ML20198D308
| ML20198D308 | |
| Person / Time | |
|---|---|
| Site: | Farley  |
| Issue date: | 09/24/1984 |
| From: | HITTMAN NUCLEAR & DEVELOPMENT CORP. (SUBS. OF HITTMAN |
| To: | |
| Shared Package | |
| ML20198D286 | List: |
| References | |
| STD-P-05-003, STD-P-5-3, NUDOCS 8511120306 | |
| Download: ML20198D308 (18) | |
Text
- 3
'..- c -r
~1
.* + .de ,
' W "A Documsnt Number: Rev: Rav Date:
e HITIMAN NUCLEAR & STD-P-05-003 3 9-24-84 DEVELOPMENT O CORPORATION
Title:
Process Control Program for Incontainer Q Solidification of 4 to 20 Weight /ercent Boric Acid i
Prepared Reviewed g Director Manager Rev. Rev Date by by Engineering @
Services 0 1-5-82 & [b I
ECN-1 12-14-82 E.MDoak( , 2-263
(.
Director Proj ect QA Engr. Manager Manager 2 12-8-83 k-k-h su
[ 276 k-h . Rewrit*.ea 3 9-24-84 k 'z9f ', ,..;, g/f g j f ECN-6 L.- ,84-147 This docwnent supersedes STD-P<-05-007.
UNMMISQLlfDrfQ)py c or D
- dn*d nu. -
a unmum.
8511120306 850827' 38 PDR ADOCK 050 C)
HNDC-Ol(A) Page 1 of 12 L j
4 7) 1~~ r STD-P-05-003 Page 2 of 18
() PROCESS CONTROL PROGRAM FOR INCONTAINER SOLIDIFICATION OF 4 TO 20 WEIGHT PERCENT BORIC ACID 1.0 SCOPE This procedure is applicable to the solidification of 4 to 20 weight percent boric acid classified as either Class A Unstable or Stable, Class B or Class C wastes. Class A Unstable waste meets the minimum requirements under the NRC Criteria of 10CFR61.56, Waste Characteris-tics. Class A Stable waste meets the stability requirements of Class B and C wastes under the criteria of 10CFR61.56, Waste Characteristics as required by the state of South Carolina.
2.0 PURPOSE 2.1 The purpose of the Process Control Program (PCP) for the incon-tainer solidification of boric acid wastes is to provide a pro-gram which will . assure a solidified product which meets the requirements of 10CFR61.56, Waste Characteristics.
The program consists of three major steps:
2.1.1 Procedures for collecting and analyzing samples;
[)
2.1.2 Procedures for solidifying samples; ,
2.1.3 Criteria for process parameters for acceptance or rejec-tion as solidified waste.
1 2.2 This document shall be considered complete only when used in concert with the Westinghouse Hittman Nuclear Incorporated proce-dures for field solidification. This document describes the methodology for determining the acceptable ratios of waste, cement and additive that will result in an acceptable product for transportation and burial. The Solidification Data Sheet then converts these ratios into the recommended quantities of cement and additive that must be mixed with the waste.
3.0 COLLECTION AND ANALYSIS OF SAMPLES 3.1 General Requirements. -
3.1.1 As required by the Radiological Effluent Technical Specifications for PWR's and BRW's the PCP shall be used to verify the solidification of at least one representative test specimen from every tenth batch of each type of wet radioactive waste.
-(
' 4, 0 $ STD-P-05-003 Page 3 of 18 U,m k 3.1.2 For the purpose of the PCP a batch is defined as the quantity of waste required to fill a disposable liner with the appropriate quantity of waste prior to solidi-fication.
3.1.3 If any test specimen fails to solidify, the batch under test shall be suspended until such time as additional test specimens can be obtained, alternate solidification parameters can be determined in accordance with the Process Control Program, and a subsequent test verifies solidification. Solidification of the batch may then be resumed using the alternate selidification parameters determined.
3.1.4 If the initial test specimen from a. batch of waste fails to verify solidification, then representative test specimens shall be collected from each consecutive batch of the same type of wacte until three consecu-tive initial test specimens demonstrate solidification.
The Process Control Program shall be modified as re-quired to assure solidification of subsequent batches of waste.
3.1.5 For high activity wastes where the handling of samples g,
i _j could result in personnel radiation exposures which are inconsistent with the ALARA principle, representative non-radioactive samples will be tested. These samples should be as close as possible to the actual wastes' chemical properties.
3.2 Collection of Samples 3.2.1 Radiological Protection 3.2.1.1 Comply with applicable Radiation Work Permits.
3.2.1.2 Test samples which use actual waste shall be disposed of by placing in the solidified liner.
3.2.1.3 A Test Solidification Data Sheet will be maintained for each test sample solidified.
Each data sheet will contain pertinent infor-mation on the test sample and the batch l
t numbers of waste solidified based on each test sample.
3.2.2 Test Solidification Data Sheet -
The Test Solidification Data Sheet will contain perti-(d'"x nent information on the characteristics of the test
(- ,
- < STD-P-05-003
.,a
- Pagn 4 of 18
() sample solidified so as to verify solidification of subsequent batches of similar wastes without retesting.
3.2.2.1 The test sample data for boric acid waste will in-clude, but not necessarily be limited to, the type of waste solidified, percent solids, pH of waste, volume of sample, and the amount of oil in sample.
3.2.2.2 The Test Solidification Data sheet will include the Solidification Number, Liner Number, Waste Volume, and Date Solidified, for each batch solidified.
3.2.3 Collection of Samples 3.2.3.1 Evaporator bottoms shall be kept heated or re-
- heated to 100*F prior to testing.
3.2.3.2 Two samples shall be taken for solidification. If the radioactivity levels are too high to permit full size samples to be taken then smaller samples shall be taken with the results corrected accord-ingly. Sample sizes shall be determined by the plant Health Physics Staff.
~ 3.2.3.3 If possible, samples should be drawn at least two days prior to the planned waste solidification procedure to allow adequate time to complete the required testing and verification of solidifica-tion, and to allow for retesting if necessary.
Approximately 28 hours3.240741e-4 days <br />0.00778 hours <br />4.62963e-5 weeks <br />1.0654e-5 months <br /> are necessary to verify solidification.
3.2.3.4 If the sample is drawn from the liner, it should be i mixed for 10 minutes, or recirculated in the liner for at least three (3) volume changes prior to sampling to assure a representative sample.
3.2.3.5 If the contents of more than one tank are to be solidified in the same liner then representative samples of each tank should be drawn. The samples should be of such size that when mixed together they form samples of standard size as prescribed in Section 3.2.3.2. If the contents of a particu-lar tank represents x% of the total waste quantity to be solidified then the sample of that tank should be of such size to represent x% of the composite samples.
3.3 Analysis of Samples
('] This document only defines the parameters to be analyzed and not the methodology. This is left to the plant staff.
r L
7 -.
STD-P-05-003
] ,
Pege 5 of yg
- %,o ( !
() Parameter Acceptable 8* for 4 to 10 weight percent boric pH acid.
12* for >10 to 20 weight percent boric acid.
Detergents No appreciable foaming Oil <1%
~ *After addition of sodium hydroxide.
4.0 TEST SOLIDIFICATION AND ACCEPTANCE CRITERIA 4.1 Waste Conditioning 4.1.1 Prior to the test sample solidification, the pH of the sample shall be adjusted to 8 for 4 to 10 weight percent boric acid and to 12 for >10 to 20 weight percent boric acid.
4.1.2 It is recommended that 50 weight percent sodium by-droxide be used to adjust the pH. The amount of sodium hydroxide necessary for the pH adjustment shall be recorded on the Test Solidification Data Sheet.
4.1.3 It large_ (i.e. , foam causing) quantities of detergents are present, the ssmple should be treated with an anti-foaming agent. The quantity of anti-foaming agent shall be recorded on the Test Solidification Data Sheet and shall not exceed one half of one percent by volume of the waste.
4.1.4 If oil is present in quantities greater than 1% by volume, the oil shall be reduced to less than 1% by skimming.
NOTE: Waste with oil greater than 1% by volume may not be shipped to Barnwell, South Carolina, but must be shipped to Hanford, Washington.
~
Emusification agents need not be used until the volume of oil exceeds 3% of the waste volume. The quantity of any substance added to' the sample for this purpose shall be recorded on the Test Solidification Data ~
Sheet and shall not exceed one percent by volume of the waste. Oil in concentrations
[ greater-than 12% by volume may not-be solidi-fied under this procedure.
O
~ -
(
a STD-P-05-003 1
.= J> ; * , . Page 6 of 18 l i
l 4.2 Test Solidification of 4 to 10 Weight Percent Boric Acid 4.2.1 MEASURE 500 gas of untreated waste into a container.
4.2.2 RECORD the weight on the Test Solidification Data Sheet for 4 to 10 Weight Percent Boric Acid.
4.2.3 ADD 50 weight percent sodium hydroxide until the pH is 8.
4.2.4 RECORD the weight of sodium hydroxide used on the Test Solidification Data Sheet for 4 to 10 Weight Percent Boric Acid.
4.2.5 If large (i.e., foam causing) quantities of detergents are present, TREAT the sample with an anti-foaming agent.
4.2.6 RECORD the weight of anti-foaming agent used on the Test Solidification Data Sheet for 4 to 10 Weight Percent Boric Acid.
4.2.7 If oil is present and the volume is between 3 and 12%
of the volume of waste, TREAT with an emulsifying agent such as Maysol 776 (20% of the volume of oil).
O NOTE: The density of Maycol 776 is 1.0 g/ml; the volume i. ml is equal to the weight in grams.
4.2.8 RECORD the quanti y of any emulsifying agent used on the Test Solidific stion Data Sheet for 4 to 10 Weight Percent Boric Acic 4.2.9 For the test so' .dification of the borated waste, measure into two 'ixing vessels 400ml of waste each pretreated as in Seccions 4.2.3 through 4.2.8.
NOTE: Test solidifications should be conducted using a 1,000 ml disposable beaker or similar size container.
4.2.10 RECORD the volume AND weight of the sample on the Test Solidification Data Sheet for 4 to 10 Weight Percent j Boric Acid.-
l 4.2.11 Using Figure I and the percent solids from the Test l Solidification Data Sheet, Form STD-P-05-003-01, Item (9), WEIGH out the required quantity of Portland Type I cement.
4.2.12 RECORD the weight of cement on the Test Solidification
! Data Sheet for 4 to 10 Weight Percent Boric Acid.
7__
. STD-P-05-003 )
= . Page 7 of 18 l 4*'. I n 4.2.13 WEIGH out the required quantity of anhydrous sodium U metasilicate (ASMS) into a separate vessel.
NOTE: The quantity of ASMS is 15% of the cement weight.
4.2.14 RECORD the weight of ASMS on the Test Solidification Data Sheet for 4 to 10 Weight Percent Boric Acid.
4.2.15 Slowly ADD the cement to the test sample while it is being mixed.
NOTE: Mixing should be accomplished by stirring with an electric mixing motor with blade until a homogeneous mixture is obtained, approximately one minute or less if the mixture begins to set.
4.2.16 After all 'the cement is added, slowly ADD the ASMS to the test sample while it is being mixed.
4.2.17 After sufficient mixing (2 minutes after all the ASMS is added) so that a homogeneous mixture is obtained, SEAL the sample and CURE at 120 15*F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.
NOTE: If at- any time during the 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> cure, the sample meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be disqualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
4.3 Test Solidification of >10 to 20 Weight Percent Boric Acid 4.3.1 MEASURE 500 gas of untreated waste into a container.
4.3.2 RECORD the weight on the Test Solidification Data Sheet for >10 to 20 Weight Percent Boric Acid.
4.3.3 ADD'50 weight percent sodium hydroxide until the pH is 12.
4.3.4 RECORD the weight of sodium hydroxide used on the Test Solidification Data Sheet for >10 to 20 Weight Percent Boric Acid.,
4.3.5 If large (i.e., foam causing) quantities of detergents are present, TREAT the sample with an anti-foaming agent.
w, 7 ,- - 4 n y. g --.n - ,--p -
-w---y
c r-
[. ,
STD-P-05-003 Pagn 8 of 18 O 4.3.6 RECORD the weight of anti-foaming agent used on the Test Solidification Data Sheet for >10 to 20 Weight Percent Boric Acid.
4.3.7 If oil is present and the volume is between 3 and 12%
of the volume of waste, TREAT with an emulsifying agent such as Maysol 776 (20% of the volume of oil).
NOTE: The density of Maysol 776 is 1.0 g/ml; the volume in ml is equal to the weight in grams.
4.3.8 RECORD the quantity of any emulsifying agent used on the Test Solidification Data Sheet for >10 to 20 Weight Percent Boric Acid.
4.3.9 For the test solidification of the borated waste, MEASURE into two mixing vessels 400 ml of waste pre-treated as in Sections 4.3.3 through 4.3.8.
NOTE: Test Solidifications should be conducted using a 1,000 ml disposable beaker or similar size container.
4.3.10 RECORD the volume AND weight of the sample on the Test Solidification Data Sheet for >10 to 20 Weight Percent O Boric Acid.
4.3.11 Using Figure I and the percent solids from the Test Solidification Data Sheet, Form STD-P-05-003-03, Item (9), VEIGH out the required quantity of Portland Type I cement.
4.3.12 RECORD the weight of cement on the Test Solidification Data Sheet for >?O to 20 Weight Percent Boric Acid.
4.3.13 WEIGH out the - required quantity of anhydrous sodium metasilicate (ASMS) into a separate vessel.
NOTE: The quantity of ASMS is 15% of the cement weight.
4.3.14 RECORD.the, weight of ASMS on the Test Solidification Data Sheet, for >10 to 20 Weight Percent Boric Acid.
4.3.15 Slowly ADD the cement to the test sample while it is
, being mixed.
NOTE: Mixing should be accomplished by stirring l with' an electric mixing motor with blade until a homogeneous mixture is obtained, approximately one minute or less if the
[] mixture begins to set.
t i
. - , . - , e - - ~ . - , . ,-, - , , - . .
STD-P-05-003
. J,- . * , Page 9 of 18
-4.3.16 After all the cement is added, slowly ADD the ASMS to the test sample while it is being mixed.
4.3.17 After sufficient mixing (2 minutes after all the ASMS is added) so that a homogeneous mixture is obtained, SEAL the. sample and CURE at 120 15*F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.
NOTE: If at any time during the 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> cure, the sample meets the acceptance critiera, the liner solidification may proceed. However, no test solidification shall be disqualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
4.4 Solidification Acceptability The following criteria define an acceptable solidification process and process parameters.
4.4.1 The sample solidifications are considered acceptable if there is no free standing water, and 4.4.2 If upon visual inspection, the waste appears that it would hold its shape if removed from the mixing vessel, and 4.4.3 It resists penetration.
4.5 Solidification Unacceptability 4.5.1 If the waste fails any of the criteria set forth in Section 4.4, the solidification will be termed unaccept-able. CONTACT Hittman for specific instructions.
l 9
35F , ,
l l
, , STD-P-05-003 Page 10 of 18 Liner No.:
Sample No.:
Date:
TEST SOLIDIFICATION DATA SHEET FOR 4 to 10 WEIGHT PERCENT BORIC ACID I. PRECONDITIONING Weight Percent of Boric Acid (in decimal form) (1)
Weight of Untreated Sample, ges: (2)
Weight of 50% NaOH Added to Adjusted pH to 8, gas: (3)
Weight of Anti-foam Added, gms: (4)
Weight of Emulsifier Added, gms: (5)
II. DETERMINATION OF PERCENT SOLIDS OF SAMPLE Weight of Untreated Sample (2) x Percent Boric Acid (1) gm (6)
Weight of 50% Na0H (3) x 0.5 gm (7)
Weight of Solids in Treated Sample, gms:
(4) + (5) + (6) + (7):
( )+( )+( )+( )= gms (8)
Percent Solids in Treated Sample:
100 x (8) + [(2) + (3) + (4) + (5)]:
100 x ( ) + [( )+( )+( )+( )] = % (9)
III. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATION:
Volume of Sample to be Solidified, ml (10)
Weight of Sample to be Solidified, gms (11)
Weight of Water in 50% Na0H Used to Adjust pH, gms:
[f x (3)] x 0.5:
[ (500x( )] x 0.5: (12)
Weight of Water in Sample to be Solidified, gms:
[(11) - (12)] x [1 - (11] + (12):
[( )-( )] x [1 - ( )] + ( )= (13)
IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT TO USE FOR SAMPLE SOLIDIFICATION, gas : .
Using Figure I, find the % solids in sample (9), and DETERMINE the Water / Cement Ratio: (14)
- n l G FORM STD-P-05-003-01 Sheet 1 of 2 l
,',,.' STD-P-05-003 g . .' Page 11 of 18
..77
%) Weight of Cement to Use, gas:
(13) , ( )= (15)
(14) ( )
Additional batches solidified based on this sample solidification:
Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date t
V. SAMPLE INSPECTION 2
Sample cured for 24 h'o ursi @ 120* 1 5'F:
l.
Verified by Date
[)
Sample contains "No Free Liquid" Verified by Date Sample is a " Free Standing Monolith":
l i i.
l Verified by Date. s' l \
(
i-FOOTNOTES
}
I It is not necessary to cure .at 120' i. 5'F for Class A Unstable Waste.
If Class A Stable, Class B or C wastes are qualified in less than 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />, note the total hours cured.
l
\~
FORM STD-P-05-003-01 ,N
() Sheet 2 of 2 s
4% .=
s -
i t.
- i. -
l .. -_
- . . . _ _ ._. _ ___ . . - - . . - - _ . . . _.. - , . . _ .... s, _ . , , . . _ . . . _ ,
STD-P-05-003 ap <
Paga 12 of 18 A
c- SOLIDIFICATION CALCULATION SHEET FOR 4 TO 10 WEIGHT PERCENT BORIC ACID Volume of Untreated Waste to Add to Liner, ft3:
Max. Treated Waste Vol.
500 x from Solidification Data Item 3 + Item 4 + Item 5 + 500 Tables 500 x = ft3 (3)
( )+( )+( ) + 500 Volume of Additives to Add to Liner, Gallons:
', x .0097 x (1) = gallons (2)
Item 3 .
STD-P-05-003-01 x 1.04 x (1) = gallons (3)
Item 4 STD-P-05-003-01 x 1.04 x (1) = gallons (4)
Item 5
( ,,) STD-P-05-003-01 Volume of Treated Waste to be Solidified 1 , ft 3 (1) +[ (2)7.48
+ (3) + (4) );
( )+[I I*I )*I 7.48
))= ft3 (5)
Cement Quantity for Full Scale Solidification, lbs:
x 0.156 x (5) = lbs (6)
Item 15 STD-P-05-003-01 ASMS Quantity for Full Scale Solidification, lbs:
(6) x .15 = ,
(1bs) (7)
FOOTNOTES 1
The volume of treated waste to be solidified in a single liner cannot exceed the maximum waste volume listed on the attached Solidification Data Tables.
~
I Form STD-P-05-003-02 l Page 1 of 1 l
s i
r1 l
l
, , 3 STD-P-05-003
. Page 13 of 18
.,..< c 3
Liner No.:
Sample No.:
Date:
TEST SOLIDIFICATION DATA SHEET FOR
>10 TO 20 WEIGliT PERCENT BORIC ACID i I. PRECONDITIONING Weight Percent of Boric Acid (in decimal form) (1)
Weight of Untreated Sample, gms: (2)
Weight of 50% NaOH Added to Adjusted pH to 12, gms: (3)
Weight of Anti-foam Added, gms: (4)
Weight of Emulsifier Added, gms: (5) it II. DETERMINATION OF PERCENT SOLIDS OF SAMPLE Weight of Untreated Sample (2) x Percent Boric Acid (1) gm (6)
Weight of 50% NaOH (3) x 0.5 gm (7)
Weight of Solids in Treated Sample, gms:
(4) + (5) + (6) + (7):
( )+( )+( )+( )= gms (8)
Percent Solids in Treated Sample:
100 x (8) +;[(2) + (3) + (4) + (5)]:
4 100 x~( ) + [( )+( )+( )+( )] = % (9)
III. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATION:
Volume of Sample to be Solidified, ml (10)
Weight of Sample to be Solidified, gms (11)
Weight of Wateb in 50% NaOH Used to Adjust pH, gms:
[f x (3)] x 0.5:
[ (500x( )] x 0.5: (12)
Weight of Water in Sample to be Solidified, gms:
[(11) - (12)] x [1 - (1)] + (12):
~
[( )-( )] x'[1 - ( )] + ( )= (13)
. IV . DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT TO USE FOR SAMPLE SOLIDIFICATION, gas.:
Using Figure I, find the %. solids in sample (9),-and DETERMINE '
the Water / Cement Ratio: (14)
, , c
.7 FORM STD-P-05-003-03 ,
Sheet 1 of 2 s s
N t' -e ? -fP e
^
STD-P-05-003
.. i 4- Page 14 of 18 s
- Weight of Cement to Use, gas:
(13) _ ( )= (15)
(14) ( )
Additional batches solidified based on this sample solidification:
Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date V. SAMPLE INSPECTION Sample cured for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 1 @ 120' t 5*F:
Verified by Date Os Sample contains "No Free Liquid" Verified by Date Sample is a " Free Standing Monolith":
Verified by Date FOOTNOTES IIt is not necessary to cure'at 120 t 5'F for Class A Unstable Waste.
If Class A Stable, Class B o'r C wastes are qualified in less than 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />, note the total hours cured.
FORM STD-P-05-003 Sheet 2 of 2 f
r'
(
'. STD-P-05-003
.** ' Peg 2 15 of 18 i
SOLIDIFICATION CALCULATION SHEET FOR
>10 TO 20 WEIGHT PERCENT BORIC ACID Volume of Untreated Waste to Add to Liner, ft3:
Max. Treated Waste Vol.
500 x fr m S lidification Data Item 3 + Item 4 + Item 5 + 500 Tables
( )+( ) ( ) + 500
- I' (I)
Volume of Additives to Add to Liner, Gallons:
x .0097 x (1) = gallons (2)
Item 3 STD-P-05-003-03 x 1.04 x (1) = gallons (3)
Item 4 STD-P-05-003-03 x 1.04 x (1) = gallons (4)
Item 5 STD-P-05-003-03 Volume of Treated Waste to be Solidified 1 , ft3 (1) +[ (2)7.48
+ (3) + (4) ), *
(')+[( )+f )+f 7.48
)]= ft3 (5)
Cement Quantity for Full Scale Solidification, lbs:
x 0.156 x (5) = lbs (6)
Item 15 STD-P-05-003-03 ASMS Quantity for Full Scale Solidification, lbs:
(6) x .15 = (1bs) (7)
FOOTNOTES 1
The volume of treated waste to be solidified in a single liner cannot exceed the maximum waste volume listed.on the attached Solidification Data Tables.
?
.(nT, Form STD-P-05-003-04
"' Page 1 of 1
{
STD-P-05-003 Pags 16 of 18 vA., . _ . -. . _ _ _ _. _ _ _ . . . ;
l
. ... . ., . j . . . _ . . . . . ..
p . ..I _. _ _ _ . . .._____4_- ._ j _.. .. . . . _ _ . _ _.. ,
l 9 _ _ _ _ _ _ . . . .
j .
, _ _ _ _ _ _ . t
)
_ - . g . . . _.. ..
..}._..... -
} .
l
__ ._ .__ - ~~~
FIGURE!1
~ ~ ~ ~ !- i U ____fERCENI.50 LIDS.0F-pd ADJUSTED MAS'I5 ..j
(- ._ ___ y . . _ .
. ._ _ . ._ j . . "~~ ' " - ~ !
~
WATERICD ST RhTIO' '
..__ _ _ _. } , . . . . 1.._._._.. _ . _ _ _ .. ,
}
, . 1 .____ _.
j _
____._j..._ _ . . . _ .
__._3... . . . _ . _ _ __ y ____
e .
.__p_.... _ . . . . .. __
_ .4 N
.._..__4...._
. _. . _ _q . ._
.-._...f.__.. ___ _p
.._____q___
__f. l _ _ _ - . . .
__.p. _
y . .._____ g . _. _ ._.._____ _. _ _ _ _ _ . _ _
.._..-.-4 - . . _ _ _ . . _ . . . . . _
_7 0,, . _ _ _ .
,},,,_,_,. , , , , _ _ , _ _ j . _ _ , , , . _ .
u a. . _,_,,_
x
___. _t....-_.f__ _ ._. _ . _ -
. __ y
.}
-_.. - _ -_ . _. g
. . { . _ ._ .. _...q_..._ . _ ...._-._;____ _, _i- - _ . . . .
c .
.._...[. _ . , . _ . _ .
a _ _. ... . _ _ ._-..._... . . _ _
7 u . ______; ...-___.
4
. . ._ f _ _ . ___..___7.._
_____. q _ . _ . _ _ _ . _ .
,, u, , ,
i
) w ._ ,..-.._. .
g ,.-
.-._ _-_..-.g 3 _. ; . _ . . .
j ..._ _._ ._ . . . . , . _ . . . _. ..
. . . _ _ _ . . _ . . . . . .. 4 __. _ . _ _ _ _ _ _ .
7 . _ . _
, 0.85 , , ,
3 . _ . .._. .. _. ....
7
- j. . . . . . . . . _ . _ . .. . _ _ _ _ .- .-
___._}.
j 7 -.. . , ,
- I __ . ; .. . . . . . . _ .._ _
p _. _ __ _.___.p_____. } . ._ . . _1 .
p
_s 3._.
_ _. p. _
. _ _4 .
.=
)__-.__ .-__.1,_._.....
g> ._ . - - . , _ . .
______.7-. . __ __
0 . .
.I.-_.._. f . . _ . .
___-.....1....._.
.g __,___;._.__..._ .
__. .1 _. __ __.L _.. ._ ..
- g . . _ .
7 g _ __ ._. __ .____ _ _ _ . . . .. .. . . .
WJ j _ _____ . . _ . . L . . _ _ .
y ___. - -
1
_-._.y
.._1___.___ __p 5
( . .._. ,{_. ._ _. __ _ _ _ . _ _ . . _ . .. .e
. _q l
, j { ..
0.8 ; , .
. . . -.\.
__ } _. . . .. . _ - . _ . -
I J .
. _ _ . - . . ,I 5 10 15 20 25
% Solids of pH Adjusted Waste
- +
a' . STD-P-05-003
, , , , Page 17 of 18 O SOLIDIFICATION DATA TABLES FOR 4 to 10 WEIGHT PERCENT BORIC ACID HN-100 HN-100 LVM Series 1 1 Series 21 Series 3 S Series 32 KN-100TVA Useable Liner Vol. (cu.ft.) 143.0 143.0 143.0 143.0 160.0 125.0 Max. Treated Waste Vol. (cu.ft.) 89.4 87.3 105.8 105.8 118.4 92.5 Max. Solidified Waste Vol. (cu.ft.) 120.9 . 117.9 143.0 143.0 160.0 125.0 Max. Rad. Level R/hr Contact 12 12 12 3 12 10 1 For less than A2 quantities of LSA waste, use data for Series 3 cask.
() 2 For less than A2 quantities of LSA waste.
J k -
Form STD-P-05-003-05
E
]
. l
.* 5' STD-P-05-003
,'
- Page 18 of 18
(}
SOLIDIFICATION DATA TABLES FOR
>10 to 20 WEIGHT PERCENT BORIC ACID HN-100 HN-100 LVM Series 1 1 Series 21 Series 3 S2 Series 32 KN-100TVA Useable Liner Vol. (cu.ft.) 143.0 143.0 143.0 143.0 160.0 125.0 Max. Treated Waste Vol. (cu.ft.) 83.4 81.4 102.8 102.8 115.0 89.9 Max. Solidified Waste Vol. (cu.ft.) 116.0 113.2 143.0 143.0 160.0 125.0 Max. Rad. Level R/hr Contact 12 12 12 3 12 10 1 For less than A2 quantities of LSA waste, use data for Series 3 cask.
() 2 For less than A2 quantities of LSA waste.
l 1
4 l
O
! Form STD-P-05-003-06 i
i L