ML14122A060

Radioactive Effluent Release Report, Radioactive Effluent Control Program Report, Offsite Dose Calculation Manual and Process Control Program for 2013

ML14122A060
Person / Time
Site:	Zion  File:ZionSolutions icon.png
Issue date:	04/28/2014
From:	Bouchard G ZionSolutions
To:	Document Control Desk, NRC/FSME
References
ZS-2014-0100
Download: ML14122A060 (24)

Text

ZIONSOLUTIONSLLC An Emr dtloSfl Company April 28, 2014 ZS-2014-0100 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, DC 20555-0001 Zion Nuclear Power Station, Units I and 2 Facility Operating License Nos. DPR-39 and DPR-48 NRC Docket Nos. 50-295, 50-304 and 72-1037

Subject:

Radioactive Effluent Release Report, Radioactive Effluent Control Program Report, Offsite Dose Calculation Manual and Process Control Program for 2013.

In accordance with Facility Operation License Nos. DPR-39 and DPR-48, Appendix A, Technical Specification 5.7.3, "Radioactive Effluent Release Report," for Zion Nuclear Power Station, Units 1 and 2, this is the submittal of a Radioactive Effluent Release Report for the year 2013. The report is required to be submitted prior to May 1, 2014 and is provided as Attachments 1 through 6 to this letter. A listing of commitments contained in this submittal is provided in Attachment 1. Certificate of Compliance No. 1031 for the MAGNASTOR SYSTEM, Appendix A, Technical Specifications 5.1.1 and 5.1.3 require submittal of an Annual Radioactive Effluent Control Program report which is included in this document.

Pursuant to 10 CFR 50.4 and Technical Specification 5.6.1 .c. there were changes made to the Zion Station Offsite Dose Calculation Manual (ODCM) during the period of January through December 2013. Attachment 1, Supplemental Information, summarizes the changes made to the ODCM during the calendar year of 2013. Attachment 7 is a copy of Zion Station ODCM, current as of December 31, 2013.

There are no new regulatory commitments in this submittal.

If you have any questions about this submittal please contact Mr. Christopher Keene at (224)789-4073.

Respectfully, VP Operations & Engineering & Decommissioning Plant Manager ZionSolutions, LLC A 00 101 Shiloh Boulevard, Zion - IL60099 (224) 789-4016

• Fax: (224) 789-4008

• www.zionsolutionscompany.com

ZionSolutions, LLC ZS-2014-0 100 Page 2 of 2 Attachments:

1. Supplemental Information

2. Effluent & Waste Disposal Summary 2.1. Unit 1 Gaseous Effluent 2.2. Unit 2 Gaseous Effluent 2.3. Liquid Effluent 2.4. Direct Radiation 2.5. LLIYs 2.6. Error Estimation

3. Solid Waste and Irradiated Fuel Shipments

4. Radiological Impact on Man 4.1. 40CFR190 & 10CFR72 Compliance summary 4.2. Unit 1 4.3. Unit 2 4.4. ISFSI 4.5. Combined 40CFR190 report

5. Meteorology Data

6. Errata Data from previous years

7. Zion Station ODCM

8. ZS-WM-123 Process Control Program Requirements cc: John Hickman, U.S. NRC Senior Project Manager Service List

Zion Nuclear Power Station, Unit 1 and 2 License Transfer Service List cc:

Alan Parker Russ Workman President Projects Group General Counsel EnergySolutions EnergySolutions 1009 Commerce Park Drive, Ste. 100 423 West 300 South, Ste. 200 Oak Ridge, TN 37830 Salt Lake City, UT 84101 John Sauger Alwyn C. Settles Senior VP & General Manager Section Head, Nuclear Facility Inspection ZionSolutions, LLC Bureau of Nuclear Facility Safety 101 Shiloh Boulevard Illinois Emergency Management Agency Zion, IL 60099 1011 North St., PO Box 250 Mazon, IL 60444 Gary Bouchard VP Ops, Engineering, and Kent McKenzie Decommissioning Plant Manager Emergency Management Coordinator ZionSolutions, LLC Lake County Emergency Management Agency 101 Shiloh Boulevard 1303 N. Milwaukee Avenue Zion, IL 60099 Libertyville, IL 60048-1308 Gerard van Noordenmen Regional Administrator VP Regulatory Affairs U.S. NRC, Region III ZionSolutions, LLC 2443 Warrenville Road 101 Shiloh Boulevard Lisle, IL 60532-4352 Zion, IL 60099 John E. Matthews Dan Shrum Morgan, Lewis & Bockius LLP Senior VP Regulatory Affairs 1111 Pennsylvania Avenue, NW EnergySolutions Washington, DC 20004 423 West 300 South, Ste. 200 Salt Lake City, UT 84101

ZionSolutions LLC ZS-2014-0100: Attachment I - Supplemental Information

1. Regulatory Limits: The dose to a member of the public fi'om direct radiation, liquid and gaseous effluents released friom each unit to areas at or beyond site boundary shall be limited to the following:

a. Fission and Activation products:

i. Tech Spec Whole Body: 500 norero/year ii. Tech Spec Skin: 3000 morem/year

b. Particulates with half-lives > 8 days, tritium and Iodine:

i. Tech Spec Organ: 1500 orero/year ii. 10CFR50 Organ: 7.5 mrem/quarter, 15 mrem/year

c. Liquid Effluents:

i. IOCFR50 Whole body: 1.5 mrem/quarter, 3 mrem/year ii. IOCFR50 Organ: 5 torem/quarter. 10 torem/year

d. Combined dose to real individual beyond controlled area:

i. 10CFR72 Whole body: 25 torem/year ii. IOCFR72 Thyroid: 75 mrem/year iii. 10CFR72 Organ: 25 mrem/year

2. Effluent Concentration Limits (ECL): Limits used in determining allowable release rates or concentrations.

a. Gaseous Effluents: I OCFR20 Appendix B Table 2 Column 1.

b. Liquid Effluents: 10 X IOCFR20 Appendix B Table 2 Column 2.

3. Measurements and Approximations of Total Radioactivity.

a. Fission and Activation Products: 100% Kr-85 is assumed in calculations since other isotopes have decayed. Vent stack activity is continuously monitored for fission and activation gases.

b. Particulate and tritium releases are continuously monitored and samples collected and analyzed weekly. Particulate filters are sent to an independent lab for quarterly composite analysis. Tritium activity is monitored in gaseous releases from evaporation of water in the spent fuel pool and water filled reactor cavities.

c. Liquid effluents are continuously monitored and isotopic analysis performed weekly.

d. Occupancy factors to accurately estimate dose due to habits of the real individual that are used to calculate maximum exposed member of the public are discussed in ES&H Technical Support Document 13-009 "Member of the Public Dose from All Onsite Sources."

4. Batch Releases:

a. Liquid: There were no liquid batch releases in 2013.

b. Gaseous: There were no gaseous batch releases in 2013.

5. Abnormal Releases:

a. Liquid: There were no liquid abnormal releases in 2013.

b. Gaseous: there were no gaseous abnormal releases in 2013.

ZionSolutions LLC ZS-2014-01 00: Attachment I - Supplemental Information

6. Gaseous and Liquid Waste Treatment Systems and Process Control Program Zion Station ODCM Section 12.7.2 pursuant to ODCM Section 12.7.4 requires major changes to the Gaseous and Liquid Waste Treatment Systems to be reported in the Annual Radioactive Effluent Release Report. There are major changes ongoing with the physical configuration of the liquid radwaste system. along with associated DSAR and ODCM descriptive changes; however the changes were not completed and further revisions were being evaluated as of Dec. 3 1, 2013; therefore the completed change package will be submitted in the reporting year during which the change was complete.

Zion Station ODCM Section 12.6.2 requires major changes to the Process Control Program(PCP) to be submitted in the Annual Radioactive Effluent Release Report. There were no major changes to the PCP.

The Waste Gas Hold-up System was permanently vented. In Zion's defueled configuration this system is no longer applicable.

In Zion's defueled configuration, the charcoal iodine removal system is no longer applicable.

Due to radioactive decay and no means of production, radioactive iodine is not a concern at Zion.

7. Limiting Conditions of Operation (LCOs)

Zion Station ODCM Section 12.7.2 requires explanation as to why the inoperability of liquid or gaseous monitoring instrumentation was not corrected within the time specified in the ODCM to be submitted with the Annual Radioactive Effluent Release Report.

There are no such occurrences.

8. Liquid Holdup Tanks and Gas Storage Tanks Zion Station ODCM Section 12.7.2 requires a description of events leading to liquid holdup tanks or gas storage tanks exceeding technical specification limits to be included in the Annual Radioactive Effluent Release Report.

The contents of the six gas decay tanks have been sampled and determined to have negligible activity. The Gas Decay Tanks have been abandoned in place.

No liquid holdup tanks exceeded the limits of Permanently Defueled Technical Specifications 5.6.3 during 2013.

9. Offsite Dose Calculation Manual (ODCM)

Changes to the ODCM are required by Zion Station Permanently Defueled Technical Specification 5.6. 1. and ODCM Section 12.6.3 to be submitted as part of, or concurrent with, the Annual Radioactive Effluent Release Report.

ZionSolutions LLC ZS-2014-0100: Attachment I - Supplemental Information A summary of changes made to the ODCM during 2013 and an entire copy of tile ODCM, current as of December 31, 2013 are required to be submitted.

Revisions to ODCM and Process Control Program are listed below:

a. ODCM Revisions:

Chapter Section Description 10 10.2.1 Grammatical change 10 10.2.1 .1 Renamed Boric Acid Monitor Tank to Lake Release Tank; There are 2 Lake Release tanks in the new system each with a nominal capacity of 35,000 gallons.

10 10.2.1.2 Added section: The existing Holdup Tanks are added as the dedicated location to receive and store unprocessed liquid waste.

10 10.2.2.1 Revised the discussion of monitoring releases. The new radiation monitor OR-PRO4 monitors the release from the Lake Release tank that is discharging. Previously, the radiation monitor was located in the AB at the 542' elevation and the isolation valve was approximately 250 feet downstream of the radiation monitor which provided a margin of time for the monitor to process an alarm and close the valve prior to the release entering the discharge canal. This was necessary due to the discharge line connecting to the discharge canal downstream of the dilution flow stream. As such, any water thatentered the canal would be released to the lake with the dilution flow such that when the release is terminated, that water is stagnant in the canal and does not enter into the dilution stream.

10 10.2.3.1 Changed "condenser cooling" water to "service" water.

Renamed Boric Acid Monitor Tank to Lake Release Tank.

10 10.2.3.2.1 Renamed Boric Acid Monitor Tank to Lake Release Tank 10 10.2.4 Renamed Boric Acid Monitor Tank to Lake Release Tank.

II Table I I-I.b Section b. added to include new control air sample location 12 Table 12.5-1.b Section b. added to include new control air sample location I1 Table I-I .2.b Added control TLD location II Table I I-1.2.c & II- Added sections c. and d. To include TLD's placed for ISFSI 1.2.d background trending. Added section to re-establish 5 mile ring REMP TLD's.

II Figure I1-1 Renamed to figure I 1-la. and updated with new REMP monitoring locations 11 Figure I l-lb. Figure added to show5 mile ring TLD placement locations 12 Table 12.5-1 Updated table for new TLD locations.

12 Table 12.3-2.A & Removed Sr-89 from analysis, added Ni-63 12.3-2.B 12 Table 12.4-1.C & Removed Sr-89 friom analysis, added Ni-63 12.4- 1.D

ZionSolutions LLC ZS-2014-0100: Attachment 1 - Supplemental Information Chapter Section Description 12 Table 12.4-1 Note c. Removed Sr-89 from analysis, added Ni-63 12 Table 12.2-1. .A Renamed Boric Acid Monitor Tanks (BAMT) to Lake Release Tanks.

12 Table 12.2- 1. I.A. 1 Changed OR-PRO5 to OR-PRO4 12 Table 12.2-1.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank #1 12 Table 12.2-1.3.B & Added Item 3.B and 3.B.1I Lake Release tank #2 is monitored 12.2-1.3.B. I for flow from new flow meter OFI-WD-006 12 Table 12.2-2. I.A & Renamed Boric Acid Monitor Tank to Lake Release Tank.

12.2-2. I.A. 1 12 Table 12.2-2.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank #1 12 12.2-2.3.b & 12.2- Lake Release Tank #2 is monitored for flow from new flow 2.3.b. 1 meter OFI-WD006 12 Table 12.3-2.1 .A Renamed Boric Acid Monitor Tank to Lake Release Tank.

12 Table 12.2-4.3.A.4 Added Item A.4 to include 0RT-AR24 12 Table 12.2-4 Note 3 Changed note to include ORT-AR24 12 Table 12.2-3.3.A.4 Added section 4 to include ORT-AR24 12 Table 12.2-3 Deleted surveillance 13 subsections 1-4 and added surveillance Surveillance 13 for ORT-AR24 10 r 15 Table 10-2 Corrected inadvertently changed table from previous revision.

12 Table 12.2-3.3.A.2 Surveillance requirement of 0RT-AR22 changed from 14 to 12 to match ORT-AR21.

App. A A.0 Added instance of I OCFR72 App. A A.4 Added several instances of IOCFR72" App. A A.4.1.2) Added *ISFSI" to clarify contained sources App. A A.5.1 .1 Added requirements for Zion to comply with I OCFR72 App. A A.5.1.2 Added instance of"IOCFR72" App. A A.5.2 Added instance of IOCFR72.104 and added "ISFSI" to example of sources App. A A.5.2 Added instance of I OCFR72 to compliance assessment requirements App. A A.5.3 Added ISFSI direct dose contribution in compliance methodology, provided references to ISFSI NAC dose calculation for methodology, added reference to TSD#1 3-002 for occupancy factor determinations and additional regulatory requirements of IOCFR72 as additional regulations requiring compliance.

App. A Table A-I Added IOCFR72 to Compliance matrix.

App. A Table A-4 Added IOCFR72.104(a) dose limit requirements.

12 Table 12.2-4 Changed ORT-AR24 Channel function chest to Q App. A Section A.5.3 Paragraphs l&3: Changed wording referring to TSD#13-002 to: TSD 13-008 "Evaluation of Independent Spent Fuel Storage Installation and Associated Process Dose Rates" and TSD 13-009 "Member of the Public Dose from All Onsite sources" 12 Table 12.2-1 Added item 4.A Dilution flow instrument OFIT-SW54 12 Table 12.2-2 Item 3.A. I Changed "channel calibration to include sensor

ZionSolutions LLC ZS-2014-0100: Attachment I - Supplemnental Information Chapter Section Description 12 12.2-2 Item 3.B.1 Changed "channel calibration" to include sensor 12 12.2-2 Added Item 4.A OFIT-SW54 dilution flowrate instrument.

12 12.2-I Modified surveillance 1. Added Plant Manager Approval required for all releases without a rad monitor.

Chapter Section Description II Table 1I-1 .b Section b. added to include new control air sample location 12 Table 12.5-I .b Section b. added to include new control air sample location 11 Table 11-1.2.b Added control TLD location II Table I I-1.2.c & I1- Added sections c. and d. To include TLD's placed for ISFSI 1.2.d background trending. Added section to re-establish 5 mile ring REMP TLD's.

II Figure I I-1 Renamed to figure 1 I -Ia. and updated with new REMP monitoring locations II Figure I1-I b. Figure added to show 5 mile ring TLD placement locations 12 Table 12.5-1 Updated table for new TLD locations.

12 Table 12.3-2.A & Removed Sr-89 from analysis, added Ni-63 12.3-2.B 12 Table 12.4-1.C & Removed Sr-89 from analysis, added Ni-63 12.4- 1.D 12 Table 12.4-1 Note c. Removed Sr-89 from analysis, added Ni-63 12 Table 12.2-1. I .A Renamed Boric Acid Monitor Tanks (BAMT) to Lake Release Tanks.

12 Table 12.2-1 I.A.1 Changed OR-PRO5 to OR-PRO4 12 Table 12.2-1.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank #I 12 Table 12.2-1.3.B & Added Item 3.B and 3.B. I Lake Release Tank #2 is monitored 12.2-1.3.B. I for flow from new flow meter OFI-WD-006 12 Table 12.2-2. I.A & Renamed Boric Acid Monitor Tank to Lake Release Tank.

12.2-2.1 .A. 1 12 Table 12.2-2.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank # I 12 12.2-2.3.b & 12.2- Lake Release Tank #2 is monitored for flow from new flow 2.3.b. I meter OFI-WD006 12 Table 12.3-2. .A Renamed Boric Acid Monitor Tank to Lake Release Tank.

12 Table 12.2-4.3.A.4 Added Item A.4 to include ORT-AR24 12 Table 12.2-4 Note 3 Changed note to include ORT-AR24 12 Table 12.2-3.3.A.4 Added section 4 to include ORT-AR24 12 Table 12.2-3 Deleted surveillance 13 subsections 1-4 and added surveillance Surveillance 13 for ORT-AR24 10 r 15 Table 10-2 Corrected inadvertently changed table from previous revision.

12 Table 12.2-3.3.A.2 Surveillance requirement of ORT-AR22 changed from 14 to 12 to match ORT-AR2 1.

App. A A.0 Added instance of IOCFR72 App. A A.4 Added several instances of"IOCFR72" App. A A.4.1.2) Added "ISFSI" to clarify contained sources App. A A.5.1.1 Added requirements for Zion to comply with IOCFR72 App. A A.5.1.2 Added instance of"IOCFR72"'

ZionSolutions LLC ZS-2014-01 00: Attachment I - Supplemental Information Chapter Section Description App. A A.5.2 Added instance of IOCFR72.104 and added "ISFSI" to example of sources App. A A.5.2 Added instance of 10CFR72 to compliance assessment requirements App. A A.5.3 Added ISFSI direct dose contribution in compliance methodology, provided references to ISFSI NAC dose calculation for methodology, added reference to TSD# 13-002 for occupancy factor determinations and additional regulatory requiremnents of IOCFR72 as additional regulations requiring compliance.

App. A Table A-I Added 10CFR72 to Compliance matrix.

App. A Table A-4 Added IOCFR72.104(a) dose limit requirements.

12 Table 12.2-4 Changed ORT-AR24 Channel function chest to Q App. A Section A.5.3 Paragraphs 1&3: Changed wording referring to TSD 13-002 to: TSD 13-008 "Evaluation of Independent Spent.uel Storage Installation and Associated Process Dose Rates" and TSD 13-009 "Meemberof the Public Dose from All Onsite sources" 12 Table 12.2-1 Added item 4.A Dilution flow instrument OFIT-SW54 12 Table 12.2-2 Item 3.A. I Changed "channel calibration to include sensor 12 12.2-2 Item 3.B. 1 Changed "channel calibration" to include sensor 12 12.2-2 Added Item 4.A OFIT-SW54 dilution flowrate instrument.

12 12.2-1 Modified surveillance 1. Added plant Manager Approval required for all releases without a rad monitor.

b. Process Control Program (PCP) ZS-WM-123 Revisions:

Section Description of change 3.8 Definition of Process Control Program revised for clarity and to match Reg.

guide 1.21 rev.1 4.2.1.7 Revised notation to references 5.10 Revised Reference Bead ion exchange resin dewatering criteria wording revised.

Section 2.0 Miscellaneous metals and irradiated hardware dewatering criteria wording Section 3.0 revised.

Section Description of change 3.8 Definition of Process Control Program revised for clarity and to match Reg.

guide 1.21 rev.l 4.2.1.7 Revised notation to references 5.10 Revised Reference Bead ion exchange resin dewatering criteria wording revised.

Section 2.0 Miscellaneous metals and irradiated hardware dewatering criteria wording Section 3.0 revised.

ZionSolutions, LLC ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary Attachment 2.1 - Unit I Gaseous Releases GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Unit 1 Vent Stack REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR Fission and Activation Gases

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Iodine-131

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Particulates Half Life >= 8 days

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Tritium

1. Total Release Ci 9.35E-03. 6.5OE-03 7.50E-03 9.10E-03 3.25E-02

2. Avg. Release Rate uCi/sec 0.D0E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 GASEOUS EFFLUENTS - GROUND RELEASES - CONTINUOUS MODE REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR Fission and Activation Gases <LLD <LLD <LLD <LLD <LLD Iodines <LLD <LLD <LLD <LLD <LLD Particulates Half Life >= 8 days<LLD <LLD <LLD <LLD <LLD Tritium H-3 Ci 9.35E-03 6.50E-03 7. SE-03 9. 10E-03 3.25E-02 Totals for Period Ci 9.35E-03 6.50E-03 7. 50E-03 9. lOE-03 3. 25E-02 GASEOUS EFFLUENTS - GROUND RELEASES - BATCH MODE REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR No Batch Releases.

LLD values are listed on attachment 2.5

ZionSohittions. LLC ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary Attachment 2.2 - Unit 2 Gaseous Releases GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Unit 2 Vent Stack REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR Fission and Activation Gases

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Iodine-131

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Particulates Half Life >= 8 days

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Tritium

1. Total Release Ci 9.35E-03 6.50E-03 7.50E-03 9.10E-03 3.25E-02

2. Avg. Release Rate uCi/sec ).OOE+00 0.OOE-i00 0.OOE+00 0.OOE+00 0.OOE+D0 GASEOUS EFFLUENTS - GROUND RELEASES - CONTINUOUS MODE REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR Fission and Activation Gases <LLD <LLD <LLD <LLD <LLD Iodines <LLD <LLD <LLD <LLD <LLD Particulates Half Life >= 8 days<LLD <LLD <LLD <LLD <LLD Tritium H-3 Ci 9.35E-03 6.50E-03 7.50E-03 9. lOE-03 3. 25E-02 Totals for Period Ci 9.35E-03 6.50E-03 7. 50E-03 9. IOE-03 3.25E-02 GASEOUS EFFLUENTS - GROUND RELEASES - BATCH MODE REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR No Batch Releases.

LLD values are listed on attachment 2.5

ZionSolutions, LLC ZS-2014-01 00: Attachment 2- Effluent & Waste Disposal Summary Attachment 2.3 - Liquid Effluent Releases LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR Fission and Activation Gases

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Iodine-131

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Particulates Half Life >= 8 days

1. Total Release Ci <LLD <LLD <LLD <LLD <LLD

2. Avg. Release Rate uCi/sec <LLD <LLD <LLD <LLD <LLD Volume of liquid waste gallons 8.91E+05 9.50E+05 7.09E+05 6.27E+05 3.18E+06 Volume of dil. water gallons 3.24E+08 3.28E+08 3.31E+08 3.31E+08 1.31E+09 LIQUID EFFLUENTS - BATCH MODE REPORT FOR 2013 Units QTR 1 QTR 2 QTR 3 QTR 4 YEAR No batch releases.

LLD values are listed in attachment 2.5

ZionSohitions, LLC ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary Attachment 2.4-Direct Radiation Unit Qtr I Qtr 2 Qtr 3 Qtr 4 2013 annual dose(rnrero) cdose(mremn) dose(rnrem) dose(mrem) dose(mrern)

Unit i 2.34E+00 0.OOE+00 O.OOE+00 0.OOE+00 2.34E+00 Unit 2 2.34E+00 O.OOE+00 O.OOE+00 0.OOE+00 2.34E+00 ISFSI O.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00

ZionSohltions, LLC ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Sumnmnary Attachment 2.5-LLD's Various detectors were used on different counting platforms for the gaseous and liquid weekly effluent samples. The lower limit of detection(LLD) accompanies each counted sample and is verified to meet the following maximum LLD's:

A. Liquid Sample frequency Type of analysis Lower Limit of Detection (LLD) uCi/mL Weekly/prior to each release Principal Gamma Emitters: <5.OOE-07 Dissolved and Entrained < 1.00E-05 Gases Monthly composite Tritium <I .OOE-05 Gross Alpha <l.OOE-07 Quarterly composite Sr-90 5.OOE-08 Fe-55, Ni-63 1.OOE-06 B. Gaseous Sample frequency Type of analysis Lower Limit of Detection (LLD) uCi/mL Continuous/daily/weekly Principle gamma emitters <1 .OOE-i I Continuous Noble gas < .OOE-06 Monthly Noble Gas / Principle gamma <1.OOE-04 emitters Tritium 1.OOE-06 Quarterly composite Sr-90 <1.OOE-l I Fe-55 <3.OOE- II Ni-63 <I.OOE- I1 Gross Alpha <1.OOE-1 I

ZionSolutions, LLC ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary Attachment 2.6-Error Estimation Estimates of Total Error The following is a calculated estimate of the maximum potential total error associated with reported values in the Annual Radioactive Effluent Release Report. The Total Error is determined by calculating the square root of the sum of the squares of the individual errors.

a. Gaseous Effluents Sampling Error 5%

Calibration Error 10%

Counting Statistics Error 17%

Ssninle Vcinhrn FErrnr 10%

Total Error 23%

b. Liquid Effluents Sampling Error 5%

Calibration Error 10%

Counting Statistics Error 16%

Sample Volume Error 2%

Total Error 20%

ZionSolutions. LLC ZS-2014-0100: Attachment 3- Solid Waste and Irradiated Fuel Shipments A. Solid Waste Shipped Offsite for Burial or Disposal (Not irradiated fuel)

1. Types of Waste Total Total Est. Total Types of Waste Quantity Activity Period (m 3) (Ci) Error %

a. Spent resins, filter sludges, 3.78E+02 2.26E+01 2013 2.50E+01 evaporator bottoms, etc.

b. Dry compressible waste. 90'E+04 l.38E+0 2013 2.50E+0l contaminated equip, etc.

c. Irradiated components, control 4.40E+03 1.73E+03 2013 2.50E+0I rods, etc.

d. Other (describe) 0.OOE+00 O.O0E+00 2013 0.OOE+00

ZionSolutions. LLC ZS-2014-0100: Attachment 3- Solid Waste and Irradiated Fuel Shipments

2. Estimate of major nuclide composition (by waste type)

Major Nuclide Waste Type a. Waste Type b. Waste Type d. Waste Type d.

Composition Resins, sludges DAW Irradiated Other %

bottoms (%) contaminated components (%)

equipment (%)

Ag-I 1i0m O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Am-241 1.20E-03 5.48E-02 O.OOE+00 O.OOE+00 C- 14 1.93E-02 1.47E-01 4.97E-02 O.OOE+00 Ce- 144 5.20E-03 3.07E-0 I O.OOE+00 O.OOE+00 Cm-242 O.OOE+00 3.OOE-04 O.OOE+00 O.OOE+00 Cm-243 5.OOE-04 1.81 E-02 O.OOE+00 O.OOE+00 Cm-244 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Co-60 1.51E+O1 3.53 E+OI 5.80E+O1 O.OOE+00 Cs- 134 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Cs-137 3.42E+00 2.28E+0 I 5.30E-03 O.OOE+00 Fe-55 9.28E-02 1.77E+OI 8.67E+00 O.OOE+00 H-3 5.OOE-03 3.44E-01 1.20E-0I O.OOE+00 1-129 4.OOE-04 1.25E-02 O.OOE+00 O.OOE+00 Mn-54 O.OOE+00 3.80E-02 2.80E-03 O.OOE+00 Nb-94 2.40E-02 6.69E-02 1.00E-03 O.OOE+00 Ni-59 1.01E+00 4.51E-0I 3.03E-01 O.OOE+00 Ni-63 8.OOE+O1 2.16E+OI O.OOE+00 O.OOE+00 Ni-63am O.OOE+00 O.OOE+00 3.28 E+O I O.OOE+00 Np-237 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00 Pu-238 6.OOE-04 5.37E-02 O.OOE+00 O.OOE+00 Pu-239 3.OOE-04 1.73E-02 O.OOE+00 O.OOE+00 Pu-240 O.OOE+00 0.00E+00 O.OOE+00 O.OOE+00 Pu-241 1.41E-01 1.70E-0I 2.OOE-04 O.OOE+00 Pu-242 O.OOE+00 8.OOE-04 O.OOE+00 O.00E+00 Ra-226 O.OOE+00 O.OOE+00 7.OOE-04 O.OOE+00 Sb-125 3.68E-02 2.43E-0I 3.OOE-04 O.OOE+00 Sr-89 8.90E-03 8.24E-02 O.OOE+00 O.OOE+00 Sr-90 I. II E-0 I 2.09E-0 I 1.00E-04 O.OOE+00 Tc-99 4.60E-03 2.03 E-01 I.OOE-04 O.OOE+00 Zn-65 5.58E-02 2.01E-0I O.OOE+00 O.OOE+00

ZionSolutions, LLC ZS-2014-0100: Attachment 3- Solid Waste and Irradiated Fuel Shipments

3. Solid Waste Disposition I

Number of Shipments Mode of Transportation Destination 10 Truck Clive CWF 22 Rail Clive BWF I Truck WCS B. Irradiated Fuel Shipments (disposition)

Number of Shipments Mode of Transportation Destination 0 N/A N/A C. Changes to the Process Control Program:

Changes to the PCP are included in Attachment I along with changes to the ODCM.

ZionSolttions, LLC ZS-2014-0100: Attachment 4- Radiological Impact on Man Attachment 4.1 -40CFRI90 & IOCRF72 Compliance Summary UNIT 1, 2 & ISFSI (DOCKET Numbers 50-295, 50-304 & 72-1037)

EXECUTIVE

SUMMARY

A review of 2013 effluent data indicates that the activity released from the station was far below any regulatory limit. There was no noble gas released in 2013. This trend can be attributed to the shutdown of both units since late September 1997.

Airborne Dose to Maximally Dose to Maximally Exposed Receptor fi'om Exposed Receptor from Unit I Unit 2 Gamma Air 0.OOE+00 mrad 0.00E+00 mrad Beta Air 0.OOE+00 mrad 0.OOE+00 mrad Total Body 0.OOE+00 nirem 0.00E+00 mrem Skin 0.OOE+00 mrem 0.OOEE+00 mrem 8.25E-05 mrem (Child 8.25E-05 mrem (Child Organ Liver) Liver)

Aquatic There was NO Aquatic release of radioactivity from Zion Station for 2013.

Dose to Maximally Dose to Maximally Exposed Receptor (Any) Exposed Receptor (Any) from Unit I from Unit 2 Total Body 0 mrem 0 mrem Organ 0 mrem 0 mrem Direct Radiation Dose to Dose to Maximally Dose to Maximally Maximally Exposed Member of the Exposed Member of the Exposed Member public from Unit I public from Unit 2 of the public from ISFSI Total Body 2.34E+00mrem 2.34E+00mrem 0.00E+00mrem

ZionSolutions. LLC ZS-2014-0100: Attachment 4- Radiological Impact on Man Attachment 4.2 - Unit I I. Unit I (Docket Number 50-295)

A. 10 CFR20 & 40CFRI90 Compliance Assessment: The demonstration of compliance with 40CFR 190 will be used to demonstrate compliance with IOCFR20.

1. Total Effective Dose Equivalent 2.34+00 torero/year

2. 40 CFR 190 Whole body limit 25 mrem/year

3. 40 CFR 190 Max exposed organ 25 mrem (75 nirem thyroid)

4.  % Whole body limit 9.36E+00%

5.  % Max exposed organ 9.36E+00% child liver (3.12E+00% thyroid) 6.

Quarter I Quarter 2 Quarter 3 Quarter 4 Total TEDE 2.34E+00 1.65E-05 1.91 E-05 4.63E-05 2.34E+00 rex poe R imll reetr mrem mrem rnrern B. Maximally Exposed Receptor:

I. Airborne Yearly limit  % of Qtr Obi I" Qtr 2 ,,d Qtr 3" Qtr 4'* Qtr IOCFR 50 2(113 Yearly limit App. 1 20p1 Gamma air (mrad) 5.0 0.OOE+00 0.00E+00 0 (i0E+00 0.(iE+00 10.0 O.00E+00 0.00E+00 Beta Air (mrad) 10.0 O.00E+00 0.00E+00 O.00E+00 0.00E+i00 20.0 O.OOE+00 O.OOE+00 Total Bodv (mnrem) 7.5 2 38E-05 1.65E-05 1.91E-05 4.63E-05 15.0 8.25E-05 5.50E-06 Skin imrem) 7.5 0 00E+00 0.00E+00 0.i00E+00 0.00E+00 15.0 0 0(F+00+1 0.OOE+00 Organ lmrem) 7.5 2.38E-05 1.65E-05 1.91E-05 4.,3E-05 15.0 8.25E-05 5 50E-06 Child liver Child liver Child liver Child liver Child liver Child Critical Organ

2. Aquatic Yearly limit Total Dose  % of Qtr Obi I" Qtr 2"' Qtr 3O Qtr 4" Qtr 10CFR 50 Yearl, Y

App. I limit Total Body (mireml 2.5 O.0(E+00 (l.0IE+0(i 0.00E+001 0.00E+00 3.0. 0.0E+00 O.OOE+0 }

Organ (mi1relnl 2.5 0.OOE+00 (lOOE+00

- (i.00E+tV{} 0.00E+00 10(0 j(OE+G0 0.00E+00 Critical Organ NA NA NA NA NA NA

3. Direct Ialy limit Total Dose  % of OiJtr I" Qtr Qir 3' Qr 4dQtr 4 eary 22013 Yearly IF limit Total body (mremr 6.25 2.34E+ G.OOF--E+00 ).OE+00 l 0.0(E+(10 25 V 2.34E+i1 9.36E-02

ZionSolutions. LLC ZS-20 14-0100: Attachment 4- Radiological Impact on Man Attachment 4.3 - Unit 2 II. Unit 2 (Docket Number 50-304)

A. 10 CFR20 & 40CFR190 Compliance Assessment: The demonstration of compliance with 40CFRI90 will be used to demonstrate compliance with IOCFR20.

1. Total Effective Dose Equivalent 2.34E+00 mrem/year

2. 40 CFR 190 Whole body limit 25 mrem/year

3. 40 CFR 190 Max exposed organ 25 mrem (75 mrem thyroid)

4. % Whole body limit 9.36E+00%

5. % Max exposed organ 9.36E+00% child liver (3.12E+00% thyroid)

Quarter I Quarter 2 Quarter 3 Quarter 4 Total TEDE 2.34E+00 1.65E-05 1.9 iE-05 4.63E-05 2.34E+00 mrem mrem m re11i mrem mnrem B. Maximally Exposed Receptor:

1. Airborne Yearly limit Qtr Obi I" Qtr 2 Qtr 3 Qtr 4h QIr I OCFR 50 Total 2013 Dose  % mof early App.l I limit Gamma air (mrad) 50 0.OOE+O0 0.00E+00 0.00E+00 0.00E+00 10.0(.00E+00 O.00E+00 Beta Air (mrad) 10.(0 0.00E+00 0.00E+00 O.00El00 0.0OE+00 20.0 0.OOE+00 (i.OOE+-00 Total Body (mremn 75 2.38E-05 1.65F-05 1.91E-05 4.63E-05 150 8.25E-05 5.50E-06 Skin (tmremr) 7.5 0 00E++00 .00E+/-0('

0.E .OE+-ioo 0.)O-E+10 15.0 0 00E+00 ( ()OE+0-()

Organ (mrem) 7.5 2.38E-05 1.65E-05 1.91E-05 4.63E-05 15.0 8.25E-05 5.50E-06 Critical Organ Child liver Child liver Child liver Child liver ___ _ Child liver Child liver

2. Aquatic Qtr rYearly d limit Total Dose  % of Qtr Obj I" Qtr Qtr 3 Otr 4' Qtr I OCFR 50 2013 Yearly App. I limit Total Body (itoern) 2.5 0 OOE+00 0.00E+00 O.OO0E+ 0.00E+00 30 0 OOE+00 E O0.OOE+IO Organ Imrem) 2.5 0.OF+00Et O.O(Fi00 0.O.E+O0 010FE+00 10.0 0.OOE+00 0.00E+00 Critical Orian NA NA NA NA NA NA

3. Direct Qtr Ob r1 625 I

I.

oil "Qtr 0

I 2 ' tr

__2__t_3__

3 d' t

Qt 4' QtrI Yearly limit Total Dose 2013 [40C

% of e19l.

lim it Tlotal body, i nrem ) 2.34E+00 IO.00E+O00 O.OOE+ )O O.OOE+O0 25.C0.E00 O.OOE+00.0.E+I

ZionSolutions, LLC ZS-2014-0 100: Attachment 4- Radiological Impact on Man Attachment 4.4 - ISFSI Ill. ISFSI (Docket Number 72-1037)

A. 10CFR72 & 40CFR190 Compliance Assessment:

1. Total Effective Dose Equivalent 0.00+00 mrem/year

2. 40 CFRI90 / IOCFR72 Whole body limit 25 morem/year

3. 40 CFRI190 / IOCFR72 Max exposed organ 25 mrem (75 nirem thyroid)

4.  % Whole body limit 0.OOE+00%

5.  % Max exposed organ(child liver/thyroid) 0.OOE+00% / O.OOE+00%

Quarter I Quarter 2 Quarter 3 Quarter 4 Total TEDE 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 m rem mrem m rem iIre m Irenm B. Maximally Exposed Receptor:

I. Direct Yearly limit Total Dose  % of Qtr Obj I" Qtr 2 ,d Qtr 3 rdQtr 4h Qtr 40CFR9/ 213 Yearly IOCFR72.104 limit Total body (torem) 6.25 O.O0E+00 I O.OOE+O O.OOE+00 0 OOE+00 25.1) O.OOE+00 I0.0(E+O(,

ZionSolutions, LLC ZS-2014-01 00: Attachment 4- Radiological Impact on Man Attachment 4.5 - Combined 40CRF 190 Report IV. Combined 40CFR190 Report:

40CFR190 URANIUM FUEL CYCLE DOSE REPORT GAS ANNUAL DOSE

SUMMARY

Year ..................... 2013 From Unit ................ 1 To Unit ................ 2 Coefficient Type ....... Hist orical Gas Receptor ............ 5 Cot mposite Crit. Receptor - IP Distance (meters) ..... 0.00 Compass Point .......... NA

MAXIMUM PERIOD DOSE TO LIMIT (Any Organ)--------=====

Dose Age Dose Limit Admin Admin % T.Spec T.Spec 0 Period Group Organ (mrem) Period Limit of Limit Limit of Limit Quarter 1 CHILD LIVER 4.76E-05 Quarter 5.63E+/-00 8.46E-04 Quarter 2 CHILD LIVER 3.30E-05 Quarter 5.63E+00 5.87E-04 7.50E+00 6.35E-04 3.82E-05 Quarter 5.63E+00 6.79E-04 7.50E+00 4.41E-04 Quarter 3 CHILD LIVER 7.50E+00 5.10E-04 Quarter 4 CHILD LIVER 4.63E-05 Quarter 5.63E+00 8.24E-04 7.50E+00 6.18E-04 Annual CHILD LIVER 1.65E-04 Annual 1.13E+01 1.47E-03 1.50E+01 1.10E-03

=== MAXIMUM PERIOD DOSE TO LIMIT (Tot Body))-----------=------

Dose Age Dose Limit Admin Admin  % T.Spec T.Spec %

Period Group Organ (mrem) Period Limit of Limit Limit of Limit Quarter 1 CHILD T-ODY 4.76E-05 Quarter 5.25E+/-00 9.O-E-04 Quarter 2 CHILD TBODY 3.30E-05 Quarter 5.25E+00 6.29E-04 7.50E+00 6.35E-04 Quarter 3 CHILD TBODY 3.82E-05 Quarter 5.25E+00 7.28E-04 7.50E+00 4.41E-04 Quarter 4 CHILD TBODY 7.50E+00 5.10E-04 4.63E-05 Quarter 5.25E+00 8.82E-04 7.50E+00 6.18E-04 Annual CHILD TBODY 1.65E-04 Annual 1.05E+0l 1.57E-03 1.50E+01 1.10E-03

ZionSolutions, LLC ZS-2014-0100: Attachment 4- Radiological Impact on Man Attachment 4.5(continued) - Combined 40CRF 190 Report 40CFRi90 URANIUM FUEL CYCLE DOSE REPORT COMBINED MAXIMUM ANNUAL DOSE

SUMMARY

Year ............. 2013 From Unit ........

To Unit ..........

Liquid Receptor..

Coefficient Type. Historical ..

Gas Receptor ..... ...... 5 Composite Crit. Receptor IP Distance (meters) 0.00 Compass Point .... NA ..

MAXIMUM PERIOD DOSE TO LIMIT (Any Organ)

Dose Age Dose Limit Admin Admin  % T. Spec T.Spec Period Group Organ (ntrem) Period Limit of Limit Limit of Limit Quarter 1 CHILD LIVER 4. 76E-Q 5 Quarter 5.63E+00 8.46E-04 7.50E+00 6. 35E-04 Quarter 2 CHILD LIVER 5 Quarter 5.63E+00

7. 50E+00 4.41E-04 Quarter 3 CHILD LIVER 3. 30E-0 5 Quarter 5.63E+00 5. 87E-04 3.82E-0 5 Quarter 5.63E+00 6.79E-04 7. 50E+00 5. l0E-04 Quarter 4 CHILD LIVER 4.63E-0 8.24E-04 7. 50E+00 6. 18E-04 Annual CHILD LIVER 1.65E-0 4 Annual 1.13E+01 1.47E-03 1.50E+01 1. lOE-03

=== MAXIMUM PERIOD DOSE TO LIMIT (Tot Body) )

Dose Age Dose Limit Admin Admin  % T. Spec T.Spec %

Period Group Organ (mrem) Period Limit of Limit Limit of Limit Quarter 1 CHILD T-ODY 5 Quarter 5.25E+00

4. 76E-0 5 9. 06E-04 7. 50E+00 6. 35E-04 Quarter 2 CHILD TBODY Quarter 5.25E+00

7. 50E+00 Quarter 3 CHILD TBODY 3.30E-0 5 Quarter 5.25E+00 6.29E-04 4 .41E-04

3. 82E-0 5 Quarter 5.25E+00 7.28E-04 7. 50E+00 5. l0E-04 Quarter 4 CHILD TBODY 4.63E-0 8.82E-04 7. 50E+00 6. 18E-04 Annual CHILD TBODY 1. 65E-0 4 Annual 1.05E+01 1. 57E-03 1.50E+01 1. l0E-03