ML070740623
| ML070740623 | |
| Person / Time | |
|---|---|
| Site: | Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png |
| Issue date: | 01/19/2007 |
| From: | Wojtkowiak D Connecticut Yankee Atomic Power Co |
| To: | Office of Nuclear Material Safety and Safeguards |
| References | |
| Download: ML070740623 (373) | |
Text
{{#Wiki_filter:CBook 7 of 181 Final Status Survey Final Report Phase VI Appendix A6 Survey Unit Release Record 9522-0001, Southeast Site Grounds (Non-Protected Area) February 2007
CYAPCO FINAL STATUS SURVEY RELEASE RECORD SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 Prepared B WA*V Date: 'IS 10-7 F!SýS g~er Reviewed B,, B?3'ev-$v// , Date: ____" TSS Engineer Approved By: _ _ __._ Date: Technical Support Manager Revision 0
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD TABLE OF CONTENTS
- 1. SURVEY UNIT DESCRIPTION ...................................................... 3
- 2. CLASSIFICATION BASIS ................................................................ 3
- 3. DATA QUALITY OBJECTIVES (DQO) .......................................... 6
- 4. SURV EY D ESIGN ............................................................................. 9
- 5. SURVEY IMPLEMENTATION ....................................................... 13
- 6. SU RV EY RESU LTS ........................................................................ 14
- 7. QUALITY CON TROL .................................................................... 19
- 8. INVESTIGATIONS AND RESULTS ............................................. 19
- 9. REMEDIATION AND RESULTS .................................................. 21
- 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN ...... 21
- 11. DATA QUALITY ASSESSMENT (DQA) ...................................... 21
- 12. A NO M ALIE S .................................................................................... 22
- 13. CO N CLU SIO N ................................................................................ 23
- 14. A TTA CH MEN TS ............................................................................. 23 14.1 Attachment 1 - Figures (9 pages including cover) 14.2 Attachment 2 - Scan Results (5 pages including cover) 14.3 Attachment 3 - Laboratory Data (318 pages including cover) 14.4 Attachment 4- DQA Results (15 pages including covers)
TOTAL 370 Revision 0
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD SURVEY UNIT DESCRIPTION Survey Unit 9522-0001 (Southeast Site Grounds (non-protected area) is designated as Final Status Survey (FSS) Class 2 and consists of approximately 2 six thousand nine hundred and seventy two square meters (6,972 M ) of uninhabited, undeveloped land and is located approximately one thousand and fifty five feet (1,055 ft) from the reference coordinate system benchmark used at Haddam Neck Plant (HNP) (see Attachment 1). The survey unit is bounded as follows: land Survey Unit 9522-0002, land Survey Unit 9522-0003 and land Survey Unit 9522-0004 to the north (called north as oriented with the north to south flow of the Connecticut River), the Discharge Canal to the west, land Survey Unit 9539-0001 to the south, and land Survey Unit 9532 to the east. The survey unit is located along the southern boundary of Survey Area 9522, from the northern transmission tower south to the owner-controlled area fence. It is comprised mostly of rock outcroppings, rock ledge, underbrush and trees. The eastern portion of the survey unit has a moderate slope running east to west. The Independent Spent Fuel Storage Installation (ISFSI) Haul Road runs north to south along the western portion of the survey unit. The reference coordinates associated with this survey unit are E009 through E016 by S078 through S081 (refer to "HNP License Termination Plan" (LTP) Section 5.4.4). The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit. The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Connecticut State Plane System North American Datum (NAD) 1927.
- 2. CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10, "Survey Unit Classification."
The "Classification Basis Summary" conducted for Survey Unit 9522-0001 consisted of: a) A review of the 10CFR50.75 (g) (1) database, b) A review of the "InitialCharacterizationReport" and the "HistoricSite Assessment Supplement, " c) Historic and current survey records review, d) Visual inspections and a "walk-down." A review of the "Initialand Supplemental CharacterizationReports" as well as the previous "Classification Basis Summaries" was performed. Survey Unit 9522-0001 was initially designated as Class 2 during the development of the LTP. The source documents, the "Connecticut Yankee Haddam Neck Characterization Report" and "Initial Classification for Survey Areas at Connecticut Yankee", were incorporated by reference in LTP revision 0. Revision 0 3
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD The second source document justified a Class 2 designation for those areas for which there was historical evidence of contamination above the Derived Concentration Guideline Levels (DCGLs - refer to Section 2 for definition and description of DCGL), but for which recent surveys had shown that decontamination efforts had occurred and that the radiological conditions were expected to be below the DCGLs. Additional justification for a Class 2 designation based on survey and sampling data was provided as another reference to the LTP by the "Haddam Neck Plant Historical Site Assessment Supplement". Open land Survey Area 9522 was at one time an open land immediately adjacent to the southern boundary of the Radiologically Controlled Area (RCA) and security fences. Initially, only a small section of the north side of the unit was paved, with the remainder of the unit gradually sloping down to the original site elevation. As the result of plant operations, there was a need to expand the industrial area to support plant operations and to control exposure to radiation. According to the "Haddam Neck Plant Historic Site Assessment Supplement", plant photos reveals that the area was gradually filled in from approximately 1972 to between 1974 and 1976, with soil that may have originated from on-site. This action raised the elevation up to site grade, thereby facilitating a reconfiguration and expansion of the RCA and security protected area. Photos taken in 1976 show that the area was landscaped with grass and small trees and was probably given the name "ball field" at that time. Over the next several years, additional fill was brought in. By 1987, photos show that half of the survey area was paved and occupied with buildings. It is estimated that the elevation in the survey area may have increased by up to five (5) feet from the original site grade. Survey Area 9522 was impacted by several radiologically significant events during plant operations. These include the discovery of several discrete sources of elevated activity on the ball-field in March 1980, the spill of radioactive liquid into the drain system in February of 1989 and the discovery of several discrete particles outside of the RCA in 1995. Additionally, a portion of Survey Area 9522 was used as a temporary laydown area for the Steam Generator Lower Assemblies (SGLAs) and the Pressurizer until these components where shipped off-site for disposal in 2001. All of these events occurred in the northern portion of Survey Area 9522. It appears based upon a review of the photographs and historical documents that Survey Unit 9522-0001 was not developed and used in the same manner as the remainder of the survey area to the north, mainly due to the physical geography of the survey unit and its lack of proximity to the south boundary of the RCA during plant operations. Leaks and spills that occurred during plant operations that affected the northern survey units in Survey Area 9522, did not affect Survey Unit 9522-0001 as the natural slope of the survey area directed flow in an east to west direction away from the survey unit. Subsequently, the Revision 0 4
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD operational incidents impacting the northern portions of the survey area do not seem to specifically apply to Survey Unit 9522-0001. During previous characterization surveys, focus was given to the northern survey units in Survey Area 9522 as most of the historical events occurred in these area. Minimal survey data was available that distinctively addressed Survey Unit 9522-0001. Subsequently, a Survey and Sampling Work Plan (SSWP X2. SSWP-06-09-006) was developed to specifically characterize the soils in Survey Unit 9522-0001. This survey plan was implemented in October of 2006. Six (6) soil samples were collected to aid in the characterization of this area and to provide sample data with regard to types and quantities of radioactive material present in the surface soil. During scanning, several areas were identified with slightly elevated readings, which prompted the collection of three (3) additional investigation soil samples at those locations. All samples were collected and analyzed by gamma spectroscopy. Two (2) of the soil samples were analyzed by an approved off-site laboratory for the presence of "Hard-to-Detect" (HTD) radionuclides. Cs-137 and Co-60 was positively identified in six (6) of the nine (9) samples at concentrations greater than MDA but far less than their respective Operational DCGL. In addition, Sr-90 was positively identified (i.e., a result greater than two (2) standard deviations uncertainty) but at concentrations less than 5% of the Operational DCGL. Subsequently, Sr-90 was deselected as an isotope of concern in accordance with Section 5.4.7.2 of the LTP. Statistical quantities (mean, median and standard deviation) from the 2006 characterization survey conducted under SSWP 06-09-006 are provided in Table 1. Table 1 - Basic Statistical Quantities for Cs-137 and Co-60 from the 2006 Characterization Survey Cs-137 Co-60 (pCi/g) (pCi/g) Minimum Value: 2.05E-02 -4.58E-02 Maximum Value: 2.55E+00 1.08E-01 Mean: 6.32E-01 2.05E-02 Median: 2.04E-01 5.63E-03 Standard Deviation: 8.96E-01 4.37E-02 The FSS Engineer performed a visual inspection and walk-down during September 2006 to assess the physical condition of the survey unit, evaluate access points and travel paths and identify potentially hazardous conditions. Revision 0 5
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD This survey area is affected by existing groundwater (reference CY memo ISC 06-024) which will be a source of dose from residual radioactivity, as discussed in Section 3 under the DataQuality Objectives. Based upon a review of the historical information and the results of the Characterization Survey data, it was concluded that there was a low probability for residual radioactivity in concentrations greater than the DCGLs, justifying a final survey unit classification of Class 2 (refer to Section 3).
- 3. DATA QUALITY OBJECTIVES (DQO)
FSS design and planning used the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1-11, "Preparationof Final Status Survey Plan," and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM). A summary of the main features of the DQO process are provided herein. The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would indicate that residual activity within the survey unit does not exceed the release criteria. Therefore, the survey unit would satisfy the primary objective of the FSS plan. The primary objective of the FSS plan was to demonstrate that the level of residual radioactivity in Survey Unit 9522-0001 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA). A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity. This is done through the development of DCGLs. The DCGLs represent average levels of radioactivity above background levels and are presented in terms of surface or mass activity concentrations. Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soil (called Base Case Soil DCGL), existing groundwater radioactivity and future groundwater radioactivity that will be contributed by building basements and footings. The DCGLs presented in Chapter 6 of the LTP were developed for exposures from three (3) components, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity. Equation 1 shows the mathematical relationship between the three (3) components and the total dose. Revision 0 6
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Equation I HTotal=Hsoil+HExistingGW+HFutureGW The total dose under the LTP criteria is twenty-five (25) mrem/yr TEDE from all three (3) components. The allowable total dose under the Connecticut Department of Environmental Protection (CTDEP) radiological remediation standard for CY is nineteen (19) mrem/yr TEDE. To satisfy both the LTP and CY CTDEP criteria, the dose from soil must be reduced when using the existing and future groundwater dose values discussed above. This survey area is affected by existing groundwater (reference CY memo ISC 06-024). Therefore, the dose contribution from existing groundwater is bounded by two (2) mrem/yr TEDE. This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no buried concrete foundations or footings containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contribution from future groundwater, the third dose component is, therefore, zero (0) mrem/yr TEDE. Equation 2 19 mrem/yrTotal = 17 mrem/yrsoil + 2 mrem/yrExisting Gw+ 0 mrem/yrFuturoGw The allowable dose for soil in this survey unit is seventeen (17) mrem/yr TEDE as shown by Equation 2 above. The concentration of residual radioactivity resulting in seventeen (17) mrem/yr TEDE is designated as the Operational DCGL, and has been established for the radionuclides of concern as provided in Table 2. Revision 0 7 Revision 0 7
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Table 2 - Radionuclide Specific Base Case Soil DCGLs, Operational DCGLs and Required Minimum Detectable Concentrations (MDCs) Radionuclide ) Base Case Soil Operational DCGL Required MDC DCGL (pC/g) (2) (pC/g) (3) (pC/g) (4) H-3 4.12E+02 2.80E+02 1.65E+01 C-14 5.66E+00 3.85E+00 2.26E-01 Mn-54 1.74E+01 1.18E+O1 6.96E-01 Fe-55 2.74E+04 1.86E+04 1.1OE+03 Co-60 3.81E+00 2.59E+00 1.52E-01 Ni-63 7.23E+02 4.92E+02 2.89E+01 Sr-90 1.55E+00 1.05E+00 6.20E-02 Nb-94 7.12E+00 4.84E+00 2.85E-01 Tc-99 1.26E+01 8.57E+00 5.04E-01 Ag-108m 7.14E+00 4.86E+00 2.86E-01 Cs- 134 4.67E+00 3.1 8E+00 1.87E-01 Cs-137 7.91E+00 5.38E+00 3.16E-01 Eu-152 1.01E+01 6.87E+00 4.04E-01 Eu-154 9.29E+00 6.32E+00 3.72E-01 Eu-155 3.92E+02 2.67E+02 1.57E+01 Pu-238 2.96E+01 2.01E+01 1.18E+00 Pu-239/240 2.67E+O 1 1.82E+01 1.07E+00 Am-241 (5) 2.58E+01 1.75E+01 1.03E+00 Pu-241 8.70E+02 5.92E+02 3.48E+01 Cm-243/244 2.90E+0 1 1.97E+01 1.16E+00 (1) Bold indicates those radionuclides considered Hard to Detect (HTD) (2) The Base Case Soil DCGL(s) are specified by the LTP in Chapter 6 and are equivalent to twenty-five (25) mrem/yr TEDE (3) The Operational DCGL is equivalent to achieving seventeen (17) mrem/yr TEDE (4) The required MDC is equivalent to achieving one (1) mrem/yr TEDE (5) Americium-241 can be analyzed by gamma and alpha spectroscopy and is considered to be Easy to Detect (ETD). The preferred result is the alpha spectroscopy's when both analyses are performed Revision 0 8 Revision 0 8
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Another important facet of the DQO process is to identify the radionuclides of concern and determine the concentration variability. Soil samples were collected in 2006 to establish the radiological condition Survey Unit 9522-0001 for FSS. Cs-137 and Co-60 were the only two (2) gamma emitting radionuclides reported in concentrations with the potential for exceeding the screening criteria. Sr-90 was positively identified (i.e., a result greater than two (2) standard deviations uncertainty) but at concentrations less than 5% of the Operational DCGL. Subsequently, Sr-90 was deselected as an isotope of concern in accordance with Section 5.4.7.2 of the LTP. The characterization data were used for the survey design and are provided in Table 1. Instrument DQOs included a verification of the ability of the survey instrument to detect the radiation(s) of interest relative to the DCGL. Survey instrument response checks were required prior to issue and after the instrument had been used. Control and accountability of survey instruments was required to assure the quality and prevent the loss of data. As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. Results reported as less than Minimum Detectable Concentration (MDC) were not accepted for FSS. Sample report summaries included unique sample identification, analytical method, radionuclide, result, and uncertainty to two (2) standard deviations, laboratory data qualifiers, units, and the required and observed MDC.
- 4. SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. Guidance for preparing FSS plans is provided in Procedure RPM 5.1-11, "Preparation of Final Status Survey Plans". The FSS plan uses an integrated sample design that combines scanning surveys and sampling which can be either random or biased.
The DQO process determined that both Cs-137 and Co-60 would be the radionuclides of concern in Survey Unit 9522-0001 (refer to Section 3). The characterization survey did not identify any HTD radionuclides of concern for this survey unit. Subsequently, surrogate DCGLs were not required for this survey unit via screening under LTP Section 5.4.7.2, "Gross Activity DCGLs". Other radionuclides that were positively identified in concentrations greater than the screening criteria during the performance of this FSS would be evaluated to ensure adequate survey design. Radionuclide screening or de-selection is a process where the dose contribution from an individual radionuclide or aggregates may be considered insignificant and eliminated from the FSS. The criteria for de-selection are concentrations less than 5% for individual radionuclides and less than 10% for aggregates. The Elevated Measurement Comparison (EMC) did not apply to this survey unit since it is a Class 2 area and discrete, elevated areas of contamination were not expected. Revision 0 9
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation. This approach was conservative since it included background Cs-137 as part of the sample set. The number of soil samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determinationof the Number of Surface Samples for FinalStatus Survey." The Lower Bound of the Gray Region (LBGR) was set in accordance with Procedure RPM 5.1-11 to 0.5 to maintain the relative shift (A/o) in the range of 1 and 3. The resulting relative shift was 2.99. A Prospective Power Curve was generated using COMPASS, a software package developed under the sponsorship of the United States Nuclear Regulatory Commission (USNRC) for implementation of the MARSSIM in support of the decommissioning license termination rule (10CFR20, Subpart E). The result of the COMPASS computer run showed adequate power for the survey design. The survey design specified fifteen (15) surface soil samples for non-parametric statistical testing. Based upon a review of the historical information and Characterization Survey data, the acquisition of additional judgmental surface soil samples from within this survey unit was deemed unnecessary. The grid pattern and locations of the soil samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying, and Marking Surface Sample Locations for Final Status Survey." Visual Sample Plan was created by Pacific Northwest National Laboratory (PNNL) for the United States Department of Energy. A systematic triangular grid pattern with a random starting point was selected for sample design, which is appropriate for a Class 2 area. Sample locations were identified using AutoCAD-LT, a commercially available plotting software package with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample locations in the field. Sample Measurement Locations for the design are listed with the GPS coordinates in Table 3. Revision 0 10
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Table 3 - Sample Measurement Locations with Associated GPS Coordinates Designation Northing Easting 9522-0001-OO1F 236516.39 669283.45 9522-0001-002F 236516.39 669359.45 9522-0001-003F 236450.56 669321.45 9522-0001-004F 236450.56 669397.46 9522-0001-005F 236384.73 669283.45 9522-0001-006F 236384.73 669359.45 9522-0001-008F 236318.91 669397.46 9522-0001-009F 236253.08 669283.45 9522-0001-O0OF 236253.08 669359.45 9522-0001-01IF 236253.08 669435.46 9522-0001-012F 236187.25 669245.44 9522-0001-013F 236187.25 669321.45 9520-0001-014F 236187.25 669397.46 9522-0001-015F 236121.43 669359.45 9522-0001-016F01) 236516.39 669283.45 (1) Sample location 9522-0001-007F was inaccessible due to due to the presence of a rock ledge and heavy brush; sample location 9522-0001-016F was added under an FSS plan addendum (refer to Section 10) Procedure RPM 5.1-11 specifies that 5% of the samples are required to be selected for HTD analysis. Two (2) soil samples, or about 10% of the number of samples that would be used for non-parametric statistical testing were randomly selected for HTD radionuclide analysis using the Microsoft Excel "RANDBETWEEN" function. Each sample was sent off-site for a full suite analysis of the HTD radionuclides specified in the LTP, Table 2-12, "Radionuclides Potentially Presentat Haddam Neck Plant" and as provided in Table 2. The implementation of quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey," included the collection of one (1) soil sample for "split sample" analysis by the off-site laboratory. This location was selected randomly using the Microsoft Excel "RANDBETWEEN" function. Revision 0 I1I Revision 0 11
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD The LTP specifies a required scanning coverage of 10% to 100% for outdoor Class 2 areas. The fraction of scanning coverage was determined during the DQO process with the total amount and location(s) based on the likelihood of finding elevated activity during FSS. Based on the historical site assessment, the characterization data available, and the use of this survey unit, it was determined that scanning was required in three (3) separate areas. The total surface area to be scanned was approximately 25% of the survey unit. A combination of two of the scan areas resulted in approximately 100% scan coverage of the section of the ISFSI Haul Road contained in this survey unit. A map of the scan grid locations is provided in Attachment 1. For this Class 2 survey unit, the "Investigation Level" for area scanning and soil sample measurement results are those levels specified in LTP, Table 5-8. Table 4 provides a synopsis of the survey design. Table 4 - Synopsis of the Survey Design Feature Design Criteria Basis Survey Unit Land Area 6,972 m 2 Based on AutoCAD-LT Type 1 and Type 2 errors were 15 0.05, sigma was 0.17 pCi/g, the Number of Measurements (15 systematic grid) LBGR was set at 0.5 to maintain Relative Shift in the range of 1 and 3 Grid Spacing 23.09 m Based on triangular grid 5.38 pCi/g Cs-137 Administratively set to achieve 2.59 pCi/g Co-60 seventeen (17) mrem/yr TEDE l"' 5.38 pCi/g Cs-137 The Operational DCGL meets the Soil Investigation Level LTP criteria for a Class 2 survey 2.59 pCi/g Co-60 unit Scan Survey Area Approximately 25% The LTP requires >10% area Coverage of the area coverage for Class 2 survey units Scan Investigation Level Detectable over Administratively set to achieve background seventeen (17) mrem/yr TEDE ) (1) The allowable dose for soil in this survey unit is seventeen (17) mrem/yr TEDE as the bounding dose from existing and future groundwater has been established based on field data (reference CY memo ISC 06-024) Revision 0 12
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD
- 5. SURVEY IMPLEMENTATION Final status survey field activities were conducted under Work Plan and Inspection Record (WP&IR) 2006-0047. The WP&IR package included a detailed FSS plan, job safety analysis, job planning checklist and related procedures for reference. Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.
Three (3) scan areas were established that constituted approximately 25% of the surface area of Survey Unit 9522-0001. Grid lines, one meter wide, were painted on the ground of the scan area. A background survey was performed around the survey unit and it was determined that, using an Eberline E-600 with a SPA-3 sodium iodide detector, background ranged from 4,210 counts per minute (cpm) up to 9,750 cpm. The scan areas were established and scanned for elevated readings (see Attachment 2 for all scan results). Scanning was performed with an Eberline E-600 using a SPA-3 sodium iodide detector. The E-600 was operated in the rate-meter mode and used with audio response. The probe was positioned as close to the ground as possible and was moved at a scan speed of about 0.5 meters per second. Approximately 25% of the survey unit was scanned. Measurement locations were identified in North American Datum (NAD) 1927 coordinates using GPS coordinates; sample locations were identified and marked with a surveyor's flag or paint for identification. At each sample location, a one (1) meter radius around the sample flag or paint mark was scanned for elevated radiation levels. Fifteen (15) surface soil samples were collected and packaged in accordance with Haddam Neck Plant (HNP) Procedure RPM 5.1-3, "Collection of Sample Media for Final Status Survey" and FSS design. Samples were controlled, transported, stored, and transferred to the off-site laboratory using Chain-of-Custody (COC) protocol in accordance with Procedure RPM 5.1-5, "Chain of Custodyfor FinalStatus Survey Samples." Two (2) samples (9522-0001-008F and 9522-0001-014F) were randomly selected for HTD radionuclide analysis. The implementation of surve' specific quality control measures included the collection of one (1) sample (9*22-0001-009F) for "split sample" analysis. Revision 0 13 Revision 0 13
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD
- 6. SURVEY RESULTS All field survey activities were conducted between November 9, 2006 and November 21, 2006.
The sample locations identified in the FSS plan were scanned over approximately a one (1) meter radius for elevated radiation levels. Table 5 provides an overview of the scan results for sample measurement locations. Scan results for the entire survey unit are provided in Attachment 2. Table 5 - Scan Results for Sample Measurement Locations Sample Highest Logged Action Level (2) Measurement Reading A ct e ) > Action Level (3) Location (kcpm) (kcpm) 1 10.05 10.10 YES 2 11.00 11.10 NO 3 10.50 10.50 NO 4 10.80 11.70 NO 5 9.12 10.50 NO 6 10.30 10.10 YES 8 8.30 8.23 YES 9 6.96 7.67 NO 10 7.69 11.10 NO 11 7.41 8.34 NO 12 6.33 7.38 NO 13 4.55 5.77 NO 14 7.69 6.83 YES 15 9.75 9.17 YES 16(l) 7.15 9.01 NO (1) Sample location 9522-0001-007F was inaccessible due to due to the presence of a rock ledge and heavy brush; sample location 9522-0001-016F was added under an FSS plan addendum (refer to Section 10) (2) The action level is based on a measurement above ambient background in accordance with the FSS plan (3) The FSS plan requires movement of the sample measurement location to the area within the 1 meter radius yielding the response above the action level. Sample locations 9522-0001-0011F, 9522-0001-006F, 9522-0001-008F, 9522-0001-014F and 9522-0001-015F were moved accordingly. Revision 0 14 Revision 0 14
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD The scan areas, that comprised approximately 25% of the total surface area for the survey unit, were scanned for elevated radiation levels. The areas were scanned in accordance with the FSS plan on November 15, 2006 through November 21, 2006. Several elevated measurement locations were identified during scanning. Table 6 provides an overview of the scan area survey. Complete scan results are provided in Attachment 2. Table 6 - Scan Area Results Highest Action Scan Logged Level o Elevated Reading Investigation Area Reading Lecel Identification (2) Sample (kcpm) (kcpm) 9522-01-ER-01-06-1 9522-0001-0211 1 9.49 7.60 9522-01-ER-01-09-1 9522-0001-0221 9522-01-ER-01-12-1 9522-0001-0231 9522-01-ER-02-03-1 9522-0001-0171 9522-01-ER-02-10-1 9522-0001-0181 2 9.68 8.46 9522-01-ER-02-19-1 9522-0001-0191 9522-01-ER-02-19-2 9522-0001-0201 3 11.00 9.70 9522-01-ER-03-03-1 9522-0001-0241 (1) The action level is based on a measurement above ambient background (2) ER is an abbreviation associated with the barcodes used in the field where ER stands for Elevated Reading The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories, LLC. The laboratory analyzed the fifteen (15) samples collected for non-parametric statistical testing, the associated field split and the eight (8) investigative samples using gamma spectroscopy. Gamma spectroscopy results identified some radionuclides meeting the accepted criteria for detection (i.e., a result greater than two (2) standard deviations uncertainty). HowNever, Cs-137 and Co-60 were the only gamma-emitting radionuclides reported in concentrations exceeding the de-selection criteria. Cs-137 was identified in fourteen (14) and Co-60 was identified in three (3) of the fifteen (15) samples collected for non-parametric statistical testing. The mean of the gamma spectroscopic analysis results for the sample population indicated that Cs-137 was present at levels lower than the concentrations of Cs-137 found in soil at off-site locations within the vicinity of the HNP as presented in the Health Physics TSD BCY-HP-0063. A summary of the fifteen (15) samples collected for non-parametric statistical testing results is provided in Table 7. Revision 0 15
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Table 7 - Summary of Gamma Spectroscopy Results for Surface Soil Samples Comprising the Statistical Sample Population Cs-137 Co-60 Sample Number pCi/g pCi/g 9522-0001-OO1F 6.77E-01 -1.86E-04 9522-0001-002F 6.66E-01 2.40E-02 9522-0001-003F 1.17E+00 -2.28E-03 9522-0001-004F 6.37E-01 2.27E-02 9522-0001-005F 8.24E-01 5.08E-02 9522-0001-006F 3.08E+00 5.70E-02 9522-0001-008F 2.23E-01 3.85E-03 9522-0001-009F 1.16E-01 -3.91E-03 9522-0001-01OF 2.39E-01 -7.76E-03 9522-0001-011F 1.17E-01 1.32E-02 9522-0001-012F 5.04E-02 1.22E-02 9522-0001-013F 2.77E-02 3.35E-03 9522-0001-014F 2.91E-01 0.OOE+00 9522-0001-015F 4.11E-02 1.38E-02 9522-0001-016F11) 3.89E-01 1. 15E-02 (1) Sample location 9522-0001-007F was inaccessible due to due to the presence of a rock ledge and heavy brush; sample location 9522-0001-016F was added under an FSS plan addendum (refer to Section 10) The off-site laboratory also processed two (2) samples for HTD analysis as required by the sample plan. The requested analyses included alpha spectroscopy, gas proportional counting, and liquid scintillation depending on the radionuclide and the measurement method. All analyses met the required MDC. Sr-90 was positively identified (i.e., a result greater than two standard deviations uncertainty) in both of the samples analyzed for HTD radionuclides. As previously stated in Section 4 of this report, the criteria for de-selection of a radionuclide is a concentration that is less than 5% of the Operational DCGL for individual radionuclides and less than 10% of the Operational DCGLs for aggregates. For Sr-90, the Operational DCGL is 1.05 pCi/g to achieve a TEDE of seventeen (17) mrem/yr. Revision 0 16 Revision 0 16
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD The analytical results for Sr-90 in the two (2) samples selected for HTD analysis respectively equated to 3% and 73% of the Operational DCGL. Subsequently, Sr-90 was added as a radionuclide of concern for this survey unit. In response, all samples that comprised the statistical sample population for this survey unit were subjected to additional analysis for the presence of Sr-90. The results are provided below in Table 8. Table 8 - Summary of Sr-90 Analysis Results for Surface Soil Samples Comprising the Statistical Sample Population Sr-90 pCi/g Sample Number 9522-0003-001F 1.68E-02 9522-0003-002F -1.28E-02 9522-0003-003F 4.20E-02 9522-0003-004F 3.19E-02 9522-0003-005F 1.79E-02 9522-0003-006F 1.59E-01 9522-0003-008F 3.61E-02 9522-0003-009F 1.97E-04 9522-0003-OIOF 2.88E-02 9522-0003-011F -6.62E-03 9522-0003-012F 3.70E-02 9522-0003-013F 3.35E-02 9522-0003-014F 7.66E-01 9522-0003-015F 8.07E-04 9522-0003-016F*'i -2.89E-03 (1) Sample location 9522-0001-007F was inaccessible due to due to the presence of a rock ledge and heavy brush; sample location 9522-0001-016F was added under an FSS plan addendum (refer to Section 10) The "sum-of-fractions" or "unity rule" is the mathematical test used to evaluate compliance with radiological criteria for license termination when more than one radionuclide has been determined to be potentially present. The unity rule is: Revision 0 17 Revision 0 17
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Equation3 C + C-2 + .......
+ C. <_1 DCGLI DCGL2 DCGL, Where: Cn = concentration of radionuclide n and DCGLn = DCGL of radionuclide n.
The results of the unity rule calculation for the radionuclides of concern in the statistical sample population for Survey Unit 9522-0001 are provided in Table 9 below. Table 9 -Results of Unity Calculation for Surface Soil Samples Comprising the *tatiktieal SamnlP Pnnullatinn Fraction of the Operational DCGL('1 31 Unity Cs-137 Co-60 Sr-90 Fraction 9522-0006-001F 0.13 0.02 0.14 9522-0006-002F 0.12 - 0.12 9522-0006-003F 0.22 - 0.04 0.26 9522-0006-004F 0.12 0.01 0.03 0.16 9522-0006-005F 0.15 0.02 0.02 0.19 9522-0006-006F 0.57 0.02 0.15 0.75 9522-0006-008F 0.04 - 0.03 0.08 9522-0006-009F 0.02 - - 0.02 9522-0006-OIOF 0.04 - 0.03 0.07 9522-0006-01IF 0.02 - - 0.02 9522-0006-012F 0.01 - 0.04 0.04 9522-0006-013F 0.01 - 0.03 0.04 9522-0006-014F 0.05 - 0.73 0.78 9522-0006-015F - - - 0.00 9522-0006-016F(2) 0.07 - - 0.07 (1) The Operational DCGL from Table 2 is 5.38 pCi/g for Cs-137, 2.59 pCi/g for Co-60 and 1.05 pCi/g for Sr-90 to achieve seventeen (17) mrem/yr TEDE respectively. (2) Sample location 9522-0001-007F was inaccessible due to due to the presence of a rock ledge and heavy brush; sample location 9522-0001-016F was added under an FSS plan addendum (refer to Section 10) (3) - indicates that the radionuclide was not positively detected in the sample Revision 0 18
I SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD
- 7. QUALITY CONTROL The off-site laboratory processed the split samples and performed gamma spectroscopy analysis. One sample location was selected for analysis, which exceeds the 5% minimum required by the LTP. The data were evaluated using USNRC acceptance criteria specified in Inspection Procedure 84750 as detailed in HNP Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey ". There was acceptable agreement between the field split results at location 9520-0001-009.
The sample analysis vendor, General Engineering Laboratories, LLC, maintains quality control and quality assurance plans as part of normal operation. Refer to Attachment 4 for data and data quality analysis results.
- 8. INVESTIGATIONS AND RESULTS Eight (8) investigative samples were collected from scan area 1, scan area 2 and scan area 3 at locations exhibiting elevated scan readings. As previously stated, Sr-90 was positively identified (i.e. a result greater than two (2) standard deviations uncertainty) in the two (2) surface soil samples selected for HTD analysis. Consequently, Sr-90 was added as a radionuclide of concern for this survey unit. All surface soil samples comprising the statistical sample population were subjected to additional analysis for the presence of Sr-90.
Subsequently, the statistical sample population as a whole was evaluated to assess the distribution of the detected radionuclides of concern. The radionuclide distribution percentage for each sample in the population was calculated by dividing the concentration of each detected radionuclide by the total activity concentration in the sample, expressing the abundance of the specific nuclide in the sample compared against the total activity. The mean radionuclide distribution was then calculated by taking the average of the individual sample distribution fractions. The resultant distribution fractions are presented in Table 10 below. Table 10 - Radionuclide Distribution Fraction for the Radionuclides of Concern in the Statistical Soil Sample Population Detected Radionuclide Distribution Fraction Cs-137 0.841 Co-60 0.008 Sr-90 0.151 The potential presence of Sr-90 in the investigative samples taken that were not subjected to direct analysis for Sr-90 was addressed by using a surrogate relationship to another detectable radionuclide as recommended in NUREG-1575 (MARSSIM), in this case Cs-137. To demonstrate compliance Revision 0 19 Revision 0 19
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD with the release criteria by directly comparing the individual investigative sample results with the DCGL(s) as required by MARSSIM, the DCGL for the surrogate radionuclide, in this case Cs-137 was scaled to account for the fact that it was being used as an indicator for additional radionuclides, in this case Sr-90. This result is referred to as the surrogate DCGL. The surrogate DCGL was computed based on the distribution ratio between the hard-to-detect radionuclides and the easy-to-detect radionuclides. The surrogate DCGL is computed as follows: Equation 4 S Surrogale C _ DCGL 3 DCGL=+ Where: DCGLsur = Surrogate radionuclide DCGL DCGL 2,3..., = DCGL for radionuclides to be represented by the surrogate Rn = Ratio of concentration (or nuclide mixture fraction) of radionuclide "n" to surrogate radionuclide Using the DCGLs presented in Table 2 and the soil nuclide distribution presented in Table 10, the following surrogate calculation was deduced; Equation 5 SurrogateDCGL(Uc-137 ) .151 =2.80 pCig (5S. 3 8 (C-1 3 7 ) r+1 .0 5 (sr-90) Subsequently, the surrogate DCGL that was used for Cs-137 in this survey unit for direct comparison of investigative sample results to demonstrate compliance with the operational dose limit of seventeen (17) mrem per year is 2.80 pCi/g. The samples are denoted as shown in Table 6, with the sample results shown in Table 11 below. Table 11 - Investigative Sample Results Sample Number Cs-137 Co-60 1 ) Unity FractionO pCi/g pCi/g 9522-0001-0171 O.OOE+00 1.28E-02 0.005 9522-0001-0181 8.04E-02 1.20E-02 0.033 9522-0001-0191 4.95E-02 4.30E-02 0.034 Revision 0 20 Revision 0 20
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Table 11 - (continued) Sample Number Cs-137 Co-60 Unity Fraction(1 ) pCi/g pCi/g 9522-0001-0201 3.56E-02 4.71E-03 0.015 9522-0001-0211 5.19E-01 2.53E-02 0.195 9522-0001-0221 6.53E-02 1.79E-02 0.030 9522-0001-0231 5.50E-02 -1.47E-02 0.014 9522-0001-0241 6.30E-01 4.35E-03 0.227 (1) The Operational DCGL from Table 2 is 5.38 pCi/g for Cs-137 and 2.59 pCi/g for Co-60 to achieve seventeen (17) mrem/yr TEDE respectively. The Operational DCGL for Cs-137 has been adjusted to 2.80 pCi/g as a surrogate to account for the potential presence of HTD radionuclide Sr-90.
- 9. REMEDIATION AND RESULTS Historically, no radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit prior to or as a result of the FSS. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey, " determined that remediation beyond that required to meet the release criteria is unnecessary and that the remaining residual radioactivity in soil was ALARA.
- 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN An addendum to the FSS plan was initiated on November 13, 2006 to replace sample location 9522-0001-007F, which was determined to be inaccessible due to the presence of a rock ledge and heavy brush. Sample location 9522-0001-016F was determined randomly using VSP.
Additional analysis for the presence of Sr-90 was performed on the statistical survey population as a consequence of the results from the initial samples selected for HTD analysis. This was to ensure that the dose consequence from the possible presence of Sr-90 in the surface soils in this survey unit was adequately addressed.
- 11. DATA QUALITY ASSESSMENT (DQA)
The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment," for completeness and consistency. The sampling design had adequate power as indicated by the Retrospective Power Curve. The Sign Test was performed on the data and compared to the original assumptions of the DQOs. The evaluation of the Sign Test results demonstrates that the survey unit passes the unrestricted release criteria, thus, the null hypothesis is rejected. Revision 0 21 Revision 0 21
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 2. The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation). The mean and median values are well below the Operational DCGL. Also, the retrospective power curve shows that a sufficient number of samples were collected to achieve the desired power. Therefore, the survey unit meets the unrestricted release criteria with adequate power as required by the DQOs. The basic statistical quantities for the statistical sample population are provided below in Table 12. Table 12 - Basic Statistical Quantities for Cs-137, Co-60 and Sr-90 from the Final Status Survey Cs-137 Co-60 Sr-90 pCi/g pCi/g pCi/g DCGL0 p: 5.38E+00 2.59E+00 1.05E+00 Minimum Value: 2.77E-02 -7.76E-03 -1.28E-02 Maximum Value: 3.08E+00 5.70E-02 7.66E-01 Mean: 5.70E-0 1 1.32E-02 7.65E-02 Median: 2.91E-01 1. 15E-02 2.88E-02 Standard Deviation: 7.72E-01 1.90E-02 1.95E-01 For Cs-137 and Sr-90, the range of the data, about four (4) standard deviations, was not a particularly large variation considering that the levels were essentially at existing environmental levels where such variation is to be expected and the difference between the mean and median was about 36% and 24% of the standard deviation which indicates some skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot indicates positive skewness as confirmed by the calculated skew of 2.7 for Cs-137 and 3.6 for Sr-90. Co-60, although included in the FSS plan for compliance purposes, was positively identified in only three (3) of the fifteen (15) samples collected for non-parametric statistical testing. Assessment of the basic statistical quantities and graphical representation of Co-60 was not considered useful given the limited number of data points to represent the distribution. All data, assessments, and graphical representations are provided in Attachment 4.
- 12. ANOMALIES No anomalies were noted.
Revision 0 22
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD
- 13. CONCLUSION Survey Unit 9522-0001 has met the final DQOs of the FSS plan. The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved. Elevated Measurement Comparison and remediation was not required.
All identified radionuclides of concern were used for statistical testing to determine the adequacy of the survey unit for FSS. The sample data passed the Sign Test. The null hypothesis was rejected. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved. The survey unit is properly designated as Class 2. The dose contribution from soil is 3.126 mremlyr TEDE based on the average concentration of the samples used for non-parametric statistical sampling. This survey area is affected by existing groundwater (reference CY memo ISC 06-024); therefore the dose contribution from existing groundwater is bounded at two (2) mrem/yr TEDE. This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no underground structures, systems or components containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024); therefore, the dose contribution from future groundwater is zero (0) mrem/yr TEDE. The average total dose from residual radioactivity in this survey unit, including exposures from the three (3) components as described in Section 3, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity, will not exceed 5.126 mrem/yr TEDE. Therefore, Survey Unit 9522-0001 is acceptable for unrestricted release.
- 14. ATTACHMENTS 14.1 Attachment 1 - Survey Unit Location Map 14.2 Attachment 2 - Scan Results 14.3 Attachment 3 - Laboratory Results 14.4 Attachment 4 - DQA Results Revision 0 23
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 1 (FIGURES) Revision 0
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SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 2 (SCAN RESULTS) Revision 0
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Attachment 2 SCAN RESULTS FOR SCAN STRIPS
>Alarm E-600 S/N Probe S/N Survey Location Log Date Log Time Reading Alarm Level Level SCAN AREA #1 1111612006 10:15:00 5.98E+03 1114 1014 9522-01-SC-01-01-0 11/16/2006 10:21:00 6.91E+03 7.08E+03 1114 1014 9522-01-BC-01-02-0 11/16/2006 10:21:00 7.31 E+03 1114 .1014 9522-C1 -SC-*B-02-0 11/16/2006 10:24:00 6.15E+03 8.53E+03 1114 1014 9522-01-BC-01-03-0 11/16/2006 10:25:00 7.11 E+03 1114 1014 9522-01-SC-01-03-0 11/16/2006 10:26:00 7.34E+03 8.31E+03 1114 1014 9522-01-BC-Cl-04-0 11/16/2006 10:28:00 6.93E+03 1114 .1o014 9522-01-SC-01-04-0 11/16/2006 10:29:00 5.90E+03 8.12E+03 1114 1014 9522-01-BC-01-0C-0 11/16/2006 10:31:00 6.12E+03 1114 1014 9522-01-SC-01-0C-C 11/1612006 10:33:00 6.15E+03 7.24E+03 1114 1014 9522-0C -BC-0C 06-0 10:34:00 6.53E+03 1114 1014 Il/I16/2006 9522-01-SC-01-06-0 10:37:00 6.44E+03 7.68E+03 1114 1014 11/16/2006 9522-01-ER-01-06-0 13:30:00 8.46E+03 7.68E+03 + 1114 1014 9522w01-BC-0*Cl -0Cl 11/1612006 10:38:00 6.83E+03 1114 1014 9522-01-SC-01-07-0 11/16/2006 10:40:00 6.47E+03 8.01E+03 1114 1014 9522--BC-C-08-0 11/16/2006 10:41:00 6.60E03 1114 1014 9522-01 -SC-01 0 11/16/2006 10:43:00 5.31 E+03 7.76E+03 1114 1014 9522-01-BC-01-19-0 11/16/2006 10:47:00 6.45E+03 1114 1014 9522-01 -SC-01-09-0 11/16/2006o 10:54:00 5.75E+03 7.60E+03 1114 1014 9522-01 -ER-01-09-1 11/16/2006 13:31:00 9.49E+03 7.60E+03 4- 1114 1014 9522-*C-BC-01C-1C-0 11/16/2006 10:56:00 6.81 E+03 1114 1014 9522-01-SC-01-1-0 11/16/2006 11:03:00 6.53E+03 7.99E+03 1114 1014 9522-01 -BC-0 -1l-C 11/16/2006 11:04:00 6.63E+03. 1114 1014 9522-01-SC-01-14-0 11/1612006 11:07:00 5.68E+03 7.79E+03 1114 1014 9522-Cl -BC-Cl -l2-0 11/1612006 11:07:00 6.98E+03 1114 1014 9522-01 -SC-01 0 11/16/2006 11:12:00 6.69E+03 8.17E+03 1114 1014 9522-0Cl-ER-Cli-12-I 11/16/2006 13:32:00 8.17E+03 8.17Et03 1114 1014 9522-Cl -BC-Cl C 11/16/2006 11:13:00 7.25E+03 1114 1014 9522-Cl -SC-Cl1 C 11/16/2006 11:19:00 7.62E+03 8.47E+03 1114 11/16/2006 9522-Cl -BC-Cl C 11:21:00 7.46E+03.. 1114 1014 9522-Cl -SC-Cl C 11/16/2006 11:25:00 6.72E+03 8.69E+03 1114 1014 9522-Cl-BC-Cl-Is-C 11/16/2006 11:25:00 7.16E+03 1114 1014 9522-Cl -SC-Cl -I5-C 11)16/2006 11:30:00 7.54E+03 8.37E+03 1114 1014 952-Cl -BC-Cl C 11/16/2006 11:31:00 .8.59E+03 1114. 1014 9522-01-SC-01-16-0 1111612006 11:34:00 7.44E+03 9.91E+03 1114 10`14 9522-01-BC-01-17-0 11/16/2006 11:35:00 7.32E+03 1114 1014 9522-Cl -SC-Cl 0 11/16/2006 11:38:00 7.98E+03 8.54E+03 1114 1014 REVISION 0 Page I of 4
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-000 1 RELEASE RECORD Attachment 2
>Alarm Survey Location Log Date Log Time Reading Alarm Level E-600 S/N Probe S/N Level SCAN AREA #2 9522-01-BC-02-01-0 11115/2006 12:50:00 6.1 9E+03 1116 1006 9522-01-SC-02-01-0 11/15/2006 12:54:00 6.95E+03 7.31 E+03 1116 1006 9522-01-BC-02-02-0 11/15/2006 12:54:00 6.86E+03 1116 1006 9522-01-SC-02-02-0 11/15/2006 12:57:00 6.64E+03 8.04E+03 1116 1006 9522-01 -BC-02-03-0 11/15/2006 12:59:00 6.64E+03 1116 1006 9522-01-SC-02-03-0 11/15/2006 13:02:00 7.16E+03 7.80E+03 1116 1006 9522-01-ER-02-03-1 11/16/2006 7:16:00 6.93E+03 7.80E+03 1112 1013 9522-01-BC-02-04-0 11/15/2006 13:03:00 6.75E+03 1116 1006 9522-01-SC-02-08-0 11/15/2006 13:07:00 6.40E+03 7.92E+03 1006 9522-01 -SC-02-09-0 1115/2006 13:10:00 6.31 E+03 1116 1006 9522-01 -SC-02-05-0 11/15/2006 13:14:00 6.56E+03 7.44E+03 1006 9522-01 -EC-02-06-0 11/15/2006 13:22:00 5.15E+03 1112 1013 9522-01-SC-02-06-0 11/15/2006 13:25:00 6.04E+03 6.1 7E+03 1112 1013 9522-01-SC-02-01-0 11/15/2006 13:26:00 5.66E+03 1112 1013 9522-01-SC-02-07-0 11/15/2006 13:28:00 4.95E+03 6.73E+03 1112 1013 9522-01 -SC-02-01-0 11/15/2006 13:30:00 .6.24E+03 .1.1 12 1013 9522-01-SC-02-08-0 11/15/2006 13:31:00 5.95E+03 7.37E+03 1112 1013 9522-01 -SC-02-01-0 11/15/2006 13:35:00 5.95E+03 1112 1013.
9522-01 -SC-02-09-0 11/15/2006 13:38:00 5.23E+03 7.05E+03 1112 1013 9522-01 -SC-02-10-0 11/115/2006~ 13:38:0.0 5.50E+03 1112 .1013* 9522-01-SC-02-10-0 1111512006 13:41:00 5.17E+03 6.56E+03 1112 1013 9522-01-ER-02-10-1 11/16/2006 7:17:00 8.19E+03 6.56E+03 1112 1013 9522-01 -BC-02-1 1-0 11/15/2006 13:41:00 5.52E+03 1112 1013 9522-01 -SC-02-1 1-0 11/15/2006 13:45:00 5.79E+03 6.58E+03 1112 1013 9522-01 -BC-02-1 2-0 11/15/2006 13:46:00 5.71 E+03 1112 1013 9522-01 -SC-02-1 2-0 11/15/2006 13:48:00 5.02E+03 6.79E+03 1112 1013
.9522-01 -BC-02,1 3-0 11/1512006 13:49:00 6.OOE+03 1112 1013 9522-01 -SC-02-1 3-0 11/15/2006 13:51:00 5.06E+03 7.11IE+03 1112 1013 9522-01 -BC-02-14-0 11/15/2006 13:54:00 4.90 E+03 1112 1013 9522-01 -SC-02-14-0 11115/2006 13:57:00 4.96E+03 5.90E+03 1112 1013 9522-01 -BC-02-1 5-0. 11/15/2006 13:57:00 6.76E+03 1112 1013 9522-01 -SC-02-1 5-0 11/1512006 14:00:00 4.72E+03 7.93E+03 1112 1013 9522-01 -BC-02-1 6-0 11/15/2006 14:02:00 4.21 E+03 1112 1112 1013 9522-01 -SC-02-1 6-0 11/15/2006 14:05:00 5.08E+03 5.14E+03 1112 1013 9522-01 -BC-02-1 7-0 14:06:00 4.49E+03 1112 1013.
9522-01 -SC-02-1 7-0 11/15/2006 14:08:00 4.95E+03 5.45E+03 1112 1013
.11/15/2006.
92-1-BC-02-1 8-0 6.1 5E+03. 1112 1013 11/15/2006 9522-01 -SC-02-1 8-0 14:10:00 6.85E+03 7.27E+03 1112 1013 91522-01 -BC-02-1 9-0 11/15/2006 .7.24E+03 1112 1013 9522-01 -SC-02-1 9-0 14:12:00 7.21 E+03 8.46E+03 1112 1013 9522-01 -ER-02-1 9-1 11/16/2006 7:18:00 9.68E+00 8.46E+03 1112 1013 9522-01 -ER-02-1 9-2 11/16/2006 7:19:00 6.31 E+03 8.46E+03 1013 REVISION 0 Page 2 of 4
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD Attachment 2 Survey Location Log Date Log Time Reading Alarm Level >Alarm E-600 SIN Probe SIN Level SCAN AREA #3 9522-*1-BC-03-01-0 1112112006 10:7:00 71.27E+03 1114 1014 9522-01 -SC-03-01-0 11/21/2006 10:10:00 7.54E+03 8.49E+03 1114 1014 9522-01 -BC-03-02-0 11/21/2006 10:11:00 8.89E+03 1114 1014 9522-01-SC-03-02-0 11/21/2006 10:13:00 6.32E+03 1.02E+04 1114 1014 9522-01-BC-03-03-0 11/21/2006 10:14:00 8.39E+03 1114 1014 9522-01-SC-03-03-0 11/21/2006 10:18:00 9.39E+03 9.70E+03 1114 1014 9522-01 -ER-03-03-1 11/2112006 12:54:00 1.IOE+04 9.70E+03 + 1114 1014 9522-01 -BC-03-04-0 1121/2 120..0 .6 10:19:0.0 9.7..5
.E+03 1114 1014 9522-01 -SC-03-04-0 11/21/2006 10:21:00 8.OOE+03 1.12E+04 1114 1014 REVISION 0 Page 3 of 4
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-000 1 RELEASE RECORD Attachment 2 SCAN RESULTS @ SAMPLE LOCATIONS
>Alarm E-600 S/N Survey Location Log Date Log Time Reading Alarm Level Probe S/N Level 9522-01-BL-00-01 -0 11/912006 9:55:00 8.75E+03 1114 1014 9522-01-SL-00-01-0 111912006 9:55:00 1.05E+04 1.01E+04 + 1114 1014 9522-01-BL-00-02-0 11/9/2006 9:54:00 9.72E+03. 1114 1014 9522-01 -SL-00-02-0 11/9/2006 9:54:00 1.10E+04 1.11E+04 1114 1014 9522-01 -BL-00-03-0 11/9/2006 9:58:00 9.1 7E+03 1114 1014 9522-01 -SL-00-03-0 11/9/2006 9:58:00 1.05E+04 1.05E+04 1114 1014 9522-01 -BL00504-0 11/9/2006 : 14:05:00 1.03E+04 1114 1014 9522-01 -SL-00-04-0 11/9/2006 14:05:00 1.08E+04 1.17E+04 1114 1014 9522-01 -BL-00-05-0 11/9/2006 13:58:00 9.18E+03 1114 1014 9522-01 -SL-00-05-0 11/9/2006 13:58:00 9.1 2E+03 1.05E+04 1114 1014 9522-01 -BL-00-06-0 11/9/2006 14:00:00 ..8.72Ei+03. ,. .11. 14. 1014 9522-01-SL-00-06-0 11/9/2006 14:00:00 1.03E+04 1.01E+04 + 1114 1014 9522-01 -BL-00-08::0 11/9/2006 13:11:00 ..7.03E+03. 1114 1014 9522-01 -SL-00-08-0 11/9/2006 13:11:00 8.30E+03 8.23E+03 + 1114 1014 9522-01 -BL-00-09-0 11/9/2006 10:57:00 6.52E+03 1114 9522-01-SL-00-09-0 11/9/2006 10:57:00 6.96E+03 7.67E+03 1114 1014
,9522-01.BL00-10-02 11/9/2006 10:52:00 9.71 E+0 13 1014 9522-03-SL-00-1 0-0 11/9/2006 10:52:00 7.69E+03 1.11E+04 1114 1014 9522-01-BL-00-1 1 -0 .13:12:00. .7.13E+03. 1114 1014 9522-01 -SL-00-1 1-0 11/9/2006 13: 12: 00 7.41 E+03 8.34E+03 1114 1014 .9522-01 BL-001 2-0 11/9/2006 8:08:00 6.25E+03 1114 1014 9522-03-SL-00-12-0 11/9/2006. 8:08:00 6.33E+03 7.38E+03 1114 1014 9522-01S L-00-1 -0 11/9/2006 13:37:00 4.78E+03 1114 1014 9522-01 -SL-00-1 3-0 11/9/2006. 13:37:00 4.55E+03 5.77E+03 1114 1014 9522-01 -SL-00-143-0. 11/9/2006 10:54:00 5.75E+03 1114 1014 iiii*ii!*iii*ii*i;ii
÷ 9522-01 -SL-00-14-0 10:54:00 7.69E+03 6.83E+03 1114 1014 11/9/2006 i!ii*ii*iiiiiiiiiii 9522-01 -BL-00-15-0 8:15:00 7.9.E+03 1114 1014 11/9/2006 ÷ 9522-01 -SL-00-1 5-0 8:15:00 9.75E+03 9.17E+03 1114 1014 19522-01 miBL-001 6-0 11/15/2006 9:.35:00 7.75E+03 1116 1006 9522-01 -SL-00-1 6-0 11/15/2006 9:35:00 7.15E+03 9.01IE+03 1116 1006 REVISION 0 Page 4 of 4
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 3 (LABORATORY DATA) Revision 0
General Narrative 1
General Narrative for Connecticut Yankee Atomic Power Co. Work Order: 176896 SDG: MSR#06-1505 December 01, 2006 Laboratory Identification: General Engineering Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 Summary Sample receipt The samples arrived at General Engineering Laboratories, LLC, Charleston, South Carolina on November 30, 2006 for analysis. Shipping container temperatures were checked, documented, and within specifications. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any visible signs of tampering or breakage. Sample Identification The laboratory received the following samples: Laboratory Sample Identification Description 176896001 9522-0001-012F 176896002 9522-0001-015F 176896003 9522-0001-002F 176896004 9522-0001-OOIF 176896005 9522-0001-003F 176896006 9522-0001-O0OF 176896007 9522-0001-014F 176896008 9522-0001-009F 176896009 9522-0001-009FS 176896010 9522-0001-008F 176896011 9522-0001-01 IF 176896012 9522-0001-013F 176896013 9522-0001-005F 176896014 9522-0001-006F 176896015 9522-0001-004F 176896016 9522-0001-016F 176896017 9522-0001-017-1 176896018 9522-0001-018-1 176896019 9522-0001-019-I 176896020 9522-0001-020-I 176896021 9522-0001-021-1 176896022 9522-0001-022-I 176896023 9522-0001-023-1 176896024 9522-0001-024-1 GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC. P.O. BOX 30712 Charleston, SC 29417 , 2040 Savage Road (29407) Phone (843) 556-8171 , Faxb43) 766-1178 www .gel.com
Items of Note There are no items to note. Case Narrative Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package. Analytical Request Twenty-two soil samples were analyzed for FSSGAM. Two soil samples were analyzed for FSSALL. Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, Data Review Qualifier Definitions, and data from the following fractions: Radiochemistry. I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee,' as verified by the following signature. Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC. P.O. BOX 30712 Charleston, SC 29417 "2040 Sayage Road (29407) Phone (643) 556-8171 - Fax343) 766-1178 www.gel.com
List of current GEL Certifications as of 01 December 2006 State Certification Alaska UST-062 Arizona AZ0668 Arkansas 88-0651 CLIA 42D0904046 California 01 151CA Colorado GenEngLabs Connecticut PH-0169 Dept. of Navy NFESC 413 EPA WG- I5J Florida/NELAP E87156 Georgia E87156 (FL/NELAP) Hawaii N/A Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas E-10332 Kentucky 90129 Louisiana 03046 Maryland 270 Massachusetts M-SC012 Michigan 9903 Nevada SC12 New Jersey SCO02 New Mexico FL NELAP E87156 New York 11501 North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-00485 South Carolina 10120001/10585001/10120002 Tennessee 02934 Texas TX213-2006A Texas NELAP TI 04704235-06-TX U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Vermon 8037697376 GEL Vermont VT87156 Virginia 00151 Washington C1641 4
Chain of Custody and Supporting Documentation 5
4,¸. Health Physics, Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00666 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 < 843 556 8171. Attn. Cheryl Jones Priority:D] 30 D. E] 14 D. Z 7 D. D 3 D. Container Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-000i-012F 11/09/06 0808 TS G BP X II 9522-0001-015F 11/09/06 0815 TS G BP X 9522-0001-002F 11/09/06 0954 TS G BP X 9522-0001-OOIF 11/09/06 0955 TS G BP X 9522-0001-003F 11/09/06 0958 TS G BP X 9522-0001-010F 11/09/06 1052 TS G BP X 9522-0001-014F 11/09/06 1054 TS G BP X 9522-0001-009F 11/09/06 1057 TS G BP X "9522-0001-009FS 11/09/06 1057 TS G BP X 9522-0001-008F 11/09/06 1311 TS G BP X 9522-0001-01IF 11/09/06 1312 TS G BP X NOTES: PO #: 002332 MSR #: 06-U16",6" SSWP# NA 0 LTP QA ni Radwaste QA El Non QA Samples Shipped Via: Internal Container S Fed Ex Temp.: __Deg. F- uPs C MI Hand Custody Sealed? YLU N]1
- 1) Relinquished By Date/Time 2) d By Date/Time Custody Seal E] Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time YD N]L Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Chain of Custody Form N.20-06 Connecticut Yankee Atomic Power Company No. 2006-00667 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories
- 2040 Savage Road. Charleston SC. 29407 0 <
843 556 8171. Attn. Cheryl Jones Priority: U 30 D. ] 14 D. M 7 D. ] 3D. Container Ca
-I 4 (Asq (ýr_1, Sample Size- -Sample Designation- Date Time Media Type &Type Comment, Preservation - Lab Sample ID Code Code Code
, 9522-0001-013F 11/09/06 1337 TS G BP X ,_ 9522-0001-005F 11/09/06 1358 TS G BP X , 9522-0001-006F 11/09/06 1400 TS G BP X 9522-0001-004F 11/09/06 1405 TS G BP X NOTES: PO #: 002332 MSR #: 06-13l. SSWP# NA [ LTP QA U Radwaste QA Ul Non QA Samples Shipped Via: Internal Container [ Fed Ex Temp.: - Deg. U UPS C U Hand Custody Sealed? YO NO
- 1) Relinquished By Date/Time ofived By Date/Time Custody Seal Ul Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time Y0 N]
Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Maj or Chain of Custody Form N.20-07 Connecticut Yankee Atomic Power Company No. 2006-00671 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority: E] 30 D. E] 14 D. E 7 D. El 3 D. o Container ' - " / Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0001-016F 11/15/06 j . TS G BP X r - , - - NOTES: PO #: 002332 MSR #: 06-1-3Wl' SSWP# NA LTP QA D Radwaste QA F1 Non QA Samples Shipped Via: Internal Container 0 Fed Ex Temp.: __ Deg. F- UPS C fl Hand Custody Sealed? YF1 N0
- 1) Relinquished By Date/Time 2) Reyi ed By Date/Time Custody Seal E] Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time YD NEI Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Maj or Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00677 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Cn Priority: FZ 30 D. [] 14 D. E 7 D. ] 3 D. Contaer 4Q 9Q Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID
- Code-- Code- Code 9522-0001-017-I 11/16/06 0716 TS G BP X _
9522-0001-018-1 11/16/06 0717 TS G BP X 9522-0001-019-1 11/16/06 0718 TS G BP X 9522-0001-020-1 11/16/06 0719 TS G BP X 9522-0001-021-1 11/16/06 1335 TS G BP X 9522-0001-022-1 11/16/06 1340 TS G BP X 9522-0001-023-1 11/16/06 1345 TS G BP X
~.- . .
- NOTES: PO #: 002332 MSR #: 06-W $ SWP# NA LTP QA E] Radwaste QA El Non QA Samples Shipped Via: Internal Container 0 Fed Ex Temp.: - Deg..:
El UPS , C * [] Hand Custody Sealed? Y N
- 1) Relinquished By Date/Time 2 ed By Date/Time :Custody Seal El Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time Y N Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Chain of Custody Form N.20-08 Connecticut Yankee Atomic Power Company No. 2006-00684 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Uý (I Priority: 1] 30 D. r 14 D. Z 7 D. [] 3 D. Conti-er(IC. c6 9( Container Sample Size-Sample Designation Date Time Media Type &Type t, Preservation Lab Sample ID Code Code Code 9522-0001-024-I 11/21/06 [ 5_ TS G BP X
'VOW,~d7f NOTES: PO #: 002332 MSR #: 06-J.n¶ SSWP4 NA [E LTP QA El Samples Shipped Via:
El Radwaste QA Non QA Internal Container i!56 [ Fed Ex Temp.: _ Deg. I: UPS C E! Hand Custody Sealed? YE NO
- 1) Relinquished By Date/Time 2 Date/Time Custody Seal El Other Intact?
0 R4 0
- 3) Relinquished By Date/Time 4) Received By Date/Time YE NE Bill of Lading #
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Samplc Check-in List Datc/Timc Reccived: 3 - C.A I/) i/ D SDG#: M', O ,t- k t5-Oc -- Work Order Number:_ C4 U I%G, -,5 qC Shipping Container ID: ,.Se*e ij i tdvca1 m Of CUstody # url
- 1. Custody Seals on shipping container intact'? Yes (No []
- 2. Custody Seals dated and signed'? Yes,._] No []
- 3. Chain-of-Custody record present? Yes kL\No []
- 4. Cooler tenperature .S ,*pv 4
-i@..3 V-,*, 5h..w fd'
- 5. Vermiculite/packing materials is: Wet [] Dry [>
- 6. Number of samples in shipping container:
- 7. Sample holding times exceeded'? Yes [] No
- 8. Samples have:
_ tape - hazard labels custody seals appropriate sample labels
- 9. Samples are:
.& in good condition leaking broken have air bubbles
- 10. Were any anomalies identified in sample receipt? Yes X No It. Description of anomalies (include sample numbers): 0 -, . in ý
-n0 Sample Custodian/Laboratory: Date: /P30(n Telephoned to: On By Page 45 of 56 11
0 SAMPLE RECEIPT & REVIEW FORM IClient:Received:- Date Received By: A I& ¶ PMI(A) Review (enswreOrder-JSDC/ARCOCJWork nono a-PM ane ony (000 Items are1resolvedg(, 99prior l4 do1ft: j Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conformlný Items) Shipping containers received intact Circle Applicable: seals broken damaged container leaking container ol" (describe) and
-- sealed? .... __
Samples requiring cold Circle Coolant I ice bags blue ice dry ice none (ttrdewsribe) 2 preservation within (4 +/- 2 C)? Record preservation method. _-",__ . __ Chain of custody documents included with shipment? ,,__ 4 Sample containers intact and ircie Applicable: seals broken damaged container leaking container o ,tidccr*b*) sealed? Samples requiring chemical ample ID's, containers affected and observed pH: reservation at proper pH? '__ VOA vials free of headspace sane I's and containers affected: 6defined as < 6mm bubble)? Are Encore containers present? 7 (If yes, immediately deliver to VOA laboratory) .attfe Samples received within holding Id's and ts affced: rime? Sample ID's on COC match ID's Sample ID's and containers affected: on bottles? Date & time on COC match date Sample ID's affected: 0&time on bottles? Number of containers received Sample ID's affecte: match number indicated on COC? ___ COC form is properly signed in 12relinquished/received sections? _ 4 :51 5n, qIa I
- 1 II O I Il I Air Bill ,Tracking #'s, & qOq- O -119 ,Q7nQ c" 0 'i Additional Comments ýQooit(-gOY 11C400
-~~~~~~0
_2~ _ _ _ t92 53 tfl
-0 RSO RAD Receipt #/_ _
-if > x2 area background is observed on samples identified *non-Suspected Hazard Information " A regulated/non-radioactive", contact the Radiation Safety group for further 09 investigation.
Radiological Classification? 7 Maximum Counts Observed: BPB Regulated? hlipped as DOT Hazardous
,C Material?orIf ESH yes, contact Manager. Waste Hazard Class Shipped:
Manager D Regulated as a Foreign Soil? PM (or PMA) PMreview r osDate: of (ot-is Hazard classifica*tiow., t 12
SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM 13
Data Review Qualifier Definitions 14
Data Review Qualifier Definitions Qualifier Explanation
- A quality control analyte recovery is outside of specified acceptance criteria
- Analyte is a surrogate compound
- Result is less than value reported
> Result is greater than value reported RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank B Metals-Either presence of analyte detected in the associated blank, or MDL/IDL < sample value < PQL BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample d 5-day BOD-The 2:1 depletion requirement was not met for this sample E Organics-Concentration of the target analyte exceeds the instrument calibration range E Metals-%difference of sample and SD is >10%. Sample concentration must meet flagging criteria H Analytical holding time was exceeded h Preparation or preservation holding time was exceeded J Value is estimated N Metals-The Matrix spike sample recovery is not within specified control limits N Organics-Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest internal standard response factor N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the reporting limit UI Gamma Spectroscopy-Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound Z Paint Filter Test-Particulates passed through the filter, however no free liquids were observed. GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC. P.O. BOX 30712 Charleston, SC 29417 , 2040 Savage Road (29407) Phone (843) 556-8171 - Fa*,(3) 768-1178 www.gel.com
I RADIOLOGICAL ANALYSIS 16
Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK) Work Order 176896 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 592107 Prep Batch Number: 592100 Dry Soil Prep GL-RAD-A-021 Batch Number: 592095 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238056 Method Blank (MB) 1201238057 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238058 176896007(9522-0001-014F) Matrix Spike (MS) 1201238059 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. 17
Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Manual Integration No manual integrations were performed on data in this batch. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information 18
Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- 1-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 592108 Prep Batch Number: 592100 Dry Soil Prep GL-RAD-A-021 Batch Number: 592095 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238060 Method Blank (MB) 1201238061 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238062 176896007(9522-0001-014F) Matrix Spike (MS) 1201238063 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Oualitv Control (OC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information All of the QC samples met the required acceptance limits. 19
Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Manual Integration No manual integrations were performed on data in this batch. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- I1-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 592109 Prep Batch Number: 592100 Dry Soil Prep GL-RAD-A-021 Batch Number: 592095 20
Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238064 Method Blank (MB) 1201238065 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238066 176896007(9522-0001-014F) Matrix Spike (MS) 1201238067 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 21
referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Manual Integration No manual integrations were performed on data in this batch. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method: EML HASL 300, 4.5.2.3 Prep Method: Dry Soil Prep Analytical Batch Number: 592140 Prep Batch Number: 592095 22
Sample ID Client ID 176896001 9522-0001-012F 176896002 9522-0001-015F 176896003 9522-0001-002F 176896004 9522-0001-O0IF 176896005 9522-0001-003F 176896006 9522-0001-O0OF 176896007 9522-0001-014F 176896008 9522-0001-009F 176896009 9522-0001-009FS 176896010 9522-0001-008F 176896011 9522-0001-01IF 176896012 9522-0001-013F 176896013 9522-0001-005F 176896014 9522-0001-006F 176896015 9522-0001-004F 176896016 9522-0001-016F 176896017 9522-0001-017-1 176896018 9522-0001-018-1 176896019 9522-0001-019-1 176896020 9522-0001-020-I 1201238138 Method Blank (MB) 1201238139 176896001(9522-0001-012F) Sample Duplicate (DUP) 1201238140 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 13. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896001 (9522-0001-012F). 23
QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments The sample and the duplicate, 1201238139 (9522-0001-012F) and 176896001 (9522-0001-012F), did not meet the relative percent difference requirement for Pb-212, however they do meet the relative error ratio requirement with value of 2.89. Qualifier information 24
Qualifier Reason Analyte Sample U' Data rejected due to high peak-width. Actinium-228 176896012 Bismuth-212 176896005 Cesium- 137 176896017 Cobalt-60 1201238139 UI Data rejected due to interference. Europium- 155 176896005 UI Data rejected due to low abundance. Cesium- 134 176896001 176896003 176896006 176896014 176896015 176896016 Niobium-94 176896008 UI Data rejected due to no valid peak. Cobalt-60 176896007 Method/Analysis Information Product: Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method: EML HASL 300, 4.5.2.3 Prep Method: Dry Soil Prep Analytical Batch Number: 592142 Prep Batch Number: 592096 Sample ID Client ID 176896021 9522-0001-021-I 176896022 9522-0001-022-I 176896023 9522-0001-023-1 176896024 9522-0001-024-1 1201238141 Method Blank (MB) 1201238142 176890002(9522-0004-001FS) Sample Duplicate (DUP) 1201238143 Laboratory Control Sample (LCS) 25
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 3 REV# 13. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176890002 (9522-0004-001FS). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments The sample and the duplicate, 1201238142 (9522-0004-OO1FS), did not meet the relative percent difference requirement for Ac-228 and T1-208, however they do meet the relative error ratio requirement with value of 2.44 for Ac-228 and 1.80 for TI-208. 26
Oualifier information Qualifier Reason Analyte Sample UI Data rejected due to low abundance. Cesium-134 176896021 176896024 1201238142 Thallium-208 1201238141 Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 592186 Prep Batch Number: 592100 Dry Soil Prep GL-RAD-A-021 Batch Number: 592095 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238231 Method Blank (MB) 1201238232 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238233 176896007(9522-0001-014F) Matrix Spike (MS) 1201238234 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. 27
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information Refer to Non-Conformance Report. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG: NCR 390300 was generated due to Container scanning event for custody missed and Failed RPD for DUP. 1. Sample 176896007 and 1201238232 did not meet the relative percent difference due to the matrix of the sample. Large amounts of the sample was used to achieve the detection limit. 2. The analyst did not scan the samples 176890005, 176890008, 176896007, and 176896010 into the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on the proper scanning procedures. 1. Client was contacted and granted relief to report results. 2. Reporting results. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. 28
Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 592312 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238554 Method Blank (MB) 1201238555 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238556 176896007(9522-0001-014F) Matrix Spike (MS) 1201238557 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same :geometry as the calibration standards. Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. 29
Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments The blank result for 1201238554 (MB) is greater than the MDA but less than the detection limit. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 592304 Prep Batch Number: 592100 Dry Soil Prep GL-RAD-A-021 Batch Number: 592095 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238526 Method Blank (MB) 1201238527 176518004(9504-0000-004F) Sample Duplicate (DUP) 1201238528 176518004(9504-0000-004F) Matrix Spike (MS) 1201238529 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this 30
narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176518004 (9504-0000-004F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Samples 176896007 (9522-0001-014F) and 176896010 (9522-0001-008F) were reprepped due to high blank activity. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information 31
Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 592310 Prep Batch Number: 592100 Dry Soil Prep GL-RAD-A-021 Batch Number: 592095 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238546 Method Blank (MB) 1201238547 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238548 176896007(9522-0001-014F) Matrix Spike (MS) 1201238549 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Ouality Control (OC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information 32
All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: LSC, Tritium Dist, Solid - 3 pCi/g Analytical Method: EPA 906.0 Modified Analytical Batch Number: 593064 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201240325 Method Blank (MB) 1201240326 176890008(9522-0004-007F) Sample Duplicate (DUP) 1201240327 176890008(9522-0004-007F) Matrix Spike (MS) 1201240328 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 13. 33
Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (OC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176890008 (9522-0004-007F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Samples 176896007 (9522-0001-014F) and 176896010 (9522-0001-008F) were reprepped due to low/high recovery. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information 34
Product: Liquid Scint C14, Solid AIl,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 592313 Sample ID Client ID 176896007 9522-0001-014F 176896010 9522-0001-008F 1201238558 Method Blank (MB) 1201238559 176896007(9522-0001-014F) Sample Duplicate (DUP) 1201238560 176896007(9522-0001-014F) Matrix Spike (MS) 1201238561 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 176896007 (9522-0001-014F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. 35
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Review Validation: GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package. The following data validator verified the information presented in this case narrative: Reviewer/Date: 36
!/General Engineering Laboratories NCR Report No.: 390300 Form GEL-NCR Revision No.: Rev. 06/05 COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr. Division: Quality Criteria: Type: 07-DEC-06 Radiochemistry Specifications Process Instrument Type: Test / Method: Matrix Type: Client Code: GFPC EPA 905.0 Modified Solid YANK Batch ID: Sample Numbers: 592186 See Below Potentially affected work order(s)(SDG): 176890(MSR#06-1506),176896(MSR#06-1505) Application Issues: Container scanning event for custody missed Failed RPD for DUP Specification and Requirements NRG Disposition: Nonconformance
Description:
- 1. Sample 176896007 and 1201238232 did not meet the relative percent 1. Client was contacted and granted relief to report results.
difference due to the matrix of the sample. Large amounts of the sample was used to achieve the detection limit.
- 2. The analyst did not scan the samples 176890005, 176890008, 2. Reporting results.
176896007, and 176896010 into the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on the proper scanning procedures. Originator's Name: Data Validator/Group Leader: Melanie Aycock 07-DEC-06 Heather Anderson 07-DEC-06 Quality Review: Director: Page 1 37
SAMPLE DATA
SUMMARY
38
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANK001 Connecticut Yankee Atomic Power Co. Client SDG: MSR#06-1505 GEL Work Order: 176896 The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
- Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the detection limit. The above sample is reported on a dry weight basis except where prohibited by the analytical procedure. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones. Reviewed by 39
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-012F Project: YANK01204 Sample ID: 176896001 Client ID: YANK00i Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.690 +/-0.169 0.0534 +/-0.169 0.119 pCi/g MJH1 12/05/06 0937 592140 Americium-241 U -0.0319 +/-0.0718 0.0666 +/-0.0718 0.138 pCi/g Bismuth-212 0.737 +/-0.318 0.131 +/-0.318 0.285 pCi/g Bismuth-214 0.474 +/-0.0988 0.035 +/-0.0988 0.0749 pCi/g Cesium-134 U1 0.00 +/-0.0205 0.0237 +/-0.0205 0.0508 pCi/g Cesium-137 0.0504 +/-0.044 0.0183 +/-0.044 0.0393 pCi/g Cobalt-60 U 0.0122 +/-0.0226 0.0208 +/-0.0226 0.046 pCi/g Europium-152 U -0.0356 +/-0.0562 0.0489 +/-0.0562 0.104 pCi/g Europium-154 U 0.0201 +/-0.0657 0.0588 +/-0.0657 0.130 pCi/g Europium-155 U -0.014 +/-0.0582 0.0529 +/-0.0582 0.110 pCi/g Lead-212 0.637 +/-0.0778 0.0303 +/-0.0778 0.0633 pCi/g Lead-214 0.591 +/-0.0967 0.0343 +/-0.0967 0.0727 pCi/g Manganese-54 U 0.00981 +/-0.0206 0.0184 +/-0.0206 0.040 pCi/g Niobium-94 U 0.0153 +/-0.0127 0.0164 +/-0.0127 0.0354 pCi/g Potassium-40 8.72 +/-0.980 0.153 +/-0.980 0.351 pCi/g Radium-226 0.474 +/-0.0988 0.035 +/-0.0988 0.0749 pCi/g Silver-108m U -0.00701 +/-0.0167 0.0144 +/-0.0167 0.0309 pCi/g Thallium-208 0.169 +/-0.0436 0.018 +/-0.0436 0.0387 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 40
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-012F Project: YANK01204 Sample ID: 176896001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 41
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-015F Project: YANK01204 Sample ID: 176896002 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.51 +/-0.294 0.114 +/-0.294 0.245 pCi/g MJHI 12/05/06 0938 592140 Americium-241 U -0.0253 +/-0.0587 0.0463 +/-0.0587 0.0956 pCi/g Bismuth-212 0.931 +/-0.590 0.277 +/-0.590 0.588 pCi/g Bismuth-214 1.64 +/-0.209 0.0585 +/-0.209 0.124 pCi/g Cesium-134 U 0.0709 +/-0.049 0.0454 +/-0.049 0.096 pCi/g Cesium-137 U 0.0411 +/-0.0451 0.0407 +/-0.0451 0.0857 pCi/g Cobalt-60 U 0.0138 +/-0.0451 0.0388 +/-0.0451 0.0844 pCi/g Europium-152 U -0.0674 +/-0.0964 0.0776 +/-0.0964 0.163 pCi/g Europium-154 U -0.076 +/-0.166 0.113 +/-0.166 0.244 pCi/g Europium-155 U 0.107 +/-0.126 0.0783 +/-0.126 0.162 pCi/g Lead-212 1.39 +/-0.132 0.0745 +/-0.132 0.153 pCi/g Lead-214 1.88 +/-0.166 0.0577 +/-0.166 0.121 pCi/g Manganese-54 U -0.0436 +/-0.0442 0.0335 +/-0.0442 0.0717 pCi/g Niobium-94 U 0.00226 +/-0.0372 0.0316 +/-0.0372 0.0671 pCi/g Potassium-40 23.1 +/-1.70 0.274 +/-1.70 0.614 pCi/g Radium-226 1.64 +/-0.209 0.0585 +/-0.209 0.124 pCi/g Silver-108m U 0.038 +/-0.0319 0.0296 +/-0.0319 0.0623 pCi/g Thallium-208 0.504 +/-0.0769 0.0289 +/-0.0769 0.0619 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 42
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-015F Project: YANK01204 Sample ID: 176896002 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 43
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-002F Proiect: YANK01204 Sample ID: 176896003 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 28.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.995 +/-0.250 0.0769 +/-0.250 0.169 pCi/g MJHI 12/05/06 0938 592140 Americium-241 U 0.0119 +/-0.0358 0,0316 +/-0.0358 0.0653 pCi/g Bismuth-212 1.12 +/-0.360 0.144 +/-0.360 0.318 pCi/g Bismuth-214 1.07 +/-0.119 0.0361 +/-0.119 0.0786 pCi/g Cesium- 134 UI 0.00 +/-0.0531 0.0315 +/-0.0531 0.0675 pCi/g Cesium-137 0.666 +/-0.0684 0.0281 +/-0.0684 0.060 pCi/g Cobalt-60 U 0.024 +/-0.0293 0.0273 +/-0.0293 0.0607 pCi/g Europium-152 U -0.0805 +/-0.0712 0.0546 +/-0.0712 0.116 pCi/g Europium-154 U 0.00768 +/-0.0971 0.0823 +/-0.0971 0.181 pCi/g Europium-155 U 0.0333 +/-0.0534 0.0507 +/-0.0534 0.106 pCi/g Lead-212 1.13 +/-0.0802 0.0314 +/-0.0802 0.0659 pCi/g Lead-214 1.14 +/-0.102 0.0422 +/-0.102 0.0892 pCi/g Manganese-54 U 0.00223 +/-0.0303 0.0253 +/-0.0303 0.0548 pCi/g Niobium-94 U -0.00704 +/-0.0237 0.0194 +/-0.0237 0.0421 pCi/g Potassium-40 11.9 +/-1.13 0.185 +/-1.13 0.431 pCi/g Radium-226 1.07 +/-0.119 0.0361 +/-0.119 0.0786 pCi/g Silver-108m U -0.0199 +/-0.025 0.0209 +/-0.025 0.0444 pCi/g Thallium-208 0.339 +/-0.0558 0.0203 +/-0.0558 0.0441 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 44
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-002F Project: YANK01204 Sample ID: 176896003 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 45
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-001F Project: YANKO 1204 Sample ID: 176896004 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 29.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.17 +/-0.269 0.0746 +/-0.269 0.166 pCi/g MJH1 12/05/06 0939 592140 Americium-241 U 0.0035 +/-0.102 0.0784 +/-0.102 0.163 pCi/g Bismuth-212 0.820 +/-0.401 0.163 +/-0.401 0.359 pCi/g Bismuth-214 0.886 +/-0.136 0.0383 +/-0.136 0.0835 pCi/g Cesium-I 34 U 0.0563 +/-0.032 0.0313 +/-0.032 0.0675 pCi/g Cesium-I 37 0.677 +/-0.0983 0.0236 +/-0.0983 0.0513 pCi/g Cobalt-60 U-0.000186 +/-0.0276 0.0234 +/-0.0276 0.0531 pCi/g Europium-152 U 0.0743 +/-0.107 0.0631 +/-0.107 0.134 pCi/g Europium-154 U -0.035 +/-0.0882 0.071 +/-0.0882 0.159 pCi/g Europium-155 U 0.0447 +/-0.0777 0.0651 +/-0.0777 0.136 pCi/g Lead-212 1.17 +/-0.129 0.0333 +/-0.129 0.0703 pCi/g Lead-214 0.965 +/-0.167 0.0402 +/-0.167 0.0859 pCi/g Manganese-54 U 0.0156 +/-0.0284 0.0252 +/-0.0284 0.0549 pCi/g Niobium-94 U -0.00061 +/-0.025 0.0212 +/-0.025 0.046 pCi/g Potassium-40 11.5 +/-1.33 0.154 +/-1.33 0.372 pCi/g Radium-226 0.886 +/-0.136 0.0383 +/-0.136 0.0835 pCi/g Silver-108m U -0.006 +/-0.0245 0.0196 +/-0.0245 0.0422 pCi/g Thallium-208 0.339 +/-0.0726 0.0207 +/-0.0726 0.0451 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 46
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-OOIF Project: YANK01204 Sample ID: 176896004 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 47
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-003F Proiect: YANK01204 Sample ID: 176896005 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 32.4% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.25 +/-0.396 0.112 +/-0.396 0.252 pCi/g MJH1 12/05/06 0940 592140 Americium-241 U 0.000605 +/-0.0563 0.0471 +/-0.0563 0.0981 pCi/g Bismuth-212 UI 0.00 +/-0.615 0.280 +/-0.615 0.614 pCi/g Bismuth-214 1.03 +/-0.177 0.0759 +/-0.177 0.163 pCi/g Cesium-134 U 0.0945 +/-0.0985 0.0514 +/-0.0985 0.111 pCi/g Cesium-137 1.17 +/-0.117 0.0355 +/-0.117 0.0777 pCi/g Cobalt-60 U -0.00228 +/-0.0553 0.0444 +/-0.0553 0.0996 pCi/g Europium-152 U -0.105 +/-0.115 0.0902 +/-0.115 0.192 pCi/g Europium-154 U 0.000711 +/-0.134 0.109 +/-0.134 0.246 pCi/g Europium-155 UI 0.00 +/-0.148 0.0709 +/-0.148 0.149 pCi/g Lead-212 1.31 +/-0.120 0.0467 +/-0.120 0.0987 pCi/g Lead-214 1.40 +/-0.186 0.0627 +/-0.186 0.134 pCi/g Manganese-54 U -0.0278 +/-0.0456 0.0357 +/-0.0456 0.0789 pCi/g Niobium-94 U 0.00883 +/-0.0412 0.0359 +/-0.0412 0.0779 pCi/g Potassium-40 12.5 +/-1.63 0.310 +/-1.63 0.728 pCi/g Radium-226 1.03 +/-0.177 0.0759 +/-0.177 0.163 pCi/g Silver-108m U 0.00935 +/-0.0366 0.031 +/-0.0366 0.0667 pCi/g Thallium-208 0.419 +/-0.102 0.0366 +/-0.102 0.0794 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 48
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-003F Project: YANK01204 Sample ID: 176896005 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch IN
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 49
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-O0OF Project: YANK01204 Sample ID: 176896006 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 29.2% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1l Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.938 +/-0.172 0.0553 +/-0.172 0.118 pCi/g MJHI 12/05/06 0940 592140 Americium-241 U -0.00666 +/-0.142 0.0939 +/-0.142 0.194 pCi/g Bismuth-212 0.656 +/-0.255 0.115 +/-0.255 0.245 pCi/g Bismuth-214 0.662 +/-0.0785 0.0307 +/-0.0785 0.0645 pCi/g Cesium-134 UI 0.00 +/-0.0336 0.022 +/-0.0336 0.0462 pCi/g Cesium-137 0.239 +/-0.0412 0.0191 +/-0.0412 0.040 pCi/g Cobalt-60 U -0.00776 +/-0.0226 0.0157 +/-0.0226 0.0343 pCi/g Europium-152 U -0.00378 +/-0.0476 0.0414 +/-0.0476 0.0866 pCi/g Europium-154 U -0.00764 +/-0.0591 0.050 +/-0.0591 0.108 pCi/g Europium-155 U 0.0605 +/-0.0604 0.0556 +/-0.0604 0.115 pCi/g Lead-212 0.879 +/-0.0601 0.0253 +/-0.0601 0.0525 pCi/g Lead-214 0.782 +/-0.0885 0.0294 +/-0.0885 0.0615 pCi/g Manganese-54 U 0.0031 +/-0.0252 0.0179 +/-0.0252 0.0377 pCi/g Niobium-94 U 0.00226 +/-0.0167 0.0146 +/-0.0167 0.0308 pCi/g Potassium-40 14.3 +/-0.878 0.149 +/-0.878 0.325 pCi/g Radium-226 0.662 +/-0.0785 0.0307 +/-0.0785 0.0645 pCi/g Silver-108m U 0.000593 +/-0.0168 0.0144 +/-0.0168 0.0302 pCi/g Thallium-208 0.267 +/-0.0434 0.0153 +/-0.0434 0.0323 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 50
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-O0OF Proiect: YANK01204 Sample ID: 176896006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 51
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-014F Proiect: YANKO 1204 Sample ID: 176896007 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 21.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.105 +/-0.153 0.0841 +/-0.154 0.258 pCi/g MXA 12/03/06 0901 592107 I Curium-242 U 0.075 +/-0.129 0.066 +/-0.130 0.231 pCi/g Curium-243/244 U 0.0863 +/-0.154 0.0942 +/-0.154 0.278 pCi/g AIphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0367 +/-0.103 0.0633 +/-0.103 0.222 pCi/g MXA 12/03/06 0901 592108 M Plutonium-239/240 U 0.0268 +/-0.071 0.0316 +/-0.0711 0.159 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 6.51 +/-7.02 5.58 +/-7.05 11.8 pCi/g MXA 12/05/06 1921 592109 I Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.657 +/-0.178 0.0615 +/-0.178 0.135 pCi/g MJHI 12/05/060941 592140 Americium-241 U 0.0409 +/-0.0598 0.0551 +/-0.0598 0.115 pCi/g Bismuth-212 0.561 +/-0.311 0.147 +/-0.311 0.319 pCi/g Bismuth-214 0.601 +/-0.107 0.0348 +/-0.107 0.0747 pCi/g Cesium-134 U 0.047 +/-0.0365 0.0255 +/-0.0365 0.0546 pCi/g Cesium-137 0.291 +/-0.0636 0.019 +/-0.0636 0.0411 pCi/g Cobalt-60 UI 0.00 +/-0.0155 0.011 +/-0.0155 0.0267 pCi/g Europium-152 U -0.0841 +/-0.0577 0.0444 +/-0.0577 0.0948 pCi/g Europium-154 U -0.00935 +/-0.0615 0.0498 +/-0.0615 0.113 pCi/g Europium-155 U -0.0271 +/-0.0552 0.0514 +/-0.0552 0.107 pCi/g Lead-212 0.717 +/-0.0854 0.027 +/-0.0854 0.0567 pCi/g Lead-214 0.592 +/-0.105 0.0341 +/-0.105 0.0725 pCi/g Manganese-54 U 0.0142 F/-0.0277 0.0176 +/-0.0277 0.0386 pCi/g Niobium-94 U -0.00245 +/-0.0192 0.0167 +/-0.0192 0.0362 pCi/g Potassium-40 8.88 +/-1.04 0.136 +/-1.04 0.319 pCi/g Radium-226 0.601 +/-0.107 0.0348 +/-0.107 0.0747 pCi/g Silver-108m U 0.019 +/-0.0203 0.0187 +/-0.0203 0.0396 pCi/g Thallium-208 0.204 F/-0.0498 0.0175 +/-0.0498 0.0378 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.766 +/-0.116 0.0297 +/-0.118 0.0719 pCi/g KSD1 12/07/06 1236 592186 Rad Liquid Scintillation Analysis 52
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-014F Proiect: YANKO01204 Sample ID: 176896007 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.536 +/-1.21 1.02 +/-1.21 2.10 pCi/g DFAl 12/06/06 0204 593064 Liquid Scint C04, Solid AIl, FSS Carbon-14 U -0.0179 +/-0.0898 0.0758 +/-0.0898 0.155 pCi/g AXD2 12/01/06 1937 592313 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -3.56 +/-43.4 33.8 +/-43.4 71.3 pCi/g MXPI 12/02/06 1849 592304 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.44 +/-12.1 10.2 +/-12.1 21.5 pCi/g MXP1 12/04/06 2048 592310 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.194 +/-0.161 0.130 +/-0.162 0.268 pCi/g KXRI 12/06/06 1754 592312 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- 11-RC Modified 3 DOE EML HASL-300, Pu- 11-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-l, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 81 (15%-125%) Plutonium-242 Alphaspec Pu, Solid-ALL FSS 83 (15%-125%) Plutonium-241 Liquid Scint Pu241, Solid-ALL Fý 87 (25%-125%) Strontium-90 GFPC, Sr90, solid-ALL FSS 30 (25%-125%) 53
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-014F Project: YANK01204 Sample ID: 176896007 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1N Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 30 (25%-125%) Iron-55 Liquid Scint Fe55, Solid-ALL FS 54 (15%-125%) Nickel-63 Liquid Scint Ni63, Solid-ALL FS 68 (25%-125%) Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 68 (25%-125%) Technetium-99 Liquid Scint Tc99, Solid-ALL FS 77 (15%-125%) Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 77 (15%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 54
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-009F Proiect: YANK01204 Sample ID: 176896008 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12.7% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.739 +/-0.142 0.0521 +/-0.142 0.113 pCi/g MJHI 12/05/06 0942 592140 Americium-241 U 0.0274 +/-0.094 0.0651 +/-0.094 0.135 pCi/g Bismuth-212 0.641 +/-0.225 0.120 +/-0.225 0.257 pCi/g Bismuth-214 0.598 +/-0.0874 0.0329 +/-0.0874 0.0695 pCi/g Cesium-134 U 0.0159 +/-0.0259 0.0208 +/-0.0259 0.0442 pCi/g Cesium-137 0.116 +/-0.0344 0.0166 +/-0.0344 0.0353 pCi/g Cobalt-60 U -0.00391 +/-0.0203 0.0171 +/-0.0203 0.0373 pCi/g Europium-152 U -0.0172 +/-0.0519 0.0442 +/-0.0519 0.0927 pCi/g Europium-154 U -0.017 +/-0.0525 0.0437 +/-0.0525 0.0958 pCi/g Europium-155 U 0.0315 +/-0.0787 0.0532 +/-0.0787 0.110 pCi/g Lead-212 0.738 +/-0.0618 0.0265 +/-0.0618 0.0551 pCi/g Lead-214 0.582 +/-0.0921 0.0307 +/-0.0921 0.0646 pCi/g Manganese-54 U 0.0123 +/-0.0122 0.0188 +/-0.0122 0.0398 pCi/g Niobium-94 UI 0.00 +/-0.0402 0.0154 +/-0.0402 0.0327 pCi/g Potassium-40 10.4 +/-0.755 0.105 +/-0.755 0.240 pCi/g Radium-226 0.598 +/-0.0874 0.0329 +/-0.0874 0.0695 pCi/g Silver-108m U -0.0134 +/-0.0166 0.0141 +/-0.0166 0.0299 pCi/g Thallium-208 0.196 +/-0.0408 0.0168 +/-0.0408 0.0355 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 55
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-009F Project: YANK01204 Sample ID: 176896008 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A*
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank 1D Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 56
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-009FS Project: YANKO01204 Sample ID: 176896009 Client ID: YANK00I Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.730 +/-0.185 0.0552 +/-0.185 0.119 pCi/g MJH1 12/05/06 1000 592140 Americium-241 U -0.00587 +/-0.116 0.0945 +/-0.116 0.196 pCi/g Bismuth-212 0.446 +/-0.236 0.115 +/-0.236 0.248 pCi/g Bismuth-214 0.579 +/-0.0782 0.0249 +/-0.0782 0.0536 pCi/g Cesium-] 34 U 0.0171 +/-0.0211 0.0192 +/-0.0211 0.0411 pCi/g Cesium-] 37 0.101 +/-0.0351 0.0147 +/-0.0351 0.0316 pCi/g Cobalt-60 U 0.00698 +/-0.0275 0.0174 +/-0.0275 0.0384 pCi/g Europium-152 U -0.0348 +/-0.0476 0.0388 +/-0.0476 0.0819 pCi/g Europium-154 U 0.0378 +/-0.0599 0.0546 +/-0.0599 0.119 pCi/g Europium-155 U -0.0146 +/-0.0516 0.0485 +/-0.0516 0.101 pCi/g Lead-212 0.630 +/-0.0547 0.0241 +/-0.0547 0.0503 pCi/g Lead-214 0.615 +/-0.0857 0.0304 +/-0.0857 0.0638 pCi/g Manganese-54 U 0.0051 +/-0.0184 0.0159 +/-0.0184 0.0343 pCi/g Niobium-94 U 0.00108 +/-0.0164 0.0142 +/-0.0164 0.0304 pCi/g Potassium-40 10.0 +/-0.746 0.105 +/-0.746 0.245 pCi/g Radium-226 0.579 +/-0.0782 0.0249 +/-0.0782 0.0536 pCi/g Silver-108m U -0.00186 +/-0.016 0.0126 +/-0.016 0.0269 pCi/g Thallium-208 0.197 +/-0.0403 0.0155 +/-0.0403 0.033 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 57
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-009FS Proiect: YANK01204 Sample ID: 176896009 Client ID: YANKO0I Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-008F Project: YANK01204 Sample ID: 176896010 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 21% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0199 +/-0.0384 0.0538 +/-0.0385 0.202 pCi/g MXA 12/03/060901 592107
]
Curium-242 U -0.0184 +/-0.0256 0.0488 +/-0.0257 0.202 pCi/g Curium-243/244 U 0.0722 +/-0.144 0.0881 +/-0.144 0.270 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0757 +/-0.171 0.111 +/-0.172 0.333 pCi/g MXA 12/03/06 0901 592108 I Plutonium-239/240 U -0.0296 +/-0.0335 0.0639 +/-0.0337 0.239 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 11.0 +/-8.26 6.42 +/-8.34 13.5 pCi/g MXA 12/05/06 1937 592109 1 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.556 +/-0.158 0.0523 +/-0.158 0.114 pCi/g MJHI 12/05/06 1132 592140 Americium-241 U 0.015 +/-0.106 0.0779 +/-0.106 0.162 pCi/g Bismuth-212 0.320 +/-0.217 0.119 +/-0.217 0.257 pCi/g Bismuth-214 0.413 +/-0.0879 0.0278 +/-0.0879 0.0596 pCi/g Cesium-134 U 0.00824 +/-0.0204 0.0181 +/-0.0204 0.0389 pCi/g Cesium- 137 0.223 +/-0.0382 0.0143 +/-0.0382 0.0309 pCi/g Cobalt-60 U 0.00385 +/-0.0203 0.0177 +/-0.0203 0.0391 pCi/g Europium-152 U - 0.00971 +/-0.0465 0.0394 +/-0.0465 0.0834 pCi/g Europium-154 U 0.0296 +/-0.0803 0.0504 +/-0.0803 0.111 pCi/g Europium-155 U 0.0731 +/-0.066 0.044 +/-0.066 0.0915 pCi/g Lead-212 0.571 +/-0.0532 0.0217 +/-0.0532 0.0456 pCi/g Lead-214 0.438 +/-0.083 0.0266 +/-0.083 0.0566 pCi/g Manganese-54 U 0.0023 +/-0.018 0.0154 +/-0.018 0.0334 pCi/g Niobium-94 U 0.0184 +/-0.0164 0.0155 +/-0.0164 0.033 pCi/g Potassium-40 9.47 +/-0.736 0.127 +/-0.736 0.291 pCi/g Radium-226 0.413 +/-0.0879 0.0278 +/-0.0879 0.0596 pCi/g Silver-108m U 0.0114 +/-0.0153 0.0145 +/-0.0153 0.0308 pCi/g Thallium-208 0.165 +/-0.0436 0.0143 +/-0.0436 0.0308 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.0361 +/-0.031 0.0212 +/-0.0311 0.0495 pCi/g KSDI 12/07/06 1151 592186 Rad Liquid Scintillation Analysis 59
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-008F Project: YANKO 1204 Sample ID: 176896010 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.535 +/-1.20 1.02 +/-1.20 2.10 pCi/g DFAI 12/06/06 0538 593064 Liquid Scint C14, Solid All, FSS Carbon-14 U -0.00299 +/-0.0942 0.0792 +/-0.0942 0.162 pCi/g AXD2 12/01/06 2040 592313 Liquid Scint Fe55, Solid-ALL FSS lron-55 U 1.47 +/-35.2 26.9 +/-35.2 56.6 pCi/g MXPI 12/02/06 1905 592304 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -3.88 +/-11.0 9.37 +/-11.0 19.7 pCi/g MXPI 12/04/06 2104 592310 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.135 +/-0.154 0.125 +/-0.154 0.258 pCi/g KXR1 12/06/06 1825 592312 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I 1-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-1, Modified 10 DOE RESL Ni-1, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 76 (15%-125%) Plutonium-242 Alphaspec Pu, Solid-ALL FSS 82 (15%-125%) Plutonium-241 Liquid Scint Pu241, Solid-ALL FS 75 (25%-125%) Strontium-90 GFPC, Sr90, solid-ALL FSS 47 (25%-125%) 60
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-008F Project: YANK0 1204 Sample ID: 176896010 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 47 (25%-125%) Iron-55 Liquid Scint Fe55, Solid-ALL FS 66 (15%-125%) Nickel-63 Liquid Scint Ni63, Solid-ALL FS 67 (25%-125%) Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 67 (25%-125%) Technetium-99 Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%) Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 61
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-01iF Project: YANK01204 Sample ID: 176896011 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 18.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.590 +/-0.186 0.0549 +/-0.186 0.118 pCi/g MJHI 12/05/06 1133 592140 Americium-241 U 0.00418 +/-0.0783 0.0674 +/-0.0783 0.139 pCi/g Bismuth-212 0.503 +/-0.236 0.126 +/-0.236 0.269 pCi/g Bismuth-214 0.490 +/-0.084 0.0285 +/-0.084 0.0605 pCi/g Cesium-134 U 0.0346 +/-0.0206 0.0192 +/-0.0206 0.0408 pCi/g Cesium-137 0.177 +/-0.0313 0.0171 +/-0.0313 0.0363 pCi/g Cobalt-60 U 0.0132 +/-0.0218 0.0198 +/-0.0218 0.0428 pCi/g Europium-152 U -0.0144 +/-0.0503 0.0434 +/-0.0503 0.0907 pCi/g Europium-154 U 0.0136 +/-0.0613 0.0541 +/-0.0613 0.117 pCi/g Europium-155 U 0.0698 +/-0.0518 0.0499 +/-0.0518 0.103 pCi/g Lead-212 0.587 +/-0.0564 0.0256 +/-0.0564 0.053 pCi/g Lead-214 0.555 +/-0.080 0.0291 +/-0.080 0.0611 pCi/g Manganese-54 U -0.0128 +/-0.0204 0.0171 +/-0.0204 0.0364 pCi/g Niobium-94 U -0.00519 +/-0.0168 0.014 +/-0.0168 0.0298 pCi/g Potassium-40 10.5 +/-0.780 0.129 +/-0.780 0.289 pCi/g Radium-226 0.490 +/-0.084 0.0285 +/-0.084 0.0605 pCi/g Silver-108m U -0.00727 +/-0.0161 0.0142 +/-0.0161 0.0298 pCi/g Thallium-208 0.174 +/-0.042 0.0171 +/-0.042 0.0361 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 62
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-O0IF Project: YANK01204 Sample ID: 176896011 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Ui Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 63
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC.29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-013F Project: YANKO 1204 Sample ID: 176896012 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 10.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 UI 0.00 +/-0.219 0.0557 +/-0.219 0.128 pCi/g MJH1 12/05/06 1134 592140 Americium-241 U 0.0146 +/-0.0256 0.0227 +/-0.0256 0.0478 pCi/g Bismuth-212 U 0.0341 +/-0.183 0.160 +/-0.183 0.352 pCi/g Bismuth-214 0.265 +/-0.0861 0.0353 +/-0.0861 0.0775 pCi/g Cesium-134 U 0.0198 +/-0.0249 0.0233 +/-0.0249 0.0514 pCi/g Cesium-137 U 0.0277 +/-0.022 0.0217 +/-0.022 0.0474 pCi/g Cobalt-60 U 0.00335 +/-0.025 0.0218 +/-0.025 0.0498 pCi/g Europium-152 U 0.000766 +/-0.0527 0.0478 +/-0.0527 0.103 pCi/g Europium-154 U 0.0388 +/-0.070 0.0651 +/-0.070 0.147 pCi/g Europium-155 U 0.0083 +/-0.0449 0.0415 +/-0.0449 0.0875 pCi/g Lead-212 0.289 +/-0.053 0.0281 +/-0.053 0.0595 pCi/g Lead-214 0.291 +/-0.0861 0.0332 +/-0.0861 0.0716 pCi/g Manganese-54 U 0.00791 +/-0.0184 0.0166 +/-0.0184 0.0377 pCi/g Niobium-94 U 0.0194 +/-0.0199 0.019 +/-0.0199 0.0416 pCi/g Potassium-40 4.39 +/-0.761 0.144 +/-0.761 0.350 pCi/g Radium-226 0.265 +/-0.0861 0.0353 +/-0.0861 0.0775 pCi/g Silver-108m U 0.00653 +/-0.0171 0.0158 +/-0.0171 0.0345 pCi/g Thallium-208 0.0611 +/-0.0484 0.0188 +/-0.0484 0.0413 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1301 592095 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 64
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-013F Project: YANKO 1204 Sample ID: 176896012 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 65
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-005F Project: YANK01204 Sample ID: 176896013 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 38.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.20 +/-0.268 0.0715 +/-0.268 0.156 pCi/g MJHI 12/05/06 1135 592140 Americium-241 U -0.00326 +/-0.114 0.0924 +/-0.114 0.192 pCi/g Bismuth-212 0.564 +/-0.344 0.202 +/-0.344 0.430 pCi/g Bismuth-214 0.824 +/-0.142 0.0414 +/-0.142 0.0883 pCi/g Cesium-134 U 0.0305 +/-0.0341 0.0276 +/-0.0341 0.0589 pCi/g Cesium-137 0.824 +/-0.106 0.0229 +/-0.106 0.0489 pCi/g Cobalt-60 U 0.0508 +/-0.0263 0.0278 +/-0.0263 0.0605 pCi/g Europium-152 U -0.0355 +/-0.0644 0.0543 +/-0.0644 0.115 pCi/g Europium-154 U -0.0437 +/-0.0783 0.0597 +/-0.0783 0.133 pCi/g Europium-155 U 0.0828 +/-0.109 0.0575 +/-0.109 0.120 pCi/g Lead-212 0.985 +/-0.107 0.0341 +/-0.107 0.0709 pCi/g Lead-214 0.915 +/-0.145 0.0395 +/-0.145 0.0831 pCi/g Manganese-54 U 0.0129 +/-0.0259 0.0232 +/-0.0259 0.0499 pCi/g Niobium-94 U -0.00613 +/-0.0245 0.0198 +/-0.0245 0.0424 pCi/g Potassium-40 11.1 +/-1.20 0.210 +/-1.20 0.471 pCi/g Radium-226 0.824 +/-0.142 0.0414 +/-0.142 0.0883 pCi/g Silver-108m U -0.0154 +/-0.0241 0.0198 +/-0.0241 0.0419 pCi/g Thallium-208 0.347 +/-0.0719 0.0218 +/-0.0719 0.0465 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 66
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-005F Project: YANK01204 Sample ID: 176896013 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 67
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-006F Project: YANK01204 Sample ID: 176896014 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 44.9% Parameter ()ualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.943 +/-0.221 0.0666 +/-0.221 0.143 pCi/g MJHI 12/05/06 1135 592140 Americium-241 U 0.0124 +/-0.0994 0.0862 +/-0.0994 0.177 pCi/g Bismuth-212 0.583 +/-0.289 0.164 +/-0.289 0.347 pCi/g Bismuth-214 0.907 +/-0.145 0.0364 +/-0.145 0.077 pCi/g Cesium- 134 Ul 0.00 +/-0.039 0.0259 +/-0.039 0.0547 pCi/g Cesium-137 3.08 +/-0.251 0.0205 +/-0.251 0.0434 pCi/g Cobalt-60 0.057 +/-0.0467 0.018 +/-0.0467 0.0399 pCi/g Europium- 152 U -0.0255 +/-0.0682 0.0574 +/-0.0682 0.119 pCi/g Europium-154 U -0.0149 +/-0.0692 0.0558 +/-0.0692 0.122 pCi/g Europium-155 U 0.0414 +/-0.0671 0.058 +/-0.0671 0.119 pCi/g Lead-212 0.888 +/-0.0994 0.0316 +/-0.0994 0.0654 pCi/g Lead-214 1.01 +/-0.144 0.041 +/-0.144 0.0853 pCi/g Manganese-54 U-0.000149 +/-0.0266 0.0198 +/-0.0266 0.0423 pCi/g Niobium-94 U 0.0105 +/-0.0216 0.0183 +/-0.0216 0.0387 pCi/g Potassium-40 8.65 +/-0.992 0.169 +/-0.992 0.376 pCi/g Radium-226 0.907 +/-0.145 0.0364 +/-0.145 0.077 pCi/g Silver-108m U 0.00226 +/-0.0251 0.0213 +/-0.0251 0.0444 pCi/g Thallium-208 0.286 +/-0.051 0.0191 +/-0.051 0.0405 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 68
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-006F Proiect: YANKO 1204 Sample ID: 176896014 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 69
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-004F Project: YANK01204 Sample ID: 176896015 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 42% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1r Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.838 +/-0.155 0.0431 +/-0.155 0.0902 pCi/g MJHI 12/05/06 1136 592140 Americium-241 U -0.13 +/-0.117 0.088 +/-0.117 0.179 pCi/g Bismuth-212 0.537 +/-0.192 0.102 +/-0.192 0.211 pCi/g Bismuth-214 0.970 +/-0.111 0.0223 +/-0.111 0.0463 pCi/g Cesium-134 U1 0.00 +/-0.0306 0.0161 +/-0.0306 0.0334 pCi/g Cesium-] 37 0.637 +/-0.0598 0.0133 +/-0.0598 0.0275 pCi/g Cobalt-60 U 0.0227 +/-0.0158 0.0147 +/-0.0158 0.0309 pCi/g Europium-152 U -0.0052 +/-0.0401 0.0342 +/-0.0401 0.0702 pCi/g Europium-154 U -0.0357 +/-0.0445 0.0362 +/-0.0445 0.0764 pCi/g Europium-155 U 0.0616 +/-0.0575 0.039 +/-0.0575 0.0793 pCi/g Lead-212 0.981 +/-0.0897 0.0196 +/-0.0897 0.040 pCi/g Lead-214 1.10 +/-0.116 0.024 +/-0.116 0.0493 pCi/g Manganese-54 U 0.0082 +/-0.0167 0.0132 +/-0.0167 0.0274 pCi/g Niobium-94 U -0.00353 +/-0.0131 0.0111 +/-0.0131 0.0231 pCi/g Potassium-40 11.7 +/-0.944 0.113 +/-0.944 0.241 pCi/g Iadium-226 0.970 +/-0.111 0.0223 +/-0.111 0.0463 pCi/g Silver-108m U -0.0099 +/-0.014 0.0115 +/-0.014 0.0237 pCi/g Thallium-208 0.320 +/-0.0361 0.0116 +/-0.0361 0.0242 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 70
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-004F Project: YANK01204 Sample ID: 176896015 Client ID: YANK00I Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 71
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-016F Proiect: YANK0 1204 Sample ID: 176896016 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 15-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 23.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.619 +/-0.150 0.0562 +/-0.150 0.122 pCi/g MJH1 12/05/06 1136 592140 Americium-241 U -0.18 +/-0.102 0.0788 +/-0.102 0.162 pCi/g Bismuth-212 0.507 +/-0.272 0.112 +/-0.272 0.242 pCi/g Bismuth-214 0.592 +/-0.0854 0.0332 +/-0.0854 0.0703 pCi/g Cesium-134 UI 0.00 +/-0.0343 0.0216 +/-0.0343 0.0459 pCi/g Cesium-137 0.389 +/-0.0492 0.017 +/-0.0492 0.0363 pCi/g Cobalt-60 U 0.0115 +/-0.0427 0.0177 +/-0.0427 0.0389 pCi/g Europium-152 U 0.0171 +/-0.055 0.0484 +/-0.055 0.101 pCi/g Europium-154 U -0.0361 +/-0.0613 0.0473 +/-0.0613 0.104 pCi/g Europium-155 U 0.00617 +/-0.0595 0.0551 +/-0.0595 0.114 pCi/g Lead-212 0.689 +/-0.0563 0.0277 +/-0.0563 0.0574 pCi/g Lead-214 0.637 +/-0.0859 0.0328 +/-0.0859 0.0688 pCi/g Manganese-54 U 0.00642 +/-0.0225 0.0174 +/-0.0225 0.0373 pCi/g Niobium-94 U 0.022 +/-0.0272 0.0155 +/-0.0272 0.033 pCi/g Potassium-40 8.98 +/-0.762 0.119 +/-0.762 0.274 pCi/g Radium-226 0.592 +/-0.0854 0.0332 +/-0.0854 0.0703 pCi/g Silver-108m U 0.00618 +/-0.0203 0.0177 +/-0.0203 0.037 pCi/g Thallium-208 0.183 +/-0.0404 0.0166 +/-0.0404 0.0353 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 72
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-016F Project: YANK01204 Sample ID: 176896016 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 73
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-017-1 Project: YANKO01204 Sample ID: 176896017 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 10.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.24 +/-0.228 0.0723 +/-0.228 0.155 pCi/g MJH1 12/05/06 1145 592140 Americium-241 U -0.154 +/-0.101 0.0713 +/-0.101 0.146 pCi/g Bismuth-212 0.586 +/-0.286 0.168 +/-0.286 0.357 pCi/g Bismuth-214 0.641 +/-0.110 0.0459 +/-0.110 0.0963 pCi/g Cesium-134 U 0.0362 +/-0.0338 0.0276 +/-0.0338 0.0583 pCi/g Cesium-137 UI 0.00 +/-0.0479 0.0213 +/-0.0479 0.0451 pCi/g Cobalt-60 U 0.0128 +/-0.0296 0.023 +/-0.0296 0.0501 pCi/g Europium-152 U -0.0819 +/-0.068 0.0552 +/-0.068 0.115 pCi/g Europium-154 U 0.0535 +/-0.0775 0.0698 +/-0.0775 0.151 pCi/g Europium-155 U 0.0508 +/-0.0696 0.0612 +/-0.0696 0.126 pCi/g Lead-212 1.21 +/-0.120 0.0318 +/-0.120 0.066 pCi/g Lead-214 0.761 +/-0.115 0.0413 +/-0.115 0.0863 pCi/g Manganese-54 U -0.00326 +/-0.0251 0.0205 +/-0.0251 0.0439 pCi/g Niobium-94 U 0.0261 +/-0.0226 0.0204 +/-0.0226 0.0431 pCi/g Potassium-40 17.9 +/-1.54 0.187 +/-1.54 0.416 pCi/g Radium-226 0.641 +/-0.110 0.0459 +/-0.110 0.0963 pCi/g Silver-108m U -0.0125 +/-0.0207 0.0171 +/-0.0207 0.0361 pCi/g Thallium-208 0.340 +/-0.0533 0.0202 +/-0.0533 0.0427 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 74
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-017-I Project: YANK01204 Sample ID: 176896017 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 75
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-018-I Project: YANK01204 Sample ID: 176896018 Client ID: YAN K001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 9.55% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.820 +/-0.207 0.0916 +/-0.207 0.198 pCi/g MJHI 12/05/06 1146 592140 Americium-241 U -0.0168 +/-0.0415 0.0375 +/-0.0415 0.0775 pCi/g Bismuth-212 0.902 +/-0.393 0.186 +/-0.393 0.400 pCi/g Bismuth-214 0.782 +/-0.136 0.0459 +/-0.136 0.0978 pCi/g Cesium-134 U 0.0645 +/-0.0428 0.0327 +/-0.0428 0.0696 pCi/g Cesium-I 37 0.0804 +/-0.0483 0.026 +/-0.0483 0.0556 pCi/g Cobalt-60 U 0.012 +/-0.0308 0.0185 +/-0.0308 0.0424 pCi/g Europium-152 U -0.0184 +/-0.0724 0.0618 +/-0.0724 0.130 pCi/g Europium-154 U 0.0808 +/-0.0972 0.0897 +/-0.0972 0.194 pCi/g Europium-155 U 0.0487 +/-0.102 0.0556 +/-0.102 0.116 pCi/g Lead-212 0.863 +/-0.0764 0.033 +/-0.0764 0.0691 pCi/g Lead-214 0.847 +/-0.128 0.0457 +/-0.128 0.0963 pCi/g Manganese-54 U 0.0128 +/-0.0332 0.0291 +/-0.0332 0.062 pCi/g Niobium-94 U 0.0143 +/-0.0283 0.0255 +/-0.0283 0.0541 pCi/g Potassium-40 13.6 +/-1.13 0.237 +/-1.13 0.528 pCi/g Radium-226 0.782 +/-0.136 0.0459 +/-0.136 0.0978 pCi/g Silver-108m U -0.0114 +/-0.0246 0.0217 +/-0.0246 0.046 pCi/g Thallium-208 0.254 +/-0.0665 0.0254 +/-0.0665 0.0541 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 76
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-018-I Proiect: YANKO 1204 Sample ID: 176896018 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 77
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-019-I Project: YANK01204 Sample ID: 176896019 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 10.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.05 +/-0.230 0.0936 +/-0.230 0.202 pCi/g MJH1 12/05/06 1146 592140 Americium-241 U -0.0195 +/-0.0364 0.0313 +/-0.0364 0.0647 pCi/g Bismuth-212 0.851 +/-0.420 0.183 +/-0.420 0.395 pCi/g Bismuth-214 1.04 +/-0.129 0.0423 +/-0.129 0.0907 pCi/g Cesium-134 U 0.0208 +/-0.0354 0.0312 +/-0.0354 0.0666 pCi/g Cesium-137 U 0.0495 +/-0.0421 0.0232 +/-0.0421 0.0499 pCi/g Cobalt-60 U 0.043 +/-0.043 0.0233 +/-0.043 0.0523 pCi/g Europium-152 U -0.0527 +/-0.0694 0.0556 +/-0.0694 0.118 pCi/g Europium-154 U -0.0241 +/-0.101 0.0827 +/-0.101 0.181 pCi/g Europium-155 U 0.0283 +/-0.0573 0.0546 +/-0.0573 0.113 pCi/g Lead-212 1.04 +/-0.0756 0.0321 +/-0.0756 0.067 pCi/g Lead-214 1.34 +/-0.113 0.0374 +/-0.113 0.0794 pCi/g Manganese-54 U -0.0064 +/-0.0294 0.024 +/-0.0294 0.0518 pCi/g Niobium-94 U -0.0141 +/-0.0267 0.0216 +/-0.0267 0.0465 pCi/g Potassium-40 17.9 +/-1.31 0.125 +/-1.31 0.308 pCi/g Radium-226 1.04 +/-0.129 0.0423 +/-0.129 0.0907 pCi/g Silver-108m U 0.00609 +/-0.0214 0.0195 +/-0.0214 0.0415 pCi/g Thallium-208 0.343 +/-0.0627 0.0205 +/-0.0627 0.0442 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 78
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-019-I Project: YANK01204 Sample ID: 176896019 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 79
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-020-I Project: YANK01204 Sample ID: 176896020 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 9.07% Parameter ()ualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.435 +/-0.128 0.0372 +/-0.128 0.0823 pCi/g MJH1 12/05/06 1147 592140 Americium-241 U -0.016 +/-0,039 0.0346 +/-0.039 0.0722 pCi/g Bismuth-212 0.272 +/-0.192 0.0894 +/-0.192 0.194 pCi/g Bismuth-214 0.327 +/-0.068 0.0228 +/-0.068 0.0489 pCi/g Cesium-I 34 U 0.0255 +/-0.0278 0.0156 +/-0.0278 0.0334 pCi/g Cesium-137 0.0356 +/-0.0192 0.0124 +/-0.0192 0.0267 pCi/g Cobalt-60 U 0.00471 +/-0.014 0.0126 +/-0.014 0.0282 pCi/g Europium- 152 U 0.0268 +/-0.0343 0.0318 +/-0.0343 0.0673 pCi/g Europium- 154 U -0.0589 +/-0.0391 0.0257 +/-0.0391 0.0594 pCi/g Europium-I155 U 0.0269 +/-0.0493 0.0351 +/-0.0493 0.0731 pCi/g Lead-212 0.431 +/-0.0531 0.0188 +/-0.0531 0.0393 pCi/g Lead-214 0.354 +/-0.0691 0.0212 +/-0.0691 0.045 pCi/g Manganese-54 U 0.00258 +/-0.0128 0.0113 +/-0.0128 0.0247 pCi/g Niobium-94 U-0.000294 +/-0.0122 0.0107 +/-0.0122 0.023 pCi/g Potassium-40 6.67 +/-0.722 0.0877 +/-0.722 0.205 pCi/g Radium-226 0.327 +/-0.068 0.0228 +/-0.068 0.0489 pCi/g Silver-108m U -0.00196 +/-0.0119 0.010 +/-0.0119 0.0215 pCi/g Thallium-208 0.140 +/-0.0368 0.0108 +/-0.0368 0.0234 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 80
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-020-I Project: YANK01204 Sample ID: 176896020 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 81
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-021-1 Project: YANK01204 Sample ID: 176896021 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 16.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.654 +/-0.145 0.0568 +/-0.145 0.120 pCi/g MJHI 12/04/06 0657 592142 Americium-241 U 0.0382 +/-0.0896 0.053 +/-0.0896 0.109 pCi/g Bismuth-212 0.394 +/-0.211 0.106 +/-0.211 0.224 pCi/g Bismuth-214 0.532 +/-0.0827 0.0298 +/-0.0827 0.0624 pCi/g Cesium-134 UI 0.00 +/-0.0308 0.0182 +/-0.0308 0.0383 pCi/g Cesium-137 0.519 +/-0.0627 0.0156 +/-0.0627 0.0327 pCi/g Cobalt-60 U 0.0253 +/-0.0187 0.0178 +/-0.0187 0.0382 pCi/g Europium-152 U 0.00452 +/-0.0502 0.039 +/-0.0502 0.0811 pCi/g Europium-154 U 0.0204 +/-0.0518 0.0458 +/-0.0518 0.0985 pCi/g Europium-155 U 0.0389 +/-0.0432 0.0425 +/-0.0432 0.0872 pCi/g Lead-212 0.680 +/-0.0717 0.0235 +/-0.0717 0.0485 pCi/g Lead-214 0.647 +/-0.0859 0.0291 +/-0.0859 0.0605 pCi/g Manganese-54 U -0.0215 +/-0.0186 0.0142 +/-0.0186 0.0301 pCi/g Niobium-94 U 0.00638 +/-0.0171 0.0131 +/-0.0171 0.0276 pCi/g Potassium-40 9.96 +/-0.889 0.134 +/-0.889 0.294 pCi/g Radium-226 0.532 +/-0.0827 0.0298 +/-0.0827 0.0624 pCi/g Silver-108m U 0.00145 +/-0.0171 0.015 +/-0.0171 0.0313 pCi/g Thallium-208 0.215 +/-0.042 0.0146 +/-0.042 0.0308 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 82
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-021-I Proiect: YANK01204 Sample ID: 176896021 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 83
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-022-I Project: YANK01204 Sample ID: 176896022 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 10.9% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.602 +/-0.115 0.0483 +/-0.115 0.103 pCi/g MJHI 12/04/060658 592142 Americium-241 U -0.075 +/-0.111 0.0647 +/-0.111 0.133 pCi/g Bismuth-212 0.504 +/-0.155 0.0928 +/-0.155 0.198 pCi/g Bismuth-214 0.528 +/-0.0657 0.0249 +/-0.0657 0.0526 pCi/g Cesium-134 U 0.0287 +/-0.0233 0.018 +/-0.0233 0.0378 pCi/g Cesium-I 37 0.0653 +/-0.024 0.0156 +/-0.024 0.0328 pCi/g Cobalt-60 U 0.0179 +/-0.0176 0.0162 +/-0.0176 0.0349 pCi/g Europium-152 U -0.0225 +/-0.0437 0.037 +/-0.0437 0.0772 pCi/g Europium-154 U 0.0195 +/-0.0512 0.0444 +/-0.0512 0.0956 pCi/g Europium-155 U 0.0625 +/-0.0513 0.0451 +/-0.0513 0.0925 pCi/g Lead-212 0.603 +/-0.0484 0.0231 +/-0.0484 0.0477 pCi/g Lead-214 0.550 +/-0.0696 0.0261 +/-0.0696 0.0544 pCi/g Manganese-54 U 0.00167 +/-0.017 0.0129 +/-0.017 0.0275 pCi/g Niobium-94 U 0.00451 +/-0.0141 0.0127 +/-0.0141 0.0268 pCi/g Potassium-40 9.75 +/-0.656 0.127 +/-0.656 0.280 pCi/g Radium-226 0.528 +/-0.0657 0.0249 +/-0.0657 0.0526 pCi/g Silver-108m U -0.00371 +/-0.0147 0.0124 +/-0.0147 0.026 pCi/g Thallium-208 0.221 +/-0.038 0.0126 +/-0.038 0.0267 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 84
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-022-I Project: YANK01204 Sample ID: 176896022 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 85
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-023-1 Proiect: YANK01204 Sample ID: 176896023 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 11.8% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1' Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.581 +/-0.137 0.0617 +/-0.137 0.131 pCi/g MJH1 12/04/06 0658 592142 Americium-241 U 0.0151 +/-0.0268 0.0248 +/-0.0268 0.0509 pCi/g Bismuth-212 U 0.278 +/-0.239 0.147 +/-0.239 0.309 pCi/g Bismuth-214 0.446 +/-0.0932 0.0316 +/-0.0932 0.0664 pCi/g Cesium-134 U 0.0422 +/-0.048 0.0209 +/-0.048 0.0441 pCi/g Cesium-137 0.055 +/-0.0298 0.0202 +/-0.0298 0.0423 pCi/g Cobalt-60 U -0.0147 +/-0.0226 0.0179 +/-0.0226 0.0386 pCi/g Europium-I152 U -0.00132 +/-0.051 0.0439 +/-0.051 0.0914 pCi/g Europium-154 U -0.0173 +/-0.063 0.052 +/-0.063 0.112 pCi/g Europium-155 U 0.0146 +/-0.0462 0.0406 +/-0.0462 0.0835 pCi/g Lead-212 0.533 +/-0.0569 0.0314 +/-0.0569 0.0644 pCi/g Lead-214 0.513 +/-0.0809 0.0295 +/-0.0809 0.0616 pCi/g Manganese-54 U -0.00392 +/-0.0219 0.0182 +/-0.0219 0.0384 pCi/g Niobium-94 U9.330E-05 +/-0.0191 0.0164 +/-0.0191 0.0345 pCi/g Potassium-40 9.21 +/-0.696 0.173 +/-0.696 0.374 pCi/g Radium-226 0.446 +/-0.0932 0.0316 +/-0.0932 0.0664 pCi/g Silver-108m U 0.00276 +/-0.0168 0.0153 +/-0.0168 0.032 pCi/g Thallium-208 0.193 +/-0.0439 0.017 +/-0.0439 0.0357 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 86
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-023-I Project: YANK01204 Sample ID: 176896023 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 87
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-024-1 Project: YANK01204 Sample ID: 176896024 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 21-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 44.9% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch IN Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.985 +/-0.159 0.0657 +/-0.159 0.141 pCi/g MJH 1 12/04/06 0659 592142 Americium-241 U 0.011 +/-0.0288 0.0241 +/-0.0288 0.0495 pCi/g Bismuth-212 0.629 +/-0.357 0.145 +/-0.357 0.309 pCi/g Bismuth-214 0.975 +/-0.109 0.0328 +/-0.109 0.0695 pCi/g Cesium-134 U1 0.00 +/-0.0598 0.0245 +/-0.0598 0.0517 pCi/g Cesium-137 0.630 +/-0.0618 0.020 +/-0.0618 0.0424 pCi/g Cobalt-60 U 0.00435 +/-0.0255 0.0215 +/-0.0255 0.0468 pCi/g Europium-152 U -0.00564 +/-0.0581 0.0473 +/-0.0581 0.0987 pCi/g Europium-154 U -0.00448 +/-0.0854 0.0608 +/-0.0854 0.132 pCi/g Europium-155 U 0.00567 +/-0.0451 0.0401 +/-0.0451 0.0826 pCi/g Lead-212 1.03 +/-0.0634 0.0264 +/-0.0634 0.0548 pCi/g Lead-214 1.09 +/-0.106 0.034 +/-0.106 0.0711 pCi/g Manganese-54 U 0.0017 +/-0.0236 0.0194 +/-0.0236 0.0413 pCi/g Niobium-94 U 0.0207 +/-0.0209 0.0186 +/-0.0209 0.0393 pCi/g Potassium-40 11.3 +/-0.858 0.204 +/-0.858 0.446 pCi/g Radium-226 0.975 +/-0.109 0.0328 +/-0.109 0.0695 pCi/g Silver-108m U -0.00821 +/-0.0196 0.0165 +/-0.0196 0.0346 pCi/g Thallium-208 0.329 +/-0.0512 0.0172 +/-0.0512 0.0366 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 11/30/06 1316 592096 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 88
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 7, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-024-1 Project: YANK01204 Sample ID: 176896024 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 89
QUALITY CONTROL DATA I, 90
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Revort Date: December 7, 2006 Client : Connecticut Yankee Atomic Power Page 1 of 12 362 Injun Hollow Rd East Hampton, Connecticut
Contact:
Mr. Jack McCarthy Workorder: 176896 Parmname NOM Sample Qual QC Units RPD% REC % Range Anist Date Time Rad Alpha Spec Batch 592107 QC1201238057 176896007 DUP Americium-241 U 0.105 U 0.0986 pCi/g 6 (0% - 100%) AXAI 12/03/06 09:01 Uncert: +/-0.153 +/-0.182 TPU: +/-0.154 +/-0.183 Curium-242 U 0.075 U -0.00937 pCi/g 257 (0% - 100%) Uncert: +/-0.129 +/-0.0787 TPU: +/-0.130 +/-0.0788 Curium-243/244 U 0.0863 U 0.00564 pCi/g 175 (0%- 100%) Uncert: +/-0.154 +/-0.153 TPU: +/-0.154 +/-0.153 QC1201238059 LCS Americium-241 13.5 12.7 pCi/g 94 (75%-125%) Uncert: +/-1.32 TPU: +/-2.06 Curium-242 U 0.0185 pCi/g Uncert: +/-0.0736 TPU: +/-0.0736 Curium-243/244 11.7 11.1 pCi/g 95 (75%-125%) Uncert: +/-1.23 TPU: +/-1.84 QC1201238056 MB Americium-241 U -0.0952 pCi/g Uncert: +/-0.0629 TPU: +/-0.064 Curium-242 U -0.0674 pCi/g Uncert: +/-0.0467 TPU: +/-0.0475 Curium-243/244 U -0.173 pCi/g Uncert: +/-0.131 TPU: +/-0.133 QC1201238058 176896007 MS Americium-241 13.7 U 0.105 12.1 pCi/g 88 (75%-125%) Uncert: +/-0.153 +/-1.19 TPU: +/-0.154 +/-1.87 Curium-242 U 0.075 U 0.0267 pCi/g Uncert: +/-0.129 +/-0.099 TPU: +/-0.130 +/-0.0991 Curium-243/244 11.9 U 0.0863 11.6 pCi/g 98 (75%-125%) Uncert: +/-0.154 +/-1.17 TPU: +/-0.154 +/-1.80 Batch 592108 QC1201238061 176896007 DUP Plutonium-238 U 0.0367 U 0.0113 pCi/g 106 (0% - 100%) AXAI 12/03/06 09:01 91
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com OC Summary Workorder: 176896 Page 2 of 12 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Rad Alpha Spec Batch 592108 Uncert: +/-0.103 +/-0.107 TPU: +/-0.103 +/-0.107 Plutonium-239/240 U 0.0268 U -0.0847 pCi/g 385 (0%- 100%) Uncert: +/-0.071 +/-0.0525 TPU: +/-0.0711 +/-0.0535 QC1201238063 LCS Plutonium-238 U -0.034 pCi/g (75%-125%) Uncert: +/-0.123 TPU: +/-0.123 Plutonium-239/240 12.0 10.9 pCi/g 91 (75%-125%) Uncert: +/-1.16 TPU: +/- 1.75 QC1201238060 MB Plutonium-238 U 0.0771 pCi/g Uncert: +/-0.165 TPU: +/-0.165 Plutonium-239/240 U 0.0681 pCi/g Uncert: +/-0.228 TPU: +/-0.228 QC1201238062 176896007 MS Plutonium-238 U 0.0367 U -0.0903 pCi/g (75%-125%) Uncert: +/-0.103 +/-0.175 TPU: +/-0.103 +/-0.176 Plutonium-239/240 12.0 U 0.0268 11.2 pCi/g 93 (75%-125%) Uncert: +/-0.071 +/-1.17 TPU: +/-0.0711 +/-1.78 Batch 592109 QC1201238065 176896007 DUP Plutonium-241 U 6.51 U 4.12 pCi/g 0 (0% - 100%) AIXA1 12/05/06 20:09 Uncert: +/-7.02 +/-7.74 TPU: +/-7.05 +/-7.75 QC1201238067 LCS Plutonium-241 139 136 pCi/g 98 (75%-125%) 12/05/06 20:42 Uncert: +/-11.8 TPU: +/-17.6 QC1201238064 MB Plutonium-241 U 3.78 pCi/g 12/05/06 19:53 Uncert: +/-6.72 TPU: +/-6.73 QC1201238066 176896007 MS Plutonium-241 141 U 6.51 139 pCi/g 99 (75%-125%) 12/05/06 20:26 Uncert: +/-7.02 +/-12.2 TPU: +/-7.05 +/-18A1 Rad Gamma Spec Batch 592140 QC1201238139 176896001 DUP Actinium-228 0.690 0.579 pCi/g 18 (0% - 100%) MJH1 12/05/06 11:48 Uncert: +/-0.169 +/-0.0989
+/-0.0989 92
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 3 of 12 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 592140 TPU: +/-0.169 Americium-241 U -0.0319 U 0.022 pCi/g 1090 (0% - 100%) Uncert: +/-0.0718 +/-0.0771 TPU: +/-0.0718 +/-0.0771 Bismuth-212 0.737 0.419 pCi/g 55 (0%- 100%) Uncert: +/-0.318 +/-0.158 TPU: +/-0.318 +/-0.158 Bismuth-214 0.474 0.391 pCi/g 19 (0%- 100%) Uncert: +/-0.0988 +/-0.0636 TPU: +/-0.0988 +/-0.0636 Cesium- 134 UI 0.00 U 0.028 pCi/g 73 (0%- 100%) Uncert: +/-0.0205 +/-0.0246 TPU: +/-0.0205 +/-0.0246 Cesium- 137 0.0504 0.0316 pCi/g 46 (0%- 100%) Uncert: +/-0.044 +/-0.0185 TPU: +/-0.044 +/-0.0185 Cobalt-60 U 0.0122 UI 0.00 pCi/g 104 (0%- 100%) Uncert: +/-0.0226 +/-0.0324 TPU: +/-0.0226 +/-0.0324 Europium- 152 U -0.0356 U -0.0176 pCi/g 68 (0%- 100%) Uncert: +/-0.0562 +/-0.0329 TPU: +/-0.0562 +/-0.0329 Europium- 154 U 0.0201 U -0.0127 pCi/g 883 (0%- 100%) Uncert: +/-0.0657 +/-0.040 TPU: +/-0.0657 +/-0.040 Europium- 155 U -0.014 U 0.00505 pCi/g 424 (0%- 100%) Uncert: +/-0.0582 +/-0.042 TPU: +/-0.0582 +/-0.042 Lead-212 0.637 0.508 pCi/g 23* (0% - 20%) Uncert: +/-0.0778 +/-0.0408 TPU: +/-0.0778 +/-0.0408 Lead-214 0.591 0.496 pCi/g 18 (0%-20%) Uncert: +/-0.0967 +/-0.0551 TPU: +/-0.0967 +/-0.0551 Manganese-54 U 0.00981 U 0.00646 pCi/g 41 (0%- 100%) Uncert: +/-0.0206 +/-0.0157 TPU: +/-0.0206 +/-0.0157 Niobium-94 U 0.0153 U 0.00803 pCi/g 62 (0%- 100%) Uncert: +/-0.0127 +/-0.0119 TPU: +/-0.0127 +/-0.0119 Potassium-40 8.72 9.01 pCi/g 3 (0% - 20%) Uncert: +/-0.980 +/-0.576 TPU: +/-0.980 +/-0.576 Radium-226 0.474 0.391 pCi/g 19 (0%- 100%) Uncert: +/-0.0988 +/-0.0636 TPU: +/-0.0988 +/-0.0636 Silver-108m U -0.00701 U -0.00673 pCi/g 4 (0%- 100%) Uncert: +/-0.0167 +/-0.0104 93
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 4 of 12 Parnmname NOM Sample _Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 592140 TPU: +/-0.0167 +/-0.0104 Thallium-208 0.169 0.195 pCi/g 14 (0% - 100%) Uncert: +/-0.0436 +/-0.0329 TPU: +/-0.0436 +/-0.0329 QC1201238140 LCS Actinium-228 U -0.349 pCi/g 12/04/06 17:43 Uncert: +/-0.544 TPU: +/-0.544 Americium-241 23.4 24.5 pCi/g 105 (75%-125%) Uncert: +/-1.33 TPU: +/-1.33 Bismuth-212 U -0.197 pCi/g Uncert: +/-0.892 TPU: +/-0.892 Bismuth-214 U 0.0481 pCi/g Uncert: +/-0.206 TPU: +/-0.206 Cesium-134 U 0.0433 pCi/g Uncert: +/-0.129 TPU: +/-0.129 Cesium- 137 9.52 9.77 pCi/g 103 (75%-125%) Uncert: +/-0.486 TPU: +/-0.486 Cobalt-60 14.0 14.0 pCi/g 100 (75%-125%) Uncert: +/-0.633 TPU: +/-0.633 Europium- 152 U -0.107 pCi/g Uncert: +/-0.309 TPU: +/-0.309 Europium-154 U -0.022 pCi/g Uncert: +/-0.237 TPU: +/-0.237 Europium- 155 U 0.200 pCi/g Uncert: +/-0.264 TPU: +/-0.264 Lead-212 U 0.133 pCi/g Uncert: +/-0.139 TPU: +/-0.139 Lead-214 U 0.0188 pCi/g Uncert: +/-0.206 TPU: +/-0.206 Manganese-54 U 0.0506 pCi/g Uncert: +/-0.122 TPU: +/-0.122 Niobium-94 U 0.116 pCi/g Uncert: +/-0.122 TPU: +/-0.122 Potassium-40 U 0.910 pCi/g 94
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 5 of 12 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 592140 Uncert: +/-0.909 TPU: +/-0.909 Radium-226 U 0.0481 pCi/g (75%-125%) Uncert: +/-0.206 TPU: +/-0.206 Silver-I 08m U 0.00823 pCi/g Uncert: +/-0.100 TPU: +/-0.100 Thallium-208 U 0.0835 pCi/g Uncert: +/-0.106 TPU: +/-0.106 QC1201238138 MB Actinium-228 U 0.00695 pCi/g 12/05/06 11:48 Uncert: +/-0.0741 TPU: +/-0.0741 Americium-241 U 0.00711 pCi/g Uncert: +/-0.0184 TPU: +/-0.0184 Bismuth-212 U 0.139 pCi/g Uncert: +/-0.149 TPU: +/-0.149 Bismuth-214 U 0.0265 pCi/g Uncert: +/-0.0542 TPU: +/-0.0542 Cesium-134 U 0.00575 pCi/g Uncert: +/-0.0187 TPU: +/-0.0187 Cesium- 137 U -0.0122 pCi/g Uncert: +/-0.0147 TPU: +/-0.0147 Cobalt-60 U 0.0207 pCi/g Uncert: +/-0.0135 TPU: +/-0.0135 Europium-152 U 0.00393 pCi/g Uncert: +/-0.0402 TPU: +/-0.0402 Europium- 154 U -0.033 pCi/g Uncert: +/-0.0549 TPU: +/-0.0549 Europium- 155 U 0.0303 pCi/g Uncert: +/-0.0311 TPU: +/-0.0311 Lead-212 U 0.0116 pCi/g Uncert: +/-0.0353 TPU: +/-0.0353 Lead-214 U 0.0313 pCi/g Uncert: +/-0.0318 TPU: +/-0.0318 95
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 6 of 12 Parmname NOM Sample Qual QC Units RPD % REC% Range Anist Date Time Rad Gamma Spec Batch 592140 Manganese-54 U 0.00269 pCi/g Uncert: +/-0.0189 TPU: +/-0.0189 Niobium-94 U -0.00121 pCi/g Uncert: +/-0.0166 TPU: +/-0.0166 Potassium-40 U 0.0654 pCi/g Uncert: +/-0.216 TPU: +/-0.216 Radium-226 U 0.0265 pCi/g Uncert: +/-0.0542 TPU: +/-0.0542 Silver- 108m U -0.0139 pCi/g Uncert: +/-0.0167 TPU: +/-0.0167 Thallium-208 U 0.0157 pCi/g Uncert: +/-0.0195 TPU: +/-0.0195 Batch 592142 QC1201238142 176890002 DUP Actinium-228 0.499 0.739 pCi/g 39 (0% - 100%) MJHI 12/04/06 07:00 Uncert: +/-0.133 +/-0.139 TPU: +/-0.133 +/-0.139 Americium-241 U 0.0286 U 0.00936 pCi/g 101 (0%- 100%) Uncert: +/-0.0593 +/-0.0223 TPU: +/-0.0593 +/-0.0223 Bismuth-212 0.400 0.367 pCi/g 8 (0%- 100%) Uncert: +/-0.177 +/-0.223 TPU: +/-0.177 +/-0.223 Bismuth-214 0.425 0.515 pCi/g 19 (0%- 100%) Uncert: +1-0.0754 +/-0.0798 TPU: +/-0.0754 +/-0.0798 Cesium- 134 U 0.0213 UT 0.00 pCi/g 91 (0%- 100%) Uncert: +/-0.0198 +/-0.0286 TPU: +/-0.0198 +/-0.0286 Cesium- 137 0.0722 0.0527 pCi/g 31 (0%- 100%) Uncert: +/-0.0297 +/-0.0252 TPU: +/-0.0297 +/-0.0252 Cobalt-60 U 0.0304 U 0.00911 pCi/g 108 (0%- 100%) Uncert: +/-0.0183 +/-0.0209 TPU: +/-0.0183 +/-0.0209 Europium- 152 U 0.00662 U -0.00857 pCi/g 1550 (0%- 100%) Uncert: +/-0.0743 +/-0.0387 TPU: +/-0.0743 +/-0.0387 Europium- 154 U 0.00889 U -0.0259 pCi/g 409 (0%- 100%) Uncert: +/-0.098 +/-0.0566 TPU: +/-0.098 +/-0.0566 Europium- 155 U 0.0169 U 0.0258 pCi/g 42 (0%- 100%) 96
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 7 of 12 Parmname NOM Sample Qual OC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 592142 Uncert: +/-0.0482 +/-0.0557 TPU: +/-0.0482 +/-0.0557 Lead-212 0.527 0.591 pCi/g II (0% - 20%) Uncert: +/-0.0622 +/-0.0454 TPU: +/-0.0622 +/-0.0454 Lead-214 0.556 0.640 pCi/g 14 (0% - 20%) Uncert: +/-0.0808 +/-0.0736 TPU: +/-0.0808 +/-0.0736 Manganese-54 U 0.00229 U 0.00242 pCi/g 5 (0% - 100%) Uncert: +/-0.0177 +/-0.0176 TPU: +/-0.0177 +/-0.0176 Niobium-94 U -0.0108 U -0.00432 pCi/g 86 (0%- 100%) Uncert: +/-0.0173 +/-0.0161 TPU: +/-0.0173 +/-0.0161 Potassium-40 11.4 10.1 pCi/g 12 (0%- 20%) Uncert: +/-0.994 +/-0.786 TPU: +/-0.994 +/-0.786 Radium-226 0.425 0.515 pCi/g 19 (0%- 100%) Uncert: +/-0.0754 +/-0.0798 TPU: +/-0.0754 +/-0.0798 Silver-108m U 0.0032 U 0.0106 pCi/g 107 (0%- 100%) Uncert: +/-0.0141 +/-0.0144 TPU: +/-0.0141 +/-0.0144 Thallium-208 0.144 0.188 pCi/g 26 (0%- 100%) Uncert: +/-0.0319 +/-0.0358 TPU: +/-0.0319 +/-0.0358 QC1201238143 LCS Actinium-228 U -0.0385 pCi/g 12/04/06 07:02 Uncert: +/-0.615 TPU: +/-0.615 Americium-241 23.4 24.4 pCi/g 104 (75%-125%) Uncert: +/-0.541 TPU: +/-0.541 Bismuth-212 U -0.109 pCi/g Uncert: +/-0.957 TPU: +/-0.957 Bismuth-214 U -0.146 pCi/g Uncert: +/-0.217 TPU: +/-0.217 Cesium-134 U -0.0676 pCi/g Uncert: +/-0.149 TPU: +/-0.149 Cesium-137 9.52 10.4 pCi/g 109 (75%-125%) Uncert: +/-0.503 TPU: +/-0.503 Cobalt-60 14.0 14.5 pCi/g 104 (75%-125%) Uncert: +/-0.677 TPU: +/-0.677 97
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 8 of 12 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 592142 Europium- 152 U -0.0484 pCi/g Uncert: +/-0.266 TPU: +/-0.266 Europium- 154 U 0.090 pCi/g Uncert: +/-0.250 TPU: +/-0.250 Europium- 155 U 0.144 pCi/g Uncert: +/-0.227 TPU: +/-0.227 Lead-212 U -0.0264 pCi/g Uncert: +/-0.146 TPU: +/-0.146 Lead-214 U 0.0333 pCi/g Uncert: +/-0.193 TPU: +/-0.193 Manganese-54 U 0.0139 pCi/g Uncert: +/-0.142 TPU: +/-0.142 Niobium-94 U -0.0307 pCi/g Uncert: +/-0.116 TPU: +/-0.116 Potassium-40 U 0.0841 pCi/g Uncert: +/-0.896 TPU: +/-0.896 Radium-226 U -0.146 pCi/g (75%-125%) Uncert: +/-0.217 TPU: +/-0.217 Silver- 108m U 0.019 pCi/g Uncert: +/-0.109 TPU: +/-0.109 Thallium-208 U -0.0275 pCi/g Uncert: +/-0.125 TPU: +/-0.125 QC1201238141 MB Actinium-228 U 0.016 pCi/g 12/04/06 07:00 Uncert: +/-0.0236 TPU: +/-0.0236 Americium-241 U 0.00128 pCi/g Uncert: +/-0.0195 TPU: +/-0.0195 Bismuth-212 U 0.0245 pCi/g Uncert: +/-0.102 TPU: +/-0.102 Bismuth-214 U 0.0232 pCi/g Uncert: +/-0.0167 TPU: +/-0.0167 Cesium- 134 U -0.00374 pCi/g Uncert: +/-0.00763 98
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 9 of 12 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 592142 TPU: +/-0.00763 Cesium- 137 U -0.00427 pCi/g Uncert: +/-0.00666 TPU: +/-0.00666 Cobalt-60 U 0.00632 pCi/g Uncert: +/-0.00816 TPU: +/-0.00816 Europium- 152 U -0.0022 pCi/g Uncert: +/-0.0183 TPU: +/-0.0183 Europium- 154 U -0.0122 pCi/g Uncert: +/-0.019 TPU: +/-0.019 Europium- 155 U 0.00667 pCi/g Uncert: +/-0.0183 TPU: +/-0.0183 Lead-212 U 0.0162 pCi/g Uncert: +/-0.0249 TPU: +/-0.0249 Lead-214 U 0.00126 pCi/g Uncert: +/-0.0145 TPU: +/-0.0145 Manganese-54 U 0.00222 pCi/g Uncert: +/-0.00775 TPU: +/-0.00775 Niobium-94 U 0.00384 pCi/g Uncert: +/-0.00734 TPU: +/-0.00734 Potassium-40 U 0.158 pCi/g Uncert: +/-0.098 TPU: +/-0.098 Radium-226 U 0.0232 pCi/g Uncert: +/-0.0167 TPU: +/-0.0167 Silver- 108m U 0.00867 pCi/g Uncert: +/-0.0121 TPU: +/-0.0121 Thallium-208 U1 0.00 pCi/g Uncert: +/-0.00876 TPU: +/-0.00876 Rad Gas Flow Batch 592186 QC1201238232 176896007 DUP Strontium-90 0.766 0.315 pCi/g 84* (0% - 20%) KSD1 12/07/06 12:19 Uncert: +/-0.116 +/-0.0715 TPU: +/-0.118 +/-0.0719 QC1201238234 LCS Strontium-90 4390 4740 pCi/g 108 (75%-125%) 12/07/06 12:24 99
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com OC Summary Workorder: 176896 Page 10 of 12 Parmname NOM Sample Qual QC Units RPD % REC% Range AnIst Date Time Rad Gas Flow Batch 592186 Uncert: +/-5.18 TPU: +/-108 QC1201238231 MB Strontium-90 U 0.00521 pCi/g 12/07/06 12:18 Uncert: +/-0.017 TPU: +/-0.017 QC1201238233 176896007 MS Strontium-90 4390 0.766 4830 pCi/g 110 (75%-125%) 12/07/06 12:23 Uncert: +/-0.116 +/-5.59 TPU: +/-0.118 +/-120 Rad Liquid Scintillation Batch 592304 QC1201238527 176518004 DUP Iron-55 U -16.5 U -9.15 pCi/g 0 (0% - 100%) \IXPI 12/02/06 19:38 Uncert: +/-39.7 +/-36.9 TPU: +/-39.7 +/-36.9 QC1201238529 LCS Iron-55 797 803 pCi/g 101 (75%-125%) 12/02/06 20:11 Uncert: +/-60.4 TPU: +/-107 QC1201238526 MB Iron-55 U -10.8 pCi/g 12/02/06 19:22 Uncert: +/-29.0 TPU: +/-29.0 QC1201238528 176518004 MS Iron-55 806 U -16.5 789 pCi/g 98 (75%-125%) 12/02/06 19:54 Uncert: +/-39.7 +/-72.2 TPU: +/-39.7 +/-126 Batch 592310 QC1201238547 176896007 DUP Nickel-63 U -2.44 U 4.04 pCi/g 0 (0% - 100%) MXP1 12/04/06 21:37 Uncert: +/-12.1 +/-12.8 TPU: +/-12.1 +/-12.8 QC1201238549 LCS Nickel-63 513 503 pCi/g 98 (75%-125%) 12/04/06 22:10 Uncert: +/-27.8 TPU: +/-32.8 QC1201238546 MB Nickel-63 U -3.04 pCi/g 12/04/06 21:20 Uncert: +/-10.4 TPU: +/-10.4 QC1201238548 176896007 MS Nickel-63 513 U -2.44 595 pCi/g 116 (75%-125%) 12/04/06 21:53 Uncert: +/-12.1 +/-32.5 TPU: +/-12.1 +/-38.5 Batch 592312 QC1201238555 176896007 DUP Technetium-99 U 0.194 U 0.175 pCi/g 11 (0% - 100%) KXRI 12/06/06 19:28 100
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 11 of 12 Parmname NOM Sample Qua] QC Units RPD % REC % Range AnIst Date Time Rad Liquid Scintillation Batch 592312 Uncert: +/-0.161 +/-0.153 TPU: +/-0.162 +/-0.153 QC1201238557 LCS Technetium-99 12.9 12.7 pCi/g 99 (75%-125%) 12/06/06 20:32 Uncert: +/-0.375 TPU: +/-0.471 QC1201238554 MB Technetium-99 0.283 pCi/g 12/06/06 18:57 Uncert: +/-0.148 TPU: +/-0.148 QC1201238556 176896007 MS Technetium-99 12.9 U 0.194 12.6 pCi/g 98 (75%-125%) 12/06/06 20:00 Uncert: +/-0.161 +/-0.388 TPU: +/-0.162 +/-0.480 Batch 592313 QC1201238559 176896007 DUP Carbon- 14 U -0.0179 U -0.0249 pCi/g 0 (0% - 100%) 'kXD2 12/01/06 22:47 Uncert: +/-0.0898 +/-0.0889 TPU: +/-0.0898 +/-0.0889 QC1201238561 LCS Carbon- 14 6.69 7.10 pCi/g 106 (75%-125%) 12/02/06 00:53 Uncert: +/-0.201 TPU: +/-0.229 QC1201238558 MB Carbon- 14 U 0.000718 pCi/g 12/01/06 21:43 Uncert: +/-0.0906 TPU: +/-0.0906 QC1201238560 176896007 MS Carbon-14 6.86 U -0.0179 6.91 pCilg 101 (75%-125%) 12/01/06 23:50 Uncert: +/-0.0898 +/-0.202 TPU: +/-0.0898 +/-0.228 Batch 593064 QC1201240326 176890008 DUP Tritium U -1.0 U -1.35 pCi/g 0 (0% - 100%) DFA1 12/06/06 09:52 Uncert: +/-1.29 +/-1.29 TPU: +/-1.29 +/-1.29 QC1201240328 LCS Tritium 15.2 15.3 pCi/g 100 (75%-125%) 12/06/06 14:05 Uncert: +/-0.929 TPU: +/-0.965 QC1201240325 MB Tritium U -0.759 pCi/g 12/06/06 07:45 Uncert: +/-0.578 TPU: +/-0.578 QC1201240327 176890008 MS Tritium 19.8 U -1.0 16.3 pCi/g 83 (75%-125%) 12/06/06 11:59 Uncert: +/-1.29 +/-2.05 TPU: +/-1.29 +/-2.07 101
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 176896 Page 12 of 12 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
** Indicates analyte is a surrogate compound.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. 102
General Narrative 1
General Narrative for Connecticut Yankee Atomic Power Co. Work Order: 174936 SDG: MSR#06-1407 October 30, 2006 Laboratory Identification: General Engineering Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 Summary Sample receipt The samples arrived at General Engineering Laboratories, LLC, Charleston, South Carolina on October 26, 2006 for analysis. Shipping container temperatures were checked, documented, and within specifications. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any visible signs of tampering or breakage. Sample Identification The laboratory received the following samples: Laboratory Sample Identification Description 174936001 9522-01-005C 174936002 9522-01-007C 174936003 9520-0004-016F 174936004 9520-0004-017F 174936005 9504-0-01 OC 174936006 9504-0-013C 174936007 9520-0005-019F Items of Note There are no items to note. Case Narrative Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package. Analytical Request Four soil samples were analyzed for CHALL. Three soil samples were analyzed for FSSGAM. Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, Data Review Qualifier Definitions, and data from the following fractions: Radiochemistry. GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC. P.O. BOX 30712 Charleston, SC 29417
- 2040 Savage Road (29407)
Phone (843) 556-8171 - Fax243) 766-1178 www.gel.com
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature. Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member o1 THE GEL GROUP, NC. P.O. BOX 30712 Charleston, SC 29417 - 2040 Savage Road (29407) Phone (843) 556-8171 - Fax3343) 766-1178 www.gel.com
List of current GEL Certifications as of 30 October 2006 State Certification Alaska UST-062 Arizona AZ0668 Arkansas 1 88-0651 CLIA 42D0904046 California 01151CA Colorado GenEngLabs Connecticut PH-0169 Dept. of Navy NFESC 413 EPA F WG-15J Florida/NELAP E87156 Georgia E87156 (FL/NELAP) Hawaii N/A Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas I E-10332 Kentucky 90129 Louisiana 03046 Maryland 270 Massachusetts M-SC012 Michigan 9903 Nevada SC12 New Jersey SCO02 New Mexico FL NELAP E87156 New York 11501 North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-00485 South Carolina 10120001/10585001/10120002 Tennessee 02934 Texas TX213-2006A Texas NELAP TI04704235-06-TX U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah 8037697376 GEL Vermont VT87156 Virginia 00151 Washington C1641 4
Chain of Custody and Supporting Documentation 5
Health Physics Procedure GPP-GGGR- R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00637 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556"_11 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Media Sample Container Code Type Size-Analytical Lab (Name, City, State): Code &Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones (843-556-8171) Priority: [130 D. E] 14 D. [] 7 D. Other: Sample Designation Date Time U Comment, Preservation Lab Sample ID. 9522-01-005C io'if&.-
- TS G BP X .
Lb 16,r _ Is 4 .,. *L5 NOTES: PO #:002332 MSR#: oa-14o7 Z LTP QA [] Radwaste QA 0[ Non QA Samples Shipped Via: Internal ntainer [ Fed Ex. Temp.: X0 Deg. C E] ups F] Hand Custody Sealed? y)(ý: N F1
- 1) Relin ui By , Date/Time 2) Recyved By Date/Time Custoy.Seal Intact?
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- 3) R quishe By Date/Time 4) Received By Date/Time 7 1 61 2-. " ' 37. X" N E-1 Bill of Lading #
- 5) Relinquished By Date/Time 6) Received By Date/Time
Health Physics Procedure GPP-GGGR-R5]04-003-Attacliiiient B-CY-001 Major HelhPyisPoeur PGG-R 0-03Atcmn -Y0 IMao Chain of Custody Form No. 2006-00638 Connecticut Yankee Atomic Power Company 362 Injun 1lollow Road. East I lampton, CT 06424 860-267-2556 . -"
- Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:
Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 ( < 843 556 8171. Attn. Cheryl Jones ,) Priority:E[]30 D.E] 14 D. 0 7 D. [:3 D. Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample 1D Code Code Code 9520-0004-016F /o//' *L 7t..t TS G BP X 9520-0004-017F 1ol/ q/o, " TS G BP X _ NOTES: PO #: 002332 MSR #: 06- 14O7 SSWP# NA Z LTP QA El Radwaste QA El Non QA Samples Shipped Via: Internal .ntainer Fed Ex Temp.: Deg. ElI uis C
.Hand H Custody Sealed?
Y FNi7 1)Relrnq/
- ed ?ý Date/Time 2.eived By Date/Time Custody Seal El Other Intact?
- 3) 1inqui ed By Date/Time Yý N *
- 4) Received By V Date/Time 7Bil 20Vadig -
Bill of Lading #
Health Physics Procedure GPP-GGGR-R5 104-003 -Attachment B-CY-00 I Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00639 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Analyses Requested Lab Use Only Decommissioning Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Media Sample Container Code Type Size-Analytical Lab (Name, City, State): Code &Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones (843-556-8171) Priority: L] 30 D.E] 14 D. E 7 D. Other: ___-_ c' . Sample Designation Date Time U Comment, Preservation Lab Sample ID 9504-0-01OC 10/10/06 1035 TS G BP x 9504-0-013C 10/10/06 0820 TS G BP X NOTES: PO #: 002332 MSR #: &a LTP QA El Radwaste QA El Non QA Samples Shipped Via: Internal Container Z Fed Ex Temp.: I Deg. C E- UPS E]7 Hand Cq ody Sealed?
- 3) R quishd By Date/Time 4) ReceiedBy Date/Time Cusy Seal Intact?
- 3) Relquished By .'Date/Time 4) Received By Date/Time 71- 2-S"3 - N Bill of Lading #
- 5) Relinquished By Date/Time 6) Received By Date/Time
Health Physics Procedure GPP-G6.GR-R5104-003-At.tachment B-CY-00 I M jajor Health Phyics Prcdr P-G*-S1403- ahet1-Y0 ao Chain of Custody Form No. 2006-00640 Connecticut Yankee Atomic Power Company 362 Injun Hollow Road. East Hampton, CT 06424 860-267-2556 :. Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 294070 :< 843 556 8171. Attn. Cheryl Jones VD Priority: ] 30 D. Li 14 D. [D 7 D. [ 3 D. Dt Tie Mda Sample Container Size- C P
+Lcq .I Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9520-0005-019F 10/23/06 TS G BP X NOTES: PO #: 002332 MSR #:06-1-3.8-ý SSWP# NA E LTP QA El Radwaste QA Li Non QA Samples Shipped. Via: Internal Container "7 [A Fed Ex Temp.: Deg.
Di UPS C El Hand Cut*tdy Sealed?
- N F tustody Seal Li Other Intact?
)( NI..N i
I I1 Bill of Lading#
Connecticut Yankee Statement of Work for Analytical Lab Services .CY-IsC-Sow-001 Figure 1. Sample Check-in List. Date/Time Received: 91 L0LA, *, Oýj SDG#: o -4 Work Order Number: 14 0 tokk*uo :-- o 0 (.02ý Shipping Chntainer ID:9 0 9 I*6A Chain of Custody# o'(o'
- 1. Custody Seals oii shipping container intact? Yes No [ "
Yes 4 No
- 2. Custody Seals dated and signed? (]-
- 3. Chain-of-Custody record present? Yes No [ I
.4. Cooler t~ernerature_________________________________
- 5. Vermiculite/packing materials is: Wet [] Dry 6." Number of samples in shipping container:. __""_ _
- 7. Sample holding times exceeded? Yes I1 No fV
.8. Samples have:'
4 tape hazard labels
*custody seals . -appropriate sample labels
- 9. Samples are:
$ Cin good condition leaking broken -have air bubbles
- 10. Were any anomalies identified in sample receipt? Yes [ I N Description of anomalies.(include sample numbers):
Sample Custodian/Laboratoiy: Date: LOW . Telephoned to: O . B 10
Data Review Qualifier Definitions 11
Data Review Qualifier Definitions Qualifier Explanation
- A quality control analyte recovery is outside of specified acceptance criteria
- Analyte is a surrogate compound
< Result is less than value reported > Result is greater than value reported RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank B Metals-Either presence of analyte detected in the associated blank, or MDL/IDL < sample value < PQL BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample d 5-day BOD-The 2:1 depletion requirement was not met for this sample E Organics-Concentration of the target analyte exceeds the instrument calibration range E Metals-%difference of sample and SD is >10%. Sample concentration must meet flagging criteria H Analytical holding time was exceeded h Preparation or preservation holding time was exceeded J Value is estimated N Metals-The Matrix spike sample recovery is not within specified control limits N Organics-Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC) . Quantitation is based on nearest internal standard response factor N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the reporting limit U1 Gamma Spectroscopy-Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound Z Paint Filter Test-Particulates passed through the filter, however no free liquids were observed. GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC. P.O. BOX 30712 Charleston, SC 29417 , 2040 Savage Road (29407) Phone (843) 556-8171
- Fa2(,3) 766-1178 www.gel.com
RADIOLOGICAL ANALYSIS 13
Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK) Work Order 174936 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 583311 Prep Batch Number: 583211 Dry Soil Prep GL-RAD-A-021 Batch Number: 583196 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01 OC 174936006 9504-0-013C 1201216888 Method Blank (MB) 1201216890 174936001(9522-01-005C) Matrix Spike (MS) 1201216891 Laboratory Control Sample (LCS) 1201217370 174936001(9522-01-005C) Sample Duplicate (DUP) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. 14
Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Manual Integration No manual integrations were performed on data in this batch. Additional Comments The blank, 1201216888 (MB), did not meet the detection limit due to keeping the blank volume consistent with the other sample aliquots. All other samples met the detection limits. Qualifier information Manual qualifiers were not required. Method/Analysis Information 15
Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu-I 1-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 583312 Prep Batch Number: 583211 Dry Soil Prep GL-RAD-A-021 Batch Number: 583196 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01 OC 174936006 9504-0-013C 1201216892 Method Blank (MB) 1201216893 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216894 174936001(9522-01-005C) Matrix Spike (MS) 1201216895 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (OC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information 16
All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Manual Integration No manual integrations were performed on data in this batch. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu-I -RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 583313 Prep Batch Number: 583211 Dry Soil Prep GL-RAD-A-021 Batch Number: 583196 17
Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01 OC 174936006 9504-0-013C 1201216896 Method Blank (MB) 1201216897 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216898 174936001(9522-01-005C) Matrix Spike (MS) 1201216899 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis The batch was recounted due to a low LCS recovery. 18
Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Manual Integration No manual integrations were performed on data in this batch. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method: EML HASL 300, 4.5.2.3 Prep Method: Dry Soil Prep Analytical Batch Number: 583389 Prep Batch Number: 583196 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936003 9520-0004-016F 174936004 9520-0004-017F 174936005 9504-0-01OC 174936006 9504-0-013C 174936007 9520-0005-019F 1201217095 Method Blank (MB) 1201217096 174911001(9801-0-R 101-SFCC-0l -C I (0-2in)) Sample Duplicate (DUP) 1201217097 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 13. 19
Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174911001 (9801-0-R1OI-SFCC-01-Cl (0-2in)). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information 20
Qualifier Reason Analyte Sample UI Data rejected due to high counting uncertainty. Bismuth-212 1201217096 UI Data rejected due to high peak-width. Cesium- 134 1201217095 UI Data rejected due to interference. Europium- 155 174936002 Manganese-54 174936002 174936005 UI Data rejected due to low abundance. Cesium- 134 174936001 174936002 174936005 174936007 1201217096 Lead-214 1201217095 Method/Analysis Information Product: GFPC, Sr9O, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 583243 Prep Batch Number: 583211 Dry Soil Prep GL-RAD-A-021 Batch Number: 583196 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01OC 174936006 9504-0-013C 1201216717 Method Blank (MB) 1201216718 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216719 174936001(9522-01-005C) Matrix Spike (MS) 1201216720 Laboratory Control Sample (LCS) 21
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volumes in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Samples were recounted due to being originally counted on detectors with expired calibrations. Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments The blank result for 1201216717 (MB) is greater than the MDA but less than the detection limit. 22
Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 583233 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01 OC 174936006 9504-0-013C 1201216689 Method Blank (MB) 1201216690 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216691 174936001(9522-01-005C) Matrix Spike (MS) 1201216692 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Oualitv Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information 23
All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Samples 174936001 (9522-01-005C) and 174936002 (9522-01-007C) were recounted due to spectral interference. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments The result for sample 174936006 (9504-0-013C) is biased high due to spectral interference. Qualifier information Qualifier Reason Analyte Sample Sample result biased high due to spectral x Technetium-99 174936006 interference. Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe- 1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 583239 Prep Batch Number: 583211 Dry Soil Prep GL-RAD-A-021 Batch Number: 583196 24
Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01OC 174936006 9504-0-013C 1201216709 Method Blank (MB) 1201216710 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216711 174936001(9522-01-005C) Matrix Spike (MS) 1201216712 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Ouality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. 25
Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 583241 Prep Batch Number: 583211 Dry Soil Prep GL-RAD-A-021 Batch Number: 583196 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01OC 174936006 9504-0-013C 1201216713 Method Blank (MB) 1201216714 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216715 174936001(9522-01-005C) Matrix Spike (MS) 1201216716 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8. Calibration Information: Calibration Information 26
All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information 27
Product: LSC, Tritium Dist, Solid-HTD2,ALL FSS Analytical Method: EPA 906.0 Modified Analytical Batch Number: 583234 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-01OC 174936006 9504-0-013C 1201216693 Method Blank (MB) 1201216694 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216695 174936001(9522-01-005C) Matrix Spike (MS) 1201216696 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 13. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Oualitv Control (OC0 Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. 28
Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Sample 174936005 (9504-0-010C) was recounted due to high MDA. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: Liquid Scint C14, Solid All,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 583236 Sample ID Client ID 174936001 9522-01-005C 174936002 9522-01-007C 174936005 9504-0-O0OC 174936006 9504-0-013C 1201216701 Method Blank (MB) 1201216702 174936001(9522-01-005C) Sample Duplicate (DUP) 1201216703 174936001(9522-01-005C) Matrix Spike (MS) 1201216704 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. 29
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 174936001 (9522-01-005C). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. Qualifier information Manual qualifiers were not required. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Review Validation: 30
GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package. The following data validator verified the information presented in this case narrative: Reviewer/Date: 31
SAMPLE DATA
SUMMARY
32
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co. Client SDG: MSR#06-1407 GEL Work Order: 174936 The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
- Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier ND The analyte concentration is not detected above the detection limit. The above sample is reported on a dry weight basis except where prohibited by the analytical procedure. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones. Reviewed by 33
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-01-005C Project: YANK01204 Sample ID: 174936001 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 18-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 37.8% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 01.00136 +/-0.138 0.115 +/-0.138 0.327 pCi/g MXA 10/30/06 1058 583311 I Curium-242 U 0.0391 +/-0.110 0.0674 +/-0.110 0.237 pCi/g Curium-243/244 U --0.0385 +/-0.139 0.132 +/-0.140 0.361 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.104 +/-0.112 0.133 +/-0.113 0.352 pCi/g MXA 10/30/06 1058 583312 1 Plutonium-239/240 U -0.137 +/-0.0631 0.120 +/-0.0652 0.326 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -5.01 +/-7.31 6.36 +/-7.31 13.4 pCi/g MXA 11/02/06 0824 583313 I Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.942 +/-0.216 0.0684 +/-0.216 0.148 pCi/g MJHI 10/31/06 0910 583389 Americium-241 0.232 +/-0.147 0.0857 +/-0.147 0.177 pCi/g Bismuth-212 1.25 +/-0.452 0.152 +/-0.452 0.326 pCi/g Bismuth-214 1.01 +/-0.155 0.0431 +/-0.155 0.091 pCi/g Cesium-134 UI 0.00 +/-0.0505 0.0289 +/-0.0505 0.061 pCi/g Cesium-137 1.58 +/-0.100 0.0221 +/-0.100 0.0469 pCi/g Cobalt-60 U 0.0278 +/-0.0308 0.0272 +/-0.0308 0.0585 pCi/g Europium-152 U -0.0437 +/-0.0735 0.0588 +/-0.0735 0.123 pCi/g Europium-154 U 0.0164 +/-0.0885 0.0637 +/-0.0885 0.139 pCi/g Europium-155 U 0.0621 +/-0.0836 0.0693 +/-0.0836 0.143 pCi/g Lead-212 1.10 +/-0.0891 0.0406 +/-0.0891 0.0838 pCi/g Lead-214 0.962 +/-0.132 0.044 +/-0.132 0.0921 pCi/g Manganese-54 U -0.00466 +/-0.0271 0.0223 +/-0.0271 0.0474 pCi/g Niobium-94 U -0.0112 +/-0.0232 0.0188 +/-0.0232 0.0401 pCi/g Potassium-40 12.1 +/-1.00 0.191 +/-1.00 0.423 pCi/g Radium-226 1.01 +/-0.155 0.0431 +/-0.155 0.091 pCi/g Silver-108m U3.670E-05 +/-0.026 0.0213 +/-0.026 0.0446 pCi/g Thallium-208 0.306 +/-0.0549 0.0218 +/-0.0549 0.0461 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.0263 +/-0.0109 0.00825 +/-0.011 0.0172 pCi/g KSD1 11/01/06 2100 583243 34
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-01-005C Project: YANK01204 Sample ID: 174936001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 3.72 +/-5.94 4.71 +/-5.94 10.2 pCi/g DFA1 10/28/06 0650 583234 Liquid Scint C14, Solid AII, FSS Carbon-14 U 0.179 +/-0.112 0.0898 +/-0.112 0.184 pCi/g AXD2 10/27/06 2110 583236 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 14.2 +/-19.7 12.8 +/-19.7 27.0 pCi/g MXPI 11/01/06 1809 583239 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -0.799 +/-7.83 6.60 +/-7.83 13.8 pCi/g MXPI 11/01/06 1536 583241 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.320 +/-0.221 0.181 +/-0.221 0.367 pCi/g KXR1 10/31/06 2145 583233 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1442 583196 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-i 1-RC Modified 3 DOE EML HASL-300, Pu- I -RC Modified 4 DOE EML HASL-300, Pu-1 1-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-1, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 92 (15%-125%) Plutonium-242 Alphaspec Pu, Solid-ALL FSS 93 (15%-125%) 35
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-01-005C Project: YANK01204 Sample ID: 174936001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Plutonium-241 Liquid Scint Pu241, Solid-ALL FS 88 (25%-125%) Strontium-90 GFPC, Sr90, solid-ALL FSS 76 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 76 (25%-125%) Iron-55 Liquid Scint Fe55, Solid-ALL FS 83 (15%-125%) Nickel-63 Liquid Scint Ni63, Solid-ALL FS 88 (25%-125%) Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 88 (25%-125%) Technetium-99 Liquid Scint Tc99, Solid-ALL FS 50 (15%-125%) Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 50 (15%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 36
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-01-007C Proiect: YANKO 1204 Sample ID: 174936002 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 18-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 18% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0547 +/-0.122 0.0789 +/-0.123 0.237 pCi/g MXA 10/30/06 1058 583311 1 Curium-242 U 0.0395 +/-0.0893 0.048 +/-0.0894 0.180 pCi/g Curium-243/244 U -0.0258 +/-0.0943 0.0912 +/-0.0944 0.262 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0671 +/-0.0439 0.0837 +/-0.0444 0.252 pCi/g MXA 10/30/06 1058 583312 M Plutonium-239/240 U 0.0733 +/-0.145 0.0925 +/-0.145 0.269 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 4.10 +/-7.32 5.96 +/-7.33 12.5 pCi/g MXA 11/02/06 0840 583313 I Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 4.39 +/-0.204 0.0457 +/-0.204 0.0959 pCi/g MJH1 10/31/06 0925 583389 Americium-241 U -0.147 +/-0.0988 0.0841 +/-0.0988 0.170 pCi/g Bismuth-212 2.99 +/-0.322 0.128 +/-0.322 0.264 pCi/g Bismuth-214 1.41 +/-0.0972 0.0296 +/-0.0972 0.0611 pCi/g Cesium-134 UI 0.00 +/-0.0358 0.0276 +/-0.0358 0.0564 pCi/g Cesium-137 2.55 +/-0.0752 0.0187 +/-0.0752 0.0386 pCi/g Cobalt-60 U 0.0262 +/-0.0 175 0.0166 +/-0.0175 0.0351 pCi/g Europium-152 U -0.03 +/-0.059 0.0503 +/-0.059 0.103 pCi/g Europium-154 U 0.0248 +/-0.0468 0.0422 +/-0.0468 0.0893 pCi/g Europium-155 UI 0.00 +/-0.0881I 0.056 +/-0.0881 0.114 pCi/g Lead-212 4.38 +/-0.0865 0.0288 +/-0.0865 0.0585 pCi/g Lead-214 1.56 +/-0.100 0.0346 +/-0.100 0.0707 pCi/g Manganese-54 UI 0.00 +/-0.0272 0.0159 +/-0.0272 0.0331 pCi/g Niobium-94 U 0.0109 +/-0.01 82 0.0162 +/-0.0182 0.0335 pCi/g Potassium-40 2.51 +/-0.375 0.124 +/-0.375 0.266 pCi/g Radium-226 1.41 +/-0.0972 0.0296 +/-0.0972 0.0611 pCi/g Silver-108m U -0.00514 +/-0.0191 0.0173 +/-0.0191 0.0353 pCi/g Thallium-208 1.40 +/-0.0595 0.0174 +/-0.0595 0.0359 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.0327 +/-0.00864 0.00613 +/-0.00866 0.0128 pCi/g KSDI 11/01/06 2100 583243 Rad Liquid Scintillation Analysis 37
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-01-007C Project: YANK01204 Sample ID: 174936002 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A% Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 3.14 +/-7.71 6.23 +/-7.71 13.5 pCi/g DFA 1 10/28/06 0706 583234 Liquid Scint C14, Solid Al1, FSS Carbon-14 U 0.0254 +/-0.113 0.0944 +/-0.113 0.194 pCi/g AXD2 10/27/06 2158 583236 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 8.48 +/-18.0 11.8 +/-18.0 24.9 pCi/g MXPI 11/01/06 1825 583239 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 2.80 +/-7.02 5.78 +/-7.02 12.1 pCi/g MXP1 11/01/06 1558 583241 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 0.321 +/-0.163 0.126 +/-0.163 0.262 pCi/g KXRI 10/31/06 2246 583233 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1442 583196 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- 11-RC Modified 3 DOE EML HASL-300, Pu- 11-RC Modified 4 DOE EML HASL-300, Pu-I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 93 (15%-125%) Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (15%-125%) 38
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-01-007C Project: YANK0 1204 Sample ID: 174936002 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Plutonium-241 Liquid Scint Pu241, Solid-ALL FS 94 (25%-125%) Strontium-90 GFPC, Sr90, solid-ALL FSS 100 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 100 (25%-125%) Iron-55 Liquid Scint Fe55, Solid-ALL FS 86 (15%-125%) Nickel-63 Liquid Scint Ni63, Solid-ALL FS 90 (25%-125%) Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 90 (25%-125%) Technetium-99 Liquid Scint Tc99, Solid-ALL FS 113 (15%-125%) Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 113 (15%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 39
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9520-0004-016F Project: YANKO 1204 Sample ID: 174936003 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 19-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 15.4% Parameter )ualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.747 +/-0.134 0.0498 +/-0.134 0.105 pCi/g MJH1 10/31/06 0927 583389 Americium-241 U 0.0504 +/-0.105 0.0823 +/-0.105 0.169 pCi/g Bismuth-212 0.654 +/-0.242 0.105 +1-0.242 0.221 pCi/g Bismuth-214 0.970 +/-0.0713 0.026 +/-0.0713 0.0544 pCi/g Cesium- 134 U 0.0184 +/-0.0256 0.0177 +/-0.0256 0.0372 pCi/g Cesium-137 0.125 +/-0.0228 0.0129 +/-0.0228 0.0273 pCi/g Cobalt-60 U -0.00778 +/-0.0166 0.0131 +/-0.0166 0.0286 pCi/g Europium-152 U 0.00444 +/-0.044 0.0366 +/-0.044 0.076 pCi/g Europium-154 U -0.0216 +/-0.0534 0.0432 +/-0.0534 0.0927 pCi/g Europium- 155 U 0.0674 +/-0.0698 0.0415 +/-0.0698 0.0852 pCi/g Lead-212 0.838 +/-0.0517 0.0219 +/-0.0517 0.045 pCi/g Lead-214 1.12 +/-0.0838 0.0267 +/-0.0838 0.0553 pCi/g Manganese-54 U 0.0154 +/-0.0174 0.0152 +/-0.0174 0.032 pCi/g Niobium-94 U -0.00323 +1-0.015 0.0124 +/-0.015 0.026 pCi/g Potassium-40 12.1 +/-0.758 0.140 +/-0.758 0.303 pCi/g Radium-226 0.970 +/-0.0713 0.026 +/-0.0713 0.0544 pCi/g Silver-108m U -0.00181 +/-0.0144 0.0125 +/-0.0144 0.0261 pCi/g Thallium-208 0.238 +/-0.0369 0.013 +/-0.0369 0.0273 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1443 583196 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 40
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9520-0004-016F Project: YANKO 1204 Sample ID: 174936003 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 41
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9520-0004-017F Project: YANK01204 Sample ID: 174936004 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 19-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 18.7% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gamma Spec Analysis Gainma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.492 +/-0.157 0.0658 +/-0.157 0.140 pCi/g MJH1 10/31/06 0927 583389 Americium-241 U -0.0222 +/-0.0995 0.0726 +/-0.0995 0.149 pCi/g Bismuth-212 0.424 +/-0.289 0.143 +/-0.289 0.303 pCi/g Bismuth-214 0.778 +/-0.115 0.0326 +/-0.115 0.0688 pCi/g Cesium-134 U 0.00206 +/-0.0338 0.0207 +/-0.0338 0.0438 pCi/g Cesium-137 0.168 +/-0.0358 0.0171 +/-0.0358 0.0363 pCi/g Cobalt-60 U -0.0183 +/-0.024 0.0187 +/-0.024 0.0408 pCi/g Europium-152 U -0.00147 +/-0.061 0.0498 +/-0.061 0.103 pCi/g Europium-154 U -0.0213 +/-0.0645 0.0528 +/-0.0645 0.115 pCi/g Europium-155 U 0.00598 +/-0.0551 0.0479 +/-0.0551 0.0986 pCi/g Lead-212 0.616 +/-0.0645 0.0293 +/-0.0645 0.0603 pCi/g Lead-214 0.926 +/-0.0913 0.0374 +/-0.0913 0.0776 pCi/g Manganese-54 U 0.0215 +/-0.0229 0.0202 +/-0.0229 0.0426 pCi/g Niobium-94 U 0.00767 +/-0.0209 0.0179 +/-0.0209 0.0376 pCi/g Potassium-40 9.31 +/-0.909 0.166 +/-0.909 0.366 pCi/g Radium-226 0.778 +/-0.115 0.0326 +/-0.115 0.0688 pCi/g Silver-108m U -0.00183 +/-0.0211 0.0168 +/-0.0211 0.0352 pCi/g Thallium-208 0.222 +/-0.0438 0.0192 +/-0.0438 0.0402 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLI 10/26/06 1444 583196 The following Analytical Methods were performed Method Description I EML HASL 300,4.5.2.3 Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 42
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9520-0004-017F Proiect: YANK01204 Sample ID: 174936004 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1\
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 43
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9504-0-010C Project: YANK01204 Sample ID: 174936005 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 10-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 43.4% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0682 +/-0.103 0.0315 +/-0.103 0.158 pCi/g MXA 10/30/06 1058 583311 1 Curium-242 U -0.046 +/-0.0403 0.0769 +/-0.0408 0.258 pCi/g Curium-243/244 U -0.10 +/-0.0956 0.126 +/-0.0966 0.348 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0235 +/-0.087 0.0589 +/-0.087 0.197 pCi/g MXA 10/30/06 1058 583312 I Plutonium-239/240 U 0.0235 +/-0.0869 0.0588 +/-0.087 0.197 pCi/g Liquid Scint Pu24/, Solid-ALL FSS Plutonium-241 U 0.00 +/-6.56 5.51 +/-6.56 11.6 pCi/g MXA 11/02/06 0856 583313 1 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.635 +/-0.167 0.0577 +/-0.167 0.129 pCi/g MJH1 10/31/06 0928 583389 Americium-241 U 0.0432 +/-0.109 0.0836 +/-0.109 0.174 pCi/g Bismuth-212 0.532 +/-0.302 0.151 +/-0.302 0.329 pCi/g Bismuth-214 0.566 +/-0.113 0.0405 +/-0.113 0.0866 pCi/g Cesium- 134 U1 0.00 1/-0.0454 0.0264 +/-0.0454 0.0566 pCi/g Cesium-137 0.402 +/-0.057 0.0194 +/-0.057 0.042 pCi/g Cobalt-60 U 0.00339 1/-0.0231 0.0198 +/-0.0231 0.0448 pCi/g Europium-152 U 0.00635 -/-0.0624 0.0514 +/-0.0624 0.109 pCi/g Europium-154 U -0.00961 /-0.0889 0.0634 +/-0.0889 0.141 pCi/g Europium-155 U 0.0463 +/-0.0667 0.0601 +/-0.0667 0.125 pCi/g Lead-212 0.655 +/-0.0666 0.0278 +/-0.0666 0.0584 pCi/g Lead-214 0.611 +/-0.108 0.038 +/-0.108 0.0804 pCi/g Manganese-54 UI 0.00 +/-0.0682 0.0185 +/-0.0682 0.0405 pCi/g Niobium-94 U -0.0145 1/-0.0248 0.0196 +/-0.0248 0.0421 pCi/g Potassium-40 10.0 +/-1.01 0.181 +/-1.01 0.414 pCi/g Radium-226 0.566 +/-0.113 0.0405 +/-0.113 0.0866 pCi/g Silver-108m U -0.0205 /-0.0201 0.0159 +/-0.0201 0.0342 pCi/g Thallium-208 0.223 +/-0.0488 0.0181 +/-0.0488 0.0392 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.0342 +/-0.00877 0.00599 +/-0.0088 0.0126 pCi/g KSDI 11/01/06 2100 583243 Rad Liquid Scintillation Analysis 44
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9504-0-010C Project: YANKO01204 Sample ID: 174936005 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -0.632 +/-6.79 5.72 +/-6.79 11.9 pCi/g DFA1 11/01/06 0800 583234 Liquid Scint C14, Solid AII,FSS Carbon-14 U 0.0868 +/-0.115 0.0942 +/-0.115 0.193 pCi/g AXD2 10/27/06 2245 583236 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 2.22 +/-18.6 12.4 +/-18.6 26.3 pCi/g MXPI 11/01/06 1842 583239 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -4.66 +/-6.33 5.51 +/-6.33 11.5 pCi/g MXPI 11/01/06 1619 583241 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.475 +/-0.296 0.236 +/-0.296 0.486 pCi/g KXRI 10/31/06 0310 583233 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLI 10/26/06 1444 583196 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-1 I-RC Modified 4 DOE EML HASL-300, Pu- I1-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Ni-l, Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 85 (15%-125%) Plutonium-242 Alphaspec Pu, Solid-ALL FSS 95 (15%-125%) 45
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9504-0-01OC Project: YANK01204 Sample ID: 174936005 Client ID: YANKO01 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Plutonium-241 Liquid Scint Pu241, Solid-ALL FS 102 (25%-125%) Strontium-90 GFPC, Sr90, solid-ALL FSS 84 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 84 (25%-125%) Iron-55 Liquid Scint Fe55, Solid-ALL FS 82 (15%-125%) Nickel-63 Liquid Scint Ni63, Solid-ALL FS 93 (25%-125%) Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 93 (25%-125%) Technetium-99 Liquid Scint Tc99, Solid-ALL FS 78 (15%-125%) Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 78 (15%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 46
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9504-0-013C Proiect: YANK01204 Sample ID: 174936006 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 10-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 48.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0277 +/-0.0621 0.0513 +/-0.0621 0.180 pCi/g MXA 10/30/06 1058 583311 I Curium-242 U 0.0786 +/-0.108 0.0396 +/-0.108 0.164 pCi/g Curium-243/244 U -0.109 +/-0.0823 0.115 +/-0.0836 0.307 pCi/g AIphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00331 +/-0.105 0.0892 +/-0.105 0.253 pCi/g MXA 10/30/06 1058 583312 1 Plutonium-239/240 U 0.120 +/-0.149 0.082 +/-0.150 0.239 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -0.741 +/-6.61 5.58 +/-6.61 11.7 pCi/g MXA 11/02/06 0913 583313 I Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.506 +/-0.193 0.0706 +/-0.193 0.151 pCi/g MJHI 10/31/06 0929 583389 Americium-241 U -0.00807 +/-0.113 0.0819 +/-0.113 0.169 pCi/g Bismuth-212 0.519 +/-0.319 0.151 +/-0.319 0.322 pCi/g Bismuth-214 0.717 +/-0.116 0.0427 +/-0.116 0.0896 pCi/g Cesium-134 U 0.00314 +/-0.029 0.0232 +/-0.029 0.0493 pCi/g Cesium-137 0.684 +/-0.076 0.0208 +/-0.076 0.044 pCi/g Cobalt-60 U-0.000581 +/-0.0261 0.0212 +/-0.0261 0.0462 pCi/g Europium-152 U -0.0282 +/-0.0661 0.0534 +/-0.0661 0.111 pCi/g Europium-154 U 0.0313 +/-0.076 0.0646 +/-0.076 0.140 pCi/g Europium-155 U 0.0397 +/-0.0774 0.0508 +/-0.0774 0.105 pCi/g Lead-212 0.596 +/-0.0656 0.0366 +/-0.0656 0.0753 pCi/g Lead-214 0.676 +/-0.107 0.0383 +/-0.107 0.0799 pCi/g Manganese-54 U 0.0203 +/-0.0251 0.0222 +/-0.0251 0.047 pCi/g Niobium-94 U -0.00724 +/-0.0293 0.0199 +/-0.0293 0.042 pCi/g Potassium-40 5.95 +/-0.804 0.187 +/-0.804 0.412 pCi/g Radium-226 0.717 +/-0.116 0.0427 +/-0.116 0.0896 pCi/g Silver-108m U 0.00332 +/-0.0405 0.0182 +/-0.0405 0.0383 pCi/g Thallium-208 0.180 +/-0.0485 0.0208 +/-0.0485 0.0439 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.178 +/-0.0136 0.00626 +/-0.0145 0.0131 pCi/g KSD1 11/01/06 2100 583243 Rad Liquid Scintillation Analysis 47
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9504-0-013C Proiect: YAN K01204 Sample ID: 174936006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -1.43 +/-6.02 5.17 +/-6.02 11.2 pCi/g DFA1 10/28/06 0738 583234 Liquid Scint C14, Solid A//, FSS Carbon- 14 U 0.190 +/-0.121 0.0969 +/-0.121 0.199 pCi/g AXD2 10/27/06 2332 583236 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 4.58 +/-18.8 12.4 +/-18.8 26.2 pCi/g MXPI 11/01/06 1858 583239 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -3.51 +/-7.96 6.83 +/-7.96 14.3 pCi/g MXPI 11/01/06 1641 583241 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 X 1.20 +/-0.319 0.237 +/-0.320 0.489 pCi/g KXRI 10/31/06 0327 583233 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLl 10/26/06 1445 583196 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified 3 DOE EML HASL-300, Pu-I 1-RC Modified 4 DOE EML HASL-300, Pu-I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified II DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified 14 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery % Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 98 (15%-125%) 48
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9504-0-013C Project: YANK01204 Sample ID: 174936006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Plutonium-242 Alphaspec Pu, Solid-ALL FSS 99 (15%-125%) Plutonium-241 Liquid Scint Pu241, Solid-ALL FS 101 (25%-125%) Strontium-90 GFPC, Sr90, solid-ALL FSS 95 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 95 (25%-125%) Iron-55 Liquid Scint Fe55, Solid-ALL FS 88 (15%-125%) Nickel-63 Liquid Scint Ni63, Solid-ALL FS 86 (25%-125%) Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 86 (25%- 125%) Technetium-99 Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%) Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 49
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9520-0005-019F Proiect: YANK01204 Sample ID: 174936007 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 23-OCT-06 Receive Date: 26-OCT-06 Collector: Client Moisture: 8.59% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1l Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.956 +/-0.140 0.0577 +/-0.140 0.125 pCi/g MJHI 10/31/06 0930 583389 Americium-241 U -0.0344 +/-0.0932 0.0853 +/-0.0932 0.176 pCi/g Bismuth-212 0.469 +/-0.323 0.150 +/-0.323 0.320 pCi/g Bismuth-214 0.547 +/-0.0937 0.0337 +/-0.0937 0.0717 pCi/g Cesium- 134 UI 0.00 +/-0.0287 0.0245 +/-0.0287 0.0518 pCi/g Cesium-137 0.128 +/-0.041 0.0183 +/-0.041 0.0391 pCi/g Cobalt-60 U 0.0143 +/-0.0233 0.0193 +/-0.0233 0.0426 pCi/g Europium-152 U -0.0255 +/-0.0562 0.0466 +/-0.0562 0.0979 pCi/g Europium-154 U -0.0349 +/-0.0722 0.0565 +/-0.0722 0.123 pCi/g Europium-155 U 0.0307 +/-0.0645 0.0594 +/-0.0645 0.122 pCi/g Lead-212 0.754 +/-0.0632 0.029 +/-0.0632 0.0601 pCi/g Lead-214 0.623 +/-0.085 0.0372 +/-0.085 0.0779 pCi/g Manganese-54 U 0.0044 +/-0.0225 0.0196 +/-0.0225 0.0417 pCi/g Niobium-94 U 0.00264 +/-0.0188 0.0164 +/-0.0188 0.0351 pCi/g Potassium-40 11.2 +/-0.971 0.126 +/-0.971 0.290 pCi/g Radium-226 0.547 +/-0.0937 0.0337 +/-0.0937 0.0717 pCi/g Silver-108m U 0.0078 +/-0.0199 0.0172 +/-0.0199 0.0363 pCi/g Thallium-208 0.265 +/-0.044 0.0179 +/-0.044 0.038 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1445 583196 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported 50
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: November 2, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9520-0005-019F Project: YANK01204 Sample ID: 174936007 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 51
QUALITY CONTROL DATA 52
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Reoort Date: November 2, 2006 Client : Connecticut Yankee Atomic Power Page 1 of 9 362 Injun Hollow Rd East Hampton, Connecticut
Contact:
Mr. Jack McCarthy Workorder: 174936 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 583311 QC1201217370 174936001 DUP Americium-241 U 0.00136 U -0.0141 pCi/g 243 (0% - 100%) vdXA1 10/30/06 10:58 Uncert: +/-0.138 +/-0.0635 TPU: +/-0.138 +/-0.0635 Curium-242 U 0.0391 U -0.0144 pCi/g 433 (0%- 100%) Uncert: +/-0.110 +/-0.020 TPU: +/-0.110 +/-0.020 Curium-243/244 U -0.0385 U 0.0308 pCi/g 1800 (0%- 100%) Uncert: +/-0.139 +/-0.104 TPU: +/-0.140 +/-0.104 QC1201216891 LCS Americium-241 2.69 2.51 pCi/g 93 (75%-125%) 10/30/06 10:58 Uncert: +/-0.236 TPU: +/-0.371 Curium-242 U -0.00394 pCi/g Uncert: +/-0.0135 TPU: +/-0.0135 Curium-243/244 3.24 2.95 pCi/g 91 (75%-125%) Uncert: +/-0.256 TPU: +/-0.422 QC1201216888 MB Americium-241 U -0.0169 pCi/g 10/30/06 10:58 Uncert: +/-0.0283 TPU: +/-0.0284 Curium-242 U 0.0056 pCi/g Uncert: +/-0.030 TPU: +/-0.030 Curium-243/244 U 0.0146 pCi/g Uncert: +/-0.0557 TPU: +/-0.0557 QC1201216890 174936001 MS Americium-241 13.7 U 0.00136 13.4 pCi/g 98 (75%-125%) 10/30/06 10:58 Uncert: +/-0.138 +/-1.31 TPU: +/-0.138 +/-2.08 Curium-242 U 0.0391 U 0.0528 pCi/g Uncert: +/-0.110 +/-0.0991 TPU: +/-0.110 +/-0.0993 Curium-243/244 16.5 U -0.0385 16.0 pCi/g 97 (75%-125%) Uncert: +/-0.139 +/-1.43 TPU: +/-0.140 +/-2.41 Batch 583312 QC1201216893 174936001 DUP Plutonium-238 U -0.104 U -0.0623 pCi/g 50 (0% - 100%) vIXA1 10/30/06 10:58 53
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 2 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Alpha Spec Batch 583312 Uncert: +/-0.112 +/-0.114 TPU: +/-0.113 +/-0.114 Plutonium-239/240 U -0.137 U -0.0217 pCi/g 145 (0%- 100%) Uncert: +/-0.0631 +/-0.108 TPU: +/-0.0652 +/-0.108 QC1201216895 LCS Plutonium-238 U 0.00501 pCi/g (75%-125%) 10/30/06 10:58 Uncert: +/-0.0185 TPU: +/-0.0186 Plutonium-239/240 2.49 2.37 pCi/g 95 (75%-125%) Uncert: +/-0.239 TPU: +/-0.334 QC1201216892 MB Plutonium-238 U -0.0011 pCi/g 10/30/06 10:58 Uncert: +/-0.0122 TPU: +/-0.0122 Plutoriium-239/240 U 0.000219 pCi/g Uncert: +/-0.0119 TPU: +/-0.0119 QC1201216894 174936001 MS Plutonium-238 U -0.104 U 0.0643 pCi/g (75%-1 25%) 10/30/06 10:58 Uncert: +/-0.112 +/-0.142 TPU: +/-0.113 +/-0.142 Plutonium-239/240 12.6 U -0.137 12.8 pCi/g 102 (75%-125%) Uncert: +/-0.0631 +/-1.22 TPU: +/-0.0652 +/-1.79 Batch 583313 QC1201216897 174936001 DUP Plutonium-241 U -5.01 U 1.93 pCi/g 0 (0% - 100%) VIXAI 11/02/06 09:45 Uncert: +/-7.31 +/-8.93 TPU: +/-7.31 +/-8.93 QC1201216899 LCS Plutonium-241 35.9 27.9 pCi/g 78 (75%-125%) 11/02/06 10:18 Uncert: +/-2.66 TPU: +/-3.77 QC1201216896 MB Plutonium-241 U 4.08 pCi/g 11/02/06 09:29 Uncert: +/-8.97 TPU: +/-9.01 QC1201216898 174936001 MS Plutonium-241 141 U -5.01 124 pCi/g 88 (75%-125%) 11/02/06 10:01 Uncert: +/-7.31 +/-11.4 TPU: +/-7.31 +/-16.5 Rad Gamma Spec Batch 583389 QC1201217096 174911001 DUP Actinium-228 0.325 0.320 pCi/g 2 (0%- 100%) MJHI 10/31/06 10:33 Uncert: +/-0.119 +/-0.135
+/-0.135 54
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 3 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 583389 TPU: +/-0.119 Americium-241 U 0.018 U 0.0192 pCi/g 6 (0%- 100%) Uncert: +/-0.0921 +/-0.058 TPU: +/-0.0921 +/-0.058 Bismuth-212 0.274 UI 0.00 pCi/g 36 (0% - 100%) Uncert: +/-0.157 +/-0.192 TPU: +/-0.157 +/-0.192 Bismuth-214 0.423 0.448 pCi/g 6 (0% - 100%) Uncert: +/-0.070 +/-0.0781 TPU: +/-0.070 +/-0.0781 Cesium-134 Ul 0.00 UI 0.00 pCi/g 16 (0% - 100%) Uncert: +/-0.033 +/-0.0327 TPU: +/-0.033 +/-0.0327 Cesium- 137 UT 0.00 U -0.00065 pCi/g 208 (0% - 100%) Uncert: +/-0.0281 +/-0.0206 TPU: +/-0.0281 +/-0.0206 Cobalt-60 U -0.013 U 0.00792 pCi/g 827 (0%- 100%) Uncert: +/-0.0169 +/-0.0186 TPU: +/-0.0169 +/-0.0186 Europium- 152 U 0.024 U 0.0167 pCi/g 36 (0%- 100%) Uncert: +/-0.041 +/-0.0509 TPU: +/-0.041 +/-0.0509 Europium- 154 U 0.00185 U -0.0485 pCi/g 216 (0%- 100%) Uncert: +/-0.0495 +/-0.0647 TPU: +/-0.0495 +/-0.0647 Europium- 155 U 0.0651 U -0.033 pCi/g 612 (0%- 100%) Uncert: +/-0.0432 +/-0.0473 TPU: +/-0.0432 +/-0.0473 Lead-212 0.285 0.346 pCi/g 19 (0%- 100%) Uncert: +/-0.0477 +/-0.0549 TPU: +/-0.0477 +/-0.0549 Lead-214 0.402 0.419 pCi/g 4 (0% - 100%) Uncert: +/-0.0695 +/-0.0777 TPU: +/-0.0695 +/-0.0777 Manganese-54 U 0.000309 U 0.014 pCi/g 191 (0% - 100%) Uncert: +/-0.0169 +/-0.0173 TPU: +/-0.0169 +/-0.0173 Niobium-94 U 0.00718 U 0.0089 pCi/g 21 (0%- 100%) Uncert: +/-0.0145 +/-0.0158 TPU: +/-0.0145 +/-0.0158 Potassium-40 7.04 7.61 pCi/g 8 (0%- 20%) Uncert: +/-0.674 +/-0.836 TPU: +/-0.674 +/-0.836 Radium-226 0.423 0.448 pCi/g 6 (0%- 100%) Uncert: +/-0.070 +/-0.0781 TPU: +/-0.070 +/-0.0781 Silver- 108m U 0.00582 U -0.00782 pCi/g 1360 (0%- 100%) Uncert: +/-0.0134 +/-0.0162 55
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com OC Summary Workorder: 174936 Page 4 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 583389 TPU: +/-0.0134 +/-0.0162 Thallium-208 0.107 0.108 pCi/g 2 (0%- 100%) Uncert: +/-0.031 +/-0.036 TPU: +/-0.031 +/-0.036 QC 1201217097 LCS Actinium-228 U 0.166 pCi/g 10/31/06 10:56 Uncert: +/-0.579 TPU: +/-0.579 Americium-241 23.4 25.2 pCi/g 108 (75%-125%) Uncert: +/-1.33 TPU: +/-1.33 Bismuth-212 U 0.169 pCi/g Uncert: +/-0.989 TPU: +/-0.989 Bismuth-214 U 0.208 pCi/g Uncert: +/-0.235 TPU: +/-0.235 Cesium- 134 U 0.0196 pCi/g Uncert: +/-0.149 TPU: +/-0.149 Cesium- 137 9.54 10.1 pCi/g 106 (75%-125%) Uncert: +/-0.474 TPU: +/-0.474 Cobalt-60 14.2 14.4 pCi/g 101 (75%-125%) Uncert: +/-0.640 TPU: +/-0.640 Europium- 152 U -0.0221 pCi/g Uncert: +/-0.301 TPU: +/-0.301 Europium- 154 U -0.0891 pCi/g Uncert: +/-0.300 TPU: +/-0.300 Europium- 155 U 0.246 pCi/g Uncert: +/-0.296 TPU: +/-0.296 Lead-212 U 0.0927 pCi/g Uncert: +/-0.160 TPU: +/-0.160 Lead-214 U -0.0668 pCi/g Uncert: +/-0.216 TPU: +/-0.216 Manganese-54 U 0.0637 pCi/g Uncert: +/-0.141 TPU: +/-0.141 Niobium-94 U -0.0941 pCi/g Uncert: +/-0.131 TPU: +/-0.131 Potassium-40 U 0.512 pCi/g 56
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 5 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 583389 Uncert: +/-1.01 TPU: +/-1.01 Radium-226 U 0.208 pCi/g (75%-125%) Uncert: +/-0.235 TPU: +/-0.235 Silver- 108m U 0.00145 pCi/g Uncert: +/-0.116 TPU: +/-0.116 Thallium-208 U 0.109 pCi/g Uncert: +/-0.124 TPU: +/-0.124 QC1201217095 MB Actinium-228 U 0.017 pCi/g 10/31/06 09:31 Uncert: +/-0.0424 TPU: +/-0.0424 Americium-241 U 0.00734 pCi/g Uncert: +/-0.0106 TPU: +/-0.0106 Bismuth-212 U 0.000324 pCi/g Uncert: +/-0.0883 TPU: +/-0.0883 Bismuth-214 U 0.0233 pCi/g Uncert: +/-0.033 TPU: +/-0.033 Cesium- 134 UI 0.00 pCi/g Uncert: +/-0.0377 TPU: +/-0.0377 Cesium-137 U -0.00239 pCi/g Uncert: +/-0.0102 TPU: +/-0.0102 Cobalt-60 U 0.0115 pCi/g Uncert: +/-0.0112 TPU: +/-0.0112 Europium-152 U -0.00208 pCi/g Uncert: +/-0.0274 TPU: +/-0.0274 Europium- 154 U 0.0176 pCi/g Uncert: +/-0.030 TPU: +/-0.030 Europium- 155 U 0.00314 pCi/g Uncert: +/-0.0186 TPU: +/-0.0186 Lead-212 U 0.0227 pCi/g Uncert: +/-0.0166 TPU: +/-0.0166 Lead-214 UI 0.00 pCi/g Uncert: +/-0.0396 TPU: +/-0.0396 57
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 6 of 9 Parmnan tie NOM Sample Oual QC Units RPD% REC% Range AnIst Date Time e NO Rad Gamma Spec Batch 583389 Manganese-54 U -0.00543 pCi/g Uncert: +/-0.0113 TPU: +/-0.0113 Niobium-94 U 0.00493 pCi/g Uncert: +/-0.0109 TPU: +/-0.0109 Potassium-40 U 0.356 pCi/g Uncert: +/-0.179 TPU: +/-0.179 Radium-226 U 0.0233 pCi/g Uncert: +/-0.033 TPU: +/-0.033 Silver- 108m U -0.00346 pCi/g Uncert: +/-0.00831 TPU: +/-0.00831 Thallium-208 U 0.0108 pCi/g Uncert: +/-0.0183 TPU: +/-0.0183 Rad Gas Flow Batch 583243 QC1201216718 174936001 DUP Strontium-90 0.0263 0.0557 pCi/g 72 (0% - 100%) KSD1 11/02/06 09:35 Uncert: +/-0.0109 +/-0.019 TPU: +/-0.011 +/-0.019 QC1201216720 LCS Strontium-90 1.64 1.34 pCi/g 82 (75%-125%) 11/02/06 09:35 Uncert: +/-0.0863 TPU: +/-0.0946 QC1201216717 MB Strontium-90 0.0333 pCi/g 11/02/06 09:35 Uncert: +/-0.0137 TPU: +/-0.0137 QC1201216719 174936001 MS Strontium-90 5.18 0.0263 4.66 pCi/g 89 (75%-125%) 11/02/06 09:35 Uncert: +/-0.0109 +/-0.304 TPU: +/-0.011 +/-0.330 Rad Liquid Scintillation Batch 583233 QC1201216690 174936001 DUP Technetium-99 U 0.320 U 0.321 pCi/g 0 (0% - 100%) KXRI 10/31/06 04:00 Uncert: +/-0.221 +/-0.291 TPU: +/-0.221 +/-0.291 QC1201216692 LCS Technetium-99 13.0 12.9 pCi/g 99 (75%-125%) 10/31/06 04:32 Uncert: +/-0.501 TPU: +/-0.601 QC1201216689 MB Technetium-99 U 0.047 pCi/g 10/31/06 03:43 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 7 of 9 Parmname NOM Sample Qual QC Units RPD % REC% Range AnIst Date Time Rad Liquid Scintillation Batch 583233 Uncert: +/-0.238 TPU: +/-0.238 QC1201216691 174936001 MS Technetium-99 13.1 U 0.320 12.5 pCi/g 96 (75%-125%) 10/31/06 04:16 Uncert: +/-0.221 +/-0.543 TPU: +/-0.221 +/-0.631 Batch 583234 QC1201216694 174936001 DUP Tritium U 3.72 U -6.31 pCi/g 0 (0% - 100%) DFAI 10/28/06 08:10 Uncert: +/-5.94 +/-6.86 TPU: +/-5.94 +/-6.86 QC1201216696 LCS Tritium 51.5 45.3 pCi/g 88 (75%-125%) 10/28/06 08:42 Uncert: +/-8.97 TPU: +/-9.01 QC1201216693 MB Tritium U -0.82 pCi/g 10/28/06 07:54 Uncert: +/-5.74 TPU: +/-5.74 QC1201216695 174936001 MS Tritium 60.3 U 3.72 48.1 pCi/g 80 (75%-125%) 10/28/06 08:26 Uncert: +/-5.94 +/-10.1 TPU: +/-5.94 +/-10.1 Batch 583236 QC1201216702 174936001 DUP Carbon-14 U 0.179 U 0.0712 pCi/g 0 (0% - 100%) 6,XD2 10/28/06 01:06 Uncert: +/-0.112 +/-0.108 TPU: +/-0.112 +/-0.108 QC1201216704 LCS Carbon-14 6.78 6.63 pCi/g 98 (75%-125%) 10/28/06 02:40 Uncert: +/-0.229 TPU: +/-0.251 QC1201216701 MB Carbon- 14 U 0.0836 pCi/g 10/28/06 00:19 Uncert: +/-0.109 TPU: +/-0.109 QC1201216703 174936001 MS Carbon- 14 7.17 U 0.179 6.59 pcilg 92 (75%-125%) 10/28/06 01:53 Uncert: +/-0.112 +/-0.237 TPU: +/-0.112 +/-0.258 Batch 583239 QC1201216710 174936001 DUP Iron-55 U 14.2 U -3.35 pCi/g 0 (0% - 100%) VIXPI 11/01/06 19:15 Uncert: +/-19.7 +/-19.4 TPU: +/-19.7 +/-19.4 QC1201216712 LCS Iron-55 57.2 54.5 pCi/g 95 (75%-125%) 11/01/06 19:47 Uncert: +/-3.71 TPU: +/-5.38 59
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 8 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Rad Liquid Scintillation Batch 583239 QC1201216709 MB Iron-55 U -0.337 pCi/g 11/01/06 16:51 Uncert: +/-1.02 TPU: +/-1.02 QC1201216711 174936001 MS Iron-55 611 U 14.2 593 pCi/g 97 (75%-125%) 11/01/06 19:31 Uncert: +/-19.7 +/-37.3 TPU: +/-19.7 +/-58.7 Batch 583241 QC1201216714 174936001 DUP Nickel-63 U -0.799 U 0.571 pCi/g 0 (0% - 100%) "4XP1 11/01/06 17:24 Uncert: +/-7.83 +/-7.52 TPU: +/-7.83 +/-7.52 QC1201216716 LCS Nickel-63 179 160 pCi/g 90 (75%-125%) 11/01/06 18:07 Uncert: +/-6.78 TPU: +/-8.10 QC1201216713 MB Nickel-63 U 1.12 pCi/g 11/01/06 17:02 Uncert: +/-2.38 TPU: +/-2.38 QC1201216715 174936001 MS Nickel-63 535 U -0.799 448 pCi/g 84 (75%-125%) 11/01/06 17:45 Uncert: +/-7.83 +/-19.0 TPU: +/-7.83 +/-24.7 Notes: The Qualifiers in this report are defined as follows: A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL 60
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 174936 Page 9 of 9 Parmname NOM Sample. Qual QC Units RPD% REC% Range AnIst Date Time A h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
** Indicates analyte is a surrogate compound.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. 61
General Narrative 1
General Narrative for Connecticut Yankee Atomic Power Co. Work Order: 177540 SDG: MSR#06-1549 December 14, 2006 Laboratory Identification: General Engineering Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 Summary Sample receipt The samples arrived at General Engineering Laboratories, LLC, Charleston, South Carolina on November 10, 2006 and November 30, 2006 for analysis. Shipping container temperatures were checked, documented, and within specifications. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any visible signs of tampering or breakage. Sample Identification The laboratory received the following samples: Laboratory Sample Identification Description 177540001 9522-0001-00IF 177540002 9522-0001-002F 177540003 9522-0001-003F 177540004 9522-0001-004F 177540005 9522-0001-005F 177540006 9522-0001-006F 177540007 9522-0001-009F 177540008 9522-0001-OIOF 177540009 9522-0001-01 IF 177540010 9522-0001-012F 177540011 9522-0001-013F 177540012 9522-0001-015F 177540013 9522-0001-016F 177540014 9522-0001-021-1 177540015 9522-0001-024-1 177540016 9522-0002-002F 177540017 9522-0002-003F 177540018 9522-0002-005F 177540019 9522-0002-007F 177540020 9522-0002-008F 177540021 9522-0002-01OF 177540022 9522-0002-01 IF 177540023 9522-0002-012F 177540024 9522-0002-013F 177540025 9522-0002-014F GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, NC. P.O. BOX 30712 Charleston, SC 29417 " 2040 Savage Road (29407) Phone (843) 556-8171 - Fax243) 766-1178 www.gel.com
177540026 9522-0002-016F 177540027 9522-0003-00IF 177540028 9522-0003-002F 177540029 9522-0003-003F 177540030 9522-0003-004F 177540031 9522-0003-005F 177540032 9522-0003-007F 177540033 9522-0003-008F 177540034 9522-0003-009F 177540035 9522-0003-OIOF 177540036 9522-0003-01IF 177540037 9522-0003-012F 177540038 9522-0003-013F 177540039 9522-0003-014F 177540040 9522-0003-015F 177540041 9522-0004-001F 177540042 9522-0004-002F 177540043 9522-0004-003F 177540045 9522-0004-005F 177540046 9522-0004-006F 177540047 9522-0004-008F 177540048 9522-0004-009F 177540049 9522-0004-OIOF 177540050 9522-0004-011 F 177540051 9522-0004-012F 177540052 9522-0004-013F 177540053 9522-0004-014F 177540054 9522-0004-015F 177540055 9522-0004-016F Items of Note The above samples were relogged at the request of Arthur Hammond on 12/11/06. See attached emails. Case Narrative Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package. Analytical Request Fifty-four soil samples were analyzed for Strontium-90. Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, Data Review Qualifier Definitions, and data from the following fractions: Radiochemistry. I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature. Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP. INC. P.O. BOX 30712 Charleston, SC 29417
- 2040 Savage Road (29407)
Phone (843) 556-8171 - Fa4x43) 766-1178 www.gel.com
List of current GEL Certifications as of 14 December 2006 State Certification Alaska UST-062 Arizona AZ0668 Arkansas 88-0651 CLIA 42D0904046 California 01 151CA Colorado GenEngLabs Connecticut PH-01 69 Dept. of Navy [ NFESC 413 EPA [ WG-15J Florida/NELAP E87156 Georgia E87156 (FL/NELAP) Hawaii N/A Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas E-10332 Kentucky 90129 Louisiana 03046 Maryland 270 Massachusetts M-SC012 Michigan 9903 Nevada SC12 New Jersey SCO02 New Mexico FL NELAP E87156 New York 11501 North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-00485 South Carolina 10120001/10585001/10120002 Tennessee 02934 Texas TX213-2006A Texas NELAP T104704235-06-TX U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah 8037697376 GEL Vermont VT87156 Virginia 00151 Washington C1641 4
Chain of Custody and Supporting Documentation 5
Health Physics, Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Chain of Custody Form N.20-06 Connecticut Yankee Atomic Power Company No. 2006-00666 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use.Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories t 2-1H it.e+ 1654 2040 Savage Road. Charleston SC. 29407 <A 843 556 8171. Attn. Cheryl Jones CA Priority: L] 30D. [] 14 D. Z 7 D. [] 3 D. Container Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Code Code Code ON 9522-0001-012F 11/09/06 0808 TS G BP X _ ___ _ _" _ 9522-0001-015F 11/09/06 0815 TS G BP X 9522-0001-002F 11/09/06 0954 TS G BP X el 9522-0001-OOIF 11/09/06 0955 TS G BP X 9522-0001-003F 11/09/06 0958 TS G BP X 9522-0001-OIOF 11/09/06 1052 TS G BP X 9522-0001-014F 11/09/06 1054 TS G BP X 9522-0001-009F 11/09/06 1057 TS G BP X
*9522-0001-009FS 11/09/06 1057 TS G BP X 9522-0001-008F 11/09/06 1311 TS G BP X 9522-0001-01IF 11/09/06 1312 TS G BP X NOTES: PO #: 002332 MSR #: 06-1 SSWP# NA Z LTP QA El Radwaste QA Li Non QA Samples Shipped Via: Internal Container Z Fed Ex Temp.: Deg.
LI UPS C 13 Hand Custody Sealed? Y1 N0
- 1) Relinquished By Date/Time 1I 2) = -
,l IfDate/Time
- in [F] Other Custody Seal intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time YEl N U Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00667 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 CJ < 843 556 8171. Attn. Cheryl Jones Priority: [] 30 D. [1 14 D. [] 7 D. 3 D. Cota,. Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0001-013F 11/09/06 1337 TS G BP X I 9522-0001-005F 11/09/06 1358 TS G BP X - -'- 9522-0001-006F 11/09/06 1400 TS G BP X 9522-0001-004F 11/09/06 1405 TS G BP X NOTES: PO #: 002332 MSR #: 06-I1,81 SSWP# NA 0 LTP QA [] Radwaste QA D Non QA Samples Shipped Via: Internal Container Z Fed Ex Temp.: - Deg. Q UPS C [] Hand Custody Sealed? YO NO
- 1) Relinquished By Date/Time
- l0 *igived By Date/Time Custody Seal E] Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time YO NO Bill of Lading 4
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Chain of Custody Form N.20-07 Connecticut Yankee Atomic Power Company No. 2006-00671 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 ______ V Project Name: Haddam Neck Decommissioning Analyses Requested I Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 843 556 8171. Attn. Cheryl Jones ci: Priority: ] 30 D. El 14 D. H 7 D. n 3 D. Container Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Code Code Code -. 9522-0001-016F 111/15/06 TS c BP X
-i --
NOTES: PO #: 002332 MSR #: 06-1;',rV SSWP#NA Z LTPQA E Radwaste QA E] Non QA Samples Shipped Via: Internal Container E Fed Ex Temp.: __ Deg. El UPS C F1 Hand Custody Sealed? Y P N i0 I) Relinquished By Date/Time 2) Re i ed By Date/Time Custody Seal 0 Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time Y!] N L' Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Maj or Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00677 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab.Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories
- 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority: El 30 D. [] 14 D. N 7 D. ZI 3 D. Ca r.9 Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0001-017-I 11/16/06 0716 TS G BP X 9522-0001-018-1 11/16/06 0717 TS G BP X 9522-0001-019-I 11/16/06 0718 TS G BP X 9522-0001-020-1 11/16/06 0719 TS G BP X 9522-0001-021-I 11/16/06 1335 TS G BP X 9522-0001-022-I 11/16/06 1340 TS G BP X 9522-0001-023-I 11/16/06 1345 TS G BP X NOTES: PO #: 002332 MSR #: 06-1~rS 3WP# NA 0 LTP QA D] Radwaste QA E] Non QA Samples Shipped Via: Internal Container
[ Fed Ex Temp.: - Deg. EuPs C E Hand Custody Sealed? Y N
- 1) Relinquished By Date/Time 2 c ed By / Date/Time Custody, Seal E Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time Y N Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00684 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Onl, Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority : [" 30 D . ] 14 D . Z 7 D . 1 3 D . Conta i e Container Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0001-024-1 11/21/06 "Z 5-{ TS G BP X NOTES: PO #: 002332 MSR #: 06-1T30 SSWP# NA Z LTP QA D Radwaste QA D Non QA Samples Shipped Via: Internal Container i5 66 0 Fed Ex Temp.: __ Deg. 0 UPS C El Hand Custody Sealed? Y [J N1
- 1) Relinquished By Date/Time Date/Time Custody Seal ED Other Intact?
240 = Reli.que 19 D e U Q
- 3) Relinquished By Date/Time 4) Received By Date/Time Y"1 NO Bill of Lading #
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Samplc Chcck-In List Datc/Ti-rc Rcccivcd: II LG.&,Q
, / O% I0 SDG#: Nlsuý4ouh,.- ,. - C, Work Order Number: t- * * ,
ShippingI Containcr ID: §Se e C c.-A aldo ' l"tody I1. Custody Seats oil shipping container intact'? Yes )(No []
- 2. Custody Seals dated and signed? Yes/A No [
- 3. Chain-of-Custody record present? Yes L\No [
- 4. Cooler temperature . @ e rC4 r i t. I
- 5. Vermiculite/packing materials is: Wet (] Dry [\
- 6. Number of samples in shipping container:
- 7. Sample holding times exceeded'? Yes [] No X
- 8. Samples have:
tape hazard labels custody seals _ appropriate sample labels
- 9. Samples arc:
. in good condition leaking broken have air bubbles I0. Were any anom.alies identified in sample receipt'? Yes X No I . Description of anomalies (include sample numbers): 1 !9tn -e Sample Ctisiodiian./L..aboratory: AU, .... LO..... Date: /1' 30"'0 Telephoned to: On By_
Page 45 of 56 11
SAMPLE RECEIPT & REVIEW FORM PM am0Onl il SDG/ARCOCWrk OrderI I SDate Received: 11 FM(A) Review (ensure non-cafl Items we resolved prior d~:ii Received By: Sample Receipt Criteria ; Comments/Oualifiers (Required for Non-Conformini Items) Shipping containers received intact Cirle Applicable: sels broken damged cotainer leaking coniner "Iemtbe) and sealed? _____ Samples requiring cold Circle Coola.t I ice bass blue ice dry ice none Fler describt) 2 preservation within (4 +1- 2 C)? Record preservation method. _ __ ,__ Chain of custody documents 3 included with shipment? a 4 Sample containers intact and Circle Applicae: sesls broken damaged conancr Icaki sealed? / Samples requiring chemical Snpe ID's. cotainers affected and observed pH:. reservation at proper pH? 6VOA vials free of headspace s"P'e I's and containers alfec,: 6 (defined as < 6mm bubble)? .............. ... ___ .... Are Encore containers present? 7 (If yes, immediately deliver to VO A laboratory) . . ....... . . ..... .. _ _ Samples received within holding Id's ard tests Affecied: 8 time? Sample ID's on COC match ID's S.pe ID's Sod coainers affecwd: 9 on bottles? Date & time on COC match date Sample ID'S affected:
& time on bottles? V" Number of containers received Sni I t...ttid:
match number indicated on COC? COC form is properly signed in Srelinquished/received sections? Air Bill #Tracking
's, &
Additional Comments 7 017 C) S'k Ta r ii IV RSO RAOD pt, .i__ Hzr > x2 area backgrund is observed on samples identified 'non-Suspected Hazard Inrormation 10 regulated/non-radioactive'. contact the Radiation Safety group for furtr O investigation. Radiological Classification? "Z. Maximum Counts Observed*: 77 B PM Regulated? 1happed as VUfl' Hazardous Matcrial? If yes, contact Waste Hazad Class Shipped: aManager or ESH Manager. N#: DIRegulated as a Foreign Soil? PM (or PMA) review of Hazard classification: v InitialsDate: ' 1 12
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Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Chain of Custody Form N.20-04 Connecticut Yankee Atomic Power Company No. 2006-00648 362 Injun Ilollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road, Charleston SC. 29407 0 843 556 8171. Attn. Cheryl Jones Priority: E] 30D. [] 14 D. N 7 D. 1 3 D. Container Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0002-013F 10/30/06 1100 TS G BP X 4'w-Jo*- o/L ! 4/ 6~i 13)-A _rf G , x 91rx -O,.+-)Gr- 10 );/,2)6 L ? yo TS
?L ap /,
a)~- 01 I'hoI"6 / O j - jf.- __ NOTES: PO#: 002332 MSR #: 06-4g 8r"*'A SSWP# NA Z LTP QA El Radwaste QA El Non QA Samples Shipped Via: Internal Container
/.yl9r Z Fed Ex Temp.: _7ý Deg.
El UPS C El Hand Custody Sealed? YD" NL
- 1) Reli nqui d By2. Date/Time 2) Received By Date/Time Custody Seal El Other Intact?
- 3) R inquished By Date/Time 4) Received By Date/Time Y! E" ND Bill of Lading #
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-O01
, i Figure 1. Sample Check-in List.
Date/Time Received: i - O C/,(-. 9 SDG#: P31_(~~ Work Order Number: - 75 7-'Tc' Shipping Container ID: 75 3* 9 'R3&2" Chain of Custody c - e ýý.
- 1. Custody Seals ori shipping container intact?.. -Yes , No []
- 2. Custody Seals dated and signed? Yes' aNo [I.
- 3. Chain-of-Custoly record present? Yes ,NO toI
- 4. Cooler temperature -- "'
- 5. Vermiculite/packing materials is: Wet [ Dry A)A- 2r1 .
6 *'Number of samples in shipping container:; "
- 7. Sample holding times exceeded? Yes [] No [a,]
S. Samples have-' tape-hazard labels
-custody seals -appropriate sample labels
- 9. Samples are.
good condition
-leaking
-broken ' have air bubbles
- 10. Were any anomalies identified in sample receipt? Yes []No [L.
- 11. Description of anomalies.(include sample numbers):
Sample Custodian/Laboratory: -"4"" 7', Z Date:., */"/ Telephoned to: On By 16
SAMPLE RECEIPT & REVIEW FORM PM use only ClientC~mea- (t_+ Ya4)hpp? SDG/ARCOC[WorIS Order: 5 j 90 Date Received: 1 - PM(A) Review (ensure non-con i gt sgare resolved prior to signing): Received By: Y4 Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items) Circle Applicable: seals broken damaged container liaking container other (describe) 1 Shipping containers received intact and sealed? I Samples requiring cold Circle Coolant # ice bags blue ice dry ice none other describe) 2 preservation within (4 +/- ? Record preservation method. " - Chain of custody documents included with shipment? 4 Sample containers intact and Circle Applicable: seals broken damaged container leaking container other (describe) sealed? '_ 5 Samples requiring chemical Sample ID's, containers affected and observed pH:
- preservation at proper pH?
6VOA-vials free of headspace Sa 's and containers affected: 6 (defined as < 6ram bubble)?_. Are Encore containers present? 7 (If yes, immediately deliver to VOA laboratory) 8tiSamples received within holding Id's and tests affected: time? 9 Sample ID's on COC match ID's Sample ID's and containers alted on bottles? 10 Date & time on COC match date Sample ID's affected 10 & time on bottles? U Number of containers received Sample ID's affected: match number indicated on COC? 12 COG form is properly signed in 1relinquished/received sections? Air Bill ,Tracking #'s, & Additional Comments V "o T RSO RAD Receipt## ______________"____ Z cedi*d"...
- .Su "J*If > x2 atea background is observed on samplp idetified as "nn regulated/non-radioactive, contact the Radiation Safe group orfurther.
___________. __:. ___. ___. ___ _
- linvestigation.
A adiO10gical Classifictioafn? Maximum.Counts Observed*: ( ':
~~~
PC euated? nnns Mhpeda -- '1 I%0--Ia9atddus Material? If yes ,contact "< UC Waste
' " Hazard Class
~~URN#: Shipped:
Manager orESH Manager. PM (or PMA) review of Hazard classification: Initials Date: \ O,'o a 17
Health Physics ProcedUre GPP-GGGR-R55104-003-Attachment B-CY-00 1 Major Chain of Custody Form N.20-05 Connecticut Yankee Atomic Power Company No. 2006-00655 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 < 0 < -A t C_ 843 556 8171. Attn. Cheryl Jones U U Priority: [] 30 D. [ 14 D. [E 7 D. [] 3 D. Container C iaie"l:1cl-.
-4J-V4o
*.'SSA# F56 ALLALL Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code
,- i]/*L l,)¶" TS G BP /
Lj* 9y o j).)- .!I1/*, /)iI-( TS G BP __,
./s)-o3, 1!: i, I3 . TS G BP _
.*t-:' - p F, /ii;,, ; r & gi /.-
c~'~ )cc'~F t'!/ uc 3p.. .4S.~ .. L - ________ NOTES: PO#: 002332 MSR #: 06-P '¢8+0 tSSWP# NA Z LTP QA El Radwaste QA E] Non QA Samples Shipped Via: Internal Container 1q51 Z Fed Ex El UPS Temp.: J0!Deg. C El Hand Cut d Sealed? uYV Nn 1)R in "hed Date/Time 2) Received By Date/Time Custody Seal El Other Intact? 3)'ielinquished By Date/Time 4) Received By Date/Time -?7 Or /5l 25" YE N3 Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Chain of Custody Form N.20-05 Connecticut Yankee Atomic Power Company No. 2006-00656 362 Injun Hollow Road, East Hampton. CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones ) Priority: [] 30 D. [1 14 D. Z 7 D. [-J 3 D. Ca - - Container F56O R-*::, LL-Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0003-009F 11/6/06 0734 TS G BP X 9522-0003-OIIF 11/6/06 0737 TS G BP X 9522-0003-OIOF 11/6/06 0739 TS G BP X 9522-0003-012F 11/6/06 0741 TS G BP X 9522-0003-014F 11/6/06 0800 TS G BP X 9522-0003-015F 11/6/06 0803 TS G BP X 9522-0003-013F 11/6/06 0805 TS G BP X 9522-0003-016F 11/6/06 o TS G BP -*T K betS1 NOTES: PO #: 002332 MSR #: 06-4-1,# SSWP# NA SLTP QA F1 Radwaste QA RI Non QA Samples Shipped Via: Internal Container Il15- Z Fed Ex Temp.: T Deg. F1 ups C [] Hand Custody Sealed? Y W" N-,
) Relinqsed Date/Time 2) Received By Date/Time Custody Seal Z Other Intact?
- 3) linquished By Date/Time 4) Received By Date/Time 7 '6 3;$f I 25"2 Y'N :1 Bill of Lading #
Connecticut Yankee ¢Y-ISC-SOW-001 Statement of Work for Analytical Lab ServicesC Figure 1. Sample Check-in List Date/Time Received4: 1 ).0'0, s g (,Y,- -,f SDGU#: 17$Sq iM7*'" Work Order Number: Chain of Custgdy*# QQ2t&d CUA55ý t* Y(5 Shpig,C itir D: 7 3ý32 5C95 Yes t No (1
- 1. Custody Seals oaishipping container intact?.
- 2. Custody Seals dated and signed? Yes [to (
- 3. Chain-of-Custody rcord present? ' Yes [1 /No .] "
-4. Cooler temperature __
- 5. Vermiculitc/packing materials is: -' Wet ( ] Dry t\ ] A .
6;; ' *Numberof-samples in shipping container:. - Sample holding times exceeded? Yes [No/ 7. Samples have. s.8.
.... hazard labels
.. ~ cu~tody seals . appropriate sample labels
- 9. Samples are:
_ L.jM good condition -leaking
-broken .. .hai. air bubbles
- 10. ~~yesin sample receipt?
Were any anomalies identified []No t 1.. Descriptomn of anomalies (include sample numbers): Sample Custodian/Laboratoy .. Date.: Telephoned to_-"
.- Coy-i.
20
0 SAMPLE RECEIPT & REVIEW FORM r PM use only Client: C(x_(p ,- 17 &"Z. SDG/ARCOC!Work Order: I"{-F7,
- t **O Date Received: ( JPM(A) Review (ensure noo-cont rming items are resolved prior to signing):
2 .7 <Ir'--
)-.-l
-Received By: Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items) Circle Applicable, seals broken damaged comtainer leaking container other (describe) 1 Shipping containers receved intact and sealed? *__ Samples requiring cold Circle Coolant # ice bags blue ice dry ice none other desuribe) 2 preservation within (4 +/- 2,)? Record preservation method. "__ Chain of custody documents included with shipment? 4 Sample containers intact and Circle Applicable: seals broken damaged container leaking container other (describe) sealed? 5 Samples requiring chemical Sample ID's. containers affected and observed pH: preservation at proper pH? _ VOA vials free of headspace Sample Uo's and containers affected: (defined as < 6mm bubble)? Are Encore containers present? 7 (If yes, immediately deliver to
-VOA laboratory)
Id's and tes iected: within holding time? received 8 Samples 4 9 Sample ID's on COC match ID's Sample U's and iners affected: on bottles? ,, \ Date & time on COC match date Sample U's affected: 10 & time on bottles? 11 Number of containers received Sample ID's affected: match number indicated on COC? COC form is properly signed in 12 relinquished/received sections? 14 Air Bill ,Tracking #'s, & Additional Comments S RSORADReceipt# ___________________
... o c *If > x2 area background is observed on s lesidentified as :.on"-
Suspectedý Hazard Information 27
. & regulated/non-radioactive". contact the Radiation Safetygroup for further I_ iiIII IIIIInvestigation.
ARadiologia.Classifcation9 "-L Maximum Counts Observed*: {Cy0 C)
,PCB Bý Regulated? -omments:
Shlippedl as D*O I .Hazatd~us _azal Cls - ' .ip'p' .'d" C Material?:If:yes, contact Waste azard Class Shipped: Manager' or ESIH Manager. N#: PM (or PMA) review of Hazard classification: v' Initials Date: -- t-U 21
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Chain of Custody Form N.20-08 Connecticut Yankee Atomic Power Company No. 2006-00685 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Iab'U~e"O-l, Contact Name & Phone: 'c0mri&e*: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 < 843 556 8171. Attn. Cheryl Jones Priority: [130 D. [1 14 D. Z 7 D. r 3 D.
. Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 952 2 0 0 0 4
- -0 17 L 0./D2 I TS G BP _ _ _ _ '
*'.Ž -o,( -,o" El 1.L . 6i7) 7*f 6_ e 9*i.1. r(A?,_ e,:'* t//(2l/*i .t17..,.L .... &l __ ___ _ __ _ __ _ __ ...
s)..~~ .s7=.Lif 7(yu~( T(/J)/' .ý- _________________ y,)-o)of f-/pr! o 3)1 T7 8 --- -- NOTES: PO #: 002332 MSR #I:0--1 SSWP# NA E LTP QA E Radwaste QA 0 Non QA Samples Shipped Via: Internal Container 0 Fed Ex Temp.: h Deg. 05043, E UPS C 0 Hand Custodyy Sealed? YE NO
- 1) Relinquished By Date/Time 2) Rate/Tube Custody Seal
- 3) Relinquished By Date/Time 3)IU0tý P3 -JA 4) 1e IA) E] Other "Ina-ct?
- 4) Received By IDatetTimre I YE NE Bill of Lading#
ffealth Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Chain of Custody Form N.20-08 Connecticut Yankee Atomic Power Company No. 2006-00686 362 lnjun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab UseOnly Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State) General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 < 843 556 8171. Attn. Cheryl Jones Priority: [-] 30 D. ] 14 D. Z 7 D. -1 3 D. Container (c_c6 _0' Sample Size-Sample Designation Date Time Media Type &Type Comment, Preservation Lab Sample ID Code Code Code 9522-0004- oI /{ 0/i V TS G BP _ _ __.... 9 ,;, 1(b; IL 09 y L TL. FRL 9 .. - 9 W/. L: t Wluý 2*- qr.*--*c. t iti- t " - - -U Ti I~l 4 */ NOTES: PO #: 002332 MSR #: 06-,3Vt SSWP# NA Z LTP QA [I Radwaste QA LI Non QA Samples Shipped Via: Internal Container 16o06 Z Fed Ex Temp,: _ Deg. L] ups C Li Hand Custody Sealed? YE NE I) Relinquished By Date/Time 2) ed By DateiT me Custody Seal LI Other Intact?
- 3) Relinquished By Date/Time 4) Received By Date/Time YE NO Bill of Lading #
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List Date/Time Received: j _j_.c), 1, 110 SDG#: M$o..0- -cl
$D , O c- [s%*
Work Order Number: c-4 u% , i qC Shipping Container ID: __ e e___i_____C_ _ "ofIC tody # 2~S~C~nu V ..... ADrN~e
- 1. Custody Seals on shipping container intact? Yes j*No []
- 2. Custody Seals dated and signed? YesA No ]
- 3. Chain-of-Custody record present? Yes [No [ ]
- 4. Cooler temperature I's Ce 0 I .4" -,m* .Shvee',
- 5. Venaniculite/packing materials is: Wet [I Dry
- 6. Number of samples in shipping container:
- 7. Sample holding times exceeded? Yes [ ] No
- 8. Samples have:
_ tape hazard labels custody seals _ appropriate sample labels
- 9. Samples are:
in good condition __ leaking broken _ have air bubbles
- 10. Were any anomalies identified in sample receipt'? Yes X"No 1I. Description of anomalies (include sample numbers): zS C,*n _C Sample Custociian/Laboratory: I-Lh.4 D~ate: 113 6(
Telephoned to: _On Bvy Page 45 of 56 24
SAMPLE RECEIPT & REVIEW FORM PMaueoa~ly L%Y~I'.1y 1f4- (ole t7 (99 r Client: -- t SO)G/ARCOC/Work Order: [ate Received: APM(A) Review (emure nm-conUft wresolved prir 14 dsginpg: Received By: j _ _ _ _"___'" Sample Receipt Criteria Comments/Qualifiers (Required for NoR-Coufnmu& Items) Shipping containers received intact Circl Applicable: seals broken damaged container leaking container o (describe) and sealed? Samples requiring cold Circle Coolant I ice bags blue ice dry ice none oufr describe) 2 preservation within (4 +/- 2 C)? Record preservation method. Chain of custody documents included with shipment? nSample containersintact and ircle Applicable: seals broken damaged container leaking comainer JdC5t) -t1 sealed? Samples requiring chemical le ID's. cers affee ad observed pK: preservation at proper pH? VOA vials free of headspace Sanil ID'sad containers affected: 6 (defined as < 6mm bubble)? Are Encore containers present? 7 (If yes, immediately deliver to VOA laboratoor Samples received within holding Id's and tests arfcted: time? 9 Sample ID's on COC match ID's Sanuile ID's and containers affected: on bottles? Date & time on COC match date Sample ID's affected:
& time on bottles? V Number of containers received ,teI'* afetd match number indicated on COC? V-COC form is properly signed in 12_
relinquished/received __ sections? _ _ / _ ) D 4- _ e!5704 14Air Bill ,Tracking #'s, & - U& o- cZ710 ".gg Additional Comments "*t* 0 ¶)'l"(o - 2'?y 2253 -1"' Hzar Inormtio Susectd 1 V T *I RSO>x2 RADarea Receipt #_ background is observed on samples identified a*"non-Suspected Hzregulated/non-radioactive'. contact the Radiation Safety group [for further 0 investigation. A lRadiological' Ciassification Maximum Counts Observed*: 5/ (at B PC Regulaed?
"lhipped as DO I Hazardous C [Material? If yes, contact Waste HazardClassShipped: ~Manager or IESH Manager.
Regulated as a Foreign S"o~il? N! PM (or PMA) review of Hazard classification: Initials Date: 25
a SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM
/ 0 C '7<a -/ý6loI
-c (oo2'l
- 5o(co 2~
- roo r,1
_______- boo*,* I 26
Re: Additional analyses (Sr-90)
Subject:
Re: Additional analyses (Sr-90) From: Cheryl Jones <cj@gel.com> Date: Tue, 12 Dec 2006 07:55:22 -0500 To: "Arthur L. Hammond" <Hammond@CYAPCO.com> CC: David Wojtkowiak <wojtkowiak@cyapco.com>, Jack McCarthy <mccarthy@cyapco.com> Arthur, The sample listed for recount below (9522-0004-004F) is already being processed as a reanalysis for Sr-90 based on Jack's email last Friday (new workorder 177405). It will be completed this Friday and I will reference the new MSR# below. The remaining samples have been relogged per your request yesterday and will be processed on a 7d TAT. Please let me know if you have any questions. Thanks, Cheryl Arthur L. Hammond wrote: Cheryl, I put a 7 day TAT on the MSR however, if you have the results sooner we will take them. Thank you, Arthur
------ Original Message -----
From: Cheryl Jones [1] Sent: Monday, December 11, 2006 4:33 PM To: Arthur L. Hammond Cc: Clyde Newson; John McCarthy; Jeffrey D. Wagner; David Wojtkowiak; Amanda Rasco
Subject:
Re: Additional analyses (Sr-90) Arthur, Thank you for the list of IDs, we will have the samples pulled from their storage location and rescheduled by tomorrow morning. When do you need this data returned to you (TAT)? Cheryl Arthur L. Hammond wrote: Cheryl, We are requesting additional analyses on the attached list of samples. One sample, 9522-0004-004F, is a recount. The GEL sample ID for that sample is 176890005. We are requesting Sr-90 analyses counts on these samples. The MSR NO 06-1549. Thank you, I of 2 12/12/2006 7:55 AV 27
Re: Additional analyses (Sr-90) Arthur Cheryl A. Jones Project Manager/PM Team Leader General Engineering Laboratories, LLC 2040 Savage Road Charleston, SC (USA) 29407 Direct: 843.769.7388 Main: 843.556.8171 x 4243 Fax: 843.766.1178 E-mail: c J gei .com Web: ,wqe .com 2 of 2 12/12/2006 7:55 AP 28
12/11/2006 MEMORANDUM To: Art Hammond From: Dave Wojtkowiak In support of the FSS of Survey Area 9522, I would like to request additional analysis for Sr-90 in the following soil samples: 9522-0001 -001 F 9522-0003-003F 9522-0001-002F 9522-0003-004F 9522-0001-003F 9522-0003-005F 9522-0001-004F 9522-0003-007F 9522-0001-005F 9522-0003-008F 9522-0001-006F 9522-0003-009F 9522-0001-009F 9522-0003-01OF 9522-0001-01 OF 9522-0003-011 F 9522-0001-011 F 9522-0003-012F 9522-0001-012F 9522-0003-013F 9522-0001-013F 9522-0003-014F 9522-0001-015F 9522-0003-015F 9522-0001-016F 9522-0004-001 F 9522-0001-021-1 9522-0004-002F 9522-0001-024-1 9522-0004-003F 9522-0002-002F 9522-0004-004F (recount) 9522-0002-003F 9522-0004-005F 9522-0002-005F 9522-0004-006F 9522-0002-007F 9522-0004-008F 9522-0002-008F 9522-0004-009F 9522-0002-01 OF 9522-0004-01OF 9522-0002-011 F 9522-0004-011 F 9522-0002-012F 9522-0004-012F 9522-0002-013F 9522-0004-013F 9522-0002-014F 9522-0004-014F 9522-0002-0 16F 9522-0004-015F 9522-0003-001 F 9522-0004-016F 9522-0003-002F Connecticut Yankee FSS Survey Area 9522 Page 1 of 1 29
RE: Additional analyses (Sr-90)
Subject:
RE: Additional analyses (Sr-90) From: "Arthur L. Hammond" <Hammond@CYAPCO.com> Date: Wed, 13 Dec 2006 16:00:57 -0500 To: "Cheryl Jones" <cj@gel.corn> CC: "Clyde Newson" <Newson@CYAPCO.com>, "David Wojtkowiak" <wojtkowiak@cyapco.com>,
"John McCarthy" <McCarthy@ CYAPCO.com>, "Jeffrey D. Wagner" <Wagner@ CYAPCO.com>
Cheryl, As per our conversation sample, 9522-0004-004F, will not need a third recount. It is my understanding that Jack McCarthy had previously requested a recount on this sample on 12/8/06. Thank you, Arthur
----- Original Message-----
From: Cheryl Jones [2] Sent: Monday, December 11, 2006 4:33 PM To: Arthur L. Hammond Cc: Clyde Newson; John McCarthy; Jeffrey D. Wagner; David Wojtkowiak; Amanda Rasco
Subject:
Re: Additional analyses (Sr-90) Arthur, Thank you for the list of IDs, we will have the samples pulled from their storage location and rescheduled by tomorrow morning. When do you need this data returned to you (TAT)? Cheryl Arthur L. Hammond wrote: Cheryl, We are requesting additional analyses on the attached list of samples. One sample, 9522-0004-004F, is a recount. The GEL sample ID for that sample is 176890005. We are requesting Sr-90 analyses counts on these samples. The MSR NO 06-1549. Thank you, Arthur Cheryl A. Jones Project Manager/PM Team Leader General Engineering Laboratories, LLC 2040 Savage Road Charleston, SC (USA) 29407 l of 2 12/13/2006 4:11 PT 30
RE: Additional analyses (Sr-90) Direct: 843.769.7388 Main: 843.556.8171 x 4243 Fax: 843.766.1178 E-mail: cw@gej. .cor Web: ;..gei g .com The information contained in this message is confidential and is intended only for the use of the individual or firm of record. If you are not the intended recipient and have received this message in error, you are asked not to copy or distribute any of the pages that follow. Please notify the sender immediately by telephone or email if you have received this communication in error and destroy the contents that do not pertain to your business with The GEL Group, INC. 2 of 2 12/13/2006 4:11 PT 31
Data Review Qualifier Definitions 32
Data Review Qualifier. Definitions Qualifier Explanation
- A quality control analyte recovery is outside of specified acceptance criteria
- Analyte is a surrogate compound
- Result is less than value reported
> Result is greater than value reported RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank B Metals-Either presence of analyte detected in the associated blank, or MDL/IDL < sample value < PQL BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample d 5-day BOD-The 2:1 depletion requirement was not met for this sample E Organics-Concentration of the target analyte exceeds the instrument calibration range E Metals-%difference of sample and SD is >10%. Sample concentration must meet flagging criteria H Analytical holding time was exceeded h Preparation or preservation holding time was exceeded J Value is estimated N Metals-The Matrix spike sample recovery is not within specified control limits N Organics-Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest internal standard response factor N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the reporting limit UI Gamma Spectroscopy-Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound Z Paint Filter Test-Particulates passed through the filter, however no free liquids were observed. GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC. P.O. BOX 30712 Charleston, SC 29417
- 2040 Savage Road (29407)
Phone (843) 556-8171 F Fa(3) 766-1178 www.geld.com
RADIOLOGICAL ANALYSIS 34
Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK) Work Order 177540 Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 595174 Prep Batch Number: 595088 Dry Soil Prep GL-RAD-A-021 Batch Number: 595084 Sample ID Client ID 177540021 9522-0002-01 OF 177540022 9522-0002-01 IF 177540023 9522-0002-012F 177540024 9522-0002-013F 177540025 9522-0002-014F 177540026 9522-0002-016F 177540027 9522-0003-001F 177540028 9522-0003-002F 177540029 9522-0003-003F 177540030 9522-0003-004F 177540031 9522-0003-005F 177540032 9522-0003-007F 177540033 9522-0003-008F 177540034 9522-0003-009F 177540035 9522-0003-01OF 177540036 9522-0003-01 IF 177540037 9522-0003-012F 177540038 9522-0003-013F 177540039 9522-0003-014F 177540040 9522-0003-015F 1201245012 Method Blank (MB) 1201245013 177540021 (9522-0002-OIOF) Sample Duplicate (DUP) 1201245014 177540021 (9522-0002-OIOF) Matrix Spike (MS) 1201245015 Laboratory Control Sample (LCS) 35
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 177540021 (9522-0002-010F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis. Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. 36
Qualifier information Manual qualifiers were not required. Method/Analysis Information Product: GFPC, Sr9O, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 595177 Prep Batch Number: 595089 Dry Soil Prep GL-RAD-A-021 Batch Number: 595086 Sample ID Client ID 177540041 9522-0004-OOIF 177540042 9522-0004-002F 177540043 9522-0004-003F 177540045 9522-0004-005F 177540046 9522-0004-006F 177540047 9522-0004-008F 177540048 9522-0004-009F 177540049 9522-0004-OIOF 177540050 9522-0004-01 IF 177540051 9522-0004-012F 177540052 9522-0004-013F 177540053 9522-0004-014F 177540054 9522-0004-015F 177540055 9522-0004-016F 1201245020 Method Blank (MB) 1201245021 177540041(9522-0004-001F) Sample Duplicate (DUP) 1201245022 177540041(9522-0004-001F) Matrix Spike (MS) 1201245023 Laboratory Control Sample (LCS) SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10. 37
Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (QC) Information: Blank Information The blank volume is representative of the sample volumes in this batch. Designated QC The following sample was used for QC: 177540041 (9522-0004-001F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Samples 1201245020 (MB), 177540041 (9522-0004-001F), 177540042 (9522-0004-002F), 177540043 (9522-0004-003F), 177540047 (9522-0004-008F), 177540050 (9522-0004-01 IF), 177540052 (9522-0004-013F) and 177540054 (9522-0004-015F) were recounted due to a suspected blank false positive. Samples 1201245020 (MB) and 1201245021 (9522-0004-001F) were recounted due to high MDAs. Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. Additional Comments Additional comments were not required for this sample set. 38
Oualifier information Manual qualifiers were not required. Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 597316 Prep Batch Number: 595087 Dry Soil Prep GL-RAD-A-021 Batch Number: 595082 Sample ID Client ID 177540001 9522-0001-OOIF 177540002 9522-0001-002F 177540003 9522-0001-003F 177540004 9522-0001-004F 177540005 9522-0001-005F 177540006 9522-0001-006F 177540007 9522-0001-009F 177540008 9522-0001-OIOF 177540009 9522-0001-01 IF 177540010 9522-0001-012F 177540011 9522-0001-013F 177540012 9522-0001-015F 177540013 9522-0001-016F 177540014 9522-0001-021-I 177540015 9522-0001-024-1 177540016 9522-0002-002F 177540017 9522-0002-003F 177540018 9522-0002-005F 177540019 9522-0002-007F 177540020 9522-0002-008F 1201250079 Method Blank (MB) 1201250080 177540001(9522-0001-001 F) Sample Duplicate (DUP) 1201250081 177540001(9522-0001-001 F) Matrix Spike (MS) 1201250082 Laboratory Control Sample (LCS) SOP Reference 39
Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met. Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s). Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control (0C) Information: Blank Information The blank volume is representative of the sample volume in this batch. Designated QC The following sample was used for QC: 177540001 (9522-0001-001F). QC Information All of the QC samples met the required acceptance limits. Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time. Preparation Information All preparation criteria have been met for these analyses. Sample Re-prep/Re-analysis Samples 1201250080 (9522-0001-001F), 177540003 (9522-0001-003F), 177540004 (9522-0001-004F), 177540005 (9522-0001-005F), 177540006 (9522-0001-006F), 177540009 (9522-0001-011 F), 177540010 (9522-0001-012F) and 177540015 (9522-0001-024-I) were recounted due to a suspected false positive. Samples were reprepped due to high relative percent difference/relative error ratio. Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set. Miscellaneous Information: NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG. 40
Additional Comments The MDA for sample 177540001 (9522-0001-001 F) was used to calculcate the relative percent difference. Oualifier information Manual qualifiers were not required. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Review Validation: GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package. The following data validator verified the information presented in this case narrative: Reviewer/Date: V a ,_T_6 41
SAMPLE DATA
SUMMARY
42
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co. Client SDG: MSR#06-1549 GEL Work Order: 177540 The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
- Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
ND The analyte concentration is not detected above the detection limit. The above sample is reported on a dry weight basis except where prohibited by the analytical procedure. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones. Reviewed by 43
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-OOIF Project: YANK01204 Sample ID: 177540001 Client ID: YANKOOl Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 29.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A¶ Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0168 +/-0.0162 0.0147 +/-0.0162 0.0314 pCi/g KSDI 12/21/06 1601 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 72 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 72 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
44
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-001F Proiect: YANK01204 Sample ID: 177540001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 45
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-002F Project: YANK01204 Sample ID: 177540002 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 28.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0128 +/-0.0177 0.0162 +/-0.0177 0.036 pCi/g KSDI 12/21/06 1601 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 80 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 80 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 46
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-002F Project: YANKO01204 Sample ID: 177540002 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 47
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-003F Project: YANK01204 Sample ID: 177540003 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 32.4% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.042 +/-0.0207 0.0136 +/-0.0208 0.0304 pCi/g KSDI 12/22/06 1204 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 72 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 72 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
48
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-003F Project: YANK01204 Sample ID: 177540003 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 49
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-004F Project: YANK01204 Sample ID: 177540004 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 42% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0319 +/-0.0236 0.017 +/-0.0236 0.0376 pCi/g KSDI 12/22/06 1204 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 59 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 59 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 50
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-004F Project: YANK01204 Sample ID: 177540004 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 51
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-005F Project: YANK01204 Sample ID: 177540005 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 38.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I Rad Gas Flow Proportional Counting GFPC,S90, solid-ALL FSS Strontium-90 U 0.0179 +/-0.0179 0.0133 +/-0.0179 0.0296 pCi/g KSD1 12/22/06 1204 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 73 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 73 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 52
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analiwis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-005F Project: YANK01204 Sample ID: 177540005 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 53
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-006F Project: YANK01204 Sample ID: 177540006 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 44.9% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.159 +/-0.0263 0.012 +/-0.0266 0.0264 pCi/g KSD1 12/22/06 1204 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery % Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 88 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 88 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 54
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-006F Project: YANK0 1204 Sample ID: 177540006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1l U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 55
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-009F Project: YANKO 1204 Sample ID: 177540007 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12.7% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.000197 +/-0.0178 0.0149 +/-0.0178 0.0327 pCi/g KSDI 12/21/06 1602 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 82 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 82 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
56
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-009F Proiect: YANK01204 Sample ID: 177540007 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 57
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-010F Project: YANKO 1204 Sample ID: 177540008 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 29.2% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.0288 +/-0.0241 0.0173 +/-0.0241 0.0388 pCi/g KSDI 12/21/06 1608 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 74 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 74 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-OIOF Proiect: YANK01204 Sample ID: 177540008 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 59
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-01iF Project: YANK01204 Sample ID: 177540009 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 18.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.00662 +/-0.0149 0.0131 +/-0.0149 0.0289 pCi/g KSD1 12/22/06 1204 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery % Acceptable Limits Strontium-90 GFP,C, Sr90, solid-ALL FSS 80 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 80 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
60
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-01IF Project: YANKO 1204 Sample ID: 177540009 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 61
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-012F Proiect: YANK01204 Sample ID: 177540010 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,SO9O, solid-ALL FSS Strontium-90 0.037 +/-0.0177 0.0118 +/-0.0177 0.026 pCi/g KSDl 12/22/06 1204 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 88 (25%-I 25%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 88 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
62
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-012F Project: YANKO01204 Sample ID: 177540010 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 63
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-013F Proiect: YANK01204 Sample ID: 177540011 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 10.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.0335 +/-0.0235 0.0139 +/-0.0235 0.0343 pCi/g KSDI 12/21/06 1658 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 81 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 81 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more 64
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-013F Project: YANK01204 Sample ID: 177540011 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch N R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 65
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-015F Project: YANK01204 Sample ID: 177540012 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 09-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 12% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.000807 +/-0.0199 0.0166 +/-0.0199 0.0381 pCi/g KSDI 12/21/06 1658 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 66
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-015F Project: YANK01204 Sample ID: 177540012 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 67
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-016F Project: YANK01204 Sample ID: 177540013 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 15-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 23.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.00289 +/-0.0178 0.0153 +/-0.0178 0.0354 pCi/g KSDI 12/21/06 1859 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 105 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 105 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 68
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-016F Project: YANK01 204 Sample ID: 177540013 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch I% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UL Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 69
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-021-I Project: YANK01204 Sample ID: 177540014 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 16-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 16.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0164 +/-0.0169 0.0112 +/-0.0169 0.0275 pCi/g KSD1 12/21/06 1859 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 100 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 100 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
70
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-021-1 Project: YANK01204 Sample ID: 177540014 Client ID: YANKOO I Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 71
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-024-I Proiect: YANK01204 Sample ID: 177540015 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 21-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 44.9% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.026 +/-0.0185 0.0119 +/-0.0185 0.0281 pCi/g KSDI 12/22/06 1205 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 105 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 105 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 72
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0001-024-I Proiect: YANKO1204 Sample ID: 177540015 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 73
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-002F Proiect: YANKO 1204 Sample ID: 177540016 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 18.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0095 +/-0.0171 0.0158 +/-0.0171 0.0366 pCi/g KSDI 12/21/06 1859 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 104 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 104 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 74
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-002F Proiect: YANKO 1204 Sample ID: 177540016 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 75
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-003F Project: YANK0 1204 Sample ID: 177540017 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 14.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.00348 +/-0.0155 0.0125 +/-0.0155 0.0292 pCi/g KSDI 12/22/06 1205 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 107 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 107 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 76
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-003F Project: YANK01204 Sample ID: 177540017 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch N U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 77
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-005F Project: YANK01204 YANK001 Sample ID: 177540018 Client ID: Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 17.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,SO9O, solid-ALL FSS Strontium-90 U 0.0267 +/-0.0237 0.0168 +/-0.0237 0.0384 pCi/g KSDI 12/21/06 1900 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 109 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 109 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 78
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-005F Project: YANK01204 Sample ID: 177540018 Client ID: YANKO01 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 79
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-007F Project: YANK01204 Sample ID: 177540019 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 20.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.00433 +/-0.0171 0.0137 +/-0.0171 0.0322 pCi/g KSDI 12/21/06 1900 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 107 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 107 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 80
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-007F Project: YANKO 1204 Sample ID: 177540019 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 81
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-008F Proiect: YANKO01204 Sample ID: 177540020 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 28.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0235 +/-0.0229 0.0164 +/-0.0229 0.0375 pCi/g KSD1 12/21/06 1900 597316 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1340 595082 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified 2 EPA 905.0 Modified 3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 107 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 107 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected 82
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-008F Project: YANK01204 Sample ID: 177540020 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 83
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-OIOF Project: YANKO 1204 Sample ID: 177540021 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 9.97% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.0584 +/-0.0287 0.0155 +/-0.0288 0.0374 pCi/g KSDI 12/15/06 1439 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 72 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 72 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification 84
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-01OF Project: YANK01204 Sample ID: 177540021 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch \ X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 85
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-011F Proiect: YANK01204 Sample ID: 177540022 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 20.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0187 +/-0.0244 0.021 +/-0.0244 0.0433 pCi/g KSDI 12/15/06 1823 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 65 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 65 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 86
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-011F Project: YANK01204 Sample ID: 177540022 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 87
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-012F Project: YANK01204 Sample ID: 177540023 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 23% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0332 +/-0.0184 0.018 +/-0.0184 0.0387 pCi/g KSDI 12/15/06 1823 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 65 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 65 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 88
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-012F Proiect: YANKO 1204 Sample ID: 177540023 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 89
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-013F Project: YANK01204 Sample ID: 177540024 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 22.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.0663 +/-0.0236 0.0154 +/-0.0237 0.0335 pCi/g KSDI 12/15/06 1823 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 90
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-013F Project: YANK01204 Sample ID: 177540024 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 91
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-014F Project: YANK01204 Sample ID: 177540025 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 22.7% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,SO9O, solid-ALL FSS Strontium-90 0.122 +/-0.0325 0.0134 +/-0.0327 0.0319 pCi/g KSDl 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 92
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-014F Project: YANK01204 Sample ID: 177540025 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 93
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-016F Project: YANK01204 Sample ID: 177540026 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 30-OCT-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 42.8% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1 Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.0131 +/-0.0182 0.0139 +/-0.0182 0.0311 pCi/g KSD1 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 79 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 79 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 94
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0002-016F Proiect: YANK01204 Sample ID: 177540026 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 95
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-OO1F Project: YANK01204 Sample ID: 177540027 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 5.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0111 +/-0.0195 0.0156 +/-0.0195 0.0337 pCi/g KSDI 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 96
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-001F Proiect: YANK01204 Sample ID: 177540027 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 97
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-002F Proiect: YANK01204 Sample ID: 177540028 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 8.78% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.121 +/-0.0277 0.0158 +/-0.028 0.0344 pCi/g KSD1 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 74 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 74 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 98
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-002F Proiect: YAN K01204 Sample ID: 177540028 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 99
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-003F Project: YANK01204 Sample ID: 177540029 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 19.8% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.0478 +/-0.0239 0.0163 +/-0.024 0.0359 pCi/g KSD1 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 69 (25%- 125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 69 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 100
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-003F Project: YANKO 1204 Sample ID: 177540029 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 101
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-004F Proiect: YANK01204 Sample ID: 177540030 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 19.6% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A! Rad Gas Flow Proportional Counting GFPC,SO9O, solid-ALL FSS Strontium-90 0.0504 +/-0.0263 0.0167 +/-0.0263 0.038 pCi/g KSDI 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery % Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 63 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 63 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 102
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-004F Project: YANKO 1204 Sample ID: 177540030 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 103
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-005F Proiect: YANK01204 Sample ID: 177540031 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 9.28% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.0377 +/-0.0217 0.0146 +/-0.0217 0.0327 pCi/g KSDI 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification 104
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-005F Proiect: YANK01204 Sample ID: 177540031 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 105
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-007F Proiect: YANK01204 Sample ID: 177540032 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 19.4% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.0227 +/-0.0165 0.0153 +/-0.0165 0.0328 pCi/g KSD1 12/15/06 1824 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 77 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 77 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 106
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-007F Proiect: YANK01204 Sample ID: 177540032 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch IN Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 107
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-008F Proiect: YANK01204 Sample ID: 177540033 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 03-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 26.9% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.0447 +/-0.0138 0.0102 +/-0.0139 0.0212 pCi/g KSDI 12/15/06 1929 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 73 (25%- 125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 73 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 108
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-008F Project: YANKO 1204 Sample ID: 177540033 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 109
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-009F Project: YANK01204 Sample ID: 177540034 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 10.9% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.024 +/-0.0122 0.00949 +/-0.0122 0.0197 pCi/g KSD1 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 74 (25%-125%) Carrier/Tracer Recovery GFP SC, r90, solid-ALL FSS 74 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 110
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-009F Project: YANK01204 Sample ID: 177540034 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 1il
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-01OF Project: YANK01204 Sample ID: 177540035 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 4.79% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.00579 +/-0.0111 0.00953 +/-0.0111 0.0198 pCi/g KSD1 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 72 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 72 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 112
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-OIOF Project: YANK01204 Sample ID: 177540035 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 113
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-011F Project: YANK01204 Sample ID: 177540036 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 8.03% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.00757 +/-0.0129 0.0111 +/-0.0129 0.0229 pCi/g KSDI 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 73 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 73 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 114
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-011F Project: YANK01204 Sample ID: 177540036 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 115
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-012F Proiect: YANK01204 Sample ID: 177540037 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 12.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0083 +/-0.0114 0.00982 +/-0.0114 0.0204 pCi/g KSD1 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB] 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 116
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-012F Project: YANKO 1204 Sample ID: 177540037 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 117
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-013F Project: YANK01204 Sample ID: 177540038 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 14.2% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.00789 +/-0.00969 0.00786 +/-0.00969 0.0163 pCi/g KSDI 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 87 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 87 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 118
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-013F Project: YANK01204 Sample ID: 177540038 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +I-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 119
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-014F Proiect: YANKO 1204 Sample ID: 177540039 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 4.71% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.0145 +/-0.0102 0.0091 +/-0.0102 0.0189 pCi/g KSDI 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI1 12/12/06 1237 595084 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 120
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-014F Project: YANK01204 Sample ID: 177540039 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 121
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-015F Proiect: YANKO01204 Sample ID: 177540040 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 06-NOV-06 Receive Date: 10-NOV-06 Collector: Client Moisture: 4.81% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.00651 +/-0.0168 0.0142 +/-0.0168 0.0292 pCi/g KSDI 12/15/06 1928 595174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1237 595084 The following Analytical Methods were performed Method Description EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery % Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 82 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 82 (25%-125%) Notes: The.Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 122
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0003-015F Project: YANK01204 Sample ID: 177540040 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 123
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr, Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-001F Project: YANK01204 Sample ID: 177540041 Client ID: YANKOO Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 6.28% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0197 +/-0.0223 0.017 +/-0.0224 0.0375 pCi/g KSD1 12/19/06 1849 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP SC, r90, solid-ALL FSS 72 (25%-125%) Carrier/Tracer Recovery GFP, SC,r90, solid-ALL FSS 72 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
124
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analvsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-001F Proiect: YANKO 1204 Sample ID: 177540041 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 125
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-002F Project: YANKO 1204 Sample ID: 177540042 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 3.79% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 0.0804 +/-0.0265 0.0163 +/-0.027 0.0358 pCi/g KSDI 12/19/06 1849 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 77 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 77 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
126
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-002F Project: YANKO01204 Sample ID: 177540042 Client ID: YANKO01 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 127
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-003F Project: YANK01204 Sample ID: 177540043 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 3.6% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0236 +/-0.0222 0.0167 +/-0.0223 0.0367 pCi/g KSDI 12/18/06 1819 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP C, Sr90, solid-ALL FSS 77 (25%-125%) Carrier/Tracer Recovery GFP C, Sr90, solid-ALL FSS 77 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
128
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-003F Proiect: YANK01204 Sample ID: 177540043 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 129
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-005F Project: YANK01204 Sample ID: 177540045 Client ID: YANK00I Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 5.44% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0234 +/-0.0195 0.017 +/-0.0195 0.0349 pCi/g KSDI 12/14/06 2006 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP( Sr90, S, solid-ALL FSS 68 (25%-125%) Carrier/Tracer Recovery GFP( Sr90, solid-ALL FSS 68 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 130
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-005F Project: YANK01204 Sample ID: 177540045 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1 Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 131
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-006F Project: YANK0 1204 Sample ID: 177540046 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 4.7% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.00284 +/-0.0147 0.0123 +/-0.0147 0.0253 pCi/g KSDI 12/15/06 1854 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 77 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 77 (25%-1 25%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 132
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-006F Project: YANK01204 Sample ID: 177540046 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch N Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 133
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-008F Project: YANK01204 Sample ID: 177540047 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 6.58% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A% Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0368 +/-0.0239 0.0174 +/-0.024 0.0378 pCi/g KSDI 12/18/06 1819 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP( ", Sr90, solid-ALL FSS 77 (25%-125%) Carrier/Tracer Recovery GFP(1, Sr90, solid-ALL FSS 77 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
134
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-008F Proiect: YANK01204 Sample ID: 177540047 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1l UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 135
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-009F Project: YANK01204 Sample ID: 177540048 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 9.4% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0343 +/-0.024 0.0182 +/-0.0241 0.0388 pCi/g KSDI 12/15/06 0844 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFP( Or90, solid-ALL FSS 76 (25%-125%) Carrier/Tracer Recovery GFP( Or90, solid-ALL FSS 76 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 136
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-009F Proiect: YANKO 1204 Sample ID: 177540048 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 137
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-01 OF Proiect: YANK01204 Sample ID: 177540049 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 5.53% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,SO9O, solid-ALL FSS Strontium-90 U 0.019 +/-0.025 0.020 +/-0.0251 0.0424 pCi/g KSDI 12/15/06 0844 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 75 (25%-125%) Notes: The Qualifiers in this report are defined as follows
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 138
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-01OF Project: YANKO 1204 Sample ID: 177540049 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 139
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-01IF Proiect: YANKO01204 Sample ID: 177540050 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 8.26% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 0.0296 +/-0.0187 0.0131 +/-0.0188 0.029 pCi/g KSDI 12/18/06 1819 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 87 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 87 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
140
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-01IF Proiect: YANK01204 Sample ID: 177540050 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 141
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-012F Proiect: YANK01204 Sample ID: 177540051 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 68.2% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Rad Gas Flow Proportional Counting GFPC,SO9O, solid-ALL FSS Strontium-90 U 0.0196 +/-0.024 0.019 +/-0.024 0.0405 pCi/g KSDl 12/15/06 0817 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 83 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 83 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 142
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-012F Project: YANK01204 Sample ID: 177540051 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 143
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-013F Project: YANK01204 Sample ID: 177540052 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 78.5% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1I Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U -0.00038 +/-0.0211 0.0177 +/-0.0211 0.0385 pCi/g KSD1 12/18/06 1819 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 79 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 79 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
144
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-013F Proiect: YANK01204 Sample ID: 177540052 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 145
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-014F Project: YANK01204 Sample ID: 177540053 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 51.1% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A* Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.0195 +/-0.0171 0.0138 +/-0.0171 0.0284 pCi/g KSD1 12/15/06 1854 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 12/12/06 1224 595086 The following Analytical Methods were performed Method Description 1 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 71 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 71 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 146
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-014F Project: YANKO 1204 Sample ID: 177540053 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 147
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-015F Proiect: YANK0 1204 Sample ID: 177540054 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 10.3% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Rad Gas Flow Proportional Counting GFPC,Sr9O, solid-ALL FSS Strontium-90 U 0.0359 +/-0.0237 0.0166 +/-0.0238 0.0369 pCi/g KSDI 12/18/06 1833 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery % Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 80 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 80 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
148
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-015F Proiect: YANK01204 Sample ID: 177540054 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 149
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-016F Project: YANK01204 Sample ID: 177540055 Client ID: YANK001 Matrix: TS Vol. Recv.: Collect Date: 22-NOV-06 Receive Date: 30-NOV-06 Collector: Client Moisture: 14.8% Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.00675 +/-0.0157 0.013 +/-0.0157 0.0268 pCi/g KSDI 12/15/06 1854 595177 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 12/12/06 1224 595086 The following Analytical Methods were performed Method Description I EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Strontium-90 GFPC, Sr90, solid-ALL FSS 68 (25%-125%) Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 68 (25%-125%) Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported > Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier 150
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis I Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: December 22, 2006
Contact:
Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9522-0004-016F Project: YANKO 1204 Sample ID: 177540055 Client ID: YANKOO I Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1% Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis. 151
QUALITY CONTROL DATA I 152
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Report Date: December 22, 2006 Client : Connecticut Yankee Atomic Power Page 1 of 2 362 Injun Hollow Rd East Hampton, Connecticut
Contact:
Mr. Jack McCarthy Workorder: 177540 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gas Flow Batch 595174 QC1201245013 177540021 DUP Strontium-90 0.0584 0.141 pCilg 83* (0% - 100%) KSD1 12/15/06 14:39 Uncert: +/-0.0287 +/-0.0374 TPU: +/-0.0288 +/-0.0375 QC12o1245015 LCS Strontium-90 1.58 1.68 pCi/g 107 (75%-125%) 12/15/06 20:06 Uncert: +/-0.153 TPU: +1-0.161 QC1201245012 MB Strontium-90 U -0.0237 pCi/g 12/15/06 19:33 Uncert: +/-0.0106 TPU: +/-0.0106 QC1201245014 177540021 MS Strontium-90 5.15 0.0584 5.07 pCi/g 97 (75%-125%) 12/15/06 20:06 Uncert: +/-0.0287 +/-0.459 TPU: +/-0.0288 +/-0.482 Batch 595177 QC1201245021 177540041 DUP Strontium-90 U 0.0197 U -0.00914 pCi/g 0 (0% - 100%) KSD1 12/18/06 14:48 Uncert: +/-0.0223 +/-0.0185 TPU: +/-0.0224 +/-0.0185 QC1201245023 LCS Strontium-90 1.58 1.58 pCi/g 100 (75%-125%) 12/14/06 17:39 Uncert: +/-0.121 TPU: +/-0.250 QC 1201245020 MB Strontium-90 U 0.00173 pCi/g 12/18/06 18:33 Uncert: +/-0.0167 TPU: +/-0.0167 QC1201245022 177540041 MS Strontium-90 4.92 U 0.0197 5.26 pCi/g 107 (75%-125%) 12/15/06 08:09 Uncert: +/-0.0223 +/-0.360 TPU: +/-0.0224 +/-0.483 Batch 597316 QC1201250080 177540001 DUP Strontium-90 U -0.0168 0.0309 pCi/g 2 (0% - 100%) KSD1 12/22/06 12:05 Uncert: +/-0.0162 +/-0.0186 TPU: +/-0.0162 +/-0.0186 QC1201250082 LCS Strontium-90 1.46 1.43 pCi/g 98 (75%-125%) 12/21/06 20:14 Uncert: +/-0.0938 TPU: +/-0.102 QC1201250079 MB Strontium-90 U -0.00679 pCilg 12/21/06 19:01 153
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 177540 Page 2 of 2 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Rad Gas Flow Batch 597316 Uncert: +/-0.0159 TPU: +/-0.0159 QC1201250081 177540001 MS Strontium-90 4.25 U -0.0168 3.52 pCi/g 83 (75%-125%) 12/21/06 20:14 Uncert: +/-0.0162 +/-0.245 TPU: +/-0.0162 +/-0.257 Notes: The Qualifiers in this report are defined as follows:
- A quality control analyte recovery is outside of specified acceptance criteria
< Result is less than value reported
> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
** Indicates analyte is a surrogate compound.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. 154
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 4 (DQA RESULTS) Revision 0
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 4A (PRELIMINARY DATA REVIEW) Revision 0
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) PRELIMINARY DATA REVIEW SURVEY UNIT 9522-0001 RELEASE RECORD Attachment 4 Survey Unit: 9522-0001 Area Description Southeast Grounds (non-protected) Classification 2 Survey Media Surface Soils Type of Survey Final Status Survey Number of Measurements 15 Static, 8 Investigative STATISTICS on TOTAL STATISTICS on NON-POPULATION PARAMETRIC POPULATION Cs-137 Co-60 Sr-90 Cs-137 Co-60 Sr-90 DCGLop (pCi/g): 5.38E+00 2.59E+00 1.05E+00 DCGLop (pCilg): 5.38E+00 2.59E+00 1.05E+00 Minimum Value: 0.OOE+00 -1.47E-02 -1.28E-02 Minimum Value: 2.77E-02 -7.76E-03 -1 .28E-02 Maximum Value: 3.08E+00 5.70E-02 7.66E-01 Maximum Value: 3.08E+00 5.70E-02 7.66E-01 Mean: 4.20E-01 1.29E-02 7.65E-02 Mean: 5.70E-01 1.32E-02 7.65E-02 Median: 1.70E-01 1.18E-02 2.88E-02 Median: 2.91E-01 1.15E-02 2.88E-02 Standard Deviation: 6.49E-01 1.75E-02 1.95E-01 Standard Deviation: 7.72E-01 1.90E-02 1.95E-01 DCGLýr (pCi/g): 2.80E+00 Nuclide Distribution: 0.841 0.008 0.151 Cs-137 Co-60 Sr-90 GPS Coordinates1r 1T Sample ID North East Result (pCilg) 2o I MDA (pCilg) Identified Result (PCilg) j 2a j MDA (pCilg) Identified Result tpcilg) 20 MDA (pCilg) Identified Fraction of DCGL 9522-0001-OOIF 236516.39 669283.45 6.77E-01 0.098 5.13E-02 + -1.86E-04 0.028 5.31E-02 1.68E-02 0.016 3.14E-02 + 0.142 9522-0001-002F 236516.39 669359.45 6.66E-01 0.068 6.OOE-02 + 2.40E-02 0.029 6.07E-02 -1 28E-02 0.018 3.60E-02 0.121 9522-0001-003F 236450.56 669321,45 1.17E+00 0.117 7.77E-02 + -2.28E-03 0055 9.96E-02 4.20E-02 0.021 3.04E-02 + 0.257 9522-0001-004F 236450.56 669397.46 6.37E-01 0.060 2.75E-02 + 2.27E-02 0.016 3.09E-02 + 3.19E-02 0.024 3.76E-02 + 0.158 9522-0001-005F
. ... 236384.73 669283.45 . . . ....... ..
8.24E-01 ....0.106
. . ...4.89E-02
. ...... ....... ..+ . .. .... 5.08E-02 .... . .... . . .....
0.026 . .. ................... 605E02 ....
+ . .....................
1.79E-02 ......... ............. 0018 ....... 2.96E-02 ................................
+ 0.190 9522-0001-006F 236384.73 669359.45 3.08E+00 0.251 4.34E-02 + 5.70E-02 0.047 3.99E-02 + 1.59E-01 0.026 2.64E-02 + 0.746 9522-0001-008F 236318.91 669397.46 2.23E-01 0.038 3.09E-02 + 3.85E-03 0.020 3.91E-02 3.61E-02 0.031 4.95E-02 + 0.077 9522-0001-009F 236253.08 669283.45 1.16E-01 0.034 3.53E-02 + -3.91E-03 0.020 3.73E-02 i 1.97E-04 0.018 3.27E-02 0.020 9522-0001-001OF 236253.08 669359.45 2.39E-01 0.041 4.OOE-02 + -7.76E-03 0.023 3.43E-02 2.88E-02 0.024 3.88E-02 + 0.069 REVISION Page I of 2
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) PRELIMINARY DATA REVIEW SURVEY UNIT 9522-0001 RELEASE RECORD Attachment 4 Cs-137 Co-60 Sr-90 GPS CoordinatesrTI Sample ID Result MDA Result IMDA Result MDA _ _ _ _____ _ _ _ _ _ _____ _ _ 2__ _ _ _ ___[Identified _____I 2ci I Identified 20j Identified Fraction North East (pCilg) (pCi/g) (pCi/g) (pCi/g) (pCi/g) (pCi/g) of DCGL 9522-0001-0011F 236253.08 669435.46 1.17E-01 0.031 3.63E-02 + 1.32E-02 0.022 4.28E-02 -6.62E-03 0.015 2.89E-02 0.021 9522-0001-0012F ............................... 236187.25 . ....................................................... 669245.44 ...............................
...............................5.04E-02 i...............................
0.044 3.93E-02 i...............................................................
............................... + 1.22E-02 . 0.023
. 4.60E-02 ...............................
............................... 3.70E-02
....... 0.018
................................ 2.60E-02
. + 0.049 9522-0001-0013F *...............................
236187.25 *'............................... 669321.45 ............................... 2.77E-02 i............................... 0.022 i.................... 4.74E-02 ... ....i ...........................
+ .................................
3.35E-03 r............................... 0.025 r'...............................' 4 98E-02 .............................................................. 3.35E-02 ............................... 0.024 ............................ 3 43E-02 .......
+ 0.038 9522-0001-0014F 236187.25 669397.46 2.91E-01 0.064 i E-02 + 0.00E+00 0016 267E-02 7.66E-01 0116 7 19E-02 +
0.784 9522-0001-0015F 236121.43 669359.45 4.11E-02 0.045 8.57E-02 1.38E-02 0.045 8.44E-02 8.07E-04 0.020 3.81E-02 0.014 9522-0001-0016F 236308.33 669394.58
...................... . ....a..........................
3.89E-01 0.049 3.63E-02 + 1.15E-02 0.043 3.89E-02 -2.89E-03 0.018 3.54E-02 0.074
*. .. .............................. . . . ......................... ... .......................... .................... ........ 2..................... . ...... i ............................ ..............................2.............................. 2............ .................i .....
9522-0001-009FS ... ............. . ............................ 236253.08 i............... 669283.45 ..........
..... .....................................- 1.01E-01
................... 0.035
............. 3.16E-02 ..."..............................
........ ............................... + 6.98E-03
............................. 0.028
.-............................... 3.84E-02
................ . ..............................". .......................... 0.021 9522-0001-0017-1 I 236136.88 669384.53 0.OOE+00 0.048 4 51E-02 1.28E-02 0.030 5 01E-02 0.005
- 9522-0001-0018-1 236124.11 669364.90 8.04E-02 0.048 5.56E-02 + 1.20E-02 0.031 4.24E-02 0.033
- 9522-0001-00192 - 236093.52 669367.74 4.95E-02 0.042 4.99E.02 + 4.30E-02 0.043 5.23E 02 + 0.034
- 9522-0001-0020-1 236106.07 669351.31 3.56E-02 0.019 2.67E.02 + 4.71 E-03 0.014 2.82E.02 0.015
- 9522-0001-0021 I 236255.72 669254.25 5.19E-01 0063 3.27E.02 + 2.53E-02 0.019 3.82E- 02 0.195 *
..... 22....... oo2.... ,.................8.6......6...............
236251.53 ...................... 669261.17 6.53E-02 ...................... 3...................... 0............................ .................. ................. 9522-0001-0022-1 9522-0001-0023- i 236246.3 6 66926980 5.50E-02 0.024 0.030 3.28E-02 4.23E.02
+
+
... 1.79E-02 47E-
-. 02:
0.018 0023 3.49E-02 3.86E-02
+
........ 0.030 0.014 9522-0001-0024-1 236414.93 669427.88 6.30E-01 0.062 4.24E-02 + 4.35E-03 0.026 4.68E-02 0.227 *
- The Operational DCGL for Cs-1 37 has been adjusted to 2.80 pCi/g as a surrogate to account for the potential presence of HTD radionuclide Sr-90.
OTHER RADIONUCLIDES Result 1[ MDA 1[DCGLo* Fraction Isotope R 2a j Identified i Sample ID (pci/g) (pCi/g) (pci/g) of DCGL 9522-0001-008F jPu-241 i 1.10E+01 8.260 1.35E+01i + 5.9E+02 0.02
. .... .. . 4...E.............................
-. ..................................... . ... ....................... . ............................. .... ................................................ . .............................. 0......................
0.......................... 95200-1FTc-99 1.94E-01i 0.161 i2.68E-01i 8.6E÷00 0.OO2 REVISION 0 Page 2 of 2
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 4B (GRAPHICAL REPRESENTATION OF DATA) Revision 0
QUANTILE PLOT FOR CESIUM-137 Survey Unit: 9522-0001 Survey Unit Name: Southeast Site Grounds (non-protected area) Mean: 5.70E-01 pCi/g Quantile Plot For Cs-137 3.50E+00 3.00E+00 -
*0 2.50E+00
" 2.00E+00 0
.2
-,,1.50E+00 o0 1.00E+00 U U U 5.OOE-01 - --- -
0.00E+00 " u.! 0 20 40 60 80 100 Percentage Cs- 137 Rank Percentage 2.77E-02 1 3.3% 4.11E-02 2 10.0% 5.04E-02 3 16.7% 1.16E-01 4 23.3% 1.17E-01 5 30.0% 2.23E-01 6 36.7% 2.39E-01 7 43.3% 2.91E-01 8 50.0% 3.89E-01 9 56.7% 6.37E-01 10 63.3% 6.66E-01 11 70.0% 6.77E-01 12 76.7% 8.24E-01 13 83.3% 1.17E+00 14 90.0% 3.08E+00 15 96.7% itte by/Date Revieweftby/Date
FREQUENCY PLOT FOR CESIUM-137 Survey Unit: 9522-0001 Survey Unit Name: Southeast Site Grounds (non-protected area) Mean: 5.70E-01 pCi/g Frequency Plot For Cs-137 10 8 6 U.) 4 2 0 5.36E-01 1.05E+00 1.55E+00 2.06E+00 2.57E+00 3.08E+00 Upper End Value (pCilg) Upper End Observation Observation Value Frequency Frequency 5.36E-01 9 60% 1.05E+00 4 27% 1.55E+00 0 7% 2.06E+00 0 0% 2.57E+00 0 0%
' .08E+00 1 7%
Total: 15 100% WdJI~e VJ0I Su flted ylDate Re wýed by/Date 1 of 1
QUANTILE PLOT FOR STRONTIUM-90 Survey Unit: 9522-0001 Survey Unit Name: Southeast Site Grounds (non-protected area) Mean: 7.65E-02 pCi/g Quantile Plot For Sr-90 9.OOE-01 8.OOE-01 7.OOE-01 6.OOE-01 5.OOE-01 U 4.OOE-01 _* .I * * *U C
- 0) 3.OOE-01 0
2.OOE-01 1.OOE-01 0.00E+00 0 20 40 60 80 100 Percentage Sr-90 Rank Percentage
-1.28E-02 1 3.3%
-6.62E-03 2 10.0%
-2.89E-03 3 16.7%
1.97E-04 .4 23.3% 8.07E-04 5 30.0% 1.68E-02 6 36.7% 1.79E-02 7 43.3% 2.88E-02 8 50.0% 3.19E-02 9 56.7% 3.35E-02 10 63.3% 3.61 E-02 11 70.0% 3.70E-02 12 76.7% 4.20E-02 13 83.3% 1.59E-01 14 90.0% 7.66E-01 15 96.7%
-/8)0-7 Smitt by/Date Revi(!ýo by/Date d Ile1ýd ý L
FREQUENCY PLOT FOR STRONTIUM-90 Survey Unit: 9522-0001 Survey Unit Name: Southeast Site Grounds (non-protected area) Mean: 7.65E-02 pCi/g Frequency Plot For Sr-90 14 12 10 C.) 8 2 0_ 6 4 2 0 1.17E-01 2.47E-01 3.77E-01 5.06E-01 6.36E-01 7.66E-01 Upper End Value (pCi/g) Upper End Observation Observation Value Frequency Frequency 1.17E-01 13 87% 2.47E-01 1 7% 3.77E-01 0 0% 5.06E-01 0 0% 6.36E-01 0 0% 7.66E-01 1 7% Total: 15 100% I . V3 W< Sub itted by/D te ewed- by/Date 1o 1 of 1
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 4C (SIGN TEST) Revision 0
Connecticut Yankee Decommissioning Project GPP-GGGR-R5121-001 Attachment B, Health Physics Procedure Rev.CY-001 MAJOR Sign Test Calculation Sheet for Multiple Radionuclides Survey Area Number: 9522 Survey Unit Number: 0001 WPIR #: 2006-0047 Survey Area Name: Southeast Site Grounds Classification: 2 TYPE I (a error): 0.05 IN: 15 (non-protected area) Radionuclides: 1 st Radionuclide 2nd Radionuclide 3rd Radionuclide 4 th Radionuclide Cs-1 37 Co-60 Sr-90 DCGL: 5.38E+00 2.59E+00 1.05E+00 Results 1 st Results 2 nd Results 3 rd Results 4 th Weighted Sum 1-Ws Sign Radionuclide Radionuclide Radionuclide Radionuclide (W.) (pCi/g) (pCi/g) (pCi/g) (pCi/g) 6.77E-01 -1.86E-04 1.68E-02 0.14 0.86 +1 6.66E-01 2.40E-02 -1.28E-02 0.12 0.88 +1 1.17E+00 -2.28E-03 4.20E-02 0.26 0.74 +1 6.37E-01 2.27E-02 3.19E-02 0.16 0.84 +1 8.24E-01 5.08E-02 1.79E-02 0.19 0.81 +1 3.08E+00 5.70E-02 1.59E-01 0.75 0.25 +1 2.23E-01 3.85E-03 3.61 E-02 0.08 0.92 +1 1.16E-01 -3.91 E-03 1.97E-04 0.02 0.98 +1 2.39E-01 -7.76E-03 2.88E-02 0.07 0.93 +1 1.17E-01 1.32E-02 -6.62E-03 0.02 0.98 +1 5.04E-02 1.22E-02 3.70E-02 0.05 0.95 +1 2.77E-02 3.35E-03 3.35E-02 0.04 0.96 +1 2.91E-01 0.OOE+00 7.66E-01 0.78 0.22 +1 4.11 E-02 1.38E-02 8.07E-04 0.01 0.99 +1 3.89E-01 1.15E-02 -2.89E-03 0.07 0.93 +1 Number of positive differences (S+) 15 Critical Value 11 Survey Unit Meets the Acceptance Criteria Performed by: David Wojtkowiak, Date: 1/8/2007 Independent Review by: i/j* ] - ""Date: Page 1 of 1
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 4D (QC SPLIT RESULTS) Revision 0
Health Physics Procedure 24265-000-GPP-GGGR-R5124-000-Rev.CY-000 Attachment A Split Sample Assessment Form Survey Area #: 9522 Survey Unit # 0001 Survey Unit Name: Southeast Site Grounds (non-protected area) Sample Plan or WPIR#: 2006-0047 SML#: 9522-0001-009 Sample
Description:
Comparison of split samples collected from sample measurement location #9 and analyzed using gamma spectroscopy by off-site Vendor Laboratory. The standard sample was 9522-0001-009F, the comparison sample was 9522-0001-009FS. STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable Value Error Range Value Error Ratio (Y/N) Cs-137 1.16E-01 0.017 7 0.5-2.0 1.01E-01 0.018 0.87 Y Comments/Corrective Actions: None Table is provided to show acceptance criteria used to assess split samples. Rcpupn Agreement Range 4-7 0.5-20 8-15 0.6-166 16-50 075 -1.33 51 -200 0.80 - 1.25
>200 0.85- 1.18 Perfued by: D. ojtkowiak Date: Reveiwed by: ,- ./1 Date:
,__1/4/20071
?
ýIj Page I of I
SOUTHEAST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9522-0001 RELEASE RECORD ATTACHMENT 4E (COMPASS DQA WITH POWER CURVE) Revision 0
DQA Surface Soil Report Assessment Summary Site: Southeast Grounds (non-protected area) 2 Planner(s): Wojo Survey Unit Name: 9522-0001 Report Number: 1 Survey Unit Samples: 15 Reference Area Samples: 0 Test Performed: Sign Test Result: Not Performed Judgmental Samples: 0 EMC Result: Not Performed Assessment
Conclusion:
Reject Null Hypothesis (Survey Unit PASSES) Retrospective Power Curve 1 0.9 0.8 -I __ U -I 0.7
- i -
3- 0.6 - I - ____ C, 0.5
-I - -
-I _-
0.4 -I - - ____ ____ 0.3 e 0.2 -I-- --- 0.1 E 0 0.0 02 0.4 0.6 0.8 1.0 1.2 Unity Rule Sum-ogfRatlis, including background Prospective Power U 1-beta .... Actual Power
- LBGR - - Estimated Power
'DCGL -- - Retrospective Power COMPASS vI.0.0 118/82007 Page 1
NORTHWEST SITE GROUNDS (NON-PROTECTED AREA) SURVEY UNIT 9512-0000 RELEASE RECORD ATTACHMENT 4E (COMPASS POWER CURVE) Revision 0
DQA Surface Soil Report Assessment Summary Site: 9512-0000 Planner(s): Arthur L. Hammond Survey Unit Name: Northwest site Grounds (Non-Protected Area) Report Number: 1 Survey Unit Samples: 15 Reference Area Samples: 0 Test Performed: Sign Test Result: Not Performed Judgmental Samples: 0 EMC Result: Not Performed Assessment
Conclusion:
Reject Null Hypothesis (Survey Unit PASSES) Retrospective Power Curve
~1 10.9 II _________ q 00.8 0.7 II ___ ___ ___ if-
___ ___ ___ JL-t 0.6 'I ___ ___ ___ U ___ ___ ___ - - 0.4 0.3 'I ___ 02
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0 1 2 3 4 5 6 Sell Cramehmllm OCfg) Wmcuidu backgurawd
-- ProspxctivPowe U 1-bea -- Actual Power
-LemR- Estknatod Power
- DCG. . RetrowpctvePowe' COMPASS v1.0.0 2/15/2007 Page I}}