 132.6 out of 163.3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />.(D) Pump running; possible power outage at some point during sampling period. Estimated run time 144.9 out of 170.8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />.2.b.2. AIR PARTICULATES
-GAMMA ANALYSIS OF OUARTERLY COMPOSITES
-(nCi/m 3)Fourth Quarter, 2007 Sample Site H08 H12 H14 H30 H34 Be-7 0.1644 + 0.0138 0.1703 +/- 0.0125 0.1740 +/- 0.0124 0.1388 +/- 0.0113 0.1600 +/- 0.0046 K-40<0.0200<0.0167<0.0167<0.0197<0.0073 Cs-134<0.0011<0.0011<0.0012<0.0011<0.0005 Cs-137<0.0008<0.0010<0.0006<0.0010<0.0004 Pb-2 10 0.0269 +/- 0.0046 0.0326 +/- 0.0037<0.01 12 0.0240 +/- 0.0034<0.0163 4 of 7 SL QR 4Q-2007 3.a. SURFACE WATER -(pCi/L)Sample Site Collection Date H15 02-Oct-07 09-Oct-07 16-Oct-07 22-Oct-07 29-Oct-07 07-Nov-07 14-Nov-07 20-Nov-07 28-Nov-07 05-Dec-07 10-Dec-07 18-Dec-07 26-Dec-07 H59 02-Oct-07 07-Nov-07 03-Dec-07 H-3<134<134<143<143<147<146<146<146<146<143<143<143<134<134<146<143 Zr-95 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 (A)413 +/- 36 <3 <3 <5 <4 <8 <5 337 +/- 43 <4 <3 <9 <4 <9 <7 318 +/- 40 <4 <4 <8 <4 <10 <6 345 +/- 39 <3 <3 <6 <4 <6 <5 334+/- 32 <4 <3 <6 <4 <8 <7 373 +/- 45 <4 <4 <9 <4 <11 <8 367 +/- 23 <2 <3 <6 <3 <6 <5 297 +/- 62 <5 <5 <8. <5 <13 <8 336 +/- 31 <2 <2 <4 <2 <5 <3 415 +/- 28. <3 <3 <6 <3 <7 <5 315 +/- 34 <2 <2 <5 <3 <5 <4 421 +/- 15 <1 <2 <3 <2 <3 <3 384 +/- 32 <3 <3 <6 <4 <6 <5 279 +/- 42 <4 <4 <9 <5 <8 <6 358 +/- 33 <2 <2 <5 <3 <5 <4 295 +/- 40 <4 <4 <9 <4 <8 <7<4<4<4<3<4<5<4<8<3<4<3<2<6<5<2<5 Ba- 140 1-131 Cs-134 Cs-137 La-140<5<5<5<4<4<6<3<6<2<4<3<2<3<4<3<5<4<4<4<3<3<5<3<5<2<3<2<2<3<4<2<5 (B)<10<10<11<8<5<10<4<6<3<5<4<3<5<5<4<10 (A) These tabulated LLD values for Zr/Nb-95 are the higher of the individual parent or daughter LLDs.(B) These tabulated LLD values are for Ba-140, either based on direct measurement of Ba-140 or based on ingrowth of La-140, whichever method yields the greater sensitivity for a given sample.5 of 7 SL QR 4Q-2007 3.b. SHORELINE SEDIMENT -(pCi/kg, dry weight)Sample Collection Site Date Be-7 K-40 Co-58 H15 This sample was previously collected.
H59 This sample was previously collected.
Others: Pb-210 Ra-226 Th-232 U-238 Co-60 Cs-134 Cs-137 4.a.1. CRUSTACEA
-(pCi/kg, wet weight)Sample Collection Site Date K-40 Mn-54 Co-58 Fe-59 H15 This sample was previously collected.
H59 This sample was previously collected.
Co-60 Zn-65 Cs-134 Cs-137 Ra-226 Ra-228 4.a.2. FISH -(pCi/kg, wet weight)Sample Site H15 H59 Collection Date K-40 Mn-54 09-Oct-07 3277+/- 222 <14 This sample was previously collected.
Co-58<15 Fe-59<42 Co-60<22 Zn-65<52 Cs-134<21 Cs-137<22 Ra-226<300 Ra-228<71 6 of 7 SL QR 4Q-2007 4.b. BROADLEAF VEGETATION
-Brazilian Pepper -(pCi/kc. wet weiaht)Sample Site H51 H52 H59 Collection Date 02-Oct-07 07-Nov-07 03-Dec-07 02-Oct-07 07-Nov-07 03-Dec-07 02-Oct-07 07-Nov-07 03-Dec-07 Be-7 1718 +/- 95 2096 +/- 49 1699+/- 115 1377 +42 1919 102 1916+/- 83 1635 + 49 1883 +/- 36 1558+ 120 K-40 4383 +/- 198 2071 +/- 97 2921 +/- 197 5186 +/- 88 2127 +/- 168 2986+/- 138 3118+/- 110 2404 +/- 51 2999 +/- 195 1-131<22<10<26<10<25<22<13<8<30 Cs- 134<16<7<17<6<17<12<9<4<17 Cs-137<15<7<16<5<18<9<8<5<18 Pb-210<1869<938<2324<358<2352<708<1006 626 +/- 159<2501 Pb-212 41 +/- 9 38+/-5<76<38 77 +/- 12<86 40+/- 5<31<91 Ra-226<271<138<326<118<348<228<151<98<350 Ra-228<56<23<47<20<55<33<27<14<75 7 of 7 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 ATTACHMENT C AMENDED RESULTS FROM THE INTERLABORATORY COMPARISON PROGRAM 2007 DEPARTMENT OF ENERGY MAPEP 17, June 2007 AND MAPEP 18, December 2007 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS 1 & 2 Result DOE-MAPEP Ref.Value 17 RESULTS Flag (Evaluation)
Acceptance Ranqe Radionuclide Matrix: RdF Air Filter Bq/filter MN54 C057 C060 ZN65 CS134 CS137 Am241 U234/233 0 U238 0 4.17 3.81 3.11 2.77 4.52 2.95 0.11.0998.1079 Matrix: GrF Air Filter Bq/filter Gross Beta .050 Matrix: MaS Soil Bq/kg K40 620.33 MN54 706.67 C057 493.33 C060 269.67 ZN65 563.3 CS134 319.26 CS137 808.67 U238 194.67 AM241 35.73 Matrix: MaW Water Bq/L H3 293.75 MN54 133.17 C057 145.1 C060 28.41 ZN65 126.13 CS134 84.74 CS137 170.7 AM241 1.90 Matrix: RdV Vegetation, Bq/sample:
MN54 7.59 C057 7.01 C060 5.03 ZN65 6.05 CS134 5.63 CS137 6.35 3.5185 2.8876 2.9054 2.6828 4.1960 2.5693 0.0977 0.0981 0.1021 0.441 602 685.2 471.2 274.7 536.8 327.4 799.7 192.4 34.8 283.0 123.8 143.7 26.9 114.8 83.5 163.0 1.71 8.4492 8.1878 5.8215 5.6991 6.2101 6.9949 A N A A A A ,A A A A A A A A A A A A A A A A A A A A A 2.4603 -4.5741 2.0213 -3.7539 2.0338 -3.7770 1.8780 -3.4876 2.9372 -5.4548 1.7985 -3.3401 0.0684 -0.1270 0.0687 -0.1275 0.0715 -0.1327 0:221 -0.662 421 -783 479.6 -890.8 329.8 -612.6 192.3 -357.1 375.8 -697.8 229.2 -425.6 559.8 -1039.6 134.7 -250.1 24.4 -45.2 198.1 -367.9 86.7 -160.9 100.6 -186.8 18.8-35.0 80.4 -149.2 58.5- 108.6 114.1 -211.9 1.20-2.22 A A A A A A 5.9144 -10.9840 5.7315 -10.6441 4.0751 -7.5680 3.9894 -7.4088 4.3471 -8.0731 4.8964 -9.0934 Evaluation A = Acceptable, W Acceptable with Warning, N = Not Acceptable 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 DOE-MAPEP 18 RESULTS Result Ref. Flag Acceptance Radionuclide Matrix: RdF Air Filter Bq/filter MN54 C057 C060 ZN65 CS134 CS137 AM241 U238 Matrix: GrF Air Filter Bq/filter Gross Beta Matrix: MaS Soil Bq/kg K40 MN54 C057 C060 ZN65 CS134 CS137 Am241 U238 Matrix: MaW Water Bq/L H3 MN54 C057 C060 N163 ZN65.SR9O CS134 CS137 Am241 Matrix: RdV Vegetation, Bq/sa MN54 C057 C060 ZN65 CS134 CS137 AM241 Value (Evaluation)
Ranqe 0.004 3.58 1.28 2.32 2.34 2.59 0.16 0.20 0.33 632.57 617.70 461.2 8.41-6.71 881.67 580 140.67 158.37 506.83 12.78 22.23 8.48 26.05 17.69 12.5-0.01-0.08 1.2 mple: 4.22 6.34 2.36-0.10 5.51 2.99 0.29 3.55 1.31 2.04 2.52 2.70 0.158 0.225 0.286 571 570 421 2.9 854 545 127.2 148 472 12.1 22.8 8.40 30.7 16.3 11.40 1.23 4.74 6.89 2.77 6.28 3.41 0.240 Sensitivity Eval.2.49 -4.62 0.92-1.70 1.43- 2.65 1.76-3.28 1.89- 3.51 0.111 -0.205 0.158 -0.293 0.143 -0.429 400 -742 399 -741 295 -547 Sensitivity Eval.Blank (no activity)598- 1110 382 -709 89.0- 165.4 104- 192 330-614 8.5- 15.7 16.0-29.6 5.88- 10.92 21.5- 39.9 11.4-21.2 7.98- 14.82 Blank (no activity)Blank (no activity)0.86-1.60 3.32-6.16 4.82- 8.96 1.94-3.60 Blank (no activity)4.40- 8.16 2.39-4.43 0.198 -0.312 A A A A A A W Evaluation
- A = Acceptable, W = Acceptable with Warning, N = Not Acceptable 2007 AMENDED ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT ST. LUCIE PLANT -UNITS I & 2 Footnote for MAPEP Evaluation:
From the MAPEP handbook: Acceptance criteria were developed from a review of precision and accuracy data compiled by other PEPs, the analytical methods literature, from several MAPEP pilot studies, and from what is considered reasonable, acceptable, and achievable for routine analyses among the more experienced laboratories.