ML14108A044: Difference between revisions
StriderTol (talk | contribs) (Created page by program invented by StriderTol) |
StriderTol (talk | contribs) (Created page by program invented by StriderTol) |
||
Line 220: | Line 220: | ||
Surface Water GS 36 (pCi/L) Cs-134 15 < LLD -< LLD 0 0 Cs-137 Other Gammas 18 15 | Surface Water GS 36 (pCi/L) Cs-134 15 < LLD -< LLD 0 0 Cs-137 Other Gammas 18 15 | ||
< LLD | < LLD | ||
< LLD | < LLD LLD LLD 0 | ||
LLD LLD 0 | |||
0 0 | 0 0 | ||
H-3 12 300 < LLD < LLD Page 7 of 14 | H-3 12 300 < LLD < LLD Page 7 of 14 | ||
Line 232: | Line 229: | ||
Range0 Location Rangec RangeR Resultse Fish GS 5 (pCi/g wet) Mn-54 0.021 < LLD -< LLD 0 Co-58 0.023 < LLD -< LLD 0 Co-60 0.016 < LLD -< LLD 0 Fe-59 0.071 < LLD -< LLD 0 Zn-65 0.040 < LLD -< LLD 0 Ru-103 0.031 < LLD -< LLD 0 Cs-1 34 0.022 < LLD -< LLD 0 Cs-1 37 0.019 < LLD -< LLD 0 Sediment GS 4 pCi/g dry Mn-54 0.023 < LLD -< LLD 0 Co-58 0.023 < LLD -< LLD 0 Co-60 0.016 < LLD -< LLD 0 Fe-59 0.066 < LLD -< LLD 0 Zn-65 0.051 < LLD <- LLD 0 Cs-134 0.015 < LLD -< LLD 0 Cs-1 37 0.020 < LLD -< LLD 0 0 Food Crops (pCi/g wet) | Range0 Location Rangec RangeR Resultse Fish GS 5 (pCi/g wet) Mn-54 0.021 < LLD -< LLD 0 Co-58 0.023 < LLD -< LLD 0 Co-60 0.016 < LLD -< LLD 0 Fe-59 0.071 < LLD -< LLD 0 Zn-65 0.040 < LLD -< LLD 0 Ru-103 0.031 < LLD -< LLD 0 Cs-1 34 0.022 < LLD -< LLD 0 Cs-1 37 0.019 < LLD -< LLD 0 Sediment GS 4 pCi/g dry Mn-54 0.023 < LLD -< LLD 0 Co-58 0.023 < LLD -< LLD 0 Co-60 0.016 < LLD -< LLD 0 Fe-59 0.066 < LLD -< LLD 0 Zn-65 0.051 < LLD <- LLD 0 Cs-134 0.015 < LLD -< LLD 0 Cs-1 37 0.020 < LLD -< LLD 0 0 Food Crops (pCi/g wet) | ||
GS Mn-54 8 | GS Mn-54 8 | ||
0.021 < LLD - < LLD 0 S Co-58 Co-60 0.020 0.014 | 0.021 < LLD - < LLD 0 S Co-58 Co-60 0.020 0.014 LLD LLD LLD LLD 0 | ||
0 Fe-59 0.045 < LLD - < LLD 0 0 Zn-65 Zr-Nb-95 0.043 0.023 LLD LLD LLD LLD 0 | |||
LLD LLD | |||
LLD LLD 0 | |||
0 Fe-59 0.045 < LLD - < LLD 0 0 Zn-65 Zr-Nb-95 0.043 0.023 | |||
LLD LLD | |||
LLD LLD 0 | |||
0 Cs-134 0.017 < LLD - < LLD 0 Cs-1 37 0.016 < LLD - < LLD 0 0 Ba-La-140 0.015 < LLD - < LLD 0 S | 0 Cs-134 0.017 < LLD - < LLD 0 Cs-1 37 0.016 < LLD - < LLD 0 0 Ba-La-140 0.015 < LLD - < LLD 0 S | ||
Vegetation (MI) GS I 0 (pCi/g wet) Mn-54 0.033 < LLD - < LLD 0 Co-58 0.029 < LLD - < LLD 0 Co-60 0.026 < LLD - < LLD 0 0 Fe-59 0.050 < LLD - < LLD 0 0 Zn-65 Zr-Nb-95 0.052 0.035 | Vegetation (MI) GS I 0 (pCi/g wet) Mn-54 0.033 < LLD - < LLD 0 Co-58 0.029 < LLD - < LLD 0 Co-60 0.026 < LLD - < LLD 0 0 Fe-59 0.050 < LLD - < LLD 0 0 Zn-65 Zr-Nb-95 0.052 0.035 LLD LLD LLD LLD 0 | ||
0 1-131 0.046 < LLD < LLD 0 0 Cs-1 34 Cs-137 0.026 0.029 LLD LLD LLD LLD 0 | |||
LLD LLD | |||
LLD LLD 0 | |||
0 1-131 0.046 < LLD < LLD 0 0 Cs-1 34 Cs-137 0.026 0.029 | |||
LLD LLD | |||
LLD LLD 0 | |||
0 Ba-La-140 0.027 < LLD - < LLD 0 8GB = gross beta, GS = gamma scan. | 0 Ba-La-140 0.027 < LLD - < LLD 0 8GB = gross beta, GS = gamma scan. | ||
b LLD = nominal lower limit of detection based on a 95% confidence level. | b LLD = nominal lower limit of detection based on a 95% confidence level. | ||
Line 712: | Line 677: | ||
- 1230.0 | - 1230.0 | ||
- 440.0 Pass 0 ERAP-1174 03/18/13 Mn-54 <3.1 0.0 0.0 - 50.0 Pass ERAP-1 174 03/18/13 Pu-238 50.0 +/- 3.0 51.1 34.3 - 65.9 Pass S ERAP-1174 03/18/13 Pu-239/40 65.7 +/- 2.6 65.2 47.2 - 85.2 Pass ERAP-1174 03/18/13 U-233/4 54.0 +/- 2.5 59.4 36.8 89.6 Pass 0 ERAP-1174 03/18/13 U-238 55.6 +/- 2.6 58.9 38.1 | - 440.0 Pass 0 ERAP-1174 03/18/13 Mn-54 <3.1 0.0 0.0 - 50.0 Pass ERAP-1 174 03/18/13 Pu-238 50.0 +/- 3.0 51.1 34.3 - 65.9 Pass S ERAP-1174 03/18/13 Pu-239/40 65.7 +/- 2.6 65.2 47.2 - 85.2 Pass ERAP-1174 03/18/13 U-233/4 54.0 +/- 2.5 59.4 36.8 89.6 Pass 0 ERAP-1174 03/18/13 U-238 55.6 +/- 2.6 58.9 38.1 | ||
-81.4 Pass 0 ERAP-1174 03/18/13 Uranium 112.0 +/- 5.6 121.0 67.0 - 184.0 Pass 0 ERAP-1174 03/18/13 03/18/13 Zn-65 Gr. Alpha 236.6 52.3 | -81.4 Pass 0 ERAP-1174 03/18/13 Uranium 112.0 +/- 5.6 121.0 67.0 - 184.0 Pass 0 ERAP-1174 03/18/13 03/18/13 Zn-65 Gr. Alpha 236.6 52.3 | ||
+/- 13.8 | +/- 13.8 | ||
+/- 2.8 199.0 142.0 - 275.0 Pass ERAP-1175 42.3 14.2 - 65.7 Pass 0 ERAP-1175 03/18/13 Gr. Beta 36.2 +/- 2.0 25.1 15.9 - 36.6 Pass ERSO-1176 03/18/13 Am-241 293.1 +/- 97.4 229.0 134.0 - 297.0 Pass S ERSO-1176 03/18/13 Pu-238 909.0 +/- 180.0 788.0 474.0 - 1090.0 Pass ERSO-1176 03/18/13 Pu-239/40 432.0 +/- 120.0 366.0 239.0 - 506.0 Pass 0 ERSO-1 176 03/18/13 Sr-90 8050.8 +/- 376.0 8530.0 3250.0 - 13500.0 Pass 0 ERSO-1176 03/18/13 U-233/4 1662.6 +/- 150.0 1920.0 1170.0 - 2460.0 Pass ERSO-1176 03/18/13 U-238 1682.8 +/- 160.0 1900.0 1180.0 - 2410.0 Pass ERSO-1176 03/18/13 Uranium 3404.0 +/- 330.5 3920.0 2130.0 - 5170.0 Pass ERSO-1176 03/18/13 Ac-228 1335.0 +/- 132.0 1240.0 795.0 - 1720.0 Pass 0 ERSO-1176 03/18/13 Bi-212 1420.0 +/- 311.0 1240.0 330.0 - 1820.0 Pass ERSO-1176 03/18/13 Bi-214 2626.0 +/- 60.0 3660.0 2200.0 - 5270.0 Pass S ERSO-1176 03/18/13 Co-60 7951.0 +/- 45.4 7920.0 5360.0 - 10900.0 Pass ERSO-1 176 03/18/13 Cs-134 5785.0 +/- 51.0 6370.0 4160.0 - 7650.0 Pass 0 ERSO-1 176 03/18/13 Cs-137 6106.0 +/- 47.9 6120.0 4690.0 - 7870.0 Pass ERSO-1176 03/18/13 K-40 11756.0 +/- 284.3 10300.0 7520.0 - 13800.0 Pass 0 ERSO-1176 03/18/13 Mn-54 < 28.0 0.0 0.0 - 1000.0 Pass 0 ERSO-1176 03/18/13 Pb-212 1096.0 +/- 29.1 1240.0 812.0 - 1730.0 Pass ERSO-1 176 03/18/13 Pb-214 2875.0 +/- 60.0 Pass 0 ERSO-1 176 03/18/13 Th-234 2404.0 +/- 218.3 3660.0 1900.0 2140.0 601.0 | +/- 2.8 199.0 142.0 - 275.0 Pass ERAP-1175 42.3 14.2 - 65.7 Pass 0 ERAP-1175 03/18/13 Gr. Beta 36.2 +/- 2.0 25.1 15.9 - 36.6 Pass ERSO-1176 03/18/13 Am-241 293.1 +/- 97.4 229.0 134.0 - 297.0 Pass S ERSO-1176 03/18/13 Pu-238 909.0 +/- 180.0 788.0 474.0 - 1090.0 Pass ERSO-1176 03/18/13 Pu-239/40 432.0 +/- 120.0 366.0 239.0 - 506.0 Pass 0 ERSO-1 176 03/18/13 Sr-90 8050.8 +/- 376.0 8530.0 3250.0 - 13500.0 Pass 0 ERSO-1176 03/18/13 U-233/4 1662.6 +/- 150.0 1920.0 1170.0 - 2460.0 Pass ERSO-1176 03/18/13 U-238 1682.8 +/- 160.0 1900.0 1180.0 - 2410.0 Pass ERSO-1176 03/18/13 Uranium 3404.0 +/- 330.5 3920.0 2130.0 - 5170.0 Pass ERSO-1176 03/18/13 Ac-228 1335.0 +/- 132.0 1240.0 795.0 - 1720.0 Pass 0 ERSO-1176 03/18/13 Bi-212 1420.0 +/- 311.0 1240.0 330.0 - 1820.0 Pass ERSO-1176 03/18/13 Bi-214 2626.0 +/- 60.0 3660.0 2200.0 - 5270.0 Pass S ERSO-1176 03/18/13 Co-60 7951.0 +/- 45.4 7920.0 5360.0 - 10900.0 Pass ERSO-1 176 03/18/13 Cs-134 5785.0 +/- 51.0 6370.0 4160.0 - 7650.0 Pass 0 ERSO-1 176 03/18/13 Cs-137 6106.0 +/- 47.9 6120.0 4690.0 - 7870.0 Pass ERSO-1176 03/18/13 K-40 11756.0 +/- 284.3 10300.0 7520.0 - 13800.0 Pass 0 ERSO-1176 03/18/13 Mn-54 < 28.0 0.0 0.0 - 1000.0 Pass 0 ERSO-1176 03/18/13 Pb-212 1096.0 +/- 29.1 1240.0 812.0 - 1730.0 Pass ERSO-1 176 03/18/13 Pb-214 2875.0 +/- 60.0 Pass 0 ERSO-1 176 03/18/13 Th-234 2404.0 +/- 218.3 3660.0 1900.0 2140.0 601.0 5460.0 3570.0 Pass 0 ERSO-1 176 03/18/13 Zn-65 1542.0 +/- 56.4 1400.0 1110.0 - 1860.0 Pass 0 | ||
5460.0 3570.0 Pass 0 ERSO-1 176 03/18/13 Zn-65 1542.0 +/- 56.4 1400.0 1110.0 - 1860.0 Pass 0 | |||
0 0 | 0 0 | ||
0 A7-1 | 0 A7-1 | ||
Line 730: | Line 691: | ||
- 6230.0 | - 6230.0 | ||
- 1230.0 Pass Pass 0 | - 1230.0 Pass Pass 0 | ||
ERW-1184 03/18/13 Am-241 114.5 +/-8.1 118.0 79.5 - 158.0 Pass 0 ERW-1184 03/18/13 Co-60 2221.8 +/- 17.0 2270.0 1970.0 - 2660.0 Pass 1309.4 +/- 58.4 Pass 0 ERW-1 184 ERW-1184 03/18/13 03/18/13 Cs-134 Cs-137 1865.9 +/- 22.0 1400.0 1880.0 1030.0 1600.0 | ERW-1184 03/18/13 Am-241 114.5 +/-8.1 118.0 79.5 - 158.0 Pass 0 ERW-1184 03/18/13 Co-60 2221.8 +/- 17.0 2270.0 1970.0 - 2660.0 Pass 1309.4 +/- 58.4 Pass 0 ERW-1 184 ERW-1184 03/18/13 03/18/13 Cs-134 Cs-137 1865.9 +/- 22.0 1400.0 1880.0 1030.0 1600.0 1610.0 2250.0 Pass ERW-1184 03/18/13 Fe-55 503.1 +/- 105.0 712.0 424.0 - 966.0 Pass 0 ERW-1 184 03/18/13 Mn-54 < 9.4 0.0 0.0 - 100.0 Pass 0 ERW-1184 03/18/13 Pu-238 98.4 +/- 5.6 98.8 73.1 - 123.0 Pass ERW-1 184 03/18/13 Pu-239/40 184.5 +/- 7.7 185.0 144.0 - 233.0 Pass 0 ERW-1 184 03/18/13 Sr-O90 125.7 +/- 6.0 137.0 89.2 -181.0 Pass ERW-1 184 03/18/13 U-233/4 44.9 +/- 3.4 48.8 36.7 - 62.9 Pass 0 ERW-1184 03/18/13 U-238 46.5 +/- 3.5 48.4 36.9 - 59.4 Pass ERW-1184 03/18/13 Uranium 93.3 +/- 7.1 99.5 73.1 - 129.0 Pass 0 ERW-1 184 03/18/13 Zn-65 412.8 +/- 32.0 384.0 320.0 - 484.0 Pass ERW-1186 03/18/13 Gr. Alpha 109.1 +/- 5.7 130.0 46.2 - 201.0 Pass S ERW-1 186 03/18/13 Gr. Beta 74.5 +/- 6.4 78.9 45.2 - 117.0 Pass ERW-1188 03/18/13 H-3 12279.0 +/- 319.0 12300.0 8240.0 - 17500.0 Pass 0 | ||
1610.0 2250.0 Pass ERW-1184 03/18/13 Fe-55 503.1 +/- 105.0 712.0 424.0 - 966.0 Pass 0 ERW-1 184 03/18/13 Mn-54 < 9.4 0.0 0.0 - 100.0 Pass 0 ERW-1184 03/18/13 Pu-238 98.4 +/- 5.6 98.8 73.1 - 123.0 Pass ERW-1 184 03/18/13 Pu-239/40 184.5 +/- 7.7 185.0 144.0 - 233.0 Pass 0 ERW-1 184 03/18/13 Sr-O90 125.7 +/- 6.0 137.0 89.2 -181.0 Pass ERW-1 184 03/18/13 U-233/4 44.9 +/- 3.4 48.8 36.7 - 62.9 Pass 0 ERW-1184 03/18/13 U-238 46.5 +/- 3.5 48.4 36.9 - 59.4 Pass ERW-1184 03/18/13 Uranium 93.3 +/- 7.1 99.5 73.1 - 129.0 Pass 0 ERW-1 184 03/18/13 Zn-65 412.8 +/- 32.0 384.0 320.0 - 484.0 Pass ERW-1186 03/18/13 Gr. Alpha 109.1 +/- 5.7 130.0 46.2 - 201.0 Pass S ERW-1 186 03/18/13 Gr. Beta 74.5 +/- 6.4 78.9 45.2 - 117.0 Pass ERW-1188 03/18/13 H-3 12279.0 +/- 319.0 12300.0 8240.0 - 17500.0 Pass 0 | |||
0 0 | 0 0 | ||
a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency 0 testing administered by Environmental Resources Associates, serving as a replacement for studies conducted 0 previously by the Environmental Measurements Laboratory Quality Assessment Program (EML). | a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency 0 testing administered by Environmental Resources Associates, serving as a replacement for studies conducted 0 previously by the Environmental Measurements Laboratory Quality Assessment Program (EML). |
Latest revision as of 21:56, 5 February 2020
ML14108A044 | |
Person / Time | |
---|---|
Site: | Fort Calhoun ![]() |
Issue date: | 12/31/2013 |
From: | Omaha Public Power District |
To: | Office of Nuclear Reactor Regulation |
References | |
Download: ML14108A044 (48) | |
Text
Omaha Public Power District Fort Calhoun Station Unit No. 1
- Radiological Environmental 0* Operating Report
- 0 For
- Technical Specification
- Section 5.9.4.b 0
0
- January 1, 2013 to December 31, 2013 0
0 0 - r 0"
0..
0 0 i) 0 0..1 i O
0 0
0 DOCKET NO. 50-285 OPERATING LICENSE DPR-40
0 0
0 0
0 0
S 0
0 0
0 0
0 OMAHA PUBLIC POWER DISTRICT FORT CALHOUN STATION RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TECHNICAL SPECIFICATION 5.9.4.b 0
0 January 01, 2013 - December 31, 2013 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0
0 0
0 0
0 Annual Radiological Environmental Operating Report 0
This report is submitted in accordance with Section 5.9.4.b of the Technical 0 Specifications of Fort Calhoun Station Unit No. 1, Facility Operating License DPR-40 S for the period January 01, 2013 through December 31, 2013.
0 In addition, this report provides any observations and anomalies that occurred during 0 the monitoring period.
0 0
0 Reviewed by: Approved by:
0 Supervisrr-System Chemistry Ma, ger-Chemistry 0
S Plant Manager 0
S 0
0 S
0 0
0 0
0 0
0 0
0 Annual Radiological Environmental Operating Report 0
- In accordance with Technical Specification 5.9.4.b, herein is the Fort Calhoun
- Station (FCS) Annual Radiological Environmental Operating Report for year 2013.
The data provided is consistent with the objectives as specified in Section 5.2.2 of the
- Offsite Dose Calculation Manual (ODCM), "Annual Radiological Environmental
- Operating Report." The report is presented as follows:
0
- 1) An introductory discussion of the implementation of the Radiological Environmental Monitoring Program (REMP), including program observations
- and environmental impact relevant to the operation of FCS.
0
- 2) The sample class, sample collection frequency, number of sample locations, and the number of samples collected this reporting period for each parameter
- is delineated in Table 1.0.
S
- 3) A statistical evaluation of REMP data is summarized in Table 2.0, in accordance with Regulatory Guide 4.8, Table 1. For each type of sample media and analysis, Table 2.0 presents data separately for all indicator
- locations, all control (background) locations, and the location having the
- highest annual mean result. For each of these classes, Table 2.0 specifies the
- following:
- a. The total number of analyses
- b. The fraction of analyses yielding detectable results (i.e., results above
- the highest Lower Limit of Detection (LLD) for this period)
- c. The maximum, minimum, and average results
- d. Locations with the highest annual mean are specified by code, name,
- and by distance and direction from the center of plant reactor
- containment building.
S
- 4) Table 3.0 is a listing of missed samples and explanations
- 5) FC-801, 2012 Environmental Land Use Survey Report S
- 6) Review of Environmental Inc. Quality Assurance Program
- 7) Appendix A describes the Interlaboratory Comparison Program 0
- 8) Appendix B describes the vendor Data Reporting Conventions utilized
- 9) Appendix C reports the information required when primary coolant specific
- activity has exceeded the limits of Technical Specification 2.1.3 S
- 10) Appendix D is the Sample Locations/Map P
S
- Page 1 of 14 S
S
0 0 INTRODUCTION
- Radiological Environmental Monitoring Program (REMP)- 2013 0
This report gives the results of the Radiological Environmental Monitoring Program (REMP) for the year 2013. The REMP is a requirement of the Fort Calhoun Station (FCS) operating license. It was initiated prior to plant operation in 1973.
- The main purpose of the REMP is to ensure public safety by monitoring plant discharges and assessing the effect, if any, of plant operations, on the environment. Samples are collected that would account for various exposure pathways such as ingestion, inhalation, adsorption and direct
- exposure. Samples collected on a regular basis include: air, surface water, ground water, milk,
- vegetation, fish, sediment, and food crops. Direct radiation is measured by thermoluminescent dosimeters (TLDs). These samples and TLDs are sent to an independent vendor laboratory for analysis. The vendor uses analytical methods that are sensitive enough to detect a level of activity far below that which would be considered harmful. Locations for sample collection are based on
- radiological and meteorological data from the Annual Effluent Release Report and information
- obtained from the Environmental Land Use Survey.
- Most samples, particularly indicator samples, are collected in a circular area within a five-mile radius
- of plant containment while control locations are usually outside of five miles. This circle is divided into
- sixteen equal sectors, each assigned an identification letter "A" through "R" (note: letters "I"and "0" are not used, as they may be mistaken for the numbers "1" and "0"). Sector "A" is centered on North or zero degrees. Sectors are also given directional labels such as "West-Southwest" ("WSW").
Sample locations are listed by number along with their respective distances and direction from plant I* containment, in the Offsite Dose Calculation Manual (ODCM).
When assessing sample results, data from indicator locations most likely to be effected by plant operations are compared to control locations least or not likely to be effected. Results from an indicator location which were significantly higher than those from a control location, could indicate a plant-attributable effect, and could require additional investigation.
The results of the sample analyses, as required by the FCS Offsite Dose Calculation Manual 0 (ODCM), are presented in the attached statistical tables in accordance with Table 1 of Regulatory Guide 4.8, "Environmental Technical Specifications for Nuclear Power Plants." Sample collection was conducted by plant chemistry/environmental staff. A contract vendor (Environmental Inc.,
Northbrook, Illinois) performed sample analyses, preparation of monthly reports and the statistical evaluation of sample results. All vendor analysis techniques met the sensitivity requirements as 0 stated in the ODCM.
0 Results for 2013 were within expected ranges and compared closely with historical results, with the following exceptions.
0 0
0 0
0
- Page 2 of 14 0
0
0 1) Ambient Gamma Radiation 0 Ambient gamma radiation is measured by thermoluminescent dosimeters (TLDs) provided by 0 the vendor laboratory. These dosimeters contain calcium sulfate phosphors and are 0 processed quarterly. Thirty-two new thermoluminescent dosimeters were added to the 0 program during the fourth quarter of 2010.
0 All sample results are within the range of historical data and displayed less than 16%
difference when compared to historical averages. All results were less than 3 sigma standard 0 deviations from historical means. No discrepancy between released effluents and resultant 0 radiation dose measured was observed. No changes in plant operation/procedures are 0 required based upon observed impacts to the environment to date.
0 10-Year Trend Comparison of TLD Locations 0
Location Avg. Dose (mr/week) 2013 Avg. Dose (mr/week)
S 0 A 1.38 1.60 B 1.45 1.43 0 C 1.47 1.35 D 1.27 1.28 F 1.43 1.33 0 G 1.35 1.38 H 1.47 1.40 S
1.53 1.48 J 1.60 1.65 0 K 1.51 1.53 0 N 1.42 1.48 0 0 1.41 1.50 P 1.45 1.60 0 S 1.46 1.58 L (Control) 1.30 1.30 S
0 0 2) Milk/Pasture 0 Milk samples or pasture grasses, if milk is temporarily unavailable, are collected every two 0 weeks during the pasture season from the beginning of May through September, and monthly the rest of the calendar year. Indicator samples are collected from a herd of milk goats at a family farm located approximately 3.4 miles from the plant in Sector J (South). The control samples are collected from a commercial dairy cow herd located approximately 9.9 miles from 0 the plant in Sector J (South). This indicator station was added in March of this year, the control location is unchanged from last year. No indicator sample of vegetation was available 0 in February due to freezing conditions and no milk locations being present within 5 miles.
0 All sample results for Cesium-1 34, Cesium-1 37 and other gammas were at the LLD for both indicator and control locations. No plant-related effects were observed.
Page 3 of 14
0 0
- 3) Fish 0
Fish are collected on an annual basis. Control samples are collected at a location approximately twenty miles upstream of the plant (river miles 665 - 667). Indicator samples
- are collected in the immediate vicinity of the power plant (river miles 644 - 646). Several
- species of fish, important to commercial and recreational interest, representing all levels of the
- aquatic food chain are collected at both locations.
- All sample results are within the range of historical data. Results from both control and
- indicator locations were less than LLD for all gamma emitters, indicating no plant-related
- effects.
- 4) Food Crop
- Based on the results of the biennial Land Use Survey, the nearest high deposition pathway for
- food crops is the Alvin Pechnik Farm in Sector H (0.94 miles, 1630). Accordingly, vegetable samples were collected at Alvin Pechnik Farm for the purposes of the 2013 REMP.
- Samples were comparable with historical results and within the range of results reported from
- the control location garden at Mohr Dairy.
All results were at the LLD for all non-naturally occurring radionuclides. No plant-related
- effects were observed.
0
- 5) Sediment
- River sediment samples are collected twice a year at an upstream control location (0.09 miles,
- 40 N) and a downstream indicator location (0.45 miles, 1080 ESE).
0 All results were at the LLD for all non-naturally occurring radionuclides. No plant-related effects were observed.
0
- 6) Air Monitoring Air sample results for 2013 were well within historical limits for all locations. Additionally, all 0*indicator locations showed results very similar to the control locations.
- All sample results are within the range of historical data. All indicator locations displayed less than 8% difference when compared to historical average. All 2013 results when compared to historical averages are within the stated vendor error acceptance tolerance.
S
- Results from both control and indicator locations were less than LLD for gamma emitters and
- iodine. No changes in plant operation/procedures are required based upon observed impacts to the environment to date.
0 0
- Page 4 of 14 0
0
S 0
0 0
0 10-Year Trend Comparison of Air Sampling Locations 0 Location Avg. Beta (pCi/m 3) 2013 Avg. Beta (pCi/m 3 )
0 Sector B 0.030 .029 Sector D 0.029 .028 0 Sector I 0.027 .028 Sector J 0.028 .030 0 Sector K* 0.029 .030 Sector F (Control) 0.030 .029 S
- At least a 5-Year comparison due to data availability 0 7) Surface Water 0
Water samples are collected upstream of the plant (control location) as well as half-mile 0 downstream and at a municipal water treatment plant on the north edge of Omaha.
Results for Cs-1 34, Cs-1 37, and other gammas were all less than LLD. Tritium results were also less than LLD. No plant-related effects were detected.
0
- 8) Ground Water 0
S Quarterly residential well water samples are collected at the following locations: Station No.
15, Smith Farm, Station No. 20, Mohr Dairy, Station No. 74, D. Miller Farm and Station No. 75, 0 Lomp Acreage. All sample results to date have been at the LLD except gross beta due to 0 naturally occurring radionuclides. Gross beta results have ranged from a low of 2.7 pCi/liter to 0 a high of 12.1 pCi/liter, with an average gross beta for the year of 5.7 pCi/liter. Strontium-90 analysis is being conducted on wells as part of the station's groundwater protection program.
0 No plant-related effects were detected.
0 0
0 0
0 0
0 S
0 Page 5 of 14
S 0
0 0 Table 1.0 0
Sample Collection Program 0
0 Collection Number of Samples 0 Sample Class Frequency Sample Collected this 0 Locations Period.
0 Background Radiation (TLDs) Quarterly 47 188 0
S Air Particulates Weekly 6 312 0
Airborne Iodine Weekly 6 312 0
Biweekly 0 Milk May thru Sept 2 351 0
0 Surface Water Monthly 3 36 0
0 Ground Water Quarterly 4 16 0 Fish Annually 2 52 S
0 Sediment Semi-annually 2 4 0
0 Food Crops Annually 383 S
TOTAL 916 0
0 Note 1: Milk sample collection total includes vegetation performed for milk unavailability. Milk 0 sampling is semi-monthly during May-Sept, and monthly the rest of the year. Three milk 0 samples were performed in August to maintain ST frequency.
Note 2: Includes one background sample.
Note 3: Variety of samples collect during period.
0 Page 6 of 14
Table 2.0 Radiological Environmental Monitoring Program Summary Reporting Period January-December, 2013 Name of Facility Fort Calhoun Nuclear Power Station - Unit 1 Docket No. 50-285 Location of Facility Washington, Nebraska
( County, State )
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLDb Mean (F)0 Mean (F)0 Mean (F)c Routine (Units) Analyses' Range' Locationd Rangec Rangec Resultse Background Gamma 188 0.5 1.5 (184/184) OTD-2K-(I), 1.7 (4/4) 1.3 (4/4) 0 Radiation (1.1-1.9) 2.52 mi. @ 2050 (1.4-1.9) (1.1-1.5)
(TLD)
(mR/week)
Airborne GB 312 0.005 0.028 (260/260) OAP-K-(I) 0.029 (52/52) 0.029 (52/52) 0 Particulates (0.011-0.067) 0.65 miles SSE. (0.011-0.065) (0.012-0.065)
(pCi/m 3) GS 24 Cs-134 0.001 < LLD -< LLD 0 Cs-137 0.001 < LLD <- LLD 0 Other Gammas 0.001 < LLD <- LLD 0 Airborne 1-131 312 0.070 < LLD -< LLD 0 0 Iodine (pCi/m3) 0 Milk 1-131 34 0.5 < LLD -< LLD 0 0 (pCi/L)
GS 34 0 K-40 150 1831 (16/16)
(1706-1974)
OFM-G-(I), Stangl Dairy, 3.4 mi@369° 1831 (16/16)
(1706-1974) 1378 (18/18)
(1305-1585) 0 0 Cs-134 Cs-137 15 15
< LLD
< LLD
- < LLD
< LLD 0
0 0 Other Gammas 15 < LLD < LLD 0 Ground Water GB 16 5.7 (12/12) OGW-A-(I), Smith 6.6 (4/4) 5.7 (4/4) 0 0 (pCi/L) (2.7-12.1) Farm, 1.9 mi @ 1330 (2.7-12.1) (4.1-6.9)
H-3 16 300 < LLD -< LLD 0 Sr-90 16 0.71 < LLD -< LLD 0 GS 16 (pCi/L) Cs-1 34 15 < LLD - < LLD 0 0 Cs-137 18 < LLD - < LLD 0 Other Gammas 15 < LLD - < LLD 0 0
Surface Water GS 36 (pCi/L) Cs-134 15 < LLD -< LLD 0 0 Cs-137 Other Gammas 18 15
< LLD
0 0
H-3 12 300 < LLD < LLD Page 7 of 14
Name of Facility Fort Calhoun Nuclear Power Station - Unit 1 Docket No. 50-285 Location of Facility Washington, Nebraska
( County, State)
Sample Type and Indicator Location with Highest Control Number Type Number of LLDb Locations Annual Mean Locations Non-Analysesa Mean (F)L d Mean (F)' Mean (F)' Routine (Units)
Range0 Location Rangec RangeR Resultse Fish GS 5 (pCi/g wet) Mn-54 0.021 < LLD -< LLD 0 Co-58 0.023 < LLD -< LLD 0 Co-60 0.016 < LLD -< LLD 0 Fe-59 0.071 < LLD -< LLD 0 Zn-65 0.040 < LLD -< LLD 0 Ru-103 0.031 < LLD -< LLD 0 Cs-1 34 0.022 < LLD -< LLD 0 Cs-1 37 0.019 < LLD -< LLD 0 Sediment GS 4 pCi/g dry Mn-54 0.023 < LLD -< LLD 0 Co-58 0.023 < LLD -< LLD 0 Co-60 0.016 < LLD -< LLD 0 Fe-59 0.066 < LLD -< LLD 0 Zn-65 0.051 < LLD <- LLD 0 Cs-134 0.015 < LLD -< LLD 0 Cs-1 37 0.020 < LLD -< LLD 0 0 Food Crops (pCi/g wet)
GS Mn-54 8
0.021 < LLD - < LLD 0 S Co-58 Co-60 0.020 0.014 LLD LLD LLD LLD 0
0 Fe-59 0.045 < LLD - < LLD 0 0 Zn-65 Zr-Nb-95 0.043 0.023 LLD LLD LLD LLD 0
0 Cs-134 0.017 < LLD - < LLD 0 Cs-1 37 0.016 < LLD - < LLD 0 0 Ba-La-140 0.015 < LLD - < LLD 0 S
Vegetation (MI) GS I 0 (pCi/g wet) Mn-54 0.033 < LLD - < LLD 0 Co-58 0.029 < LLD - < LLD 0 Co-60 0.026 < LLD - < LLD 0 0 Fe-59 0.050 < LLD - < LLD 0 0 Zn-65 Zr-Nb-95 0.052 0.035 LLD LLD LLD LLD 0
0 1-131 0.046 < LLD < LLD 0 0 Cs-1 34 Cs-137 0.026 0.029 LLD LLD LLD LLD 0
0 Ba-La-140 0.027 < LLD - < LLD 0 8GB = gross beta, GS = gamma scan.
b LLD = nominal lower limit of detection based on a 95% confidence level.
c Mean and range are based on detectable measurements only (i.e., >LLD) Fraction of detectable measurements at specified locations is indicated in parentheses (F).
d Locations are specified: (1) by code, (2) by name, and (3) by distance and direction relative to the Reactor Containment Building.
Non-routine results are those which exceed ten times the control station value. If no control station value is available, the result is considered non-routine if it exceeds the typical pre-operational value for the medium or location.
Page 8 of 14
0 0
0 Table 3.0 Listing of Missed Samples (samples scheduled but not collected)
Sample Date Location Reason Type 0
0 0
0 0
S 0
0 0
0 0
0 S
0 0
0 0
0 0
0 0
0 0
0 0
Page 9 of 14
- @@@@*OOO@O@@e@@@@OOO@@O@eOO@@@OO@SOSoe@@@e@
FORT CALHOUN STATION FC-801 CHEMISTRY FORM 2012 REV I Environmental Land Use Survey Report Page 1 of3 Sector r Land Use Owner Miles Meters Deg Survey _ XOQ DOQ Remarks Technique 50 2r A IN RESIDENCE WRIGHT 14.361 7016.7ý 3511 INTERVIEW X[ IXl 1.60E-071 5.50E-10 MILK ANIMAL MEAT ANIMAL VEGETATION GROUNDWATER WRIGHT 4.36 7016.7 351 INTERVIEW X IXl 1.60E-07 5.50E-11 B INNE RESIDENCE RAND,J 1.93 3106.0q 12 INTERVIEW X 1.30E-06 2.50E-09 MILK ANIMAL MEAT ANIMAL VEGETATION GROUNDWATER RAND,J 1.93 3106.01 12 INTERVIEW X 1.30E-06 2.50E-01 C I NE RESIDENCE HANSEN,S 1.52 2446.2q 42 INTERVIEW X X 1.70E-06 1.80E-09 MILK ANIMAL MEAT ANIMAL VEGETATION THIELE 1 1.59 2558.80 52 MAIL SURVEY X 1.60E-06 1.70E-09f GROUNDWATER HANSEN,S 1 1.52 2446.21 421 MAIL SURVEY X1I xl 1.70E-06 1.80E-09j D ENE RESIDENCE MEADE,G 14.79 7708.7 63j INTERVIEW X 1.60E-07 8.40E-111 MILK ANIMAL MEAT ANIMAL VEGETATION MEADE,G 14.79 7708.71 631 INTERVIEW X I 1.60E-071 8.40E-111 GROUNDWATER MEADE,G 14.79 7708.71 631 INTERVIEW X 1.60E-07 8.40E-111 RESIDENCE DOTY,J 1 4.6717515.61 891 MAIL SURVEY X 2.30E-07 1.40E-10_
MILK ANIMAL MEAT ANIMAL BROTHERS,D 4.917901.8 90 INTERVIEW X 2.30E-0711.20E-1 VEGETATION GROUNDWATER DOTY,J 4.67 7515.6 89 INTERVIEW X 2.30E-07 1.40E-10 F IESE RESIDENCE WILSON ISLAND 4.22 6791.!q 121 INTERVIEW X 2.30E-07 2.60E-1q MILK ANIMAL MEAT ANIMAL VEGETATION GROUNDWATER WILSON ISLAND 4.22 6791.43 121 INTERVIEW X 2.30E-07 2.60E-11 G SE RESIDENCE CARTER,T 1.67 2687.6q 145 INTERVIEW X 1.60E-06 4.80E-0ý MILK ANIMAL MEAT ANIMAL VEGETATION KALIN,W 11.742800.21145 INTERVIEW X 1.50E-06 4.50E-0 GROUNDWATEF SMITH 1.9913202.5 134 INTERVIEW X 1.02E-06 2.97E-0 Page 10 of 14
FORT CALHOUN STATION FC-801 CHEMISTRY FORM 2012 REV I Environmental Land Use Survey Report Page 2 of 3 Sector DIr Land Use Owner Miles Meters Deg Survey Aeroup XOQ DOQ Remarks Technique [
- j __ j H SSE RESIDENCE LOMP .6511046.011631 INTERVIEW [X[ 11.10E-051 5.80E-08_
MILK ANIMAL MEAT ANIMAL HINELINE,R 1.82 2929.01 148 INTERVIEW X 1.OOE-06 5.10E-09 VEGETATION PECHNIK,A .94 1512.74 163 INTERVIEW X 4.80E-06 2.60E-08 GROUNDWATER LOMP .65 1046.0 163 INTERVIEW X 1.1OE-05 5.80E-08 J I S RESIDENCE DOWLER .7311174.8 175 INTERVIEW X 5.70E-06 2.50E-08 MILK ANIMAL MEATANIMAL DICKES,L 2.60 4184.20 170 INTERVIEW X 2.60E-07 9.40E-1C VEGETATION DOWLER .73 1174.81 175 INTERVIEW X 5.70E-06 2.50E-08 GROUNDWATER DOWLER .73 1174.8 175 INTERVIEW X 5.70E-06 2.50E-08 K SSW RESIDENCE D.MILLER .65 1046.07 203 INTERVIEW X 3.40E-06 1.00E-08 MILK ANIMAL MEAT ANIMAL T. DEIN 2.00 3218.6c 189 INTERVIEW X 2.50E-07 6.70E-10 VEGETATION T.DEIN 2.00 3218.6c 189 INTERVIEW X 2.50E-07 6.70E-1C GROUNDWATER D.MILLER .65 1046.07 203 INTERVIEW X 3.40E-06 1.OOE-01 L SW RESIDENCE ROBERTSON,D .73 1174.84 224 INTERVIEW X 3.80E-06 7.20E-09 MILK ANIMAL MEAT ANIMAL ROBERTSON,D .73 1174.81 224 INTERVIEW X 3.80E-06 7.20E-0*
VEGETATION ROBERTSON,D .73 1174.84 224 INTERVIEW X 3.80E-06 7.20E-0*
GROUNDWATER ROBERTSON,D .73 1174.8, 224 INTERVIEW X 3.80E-06 7.20E-0 _
M IWSW RESIDENCE BENSEN,M 1.06 1705.90 257 MAIL SURVEY X 3.60E-06 3.80E-01 MILK ANIMAL MEAT ANIMAL WRICH,B 2.42 3894.61 250 MAIL SURVEY X 4.60E-07 4.20E-1 VEGETATION RUSSELL,D 1.21 1947.311246 MAIL SURVEY Xi 2.50E-06 2.50E-0*
GROUNDWATER BENSEN,M 1.06 1705.9C 257 MAIL SURVEY XI 3.60E-06 3.80E-01 N I W RESIDENCE NIELSEN,D 1.20 1931.21 263 INTERVIEW Xj 2.40E-06 3.80E-0-c MILK ANIMAL MEAT ANIMAL ANDERSON,J 3.25 5230.37 281 INTERVIEW X 2.40E-07 2.80E-1C VEGETATION ASMUSSEN,G 1.30 2092.1- 270 MAIL SURVEY X 1.90E-06 3.OOE-0E GROUNDWATER ANDERSON,J 3.25 5230.37 281 INTERVIEW X_ 2.40E-07 2.80E-1C PWNVý RESIDENCE WACHTER,G 2.27 3653.21[302 INTERVIEW Xj 6.1OE-07 1.10E-0O MILK ANIMAL MEAT ANIMAL WACHTER,G 2.27 3653.21 302 INTERVIEW X 6.1OE-07 1.10E-0*
VEGETATION WACHTER,G 2.27 3653.21302 INTERVIEW X 6.10E-07 1.10E-0 GROUNDWATER WACHTER,G 2.27 3653.21 302 INTERVIEW X j6.10E-07 1.1OE-0ý Page 11 of 14
FORT CALHOUN STATION FC-801 CHEMISTRY FORM 2012 REV I Environmental Land Use Survey Report Page 3 of 3 Sector Dir Land Use Owner Miles Meters Deg Survey A e Group XOQ DOQ Remarks Technique = =
Q NW RESIDENCE HANSEN, R 12 4013862.413181 INTERVIEW _ ____ 6.20E-071 1.70E-09[
MILK ANIMAL MEAT ANIMAL VEGETATION HANSEN, R 2.40 3862. 318 INTERVIEW X 6.20E-07 1.70E-0O GROUNDWATER HANSEN,R 12.40 3862.4,318 INTERVIEW X 6.20E-071 1.70E-09 R JNNW RESIDENCE SHUBERT,B 2.08 3347.41330 INTERVIEW X 9.40E-071 3.40E-0q MILK ANIMAL MEAT ANIMAL SONDERUP 3.73 6002.8* 328 INTERVIEW X 2.60E-07 7.60E-1 VEGETATION SONDERUP 3.73 6002.8. 328 INTERVIEW X 2.60E-07 7.60E-1 GROUNDWATEF SONDERUP 3.73 6002.81 328 INTERVIEW X1 2.60E-07 7.60E-1 Performed bv Reviewed by (1) Approximate age categories in receptor deck for evaluating dose commitment:
Infant 0-1 Yr.
Child 1-11 Yrs.
Teen 12-17 Yrs.
Adult Over 17 Yrs.
Page 12 of 14
0 0
0 Review of Environmental Inc., Quality Assurance Program
- Fort Calhoun Station contracts with Environmental Inc., Midwest Laboratory (vendor
- lab) to perform radioanalysis of environmental samples. Environmental Inc.
- participates in interlaboratory comparison (cross-check) programs as part of its quality control program. These programs are operated by such agencies as the Department of Energy, which supply blind-spike samples such as milk or water
- containing concentrations of radionuclides unknown to the testing laboratory. This
- type of program provides an independent check of the analytical laboratory's
- procedures and processes, and provides indication of possible weaknesses. In addition, Environmental Inc. has its own in-house QA program of blind-spike and
- duplicate analyses.
0
- Vendor in-house spike sampling was performed without a failure and in-house blank analyses were performed within acceptable ranges.
0
- Water sample ERW-1257 was performed in 2012 to determine isotopes of radium.
Determinations for Ra-226 and Ra-228 displayed a high bias. Reanalysis of both samples produced acceptable results. No reason was given for the failures. A new
- test was ordered from ERA to be performed in the first quarter of 2013. That test,
- ERW-6022, failed in February of 2013 again with a high bias. The test was again re-
- performed, and like last year, produced acceptable results. It was determined that interference from short lived radon daughters Pb-214 and Bi-214 was producing the high bias. Allowing decay time removes the bias. Radium analysis is not part of the
- identified and corrected issue.
DOE MAPEP air particulate sample MAAP-738 failed low at 0.14 pCi/filter with an
- acceptable range of 0.36-2.04. The sample was re-analyzed and no alpha activity
- was detected. The sample was counted per enclosed instructions; however the filter
- appears to have been loaded on the wrong side. When the sample was flipped over, gross alpha was determined to be 0.61 pCi/filter in the acceptable range.
- particulate gross beta, which would not be impacted by the misloaded sample, and
OPPD results were not negatively impacted by this vendor identified and corrected issue. DOE air particulate sample MAAP-5046 was performed in the 3rd qtr. Gross
- alpha & gross beta were once again performed satisfactory. Additional gamma scan
- and transuranic analyses were performed. One of the four transuranic tests, for U-
- 233/234, had a high bias. The sample was reanalyzed, with acceptable results.
Uranium analysis is not part of the FCS REMP program. OPPD results were not
- negatively impacted by these vendor identified issues. Gamma counts from control
- or indicator spectrums had plant related nuclides present. A sample geometry
- adjustment was made and the sample recounted. The re-performed analysis was within acceptable limits (6.74).
0
- Page 13 of 14 0
S
S 0
0 0
0 Two failures occurred on analysis of MAPEP soil samples. MASO-744 failed low on Sr-90 (408.4bq/kq) for a range of 440-816 bq/kg. The sample was reanalyzed using 0 additional fuming nitric separations and produced acceptable results. Another soil 0 sample MASO-5043 was performed in the 3 rd quarter and had acceptable Sr-90 results. This soil sample however failed a gamma scan for Co-57(high), it was 0 determined to be an interference from Eu-1 52 being present in the sample. When the scan was corrected for this energy line interference, that 0 result fell within the 0 acceptance band of 0-5. Sr-90 analysis in soil is not part of the FCS REMP S program. OPPD gamma scan results on soil were not negatively impacted by this vendor identified issue.
0 No test results failed both the ERA and DOE methodologies for a given sample type.
0 Reanalysis produced acceptable results. Ordering of additional tests, and successfully testing after fixes were applied, visibly demonstrates the vendor's commitment to reporting and resolving deficiencies.
0 These results indicate the vendor's ability to self-identify and correct any deviations from acceptable or expected results. The test results had no impact on Fort 0 Calhoun samples and were documented as such by the vendor.
0 0
0 0
0 0
0 0
S 0
0 Page 14 of 14
0 0
0 0 *A kTI Environmental, Inc.
S MidestLaboratory 700 Landwehi Road - Northbrook. IL.60062-23 W 0 phone (847) 564-0700 - fax (847) 564-4517 0
S 0
0 0
0 S
0 0
0 APPENDIX A 0 INTERLABORATORY COMPARISON PROGRAM RESULTS 0
S 0
0 0
0 0
0 0
0 0
0 NOTE: Environmental Inc., Midwest Laboratory participates in intercomparison studies administered by Environmental Resources Associates, and serves as a replacement for studies conducted previously 0 by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. Results are reported in Appendix A.TLD Intercomparison results, in-house spikes, blanks, duplicates and 0 mixed analyte performance evaluation program results are also reported. Appendix A is updated four times a year; the complete Appendix is included in March, June, September and December monthly progress reports only.
January through December, 2013
0 0
0 0
- Appendix A 1 Interlaboratory Comparison Proqram Results S
0 Environmental, Inc., Midwest Laboratory has participated in interlaboratory comparison (crosscheck) programs since the formulation of it's quality control program in December 1971. These programs are operated by agencies which supply environmental type samples containing concentrations of radionuclides 0known to the issuing agency but not to participant laboratories. The purpose of such a program is to provide an independent check on a laboratory's analytical procedures and to alert it of any possible problems.
0Participant laboratories measure the concentration of specified radionuclides and report them to the issuing agency. Several months later, the agency reports the known values to the participant laboratories and specifies control limits. Results consistently higher or lower than the known values or outside the control limits indicate a need to check the instruments or procedures used.
Results in Table A-1 were obtained through participation in the environmental sample crosscheck program administered by Environmental Resources Associates, serving as a replacement for studies conducted
S Table A-2 lists results for thermoluminescent dosimeters (TLDs), via International 0Intercomparison 0 of Environmental Dosimeters, when available, and internal laboratory testing.
Table A-3 lists results of the analyses on in-house "spiked" samples for the past twelve months. All samples 0 are prepared using NIST traceable sources. Data for previous years available upon request.
5Table A-4 lists results of the analyses on in-house "blank" samples for the past twelve months. Data for previous years available upon request.
- Table A-5 lists REMP specific analytical results from the in-house "duplicate" program for the past twelve months. Acceptance is based on the difference of the results being less than the sum of the errors.
Complete analytical data for duplicate analyses is available upon request.
- The results in Table A-6 were obtained through participation in the Mixed Analyte Performance Evaluation Program.
5Results in Table A-7 were obtained through participation in the environmental sample crosscheck program administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the Environmental Measurement Laboratory Quality Assessment Program (EML).
0t Attachment A lists the laboratory precision at the 1 sigma level for various analyses. The acceptance criteria
- in Table A-3 is set at +/- 2 sigma.
- Out-of-limit results are explained directly below the result.
0 0
0 0
0
- Al S
0
TABLE A-1. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.
0 S
S Concentration (pCi/L)
Lab Code Date Analysis Laboratory ERA Control 0 Result b Result C Limits Acceptance 0
0 ERW-76 01/07/13 Ra-226 10.04 +/- 0.55 9.91 7.42 -11.60 Pass 0 ERW-76 01/07/13 Ra-228 6.11 +/- 1.29 5.22 3.14 -6.96 Pass ERW-76 01/07/13 Uranium 5.90 +/- 0.58 5.96 4.47 -7.13 Pass 0
ERW-1593 04/08/13 Sr-89 43.60 +/- 4.32 41.30 31.60 - 48.40 Pass 0 ERW-1593 04/08/13 Sr-90 23.20 +/- 1.70 23.90 17.20 - 28.00 Pass ERW-1 596 04/08/13 Ba-133 74.80 +/- 4.00 82.10 69.00 - 90.30 Pass 0 ERW-1596 ERW-1596 04/08/13 04/08/13 Co-60 65.50 +/- 3.42
+/- 3.47 65.90 59.30 - 75.00 Pass Cs-134 41.10 42.80 34.20 - 47.10 Pass ERW-1 596 04/08/13 Cs-137 42.30 +/- 4.03 41.70 37.00 - 48.80 Pass 0 ERW-1 596 04/08/13 Zn-65 200.3 +/- 10.1 189.0 170.0 - 222.0 Pass 0 ERW-1 598 04/08/13 Gr. Alpha 34.30 +/- 1.98 40.80 21.10 - 51.90 Pass 0 ERW-1 598 ERW-1600 04/08/13 04/08/13 Gr. Beta 1-131 18.70 23.00
+/- 0.98
+/- 1.10 21.60 23.80 13.00 19.70
- 29.70
- 28.30 Pass Pass ERW-1600 04/08/13 1-131(G) 23.48 +/- 9.44 23.80 19.70 - 28.30 Pass 0 ERW-1605 04/08/13 Ra-226 16.30 +/- 0.70 15.40 11.50 - 17.70 Pass 0 ERW-1605 04/08/13 Ra-228 5.32 +/- 1.30 4.36 2.54 - 5.98 Pass ERW-1605 04/08/13 0 ERW-1606 04/08/13 Uranium H-3 57.30 4041
+/- 4.20
+/- 194 61.20 4050 49.80 3450
- 67.90
- 4460 Pass Pass S
0 ERW-6009 10/07/13 Sr-89 22.00 +/- 2.80 21.90 14.40 +/- 28.20 Pass 0 ERW-6009 10/07/13 Sr-90 17.10 +/- 2.55 18.10 12.80 +/- 21.50 Pass ERW-6012 10/07/13 Ba-133 48.20 +/- 4.29 54.20 44.70 +/- 59.90 Pass 0 ERW-6012 10/07/13 Co-60 100.8 +/- 4.7 102.0 91.80 +/- 114.00 Pass ERW-6012 10/07/13 Cs-134 87.30 +/- 4.35 86.70 71.10 +/- 95.40 Pass 0 ERW-6012 10/07/13 Cs-137 199.6 +/- 7.4 206.0 185.0 - 228.0 Pass ERW-6012 10/07/13 Zn-65 356.2 + 13.2 333.0 300.0 - 389.0 Pass ERW-6015 10/07/13 Gr. Alpha 30.70 +11.90 42.80 22.20 +/- 54.30 Pass 0 ERW-6015 10/07/13 Gr. Beta 25.70 +/- 6.48 32.20 20.80 +/- 39.90 Pass 0 ERW-6019 ERW-6022 10/07/13 10/07/13 1-131 Ra-226 22.50 12.70
+/- 1.01 23.60 19.60 +/- 28.00 Pass
+ 1.62 12.10 9.04 +/- 14.00 Pass d
ERW-6022 10/07/13 Ra-228 5.70 +/- 0.56 4.02 2.30 +/- 5.59 Fail ERW-6022 10/07/13 Uranium 6.59 +/- 0.38 6.24 4.70 +/- 7.44 Pass 0 ERW-6024 10/07/13 H-3 18397 +/- 695 17700 15500 - 19500 Pass 0
0 Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency 0 testing in drinking water conducted by Environmental Resources Associates (ERA).
0 b Unless otherwise indicated, the laboratory result is given as the mean
- standard deviation for three determinations.
C Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits as provided by ERA.
d The reported result was obtained in the first cycle of counting. It can be positively biased due to extra beta counts contributed by Pb-214 and Bi-214 daughters of Rn-222. Result of second cycle of counting 4.47 pCi/L.
A1-1
0 S
0 0
S Attachment A ACCEPTANCE CRITERIA FOR "SPIKED" SAMPLES 0
S LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSESa 0 One standard deviation Analysis Level for single determination Gamma Emitters 5 to 100 pCi/liter or kg 5.0 pCi/liter
> 100 pCi/liter or kg 5% of known value Strontium-89b 5 to 50 pCi/liter or kg 5.0 pCi/liter
> 50 pCi/liter or kg 10% of known value 2 to 30 pCi/liter or kg 5.0 pCi/liter Strontium-90b
> 30 pCi/liter or kg 10% of known value Potassium-40 a 0.1 g/liter or kg 5% of known value Gross alpha 5 20 pCi/liter 5.0 pCi/liter
> 20 pCi/liter 25% of known value Gross beta < 100 pCi/liter 5.0 pCi/liter
> 100 pCi/liter 5% of known value 0 Tritium 5 4,000 pCi/liter +la =
0 33 0 169.85 x (known) °9
> 4,000 pCi/liter 10% of known value 0
0 Radium-226,-228 > 0.1 pCi/liter 15% of known value 0 Plutonium a 0.1 pCi/liter, gram, or sample 10% of known value 0
Iodine-1 31, < 55 pCi/liter 6 pCi/liter 0 Iodine-1 2 9 b > 55 pCi/liter 10% of known value Uranium-238, < 35 pCi/liter 6 pCi/liter Nickel-63b > 35 pCi/liter 15% of known value Technetium-99b S Iron-55b 50 to 100 pCi/liter 10 pCi/liter
> 100 pCi/liter 10% of known value 0
0 Other Analyses b 20% of known value 0
S 0 From EPA publication, "Environmental Radioactivity Laboratory Intercomparison Studies 0 b Program, Fiscal Year, 1981-1982, EPA-600/4-81-004.
Laboratory limit.
S 0 A2 0
0 S
0 S
0 TABLE A-2. Thermoluminescent Dosimetry, (TLD, CaSO 4 : Dy Cards).
S 0 mR Lab Code Date Known Lab Result Control 0 Description Value +/- 2 sigma Limits Acceptance 0 Environmental, Inc.
0 0
2013-1 5/6/2013 40 cm. 34.26 39.92 +/- 2.67 23.98 - 44.54 Pass 0 2013-1 5/6/2013 50 cm. 21.93 25.44 +/- 3.31 15.35 - 28.51 Pass 0 2013-1 5/6/2013 60 cm. 15.23 15.88 +/- 1.12 10.66 - 19.80 Pass 0 2013-1 5/6/2013 70 cm. 11.19 10.89 +/- 0.66 7.83 - 14.55 Pass 2013-1 5/6/2013 80 cm. 8.57 9.21 +/- 0.41 6.00-11.14 Pass 0 2013-1 5/6/2013 90 cm. 6.77 6.52 +/- 0.34 4.74 - 8.80 Pass 0 2013-1 5/6/2013 100 cm. 5.48 5.02 +/- 0.53 3.84 -7.12 Pass 0 2013-1 5/6/2013 110 cm. 4.53 4.51 +/- 0.34 3.17 -5.89 Pass 2013-1 5/6/2013 120 cm. 3.81 4.28 +/- 0.35 2.67 - 4.95 Pass 2013-1 5/6/2013 135 cm. 3.01 2.64 +/- 0.18 2.11 -3.91 Pass 2013-1 5/6/2013 150 cm. 2.44 2.10 +/- 0.25 1.71 -3.17 Pass 2013-1 5/6/2013 180 cm. 1.69 1.78 +/- 0.33 1.18 -2.20 Pass Environmental, Inc.
0 0
201 3-2 11/18/2013 50 cm. 19.93 22.75 +/- 3.67 13.95 - 25.91 Pass 0 2013-2 11/18/2013 60 cm. 13.84 15.75 +/- 1.94 9.69 - 17.99 Pass 0 2013-2 11/18/2013 70 cm. 10.17 11.24 +/- 0.88 7.12 - 13.22 Pass 0 2013-2 11/18/2013 75 cm. 8.86 9.18 +/- 1.23 6.20-11.52 Pass 0 2013-2 2013-2 11/18/2013 11/18/2013 80 cm.
90 cm.
7.79 6.15 7.81 +/- 1.10 5.98 +/- 0.90 5.45 - 10.13 4.31 - 8.00 Pass Pass 0 2013-2 11/18/2013 100 cm. 4.98 5.13 +/- 0.73 3.49 - 6.47 Pass 0 2013-2 11/18/2013 110 cm. 4.12 3.87 +/- 0.32 2.88 - 5.36 Pass 0 2013-2 11/18/2013 120 cm. 3.46 3.11 +/-0.39 2.42 - 4.50 Pass 2013-2 11/18/2013 135 cm. 2.73 2.71 +/- 0.83 1.91 - 3.55 Pass 0 2013-2 11/18/2013 150 cm. 2.21 2.11 +/- 0.63 1.55 -2.87 Pass 0 2013-2 11/18/2013 180 cm. 1.54 1.81 +/- 0.10 1.08 - 2.00 Pass 0
0 0
0 0
0 0
A2-1 0
0
0 S
S 0 TABLE A-3. In-House "Spiked" Samples S
0 Concentration (pCi/L)a 0 Lab Code b Date Analysis Laboratory results Known Control 2s, n=1 c Activity Limitsd Acceptance 0
0 SPW-66 1/9/2013 Tc-99 1009 +/- 5 1078 754.9 - 1402.0 Pass S SPW-1891 1/18/2013 Ra-228 35.60 +/- 2.75 30.85 21.60 - 40.11 Pass 0 SPSO-12313S 1/23/2013 Tc-99 103.5 +/- 2.2 107.8 75.46 - 140.14 Pass SPMI-264 1/25/2013 Cs-134 110.9 +/-_6.7 107.5 96.73 - 118.23 Pass 0 SPMI-264 1/25/2013 Cs- 137 82.84 +/- 7.47 77.48 67.48 - 87.48 Pass 0 SPMI-264 1/25/2013 Sr-90 38.19 +/- 1.49 40.11 32.09 - 48.13 Pass SPW-266 1/25/2013 Co-60 46.89 +/- 4.68 44.48 34.48 - 54.48 Pass 0 SPW-266 1/25/2013 Cs-134 105.9 +/- 8.0 107.5 96.73 - 118.23 Pass SPW-266 1/25/2013 Cs-1 37 42.17 +/- 5.65 39.49 29.49 - 49.49 Pass 0 SPW-266 1/25/2013 Sr-90 39.84 +/- 1.65 40.11 32.09 - 48.13 Pass SPAP-376 2/1/2013 Gr. Beta 44.20 +/- 0.11 45.68 27.41 - 63.95 Pass 0 SPAP-378 2/1/2013 Cs- 134 3.71 +/- 0.65 3.87 2.32 - 5.42 Pass SPAP-378 2/1/2013 Cs-137 97.47 +/- 2.50 102.9 92.61 - 113.19 Pass 0 SPW-391 2/1/2013 H-3 63719 +/- 703 65626 52501 -78751 Pass SPW-380 2/10/2013 Ni-63 217.0 +/- 3.7 205.3 143.7 - 266.9 Pass W-30413 3/4/2013 Gr. Alpha 19.77 +/- 0.40 20.00 10.00 - 30.00 Pass 0 W-30413 3/4/2013 Gr. Beta 30.48 +/- 0.34 30.90 20.90 - 40.90 Pass W-30713 3/7/2013 Ra-226 18.06 +/- 0.51 16.70 11.69 - 21.71 Pass 0
W-42713 4/27/2013 Gr. Alpha 20.67 +/- 0.40 20.00 10.00 - 30.00 Pass W-42713 4/27/2013 Gr. Beta +/- 0.32 Pass 0 WW-2870 5/7/2013 Co-60 28.44 166.1 +/- 7.4 30.90 161.6 20.90 - 40.90 145.4 - 177.8 Pass 0 WW-2870 5/7/2013 Cs-137 161.2 +/- 9.3 149.0 134.1 - 163.9 Pass WW-2870 5/7/2013 H-3 6853 +/- 250 6735 5388 - 8082 Pass 0 W-53113 5/31/2013 Ra-226 16.83 +/- 0.41 16.70 11.69 - 21.71 Pass 0 SPAP-3332 6/19/2013 Am-241 4.60 +/- 0.14 4.00 2.40 - 5.60 Pass SPW-3334 6/19/2013 Th-230 4.36 +/- 0.34 4.00 2.40-5.60 Pass SPW-3458 6/24/2013 C-14 3825 +/- 13 4736 2842 - 6630 Pass 0 SPAP-3529 6/27/2013 Cs-1 34 3.49 +/- 1.26 3.30 1.98 - 4.62 Pass 0 SPAP-3529 6/27/2013 Cs-137 102.0 +/- 2.9 101.1 90.99 - 111.21 Pass SPAP-3531 6/27/2013 Gr. Beta 45.64 +/- 0.11 45.42 27.25 - 63.59 Pass 0 SPF-3533 6/27/2013 Cs- 134 1.31 +/- 0.14 1.50 0.90 -2.10 Pass S SPF-3533 SPW-3535 6/27/2013 6/27/2013 Cs-1 37 Ni-63 2.77 204.3
+/- 0.27
+/- 3.5 2.43 204.8 1.46 - 3.40 143.4 - 266.2 Pass Pass 0 SPW-3537 6/27/2013 Tc-99 104.5 +/- 1.7 107.8 75.46 - 140.14 Pass SPW-3539 Fe-55 0 SPW-1893 6/27/2013 6/28/2013 Ra-228 97015 30.16
+/- 860
-2.73 90677 30.85 72542 - 108812 21.60 - 40.11 Pass Pass 0
0 A3-1
S 0
0 TABLE A-3. In-House "Spiked" Samples 0
0 Concentration (pCi/L)a 0 Lab Code b Date Analysis Laboratory results Known Control 2s, n=1 c Activity Limits d Acceptance S
0 SPW-72913S 7/29/2013 Tc-99 126.6 +/- 2.2 107.8 75.46 +/- 140.14 Pass SPW-4373 7/31/2013 Cs-134 91.71 +/- 6.02 90.94 80.94 +/- 100.94 Pass SPW-4373 7/31/2013 Cs-137 83.05 +/- 7.20 76.57 66.57 +/- 86.57 Pass 0 SPW-4373 7/31/2013 Sr-90 39.28 +/- 1.77 39.64 31.71 +/- 47.57 Pass SPW-4374 7/31/2013 Sr-90 42.17 +/- 1.71 39.64 31.71 +/- 47.57 Pass 0 SPMI-4376 SPMI-4376 7/31/2013 7/31/2013 Cs-1 34 Cs-137 82.22 83.31
- 7.23
- 8.29 90.94 76.57 80.94 66.57
+/- 100.94
+/- 86.57 Pass Pass S SPMI-4376A 7/31/2013 Sr-90 35.00 +/- 1.63 39.64 31.71 +/- 47.57 Pass S W-73113 SPS-4514 7/31/2013 8/5/2013 Ra-226 Sr-90 17.61 78.63
+/- 0.41
+/- 2.95 16.70 79.28 11.69 63.42
+/- 21.71
+/- 95.14 Pass Pass W-82013 8/20/2013 Gr. Alpha 21.53 +/- 0.45 20.00 10.00 +/- 30.00 Pass 0 W-82013 8/20/2013 Gr. Beta 28.03 +/- 0.32 30.90 20.90 +/- 40.90 Pass 0 SPW-1894 8/28/2013 Ra-228 32.49 +/- 3.00 30.85 21.60 +/- 40.11 Pass W-90913 9/9/2013 Gr. Alpha 19.08 +/- 0.51 20.10 10.05 +/- 30.15 Pass S W-90913 9/9/2013 Gr. Beta 32.12 +/- 0.35 32.10 22.10 +/- 42.10 Pass 0
0 WW-5623 WW-5623 10/3/2013 10/3/2013 Co-60 Cs-137 157.0 156.0
+/-
+/-
7.0 8.8 155.3 148.1 139.8 133.3
- 170.8
- 162.9 Pass Pass S WW-5623 10/3/2013 H-3 6590 +/- 245 6322 5058 - 7586 Pass 10/3/2013 0 WW-5750 WW-5750 10/3/2013 Co-60 Cs-137 87.00 82.30
+/-
+/-
7.80 7.80 77.40 78.80 77.00 68.80
+/- 97.00
+/- 88.80 Pass Pass WW-5750 10/3/2013 H-3 6181 +/- 238 6322 5058 - 7586 Pass 0 W-102813 10/28/2013 Ra-226 15.69 +/- 0.37 16.70 11.69 +/- 21.71 Pass 0 SPW-1898 12/17/2013 Ra-228 28.15 +/- 2.37 30.85 21.60 +/- 40.11 Pass W-122313 12/23/2013 Gr. Alpha 20.96 +/- 0.47 20.10 10.05 +/- 30.15 Pass 0 W-122313 12/23/2013 Gr. Beta 31.00 +/- 0.34 32.10 22.10 +/- 42.10 Pass 0
0 0
0 S
0 0
0 8 Liquid sample results are reported in pCi/Uter, air filters( pCi/m 3), charcoal (pCilcharcoal canister), and solid samples (pCi/kg).
b Laboratory codes : W (Water), MI (milk), AP (air filter), SO (soil), VE (vegetation), CH (charcoal canister), F (fish), U (urine).
0 c Results are based on single determinations.
d Control limits are established from the precision values listed in Attachment A of this report, adjusted to +/- 2s.
NOTE: For fish, Jello is used for the Spike matrix. For Vegetation, cabbage is used for the Spike matrix.
A3-2
0 0
0 0 TABLE A-4. In-House "Blank" Samples 0 Concentration (pCi/L)a 0 Lab Code Sample Date Analysisb Laboratory results (4.66ca) Acceptance Type LLD Activityc Criteria (4.66 cv)
S SPW-67 Water 1/9/2013 Tc-99 1.10 0.69 +/- 0.68 10 0 SPW-190 Water 1/18/2013 Ra-228 0.74 0.66 +/- 0.43 2 0 SPW-1901 SPMI-263 Water Milk 1/18/2013 1/25/2013 Ra-228 Sr-90 0.74 0.64 0.66 0.31
+/- 0.43
+/- 0.34 2
1 0 SPMI-263 Milk 1/25/2013 Sr-90 0.64 0.31 +/- 0.34 1 0 SPW-265 SPW-265 Water Water 1/25/2013 1/25/2013 Co-60 Cs-134 2.86 2.98 2.10 2.25
+/- 1.72
+/- 1.57 10 10 SPW-265 Water 1/25/2013 Cs-1 37 2.71 0.44 +/- 1.61 10 0 SPW-266 Water 1/25/2013 Sr-90 0.72 -0.12 +/- 0.32 1 0 SPAP-375 Air Filter 2/1/2013 Gr. Beta 0.003 0.016 +/- 0.003 0.010 SPAP-377 Air Filter 2/1/2013 Co-60 2.31 -0.34 +/- 1.75 100 SPAP-377 Air Filter 2/1/2013 Cs-134 2.72 1.22 +/- 1.62 100 SPAP-377 Air Filter 211/2013 Cs-137 1.50 -0.52 +/- 1.80 100 SPW-391 Water 2/1/2013 H-3 92.04 -29.44 +/- 69.24 200 0 SPW-379 Water 2/10/2013 Ni-63 2.11 0.91 +/- 1.30 20 S W-30413 Water 3/4/2013 Gr. Alpha 0.35 0.08 +/- 0.26 1 W-30413 Water 3/4/2013 Gr. Beta 0.73 0.10 +/- 0.51 3.2 0 W-30713 Water 3/7/2013 Ra-226 0.031 0.032 +/- 0.024 1 0
0 W-42713 Water 4/27/2013 Gr. Alpha 0.45 -0.14 +/- 0.30 1 W-42713 Water 4/27/2013 Gr. Beta 0.72 -0.23 +/- 0.50 3.2 0 W-53113 Water 5/31/2013 Ra-226 0.03 0.01 +/- 0.02 1 0 SPW-3335 Water 6/19/2013 Th-230 0.01 0.01 +/- 0.01 1 SPW-3459 Water 6/24/2013 C-14 10.89 10.44 +/- 6.82 200 0 SPAP-3528 Air Filter 6/27/2013 Cs-134 2.10 -0.98 +/- 1.11 100 0 SPAP-3528 Air Filter 6/27/2013 Cs-137 2.71 -0.24 +/- 1.36 100 SPAP-3530 Air Filter 6/27/2013 Gr. Beta 0.004 0.018 +/- 0.003 0.010 0 SPF-3532 Fish 6/27/2013 Cs-134 8.38 -1.39 +/- 5.69 100 SPF-3532 Fish 6/27/2013 Cs-137 8.37 -1.88 +/- 6.41 100 0 SPW-3534 Water 6/27/2013 Ni-63 2.47 -1.04 +/- 1.48 20 SPW-3536 Water 6/27/2013 Tc-99 1.15 -1.11 +/- 0.68 10 SPW-3538 water 6/27/2013 Fe-55 170.27 -17.50 +/- 102.70 1000 0 SPW-1903 Water 6/28/2013 Ra-228 0.85 -0.02 +/- 0.39 2 S
0 0
0 A4-1
0 0
0 0
0 TABLE A-4. In-House "Blank" Samples 0
0 Concentration (pCi/L)a Lab Code Sample Date Analysis' Laboratory results (4.66c) Acceptance LLD Activityc Criteria (4.66 c) 0 Type 0
0 SPW-72913B SPW-4372 Water Water 7/29/2013 7/31/2013 Tc-99 Co-60 1.44 1.41
-0.33
-1.42
+/- 0.87
+/- 3.00 10 10 0 SPW-4372 Water 7/31/2013 Cs-134 3.68 -2.66 +/- 3.46 10 S SPW-4372 SPMI-4375 Water Milk 7131/2013 7/31/2013 Cs-137 Co-60 3.53 3.92 0.29 2.65
+/- 3.31
+/- 2.26 10 10 0 SPMI-4375 Milk 7/31/2013 Cs-134 4.67 0.68 +/- 2.54 10 0 SPMI-4375 Milk Milk 7/31/2013 7/31/2013 Cs-137 Sr-90 4.79 0.57 1.30 0.32
+/- 2.68
+/- 0.30 10 1
SPMI-4375 W-73113 Water 7/31/2013 Ra-226 0.02 0.04 +/- 0.02 1 0 SPS-4515 Powder Water 8/5/2013 8/20/2013 Sr-90 Gr. Alpha 0.09 0.42
-0.01
-0.15
+/- 0.04
+/- 0.28 1
1 W-82013 0 W-82013 Water 8/20/2013 Gr. Beta 0.74 -0.24 +/- 0.51 3.2 0 SPW-1904 Water 8/28/2013 9/9/2013 Ra-228 0.96 0.85 +/- 0.56 2 1
CHW-90913 Water Gr. Alpha 0.25 0.20 +/- 0.29 0 CHW-90913 Water 9/9/2013 Gr. Beta 0.49 -0.18 +/- 0.53 3.2 CHW-102013 Water 10/20/2013 Gr. Alpha 0.29 0.24 +/- 0.33 1 CHW-102013 Water 10/20/2013 Gr. Beta 0.54 -0.32 +/- 0.54 3.2 W-102813 Water 10/28/2013 Ra-226 0.02 0.02 +/- 0.01 1 SPW-1908 Water 12/1712013 Ra-228 0.69 - 0.55 +/- 0.39 2 CHW-122313 Water 12/23/2013 Gr. Alpha 0.25 -0.09 +/- 0.26 1 CHW-122313 Water 12/23/2013 Gr. Beta 0.48 0.05 +/- 0.53 3.2 CHW-122713 Water 12/27/2013 Gr. Alpha 0.28 0.04 +/- 0.31 1 CHW-122713 Water 12/27/2013 Gr. Beta 0.49 -0.33 +/- 0.53 3.2 0 B Liquid sample results are reported in pCi/Liter, air filters( pCi/m 3). charcoal (pCi/charcoal canister), and solid samples (pCi/kg).
0 b 1-131(G); iodine-131 as analyzed by gamma spectroscopy.
r Activity reported is a net activity result.
0 0
0 0
0 0
0 0 A4-2 0
0 0
0 TABLE A-5. In-House "Duplicate" Samples 0
S Concentration (pCi/L)a S Averaged 0 Lab Code Date Analysis First Result Second Result Result Acceptance 0 CF-41, 42 1/2/2013 Gr. Beta 8.45 +/- 0.37 7.90 +/- 0.35 8.17 +/- 0.26 Pass CF-41, 42 1/2/2013 Sr-90 0.030 +/- 0.015 0.029 +/- 0.014 0.030 +/- 0.010 Pass S SWT-8243, 8244 1/2/2013 Gr. Beta 1.07 +/- 0.54 0.98 +/- 0.51 1.03 +/- 0.37 Pass 0 AP-8454, 8455 1/2/2013 Be-7 0.053 +/- 0.010 0.042 +/- 0.010 0.048 +/- 0.007 Pass AP-8517, 8518 1/3/2013 Be-7 0.051 +/- 0.015 0.049 +/- 0.017 0.050 +/- 0.011 Pass 0 MI-62, 63 1/8/2013 K-40 1317.70 +/- 91.70 1351.90 +/- 72.50 1334.80 +/- 58.45 Pass WW-151, 152 1/8/2013 H-3 222.70 +/- 81.00 289.70 +/- 84.10 256.20 +/- 58.38 Pass 0 SG-107, 108 1/11/2013 Ra-226 55.20 +/- 5.53 58.60 +/- 5.94 56.90 +/- 4.06 Pass 0 SG-107, 108 1/11/2013 Ra-228 71.60 +/- 1.10 74.30 +/- 1.70 72.95 +/- 1.01 Pass SG-130, 131 1/14/2013 Ra-226 3.91 +/- 0.20 3.45 +/- 0.27 3.68 +/- 0.17 Pass 0 SG-130, 131 1/14/2013 Ra-228 2.40 +/- 0.33 2.70 +/- 0.39 2.55 +/- 0.26 Pass 0 WW-277,278 1/17/2013 H-3 159.71 +/- 77.91 196.57 +/- 79.72 178.14 +/- 55.73 Pass WW-256, 257 1/22/2013 H-3 502.70 +/- 93.40 483.30 +/- 92.60 493.00 +/- 65.76 Pass 0 DW-40010, 40011 1/24/2013 Ra-226 2.55 +/- 0.18 2.86 +/- 0.20 2.71 +/- 0.13 Pass 1/24/2013 Pass 0 DW-40010, 40011 SWT-361, 362 1/29/2013 Ra-228 Gr. Beta 1.78 0.90
+/- 0.62
+/- 0.40 2.22 +/- 0.62 1.01 +/- 0.38 2,00 0.96
+/- 0.44
+/- 0.28 Pass DW-484, 485 1/29/2013 Gr. Beta 14.85 +/- 1.93 14.81 +/- 2.06 14.83 +/- 1.41 Pass 0 S-945, 946 1/29/2013 Cs-137 14.50 +/- 0.18 14.45 +/- 0.19 14.48 +/- 0.13 Pass S-945, 946 1/29/2013 K-40 7.90 +/- 0.74 8.00 +/- 0.73 7.95 +/- 0.52 Pass 0 S-340, 341 1/31/2013 Cs-137 0.16 +/- 0.05 0.15 +/- 0.06 0.15 +/- 0.04 Pass 0 S-340, 341 1/31/2013 K-40 17.35 +/- 1.34 19.75 +/- 1.25 18.55 +/- 0.92 Pass AP-463, 464 1/31/2013 Be-7 0.27 +/- 0.10 Pass 0 MI-631, 632 2/13/2013 K-40 1350.50 +/- 105.20 0.26 +/- 0.10 1413.70 +/- 85.94 0.26 1382.10
+/- 0.07
+/- 67.92 Pass 0 WW-769, 770 2/25/2013 Gr. Beta 1.20 +/- 0.33 1.35 +/- 0.34 1.28 +/- 0.24 Pass 0 DW-736, 737 2/26/2013 Gr. Beta 1.09 +/- 0.54 1.57 +/- 0.58 1.33 +/- 0.40 Pass SWU-790, 791 2/26/2013 Gr. Beta 2.68 +/- 0.96 2.08 +/- 0.95 2.38 +/- 0.67 Pass 0 W-925, 926 2/27/2013 H-3 2265.00 +/- 153.00 2329.00 +/- 154.00 2297.00 +/- 108.54 Pass 0 AP-1034, 1035 3/7/2013 Be-7 0.17 +/- 0.08 0.16 +/- 0.09 0.17 +/- 0.06 Pass MI-1076, 1077 3/13/2013 K-40 1347.70 +/- 99.32 1396.10 +/- 108.00 1371.90 +/- 73.36 Pass 0 CH-1118, 1119 3/14/2013 1-131 (G) 109.41 +/- 5.69 103.88 +/- 7.76 106.65 +/- 4.81 Pass WW-1221, 1222 3/14/2013 H-3 452.11 +/- 97.43 403.29 +/- 95.46 427.70 +/- 68.20 Pass S P-1368, 1369 3/15/2013 H-3 735.24 +/- 113.99 666.04 +/- 111.41 700.64 +/- 79.70 Pass 0 DW-40017, 40018 3/19/2013 Gr. Alpha 1.43 +/- 0.94 1.61 +/- 1.00 1.52 +/- 0.69 Pass 0 M1-1473, 1474 4/1/2013 K-40 1618.00 +/- 107.00 1767.00 +/- 129.00 1692.50 +/- 83.80 Pass AP-2014, 2015 4/1/2013 Be-7 0.055 +/- 0.008 0.057 +/- 0.006 0.056 +/- 0.005 Pass 0 DW-40023, 40024 4/1/2013 Ra-226 2.29 + 0.18 2.54 +/- 0.20 2.42 +/- 0.13 Pass DW-40023, 40024 4/1/2013 Ra-228 2.99 + 0.69 2.96 +/- 0.67 2.98 +/- 0.48 Pass 0 SWU-736, 737 4/2/2013 4/2/2013 Gr. Beta 4.80 +/- 0.95 4.43 +/- 0.86 4.62 +/- 0.64 Pass AP-2035, 2036 Be-7 0.070 +/- 0.013 0.065 +/- 0.013 0.068 +/- 0.009 Pass 0 BS-1680, 1681 4/8/2013 K-40 1995.30 +/- 265.70 1992.00 +/- 289.40 1993.65 +/- 196.44 Pass 0 SW-1638, 1639 4/9/2013 H-3 1350.77 +/- 130.08 1320.45 +/- 129.25 1335.61 +/- 91.69 Pass 0
A5-1
0 0
0 TABLE A-5. In-House "Duplicate" Samples 0
S Concentration (pCi/L)a 0 Averaged Lab Code Date Analysis First Result Second Result Result Acceptance 0
0 WW-2394, 2395 4/9/2013 H-3 348.08 +/- 88.40 302.43 +/- 86.41 325.25 +/- 61.81 Pass DW-40035, 40036 4/12/2013 Ra-226 1.36 +/- 0.15 1.29 +/- 0.13 1.33 +/- 0.10 Pass 0 DW-40035, 40036 4/12/2013 Ra-228 1.22 +/- 0.49 1.38 +/- 0.53 1.30 +/- 0.36 Pass 0 MI-1825, 1826 4/15/2013 K-40 1290.20 +/- 113.80 1378.60 +/- 91.99 1334.40 +/- 73.17 Pass S M1-1825, 1826 4/15/2013 Sr-90 0.68 + 0.32 0.46 +/- 0.31 0.57 +/- 0.22 Pass DW-40049, 40050 4/15/2013 Gr. Alpha 1.88 +/- 0.69 2.51 +/- 0.71 2.20 +/- 0.50 Pass WW-1909, 1910 4/16/2013 H-3 2145.68 +/- 156.65 2108.32 +/- 155.80 2127.00 +/- 110.47 Pass 0 DW-40064, 40065 4/23/2013 Gr. Alpha 1.95 +/- 0.79 1.80 +/- 0.81 1.88 +/- 0.57 Pass DW-40066, 40067 4/23/2013 Ra-226 1.98 +/- 0.17 1.66 +/- 0.16 1.82 +/- 0.12 Pass 0 DW-40066, 40067 4/23/2013 Ra-228 2.30 +/- 0.59 2.32 +/- 0.59 2.31 +/- 0.42 Pass F-2225, 2226 5/1/2013 K-40 2.81 +/- 0.37 2.67 +/- 0.39 2.74 +/- 0.27 Pass 0 BS-2267, 2268 5/11/2013 K-40 13.46 +/- 0.64 13.59 +/- 0.62 13.52 +/- 0.45 Pass SG-2235, 2236 5/2/2013 Ac-228 18.30 +/- 0.60 18.50 +/- 0.60 18.40 +/- 0.42 Pass 0 SG-2235, 2236 5/2/2013 Gr. Alpha 54.00 +/- 3.70 51.90 +/- 3.40 52.95 +/- 2.51 Pass 0 SG-2235, 2236 5/2/2013 Pb-214 11.30 +/- 0.30 11.20 +/- 0.20 11.25 +/- 0.18 Pass AP-2288, 2289 5/2/2013 Be-7 0.19 +/- 0.10 0.19 +/- 0.08 0.19 +/- 0.07 Pass S WW-3091, 3092 5/2/2013 H-3 1107.91 +/- 153.49 1263.37 +/- 157.43 1185.64 +/- 109.94 Pass 0 SW-2373, 2374 5/8/2013 H-3 324.80 +/- 86.81 364.61 +/- 88.53 344.71 +/- 62.00 Pass W-2352,2353 5/9/2013 Ra-226 +/- 0.20 Pass 0 W-2352,2353 5/9/2013 Ra-228 0.91 1.28 +/- 0.87 1.29 1.03
+/- 0.22
+/- 0.94 1.10 1.16
+/- 0.15
+/- 0.64 Pass 0 CF-2499, 2500 5/13/2013 K-40 11.52 +/- 0.45 12.55 +/- 0.61 12.04 +/- 0.38 Pass 0 F-3987, 3988 5/20/2013 K-40 3.07 +/- 0.48 3.05 +/- 0.43 3.06 +/- 0.32 Pass BS-4113, 4114 5/20/2013 K-40 8.06 +/- 0.44 7.99 +/- 0.44 8.02 +/- 0.31 Pass 0 SO-2902, 2903 SO-2902, 2903 5/22/2013 5/22/2013 Th-228 Th-230 0.57 0.39
+/- 0.07
+/- 0.06 0.51 0.40
+/- 0.06
+/- 0.05 0.54 0.40
+/- 0.05
+/- 0.04 Pass Pass SO-2902, 2903 5/22/2013 Th-232 0.55 +/- 0.07 0.62 +/- 0.06 0.59 +/- 0.05 Pass 0 WW-2776,2777 5/23/2013 H-3 261.76 +/- 100.85 283.17 +/- 101.68 272.46 +/- 71.61 Pass 0 WW-2818,2819 5/23/2013 H-3 999.35 +/- 126.15 880.63 +/- 122.43 939.99 +/- 87.90 Pass 0 S-7271,7272 5/27/2013 5/27/2013 Cs-137 2.82 +/- 0.10 2.91 +/- 0.09 2.86 +/- 0.07 Pass S-7271, 7272 K-40 21.52 +/- 0.97 21.13 +/- 1.02 21.32 +/- 0.70 Pass 0 P-2923, 2924 5/29/2013 H-3 441.31 +/- 92.75 374.30 +/- 89.94 407.80 +/- 64.60 Pass 0 WW-3133,3134 6/1/2013 H-3 278.42 +/- 86.54 209.45 +/- 83.44 243.93 +/- 60.11 Pass WW-3049,3050 6/5/2013 H-3 156.08 +/- 79.16 244.66 +/- 83.86 200.37 +/- 57.66 Pass 0 DW-40079, 40080 6/5/2013 Ra-226 6.67 +/- 0.30 7.03 +/- 0.35 6.85 +/- 0.23 Pass DW-40079, 40080 6/5/2013 Ra-228 5.55 +/- 0.75 6.11 +/- 0.77 5.83 +/- 0.54 Pass S DW-40089, 40090 6/5/2013 Gr. Alpha 6.82 +/- 0.90 5.64 +/- 1.02 6.23 +/- 0.68 Pass 0 DW-40091, 40092 6/5/2013 Ra-226 3.44 +/- 0.19 3.66 +/- 0.19 3.55 +/- 0.13 Pass DW-40091, 40092 6/5/2013 Ra-228 3.70 +/- 0.68 4.69 +/- 0.73 Pass 0 DW-40103, 40104 6/5/2013 Ra-226 0.98 +/- 0.22 0.62 +/- 0.15 4.20 0.80
+/- 0.50
+/- 0.13 Pass MI-3154,3155 6/12/2013 K-40 1513.00 +/- 128.10 1456.70 +/- 110.30 1484.85 +/- 84.52 Pass P-3385, 3386 6/14/2013 H-3 236.88 +/- 87.87 242.87 +/- 88.14 239.88 +/- 62.23 Pass 0 F-3776, 3777 6/16/2013 Cs-137 0.039 +/- 0.015 0.048 +/- 0.019 0.044 +/- 0.012 Pass F-3776, 3777 6/16/2013 Gr. Beta 4.52 +/- 0.09 4.63 +/- 0.09 4.57 +/- 0.06 Pass F-3776, 3777 6/16/2013 K-40 3.40 +/- 0.41 3.52 +/- 0.39 3.46 +/- 0.29 Pass A5-2
0 0
0 0 TABLE A-5. In-House "Duplicate" Samples 0
Concentration (pCi/L)a Averaged 0 Lab Code Date Analysis First Result Second Result Result Acceptance 0
S S-3238, 3239 6/17/2013 Be-7 1139.80 +/- 215.00 1102.00 +/- 194.70 1120.90 +/- 145.03 Pass S-3238, 3239 6/17/2013 Cs-1 34 26.23 +/- 13.23 39.91 +/- 11.73 33.07 +/- 8.84 Pass 0 S-3238, 3239 6/17/2013 Cs-137 72.75 +/- 25.99 85.91 +/- 22.58 79.33 +/- 17.21 Pass 0 S-3238, 3239 6/17/2013 K-40 21847.00 +/- 656.50 22158.00 +/- 622.80 22002.50 +/- 452.46 Pass S SO-3343, 3344 SO-3343, 3344 6/17/2013 6/17/2013 Cs-1 37 K-40 0.087 8.90
+/- 0.022
+/- 0.53 0.084 9.47
+/- 0.017
+/- 0.49 0.086 9.19
+/- 0.014
+/- 0.36 Pass Pass 0 DW-40118, 40119 6/26/2013 Gr. Alpha 3.56 +/- 1.07 4.51 +/- 0.96 4.04 +/- 0.72 Pass DW-40118, 40119 6/26/2013 Ra-226 2.52 +/- 0.22 2.48 +/- 0.19 2.50 +/- 0.15 Pass 0 DW-40118, 40119 6/26/2013 Ra-228 2.75 +/- 0.71 2.86 +/- 0.75 2.81 +/- 0.52 Pass WW-3583, 3584 6/27/2013 H-3 6732.57 +/- 246.74 6807.94 +/- 247.98 6770.26 +/- 174.91 Pass 0 AP-4092, 4093 6/28/2013 Be-7 0.078 +/- 0.015 0.083 +/- 0.017 0.080 +/- 0.011 Pass S E-3608, 3609 7/1/2013 K-40 1.28 +0.13 1.29 +/- 0.11 1.28 +/- 0.09 Pass MI-3629, 3630 7/1/2013 K-40 1840.70 +/- 130.10 1804.90 +/- 143.00 1822.80 +/- 96.66 Pass 0 AP-4050, 4051 7/1/2013 Be-7 0.094 +/- 0.009 0.093 +/- 0.009 0.093 +/- 0.006 Pass 0 DW-40134, 40135 7/1/2013 Ra-226 1.75 + 0.15 1.56 +/- 0.15 1.66 +/- 0.11 Pass 0 DW-40134, 40135 7/1/2013 Ra-228 2.07 +/- 0.60 1.61 +/- 0.57 1.84 +/- 0.41 Pass AP-4071, 4072 7/3/2013 Be-7 0.066 +/- 0.009 0.069 +/- 0.011 0.067 +/- 0.007 Pass S DW-40144, 40145 7/9/2013 Gr. Alpha 3.66 +/- 0.85 2.85 +/- 0.79 3.26 +/- 0.58 Pass DW-40146, 40147 7/9/2013 Ra-226 0.70 +0.11 0.72 +/- 0.11 0.71 +/- 0.08 Pass 0 DW-40146, 40147 7/9/2013 Ra-228 1.00 +/- 0.58 0.70 +/- 0.52 0.85 +/- 0.39 Pass 0 VE-3818, 3819 7/9/2013 Be-7 0.41 +/-0.11 0.46 +/- 0.18 0.43 +/- 0.11 Pass VE-3818, 3819 7/9/2013 K-40 4.67 +/- 0.30 4.52 +/- 0.43 4.60 +/- 0.26 Pass 0 XW-4646, 4647 7/15/2013 H-3 465.00 +/- 111.00 525.00 +/- 114.00 495.00 +/- 79.56 Pass WW-4134, 4135 7/16/2013 H-3 315.86 +/- 123.54 264.98 +/- 121.78 290.42 +/- 86.73 Pass 0 AP-4155, 4156 7/18/2013 Be-7 0.20 +/- 0.11 0.16 +/- 0.09 0.18 +/- 0.07 Pass 0 MI-4218, 4219 7/22/2013 K-40 1426.80 +/- 117.50 1335.70 +/- 110.60 1381.25 +/- 80.68 Pass MI-4218, 4219 7/22/2013 Sr-90 0.62 +/- 0.32 0.67 +/- 0.32 0.65 +/- 0.23 Pass 0 WW-4239, 4240 7/23/2013 H-3 223.71 +/- 92.64 221.74 +/- 92.56 222.73 +/- 65.48 Pass 0 WW-4394, 4395 7/30/2013 Gr. Alpha 2.63 +/- 1.49 2.57 +/- 1.11 2.60 +/- 0.93 Pass WW-4394, 4395 7/30/2013 Gr. Beta 3.72 +/- 1.17 2.63 +/- 1.29 3.18 Pass 0 WW-4394, 4395 7/30/2013 H-3 271.50 +/- 91.30 297.60 +/- 91.50 284.55
+/- 0.87
+/- 64.63 Pass SWU-4478, 4479 7/30/2013 Gr. Beta 2.07 +/- 0.54 2.24 +/- 0.55 2.16 +/- 0.39 Pass 0 DW-40159, 40160 7/31/2013 Ra-226 3.39 +/- 0.63 2.39 +/- 0.45 2.89 +/- 0.39 Pass DW-40159, 40160 7/31/2013 Ra-228 3.29 +/- 0.73 2.94 +/- 0.68 3.12 +/- 0.50 Pass VE-4436, 4437 8/1/2013 Be-7 0.98 +/- 0.21 0.89 +/- 0.17 0.94 +/- 0.14 Pass VE-4436, 4437 8/1/2013 K-40 3.95 +/- 0.39 3.75 +/- 0.31 3.85 +/- 0.25 Pass G-4457, 4458 8/1/2013 Be-7 0.78 +/- 0.19 0.67 +/- 0.16 0.72 +/- 0.12 Pass G-4457, 4458 8/1/2013 Gr. Beta 6.15 +/- 0.14 6.10 +/- 0.14 6.13 +/- 0.10 Pass G-4457, 4458 8/1/2013 K-40 4.25 +/- 0.36 4.60 +/- 0.41 4.42 +/- 0.27 Pass VE-4520, 4521 8/1/2013 K-40 2.20 +/- 0.16 2.09 +/- 0.17 2.15 +/- 0.12 Pass WW-4772, 4773 8/6/2013 H-3 143.80 +/- 86.70 157.80 +/- 87.30 150.80 +/- 61.52 Pass A5-3
S 0
0 TABLE A-5. In-House "Duplicate" Samples 0
Concentration (pCi/L)a 0 Averaged Lab Code Date Analysis First Result Second Result Result Acceptance S
VE-4709, 4710 8/8/2013 Gr. Beta 31.40 +/- 1.00 30.70 +/- 1.00 31.05 +/- 0.71 Pass 0 VE-4709, 4710 8/8/2013 H-3 1504.00 +/- 132.00 1468.00 +/- 131.00 1486.00 +/- 92.99 Pass VE-4709, 4710 8/8/2013 U-233/4 0.009 +/- 0.002 0.005 +/- 0.002 0.007 +/- 0.001 Pass 0 VE-4709,4710 8/8/2013 U-238 0.005 +/- 0.002 0.004 +/- 0.001 0.005 +/- 0.001 Pass WW-4562,4563 8/8/2013 H-3 208.82 +/- 105.55 213.13 +/- 105.73 210.97 +/- 74.70 Pass 0 SG-4651, 4652 8/13/2013 Gr. Alpha 29.00 +/- 3.10 28.80 +/- 3.20 28.90 +/- 2.23 Pass 0 SG-4651, 4652 8/13/2013 Gr. Beta 34.10 +/- 1.80 34.00 +/- 1.80 34.05 +/- 1.27 Pass 0 SG-4651, 4652 8/13/2013 Ra-226 9.00 + 0.20 8.70 +/- 0.20 8.85 +/- 0.14 Pass VE-4835, 4836 8/13/2013 K-40 3.01 +/- 0.24 3.08 +/- 0.28 3.04 +/- 0.19 Pass 0 WW-4877, 4878 8/14/2013 H-3 217.35 +/- 87.57 276.63 +/- 90.20 246.99 +/- 62.86 Pass LW-4856, 4857 8/15/2013 Gr. Beta 0.96 +/- 0.40 0.94 +/- 0.38 0.95 +/- 0.28 Pass 0 W-4982,4983 8/16/2013 H-3 757.43 +/- 112.40 767.56 +/- 112.76 762.50 +/- 79.60 Pass S VE-4919,4920 8/19/2013 K-40 4891.90 +/- 407.90 4907.40 +/- 350.40 4899.65 +/- 268.87 Pass VE-4919,4920 8/19/2013 Be-7 470.50 +/- 159.60 325.10 +/- 104.10 397.80 +/- 95.27 Pass DW-40184, 40185 8/19/2013 Ra-228 2.35 +/- 0.72 2.53 +/- 0.70 2.44 +/- 0.50 Pass 0 DW-40184, 40185 8/19/2013 Ra-228 1.44 +/- 0.35 2.30 +/- 0.56 1.87 +/- 0.33 Pass AP-5003, 5004 8/22/2013 Be-7 0.23 +/- 0.10 +/- 0.07 Pass 0 LW-5229, 5230 8/29/2013 Gr. Beta 1.09 +/- 0.86 0.21 2.28
+/- 0.10
+/- 0.96 0.22 1.69 +/- 0.64 Pass 0 SS-5333, 5334 9/3/2013 Cs-1 37 89.20 +/- 41.60 97.80 +/- 34.60 93.50 +/- 27.05 Pass SS-5333, 5334 9/3/2013 K-40 11893.00 +/- 681.30 12353.00 +/- 778.90 12123.00 +/- 517.41 Pass VE-5313, 5314 9/3/2013 K-40 1.84 +/- 0.20 1.85 +/- 0.20 1.85 +/- 0.14 Pass 0 VE-5313, 5314 9/3/2013 Gr. Beta 2.38 +/- 0.04 2.43 +/- 0.04 2.41 +/- 0.03 Pass WW-5617,5618 9/5/2013 H-3 1987.00 +/- 147.00 2094.00 +/- 150.00 2040.50 +/- 105.01 Pass 0 AP-5355, 5356 9/5/2013 Be-7 0.22 +/- 0.12 0.27 +/- 0.14 0.25 +/- 0.09 Pass 0 XW-5694, 5695 9/8/2013 C-14 0.94 +/- 0.09 0.78 +/- 0.10 0.86 +/- 0.07 Pass VE-5409, 5410 9/9/2013 K-40 3.60 +/- 0.26 3.33 +/- 0.29 3.46 +/- 0.19 Pass 0 AP-5430, 5431 9/12/2013 Be-7 0.26 +/- 0.10 0.26 +/- 0.10 0.26 +/- 0.07 Pass 0 MI-5401, 5402 9/12/2013 K-40 1404.60 +/- 114.10 1356.10 +/- 128.60 1380.35 +/- 85.96 Pass WW-5451, 5452 9/12/2013 H-3 196.66 +/- 84.44 0 MI-5484, 5485 9/16/2013 K-40 1398.50 +/- 88.93 200.78 1364.60
+/- 84.64
+/- 113.30 198.72 1381.55
+/- 59.78
+/- 72.02 Pass Pass WW-5568, 5569 9/17/2013 H-3 274.69 +/- 87.95 203.72 +/- 84.71 239.20 +/- 61.05 Pass 0 BS-5764, 5765 9/20/2013 Cs-137 0.40 +/- 0.03 0.37 +/- 0.02 0.39 +/- 0.02 Pass BS-5764, 5765 9/20/2013 K-40 17.97 +/- 0.59 17.54 +/- 0.55 17.76 +/- 0.40 Pass 0 VE-5638, 5639 9/23/2013 K-40 4.15 +/- 0.33 4.46 +/- 0.38 4.31 +/- 0.25 Pass WW-5596, 5597 9/23/2013 Gr. Beta 5.97 +/- 1.39 5.95 +/- 1.45 5.96 +/- 1.01 Pass G-5680,5681 9/25/2013 Be-7 0.36 +/- 0.13 0.35 +/- 0.09 0.35 +/- 0.08 Pass G-5680,5681 9/25/2013 Gr. Beta 3.81 +/-0.11 3.77 +/- 0.11 3.79 +/- 0.08 Pass G-5680,5681 9/25/2013 K-40 3.23 +/- 0.32 2.99 +/- 0.24 3.11 +/- 0.20 Pass S-5659,5660 9/2612013 Ac-228 1.19 +/- 0.21 1.06 +/- 0.21 1.13 +/- 0.15 Pass S-5659,5660 9/26/2013 Cs-137 0.13 +/- 0.04 0.14 +/- 0.05 0.14 +/- 0.03 Pass S-5659,5660 9/26/2013 K-40 16.08 +/- 1.39 16.65 +/- 1.46 16.37 +/- 1.01 Pass S-5659,5660 9/26/2013 Pb-214 0.97 +/- 0.15 1.10 +/- 0.16 1.04 +/- 0.11 Pass AP-6345, 6346 9/30/2013 Be-7 0.077 +/- 0.010 0.081 +/- 0.008 0.079 +/- 0.006 Pass AP-6366,6367 9/30/2013 Be-7 0.078 +/- 0.012 0.083 +/- 0.014 0.081 +/- 0.009 Pass A5-4
0 0
S S TABLE A-5. In-House "Duplicate" Samples 0
Concentration (pCi/L)a Averaged 0 Lab Code Date Analysis First Result Second Result Result Acceptance 0
0 DW-5701, 5702 SG-5722, 5723 9/30/2013 9130/2013 Gr. Beta Ra-226 14.48 12.41
+/- 2.04
+/- 0.47 13.32 11.98
+/- 1.84
+/- 0.59 13.90 12.20
+/- 1.37
+/- 0.38 Pass Pass 0 SG-5722, 5723 9/30/2013 Ra-228 7.84 +/- 0.71 8.13 +/- 0.97 7.99 +/- 0.60 Pass 0 G-5806, 5807 10/1/2013 Be-7 3.26 +/- 0.30 3.11 +/- 0.13 3.19 +/- 0.16 Pass G-5806, 5807 1011/2013 K-40 6.65 +/- 0.21 6.68 +/- 0.50 6.67 +/- 0.27 Pass 0 SG-5827, 5828 10/1/2013 Ac-228 4.08 +/- 0.33 3.92 +/- 0.40 4.00 +/- 0.26 Pass SG-5827, 5828 10/1/2013 K-40 2.55 +/- 0.65 2.37 +/- 0.63 2.46 +/- 0.45 Pass S SG-5827, 5828 10/11/2013 Pb-214 3.82 +/- 0.17 3.93 +/- 0.20 3.88 +/- 0.13 Pass VE-5848, 5849 10/1/2013 K-40 1.62 +/- 0.16 1.57 +/- 0.14 1.60 +/- 0.11 Pass AP-6408, 6409 10/3/2013 Be-7 0.072 +/- 0.015 0.063 +/- 0.012 0.068 +/- 0.010 Pass 0 f-5954, 5955 10/3/2013 K-40 2.74 +/- 0.36 3.02 +/- 0.34 2.88 +/- 0.25 Pass 0 P-6035, 6036 10/7/2013 H-3 198.41 +/- 85.00 288.60 +/- 89.15 243.51 +/- 61.59 Pass SG-6115, 6116 10/8/2013 Ac-228 5.22 +/- 0.50 4.87 +/- 0.48 5.05 +/- 0.35 Pass 0 SG-6115, 6116 10/8/2013 K-40 5.61 +/- 1.08 6.61 +/- 1.04 6.11 +/- 0.75 Pass SG-6115, 6116 10/8/2013 Pb-214 4.29 +/- 0.24 4.24 +/- 0.20 4.27 +/- 0.16 0 VE-6136, 6137 10/8/2013 Be-7 0.55 +/- 0.18 0.60 +/- 0.15 0.58 +/- 0.12 Pass Pass 0 VE-6136, 6137 10/8/2013 K-40 2.78 +/- 0.35 2.61 +/- 0.33 2.69 +/- 0.24 Pass 0 WW-6198, 6199 10/8/2013 10/9/2013 H-3 12973.70 +/- 332.60 12757.80 +/- 330.00 12865.75 +/- 234.27 Pass VE-6240, 6241 K-40 14.29 +/- 0.29 14.95 +/- 0.54 14.62 +/- 0.31 Pass S W-5996, 5997 10/9/2013 Gr. Alpha 3.87 +/- 1.18 4.07 +/- 1.08 3.97 +/- 0.80 Pass 0 W-5996, 5997 10/9/2013 Gr. Beta 9.82 +/- 0.85 8.53 +/- 0.82 9.18 +/- 0.59 Pass W-5996, 5997 10/9/2013 Ra-228 3.42 +/- 1.02 3.39 +/- 1.01 3.41 +/- 0.72 Pass DW-40224, 40225 10/11/2013 Ra-226 0.62 +/- 0.10 0.76 +/- 0.10 0.69 +/- 0.07 Pass DW-40224, 40225 10/11/2013 Ra-228 0.87 +/- 0.55 1.00 +/- 0.54 0.94 +/- 0.39 Pass 0 WW-6219, 6220 CF-6261, 6262 10/11/2013 10/14/2013 H-3 Be-7 455.41 1.97
+/- 111.54
+/- 0.24 354.66 +/- 107.84 405.03 +/- 77.57 Pass 2.06 +/- 0.22 2.01 +/- 0.16 Pass CF-6261, 6262 10/14/2013 K-40 11.55 +/- 0.56 12.06 +/- 0.61 11.80 +/- 0.41 Pass 0 MI-6303, 6304 10/14/2013 K-40 1507.30 +/- 110.80 1482.40 +/- 110.00 1494.85 +/- 78.07 Pass VE-6534, 6535 10/17/2013 K-40 15.96 +/- 0.17 16.16 +/- 0.36 16.06 +/- 0.20 Pass S-6471, 6472 10/18/2013 Ac-228 0.94 +/- 0.19 0.78 +/- 0.18 0.86 +/- 0.13 Pass 0 S-6471, 6472 10/18/2013 K-40 12.82 +/- 1.05 12.90 +/- 1.17 12.86 +/- 0.79 Pass S-6471, 6472 10/18/2013 Pb-214 0.88 +/- 0.11 0.72 +/- 0.12 0.80 +/- 0.08 Pass 0 VE-6597, 6598 10/22/2013 K-40 2.46 +/- 0.22 2.58 +/- 0.20 2.52 +/- 0.15 Pass WW-6576, 6577 10/22/2013 H-3 745.60 +/- 110.70 663.30 +/- 107.60 704.45 +/- 77.19 Pass LW-6681, 6682 10/29/2013 Gr. Beta 2.00 +/- 0.92 2.17 +/- 0.98 2.09 +/- 0.67 Pass 0 SWU-6765, 6766 10/29/2013 Gr. Beta 3.07 +/- 0.61 2.90 +/- 0.65 2.99 +/- 0.45 Pass WW-6849, 6850 10/29/2013 H-3 863.00 +/- 113.80 826.60 +/- 112.50 844.80 +/- 80.01 Pass 0 MI-6786, 6787 10/30/2013 K-40 1370.60 +/- 109.60 1449.20 +/- 105.50 1409.90 +/- 76.06 Pass SO-6744, 6745 10/30/2013 Ac-228 0.46 +/- 0.11 0.51 +/- 0.11 0.48 +/- 0.08 Pass SO-6744, 6745 10/30/2013 Bi-214 0.48 +/- 0.10 0.30 +/- 0.10 0.39 +/- 0.07 Pass SO-6744, 6745 10/30/2013 Cs-137 0.21 +/- 0.04 0.24 +/- 0.04 0.23 +/- 0.03 Pass SO-6744, 6745 10/30/2013 Gr. Beta 27.40 +/- 1.14 27.44 +/- 1.11 27.42 +/- 0.80 Pass SO-6744, 6745 10/30/2013 K-40 14.93 +/- 0.88 15.20 +/- 0.90 15.07 +/- 0.63 Pass SO-6744, 6745 10/30/2013 Pb-212 0.43 +/- 0.04 0.40 +/- 0.05 0.42 +/- 0.03 Pass SO-6744, 6745 10/30/2013 Ra-226 1.47 +/- 0.35 1.31 +/- 0.36 1.39 +/- 0.25 Pass SO-6744, 6745 10/30/2013 TI-208 0.16 +/- 0.04 0.16 +/- 0.04 0.16 +/- 0.03 Pass A5-5
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged 0
Lab Code Date Analysis First Result Second Result Result Acceptance S DW-40238, 40239 10/31/2013 Ra-228 0.94 +/- 0.41 1.60 +/- 0.55 1.27 +/- 0.34 Pass WW-7018, 7019 11/1/2013 H-3 593.09 +/- 104.72 648.69 +/- 106.89 620.89 +/- 74.82 Pass S CF-6870, 6871 11/4/2013 K-40 12.67 +/- 0.49 13.30 +/- 0.47 12.98 +/- 0.34 Pass XW-6828, 6829 11/4/2013 K-40 97.99 +/- 55.33 160.21 +/- 74.99 129.10 +/- 46.60 Pass 0 BS-6891,6892 11/5/2013 Cs-137 0.018 +/- 0.010 0.018 +/- 0.009 0.018 +/- 0.007 Pass 0 BS-6891,6892 11/5/2013 Gr. Beta 12.41 +/- 1.74 9.97 +/- 1.57 11.19 +/- 1.17 Pass BS-6891,6892 11/5/2013 K-40 6.49 +/- 0.33 6.28 +/- 0.40 6.39 +/- 0.26 Pass 0 WW-6912,6913 11/5/2013 Gr. Alpha 2.87 +/- 1.30 4.46 +/- 1.47 3.67 +/- 0.98 Pass WW-6912,6913 11/5/2013 Gr. Beta 3.18 +/-0.87 3.18 +/- 0.87 3.18 +/- 0.62 Pass WW-6912,6913 11/5/2013 H-3 349.01 + 101.42 430.14 +/- 98.06 389.58 +/- 70.54 Pass SO-6954, 6955 11/6/2013 Cs-137 0.14 +/- 0.03 0.12 +/- 0.02 0.13 +/- 0.02 Pass 0 SO-6954,6955 11/6/2013 K-40 15.16 +/-0.72 14.11 +/-0.64 14.64 +/- 0.48 Pass S-6976,6977 11/13/2013 K-40 22.36 +/- 0.69 22.62 +/- 0.72 22.49 +/- 0.50 Pass 0 DW-40246, 40247 11/15/2013 Gr. Alpha 15.00 +/- 3.41 20.31 +/- 4.00 17.65 +/- 2.63 Pass 0 CF-7102, 7103 11/18/2013 Be-7 17.79 +/- 0.51 18.09 +/- 0.80 17.94 +/- 0.48 Pass DW-40250, 40251 11/18/2013 Ra-226 27.77 +/- 2.84 26.15 +/- 2.67 26.96 +/- 1.95 Pass 0 DW-40250, 40251 11/18/2013 11/19/2013 Ra-228 H-3 7.91 266.90
+/- 0.94
+ 91.10 6.32 +/- 0.84 268.90 +/- 91.20 7.12 267.90
+/- 0.63
+/- 64.45 Pass Pass WW-7164,7165 0 SS-7334,7335 11/20/2013 K-40 15.51 +/- 0.72 14.14 +/- 0.80 14.83 +/- 0.54 Pass 0 WW-7558,7559 11/22/2013 H-3 229.86 + 83.89 191.77 +/- 82.05 210.82 +/- 58.67 Pass LW-7292, 7293 11/26/2013 Gr. Beta 1.92 +/- 0.75 2.38 +/- 0.77 2.15 +/- 0.54 Pass S W-7229,7230 12/1/2013 Ra-226 0.87 +/- 0.23 0.88 +/- 0.25 0.88 +/- 0.17 Pass S W-7229,7230 12/1/2013 Ra-228 3.00 +/- 0.98 3.27 +/- 1.16 3.14 +/- 0.76 Pass 12/2/2013 Pass 0 SG-7313, 7314 SG-7313, 7314 12/2/2013 Ac-228 K-40 6.33 5.47
+/-0.23
+/- 0.61 6.69 +/- 0.30 6.24 +/- 0.74 6.51 5.86
+/- 0.19
+/- 0.48 Pass SG-7313, 7314 12/2/2013 Pb-214 5.60 +/- 0.14 5.37 +/- 0.16 5.49 +/- 0.11 Pass 0 W-7432,7433 12/4/2013 Gr. Beta 5.35 +/- 1.20 3.89 +/- 1.23 4.62 +/- 0.86 Pass WW-7516,7517 12/10/2013 H-3 369.30 +/- 95.64 269.22 +/- 91.35 319.26 +/- 66.13 Pass 0 SG-7579, 7580 12/20/2013 12/20/2013 Ra-226 3.72 +/- 0.11
+/- 0.18 3.85 +/- 0.30 3.79 +/- 0.16 Pass SG-7579, 7580 Ra-228 2.38 2.77 +/- 0.44 2.58 +/- 0.24 Pass 12/23/2013 S LW-7684, 7685 DW-40261, 40262 12/27/2013 Gr. Beta Ra-226 0.84 0.54
+/- 0.51
+/- 0.10 1.96 +/- 0.61 0.67 +/- 0.10 1.40 0.61
+/- 0.40
+/- 0.07 Pass Pass DW-40261, 40262 12/27/2013 Ra-228 1.09 +/- 0.51 1.12 +/- 0.43 1.11 +/-0.33 Pass S SWU-7663, 7664 12/30/2013 Gr. Beta 2.85 +/- 0.71 3.88 +/- 0.77 3.37 +/- 0.52 Pass 0
Note: Duplicate analyses are performed on every twentieth sample received in-house. Results are not listed for those analyses with activities that measure below the LLD.
a Results are reported in units of pCi/L, except for air filters (pCi/Filter), food products, vegetation, soil, sediment (pCi/g).
A5-6
0 S TABLE A-6. Department of Energy's Mixed Analyte PerforMAnce Evaluation Program (MAPEP).
0 Concentration a Known Control 0 Lab Code b Date Analysis Laboratory result Activity Limits c Acceptance 0 MAAP-738 02/01/13 Am-241 0.10 +/- 0.02 0.10 0.07 -0.14 Pass MAAP-738 02/01/13 Co-57 2.58 +/- 0.06 2.36 1.65 - 3.07 Pass 0 MAAP-738 02/01/13 Co-60 0.01 +/- 0.03 0.00 0.00 -0.10 Pass MAAP-738 02/01/13 Cs-I 34 1.82 +/- 0.13 1.78 1.25 -2.31 Pass 0 MAAP-738 02/01/13 Cs-I 37 2.93 +/- 0.10 2.60 1.82 -3.38 Pass 0 MAAP-738 02/01/13 Mn-54 4.87 +/- 0.13 4.26 2.98 - 5.54 Pass MAAP-738 02/01/13 Pu-238 0.12 +/- 0.02 0.13 0.09 -0.17 Pass 0 MAAP-738 02/01/13 Pu-239/40 0.11 +/-0.02 0.12 0.09 -0.16 Pass MAAP-738 02/01/13 Sr-90 1.39 +/- 0.14 1.49 1.04 - 1.94 Pass 0 MAAP-738 02/01/13 U-233/4 0.03 +/- 0.01 0.03 0.02 - 0.04 Pass S MAAP-738 02/01/13 U-238 0.23 +/- 0.03 0.23 0.16 -0.30 Pass MAAP-738 02/01/13 Zn-65 3.84 +/- 0.20 3.13 2.19 -4.07 Pass S MAAP-738 d 02/01/13 Gr. Alpha 0.14 +/- 0.03 1.20 0.36 - 2.04 Fail MAAP-738 02101/13 Gr. Beta 0.93 +/- 0.06 0.85 0.43 - 1.28 Pass 0
0 MAW-806 02/01/13 Am-241 0.71 +/- 0.08 0.69 0.48 - 0.90 Pass 0 MAW-806 02/01/13 Co-57 31.20 +/- 0.40 30.90 21.60 - 40.20 Pass MAW-806 02/01/13 Co-60 19.70 +/- 0.30 16.56 13.69 - 25.43 Pass MAW-806 02/01/13 Cs-134 23.20 +/- 0.50 24.40 17.10 - 31.70 Pass MAW-806 02/01/13 Cs-137 0.03 +/- 0.12 0.00 0.00 - 1.00 Pass 0 MAW-806 02/01/13 Fe-55 34.00 +/- 3.30 44.00 30.80 - 57.20 Pass 0 MAW-806 02/01/13 H-3 511.60 +/- 12.50 507.00 355.00 - 659.00 Pass MAW-806 02/01/13 K-40 2.20 +/- 0.90 0.00 0.00 - 5.00 Pass 0 MAW-806 02/01/13 Mn-54 27.60 +/- 0.50 27.40 19.20 - 35.60 Pass 0 MAW-806 02/01/13 Ni-63 34.30 +/- 2.80 33.40 23.40 - 43.40 Pass MAW-806 02/01/13 Pu-238 0.83 +/- 0.10 0.88 0.62 -1.15 Pass 0 MAW-806 02/01/13 Pu-239/40 0.02 +/- 0.02 0.01 0.00 - 1.00 Pass MAW-806 02/01/13 Sr-90 9.30 +/- 0.80 10.50 7.40 - 13.70 Pass MAW-806 02/01/13 Tc-99 10.25 +/- 0.40 13.10 9.20 - 17.00 Pass MAW-806 02/01/13 U-233/4 0.31 +/- 0.05 0.32 0.22 - 0.41 Pass 0 MAW-806 02/01/13 U-238 1.91 +/-0.13 1.95 1.37 -2.54 Pass 0 MAW-806 02/01/13 Zn-65 31.60 +/- 0.80 30.40 21.30 - 39.50 Pass MAW-811 02/01/13 Gr. Alpha 1.87 +/- 0.09 2.31 0.69 - 3.93 Pass MAW-811 02/01/13 Gr. Beta 13.04 +/- 0.13 13.00 6.50 - 19.50 Pass MAW-811 02/01/13 1-129 4.60 +/- 0.19 6.06 4.24 - 7.88 Pass A6-1
0 0
0 TABLE A-6. Department of Energy's Mixed Analyte PerforMAnce Evaluation Program (MAPEP).
Concentration a S Known Control 0 Lab Code b Date Analysis Laboratory result Activity Limits ' Acceptance 0
0 MASO-739 02/01/13 Am-241 106.90 +/- 11.40 113.00 79.00 - 147.00 Pass 0 MASO-739 MASO-739 02/01/13 02/01/13 Co-57 Co-60 0.60 739.20
+/- 0.50
+/- 28.50 0.00 691.00 0.00 484.00
-5.00
- 898.00 Pass Pass MASO-739 02/01/13 Cs-1 34 863.30 +/- 34.10 887.00 621.00 - 1153.00 Pass 0 MASO-739 02/01/13 Cs-137 661.80 +/- 25.70 587.00 411.00 - 763.00 Pass MASO-739 02/01/13 K-40 745.80 +/- 33.30 625.30 437.70 - 812.90 Pass 0 MASO-739 02/01/13 Mn-54 1.10 +/- 1.00 0.00 0.00 -5.00 Pass MASO-739 02/01/13 Zn-65 1109.60 +/- 44.10 995.00 697.00 - 1294.00 Pass 02/01/13 Pass 0 MASO-744 MASO-744 02/01/13 Ni-63 Pu-238 682.60 0.20
+/- 16.80
+/- 0.90 670.00 0.00 469.00 0.00
-871.00
-1.00 Pass S MASO-744 02/01/13 Pu-239/40 88.30 +/- 9.00 79.50 55.70 - 103.40 Pass 0 MASO-744 MASO-744 02/01/13 02/01/13 Sr-90 Tc-99 408.40 380.50
+/- 14.00
+/- 16.80 628.00 444.00 440.00 311.00
- 816.00
-577.00 Fail Pass 0 MASO-744 02/01/13 U-233/4 53.20 +/- 4.80 62.50 43.80 -81.30 Pass 0 MASO-744 02/01/13 U-238 242.10 +/- 10.20 281.00 197.00 - 365.00 Pass 0
MAVE-747 02/01/13 Co-57 10.37 +/- 0.17 8.68 6.08 -11.28 Pass MAVE-747 02/01/13 Co-60 6.48 +/- 0.17 5.85 4.10 -7.61 Pass MAVE-747 02/01/13 Cs-134 0.02 +/- 0.04 0.00 0.00 -0.10 Pass MAVE-747 02/01/13 Cs-137 7.79 +/- 0.21 6.87 4.81 - 8.93 Pass MAVE-747 02/01/13 Mn-54 0.00 +/- 0.05 0.00 0.00 -0.10 Pass MAVE-747 02/01/13 Zn-65 7.29 +/- 0.33 6.25 4.38 -8.13 Pass 0
0 MASO-5043 08/01/13 Am-241 1.40 +/- 1.70 0.00 0.00 - 5.00 Pass t
MASO-5043 08/01/13 Co-57 699.60 +/- 3.90 0.00 0.00 - 5.00 Fail 0 MASO-5043 08/01/13 Cs-134 1191.70 1072.00
+/- 23.00 1172.00 820.00 - 1524.00 Pass MASO-5043 08/01/13 Cs-137 +/- 5.10 977.00 684.00 - 1270.00 Pass 0 MASO-5043 08/01/13 K-40 760.00 +/- 16.20 633.00 443.00 - 823.00 Pass S MASO-5043 MASO-5043 08/01/13 08/01/13 Mn-54 Ni-63 753.80 560.00
+/- 4.90 674.00 472.00 - 876.00 Pass
+/- 23.70 571.00 400.00 - 742.00 Pass 0 MASO-5043 08/01/13 Pu-238 68.40 +/- 7.50 61.50 43.10 - 80.00 Pass 0 MASO-5043 08/01/13 Pu-239/40 0.40 +/- 0.80 0.36 0.00 -1.00 Pass MASO-5043 08/01/13 Sr-90 383.90 +/- 14.50 460.00 322.00 - 598.00 Pass 0 MASO-5043 08/01/13 Tc-99 -1.00 +/- 10.50 0.00 0.00 -5.00 Pass 0 MASO-5043 08/01/13 U-233/4 23.80 +/- 3.30 30.00 21.00 -39.00 Pass 0 MASO-5043 MASO-5043 08/01/13 08/01/13 U-238 Zn-65 26.80
-351.50
+/- 3.50
+/- 5.50 34.00 0.00 23.80 0.00
- 44.20
-0.00 Pass Pass 0
0 A6-2 0
S 0
0 0
0 TABLE A-6. Department of Energy's Mixed Analyte PerforMAnce Evaluation Program (MAPEP).
0 Concentration a 0 Known Control Lab Code b Date Analysis Laboratory result Activity Limits c Acceptance 0
MAW-5052 08/01/13 1-129 2.75 +/- 0.20 3.79 2.65 - 4.93 Pass 0 MAW-5094 08/01/13 Am-241 0.00 +/- 0.01 0.00 0.00 - 5.00 Pass MAW-5094 08/01/13 Co-57 0.01 +/- 0.09 0.00 0.00 - 5.00 Pass 0 MAW-5094 08/01/13 Co-60 23.20 +/- 0.32 23.58 16.51 - 30.65 Pass MAW-5094 08/01113 Cs-134 27.60 +/- 0.58 30.40 21.00 - 39.00 Pass 0 MAW-5094 08/01/13 Cs-137 32.31 +/- 0.52 31.60 22.10 - 41.10 Pass MAW-5094 08/01/13 Fe-55 39.20 +/- 3.50 53.30 37.30 - 69.30 Pass 0 MAW-5094 08/01/13 Gr. Alpha 0.54 +/- 0.05 0.70 0.21 -1.19 Pass S MAW-5094 08/01/13 08/01/13 Gr. Beta 5.85 +/- 0.09 5.94 2.97 - 8.91 Pass MAW-5094 H-3 1.20 +/- 3.00 0.00 0.00 - 5.00 Pass S MAW-5094 08/01/13 K-40 2.22 +/- 0.90 0.00 0.00 - 5.00 Pass MAW-5094 08/01/13 Mn-54 0.010 +/-0.11 0.00 0.00 - 5.00 Pass S MAW-5094 08/01/13 Ni-63 21.80 +/- 3.30 26.40 18.50 - 34.30 Pass 0 MAW-5094 MAW-5094 08/01/13 08/01/13 Pu-238 Pu-239/40 1.30 0.98
+/- 0.11
+/- 0.09 1.22 1.00 0.85 0.70
- 1.58
- 1.30 Pass Pass 0 MAW-5094 08/01/13 Sr-90 6.40 +/- 0.60 7.22 5.05 - 9.39 Pass S MAW-5094 08/01/13 Tc-99 13.10 +/- 0.70 16.20 11.30 -21.10 Pass MAW-5094 08/01/13 U-233/4 0.080 +/- 0.019 0.07 0.00 - 1.00 Pass 0 MAW-5094 MAW-5094 08/01/13 08/01/13 U-238 Zn-65 0.032 35.30
+/- 0.012
+/- 0.90 0.03 34.60 0.00 24.20
- 1.00
- 45.00 Pass Pass S
MAVE-5046 08/01/13 Co-57 0.01 +/- 0.03 0.00 0.00 - 0.00 Pass 0 MAVE-5046 08/01/13 Co-60 0.00 +/- 0.04 0.00 0.00 - 0.00 Pass MAVE-5046 08/01/13 Cs-I 34 5.71 +/- 0.23 5.20 3.64 - 6.76 Pass MAVE-5046 08/01/13 Cs-137 7.64 +/- 0.20 6.60 4.62 - 8.58 Pass 0 MAVE-5046 08/01/13 Mn-54 9.08 +/- 0.24 7.88 5.52 - 10.24 Pass MAVE-5046 08/01/13 Zn-65 2.92 +/- 0.25 2.63 1.84 -3.42 Pass 0
0 0
0 S
0 A6-3
TABLE A-6. Department of Energy's Mixed Analyte PerforMAnce Evaluation Program (MAPEP).
Concentration a Known Control Lab Code b Date Analysis Laboratory result Activity Limits' Acceptance 0 MAAP-5046 08/01/13 Am-241 0.01 +/- 0.02 0.00 0.02 - 0.04 Pass 0 MAAP-5046 08/01/13 Co-57 3.48 +/- 0.14 3.40 1.90 -3.50 Pass MAAP-5046 08/01/13 Co-60 2.44 +/- 0.08 3.40 1.60 - 3.00 Pass S MAAP-5046 08/01/13 Cs-134 0.01 +/- 0.03 0.00 0.02 - 0.04 Pass 0 MAAP-5046 08/01/13 Cs-137 3.09 +/- 0.13 2.70 1.90 -3.50 Pass MAAP-5046 08/01/13 Gr. Alpha 0.28 +/- 0.04 0.90 0.27 - 1.53 Pass S MAAP-5046 MAAP-5046 08/01/13 08/01/13 Gr. Beta Mn-54 1.90 3.95
+/- 0.08
+/- 0.12 1.63 3.50 0.82 2.50
-2.45
- 4.60 Pass Pass 0 MAAP-5046 08/01/13 Pu-238 0.14 +/- 0.028 0.12 0.087 - 0.16 Pass 0 MAAP-5046 MAAP-5046 08/01/13 08/01/13 Pu-239/40 Sr-90 0.10 1.69
+/- 0.022
+/- 4.10 0.092 1.81 0.064 1.27
- 0.12
-2.35 Pass Pass 0 MAAP-5046 g 08/01/13 U-233/4 0.044 +/- 0.012 0.029 0.020 - 0.038 Fail MAAP-5046 08/01/13 U-238 0.19 +/- 0.027 0.21 0.14 - 0.27 Pass MAAP-5046 08/01/13 Zn-65 3.27 +/- 0.18 2.70 2.50 -4.60 Pass 0
S 0
S S 8 Results are reported in units of Bq/kg (soil), Bq/L (water) or Bq/total sample (filters, vegetation).
hLaboratory codes as follows: MAW (water), MAAP (air filter), MASO (soil), MAVE (vegetation).
CMAPEP results are presented as the known values and expected laboratory precision (1 sigma, 1 determination) and 0
control limits as defined by the MAPEP. A known value of "zero" indicates an analysis was included in the testing 0 series as a "false positive". MAPEP does not provide control limits.
0 d The filter was recounted overnight, no significant alpha activity could be detected.
eThe sample was reanalyzed using additional fuming nitric separations. Result of reanalysis: 574.4 +/- 35.2 Bq/kg.
f Interference from Eu-152 resulted in misidentification of Co-57.
0 g Result of repeat analysis: 0.031 +/- 0.013 pCi/filter.
0 0
0 A6-4
0 0
0 0 TABLE A-7. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.
0 0 Concentration (pCi/L) b Lab Code b Date Analysis Laboratory ERA Control 0 Result c Result d Limits Acceptance 0
0 ERAP-1 174 03/18/13 Am-241 65.2 _ 4.4 66.8 41.2 -90.4 Pass ERAP-1174 03/18/13 Co-60 226.5 + 4.1 214.0 166.0 - 267.0 Pass 0 ERAP-1174 03/18/13 Cs-134 1101.2 +/-23.6 1110.0 706.0 - 1380.0 Pass Cs-137 1065.6 + 21.4 Pass 0 ERAP-1174 ERAP-1174 03/18/13 03/18/13 Fe-55 178.8 + 88.0 940.0 225.0 706.0 69.8
- 1230.0
- 440.0 Pass 0 ERAP-1174 03/18/13 Mn-54 <3.1 0.0 0.0 - 50.0 Pass ERAP-1 174 03/18/13 Pu-238 50.0 +/- 3.0 51.1 34.3 - 65.9 Pass S ERAP-1174 03/18/13 Pu-239/40 65.7 +/- 2.6 65.2 47.2 - 85.2 Pass ERAP-1174 03/18/13 U-233/4 54.0 +/- 2.5 59.4 36.8 89.6 Pass 0 ERAP-1174 03/18/13 U-238 55.6 +/- 2.6 58.9 38.1
-81.4 Pass 0 ERAP-1174 03/18/13 Uranium 112.0 +/- 5.6 121.0 67.0 - 184.0 Pass 0 ERAP-1174 03/18/13 03/18/13 Zn-65 Gr. Alpha 236.6 52.3
+/- 13.8
+/- 2.8 199.0 142.0 - 275.0 Pass ERAP-1175 42.3 14.2 - 65.7 Pass 0 ERAP-1175 03/18/13 Gr. Beta 36.2 +/- 2.0 25.1 15.9 - 36.6 Pass ERSO-1176 03/18/13 Am-241 293.1 +/- 97.4 229.0 134.0 - 297.0 Pass S ERSO-1176 03/18/13 Pu-238 909.0 +/- 180.0 788.0 474.0 - 1090.0 Pass ERSO-1176 03/18/13 Pu-239/40 432.0 +/- 120.0 366.0 239.0 - 506.0 Pass 0 ERSO-1 176 03/18/13 Sr-90 8050.8 +/- 376.0 8530.0 3250.0 - 13500.0 Pass 0 ERSO-1176 03/18/13 U-233/4 1662.6 +/- 150.0 1920.0 1170.0 - 2460.0 Pass ERSO-1176 03/18/13 U-238 1682.8 +/- 160.0 1900.0 1180.0 - 2410.0 Pass ERSO-1176 03/18/13 Uranium 3404.0 +/- 330.5 3920.0 2130.0 - 5170.0 Pass ERSO-1176 03/18/13 Ac-228 1335.0 +/- 132.0 1240.0 795.0 - 1720.0 Pass 0 ERSO-1176 03/18/13 Bi-212 1420.0 +/- 311.0 1240.0 330.0 - 1820.0 Pass ERSO-1176 03/18/13 Bi-214 2626.0 +/- 60.0 3660.0 2200.0 - 5270.0 Pass S ERSO-1176 03/18/13 Co-60 7951.0 +/- 45.4 7920.0 5360.0 - 10900.0 Pass ERSO-1 176 03/18/13 Cs-134 5785.0 +/- 51.0 6370.0 4160.0 - 7650.0 Pass 0 ERSO-1 176 03/18/13 Cs-137 6106.0 +/- 47.9 6120.0 4690.0 - 7870.0 Pass ERSO-1176 03/18/13 K-40 11756.0 +/- 284.3 10300.0 7520.0 - 13800.0 Pass 0 ERSO-1176 03/18/13 Mn-54 < 28.0 0.0 0.0 - 1000.0 Pass 0 ERSO-1176 03/18/13 Pb-212 1096.0 +/- 29.1 1240.0 812.0 - 1730.0 Pass ERSO-1 176 03/18/13 Pb-214 2875.0 +/- 60.0 Pass 0 ERSO-1 176 03/18/13 Th-234 2404.0 +/- 218.3 3660.0 1900.0 2140.0 601.0 5460.0 3570.0 Pass 0 ERSO-1 176 03/18/13 Zn-65 1542.0 +/- 56.4 1400.0 1110.0 - 1860.0 Pass 0
0 0
0 A7-1
TABLE A-7. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.
0 0 Concentration (pCi/L) b 0 Lab Code b Date Analysis Laboratory Result c ERA Result Control d Limits Acceptance 0 ERVE-1 180 03/18/13 Am-241 569.8 +/- 81.7 553.0 338.0 - 735.0 Pass S ERVE-1 180 03/18/13 Cm-244 1260.9 +/- 107.3 1340.0 657.0 - 2090.0 Pass 0 ERVE-1 180 03/18/13 03/18/13 Co-60 Cs-134 2130.5 1296.5
+/- 48.0
+/- 68.0 1920.0 1320.0 - 2680.0 Pass ERVE-1 180 1240.0 797.0 - 1610.0 Pass 0 ERVE-1 180 03/18/13 Cs-137 600.1 +/- 34.3 544.0 394.0 - 757.0 Pass 0 ERVE-1 180 03/18/13 K-40 34078.0 +/- 787.0 31900.0 23000.0 - 44800.0 Pass ERVE-1 180 03/18/13 Mn-54 < 28.7 0.0 0.0 - 300.0 Pass 0 ERVE-1 180 03/18/13 Pu-238 2476.5 +/- 259.4 1980.0 1180.0 - 2710.0 Pass 0 ERVE-1 180 03/18/13 Pu-239/40 2659.3 +/- 273.2 2260.0 1390.0 - 3110.0 Pass ERVE-1 180 03/18/13 Sr-90 3809.7 +/- 420.5 3840.0 2190.0 - 5090.0 Pass 0 ERVE-1 180 03/18/13 U-233/4 2460.6 +/- 205.0 2460.0 1620.0 - 3160.0 Pass S ERVE-1 180 03/18/13 U-238 2319.1 +/- 189.6 2440.0 1630.0 - 3100.0 Pass 0 ERVE-1 ERVE-1 180 180 03/18/13 03/18/13 Uranium Zn-65 4866.3 1052.5
+/- 375.6
+/- 82.1 5010.0 878.0 3390.0 633.0
- 6230.0
- 1230.0 Pass Pass 0
ERW-1184 03/18/13 Am-241 114.5 +/-8.1 118.0 79.5 - 158.0 Pass 0 ERW-1184 03/18/13 Co-60 2221.8 +/- 17.0 2270.0 1970.0 - 2660.0 Pass 1309.4 +/- 58.4 Pass 0 ERW-1 184 ERW-1184 03/18/13 03/18/13 Cs-134 Cs-137 1865.9 +/- 22.0 1400.0 1880.0 1030.0 1600.0 1610.0 2250.0 Pass ERW-1184 03/18/13 Fe-55 503.1 +/- 105.0 712.0 424.0 - 966.0 Pass 0 ERW-1 184 03/18/13 Mn-54 < 9.4 0.0 0.0 - 100.0 Pass 0 ERW-1184 03/18/13 Pu-238 98.4 +/- 5.6 98.8 73.1 - 123.0 Pass ERW-1 184 03/18/13 Pu-239/40 184.5 +/- 7.7 185.0 144.0 - 233.0 Pass 0 ERW-1 184 03/18/13 Sr-O90 125.7 +/- 6.0 137.0 89.2 -181.0 Pass ERW-1 184 03/18/13 U-233/4 44.9 +/- 3.4 48.8 36.7 - 62.9 Pass 0 ERW-1184 03/18/13 U-238 46.5 +/- 3.5 48.4 36.9 - 59.4 Pass ERW-1184 03/18/13 Uranium 93.3 +/- 7.1 99.5 73.1 - 129.0 Pass 0 ERW-1 184 03/18/13 Zn-65 412.8 +/- 32.0 384.0 320.0 - 484.0 Pass ERW-1186 03/18/13 Gr. Alpha 109.1 +/- 5.7 130.0 46.2 - 201.0 Pass S ERW-1 186 03/18/13 Gr. Beta 74.5 +/- 6.4 78.9 45.2 - 117.0 Pass ERW-1188 03/18/13 H-3 12279.0 +/- 319.0 12300.0 8240.0 - 17500.0 Pass 0
0 0
a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency 0 testing administered by Environmental Resources Associates, serving as a replacement for studies conducted 0 previously by the Environmental Measurements Laboratory Quality Assessment Program (EML).
b Laboratory codes as follows: ERW (water), ERAP (air filter), ERSO (soil), ERVE (vegetation). Results are reported in units 0
of pCi/L, except for air filters (pCi/Filter), vegetation and soil (pCi/kg).
c Unless otherwise indicated, the laboratory result is given as the mean +/- standard deviation for three determinations.
0 dResults are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits as provided by ERA. A known value of "zero" indicates an analysis was included in the testing series as a "false positive". Control limits are not provided.
A7-2
0 0
0 0
0 0
0 0
0 0
0 0
0 0 APPENDIX B 0
0 DATA REPORTING CONVENTIONS 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0 B-1 0
0 0
0
- Data Reportinq Conventions 01.0. All activities, except gross alpha and gross beta, are decay corrected to collection time or the end
- of the collection period.
- 2.0. Single Measurements Each single measurement is reported as follows: x+/-s where: x = value of the measurement; 0s = 2s counting uncertainty (corresponding to the 95% confidence level).
- In cases where the activity is less than the lower limit of detection L, it is reported as: <L, where L = the lower limit of detection based on 4.66s uncertainty for a background sample.
S 3.0. Duplicate analyses 3.1 Individual results: For two analysis results; xi +/- sl and x2 +/- s2 Reported result: x + s; where x = (1/2) (xi + x2) and s = (1/2)"s2 + s2 1
3.2. Individual results: <Li , <L2 Reported result: <L, where L = lower of Li and L2 3.3. Individual results: x +/- s, <L Reported result: x +/- s if x > L; <L otherwise.
4.0. Computation of Averages and Standard Deviations S
4.1 Averages and standard deviations listed in the tables are computed from all of the individual measurements over the period averaged; for example, an annual standard deviation would not 5be the average of quarterly standard deviations. The average x and standard deviation s of a set of n numbers x1 , x2 ... xn are defined as follows:
Sx = n s =
n
- 4.2 Values below the highest lower limit of detection are not included in the average.
4.3 If all values in the averaging group are less than the highest LLD, the highest LLD is reported.
4.4 If all but one of the values are less than the highest LLD, the single value x and associated two 5 sigma error is reported.
4.5 In rounding off, the following rules are followed:
4.5.1. If the figure following those to be retained is less than 5, the figure is dropped, and the retained figures are kept unchanged. As an example, 11.443 is rounded off to 11.44.
4.5.2. If the figure following those to be retained is equal to or greater than 5, the figure is dropped
- and the last retained figure is raised by 1. As an example, 11.445 is rounded off to 11.45.
4.6 Composite samples which overlap the next month or year are reported for the month or year in Swhich most of the sample is collected.
B S
ID B-2 S
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0 APPENDIX C 0
0 TECHNICAL SPECIFICATION 2.1.3 0
0 REACTOR COOLANT DOSE EQUIVALENT IODINE ABOVE TECHNICAL SPECIFICATION LIMIT 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0 C-1 0
0 0
0 0
0 uigte21 eotn eid aiatvt fpiaycoatddntece th0iiso ehialSeiiain213 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0 C-2 0
S 0
0 S
0 0
0 0
0 0
0 0
0 0
0 0
0 0 APPENDIX D 0
0 0 SAMPLE LOCATIONS/MAP 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0 D-1 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0
.IN 0
0 0
0 0
0 0
0 0
0 L
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 D-2
RaOdiOegcOlEOOOviOOnmentaSapligocOtOnOOndMei Radiological Environmental Sampling Locations And Media Approximate Approximate Air Monitoring Arximt Distance from Diro t Vegetables Approximate Center of Direction Sector TLD Water Milk Sediment Fish and Food Ground-water Collection Sites of (degrees from Containment true north) Airborne Airborne Products (miles) Particulate Iodine Onsite Station, 110-meter weather tower 0.53 2930/WNW P X Onsite Station, adjacent to old plant access road 0.59 207 0/SSW K X X X Offsite Station, Intersection of Hwy. 75 and farm access road 0.94 145 0/SE G X Blair OPPD office 2.86 305 0/NW Q X X X Fort Calhoun, NE City Hall 5.18 150 0/SSE H X Fence around intake gate, Desoto Wildlife Refuge 2.07 102 0/ESE F X Onsite Station, entrance to Plant Site from Hwy.
75 0.55 1910/S J X Onsite Station, NW of Plant 0.68 305 0/NW Q X Onsite Station, WSW of Plant 0.61 242 0/WSW M X Offsite Station, SE of Plant 1.07 390/SE G X D-3
Radiological Environmental Sampling Locations And Media Approximate Approximate Air Monitoring Distance from Direction Vegetables C oximate Collection Sites Center of directiom (degrees from Sector Aron ibrePout TLD Water Milk Sediment Fish and Food Ground-water Containment trueAirborne Airborne Products (miles) Particulate Iodine Metropolitan Utilities Dist.,
Florence Treatment Plant North Omaha, NE 14.3 154 0/SSE H X West bank Missouri River, downstream from Plant discharge 0.45 108 0/ESE F X X Upstream from Intake Bldg.,
west bank of river 0.09 40/N A X X 0
Smith Farm 1.99 134 /SE G X Mohr Dairy 9.86 1860/S J X X Fish Sampling Area, Missouri 0.08 River (R.M. 645.0) 60/N A X Fish Sampling Area, Missouri 17.9 River (R.M. 666.0) 358 0/N A X Alvin Pechnik Farm 0.94 163 0/SSE H X Valley Substation #902 19.6 221 °/SW L X X X D. Miller Farm 0.65 203°/SSW K X D-4
RdooiaOOEOvO@rnetOlSampling OOcationsOAdedoia Radiological Environmental Sampling Locations And Media Approximate Approximate Air Monitoring Approximate Distance from Direction Vegetables Center of Sector TLD Water Milk Sediment Fish and Food Ground-water Containment (ree from Airborne Airborne Products (miles) true north) Particulate Iodine 0
Lomp Acreage 0.65 163 /SSE H X X X X Onsite Farm Field 0.52 11 80/ESE F X Offsite Station Intersection Hwy 75/Co. Rd.
P37 0.75 227 0/SW L X Offsite Station Desoto Township 1.57 144 0/SE G X X X Dowler Acreage 0.73 1750/S J X X X 0
Sector A-i 1.94 0 /NORTH A X Sector B-I 1.97 160/NNE B X Sector C-1 1.56 4 1/NE C X Sector D-1 1.34 71 °/ENE D X 0
Sector E- 1 1.54 90 /EAST E X 0
Sector F-1 0.45 108 /ESE F X 0
Sector G-I 1.99 134 /SE G X 0
Sector H-1 1.04 159 /SSE H X Sector J- 1 0.71 179 0/SOUTH i X 0
Sector K- 1 0.61 205 /SSW K X 0
Sector L- 1 0.74 229 /SW L X 0
Sector M-1 0.93 248 /WSW M X 0
Sector N- 1 1.31 266 /WEST N X D-5
Radiological Environmental Sampling Locations And Media Approximate Approximate Air Monitoring Approximate Distance from Direction Vegetables Collection Sites Center of (degrees from Sector TLD Water Milk Sediment Fish and Food Ground-water Containment t Airborne Airborne Products (miles) true north) Particulate Iodine Sector P-1 0.60 2910/WNW P X 0
Sector Q-1 0.67 307 /NW Q X Sector R-1 0 2.32 328 /NNW R X Sector A-2 0 4.54 350 /NORTH A X 0
Sector B-2 2.95 26 /NNE B X Sector C-2 3.32 500/NE C X 0
Sector D-2 3.11 75 /ENE D X 0
Sector E-2 2.51 90 /EAST E X Sector F-2 0 2.91 110 /ESE F X 0
Sector G-2 3.00 140 /SE G X 0
Sector H-2 2.58 154 /SSE H X Sector J-2 3.53 181°/SOUTH J X Sector K-2 0 2.52 205 /SSW K X Sector L-2 0 2.77 214 /SW L X 0
Sector M-2 2.86 243 /WSW M X Sector N-2 0 2.54 263 /WEST N X 0
Sector P-2 2.99 299 /WNW P X 0
Sector Q-2 3.37 311 /NW Q X Sector R-2 0 3.81 328 /NNW R X 0
Stangl Farm 3.4 369 /SOUTH J X D-6