Text

Proposed Change: Revised Activated Concrete Dcgl and More Realistic Activated Concrete Dose Modeling - License Condition 2.B.(10), License Termination
	ML032730682
Person / Time
Site:	Maine Yankee
Issue date:	09/11/2003
From:	Williamson T; Maine Yankee Atomic Power Co
To:	; Document Control Desk, NRC/FSME
References
	+sisprbs20060109, -RFPFR, MN-03-049, RA-03-130
	Download: ML032730682 (320)
	v • d • e

Maine Yankee 321 OLD FERRY RD. -WISCASSET, ME 04578-4922 September 11, 2003 MN-03-049 RA-03-130 Proposed Change No. 216 UNITED STATES NUCLEAR REGULATORY COMMISSION Attention: Document Control Desk Washington, DC 20555

References:

(1) License No. DPR-36 (Docket No. 50-309)

(2) Maine Yankee Letter to the USNRC, MN-02-048, dated October 15, 2002, "Revision 3, Maine Yankee's License Termination Plan".

(3) USNRC Letter to Maine Yankee, dated February 28, 2003, Issuance of Amendment No. 168 To Facility Operating License No. DPR-36

Subject:

Proposed Change: Revised Activated Concrete DCGL and More Realistic Activated Concrete Dose Modeling - License Condition 2.B.(10), License Termination Pursuant to 10 CFR 50.90, Maine Yankee hereby requests an amendment to the facility operating license (Reference 1) to indicate NRC approval of the attached supplement to the Maine Yankee License Termination Plan (LTP), Revision 3 (Reference 2). In this supplement, Maine Yankee proposes to modify the dose model for the containment activated concrete, rebar (hereafter referred to as simply "activated concrete") and liner, by incorporating more realistic radionuclide release rates and to change the associated DCGL for activated concrete. Maine Yankee intends to use the modified dose model and corresponding DCGL change, when approved, to facilitate a revised remediation strategy for the containment building. An amendment is required because the dose model described in the LTP is being revised and the DCGL is increasing by more than a factor of two'. The dose impact from the revised activated concrete remediation strategy and modified modeling combined is negligible, i.e., the activated concrete dose increases by less 0.006 mrem/yr.

Maine Yankee desires to revise the remediation strategy for containment as a result of lessons learned in the remediation and survey of other buildings such as the containment spray building and the primary auxiliary building. The revised strategy involves a more aggressive removal of the contaminated concrete that is inside the liner and leaving some additional activated concrete that is behind the liner in the Incore Instrumentation (ICI) Sump.

While the activated concrete DCGL metric is expressed in concentration and difficult to compare to a concentration distribution, it is clear that the total inventory of activated concrete activity will increase by more than a factor of two. Thus, the criteria for seeking NRC review, as stated in LTP Section 1.4, is satisfied.

P ,.s o

U. S. Nuclear Regulatory Commission Attention: Document Control Desk Page 2 Essentially, Maine Yankee now intends to remove all of the interior contaminated and activated concrete to the containment liner. This approach will eliminate the need for expending excessive resources on identifying and remediating contamination which may have penetrated cracks and crevices in the concrete to the liner and will leave behind a surface condition more suitable for instrument detection. Conversely, the removal of the activated concrete behind the liner requires very high resource expenditures relative to the dose saved because of the location and configuration of the material. Therefore, the revised strategy calls for leaving more of this material in place.

Using this approach, Maine Yankee will remove a higher volume of contaminated concrete from containment than proposed in the LTP and thus will remove more of the contaminated concrete source term. While the total activated inventory remaining will increase, over ninety percent of the activated concrete source term will be removed. The only region of the plant with any significant activated activity, per this proposed remediation plan, would be a six to eight inch width of activated concrete behind the liner in the ICI sump walls below the neutron shield tank. This portion of the containment (i.e., the ICI sump) is a right circular cylinder approximately twenty feet high, located between forty and sixty feet below grade.

Maine Yankee has examined the costs and logistical hazards associated with the removal of this concrete volume and believes that the safest approach, most consistent with ALARA principles, is to leave the liner and the activated concrete behind the liner intact, while removing all of the activated concrete inside or above the liner.

This submittal discusses two additional changes that, while not the subject of this request for NRC review (and approval), are described to provide a more complete description of changes to remediation plans. These are: (I) the reduction in the surface and deep soil DCGLs, and (2) the use of a building specific surface area to open basement volume (SAN) ratio for the containment building (containment). Both of these changes will be implemented through the 10 CFR 50.59 process after NRC approval of the activated concrete model and DCGL revision. While the increase in activated material inventory is fully accounted for by the changes in the dose model, the surface and deep soil DCGL's are being decreased to provide a corresponding decrease in the allowable inventory of soil activity. This is not required by regulation or LTP commitments; however, Maine Yankee believes these actions and their composite impacts present a reasonable approach to addressing both regulation and other stakeholder interests.

The LTP was approved by the USNRC via License Condition 2.B.(l0), on February 28, 2003 (Reference 3). The LTP demonstrates compliance with the radiological criteria for unrestricted use specified in 10 CFR 20.1402 by meeting the enhanced State of Maine dose criteria of 10 mrem/yr or less from all pathways and 4 rnrem/yr or less from groundwater drinking sources. The proposed dose model modifications and activated concrete DCGL change combined with the two other changes described above would cumulatively lower the total contaminated material annual dose (from all pathways) from 9.76 mrem/yr to 7.44 mrem/yr (7.27 mrem/yr for containment.) In addition, these changes will result in a reduction

U. S. Nuclear Regulatory Commission Attention: Document Control Desk Page 3 in a more accessible source term (soil) in contrast to an increase in a less accessible source term (activated materials).

Following NRC approval of the attached proposed license amendment, appropriate changes to the LTP will be made in accordance with the provisions of 10 CFR 50.71(e). The current decommissioning schedule calls for completion of the containment demolition in the first quarter of 2004; therefore Maine Yankee requests NRC approval of the license amendment by the end of 2003.

Attachment I provides a detailed discussion of the proposed changes, a no significant hazards consideration determination and an environmental impact consideration determination.

Attachment II provides a copy of the affected License Condition page with changes annotated. Attachment III provides a Brookhaven National Laboratory Report supporting the proposed change. Attachments IV through IX provide supporting inventory and dose calculation spreadsheets.

As discussed in Attachment I, Maine Yankee concluded that the proposed amendment meets the eligibility criteria for categorical exclusion set forth in 10 CFR 51.22 (c)(9). Therefore, no environmental impact statement or environmental assessment need to be prepared in connection with issuance of this amendment.

This change does not involve a significant increase in the probability or consequences of an accident previously evaluated, create the possibility of a new or different kind of accident fiom any accident previously evaluated, or involve a significant reduction in the margin of safety. Therefore, Maine Yankee concludes that the proposed change presents no significant hazards consideration under the standards set forth in 10 CFR 50.92(c), and, accordingly, a finding of"no significant hazards consideration" is justified. This determination is described in Attachment I. This proposed change has undergone an Independent Safety Review. The Independent Review and Audit Committee has also reviewed this proposed change. A representative of the State of Maine is being informed of this request by a copy of this letter.

If you have any questions, please contact us.

Sincl Thomas L. Williamson, Director Nuclear Safety and Regulatory Affairs Attachments I. Description and Evaluation of Proposed Change II. Proposed License Condition Changes (mark-up)

III. BNL Report: Assessment of Release Rates for Radionuclides in Activated Concrete

U. S. Nuclear Regulatory Commission Attention: Document Control Desk Page 4 IV. Activated Concrete Dose Assessment Using Revised Inventory and Dose Model V. Activated Liner Dose For Peak Activity and 50-Year Liner Breach VI. Dose Assessment Using 0.46 SA/V Ratio for Containment VII. Dose Assessment Assuming 100% Release of Activated Inventory VIII. Dose Assessment for Deep and Surface Soil Using 2.39 pCi/g DCGL IX. Revised Dose Summation Tables for Containment and Non-Containment cc:

Dr. R. R. Bellamy, NRC Region I D. R. Lewis, Esq., Shaw Pittman Ms. P. Craighead, Esq., State of Maine, Nuclear Safety Advisor Mr. P. J. Dostie, State of Maine, Division of Health Engineering Mr. J. T. Greeves, NRC Director, Division of Waste Management Ms. E. Mason, Esq., USEPA New England, Office of Regional Counsel Mr. H. J. Miller, NRC Regional Administrator, Region I Mr. J. Buckley, NRC NMSS Project Manager, Decommissioning Mr. R. Ragland, NRC Region I Mr. R. Shadis, Friends of the Coast

AFFIDAVIT STATE OF MAINE Then personally appeared before me, Thomas L. Williamson, who being duly sworn did state that he is the Director, Nuclear Safety and Regulatory Affairs of Maine Yankee Atomic Power Company, that he is duly authorized to execute and file the foregoing request in the name and on the behalf of Maine Yankee Atomic Power Company, and that the statements therein are true to the best of his knowledge and belief.

Notary Public My commission expires n9. lII M6

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216

Subject:

Revised Activated Concrete DCGL and More Realistic Activated Concrete Dose Modeling Table of Contents

1.0 DESCRIPTION

.......................................................... 2 2.0 PROPOSED LICENSE CONDITION CHANGE .......................................................... 2

3.0 BACKGROUND

.......................................................... 4 4.0 ACTIVATED MATERIALS REMEDIATION STRATEGY .......................................... 5 4.1 Physical Description of Areas Containing Activated Concrete and Liner ..................... 5 4.2 LTP Activated Materials Remediation Approach ........................................................ 10 4.3 Revised Activated Materials Remediation Strategy ..................................................... 11 4.4 Reasons for Activated Materials Remediation Change . ...............................................

1 5.0 CHARACTERIZATION OF ACTIVATED CONCRETE, REBAR, AND CONTAINMENT LINER ......................................................... 14 5.1 Summary of Current LTP Information ......................................................... 14 5.2 Additional Characterization Cores ......................................................... 18 5.3 Calculation of Remaining Activated Concrete Inventory . ...........................................

23 5.4 Calculation of Activated Liner Inventory .......................................... 27 5.5 Additional Characterization Data to be Collected .................................... 30 6.0 DOSE MODELING ......................................................... 31 6.1 Revision to Activated Concrete Dose Model ......................................................... 31 6.2 Activated Steel Liner ......................................................... 36 6.3 Revision to Containment SAN Ratio ......................................................... 36 6.4 Decrease in Soil DCGL ......................................................... 38 6.5 Revised Dose Summation Tables ......................................................... 38 7.0 FINAL STATUS SURVEY ......................................................... 39 7.1 Proposed FSS for Activated Concrete ......................................................... 39 7.2 Impact of Reduced Soil DCGL .................................................. 39 8.0 OTHER CONSIDERATIONS........................................................................................40 8.1 ALARA ......................................................... 40 8.2 LLRW Disposal Impacts ......................................................... 40 9.0 REGULATORY SAFETY ANALYSIS ......................................................... 41 9.1 No Significant Hazards Consideration ......................................................... 41 9.2 Applicable Regulatory Requirements/Criteria.............................................................43

10.0 ENVIRONMENTAL CONSIDERATION

(10 CFR 51.22) . ..........................................

44

11.0 REFERENCES

.......................................................... 45 I-1

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216

1.0 DESCRIPTION

This letter is a request to amend Operating License No. DPR-36 for Maine Yankee, specifically License Condition 2.B.(10), which indicated USNRC approval and authorized implementation of the Maine Yankee License Termination Plan (LTP) into the Facility Operating License2. Maine Yankee is requesting NRC review and approval of the proposed change to modify the dose model for activated concrete and rebar (hereafter referred to as simply "activated concrete") and liner by incorporating more realistic radionuclide release rates and to change the associated DCGL for activated concrete. Maine Yankee intends to use the modified dose model and corresponding DCGL change, when approved, to facilitate a revised remediation strategy for the containment building. An amendment is required because the dose model described in the LTP is being revised and the DCGL is increasing by more than a factor of two3 . The dose impact from the revised activated concrete remediation strategy and modified modeling combined is negligible, i.e., the activated concrete dose increases by less 0.006 mrem/yr.

The revised plans, described here, address key elements of the approved LTP. As such, this information constitutes a supplement to the LTP. This supplement demonstrates that Maine Yankee will continue to comply with the radiological criteria for unrestricted use specified in 10 CFR 20.1402 by meeting the enhanced State of Maine dose criteria of 10 mrem/yr or less from all pathways and 4 mrem/yr or less from groundwater drinking sources.

This submittal discusses two additional changes that, while not the subject of this request for NRC review (and approval), are described to provide a more complete description of changes to remediation plans. These are: (1) the reduction in the surface and deep soil DCGLs, and (2) the use of a building specific surface area to open basement volume (SA/V) ratio for the containment building (containment). Both of these changes will be implemented through the 10 CFR 50.594 process after NRC approval of the activated concrete model and DCGL revision.

2.0 PROPOSED LICENSE CONDITION CHANGE The proposed change will amend License Condition 2.B.(10) to reference the date of this supplement to the LTP and the date of the USNRC SER, when approved. The subject of this request for NRC approval is a modification to the activated concrete dose model by incorporating more realistic nuclide release rates and a change to the DCGL for activated 2 LTP Revision 3 was submitted on October 15, 2002 (Reference 11.1). License Condition 2.BR(10) was issued by USNRC as Amendment No. 168, on February 28, 2003 (Reference 11.2).

While the activated concrete DCGL metric is expressed in concentration and difficult to compare to a concentration distribution, it is clear that the total inventory of activated concrete activity will increase by more than a factor of two. Thus, the criteria for seeking NRC review, as stated in LP Section 1.4, is satisfied.

4 The subject changes will also be evaluated by the criteria specified described in the license and LIT Section 1.4.1. References throughout this attachment made to the use of the provisions of §50.59 should be taken to mean that the requirements for evaluating LTP changes per License Condition 2.B.(10) and LTP Section 1.4.1 will be observed.

I-2

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 concrete. Other changes such as the reduction in the surface and deep soil DCGL and the use of a containment building specific ratio of surface area to open basement volume are included for completeness but are not the subject of the request for NRC approval. Following NRC approval, Maine Yankee will revise the LTP to reflect the changes described in this supplement, in accordance with 10 CFR 50.71(e).

Currently, License Condition 2.B.(l0) states (in part) the following:

2.B.(10) License Termination (i) The Maine Yankee License Termination Plan describes an acceptable approachfor demonstratingcompliance with the radiologicalcriteriafor unrestricteduse, as defined by 10 CFR 20.1402, by meeting a site release criteriaof 10 millirem TEDEperyear over background(allpathways) and 4 millirem (as distinguishablefrom background) TEDEperyearfor groundwatersources of drinking water using appropriatedose modeling methods, pathways andparametersand acceptablefinal radiationsurvey methods.

The licensee shall implement and maintain in effect all theprovisions of the approvedLicense Termination Plan submitted on August 13, 2001, as supplemented and approvedin the SER dated February28, 2003, subject to and as amended under thefollowing stipulations:

Maine Yankee is proposing to revise License Condition 2.B.(10) as follows:

2.B.(J0) License Termination (i) The Maine Yankee License TerminationPlan describesan acceptable approachfor demonstratingcompliance with the radiologicalcriteriafor unrestricteduse, as defined by 10 CFR 20.1402, by meeting a site release criteriaof 10 millirem TEDEperyear over background(allpathways) and 4 millirem (as distinguishablefrom background) TEDEperyearfor groundwatersources of drinking water using appropriatedose modeling methods, pathways andparametersandacceptablefinal radiationsurvey methods.

The licensee shall implement and maintain in effect all the provisions of the approvedLicense Termination Plan, as submitted and approved infollowing documents:

Licensee Submittal SER Approval: I! 0 -I.. l August 13, 2001, as supplemented on February28, 2003 October 15, 2002 September 11, 2003 I-3

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 subject to andas amended under the following stipulations:

Attachment II to this submittal contains a proposed mark-up of the Facility Operating License, as described above.

3.0 BACKGROUND

The LTP indicates that structures will be demolished to an elevation corresponding to three feet below grade. Maine Yankee still intends to demolish structures, including the containment building structure to an elevation corresponding to three feet below grade.

However, as a result of lessons learned during the remediation of the containment spray building and primary auxiliary building (PAB), Maine Yankee intends to pursue a more aggressive remediation strategy of removing additional interior below grade concrete in the containment building. Essentially, Maine Yankee now plans to remove the containment building interior below grade concrete down to the containment liner. This results in less contaminated concrete surface area and less potential for the need to pursue remediation of contamination in cracks and crevices. Removing concrete down to the liner also leaves a smoother surface that enhances the detection capability of survey instruments.

As part of this remediation strategy, Maine Yankee is proposing to leave the containment liner in place. In LTP Revision 3, Maine Yankee stated that activated portions of the remaining foundations above the activated concrete DCGLs will be removed. This would have required penetration of the containment liner and removal of volumes of concrete. Over 93% of the activated concrete resides inside the containment building above the liner and will thus be removed. Maine Yankee is proposing not to remove the remaining 7% of activated concrete inventory. As described in the characterization section of this document (Section 5.0), this remaining activated concrete is located primarily in the walls of the ICI Sump from the sump floor up to the bottom of the NST (See Figure 2 in Section 4.1). As discussed in Section 4.4, removal of this activated concrete would be unnecessarily costly, resource intensive and hazardous.

If the increased activated concrete activity inventory were to be inserted into the basement fill model as described in the current LTP, the dose from the activated concrete would increase.

The basement fill model assumes an instantaneous release of activated inventory in the first year. A more realistic radionuclide release rate and associated DCGL is being proposed (Section 6.0) that results in a smaller increase, and more realistic dose, that remains within the enhanced State of Maine unrestricted use dose criteria of 10 mrem/yr.

As noted in the Section 1.0 above, two additional changes are described in this submittal: (1) the reduction in the surface and deep soil DCGLs, and (2) the use of a building specific surface area to open basement volume (SAIV) ratio for the containment building. While not the subject of this request for NRC review (and approval), they are described to provide a more complete description of changes to remediation plans. Section 6.0 integrates the SAIV change into the revised activated concrete dose model calculations (Section 6.3), and also includes a description of the reduction in the soil DCGL (Section 6.4). Section 7.0 also discusses the impact of the change in soil DCGL on FSS requirements (Section 7.2).

1-4

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 The proposed remediation strategy has been evaluated for its effect upon the final state of the site and associated impacts on dose assessment, survey design and environmental assessment.

Maine Yankee has evaluated the dose significance of the release of the radioactive inventory associated with this activated material and concluded that the dose to the critical group, the resident farmer, is within the dose based NRC radiological criteria for license termination and the State of Maine enhanced radiological criteria. Survey design considerations have been evaluated and are described in the Final Status Survey section of this document.

Environmental assessment considerations relate primarily to an increase in low level waste disposal volumes and are evaluated and described in the Environmental Considerations section of this document. Maine Yankee's dismantlement activities and proposed remediation strategy will continue to be performed in accordance with 10 CFR Part 50 and will not be inimical to the common defense and security or to the health and safety of the public.

4.0 ACTIVATED MATERIALS REMEDIATION STRATEGY 4.1 Physical Description of Areas Containing Activated Concrete and Liner

a. The reactor pressure vessel (RPV) was enclosed and shielded by a combination of the primary shield wall and the ICI sump. The major arrangements of these structures are illustrated in Figure 1 below ("Primary Shielding Arrangement," FSAR Figure 11.1 -3). Additional detail of this arrangement is provided in Figure 2. The RPV is further shielded by the neutron shield tank (NST) which is supported inside the ICI sump.

b. The ICI sump is a right-circular cylinder, approximately 37' tall with a radius of 11.8' for the majority of that height. The lower 2' has a radius of 8.5'. The walls of the ICI sump vary in thickness but are a minimum of approximately 7'

c. The containment's carbon steel liner is attached to the inside walls of the ICI sump. The liner is covered by the NST (and grout) for the height of the NST. The walls (vertical sections) of the liner are 3/8" thick; the floors (horizontal sections) are 1/4" thick. There are also two locations where concrete is poured on top of the liner. The ICI sump floor has approximately 2' of concrete on top, from -39 to -37. And the outer radius from -34 to -32 also has an approximate two-foot pour. See Figure 2. On one side of the ICI sump, there is a horizontal tunnel (1O' x 1O') that provided access to the ICI sump area beneath the RPV. Figure 3 illustrates this arrangement, relative to the sump and RPV.

d. The revised remediation plans now call for all concrete in the containment, above 4' elevation, to be removed. Revised remediation plans call for the removal of the concrete poured on top of the liner at -32' to -34' and on top of the liner at -39' (i.e., the ICI sump floor concrete). Thus, the remaining 1-5

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 concrete with significant activity from activation would be located in the ICI sump walls, behind the liner, from -37' to -4'.

1-6

-4.

-a~~~~~~~ 4... Primary Shield Ulall

.*4

, / Neutron Shield T ank 4-A,0 I1 III 4..

A. *

.4.

4..,.

4

4

. 4..

a A- __________

.. *-j. 44* a 4.. .4 . I *.. - A . .4 . . -

-37 Elev

-39 Elev

4 A.-. S A' Fi-eure 1- Primary Shielding Arrangement 1-7

Primary Shield Wall Containment Floor Cores 5-1,5 (-1 Elev)

-4' A.

! Neutron'ShieldTank 4r Top of Popcorn doncreted4 It

-^,~ - SrR49.k

' ' I\ -14',.,

I ~~Sound Rock 4 or Fill Concrete II Sound Rock Liner or Core 12-8 (-22 Elev)

Fill Concrete I

-2" Core 12-7 (-29 Elev)

'A 190 Top of Popcom Concrete 6

-47 B-B Fizure 2- Core Locations 1-8

a 7w .* ,. I f7 . . . , ;, #-. ,

.-OW-MMONOWONVOOMM . - A I W--q"

-4.

Tcooccm eoncretif, sh 0'

SoLrM Rock Swo,Rock

.67 or Fill Cavcete 11 Fill Ccocrete Tu'ril ICY xIO ITop of 7.2 Pcvom Concrete\ -1 f67 I T~~I -E -

IA~ _0

-B!-2' Ow~ 4 VII -3T-2Z

-3r z ___

.4 - ~ ~ ~ ~ ~ 4. -3(Y-2' E7.4 4 >~~~~~~~~

. I 7~e2 Top of rJ~corn Corcreh .

,q I

1 ~~-4 . Po .I .....I-1. II-i 1- --

.47 32550 A A-A Figure 3 - ICI Sump Tunnel Arrangement I-9

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 4.2 LTP Activated Materials Remediation Approach In the LTP Maine Yankee identified activated concrete as a material for which some residual radioactivity would be left at the site. It was assumed that Maine Yankee would remediate the activated concrete to a value of I pCi/g throughout the relevant locations of the containment building. It was expected that as much as two feet of concrete would be removed throughout the walls and floor of the ICI Sump. Maine Yankee based its two feet expectation upon activated concrete depth profiles taken from core bores from the ICI sump floor. The lpCi/g DCGL included the activity from all nuclides in the activated concrete nuclide mixture. The dose from activated concrete was calculated by determining the mass of concrete that would remain after remediation to 1 pCi/g, multiplying the mass by 1pCi/g to determine the total inventory, and inputing the total inventory into the basement fill dose assessment spreadsheet. The total inventory was assumed to be instantaneously released to the basement of containment in the first year. In Section 6.6.2.a of the LTP, Maine Yankee envisioned the possible future need to incorporate more realistic radionuclide release rate into the activated concrete dose model as follows:

"A conservative screeningapproachwas used to accountfor the activated concrete source term by assuming that the entire inventory of the residualactivity in the activated concrete, at all depths, is immediately releasedinto the 738 m 3 of water in the basementfill. A more realisticmodel would accountfor thefact that the activated inventory would be released very slowly over time... "

Following activated concrete remediation, LTP section 6.6.2.b referred to a final dose assessment based on the actual remediation level selected and a final status survey of the ICI Sump area as follows:

"The surface activity (measured volumetrically) is the measurable quantity that will be used to demonstrate compliance duringthefinal status survey. However, the total inventory, i.e., source term, includes the radionuclidesin the entire volume of activatedconcrete, including surface andsubsurface. The total inventory was determined to be 3.30E+08pCi as described in Attachment 6-6. This inventory may change if the remediationlevel (i.e., DCGL)for activatedconcrete is changed. The final dose assessment will be based on the actual remediationlevel selected."

The total inventory of 3.30E+08 pCi, as calculated in LTP Attachment 6-6, resulted from the planned removal of 22 inches of the ICI sump floor, and 24 inches of the concrete walls.

1-10

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 4.3 Revised Activated Materials Remediation Strategy Maine Yankee now plans to remove the interior below grade concrete down to the containment liner. Thus, all containment building interior concrete above the -4 foot elevation would be removed. The 3-4 inches of grout between the Neutron Shield Tank (NST)/Skirt and the liner would be removed following removal of the NST and NST skirt. The activated concrete on the floor of the ICI Sump and sump would also be removed. This plan would leave the activated concrete behind the liner on the walls of the ICI Sump, which is a change from the current LTP plan of removing 24 inches of the concrete walls.

While the removal of all concrete above the - 4 foot elevation results in a decrease in contaminated concrete inventory, leaving the activated concrete behind the liner results in an increase in the activated concrete activity inventory from 0.33 mCi to 20.8 mCi. An additional 26 mCi of activated liner activity will also be left. As noted above in LTP Section 6.6.2, the final dose assessment therefore, should be based upon the inventory resulting from the actual remediation level. Currently the DCGL for activated concrete is expressed in a concentration of 1 pCi/g. In leaving the activated concrete behind the liner, the activated concrete activity concentration would consist of a distribution. A better metric for this case is the total activated concrete activity inventory which is derived by integrating the concentration distribution over the activated volume to a conservative depth e.g., two feet. In LTP Section 1.4. 1, Maine Yankee committed to seek NRC approval if it increased a DCGL by more than a factor of two. While the activated concrete DCGL metric is expressed in concentration and difficult to compare to a concentration distribution, it is clear that the total inventory of activated concrete activity will increase by more than a factor of two; therefore, Maine Yankee is seeking NRC approval for this increase.

4.4 Reasons for Activated Materials Remediation Change Maine Yankee has gained considerable experience with concrete demolition and the effectiveness of various remediation techniques as decommissioning has progressed. Based on the experience and lessons-learned from earlier concrete demolition (e.g., in the Spray Building), a refined Containment demolition plan was developed. Essentially, Maine Yankee now plans to remove the containment building interior below grade concrete down to the containment liner, with the liner itself essentially intact. This results in less contaminated concrete surface area and less potential for the need to pursue remediation of contamination in cracks and crevices. Removing concrete down to the liner also leaves a smooth surface that enhances the detection capability of survey instruments. In addition, the liner has been a pressure tested protective membrane throughout plant operations. Leaving the liner in place provides an additional barrier to the movement of radionuclides from the 1-11

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 structural concrete into the basement fill volume, as discussed and analyzed in detail in Section 6.

As part of planning this remediation strategy, Maine Yankee evaluated the difficulty, hazards, and cost of removing concrete behind the liner in the ICI Sump walls. These elements are summarized below.

Difficulty and Hazards All of the activated concrete to remain is located behind the containment liner.

The vertical sections of the liner are constructed of 3/8" thick carbon steel plates with full penetration welds at the seams. The back side of every seam is covered with a welded channel that serves as a leak test channel for the liner.

The entire liner below elevation -4' is secured into the concrete with multiple anchors, 5" long welded nelson studs on 12" centers, 12" "L" type welded anchors at 16" centers on the corners, and the attachments for the bridging bar that held the Neutron Shield Tank and the Primary Shield Wall. The exterior horizontal surfaces of the liner below the -4' elevation are 1/4" thick and are clad with monel; the stud attachments are also monel in this area.

The concrete identified as activated will also contain a significant amount rebar, up to and including #18s bars, with the first layer to be encountered located 6" behind the liner.

The work to remove the liner, rebar, and activated concrete would be similar to a mine shaft installation approximately 27' diameter and 60' below grade with additional remediation work to remove the activated concrete located in the ICI Sump access tunnel 53' below grade.

Initially, the liner removal would require vertical segmentation. Thermal cutting is generally considered to be the most cost effective; however, the industrial safety aspects of cutting the liner in this deep excavation while backed with concrete are of significant concern. Some of the industrial safety considerations related to this work are: (1) fall protection, (2) high temperature personal protection equipment for the slag due to the concrete "explosions" (sparks/slag), (3) egress and access into the ICI Sump area, (4) permitting of confined spaces, (5) effective deployment of emergency personnel retrieval team, (6) material stabilization and removal, (7) point of source smoke capture, (8) work control and emergency communication effectiveness, and (9) atmospheric testing and maintenance. After the liner is segmented, it is expected that explosives would be used to crack and separate the concrete and push the liner inward. The use of explosives would most likely follow with a series of blasting campaigns. The resulting demolition material would then be removed from the sump area using an excavator and manual labor for cleanup.

The campaign would then be repeated until the excavation is completed.

1-12

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Additional work thermal cutting of the rebar and bottom liner, and concrete smoothing may be required to achieve a surface that would allow the performance of FSS.

The underground blasting raises the potential for ground water in-leakage The most recent groundwater surveys around the site identify the phreatic contours around containment at approximately elevation 8'.

Cost The cost to remove the activated concrete behind the liner is estimated as follows:

Labor $293,700.

Materials $180,400.

Subcontractors $175,000.

Equipment $80,000. /

Total $729.100.

The costs associated with waste disposal are estimated to be about $70,000 for a total cost estimate of $800,000 to remove the activated concrete behind the liner There are increased demolition and waste disposal costs associated with the proposed strategy for aggressive removal of containment building interior concrete, however, these costs are believed to be offset by the possible costs associated with remediation and survey of contamination which might have penetrated into the concrete through cracks and crevices.

Conclusion Maine Yankee has evaluated the difficulty, hazards and cost of removing the activated concrete behind the liner in the ICI Sump walls and has concluded that the safest approach, consistent with ALARA principles, is to leave the liner and the activated concrete behind the liner intact The technical analysis that follows shows that, even with leaving the activated concrete behind the liner, in excess of 93% of the activated concrete inventory will be removed during the remediation of the Containment Building.

1-13

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 5.0 CHARACTERIZATION OF ACTIVATED CONCRETE. REBAR. AND CONTAINMENT LINER 5.1 Summary of Current LTP Information

a. In general, the LTP remediation strategy, as discussed above, was to remove all activated concrete with activity above I pCi/g. The dose assessment related to the remaining activity relied on characterization work performed during initial and continuing characterization efforts. Concrete sample cores were obtained from the containment structure, missile shield, incore instrumentation (ICI) sump floor, and reactor nozzle penetrations.

Initial assessments (for LTP purposes) of activated concrete built on an activation analysis study that had been performed to support the classification of the reactor vessel, reactor internals, and material immediately surrounding the reactor for waste disposal considerations.

This activation analysis provided useful insights regarding the location and extent of activated concrete. High neutron fluence levels were predicted at the missile shield (which has been removed), the ICI sump floor, and the reactor nozzle penetration. This conclusion was based on either their proximity to the reactor core or the relative lack of shielding in the axial direction from the core. The activation analysis predicted lower specific activity in the shield walls surrounding the reactor vessel due to the attenuation provided by the water-filled neutron shield tank (NST). Based on the activation analysis work, focus was then placed on sampling of the ICI sump floor which was expected to exhibit the highest activity from activation.

b. LTP Section 2.5.3.b summarizes the characterization work performed to establish the nuclide profile (or fraction) for activated concrete and rebar.

The nuclide fraction set by sampling and analysis of the core data is presented in LTP Table 2-9. (For convenience, the data from LTP Table 2-9 is repeated below in Table 1.) A nuclide fraction for activated rebar was also established and provided in Table 2-9. As discussed in LTP 2.5.3.f, a dose assessment comparing both profiles concluded that it was more conservative to assume 100% activated concrete. Thus, the activated concrete nuclide fraction LTP Table 2-9 was used for the LTP dose assessment presented in LTP Section 6.

1-14

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Table I Activated Concrete and Rebar Nuclide Fractions Decay Corrected to January 2004 (Duplicated from LTP Table 2-9)

Concrete as of Rebar as of 1/2004 1/2004 Nuclide Fraction Fraction H-3 0.647 -

C-14 0.058 Fe-55 0.124 0.910 Ni-63 0.007 0.006 Co-60 0.040 0.084 Cs- 134 0.0084 Eu-152 0.111 Eu-1 54 0.009

c. As discussed above, numerous concrete core samples were taken to support activated concrete characterization. However, the primary focus was on ICI sump area due to the high, unshielded neutron radiation exposure to this region around and below the reactor vessel and the expected high level of activation. Cores in the ICI sump floor confirmed that the floor area exhibited the highest reported values of specific activity. A total of five cores were taken from the ICI sump floor during the initial and continuing characterization process. As part of the characterization program these cores were sliced and counted on-site using gamma spectroscopy. Two of the cores from this highly activated area (ICI sump floor) were also shipped to an independent laboratory 5 and were analyzed for hard-to-detect nuclide content. One of the ICI sump floor core samples included a portion of rebar. This portion of rebar was also analyzed for HTD nuclides by the same independent laboratory. The final nuclide fraction presented in the LTP Table 2-9 and used in the LTP dose assessment was based on these HTD analyses.

d. The final nuclide fractions for both activated concrete and rebar presented in LTP Table 2-9 showed good correlation with the nuclide fraction results for these media provided in NUREG/CR-3474. Additional data and discussion supporting this was provided by Maine Yankee in response to the Request for Additional Information (RAI), Question 14 (Attachment I of Reference 11.3).

5 Duke Engineering and Services Enviromnental Laboratory.

1-15

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216

e. Cores of extended depth (from the ICI sump floor) were also evaluated regarding the variance of both activity and fuclide fraction with depth.

LTP Table 2-10 provides the results of one of the extended depth cores taken from the ICI sump floor. (Table 2 below duplicates the data from LTP 2-10.) This table exhibits the expected variance with depth, namely a typical maximum value several inches from concrete surface. The table also demonstrates that specific activity decreases relatively quickly with depth, such that specific activity at greater than approximately 20" is 1 pCi/g or less.

f. As discussed in Maine Yankee's response to RAI-14 (Attachment I of Reference 11.3), nuclide fractions were found to be quite consistent throughout the depth of concrete. Only the total activity changes with depth. This is an expected outcome since the nuclide fraction would be governed primarily from the relative fraction of the chemical constituents of the concrete. Activation and specific activity would vary with thermal neutron fluence levels, but nuclide fraction should not vary with depth.

Quality controls on containment concrete mixing and construction were in place to ensure reasonably consistent relative ratios of "target" atoms within the concrete. The consistency in concrete construction methods is in part demonstrated by consistency of nuclide fractions at various depths and locations containing activated concrete. (See also, the Maine Yankee response to RAI 14, Reference 11.3.)

1-16

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Table 2 Activated Concrete: Deep Core Sample Activity Profile Depth (in)*

Activity Depth (in) Activity (pci/g)* *_* (pci/g)*4*

0 - 0.5 677* 10.75 - 11.5 87 0.5 - 1.0 828 11.5 - 12.25 23 1.0- 1.5 845 12.25- 13.0 23 1.5 - 4.0 824 13.0 - 13.75 17 4.0-4.75 771 13.75- 14.5 14 4.75 - 5.5 329 14.5 - 15.25 14 5.5 - 6.25 534 15.25 - 16.0 11 6.25 - 7.0 365 16.0- 16.75 7 7.0 - 7.75 290 16.75 - 17.5 6 7.75 - 8.5 233 17.5 - 18.25 6 8.5 - 9.25 206 18.25 - 19.0 1 9.25- 10.0 182 19.0 -20.0 I I 0. - 10.75 103 11111

Adjusted to remove Cs-137 surface contamination from the total activity

- Note that the depth column represents a "laber' for each sequential slice and is not intended as an exact measurement. The slices were generally %/2"to %" but were not uniform in thickness. Therefore, while Table 2-10 presents the profile out to 20 inches, this represents all of the data available for the entire 22-inch core.

- - Measured activity provided in this table includes gamma detectable activity from the nuclides listed in Table 2-9.

g. At the time of the LTP review, Maine Yankee considered characterization data more than adequate to support characterization and dose assessment for the remediation strategy planned. Based on an analysis of activation impact and the characterization information, it was concluded that the ICI sump floor represented the highest area of activity for remaining concrete.

Additional confirmatory samples were planned for the ICI sump walls once the reactor vessel was removed, thus reducing background radiation levels.

(Additional core samples taken and analyzed to support this revised remediation approach are described below.)

1-17

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 5.2 Additional Characterization Cores

a. To support the revised remediation strategy, additional characterization data was required. Because the strategy called for more aggressive remediation of activated concrete above -4', additional sampling was needed to support remediation planning, radiation protection, and contamination control considerations. As a result, a substantial campaign to obtain concrete cores from a wide range of areas was designed and implemented in 2002. Also, since activity would now remain behind the liner in the ICI sump walls, the additional cores were useful to support a conservative assessment of remaining inventory.

b. The new sampling campaign included additional samples from:

(1) the primary shield wall (+ 15' and -1' elevations),

(2) the ICI sump wall (-22' and -29' elevations),

(3) the containment floor, including specific areas that exhibited cracks

(-2' elevation),

(4) walls of the upender pit (+13.5' elevation), crane walls (-I' and +10 elevations), and (5) miscellaneous other floor samples.

These cores were sliced in 1/2 inch slices and subject to gamma spectroscopy

c. The analysis of the results from this latest activated concrete characterization campaign confirmed the original assessment that the NST was highly effective in minimizing neutron exposure to concrete and other materials surrounding the RPV. Those areas that were exposed to relatively high neutron fluence showed corresponding high levels of activity. For example, cores in the shield wall at +15' elevation reported activities of > 2700 pCi/g (gamma emitters only) near the concrete surface.

The reported activity did not reach the 1 to 2 pCi/g range until a depth of approximately 18" to 19" at this elevation. (This wall will be removed above -4' elevation.)

d. Concrete protected by the NST showed little or no activation of significance. No additional information is provided here related to concrete to be remediated and removed since the principal focus here is to support an assessment of the inventory for the remaining activated concrete, which is primarily in the ICI walls behind the containment liner.

e. The new information related to the remaining activated concrete is associated with the following cores. Refer to Figure 2.

(1) Primary shield wall; core taken behind the NST, at -1' elevation. (Cores 5-1,5; Figure 2).

(2) ICI sump wall; -22' elevation (Core 12-8, Figure 2).

1-18

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 (3) ICI sump wall; -29' elevation (Core 12-7, Figure 2).

f. A summary of the reported activity associated with the initial several inches of concrete depth for the cores at elevations -1', -22', and -29' is provided in Table 3. The material sampled by the core at 1' elevation in the primary shield wall was fully shielded by the NST; and, therefore, the core exhibited very limited activation. The remaining two cores were also as expected. Overall, these two cores (at elevations -22' and -29') were comparable, with the higher elevation core (-22') having slightly higher levels of activity near the exposed surface, likely due to the closer distance to the core. More importantly, both wall samples reported considerably less activity (near the exposed surface) in comparison to the ICI sump floor (as shown in LTP Table 2-10 with a peak of 845 pCi/g at 1.5"). This comparison supports the earlier LTP assessment that the highest activity in the remaining activated concrete is located in the sump floor. Note that the concrete core above the NST exhibited higher activity than the floor cores.

However, this concrete will be removed.

Figures 4 and 5 illustrate the axial profile of the activity (gamma emitters) for the cores taken at the -29' and -22' elevations, respectively 6 .

Table 3 Additional Characterization Results for Cores from the Primary Shield Wall and ICI Sump Walls (Activities Gamma Emitter inpCi/g, Note 1)

<gv 0.5" 1.0" 1.5" 2.0" 2.5" (Core ID2s Primary Shield < 3.2 <3.2 <3.2 <3.2 <3.2 Note 2 Cores 5-1 Wall (-1') through 5 ICI Sump 116.4 132.9 121.8 104.5 95.9 Note 3 Core 12-8 Wall (-22')

ICI Sump 102.6 98.0 76.4 70.9 60.7 Note 4 Core 12-7 Wall (-29') I Notes:

1. Activities listed are for gamma emitters only. The total activity concentration is obtained by a correction factor of 0.168 based on the activated concrete nuclide fraction (to account for the presence of HTD nuclides, principally H-3).

2. This location was fully shielded by the NST and exhibited very low activity.

3. Activities of < 1 pCi/g were reached at approximately 13" depth.

4. Activities of< I pCi/g were reached at approximately 16" depth.

6 The cores at -29' and -22' were actually approximately 24" in length. Figures 4 and 5 illustrate only the portion of the core that reported significant activity (i.e., > approximately I pCi/g).

I-19

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 120 I

' 100 - Figure 4. Specific Activity Variance with Core Depth P Core 12-7, ICI Sump Wall (EL. -29'), Gamma Emitters

-80 C

C0 '

Q 2020 >.7Sg 0.5 1.5 2.5 3.5 4.5 5.5 6.5 7.5 8.5 95 10.5 11.5 12.5 13.5 14.5 15.5 Depth (Inches) 140 120

-e g g Figure 5. Specific Activity Variance with Core Depth, 100 - Core 12-8, ICI Sump Wall (EL. -22'), Gamma Emitters 0 80 ' l 0, , -i 60 20 Sic acivtio vaie wit netro flec, th seeto an use o, core 0

0.5 1.5 2.5 3.5 4.5 5.5 6.5 7.5 8.5 9.5 10.5 11.5 12.5 13.5 14.5 Depth (inches)

g. Since activation varies withi neutron fluence, thie selection and use of core locations must also take into account how the fluence variability might I-20

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 impact activation levels around the reactor core. Neutron radiation from the reactor core varies in three dimensions, i.e., along the reactor vertical axis, radially from the core center, and circumferentially (i.e., by azimuth direction around the core). The above discussion deals with the axial and radial directions, in terms of distance out from the core and displacement up and down axially. To address circumferential variation, the additional cores taken at elevations -I', -22', and -29' were located in consideration of the approximate maximum neutron fluence. This discussion provides additional detail regarding that placement and the conservatism involved.

h. Neutron exposure at the RPV is monitored and projected due to embrittlement considerations over the vessel lifetime. This neutron exposure information can be used, for decommissioning purposes, to inform decisions regarding neutron variance around the core at greater distances, such as, to the ICI sump and related structures. Maine Yankee reactor engineering measurements have shown that the Maine Yankee reactor core produces a neutron exposure pattern at the RPV that exhibits "octant symmetry." That is, fluence levels consistently repeat each 45 degrees around the core.

i. For the subject octant in which the new 2002 cores were obtained, the maximum is approximately at the 260 degree azimuth. The cores were taken from a location that was approximately on the 270 degree azimuth.

Maine Yankee Reactor Engineering studies for early reactor core cycles (to support assessment of neutron embrittlement of the reactor pressure vessel) show that the accumulated neutron exposure (in terms of fluence) at the 270 degree azimuth was about 20% greater than the average in the octant. 7 See Figure 6. Early in plant operation, due to programs to reduce neutron exposure to the RPV, reactor fuel management practices were implemented to "flatten" flux shapes and, thereby, minimize vessel exposure from neutron radiation. The octant fluence shape for Cycle 8 illustrates that these measures were successful (Figure 6). The same can be seen in the neutron flux profiles, comparing Cycles 1 through 6 with the later Cycle 8 (Figure 7).

j. The fluence shape for Cycle 8 (Figure 6) indicates that the neutron exposure at 270 degrees is about 6% greater than the average in the octant.

Therefore, the concrete wall cores obtained from that azimuth would over-estimate the degree of activation in the sump walls by at least this amount.

In fact, since the ICI sump walls are more distant from the reactor core than the RPV walls, neutron diffusion would tend to further "flatten" the neutron flux variance in a given octant. Overall, Maine Yankee concludes 7 In that neutron fluence from the reactor core exhibits a pattern of octant symmetry, the fluence and flux shapes apply to each octant around the reactor core.

1-21

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 that an azimuth angle of 270 degrees is a conservative selection for concrete core samples (from the standpoint of azimuthal flux variations).

k. Rebar characterization data was used to support an estimate of activated activity within the containment steel liner. See Section 6.2 below.

Figure 6. Percent Over-Estimation of Inventory For Cycles 1-6, Flux at 270° Is 20.45% >Average, For Cycle 8, 5.93%

50.00%

40.00% Cycles Ito 6

-Cyle 8 W

o3000%/@ SS

-I-OctantAvg Y Flux 2

20.00%

< 10.00% Mle E

0 C

-10.00%

-20.000/ - -

Aj,,Azimuthal Angle (Degrees) for Octant from 260' to 3050 7

-30.00%/

250 260 270 280 290 300 310 1-22

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Figure 7. Octant Flux Profile For Cycles 1-6, Rux at 2700 Is 17.4% < Max at 2600. For Cycle 8,18.40/

1.90E40-1

.-. 1.7E8E10+1O *- K.

iCycleS 1to 6 E150 10 E Cycle8 E 1 30E+101-7E+1O'; -

e 1.10E+10

, ;' '-"!-:.Az 5mut al <Anl (erees) fo r Ocan fro 26 tf 2>o ,4 7.OOE+09 ~7 - ,,7_ ?xT i< ~,-,iyi c¢,=

A_

EiEt 250 260 270 280 290 300 310 5.3 Calculation of Remaining Activated Concrete Inventory

a. To determine the activity in the remaining activated concrete inventory, the associated concrete volumes in the ICI sump area, below the -4' elevation, were modeled by a number of right-circular cylindrical shells. The associated core activities were assigned to each volume. The variance of activity by depth was applied as appropriate to the shell volumes and a total integrated (gamma) activity for each shell volume was computed. The sum of all shell volumes then provided a determination of the total gamma activity in the remaining volume. The results of this determination (for each shell volume and the total gamma activity) are provided in Table 4.

b. To support the dose assessment, this inventory of the remaining concrete was scaled up, based on the activated concrete nuclide fraction, to account for H-3 and other HTD nuclides. (Liner activity was also estimated. This determination is discussed later.) As discussed above, the cores applied to each volume are considered appropriate and conservative for this application. Thus, this determination is considered to over-predict the actual activity inventory in the remaining activated concrete. The basis for this conclusion is discussed below.

1-23

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Table 4 Determination of Activated Concrete Inventorv: Summarv Results Cylindrical Elevation Range Core Core Shell Shell Activity Total % of Shell Comments Shell (Ft) Applied Elev. Height Volume Profile (Ganmma) Activity to Shell (Ft) (Ft) (cm3) Activity in to Total Shell Concrete (pCi) Inventory

_ _ _ _ _ _ __ __ ___ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _N o t e _1 A -15.14 to -4 Cores -1' 11.14' 5.09 E+07 3.3 3.69 E+08 10.6% Note 2 5-1,5 .. .

B -29 to -15.14 12-8 -22' 13.86' 6.33 E+07 Illustrated in 2.55 E+09 73.0%

Figure 3 C -32.17 to -29 12-7 -29' 3.17' 1.45 E+07 Illustrated in 3.42 E+08 9.8%

Figure 4 D -34.17 to -32.17 NA NA 2.00' 9.13 E+06 NA NA NA Note 3 E -37.17 to -34.17 12-7 -29' 3.00' 1.01 E+07 Illustrated in 2.34 E+08 6.7%

Figure 4 Total Gamma Activity Inventory in Remaining Activated Concrete (pCi) 3.50 E+09 100%

Notes:

1. Activity listed is for gamma emitters only. The dose assessment is based on a total activity for allnuclides which is developed from the total inventory listed here, adjusted for HTD nuclides.

2. Reported activities from Core 12-8 were all less than 3.2 pCi/g (with the exception of one artifact, considered to be non-reliable due to possible cross-contamination during sample handling). The entire volume of this shell was assigned a conservative specific activity of 3.3pCi/g for the inventory calculation.

3. The ICI sump lower elevation includes a concrete step from -34' to -32' (Figures 2 and 3). At this location the concrete was poured on top of the containment liner (which is attached to the horizontal surface at -34' and on the sump walls from -34' to -32'). The portion of concrete behind the liner (Shell D) is effectively shielded by the concrete step such that no activation activity was assigned to the Shell D.

I-24

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216

c. As described earlier (and illustrated in Figure 2), the ICI sump area and related structures form a right-circular cylinder around the reactor pressure vessel. Based on the geometry of the structures and the core locations, the remaining concrete ICI sump wall volumes were divided into five right-circular cylindrical shells, illustrated in Figure 8. For this discussion, the shells were labeled A through E, from higher elevations to lower.

d. For simplicity, a single activity concentration was conservatively established and applied to all of Shell A. A set of sequential cores in the same location (Cores 5-1,5) was used for to establish the activity in Shell A. The core activity was applied to a concrete depth, behind the liner, of 24." This 24" depth is considered a conservative limit for dose significant activation, based on numerous profiles which consistently indicate a rapid drop-off of activity 1-25

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 after several inches into the concrete. (See LTP Figure 2-10 and related discussion in Maine Yankee's response to RAI 14 (Reference 12.3.) The cores were taken at elevation -1' through the neutron shield tank and into the primary shield. This core is being used to characterize concrete that is at a lower and generally shielded volume. Therefore, this approach is expected to over-predict the activity for the wall concrete in elevations -15' to -4'. All activities reported for Cores 5-1,5 were < 3.2 pCi/g (except for one discounted artifact). A concentration of 3.3 pCi/g was assumed for the entire Shell A volume. Based on the location of Cores 5-1,5 and the use of 3.3 pCi/g for the entire volume, the resulting activity of Shell A is considered conservative.

This shell resulted in a small fraction of the total remaining activated concrete inventory (i.e., about 11 %).

e. The Shell B volume spanned elevation -29' to -15.14'. Like Shell A and for the same reasons, the concrete depth was assumed to be 24". The 24" depth was divided into 48 one-half-inch intervals. Thus, the shell volume was divided into 48 one-half-inch thick right-circular cylinders of concrete wall material. For each half-inch shell, the appropriate activity for that depth was applied from Core 12-8. The sum of all 48 shells produced a total Shell B activity of 2.55 E+09 pCi which accounts for the largest portion of the remaining activated concrete activity inventory (approx. 73%). See Table 4.

Core 12-8 was taken at the -22' elevation. While this core is considered appropriate for characterizing this shell's elevation range, it is recognized that it's use may over-predict activity concentrations for elevations below -22' and under-predict activity concentrations between -22' and -15'. For this reason, an additional core is planned to confirm the conservatism of this overall inventory assessment. (The additional characterization is discussed below.)

The Shell C (-29' to -32') activity inventory was determined in a similar fashion using Core 12-7 to produce an activity of 3.42 E+09 pCi.

f. No activity was assigned to Shell D (-34' to -32') since it was considered to be effectively shielded by concrete poured on top of the liner from -34' to -

32'. See Figure 3. The total activity for Shell E was computed in the same manner as for Shells B and C. The core at -29' was used to characterize the activity profile for Shell E. The results for all ICI wall shells are summarized in Table 4. .

g. As discussed in Section 4.1, an access tunnel is provided on one side of the ICI sump (Figure 3). The steel liner covers the surfaces of the tunnel. For conservatism and simplicity, the tunnel access doorway was assumed walled and covered with the liner as if the sump were a complete right cylinder. This is considered conservative since it provides concrete (and liner material) closer to the reactor core, thus over-predicting the extent of activation for the tunnel access area.

1-26

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 5.4 Calculation of Activated Liner Inventory

a. Exposed portions of the containment liner attached to the walls of the ICI sump were also subjected to neutron activation. Liner activity was estimated (as discussed below) and considered in the total activity inventory estimate (and related dose impact). As discussed in the dose assessment, however, the liner's release mechanism for activation products is primarily governed by corrosion processes (rather than diffusion) and was evaluated to have a negligible contribution to dose. See Section 6.2.

b. The carbon steel liner8 activity inventory was estimated based on liner volume and concrete activity immediately adjacent to the liner (at various elevations). For each elevation segment of the ICI sump walls (as defined in Table 4 and illustrated in Figure 6), there is an associated portion of the containment liner. Each vertical portion of the liner is a 3/8" thick, right circular cylindrical steel shell. The liner volume for each exposed liner shell was determined. Rebar characterization information was used, in concert with ICI concrete wall core results, to provide an estimate of liner activity for a given liner shell. (See below for discussion of the correlation of rebar activity to liner activity.) Using an appropriate volume, density, and activity concentration, the activity inventory for each liner shell was determined.

Based on this method, the total remaining liner activity (gamma and HTD nuclides) was estimated to be 2.60E +10 pCi (decay corrected to 2004). See Table 5 notes for additional discussion.

c. Not all liner portions in the sump were included in the inventory estimate due to shielding considerations from the NST (Liner Shell A) or structural concrete (Liner Shell D). See Table 5 for details.

d. Activated liner activity was estimated based on correlating activated rebar to concrete ratios from earlier site characterization work. One of the cores in the ICI sump floor (see LTP Section 2.5.2f) contained a segment ofrebar steel.

From the HTD and other characterization analysis work, a correlation was made relating total rebar activity to activity in the immediately adjacent sump floor concrete. In that the same neutron activation process applied to concrete adjacent to the steel liner, total liner activity was estimated based on this rebar-to-floor-concrete correlation and then related to the specific activity measurements from concrete cores taken from the ICI sump walls, adjacent to the liner. 9 As noted above, to compute liner volume and activity, the liner was divided into several portions or shells, identical to those defined in the ICI 8 See Section 4.1.2 for physical description details.

9 Activity concentrations in the first 0.5" layer of concrete in the ICI sump walls was used to make this estimate of liner activity. See Table 3 for specific activities for the subject cores (at -22' and -29').

1-27

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 sump walls (Table 5 and Figure 6). The same core used to estimate concrete activity for a given wall shell was also used to compute the liner activity, using the rebar to floor concrete activity correlation discussed above. The core used for estimating the activity in each liner shell is listed in Table 5.

1-28

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Table 5 Determination of Containment Liner Activity Inventory: Summary Results (Decay Corrected to 2004)

Liner Shell Elevation Range Core Applied Core Shell Shell Total % of Shell Comments (See Figure 6) (Ft) to Shell Elev. Height Volume Activity in Activity (Ft) (Ft) (cm3) Shell to Total (pCi) Concrete Note 1 Inventory A -15.14 to -4 Not NA NA NA NA NA Shielded by NST Applicable (Note 2)

(NA)

B -29 to -15.14 12-8 -22' 13.86' 9.31 E+05 1.94 E+10 74.7%

C -32.17 to -29 12-7 -29' 3.17' 2.13 E+05 3.91 E+09 15.1% _

D -34.17 to -32.17 NA NA NA NA NA NA Shielded by concrete step, -34' to -32' (Note 3)

E -37.17 to -34.17 12-7 -29?? 3.00' 1.45 E+05 2.67 E+09 10.3%

Total Activity Estimated in the Remaining Containment Liner(pCi) 2.60 E+10 100%

Notes:

1. Reflects total nuclide activity (including HTD nuclides).

2. No significant activation is expected due to shielding from the NST.

3. The ICI sump lower elevation includes a concrete step from -34' to -32' (Figures 2 and 3). At this location the liner is attached to the horizontal surface at -

34' and on the sump walls from -34' to -32'. This portion of the liner from -34' to -32' (and the horizontal or floor portion at -34') is effectively shielded by the concrete poured on top of the liner, such that no activation activity was assigned to this portion of the liner.

4. There is also a horizontal or floor portion of the liner at the -39' elevation at the bottom of the ICI sump. This liner portion (1/4" thick) was not included in the activity inventory assessment since it is effectively shielded by the 2 foot thick concrete floor poured on top of the liner from -39' to -37'.

I-29

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 5.5 Additional Characterization Data to be Collected

a. The principal nuclide contributing to activated concrete diffusion and dose is the HTD nuclide, H-3. During the development of the diffusion modeling approach a question arose as to whether any significant H-3 diffusion has already occurred relative to the other nuclides, which have a much lower diffusion coefficient. If such diffusion occurred, it could change the assumed depth profile that was developed using gamma emitters. It was not expected that any significant diffusion had occurred since the concrete behind the liner was not expected to be saturated due to the containment foundation drain pump operation. This expectation was supported by the fact that the sump wall core samples from behind the liner were dry. Notwithstanding that this was viewed as a minor issue that would likely have a small affect on diffusion and dose, additional H-3 lab analyses were performed on selected portions of the three ICI sump wall cores to provide additional qualitative information.

Three slices from the first few inches of each core obtained from the -29', -22' and +15' elevations were submitted and analyzed for H-3. The lab results for three slices (from each core) provided the general shape of the expected H-3 profile for that location. An assessment of these profiles concluded that substantial migration due to diffusion since plant shutdown was unlikely.

Thus, the assumed depth activity profiles used in the diffusion analysis were appropriate for that use.

b. The above describes the method and results for determining the activity inventory for the remaining activated concrete and liner material. The methods are considered realistic and conservative for the reasons provided.

As mentioned above, there are areas where additional characterization work is prudent to confirm assumptions made in this determination of inventory.

One additional core sample will be obtained at an appropriate location below the NST bottom where the ICI sump wall would likely see little or no shielding from the NST (in the general area of elevation -15', to be determined later by Maine Yankee). This additional core will be obtained at such time when the decommissioning project schedule permits, considering personnel safety, access, and impact to schedule.

I-30

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 6.0 DOSE MODELING Maine Yankee is proposing a revision to the activated concrete dose model presented in the LTP to include a more realistic estimate of the radionuclide release rate from activated concrete into the containment basement. During the evaluation of the activated concrete dose model, Maine Yankee decided to also change the SA/V ratio used in the containment basement fill model to use the actual containment SA/V ratio in the calculations, as opposed to the conservative application of the Spray Building SANV ratio.

The affect of using the containment surface area to volume (SA/V) ratio in the calculation of containment basement fill dose is described below, along with the other changes.

In addition to the dose model revisions, the DCGL for deep soil and surface soil have been reduced to provide an additional margin of safety to ensure, with a high level of confidence, that the revised activated concrete remediation strategy will not result in a dose that exceeds the unrestricted use criteria. The dose from this reduced soil DCGL is calculated.

As discussed later in this section, the change to the SANV ratio and the reduction in the deep and surface soil DCGL is not being proposed as part of this license amendment request. These changes are provided here as a matter of completeness and will be evaluated and implemented by appropriate processes governing changes to the LTP under 10 CFR 50.59, the Maine Yankee Operating License Condition 2.B.(l0), and LTP Section 1.4.1, following the NRC review and approval of the changes to the activated concrete model and DCGL 6.1 Revision to Activated Concrete Dose Model The conceptual dose model for activated concrete described in Section 6.6.2(a) of the LTP was a very conservative screening model that assumed the instantaneous release of 100% of the activated concrete inventory. The physical meaning of this assumption is that the radionuclides in the activated concrete and rebar matrices would instantaneously dissolve into the water contained in the concrete pore space and then immediately diffuse through several inches of concrete into the water that is assumed to fill the containment basement.

The LTP states that a more realistic model would account for the fact that the activated concrete inventory would be released slowly over time. The revised activated concrete dose model includes more realistic estimates of the radionuclide release rates by calculating diffusion rates through the concrete pore space water. The conservative assumption of instantaneous dissolution of the radionuclides in the concrete and rebar matrices is still applied. Once released, the revised source term was entered into the basement fill dose assessment model, as was done in the LTP.

1-31

ATTACHMENT I DESCRIPTION AND EVALUATION OV CHANGES PROPOSED CHANGE NO. 216 The original remediation plans for the activated concrete included the removal of the steel liner to access and remediate the activated concrete and rebar. As discussed above, the new remediation plans call for leaving the steel liner in place below -4 ft elevation. The revised dose model accounts for the presence of the steel liner and how the liner would inhibit the release of radionuclides into the containment basement. The revised model estimates the release rate with the liner in place (essentially zero) as well as the rate at which the liner may corrode or pit leading to liner breach. After the liner is breached, the diffusion-based release rate of the radionuclides is estimated.

Detailed calculations of the release rates as a function of time, considering both diffusion through the concrete and the effect of the steel liner, were developed by Brookhaven National Laboratory (BML) using the DUST-MS code. The conclusions of the BNL report (Attachment III) as they pertain to the calculation of a revised activated concrete source term are listed below. The releases are expressed as the maximum cumulative fractional release of the entire inventory over a 1000 yr period.

The cumulative fractional release is the total mass released from the activated concrete expressed as a fraction of the initial inventory. The cumulative fractional release accounts for decay within the activated concrete as diffusion is occurring but does not account for decay after the radionuclide is released to containment. The BNL report includes these additional decay calculations and reports them as the "maximum fractional amount in solution." For example, Table 6 of the BNL report lists the cumulative fraction release for H-3 as 0.0 16, assuming liner failure time of 50 years and a diffusion coefficient of 5.5E-08 cm2 /s. The same table lists the maximum fractional amount in solution as 0.009 cm 2 /s. To ensure conservative results, and direct linkage with the DUST-MS results, the cumulative fraction is used in the revised dose calculations described below.

The DUST-MS model analyses were performed for H-3 and C-14. The results for H-3 are conservatively applied to Fe-55, Co-60, Cs-134, Eu-154, because these nuclides have a shorter half-life than H-3 and diffusion coefficient in cement is expected to be lower than for H-3. The H-3 results are conservatively applied to Eu- 152 because the half-life of Eu- 152 (13.4 yr) is only slightly higher than H-3 (12.3 yr) but the Kd for Eu-152 is much higher than H-3 (400 vs. 0) which will lead to a lower diffusion coefficient and lower dose in the basement fill model. In addition, the dose from Eu-152 is a very small fraction of the H-3 dose, i.e., less than 0.3%. Separate diffusion analyses were made for C-14 because of a significantly greater half-life (5730 yr) and relatively low Kd (5.0).

In all cases, the cumulative fractional release of Ni-63 was assumed to be 1.0 for ease of calculation (note that radioactive decay was accounted for in the dose calculation for the 50 yr liner breach). If this assumption were not made, a I-32

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 separate diffusion analysis would have been needed for Ni-63 due to its long half-life relative to H-3 (100 yr vs. 12.3 yr). The effort to perform these analyses was not considered warranted due to the very low dose from Ni-63.

a. Brookhaven Report Conclusions

1. Assuming the liner remains intact for 1000 years the cumulative fractional release of H-3, Fe-55, Co-60, Cs-134, Eu-152, and Eu-154 through the 7 foot thick containment concrete wall into the groundwater outside of containment was 9.OE-04. The cumulative fractional release of C-14 was 2.4E-05. These values are artificially high as a result of using the unrealistic assumption that the total activity profile never decreases below 1 pCi/g throughout the seven feet of concrete.

2. It is unlikely that corrosion or pitting will result in breaching of the steel liner within 50 years. The average times for breaching due to corrosion and pitting were estimated to be 168 years and 200 years, respectively.

3. Assuming a 50 year time period before the liner is breached, the cumulative fractional release of H-3, Fe-55, Co-60, Cs-134, Eu-152, and Eu-154 into the containment basement was 1.6E-02. The cumulative fractional release of C- 14 was 6.OE-02. These results were based on diffusion coefficients of 5.5E-08 cm 2 /s and L.OE-12 Cm2 /s for H-3 and C-14, respectively.

From the above diffusion results, it is seen that the maximum source term for the revised activated concrete conceptual model would occur under the condition of liner failure. Using the results from the 50 year liner breach calculations, and the revised activated inventory calculations from Section 5.0, the source term inputs for the revised activated concrete dose assessment are calculated below.

b. Diffusion-Based Activated Concrete Dose Assessment Source Term Assumptions

Total Activated Concrete Inventory is 2.08E+l0 pCi at year 2004.

The total activity inventory is obtained by dividing the total gamma emitter activity inventory of 3.50 E+09 (Table 4) by the fraction of activated concrete nuclides that emit gamma radiation (gamma fraction), 0.168.

The cumulative fractional release value for H-3 was 1.6%. This fraction applies to H-3, Fe-55, Co-60, Cs-134, Eu-152, and Eu-154.

The sum total inventory of these radionuclides is equal to 2.08E+10 I-33

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 pCi minus the activity associated with C-14 (NF of 5.8%) and Ni-63 (NF of 0.7%). This is a conservative approach to calculating the release fraction for Fe-55, Co-60, Cs-134, Eu-152, and Eu-154 because the actual cumulative fractional release of these nuclides would be less than H-3 due to H-3's longer half-life and/or higher diffusion coefficient.

The cumulative fractional release value of 6% applies to the C-14 activity

The Ni-63 source term is 100% of the Ni-63 activity present 50 years after license termination.

Source Term Calculations

1. H-3 + Fe-55 + Co-60 + Cs-134 + Eu-152 + Eu-154

= 2.08E+l0 pCi * (1-0.065)

0.016

= 3.11 E+08 pCi

2. C-14 = 2.08E+10 pCi

0.058

0.06 = 7.24E+07 pCi.

693 *50/100 = 1.03E+08 pCi.

3. Ni-63 = 2.08E+10 pCi

0.007

e

4. Total Source Term = 4.86E+08 pCi

c. Revised Activated Concrete Dose Assessment The dose assessment model described in the LTP Revision 3 was used for the revised dose assessment. To use the model, the total inventory and nuclide fractions are required. To determine the diffusion-based nuclide fractions, the diffusion-based radionuclide specific inventories must first be calculated as shown below. The values in parenthesis are the nuclide fractions from LTP Revision 3 Table 2.19 (see Table 1 above). The C-14 and N-63 inventories were calculated directly above. The inventories for H-3, Fe-55, Co-60, Cs-134, Eu-152, and Eu- 154 were determined by dividing the nuclide specific fraction by the total fraction after excluding C-14 and Ni-63, i.e., 0.935. The result was then multiplied by the total inventory attributed to the nuclides, i.e., 3.1 lE+08 pCi.

1-34

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Radionuclide-Specific Inventories H-3 = (3.11 E+08 pCi)(0.647/0.935) = 2.15E+08 pCi Fe-55 = (3.1 IE+08 pCi)(0.124/0.935) = 4.12E+07 pCi Co-60 = (3.1 1E+08 pCi)(0.040/0.935) = 1.33E+07 pCi Cs-134 = (3.1 1E+08 pCi)(0.0084/0.935) = 2.79E+06 pCi Eu-152 = (3.1 1E+08 pCi)(0.1 11/0.935) = 3.69E+07 pCi Eu-154 = (3.1 1E+08 pCi)(0.009/0.935) = 2.99E+06 pCi C-14 = 7.24E+07 pCi Ni-63 = 1.03E+08 pCi Table 6 - Diffusion-Based Nuclide Inventories and Fractions Nuclide Diffusion-Based Inventory Diffusion-Based Basement Fill (pCi) Radionuclide Fraction H-3 2.15E+08 0.441 C-14 7.24E+07 0.148 Fe-55 4.12E+07 0.0844 Ni-63 1.03E+08 0.211 Co-60 1.33E+07 0.0273 Cs-134 2.79E+06 0.00572 Eu-152 3.69E+07 0.0756 Eu-154 2.98E+06 0.00611 Total 4.88E+08 1.00 The total inventory and nuclide fractions from Table 6 were input to the dose calculation spreadsheet used in LTP Revision 3 after two modifications were made to the spreadsheet; 1) the SANV ratio was changed from 1.7 to 0.46 as discussed in Section 6.3 below, and 2) the I pCi/g DCGL value was removed since the revised model relies on inventory directly, without the intermediary step of calculating inventory from the 1 pCi/g assumption. Although the revised remediation plans call for the removal of all concrete inside the liner in the ICI sump, the concrete wall assumption was left in the basement fill dose assessment spreadsheet to maintain consistency with the mathematical formulations provided in the LTP Revision 3. The effect of the assumed concrete wall on dose is negligible since it's mass is less than 0.1% of the fill mass.

The expression of the source term in the revised dose model is in terms of available inventory after liner breach and diffusion. This does not fundamentally differ from the LTP dose calculation where the final source term input was also available inventory but in the LTP 100% of the total activated concrete inventory was assumed to be available for the dose model. The available inventory in the revised dose model is less than the total inventory because of diffusion and decay.

1-35

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 In the LTP, the total inventory was calculated assuming 1 pCi/g DCGL uniformly distributed over the volume of activated concrete projected to remain after remediation. In the revised dose model, the total inventory was calculated directly based on characterization results of the concrete projected to remain. The intermediary step of assigning the 1 pCi/g concentration value in the LTP did not affect the dose since the dose pathway is drinking water and 100% of the inventory was assumed to be released. The I pCi/g value was used as the basis for remediation planning. In the revised remediation strategy, other consideration such as ALARA and industrial safety were used to determine what activated concrete would remain and a dose assessment was performed to ensure that the dose from the remaining activated concrete was acceptable.

The revised activated concrete DCGL is 2.08E+ I0 pCi total inventory (decayed to 2004). The comparable DCGL in the LTP was a total inventory of 3.3E+08 pCi.

The revised activated concrete dose, including the revised inventory and revised dose model, is 0.047 mremlyr (Attachment IV) compared with 0.041 mrem/yr in the LTP.

6.2 Activated Steel Liner The revised conceptual model for the ICI sump includes the presence of the steel liner, which was assumed to be removed in LTP Revision 3. Therefore a simple conceptual model was developed to ensure that the dose from the liner was not significant. The conceptual model assumed that the liner would corrode at a constant rate over the assumed 50 year period, i.e., 2% per year. As stated above, this corrosion rate is conservative. The radionuclide mixture of the steel liner is assumed to be the same as rebar. The total liner inventory at the time of license termination (2004) is 2.60E+l0 pCi as shown in Table 5 Assuming a fractional release rate of 2% per year, the maximum fraction amount in solution is 3.9% of the initial 2.60E+l0 pCi inventory and occurs in year 2007 (Attachment V). The corresponding maximum dose from liner corrosion is 6.7E-03 mrem/yr (Attachment V). The dose from liner corrosion prior to the 50 year liner breach is not additive with the post-breach activated concrete dose and since it is less than the maximum post 50-year activated concrete dose of 0.047 mrem/yr it can be ignored. However, the inventory available from liner corrosion at year 50 post-license termination would be additive. The inventory in solution from liner corrosion at 50 years is 1.15E+08, with a corresponding dose of 1.8E-04 mrem/yr. This dose is negligible and will not be considered in the total dose summation.

6.3 Revision to Containment SAIV Ratio LTP Rev 3, Section 6.6.1(b), Page 6-10 states that "Ifnecessary, as the project proceeds, Maine Yankee may use building-specificsurface area to volume ratios 1-36

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 based on the datapresented in Section 6.6. 1(d)(2) to calculate building-specific DCGLs." Maine Yankee has determined that the use of a building-specific SAN ratio for containment is consistent with the more realistic modeling being performed for the activated concrete in containment. The SAN change will be implemented through the 10 CFR 50.59 process after NRC approval of the activated concrete model and DCGL revisions.

Section 6.6.1 (d)(2) lists a SAN ratio of 0.46 for containment. The use of the building-specific SAN ratio of 0.46, as opposed to the conservative spray building value of 1.7, predominantly results in a reduction of dose from contaminated concrete. The basement fill dose model is also used for BOP embedded piping, embedded spray piping, contaminated concrete special areas, and activated concrete. Activated concrete is addressed in Section 6.1 and is not discussed further in this section.

As described above, the remediation plans for the containment basement have changed from that envisioned in the LTP in that additional interior containment concrete walls are going to be removed. This will result in the actual post-remediation SAN being reduced to 0.31 with a corresponding 33% reduction in dose as compared to that calculated using 0.46. However, Maine Yankee has elected to use the approved LTP SA/V ratio of 0.46 to facilitate NRC staff review and approval of this amendment request.

Attachment VI contains the dose calculation spreadsheets using the 0.46 SAN ratio. These spreadsheets are the same as those used in Attachment 6-13 of LTP Revision 3 except the SA/V ratio is changed from 1.7 to 0.46. The dose using 0.46 and 1.7 is listed in Table 7. The total dose reduction is 0.22 mrem/yr when the building-specific value of 0.46 is used. Note that the Contaminated Concrete Special Area dose was calculated in the LTP to show that the special area dose was less than contaminated concrete and was not included in the dose summation table. The calculation with the new SAN ratio is included here for completeness.

Table 7 - Dose From Contaminated Concrete and BOP Embedded Piping With SANV Ratios of 1.7 and OA6.

Contaminated Material SA/V Ratio of 1.7 SANV Ratio of 0.46 (mrem/yr) (mrem/yr)

Contaminated Concrete 0.30 0.082 BOP Embedded Piping 0.051 0.051 Embedded Spray Piping 0.085 0.085 Contaminated Concrete 0.11 0.029 SpecialA rea _ _ _ _ _ _ _ _ I___ _ _ _ _ _ _ _ _

I-37

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 6A Decrease in Soil DCGL The dose calculations show (Attachment IV) that the dose from the increased inventory due to the revised activated concrete remediation plans is only about 0.0060 mrem/yr higher than the activated concrete dose reported in the LTP (Table 6-11). When the containment-specific SANV ratio is included, the total dose from all pathways would be 0.21 mrem/yr lower than the dose reported in the LTP.

Notwithstanding the fact that dose assessment shows that the dose is below the unrestricted use criteria, Maine Yankee plans to lower the surface and deep soil DCGL to provide additional confidence that the revised remediation strategy can be implemented safely. This is not required by regulation or LTP commitments; however, Maine Yankee believes these actions and their composite impacts present a reasonable approach to addressing both regulation and other stakeholder interests. The soil DCGL change will be implemented through the 10 CFR 50.59 process after NRC approval of the activated concrete model and DCGL revisions.

The deep and surface soil DCGLs will be reduced by an amount that ensures that the total dose from all pathways (using the containment SA/V ratio) is less than 10 mrne/yr when the revised remediation strategy is implemented under a worse-case assumption that 100% of the 2004 inventory is instantaneously released to containment, i.e., taking no credit for diffusion or the liner integrity. Attachment VII shows that the dose from the liner and activated concrete would be 2.73 mrem/yr under the worst-case conditions. Considering the 0.22 mrem/yr decrease in contaminated concrete dose due to the containment SANV ratio and including the 0.24 mrem/yr margin available from the LTP Table 6-11 dose assessment, the total dose reduction required from a lowered soil DCGL would be 2.73 - 0.22 -

0.24 mrem/yr, which equals 2.27 mrem/yr.

Attachment VIII shows that reducing the deep and surface soil DCGL to 2.39 pCi/g would reduce the soil dose to 6.77 mren/yr. The LTP soil dose was 9.04 mrem/yr making the difference between the LTP dose and revised dose equal to 2.27 mrem/yr, which equals the 2.27 mrem/yr reduction goal.

6.5 Revised Dose Summation Tables Table 6-11 from the LTP provided a summation of the doses from all contaminated materials. Because of the revisions to the dose models and the reduction in the deep and surface soil DCGLs, new tables were required. In addition, the application of a building-specific SA/V ratio for containment required a separate summation tables for containment. The summation table for all building basements except containment does not include the activated concrete dose. Activated concrete inventory is limited to containment only and no longer 1-38

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 considered as a source for the other building basements due to diffusion results showing essentially zero release from behind the liner to surrounding groundwater. The dose summation tables are shown in Attachment IX. The total dose for the containment building is 7.27 mrem/yr and the total dose from the non-containment buildings is 7.44 mrem/yr 7.0 FINAL STATUS SURVEY 7.1 Proposed FSS for Activated Concrete As stated in Section 5.5.l.a of Revision 3 of the LTP, activated concrete was planned to be "measured volumetrically ...by coring or other means".

The activated concrete has been well characterized as described in Section 2 of the LTP. The nuclide fractions of the samples taken were generally consistent with each other and with reported values (NUREG/CR-3474). The data to be used to support the final status survey of activated material were obtained from the three ICI sump wall cores already obtained and analyzed. This data will be supplemented by one additional core to be obtained later. The core samples already collected are those from the sump walls at the -29', -22, and -1' elevations.

The additional core, as discussed in Section 5.5, will be obtained from the sump wall in the area of the -15' elevation. This additional core is to confirm the conservatism of the overall inventory estimate, used for the dose assessment.

Maine Yankee considers no further measurements for FSS are required for activated concrete since the dose model is inventory-based and current calculations are considered to be realistic but conservative. There is no change proposed for the measurement of activated concrete.

In the LTP, the size of a survey unit is based upon the dose model surface area, which is related to the SANV ratio multiplied by the model volume. Since the SA/V for the containment building has been revised to be building specific, the maximum survey unit size in containment will be reduced from 2000 m2 to 1130 m2 (2460 m3 x 0.46 m2/m 3).

7.2 Impact of Reduced Soil DCGL Direct measurements of soil activity for FSS will be made by taking volumetric soil samples and using gamma spectroscopy for nuclide analysis. The MDC of the gamma spectroscopy is more than adequate to detect activity at the revised soil DCGL level of 2.39 pCi/g, as described in Section 6.4.

a. Scan MDC The scan MDC for soils was increased from the 3.2 pCi/g (Cs-137 equivalent) as reported in Revision 3 of the LTP to a value of 5.9 pCi/g based on discussions between MY and the NRC and stakeholders. This 1-39

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 Scan MDC is adequate to detect soil activity at the DCGLEMC which is the required detection sensitivity. The lower DCGL may result in slightly more soil samples being needed to meet NUREG-1575 requirements.

b. Relative Shift The relative shift is the width of the gray region (DCGL - LBGR) divided by the soil sample standard deviation. By lowering the DCGL, the width of the gray region may be somewhat reduced. This may result in lower values of relative shift which will require a few additional soil samples.

c. Area Classification The change in soil DCGL will have no impact on survey area classification.

Soils are generally well below the DCGL value or well above it and minor changes in DCGL have no impact on classification. However, each area will be evaluated during survey design to ensure it has been properly classified considering the revised DCGL.

d. Instrumentation As stated above, the gamma spectroscopy system is more than sensitive enough to deal with a lower soil DCGL. The Scan MDC has been discussed in (a) above.

8.0 OTHER CONSIDERATIONS 8.1 ALARA The ALARA evaluation, in LTP Section 4.2.1, addressed those remediation activities necessary to support a DCGL of 1.0 pCi/g for activated concrete (which is present only in the containment structure). That evaluation concluded that since the annual dose to the critical group associated with residual (remaining) activated concrete was less estimated to be < 0.1 mrem/yr, ALARA evaluations were not deemed necessary.

The revised remediation plan and related dose assessment for contributions from activated concrete and containment liner concluded that the dose to the critical group remains < 0.1 mrem/yr. Therefore, no additional ALARA evaluations are considered necessary.

8.2 LLRW Disposal Impacts With regard to environmental considerations from the revised activated material remediation strategy, the overall impact is negligible and the volume of waste generated remains consistent with the conclusions of the Final Generic Environmental Impact Statement for Decommissioning (FGEIS) (Reference 11.4). These changes will be 1-40

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 implemented through the 10 CFR 50.59 process after NRC approval of the activated concrete model and DCGL revision LTP Table 3-9 provides early, preliminary estimates related to the projected activity and volume of activated concrete as 390 Ci and 23,000 ft3 . More recent and refined activated concrete characterization efforts have determined that the total activity of activated concrete is less than a curie. Therefore the amount disposed will also be less than a curie.

The volume of activated concrete to be removed will also be less than the estimated value.

LTP Table 3-8 lists the projected volume of contaminated concrete low level radioactive waste (LLRW) as 900,000 ft3 . Under the proposed revised strategy, the volume of contaminated concrete to be removed from containment will increase. The increased volume of low level contaminated concrete is estimated to be approximately 60,000 ft3 .

bringing the total to approximately 960,000 ft.

LTP Revision 3, Section 8.7, discusses the impact of Maine Yankee's LLRW disposal and concluded that, from a dose and disposal space commitment, the projected LLRW volume has impacts less than the reference plant in the FGEIS. Overall, given the relatively small increase in LLRW disposal volume associated with the proposed revised activated material remediation strategy, the impacts to dose and space requirements are negligible. Therefore, the impacts related to the revised remediation strategy do not change the overall conclusion of the LTP, namely, that the impacts remain consistent with the conclusions of the FGEIS.

Further environmental analysis in accordance with 10 CFR 51.22(c)(9) - categorical exclusion from the requirements to perform an environmental assessment - is provided in Section 10.0 below.

.9 REGULATORY SAFETY ANALYSIS 9.1 No Significant Hazards Consideration Maine Yankee has evaluated whether or not a significant hazards consideration is involved with the proposed amendment(s) by focusing on the three standards set forth in 10 CFR 50.92, "Issuance of amendment," as discussed below:

1. Does the proposed amendment involve a significant increase in the probability or consequences of an accident previously evaluated?

Response: No.

The requested license amendment does not authorize any plant activities beyond those allowed by 10 CFR Chapter I or beyond those considered in the DSAR.

I-41

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 The bounding accident described in the Defueled Safety Analysis Report (DSAR) for potential airborne activity is the postulated resin cask drop accident in the Low Level Radioactive Waste Storage Building. This accident is expected to contain more potential airborne activity than can be released from other decommissioning events. The radionuclide distribution assumed for the spent resin cask has a greater inventory of transuranics radionuclides (the major dose contributor) than the distribution of plant derived radionuclides in the components involved in other decommissioning accidents. The other accidents considered in the DSAR include: 1) Explosion of Liquid Petroleum Gas (LPG) Leaked from a Front End Loader or Forklift; 2) Explosion of Oxyacetylene During Segmenting of the Reactor Vessel Shell; 3) Release of Radioactivity from the RCS Decontamination Ion Exchange Resins; 4) Gross Leak During In-Situ Decontamination; 5)

Segmentation of RCS Piping with Unremoved Contamination; 6) Fire Involving Contaminated Clothing or Combustible Waste; 7) Loss of Local Airborne Contamination Control During Blasting or Jackhammer Operations; 8) Temporary Loss of Services, 9) Dropping of Contaminated Concrete Rubble; 10) Natural Phenomena; and I1) Transportation Accidents. The probabilities and consequences for these accidents are estimated in the basis documentation for DSAR Section 7. No systems, structures, or components that could initiate or be required to mitigate the consequences of an accident are affected by the proposed change in any way not previously evaluated in the DSAR. Since Maine Yankee does not exceed the salient parameters associated with the plant referenced in the basis documentation in any material respects, it is concluded that these probabilities and consequences are not increased. Therefore, the proposed change to the Maine Yankee License does not involve any increase in the probability or consequences of any accident previously evaluated.

2. Does the proposed amendment create the possibility of a new or different kind of accident from any accident previously evaluated?

Response: No.

The requested license amendment does not authorize any plant activities that could precipitate or result in any accidents beyond those considered in the DSAR.

The accidents previously evaluated in the DSAR are described above. These accidents are described in the basis documentation for DSAR Section 7. The proposed change does not affect plant systems, structures, or components in any way not previously evaluated in the DSAR. Since Maine Yankee does not exceed the salient parameters associated with the plant referenced in the basis documentation in any material respects, it is concluded that these accidents appropriately bound the kinds of accidents possible during decommissioning.

Therefore, the proposed change to the Maine Yankee License would not create the possibility of a new or different kind of accident from any accident previously evaluated.

I-42

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216

3. Does the proposed amendment involve a significant reduction in a margin of safety?

Response: No.

The margin of safety defined in Maine Yankee's license basis for the consequences of decommissioning accidents has been established as the margin between the bounding decommissioning accident and the dose limits associated with the need for emergency plan offsite protection, namely the Environmental Protection Agency Protective Action Guidelines EPA-PAGs. As described above, the bounding decommissioning accident is the postulated resin cask drop accident in the Low Level Radioactive Waste Storage Building. Since the bounding decommissioning accident is expected to contain more potential airborne activity than can be released from other decommissioning events and since the radionuclide distribution assumed for the spent resin cask has more transuranics (the major dose contributor) than the distribution in the components involved in other decommissioning accidents, the margin of safety associated with the consequences of decommissioning accidents cannot be reduced. The margin of safety defined in the statements of consideration for the final rule on the Radiological Criteria for License Termination is described as the margin between the 100 mrem/yr public dose limit established in 10 CFR 20.1301 for licensed operation and the 25 mrem/yr dose limit to the average member of the critical group at a site considered acceptable for unrestricted use. This margin of safety accounts for the potential effect of multiple sources of radiation exposure to the critical group. Since the LTP was designed to comply with the radiological criteria for license termination for unrestricted use, the margin of safety cannot be reduced. Therefore, the proposed changes to the Maine Yankee License would not involve a significant reduction in any margin of safety.

Conclusion Based on the above, Maine Yankee concludes that the proposed amendment presents no significant hazards consideration under the standards set forth in 10 CFR 50.92(c), and, accordingly, a finding of"no significant hazards consideration" is justified.

9.2 Applicable Regulatory Requirements/Criteria The proposed revised remediation strategy for activated concrete and soil (surface and deep), as presented in this submittal, complies with the radiological criteria for license termination. The technical analysis and conclusions of this submittal describe the methods used for conducting a dose assessment to develop the DCGLs for demonstrating compliance with the unrestricted use criteria in Subpart E of 10 CFR 20 and the enhanced state clean-up standards established by State of Maine Public Law - LD 2688-SP 1084.

1-43

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216 10 CFR 20.1402, "Radiological Criteria for Unrestricted Use," allows termination/amendment of a license and release of a site for unrestricted use if the residual radioactivity that is distinguishable from background radiation results in a total effective dose equivalent to an average member of a critical group that does not exceed 25 mrem/yr and the residual radioactivity has been reduced to levels that are ALARA.

The enhanced state cleanup standards require that the residual radioactivity distinguishable from background radiation will result in a total effective dose equivalent to an average member of a critical group not more than 10 mrem/yr for all pathways and 4 mrem/yr for groundwater sources of drinking water. The revised remediation approach presented in this submittal demonstrates these criteria are met.

In conclusion, based on the considerations discussed above, (I) there is reasonable assurance that the health and safety of the public will not be endangered by operation in the proposed manner, (2) such activities will be conducted in compliance with the Commission's regulations, and (3) the issuance of the amendment will not be inimical to the common defense and security or to the health and safety of the public.

10.0 ENVIRONMENTAL CONSIDERATION

(10 CFR 51.22)

This amendment request meets the criteria specified in 10 CFR 51 .22(c)(9) for a categorical exclusion from the requirements to perform an environmental assessment or to prepare an environmental impact statement. The specific criteria of 10 CFR 51.22(c)(9) are discussed below:

1. The amendment involves no significant hazards consideration. As demonstrated above, this requested amendment involves no significant hazards considerations.

2. There is no significant change in the types or significant increase in the amounts of any effluents that may be released offsite. The environmental impacts associated with doses to members of the public as a result of decommissioning activities and site release for unrestricted use were considered in the Generic Environmental Impact Statement on Decommissioning of Nuclear Facilities (NUREG-0586) and the Generic Environmental Impact Statement in Support of the Rulemaking on Radiological Criteria for License Termination ("GEIS," NUREG-1496). In Maine Yankee's PSDAR, Maine Yankee concluded that the environmental impacts associated with the site-specific decommissioning activities will be bounded by appropriate previously issued environmental impact statements.

In particular, the decommissioning activities covered by the LTP will result in radiation doses to the public below a comparable level when the plant was operating. Radiation dose to the public will be minimal. The release of effluents will continue to be controlled by plant procedures throughout decommissioning. Maine Yankee will continue to operate in accordance with the Offsite Dose Calculation Manual (ODCM) during the decommissioning activities. In addition, because of the decay of short-lived radionuclides, the types of nuclides that could potentially be released in effluents have decreased.

1-44

ATTACHMENT I DESCRIPTION AND EVALUATION OF CHANGES PROPOSED CHANGE NO. 216

3. There is no significant increase in individual or cumulative occupational radiation worker exposure. The environmental impacts associated with individual or cumulative occupational radiation exposure were also considered in the Generic Environmental Impact Statements referred to above. It was similarly concluded that the GEIS appropriately bounded the environmental impacts associated with the Maine Yankee site-specific decommissioning activities. Radiation dose to decommissioning workers will be a small fraction of the operating experience. The total decommissioning dose including exposure from decontamination and dismantlement activities and the exposure during transportation of the low-level wastes is estimated to be less than the total dose that was found acceptable for decommissioning the reference PWR in the GEIS on decommissioning of nuclear facilities.

Radiation protection principles used during plant operation remain in effect during decommissioning to ensure that protective techniques, clothing, and breathing apparatus are used as appropriate.

On the basis of the preceding discussion, it has been concluded that the proposed amendment meets the eligibility criteria for categorical exclusion set forth in 10 CFR 51.22 (c)(9), and thus no environmental impact statement or environmental assessment need to be prepared in connection with issuance of this amendment.

11.0 REFERENCES

11.1 Maine Yankee Letter to the USNRC, MN-02-048, dated October 15, 2002, "Revision 3, Maine Yankee's License Termination Plan".

11.2 USNRC Letter to Maine Yankee, dated February 28, 2003, Issuance of Amendment No. 168 To Facility Operating License No. DPR-36 11.3 Maine Yankee Letter to the USNRC, MN-02-01 1, dated March 13, 2002, "Response to NRC Request(s) for Additional Information for Maine Yankee Atomic Power Station License Termination Plan" 11.4 United States Nuclear Regulatory Commission (NRC), NUREG-0586, Final Generic EnvironmentalImpact Statement on Decommissioningof Nuclear Facilities.(August 1988) 1-45

PROPOSED CHANGE NO. 216 ATTACHMENT II Proposed License Condition Changes, Pages 5 & 6 (mark-up)

Condition 2.B.(10)

PROPOSED CHANGE NO. 216 2.B.(7) This amended license is subject to the following conditions for protection of the environment:

(a) Deleted.

(b) Deleted.

2.B.(8) This amended license is effective as of the date of issuance and shall expire at midnight October 21, 2008.

2.B.(9) Lands Released from the Jurisdiction of Facility Operating License No. DPR-36 The lands described in the following correspondence have been released from the jurisdiction of Facility Operating License No. DPR-36. The NRC may require additional surveys and/or decontamination only if, based upon new information, it determines that the criteria of 10 CFR Part 20, Subpart E were not met and residual activity remaining at the site could result in a significant threat to public health and safety.

(a) MYAPC Letter to USNRC dated August 16, 2001 "Early Release of Backlands, Proposed Change No. 211 as supplemented and as approved in Amendment No. 167.

2.B.(10) License Termination (i) The Maine Yankee License Termination Plan describes an acceptable approach for demonstrating compliance with the radiological criteria for unrestricted use, as defined by 10 CFR 20.1402, by meeting a site release criteria of 10 millirem TEDE per year over background (all pathways) and 4 millirem (as distinguishable from background) TEDE per year for groundwater sources of drinking water using appropriate dose modeling methods, pathways and parameters and acceptable final radiation survey methods.

The licensee shall implement and maintain in effect all the provisions of the approved License Termination Plan, as submitted and approved in following documents:

Licensee Submittal SER Approval August 13, 2001, as supplemented on February 28, 2003 October 15, 2002 September 11, 2003 subject to and as amended under the following stipulations:

The licensee may make changes to the License Termination Plan without prior approval, provided the proposed changes do not:

II-I

PROPOSED CHANGE NO. 216 (a) Require Commission approval pursuant to 10 CFR 50.59; (b) Violate the requirements of 10 CFR 50.82(a)(6);

(c) Reduce the coverage requirements for scan measurements; (d) Increase the radioactivity level, relative to the applicable derived concentration guideline level, at which an investigation occurs; or (e) Increase the probability ( ) of making a Type I decision error.

The licensee shall submit an updated License Termination Plan in accordance with 10 CFR 50.71 (e).

(ii The licensee shall certify in its application for Part 50 license termination that it has met the radiological criteria for unrestricted use, as defined by 10 CFR 20.1402, by meeting a site release criteria of 10 millirem TEDE per year over background (all pathways) and 4 millirem (as distinguishable from background) TEDE per year for groundwater sources of drinking water in accordance with the approved License Termination Plan. The licensee shall at that time request NRC to confirm this certification.

II-2

PROPOSED CHANGE NO. 216 ATTACHMENT III BNL Report:

Assessment of Release Rates for Radionuclides in Activated Concrete

NATION7KL i~EN BROOKLABORATORY BNL-71537-2003 Assessment of Release Rates for Radionuclides in Activated Concrete T.M. Sullivan August 21, 2003 Brookhaven National Laboratory Upton, New York 11973-5000

BROOK"tiEN BNL-71537-2003 NATIONAL LABORATORY Assessment of Release Rates for Radionuclides in Activated Concrete T.M. Sullivan August 21, 2003 Environmental Research and Technology Division Environmental Sciences Department Brookhaven National Laboratory P.O. Box 5000 Upton, NY 11973-5000 www.bnl.gov Managedby Brookhaven Science Associates, LLC for the United States Departmn ent of Energy under Contract No. DE-AC02-98CH10886

This work was performed under the auspices of the U.S. Department of Energy

DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, nor any of their contractors, subcontractors or their employees, make any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or any third party's use or the results of such use of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof or its contractors or subcontractors. The views and opinions of author's expresses herein do not necessarily state to reflect those of the United States Government or any agency thereof.

Table of Contents Table of Contents ............................................ I Table of Figures ............................................ 2 Introduction......................................................................................................................................3 Objective:.........................................................................................................................................5 Approach..........................................................................................................................................5 Liner Performance ............................................ 6 Conceptual Model ............................................. 6 Soil Corrosion Data............................................. 7 Soil Corrosion Models and Results ............................................. 7 General Corrosion ............................................. 7 Pitting Corrosion ............................................. 8 Pitting Corrosion Modeling Results ............................................ 10 Selection of Container Lifetimes for Release Analysis .......................... .................. 13 Diffusion Controlled Release ............................................ 14 Key Radionuclides ............................................ 14 Experimental Diffusion Coefficients ............................................ 15 Predicted H-3 and C-14 Release Rates and Cumulative Release ............................................ 15 Instantaneous Liner Failure ............................................ 15 Tritium.................................................................................................................................. 15 Carbon-14 ............................................ 19 Liner Intact ............................................ 20 Effect of Liner Failure Time ............................................ 22 Tritium ............................................ 22 Carbon-14 ............................................ 25 Effect of Partial Failure ............................................ 25 Conclusions...................................................................................................................................

.25 References.....................................................................................................................................

.26 1

Table of Figures Figure 1 Top view of ICI Pit...........................................................................................................3 Figure 2 Cross Section A-A of the ICI sump. Carbon steel liner is outlined in red ...................... 4 Figure 3 Cross Section B-B. Carbon steel liner is outlined in red ................................................. 4 Figure 4 Normalized inventory based on coring data. Note, after 30 inches the normalized inventory is assumed to be 0.00036 ................................................................ 6 Figure 5 Predicted maximum pit depths as a function of aeration ....................... 11.......................

1 Figure 6 fractional areas penetrated by pits as a function of pit density for very poor and fair aeration soils......................................................................................................................... 12 Figure 7 Predicted fractional area penetrated by pitting as a function of pH . .............................. 13 Figure 8 Schematic diagram of the one-dimensional model used to simulate release from the waste form ................................................................. 14 Figure 9 Cumulative fractional release for H-3 in the case of no liner and three values for the diffusion coefficient.............................................................................................................. 16 Figure 10 Annual release rates over time in the case of no liner and three values for the diffusion coefficient............................................................................................................................. 17 Figure 11 Cumulative fractional amount in solution.................................................................... 18 Figure 12 Cumulative fractional release for C-14 in the absence of a liner ................................ 19 Figure 13 Annual fractional release rate predicted for C-14 ....................................................... 20 Figure 14 Predicted redistribution of tritium with liner intact and D= 10-6 cm 2 /s....................... 21 Figure 15 Predicted redistribution of tritium with liner intact and D= 10-8 cm 2 /s ........................ 22 Figure 16 Cumulative fractional releases for H-3 for a 25-year lifetime liner.

Figure 17 Annual Fractional Release for H-3 for a 25-year liner lifetime .................................. 23 2

Introduction The Maine Yankee (MY) nuclear power plant is undergoing the process of decontamination and decommissioning (D&D). Part of the process requires analyses that demonstrate that any radioactivity that remains after D&D will not cause exposure to radioactive contaminants to exceed acceptable limits. This requires knowledge of the distribution of radionuclides in the remaining material and their potential release mechanisms from the material to the contacting groundwater.

In this study the concern involves radionuclide contamination in activated concrete in the ICI Sump below the containment building. Figures 1 -3 are schematic representations of the ICI Sump. Figure 2 and 3 contain the relevant dimensions needed for the analysis. The key features of Figures 2 and 3 are the 3/8-inch carbon steel liner that isolates the activated concrete from the pit and the concrete wall, which is between 7 feet and 7 feet 2 inches thick. During operations, a small neutron flux from the reactor activated the carbon steel liner and the concrete outside the liner. Current MY plans call for filling the ICI sump with compacted sand.

ICI Pit Activated Concrete

\146 Figure 1 Top view of ICI Pit.

3

Top of Fpcorn Concrete i =

-47

-32 50 -

A-A Figure 2 Cross Section A-A of the ICI sump. Carbon steel liner is outlined in red.

/ tcpouwRnCe TopL-.-

/ [_ w ' ._________ _.I----- -- 3,e- FinConcrte Saxr*Rock Or.

yi3e Fill Caete ,

,' A ,~ -1 34', T i 44 --- '

Top Of Popcorn Concrete A : ' * .- 4 47 B-B Figure 3 Cross Section B-B. Carbon steel liner is outlined in red.

4

Isotope specific characterization data was obtained to define the contamination. Table 1 provides the expected nuclide fractions decayed to January 2004. Characterization included taking approximately 1/2 inch slices of the concrete core. A total of 108 slices were analyzed covering approximately 54 inches. Each slice was analyzed to provide an estimate of the average concentration within the slice. The data indicated a peak in activity at a depth of approximately 2 inches into the concrete. The depth profile found in this characterization study and used in these analyses is presented in Figure 4. Concentrations were normalized to the peak concentration and results are presented in terms of a fractional release of the total inventory. In the data set used for analysis, the concentration of gamma emitting radionuclides was measured and the peak concentration was 2750 pCi/g. This core was taken from a region that will be removed as part of the decontamination effort, but it is the highest activity region of the ICI sump region. A default value of 1 pCi/g was used for all locations more than 30 inches from the inside wall of the core. This concentration is 3.6 x10 4 of the peak concentration.

Table I Nuclide fraction in activated concrete and rebar (Table 2-9 from License Termination Plan)

Nuclide Fraction in Activated Concrete Fraction in Activated Rebar H-3 0.647 __ l C-14 0.058 _ l Fe-55 0.124 0.910 Ni-63 0.007 0.006 Co-60 0.040 0.084 Cs-134 0.0084 __ ---- a- l Eu-152 0.111 ___

Eu-154 0.009 -- -_----

Objective:

The objective is to determine the normalized release rates and cumulative release of key radionuclides from the activated concrete to the groundwater in the surrounding porous medium as a function of liner performance.

Approach Releases will be examined under the following conditions a) Liner intact b) Liner failed instantaneously (total failure, equivalent to liner removal) c) Liner failed at a range of times suggested by liner lifetime estimates.

d) Partial failure of the liner.

A range of liner lifetime estimates will be made based on two failure mechanisms; general corrosion and pitting corrosion. These estimates will be used as the basis of determining releases as a function of liner performance.

5

Inventory between surface and depth Normalized to Peak Concentration 0.8 02 I, i Z 0.2 v ~~~~~~~- -- ~-- - - - - --- --- -----------------

0 5 10 15 20 25 30 35 40 45 50 55 60 Depth (inches)

Figure 4 Normalized inventory based on coring data. Note, after 30 inches the normalized inventory is assumed to be 0.00036.

Key radionuclides will be identified from the inventory data and unit dose conversion factors for activated concrete found in Table 6-5 of the LTP.

The release mechanism from the concrete will be assumed to be diffusion controlled. A number of experimental studies have observed this behavior in concrete for many radionuclides.

Advection is another possible transport mechanism. However, it is not being accounted for because flow would occur through the more permeable host rock if a pressure gradient formed.

In addition, while the liner is intact, flow would not occur through the concrete. As the liner failed, transport of the advection front through the 7 feet of concrete would take longer than the diffusion controlled release from the high concentration zone within the first few inches of the liner.

Liner Performance Conceptual Model The liner is 3/8-inch carbon steel. The exterior of the liner (contacting concrete) is coated with bituminous material or Monel. The interior of the liner is coated with 3-mil thick zinc-silicate based paint, which provides galvanic protection to the liner. Modeling of corrosion will not take credit for the coatings. Two corrosion mechanisms, general corrosion and pitting corrosion will be modeled to estimate lifetime.

6

Soil CorrosionData The National Bureau of Standards (NBS, currently National Institute of Standards and Technology) conducted extensive soil corrosion tests (Romanoff, 1957, Gerhold, 1981).

Soil coupons were buried and periodically examined for general and pitting corrosion. In total, 333 different materials were tested for periods of up to 18 years in at least one of 128 different soils. The soil properties covered the following range of conditions: resistivity (64 - 45,000 ohm-cm); pH values (3.1 - 9.8); residual moisture content (2.8 - 585); air filled porosity (1.1 -

57.8%); and aeration properties (very poor to good). In these studies, carbon steel and ferrous metals were exposed to 47 different soils for time periods of up to 14 years. Analysis of the data (Romanoff, 1968) showed that corrosion rates for carbon steel, wrought iron, and ductile iron were similar in these soils. These data form the basis of the analysis of container lifetime.

An important parameter for correlating localized corrosion is the degree of aeration. Aeration provides a measure of the degree of oxygen and moisture that can access the soils. General guidelines for determining aeration can be found in Romanoff [Romanoff, 1957]. Aeration characteristics of a soil are dependent on the physical characteristics such as particle size, particle-size distribution, and apparent specific gravity. All of these are related to the size and continuity of the pore space, which is also related to drainage. Aeration is a more general concept than drainage, however, as aeration also depends on topographic features, depth to the water table, and amount of rainfall. In general, soils of coarse texture, such as sands, tend to have low water-holding capacity and are characterized by high aeration. Fine textured soils, such as clays, tend to have poor aeration. Four aeration categories were defined in the NBS study: good, fair, poor, and very poor. Very poor aerated soils have low resistivity and are known to be corrosive to carbon steel and favor pit growth.

Soil CorrosionModels and Results General Corrosion The general degradation model assumes that the degradation process is constant and independent of time. For corrosion of metals, this can be conservative because the corrosion data in soil systems generally indicate a decreasing rate of corrosion in time [Romanoff, 1957; Gerhold, 1981]. The output of the general degradation model is the time at which failure occurs, tf, and can be determined from the following:

tf =d/g where d = degradation allowance thickness (cm) and g = is the general degradation rate (cmlyr).

The degradation thickness is the thickness of the container that is allowed to degrade prior to failure. It is often the container thickness minus a fraction of the thickness to account for mechanical failure when the container gets too thin to support the overburden or to account for localized corrosion.

7

Table 2 presents the average and range of corrosion rates and lifetimes for a 3/8-inch (0.95 cm) thick carbon steel liner. Adjustments for localized corrosion or mechanical failure have not been accounted for in Table 2, however, they will be addressed in estimating liner lifetimes for modeling diffusion release.

Table 2 Average and range of corrosion rates and lifetimes for 3/8 inch (0.95 cm) carbon steel liner Average (cm/s) Range (cm/s)

Rate 5.7 10-3 8.5 10a-1.9 102-Average (years) Range (years)

Lifetime 168 50 -1120 Values at the low end of the lifetime range are typically found in poorly aerated soils with either low pH or high chlorine content. For example, the corrosion rate of carbon steel in a Tidal Marsh setting with a chlorine content of 43 mg/lOOg of soil was 1.3 x 10-2 cm/yr (Romanoff, 1957). The aeration conditions at Maine Yankee are expected to be fair to good and the chlorine content is expected to be less than 50 ppm, therefore, the low end of container lifetime estimates are probably not appropriate.

Independently, Maine Yankee staff estimated a lifetime of 490 years for the 3/8-inch liner in sandy soils in the pH range of 6 - 9. In addition, they estimated a lifetime of 57.8 years for the 3-mil thick zinc-silicate based paint that provides galvanic protection of the carbon steel.

Pitting Corrosion The objective of the local degradation model is to calculate the fraction of the liner that has been penetrated due to degradation as a function of time. The localized failure model generally permits water access to the activated concrete at earlier times than the general corrosion model.

Therefore, it will tend to be more important for short-lived radionuclides that undergo substantial decay prior to release.

The localized failure model is structured to evaluate pitting corrosion of metallic containers. The database used to generate the empirical parameters is based on carbon steel data. The localized corrosion pitting model assumes that a hemispherical pit is formed and estimates the area breached based on the maximum pit depth h, corrosion allowance, d, and the number of penetrating pits per container, Np. The area breached is equal to Ab = Np X W2 _d2)

Ab=O whenh<d 8

d is the corrosion allowance used for estimating failure time. In these calculations, it is assumed that the corrosion allowance is the entire thickness of the liner. To address concerns about a combination of general and pitting corrosion leading to failure, the failure time used in estimating release will be reduced from the values calculated independently for either mechanism.

The typical distribution of pit sizes shows a large number of small pits with a few deep pits.

Marsh conducted pitting experiments for 10,000 hours0 days <br />0 hours <br />0 weeks <br />0 months <br /> on carbon steel at 90 C with the contacting solution having 1000 ppm Cl- [Marsh, 1985]. He found a pit density of 8 per square centimeter with a pit depth of at least 0.1 cm. The pit density for large pits was approximately 0.05 (cm 2y'. The large pits represent the pits that will eventually penetrate the container. Based on these data, the number of penetrating pits on carbon steel has been estimated to range between 0.05 and 0.5 per cm2 . [Sullivan, 1988]

The maximum pit depth, h, is obtained from the data generated by the National Institute of Standards and Technology [Romanoff, 1957] and takes the form:

h= kt- (A/372)a where k = empirical pitting parameter cm/yr",

t = corrosion time in years, n = empirical pitting exponent 2 A = representative surface area in cm a = experimentally derived empirical correlation coefficient.

The term (A/372)a is correction term to account for the fact that pitting is a statistical process and therefore, the larger area studied, the higher probability of finding a deeper pit. The constant 372 cmr is a scaling factor and represents the size of the samples in Romanoff's study. The equation above provides an estimate of the maximulk pit depth over the entire surface area under evaluation.

Values for the pitting parameter k and n were determined as a function of soil aeration and are presented in Table 3 [Mughabghab, 1989]. In the data from Romanoff, the range of values for k was 0.03 - 0.15 with an average value of 0.074 and the range of values for n was 0 -

0.92 with an average value of 0.39.

Table 3 Values for pitting parameters as a function of soil aeration.

Degree of aeration Good l Fair Poor Very Poor Pitting Parameter 0.094 0.086 0.052 0.068 k (cm/yr')

Pitting exponent 0.26 0.39 0.44 0.59 1 n I _ _ _ _ I_ _ _ _ _ _ I__ _ _ _I_ I__

9

In addition to estimating the value of the pitting parameter k as a function of soil aeration, correlations of k with pH were obtained (Mughabghab, 1989).

k = 0.01458 (10 - pH) pH < 6.8 k=0.0457 6.8 <pH<7.3 k = 0.0256(pH - 5.13) pH > 7.3 This correlation was used to assess the potential for pitting in pH 9 solution as the collected sump water outside the containment building beneath the reactor averaged 9.3 over the past 3 years.

Values for the exponent "a" depend on the material and the soil. Extensive studies by Logan [Logan, 1939] indicate that for wrought iron and carbon steels "a" ranged from 0.08 to 0.32 with a mean value of 0.15. A value of 0.15 was used in estimating pitting in this study.

The choice of the area, A, has to be balanced with the assumptions of the number of penetrating pits per unit area. Use of a large value for A will provide a better estimate of the largest penetrating pit. However, for estimation of breached area, the average pit depth for penetrating pits is the most relevant parameter. Thus, if a high value for the number of penetrating pits per unit area is selected, the average depth of this pit will be smaller than if a low value is selected. A value of 104 cm2 (1 M2) is used for the area correction factor. This is less than the actual area of the ICI sump, however use of the actual area would be inappropriate for these calculations. The area-scaling factor is used to find the maximum pit over a sample area.

Therefore, use of the actual area would give an estimate of the single largest pit. In this calculation, the objective is to calculate the area breached by pitting, not the largest pit, and an estimate of the average size of a penetrating pit is the appropriate value. This calculation assumes that there are between 0.05 and 0.5 (cm2)- pits. Therefore, using the maximum pit depth from a I M2 area, where there are between 500 and 5000 penetrating pits is believed to provide a conservative estimate of breached area.

Pittingg Corrosion Modeling Results The model and parameters described above were used to estimate potential pitting rates through the 3/8-inch carbon steel liner. Figure 5 presents the maximum pit depth as a function of time and soil aeration conditions and contrasts this with the liner thickness. From the liner thickness, the approximate time of first penetration as a function of soil aeration was estimated: 40 years for very poor aeration, 135 years for fair aeration, 200 years for average pitting parameter values, 245 years for poor aeration and greater than 250 years for good aeration.

10

Maximum Pit Depths as a function of soil aeration and time 3

2.5 Very or Aeration 2

0.

0.5 r Average of all soils 0 20 40 60 80 100 120 140 160 180 200 Time (years)

Figure 5 Predicted maximum pit depths as a function of aeration Figure 6 presents the results for the analysis of area breached as a function of the number of penetrating pits per unit area. The two most aggressive soil conditions, Very Poor and Fair Aeration were simulated. The results indicate that if there are 0.5 penetrating pits/cm 2 , pitting will rapidly consume the liner. In the very poor aeration case, 7% is breached at 40 years, 53%

is breached by 50 years and 100% is breached by 60 years. At 0.05 penetrating pits/cm 2 , it takes 100 years since the time of first penetration to corrode all of the metal. The rate of pitting in fair soils is slower than in very poor soils and therefore, the effects are less pronounced but similar.

For the high pit density, 0.5 (cm 2 )-, the first penetration occurs at 135 years and pits are predicted to penetrate 83% of the area by 250 years. For the lower density of penetrating pits, only 8% of the area is predicted to have pitted through by 250 years.

11

Fractional Area as a Function of Number of Pits per Unit Area 09 81 R Very Poor Aeration

<0.9 sD 0 .7 _ _ _ _ _ _ _ _ _Pit 0.8

<0.

_ 0.5 la Fair Aeration Ud 0.3 I WMximum Number of Pit-0.2 Minimum Number of Pits 0.1 0

0 50 100 150 200 250 300 Time (years)

Figure 6 Fractional areas penetrated by pits as a function of pit density for very poor and fair aeration soils.

The third variable examined for its impacts on pitting was pH. It is likely that the pH of the water contacting the carbon steel liner will be around 9 based on data collected from the ICI sump. The exponent k was estimated using the correlation with pH for pH between 7 and 11.

The correlation is linear and increasing with pH. Extrapolation up to pH 11 is suspect as the soil data maximum pH was 9.3, similar to the values found in the ICI sump. However, this was performed to get a worst-case estimate of the impacts of pH on pitting. The other parameters used were identical to that for the fair aeration soil (exponent n is 0.39). Figure 7 shows the results of the analysis. The model indicates that at high pH pitting corrosion may lead to early failure of the container. At pH 7, the model predicts that pits have not penetrated the container for 250 years. At pH 9, the first penetration occurs at 95 years and the entire liner would be corroded away by 185 years. This is slightly faster than the previous case because the pitting parameter k is approximately 15% higher at pH 9 than the average value. At pH I1, the k is estimated to be 0.15 as compared to the average value of 0.086. This causes the predicted first penetration to occur after 33 years and complete corrosion of the liner would occur within 75 years.

12

Fraction of Area Breached due to Pitting 0.9 0.8 / z

0) ph0 Eo047 ID - ph 9 z km0.5 -h-r-phil1 c

0 0.2-o 0.4- /- / fPt entare 0.5 pits/cm2. Maximum Number 0.2 /

0.1 0 20 40 60 80 100 120 140 160 180 200 Time (years)

Figure 7 Predicted fractional area penetrated by pitting as a function of pH.

Selection of Container Lifetimes for Release Analysis The preceding analysis on corrosion of carbon steel suggests lifetimes on the order of a few hundred years under conditions likely to occur at the Maine Yankee site. Using the average corrosion rate for all soils suggests a lifetime of 168 years with a range of 50 - 1200 years. First penetration by pitting is also predicted to occur at 200 years, based on the average values for pitting rates, with a range of 35 to greater than 250 years. Additionally, a lifetime of 57.8 years was estimated for the protective paint on the liner.

These analyses did not account for combination of general corrosion and pitting. Therefore, the lifetime is likely to be lower than the predicted values. For the purposes of examining potential releases from the activated concrete, lifetime estimates of 0, 25, 50, and 100 years will be used.

Instantaneous failure, equivalent to removal of the liner, is an unrealistic assumption but provides an upper bound on the maximum release. A lifetime of 25 years is also felt to be unrealistically low because the protective paint liner is expected to last more than 50 years before corrosion can start. Even if the protective layer fails earlier, the highest pitting rates suggest 35 years before penetration and the highest corrosion rates suggest 50 years before complete consumption of the liner. Thus, even in combination it is likely that the liner will last more than 25 years. In addition, the high general and pitting corrosion rates occurred in environments that are known to be more aggressive to carbon steel than the environment anticipated at Maine Yankee. The lifetimes of 50 and 100 years are used to explore the range of impacts of lifetime 13

on release. Although the liner may last more than 100 years, releases will be insensitive to longer lifetimes because short-lived radionuclides, for example H-3, will have undergone substantial decay. Long-lived radionuclides such as C-14 will not undergo substantial decay unless the liner lasts more than 1000 years.

Diffusion Controlled Release Previous estimates of release assumed that the entire inventory was released from the concrete into the contacting water instantly. This is extremely conservative as there are several studies that show release is controlled by diffusion or solubility. Therefore, a more realistic conceptual model for estimating release from the activated concrete assumes diffusion is the rate controlling mechanism. A one-dimensional finite difference model was set up to represent the system as shown in Figure 8. The DUST code was used to perform the analysis (Sullivan, 1993).

Conceptual Model of Activated Concrete System Porous Mediato Scale Porous Media/

I Water I Concrete - 7 ft I Water I 3/8-inch liner Figure 8 Schematic diagram of the one-dimensional model used to simulate release from the waste form.

In the porous media/water regions surrounding the concrete, the diffusion coefficient was set to I0-5 cm2/s to provide rapid transport away from the concrete and thereby enhance the predicted rate of release. Prior to failure of the liner, it was modeled as a region with a very low diffusion coefficient (D = 10-14 cm 2/s) that effectively prevents diffusion through the liner. After the designated container lifetime, the diffusion properties of the liner were increased to that of the surrounding porous media. The diffusion coefficient of the radionuclide in the concrete is discussed later.

In translating the conceptual model geometry into a finite difference model, the concrete region was modeled with 1/4 inch (0.635 cm) cells. The liner was modeled as two 3/16-inch (0.48 cm) cells. The normalized inventory depicted in Figure 4 was used as the initial condition for the distribution of contaminants.

Key Radionuclides In the License Termination Plan Cs-134, Co-60, C-14, Eu-152, Eu-154, Fe-55, H-3, and Ni-63 were identified as the radionuclides in the activated concrete (Table 1). In these analyses H-3 and C-14 are simulated. H-3 had the highest inventory and the highest predicted dose for the inventory distribution in the concrete. C-14 is considered because of its long half-life and relatively high predicted dose for the inventory distribution. In the current analyses releases are 14

reported in terms of the fraction of the total inventory in the activated concrete. This will permit scaling of the results to the actual measured inventory. H-3 will have as high or higher mobility than any other radionuclide and can serve as an upper bound to release of all radionuclides with a shorter half-life and Eu-152, which has a slightly longer half-life (13.4 years). Although Eu-152 has a longer half-life than H-3, it is expected to have slower release rates from the concrete than H-3 and will also sorb to the surrounding porous medium and H-3 will not. Therefore, the dose impacts from Eu-152 per unit inventory will be much lower than for H-3. Thus, the only radionuclide not bounded by this analysis is Ni-63. This is not believed to be a major issue as the predicted dose impact for Ni-63 is four orders of magnitude less than that of H-3.

ExperimentalDiffusion Coefficients A few studies have been conducted for the diffusion of H-3 and C-14 in cement. Literature values for H-3 diffusion range from 6 10-9 cm 2/s to 5.5 10-7 cm 2 /s (Dayal, 2003, Serne, 2001, Matsuzuro, 1976, Szabo, 2002). For the purposes of analysis, three diffusion coefficients will be used D = 10-6, 5.5 10-8, and 10-8 cm2/s. The largest value represents the highest transport rate, as it is larger than any measured value. The second value represents a mid-range value from all of the data and the third value is a value on the low end of the range of measured data. These three values were chosen to examine the range of conditions that could be expected to occur.

Carbon-14 movement in cement is a complicated geochemical issue. In cement chemical environments, carbon often forms carbonates and is not readily transported through the cement.

A few experiments have estimated diffusion coefficients based on leaching data. The estimated diffusion coefficient values range from 7 10-15 to 1 10-12 cm2%s (Habeyab, 1985, Semne, 2001).

These values suggest that C-14 is not mobile in cement systems. For the analyses in this study, a value 10-12 cm2/s was used. This should provide an upper bound estimate of C-14 releases.

Predicted H-3 and C-14 Release Rates and Cumulative Release The data values for initial distribution, diffusion coefficients, and liner lifetimes were used in a series of analyses that examined the normalized annual release rate and cumulative fractional release from the activated concrete. Three major categories, instantaneous liner failure, liner intact for all times, and liner completely failed after a specified time were analyzed. The instantaneous failure provides an upper bound on release. The liner intact for all times provides an upper bound estimate on release out of the unlined section of concrete. In addition, it provides information on the potential redistribution of contaminants prior to liner failure and may help interpret current distributions of H-3 in the activated concrete. The fixed liner lifetime analyses provide more realistic evaluations of what will occur.

InstantaneousLiner Failure Tritium As an upper bound on potential releases, the liner was assumed to fail instantly. Figure 9 presents the cumulative fractional release of H-3 from the activated concrete with an instantaneous failure of the liner for the three selected values of the diffusion coefficient (D= 10-6; 5.5 10-8; and 10-8 cm2 /s). The results indicate a large fraction of the inventory is released 15

within the first few years. Due to depletion and radioactive decay release is essentially complete within 30 years. The high release rate occurs because for inventory distribution used in the analysis, Figure 1,49% of the mass is within 2 inches and 99% is within 12 inches of the surface adjacent to the liner.

Tritium Cumulative Fractional Release No liner 7.E-01 6.E . .

DIE-6cm2ls 5.E-01 - "D=5.5E-cm21s a-AD= 1E-8cm2Is 8 4.E-01 3.E &

g 2.E 1.E-01 O.E+00-0 10 20 30 40 50 60 70 80 90 100 rime (years)

Figure 9 Cumulative fractional release for H-3 in the case of no liner and three values for the diffusion coefficient.

Figure 10 presents the annual fractional release rate for the three values of the diffusion coefficient. This graph indicates that the peak release is always in the first year and declines rapidly as the source is depleted. It is interesting to note that the case with the largest diffusion coefficient, D, after about 10 years, has a lower release rate than the lower diffusion coefficients.

This is a result of the rapid depletion of the high concentration zone near the surface for the higher value for D. In all cases, the release rate declines by more than an order of magnitude within 10 years.

16

Tritium Fractional Release Rate High concentration side 1.OOE+0-0~~~~~ + 'D=lE-6 cm 2/s' 1.00E-01 -i-- D=5.5E-8 cm2ls t k~~~~~~~~J D=1E-8 cm2/s 1.00E-02 U 1.00E-03 C

1.OOE-04 IL 1.OOE-05 1.00E-06 0 10 20 30 40 50 60 70 80 90 100 Time (years)

Figure 10 Annual release rates over time in the case of no liner and three values for the diffusion coefficient.

The ultimate concern is the amount of radioactivity in the contacting solution, as groundwater is the pathway for human exposure. To obtain an upper bound estimate, it was assumed that everything released remained in solution subject to radioactive decay (i.e. transport processes were not fast enough to move contaminants out of the area). For H-3 due to its short half-life, there will be a brief period when the concentration in solution builds up until the decay of the mass in solution exceeds the amount released per year. At that time, the inventory in solution will decrease in time. Figure 11 shows the fractional inventory in solution for the three values of diffusion coefficient.

17

Tritium Cumulative Fraction in Solution No liner 0.50 C 0.45 0 0.40 co C 0.35 . ~~~~ * ~~~--*D=5.5E-8 cm2ls S D I1E-8

^~~~~~~-A cm2/s 0

E 0.30

. "%%6 0r 0.25 i -!%

is 0.20 0.15 E

U. 0.10 0.05 0.00 0 10 20 30 40 50 60 70 80 90 100 Time (years)

Figure 11 Cumulative fractional amount in solution.

Table 4 summarizes the total cumulative fractional release, peak fractional release rate, and maximum fraction in solution for the three cases when a liner is not present. The maximum amount in solution for H-3 is only slightly greater than the maximum annual release as result of radioactive decay and the decrease in release rates over time. The ratio of maximum in solution divided by maximum annual release never exceeded a value of 1.6.

Table 4: Summary of maximum annual, cumulative, and fraction in solution for H-3 in the case of no liner.

Maximum Annual Cumulative Maximum Fractional

-6 2 Fractional Release Fractional Release Amount in Solution D = 106 cmn/s - 0.37 0.59 0.44 D= 5.5 10-" cm2/s 0.16 0.41 0.26 D = I 10- cm2 /s 0.09 0.25 0.13 Similar analyses were performed for the concrete that is always intact with groundwater on the side away from the liner. Due to its much lower concentration (approximately 1I3000 of the peak concentration) releases were substantially lower from this side. For D= 10 cm 2 /s, peak release rates were less than 2.2 104 and the peak cumulative fractional release was 8.1 104.

Lower release rates and cumulative fractional release were obtained for the lower values of D.

18

Carbon-14 For the instantaneous liner failure case, the cumulative fractional release near the liner is presented in Figure 12. The predicted fractional release in the first year is greater than 4% of the inventory. This is unreasonably high for a diffusion coefficient of I0 cm Is. Analytical models for diffusion release [Pescatore, 1991] from a 15 cm thick rectangular geometry with a uniform concentration suggest a release of less than 0.1% during the first year and less than 2.6%

over 1000 years. This model allows diffusion out both sides and therefore, is equivalent to assuming a thickness of 7.5 cm for the one-sided case. In other words, 100% of the inventory is within 7.5 cm (3 inches of the surface). The cause of this discrepancy is numerical simulation error at the interface between the activated concrete and the contacting porous media. In DUST, the diffusion coefficient used to estimate transport is the average of the diffusion coefficient in two adjacent finite-difference control volumes. Thus, at the interface, where the diffusion coefficient changes from 10-12 cm2/s in the activated concrete to 10-6 cm 2 /s in the porous medium, the code uses a value of 0.5 10-6 cm 2 /s. This effectively makes the first control volume of the activated concrete have a diffusion coefficient that is l/2 the value of the porous media and almost six orders of magnitude greater than intended. This causes the first control volume, which contains 5.7% of the total inventory, to empty rapidly leading to the predicted high release.

Carbon-14 cumulative fractional release No liner 0.07 -

0.06 -

o 0.05 _

E_ <0.04 LL CU

> 0.03 -l -Diffusion Coefficient =IE-12 cmA2/s E 0.02 o 0.01 0.00 0 20 40 60 80 100 Time (years)

Figure 12 Cumulative fractional release for C-14 in the absence of a liner.

Figure 13 presents the annual fractional release rate for C-14. The rapid decrease from 4 % in the first year to less than 10-3% within 20 years reflects the rapid draining of the first computational cell due to the numerical simulation model. The lower rates at the longer times are more representative of diffusion out of a low diffusion region.

19

Carbon-14 Fractional Release Rate No liner I .OOE+01 1.OOE+OO -00 Diffusion Coefficient =1E-12 cmA2/s

. 1 .OOE-01 e

E 1.00E-02 2co.

0 e1.00E-03 11.OOE-04 E i.OOE-03 ^

LL.

t~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

1 .00E-05 1.OOE-06 5

0 100 200 300 400 TI ?O) 600 700 800 900 1000 Figure 13 Annual fractional release rate predicted for C-14.

To remove this unintended numerical consequence, an additional 0.6 cm long volume was introduced between the liner and the activated concrete. The diffusion coefficient for this region was set to I I-2 cm 2 /s, the value for the activated concrete. This forced the value of the diffusion coefficient in the activated concrete to remain at 10-12 cm 2 /s in the finite difference simulation.

In this case, the predicted release over 1000 years was only 0.4%. This is similar in magnitude to the analytical solution and is felt to be more representative of actual releases.

For the remainder of the paper, the diffusion model in DUST will be used to generate the results for C-14 recognizing that they will provide extremely high estimates of release at the liner side.

Due to the long half-life for C-14, the cumulative fractional release provides a reasonable estimate of the maximum amount that could be in solution at any time.

LinerIntact If the liner is intact, the contaminants have to diffuse through the 7 feet of concrete to be released from the other side. Due to the short half-life of tritium, releases are extremely low from this side for any value of the diffusion coefficient. Due to the low diffusion coefficient for C-14, the releases are also very low. The maximum release for both H-3 and C-14 at the unlined side of the concrete arises from the assumption that the concentration has a minimum value of I pCilg.

Table 5 summarizes the maximum fractional annual release and the cumulative release over the 1000-year simulation period.

20

Table 5: Maximum total and annual fractional release for an intact liner.

Maximum Annual Fractional Release Cumulative Fractional Release H-3 210-' 9.010 C-14 2 10-' 2.4 10-'

An interesting consideration is the possible redistribution of H-3 while the liner is intact. This may be important in understanding the current distribution of H-3 in the activated concrete as several years have passed since the end of operation. Figures 14 and 15 show the redistribution of H-3 if the diffusion coefficient is 10-6 cm Is and 10-8 cm2/s. At the higher diffusion coefficient, redistribution is rapid and the peak concentration moves from a depth of two inches to the surface within 1 year. For the lower value of the diffusion coefficient, the redistribution is much slower and even after 10 years, the peak remains at a depth of 2 inches.

Tritium Concentration Profile 9.OOE-011 8.OOE-01 7.OOE-01 g ~ ~~\ D1.0EO-6 CMAJ2tS r- 6.01E-011 1 0 +Time

= 0.1 year -

1

_i_ f IF~~~~ Time = 1.0 year 8 5.001E-01 -~~~_\F~ + Time = 5.0 years

_9~ Time = 10 yearsI i 4.OOE-01 a Vai I

)MO z 3.OOE-01 2.OOE-01

^so**^,^~~~

AM6 ---

1.OOE-01 O.OOE+00 O.OOE+00 2.OOEv00 4.00E+00 6.OOE+00 8.OOE+00 1.00E+01 1.20E+01 Distance (inch)

Figure 14 Predicted redistribution of tritium with liner intact and D= 10-6 cm 2 /s.

21

Tritium Concentration Profile 1.0 -

g 0.9 k "I L D=1.OE-8 cmA2/s 0.8

~0.7 0.6- w a 0.6 / Time = 0.1 year 0.5 0.4 N i__ _ -- Time = 1.0 year 0.4 * -- Time = 5.0 years E0.3 -2l-Time = 10 years 0.1 0 2 4 6 8 10 12 Distance (inch)

Figure 15 Predicted redistribution of tritium with liner intact and D= lo-8 cm2 ls.

Effect ofLiner FailureTime Tritium The corrosion modelling suggested a liner time of at least 100 years if credit was taken for the protective paint. Considering combination of pitting and general corrosion suggested that lifetimes of 25, 50, and 100 years be examined to determine the effect of failure time. Twenty-five years is believed to be an extremely conservative estimate of lifetime. To simulate this, it was assumed that the liner would be intact until the failure time and diffusion through the liner would be very slow (D= 10-14 cm 2 /s). At this time, the liner was assumed to provide no barrier to release and the effective diffusion coefficient was changed to that of the surrounding porous medium (D= 10-5 cm 2 /s for H-3 and D=l0-6 cm2 /s for C-14).

Figure 16 provides the cumulative fractional release for the 25-year liner lifetime. The figure contains the predicted cumulative fractional release for three values of the diffusion coefficient (D = 106, 5.5 10-8, and 10-8 cm 2 /s). Two important differences occur from when the liner fails instantly. First, total releases are much lower. Second, the D= 10-6 cm2/s simulation does not release the maximum amount, the D= 5.5 10-8 cm2/s case does. The cause for this is while the liner is intact, more of the mass has moved away from the liner at the higher diffusion coefficient. Figure 17 shows the annual fractional release for the 25-year liner lifetime. It can be 22

seen that after the first few years, the annual release rate is not strongly dependent on the choice of diffusion coefficient.

H-3 Cumulative Fractional Release 9.OOE-02 *- D=Ie-6 cmA2/s

-s-D=5.5E-8 cmA2/s a, 8.00E-02 -U-- D=1 E-8 cmA2/sI IE 7.OOE-02 6.00E-02 0

5.001E U.

a, 4.001E 3.00E-02 -_

2.OOE E 1.OOE O O.OOE+00 0 20 40 60 80 100 Time (years)

Figure 16 Cumulative fractional releases for H-3 for a 25-year lifetime liner.

H-3 Fractional Release Rate High concentration side 1.OE 1.OE g 1.OE e 1.OE-04

I .OE-05 11.OE +D 1E-6cm^2/s

-u- D=5.5E-8 cmA2/s 1 1.0E-07 - D=1E-8 cmA2/s 1.OE 1.0E 09 0 10 20 30 40 50 60 70 80 90 100 Time (years)

Figure 17 Annual Fractional Release for H-3 for a 25-year liner lifetime.

23

Figure 18 presents the maximum annual fractional release as a function of failure time. This graphic illustrates the rapid decrease in maximum annual release as a function of time. This is due to the short half-life of tritium (12.3 years) as compared to the failure times. The importance of the liner as a protective barrier for release of tritium is clear.

Maximum yearly release as a function of liner failure time CD W

CD 0

A 0.1 15 W

C 0

L 0.01 E

E 0.0001 0 20 40 60 80 100 Liner Failure Time Figure 18 Effect of liner lifetime on annual fractional H-3 release.

Table 6 summarizes the cumulative and maximum annual fractional release for H-3 at the four failure times (0, 25, 50, and 100 years) for the three diffusion coefficients. The annual fractional release values in Table 6 can be multiplied by the total inventory to estimate mass release and this value can be used in dose assessments. The table shows that after 25 years, the lowest diffusion coefficient has the highest release rates. Although the cumulative release for the D= 10-cm case are always lower than for the D=5.5 10-8 cm Is case. This is a result of diffusion.

While the liner is intact, the higher diffusion coefficient case moves more material away from the liner. After the liner fails, some of this material diffuses back to be released at this interface.

24

Table 6 Effect of Liner Lifetime on Predicted H-3 release.

Diffusion Maximum Cumulative Maximum Coefficient Annual Fractional Fractional Amount (cm 2 /s) Fractional Release In Solution Release

_________FE ire AN-i 0yearR -I.

106 0.37 0.59 0.44 5.5 10- 0.15 0.41 0.26 IF0 0.086 0.24 0.13 Fai ure Ti me 25yea rs

_ _ _ _ _ _ _ _ _ _ _ _Ad_ _

10-6 0.024 0.071 0.041 5.5 10-" 0.031 0.078 0.045 1O- 0.028 0.059 0.034

_______ FailureTmte=50 yers _____________z l0-6 4.2 10-3 0.014 7.5E-3 5.5 10-8 6.1 10-3 0.016 9.OE-3 lo-8 6.5 10-3 0.014 7.9E-3

___6 1.8 104 6.1 104 3.3 104 5.5 10- 2.9 I04 7.7 104 4.3 104 lO- 3.5 10i 7.3Y04 4.2 104 Carbon-14 Analyses were also performed for C-14 release rates as a function of liner lifetime. Due to the long half-life of C-14 (5730 years) compared to the failure times and the low diffusion coefficient of C-14 in the activated concrete. The predicted releases were not sensitive to the failure time and the discussion on C-14 releases from an instantaneously failed liner remain essentially unchanged. The cumulative fractional release over 1000 years ranged from 6.0% for a 100-year liner lifetime to 6.1 % for instantaneous liner failure.

Effect of PartialFailure Modeling of partial failure due to pitting was not performed. The pitting modeling suggested breakthrough would not occur prior to 35 years for all conditions considered. For the conditions likely to be found at Maine Yankee, it is more likely that through pitting would not occur for much longer periods. Therefore, it is unlikely that breach due to pitting will occur prior to the minimum lifetime assumed for the analysis, 25 years. However, if the pitting caused partial failure of the liner prior to the assumed total failure time, as a first approximation, the amount released from a partially failed liner should be directly proportional to the release from a totally failed liner at that time scaled by the fraction of the area that is failed. The fraction of failed area should be small due to the conservative nature of the selected failure times.

Conclusions Modeling has been performed to examine the potential releases from activated concrete in the ICI sump at Maine Yankee. Two radionuclides were considered in the assessment, H-3 and C-

14. Tritium was selected because it constitutes over 60% of the inventory and had the highest 25

dose impact of all contaminants in the concrete. Carbon-14 was selected because of its long-half life and high dose impact. A key parameter in the assessment is the lifetime of the 3/8-inch carbon steel liner. Estimates of general and pitting corrosion were performed for a wide range of conditions and the data indicated that under expected conditions the liner should last several hundred years. Under the most aggressive conditions the lifetime was predicted to be around 50 years for either general or pitting corrosion. To address a combination of corrosion mechanisms, a minimum lifetime of 25 years was selected for analysis of releases. Lifetimes of 0, 50, and 100 years were also selected. The release modelling showed that if the liner failed immediately, H-3 releases could be as high as 37% in one year. If the liner lasted only 25 years, the maximum release was limited to 3.1 % of the inventory with a maximum cumulative release of less than 8%. Finite difference modeling of the release of C-14 showed a release of 5% in the first year, this was due to the numerical treatment of the discontinuity at the interface of the activated concrete (D= 10.12 cm 2 /s) and the porous medium (D= 10 cm 2 /s). The cumulative release over 1000 years is predicted to be 6.1%. Due to the long half-life of C-14, the release is essentially independent of liner failure time.

References

[Gerhold, 1981]

Gerhold, W.F., E. Escalante, and B.T. Sanderson, "The Corrosion Behavior of Selected Stainless Steels in Soil Environments," NBSIR 81-2228, National Bureau of Standards, 1981.

[Logan, 1939]

Logan, K.H., "Engineering Significance of National Bureau of Standards Soil-Corrosion Data," Journal of Research of the National Bureau of Standards, Vol. 22, January 1939.

[Marsh, 1985]

Marsh, G.P., Bland, I.D., Desport, J.A., Naish, C., Westcott, C., and Taylor, K.J.,

"Corrosion Assessment of metal overpacks for radioactive waste disposal," Scientific BasisforNuclear Waste ManagementIX, Materials Research Society, Pittsburgh, PA, 421 (1985).

[Mughabghab, 1989]

Mughabghab, S.F., and T.M. Sullivan, "Evaluation of the Pitting Corrosion of Carbon Steels and other Ferrous Metals in Soil Systems," Waste Management, V. 9, pp 239 -

251, 1989.

[Pescatore, 1991]

Pescatore, C."Leach Rate Expressions for Performance Assessment of Solidified, Low-Level Radioactive Waste," JournalofNuclear and Chemical Waste Management, 1991.

[Romanoff, 1957]

Romanoff, M., "Underground Corrosion," National Bureau of Standards Circular 579, 1957.

26

[Sullivan, 1988]

Sullivan, T.M., C.R. Kempf, C.J. Suen, and S.F. Mughabghab, "Low-Level Radioactive Waste Source Term Model Development and Testing," NUREG/CR-5204, BNL-NUREG-52160, Brookhaven National Laboratory, 1988.

[Sullivan, 1993]

Sullivan, T.M., "DUST: Disposal Unit Source Term - Data Input Guide," NUREG/CR-6041, BNL-NUREG-52375, Brookhaven National Laboratory, 1993.

27

PROPOSED CHANGE NO. 216 BNL Report:

Supporting Input and Output DUST Files

BNL Report Input Files

Data Set 1: General Parameters Maine Yankee Max diffusion D=1E-8 Liner NISO IACT 2 1 NNP ITRANS 470 1 RN Prop H-3 1.233e+01 0.000e+00 3.000e+00 RN Prop C-14 5.730e+03 0.000e+00 1.400e+01 Decay Chn 0 Data Set 2: Time Parameters NTI DTCHG 9000 1 TIME STEP 1.000e-01 0.000e+00 1.000e-01 1.000e+02 TIME DTCHG 5.000e+01 Data Set 3: Material Parameters NMAT NCM 3 339 K-d DENSITY DISP. DIFFUSION H-3 0.OOOE+00 1.500E+00 1.OOOE+01 1.000E-05 Material #1 H-3 O.OOOE+00 2.200E+00 1.OOOE+01 5.500E-08 Material #2 H-3 0.OOOE+00 3.500E+00 1.000E+01 1.000E-14 Material #3 C-14 0.OOOE+00 1.500E+00 1.000E+01 1.000E-06 Material #1 C-14 0.OOOE+00 2.200E+00 1.000E+01 1.OOOE-12 Material #2 C-14 0.OOOE+00 2.200E+00 1.OOOE+01 1.OOOE-14 Material #3 Matl chng 58 2 1 3 0 Matl chng 60 337 1 2 0 0

Data Set 4: Output Control Parameters Print Control Parameters for each time step (NTI) 1E+69 I E+50 1E+30 1E+10 1

1E+60 11E+40 1E+20 1E+60 I E+40 IE+20 1E+60 1E+40 1E+19 0

Trace var 8 2 10 Con Tr Loc 58 59 60 62 395 396 397 420 FXTrLoc 58 397 Data Set 5: Facility Coordinate Data Area 1.000E+04 Delta-X 1 40 1 0.OOOE+00 1.524E+01 O.OOOE+00 Delta-X 41 10 1 6.020E+02 7.620E+00 O.OOOE+00 Delta-X 51 7 1 6.712E+02 6.350E-01 0.000E+00 Delta-X 58 2 1 676.0 4.760e-01 0.000e+00 Delta-X 60 346 1 677.1 6.350E-01 0.000E+00 Delta-X 406 11 1 9.034E+02 7.620E+00 0.OOOE+00 Delta-X 417 54 1 9.7910E+2 1.524E+01 0.OOOE+00 0 00 0 0 0 Data Set 6: Initial and Boundary Conditions H-3 INV 1 60 1 0.OOOE+00 0.000E+00 H-3 INV 407 74 1 0.OOOE+00 0.OOOE+00

H-3 Inv 61 1 0.861292 0 H-3 Inv 62 1 0.861292 0 H-3 Inv 63 2 0.8870733 0 H-3 Inv 65 2 0.9103122 0 H-3 Inv 67 2 1.0 0 H-3 Inv 69 2 0.9335511 0 H-3 Imv 71 2 0.5424836 0 H-3 Inv 73 2 0.3602033 0 H-3 Inv 75 2 0.3068264 0 H-3 Inv 77 2 0.3173565 0 H-3 Inv 79 2 0.2585330 0 H-3 Inv 81 2 0.1978939 0 H-3 Inv 83 2 0.1561365 0 H-3 Inv 85 2 0.1427015 0 H-3 Inv 87 2 0.1176470 0 H-3 Inv 89 2 0.0918663 0 H-3 Inv 91 2 0.0762527 0 H-3 Inv 93 2 0.0559186 0 H-3 Inv 95 2 0.0421205 0 H-3 Inv 97 2 0.0403050 0 H-3 Inv 99 2 0.0337690 0 H-3 Inv 101 2 0.0246913 0 H-3 Inv 103 2 0.0116194 0 H-3 Inv 105 2 0.0112563 0 H-3 Inv 107 2 0.0098039 0 H-3 Inv 109 2 0.0083514 0 H-3 Inv 111 2 0.0058097 0 H-3 Inv 113 2 0.0036310 0 H-3 Inv 115 2 0.0032679 0 H-3 Inv 117 2 0.0025417 0 H-3 Inv 119 2 0.0025417 0 H-3 Inv 121 2 0.0007262 0 H-3 Inv 123 2 0.0011619 0 H-3 Inv 125 2 0.0008351 0 H-3 Inv 127 2 0.0011256 0 H-3 Inv 129 2 0.0004720 0 H-3 Inv 131 2 0.0003267 0 H-3 Inv 133 2 0.0004357 0 H-3 Inv 135 2 0.0004357 0 H-3 Inv 137 2 0.0004720 0 H-3 Inv 139 2 0.0004357 0 H-3 Inv 141 2 0.0006535 0 H-3 Inv 143 2 0.0005083 0 H-3 Inv 145 2 0.0005083 0 H-3 Inv 147 2 0.0004357 0 H-3 Inv 149 2 0.0054466 0 H-3 Inv 151 2 0.0005809 0 H-3 Inv 153 2 0.0005083 0 H-3 Inv 155 2 0.0006535 0 H-3 Inv 157 2 0.0005446 0 H-3 Inv 159 2 0.0005446 0 H-3 Inv 161 2 0.0005446 0 H-3 Inv 163 2 0.0006535 0 H-3 Inv 165 2 0.0004357 0 H-3 Inv 167 2 0.0001815 0 H-3 Inv 169 2 0.0047204 0 H-3 Inv 171 2 0.0004720 0 H-3 Inv 173 2 0.0006172 0 H-3 Inv 175 2 0.0004720 0 H-3 Inv 177 2 0.0005809 0 H-3 Inv 179 98 0.0003631 0

H-3 Inv 277 120 1 0.0003631 0 0 00 0 0 0 C-14 INV 1 60 1 O.OOOE+00 O.OOOE+00 C-14 INV 387 74 O.OOOE+00 O.OOOE+00 c-14 Inv 61 2 0.861292 0 c-14 Inv 63 2 0.8870733 0 c-14 Inv 65 2 0.9103122 0 c-14 Inv 67 2 1.0 0 c-14 Inv 69 2 0.9335511 0 c-14 Inv 71 2 0.5424836 0 c-14 Inv 73 2 0.3602033 0 c-14 Inv 75 2 0.3068264 0 c-14 Inv 77 2 0.3173565 0 c-14 Inv 79 2 0.2585330 0 c-14 Inv 81 2 0.1978939 0 c-14 Inv 83 2 0.1561365 0 c-14 Inv 85 2 0.1427015 0 c-14 Inv 87 2 0.1176470 0 c-14 Inv 89 2 0.0918663 0 c-14 Inv 91 2 0.0762527 0 c-14 Inv 93 2 0.0559186 0 c-14 Inv 95 2 0.0421205 0 c-14 Inv 97 2 0.0403050 0 c-14 Inv 99 2 0.0337690 0 c-14 Inv 101 2 0.0246913 0 c-14 Inv 103 2 0.0116194 0 c-14 Inv 105 2 0.0112563 0 c-14 Inv 107 2 0.0098039 0 c-14 Inv 109 2 0.0083514 0 c-14 Inv 111 2 0.0058097 0 c-14 Inv 113 2 0.0036310 0 c-14 Inv 115 2 0.0032679 0 c-14 Inv 117 2 0.0025417 0 c-14 Inv 119 2 0.0025417 0 c-14 Inv 121 2 0.0007262 0 c-14 Inv 123 2 0.0011619 0 c-14 Inv 125 2 0.0008351 0 c-14 Inv 127 2 0.0011256 0 c-14 Inv 129 2 0.0004720 0 c-14 Inv 131 2 0.0003267 0 c-14 Inv 133 2 0.0004357 0 c-14 Inv 135 2 0.0004357 0 c-14 Inv 137 2 0.0004720 0 c-14 Inv 139 2 0.0004357 0 c-14 Inv 141 2 0.0006535 0 c-14 Inv 143 2 0.0005083 0 c-14 Imv 145 2 0.0005083 0 c-14 Inv 147 2 0.0004357 0 c-14 Inv 149 2 0.0054466 0 c-14 Inv 151 2 0.0005809 0 c-14 Inv 153 2 0.0005083 0 c-14 Inv 155 2 0.0006535 0 c-14 Inv 157 2 0.0005446 0 c-14 Inv 159 2 0.0005446 0 c-14 Inv 161 2 0.0005446 0 c-14 Inv 163 2 0.0006535 0 c-14 Inv 165 2 0.0004357 0 c-14 Inv 167 2 0.0001815 0 c-14 Irw 169 2 0.0047204 0 c-14 Inv 171 2 0.0004720 0 c-14 Inv 173 2 0.0006172 0

c-14 Inv 175 2 1 0.0004720 0 c-14 Inv 177 2 1 0.0005809 0 c-14 Inv 179 98 1 0.0003631 0 c-14 Inv 277 120 1 0.0003631 0 0 00 0 0 0 BC FLAGS 1 1 2 0 H-3 TIME TOP 0.OOOE+00 1.OOOE+03 VALUE O.OOOE+00 O.OOOE+00 TIME BOT O.OOOE+00 1.000E+03 VALUE O.OOOE+00 O.OOOE+00 BC FLAGS 1 1 2 0 C-14 TIME TOP O.OOOE+00 1.OOOE+03 VALUE O.OOOE+00 O.OOOE+00 TIME BOT O.OOOE+00 1.OOOE+03 VALUE O.OOOE+00 O.OOOE+00 Data Set 7: Water Flow Parameters Vel Pts 2 TIME 0.OOOe+00 1.OOe+03 VALUE 0.000e+00 0.OOOe+00 MST CONT 1 470 1 2.400E-01 O.OOOE+OO 0 00 0 0 0 Data Set 8: Container Parameters NCON TYPE 0 0 Data Set 9: Wasteform Leaching Parameters WF Type 0 Data Set 10: External Sources (F.D. model only)

H-3 SRC 0 1 2 C-14 SRC 0 1 2

BNL Report Output Files

DUST-MS VERSION 3 8197 Spherical and finite difference release models Capability to read upstream mass flow rate from an auxiliary file as a boundary condition TITLE: Maine Yankee Max diffusion D=1 E-8 Liner NUMBER OF ISOTOPES ........... 2 ACTIVITY FLAG (0=Gm, I=Ci, 2=Bq).... I NUMBER OF NODAL POINTS/MIXING CELLS.. 470 TRNSPRT FLAG (FIN DIFF=1) ....... I CONTAMINANT PROPERTIES ***

RADIONUCLIDE .............. H-3 HALF-LIFE (YRS) ............ 1.23E+01 SATURATION CONCENTRATION ..... 1.00E+03 ATOMIC WEIGHT ............. 3.0 CONTAMINANT PROPERTIES ****

RADIONUCLIDE .............. C-14 HALF-LIFE (YRS) ...... ...... 5.73E+03 SATURATION CONCENTRATION . .......

1.00E+03 ATOMIC WEIGHT ............. 14.0 DECAY CHAINS ****

NUMBER OF DECAY CHAINS(O=NO, > =YES).. 0 TIME PARAMETERS ***

NUMBER OF TIME INCREMENTS ....... 9000 NO. OF DISCRETE TIME CHANGES ...... 1 TIME INCREMENT (DELT - YEARS) ...... 1.0E+00 MULTIPLIER FOR INCREASING DELT..... .OOE+00 MAXIMUM VALUE OF DELT (YEARS) ..... 1.00E+00

MAXIMUM VALUE OF TIME (YEARS) ... 1.00E+03 LIST OF TIMES AT WHICH 'DELr CHANGES:

NO. TIME (YRS) NO. TIME (YRS) NO. TIME (YRS) NO. TIME (YRS) 1 5.OOE+01

MATERIAL PROPERTIES NUMBER OF MATERIALS ..... .... 3 NUMBER OF MATERIAL PROPERTIES.... 4 NUMBER OF REDEFINED MATERIALS .... 339 MAT. NO. DISTR.COEFF. DENSITY DISPERS. DIFFUSION Contaminant 1 0.OOE+00 1.50E+00 1.OOE+01 1.OOE-05 H-3 2 0.OOE+00 2.20E+00 1.00E+01 5.50E-08 H-3 3 0.OOE+00 3.50E+00 1.00E+01 1.00E-14 H-3 1 0.OOE+00 1.50E+00 1.00E+01 1.OOE-06 C-14 2 0.OOE+00 2.20E+00 1.00E+01 1.OOE-12 C-14 3 0.OOE+00 2.20E+00 1.00E+01 1.OOE-14 C-14 MATERIAL TYPE ASSIGNMENTS NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 1 29 1 30 1 31 1 32 1 33 1 34 1 35 1 36 1 37 1 38 1 39 1 40 1 41 1 42 1 43 1 44 1 45 1 46 1 47 1 48 1 49 1 50 1 51 1 52 1 53 1 54 1 55 1 56 1 57 1 58 3 59 3 60 2 61 2 62 2 63 2 64 2 65 2 66 2 67 2 68 2 69 2 70 2 71 2 72 2 73 2 74 2 75 2 76 2 77 2 78 2 79 2 80 2 81 2 82 2 83 2 84 2 85 2

86 2 87 2 88 2 89 2 90 2 91 2 92 2 93 2 94 2 95 2 96 2 97 2 98 2 99 2 100 2 101 2 102 2 103 2 104 2 105 2 106 2 107 2 108 2 109 2 110 2 111 2 112 2 113 2 114 2 115 2 116 2 117 2 118 2 119 2 120 2 121 2 122 2 123 2 124 2 125 2 NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE 126 2 127 2 128 2 129 2 130 2 131 2 132 2 133 2 134 2 135 2 136 2 137 2 138 2 139 2 140 2 141 2 142 2 143 2 144 2 145 2 146 2 147 2 148 2 149 2 150 2 151 2 152 2 153 2 154 2 155 2 156 2 157 2 158 2 159 2 160 2 161 2 162 2 163 2 164 2 165 2 166 2 167 2 168 2 169 2 170 2 171 2 172 2 173 2 174 2 175 2 176 2 177 2 178 2 179 2 180 2 181 2 182 2 183 2 184 2 185 2 186 2 187 2 188 2 189 2 190 2 191 2 192 2 193 2 194 2 195 2 196 2 197 2 198 2 199 2 200 2 201 2 202 2 203 2 204 2 205 2 206 2 207 2 208 2 209 2 210 2 211 2 212 2 213 2 214 2 215 2 216 2 217 2 218 2 219 2 220 2 221 2 222 2 223 2 224 2 225 2 226 2 227 2 228 2 229 2 230 2 231 2 232 2 233 2 234 2 235 2 236 2 237 2 238 2 239 2 240 2 241 2 242 2 243 2 244 2 245 2 246 2 247 2 248 2 249 2 250 2 NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE 251 2 252 2 253 2 254 2 255 2 256 2 257 2 258 2 259 2 260 2 261 2 262 2 263 2 264 2 265 2 266 2 267 2 268 2 269 2 270 2 271 2 272 2 273 2 274 2 275 2 276 2 277 2 278 2 279 2 280 2 281 2 282 2 283 2 284 2 285 2 286 2 287 2 288 2 289 2 290 2 291 2 292 2 293 2 294 2 295 2 296 2 297 2 298 2 299 2 300 2 301 2 302 2 303 2 304 2 305 2 306 2 307 2 308 2 309 2 310 2 311 2 312 2 313 2 314 2 315 2

316 2 317 2 318 2 319 2 320 2 321 2 322 2 323 2 324 2 325 2 326 2 327 2 328 2 329 2 330 2 331 2 332 2 333 2 334 2 335 2 336 2 337 2 338 2 339 2 340 2 341 2342 2343 2344 2345 2 346 2347 2348 2349 2350 2 351 2 352 2 353 2 354 2 355 2 356 2357 2358 2359 2360 2 361 2362 2363 2364 2365 2 366 2 367 2 368 2 369 2 370 2 371 2 372 2 373 2 374 2 375 2 NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE NODE MAT.TYPE 376 2 377 2 378 2 379 2 380 2 381 2 382 2 383 2 384 2 385 2 386 2387 2388 2389 2390 2 391 2392 2393 2394 2395 2 396 2397 1398 1399 1400 1 401 1 402 1 403 1 404 1 405 1 406 1 407 1 408 1 409 1 410 1 411 1 412 1 413 1 414 1 415 1 416 1 417 1 418 1 419 1 420 1 421 1 422 1 423 1 424 1 425 1 426 1 427 1 428 1 429 1 430 1 431 1 432 1 433 1 434 1 435 1 436 1 437 1 438 1 439 1 440 1 441 1 442 1 443 1 444 1 445 1 446 1 447 1 448 1 449 1 450 1 451 1 452 1 453 1 454. 1 455 1 456 1 457 1 458 1 459 1 460 1 461 1 462 1 463 1 464 1 465 1 466 1 467 1 468 1 469 1 470 1

"***OUTPUT CONTROL AT EACH TIME STEP***

1000000000000000000000000000000000000000 0000000000000000000000000000010000000000 0000000001000000000000000000000000000000 0000000000000000000100000000000000000000 0000000000000000000100000000000000000000 0000000001000000000000000000000000000000 0000000000000000000000000000010000000001 0000000000000000000000000000000000000000 0000000000000000000000000000010000000001 0000000000000000000000000000000000000000

00000000000000000001 00000000000000000000 000000000 1000000000000000000000000000000 000000000 1000000000000000000000000000000 00000000000000000001 00000000000000000001 000000 0010 00000000000000000000000000000 0000000000000000000000000000010000000000 00000000000000000001 00000000000000000000 0000000000000000000100000000000000000000 0000000000000000000000000000010000000000 0000000001000000000100000000000000000000 0000000000000000000000000000000000000001 0000000000000000000000000000010000000000 0000000000000000000000000000010000000000 0000000000000000000000000000000000000000 1000000000000000000100000000000000000000 NODE NUMBERS FOR CONCENTRATION TRACES:

58 59 60 62 395 396 397 420 NODE NUMBERS FOR FLUX TRACES:

58 397

- - - NODE COORDINATES NODE COORD. NODE COORD. NODE COORD. NODE COORD. NODE COORD.

1 0.0 2 15.2 3 30.5 4 45.7 5 61.0 6 76.2 7 91.4 8 106.7 9 121.9 10 137.2 11 152.4 12 167.6 13 182.9 14 198.1 15 213.4 16 228.6 17 243.8 18 259.1 19 274.3 20 289.6 21 304.8 22 320.0 23 335.3 24 350.5 25 365.8 26 381.0 27 396.2 28 411.5 29 426.7 30 442.0 31 457.2 32 472.4 33 487.7 34 502.9 35 518.2 36 533.4 37 548.6 38 563.9 39 579.1 40 594.4 41 602.0 42 609.6 43 617.2 44 624.9 45 632.5 46 640.1 47 647.7 48 655.3 49 663.0 50 670.6 51 671.2 52 671.8 53 672.5 54 673.1 55 673.7 56 674A 57 675.0 58 676.0 59 676.5 60 677.1 61 677.7 62 678.4 63 679.0 64 679.6 65 680.3 66 680.9 67 681.5 68 682.2 69 682.8 70 683.5 71 684.1 72 684.7 73 685A 74 686.0 75 686.6 76 687.3 77 687.9 78 688.5 79 689.2 80 689.8

81 690.4 82 691.1 83 691.7 84 692.3 85 693.0 86 693.6 87 694.2 88 694.9 89 695.5 90 696.1 91 696.8 92 697.4 93 698.1 94 698.7 95 699.3 96 700.0 97 700.6 98 701.2 99 701.9 100 702.5 101 703.1 102 703.8 103 704.4 104 705.0 10E 705.7 106 706.3 107 706.9 108 707.6 109 708.2 lic I 708.9 111 709.5 112 710.1 113 710.8 114 711.4 11E 712.0 116 712.7 117 713.3 118 713.9 119 714.6 i12C I 715.2 121 715.8 122 716.5 123 717.1 124 717.7 12E; 718.4 NODE COORD. NODE COORD. NODE COORD. NODE COORD. NODE COORD.

126 719.0 127 719.6 128 720.3 129 720.9 13CI 721.6 131 722.2 132 722.8 133 723.5 134 724.1 13E; 724.7 136 725.4 137 726.0 138 726.6 139 727.3 14CI 727.9 141 728.5 142 729.2 143 729.8 144 730.4 145; 731.1 146 731.7 147 732.3 148 733.0 149 733.6 15CI 734.3 151 734.9 152 735.5 153 736.2 154 736.8 15E; 737.4 156 738.1 157 738.7 158 739.3 159 740.0 16CI 740.6 161 741.2 162 741.9 163 742.5 164 743.1 16E5 743.8 166 744A 167 745.0 168 745.7 169 746.3 17CI 747.0 171 747.6 172 748.2 173 748.9 174 749.5 1755 750.1 176 750.8 177 751.4 178 752.0 179 752.7 18CI 753.3 181 753.9 182 754.6 183 755.2 184 755.8 18E5 756.5 186 757.1 187 757.7 188 758.4 189 759.0 19CI 759.6 191 760.3 192 760.9 193 761.6 194 762.2 1955 762.8 196 763.5 197 764.1 198 764.7 199 765.4 20CI 766.0 201 766.6 202 767.3 203 767.9 204 768.5 20E5 769.2 206 769.8 207 770.4 208 771.1 209 771.7 21CI 772.4 211 773.0 212 773.6 213 774.3 214 774.9 21 E5 775.5 216 776.2 217 776.8 218 777.4 219 778.1 22CI 778.7 221 779.3 222 780.0 223 780.6 224 781.2 2255 781.9 226 782.5 227 783.1 228 783.8 229 784.4 23CI 785.1 231 785.7 232 786.3 233 787.0 234 787.6 2355 788.2 236 788.9 237 789.5 238 790.1 239 790.8 24CI 791.4 241 792.0 242 792.7 243 793.3 244 793.9 2455 794.6 246 795.2 247 795.8 248 796.5 249 797.1 25CI 797.8 NODE COORD. NODE COORD. NODE COORD. NODE COORD. NODE COORD.

251 798.4 252 799.0 253 799.7 254 800.3 255 800.9 256 801.6 257 802.2 258 802.8 259 803.5 260 804.1 261 804.7 262 805.4 263 806.0 264 806.6 265 807.3 266 807.9 267 808.5 268 809.2 269 809.8 270 810.5 271 811.1 272 811.7 273 812.4 274 813.0 275 813.6 276 814.3 277 814.9 278 815.5 279 816.2 280 816.8 281 817.4 282. 818.1 283 818.7 284 819.3 285 820.0 286 820.6 287 821.2 288 821.9 289 822.5 290 823.1 291 823.8 292 824.4 293 825.1 294 825.7 295 826.3 296 827.0 297 827.6 298 828.2 299 828.9 300 829.5 301 830.1 302 830.8 303 831.4 304 832.0 305 832.7 306 833.3 307 833.9 308 834.6 309 835.2 310 835.9

311 836.5 312 837.1 313 837.8 314 838.4 315 839.0 316 839.7 317 840.3 318 840.9 319 841.6 320 842.2 321 842.8 322 843.5 323 844.1 324 844.7 325 845.4 326 846.0 327 846.6 328 847.3 329 847.9 330 848.6 331 849.2 332 849.8 333 850.5 334 851.1 335 851.7 336 852.4 337 853.0 338 853.6 339 854.3 340 854.9 341 855.5 342 856.2 343 856.8 344 857.4 345 858.1 346 858.7 347 859.3 348 860.0 349 860.6 350 861.3 351 861.9 352 862.5 353 863.2 354 863.8 355 864.4 356 865.1 357 865.7 358 866.3 359 867.0 360 867.6 361 868.2 362 868.9 363 869.5 364 870.1 365 870.8 366 871.4 367 872.0 368 872.7 369 873.3 370 874.0 371 874.6 372 875.2 373 875.9 374 876.5 375 877.1 NODE COORD. NODE COORD. NODE COORD. NODE COORD. NODE COORD.

376 877.8 377 878.4 378 879.0 379 879.7 380 880.3 381 880.9 382 881.6 383 882.2 384 882.8 385 883.5 386 884.1 387 884.7 388 885.4 389 886.0 390 886.6 391 887.3 392 887.9 393 888.6 394 889.2 395 889.8 396 890.5 397 891.1 398 891.7 399 892.4 400 893.0 401 893.6 402 894.3 403 894.9 404 895.5 405 896.2 406 903.4 407 911.0 408 918.6 409 926.3 410 933.9 411 941.5 412 949.1 413 956.7 414 964A 415 972.0 416 979.6 417 979.1 418 994.3 419 1009.6 420 1024.8 421 1040.1 422 1055.3 423 1070.5 424 1085.8 425 1101.0 426 1116.3 427 1131.5 428 1146.7 429 1162.0 430 1177.2 431 1192.5 432 1207.7 433 1222.9 434 1238.2 435 1253.4 436 1268.7 437 1283.9 438 1299.1 439 1314.4 440 1329.6 441 1344.9 442 1360.1 443 1375.3 444 1390.6 445 1405.8 446 1421.1 447 1436.3 448 1451.5 449 1466.8 450 1482.0 451 1497.3 452 1512.5 453 1527.7 454 1543.0 455 1558.2 456 1573.5 457 1588.7 458 1603.9 459 1619.2 460 1634.4 461 1649.7 462 1664.9 463 1680.1 464 1695.4 465 1710.6 466 1725.9 467 1741.1 468 1756.3 469 1771.6 470 1786.8 FACILITY DIMENSIONS FACILITY HEIGHT X-SECT. AREA VOL.OF FACILITY 1.787E.03 1.OOOE+04 1.787E+07 INITIAL CONCENTRATION AT EACH NODE FOR H-3

NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

1 0.OE+00 2 0.0E+00 3 0.OE+00 4 0.OE+00 5 0.OE+00 6 0.OE+00 7 0.OE+00 8 0.OE+00 9 0.OE+00 10 0.OE+00 11 0.0E+00 12 0.OE+00 13 0.0E+00 14 0.OE+00 15 0.OE+00 16 0.OE+00 17 0.OE+00 18 0.OE+00 19 0.OE+00 20 0.OE+00 21 0.OE+00 22 0.OE+00 23 0.OE+00 24 0.OE+00 25 0.OE+00 26 0.OE+00 27 0.0E+00 28 0.OE+00 29 0.OE+00 30 0.OE+00 31 0.OE+00 32 0.0E+00 33 0.OE+00 34 0.OE+00 35 0.OE+00 36 0.OE+00 37 0.OE+00 38 0.0E+00 39 0.OE+00 40 0.OE+00 41 0.OE+00 42 0.0E+00 43 0.OE+00 44 0.0E+00 45 0.OE+00 46 0.OE+00 47 0.OE+00 48 0.OE+00 49 0.OE+00 50 0.OE+00 51 0.OE+00 52 0.OE+00 53 0.OE+00 54 0.OE+00 55 0.OE+00 56 0.OE+00 57 0.0E+00 58 0.OE+00 59 0.OE+00 60 0.OE+00 61 8.6E-01 62 8.6E-01 63 8.9E-01 64 8.9E-01 65 9.1E-01 66 9.1E-01 67 1.0E+00 68 1.0E+00 69 9.3E-01 70 9.3E-01 71 5.4E-01 72 5.4E-01 73 3.6E-01 74 3.6E-01 75 3.E-01 76 3.1E-01 77 3.2E-01 78 3.2E-01 79 2.6E-01 80 2.6E-01 81 2.0E-01 82 2.0E-01 83 1.6E-01 84 1.6E-01 85 1.4E-01 86 1.4E-01 87 1.2E-01 88 1.2E-01 89 9.2E-02 90 9.2E-02 91 7.6E-02 92 7.6E-02 93 5.6E-02 94 5.6E-02 95 4.2E-02 96 4.2E-02 97 4.OE-02 98 4.0E-02 99 3.4E-02 100 3.4E-02 101 2.5E-02 102 2.5E-02 103 1.2E-02 104 1.2E-02 105 1.1E-02 106 1.1E-02 107 9.8E-03 108 9.8E-03 109 8AE403 110 8.4E-03 111 5.8E-03 112 5.8E-03 113 3.6E-03 114 3.6E-03 115 3.3E-03 116 3.3E-03 117 2.5E-03 118 2.5E-03 119 2.5E-03 120 2.5E-03 121 7.3E-04 122 7.3E-04 123 1.2E-03 124 1.2E-03 125 8.4E-04 INITIAL CONCENTRATION AT EACH NODE FOR H-3 NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

126 8.4E-04 127 1.1E-03 128 1.IE-03 129 4.7E-04 130 4.7E-04 131 3.3E-04 132 3.3E-04 133 4.4E-04 134 4.4E-04 135 4AE-04 136 4.4E-04 137 4.7E-04 138 4.7E-04 139 4.4E-04 140 4AE-04 141 6.5E-04 142 6.5E-04 143 5.lE-04 144 5.1 E-04 145 5.1 E-04 146 5.1E-04 147 4.4E-04 148 4.4E-04 149 5.4E-03 150 5.4E-03 151 5.8E-04 152 5.8E-04 153 5.lE-04 154 5.1 E-04 155 6.5E-04 156 6.5E-04 157 5.4E-04 158 5.4E-04 159 5.4E-04 160 5.4E-04 161 5.4E-04 162 5.4E-04 163 6.5E-04 164 6.5E-04 165 4.4E-04 166 4.4E-04 167 1.8E-04 168 1.8E-04 169 4.7E-03 170 4.7E-03 171 4.7E-04 172 4.7E-04 173 6.2E-04 174 6.2E-04 175 4.7E-04 176 4.7E-04 177 5.8E-04 178 5.8E-04 179 3.6E-04 180 3.6E-04 181 3.6E-04 182 3.6E-04 183 3.6E-04 184 3.6E-04 185 3.6E-04 186 3.6E-04 187 3.6E-04 188 3.6E-04 189 3.6E-04 190 3.6E-04 191 3.6E-04 192 3.6E-04 193 3.6E-04 194 3.6E-04 195 3.6E-04 196 3.6E-04 197 3.6E-04 198 3.6E-04 199 3.6E-04 200 3.6E-04 201 3.6E-04 202 3.6E-04 203 3.6E-04 204 3.6E-04 205 3.6E-04 206 3.6E-04 207 3.6E-04 208 3.6E-04 209 3.6E-04 210 3.6E-04

211 3.6E-04 212 3.6E-04 213 3.6E-04 214 3.6E-04 215 3.6E-04 216 3.6E-04 217 3.6E-04 218 3.6E-04 219 3.6E-04 220 3.6E-04 221 3.6E-04 222 3.6E-04 223 3.6E-04 224 3.6E-04 225 3.6E-04 226 3.6E-04 227 3.6E-04 228 3.6E-04 229 3.6E-04 230 3.6E-04 231 3.6E-04 232 3.6E-04 233 3.6E-04 234 3.6E-04 235 3.6E-04 236 3.6E-04 237 3.6E-04 238 3.6E-04 239 3.6E-04 240 3.6E-04 241 3.6E-04 242 3.6E-04 243 3.6E-04 244 3.6E-04 245 3.6E-04 246 3.6E-04 247 3.6E-04 248 3.6E-04 249 3.6E-04 250 3.6E-04 INITIAL CONCENTRATION AT EACH NODE FOR H-3 NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

251 3.6E-04 252 3.6E-04 253 3.6E-04 254 3.6E-04 255 3.6E-04 256 3.6E-04 257 3.6E-04 258 3.6E-04 259 3.6E-04 260 3.6E-04 261 3.6E-04 262 3.6E-04 263 3.6E-04 264 3.6E-04 265 3.6E-04 266 3.6E-04 267 3.6E-04 268 3.6E-04 269 3.6E-04 270 3.6E-04 271 3.6E-04 272 3.6E-04 273 3.6E-04 274 3.6E-04 275 3.6E-04 276 3.6E-04 277 3.6E-04 278 3.6E-04 279 3.6E-04 280 3.6E-04 281 3.6E-04 282 3.6E-04 283 3.6E-04 284 3.6E-04 285 3.6E-04 286 3.6E-04 287 3.6E-04 288 3.6E-04 289 3.6E-04 290 3.6E-04 291 3.6E-04 292 3.6E-04 293 3.6E-04 294 3.6E-04 295 3.6E-04 296 3.6E-04 297 3.6E-04 298 3.6E-04 299 3.6E-04 300 3.6E-04 301 3.6E-04 302 3.6 E-04 303 3.6E-04 304 3.6E-04 305 3.6E-04 306 3.6E-04 307 3.6E-04 308 3.6E-04 309 3.6E-04 310 3.6E-04 311 3.6E-04 312 3.6E-04 313 3.6E-04 314 3.6E-04 315 3.6E-04 316 3.6E-04 317 3.6E-04 318 3.6E-04 319 3.6E-04 320 3.6E-04 321 3.6E-04 322 3.6E-04 323 3.6E-04 324 3.6E-04 325 3.6E-04 326 3.6E-04 327 3.6E-04 328 3.6E-04 329 3.6E-04 330 3.6E-04 331 3.6E-04 332 3.6E-04 333 3.6E-04 334 3.6E-04 335 3.6 E-04 336 3.6E-04 337 3.6E-04 338 3.6E-04 339 3.6E-04 340 3.6E-04 341 3.6E-04 342 3.6E-04 343 3.6E-04 344 3.6E-04 345 3.6E-04 346 3.6E-04 347 3.6E-04 348 3.6E-04 349 3.6E-04 350 3.6E-04 351 3.6E-04 352 3.6E-04 353 3.6E-04 354 3.6E-04 355 3.6E-04 356 3.6E-04 357 3.6E-04 358 3.6E-04 359 3.6E-04 360 3.6E-04 361 3.6E-04 362 3.6E-04 363 3.6E-04 364 3.6E-04 365 3.6E-04 366 3.6E-04 367 3.6E-04 368 3.6E-04 369 3.6E-04 370 3.6E-04 371 3.6E-04 372 3.6E-04 373 3.6E-04 374 3.6E-04 375 3.6E-04 INITIAL CONCENTRATION AT EACH NODE FOR H-3 NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

376 3.6E-04 377 3.6E-04 378 3.6E-04 379 3.6E-04 380 3.6E-04 381 3.6E-04 382 3.6E-04 383 3.6E-04 384 3.6E-04 385 3.6E-04 386 3.6E-04 387 3.6E-04 388 3.6E-04 389 3.6E-04 390 3.6E-04

391 3.6E-04 392 3.6E-04 393 3.6E-04 394 3.6E-04 395 3.6E-04 396 3.6E-04 397 0.OE+00 398 O.0E+00 399 0.OE+00 400 0.OE+00 401 0.OE+00 402 0.OE+00 403 0.OE+00 404 0.OE+00 405 0.OE+00 406 0.OE+00 407 0.0E+00 408 0.0E+00 409 0.OE+00 410 0.OE+00 411 0.OE+00 412 0.0E+00 413 0.OE+00 414 0.OE+00 415 0.OE+00 416 0.OE+00 417 0.0E+00 418 0.OE+00 419 0.OE+00 420 0.OE+00 421 0.OE+00 422 0.OE+00 423 0.OE+00 424 0.OE+00 425 0.OE+00 426 0.OE+00 427 0.OE+00 428 0.OE+00 429 O.OE+00 430 0.OE+00 431 0.OE+00 432 0.OE+00 433 0.0E+00 434 0.OE+00 435 O.OE+00 436 0.OE+00 437 0.OE+00 438 0.OE+00 439 0.OE+00 440 0.OE+00 441 0.OE+00 442 0.OE+00 443 0.OE+00 444 0.OE+00 445 0.OE+00 446 0.OE+00 447 0.OE+00 448 0.0E+00 449 0.OE+00 450 0.OE+00 451 0.OE+00 452 0.OE+00 453 0.OE+00 454 0.OE+00 455 0.OE+00 456 0.OE+00 457 O.OE+00 458 0.OE+00 459 0.OE+00 460 0.OE+00 461 0.OE+00 462 0.OE+00 463 0.0E+00 464 0.OE+00 465 0.OE+00 466 0.OE+00 467 0.OE+00 468 0.OE+00 469 0.OE+00 470 0.OE+00 INITIAL CONCENTRATION AT EACH NODE FOR C-14 NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

I 0.OE+00 2 0.OE+00 3 0.OE+00 4 0.OE+00 5 0.OE+00 6 0.OE+00 7 0.OE+00 8 0.OE+00 9 0.OE+00 10 0.OE+00 11 0.OE+00 12 0.OE+00 13 0.OE+00 14 0.OE+00 15 0.OE+00 16 0.OE+00 17 0.OE+00 18 0.OE+00 19 0.OE+00 20 0.OE+00 21 0.OE+00 22 0.OE+00 23 0.OE+00 24 0.OE+00 25 0.OE+00 26 0.OE+00 27 0.OE+00 28 0.OE+00 29 0.OE+00 30 0.OE+00 31 0.OE+00 32 0.OE+00 33 0.OE+00 34 0.OE+00 35 0.OE+00 36 0.OE+00 37 0.OE+00 38 0.0E+00 39 0.OE+00 40 O.OE+00 41 0.OE+00 42 0.OE+00 43 0.OE+00 44 0.OE+00 45 0.OE+00 46 0.OE+00 47 0.OE+00 48 0.OE+00 49 0.OE+00 50 0.OE+00 51 0.OE+00 52 0.OE+00 53 0.OE+00 54 0.OE+00 55 0.OE+00 56 0.OE+00 57 0.OE+00 58 0.OE+00 59 0.OE+00 60 0.OE+00 61 8.6E-01 62 8.6E-01 63 8.9E-01 64 8.9E-01 65 9.1 E-01 66 9.1E-01 67 1.OE+00 68 1.0E+00 69 9.3E-01 70 9.3E-01 71 5.4E-01 72 5.4E-01 73 3.6E-01 74 3.6E-01 75 3.IE-01 76 3.1E-01 77 3.2E-01 78 3.2E-01 79 2.6E-01 80 2.6E-01 81 2.OE-01 82 2.0E-01 83 1.6E-01 84 1.6E-01 85 1.4E-01 86 1.4E-01 87 1.2E-01 88 1.2E-01 89 9.2E-02 90 9.2E-02 91 7.6E-02 92 7.6E-02 93 5.6E-02 94 5.6E-02 95 4.2E-02 96 4.2E-02 97 4.OE-02 98 4.OE-02 99 3.4E-02 100 3.4E-02 101 2.5E-02 102 2.5E-02 103 1.2E-02 104 1.2E-02 105 1.1 E-02 106 1.1E-02 107 9.8E-03 108 9.8E-03 109 8.4E-03 110 8.4E-03 111 5.8E-03 112 5.8E-03 113 3.6E-03 114 3.6E-03 115 3.3E-03 116 3.3E-03 117 2.5E-03 118 2.5E-03 119 2.5E-03 120 2.5E-03 121 7.3E-04 122 7.3E-04 123 1.2E-03 124 1.2E-03 125 8.4E-04

INITIAL CONCENTRATION AT EACH NODE FOR C-14 NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

126 8.4E-04 127 1.1E-03 128 1.1 E-03 129 4.7E-04 130 4.7E-04 131 3.3E-04 132 3.3E-04 133 4.4E-04 134 4.4E-04 135 4AE-04 136 4.4E-04 137 4.7E-04 138 4.7E-04 139 4.4E-04 140 4.4E-04 141 6.5E-04 142 6.5E-04 143 5.1E-04 144 5.1 E-04 145 5.1E-04 146 5.1E-04 147 4.4E-04 148 4.4E-04 149 5.4E-03 150 5.4E-03 151 5.8E-04 152 5.8E-04 153 5.1E-04 154 5.1 E-04 155 6.5E-04 156 6.5E-04 157 5.4E-04 158 5.4E-04 159 5.4E-04 160 5.4E-04 161 5.4E-04 162 5.4E-04 163 6.5E-04 164 6.5E-04 165 4.4E-04 166 4.4E-04 167 1.8E-04 168 1.8E-04 169 4.7E-03 170 4.7E-03 171 4.7E-04 172 4.7E-04 173 6.2E-04 174 6.2E-04 175 4.7E-04 176 4.7E-04 177 5.8E-04 178 5.8E-04 179 3.6E-04 180 3.6E-04 181 3.6E-04 182 3.6E-04 183 3.6E-04 184 3.6E-04 185 3.6E-04 186 3.6E-04 187 3.6E-04 188 3.6E-04 189 3.6E-04 190 3.6E-04 191 3.6E-04 192 3.6E-04 193 3.6E-04 194 3.6E-04 195 3.6E-04 196 3.6E-04 197 3.6E-04 198 3.6E-04 199 3.6E-04 200 3.6E-04 201 3.6E-04 202 3.6E-04 203 3.6E-04 204 3.6E-04 205 3.6E-04 206 3.6E-04 207 3.6E-04 208 3.6E-04 209 3.6E-04 210 3.6E-04 211 3.6E-04 212 3.6E-04 213 3.6E-04 214 3.6E-04 215 3.6E-04 216 3.6E-04 217 3.6E-04 218 3.6E-04 219 3.6E-04 220 3.6E-04 221 3.6E-04 222 3.6E-04 223 3.6E-04 224 3.6E-04 225 3.6E-04 226 3.6E-04 227 3.6E-04 228 3.6E-04 229 3.6E-04 230 3.6E-04 231 3.6E-04 232 3.6E-04 233 3.6E-04 234 3.6E-04 235 3.6E-04 236 3.6E-04 237 3.6E-04 238 3.6E-04 239 3.6E-04 240 3.6E-04 241 3.6E-04 242 3.6E-04 243 3.6E-04 244 3.6E-04 245 3.6E-04 246 3.6E-04 247 3.6E-04 248 3.6E-04 249 3.6E-04 250 3.6E-04 INITIAL CONCENTRATION AT EACH NODE FORC-14 NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

251 3.6E-04 252 3.6E-04 253 3.6E-04 254 3.6E-04 255 3.6E-04 256 3.6E-04 257 3.6E-04 258 3.6E-04 259 3.6E-04 260 3.6E-04 261 3.6E-04 262 3.6E-04 263 3.6E-04 264 3.6E-04 265 3.6E-04 266 3.6E-04 267 3.6E-04 268 3.6E-04 269 3.6E-04 270 3.6E-04 271 3.6E-04 272 3.6E-04 273 3.6E-04 274 3.6E-04 275 3.6E-04 276 3.6E-04 277 3.6E-04 278 3.6E-04 279 3.6E-04 280 3.6E-04 281 3.6E-04 282 3.6E-04 283 3.6E-04 284 3.6E-04 285 3.6E-04 286 3.6E-04 287 3.6E-04 288 3.6E-04 289 3.6E-04 290 3.6E-04 291 3.6E-04 292 3.6E-04 293 3.6E-04 294 3.6E-04 295 3.6E-04 296 3.6E-04 297 3.6E-04 298 3.6E-04 299 3.6E-04 300 3.6E-04 301 3.6E-04 302 3.6E-04 303 3.6E-04 304 3.6E-04 305 3.6E-04 306 3.6E-04 307 3.6E-04 308 3.6E-04 309 3.6E-04 310 3.6E-04 311 3.6E-04 312 3.6E-04 313 3.6E-04 314 3.6E-04 315 3.6E-04

316 3.6E-04 317 3.6E-04 318 3.6E-04 319 3.6E-04 320 3.6E-04 321 3.6E-04 322 3.6E-04 323 3.6E-04 324 3.6E-04 325 3.6E-04 326 3.6E-04 327 3.6E-04 328 3.6E-04 329 3.6E-04 330 3.6E-04 331 3.6E-04 332 3.6E-04 333 3.6E-04 334 3.6E-04 335 3.6E-04 336 3.6E-04 337 3.6E-04 338 3.6E-04 339 3.6E-04 340 3.6E-04 341 3.6E-04 342 3.6E-04 343 3.6E-04 344 3.6E-04 345 3.6E-04 346 3.6E-04 347 3.6E-04 348 3.6E-04 349 3.6E-04 350 3.6E-04 351 3.6E-04 352 3.6E-04 353 3.6E-04 354 3.6E-04 355 3.6E-04 356 3.6E-04 357 3.6E-04 358 3.6E-04 359 3.6E-04 360 3.6E-04 361 3.6E-04 362 3.6E-04 363 3.6E-04 364 3.6E-04 365 3.6E-04 366 3.6E-04 367 3.6E-04 368 3.6E-04 369 3.6E-04 370 3.6E-04 371 3.6E-04 372 3.6E-04 373 3.6E-04 374 3.6E-04 375 3.6E-04 INITIAL CONCENTRATION AT EACH NODE FOR C-14 NODE CONCENTR. NODE I CONCENTR. NODE CONCENTR. NODE CONCENTR. NODE CONCENTR.

376 3.6E-04 377 3.6E-04 378 3.6E-04 379 3.6E-04 380 3.6E-04 381 3.6E-04 382 3.6E-04 383 3.6E-04 384 3.6E-04 385 3.6E-04 386 3.6E-04 387 3.6E-04 388 3.6E-04 389 3.6E-04 390 3.6E-04 391 3.6E-04 392 3.6E-04 393 3.6E-04 394 3.6E-04 395 3.6E-04 396 3.6E-04 397 O.OE+00 398 0.OE+00 399 0.OE+00 400 0.OE+00 401 0.OE+00 402 0.OE+00 403 0.OE+00 404 0.OE+00 405 0.OE+00 406 0.OE+00 407 0.OE+00 408 0.OE+00 409 0.OE+00 410 0.OE+00 411 O.OE+00 412 0.OE+00 413 0.OE+00 414 0.OE+00 415 0.OE+00 416 0.OE+00 417 0.OE+00 418 0.OE+00 419 0.OE+00 420 0.OE+00 421 0.OE+00 422 0.OE+00 423 0.OE+00 424 0.OE+00 425 0.OE+00 426 0.OE+00 427 0.OE+00 428 0.OE+00 429 0.OE+00 430 0.OE+00 431 0.OE+00 432 0.OE+00 433 0.OE+00 434 0.OE+00 435 0.OE+00 436 O.OE+00 437 0.OE+00 438 0.OE+00 439 0.OE+00 440 0.OE+00 441 O.OE+00 442 0.OE+00 443 0.OE+00 444 0.OE+00 445 0.OE+00 446 0.OE+00 447 0.OE+00 448 0.OE+00 449 0.OE+00 450 0.0E+00 451 0.OE+00 452 0.OE+00 453 0.OE+00 454 0.OE+00 455 0.OE+00 456 O.OE+00 457 0.OE.00 458 0.OE+00 459 O.OE+00 460 0.OE+00 461 0.OE+00 462 0.OE+00 463 0.OE+00 464 0.OE+00 465 0.OE+00 466 0.OE+00 467 0.OE+00 468 0.OE+00 469 0.OE+00 470 0.OE+00

- BOUNDARY CONDITIONS FOR H-3 **

FLAGS FOR BOUNDARY CONDITIONS:

TOP BOUNDARY: FLAG SPECIFIED IS 1: Concentration BOTTOM BOUNDARY: FLAG SPECIFIED IS 1: Concentration

NO. OF BOUND. COND. DATA POINTS IN EACH PROFILE FOR H-3 : 2 TOP BOUNDARY CONDITION: BOTTOM BOUNDARY CONDITION:

TIME (YRS) VALUE TIME (YRS) VALUE 0.000E+00 0.OOOE+00 0.000E+00 O.OOOE+00 1.OOOE+03 0.000E+00 1.000E+03 O.OOOE+00

- - - BOUNDARY CONDITIONS FOR C-14 **

FLAGS FOR BOUNDARY CONDITIONS:

TOP BOUNDARY: FLAG SPECIFIED IS 1: Concentration BOTTOM BOUNDARY: FLAG SPECIFIED IS 1: Concentration NO. OF BOUND. COND. DATA POINTS IN EACH PROFILE FOR C-14 : 2 TOP BOUNDARY CONDITION: BOTTOM BOUNDARY CONDITION:

TIME (YRS) VALUE TIME (YRS) VALUE 0.OOOE+00 0.OOOE+00 O.OOOE+00 0.000E+00 1.OOOE+03 O.OOOE+00 1.OOOE+03 O.000E+00 WATER FLOW PARAMETERS DARCY VELOCITY TABLE (CM/SEC):

TIME (YRS) VDAR 0.OOOE+00 0.OOOE+00 1.000E+03 0.OOOE+00 MOISTURE CONTENT NODE THETA NODE THETA NODE THETA NODE THETA NODE THETA 1 0.24 2 0.24 3 0.24 4 0.24 5 0.24 6 0.24 7 0.24 8 0.24 9 0.24 10 0.24 11 0.24 12 0.24 13 0.24 14 0.24 15 0.24 16 0.24 17 0.24 18 0.24 19 0.24 20 0.24 21 0.24 22 0.24 23 0.24 24 0.24 25 0.24 26 0.24 27 0.24 28 0.24 29 0.24 30 0.24 31 0.24 32 0.24 33 0.24 34 0.24 35 0.24 36 0.24 37 0.24 38 0.24 39 0.24 40 0.24 41 0.24 42 0.24 43 0.24 44 0.24 45 0.24 46 0.24 47 0.24 48 0.24 49 0.24 50 0.24

51 0.24 52 0.24 53 0.24 54 0.24 55 0.24 56 0.24 57 0.24 58 0.24 59 0.24 60 0.24 61 0.24 62 0.24 63 0.24 64 0.24 65 0.24 66 0.24 67 0.24 68 0.24 69 0.24 70 0.24 71 0.24 72 0.24 73 0.24 74 0.24 75 0.24 76 0.24 77 0.24 78 0.24 79 0.24 80 0.24 81 0.24 82 0.24 83 0.24 84 0.24 85 0.24 86 0.24 87 0.24 88 0.24 89 0.24 90 0.24 91 0.24 92 0.24 93 0.24 94 0.24 95 0.24 96 0.24 97 0.24 98 0.24 99 0.24 100 0.24 101 0.24 102 0.24 103 0.24 104 0.24 105 0.24 106 0.24 107 0.24 108 0.24 109 0.24 110 0.24 111 0.24 112 0.24 113 0.24 114 0.24 115 0.24 116 0.24 117 0.24 118 0.24 119 0.24 120 0.24 121 0.24 122 0.24 123 0.24 124 0.24 125 0.24 MOISTURE CONTENT NODE THETA NODE THETA NODE THETA NODE THETA NODE THETA 126 0.24 127 0.24 128 0.24 129 0.24 130 0.24 131 0.24 132 0.24 133 0.24 134 0.24 135 0.24 136 0.24 137 0.24 138 0.24 139 0.24 140 0.24 141 0.24 142 0.24 143 0.24 144 0.24 145 0.24 146 0.24 147 0.24 148 0.24 149 0.24 150 0.24 151 0.24 152 0.24 153 0.24 154 0.24 155 0.24 156 0.24 157 0.24 158 0.24 159 0.24 160 0.24 161 0.24 162 0.24 163 0.24 164 0.24 165 0.24 166 0.24 167 0.24 168 0.24 169 0.24 170 0.24 171 0.24 172 0.24 173 0.24 174 0.24 175 0.24 176 0.24 177 0.24 178 0.24 179 0.24 180 0.24 181 0.24 182 0.24 183 0.24 184 0.24 185 0.24 186 0.24 187 0.24 188 0.24 189 0.24 190 0.24 191 0.24 192 0.24 193 0.24 194 0.24 195 0.24 196 0.24 197 0.24 198 0.24 199 0.24 200 0.24 201 0.24 202 0.24 203 0.24 204 0.24 205 0.24 206 0.24 207 0.24 208 0.24 209 0.24 210 0.24 211 0.24 212 0.24 213 0.24 214 0.24 215 0.24 216 0.24 217 0.24 218 0.24 219 0.24 220 0.24 221 0.24 222 0.24 223 0.24 224 0.24 225 0.24 226 0.24 227 0.24 228 0.24 229 0.24 230 0.24 231 0.24 232 0.24 233 0.24 234 0.24 235 0.24 236 0.24 237 0.24 238 0.24 239 0.24 240 0.24 241 0.24 242 0.24 243 0.24 244 0.24 245 0.24 246 0.24 247 0.24 248 0.24 249 0.24 250 0.24 MOISTURE CONTENT NODE THETA NODE THETA NODE THETA NODE THETA NODE THETA 251 0.24 252 0.24 253 0.24 254 0.24 255 0.24 256 0.24 257 0.24 258 0.24 259 0.24 260 0.24

261 0.24 262 0.24 263 0.24 264 0.24 265 0.24 266 0.24 267 0.24 268 0.24 269 0.24 270 0.24 271 0.24 272 0.24 273 0.24 274 0.24 275 0.24 276 0.24 277 0.24 278 0.24 279 0.24 280 0.24 281 0.24 282 0.24 283 0.24 284 0.24 285 0.24 286 0.24 287 0.24 288 0.24 289 0.24 290 0.24 291 0.24 292 0.24 293 0.24 294 0.24 295 0.24 296 0.24 297 0.24 298 0.24 299 0.24 300 0.24 301 0.24 302 0.24 303 0.24 304 0.24 305 0.24 306 0.24 307 0.24 308 0.24 309 0.24 310 0.24 311 0.24 312 0.24 313 0.24 314 0.24 315 0.24 316 0.24 317 0.24 318 0.24 319 0.24 320 0.24 321 0.24 322 0.24 323 0.24 324 0.24 325 0.24 326 0.24 327 0.24 328 0.24 329 0.24 330 0.24 331 0.24 332 0.24 333 0.24 334 0.24 335 0.24 336 0.24 337 0.24 338 0.24 339 0.24 340 0.24 341 0.24 342 0.24 343 0.24 344 0.24 345 0.24 346 0.24 347 0.24 348 0.24 349 0.24 350 0.24 351 0.24 352 0.24 353 0.24 354 0.24 355 0.24 356 0.24 357 0.24 358 0.24 359 0.24 360 0.24 361 0.24 362 0.24 363 0.24 364 0.24 365 0.24 366 0.24 367 0.24 368 0.24 369 0.24 370 0.24 371 0.24 372 0.24 373 0.24 374 0.24 375 0.24 MOISTURE CONTENT NODE THETA NODE THETA NODE THETA NODE THETA NODE THETA 376 0.24 377 0.24 378 0.24 379 0.24 380 0.24 381 0.24 382 0.24 383 0.24 384 0.24 385 0.24 386 0.24 387 0.24 388 0.24 389 0.24 390 0.24 391 0.24 392 0.24 393 0.24 394 0.24 395 0.24 396 0.24 397 0.24 398 0.24 399 0.24 400 0.24 401 0.24 402 0.24 403 0.24 404 0.24 405 0.24 406 0.24 407 0.24 408 0.24 409 0.24 410 0.24 411 0.24 412 0.24 413 0.24 414 0.24 415 0.24 416 0.24 417 0.24 418 0.24 419 0.24 420 0.24 421 0.24 422 0.24 423 0.24 424 0.24 425 0.24 426 0.24 427 0.24 428 0.24 429 0.24 430 0.24 431 0.24 432 0.24 433 0.24 434 0.24 435 0.24 436 0.24 437 0.24 438 0.24 439 0.24 440 0.24 441 0.24 442 0.24 443 0.24 444 0.24 445 0.24 446 0.24 447 0.24 448 0.24 449 0.24 450 0.24 451 0.24 452 0.24 453 0.24 454 0.24 455 0.24 456 0.24 457 0.24 458 0.24 459 0.24 460 0.24 461 0.24 462 0.24 463 0.24 464 0.24 465 0.24 466 0.24 467 0.24 468 0.24 469 0.24 470 0.24

- - - EXTERNAL SOURCE PARAMETERS FOR H-3 ****

NO. OF SOURCE/SINK ELEMENTS ........... 0 NO. OF SOURCE PROFILES ............. 1 NO. OF DATA POINTS IN EACH SOURCE PROFILE.... 2

- - - EXTERNAL SOURCE PARAMETERS FOR C-14 ****

NO. OF SOURCE/SINK ELEMENTS ........... 0 NO. OF SOURCE PROFILES ............. I NO. OF DATA POINTS IN EACH SOURCE PROFILE.... 2 COMPLETION OF INPUT ROUTINE BEGINNING OF CALCULATION H-3 Concentrations at time =1.OOOE+00 ,(Deft =1.000E+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.16E+04 Mass sorbed = O.OOE+00 Total Mass = 2.16E+04

1 1.3109E-25 5.6257E-25 1.5752E-24 3.8123E-24 9.0129E-24 6 2.1220E-23 4.9921E-23 1.1743E-22 2.7622E-22 6.4972E-22 11 1.5283E-21 3.5949E-21 8.4559E-21 1.9890E-20 4.6786E-20 16 1.1005E-19 2.5886E-19 6.0889E-19 1A322E-18 3.3689E-18 21 7.9245E-18 1.8640E-17 4.3845E-1 7 1.0313E-16 2.4259E-16 26 5.7063E-16 1.3422E-15 3.1572E-1 5 7.4265E-15 1.7469E-14 31 4.1090E-14 9.6652E-14 2.2735E-1 3 5.3477E-13 1.2579E-12 36 2.9588E-12 6.9598E-12 1.6371E-11 3.8508E-11 9.0579E-1 1 41 1.4318E-10 2.2350E-10 3.4726E-10 5.3850E-10 8.3440E-10 46 1.2924E-09 2.0017E-09 3.0999E-09 4.8005E-09 7.4341 E-09 51 7.7119E-09 8.0067E-09 8.3124E-09 8.6292E-09 8.9577E-09 56 9.2983E-09 9.6515E-09 1.0805E-08 2.8983E-01 4.1089E-01 61 5.7244E-01 6.7436E-01 7.4165E-41 7.8486E-01 8.1456E-01 66 8.3266E-01 8.4359E-01 8.2920E-01 7.8597E-01 7.1871E-01 71 6.1092E-01 5.2702E-01 4.4640E-01 3.9164E-01 3.4929E-01 76 3.2138E-01 3.0104E-01 2.8083E-01 2.5582E-01 2.3351 E-01 81 2.0844E-01 1.8854E-01 1.6893E-01 1.5450E-01 1.4171 E-01 86 1.3054E-01 1.1825E-01 1.0765E-01 9.6124E-02 8.6845E-02 91 7.7534E-02 6.9534E-02 6.0881 E-02 5.4175E-02 4.7772E-02 96 4.3306E-02 3.9681 E-02 3.6429E-02 3.2752E-02 2.9267E-02 101 2.5118E-02 2.1396E-02 1.7189E-02 1.4499E-02 1.2668E-02 106 1.1330E-02 1.0158E-02 9.2003E-03 8.2227E-03 7.3225E-03 111 6.2790E-03 5.4265E-03 4.5558E-03 3.9595E-03 3.4912E-03 116 3.1204E-03 2.7561E-03 2.4776E-03 2.2165E-03 1.9089E-03 121 1.4792E-03 1.2437E-03 1.1446E-03 1.0565E-03 9.5775E-04 126 8.9997E-04 8.6902E-04 7.8980E-04 6.4289E-04 5.4408E-04 131 4.6912E-04 4.3338E-04 4.2807E-04 4.2659E-04 4.2856E-04 136 4.3447E-04 4.4576E-04 4.5678E-04 4.7023E-04 4.9785E-04 141 5.4640E-04 5.7722E-04 5.9784E-04 6.4708E-04 7.3701 E-04 146 8.8970E-04 1.1426E-03 1.5747E-03 2.2919E-03 2.3061 E-03 151 1.6209E-03 1.1985E-03 9.3525E-04 7.8337E-04 7.0563E-04 156 6.4921E-04 6.0028E-04 5.7212E-04 5.5783E-04 5.5390E-04 161 5.5936E-04 5.7556E-04 6.0646E-04 6.3436E-04 6.6609E-04 166 7.6004E-04 9.3927E-04 1.3068E-03 1.9528E-03 1.9814E-03 171 1.3996E-03 1.0516E-03 8.5187E-04 7.1784E-04 6.1655E-04 176 5.5690E-04 5.2424E-04 4.8527E-04 4.3042E-04 3.9684E-04 181 3.7627E-04 3.6367E-04 3.5596E-04 3.5124E-04 3.4834E-04 186 3.4657E-04 3.4549E-04 3.4482E-04 3.4442E-04 3.4417E-04 191 3.4402E-04 3.4392E-04 3.4386E-04 3.4383E-04 3.4381E-04 196 3.4380E-04 3.4379E-04 3.4378E-04 3.4378E-04 3.4378E-04 201 3.4378E-04 3.4378E-04 3A377E-04 3.4377E-04 3.4377E-04 206 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 211 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 216 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 221 3.4377E-04 3.4377E-04 3.4377E-04 3A377E-04 3.4377E-04 226 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 231 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 236 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 241 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3A377E-04 246 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04

H-3 Concentrations at time =1.000E+00 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 256 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 261 3.4377E-04 3A377E-04 3.4377E-04 3.4377E-04 3.4377E-04 266 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 271 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 276 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 281 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 286 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 291 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 296 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 301 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 306 3A377E-04 3.4377E-04 3.4377E-04 3A377E-04 3.4377E-04 311 3A377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 316 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 321 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 326 3.4377E-04 3A377E-04 3.4377E-04 3.4377E-04 3.4377E-04 331 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3A377E-04 336 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 341 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 346 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 351 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 356 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 361 3.4377E-04 3.4377E-04 3A377E-04 3.4377E-04 3.4377E-04 366 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 371 3.4377E-04 3.4377E-04 3.4377E-04 3.4377E-04 3.4376E-04 376 3.4376E-04 3.4375E-04 3.4373E-04 3.4370E-04 3.4365E-04 381 3.4357E-04 3.4345E-04 3.4324E-04 3.4290E-04 3.4235E-04 386 3.4145E-04 3.3999E-04 3.3759E-04 3.3367E-04 3.2728E-04 391 3.1683E-04 2.9978E-04 2.7193E-04 2.2646E-04 1.5220E-04 396 3.0925E-05 2.8758E-05 2.7708E-05 2.6695E-05 2.5718E-05 401 2.4776E-05 2.3867E-05 2.2990E-05 2.2145E-05 2.1329E-05 406 1.4075E-05 9.0890E-06 5.8691 E-06 3.7898E-06 2.4470E-06 411 1.5797E-06 1.0195E-06 6.5735E-07 4.2297E-07 2.7078E-07 416 1.7122E-07 1.7673E-07 7.5135E-08 3.1942E-08 1.3580E-08 421 5.7731 E-09 2A543E-09 1.0434E-09 4.4359E-10 1.8858E-10 426 8.0173E-1 I 3.4084E-1 I 1.4490E-1 I 6.1603E-12 2.6189E-12 431 1.1134E-12 4.7334E-13 2.0123E-13 8.5549E-14 3.6370E-14 436 1.5462E-14 6.5734E-15 2.7945E-15 1.1880E-15 5.0508E-16 441 2.1472E-16 9.1286E-17 3.8809E-17 1.6499E-17 7.0141E-18 446 2.9819E-18 1.2677E-18 5.3895E-19 2.2912E-19 9.7407E-20 451 4.1411E-20 1.7605E-20 7.4845E-21 3.1819E-21 1.3527E-21 456 5.7509E-22 2.4449E-22 1.0394E-22 4.4188E-23 1.8786E-23 461 7.9864E-24 3.3953E-24 1.4434E-24 6.1363E-25 2.6083E-25

466 1.1079E-25 4.6861E-26 1.9362E-26 6.9151E-27 1.6114E-27 C-14 Concentrations at time =1.OOOE+00 ,(Det =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.28E+04 Mass sorbed = 0.OOE+00 Total Mass = 2.28E+04 1 8.4029E-60 5.6805E-59 5.3946E-58 4.9929E-57 4.6197E-56 6 4.2744E-55 3.9549E-54 3.6593E-53 3.3857E-52 3.1327E-51 11 2.8985E-50 2.6818E-49 2.4814E-48 2.2959E-47 2.1243E-46 16 1.9655E-45 1.8186E-44 1.6826E-43 1.5569E-42 1.4405E-41 21 1.3328E-40 1.2332E-39 1.1410E-38 1.0557E-37 9.7681 E-37 26 9.0380E-36 8.3624E-35 7.7373E-34 7.1590E-33 6.6239E-32 31 6.1287E-31 5.6706E-30 5.2468E-29 4.8546E-28 4.4917E-27 36 4.1560E-26 3.8453E-25 3.5579E-24 3.2919E-23 3.0459E-22 41 1.2844E-21 4.6284E-21 1.6489E-20 5.8693E-20 2.0890E-19 46 7.4352E-19 2.6463E-18 9.4187E-18 3.3523E-17 1.1931 E-16 51 1.3595E-16 1.5471 E-16 1.7545E-16 1.9843E-16 2.2394E-16 56 2.5231 E-1 6 2.8391 E-16 3.9692E-16 3.1556E-09 6.7967E-05 61 8.6112E-01 8.6119E-01 8.8696E-01 8.8697E-01 9.1020E-01 66 9.1021 E-01 9.9987E-01 9.9987E-01 9.3344E-01 9.3341 E-01 71 5.4245E-01 5.4240E-01 3.6017E-01 3.6016E-01 3.0679E-01 76 3.0679E-01 3.1732E-01 3.1731E-01 2.5851 E-01 2.5850E-01 81 1.9787E-01 1.9787E-01 1.5612E-01 1.5612E-01 I A269E-01 86 1.4268E-01 1.1763E-01 1.1763E-01 9.1857E-02 9.1854E-02 91 7.6245E-02 7.6242E-02 5.5913E-02 5.5911 E-02 4.2116E-02 96 4.2115E-02 4.0300E-02 4.0300E-02 3.3765E-02 3.3764E-02 101 2.4689E-02 2.4687E-02 1.1619E-02 1.1618E-02 1.1255E-02 106 1.1255E-02 9.8028E-03 9.8026E-03 8.3505E-03 8.3502E-03 111 5.8092E-03 5.8088E-03 3.6307E-03 3.6305E-03 3.2675E-03 116 3.2674E-03 2.5414E-03 2.5414E-03 2.5414E-03 2.5413E-03 121 7.2625E-04 7.2615E-04 1.1617E-03 1.1617E-03 8.3502E-04 126 8.3502E-04 1.1254E-03 1.1254E-03 4.7199E-04 4.7193E-04 131 3.2667E-04 3.2667E-04 4.3564E-04 4.3565E-04 4.3565E-04 136 4.3565E-04 4.7194E-04 4.7194E-04 4.3565E-04 4.3566E-04 141 6.5340E-04 6.5341 E-04 5.0825E-04 5.0824E-04 5.0824E-04 146 5.0823E-04 4.3565E-04 4.3604E-04 5.4455E-03 5.4456E-03 151 5.8121 E-04 5.8082E-04 5.0824E-04 5.0825E-04 6.5341 E-04 156 6.5341 E-04 5.4454E-04 5.4453E-04 5.4453E-04 5.4453E-04 161 5.4453E-04 5.4454E-04 6.5341 E-04 6.5340E-04 4.3566E-04 166 4.3563E-04 1.8150E-04 1.8183E-04 4.7195E-03 4.7195E-03 171 4.7228E-04 4.7195E-04 6.1711E-04 6.1711E-04 4.7195E-04 176 4.7195E-04 5.8082E-04 5.8081 E-04 3.6307E-04 3.6306E-04 181 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04

186 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 191 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 196 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 201 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 206 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 211 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 216 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 221 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 226 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 231 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 236 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 241 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 246 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 C-14 Concentrations at time =1.OOOE+00 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 256 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 261 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 266 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 271 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 276 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 281 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 286 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 291 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 296 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 301 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 306 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 311 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 316 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 321 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 326 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 331 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 336 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 341 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 346 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 351 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 356 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 361 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 366 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 371 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 376 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 381 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 386 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 391 3.6306E-04 3.6306E-04 3.6306E-04 3.6306E-04 3.6303E-04 396 4.1647E-05 3.3432E-05 2.9752E-05 2.6452E-05 2.3490E-05

401 2.0828E-05 1.8432E-05 1.6272E-05 1.4319E-05 1.2550E-05 406 3.7116E-06 1.0428E-06 2.9299E-07 8.2320E-08 2.3129E-08 411 6.4983E-09 1.8258E-09 5.1293E-10 1.4393E-10 3.9802E-1 1 416 8.9121E-12 1.0436E-11 1.1279E-12 1.2191 E-13 1.3175E-14 421 1 A240E-15 1.5390E-16 1.6634E-17 1.7977E-18 1.9430E-19 426 2.0999E-20 2.2696E-21 2.4529E-22 2.6511 E-23 2.8653E-24 431 3.0967E-25 3.3469E-26 3.6173E-27 3.9095E-28 4.2254E-29 436 4.5667E-30 4.9357E-31 5.3344E-32 5.7654E-33 6.2311 E-34 441 6.7345E-35 7.2786E-36 7.8666E-37 8.5021 E-38 9.11890E-39 446 9.9313E-40 1.0734E-40 1.1601E-41 1.2538E-42 1.3551 E-43 451 1.4646E-44 1.5829E-45 1.7108E-46 1.8490E-47 1.9983E-48 456 2.1598E-49 2.3343E-50 2.5228E-51 2.7266E-52 2.9469E-53 461 3.1850E-54 3.4423E-55 3.7204E-56 4.0209E-57 4.3458E-58 466 4.6969E-59 5.0763E-60 5.4847E-61 5.7754E-62 8.5432E-63 H-3 Concentrations at time =7.OOOE+01 ,(Deft =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 4.96E+02 Mass sorbed = O.OOE+00 Total Mass = 4.96E+02 I 2.2983E-13 9.2436E-13 1.9043E-1 2 2.9942E-12 4.2545E-12 6 5.7522E-12 7.5633E-12 9.7751 E-12 1.2489E-1 I 1.5823E-1 1 11 1.9914E-1 I 2.4924E-1I 3.1037E-1 I 3.8468E-1 I 4.7465E-1 I 16 5.8308E-1 1 7.1318E-1 1 8.6855E-1 1 1.0532E-10 1.2717E-10 21 1.5289E-10 1.8301 E-10 2.1814E-10 2.5888E-10 3.0590E-1 0 26 3.5992E-10 4.2164E-10 4.9182E-10 5.7122E-10 6.6058E-110 31 7.6065E-10 8.7215E-10 9.9572E-10 1.1320E-09 1.2815E-09 36 1.4446E-09 1.6218E-09 1.8131 E-09 2.0187E-09 2.2385E-09 41 2.3539E-09 2.4724E-09 2.5943E-09 2.7196E-09 2.8481 E-09 46 2.9797E-09 3.1144E-09 3.2520E-09 3.3924E-09 3.5356E-09 51 3.5474E-09 3.5594E-09 3.5715E-09 3.5836E-09 3.5957E-09 56 3.6078E-09 3.6200E-09 3.6579E-09 9.1380E-03 9.1181 E-03 61 9.0965E-03 9.0634E-03 9.0188E-03 8.9631 E-03 8.8963E-03 66 8.8188E-03 8.7309E-03 8.6328E-03 8.5249E-03 8.4077E-03 71 8.2816E-03 8.1470E-03 8.0045E-03 7.8544E-03 7.6975E-03 76 7.5341 E-03 7.3649E-03 7.1904E-03 7.0112E-03 6.8278E-03 81 6.6409E-03 6.4511 E-03 6.2588E-03 6.0646E-03 5.8692E-03 86 5.6729E-03 5.4765E-03 5.2803E-03 5.0848E-03 4.8906E-03 91 4.6979E-03 4.5074E-03 4.3193E-03 4.1340E-03 3.9518E-03 96 3.7732E-03 3.5982E-03 3.4273E-03 3.2606E-03 3.0983E-03 101 2.9406E-03 2.7877E-03 2.6396E-03 2.4964E-03 2.3583E-03 106 2.2253E-03 2.0974E-03 1.9746E-03 1.8569E-03 1.7443E-03 111 1.6366E-03 1.5340E-03 1.4362E-03 1.3432E-03 1.2548E-03 116 1.1711E-03 1.0918E-03 1.0168E-03 9.4603E-04 8.7931 E-04

121 8.1649E-04 7.5743E-04 7.0198E-04 6.5000E-04 6.0133E-04 126 5.5583E-04 5.1333E-04 4.7371 E-04 4.3680E-04 4.0247E-04 131 3.7058E-04 3.4099E-04 3.1358E-04 2.8820E-04 2.6475E-04 136 2.4309E-04 2.2313E-04 2.0474E-04 1.8782E-04 1.7228E-04 141 1.5801E-04 1.4493E-04 1.3295E-04 1.2199E-04 1.1197E-04 146 1.0283E-04 9.4492E-05 8.6895E-05 7.9980E-05 7.3691 E-05 151 6.7976E-05 6.2786E-05 5.8078E-05 5.3809E-05 4.9941 E-05 156 4.6437E-05 4.3264E-05 4.0393E-05 3.7795E-05 3.5444E-05 161 3.3316E-05 3.1390E-05 2.9646E-05 2.8066E-05 2.6633E-05 166 2.5333E-05 2.4151 E-05 2.3075E-05 2.2095E-05 2.1200E-05 171 2.0381 E-05 1.9630E-05 1.8940E-05 1.8304E-05 1.7716E-05 176 1.7171 E-05 1.6664E-05 1.6192E-05 1.5751E-05 1.5337E-05 181 1.4948E-05 1.4581 E-05 1.4235E-05 1.3906E-05 1.3594E-05 186 1.3298E-05 1.3015E-05 1.2746E-05 1.2489E-05 1.2242E-05 191 1.2007E-05 1.1781E-05 1.1565E-05 1.1359E-05 1.1161 E-05 196 1.0971 E-05 1.0790E-05 1.0616E-05 1.0450E-05 1.0292E-05 201 1.0140E-05 9.9962E-06 9.8590E-06 9.7284E-06 9.6044E-06 206 9.4867E-06 9.3753E-06 9.2698E-06 9.1701E-06 9.0761 E-06 211 8.9875E-06 8.9042E-06 8.8260E-06 8.7526E-06 8.6839E-06 216 8.6197E-06 8.5598E-06 8.5040E-06 8.4520E-06 8.4038E-06 221 8.3591 E-06 8.3177E-06 8.2795E-06 8.2442E-06 8.2117E-06 226 8.1818E-06 8.1543E-06 8.1292E-06 8.1061E-06 8.0851 E-06 231 8.0659E-06 8.0484E-06 8.0325E-06 8.0181 E-06 8.0050E-06 236 7.9932E-06 7.9825E-06 7.9729E-06 7.9642E-06 7.9564E-06 241 7.9494E-06 7.9431 E-06 7.9375E-06 7.9324E-06 7.9280E-06 246 7.9240E-06 7.9204E-06 7.9173E-06 7.9145E-06 7.9120E-06 H-3 Concentrations at time =7.OOOE+01 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 7.9098E-06 7.9079E-06 7.9061 E-06 7.9046E-06 7.9033E-06 256 7.9022E-06 7.9012E-06 7.9003E-06 7.8995E-06 7.8988E-06 261 7.8982E-06 7.8977E-06 7.8973E-06 7.8969E-06 7.8965E-06 266 7.8963E-06 7.8960E-06 7.8958E-06 7.8956E-06 7.8954E-06 271 7.8953E-06 7.8952E-06 7.8951 E-06 7.8950E-06 7.8949E-06 276 7.8949E-06 7.8948E-06 7.8947E-06 7.8947E-06 7.8947E-06 281 7.8946E-06 7.8946E-06 7.8946E-06 7.8946E-06 7.8945E-06 286 7.8945E-06 7.8945E-06 7.8945E-06 7.8945E-06 7.8944E-06 291 7.8944E-06 7.8944E-06 7.8943E-06 7.8943E-06 7.8943E-06 296 7.8942E-06 7.8941 E-06 7.8941 E-06 7.8940E-06 7.8939E-06 301 7.8938E-06 7.8937E-06 7.8935E-06 7.8933E-06 7.8931E-06 306 7.8929E-06 7.8927E-06 7.8923E-06 7.8920E-06 7.8916E-06 311 7.8911 E-06 7.8906E-06 7.8899E-06 7.8892E-06 7.8884E-06 316 7.8875E-06 7.8864E-06 7.8852E-06 7.8838E-06 7.8823E-06 321 7.8805E-06 7.8784E-06 7.8762E-06 7.8736E-06 7.8707E-06 326 7.8674E-06 7.8637E-06 7.8595E-06 7.8548E-06 7.8496E-06 331 7.8438E-06 7.8372E-06 7.8299E-06 7.8218E-06 7.8128E-06

336 7.8028E-06 7.7917E-06 7.7795E-06 7.7659E-06 7.751 OE-06 341 7.7345E-06 7.7164E-06 7.6966E-06 7.6748E-06 7.651 OE-06 346 7.6250E-06 7.5966E-06 7.5657E-06 7.5321 E-06 7.4957E-06 351 7.4562E-06 7.4135E-06 7.3673E-06 7.3176E-06 7.2641E-06 356 7.2065E-06 7.1448E-06 7.0787E-06 7.0081E-06 6.9326E-06 361 6.8523E-06 6.7668E-06 6.6760E-06 6.5798E-06 6.4779E-06 366 6.3704E-06 6.2569E-06 6.1375E-06 6.0119E-06 5.8802E-06 371 5.7423E-06 5.5981E-06 5.4476E-06 5.2908E-06 5.1277E-06 376 4.9584E-06 4.7829E-06 4.6014E-06 4.4139E-06 4.2207E-06 381 4.0218E-06 3.8175E-06 3.6080E-06 3.3936E-06 3.1745E-06 386 2.9511 E-06 2.7236E-06 2.4924E-06 2.2578E-06 2.0203E-06 391 1.7801 E-06 1.5378E-06 1.2938E-06 1.0484E-06 8.0208E-07 396 5.5532E-07 5.5262E-07 5.5127E-07 5.4991 E-07 5.4855E-07 401 5.4719E-07 5.4584E-07 5.4448E-07 5.4312E-07 5.4176E-07 406 5.2632E-07 5.1006E-07 4.9385E-07 4.7771 E-07 4.6167E-07 411 4.4574E-07 4.2995E-07 4.1432E-07 3.9887E-07 3.8362E-07 416 3.6859E-07 3.6957E-07 3.4018E-07 3.1187E-07 2.8474E-07 421 2.5889E-07 2.3439E-07 2.1132E-07 1.8970E-07 1.6957E-07 426 1.5091E-07 1.3371E-07 1.1796E-07 1.0360E-07 9.0592E-08 431 7.8862E-08 6.8346E-08 5.8968E-08 5.0650E-08 4.3311 E-08 436 3.6870E-08 3.1247E-08 2.6364E-08 2.2145E-08 1.8518E-08 441 1.5417E-08 1.2778E-08 1.0545E-08 8.6632E-09 7.0865E-09 446 5.7715E-09 4.6801E-09 3.7788E-09 3.0380E-09 2.4320E-09 451 1.9386E-09 1.5388E-09 1.2163E-09 9.5744E-10 7.5052E-10 456 5.8587E-10 4.5545E-10 3.5258E-10 2.7177E-10 2.0855E-10 461 1.5927E-10 1.2095E-10 9.1224E-11 6.8155E-11 5.0192E-11 466 3.6080E-1 I 2.4796E-1 1 1.5488E-1 1 7.4320E-1 2 1.8439E-12 C-14 Concentrations at time =7.0OOE+01 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmr3) at nodes 1,1+1,...,1+4 Mass in solution = 2.26E+04 Mass sorbed = O.OOE+00 Total Mass 2.26E+04 I 4.9296E-32 2.3776E-31 1.0081E-30 3.9433E-30 1.5188E-29 6 5.7807E-29 2.1743E-28 8.0789E-28 2.9646E-27 1.0740E-26 11 3.8396E-26 1.3542E-25 4.7102E-25 1.6150E-24 5.4562E-24 16 1.8156E-23 5.9483E-23 1.9177E-22 6.0816E-22 1.8961E-21 21 5.8091E-21 1.7480E-20 5.1634E-20 1.4964E-19 4.2525E-19 26 1.1844E-18 3.2308E-18 8.6277E-18 2.2540E-17 5.7580E-17 31 1.4374E-16 3.5046E-16 8.3408E-16 1.9367E-15 4.3855E-15 36 9.6794E-15 2.0816E-14 4.3605E-14 8.8951E-14 1.7668E-13 41 2.4972E-13 3.4861 E-13 4.8209E-13 6.6118E-13 8.9992E-13 46 1.2160E-12 1.6316E-12 2.1742E-12 2.8779E-12 3.7843E-12 51 3.8692E-12 3.9579E-12 4.0484E-12 4.1408E-12 4.2351 E-12

56 4.3313E-12 4.4295E-12 4.7435E-12 7.7327E-06 4.6861E-03 61 8.4939E-01 8.5416E-01 8.7946E-01 8.7972E-01 9.0251E-01 66 9.0312E-01 9.9108E-01 9.9121E-01 9.2603E-01 9.2357E-01 71 5.4001E-01 5.3693E-01 3.5815E-01 3.5688E-01 3.0453E-01 76 3.0430E-01 3.1462E-01 3.1436E-01 2.5667E-01 2.5603E-01 81 1.9655E-01 1.9600E-01 1.5504E-01 1.5475E-01 1.4157E-01 86 1.4136E-01 1.1679E-01 1.1652E-01 9.1230E-02 9.1008E-02 91 7.5694E-02 7.5500E-02 5.5556E-02 5.5373E-02 4.1840E-02 96 4.1756E-02 3.9975E-02 3.9930E-02 3.3519E-02 3.3435E-02 101 2.4532E-02 2.4413E-02 1.1592E-02 1.1520E-02 1.1163E-02 106 1.1154E-02 9.7290E-03 9.7134E-03 8.2888E-03 8.2673E-03 111 5.7744E-03 5.7490E-03 3.6121 E-03 3.5985E-03 3.2423E-03 116 3.2364E-03 2.5242E-03 2.5203E-03 2.5202E-03 2.5105E-03 121 7.2986E-04 7.2245E-04 1.1498E-03 1.1503E-03 8.2982E-04 126 8.2963E-04 1.1145E-03 1.1126E-03 4.7154E-04 4.6725E-04 131 3.2473E-04 3.2453E-04 4.3144E-04 4.3202E-04 4.3203E-04 136 4.3222E-04 4.6782E-04 4.6782E-04 4.3223E-04 4.3320E-04 141 6.4681E-04 6.4720E-04 5.0480E-04 5.0402E-04 5.0401E-04 146 5.0362E-04 4.3249E-04 4.5902E-04 5.3736E-03 5.3744E-03 151 6.0221 E-04 5.7568E-04 5.0441 E-04 5.0480E-04 6.4721E-04 156 6.4740E-04 5.4059E-04 5.4001 E-04 5.4001 E-04 5.4001 E-04 161 5.4001E-04 5.4059E-04 6.4740E-04 6.4682E-04 4.3320E-04 166 4.3066E-04 1.8141E-04 2.0442E-04 4.6561E-03 4.6576E-03 171 4.9091E-04 4.6887E-04 6.1121E-04 6.1121E-04 4.6880E-04 176 4.6861E-04 5.7541E-04 5.7483E-04 3.6121E-04 3.6004E-04 181 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 186 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 191 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 196 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 201 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 206 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 211 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 216 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 221 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 226 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 231 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 236 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 241 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 246 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 C-14 Concentrations at time =7.OOOE+01 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 256 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 261 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 266 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04

271 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 276 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 281 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 286 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 291 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 296 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 301 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 306 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 311 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 316 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 321 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 326 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 331 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 336 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 341 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 346 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 351 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 356 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 361 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 366 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 371 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 376 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 381 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 386 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 3.6004E-04 391 3.6004E-04 3.6004E-04 3.6004E-04 3.6003E-04 3.5811 E-04 396 2.7916E-06 2.7904E-06 2.7895E-06 2.7884E-06 2.7870E-06 401 2.7854E-06 2.7835E-06 2.7813E-06 2.7789E-06 2.7763E-06 406 2.7283E-06 2.6439E-06 2.5282E-06 2.3855E-06 2.221 OE-06 411 2.0407E-06 1.8503E-06 1.6558E-06 I A626E-06 1.2753E-06 416 1.0980E-06 1.1092E-06 7.9107E-07 5.3700E-07 3.4751E-07 421 2.1475E-07 1.2694E-07 7.1907E-08 3.9097E-08 2.0440E-08 426 1.0292E-08 4.9987E-09 2.3456E-09 1.0649E-09 4.6843E-10 431 1.9990E-10 8.2868E-11 3.3409E-11 1.3114E-11 5.0174E-12 436 1.8729E-12 6.8277E-13 2.4330E-1 3 8.4822E-14 2.8954E-14 441 9.6844E-15 3.1764E-15 1.0223E-15 3.2307E-16 1.0031E-16 446 3.0621E-17 9.1944E-18 2.7171E-18 7.9066E-19 2.2666E-19 451 6.4045E-20 1.7844E-20 4.9042E-21 1.3302E-21 3.5619E-22 456 9.4197E-23 2.4611 E-23 6.3548E-24 1.6222E-24 4.0951E-25 461 1.0226E-25 2.5267E-26 6.1794E-27 1.4961 E-27 3.5872E-28 466 8.5190E-29 2.0041E-29 4.6574E-30 1.0088E-30 2.0332E-31 H-3 Concentrations at time =9.OOOE+01 ,(Delt =1.OOOE+00)

Node I Concentration (Cilcm^3) at nodes 1,1+1,...,1+4 Mass in solution = 1.66E+02 Mass sorbed = O.OOE+00 Total Mass = 1.66E+02

1 2.6097E-13 1.0475E-12 2.1349E-12 3.3004E-12 4.5854E-12 6 6.0334E-12 7.6913E-12 9.6101 E-12 1.1846E-11 1.4459E-1 I 11 1.7519E-1 I 2.11OOE-11 2.5283E-11 3.0161 E-11 3.5832E-1 I 16 4.2404E-1 I 4.9995E-1 1 5.8732E-1 1 6.8750E-1 1 8.0194E-1 I 21 9.3218E-1 I 1.0798E-10 1.2465E-10 1.4340E-1 0 1.6440E-10 26 1.8784E-10 2.1388E-10 2.4271 E-10 2.7449E-1 0 3.0938E-10 31 3.4754E-10 3.8910E-10 4.3418E-10 4.8289E-10 5.3529E-10 36 5.9144E-10 6.5136E-10 7.1505E-10 7.8247E-1 0 8.5354E-10 41 8.9050E-10 9.2824E-10 9.6683E-10 1.0062E-09 1.0465E-09 46 1.0875E-09 1.1292E-09 1.1717E-09 1.2149E-09 1.2587E-09 51 1.2623E-09 1.2660E-09 1.2697E-09 1.2734E-09 1.2771E-09 56 1.2808E-09 1.2845E-09 1.2961 E-09 2.7862E-03 2.7812E-03 61 2.7757E-03 2.7674E-03 2.7561 E-03 2.7420E-03 2.7251E-03 66 2.7055E-03 2.6831 E-03 2.6582E-03 2.6307E-03 2.6008E-03 71 2.5685E-03 2.5339E-03 2.4972E-03 2.4584E-03 2.4177E-03 76 2.3752E-03 2.3309E-03 2.2852E-03 2.2379E-03 2.1894E-03 81 2.1397E-03 2.0889E-03 2.0372E-03 1.9847E-03 1.9316E-03 86 1.8779E-03 1.8239E-03 1.7696E-03 1.7151E-03 1.6606E-03 91 1.6062E-03 1.5519E-03 1.4980E-03 1.4445E-03 1.3914E-03 96 1.3390E-03 1.2872E-03 1.2361 E-03 1.1859E-03 1.1366E-03 101 1.0883E-03 1.0409E-03 9.9467E-04 9.4951 E-04 9.0551 E-04 106 8.6270E-04 8.2111E-04 7.8075E-04 7.4166E-04 7.0385E-04 111 6.6732E-04 6.3208E-04 5.9813E-04 5.6547E-04 5.3409E-04 116 5.0398E-04 4.7513E-04 4.4752E-04 4.2113E-04 3.9594E-04 121 3.7192E-04 3.4905E-04 3.2729E-04 3.0663E-04 2.8703E-04 126 2.6846E-04 2.5088E-04 2.3426E-04 2.1856E-04 2.0376E-04 131 1.8982E-04 1.7670E-04 1.6436E-04 1.5278E-04 1.4192E-04 136 1.3175E-04 1.2223E-04 1.1333E-04 1.0502E-04 9.7264E-05 141 9.0039E-05 8.3314E-05 7.7059E-05 7.1249E-05 6.5857E-05 146 6.0858E-05 5.6227E-05 5.1941 E-05 4.7980E-05 4.4320E-05 151 4.0943E-05 3.7829E-05 3.4961 E-05 3.2320E-05 2.9892E-05 156 2.7660E-05 2.561 OE-05 2.3730E-05 2.2005E-05 2.0424E-05 161 1.8976E-05 1.7650E-05 1.6437E-05 1.5328E-05 1.4314E-05 166 1.3387E-05 1.2539E-05 1.1765E-05 1.1058E-05 1.0413E-05 171 9.8224E-06 9.2831 E-06 8.7902E-06 8.3394E-06 7.9271 E-06 176 7.5496E-06 7.2038E-06 6.8867E-06 6.5958E-06 6.3285E-06 181 6.0827E-06 5.8564E-06 5.6477E-06 5.4550E-06 5.2769E-06 186 5.1119E-06 4.9589E-06 4.8167E-06 4.6845E-06 4.5612E-06 191 4.4462E-06 4.3386E-06 4.2379E-06 4.1435E-06 4.0549E-06 196 3.9715E-06 3.8931 E-06 3.8192E-06 3.7495E-06 3.6837E-06 201 3.6216E-06 3.5628E-06 3.5072E-06 3.4547E-06 3.4050E-06 206 3.3579E-06 3.3133E-06 3.2712E-06 3.2312E-06 3.1935E-06 211 3.1578E-06 3.1240E-06 3.0921 E-06 3.0620E-06 3.0336E-06 216 3.0067E-06 2.9815E-06 2.9577E-06 2.9353E-06 2.9142E-06 221 2.8944E-06 2.8759E-06 2.8585E-06 2.8422E-06 2.8269E-06 226 2.8127E-06 2.7994E-06 2.7870E-06 2.7754E-06 2.7647E-06 231 2.7547E-06 2.7454E-06 2.7368E-06 2.7289E-06 2.7215E-06 236 2.7147E-06 2.7084E-06 2.7027E-06 2.6973E-06 2.6925E-06

241 2.6880E-06 2.6838E-06 2.6801 E-06 2.6766E-06 2.6735E-06 246 2.6706E-06 2.6680E-06 2.6656E-06 2.6634E-06 2.6614E-06 H-3 Concentrations at time =9.OOOE+01 ,(Det =1.000E+O0)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 2.6596E-06 2.6580E-06 2.6566E-06 2.6552E-06 2.6540E-06 256 2.6530E-06 2.6520E-06 2.6511 E-06 2.6503E-06 2.6496E-06 261 2.6490E-06 2.6484E-06 2.6479E-06 2.6475E-06 2.6471E-06 266 2.6467E-06 2.6464E-06 2.6461 E-06 2.6459E-06 2.6456E-06 271 2.6454E-06 2.6453E-06 2.6451 E-06 2.6450E-06 2.6448E-06 276 2.6447E-06 2.6446E-06 2.6445E-06 2.6445E-06 2.6444E-06 281 2.6443E-06 2.6443E-06 2.6442E-06 2.6442E-06 2.6441 E-06 286 2.6441 E-06 2.6440E-06 2.6440E-06 2.6439E-06 2.6438E-06 291 2.6438E-06 2.6437E-06 2.6437E-06 2.6436E-06 2.6435E-06 296 2.6434E-06 2.6433E-06 2.6432E-06 2.6431 E-06 2.6429E-06 301 2.6427E-06 2.6426E-06 2.6424E-06 2.6421 E-06 2.6419E-06 306 2.6416E-06 2.6412E-06 2.6409E-06 2.6404E-06 2.6400E-06 311 2.6394E-06 2.6389E-06 2.6382E-06 2.6375E-06 2.6366E-06 316 2.6357E-06 2.6347E-06 2.6336E-06 2.6324E-06 2.6310E-06 321 2.6295E-06 2.6278E-06 2.6259E-06 2.6239E-06 2.6217E-06 326 2.6192E-06 2.6165E-06 2.6135E-06 2.6102E-06 2.6067E-06 331 2.6028E-06 2.5985E-06 2.5939E-06 2.5888E-06 2.5834E-06 336 2.5774E-06 2.5710E-06 2.5640E-06 2.5564E-06 2.5483E-06 341 2.5395E-06 2.5300E-06 2.5198E-06 2.5088E-06 2.4970E-06 346 2.4844E-06 2.4709E-06 2.4565E-06 2.441 1E-06 2.4246E-06 351 2.4071 E-06 2.3885E-06 2.3688E-06 2.3478E-06 2.3256E-06 356 2.3022E-06 2.2774E-06 2.2512E-06 2.2237E-06 2.1947E-06 361 2.1642E-06 2.1322E-06 2.0987E-06 2.0637E-06 2.0270E-06 366 1.9888E-06 1.9490E-06 1.9075E-06 1.8644E-06 1.8197E-06 371 1.7733E-06 1.7253E-06 1.6756E-06 1.6244E-06 1.5716E-06 376 1.5172E-06 1.4613E-06 1.4039E-06 1.3451 E-06 1.2848E-06 381 1.2232E-06 1.1604E-06 1.0962E-06 1.0309E-06 9.6453E-07 386 8.9711 E-07 8.2874E-07 7.5952E-07 6.8952E-07 6.1883E-07 391 5.4755E-07 4.7576E-07 4.0358E-07 3.3108E-07 2.5839E-07 396 1.8559E-07 1.8479E-07 1.8439E-07 1.8399E-07 1.8359E-07 401 1.8319E-07 1.8279E-07 1.8239E-07 1.8199E-07 1.8159E-07 406 1.7703E-07 1.7223E-07 1.6744E-07 1.6267E-07 1.5792E-07 411 1.5320E-07 1.4851 E-07 1.4385E-07 1.3924E-07 1.3467E-07 416 1.3016E-07 1.3045E-07 1.2158E-07 1.1296E-07 1.0461E-07 421 9.6577E-08 8.8871 E-08 8.1514E-08 7.4519E-08 6.7898E-08 426 6.1658E-08 5.5802E-08 5.0331E-08 4.5241 E-08 4.0526E-08 431 3.6176E-08 3.2182E-08 2.8529E-08 2.5202E-08 2.2185E-08 436 1.9460E-08 1.7010E-08 1.4816E-08 1.2859E-08 1.1122E-08 441 9.5848E-09 8.231 1E-09 7.0436E-09 6.0061 E-09 5.1034E-09 446 4.321 OE-09 3.6457E-09 3.0652E-09 2.5680E-09 2.1439E-09 451 1.7836E-09 1.4787E-09 1.2216E-09 1.0057E-09 8.2496E-10

456 6.7431E-10 5.4916E-10 4.4554E-10 3.6001E-10 2.8961E-10 461 2.3179E-10 1.8435E-10 1.4542E-10 1.1338E-10 8.6873E-11 466 6.4687E-11 4.5787E-11 2.9249E-11 1.4238E-11 3.5421E-12 C-14 Concentrations at time =9.OOOE+01 ,(Delt =1.OOOE+0O)

Node I Concentration (Ci/CmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.26E+04 Mass sorbed = O.OOE+00 Total Mass = 2.26E+04 I 2.1603E-29 1.0031E-28 3.7652E-28 1.2839E-27 4.2984E-27 6 1.4211E-26 4.6408E-26 1.4966E-25 4.7645E-25 1A970E-24 11 4.6408E-24 1.4190E-23 4.2779E-23 1.2713E-22 3.7224E-22 16 1.0736E-21 3.0491E-21 8.5234E-21 2.3444E-20 6.3425E-20 21 1.6871E-19 4.4105E-19 1.1328E-18 2.8575E-18 7.0762E-1 8 26 1.7196E-17 4.0993E-17 9.5827E-17 2.1959E-16 4.9309E-16 31 1.0847E-1 5 2.3366E-15 4.9283E-1 5 1.0174E-14 2.0555E-14 36 4.0632E-14 7.8583E-14 1.4868E-1 3 2.7520E-13 4.9837E-13 41 6.7105E-13 8.9536E-13 1.1861E-12 1.5612E-12 2.0425E-12 46 2.6567E-12 3.4365E-1 2 4.4211E-12 5.6575E-12 7.2019E-12 51 7.3440E-12 7.4922E-12 7.6431 E-12 7.7967E-12 7.9531 E-12 56 8.1123E-12 8.2743E-12 8.7913E-12 1.2691 E-05 5.9987E-03 61 8.4603E-01 8.5212E-01 8.7729E-01 8.7763E-01 9.0030E-01 66 9.0107E-01 9.8855E-01 9.8871 E-01 9.2389E-01 9.2075E-01 71 5.3930E-01 5.3536E-01 3.5756E-01 3.5594E-01 3.0387E-01 76 3.0358E-01 3.1385E-01 3.1351E-01 2.5614E-01 2.5532E-01 81 1.9617E-01 1.9546E-01 1.5473E-01 1.5435E-01 1.4125E-01 86 1.4098E-01 1.1655E-01 1.1620E-01 9.1049E-02 9.0765E-02 91 7.5534E-02 7.5287E-02 5.5453E-02 5.5219E-02 4.1760E-02 96 4.1652E-02 3.9881 E-02 3.9824E-02 3.3448E-02 3.3341 E-02 101 2.4486E-02 2.4334E-02 1.1584E-02 1.1491E-02 1.1137E-02 106 1.1124E-02 9.7077E-03 9.6878E-03 8.2709E-03 8.2435E-03 111 5.7643E-03 5.7318E-03 3.6067E-03 3.5892E-03 3.2350E-03 116 3.2275E-03 2.5192E-03 2.5142E-03 2.5141E-03 2.5017E-03 121 7.3086E-04 7.2138E-04 1.1463E-03 1.1471E-03 8.2832E-04 126 8.2807E-04 1.1114E-03 1.1089E-03 4.7139E-04 4.6590E-04 131 3.2417E-04 3.2392E-04 4.3023E-04 4.3098E-04 4.3098E-04 136 4.3123E-04 4.6664E-04 4.6664E-04 4.3124E-04 4.3248E-04 141 6.4492E-04 6.4542E-04 5.0380E-04 5.0280E-04 5.0279E-04 146 5.0230E-04 4.3161E-04 4.6552E-04 5.3530E-03 5.3540E-03 151 6.0815E-04 5.7423E-04 5.0330E-04 5.0380E-04 6.4542E-04 156 6.4567E-04 5.3945E-04 5.3871 E-04 5.3870E-04 5.3870E-04 161 5.3871E-04 5.3945E-04 6.4567E-04 6.4492E-04 4.3248E-04 166 4.2924E-04 1.8140E-04 2.1083E-04 4.6379E-03 4.6399E-03 171 4.9618E-04 4.6799E-04 6.0951 E-04 6.0951 E-04 4.6789E-04

176 4.6764E-04 5.7385E-04 5.7311E-04 3.6067E-04 3.5917E-04 181 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 186 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 191 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 196 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 201 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 206 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 211 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 216 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 221 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 226 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 231 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 236 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 241 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 246 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 C-14 Concentrations at time =9.OOOE+01 ,(Deft =1.000E+00)

Node I Concentration (CVcm^3) at nodes 1,1+1,...,1+4 251 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 256 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 261 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 266 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 271 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 276 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 281 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 286 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 291 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 296 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 301 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 306 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 311 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 316 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 321 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 326 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 331 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 336 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 341 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 346 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 351 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 356 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 361 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 366 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 371 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 376 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 381 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 386 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04 3.5917E-04

391 3.5917E-04 3.5917E-04 3.5917E-04 3.5916E-04 3.5669E-04 396 2.4590E-06 2.4580E-06 2.4573E-06 2.4564E-06 2.4554E-06 401 2.4541 E-06 2.4528E-06 2.4512E-06 2.4495E-06 2.4475E-06 406 2.4137E-06 2.3549E-06 2.2740E-06 2.1735E-06 2.0561 E-06 411 1.9253E-06 1.7844E-06 1.6370E-06 1.4867E-06 1.3366E-06 416 1.1896E-06 1.1991E-06 9.2126E-07 6.8031 E-07 4.8325E-07 421 3.3049E-07 2.1781E-07 1.3846E-07 8.4988E-08 5.0420E-08 426 2.8940E-08 1.6088E-08 8.6706E-09 4.5348E-09 2.3038E-09 431 1.1380E-09 5.4705E-10 2.5615E-10 1.1693E-10 5.2075E-1 1 436 2.2647E-1 1 9.6246E-12 4.OOOOE-12 1.6269E-12 6.4796E-1 3 441 2.5289E-13 9.6781E-14 3.6338E-14 1.3394E-14 4.8490E-1 5 446 1.7252E-1 5 6.0350E-16 2.0767E-16 7.0333E-1 7 2.3453E-17 451 7.7033E-18 2.4934E-18 7.9559E-19 2.5036E-1 9 7.7722E-20 456 2.3812E-20 7.2024E-21 2.1514E-21 6.3481 E-22 1.8510E-22 461 5.3346E-23 1.5201E-23 4.2839E-24 1.1943E-24 3.2945E-25 466 8.9944E-26 2.4301 E-26 6.4698E-27 1.5841 E-27 3.3244E-28 H-3 Concentrations at time =1.400E+02 ,(Delt =1 .OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 1.08E+01 Mass sorbed = O.OOE+00 Total Mass = 1.08E+01 I 8.0858E-14 3.2390E-13 6.5300E-13 9.9218E-1 3 1.3466E-12 6 1.7213E-12 2.1216E-12 2.5528E-12 3.0204E-12 3.5300E-12 11 4.0873E-12 4.6980E-12 5.3682E-12 6.1040E-12 6.9115E-12 16 7.7972E-12 8.7672E-12 9.8282E-12 1.0987E-1 I 1.2249E-1 1 21 1.3621 E-11 1.5109E-1 1 1.6720E-1 1 1.8460E-1 I 2.0333E-1 1 26 2.2345E-1 1 2.4501 E-1 I 2.6806E-1 1 2.9262E-1 I 3.1874E-1 1 31 3.4644E-11 3.7574E-1 1 4.0664E-1 1 4.3915E- 1 4.7327E-1 1 36 5.0897E-1 1 5.4623E-1 1 5.8502E-1 1 6.2529E-1 I 6.6699E-1 I 41 6.8841 E-11 7.101OE-1 I 7.3212E-1 1 7.5444E-1 1 7.7707E-1 I 46 7.9999E-1 I 8.2319E-1 I 8.4665E-1 1 8.7037E-11 8.9433E-1 I 51 8.9629E-1 1 8.9830E-1 I 9.0031 E-1 I 9.0232E-1 1 9.0433E-1 1 56 9.0635E-1 1 9.0836E-1 1 9.1465E-11 1.5140E-04 1.5121 E-04 61 1.5101 E-04 1.5069E-04 1.5026E-04 1.4972E-04 1.4908E-04 66 1.4833E-04 1.4747E-04 1.4652E-04 1.4546E-04 1.4430E-04 71 1.4305E-04 1.4170E-04 1.4026E-04 1.3874E-04 1.3713E-04 76 1.3544E-04 1.3368E-04 1.3184E-04 1.2993E-04 1.2795E-04 81 1.2591E-04 1.2382E-04 1.2167E-04 1.1947E-04 1.1 722E-04 86 1.1493E-04 1.1 261 E-04 1.1025E-04 1.0786E-04 1.0545E-04 91 1.0302E-04 1.0057E-04 9.8105E-05 9.5633E-05 9.3156E-05 96 9.0678E-05 8.8202E-05 8.5732E-05 8.3271E-05 8.0822E-05 101 7.8390E-05 7.5976E-05 7.3583E-05 7.1216E-05 6.8875E-05 106 6.6564E-05 6.4284E-05 6.2039E-05 5.9830E-05 5.7658E-05

111 5.5527E-05 5.3436E-05 5.1388E-05 4.9385E-05 4.7426E-05 116 4.5513E-05 4.3647E-05 4.1828E-05 4.0058E-05 3.8337E-05 121 3.6664E-05 3.5040E-05 3.3465E-05 3.1940E-05 3.0464E-05 126 2.9036E-05 2.7657E-05 2.6326E-05 2.5042E-05 2.3806E-05 131 2.2615E-05 2.1471E-05 2.0371E-05 1.9315E-05 1.8303E-05 136 1.7332E-05 1.6403E-05 1.5514E-05 1.4665E-05 1.3853E-05 141 1.3079E-05 1.2341E-05 1.1638E-05 1.0969E-05 1.0332E-05 146 9.7271E-06 9.1527E-06 8.6077E-06 8.0910E-06 7.6016E-06 151 7.1383E-06 6.7001E-06 6.2860E-06 5.8949E-06 5.5259E-06 156 5.1779E-06 4.8500E-06 4.5413E-06 4.2509E-06 3.9778E-06 161 3.7212E-06 3.4803E-06 3.2543E-06 3.0424E-06 2.8439E-06 166 2.6581E-06 2.4841E-06 2.3215E-06 2.1696E-06 2.0277E-06 171 1.8952E-06 1.7717E-06 1.6565E-06 1.5493E-06 1.4494E-06 176 1.3564E-06 1.2699E-06 1.1896E-06 1.1 149E-06 1.0455E-06 181 9.8115E-07 9.2142E-07 8.6601E-07 8.1465E-07 7.6705E-07 186 7.2295E-07 6.8211 E-07 6.4430E-07 6.0930E-07 5.7692E-07 191 5A697E-07 5.1926E-07 4.9364E-07 4.6995E-07 4.4804E-07 196 4.2780E-07 4.0908E-07 3.9177E-07 3.7578E-07 3.6099E-07 201 3.4732E-07 3.3468E-07 3.2299E-07 3.1217E-07 3.0217E-07 206 2.9291E-07 2.8434E-07 2.7641 E-07 2.6906E-07 2.6225E-07 211 2.5594E-07 2.5009E-07 2.4467E-07 2.3963E-07 2.3496E-07 216 2.3062E-07 2.2658E-07 2.2283E-07 2.1935E-07 2.1611E-07 221 2.1309E-07 2.1028E-07 2.0766E-07 2.0522E-07 2.0294E-07 226 2.0082E-07 1.9885E-07 1.9700E-07 1.9528E-07 1.9367E-07 231 1.9217E-07 1.9077E-07 1.8946E-07 1.8823E-07 1.8709E-07 236 1.8602E-07 1.8502E-07 1.8409E-07 1.8322E-07 1.8240E-07 241 1.8164E-07 1.8093E-07 1.8027E-07 1.7965E-07 1.7907E-07 246 1.7853E-07 1.7803E-07 1.7756E-07 1.7712E-07 1.7671E-07 H-3 Concentrations at time =1.400E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 1.7633E-07 1.7598E-07 1.7565E-07 1.7534E-07 1.7506E-07 256 1.7479E-07 1.7454E-07 1.7431E-07 1.7410E-07 1.7390E-07 261 1.7372E-07 1.7355E-07 1.7339E-07 1.7324E-07 1.7311 E-07 266 1.7298E-07 1.7287E-07 1.7276E-07 1.7266E-07 1.7256E-07 271 1.7248E-07 1.7240E-07 1.7232E-07 1.7225E-07 1.7219E-07 276 1.7212E-07 1.7207E-07 1.7201E-07 1.7196E-07 1.7191E-07 281 1.7187E-07 1.7182E-07 1.7178E-07 1.7174E-07 1.7170E-07 286 1.7166E-07 1.7162E-07 1.7157E-07 1.7153E-07 1.7149E-07 291 1.7145E-07 1.7140E-07 1.7136E-07 1.7131E-07 1.7126E-07 296 1.7120E-07 1.7114E-07 1.7108E-07 1.7102E-07 1.7095E-07 301 1.7087E-07 1.7079E-07 1.7070E-07 1.7061 E-07 1.7051 E-07 306 1.7040E-07 1.7028E-07 1.7016E-07 1.7002E-07 1.6988E-07 311 1.6972E-07 1.6956E-07 1.6938E-07 1.6919E-07 1.6898E-07 316 1.6876E-07 1.6852E-07 1.6827E-07 1.6800E-07 1.6771 E-07 321 1.6740E-07 1.6707E-07 1.6671 E-07 1.6634E-07 1.6594E-07

326 1.6551 E-07 1.6506E-07 1.6458E-07 1.6407E-07 1.6353E-07 331 1.6296E-07 1.6235E-07 1.6171E-07 1.6104E-07 1.6032E-07 336 1.5957E-07 1.5877E-07 1.5794E-07 1.5706E-07 1.5613E-07 341 1.5516E-07 1.5414E-07 1.5307E-07 1.5195E-07 1.5078E-07 346 1.4955E-07 1.4827E-07 1.4693E-07 1.4554E-07 1.4408E-07 351 1.4257E-07 1.4099E-07 1.3935E-07 1.3765E-07 1.3589E-07 356 1.3406E-07 1.3216E-07 1.3020E-07 1.2817E-07 1.2607E-07 361 1.2390E-07 1.2167E-07 1.1937E-07 1.1 700E-07 1.1456E-07 366 1.1206E-07 1.0949E-07 1.0685E-07 1.0414E-07 1.0137E-07 371 9.8535E-08 9.5636E-08 9.2675E-08 8.9653E-08 8.6571 E-08 376 8.3432E-08 8.0236E-08 7.6986E-08 7.3684E-08 7.0331E-08 381 6.6931E-08 6.3485E-08 5.9995E-08 5.6466E-08 5.2898E-08 386 4.9296E-08 4.5661 E-08 4.1997E-08 3.8307E-08 3.4593E-08 391 3.0860E-08 2.711 OE-08 2.3347E-08 1.9573E-08 1.5793E-08 396 1.2009E-08 1.1967E-08 1.1947E-08 1.1926E-08 1.1905E-08 401 1.1884E-08 1.1863E-08 1.1843E-08 1.1822E-08 1.1801 E-08 406 1.1564E-08 1.1315E-08 1.1065E-08 1.0817E-08 1.0569E-08 411 1.0322E-08 1.0076E-08 9.8312E-09 9.5879E-09 9.3461 E-09 416 9.1061 E-09 9.1218E-09 8.6471E-09 8.1810E-09 7.7247E-09 421 7.2791 E-09 6.8454E-09 6.4243E-09 6.0166E-09 5.6230E-09 426 5.2441 E-09 4.8803E-09 4.5319E-09 4.1994E-09 3.8828E-09 431 3.5822E-09 3.2976E-09 3.0289E-09 2.7758E-09 2.5382E-09 436 2.3158E-09 2.1080E-09 1.9145E-09 1.7349E-09 1.5684E-09 441 IA147E-09 1.2731 E-09 1.1431 E-09 1.0239E-09 9.1502E-10 446 8.1580E-10 7.2562E-10 6.4388E-10 5.6998E-10 5.0334E-10 451 4.4339E-10 3.8961 E-1 0 3.4146E-1 0 2.9846E-10 2.6013E-10 456 2.2604E-10 1.9576E-10 1.6891 E-10 1.4510E-10 1.2401E-10 461 1.0530E-10 8.8677E-1 I 7.3855E-1 I 6.0569E-1 1 4.8571E-1 I 466 3.7624E-11 2.7505E-1 I 1.7998E-1 I 8.8955E-1 2 2.2192E-12 C-14 Concentrations at time =1.400E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.24E+04 Mass sorbed = O.OOE+00 Total Mass = 2.24E+04 I 4.4097E-25 1.9340E-24 5.9050E-24 1.5805E-23 4.1190E-23 6 1.0589E-22 2.6892E-22 6.7478E-22 1.6726E-21 4.0950E-21 11 9.9003E-21 2.3632E-20 5.5683E-20 1.2949E-19 2.9716E-19 16 6.7278E-19 1.5025E-18 3.3094E-18 7.1877E-18 1.5391E-17 21 3.2488E-17 6.7589E-17 1.3857E-16 2.7993E-16 5.5711 E-16 26 1.0922E-15 2.1092E-15 4.0115E-15 7.5136E-15 1.3859E-14 31 2.5172E-14 4.5020E-14 7.9286E-14 1.3750E-13 2.3482E-1 3 36 3.9494E-13 6.5422E-13 1.0675E-12 1.7160E-12 2.7181 E-1 2 41 3.4173E-12 4.2732E-12 5.3202E-12 6.5967E-12 8.1474E-12

46 1.0025E-1 1 1.2290E-11 1.5013E-11 1.8275E-11 2.2170E-1 1 51 2.2520E-1 1 2.2883E-1 1 2.3251 E-11 2.3625E-1 1 2.4004E-1 I 56 2.4388E-1 1 2.4778E-1 1 2.6017E-1 1 3.0281 E-05 9.2295E-03 61 8.3771E-01 8.4705E-01 8.7191 E-01 8.7242E-01 8.9479E-41 66 8.9598E-01 9.8225E-01 9.8250E-01 9.1856E-01 9.1374E-41 71 5.3751E-01 5.3147E-01 3.5608E-01 3.5360E-01 3.0224E-01 76 3.0179E-01 3.1191 E-01 3.1140E-01 2.5481 E-01 2.5355E-41 81 1.9521 E-01 1.9413E-01 1.5396E-01 1.5337E-01 1.4045E-41 86 1.4004E-01 1.1594E-01 1.1540E-01 9.0596E-02 9.01 60E-02 91 7.5137E-02 7.4758E-02 5.5194E-02 5.4835E-02 4.1 559E-02 96 4.1395E-02 3.9647E-02 3.9559E-02 3.3271 E-02 3.3106E-02 101 2.4372E-02 2.4139E-02 1.1563E-02 1.1421 E-02 1.1071 E-02 106 1.1052E-02 9.6546E-03 9.6240E-03 8.2264E-03 8.1843E-03 111 5.7389E-03 5.6892E-03 3.5931 E-03 3.5663E-03 3.2168E-03 116 3.2054E-03 2.5067E-03 2.4991 E-03 2.4989E-03 2.4798E-03 121 7.3327E-04 7.1873E-04 1.1378E-03 1.1389E-03 8.2456E-04 126 8.2417E-04 1.1036E-03 1.0998E-03 4.7099E-04 4.6257E-04 131 3.2276E-04 3.2238E-04 4.2723E-04 4.2838E-04 4.2839E-04 136 4.2877E-04 4.6369E-04 4.6369E-04 4.2878E-04 4.3069E-04 141 6.4021E-04 6.4098E-04 5.0130E-04 4.9977E-04 4.9976E-04 146 4.9900E-04 4.2945E-04 4.8148E-04 5.3018E-03 5.3033E-03 151 6.2270E-04 5.7066E-04 5.0054E-04 5.0131 E-04 6.4098E-04 156 6.4136E-04 5.3661 E-04 5.3546E-04 5.3546E-04 5.3546E-04 161 5.3546E-04 5.3661 E-04 6.4136E-04 6.4021E-04 4.3068E-04 166 4.2570E-04 1.8141E-04 2.2656E-04 4.5928E-03 4.5959E-03 171 5.0910E-04 4.6586E-04 6.0529E-04 6.0529E-04 4.6562E-04 176 4.6524E-04 5.6998E-04 5.6883E-04 3.5931 E-04 3.5702E-04 181 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 186 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 191 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 196 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 201 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 206 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 211 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 216 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 221 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 226 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 231 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 236 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 241 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 246 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 C-14 Concentrations at time =1 .400E+02 ,(Delt =1 .OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 256 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04

261 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 266 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 271 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 276 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 281 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 286 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 291 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 296 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 301 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 306 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 311 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 316 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 321 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 326 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 331 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 336 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 341 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 346 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 351 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 356 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 361 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 366 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 371 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 376 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 381 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 386 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 3.5700E-04 391 3.5700E-04 3.5700E-04 3.5700E-04 3.5698E-04 3.5318E-04 396 1.9707E-06 1.9699E-06 1.9693E-06 1.9687E-06 1.9680E-06 401 1.9672E-06 1.9664E-06 1.9654E-06 1.9643E-06 1.9632E-06 406 1.9442E-06 1.9123E-06 1.8688E-06 1.8145E-06 1.7504E-06 411 1.6776E-06 1.5973E-06 1.5111 E-06 1.4202E-06 1.3262E-06 416 1.2303E-06 1.2366E-06 1.0435E-06 8.5798E-07 6.8744E-07 421 5.3688E-07 4.0881 E-07 3.0359E-07 2.1995E-07 1.5551E-07 426 1.0734E-07 7.2353E-08 4.7648E-08 3.0668E-08 1.9299E-08 431 1.1880E-08 7.1552E-09 4.2189E-09 2.4361E-09 1.3781 E-09 436 7.6411E-10 4.1540E-1O 2.2152E-10 1.1591E-10 5.9542E-1 I 441 3.0035E-1 1 1.4884E-1 1 7.2487E-12 3.4705E-12 1.6341E-12 446 7.5697E-13 3.4508E-13 1.5487E-13 6.8442E-14 2.9796E-14 451 1.2782E-14 5.4046E-15 2.2532E-15 9.2640E-16 3.7576E-16 456 1.5040E-16 5.9416E-17 2.3174E-17 8.9262E-18 3.3961E-18 461 1.2766E-18 4.7424E-19 1.7414E-19 6.3219E-20 2.2695E-20 466 8.0573E-21 2.8262E-21 9.6978E-22 2.9604E-22 6.6265E-23 H-3 Concentrations at time =1.800E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 1.21E+00

Mass sorbed = O.OOE+O0 Total Mass = 1.21 E+OO I 1.6831 E-14 6.7382E-14 1.3540E-13 2.0467E-13 2.7579E-13 6 3.4939E-13 4.2610E-13 5.0653E-13 5.9130E-13 6.8102E-13 11 7.7632E-13 8.7780E-13 9.8608E-13 1.1017E-12 1.2254E-12 16 1.3576E-12 1.4990E-12 1.6500E-12 1.8113E-12 1.9833E-12 21 2.1665E-12 2.3615E-12 2.5686E-12 2.7882E-12 3.0208E-12 26 3.2665E-12 3.5258E-12 3.7988E-12 4.0857E-12 4.3866E-12 31 4.7016E-12 5.0307E-12 5.3738E-12 5.7308E-12 6.1015E-12 36 6.4856E-12 6.8829E-12 7.2928E-12 7.7150E-12 8.1489E-12 41 8.3706E-12 8.5944E-12 8.8209E-12 9.0498E-12 9.2812E-12 46 9.5149E-12 9.7509E-12 9.9890E-12 1.0229E-1 I 1.0471 E-11 51 1.0491 E-11 1.0511E-11 1.0531E-1 1 1.0552E-11 1.0572E-1 1 56 1.0592E-1 I 1.0613E-1 I 1.0676E-1 1 1.5258E-05 1.5242E-05 61 1.5226E-05 1.5200E-05 1.5165E-05 1.5122E-05 1.5069E-05 66 1.5008E-05 1.4938E-05 1.4860E-05 1.4773E-05 1.4679E-05 71 1.4576E-05 1.4465E-05 1.4347E-05 1.4221 E-05 1.4088E-05 76 1.3948E-05 1.3802E-05 1.3648E-05 1.3489E-05 1.3323E-05 81 1.3152E-05 1.2975E-05 1.2793E-05 1.2607E-05 1.2415E-05 86 1.2220E-05 1.2020E-05 1.1816E-05 1.1610E-05 1.1400E-05 91 1.1187E-05 1.0972E-05 1.0755E-05 1.0536E-05 1.0315E-05 96 1.0093E-05 9.8700E-06 9.6463E-06 9.4221 E-06 9.1978E-06 101 8.9736E-06 8.7498E-06 8.5266E-06 8.3043E-06 8.0830E-06 106 7.8631 E-06 7.6448E-06 7.4282E-06 7.2136E-06 7.0011 E-06 111 6.791 OE-06 6.5834E-06 6.3785E-06 6.1764E-06 5.9773E-06 116 5.7814E-06 5.5886E-06 5.3992E-06 5.2133E-06 5.0309E-06 121 4.8521 E-06 4.6771 E-06 4.5058E-06 4.3383E-06 4.1748E-06 126 4.0151E-06 3.8595E-06 3.7077E-06 3.5600E-06 3.4163E-06 131 3.2766E-06 3.1408E-06 3.0091 E-06 2.8813E-06 2.7574E-06 136 2.6375E-06 2.5214E-06 2.4091 E-06 2.3006E-06 2.1958E-06 141 2.0947E-06 1.9972E-06 1.9033E-06 1.8128E-06 1.7258E-06 146 1.6421E-06 1.5617E-06 1.4845E-06 1.4104E-06 1.3394E-06 151 1.2713E-06 1.2061 E-06 1.1437E-06 1.0840E-06 1.0270E-06 156 9.7253E-07 9.2055E-07 8.7097E-07 8.2371 E-07 7.7869E-07 161 7.3584E-07 6.9506E-07 6.5630E-07 6.1946E-07 5.8448E-07 166 5.5129E-07 5.1980E-07 4.8996E-07 4.6169E-07 4.3493E-07 171 4.0961E-07 3.8567E-07 3.6304E-07 3.4167E-07 3.2150E-07 176 3.0247E-07 2.8453E-07 2.6762E-07 2.5170E-07 2.3671E-07 181 2.2260E-07 2.0934E-07 1.9688E-07 1.8518E-07 1.7419E-07 186 1.6388E-07 1.5421E-07 1.4514E-07 1.3665E-07 1.2869E-07 191 1.2124E-07 1.1428E-07 1.0776E-07 1.0167E-07 9.5981E-08 196 9.0665E-08 8.5702E-08 8.1071E-08 7.6750E-08 7.2721E-08 201 6.8964E-08 6.5464E-08 6.2204E-08 5.9167E-08 5.6341E-08 206 5.3710E-08 5.1262E-08 4.8985E-08 4.6868E-08 4.4900E-08 211 4.3070E-08 4.1370E-08 3.9791E-08 3.8323E-08 3.6960E-08 216 3.5695E-08 3.4520E-08 3.3429E-08 3.2416E-08 3.1476E-08 221 3.0604E-08 2.9794E-08 2.9042E-08 2.8345E-08 2.7698E-08 226 2.7097E-08 2.6539E-08 2.6022E-08 2.5542E-08 2.5096E-08

231 2.4682E-08 2.4298E-08 2.3941E-08 2.3610E-08 2.3302E-08 236 2.3017E-08 2.2751 E-08 2.2505E-08 2.2276E-08 2.2063E-08 241 2.1865E-08 2.1681E-08 2.1510E-08 2.1351E-08 2.1204E-08 246 2.1066E-08 2.0938E-08 2.0819E-08 2.0708E-08 2.0605E-08 H-3 Concentrations at time =1.800E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 2.0509E-08 2.0420E-08 2.0337E-08 2.0259E-08 2.0187E-08 256 2.0120E-08 2.0057E-08 1.9999E-08 1.9944E-08 1.9894E-08 261 1.9846E-08 1.9802E-08 1.9761E-08 1.9722E-08 1.9686E-08 266 1.9652E-08 1.9621E-08 1.9591E-08 1.9564E-08 1.9538E-08 271 1.9513E-08 1.9490E-08 1.9469E-08 1.9448E-08 1.9429E-08 276 1.9410E-08 1.9393E-08 1.9376E-08 1.9360E-08 1.9345E-08 281 1.9330E-08 1.9316E-08 1.9302E-08 1.9289E-08 1.9275E-08 286 1.9262E-08 1.9249E-08 1.9236E-08 1.9223E-08 1.9209E-08 291 1.9196E-08 1.9182E-08 1.9169E-08 1.9154E-08 1.9139E-08 296 1.9124E-08 1.9108E-08 1.9092E-08 1.9075E-08 1.9057E-08 301 1.9038E-08 1.9018E-08 1.8997E-08 1.8975E-08 1.8952E-08 306 1.8928E-08 1.8902E-08 1.8875E-08 1.8847E-08 1.8817E-08 311 1.8785E-08 1.8752E-08 1.8716E-08 1.8679E-08 1.8640E-08 316 1.8599E-08 1.8555E-08 1.8509E-08 1.8461 E-08 1.8410E-08 321 1.8356E-08 1.8300E-08 1.8241E-08 1.8178E-08 1.8113E-08 326 1.8045E-08 1.7973E-08 1.7898E-08 1.7819E-08 1.7737E-08 331 1.7651E-08 1.7561 E-08 1.7467E-08 1.7368E-08 1.7266E-08 336 1.7159E-08 1.7048E-08 1.6932E-08 1.6812E-08 1.6687E-08 341 1.6557E-08 1.6422E-08 1.6282E-08 1.6136E-08 1.5986E-08 346 1.5830E-08 1.5669E-08 1.5502E-08 1.5330E-08 1.5152E-08 351 1.4968E-08 1.4778E-08 1.4583E-08 1.4382E-08 1.4175E-08 356 1.3962E-08 1.3743E-08 1.3519E-08 1.3288E-08 1.3051 E-08 361 1.2809E-08 1.2561 E-08 1.2306E-08 1.2046E-08 1.1780E-08 366 1.1509E-08 1.1231E-08 1.0949E-08 1.0660E-08 1.0366E-08 371 1.0067E-08 9.7632E-09 9.4539E-09 9.1397E-09 8.8207E-09 376 8.4970E-09 8.1689E-09 7.8364E-09 7.4998E-09 7.1592E-09 381 6.8149E-09 6A669E-09 6.1156E-09 5.7612E-09 5.4038E-09 386 5.0436E-09 4.6810E-09 4.3161 E-09 3.9492E-09 3.5805E-09 391 3.2103E-09 2.8388E-09 2.4662E-09 2.0929E-09 1.7191E-09 396 1.3450E-09 1.3409E-09 1.3388E-09 1.3368E-09 1.3347E-09 401 1.3326E-09 1.3306E-09 1.3285E-09 1.3265E-09 1.3244E-09 406 1.3010E-09 1.2763E-09 1.2517E-09 1.2271 E-09 1.2025E-09 411 1.1780E-09 1.1536E-09 1.1293E-09 1.1051E-09 1.0811E-09 416 1.0571E-09 1.0587E-09 1.0112E-09 9.6440E-10 9.1836E-10 421 8.7317E-10 8.2891E-10 7.8565E-10 7.4346E-10 7.0241E-10 426 6.6256E-10 6.2394E-10 5.8661E-10 5.5059E-10 5.1593E-10 431 4.8263E-10 4.5072E-10 4.2020E-10 3.9107E-10 3.6334E-10 436 3.3698E-10 3.1199E-10 2.8835E-10 2.6603E-10 2.4500E-10 441 2.2522E-10 2.0667E-10 1.8931E-10 1.7308E-10 1.5795E-10

446 1.4387E-10 1.3080E-10 1.1869E-10 1.0748E-10 9.7126E-11 451 8.7586E-1 i 7.8806E-1 1 7.0739E-1 1 6.3335E-1 1 5.6549E-1 1 456 5.0333E-1 I 4.4644E-1 1 3.9436E-1 1 3.4666E-1 I 3.0294E-1 I 461 2.6278E-1 1 2.2580E-1 1 1.9160E-11 1.5982E-11 1.3009E-11 466 1.0205E-11 7.5365E-12 4.9684E-12 2.4670E-12 6.1597E-13 C-14 Concentrations at time =1.800E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.23E+04 Mass sorbed = O.OOE+00 Total Mass = 2.23E+04 I 6.6307E-23 2.8356E-22 7.8129E-22 1.8414E-21 4.1942E-21 6 9.4113E-21 2.0873E-20 4.5779E-20 9.9287E-20 2.1292E-19 11 4.5145E-19 9.4624E-1 9 1.9605E-1 8 4.0145E-18 8.1241E-18 16 1.6246E-17 3.2101 E-1 7 6.2666E-1 7 1.2085E-16 2.3023E-16 21 4.3324E-16 8.0522E-16 1.4781 E-15 2.6796E-15 4.7972E-15 26 8.4814E-15 1.4808E-14 2.5530E-14 4.3466E-14 7.3079E-14 31 1.2134E-13 1.9898E-13 3.2225E-1 3 5.1550E-13 8.1458E-1 3 36 1.2716E-12 1.9613E-12 2.9891E-12 4.5022E-12 6.7028E-12 41 8.1681 E-12 9.9135E-12 1.1992E-11 1.4461E-11 1.7386E-1 I 46 2.0841 E-1 1 2.4911 E-11 2.9693E-1 1 3.5296E-1 I 4.1843E-1 1 51 4.2423E-1 1 4.3025E-1 1 4.3634E-1 1 4.4252E-1 I 4.4877E-1 1 56 4.5510E-1 1 4.6151 E-1 1 4.8183E-1 1 4.9574E-05 1.1763E-02 61 8.3112E-01 8.4301 E-01 8.6762E-01 8.6828E-01 8.9040E-01 66 8.9191 E-01 9.7725E-01 9.7756E-01 9.1430E-01 9.0817E-01 71 5.3606E-01 5.2838E-01 3.5490E-01 3.5174E-01 3.0094E-01 76 3.0037E-01 3.1037E-01 3.0973E-01 2.5375E-01 2.5215E-01 81 1.9445E-01 1.9307E-01 1.5334E-01 1.5260E-01 1.3981 E-01 86 1.3929E-01 1.1545E-01 1.1477E-01 9.0234E-02 8.9679E-02 91 7.4819E-02 7.4337E-02 5.4987E-02 5.4530E-02 4.1399E-02 96 4.1190E-02 3.9461 E-02 3.9349E-02 3.3129E-02 3.2920E-02 101 2.4281 E-02 2.3984E-02 1.1546E-02 1.1365E-02 1.1019E-02 106 1.0994E-02 9.6122E-03 9.5733E-03 8.1909E-03 8.1374E-03 111 5.7187E-03 5.6554E-03 3.5822E-03 3.5481E-03 3.2023E-03 116 3.1878E-03 2.4968E-03 2.4870E-03 2.4868E-03 2.4625E-03 121 7.351OE-04 7.1661E-04 1.1310E-03 1.1324E-03 8.2155E-04 126 8.2106E-04 1.0974E-03 1.0925E-03 4.7064E-04 4.5994E-04 131 3.2164E-04 3.2115E-04 4.2485E-04 4.2631 E-04 4.2632E-04 136 4.2681 E-04 4.6134E-04 4.6134E-04 4.2683E-04 4.2926E-04 141 6.3647E-04 6.3745E-04 4.9931 E-04 4.9737E-04 4.9735E-04 146 4.9638E-04 4.2777E-04 4.9394E-04 5.2612E-03 5.2632E-03 151 6.3404E-04 5.6787E-04 4.9835E-04 4.9932E-04 6.3746E-04 156 6.3794E-04 5.3434E-04 5.3288E-04 5.3287E-04 5.3287E-04 161 5.3288E-04 5.3434E-04 6.3793E-04 6.3648E-04 4.2923E-04

166 4.2291E-04 1.8145E-04 2.3886E-04 4.5571E-03 4.5610E-03 171 5.1917E-04 4.6420E-04 6.0194E-04 6.0193E-04 4.6380E-04 176 4.6332E-04 5.6690E-04 5.6544E-04 3.5822E-04 3.5530E-04 181 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 186 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 191 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 196 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 201 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 206 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 211 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 216 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 221 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 226 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 231 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 236 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 241 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 246 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 C-14 Concentrations at time =1.800E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 256 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 261 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 266 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 271 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 276 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 281 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 286 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 291 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 296 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 301 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 306 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 311 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 316 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 321 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 326 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 331 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 336 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 341 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 346 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 351 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 356 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 361 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 366 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 371 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 376 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04

381 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 386 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 3.5528E-04 391 3.5528E-04 3.5528E-04 3.5528E-04 3.5525E-04 3.5039E-04 396 1.7390E-06 1.7382E-06 1.7377E-06 1.7372E-06 1.7366E-06 401 1.7360E-06 1.7353E-06 1.7345E-06 1.7337E-06 1.7328E-06 406 1.7187E-06 1.6958E-06 1.6648E-06 1.6263E-06 1.5808E-06 411 1.5289E-06 1.4713E-06 1.4087E-06 1.3420E-06 1.2721 E-06 416 1.1997E-06 1.2045E-06 1.0552E-06 9.0581 E-07 7.6205E-07 421 6.2834E-07 5.0784E-07 4.0238E-07 3.1259E-07 2.3813E-07 426 1.7793E-07 1.3042E-07 9.3792E-08 6.6195E-08 4.5858E-08 431 3.1 190E-08 2.0832E-08 1.3667E-08 8.8086E-09 5.5792E-09 436 3.4734E-09 2.1260E-09 1.2797E-09 7.5767E-10 4.4136E-10 441 2.5302E-10 1.4278E-10 7.9329E-1 I 4.3407E-1 I 2.3396E-1 I 446 1.2425E-1 1 6.5030E-12 3.3550E-12 1.7066E-12 8.5614E-13 451 4.2365E-13 2.0683E-13 9.9652E-14 4.7390E-14 2.2249E-14 456 1.0315E-14 4.7229E-15 2.1362E-1 5 9.5470E-16 4.2164E-16 461 1.8406E-16 7.9431 E-1 7 3.3894E-17 1.4303E-17 5.9695E-18 466 2.4637E-18 1.0032E-18 3.9686E-1 9 1.3624E-19 3.1433E-20 H-3 Concentrations at time =2.IOOE+02 (Delt =1.OOOE+00)

Node I Concentration (CiIcmA3) at nodes 1,1+1,....1+4 Mass in solution = 2.34E-01 Mass sorbed = O.OOE+00 Total Mass = 2.34E-01 1 4.4095E-15 1.7649E-14 3.5418E-14 5.3420E-14 7.1770E-14 6 9.0586E-14 1.0998E-13 1.3007E-1 3 1.5096E-13 1.7277E-13 11 1.9561E-13 2.1958E-13 2.4479E-1 3 2.7134E-13 2.9934E-13 16 3.2888E-13 3.6005E-13 3.9294E-13 4.2764E-13 4.6423E-13 21 5.0278E-1 3 5.4336E-13 5.8603E-1 3 6.3086E-13 6.7788E-13 26 7.2715E-13 7.7868E-13 8.3252E-13 8.8867E-13 9.4714E-13 31 1.0079E-12 1.0710E-12 1.1364E-12 1.2041E-12 1.2739E-12 36 1.3459E-12 1.4200E-12 1.4962E-12 1.5743E-12 1.6542E-12 41 1.6949E-12 1.7360E-12 1.7774E-12 1.8193E-12 1.8616E-12 46 1.9042E-12 1.9471E-12 1.9904E-12 2.0340E-12 2.0779E-12 51 2.0815E-12 2.0852E-12 2.0889E-12 2.0925E-12 2.0962E-12 56 2.0999E-12 2.1036E-12 2.1151E-12 2.7644E-06 2.7620E-06 61 2.7593E-06 2.7553E-06 2.7498E-06 2.7429E-06 2.7346E-06 66 2.7249E-06 2.7138E-06 2.7014E-06 2.6877E-06 2.6726E-06 71 2.6563E-06 2.6387E-06 2.6198E-06 2.5998E-06 2.5786E-06 76 2.5562E-06 2.5327E-06 2.5081 E-06 2.4825E-06 2.4559E-06 81 2.4283E-06 2.3998E-06 2.3704E-06 2.3402E-06 2.3091E-06 86 2.2773E-06 2.2448E-06 2.2116E-06 2.1778E-06 2.1434E-06 91 2.1084E-06 2.0730E-06 2.0371 E-06 2.0008E-06 1.9641 E-06 96 1.9272E-06 1.8899E-06 1.8524E-06 1.8148E-06 1.7770E-06

101 1.7391E-06 1.7011E-06 1.6631 E-06 1.6252E-06 1.5873E-06 106 1.5495E-06 1.5118E-06 1.4743E-06 1.4370E-06 1.3999E-06 111 1.3631E-06 1.3266E-06 1.2904E-06 1.2546E-06 1.2191 E-06 116 1.1841E-06 1.1495E-06 1.1153E-06 1.0817E-06 1.0485E-06 121 1.0158E-06 9.8362E-07 9.5201 E-07 9.2096E-07 8.9048E-07 126 8.6058E-07 8.3128E-07 8.0258E-07 7.7449E-07 7.4701 E-07 131 7.2016E-07 6.9393E-07 6.6833E-07 6.4336E-07 6.1903E-07 136 5.9533E-07 5.7226E-07 5.4982E-07 5.2801E-07 5.0683E-07 141 4.8626E-07 4.6631 E-07 4.4696E-07 4.2822E-07 4.1007E-07 146 3.9251 E-07 3.7553E-07 3.5912E-07 3.4326E-07 3.2796E-07 151 3.1321E-07 2.9898E-07 2.8527E-07 2.7207E-07 2.5937E-07 156 2.4715E-07 2.3541E-07 2.2414E-07 2.1331 E-07 2.0292E-07 161 1.9296E-07 1.8342E-07 1.7428E-07 1.6553E-07 1.5715E-07 166 1.A915E-07 1.4150E-07 1.3420E-07 1.2722E-07 1.2057E-07 171 1.1423E-07 1.0818E-07 1.0243E-07 9.6949E-08 9.1736E-08 176 8.6779E-08 8.2068E-08 7.7593E-08 7.3345E-08 6.9315E-48 181 6.5492E-08 6.1868E-08 5.8435E-08 5.5185E-08 5.2108E-08 186 4.9198E-08 4.6447E-08 4.3846E-08 4.1390E-08 3.9071E-08 191 3.6883E-08 3.4819E-08 3.2873E-08 3.1040E-08 2.9313E-08 196 2.7687E-08 2.6157E-08 2.4718E-08 2.3365E-08 2.2093E-08 201 2.0899E-08 1.9777E-08 1.8724E-08 1.7737E-08 1.6811 E-08 206 1.5942E-08 1.5128E-08 1.4366E-08 1.3653E-08 1.2984E-08 211 1.2359E-08 1.1775E-08 1.1228E-08 1.0717E-08 1.0239E-08 216 9.7935E-09 9.3770E-09 8.9881 E-09 8.6253E-09 8.2867E-09 221 7.9709E-09 7.6764E-09 7.4019E-09 7.1461 E-09 6.9077E-09 226 6.6856E-09 6.4787E-09 6.2861E-09 6.1067E-09 5.9398E-09 231 5.7844E-09 5.6399E-09 5.5054E-09 5.3802E-09 5.2638E-09 236 5.1556E-09 5.0549E-09 4.9613E-09 4.8743E-09 4.7934E-09 241 4.7182E-09 4.6482E-09 4.5832E-09 4.5228E-09 4A666E-09 246 4A144E-09 4.3659E-09 4.3207E-09 4.2788E-09 4.2398E-09 H-3 Concentrations at time =2.100E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,l+4 251 4.2035E-09 4.1698E-09 4.1384E-09 4.1092E-09 4.0821E-09 256 4.0569E-09 4.0333E-09 4.0115E-09 3.9911E-09 3.9721E-09 261 3.9544E-09 3.9379E-09 3.9226E-09 3.9082E-09 3.8948E-09 266 3.8823E-09 3.8706E-09 3.8596E-09 3.8493E-09 3.8397E-09 271 3.8307E-09 3.8221 E-09 3.8141E-09 3.8066E-09 3.7994E-09 276 3.7926E-09 3.7862E-09 3.7801E-09 3.7742E-09 3.7686E-09 281 3.7632E-09 3.7580E-09 3.7530E-09 3.7481 E-09 3.7433E-09 286 3.7386E-09 3.7340E-09 3.7295E-09 3.7250E-09 3.7205E-09 291 3.7159E-09 3.7114E-09 3.7068E-09 3.7022E-09 3.6975E-09 296 3.6927E-09 3.6877E-09 3.6827E-09 3.6775E-09 3.6721 E-09 301 3.6666E-09 3.6608E-09 3.6549E-09 3.6487E-09 3.6422E-09 306 3.6355E-09 3.6285E-09 3.6213E-09 3.6136E-09 3.6057E-09 311 3.5974E-09 3.5888E-09 3.5797E-09 3.5703E-09 3.5604E-09

316 3.5501E-09 3.5393E-09 3.5281 E-09 3.5164E-09 3.5041E-09 321 3.4913E-09 3.4780E-09 3.4641 E-09 3.4496E-09 3.4345E-09 326 3.4188E-09 3.4024E-09 3.3854E-09 3.3677E-09 3.3493E-09 331 3.3302E-09 3.3103E-09 3.2898E-09 3.2684E-09 3.2463E-09 336 3.2233E-09 3.1996E-09 3.1750E-09 3.1495E-09 3.1232E-09 341 3.0961 E-09 3.0680E-09 3.0391 E-09 3.0092E-09 2.9784E-09 346 2.9467E-09 2.9141E-09 2.8805E-09 2.8459E-09 2.8104E-09 351 2.7739E-09 2.7364E-09 2.6979E-09 2.6585E-09 2.6180E-09 356 2.5766E-09 2.5342E-09 2.4909E-09 2.4465E-09 2.4012E-09 361 2.3549E-09 2.3076E-09 2.2594E-09 2.2102E-09 2.1601 E-09 366 2.1091 E-09 2.0571 E-09 2.0043E-09 1.9506E-09 1.8961 E-09 371 1.8407E-09 1.7844E-09 1.7274E-09 1.6696E-09 1.611 OE-09 376 1.5518E-09 1.4918E-09 1.4311 E-09 1.3698E-09 1.3079E-09 381 1.2453E-09 1.1823E-09 1.1187E-09 1.0546E-09 9.9005E-10 386 9.2509E-10 8.5974E-10 7.9404E-10 7.2804E-10 6.6176E-10 391 5.9524E-10 5.2852E-10 4.6165E-1 0 3.9466E-10 3.2758E-10 396 2.6047E-10 2.5973E-10 2.5936E-1 0 2.5899E-10 2.5862E-10 401 2.5826E-10 2.5789E-10 2.5752E-10 2.5715E-10 2.5678E-10 406 2.5258E-10 2.4815E-10 2.4373E-10 2.3931 E-10 2.3490E-10 411 2.3051E-10 2.2612E-10 2.2175E-10 2.1740E-10 2.1306E-10 416 2.0875E-10 2.0903E-10 2.0047E-10 1.9200E-10 1.8366E-10 421 1.7545E-10 1.6738E-10 1.5947E-10 1.5173E-10 1.4417E-10 426 1.3679E-10 1.2961E-10 1.2264E-10 1.1588E-10 1.0934E-10 431 1.0301E-10 9.6915E-1 1 9.1047E-1 1 8.5408E-1 1 8.0001 E-1 I 436 7.4825E-11 6.9879E-1 1 6.5161 E-1 1 6.0670E-1 1 5.6401 E-11 441 5.2351 E-11 4.8516E-1 1 4.4891E-11 4.1469E-1 1 3.8246E-1 1 446 3.5213E-11 3.2366E-11 2.9696E-1 I 2.7195E-1 1 2.4858E-1 I 451 2.2675E-1 1 2.0639E-1 I 1.8741E-11 1.6975E-1 I 1.5330E-1 1 456 1.3801 E-11 1.2378E-1 I 1.1053E-11 9.8189E-12 8.6672E-12 461 7.5901E-12 6.5799E-12 5.6290E-12 4.7296E-12 3.8743E-12 466 3.0557E-12 2.2662E-12 1.4986E-12 7.4555E-13 1.8622E-13 C-14 Concentrations at tirne =2.100E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.22E+04 Mass sorbed = O.OOE+00 Total Mass = 2.22E+04 I 1.1002E-21 4.6455E-21 1.2115E-20 2.6605E-20 5.6136E-20 6 1.1653E-19 2.3914E-19 4.8560E-19 9.7591 E-19 1.9410E-18 11 3.8200E-18 7.4394E-18 1.4335E-17 2.7328E-17 5.1542E-17 16 9.6165E-17 1.7748E-16 3.2401E-16 5.8507E-16 1.0449E-15 21 1.8457E-15 3.2245E-15 5.5712E-15 9.5199E-15 1.6088E-14 26 2.6888E-14 4.4445E-14 7.2659E-14 1.1748E-13 1.8789E-13 31 2.9723E-13 4.6511 E-13 7.2002E-13 1.1028E-12 1.6712E-12

36 2.5060E-12 3.7191 E-12 5.4629E-1 2 7.9433E-12 1.1435E-11 41 1.3702E-1 1 1.6363E-1 I 1.9486E-11 2.3144E-1 1 2.7417E-1 1 46 3.2398E-1 I 3.8190E-1 1 4.4910E-11 5.2687E-1 1 6.1667E-1 1 51 6.2458E-1 I 6.3277E-1 1 6.4106E-1 1 6.4945E-1 1 6.5794E-1 1 56 6.6652E-1 1 6.7521 E-11 7.0271E-11 6.701SE-05 1.3634E-02 61 8.2623E-01 8.3998E-01 8.6442E-01 8.6518E-01 8.8713E-01 66 8.8888E-01 9.7351 E-01 9.7387E-01 9.1112E-01 9.0403E-01 71 5.3497E-01 5.2608E-01 3.5401 E-01 3.5036E-01 2.9997E-01 76 2.9930E-01 3.0922E-01 3.0848E-01 2.5296E-01 2.511 1E-01 81 1.9387E-01 1.9229E-01 1.5287E-01 1.5202E-01 1.3933E-01 86 1.3873E-01 1.1508E-01 1.1430E-01 8.9963E-02 8.9321E-02 91 7.4582E-02 7.4024E-02 5.4832E-02 5.4303E-02 4.1280E-02 96 4.1037E-02 3.9322E-02 3.9192E-02 3.3023E-02 3.2781 E-02 101 2.4212E-02 2.3869E-02 1.1532E-02 1.1324E-02 1.0979E-02 106 1.0951 E-02 9.5805E-03 9.5355E-03 8.1643E-03 8.1024E-03 111 5.7034E-03 5.6303E-03 3.5739E-03 3.5345E-03 3.1915E-03 116 3.1746E-03 2.4893E-03 2.4780E-03 2.4777E-03 2.4496E-03 121 7.3642E-04 7.1503E-04 1.1259E-03 1.1276E-03 8.1930E-04 126 8.1874E-04 1.0927E-03 1.0871 E-03 4.7036E-04 4.5797E-04 131 3.2079E-04 3.2023E-04 4.2307E-04 4.2476E-04 4.2478E-04 136 4.2534E-04 4.5959E-04 4.5959E-04 4.2537E-04 4.2818E-04 141 6.3369E-04 6.3481 E-04 4.9782E-04 4.9557E-04 4.9554E-04 146 4.9442E-04 4.2655E-04 5.0311 E-04 5.2310E-03 5.2333E-03 151 6.4238E-04 5.6582E-04 4.9671 E-04 4.9783E-04 6.3483E-04 156 6.3539E-04 5.3264E-04 5.3095E-04 5.3094E-04 5.3094E-04 161 5.3095E-04 5.3264E-04 6.3538E-04 6.3369E-04 4.2814E-04 166 4.2083E-04 1.8151 E-04 2.4793E-04 4.5305E-03 4.5350E-03 171 5.2659E-04 4.6298E-04 5.9943E-04 5.9943E-04 4.6244E-04 176 4.6188E-04 5.6460E-04 5.6291 E-04 3.5740E-04 3.5402E-04 181 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 186 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 191 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 196 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 201 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 206 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 211 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 216 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 221 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 226 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 231 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 236 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 241 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 246 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 C-14 Concentrations at ime =2.100E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcAnA3) at nodes 1,1+1,...,1+4

251 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 256 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E04D 3.5399E-04 261 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 266 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 271 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 276 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 281 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 286 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 291 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 296 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 301 3.5399E-04 3.5399E{04 3.5399E-04 3.5399E-04 3.5399E-04 306 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 311 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 316 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 321 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 326 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 331 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 336 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E04D 3.5399E-04 341 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 346 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 351 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 356 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 361 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 366 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 371 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 376 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 381 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 3.5399E-04 386 3.5399E-04 3.5399E-04 3.5399E'04 3.5399E-04 3.5399E-04 391 3.5399E-04 3.5399E-04 3.5399E-04 3.5395E-04 3.4832E-04 396 1.61I0E-06 1.6102E-06 1.6097E-06 1.6092E-06 1.6087E-06 401 1.6081 E-06 1.6075E-06 1.6068E-06 1.6061 E-06 1.6054E-06 406 1.5934E-06 1.5745E-06 1.5493E-06 1.5180E-06 1.4810E-06 411 1.4388E-06 1.3918E-06 1.3406E-06 1.2857E-06 1.2278E-06 416 1.1674E-06 1.1714E-06 1.0455E-06 9.1701E-07 7.9053E-07 421 6.698311-07 5.5787E-07 4.5673E-07 3.6760E-07 2.9089E-07 426 2.2634E-07 1.7319E407 1.3034E-07 9.6484E-08 7.0266E-08 431 5.0350E-08 3.5505E-08 2.4641 E-08 1.6835E-08 1.1324E-08 436 7.5003E-09 4.8926E-09 3.1439E-09 1.9903E-09 1.2416E-09 441 7.6331E-10 4.6259E-10 2.7639E-10 1.6284E-10 9.4620E-1 I 446 5.4234E-1 1 3.0669E-1 1 1.7114E-1 1 9.4251 E-1 2 5.1239E-12 451 2.7501E-12 1A575E-12 7.6292E-13 3.9446E-13 2.0149E-13 456 1.0170E-13 5.0732E-14 2.5014E-14 1.2192E-14 5.8761E-15 461 2.8005E-1 5 1.3201 E-1 5 6.1555E-16 2.8395E-16 1.2959E-16 466 5.8482E-1 7 2.6004E-17 1.1168E-17 4.0932E-18 9.5937E-19 H-3 Concentrations at time =2.700E+02 P(eft =1.000E+00)

Node I Concentration (Ci/cmA3)at nodes 1,1+1,...,1+4

Mass In solution = 8.80E-03 Mass sorbed = O.OOE+00 Total Mass = 8.80E-03 1 2.4362E-16 9.7482E-16 1.9534E-15 2.9393E-1 5 3.9362E-15 6 4.9476E-15 5.9771E-15 7.0282E-15 8.1044E-15 9.2089E-15 11 1.0345E-14 1.1516E-14 1.2725E-14 1.3975E-14 1.5269E-14 16 1.6609E-14 1.7999E-14 1.9439E-14 2.0933E-14 2.2483E-14 21 2.4090E-14 2.5757E-14 2.7483E-14 2.9272E-14 3.1124E-14 26 3.3039E-14 3.5018E-14 3.7062E-14 3.9170E-14 4.1342E-14 31 4.3579E-14 4.5878E-14 4.8240E-14 5.0663E-14 5.3145E-14 36 5.5686E-14 5.8282E-14 6.0932E-14 6.3633E-14 6.6383E-14 41 6.7779E-14 6.9182E-14 7.0596E-14 7.2020E-14 7.3454E-14 46 7.4898E-14 7.6350E-14 7.7812E-14 7.9281E-14 8.0758E-14 51 8.0878E-14 8.1002E-14 8.1125E-14 8.1249E-14 8.1373E-14 56 8.1496E-14 8.1620E-14 8.2006E-14 9.2811 E-08 9.2746E-08 61 9.267SE-08 9.2566E-08 9.2418E-08 9.2234E-08 9.2011 E-08 66 9.1751E-08 9.1454E-08 9.1121 E-08 9.0752E-08 9.0346E-08 71 8.9906E-08 8.9430E-08 8.8921 E-08 8.8378E-08 8.7802E-08 76 8.7194E-08 8.6555E-08 8.5885E-08 8.5185E-08 8.4456E-08 81 8.3699E-08 8.2914E-08 8.2103E-08 8.1267E-08 8.0406E-08 86 7.9521 E-08 7.8614E-08 7.7686E-08 7.6736E-08 7.5768E-08 91 7.4781 E-08 7.3776E-08 7.2755E-08 7.1719E-08 7.0668E-08 96 6.9605E-08 6.8529E-08 6.7443E-08 6.6346E-08 6.5241 E-08 101 6.4128E-08 6.3008E-08 6.1882E-08 6.0752E-08 5.9618E-08 106 5.8481E-08 5.7343E-08 5.6204E-08 5.5065E-08 5.3927E-08 111 5.2792E-08 5.1659E-08 5.0530E-08 4.9406E-08 4.8287E-08 116 4.7174E-08 4.6068E-08 4.4971 E-08 4.3881 E-08 4.2801 E-08 121 4.1730E-08 4.0670E-08 3.9621E-08 3.8583E-08 3.7558E-08 126 3.6545E-08 3.5545E-08 3.4559E-08 3.3587E-08 3.2629E-08 131 3.1685E-08 3.0757E-08 2.9844E-08 2.8947E-08 2.8066E-08 136 2.7200E-08 2.6351E-08 2.5519E-08 2.4703E-08 2.3903E-08 141 2.3121 E-08 2.2355E-08 2.1606E-08 2.0875E-08 2.0160E-08 146 1.9462E-08 1.8781 E-08 1.8117E-08 1.7470E-08 1.6840E-08 151 1.6226E-08 1.5628E-08 1.5047E-08 1.4482E-08 1.3933E-08 156 1.3399E-08 1.2882E-08 1.2380E-08 1.1893E-08 1.1420E-08 161 1.0963E-08 1.0520E-08 1.0092E-08 9.6772E-09 9.2764E-09 166 8.8890E-09 8.5149E-09 8.1 536E-09 7.8050E-09 7.4688E-09 171 7.1446E-09 6.8322E-09 6.5314E-09 6.2417E-09 5.9630E-09 176 5.6949E-09 5.4371 E-09 5.1894E-09 4.9515E-09 4.7231 E-09 181 4.5039E-09 4.2937E-09 4.0921 E-09 3.8989E-09 3.7139E-09 186 3.5367E-09 3.3671 E-09 3.2049E-09 3.0498E-09 2.9015E-09 191 2.7599E-09 2.6246E-09 2.4955E-09 2.3723E-09 2.2548E-09 196 2.1428E-09 2.0361 E-09 1.9344E-09 1.8376E-09 1.7455E-09 201 1.6578E-09 1.5744E-09 1.4952E-09 1.4199E-09 1.3484E-09 206 1.2805E-09 1.2161E-09 1.1550E-09 1.0970E-09 1.0421 E-09 211 9.9006E-10 9.4076E-10 8.9408E-10 8.4991 E-1 0 8.0811 E-1 0 216 7.6859E-10 7.3122E-10 6.9591E-10 6.6255E-10 6.3106E-10

221 6.0132E-10 5.7327E-10 5.4680E-10 5.2184E-10 4.9832E-10 226 4.7615E-10 4.5527E-10 4.3561E-10 4.1710E-10 3.9968E-10 231 3.8329E-10 3.6788E-10 3.5339E-10 3.3978E-10 3.2699E-10 236 3.1497E-10 3.0369E-10 2.931 OE-10 2.8316E-10 2.7383E-10 241 2.6509E-10 2.5689E-10 2.4920E-10 2.4200E-10 2.3525E-10 246 2.2892E-10 2.2300E-10 2.1746E-10 2.1226E-10 2.0741 E-10 H-3 Concentrations at time =2.700E+02 ,(Deft =1.OOOE+O0)

Node I Concentration (CilcmA3) at nodes 1,1+1,...,1+4 251 2.0286E-10 1.9861 E-10 1.9463E-10 1.9091 E-10 1.8742E-1 0 256 1.8417E-10 1.8113E-10 1.7828E-10 1.7562E-10 1.7313E-10 261 1.7080E-10 1.6863E-10 1.6660E-10 1.6469E-10 1.6291E-10 266 1.6125E-10 1.5969E-10 1.5823E-10 1.5687E-10 1.5559E-10 271 1.5438E-10 1.5326E-10 1.5220E-10 1.5121 E-10 1.5027E-10 276 1.4939E-10 1.4856E-10 1.4778E-10 1.4704E-10 1.4634E-10 281 1.4568E-10 I.4504E-10 1.4444E-10 1.4387E-10 1.4332E-10 286 1.4279E-10 1.4228E-10 1.4180E-10 1A132E-10 1.4086E-10 291 1.4042E-10 1.3998E-10 1.3955E-10 1.3913E-10 1.3872E-10 296 1.3831E-10 1.3790E-10 1.3749E-10 1.3709E-10 1.3668E-10 301 1.3627E-10 1.3586E-10 1.3544E-10 1.3502E-10 1.3460E-10 306 1.3416E-10 1.3372E-10 1.3327E-10 1.3281E-10 1.3234E-10 311 1.3186E-10 1.3136E-10 1.3086E-1 0 1.3034E-10 1.2980E-1 0 316 1.2925E-10 1.2869E-10 1.2810E-10 1.2751 E-1 0 1.2689E-10 321 1.2625E-10 1.2560E-10 1.2493E-10 1.2423E-10 1.2352E-1 0 326 1.2279E-10 1.2203E-10 1.2125E-10 1.2045E-10 1.1962E-10 331 1.1878E-10 1.1790E-10 1.1701 E-1 0 1.1609E-10 1.1514E-10 336 1.1417E-10 1.1317E-10 1.1214E-10 1.1 109E-10 1.1001E-10 341 1.0891E-10 1.0777E-10 1.0661 E-10 1.0542E-10 1.0421E-10 346 1.0296E-10 1.0169E-10 1.0039E-10 9.9055E-1 1 9.7696E-1 1 351 9.6309E-1 1 9.4893E-1 I 9.3449E-1 I 9.1976E-1 1 9.0475E-1 I 356 8.8946E-1 1 8.7388E-1 1 8.5803E-1 1 8.4191E-11 8.2550E-1 1 361 8.0883E-1 1 7.9189E-1 1 7.7469E-1 I 7.5723E-1 1 7.3951 E-1 I 366 7.2153E-11 7.0331 E-1 I 6.8485E-1 1 6.6615E-1I 6.4722E-1 1 371 6.2806E-1 1 6.0869E-1 1 5.8910E-1 1 5.6930E-1 1 5.4930E-1 1 376 5.2911E-11 5.0873E-1 1 4.8818E-1 1 4.6746E-1 1 4.4657E-1 1 381 4.2553E-11 4.0435E-1 I 3.8303E-1 I 3.6158E-1 I 3.4002E-1 1 386 3.1834E-11 2.9657E-1 I 2.7470E-11 2.5276E-1 I 2.3075E-1 I 391 2.0867E-11 1.8654E-1 I 1.6438E-1 I 1.4218E-1 1 1.1996E-11 396 9.7729E-1 2 9.7486E-1 2 9.7363E-12 9.7241 E-12 9.7119E-12 401 9.6997E-12 9.6874E-12 9.6752E-12 9.6630E-12 9.6508E-12 406 9.5116E-12 9.3650E-12 9.2184E-12 9.0721 E-12 8.9259E-12 411 8.7800E-12 8.6344E-12 8.4892E-12 8.3445E-12 8.2002E-12 416 8.0564E-12 8.0658E-12 7.7799E-12 7.4968E-12 7.2166E-12 421 6.9399E-12 6.6670E-12 6.3982E-12 6.1339E-12 5.8743E-12 426 5.6197E-12 5.3703E-12 5.1265E-12 4.8884E-12 4.6563E-12 431 4.4302E-12 4.2104E-12 3.9970E-12 3.7900E-12 3.5896E-12

436 3.3958E-12 3.2087E-12 3.0282E-12 2.8544E-12 2.6872E-12 441 2.5266E-12 2.3725E-12 2.2248E-12 2.0834E-12 1.9483E-12 446 1.8192E-12 1.6960E-12 1.5786E-12 1.4667E-12 1.3603E-12 451 1.2590E-12 1.1627E-12 1.0711E-12 9.8409E-13 9.0136E-13 456 8.2267E-13 7.4778E-13 6.7643E-13 6.0838E-13 5.4336E-13 461 4.8109E-13 4.2132E-13 3.6378E-13 3.0818E-13 2.5425E-13 466 2.0172E-13 1.5031E-13 9.9735E-14 4.9723E-14 1.2424E-14 G-14 Concentrations at time =2.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.21E+04 Mass sorbed = O.OOE+00 Total Mass = 2.21E+04 I 6.8473E-20 2.8438E-19 6.8801E-19 1.3670E-18 2.5805E-18 6 4.7757E-18 8.7353E-18 1.5826E-17 2.8413E-17 5.0560E-17 11 8.9173E-17 1.5588E-16 2.7008E-16 4.6376E-16 7.8923E-16 16 1.3311E-15 2.2250E-15 3.6860E-15 6.0515E-15 9.8462E-15 21 1.5878E-14 2.5375E-14 4.0192E-14 6.3095E-14 9.8173E-14 26 1.5141E-13 2.3145E-13 3.5072E-1 3 5.2683E-1 3 7.8455E-1 3 31 1.1583E-12 1.6956E-12 2.461 1E-12 3.5424E-12 5.0566E-12 36 7.1589E-12 1.0053E-1 1 1.4005E-11 1.9357E-11 2.6545E-1 1 41 3.1048E-1 1 3.6221E-1 I 4.2167E-1 1 4.8988E-1 1 5.6800E-1 1 46 6.5729E-1 1 7.5917E-1 I 8.7520E-1 I 1.0071E-10 1.1568E-10 51 1.1698E-10 1.1834E-10 1.1970E-10 1.2108E-1 0 1.2247E-1 0 56 1.2388E-1 0 1.2530E-10 1.2980E-10 1.0933E-04 1.7301E-02 61 8.1656E-01 8.3395E-01 8.5806E-01 8.5903E-01 8.8062E-01 66 8.8283E-01 9.6608E-01 9.6653E-01 9.0479E-01 8.9582E-01 71 5.3276E-01 5.2152E-01 3.5223E-01 3.4761 E-01 2.9803E-01 76 2.9719E-01 3.0694E-01 3.0599E-01 2.5138E-01 2.4904E-01 81 1.9273E-01 1.9072E-01 1.5194E-01 1.5086E-01 1.3838E-01 86 1.3762E-01 1.1436E-01 1.1336E-01 8.9422E-02 8.8610E-02 91 7A108E-02 7.3403E-02 5.4522E-02 5.3853E-02 4.1040E-02 96 4.0734E-02 3.9045E-02 3.8881 E-02 3.2812E-02 3.2505E-02 101 2.4075E-02 2.3641 E-02 1.1505E-02 1.1242E-02 1.0902E-02 106 1.0866E-02 9.5174E-03 9.4604E-03 8.1113E-03 8.0330E-03 111 5.6729E-03 5.5804E-03 3.5574E-03 3.5076E-03 3.1699E-03 116 3.1486E-03 2.4744E-03 2.4602E-03 2A597E-03 2.4241 E-03 121 7.3893E-04 7.1188E-04 1.1159E-03 1.1 180E-03 8.1480E-04 126 8.1409E-04 1.0835E-03 1.0764E-03 4.6975E-04 4.5409E-04 131 3.1911E-04 3.1839E-04 4.1954E-04 4.2168E-04 4.2171 E-04 136 4.2242E-04 4.5611 E-04 4.5611 E-04 4.2246E-04 4.2602E-04 141 6.2816E-04 6.2958E-04 4.9484E-04 4.9200E-04 4.9195E-04 146 4.9054E-04 4.2419E-04 5.2100E-04 5.1713E-03 5.1741 E-03 151 6.5862E-04 5.6181 E-04 4.9344E-04 4.9486E-04 6.2960E-04

156 6.3031E-04 5.2926E-04 5.2712E-04 5.2710E-04 5.2710E-04 161 5.2712E-04 5.2926E-04 6.3030E-04 6.2816E-04 4.2596E-04 166 4.1672E-04 1.8166E-04 2.6565E-04 4.4779E-03 4.4836E-03 171 5.4104E-04 4.6060E-04 5.9447E-04 5.9446E-04 4.5973E-04 176 4.5902E-04 5.6003E-04 5.5790E-04 3.5575E-04 3.5148E-04 181 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 186 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 191 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 196 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 201 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 206 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 211 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 216 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 221 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 226 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 231 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 236 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 241 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 246 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 C-14 Concentrations at time =2.700E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 256 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 261 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 266 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 271 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 276 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 281 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 286 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 291 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 296 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 301 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 306 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 311 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 316 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 321 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 326 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 331 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 336 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 341 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 346 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 351 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 356 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 361 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 366 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04

371 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 376 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 381 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 386 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 3.5143E-04 391 3.5143E-04 3.5143E-04 3.5143E-04 3.5136E-04 3.4422E-04 396 1.4226E-06 1.4218E-06 1.4214E-06 1.4210E-06 1.4205E-06 401 1.4200E-06 1.4195E-06 1.4189E-06 1.4183E-06 1.4177E-06 406 1.4084E-06 1.3943E-06 1.3760E-06 1.3534E-06 1.3269E-06 411 1.2966E-06 1.2629E-06 1.2260E-06 1.1863E-06 1.1440E-06 416 1.0996E-06 1.1025E-06 1.0085E-06 9.1023E-07 8.1056E-07 421 7.1218E-07 6.1741E-07 5.2813E-07 4.4576E-07 3.7125E-07 426 3.0512E-07 2.4747E-07 1.9809E-07 1.5649E-07 1.2202E-07 431 9.3919E-08 7.1360E-08 5.3529E-08 3.9644E-08 2.8990E-08 436 2.0935E-08 1.4930E-08 1.0516E-08 7.3160E-09 5.0281 E-09 441 3.4140E-09 2.2904E-09 1.5183E-09 9.9466E-10 6.4402E-10 446 4.1217E-10 2.6076E-10 1.6310E-10 1.0087E-10 6.1686E-1 I 451 3.7307E-11 2.2317E-11 1.3205E-1 I 7.7296E-12 4.4766E-12 456 2.5653E-12 1.4548E-12 8.1647E-13 4.5357E-13 2.4942E-1 3 461 1.3579E-13 7.3191E-14 3.9064E-14 2.0644E-14 1.0800E-14 466 5.5838E-15 2.8346E-15 1.3735E-1 5 5.5197E-16 1.3210E-16 H-3 Concentrations at time =2.800E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CIIcMA3) at nodes 1,1+1,...,1+4 Mass in solution = 5.10E-03 Mass sorbed = O.OOE+00 Total Mass = 5.10E-03 I 1.4767E-16 5.9086E-16 1.1838E-15 1.7809E-1 5 2.3840E-1 5 6 2.9953E-15 3.6166E-1 5 4.2499E-15 4.8972E-1 5 5.5603E-15 11 6.2411E-15 6.9412E-15 7.6624E-15 8.4063E-15 9.1746E-1 5 16 9.9686E-15 1.0790E-14 1.1639E-14 1.2519E-14 1.3429E-14 21 1.4371E-14 1.5346E-14 1.6354E-14 1.7396E-14 1.8473E-14 26 1.9585E-14 2.0733E-14 2.1916E-14 2.3134E-14 2.4388E-14 31 2.5677E-14 2.7001 E-14 2.8359E-14 2.9751 E-14 3.1175E-14 36 3.2631E-14 3.4117E-14 3.5633E-14 3.7177E-14 3.8748E-14 41 3.9545E-14 4.0346E-14 4.1152E-14 4.1965E-14 4.2782E-14 46 4.3605E-14 4.4433E-14 4.5265E-14 4.6102E-14 4.6943E-14 51 4.7012E-14 4.7082E-14 4.7152E-14 4.7223E-14 4.7293E-14 56 4.7363E-14 4.7434E-14 4.7654E-14 5.2833E-08 5.2797E-08 61 5.2758E-08 5.2698E-08 5.2617E-08 5.2515E-08 5.2393E-08 66 5.2250E-08 5.2086E-08 5.1902E-08 5.1699E-08 5.1475E-08 71 5.1233E-08 5.0971E-08 5.0690E-08 5.0390E-08 5.0073E-08 76 4.9737E-08 4.9384E-08 4.9015E-08 4.8628E-08 4.8226E-08 81 4.7807E-08 4.7374E-08 4.6925E-08 4.6463E-08 4.5987E-08 86 4.5497E-08 4.4995E-08 4.4481 E-08 4.3955E-08 4.3418E-08

91 4.2871 E-08 4.2313E-08 4.1747E-08 4.1171 E-08 4.0588E-08 96 3.9997E-08 3.9399E-08 3.8794E-08 3.8184E-08 3.7568E-08 101 3.6948E-08 3.6324E-08 3.5696E-08 3.5065E-08 3.4431 E-08 106 3.3796E-08 3.3159E-08 3.2522E-08 3.1884E-08 3.1246E-08 111 3.0609E-08 2.9974E-08 2.9340E-08 2.8708E-08 2.8079E-08 116 2.7452E-08 2.6830E-08 2.6211 E-08 2.5596E-08 2A986E-08 121 2.4381 E-08 2.3781 E-08 2.3187E-08 2.2599E-08 2.2018E-08 126 2.1443E-08 2.0875E-08 2.0314E-08 1.9761 E-08 1.9215E-08 131 1.8677E-08 1.8147E-08 1.7626E-08 1.7113E-08 1.6608E-08 136 1.6112E-08 1.5625E-08 1.5147E-08 1.4678E-08 1.4218E-08 141 1.3767E-08 1.3325E-08 1.2893E-08 1.2470E-08 1.2056E-08 146 1.1652E-08 1.1257E-08 1.0871 E-08 1.0495E-08 1.0128E-08 151 9.7701E-09 9.4214E-09 9.0818E-09 8.7513E-09 8.4297E-09 156 8.1169E-09 7.8129E-09 7.5176E-09 7.2308E-09 6.9525E-09 161 6.6826E-09 6.4208E-09 6.1671E-09 5.9214E-09 5.6835E-09 166 5.4532E-09 5.2305E-09 5.0152E-09 4.8071E-09 4.6061 E-09 171 4.4120E-09 4.2247E-09 4.0441 E-09 3.8699E-09 3.7020E-09 176 3.5403E-09 3.3846E-09 3.2348E-09 3.0907E-09 2.9521 E-09 181 2.8188E-09 2.6909E-09 2.5680E-09 2.4500E-09 2.3368E-09 186 2.2283E-09 2.1242E-09 2.0245E-09 1.9291 E-09 1.8376E-09 191 1.7502E-09 1.6665E-09 1.5865E-09 1.51OOE-09 1.4369E-09 196 1.3672E-09 1.3006E-09 1.2370E-09 1.1764E-09 1.1186E-09 201 1.0636E-09 1.0111E-09 9.6117E-10 9.1363E-10 8.6839E-10 206 8.2537E-10 7.8447E-10 7A560E-10 7.0868E-10 6.7362E-10 211 6.4034E-10 6.0876E-10 5.7880E-10 5.5041E-10 5.2349E-10 216 4.9799E-10 4.7384E-1 0 4.5097E-10 4.2934E-10 4.0887E-10 221 3.8951E-10 3.7121E-1 0 3.5392E-10 3.3758E-10 3.2215E-10 226 3.0759E-10 2.9385E-1 0 2.8088E-10 2.6866E-10 2.5713E-10 231 2.4627E-10 2.3604E-1 0 2.2640E-10 2.1733E-10 2.0879E-10 236 2.0075E-10 1.9319E-10 1.8608E-10 1.7940E-10 1.7312E-10 241 1.6722E-10 1.6168E-10 1.5648E-10 1.5159E-10 1.4701 E-10 246 1.4271 E-1 0 1.3867E-10 1.3489E-10 1.3134E-10 1.2802E-1 0 H-3 Concentrations at time =2.800E+02 ,(Deft =1 .OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 1.2490E-10 1.2198E-10 1.1924E-10 1.1668E-10 1.1428E-10 256 1.1203E-10 1.0992E-10 1.0795E-10 1.0611E-10 1.0438E-10 261 1.0276E-10 1.0125E-10 9.9830E-1 1 9.8503E-1 I 9.7261E-1 I 266 9.6097E-1 I 9.5007E-1 1 9.3986E-1 I 9.3029E-1 1 9.2132E-1 I 271 9.1290E-11 9.0500E-11 8.9758E-1 I 8.9061 E-1 1 8.8405E-1 1 276 8.7788E-1 I 8.7207E-1 1 8.6658E-1 I 8.6140E-1 1 8.5650E-1 1 281 8.5186E-11 8.4745E-11 8.4327E-1 1 8.3928E-1 I 8.3547E-1 I 286 8.3183E-11 8.2834E-11 8.2498E-1 I 8.2174E-1 1 8.1862E-1 I 291 8.1558E-11 8.1263E-11 8.0975E-1 I 8.0694E-1 1 8.0417E-1 I 296 8.0145E-1 1 7.9876E-1 1 7.9609E-1 I 7.9344E-1 I 7.9080E-1 I 301 7.8816E-1 1 7.8552E-1 I 7.8286E-1 I 7.8018E-1 I 7.7747E-1 I

306 7.7473E-11 7.7196E-11 7.6914E-11 7.6627E-11 7.6335E-11 311 7.6037E-11 7.5732E-11 7.5421 E-11 7.5102E-11 7.4776E-11 316 7.4441E-11 7.4097E-11 7.3745E-11 7.3383E-11 7.3012E-11 321 7.2630E-11 7.2238E-11 7.1834E-11 7.1420E-11 7.0994E-11 326 7.0557E-11 7.0107E-11 6.9645E-11 6.9170E-11 6.8682E-11 331 6.8180E-11 6.7666E-11 6.7137E-11 6.6595E-11 6.6038E-11 336 6.5468E-1 I 6.4882E-1 I 6.4282E-1 I 6.3667E-1 1 6.3036E-1 1 341 6.2391 E-11 6.1730E-11 6.1054E-11 6.0362E-11 5.9655E-11 346 5.8932E-11 5.8193E-11 5.7438E-11 5.6667E-11 5.5881 E-11 351 5.5078E-11 5.4260E-11 5.3426E-11 5.2576E-11 5.1711 E-11 356 5.0830E-11 4.9933E-11 4.9021E-11 4.8094E-11 4.7151E-11 361 4.6194E-11 4.5221 E-11 4.4234E-11 4.3233E-11 4.2218E-11 366 4.1189E-11 4.0146E-11 3.9089E-11 3.8020E-11 3.6938E-11 371 3.5843E-11 3.4736E-11 3.3618E-11 3.2488E-11 3.1347E-11 376 3.0196E-1 1 2.9034E-1 1 2.7863E-1 I 2.6682E-1 I 2.5493E-1 1 381 2.4295E-11 2.3089E-11 2.1875E-11 2.0655E-11 1.9428E-11 386 1.8195E-1 I 1.6957E-11 1.5714E-1 I 1.4466E-1 1 1.3215E-1 1 391 1.1 960E-1 I 1.0702E-1 I 9.4423E-12 8.1808E-12 6.9181E-12 396 5.6548E-12 5.6410E-12 5.6340E-12 5.6271E-12 5.6201E-12 401 5.6132E-12 5.6062E-12 5.5993E-12 5.5924E-12 5.5854E-12 406 5.5063E-12 5.4230E-12 5.3397E-12 5.2565E-12 5.1734E-12 411 5.0905E-12 5.0078E-12 4.9252E-12 4.8429E-12 4.7609E-12 416 4.6791E-12 4.6845E-12 4.5218E-12 4.3607E-12 4.2012E-12 421 4.0437E-12 3.8881E-12 3.7349E-12 3.5841E-12 3.4359E-12 426 3.2904E-12 3.1479E-12 3.0084E-12 2.8720E-12 2.7389E-12 431 2.6092E-12 2.4829E-12 2.3602E-12 2.241 OE-12 2.1255E-12 436 2.0136E-12 1.9054E-12 1.8010E-12 1.7002E-12 1.6031E-12 441 1.5097E-12 1.4199E-12 1.3337E-1 2 1.2511E-12 1.1719E-12 446 1.0961E-12 1.0237E-12 9.5443E-13 8.8833E-13 8.2528E-13 451 7.6514E-13 7.0781E-13 6.5317E-13 6.011OE-13 5.5145E-13 456 5.0410E-13 4.5891E-13 4.1573E-13 3.7443E-13 3.3484E-13 461 2.9683E-13 2.6025E-13 2.2493E-13 1.9072E-13 1.5747E-13 466 1.2501E-13 9.3198E-14 6.1863E-14 3.0849E-14 7.7085E-15 C-14 Concentrations at time =2.800E+02 ,(Delt =1.OOOE+O0)

Node I Concentration (CicmW3) at nodes 1,1+1,...,1+4 Mass In solution = 2.20E+04 Mass sorbed = O.OOE+00 Total Mass = 2.20E+04 1 1.1893E-19 4.9297E-19 1.1816E-18 2.3178E-18 4.3120E-18 6 7.8597E-18 1.4158E-17 2.5261E-17 4.4676E-17 7.8329E-17 11 1.3615E-16 2.3461E-16 4.0077E-16 6.7870E-16 1.1394E-15 16 1.8963E-15 3.1285E-15 5.1167E-15 8.2957E-15 1.3333E-14 21 2.1244E-14 3.3557E-14 5.2548E-14 8.1580E-14 1.2557E-13

26 1.9162E-13 2.8995E-1 3 4.3501E-13 6.4718E-13 9.5480E-13 31 1.3970E-12 2.0271 E-1 2 2.9176E-12 4.1653E-12 5.8991 E-1 2 36 8.2888E-12 1.1555E-1 1 1.5986E-11 2.1946E-1 I 2.9903E-1 1 41 3.4864E-1 1 4.0547E-1 I 4.7060E-1 I 5.4513E-11 6.3024E-1 1 46 7.2728E-1 1 8.3773E-1 I 9.6320E-1 I 1.1055E-10 1.2666E-10 51 1.2806E-10 1.2951E-10 1.3098E-10 1.3246E-10 1.3396E-10 56 1.3547E-10 1.3700E-10 1.4182E-10 1.1733E-04 1.7902E-02 61 8.1496E-01 8.3294E-01 8.5701 E-01 8.5800E-01 8.7954E-01 66 8.8183E-01 9.6484E-01 9.6532E-01 9.0374E-01 8.9446E-01 71 5.3239E-01 5.2077E-01 3.5193E-01 3.4715E-01 2.9771 E-01 76 2.9684E-01 3.0656E-01 3.0558E-01 2.5112E-01 2.4869E-01 81 1.9254E-01 1.9046E-01 1.5179E-01 1.5067E-01 1.3822E-01 86 1.3744E-01 1.1424E-01 1.1321E-01 8.9332E-02 8.8493E-02 91 7.4029E-02 7.3300E-02 5.4470E-02 5.3778E-02 4.10OOE-02 96 4.0684E-02 3.8999E-02 3.8829E-02 3.2776E-02 3.2460E-02 101 2.4052E-02 2.3603E-02 1.1500E-02 1.1228E-02 1.0889E-02 106 1.0852E-02 9.5069E-03 9.4480E-03 8.1025E-03 8.0215E-03 111 5.6678E-03 5.5721 E-03 3.5547E-03 3.5031 E-03 3.1664E-03 116 3.1443E-03 2.4719E-03 2.4572E-03 2.4567E-03 2.4198E-03 121 7.3933E-04 7.1135E-04 1.1 142E-03 1.1 164E-03 8.1405E-04 126 8.1332E-04 1.0820E-03 1.0747E-03 4.6965E-04 4.5345E-04 131 3.1882E-04 3.1809E-04 4.1896E-04 4.2117E-04 4.2120E-04 136 4.2193E-04 4.5553E-04 4.5553E-04 4.2198E-04 4.2566E-04 141 6.2724E-04 6.2871 E-04 4.9435E-04 4.9141 E-04 4.9136E-04 146 4.8989E-04 4.2380E-04 5.2392E-04 5.1614E-03 5.1643E-03 151 6.6128E-04 5.6116E-04 4.9290E-04 4.9437E-04 6.2874E-04 156 6.2947E-04 5.2870E-04 5.2649E-04 5.2646E-04 5.2646E-04 161 5.2649E-04 5.2870E-04 6.2946E-04 6.2725E-04 4.2560E-04 166 4.1604E-04 1.8169E-04 2.6855E-04 4.4692E-03 4.4751 E-03 171 5.4340E-04 4.6021E-04 5.9364E-04 5.9364E-04 4.5928E-04 176 4.5855E-04 5.5927E-04 5.5707E-04 3.5547E-04 3.5106E-04 181 3.5101 E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 186 3.5101 E-04 3.5101E-04 3.51 01 E-04 3.5101 E-04 3.51I1E-04 191 3.5101 E-04 3.5101E-04 3.51 01 E-04 3.5101 E-04 3.5101E-04 196 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 201 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 206 3.5101 E-04 3.51 01 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 211 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101 E-04 3.5101E-04 216 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 221 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 226 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 231 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 236 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 241 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 246 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101 E-04 C-14 Concentrations at time =2.800E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.5101E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 256 3.5101E-04 3.5101E-04 3.5101E-04 3.5101 E-04 3.5101E-04 261 3.5101E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 266 3.5101E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 271 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 276 3.5101E-04 3.5101E-04 3.5101E-04 3.5101E-04 3.5101E-04 281 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101E-04 286 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101 E-04 291 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101 E-04 296 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101 E-04 301 3.5101 E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101 E-04 306 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 311 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 316 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101E-04 321 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101E-04 326 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101E-04 331 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101 E-04 336 3.5101E-04 3.5101 E-04 3.51 01 E-04 3.5101E-04 3.5101 E-04 341 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 346 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 351 3.5101E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 356 3.5101E-04 3.51OIE-04 3.5101 E-04 3.5101 E-04 3.5101E-04 361 3.5101E-04 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 366 3.5101E-04 3.5101E-04 3.51 01 E-04 3.5101 E-04 3.5101E-04 371 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101 E-04 376 3.5101E-04 3.5101 E-04 3.5101 E-04 3.5101 E-04 3.5101E-04 381 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.5101E-04 386 3.5101E-04 3.5101 E-04 3.5101E-04 3.5101E-04 3.51 01 E-04 391 3.5101E-04 3.5101 E-04 3.5101E-04 3.5093E-04 3.4354E-04 396 1.3972E-06 1.3965E-06 1.3961 E-06 1.3957E-06 1.3952E-06 401 1.3947E-06 1.3942E-06 1.3936E-06 1.3931 E-06 1.3925E-06 406 1.3835E-06 1.3700E-06 1.3524E-06 1.3308E-06 1.3055E-06 411 1.2767E-06 1.2446E-06 1.2094E-06 1.1714E-06 1.1311E-06 416 1.0886E-06 1.0914E-06 1.0014E-06 9.0704E-07 8. I1OOE-07 421 7.1580E-07 6.2366E-07 5.3641 E-07 4.5545E-07 3.8177E-07 426 3.1593E-07 2.5813E-07 2.0823E-07 1.6586E-07 1.3045E-07 431 1.0132E-07 7.7720E-08 5.8879E-08 4.4058E-08 3.2565E-08 436 2.3778E-08 1.7152E-08 1.2225E-08 8.6095E-09 5.9917E-09 441 4.1210E-09 2.8014E-09 1.8824E-09 1.2504E-09 8.2112E-10 446 5.3316E-10 3.4232E-10 2.1736E-10 1.3649E-10 8A783E-1 1 451 5.2095E-1 1 3.1667E-1 I 1.9046E-1 1 1.1 335E-1 1 6.6757E-12 456 3.8911 E-12 2.2449E-12 1.2821 E-1 2 7.2490E-13 4.0579E-13 461 2.2493E-13 1.2346E-13 6.7116E-14 3.6131E-14 1.9255E-14 466 1.0140E-14 5.2397E-15 2.5792E-15 1.0487E-15 2.5162E-16 H-3 Concentrations at time =3.500E+02 ,(Deft =1 .OOOE+00)

Node I Concentration (Cilcmrn3) at nodes 1,1+1,...,1+4 Mass in solution= 1.11E-04 Mass sorbed = O.OOE+00 Total Mass = 1.11E-04 I 4.0762E-18 1.6308E-17 3.2650E-17 4.9058E-17 6.5564E-17 6 8.2201 E-17 9.9000E-17 1.1599E-16 1.3321 E-1 6 1.5068E-16 11 1.6844E-16 1.8650E-16 2.0490E-16 2.2367E-16 2.4282E-16 16 2.6238E-16 2.8237E-16 3.0281 E-16 3.2373E-16 3.4512E-16 21 3.6702E-1 6 3.8943E-16 4.1236E-16 4.3583E-16 4.5983E-16 26 4.8438E-1 6 5.0948E-1 6 5.3512E-16 5.6131E-16 5.8803E-16 31 6.1530E-16 6.4309E-1 6 6.7140E-16 7.0022E-16 7.2953E-16 36 7.5931 E-16 7.8955E-16 8.2023E-16 8.5132E-16 8.8280E-1 6 41 8.9872E-16 9.1468E-16 9.3073E-16 9.4686E-16 9.6307E-1 6 46 9.7935E-16 9.9570E-16 1.0121E-15 1.0286E-15 1.0451 E-15 51 1.0465E-15 1.0479E-15 1.0492E-15 1.0506E-15 1.0520E-15 56 1.0534E-15 1.0548E-15 1.0591 E-15 1.0370E-09 1.0364E-09 61 1.0358E-09 1.0349E-09 1.0336E-09 1.0319E-09 1.0300E-09 66 1.0277E-09 1.0251 E-09 1.0221 E-09 1.0189E-09 1.0153E-09 71 1.01 14E-09 1.0072E-09 1.0026E-09 9.9782E-10 9.9270E-10 76 9.8729E-10 9.8158E-10 9.7559E-10 9.6933E-10 9.6279E-10 81 9.5599E-10 9.4893E-10 9.4161 E-1 0 9.3405E-10 9.2625E-10 86 9.1822E-10 9.0996E-10 9.0148E-10 8.9280E-1 0 8.8391E-10 91 8.7483E-1 0 8.6556E-10 8.5611 E-1 0 8.4649E-1 0 8.3671E-10 96 8.2677E-1 0 8.1669E-10 8.0647E-10 7.9613E-10 7.8566E-10 101 7.7508E-10 7.6439E-1 0 7.5361 E-1 0 7.4274E-10 7.3180E-10 106 7.2078E-10 7.0970E-1 0 6.9856E-10 6.8738E-10 6.7616E-10 111 6.6491 E-10 6.5363E-10 6.4234E-10 6.3105E-10 6.1975E-10 116 6.0846E-10 5.9719E-10 5.8593E-10 5.7470E-10 5.6351 E-1 0 121 5.5236E-10 5.4126E-10 5.3021 E-1 0 5.1922E-10 5.0830E-10 126 4.9745E-10 4.8667E-10 4.7598E-1 0 4.6537E-10 4.5485E-10 131 4.4444E-10 4.3412E-10 4.2391 E-10 4.1380E-10 4.0381E-10 136 3.9394E-10 3.8419E-10 3.7456E-10 3.6505E-10 3.5568E-10 141 3.4643E-10 3.3733E-10 3.2835E-10 3.1952E-10 3.1083E-10 146 3.0228E-10 2.9387E-10 2.8561E-10 2.7749E-10 2.6952E-10 151 2.6170E-10 2.5403E-10 2.4650E-10 2.3913E-10 2.3190E-10 156 2.2483E-10 2.1790E-10 2.1112E-10 2.0449E-10 1.9801E-10 161 1.9168E-10 1.8549E-10 1.7945E-10 1.7355E-10 1.6779E-10 166 1.6218E-10 1.5671 E-10 1.5138E-10 1.4619E-10 1.4113E-10 171 1.3621E-10 1.3143E-10 1.2677E-10 1.2224E-10 1.1784E-10 176 1.1357E-10 1.0942E-10 1.0540E-10 1.0149E-10 9.7698E-1 1 181 9.4024E-1 I 9.0463E-1 1 8.7013E-1 1 8.3673E-1 I 8.0439E-1 1 186 7.7309E-1 I 7.4282E-1 I 7.1354E-1 I 6.8525E-1 I 6.5791 E-1 I 191 6.3150E-11 6.0600E-1 1 5.8139E-1 I 5.5765E-1 I 5.3475E-1 1 196 5.1267E-1 1 4.9139E-1 I 4.7088E-1 1 4.5114E-1 I 4.3213E-11 201 4.1384E-1 I 3.9624E-1 1 3.7931 E-1 1 3.6304E-1 1 3.4740E-1 1 206 3.3237E-1 I 3.1795E-1 I 3.0410E-11 2.9080E-1 I 2.7805E-1 I

211 2.6582E-11 2.5409E-11 2.4286E-11 2.3209E-11 2.2178E-11 216 2.1191 E-1 1 2.0246E-1 1 1.9342E-1 I 1.8478E-1 1 1.7651 E-1 1 221 1.6861 E-11 1.6107E-11 1.5386E-11 1.4697E-11 1.4040E-11 226 1.3413E-11 1.2815E-11 1.2245E-1 I 1.1701E-1 1 1.1183E-11 231 1.0689E-11 1.0219E-11 9.7718E-12 9.3458E-12 8.9405E-12 236 8.5549E-12 8.1883E-12 7.8398E-12 7.5086E-12 7.1939E-12 241 6.8951E-12 6.6114E-12 6.3420E-12 6.0865E-12 5.8440E-12 246 5.6141E-12 5.3960E-12 5.1894E-12 4.9936E-12 4.8081E-12 H-3 Concentrations at time =3.500E+02 ,(Delt =1 .000E+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 4.6324E-12 4.4660E-12 4.3085E-12 4.1594E-12 4.0184E-12 256 3.8850E-12 3.7588E-12 3.6395E-12 3.5267E-12 3.4201E-12 261 3.3194E-12 3.2242E-12 3.1343E-12 3.0493E-12 2.9691E-12 266 2.8933E-12 2.8218E-12 2.7543E-12 2.6905E-12 2.6303E-12 271 2.5734E-12 2.5198E-12 2.4691E-12 2.4212E-12 2.3760E-12 276 2.3333E-12 2.2930E-12 2.2549E-12 2.2189E-12 2.1848E-12 281 2.1525E-12 2.1220E-12 2.0931E-12 2.0657E-12 2.0398E-12 286 2.0151E-12 1.9917E-12 1.9695E-12 1.9483E-12 1.9281E-12 291 1.9089E-12 1.8905E-12 1.8729E-12 1.8560E-12 1.8399E-12 296 1.8243E-12 1.8094E-12 1.7950E-12 1.7810E-12 1.7675E-12 301 1.7544E-12 1.7417E-12 1.7293E-12 1.7172E-12 1.7053E-12 306 1.6937E-12 1.6822E-12 1.6709E-12 1.6598E-12 1.6488E-12 311 1.6379E-12 1.6270E-12 1.6162E-12 1.6054E-12 1.5946E-12 316 1.5839E-12 1.5730E-12 1.5622E-12 1.5513E-12 1.5403E-12 321 1.5292E-12 1.5180E-12 1.5068E-12 1.4953E-12 1.4838E-12 326 1.4721E-12 1.4603E-12 1.4482E-12 1.4361 E-12 1.4237E-12 331 1.4111E-12 1.3984E-12 1.3854E-12 1.3723E-12 1.3589E-12 336 1.3453E-1 2 1.3315E-12 1.3174E-12 1.3031 E-1 2 1.2886E-12 341 1.2738E-12 1.2588E-12 1.2435E-12 1.2280E-12 1.2123E-12 346 1.1963E-12 1.1800E-12 1.1635E-12 1.1467E-12 1.1297E-12 351 1.1124E-12 1.0948E-12 1.0770E-12 1.0590E-12 1.0407E-12 356 1.0221E-12 1.0033E-12 9.8426E-13 9.6496E-13 9.4542E-13 361 9.2565E-13 9.0563E-13 8.8539E-13 8.6491E-13 8.4422E-13 366 8.2330E-13 8.0216E-13 7.8081 E-13 7.5926E-13 7.3751 E-13 371 7.1556E-13 6.9342E-13 6.7110E-13 6.4860E-13 6.2592E-13 376 6.0308E-13 5.8009E-13 5.5694E-13 5.3364E-13 5.1021E-13 381 4.8664E-13 4.6296E-13 4.3915E-13 4.1524E-13 3.9123E-13 386 3.6713E-13 3.4294E-13 3.1868E-13 2.9434E-13 2.6995E-13 391 2.4551E-13 2.2102E-13 1.9650E-13 1.7195E-13 1.4739E-13 396 1.2282E-13 1.2255E-13 1.2241E-13 1.2228E-13 1.2214E-13 401 1.2201 E-1 3 1.2187E-13 1.2174E-13 1.2160E-13 1.2147E-13 406 1.1993E-13 1.1831E-13 1.1669E-13 1.1507E-13 1.1345E-13 411 1.1184E-13 1.1022E-13 1.0861E-13 1.0701E-13 1.0541E-13 416 1.0381 E-1 3 1.0391E-13 1.0073E-13 9.7575E-14 9.4443E-14 421 9.1340E-14 8.8269E-14 8.5233E-14 8.2236E-14 7.9279E-14

426 7.6365E-14 7.3496E-14 7.0676E-14 6.7906E-14 6.5187E-14 431 6.2523E-14 5.9913E-14 5.7360E-14 5.4866E-14 5.2430E-14 436 5.0054E-14 4.7738E-14 4.5484E-14 4.3291 E-14 4.1159E-14 441 3.9088E-14 3.7079E-14 3.5130E-14 3.3242E-14 3.1413E-14 446 2.9642E-14 2.7929E-14 2.6272E-14 2.4669E-14 2.3120E-14 451 2.1623E-14 2.0175E-14 1.8775E-14 1.7421E-14 1.6111E-14 456 I A843E-14 1.3613E-14 1.2421E-14 1.1262E-14 1.0136E-14 461 9.0381 E-1 5 7.9667E-1 5 6.9189E-1 5 5.8917E-1 5 4.8823E-1 5 466 3.8879E-1 5 2.9054E-1 5 1.9319E-15 9.6440E-16 2.4103E-16 C-14 Concentrations at time =3.500E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.19E+04 Mass sorbed = O.OOE+00 Total Mass = 2.19E+04 1 2.7612E-18 1.1328E-17 2.5841E-17 4.7303E-17 8.1220E-17 6 1.3599E-16 2.2470E-16 3.6788E-16 5.9756E-16 9.6341E-16 11 1.5420E-1 5 2.4501 E-1 5 3.8652E-15 6.0536E-1 5 9.4130E-15 16 1.4532E-14 2.2274E-14 3.3898E-14 5.1221E-14 7.6847E-14 21 1.1448E-13 1.6934E-13 2.4873E-1 3 3.6281 E-1 3 5.2552E-1 3 26 7.5597E-1 3 1.0800E-12 1.5325E-12 2.1597E-1 2 3.0234E-12 31 4.2044E-12 5.8080E-12 7.9711 E-12 1.0869E-1 1 1.4726E-11 36 1.9826E-11 2.6525E-1 I 3.5269E-1 I 4.6610E-11 6.1229E-1 1 41 7.0104E-1 1 8.0106E-1 I 9.1390E-1 I 1.0410E-10 1.1840E-10 46 1.3446E-10 1.5248E-10 1.7266E-10 1.9523E-10 2.2045E-1 0 51 2.2263E-10 2.2488E-10 2.2715E-10 2.2945E-10 2.3176E-10 56 2.3410E-10 2.3645E-10 2.4389E-10 1.8062E-04 2.2038E-02 61 8.0389E-01 8.2594E-01 8.4966E-01 8.5088E-01 8.7202E-01 66 8.7483E-01 9.5626E-01 9.5684E-01 8.9639E-01 8.8502E-01 71 5.2979E-01 5.1554E-01 3.4985E-01 3.4399E-01 2.9546E-01 76 2.9439E-01 3.0392E-01 3.0271 E-01 2.4928E-01 2.4631 E-01 81 1.9120E-01 1.8866E-01 1.5071 E-01 1.4934E-01 1.3712E-01 86 1.3616E-01 1.1339E-01 1.1213E-01 8.8703E-02 8.7673E-02 91 7.3478E-02 7.2585E-02 5.4108E-02 5.3260E-02 4.0722E-02 96 4.0333E-02 3.8678E-02 3.8470E-02 3.2531 E-02 3.2143E-02 101 2.3892E-02 2.3341 E-02 1.1467E-02 1.1 133E-02 1.0798E-02 106 1.0753E-02 9.4336E-03 9.3614E-03 8.041OE-03 7.9416E-03 111 5.6322E-03 5.5148E-03 3.5353E-03 3.4721E-03 3.1413E-03 116 3.1143E-03 2.4546E-03 2.4366E-03 2.4357E-03 2.3906E-03 121 7.4201 E-04 7.0770E-04 1.1026E-03 1.1054E-03 8.0882E-04 126 8.0792E-04 1.0714E-03 1.0624E-03 4.6886E-04 4.4900E-04 131 3.1686E-04 3.1595E-04 4.1489E-04 4.1760E-04 4.1765E-04 136 4.1855E-04 4.5151E-04 4.5151 E-04 4.1863E-04 4.2314E-04 141 6.2087E-04 6.2268E-04 4.9089E-04 4.8728E-04 4.8721 E-04

146 4.8542E-04 4.2119E-04 5.4395E-04 5.0929E-03 5.0965E-03 151 6.7942E-04 5.5667E-04 4.8912E-04 4.9091E-04 6.2271E-04 156 6.2362E-04 5.2477E-04 5.2206E-04 5.2203E-04 5.2203E-04 161 5.2206E-04 5.2477E-04 6.2359E-04 6.2088E-04 4.2304E-04 166 4.1132E-04 1.8195E-04 2.8845E-04 4.4089E-03 4.4161E-03 171 5.5955E-04 4.5756E-04 5.8792E-04 5.8791E-04 4.5613E-04 176 4.5523E-04 5.5400E-04 5.5129E-04 3.5354E-04 3.4812E-04 181 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 186 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 191 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 196 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 201 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 206 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 211 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 216 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 221 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 226 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 231 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 236 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 241 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 246 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 C-14 Concentrations at time =3.500E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 256 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 261 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 266 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 271 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 276 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 281 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 286 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 291 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 296 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 301 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 306 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 311 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 316 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 321 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 326 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 331 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 336 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 341 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 346 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 351 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 356 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04

361 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 366 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 371 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 376 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 381 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 386 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 3.4805E-04 391 3.4805E-04 3.4805E-04 3.4805E-04 3.4792E-04 3.3884E-04 396 1.2515E-06 1.2508E-06 1.2504E-06 1.2501E-06 1.2496E-06 401 1.2492E-06 1.2487E-06 1.2482E-06 1.2477E-06 1.2472E-06 406 1.2398E-06 1.2292E-06 1.2156E-06 1.1993E-06 1.1802E-06 411 1.1586E-06 1.1345E-06 1.1082E-06 1.0797E-06 1.0493E-06 416 1.0172E-06 1.0194E-06 9.5076E-07 8.7773E-07 8.0203E-07 421 7.2535E-07 6.4928E-07 5.7522E-07 5.0438E-07 4.3772E-07 426 3.7598E-07 3.1964E-07 2.6897E-07 2.2402E-07 1.8469E-07 431 1.5072E-07 1.2175E-07 9.7358E-08 7.7072E-08 6.0402E-08 436 4.6865E-08 3.6002E-08 2.7383E-08 2.0622E-08 1.5379E-08 441 1.1357E-08 8.3055E-09 6.0153E-09 4.3149E-09 3.0656E-09 446 2.1573E-09 1.5038E-09 1.0385E-09 7.1043E-10 4.8151E-10 451 3.2335E-10 2.1515E-10 1.4186E-10 9.2689E-1 1 6.0019E-1 1 456 3.8517E-11 2.4500E-11 1.5447E-11 9.6540E-12 5.9813E-12 461 3.6738E-12 2.2372E-12 1.3505E-12 8.0800E-13 4.7859E-13 466 2.7971E-13 1.5955E-13 8.5606E-14 3.7048E-14 9.0064E-15 H-3 Concentrations at time =3.600E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/rmA3) at nodes 1,1+1,...,1+4 Mass In solution = 6.41E-05 Mass sorbed = O.OOE+00 Total Mass = 6.41 E-05 1 2.4189E-18 9.6772E-18 1.9373E-17 2.9105E-17 3.8892E-17 6 4.8751E-17 5.8700E-17 6.8756E-17 7.8935E-17 8.9256E-17 11 9.9732E-17 1.1038E-16 1.2121E-16 1.3225E-16 1.4350E-16 16 1.5497E-16 1.6669E-16 1.7865E-16 1.9087E-16 2.0336E-16 21 2.1612E-16 2.2917E-16 2.4250E-16 2.5613E-16 2.7006E-16 26 2.8428E-16 2.9881E-16 3.1364E-16 3.2876E-16 3.4419E-16 31 3.5991E-16 3.7592E-16 3.9221E-16 4.0879E-16 4.2563E-16 36 4.4273E-16 4.6008E-16 4.7768E-16 4.9549E-16 5.1353E-16 41 5.2264E-16 5.3178E-16 5.4096E-16 5.5019E-16 5.5946E-16 46 5.6877E-16 5.7812E-16 5.8751E-16 5.9692E-16 6.0637E-16 51 6.0714E-16 6.0793E-16 6.0872E-16 6.0951 E-16 6.1030E-16 56 6.1109E-16 6.1188E-16 6.1434E-16 5.9237E-10 5.9205E-10 61 5.9171E-10 5.9117E-10 5.9045E-10 5.8954E-10 5.8845E-10 66 5.8718E-10 5.8572E-10 5.8408E-10 5.8227E-10 5.8027E-10 71 5.781OE-10 5.7576E-10 5.7324E-10 5.7055E-10 5.6770E-10 76 5.6468E-10 5.6151E-10 5.5817E-10 5.5468E-10 5.5103E-10

81 5.4724E-10 5.4330E-10 5.3922E-10 5.3500E-10 5.3065E-10 86 5.2617E-10 5.2156E-10 5.1682E-10 5.1197E-10 5.0701 E-1 0 91 5.0193E-10 4.9675E-10 4.9147E-10 4.8609E-10 4.8062E-10 96 4.7506E-10 4.6941 E-10 4.6369E-10 4.5789E-10 4.5203E-10 101 4.4609E-10 4.4010E-10 4.3405E-1 0 4.2795E-10 4.2181E-10 106 4.1562E-10 4.0939E-10 4.0314E-10 3.9685E-1 0 3.9054E-10 111 3.8420E-1 0 3.7786E-10 3.7150E-1 0 3.6513E-10 3.5876E-10 116 3.5239E-1 0 3A603E-10 3.3967E-10 3.3333E-10 3.2700E-10 121 3.2070E-10 3.1442E-10 3.0816E-10 3.0194E-1 0 2.9575E-10 126 2.8959E-10 2.8348E-10 2.7741 E-10 2.7138E-10 2.6541E-10 131 2.5948E-10 2.5361E-10 2A780E-10 2.4204E-10 2.3634E-1 0 136 2.3071E-10 2.2514E-10 2.1964E-10 2.1421E-10 2.0885E-10 141 2.0356E-10 1.9834E-10 1.9320E-10 1.8813E-10 1.8314E-10 146 1.7823E-10 1.7339E-10 1.6864E-10 1.6397E-10 1.5938E-10 151 1.5487E-10 1.5044E-10 1.4610E-10 1.4183E-10 1.3765E-10 156 1.3356E-10 1.2955E-10 1.2562E-10 1.2177E-10 1.1801E-10 161 1.1432E-10 1.1072E-10 1.0721E-10 1.0377E-10 1.0041E-10 166 9.7138E-1 I 9.3942E-1 1 9.0825E-1 I 8.7785E-1 1 8.4823E-1 1 171 8.1938E-11 7.9128E-1 I 7.6392E-1 1 7.3731 E-1 1 7.1141E-11 176 6.8624E-1 1 6.6177E-1 1 6.3800E-1 I 6.1491 E-11 5.9250E-1 1 181 5.7074E-11 5.4964E-1 1 5.2917E-1 I 5.0933E-1 1 4.9011E-11 186 4.7148E-1 I 4.5345E-1 I 4.3599E-1 I 4.1910E-11 4.0276E-1 I 191 3.8696E-1 I 3.7169E-1 1 3.5694E-1 1 3.4269E-1 1 3.2893E-1 I 196 3.1565E-1 1 3.0283E-1 1 2.9047E-1 1 2.7856E-1 1 2.6707E-1 1 201 2.5601 E-11 2.4535E-1 1 2.3509E-11 2.2521 E-1 1 2.1571E-1 1 206 2.0657E-1 1 1.9778E-1 1 1.8933E-1 1 1.8122E-1 I 1.7342E-1 1 211 1.6594E-1 1 1.5875E-1 I 1.5186E-1 1 1.4524E-1 I 1.3890E-1 1 216 1.3283E-1 1 1.2700E-1 I 1.2142E-1 1 1.1608E-11 1.1096E-11 221 1.0607E-1 1 1.0139E-11 9.6909E-12 9.2628E-12 8.8536E-1 2 226 8.4627E-12 8.0892E-12 7.7327E-12 7.3924E-12 7.0676E-12 231 6.7578E-12 6.4624E-12 6.1808E-12 5.9123E-12 5.6566E-12 236 5.4131 E-12 5.1811 E-12 4.9604E-12 4.7503E-12 4.5505E-12 241 4.3604E-12 4.1797E-12 4.0080E-12 3.8448E-12 3.6898E-12 246 3.5425E-12 3.4028E-12 3.2701E-12 3.1442E-12 3.0248E-12 H-3 Concentrations at time =3.600E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CiIcmA3) at nodes 1,1+1,...,1+4 251 2.9115E-12 2.8041E-12 2.7024E-12 2.6059E-12 2.5145E-12 256 2.4279E-12 2.3459E-12 2.2683E-12 2.1948E-12 2.1253E-12 261 2.0595E-12 1.9972E-12 1.9383E-12 1.8826E-12 1.8300E-12 266 1.7802E-12 1.7331E-12 1.6886E-12 1.6465E-12 1.6067E-1 2 271 1.5691E-12 1.5336E-12 1.5000E-12 1.4683E-12 1.4383E-12 276 1.4099E-12 1.3831E-12 1.3577E-12 1.3338E-12 1.3110E-12 281 1.2895E-12 1.2692E-12 1.2499E-12 1.2316E-12 1.2143E-12 286 1.1979E-12 1.1822E-12 1.1674E-12 1.1533E-12 1.1398E-12 291 1.1270E-12 1.1148E-12 1.1031E-12 1.0919E-12 1.0812E-12

296 1.0709E-12 1.0611E-12 1.0516E-12 1.0424E-12 1.0336E-12 301 1.0250E-12 1.0167E-12 1.0086E-12 1.0008E-12 9.9313E-13 306 9.8565E-13 9.7832E-13 9.7112E-13 9.6404E-13 9.5706E-13 311 9.5017E-13 9.4335E-13 9.3658E-13 9.2986E-13 9.2316E-13 316 9.1649E-13 9.0982E-13 9.0315E-13 8.9647E-13 8.8976E-13 321 8.8303E-13 8.7625E-13 8.6943E-13 8.6255E-13 8.5561E-13 326 8.4859E-13 8.4151E-13 8.3434E-13 8.2708E-13 8.1973E-13 331 8.1229E-13 8.0474E-13 7.9709E-13 7.8933E-13 7.8145E-13 336 7.7345E-13 7.6534E-13 7.571 OE-13 7.4874E-13 7.4025E-13 341 7.3162E-13 7.2287E-13 7.1398E-13 7.0495E-13 6.9579E-13 346 6.8649E-13 6.7705E-13 6.6747E-13 6.5776E-13 6.4790E-13 351 6.3790E-13 6.2776E-13 6.1748E-13 6.0705E-13 5.9650E-13 356 5.8580E-13 5.7496E-13 5.6399E-13 5.5288E-13 5.4164E-13 361 5.3027E-13 5.1877E-13 5.0714E-13 4.9538E-13 4.8350E-13 366 4.7149E-13 4.5937E-13 4.4713E-13 4.3478E-13 4.2231E-13 371 4.0974E-13 3.9706E-13 3.8428E-13 3.7140E-13 3.5843E-13 376 3.4536E-13 3.3221 E-13 3.1897E-13 3.0565E-13 2.9226E-13 381 2.7879E-1 3 2.6526E-13 2.5166E-13 2.3800E-13 2.2429E-1 3 386 2.1053E-13 1.9671E-13 1.8286E-13 1.6897E-13 1.5505E-13 391 1.4109E-1 3 1.2712E-13 1.1312E-13 9.9111E-14 8.5092E-14 396 7.1068E-14 7.0914E-14 7.0837E-14 7.0760E-14 7.0683E-14 401 7.0606E-14 7.0529E-14 7.0451 E-14 7.0374E-14 7.0297E-14 406 6.9419E-14 6.8494E-14 6.7569E-14 6.6645E-14 6.5722E-14 411 6.4800E-14 6.3880E-14 6.2961E-14 6.2044E-14 6.1130E-14 416 6.0218E-14 6.0277E-14 5.8461E-14 5.6657E-14 5A868E-14 421 5.3094E-14 5.1339E-14 4.9602E-14 4.7887E-14 4.6195E-14 426 4.4526E-14 4.2882E-14 4.1266E-14 3.9677E-14 3.8116E-14 431 3.6586E-14 3.5086E-14 3.3618E-14 3.2182E-14 3.0778E-14 436 2.9408E-14 2.8072E-14 2.6769E-14 2.5501E-14 2.4267E-14 441 2.3067E-14 2.1902E-14 2.0770E-14 1.9671E-14 1.8606E-14 446 1.7574E-14 1.6573E-14 1.5604E-14 1.4666E-14 1.3758E-14 451 1.2878E-14 1.2026E-14 1.1202E-14 1.0403E-14 9.6281E-15 456 8.8769E-15 8.1477E-15 7.4392E-15 6.7499E-15 6.0784E-15 461 5.4233E-15 4.7829E-15 4.1558E-15 3.5403E-15 2.9348E-15 466 2.3377E-15 1.7474E-15 1.1621E-15 5.8016E-16 1.4500E-16 C-14 Concentrations at time =3.600E+02 ,(Delt =1.000E+00)

Node I Concentration (Ci/cm^3) at nodes 1,1+1,...,1+4 Mass in solution = 2.18E+04 Mass sorbed = O.OOE+00 Total Mass = 2.18E+04 1 3.9908E-18 1.6355E-17 3.7110E-17 6.7415E-17 1.1472E-16 6 1.9022E-16 3.1122E-16 5.0448E-16 8.1140E-16 1.2955E-15 11 2.0538E-15 3.2329E-15 5.0532E-15 7.8431E-15 1.2088E-14

16 1.8500E-14 2.8117E-14 4.2436E-14 6.3602E-14 9.4667E-14 21 1.3994E-1 3 2.0544E-13 2.9954E-13 4.3378E-13 6.2394E-1 3 26 8.9144E-13 1.2651E-12 1.7836E-12 2.4981 E-1 2 3.4759E-12 31 4.8052E-1 2 6.6004E-12 9.0088E-12 1.2219E-1 1 1.6470E-1 1 36 2.2063E-11 2.9377E-1 I 3.8882E-1 1 5.1157E-11 6.6915E-1 1 41 7.6452E-1 I 8.7179E-1 I 9.9259E-1 1 1.1284E-10 1.2809E-10 46 1.4520E-1 0 1.6435E-10 1.8577E-10 2.0968E-10 2.3636E-10 51 2.3866E-10 2.4104E-10 2A344E-10 2.4586E-10 2.4831 E-1 0 56 2.5078E-10 2.5327E-10 2.6112E-10 1.9069E-04 2.2619E-02 61 8.0233E-01 8.2494E-01 8.4861E-01 8.4987E-01 8.7095E-01 66 8.7383E-01 9.5504E-01 9.5564E-01 8.9535E-01 8.8368E-01 71 5.2942E-01 5.1480E-01 3.4955E-01 3.4354E-01 2.9514E-01 76 2.9404E-01 3.0354E-01 3.0231 E-01 2.4902E-01 2.4597E-01 81 1.9101E-01 1.8840E-01 1.5056E-01 1A915E-01 1.3696E-01 86 1.3598E-01 1.1327E-01 1.1 198E-01 8.8613E-02 8.7557E-02 91 7.3400E-02 7.2483E-02 5.4057E-02 5.3186E-02 4.0682E-02 96 4.0284E-02 3.8632E-02 3.8419E-02 3.2496E-02 3.2098E-02 101 2.3869E-02 2.3304E-02 1.1462E-02 1.1 120E-02 1.0786E-02 106 1.0739E-02 9.4232E-03 9.3491 E-03 8.0322E-03 7.9303E-03 111 5.6271 E-03 5.5067E-03 3.5325E-03 3.4677E-03 3.1378E-03 116 3.1 1OOE-03 2.4522E-03 2.4337E-03 2.4327E-03 2.3864E-03 121 7.4237E-04 7.0718E-04 1.101OE-03 1.1038E-03 8.0807E-04 126 8.0715E-04 1.0699E-03 1.0606E-03 4.6874E-04 4.4837E-04 131 3.1658E-04 3.1565E-04 4.1432E-04 4.1709E-04 4.1715E-04 136 4.1807E-04 4.5094E-04 4.5094E-04 4.1815E-04 4.2278E-04 141 6.1997E-04 6.2182E-04 4.9040E-04 4.8669E-04 4.8661 E-04 146 4.8478E-04 4.2083E-04 5.4674E-04 5.0831 E-03 5.0868E-03 151 6.8195E-04 5.5604E-04 4.8859E-04 4.9042E-04 6.2186E-04 156 6.2278E-04 5.2421 E-04 5.2143E-04 5.2139E-04 5.2139E-04 161 5.2143E-04 5.2421 E-04 6.2276E-04 6.1998E-04 4.2267E-04 166 4.1065E-04 1.8199E-04 2.9124E-04 4.4003E-03 4.4077E-03 171 5.6180E-04 4.5719E-04 5.8711 E-04 5.8709E-04 4.5568E-04 176 4.5476E-04 5.5325E-04 5.5047E-04 3.5326E-04 3.4771 E-04 181 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 186 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 191 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 196 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 201 3.4763E-04 3A763E-04 3.4763E-04 3.4763E-04 3.4763E-04 206 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3A763E-04 211 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 216 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 221 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 226 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 231 3.4763E-04 3.4763E-04 3A763E-04 3.4763E-04 3.4763E-04 236 3.4763E-04 3.4763E-04 3A763E-04 3.4763E-04 3.4763E-04 241 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 246 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04

C-14 Concentrations at time =3.600E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 256 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 261 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 266 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 271 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 276 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 281 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 286 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 291 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 296 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 301 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 306 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 311 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 316 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 321 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 326 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 331 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 336 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 341 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 346 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 351 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 356 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 361 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 366 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 371 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 376 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 381 3A763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 386 3A763E-04 3.4763E-04 3.4763E-04 3.4763E-04 3.4763E-04 391 3.4763E-04 3.4763E-04 3.4763E-04 3.4750E-04 3.3817E-04 396 1.2343E-06 1.2336E-06 1.2332E-06 1.2328E-06 1.2324E-06 401 1.2319E-06 1.2315E-06 1.2310E-06 1.2305E-06 1.2300E-06 406 1.2228E-06 1.2124E-06 1.1993E-06 1.1835E-06 1.1651E-06 411 1.1442E-06 1.1210E-06 1.0956E-06 1.0681E-06 1.0388E-06 416 1.0078E-06 1.0099E-06 9.4364E-07 8.7300E-07 7.9963E-07 421 7.2513E-07 6.5102E-07 5.7866E-07 5.0921E-07 4.4362E-07 426 3.8263E-07 3.2674E-07 2.7624E-07 2.3123E-07 1.9163E-07 431 1.5725E-07 1.2777E-07 1.0279E-07 8.1889E-08 6.4600E-08 436 5.0467E-08 3.9044E-08 2.9916E-08 2.2701 E-08 1.7062E-08 441 1.2702E-08 9.3663E-09 6.8417E-09 4.9507E-09 3.5490E-09 446 2.5205E-09 1.7736E-09 1.2366E-09 8.5431E-10 5.8485E-1 0 451 3.9678E-10 2.6677E-10 1.7777E-10 1.1741E-10 7.6865E-1 1 456 4.9881E-11 3.2089E-11 2.0466E-11 1.2941E-11 8.1128E-12 461 5.0431 E-1 2 3.1084E-12 1.8996E-12 1.1506E-12 6.8991 E-1 3 466 4.0808E-13 2.3540E-13 1.2751E-13 5.5556E-14 1.3525E-14

H-3 Concentrations at time =4.200E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass In solution = 2.41E-06 Mass sorbed = O.OOE+00 Total Mass = 2.41E-06 1 1.0237E-19 4.0954E-19 8.1962E-19 1.2307E-18 1.6434E-18 6 2.0581E-18 2.4753E-18 2.8955E-18 3.3193E-18 3.7470E-18 11 4.1792E-18 4.6162E-18 5.0584E-18 5.5063E-1 8 5.9603E-18 16 6.4205E-18 6.8875E-18 7.3615E-18 7.8427E-1 8 8.3315E-18 21 8.8279E-18 9.3322E-18 9.8446E-18 1.0365E-1 7 1.0894E-17 26 1.1431E-17 1.1977E-17 1.2530E-17 1.3092E-1 7 1.3663E-1 7 31 1.4241E-17 1.4827E-17 1.5421E-17 1.6023E-17 1.6631E-17 36 1.7247E-17 1.7870E-1 7 1.8498E-17 1.9133E-17 1.9773E-1 7 41 2.0096E-17 2.0420E-1 7 2.0744E-17 2.1070E-17 2.1396E-1 7 46 2.1724E-17 2.2052E-1 7 2.2382E-17 2.2712E-17 2.3042E-17 51 2.3069E-17 2.3097E-1 7 2.3125E-17 2.3152E-17 2.3180E-17 56 2.3207E-17 2.3235E-1 7 2.3321 E-17 2.0714E-1 1 2.0704E-1 I 61 2.0694E-11 2.0677E-1 I 2.0656E-1 I 2.0628E-1 1 2.0595E-1 I 66 2.0556E-11 2.0512E-1 I 2.0463E-1 1 2.0408E-1 1 2.0347E-1 1 71 2.0281 E-11 2.0210E-11 2.0133E-1 1 2.0052E-11 1.9965E-1 1 76 1.9873E-11 1.9776E-1 I 1.9675E-1 1 1.9568E-1 I 1.9457E-1 1 81 1.9341 E-11 1.9220E-1 I 1.9095E-1 1 1.8966E-1 I 1.8832E-1 1 86 1.8694E-1 1 1.8552E-1 1 1.8407E-11 1.8257E-11 1.8104E-11 91 1.7947E-1 1 1.7786E-1 1 1.7622E-11 1.7455E-1 1 1.7285E-1 1 96 1.7112E-11 1.6935E-1 1 1.6757E-1 1 1.6575E-1 1 1.6391 E-1 1 101 1.6205E-11 1.6016E-11 1.5825E-1 I 1.5633E-1 1 1.5438E-1 I 106 1.5242E-11 1.5044E-1 1 1.4844E-1 I 1.4644E-1 1 1.4442E-11 111 1.4239E-11 1.4035E-1 I 1.3830E-1 1 1.3624E-1 1 1.3418E-11 116 1.3212E-11 1.3005E-1 I 1.2798E-1 1 1.2591 E-11 1.2383E-1 I 121 1.2176E-11 1.1969E-11 1.1763E-11 1.1557E-11 1.1351E-11 126 1.1146E-11 1.0942E-1 I 1.0739E-1 1 1.0536E-1 I 1.0335E-1 I 131 1.0135E-11 9.9355E-12 9.7378E-12 9.5414E-12 9.3464E-1 2 136 9.1530E-12 8.9612E-12 8.7711 E-1 2 8.5827E-12 8.3961 E-1 2 141 8.2113E-12 8.0285E-12 7.8477E-12 7.6689E-12 7.4921 E-1 2 146 7.3175E-12 7.1451E-12 6.9748E-12 6.8069E-12 6.6412E-12 151 6.4778E-12 6.3168E-12 6.1581E-12 6.0019E-12 5.8480E-1 2 156 5.6966E-12 5.5477E-1 2 5.4013E-12 5.2573E-12 5.1159E-12 161 4.9769E-12 4.8405E-12 4.7066E-12 4.5752E-12 4.4463E-12 166 4.3199E-12 4.1961 E-12 4.0747E-12 3.9558E-12 3.8394E-12 171 3.7255E-12 3.6141 E-12 3.5051 E-12 3.3985E-12 3.2943E-12 176 3.1926E-12 3.0931 E-1 2 2.9961E-12 2.9013E-12 2.8089E-12 181 2.7187E-12 2.6308E-12 2.5451E-12 2.4616E-12 2.3802E-12 186 2.3010E-12 2.2239E-12 2.1488E-1 2 2.0758E-12 2.0048E-12 191 1.9358E-12 1.8687E-12 1.8035E-12 1.7402E-12 1.6787E-12 196 1.6191E-12 1.5612E-12 1.5050E-12 I A506E-1 2 1.3978E-12

201 1.3466E-12 1.2971 E-1 2 1.2491E-12 1.2026E-12 1.1576E-12 206 1.1141E-12 1.0720E-1 2 1.0313E-12 9.9194E-13 9.5391 E-13 211 9.1717E-13 8.8169E-13 8.4743E-13 8.1436E-13 7.8245E-13 216 7.5167E-13 7.2198E-13 6.9337E-13 6.6579E-13 6.3921E-13 221 6.1362E-13 5.8897E-13 5.6525E-13 5.4242E-13 5.2045E-13 226 4.9932E-13 4.7901 E-13 4.5949E-13 4.4072E-13 4.2270E-13 231 4.0539E-13 3.8877E-13 3.7281E-13 3.5750E-13 3.4282E-13 236 3.2874E-13 3.1523E-13 3.0229E-13 2.8989E-13 2.7801E-13 241 2.6663E-13 2.5573E-13 2.4531 E-13 2.3533E-13 2.2578E-13 246 2.1665E-13 2.0792E-13 1.9957E-13 1.9160E-13 1.8398E-1 3 H-3 Concentrations at time =4.200E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 251 1.7670E-13 1.6975E-1 3 1.6311 E-1 3 1.5678E-13 1.5074E-13 256 1.4497E-13 1.3947E-13 1.3423E-13 1.2923E-13 1.2446E-13 261 1.1992E-13 1.1559E-13 1.1147E-13 1.0755E-13 1.0381E-13 266 1.0025E-13 9.6863E-14 9.3639E-14 9.0572E-14 8.7654E-14 271 8.4878E-14 8.2238E-14 7.9727E-14 7.7339E-14 7.5068E-14 276 7.2909E-14 7.0857E-14 6.8905E-14 6.7050E-14 6.5286E-14 281 6.3608E-14 6.2014E-14 6.0497E-14 5.9055E-14 5.7684E-14 286 5.6379E-14 5.5137E-14 5.3955E-14 5.2830E-14 5.1759E-14 291 5.0739E-14 4.9766E-14 4.8839E-14 4.7954E-14 4.7110E-14 296 4.6303E-14 4.5533E-14 4.4796E-14 4.4090E-14 4.3415E-14 301 4.2767E-14 4.2145E-14 4.1548E-14 4.0973E-14 4.0420E-14 306 3.9887E-14 3.9373E-14 3.8875E-14 3.8394E-14 3.7928E-14 311 3.7475E-14 3.7036E-14 3.6607E-14 3.6190E-14 3.5783E-14 316 3.5384E-14 3.4994E-14 3.4611E-14 3.4235E-14 3.3864E-14 321 3.3499E-14 3.3139E-14 3.2783E-14 3.2430E-14 3.2081E-14 326 3.1734E-14 3.1389E-14 3.1045E-14 3.0703E-14 3.0362E-14 331 3.0021E-14 2.9680E-14 2.9340E-14 2.8998E-14 2.8656E-14 336 2.8312E-14 2.7968E-14 2.7621E-14 2.7273E-14 2.6923E-14 341 2.6571E-14 2.6217E-14 2.5860E-14 2.5500E-14 2.5138E-14 346 2.4773E-14 2.4404E-14 2.4033E-14 2.3658E-14 2.3281 E-14 351 2.2900E-14 2.2515E-14 2.2127E-14 2.1736E-14 2.1341 E-14 356 2.0943E-14 2.0541E-14 2.0136E-14 1.9727E-14 1.9315E-14 361 1.8899E-14 1.8480E-14 1.8057E-14 1.7631E-14 1.7202E-14 366 1.6769E-14 1.6333E-14 1.5894E-14 1.5451E-14 1.5006E-14 371 1.4558E-14 1.4106E-14 1.3652E-14 1.3195E-14 1.2736E-14 376 1.2274E-14 1.1809E-14 1.1343E-14 1.0873E-14 1.0402E-14 381 9.9289E-15 9.4537E-15 8.9768E-15 8.4981 E-15 8.0178E-15 386 7.5362E-15 7.0532E-15 6.5690E-15 6.0837E-15 5.5976E-15 391 5.1106E-15 4.6229E-15 4.1347E-15 3.6461E-15 3.1573E-15 396 2.6682E-15 2.6629E-1 5 2.6602E-15 2.6575E-15 2.6548E-15 401 2.6521E-15 2.6494E-15 2.6468E-15 2.6441E-15 2.6414E-15 406 2.6108E-15 2.5785E-15 2.5463E-15 2.5140E-15 2.4818E-15 411 2.4497E-15 2.4176E-15 2.3855E-15 2.3535E-15 2.3216E-15

416 2.2897E-15 2.291 BE- 5 2.2283E-1 5 2.1651E-15 2.1024E-15 421 2.0401 E-1 5 1.9784E-1 5 1.9172E-1 5 1.8566E-1 5 1.7967E-15 426 1.7375E-1 5 1.6791 E-1 5 1.6214E-15 1.5645E-1 5 1.5085E-15 431 1.4534E-1 5 1.3992E-1 5 1.3459E-1 5 1.2935E-1 5 1.2422E-15 436 1.1918E-15 1.1424E-15 1.0941 E-15 1.0467E-1 5 1.0004E-1 5 441 9.5513E-16 9.1087E-16 8.6764E-1 6 8.2542E-1 6 7.8421 E-1 6 446 7.4398E-1 6 7.0473E-1 6 6.6644E-16 6.2909E-16 5.9265E-16 451 5.5709E-1 6 5.2239E-16 4.8851 E-1 6 4.5543E-16 4.2311E-16 456 3.9151 E-1 6 3.6058E-1 6 3.3030E-1 6 3.0062E-16 2.7148E-16 461 2.4286E-1 6 2.1470E-1 6 1.8695E-16 1.5956E-1 6 1.3248E-16 466 1.0567E-1 6 7.9067E-17 5.2623E-17 2.6284E-17 6.5698E-18 C-14 Concentrations at time =4.200E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.17E+04 Mass sorbed = O.OOE+00 Total Mass = 2.17E+04 I 2.6898E-17 1.0966E-16 2.4247E-16 4.2430E-16 6.9033E-16 6 1.0902E-15 1.6959E-15 2.6129E-1 5 3.9957E-1 5 6.0697E-15 11 9.1619E-15 1.3744E-14 2.0491E-14 3.0363E-14 4.4719E-14 16 6.5463E-14 9.5252E-14 1.3776E-1 3 1.9806E-13 2.8304E-13 21 4.0209E-1 3 5.6784E-1 3 7.9721 E-1 3 1.1127E-12 1.5441E-12 26 2.1303E-12 2.9223E-1 2 3.9861 E-1 2 5.4065E-12 7.2921 E-1 2 31 9.781 OE-1 2 1.3047E-11 1.7310E-11 2.2843E-1 I 2.9984E-1 I 36 3.9150E-1 I 5.0853E-1 I 6.5717E-1 I 8.4495E-1 1 1.0810E-10 41 1.2215E-10 1.3781E-10 1.5527E-10 1.7471E-10 1.9635E-10 46 2.2039E-10 2.4707E-10 2.7665E-10 3.0940E-10 3.4562E-10 51 3.4874E-1 0 3.5195E-10 3.5520E-10 3.5847E-10 3.6176E-10 56 3.6509E-10 3.6844E-10 3.7900E-10 2.5632E-04 2.6046E-02 61 7.9302E-01 8.1898E-01 8.4237E-01 8.4381 E-01 8.6457E-01 66 8.6788E-01 9.4776E-01 9.4844E-01 8.8909E-01 8.7571 E-01 71 5.2716E-01 5.1038E-01 3.4776E-01 3.4086E-01 2.9322E-01 76 2.9197E-01 3.0129E-01 2.9988E-01 2.4745E-01 2.4395E-01 81 1.8988E-01 1.8688E-01 1.4964E-01 1.4802E-01 1.3602E-01 86 1.3489E-01 1.1255E-01 1.1106E-01 8.8075E-02 8.6864E-02 91 7.2930E-02 7.1878E-02 5.3747E-02 5.2748E-02 4.0444E-02 96 3.9987E-02 3.8359E-02 3.8115E-02 3.2286E-02 3.1829E-02 101 2.3732E-02 2.3084E-02 1.1433E-02 1.1 039E-02 1.0709E-02 106 1.0656E-02 9.3608E-03 9.2757E-03 7.9797E-03 7.8628E-03 111 5.5965E-03 5.4583E-03 3.5158E-03 3.4414E-03 3.11165E-03 116 3.0846E-03 2.4374E-03 2.4161E-03 2A149E-03 2.3618E-03 121 7.4445E-04 7.0407E-04 1.0912E-03 1.0944E-03 8.0360E-04 126 8.0253E-04 1.0609E-03 1.0503E-03 4.6799E-04 4.4462E-04 131 3.1490E-04 3.1383E-04 4.1088E-04 4.1406E-04 4.1413E-04

136 4.1520E-04 4.4752E-04 4.4752E-04 4.1530E-04 4.2061 E-04 141 6.1458E-04 6.1670E-04 4.8744E-04 4.8319E-04 4.8309E-04 146 4.8099E-04 4.1872E-04 5.6320E-04 5.0254E-03 5.0296E-03 151 6.9682E-04 5.5234E-04 4.8538E-04 4.8748E-04 6.1676E-04 156 6.1782E-04 5.2086E-04 5.1768E-04 5.1762E-04 5.1762E-04 161 5.1768E-04 5.2086E-04 6.1778E-04 6.1460E-04 4.2047E-04 166 4.0669E-04 1.8228E-04 3.0764E-04 4.3495E-03 4.3580E-03 171 5.7506E-04 4.5501E-04 5.8226E-04 5.8224E-04 4.5299E-04 176 4.5193E-04 5.4878E-04 5.4559E-04 3.5159E-04 3.4522E-04 181 3A512E-04 3.4511 E-04 3.4511 E-04 3.4511E-04 3.4511 E-04 186 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 191 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 196 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 201 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 206 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 211 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 216 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 221 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 226 3.4511 E-04 3.4511E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 231 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 236 3.4511 E-04 3A511 E-04 3.4511 E-04 3A511 E-04 3.4511 E-04 241 3.4511 E-04 3A511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 246 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 C-14 Concentrations at time =4.200E+02 (Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.4511E-04 3.4511 E-04 3.4511E-04 3.4511 E-04 3.4511 E-04 256 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 261 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 266 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 271 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 276 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 281 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 286 3.4511 E-04 3.4511 E-04 3A511 E-04 3A511 E-04 3.4511 E-04 291 3.4511 E-04 3A511 E-04 3.4511 E-04 3.4511 E-04 3A511E-04 296 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 301 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 306 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 311 3.4511E-04 3.4511 E-04 3.4511E-04 3.4511E-04 3.4511E-04 316 3.4511E-04 3.4511E-04 3.4511E-04 3.4511E-04 3.4511E-04 321 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 326 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 331 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 336 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 341 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 346 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04

351 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 356 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 361 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 366 3.4511E-04 3.4511E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 371 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 376 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 381 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 386 3A511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4511 E-04 391 3.4511 E-04 3.4511 E-04 3.4511 E-04 3.4494E-04 3.3420E-04 396 1.1440E-06 1.1433E-06 1.1430E-06 1.1426E-06 1.1422E-06 401 1.1418E-06 1.1414E-06 1.1409E-06 1.1405E-06 1.1400E-06 406 1.1335E-06 1.1246E-06 1.1135E-06 1.1003E-06 1.0851 E-06 411 1.0678E-06 1.0487E-06 1.0279E-06 1.0053E-06 9.8119E-07 416 9.5567E-07 9.5738E-07 9.0263E-07 8.4385E-07 7.8223E-07 421 7.1895E-07 6.5517E-07 5.9196E-07 5.3029E-07 4.7098E-07 426 4.1473E-07 3.6208E-07 3.1341 E-07 2.6897E-07 2.2887E-47 431 1.9308E-07 1.6151E-07 1.3395E-07 1.1016E-07 8.9827E-08 436 7.2630E-08 5.8233E-08 4.6298E-08 3.6502E-08 2.8539E-08 441 2.2128E-08 1.7015E-08 1.2976E-08 9.8148E-09 7.3628E-09 446 5.4785E-09 4.0433E-09 2.9600E-09 2.1496E-09 1.5485E-09 451 1.1066E-09 7.8457E-10 5.5185E-10 3.8511 E-10 2.6665E-10 456 1.8319E-10 1.2488E-10 8.4473E-1 I 5.6703E-1 1 3.7771'E-11 461 2.4968E-1 I 1.6378E-1 1 1.0657E-1 I 6.8755E-1 2 4.3891 E-1 2 466 2.7584E-12 1.6828E-12 9.5535E-1 3 4.3005E-1 3 1.0538E-1 3 H-3 Concentrations at time =4.500E+02 ,(Delt =1 .OOOE+00)

Node I Concentration (CiVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 4.67E-07 Mass sorbed = O.OOE+00 Total Mass = 4.67E-07 1 2.0739E-20 8.2964E-20 1.6602E-19 2.4924E-19 3.3272E-19 6 4.1655E-19 5.0080E-19 5.8556E-19 6.7090E-19 7.5691 E-19 11 8.4365E-19 9.3121E-19 1.0196E-18 1.1090E-18 1.1994E-18 16 1.2908E-18 1.3834E-18 1.4771 E-18 1.5721 E-18 1.6683E-18 21 1.7657E-18 1.8645E-18 1.9646E-18 2.0661E-18 2.1689E-18 26 2.2732E-18 2.3787E-18 2.4857E-18 2.5940E-18 2.7037E-18 31 2.8147E-18 2.9270E-18 3.0406E-18 3.1554E-18 3.2714E-18 36 3.3885E-18 3.5066E-18 3.6258E-18 3.7460E-18 3.8670E-18 41 3.9279E-18 3.9889E-18 4.0501 E-18 4.1115E-18 4.1730E-18 46 4.2346E-18 4.2964E-18 4.3583E-18 4.4203E-18 4A825E-18 51 4.4875E-1 8 4.4927E-18 4.4979E-18 4.5031 E-18 4.5082E-18 56 4.5134E-18 4.5186E-18 4.5348E-18 3.8871E-12 3.8854E-12 61 3.8836E-12 3.8807E-12 3.8769E-12 3.8721E-12 3.8663E-12 66 3.8595E-12 3.8517E-12 3.8430E-12 3.8333E-12 3.8226E-12

71 3.811 OE-12 3.7985E-12 3.7850E-12 3.7706E-12 3.7553E-12 76 3.7391E-12 3.7220E-12 3.7041 E-12 3.6853E-12 3.6656E-12 81 3.6452E-12 3.6239E-12 3.6018E-12 3.5789E-12 3.5553E-12 86 3.5309E-12 3.5058E-12 3.4800E-12 3.4534E-12 3.4262E-12 91 3.3984E-12 3.3699E-12 3.3408E-12 3.3111E-12 3.2808E-12 96 3.2500E-12 3.2187E-12 3.1868E-12 3.1544E-12 3.1216E-12 101 3.0883E-12 3.0546E-12 3.0205E-12 2.9860E-12 2.9512E-12 106 2.9160E-12 2.8805E-12 2.8447E-12 2.8086E-12 2.7723E-12 111 2.7358E-12 2.6991 E-12 2.6621 E-1 2 2.6250E-12 2.5878E-12 116 2.5504E-12 2.5130E-12 2.4755E-12 2.4379E-12 2.4002E-12 121 2.3626E-1 2 2.3249E-12 2.2873E-12 2.2497E-12 2.2122E-12 126 2.1747E-12 2.1374E-12 2.1001 E-12 2.0630E-12 2.0260E-12 131 1.9892E-12 1.9525E-12 1.9161 E-12 1.8798E-12 1.8438E-12 136 1.8080E-1 2 1.7725E-12 1.7372E-12 1.7022E-12 1.6674E-12 141 1.6330E-1 2 1.5989E-12 1.5651 E-12 1.5316E-12 1.4985E-12 146 1.4657E-12 1.4333E-1 2 1.4013E-12 1.3696E-12 1.3383E-12 151 1.3074E-12 1.2769E-1 2 1.2468E-12 1.2171 E-12 1.1878E-12 156 1.1589E-12 1.1305E-12 1.1025E-12 1.0749E-12 1.0477E-12 161 1.0210E-12 9.9473E-1 3 9.6889E-1 3 9.4348E-13 9.1852E-13 166 8.9400E-13 8.6992E-1 3 8.4628E-1 3 8.2309E-13 8.0034E-13 171 7.7803E-13 7.5616E-1 3 7.3473E-1 3 7.1373E-1 3 6.9317E-13 176 6.7304E-13 6.5333E-13 6.3406E-1 3 6.1521 E-13 5.9677E-13 181 5.7876E-13 5.6115E-13 5.4396E-1 3 5.2717E-13 5.1077E-13 186 4.9478E-13 4.7917E-1 3 4.6395E-1 3 4.4912E-13 4.3465E-13 191 4.2056E-13 4.0684E-13 3.9347E-1 3 3.8046E-13 3.6780E-1 3 196 3.5548E-13 3.4350E-13 3.3185E-1 3 3.2053E-1 3 3.0953E-13 201 2.9884E-13 2.8846E-13 2.7838E-1 3 2.6861 E-1 3 2.5912E-1 3 206 2.4992E-13 2.4099E-13 2.3234E-1 3 2.2396E-1 3 2.1584E-13 211 2.0797E-13 2.0035E-13 1.9298E-13 1.8585E-1 3 1.7894E-13 216 1.7227E-13 1.6581 E-13 1.5957E-13 1.5354E-1 3 1.4772E-13 221 1.4210E-13 1.3667E-13 1.3142E-13 1.2637E-1 3 1.2149E-1 3 226 1.1678E-13 1.1224E-13 1.0787E-13 1.0365E-1 3 9.9595E-14 231 9.5685E-14 9.1920E-14 8.8296E-14 8.4809E-14 8.1454E-14 236 7.8227E-14 7.5125E-14 7.2143E-14 6.9276E-14 6.6523E-14 241 6.3878E-14 6.1338E-14 5.8900E-14 5.6560E-14 5.4314E-14 246 5.2160E-14 5.0095E-14 4.8114E-14 4.6216E-14 4.4396E-14 H-3 Concentrations at time =4.500E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 4.2653E-14 4.0984E-14 3.9385E-14 3.7854E-14 3.6389E-14 256 3A987E-14 3.3646E-14 3.2363E-14 3.1136E-14 2.9963E-14 261 2.8842E-14 2.7771E-14 2.6747E-14 2.5769E-14 2.4835E-14 266 2.3944E-14 2.3092E-14 2.2279E-14 2.1504E-14 2.0763E-14 271 2.0057E-14 1.9384E-14 1.8741 E-14 1.8128E-14 1.7544E-14 276 1.6987E-14 1.6456E-14 1.5950E-14 1.5467E-14 1.5007E-14 281 1.4569E-14 1.A151E-14 1.3753E-14 1.3373E-14 1.3011 E-14

286 1.2666E-14 1.2338E-14 1.2024E-14 1.1725E-14 1.1440E-14 291 1.1169E-14 1.0909E-14 1.0662E-14 1.0426E-14 1.0200E-14 296 9.9846E-15 9.7787E-15 9.5819E-15 9.3936E-15 9.2135E-15 301 9.0409E-15 8.8756E-1 5 8.7171 E-1 5 8.5651E-15 8.4191 E-15 306 8.2787E-15 8.1438E-15 8.0138E-15 7.8886E-15 7.7678E-15 311 7.6512E-15 7.5384E-15 7.4292E-15 7.3234E-15 7.2208E-15 316 7.1211E-15 7.0241E-15 6.9296E-15 6.8375E-15 6.7475E-15 321 6.6595E-15 6.5733E-15 6.4888E-15 6.4057E-15 6.3241E-15 326 6.2437E-15 6.1645E-15 6.0862E-15 6.0088E-15 5.9323E-15 331 5.8564E-15 5.7811 E-15 5.7064E-15 5.6320E-15 5.5580E-15 336 5.4843E-15 5.4108E-15 5.3374E-15 5.2642E-15 5.1909E-15 341 5.1176E-15 5.0442E-15 4.9707E-15 4.8971 E-15 4.8232E-15 346 4.7491E-15 4.6747E-15 4.6000E-15 4.5250E-15 4.4496E-15 351 4.3738E-15 4.2976E-15 4.2210E-15 4.1440E-15 4.0664E-15 356 3.9885E-15 3.9100E-15 3.8311 E-15 3.7517E-15 3.6717E-15 361 3.5913E-15 3.5103E-15 3.4289E-15 3.3469E-15 3.2645E-15 366 3.1815E-15 3.0981E-15 3.0141E-15 2.9297E-15 2.8448E-15 371 2.7595E-15 2.6737E-15 2.5874E-15 2.5007E-15 2.4136E-15 376 2.3261E-15 2.2382E-15 2.1499E-15 2.0613E-15 1.9723E-15 381 1.8830E-15 1.7933E-15 1.7034E-15 1.6132E-15 1.5228E-15 386 1.4321E-15 1.3412E-15 1.2502E-15 1.1589E-15 1.0675E-15 391 9.7598E-16 8.8434E-16 7.9262E-16 7.0082E-16 6.0899E-16 396 5.1713E-16 5.1612E-16 5.1562E-16 5.1511E-16 5.1461E-16 401 5.1410E-16 5.1360E-16 5.1309E-16 5.1259E-16 5.1208E-1 6 406 5.0633E-16 5.0027E-16 4.9422E-16 4.8817E-16 4.8212E-16 411 4.7608E-16 4.7005E-16 4.6403E-16 4.5801E-16 4.5201E-16 416 4.4603E-16 4.4642E-16 4.3448E-16 4.2261E-16 4.1081E-16 421 3.9909E-16 3.8746E-16 3.7593E-16 3.6451E-16 3.5320E-16 426 3.4201E-16 3.3094E-16 3.2002E-16 3.0923E-16 2.9859E-16 431 2.881OE-16 2.7777E-1 6 2.6760E-16 2.5759E-16 2.4775E-16 436 2.3808E-16 2.2859E-16 2.1927E-16 2.1013E-16 2.0117E-16 441 1.9238E-16 1.8378E-16 1.7535E-16 1.6709E-16 1.5902E-16 446 1.5111E-16 1.4337E-16 1.3580E-16 1.2840E-16 1.2115E-16 451 1.1405E-16 1.0711E-16 1.0031 E-1 6 9.3650E-17 8.7122E-17 456 8.0719E-17 7.4435E-17 6.8264E-17 6.2197E-17 5.6226E-17 461 5.0345E-17 4.4544E-17 3.8816E-17 3.3151E-17 2.7542E-17 466 2.1978E-17 1.6451E-17 1.0952E-17 5.4710E-18 1.3675E-18 C-14 Concentrations at time =4.500E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.16E+04 Mass sorbed = O.OOE+00 Total Mass = 2.16E+04 1 5.9720E-17 2A300E-16 5.3199E-16 9.1748E-16 1.4664E-15

6 2.2709E-15 3.4609E-15 5.2228E-15 7.8231 E-1 5 1.1643E-14 11 1.7223E-14 2.5328E-14 3.7033E-14 5.3837E-14 7.7820E-14 16 1.1185E-13 1.5985E-1 3 2.2718E-13 3.2104E-13 4.5117E-1 3 21 6.3052E-1 3 8.7632E-1 3 1.2113E-12 1.6651E-12 2.2767E-12 26 3.0961 E-12 4.1880E-12 5.6350E-12 7.5423E-12 1.0043E-1 I 31 1.3303E-1 1 1.7531E-11 2.2987E-1 I 2.9990E-1 1 3.8933E-11 36 5.0295E-1 1 6.4659E-1 1 8.2728E-1 I 1.0535E-10 1.3353E-10 41 1.5020E-10 1.6869E-10 1.8922E-10 2.1201E-10 2.3725E-10 46 2.6520E-10 2.9611 E-1 0 3.3024E-10 3.6790E-10 4.0941E-10 51 4.1297E-10 4.1664E-10 4.2035E-10 4.2409E-10 4.2785E-10 56 4.3165E-10 4.3547E-10 4.4752E-10 2.9243E-04 2.7724E-02 61 7.8842E-01 8.1600E-01 8.3927E-01 8.4080E-01 8.6140E-01 66 8.6491 E-01 9.4415E-01 9.4487E-01 8.8598E-01 8.7175E-01 71 5.2602E-01 5.0819E-01 3.4686E-01 3.3953E-01 2.9227E-01 76 2.9093E-01 3.0018E-01 2.9868E-01 2.4666E-01 2.4295E-01 81 1.8931E-01 1.8612E-01 1.4918E-01 1.4746E-01 1.3555E-01 86 1.3436E-01 1.1219E-01 1.1061E-01 8.7807E-02 8.6519E-02 91 7.2696E-02 7.1578E-02 5.3592E-02 5.2531 E-02 4.0325E-02 96 3.9839E-02 3.8224E-02 3.7964E-02 3.2182E-02 3.1696E-02 101 2.3663E-02 2.2975E-02 1.1417E-02 1.10OOE-02 1.0671 E-02 106 1.0614E-02 9.3297E-03 9.2393E-03 7.9535E-03 7.8293E-03 111 5.5812E-03 5.4344E-03 3.5074E-03 3.4284E-03 3.1059E-03 116 3.0720E-03 2.4300E-03 2.4074E-03 2.4060E-03 2.3496E-03 121 7.4543E-04 7.0252E-04 1.0864E-03 1.0898E-03 8.0136E-04 126 8.0023E-04 1.0564E-03 1.0451 E-03 4.6760E-04 4.4276E-04 131 3.1406E-04 3.1292E-04 4.0917E-04 4.1256E-04 4.1264E-04 136 4.1377E-04 4.4583E-04 4.4583E-04 4.1389E-04 4.1953E-04 141 6.1191 E-04 6.1416E-04 4.8597E-04 4.8145E-04 4.8133E-04 146 4.7911 E-04 4.1770E-04 5.7123E-04 4.9968E-03 5.0013E-03 151 7.0406E-04 5.5053E-04 4.8378E-04 4.8601E-04 6.1422E-04 156 6.1535E-04 5.1919E-04 5.1581E-04 5.1575E-04 5.1575E-04 161 5.1581E-04 5.1919E-04 6.1531 E-04 6.1192E-04 4.1937E-04 166 4.0472E-04 1.8245E-04 3.1566E-04 4.3243E-03 4.3333E-03 171 5.8151 E-04 4.5395E-04 5.7985E-04 5.7983E-04 4.5165E-04 176 4.5052E-04 5.4656E-04 5.4317E-04 3.5076E-04 3A398E-04 181 3.4387E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 186 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 191 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 196 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 201 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 206 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 211 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 216 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 221 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 226 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 231 3.4386E-04 3.4386E-04 3.4386E-04 3A386E-04 3.4386E-04 236 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 241 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 246 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04

C-14 Concentrations at Ume =4.500E+02 ,(Det =1.000E+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 256 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 261 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 266 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 271 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 276 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 281 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 286 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 291 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 296 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 301 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 306 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 311 3.4386E-04 3.4386E-04 3A386E-04 3.4386E-04 3.4386E-04 316 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 321 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 326 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 331 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 336 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 341 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 346 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 351 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 356 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 361 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 366 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 371 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 376 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 381 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 386 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 3.4386E-04 391 3.4386E-04 3.4386E-04 3.4386E-04 3.4366E-04 3.3224E-04 396 1.1058E-06 1.1051E-06 1.1048E-06 1.1044E-06 1.1040E-06 401 1.1036E-06 1.1032E-06 1.1028E-06 1.1023E-06 1.1019E-06 406 1.0957E-06 1.0873E-06 1.0770E-06 1.0648E-06 1.0507E-06 411 1.0349E-06 1.0174E-06 9.9822E-07 9.7755E-07 9.5546E-07 416 9.3205E-07 9.3363E-07 8.8337E-07 8.2929E-07 7.7239E-07 421 7.1372E-07 6.5428E-07 5.9503E-07 5.3684E-07 4.8048E-07 426 4.2662E-07 3.7577E-07 3.2834E-07 2.8462E-07 2.4475E-07 431 2.0879E-07 1.7670E-07 1.4836E-07 1.2357E-07 1.0211 E-07 436 8.3716E-08 6.8093E-08 5.4950E-08 4.3997E-08 3.4952E-08 441 2.7550E-08 2.1547E-08 1.6721 E-08 1.2876E-08 9.8394E-09 446 7.4610E-09 5.6143E-09 4.1925E-09 3.1071E-09 2.2853E-09 451 1.6682E-09 1.2086E-09 8.6911E-10 6.2033E-10 4.3949E-10 456 3.0908E-10 2.1577E-10 1.4953E-10 1.0287E-10 7.0256E-1 1 461 4.7632E-11 3.2055E-11 2.1405E-11 1.4170E-11 9.2788E-12 466 5.9753E-12 3.7268E-12 2.1546E-12 9.8201E-13 2.4123E-13

H-3 Concentrations at time =4.900E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 5.24E-08 Mass sorbed = O.OOE+00 Total Mass = 5.24E-08 1 2.4391 E-21 9.7571 E-21 1.9522E-20 2.9303E-20 3.9108E-20 6 4.8944E-20 5.8819E-20 6.8741 E-20 7.8716E-20 8.8752E-20 11 9.8856E-20 1.0903E-1 9 1.1929E-19 1.2964E-19 1.4007E-19 16 1.5061 E-19 1.6124E-19 1.7198E-19 1.8283E-19 1.9380E-19 21 2.0488E-19 2.1608E-19 2.2740E-19 2.3884E-19 2.5041 E-1 9 26 2.621OE-19 2.7392E-19 2.8585E-19 2.9791 E-1 9 3.1009E-19 31 3.2239E-19 3.3480E-19 3.4733E-1 9 3.5996E-19 3.7269E-19 36 3.8552E-19 3.9844E-19 4.1145E-1 9 4.2454E-19 4.3770E-19 41 4.4432E-19 4.5093E-19 4.5757E-1 9 4.6421E-19 4.7087E-19 46 4.7754E-19 4.8422E-19 4.9090E-19 4.9760E-19 5.0430E-19 51 5.0484E-19 5.0540E-19 5.0596E-19 5.0652E-19 5.0708E-19 56 5.0764E-19 5.0820E-19 5.0994E-19 4.1889E-13 4.1873E-13 61 4.1854E-1 3 4.1826E-13 4.1788E-13 4.1740E-13 4.1682E-13 66 4.1614E-13 4.1537E-13 4.1450E-13 4.1354E-13 4.1248E-13 71 4.1132E-13 4.1007E-1 3 4.0873E-13 4.0730E-1 3 4.0577E-13 76 4.0416E-1 3 4.0246E-1 3 4.0067E-13 3.9879E-13 3.9683E-13 81 3.9478E-13 3.9265E-1 3 3.9045E-13 3.8816E-13 3.8579E-13 86 3.8335E-13 3.8083E-1 3 3.7825E-13 3.7559E-13 3.7286E-13 91 3.7006E-13 3.6720E-13 3.6427E-13 3.6128E-13 3.5823E-13 96 3.5513E-13 3.5196E-13 3.4875E-13 3.4548E-13 3.4216E-1 3 101 3.3879E-13 3.3538E-13 3.3192E-13 3.2843E-13 3.2489E-1 3 106 3.2131 E-1 3 3.1770E-13 3.1406E-1 3 3.1038E-13 3.0668E-1 3 111 3.0295E-13 2.9919E-13 2.9541 E-13 2.9161E-13 2.8779E-1 3 116 2.8396E-13 2.8011 E-13 2.7624E-13 2.7237E-13 2.6849E-13 121 2.6460E-13 2.6071 E-13 2.5681 E-1 3 2.5291 E-13 2.4902E-13 126 2.4512E-13 2.4123E-13 2.3735E-13 2.3347E-13 2.2961 E-13 131 2.2575E-13 2.2191 E-1 3 2.1808E-13 2.1427E-13 2.1048E-13 136 2.0670E-13 2.0295E-13 1.9922E-13 1.9551 E-13 1.9182E-13 141 1.8817E-13 1.8453E-13 11.8093E-13 1.7735E-13 1.7381 E-13 146 1.7030E-13 1.6682E-13 1.6337E-13 1.5996E-1 3 1.5658E-13 151 1.5324E-13 1.4993E-13 1.4667E-13 1.4344E-1 3 1.4025E-13 156 1.3710E-13 1.3398E-13 1.3091E-13 1.2789E-1 3 1.2490E-13 161 1.2195E-13 1.1905E-13 1.1619E-13 1.1337E-13 1.1060E-13 166 1.0786E-1 3 1.0518E-13 1.0253E-13 9.9934E-14 9.7378E-14 171 9.4867E-14 9.2399E-14 8.9975E-14 8.7595E-14 8.5260E-14 176 8.2968E-14 8.0719E-14 7.8514E-14 7.6353E-14 7.4234E-14 181 7.2159E-14 7.0126E-14 6.8135E-14 6.6187E-14 6.4280E-14 186 6.2415E-14 6.0590E-14 5.8807E-14 5.7063E-14 5.5360E-14

191 5.3695E-14 5.2070E-14 5.0483E-14 4.8935E-14 4.7424E-14 196 4.5949E-14 4.4512E-14 4.3111 E-14 4.1745E-14 4.0414E-14 201 3.9118E-14 3.7855E-14 3.6626E-14 3.5430E-14 3.4266E-14 206 3.3134E-14 3.2034E-14 3.0963E-14 2.9923E-14 2.8912E-14 211 2.7931E-14 2.6977E-14 2.6052E-14 2.5153E-14 2.4281E-14 216 2.3436E-14 2.2616E-14 2.1821 E-14 2.1050E-14 2.0303E-14 221 1.9579E-14 1.8879E-14 1.8200E-14 1.7543E-14 1.6908E-14 226 1.6293E-14 1.5698E-14 1.5123E-14 1.4567E-14 1.4029E-14 231 1.3510E-14 1.3008E-14 1.2524E-14 1.2056E-14 1.1604E-14 236 1.1169E-14 1.0748E-14 1.0343E-14 9.9521E-15 9.5752E-15 241 9.2120E-15 8.8620E-15 8.5248E-15 8.2001E-15 7.8874E-15 246 7.5864E-15 7.2968E-15 7.0181E-15 6.7500E-15 6.4922E-15 H-3 Concentrations at time =4.900E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcnV3) at nodes 1,1+1,...,1+4 251 6.2443E-15 6.0061E-15 5.7771E-15 5.5571E-15 5.3458E-15 256 5.1428E-15 4.9479E-15 4.7609E-15 4.5813E-15 4.4091E-15 261 4.2438E-15 4.0853E-15 3.9333E-15 3.7876E-15 3.6479E-15 266 3.5141E-15 3.3858E-15 3.2630E-15 3.1453E-15 3.0326E-15 271 2.9247E-15 2.8214E-15 2.7226E-15 2.6280E-15 2.5374E-15 276 2.4508E-15 2.3680E-15 2.2887E-15 2.2129E-15 2.1404E-15 281 2.0711E-15 2.0049E-15 1.9415E-15 1.8810E-15 1.8231E-15 286 1.7678E-15 1.7149E-15 1.6643E-15 1.6160E-15 1.5698E-15 291 1.5256E-15 1.4834E-15 1.4431E-15 1.4045E-15 1.3676E-15 296 1.3323E-15 1.2985E-15 1.2662E-1 5 1.2352E-15 1.2056E-15 301 1.1773E-15 1.1501E-15 1.1241E-15 1.0991E-15 1.0752E-15 306 1.0522E-15 1.0302E-15 1.0090E-15 9.8862E-16 9.6904E-16 311 9.5019E-16 9.3205E-16 9.1456E-16 8.9769E-16 8.8140E-16 316 8.6567E-16 8.5045E-16 8.3572E-16 8.2145E-16 8.0762E-16 321 7.9418E-16 7.8112E-16 7.6842E-16 7.5604E-16 7.4398E-16 326 7.3220E-16 7.2069E-16 7.0943E-16 6.9839E-16 6.8758E-16 331 6.7695E-16 6.6651E-16 6.5624E-16 6.4611E-16 6.3613E-16 336 6.2627E-16 6.1653E-16 6.0689E-16 5.9735E-16 5.8789E-1 6 341 5.7850E-16 5.6918E-16 5.5992E-16 5.5070E-16 5.4153E-1 6 346 5.3239E-16 5.2329E-16 5.1420E-16 5.0513E-16 4.9607E-1 6 351 4.8702E-16 4.7798E-16 4.6893E-16 4.5987E-16 4.5081E-16 356 4.4174E-16 4.3265E-16 4.2354E-16 4.1441E-16 4.0526E-16 361 3.9609E-16 3.8689E-16 3.7767E-16 3.6841E-16 3.5913E-16 366 3.4982E-16 3.4047E-16 3.3110E-16 3.2169E-16 3.1225E-16 371 3.0278E-16 2.9328E-16 2.8375E-1 6 2.7419E-16 2.6460E-16 376 2.5497E-16 2.4532E-16 2.3564E-16 2.2593E-16 2.1620E-16 381 2.0644E-16 1.9666E-16 1.8686E-16 1.7703E-16 1.6718E-16 386 1.5732E-16 1.4744E-16 1.3754E-16 1.2764E-16 1.1771 E-1 6 391 1.0778E-16 9.7843E-17 8.7896E-17 7.7944E-17 6.7989E-17 396 5.8032E-17 5.7923E-17 5.7869E-17 5.7814E-17 5.7759E-17 401 5.7704E-17 5.7650E-17 5.7595E-17 5.7540E-17 5.7485E-17

406 5.6863E-1 7 5.6206E-17 5.5551 E-17 5.4895E-17 5.4241 E-17 411 5.3587E-17 5.2934E-17 5.2283E-17 5.1632E-17 5.0983E-17 416 5.0335E-17 5.0377E-17 4.9085E-17 4.7800E-17 4.6521 E-17 421 4.5251 E-17 4.3990E-17 4.2738E-17 4.1497E-17 4.0267E-17 426 3.9048E-17 3.7842E-17 3.6649E-17 3.5470E-17 3.4305E-17 431 3.3154E-17 3.2018E-17 3.0899E-17 2.9794E-17 2.8707E-17 436 2.7635E-17 2.6581 E-17 2.5543E-17 2.4523E-17 2.3520E-17 441 2.2534E-17 2.1565E-17 2.0614E-17 1.9679E-17 1.8762E-17 446 1.7861E-17 1.6976E-17 1.6108E-17 1.5256E-17 1.4419E-1 7 451 1.3597E-17 1.2790E-17 1.1996E-17 1.1217E-17 1.0450E-17 456 9.6950E-18 8.9519E-18 8.2198E-18 7.4978E-18 6.7854E-18 461 6.0816E-18 5.3856E-18 4.6968E-18 4.0141E-18 3.3368E-18 466 2.6640E-18 1.9949E-1 8 1.3284E-18 6.6372E-19 1.6591 E-1 9 C-14 Concentrations at time =4.900E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/crnA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.15E+04 Mass sorbed = O.OOE+00 Total Mass = 2.15E+04 I 1.5275E-16 6.2022E-16 1.3430E-15 2.2788E-1 5 3.5700E-15 6 5.4062E-15 8.0478E-15 1.1857E-14 1.7338E-14 2.5196E-14 11 3.6406E-14 5.2316E-14 7.4777E-14 1.0632E-13 1.5036E-13 16 2.1155E-13 2.9608E-1 3 4.1226E-13 5.7107E-13 7.8700E-1 3 21 1.0791 E-12 1.4720E-12 1.9980E-12 2.6984E-12 3.6262E-12 26 4.8490E-12 6.4525E-12 8.5446E-12 1.1261E-11 1.4769E-11 31 1.9279E-11 2.5049E-11 3.2395E-1 1 4.1703E-1 I 5.3441 E-1 1 36 6.8177E-1 I 8.6590E-11 1.0949E-10 1.3786E-10 1.7282E-10 41 1.9335E-10 2.1600E-10 2.4104E-10 2.6869E-10 2.9919E-1 0 46 3.3280E-10 3.6980E-10 4.1049E-10 4.5519E-10 5.0425E-10 51 5.0845E-10 5.1279E-10 5.1715E-10 5.2155E-10 5.2599E-10 56 5.3046E-10 5.3496E-10 5.4914E-10 3.4388E-04 2.9927E-02 61 7.8235E-01 8.1205E-01 8.3515E-01 8.3680E-01 8.5719E-01 66 8.6097E-01 9.3935E-01 9.4012E-01 8.8184E-01 8.6652E-01 71 5.2450E-01 5.0530E-01 3.4567E-01 3.3777E-01 2.91OOE-01 76 2.8956E-01 2.9870E-01 2.9708E-01 2.4562E-01 2.4162E-01 81 1.8855E-01 1.8512E-01 1.4857E-01 I A672E-01 1.3493E-01 86 1.3364E-01 1.1172E-01 1.1001 E-01 8.7450E-02 8.6063E-02 91 7.2385E-02 7.1180E-02 5.3386E-02 5.2243E-02 4.0167E-02 96 3.9643E-02 3.8043E-02 3.7763E-02 3.2043E-02 3.1520E-02 101 2.3572E-02 2.2830E-02 1.1397E-02 1.0947E-02 1.0620E-02 106 1.0559E-02 9.2883E-03 9.1910E-03 7.9187E-03 7.7849E-03 111 5.5607E-03 5.4026E-03 3.4962E-03 3.4111E-03 3.0918E-03 116 3.0553E-03 2.4202E-03 2.3959E-03 2.3943E-03 2.3334E-03 121 7.4668E-04 7.0046E-04 I.0800E-03 1.0836E-03 7.9838E-04

126 7.9717E-04 1.0505E-03 1.0383E-03 4.6705E-04 4.4030E04D 131 3.1294E-04 3.1172E-04 4.0691 E-04 4.1056E-04 4.1065E-04 136 4.1187E-04 4.4357E-04 4.4358E-04 4.1201 E-04 4.1808E-04 141 6.0836E-04 6.1079E-04 4.8400E-04 4.7914E-04 4.7900EE4D 146 4.7661 E-04 4.1637E404 5.8171 E-04 4.9589E-03 4.9638E-03 151 7.1350E-04 5.4816E-04 4.8166E-04 4.8405E-04 6.1086E-04 156 6.1208E-04 5.1698E-04 5.1333E-04 5.1326E-04 5.1326E-04 161 5.1333E-04 5.1698E-04 6.1203E-04 6.0838E-04 4.1790E-04 166 4.0213E-04 1.8269E-04 3.2615E-04 4.29I0E-03 4.3007E-03 171 5.8994E-04 4.5256E-04 5.7666E-04 5.7663E-04 4.4986E-04 176 4.4865E-04 5.4361 E-04 5.3996E-04 3.4964E-04 3.4235E-04 181 3.4221 E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 186 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 191 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-64 3.4220E-04 196 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 201 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 206 3.4220E-04 3A4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 211 3.4220E-04 3A4220E-04 3.4220E'04 3.4220E-04 3.4220E-04 216 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 221 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 226 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 231 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 236 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-0.4 3.4220E-04 241 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 246 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 C-14 Concentrations at time =4.900E+02 ,(Delt =l.000E+00)

Node I Concentration (CUcmW3) at nodes 1,1+1,...,1+4 251 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 256 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 261 3.4220E-04 3.4220E044 3.4220E-04 3.4220E-04 3.4220E-04 266 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 271 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 276 3.4220E-04 3.4220E-04 3.4220E404 3.4220E-04 3.4220E-04 281 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 286 3.4220E-04 3.4220E-04 3.4220E404 3.4220E-04 3.4220E-04 291 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 296 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 301 3.4220E-04 3.4220E-04 3.4220E404 3.4220E-04 3.4220E-04 306 3.4220E-04 3.4220E-04 3.4220E404 3.4220E404 3.4220E-04 311 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 316 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E404 3.4220E-04 321 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 326 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E404 3.4220E-04 331 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 336 3.4220E-04 3.4220E-04 3.4220E404 3.4220E-04 3.4220E-04

341 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 346 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 351 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 356 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 361 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 366 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 371 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 376 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 381 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 386 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 3.4220E-04 391 3.4220E-04 3.4220E-04 3.4220E-04 3.4197E-04 3.2964E-04 396 1.0604E-06 1.0598E-06 1.0594E-06 1.0590E-06 1.0587E-06 401 1.0583E-06 1.0579E-06 1.0575E-06 1.0570E-06 1.0566E-06 406 1.0508E-06 1.0430E-06 1.0335E-06 1.0224E-06 1.0097E-06 411 9.9535E-07 9.7955E-07 9.6232E-07 9.4374E-07 9.2388E-07 416 9.0285E-07 9.0426E-07 8.5905E-07 8.1028E-07 7.5877E-07 421 7.0542E-07 6.5106E-07 5.9652E-07 5.4257E-07 4.8990E-07 426 4.3910E-07 3.9070E-07 3.4508E-07 3.0256E-07 2.6334E-07 431 2.2753E-07 1.9515E-07 1.6615E-07 1.4044E-07 1.1783E-07 436 9.8151E-08 8.1162E-08 6.6627E-08 5.4300E-08 4.3934E-08 441 3.5291 E-08 2.8145E-08 2.2285E-08 1.7519E-08 1.3674E-08 446 1.0597E-08 8.1546E-09 6.2306E-09 4.7271E-09 3.5613E-09 451 2.6642E-09 1.9792E-09 1.4601 E-09 1.0697E-09 7.7830E-10 456 5.6239E-1 0 4.0359E-10 2.8765E-1 0 2.0362E-10 1A315E-10 461 9.9950E-11 6.9290E-1 I 4.7672E-1 1 3.2513E-1 1 2.1920E-1 1 466 1.4512E-11 9.2788E-12 5.4737E-12 2.5291E-12 6.2293E-13 H-3 Concentrations at time =5.400E+02 ,(Deft =1.000E+00)

Node I Concentration (Ci/crnA3) at nodes 1,1+1,...,1+4 Mass In solution = 3.40E-09 Mass sorbed = O.OOE+00 Total Mass = 3.40E-09 1 1.6560E-22 6.6245E-22 1.3253E-21 1.9890E-21 2.6538E-21 6 3.3202E-21 3.9885E-21 4.6592E-21 5.3325E-21 6.0089E-21 11 6.6886E-21 7.3720E-21 8.0593E-21 8.7510E-21 9.4472E-21 16 1.0148E-20 1.0854E-20 1.1565E-20 1.2282E-20 1.3004E-20 21 1.3732E-20 1.4466E-20 1.5206E-20 1.5951 E-20 1.6703E-20 26 1.7461E-20 1.8224E-20 1.8994E-20 1.9769E-20 2.0550E-20 31 2.1336E-20 2.2128E-20 2.2925E-20 2.3727E-20 2.4533E-20 36 2.5344E-20 2.6158E-20 2.6977E-20 2.7798E-20 2.8623E-20 41 2.9037E-20 2.9451E-20 2.9865E-20 3.0279E-20 3.0694E-20 46 3.1 11OE-20 3.1525E-20 3.1941E-20 3.2357E-20 3.2772E-20 51 3.2806E-20 3.2841 E-20 3.2876E-20 3.291OE-20 3.2945E-20 56 3.2979E-20 3.3014E-20 3.3122E-20 2.5972E-14 2.5962E-14

61 2.5952E-14 2.5936E-14 2.5914E-14 2.5887E-14 2.5855E-14 66 2.5816E-14 2.5773E-14 2.5724E-14 2.5669E-14 2.5609E-14 71 2.5544E-14 2.5473E-14 2.5397E-14 2.5316E-14 2.5229E-14 76 2.5138E-14 2.5041 E-14 2A940E-14 2.4833E-14 2.4722E-14 81 2.4605E-14 2.4484E-14 2.4359E-14 2A229E-14 2.4094E-14 86 2.3955E-14 2.3812E-14 2.3664E-14 2.3512E-14 2.3356E-14 91 2.3197E-14 2.3033E-14 2.2865E-14 2.2694E-14 2.2520E-14 96 2.2342E-14 2.2160E-14 2.1975E-14 2.1788E-14 2.1597E-14 101 2.1403E-14 2.1206E-14 2.1007E-14 2.0805E-14 2.0600E-14 106 2.0393E-14 2.0184E-14 1.9973E-14 1.9760E-14 1.9545E-14 111 1.9328E-14 1.9109E-14 1.8889E-14 1.8667E-14 1.8444E-14 116 1.8220E-14 .1.7994E-14 1.7768E-14 1.7541E-14 1.7312E-14 121 1.7084E-14 1.6854E-14 1.6624E-14 1.6394E-14 1.6163E-14 126 1.5933E-14 1.5702E-14 1.5471 E-14 1.5241 E-14 1.5010E-14 131 1.4780E-14 1.4551 E-14 1.4322E-14 1.4093E-14 1.3865E-14 136 1.3638E-14 1.3412E-14 1.3187E-14 1.2963E-14 1.2740E-14 141 1.2518E-14 1.2297E-14 1.2078E-14 1.1860E-14 1.1644E-14 146 1.1429E-14 1.1215E-14 1.1004E-14 1.0794E-14 1.0586E-14 151 1.0379E-14 1.0175E-14 9.9721 E-15 9.7716E-1 5 9.5730E-15 156 9.3765E-15 9.1821 E-15 8.9899E-15 8.7998E-15 8.6119E-15 161 8.4263E-15 8.2430E-15 8.0620E-15 7.8833E-1 5 7.7069E-1 5 166 7.5329E-1 5 7.3614E-15 7.1922E-15 7.0255E-1 5 6.8612E-15 171 6.6994E-1 5 6.5400E-15 6.3831E-15 6.2287E-15 6.0768E-15 176 5.9273E-1 5 5.7804E-15 5.6359E-15 5.4940E-15 5.3545E-1 5 181 5.2175E-1 5 5.0830E-15 4.9509E-15 4.8213E-15 4.6941 E-15 186 4.5694E-15 4.4471 E-15 4.3272E-15 4.2097E-15 4.0946E-15 191 3.9818E-1 5 3.8713E-15 3.7632E-15 3.6574E-1 5 3.5539E-15 196 3.4526E-1 5 3.3536E-15 3.2567E-15 3.1621E-15 3.0696E-15 201 2.9792E-1 5 2.8910E-15 2.8048E-15 2.7207E-15 2.6386E-15 206 2.5586E-1 5 2.4804E-15 2.4043E-15 2.3300E-15 2.2576E-15 211 2.1871E-15 2.1184E-15 2.0515E-15 1.9864E-15 1.9229E-15 216 1.8612E-15 1.8012E-15 1.7428E-15 1.6860E-15 1.6308E-15 221 1.5771 E-15 1.5250E-15 1.4743E-15 1.4251 E-15 1.3773E-15 226 1.3310E-15 1.2859E-1 5 1.2423E-15 1.1999E-15 1.1588E-15 231 1.1190E-15 1.0803E-15 1.0429E-15 1.0066E-1 5 9.7151 E-16 236 9.3749E-16 9.0455E-16 8.7267E-16 8.4181 E-16 8.1196E-16 241 7.8308E-1 6 7.5515E-16 7.2815E-16 7.0204E-16 6.7682E-16 246 6.5244E-16 6.2890E-16 6.0616E-16 5.8421 E-16 5.6301 E-1 6 H-3 Concentrations at time =5.400E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 5.4256E-16 5.2282E-16 5.0379E-16 4.8542E-16 4.6772E-16 256 4.5064E-16 4.3419E-16 4.1834E-16 4.0306E-16 3.8834E-16 261 3.7417E-16 3.6053E-16 3.4739E-16 3.3475E-16 3.2259E-16 266 3.1088E-16 2.9962E-16 2.8879E-16 2.7838E-16 2.6837E-16 271 2.5875E-16 2.4951 E-1 6 2A062E-16 2.3209E-16 2.2389E-16

276 2.1602E-16 2.0846E-16 2.0120E-16 1.9423E-16 1.8754E-16 281 1.8112E-16 1.7496E-16 1.6905E-16 1.6338E-16 1.5794E-16 286 1.5272E-16 1.4772E-16 1.4292E-16 1.3832E-16 1.3391 E-16 291 1.2967E-16 1.2562E-16 1.2173E-16 1.1800E-16 1.1442E-16 296 1.1099E-16 1.0770E-16 1.0455E-16 1.0153E-16 9.8626E-17 301 9.5845E-17 9.3177E-17 9.0617E-17 8.8160E-17 8.5803E-17 306 8.3539E-17 8.1366E-17 7.9279E-17 7.7274E-17 7.5347E-17 311 7.3495E-17 7.1714E-17 7.OOOOE-17 6.8351 E-17 6.6762E-17 316 6.5233E-17 6.3758E-1 7 6.2336E-17 6.0964E-17 5.9639E-17 321 5.8359E-17 5.7122E-1 7 5.5925E-17 5.4766E-17 5.3644E-17 326 5.2555E-17 5.1499E-17 5.0474E-17 4.9477E-17 4.8507E-17 331 4.7563E-17 4.6643E-17 4.5745E-17 4.4869E-17 4.4013E-17 336 4.3175E-17 4.2356E-17 4.1552E-17 4.0764E-17 3.9990E-17 341 3.9230E-17 3.8482E-17 3.7745E-17 3.7020E-17 3.6304E-17 346 3.5598E-17 3.4900E-17 3.4210E-17 3.3527E-17 3.2851E-17 351 3.2181 E-17 3.1517E-17 3.0858E-17 3.0203E-17 2.9553E-17 356 2.8906E-17 2.8262E-17 2.7622E-17 2.6984E-17 2.6349E-17 361 2.5716E-17 2.5085E-17 2.4455E-17 2.3826E-17 2.3199E-17 366 2.2573E-17 2.1947E-17 2.1322E-17 2.0697E-17 2.0073E-17 371 1.9449E-17 1.8825E-17 1.8201 E-17 1.7577E-17 1.6953E-17 376 1.6328E-1 7 1.5704E-17 1.5079E-17 1.4454E-17 1.3828E-17 381 1.3202E-17 1.2576E-17 1.1949E-17 1.1322E-17 1.0694E-17 386 1.0066E-1 7 9.4383E-18 8.8099E-18 8.1812E-18 7.5523E-18 391 6.9232E-18 6.2940E-18 5.6646E-18 5.0352E-18 4.4057E-18 396 3.7763E-18 3.7694E-1 8 3.7660E-18 3.7625E-1 8 3.7590E-18 401 3.7556E-18 3.7521 E-1 8 3.7487E-18 3.7452E-1 8 3.7417E-18 406 3.7024E-18 3.661 OE-1 8 3.6197E-18 3.5784E-18 3.5372E-18 411 3.4961E-18 3.4550E-18 3.4141 E-18 3.3732E-18 3.3324E-18 416 3.2917E-18 3.2944E-18 3.2133E-18 3.1326E-18 3.0524E-18 421 2.9727E-18 2.8935E-18 2.8149E-18 2.7369E-18 2.6595E-18 426 2.5827E-18 2.5067E-18 2.4314E-18 2.3568E-18 2.2830E-18 431 2.2101E-18 2.1379E-18 2.0666E-18 1.9962E-18 1.9266E-18 436 1.8580E-18 1.7902E-18 1.7234E-18 1.6575E-18 1.5925E-18 441 1.5285E-18 1.4654E-18 1.4032E-18 1.3420E-18 1.2817E-18 446 1.2222E-18 1.1637E-18 1.1061E-18 1.0493E-18 9.9330E-19 451 9.3816E-19 8.8381 E-1 9 8.3021 E-19 7.7735E-19 7.2519E-19 456 6.7369E-19 6.2282E-19 5.7255E-19 5.2283E-19 4.7362E-19 461 4.2488E-19 3.7658E-19 3.2865E-19 2.8107E-19 2.3377E-19 466 1.8672E-19 1.3987E-19 9.3164E-20 4.6557E-20 1.1638E-20 C-14 Concentrations at time =5.400E+02 ,(Deft =1.0OOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.14E+04 Mass sorbed = O.OOE+00 Total Mass = 2.14E+04

1 4.2081 E-16 1.7050E-15 3.6516E-15 6.0953E-15 9.3555E-15 6 1.3844E-14 2.0109E-14 2.8889E-14 4.1186E-14 5.8359E-14 11 8.2244E-14 1.1532E-13 1.6089E-13 2.2340E-13 3.0870E-13 16 4.2455E-1 3 5.8112E-13 7.9171 E-1 3 1.0736E-12 1.4490E-12 21 1.9467E-1 2 2.6034E-12 3.4658E-1 2 4.5929E-12 6.0593E-12 26 7.9581 E-1 2 1.0406E-1 1 1.3547E-1 I 1.7559E-11 2.2661 E-1 I 31 2.9121 E-1 I 3.7263E-1 1 4.7482E-1 I 6.0253E-11 7.6145E-1 I 36 9.5838E-1 I 1.2014E-10 1.5000E-10 1.8656E-10 2.3112E-10 41 2.5705E-10 2.8553E-10 3.1683E-10 3.5123E-10 3.8898E-1 0 46 4.3038E-10 4.7574E-10 5.2538E-10 5.7966E-1 0 6.3897E-10 51 6.4403E-10 6.4926E-10 6.5452E-10 6.5982E-1 0 6.6516E-10 56 6.7054E-10 6.7596E-10 6.9301 E-1 0 4.1338E-04 3.2625E-02 61 7.7483E-01 8.0712E-01 8.3003E-01 8.3183E-01 8.5196E-01 66 8.5607E-01 9.3338E-01 9.3422E-01 8.7669E-01 8.6003E-01 71 5.2258E-01 5.0171 E-01 3.4417E-01 3.3558E-01 2.8942E-01 76 2.8786E-01 2.9685E-01 2.9509E-01 2.4433E-01 2.3998E-01 81 1.8760E-01 1.8388E-01 1.4781E-01 1.4580E-01 1.3416E-01 86 1.3276E-01 1.1112E-01 1.0927E-01 8.7004E-02 8.5497E-02 91 7.1996E-02 7.0687E-02 5.3128E-02 5.1886E-02 3.9969E-02 96 3.9400E-02 3.7819E-02 3.7515E-02 3.1870E-02 3.1301 E-02 101 2.3457E-02 2.2651 E-02 1.1371 E-02 1.0881 E-02 1.0557E-02 106 1.0491E-02 9.2369E-03 9.131 1E-03 7.8754E-03 7.7299E-03 111 5.5352E-03 5.3633E-03 3.4822E-03 3.3896E-03 3.0742E-03 116 3.0345E-03 2A080E-03 2.3815E-03 2.3796E-03 2.3135E-03 121 7.4813E-04 6.9790E-04 1.0720E-03 1.0759E-03 7.9467E-04 126 7.9335E-04 1.0431E-03 1.0299E-03 4.6634E-04 4.3726E-04 131 3.1154E-04 3.1021E-04 4.0410E-04 4.0807E-04 4.0818E-04 136 4.0950E-04 4.4078E-04 4.4078E-04 4.0967E-04 4.1628E-04 141 6.0397E-04 6.0661 E-04 4.8156E-04 4.7627E-04 4.7611 E-04 146 4.7352E-04 4.1476E-04 5.9449E-04 4.9121 E-03 4.9174E-03 151 7.2499E-04 5.4527E-04 4.7903E-04 4.8162E-04 6.0669E-04 156 6.0802E-04 5.1421 E-04 5.1025E-04 5.1017E-04 5.1017E-04 161 5.1025E-04 5.1421 E-04 6.0796E-04 6.0399E-04 4.1605E-04 166 3.9892E-04 1.8302E-04 3.3896E-04 4.2498E-03 4.2604E-03 171 6.0020E-04 4.5087E-04 5.7271 E-04 5.7266E-04 4.4764E-04 176 4.4632E-04 5.3995E-04 5.3598E-04 3.4824E-04 3.4031 E-04 181 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 186 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 191 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 196 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 201 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 206 3.4014E-04 3.4014E-04 3.4014E-04 3A014E-04 3.4014E-04 211 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 216 3.4014E-04 3.4014E-04 3.4014E-04 3A014E-04 3.4014E-04 221 3A014E-04 3.4014E-04 3.4014E-04 3A014E-04 3.4014E-04 226 3A014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 231 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 236 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 241 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04

246 341E0 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 C-14 Concentrations at time =5.400E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CilcmA3) at nodes 1,1+1,...,1+4 251 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 256 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 261 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 266 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 271 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 276 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 281 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 286 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3A014E-04 291 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 296 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 301 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 306 3.4014E-04 3A014E-04 3.4014E-04 3.4014E-04 3.4014E-04 311 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 316 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 321 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 326 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 331 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 336 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 341 3.4014E-04 3.4014E-04 3A014E-04 3.4014E-04 3.4014E-04 346 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 351 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 356 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 361 3A014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 366 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 371 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 376 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 381 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 386 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 3.4014E-04 391 3.4014E-04 3.4014E-04 3.4014E-04 3.3986E-04 3.2643E-04 396 1.0109E-06 1.0103E-06 1.0099E-06 1.0096E-06 1.0092E-06 401 1.0088E-06 1.0084E-06 1.0080E-06 1.0076E-06 1.0072E-06 406 1.0017E-06 9.9455E-07 9.8592E-07 9.7588E-07 9.6445E-07 411 9.5169E-07 9.3762E-07 9.2232E-07 9.0584E-07 8.8824E-07 416 8.6960E-07 8.7085E-07 8.3078E-07 7.8744E-07 7.4153E-07 421 6.9374E-07 6.4479E-07 5.9536E-07 5.4609E-07 4.9760E-07 426 4.5041 E-07 4.0499E-07 3.6174E-07 3.2096E-07 2.8289E-07 431 2.4768E-07 2.1541E-07 1.8611E-07 1.5972E-07 1.3617E-07 436 1.1532E-07 9.7017E-08 8.1081E-08 6.7315E-08 5.5519E-08 441 4.5489E-08 3.7027E-08 2.9942E-08 2.4054E-08 1.9198E-08 446 11.5223E-08 1.1993E-08 9.3866E-09 7.2995E-09 5.6399E-09 451 4.3297E-09 3.3026E-09 2.5030E-09 1.8850E-09 1.4106E-09 456 1.0488E-09 7.7497E-10 5.6899E-10 4.1512E-10 3.0093E-10

461 2.1674E-10 1.5504E-10 1.1007E-10 7.7444E-11 5.3816E-11 466 3.6654E-11 2.4033E-11 1.4465E-11 6.7739E-12 1.6728E-12 H-3 Concentrations at time =5.600E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 1.14E-09 Mass sorbed = O.OOE+00 Total Mass = 1.14E-09 1 5.6269E-23 2.2509E-22 4.5030E-22 6.7574E-22 9.0155E-22 6 1.1278E-21 1.3547E-21 1.5822E-21 1.8106E-21 2.0398E-21 11 2.2701 E-21 2.5014E-21 2.7340E-21 2.9678E-21 3.2030E-21 16 3A396E-21 3.6778E-21 3.9175E-21 4.1588E-21 4.4017E-21 21 4.6464E-21 4.8928E-21 5.1409E-21 5.3908E-21 5.6424E-21 26 5.8959E-21 6.151OE-21 6.4079E-21 6.6665E-21 6.9267E-21 31 7.1886E-21 7.4520E-21 7.7168E-21 7.9831E-21 8.2506E-21 36 8.5194E-21 8.7892E-21 9.0601 E-21 9.3318E-21 9.6043E-21 41 9.7411 E-21 9.8777E-21 1.0014E-20 1.0151E-20 1.0288E-20 46 1.0425E-20 1.0562E-20 1.0699E-20 1.0836E-20 1.0973E-20 51 1.0984E-20 1.0995E-20 1.1007E-20 1.1018E-20 1.1030E-20 56 1.1041 E-20 1.1052E-20 1.1088E-20 8.5497E-15 8.5467E-15 61 8.5434E-15 8.5383E-15 8.5315E-15 8.5228E-1 5 8.5125E-15 66 8.5003E-15 8.4864E-15 8A708E-15 8.4534E-15 8.4343E-15 71 8.4135E-15 8.3910E-15 8.3668E-1 5 8.3410E-15 8.3135E-1 5 76 8.2844E-15 8.2536E-15 8.2213E-1 5 8.1873E-15 8.1519E-15 81 8.1149E-15 8.0763E-15 8.0363E-15 7.9948E-15 7.9519E-1 5 86 7.9076E-15 7.8618E-15 7.8148E-1 5 7.7663E-15 7.7166E-1 5 91 7.6656E-15 7.6134E-15 7.5599E-1 5 7.5053E-15 7.4495E-1 5 96 7.3925E-15 7.3345E-15 7.2755E-1 5 7.2154E-15 7.1543E-15 101 7.0922E-115 7.0293E-15 6.9654E-15 6.9007E-15 6.8352E-1 5 106 6.7689E-15 6.7019E-15 6.6341 E-15 6.5657E-15 6.4966E-15 111 6.4269E-15 6.3567E-15 6.2859E-15 6.2146E-15 6.1429E-15 116 6.0707E-15 5.9981 E-1 5 5.9252E-15 5.8519E-15 5.7784E-15 121 5.7046E-1 5 5.6306E-15 5.5564E-15 5.4820E-15 5.4075E-15 126 5.3329E-1 5 5.2583E-15 5.1836E-15 5.1090E-15 5.0344E-15 131 4.9598E-15 4.8854E-15 4.8111E-15 4.7369E-15 4.6629E-15 136 4.5891 E-15 4.5156E-15 4.4423E-15 4.3694E-15 4.2967E-15 141 4.2244E-15 4.1524E-15 4.0808E-15 4.0097E-1 5 3.9390E-15 146 3.8687E-15 3.7989E-15 3.7296E-15 3.6608E-15 3.5926E-1 5 151 3.5249E-115 3.4578E-15 3.3913E-15 3.3253E-1 5 3.2600E-15 156 3.1953E-15 3.1313E-15 3.0679E-15 3.0052E-15 2.9432E-15 161 2.8819E-15 2.8213E-15 2.7614E-15 2.7022E-15 2.6438E-1 5 166 2.5861 E-1 5 2.5291 E-15 2A729E-15 2.4175E-15 2.3629E-1 5 171 2.3090E-15 2.2559E-15 2.2035E-15 2.1520E-15 2.1013E-15 176 2.0513E-15 2.0021 E-15 1.9537E-1 5 1.9061E-15 1.8593E-1 5

181 1.8133E-15 1.7681 E-15 1.7237E-1 5 1.6800E-15 1.6372E-15 186 1.5951 E-15 1.5538E-15 1.5133E-1 5 1A735E-15 1.4345E-1 5 191 1.3963E-15 1.3588E-15 1.3221 E-15 1.2862E-15 1.2509E-15 196 1.2164E-15 1.1827E-15 1.1496E-15 1.1173E-15 1.0856E-15 201 1.0547E-15 1.0245E-15 9.9492E-16 9.6604E-16 9.3782E-16 206 9.1026E-16 8.8335E-16 8.5708E-16 8.3144E-16 8.0643E-16 211 7.8203E-16 7.5823E-16 7.3503E-16 7.1241 E-1 6 6.9037E-16 216 6.6890E-16 6.4799E-16 6.2762E-16 6.0779E-16 5.8849E-16 221 5.6971 E-1 6 5.5144E-16 5.3367E-1 6 5.1639E-16 4.9960E-16 226 4.8327E-16 4.6740E-16 4.5199E-16 4.3702E-16 4.2249E-16 231 4.0838E-16 3.9468E-16 3.8139E-16 3.6850E-16 3.5600E-16 236 3.4387E-16 3.3212E-16 3.2073E-16 3.0969E-16 2.9900E-16 241 2.8864E-16 2.7861E-16 2.6890E-16 2.5950E-16 2.5040E-16 246 2.4161E-16 2.3309E-16 2.2486E-16 2.1691E-16 2.0921E-16 H-3 Concentrations at time =5.600E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1....,1+4 251 2.0178E-16 1.9460E-16 1.8766E-16 1.8096E-16 1.7449E-16 256 1.6824E-16 1.6221 E-1 6 1.5640E-16 1.5078E-16 1.4537E-16 261 1.4015E-16 1.3511E-16 1.3026E-16 1.2558E-16 1.2108E-16 266 1.1673E-16 1.1255E-16 1.0852E-16 1.0464E-16 1.0091E-16 271 9.7312E-17 9.3852E-17 9.0524E-17 8.7321 E-17 8.4241 E-17 276 8.1278E-1 7 7.8429E-17 7.5690E-17 7.3057E-17 7.0527E-17 281 6.8094E-17 6.5757E-17 6.3512E-17 6.1355E-17 5.9283E-17 286 5.7293E-17 5.5382E-17 5.3547E-17 5.1785E-17 5.0094E-17 291 4.8470E-17 4.6911E-17 4.5414E-17 4.3977E-17 4.2599E-17 296 4.1275E-17 4.0004E-17 3.8785E-17 3.7614E-17 3.6491E-17 301 3.5412E-17 3.4377E-17 3.3382E-17 3.2427E-17 3.1511E-17 306 3.0630E-17 2.9784E-17 2.8971E-17 2.8190E-17 2.7439E-17 311 2.6717E-17 2.6023E-17 2.5355E-17 2.4712E-17 2.4094E-17 316 2.3498E-17 2.2924E-17 2.2371E-17 2.1837E-17 2.1323E-17 321 2.0826E-17 2.0347E-17 1.9883E-17 1.9435E-17 1.9002E-17 326 1.8583E-17 1.8176E-17 1.7782E-17 1.7400E-17 1.7030E-17 331 1.6670E-17 1.6319E-17 1.5979E-17 1.5647E-17 1.5324E-17 336 1.5008E-17 1.4700E-17 1.4400E-17 1.4106E-17 1.3818E-17 341 1.3536E-17 1.3259E-17 1.2988E-17 1.2722E-17 1.2460E-17 346 1.2202E-17 1.1948E-17 1.1698E-17 1.1452E-17 1.1209E-17 351 1.0968E-17 1.0731E-17 1.0496E-17 1.0263E-17 1.0033E-17 356 9.8041 E-18 9.5775E-18 9.3527E-18 9.1294E-18 8.9076E-18 361 8.6870E-18 8.4677E-18 8.2494E-18 8.0322E-18 7.8158E-18 366 7.6002E-18 7.3854E-18 7.1712E-18 6.9575E-18 6.7444E-18 371 6.5317E-18 6.3194E-18 6.1075E-18 5.8958E-18 5.6844E-18 376 5.4733E-18 5.2623E-1 8 5.0515E-18 4.8408E-18 4.6303E-1 8 381 4.4198E-18 4.2094E-18 3.9990E-18 3.7888E-18 3.5785E-18 386 3.3683E-18 3.1581 E-18 2.9479E-18 2.7378E-18 2.5276E-18 391 2.3175E-18 2.1074E-18 1.8973E-18 1.6873E-18 1.4772E-18

396 1.2672E-18 1.2649E-18 1.2638E-18 1.2626E-18 1.2615E-18 401 1.2603E-1 8 1.2592E-18 1.2580E-18 1.2568E-18 1.2557E-1 8 406 1.2426E-18 1.2288E-18 1.2150E-18 1.2013E-18 1.1876E-18 411 1.1739E-18 1.1603E-18 1.1466E-18 1.1331E-18 1.1195E-18 416 1.1060E-18 1.1069E-18 1.0800E-18 1.0532E-18 1.0266E-18 421 1.0002E-18 9.7393E-19 9.4786E-19 9.2198E-19 8.9631 E-19 426 8.7086E-19 8.4563E-19 8.2063E-19 7.9587E-19 7.7136E-19 431 7.471OE-19 7.2311 E-19 6.9938E-19 6.7592E-19 6.5274E-19 436 6.2984E-19 6.0723E-19 5.8491 E-1 9 5.6287E-19 5.4113E-19 441 5.1968E-19 4.9852E-19 4.7765E-19 4.5707E-19 4.3677E-19 446 4.1676E-19 3.9702E-19 3.7756E-19 3.5837E-19 3.3943E-19 451 3.2076E-19 3.0232E-19 2.8413E-19 2.6616E-19 2.4841 E-1 9 456 2.3086E-19 2.1352E-19 1.9636E-1 9 1.7937E-19 1.6254E-19 461 1.4586E-19 1.2931E-19 1.1288E-19 9.6555E-20 8.0323E-20 466 6.4166E-20 4.8071 E-20 3.2021 E-20 1.6003E-20 4.0003E-21 C-14 Concentrations at time =5.600E+02 (Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.13E+04 Mass sorbed = O.OOE+O0 Total Mass = 2.13E+04 1 6.0562E-16 2.4520E-1 5 5.2321 E-1 5 8.6846E-15 1.3236E-14 6 1.9431E-14 2.7983E-14 3.9846E-14 5.6300E-14 7.9064E-14 11 1.1044E-13 1.5351 E-13 2.1235E-13 2.9238E-13 4.0070E-13 16 5.4663E-13 7.4232E-13 1.0035E-12 1.3505E-12 1.8093E-12 21 2.4133E-12 3.2046E-12 4.2367E-12 5.5768E-12 7.3090E-12 26 9.5382E-12 1.2394E-1 1 1.6037E-1 1 2.0664E-1 I 2.6515E-1 1 31 3.3883E-1 1 4.3121 E-11 5.4657E-1 1 6.9002E-1 I 8.6766E-1 1 36 1.0868E-10 1.3560E-10 1.6853E-10 2.0868E-10 2.5742E-10 41 2.8570E-10 3.1670E-10 3.5071 E-10 3.8801E-10 4.2888E-10 46 4.7361E-10 5.2253E-10 5.7598E-10 6.3434E-10 6.9799E-10 51 7.0342E-10 7.0902E-10 7.1466E-1 0 7.2034E-10 7.2606E-10 56 7.3183E-10 7.3763E-10 7.5589E-10 4.4275E-04 3.3686E-02 61 7.7186E-01 8.0515E-01 8.2799E-01 8.2985E-01 8.4987E-01 66 8.5411 E-01 9.3101 E-01 9.3188E-01 8.7463E-01 8.5745E-01 71 5.2181E-01 5.0028E-01 3.4357E-01 3.3472E-01 2.8879E-01 76 2.8718E-01 2.9612E-01 2.9430E-01 2.4381 E-01 2.3932E-01 81 1.8723E-01 1.8338E-01 I A750E-01 1.4543E-01 1.3385E-01 86 1.3240E-01 1.1088E-01 1.0897E-01 8.6826E-02 8.5272E-02 91 7.1841E-02 7.0491 E-02 5.3025E-02 5.1744E-02 3.9890E-02 96 3.9304E-02 3.7730E-02 3.7416E-02 3.1801 E-02 3.1214E-02 101 2.3412E-02 2.2580E-02 1.1360E-02 1.0855E-02 1.0532E-02 106 1.0464E-02 9.2163E-03 9.1072E-03 7.8581 E-03 7.7081 E-03 111 5.5249E-03 5.3477E-03 3.4765E-03 3.3811 E-03 3.0672E-03

116 3.0263E-03 2.4031E-03 2.3758E-03 2.3737E-03 2.3056E-03 121 7.4869E-04 6.9687E-04 1.0688E-03 1.0729E-03 7.9319E-04 126 7.9182E-04 1.0402E-03 1.0265E-03 4.6605E-04 4.3606E-04 131 3.1098E-04 3.0961E-04 4.0298E-04 4.0707E-04 4.0719E-04 136 4.0856E-04 4.3966E-04 4.3967E-04 4.0874E-04 4.1555E-04 141 6.0222E-04 6.0494E-04 4.8058E-04 4.7513E-04 4.7495E-04 146 4.7228E-04 4.1414E-04 5.9950E-04 4.8935E-03 4.8989E-03 151 7.2949E-04 5.4414E-04 4.7798E-04 4.8064E-04 6.0504E-04 156 6.0640E-04 5.1311 E-04 5.0902E-04 5.0893E-04 5.0893E-04 161 5.0902E-04 5.1311E-04 6.0634E-04 6.0225E-04 4.1531E-04 166 3.9764E-04 1.8317E-04 3.4399E-04 4.2335E-03 4.2444E-03 171 6.0422E-04 4.5021E-04 5.7113E-04 5.7108E-04 4.4675E-04 176 4.4539E-04 5.3849E-04 5.3440E-04 3.4768E-04 3.3950E-04 181 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 186 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 191 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 196 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 201 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 206 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 211 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 216 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 221 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 226 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 231 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 236 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 241 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 246 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 C-14 Concentrations at time =5.600E+02 (Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 256 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 261 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 266 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 271 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 276 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 281 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 286 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 291 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 296 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 301 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 306 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 311 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 316 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 321 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 326 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04

331 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 336 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 341 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 346 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 351 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 356 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 361 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 366 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 371 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 376 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 381 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 386 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 3.3932E-04 391 3.3932E-04 3.3932E-04 3.3931 E-04 3.3901 E-04 3.2516E-04 396 9.9300E-07 9.9233E-07 9.9199E-07 9.9164E-07 9.9128E-07 401 9.9090E-07 9.9052E-07 9.9013E-07 9.8973E-07 9.8932E-07 406 9.8397E-07 9.7698E-07 9.6864E-07 9.5897E-07 9.4799E-07 411 9.3574E-07 9.2227E-07 9.0763E-07 8.9186E-07 8.7503E-07 416 8.5721E-07 8.5841E-07 8.2009E-07 7.7864E-07 7.3467E-07 421 6.8884E-07 6.4180E-07 5.9419E-07 5.4663E-07 4.9967E-07 426 4.5384E-07 4.0958E-07 3.6728E-07 3.2723E-07 2.8969E-07 431 2.5481 E-07 2.2270E-07 1.9339E-07 1.6686E-07 1.4305E-07 436 1.2185E-07 1.0314E-07 8.6738E-08 7.2483E-08 6.0185E-08 441 4.9656E-08 4.071OE-08 3.3165E-08 2.6847E-08 2.1596E-08 446 1.7263E-08 1.3713E-08 1.0824E-08 8.4909E-09 6.6192E-09 451 5.1279E-09 3.9481 E-09 3.0209E-09 2.2972E-09 1.7361E-09 456 1.3041 E-09 9.7352E-10 7.2231 E-10 5.3263E-1 0 3.9032E-10 461 2.8421 E-10 2.0556E-10 1.4756E-10 1.0495E-10 7.3703E-1 1 466 5.0693E-1 I 3.3523E-1 1 2.0315E-11 9.5560E-12 2.3619E-1 2 H-3 Concentrations at time =5.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass In solution = 6.59E-10 Mass sorbed = O.OOE+00 Total Mass = 6.59E-10 1 3.2778E-23 1.3112E-22 2.6231 E-22 3.9362E-22 5.2513E-22 6 6.5690E-22 7.8899E-22 9.2145E-22 1.0544E-21 1.1878E-21 11 1.3217E-21 1.4562E-21 1.5915E-21 1.7274E-21 1.8640E-21 16 2.0014E-21 2.1397E-21 2.2787E-21 2.4187E-21 2.5596E-21 21 2.7014E-21 2.8441E-21 2.9878E-21 3.1325E-21 3.2781 E-21 26 3.4246E-21 3.5721 E-21 3.7205E-21 3.8699E-21 4.0201 E-21 31 4.1712E-21 4.3231 E-21 4A758E-21 4.6292E-21 4.7834E-21 36 4.9381E-21 5.0935E-21 5.2493E-21 5.4056E-21 5.5623E-21 41 5.6409E-21 5.7194E-21 5.7980E-21 5.8766E-21 5.9552E-21 46 6.0339E-21 6.1125E-21 6.1912E-21 6.2698E-21 6.3484E-21

51 6.3548E-21 6.3613E-21 6.3679E-21 6.3744E-21 6.381 OE-21 56 6.3875E-21 6.3941 E-21 6.4145E-21 4.9065E-15 4.9048E-1 5 61 4.9029E-15 4.9001 E-1 5 4.8962E-15 4.8913E-15 4.8855E-1 5 66 4.8786E-15 4.8708E-15 4.8619E-15 4.8521 E-15 4.8414E-1 5 71 4.8296E-15 4.8169E-1 5 4.8033E-15 4.7887E-15 4.7732E-1 5 76 4.7567E-15 4.7394E-1 5 4.7211 E-15 4.7020E-1 5 4.6819E-15 81 4.661OE-15 4.6393E-15 4.6167E-15 4.5932E-1 5 4.5690E-1 5 86 4.5439E-15 4.5181E-15 4.4915E-15 4.4641 E-1 5 4.4360E-15 91 4.4072E-15 4.3776E-1 5 4.3474E-1 5 4.3165E-1 5 4.2850E-1 5 96 4.2528E-15 4.2200E-1 5 4.1865E-1 5 4.1525E-1 5 4.1180E-15 101 4.0829E-15 4.0472E-1 5 4.0111E-15 3.9744E-1 5 3.9373E-1 5 106 3.8998E-15 3.8618E-15 3.8234E-1 5 3.7846E-1 5 3.7455E-1 5 111 3.7060E-15 3.6661 E-1 5 3.6260E-1 5 3.5855E-1 5 3.5448E-1 5 116 3.5039E-1 5 3A627E-1 5 3.4213E-1 5 3.3797E-1 5 3.3379E-15 121 3.2960E-1 5 3.2539E-15 3.2118E-15 3.1695E-1 5 3.1271E-15 126 3.0847E-1 5 3.0423E-15 2.9998E-1 5 2.9573E-1 5 2.9148E-15 131 2.8724E-15 2.8300E-1 5 2.7877E-1 5 2.7454E-1 5 2.7032E-15 136 2.6612E-15 2.6192E-15 2.5774E-1 5 2.5358E-15 2.4943E-1 5 141 2.4530E-15 2.4119E-15 2.3711E-15 2.3304E-1 5 2.2900E-15 146 2.2498E-15 2.2099E-15 2.1702E-15 2.1309E-15 2.0918E-15 151 2.0530E-15 2.0146E-15 1.9765E-15 1.9387E-15 1.9012E-15 156 1.8641 E-15 1.8274E-15 1.7910E-15 1.7550E-15 1.7194E-15 161 1.6841 E-1 5 1.6493E-15 1.6149E-15 1.5808E-15 1.5472E-15 166 1.5140E-15 1.4812E-15 1.4488E-15 1.4169E-15 1.3854E-15 171 1.3543E-15 1.3236E-15 1.2934E-15 1.2637E-15 1.2344E-15 176 1.2055E-15 1.1771E-15 1.1491E-15 1.1215E-15 1.0945E-15 181 1.0678E-15 1.0416E-15 1.0159E-15 9.9055E-16 9.6569E-16 186 9.4127E-16 9.1730E-16 8.9376E-16 8.7066E-16 8.4799E-16 191 8.2576E-16 8.0395E-16 7.8258E-16 7.6163E-16 7.4110E-16 196 7.2099E-16 7.0129E-16 6.8200E-16 6.6313E-16 6.4465E-16 201 6.2657E-16 6.0889E-16 5.9160E-16 5.7470E-16 5.5817E-16 206 5.4203E-16 5.2625E-16 5.1085E-16 4.9581 E-1 6 4.8112E-16 211 4.6679E-16 4.5280E-16 4.3916E-16 4.2586E-16 4.1288E-16 216 4.0024E-16 3.8791E-16 3.7591 E-1 6 3.6421 E-16 3.5282E-16 221 3A173E-16 3.3093E-16 3.2043E-16 3.1021 E-16 3.0027E-16 226 2.9060E-16 2.8120E-16 2.7206E-16 2.6318E-16 2.5455E-16 231 2A617E-16 2.3803E-1 6 2.3013E-16 2.2246E-16 2.1502E-16 236 2.0779E-16 2.0079E-16 1.9399E-16 1.8741 E-16 1.8102E-16 241 1.7483E-16 1.6884E-16 1.6303E-1 6 1.5740E-16 1.5195E-16 246 1.4668E-16 1.4157E-16 1.3664E-1 6 1.3186E-16 1.2723E-1 6 H-3 Concentrations at time =5.700E+02 ,(Deft =1.OOOE+00)

Node I Concentration (ClfcmA3) at nodes 1,1+1,...,1+4 251 1.2277E-16 1.1844E-16 1.1427E-16 1.1023E-16 1.0633E-16 256 1.0256E-16 9.8922E-17 9.5409E-17 9.2016E-17 8.8742E-17 261 8.5582E-17 8.2533E-17 7.9592E-17 7.6755E-17 7.4020E-17

266 7.1383E-17 6.8841E-17 6.6391 E-1 7 6.4031 E-1 7 6.1757E-17 271 5.9567E-17 5.7458E-17 5.5427E-17 5.3472E-17 5.1590E-17 276 4.9779E-17 4.8036E-17 4.6359E-17 4.4747E-17 4.3195E-17 281 4.1704E-17 4.0269E-17 3.8890E-17 3.7565E-17 3.6291E-17 286 3.5066E-17 3.3890E-17 3.2759E-17 3.1673E-17 3.0629E-17 291 2.9627E-17 2.8664E-17 2.7739E-17 2.6851 E-17 2.5998E-17 296 2.5179E-17 2A392E-17 2.3636E-17 2.2911E-17 2.2214E-17 301 2.1544E-17 2.0902E-17 2.0284E-17 1.9691E-17 1.9121E-17 306 1.8574E-1 7 1.8048E-1 7 1.7542E-1 7 1.7056E-1 7 1.6589E-1 7 311 1.6140E-17 1.5707E-17 1.5292E-17 1.4892E-17 1.4507E-17 316 1.4136E-17 1.3778E-1 7 1.3434E-1 7 1.3102E-1 7 1.2782E-1 7 321 1.2474E-17 1.2176E-17 1.1888E-17 1.1610E-17 1.1341E-17 326 1.1081 E-1 7 1.0829E-1 7 1.0585E-1 7 1.0349E-1 7 1.0119E-17 331 9.8969E-18 9.6808E-18 9.4708E-18 9.2665E-18 9.0677E-18 336 8.8740E-18 8.6851E-18 8.5008E-18 8.3209E-18 8.1450E-18 341 7.9729E-18 7.8045E-18 7.6395E-18 7.4777E-18 7.3188E-18 346 7.1628E-18 7.0094E-18 6.8585E-18 6.7099E-18 6.5635E-18 351 6.4191E-18 6.2766E-18 6.1358E-18 5.9967E-18 5.8591E-18 356 5.7229E-18 5.5880E-18 5.4543E-18 5.3218E-18 5.1903E-18 361 5.0597E-18 4.9300E-18 4.8011E-18 4.6730E-18 4.5455E-18 366 4.4187E-18 4.2924E-18 4.1666E-18 4.0413E-18 3.9164E-18 371 3.7919E-18 3.6678E-18 3.5439E-18 3.4204E-18 3.2970E-18 376 3.1739E-18 3.0510E-18 2.9283E-18 2.8057E-18 2.6833E-18 381 2.5610E-18 2.4388E-18 2.3167E-18 2.1947E-18 2.0727E-18 386 1.9508E-18 1.8290E-18 1.7072E-18 1.5855E-18 1.4638E-18 391 1.3421 E-18 1.2205E-18 1.0989E-18 9.7735E-19 8.5581 E-19 396 7.3430E-19 7.3297E-19 7.3230E-19 7.3163E-19 7.3096E-19 401 7.3030E-19 7.2963E-19 7.2896E-19 7.2830E-19 7.2763E-19 406 7.2005E-19 7.1207E-19 7.0411E-19 6.9618E-19 6.8826E-19 411 6.8036E-19 6.7248E-19 6.6463E-19 6.5679E-19 6A898E-19 416 6.4118E-19 6.4169E-19 6.2617E-19 6.1074E-19 5.9540E-19 421 5.8016E-19 5.6503E-19 5.5001E-19 5.3510E-19 5.2030E-19 426 5.0563E-19 4.9109E-19 4.7668E-19 4.6241E-19 4.4827E-19 431 4.3428E-19 4.2044E-19 4.0674E-19 3.9320E-19 3.7982E-19 436 3.6659E-19 3.5352E-1 9 3.4062E-1 9 3.2788E-1 9 3.1530E-19 441 3.0288E-19 2.9062E-19 2.7853E-19 2.6660E-19 2.5483E-19 446 2.4322E-19 2.3176E-19 2.2046E-19 2.0930E-19 1.9829E-19 451 1.8742E-19 1.7669E-19 1.6609E-19 1.5562E-19 1.4527E-19 456 1.3504E-19 1.2492E-19 1.1490E-19 1.0497E-19 9.5137E-20 461 8.5385E-20 7.5706E-20 6.6095E-20 5.6542E-20 4.7040E-20 466 3.7581E-20 2.8156E-20 1.8756E-20 9.3736E-21 2.3432E-21 C-14 Concentrations at time =5.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcrnA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.13E+04 Mass sorbed = O.OOE+00

Total Mass = 2.13E+04 1 7.2093E-16 2.9179E-1 5 6.2154E-15 1.0290E-14 1.5631 E-14 6 2.2859E-14 3.2787E-14 4.6491 E-14 6.5411E-14 9.1469E-14 11 1.2723E-1 3 1.7611E-13 2.4263E-13 3.3272E-13 4.5420E-13 16 6.1724E-13 8.3505E-1 3 1.1247E-12 1.5081E-12 2.0134E-12 21 2.6762E-12 3.5417E-12 4.6670E-12 6.1235E-12 8.0004E-12 26 1.0409E-1 I 1.3485E-11 1.7398E-1 1 2.2354E-1 1 2.8604E-1 I 31 3.6455E-1 I 4.6274E-1 1 5.8504E-1 I 7.3677E-1 1 9.2424E-1 1 36 1.1550E-10 1A378E-10 1.7832E-10 2.2033E-10 2.7124E-10 41 3.0073E-10 3.3302E-10 3.6843E-10 4.0722E-10 4.4969E-10 46 4.9614E-10 5A689E-1 0 6.0230E-10 6.6274E-10 7.2861 E-10 51 7.3423E-10 7.4002E-1 0 7.4586E-10 7.5173E-10 7.5765E-10 56 7.6361 E-1 0 7.6961 E-1 0 7.8850E-10 4.5776E-04 3.4213E-02 61 7.7037E-01 8.0417E-01 8.2698E-01 8.2886E-01 8A883E-01 66 8.5314E-01 9.2982E-01 9.3070E-01 8.7360E-01 8.5617E-01 71 5.2143E-01 4.9957E-01 3.4327E-01 3.3428E-01 2.8848E-01 76 2.8684E-01 2.9575E-01 2.9391E-01 2.4355E-01 2.3900E-01 81 1.8704E-01 1.8313E-01 1.4735E-01 1.4525E-01 1.3370E-01 86 1.3223E-01 1.1076E-01 1.0883E-01 8.6737E-02 8.5159E-02 91 7.1764E-02 7.0393E-02 5.2974E-02 5.1673E-02 3.9851E-02 96 3.9255E-02 3.7685E-02 3.7366E-02 3.1766E-02 3.1171E-02 101 2.3389E-02 2.2545E-02 1.1355E-02 1.0842E-02 1.0519E-02 106 1.0450E-02 9.2061 E-03 9.0953E-03 7.8494E-03 7.6972E-03 111 5.5198E-03 5.3399E-03 3.4737E-03 3.3768E-03 3.0637E-03 116 3.0222E-03 2.4007E-03 2.3730E-03 2.3708E-03 2.3016E-03 121 7.4896E-04 6.9636E-04 1.0672E-03 1.0714E-03 7.9244E-04 126 7.9106E-04 1.0387E-03 1.0249E-03 4.6590E-04 4.3546E-04 131 3.1070E-04 3.0931 E-04 4.0243E-04 4.0658E-04 4.0670E-04 136 4.0809E-04 4.3911 E-04 4.3911 E-04 4.0827E-04 4.1519E-04 141 6.0135E-04 6.0411 E-04 4.8009E-04 4.7456E-04 4.7437E-04 146 4.7167E-04 4.1383E-04 6.0198E-04 4.8842E-03 4.8897E-03 151 7.3172E-04 5.4357E-04 4.7745E-04 4.8016E-04 6.0421 E-04 156 6.0559E-04 5.1256E-04 5.0841 E-04 5.0832E-04 5.0832E-04 161 5.0841 E-04 5.1256E-04 6.0553E-04 6.0137E-04 4.1494E-04 166 3.9701 E-04 1.8324E-04 3.4648E-04 4.2253E-03 4.2364E-03 171 6.0621 E-04 4A988E-04 5.7035E-04 5.7030E-04 4.4630E-04 176 4.4492E-04 5.3777E-04 5.3361 E-04 3.4740E-04 3.3910E-04 181 3.3891 E-04 3.3891EE-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 186 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 191 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 196 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 201 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 206 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 211 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 216 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 221 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 226 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 231 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04

236 3.3891E-04 3.3891E-04 3.3891E-04 3.3891E-04 3.3891E-04 241 3.3891E-04 3.3891E-04 3.3891E-04 3.3891E-04 3.3891E-04 246 3.3891E-04 3.3891E-04 3.3891E-04 3.3891E-04 3.3891E-04 C-14 Concentrations at time =5.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (C/cmA3) at nodes 1,1+1,...,1+4 251 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 256 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891E-04 261 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891E-04 266 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891E-04 271 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 276 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 281 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 286 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 291 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 296 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 301 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 306 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 311 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 316 3.3891E-04 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 321 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 326 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 331 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 336 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 341 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 346 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 351 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 356 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 361 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 366 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891 E-04 371 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891E-04 376 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 381 3.3891 E-04 3.3891 E-04 3.3891 E-04 3.3891E-04 3.3891E-04 386 3.3891E-04 3.3891E-04 3.3891 E-04 3.3891E-04 3.3891 E-04 391 3.3891E-04 3.3891E-04 3.3890E-04 3.3859E-04 3.2452E-04 396 9.8439E-07 9.8372E-07 9.8338E-07 9.8303E-07 9.8267E-07 401 9.8230E-07 9.8192E-07 9.8153E-07 9.8113E-07 9.8072E-07 406 9.7543E-07 9.6854E-07 9.6034E-07 9.5084E-07 9A006E-07 411 9.2806E-07 9.1487E-07 9.0053E-07 8.8510E-07 8.6863E-07 416 8.5120E-07 8.5237E-07 8.1488E-07 7.7431 E-07 7.3126E-07 421 6.8635E-07 6.4022E-07 5.9349E-07 5.4674E-07 5.0053E-07 426 4.5536E-07 4.1167E-07 3.6983E-07 3.3016E-07 2.9289E-07 431 2.5819E-07 2.2618E-07 1.9688E-07 1.7031 E-07 1.4639E-07 436 1.2505E-07 1.0614E-07 8.9532E-08 7.5048E-08 6.2514E-08 441 5.1748E-08 4.2570E-08 3.4802E-08 2.8274E-08 2.2829E-08 446 1.8318E-08 1.4608E-08 1.1578E-08 9.1196E-09 7.1393E-09

451 5.5549E-09 4.2958E-09 3.3018E-09 2.5225E-09 1.9154E-09 456 1.4456E-09 1.0845E-09 8.0867E-10 5.9934E-10 4.4147E-10 461 3.2314E-10 2.3494E-10 1.6953E-10 1.2121E-10 8.5538E-1 1 466 5.9103E-11 3.9241E-11 2.3856E-11 1.1245E-11 2.7805E-12 H-3 Concentrations at time =6.300E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass In solution = 2.47E-1 I Mass sorbed = O.OOE+00 Total Mass = 2.47E-1 I 1 1.2710E-24 5.0841E-24 1.0170E-23 1.5259E-23 2.0353E-23 6 2.5454E-23 3.0564E-23 3.5683E-23 4.0814E-23 4.5957E-23 11 5.1115E-23 5.6288E-23 6.1479E-23 6.6687E-23 7.1914E-23 16 7.7161E-23 8.2430E-23 8.7720E-23 9.3032E-23 9.8366E-23 21 1.0372E-22 1.0911 E-22 1.1451 E-22 1.1994E-22 1.2539E-22 26 1.3086E-22 1.3636E-22 1.4188E-22 1.4742E-22 1.5298E-22 31 1.5855E-22 1.6415E-22 1.6976E-22 1.7539E-22 1.8103E-22 36 1.8668E-22 1.9234E-22 1.9800E-22 2.0367E-22 2.0934E-22 41 2.1219E-22 2.1502E-22 2.1786E-22 2.2069E-22 2.2352E-22 46 2.2635E-22 2.2918E-22 2.3200E-22 2.3483E-22 2.3765E-22 51 2.3787E-22 2.3811 E-22 2.3834E-22 2.3858E-22 2.3881 E-22 56 2.3905E-22 2.3928E-22 2.4001 E-22 1.7575E-16 1.7570E-16 61 1.7564E-16 1.7554E-16 1.7542E-16 1.7526E-16 1.7507E-16 66 1.7484E-16 1.7459E-16 1.7430E-16 1.7398E-16 1.7363E-16 71 1.7325E-16 1.7283E-16 1.7239E-16 1.7191E-16 1.7141E-16 76 1.7087E-16 1.7030E-16 1.6971 E-16 1.6908E-16 1.6843E-16 81 1.6774E-16 1.6703E-16 1.6629E-16 1.6553E-1 6 1.6473E-16 86 1.6391E-16 1.6306E-16 1.6219E-16 1.6129E-16 1.6037E-16 91 1.5942E-16 1.5845E-16 1.5746E-16 1.5644E-16 1.5540E-16 96 1.5434E-16 1.5326E-16 1.5215E-16 1.5103E-16 1.4989E-16 101 1.4873E-16 1.4754E-16 1.4635E-16 1.4513E-16 1.4390E-16 106 1.4265E-16 1.4139E-16 1.4011 E-16 1.3882E-16 1.3751E-16 111 1.3619E-16 1.3486E-16 1.3352E-16 1.3217E-16 1.3080E-16 116 1.2943E-16 1.2805E-16 1.2665E-16 1.2525E-16 1.2385E-16 121 1.2243E-16 1.2101E-16 1.1958E-16 1.1815E-16 1.1672E-16 126 1.1528E-16 1.1383E-16 1.1239E-16 1.1094E-16 1.0949E-16 131 1.0804E-16 1.0659E-16 1.0514E-16 1.0369E-16 1.0224E-16 136 1.0079E-16 9.9350E-17 9.7908E-1 7 9.6469E-17 9.5033E-1 7 141 9.3602E-17 9.2176E-17 9.0754E-1 7 8.9338E-17 8.7928E-17 146 8.6525E-17 8.5128E-17 8.3738E-1 7 8.2356E-17 8.0982E-17 151 7.9616E-17 7.8259E-17 7.6911 E-17 7.5573E-17 7.4244E-17 156 7.2925E-17 7.1617E-17 7.0319E-17 6.9033E-17 6.7757E-17 161 6.6493E-17 6.5241 E-1 7 6.4000E-17 6.2772E-17 6.1556E-17 166 6.0353E-17 5.9163E-17 5.7985E-17 5.6821E-1 7 5.5670E-17

171 5A533E-17 5.3409E-17 5.2299E-17 5.1203E-1 7 5.0121E-17 176 4.9053E-17 4.7999E-17 4.6959E-17 4.5934E-1 7 4.4923E-17 181 4.3926E-17 4.2944E-17 4.1976E-17 4.1023E-17 4.0084E-17 186 3.9160E-17 3.8251 E-1 7 3.7356E-17 3.6475E-1 7 3.5609E-17 191 3.4758E-17 3.3921 E-1 7 3.3098E-17 3.2290E-1 7 3.1496E-17 196 3.0716E-17 2.9950E-17 2.9198E-17 2.8460E-17 2.7736E-17 201 2.7026E-17 2.6330E-1 7 2.5647E-17 2.4978E-1 7 2.4321 E-1 7 206 2.3679E-17 2.3049E-1 7 2.2432E-17 2.1828E-17 2.1237E-17 211 2.0659E-17 2.0093E-1 7 1.9539E-17 1.8997E-17 1.8467E-17 216 1.7950E-17 1.7444E-17 1.6949E-17 1.6466E-17 1.5994E-17 221 1.5533E-17 1.5083E-1 7 1.4644E-17 1.4215E-17 1.3797E-17 226 1.3389E-17 1.2992E-1 7 1.2604E-1 7 1.2226E-17 1.1857E-17 231 1.1498E-17 1.1148E-17 1.0807E-1 7 1.0476E-17 1.0153E-17 236 9.8382E-18 9.5323E-18 9.2345E-1 8 8.9449E-18 8.6633E-18 241 8.3894E-18 8.1231 E-18 7.8643E-1 8 7.6128E-18 7.3685E-18 246 7.1312E-18 6.9007E-18 6.6769E-18 6.4596E-18 6.2488E-18 H-3 Concentrations at time =6.300E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 6.0441E-18 5.8456E-18 5.6531E-18 5.4663E-18 5.2852E-18 256 5.1097E-18 4.9396E-18 4.7747E-18 4.6150E-18 4.4602E-1 8 261 4.3104E-18 4.1653E-18 4.0248E-18 3.8888E-18 3.7572E-18 266 3.6299E-18 3.5067E-1 8 3.3875E-18 3.2723E-18 3.1609E-18 271 3.0532E-18 2.9491 E-18 2.8485E-18 2.7513E-18 2.6574E-18 276 2.5666E-18 2.4790E-1 8 2.3945E-18 2.3128E-18 2.2340E-1 8 281 2.1579E-18 2.0844E-18 2.0136E-18 1.9453E-18 1.8793E-1 8 286 1.8158E-18 1.7544E-18 1.6953E-18 1.6383E-18 1.5834E-18 291 1.5304E-18 1.4794E-18 1.4302E-18 1.3828E-18 1.3371 E-18 296 1.2931 E-18 1.2507E-18 1.2099E-18 1.1705E-18 1.1327E-18 301 1.0962E-18 1.0610E-18 1.0272E-18 9.9460E-19 9.6321 E-1 9 306 9.3299E-19 9.0389E-19 8.7586E-1 9 8A886E-19 8.2286E-19 311 7.9782E-19 7.7370E-19 7.5046E-1 9 7.2808E-19 7.0651 E-1 9 316 6.8573E-19 6.6570E-19 6.4639E-19 6.2778E-19 6.0983E-19 321 5.9253E-19 5.7583E-19 5.5972E-19 5.4417E-19 5.2917E-19 326 5.1467E-19 5.0067E-19 4.8714E-19 4.7407E-19 4.6142E-19 331 4A919E-19 4.3735E-19 4.2589E-19 4.1479E-19 4.0404E-19 336 3.9361E-19 3.8349E-19 3.7367E-19 3.6414E-19 3.5487E-19 341 3.4587E-19 3.3711E-19 3.2858E-19 3.2028E-19 3.1219E-19 346 3.0430E-19 2.9660E-19 2.8908E-19 2.8173E-19 2.7455E-19 351 2.6752E-19 2.6064E-19 2.5390E-19 2.4729E-19 2.4081E-19 356 2.3444E-19 2.2819E-19 2.2204E-19 2.1599E-19 2.1003E-19 361 2.0417E-19 1.9839E-19 1.9269E-19 1.8706E-19 1.8150E-19 366 1.7601E-19 1.7058E-19 1.6521E-19 1.5989E-19 1.5463E-19 371 1.4941 E-19 1.4424E-19 1.3911E-19 1.3403E-19 1.2897E-1 9 376 1.2396E-19 1.1897E-19 1.1402E-19 1.0909E-19 1.0419E-19 381 9.931OE-20 9.4455E-20 8.9620E-20 8.4804E-20 8.0004E-20

386 7.5221E-20 7.0452E-20 6.5695E-20 6.0950E-20 5.6215E-20 391 5.1490E-20 4.6772E-20 4.2060E-20 3.7355E-20 3.2653E-20 396 2.7955E-20 2.7904E-20 2.7878E-20 2.7852E-20 2.7826E-20 401 2.7800E-20 2.7775E-20 2.7749E-20 2.7723E-20 2.7697E-20 406 2.7405E-20 2.7099E-20 2.6794E-20 2.6491 E-20 2.6190E-20 411 2.5889E-20 2.5591 E-20 2.5293E-20 2.4997E-20 2.4703E-20 416 2.4409E-20 2.4429E-20 2.3846E-20 2.3268E-20 2.2696E-20 421 2.2128E-20 2.1565E-20 2.1007E-20 2.0454E-20 1.9905E-20 426 1.9362E-20 1.8823E-20 1.8289E-20 1.7761E-20 1.7237E-20 431 1.6718E-20 1.6204E-20 1.5695E-20 1.5191 E-20 1.4692E-20 436 1.4199E-20 1.3710E-20 1.3227E-20 1.2749E-20 1.2276E-20 441 1.1808E-20 1.1345E-20 1.0888E-20 1.0435E-20 9.9873E-21 446 9.5444E-21 9.1063E-21 8.6729E-21 8.2441 E-21 7.8198E-21 451 7.3997E-21 6.9839E-21 6.5721 E-21 6.1642E-21 5.7600E-21 456 5.3593E-21 4.9620E-21 4.5678E-21 4.1766E-21 3.7880E-21 461 3.4019E-21 3.0182E-21 2.6364E-21 2.2564E-21 1.8780E-21 466 1.5008E-21 1.1247E-21 7.4936E-22 3.7455E-22 9.3630E-23 C-14 Concentrations at time =6.300E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.11 E+04 Mass sorbed = O.OOE+00 Total Mass = 2.11E+04 1 1.8659E-15 7.5390E-15 1.5915E-14 2.5991E-14 3.8803E-14 6 5.5628E-14 7.8087E-14 1.0827E-13 1.4890E-13 2.0351E-13 11 2.7674E-13 3.7457E-13 5.0477E-1 3 6.7737E-13 9.0523E-13 16 1.2048E-12 1.5970E-12 2.1084E-12 2.7724E-12 3.6311 E-12 21 4.7370E-12 6.1556E-12 7.9679E-12 1.0274E-1 1 1.3197E-1 1 26 1.6886E-11 2.1526E-11 2.7337E-1 1 3.4589E-1 1 4.3604E-1 I 31 5A768E-11 6.8541E-11 8.5472E-1 I 1.0621E-10 1.3151E-10 36 1.6227E-10 1.9955E-10 2.4456E-10 2.9870E-10 3.6363E-10 41 4.0095E-10 4.4160E-10 4.8596E-10 5.3433E-1 0 5.8702E-10 46 6.4438E-10 7.0678E-10 7.7459E-10 8.4824E-1 0 9.2816E-10 51 9.3496E-10 9A196E-10 9.4902E-10 9.5613E-10 9.6328E-10 56 9.7048E-10 9.7773E-10 1.0005E-09 5.5240E-04 3.7326E-02 61 7.6155E-01 7.9830E-01 8.2090E-01 8.2295E-01 8.4262E-01 66 8.4730E-01 9.2275E-01 9.2370E-01 8.6747E-01 8.4851E-01 71 5.1910E-01 4.9534E-01 3A147E-01 3.3170E-01 2.8659E-01 76 2.8482E-01 2.9356E-01 2.9156E-01 2.4200E-01 2.3705E-01 81 1.8591E-01 1.8166E-01 1A644E-01 1.4415E-01 1.3278E-01 86 1.3118E-01 1.1005E-01 1.0795E-01 8.6205E-02 8.4489E-02 91 7.1300E-02 6.9810E-02 5.2665E-02 5.1251 E-02 3.9615E-02 96 3.8967E-02 3.7418E-02 3.7072E-02 3.1559E-02 3.0912E-02 101 2.3252E-02 2.2334E-02 1.1322E-02 1.0765E-02 1.0445E-02

106 1.0369E-02 9.1447E-03 9.0243E-03 7.7977E-03 7.6321E-03 111 5.4891 E-03 5.2935E-03 3.4568E-03 3.3514E-03 3.0428E-03 116 2.9977E-03 2.3861 E-03 2.3559E-03 2.3533E-03 2.2781 E-03 121 7.5049E-04 6.9330E-04 1.0578E-03 1.0623E-03 7.8800E-04 126 7.8649E-04 1.0300E-03 1.0149E-03 4.6497E-04 4.3188E-04 131 3.0903E-04 3.0751E-04 3.9910E-04 4.0362E-04 4.0377E-04 136 4.0527E-04 4.3579E-04 4.3579E-04 4.0550E-04 4.1302E-04 141 5.9615E-04 5.9916E-04 4.7717E-04 4.7115E-04 4.7093E-04 146 4.6801E-04 4.1202E-04 6.1657E-04 4.8291E-03 4.8351E-03 151 7.4480E-04 5.4025E-04 4.7432E-04 4.7725E-04 5.9927E-04 156 6.0077E-04 5.0926E-04 5.0475E-04 5.0464E-04 5.0464E-04 161 5.0475E-04 5.0926E-04 6.0070E-04 5.9618E-04 4.1272E-04 166 3.9324E-04 1.8370E-04 3.6118E-04 4.1768E-03 4.1889E-03 171 6.1 i90E-04 4.4795E-04 5.6567E-04 5.6560E-04 4.4365E-04 176 4.4214E-04 5.3343E-04 5.2891E-04 3.4571E-04 3.3668E-04 181 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 186 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 191 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 196 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 201 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 206 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 211 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 216 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 221 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 226 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 231 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 236 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 241 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 246 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 C-14 Concentrations at time =6.300E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 251 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 256 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 261 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 266 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 271 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 276 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 281 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 286 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 291 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 296 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 301 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 306 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 311 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 316 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04

321 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 326 3.3646E-04 3.3646E-04 3,3646E-04 3.3646E-04 3.3646E-04 331 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 336 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 341 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 346 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 351 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 356 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 361 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 366 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 371 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 376 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 381 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 386 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 3.3646E-04 391 3.3646E-04 3.3646E-04 3.3645E-04 3.3608E-04 3.2074E-04 396 9.3707E-07 9.3641 E-07 9.3607E-07 9.3573E-07 9.3538E-07 401 9.3502E-07 9.3465E-07 9.3428E-07 9.3389E-07 9.3350E-07 406 9.2850E-07 9.2212E-07 9.1461E-07 9.0601E-07 8.9633E-07 411 8.8559E-07 8.7384E-07 8.61 1OE-07 8.4742E-07 8.3284E-07 416 8.1741E-07 8.1845E-07 7.8530E-07 7.4938E-07 7.1118E-07 421 6.7120E-07 6.2995E-07 5.8793E-07 5.4564E-07 5.0355E-07 426 4.6208E-07 4.2163E-07 3.8254E-07 3.4511E-07 3.0957E-07 431 2.7611 E-07 2.4487E-07 2.1593E-07 1.8932E-07 1.6505E-07 436 1.4307E-07 1.2332E-07 1.0569E-07 9.0061 E-08 7.631 OE-08 441 6.4292E-08 5.3861E-08 4.4867E-08 3.7163E-08 3.0609E-08 446 2.5069E-08 2.0416E-08 1.6534E-08 1.3314E-08 1.0662E-08 451 8.4905E-09 6.7236E-09 5.2948E-09 4.1464E-09 3.2292E-09 456 2.5009E-09 1.9261E-09 1.4752E-09 1.1234E-09 8.5064E-10 461 6.4020E-10 4.7866E-10 3.5514E-10 2.6092E-10 1.8899E-10 466 1.3376E-10 9.0670E-1 1 5.6026E-1 1 2.6693E-1 I 6.6135E-12 H-3 Concentrations at time =6.600E.02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 4.80E-12 Mass sorbed = O.OOE+00 Total Mass = 4.80E-12 I 2.4922E-25 9.9692E-25 1.9941E-24 2.9919E-24 3.9904E-24 6 4.9900E-24 5.9909E-24 6.9934E-24 7.9977E-24 9.0040E-24 11 1.0013E-23 1.1024E-23 1.2037E-23 1.3054E-23 1.4073E-23 16 1.5096E-23 1.6122E-23 1.7151E-23 1.8184E-23 1.9220E-23 21 2.0259E-23 2.1302E-23 2.2349E-23 2.3399E-23 2.4453E-23 26 2.5510E-23 2.6571 E-23 2.7634E-23 2.8700E-23 2.9770E-23 31 3.0841E-23 3.1915E-23 3.2991E-23 3.4069E-23 3.5148E-23 36 3.6229E-23 3.7310E-23 3.8391E-23 3.9472E-23 4.0553E-23

41 4.1094E-23 4.1634E-23 4.2173E-23 4.2711 E-23 4.3250E-23 46 4.3787E-23 4.4324E-23 4.4860E-23 4.5396E-23 4.5930E-23 51 4.5974E-23 4.6018E-23 4.6063E-23 4.6107E-23 4.6152E-23 56 4.6196E-23 4.6241 E-23 4.6379E-23 3.3317E-17 3.3307E-17 61 3.3296E-17 3.3279E-17 3.3256E-17 3.3227E-17 3.3193E-17 66 3.3152E-17 3.3106E-17 3.3054E-17 3.2996E-17 3.2932E-17 71 3.2863E-17 3.2788E-17 3.2707E-17 3.2621 E-17 3.2529E-17 76 3.2431 E-17 3.2328E-17 3.2220E-1 7 3.2107E-17 3.1988E-17 81 3.1863E-17 3.1734E-17 3.1600E-17 3.1460E-17 3.1316E-17 86 3.1167E-17 3.1013E-17 3.0854E-1 7 3.0691 E-1 7 3.0523E-17 91 3.0350E-17 3.0173E-1 7 2.9992E-17 2.9807E-17 2.9618E-17 96 2.9424E-17 2.9227E-1 7 2.9025E-1 7 2.8820E-17 2.8612E-17 101 2.8400E-1 7 2.8184E-1 7 2.7965E-1 7 2.7743E-17 2.7518E-17 106 2.7290E-1 7 2.7059E-1 7 2.6825E-1 7 2.6588E-17 2.6349E-17 111 2.6107E-1 7 2.5863E-1 7 2.5617E-17 2.5368E-17 2.5118E-17 116 2.4865E-17 2.4611 E-17 2.4355E-1 7 2.4098E-17 2.3839E-17 121 2.3578E-17 2.3316E-17 2.3054E-17 2.2790E-17 2.2525E-17 126 2.2259E-17 2.1992E-17 2.1725E-17 2.1457E-1 7 2.1189E-17 131 2.0921 E-1 7 2.0652E-17 2.0383E-1 7 2.0114E-17 1.9845E-17 136 1.9577E-17 1.9308E-17 1.9040E-17 1.8772E-17 1.8505E-17 141 1.8238E-17 1.7972E-17 1.7707E-17 1.7443E-17 1.7179E-17 146 1.6917E-17 1.6656E-17 1.6395E-17 1.6136E-17 1.5879E-17 151 1.5623E-17 1.5368E-17 1.5114E-17 1.4863E-17 1.4613E-17 156 1.4364E-17 1.4118E-17 1.3873E-17 1.3630E-17 1.3389E-17 161 1.3150E-17 1.2913E-17 1.2678E-17 1.2445E-17 1.2214E-1 7 166 1.1986E-17 1.1759E-17 1.1535E-17 1.1314E-17 1.1094E-17 171 1.0877E-17 1.0663E-17 1.0451 E-17 1.0241E-17 1.0034E-17 176 9.8291 E-1 8 9.6269E-18 9.4272E-18 9.2301 E-1 8 9.0356E-18 181 8.8437E-18 8.6543E-18 8.4676E-18 8.2835E-18 8.1020E-18 186 7.9232E-18 7.7469E-18 7.5733E-18 7.4024E-18 7.2341 E-18 191 7.0684E-18 6.9053E-18 6.7449E-18 6.5871 E-1 8 6.4319E-18 196 6.2794E-1 8 6.1294E-18 5.9820E-18 5.8372E-18 5.6949E-18 201 5.5552E-18 5.4180E-18 5.2834E-18 5.1512E-18 5.0215E-18 206 4.8943E-18 4.7696E-18 4.6472E-1 8 4.5273E-18 4.4098E-18 211 4.2946E-18 4.1817E-18 4.0712E-1 8 3.9630E-18 3.8570E-18 216 3.7533E-1 8 3.6518E-1 8 3.5525E-1 8 3.4553E-18 3.3603E-18 221 3.2674E-1 8 3.1766E-18 3.0878E-1 8 3.OOIOE-18 2.9163E-18 226 2.8335E-1 8 2.7527E-1 8 2.6738E-1 8 2.5967E-18 2.5215E-18 231 2.4481E-18 2.3766E-1 8 2.3068E-1 8 2.2387E-18 2.1723E-18 236 2.1076E-18 2.0446E-18 1.9832E-18 1.9233E-18 1.8650E-18 241 1.8083E-18 1.7530E-18 1.6992E-18 1.6469E-18 1.5960E-18 246 1.5464E-18 1.4982E-18 1.4514E-18 1.4058E-18 1.3615E-18 H-3 Concentrations at time =6.600E+02 ,(Det =1.OOOE+00)

Node I Concentration (Ci/cmn^3) at nodes 1,1+1...,1+4 251 1.3185E-18 1.2767E-18 1.2361E-18 1.1966E-18 1.1583E-18

I 256 1.1211E-18 1.0850E-18 1.0499E-18 1.0159E-18 9.8293E-19 261 9.5092E-19 9.1988E-19 8.8978E-19 8.6060E-19 8.3231E-19 266 8.0490E-19 7.7833E-19 7.5260E-19 7.2767E-19 7.0353E-19 271 6.8016E-19 6.5753E-19 6.3563E-19 6.1443E-19 5.9392E-19 276 5.7407E-19 5.5487E-19 5.3631 E-1 9 5.1835E-19 5.0099E-19 281 4.8421E-19 4.6799E-19 4.5231 E-19 4.3717E-19 4.2253E-19 286 4.0839E-1 9 3.9474E-1 9 3.8155E-19 3.6881 E-19 3.5652E-19 291 3.4465E-19 3.3319E-19 3.2213E-19 3.1146E-19 3.0116E-19 296 2.9122E-19 2.8163E-1 9 2.7238E-19 2.6346E-19 2.5485E-19 301 2.4655E-19 2.3855E-1 9 2.3083E-19 2.2339E-19 2.1621E-19 306 2.0929E-19 2.0261 E-1 9 1.9618E-19 1.8997E-19 1.8399E-19 311 1.7823E-1 9 1.7266E-1 9 1.6730E-1 9 1.6213E-19 1.5715E-19 316 1.5234E-19 1.4770E-1 9 1.4323E-1 9 1.3891 E-1 9 1.3475E-19 321 1.3073E-19 1.2686E-19 1.2312E-19 1.1951E-19 1.1602E-19 326 1.1266E-19 1.0941 E-19 1.0627E-1 9 1.0323E-19 1.0030E-19 331 9.7463E-20 9.4720E-20 9.2067E-20 8.9499E-20 8.7013E-20 336 8.4605E-20 8.2273E-20 8.0013E-20 7.7821 E-20 7.5695E-20 341 7.3631 E-20 7.1628E-20 6.9682E-20 6.7791E-20 6.5952E-20 346 6.4162E-20 6.2421 E-20 6.0725E-20 5.9071E-20 5.7460E-20 351 5.5887E-20 5.4352E-20 5.2852E-20 5.1386E-20 4.9952E-20 356 4.8549E-20 4.7175E-20 4.5828E-20 4.4508E-20 4.3213E-20 361 4.1941E-20 4.0692E-20 3.9463E-20 3.8255E-20 3.7066E-20 366 3.5895E-20 3.4741 E-20 3.3603E-20 3.2480E-20 3.1371E-20 371 3.0276E-20 2.9194E-20 2.8123E-20 2.7064E-20 2.6016E-20 376 2.4977E-20 2.3948E-20 2.2927E-20 2.1914E-20 2.0909E-20 381 1.9911 E-20 1.8920E-20 1.7935E-20 1.6955E-20 1.5980E-20 386 1.5010E-20 1.4044E-20 1.3083E-20 1.2124E-20 1.1169E-20 391 1.0216E-20 9.2661 E-21 8.3178E-21 7.3712E-21 6.4259E-21 396 5.4816E-21 5.4712E-21 5.4661 E-21 5.4609E-21 5.4557E-21 401 5.4505E-21 5.4453E-21 5.4402E-21 5.4350E-21 5.4298E-21 406 5.3713E-21 5.31OOE-21 5.2492E-21 5.1887E-21 5.1287E-21 411 5.0691 E-21 5.0098E-21 4.9510E-21 4.8925E-21 4.8343E-21 416 4.7765E-21 4.7803E-21 4.6656E-21 4.5522E-21 4.4400E-21 421 4.3291 E-21 4.2192E-21 4.1105E-21 4.0028E-21 3.8962E-21 426 3.7906E-21 3.6861 E-21 3.5825E-21 3.4800E-21 3.3784E-21 431 3.2779E-21 3.1783E-21 3.0797E-21 2.9821 E-21 2.8854E-21 436 2.7897E-21 2.6950E-21 2.6012E-21 2.5083E-21 2.4164E-21 441 2.3255E-21 2.2354E-21 2.1463E-21 2.0580E-21 1.9707E-21 446 1.8842E-21 1.7986E-21 1.7138E-21 1.6298E-21 1.5466E-21 451 1.4641E-21 1.3824E-21 1.3015E-21 1.2212E-21 1.1415E-21 456 1.0625E-21 9.8407E-22 9.0618E-22 8.2881 E-22 7.5191 E-22 461 6.7545E-22 5.9938E-22 5.2367E-22 4.4828E-22 3.7315E-22 466 2.9825E-22 2.2353E-22 1.4894E-22 7.4447E-23 1.8611 E-23 C-14 Concentrations at time =6.600E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4

Mass In solution = 2.1 1E+04 Mass sorbed = O.OOE+00 Total Mass = 2.11E+04 I 2.8476E-15 1.1498E-14 2.4182E-14 3.9266E-14 5.8195E-14 6 8.2726E-14 1 .1506E-13 1.5800E-1 3 2.1515E-13 2.9115E-13 11 3.9201 E-13 5.2541E-13 7.0124E-13 9.3211E-13 1.2341 E-12 16 1.6275E-12 2.1381E-12 2.7980E-12 3.6478E-12 4.7376E-12 21 6.1299E-12 7.9017E-12 1.0148E-11 1.2985E-1 I 1.6554E-1 I 26 2.1028E-1 1 2.6615E-11 3.3567E-1 1 4.2184E-1 1 5.2828E-1 1 31 6.5927E-1 I 8.1991E-11 1.0162E-10 1.2553E-10 1.5454E-10 36 1.8962E-10 2.3192E-10 2.8272E-10 3.4355E-10 4.1615E-10 41 4.5773E-10 5.0292E-10 5.5212E-10 6.0566E-10 6.6386E-10 46 7.2708E-10 7.9571E-10 8.7015E-10 9.5084E-10 1.0382E-09 51 1.0457E-09 1.0533E-09 1.061OE-09 1.0688E-09 1.0766E-09 56 1.0844E-09 1.0923E-09 1.1172E-09 6.0258E-04 3.8850E-02 61 7.5719E-01 7.9537E-01 8.1788E-01 8.2001E-01 8.3954E-01 66 8.4440E-01 9.1923E-01 9.2022E-01 8.6441 E-01 8.4471 E-01 71 5.1793E-01 4.9325E-01 3.4057E-01 3.3041 E-01 2.8566E-01 76 2.8381 E-01 2.9247E-01 2.9039E-01 2.4123E-01 2.3608E-01 81 1.8534E-01 1.8093E-01 1.4599E-01 1.4361 E-01 1.3232E-01 86 1.3066E-01 1.0970E-01 1.0751 E-01 8.5939E-02 8.4156E-02 91 7.1069E-02 6.9521 E-02 5.2511 E-02 5.1041 E-02 3.9497E-02 96 3.8824E-02 3.7285E-02 3.6925E-02 3.1456E-02 3.0784E-02 101 2.3183E-02 2.2229E-02 1.1305E-02 1.0727E-02 1.0407E-02 106 1.0329E-02 9.1142E-03 8.9891 E-03 7.7719E-03 7.5999E-03 111 5.4738E-03 5.2705E-03 3.4483E-03 3.3388E-03 3.0324E-03 116 2.9855E-03 2.3788E-03 2.3475E-03 2.3446E-03 2.2665E-03 121 7.5120E-04 6.9178E-04 1.0532E-03 1.0578E-03 7.8578E-04 126 7.8422E-04 1.0257E-03 1.0100E-03 4.6449E-04 4.301 OE-04 131 3.0819E-04 3.0661 E-04 3.9745E-04 4.0215E-04 4.0231 E-04 136 4.0387E-04 4.3414E-04 4.3414E-04 4.0412E-04 4.1193E-04 141 5.9357E-04 5.9669E-04 4.7571 E-04 4.6946E-04 4.6922E-04 146 4.6619E-04 4.1115E-04 6.2368E-04 4.8017E-03 4.8080E-03 151 7.5116E-04 5.3863E-04 4.7277E-04 4.7580E-04 5.9682E-04 156 5.9838E-04 5.0762E-04 5.0294E-04 5.0281E-04 5.0281 E-04 161 5.0294E-04 5.0762E-04 5.9830E-04 5.9360E-04 4.1160E-04 166 3.9137E-04 1.8395E-04 3.6835E-04 4.1528E-03 4.1653E-03 171 6.2359E-04 4.4701 E-04 5.6334E-04 5.6326E-04 4.4232E-04 176 4.4076E-04 5.3127E-04 5.2658E-04 3.4486E-04 3.3549E-04 181 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 186 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 191 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 196 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 201 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 206 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 211 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 216 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 221 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04

226 3.3524E404 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 231 3.3524EO04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 236 3.3524E 04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 241 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 246 3.3524E-04 3.3524E-04 3.3524E (14 3.3524E-04 3.3524E-04 C-14 Concentrations at time =6.600E+02 ,(Delt = 1.000E+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 256 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 261 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E044 3.3524E-04 266 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 271 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E044 3.3524E-04 276 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 281 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 286 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 291 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 296 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E-04 301 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 306 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 311 3.3524E-04 3.3524E'04 3.3524E404 3.3524E-04 3.3524E-04 316 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 321 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 326 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 331 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 336 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 341 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 346 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 351 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 356 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 361 3.3524E-04 3.3524E-04 3.3524E-04 3.3524EO04 3.3524E-04 366 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 371 3.3524E-04 3.3524E-04 3.3524E404 3.3524E044 3.3524E-04 376 3.3524E-04 3.3524E-04 3.3524E-04 3.3524E{04 3.3524E-04 381 3.3524E-04 3.3524E-04 3.3524E404 3.3524EO04 3.3524E-04 386 3.3524E-04 3.3524E-04 3.3524E404 3.3524E-04 3.3524E-04 391 3.3524E-04 3.3524E-04 3.3523E404 3.3482E044 3.1887E-04 396 9.1584E407 9.1519E-07 9.1486E407 9.1452E407 9.1417E-07 401 9.1381 E-07 9.1345E-07 9.1308E407 9.1271E-07 9.1232E-07 406 9.0744E-07 9.0127E-07 8.9406E407 8.8584E-07 8.7661E-07 411 8.6640E-07 8.5525E-07 8.4318E-07 8.3024E407 8.1645E-07 416 8.0187E-07 8.0285E-07 7.7152E-07 7.3758E-07 7.0145E-07 421 6.6359E-07 6.2445E-07 5.8450E407 5.4418E-07 5.0393E-07 426 4.6416E-07 4.2522E-07 3.8744E-07 3.511 1E-07 3.1647E-07 431 2.8369E-07 2.5294E-07 2.2429E407 1.9781 E-07 1.7350E-07 436 1.5136E-07 1.3132E-07 1.1332E407 9.7259E-08 8.3020E-08

441 7.0481E-08 5.9513E-08 4.9980E-08 4.1747E-08 3.4682E-08 446 2.8658E-08 2.3553E-08 1.9253E-08 1.5654E-08 1.2659E-08 451 1.0183E-08 8.1473E-09 6.4839E-09 5.1326E-09 4.0413E-09 456 3.1652E-09 2.4657E-09 1.9105E-09 1.4723E-09 1.1282E-09 461 8.5936E-10 6.5031E-10 4.8828E-10 3.6293E-10 2.6579E-10 466 1.9001E-10 1.2992E-10 8.0814E-1 1 3.8671 E-1 9.5892E-12 H-3 Concentrations at time =7.OOOE+02 (Deft =1 .OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 5.38E-13 Mass sorbed = O.OOE+00 Total Mass = 5.38E-13 1 2.8292E-26 1.1317E-25 2.2636E-25 3.3960E-25 4.5291 E-25 6 5.6630E-25 6.7980E-25 7.9343E-25 9.0721 E-25 1.0212E-24 11 1.1353E-24 1.2496E-24 1.3642E-24 I A789E-24 1.5940E-24 16 1.7092E-24 1.8248E-24 1.9406E-24 2.0566E-24 2.1729E-24 21 2.2896E-24 2.4064E-24 2.5236E-24 2.6410E-24 2.7586E-24 26 2.8765E-24 2.9946E-24 3.1130E-24 3.2315E-24 3.3501E-24 31 3.4690E-24 3.5879E-24 3.7069E-24 3.8260E-24 3.9451 E-24 36 4.0641 E-24 4.1831E-24 4.3020E-24 4.4208E-24 4.5394E-24 41 4.5987E-24 4.6578E-24 4.7169E-24 4.7758E-24 4.8347E-24 46 4.8935E-24 4.9522E-24 5.0107E-24 5.0692E-24 5.1275E-24 51 5.1323E-24 5.1371 E-24 5.1420E-24 5.1468E-24 5.1517E-24 56 5.1565E-24 5.1614E-24 5.1765E-24 3.6334E-18 3.6324E-18 61 3.6312E-18 3.6295E-18 3.6271E-18 3.6242E-18 3.6206E-18 66 3.6164E-18 3.6117E-18 3.6063E-18 3.6003E-18 3.5938E-18 71 3.5866E-18 3.5789E-18 3.5705E-18 3.5616E-18 3.5521 E-1 8 76 3.5421 E-18 3.5315E-18 3.5203E-18 3.5086E-18 3.4963E-18 81 3.4835E-18 3.4701 E-18 3.4562E-18 3.4418E-18 3.4269E-18 86 3.4115E-18 3.3955E-18 3.3791 E-1 8 3.3622E-18 3.3448E-18 91 3.3269E-18 3.3086E-18 3.2898E-18 3.2706E-1 8 3.251OE-18 96 3.2309E-18 3.2104E-18 3.1895E-18 3.1683E-1 8 3.1466E-18 101 3.1245E-18 3.1021E-18 3.0794E-18 3.0562E-1 8 3.0328E-1 8 106 3.0090E-1 8 2.9849E-18 2.9605E-18 2.9358E-18 2.9109E-1 8 111 2.8856E-1 8 2.8601E-18 2.8344E-18 2.8084E-18 2.7822E-18 116 2.7558E-18 2.7291 E-1 8 2.7023E-18 2.6753E-18 2.6481 E-1 8 121 2.6207E-18 2.5932E-18 2.5656E-18 2.5378E-18 2.5099E-18 126 2.4819E-18 2.4538E-1 8 2.4257E-18 2.3974E-18 2.3691 E-18 131 2.3407E-18 2.3123E-1 8 2.2838E-18 2.2553E-18 2.2268E-18 136 2.1983E-18 2.1698E-18 2.1413E-18 2.1128E-18 2.0844E-18 141 2.0560E-18 2.0276E-18 1.9993E-18 1.9711 E-18 1.9430E-18 146 1.9149E-18 1.8869E-18 1.8591E-18 1.8313E-18 1.8036E-18 151 1.7761E-18 1.7487E-18 1.7215E-18 1.6943E-18 1.6674E-18 156 1.6406E-18 1.6139E-18 1.5875E-18 1.5612E-18 1.5351E-18

161 1.5091 E-18 1.4834E-18 1.4579E-18 1.4325E-18 1.4074E-18 166 1.3825E-18 1.3578E-18 1.3334E-18 1.3091E-18 1.2851E-18 171 1.2613E-18 1.2378E-18 1.2145E-18 1.1914E-18 1.1686E-18 176 1.1461E-18 1.1238E-18 1.1017E-18 1.0799E-18 1.0584E-18 181 1.0371E-18 1.0161E-18 9.9534E-19 9.7486E-19 9.5464E-19 186 9.3470E-19 9.1502E-19 8.9561E-19 8.7648E-19 8.5761E-19 191 8.3902E-19 8.2070E-19 8.0265E-19 7.8487E-19 7.6736E-19 196 7.5013E-19 7.3316E-19 7.1647E-19 7.0004E-19 6.8388E-19 201 6.6799E-19 6.5237E-19 6.3701 E-19 6.2192E-19 6.0709E-19 206 5.9252E-19 5.7821E-19 5.6416E-19 5.5036E-19 5.3682E-19 211 5.2353E-19 5.1049E-19 4.9771E-19 4.8516E-19 4.7286E-19 216 4.6081E-19 4.4899E-19 4.3741E-19 4.2606E-19 4.1495E-19 221 4.0407E-19 3.9341E-19 3.8298E-19 3.7277E-19 3.6278E-19 226 3.5301E-19 3.4345E-19 3.3410E-19 3.2496E-19 3.1602E-19 231 3.0729E-19 2.9875E-19 2.9041 E-19 2.8227E-19 2.7431 E-19 236 2.6655E-19 2.5897E-19 2.5157E-19 2.4435E-19 2.3730E-19 241 2.3043E-19 2.2373E-19 2.1719E-19 2.1082E-19 2.0461E-19 246 1.9855E-19 1.9266E-19 1.8691E-19 1.8132E-19 1.7587E-19 H-3 Concentrations at time =7.OOOE+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cm^3) at nodes 1,1+1,...,1+4 251 1.7056E-19 1.6540E-19 1.6037E-19 1.5548E-19 1.5072E-19 256 1A609E-19 1.4159E-19 1.3721E-19 1.3296E-19 1.2882E-19 261 1.2480E-19 1.2090E-19 1.1710E-19 1.1341E-19 1.0983E-19 266 1.0636E-19 1.0298E-19 9.9705E-20 9.6526E-20 9.3441 E-20 271 9.0447E-20 8.7544E-20 8.4728E-20 8.1997E-20 7.9350E-20 276 7.6783E-20 7.4296E-20 7.1885E-20 6.9549E-20 6.7286E-20 281 6.5094E-20 6.2972E-20 6.0916E-20 5.8926E-20 5.6999E-20 286 5.5134E-20 5.3329E-20 5.1582E-20 4.9893E-20 4.8258E-20 291 4.6676E-20 4.5147E-20 4.3668E-20 4.2238E-20 4.0855E-20 296 3.9519E-20 3.8227E-20 3.6978E-20 3.5771 E-20 3.4605E-20 301 3.3479E-20 3.2390E-20 3.1338E-20 3.0322E-20 2.9341E-20 306 2.8393E-20 2.7478E-20 2.6594E-20 2.5741 E-20 2.4916E-20 311 2.4120E-20 2.3351E-20 2.2609E-20 2.1893E-20 2.1201E-20 316 2.0533E-20 1.9887E-20 1.9264E-20 1.8663E-20 1.8082E-20 321 1.7521 E-20 1.6979E-20 1.6456E-20 1.5950E-20 1.5462E-20 326 1.4990E-20 1.4534E-20 1.4094E-20 1.3668E-20 1.3256E-20 331 1.2859E-20 1.2474E-20 1.2102E-20 1.1742E-20 1.1393E-20 336 1.1056E-20 1.0730E-20 1.0413E-20 1.0107E-20 9.8106E-21 341 9.5230E-21 9.2442E-21 8.9738E-21 8.7115E-21 8.4568E-21 346 8.2096E-21 7.9694E-21 7.7359E-21 7.5090E-21 7.2882E-21 351 7.0734E-21 6.8642E-21 6.6605E-21 6A620E-21 6.2684E-21 356 6.0795E-21 5.8951 E-21 5.7150E-21 5.5391 E-21 5.3670E-21 361 5.1987E-21 5.0339E-21 4.8725E-21 4.7143E-21 4.5592E-21 366 4.4069E-21 4.2575E-21 4.1106E-21 3.9662E-21 3.8242E-21 371 3.6845E-21 3.5468E-21 3.4111 E-21 3.2774E-21 3.1454E-21

376 3.0150E-21 2.8863E-21 2.7590E-21 2.6331 E-21 2.5086E-21 381 2.3852E-21 2.2630E-21 2.1418E-21 2.0216E-21 1.9022E-21 386 1.7837E-21 1.6660E-21 1.5489E-21 1.4325E-21 1.3165E-21 391 1.2011E-21 1.0861 E-21 9.7140E-22 8.5702E-22 7.4286E-22 396 6.2886E-22 6.2762E-22 6.2699E-22 6.2636E-22 6.2574E-22 401 6.2512E-22 6.2449E-22 6.2387E-22 6.2325E-22 6.2263E-22 406 6.1559E-22 6.0824E-22 6.0097E-22 5.9377E-22 5.8663E-22 411 5.7957E-22 5.7257E-22 5.6563E-22 5.5874E-22 5.5192E-22 416 5.4515E-22 5.4560E-22 5.3222E-22 5.1904E-22 5.0606E-22 421 4.9326E-22 4.8062E-22 4.6816E-22 4.5584E-22 4.4368E-22 426 4.3166E-22 4.1978E-22 4.0803E-22 3.9641E-22 3.8492E-22 431 3.7355E-22 3.6230E-22 3.5116E-22 3.4014E-22 3.2923E-22 436 3.1843E-22 3.0774E-22 2.9716E-22 2.8667E-22 2.7629E-22 441 2.6601 E-22 2.5583E-22 2.4575E-22 2.3576E-22 2.2586E-22 446 2.1605E-22 2.0633E-22 1.9669E-22 1.8714E-22 1.7767E-22 451 1.6828E-22 1.5896E-22 1A971 E-22 1.4053E-22 1.3142E-22 456 1.2237E-22 1.1337E-22 1.0443E-22 9.5547E-23 8.6708E-23 461 7.7911 E-23 6.9154E-23 6.0432E-23 5.1741 E-23 4.3076E-23 466 3.4434E-23 2.5810E-23 1.7199E-23 8.5972E-24 2.1492E-24 C-14 Concentrations at tme =7.OOOE+02 ,(Det =1.OOOE+00)

Node I Concentration (ClI/cnA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.1OE+04 Mass sorbed = O.OOE+00 Total Mass = 2.1OE+04 I 4.7804E-15 1.9285E-14 4.0385E-14 6.5139E-14 9.5715E-14 6 1.3470E-13 1.8531E-13 2.5153E-13 3.3847E-13 4.5258E-13 11 6.0210E-13 7.9748E-13 1.0520E-12 1.3823E-12 1.8095E-12 16 2.3600E-12 3.0668E-12 3.9708E-12 5.1228E-12 6.5856E-12 21 8.4362E-12 1.0769E-11 1.3699E-1 I 1.7365E-1 I 2.1937E-1 I 26 2.7619E-11 3.4654E-1 I 4.3336E-1 I 5.4013E-11I 6.7097E-1 I 31 8.3079E-1 1 1.0254E-10 1.2614E-10 1.5469E-10 1.8910E-10 36 2.3044E-10 2.7996E-10 3.3909E-10 4.0946E-10 4.9296E-10 41 5.4058E-10 5.9219E-10 6.4823E-10 7.0904E-10 7.7499E-10 46 8.4644E-10 9.2380E-10 1.0075E-09 1.0980E-09 1.1958E-09 51 1.2041 E-09 1.2127E-09 1.2213E-09 1.2299E-09 1.2387E-09 56 1.2474E-09 1.2563E-09 1.2840E-09 6.7234E-04 4.0849E-02 61 7.5143E-01 7.9148E-01 8.1387E-01 8.1610E-01 8.3544E-01 66 8.4054E-01 9.1456E-01 9.1561E-01 8.6035E-01 8.3968E-01 71 5.1637E-01 4.9047E-01 3.3936E-01 3.2871E-01 2.8441E-01 76 2.8247E-01 2.9103E-01 2.8885E-01 2.4020E-01 2.3480E-01 81 1.8459E-01 1.7996E-01 1.4538E-01 1.4289E-01 1.3171E-01 86 1.2997E-01 11.0923E-01 1.0693E-01 8.5586E-02 8.3715E-02 91 7.0762E-02 6.9137E-02 5.2306E-02 5.0764E-02 3.9340E-02

96 3.8634E-02 3.7109E-02 3.6731 E-02 3.1319E-02 3.0614E-02 101 2.3092E-02 2.2091 E-02 1.1283E-02 1.0676E-02 1.0358E-02 106 1.0275E-02 9.0736E-03 8.9423E-03 7.7376E-03 7.5571 E-03 111 5.4533E-03 5.2401E-03 3.4370E-03 3.3221 E-03 3.0186E-03 116 2.9693E-03 2.3691 E-03 2.3362E-03 2.3331 E-03 2.251 1E-03 121 7.5209E-04 6.8975E-04 1.0470E-03 1.0519E-03 7.8283E-04 126 7.8119E-04 1.0199E-03 1.0035E-03 4.6384E-04 4.2776E-04 131 3.0708E-04 3.0542E-04 3.9527E-04 4.0019E-04 4.0037E-04 136 4.0201 E-04 4.3195E-04 4.3195E-04 4.0229E-04 4.1048E-04 141 5.9015E-04 5.9343E-04 4.7377E-04 4.6721 E-04 4.6695E-04 146 4.6378E-04 4.1002E-04 6.3297E-04 4.7656E-03 4.7722E-03 151 7.5945E-04 5.3651 E-04 4.7070E-04 4.7386E-04 5.9357E-04 156 5.9520E-04 5.0544E-04 5.0052E-04 5.0039E-04 5.0039E-04 161 5.0052E-04 5.0544E-04 5.9511 E-04 5.9019E-04 4.1012E-04 166 3.8890E-04 1.8429E-04 3.7773E-04 4.1211E-03 4.1342E-03 171 6.3101 E-04 4.4577E-04 5.6026E-04 5.6017E-04 4A056E-04 176 4.3891 E-04 5.2841E-04 5.2349E-04 3.4373E-04 3.3390E-04 181 3.3363E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 186 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 191 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 196 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 201 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 206 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 211 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 216 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 221 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 226 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 231 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 236 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 241 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 246 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 C-14 Concentrations at time =7.OOOE+02 ,(Delt =1.OOOE+00)

Node I Concentration (Cicm^3) at nodes 1,1+1,...,1+4 251 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 256 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 261 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 266 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 271 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 276 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 281 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 286 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 291 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 296 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 301 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 306 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04

311 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 316 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 321 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 326 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 331 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 336 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 341 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 346 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 351 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 356 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 361 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 366 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 371 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 376 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 381 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 386 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 3.3362E-04 391 3.3362E-04 3.3362E-04 3.3361E-04 3.3316E-04 3.1639E-04 396 8.8966E-07 8.8902E-07 8.8869E-07 8.8835E-07 8.8801 E-07 401 8.8766E-07 8.8731 E-07 8.8695E-07 8.8658E-07 8.8620E-07 406 8.8147E-07 8.7555E-07 8.6869E-07 8.6090E-07 8.5221 E-07 411 8.4263E-07 8.3218E-07 8.2090E-07 8.0882E-07 7.9596E-07 416 7.8237E-07 7.8329E-07 7.5412E-07 7.2251 E-07 6.8884E-07 421 6.5350E-07 6.1690E-07 5.7944E-07 5.4153E-07 5.0356E-07 426 4.6588E-07 4.2884E-07 3.9274E-07 3.5784E-07 3.2439E-07 431 2.9256E-07 2.6251 E-07 2.3434E-07 2.0813E-07 1.8389E-07 436 1.6165E-07 1.4137E-07 1.2301E-07 1.0648E-07 9.1697E-08 441 7.8565E-08 6.6970E-08 5.6795E-08 4.7920E-08 4.0225E-08 446 3.3595E-08 2.7914E-08 2.3077E-08 1.8981E-08 1.5532E-08 451 1.2647E-08 1.0245E-08 8.2572E-09 6.6217E-09 5.2833E-09 456 4.1941E-09 3.3126E-09 2.6028E-09 2.0344E-09 1.5815E-09 461 1.2222E-09 9.3827E-10 7.1458E-10 5.3848E-10 3.9951E-10 466 2.8897E-10 1.9957E-10 1.2510E-10 6.0165E-1 1 1.4933E-1 1 H-3 Concentrations at time =7.500E+02 (Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 3.49E-14 Mass sorbed = O.OOE+00 Total Mass = 3.49E-14 I 1.8555E-27 7.4219E-27 1.4845E-26 2.2269E-26 2.9697E-26 6 3.7128E-26 4.4563E-26 5.2004E-26 5.9451E-26 6.6904E-26 11 7.4365E-26 8.1833E-26 8.9310E-26 9.6796E-26 1.0429E-25 16 1.1180E-25 1.1931E-25 1.2683E-25 1.3437E-25 1A191E-25 21 1.4946E-25 1.5702E-25 1.6459E-25 1.7217E-25 1.7975E-25 26 1.8734E-25 1.9494E-25 2.0253E-25 2.1013E-25 2.1773E-25

-1 31 2.2533E-25 2.3293E-25 2.4052E-25 2.4811 E-25 2.5569E-25 36 2.6326E-25 2.7081 E-25 2.7835E-25 2.8587E-25 2.9336E-25 41 2.971 1E-25 3.0085E-25 3.0457E-25 3.0829E-25 3.1200E-25 46 3.1570E-25 3.1940E-25 3.2308E-25 3.2676E-25 3.3042E-25 51 3.3072E-25 3.3103E-25 3.3133E-25 3.3164E-25 3.3194E-25 56 3.3225E-25 3.3255E-25 3.3350E-25 2.2819E-19 2.2813E-19 61 2.2806E-19 2.2796E-19 2.2782E-19 2.2765E-19 2.2744E-19 66 2.2719E-19 2.2691E-19 2.2659E-19 2.2624E-19 2.2586E-1 9 71 2.2544E-19 2.2498E-1 9 2.2449E-19 2.2397E-19 2.2341 E-1 9 76 2.2282E-1 9 2.2219E-1 9 2.2154E-19 2.2085E-19 2.2012E-19 81 2.1937E-19 2.1858E-19 2.1776E-19 2.1691E-19 2.1603E-19 86 2.1512E-19 2.1418E-19 2.1321E-19 2.1221 E-19 2.1119E-19 91 2.1013E-19 2.0905E-1 9 2.0794E-19 2.0680E-19 2.0564E-19 96 2.0445E-19 2.0324E-19 2.0200E-1 9 2:0074E-19 1.9945E-19 101 1.9815E-19 1.9682E-19 1.9546E-19 1.9409E-19 1.9270E-19 106 1.9128E-19 1.8985E-19 1.8840E-19 1.8693E-19 1.8544E-19 111 1.8393E-19 1.8241E-19 1.8088E-19 1.7932E-19 1.7776E-19 116 1.7618E-19 1.7458E-19 1.7298E-19 1.7136E-19 1.6973E-19 121 1.6809E-19 1.6644E-19 1.6477E-19 1.6311 E-19 1.6143E-19 126 1.5974E-19 1.5805E-19 1.5635E-19 1.5464E-1 9 1.5293E-19 131 1.5122E-19 1.4950E-19 1.4778E-19 1.4605E-19 1.4432E-19 136 1.4259E-19 I.4086E-19 1.3913E-19 1.3740E-1 9 1.3567E-19 141 1.3394E-19 1.3221E-19 1.3048E-19 1.2875E-19 1.2703E-19 146 1.2532E-19 1.2360E-19 1.2189E-19 1.2019E-19 1.1849E-19 151 1.1679E-19 1.1511E-19 1.1343E-19 1.1175E-19 1.1009E-19 156 1.0843E-19 1.0678E-1 9 1.0514E-19 1.0351E-19 1.0189E-19 161 1.0028E-19 9.8677E-20 9.7086E-20 9.5506E-20 9.3937E-20 166 9.2380E-20 9.0835E-20 8.9302E-20 8.7781 E-20 8.6273E-20 171 8.4777E-20 8.3295E-20 8.1826E-20 8.0371 E-20 7.8930E-20 176 7.7502E-20 7.6089E-20 7A690E-20 7.3305E-20 7.1935E-20 181 7.0580E-20 6.9240E-20 6.7915E-20 6.6606E-20 6.5311 E-20 186 6.4033E-20 6.2769E-20 6.1521E-20 6.0289E-20 5.9073E-20 191 5.7872E-20 5.6688E-20 5.5519E-20 5.4366E-20 5.3229E-20 196 5.2108E-20 5.1003E-20 4.9914E-20 4.8841E-20 4.7784E-20 201 4.6743E-20 4.5717E-20 4.4708E-20 4.3714E-20 4.2736E-20 206 4.1774E-20 4.0828E-20 3.9897E-20 3.8981E-20 3.8081 E-20 211 3.7197E-20 3.6327E-20 3.5473E-20 3.4634E-20 3.381OE-20 f) 216 3.3000E-20 3.2206E-20 3.1426E-20 3.0660E-20 2.9909E-20 221 2.9172E-20 2.8450E-20 2.7741 E-20 2.7046E-20 2.6365E-20 226 2.5697E-20 2.5043E-20 2.4402E-20 2.3775E-20 2.3160E-20 231 2.2558E-20 2.1968E-20 2.1392E-20 2.0827E-20 2.0275E-20 236 1.9734E-20 1.9206E-20 1.8689E-20 1.8184E-20 1.7690E-20 241 1.7207E-20 1.6736E-20 1.6275E-20 1.5825E-20 1.5385E-20 246 1.4956E-20 1.4537E-20 1.4127E-20 1.3728E-20 1.3339E-20 H-3 Concentrations at time =7.500E+02 ,(Deft =1 .OOOE+00)

Node I Concentration (CiIcmA3) at nodes 1,1+1,...,1+4

251 1.2958E-20 1.2588E-20 1.2226E-20 1.1873E-20 1.1530E-20 256 1.1 195E-20 1.0868E-20 1.0550E-20 1.0240E-20 9.9379E-21 261 9.6439E-21 9.3575E-21 9.0787E-21 8.8073E-21 8.5432E-21 266 8.2861 E-21 8.0361 E-21 7.7928E-21 7.5562E-21 7.3261 E-21 271 7.1024E-21 6.8849E-21 6.6735E-21 6.4680E-21 6.2684E-21 276 6.0745E-21 5.8861E-21 5.7031E-21 5.5254E-21 5.3529E-21 281 5.1854E-21 5.0228E-21 4.8651E-21 4.7120E-21 4.5634E-21 286 4.4193E-21 4.2795E-21 4.1440E-21 4.0125E-21 3.8851E-21 291 3.7616E-21 3.6418E-21 3.5257E-21 3.4133E-21 3.3043E-21 296 3.1987E-21 3.0964E-21 2.9973E-21 2.9014E-21 2.8085E-21 301 2.7185E-21 2.6314E-21 2.5471 E-21 2.4654E-21 2.3864E-21 306 2.3100E-21 2.2360E-21 2.1643E-21 2.0951E-21 2.0280E-21 311 1.9632E-21 1.9004E-21 1.8397E-21 1.7810E-21 1.7242E-21 316 1.6693E-21 1.6162E-21 1.5648E-21 1.5151E-21 1.4671E-21 321 1.4206E-21 1.3756E-21 1.3322E-21 1.2901 E-21 1.2494E-21 326 1.2101E-21 1.1721E-21 1.1353E-21 1.0997E-21 1.0652E-21 331 1.0319E-21 9.9970E-22 9.6850E-22 9.3831 E-22 9.0909E-22 336 8.8080E-22 8.5342E-22 8.2690E-22 8.0121 E-22 7.7633E-22 341 7.5223E-22 7.2887E-22 7.0623E-22 6.8428E-22 6.6300E-22 346 6.4235E-22 6.2232E-22 6.0287E-22 5.8400E-22 5.6567E-22 351 5.4786E-22 5.3055E-22 5.1372E-22 4.9736E-22 4.8144E-22 356 4.6594E-22 4.5086E-22 4.3616E-22 4.2183E-22 4.0786E-22 361 3.9423E-22 3.8093E-22 3.6795E-22 3.5526E-22 3.4285E-22 366 3.3072E-22 3.1884E-22 3.0722E-22 2.9583E-22 2.8466E-22 371 2.7370E-22 2.6295E-22 2.5239E-22 2.4201 E-22 2.3180E-22 376 2.2175E-22 2.1186E-22 2.0212E-22 1.9250E-22 1.8302E-22 381 1.7366E-22 1.6440E-22 1.5526E-22 1.4620E-22 1.3724E-22 386 1.2836E-22 1.1955E-22 1.1082E-22 1.0214E-22 9.3519E-23 391 8.4946E-23 7.6414E-23 6.7918E-23 5.9451E-23 5.1007E-23 396 4.2580E-23 4.2487E-23 4.2441 E-23 4.2395E-23 4.2349E-23 401 4.2303E-23 4.2257E-23 4.2211 E-23 4.2165E-23 4.2119E-23 406 4.1602E-23 4.1063E-23 4.0533E-23 4.0009E-23 3.9493E-23 411 3.8983E-23 3.8480E-23 3.7983E-23 3.7492E-23 3.7007E-23 416 3.6528E-23 3.6559E-23 3.5616E-23 3.4693E-23 3.3788E-23 421 3.2902E-23 3.2031 E-23 3.1177E-23 3.0336E-23 2.9510E-23 426 2.8696E-23 2.7895E-23 2.7105E-23 2.6326E-23 2.5558E-23 431 2.4799E-23 2.4050E-23 2.3311 E-23 2.2579E-23 2.1857E-23 436 2.1142E-23 2.0435E-23 1.9736E-23 1.9044E-23 1.8359E-23 441 1.7681 E-23 1.7009E-23 1.6343E-23 1.5684E-23 1.5030E-23 446 1.4383E-23 1.3740E-23 1.3103E-23 1.2472E-23 1.1845E-23 451 1.1222E-23 1.0605E-23 9.9911E-24 9.3816E-24 8.7761E-24 456 8.1742E-24 7.5757E-24 6.9804E-24 6.3881E-24 5.7985E-24 461 5.2115E-24 4.6267E-24 4.0439E-24 3.4629E-24 2.8834E-24 466 2.3052E-24 1.7280E-24 1.1516E-24 5.7564E-25 1.4390E-25 C-14 Concentrations at time =7.500E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.08E+04 Mass sorbed = O.OOE+00 Total Mass = 2.08E+04 1 8.5776E-15 3.4574E-14 7.2066E-14 .1.1541E-13 1.6803E-13 6 2.3393E-13 3.1798E-13 4.2619E-13 5.6605E-13 7.4693E-13 11 9.8061 E-1 3 1.2818E-12 1.6690E-12 2.1650E-12 2.7986E-12 16 3.6051 E-12 4.6281 E-1 2 5.9213E-12 7.5507E-12 9.5964E-12 21 1.2156E-1 I 1.5349E-1 1 1.9317E-11 2.4232E-1 1 3.0301 E-1 1 26 3.7770E-1 1 4.6931 E-1 I 5.8133E-1 1 7.1785E-1 1 8.8372E-1 1 31 1.0846E-10 1.3271 E-10 1.6190E-10 1.9693E-10 2.3883E-10 36 2.8880E-10 3.4823E-10 4.1870E-10 5.0201 E-10 6.0022E-10 41 6.5595E-10 7.1617E-10 7.8136E-10 8.5188E-10 9.2814E-10 46 1.0105E-09 1.0995E-09 1.1954E-09 1.2989E-09 1.A104E-09 51 1.4199E-09 1.4296E-09 1.4394E-09 1.4493E-09 1.4592E-09 56 1.4692E-09 1.4792E-09 1.5108E-09 7.6404E-04 4.3296E-02 61 7.4430E-01 7.8663E-01 8.0888E-01 8.1125E-01 8.3035E-01 66 8.3574E-01 9.0877E-01 9.0987E-01 8.5529E-01 8.3345E-01 71 5.1441 E-01 4.8703E-01 3.3786E-01 3.2660E-01 2.8286E-01 76 2.8081 E-01 2.8923E-01 2.8692E-01 2.3892E-01 2.3321 E-01 81 1.8365E-01 1.7876E-01 1.4463E-01 1.4199E-01 1.3095E-01 86 1.2911E-01 1.0864E-01 1.0621 E-01 8.5145E-02 8.3168E-02 91 7.0379E-02 6.8662E-02 5.2049E-02 5.0420E-02 3.9144E-02 96 3.8398E-02 3.6890E-02 3.6490E-02 3.1149E-02 3.0403E-02 101 2.2978E-02 2.1920E-02 1.1254E-02 1.0612E-02 1.0296E-02 106 1.0209E-02 9.0230E-03 8.8842E-03 7.6949E-03 7.5041 E-03 111 5.4277E-03 5.2023E-03 3.4228E-03 3.3013E-03 3.0014E-03 116 2.9493E-03 2.3570E-03 2.3223E-03 2.3187E-03 2.2320E-03 121 7.5311 E-04 6.8723E-04 1.0393E-03 1.0444E-03 7.7915E-04 126 7.7741 E-04 1.0128E-03 9.9542E-04 4.6299E-04 4.2486E-04 131 3.0568E-04 3.0393E-04 3.9256E-04 3.9776E-04 3.9796E-04 136 3.9970E-04 4.2923E-04 4.2923E-04 4.0001 E-04 4.0867E-04 141 5.8591 E-04 5.8937E-04 4.7135E-04 4.6442E-04 4.6412E-04 146 4.6079E-04 4.0864E-04 6.4426E-04 4.7209E-03 4.7278E-03 151 7.6952E-04 5.3391E-04 4.6813E-04 4.7146E-04 5.8953E-04 156 5.9126E-04 5.0272E-04 4.9752E-04 4.9737E-04 4.9737E-04 161 4.9752E-04 5.0272E-04 5.9116E-04 5.8595E-04 4.0826E-04 166 3.8585E-04 1.8475E-04 3.8918E-04 4.0818E-03 4.0956E-03 171 6.4004E-04 4.4427E-04 5.5644E-04 5.5633E-04 4.3836E-04 176 4.3662E-04 5.2486E-04 5.1966E-04 3.4232E-04 3.3192E-04 181 3.3162E-04 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 186 3.3161 E-04 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 191 3.3161 E-04 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161E-04 196 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 201 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 206 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 211 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04

216 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 3.3161E-04 221 3.3161 E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 3.3161E-04 226 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 231 3.3161E-04 3.3161E-04 3.3161E-04 3.3161E-04 3.3161 E-04 236 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 241 3.3161E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 246 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 C-14 Concentrations at time =7.500E+02 ,(Delt =1.000E+OO)

Node I Concentration (Ci/cm^3) at nodes 1,1+1,...,1+4 251 3.3161 E-04 3.3161 E-04 3.3161 E 04 3.3161 E-04 3.3161 E-04 256 3.3161 E-04 3.3161 E-04 3.3161 E 04 3.3161 E-04 3.3161 E-04 261 3.3161 E-04 3.3161 E-04 3.3161 E044 3.3161 E-04 3.3161 E-04 266 3.3161 E-04 3.3161 E^04 3.3161 E-04 3.3161 E-04 3.3161 E-04 271 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 276 3.3161 E-04 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161 E-04 281 3.3161E404 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161E-04 286 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 3.3161E-04 291 3.3161E-04 3.3161E-04 3.3161E-04 3.3161E-04 3.3161E-04 296 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161E-04 301 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 306 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 311 3.3161E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 316 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 321 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 326 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 331 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 336 3.3161 E-04 3.3161 E044 3.3161 E-04 3.3161 E-04 3.3161 E-04 341 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 346 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 351 3.3161 E-04 3.3161 E-04 3.3161 E 04 3.3161 E-04 3.3161 E-04 356 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E-04 361 3.3161 E-04 3.3161 E-04 3.3161 E-04 3.3161 E 04 3.3161 E-04 366 3.3161 E-04 3.3161E-04 3.3161 E-04 3.3161 E404 3.3161 E-04 371 3.3161 E-04 3.3161 E-04 3.3161E-04 3.3161E-04 3.3161 E-04 376 3.3161 E-04 3.3161E-04 3.3161E-04 3.3161 E-04 3.3161 E-04 381 3.3161 E-04 3.3161 E-04 3.3161E-04 3.3161 E-04 3.3161 E-04 386 3.3161E-04 3.3161 E-04 3.3161E-04 3.3161E-04 3.3161E-04 391 3.3161E-04 3.3161E-04 3.3160E-04 3.3108E-04 3.1332E-04 396 8.5989E-07 8.5926E-07 8.5893E-07 8.5860E-07 8.5827E-07 401 8.5792E-07 8.5758E-07 8.5722E-07 8.5686E-07 8.5650E-07 406 8.5192E-07 8.4627E-07 8.3979E-07 8.3248E-07 8.2436E-07 411 B.1544E-07 8.0575E-07 7.9531 E-07 7.8415E-07 7.7230E-07 416 7.5978E-07 7.6062E-07 7.3377E-07 7.0469E-07 6.7369E-07 421 6.41 1 OE-07 6.0729E-07 5.7259E-07 5.3736E-07 5.0195E-07 426 4.6666E-07 4.3181 E-07 3.9768E-07 3.6451 E-07 3.3252E-07

431 3.0190E-07 2.7279E-07 2.4532E-07 2.1955E-07 1.9556E-07 436 1.7336E-07 1.5294E-07 1.3428E-07 1.1734E-07 1.0204E-07 441 8.8315E-08 7.6070E-08 6.5211 E-08 5.5635E-08 4.7239E-08 446 3.9919E-08 3.3572E-08 2.8101E-08 2.3409E-08 1.9409E-08 451 1.6015E-08 1.3153E-08 1.0751E-08 8.7455E-09 7.0806E-09 456 5.7053E-09 4.5750E-09 3.6507E-09 2.8984E-09 2.2888E-09 461 1.7970E-09 1.4014E-09 1.0839E-09 8.2899E-10 6.2365E-10 466 4.5677E-10 3.1880E-10 2.0147E-10 9.7396E-1 1 2.4198E-1 I H-3 Concentrations at time =7.700E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 1.17E-14 Mass sorbed = O.OOE+00 Total Mass = 1.17E-14 I 6.2319E-28 2.4928E-27 4.9858E-27 7.4794E-27 9.9736E-27 6 1.2469E-26 1.4965E-26 1.7463E-26 1.9962E-26 2.2463E-26 11 2.4966E-26 2.7471 E-26 2.9979E-26 3.2488E-26 3.5000E-26 16 3.7514E-26 4.0031 E-26 4.2549E-26 4.5071 E-26 4.7594E-26 21 5.0119E-26 5.2647E-26 5.5176E-26 5.7706E-26 6.0238E-26 26 6.2771 E-26 6.5303E-26 6.7837E-26 7.0369E-26 7.2901 E-26 31 7.5431 E-26 7.7960E-26 8.0485E-26 8.3007E-26 8.5526E-26 36 8.8039E-26 9.0547E-26 9.3048E-26 9.5542E-26 9.8028E-26 41 9.9271 E-26 1.0051 E-25 1.0174E-25 1.0297E-25 1.0420E-25 46 1.0543E-25 1.0665E-25 1.0787E-25 1.0909E-25 1.1030E-25 51 1.1040E-25 1.1050E-25 1.1060E-25 1.1070E-25 1.1080E-25 56 1.1090E-25 1.1 100E-25 1.1 132E-25 7.5464E-20 7.5445E-20 61 7.5423E-20 7.5390E-20 7.5346E-20 7.5290E-20 7.5222E-20 66 7.5143E-20 7.5053E-20 7.4951 E-20 7.4838E-20 7.4713E-20 71 7.4577E-20 7.4431 E-20 7.4273E-20 7.4104E-20 7.3924E-20 76 7.3733E-20 7.3531E-20 7.331 9E-20 7.3096E-20 7.2863E-20 81 7.2619E-20 7.2365E-20 7.2101E-20 7.1827E-20 7.1542E-20 86 7.1248E-20 7.0945E-20 7.0632E-20 7.0309E-20 6.9977E-20 91 6.9637E-20 6.9287E-20 6.8928E-20 6.8561 E-20 6.8185E-20 96 6.7801 E-20 6.7409E-20 6.7009E-20 6.6601E-20 6.6185E-20 101 6.5762E-20 6.5331 E-20 6.4894E-20 6.4449E-20 6.3998E-20 106 6.3540E-20 6.3076E-20 6.2606E-20 6.2129E-20 6.1647E-20 111 6.1159E-20 6.0666E-20 6.0168E-20 5.9664E-20 5.9156E-20 116 5.8643E-20 5.8126E-20 5.7604E-20 5.7079E-20 5.6549E-20 121 5.6016E-20 5.5480E-20 5.4940E-20 5.4397E-20 5.3852E-20 126 5.3303E-20 5.2752E-20 5.2199E-20 5.1644E-20 5.1087E-20 131 5.0529E-20 4.9969E-20 4.9407E-20 4.8844E-20 4.8281E-20 136 4.7717E-20 4.7152E-20 4.6586E-20 4.6021 E-20 4.5455E-20 141 4A890E-20 4.4325E-20 4.3760E-20 4.3196E-20 4.2633E-20 146 4.2070E-20 4.1509E-20 4.0949E-20 4.0391 E-20 3.9834E-20

151 3.9279E-20 3.8726E-20 3.8174E-20 3.7625E-20 3.7079E-20 156 3.6534E-20 3.5992E-20 3.5453E-20 3.4917E-20 3.4383E-20 161 3.3853E-20 3.3326E-20 3.2802E-20 3.2281E-20 3.1764E-20 166 3.1251 E-20 3.0741 E-20 3.0235E-20 2.9733E-20 2.9234E-20 171 2.8740E-20 2.8250E-20 2.7764E-20 2.7282E-20 2.6805E-20 176 2.6332E-20 2.5864E-20 2.5400E-20 2.4941E-20 2.4486E-20 181 2A036E-20 2.3591E-20 2.3151E-20 2.2715E-20 2.2285E-20 186 2.1859E-20 2.1438E-20 2.1023E-20 2.0612E-20 2.0206E-20 191 1.9806E-20 1.9410E-20 1.9020E-20 1.8634E-20 1.8254E-20 196 1.7879E-20 1.7509E-20 1.7145E-20 1.6785E-20 1.6430E-20 201 1.6081 E-20 1.5737E-20 1.5398E-20 1.5064E-20 1.4735E-20 206 1.4411E-20 1.4093E-20 1.3779E-20 1.3471E-20 1.3167E-20 211 1.2869E-20 1.2575E-20 1.2286E-20 1.2003E-20 1.1724E-20 216 1.1450E-20 1.1181E-20 1.0917E-20 1.0657E-20 1.0402E-20 221 1.0152E-20 9.9066E-21 9.6656E-21 9.4293E-21 9.1974E-21 226 8.9700E-21 8.7471E-21 8.5285E-21 8.3142E-21 8.1042E-21 231 7.8985E-21 7.6970E-21 7.4996E-21 7.3063E-21 7.1170E-21 236 6.9317E-21 6.7504E-21 6.5729E-21 6.3993E-21 6.2294E-21 241 6.0633E-21 5.9009E-21 5.7421 E-21 5.5868E-21 5.4351 E-21 246 5.2869E-21 5.1420E-21 5.0005E-21 4.8623E-21 4.7274E-21 H-3 Concentrations at time =7.700E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 4.5956E-21 4.4670E-21 4.3415E-21 4.2190E-21 4.0995E-21 256 3.9829E-21 3.8692E-21 3.7583E-21 3.6502E-21 3.5448E-21 261 3.4421E-21 3.3420E-21 3.2445E-21 3.1495E-21 3.0570E-21 266 2.9668E-21 2.8791 E-21 2.7936E-21 2.7105E-21 2.6295E-21 271 2.5508E-21 2A742E-21 2.3996E-21 2.3271 E-21 2.2566E-21 276 2.1881E-21 2.1214E-21 2.0567E-21 1.9937E-21 1.9325E-21 281 1.8731E-21 1.8153E-21 1.7593E-21 1.7048E-21 1.6519E-21 286 1.6005E-21 1.5507E-21 1.5023E-21 1.4553E-21 1.4098E-21 291 1.3656E-21 1.3227E-21 1.2811E-21 1.2407E-21 1.2016E-21 296 1.1637E-21 1.1269E-21 1.0912E-21 1.0567E-21 1.0232E-21 301 9.9072E-22 9.5927E-22 9.2880E-22 8.9928E-22 8.7068E-22 306 8.4299E-22 8.1616E-22 7.9019E-22 7.6503E-22 7.4068E-22 311 7.1710E-22 6.9427E-22 6.7217E-22 6.5078E-22 6.3008E-22 316 6.1003E-22 5.9064E-22 5.7187E-22 5.5370E-22 5.3612E-22 321 5.1911E-22 5.0264E-22 4.8671E-22 4.7129E-22 4.5637E-22 326 4.4193E-22 4.2796E-22 4.1444E-22 4.0135E-22 3.8869E-22 331 3.7643E-22 3.6457E-22 3.5308E-22 3.4196E-22 3.3119E-22 336 3.2077E-22 3.1067E-22 3.0089E-22 2.9142E-22 2.8225E-22 341 2.7336E-22 2.6474E-22 2.5639E-22 2.4829E-22 2.4044E-22 346 2.3283E-22 2.2544E-22 2.1827E-22 2.1132E-22 2.0456E-22 351 1.9800E-22 1.9163E-22 1.8543E-22 1.7941E-22 1.7356E-22 356 1.6786E-22 1.6232E-22 1.5692E-22 1.5167E-22 1.4654E-22 361 1A155E-22 1.3668E-22 1.3193E-22 1.2729E-22 1.2276E-22

366 1.1834E-22 1.1401 E-22 1.0977E-22 1.0563E-22 1.0157E-22 371 9.7591 E-23 9.3690E-23 8.9862E-23 8.6104E-23 8.2412E-23 376 7.8782E-23 7.5211 E-23 7.1696E-23 6.8233E-23 6.4820E-23 381 6.1453E-23 5.8128E-23 5.4844E-23 5.1598E-23 4.8385E-23 386 4.5205E-23 4.2054E-23 3.8929E-23 3.5827E-23 3.2748E-23 391 2.9686E-23 2.6642E-23 2.3611 E-23 2.0591 E-23 1.7580E-23 396 1.4576E-23 1.4543E-23 1.4527E-23 1.4510E-23 1.4494E-23 401 1.4477E-23 1.4461E-23 1.4445E-23 1.4428E-23 1.4412E-23 406 1.4228E-23 1.4037E-23 1.3848E-23 1.3663E-23 1.3480E-23 411 1.3300E-23 1.3123E-23 1.2948E-23 1.2776E-23 1.2605E-23 416 1.2437E-23 1.2448E-23 1.2118E-23 1.1796E-23 1.1482E-23 421 1.1174E-23 1.0872E-23 1.0577E-23 1.0288E-23 1.0003E-23 426 9.7240E-24 9.4493E-24 9.1791E-24 8.9130E-24 8.6509E-24 431 8.3925E-24 8.1377E-24 7.8862E-24 7.6380E-24 7.3928E-24 436 7.1505E-24 6.9111 E-24 6.6743E-24 6.4401E-24 6.2084E-24 441 5.9790E-24 5.7519E-24 5.5271 E-24 5.3043E-24 5.0835E-24 446 4.8647E-24 4.6478E-24 4.4326E-24 4.2191E-24 4.0073E-24 451 3.7971E-24 3.5884E-24 3.3810E-24 3.1751E-24 2.9704E-24 456 2.7668E-24 2.5645E-24 2.3631 E-24 2.1627E-24 1.9633E-24 461 1.7646E-24 1.5667E-24 1.3694E-24 1.1727E-24 9.7649E-25 466 7.8069E-25 5.8523E-25 3.9001 E-25 1.9496E-25 4.8739E-26 C-14 Concentrations at ime =7.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CiIcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.08E+04 Mass sorbed = O.OOE+00 Total Mass = 2.08E+04 1 1.0654E-14 4.2929E-14 8.9336E-14 1.4271E-13 2.0708E-13 6 2.8718E-13 3.8869E-13 5.1858E-13 6.8550E-13 9.0020E-13 11 1.1761E-12 1.5300E-12 1.9826E-12 2.5598E-12 3.2936E-12 16 4.2234E-12 5.3977E-12 6.8758E-12 8.7302E-12 1.1049E-11 21 1.3939E-1 I 1.7529E-1 1 2.1973E-1 I 2.7459E-1 I 3.4207E-1 1 26 4.2481E-11 5.2596E-11 6.4922E-1 1 7.9894E-1 1 9.8026E-1 1 31 1.1992E-10 1.4626E-10 1.7788E-10 2.1571E-10 2.6084E-10 36 3.1452E-10 3.7819E-10 4.5348E-10 5.4228E-10 6.4671E-10 41 7.0586E-10 7.6969E-10 8.3873E-10 9.1333E-1 0 9.9390E-10 46 1.0808E-09 1.1746E-09 1.2757E-09 1.3846E-09 1.5018E-09 51 1.5117E-09 1.5219E-09 1.5322E-09 1.5426E-09 1.5530E-09 56 1.5635E-09 1.5740E-09 1.6072E-09 8.0207E-04 4.4259E-02 61 7.4148E-01 7.8470E-01 8.0690E-01 8.0931 E-01 8.2832E-01 66 8.3382E-01 9.0646E-01 9.0758E-01 8.5328E-01 8.3097E-01 71 5.1362E-01 4.8566E-01 3.3726E-01 3.2576E-01 2.8224E-01 76 2.8015E-01 2.8852E-01 2.8616E-01 2.3841E-01 2.3258E-01 81 1.8328E-01 1.7829E-01 1.4433E-01 1.4164E-01 1.3065E-01

86 1.2877E-01 1.0840E-01 1.0593E-01 8.4969E-02 8.2950E-02 91 7.0226E-02 6.8473E-02 5.1947E-02 5.0283E-02 3.9066E-02 96 3.8304E-02 3.6802E-02 3.6395E-02 3.1081E-02 3.0319E-02 101 2.2932E-02 2.1852E-02 1.1243E-02 1.0587E-02 1.0272E-02 106 1.0183E-02 9.0028E-03 8.8611 E-03 7.6779E-03 7.4831 E-03 111 5.4175E-03 5.1874E-03 3.4171 E-03 3.2931 E-03 2.9945E-03 116 2.9413E-03 2.3522E-03 2.3167E-03 2.3130E-03 2.2244E-03 121 7.5349E-04 6.8622E-04 1.0362E-03 1.0415E-03 7.7767E-04 126 7.7590E-04 1.0099E-03 9.9222E-04 4.6264E-04 4.2371 E-04 131 3.0513E-04 3.0334E-04 3.9148E-04 3.9679E-04 3.9700E-04 136 3.9877E-04 4.2814E-04 4.2815E-04 3.9910E-04 4.0795E-04 141 5.8422E-04 5.8776E-04 4.7038E-04 4.6331 E-04 4.6299E-04 146 4.5960E-04 4.0811 E-04 6.4869E-04 4.7031 E-03 4.7102E-03 151 7.7346E-04 5.3289E-04 4.6711 E-04 4.7050E-04 5.8792E-04 156 5.8969E-04 5.0163E-04 4.9633E-04 4.9617E-04 4.9617E-04 161 4.9633E-04 5.0163E-04 5.8958E-04 5.8427E-04 4.0751 E-04 166 3.8464E-04 1.8494E-04 3.9367E-04 4.0662E-03 4.0803E-03 171 6A357E-04 4.4368E-04 5.5492E-04 5.5480E-04 4.3748E-04 176 4.3571 E-04 5.2344E-04 5.1813E-04 3.4175E-04 3.3113E-04 181 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 186 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 191 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 196 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 201 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 206 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 211 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 216 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 221 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 226 3.3081 E-04 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 231 3.3081 E-04 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 236 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 241 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 246 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 C-14 Concentrations at time =7.700E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 251 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 256 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 3.3081E-04 261 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 266 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 271 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 276 3.3081 E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 281 3.3081 E-04 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 286 3.3081 E-04 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 291 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 296 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081E-04 3.3081 E-04

301 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 306 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 311 3.3081E-04 3.3081 E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 316 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 321 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 326 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 331 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 336 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 341 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 346 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 351 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 356 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 361 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 366 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081E-04 371 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 376 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 381 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 3.3081 E-04 386 3.3081E-04 3.3081E-04 3.3081E-04 3.3081 E-04 3.3081 E-04 391 3.3081 E-04 3.3081 E-04 3.3080E-04 3.3026E-04 3.1211 E-04 396 8.4879E-07 8.4816E-07 8.4784E-07 8.4751 E-07 8.4718E-07 401 8.4684E-07 8.4649E-07 8.4614E-07 8.4578E-07 8.4542E-07 406 8A090E-07 8.3535E-07 8.2900E-07 8.2186E-07 8.1394E-07 411 8.0526E-07 7.9585E-07 7.8571 E-07 7.7488E-07 7.6338E-07 416 7.5124E-07 7.5205E-07 7.2604E-07 6.9786E-07 6.6782E-07 421 6.3623E-07 6.0342E-07 5.6973E-07 5.3549E-07 5.0102E-07 426 4.6662E-07 4.3260E-07 3.9921 E-07 3.6671E-07 3.3529E-07 431 3.0515E-07 2.7643E-07 2.4925E-07 2.2370E-07 1.9984E-07 436 1.7769E-07 1.5726E-07 1.3853E-07 1.2147E-07 1.0601 E-07 441 9.2087E-08 7.9621E-08 6.8522E-08 5.8697E-08 5.0046E-08 446 4.2473E-08 3.5878E-08 3.0167E-08 2.5248E-08 2.1032E-08 451 1.7440E-08 1.4394E-08 1.1826E-08 9.6705E-09 7.8713E-09 456 6.3769E-09 5.1419E-09 4.1261E-09 3.2945E-09 2.6166E-09 461 2.0661 E-09 1.6204E-09 1.2602E-09 9.6899E-10 7.3259E-10 466 5.3892E-10 3.7754E-1 0 2.3927E-10 1.1588E-10 2.8800E-1 1 H-3 Concentrations at time =7.800E+02 .(Delt =1.OOOE+00)

Node I Concentration (Ci/crn^3) at nodes 1,1+1,...,1+4 Mass in solution = 6.77E-15 Mass sorbed = O.OOE+00 Total Mass = 6.77E-15 1 3.6108E-28 1.4443E-27 2.8888E-27 4.3335E-27 5.7786E-27 6 7.2241E-27 8.6703E-27 1.0117E-26 1.1565E-26 1.3013E-26 11 1.4463E-26 1.5913E-26 1.7365E-26 1.8817E-26 2.0271E-26 16 2.1726E-26 2.3182E-26 2.4640E-26 2.6098E-26 2.7557E-26

21 2.9017E-26 3.0479E-26 3.1940E-26 3.3403E-26 3.4865E-26 26 3.6328E-26 3.7791 E-26 3.9253E-26 4.0715E-26 4.2176E-26 31 4.3636E-26 4.5095E-26 4.6552E-26 4.8006E-26 4.9458E-26 36 5.0906E-26 5.2351 E-26 5.3792E-26 5.5229E-26 5.6660E-26 41 5.7376E-26 5.8088E-26 5.8798E-26 5.9507E-26 6.0214E-26 46 6.0920E-26 6.1623E-26 6.2325E-26 6.3025E-26 6.3722E-26 51 6.3779E-26 6.3837E-26 6.3895E-26 6.3953E-26 6.4011 E-26 56 6.4069E-26 6.4127E-26 6.4307E-26 4.3403E-20 4.3392E-20 61 4.3380E-20 4.3361 E-20 4.3335E-20 4.3304E-20 4.3265E-20 66 4.3220E-20 4.3169E-20 4.3111E-20 4.3047E-20 4.2976E-20 71 4.2899E-20 4.2816E-20 4.2726E-20 4.2630E-20 4.2528E-20 76 4.2419E-20 4.2305E-20 4.2184E-20 4.2057E-20 4.1925E-20 81 4.1786E-20 4.1642E-20 4.1492E-20 4.1336E-20 4.1174E-20 86 4.1007E-20 4.0835E-20 4.0657E-20 4.0473E-20 4.0285E-20 91 4.0091 E-20 3.9892E-20 3.9688E-20 3.9479E-20 3.9266E-20 96 3.9047E-20 3.8824E-20 3.8596E-20 3.8364E-20 3.8128E-20 101 3.7887E-20 3.7642E-20 3.7393E-20 3.7140E-20 3.6883E-20 106 3.6623E-20 3.6358E-20 3.6091E-20 3.5819E-20 3.5545E-20 111 3.5267E-20 3.4986E-20 3.4702E-20 3.4416E-20 3.4126E-20 116 3.3834E-20 3.3539E-20 3.3242E-20 3.2942E-20 3.2640E-20 121 3.2337E-20 3.2031 E-20 3.1723E-20 3.1413E-20 3.1102E-20 126 3.0789E-20 3.0475E-20 3.0160E-20 2.9843E-20 2.9525E-20 131 2.9206E-20 2.8886E-20 2.8566E-20 2.8244E-20 2.7922E-20 136 2.7600E-20 2.7277E-20 2.6954E-20 2.6631E-20 2.6308E-20 141 2.5985E-20 2.5662E-20 2.5339E-20 2.5016E-20 2.4694E-20 146 2.4372E-20 2.4051 E-20 2.3731 E-20 2.3411 E-20 2.3092E-20 151 2.2774E-20 2.2457E-20 2.2142E-20 2.1827E-20 2.1514E-20 156 2.1202E-20 2.0891E-20 2.0582E-20 2.0275E-20 1.9969E-20 161 1.9664E-20 1.9362E-20 1.9061 E-20 1.8762E-20 1.8465E-20 166 1.8171E-20 1.7878E-20 1.7587E-20 1.7298E-20 1.7012E-20 171 1.6728E-20 1.6446E-20 1.6167E-20 1.5890E-20 1.5615E-20 176 1.5343E-20 1.5073E-20 1.4806E-20 1.4542E-20 1.4280E-20 181 1.4021 E-20 1.3764E-20 1.3511 E-20 1.3260E-20 1.3011E-20 186 1.2766E-20 1.2523E-20 1.2283E-20 1.2046E-20 1.1812E-20 191 1.1580E-20 1.1352E-20 1.1 126E-20 1.0904E-20 1.0684E-20 196 1.0467E-20 1.0253E-20 1.0042E-20 9.8340E-21 9.6288E-21 201 9.4266E-21 9.2272E-21 9.0308E-21 8.8373E-21 8.6467E-21 206 8.4590E-21 8.2742E-21 8.0923E-21 7.9133E-21 7.7371 E-21 211 7.5638E-21 7.3933E-21 7.2257E-21 7.0608E-21 6.8987E-21 216 6.7395E-21 6.5829E-21 6.4292E-21 6.2781 E-21 6.1297E-21 221 5.9841 E-21 5.8410E-21 5.7007E-21 5.5629E-21 5.4277E-21 226 5.2951 E-21 5.1650E-21 5.0374E-21 4.9123E-21 4.7897E-21 231 4.6695E-21 4.5518E-21 4.4364E-21 4.3233E-21 4.2126E-21 236 4.1042E-21 3.9981 E-21 3.8942E-21 3.7925E-21 3.6929E-21 241 3.5956E-21 3.5003E-21 3.4072E-21 3.3161E-21 3.2271 E-21 246 3.1400E-21 3.0549E-21 2.9718E-21 2.8906E-21 2.8112E-21 H-3 Concentrations at time =7.800E+02 ,(DeH =1.OOOE+00)

Node I Concentration (Ci/CmA3) at nodes 1,1+1,...,1+4 251 2.7337E-21 2.6581 E-21 2.5842E-21 2.5121E-21 2.4417E-21 256 2.3730E-21 2.3060E-21 2.2406E-21 2.1768E-21 2.1146E-21 261 2.0540E-21 1.9949E-21 1.9373E-21 1.8811 E-21 1.8264E-21 266 1.7731E-21 1.7212E-21 1.6706E-21 1.6214E-21 1.5734E-21 271 1.5268E-21 1.4813E-21 1.4371 E-21 1.3941 E-21 1.3523E-21 276 1.3116E-21 1.2720E-21 1.2335E-21 1.1961 E-21 1.1597E-21 281 1.1243E-21 1.09OOE-21 1.0566E-21 1.0241 E-21 9.9262E-22 286 9.6201 E-22 9.3228E-22 9.0341 E-22 8.7539E-22 8.4818E-22 291 8.2178E-22 7.9615E-22 7.7128E-22 7.4716E-22 7.2375E-22 296 7.0105E-22 6.7902E-22 6.5767E-22 6.3696E-22 6.1689E-22 301 5.9742E-22 5.7856E-22 5.6027E-22 5.4255E-22 5.2537E-22 306 5.0873E-22 4.9261 E-22 4.7699E-22 4.6186E-22 4.4721 E-22 311 4.3302E-22 4.1927E-22 4.0596E-22 3.9307E-22 3.8059E-22 316 3.6850E-22 3.5680E-22 3.4548E-22 3.3451 E-22 3.2389E-22 321 3.1362E-22 3.0367E-22 2.9404E-22 2.8472E-22 2.7570E-22 326 2.6697E-22 2.5851 E-22 2.5033E-22 2.4241 E-22 2.3474E-22 331 2.2732E-22 2.2013E-22 2.1317E-22 2.0643E-22 1.9991 E-22 336 1.9359E-22 1.8747E-22 1.8154E-22 1.7580E-22 1.7023E-22 341 1.6484E-22 1.5961 E-22 1.5455E-22 1.4963E-22 1.4487E-22 346 1.4025E-22 1.3577E-22 1.3142E-22 1.2720E-22 1.2311 E-22 351 1.1913E-22 1.1526E-22 1.1151E-22 1.0786E-22 1.0431E-22 356 1.0086E-22 9.7498E-23 9.4229E-23 9.1046E-23 8.7945E-23 361 8A924E-23 8.1977E-23 7.9103E-23 7.6299E-23 7.3560E-23 366 7.0885E-23 6.8271 E-23 6.5714E-23 6.3212E-23 6.0763E-23 371 5.8364E-23 5.6012E-23 5.3706E-23 5.1442E-23 4.9219E-23 376 4.7035E-23 4.4887E-23 4.2774E-23 4.0693E-23 3.8642E-23 381 3.6620E-23 3.4624E-23 3.2654E-23 3.0706E-23 2.8780E-23 386 2.6873E-23 2.4985E-23 2.3113E-23 2.1256E-23 1.9411E-23 391 1.7579E-23 1.5757E-23 1.3943E-23 1.2136E-23 1.0335E-23 396 8.5379E-24 8.5183E-24 8.5084E-24 8.4986E-24 8.4888E-24 401 8.4789E-24 8.4691 E-24 8.4594E-24 8.4496E-24 8.4398E-24 406 8.3298E-24 8.2156E-24 8.1033E-24 7.9928E-24 7.8840E-24 411 7.7768E-24 7.6713E-24 7.5673E-24 7.4647E-24 7.3636E-24 416 7.2639E-24 7.2704E-24 7.0749E-24 6.8843E-24 6.6983E-24 421 6.5166E-24 6.3390E-24 6.1651E-24 5.9948E-24 5.8277E-24 426 5.6637E-24 5.5027E-24 5.3443E-24 5.1886E-24 5.0352E-24 431 4.8842E-24 4.7354E-24 4.5886E-24 4.4437E-24 4.3007E-24 436 4.1595E-24 4.0200E-24 3.8821 E-24 3.7458E-24 3.6109E-24 441 3.4774E-24 3.3453E-24 3.2145E-24 3.0849E-24 2.9565E-24 446 2.8293E-24 2.7032E-24 2.5781 E-24 2.4540E-24 2.3308E-24 451 2.2086E-24 2.0872E-24 1.9667E-24 1.8469E-24 1.7279E-24 456 1.6096E-24 1A919E-24 1.3748E-24 1.2582E-24 1.1422E-24 461 1.0267E-24 9.1152E-25 7.9675E-25 6.8232E-25 5.6816E-25 466 4.5425E-25 3.4052E-25 2.2693E-25 1.1344E-25 2.8360E-26

C-14 Concentrations at time =7.800E+02 ,(Det =1.0OOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.07E+04 Mass sorbed = O.OOE+00 Total Mass = 2.07E+04 1 1.1834E-14 4.7678E-14 9.9140E-14 1.5818E-1 3 2.2917E-13 6 3.1722E-13 4.2847E-1 3 5.7039E-13 7.5227E-1 3 9.8560E-1 3 11 1.2847E-12 1.6673E-12 2.1556E-12 2.7769E-12 3.5649E-12 16 4.5613E-12 5.8169E-12 7.3942E-12 9.3689E-12 1.1833E-11 21 1.4899E-1 1 1.8699E-1 I 2.3396E-1 1 2.9182E-11I 3.6287E-1 1 26 4.4985E-1 I 5.5600E-1 I 6.8513E-1 I 8.4174E-1 I 1.0311 E-10 31 1.2594E-1 0 1.5337E-1 0 1.8625E-10 2.2552E-10 2.7232E-10 36 3.2790E-1 0 3.9375E-1 0 4.7152E-10 5.6313E-10 6.7074E-10 41 7.3163E-10 7.9731 E-10 8.6831 E-1 0 9.4499E-10 1.0278E-09 46 1.1170E-09 1.2133E-09 1.3169E-09 1 A286E-09 1.5487E-09 51 1.5588E-09 1.5693E-09 1.5798E-09 1.5905E-09 1.6011 E-09 56 1.6119E-09 1.6227E-09 1.6566E-09 8.2138E-04 4.4737E-02 61 7.4007E-01 7.8373E-01 8.0591 E-01 8.0835E-01 8.2731 E-01 66 8.3287E-01 9.0531 E-01 9.0644E-01 8.5227E-01 8.2974E-01 71 5.1322E-01 4.8498E-01 3.3696E-01 3.2534E-01 2.8193E-01 76 2.7982E-01 2.8816E-01 2.8578E-01 2.3815E-01 2.3227E-01 81 1.8309E-01 1.7805E-01 1.4418E-01 1.4146E-01 1.3050E-01 86 1.2860E-01 1.0829E-01 1.0578E-01 8.4881 E-02 8.2841E-02 91 7.0150E-02 6.8378E-02 5.1896E-02 5.0214E-02 3.9027E-02 96 3.8257E-02 3.6759E-02 3.6347E-02 3.1047E-02 3.0277E-02 101 2.2909E-02 2.1818E-02 1.1237E-02 1.0575E-02 1.0259E-02 106 1.0170E-02 8.9927E-03 8.8496E-03 7.6694E-03 7.4726E-03 111 5.4124E-03 5.1799E-03 3.4142E-03 3.2890E-03 2.9911 E-03 116 2.9374E-03 2.3497E-03 2.3139E-03 2.3101 E-03 2.2207E-03 121 7.5368E-04 6.8572E-04 1.0347E-03 1.0400E-03 7.7694E-04 126 7.7514E-04 1.0085E-03 9.9062E-04 4.6246E-04 4.2313E-04 131 3.0485E-04 3.0304E-04 3.9094E-04 3.9631 E-04 3.9652E-04 136 3.9831 E-04 4.2760E-04 4.2761 E-04 3.9865E-04 4.0758E-04 141 5.8338E-04 5.8695E-04 4.6990E-04 4.6276E-04 4.6243E-04 146 4.5900E-04 4.0785E-04 6.5088E-04 4.6943E-03 4.7014E-03 151 7.7541 E-04 5.3238E-04 4.6660E-04 4.7002E-04 5.8712E-04 156 5.8891 E-04 5.0109E-04 4.9573E-04 4.9557E-04 4.9557E-04 161 4.9573E-04 5.0109E-04 5.8880E-04 5.8343E-04 4.0714E-04 166 3.8404E-04 1.8504E-04 3.9590E-04 4.0584E-03 4.0727E-03 171 6.4532E-04 4.4339E-04 5.5417E-04 5.5404E-04 4.3704E-04 176 4.3525E-04 5.2274E-04 5.1737E-04 3.4146E-04 3.3074E-04 181 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041E-04 186 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041E-04 191 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 196 3.3041 E-04 3.3041E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 201 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04

206 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 211 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 216 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 221 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 226 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 231 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 3.3041 E-04 236 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 241 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 246 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 C-14 Concentrations at time =7.800E+02 P(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 256 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 261 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 266 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 271 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 276 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 281 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 286 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 291 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 296 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 301 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 306 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 311 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 316 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 321 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 326 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 331 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 336 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 341 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 346 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 351 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 356 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 361 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 366 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 371 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 376 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 381 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 386 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 3.3041E-04 391 3.3041E-04 3.3041E-04 3.3040E-04 3.2984E-04 3.1150E-04 396 8.4340E-07 8.4277E-07 8.4245E-07 8.4212E-07 8.4179E-07 401 8.4145E-07 8.4110E-07 8.4076E-07 8.4040E-07 8.4004E-07 406 8.3555E-07 8.3005E-07 8.2376E-07 8.1670E-07 8.0888E-07 411 8.0031E-07 7.9102E-07 7.8103E-07 7.7035E-07 7.5903E-07 416 7.4707E-07 7.4787E-07 7.2225E-07 6.9451 E-07 6.6492E-07

421 6.3381 E-07 6.0149E-07 5.6829E-07 5.3452E-07 5.0050E-07 426 4.6654E-07 4.3291 E-07 3.9989E-07 3.6771 E-07 3.3658E-07 431 3.0668E-07 2.7816E-07 2.5113E-07 2.2569E-07 2.0190E-07 436 1.7979E-07 1.5936E-07 1.4060E-07 1.2349E-07 1.0796E-07 441 9.3943E-08 8.1374E-08 7.0163E-08 6.0219E-08 5.1448E-08 446 4.3752E-08 3.7037E-08 3.1209E-08 2.6178E-08 2.1858E-08 451 1.8167E-08 1.5031E-08 1.2379E-08 1.0148E-08 8.2812E-09 456 6.7266E-09 5.4383E-09 4.3757E-09 3.5033E-09 2.7901 E-09 461 2.2091E-09 1.7373E-09 1.3547E-09 1.0443E-09 7.9137E-10 466 5.8339E-10 4.0941E-10 2.5981E-10 1.2594E-10 3.1305E-11 H-3 Concentrations at time =8.400E+02 ,(Deft =1.OOOE+O0)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass In solution = 2.54E-16 Mass sorbed = O.OOE+OO Total Mass = 2.54E-16 I 1.3620E-29 5.4482E-29 1.0896E-28 1.6345E-28 2.1794E-28 6 2.7243E-28 3.2693E-28 3.8144E-28 4.3595E-28 4.9046E-28 11 5.4499E-28 5.9952E-28 6.5405E-28 7.0859E-28 7.6313E-28 16 8.1767E-28 8.7221 E-28 9.2674E-28 9.8126E-28 1.0358E-27 21 11.0902E-27 1.1447E-27 1.1991E-27 1.2535E-27 1.3079E-27 26 11.3622E-27 1.4164E-27 1.4705E-27 1.5246E-27 1.5786E-27 31 1.6324E-27 1.6862E-27 1.7398E-27 1.7933E-27 1.8466E-27 36 1.8997E-27 11.9526E-27 2.0053E-27 2.0578E-27 2.1 101 E-27 41 2.1362E-27 2.1621 E-27 2.1880E-27 2.2138E-27 2.2395E-27 46 2.2652E-27 2.2907E-27 2.3162E-27 2.3416E-27 2.3669E-27 51 2.3690E-27 2.3711 E-27 2.3732E-27 2.3753E-27 2.3774E-27 56 2.3795E-27 2.3816E-27 2.3881 E-27 1.5734E-21 1.5730E-21 61 1.5726E-21 1.5720E-21 1.5711E-21 1.5701 E-21 1.5688E-21 66 1.5673E-21 1.5655E-21 1.5636E-21 1.5614E-21 1.5590E-21 71 1.5564E-21 1.5536E-21 11.5506E-21 1.5473E-21 1.5439E-21 76 1.5402E-21 1.5363E-21 1.5323E-21 1.5280E-21 1.5235E-21 81 1.5188E-21 1.5139E-21 1.5088E-21 1.5036E-21 1.4981 E-21 86 1.4924E-21 1.4866E-21 1.4806E-21 1.4743E-21 1.4679E-21 91 1.4614E-21 1.4546E-21 1.4477E-21 1.4406E-21 1.4333E-21 96 1.4259E-21 1.4183E-21 1.4106E-21 1.4027E-21 1.3946E-21 101 1.3864E-21 1.3781E-21 1.3696E-21 1.3610E-21 1.3522E-21 106 1.3433E-21 1.3343E-21 1.3252E-21 1.3159E-21 1.3065E-21 111 1.2970E-21 1.2874E-21 1.2776E-21 1.2678E-21 1.2579E-21 116 1.2479E-21 1.2377E-21 1.2275E-21 1.2172E-21 1.2068E-21 121 1.1964E-21 1.1858E-21 1.1752E-21 1.1645E-21 1.1538E-21 126 1.1430E-21 1.1321E-21 1.1212E-21 1.1103E-21 1.0992E-21 131 1.0882E-21 1.0771 E-21 1.0660E-21 1.0548E-21 1.0436E-21 136 1.0324E-21 1.0211 E-21 1.0099E-21 9.9859E-22 9.8730E-22

141 9.7600E-22 9.6470E-22 9.5340E-22 9.4209E-22 9.3079E-22 146 9.1949E-22 9.0821 E-22 8.9694E-22 8.8569E-22 8.7445E-22 151 8.6324E-22 8.5205E-22 8.4089E-22 8.2976E-22 8.1867E-22 156 8.0761E-22 7.9658E-22 7.8560E-22 7.7467E-22 7.6378E-22 161 7.5293E-22 7.4214E-22 7.3140E-22 7.2072E-22 7.1010E-22 166 6.9953E-22 6.8903E-22 6.7859E-22 6.6821 E-22 6.5790E-22 171 6.4767E-22 6.3750E-22 6.2741 E-22 6.1739E-22 6.0745E-22 176 5.9758E-22 5.8779E-22 5.7809E-22 5.6847E-22 5.5893E-22 181 5.4947E-22 5.4010E-22 5.3082E-22 5.2162E-22 5.1252E-22 186 5.0350E-22 4.9458E-22 4.8574E-22 4.7700E-22 4.6836E-22 191 4.5980E-22 4.5135E-22 4.4298E-22 4.3472E-22 4.2654E-22 196 4.1847E-22 4.1049E-22 4.0261E-22 3.9483E-22 3.8715E-22 201 3.7956E-22 3.7208E-22 3.6469E-22 3.5740E-22 3.5021 E-22 206 3.4312E-22 3.3612E-22 3.2923E-22 3.2243E-22 3.1573E-22 211 3.0913E-22 3.0263E-22 2.9622E-22 2.8991 E-22 2.8370E-22 216 2.7759E-22 2.7157E-22 2.6565E-22 2.5982E-22 2.5408E-22 221 2.4844E-22 2.4290E-22 2.3745E-22 2.3208E-22 2.2682E-22 226 2.2164E-22 2.1655E-22 2.1155E-22 2.0664E-22 2.0182E-22 231 1.9709E-22 1.9244E-22 1.8788E-22 1.8340E-22 1.7901E-22 236 1.7470E-22 1.7047E-22 1.6633E-22 1.6226E-22 1.5828E-22 241 1.5437E-22 1.5054E-22 1.4679E-22 1.4312E-22 1.3952E-22 246 1.3599E-22 1.3254E-22 1.2916E-22 1.2585E-22 1.2261 E-22 H-3 Concentrations at time =8.400E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 1.1944E-22 1.1634E-22 1.1330E-22 1.1034E-22 1.0743E-22 256 1.0460E-22 1.0182E-22 9.911 OE-23 9.6459E-23 9.3869E-23 261 9.1338E-23 8.8866E-23 8.6451E-23 8.4093E-23 8.1790E-23 266 7.9542E-23 7.7347E-23 7.5206E-23 7.3116E-23 7.1076E-23 271 6.9087E-23 6.7147E-23 6.5254E-23 6.3409E-23 6.1610E-23 276 5.9856E-23 5.8147E-23 5.6481E-23 5.4858E-23 5.3277E-23 281 5.1 736E-23 5.0236E-23 4.8775E-23 4.7352E-23 4.5967E-23 286 4.4619E-23 4.3306E-23 4.2029E-23 4.0786E-23 3.9577E-23 291 3.8401E-23 3.7257E-23 3.6145E-23 3.5063E-23 3.4011 E-23 296 3.2988E-23 3.1994E-23 3.1028E-23 3.0089E-23 2.9177E-23 301 2.8291 E-23 2.7429E-23 2.6593E-23 2.5781E-23 2.4991 E-23 306 2.4225E-23 2.3481 E-23 2.2759E-23 2.2058E-23 2.1377E-23 311 2.0717E-23 2.0076E-23 1.9454E-23 1.8850E-23 1.8264E-23 316 1.7696E-23 1.7145E-23 1.661 OE-23 1.6091 E-23 1.5588E-23 321 1.5100E-23 1.4627E-23 1.4168E-23 1.3723E-23 1.3292E-23 326 1.2873E-23 1.2468E-23 1.2074E-23 1.1693E-23 1.1323E-23 331 1.0964E-23 1.0617E-23 1.0280E-23 9.9528E-24 9.6358E-24 336 9.3285E-24 9.0306E-24 8.7416E-24 8.4613E-24 8.1896E-24 341 7.9259E-24 7.6702E-24 7.4222E-24 7.1815E-24 6.9480E-24 346 6.7214E-24 6.5015E-24 6.2880E-24 6.0807E-24 5.8795E-24 351 5.6840E-24 5.4942E-24 5.3097E-24 5.1304E-24 4.9562E-24

356 4.7868E-24 4.6220E-24 4.4617E-24 4.3057E-24 4.1538E-24 361 4.0060E-24 3.8619E-24 3.7216E-24 3.5847E-24 3.4513E-24 366 3.321OE-24 3.1939E-24 3.0698E-24 2.9485E-24 2.8299E-24 371 2.7140E-24 2.6005E-24 2.4893E-24 2.3804E-24 2.2737E-24 376 2.1689E-24 2.0661 E-24 1.9651 E-24 1.8659E-24 1.7682E-24 381 1.6720E-24 1.5773E-24 1.4839E-24 1.3918E-24 1.3007E-24 386 1.2108E-24 1.1218E-24 1.0337E-24 9.4638E-25 8.5979E-25 391 7.7383E-25 6.8842E-25 6.0348E-25 5.1893E-25 4.3468E-25 396 3.5066E-25 3.4974E-25 3.4928E-25 3.4882E-25 3.4836E-25 401 3.4791 E-25 3.4745E-25 3.4699E-25 3.4654E-25 3.4608E-25 406 3.4096E-25 3.3567E-25 3.3048E-25 3.2540E-25 3.2041 E-25 411 3.1552E-25 3.1072E-25 3.0602E-25 3.0139E-25 2.9685E-25 416 2.9239E-25 2.9268E-25 2.8398E-25 2.7557E-25 2.6742E-25 421 2.5953E-25 2.5187E-25 2.4442E-25 2.3718E-25 2.3012E-25 426 2.2325E-25 2.1653E-25 2.0997E-25 2.0356E-25 1.9728E-25 431 1.9113E-25 1.8509E-25 1.7916E-25 1.7334E-25 1.6762E-25 436 1.6199E-25 1.5645E-25 1.5098E-25 1.4560E-25 1.4028E-25 441 1.3504E-25 1.2985E-25 1.2473E-25 1.1967E-25 1.1466E-25 446 1.0970E-25 1.0479E-25 9.9927E-26 9.5106E-26 9.0325E-26 451 8.5583E-26 8.0876E-26 7.6203E-26 7.1561 E-26 6.6949E-26 456 6.2364E-26 5.7805E-26 5.3269E-26 4.8755E-26 4.4261 E-26 461 3.9784E-26 3.5324E-26 3.0877E-26 2.6443E-26 2.2020E-26 466 1.7605E-26 1.3198E-26 8.7956E-27 4.3969E-27 1.0992E-27 C-14 Concentrations at time =8.400E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmr3) at nodes 1,1+1,...,1+4 Mass in solution = 2.06E+04 Mass sorbed = O.OOE+00 Total Mass = 2.06E+04 I 2.1308E-14 8.5780E-14 1.7763E-13 2.8157E-13 4.0449E-13 6 5.5430E-13 7.4031 E-13 9.7376E-13 1.2683E-12 1.6406E-12 11 2.1111E-12 2.7049E-12 3.4527E-12 4.3921 E-1 2 5.5690E-12 16 7.0390E-12 8.8698E-12 1.1143E-11 1.3957E-11 1.7430E-11 21 2.1704E-11 2.6947E-11 3.3360E-11 4.1181E-11 5.0692E-11 26 6.2222E-11 7.6162E-11 9.2967E-11 1.1317E-10 1.3738E-10 31 1.6632E-10 2.0082E-10 2.4183E-10 2.9045E-10 3A793E-10 36 4.1571E-10 4.9543E-10 5.8893E-10 6.9833E-10 8.2600E-10 41 8.9788E-10 9.7518E-10 1.0585E-09 1.1482E-09 1.2447E-09 46 1.3485E-09 1A601E-09 1.5799E-09 1.7086E-09 1.8467E-09 51 1.8584E-09 1.8704E-09 1.8825E-09 1.8947E-09 1.9069E-09 56 1.9192E-09 1.9316E-09 1.9705E-09 9.4112E-04 4.7558E-02 61 7.3171E-01 7.7796E-01 7.9999E-01 8.0258E-01 8.2126E-01 66 8.2716E-01 8.9843E-01 8.9963E-01 8.4625E-01 8.2238E-01 71 5.1084E-01 4.8093E-01 3.3515E-01 3.2284E-01 2.8009E-01

76 2.7784E-01 2.8603E-01 2.8350E-01 2.3662E-01 2.3039E-01 81 1.8197E-01 1.7663E-01 1.4328E-01 1.4040E-01 1.2960E-01 86 1.2759E-01 1.0759E-01 1.0493E-01 8.4354E-02 8.2193E-02 91 6.9693E-02 6.7816E-02 5.1589E-02 4.9808E-02 3.8793E-02 96 3.7977E-02 3.6498E-02 3.6061 E-02 3.0843E-02 3.0028E-02 101 2.2773E-02 2.1617E-02 1.1201E-02 1.05OOE-02 1.0186E-02 106 1.0091E-02 8.9325E-03 8.7808E-03 7.6185E-03 7.4099E-03 ill 5.3817E-03 5.1353E-03 3.3971 E-03 3.2644E-03 2.9706E-03 116 2.9136E-03 2.3353E-03 2.2973E-03 2.2930E'03 2.1982E-03 121 7.5470E-04 6.8270E-04 1.0256E-03 1.0313E-03 7.7253E-04 126 7.7063E-04 1.0001 E-03 9.8109E-04 4.6138E-04 4,1971 E-04 131 3.0319E-04 3.0127E-04 3.8773E-04 3.9341E04D 3.9366E044 136 3.9556E-04 4.2438E-04 4.2438E-04 3.9594E-04 4.0541 E-04 141 5.7836E-04 5.8215E-04 4.6701 E-04 4.5944E-04 4.5907E-04 146 4.5547E-04 4.0630E-04 6.6376E-04 4.6416E-03 4.6492E-03 151 7.8685E-04 5.2940E-04 4.6355E-04 4.6715E-04 5.8234E-04 156 5.8423E-04 4.9785E-04 4.9217E-04 4.9199E-04 4.9199E-04 161 4.9217E-04 4.9785E-04 5.841 1E-04 5.7842E-04 4.0490E-04 166 3.8045E-04 1.8564E-04 4.0901 E-04 4.0121 E-03 4.0273E-03 171 6.5558E-04 4.4167E-04 5.4965E-04 5.4949E-04 4.3441 E-04 176 4.3252E-04 5.1853E-04 5.1284E-04 3.3976E-04 3.2840E-04 181 3.2803E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 186 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 191 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 196 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 201 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 206 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 211 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 216 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E044 221 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 226 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E04D 3.2802E-04 231 3.2802E-04 3.2802E04D 3.2802E-04 3.2802E04D 3.2802E-04 236 3.2802E-04 3.2802E04D 3.2802E-04 3.2802E-04 3.2802E-04 241 3.2802E-04 3.2802E04D 3.2802E-04 3.2802E04D 3.2802E-04 246 3.2802E04D 3.2802E04D 3.2802E-04 3.2802E-04 3.2802E-04 C-14 Concentrations at time =8.400E+02 ,(Delt =1.000E+00)

Node I Concentration (CitCMA3) at nodes 1,1+1,...,1+4 251 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 256 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 261 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 266 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 271 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 276 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 281 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 286 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04

291 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 296 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 301 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 306 3.2802E-04 3.2802E-04. 3.2802E-04 3.2802E-04 3.2802E-04 311 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 316 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 321 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 326 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 331 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 336 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 341 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 346 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 351 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 356 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 361 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 366 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 371 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 376 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 381 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 386 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 3.2802E-04 391 3.2802E-04 3.2802E-04 3.2800E-04 3.2737E-04 3.0789E-04 396 8.1306E-07 8.1243E-07 8.1212E-07 8.1179E-07 8.1147E-07 401 8.1114E-07 8.1080E-07 8.1046E-07 8.1011E-07 8.0976E-07 406 8.0543E-07 8.0018E-07 7.9424E-07 7.8761 E-07 7.8032E-07 411 7.7237E-07 7.6377E-07 7.5455E-07 7.4473E-07 7.3432E-07 416 7.2335E-07 7.2409E-07 7.0061E-07 6.7521E-07 6.4813E-07 421 6.1962E-07 5.8996E-07 5.5942E-07 5.2827E-07 4.9679E-07 426 4.6524E-07 4.3388E-07 4.0294E-07 3.7263E-07 3.4314E-07 431 3.1466E-07 2.8731E-07 2.6123E-07 2.3651E-07 2.1322E-07 436 1.9140E-07 1.7109E-07 1.5227E-07 1.3495E-07 1.1909E-07 441 1.0465E-07 9.1561E-08 7.9769E-08 6.9200E-08 5.9775E-08 446 5.1414E-08 4.4034E-08 3.7552E-08 3.1888E-08 2.6963E-08 451 2.2702E-08 1.9033E-08 1.5888E-08 1.3206E-08 11.0930E-08 456 9.0066E-09 7.3887E-09 6.0337E-09 4.9035E-09 3.9643E-09 461 3.1862E-09 2.5430E-09 2.0116E-09 1.5720E-09 1.2064E-09 466 8.9940E-10 6.3712E-10 4.0720E-10 1.9828E-10 4.9328E-11 H-3 Concentrations at time =8.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 4.93E-17 Mass sorbed = O.OOE+00 Total Mass = 4.93E-17 1 2.6409E-30 1.0563E-29 2.1127E-29 3.1690E-29 4.2253E-29 6 5.2816E-29 6.3379E-29 7.3941E-29 8A503E-29 9.5063E-29

11 1.0562E-28 1.1618E-28 1.2674E-28 1.3729E-28 1.4784E-28 16 1.5839E-28 1.6893E-28 1.7947E-28 1.9OOOE-28 2.0052E-28 21 2.1104E-28 2.2154E-28 2.3204E-28 2.4252E-28 2.5299E-28 26 2.6344E-28 2.7388E-28 2.8430E-28 2.9469E-28 3.0506E-28 31 3.1541E-28 3.2572E-28 3.3601 E-28 3.4626E-28 3.5648E-28 36 3.6665E-28 3.7679E-28 3.8687E-28 3.9691 E-28 4.0690E-28 41 4.1188E-28 4.1684E-28 4.2178E-28 4.2671 E-28 4.3162E-28 46 4.3651 E-28 4.4139E-28 4.4625E-28 4.5109E-28 4.5592E-28 51 4.5631 E-28 4.5671 E-28 4.5711 E-28 4.5751 E-28 4.5791 E-28 56 4.5831 E-28 4.5871 E-28 4.5996E-28 2.9985E-22 2.9978E-22 61 2.9971 E-22 2.9959E-22 2.9943E-22 2.9923E-22 2.9900E-22 66 2.9872E-22 2.9840E-22 2.9804E-22 2.9764E-22 2.9720E-22 71 2.9672E-22 2.9620E-22 2.9564E-22 2.9504E-22 2.9441 E-22 76 2.9373E-22 2.9302E-22 2.9227E-22 2.9148E-22 2.9065E-22 81 2.8979E-22 2.8888E-22 2.8795E-22 2.8697E-22 2.8597E-22 86 2.8492E-22 2.8384E-22 2.8273E-22 2.8158E-22 2.8040E-22 91 2.7919E-22 2.7794E-22 2.7666E-22 2.7535E-22 2.7401 E-22 96 2.7264E-22 2.7124E-22 2.6981 E-22 2.6835E-22 2.6686E-22 101 2.6534E-22 2.6380E-22 2.6223E-22 2.6063E-22 2.5901 E-22 106 2.5736E-22 2.5569E-22 2.5400E-22 2.5228E-22 2.5054E-22 111 2.4877E-22 2.4699E-22 2A519E-22 2.4336E-22 2.4152E-22 116 2.3966E-22 2.3778E-22 2.3588E-22 2.3397E-22 2.3204E-22 121 2.301 OE-22 2.2814E-22 2.2616E-22 2.2418E-22 2.2218E-22 126 2.2017E-22 2.1814E-22 2.1611 E-22 2.1407E-22 2.1201 E-22 131 2.0995E-22 2.0788E-22 2.0580E-22 2.0372E-22 2.0163E-22 136 1.9953E-22 1.9743E-22 1.9533E-22 1.9322E-22 1.9111E-22 141 1.8899E-22 1.8688E-22 1.8476E-22 1.8264E-22 1.8052E-22 146 1.7840E-22 1.7629E-22 1.7417E-22 1.7206E-22 1.6995E-22 151 1.6784E-22 1.6574E-22 1.6364E-22 1.6155E-22 1.5946E-22 156 1.5737E-22 1.5530E-22 1.5323E-22 1.5117E-22 1.4911 E-22 161 1.4706E-22 1.4503E-22 1.4300E-22 1.4098E-22 1.3897E-22 166 1.3697E-22 1.3498E-22 1.3300E-22 1.3103E-22 1.2908E-22 171 1.2714E-22 1.2521 E-22 1.2329E-22 1.2139E-22 1.1950E-22 176 1.1762E-22 1.1576E-22 1.1391E-22 1.1207E-22 1.1026E-22 181 1.0845E-22 1.0666E-22 1.0489E-22 1.0313E-22 1.0139E-22 186 9.9667E-23 9.7958E-23 9.6266E-23 9A590E-23 9.2932E-23 191 9.1290E-23 8.9666E-23 8.8059E-23 8.6469E-23 8.4897E-23 196 8.3342E-23 8.1805E-23 8.0286E-23 7.8785E-23 7.7302E-23 201 7.5837E-23 7.4390E-23 7.2961 E-23 7.1550E-23 7.0157E-23 206 6.8782E-23 6.7426E-23 6.6087E-23 6.4767E-23 6.3465E-23 211 6.2181E-23 6.0916E-23 5.9668E-23 5.8438E-23 5.7227E-23 216 5.6033E-23 5.4857E-23 5.3699E-23 5.2559E-23 5.1436E-23 221 5.0331 E-23 4.9244E-23 4.8173E-23 4.7120E-23 4.6085E-23 226 4.5066E-23 4.4065E-23 4.3080E-23 4.2112E-23 4.1161 E-23 231 4.0226E-23 3.9307E-23 3.8405E-23 3.7519E-23 3.6648E-23 236 3.5794E-23 3.4955E-23 3.4132E-23 3.3324E-23 3.2531 E-23 241 3.1753E-23 3.0990E-23 3.0242E-23 2.9508E-23 2.8789E-23 246 2.8084E-23 2.7393E-23 2.6715E-23 2.6052E-23 2.5402E-23

H-3 Concentrations at time =8.700E+02 (Deft =1 .OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 2.4765E-23 2.4142E-23 2.3531 E-23 2.2933E-23 2.2348E-23 256 2.1776E-23 2.1215E-23 2.0667E-23 2.0131 E-23 1.9606E-23 261 1.9093E-23 1.8592E-23 1.8101E-23 1.7622E-23 1.7153E-23 266 1.6695E-23 1.6248E-23 1.5811E-23 1.5384E-23 1.4967E-23 271 1.4560E-23 1.4163E-23 1.3775E-23 1.3396E-23 1.3026E-23 276 1.2666E-23 1.2314E-23 1.1971 E-23 1.1 636E-23 1.1 309E-23 281 1.0991 E-23 1.0681 E-23 1.0378E-23 1.0083E-23 9.7957E-24 286 9.5157E-24 9.2428E-24 8.9770E-24 8.7181E-24 8.4660E-24 291 8.2204E-24 7.9814E-24 7.7487E-24 7.5221E-24 7.3016E-24 296 7.0870E-24 6.8783E-24 6.6751 E-24 6.4775E-24 6.2853E-24 301 6.0983E-24 5.9165E-24 5.7398E-24 5.5679E-24 5.4008E-24 306 5.2384E-24 5.0806E-24 4.9271 E-24 4.7781 E-24 4.6332E-24 311 4.4925E-24 4.3558E-24 4.2230E-24 4.0940E-24 3.9687E-24 316 3.8471 E-24 3.7289E-24 3.6142E-24 3.5029E-24 3.3947E-24 321 3.2898E-24 3.1879E-24 3.0890E-24 2.9930E-24 2.8998E-24 326 2.8094E-24 2.7217E-24 2.6365E-24 2.5539E-24 2.4737E-24 331 2.3959E-24 2.3204E-24 2.2471 E-24 2.1760E-24 2.1070E-24 336 2.0401 E-24 1.9751 E-24 1.9121E-24 1.8509E-24 1.7915E-24 341 1.7339E-24 1.6780E-24 1.6237E-24 1.571 OE-24 1.5198E-24 346 1.4702E-24 1.4219E-24 1.3751E-24 1.3296E-24 1.2854E-24 351 1.2425E-24 1.2008E-24 1.1602E-24 1.1208E-24 1.0825E-24 356 1.0452E-24 1.0090E-24 9.7371 E-25 9.3939E-25 9.0597E-25 361 8.7343E-25 8.4172E-25 8.1083E-25 7.8072E-25 7.5135E-25 366 7.2270E-25 6.9473E-25 6.6743E-25 6A075E-25 6.1468E-25 371 5.8919E-25 5.6425E-25 5.3983E-25 5.1591 E-25 4.9248E-25 376 4.6949E-25 4.4693E-25 4.2478E-25 4.0301E-25 3.8161 E-25 381 3.6054E-25 3.3980E-25 3.1935E-25 2.9919E-25 2.7928E-25 386 2.5961E-25 2.4015E-25 2.2090E-25 2.0183E-25 1.8292E-25 391 1.6415E-25 1.4551E-25 1.2698E-25 1.0853E-25 9.0153E-26 396 7.1828E-26 7.1628E-26 7.1528E-26 7.1427E-26 7.1327E-26 401 7.1227E-26 7.1128E-26 7.1028E-26 7.0929E-26 7.0830E-26 406 6.9715E-26 6.8565E-26 6.7439E-26 6.6337E-26 6.5258E-26 411 6.4201 E-26 6.3166E-26 6.2151 E-26 6.1157E-26 6.0182E-26 416 5.9226E-26 5.9289E-26 5.7428E-26 5.5636E-26 5.3907E-26 421 5.2236E-26 5.0621 E-26 4.9057E-26 4.7540E-26 4.6069E-26 426 4.4639E-26 4.3247E-26 4.1892E-26 4.0572E-26 3.9282E-26 431 3.8023E-26 3.6791 E-26 3.5585E-26 3.4403E-26 3.3244E-26 436 3.2107E-26 3.0989E-26 2.9890E-26 2.8809E-26 2.7744E-26 441 2.6694E-26 2.5659E-26 2.4638E-26 2.3630E-26 2.2633E-26 446 2.1648E-26 2.0674E-26 1.9710E-26 1.8755E-26 1.7808E-26 451 1.6870E-26 1.5940E-26 1.5017E-26 1.4100E-26 1.3190E-26 456 1.2285E-26 1.1386E-26 1.0492E-26 9.6022E-27 8.7165E-27 461 7.8345E-27 6.9558E-27 6.0800E-27 5.2067E-27 4.3357E-27 466 3.4664E-27 2.5985E-27 1.7317E-27 8.6569E-28 2.1641 E-28

C-14 Concentrations at time =8.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.05E+04 Mass sorbed = O.OOE+00 Total Mass = 2.05E+04 I 2.7904E-14 1.1230E-13 2.3211 E-1 3 3.6690E-1 3 5.2512E-13 6 7.1641E-13 9.5209E-13 1.2457E-12 1.6134E-12 2.0750E-12 11 2.6547E-12 3.3818E-12 4.2920E-112 5.4287E-12 6.8447E-12 16 8.6038E-12 1.0783E-11 1.3474E-11 1.6789E-1 1 2.0859E-11 21 2.5843E-1 1 3.1928E-1 1 3.9337E-1 1 4.8330E-1 1 5.9218E-1 1 26 7.2360E-1 I 8.8181 E-11 1.0717E-10 1.2991 E-10 1.5706E-10 31 1.8938E-10 2.2777E-10 2.7324E-10 3.2694E-10 3.9022E-10 36 4.6459E-10 5.5176E-10 6.5369E-10 7.7257E-10 9.1089E-10 41 9.8860E-10 1.0720E-09 1.1618E-09 1.2584E-09 1.3621 E-09 46 1.4736E-09 1.5932E-09 1.7215E-09 1.8591 E-09 2.0065E-09 51 2.01190E-09 2.0318E-09 2.0447E-09 2.0577E-09 2.0708E-09 56 2.0839E-09 2.0971 E-09 2.1386E-09 1.0034E-03 4.8939E-02 61 7.2757E-01 7.7508E-01 7.9704E-01 7.9971 E-01 8.1826E-01 66 8.2431 E-01 8.9501 E-01 8.9624E-01 8A325E-01 8.1873E-01 71 5.0965E-01 4.7891 E-01 3.3425E-01 3.2160E-01 2.7917E-01 76 2.7686E-01 2.8496E-01 2.8237E-01 2.3586E-01 2.2945E-01 81 1.8141 E-01 1.7592E-01 1.4283E-01 1.3987E-01 1.2915E-01 86 1.2708E-01 1.0724E-01 1.0451 E-01 8.4092E-02 8.1871 E-02 91 6.9465E-02 6.7537E-02 5.1436E-02 4.9606E-02 3.8676E-02 96 3.7838E-02 3.6368E-02 3.5920E-02 3.0742E-02 2.9904E-02 101 2.2704E-02 2.1517E-02 1.1183E-02 1.0463E-02 1.0150E-02 106 1.0052E-02 8.9025E-03 8.7467E-03 7.5931 E-03 7.3788E-03 111 5.3663E-03 5.1133E-03 3.3886E-03 3.2522E-03 2.9604E-03 116 2.9019E-03 2.3281 E-03 2.2891 E-03 2.2845E-03 2.1871E-03 121 7.5517E-04 6.8120E-04 1.0211 E-03 1.0269E-03 7.7033E-04 126 7.6838E-04 9.9585E-04 9.7637E-04 4.6082E-04 4.1802E-04 131 3.0236E-04 3.0038E-04 3.8614E-04 3.9198E-04 3.9224E-04 136 3.9419E-04 4.2277E-04 4.2278E-04 3.9460E-04 4.0432E-04 141 5.7587E-04 5.7976E-04 4.6557E-04 4.5779E-04 4.5740E-04 146 4.5371 E-04 4.0556E-04 6.7003E-04 4.6155E-03 4.6233E-03 151 7.9240E-04 5.2794E-04 4.6203E-04 4.6571 E-04 5.7997E-04 156 5.8191 E-04 4.9623E-04 4.9040E-04 4.9021 E-04 4.9021 E-04 161 4.9040E-04 4.9623E-04 5.8178E-04 5.7593E-04 4.0378E-04 166 3.7868E-04 1.8595E-04 4.1541E-04 3.9892E-03 4.0048E-03 171 6.6056E-04 4.4083E-04 5.4740E-04 5.4723E-04 4.3310E-04 176 4.3115E-04 5.1643E-04 5.1059E-04 3.3891E-04 3.2724E-04 181 3.2684E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 186 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 191 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04

196 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 201 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 206 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 211 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 216 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 221 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 226 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 231 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 236 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 241 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 246 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 C-14 Concentrations at time =8.700E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CiVcmA3) at nodes 1,1+1,...,1+4 251 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 256 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 261 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 266 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 271 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 276 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 281 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 286 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 291 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 296 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 301 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 306 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 311 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 316 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 321 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 326 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 331 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 336 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 341 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 346 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 351 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 356 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 361 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 366 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 371 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 376 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 381 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 386 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 3.2683E-04 391 3.2683E-04 3.2683E-04 3.2682E-04 3.2614E-04 3.061 1E-04 396 7.9905E-07 7.9843E-07 7.9812E-07 7.9780E-07 7.9747E-07 401 7.9714E-07 7.9681E-07 7.9647E-07 7.9613E-07 7.9579E-07 406 7.9152E-07 7.8638E-07 7.8060E-07 7.7417E-07 7.671 OE-07

411 7.5942E-07 7.5113E-07 7.4225E-07 7.3280E-07 7.2279E-07 416 7.1226E-07 7.1297E-07 6.9043E-07 6.6607E-07 6.4009E-07 421 6.1274E-07 5.8426E-07 5.5491E-07 5.2494E-07 4.9461E-07 426 4.6417E-07 4.3385E-07 4.0387E-07 3.7444E-07 3.4575E-07 431 3.1795E-07 2.9119E-07 2.6560E-07 2.4126E-07 2.1825E-07 436 1.9663E-07 1.7642E-07 1.5764E-07 1.4028E-07 1.2431E-07 441 1.0971E-07 9.6423E-08 8.4397E-08 7.3567E-08 6.3862E-08 446 5.5209E-08 4.7532E-08 4.0754E-08 3.4799E-08 2.9592E-08 451 2.5060E-08 2.1134E-08 1.7750E-08 1.4846E-08 1.2365E-08 456 1.0255E-08 8.4678E-09 6.9608E-09 5.6948E-09 4.6349E-09 461 3.7500E-09 3.0125E-09 2.3981 E-09 1.8853E-09 1.4548E-09 466 1.0898E-09 7.7513E-10 4.9691E-10 2.4243E-10 6.0334E-11 H-3 Concentrations at time =9.1OOE+02 ,(Det =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 Mass in solution = 5.53E-18 Mass sorbed = O.OOE+00 Total Mass = 5.53E-18 I 2.9592E-31 1.1837E-30 2.3673E-30 3.5509E-30 4.7343E-30 6 5.9176E-30 7.1006E-30 8.2834E-30 9.4658E-30 1.0648E-29 11 1.1829E-29 1.3011 E-29 1.4191E-29 1.5371 E-29 1.6550E-29 16 1.7728E-29 1.8905E-29 2.0081E-29 2.1256E-29 2.2429E-29 21 2.3601E-29 2.4771 E-29 2.5940E-29 2.7106E-29 2.8271 E-29 26 2.9432E-29 3.0591 E-29 3.1748E-29 3.2901E-29 3A051 E-29 31 3.5197E-29 3.6340E-29 3.7478E-29 3.8612E-29 3.9741 E-29 36 4.0865E-29 4.1983E-29 4.3096E-29 4.4202E-29 4.5302E-29 41 4.5851E-29 4.6397E-29 4.6941 E-29 4.7483E-29 4.8023E-29 46 4.8561E-29 4.9097E-29 4.9631 E-29 5.0163E-29 5.0692E-29 51 5.0735E-29 5.0779E-29 5.0823E-29 5.0867E-29 5.0911 E-29 56 5.0955E-29 5.0999E-29 5.1136E-29 3.2913E-23 3.2905E-23 61 3.2897E-23 3.2885E-23 3.2869E-23 3.2848E-23 3.2823E-23 66 3.2793E-23 3.2760E-23 3.2722E-23 3.2680E-23 3.2634E-23 71 3.2583E-23 3.2529E-23 3.2470E-23 3.2407E-23 3.2340E-23 76 3.2269E-23 3.2194E-23 3.2115E-23 3.2032E-23 3.1945E-23 81 3.1854E-23 3.1759E-23 3.1661 E-23 3.1558E-23 3.1452E-23 86 3.1342E-23 3.1228E-23 3.1111 E-23 3.0990E-23 3.0866E-23 91 3.0738E-23 3.0607E-23 3.0472E-23 3.0334E-23 3.0192E-23 96 3.0048E-23 2.9900E-23 2.9749E-23 2.9594E-23 2.9437E-23 101 2.9277E-23 2.9114E-23 2.8948E-23 2.8779E-23 2.8608E-23 106 2.8434E-23 2.8257E-23 2.8078E-23 2.7896E-23 2.7711 E-23 111 2.7525E-23 2.7336E-23 2.7145E-23 2.6951 E-23 2.6756E-23 116 2.6559E-23 2.6359E-23 2.6158E-23 2.5955E-23 2.5750E-23 121 2.5543E-23 2.5335E-23 2.5125E-23 2.4914E-23 2.4701 E-23 126 2.4487E-23 2.4271 E-23 2A055E-23 2.3837E-23 2.3618E-23

131 2.3398E-23 2.3177E-23 2.2955E-23 2.2733E-23 2.2509E-23 136 2.2285E-23 2.2061E-23 2.1835E-23 2.161 OE-23 2.1384E-23 141 2.1157E-23 2.0930E-23 2.0703E-23 2.0476E-23 2.0248E-23 146 2.0021 E-23 1.9793E-23 1.9566E-23 1.9339E-23 1.9111E-23 151 1.8884E-23 1.8658E-23 1.8432E-23 1.8206E-23 1.7980E-23 156 1.7755E-23 1.7531E-23 1.7307E-23 1.7084E-23 1.6861 E-23 161 1.6640E-23 1.6419E-23 1.6199E-23 1.5980E-23 1.5762E-23 166 1.5544E-23 1.5328E-23 1.5113E-23 1.4899E-23 1.4686E-23 171 1.4474E-23 1.4264E-23 1.4055E-23 1.3847E-23 1.3640E-23 176 1.3435E-23 1.3231 E-23 1.3029E-23 1.2828E-23 1.2628E-23 181 1.2431E-23 1.2234E-23 1.2039E-23 1.1846E-23 1.1654E-23 186 1.1464E-23 1.1276E-23 1.1090E-23 1.0905E-23 1.0721 E-23 191 1.0540E-23 1.0360E-23 1.0182E-23 1.0006E-23 9.8318E-24 196 9.6593E-24 9.4886E-24 9.3198E-24 9.1528E-24 8.9877E-24 201 8.8244E-24 8.6630E-24 8.5035E-24 8.3459E-24 8.1902E-24 206 8.0364E-24 7.8845E-24 7.7344E-24 7.5864E-24 7.4402E-24 211 7.2959E-24 7.1535E-24 7.0131 E-24 6.8745E-24 6.7378E-24 216 6.6031E-24 6.4702E-24 6.3393E-24 6.2102E-24 6.0830E-24 221 5.9577E-24 5.8342E-24 5.7126E-24 5.5929E-24 5.4750E-24 226 5.3589E-24 5.2447E-24 5.1323E-24 5.0216E-24 4.9128E-24 231 4.8058E-24 4.7005E-24 4.5970E-24 4.4952E-24 4.3951 E-24 236 4.2968E-24 4.2001 E-24 4.1052E-24 4.0119E-24 3.9203E-24 241 3.8303E-24 3.7420E-24 3.6552E-24 3.5701 E-24 3.4865E-24 246 3.4045E-24 3.3240E-24 3.2451 E-24 3.1677E-24 3.0918E-24 H-3 Concentrations at time =9.1OOE+02 ,(Deft =1.OOOE+00)

Node I Concentration (CilcmA3) at nodes 1,1+1,...,1+4 251 3.0173E-24 2.9443E-24 2.8728E-24 2.8026E-24 2.7339E-24 256 2.6666E-24 2.6006E-24 2.5360E-24 2.4727E-24 2.4108E-24 261 2.3501E-24 2.2907E-24 2.2326E-24 2.1757E-24 2.1200E-24 266 2.0656E-24 2.0123E-24 1.9602E-24 1.9092E-24 1.8594E-24 271 1.8107E-24 1.7631 E-24 1.7165E-24 1.6711 E-24 1.6266E-24 276 1.5832E-24 1.5408E-24 1.4994E-24 1.4589E-24 1.4194E-24 281 1.3809E-24 1.3432E-24 1.3065E-24 1.2706E-24 1.2356E-24 286 1.2015E-24 1.1682E-24 1.1357E-24 1.1040E-24 1.0732E-24 291 1.0430E-24 1.0137E-24 9.8506E-25 9.5717E-25 9.2999E-25 296 9.0350E-25 8.7770E-25 8.5256E-25 8.2807E-25 8.0423E-25 301 7.8100E-25 7.5839E-25 7.3637E-25 7.1494E-25 6.9408E-25 306 6.7378E-25 6.5402E-25 6.3479E-25 6.1608E-25 5.9788E-25 311 5.8017E-25 5.6295E-25 5A620E-25 5.2991 E-25 5.1407E-25 316 4.9867E-25 4.8369E-25 4.6913E-25 4.5498E-25 4.4122E-25 321 4.2785E-25 4.1486E-25 4.0223E-25 3.8996E-25 3.7803E-25 326 3.6644E-25 3.5519E-25 3.4425E-25 3.3362E-25 3.2330E-25 331 3.1327E-25 3.0353E-25 2.9407E-25 2.8487E-25 2.7594E-25 336 2.6727E-25 2.5885E-25 2.5066E-25 2.4271E-25 2.3499E-25 341 2.2749E-25 2.2020E-25 2.1312E-25 2.0624E-25 1.9955E-25

346 1.9306E-25 1.8675E-25 1.8061E-25 1.7465E-25 1.6885E-25 351 1.6322E-25 1.5774E-25 1.5241E-25 1.4723E-25 1.4219E-25 356 1.3728E-25 1.3250E-25 1.2786E-25 1.2333E-25 1.1892E-25 361 1.1463E-25 1.1045E-25 1.0637E-25 1.0239E-25 9.8510E-26 366 9A724E-26 9.1028E-26 8.7419E-26 8.3893E-26 8.0447E-26 371 7.7076E-26 7.3779E-26 7.0550E-26 6.7388E-26 6.4290E-26 376 6.1251E-26 5.8269E-26 5.5341 E-26 5.2465E-26 4.9636E-26 381 4.6853E-26 4.4113E-26 4.1413E-26 3.8750E-26 3.6121E-26 386 3.3525E-26 3.0958E-26 2.8418E-26 2.5902E-26 2.3408E-26 391 2.0933E-26 1.8475E-26 1.6031 E-26 1.3600E-26 1.1178E-26 396 8.7634E-27 8.7371 E-27 8.7238E-27 8.7106E-27 8.6974E-27 401 8.6843E-27 8.6712E-27 8.6581 E-27 8.6450E-27 8.6320E-27 406 8.4853E-27 8.3342E-27 8.1865E-27 8.0422E-27 7.9011E-27 411 7.7632E-27 7.6283E-27 7.4963E-27 7.3672E-27 7.2408E-27 416 7.1171E-27 7.1251E-27 6.8851 E-27 6.6547E-27 6.4332E-27 421 6.2202E-27 6.0151 E-27 5.8173E-27 5.6263E-27 5.4418E-27 426 5.2632E-27 5.0903E-27 4.9225E-27 4.7597E-27 4.6014E-27 431 4.4474E-27 4.2973E-27 4.1510E-27 4.0082E-27 3.8686E-27 436 3.7320E-27 3.5983E-27 3.4673E-27 3.3387E-27 3.2125E-27 441 3.0885E-27 2.9665E-27 2.8464E-27 2.7280E-27 2.6114E-27 446 2.4963E-27 2.3827E-27 2.2704E-27 2.1594E-27 2.0495E-27 451 1.9408E-27 1.8331 E-27 1.7264E-27 1.6205E-27 1.5155E-27 456 1.4112E-27 1.3076E-27 1.2047E-27 1.1023E-27 1.0005E-27 461 8.9911E-28 7.9816E-28 6.9759E-28 5.9734E-28 4.9737E-28 466 3.9762E-28 2.9806E-28 1.9863E-28 9.9291 E-29 2.4822E-29 C-14 Concentrations at time =9.100E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.04E+04 Mass sorbed = O.OOE+00 Total Mass = 2.04E+04 1 3.9106E-14 1.5731E-13 3.2445E-13 5.1112E-13 7.2825E-13 6 9.8821E-13 1.3054E-12 1.6968E-12 2.1826E-12 2.7875E-12 11 3.5409E-12 4.4784E-12 5.6434E-12 7.0879E-12 8.8746E-12 16 1.1079E-11 1.3791 E-11 1.7120E-11 2.1193E-11 2.6163E-11 21 3.2212E-1I 3.9554E-11 4.8441E-11 5.9167E-11 7.2080E-11 26 8.7583E-1 1 1.0615E-10 1.2832E-10 1.5472E-10 1.8610E-10 31 2.2328E-10 2.6722E-10 3.1903E-10 3.7996E-10 4.5144E-10 36 5.3509E-10 6.3275E-10 7.4648E-10 8.7861E-10 1.0318E-09 41 1.1176E-09 1.2095E-09 1.3083E-09 1.4143E-09 1.5281 E-09 46 1.6501E-09 1.7808E-09 1.9208E-09 2.0707E-09 2.23IOE-09 51 2.2445E-09 2.2585E-09 2.2725E-09 2.2866E-09 2.3007E-09 56 2.3150E-09 2.3293E-09 2.3743E-09 1.0890E-03 5.0750E-02 61 7.2210E-01 7.7126E-01 7.9314E-01 7.9590E-01 8.1427E-01

66 8.2053E-01 8.9D48E-01 8.9175E-01 8.3927E-01 8.1389E-01 71 5.0805E-01 4.7625E-01 3.3305E-01 3.1996E-01 2.7794E-01 76 2.7556E-01 2.8356E-01 2.8087E-01 2.3484E-01 2.2822E-01 81 1.8067E-01 1.7499E-01 1.4224E-01 1.3917E-01 1.2855E-01 86 1.2641 E-01 1.0677E-01 1.0395E-01 8.3742E-02 8.1445E-02 91 6.9162E-02 6.7167E402 5.1232E-02 4.9338E-02 3.8521 E-02 96 3.7653E-02 3.6196E-02 3.5731 E-02 3.0607E-02 2.9740E-02 101 2.2613E-02 2.1385E-02 1.1 159E-02 1.0414E-02 1.0102E-02 106 1.0000E-02 8.8626E-03 8.7013E-03 7.5593E-03 7.3377E-03 ill 5.3459E-03 5.0840E-03 3.3771 E-03 3.2360E-03 2.9468E-03 116 2.8863E-03 2.3185E'03 2.2782E-03 2.2731 E-03 2.1724E-03 121 7.5574E-04 6.7921E-04 1.0152E-03 1.021 1 E403 7.6741 E-04 126 7.6538E-04 9.9027E-04 9.7012E-04 4.6006E-04 4.1578E-04 131 3.0125E-04 2.9921 E-04 3.8403E-04 3.9007E-04 3.9035E-04 136 3.9237E-04 4.2064E-04 4.2065E04D 3.9281 E04D 4.0287E-04 141 5.7257E-04 5.7660E-04 4.6365E-04 4.5561 E-04 4.5518E-04 146 4.5139E-04 4.0459E044 6.7821 E-04 4.5810OE-03 4.5891E-03 151 7.9963E-04 5.2602E-04 4.6002E-04 4.6381 E-04 5.7682E-04 156 5.7883E-04 4.9409E-04 4.8806E-04 4.8784E-04 4.8784E-04 161 4.8806E-04 4.9408E-04 5.7868E-04 5.7263E-04 4.0229E-04 166 3.7633E-04 1.8638E-04 4.2377E-04 3.9589E-03 3.9750E-03 171 6.6706E-04 4.3973E-04 5.4443E-04 5.4424E-04 4.3136E-04 176 4.2934E-04 5.1366E-04 5.0761 E-04 3.3777E-04 3.2569E-04 181 3.2526E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 186 3.2525E-04 3.2525E-04 3.2525E04D 3.2525E-04 3.2525E-04 191 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 196 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 201 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 206 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 211 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 216 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 221 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 226 3.2525E04D 3.2525E044 3.2525E-04 3.2525E-04 3.2525E-04 231 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 236 3.2525E-04 3.2525E-04 3.2525E04D 3.2525E04D 3.2525E04D 241 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 246 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E04D C-14 Concentrations at time =9.IOOE+02 ,(Delt =1.000E+00)

Node I Concentration (CVCMA3) at nodes 1,1+1,...,1+4 251 3.2525E-04 3.2525E 04 3.2525E-04 3.2525E-04 3.2525E-04 256 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 261 3.2525E-04 3.2525E-04 3.2525E 04 3.2525E-04 3.2525E-04 266 3.2525E-04 3.2525E 04 3.2525E-04 3.2525E-04 3.2525E-04 271 3.2525E-04 3.252SE-04 3.2525E-04 3.2525E-04 3.2525E04D 276 3.2525E 04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E04D

281 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 286 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 291 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 296 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 301 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 306 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 311 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 316 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 321 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 326 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 331 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 336 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 341 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 346 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 351 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 356 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 361 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 366 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 371 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 376 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 381 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 386 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 3.2525E-04 391 3.2525E-04 3.2525E-04 3.2524E-04 3.2451 E-04 3.0374E-04 396 7.8144E-07 7.8082E-07 7.8051 E-07 7.8020E-07 7.7988E-07 401 7.7955E-07 7.7922E-07 7.7889E-07 7.7855E-07 7.7821 E-07 406 7.7403E-07 7.6903E-07 7.6343E-07 7.5724E-07 7.5046E-07 411 7.4310E-07 7.3518E-07 7.2671E-07 7.1771 E-07 7.0819E-07 416 6.9818E-07 6.9885E-07 6.7747E-07 6.5436E-07 6.2973E-07 421 6.0378E-07 5.7675E-07 5.4887E-07 5.2036E-07 4.9146E-07 426 4.6239E-07 4.3337E-07 4.0461 E-07 3.7630E-07 3.4862E-07 431 3.2172E-07 2.9573E-07 2.7079E-07 2.4698E-07 2.2438E-07 436 2.0305E-07 1.8302E-07 1.6432E-07 1.4696E-07 1.3091 E-07 441 1.1615E-07 1.0265E-07 9.0366E-08 7.9237E-08 6.9204E-08 446 6.0203E-08 5.2167E-08 4.5025E-08 3.8708E-08 3.3146E-08 451 2.8271 E-08 2.4017E-08 2.0323E-08 1.7128E-08 1.4377E-08 456 1.2018E-08 1.0004E-08 8.2904E-09 6.8382E-09 5.611 OE-09 461 4.5766E-09 3.7058E-09 2.9727E-09 2.3538E-09 1.8284E-09 466 1.3776E-09 9.8454E-10 6.3343E-10 3.0974E-10 7.7119E-1 I H-3 Concentrations at time =9.610E+02 ,(Delt =1.OOOE+00)

Node I Concentration (CicmA3) at nodes 1,1+1,....,1+4 Mass In solution = 3.40E-19 Mass sorbed = O.OOE+00 Total Mass = 3.40E-19

1 1.8125E-32 7.2499E-32 1.4499E-31 2.1748E-31 2.8995E-31 6 3.6239E-31 4.3482E-31 5.0721 E-31 5.7956E-31 6.5188E-31 11 7.2414E-31 7.9635E-31 8.6849E-31 9.4057E-31 1.0126E-30 16 1.0845E-30 1.1563E-30 1.2280E-30 1.2996E-30 1.371 1E-30 21 1.4425E-30 1.5137E-30 1.5847E-30 1.6556E-30 1.7263E-30 26 1.7969E-30 1.8672E-30 1.9373E-30 2.0071 E-30 2.0767E-30 31 2.1461E-30 2.2152E-30 2.2839E-30 2.3524E-30 2.4205E-30 36 2.4882E-30 2.5556E-30 2.6226E-30 2.6891 E-30 2.7553E-30 41 2.7882E-30 2.821OE-30 2.8537E-30 2.8862E-30 2.9186E-30 46 2.9508E-30 2.9830E-30 3.0150E-30 3.0468E-30 3.0786E-30 51 3.0811 E-30 3.0838E-30 3.0864E-30 3.0890E-30 3.0917E-30 56 3.0943E-30 3.0969E-30 3.1051 E-30 1.9702E-24 1.9698E-24 61 1.9693E-24 1.9686E-24 1.9677E-24 1.9665E-24 1.9651 E-24 66 1.9634E-24 1.9615E-24 1.9594E-24 1.9570E-24 1.9544E-24 71 1.9515E-24 1.9484E-24 1.9451 E-24 1.9415E-24 1.9377E-24 76 1.9337E-24 1.9294E-24 1.9249E-24 1.9202E-24 1.9152E-24 81 1.9101 E-24 1.9047E-24 1.8991 E-24 1.8932E-24 1.8872E-24 86 1.8809E-24 1.8745E-24 1.8678E-24 1.8609E-24 1.8538E-24 91 1.8465E-24 1.8390E-24 1.8314E-24 1.8235E-24 1.8154E-24 96 1.8072E-24 1.7987E-24 1.7901 E-24 1.7813E-24 1.7723E-24 101 1.7632E-24 1.7539E-24 1.7444E-24 1.7348E-24 1.7250E-24 106 1.7150E-24 1.7049E-24 1.6946E-24 1.6842E-24 1.6737E-24 111 1.6630E-24 1.6521 E-24 1.6412E-24 1.6301 E-24 1.6189E-24 116 1.6075E-24 1.5961 E-24 1.5845E-24 1.5729E-24 1.561 1E-24 121 1.5492E-24 1.5372E-24 1.5251 E-24 1.5130E-24 1.5007E-24 126 1.4884E-24 1.4759E-24 1.4634E-24 1.4509E-24 1.4382E-24 131 1.4255E-24 1.4128E-24 1.3999E-24 1.3871 E-24 1.3741 E-24 136 1.3612E-24 1.3481 E-24 1.3351 E-24 1.3220E-24 1.3089E-24 141 1.2957E-24 1.2825E-24 1.2693E-24 1.2561 E-24 1.2429E-24 146 1.2296E-24 1.2163E-24 1.2031 E-24 1.1898E-24 1.1766E-24 151 1.1633E-24 1.1501 E-24 1.1368E-24 1.1236E-24 1.1 104E-24 156 1.0972E-24 1.0841 E-24 1.0709E-24 1.0578E-24 1.0448E-24 161 1.0317E-24 1.0187E-24 1.0058E-24 9.9287E-25 9.8000E-25 166 9.6718E-25 9.5442E-25 9.4171E-25 9.2905E-25 9.1645E-25 171 9.0392E-25 8.9144E-25 8.7904E-25 8.6669E-25 8.5442E-25 176 8.4222E-25 8.3009E-25 8.1804E-25 8.0607E-25 7.9417E-25 181 7.8236E-25 7.7062E-25 7.5897E-25 7.4741E-25 7.3594E-25 186 7.2455E-25 7.1325E-25 7.0204E-25 6.9093E-25 6.7991 E-25 191 6.6899E-25 6.5816E-25 6.4743E-25 6.3679E-25 6.2626E-25 196 6.1583E-25 6.0550E-25 5.9527E-25 5.8514E-25 5.7511 E-25 201 5.6519E-25 5.5538E-25 5.4567E-25 5.3606E-25 5.2657E-25 206 5.1717E-25 5.0789E-25 4.9871 E-25 4.8964E-25 4.8068E-25 211 4.7183E-25 4.6308E-25 4.5445E-25 4.4592E-25 4.3750E-25 216 4.2918E-25 4.2098E-25 4.1289E-25 4.0490E-25 3.9702E-25 221 3.8925E-25 3.8158E-25 3.7403E-25 3.6658E-25 3.5923E-25 226 3.5200E-25 3.4486E-25 3.3784E-25 3.3092E-25 3.2410E-25 231 3.1738E-25 3.1077E-25 3.0427E-25 2.9786E-25 2.9156E-25 236 2.8535E-25 2.7925E-25 2.7325E-25 2.6734E-25 2.6154E-25 241 2.5583E-25 2.5021E-25 2.4469E-25 2.3927E-25 2.3394E-25 246 2.2871E-25 2.2356E-25 2.1851 E-25 2.1355E-25 2.0867E-25

H-3 Concentrations at time =9.610E+02 ,(Deft =1.000E+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 2.0389E-25 1.9919E-25 1.9459E-25 1.9006E-25 1.8562E-25 256 1.8127E-25 1.7700E-25 1.7281 E-25 1.6870E-25 1.6467E-25 261 1.6072E-25 1.5685E-25 1.5306E-25 1.4934E-25 1A569E-25 266 1.4212E-25 1.3863E-25 1.3520E-25 1.3185E-25 1.2857E-25 271 1.2535E-25 1.2220E-25 1.1912E-25 1.1611E-25 1.1316E-25 276 1.1027E-25 1.0745E-25 1.0469E-25 1.0199E-25 9.9351E-26 281 9.6770E-26 9.4246E-26 9.1780E-26 8.9369E-26 8.7014E-26 286 8.4712E-26 8.2464E-26 8.0268E-26 7.8122E-26 7.6028E-26 291 7.3982E-26 7.1985E-26 7.0035E-26 6.8132E-26 6.6275E-26 296 6.4463E-26 6.2694E-26 6.0969E-26 5.9286E-26 5.7644E-26 301 5.6043E-26 5A481E-26 5.2959E-26 5.1474E-26 5.0027E-26 306 4.8617E-26 4.7242E-26 4.5902E-26 4.4597E-26 4.3325E-26 311 4.2085E-26 4.0878E-26 3.9702E-26 3.8557E-26 3.7441 E-26 316 3.6355E-26 3.5298E-26 3.4268E-26 3.3265E-26 3.2289E-26 321 3.1339E-26 3.0415E-26 2.9515E-26 2.8639E-26 2.7787E-26 326 2.6958E-26 2.6151 E-26 2.5366E-26 2.4602E-26 2.3859E-26 331 2.3136E-26 2.2433E-26 2.1749E-26 2.1084E-26 2.0436E-26 336 1.9807E-26 1.9194E-26 1.8599E-26 1.8020E-26 1.7456E-26 341 1.6908E-26 1.6375E-26 1.5856E-26 1.5352E-26 1.4861 E-26 346 1.4384E-26 1.3919E-26 1.3467E-26 1.3027E-26 1.2599E-26 351 1.2183E-26 1.1777E-26 1.1382E-26 1.0998E-26 1.0624E-26 356 1.0259E-26 9.9042E-27 9.5582E-27 9.22IOE-27 8.8923E-27 361 8.5719E-27 8.2594E-27 7.9545E-27 7.6570E-27 7.3665E-27 366 7.0830E-27 6.8060E-27 6.5353E-27 6.2707E-27 6.0119E-27 371 5.7586E-27 5.5108E-27 5.2680E-27 5.0301E-27 4.7969E-27 376 4.5681E-27 4.3435E-27 4.1229E-27 3.9061E-27 3.6929E-27 381 3.4830E-27 3.2764E-27 3.0727E-27 2.8718E-27 2.6734E-27 386 2A775E-27 2.2838E-27 2.0920E-27 1.9021 E-27 1.7139E-27 391 1.5271E-27 1.3416E-27 1.1571E-27 9.7359E-28 7.9081E-28 396 6.0857E-28 6.0658E-28 6.0559E-28 6.0459E-28 6.0360E-28 401 6.0260E-28 6.0161E-28 6.0063E-28 5.9964E-28 5.9866E-28 406 5.8761 E-28 5.7623E-28 5.6512E-28 5.5428E-28 5.4370E-28 411 5.3337E-28 5.2328E-28 5.1343E-28 5.0380E-28 4.9439E-28 416 4.8519E-28 4.8579E-28 4.6799E-28 4.5097E-28 4.3468E-28 421 4.1906E-28 4.0409E-28 3.8971E-28 3.7590E-28 3.6261 E-28 426 3.4981 E-28 3.3747E-28 3.2556E-28 3.1405E-28 3.0292E-28 431 2.9214E-28 2.8170E-28 2.7156E-28 2.6171E-28 2.5212E-28 436 2.4280E-28 2.3370E-28 2.2483E-28 2.1616E-28 2.0769E-28 441 1.9939E-28 1.9126E-28 1.8329E-28 1.7547E-28 1.6778E-28 446 1.6021E-28 1.5277E-28 1.4544E-28 1.3821E-28 1.3107E-28 451 1.2403E-28 1.1706E-28 1.1017E-28 1.0336E-28 9.6603E-29 456 8.9910E-29 8.3271 E-29 7.6683E-29 7.0139E-29 6.3637E-29 461 5.7172E-29 5.0739E-29 4.4335E-29 3.7956E-29 3.1598E-29

466 2.5257E-29 1.8931 E-29 1.2615E-29 6.3056E-30 1.5763E-30 C-14 Concentrations at time =9.610E+02 ,(Dett =1.OOOE+00)

Node I Concentration (CilcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.03E+04 Mass sorbed = O.OOE+00 Total Mass = 2.03E+04 1 5.8213E-14 2.3407E-13 4.8157E-13 7.5573E-13 1.0713E-12 6 1.4449E-12 1.8956E-12 2.4456E-12 3.1212E-12 3.9540E-12 11 4.9814E-12 6.2484E-12 7.8089E-12 9.7274E-1 2 1.2081E-11 16 1.4961E-1 1 1.8478E-1 1 2.2761 E-11 2.7962E-1 I 3.4264E-1 I 21 4.1879E-1 I 5.1057E-1 1 6.2089E-1 1 7.5318E-1 1 9.1 140E-1 I 26 1.1002E-10 1.3248E-10 1.5914E-10 1.9071E-10 2.2800E-10 31 2.7195E-10 3.2360E-1 0 3.8418E-10 4.5504E-10 5.3776E-10 36 6.3408E-10 7.4599E-10 8.7570E-10 1.0257E-09 1.1988E-09 41 11.2955E-09 1.3989E-09 1.5097E-09 1.6284E-09 1.7555E-09 46 I.8915E-09 2.0369E-09 2.1924E-09 2.3586E-09 2.5360E-09 51 2.5509E-09 2.5663E-09 2.5818E-09 2.5974E-09 2.6130E-09 56 2.6288E-09 2.6446E-09 2.6943E-09 1.2021 E-03 5.3009E-02 61 7.1521E-01 7.6640E-01 7.8818E-01 7.9107E-01 8.0922E-01 66 8.1574E-01 8.8473E-01 8.8605E-01 8.3421E-01 8.0778E-01 71 5.0601 E-01 4.7289E-01 3.3151 E-01 3.1788E-01 2.7639E-01 76 2.7390E-01 2.8177E-01 2.7897E-01 2.3355E-01 2.2665E-01 81 1.7972E-01 1.7381E-01 1.4148E-01 1.3829E-01 1.2779E-01 86 1.2557E-01 1.0618E-01 1.0324E-01 8.3298E-02 8.0905E-02 91 6.8777E-02 6.6699E-02 5.0972E-02 4.9000E-02 3.8323E-02 96 3.7420E-02 3.5977E-02 3.5493E-02 3.0435E-02 2.9532E-02 101 2.2497E-02 2.1218E-02 1.1 128E-02 1.0352E-02 1.0040E-02 106 9.9346E-03 8.811 9E-03 8.6440E-03 7.5164E-03 7.2856E-03 111 5.3198E-03 5.0471E-03 3.3625E-03 3.2156E-03 2.9296E-03 116 2.8665E-03 2.3063E-03 2.2643E-03 2.2588E-03 2.1539E-03 121 7.5638E-04 6.7667E-04 1.0076E-03 1.0138E-03 7.6368E-04 126 7.6157E-04 9.8321 E-04 9.6222E-04 4.5907E-04 4.1295E-04 131 2.9984E-04 2.9771 E-04 3.8136E-04 3.8765E-04 3.8796E-04 136 3.9006E-04 4.1794E-04 4.1796E-04 3.9055E-04 4.0102E-04 141 5.6840E-04 5.7259E-04 4.6122E-04 4.5284E-04 4.5237E-04 146 4.4844E-04 4.0340E-04 6.8835E-04 4.5375E-03 4.5459E-03 151 8.0857E-04 5.2364E-04 4.5747E-04 4.6139E-04 5.7284E-04 156 5.7493E-04 4.9136E-04 4.8508E-04 4.8484E-04 4.8484E-04 161 4.8508E-04 4.9135E-04 5.7477E-04 5.6846E-04 4.0038E-04 166 3.7338E-04 1.8695E-04 4.3417E-04 3.9207E-03 3.9374E-03 171 6.7511 E-04 4.3836E-04 5.4067E-04 5.4045E-04 4.2915E-04 176 4.2705E-04 5.1014E-04 5.0384E-04 3.3631E-04 3.2374E-04 181 3.2326E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04

186 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 191 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 196 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 201 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 206 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 211 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 216 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 221 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 226 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 231 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 236 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 241 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 246 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 C-14 Concentrations at time =9.610E+02 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 256 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 261 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 266 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 271 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 276 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 281 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 286 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 291 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 296 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 301 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 306 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 311 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 316 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 321 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 326 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 331 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 336 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 341 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 346 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 351 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 356 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 361 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 366 3.2325E-041 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 371 3.2325E-041 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 376 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 381 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 386 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 3.2325E-04 391 3.2325E-04 3.2325E-04 3.2323E-04 3.2243E-04 3.0076E-04 396 7.6055E-07 7.5994E-07 7.5964E-07 7.5933E-07 7.5901 E-07

401 7.5869E-07 7.5837E-07 7.5804E-07 7.5771 E-07 7.5738E-07 406 7.5330E-07 7.4846E-07 7.4307E-07 7.3714E-07 7.3068E-07 411 7.2369E-07 7.1619E-07 7.0818E-07 6.9969E-07 6.9073E-07 416 6.8132E-07 6.8195E-07 6.6186E-07 6.4018E-07 6.1708E-07 421 5.9275E-07 5.6738E-07 5.4117E-07 5.1435E-07 4.8710E-07 426 4.5964E-07 4.3216E-07 4.0485E-07 3.7788E-07 3.5141 E-07 431 3.2561 E-07 3.0058E-07 2.7646E-07 2.5334E-07 2.3129E-07 436 2.1037E-07 1.9064E-07 1.7212E-07 1.5481E-07 1.3873E-07 441 1.2386E-07 1.1017E-07 9.7623E-08 8.6186E-08 7.5804E-08 446 6.6424E-08 5.7987E-08 5.0432E-08 4.3698E-08 3.7721 E-08 451 3.2440E-08 2.7793E-08 2.3721 E-08 2.0168E-08 1.7081E-08 456 1.4409E-08 1.2106E-08 1.0126E-08 8.4307E-09 6.9825E-09 461 5.7479E-09 4.6962E-09 3.7996E-09 3.0330E-09 2.3734E-09 466 1.7999E-09 1.2931 E-09 8.3528E-10 4.0947E-10 1.0200E-10 H-3 Concentrations at time =9.800E+02 ,(Delt =1.OOOE 00)

Node I Concentration (CicmA3) at nodes 1,1+1,...,1+4 Mass in solution = 1.20E-19 Mass sorbed = O.OOE+00 Total Mass = 1.20E-19 1 6.4000E-33 2.5600E-32 5.1197E-32 7.6791E-32 1.0238E-31 6 1.2796E-31 1.5353E-31 1.7908E-31 2.0462E-31 2.3014E-31 11 2.5565E-31 2.8113E-31 3.0659E-31 3.3201 E-31 3.5741 E-31 16 3.8278E-31 4.081OE-31 4.3339E-31 4.5864E-31 4.8383E-31 21 5.0898E-31 5.3407E-31 5.591OE-31 5.8407E-31 6.0897E-31 26 6.3380E-31 6.5855E-31 6.8321 E-31 7.0779E-31 7.3228E-31 31 7.5667E-31 7.8095E-31 8.0512E-31 8.2917E-31 8.5310E-31 36 8.7689E-31 9.0055E-31 9.2407E-31 9.4743E-31 9.7063E-31 41 9.8220E-31 9.9369E-31 1.0051 E-30 1.0166E-30 1.0279E-30 46 1.0392E-30 1.0505E-30 1.0617E-30 1.0729E-30 1.0840E-30 51 1.0849E-30 1.0858E-30 1.0867E-30 1.0877E-30 1.0886E-30 56 1.0895E-30 1.0904E-30 1.0933E-30 6.9038E-25 6.9024E-25 61 6.9008E-25 6.8984E-25 6.8952E-25 6.8912E-25 6.8863E-25 66 6.8805E-25 6.8740E-25 6.8666E-25 6.8584E-25 6.8494E-25

'71 6.8395E-25 6.8289E-25 6.8174E-25 6.8051 E-25 6.7920E-25 76 6.7781E-25 6.7635E-25 6.7480E-25 6.7318E-25 6.7148E-25 81 6.6970E-25 6.6785E-25 6.6592E-25 6.6391 E-25 6.6183E-25 86 6.5968E-25 6.5745E-25 6.5516E-25 6.5279E-25 6.5035E-25 91 6.4784E-25 6.4526E-25 6.4262E-25 6.3991E-25 6.3713E-25 96 6.3429E-25 6.3138E-25 6.2841 E-25 6.2538E-25 6.2229E-25 101 6.1914E-25 6.1593E-25 6.1266E-25 6.0934E-25 6.0596E-25 106 6.0253E-25 5.9904E-25 5.9550E-25 5.9191 E-25 5.8828E-25 111 5.8459E-25 5.8085E-25 5.7707E-25 5.7325E-25 5.6938E-25 116 5.6547E-25 5.6152E-25 5.5752E-25 5.5349E-25 5.4943E-25

121 5.4532E-25 5.4118E-25 5.3701 E-25 5.3281 E-25 5.2857E-25 126 5.2431E-25 5.2001 E-25 5.1569E-25 5.1135E-25 5.0698E-25 131 5.0258E-25 4.9816E-25 4.9373E-25 4.8927E-25 4.8479E-25 136 4.8030E-25 4.7579E-25 4.7127E-25 4.6674E-25 4.6219E-25 141 4.5763E-25 4.5306E-25 4.4848E-25 4.4390E-25 4.3931 E-25 146 4.3471 E-25 4.3012E-25 4.2551 E-25 4.2091 E-25 4.1631E-25 151 4.1171E-25 4.0711 E-25 4.0251 E-25 3.9791 E-25 3.9333E-25 156 3.8874E-25 3.8417E-25 3.7960E-25 3.7505E-25 3.7050E-25 161 3.6596E-25 3.6144E-25 3.5693E-25 3.5243E-25 3.4795E-25 166 3.4349E-25 3.3904E-25 3.3461 E-25 3.3019E-25 3.2580E-25 171 3.2142E-25 3.1707E-25 3.1274E-25 3.0843E-25 3.0415E-25 176 2.9988E-25 2.9565E-25 2.9143E-25 2.8725E-25 2.8309E-25 181 2.7895E-25 2.7485E-25 2.7077E-25 2.6672E-25 2.6270E-25 186 2.5871E-25 2.5475E-25 2.5082E-25 2.4693E-25 2.4306E-25 191 2.3923E-25 2.3543E-25 2.3166E-25 2.2793E-25 2.2423E-25 196 2.2056E-25 2.1693E-25 2.1333E-25 2.0977E-25 2.0624E-25 201 2.0275E-25 1.9929E-25 1.9587E-25 1.9249E-25 1.8914E-25 206 1.8583E-25 1.8256E-25 1.7932E-25 1.7612E-25 1.7295E-25 211 1.6983E-25 1.6674E-25 1.6368E-25 1.6067E-25 1.5769E-25 216 1.5475E-25 1.5184E-25 1.4898E-25 1.4615E-25 1.4336E-25 221 1.4060E-25 1.3788E-25 1.3520E-25 1.3256E-25 1.2995E-25 226 1.2738E-25 1.2485E-25 1.2235E-25 1.1989E-25 1.1746E-25 231 1.1507E-25 1.1272E-25 1.1040E-25 1.0812E-25 1.0587E-25 236 1.0366E-25 1.0148E-25 9.9341 E-26 9.7233E-26 9.5158E-26 241 9.3118E-26 9.1111E-26 8.9138E-26 8.7198E-26 8.5290E-26 246 8.3415E-26 8.1572E-26 7.9761 E-26 7.7982E-26 7.6234E-26 H-3 Concentrations at time =9.800E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 251 7.4517E-26 7.2831 E-26 7.1176E-26 6.9550E-26 6.7954E-26 256 6.6388E-26 6.4851E-26 6.3343E-26 6.1863E-26 6.0411 E-26 261 5.8987E-26 5.7591E-26 5.6222E-26 5.4879E-26 5.3563E-26 266 5.2273E-26 5.1009E-26 4.9770E-26 4.8557E-26 4.7368E-26 271 4.6203E-26 4.5063E-26 4.3946E-26 4.2853E-26 4.1782E-26 276 4.0734E-26 3.9709E-26 3.8706E-26 3.7724E-26 3.6763E-26 281 3.5823E-26 3.4904E-26 3.4006E-26 3.3127E-26 3.2268E-26 286 3.1428E-26 3.0607E-26 2.9804E-26 2.9020E-26 2.8254E-26 291 2.7506E-26 2.6775E-26 2.6061 E-26 2.5363E-26 2.4682E-26 296 2.4018E-26 2.3369E-26 2.2735E-26 2.2117E-26 2.1513E-26 301 2.0924E-26 2.0350E-26 1.9789E-26 1.9242E-26 1.8709E-26 306 1.8189E-26 1.7681 E-26 1.7187E-26 1.6705E-26 1.6235E-26 311 1.5776E-26 1.5330E-26 1.4894E-26 1.4470E-26 1.4057E-26 316 1.3654E-26 1.3262E-26 1.2880E-26 1.2507E-26 1.2145E-26 321 1.1792E-26 1.1448E-26 1.1113E-26 1.0787E-26 1.0469E-26 326 1.0160E-26 9.8595E-27 9.5666E-27 9.2815E-27 9.0039E-27 331 8.7338E-27 8.4709E-27 8.2150E-27 7.9660E-27 7.7237E-27

336 7.4879E-27 7.2583E-27 7.0350E-27 6.8176E-27 6.6061E-27 341 6.4003E-27 6.2000E-27 6.0050E-27 5.8153E-27 5.6306E-27 346 5.4509E-27 5.2759E-27 5.1056E-27 4.9398E-27 4.7784E-27 351 4.6212E-27 4.4682E-27 4.3191E-27 4.1739E-27 4.0324E-27 356 3.8946E-27 3.7603E-27 3.6293E-27 3.5017E-27 3.3772E-27 361 3.2558E-27 3.1374E-27 3.0218E-27 2.9090E-27 2.7988E-27 366 2.6912E-27 2.5860E-27 2.4832E-27 2.3827E-27 2.2844E-27 371 2.1881E-27 2.0939E-27 2.0016E-27 1.9111E-27 1.8223E-27 376 1.7352E-27 1.6498E-27 1.5658E-27 1.4832E-27 1.4020E-27 381 1.3221E-27 1.2433E-27 1.1657E-27 1.0891E-27 1.0135E-27 386 9.3884E-28 8.6497E-28 7.9187E-28 7.1946E-28 6.4767E-28 391 5.7643E-28 5.0567E-28 4.3532E-28 3.6533E-28 2.9561 E-28 396 2.2611 E-28 2.2535E-28 2.2497E-28 2.2459E-28 2.2421 E-28 401 2.2383E-28 2.2346E-28 2.2308E-28 2.2270E-28 2.2233E-28 406 2.1811 E-28 2.1378E-28 2.0954E-28 2.0541E-28 2.0138E-28 411 1.9745E-28 1.9361 E-28 1.8986E-28 1.8620E-28 1.8262E-28 416 1.7913E-28 1.7936E-28 1.7260E-28 1.6614E-28 1.5997E-28 421 1.5406E-28 1.4839E-28 1.4297E-28 1.3776E-28 1.3275E-28 426 1.2794E-28 1.2331 E-28 1.1884E-28 1.1454E-28 1.1038E-28 431 1.0636E-28 1.0247E-28 9.8701 E-29 9.5045E-29 9.1496E-29 436 8.8045E-29 8.4688E-29 8.1417E-29 7.8227E-29 7.5113E-29 441 7.2069E-29 6.9092E-29 6.6176E-29 6.3318E-29 6.0514E-29 446 5.7760E-29 5.5052E-29 5.2387E-29 4.9763E-29 4.7177E-29 451 4.4625E-29 4.2106E-29 3.9616E-29 3.7154E-29 3.4717E-29 456 3.2304E-29 2.9912E-29 2.7540E-29 2.5185E-29 2.2846E-29 461 2.0522E-29 1.8211E-29 1.5910E-29 1.3620E-29 1.1337E-29 466 9.0616E-30 6.7914E-30 4.5254E-30 2.2620E-30 5.6547E-31 C-14 Concentrations at time =9.800E+02 ,(Delt =1.OOOE+00)

Node I Concentration (Cicm^3) at nodes 1,1+1,...,1+4 Mass In solution = 2.03E+04 Mass sorbed = O.OOE+00 Total Mass = 2.03E+04 I 6.6949E-14 2.6915E-13 5.5330E-13 8.6716E-13 1.2272E-12 6 1.6517E-12 2.1617E-12 2.7818E-12 3.5407E-12 4.4728E-12 11 5.6189E-12 7.0279E-12 8.7579E-12 1.0878E-11 1.3472E-11 16 1.6638E-11 2.0493E-11 2.5174E-11 3.0845E-11 3.7698E-11 21 4.5959E-11 5.5890E-11 6.7801 E-11 8.2049E-11 9.9051 E-11 26 1.1929E-10 1.4332E-10 1.7179E-10 2.0542E-10 2.4507E-10 31 2.9170E-10 3.4641E-10 4.1044E-10 4.8522E-10 5.7235E-10 36 6.7363E-10 7.9109E-10 9.2703E-10 1.0840E-09 1.2648E-09 41 1.3657E-09 1.4735E-09 1.5889E-09 1.7125E-09 1.8448E-09 46 1.9861E-09 2.1373E-09 2.2987E-09 2.4710E-09 2.6550E-09 51 2.6705E-09 2.6864E-09 2.7025E-09 2.7186E-09 2.7349E-09

56 2.7512E-09 2.7676E-09 2.8190E-09 1.2453E-03 5.3836E-02 61 7.1266E-01 7.6460E-01 7.8634E-01 7.8927E-01 8.0734E-01 66 8.1396E-01 8.8260E-01 8.8394E-01 8.3233E-01 8.0552E-01 71 5.0524E-01 4.7164E-01 3.3094E-01 3.1711E-01 2.7581 E-01 76 2.7329E-01 2.8111E-01 2.7827E-01 2.3307E-01 2.2607E-01 81 1.7937E-01 1.7337E-01 1.A120E-01 1.3796E-01 1.2751 E-01 86 1.2525E-01 1.0596E-01 1.0298E-01 8.3133E-02 8.0704E-02 91 6.8634E-02 6.6526E-02 5.0875E-02 4.8874E-02 3.8249E-02 96 3.7333E-02 3.5896E-02 3.5405E-02 3.0371E-02 2.9456E-02 101 2.2454E-02 2.1156E-02 1.1116E-02 1.0328E-02 1.0018E-02 106 9.9103E-03 8.7931 E-03 8.6227E-03 7.5005E-03 7.2663E-03 111 5.3101E-03 5.0334E-03 3.3571 E-03 3.2080E-03 2.9232E-03 116 2.8592E-03 2.3018E-03 2.2591 E-03 2.2534E-03 2.1470E-03 121 7.5659E-04 6.7572E-04 1.0048E-03 1.0111E-03 7.6229E-04 126 7.6015E-04 9.8060E-04 9.5929E-04 4.5869E-04 4.1190E-04 131 2.9932E-04 2.9715E-04 3.8037E-04 3.8675E-04 3.8707E-04 136 3.8920E-04 4.1694E-04 4.1696E-04 3.8971 E-04 4.0033E-04 141 5.6685E-04 5.71 1OE-04 4.6031 E-04 4.5181 E-04 4.5133E-04 146 4.4735E-04 4.0296E-04 6.9204E-04 4.5214E-03 4.5299E-03 151 8.1182E-04 5.2276E-04 4.5652E-04 4.6049E-04 5.7136E-04 156 5.7348E-04 4.9035E-04 4.8397E-04 4.8373E-04 4.8373E-04 161 4.8397E-04 4.9034E-04 5.7331E-04 5.6692E-04 3.9967E-04 166 3.7228E-04 1.8716E-04 4.3797E-04 3.9065E-03 3.9235E-03 171 6.7803E-04 4.3786E-04 5.3928E-04 5.3904E-04 4.2832E-04 176 4.2619E-04 5.0884E-04 5.0245E-04 3.3577E-04 3.2301E-04 181 3.2252E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 186 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 191 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 196 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 201 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 206 3.2251E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 211 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 216 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 221 3.2251 E-04 3.2251E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 226 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 231 3.2251 E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 236 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 241 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 246 3.2251 E-04 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 C-14 Concentrations at time =9.800E+02 ,(Deft =1.OOOE+00)

Node I Concentration (CilcMA3) at nodes 1,1+1,...,1+4 251 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 256 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 261 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 266 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04

271 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 276 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 281 3.2251E-04 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 286 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 291 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 296 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 301 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 306 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 311 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 316 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 321 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 326 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 331 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 336 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251E-04 341 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 346 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 351 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 356 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 361 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 366 3.2251E-04 3.2251E-04 3.2251 E-04 3.2251E-04 3.2251E-04 371 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251E-04 376 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 381 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 3.2251 E-04 386 3.2251 E-04 3.2251 E-04 3.2251E-04 3.2251 E-04 3.2251 E-04 391 3.2251 E-04 3.2251 E-04 3.2249E-04 3.2166E-04 2.9966E-04 396 7.5318E-07 7.5257E-07 7.5227E-07 7.5196E-07 7.5164E-07 401 7.5133E-07 7.5101E-07 7.5068E-07 7.5035E-07 7.5002E-07 406 7.4597E-07 7.4119E-07 7.3587E-07 7.3004E-07 7.2368E-07 411 7.1682E-07 7.0946E-07 7.0162E-07 6.9330E-07 6.8453E-07 416 6.7532E-07 6.7594E-07 6.5629E-07 6.351OE-07 6.1252E-07 421 5.8874E-07 5.6394E-07 5.3832E-07 5.1208E-07 4.8541 E-07 426 4.5850E-07 4.3156E-07 4.0476E-07 3.7826E-07 3.5224E-07 431 3.2682E-07 3.0215E-07 2.7833E-07 2.5546E-07 2.3362E-07 436 2.1287E-07 1.9326E-07 1.7482E-07 1.5756E-07 1.4148E-07 441 1.2659E-07 1.1284E-07 1.0022E-07 8.8689E-08 7.8196E-08 446 6.8691E-08 6.0121E-08 5.2427E-08 4.5550E-08 3.9430E-08 451 3.4006E-08 2.9219E-08 2.5013E-08 2.1332E-08 1.8123E-08 456 1.5336E-08 1.2925E-08 1.0846E-08 9.0591E-09 7.5270E-09 461 6.2156E-09 5.0939E-09 4.1335E-09 3.3086E-09 2.5955E-09 466 1.9725E-09 I A197E-09 9.1824E-10 4.5052E-10 1.1224E-10 H-3 Concentrations at time =1.OOOE+03 ,(Delt =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,Nl+4 Mass In solution = 4.03E-20 Mass sorbed = O.OOE+00 Total Mass = 4.03E-20

1 2.1388E-33 8.5549E-33 1.7109E-32 2.5662E-32 3.4212E-32 6 4.2759E-32 5.1302E-32 5.9840E-32 6.8373E-32 7.6899E-32 11 8.5418E-32 9.3928E-32 1.0243E-31 1.1092E-31 1.1 940E-31 16 1.2787E-31 1.3632E-31 1.4476E-31 1.5318E-31 1.6159E-31 21 1.6997E-31 1.7834E-31 1.8669E-31 1.9501 E-31 2.0331 E-31 26 2.1158E-31 2.1983E-31 2.2804E-31 2.3623E-31 2A438E-31 31 2.5249E-31 2.6057E-31 2.6861 E-31 2.7661 E-31 2.8457E-31 36 2.9248E-31 3.0034E-31 3.0816E-31 3.1592E-31 3.2362E-31 41 3.2746E-31 3.3128E-31 3.3508E-31 3.3887E-31 3.4264E-31 46 3.4640E-31 3.5013E-31 3.5386E-31 3.5756E-31 3.6125E-31 51 3.6155E-31 3.6185E-31 3.6216E-31 3.6247E-31 3.6277E-31 56 3.6308E-31 3.6338E-31 3.6434E-31 2.2897E-25 2.2892E-25 61 2.2887E-25 2.2880E-25 2.2869E-25 2.2856E-25 2.2840E-25 66 2.2821 E-25 2.2800E-25 2.2776E-25 2.2749E-25 2.2720E-25 71 2.2688E-25 2.2653E-25 2.2616E-25 2.2576E-25 2.2534E-25 76 2.2488E-25 2.2441 E-25 2.2390E-25 2.2338E-25 2.2282E-25 81 2.2224E-25 2.2164E-25 2.2101 E-25 2.2036E-25 2.1968E-25 86 2.1898E-25 2.1826E-25 2.1751 E-25 2.1674E-25 2.1594E-25 91 2.1513E-25 2.1429E-25 2.1343E-25 2.1255E-25 2.1164E-25 96 2.1072E-25 2.0977E-25 2.0880E-25 2.0781 E-25 2.0681 E-25 101 2.0578E-25 2.0473E-25 2.0367E-25 2.0259E-25 2.0148E-25 106 2.0036E-25 1.9923E-25 1.9807E-25 1.9690E-25 1.9572E-25 111 1.9451 E-25 1.9329E-25 1.9206E-25 1.9081 E-25 1.8955E-25 116 1.8827E-25 1.8698E-25 1.8568E-25 1.8436E-25 1.8303E-25 121 1.8169E-25 1.8034E-25 1.7898E-25 1.7760E-25 1.7622E-25 126 1.7483E-25 1.7342E-25 1.7201E-25 1.7059E-25 1.6916E-25 131 1.6772E-25 1.6627E-25 1.6482E-25 1.6336E-25 1.6190E-25 136 1.6043E-25 1.5895E-25 1.5747E-25 1.5598E-25 1.5449E-25 141 1.5300E-25 1.5150E-25 1.50OOE-25 1A849E-25 1.4699E-25 146 1.4548E-25 1.4397E-25 1.4246E-25 1.4095E-25 1.3944E-25 151 1.3793E-25 1.3641 E-25 1.3490E-25 1.3339E-25 1.3189E-25 156 1.3038E-25 1.2887E-25 1.2737E-25 1.2587E-25 1.2438E-25 161 1.2288E-25 1.2139E-25 1.1991 E-25 1.1843E-25 1.1695E-25 166 1.1548E-25 1.1401E-25 1.1255E-25 1.1109E-25 1.0964E-25 171 1.0820E-25 1.0676E-25 1.0533E-25 1.0391E-25 1.0249E-25 176 1.0108E-25 9.9683E-26 9.8290E-26 9.6905E-26 9.5528E-26 181 9.4160E-26 9.2801 E-26 9.1450E-26 9.0109E-26 8.8777E-26 186 8.7455E-26 8.6142E-26 8.4840E-26 8.3547E-26 8.2264E-26 191 8.0991 E-26 7.9729E-26 7.8478E-26 7.7237E-26 7.6007E-26 196 7.4788E-26 7.3580E-26 7.2383E-26 7.1197E-26 7.0023E-26 201 6.8860E-26 6.7709E-26 6.6569E-26 6.5441 E-26 6.4324E-26 206 6.3219E-26 6.2127E-26 6.1046E-26 5.9976E-26 5.8919E-26 211 5.7874E-26 5.6841E-26 5.5820E-26 5.4811 E-26 5.3815E-26 216 5.2830E-26 5.1857E-26 5.0897E-26 4.9948E-26 4.9012E-26 221 4.8088E-26 4.7176E-26 4.6276E-26 4.5388E-26 4.4512E-26 226 4.3648E-26 4.2796E-26 4.1956E-26 4.1128E-26 4.0311 E-26 231 3.9507E-26 3.8714E-26 3.7933E-26 3.7163E-26 3.6405E-26 236 3.5659E-26 3.4924E-26 3.4200E-26 3.3488E-26 3.2787E-26

241 3.2097E-26 3.1418E-26 3.0750E-26 3.0093E-26 2.9447E-26 246 2.8811E-26 2.8186E-26 2.7572E-26 2.6968E-26 2.6375E-26 H-3 Concentrations at time =1.OOOE+03 ,(Delt =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 2.5792E-26 2.5219E-26 2.4656E-26 2.4103E-26 2.3560E-26 256 2.3027E-26 2.2503E-26 2.1989E-26 2.1485E-26 2.0990E-26 261 2.0504E-26 2.0027E-26 1.9560E-26 1.9101E-26 1.8651E-26 266 1.8210E-26 1.7777E-26 1.7353E-26 1.6937E-26 1.6530E-26 271 1.6131E-26 1.5740E-26 1.5356E-26 1.4981E-26 1A613E-26 276 1.4253E-26 1.3900E-26 1.3555E-26 1.3217E-26 1.2886E-26 281 1.2562E-26 1.2246E-26 1.1936E-26 1.1632E-26 1.1336E-26 286 1.1045E-26 1.0762E-26 1.0484E-26 1.0213E-26 9.9477E-27 291 9.6884E-27 9.4351 E-27 9.1875E-27 8.9455E-27 8.7092E-27 296 8.4783E-27 8.2527E-27 8.0325E-27 7.8174E-27 7.6073E-27 301 7.4023E-27 7.2021 E-27 7.0067E-27 6.8159E-27 6.6298E-27 306 6.4482E-27 6.2710E-27 6.0981E-27 5.9295E-27 5.7650E-27 311 5.6045E-27 5.4481E-27 5.2955E-27 5.1468E-27 5.0017E-27 316 4.8604E-27 4.7226E-27 4.5882E-27 4.4573E-27 4.3298E-27 321 4.2055E-27 4.0843E-27 3.9663E-27 3.8514E-27 3.7394E-27 326 3.6303E-27 3.5240E-27 3.4205E-27 3.3197E-27 3.2215E-27 331 3.1259E-27 3.0328E-27 2.9422E-27 2.8539E-27 2.7679E-27 336 2.6842E-27 2.6027E-27 2.5234E-27 2.4461 E-27 2.3709E-27 341 2.2977E-27 2.2264E-27 2.1569E-27 2.0893E-27 2.0235E-27 346 1.9594E-27 1.8969E-27 1.8361 E-27 1.7769E-27 1.7192E-27 351 1.6630E-27 1.6082E-27 1.5549E-27 1.5029E-27 I A522E-27 356 1.4028E-27 1.3547E-27 1.3077E-27 1.2619E-27 1.2172E-27 361 1.1736E-27 1.1310E-27 1.0895E-27 1.0489E-27 1.0093E-27 366 9.7053E-28 9.3267E-28 8.9565E-28 8.5943E-28 8.2399E-28 371 7.8929E-28 7.5530E-28 7.2199E-28 6.8934E-28 6.5730E-28 376 6.2586E-28 5.9498E-28 5.6464E-28 5.3481 E-28 5.0545E-28 381 4.7655E-28 4.4808E-28 4.2001 E-28 3.9231 E-28 3.6495E-28 386 3.3792E-28 3.1119E-28 2.8473E-28 2.5852E-28 2.3253E-28 391 2.0673E-28 1.8111 E-28 1.5564E-28 1.3029E-28 1.0505E-28 396 7.9880E-29 7.9605E-29 7.9467E-29 7.9329E-29 7.9192E-29 401 7.9055E-29 7.8918E-29 7.8782E-29 7.8646E-29 7.8510E-29 406 7.6984E-29 7.5414E-29 7.3883E-29 7.2388E-29 7.0931 E-29 411 6.9508E-29 6.8120E-29 6.6764E-29 6.5441E-29 6.4150E-29 416 6.2888E-29 6.2970E-29 6.0531E-29 5.8203E-29 5.5979E-29 421 5.3852E-29 5.1817E-29 4.9868E-29 4.8000E-29 4.6208E-29 426 4.4487E-29 4.2833E-29 4.1241E-29 3.9708E-29 3.8230E-29 431 3.6803E-29 3.5425E-29 3.4092E-29 3.2801 E-29 3.1550E-29 436 3.0335E-29 2.9156E-29 2.8009E-29 2.6892E-29 2.5804E-29 441 2.4741E-29 2.3704E-29 2.2690E-29 2.1697E-29 2.0725E-29 446 1.9771E-29 1.8835E-29 1.7915E-29 1.7010E-29 1.6119E-29 451 1.5241E-29 1.4375E-29 1.3520E-29 1.2676E-29 1.1841E-29

456 1.1014E-29 1.0196E-29 9.3853E-30 8.5809E-30 7.7825E-30 461 6.9895E-30 6.2012E-30 5.4171E-30 4.6367E-30 3.8592E-30 466 3.0844E-30 2.3115E-30 1.5402E-30 7.6983E-31 1.9245E-31 H-3 Material Flux at time =1.OOOE+03 (Delt =1.000E+00)

Node Flux Node Flux Node Flux Node Flux 1 -1.35E-39 2 -1.35E-39 3 -1.35E-39 4 -1.35E-39 5 -1.35E-39 6 -1.35E-39 7 -1.34E-39 8 -1.34E-39 9 -1.34E-39 10 -1.34E-39 11 -1.34E-39 12 -1.34E-39 13 -1.34E-39 14 -1.34E-39 15 -1.33E-39 16 -1.33E-39 17 -1.33E-39 18 -1.33E-39 19 -1.32E-39 20 -1.32E-39 21 -1.32E-39 22 -1.31 E-39 23 -1.31 E-39 24 -1.31 E-39 25 -1.30E-39 26 -1.30E-39 27 -1.29E-39 28 -1.29E-39 29 -1.28E-39 30 -1.28E-39 31 -1.27E-39 32 -1.27E-39 33 -1.26E-39 34 -1.25E-39 35 -1.25E-39 36 -1.24E-39 37 -1.23E-39 38 -1.22E-39 39 -1.21E-39 40 -1.21 E-39 41 -1.20E-39 42 -1.20E-39 43 -1.19E-39 44 -1.19E-39 45 -1.18E-39 46 -1.18E-39 47 -1.17E-39 48 -1.17E-39 49 -1.16E-39 50 -1.16E-39 51 -1.16E-39 52 -1.16E-39 53 -1.16E-39 54 -1.16E-39 55 -1.16E-39 56 -1.16E-39 57 -1.16E-39 58 -1.15E-39 59 4.89E-37 60 1.05E-36 61 1.62E-36 62 2.18E-36 63 2.75E-36 64 3.31 E-36 65 3.87E-36 66 4.43E-36 67 4.99E-36 68 5.55E-36 69 6.10E-36 70 6.66E-36 71 7.21 E-36 72 7.76E-36 73 8.30E-36 74 8.84E-36 75 9.38E-36 76 9.92E-36 77 1.05E-35 78 1.10E-35 79 1.15E-35 80 1.20E-35 81 1.25E-35 82 1.31E-35 83 1.36E-35 84 1.41E-35 85 1.46E-35 86 1.51E-35 87 1.55E-35 88 1.60E-35 89 1.65E-35 90 1.70E-35 91 1.74E-35 92 1.79E-35 93 1.84E-35 94 1.88E-35 95 1.92E-35 96 1.97E-35 97 2.01 E-35 98 2.05E-35 99 2.09E-35 100 2.13E-35 101 2.17E-35 102 2.21 E-35 103 2.25E-35 104 2.29E-35 105 2.33E-35 106 2.36E-35 107 2.40E-35 108 2.43E-35 109 2.47E-35 110 2.50E-35 111 2.53E-35 112 2.56E-35 113 2.60E-35 114 2.62E-35 115 2.65E-35 116 2.68E-35 117 2.71 E-35 118 2.74E-35 119 2.76E-35 120 2.79E-35 121 2.81 E-35 122 2.83E-35 123 2.86E-35 124 2.88E-35 125 2.90E-35 126 2.92E-35 127 2.94E-35 128 2.96E-35 129 2.97E-35 130 2.99E-35 131 3.OOE-35 132 3.02E-35 133 3.03E-35 134 3.05E-35 135 3.06E-35 136 3.07E-35 137 3.08E-35 138 3.09E-35 139 3.10E-35 140 3.11E-35 141 3.11 E-35 142 3.12E-35 143 3.13E-35 144 3.13E-35 145 3.13E-35 146 3.14E-35 147 3.14E-35 148 3.14E-35 149 3.14E-35 150 3.14E-35 151 3.14E-35 152 3.14E-35 153 3.14E-35 154 3.14E-35 155 3.13E-35 156 3.13E-35 157 3.12E-35 158 3.12E-35 159 3.11E-35 160 3.1OE-35 161 3.10E-35 162 3.09E-35 163 3.08E-35 164 3.07E-35

165 3.06E-35 166 3.05E-35 167 3.04E-35 168 3.03E-35 169 3.01E-35 170 3.OOE-35 171 2.99E-35 172 2.97E-35 173 2.96E-35 174 2.94E-35 175 2.93E-35 176 2.91 E-35 177 2.90E-35 178 2.88E-35 179 2.86E-35 180 2.84E-35 181 2.83E-35 182 2.81E-35 183 2.79E-35 184 2.77E-35 185 2.75E-35 186 2.73E-35 187 2.71E-35 188 2.69E-35 189 2.67E-35 190 2.65E-35 191 2.62E-35 192 2.60E-35 193 2.58E-35 194 2.56E-35 195 2.53E-35 196 2.51E-35 197 2.49E-35 198 2.46E-35 199 2.44E-35 200 2.42E-35 201 2.39E-35 202 2.37E-35 203 2.35E-35 204 2.32E-35 205 2.30E-35 206 2.27E-35 207 2.25E-35 208 2.22E-35 209 2.20E-35 210 2.17E-35 211 2.15E-35 212 2.12E-35 213 2.10E-35 214 2.07E-35 215 2.05E-35 216 2.02E-35 217 2.OOE-35 218 1.97E-35 219 1.95E-35 220 1.92E-35 221 1.90E-35 222 1.87E-35 223 1.85E-35 224 1.82E-35 225 1.80E-35 226 1.77E-35 227 1.75E-35 228 1.72E-35 229 1.70E-35 230 1.67E-35 231 1.65E-35 232 1.62E-35 233 1.60E-35 234 1.58E-35 235 1.55E-35 236 1.53E-35 237 1.50E-35 238 1.48E-35 239 1.46E-35 240 1.43E-35 241 1.41E-35 242 1.39E-35 243 1.37E-35 244 1.34E-35 245 1.32E-35 246 1.30E-35 247 1.28E-35 248 1.26E-35 249 1.23E-35 250 1.21E-35 251 1.19E-35 252 1.17E-35 253 1.15E-35 254 1.13E-35 255 1.11E-35 256 1.09E-35 257 1.07E-35 258 1.05E-35 259 1.03E-35 260 1.01E-35 261 9.91 E-36 262 9.72E-36 263 9.54E-36 264 9.35E-36 265 9.17E-36 266 8.99E-36 267 8.82E-36 268 8.64E-36 269 8.47E-36 270 8.30E-36 271 8.13E-36 272 7.97E-36 273 7.80E-36 274 7.64E-36 275 7.49E-36 276 7.33E-36 277 7.18E-36 278 7.03E-36 279 6.88E-36 280 6.73E-36 281 6.59E-36 282 6.44E-36 283 6.30E-36 284 6.17E-36 285 6.03E-36 286 5.90E-36 287 5.77E-36 288 5.64E-36 289 5.51 E-36 290 5.39E-36 291 5.27E-36 292 5.15E-36 293 5.03E-36 294 4.91 E-36 295 4.80E-36 296 4.69E-36 297 4.58E-36 298 4.47E-36 299 4.37E-36 300 4.26E-36 301 4.16E-36 302 4.06E-36 303 3.96E-36 304 3.87E-36 305 3.78E-36 306 3.68E-36 307 3.59E-36 308 3.51 E-36 309 3.42E-36 310 3.33E-36 311 3.25E-36 312 3.17E-36 313 3.09E-36 314 3.01E-36 315 2.94E-36 316 2.86E-36 317 2.79E-36 318 2.72E-36 319 2.65E-36 320 2.58E-36 321 2.52E-36 322 2.45E-36 323 2.39E-36 324 2.33E-36 325 2.27E-36 326 2.21 E-36 327 2.15E-36 328 2.10E-36 329 2.04E-36 330 1.99E-36 331 1.94E-36 332 1.88E-36 333 1.84E-36 334 1.79E-36 335 1.74E-36 336 1.69E-36 337 1.65E-36 338 1.61 E-36 339 1.56E-36 340 1.52E-36 341 1.48E-36 342 1.44E-36 343 1.41 E-36 344 1.37E-36 345 1.33E-36 346 1.30E-36 347 1.26E-36 348 1.23E-36 349 1.20E-36 350 1.17E-36 351 1.14E-36 352 1.IIE-36 353 1.08E-36 354 1.05E-36 355 1.03E-36 356 1.OOE-36 357 9.76E-37 358 9.52E-37 359 9.29E-37 360 9.06E-37 361 8.85E-37 362 8.64E-37 363 8.43E-37 364 8.24E-37

365 8.05E-37 366 7.87E-37 367 7.70E-37 368 7.53E-37 369 7.37E-37 370 7.21 E-37 371 7.07E-37 372 6.92E-37 373 6.79E-37 374 6.66E-37 375 6.54E-37 376 6.42E-37 377 6.31E-37 378 6.20E-37 379 6.10E-37 380 6.01E-37 381 5.92E-37 382 5.84E-37 383 5.76E-37 384 5.69E-37 385 5.62E-37 386 5.56E-37 387 5.50E-37 388 5.45E-37 389 5.40E-37 390 5.36E-37 391 5.33E-37 392 5.29E-37 393 5.27E-37 394 5.25E-37 395 5.23E-37 396 5.22E-37 397 5.21E-37 398 5.20E-37 399 5.19E-37 400 5.18E-37 H-3 Material Flux at time =1.OOOE+03 ,(Deft =1.OOOE+00)

Node Flux Node Flux Node Flux Node Flux 401 5.17E-37 402 5.16E-37 403 5.14E-37 404 5.13E-37 405 5.07E-37 406 4.95E-37 407 4.82E-37 408 4.71 E-37 409 4.59E-37 410 4.48E-37 411 4.37E-37 412 4.27E-37 413 4.17E-37 414 4.07E-37 415 3.97E-37 416 3.93E-37 417 3.84E-37 418 3.67E-37 419 3.50E-37 420 3.35E-37 421 3.20E-37 422 3.07E-37 423 2.94E-37 424 2.82E-37 425 2.71E-37 426 2.61 E-37 427 2.51E-37 428 2.41 E-37 429 2.33E-37 430 2.25E-37 431 2.17E-37 432 2.10E-37 433 2.03E-37 434 1.97E-37 435 1.91 E-37 436 1.86E-37 437 1.81 E-37 438 1.76E-37 439 1.71 E-37 440 1.67E-37 441 1.63E-37 442 1.60E-37 443 1.56E-37 444 1.53E-37 445 1.50E-37 446 1.47E-37 447 1.45E-37 448 1.43E-37 449 1.40E-37 450 1.38E-37 451 1.36E-37 452 1.35E-37 453 1.33E-37 454 1.31 E-37 455 1.30E-37 456 1.29E-37 457 1.28E-37 458 1.27E-37 459 1.26E-37 460 1.25E-37 461 1.24E-37 462 1.23E-37 463 1.23E-37 464 1.22E-37 465 1.22E-37 466 1.22E-37 467 1.21 E-37 468 1.21 E-37 469 1.21 E-37 470 1.21 E-37 C-14 Concentrations at time =1.OOOE+03 ,(Det =1.OOOE+00)

Node I Concentration (CVcmA3) at nodes 1,1+1,...,1+4 Mass in solution = 2.02E+04 Mass sorbed = O.OOE+00 Total Mass = 2.02E+04 1 7.7214E-14 3.1037E-13 6.3750E-13 9.9783E-13 1.4096E-12

6 1.8933E-12 2.4721 E-12 3.1730E-12 4.0276E-12 5.0736E-12 11 6.3553E-12 7.9257E-12 9.8480E-12 1.2197E-1 1 1.5062E-1 I 16 1.8549E-1 1 2.2782E-1 1 2.791 OE-11 3.4106E-1 1 4.1573E-1 I 21 5.0551 E-11 6.1318E-11 7.4200E-1 I 8.9573E-1 1 1.0788E-10 26 1.2961E-10 1.5537E-10 1.8581 E-10 2.2170E-1 0 2.6392E-10 31 3.1348E-10 3.7151 E-10 4.3930E-10 5.1832E-10 6.1021E-10 36 7.1685E-10 8.4031 E-10 9.8296E-10 1.1474E-09 1.3366E-09 41 1.4419E-09 1.5544E-09 1.6749E-09 1.8037E-09 1.9414E-09 46 2.0886E-09 2.2457E-09 2.4135E-09 2.5925E-09 2.7834E-09 51 2.7995E-09 2.8161E-09 2.8327E-09 2.8495E-09 2.8663E-09 56 2.8832E-09 2.9002E-09 2.9536E-09 1.2915E-03 5.4699E-02 61 7.0999E-01 7.6270E-01 7.8442E-01 7.8739E-01 8.0537E-01 66 8.1209E-01 8.8036E-01 8.8172E-01 8.3036E-01 8.0315E-01 71 5.0444E-01 4.7033E-01 3.3034E-Oi 3.1630E-01 2.7521 E-01 76 2.7264E-01 2.8041 E-01 2.7753E-01 2.3257E-01 2.2547E-01 81 1.7900E-01 1.7291 E-01 1.4090E-01 1.3761 E-01 1.2722E-01 86 1.2492E-01 1.0573E-01 1.0271 E-01 8.2959E-02 8.0494E-02 91 6.8484E-02 6.6344E-02 5.0774E-02 4.8743E-02 3.8172E-02 96 3.7242E-02 3.5811 E-02 3.5313E-02 3.0304E-02 2.9375E-02 101 2.2409E-02 2.1091 E-02 1.1 104E-02 1.0304E-02 9.9937E-03 106 9.8848E-03 8.7733E-03 8.6004E-03 7.4838E-03 7.2460E-03 111 5.2999E-03 5.0191 E-03 3.3514E-03 3.2000E-03 2.9164E-03 116 2.8515E-03 2.2971 E-03 2.2537E-03 2.2478E-03 2.1399E-03 121 7.5680E-04 6.7473E-04 1.0019E-03 1.0083E-03 7.6084E-04 126 7.5866E-04 9.7785E-04 9.5623E-04 4.5829E-04 4.1080E-04 131 2.9877E-04 2.9657E-04 3.7933E-04 3.8580E-04 3.8614E-04 136 3.8830E-04 4.1589E-04 4.1591 E-04 3.8882E-04 3.9961 E-04 141 5.6523E-04 5.6954E-04 4.5936E-04 4.5073E-04 4.5023E-04 146 4.4621E-04 4.0251E-04 6.9588E-04 4.5045E-03 4.5131 E-03 151 8.1520E-04 5.2185E-04 4.5553E-04 4.5954E-04 5.6981 E-04 156 5.7196E-04 4.8928E-04 4.8281 E-04 4.8256E-04 4.8256E-04 161 4.8281E-04 4.8928E-04 5.7179E-04 5.6530E-04 3.9892E-04 166 3.7114E-04 1.8739E-04 4.4192E-04 3.8917E-03 3.9090E-03 171 6.8108E-04 4.3734E-04 5.3782E-04 5.3757E-04 4.2746E-04 176 4.2529E-04 5.0747E-04 5.0099E-04 3.3520E-04 3.2225E-04 181 3.2175E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 186 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 191 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 196 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 201 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 206 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 211 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 216 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 221 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 226 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 231 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 236 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 241 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 246 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04

C-14 Concentrations at time =1.0OOE+03 ,(Deft =1.OOOE+00)

Node I Concentration (Ci/cmA3) at nodes 1,1+1,...,1+4 251 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 256 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 261 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 266 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 271 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 276 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 281 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 286 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 291 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 296 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 301 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 306 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 311 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 316 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 321 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 326 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 331 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 336 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 341 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 346 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 351 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 356 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 361 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 366 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 371 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 376 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 381 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 386 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 3.2173E-04 391 3.2173E-04 3.2173E-04 3.2171E-04 3.2085E-04 2.9850E-04 396 7.4564E-07 7.4504E-07 7.4473E-07 7.4442E-07 7.4411 E-07 401 7.4380E-07 7A348E-07 7A315E-07 7A283E-07 7.4250E-07 406 7.3849E-07 7.3376E-07 7.2852E-07 7.2277E-07 7.1653E-07 411 7.0979E-07 7.0258E-07 6.9489E-07 6.8675E-07 6.7817E-07 416 6.6916E-07 6.6977E-07 6.5057E-07 6.2986E-07 6.0781E-07 421 5.8459E-07 5.6036E-07 5.3533E-07 5.0967E-07 4.8359E-07 426 4.5725E-07 4.3086E-07 4.0457E-07 3.7856E-07 3.5299E-07 431 3.2798E-07 3.0367E-07 2.8017E-07 2.5757E-07 2.3595E-07 436 2.1538E-07 1.9591 E-07 1.7755E-07 1.6034E-07 1.4429E-07 441 1.2937E-07 1.1559E-07 1.0290E-07 9.1273E-08 8.0672E-08 446 7.1046E-08 6.2344E-08 5.4511E-08 4.7491E-08 4.1226E-08 451 3.5657E-08 3.0729E-08 2.6385E-08 2.2571E-08 1.9235E-08 456 1.6329E-08 1.3806E-08 1.1623E-08 9.7396E-09 8.1184E-09 461 6.7251 E-09 5.5284E-09 4.4992E-09 3.6111 E-09 2.8399E-09 466 2.1629E-09 1.5594E-09 1.0100E-09 4.9594E-10 1.2357E-10

C-14 Material Flux at time =1.OOOE+03 ,(Delt =1.OOOE+0O)

Node Flux Node Flux Node Flux Node Flux I -4.90E-21 2 -5.15E-21 3 -5.67E-21 4 -6.49E-21 5 -7.62E-21 6 -9.11E-21 7 -1.10E-20 8 -1.35E-20 9 -1.65E-20 10 -2.02E-20 11 -2.47E-20 12 -3.03E-20 13 -3.70E-20 14 -4.51E-20 15 -5.49E-20 16 -6.67E-20 17 -8.07E-20 18 -9.76E-20 19 -1.18E-19 20 -1.A1E-19 21 -1.70E-19 22 -2.03E-19 23 -2.42E-19 24 -2.88E-19 25 -3.42E-19 26 -4.06E-19 27 -4.79E-19 28 -5.65E-19 29 -6.65E-19 30 -7.80E-19 31 -9.14E-19 32 -1.07E-18 33 -1.24E-18 34 -1.45E-18 35 -1.68E-18 36 -1.94E-18 37 -2.25E-18 38 -2.59E-18 39 -2.98E-18 40 -3.31 E-18 41 -3.54E-18 42 -3.79E-18 43 -4.06E-18 44 -4.34E-18 45 -4.64E-18 46 -4.95E-18 47 -5.28E-18 48 -5.64E-18 49 -6.01E-18 50 -6.23E-18 51 -6.26E-18 52 -6.29E-18 53 -6.33E-18 54 -6.36E-18 55 -6.39E-18 56 -6.43E-18 57 -6.47E-18 58 -6.51E-18 59 -1.04E-14 60 -2.48E-13 61 -1.99E-14 62 -8.21 E-15 63 -1.12E-15 64 -6.80E-15 65 -2.54E-15 66 -2.58E-14 67 -5.14E-16 68 1.94E-14 69 1.03E-14 70 1.13E-13 71 1.29E-14 72 5.29E-14 73 5.31E-15 74 1.55E-14 75 9.69E-16 76 -2.94E-15 77 1.09E-1 5 78 1.70E-14 79 2.69E-15 80 1.76E-14 81 2.30E-15 82 1.21E-14 83 1.24E-15 84 3.93E-15 85 8.67E-16 86 7.25E-15 87 1.14E-15 88 7.46E-15 89 9.31 E-16 90 4.54E-15 91 8.09E-16 92 5.88E-15 93 7.68E-16 94 4.00E-15 95 3.52E-16 96 5.41 E-16 97 1.88E-16 98 1.89E-15 99 3.51E-16 100 2.63E-15 101 4.98E-16 102 3.77E-15 103 3.02E-16 104 1.17E-16 105 4.11E-17 106 4.20E-16 107 6.54E-17 108 4.22E-16 109 8.99E-17 110 7.36E-16 111 1.06E-16 112 6.30E-16 113 5.72E-17 114 1.07E-16 115 2.45E-17 116 2.10E-16 117 1.64E-17 118 2.23E-18 119 4.08E-17 120 5.23E-16 121 3.10E-17 122 -1.24E-16 123 -2.41 E-18 124 9.35E-17 125 8.21 E-19 126 -8.28E-17 127 8.17E-18 128 1.88E-16 129 1.79E-17 130 4.23E-17 131 8.31E-19 132 -3.13E-17 133 -2.45E-18 134 -1.28E-19 135 -8.18E-19 136 -1.04E-17 137 -5.OOE-21 138 1.02E-17 139 -4.08E-18 140 -6.26E-17 141 -1.63E-18 142 4.16E-17 143 3.26E-18 144 1.89E-19 145 1.52E-18 146 1.65E-17 147 -1.IIE-16 148 -1.44E-15 149 -3.26E-18 150 1AOE-15 151 1.11E-16 152 2.51E-17 153 -1.52E-18 154 -4.17E-17 155 -8.14E-19 156 3.13E-17 157 2.44E-18 158 9.56E-20 159 5.14E-25 160 -9.56E-20 161 -2.44E-18 162 -3.12E-17 163 2.45E-18 164 6.29E-17 165 1.05E-17 166 6.94E-17 167 -9.62E-17 168 -1.30E-15 169 -6.53E-18 170 1.22E-15 171 9.21E-17 172 -3.80E-17 173 9.50E-20 174 4.16E-17 175 8.18E-19 176 -3.11E-17

177 2.45E-18 178 6.27E-17 179 4.89E-18 180 1.91E-19 181 5.OOE-21 182 9.81E-23 183 1.54E-24 184 2.02E-26 185 2.28E-28 186 1.44E-30 187 2.28E-32 188 -9.13E-32 189 -3.88E-31 190 -2.10E-29 191 4.57E-32 192 2.10E-29 193 4.11E-31 194 O.OOE+00 195 O.OOE+00 196 O.OOE+00 197 O.OOE+00 198 O.OOE+00 199 O.OOE+00 200 -9.13E-32 201 -3.88E-31 202 -2.10E-29 203 4.57E-32 204 2.1OE-29 205 4.1 1E-31 206 O.OOE+00 207 O.OOE+00 208 O.OOE+00 209 O.OOE+00 210 O.OOE+0O 211 O.OOE+00 212 O.OOE+00 213 -9.13E-32 214 -3.88E-31 215 -2.10E-29 216 4.57E-32 217 2.10E-29 218 4.11E-31 219 O.OOE+00 220 O.OOE+00 221 O.OOE+00 222 O.OOE+00 223 O.OOE+00 224 O.OOE+00 225 -9.13E-32 226 -3.88E-31 227 -2.10E-29 228 4.57E-32 229 2.10E-29 230 4.11 E-31 231 O.OOE+00 232 O.OOE+00 233 O.OOE+00 234 O.OOE+00 235 O.OOE+00 236 O.OOE+00 237 O.OOE+00 238 -9.13E-32 239 -3.88E-31 240 -2.1OE-29 241 4.57E-32 242 2.10E-29 243 4.11E-31 244 O.OOE+00 245 O.OOE+00 246 O.OOE+00 247 O.OOE+O0 248 O.OOE+O0 249 O.OOE+00 250 -9.13E-32 251 -3.88E-31 252 -2.10E-29 253 4.57E-32 254 2.10E-29 255 4.1 1E-31 256 O.OOE+00 257 O.OOE+00 258 O.OOE+00 259 O.OOE+O0 260 O.OOE+00 261 O.OOE+00 262 O.OOE+00 263 -9.13E-32 264 -3.88E-31 265 -2.10E-29 266 4.57E-32 267 2.10E-29 268 4.11 E-31 269 O.OOE+00 270 O.OOE+00 271 O.OOE+00 272 O.OOE+00 273 O.OOE+00 274 O.OOE+00 275 -9.13E-32 276 -3.88E-31 277 -2.10E-29 278 4.57E-32 279 2.10E-29 280 4.11E-31 281 O.OOE+00 282 O.OOE+00 283 O.OOE+00 284 O.OOE+00 285 O.OOE+00 286 O.OOE+00 287 O.OOE+00 288 -9.13E-32 289 -3.88E-31 290 -2.10E-29 291 4.57E-32 292 2.1OE-29 293 4.11E-31 294 O.OOE+00 295 O.OOE+00 296 O.OOE+00 297 O.OOE+00 298 O.OOE+00 299 O.OOE+O0 300 -9.13E-32 301 -3.88E-31 302 -2.10E-29 303 4.57E-32 304 2.10E-29 305 4.11E-31 306 O.OOE+00 307 O.OOE+00 308 O.OOE+00 309 O.OOE+00 310 O.OOE+00 311 O.OOE+00 312 -9.13E-32 313 -3.88E-31 314 -2.10E-29 315 4.57E-32 316 2.10E-29 317 4.11E-31 318 O.OOE+00 319 O.OOE+00 320 O.OOE+00 321 O.OOE+00 322 O.OOE+00 323 O.OOE+00 324 O.OOE+00 325 -9.13E-32 326 -3.88E-31 327 -2.10E-29 328 4.57E-32 329 2.10E-29 330 4.11E-31 331 O.OOE+00 332 O.OOE+00 333 O.OOE+00 334 O.OOE+00 335 O.OOE+00 336 O.OOE+00 337 -9.13E-32 338 -3.88E-31 339 -2.1OE-29 340 4.57E-32 341 2.10E-29 342 4.11E-31 343 O.OOE+0O 344 O.OOE+00 345 O.OOE+00 346 O.OOE+00 347 O.OOE+00 348 O.OOE+00 349 O.OOE+00 350 -9.13E-32 351 -3.88E-31 352 -2.10E-29 353 4.57E-32 354 2.10E-29 355 4.11 E-31 356 O.OOE+00 357 O.OOE+00 358 O.OOE+00 359 O.OOE+00 360 O.OOE+00 361 O.OOE+00 362 -9.13E-32 363 -3.88E-31 364 -2.10E-29 365 4.57E-32 366 2.1OE-29 367 4.11E-31 368 O.OOE+00 369 O.OOE+00 370 O.OOE+00 371 O.OOE+00 372 O.OOE+00 373 O.OOE+00 374 O.OOE+00 375 -9.13E-32 376 -3.88E-31

377 -2.10E-29 378 4.57E-32 379 2.1OE-29 380 4.11 E-31 381 O.OOE+00 382 O.OOE+0O 383 O.OOE+00 384 O.OOE+00 385 O.OOE+00 386 4.11E-31 387 3.81E-30 388 3.78E-28 389 3.37E-26 390 2.58E-24 391 1.65E-22 392 8.45E-21 393 3.26E-19 394 8A5E-18 395 1.13E-16 396 1.14E-16 397 1.15E-16 398 1.17E-16 399 1.18E-16 400 1.19E-16 C-14 Material Flux at time =1.000E+03 ,(Delt =1.000E+0O)

Node Flux Node Flux Node Flux Node Flux 401 1.21E-16 402 1.22E-16 403 1.23E-16 404 1.25E-16 405 1.33E-16 406 1.49E-16 407 1.65E-16 408 1.81E-16 409 1.97E-16 410 2.12E-16 411 2.27E-16 412 2.42E-16 413 2.56E-16 414 2.70E-16 415 2.84E-16 416 2.90E-16 417 3.02E-16 418 3.26E-16 419 3.47E-16 420 3.66E-16 421 3.81E-16 422 3.94E-16 423 4.04E-16 424 4.11E-16 425 4.15E-16 426 4.16E-16 427 4.14E-16 428 4.1OE-16 429 4.03E-16 430 3.94E-16 431 3.83E-16 432 3.70E-16 433 3.56E-16 434 3.40E-16 435 3.24E-16 436 3.07E-16 437 2.89E-16 438 2.71 E-16 439 2.53E-16 440 2.35E-16 441 2.17E-16 442 2.OOE-16 443 1.83E-16 444 1.67E-16 445 1.52E-16 446 1.37E-16 447 1.23E-16 448 1.11E-16 449 9.87E-17 450 8.77E-17 451 7.76E-17 452 6.84E-17 453 6.01 E-17 454 5.25E-17 455 4.58E-17 456 3.97E-17 457 3.44E-17 458 2.97E-17 459 2.55E-17 460 2.19E-17 461 1.88E-17 462 1.62E-17 463 1.40E-17 464 1.21E-17 465 1.07E-17 466 9.50E-18 467 8.65E-18 468 8.10E-18 469 7.82E-18 470 7.82E-18

BNL Report H-3 Spreadsheets

Maine Yen kee Max diffusion D=1E-6 ISOTOPE H-3 Total Mass In the System 2.28E+04 Liner In NODE 60 60 60 397 397 397 60 60 397 397 Solution DISTANCE 6.77E+02 6.77E+02 6.77E+02 8.91E+02 8.91E+02 8.91E+02 Norm cum Norm rel Norm cum Norm rel Liner side Away from liner TIME-YRS Flux Mass Mass Rat e Flux Mass Mass Rate Release rate Release rate rate rate 1.OOE+00 -9.03E-08 -6.66E-04 -9.03E-04 5.88E-05 1.38E+00 5.88E-01 2.92E-08 2.92E-08 6.05E-05 6.05E-05 2.92E-08 6.052-05 2.00E+00 -1.01 E-07 -1.64E-03 -1.01 E-03 3.88E-05 1.84E+00 3.88E-01 7.19E-08 4.20E-08 8.07E-05 2.14E-05 6.96E-08 1.38E-04 3.00E+00 -1.00E-07 -2.65E-03 -1.00E-03 2.98E-05 2.17E+00 2.98E-01 1.16E-07 4.41 E-08 9.52E-05 1.50E-05 1.10E-07 2.26E-04 4.00E+00 -9.61 E-08 -3.63E-03 -9.61 E-04 2.43E-05 2.44E+00 2.43E-01 1.59E-07 4.30E-08 1.07E-04 1.19E-05 1.47E-07 3.20E-04 5.OOE+00 -9.09E-08 -4.56E-03 -9.09E-04 2.06E-05 2.66E+00 2.06E-01 2.00E-07 4.10E-08 1.17E-04 9.85E-06 1.80E-07 4.19E-04 6.OOE+00 -8.54E-08 -5.44E-03 -8.54E-04 1.77E-05 2.85E+00 1.77E-01 2.39E-07 3.87E-08 1.25E-04 8.40E-06 2.09E-07 5.21 E-04 7.00E+00 -7.99E-08 -6.26E-03 -7.99E-04 1.55E-05 3.01 E+00 1.55E-01 2.75E-07 3.63E-08 1.32E-04 7.28E-06 2.34E-07 6.25E-04 8.OOE+00 -7.46E-08 -7.03E-03 -7.46E-04 1.37E-05 3.16E+00 1.37E-01 3.08E-07 3.39E-08 1.39E-04 6.40E-06 2.55E-07 7.29E-04 9.OOE+00 -6.96E-08 -7.75E-03 -6.96E-04 1.22E-05 3.29E+00 1.22E-01 3.40E-07 3.16E-08 1.44E-04 5.68E-06 2.72E-07 8.34E-04 1.00E+01 -6.48E-08 -8.42E-03 -6.48E-04 1.09E-05 3.40E+00 1.09E-01 3.69E-07 2.95E-08 1.49E-04 5.07E-06 2.87E-07 9.37E-04 1.10E+01 -6.04E-08 -9.04E-03 -6.04E-04 9.87E-06 3.51 E+00 9.87E-02 3.96E-07 2.75E-08 1.54E-04 4.55E-06 2.99E-07 1.04E-03 1.20E+01 -5.63E-08 -9.63E-03 -5.63E-04 8.93E-06 3.60E+00 8.93E-02 4.22E-07 2.56E-08 1.58E-04 4.12E-06 3.08E-07 1.14E-03 1.30E+01 -5.25E-08 -1.02E-02 -5.25E-04 8.11E-06 3.68E+00 8.11 E-02 4.47E-07 2.39E-08 1.61 E-04 3.74E-06 3.15E-07 1.24E-03 1.40E+01 -4.89E-08 -1.07E-02 -4.89E-04 7.39E-06 3.76E+00 7.39E-02 4.69E-07 2.22E-08 1.65E-04 3.40E-06 3.20E-07 1.34E-03 1.50E+01 -4.56E-08 -1.11E-02 -4.56E-04 6.75E-06 3.83E+00 6.75E-02 4.87E-07 2.07E-08 1.68E-04 3.102-06 3.23E-07 1.43E-03 1.60E+01 -4.25E-08 -1.16E-02 -4.25E-04 6.18E-06 3.89E+00 6.18E-02 5.09E-07 1.93E-08 1.71 E-04 2.84E-06 3.25E-07 1.52E-03 1.70E+01 -3.97E-08 -1.20E-02 -3.97E-04 5.67E-06 3.95E+00 5.67E-02 5.26E-07 1.80E-08 1.73E-04 2.60E-06 3.25E-07 1.61 E-03 1.80E+01 -3.70E-08 -1.24E-02 -3.70E-04 5.20E-06 4.01 E+00 5.202-02 5.44E-07 1.68E-08 1.76E-04 2.38E-06 3.24E-07 1.70E-03 1.90E+01 -3.46E-08 -1.27E-02 -3.46E-04 4.79E-06 4.06E+00 4.79E-02 5.57E-07 1.57E-08 1.78E-04 2.19E-06 3.22E-07 1.79E-03 2.OOE+01 -3.23E-08 -1.31 E-02 -3.23E-04 4.41 E-06 4.10E+00 4.41 E-02 5.75E-07 1.47E-08 1.80E-04 2.02E-06 3.19E-07 1.87E-03 2.10E2+01 -3.02E-08 -1.34E-02 -3.02E-04 4.07E-06 4.15E+00 4.07E-02 5.88E-07 1.37E-08 1.82E-04 1.86E-06 3.16E-07 1.95E-03 2.20E+01 -2.82E-08 -1.37E-02 -2.82E-04 3.76E-06 4.18E+00 3.76E-02 6.01 E-07 1.28E-08 1.83E-04 1.72E-06 3.11 E-07 2.03E-03 2.30E+01 -2.63E-08 -1.39E-02 -2.63E-04 3.48E-06 4.22E+00 3.48E-02 6.10E-07 1.20E-08 1.85E-04 1.59E-06 3.06E-07 2.10E-03 2.40E+01 -2.46E-08 -1.42E-02 -2.46E-04 3.22E-06 4.25E+00 3.22E-02 6.23E-07 1.12E-08 1.86E-04 1.47E-06 3.00E-07 2.17E-03 2.50E+01 -2.30E-08 -1.44E-02 -2.30E-04 2.98E-06 4.28E+00 2.98E-02 6.32E-07 1.04E-08 1.88E-04 1.36E-06 2.94E-07 2.24E-03 2.60E+01 -2.15E-08 -1.46E-02 -2.15E-04 2.76E-06 4.31 E+00 2.76E-02 6.40E-07 9.76E-09 1.89E-04 1.26E-06 2.88E-07 2.31 E-03 2.70E+01 -2.01 E-08 -1.49E-02 -2.01E-04 2.56E-06 4.34E+00 2.56E-02 6.54E-07 9.12E-09 1.90E-04 1.17E-06 2.82E-07 2.37E-03 2.80E+01 -1.88E-08 -1.51E-02 -1.88E-04 2.38E-06 4.36E+00 2.38E-02 6.62E-07 8.53E-09 1.91 E-04 1.08E-06 2.75E-07 2.43E-03 2.902+01 -1.76E-08 -1.52E-02 -1.76E-04 2.21 E-06 4.39E+00 2.21 E-02 6.67E-07 7.98E-09 1.93E-04 1.01 E-06 2.68E-07 2.49E-03 3.00E+01 -1.65E-08 -1.54E-02 -1.65E-04 2.06E-06 4.41 E+00 2.06E-02 6.75E-07 7.48E-09 1.93E-04 9.36E-07 2.60E-07 2.55E-03 3.102+01 -1.55E-08 -1.56E-02 -1.55E-04 1.91 E-06 4.43E+00 1.91 E-02 6.84E-07 7.02E-09 1.94E-04 8.71 E-07 2.53E-07 2.61E-03

3.20E+01 -1.45E-08 -1.57E-02 -1.45E-04 1.78E-06 4.45E+00 1.78E-02 6.89E-07 6.58E-09 1.95E-04 8.09E-07 2.46E-07 2.66E-03 3.30E+01 -1.36E-08 -1.59E-02 -1.36E-04 1.66E-06 4.46E+00 1.66E-02 6.97E-07 6.16E-09 1.96E-04 7.54E-07 2.39E-07 2.71 E-03 3.40E+01 -1.27E-08 -1.60E-02 -1.27E-04 1.54E-06 4.48E+00 1.54E-02 7.02E-07 5.77E-09 1.96E-04 7.02E-07 2.31 E-07 2.76E-03 3.50E+01 -1.19E-08 -1.61E-02 -1.19E-04 1.44E-06 4.49E+00 1.44E-02 7.06E-07 5.39E-09 1.97E-04 6.54E-07 2.24E-07 2.80E-03 3.60E+01 -1.12E-08 -1.62E-02 -1.12E-04 1.34E-06 4.51E+00 1.34E-02 7.11 E-07 5.07E-09 1.98E-04 6.1 OE-07 2.17E-07 2.85E-03 3.70E+01 -1.05E-08 -1.63E-02 -1.05E-04 1.25E-06 4.52E+00 1.25E-02 7.15E-07 4.76E-09 1.98E-04 5.68E-07 2.1 OE-07 2.89E-03 3.80E+01 -9.80E-09 -1.64E-02 -9.80E-05 1.17E-06 4.53E+00 1.17E-02 7.19E-07 4.45E-09 1.99E-04 5.31 E-07 2.03E-07 2.93E-03 3.90E+01 -9.19E-09 -1.65E-02 -9.19E-05 1.09E-06 4.54E+00 1.09E-02 7.24E-07 4.16E-09 1.99E-04 4.96E-07 1.96E-07 2.97E-03 4.OOE+01 -8.62E-09 -1.66E-02 -8.62E-05 1.02E-06 4.56E+00 1.02E-02 7.28E-07 3.91 E-09 2.00E-04 4.63E-07 1.89E-07 3.01 E-03 4.10E+01 -8.08E-09 -1.67E-02 -8.08E-05 9.49E-07 4.57E+00 9.49E-03 7.32E-07 3.66E-09 2.00E-04 4.32E-07 1.82E-07 3.04E-03 4.20E+01 -7.58E-09 -1.68E-02 -7.58E-05 8.87E-07 4.57E+00 8.87E-03 7.37E-07 3.43E-09 2.00E-04 4.03E-07 1.76E-07 3.08E-03 4.30E+01 -7.11E-09 -1.68E-02 -7.11E-05 8.28E-07 4.58E+00 8.28E-03 7.37E-07 3.22E-09 2.01 E-04 3.76E-07 1.70E-07 3.11E-03 4.40E+01 -6.67E-09 -1.69E-02 -6.67E-05 7.74E-07 4.59E+00 7.74E-03 7.41 E-07 3.02E-09 2.01 E-04 3.51 E-07 1.63E-07 3.14E-03 4.50E+01 -6.26E-09 -1.70E-02 -6.26E-05 7.24E-07 4.60E+00 7.24E-03 7.46E-07 2.84E-09 2.02E-04 3.29E-07 1.57E-07 3.17E-03 4.60E+01 -5.88E-09 -1.70E-02 -5.88E-05 6.77E-07 4.61 E+00 6.77E-03 7.46E-07 2.66E-09 2.02E-04 3.07E-07 1.51 E-07 3.20E-03 4.70E+01 -5.52E-09 -1.71 E-02 -5.52E-05 6.33E-07 4.61 E+00 6.33E-03 7.50E-07 2.50E-09 2.02E-04 2.87E-07 1.46E-07 3.23E-03 4.80E+01 -5.18E-09 -1.71E-02 -5.18E-05 5.92E-07 4.62E+00 5.92E-03 7.50E-07 2.35E-09 2.03E-04 2.69E-07 1.40E-07 3.25E-03 4.90E+01 -4.86E-09 -1.72E-02 -4.86E-05 5.54E-07 4.62E+00 5.54E-03 7.54E-07 2.20E-09 2.03E-04 2.51 E-07 1.34E-07 3.28E-03 5.00E+01 -4.56E-09 -1.72E-02 -4.56E-05 5.19E-07 4.63E+00 5.19E-03 7.54E-07 2.07E-09 2.03E-04 2.35E-07 1.29E-07 3.30E-03 5.10E+01 -4.63E-03 -1.40E+02 -4.63E+01 4.86E-07 4.63E+00 4.86E-03 6.14E-03 6.14E-03 2.03E-04 2.20E-07 6.14E-03 3.33E-03 5.20E+01 -2.97E-03 -1.75E+02 -2.97E+01 4.55E-07 4.64E+00 4.55E-03 7.68E-03 1.67E-03 2.04E-04 2.06E-07 7.47E-03 3.35E-03 5.30E+01 -2.24E-03 -2.01 E+02 -2.24E+01 4.26E-07 4.64E+00 4.26E-03 8.82E-03 1.14E-03 2.04E-04 1.93E-07 8.21 E-03 3.37E-03 5.40E+01 -1.80E-03 -2.20E+02 -1.80E+01 3.99E-07 4.65E+00 3.99E-03 9.65E-03 8.86E-04 2.04E-04 1.81 E-07 8.64E-03 3.39E-03 5.50E+01 -1.50E-03 -2.37E+02 -1.50E+01 3.74E-07 4.65E+00 3.74E-03 1.04E-02 7.24E-04 2.04E-04 1.70E-07 8.89E-03 3.41 E-03 5.60E+01 -1.27E-03 -2.50E+02 -1.27E+01 3.50E-07 4.65E+00 3.50E-03 1.10E-02 6.07E-04 2.04E-04 1.59E-07 9.02E-03 3.42E-03 5.70E+01 -1.10E-03 -2.62E+02 -1.10E+01 3.28E-07 4.66E+00 3.28E-03 1.15E-02 5.20E-04 2.04E-04 1.49E-07 9.04E-03 3.44E-03 5.80E+01 -9.57E-04 -2.72E+02 -9.57E+00 3.08E-07 4.66E+00 3.08E-03 1.19E-02 4.51 E-04 2.04E-04 1.39E-07 9.00E-03 3.46E-03 5.90E+01 -8.41 E-04 -2.81E+02 -8.41E+00 2.88E-07 4.66E+00 2.88E-03 1.23E-02 3.94E-04 2.04E-04 1.31 E-07 8.90E-03 3.47E-03 6.00E+01 -7.44E-04 -2.89E+02 -7.44E+OO 2.70E-07 4.67E+00 2.70E-03 1.27E-02 3.48E-04 2.05E-04 1.22E-07 8.76E-03 3.49E-03 6.10E+01 -6.62E-04 -2.96E+02 -6.62E+00 2.53E-07 4.67E+00 2.53E-03 1.30E-02 3.08E-04 2.05E-04 1.15E-07 8.59E-03 3.50E-03 6.20E+01 -5.91 E-04 -3.02E+02 -5.91 E+00 2.38E-07 4.67E+00 2.38E-03 1.32E-02 2.75E-04 2.05E-04 1.08E-07 8.40E-03 3.52E-03 6.30E+01 -5.30E-04 -3.08E+02 -5.30E+00 2.23E-07 4.67E+00 2.23E-03 1.35E-02 2.46E-04 2.05E-04 1.01 E-07 8.18E-03 3.53E-03 6.40E+01 -4.77E-04 -3.13E+02 -4.77E+00 2.09E-07 4.68E+00 2.09E-03 1.37E-02 2.21 E-04 2.05E-04 9.47E-08 7.96E-03 3.54E-03 6.50E+01 -4.30E-04 -3.17E+02 -4.30E+O0 1.96E-07 4.68E+00 1.96E-03 1.39E-02 1.99E-04 2.05E-04 8.88E-08 7.72E-03 3.55E-03 6.60E+01 -3.89E-04 -3.21 E+02 -3.89E+00 1.84E-07 4.68E+00 1.84E-03 1.41 E-02 1.80E-04 2.05E-04 8.33E-08 7.48E-03 3.56E-03 6.70E+01 -3.53E-04 -3.25E+02 -3.53E+00 1.73E-07 4.68E+00 1.73E-03 1.43E-02 1.63E-04 2.05E-04 7.83E-08 7.23E-03 3.57E-03 6.80E+01 -3.20E-04 -3.28E+02 -3.20E+00 1.62E-07 4.68E+00 1.62E-03 1.44E-02 1.48E-04 2.05E-04 7.35E-08 6.99E-03 3.58E-03 6.90E+01 -2.91 E-04 -3.32E+02 -2.91 E+00 1.52E-07 4.69E+00 1.52E-03 1.46E-02 1.34E-04 2.06E-04 6.89E-08 6.74E-03 3.59E-03

7.00E+01 -2.65E-04 -3.34E+02 -2.65E+OO 1.43E-07 4.69E+00 1.43E-03 1.46E-02 1.22E-04 2.06E-04 6.47E-08 6.49E-03 3.60E-03 7.10OE+01 -2.42E-04 -3.37E+02 -2.42E+OO 1.34E-07 4.69E+00 1.34E-03 1.48E-02 1.11 E-04 2.06E-04 6.07E-08 6.25E-03 3.61 E-03 7.20E+01 -2.21 E-04 -3.39E+02 -2.21 E+OO 1.26E-07 4.69E+00 1.26E-03 1.49E-02 1.02E-04 2.06E-04 5.70E-08 6.01 E-03 3.62E-03 7.30E+01 -2.02E-04 -3.41 E+02 -2.02E+OO 1.18E-07 4.69E+00 1.18E-03 1.50E-02 9.28E-05 2.06E-04 5.35E-08 5.77E-03 3.63E-03 7.40E+01 -1.85E-04 -3.43E+02 -1.85E+OO 1.11 E-07 4.69E+00 1.11E-03 1.50E-02 8.49E-05 2,06E-04 5.02E-08 5.54E-03 3.64E-03 7.50E+01 -1.70E-04 -3.45E+02 -1.70E+OO 1.04E-07 4.69E+00 1.04E-03 1.51 E-02 7.79E-05 2.06E-04 4.71 E-08 5.32E-03 3.64E-03 7.60E+01 -1.56E-04 -3.47E+02 -1.56E+OO 9.79E-08 4.69E+00 9.79E-04 1.52E-02 7.15E-05 2.06E-04 4.43E-08 5.1 OE-03 3.65E-03 7.70E+01 -1.43E-04 -3.48E+02 -1.43E+OO 9.20E-08 4.69E+00 9.20E-04 1,53E-02 6.56E-05 2.06E-04 4.16E-08 4.88E-03 3.66E-03 7.80E+01 -1.31 E-04 -3.49E+02 -1.31 E+OO 8,64E-08 4.70E+00 8.64E-04 1.53E-02 6.01 E-05 2.06E-04 3.91 E-08 4.68E-03 3.66E-03 7.90E+01 -1.21 E-04 -3.51 E+02 -1.21 E+OO 8.12E-08 4.70E+00 8.12E-04 1.54E-02 5.53E-05 2.06E-04 3.68E-08 4.48E-03 3.67E-03 8.00E+01 -1.11 E-04 -3.52E+02 -1.11 E+OO 7.63E-08 4.70E+00 7.63E-04 1.54E-02 5.09E-05 2.06E-04 3.45E-08 4.28E-03 3.67E-03 8.10OE+01 -1.02E-04 -3.53E+02 -1.02E+OO 7.17E-08 4.70E+00 7.17E-04 1.55E-02 4.67E-05 2.06E-04 3.25E-08 4.1 OE-03 3.68E-03 8.20E+01 -9.41 E-05 -3.54E+02 -9.41 E-01I 6.74E-08 4.70E+00 6.74E-04 1.55E-02 4.30E-05 2.06E-04 3.05E-08 3.92E-03 3.68E-03 8.30E+01 -8.68E-05 -3.55E+02 -8.68E-01 6.33E-08 4.70E+00 6.33E-04 1.56E-02 3.97E-05 2.06E-04 2.87E-08 3.74E-03 3.69E-03 8.40E+01 -8.01 E-05 -3.56E+02 -8.01 E-01 5.95E-08 4.70E+00 5.95E-04 1.56E-02 3.66E-05 2.06E-04 2.69E-08 3.57E-03 3.69E-03 8.50E+01 -7.39E-05 -3.56E+02 -7.39E-01 5.59E-08 4.70E+00 5.59E-04 1.56E-02 3.38E-05 2.06E-04 2.53E-08 3.41 E-03 3.70E-03 8.60E+01 -6.82E-05 -3.57E+02 -6.82E-01 5.26E-08 4.70E+00 5.26E-04 1.57E-02 3.12E-05 2.06E-04 2.38E-08 3.26E-03 3.70E-03 8.70E+01 -6.30E-05 -3.58E+02 -6.30E-01 4.94E-08 4.70E+00 4.94E-04 1.57E-02 2.88E-05 2.06E-04 2.24E-08 3.1 1E-03 3.71 E-03 8.80E+01 -5.83E-05 -3.58E+02 -5.83E-01 4.65E-08 4.70E+00 4.65E-04 1.57E-02 2.66E-05 2.06E-04 2.10E-08 2.96E-03 3.71 E-03 8.90E+01 -5.39E-05 -3.59E+02 -5.39E-01 4.37E-08 4.70E+00 4.37E-04 1.57E-02 2.46E-05 2.06E-04 1.98E-08 2.83E-03 3.71 E-03 9.00E+01 -4.98E-05 -3.59E+02 -4.98E-01 4.1 1 E-08 4.70E+00 4.1 1E-04 1.57E-02 2.27E-05 2.06E-04 1.86E-08 2.69E-03 3.72E-03 9.10E+01 -4.61 E-05 -3.60E+02 -4.61E-01 3.86E-08 4.70E+00 3.86E-04 1.58E-02 2.10E-05 2.06E-04 1.75E-08 2.57E-03 3.72E-03 9.20E+01 -4.27E-05 -3.60E+02 -4.27E-01 3.63E-08 4.70E+00 3,63E-04 1.58E-02 1.95E-05 2.06E-04 1.64E-08 2.45E-03 3.72E-03 9.30E+01 -3.95E-05 -3.61 E+02 -3.95E-01 3.41 E-08 4.70E+00 3.41 E-04 1.58E-02 1.80E-05 2.06E-04 1,54E-08 2.33E-03 3.72E-03 9.40E+01' -3.66E-05 -3.61 E+02 -3.66E-01 3.21 E-08 4.70E+00 3.21 E-04 1.56E-02 1.67E-05 2.06E-04 1.45E-08 2.22E-03 3.73E-03 9.50E+01 -3.39E-05 -3.61 E+02 -3.39E-01 3.02E-08 4.70E+00 3.02E-04 1.56E-02 1.55E-05 2.06E-04 1.37E-08 2.12E-03 3.73E-03 9.60E+01 -3.15E-05 -3.62E+02 -3.15E-01 2.84E-08 4.70E+00 2.84E-04 1.59E-02 1.43E-05 2.06E-04 1.29E-08 2.01 E-03 3.73E-03 9.70E+01 -2.92E-05 -3.62E+02 -2.92E-01 2.67E-08 4.71 E+00 2.67E-04 1.59E-02 1.33E-05 2.07E-04 1.21 E-08 1.92E-03 3.73E-03 9.80E+01 -2.71 E-05 -3.62E+02 -2.71 E-01I 2.51 E-08 4.71 E+00 2.51 E-04 1.59E-02 1.23E-05 2.07E-04 1.14E-08 1.82E-03 3.74E-03 9.90E+01 -2.51 E-05 -3.63E+02 -2.51 E-01 2.36E-08 4.71 E+00 2.36E-04 1.59E-02 1.14E-05 2.07E-04 1.07E-08 1.74E-03 3.74E-03 1.OOE+02 -2.33E-05 -3.63E+02 -2.33E-01 2.22E-08 4.71 E+00 2.22E-04 1.59E-02 1.06E-05 2.07E-04 1.OOE-08 1.65E-03 3.74E-03

H-3 Fractional Release Rate low concentration side 1.OOE Diffusion Coefficient = 5.5e-8 cmA2/s I .OOE-05 1.OOE A1

,0 1.OOE-07

('"I U.

1.OOE O.OOE.O0 2.OOE+01 4.OOE+01 6.OOE+01 8.OOE+01 1.OOE+02 1.20E+02 1.40E+02 Time (years)

H-3 Fractional Release Rate low concentration side 2.50E-04 2.OOE-04 0 Diffusion Coefficient = 5.5E-8 cmA2/s 1.50E-04 0r E

- Fractional l- Cumulative Release High I.'.1 concentration side 1.001E-04 Eu E

5.OOE-05 O.OOE+OO O.O( )E+OO 1.OOE+01 2.OOE.O1 3.OOE+01 4.OOE+01 5.OOE+01 6.OOE+01 7.OOE+01 8.00E+01 9.OOE+01 1.OOE.02 Time (years)

H-3 Fractional Release Rate High concentration side 1.00E-02 Diffusion Coefficient = 5.5e-8 cmA2/s 1.00E-03 I.OOE-04 11.00E-05 0

bU (A

0 -I -Fractional Release Rate High concentration sidel

" 1.00E-06 I-0 11.00E-07 1.002-08 1.00E-09 1 OOE-l I O.OOE+00 2.00E+0 4.OOE+01 6.OOE+01 8.OOE+01 1.OOE+02 1.20E+02 Time (years)

H-3 Fractional Release Rate High concentration side 1.80E-02 Diffusion Coefficient = 5.5E-8 cmA2/s 1.60E-02

-I- Fractional Cumulative Release High concentration side 1.40E-02 e 1.20E-02 c 1.OOE-02 0

I-o 8.OOE-03 E

) 6.OOE-03 4.OOE 2.OOE O.OOE+OO O.OOE.00 2.OOE+01 4.OOE+01 6.OOE+01 8.OOE+01 1.OOE+02 1.20E+02 Time (years)

BNL Report C-14 Spreadsheets

Maine Yen kee Max diffusion Diffusion Coefficient =1 E-12 cmA2Is ISOTOPE C-14 Total Mass In the System 2.28E+04 NODE 60 60 60 397 397 397 60 60 397 397 DISTANCE 6.77E+02 6.77E+02 6.77E+02 8.91E+02 8.91E+02 8.91E+02 Norm cum Norm rel Norm cum Norm rel TIME-YRS Flux Mass Mass Rat e Flux Mass Mass Rate Release rate Release rate 1.00E+00 -5.90E-12 -5.90E-08 -5.90E-08 4.38E-05 4.38E-01 4.38E-01 2.59E-12 2.59E-12 1.92E-05 1.92E-05 2.OOE+00 -1.20E-11 -1.79E-07 -1.20E-07 5.37E-06 4.92E-01 5.37E-02 7.85E-12 3.93E-12 2.16E-05 1.08E-05 3.OOE+00 -1.82E-11 -3.61E-07 -1.82E-07 1.51E-06 5.07E-01 1.51E-02 1.58E-11 7.98E-12 2.22E-05 1.51E-06 4.OOE+00 -2.44E-11 -6.06E-07 -2.44E-07 7.38E-07 5.15E-01 7.38E-03 2.66E-11 9.34E-12 2.26E-05 4.93E-07 5.OOE+00 -3.06E-11 -9.12E-07 -3.06E-07 4.68E-07 5.19E-01 4.68E-03 4.OOE-11 1.21E-11 2.28E-05 2.64E-07 6.OOE+00 -3.69E-1 1 -1.28E-06 -3.69E-07 3.35E-07 5.23E-01 3.35E-03 5.61 E-1 1 1.48E-1 1 2.29E-05 1.76E-07 7.00E+00 -4.31 E-11 -1.71 E-06 -4.31 E-07 2.56E-07 5.25E-01 2.56E-03 7.50E-11 1.75E-11 2.30E-05 1.30E-07 8.00E+00 -4.94E-11 -2.21E-06 -4.94E-07 2.04E-07 5.27E-01 2.04E-03 9.69E-11 2.03E-11 2.31E-05 1.01E-07 9.OOE+00 -5.56E-11 -2.76E-06 -5.56E-07 1.68E-07 5.29E-01 1.68E-03 1.21E-10 2.30E-11 2.32E-05 8.16E-08 1.OOE+01 -6.19E-11 -3.38E-06 -6.19E-07 1.41E-07 5.30E-01 1.41E-03 1.48E-10 2.58E-11 2.32E-05 6.78E-08 1.10E+01 -6.81E-11 -4.06E-06 -6.81E-07 1.21E-07 5.32E-01 1.21E-03 1.78E-10 2.85E-11 2.33E-05 5.75E-08 1.20E+01 -7.44E-11 -4.81E-06 -7.44E-07 1.05E-07 5.33E-01 1.05E-03 2.11E-10 3.13E-11 2.34E-05 4.96E-08 1.30E+01 -8.07E-11 -5.61E-06 -8.07E-07 9.26E-08 5.34E-01 9.26E-04 2.46E-10 3.40E-11 2.34E-05 4.33E-08 1.40E+01 -8.69E-11 -6.48E-06 -8.69E-07 8.24E-08 5.34E-01 8.24E-04 2.84E-10 3.68E-11 2.34E-05 3.84E-08 1.50E+01 -9.32E-11 -7.41E-06 -9.32E-07 7.40E-08 5.35E-01 7.40E-04 3.25E-10 3.95E-11 2.35E-05 3.43E-08 1.60E+01 -9.94E-11 -8.41E-06 -9.94E-07 6.70E-08 5.36E-01 6.70E-04 3.69E-10 4.22E-11 2.35E-05 3.09E-08 1.70E+01 -1.06E-10 -9.46E-06 -1.06E-06 6.11E-08 5.36E-01 6.11E-04 4.15E-10 4.50E-11 2.35E-05 2.81E-08 1.80E+01 -1.12E-10 -1.06E-05 -1.12E-06 5.61E-08 5.37E-01 5.61E-04 4.65E-10 4.78E-11 2.36E-05 2.57E-08 1.90E+01 -1.18E-10 -1.18E-05 -1.18E-06 5.18E-08 5.37E-01 5.18E-04 5.18E-10 5.04E-11 2.36E-05 2.37E-08 2.OOE+01 -1.24E-10 -1.30E-05 -1.24E-06 4.80E-08 5.38E-01 4.80E-04 5.70E-10 5.31E-11 2.36E-05 2.19E-08 2.10E+01 -1.31E-10 -1.43E-05 -1.31E-06 4.47E-08 5.38E-01 4.47E-04 6.27E-10 5.59E-11 2.36E-05 2.03E-08 2.20E+01 -1.37E-10 -1.57E-05 -1.37E-06 4.18E-08 5.39E-01 4.18E-04 6.89E-10 5.88E-11 2.36E-05 1.90E-08 2.30E+01 -1.43E-10 -1.71E-05 -1.43E-06 3.92E-08 5.39E-01 3.92E-04 7.50E-10 6.14E-11 2.36E-05 1.78E-08 2.40E+01 -1.50E-10 -1.86E-05 -1.50E-06 3.69E-08 5.40E-01 3.69E-04 8.16E-10 6.43E-11 2.37E-05 1.67E-08 2.50E+01 -1.56E-10 -2.02E-05 -1.56E-06 3.49E-08 5.40E-01 3.49E-04 8.86E-10 6.71E-11 2.37E-05 1.57E-08 2.60E+01 -1.62E-10 -2.18E-05 -1.62E-06 3.30E-08 5.40E-01 3.30E-04 9.56E-10 6.97E-11 2.37E-05 1.49E-08 2.70E+01 -1.68E-10 -2.35E-05 -1.68E-06 3.13E-08 5.41E-01 3.13E-04 1.03E-09 7.24E-11 2.37E-05 1.41E-08 2.80E+01 -1.75E-10 -2.52E-05 -1.75E-06 2.98E-08 5.41E-01 2.98E-04 1.11E-09 7.52E-11 2.37E-05 1.34E-08 2.90E+01 -1.81E-10 -2.70E-05 -1.81E-06 2.84E-08 5.41E-01 2.84E-04 1.18E-09 7.81E-11 2.37E-05 1.28E-08 3.00E+01 -1.87E-10 -2.89E-05 -1.87E-06 2.72E-08 5.41E-01 2.72E-04 1.27E-09 8.07E-11 2.37E-05 1.22E-08 3.10E+01 -1.93E-10 -3.08E-05 -1.93E-06 2.60E-08 5.42E-01 2.60E-04 1.35E-09 8.33E-11 2.38E-05 1.17E-08

3.20E+01 -2.OOE-10 -3.28E-05 -2.00E-06 2.50E-08 5.42E-01 2.50E-04 1.44E-09 8.62E-11 2.38E-05 1.12E-08 3.30E+01 -2.06E-10 -3.49E-05 -2.06E-06 2.40E-08 5.42E-01 2.40E-04 1.53E-09 8.90E-11 2.38E-05 1.07E-08 3.40E+01 -2.12E-10 -3.70E-05 -2.12E-06 2.31E-08 5.42E-01 2.31E-04 1.62E-09 9.17E-11 2.38E-05 1.03E-08 3.50E+01 -2.18E-10 -3.92E-05 -2.18E-06 2.22E-08 5.43E-01 2.22E-04 1.72E-09 9.43E-11 2.38E-05 9.93E-09 3.60E+01 -2.25E-10 -4.14E-05 -2.25E-06 2.15E-08 5.43E-01 2.15E-04 1.82E-09 9.71E-11 2.38E-05 9.58E-09 3.70E+01 -2.31E-10 -4.37E-05 -2.31E-06 2.07E-08 5.43E-01 2.07E-04 1.92E-09 1.00E-10 2.38E-05 9.25E-09 3.80E+01 -2.37E-10 -4.61E-05 -2.37E-06 2.01E-08 5.43E-01 2.01E-04 2.02E-09 1.03E-10 2.38E-05 8.95E-09 3.90E+01 -2.43E-10 -4.85E-05 -2.43E-06 1.94E-08 5.43E-01 1.94E-04 2.13E-09 1.05E-10 2.38E-05 8.66E-09 4.00E+01 -2.50E-10 -5.10E-05 -2.50E-06 1.89E-08 5.44E-01 1.89E-04 2.24E-09 1.08E-10 2.39E-05 8.40E-09 4.10E+01 -2.56E-10 -5.36E-05 -2.56E-06 1.83E-08 5.44E-01 1.83E-04 2.35E-09 1.11E-10 2.39E-05 8.16E-09 4.20E+01 -2.62E-10 -5.62E-05 -2.62E-06 1.78E-08 5.44E-01 1.78E-04 2.46E-09 1.14E-10 2.39E-05 7.92E-09 4.30E+01 -2.68E-10 -5.89E-05 -2.68E-06 1.73E-08 5.44E-01 1.73E-04 2.58E-09 1.16E-10 2.39E-05 7.70E-09 4.40E+01 -2.74E-10 -6.16E-05 -2.74E-06 1.68E-08 5.44E-01 1.68E-04 2.70E-09 1.19E-10 2.39E-05 7.48E-09 4.50E+01 -2.81E-10 -6.45E-05 -2.81E-06 1.64E-08 5.45E-01 1.64E-04 2.83E-09 1.22E-10 2.39E-05 7.28E-09 4.60E+01 -2.87E-10 -6.73E-05 -2.87E-06 1.60E-08 5.45E-01 1.60E-04 2.95E-09 1.25E-10 2.39E-05 7.11E-09 4.70E+01 -2.93E-10 -7.03E-05 -2.93E-06 1.56E-08 5.45E-01 1.56E-04 3.08E-09 1.27E-10 2.39E-05 6.93E-09 4.80E+01 -2.99E-10 -7.32E-05 -2.99E-06 1.52E-08 5.45E-01 1.52E-04 3.21 E-09 1.30E-10 2.39E-05 6.75E-09 4.90E+01 -3.06E-10 -7.63E-05 -3.06E-06 1.49E-08 5.45E-01 1.49E-04 3.35E-09 1.33E-10 2.39E-05 6.60E-09 5.00E+01 -3.12E-10 -7.94E-05 -3.12E-06 1.46E-08 5.45E-01 1.46E-04 3.48E-09 1.36E-10 2.39E-05 6.47E-09 5.10E+01 -9.70E-02 -9.70E+02 -9.70E+02 1.42E-08 5.45E-01 1.42E-04 4.25E-02 4.25E-02 2.39E-05 6.32E-09 5.20E+01 -1.45E-02 -1.12E+03 -1.45E+02 1.39E-08 5.46E-01 1.39E-04 4.91E-02 2.45E-02 2.39E-05 6.16E-09 5.30E+01 -4.33E-03 -1.16E+03 -4.33E+01 1.37E-08 5.46E-01 1.37E-04 5.09E-02 4.13E-03 2.39E-05 6.05E-09 5.40E+01 -2.13E-03 -1.18E+03 -2.13E+01 1.34E-08 5.46E-01 1.34E-04 5.18E-02 1.42E-03 2.39E-05 5.94E-09 5.50E+01 -1.36E-03 -1.19E+03 -1.36E+01 1.31E-08 5.46E-01 1.31E-04 5.22E-02 7.65E-04 2.39E-05 5.81E-09 5.60E+01 -9.74E-04 -1.20E+03 -9.74E+00 1.29E-08 5.46E-01 1.29E-04 5.26E-02 5.12E-04 2.39E-05 5.70E-09 5.70E+01 -7.47E-04 -1.21E+03 -7.47E+00 1.27E-08 5.46E-01 1.27E-04 5.31E-02 3.77E-04 2.39E-05 5.61E-09 5.80E+01 -5.96E-04 -1.22E+03 -5.96E+00 1.24E-08 5.46E-01 1.24E-04 5.35E-02 2.95E-04 2.39E-05 5.50E-09 5.90E+01 -4.90E-04 -1.22E+03 -4.90E+00 1.22E-08 5.46E-01 1.22E-04 5.35E-02 2.38E-04 2.39E-05 5.39E-09 6.00E+01 -4.12E-04 -1.23E+03 -4.12E+00 1.20E-08 5.47E-01 1.20E-04 5.39E-02 1.98E-04 2.40E-05 5.31E-09 6.10E+01 -3.53E-04 -1.23E+03 -3.53E+00 1.18E-08 5.47E-01 1.18E-04 5.39E-02 1.68E-04 2.40E-05 5.22E-09 6.20E+01 -3.06E-04 -1.23E+03 -3.06E+00 1.16E-08 5.47E-01 1.16E-04 5.39E-02 1.45E-04 2.40E-05 5.13E-09 6.30E+01 -2.70E-04 -1.23E+03 -2.70E+00 1.14E-08 5.47E-01 1.14E-04 5.39E-02 1.26E-04 2.40E-05 5.04E-09 6.40E+01 -2.40E-04 -1.24E+03 -2.40E+00 1.13E-08 5.47E-01 1.13E-04 5.44E-02 1.12E-04 2.40E-05 4.98E-09 6.50E+01 -2.15E-04 -1.24E+03 -2.15E+00 1.11E-08 5.47E-01 1.11E-04 5.44E-02 9.98E-05 2.40E-05 4.91E-09 6.60E+01 -1.95E-04 -1.24E+03 -1.95E+00 1.09E-08 5.47E-01 1.09E-04 5.44E-02 8.99E-05 2.40E-05 4.82E-09 6.70E+01 -1.77E-04 -1.24E+03 -1.77E+00 1.08E-08 5.47E-01 1.08E-04 5.44E-02 8.16E-05 2.40E-05 4.76E-09 6.80E+01 -1.62E-04 -1.24E+03 -1.62E+00 1.06E-08 5.47E-01 1.06E-04 5.44E-02 7.43E-05 2.40E-05 4.69E-09 6.90E+01 -1.50E-04 -1.25E+03 -1.50E+00 1.05E-08 5.48E-01 1.05E-04 5.48E-02 6.84E-05 2.40E-05 4.63E-09

7.00E+01 -1.39E-04 -1.25E+03 -1.39E+00 1.04E-08 5.48E-01 1.04E-04 5.48E-02 6.34E-05 2.40E-05 4.58E-09 7.10E+01 -1.29E-04 -1.25E+03 -1.29E+00 1.02E-08 5.48E-01 1.02E-04 5.48E-02 5.88E-05 2.40E-05 4.52E-09 7.20E+01 -1.20E-04 -1.25E+03 -1.20E+00 1.01 E-08 5.48E-01 1.01 E-04 5.48E-02 5.46E-05 2.40E-05 4.45E-09 7.30E+01 -1.13E-04 -1.25E+03 -1.13E+00 9.96E-09 5.48E-01 9.96E-05 5.48E-02 5.1 1E-05 2.40E-05 4.40E-09 7.40E+01 -1.06E-04 -1.25E+03 -1.06E+00 9.84E-09 5.48E-01 9.84E-05 5.48E-02 4.80E-05 2.40E-05 4.34E-09 7.50E+01 -1.00E-04 -1.25E+03 -1.00E+00 9.73E-09 5.48E-01 9.73E-05 5.48E-02 4.52E-05 2.40E-05 4.29E-09 7.60E+01 -9.45E-05 -1.25E+03 -9.45E-01 9.61 E-09 5.48E-01 9.61 E-05 5.48E-02 4.27E-05 2.40E-05 4.24E-09 7.70E+01 -8.96E-05 -1.26E+03 -8.96E-01 9.51 E-09 5.48E-01 9.51 E-05 5.53E-02 4.04E-05 2.40E-05 4.19E-09 7.80E+01 -8.52E-05 -1.26E+03 -8.52E-01 9.40E-09 5.48E-01 9.40E-05 5.53E-02 3.83E-05 2.40E-05 4.15E-09 7.90E+01 -8.1 1E-05 -1.26E+03 -8.1 1E-01 9.30E-09 5.49E-01 9.30E-05 5.53E-02 3.65E-05 2.41 E-05 4.10E-09 8.00E+01 -7.74E-05 -1.26E+03 -7.74E-01 9.20E-09 5.49E-01 9.20E-05 5.53E-02 3.48E-05 2.41E-05 4.06E-09 8.10E+01 -7.40E-05 -1.26E+03 -7.40E-01 9.10E-09 5.49E-01 9.10E-05 5.53E-02 3.32E-05 2.41E-05 4.01 E-09 8.20E+01 -7.09E-05 -1.26E+03 -7.09E-01 9.01 E-09 5.49E-01 9.01 E-05 5.53E-02 3.18E-05 2.41E-05 3.97E-09 8.30E+01 -6.80E-05 -1.26E+03 -6.80E-01 8.92E-09 5.49E-01 8.92E-05 5.53E-02 3.05E-05 2.41 E-05 3.93E-09 8.40E+01 -6.54E-05 -1.26E+03 -6.54E-01 8.83E-09 5.49E-01 8.83E-05 5.53E-02 2.93E-05 2.41 E-05 3.89E-09 8.50E+01 -6.29E-05 -1.26E+03 -6.29E-01 8.75E-09 5.49E-01 8.75E-05 5.53E-02 2.81 E-05 2.41 E-05 3.86E-09 8.60E+01 -6.06E-05 -1.26E+03 -6.06E-01 8.67E-09 5.49E-01 8.67E-05 5.53E-02 2.71 E-05 2.41 E-05 3.82E-09 8.70E+01 -5.85E-05 -1.26E+03 -5.85E-01 8.59E-09 5.49E-01 8.59E-05 5.53E-02 2.61 E-05 2.41 E-05 3.79E-09 8.80E+01 -5.65E-05 -1.26E+03 -5.65E-01 8.51 E-09 5.49E-01 8.51 E-05 5.53E-02 2.52E-05 2.41 E-05 3.75E-09 8.90E+01 -5.47E-05 -1.26E+03 -5.47E-01 8.43E-09 5.49E-01 8.43E-05 5.53E-02 2.44E-05 2.41 E-05 3.71 E-09 9.00E+01 -5.29E-05 -1.26E+03 -5.29E-01 8.36E-09 5.50E-01 8.36E-05 5.53E-02 2.36E-05 2.41 E-05 3.68E-09 9.10E+01 -5.13E-05 -1.26E+03 -5.13E-01 8.29E-09 5.50E-01 8.29E-05 5.53E-02 2.29E-05 2.41E-05 3.65E-09 9.20E+01 -4.98E-05 -1.26E+03 -4.98E-01 8.22E-09 5.50E-01 8.22E-05 5.53E-02 2.22E-05 2.41 E-05 3.62E-09 9.30E+01 -4.83E-05 -1.27E+03 -4.83E-01 8.15E-09 5.50E-01 8.15E-05 5.57E-02 2.15E-05 2.41 E-05 3.59E-09 9.40E+01 -4.70E-05 -1.27E+03 -4.70E-01 8.09E-09 5.50E-01 8.09E-05 5.57E-02 2.09E-05 2.41 E-05 3.56E-09 9.50E+01 -4.57E-05 -1.27E+03 -4.57E-01 8.02E-09 5.50E-01 8.02E-05 5.57E-02 2.03E-05 2.41 E-05 3.53E-09 9.60E+01 -4.45E-05 -1.27E+03 -4.45E-01 7.96E-09 5.50E-01 7.96E-05 5.57E-02 1.98E-05 2.41 E-05 3.50E-09 9.70E+01 -4.34E-05 -1.27E+03 -4.34E-01 7.90E-09 5.50E-01 7.90E-05 5.57E-02 1.93E-05 2.41 E-05 3.48E-09 9.80E+01 -4.23E-05 -1.27E+03 -4.23E-01 7.84E-09 5.50E-01 7.84E-05 5.57E-02 1.88E-05 2.41 E-05 3.45E-09 9.90E+01 -4.13E-05 -1.27E+03 -4.13E-01 7.79E-09 5.50E-01 7.79E-05 5.57E-02 1.83E-05 2.41 E-05 3.43E-09 1.00E+02 -4.03E-05 -1.27E+03 -4.03E-01 7.73E-09 5.50E-01 7.73E-05 5.57E-02 1.79E-05 2.41 E-05 3.40E-09 1.01 E+02 '-3.94E-05 -1.27E+03 -3.94E-01 7.67E-09 5.50E-01 7.67E-05 5.57E-02 1.75E-05 2.41 E-05 3.38E-09 1.02E+02 -3.85E-05 -1.27E+03 -3.85E-01 7.62E-09 5.50E-01 7.62E-05 5.57E-02 1.71 E-05 2.41 E-05 3.35E-09 1.03E+02 -3.77E-05 -1.27E+03 -3.77E-01 7.57E-09 5.51 E-01 7.57E-05 5.57E-02 1.67E-05 2.42E-05 3.33E-09 1.04E+02 -3.69E-05 -1.27E+03 -3.69E-01 7.52E-09 5.51 E-01 7.52E-05 5.57E-02 1.64E-05 2.42E-05 3.31 E-09 1.05E+02 -3.61 E-05 -1.27E+03 -3.61 E-01 7.47E-09 5.51E-01 7.47E-05 5.57E-02 1.60E-05 2.42E-05 3.29E-09 1.06E+02 -3.54E-05 -1.27E+03 -3.54E-01 7.42E-09 5.51E-01 7.42E-05 5.57E-02 1.57E-05 2.42E-05 3.27E-09 1.07E+02 -3.47E-05 -1.27E+03 -3.47E-01 7.37E-09 5.51 E-01 7.37E-05 5.57E-02 1.54E-05 2.42E-05 3.24E-09

1.08E+02 -3.40E-05 -1.27E+03 -3.40E-01 7.33E-09 5.51E-01 7.33E-05 5.57E-02 1.51E-05 2.42E-05 3.22E-09 1.09E+02 -3.34E-05 -1.27E+03 -3.34E-01 7.28E-09 5.51E-01 7.28E-05 5.57E-02 1.48E-05 2.42E-05 3.20E-09 1.10E+02 -3.28E-05 -1.27E+03 -3.28E-01 7.24E-09 5.51E-01 7.24E-05 5.57E-02 1.45E-05 2.42E-05 3.18E-09 1.11E+02 -3.22E-05 -1.27E+03 -3.22E-01 7.20E-09 5.51E-01 7.20E-05 5.57E-02 1.43E-05 2.42E-05 3.17E-09 1.12E+02 -3.17E-05 -1.27E+03 -3.17E-01 7.15E-09 5.51E-01 7.15E-05 5.57E-02 1.40E-05 2.42E-05 3.15E-09 1.13E+02 -3.11 E-05 -1.27E+03 -3.11 E-01 7.11 E-09 5.51E-01 7.11 E-05 5.57E-02 1.38E-05 2.42E-05 3.13E-09 1.14E+02 -3.06E-05 -1.27E+03 -3.06E-01 7.07E-09 5.51E-01 7.07E-05 5.57E-02 1.35E-05 2.42E-05 3.11E-09 1.15E+02 -3.01E-05 -1.27E+03 -3.01E-01 7.03E-09 5.51E-01 7.03E-05 5.57E-02 1.33E-05 2.42E-05 3.09E-09 1.16E+02 -2.97E-05 -1.27E+03 -2.97E-01 6.99E-09 5.51E-01 6.99E-05 5.57E-02 1.31E-05 2.42E-05 3.07E-09 1.17E+02 -2.92E-05 -1.27E+03 -2.92E-01 6.96E-09 5.52E-01 6.96E-05 5.57E-02 1.29E-05 2.42E-05 3.06E-09 1.18E+02 -2.88E-05 -1.27E+03 -2.88E-01 6.92E-09 5.52E-01 6.92E-05 5.57E-02 1.27E-05 2.42E-05 3.04E-09 1.19E+02 -2.83E-05 -1.27E+03 -2.83E-01 6.88E-09 5.52E-01 6.88E-05 5.57E-02 1.25E-05 2.42E-05 3.03E-09 1.20E+02 -2.79E-05 -1.28E+03 -2.79E-01 6.85E-09 5.52E-01 6.85E-05 5.61 E-02 1.23E-05 2.42E-05 3.01E-09 1.21E+02 -2.75E-05 -1.28E+03 -2.75E-01 6.81E-09 5.52E-01 6.81E-05 5.61E-02 1.21E-05 2.42E-05 3.00E-09 1.22E+02 -2.72E-05 -1.28E+03 -2.72E-01 6.78E-09 5.52E-01 6.78E-05 5.61 E-02 1.20E-05 2.42E-05 2.98E-09 1.23E+02 -2.68E-05 -1.28E+03 -2.68E-01 6.75E-09 5.52E-01 6.75E-05 5.61E-02 1.18E-05 2.42E-05 2.97E-09 1.24E+02 -2.64E-05 -1.28E+03 -2.64E-01 6.71E-09 5.52E-01 6.71E-05 5.61E-02 1.17E-05 2.42E-05 2.95E-09 1.25E+02 -2.61E-05 -1.28E+03 -2.61E-01 6.68E-09 5.52E-01 6.68E-05 5.61E-02 1.15E-05 2.42E-05 2.94E-09 1.26E+02 -2.58E-05 -1.28E+03 -2.58E-01 6.65E-09 5.52E-01 6.65E-05 5.61E-02 1.14E-05 2.42E-05 2.92E-09 1.27E+02 -2.54E-05 -1.28E+03 -2.54E-01 6.62E-09 5.52E-01 6.62E-05 5.61E-02 1.12E-05 2.42E-05 2.91E-09 1.28E+02 -2.51E-05 -1.28E+03 -2.51E-01 6.59E-09 5.52E-01 6.59E-05 5.61E-02 1.11E-05 2.42E-05 2.90E-09 1.29E+02 -2.48E-05 -1.28E+03 -2.48E-01 6.56E-09 5.52E-01 6.56E-05 5.61 E-02 1.09E-05 2.42E-05 2.88E-09 1.30E+02 -2.45E-05 -1.28E+03 -2.45E-01 6.53E-09 5.52E-01 6.53E-05 5.61 E-02 1.08E-05 2.42E-05 2.87E-09 1.31E+02 -2.43E-05 -1.28E+03 -2.43E-01 6.50E-09 5.52E-01 6.50E-05 5.61E-02 1.07E-05 2.42E-05 2.86E-09 1.32E+02 -2.40E-05 -1.28E+03 -2.40E-01 6.47E-09 5.53E-01 6.47E-05 5.61 E-02 1.06E-05 2.43E-05 2.84E-09 1.33E+02 -2.37E-05 -1.28E+03 -2.37E-01 6.45E-09 5.53E-01 6.45E-05 5.61 E-02 1.05E-05 2.43E-05 2.83E-09 1.34E+02 -2.35E-05 -1.28E+03 -2.35E-01 6.42E-09 5.53E-01 6.42E-05 5.61 E-02 1.04E-05 2.43E-05 2.82E-09 1.35E+02 -2.32E-05 -1.28E+03 -2.32E-01 6.39E-09 5.53E-01 6.39E-05 5.61E-02 1.02E-05 2.43E-05 2.81E-09 1.36E+02 -2.30E-05 -1.28E+03 -2.30E-01 6.37E-09 5.53E-01 6.37E-05 5.61E-02 1.01E-05 2.43E-05 2.80E-09 1.37E+02 -2.28E-05 -1.28E+03 -2.28E-01 6.34E-09 5.53E-01 6.34E-05 5.61 E-02 1.OOE-05 2.43E-05 2.79E-09 1.38E+02 -2.25E-05 -1.28E+03 -2.25E-01 6.32E-09 5.53E-01 6.32E-05 5.61 E-02 9.93E-06 2.43E-05 2.78E-09 1.39E+02 -2.23E-05 -1.28E+03 -2.23E-01 6.29E-09 5.53E-01 6.29E-05 5.61 E-02 9.82E-06 2.43E-05 2.77E-09 1.40E+02 -2.21 E-05 -1.28E+03 -2.21 E-01 6.27E-09 5.53E-01 6.27E-05 5.61 E-02 9.74E-06 2.43E-05 2.75E-09 1.41E+02 -2.19E-05 -1.28E+03 -2.19E-01 6.24E-09 5.53E-01 6.24E-05 5.61E-02 9.65E-06 2.43E-05 2.74E-09 1.42E+02 -2.17E-05 -1.28E+03 -2.17E-01 6.22E-09 5.53E-01 6.22E-05 5.61E-02 9.56E-06 2.43E-05 2.73E-09 1.43E+02 -2.15E-05 -1.28E+03 -2.15E-01 6.20E-09 5.53E-01 6.20E-05 5.61E-02 9.47E-06 2.43E-05 2.72E-09 1.44E+02 -2.13E-05 -1.28E+03 -2.13E-01 6.18E-09 5.53E-01 6.18E-05 5.61E-02 9.39E-06 2.43E-05 2.71E-09 1.45E+02 -2.11E-05 -1.28E+03 -2.11E-01 6.15E-09 5.53E-01 6.15E-05 5.61E-02 9.30E-06 2.43E-05 2.70E-09

1.46E+02 -2.09E-05 -1.28E+03 -2.09E-01 6.13E-09 5.53E-01 6.13E-05 5.61E-02 9.21E-06 2.43E-05 2.69E-09 1.47E+02 -2.07E-05 -1.28E+03 -2.07E-01 6.11E-09 5.54E-01 6.11E-05 5.61E-02 9.12E-06 2.43E-05 2.68E-09 1.48E+02 -2.06E-05 -1.28E+03 -2.06E-01 6.09E-09 5.54E-01 6.09E-05 5.61E-02 9.06E-06 2.43E-05 2.68E-09 1.49E+02 -2.04E-05 -1.28E+03 -2.04E-01 6.07E-09 5.54E-01 6.07E-05 5.61 E-02 8.99E-06 2.43E-05 2.67E-09 1.50E+02 -2.02E-05 -1.28E+03 -2.02E-01 6.05E-09 5.54E-01 6.05E-05 5.61E-02 8.90E-06 2.43E-05 2.66E-09 1.51E+02 -2.01E-05 -1.28E+03 -2.01E-01 6.03E-09 5.54E-01 6.03E-05 5.61E-02 8.84E-06 2.43E-05 2.65E-09 1.52E+02 -1.99E-05 -1.28E+03 -1.99E-01 6.01 E-09 5.54E-01 6.01 E-05 5.61 E-02 8.77E-06 2.43E-05 2.64E-09 1.53E+02 -1.98E-05 -1.28E+03 -1.98E-01 5.99E-09 5.54E-01 5.99E-05 5.61E-02 8.71E-06 2.43E-05 2.63E-09 1.54E+02 -1.96E-05 -1.28E+03 -1.96E-01 5.97E-09 5.54E-01 5.97E-05 5.61 E-02 8.64E-06 2.43E-05 2.62E-09 1.55E+02 -1.95E-05 -1.28E+03 -1.95E-01 5.95E-09 5.54E-01 5.95E-05 5.61E-02 8.57E-06 2.43E-05 2.61E-09 1.56E+02 -1.93E-05 -1.28E+03 -1.93E-01 5.93E-09 5.54E-01 5.93E-05 5.61E-02 8.51E-06 2.43E-05 2.61E-09 1.57E+02 -1.92E-05 -1.28E+03 -1.92E-01 5.92E-09 5.54E-01 5.92E-05 5.61 E-02 8.44E-06 2.43E-05 2.60E-09 1.58E+02 -1.91E-05 -1.28E+03 -1.91 E-01 5.90E-09 5.54E-01 5.90E-05 5.61 E-02 8.40E-06 2.43E-05 2.59E-09 1.59E+02 -1.89E-05 -1.28E+03 -1.89E-01 5.88E-09 5.54E-01 5.88E-05 5.61 E-02 8.33E-06 2.43E-05 2.58E-09 1.60E+02 -1.88E-05 -1.28E+03 -1.88E-01 5.86E-09 5.54E-01 5.86E-05 5.61E-02 8.27E-06 2.43E-05 2.57E-09 1.61E+02 -1.87E-05 -1.28E+03 -1.87E-01 5.85E-09 5.54E-01 5.85E-05 5.61E-02 8.22E-06 2.43E-05 2.57E-09 1.62E+02 -1.86E-05 -1.28E+03 -1.86E-01 5.83E-09 5.54E-01 5.83E-05 5.61E-02 8.18E-06 2.43E-05 2.56E-09 1.63E+02 -1.84E-05 -1.28E+03 -1.84E-01 5.81E-09 5.54E-01 5.81E-05 5.61E-02 8.11E-06 2.43E-05 2.55E-09 1.64E+02 -1.83E-05 -1.28E+03 -1.83E-01 5.80E-09 5.55E-01 5.80E-05 5.61E-02 8.05E-06 2.43E-05 2.55E-09 1.65E+02 -1.82E-05 -1.28E+03 -1.82E-01 5.78E-09 5.55E-01 5.78E-05 5.61 E-02 8.00E-06 2.43E-05 2.54E-09 1.66E+02 -1.81E-05 -1.29E+03 -1.81 E-01 5.76E-09 5.55E-01 5.76E-05 5.66E-02 7.96E-06 2.43E-05 2.53E-09 1.67E+02 -1.80E-05 -1.29E+03 -1.80E-01 5.75E-09 5.55E-01 5.75E-05 5.66E-02 7.92E-06 2.43E-05 2.52E-09 1.68E+02 -1.79E-05 -1.29E+03 -1.79E-01 5.73E-09 5.55E-01 5.73E-05 5.66E-02 7.87E-06 2.43E-05 2.52E-09 1.69E+02 -1.78E-05 -1.29E+03 -1.78E-01 5.72E-09 5.55E-01 5.72E-05 5.66E-02 7.83E-06 2.43E-05 2.51E-09 1.70E+02 -1.77E-05 -1.29E+03 -1.77E-01 5.70E-09 5.55E-01 5.70E-05 5.66E-02 7.79E-06 2.43E-05 2.50E-09 1.71 E+02 -1.76E-05 -1.29E+03 -1.76E-01 5.69E-09 5.55E-01 5.69E-05 5.66E-02 7.74E206 2.43E-05 2.50E-09 1.72E+02 -1.75E-05 -1.29E+03 -1.75E-01 5.67E-09 5.55E-01 5.67E-05 5.66E-02 7.70E-06 2.43E-05 2.49E-09 1.73E+02 -1.74E-05 -1.29E+03 -1.74E-01 5.66E-09 5.55E-01 5.66E-05 5.66E-02 7.65E-06 2.43E-05 2.48E-09 1.74E+02 -1.73E-05 -1.29E+03 -1.73E-01 5.64E-09 5.55E-01 5.64E-05 5.66E-02 7.61E-06 2.43E-05 2.48E-09 1.75E+02 -1.72E-05 -1.29E+03 -1.72E-01 5.63E-09 5.55E-01 5.63E-05 5.66E-02 7.57E-06 2.43E-05 2.47E-09 1.76E+02 -1.71 E-05 -1.29E+03 -1.71E-01 5.62E-09 5.55E-01 5.62E-05 5.66E-02 7.52E-06 2.43E-05 2.47E-09 1.77E+02 -1.70E-05 -1.29E+03 -1.70E-01 5.60E-09 5.55E-01 5.60E-05 5.66E-02 7.48E-06 2.43E-05 2.46E-09 1.78E+02 -1.69E-05 -1.29E+03 -1.69E-01 5.59E-09 5.55E-01 5.59E-05 5.66E-02 7.43E-06 2.43E-05 2.45E-09 1.79E+02 -1.68E-05 -1.29E+03 -1.68E-01 5.58E-09 5.55E-01 5.58E-05 5.66E-02 7.39E-06 2.43E-05 2.45E-09 1.80E+02 -1.67E-05 -1.29E+03 -1.67E-01 5.56E-09 5.55E-01 5.56E-05 5.66E-02 7.35E-06 2.43E-05 2.44E-09 1.81E+02 -1.67E-05 -1.29E+03 -1.67E-01 5.55E-09 5.55E-01 5.55E-05 5.66E-02 7.32E-06 2.43E-05 2.44E-09 1.82E+02 -1.66E-05 -1.29E+03 -1.66E-01 5.54E-09 5.56E-01 5.54E-05 5.66E-02 7.30E-06 2.44E-05 2.43E-09 1.83E+02 -1.65E-05 -1.29E+03 -1.65E-01 5.53E-09 5.56E-01 5.53E-05 5.66E-02 7.26E-06 2.44E-05 2.43E-09

1.84E+02 -1.64E-05 -1.29E+03 -1.64E-01 5.51E-09 5.56E-01 5.51E-05 5.66E-02 7.21E-06 2.44E-05 2.42E-09 1.85E+02 -1.63E-05 -1.29E+03 -1.63E-01 5.50E-09 5.56E-01 5.50E-05 5.66E-02 7.17E-06 2.44E-05 2.41E-09 1.86E+02 -1.63E-05 -1.29E+03 -1.63E-01 5.49E-09 5.56E-01 5.49E-05 5.66E-02 7.15E-06 2.44E-05 2.41E-09 1.87E+02 -1.62E-05 -1.29E+03 -1.62E-01 5.48E-09 5.56E-01 5.48E-05 5.66E-02 7.13E-06 2.44E-05 2.41E-09 1.88E+02 -1.61 E-05 -1.29E+03 -1.61 E-01 5.46E-09 5.56E-01 5.46E-05 5.66E-02 7.08E-06 2.44E-05 2.40E-09 1.89E+02 -1.60E-05 -1.29E+03 -1.60E-01 5.45E-09 5.56E-01 5.45E-05 5.66E-02 7.04E-06 2.44E-05 2.39E-09 1.90E+02 -1.60E-05 -1.29E+03 -1.60E-01 5.44E-09 5.56E-01 5.44E-05 5.66E-02 7.02E-06 2.44E-05 2.39E-09 1.91 E+02 -1.59E-05 -1.29E+03 -1.59E-01 5.43E-09 5.56E-01 5.43E-05 5.66E-02 7.OOE-06 2.44E-05 2.38E-09 1.92E+02 -1.58E-05 -1.29E+03 -1.58E-01 5.42E-09 5.56E-01 5.42E-05 5.66E-02 6.95E-06 2.44E-05 2.38E-09 1.93E+02 -1.58E-05 -1.29E+03 -1.58E-01 5.41 E-09 5.56E-01 5.41 E-05 5.66E-02 6.93E-06 2.44E-05 2.38E-09 1.94E+02 -1.57E-05 -1.29E+03 -1.57E-01 5.40E-09 5.56E-01 5.40E-05 5.66E-02 6.91E-06 2.44E-05 2.37E-09 1.95E+02 -1.56E-05 -1.29E+03 -1.56E-01 5.39E-09 5.56E-01 5.39E-05 5.66E-02 6.86E-06 2.44E-05 2.37E-09 1.96E+02 -1.56E-05 -1.29E+03 -1.56E-01 5.38E-09 5.56E-01 5.38E-05 5.66E-02 6.84E-06 2.44E-05 2.36E-09 1.97E+02 -1.55E-05 -1.29E+03 -1.55E-01 5.37E-09 5.56E-01 5.37E-05 5.66E-02 6.82E-06 2.44E-05 2.36E-09 1.98E+02 -1.55E-05 -1.29E+03 -1.55E-01 5.35E-09 5.56E-01 5.35E-05 5.66E-02 6.80E-06 2.44E-05 2.35E-09 1.99E+02 -1.54E-05 -1.29E+03 -1.54E-01 5.34E-09 5.56E-01 5.34E-05 5.66E-02 6.78E-06 2.44E-05 2.34E-09 2.00E+02 -1.53E-05 -1.29E+03 -1.53E-01 5.33E-09 5.57E-01 5.33E-05 5.66E-02 6.73E-06 2.44E-05 2.34E-09 2.01 E+02 -1.53E-05 -1.29E+03 -1.53E-01 5.32E-09 5.57E-01 5.32E-05 5.66E-02 6.71 E-06 2.44E-05 2.34E-09 2.02E+02 -1.52E-05 -1.29E+03 -1.52E-01 5.31 E-09 5.57E-01 5.31 E-05 5.66E-02 6.69E-06 2.44E-05 2.33E-09 2.03E+02 -1.52E-05 -1.29E+03 -1.52E-01 5.30E-09 5.57E-01 5.30E-05 5.66E-02 6.67E-06 2.44E-05 2.33E-09 2.04E+02 -1.51 E-05 -1.29E+03 -1.51E-01 5.29E-09 5.57E-01 5.29E-05 5.66E-02 6.64E-06 2.44E-05 2.32E-09 2.05E+02 -1.51E-05 -1.29E+03 -1.51E-01 5.29E-09 5.57E-01 5.29E-05 5.66E-02 6.62E-06 2.44E-05 2.32E-09 2.06E+02 -1.50E-05 -1.29E+03 -1.50E-01 5.28E-09 5.57E-01 5.28E-05 5.66E-02 6.60E-06 2.44E-05 2.32E-09 2.07E+02 -1.50E-05 -1.29E+03 -1.50E-01 5.27E-09 5.57E-01 5.27E-05 5.66E-02 6.58E-06 2.44E-05 2.31 E-09 2.08E+02 -1.49E-05 -1.29E+03 -1.49E-01 5.26E-09 5.57E-01 5.26E-05 5.66E-02 6.56E-06 2.44E-05 2.31 E-09 2.09E+02 -1.48E-05 -1.29E+03 -1.48E-01 5.25E-09 5.57E-01 5.25E-05 5.66E-02 6.51 E-06 2.44E-05 2.30E-09 2.10E+02 -1.48E-05 -1.29E+03 -1.48E-01 5.24E-09 5.57E-01 5.24E-05 5.66E-02 6.49E-06 2.44E-05 2.30E-09 2.11E+02 -1.47E-05 -1.29E+03 -1.47E-01 5.23E-09 5.57E-01 5.23E-05 5.66E-02 6.47E-06 2.44E-05 2.30E-09 2.12E+02 -1.47E-05 -1.29E+03 -1.47E-01 5.22E-09 5.57E-01 5.22E-05 5.66E-02 6.45E-06 2.44E-05 2.29E-09 2.13E+02 -1.47E-05 -1.29E+03 -1.47E-01 5.21E-09 5.57E-01 5.21E-05 5.66E-02 6.45E-06 2.44E-05 2.29E-09 2.14E+02 -1.46E-05 -1.29E+03 -1.46E-01 5.20E-09 5.57E-01 5.20E-05 5.66E-02 6.43E-06 2.44E-05 2.28E-09 2.15E+02 -1.46E-05 -1.29E+03 -1.46E-01 5.20E-09 5.57E-01 5.20E-05 5.66E-02 6.40E-06 2.44E-05 2.28E-09 2.16E+02 -1.45E-05 -1.29E+03 -1.45E-01 5.19E-09 5.57E-01 5.19E-05 5.66E-02 6.38E-06 2.44E-05 2.28E-09 2.17E+02 -1.45E-05 -1.29E+03 -1.45E-01 5.18E-09 5.57E-01 5.18E-05 5.66E-02 6.36E-06 2.44E-05 2.27E-09 2.18E+02 -1.44E-05 -1.29E+03 -1.44E-01 5.17E-09 5.57E-01 5.17E-05 5.66E-02 6.34E-06 2.44E-05 2.27E-09 2.19E+02 -1.44E-05 -1.29E+03 -1.44E-01 5.16E-09 5.58E-01 5.16E-05 5.66E-02 6.32E-06 2.45E-05 2.27E-09 2.20E+02 -1.43E-05 -1.29E+03 -1.43E-01 5.15E-09 5.58E-01 5.15E-05 5.66E-02 6.29E-06 2.45E-05 2.26E-09 2.21E+02 -1.43E-05 -1.29E+03 -1.43E-01 5.15E-09 5.58E-01 5.15E-05 5.66E-02 6.27E-06 2.45E-05 2.26E-09

2.22E+02 -1.42E-05 -1.29E+03 -1.42E-01 5.14E-09 5.58E-01 5.14E-05 5.66E-02 6.25E-06 2.45E-05 2.26E-09 2.23E+02 -1.42E-05 -1.29E+03 -1.42E-01 5.13E-09 5.58E-01 5.13E-05 5.66E-02 6.23E-06 2.45E-05 2.25E-09 2.24E+02 -1.42E-05 -1.29E+03 -1.42E-01 5.12E-09 5.58E-01 5.12E-05 5.66E-02 6.23E-06 2.45E-05 2.25E-09 2.25E+02 -1.41E-05 -1.29E+03 -1.41E-01 5.11E-09 5.58E-01 5.11E-05 5.66E-02 6.21E-06 2.45E-05 2.24E-09 2.26E+02 -1.41E-05 -1.29E+03 -1.41E-01 5.11E-09 5.58E-01 5.11E-05 5.66E-02 6.18E-06 2.45E-05 2.24E-09 2.27E+02 -1.40E-05 -1.29E+03 -1.40E-01 5.10E-09 5.58E-01 5.10E-05 5.66E-02 6.16E-06 2.45E-05 2.24E-09 2.28E+02 -1.40E-05 -1.29E+03 -1.40E-01 5.09E-09 5.58E-01 5.09E-05 5.66E-02 6.14E.06 2.45E-05 2.23E-09 2.29E+02 -1.40E-05 -1.29E+03 -1.40E-01 5.08E-09 5.58E-01 5.08E-05 5.66E-02 6.14E-06 2.45E-05 2.23E-09 2.30E+02 -1.39E-05 -1.30E+03 -1.39E-01 5.08E-09 5.58E-01 5.08E-05 5.70E-02 6.12E-06 2.45E-05 2.23E-09 2.31E+02 -1.39E-05 -1.30E+03 -1.39E-01 5.07E-09 5.58E-01 5.07E-05 5.70E-02 6.10E-06 2.45E-05 2.23E-09 2.32E+02 -1.39E-05 -1.30E+03 -1.39E-01 5.06E-09 5.58E-01 5.06E-05 5.70E-02 6.10E-06 2.45E-05 2.22E-09 2.33E+02 -1.38E-05 -1.30E+03 -1.38E-01 5.06E-09 5.58E-01 5.06E-05 5.70E-02 6.07E-06 2.45E-05 2.22E-09 2.34E+02 -1.38E-05 -1.30E+03 -1.38E-01 5.05E-09 5.58E-01 5.05E-05 5.70E-02 6.05E-06 2.45E-05 2.22E-09 2.35E+02 -1.37E-05 -1.30E+03 -1.37E-01 5.04E-09 5.58E-01 5.04E-05 5.70E-02 6.03E-06 2.45E-05 2.21 E-09 2.36E+02 -1.37E-05 -1.30E+03 -1.37E-01 5.03E-09 5.58E-01 5.03E-05 5.70E-02 6.01 E-06 2.45E-05 2.21 E-09 2.37E+02 -1.37E-05 -1.30E+03 -1.37E-01 5.03E-09 5.58E-01 5.03E-05 5.70E-02 6.01E-06 2.45E-05 2.21E-09 2.38E+02 -1.36E-05 -1.30E+03 -1.36E-01 5.02E-09 5.58E-01 5.02E-05 5.70E-02 5.99E-06 2.45E-05 2.20E-09 2.39E+02 -1.36E-05 -1.30E+03 -1.36E-01 5.01 E-09 5.59E-01 5.01 E-05 5.70E-02 5.96E-06 2.45E-05 2.20E-09 2.40E+02 -1.36E-05 -1.30E+03 -1.36E-01 5.01 E-09 5.59E-01 5.01 E-05 5.70E-02 5.96E-06 2.45E-05 2.20E-09 2.41 E+02 -1.35E-05 -1.30E+03 -1.35E-01 5.00E-09 5.59E-01 5.00E-05 5.70E-02 5.94E-06 2.45E-05 2.20E-09 2.42E+02 -1.35E-05 -1.30E+03 -1.35E-01 4.99E-09 5.59E-01 4.99E-05 5.70E-02 5.92E-06 2.45E-05 2.19E-09 2.43E+02 -1.35E-05 -1.30E+03 -1.35E-01 4.99E-09 5.59E-01 4.99E-05 5.70E-02 5.92E-06 2.45E-05 2.19E-09 2.44E+02 -1.35E-05 -1.30E+03 -1.35E-01 4.98E-09 5.59E-01 4.98E-05 5.70E-02 5.92E-06 2.45E-05 2.19E-09 2.45E+02 -1.34E-05 -1.30E+03 -1.34E-01 4.97E-09 5.59E-01 4.97E-05 5.70E-02 5.90E-06 2.45E-05 2.18E-09 2.46E+02 -1.34E-05 -1.30E+03 -1.34E-01 4.97E-09 5.59E-01 4.97E-05 5.70E-02 5.88E-06 2.45E-05 2.18E-09 2.47E+02 -1.34E-05 -1.30E+03 -1.34E-01 4.96E-09 5.59E-01 4.96E-05 5.70E-02 5.88E-06 2.45E-05 2.18E-09 2.48E+02 -1.33E-05 -1.30E+03 -1.33E-01 4.96E-09 5.59E-01 4.96E-05 5.70E-02 5.86E-06 2.45E-05 2.18E-09 2.49E+02 -1.33E-05 -1.30E+03 -1.33E-01 4.95E-09 5.59E-01 4.95E-05 5.70E-02 5.83E-06 2.45E-05 2.17E-09 2.50E+02 -1.33E-05 -1.30E+03 -1.33E-01 4.94E-09 5.59E-01 4.94E-05 5.70E-02 5.83E-06 2.45E-05 2.17E-09 2.51E+02 -1.32E-05 -1.30E+03 -1.32E-01 4.94E-09 5.59E-01 4.94E-05 5.70E-02 5.81E-06 2.45E-05 2.17E-09 2.52E+02 -1.32E-05 -1.30E+03 -1.32E-01 4.93E-09 5.59E-01 4.93E-05 5.70E-02 5.79E-06 2.45E-05 2.16E-09 2.53E+02 -1.32E-05 -1.30E+03 -1.32E-01 4.93E-09 5.59E-01 4.93E-05 5.70E-02 5.79E-06 2.45E-05 2.16E-09 2.54E+02 -1.32E-05 -1.30E+03 -1.32E-01 4.92E-09 5.59E-01 4.92E-05 5.70E-02 5.79E-06 2.45E-05 2.16E-09 2.55E+02 -1.31E-05 -1.30E+03 -1.31E-01 4.91E-09 5.59E-01 4.91E-05 5.70E-02 5.77E-06 2.45E-05 2.16E-09 2.56E+02 -1.31E-05 -1.30E+03 -1.31E-01 4.91E-09 5.59E-01 4.91E-05 5.70E-02 5.75E-06 2.45E-05 2.15E-09 2.57E+02 -1.31E-05 -1.30E+03 -1.31E-01 4.90E-09 5.59E-01 4.90E-05 5.70E-02 5.75E-06 2.45E-05 2.15E-09 2.58E+02 -1.30E-05 -1.30E+03 -1.30E-01 4.90E-09 5.59E-01 4.90E-05 5.70E-02 5.72E-06 2.45E-05 2.15E-09 2.59E+02 -1.30E-05 -1.30E+03 -1.30E-01 4.89E-09 5.60E-01 4.89E-05 5.70E-02 5.70E-06 2.46E-05 2.15E-09

2.60E+02 -1.30E-05 -1.30E+03 -1.30E-01 4.89E-09 5.60E-01 4.89E-05 5.70E-02 5.70E-06 2.46E-05 2.14E-09 2.61E+02 -1.30E-05 -1.30E+03 -1.30E-01 4.88E-09 5.60E-01 4.88E-05 5.70E-02 5.70E-06 2.46E-05 2.14E-09 2.62E+02 -1.29E-05 -1.30E+03 -1.29E-01 4.87E-09 5.60E-01 4.87E-05 5.70E-02 5.68E-06 2.46E-05 2.14E-09 2.63E+02 -1.29E-05 -1.30E+03 -1.29E-01 4.87E-09 5.60E-01 4.87E-05 5.70E-02 5.66E-06 2.46E-05 2.14E-09 2.64E+02 -1.29E-05 -1.30E+03 -1.29E-01 4.86E-09 5.60E-01 4.86E-05 5.70E-02 5.66E-06 2.46E-05 2.13E-09 2.65E+02 -1.29E-05 -1.30E+03 -1.29E-01 4.86E-09 5.60E-01 4.86E-05 5.70E-02 5.66E-06 2.46E-05 2.13E-09 2.66E+02 -1.28E-05 -1.30E+03 -1.28E-01 4.85E-09 5.60E-01 4.85E-05 5.70E-02 5.64E-06 2.46E-05 2.13E-09 2.67E+02 -1.28E-05 -1.30E+03 -1.28E-01 4.85E-09 5.60E-01 4.85E-05 5.70E-02 5.61E-06 2.46E-05 2.13E-09 2.68E+02 -1.28E-05 -1.30E+03 -1.28E-01 4.84E-09 5.60E-01 4.84E-05 5.70E-02 5.61E-06 2.46E-05 2.13E-09 2.69E+02 -1.28E-05 -1.30E+03 -1.28E-01 4.84E-09 5.60E-01 4.84E-05 5.70E-02 5.61E-06 2.46E-05 2.12E-09 2.70E+02 -1.27E-05 -1.30E+03 -1.27E-01 4.83E-09 5.60E-01 4.83E-05 5.70E-02 5.59E-06 2.46E-05 2.12E-09 2.71E+02 -1.27E-05 -1.30E+03 -1.27E-01 4.83E-09 5.60E-01 4.83E-05 5.70E-02 5.57E-06 2.46E-05 2.12E-09 2.72E+02 -1.27E-05 -1.30E+03 -1.27E-01 4.82E-09 5.60E-01 4.82E-05 5.70E-02 5.57E-06 2.46E-05 2.12E-09 2.73E+02 -1.27E-05 -1.30E+03 -1.27E-01 4.82E-09 5.60E-01 4.82E-05 5.70E-02 5.57E-06 2.46E-05 2.11E-09 2.74E+02 -1.27E-05 -1.30E+03 -1.27E-01 4.81E-09 5.60E-01 4.81E-05 5.70E-02 5.57E-06 2.46E-05 2.11E-09 2.75E+02 -1.26E-05 -1.30E+03 -1.26E-01 4.81E-09 5.60E-01 4.81E-05 5.70E-02 5.55E-06 2.46E-05 2.11E-09 2.76E+02 -1.26E-05 -1.30E+03 -1.26E-01 4.80E-09 5.60E-01 4.80E-05 5.70E-02 5.53E-06 2.46E-05 2.11E-09 2.77E+02 -1.26E-05 -1.30E+03 -1.26E-01 4.80E-09 5.60E-01 4.80E-05 5.70E-02 5.53E-06 2.46E-05 2.11E-09 2.78E+02 -1.26E-05 -1.30E+03 -1.26E-01 4.79E-09 5.60E-01 4.79E-05 5.70E-02 5.53E-06 2.46E-05 2.10E-09 2.79E+02 -1.25E-05 -1.30E+03 -1.25E-01 4.79E-09 5.60E-01 4.79E-05 5.70E-02 5.50E-06 2.46E-05 2.10E-09 2.80E+02 -1.25E-05 -1.30E+03 -1.25E-01 4.78E-09 5.61E-01 4.78E-05 5.70E-02 5.48E-06 2.46E-05 2.10E-09 2.81E+02 -1.25E-05 -1.30E+03 -1.25E-01 4.78E-09 5.61E-01 4.78E-05 5.70E-02 5.48E-06 2.46E-05 2.10E-09 2.82E+02 -1.25E-05 -1.30E+03 -1.25E-01 4.77E-09 5.61E-01 4.77E-05 5.70E-02 5.48E-06 2.46E-05 2.09E-09 2.83E+02 -1.25E-05 -1.30E+03 -1.25E-01 4.77E-09 5.61E-01 4.77E-05 5.70E-02 5.48E-06 2.46E-05 2.09E-09 2.84E+02 -1.24E-05 -1.30E+03 -1.24E-01 4.76E-09 5.61 E-01 4.76E-05 5.70E-02 5.46E-06 2.46E-05 2.09E-09 2.85E+02 -1.24E-05 -1.30E+03 -1.24E-01 4.76E-09 5.61 E-01 4.76E-05 5.70E-02 5.44E-06 2.46E-05 2.09E-09 2.86E+02 -1.24E-05 -1.30E+03 -1.24E-01 4.75E-09 5.61 E-01 4.75E-05 5.70E-02 5.44E-06 2.46E-05 2.09E-09 2.87E+02 -1.24E-05 -1.30E+03 -1.24E-01 4.75E-09 5.61E-01 4.75E-05 5.70E-02 5.44E-06 2.46E-05 2.08E-09 2.88E+02 -1.24E-05 -1.30E+03 -1.24E-01 4.75E-09 5.61E-01 4.75E-05 5.70E-02 5.44E-06 2.46E-05 2.08E-09 2.89E+02 -1.23E-05 -1.30E+03 -1.23E-01 4.74E-09 5.61 E-01 4.74E-05 5.70E-02 5.42E-06 2.46E-05 2.08E-09 2.90E+02 -1.23E-05 -1.30E+03 -1.23E-01 4.74E-09 5.61E-01 4.74E-05 5.70E-02 5.39E-06 2.46E-05 2.08E-09 2.91E+02 -1.23E-05 -1.30E+03 -1.23E-01 4.73E-09 5.61E-01 4.73E-05 5.70E-02 5.39E-06 2.46E-05 2.08E-09 2.92E+02 -1.23E-05 -1.30E+03 -1.23E-01 4.73E-09 5.61E-01 4.73E-05 5.70E-02 5.39E-06 2.46E-05 2.07E-09 2.93E+02 -1.23E-05 -1.30E+03 -1.23E-01 4.72E-09 5.61 E-01 4.72E-05 5.70E-02 5.39E-06 2.46E-05 2.07E-09 2.94E+02 -1.23E-05 -1.30E+03 -1.23E-01 4.72E-09 5.61E-01 4.72E-05 5.70E-02 5.39E-06 2.46E-05 2.07E-09 2.95E+02 -1.22E-05 -1.30E+03 -1.22E-01 4.72E-09 5.61 E-01 4.72E-05 5.70E-02 5.37E-06 2.46E-05 2.07E-09 2.96E+02 -1.22E-05 -1.30E+03 -1.22E-01 4.71E-09 5.61E-01 4.71E-05 5.70E-02 5.35E-06 2.46E-05 2.07E-09 2.97E+02 -1.22E-05 -1.30E+03 '-1.22E-01 4.71E-09 5.61E-01 4.71E-05 5.70E-02 5.35E-06 2.46E-05 2.07E-09

2.98E+02 -1.22E-05 -1.30E+03 -1.22E-01 4.70E-09 5.61 E-01 4.70E-05 5.70E-02 5.35E-06 2.46E-05 2.06E-09 2.99E+02 -1.22E-05 -1.30E+03 -1.22E-01 4.70E-09 5.61 E-01 4.70E-05 5.70E-02 5.35E-06 2.46E-05 2.06E-09 3.00E+02 -1.21 E-05 -1.30E+03 -1.21E-01 4.69E-09 5.61E-01 4.69E-05 5.70E-02 5.33E-06 2.46E-05 2.06E-09 3.01 E+02 -1.21E-05 -1.30E+03 -1.21 E-01 4.69E-09 5.62E-01 4.69E-05 5.70E-02 5.31 E-06 2.46E-05 2.06E-09 3.02E+02 -1.21E-05 -1.30E+03 -1.21 E-01 4.69E-09 5.62E-01 4.69E-05 5.70E-02 5.31 E-06 2.46E-05 2.06E-09 3.03E+02 -1.21E-05 -1.30E+03 -1.21 E-01 4.68E-09 5.62E-01 4.68E-OS 5.70E-02 5.31 E-06 2.46E-05 2.05E-09 3.04E+02 -1.21 E-05 -1.30E+03 -1.21E-01 4.68E-09 5.62E-01 4.68E-05 5.70E-02 5.31 E-06 2.46E-05 2.05E-09 3.05E+02 -1.21 E-05 -1.30E+03 -1.21E-01 4.67E-09 5.62E-01 4.67E-05 5.70E-02 5.31 E-06 2.46E-05 2.05E-09 3.06E+02 -1.20E-05 -1.30E+03 -1.20E-01 4.67E-09 5.62E-01 4.67E-05 5.70E-02 5.29E-06 2.46E-05 2.05E-09 3.07E+02 -1.20E-05 -1.30E+03 -1.20E-01 4.67E-09 5.62E-01 4.67E-05 5.70E-02 5.26E-06 2.46E-05 2.05E-09 3.08E+02 -1.20E-05 -1.31 E+03 -1.20E-01 4.66E-09 5.62E-01 4.66E-05 5.75E-02 5.26E-06 2.46E-05 2.05E-09 3.09E+02 -1.20E-05 -1.31 E+03 -1.20E-01 4.66E-09 5.62E-01 4.66E-05 5.75E-02 5.26E-06 2.46E-05 2.04E-09 3.10E+02 -1.20E-05 -1.31 E+03 -1.20E-01 4.65E-09 5.62E-01 4.65E-05 5.75E-02 5.26E-06 2.46E-05 2.04E-09 3.1 1E+02 -1.20E-05 -1.31 E+03 -1.20E-01 4.65E-09 5.62E-01 4.65E-05 5.75E-02 5.26E-06 2.46E-05 2.04E-09 3.12E+02 -1.19E-05 -1.31 E+03 -1.19E-01 4.65E-09 5.62E-01 4.65E-05 5.75E-02 5.24E-06 2.46E-05 2.04E-09 3.13E+02 -1.19E-05 -1.31E+03 -1.19E-01 4.64E-09 5.62E-01 4.64E-05 5.75E-02 5.22E-06 2.46E-05 2.04E-09 3.14E+02 -1.19E-05 -1.31E+03 -1.19E-01 4.64E-09 5.62E-01 4.64E-05 5.75E-02 5.22E-06 2.46E-05 2.04E-09 3.15E+02 -1.19E-05 -1.31E+03 -1.19E-01 4.64E-09 5.62E-01 4.64E-05 5.75E-02 5.22E-06 2.46E-05 2.04E-09 3.16E+02 -1.19E-05 -1.31E+03 -1.19E-01 4.63E-09 5.62E-01 4.63E-05 5.75E-02 5.22E-06 2.46E-05 2.03E-09 3.17E+02 -1.19E-05 -1.31E+03 -1.19E-01 4.63E-09 5.62E-01 4.63E-05 5.75E-02 5.22E-06 2.46E-05 2.03E-09 3.18E+02 -1.19E-05 -1.31 E+03 -1.19E-01 4.62E-09 5.62E-01 4.62E-05 5.75E-02 5.22E-06 2.46E-05 2.03E-09 3.19E+02 -1.18E-05 -1.31 E+03 -1.18E-01 4.62E-09 5.62E-01 4.62E-05 5.75E-02 5.20E-06 2.46E-05 2.03E-09 3.20E+02 -1.18E-05 -1.31 E+03 -1.18E-01 4.62E-09 5.62E-01 4.62E-05 5.75E-02 5.18E-06 2.46E-05 2.03E-09 3.21 E+02 -1.18E-05 -1.31E+03 -1.18E-01 4.61 E-09 5.62E-01 4.61 E-05 5.75E-02 5.18E-06 2.46E-05 2.02E-09 3.22E+02 -1.18E-05 -1.31E+03 -1.18E-01 4.61 E-09 5.62E-01 4.61 E-05 5.75E-02 5.18E-06 2.46E-05 2.02E-09 3.23E+02 -1.18E-05 -1.31E+03 -1.18E-01 4.61 E-09 5.63E-01 4.61 E-05 5.75E-02 5.18E-06 2.47E-05 2.02E-09 3.24E+02 -1.18E-05 -1.31E+03 -1.18E-01 4.60E-09 5.63E-01 4.60E-05 5.75E-02 5.18E-06 2.47E-05 2.02E-09 3.25E+02 -1.18E-05 -1.31 E+03 -1.18E-01 4.60E-09 5.63E-01 4.60E-05 5.75E-02 5.18E-06 2.47E-05 2.02E-09 3.26E+02 -1.17E-05 -1.31 E+03 -1.17E-01 4.60E-09 5.63E-01 4.60E-05 5.75E-02 5.15E-06 2.47E-05 2.02E-09 3.27E+02 -1.17E-05 -1.31 E+03 -1.17E-p1 4.59E-09 5.63E-01 4.59E-05 5.75E-02 5.13E-06 2.47E-05 2.02E-09 3.28E+02 -1.17E-05 -1.31 E+03 -1.17E-01 4.59E-09 5.63E-01 4.59E-05 5.75E-02 5.13E-06 2.47E-05 2.01 E-09 3.29E+02 -1.17E-05 -1.31E+03 -1.17E-01 4.59E-09 5.63E-01 4.59E-05 5.75E-02 5.13E-06 2.47E-OS 2.01 E-09 3.30E+02 -1.17E-05 -1.31E+03 -1.17E-01 4.58E-09 5.63E-01 4.58E-05 5.75E-02 5.13E-06 2.47E-05 2.01 E-09 3.31 E+02 -1.17E-05 -1.31E+03 -1.17E-01 4.58E-09 5.63E-01 4.58E-05 5.75E-02 5.13E-06 2.47E-05 2.01 E-09 3.32E+02 -1.17E-05 -1.31 E+03 -1.17E-01 4.58E-09 5.63E-01 4.58E-05 5.75E-02 5.13E-06 2.47E-05 2.01 E-09 3.33E+02 -1.16E-05 -1.31 E+03 -1.16E-01 4.57E-09 5.63E-01 4.57E-05 5.75E-02 5.1 1E-06 2.47E-05 2.01 E-09 3.34E+02 -1.16E-05 -1.31E+03 -1.16E-01 4.57E-09 5.63E-01 4.57E-05 5.75E-02 5.09E-06 2.47E-05 2.00E-09 3.35E+02 -1.16E-05 -1.31 E+03 -1.16E-01 4.57E-09 5.63E-01 4.57E-05 5.75E-02 5.09E-06 2.47E-05 2.00E-09

3.36E+02 -1.16E-05 -1.31E+03 -1.16E-01 4.56E-09 5.63E-01 4.56E-05 5.75E-02 5.09E-06 2.47E-05 2.00E-09 3.37E+02 -1.16E-05 -1.31E+03 -1.16E-01 4.56E-09 5.63E-01 4.56E-05 5.75E-02 5.09E-06 2.47E-05 2.00E-09 3.38E+02 -1.16E-05 -1.31E+03 -1.16E-01 4.56E-09 5.63E-01 4.56E-05 5.75E-02 5.09E-06 2.47E-05 2.OOE-09 3.39E+02 -1.16E-05 -1.31E+03 -1.16E-01 4.55E-09 5.63E-01 4.55E-05 5.75E-02 5.09E-06 2.47E-05 2.00E-09 3.40E+02 -1.16E-05 -1.31E+03 -1.16E-01 4.55E-09 5.63E-01 4.55E-05 5.75E-02 5.09E-06 2.47E-05 2.00E-09 3.41E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.55E-09 5.63E-01 4.55E-05 5.75E-02 5.07E-06 2.47E-05 2.00E-09 3.42E+02 -1.1SE-05 -1.31E+03 -1.15E-01 4.54E-09 5.63E-01 4.54E-05 5.75E-02 5.04E-06 2.47E-05 1.99E-09 3.43E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.54E-09 5.63E-01 4.54E-05 5.75E-02 5.04E-06 2.47E-05 1.99E-09 3.44E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.54E-09 5.63E-01 4.54E-05 5.75E-02 5.04E-06 2.47E-05 1.99E-09 3.45E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.53E-09 5.64E-01 4.53E-05 5.75E-02 5.04E-06 2.47E-05 1.99E-09 3.46E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.53E-09 5.64E-01 4.53E-05 5.75E-02 5.04E-06 2.47E-05 1.99E-09 3.47E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.53E-09 5.64E-01 4.53E-05 5.75E-02 5.04E-06 2.47E-05 1.99E-09 3.48E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.52E-09 5.64E-01 4.52E-05 5.75E-02 5.04E-06 2.47E-05 1.98E-09 3.49E+02 -1.15E-05 -1.31E+03 -1.15E-01 4.52E-09 5.64E-01 4.52E-05 5.75E-02 5.04E-06 2.47E-05 1.98E-09 3.50E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.52E-09 5.64E-01 4.52E-05 5.75E-02 5.02E-06 2.47E-05 1.98E-09 3.51E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.52E-09 5.64E-01 4.52E-05 5.75E-02 5.00E-06 2.47E-05 1.98E-09 3.52E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.51E-09 5.64E-01 4.51E-05 5.75E-02 5.00E-06 2.47E-05 1.98E-09 3.53E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.51E-09 5.64E-01 4.51E-05 5.75E-02 5.00E-06 2.47E-05 1.98E-09 3.54E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.51E-09 5.64E-01 4.51E-05 5.75E-02 5.00E-06 2.47E-05 1.98E-09 3.55E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.50E-09 5.64E-01 4.50E-05 5.75E-02 5.00E-06 2.47E-05 1.98E-09 3.56E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.50E-09 5.64E-01 4.50E-05 5.75E-02 5.OOE-06 2.47E-05 1.97E-09 3.57E+02 -1.14E-05 -1.31E+03 -1.14E-01 4.50E-09 5.64E-01 4.50E-05 5.75E-02 5.00E-06 2.47E-05 1.97E-09 3.58E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.50E-09 5.64E-01 4.50E-05 5.75E-02 4.98E-06 2.47E-05 1.97E-09 3.59E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.49E-09 5.64E-01 4.49E-05 5.75E-02 4.96E-06 2.47E-05 1.97E-09 3.60E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.49E-09 5.64E-01 4.49E-05 5.75E-02 4.96E-06 2.47E-05 1.97E-09 3.61E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.49E-09 5.64E-01 4.49E-05 5.75E-02 4.96E-06 2.47E-05 1.97E-09 3.62E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.48E-09 5.64E-01 4.48E-05 5.75E-02 4.96E-06 2.47E-05 1.97E-09 3.63E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.48E-09 5.64E-01 4.48E-05 5.75E-02 4.96E-06 2.47E-05 1.96E-09 3.64E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.48E-09 5.64E-01 4.48E-05 5.75E-02 4.96E-06 2.47E-05 1.96E-09 3.65E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.48E-09 5.64E-01 4.48E-05 5.75E-02 4.96E-06 2.47E-05 1.96E-09 3.66E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.47E-09 5.64E-01 4.47E-05 5.75E-02 4.96E-06 2.47E-05 1.96E-09 3.67E+02 -1.13E-05 -1.31E+03 -1.13E-01 4.47E-09 5.65E-01 4.47E-05 5.75E-02 4.96E-06 2.48E-05 1.96E-09 3.68E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.47E-09 5.65E-01 4.47E-05 5.75E-02 4.93E-06 2.48E-05 1.96E-09 3.69E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.46E-09 5.65E-01 4.46E-05 5.75E-02 4.91E-06 2.48E-05 1.96E-09 3.70E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.46E-09 5.65E-01 4.46E-05 5.75E-02 4.91E-06 2.48E-05 1.96E-09 3.71E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.46E-09 5.65E-01 4.46E-05 5.75E-02 4.91E-06 2.48E-05 1.96E-09 3.72E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.46E-09 5.65E-01 4.46E-05 5.75E-02 4.91E-06 2.48E-05 1.96E-09 3.73E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.45E-09 5.65E-01 4.45E-05 5.75E-02 4.91E-06 2.48E-05 1.95E-09

3.74E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.45E-09 5.65E-01 4.45E-05 5.75E-02 4.91 E-06 2.48E-05 1.95E-09 3.75E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.45E-09 5.65E-01 4.45E-05 5.75E-02 4.91 E-06 2.48E-05 1.95E-09 3.76E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.45E-09 5.65E-01 4.45E-05 5.75E-02 4.91E-06 2.48E-05 1.95E-09 3.77E+02 -1.12E-05 -1.31E+03 -1.12E-01 4.44E-09 5.65E-01 4.44E-05 5.75E-02 4.91 E-06 2.48E-05 1.95E-09 3.78E+02 -1.11E-05 -1.31E+03 -1.11E-01 4.44E-09 5.65E-01 4.44E-05 5.75E-02 4.89E-06 2.48E-05 1.95E-09 3.79E+02 -1.11E-05 -1.31E+03 -1.11E-01 4.44E-09 5.65E-01 4.44E-05 5.75E-02 4.87E-06 2.48E-05 1.95E-09 3.80E+02 -1.11 E-05 -1.31 E+03 -1.11E-01 4.43E-09 5.65E-01 4.43E-05 5.75E-02 4.87E-06 2.48E-05 1.95E-09 3.81 E+02 -1.11E-05 -1.31 E+03 -1.11E-01 4.43E-09 5.65E-01 4.43E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.82E+02 -1.11E-05 -1.31E+03 -1.11E-01 4.43E-09 5.65E-01 4.43E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.83E+02 -1.11E-05 -1.31 E+03 -1.11E-01 4.43E-09 5.65E-01 4.43E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.84E+02 -1.11 E-05 -1.31E+03 -1.11 E-01 4.42E-09 5.65E-01 4.42E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.85E+02 -1.11E-05 -1.31E+03 -1.11E-01 4.42E-09 5.65E-01 4.42E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.86E+02 -1.11E-05 -1.31 E+03 -1.11E-01 4.42E-09 5.65E-01 4.42E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.87E+02 -1.11E-05 -1.31 E+03 -1.11E-01 4.42E-09 5.65E-01 4.42E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.88E+02 -1.11E-05 -1.31 E+03 -1.11 E-01 4.41 E-09 5.65E-01 4.41 E-05 5.75E-02 4.87E-06 2.48E-05 1.94E-09 3.89E+02 -1.10E-05 -1.31E+03 -1.10E-01 4.41 E-09 5.66E-01 4.41 E-05 5.75E-02 4.85E-06 2.48E-05 1.93E-09 3.90E+02 -1.10E-05 -1.31E+03 -1.10E-01 4.41 E-09 5.66E-01 4.41 E-05 5.75E-02 4.82E-06 2.48E-05 1.93E-09 3.91E+02 -1.10E-05 -1.31E+03 -1.10E-01 4.41 E-09 5.66E-01 4.41 E-05 5.75E-02 4.82E-06 2.48E-05 1.93E-09 3.92E+02 -1.10E-05 -1.31E+03 -1.10E-01 4.40E-09 5.66E-01 4.40E-05 5.75E-02 4.82E-06 2.48E-05 1.93E-09 3.93E+02 -1.10E-05 -1.31E+03 -1.10E-01 4.40E-09 5.66E-01 4.40E-05 5.75E-02 4.82E-06 2.48E-05 1.93E-09 3.94E+02 -1.10E-05 -1.31 E+03 -1.1OE-01 4.40E-09 5.66E-01 4.40E-05 5.75E-02 4.82E-06 2.48E-05 1.93E-09 3.95E+02 -1.10E-05 -1.32E+03 -1.10E-01 4.40E-09 5.66E-01 4.40E-05 5.79E-02 4.82E-06 2.48E-05 1.93E-09 3.96E+02 -1.10E-05 -1.32E+03 -1.10E-01 4.39E-09 5.66E-01 4.39E-05 5.79E-02 4.82E-06 2.48E-05 1.93E-09 3.97E+02 -1.10E-05 -1.32E+03 -1.10E-01 4.39E-09 5.66E-01 4.39E-05 5.79E-02 4.82E-06 2.48E-05 1.93E-09 3.98E+02 -1.10E-05 -1.32E+03 -1.10E-01 4.39E-09 5.66E-01 4.39E-05 5.79E-02 4.82E-06 2.48E-05 1.93E-09 3.99E+02 -1.10E-05 -1.32E+03 -1.10E-01 4.39E-09 5.66E-01 4.39E-05 5.79E-02 4.82E-06 2.48E-05 1.93E-09 4.00E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.39E-09 5.66E-01 4.39E-05 5.79E-02 4.80E-06 2.48E-05 1.93E-09 4.01 E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.38E-09 5.66E-01 4.38E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.02E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.38E-09 5.66E-01 4.38E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.03E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.38E-09 5.66E-01 4.38E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.04E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.38E-09 5.66E-01 4.38E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.05E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.37E-09 5.66E-01 4.37E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.06E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.37E-09 5.66E-01 4.37E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.07E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.37E-09 5.66E-01 4.37E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.08E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.37E-09 5.66E-01 4.37E-05 5.79E-02 4.78E-06 2.48E-05 1.92E-09 4.09E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.36E-09 5.66E-01 4.36E-05 5.79E-02 4.78E-06 2.48E-05 1.91 E-09 4.1 OE+02 -1.09E-05 -1.32E+03 -1.09E-01 4.36E-09 5.66E-01 4.36E-05 5.79E-02 4.78E-06 2.48E-05 1.91 E-09 4.11 E+02 -1.09E-05 -1.32E+03 -1.09E-01 4.36E-09 5.66E-01 4.36E-05 5.79E-02 4.78E-06 2.48E-05 1.91 E-09

4.12E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.36E-09 5.67E-01 4.36E-05 5.79E-02 4.76E-06 2.49E-05 1.91 E-09 4.13E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.36E-09 5.67E-01 4.36E-05 5.79E-02 4.74E-06 2.49E-05 1.91 E-09 4.14E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.35E-09 5.67E-01 4.35E-05 5.79E-02 4.74E-06 2.49E-05 1.91 E-09 4.15E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.35E-09 5.67E-01 4.35E-05 5.79E-02 4.74E-06 2.49E-05 1.91E-09 4.16E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.35E-09 5.67E-01 4.35E-05 5.79E-02 4.74E-06 2.49E-05 1.91E-09 4.17E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.35E-09 5.67E-01 4.35E-05 5.79E-02 4.74E-06 2.49E-05 1.91 E-09 4.18E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.34E-09 5.67E-01 4.34E-05 5.79E-02 4.74E-06 2.49E-05 1.91 E-09 4.19E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.34E-09 5.67E-01 4.34E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.20E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.34E-09 5.67E-01 4.34E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.21 E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.34E-09 5.67E-01 4.34E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.22E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.34E-09 5.67E-01 4.34E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.23E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.33E-09 5.67E-01 4.33E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.24E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.33E-09 5.67E-01 4.33E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.25E+02 -1.08E-05 -1.32E+03 -1.08E-01 4.33E-09 5.67E-01 4.33E-05 5.79E-02 4.74E-06 2.49E-05 1.90E-09 4.26E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.33E-09 5.67E-01 4.33E-05 5.79E-02 4.71 E-06 2.49E-05 1.90E-09 4.27E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.32E-09 5.67E-01 4.32E-05 5.79E-02 4.69E-06 2.49E-05 1.90E-09 4.28E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.32E-09 5.67E-01 4.32E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.29E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.32E-09 5.67E-01 4.32E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.30E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.32E-09 5.67E-01 4.32E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.31 E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.32E-09 5.67E-01 4.32E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.32E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.31 E-09 5.67E-01 4.31 E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.33E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.31 E-09 5.67E-01 4.31 E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.34E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.31 E-09 5.67E-01 4.31 E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.35E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.31 E-09 5.68E-01 4.31 E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.36E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.31 E-09 5.68E-01 4.31 E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.37E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.30E-09 5.68E-01 4.30E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.38E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.30E-09 5.68E-01 4.30E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.39E+02 -1.07E-05 -1.32E+03 -1.07E-01 4.30E-09 5.68E-01 4.30E-05 5.79E-02 4.69E-06 2.49E-05 1.89E-09 4.40E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.30E-09 5.68E-01 4.30E-05 5.79E-02 4.67E-06 2.49E-05 1.89E-09 4.41 E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.30E-09 5.68E-01 4.30E-05 5.79E-02 4.65E-06 2.49E-05 1.89E-09 4.42E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.29E-09 5.68E-01 4.29E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.43E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.29E-09 5.68E-01 4.29E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.44E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.29E-09 5.68E-01 4.29E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.45E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.29E-09 5.68E-01 4.29E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.46E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.29E-09 5.68E-01 4.29E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.47E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.28E-09 5.68E-01 4.28E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.48E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.28E-09 5.68E-01 4.28E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.49E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.28E-09 5.68E-01 4.28E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09

4.50E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.28E-09 5.68E-01 4.28E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.51 E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.28E-09 5.68E-01 4.28E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.52E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.27E-09 5.68E-01 4.27E-05 5.79E-02 4.65E-06 2.49E-05 1.88E-09 4.53E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.27E-09 5.68E-01 4.27E-05 5.79E-02 4.65E-06 2.49E-05 1.87E-09 4.54E+02 -1.06E-05 -1.32E+03 -1.06E-01 4.27E-09 5.68E-01 4.27E-05 5.79E-02 4.65E-06 2.49E-05 1.87E-09 4.55E+02 -1.05E-05 -1.32E+03 -1.OSE-01 4.27E-09 5.68E-01 4.27E-05 5.79E-02 4.63E-06 2.49E-05 1.87E-09 4.56E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.27E-09 5.68E-01 4.27E-05 5.79E-02 4.61 E-06 2.49E-05 1.87E-09 4.57E+02 -1.05E-05 -1.32E+03 -1.OSE-01 4.26E-09 5.68E-01 4.26E-05 5.79E-02 4.61 E-06 2.49E-05 1.87E-09 4.58E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.26E-09 5.69E-01 4.26E-05 5.79E-02 4.61 E-06 2.50E-05 1.87E-09 4.59E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.26E-09 5.69E-01 4.26E-05 5.79E-02 4.61 E-06 2.50E-05 1.87E-09 4.60E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.26E-09 5.69E-01 4.26E-05 5.79E-02 4.61 E-06 2.50E-05 1.87E-09 4.61 E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.26E-09 5.69E-01 4.26E-05 5.79E-02 4.61 E-06 2.50E-05 1.87E-09 4.62E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.26E-09 5.69E-01 4.26E-05 5.79E-02 4.61 E-06 2.50E-05 1.87E-09 4.63E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.25E-09 5.69E-01 4.25E-05 5.79E-02 4.61 E-06 2.50E-05 1.87E-09 4.64E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.25E-09 5.69E-01 4.25E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.65E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.25E-09 5.69E-01 4.25E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.66E+02 -1.05E-OS -1.32E+03 -1.05E-01 4.25E-09 5.69E-01 4.25E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.67E+02 -1.05E-05 -1.32E+03 -1.05E-01 4.25E-09 5.69E-01 4.25E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.68E+02 -1.05E-05 -1.32E+03 -1.OSE-01 4.24E-09 5.69E-01 4.24E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.69E+02 -1.OSE-OS -1.32E+03 -1.05E-01 4.24E-09 5.69E-01 4.24E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.70E+02 -1.05E-05 -1.32E+03 -1.OSE-01 4.24E-09 5.69E-01 4.24E-05 5.79E-02 4.61 E-06 2.50E-05 1.86E-09 4.71 E+02 -1.04E-OS -1.32E+03 -1.04E-01 4.24E-09 5.69E-01 4.24E-05 5.79E-02 4.58E-06 2.50E-05 1.86E-09 4.72E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.24E-09 5.69E-01 4.24E-05 5.79E-02 4.56E-06 2.50E-05 1.86E-09 4.73E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.23E-09 5.69E-01 4.23E-05 5.79E-02 4.56E-06 2.50E-05 1.86E-09 4.74E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.23E-09 5.69E-01 4.23E-05 5.79E-02 4.56E-06 2.50E-05 1.86E-09 4.75E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.23E-09 5.69E-01 4.23E-05 5.79E-02 4.56E-06 2.50E-05 1.86E-09 4.76E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.23E-09 5.69E-01 4.23E-05 5.79E-02 4.56E-06 2.50E-05 1.86E-09 4.77E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.23E-09 5.69E-01 4.23E-05 5.79E-02 4.56E-06 2.50E-OS 1.86E-09 4.78E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.23E-09 5.69E-01 4.23E-05 5.79E-02 4.56E-06 2.50E-05 1.86E-09 4.79E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.22E-09 5.69E-01 4.22E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.80E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.22E-09 5.69E-01 4.22E-05 5.79E-02 4.56E-06 2.50E-OS 1.85E-09 4.81 E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.22E-09 5.69E-01 4.22E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.82E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.22E-09 5.70E-01 4.22E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.83E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.22E-09 5.70E-01 4.22E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.84E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.22E-09 5.70E-01 4.22E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.85E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.21 E-09 5.70E-01 4.21 E-05 5.79E-02 4.56E-06 2.50E-OS 1.85E-09 4.86E+02 -1.04E-OS -1.32E+03 -1.04E-01 4.21 E-09 5.70E-01 4.21 E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.87E+02 -1.04E-OS -1.32E+03 -1.04E-01 4.21 E-09 5.70E-01 4.21 E-05 5.79E-02 4.56E-06 2.50E-OS 1.85E-09

4.88E+02 -1.04E-05 -1.32E+03 -1.04E-01 4.21 E-09 5.70E-01 4.21 E-05 5.79E-02 4.56E-06 2.50E-05 1.85E-09 4.89E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.21 E-09 5.70E-01 4.21 E-05 5.83E-02 4.54E-06 2.50E-05 1.85E-09 4.90E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.21 E-09 5.70E-01 4.21 E-05 5.83E-02 4.52E-06 2.50E-05 1.85E-09 4.91 E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.20E-09 5.70E-01 4.20E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.92E+02 -1.03E205 -1.33E+03 -1.03E-01 4.20E-09 5.70E-01 4.20E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.93E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.20E-09 5.70E-01 4.20E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.94E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.20E-09 5.70E-01 4.20E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.95E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.20E-09 5.70E-01 4.20E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.96E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.19E-09 5.70E-01 4.19E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.97E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.19E-09 5.70E-01 4.19E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.98E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.19E-09 5.70E-01 4.19E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 4.99E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.19E-09 5.70E-01 4.19E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 5.00E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.19E-09 5.70E-01 4.19E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 5.01 E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.19E-09 5.70E-01 4.19E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 5.02E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.18E-09 5.70E-01 4.18E-05 5.83E-02 4.52E-06 2.50E-05 1.84E-09 5.03E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.18E-09 5.70E-01 4.18E-05 5.83E-02 4.52E-06 2.50E-05 1.83E-09 5.04E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.18E-09 5.70E-01 4.18E-05 5.83E-02 4.52E-06 2.50E-05 1.83E-09 5.05E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.18E-09 5.70E-01 4.18E-05 5.83E-02 4.52E-06 2.50E-05 1.83E-09 5.06E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.18E-09 5.71 E-01 4.18E-05 5.83E-02 4.52E-06 2.50E-05 1.83E-09 5.07E+02 -1.03E-05 -1.33E+03 -1.03E-01 4.18E-09 5.71 E-01 4.18E-05 5.83E-02 4.52E-06 2.50E-05 1.83E-09 5.08E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.18E-09 5.71 E-01 4.18E-05 5.83E-02 4.50E-06 2.50E-05 1.83E-09 5.09E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.17E-09 5.71 E-01 4.17E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.10E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.17E-09 5.71E-01 4.17E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.11 E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.17E-09 5.71E-01 4.17E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.12E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.17E-09 5.71 E-01 4.17E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.13E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.17E-09 5.71E-01 4.17E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.14E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.17E-09 5.71 E-01 4.17E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.15E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.16E-09 5.71 E-01 4.16E-05 5.83E-02 4.47E-06 2.50E-05 1.83E-09 5.16E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.16E-09 5.71 E-01 4.16E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.17E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.16E-09 5.71E-01 4.16E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.18E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.16E-09 5.71E-01 4.16E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.19E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.16E-09 5.71 E-01 4.16E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.20E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.16E-09 5.71E-01 4.16E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.21 E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.22E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71 E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.23E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71 E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.24E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71 E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.25E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71 E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09

5.26E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.27E+02 -1.02E-05 -1.33E+03 -1.02E-01 4.15E-09 5.71E-01 4.15E-05 5.83E-02 4.47E-06 2.50E-05 1.82E-09 5.28E+02 -1.01E-05 -1.33E+03 -1.OIE-01 4.14E-09 5.71E-01 4.14E-05 5.83E-02 4.45E-06 2.50E-05 1.82E-09 5.29E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.14E-09 5.71E-01 4.14E-05 5.83E-02 4.43E-06 2.50E-05 1.82E-09 5.30E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.14E-09 5.72E-01 4.14E-05 5.83E-02 4.43E-06 2.51E-05 1.82E-09 5.31E+02 -1.OIE-05 -1.33E+03 -1.01E-01 4.14E-09 5.72E-01 4.14E-05 5.83E-02 4.43E-06 2.51E-05 1.82E-09 5.32E+02 -1.012-05 -1.33E+03 -1.01E-01 4.14E-09 5.72E-01 4.14E-05 5.83E-02 4.43E-06 2.51E-05 1.82E-09 5.33E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.14E-09 5.72E-01 4.14E-05 5.83E-02 4.43E-06 2.51E-05 1.82E-09 5.34E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.35E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.36E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.37E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.38E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.39E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.40E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.13E-09 5.72E-01 4.13E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.41E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.12E-09 5.72E-01 4.12E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.42E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.12E-09 5.72E-01 4.12E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.43E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.12E-09 5.72E-01 4.12E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.44E+02 -1.01E-05 -1.33E+03 -1.OIE-01 4.12E-09 5.72E-01 4.12E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.45E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.12E-09 5.72E-01 4.12E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.46E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.12E-09 5.72E-01 4.12E-05 5.83E-02 4.43E-06 2.51E-05 1.81E-09 5.47E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.43E-06 2.51E-05 1.80E-09 5.48E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.43E-06 2.51E-05 1.80E-09 5.49E+02 -1.01E-05 -1.33E+03 -1.01E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.43E-06 2.51E-05 1.80E-09 5.50E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.41E-06 2.51E-05 1.80E-09 5.51E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.52E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.53E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.11E-09 5.72E-01 4.11E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.54E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.55E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.56E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.57E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.58E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.59E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.60E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.10E-09 5.73E-01 4.10E-05 5.83E-02 4.39E-06 2.51E-05 1.80E-09 5.61 E+02 -1.00E-05 -1.33E+03 -1.00E-01 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.39E-06 2.51 E-05 1.80E-09 5.62E+02 -9.99E-06 -1.33E+03 -9.99E-02 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.38E-06 2.51 E-05 1.79E-09 5.63E+02 -9.99E-06 -1.33E+03 -9.99E-02 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.38E-06 2.51E-05 1.79E-09

5.64E+02 -9.99E-06 -1.33E+03 -9.99E-02 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.38E-06 2.51E-05 1.79E-09 5.65E+02 -9.98E-06 -1.33E+03 -9.98E-02 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.38E-06 2.51 E-05 1.79E-09 5.66E+02 -9.98E-06 -1.33E+03 -9.98E-02 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.38E-06 2.51 E-05 1.79E-09 5.67E+02 -9.97E-06 -1.33E+03 -9.97E-02 4.09E-09 5.73E-01 4.09E-05 5.83E-02 4.38E-06 2.51 E-05 1.79E-09 5.68E+02 -9.97E-06 -1.33E+03 -9.97E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.37E-06 2.51 E-05 1.79E-09 5.69E+02 -9.96E-06 -1.33E+03 -9.96E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.37E-06 2.51 E-05 1.79E-09 5.70E+02 -9.96E-06 -1.33E+03 -9.96E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.37E-06 2.51 E-05 1.79E-09 5.71 E+02 -9.96E-06 -1.33E+03 -9.96E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.37E-06 2.51 E-05 1.79E-09 5.72E+02 -9.95E-06 -1.33E+03 -9.95E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.37E-06 2.51 E-05 1.79E-09 5.73E+02 -9.95E-06 -1.33E+03 -9.95E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.36E-06 2.51 E-05 1.79E-09 5.74E+02 -9.94E-06 -1.33E+03 -9.94E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.36E-06 .2.51 E-05 1.79E-09 5.75E+02 -9.94E-06 -1.33E+03 -9.94E-02 4.08E-09 5.73E-01 4.08E-05 5.83E-02 4.36E-06 2.51 E-05 1.79E-09 5.76E+02 -9.94E-06 -1.33E+03 -9.94E-02 4.07E-09 5.73E-01 4.07E-05 5.83E-02 4.36E-06 2.51 E-05 1.79E-09 5.77E+02 -9.93E-06 -1.33E+03 -9.93E-02 4.07E-09 5.73E-01 4.07E-05 5.83E-02 4.36E-06 2.51 E-05 1.79E-09 5.78E+02 -9.93E-06 -1.33E+03 -9.93E-02 4.07E-09 5.73E-01 4.07E-05 5.83E-02 4.36E-06 2.51 E-05 1.79E-09 5.79E+02 -9.92E-06 -1.33E+03 -9.92E-02 4.07E-09 5.74E-01 4.07E-05 5.83E-02 4.35E-06 2.52E-05 1.79E-09 5.80E+02 -9.92E-06 -1.33E+03 -9.92E-02 4.07E-09 5.74E-01 4.07E-05 5.83E-02 4.35E-06 2.52E-05 1.79E-09 5.81E+02 -9.92E-06 -1.33E+03 -9.92E-02 4.07E-09 5.74E-01 4.07E-05 5.83E-02 4.35E-06 2.52E-05 1.79E-09 5.82E+02 -9.91 E-06 -1.33E+03 -9.91 E-02 4.07E-09 5.74E-01 4.07E-05 5.83E.02 4.35E-06 2.52E-05 1.79E-09 5.83E+02 -9.91 E-06 -1.33E+03 -9.91 E-02 4.06E-09 5.74E-01 4.06E-05 5.83E-02 4.35E-06 2.52E-05 1.78E-09 5.84E+02 -9.90E-06 -1.33E+03 -9.90E-02 4.06E-09 5.74E-01 4.06E-05 5.83E-02 4.34E-06 2.52E-05 1.78E-09 5.85E+02 -9.90E-06 -1.33E+03 -9.90E-02 4.06E-09 5.74E-01 4.06E-05 5.83E-02 4.34E-06 2.52E-05 1.78E-09 5.86E+02 -9.90E-06 -1.33E+03 -9.90E-02 4.06E-09 5.74E-01 4.06E-05 5.83E-02 4.34E-06 2.52E-05 1.78E-09 5.87E+02 -9.89E-06 -1.33E+03 -9.89E-02 4.06E-09 5.74E-01 4.06E-05 5.83E-02 4.34E-06 2.52E-05 1.78E-09 5.88E+02 -9.89E-06 -1.34E+03 -9.89E-02 4.06E-09 5.74E-01 4.06E-05 5.88E-02 4.34E-06 2.52E-05 1.78E-09 5.89E+02 -9.88E-06 -1.34E+03 -9.88E-02 4.06E-09 5.74E-01 4.06E-05 5.88E-02 4.34E-06 2.52E-05 1.78E-09 5.90E+02 -9.88E-06 -1.34E+03 -9.88E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.33E-06 2.52E-05 1.78E-09 5.91 E+02 -9.88E-06 -1.34E+03 -9.88E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.33E-06 2.52E-05 1.78E-09 5.92E+02 -9.87E-06 -1.34E+03 -9.87E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.33E-06 2.52E-05 1.78E-09 5.93E+02 -9.87E-06 -1.34E+03 -9.87E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.33E-06 2.52E-05 1.78E-09 5.94E+02 -9.86E-06 -1.34E+03 -9.86E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.33E-06 2.52E-05 1.78E-09 5.95E+02 -9.86E-06 -1.34E+03 -9.86E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.32E-06 2.52E-05 1.78E-09 5.96E+02 -9.86E-06 -1.34E+03 -9.86E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.32E-06 2.52E-05 1.78E-09 5.97E+02 -9.85E-06 -1.34E+03 -9.85E-02 4.05E-09 5.74E-01 4.05E-05 5.88E-02 4.32E-06 2.52E-05 1.78E-09 5.98E+02 -9.85E-06 -1.34E+03 -9.85E-02 4.04E-09 5.74E-01 4.04E-05 5.88E-02 4.32E-06 2.52E-05 1.77E-09 5.99E+02 -9.84E-06 -1.34E+03 -9.84E-02 4.04E-09 5.74E-01 4.04E-05 5.88E-02 4.32E-06 2.52E-05 1.77E-09 6.00E+02 -9.84E-06 -1.34E+03 -9.84E-02 4.04E-09 5.74E-01 4.04E-05 5.88E-02 4.32E-06 2.52E-05 1.77E-09 6.01 E+02 -9.84E-06 -1.34E+03 -9.84E-02 4.04E-09 5.74E-01 4.04E-05 5.88E-02 4.32E-06 2.52E-05 1.77E-09

6.02E+02 -9.83E-06 -1.34E+03 -9.83E-02 4.04E-09 5.74E-01 4.04E-05 5.88E-02 4.31 E-06 2.52E-05 1.77E-09 6.03E+02 -9.83E-06 -1.34E+03 -9.83E-02 4.04E-09 5.75E-01 4.04E-05 5.88E-02 4.31E-06 2.52E-05 1.77E-09 6.04E+02 -9.83E-06 -1.34E+03 -9.83E-02 4.04E-09 5.75E-01 4.04E-05 5.88E-02 4.31 E-06 2.52E-05 1.77E-09 6.05E+02 -9.82E-06 -1.34E+03 -9.82E-02 4.04E-09 5.75E-01 4.04E-05 5.88E-02 4.31 E-06 2.52E-05 1.77E-09 6.06E+02 -9.82E-06 -1.34E+03 -9.82E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.31 E-06 2.52E-05 1.77E-09 6.07E+02 -9.81E-06 -1.34E+03 -9.81E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.08E+02 -9.81 E-06 -1.34E+03 -9.81 E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.09E+02 -9.81 E-06 -1.34E+03 -9.81 E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.10E+02 -9.80E-06 -1.34E+03 -9.80E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.11E+02 -9.80E-06 -1.34E+03 -9.80E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.12E+02 -9.80E-06 -1.34E+03 -9.80E-02 4.03E-09 5.75E-01 4.03E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.13E+02 -9.79E-06 -1.34E+03 -9.79E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.30E-06 2.52E-05 1.77E-09 6.14E+02 -9.79E-06 -1.34E+03 -9.79E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.15E+02 -9.78E-06 -1.34E+03 -9.78E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.16E+02 -9.78E-06 -1.34E+03 -9.78E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.17E+02 -9.78E-06 -1.34E+03 -9.78E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.18E+02 -9.77E-06 -1.34E+03 -9.77E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.19E+02 -9.77E-06 -1.34E+03 -9.77E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.20E+02 -9.77E-06 -1.34E+03 -9.77E-02 4.02E-09 5.75E-01 4.02E-05 5.88E-02 4.29E-06 2.52E-05 1.76E-09 6.21E+02 -9.76E-06 -1.34E+03 -9.76E-02 4.01E-09 5.75E-01 4.01E-05 5.88E-02 4.28E-06 2.52E-05 1.76E-09 6.22E+02 -9.76E-06 -1.34E+03 -9.76E-02 4.01E-09 5.75E-01 4.01E-05 5.88E-02 4.28E-06 2.52E-05 1.76E-09 6.23E+02 -9.75E-06 -1.34E+03 -9.75E-02 4.01 E-09 5.75E-01 4.01 E-05 5.88E-02 4.28E-06 2.52E-05 1.76E-09 6.24E+02 -9.75E-06 -1.34E+03 -9.75E-02 4.01 E-09 5.75E-01 4.01 E-05 5.88E-02 4.28E-06 2.52E-05 1.76E-09 6.25E+02 -9.75E-06 -1.34E+03 -9.75E-02 4.01 E-09 5.75E-01 4.01 E-05 5.88E-02 4.28E-06 2.52E-05 1.76E-09 6.26E+02 -9.74E-06 -1.34E+03 -9.74E-02 4.01 E-09 5.75E-01 4.01 E-05 5.88E-02 4.27E-06 2.52E-05 1.76E-09 6.27E+02 -9.74E-06 -1.34E+03 -9.74E-02 4.01 E-09 5.75E-01 4.01 E-05 5.88E-02 4.27E-06 2.52E-05 1.76E-09 6.28E+02 -9.74E-06 -1.34E+03 -9.74E-02 4.01E-09 5.76E-01 4.01E-05 5.88E-02 4.27E-06 2.53E-05 1.76E-09 6.29E+02 -9.73E-06 -1.34E+03 -9.73E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.27E-06 2.53E-05 1.76E-09 6.30E+02 -9.73E-06 -1.34E+03 -9.73E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.27E-06 2.53E-05 1.75E-09 6.31 E+02 -9.73E-06 -1.34E+03 -9.73E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.27E-06 2.53E-05 1.75E-09 6.32E+02 -9.72E-06 -1.34E+03 -9.72E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.27E-06 2.53E-05 1.75E-09 6.33E+02 -9.72E-06 -1.34E+03 -9.72E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.26E-06 2.53E-05 1.75E-09 6.34E+02 -9.72E-06 -1.34E+03 -9.72E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.26E-06 2.53E-05 1.75E-09 6.35E+02 -9.71 E-06 -1.34E+03 -9.71 E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.26E-06 2.53E-05 1.75E-09 6.36E+02 -9.71 E-06 -1.34E+03 -9.71 E-02 4.00E-09 5.76E-01 4.00E-05 5.88E-02 4.26E-06 2.53E-05 1.75E-09 6.37E+02 -9.71 E-06 -1.34E+03 -9.71 E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.26E-06 2.53E-05 1.75E-09 6.38E+02 -9.70E-06 -1.34E+03 -9.70E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.26E-06 2.53E-05 1.75E-09 6.39E+02 -9.70E-06 -1.34E+03 -9.70E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09

6.40E+02 -9.69E-06 -1.34E+03 -9.69E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09 6.41E+02 -9.69E-06 -1.34E+03 -9.69E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09 6.42E+02 -9.69E-06 -1.34E+03 -9.69E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09 6.43E+02 -9.68E-06 -1.34E+03 -9.68E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09 6.44E+02 -9.68E-06 -1.34E+03 -9.68E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09 6.45E+02 -9.68E-06 -1.34E+03 -9.68E-02 3.99E-09 5.76E-01 3.99E-05 5.88E-02 4.25E-06 2.53E-05 1.75E-09 6.46E+02 -9.67E-06 -1.34E+03 -9.67E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.24E-06 2.53E-05 1.75E-09 6.47E+02 -9.67E-06 -1.34E+03 -9.67E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.24E-06 2.53E-05 1.75E-09 6.48E+02 -9.67E-06 -1.34E+03 -9.67E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.24E-06 2.53E-05 1.75E-09 6.49E+02 -9.66E-06 -1.34E+03 -9.66E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.24E-06 2.53E-05 1.75E-09 6.50E+02 -9.66E-06 -1.34E+03 -9.66E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.24E-06 2.53E-05 1.75E-09 6.51 E+02 -9.66E-06 -1.34E+03 -9.66E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.24E-06 2.53E-05 1.75E-09 6.52E+02 -9.65E-06 -1.34E+03 -9.65E-02 3.98E-09 5.76E-01 3.98E-05 5.88E-02 4.23E-06 2.53E-05 1.75E-09 6.53E+02 -9.65E-06 -1.34E+03 -9.65E-02 3.98E-09 5.77E-01 3.98E-05 5.88E-02 4.23E-06 2.53E-05 1.75E-09 6.54E+02 -9.65E-06 -1.34E+03 -9.65E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.23E-06 2.53E-05 1.74E-09 6.55E+02 -9.64E-06 -1.34E+03 -9.64E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.23E-06 2.53E-05 1.74E-09 6.56E+02 -9.64E-06 -1.34E+03 -9.64E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.23E-06 2.53E-05 1.74E-09 6.57E+02 -9.64E-06 -1.34E+03 -9.64E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.23E-06 2.53E-05 1.74E-09 6.58E+02 -9.63E-06 -1.34E+03 -9.63E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.23E-06 2.53E-05 1.74E-09 6.59E+02 -9.63E-06 -1.34E+03 -9.63E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.22E-06 2.53E-05 1.74E-09 6.60E+02 -9.63E-06 -1.34E+03 -9.63E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.22E-06 2.53E-05 1.74E-09 6.61 E+02 -9.62E-06 -1.34E+03 -9.62E-02 3.97E-09 5.77E-01 3.97E-05 5.88E-02 4.22E-06 2.53E-05 1.74E-09 6.62E+02 -9.62E-06 -1.34E+03 -9.62E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.22E-06 2.53E-05 1.74E-09 6.63E+02 -9.62E-06 -1.34E+03 -9.62E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.22E-06 2.53E-05 1.74E-09 6.64E+02 -9.61 E-06 -1.34E+03 -9.61 E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.22E-06 2.53E-05 1.74E-09 6.65E+02 -9.61 E-06 -1.34E+03 -9.61 E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.21 E-06 2.53E-05 1.74E-09 6.66E+02 -9.61 E-06 -1.34E+03 -9.61 E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.21 E-06 2.53E-05 1.74E-09 6.67E+02 -9.60E-06 -1.34E+03 -9.60E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.21 E-06 2.53E-05 1.74E-09 6.68E+02 -9.60E-06 -1.34E+03 -9.60E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.21E-06 2.53E-05 1.74E-09 6.69E+02 -9.60E-06 -1.34E+03 -9.60E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.21E-06 2.53E-05 1.74E-09 6.70E+02 -9.59E-06 -1.34E+03 -9.59E-02 3.96E-09 5.77E-01 3.96E-05 5.88E-02 4.21 E-06 2.53E-05 1.74E-09 6.71 E+02 -9.59E-06 -1.34E+03 -9.59E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.21 E-06 2.53E-05 1.73E-09 6.72E+02 -9.59E-06 -1.34E+03 -9.59E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.21 E-06 2.53E-05 1.73E-09 6.73E+02 -9.58E-06 -1.34E+03 -9.58E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.20E-06 2.53E-05 1.73E-09 6.74E+02 -9.58E-06 -1.34E+03 -9.58E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.20E-06 2.53E-05 1.73E-09 6.75E+02 -9.58E-06 -1.34E+03 -9.58E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.20E-06 2.53E-05 1.73E-09 6.76E+02 -9.57E-06 -1.34E+03 -9.57E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.20E-06 2.53E-05 1.73E-09 6.77E+02 -9.57E-06 -1.34E+03 -9.57E-02 3.95E-09 5.77E-01 3.95E-05 5.88E-02 4.20E-06 2.53E-05 1.73E-09

6.78E+02 -9.57E-06 -1.34E+03 -9.57E-02 3.95E-09 5.78E-01 3.95E-05 5.88E-02 4.20E-06 2.54E-05 1.73E-09 6.79E+02 -9.56E-06 -1.34E+03 -9.56E-02 3.95E-09 5.78E-01 3.95E-05 5.88E-02 4.20E-06 2.54E-05 1.73E-09 6.80E+02 -9.56E-06 -1.34E+03 -9.56E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.81E+02 -9.56E-06 -1.34E+03 -9.56E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.82E+02 -9.56E-06 -1.34E+03 -9.56E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.83E+02 -9.55E-06 -1.34E+03 -9.55E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.84E+02 -9.55E-06 -1.34E+03 -9.55E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.85E+02 -9.55E-06 -1.34E+03 -9.55E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.86E+02 -9.54E-06 -1.34E+03 -9.54E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.19E-06 2.54E-05 1.73E-09 6.87E+02 -9.54E-06 -1.34E+03 -9.54E-02 3.94E-09 5.78E-01 3.94E-05 5.88E-02 4.18E-06 2.54E-05 1.73E-09 6.88E+02 -9.54E-06 -1.34E+03 -9.54E-02 3.93E-09 5.78E-01 3.93E-05 5.88E-02 4.18E-06 2.54E-05 1.73E-09 6.89E+02 -9.53E-06 -1.34E+03 -9.53E-02 3.93E-09 5.78E-01 3.93E-05 5.88E-02 4.18E-06 2.54E-05 1.72E-09 6.90E+02 -9.53E-06 -1.34E+03 -9.53E-02 3.93E-09 5.78E-01 3.93E-05 5.88E-02 4.18E-06 2.54E-05 1.72E-09 6.91E+02 -9.53E-06 -1.35E+03 -9.53E-02 3.93E-09 5.78E-01 3.93E-05 5.92E-02 4.18E-06 2.54E-05 1.72E-09 6.92E+02 -9.52E-06 -1.35E+03 -9.52E-02 3.93E-09 5.78E-01 3.93E-05 5.92E-02 4.18E-06 2.54E-05 1.72E-09 6.93E+02 -9.52E-06 -1.35E+03 -9.52E-02 3.93E-09 5.78E-01 3.93E-05 5.92E-02 4.18E-06 2.54E-05 1.72E-09 6.94E+02 -9.52E-06 -1.35E+03 -9.52E-02 3.93E-09 5.78E-01 3.93E-05 5.92E-02 4.18E-06 2.54E-05 1.72E-09 6.95E+02 -9.51E-06 -1.35E+03 -9.51E-02 3.93E-09 5.78E-01 3.93E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 6.96E+02 -9.51E-06 -1.35E+03 -9.51E-02 3.93E-09 5.78E-01 3.93E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 6.97E+02 -9.51E-06 -1.35E+03 -9.51E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 6.98E+02 -9.51E-06 -1.35E+03 -9.51E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 6.99E+02 -9.50E-06 -1.35E+03 -9.50E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 7.00E+02 -9.50E-06 -1.35E+03 -9.50E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 7.01E+02 -9.50E-06 -1.35E+03 -9.50E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.17E-06 2.54E-05 1.72E-09 7.02E+02 -9.49E-06 -1.35E+03 -9.49E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.16E-06 2.54E-05 1.72E-09 7.03E+02 -9.49E-06 -1.35E+03 -9.49E-02 3.92E-09 5.78E-01 3.92E-05 5.92E-02 4.16E-06 2.54E-05 1.72E-09 7.04E+02 -9.49E-06 -1.35E+03 -9.49E-02 3.92E-09 5.79E-01 3.92E-05 5.92E-02 4.16E-06 2.54E-05 1.72E-09 7.05E+02 -9.48E-06 -1.35E+03 -9.48E-02 3.92E-09 5.79E-01 3.92E-05 5.92E-02 4.16E-06 2.54E-05 1.72E-09 7.06E+02 -9.48E-06 -1.35E+03 -9.48E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.16E-06 2.54E-05 1.72E-09 7.07E+02 -9.48E-06 -1.35E+03 -9.48E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.16E-06 2.54E-05 1.71E-09 7.08E+02 -9.47E-06 -1.35E+03 -9.47E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.16E-06 2.54E-05 1.71E-09 7.09E+02 -9.47E-06 -1.35E+03 -9.47E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09 7.10E+02 -9.47E-06 -1.35E+03 -9.47E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09 7.11E+02 -9.47E-06 -1.35E+03 -9.47E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09 7.12E+02 -9.46E-06 -1.35E+03 -9.46E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09 7.13E+02 -9.46E-06 -1.35E+03 -9.46E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09 7.14E+02 -9.46E-06 -1.35E+03 -9.46E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09 7.15E+02 -9.45E-06 -1.35E+03 -9.45E-02 3.91E-09 5.79E-01 3.91E-05 5.92E-02 4.15E-06 2.54E-05 1.71E-09

7.16E+02 -9.45E-06 -1.35E+03 -9.45E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.17E+02 -9.45E-06 -1.35E+03 -9.45E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.18E+02 -9.44E-06 -1.35E+03 -9.44E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.19E+02 -9.44E-06 -1.35E+03 -9.44E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.20E+02 -9.44E-06 -1.35E+03 -9.44E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.21E+02 -9.44E-06 -1.35E+03 -9.44E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.22E+02 -9.43E-06 -1.35E+03 -9.43E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.23E+02 -9.43E-06 -1.35E+03 -9.43E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71 E-09 7.24E+02 -9.43E-06 -1.35E+03 -9.43E-02 3.90E-09 5.79E-01 3.90E-05 5.92E-02 4.14E-06 2.54E-05 1.71E-09 7.25E+02 -9.42E-06 -1.35E+03 -9.42E-02 3.89E-09 5.79E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.26E+02 -9.42E-06 -1.35E+03 -9.42E-02 3.89E-09 5.79E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.27E+02 -9.42E-06 -1.35E+03 -9.42E-02 3.89E-09 5.79E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.28E+02 -9.42E-06 -1.35E+03 -9.42E-02 3.89E-09 5.79E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.29E+02 -9.41E-06 -1.35E+03 -9.41E-02 3.89E-09 5.79E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.30E+02 -9.41E-06 -1.35E+03 -9.41E-02 3.89E-09 5.80E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.31E+02 -9.41E-06 -1.35E+03 -9.41E-02 3.89E-09 5.80E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.32E+02 -9.40E-06 -1.35E+03 -9.40E-02 3.89E-09 5.80E-01 3.89E-05 5.92E-02 4.13E-06 2.54E-05 1.71E-09 7.33E+02 -9.40E-06 -1.35E+03 -9.40E-02 3.89E-09 5.80E-01 3.89E-05 5.92E-02 4.12E-06 2.54E-05 1.71E-09 7.34E+02 -9.40E-06 -1.35E+03 -9.40E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.12E-06 2.54E-05 1.70E-09 7.35E+02 -9.39E-06 -1.35E+03 -9.39E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.12E-06 2.54E-05 1.70E-09 7.36E+02 -9.39E-06 -1.35E+03 -9.39E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.12E-06 2.54E-05 1.70E-09 7.37E+02 -9.39E-06 -1.35E+03 -9.39E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.12E-06 2.54E-05 1.70E-09 7.38E+02 -9.39E-06 -1.35E+03 -9.39E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.12E-06 2.54E-05 1.70E-09 7.39E+02 -9.38E-06 -1.35E+03 -9.38E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.12E-06 2.54E-05 1.70E-09 7.40E+02 -9.38E-06 -1.35E+03 -9.38E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.41E+02 -9.38E-06 -1.35E+03 -9.38E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.42E+02 -9.37E-06 -1.35E+03 -9.37E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.43E+02 -9.37E-06 -1.35E+03 -9.37E-02 3.88E-09 5.80E-01 3.88E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.44E+02 -9.37E-06 -1.35E+03 -9.37E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.45E+02 -9.37E-06 -1.35E+03 -9.37E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.46E+02 -9.36E-06 -1.35E+03 -9.36E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.47E+02 -9.36E-06 -1.35E+03 -9.36E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.48E+02 -9.36E-06 -1.35E+03 -9.36E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.11E-06 2.54E-05 1.70E-09 7.49E+02 -9.35E-06 -1.35E+03 -9.35E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.10E-06 2.54E-05 1.70E-09 7.50E+02 -9.35E-06 -1.35E+03 -9.35E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.10E-06 2.54E-05 1.70E-09 7.51E+02 -9.35E-06 -1.35E+03 -9.35E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.10E-06 2.54E-05 1.70E-09 7.52E+02 -9.35E-06 -1.35E+03 -9.35E-02 3.87E-09 5.80E-01 3.87E-05 5.92E-02 4.10E-06 2.54E-05 1.70E-09 7.53E+02 -9.34E-06 -1.35E+03 -9.34E-02 3.86E-09 5.80E-01 3.86E-05 5.92E-02 4.10E-06 2.54E-05 1.70E-09

7.54E+02 -9.34E-06 -1.35E+03 -9.34E-02 3.86E-09 5.80E-01 3.86E-05 5.92E-02 4.10E-06 2.54E-05 1.69E-09 7.55E+02 -9.34E-06 -1.35E+03 -9.34E-02 3.86E-09 5.81E-01 3.86E-05 5.92E-02 4.10E-06 2.55E-05 1.69E-09 7.56E+02 -9.34E-06 -1.35E+03 -9.34E-02 3.86E-09 5.81E-01 3.86E-05 5.92E-02 4.10E-06 2.55E-05 1.69E-09 7.57E+02 -9.33E-06 -1.35E+03 -9.33E-02 3.86E-09 5.81E-01 3.86E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.58E+02 -9.33E-06 -1.35E+03 -9.33E-02 3.86E-09 5.81E-01 3.86E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.59E+02 -9.33E-06 -1.35E+03 -9.33E-02 3.86E-09 5.81E-01 3.86E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.60E+02 -9.32E-06 -1.35E+03 -9.32E-02 3.86E-09 5.81 E-01 3.86E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.61E+02 -9.32E-06 -1.35E+03 -9.32E-02 3.86E-09 5.81E-01 3.86E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.62E+02 -9.32E-06 -1.35E+03 -9.32E-02 3.86E-09 5.81 E-01 3.86E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.63E+02 -9.32E-06 -1.35E+03 -9.32E-02 3.85E-09 5.81 E-01 3.85E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.64E+02 -9.31E-06 -1.35E+03 -9.31E-02 3.85E-09 5.81E-01 3.85E-05 5.92E-02 4.09E-06 2.55E-05 1.69E-09 7.65E+02 -9.31E-06 -1.35E+03 -9.31E-02 3.85E-09 5.81E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.66E+02 -9.31E-06 -1.35E+03 -9.31E-02 3.85E-09 5.81E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.67E+02 -9.30E-06 -1.35E+03 -9.30E-02 3.85E-09 5.81E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.68E+02 -9.30E-06 -1.35E+03 -9.30E-02 3.85E-09 5.81E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.69E+02 -9.30E-06 -1.35E+03 -9.30E-02 3.85E-09 5.81 E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.70E+02 -9.30E-06 -1.35E+03 -9.30E-02 3.85E-09 5.81 E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.71 E+02 -9.29E-06 -1.35E+03 -9.29E-02 3.85E-09 5.81 E-01 3.85E-05 5.92E-02 4.08E-06 2.55E-05 1.69E-09 7.72E+02 -9.29E-06 -1.35E+03 -9.29E-02 3.85E-09 5.81 E-01 3.85E-05 5.92E-02 4.07E-06 2.55E-05 1.69E-09 7.73E+02 -9.29E-06 -1.35E+03 -9.29E-02 3.84E-09 5.81 E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.69E-09 7.74E+02 -9.29E-06 -1.35E+03 -9.29E-02 3.84E-09 5.81E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.75E+02 -9.28E-06 -1.35E+03 -9.28E-02 3.84E-09 5.81E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.76E+02 -9.28E-06 -1.35E+03 -9.28E-02 3.84E-09 5.81E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.77E+02 -9.28E-06 -1.35E+03 -9.28E-02 3.84E-09 5.81E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.78E+02 -9.27E-06 -1.35E+03 -9.27E-02 3.84E-09 5.81 E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.79E+02 -9.27E-06 -1.35E+03 -9.27E-02 3.84E-09 5.81 E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.80E+02 -9.27E-06 -1.35E+03 -9.27E-02 3.84E-09 5.81 E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.81E+02 -9.27E-06 -1.35E+03 -9.27E-02 3.84E-09 5.82E-01 3.84E-05 5.92E-02 4.07E-06 2.55E-05 1.68E-09 7.82E+02 -9.26E-06 -1.35E+03 -9.26E-02 3.84E-09 5.82E-01 3.84E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.83E+02 -9.26E-06 -1.35E+03 -9.26E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.84E+02 -9.26E-06 -1.35E+03 -9.26E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.85E+02 -9.26E-06 -1.35E+03 -9.26E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.86E+02 -9.25E-06 -1.35E+03 -9.25E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.87E+02 -9.25E-06 -1.35E+03 -9.25E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.88E+02 -9.25E-06 -1.35E+03 -9.25E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.89E+02 -9.25E-06 -1.35E+03 -9.25E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.06E-06 2.55E-05 1.68E-09 7.90E+02 -9.24E-06 -1.35E+03 -9.24E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.91 E+02 -9.24E-06 -1.35E+03 -9.24E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09

7.92E+02 -9.24E-06 -1.35E+03 -9.24E-02 3.83E-09 5.82E-01 3.83E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.93E+02 -9.23E-06 -1.35E+03 -9.23E-02 3.82E-09 5.82E-01 3.82E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.94E+02 -9.23E-06 -1.35E+03 -9.23E-02 3.82E-09 5.82E-01 3.82E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.95E+02 -9.23E-06 -1.35E+03 -9.23E-02 3.82E-09 5.82E-01 3.82E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.96E+02 -9.23E-06 -1.35E+03 -9.23E-02 3.82E-09 5.82E-01 3.82E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.97E+02 -9.22E-06 -1.35E+03 -9.22E-02 3.82E-09 5.82E-01 3.82E-05 5.92E-02 4.05E-06 2.55E-05 1.68E-09 7.98E+02 -9.22E-06 -1.36E+03 -9.22E-02 3.82E-09 5.82E-01 3.82E-05 5.96E-02 4.04E-06 2.55E-05 1.68E-09 7.99E+02 -9.22E-06 -1.36E+03 -9.22E-02 3.82E-09 5.82E-01 3.82E-05 5.96E-02 4.04E-06 2.55E-05 1.68E-09 8.OOE+02 -9.22E-06 -1.36E+03 -9.22E-02 3.82E-09 5.82E-01 3.82E-05 5.96E-02 4.04E-06 2.55E-05 1.68E-09 8.01 E+02 -9.21 E-06 -1.36E+03 -9.21 E-02 3.82E-09 5.82E-01 3.82E-05 5.96E-02 4.04E-06 2.55E-05 1.68E-09 8.02E+02 -9.21 E-06 -1.36E+03 -9.21 E-02 3.82E-09 5.82E-01 3.82E-05 5.96E-02 4.04E-06 2.55E-05 1.68E-09 8.03E+02 -9.21E-06 -1.36E+03 -9.21E-02 3.81E-09 5.82E-01 3.81E-05 5.96E-02 4.04E-06 2.55E-05 1.67E-09 8.04E+02 -9.21E-06 -1.36E+03 -9.21E-02 3.81E-09 5.82E-01 3.81E-05 5.96E-02 4.04E-06 2.55E-05 1.67E-09 8.05E+02 -9.20E-06 -1.36E+03 -9.20E-02 3.81 E-09 5.82E-01 3.81 E-05 5.96E-02 4.04E-06 2.55E-05 1.67E-09 8.06E+02 -9.20E-06 -1.36E+03 -9.20E-02 3.81 E-09 5.82E-01 3.81 E-05 5.96E-02 4.04E-06 2.55E-05 1.67E-09 8.07E+02 -9.20E-06 -1.36E+03 -9.20E-02 3.81 E-09 5.83E-01 3.81 E-05 5.96E-02 4.04E-06 2.56E-05 1.67E-09 8.08E+02 -9.20E-06 -1.36E+03 -9.20E-02 3.81 E-09 5.83E-01 3.81 E-05 5.96E-02 4.04E-06 2.56E-05 1.67E-09 8.09E+02 -9.19E-06 -1.36E+03 -9.19E-02 3.81E-09 5.83E-01 3.81E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.10E+02 -9.19E-06 -1.36E+03 -9.19E-02 3.81E-09 5.83E-01 3.81E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.11E+02 -9.19E-06 -1.36E+03 -9.19E-02 3.81E-09 5.83E-01 3.81E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.12E+02 -9.19E-06 -1.36E+03 -9.19E-02 3.81E-09 5.83E-01 3.81E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.13E+02 -9.18E-06 -1.36E+03 -9.18E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.14E+02 -9.18E-06 -1.36E+03 -9.18E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.15E+02 -9.18E-06 -1.36E+03 -9.18E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.03E-06 2.56E-05 1.67E-09 8.16E+02 -9.17E-06 -1.36E+03 -9.17E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.17E+02 -9.17E-06 -1.36E+03 -9.17E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.18E+02 -9.17E-06 -1.36E+03 -9.17E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.19E+02 -9.17E-06 -1.36E+03 -9.17E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.20E+02 -9.16E-06 -1.36E+03 -9.16E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.21 E+02 -9.16E-06 -1.36E+03 -9.16E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.22E+02 -9.16E-06 -1.36E+03 -9.16E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.23E+02 -9.16E-06 -1.36E+03 -9.16E-02 3.80E-09 5.83E-01 3.80E-05 5.96E-02 4.02E-06 2.56E-05 1.67E-09 8.24E+02 -9.15E-06 -1.36E+03 -9.15E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.02E-06 2.56E-05 1.66E-09 8.25E+02 -9.15E-06 -1.36E+03 -9.15E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.26E+02 -9.15E-06 -1.36E+03 -9.15E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.27E+02 -9.15E-06 -1.36E+03 -9.15E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.28E+02 -9.14E-06 -1.36E+03 -9.14E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.29E+02 -9.14E-06 -1.36E+03 -9.14E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09

8.30E+02 -9.14E-06 -1.36E+03 -9.14E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.31E+02 -9.14E-06 -1.36E+03 -9.14E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.32E+02 -9.13E-06 -1.36E+03 -9.13E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.01E-06 2.56E-05 1.66E-09 8.33E+02 -9.13E-06 -1.36E+03 -9.13E-02 3.79E-09 5.83E-01 3.79E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.34E+02 -9.13E-06 -1.36E+03 -9.13E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.35E+02 -9.13E-06 -1.36E+03 -9.13E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.OOE-06 2.56E-05 1.66E-09 8.36E+02 -9.12E-06 -1.36E+03 -9.12E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.37E+02 -9.12E-06 -1.36E+03 -9.12E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.38E+02 -9.12E-06 -1.36E+03 -9.12E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.39E+02 -9.12E-06 -1.36E+03 -9.12E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.40E+02 -9.11E-06 -1.36E+03 -9.11E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.41E+02 -9.11E-06 -1.36E+03 -9.11E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.42E+02 -9.11E-06 -1.36E+03 -9.11E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.00E-06 2.56E-05 1.66E-09 8.43E+02 -9.11E-06 -1.36E+03 -9.IIE-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 4.OOE-06 2.56E-05 1.66E-09 8.44E+02 -9.10E-06 -1.36E+03 -9.10E-02 3.78E-09 5.84E-01 3.78E-05 5.96E-02 3.99E-06 2.56E-05 1.66E-09 8.45E+02 -9.10E-06 -1.36E+03 -9.10E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.66E-09 8.46E+02 -9.10E-06 -1.36E+03 -9.10E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.65E-09 8.47E+02 -9.10E-06 -1.36E+03 -9.10E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.65E-09 8.48E+02 -9.09E-06 -1.36E+03 -9.09E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.65E-09 8.49E+02 -9.09E-06 -1.36E+03 -9.09E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.65E-09 8.50E+02 -9.09E-06 -1.36E+03 -9.09E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.65E-09 8.51 E+02 -9.09E-06 -1.36E+03 -9.09E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.99E-06 2.56E-05 1.65E-09 8.52E+02 -9.08E-06 -1.36E+03 -9.08E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.53E+02 -9.08E-06 -1.36E+03 -9.08E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.54E+02 -9.08E-06 -1.36E+03 -9.08E-02 3.77E-09 5.84E-01 3.77E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.55E+02 -9.08E-06 -1.36E+03 -9.08E-02 3.76E-09 5.84E-01 3.76E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.56E+02 -9.07E-06 -1.36E+03 -9.07E-02 3.76E-09 5.84E-01 3.76E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.57E+02 -9.07E-06 -1.36E+03 -9.07E-02 3.76E-09 5.84E-01 3.76E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.58E+02 -9.07E-06 -1.36E+03 -9.07E-02 3.76E-09 5.84E-01 3.76E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.59E+02 -9.07E-06 -1.36E+03 -9.07E-02 3.76E-09 5.84E-01 3.76E-05 5.96E-02 3.98E-06 2.56E-05 1.65E-09 8.60E+02 -9.07E-06 -1.36E+03 -9.07E-02 3.76E-09 5.85E-01 3.76E-05 5.96E-02 3.98E-06 2.57E-05 1.65E-09 8.61 E+02 -9.06E-06 -1.36E+03 -9.06E-02 3.76E-09 5.85E-01 3.76E-05 5.96E-02 3.98E-06 2.57E-05 1.65E-09 8.62E+02 -9.06E-06 -1.36E+03 -9.06E-02 3.76E-09 5.85E-01 3.76E-05 5.96E-02 3.97E-06 2.57E-05 1.65E-09 8.63E+02 -9.06E-06 -1.36E+03 -9.06E-02 3.76E-09 5.85E-01 3.76E-05 5.96E-02 3.97E-06 2.57E-05 1.65E-09 8.64E+02 -9.06E-06 -1.36E+03 -9.06E-02 3.76E-09 5.85E-01 3.76E-05 5.96E-02 3.97E-06 2.57E-05 1.65E-09 8.65E+02 -9.05E-06 -1.36E+03 -9.05E-02 3.76E-09 5.85E-01 3.76E-05 5.96E-02 3.97E-06 2.57E-05 1.65E-09 8.66E+02 -9.05E-06 -1.36E+03 -9.05E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.97E-06 2.57E-05 1.65E-09 8.67E+02 -9.05E-06 -1.36E+03 -9.05E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.97E-06 2.57E-05 1.64E-09

8.68E+02 -9.05E-06 -1.36E+03 -9.05E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.97E-06 2.57E-05 1.64E-09 8.69E+02 -9.04E-06 -1.36E+03 -9.04E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.97E-06 2.57E-05 1.64E-09 8.70E+02 -9.04E-06 -1.36E+03 -9.04E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.71E+02 -9.04E-06 -1.36E+03 -9.04E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.72E+02 -9.04E-06 -1.36E+03 -9.04E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.73E+02 -9.03E-06 -1.36E+03 -9.03E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.74E+02 -9.03E-06 -1.36E+03 -9.03E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.75E+02 -9.03E-06 -1.36E+03 -9.03E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.76E+02 -9.03E-06 -1.36E+03 -9.03E-02 3.75E-09 5.85E-01 3.75E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.77E+02 -9.02E-06 -1.36E+03 -9.02E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.78E+02 -9.02E-06 -1.36E+03 -9.02E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.79E+02 -9.02E-06 -1.36E+03 -9.02E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.80E+02 -9.02E-06 -1.36E+03 -9.02E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.96E-06 2.57E-05 1.64E-09 8.81E+02 -9.01E-06 -1.36E+03 -9.01E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.82E+02 -9.01E-06 -1.36E+03 -9.01E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.83E+02 -9.01E-06 -1.36E+03 -9.01E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.84E+02 -9.01E-06 -1.36E+03 -9.01E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.85E+02 -9.01E-06 -1.36E+03 -9.01E-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.86E+02 -9.OOE-06 -1.36E+03 -9.OOE-02 3.74E-09 5.85E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.87E+02 -9.OOE-06 -1.36E+03 -9.OOE-02 3.74E-09 5.86E-01 3.74E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.88E+02 -9.OOE-06 -1.36E+03 -9.OOE-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.89E+02 -9.OOE-06 -1.36E+03 -9.OOE-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.90E+02 -8.99E-06 -1.36E+03 -8.99E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.95E-06 2.57E-05 1.64E-09 8.91E+02 -8.99E-06 -1.36E+03 -8.99E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.92E+02 -8.99E-06 -1.36E+03 -8.99E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.93E+02 -8.99E-06 -1.36E+03 -8.99E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.94E+02 -8.98E-06 -1.36E+03 -8.98E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.95E+02 -8.98E-06 -1.36E+03 -8.98E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.96E+02 -8.98E-06 -1.36E+03 -8.98E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.97E+02 -8.98E-06 -1.36E+03 -8.98E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.98E+02 -8.97E-06 -1.36E+03 -8.97E-02 3.73E-09 5.86E-01 3.73E-05 5.96E-02 3.94E-06 2.57E-05 1.64E-09 8.99E+02 -8.97E-06 -1.36E+03 -8.97E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.00E+02 -8.97E-06 -1.36E+03 -8.97E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.01E+02 -8.97E-06 -1.36E+03 -8.97E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.02E+02 -8.97E-06 -1.36E+03 -8.97E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.03E+02 -8.96E-06 -1.36E+03 -8.96E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.04E+02 -8.96E-06 -1.36E+03 -8.96E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.05E+02 -8.96E-06 -1.36E+03 -8.96E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09

9.06E+02 -8.96E-06 -1.36E+03 -8.96E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.07E+02 -8.95E-06 -1.36E+03 -8.95E-02 3.72E-09 5.86E-01 3.72E-05 5.96E-02 3.93E-06 2.57E-05 1.63E-09 9.08E+02 -8.95E-06 -1.37E+03 -8.95E-02 3.72E-09 5.86E-01 3.72E-05 6.01 E-02 3.93E-06 2.57E-05 1.63E-09 9.09E+02 -8.95E-06 -1.37E+03 -8.95E-02 3.72E-09 5.86E-01 3.72E-05 6.01 E-02 3.93E-06 2.57E-05 1.63E-09 9.10E+02 -8.95E-06 -1.37E+03 -8.95E-02 3.71E-09 5.86E-01 3.71E-05 6.01E-02 3.93E-06 2.57E-05 1.63E-09 9.11E+02 -8.94E-06 -1.37E+03 -8.94E-02 3.71E-09 5.86E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.12E+02 -8.94E-06 -1.37E+03 -8.94E-02 3.71E-09 5.86E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.13E+02 -8.94E-06 -1.37E+03 -8.94E-02 3.71E-09 5.86E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.14E+02 -8.94E-06 -1.37E+03 -8.94E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.15E+02 -8.94E-06 -1.37E+03 -8.94E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.16E+02 -8.93E-06 -1.37E+03 -8.93E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.17E+02 -8.93E-06 -1.37E+03 -8.93E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.18E+02 -8.93E-06 -1.37E+03 -8.93E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.19E+02 -8.93E-06 -1.37E+03 -8.93E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.92E-06 2.57E-05 1.63E-09 9.20E+02 -8.92E-06 -1.37E+03 -8.92E-02 3.71E-09 5.87E-01 3.71E-05 6.01E-02 3.91E-06 2.57E-05 1.63E-09 9.21E+02 -8.92E-06 -1.37E+03 -8.92E-02 3.70E-09 5.87E-01 3.70E-05 6.01E-02 3.91E-06 2.57E-05 1.63E-09 9.22E+02 -8.92E-06 -1.37E+03 -8.92E-02 3.70E-09 5.87E-01 3.70E-05 6.01E-02 3.91E-06 2.57E-05 1.62E-09 9.23E+02 -8.92E-06 -1.37E+03 -8.92E-02 3.70E-09 5.87E-01 3.70E-05 6.01E-02 3.91E-06 2.57E-05 1.62E-09 9.24E+02 -8.92E-06 -1.37E+03 -8.92E-02 3.70E-09 5.87E-01 3.70E-05 6.01 E-02 3.91 E-06 2.57E-05 1.62E-09 9.25E+02 -8.91 E-06 -1.37E+03 -8.91 E-02 3.70E-09 5.87E-01 3.70E-05 6.01 E-02 3.91 E-06 2.57E-05 1.62E-09 9.26E+02 -8.91E-06 -1.37E+03 -8.91E-02 3.70E-09 5.87E-01 3.70E-05 6.01E-02 3.91E-06 2.57E-05 1.62E-09 9.27E+02 -8.91 E-06 -1.37E+03 -8.91 E-02 3.70E-09 5.87E-01 3.70E-05 6.01 E-02 3.91 E-06 2.57E-05 1.62E-09 9.28E+02 -8.91 E-06 -1.37E+03 -8.91 E-02 3.70E-09 5.87E-01 3.70E-05 6.01 E-02 3.91 E-06 2.57E-05 1.62E-09 9.29E+02 -8.90E-06 -1.37E+03 -8.90E-02 3.70E-09 5.87E-01 3.70E-05 6.01 E-02 3.91 E-06 2.57E-05 1.62E-09 9.30E+02 -8.90E-06 -1.37E+03 -8.90E-02 3.70E-09 5.87E-01 3.70E-05 6.01 E-02 3.90E-06 2.57E-05 1.62E-09 9.31E+02 -8.90E-06 -1.37E+03 -8.90E-02 3.70E-09 5.87E-01 3.70E-05 6.01E-02 3.90E-06 2.57E-05 1.62E-09 9.32E+02 -8.90E-06 -1.37E+03 -8.90E-02 3.70E-09 5.87E-01 3.70E-05 6.01E-02 3.90E-06 2.57E-05 1.62E-09 9.33E+02 -8.89E-06 -1.37E+03 -8.89E-02 3.69E-09 5.87E-01 3.69E-05 6.01 E-02 3.90E-06 2.57E-05 1.62E-09 9.34E+02 -8.89E-06 -1.37E+03 -8.89E-02 3.69E-09 5.87E-01 3.69E-05 6.01 E-02 3.90E-06 2.57E-05 1.62E-09 9.35E+02 -8.89E-06 -1.37E+03 -8.89E-02 3.69E-09 5.87E-01 3.69E-05 6.01E-02 3.90E-06 2.57E-05 1.62E-09 9.36E+02 -8.89E-06 -1.37E+03 -8.89E-02 3.69E-09 5.87E-01 3.69E-05 6.01E-02 3.90E-06 2.57E-05 1.62E-09 9.37E+02 -8.89E-06 -1.37E+03 -8.89E-02 3.69E-09 5.87E-01 3.69E-05 6.01 E-02 3.90E-06 2.57E-05 1.62E-09 9.38E+02 -8.88E-06 -1.37E+03 -8.88E-02 3.69E-09 5.87E-01 3.69E-05 6.01 E-02 3.90E-06 2.57E-05 1.62E-09 9.39E+02 -8.88E-06 -1.37E+03 -8.88E-02 3.69E-09 5.87E-01 3.69E-05 6.01 E-02 3.89E-06 2.57E-05 1.62E-09 9.40E+02 -8.88E-06 -1.37E+03 -8.88E-02 3.69E-09 5.87E-01 3.69E-05 6.01 E-02 3.89E-06 2.57E-05 1.62E-09 9.41E+02 -8.88E-06 -1.37E+03 -8.88E-02 3.69E-09 5.88E-01 3.69E-05 6.01E-02 3.89E-06 2.58E-05 1.62E-09 9.42E+02 -8.87E-06 -1.37E+03 -8.87E-02 3.69E-09 5.88E-01 3.69E-05 6.01 E-02 3.89E-06 2.58E-05 1.62E-09 9.43E+02 -8.87E-06 -1.37E+03 -8.87E-02 3.69E-09 5.88E-01 3.69E-05 6.01 E-02 3.89E-06 2.58E-05 1.62E-09

9.44E+02 -8.87E-06 -1.37E+03 -8.87E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.89E-06 2.58E-05 1.62E-09 9.45E+02 -8.87E-06 -1.37E+03 -8.87E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.89E-06 2.58E-05 1.61 E-09 9.46E+02 -8.87E-06 -1.37E+03 -8.87E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.89E-06 2.58E-05 1.61E-09 9.47E+02 -8.86E-06 -1.37E+03 -8.86E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.89E-06 2.58E-05 1.61 E-09 9.48E+02 -8.86E-06 -1.37E+03 -8.86E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.89E-06 2.58E-05 1.61 E-09 9.49E+02 -8.86E-06 -1.37E+03 -8.86E-02 3.68E-09 5.88E-01 3.68E-05 6.01E-02 3.89E-06 2.58E-05 1.61E-09 9.50E+02 -8.86E-06 -1.37E+03 -8.86E-02 3.68E-09 5.88E-01 3.68E-05 6.01E-02 3.89E-06 2.58E-05 1.61E-09 9.51E+02 -8.85E-06 -1.37E+03 -8.85E-02 3.68E-09 5.88E-01 3.68E-05 6.01E-02 3.88E-06 2.58E-05 1.61E-09 9.52E+02 -8.85E-06 -1.37E+03 -8.85E-02 3.68E-09 5.88E-01 3.68E-05 6.01E-02 3.88E-06 2.58E-05 1.61E-09 9.53E+02 -8.85E-06 -1.37E+03 -8.85E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.88E-06 2.58E-05 1.61 E-09 9.54E+02 -8.85E-06 -1.37E+03 -8.85E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.88E-06 2.58E-05 1.61 E-09 9.55E+02 -8.85E-06 -1.37E+03 -8.85E-02 3.68E-09 5.88E-01 3.68E-05 6.01 E-02 3.88E-06 2.58E-05 1.61E-09 9.56E+02 -8.84E-06 -1.37E+03 -8.84E-02 3.67E-09 5.88E-01 3.67E-05 6.01 E-02 3.88E-06 2.58E-05 1.61 E-09 9.57E+02 -8.84E-06 -1.37E+03 -8.84E-02 3.67E-09 5.88E-01 3.67E-05 6.01E-02 3.88E-06 2.58E-05 1.61E-09 9.58E+02 -8.84E-06 -1.37E+03 -8.84E-02 3.67E-09 5.88E-01 3.67E-05 6.01E-02 3.88E-06 2.58E-05 1.61E-09 9.59E+02 -8.84E-06 -1.37E+03 -8.84E-02 3.67E-09 5.88E-01 3.67E-05 6.01E-02 3.88E-06 2.58E-05 1.61E-09 9.60E+02 -8.83E-06 -1.37E+03 -8.83E-02 3.67E-09 5.88E-01 3.67E-05 6.01 E-02 3.88E-06 2.58E-05 1.61 E-09 9.61E+02 -8.83E-06 -1.37E+03 -8.83E-02 3.67E-09 5.88E-01 3.67E-05 6.01 E-02 3.87E-06 2.58E-05 1.61 E-09 9.62E+02 -8.83E-06 -1.37E+03 -8.83E-02 3.67E-09 5.88E-01 3.67E-05 6.01 E-02 3.87E-06 2.58E-05 1.61 E-09 9.63E+02 -8.83E-06 -1.37E+03 -8.83E-02 3.67E-09 5.88E-01 3.67E-05 6.01E-02 3.87E-06 2.58E-05 1.61E-09 9.64E+02 -8.83E-06 -1.37E+03 -8.83E-02 3.67E-09 5.88E-01 3.67E-05 6.01 E-02 3.87E-06 2.58E-05 1.61E-09 9.65E+02 -8.82E-06 -1.37E+03 -8.82E-02 3.67E-09 5.88E-01 3.67E-05 6.01E-02 3.87E-06 2.58E-05 1.61E-09 9.66E+02 -8.82E-06 -1.37E+03 -8.82E-02 3.67E-09 5.88E-01 3.67E-05 6.01E-02 3.87E-06 2.58E-05 1.61E-09 9.67E+02 -8.82E-06 -1.37E+03 -8.82E-02 3.67E-09 5.88E-01 3.67E-05 6.01 E-02 3.87E-06 2.58E-05 1.61 E-09 9.68E+02 -8.82E-06 -1.37E+03 -8.82E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.87E-06 2.58E-05 1.61 E-09 9.69E+02 -8.82E-06 -1.37E+03 -8.82E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.87E-06 2.58E-05 1.61 E-09 9.70E+02 -8.81E-06 -1.37E+03 -8.81E-02 3.66E-09 5.89E-01 3.66E-05 6.01E-02 3.87E-06 2.58E-05 1.61E-09 9.71E+02 -8.81E-06 -1.37E+03 -8.81E-02 3.66E-09 5.89E-01 3.66E-05 6.01E-02 3.86E-06 2.58E-05 1.61E-09 9.72E+02 -8.81 E-06 -1.37E+03 -8.81 E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.86E-06 2.58E-05 1.61 E-09 9.73E+02 -8.81E-06 -1.37E+03 -8.81E-02 3.66E-09 5.89E-01 3.66E-05 6.01E-02 3.86E-06 2.58E-05 1.61E-09 9.74E+02 -8.80E-06 -1.37E+03 -8.80E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.86E-06 2.58E-05 1.61 E-09 9.75E+02 -8.80E-06 -1.37E+03 -8.80E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.86E-06 2.58E-05 1.61 E-09 9.76E+02 -8.80E-06 -1.37E+03 -8.80E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.86E-06 2.58E-05 1.61 E-09 9.77E+02 -8.80E-06 -1.37E+03 -8.80E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.86E-06 2.58E-05 1.61 E-09 9.78E+02 -8.80E-06 -1.37E+03 -8.80E-02 3.66E-09 5.89E-01 3.66E-05 6.01 E-02 3.86E-06 2.58E-05 1.61 E-09 9.79E+02 -8.79E-06 -1.37E+03 -8.79E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.86E-06 2.58E-05 1.60E-09 9.80E+02 -8.79E-06 -1.37E+03 -8.79E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.86E-06 2.58E-05 1.60E-09 9.81E+02 -8.79E-06 -1.37E+03 -8.79E-02 3.65E-09 5.89E-01 3.65E-05 6.01E-02 3.86E-06 2.58E-05 1.60E-09

9.82E+02 -8.79E-06 -1.37E+03 -8.79E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.86E-06 2.58E-05 1.60E-09 9.83E+02 -8.78E-06 '1.37E+03 -8.78E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.84E+02 -8.78E-06 -1.37E+03 -8.78E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.85E+02 -8.78E-06 -1.37E+03 -8.78E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.86E+02 -8.78E-06 -1.37E+03 -8.78E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.87E+02 -8.78E-06 -1.37E+03 -8.78E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.88E+02 -8.77E-06 -1.37E+03 -8.77E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.89E+02 -8.77E-06 -1.37E+03 -8.77E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.90E+02 -8.77E-06 -1.37E+03 -8.77E-02 3.65E-09 5.89E-01 3.65E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.91E+02 -8.77E-06 -1.37E+03 -8.77E-02 3.64E-09 5.89E-01 3.64E-05 6.01E-02 3.85E-06 2.58E-05 1.60E-09 9.92E+02 -8.77E-06 -1.37E+03 -8.77E-02 3.64E-09 5.89E-01 3.64E-05 6.01 E-02 3.85E-06 2.58E-05 1.60E-09 9.93E+02 -8.76E-06 -1.37E+03 -8.76E-02 3.64E-09 5.89E-01 3.64E-05 6.01 E-02 3.84E-06 2.58E-05 1.60E-09 9.94E+02 -8.76E-06 -1.37E+03 -8.76E-02 3.64E-09 5.89E-01 3.64E-05 6.01 E-02 3.84E-06 2.58E-05 1.60E-09 9.95E+02 -8.76E-06 -1.37E+03 -8.76E-02 3.64E-09 5.90E-01 3.64E-05 6.01 E-02 3.84E-06 2.59E-05 1.60E-09 9.96E+02 -8.76E-06 -1.37E+03 -8.76E-02 3.64E-09 5.90E-01 3.64E-05 6.01 E-02 3.84E-06 2.59E-05 1.60E-09 9.97E+02 -8.75E-06 -1.37E+03 -8.75E-02 3.64E-09 5.90E-01 3.64E-05 6.01 E-02 3.84E-06 2.59E-05 1.60E-09 9.98E+02 -8.75E-06 -1.37E+03 -8.75E-02 3.64E-09 5.90E-01 3.64E-05 6.01 E-02 3.84E-06 2.59E-05 1.60E-09 9.99E+02 -8.75E-06 -1.37E+03 -8.75E-02 3.64E-09 5.90E-01 3.64E-05 6.01 E-02 3.84E-06 2.59E-05 1.60E-09 1.OOE+03 -8.75E-06 -1.37E+03 -8.75E-02 3.64E-09 5.90E-01 3.64E-05 6.01 E-02 3.84E-06 2.59E-05 1.60E-09

Carbon-14 Fractional Release Rate low concentration side 1.OOE+00 1.OOE-01

- Diffusion Coefficient =1 E-1 2 cmA2/s I.OOE-02

<. 1.00E-03 L 1.00E-04 C

1.00E-05 IL 1~ ,,OE..

1.OOE 1.OOE-09 O.OOE+00 1.00E+02 2.00E+02 3.00E+02 4.00E+02 5.00E+02 6.00E+02 7.00E+02 8.OOE+02 9.00E+02 1.00E+03 Time (years)

I

Carbon - 14 Fractional Release Rate low concentration side 3.OOE-05 2.50E-05 0

(U) f (1 2.OOE.05 5

I.

LL a 1.50E-05 1.00E-05 E

0 5.OOE-06 O.OOE+00 O.OOE+00

. ^^

4.00E Iu4 6.QOE+02 8.00E+02 1.00E+03 Time (years)

Carbon-14 Fractional Release Rate High concentration side 1.OOE+OO -

1.OOE-01 -

1.OOE-02 - I 1.OOE 0 1.OOE-04 -

en 1.OOE-05 - _

a) 1.OOE-06 - _

m I-0 1.OOE-07 - _

0 U-(3 1.OOE-08 - _

1.OOE-09 - _

1.OOE-10 - 7 1.OOE-11 I 1.OOE-12 -r-O.OOE+OO 2.OOE+02 4.OOE+02 6.OOE+02 8.OOE+02 1.OOE+03 Time (years)

Carbon-14 Fractional Release Rate High concentration side 7.OOE-02 I 6.OOE-02 0

0 5.OOE-02 r_

l. - Diffusion Coefficient =1 E-1 2 cmA2/s 0

4.OOE-02 0

(U U-0 3.OOE-02 E 2.OOE-02 0

1.OOE-02 O.OOE+OO 1~~~~~~

O.OOE+OO 2.OOE+02 4.OOE+02 6.OOE+02 8.00E+02 1 .OOE+03 Time (years)

PROPOSED CHANGE NO. 216 ATTACHMENT IV Activated Concrete Dose Assessment Using Revised Inventory and Dose Model

Attachment IV - Activated Concrete Dose Assessment Using Revised Inventory and Dose Model ACTIVATED CONCRETE (50 yr Liner Breach and Diffusion)

Key Parameter:

3 Porosity 0.30 Concrete Density 2.20 g/cr, 3 3 Buik Density 1.50 otcn Annual Total WeE Water Vol 738.0 m 2

Yearly Drinking Water 478.0 U.yr IrrIation Rate 0.274 Um -d Will Surface Area 365.0 m3 Surface Soil Depth 0.15 m 3

Fill Volume 2460.0 m Activated Concrete Total Inventory 4.88E+08 pCI 3 3 Surface Area/Open Volume 0.46 m/m Concrete Volume 1.13 mr DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION ACTIVATED CONCRETE ANNUAL DOSE NUREG-1727 FOR 11 Mlcrohield Kd Kd Drinking Irrigatlon Direct Total Nuclide mremty per mrnm/pCI mrnm/y per Nuclide Inventory Fill Concrete Adsorption Water Fill Concrete Nucllde Water Dose Dose Dose Dose pCl/g pCI/g Fraction pCI cm'/gm r cm'igm Factor pCI/L pCI/g pCI/g mremty mremry mremty mremty Ca-134 4.39E+00 7.33E-05 6.09E-05 5.72E-03 2.79E+06 7.91E+01 3.00E+00 3.96E+02 9.54E-03 7.55E-04 2.86E-05 Cs-134 3.34E.04 1.86E-05 4.60E-08 3,53E-04 Co-60 8.58E+00 2.69E-05 6.30E-04 2.73E-02 1.33E+07 1.28E+02 1.OOE+02 6.40E.02 2.82E-02 3.60E-03 2.82E03 Co4S 3.63E-04 8.25E-05 2.27E-06 4.47E-04 C-14 2.08E+00 2.09E-06 0.00E+00 1.48E-01 7.22E+07 5.OOE+00 1.00E+02 2.63E+01 3.72E+00 1.86E-02 3.72E-01 C-14 3.71E-03 3,44E-03 0.002E00 7.15E-03 Eu-154 3.13E+00 9.55E-4 3.10E-04 6.10E-03 2.98E+06 4.00E+02 5.002E03 2.02E+03 2.00E-03 8.00E404 9.99E-03 Eu-154 9.12E-06 2.78E-06 2.48E-07 1.21E-05 Fe-S5 2.50E-03 6.07E-07 0.00E+00 8.44E-02 4.12E+07 2.50E201 1.00E+02 1.26E+02 4.42E-01 1.10E-02 4.42E-02 Fe-55 1.28E-04 4.91E-07 0.00E+00 1.29E-04 2.27E4-1 6.40E-08 0.00E00 4.41E-01 2.15E+08 0.00E+00 0.00E+00 1.00E+00 2.91E+02 0.00E+00 0.00E+00 H-3 8.92E-03 2.94E-02 0.00E+00 3.83E-02 H-3 Eu-152 2.87E+00 6.48E-06 2,09E-04 7.56E-02 3.69E+07 4.00E+02 5.00E+03 2.02E+03 2.48E-02 9.91E-03 1.24E-01 Eu-152 7.67E-05 3.16E-05 2.07E206 1.10E-04 NP63 1.19E-02 5.77E-07 0.00E+00 2.11E-01 1.03E+08 1.28E+02 1.00E+02 6.40E+02 2.18E-01 2.78E-02 2.18E-02 Ni-63 6.01E405 1.15E-06 0.OOE+00 6,13E-05 9.99E-01 4.88E+08 SUM 1.36E-02 3.30E-02 4.63E-06 4.66E-02

PROPOSED CHANGE NO. 216 ATTACHMENT V Activated Liner Dose For Peak Activity and 50-Year Liner Breach

Attachment V - Activated Liner Dose for Peak Activity and 50-Year Liner Breach - Sheet I Activated Liner (Year 3 Peak Activity Corosion and Decay)

Key Parameters:

Porcaity 0.30 Concrete Density 2.20 g/cms 3

Bulk Density 1.50 g/cm Annual Total Well Water Vol 738.0 Yearly Dr*kng Water 478.0 LUyr Inigation Rate 0.274 Um'-d Wall Surface Area 1131.6 m' Surface Soil Depth 0.15 m 3

FMVolume 2460.0 m Activated Metal Total Inventory 1.01E+09 Total pCI 3

Surface Area/Open Volume 0.46 m'/m Concrete Volume 1.13 DOSE CALCULATION FACTORS SOURCETERM Kd WATER. FILL. CONCRETE CONCENTRATION ACTIVATED METAL ANNUAL DOSE NUREG.1727 FGR11 Microahleld Kd Kd DrInking IrrigatIon Direct Total Nucilde mrenVy per mrsm/pCI mrem/y per Nuclide In tory Fill Concrete AdsorptIon Water Fill Concrete Nucllde Water Dose Dose Dose Dose pCI1g pCI/g Fraction pCI cm'lgm cm'lgm Factor pCUL pCI/g pCUg mremty mremty mromly mremly Cs-134 4.39Et00 7.33E-05 6.092-05 0.00E+00 0.00E+00 7.91E+01 3.00E+00 3.96E+02 0.00E+00 0.OOE.00 0.00E+00 Cs-134 0.00E400 0.00E+00 0.OOE+00 0.00E+00 Co-60 6.8E+00 2.69E-05 6.30E-04 1.16E41 1.17E+08 1.28E+02 1.OOE*02 6.40E+02 2.48E-01 3.17E-02 2.48E-02 Co-60 3.19E-03 7.25E-04 2.00E-05 3.93E-03 C-14 2.08E+00 2.09E-06 0.00E+0 0.00E+00 0.00E+00 5.OOE+00 1.00E+02 2.63E+01 0.00+E00 0.OOE+00 0.00E+00 C-14 0.00E+00 0.002E00 0.00E+00 0.002E00 Eu-154 3.13E+00 9.55E-06 3.10E-04 0.00E+00 0.00E+00 4,00E+02 5.00E+03 2.02E+03 0.00E+00 0.00E+00 0.00E+00 Eu-154 0.00E+0 0.00E+00 0.00E+00 0.00E+00 Fe-55 2.50E-03 6.07E-07 0.OOE+00 8.72E-01 8.81E+08 2.50E+01 1.00E+02 1.26E+02 9.45E+00 2.36E-01 9.45E-01 Fe-55 2.74E-03 1.05E-05 0.00E+00 2.75E403 H-3 2.27E-01 6.40E-08 0.00E*00 0.00E+00 0.00E+00 0.00E+00 o.ooE+00 1.00E+00 0.002E00 0.00E400 0.00E200 H-3 0.002E00 0.00E+00 0.00E+00 0.00E+00 Eu-152 2.87E+00 6.48E2- 2.09E-04 0.OOE+00 0.OOE+00 4.00E+02 5.00E+03 2.02E+03 0.OOE+00 0.OOE+00 0.00E+00 Eu-152 0.002E00 0.00E+00 0.00+E00 0.00E+00 NI-63 1.19E-02 5.77E-07 0.OOE+00 1.21E-02 1.22E+07 1.28E+02 1.00E+02 6.40E+02 2.59E-02 3.31E403 2.59E-03 NI-63 7.134-06 1.37E-07 0.00E+00 7.27E06 SUM 1.01E+09 . SUM 5.94E-03 7.36E-04 2.00E-05 6.69E-03

Attachment V -Activated Liner Dose for Peak Activity and 50-Year Liner Breach - Sheet 2 Activated Liner (Year 50 Corrosion and Decay)

Key Paramete :

3 Porosity 0.30 Concrete Dnsity 2.20 g/cm 3

Sulk Density 1.50 g/cm Annual Total Weil Water Vol 738.0 M3 Yearly Drinking Water 478.0 1./yr Irrigation Rate 0.274 Urmn-d Wa1 Surface Are 1131.6 ml Surface Soil Depth 0.15 m 3

FM Volume 2480.0 m Activated Metal Total Inventory 1.15E+08 TotalpCI Surface Area/Open Volume 0.46 m'/lma Concrete Voiume 1.13 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION ACTIVATED METAL ANNUAL DOSE NUREG41727 FGR 11 Mlcroehield Kd Kd DrinkIng Irrigation Direct Total Nuclide mremly per mrwm/pCI mremly per Nuclide tnentory Fill Concrete Adsorption Water Fill Concrete Nucllde Water Dose Dose Doas Dose pClg pCI/g Fraction pCI cmigm cmlgm Factor pCi/L pCI/g pCl/g mrem/y mremly rmry mremlfy Cs-134 4.39E+00 7.33E-05 6.09E-05 0.00E+00 0.00E+00 7.91E+01 3.00E+00 3.96E+02 0.00+E00 0.00Et00 0.00E+00 Cs.134 0.002E00 0.00E+00 0.00E+00 0,00E.00 Co-60 6.58E+00 2.69E45 6.30E-04 3.002-02 3.45E+06 1.28E+02 1.00E+02 6.40E+02 7.30E-03 9.33E404 7.30E-04 Co-60 9.39E-05 2.14E-05 5.88E-07 1.16E-04 C-14 2.08E+00 2.09E48 0.00E+00 0.00E+00 0.00E+00 5.00E+00 1.00E+02 2.63E+01 0.00E+00 0.00E+00 0.00E+00 C-14 0.00E+00 0.00E+00 O.OOE+0 0.00E+00 Eu-154 3.13E+00 9.M52-0 3.10E-04 0.002+00 0.00E+00 4.00+E02 5.00E+03 2.02E+03 0.00+E00 0.00E+00 0.00E+00 Eu-154 0.00E+00 0.00+E00 0.00+E00 0.00E+00 Fe-55 2.50E-03 6.07E-07 0.00E00 8.184-04 9.41E+04 2.50E+01 1.00E+02 1.26E+02 1.01E-03 2.52E-05 1.01E-04 Fe-55 2.93E-07 1.12E-09 0.00E+00 2.94E-07 H-3 2.27E-01 6.40E-08 0.00E+00 0.00+E00 0.00E+00 0.00E+00 0.00E+00 1.00E+00 0.00E+00 0.00E+00 0.OOE+00 H-3 0.002E00 0.OOE*00 0.00E+00 0.002E00 Eu-152 2.87E+00 6.48-06 2.09E-04 0.00E+00 0.00E+00 4.00E+02 5.00E+03 2.02E+03 0.00+E00 0.OOE+00 0.00E+00 Eu-152 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4-63 1.19E-02 5.77E-07 0.00+E00 9.69E-01 1.11E+08 1.28E+02 1.00E+02 6.40E+02 2.36E-01 3.01E-02 2.36E-02 N4-63 6.51E-05 1.25E-06 0.00E+00 6.3E-05 SUM 1.15E+08 SUM 1.59E-04 2.26E-05 5.88E-07 1.82E-04

PROPOSED CHANGE NO. 216 ATTACHMENT VI Dose Assessment Using 0.46 SAN Ratio for Containment

Attachment VI -Sheot I EC.014-01(MY)

Attachment 11 Rev. 2.0 Page 22 of 25 CONTAMINATED CONCRETE SPECIAL AREAS Key Parameters:

Porosity 0.30 Concrete Density 2.20 3 3 m Bulk Density 1.50 gicm Annual Total Wen Water Vol 738.0 Yearly Drinking Water 478.0 L/w Irrigation Rate 0.274 LJM'-d Wall Surface Area 1131.6 Surface Soil Depth 0.16 8.15E.02 ces Totai Dose Contaminate Concrete Fill Volume 2460.0 2 3 m1 SpecIal Ares Grow Set DCGL 9.50E+03 dpm/100 cmn Surface Area/Open Volume 0.46 Gross Beta Nucide Fraction 0.6672 2.92E42 < Total Dose Special Areas Concrete Volume 1.13 Total Inventory 1.42E+04 dpm/100 cn2 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION CONTAMINATED CONCRETE ANNUAL DOSE NUREG-1727 FOR 11 Mlcroshleld Kd Kd Drinking Irrigation Direct Total Nuclide mnwrey per mrnempCI mremly par Nuclide bnentory Inventory Fill Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pC11g pCI/g FractIon dpmIO0rcm' pCI cm'/gm cm'/gm Factor pCUL pCI/g pCl/g mrnm/y mrermly mrenvy mnmrnly Sr-90 1.47E+01 1.42E-04 0.00E+00 6.874E403 9.79E601 4.99E+06 6.12E+01 1.00E+00 3.07E+02 2.20E-02 1.35E403 2.20E-05 Sr-90 1.50E603 1.44E-04 0.00E+00 1.64E-03 Sb-125 9.77E-01 2.81E-06 3.83E46 4.523E-03 6.44E+01 3.28E+06 4.50E+01 0.00E+00 2.26E+02 1.97E-02 8.86E-04 0.00E+00 Sb-125 2.64E-05 8.55E-06 3.39E-09 3.50E-05 Cs-134 4.39E+00 7.33E-05 6.09E-05 2.815E603 4.01E+01 2.04E+06 7.91E+01 3.00E+00 3.96E+02 6.98E-03 5.52E-04 2.09E05 Cs-134 2.45E604 1.36E-05 3.36E-06 2.58E-04 Cs-137 2.27E+00 5.OOE-05 1.20E-05 2.890E601 4.12E+03 2.10E+08 7.91E+01 3.00E+00 3.96E+02 7.17E601 5.67E-02 2.15E-03 Cs-137 1.71E-02 7.23E-04 6.80E-07 1.79E-02 Pu-238 1.00E+01 3.20E-03 2.45E-25 1.165E404 1.66E+00 8.46E+04 5.50E602 5.00E+03 2.77E+03 4.14E-05 2.28E-05 2.07E-04 Pu-238 6.33E05 1.84E407 5.58E-30 6.35E605 Pu-239 1.09E+01 3.54E-03 6.10E-15 8.752E405 125E600 6.35E+04 5.50E.02 5.00E03 2.77E+03 3.11E-05 1.71E-05 1.55E04 Pu-239 5.26E-05 1.51E-07 1.04E-19 5.28E-05 Pu-240 1.09E+01 3.54E-03 7.52E-26 8.750E-05 1.25E+00 6.35E+04 5.50E+02 5.00E+03 2.77E+03 3.11E-05 1.71E-05 1.55E-04 Pu-240 5.26E-05 1.51E-07 1.29E-30 5.28E-05 Pu-241 3.47E-01 6.85E-05 0.00E+00 6.705E-03 9.55E+01 4.87E+06 5.50E+02 5.00E+03 2.77E+03 2.38E-03 1.31E403 1.19E-02 Pu-241 7.80E-05 3.67E-07 0.006+00 7.84E-05 Arn-241 1.19E+01 3.64E-03 1.65E-19 5.929-04 8.44E+00 4.30E+05 1.90E+03 5.00E+03 9.51E+03 6.13E-05 1.16E-04 3.06E-04 Arn-241 1.07E-04 3.24E-07 1.93E-23 1.07E-04 Cm-243 7.81E+00 2.51E-03 1.27E-08 4.649E405 6.62E-01 3.37E+04 4.006E03 5.00E+03 2.00E+04 2.26E-06 9.14E-06 1.14E-05 Crn-243 2.74E-06 7.93E-09 1.16E-13 2.75E-06 Cm-244 6.00E+00 2.02E-03 9.81E-25 4.454E-05 6.344-01 3.23E+04 4.00+E03 5.006+03 2.00E+04 2.19E-06 8.75E-06 1.09E-05 Cm-244 2.11E-06 5.84E-09 8.59E-30 2.12E-06 Co-40 8.58E+00 2.69E405 6.30E404 3.639E-01 5.18E+03 2.64E+08 1.28E+02 1.00E+02 6.40E602 5.59E-01 7.14E-02 5.59E-02 Co-60 7.19E.03 1.64E-03 4.50E-05 8.87E-03 Co.57 1.67E-01 1.18E-06 2.80E-08 0.00E6+0 0.00+E00 1.28E+02 1.00E+02 6.40E+02 0.00E+00 0.00+E00 0.00E+00 Co-57 O.OOE0+0 0.006E00 0.00+E00 0.00E+00 Mn-54 1.67E+00 2.77E-06 4.40E-05 4.028E-04 5.74E+00 2.92E+05 5.00+E01 0.00E+00 2.51E+02 1.58E-03 7.89E-05 0.00E+00 Mn-54 2.09E-06 1.17E-06 3.47E-09 3.26E-06 Fe-55 2.50E-03 6.07E-07 0.00+E00 2.235E-02 3.18E+02 1.62E+07 2.50E+01 1.00E+02 1.26E+02 1.74E-01 4.35E-03 1.74E-02 Fe-55 5.05E-05 1.93E-07 0.00E+00 5.07E-05 H-3 2.27E-01 6.40E-08 0.006OO+ 0.00+E00 0.00+E00 0.00E+00 0.00E+00 1.00E#00 0.006E00 0.00E+00 0.006E00 H-3 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ni-63 1.19E-02 5.77E47 0.00E+00 3.024E-01 4.31E+03 2.19E+08 1.28E+02 1.00E+02 6.40E+02 4.65E601 5.94E602 4.65E-02 NI-63 1.28E-04 2.46E-06 0.00E+00 1.31E-04

.___________________________________ .__________________________________ SUM 2.66E-02 2.53E-03 4.57E-05 2.92E42

Attachment VI -Sheat EC-014401(MY)

Attachment 10 Rev. 2.o Page 21 of 28 EMBEDDED SPRAY PUMP PIPING Key Parameters:

Porosity 0.30 Concrete Density 2.20 g/cm' Bulk Density 1.50 g9cmS Surface Sodl Depth 0.15 m Yearly Drinking Water 478.0 I/yr Irrigation Rate 0.274 Um'-d 2

Wall Surface Area 1131.6 m Annual Total Wall Water Vol 738 3 3 2 FINVolume 2460.0 m Embedded Pipe ConversIon Factor 1191.7 pCi per dpm/100 cm 2 3 2 Surface Area/Open Volume 0.46 m/m Gross Beta DCGL 8.00E+05 dpm/100 cm Concrete Volume 1.13 m' Gross Bets Nuclide Fraction 0.616 2

Total Inventory 1.30E+06 dpm/100 cm DOSE CALCULATION FACTORS SOURCE TERM Kd WATER. FILL. CONCRETE CONCENTRATION EMBEDDED PIPE ANNUAL DOSE NUREG-1727 FGR 11 Mlcroshlold Kd Kd Drinking Irrigation DIrect Total Nuclide mrewny per mrsm/pCi mrsmty per Inventory Inventory Fill Concrete Adsorption Water Fill Concrete Nucllde Water Dose Dose Dose Dose pCUg pClIg Fraction dpm/100 cm pCI cm'/gm cm'lgm Factor pCUL pC pCI/a pCi/g mromly mremly mrom/y mremly Sr-90 1.47E+01 1A2E-04 O.ooE+00 2.80E-03 3.64E+03 4.34E+06 6.02E+01 1.00E+00 3.02E+02 1.95E-02 1.17E-03 1.95E-05 Sr.90 1.32E-03 1.27E-04 0.00E+00 1.45E-03 Cs-134 4.39E+00 7.33E405 6.09E-05 4.55E 5.91E+03 7.04E+06 7.91E401 3.00E+00 3.96E+02 2.41E-02 1.90E03 7.22E-05 Cs-134 8.43E604 4.69E-05 1.16E-07 8.90E44 Cs-137 2.27E+00 5.OOE-05 1.204-05 5.50E-01 7,15E+05 8.52E+08 7.91E601 3.00E+00 3.96E602 2.91E+00 2.30E-01 8.73E-03 Cs-137 6.96E-02 2.94E-03 2.76E-06 7.25E402 Co-60 6.58E+00 2.69E-05 6.30E-04 5.84E-02 7.59E+04 9.04E+07 1.28E+02 1.00E+02 6.40E+02 1.91E-1 2.45E-02 1.91E-02 Co-60 2.46E-03 5.60E-04 1.54E-05 3.04E603 Co-57 1.67E-01 1.18E-06 2.80E-08 3.06E-04 3.98E+02 4.74E+05 1.28E+02 1.00E+02 6.40E+02 1.00E-03 1.28E44 1.00E-04 Co-57 5.66E-07 7.45E-08 3.59E-12 6.41E-07 Fe-55 2.50E-03 6.07E-07 0.00E+00 4.81E-03 6.25E+03 7.45E+06 2.50E+01 1.00E+02 1.26E+02 7.99E-02 2.00-E03 7.99E403 Fe-55 2.32E4-5 8.88E-08 0.00E+00 2.33E-05 H-3 2.27E01 6.40E-08 0.00E00 2.36E-02 3.06E604 3.64E+07 006.E00 o.ooE+00 1.00E+00 4.94E+01 0.OOE+00 0.00E+00 H-3 1.51E-03 4.98E-03 0.00.E00 6.49E-03 M-63 1.19E-02 5.77E-07 0.OOE+00 3.55E-01 4.61E+05 5.50E+08 1.28E+02 1.00E+02 6.40E+02 1.16E+00 1.49E-01 1.16E-01 Ni-63 3.21E44 6.16E-06 0.00E+00 3.27E-04 1.30E+06 1.55E+09

_________ ____________ __ ___________7.60E-02

__ _SUM 8.66E-03 1.83E-05 8.47E-02

Attachment VI -Sheot 3 EC-014-01(MY)

Attachment 9 Rev. 2.0 Page 20 of 25 BOP EMBEDDED PIPE Key Parameter:

Porosity 0.30 Concrete Density 2.20 9/cm3 3

Bulk Density 1.50 g/cai Surface Soil Depth 0.15 m Yearly Drinking Water 478.0 vyr Irrigation Rate 0.274 L/mr-d Wall Surface Area 1131.6 ma Annual Total Well Water Vol 738 ma 2

Fill Volume 2460.0 m3 Embedded Pipe ConversIon Factor 5754.5 pCI per dpm/100 cm 2

Surface Area/Open Volume 0.46 m"/rn3 Gross Beta DCGL 1.00E+05 dpm/100 cm Conrete Volume 1.13 M3 Groasa Set Nudide Fraction 0.616 Total Inventory 1.62E+05 dpm/100 Cm2 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION EMBEDDED PIPE ANNUAL DOSE NUREG-14 FGR11 Mlcroshleld Kd Kd Drinking Irrigation Direct Total Nucilde mrsndy per mremmpCI mrmny per Inventory Inventory Fill Concrete Adsorption Water Fill Concrete Nucilde Water Dose Dose Dose Dosae pClg pCI~g Fraction dpm/100cma pCI cm'lgm cmrgm Factor pCIUL pC~lg pC11g mrsm/y mremly mremty mramny Sr-40 1.47E+01 1.42E-04 0.OOE+00 2,80E-03 4.55E+02 2.62E+06 6.02E+01 1.00E+00 3.02E+02 1.18E-02 7.07E-04 1.18E-05 Sr-90 7.98E-04 7.68E-05 0.OOE+00 8.75E-04 Cs-134 4.39E+00 7.33E-05 6.09E-05 4,55E-03 7.38E+02 4.25E+06 7.91E+01 3.00E+00 3.96E+02 1.45E-02 1,15E-03 4.36E405 Cs-134 5.09E404 2.83E05 6.99E-08 5.37E.04 Cs-137 2.27E+00 5.00E-05 1.20E-05 5.50E-01 i.93E+04 5.14E+08 7.91E01 3.00E+00 3.96E+02 1.76E+00 1.39E401 5.27E-03 Cs-137 4.20E-02 1.77E-03 1.67E-06 4.38E-02 Co-60 6.58E+00 2.69E-05 6.30E-04 5.U4E-02 9.48E+03 5.46E+07 1.28E+02 1.00E+02 6.40E+02 1.16E-1 1.484-02 1.16E-02 Co-60 1.49E03 3.38E04 9.30E06 1.83E.03 Co-57 1.67E41 1.18E-6 2,80E-8 3.06E-04 4.97E+01 2.862+05 1.28E+02 1.00E+02 6.40E+02 6.06E-04 7.74E-05 6.06E405 Co-57 3.42E-07 4.50E-08 2.17E-12 3.87E-07 Fe-55 2.502-03 6.07E-07 0.00E+00 4.81E-03 7J82E+02 4.50E+06 2.50E+01 1.00E*02 1.26E+02 4.82E-02 1.21E-03 4.82E-03 Fe-55 1.40E405 5.36E-08 0.00E+00 1.40E-05 H-3 2.27E-01 6.40E-08 0.00E+00 2.36E-02 3.82E+03 2.20E+07 0.00E+00 0.00E+00 1.00E+00 2.98E+01 0.00E+00 0.OOE+00 H-3 9.12E-04 3.01E-03 0.0OE+00 3.92E-03 Ni-63 1.19E-02 5.77E-07 0.OOE+00 3.55E-01 5.77E+04 3.32E+08 1.28E+02 1.00E+02 6.40E+02 7.02E-01 8.97E-02 7.02E-02 NI-63 1.94E-04 3.72E-06 0.OOE+00 1.97E-04 SUM 4.59E-02 5.23E-03 1.10E-05 5.11E-02

Attachment VI -Shot 4 EC-014-O1(MY)

Attachment I Rev. 2.0 Page 12 of 25 CONTAMINATED CONCRETE Key Parameters:

3 Porosity 0.30 3 Concrete Density 2.20 g/cm g/cm 3 Bulk DensIty 1.50 Annual Total Well Water Vol 738.0 m 2

Yearly Drlnkhig Water 478.0 I-1r Irrigatlon Rate 0.274 Urm-d Wan Surface Area 111311.6 Surface Sol Depth 0.15 m FM11 Volume 2460.0 Mlhn GroC Seta DCGL 1.80E.04 dpnV100 cm?

Surface Area/Open Volume 0.46 Gross Beta Nucride Fraction 0.6160 2

Concrete Volume 1.13 Total Inventory 2,92E+04 dpm/100 cuM DOSE CALCULATION FACTORS SOURCE TERM Kd WATER. FILL, CONCRETE CONCENTRATION CONTAMINATED CONCRETE ANNUAL DOSE NUREG-127 FGR 11 Mlcrwshield Kd Kd Drinking IrrigatIon Direct Total Nucilde mramly per mrmtpCI mnm/y per Nuclide Inventory inventory Fill Concrete Adsorption Water Fill Concrete Nucllde Water Dose Dose Dose Dose pCUg pCUg FractIon dpm/100ccmt pCI cm'gm cm'lgm Factor pCI/L pCi/g pCUgI mremly mremly mernly mremty Sr-90 i.47E+01 1.42E-04 0.00E00 2.80E-03 8.19E601 4.17E+06 6.02E+01 1.00E+00 3.02E602 1.87E-02 1.13E-03 1.87E-05 Sr-90 1.27E-03 1.22E-04 0.00+E00 1.39E-03 Cs-134 4.39E+00 7.33E-05 6.094-05 4.55E-03 1.33E+02 6.77E+06 7.91E+01 3.00E+00 3.96E+02 2.31E-02 1.83E-03 6.94E405 Cs-134 8.11E-04 4.52E-05 1.12E-07 8.56E-G4 Cs-137 2.27E+00 5.00E-05 1.20E-05 5.50E-01 1.61E+04 8.20E+08 7.91E+01 3.00E+00 3.96E+02 2.80E+00 2.22E-01 8.40E-03 Cs-137 6.69E-02 2.83E-03 2.66E-06 6.98E-02 Co-0 6.58E+00 2.69E-05 6.30E-04 5.84E-02 1.71E+03 8.70E+07 1.28E+02 1.00E+02 6.40E+02 1.84E-01 2.35E-02 1.84E-02 Co-S0 2.37E-03 5.39E-04 1.48E-05 2.92E-03 Co-57 1.676-01 1.188-06 2.80E-08 3.08E-04 8.95E+00 4.586E+05 1.28E+02 1.00E+02 6.40E+02 9.66E-04 1.23E-04 9.66E-05 Co-57 5.45E-07 7.17E-08 3.46E-12 6.17E-07 Fe55 2.50E-03 6.07E607 0.00E+00 4.81E-03 1.41E+02 7.17E+06 2.50E+01 1.00E+02 1.26E+02 7.89E-02 1.92E-03 7.69E-03 Fe-55 2.23E-05 8.55E-08 0.00E+00 2.24E-05 H-3 2.27E-01 6.40E-08 0.00E+00 2.36E-02 6.88E+02 3.51E+07 0.00E+00 0.00E+00 1,00E+00 4.75E+01 0.00E+00 0.00E+00 H-3 1.45E-03 4.79E-03 0.00E+00 6.25E-03 NI-63 1.19E-02 5.77E-07 0.00E+00 3.55E-01 1.04E+04 5.29E+08 1.28E+02 1.00E+02 6.40E+02 1.12E+00 1.43E-01 1.12E-01 Ni-63 3.09E-04 5.92E-06 0.00E+00 3.156E4 SUM 7.32E-02 8.33E-03 1.76E-05 8.15E-02

PROPOSED CHANGE NO. 216 ATTACHMENT VII Dose Assessment Assuming 100% Release Of Activated Inventory

Attachment VIl - Dose Assessment Assuming 100% Release of Activated Inventory - Liner Activated Liner (100% Inventory)

Key Parameters:

Porosity 0.30 Concrete DensIty 2.20 g/cm' 3

Bulk Density 1.50 g/cm Annual Total Well Water Vol 738.0 m' Yearly Drinking Water 478.0 U.yr IrrigatIon Rate 0.274 Um'-d WaN Surface Area 1131.6 m' Surface Sod Depth 0.15 m 3

Fill Volume 2460.0 m Activated Metal Total Inventory 2.60E+10 Total pCI Surface Area/Open Volume 0.46 m'/m' Concrete Volume 1.13 m' DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION ACTIVATED METAL ANNUAL DOSE NUREG.1727 FGR11 Mlcroshleld Kd Kd Drinking Irrigation DIrect Total Nucllde mremny per mrempCI mrem/y per Nuclide Inventory Fill Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pCUg pCUg FractIon pCI cm Igm cm,/gm Factor pCIQl pCI/g pCI/g mrem/y mremly mremny mrem/y Cs-134 4.39E+00 7.33E-05 6.09E405 0.00E+00 0.00E+00 7.91E+01 3.00E+00 3.96E+02 0.00E+00 0.00E+00 0.00E+00 Cs-134 0.004E00 0.004E00 0.00E+00 0.00E+00 Co-40 6.58E+00 2.69E05 6.30E44 8.40E42 2.18E+09 1.28E102 1.00E+02 6.40E102 4.62E400 5.91E-01 4.62E41 Co-60 5.94E42 1.35E42 3.72E404 7.33E-02 C-14 2.08E+00 2.09146 0.001+00 0.00E+00 0.00E+00 5.00E+00 1.00E+02 2.63E101 0.001EW 0.00E+00 0.00E+00 C14 0.00E+00 0.00E+0 0.00E+00 0.00E+00 Eu-154 3.13E+00 9.55664 3.10E-04 0.00E+0 0.00E+00 4.00E+02 5.00E+03 2.02E+03 0.00E+00 0.00E400 0.00E+00 Eu-154 0.00E+00 0.001W+0 0.000E+0 0.000E+0 Fe-55 2.50E-03 6.07E-07 0.00E+00 9.10E41 2.37E+10 2.50E+01 1.00E+02 1.26E+02 2.54E+02 6.34E+00 2.54E401 Fe55 7.36E402 2.82E-04 0.00E+00 7.39E-02 H-3 2.27E-01 6.40E-08 0,1E+40 0.00E+100 0,00100 0.W1E+00 0.04E+00 1.00E400 0.01E+00 0.001+00 0.00E+00 H-3 0.00E+0 0.001E+0 0.001E+0 0.000E+0 Eu-152 2.87E+00 6.48E-06 2.09E44 0.00E+0 0.00E+00 4.00E+02 5.00E+03 2,02E+03 0.00E+00 0.00E+0 0.00E+00 Eu-152 0.01E+0 0.W1E+00 0.00+00 0.00E+00 NI-3 1.19E-02 5.77E47 0.00E+00 6.00E43 1.56E+08 1.28E+02 1.00E+02 6.40E+02 3.30E-01 4.22E-02 3.30E-02 Ni43 9.11E-05 1.75E-06 0.00E+00 9.28E-0 SUM 2.60E+10 SUM 1.33E-01 1.38E-02 3.72E-04 1.47E-O1

Attachment VII Dose Assessment Assuming 100% Release of Activated Inventory - Concrete ACTIVATED CONCRETE Key Parameters:

3 Porosity 0.30 Concrete Density 2.20 g/cm 3

Bulk Density 1.50 g/cm Annual Total Well Water Vol 738.0 31 Yearly Drinking Water 478.0 L/yr Irrigation Rate 0.274 Urmn-d 2

M WaN Surface Area 1131.6 Surface Soil Depth 0.15 m FMiVolume 2460.0 Activated Concrete Total Inventory 2.08E+10 Total pCi per pCilg Surface Area/Open Volume 0.46 Activated Concrete Total Conc. 1.00 pCI/9 Concrete Volume 1.13 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION ACTIVATED CONCRETE ANNUAL DOSE NUREG-1727 FGR11 Mkcroshleld Kd Kd Drinking Irrigatlon Direct Total Nucilde mromly per mrem/pCI mrem/y per Nuclide Inventory Inventory Fill Concrbt Adsorption Water Fill Concrete Nuclide Water Dose Does Dose Dose pCI/g pCl~g Fraction pCI/g pCI cm/gm cm'lgm Factor pCI/L pCUg pCI/g mromly mremly mrsm/y mrsmly Cs-134 4.39E+00 7.33E-05 6.09E-05 8.40E-03 8.40E.03 1.75E208 7.91E+01 3.OOE+00 3.96E+02 5.97E-01 4.72E-02 1.79E-03 Cs-134 2.09E-02 1.17E-03 2.88E-06 2.21E-02 Co-60 6.58E+00 2.69E-05 6.30E-04 4.OOE-02 4.OOE-02 8.32E+08 1,28E+02 1.00E+02 6.40E+02 1.76E+00 2.25E401 1.76E-01 Co-60 2.26E-02 5.154-03 1.42E404 2.79E-02 C-14 2.08E+00 2.09E-06 0.002E00 5.80E-02 5.80E-02 1.21E+09 5.00E+00 1.00E+02 2.63E+01 6.21E+01 3.10E401 6.21E+00 C-14 6.20E402 5.74E202 0.00E+00 1.19E41 Eu-154 3.13E+00 9.55E-06 3.10E404 9.00E-03 9.00E-03 1.87E+08 4.00E+02 5.00E+03 2.02E+03 1.26E-01 5.03E-02 6.29E-01 Eu-154 5.74E-04 1.75E-04 1.56E-05 7.64E-04 Fe-55 2.50E203 6.07E-07 0.00E+00 1.24E-01 1.24E-01 2.58E+09 2.50E+01 1.00E+02 1.26E+02 2.77E+01 6.92E-01 2.77E200 Fe-55 8.03E-03 3.07E205 0.004E00 8.06E-03 H-3 2.27E-01 6.40E-08 0.00E+00 6.47E-01 6.47E-01 1.35E+10 0.00E+00 0.00E+00 1.00E+00 1.82E+04 0.00E+00 0.00E+00 H-3 5.58E-01 1.84E+00 0.00E+00 2.40E+00 Eu-152 2.87E+00 6.48E-06 2.09E-04 1.11E-01 1.11E-01 2.31E+09 4.00E+02 5.OOE+03 2.02E+03 1.55E+00 6.20E-01 7.75E200 Eu-152 4.80E-03 1.98E-03 1.30E-04 6.91E-03 Ni-63 1.19E-02 5.77E-07 0.002+00 7.00E-03 7.00E-03 1.46E+08 1.28E+02 1.00E+02 6.40E+02 3.08E-01 3.94E-02 3.08E-02 Ni-63 8.50E-05 1.63E-06 0.00+E00 8.66E-5 SUM 6.77E-01 1.90E+00 2.90E-04 2.58E+00

PROPOSED CHANGE NO. 216 ATTACHMENT VIII Dose Assessment for Deep and Surface Soil Using 2.39 pCi/g DCGL

Attachment Vill - Dose Assessment for Deep and Surface Soil Using 2.39pCi/g DCGL SURFACE SOIL Key Parameters:

Sod Depth 0.15 m Surface Soil (Cs-137) Concentration 2.39 pCi/g Surface Soil Total Concentration 2.69 pCi/g DOSE CALCULATION FACTORS SOURCE TERM SURFACE SOIL ANNUAL DOSE NUREG-1727 Total Nuclide mremly per Nudide Soil Dose pClIg Fraction pCilg mnremfy Cs-137 2.27E+00 8.90E-01 2.39E+00 5.43E+00 Co-60 6.58E+00 9.OOE-03 2.42E-02 1.59E-41 H-3 2.27E-01 5.30E-02 1.43E-01 3.24E-02 Ni-63 1.19E-02 4.80E-02 1.29E-01 1.54E-03 SUM 5.63E+00 8/14103

Attachment Vill - Dose Assessment for Deep and Surface Soil Using 2.39pCI/g DCGL DEEP SOIL Key Parameters:

Porosity 0.3 Surface Soil Depth 0.15 m Bulk Density 1.6 g/cm3 Deep Soil (Cs-137) Concentration 2.39 pClg Yearly Drinking Water 478 Lty Deep Soil Total Concentration 2.69 pCI/g IrrigatIon Rate 0.274 L/m2-d Using ResRad results for pCi/L per pCi/g conversion Table I of EC-018-01 half sand half gravel(.44) 6/18/02 DOSE CALCULATION FACTORS SOURCE TERM DEEP SOIL ANNUAL DOSE NUREG.1727 FGR 11 Mlcroshleld Deep Soll Derived Water Water Drinking Irrigation Direct Total Nuclide mrem/y per mremtpCI mrem/y per Nuclide Inventory Conversion Units Inventory Water Dose Dose Dose Dose pCl/g pCl/g Fraction pCI/g pCltL per pCi/g pCi/L mremly mremly mremty mrem/y Cs-137 2.27E+00 5.OOE-05 4.00E-01 8.90E-01 2.39E+00 9.02E-03 2.16E-02 5.16E-04 2.04E-05 9.58E-01 9.58E-01 Co-60 6.58E+00 2.69E-05 2.40E+00 9.00E-03 2.42E-02 2.24E-02 5.43E-04 6.98E-06 1.49E-06 5.81E-02 5.81 E-02 H-3 2.27E-01 6.40E-08 0.OOE+00 5.30E-02 1.43E-01 6.69E+03 9.53E+02 2.92E-02 9.02E-02 0.OOE+00 1.19E-01 Ni-63 1.19E-02 5.77E-07 0.OOE+00 4.80E-02 1.29E-01 6.01E-01 7.76E-02 2.14E-05 3.85E-07 0.OOE+00 2.18E-05

._______________________________l_______________ 2.97E-02 9.02E-02 1.02E+00 1.14E+00

PROPOSED CHANGE NO. 216 ATTACHMENT IX Revised Dose Summation Tables or Containment and Non-Containment

Attachment IX - (Containment) Contaminated Material DCGL And Total Annual Dose Contaminated Material DCGL Basement Contaminated Concrete, (gross beta dpm/100 cm2 ): ZZ o18,000 Special Area Contaminated Concrete, (gross beta dpm/100 cm2 ): L 9,5001 Basement Activated Concrete Total Inventory (pCi): I 4.88E+081 Surface Soil, (Cs- 137 pCilg): 1 2.39 Deep Soil, (Cs- 137 pCi/g): 1 2.39 BOP Embedded Piping [Limit: lOOK], (gross beta dpm/100 cm2):

ZI oo~oo Spray Building Pump Piping [Limit 800K], (gross beta dpm/100 cm 2 ): 800,0001 Ground Water, (H-3, pCi/L): 6,8121 Surface Water, (H-3, pCi/L): 1 9601 Buried Piping, (gross beta dpm/100 cm2): 1 9,800 Contaminated Material Annual Dose Drinking Direct, Inhalation Total Material Water & Ingestion Annual Dose (mrem/y) (mremly) (mremly)

Contaminated Concrete 7.32E-02 8.35E-03 8.15E-02 Activated Concrete 1.36E-02 3.30E-02 4.66E-02 Surface Soil 0.OOE+00 5.63E+00 5.63E+00 Deep Soil 2.97E-02 1.1IIE+00 1.14E+00 BOP Embedded Piping 4.59E-02 5.24E-03 5.1 1E-02 Embedded Spray Bldg Pump Piping 7.60E-02 8.68E-03 8.47E-02 Ground Water 2.08E-01 0.OOE+00 2.08E-01 Surface Water 2.94E-02 1.27E-03 3.06E-02 Buried Piping 6.33E-04 1.89E-03 2.52E-03 Total 0.48 6.79 7.27 mrem/y mremly mrem/y 8/14/03

Attachment IX. (Containment) EC-014-01(MY)

Attachment 1 Rev. 2.0 Contaminated Concrete Page 12 of 25 CONTAMINATED CONCRETE Key Paramters:

Porosity 0.30 Concrete Density 2.20 g/cm3 3 3 Buik Density 1.50 g/cm Annual Total Well Water Vol 738.0 m Yearly Drnking Water 478.0 L/yr Irrigation Rate 0.274 LM2_-d 2

Wail Surface Area 1131.8 m Surface Soil Depth 0.15 m 3

Fill Volume 2460.0 m Gross Beta DCGL 1.80E+04 dpm/100 cm Surface Area/Open Volume 0.48 Gross Beta Nuclide Fraction 0.6160 2

Concrete Vokum 1.13 Total Inventory 2.92E+04 dprm/100 cm DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION CONTAMINATED CONCRETE ANNUAL DOSE NUREG-1727 FGR11 Mlcroshleld Kd Kd Drinking Irrigatlon Direct Total Nueile mremly per mrem/pCI mremly per Nuclid Inventory Inventory FIll Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pCIg pC11g Fraction dpmr/100 m PCI Gm'/gm cm'Igm Factor pCI/L pC11g pCl/g mremly mremly mreml mrem/y Sr-90 1.47E+01 1.42E-04 0.00E+00 2.80E-03 8.19E+01 4.17E+06 6.02E+01 1.00E+00 3.02E802 1.87E-02 1.13E-03 1.87E-05 Sr-90 1.27E-03 1.22E-04 0.00E+00 1.39E-03 Cs-134 4.39E+00 7.33E405 6.09E405 4.55E.03 1.33E+02 6.77E+06 7.91E+01 3.00E+00 3.96E+02 2.31E.02 1.83E803 6.94E.05 CsM134 8.11E-04 4.52E405 1.12E407 8.56E-04 Cf-137 2.27E+00 5.00E-05 1,20E.05 5.50E41 1.61E+04 8.20E+08 7.91E+01 3.008E00 3.96E+02 2.80E+00 2.22E401 8.40E403 Cs-137 6.69E-02 2.83E-03 2.66E-06 6.98E-02 Co-80 6.58E+00 2.69E-05 6.30E.04 5.84E-02 1.71E+03 8.70E+07 1.28E+02 1.00E+02 6.40E802 1.84E-01 2.35E-02 1.84E-02 Co-60 2.37E-03 5.39E-04 1.48E-05 2.92E-03 Co-57 1.67E-01 1.18E-06 2.80E48 3.06E-04 8.95E+00 4.56E+05 1.28E+02 1.00E+02 6.40E+02 9.66E-04 1.23E-04 9.66E-05 Co-57 5.45E-07 7.17E8-0 3.46E-12 6.17E-07 Fe-55 2.504-03 6.07E-07 0.00E+00 4.81E-03 1.41E+02 7.17E+06 2.50E+01 1.00E+02 1.26E+02 7.69E-02 1.92E-03 7.69E-03 Fe-55 2.23E-05 8.55E-08 0.00E+00 2.24E-05 H-3 2.27E-01 6.40E-08 0.00E+00 2.36E-02 6.88E+02 3,51E+07 0.00E+00 0.00E+00 1.00E+00 4.75E+01 0.00E+00 0.00E+00 H-3 1.45E-03 4.79E-03 0.00E+00 6.25E-03 Ni-63 1.19E402 5.77E-07 0.00E+00 3.55E-01 1.04E+04 5.29E+08 1.28E802 1.00E+02 6.40E+02 1.12E+00 1.43E401 1.12E401 Ni-63 3.09E-04 5.92E-06 0.00E+00 3.158-04 SUM 7.32E-02 8.33E-03 1.76E-05 8.15E-02

Attachment IX - (Containment) EC-014-01(MY)

Attachment 2 Rev. 2.o Surface Soil Page 13 of 25 SURFACE SOIL Key Parameters:

Soil Depth 0.15 m Surface Soil (Cs-137) Concentration 2.39 pCi/g Surface Soil Total Concentration 2.69 pCi/g DOSE CALCULATION FACTORS SOURCETERM SURFACE SOIL ANNUAL DOSE NUREG-1727 Total Nucflde mremly per Nuclide Soil Dose PClS Fraction pCI/g mremly Cs-137 2.27E+00 8.90E-01 2.39E+00 5.43E+00 Co-60 6.58E+00 9.OOE-03 2.42E-02 1.59E-01 H-3 2.27E-01 5.30E-02 1.43E-01 3.24E-02 Ni-63 1.19E-02 4.80E-02 1.29E-01 1.54E-03 SUM 5.63E+00 8/14103

Attachment IX. (Containment) EC-014-01(MY)

Attachment 3 Rev. 2,0 Activated Concrete Page 14 of 25 ACTIVATED CONCRETE (50 yr Liner Breach and Diffusion)

XKy Parameters:

3 Porosity 0.30 Concrete Density 2.20 g/cm 3

Bulk Density 1.60 9/cm Annual Total Wet Water Vol 738.0 2

Yearly Drnking Water 478.0 Ufyr IrrIgation Rate 0.274 Um -d WaN Surface Area 1131.6 Ml Surface Soil Depth 0.15 m Fli Volume 2480.0 ml Actvated Concrete Total Inventory 4.88E*08 pCI Surface AreatOpen Volume 0.48 m'/mn Concrete Volume 1.13 m DOSE CALCULATION FACTORS SOURCE TERM1 Kd WATER, FILL, CONCRETE CONCENTRATION ACTIVATED CONCRETE ANNUAL DOSE NUREO.1727 FOR111 Microshield Kd Kd Drinking Irrigation Dlrect Total Nuclde mremlyper mrem/pCil mromly per Nucilde Inventory FIN Concrete Adsorption Water Fill Concrete Nucilde Water Dose Dose Dose Dose pCUg pCIQ Fraction PCI cm'lgm cm'lgm Factor pCitL pCI/g PCVI mramly iemnty mremly mromly Cs-134 4.39E+00 7.33E-05 6.09E-05 572E003 2.79E+06 7.91E+01 3.00E.00 3.96E+02 9.54E403 7.55E-04 2.86E405 Cs-1 34 3.34E404 1.86E-05 4.60E-08 3.53E-04 Co-80 6.58+E00 2.69E.05 6.30E-04 2.73E-02 1.33E+07 1.28E+02 1.OOE.02 6.40E+02 2.82E-02 3.60E-03 2.82E403 Co-60 3.63E404 8.25E-05 2.27E-06 4.47E-04 C-14 2.080E00 2.09E46 0.00+E00 1.48E-01 7.22E+07 5.00E+00 1.00E+02 2.63E.01 3.72E+00 1.86E-02 3.72E-01 C-14 3.71E-03 3.44E-03 0.OOE+00 7.15E-03 Eu-154 3.13E+00 9.55E-06 3.10E-04 6.10E-03 2.98E006 4.00E+02 5.00E+03 2.02E403 2.OOE-03 8.00E-04 9.99E-03 Eu-154 9.12E.06 2.78E-06 2.48E407 1.21E-05 Fe-55 2.50E-03 6.07E-07 0.00+E00 8.44E-02 4.12E+07 2.50E+01 1.00E+02 1.26E+02 4.42E-01 1.10E-02 4.42E-02 Fe-55 1.28E404 4.91E-07 0.000E00 1.29E-04 H-3 2.27E-01 6.40E08 o.ooE+00 4.41E-01 2.15E+08 0.00+E00 0.00+E00 1.00E000 2.91E+02 0.00+E00 0.OOE+00 H-3 8.92E-03 294E-02 0.00E+00 3.834-02 Eu-152 2.87E+00 6.46E0.6 2.094-04 7.56E-02 3.69E+07 4.00E+02 5.00E+03 2.02E+03 2.48E-02 9.91E-03 1.24E01 Eu-152 7.67E-05 3.16E-05 2.07E-06 1.10E-04 Ni-63 1.19E-02 5.77E-07 0.000E00 2.11E401 1.03E*08 1.28E+02 1.00E+02 6.40E+02 2.18E-01 2.78E-02 2.18E-02 Ni-63 6.01E-05 1.154-06 0.00+E00 6.13E4-5 9.99E-01 4.88E+08

_ .. SUM

.__________ 1.36E-02 3.30E-02 4.63E406 4.66E-02

Attachment IX - (Containment) WC.014-01(MY)

Attachment 4 Rev. 2.0 Activated Rebar Page 15 of 25 Activated Rebar Key Parunetwo:

3 Porsity 0.30 Concrete Density 2.20 gcm 3

Bulk Density 1.50 g/cm3 Annual Total Wel Water Vol 738.0 m 2

Yearly Drinking Water 478.0 LUr Irrigation Rate 0.274 Um -d Wai Surface Area 1131.6 m2 Surface Soil Depth 0.15 m 3

FiNVodume 2460.0 m Activated Concrete Total Inventory 9.01E+08 pCi (1.9Activated Concrete Inventory) 2 Surface Area/Open Volume 0.46 mWm Concrete Volume 1.13 m3 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION ACTIVATED CONCRETE ANNUAL DOSE NUREG-1727 FGR11 Mhcroehield Kd Kd Drinking Irrigation Direct Total Nuclide mrem/y per mrom/pCi mrnm/y per Nuclide Inventory Flil Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pCUg pCi/g Fraction pCi cm,/gm cm3Igm Factor pCI/IL pCUg pCI/9 mrommly mrem/y mrem/y nremly Cs-134 4.39E+00 7.33E205 8.09E-05 0.004E00 0.00E+00 7.91E201 3.00E+00 3.96E+02 0.00*E00 0.00E.00 O.00E+00 Cs-134 0.00E400 0.004E00 0.00E+00 0.00E+00 Co-60 6.58E+00 2.69E42 6.30E-04 3.00E-02 2.70E207 1.28E202 1.00E202 6.40E+02 5.72E-02 7.31E-03 5.72E-03 Co-60 7.36E-04 1.67E-04 4.61E406 9.08E.04 C-14 2.08E+00 2.09E-06 0.00E+00 0.00E+00 0.00E200 5.0E2400 1.00E202 2.63E201 0.00E+00 0.004E00 0.002E00 C-14 0.002E00 0.00E+00 0.004E00 0.00E400 Eu-154 3.13E400 9.55E-06 3.10E-04 0.0012400 0.00E+00 4.00.E02 5.002E03 2.02E+03 0.00E400 0.002E00 0.002E00 Eu-154 0.002E00 0.00+E00 0.002E00 0.00E400 Fe-55 2.50E-03 6.07E-07 0.00E+00 8.18E404 7.37E+05 2.50E+01 1.00E+02 1.26E+02 7.90E403 1.98E.04 7.90E404 Fe-55 2.29E-06 8.78E-09 0.004E00 2.30E-06 H-3 Z27E-1 8.40E208 0.00E+00 0.002E00 0.00E+00 0.00+E00 0.OOE+00 1.00E+00 0.00+E00 0.002E00 0.00E2+00 H-3 0.OOE.00 0.00E+00 0.00+E00 0.00E+00 Eu-1 52 2.87E+00 6.48E246 2.09E-04 0.002400 0.OOE+00 4,00E+02 5.00E+03 2.02E+03 0.00E+00 0.00E+00 0.00E+00 Eu-152 0.00E400 0.00+E00 0.00E+00 0.004E00 NI-63 1.19E-02 5.77E-07 0.00+E00 9,9E-01 8.73E+08 1.28E+02 1.00E+02 6.40E+02 1.85E+00 2.36E-01 1.85E-01 NI-63 5.10E-04 9.78E-06 0.00E+00 5.19E204 SUM 1.25E-03 1.77E-04 4.61E-06 1.43E403 9/5102-2

Attachment IX. (Containment) EC.014-01(MY)

Attachment 5 Rev. 2.0 Deep Soil Page 16 of 25 DEEP SOIL Key Parameters:

Porosity 0.3 Surface Soil Depth 0.15 m Bulk Density 1.6 g/cm 3 Deep Soil (Cs-137) Concentration 2.39 pCilg Yearly Drinking Water 478 Lly Deep Soil Total Concentration 2,69 pClg 2

Irrigation Rate 0.274 um -d Using ResRad results for pCI/L per pCIlg conversion Table I of EC-018-01 half sand half gravel(.44) 6118102 DOSE CALCULATION FACTORS SOURCE TERM DEEP SOIL ANNUAL DOSE NUREG-1727 FGR 11 Microshlold Deep Soil Derived Water Water Drinking Irrigation Direct Total Nuclide mrem/y per mrem/pCI mremly per Nuclide Inventory Conversion Units Inventory Water Dose Dose Dose Dose pClIg pClIg Fraction pCi/g pCI/L per pCi/g pCI/L mremly mremly mremly mremly Cs-137 2.27E+00 5.OOE-05 4.OOE-01 8.90E-01 2.39E+00 9.02E-03 2.16E-02 5.16E-04 2.04E-05 9.58E-01 9,58E-01 Co-60 6.58E+00 2.69E-05 2.40E+00 9.OOE-03 2.42E-02 2.24E-02 5.43E-04 6.98E-06 1.49E-06 5.81 E-02 5.81E-02 H-3 2.27E-01 6.40E-08 0.00E+00 5.30E-02 1.43E-01 6.69E+03 9.53E+02 2.92E-02 9.02E-02 0.00E+00 1.19E-01 Ni-63 1.19E-02 5.77E-07 0.OOE+00 4.80E-02 1i29E-01 6.01E-01 7.76E-02 2.14E-05 3.85E-07 0.OOE+00 2.18E-05 2.97E-02 9.02E-02 1 .02E+00 1 .14E+00

Attachment IX - (Containment) EC-014-01(MY)

Attachment 6 Rev. 2.0 Ground Water Page 17 of 25 GROUND WATER Key Parameters:

Annual Water Intake 478 ity Dose Calculation Factors Source Term Ground Water Annual Dose FGR 11 Drinking Nuclide mrem/pCi Nuclide Inventory Water Dose Fraction pCi1L mremly H-3 6.40E-08 1.00E+00 6,812 2.08E-01 l ____________________ ________________ SUM 2.08E-01 8130102

Attachment IX - (Containment) EC-014-O1 (MY)

Attachment 7 Rev. 2.0 Surface Water Page 18 of 25 SURFACE WATER Key Parameters:

Annual Water Intake 478 Lly Annual Fish Consumption 20.6 Kgly Dose Calculation factors Source Term Surface Water Annual Dose FGR 11 Bloaccumulation Water Drinking Fish Ingestion Total Nuclide mrem/pC1 Factor for Fish Nuclide Inventory Water Dose Dose Dose pCiIKg per pCIIL Fraction pCiIL mremly mremly mremly H-3 6.40E-08 1.OOE+00 1.OOE+00 960 2.94E-02 1 .27E-03 3.06E-02 SUM 2.94E-02 1 27E-03 3.06E-02

Attachment IX - (Containment) EC.014-01 (MY)

Attachment 8 Rev. 2.0 Burled Piping Page 19 of 25 BURIED PIPING Key Parameters:

Porosity 0.3 Burled Pipe Conversion Factor 2.59E-04 pCig per dpm/100 cm2 Bulk Density 1.6 g/cm3 Gross Beta DCGL 9.80E+03 dpm/100 cm2 Yearly Drinking Water 478 LUy Gross Beta Nuclide Fraction 0.616 Irrigation Rate 0.274 2

Lm -d Total Inventory 1.59E+04 dpm/100 cm2 Surface Soil Depth 0.15 m Dose Calculation Factors Source Term Burled Piping Annual Dose FGR 11 NUREG-1727 Mlcroshleld Water Pipe Surface Soil Drinking Irrigation Direct Total Nucilde mrom/pCI mremly per mremly per Nucilde Inventory Inventory Inventory Water Dose Dose Dose Dose 2

pCI/g pCI/g Fraction pCI/L per pCI/g dpm/100cm pCI/g mremly mrem/y mremly mremly Sr-90 1.42E-04 1.47E+01 O.OOE+00 2.80E-03 2.1 5E-02 4.46E+01 1.15E-02 1.68E-05 1.52E-06 O.OOE+00 1.832-05 Cs-134 7.33E-05 4.39E+00 2.21 E-05 4.55E-03 2.25E-05 7.23E+01 1.87E-02 1.48E-08 7.71E-10 4.14E-07 4.30E-07 Cs-137 5.OOE-05 2.27E+00 3.97E-06 5.50E-01 3.27E-04 8.75E+03 2.27E+00 1.77E-05 7.01 E-07 9.01E-06 2.74E-05 Co-60 2.69E-05 6.58E+00 2.53E-04 5.84E-02 8.14E-04 9.29E+02 2.41E-01 2.52E-06 5.37E-07 6.092-05 6,402-05 Co-57 1.18E-06 1.67E-01 9.44E-09 3.06E-04 1.15E-04 4.88E+00 1.26E-03 8.18E-11 1.01E-11 1.19E-11 1.04E-10 Fe-55 6.07E-07 2.502-03 O.OOE+00 4.81E-03 4.30E-05 7.66E+01 1.98E-02 2.47E-10 8.89E-13 O.OOE+00 2.48E-10 H-3 6.40E.08 2.27E-01 O.OOE+00 2.36E-02 1.98E+02 3.75E+02 9.70E-02 5.88E-04 1.82E-03 O.OOE+00 2.41E-03 Ni-63 5.77E207 1.19E-02 O.OOE+00 3.55E-01 2.09E-02 5.65E+03 1.46E+00 8.42E-06 1.51E-07 O.OOE+00 8.57E-06 SUM 6.33E-04 1.82E-03 7.03E-05 2.52E-03

EC-014-01(MY)

Attachment IX - (Containment)

Attachment 9 Rev. 2.0 BOP Embedded Piping Page 20 of 25 BOP EMBEDDED PIPE Key Parameters:

Po-iY 0.30 Concrete Density 2.20 i/cm' 8ulk Density 1.50 9/cm3 Surface Soil Depth 0.15 m Yearly Driring Water 478.0 ILq Irrigation Rate 0.274 Llm'-d Wal Surface Area 1131.6 Annual Total Wel Water Vol 738 Ml FM Voiume 2460.0 Mlhr Embedded Poe Conversion Factor 5754.5 pCI per dpm/100 cmr 2

Surface ArealOpen Volume 0.46 Gross Bets DCGL 1.00E+05 dpm/100 cm Conrete Volume 1.13 Gross Beta Nucide Fraction 0.616 Total Inventory 1.62E+05 dpm/100 cm' DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION EMBEDDED PIPE ANNUAL DOSE NUREG-1727 FGR111 Microsheld Kd Kd Drinking Irrigation DIrect Total Nucilde mrrm/y per mrsm/pCI mrsm/y pr Inventory Inventory Fill Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pCUg pCUg Fraction dpml00 cm' PCI cm'/gm cmi/gm Factor pCIIL pCI/g pCI/g mremly mrornly mrem/y memily Sr-90 1.47E401 1.42E44 0.004E00 2.80E-03 4.55E+02 2.62E+06 6.02E+01 1.00E+00 3.02E+02 1.18E-02 7.07E-04 1.18E-05 Sr-90 7.98E-04 7.68E-05 0.004E00 8.75E-04 Cs-134 4.39E+00 7.33E-05 6.09E45 4.55E-03 7.38E+02 4.25E406 7.91E.01 3.00E+00 3.96E+02 1.45E-02 1.15E-03 4.36E-05 Cs-134 5.09E-04 2.83E-05 6.99E4-8 5.37E-04 Cs-137 2.27E200 5.00E-05 1.20E-05 5.50E-01 8.93E204 5.14E208 7.91E201 3.00E+00 3.96E+02 1.76E+00 1.39E-01 5.27E-03 Cs-137 4.20E-02 1.77E-03 1.67E-06 4.38E-02 co-e 6.58E+00 2.69E-05 6.30E44 5.84E-02 9.48E403 5.46E+07 1.28E202 1.00E202 6.40E+02 1.16E-1 1.48E-02 1.16E02 Co-60 1.49E-03 3.38E44 9.30E-06 1.83E-03 Co-57 1.67E-01 1.18E-06 2.80E-08 3.06E-04 4,97E+01 2.86E+05 1.28E+02 1.00E+02 6.40E202 6.06E-04 7.74E-05 6.06E-05 Co-57 3.42E07 4.50E-08 2.17E-12 3.87E-07 FeS- 2.50E-03 6.07E-07 0.00E+00 4.81E-03 7.82E.02 4.502.06 2.50E+01 1.00E+02 1.26E+02 4.82E-02 1.21E-03 4.82E-03 Fe-S5 1.40E-05 5.36E-08 0.OOE+00 1.40E-05 H-3 Z2E4-01 6.40E-08 0.00E-00 2.36E-02 3.82E403 2.20E.07 0.002.00 0.00E+00 1.00E+00 2.98E+01 0.OOE+00 0.00E+00 H-3 9.12E-04 3.01E-03 0.00+E00 3.92E-03 NI-63 1.19E-02 5.77E-07 0.00+E00 3.55E-01 5.77E204 3.322.08 1.28E+02 1.00E202 6.40E+02 7.02E-01 8.97E-02 7.02E-02 Ni-63 1.94E-04 3.72E-06 0.00E+00 1.97E-04 SUM 4.59E-02 5.23E-03 1.10E-05 5.11E-02

Attachment IX. (Containment) EC-014.01(MY)

Attachment 10 Rev. 2.0 Spray Building Embedded Pump Piping Page 21 of 25 EMBEDDED SPRAY PUMP PIPING Key Parameters:

3 porosity 0.30 Concrete Density 2.20 g/cm Buik Density 1.50 g/cm' Suirace Soil Depth 0.15 m Yeawty DrM"Ig Wwr 478.0 iVr Irrigation Rate 0.274 Um'-d 2

Wall Sutace Agea 1131.6 m Annual Total Wet Water Vol 738 m' 2

FINVoume 2450.0 ms Embeded Pipe Conversion Factor 1191.7 pC per dpm/100 cm 2

Surface Aesopen Volume 0.46 m/mh Gross Bats DCOL 8.001+05 dpmr/100 c2 Conarete Voume 1.13 m' Gross Bet Nucilde Fraction 0.616 Total Inventory 1.30E-06 dpm/100 cm2 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION EMBEDDED PIPE ANNUAL DOSE NUREG-1727 FOGR11 Mlcroehleld Kd Kd Drinking Irrigation Direct Total Nuclide mrsnVy per mrenm/pCi mrom/y per Inventory Inventory Fill Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pClig pCI/g Fraction dpom/O10cm' pCI cm'lgm cm'igm Factor pCIL pCI/g pCI/g mremny memly mwrmly mremly Sr-90 1.47E+01 1.42E404 0.004E00 2.80E-03 3.64E.03 4.34E+06 6.02E401 1.00EO00 3.02E+02 1.95E-02 1.17E-03 1.95E-05 Sr-90 1.32E-03 1.27E-04 0.00.E00 1.45E-03 Cs-134 4.39E+00 7.33E405 6.09E-05 4.55E403 5.91E+03 7.04E+06 7.91E+01 3.001400 3.96E+02 2.41E402 1.90E-03 7.22E-05 Cs-134 8.43E-04 4.69E-05 1.16E-07 8.90E-04 Cs-137 2.27E+00 5.00E-05 1.20E-05 5.50E-01 7.15E+05 8.52E+08 7.91E401 3,00E500 3.96E+02 2.91E+00 2.30E-41 8.73E-03 Cs-137 6.96E02 2.94E403 2.76E406 7.25E402 Co-0 6.s58E+00 2.69f-05 6.30E04 5.84E-02 7.59E+04 9.04E407 1.28E+02 1.00E+02 6.40E+02 1.91E-01 2.45E-02 1.91E-02 Co-60 2.46E403 5.60E-04 1.54E405 3.04E403 Co-57 1.67E-01 1.18E-06 2.80E48 3.064-04 3.98E502 4.74E+05 1.26E+02 1.005E02 6.40E502 1.00E-03 1.28E-04 1.00E-04 Co-57 5.66E-07 7.45E-08 3.59E-12 6.41E-07 Fe-55 2.50E-03 6.07E-07 0.00E+00 4.61E-03 6.25E+03 7.45E406 2.50E+01 1.00E.02 1.26E+02 7.99E-02 2.00E-03 7.99E-03 Fe-55 2.32E-05 8.88E-08 O.OOE+00 2.33E-05 H41-3 2.27E-41 6.40E-08 0.00E+00 2.36E-02 3.06E+04 3.64E+07 O.00E40O 0.OOE.00 1.00E+00 4.94E+01 0.00E+00 0.00E+00 H-3 1.51E-03 4.98E-03 0.00+E00 6.49E-03 Ni-63 1.19E-02 5.77E-07 0.00E+00 3.55E-01 4.61E+05 5.50E+08 1.28E+02 1.00E+02 6.40E502 1.16E+00 1.49E-01 1.16E41 NI-63 3.21E-04 6.16E-06 0.00EO00 3.27E4 1.30E+06 1.55E509 SUM 7.60E-02 6.66E-03 1.83E-05 8.475-02

Attachment IX- (Containment) EC.014-01(MY)

Attachment 11 Rev. 2.0 Special Areas Page 22 of 25 CONTAMINATED CONCRETE SPECIAL AREAS Key Parameters:

Porosity 0.30 Concrete Density 2.20 g/cm' 2

Bulk Density 1.50 9/cm Annual Total Well Water Vol 738.0 Ms Yearly Drinking Water 478.0 Irrigation Rate 0.274 L/m-d Wall Surface Area 1131.6 Lrnr Surface Soil Depth 0.15 m S1SE-02 e-- Total Dose Contaminated Concrete 2 2 Fin Volume 2460.0 M'm Special Areas Gross Beta DCGL 9.50E+03 dpm/100 cm Surface Area/Open Volume 0.46 2 Gross Beta Nucdide Fraction 0.6672 2.922-02 Eva Total Dose Special Areas M 1m Concrete Volume 1.13 Total Inventory 1.42E+04 dpm/100 cm' DOSE CALCULATION FACTORS SOURCE TERM Kd WATER. FILL, CONCRETE CONCENTRATION CONTAMINATED CONCRETE ANNUAL DOSE NUREG-1177 FOR 11 Mlcroshleld Kd Kd Drinking Irrigation Direct Total Nuclide mrely per mr-m/pCI mrm/y per Nucilde Inventory Inventory Fill Concrete Adsorption Water Fill Concrete Nucilde Water Dose Dose Dose Dose 2

pC1Ug pCI1g Frsctuon dpml00 cm PCI cm'/gm cm3/gm Factor pCi/L pCUg pCUg mrsm/y mremty mremly mrem/y Sr-90 1.47E+01 1.42E-04 o.ooE+00 6.874E-03 9.79E+01 4.99E+06 6,12E+01 1.00E+00 3.07E+02 2.20E-02 1.35E403 2.20E-05 Sr-90 1.50E-03 1.44E404 0.00E+00 1.64E-03 Sb-125 9.77E-01 2.81E-06 3.83E-06 4.523E403 6.44E+01 3.28E+06 4.50E+01 0.00E+00 2.26E+02 1.97E-02 8.86E-04 0.005+00 Sb-125 2.64E-05 8.55E-06 3.39E-09 3.50E-05 Cs-134 4.39E+00 7.33E-05 6.09E-05 2.815E-03 4.01E+01 2.04E+06 7.91E+01 3.00E+00 3.96E+02 6.98E-03 5.52E-04 2.09E-05 Cs-134 2.45E404 1.36E-05 3.36E-08 2.58E-04 Cs-137 2.27E+00 5.00E-05 1.204-05 2.890E401 4.12E+03 2.10E+08 7.91E+01 3.00E+00 3.96E+02 7.17E401 5.67E-02 2.15E-03 Cs-137 1.71E-02 7.23E-04 6.80E-07 1.79E-02 Pu-238 1.00E201 3.20E-03 2.45E-25 1.165E404 1.66E500 8.46E+04 5.50E+02 5.00E+03 2,77E+03 4.14E-05 2.28E-05 2.07E-04 Pu-238 6.33E205 1.84E-07 5.58E-30 6.35E-05 Pu-239 1.09E+01 3.542-03 6.10E-15 8.752E-05 1.252+00 6.35E+04 5.50E+02 5.00E+03 2.77E+03 3.11E05 1.71E-05 1.55E404 Pu-239 5.26E405 1.51E-07 1.04E-19 5.28E-05 Pu-240 1.09E+01 3.54243 7.52E-26 8.750E-05 1.25E+00 6.35E+04 5.50E+02 5.00E+03 2.77E+03 3.11E-05 1.71E-05 1.55E-04 Pu.240 5.26E-05 1.51E.07 1.29E-30 5.28E-05 Pu-241 3.47E-01 6.85E-05 0.00E+00 6.705E-03 9.55E+01 4.87E+06 5.50E+02 5.002+03 2.77E+03 2.38E-03 1.31E-03 1.19E-02 Pu-241 7.80E-05 3.67E407 0.00E+00 7.84E-05 Am-241 1.19E+01 3.64E203 1.65E-19 5.929E-04 8.44E+00 4.30E+05 1.90E+03 5.NOE+03 9.51E+03 6,13E-05 1.16E-04 3.06E-04 Am-241 1.07E404 3.24E-07 1.93E-23 1.07E-04 Cm-243 7.81E+00 2.51E43 1.27E-08 4.649E-05 6.62E-01 3.37E+04 4.00E+03 5.00E+03 2.00E+04 ,.28E-06 9.14E4-6 1.14E-05 Cm-243 2.74E-06 7.93E-09 1.16E-13 2.75E-06 Cm-244 6.OOE+00 2.02E-03 9.81E-25 4.454E-05 6.34E201 3.23E+04 4.00E+03 5.00E+03 2.00E+04 2.19E-06 8.75E-06 1.09E-05 Cm-244 2.11E-06 5.84E-09 8.59E-30 2.12E-06 Co-60 6.58E+00 2.69E-05 6.30E-04 3.639E-01 5.18E+03 2.64E+08 1.28E+02 1.00E+02 6.40E+02 5.59E-01 7.14E-02 5.59E-02 Co-60 7.19E-03 1.64E203 4.50E-05 8.87E-03 Co-57 1.67E01 1.18E-06 2.80E-08 0.00E+00 0.00E+00 1.28E+02 1.00E+02 6.40E+02 0.00E+00 0.00E+00 0.00E+00 Co-57 0.00E+0 0.00E+00 0.00E+00 0.00E+00 Mn-54 1.67E+00 2.77E-06 4.40E-05 4.028E-04 5.74E+00 2,92E+05 5.00E+01 0.N2E+00 2.51E+02 1.58E-03 7.89E505 0.00E+00 Mn-54 2.09E-06 1.17E406 3.47E-09 3.26E-06 Fe-55 2.504-03 6.07E-07 0.0E+00 2.235E-02 3.18E+02 1.62E+07 2.50E+01 1.00E+02 1.26E+02 1.74E.01 4.35E403 1.74E-02 Fe-55 5.05E-05 1.93E-07 0.00E+00 5.07E-05 H-3 2.27E-01 6.40E-08 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 1.00E+00 0.00E+0 0.00E+00 o.ooEo00 H-3 0.00+E00 0.02E+0 0.00E+00 0.N0E+00 Ni-63 1.19E-02 5.77E-07 0.00E+00 3.024E201 4.31E+03 2.19E+08 1.28E+02 1.00E+02 6.40E+02 4.65E-01 5.94E-02 4.65E-02 Ni-63 1.28E-04 2.46E-06 0.00E+00 1.31E-04

__ _ __ __ _ __ __ _ __ __ _ __ __ _ __ __ _ __ __ _ __ __ __ __ _ ___ __ __ __ _ __ _ __ __ __ _ __ __ __ _ __ __ _ __ __ __ __ _ __ _ __ _ SUM 2.66 -0232.5 32-03745 72-0522.9 22-0

Attachment IX - (Non-Containment) Contaminated Material DCGL And Total Annual Dose Contaminated Material DCGL Basement Contaminated Concrete, (gross beta dpm/ 00 cm 2 ):

Special Area Contaminated Concrete, (gross beta dpm/100 cm2 ): 1 9,50 Basement Activated Concrete Total Inventory (pCi): I 4.88E+08l Surface Soil, (Cs-137 pCi/g): 1 2.39 Deep Soil, (Cs-137 pCilg): 1 2.391 BOP Embedded Piping [Limit: lOOK], (gross beta dpmI/00 cm 2):

Spray Building Pump Piping [Limit 800K], (gross beta dpm/I00 cm 2 ):

Ground Water, (H-3, pCi/L): 16,8121 Surface Water, (H-3, pCi/L): 1 9601 Buried Piping, (gross beta dpm/100 cm2): L 9I8001 Contaminated Material Annual Dose Drinking Direct, Inhalation Total Material Water & Ingestion Annual Dose (mrem/y) (mrem/y) (mrem/y)

Contaminated Concrete 2.70E-01 3.08E-02 3.01E-01 Activated Concrete 0.OOE+00 0.OOE+00 0.00E+00 Surface Soil 0.OOE+00 5.63E+00 5.63E+00 Deep Soil 2.97E-02 1.11 E+00 1.14E+00 BOP Embedded Piping 4.59E-02 5.23E-03 5.1 IE-02 Embedded Spray Bldg Pump Piping 7.60E-02 8.67E-03 8.47E-02 Ground Water 2.08E-01 0.00E+00 2.08E-01 Surface Water 2.94E-02 1.27E-03 3.06E-02 Buried Piping 6.33E-04 1.89E-03 2.52E-03 Total 0.66 6.78 7.44 mrem/y mrem/y mrem/y 8/14/03

Attachment IX - (Non-Containment) EC-014.01(MY)

Attachment I Rev. 2.0 Contaminated Concrete Page 12 of 25 CONTAMINATED CONCRETE Key Paameters:

Porosity 0.30 Concrete Density 2.20 gicmn 3 3 Bulk Density 1.50 9/cm Annual Total Well Water Vol 738.0 m 2

Yearly Drinking Water 478.0 Llyw Irrigation Rate 0.274 L/m -d Wal Surface Area 4182.0 Surface Soil Depth 0.15 m FlINVolume 2460.0 m21m Gross Bets DCGL 1.80E+04 dpm/100 cm' Surface Arss/Open Volume 1.70 Gross Beta Nudide Fraction 0.6160 Concrete Volume 4.18 Total Inventory 2.92E+04 dpm/lOO rm2 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION CONTAMINATED CONCRETE ANNUAL DOSE NUREG-1727 FGR111 Mlcroshield Kd Kd Drinking Irrigatlon DIrect Total Nuclid. mremty per mrem/pCi mremly per Nucilde Inventory Inventory Fill Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose 2

pCtg pCUg Frection dpm/100 cm pCI cmlgm cm'lgm Factor pCiIL pClg pCI/g mramly mremly mramly mremly Sr-90 1.47E+01 1.42E-04 O.OOE+00 2.80E-03 8.19E+01 1.54E+07 6.02E+01 1.OOE+00 3.01E+02 6.93E-02 4.17E403 6.93E-05 Sr.90 4.70E-03 4.52E-04 O.OOE+00 5.15E-03 Cs-134 4.39E+00 7.33E-05 6.09E-05 4.55E-03 1.33E+02 2.50E507 7.91E+01 3.00E+00 3.96E+02 8.55E402 6.77E-03 2.57E-04 Cs-134 3.00E-03 1.67E-04 4.12E-07 3.16E.03 Cs-137 2.27E+00 5.00E-05 t.20E-05 5.50E-01 1.61E+04 3.03E+09 7.91E501 3.005E00 3.96E502 1.03E+01 8.19E-01 3.10E402 Cs-137 2.47E-01 1.04E502 9.82E-06 2.58E-01 Co-60 6.58E+00 2.69E-05 6.30E-04 5.84E-02 1.71E+03 3.22E508 1.28E+02 1.OOE402 6.405402 6.80E-01 8.68E-02 6.80E-02 Co-60 8.74E-03 1.99E-03 5.47E-05 1.08E502 Co-57 1.67E-1 1.18E-06 2.80E-08 3.06E-04 8.95E+00 1.69E+06 1.28E+02 1.00E+02 6.40E+02 3.57E-03 4.56E-04 3.57E-04 Co-57 2.01E-06 2.65E-07 1.285-11 2.28E-06 Fe-55 2.50E-03 6.074-07 O.OOE+00 4.81E-03 1.41E+02 2.65E+07 2.50E+01 1.005E02 1.27E+02 2.82E-0t 7.05E-03 2.82E-02 Fe-55 8.19E-05 3.14E-07 O.OOE+00 8.22E-05 H-3 2.27Et01 6.40-08 O.OOE+00 2.36E-02 6.88E+02 1.30E+08 0.00E+00 O.OOE500 1.00E+00 1.75E502 O.OOE+00 O.OOE+00 H-3 5.36E-03 1.77E-02 0.OOE+00 2.31E-02 Ni-63 1.19E-02 5.77E-07 O.OOE500 3.55E-01 1.04E+04 1.96E+09 1.28E+02 1.00E+02 6.40E+02 4.13E+00 5.28E501 4.13E-01 NI-63 1.145-03 2.019E-05 0.053+00 1.16E4 SUM 2.70E-01 3.085-02 6.495-05 3.015-01

Attachment IX - (Non-Containment) EC-014-01(MY)

Attachment 2 Rev. 2.o Surface Soil Page 13 of 25 SURFACE SOIL Key Parameters:

Soi Depth 0.15 m Surface Sol (Cs-137) Concentration 2.39 pCvg Surface Soil Total Concentration 2.69 pCi/9 DOSE CALCULATION FACTORS SOURCE TERM SURFACE SOIL ANNUAL DOSE NUREG-1727 Total Nuclide mremly per Nuclide Soil Dose pCig Fraction pCilg mrem/y Cs-137 2.27E+00 8.90E-01 2.39E+00 5.43E+00 Co-60 6.58E+00 9.OOE-03 2.42E-02 1.59E-01 H-3 2.27E-41 5.30E-02 1.43E-01 3.24E-02 Ni-63 1.19E-02 4.80E-02 1.29E-01 1.54E-03 SUM 5.63E+00 8/14/03

Attachment IX. (Non-Contalnment) EC.014.01(MY)

Attachment 3 Rev. 2.0 Activated Concrete Page 14 of 25 ACTIVATED CONCRETE (50 yr Liner Breach and Diffusion)

Key Parameters:

3 Porosity 0.30 Concrete Density 2.20 9wcm Bulk Density 1.50 gcmS Annual Total Wel Water Vol 738.0 Yearly Dr*ning Water 478.0 Llyr 2 Irrigation Rate 0.274 L M

Wal Surface Area 4182.0 Surface Soil Depth 0.15 m 3

Fll Volume 2460.0 m Activated Concrete Total Inventory 0.00E+00 pCI 3

Surface hea/Open Volume 1.70 M'/Mr Concrete Vodume 4.18 Ms DOSE CALCULATION FACTORS SOURCETERM Kd WATER. FiLL. CONCRETE CONCENTRATION ACTIVATED CONCRETE ANNUAL DOSE NUREO.1727 FOR 1t Microshleld Kd Kd Drinking Irrigation Direct Total Nuclilde mrmly per mrernmpCI mremly per Nuclkd. Inventory Fill Concrete Adsorption Water FllN Concrete Nucllde Water Dosa Dose Does Dose pCUV pCUg Fraction pCI cmalgm cmlgm Factor pCIIL pCI/g pC1g mremly mrnmly mrnmly mnmlyr l Cs-134 4.39E+00 7.33E405 6.09E405 5.72E403 0.OOE+00 7.91E201 3.004E00 3.96E+02 0.00E+00 0.00E+00 0.00+E00 Cs-134 0.OOE+00 0.00E+00 0.002E00 0.00E+00 Co-60 6.S8E+00 2.e9E405 6.30E404 2.73E.02 0.00E+00 1.28E202 1.00E+02 6.40E+02 0.OOE+00 0.00E+00 0.00E+00 Co-60 0.00E+00 0.002E00 0.OOE+00 0.00E+00 C-14 2.08E+00 2.09E-06 0.OOE+00 1.48E01 0.00E+00 5.00+E00 1.00E+02 2.72E+01 0.00E+00 0.00E+00 0.00E+00 C-14 0.00E+00 0.00E+00 0.002E00 0.00E+00 Eu-154 3.13E+00 9.55E-06 3.10E-04 6.10E03 o.ooE+00 4.00E+02 5,00E+03 2.06E+03 0.00E+00 0.002E00 0.00E+00 Eu-154 0.00+E00 0.00+E00 0.00E+00 0.00+E00 Fe-55 2.50E403 6.07E07 0.OOE+00 8.44E402 0.OOE+00 2.50E+01 1.OOE+02 1.27E+02 0.00+E00 0,OOE+00 0.00E+00 Fe-55 0.00E+0 0.00E+00 0.00+E00 0.OOE+00 H-3 2.27E201 6.40E-08 0.00E+00 4.41E-01 0.00E+00 0.00E+00 0.00+E00 1.00E+00 0.00E+00 0.00E+00 0.00E+00 H-3 0.00E+00 0.00E+00 0.00N+00 0.00E+00 Eu-152 2.87E+00 6.48E-06 2.09E-04 7.56E-02 0.00E+00 4.00+E02 5.OOE+03 2.06E+03 0.00+E00 0.00E+00 0.00E+00 Eu-152 0.00E+00 0.00E+00 0.002E00 0.00E+00 NW63 1.19E402 5.77E-07 0.002+00 2.11E.01 0.00E+00 1.28E+02 1.00E+02 6.40E+02 0.002E00 0.00E+00 0.001200 Ni-63 0.00+E00 0.00E+00 0.00E200 0.00E00 9.99E-01 0.00E+00 SUM 0.00+E00 0.002+00 0.00E+00 0.00E+00

Attachment IX - (Non-Containment) WC-014-01(MY)

Attachment 4 Rev. 2.0 Activated Rebar Page 15 of 25 Activated Rebar Key Parameters:

3 Porosity 0.30 Concrete Density 2.20 g/cm g/cm3 3 Bulk Density 1.50 Annual Total WeUWater Vol 738.0 m 2

Yearly Drinlkng Water 478.0 L/yr Inigation Rate 0.274 Um -d Wall Surface Are. 4182.0 Surface Soil Depth 0.15 m Fill Volume 2460.0 mMs Activated Concrete Total Inventory O.OOE+00 pCi (1.9 Acltvated Concrete Inventory)

Surface Arealpen Volume 1.70 Concrete Volume 4.18 DOSE CALCULATION FACTORS SOURCE TERM Kd WATER. FiLL, CONCRETE CONCENTRATION ACTIVATED CONCRETE ANNUAL DOSE NUREG-1727 FOR11 Mlcroshield Kd Kd Drinking Irrigation Direct Total Nuclkde mremly per mrnmpCi mrmny per Nuclide Inventory FlI Concrete Adsorptlon Water Fill Concrete Nuclide Waler Dose Dose Dose Dos.

3 pCIg pC~II Fraction PCI cm /gm cm,1gm Factor pCUL pCI/g pCi/g mrnm/y mremny mromly mremly Cs-134 4.39E+00 7.33E405 6.09E-05 O.OE+00 O.OOE00 7.91E+01 3.00E00 3,96E+02 0.00E+00 O.OOE+00O.OOE+00 Cs-134 O.OOE00 O.OOE+00O.OOE+00 0.OOE+00 Co-S0 6.58E+oo 2.69E-05 6.30E.04 3.OOE-02 O.OOE+00 1.28E+02 1.00E+02 6.40E+02 O.OOE+00 O.OOE+00O.OOE+00 Co-60 0.00E+00 o.ooE+00 O.OOE+00 O.OOE+00 C-14 2.08E+00 2.09E-06 o.OOE+00 O.OOE+00 O.OOE+00 5.00E+00 1.00E+02 2.72E+01 O.OOE+00 0.OOE+OO 0O.0E+00 C-14 O.OOE+00O.OOE+000.0012+00 0.00E+00 Eu-154 3.13E+00 9.55E.06 3.10E-04 O.OOE+00 O.OOE+00 4.00E+02 5.OOE+03 2.06E+03 0o0E+00 O.OOE+000.OOE+00 Eu-154 0.00E00 O.O0E+00 .OOE+00 O.OE+00 Fe-55 2.50E43 6.07E07 0.00E+00 182.0E4 O.OOE+00 2.50E+01 1.00E+02 1.27E+02 O.OOE+00 O.OOE+00O.OOE+00 Fe-55 O.OOE+00O.OOE+00O.OOE+00 O.OOE+00 H-3 2.27E-01 6.40E-06 O.OOE+00 O.OOE+00 0.00E+00 O.OOE+00 O.OOE+00 1.00E+20 O.OE200 O.OOE+000.00E+00 H-3 O.OOE+00O.OOE+00O.OOE+00 O.OOE+O0 Eu-152 2.87E+00 6,48-EO6 2.09E-04 O.OOE+00 O.OOE+00 4.OOE+02 5.OOE+03 2.Q6E+03 O.OOE+00 0.00E+00 O.OOE+00 Eu-152 O.OOE+00O.OOE+00O.OOE+00 0.00E+00 Ni-43 1.19E-02 5.77E-07 O.OOE+00 9.69E-01 O.OOE+00 1.28E+02 1.00E+02 6.40E+02 O.OOE+00 O.OOE+00O.OOE+00 Ni-63 O.OOE+000.00E+00 0.00E+00 O.OOE+00 SUM O.OOE+00O.OOE+00O.OOE+00 O.OOE+00 9/5102-2

Attachment IX- (Non-Containment) EC-01 4-01 (MY)

Attachment 5 Rev. 2.0 Deep Soil Page 16 of 25 DEEP SOIL Key Parameters:

Porosity 0.3 Surface Soil Depth 0.15 m Bulk Density 1.6 g/cm 3 Deep Soil (Cs-1 37) Concentration 2.39 pcil/g Yearly Drinking Water 478 L/y Deep Soil Total Concentration 2.69 pci/g Irrigation Rate 0.274 Um2 -d Using ResRad results for pCUiL per pCig conversion Table I of EC-018-01 half sand half gravel(.44) 6/18/02 DOSE CALCULATION FACTORS SOURCE TERM DEEP SOIL ANNUAL DOSE NUREG-1727 FGR 11 Mlcroshleld Deep Soil Derived Water Water Drinking Irrigation Direct Total Nucilde mrem/y per mrem/pCI mrem/y per Nuclide Inventory Conversion Units Inventory Water Dose Dose Dose Dose pCI/g pCI/g Fraction pCI/g pCI/L per pCIlg pCI/L mrem/y mrem/y mremly mremly Cs-137 2.27E+00 5.00E-05 4.OOE-01 8.90E-01 2.39E+00 9.02E-03 2.16E-02 5.16E-04 2.04E-05 9.58E-01 9.58E-01 Co-60 6.58E+00 2.69E-05 2.40E+00 9.O0E-03 2.42E-02 2.24E-02 5.43E-04 6.98E-06 1.49E-06 5.81E-02 5.81E-02 H-3 2.27E-41 6.40E-08 0.OOE+00 5.30E-02 1.43E-01 6.69E+03 9.53E+02 2.92E-02 9.02E-02 0.00E+00 1.19E-01 Ni-63 1.19E-02 5.77E-07 0.OOE+00 4.80E-02 1.29E-01 6.01E-01 7.76E-02 2.14E-05 3.85E-07 0.OOE+00 2.18E-05

. 2.97E-02 9.02E-02 1.02E+00 1.14E+00

Attachment IX - (Non-Containment) EC-014-01 (MY)

Attachment 6 Rev. 2.0 Ground Water Page 17 of 25 GROUND WATER Key Parameters:

Annual Water Intake 478 L/y Dose Calculation Factors Source Term Ground Water Annual Dose FGR 11 Drinking Nuclide mremlpCi Nuclide Inventory Water Dose Fraction pCiL mremly H-3 6.40E-08 1.OOE+00 6,812 2.08E-01 SUM 2.08E-01 8/30/02

Attachment IX - (Non-Containment) EC-014-O1(MY)

Attachment 7 Rev. 2.0 Surface Water Page 18 of 25 SURFACE WATER Key Parameters:

Annual Water Intake 478 L/y Annual Fish Consumption 20.6 Kgfy Dose Calculation factors Source Term Surface Water Annual Dose FGR 11 Bloaccumulation Water Drinking Fish Ingestion Total Nuclide mremlpCi Factor for Fish Nuclide Inventory Water Dose Dose Dose pCI/Kg per pCIIL Fraction pCi/L mremly mremly mremly H-3 6.40E-08 1.OOE+00 1.OOE.00 960 2.94E-02 1 .27E-03 3.06E-02 SUM 2.94E-02 1.27E-03 3.06E-02

Attachment IX - (Non-Containment) EC.014-O1(MY)

Attachment 8 Rev. 2.0 Buried Piping Page 19 of 25 BURIED PIPING Key Parameters:

Porosity 0.3 Buried Pipe Conversion Factor 2.59E-04 pCi/g per dpm/100 cm2 3

Bulk Density 1.6 g/cm Gross Beta DCGL 9.80E+03 dpm/100 cm2 Yearly Drinking Water 478 L/y Gross Beta Nuclide Fraction 0.616 Irrigation Rate 0.274 Urm2-d Total Inventory 1.59E+04 dpmr/100 cm2 Surface Soil Depth 0.15 m Dose Calculation Factors Source Term Buried Piping Annual Dose FGR 11 NUREG-1727 Mlcroshleld Water Pipe Surface Soll Drinking Irrigation Direct Total Nuclide mrem/pCI mremly per mremly per Nuclide Inventory Inventory Inventory Water Dose Dose Dose Dose pCI/g pCI/g Fraction pCI/L per pCi/g dpm/1OOcm 2 pCI/g mremly mremly mremly mremly Sr-90 1.42E-04 1.47E+01 O.OOE+00 2.80E-03 2.15E-02 4.46E+01 1.15E-02 1.68E-05 1.52E-06 O.OOE+00 1.83E-05 Cs-134 7.33E-05 4.39E+00 2.212-05 4.55E-03 2.25E-05 7.23E+01 1.87E-02 1.48E-08 7.71E-10 4.14E-07 4.30E-07 Cs-137 5.0OE-05 2.27E+00 3.97E-06 5.50E-01 3.27E-04 8.75E+03 2.27E+00 1.77E-05 7.01E-07 9.01 E-06 2.74E-05 Co-60 2.69E-05 6.58E+00 2.53E-04 5.84E-02 8.14E-04 9.29E+02 2,41E-01 2.52E-06 5.37E-07 6.09E-05 6.40E-05 Co-57 1.18E-06 1.67E-01 9.44E-09 3.06E-04 1.15E-04 4.88E+00 1.26E-03 8.18E-11 1.012-11 1.19E-11 1.04E-10 Fe-55 6.07E-07 2.50E-03 O.OOE+00 4.81E-03 4.30E-05 7.66E+01 1.98E-02 2.47E-10 8.89E-13 O.OOE+00 2.48E-10 H-3 6.40E-08 2.2TE-01 O.OOE+00 2.36E-02 1.98E+02 3.75E+02 9.70E-02 5.88E-04 1.82E-03 O.OOE+00 2.41E-03 Ni-63 5.77E-07 1.19E-02 O.OOE+00 3.55E-01 2.09E-02 5.65E+03 1.46E+00 8.42E-06 1.51E-07 0.OOE+00 8.57E-06

____________________.______________________ SUM 6.33E-04 1.82E-03 7.03E-05 2.52E-03

Attachment IX - (Non-Containment) EC.014-01(MY)

Attachment 9 Rev. 2.0 BOP Embedded Piping Page 20 of 25 BOP EMBEDDED PIPE Key Prameters:

3 Porosity 0.30 Concrete Density 2.20 g/cm 3

Bulk Density t,50 9/cm Surface Soil Depth 0.15 m Yearly Drinking Water 478.0 ltr Irrigation Rate 0.274 Lm'-d 2 3 Wat Surface Area 4182.0 m Annual Total Wet Water Vol 738 m 3

Fili Volume 2460.0 m Embedded Pipe Conversion Factor 5754.5 pCi per dpmt100 cm' Surfac Art lOpen Volume 1.70 m'tm Gross Beta DCGL 1.00E+05 dpm/100 cm' 3

Concrete Volume 4,18 m Gross Beta Nurnide Fraction 0.616 2

Total Inventory 1.62E+05 dpm/100 cm DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION EMBEDDED PIPE ANNUAL DOSE NUREO-1727 FGR 11 MIcrosheId Kd Kd Drinking Irrigation Direct Total Nuclide mremly per mrwmtpCi mrimny per Inventory Inventory Pi" Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose pCKIg pCIg Fracfton dpmttOO cm' pCI crmlgm cm'fgm Factor pCLI. pCUg pClig mnrmly mrarnly mirmry mrml/y Sr-90 1.47E+01 1.42E-04 0.004E00 2,80E-03 4.55E+02 2.62E408 6.02E+01 1.00E00 3.01E+02 1.18E402 7.07E-04 1.18E405 Sr-90 7.98E-04 7.68E405 0.OOE+00 8.75E-04 Cs-134 4.39E+00 7.33E-5 60.9E205 4.55E-03 7.38E+02 4,25E206 7.91E+01 3.00E00 3.96E+02 1.45E.02 1.15E-03 4.36E-05 Cs-134 5.09E-04 2.83E-05 6.99E208 5.37E-04 Cs-137 Z27E+00 5.00E-05 1.20E-05 5.50E-01 8.93E+04 5.14E408 7.91E+01 3.OOE+00 3.96E202 1.76E200 1.39E-01 5.27E-03 Cs-137 4.20E-02 1.77E-03 1.67E-06 4.38E-02 Co-60 6.58E+00 2.69E-05 6.30E-04 5.84E-02 9.48E+03 5.46E+07 1.28E+02 1.00E+02 6.40E+02 1.15E41 1.47E-02 1.15E202 Co-60 1.48E403 3.37E-04 9.29E-06 1.83E-03 Co-57 1.67E-01 1.18E-06 2.80E-08 3.06E-04 4.97E201 2.56E+05 1.28E402 1.00E+02 6.40E+02 6.05E44 7,73E205 8.05E-05 Co-57 3.41E-07 4.49E408 2.16E-12 3.86E-07 Fe-55 2.50E-03 6.07E-07 0.004E00 4.81E-03 7.82E202 4.50E+06 2.50E+01 1.00E+02 1.27E+02 4.79E.02 1.20E-03 4.79E-03 Fe.55 1.39E-05 5.32E-08 0.002E00 1.39E-05 H-3 2.27E-01 6.40E-08 0.00E+00 2.36E402 3.82E+03 2.20E207 0.002E00 0.00E+00 1.00E200 2.98E201 0.002E00 0.002E00 H-3 9,10E-04 3.00E-03 0.00E+00 3.91E-3 NI-63 1.19E-02 5.77E-07 0.002E00 3.55E-01 5.77E+04 3.32E+08 1.28E+02 1.00+E02 6.40E+02 7.01E-01 8.96E-02 7.01E-02 NI-63 1.93E44 3,71E-06 0.002E00 1.97E-04 SUM 4.59E-02 5.222-03 1.102;05 5. 1E-02

Attachment IX - (Non-Containment) EC-014-01(MY)

Attachment 10 Rev. 2.o Spray Building Embedded Pump Piping Page 21 of 25 EMBEDDED SPRAY PUMP PIPING Key Parameters:

Porosity 0.30 Concrete Density 2.20 9/c3m 3

Bulk Density 1.50 glcm Surface Soil Depth 0.15 m Yearly Drinking WaSr 478.0 Vwr trliaton Rate 0.274 Llm'-d 2

Wag Surface Area 4182.0 m Annual Total Wei Water Vol 738 ms

(

3 FMVokume 2460.0 m Embedded Pipe Conversion Factor 1191.7 pCi per dpm/1 00 cm' Surface Area/Open Volume 1.70 rw/m' Gross Beta DCGL 8.OOE+05 dpm/100 cm' 3

Concrete Volume 4.18 m Gross Beta Nuclide Fraction 0.616 Total Inventory 1.30E+06 dpmN100 cm' DOSE CALCULATION FACTORS SOURCE TERM Kd WATER, FILL, CONCRETE CONCENTRATION EMBEDDED PIPE ANNUAL DOSE NUREO.1727 FOR11 Microshleld Kd Kd Drinking Irrigation DIret Total Nucilde mrmly per mremlpCI mrnm/y per Inventory Inventory Fin Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dose 2

pClIg pCI1g Fraction dpmtOO cm PCI cm'/gm cm'igm Factor pCIlL pCilg pCi/g mromly mremly rnmtly mromly Sr-90 1.47E401 1.42E.04 0.00E+00 2.80E403 3.64E+03 4.34E+06 6.02E+01 1.00E+00 3.016E402 1.95E-02 1.17E-03 1.95E-05 Sr-90 1.32E-03 1.27E-04 0.00+E00 1.45E-03 Cc-134 4.39E400 7.33E405 6.09E-05 4.55E-03 5.91E+03 7.04E+06 7.91E+01 3.00E+00 3.96E.02 2.41E-02 1.90E-03 7.22E-05 Cs-134 8.43E-04 4.69E.05 1.16E-07 8.90E-04 Cs-137 z27E+00 5.OE405 1.20E-05 5.50E-01 7.15E+05 8.52E+08 7.91E+01 3.00E+00 3.96E+02 2.91E+00 2.30E-01 8.73E-03 Cs-137 8.95E-02 2.94E.03 2.76E-06 7.25E-02 CO60 6.58E+00 2.69E-05 8.30E-04 5.84E-02 7.59E+04 9.04E+07 1.28E+02 1.00E+02 6.40E602 1.91E-1 2.44E-02 1.91E-02 Co-60 2.46E403 5,59E404 1.54E-05 3.03E-03 Co-57 1.67E401 1.18E-4 2.80E-08 3.06E-04 3.98E+02 4.74E+05 1.28E+02 1.OOE+02 6.40E+02 1.00E-03 1.28E-04 1.006E04 CO-57 5.65E-07 7.44E-08 3.59E-12 6.40E-07 Fe-55 2.50E-03 6.07E-07 0.00E+00 4.81E-03 6.25E603 7.456E+06 2.50E+01 1.00E+02 1.27E+02 7,93E602 1.98E603 7.93E-03 Fe-55 2.30E4-5 8.82E-08 0.00E+00 2.31E605 H4-3 2.27E-01 6.40E-08 0.00E+00 2.36E-02 3.06E+04 3.64E+07 0.00+E00 o.ooE+00 1.00E+00 4.93E+01 0.00+E00 0.00E+00 H4-3 1.51E-03 4.97E603 0.00E+00 6.48E-03 Ni-63 1.19E402 5.77E-07 0.00E+00 3.55E-01 4.61E+05 5.50E+08 1.28E+02 1.00E+02 6.40E602 1.16E+00 1.48E401 1.16E-01 NP-63 3.21E604 6.15E406 0.00+E00 3.27-4 1.30E+06 1.55E+09

__________________ .__________________________________ _. . SUM 7.60E6022 8.65E-03 t83E405 8.47E-02

Attachment IX. (Non-Containment) EC-014.01 (MY)

Attachment 11 Rev. 2.0 Special Areas Page 22 of 25 CONTAMINATED CONCRETE SPECIAL AREAS Key Parameters:

3 Porosity 0.30 Concrete Density 2.20 p/cm Bulk Density 1.50 g/crm Annual Total Well Water Vol 738.0 m' 2

Yearly Drlnking Water 478.0 L/yr Irrigation Rate 0.274 Lur .d Was Surface Area 4182.0 M2 Surface Soi Depth 0.15 3.01E.01 <on Total Dose Contamlnated Concrete 3

Fill Volume 2460.0 m SpecIal Areas Gross Beta DCOL 9.506E03 dpm/nOO cm2 2

Surface AreatOpen Volume 1,70 m hm' Gross Beta Nuclide Fraction 0.6672 1.08-E01 i- Total Dose SpecIal Areas 3 2 Concrete Volume 4.18 m Total Inventory 1.42E+04 dpm/100 cm DOSE CALCULATION FACTORS SOURCE TERM Kd WATER. FILL, CONCRETE CONCENTRATION CONTAMINATED CONCRETE ANNUAL DOSE NUREGO172 FOR11 Microahleld Kd Kd Drinking Irrigation Direct Total Nuclide mrnm/y per mrsm/pCI mromly per Nucilde Inventory Inventory FIll Concrete Adsorption Water Fill Concrete Nuclide Water Dose Dose Dose Dosa t

pCI/g pCUg Fraction dpm/1QOcm' PCI cm /gm cMl/gm Factor pCU/L pCUg pCI/g mrem/y mrem/y mrem/y mremly Sr-90 1.47E+01 1.42E04 0.00E+00 6.874E-03 9.79E.01 1.84E+07 6.12E+01 1.00E+00 3.06E+02 8.14E-02 4.98E-03 8.14E-05 Sr-90 5.53E-03 5.3E-04 0.006+00 6.06E-03 Sb-125 9.77E-01 2.81E-06 3.83E606 4.523E403 6.44E+01 1.21E+07 4.50E+01 0.00E+00 2.26E+02 7.276-02 3.27E-03 0.00E+00 Sb-125 9.77E-05 3.16E-05 1.25E.08 1.29E-04 Cs-134 4.39E+00 7.33E.05 6.09E.05 - 2.815E403 4.01E+01 7.55E+06 7.91E+01 3.00E+00 3.96E+02 2.58E602 2.04E403 7.74E-05 Cs-134 9.04E-04 5.03E-05 1.24E.07 9.54E-04 Cs-137 2.27E+00 5.00E05 1.20E.05 2.890E601 4.12E+03 7.75E+08 7.91E+01 3.00E+00 3.96E+02 2.65E+00 2.10E601 7.95E603 Cs-137 6.33E602 2.67E-03 2.51E-06 6.60E-02 Pu-238 1.00E+01 3.20E-03 2.45E-25 1.165E.04 1.66E+00 3.13E+05 5.50E+02 5.00E+03 2.81E+03 1.51E-04 8.28E605 7.53E-04 Pu-238 2.30E-04 6.69E-07 2.03E-29 2.31E-04 Pu-239 1.09E+01 3.54E603 6.10E.15 8.752E-05 1.25E+00 2.35E+05 5.50E+02 5.00E+03 2.81E+03 1.13E-04 6.22E-05 5.65E-04 Pu-239 1.91E-04 5.48E407 3.79E-19 1.92E-04 Pu.240 1.09E+01 3.54E603 7.52E-26 8.750E-05 1.25E+00 2.35E+05 5.50E+02 5.00E+03 2.81E+03 1.13E-04 6.22E-05 5.65E-04 Pu-240 1.91E-04 5.48E-07 4.68E-30 1.92E-04 Pu-241 3.47E-1 6.85E-05 0.00E+00 6.705E-03 9.55E+01 1.80E+07 5.50E+02 5.00E+03 2.81E+03 8.66E403 4.76E403 4.33E-02 Pu-241 2.846-04 1.34E-06 0.OOE+00 2.85E-04 Am-241 1.19E+01 3.64E-03 1.65E-19 5.929E604 8.44E+00 1.59E406 1.90E+03 5.00E+03 9.55E+03 2.25E604 4.28E404 1.13E-03 Am-241 3.92E-04 1.19E-06 7.08E-23 3.93E-04 Cm-243 7.81E+00 2.51E-03 1.27E-08 4.649E-05 6.62E-01 1.25E+05 4.00E+03 5.00E+03 2.00E+04 8.42E-06 3.37E405 4.21E-05 Cm-243 1.01E-05 2.92E-08 4.28E-13 1.01E-05 Cm-244 6,00E+00 2.02E-03 9.81E-25 4.454E-05 6.34E-01 1.19E+05 4.00E+03 5.00E+03 2.00E+04 8.07E46 3.23E405 4.03E-05 Cm-244 7.79E-06 2.15E-08 3.17E-29 7.81E-06 Co-60 6.58E+00 2.69E405 6.30E-04 3.639E.01 5.18E+03 9.76E+08 1.28E+02 1.00E+02 6.49E+02 2.06E+00 2.64E-01 2.06E-01 Co-60 2.65E-02 6.04E-03 1.66E-04 3.27E-02 CO-57 1.67E-01 .18E-06 2.80E-08 0,00E+00 0.00E+00 1.28E+02 1.00E+02 6.40E+02 0.00E+00 0.00E+00 0.00E+00 Co-57 0.00E+00 0.00E+0 0.00E+00 0.00E+00 Mn-54 1.676+00 2.77E406 4.40E-05 4.028E-04 5.74E+00 1.08E+06 5.00E+01 0.00E+00 2.51E+02 5.83E-03 2.92E-04 0.00E+00 Mn-54 7.72E-06 4.33E-06 1.28E-08 1.21E-05 Fe-55 2.504-03 6.076-07 0.00+E00 2.235E-02 3.18E+02 6.00E+07 2.50E+01 1.00E+02 1.27E+02 6,38E-01 1.60E-02 6.38E-02 Fe-55 1.85E-04 7.09E-07 0.00E+00 1.86E-04 H-3 2.27601 6.40E408 0.006E00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.00E+00 0.00E+00 0.00E+00 0.00E+00 H-3 0.00E+00 0.00Et00 0.00E+00 0,006E+00 M-63 1.19E-02 5.77E-07 0.00E+00 3.024E601 4.31E+03 8.11E+08 1.28E+02 1.00E+02 6.40E+02 1.71E+00 2.19E-01 1.71E-01 NI-63 4.73E-04 9.07E-06 0.00E+00 4.82E-04

______________________________ ____________________________ __________________ SUM 9.83E-02 9.34E-03 1.69E-04 1.08E-01

RA-03-130, Proposed Change: Revised Activated Concrete Dcgl and More Realistic Activated Concrete Dose Modeling - License Condition 2.B.(10), License Termination

Contents

Text

References:

Subject:

Subject:

1.0 DESCRIPTION

3.0 BACKGROUND

10.0 ENVIRONMENTAL CONSIDERATION

11.0 REFERENCES

1.0 DESCRIPTION

3.0 BACKGROUND

10.0 ENVIRONMENTAL CONSIDERATION

11.0 REFERENCES

Navigation menu

RA-03-130, Proposed Change: Revised Activated Concrete Dcgl and More Realistic Activated Concrete Dose Modeling - License Condition 2.B.(10), License Termination

Text

References:

Subject:

Subject:

1.0 DESCRIPTION

3.0 BACKGROUND

10.0 ENVIRONMENTAL CONSIDERATION

11.0 REFERENCES

1.0 DESCRIPTION

3.0 BACKGROUND

10.0 ENVIRONMENTAL CONSIDERATION

11.0 REFERENCES

Navigation menu

Search