ML20065Q662
| ML20065Q662 | |
| Person / Time | |
|---|---|
| Site: | Duane Arnold  |
| Issue date: | 12/31/1993 |
| From: | Huebner L TELEDYNE ISOTOPES MIDWEST LABORATORY |
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| NUDOCS 9405050315 | |
| Download: ML20065Q662 (66) | |
Text
,
W TELEDYNE ISOTOPES WDWEST LABORATORY 700 LANDWEMR ROAD NORTMBROOK. IttlNOIS 60062 23to 908) W4700
- FAA 908) 544517 REPORT TO IOWA ELECTRIC LIGHT & POWER COMPANY CEDAR RAPIDS, IOWA RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP) l FOR THE DUANE ARNOLD ENERGY CENTER CEDAR RAPIDS, IOWA DOCKET NO. 50-331 i
l ANNUAL REPORT - PART I l
SUMMARY
AND INTERPRETATION j
JANUARY - DECEMBER 1993 FOR SUBMITTAL TO l
THE NUCLEAR REGULATORY COMMISSION PREPARED AND SUBMITTED BY TELEDYNE ISOTOPES MIDWEST LABORATORY PROJECT NO. 8001 O
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Approved by:
A.
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414L "L. GCHuebner GeneralManager 9405050315 940428 PDR ADOCK 05000331 R
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PREFACE The staff members of the Teledyne Isotopes Midwest Laboratory were responsible for the acquisition of data presented in this report with the exception of Appendices D and E which were completed by Iowa Electric personnel. All environmental samples, with the exception of aquatic, were collected by personnel of DAEC. Aquatic samples were collected by University of Iowa Hygenic Laboratory personnel.
The report was prepared by L. G. Huebner, General Manager of the TIML, with the exception of Appendices D and E, which were prepared by Iowa Electric personnel. He was assisted in the i
report preparation by other staff members of the laboratory.
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TABLE OF CONTENTS No.
Pace PREFACE..
..ii List of Tables....................
..v List of Figures..
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1.0 INTRODUCTION
.1 1
2.0
SUMMARY
.2 3.0 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM.
....3 3.1 Program Design and Data Interpretation...............
...3 3.2 Program Description....
.. 4 3.3 Program Execution........
.5 3.4 Laboratory Procedures.........................................
.6 3.5 Program Modifications....
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4.0 RESULTS A ND DISCUSSION.............................
......7 4.1 Atmospheric Nuclear Detonations and Nuclear Accidents............. 7 4.2 Program Findings..
...........7 5.0 TABLES AND FIGURES............................................10
6.0 REFERENCES
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l APPENDICES A
Interlaboratory Comparison Propam Results..........
.............A-1 B
Data Reporting Conventions...
.............................................B-1 C
Maximum Permissible Concentrations of Radioactivity in Air and Water Above Natural Background in Unrestricted Areas...........C-1 D
Summary of the Land Use Census.................................................D-1 l
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Annual Radiation Dose Assessment..............................................E-1 IM l
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TABLE OF CONTENTS (continued)
PART 11 Page Data Tabulations and Analyses......
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. - -. - -, _....._.. _. -.- - -. - -. - _ -, -.. ~,. - -. _ _,. - - -, -.. -
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l LIST OF TABLES Page 5.1 Characteristic Properties of. Isotopes - Quantified in Gamma-spectroscopic Analyses..........
.11 5.2 Sample Collection and Analysis Program,1993....
.12 5.3 Sa mpling Locations, DAEC.................................................
...15 5.4 Type and Frequency of Collections..............................................17 5.5 Sample Codes Used in Table 5.4............................
.............1 8 5.6 Missed Collections and Analyses,1993.................................
.....19 5.7 Radiological Environmental Monitoring Program Summary,1993........... 20 In addition, the following tables'are in the Appendices:
t-Accendix A l
A-1 Interlaboratory Comparison Program Results, 1990-1993.......
.... A1 -1 j
A-2 Interlaboratory Comparison Program Results, Thermoluminescent l
Dosime ters (1 L Ds)..................................................................... A 2 - 1 A-3 In-house Spiked Samples.................................................................... A 3 - 1 A-4 In-house " Blank" Samples....................................................................... A 4 - 1 Attachment A: Acceptance Criteria for Spiked Samples.........................A2 Aopendix C C-1 Maximum Permissible Concentrations of Radioactivity in Air and Water Above Natural Background in Unrestricted Areas...............C-2 V
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LIST OF FIGURES MQ-Pace 5.1 Radiological Environmental Monitoring Program Sampling Stations near the Duane Arnold Energy Center...........
.....26 5.2 Radiological Environmental Monitoring Program Sampling Stations Outside 0.5 Miles.
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1.0 INTRODUCTION
This report summarizes and interprets results of the Environmental Radiological Monitoring Program conducted by Teledyne Isotopes Midwest Laboratory at the Duane Arnold Energy Center, Cedar Rapids, Iowa, during the period January - December 1993. This Program monitors the levels of radioactivity in the air, terrestrial, and aquatic environments in order to assess the impact of the Plant on its surroundings.
Tabulation of the individual analyses made during the year are included in Part 11 of this report.
Duane Arnold Energy Center (DAEC) is located in Linn County on the Cedar River, Iowa, and is operated by Iowa Electric Light and Power Company. The Duane Arnold Energy Center is a 565.7 MW(e) boiling water reactor. Initial criticality was attained on 23 March 1974. The reactor reached 100% power on 12 August 1974. Commercial operation began on 1 February j
1975.
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SUMMARY
The Environmental Radiological Monitoring Program required by the U.S. Nuclear Regulatory Commission (NRC) Technical Specifications for the Duane Arnold Energy Center is described.
Results for 1993 are summarized and discussed.
Program findings show background levels of radioactivity in the environmental samples collected in the vicinity of the Duane Arnold Energy Center. No effect on the environment due to the operation of the Duane Arnold Energy Center is indicated.
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3.0 ENVIRONMENTAL RADIOLOGICAL MONITORING PROGRAM 3.1 Procram Desien and Data Intercretation The purpose of the Environmental Radiological Monitoring Program at the Duane Arnold Energy Center (DAEC) is to assess the impact of the plant on its environment.
For this purpose, samples are collected from the air, terrestrial, and aquatic environments and analyzed for radioactive content. In addition, ambient gamma radiation levels are monitored by thermoluminescent dosimeters (TLDs).
Sources of environmental radiation include the following:
(1)
Natural background radiation arising from cosmic rays and primordial radionuclides; (2)
Fallout from atmospheric nuclear detonations; (3)
Releases from nuclear power plants; and (4)
Industrial and medical radioactive waste.
In interpreting the data, effects due to the DAEC operation must be distinguished from those due to other sources.
A major interpretive aid in assessment of these effects is the design of the monitoring program at the DAEC which is based on the indicator-control concept. Most types of samples are collected both at indicator locations (nearby, downwind, or downstream) and at control locations (distant, upwind, or upstream). A station effect would be indicated if the radiation level at an indicator location was significantly larger than that at the controllocation. The difference would have to be greater than could be accounted for by typical fluctuations in radiation levels arising from other sources.
An additional interpretive technic ue involves analyses for specific radionuclides present in the environmental samples co.lected from the DAEC site. The DAEC's monitoring program includes analyses for strontium-90 and iodine-131, which are fission products, and tritium, which is produced by cosmic rays, atmospheric nuclear detonations, and also by nuclear power plants. Most samples are also analyzed for gamma-emitting isotopes with results for the following groups quantified: zirconium-95, cesium-137, and cerium-144. These three gamma-emitting isotopes were selected as radiological impact indicators because of the different characteristic proportions in which they appear in the fission product mix produced by a' nuclear reactor and that produced by a nuclear i
detonation. Each of the three isotopes is produced in roughly equivalent amounts by a l
reactor: each constitutes about 10% of the total activity of fission products ten (10) days after reactor shutdown. On the other hand, ten (10) days after a nuclear explosion, the contributions of zirconium-95, cerium-144, and cesium-137 to the activity of the resulting debris are in the approximate ratio 4:1:0.03 (Eisenbud,1963). The other group quantified consists of niobium-95, ruthenium-103 and -106, cesium-134, barium-lanthanum-140, and cerium-141. These isotopes are released in small quantities by nuclear power plants, but to date their major source of injection into the general environment has been atmospheric nuclear testing. Nuclides of the next group, manganese-54, cobalt-58 and-60, and zinc-65, are activation products and arise from activation of corrosion products. They are typical components of nuclear power plant effluents, but are not produced in significant quantities by nuclear detonations.
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. 'l 3.1 Procram Desien and Data Interoretation (continued)
Nuclides of the final group, beryllium-7, which is of cosmogenic origin, and potassium-40, a naturally-occurring isotope, were chosen as calibration monitors and should not be considered radiological impact indicators.
Characteristic properties of isotopes quantified in gamma-spectroscopic analysis are presented in Table 5.1.
Other means of distinguishing sources of environmental radiation can be employed in interpreting the data. Current radiation levels can be compared with previous levels, including those measured before the Plant became operational. Results of the DAEC's Monitoring Program can be related to those obtained in other parts of the world. Finally, results can be related to events known to cause elevated levels of radiation in the environment, e.g., atmospheric nuclear detonations.
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3.2 Procram Descriotion The sampling and analysis schedule for the environmental n c'iological monitoring program at the DAEC is summarized in Table 5.2 and is briefly reviewed below. Table 5.3 defines the sampling location codes used in Table 5.2 and specifies for each location its type (indicator or control) and its distance, direction, and sector relative to the i
reactor site. The types of samples collected at each location and the frequency of collections are presented in Table 5.4 using codes defined in Table 5.5.
To monitor the air environment, airborne particulates are collected on membrane filters by continuous pumping at twelve (12) locations. Also, airborne iodine is collected by continuous pumping through charcoal filters at six (6) of these locations. Nine (9) of the twelve (12) locations are indicators and three (3) are controls (D-1, D-2, and D-13).
i Filters are changed and counted weekly. Particulate filters are analyzed for gress beta activity. If gross beta activity exceeds 10 times the yearly mean of the control samples gamma isotopic analysis is performed. Quarterly composites of airborne particulates from each location are gamma scanned on a germanium detector.
Charcoal filters are analyzed weekly for I-131 on all samples.
Ambient gamma radiation is monitored at twelve (12) air sampling locations. In addition, gamma radiation is monitored at thirty-two (32) special locations: seventeen j
(17) in a circle within 0.5 mi. radius of the DAEC stack; six (6) in 22.5' sectors within 1 i
mi. of the DAEC stack; and nine (9) in 22.5' sectors between 1 and 3 miles of the DAEC stack. Two TLDs are placed at each location and are exchanged and analyzed quarterly.
Precipitation samples are collected monthly from one location and analyzed for gamma-emitting isotopes. Quarterly composites are analyzed for tritium.
Milk samples are collected monthly from seven (7) locations during the non-grazing season, October through April, and biweekly during the grazing season, May 1 through September 30. One location is a control (D-105) and the rest are indicators. All samples are analyzed for I-131 and gamma-emitting isotopes.
For additional monitoring of the terrestrial environment, grain, hay, and broad leaf natural vegetation samples are collected annually from nine (9) locations: one control (D-105) and eight (8) indicators (D-57, D-58, D-63, D-72, D-93, D-94, D-106 and 4
3.2 Procram Description (continued)
D-16). Grain, hay, and broad leaf (green leafy) vegetation samples are ~ analyzed for gamma-emitting isotopes and at least one broad leaf vegetation is analyzed for iodine-131. When cattle are slaughtered for home use, it is collected annually, during or immediately following a grazing period from animals grazing on-site. The sample is analyzed for gamma-emitting isotopes. Also, potable ground water is collected quarterly from a treated municipal water system (D-53), the inlet to the municipal water treatment system (D-54), and four (4) additional ground water locations (D-55, D-57, D-58, and D-72). The samples are analyzed for gross beta and tritium. If gross beta activity exceeds 10 times yearly mean of the control samples, gamma isotopic, strontium-89, and strontium-90 analyses are performed.
Soil samples are collected once per year at two indicator locations (D-15 and D-16).
i The samples are analyzed for strontium-90 and gamma-emitting isotopes.
Surface water is collected monthly from five (5) river, pond, and sewage effluent locations, one (1) control (D-49) and four (4) indicator (D-50, D-51, D-99, and D-107).
All monthly samples are analyzed for gamma-emitting isotopes. Tritium analyses are performed on quarterly composites from each location. In addition, all samples from Location D-107 (plant sewage discharge) are analyzed for K-40 by flame photometry.
The aquatic environment is qlso monitored by upstream and downstream (D-49 and D-
- 61) semiannual collections of fish. River bottom sediment is also collected semiannually at the plant's intake and discharge (D-50 and D-51) and downstream of the sewage plant (D-107). The samples are analyzed for gamma-emitting isotopes.
1 3.3 Procram Execution The program was executed as described in the preceding section with the following exceptions:
(1)
Air particulate data was not available for the week of 08-19-93. The samples were lost in shipping. No air particulate / air iodine data was available from location D-5 for the week of 12-09-93. The sample was lost in the field. No air particulate / air iodine data was available from location D-11 on 07-15-93.
Power was out at the substation.
l (2)
Milk was not available from location D-93 for the months of January, February, and December,1993. Goats were dry.
(3)
Milk was no longer available at location D-94 after June 29,1993. The location has been dropped from the milk program.
(4)
Milk was not available from location D-101 for the months of January, February, March, April, and December,1993. Milk was not available for the first collection in May,1993. Goats were dry.
(5)
Milk was no longer available at location D-106 in December,1993. The location has been dropped from the milk program.
(6)
Fish was not collected during the first half of 1993. High water levels prohibited collection.
I (7)
River sediments were not collected during the first half of 1993. High water levels prohibited collection.
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i 3.4 Laboratory Procedures All iodine-131 analyses in milk were made by using a sensitive radio-chemical procedure which involves separation of the element by use of an ion-exchange resin and subsequent beta counting.
All gamma-spectroscopic analyses were performed with high resolution germanium detectors. Levels of iodine-131 in natural vegetation were determined by gamma spectrometry. Levels of airborne iodine-131 in charcoal samples were measured by 4
gamma spectrometry.
j Tritium levels were determined by the liquid scintillation technique.
Analytical Procedures used by TIML are specified in detail elsewhere (Teledyne Isotopes Midwest Laboratory,1993). Procedures are based on those prescribed by the National l
Center for Radiological Health of the U.S. Public Health Service (U.S. Public Health Service,1967) and by the Health and Safety Laboratory of the U.S. Atomic Energy Commission (U.S. Atomic Energy Commission,1972).
Details of TIML's QA program are presented elsewhere (Teledyne Isotopes Midwest Laboratory,1993 ). The TIML QA Program includes participation in the Interlaboratory Comparison (Crosscheck) Program. Results obtained in the crosscheck program are presented in Appendix A.
3.5 Procram Modifications Two locations (D-94 and D-106) were removed from the milk program. Dairy cattle was
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sold at location D-94 as of July,1993. Location D-106 was dropped in December,1993.
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4.0 RESULTS AND DISCUSSION All of the scheduled collections and analyses were made on schedule except those listed in Table 5.6.
All results are summarized in Table 5.7 in a format recommended by the Nuclear Regulatory Commission in Regulatory Guide 4.8. For each type of analysis of each sample medium, this table lists the mean and range of all indicator and control locations. The locations with the highest mean and range are also shown.
The tabulated results of all measurements made in 1993 are not included in this section, although references to these results will be made in the discussion. The complete tabulation of the 1993 results is contained in Part II of the 1993 Annual Report on the Environmental Radiological Monitoring Program for the Duane Arnold Energy Center.
4.1 Atmosoheric Nuclear Detonations and Nuclear Accidents There were no reported atmospheric nuclear tests in 1993. The last reported test was conducted by the People's Republic of China on October 16,1980. The reported yield was in the 200 kiloton to 1 megaton range.
There were no reported accidents at nuclear reactor facilities in 1993.
4.2 Procram Findines Results obtained show background levels of radioactivity in the environmental samples collected in 1993.
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Airborne Particulates The average annual gross beta concentration in airborne particulates was similar at 3
indicator and control locations (0.022 and 0.023 pCi/m, respectively) and was similar 1982 (0.026 pCi/m, at both indicator and control locations), 1983 (0.022 3
to levels in and 0.024 pCi/m, respectively), 1984 (0.025 and 0.026 pCi/m3, respectively),1985 3
(0.024 pCi/m at both locations), in 1986 (0.024 pCi/m3, at both indicator and control 3
locations), in 1987 (0.024 and 0.026 pCi/m, respectively), in 1988 (0.026 and 0.028 3
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pCi/m, respectively), in 1989 (0.026 and 0.029 pCi/m, respectively), in 1990 (0.022 3
3 and 0.024 pCi/m, respectively), in.1991 (0.023 and 0.022 pCi/m, respectively), and 3
in 1992 (0.022 and 0.023 pCi/m3, respectively). The average of 0.024 pCi/m for 1986 does not include the results from May 15 to June 12,1986, which were influenced by the accident at Chernobyl.
A spring peak in beta activity had been observed almost annually for many years (Wilson d d.,1969). It had been attributed to fallout of nuclides from the stratosphere (Gold d M.,1964). It was pronounced in 1981, occurred to a lesser degree in 1982, and did not occur in 1983,1984,1985,1987,1988,1989,1990,1991,1992, or 1993. In 1986, the spring peak could not be identified because it was overshadowed by the releases of radioactivity from Chernobyl. Gamma spectroscopic analysis of c uarterly composites of air paniculate filters yielded similar results for indicator anc control locations. Beryllium-7, which is produced continuously in the upper atmosphere by 7
Airborne Particulates (continued) cosmic radiation (Arnold and Al-Salih,1955), was detected in all samples. All other gamma-emitting isotopes were below their respective LLD limits. No plant effect was indicated.
Airborne k> dine Weekly levels of airborne iodine-131 were below the lower limit of detection (LLD) of 3
0.07 pCi/m in all samples.
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Ambient Radiation (TLDs)
At twelve (12) air sam aling locations, the TLD readings averaged 14.4 mR/ quarter at indicator locations anc 13.8 mR/ quarter at control locations. At locations within 0.5 mile,1.0 mile, and 3.0 mile radius of the stack, the measurements averaged 16.8 i
uarter, and 16.2 mR/ quarter, respectively. The average for all mR/ quarter,17.6 mR/q/ quarter. This is slightly lower than the estimated avera locations was 16.1 mR natural background radiation for Middle America,19.5 mR/ quarter, which is based on data on Pages 71 and 108 of the report, " Natural Background Radiation in the United States" (National Council on Radiation Protection and Measurements,1975). The terrestrial absorbed dose (uncorrected for structural and body shielding) ranges from 8.8 to 18.8 mrad / quarter and averages 11.5 mrad / quarter for Middle America. Cosmic 1
radiation and cosmogenic radionuclides contribute 8.0 mrad / quarter for a total average of 19.5 mrad / quarter. No plant effect was indicated.
Precioitation In precipitation, the tritium concentration was below the LLD of 330 pCi/L in all samples. No gamma-emitting isotopes were detected. No plant effect was indicated.
Milk lodine-131 results were below the detection limit of 1.0 pCi/L in all samples.
No gamma-emitting isotopes, except naturally occurring potassium-40, were detected in any milk samples. This is consistent with the finding of the National Center for Radiological Health that most radiocontaminants in feed do not find their way into milk due to the selective metabolism of the cow. The common exceptions are radioisotopes of potassium, cesium, strontium, barium, and iodine (National Center for Radiological i
Health,1968).
l In summary, the milk data for 1993 show no radiological effects of the plant operation.
Ground Water The annual mean for gross beta activity measured 3.5 pCi/L and was similar to the levels observed in 1980 through 1992. The location with the highest mean (7.0 pCi/L) was D-58, a farm 1.0 mile distant from the plant. Tritium was below the LLD of 330 pCi/L in all samples. No plant effect was indicated.
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Vecetation Iodine-131 results in broad leaf vegetation were below the LLD level of 0.060 pCi/g wet weight in all but one sample. The LLD could not be reached for location D-105, due to the small sample size.
Cs-137 was detected in one vegetable sample at a concentration of 0.036 pCi/g wet.
Except for potassium-40, which was observed in all vegetation samples ( broadleaf, grain, and forage ), all ather gamma-emitting isotopes were below detection limits in all samples. No pla.i offect is indicated.
Soil Strontium-90 was detected in both samples and averaged 0.058 pCi/g dry weight.
Cesium-137 was detected in both samples at a concentration of 0.26 pCi/g dry weight.
Both strontium-90 and cesium-137 concentrations were similar to levels observed in 1987 (0.08 and 0.30 pCi/g dry weight, respectively), in 1988 (0.064 and 0.33 pCi/g dry weight, respectively), in 1989 (0.046 and 0.18 pCi/g dry weight, respectively), in 1990 (0.066 and 0.21 pCi/g dry weight, respectively), in 1991 (0.064 and 0.34 pCi/g dry weight, respectively), and in 1992 (0.040 and 0.26 pCi/g dry weight, respectively).
The only other gamma-emitting isotope detected was potassium-40 and averaged 13.68 pCi/g dry weight. No plant effect on soil was indicated.
Surface Water Tritium was below the LLD level of 330 pCi/L in all samples.
All gamma-emitting isotopes were below their respective LLDs.
K-40 was measured at one location, D-107 (sewage effluent). The concentration ranged from 9.1 to 19.9 pCi/L and averaged 15.4 pCi/L..
No plant effect on the radioactivity of surface water was indicated.
Eish All gamma-emitting isotopes, except naturally-occurring potassium-40, in edible portions were below detection limits. The potassium-40 level was similar at both indicator and control locations (2.80 and 2.68 pCi/g wet weight, respectively). No plant effect on fish was indicated.
River Sediments River sediments were collected in September and October,1993, and analyzed for gamma-emitting isotopes. Cobalt-60 was detected in one sample from location D-107 (sewage effluent) at a concentration of 0.035 pCi/g dry weight. Cesium-137 was detected at both indicator and control locations at an average concentration of 0.027 pCi/g dry weight. Potassium-40 ranged from 7.16 to 9.91 pCi/g dry weight and averaged 8.54 pCi/g dry weight.
All other gamma-emitting isotopes were below detection limits. There was no indication of a plant effect on the environment.
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5.0 TABLES AND FIGURES l
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Table 5.1 Characteristic properties of isotopes quantified in gamma-spectroscopic analyses.
Designation Comment isotope Half-lifea l
I. Naturally Occurring A. Cosmogenic Produced by interaction of Be-7 53.2 d cosmic rays with atmosphere 9
B. Terrestrial Primordial K-40 1.26 x 10 y II. Fission Productsb Nuclear detonations constitute the major erwironmental source A. Short-lived I-131 8.04 d Ba-140 12.8 d B. Other than Short-lived Nb-95 35.15 d Zr-95 65 d Ru-103 39.35 d Ru-106 368.2 d Cs-134 2.061 y Cs-137 30.174 y Ce-141 32.5 d Ce-144 284.31 d III. Activation Products Typically fcund in nuclear Mn-54 312.5 d power plant effluents Fe-59 45.0 d Co-58 70.78 d Co-60 5.26 y Zn-65 245 d a Half-lives are taken from Appendix E of Environmental Quarterly,1 January 1978, EML-334 (U S. Department of Energy,1978).
b Includes fission-product daughters.
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Table 5.2 Sa~mple collection and analysis program,1993.
Exposure Sampling Location Pathway Sample Sampling and and/or Point Description Collection Frequency Type and Frequency Sample Type of Analysis Airbome 1
Cedar Rapids (C) Continuous operation of Analyze for gross beta Particulates 2
Marion (C) sampler with sample activity more than 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 3
Hiawatha collection at least once 5
Palo after filter change. Perform per week or as required by dust loading gamma isotopic analysis on 6
Center Point 7
Shellsburg each sample having gross beta 1
8 Urbana activity greater than ten 10 Atkins times the yearly mean of the 11 Toddsville control samples.
13 Albumett (C) 15 On-site North Composite weekly samples to 16 On-site South form a quarterly composite (by location). Analyze quarterly I
composite for gamma isotopic.
Airbome Iodine 2
Marion (C)
Continuous operation of Analyze each cartridge for 5
Palo sampler with sample iodine-131.
7 Shellsburg collection at least once
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8 Urbana per week.
11 Toddville 15 On-site North Ambient 1-3 Air Particulate Two dosimeters Read gamma radiation dose Radiation 5-8 Locations 10,11 continuously at each quarterly on one dosimeter.
location.
Both 13,15 16 dosimeters are changed 18-23, Within 0.5 mile of at least quarterly.
28-32, Stack 33-41 Within 3.0 miles of Stack 43-48 Within 1.0 mile of 82-86, Stack 91 Surface Water 49 lewis Access (C)
Once per month.
50 Plant Intake (C)
Gamma isotopic analyses of 51 Plant Discharge each sample (by location).
99 Pleasant Creek 107 Plant Sewage Composite monthly samples to Dischange form quarterly composite (by location). Analyze quarterly composite for tritium.
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i Table 5.2 Sample collection and analysis program,1993 (continued).
Exposure Sampling Location Pathway Sample Sampling and Type and Frequency and/or Point Description Collection Frequency of Analysis Sample Type Gmund 53 Treated Grab sample at least Gross beta and tritium Water Municipal Water once per quarter activity analysis on (potable) 54 In1et to quarterly sample. If gross Municipal Water beta is greater than ten Treatment times the yearly mean of System control samples, perform 55 On-site well gamma isotopic and Sr-89 57,58 Wells off-site and Sr-90 analyses.
72 and within 4 km of DAEC River 50 Plant Intake (C)
At least once every Gamma isotopic analysis of Sediment 51 Plant Discharge six months.
each sample.
107 Sewage Effluent Canal Vegetation 16,57, Farms that raise Annually at harvest Gamma isotopic analysis of 58,63, food crops time. One sample of edible portions.
72,93, each: grain, green 94,106, leafy, and forage. At I-131 analysis on broadleaf 105 (C) least one sample vegetation.
should be broadleaf vegetation.
Fish 49 Cedar River One sample per 6 Gamma isotopic analysis on upstream of months (once during edible portions.
DAEC not January through July influenced by and once during effluent (C)
August through 61 Downstream of December).
DAEC in influence of effluent Milkb 105 Control Farm At least once per two During the crazing season:
near
- Amana, weeks duriug the Gamma isotopic and iodine-Iowa grazing season.
131 analyses of each sampla.
63,93 Dairy Farms At least once per Durine the non-cruing season:
94,96, within 10 miles month during the Gamma isotopic and iodine-101,106 of Site non-grazing season.
131 analyses of each sample.
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Table 5.2 Sample collection and analysis program,1993 (continued).
Exposure Sampling Location Pathway Sample Sampling and Type and Frequency j
and/or Point Description Collection Frequency of Analysis Sample Type Precipitation On-site Monthly Gamma isotopic on all samples.
Tritium on quarterly i
composites.
MeatC On-site Annually Gamma Isotopic t
Soil 15,16 On-site Annually Gamma Isotopic and Sr-90.
a Gamma isotopic analysis end analysis for gamma-emitting nuclides refer to high resolution gamma ray spectrum analysis. Any radionuclide detected at a concentration greater than the lower limit of detection (LLD) should be reported quantitatively; conversely, any radionulcide concentration less than the LLD should not be reported.
b Tlw grazing season is considered to be May 1 through September 30.
i c Meat was not collected in 1993; no animals slaughtered for home use.
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O Table 5.3 Sampling locations, Duane Arnold Energy Center.
i Sampling Location r de Type Distance and o
a Sampling Direction from Site Point Location Description Stack l
D-1 C
1 Cedar Rapids 11 mi@ 135 SE D2 C
2 Marion 11 mi @ 125 ESE D-3 3
Hiawatha 7 mi @ 130 SE D-5 5
Palo 3 mi@ 200 SSW D-6 6
Center Point 7 mi @
0N D-7 7
Shellsburg 6 mi @ 255 W D-8 8
Urbana 10 mi@ 345 NW D-10 10 Atkins 9 mi@ 210 SSW D-11 11 Toddville 4 mi @ 90 E D-13 C
13 Alburnett 9 mi @ 70 ENE D-15 15 On-site, Northwest 0.5 mi @ 305'NW D-16 16 On-site, South 0.5 mi @ 190 SSE D-18 18 0.5 mi NNE D-19 19 0.5 mi NE D-20 20 0.5 mi ENE D-21 21 0.5 mi ENE D-22 22 0.5 mi E D-23 23 0.5 mi ESE D-28 28 0.5 mi WSW D-29 29 0.5 mi W D-30 30 0.5 mi WNW D-31 31 0.5 mi NW D-32 32 0.5 mi NNW D-33 33 3.0 mi N D-34 34 3.0 mi NNE D-35 35 3.0 mi NE i
D-36 36 3.0 mi ENE l
D-37 37 3.0 mi E l
D-38 38 3.0 mi ESE l
D-39 39 3.0 mi SE l
D-40 40 3.0 mi SSE D-41 41 3.0 mi S D-43 43 1.0 mi SSW D-44 44 1.0 mi WSW D-45 45 1.0 mi W D-46 46 1.0 mi WNW D-47 47 1.0 mi WNW D-48 48 1.0 mi NW D-49 C
49 Lewis Access, upstream of DAEC 4.0 mi NNW D-50 50 Plant Intake D-51 51 Plant Discharge D-53 53 Treated Municipal Water D-54 54 Inlet to Municipal Water Treatment System l
D-55 55 On-site Well 15
Table 5.3 Sampling locations, Duane Arnold Energy Center (continued).
Sampling Location Code Type Distance and a
Sampling Direction from Site Point Location Description Stack D-57 57 Farm (Off-site Well) 1.0 mi WSW D-58 58 Farm (Off-site Well) 0.5 mi WSW-SW D-61 61 0.5 mi downstream of plant discharge D-63 63 Farm 1.5 mi WNW D-72 72 Farm 2.0 mi SSW D-82 82 0.5 mi SE D-83 83 0.5 mi SSE D-84 84 0.5 mi S D-85 85 0.5 mi SSW D-86 86 0.5 mi SW D-91 91 0.5 mi N 1
D-93 93 Farm 2.8 mi NNE D-94 94 Farm 2.7 mi N D-96 96 Farm 8.0 mi SSW D-99 99 Pleasant Creek Lake 2.5 mi WNW D-101 101 Farm 4.0 mi E D-105 C
105 Farm 21.3 mi SSW D-106 106 Farm 4.5 mi SE D-107 107 Sewage Effluent Canal On-site J
a "C" denotes control location. All other locations are indicators.
16
l Table 5.4 Type and Frequency of collection.
Location
," a Weekly Monthly Quarterly Semiannually Annually D-1 C
AP,Al TLD D-3 AP TLD D-5 AP,Al TLD D-6 AP TLD D-7 AP AI TLD D-8 AP,AI TLD D-10 AP TLD D-11 AP,Al TLD D-13 C
AP TLD D-15 AP,AI TLD SO D-16 AP TLD SO, Gb D-18 through TLD D-23 D-28 through TLD D-41 D-43 through TLD D-48 D-49 C
SW F
D-50 C
SW RS D-51 SW RS D-53 WW D-54 WW D-55 WW 1
D-57 WW Gb I
D-58 WW Gb D-61 F
i D-63 MC Gb D-72 WW Gb l
D-82 through TLD D-86 D-91 TLD D-93 Mc Gb D-94 Mc Gb D-96 MC D-99 SW D-101 MC D-105 C
MC Gb D-106 Mc Gb D-107 SW RS
~ On-site P
ME a Control locations are indicated by a "C" in this column. All other locations are indicators.
b Vegetation (G) includes green leafy (and broad leaf), grain, and forage.
c Monthly from October through April; weekly from May to September.
17
Table 5.5. Sample codes used in 5.4.
Code Description AP Airborne Particulates AI Airborne lodine TLD Thermolununescent Dosimeter P
Precipitation M
Milk WW Well Water G
Vegetation ME Meat SO Soil SW Surface Water F
Fish RS River Sediment 18
b-l Table 5.6. Missed collections and analyses, Duane Arnold Energy Center,1993.
i Collection Date Sample Analysis Location or Period Comments Milk I-131, Gamma D-93 01-05-93 Sample not available.
Milk I-131, Gamma D-101 01-05-93 Sample not available.
Milk I-131, Gamma D-93 02-03-93 Sample not available.
Milk I-131, Gamma D-101 02-06-93 Sample not available.
Milk I-131, Gamma D-101 03-02-93 Sample not available.
Milk I-131, Gamma D-101 04-06-93 Sample not available.
Milk I-131, Gamma D-101 05-04-93 Sample not available.
River Gamma All January - June,1993 Floodmg and high water Sediment Fish Gamma All January -July,1993 Flooding and high water AP/AI Gross Beta /I-131 D-11 07-15-93 No power to sampler.
AP/AI Gross Beta /I-131 All 08-19-93 Samples lost in shipment.
Milk I-131, Gamma D-93 12-07-93 Sample not available.
Milk I-131, Gamma D-101 12-07-93 Sample not available.
19
i Table 5,7 Radiological Envirtwnental Program Summary.
Nameof Facery Duane Arnold Energy Center Docket No.
50-331 Location of Facility Linn, Iowa Reportmg Period January - December 1993 (County, State)
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non.
Type Number of LLob Mean (F)C Mean (F)C Mean (F)c Routine c
Locationd (Uruts)
Analvssa e
Range Results' Range Range I
Airbome GB 610 0.004 0.022 (457/457)
D-I, Cedar Rapids 0.023 (51/51) 0 023 (153/153)
O particulates (0.007-0.054) 11 mi. SE (0.012-0.048)
(0.009-0.048) 3 (pCi/m )
GS 48 Be-7 0.012 0.063 (36/36)
D-1, Cedar Rapids 0.076 (4/4) 0.068 (12/12) 0 (0.041-0.089) li mi. SE (0.068-0.085)
(0.048-0.093)
Nb-95 0.0021
<LLD
<LLD 0
Zr-95 0.0027
<LLD
<LLD C
Ru-103 0.0019
<LLD
<LLD 0
Ru-106 0.011
<LLD
<LLD 0
Cs-134 0.0012
<LLD
<LLD 0
Cs-137 0.0011
<LLD
<LLD 0
Ce-141 0.0033
<LLD
<tLD 0
Ce-144 0.0075
<LLD
<LLD 0
Airborne I 111 304 0.07
<LLD
<LLD 0
14.4 (36/36)
D-15, Onsite 15.2 (4/4) 13.8 (12/12) 0 Locations (11.8-18.4) 0.5 mi. NW (14.2-16.5)
(12.0-15.8)
(mR/ quarter)
TLD, within Gamma 68 1
16.8 (68/68)
D 31, Onsite 21.5 (4/4)
None 0
0.5 mi radius (12.1 23.9) 0.5 mi. NW (19.3-23.9) of Stack (mR/ quarter)
TLD, within Gamma 24 1
17.6 (24/24)
D-44, 19.4 (4/4)
None 0
1.0 mi radius (12.1-21.1) 1.0 mi. WSW (18.9-19.8) of Stack (mR/ quarter)
TLD, within Gamma 36 1
16.2 (36/36)
D-37, 20.4 (4/4)
None 0
3.0 mi radius 3.0 mi. E (19.4-21.6) of Stack (mR/ quarter)
Precipitation H-3 4
330
<LLD None 0
(pci/L)
Fe-59 18
<LLD None O
Co-58 7
<LLD None 0
1 20
Table 5.7 Radiological Environmental Program Summary.
Nameof Facihty Duane Arnold Energy Center Docket No.
50 331 Location of Facility Lmn, Iowa Reportmg Period Januarv - Decemtvr 1993 (County, State)
Indicator Location with Highest Control Numtvr 4
Sample Type and Locations Annual Mean Locations Non-Type Number of LLDb Mean (F)C Mean (F)C Mean (F)c Routine Rangec Locationd (Units)
Analysesa e
Range Results' Range Precipitation CM30 9
<LLD None 0
(pCi/L)
(contmucd)
Zn-65 19
<LLD None 0
Nb-95 9
<LLD None 0
Zr-95 14
<LLD None 0
1-131 19
<LLD None O
C3-134 10
<LLD None O
C9137 11
<LLD None 0
Ba-140 47
<LLD None O
La 140 12
<LLD None O
Mdk (pCi/L) I 131 107 1.0
<LLD
<LLD 0
GS 107 K-40 100 1440 (89/89)
D-101, Farm 1690 (12/12) 1370 (18/18) 0 (820-1920) 4.0 mi. E (1340-1920)
(1220-1590)
Cs-134 15
<LLD (LLD 0
Ce137 18
<LLD
<LLD 0
Ba-140 60
<LLD
<LLD 0
La-140 15
<LLD
<LLD 0
Ground Water GB 24 1.2 3.5 (15/24)
D-58, Farm 7.0 (4/4)
None 0
(pCi/L)
(1.2-8.3) 1.0 mi. WSW-SW (5.9-8.3)
H-3 24 330
<LLD None 0
Broad Leaf I-131 5
0.0608
<tLD
<LLD 0
Vegetation (pCi/g wet)
GS 5
K-40 0.5 2.18 (4/4)
D-105, Farm 4.88 (1/1) 4.88 (1/1) 0 (2.10 2.22) 213 mi. SSW Mn-54 0.059
<LLD
<LLD 0
Co-58 0.056
<LLD
<LLD 0
Co-60 0.073
<LLD
<LLD 0
Nb-95 0.059
<LLD
<LLD 0
Zr-95 0.10
<LLD
<LLD 0
Ru-103 0.067
<LLD
<LLD 0
21
i i
e i
l Table 5.7 Radiological Environmental Program Summary.
Name of Facility Duane Arnold Energy Center Docket No.
50-331 Location of Faclity Iinn, Iowa Reporting Penod January - December 1993 (County, State) j 1
Indicator Location with Highest Lontrol Number
)
Sample Type and Locations Annual Mean Locations Non-b Mean (F)C Mean (F)C Mean (F)c Routine Type Number of LLD a
e Locationd Rangee Range Results' (Units)
Analym Range Broadleaf Ru-106 0.56
<LLD
<LLD 0
i Vegetation i
(pCi/g wet)
Cs 134 0.056
<LLD
<LLD 0
l (contmued)
<LLD 0
Cs-137 0.064
<LLD Ce-141 0.089
<LLD
<LLD 0
<LLD 0
Ce-144 0.37
<LLD Vegetation (Grain)
CS 9
i (pCi/g wet)
K-40 0.5 3.62 (8/8)
D-16, Onsite 11.23 (1/1) 2.86 (1/1) 0 (2.13-11.23) 0.5 mi. SSE Mn-54 0.014
<LLD
<LLD 0
Co-58 0.013
<LLD
<LLD 0
<LLD 0
Co-60 0.015
<LLD
<LLD 0
Nb-95 0.015
<LLD
<LLD 0
Zr-95 0.023
<LLD Ru-103 0.013 (LLD
<LLD 0
Ru-106 0.11
<LLD
<LLD 0
Cs-134 0.011
<tLD
<LLD 0
Cs-137 0.008 (LLD D-16, Onsite 0 0'M (1/1)
<LLD 0
05 mi.SSE
<LLD 0
Ce-141 0.021
<l.LD
<LLD 0
Ce-144 0.079
<LLD Vegetation GS 8
(Forage)
(pCi/g wet)
K-40 0.5 14.29 (7/7)
,D 106, Farm 21.68 (1/1) 16.06 (1/1) 0 (3.35-21.68) 4.5 mi. SE
<LLD 0
Mn-54 0.046
<LLD Co-58 0.072
<LLD
<LLD 0
<tLD 0
Co-60 0.064
<LLD Nb-95 0.070
<LLD
<LLD 0
Zr-95 0.11
<LLD
<LLD 0
Ru-103 0.060
<LLD
<LLD 0
Ru-1%
0.34
<LLD
<LLD 0
Cs-134 0.051
<tLD
<LLD 0
22
Table 5.7 Radiological Environmental Program Summary.
Nameof Facility Duane Arnold Energy Center Docket No.
50-331 Location of Facihty Lmn, Iowa Reportmg Penod January - December tw3 (County, State)
Indicator Location with Highest t ontrol N umtwer Sample Type and Locations Annual Mean Locations Non-Type Nurnber of LLDb Mean (F)C Mean (F)C Mean (F)c Routine c
Locationd (Units)
Analyses ^
Range Rangec Range Resultse Vegetation.
Cs-137 0.N9
<LLD
<LLD 0
Hay (pCi/g wet)
Ce-141 0.060
<LLD
<LLD 0
levntmued)
Ce-144 0.36
<LLD (LLD 0
Soil Sr-90 2
0.01 0.058 (2/2)
D-16, Onsite 0.074 (1/1)
None 0
(pCi/g dry)
(0.043-0.074) 0.5 mi. SSE CS 2
K-40 0.5 13.68 (2/2)
D-15, Onsite 16.33 (1/1)
None 0
(11.04-16.33) 0.5 mi. NW Mn-54 0.021
<LLD None O
Co-58 0.026
<LLD None 0
1 Co-60 0.034
<LLD None 0
Nb-95 0.030
<LLD None 0
Zr-95 0.N2
<LLD None 0
Ru-103 0.020
<LLD None 0
]
Ru 106 0.15
<LLD None O
Cs-134 0.017
<LLD None O
Cs-137 0.060 0.26 (2/2)
D-16, Onsite 0.31 (1/1)
None 0
0.5 mL SSE Ce-141 0.084
<LLD None O
Ce-144 0.12
<LLD None 0
Surface Water H-3 20 330
<LLD
<LLD 0
(PCi/L)
.D-107, Onsite 15.4 (12/12)
None 0
K-40 12 0.5 15.4 (12/12)
(9.1-19.9)
Sewage Effluent (9.1 19.9)
I-131 60 15
<LLD
<tLD 0
<LLD 0
<LLD 0
Fe-59 30
<LLD Co 58 15
<LLD
<LLD 0
Co-60 15
<LLD
<tLD 0
Zn-65 30
<LLD
<LLD 0
23
Table 5.7 Radiological Environmental Program Summary.
Nameof Facihty Duane Arnold Energy Center Docket No.
50-331 location of Facility Linn, Iowa Reporting Period Januarv December 1993 (County, State)
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLDb Mean (F)C Mean (F)C Mean (F)c Routine a
c Locationd (Umts)
Analym Range c
Range Results' Range Surface Water Nb 95 15 (LLD
<LLD 0
(pCi/L)
(wntmued) 2r 95 30
<LLD
<LLD 0
Cellt 15 (LLD
<LLD 0
Ce137 18
<LLD
<LLD 0
<LLD 0
Ba-140 60
<LLD La-140 15
<LLD (LLD 0
River GS 6
Sediments (pCi/g dry)
K-40 1.0 8.42 (4/4)
D-51, Plant 9.65 (2/2) 8.79 (2/2) 0 (7.16-9.91)
Discharge (9.39-9.91)
(8.51 9.07)
I Mn-54 0.019
<LLD
<LLD 0
<LLD 0
Co-58 0.022
<LLD Co-60 0.026 0.035 (1/4)
D-107, Onsite 0.035 (1/4)
<LLD 0
Sewage Effluent Nb-95 0.047
<LLD
<LLD 0
Zr-95 0.043 (LLD
<LLD 0
Ru-103 0.038
<LLD
<LLD 0
<tLD 0
Ru-106 0.14
<LLD
<LLD 0
Crr134 0.016
<LLD Cs-137 0.018 0.026 (3/4)
D49, Lewis Access 0.029 (1/4) 0.029 (1/2) 0 (0.024-0.029) 4 mi. NNW Ce-141 0.064
<LLD (LLD 0
<LLD 0
Ce-144 0.13
<LLD Fish CS 4
(Edible Portiorts)
K-40 0.5 2.8 (2/2)
D-61, Cedar River 2.80 (2/2) 2.68 (2/2) 0 (pCi/g wet)
(2.77-2.83) 0.5 mi. downstream (2.77-2.83)
(2.62 2.74) of discharge Mn 54 0.021
<LLD
<LLD 0
<!.LD 0
Co-58 0.017 (LLD
<tLD 0
Co-60 0.032
<LLD
<LLD 0
Fe-59 0.051
<LLD
<LLD 0
Zn-65 0.033 (LLD l
24
Table 5.7 Radiological Environmental Program Summary.
Nameof Facility Duane Arnold Energy Center Docket No.
_50-331 Location of Facility Linn, Iowa Reportmg Period January - December 1993 (County, State)
Indicator Location with Highest Lontrol Number Sample Type and Locations Annual Mean Locations Non.
Type Number of LLDb Mean (F)C Mean (F)(
Mean (F)c Routme a
c Locahond e
(Units)
Analyses Range c
Range Results Range
<LLD 0
Fish Nb-93 0.027
<LLD (Edible Portions)
Zr-95 0.052
<tLD
<LLD 0
(pCi/g wet)
(contuiurd)
Ru-103 0.026
<LLD
<LLD 0
Ru-1%
0.22 (LLD
<LLD 0
Cs 134 0.021
<LLD
<LLD 0
<tLD 0
Cs-137 0.023
<LLD Ce-141 0.051
<LLD
<LLD 0
Ce-144 0.16
<LLD
<LLD 0
- GB = gross beta; GS = gamma scan.
b LLD = Nominallower lumt of detection based on 4 66 sigma countmg error for the background sample.
Mean and range based upon detectable measurements only. Fraction of detectable measurements at specified locations is C
indicated in parenthews (F).
d Locations are specified by: (1) Name and code (Table 5.3); and (2) distance, direction, and sector relative to reactor site.
8 Non routine results are those which exceed ten times the control station value for the location. If a control station value is not available, the result is considered non-routme if it exceeds ten times the preoperational value for the location.
3 I Three locations (D-1, D-2, D-3) had identical means of 0.023 pCi/m Only D-1 is detailed in this summary table.
8 One sample could not reach the required LLD due to small sample size (40 grams).
25
P Se O
E l
iN iF l
e W
l g
T u
a 3g R l
5 r
b l
7 e
le P
l 5
5 L
l 1
3 A
l AR f
N l
ra o
s 0
T l
nd r
2 S
oi l
W dl o l
l a
0 R
l r
m 0
P o
D Eg pl e
p l
u f
r e
o l
l ni c i
e a n
e G
l 1
r t
l Y
g g
n y
AI 8l yE 2
l I l g ll3 3'Ilj2l7 Cv 3
n 6
o T
l 0'l 9
I Ii c
L E
l nr ei a
i i
n t
o t
o e
ll
. m en n
r s
l e
d l
a l
n n
T l
c<WU MO<C 6g><p2.-
ta B
l j
8 l
A M
a 5
l b
4 R
o l
2 e
R n
1 5
i 6
5 I
t 4
m Dx C
or A
i f
n A
9 D
g o
5 h
5 1
r E
E C
P T
8 r
yp 0
3 1
o g
0 1
e 6
7 r
a a
slll-m 8
n 23 d
S F
6, 95 a
1 r
m 1
e
[' 5 p
qu 0
2 l
I 9
i e
/ 3 n
2 n
/
0
\\(l 8
g 1
c
/
2
\\
/
S y
/
1 lI l l, f
\\
t fI o
y-l 1
J I
a I
f t
c i
c o
o
^E n
u l
s D
le n
c e
t i
a
[
a o
o r
n.
O a
h t
i e
v D
E u
n ane r
ll 1
i j)lI
Figure 5.2 Radiological Environmental Monitoring Program Sampling Stations Outside 0.5 Miles.
10 MILE RADIUS u
URBANA e 08 CENTER POINT CEDAR e 06 RIVER\\
5 MILE RADIUS 49 94 93 33 ALBURNETT 34 13 e 35 36 99 63 47 HEMBMG 37 46 3
45
,,DAEC TODDVIU2 g
SITE 38 g 101 43 f 39 II 72 40 PALOe 05 106 41 I
HIAWATHAl l
03 g
MARION 96 02 P ATKINS 53
- 10 105 CEDAR RAPIDS 01 I
See Table 5.3 for sampling locations and Table 5.4 for Type and Frequency of collection.
27
6.0 REFERENCES
CITED Arnold, J. R. and H. A. Al-Salih.1955. Beryllium-7 Produced by Cosmic Rays. Science 121:
451-453.
Eisenbud, M.1963. Environmental Radioactivity, McGraw-Hill, New York, New York, pp.
213,275 and 276.
Gold, S., H. W. Barkhau, B. Shlein, and B. Kahn,1964. Measurement of Naturally Occurring Radionuclides in Air, in the Natural Environment, University of Chicago Press, Chicago, Illinois, 369-382.
Hazleton Environmental Sciences.1982. Environmental Radiation Monitoring for the Duane Arnold Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1980.
Hazleton Environmental Sciences.1982. Environmental Radiation Monitoring for the Duane Arnold Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1981 Hazleton Environmental Sciences.1982. Environmental Radiation Monitoring for the Duane Arnold Arnold Energy Center, Annual Repor*. - Part II, Data Tabulations and Analyses, January - December 1982.
Hohenemser, C. M. Deicher, A. Ernst, H. Hofsass, G. Lindner, E. Racknaget 1986.
"Chernobyl," Chemtech. October 1986, pp. 596-605.
National Center for Radiological Health,1968. Radiological Health and Data Reports, Vol. 9, Number 12, 730-746.
Teledyne Isotopes Midwest Laboratory.1993. Analytical Procedures, Reviewed 21, August 1992.
Teledyne Isotopes Midwest Laboratory.1993. Quality Control Program, Revision 12.
20, April 1992.
Teledyne Isotopes Midwest Laboratory.1993. Quality Control Procedures Manual, Revision 17,18, May 1993.
Teledyne Isotopes Midwest Laboratory.1993. Quality Assurance Program Manual, Revision 1, 21, September 1992.
Teledyne Isotopes Midwest Laboratory.1984. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1981.
Teledyne Isotopes Midwest Laboratory.1985. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1984.
Teledyne Isotopes Midwest Laboratory.1986. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1985.
28
I 1
[.
6.0 REFERENCES
CITED (continued) k; j
Teledyne Isotopes Midwest Laboratory.1987. Environmental Radiological Monitoring Program i
for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and j
Analyses, January - December 1985.
j Teledyne Isotopes Midwest Laboratory.1988. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and i
i Analyses, January - December 1987.
i Teledyne Isotopes Midwest Laboratory.1989. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1988.
4 Teledyne Isotopes Midwest Laboratory.1990. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and Analyses, January - December 1989.
Teledyne Isotopes Midwest Laboratory.1991. Environmental Radiological Monitoring Program i
for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and j
Analyses, January - December 1990.
Teledyne Isotopes Midwest Laboratory.1992. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and 4
Analyses, January - December 1991.
Teledyne Isotopes Midwest Laboratory.1993. Environmental Radiological Monitoring Program for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and
]
Analyses, January - December 1992.
j Teledyne Isotopes Midwest Laboratory.1994. Environmental Radiological Monitoring Program i
for the Duane Arnold Energy Center, Annual Report - Part II, Data Tabulations and i
Analyses, January - December 1993.
Wilson, D. W., G. M. Ward and J. E. Johnson. 1969. In Environmental Contamination by
]
Radioactive Materials, International Atomic Energy Agency p.125.
1 J
i 29
_. ~ __ _ _ _ _
l I
i APPENDIX A l
INTERLABORATORY COMPARISON PROGRAM RESULTS l
1 l
l I
NOTE: Tehdyne's Midwest Laboratory participates in intercomparison studies administered by U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. The results are reported in Appendix A. Also reported are results of in-house spikes and blanks. Appendix A is updated four times a year, the complete Appendix is included in March, June, September and December monthly progress reports only. Please refer to March, June, September and December progress reports for information.
January,1990 through December,1993 l
-. ~... _.. _......,..
Appendix A Interlaboratorv Comoarison Program Results Teledyne's Midwest Laboratory (formerly Hazleton Environmental Sciences) has participated in interlaboratory comparison (crosscheck) programs since the formulation of its quality control program in December 1971. These programs are operated by agencies which supply environmental type samples (e.g.,
milk or water) containing conctntrations of radionuclides known to the issuing agency but not to participant laboratories. The purpose of such a program is to provide an independent check on the laboratory's analytical procedures and to alert it to any possible problems.
Participant laboratories measure the concentration of specified radionuclides and report them to the issuing agen'cy. Several months later, the agency reports the known values to the participant laboratories and specifies control limits. Results consistently higher or lower than the known values or outside the control limits indicate a need to check the instruments or procedures used.
The results in Table A-1 were obtained through participation in the environmental sample crosscheck program for milk, water and air filters during the period 1990-1993.
This program is conducted by the U.S. Environmental Protection Agency Intercomparison and Calibration Section, Quality Assurance Branch, Environmental Monitoring and Support Laboratory, Las Vegas, Nevada.
The results in Table A-2 were obtained for Thermoluminescent Dosimeters (TLDs), since 1976 via various Intemational Intercomparisons of Environmental Dosimeters under the sponsorships listed in Table A-2. Also, Teledyne testing results are listed.
Table A-3 lists results of the analyses on in-house " spiked" samples for the past twelve months.
Data for previous years are available upon request.
Table A-4 lists results of the analyses on in-house " blank" samples for the past twelve months.
Data for previous years are available upon request.
Attachment A lists acceptance criteria for " spiked *' samples.
Out-of-limit results are explained directly below the result.
1 A1
December,1993 ATTACHMENT A ACCEPTANCE CRITERIA FOR
- SPIKED" SAMPLES LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYS Analysis Level One Standard Deviation _
for single determinations Grunma Emitters 5 to 100 pCi/ liter or kg
>100 pCi/ liter or kg 5.0 pCi/ liter 5% of known value Strontium-896 5 to 50 pCi/ liter or kg
>50 pCi/ liter or kg 5.0 pCi/ liter 10% of known value Strontium-90b 2 to 30 pCi/ liter or kg
>30 pCi/ liter or kg 5.0 pCi/ liter 10% of known value Potassium
>0.1 g/ liter or kg 5% of known value Gross alpha s20 pCi/ liter
>20 pCi/ liter 5.0 pCl/ liter 25% of known value Cross beta
$100 pCi/ liter
>100 pCi/ liter 5.0 pCi/ liter 5% of known value Tritium s4,000 pCi/ liter is = (pCi/ liter) =
>4,000 pCi/ liter 169.85 x (known)*"
10% of known value Radium-226, 228
<0.1 pCi/ liter 15% of known value Plutonium 0.1 pCl/ liter, gram, or sample 10% of known value Iodine-131, s55 pCl/ liter
>55 pCi/ liter 6.0 pCi/ liter Iodine-1296 10% of known value Uranium-238, s35 pCi/ liter Nickel-64s
>35 pCi/ liter 6.0 pCi/ Liter Technetium-996 15% of known value Iron-55, 50 to 100 pCi/mer
>100 pCi/ liter 10 pCi/ liter 10% of known value Others" 20% of known value
- Prom EPA publication, " Environmental Radioactivity Laboratory Intercomparison Studie Program, Fiscal Year, 1981-1982, EPA-600/4-81-004.
s Teledyne limit.
A2
4 Table A 1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA Midwest Laboratory results for various sample media'.
Concentration in pCi/L' Lab Sample Date Teledyne Results EPA Resultd Code Type Collected Analyses 12 Sigma' 1s, N=1 Limits Control STW-589 WATER Jan,1990 Sr-89 22.7 i 5.0 25.0 i 5.0 16.3 - 33.7 St-90 17.3 i 1.2 20.0 i 1.5 17.4 - 22.6 The sample was reanalyzed in triplicate for St-90; results of reanalyses were 18.811.5 pCi/L. No further action is planned.
'STW-591 WATER Jan,1990 Gr. Alpha 10.313.0 12.0 i 5.0 3.3 - 20.7 Gr. Beta 12.3 i 1.2 12.0 i 5.0 3.3 - 20.7 STW-592 WATER Jan,1990 Ba 133 78.0 i 0.0 74.0 i 7.0 61.9 - 86.1 Co-60 14.7 i 2.3 15.015.0 6.3 - 23.7 Cs-134 17.3 i 1.2 18.0 i 5.0 9.3 - 26.7 Cs-137 19.3 i 1.2 18.0 i 5.0 9.3 - 26.7 Ru-106 133.3 i 13.4 139.0 i 14.0 114.8 - 163.2 Zn-65 135.0 i 6.9 139.0 i 14.0 114.8 - 163.2 STW-593 WATER Feb,1990 H-3 4827.0 i 83.0 4976.0 1 498.0 4113.0 - 5839.0 STW 594 WATER Mar,1990 Ra-226 5.010.2 4.910.7 4.1 - 5.7 Ra-228 13.510.7 12.7 i 1.9 9.4 - 16.0 STW-595 WATER Mar,1990 Uranium 4.0i 0.0 4.0 i 6.0 0.0 - 14.4 STAF-596 AIR FILTER Mar,1990 Cs-137 9.311.2 10.0 i 5.0 1.3 - 18.7 Gr. Alpha 7.3 i 1.2 5.0i 5.0 0.0 - 13.7 Gr. Beta 34.0 i 0.0 31.015.0 22.3 - 39.7 Sr-90 10.0 i 0.0 10.0 i 1.5 7.4 - 12.6 STW-597 WATER Apr,1990 Gr. Alpha 81.013.5 90.0 i 23.0 50.1 - 129.9 Ra 226 4.9 i 0.4 5.010.8 3.6 - 6.4 Ra-228 10.610.3 10.2 i 1.5 7.6 - 12.8 U
18.7 i 3.0 20.0 i 6.0 9.6 - 30.4 STW-598 WATER Apr,1990 Cs-134 16.0 i 0.0 13.015.0 6.3 - 23.7 Cs-137 19.0 i 2.0 15.0 i 5.0 6.3 - 23.7 Gross Beta 51.0110.1 52.015.0 43.3 - 60.7 St-89 9.311.2 10.0 i 5.0 1.3 - 18.7 i
1 A11 I
l
\\
l t
4 i
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA ani Midwest Laboratory results for various sample media'.
i, Concentration in pCi/L" j
Lab Sample Date Teledyne Results EPA Result '
Control d
i Code Type Collected Analyses i2 Sigma
- 1s, N=1 Limits l
Sr-90 10.3 i 3.1 10.0 i 1.5 8.3 - 11.7 I
STM-599 MILK Apr,1990 Cs-137 26.0 i 6.0 24.0 i 5.0 15.3 - 32.7
(
I-131 98.7 i 1.2 99.0110.0 81.7 - 116.3 l
K 1300.0 t 69.2 1550.0 i 78.0 1414.7-1685.3
}
"Ihe K analysis was repeated in triplicate; result of reanalysis i
was 1421.7195.3 mg/L No further action is planned.
St-89 21.7 i 3.1 23.0 5.0 14.3 - 31.7
(
Sr-90 21.0 i 7.0 23.0 i 5.0 14.3 - 31.7 STW-600 WATER May,1990 Sr-89 6.0 i 2.0 7.0
- 5.0 0.0 - 15.7 i
1 Sr-90 6.7i 1.2 7.015.0 0.0 - 15.7 STW-601 WATER May,1990 Gr. Alpha 11.0 i 2.0 22.0
- 6.0 11.6 - 32.4 j
l, Gross Alpha analysis was repeated in triplicate; results of reanalyses were 13.411.0 pCi/L No further action is planned.
Gr. Beta 12.3 i 1.2 15.0 i 5.0 6.3 - 23.7 STW-602 WATER Jun,1990 Ba-133 100.7 i 8.1 99.0 i 10.0 81.7 - 116.3 l
Co-60 25.3 i 2.3 24.0 i 5.0 15.3 - 32.7 l
Cs-134 23.7 i 1.2 24.0 i 5.0 18.2 - 29.8
{
Cs-137 27.7i 3.1 25.0 i 5.0 16.3 - 33.7
{
Ru-1%
202.7i l7.2 210.0 1 21.0 173.6-246.4 i
Zn-65 155.0 i 10.6 148.0 i 15.0 130.6 - 165.4 l
STW-603 WATER Jun,1990
.i H-3 2927.0 1 306.0 2933.0 i 358.0 2312.0 - 3554.0 STW-604 WATER Jul,1990 Ra 226 11.8 i 0.9 12.1 i 1.8 9.0 - 15.2 Ra-228 4.1 i 1.4 5.1i 1.3 2.8 - 7.4 STW-605 WATER Jul,1990 U
20.3 i 1.7 20.813.0 15.6 - 26.0 STW-606 WATER Aug,1990 1-131 43,011.2 39.0 i 6.0 28.6 - 49.4 STW-607 WATER Aug,1990 Pu-239 10.0 i 1.7 9.1 i 0.9 7.5 - 10.7 STAF-608 AIR FILTER Aug,1990 Cs-137 19.0 i 2.0 20.015.0 11.3 - 28.7 Al-2
i l
Table A 1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Teledyne's Midwest Laboratory results for various sample media *.
6 Concentration in pCi/L Lab Sample Date Teledyne Results EPA Result Control d
Code Type Collected Analyses 12 Sigma
- 1s, N=1 Limits Gr. Alpha 14.010.0 10.015.0 1.3 - 18.7 Gr. Beta 65.3 t l.2 62.015.0 53.3 - 70.7 Sr-90 19.016.9 20.0 i 5.0 11.3 - 28.7 SIW 609 WATER Sep,1990 Sr-89 9.0 2.0 10.0 5.0 1.3 - 18.7 Sr-90 9.0 i 2.0 9.0 i 5.0 0.3 - 17.7 STW 610 WATER Sep,1990 Gr. Alpha 8.3 i 1.2 10.0 i 5.0 1.3 - 18.7 Gr. Beta 10.3 i 1.2 10.0 i 5.0 1.3 - 18.7 STM-611 MILK Sep,1990 Cs-137 20.0 i 2.0 20.0 i 5.0 11.3 - 28.7 l
I-131 63.016.0 58.0 i 6.0 47.6 68.4 K-40 1673.3 i 70.2 1700.0 i 85.0 1552.5 - 1847.5 Sr-89 11.713.1 16.015.0 7.3 - 24.7 St-90 15.0 i 0.0 20.0 i 5.0 11.3 - 28.7 I
STW-612 WATER Oct,1990 Ba 133 116.7 i 9.9 110.0 i 11.0 90.9 - 129.0 Co-60 20.3 i 3.1 20.015.0' 11.3 - 28.7 Cs-134 11.0 i 0.0 12.015.0 3.3 - 20.7 Cs-137 14.0 i 2.0 12.0 i 5.0 3.3 - 20.7 Ru-106 152.0 i 8.0 151.0 i 15.0 125.0 - 177.0 Zn-65 115.3 i 12.2 115.0 i 12.0 94.2 - 135.8 STW-613 WATER Oct,1990 H-3 7167.0 i 330.0 7203.0 1 720.0 5954.0 - 8452.0 STW-614 WATER Oct,1990 Gr. Alpha 68.7 i 7.2 62.0 i 16.0 34.2 - 89.8 Ra-226 12.9 i 0.3 13.6 i 2.0 10.1 - 17.1 Ra-228 4.2 i 0.6 5.0il.3 2.7 - 7.3 l
U 10.4 i 0.6 10.2 i 3.0 5.0 - 15.4 STW-615 WATER Oct,1990 Cs-134 9.0il.7 7.0 1 5.0 0.0 - 15.7 Cs-137 7.7i 1.2 5.015.0 0.0 - 13.7 j
Gross Beta 55.018.7 53.0 i 5.0 44.3 - 61.7 Sr-89 15.7 i 2.9 20.0 i 5.0 11.3 - 28.7 St-90 12.0 i 2.0 15.0 i 5.0 6.0 - 23.7 l
Al-3
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Teledy Midwest Laboratory results for various sample media'.
Concentration in pCi/L6 Lab Sample Date Teledyne Results EPA Result' Control Code Type Collected Analyses 12 Sigma' 1s, N=1 Limits STW-616 WATER Nov,1990 Ra-226 6.811.0 7.4i1.1 5.5 - 9.3 Ra-228 5.3 t l.7 7.711.9 4,4 - 11.0 STW-617 WATER Nov,1990 U
35.0 i 0.4 35.513.6 29.3 - 41.7 Sample was analyzed but the results were not submitted to the EPA because the deadline was missed (all data on file).
STW-618 WATER Jan,1991 Sr-89 4.311.2 5.015.0 0.0 - 13.7 Sr-90 4.7i 1.2 5.015.0 0.0 - 13.7 STW-619 WATER Jan,1991 Pu-239 3.6i0.2 3.310.3 2.8 - 3.8 STW-620 WATER Jan,1991 Gr. Alpha 6.7i 3.0 5.0i 5.0 0.0 - 13.7 i
Gr. Beta 6.311.2 5.0i 5.0 0.0 - 13.7 STW-621 WATER Feb,1991 Ba-133 85.7 i 9.2 75.018.0 61.1 - 88.9 Co-60 41.318.4 40.015.0 31.3 - 48.7 Cs-134 9.012.0 8.0 i 5.0 0.0 - 16.7 Cs-137 9.7i 1.2 8.0 1 5.0 0.0 - 16.7 Ru-106 209.7 i 18.6 186.0 i 19.0 153.0 - 219.0 Zn-65 166.7 i 19.7 149.0 1 15.0 123.0 175.0 STW-622 WATER Feb,1991 J
[
1131 81.3 i 6.1 75.0 i 8.0 61.1 - 88.9 t
STW-623 WATER Feb,1991 H-3 4310.0 i 144.2 4418.0 1 442.0 3651.2 - 5184.8 STW-624 WATER Mar,1991 Ra 226 31.4 i 3.2 31.8 i 4.8 23.5 - 40.1 Ra 228 21.1 i 5.3 11.9 - 30.3 No data for Ra 228 was reported; sample was lost during analysis.
STW-625 WATER Mar,1991 U
6.710.4 7.6 i 3.0 2.4 - 12.8 STAF-626 AIR FILTER Mar,1991 Cs-137 33.7 i 4.2 40.0 i 5.0 31.3 - 48.7 Al-4
- ~
-~~"
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Midwest Laboratory results for various sample media',
Concentration in pCi/L' Lab Sample Date Teledyne Results EPA Resultd Control Code Type Collected Analyses 12 Sigma' is,N=1 Limits Gr. Alpha 38.7
- 1.2 25.016.0 14.6 - 35.4 The cause of the high Gross Alpha result is the difference in geometry between the standard used in the TIML lab and the EPA filter.
Gr. Beta 130.0 i 4.0 124.0 i 6.0 113.6 - 134.4 Sr 90 35.7 i 1.2 40.015.0 31.3 - 48.7 STW-627 WATER Apt,1991 j
Gr. Alpha 51.016.0 54.0 i 14.0 29.7 - 78.3 Ra-226 7.0 i 0.8 8.011.2 5.9 - 10.1 Ra 228 9.711.9 15.2 i 3.8 8.6 - 21.8 U
27.7 i 2.4 29.8 i 3.0 24.6 - 35.0 STW-628 WATER Apr,1991 Cs-134 27.3 t 1.2 24.015.0 15.3 - 32.7 Cs-137 29.012.0 25.0 i 5.0 16.3 - 33.7 Gross Beta 93.3 i 6.4 115.0i l7.0 85.5 - 144.5 Sr-89 21.0 i 3.5 28.0 i 5.0 19.3 - 36.7 St-90 23.010.0 26.0 i 5.0 17.3 34.7 STM-629 MILK Apr,1991 Cs-137 54.7 i 11.0 49.015.0 40.3 - 57.7 I-131 65.3 i 14.7 60.0 i 6.0 49.6 - 70.4 K 40 1591.7 i 180.1 1650.0 i 83.0 1506.0 1794.0 Sr-89 24.0 i 8.7 32.015.0 23.3 - 40.7 Sr-90 28.0 i 2.0 32.015.0 23.3 - 40.7 STW-630 WATER May,1991 Sr-89 40.7i 2.3 39.015.0 30.3 - 47.7 Sr 90 23.7 i 1.2 24.015.0 15.3 - 32.7 STW 631 WATER May,1991 Gr. Alpha 27.7i 5.8 24.016.0 13.6 - 34.4 Gr. Beta 46.0 i 0.0 46.0 i 5.0 37.3 - 54.7 STW-632 WATER Jun,1991 Ba 133 74.016.9 62.0 i 6.0 51.6 - 72.4 Sample was reanalyzed for Ba-133. Result of the reanalysis was 63.816.9 pCi/L; within the EPA control limits.
Co-60 11.311.2 10.0 i 5.0 1.3 18.7 Cs-134 15.3 i 1.2 15.015.0 6.3 23.7 Cs-137 16.3 i 1.2 14.015.0 5.3 - 22.7 Ru-1%
162.3 i 19.0 149.0 1 15.0 123.0 - 175.0 Al-5
O Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Teledyne's Midwest Laboratory results for various sample media'.
Concentrationin pCi/L5 Lab Sample Date Teledyne Results EPA Result' Control Code Type Collected Analyses i2 Sigma' 1s, N=1 Limits Zn-65 119.3 i 16.3 108.0 1 11.0 88.9 - 127.1 STW-633 WATER Jun,1991 H-3 13470.0 i 385.8 12480.0 i 1248.0 10314.8 - 14645.2 STW 634 WATER Jul,1991 Ra-226 14.9 i 0.4 15.912.4 11.7 - 20.1 Ra-228 17.611.8 16.714.2 9.4 - 24.0 STW-635 WATER Jul,1991 U
12.8 i 0.1 14.2 i 3.0 9.0 - 19.4 STW-636 WATER Aug,1991 I.131 19.3 i 1.2 20.016.0 9.6 - 30.4 STW-637 WATER Aug,1991 Pu-239 21.4 i 0.5 19.4 i 1.9 16.1 - 22.7 STAF-638 AIR FILTER Aug,1991 Cs-137 26.3 i 1.2 30.015.0 21.3 - 38.7 Gr. Alpha 33.0 i 2.0 25.016.0 14.6 - 35.4 Gr. Beta 88.7 i 1.2 92.0 i 10.0 80.4 - 103.6 Sr-90 27.0 i 4.0 30.015.0 21.3 - 38.7 i
STW-639 WATER Sep,1991 Sr-89 47.0 i 10.4 49.0 i 5.0 40.3.- 57.7 Sr-90 24.012.0 25.015.0 16.3 - 33.7 STW-640 WATER Sep,1991 Gr. Alpha 12.0 i 4.0 10.015.0 1.3 - 18.7 Gr. Beta 20.3 i 1.2 20.0 i 5.0 11.3 - 28.7 STM-641 MILK Sep,1991 Cs-137 33.7 i 3.2 30.015.0 21.3 - 38.7 I-131 130.7 i 16.8 106.0 1 11.0 88.9 - 127.1
'The cause of the high result for the 1131 analysis is unknown.
An in-house spike sample was prepared with activity for I-131 of 68.3i6.8 pCi/L. Result of TIML's analysis of the in house spike was 69.119.7 pCi/L.
K 1743 3 i 340.8 1740.01 87.0 1589.1 - 1890.9 Sr-89 20.3 i 5.0 25.0 i 5.0 5.6.3 - 33.7 Sr-90 19.7 i 3.1 25.0 i 5.0 16.3 - 33.7 STW-642 WATER Oct,1991 Ba-133 94.7 i 3.1 98.0 i 10.0 80.7 - 115.3 Co-60 29.7 i 1.2 29.0 i 5.0 20.3 - 37.7 Cs-134 9.7i 1.2 10.015.0 1.3 - 18.7 Al-6
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Tcledyne's Midwest Laboratory results for various sample media'.
Concentration in pCi/LS Lab Sample Date Teledyne Results EPA Result Control d
Code Type Collected Analyses 12 Sigma' 1s, N=1 Limits Cs-137 11.0 i 2.0 10.015.0 1.3 - 18.7 Ru-106 196.3 i 15.1 199.0 1 20.0 164.3 - 233.7 Zn-65 75.7 i 8.3 73.0 i 7.0 60.9 - 85.1 l
STW-643 WATER Oct,1991 H-3 2640.0 i 156.2 2454.0 i 352.0 1843.3 - 3064.7 l
STW-644 WATER Oct,1991 Gr. Alpha 73.0113.1 82.0 i 21.0 45.6 - 118.4 1
Ra-226 20.9 i 2.0 22.0 t 3.3 16.3 - 27.7 l
Ra-228 19.6 i 2.3 22.2 i 5.6 12.5 31.9 U
13.5 i 0.6 13.513.0 8.3 - 18.7 STW-645 WATER Oct,1991 Co-60 20.311.2 20.0 i 5.0 11.3 - 28.7 Cs-134 9.015.3 10.015.0 1.3 - 18.7 Cs-137 14.7 i 5.0 11.0 t 5.0 2.3 - 19.7 Gross Beta 55.313.1 65.0110.0 47.7-82.3 Sr-89 9.713.1 10.0 i 5.0 1.3 - 18.7 Sr-90 8.7 i 1.2 10.015.0 1.3 - 18.7 STW-646 WATER Nov,1991 Ra-226 5.6i 1.2 6.5 i 1.0 4.8 - 8.2 Ra 228 9.6 i 0.5 8.112.0 4.6 - 11.6 STW-647 WATER Nov,1991 U
24.7 i 2.3 24.9 i 3.0 19.7 - 30.1 STW-648 WATER Jan,1992 Sr-89 42.7 i 6.4 51.0 i 5.0 42.3 - 59.7 Sr-90 18.3 i 3.1 20.015.0 11.3 - 28.7 STW-649 WATER Jan,1992 Pu-239 16.1 i 0.8 16.8 i 1.7 13.9 - 19.7 STW-650 WATER Jan,1992 Gr. Alpha 23.7 i 9.2 30.018.0 16.1 - 43.9 Gr. Beta 27.7 i 4.2 30.0 i 5.0 21.3 - 38.7 STW-651 WATER Feb,1992 1-131 60.314.2 59.0 i 6.0 48.6 - 69.4 STW-652 WATER Feb,1992 Ba-133 79.0 i 3.4 76.018.0 62.1 - 89.9 Co-60 40.3 i 5.0 40.0 i 5.0 31.3 - 48.7 Cs-134 31.7 i 4.2 31.015.0 22.3 - 39.7 Al 7
.m
l Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EP Midwest Laboratory results for various sample media'.
. Concentration in pCi/L' Lab Sample Date Teledyne Results EPA Resultd Code Type Collected Analyses 12 Sigma' 1s, N=1 Limits Control Cs-137 51.013.4 49.0 t 5.0 40.3-57.7 Ru-106 188.7 i 28.8 203.0 1 20.0 168.3 - 237.7 Zn-65 148.0 1 15.0 150.7 i 6.1 122.0 - 174.0 STW-653 WATER Feb,1992 H-3 7714.0 t 119.6 7904.0 1 790.0 6533.4 - 9274.6 STW-654 WATER Mar,1992 Ra-226 9.010.4 10.111.5 7.5 - 12.7 Ra-228 18.8 i 0.6 15.5 t 3.9 8.7 - 22.3 STW-655 WATER Mar,1992 Rn-222 0.0 No Data; Special EPA testing.
STW-656 WATER Mar,1992 U
25.1 i 1.9 25.3 i 3.0 20.1 - 30.5 STW-657 WATER Mar,1992 Rn-222 No Data is available; Special EPA testing.
STAF-658 AIR FILTER Mar,1992 Cs-137 10.0 i 0.0 10.015.0 1.3-18.7 Gr. Alpha 7.010.0 7.015.0 0.0 - 15.7 Gr. Beta 39.3 i 1.6 41.015.0 32.3 - 49.7 Sr-90 13.7 i 1.6 15.0 i 5.0 6.3 - 23.7 STW-659 WATER Apr,1992 Gr. Alpha 35.716.1 40.0110.0 22.7 - 57.3 Ra-226 12.7 i 1.2 14.9 i 2.2 11.1 - 18.7 Ra 228 14.512.1 14.0 i 3.5 7.9 - 20.1 U
3.9i 0.2 4.0i3.0 0.0 - 9.2 STW-660 WATER Apr,1992 Co-60 61.0 i 4.0 56.015.0 47.3 - 64.7 Cs-134 24.3 i 1.2 24.015.0 15.3 - 32.7 Cs-137 24.012.0 22.0 i 5.0 13.3 - 30.7 Gross Beta 113.0 i 7.2 140.0 1 21.0 103.6 - 176.4 Sr-89 12.314.2 15.015.0 6.3 - 23.7 Sr-90 15.0 i 1.2 17.015.0 8.3 - 25.7 STM-661 MILK Apr,1992 Cs-137 39.3 i 2.3 39.015.0 30.3 - 47.7 1-131 78.7 i 9.5 78.018.0 64.1 - 91.9 Al-8
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Teledyne's Midwest Laboratory results for various sample media *.
Concentration in pCi/L6 Lab Sample Date Teledyne Results EPA Resultd Control Code Type Collected Analyses i2 Sigma' 1s, N=1 Limits K-40 1610.0 t 72.1 1710.0 1 86.0 1560.8 1859.2 Sr 89 25.317.6 38.015.0 29.3 - 46.7 The cause of the low Sr-89 results is unknown. Data were checked for errors. An in-house spike sample was prepared with activity for St-89 of 41.0110.0 pCi/L. Result of the analysis of the in-house spike sample for Sr-89 was 37.213.6 pCi/L Sr-90 24.3 i 3.1 29.0 i 5.0 20.3 - 37.7 STW-662 WATER May,1992 Sr-89 24.014.0 29.015.0 20.3 - 37.7 Sr-90 6.7 i 1.2 8.015.0 0.0 - 16.7 STW-663 WATER May,1992 Gr. Alpha 12.312.1 15.015.0 6.3 - 23.7 Gr. Beta 46.015.0 44.0 i 5.0 35.3 - 52.7 STW-664 WATER Jun,1992 Ba 133 92.7 i 11.0 98.0110.0 80.7 - 115.3 Co-60 20.3 i 1.2 20.015.0 11.3 - 28.7 Cs-134 14.3 i 2.3 15.015.0 6.3 23.7 Cs-137 15.0 i 2.0 15.015.0 6.3 - 23.7 Ru-106 142.7 i 23.7 141.0 i 14.0 116.7 - 165.3 Zn-65 103.3 i 10.6 99.0 i 10.0 81.7 - 116.3 STW-665 WATER Jun,1992 H3 2153.3 i 144.6 2125.0 1 347.0 1523.0 - 2727.0 STW-666 WATER Jul,1992 Ra-226 22.312.2 24.913.7 18.5 - 31.3 Ra 223 16.713.1 16.7i 4.2 9.4 24.0 STW-667 WATER Jul,1992 Uranium 3.610.3 4.0 i 3.0 0.0 - 9.2 STW-668 WATER Aug,1992 1-131 47.013.5 45.016.0 34.6 - 55.4 STW-669 WATER Aug,1992 Pu-239 8.510.9 9.0 1 0.9 7.4 - 10.6 STAF-670 AIR FILTER Aug,1992 A1pha 25.7 i 1.2 30.0 i 8.0 16.1-43.9 Beta 69.0 i 2.0 69.0 i 10.0 51.7 - 86.3 Cs-137 16.010.0 18.0 i 5.0 9.3 - 26.7 Sr 90 26.014.0 25.0 i 5.0 16.3 - 33.7 Al-9 m
~
i j
i 1
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Toledyne's l
Midwest Laboratory results for various sample media'.
i Concentration in pCi/L l
b Lab Sample Date Teledyne Results EPA Resultd Control Code Type Collected Analyses f2 Sigma' 1s, N=1 Limits STW-671 WATER Sep,1992 Sr-89 16.0 i 4.0 20.015.0 11.3 - 28.7 Sr-90 14.3 i 3.1 15.0 i 5.0 6.3 - 23.7 STW-672 WATER Sep,1992 AIpha 43.0 i 13.1 45.0111.0 25.9 - 64.1 Beta 41.3118.6 50.015.0 14.3 - 58.7 STM-673 MILK Sep,1992 Cs-137 14.0 i 3.5 15.0 i 5.0 6.3 - 23.7 I-131(gamma 109.7 1 19.4 100.0 i 10.0 82.7 - 117.3 K
1540.0 i 103.9 1750.0 1 88.0 1597.3 - 1902.7 j
'Ite K activity was calculated using the wrong volume (3.5 L),
instead of 3.25 L. Correction for volume resulted in a value of 1660.01110.1; within EPA control limits.
Sr-89 11.0
- 3.5 15.0 i 5.0 6.3 - 23.7 St-90 12.711.6 15.015.0 6.3 - 23.7 STW-674 WATER Oct,1992 Ba-133 80.3 i 9.0 74.0 i 7.0 61.9 - 86.1 Co-60 11.312.3 10.015.0 1.3 - 18.7 Cs-134 9.7 1 2.3 8.0i 5.0 0.0 - 16.7 Cs-137 9.7i1.2 8.0 t 5.0 0.0 - 16.7 Ru-106
'712.3 175.0 1 18.0 143.8 - 206.2 Zn-65
't 25.0 148.0 t 15.0 122.0 - 174.0 STW-675 WATER Oct,1992 H-3 i 136.2 5962.0 i 596.0 4928.0 - 6996.0 STW-676 WATER Oct,1992 i
Gr. Alpha 24.7 i 5.0 29.0 i 7.0 16.9 - 41.1 1
Ra-226 7.1 i 0.4 7.4 i 1.1 5.5 - 9.3 Ra-228 11.5 1.0 10.012.5 5.7 - 14.3 Uranium 9.7i 0.5 10.213.0 5.0 - 15.4 STW-677 WATER Oct,1992 Co-60 15.0 i 2.0 15.0 i 5.0 6.3 - 23.7 Cs-134 5.7i 1.2 5.015.0 0.0 - 13.7 Cs-137 8<0 1 2.0 E 0 1 5.0 0.0 - 16.7 Gr. Beta 42.7 i 8.1 1A0i 10.0 35.7 - 70.3 i
Sr-89 6.7i 1.2 8.0i 5.0 0.0 - 16.7 Sr-90 10.0 i 2.0 110.0 i 5.0 1.3 - 18.7 A1-10 l
l i
l j
9
\\
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA.and Teledyne's Midwest Laboratory results for various sample ir edia'.
Concentration in pCi/L' Lab Sample Date Teledyne Results EPA Resultd Control Code Type Collected Analyses i2 Sigma' 1s, N=1 Limits STW-678 WATER Oct,1992 Ra-226 7.5 1 0.8 7.5 i 1.1 5.6 - 9.4 Ra-228 5.8 i 0.7 5.0 i 1.3 2.7 - 7.3 STW-679 WATER Nov,1992 Uranium 15.5 i 1.1 15.2 i 3.3 10.0 - 20.4 STW-680 WATER Jan,1993 Sr-89 15.0 i 2.0 15.015.0 6.3 - 23.7 Sr-90 10.3 t 1.2 10.0 5.0 1.3 - 18.7 STW-681 WATER Jan,1993 Pu-239 17.5 i 1.6 20.0 i 2.0 16.5 - 23.5 STW-682 WATER Jan,1993 J
A1pha 17.1 i 1.2 34.0 i 9.0 18.4 - 49.6
{
Gross Alpha analysis was repeated with similar results. An investigation of possible causes for the deviation from the EPA was conducted with no cause discovered. The sample was spiked with Th-230; so Alpha Spec Analysis for Th-230 was performed in triplicate with results of 15.5i2.1,13.411.4, and 14.812.0. It should be noted that 66% of all participants failed this analysis with a grand average of 17.1. This coupled with the support of the Alpha Spec results leaves TIML cause to believe that there may have been 'a dilution error at the EPA. It should be noted that on the next Gross Alpha EPA check, TIML reported results that where exactly the known value. Since ne apparent cause can be found, and TIML had outstanding results on the I
following sample, it is felt that no further investigation is needed.
Beta 46.7 i 3.2 44.0f 5.0 35.3 - 52.7 STW-683 WATER Feb,1993 I-131 106.0 i 10.0 100.0 i 10.0 82.7 - 117.3 STW-684 WATER Feb,1993 l
Uranium 7.210.5 7.6 i 3.0 2.4 - 12.8 STW-685 WATER Mar,1993 Ra-226 9.3 i 1.3 9.8i1.5 7.2 - 12.4 Ra-228 20.812.2 18.5 i 4.6 10.5 - 26.5 STW-636 WATER Apr,1993 A1pha 88.3 i 8.1 95.0124.0 53.4 - 136.6 Ra-226 25.4 i 1.4 24.9 i 3.7 18.5 - 31.3 Ra-228 17.4 i 1.2 19.014.8 10.7-27.3 Al-11 i
l
1 i
l 1
j Table A 1.
U.S. Envire nental Protection Agency's crosscheck program, comparison of EPA and Te j
Midwest I c oratory results fer various sample media'.
f Concentration in pCi/L'
)
Lab Sample Date Teledyne Results EPA Resultd i
Code Type Collected Analyses i2 Sigma
- 1s, N=1 Limits Control Uranium 27.8 i 2.2 28.9 i 3.0 23.7 - 34.1
{
STW-687 WATER Apr,1993 4
Beta 141.7 9.0 177.01 27.0 130.2 - 223.8 i
Co-60 41.3 i 1.2 39.015.0 30.3 - 47.7 I
Cs-134 24.7 i 1.2 27.015.0 18.3 - 35.7 Cs-137 30.0 0.0 32.015.0 23.3 - 40.7 Sr-89 28.7 i 9.4 41.0 i 5.0 32.3 - 49.7 The EPA report was received 08-16-93. No cause for the low result for Sr-89 was found. 'Ihe analyst has been observed performing this procedure with no noted descrepancies.
)
Teledyne will continue to monitor this procedure in the future.
3 No further action is anticipated unless conditions warrant.
Sr-90 28.0 i 3.5 29.0 i 5.0 20.3 - 37.7 STW-688 WATER Jun,1993 H-3 9613.3 i 46.2 9844.0 i 984.0 8136.8 - 11551.2 STW-689 WATER Jun,1993 Ba 133 101.7 i 10.3 99.0 i 10.0 81.7 - 116.3 i
CcHSO 17.3 i 4.6 15.015.0 6.3 - 23.7 i
Cs-134 5.7i 1.2 5.0i5.0 0.0- 13.7 i
)
Cs-137 6.012.0-5.0i 5.0 0.0- 13.7 Ru-106 108.0 i 8.0 119.0 i 12.0 98.2 - 139.8 Zn-65 114.0 i 13.2 103.0 i 10.0 85.7 - 120.3 i
STW-690 WATER Jul,1993 4
Sr-89 28.3 i 2.3 34.0 i 5.0 25.3 - 42.7 l
Sr-90 25.0 i 1.0 25.015.0 16.3 - 33.7 f
STW-691 WATER Jul,1993 A1pha 15.0 i 2.7 15.0 i 5.0 6.3 - 23.7 j
Beta 41.314.9 43.0 i 6.9 31.0 - 55.0
]
STW-692 WATER Aug,1993 Uranium 24.9 i 1.4 25.3 i 3.0 20.1 - 30.5 j
STAF-693 AIR FILTER Aug,1993 j
A1pha 17.0 1.0 19.015.0 10.3-27.7 j
Beta i
47.3i 0.6 47.015.0 38.3 - 55.7 i
Cs-137 10.0 i 1.0 9.0 i 5.0 0.3-17.7 Sr.90 19.310.6 19.0 i 5.0 10.3-27.7 STW-694 WATER Sep,1993 Ra-226 15.9 i 0.7 14.912.2 11.1 - 18.7 i
A1-12 i
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Teledyne's Midwest Laboratory results for var:ous sample media'.
6 Concentration in pCi/L Lab Sample Date Teledyne Results EPA Result' Control Code Type Collected Analyses f2 Sigma' 1s, N=1 Limits Ra-228 21.011.6 20.415.1 11.6 - 29.2 STM-695 MILK Sep,1993 Cs-137 49.013.0 49.0 i 5.0 40.3 - 57.7 I-131 125 3 i 4.5 120.0 i 12.0 99.2 - 140.8 K
1616.7 i 37.9 1679.0 i 84.0 1533.3 - 1824.7 Sr-89 19 3 i 1.5 30.015.0 21.3 - 38.7 Report was received 01-18-94; an investigation is underway as to the cause of the low Sr-89 results. In-house spikes have been prepared and the analysis is in progress (see SPM-4848 and SPM-4849 in future reports). There is no apparent cause of the low Sr-89 results. In-house spikes have been prepared and the
- analysis is in progress. The analyst has been observed performing this procedure with no discrepancies noted. No
, further action is planned unless the results of the in-house spikes show a problem.
Sr-90 22.0 i 0.0 25.0 i 5.0 16.3 - 33.7 STW-696 WATER Oct,1993 1-131 116.7 i 2.3 117.0 i 12.0 96.2 137.8 STW-697 WATER Oct,1993 Gr. Alpha 39.7 i 1.5 40.0 i 10.0 22.7 - 57.3 Ra-226 10.610.5 9.9 i 1.5 7.3 - 12.5 Ra-228 13.2 i 1.5 12.5 i 3.1 7.1 - 17.9 Uranium 15.310.6 15.113.0 9.9 - 20.3 STW-698 WATER Oct,1993 Beta 52.0 i 1.0 58.0110.0 40.7 - 75.3 Co-60 10.7 i 0.6 10.015.0 1.3 - 18.7 Cs-134 10.0 i 1.0 12.0 i 5.0 3.3 - 20.7 Cs-137 12.3 i 1.2 10.015.0 1.3 - 18.7 Sr-89 11.310.6 15.015.0 6.3 - 23.7 Sr-90 11.0 i 0.0 10.0 i 5.0 1.3 - 18.7 S'lW-699 WATER Oct,1993 A1pha 18.3 2.5 20.0 i 5.0 11.3 - 28.7 Beta 13.7 i 0.6 15.0 i 5.0 6.3 23.7 STW-700 WATER Nov,1993 H-3 7310.0 i 175.2 7398.0 i 740.0 6114.1 - 8681.9 STW-701 WATER Nov,1993 l
Ba-133 75.7 i 7.6 79.018.0 65.1 - 92.9 Co-60 30.7 i 2.1 30.0 i 5.0 21.3 - 38.7 Al-13 4m-
Table A-1.
U.S. Environmental Protection Agency's crosscheck program, comparison of EPA and Teledyne's Midwest Laboratory results for various sample media'.
Concentration in pCi/L' Lab Sample Date Teledyne Results EPA Resultd Control Code Type Collected Analyses 2 Sigma' Is, N=1 Limits Cs-134 51.3 i 5.9 59.015.0 50.3 - 67.7 Cs-137 41.7 i 1.2 40.0 i 5.0 31.3 - 48.7 Ru-106 163.3 i 3.2 201.0 i 20.0 166.3 - 235.7 The report was received on 02-14-94; the cause of the low Ru-106 is under investigation. It should be noted that the grand average of all participants in this analysis was 175.2 pCi/L, with 54%
of the participants outside of limits.
Zn-65 157.0 i 8.7 150.0 i 15.0 124.0 - 176.0
- Results obtained by Teledyne Brown Engineering Environmental Services Midwest Laboratory as a participant in the environmental sample crosscheck program operated by the Intercomparison and Calibration Section, Quality Assurance Branch, Environmental Monitoring and Support Laboratory, U.S.
Environmental Protection Agency (EPA), Las Vegas, Neveda.
)
All results are in pCi/L, except for elemental potassium (K) data in milk, which are in mg/L; air filter 6
samples, which are in pCi/ Filter.
Unless otherwise indicated, the TBEESML results are given as the mean i 2 standard deviations for three determinations.
d USEPA results are presented as the known values and expected laboratory precision (1s, I determination) and control limits as defined by the EPA.
l i
A1-14 1
Table A-2. Crosscheck program results; Thermoluminescent Dosimeters. (TLDs).
mR Lab Teledyne Results Known Average 12 Sigma Code TLD Type Date Measurement 12 Sigma Value -i 2 Sigma (All Participants) 2nd Intemational Intercomoarison 115-2 CaF : Mn Bulb Apr,1976 2
Field 17.011.9 17.1 16.4 i 7.7 Lab 20.8 i 4.1 21.3 18.8 i 7.6 j
Second InternationalIntercomparison of Environmental Dosimeters conducted in April of 1976 b the Health y
and Safety Laboratory (HASL), New York, New York, and the School of Public Health of the University of Texas, Houston, Texas.
3rd Intemational Intercomoanson 115-3 CaF : Mn Bulb Jun,1977 2
FieId 30.7 i 3.2 34.9 i 4.8
'31.5 i 3.0 Lab 89.6 i 6.4 91.7 i 14.6 86.2124.0 Third International Intercomparison of Environmental Dosimeters conducted in the summer of 1977 by Oak Ridge National Laboratory and the School of Public Health of the University of Texas, Houston, Texas.
l Ath International Intercomoarison 115-4 CaF : Mn Bulb Jun,1979 2
Field 14.111.1 14.li1.4 16.0 i 9.0 Lab, High 40.4 i l.4 45.819.2 43.9 i 13.2 12b, Low 9.8 i 1.3 12.2 i 2.4 12.0 i 7.4 I
Fourth Intemational Intercomparison of Environmental Dosimeters conducted in the summer of 1979 by the School of Public Health of the University of Texas, Houston, Texas.
5th Intemational Intercomoarison 115-5A CaF : Mn Bulb Oct,1980 2
Fie1d 31.4 i 1.8 30.0 i 6.0 30.2114.6 Lab,End 96.615.8 88.4 i 8.8 90.7 i 31.2 Lab, Start 77.4 i 5.8 75.2 i 7.6 75.8 i 40.4 115-5B LiF-100 Chips Oct,1980 F1eId 30.314.8 30.0
- 6.0 30.2114.6 Lab,End' 85.4111.7 88.4 i 8.8 90.7 i 31.2 Lab, Start 81.1 i 7.4 75.2 i 7.6 75.8 i 40.4 Fifth International Intercomparison of Environmental Dostmeters conducted in the fall of 1980 at Idaho Falls, Idaho and sponsored by the School of Public Health of the University of Texas, Houston, Texas and Environmental Measurements laboratory, New York, New York, U.S. Department of Energy.
7th International Intercomparison 115-7A LiF-100 Chips Jun,1984 FieId 75.4 i 2.6 75.816.0 75.1129.8 A21
[
l 1
=.
Table A-2. Crosscheck program results; Thermoluminescent Dosimeters. (II.Ds).
mR Lab Teledyne Results Known Average 12 Sigma Code TLD Type Date Measurement i 2 Sigma Value i 2 Sigma (All Participants)
Lab, Co-60 80.0 i 3.5 79.9 i 4.0 77.9 i 27.6 Lab, Cs-137 66.6 i 2.5 75.0 i 3.8 73.0 t 22.2 115-7B CaF : Mn Bulb Jun,1984 2
Fie1d 71.5 i 2.6 75.8 i 6.0 75.1 i 29.8 Lab, Co-60 84.8 i 6.4 79.914.0 77.9 i 27.6 Lab, Cs-137 78.811.6 75.0 i 3.8 73.0122.2 115-7C CaSO.:Dy Jun,1984 Cards 4
Fie1d 76.8 i 2.7 75.8 i 6.0 75.1 i 29.8 l
Lab, Co-60 82.5 i 3.7 79.9 i 4.0 77.9 i 27.6 l
Lab, Cs-137 79.0 i 3.2 75.013.8 73.0 i 22.2 Seventh International Intercomparison of Environmental Dosimeters conducted in the spring and summer of i
1984 at Las Vegas, Neveda, and sponsored by the U.S. Department of Energy, The Nuclear Regulatory Commission, and the U.S. Environmental Protection Agency. Teledyne did not participate in the Si.xth International Intercomparison of Environmental Dosimeters.
8th International Intercomoarison 115-8A LiF-100 Chips Jan,19%
Field, Site 1 29.511.4 29.711.5 28.9 i 12.4 Field, Site 2.
11.310.8 10.4 i 0.5 10.119.1 Lab, Cs-137 13.7 i 0.9 17.2i 0.9 16.216.8 115-8B CaF,: Mn Bulb Jan,1986 Field, Site 1 32.3 t l.2 29.7i l.5 28.9112.4 l
Field, Site 2 9.0il.0 10.410.5 10.119.0 1
Lab, Cs-137 15.8 i 0.9 17.210.9 16.2 i 6.8 115-8C CaSO :Dy Jan,1986 Cards l
Field, Site 1 32.210.7 29.7 i 1.5 28.9112.4 t
j Field, Site 2 10.610.6 10.410.5 10.119.0 Lab, Cs-137 18.1 i 0.8 17.2 i 0.9 16.2 i 6.8 Eighth InternationalIntercomparison of Environmental Dosimeters conducted in the fall and winter of 1985-1986 at New York, New York and sponsored by the U.S. Department of Energy.
10th International Intercomnarison A2-2
\\
l
]
Table A-2. Crosscheck program results; Thermoluminescent Dosimeters. (TLDs).
mR Lab Teledyne Results Known Average 12 Sigma Code TLD Type Date Measurement i 2 Sigma Value i 2 Sigma (All Participants) 115-10A LiF-100 Chips Aug,1993 Fie1d 25.7 i 1.4 27.0 i 1.6 26.4 i 10.2 Lab 22.7 i 1.6 25.911.3 25.0 i 9.4 Lab 62.712.6 72.711.9 69.8 i 20.3 115-10B CaSOgDy Aug,1993 Cards FieId 26.0 i 2.3 27.0 t 1.6 26.4110.2 Lab 24.1 i 1.7 25.911.3 25.019.4 Lab 69.2 i 3.0 72.711.9 69.8120.3 Tenth International Intercomparison of Enviranmental Dosimeters conducted in 1993 at Idaho State University and sponsored by the U.S. Department of Energy and the Idaho State University. The Ninth International Intercomparison of Environmental Dosimeters was not available to Teledyne's Midwest Laboratory.
Teledyne Testing 89-1 LiF-100 Chips Sep,1989 Lab 21.010.4 22.4 ND ND = No Data; Teledyne Testing was only performed by Teledyne.
Chips were irradiated by Teledyne Isotopes, Inc., Westwood NJ. in September,1989 89-2 Teledyne Nov,1989 CaSOgDy Cards Lab 20.9 i 1.0 20.3 ND ND = No Data; Teledyne Testing was only performed by Teledyne.
Cards were irradiated by Teledyne Isotopes, Inc., Westwood NJ. in November,1989.
90-1 Teledyne Jun,1990 CaSOpDy Cards Lab 20.6 i 1.4 19.6 ND ND = No Data; Teledyne Testing was only performed by Teledyne.
Cards were irradiated by Teledyne Isotopes, Inc., Westwood NJ. on June 19,1990.
90-2 Teledyne Sep,1990 CaSOcDy Cards Lab 100.8 i 4.3 100.0 ND ND = No Data; Teledyne Testing was anly performed by Teledyne.
Cards were irradiated by Dosimetry Associates, Inc., Northville, MI on October 30,1990.
A2-3 m
Table A-2. Crosscheck program results; Thermoluminescent Dosimeters (TLDs).
mR Lab Teledyne Results Known Code TLD Type Date Measurement i 2 Sigma Average i 2 Sigma Value i 2 Sigma (All Participants) 91-1 Teledyne Oct,1990 CaSO :Dy Cards bb1 33.4 i 2.0 32.0 ND bb2 55.2 i 4.7 58.8 ND bb3 87.816.2 85.5 ND ND = No Data; Teledyne Testing was only performed by Teledyne.
Cards were irradiated by Teledyne Isotopes,Inc., Westwood NJ. on October 8 1991 92 1 LiF-100 Chips Feb,1992 bb1 11.110.2 10.7 ND bb2 25.610.5 25.4 ND bb3 46.410.5 46.3 ND ND = No Data; Teledyne Testing was only performed by Teledyne, Chips were irradiated by Teledyne Isotopes, Inc., Westwood NJ. on February 26 92-2 Teledyne Apr,1992 Ca50 :Dy 4
i Cards Reader 1, #1 20.110.1 20.1 ND Reader 1, #2 40.610.1 40.0 ND Reader 1, #3 60.0 i 1.3 60.3,
ND Reader 2, #1 20.310.3 20.1 ND Reader 2, #2 39.210.3 40.0 ND Reader 2, #3 60.7 i 0.4 60.3 ND ND = No Data; Teledyne Testing was only performed by Teledyne.
Cards were irradiated by Teledyne isotopes, Inc., Westwood NJ. on April 1 1992 93-1 Teledyne Mar,1993 LiF-100 Chips bb1 10.011.0 10.2 ND Lab 2 25.512.2 25.5 ND Lab 3 42.715.7 45.9 ND ND = No Data; Teledyne Testing was only performed by Teledyne.
j Cards and Chips were irradiated by Teledyne Isotopes, Inc., Westwood NJ on potential error of 10-12% when cards where irradiated, results of the testing on t l
c
- 3. Due to a published. Data is available upon request.
not be l
i A2-4 I
Table A-3. In-house " spike" samples.
Concentration in pCi/L' Lab Sample Date Teledyne Results Known Control' 6
Code Type Collected Analyses 2s, n=1 Activity Limits QCMI-26 MILK Jan,1990 Cs-134 19.3 i 1.0 20.8 10.8 - 30.8 Cs-137 25.211.2 22.8 12.8 - 32.8 QCMI-27 MILK Feb,1990 Sr-90 18.0 i 1.6 18.8 8.8 - 28.8 QCMI-28 MILK Mar,1990 I-131 63.8 i 2.2 62.6 50.1 - 75.1 QCMI-29 MILK Apr,1990 Cs-134 18.3 i 1.0 19.7 9.7 - 29.7 Cs-137 20.311.0 18.2 8.2 - 28.2 I-131 90.7 i 9.2 82.5 66.0 - 99.0 QCW-61 WATER Apr,1990 Sr-89 17.915.5 23.1 13.1 - 33.1 Sr-90 19.4 i 2.5 23.5 13.5 - 33.5 QCW-62 WATER Apr,1990 Co-60 8.7i 0.4 9.4 0.0 - 19.4 Cs-134 20.010.2 19.7 9.7 - 29.7 Cs-137 28.7 i 1.4 22.7 12.7 - 32.7 QCW-63 WATER Apr,1990 I-131 63.5 i 8.0 66.0 52.8 - 79.2 QCW-64 WATER Apt,1990 H-3 1941.0 1 130.0 1826.0 1141.5 - 2510.5 QCW-65 WATER Jun,1990 Ra-226 6.4 i 0.2 6.9 4.8 - 9.0 QCW-66 WATER Jun,1990 Uranium 6.210.2 6.0 3.6 - 8.4 l
QCMI-30 MILK Jul,1990 Cs-134 46.011.3 49.0 39.0 - 59.0 Cs-137 27.6 i 1.3 25.3 15.3 - 35.3 l
Sr-89 12.810.4 18.4 8.4 - 28.4 Sr-90 18.211.4 18.7 8.7 - 28.7 QCW-68 WATER Jul,1990 Gr. Alpha 9.8 i 0.3 10.6 0.6 - 20.6 Gr. Beta 11.4 i 0.6 11.3 1.3 - 21.3 QCMI-31 MILK Aug,1990 1-131 68.811.6 61.4 49.1 - 73.7 A3-1 l
Table A-3. In-hodse " spike" samples.
Concentration in pCi/11 Lab Sample Date Teledyne Results Known Control' Code Type Collected Analyses 2s, n=1 Activity Limits 6
QCW-69 WATER Sep,1990 Sr-89 17.7 i 1.6 19.2 9.2 - 29.2 Sr-90 13.9 i 1.6 17.4 7.4 - 27.4 QC MI-32 MILK Oct,1990 Cs-134 25.8 i 1.2 27.3 17.3 - 37.3 j
Cs-137 25.3 i 2.0 22.4 12.4 - 32.4 I-131 34.810.2 32.4 20.4 - 44.4 QCW-70 WATER Oct,1990 H-3 2355.0 t 59.0 2276.0 1577.3 - 2974.7 QCW 71 WATER Oct,1990 1-131 55.910.9 51.8 39.8 - 63.8 QCW-73 WATER Oct,1990 Co-60 18.3 i 2.7 16.8 6.8 - 26.8 Cs-134 28.3 i 2.3 27.0 17.0 - 37.0 Cs-137 22.7 i 1.3 22.4 12.4 - 32.4 QCW-74 WATER Dec,1990 Gr. Alpha 21.4 i 1.0 26.1 13.1 - 39.2 Gr. Beta 25.9 i 1.0 22.3 12.3 - 32.3 QCMI-33 MILK Jan,1991 Cs-134 22.2 i 1.7 19.6 9.6 - 29.6 Cs-137 26.1 i 1.6 22.3 12.3 - 32.3 Sr-89 20.713.3 21.6 11.6 - 31.6 St-90 19.0 i t.4 23.0 13.0 - 33.0 QCMI-34 MILK Feb,1991 1-131 40.711.8 40.1 28.1 - 52.1 QCW-75 WATER Mar,1991 Sr-89 18.8 i 1.5 23.3 13.3 - 33.3 Sr-90 16.0 i 0.8 17.2 7.2-27.2 QCM1-35 MILK Apr,1991 Cs-134 19.212.0 22.6 12.6 - 32.6 Cs-137 22.8 i 2.2 22.1 12.1 - 32.1 I-131 48.0 i 0.8 49.2 37.2 - 61.2 QCW-76 WATER Apr,1991 1-131 56.511.7 59.0 47.2 - 70.8 QCW.77 WATER Apr,1991 Co-60 16.4 i 2.2 15.7 5.7 - 25.7 A3-2 w-
4 Table A-3. In-h'ouse " spike" samples.
Concentration in pCi/If 1
Lab Sarnple Date Teledyne Results Known Control'
}
6 Code Type Collected Analyses 2s, n=1 Activity Limits Cs-134 23.8 i 2.5 22.6 12.6 - 32.6 Cs-137 25.0 i 2.4 21.1 11.1 - 31.1 QCW 78 WATER Apr,1991 H-3 4027.0 1 188.0 4080.0 3264.0 - 4896.0 QCW.79 WATER Jun,1991 Gr. Alpha 7.4 i 0.7 7.8 0.0 - 17.8 Gr. Beta 11.0 i 0.7 11.0 1.0 - 21.0 SPM-36 MILK Jul,1991 Cs-137 34.3 i 3.0 35.1 25.1 - 45.1 I-131 14.4 i 1.9 18.3 6.3 - 30.3 i
Sr-89 28.1 i 2.1 34.0 24.0 - 44.0 Sr-90 11.6 i 0.7 11.5 1.5 - 21.5 QCMI-37 MILK Oct,1991 Cs-134 22.7 i 2.8 22.1 12.1 - 32.1 Cs-137 38.313.0 35.1 25.1 - 45.1
)
I-131 23.6 i 3.2 25.8 13.8 - 37.8 QCW-80 WATER Oct,1991 Sr-89 27.4 i 6.9 24.4 14.4 - 34.4 St-90 11.711.4 14.1 4.1 - 24.1 QCW-81 WATER Oct,1991 1-131 19.1 i 0.7 20.6 8.6 - 32.6 QCW-82 WATER Oct,1991 Co-60 22.612.7 22.1 12.1 - 32.1 Cs-134 15.5 i 1.8 17.6 7.6 - 27.6 Cs-137 17.5 i 2.1 17.6 7.6 - 27.6 QCW-83 WATER Oct,1991 H3 4639.0 i 137.0 4382.0 3505.6 - 5258.4 QCW-84 WATER Dec,1991 Gr. Alpha 6.2 i 6.0 7.8 0.0 - 17.8 Gr. Beta 11.010.7 11.0 1.0 - 21.0 QCMI-39 MILK Jan,1992 l
Cs-134 42.1 i 5.7 49.4 39.4 - 59.4 Cs-137 55.2 i 6.4 53.0 43.0 - 63.0 1-131 76.8 i 0.9 83.7 67.0 - 100.4 Sr-89 21.6 i 6.5 31.2 21.2 - 41.2 St-90 38.7 i 1.8 42.3 33.8 - 50.8 I
i A3-3 i
Table A-3. In-house " spike" samples.
Concentration in pCi/L' Lab Sample Date Teledyne Results Known Control' Code Type Col!ected Analyses 2s, n=1' Activity Limits l
QCW-85 WATER Mar,1992 Sr-89 26.213.1 32.0 22.0 - 42.0 Sr-90 24.4 i 1.4 28.0 18.0 - 38.0 QCMI-40 MILK Apr,1992 Cs-134 58.012.6 55.9 45.9 - 65.9 Cs-137 43.713.0 38.9 28.9 - 48.9 QCMI-41 MILK Apr,1992 I-131 50.3 i 0.8 55.9 44.7 - 67.1 QCW-86 WATER Apr,1992 H-3 4080.0 i 190.0 4027.0 3221.6 - 4832.4 QCW-87 WATER Apt,1992 I-131 33.510.6 33.2 21.2 - 45.2 QCW-88 WATER Apr,1992 CMC 17.512.7 19.7 9.7 - 29.7 Cs-134 28.9i2.5 33.5 23.5 - 43.5 Cs-137 41.013.0 38.9 28.9 - 48.9 QCW-89 WATER Jun,1992 Gr. Alpha 15.310.8 13.6 3.6 - 23.6 Gr. Beta 17.210.9 17.6 7.6 - 27.6 QCMI-42 MILK Aug,1992 Cs-134 20.112.8 20.2 10.2 - 30.2 Cs-137 26.2 i 2.7 26.1 16.1 - 36.1 St-89 41.4 i 5.9 51.2 41.0 - 61.4 Sr-90 48.9 i 2.5 51.9 41.5 - 62.3 QCW-90 WATER Sep,1992 Sr-89 6.7i 3.4 12.6 2.6 - 22.6 Sr-90 16.1 i 1.4 15.6 5.6 - 25.6 QCMI-43 MILK Oct,1992 Cs-134 14.2 i 3.4 12.7 2.7 - 22.7.
Cs-137 14.115.2 17.1 7.1 - 27.1 1-131 19.9 i 1.0 21.5 9.5 - 33.5 QCMI-44 MILK Oct,1992 Cs-134 28.2 i 4.0 25.4 15.4 - 35.4 Cs-137 38.8 i 5.1 34.2 24.2 - 44.2 1-131 36.1 i 1.2 43.0 31.0 - 55.0 A3-4
i
)
Table A-3. 'In-h6use " spike" samples.
Concentration in pCi/L' Lab Sample Date Teledyne Results Known Control' 6
Code Type Collected Analyses 2s, n=1 Activity Limits QCW-91 WATER Oct,1992 I-131 34.9 i 2.2 34.9 22.9 - 46.9 i
QCW-92 WATER Oct,1992 Co.60 11.4 i 1.9 9.2 0.0 - 19.2 Cs-134 18.7 2.3 14.3 4.3 - 24.3 Cs-137 14.1 i 1.8 15.0 5.0 - 25.0 j
QCW.93 WATER Oct,1992 J
H-3 3704.0 i 186.0 3904.0 3169.2 - 4638.8 QCW-94 WATER Cd,1992 QCW-95 WATER Oct,1992 1-131 64.212.7 67.2 53.8 - 80.6 QCW-36 WATER Dec,1992 A1pha 11.5 i 2.3 15.2 9.1 - 21.3 Beta 26.5 i 2.0 25.7 15.4 - 36.0 QCW-96 WATER Dee,1992 Gr. Alpha 8.3i0.6 10.4 0.4 - 20.4 Gr. Beta 19.8 i 1.5 20.6 10.6 - 30.6 SPM-3341 MILK Jan,1993 Cs-134 17.1 2.0 21.3 11.3 - 31.3 Cs-137 21.4 i 2.0 23.8 13.8 - 33.8 Sr-89 6.7i 3.1 8.7 0.0 - 18.7 Sr-90 20.0 i 1.2 19.2 9.2 - 29.2 SPM 3387 MILK Feb,1993 I-131 72.5 i 8.4 71.5 57.2 - 85.8 SPVE-3401 VEGETATION Feb,1993 (SAW DUST) 1-131 994.5 i 53.2 953.7 763.0 - 1144.4 SPCH-3402 CHARCOAL Feb,1993 I-131 95.2 i 12.8 95.4 76.3 - 114.5 SPW-3434 WATER Apr,1993 Gr. Alpha 10.4 i 1.8 10.4 0.4 - 20.4 Gr. Beta 22.0 i 2.0 20.6 10.6 - 30.6 SPW-3556 WATER Apt,1993 Sr-89 18.2 i 5.0 22.2 12.2 - 32.2 Sr-90 20.1 i 1.8 17.0 7.0 - 27.0 A3-5
i 1
1 Table A-3. In-house " spike" samples.
l Concentration in pCi/If Lab Sample Date Teledyne Results Known Control' i
Code Type Collected Analyses 2s, n =16 Activity Limits SPW-3597 WATER Apt,1993 H-3 5464.0 i 219.0 5428.0 4342.4 - 6513.6 SPW 3599 WATER Apr,1993 1-131 149.8 i l.9 145.0 116.0 - 174.0 SPW-3606 WATER Apr,1993 Co-60 24.8 i 2.3 21.5 11.5 - 31.5 Cs-134 26.4 i 1.9 26.4 16.4 - 36.4 Cs-137 33.912.6 31.7 21.7 - 41.7 SPM-3631 MILK Apr,1993 Cs-134 48.8 t 2.9 52.8 42.8 - 62.8 Cs-137 65.212.9 63.4 53.4 - 73.4 1-131 139.8 i 1.6 145.0 116.0 - 174.0 SPF-3681 FISH May,1993 0ELLO)
Cs-137 68.2 i 7.7 67.6 57.6 - 77.6 Concentrations are in pCi/ Total Volume (550g).
SPW-3842 WATER Jun,1993 Th-230 4.2 i 0.5 4.5 2.7 - 6.3 i
SPW-4160 WATER Jun,1993 A1pha 8.9 i 1.4 12.9 7.7 - 18.1 Beta 22.0 i 1.9 31.9 19.1 - 44.7 SPW-4232 WATER Aug,1993 Fe-55 1684.0 1 415.0 1420.0 1136.0 - 1704.0 SPW-4246 WATER Aug,1993 St-90 32.2 i 2.6 30.4 24.3 - 36.5 SPM-4247 MILK Aug,1993 Sr-89 29.1 i 4.9 35.4 25.4 - 45.4 Sr-90 18.311.3 19.2 9.2 - 29.2 SPW-4248 WATER Aug,1993 H-3 9910.0 1 300.0 10430.0 8344.0 - 12516.0 SPW-4250 WATER Aug,1993 4
Co-60 247.0 i 23.1 247.7 222.9 - 272.5 C3-134 141.6 1 15.9 141.1 127.0 - 155.2 I
1 i
1 A3-6 l
]
Table A-3. In-house " spike" samples.
Concentration in pCi/L' Lab Sample Date Teledyne Results Known Control' 6
Code Type Collected Analyses 2s, n=1 Activity Limits Cs-137 283.5 1 27.8 247.2 222.5 - 271.9 The cause of the high Cs-137 data is unknown. All data was reviewed, no errors where found in the calculations. He employee was observed performing this analysis and no deviations from the procedure where observed, ne employee's results have been good in the past; no ftuther action is planned.
SPP-4251 FISH (JELLO) Aug,1993 C3-134 68.8 i 3.3 75.3 65.3 - 85.3 Cs-137 203.6 i 8.2 198.1 178.3 - 217.9 SPS-4262 SEDIMENT Aug,1993 (BOTTOM)
Cs-114 74.1 i 9.9 71.0 61.0 - 81.0 Cs-137 212.4 i 14.8 197.8 178.0 - 217.6 SPW-4377 WATER Sep,1993 I-131 39.0110.0 42.1 30.1 - 54.1 SPM-4378 MILK Sep,1993 1-131 44.5 i 5.5 42.1 30.1 - 54.1 SPCH-4379 CHARCOAL Sep,1993 1-131 90.3 i 13.5 84.3 67.4 - 101.2 SPVE-4380 VEGETATION Sep,1993 (SAW DUST) 1-131 193.2 i 20.0 170.2 136.2 - 204.2 SPW-4381 WATER Sep,1993 Sr-89 21.914.0 28.8 18.8 - 38.8 Sr-90 19.5 i 1.8 19.0 9.0 - 29.0 SPW-4382 WATER sep,1993 1129 18.1 i 1.0 18.6 6.6 - 30.6 SPW-4421 WATER Oct,1993 H-3 16900.0 1 368.0 17380.0 13904.0 - 20856.0 SPW-4428 WATER Oct,1993 CM4 19.3 i 3.1 18.3 8.3 - 28.3 Cs-134 31.5 i 3.3 33.5 23.5 - 43.5 Cs-137 44.4 i 3.6 43.2 33.2 - 53.2 l
SPM-4426 MILK Oct,1993 l
Cs-134 30.8 i 4.5 33.0 23.0 - 43.0 l
Cs-137 43.4 i 6.0 43.2 33.2 - 53.2 1-131 49.7 i 8.6 44.5 32.5 - 56.5 l
A3-7 l
l
j Table A-3. In-house " spike" samples.
Concentration in pCi/11 j
Lab Sample Date Teledyne Results Known Control' Code Type Collected Analyses 2s, n=1 Activity Limits 6
SPW-4427 WATER Oct,1993 I131 95.2 i 10.6 88.9 71.1 - 106.7
- All results are in pCi/L, except elemental potassium (K) data in milk, which are in mg/L; air filter samples, which are in pCi/ Filter; charcoal which are in pCi/ charcoal; and food products which are in i
mg/kg.
- All samples prior to January 1991 are the results or three determinations; after January 1991, all determinations are single.
1
' Control Limits are based on EPA publication; " Environmental Radioactive Laboratory Intercomparison Studies Program", Fir <al Year 1981-1982, EPA-600/4-81-004 (see Attachment A) or limits imposed by Teledyne's Midwest Laboratory.
l
)
e A3-8
~
Table A.4.
In-house " blank" samples.
^
l Concentration pCi/L*.
Teledyne Results, Acceptance Lab Sample Sample (4.66 Sigma)
Criteria Code Tvoe Date Analyses LLD Activity' (4.66 Sigma) l SPW 8039 WATER Jan 1990 Ra-226
< 0.2
< 1.0 SPM-8040 MILK Jan 1990 Sr 89
< 0.8
< 5.0 Sr-90
< 1.0
< 1.0 SPM-8208 MILK Jan 1990 Cs-134
< 3.6
< 10.0 l
< 4.7
< 10.0 Sr-89
< 0.8
< 5.0 Sr-90 N/A 1.6 1 0.5
< 1.0 Low level of Sr-90 concentration in milk (1-5 pCi/L) is not unusual j
SPM-8312 MILK Feb 1990 Sr-89
< 0.3
<5.0 Sr90 N/A 1.2 i 0.3
< 1.0 Low level of St-90 concentration in milk (1-5 pCi/L) is not unusual.
SPW-8312 WATER Feb l990 Sr-89
< 0.6
<5.0 Sr-90
< 0.7
< 1.0 SPM-8314 MILK Mar 1990 SPM-8510 MILK May 1990 Cs-134
< 4.6
< 10.0 Cs-137
< 4.8
< 10.0 1-131
< 0.2
< 1.0 SPW-8511 WATER May 1990 H-3
< 200.0
< 300.0 SPM-8600 MILK Jul1990 Cs-134
< 5.0
< 10.0 Cs-137
< 7.0
< 10.0 1-131
< 0.3
<1.0 St-89
<OA
<5.0 St-90 N/A 1.710.6
<1.0 Low level of St-90 concentration in milk (1-5 pCi/L) is not unusual A4-1
l l
Table A-4.
In house " blank" samples.
Concentration pC1/L'.
Teledyne Results Acceptance Lab Sample Sample (4.66 Sigma)
Criteria Code Tvoe Date Analyses LLD Activitv*
(4.66 Sigma)
SPM 8877 MILK Aug 1990 1-131
< 0.2
< 1.0 SPW 8925 WATER Aug 1990 H3
< 200.0
< 300.0 SPW-8926 WATER Aug1990 Gr. Alpha
< 03
< 1.0 Gr. Beta
< 0.7
< 5.0 SPW-8927 WATER Aug 1990 U-234
< 0.01
< 1.0 U-235
< 0.02
< 1.0 l
< 0.01
< 1.0 SPW 8928 WATER Aug 1990 Co-58
< 4.1
< 10.0 Co-60
< 2.4
< 10.0 Cs-134
< 3.3
< 10.0 Cs-137
< 3.7
< 10.0 Mn-54
< 4.0
< 10.0 SPW-8929 WATER Aug 1990 Sr-89
< 1.4
< 5.0 Sr-90
< 0.6
< 1.0 1
SPW-69 WATER Sep 1990 St-89
<1.8
< 5.0 Sr-90
< 0.8
< 1.0 SPW-106 WATER Oct 1990 H-3
< 180.0
< 300.0 1131
<03
< 1.0 SPM-107 MILK Oct 1990 Cs-134
< 3.3
< 10.0 Cs-137
<4.3
< 10.0 1-131
< 0.4
< 1.0 SPW-370 WATER Oct 1990 Co-58
<2.6
< 10.0 Co-60
< 1.6
< 10.0 Cs 134
<1.7
< 10.0 Cs-137
< 1.8
< 10.0 A4-2
-,.y_,
,_w,,
,_.m
.,..-.....ww.,...._,,~,,,
,.w
...w
Table A-4.
In-house " blank" samples.
Concentration pCi/L*,
Teledyne Results Acceptance i
Lab Sample Sample (4.66 Sigma)
Criteria Code Tvoe Date Analyses LLD Activitv6 (4.66 Sigma)
< 1.7
< 10.J SPW-372 WATER Dec 1990 Gr. Alpha
< 0.3
< 1.0 Gr. Beta
< 0.8
< 5.0 SPM-406 MILK Jan 1991 Cs-134
<3.7
< 10.0 Cs-137
< 5.2
< 10.0 St-89
< 0.4
< 5.0 Sr-90 N/A 1.8 1 0.4
< 1.0 Low level of St-90 concentration in milk (1-5 pCi/L) is not unusual.
SPM-421 MILK Feb l991 1-131
< 0.3
< 1.0 SPM-451 MILK Feb l991 Ra 226
< 0.1
< 1.0 Ra-228
< 0.9
< 1.0 SPW-514 WATER Mar 1991 St-89
< 1.1
< 5.0 St-90
< 0.9
< 1.0 SPW-586 WATER Apr 1991 Co-60
< 2.5
< 10.0 Cs-134
< 2.4
< 10.0 Cs-137
< 2.2
< 10.0 1-131
<0.2
< 1.0 SPM-587 MILK Apr 1991 Cs-134
< 1.7
< 10.0 Cs-137
<1.9
< 10.0 I-131
< 0.2
<1.0 SPW-837 WATER Jun1991 Gr. Alpha
< 0.6
< 1.0 Gr. Beta
<1.1
< 5.0 SPM-953 MILK Jul1991 Cs-137
<4.9
< 10.0 I-131
< 0.2
<1.0 Sr-89
< 0.7
< 5.0 A4-3
i Table A-4.
In-house 'tlank" samples.
j Concentration pCi/L*,
Lab Sample Sample Teledyne Results 3
Code Tvoe Date Analyses (4.66 Sigma)
Acceptance
~~
Criteria LLD Activity *
~(4.66 Sigma)
Sr-90 N/A 0.4 i 0.3 Low level of Sr-90 concentra tion in milk (1-5 pCi/L) is not
<1.0 unusual.
SPM-1236 MILK Oct 1991 Cs-134
<3.7 Cs-137
< 10.0
<4.6 I-131
< 10.0
<0.2 SPW-1254 WATER Oct 1991
<1.0 Sr-89
< 2.8 Sr-90
<5.0
< 0.7 SPW-1256 WATER Oct 1991
< 1.0 Co-60
< 3.6 Cs-134
< 10.0
< 4.0 Cs-137
< 10.0
< 3.0 I-131
< 10.0
< 0.4 -
SPW-1259 WATER Oct 1991
< 1.0 H-3
< 160.0 SPW-1444 WATER Dec 1991
< 300.0 Gr. Alpha
<0.4 Cr. Beta
<1.0
<0.8 SPM-1578 MILK Jan 1992
< s.0 Cs-134
< 7.2 Cs-137
< 10.0
<8.0 I-131
< 10.0
<0.2 Sr-89
< 1.0
< 0.5 Sr-90
<5.0 N/A 1.3 i 0.4 Low level of Sr 90 concentration in milk (15 pCi/L) is not
< 1.0 unusual.
SPW-1860 WATER Mar 1992 Sr-89
< 0.6 Sr-90
<S.0
<0.4 SPW-2067 WATER Apr 1992
< 1.0 H-3
< 168.0 SPW-2114 WATER Apr 1992
< 300.0 C-14
< 1.0
< 200.0 A4-4
Table A-4.
In-house " blank" samples.
Concentration pCi/L'.
Teledyne Results Acceptance Lab Sample Sample (4.66 Sigma)
Criteria Code Type Date Analyses LLD Activitv*
(4.66 Sigma)
SPM-2119 MILK Apr 1992 Co-60
<6.3
< 10.0 Cs-134
<4.5
< 10.0 Cs-137
<5.4
< 10.0 SPW-2126 WATER Apr 1992 1131
<0.2
< 1.0 SPM-2133 MILK Apr 1992 1131
<0.2
< 1.0 SPW-2220 WATER May 1992 Co40
<2.1
< 10.0 Cs-134
< 2.1
< 10.0 Cs-137
<2.3
< 10.0 SPW-2369 WATER Jun1992 Gr. Alpha
< 0.4
< 1.0 Gr. Beta
<0.8
< 5.0 SPM-2500 MILK Aug 1992 1131
< 0.4
< 1.0 Sr-89
<1.2
< 5.0 St-90
< 0.9
< 1.0 SPW-2666 WATER Sep 1992 Sr-89
<0.8
< 5.0 St-90
<0.5
< 1.0 SPW-2828 WATER Oct 1992 Cof4
<4.8
< 10.0 Activity result is not available for this sample.
Cs-134
<6.0
< 10.0 Activity result is not available for this sample.
<6.1
< 10.0 Activity result is not available for this sample.
< 177.0
< 300.0 1-131
<0.3
< 1.0 Activity result is not available for this sample.
SPM-2829 MILK Oct 1992 Co40
<9.3
< 10.0 Cs-134
<6.4
< 10.0 Cs-137
<7.2
< 10.0 A4-5
Table A-4.
In-house " blank" samples.
Concentration pCi/L*.
Teledyne Results Acceptance Lab Sample Sample (4.66 Sigma)
Criteria Code Tvr>e Date Analyses LLD Activitv*
(4.66 Sigma)
SPW-3212 WATER Oct 1992 Ra-228
< 1.0
< 1.0 SPW-3057 WATER Nov 1992 l
<0.03
< 1.0 SPW-3294 WATER Dec 1992 Gr. Alpha
< 0.4
< 1.0 Gr. Beta
< 0.8
< 5.0 SPM-3342 MILK Jan 1993 Cs-134
< 4.1
-0.912.6
< 10.0 Activity result is not available for tids sample.
<3.9 0.812.2
< 10.0 Activity result is not available.for this sample.
Sr-89
< 0.7
-0.9 i 1.1
< 5.0 Sr-90 N/A 1.6 1 0.5
< 1.0 Tew levels of St 90 concentration in milk (1-5 pCi/L)is not unusual SPM-3386 MILK Feb 1993 I131
< 0.2 0.1 i 0.1
< 1.0 SPW-3557 WATER Mar 1993 St-89
<0.5 0.310.5
< 5.0 1
St-90
< 0.5 0.110.2
< 1.0 SPW-3598 WATER Apr 1993 H-3
< 180.0 84.7 i 94.2
< 300.0 SPW-3600 WATER Apr 1993 l
1131
< 0.2 0.110.2
< 1.0 SPW-3601 WATER Apr 1993 Co40
< 4.2
< 10.0 Activity result is not available for this sample.
Cs-134
< 4.4
< 10.0 Activity result is not available'for this sample.
<3.4
< 10.0 Activity result is not available for this sample.
1-131
< 0.4 0.3 1 0.9
< 1.0 SPM-3651 MILK May 1993 Cs-134
<4.4
< 10.0 Activity result is not available for this sample.
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Table A-4.
In house " blank" samples.
~
Concentration pCi/L*,
Teledyne Results Acceptance Lab Sample Sample (4.66 Sigma)
Criteria Code Tvoe Date Analyses LLD Activitvb (4.66 Sigma) -'
< 6.3
< 10.0 Activity result is not available for this sample.
1-131
<0.2 0.1 i 0.1
< 1.0 SPFP-3680 FOOD May 1993 Cs-137
< 6.5 0.0 i 0.0
< 10.0 SPW-3844 WATER Jun 1993 Th-228
< 0.1 0.0 i 0.1
<1.0 Th-230
< 0.1 0.2 1 0.1
<1.0 Th-232
< 0.1 0.0 i 0.0 s 1.0 SPW-4234 WATER Jun1993 Gr. Alpha
< 0.3 0.0 i 0.2
< 1.0 Gr. Beta
< 0.8 0.2 i 0.3
< i.0 SPS-4059 SEDIMENT Jul1993 (BOTTOM)
Cs-134
< 5.0 0.010.0
< 10.0 Cs-137
< 7.2 0.010.0
< 10.0 SPVE-4060 VEGETATION Jul1993 (SAW DUST)
Cs-134
<4.8 0.0 i 0.0
< 10.0 Cs-137
< 6.4 0.0 i 0.0
< 10.0 SPM-4061 MILK Jul1993 Cs-134
< 8.6 0.0 1 0.0
,: 10.0 Cs-137
< 5.8 0.0 i 0.0
< 10.0 SPM-4062 MILK Jul1993 Cs-134
<3.8 1.5 1 1.5
< 10.0 Cs-137
< 4.4
-1.6 i 3.3
< 10.0 SPW-4063 WATER Jul 1993 Co-60
<4.0 1.2 1 2.3
< 10.0 Cs-134
<3.7 0.311.2
< 10.0 Cs-137
<3.2 0.4 i 3.2
< 10.0 SPAP-4064 AIR FILTER Jul1993 (COMPOSITE)
Cs-134
< 2.1 0.0 1 0.0
< 10.0 Cs-137
<2.8 0.0 i 0.0
< 10.0 A4-7
Table A-4.
In-hodse " blank" samples.
Concentration pCi/L*.
Teledyne Results Acceptance lab Sample Sample (4.66 Sigma)
Criteria Code Tvoe Date Analyses LLD Activitv6 (4.66 Sigma)
SPCH-406 CHARCOAL Jul1993 I131
< 0.1 0.0 1 0.0
< 1.0 Based on a volume of 300 m8 SPW-4233 WATER Aug 1993 Fe-55
< 506.0 0.0 1 0.3
< 1000.0 SPM-4235 MILK Aug 1993 Cs-134
< 8.1 '
1.6 i 1.8
< 10.0 Cs-137
< 4.2
-1.7 1 3.4
< 10.0 I-131
< 0.1 0.010.2
< 1.0 Sr-89
< 0.8
-1.0 i l.1
< 5.0 Sr90 N/A 1.8 1 0.5
< 1.0 Low !cvel of Sr-90 concentration in milk (1-5 pCi/L) is not unusual.
SPW-4241 WATER Aug 1993 H-3
< 190.0 72.9 i 99.1
< 300.0 SPW-4243 WATER Aug 1993 Co-60
< 7.0 0.4 i3.1
< 10.0 Cs-134
< 7.6 0.8 i 15.6
< 10.0 Cs-137
< 5.4
-0.7 i 4.2
< 10.0 1-131
< 0.5 0.0 i 0.1
< 1.0 Sr-89
< 1.1
-0.610.9
< 5.0 Sr-90
< 0.7 0.4 i 0.4
< 1.0 SPW-4244 WATER Aug 1993 Pu-238
< 1.0 0.4 i 0.7
< 1.0 Pu-239/240
< 0.3 0.1 i 0.2
< 1.0 Th-228
< 0.4
-0.1 1 0.3
< 1.0 Th-230
< 0.1 0.010.1
< 1.0 Th-232
< 0.1 0.0 1 0.0
< 1.0 U-233/234
< 0.1 0.1 1 0.1
< 1.0 U-235
< 0.1 0.0 1 0.1
< 1.0 U-238
< 0.1 0.110.1
< 1.0 SPW-4245 WATER Aug 1993 Ra-226
< 0.1 0.0 1 0.0
< 1.0 Ra-228
< 0.8
-0.2 i 0.5
< 1.0 SPW-4422 WATER Oct 1993 H3
< 180.0
-27.5 i 88.9
< 300.0 A4-8
Table A-4.
In-house " blank" samples.
Concentration pCi/L*.
Teledyne Results Acceptance Lab Sample Sample (4.66 Sigma)
Criteria Code Type Date Analyses LLD Activitv*
(4.66 Sigma)
' All results are in pCi/L, except for air filter samples, which are in pCi/ Filter.
- Prior to 1993, results where reported as only an LLD, the activity reported is the net activity result.
A4-9
- - _ _ _ =
December,1993 ATTACHMENT A ACCEPTANCE CRITERIA FOR " SPIKED" SAMPLES LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSES' One Standard Deviation Analysis Level for single determinations 1
Gamma Emitters 5 to 100 pCi/ liter or kg 5.0 pCi/ liter l
>100 pCi/ liter or kg 5% of known value l
6 Strontium-89 5 to 50 pCi/ liter or kg 5.0 pCi/ liter
>50 pCi/ liter or kg 10% of known value Strontium-90 2 to 30 pCi/ liter or kg 5.0 pCi/ liter b
i
>30 pCi/ liter or kg 10% of known value Potassium
>0.1 g/ liter or kg 5% of known value Cross alpha s20 pCi/ liter 5.0 pCi/ liter
>20 pCi/ liter 25% of known value Gross beta s100 pCi/ liter 5.0 pCi/ liter
>100 pCi/.' iter 5% of known value Tritium
$4,000 pCi/! iter is = (pCi/ liter) =
169.85 x (known)'"
>4,000 pCi/ liter 10% of known value Radium-226< 228
<0.1 pCi/ liter 15% of known value Plutonium 0.1 pCi/ liter, gram, or sample 10% of known value Iodine-131, s55 pCi/ liter 6.0 pCi/ liter Iodine-129
>55 pCi/ liter 10% of known value 6
Uranium-238, s35 pCi/ liter 6.0 pCi/ liter
>35 pCi/ liter 15% of known value Nickel-646 Technetium-996 Iron-55, 50 to 100 pCi/ liter 10 pCi/ liter
>100 pCi/ liter 10% of known value Others*
20% of h vb
- From EPA publication, " Environmental Radioactivity Laboratory Intercomparison Studies Program, Fiscal Year, 1981 1982, EPA-600/4-81M.
Teledyne limit.
A2
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APPENDIX B DATA REPORTING CONVENTIONS B-1 l
Data Reoortine Conventions l
1.0 All activities except gross alpha and gross beta are decay corrected to collection time or the end of the collection period.
l 2.0 Sincie Meas.urements l
Each single measurement is reported as follows:
L xts where x = value of the measurement; s = 2a counting uncertainty (corresponding to the 95% confidence level).
In cases where the activity is found to be below the lower limit of detection L it is reported as I
<L
)
where L = the lower limit of detection based on 4.66a uncertainty for a background sample.
3.0 Duplicate analyses l
3.1 Individual results:
xi i si xi i S2 1
Reported result:
xis where x = (1/2) (x1 t x2) 2 2
i s = (1/2) s1 + s2 1
3.2 Individual results:
<L1
<L2 Reported result:.
<L where L = lower of L1 and L2 3.3 Individual results:
xis
<L Reported result:
x i s if x 2 L;
<L otherwise B-2
4.0.
Comoutation of Averaces and Standard Deviations 4.1 Averages and standard deviations listed in the tables are computed from all of the individual measurements over the period averaged; for example, an annual standard deviation would not be the average of quarterly standard deviations. The average i and standard deviation (s) are defined as follow:,
of a set of n numbers x1, x2
.xn 1
i = - E, x
- E(R - x,)2 s=
n-1 4.2 Values below the highest lower limit of detection are not included in the average.
4.3 If all of the values in the averaging group are less than the highest LLD, the highest LLD is reported.
4.4 If all but one of the values are less than the highest LLD, the single value x and associated two sigma error is reported.
i 4.5 In rounding off, the following rules are followed:
l 4.5.1. If the figure following those to be retained is less than 5, the figure is dropped, and the retained figures are kept unchanged.
As an example,.11.443 is rounded off to 11.44.
4.5.2. If the figure following those to be retained is greater than 5, the figure is dropped and the last retained figure is raised by 1. As an example,11.446 is rounded off to 11.45.
4.5.3. If the figure following those to be retained is 5, and if there are no figures other than zeros beyond the five, the figure five is dropped, and the last-place figure retained is increased by one if it is an odd number or it is kept unchanged if an even number.
As an example,11.435 is rounded off to 11.44, while 11.425 is rounded off to 11.42.
I B-3
5 APPENDIX C Maximum Permissible Concentrations of Radioactivity in Air and Water Above Background in Unrestricted Areas l
C-1
Table C-1.
Maximum permissible concentrations of radioactivity in air and water above a
natural background in unrestricted areas.
Air Water Gross alpha 3
pCi/m3 Strontium-89 3,000 pCi/L 3
Gross beta 100 pCi/m Strontium-90 300 pCi/L 3
Cesium-137 20,000 pCi/L Iodine-131b 0.14 pCi/m Barium-140 20,000 pCi/L
)
Iodine-131 300 pCi/L Potassium-40C 3,000 pCi/L i
Gross alpha 30 pCi/L Gross beta 100 pCi/L Tritium 3 x 106 pCi/L a Taken from Code of Federal Regulations Title 10, Part 20, Table II and appropriate footnotes. Concentrations may be averaged over a period not greater than one year.
b From 10 CFR 20 but adjusted by a factor of 700 to reduce the dose resulting from the air-grass <ow-milk-child pathway.
c A natural radionuclide, C-2
yy e
8 4
5 APPENDIX D
+
SUMMARY
OF THE LAND USE CENSUS 4
I D-1 l
l l
l I
l L
SUMMARY
OF 1993 LAND USE CENSUS The annual Land Use Census for DAEC was completed on August 6, 1993.
All milk animals and gardens greater than 500 square feet were identified within three miles for each of 16 sectors.
Within five miles, the nearest resident, milk animal and garden in each sector were identified.
Additionally, on September 25, 1993 the Cedar River was inspected for water use downstream of DAEC to Cedar Rapids.
There were no new uses of water.
Gardening activity was subdued this year due to heavy rains in the spring and summer.
A total of 15 new homes were built or under construction since the last census.
Most of the new homes were built in the sectors toward Cedar Rapids (SSE, SE and ESE) where increased building rates have been noted in previous land use census.
Three new homes were noted in the town of Palo (S and SSW) and four were noted near Pleasant Creek (WNW).
No changes in the DAEC Radiological Environmental Monitoring Program are recommended based on the Land Use Census.
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1 ANNUAL RADIATION DOSE ASSESSMENT i
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ANNUAL RADIATION DOSE ASSESSMENT The annual offsite radiation dose to a member of the public was determined by assessment of environmental dosimeter results and by calculations based on monitored effluent releases.
SECTION A.
DOSE CONTRIBUTION FROM DIRECT RADIATION Direct radiation dose from the operation of DAEC was recorded by TLDs placed at locations in the surrounding environment as described in the Offsite Dose Assessment Manual (ODAM) 1.
Pre-operational and 1993 TLD results were compared using a paired difference test.
No difference in the TLD populations were observed at 0.5 and 1 mile using a confidence level of 99%.
2.
As stated in Part 1, page 8 of this report, no plant effect was indicated by the TLDs when dose results were compared to the estimated average natural background for Middle America.
SECTION B.
ESTIMATED OFFSITE DOSE FROM EFFLUENT RELEASES The contribution of dose to a member of the public most likely to be exposed f_om effluent releases was calculated by the Meteorological Information and Dose Assessment Systems (MIDAS) computer program in accordance with the ODAM.
The calculation methods follow those prescribed by Reg Guide 1.109.
Results of these calculations are discussed below and shown in tabular form on Page E-4:
1.
There were no releases of radioactive material to liquid effluents in 1993.
2.
The dose to air from noble gases released was 5.25E-3 mrad from gamma radiation at the West site boundary and 6.73E-3 mrad from beta radiation at the West site boundary.
3.
The total body dose equivalent to the maximally exposed individual from noble gases was 2.70E-3 mrem, at 805 meters t
West.
4.
The skin dose equivalent to the maximally exposed individual from noble gases was 6.73E-3 mrem, at 805 meters West.
5.
The maximally exposed organ due to iodines and particulates with half-lives greater than eight days was the skin of a child at 805 meters West, with an estimated dose equivalent of 1.08E-2 mrem.
E-2
CONCLUSION:
No measurable dose due to operation of DAEC Eas detecteck by environmental TLDs in 1993.
The calculated doses are below the regulatory limits stated in Appendix I to 10 CFR 50 and in 40 CFR l
190.
i, 4
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E-3
b ESTIMATED MAXIMUM OFFSITE INDIVIDUAL DOSES FOR 1993 TYPE AGE DISTANCE DOSE OR DOSE ANNUAL 10CFR50, GROUP (meters)
DIRECTION EQUIVALENT APPENDIX I LIMIT NONE DIRECTION RADIATION (as measured by TLDs)
NONE 3 MREM TOTAL BODY LIQUIDS RELEASES 10 MREM ANY ORGAN NOBLE GAS GAMMA AIR DOSE 668 W
5.25E-3 MRAD 10 MRAD BETA AIR DOSE 668 W
6.73E-3 MRAD 20 MRAD TOTAL BODY ALL 805 W
2.70E-3 MREM SKIN ALL 805 W
6.73E-3 MREM PARTICULATES & IODINES ORGAN DOSE CHILD-805 W
1.08E-2 MREM 15 MREM SKIN
- NO APPENDIX I LIMIT BUT IS USED TO DETERMINE COMPLIANCE WITH 40 CFR 190 LIMITS OF 25 MREM TOTAL BODY AND 75 MREM THYROID.
t E-4 i
'MTELEDYNE ISOTOPES M.1DWEST LABORATORY 700 LANDWEHR ROAD NOR111 BROOK. ILLINOIS MX162-2310 (708) 564 4700
- F AX ("'ON) Se44517 REPORT TO j
IOWA ELECTRIC LIGHT AND POWER CEDAR RAPIDS, IOWA RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP)
FOR THE DUANE ARNOLD ENERGY CENTER l
CEDAR RAPIDS, IOWA Docket No. 50-331 ANNUAL REPORT - PART II DATA TABULATIONS AND ANALYSES j
JANUARY - DECEMBER 1993 FOR SUBMITTAL TO THE NUCLEAR REGULATORY COMMISSION PREPARED AND SUBMITTED BY TELEDYNE ISOTOPES MIDWEST LABORATORY PROJECT NO. 8001 l/$
/
Approved by' Ju/L
' /I. G. Huebner
' General Manager 22 April 1994
TABLE OF CONTENTS Section pagg List of Tables...........
...iii
1.0 INTRODUCTION
...1 2.0 LISTING OF MISSED SAMPLES.
.....2 3.0 DATA TABLES......
....3 i
l l
l l
ii t
LIST OF TABLES N2 Title Pace 1
Airborne particulates collected at Location D-1, (Cedar Rapids),
analysis for gross beta
.....4 2
Airborne particulates and iodine collected at Location D-2 (Marion),
analysis for gross beta and iodine-131........
...5 3
Airborne particulates collected at Location D-3 (Hiawatha), analysis for gross beta..
.6 4
Airborne particulates and iodine collected at Location D-5 (Palo),
analysis for gross beta and iodine-131...
... 7 5
Airborne particulates collected at Location D-6 (Center Point),
analysis for gross beta
.........8 6
Airborne particulates and iodine collected at Location D-7, (Shellsburg), analysis for gross beta and iodine-131.................. 9 7
Airborne particulates and iodine collected at Location D-8 (Urbana),
analysis for gross beta and iodine-131..
.10 8
Airborne particulates collected at Location D-10 (Atkins), analysis for gross beta....
.....11 9
Airborne particulates and iodine collected at Location D-11 (Toddville), analysis for gross beta and iodine-131.
..........12 10 Airborne particulates collected at Location D-13 (Alburnett),
analysis for gross beta................
..13 11 Airborne particulates and iodine collected at Location D-15 (on-site, north), analysis for gross beta and iodine-131..............
....14 12 Airborne particulates collected at Location D-16 (on-site, south),
analysis for gross beta...
..............................15 13 Airborne particulate samples, quarterly composites of weekly samples, analysis for gamma-emitting isotopes.....
......... 16 14 Ambient gamma radiation (TLD), quarterly exposure....................... 22 15 Milk samples, analysis for iodine-131 and gamma emitting isotopes........ 24 16 Ground water samples, analysis for gross beta and tritium........
......28 17 Vegetation samples (broadleaf), analysis for iodine-131 and gamma-emitting isotopes......
..............30 l
iii l
d 1
' LIST OF TABLES (continued) i Na Iitle.
Page j
18 Vegetation samples (hay and grain), analysis for gamma-emitting i
isotopes.....................................................
.31 19 Surface water samples, analysis for iodine-131 and gamma-emitting isotopes........
....... 3 3 20 Surface water samples, quarterly composites of monthly samples, analysis for tritium......................................
....... 3 8 J
21 Fish samples, analysis for gamma-emitting isotopes.....
......................39 i
22 River sediment samples, analysis for gamma-emitting isotopes................ 40 23 Precipitation samples, analysis for gamma-emitting isotopes.............. 41 24 Precipitation samples, quarterly composites of monthly samples, analysis for tritium.......
...42 j
25 Meat samples, analysis for gamma-emitting isotopes..........
....... 4 3 26 Soil samples, analysis for strontium-90 and gamma-emitting i s o t o p es..........................................
............44 t
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Y
1.0 INTRODUCTION
The following constitutes a supplement to the Annual Report for the Radiological Environmental Monitoring Program conducted at the Duane Arnold Energy Center, Cedar Rapids, Iowa in 1993. Results of completed analyses are presented in the attached tables.
For information regarding sampling locations, type and frequency of collection, and sample codes, please see Tables 5.3 - 5.5 and Figures 5.1 and 5.2 of Part I.
1
~
)
l 2.0 LISTING OF MISSED SAMPLES Expected Collection Sample Type Location Date Reason Milk D-93 01-05-93 Sample not available.
J Milk D-101 01-05-93 Sample not available.
Milk D-93 02-03-93 Sample not available.
Milk D-101 02-06-93 Sample not available.
Milk D-101 03-02-93 Sample not available.
Milk D-101 04-06-93 Sample not available.
Milk D-101 05-04-93 Sample not available.
j River All January -June,1993 Flooding and high water Sediment Fish All January -July,1993 Flooding and high water AP/AI D-11 07-15-93 No power to the sampler, AP/AI All 08-19-93 Samples lost in shipment.
Milk D-93 12-07-93 Sample not available.
Milk D-101 12-07-93 Sample not available.
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3.0 DATA TABLES l
l 3
DUANE ARNOLD' Table 1.-
Airborne particulates Analyses:
Gross beta Location:
D-1 (Cedar Rapids) 3 Units:
pCi/m Collection:
Continuous, weekly exchange.
~
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
M 8
0.048 t 0.004 07-08-93 286 0.015 0.003 01-07-93 332 01-14-93 290 0.040 0.004 07-15-93 284-0.016 0.003 01-21-93 3348 0.038 0.004 07-22-93 284 0.016 0.003 b
0.026 i 0.004 07-30-93 329a 0.015 0.003 01-28-93 250 02-05-93 290a 0.031 0.004 08-05-93 243b 0.016 i 0.003 02-11-93 286b 0.029 0.002 08-12-93 284 0.015 i 0.003 02-18-93 285 0.034 0.004 08-19-93 NDC
)
02-25-93 285 0.042 t 0.003 08-26-93 285 0.020 0.003 03-04-93 287 0.040 i 0.004 09-02-93 286 0.020 0.003 03-11-93 284 0.022 i 0.003 09-10-93 326a 0.017 0.003 b
03-17-93 245a 0.023 i 0.004 09-16-93 243 0.020 i 0.003 i
b 0.020 i 0.003 09-23-93 286 0.014 i 0.003 03-25-93 327 04-01-93 285 0.014 0.003 09-30-93 285 0.016 0.003 1st Qtr. Meanis.d.
0.0311 0.010 3rd Qtr. Mean s.d.
0.017 0.002 04-08-93 285 0.015 i 0.003 10-07-93 286 0.017 0.003 04-15-93 286 0.012 0.003 10-14-93 286 0.029 i 0.004 04-22-93 284 0.018 i 0.003 10-21-93 285 0.033 i 0.004 04-29-93 286 0.021 0.003 10-28-93 286 0.012 i 0.003 05-06-93 285 0.015 1 0.003 11-04-93 286 0.013 0.003 05-13-93 286 0.019 0.003 11-11-93 286 0.026 i 0.003-05-20-93 285 0.016 i 0.003 11-18-93 287 0.029 i 0.004 05-27-93 287 0.017 i 0.003 11-24-93 245b 0.029 i 0.004 06-03-93
'283 0.012 i 0.003 12-02-93 3278 0.039 i 0.004 06-10-93 287 0.013 0.003 12-09-93 285 0.032 i 0.004 06-17-93 280 0.020 t 0.002 12-16-93 285 0.031 i 0.004 b
06-24-93 291 0.019 i 0.003 12-22-93 245 0.029 i 0.004 07-01-93 286 0.015 i 0.003 12-30-93 328a 0 031 1 0.003 2nd Qtr. Meanis.d.
0.016 i 0.003" 4th Qtr. Meanis.d.
0.027 1 0.008 Cumulative Average:
0.023 Previous Annual Average:
0.022
" Eight-day collection.
Six-day collection.
C ND - No Data; sample lost in shipment.
4
.__. _ _ _. _. ~,_. _
l t
i DUANE ARNOLD l
Table 2.
Airborne particulates and charcoal canisters Analyses:
Gross beta and iodine-131 a Location:
D-2 (Marion)
Units:
pCi/n@
Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta l
(
Recuired LLD E
E b
01-07-93 342 0.046 0.004 07-08-93 286 0.018 i 0.003 01-14-93 302 0.035 0.004 07-15-93 285 0.013 0.003 b
0.030 0.003 07-22-93 284 0.016 0.003 01-22-93 349 l
01-28-93 257C 0.024 i 0.004 07-30-93 331b 0.017 0.003 b
0.028 i 0.004 08-05-93 241c 0.014 0.003 02-05-93 285 02-11-93 284C 0.031 i 0.002 08-12-93 286 0.014 0.003 l
02-18-93 286 0.035 i 0.004 08-19-93 NDd 02-25-93 286 0.037 0.003 08-26-93 286 0.020 0.003 03-04-93 288 0.037 t 0.004 09-02-93 286 0.017 0.003 03-11-93 283 0.025 i 0.003 09-10-93 328b 0.017 i 0.003 03-17-93 246C 0.022 1 0.004 09-16-93 242C 0.017 t 0.003 03-25-93 325b 0.016 i 0.003 09-23-93 286 0.016 1 0.003 04-01-93 286 0.014 i 0.003 09-30-93 285 0.013 0.003 l
l 1st Qtr. Meanis.d.
0.0291 0.009 3rd Qtr. Meanis.d.
0.016 1 0.002 04-08-93 286 0.012 i 0.003 10-07-93 287 0.024 i 0.003 04-15-93 285 0.016 0.003 10-14-93 285 0.027 i 0.004 i
04-22-93 284 0.019 t 0.003 10-21-93 286 0.035 0.004 04-29-93 286 0.024 i 0.003 10-28-93 285 0.022 i 0.004 l
05-06-93 285
' O.014 i 0.003 11-04-93 287 0.017 t 0.003 l
05-13-93 286 0.020 0.003 11-11-93 296 0.027 i 0.003 05-20-93 284 0.016 i 0.003 11-18-93 284 0.032 0.004 l
05-27-93 288 0.014 i 0.003 11-24-93 244c 0.030 0.004 b
l 06-03-93 284 0.012 i 0.003 12-02-93 327 0.051 i 0.004 06-10-93 286 0.015 1 0.003 12-09-93 285 0.034 i 0.004 06-17-93 281 0.020 i 0.002 12-16-93 286 0.026 i 0.004 06-24-93 290 0.018 i 0.003 12-22-93 244C 0.022 i 0.004 b
0.030 i 0.003 l
07-01-93 286 0.015 i 0.003 12-30-93 328 2nd Qtr. Meants.d.
0.017 0.003 4th Qtr. Meanis.d.
0.029 1 0.008 Cumulative Average:
0.023 Previous Annual Average:
0.022
^ Iodine-131 concentrations are <0.07 pCi/m'unless otherwise noted.
b Eight-day collection.
C Six-day collection.
d ND - No Data; sample lost in shipment.
I 5
1
4 DUANE ARNOLD.
Table 3.
Airborne particulates Analyses:
Gross beta Location:
D-3 (Hiawatha)
Units:
3 pCi/m Collection:
Continuous, weeldy exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta l
l Reauired LLD 0_f.1 1.0.1 01-07-93 325a 0.049 0.004 07-08-93 285 0.020 i 0.003 01-14-93 290 0.033 0.004 07-15-93 285 0.015 0.003 01-22-93 322a 0.037 0.004 07-22-93 284 0.014 i 0.003 i
01-28-93 344b 0.033 t 0.004 07-30-93 332a 0.014 t 0.003 02-05-93 285a 0.035 0.004 08-05-93 241 D 0.015 i 0.003
{
02-11-93 284b 0.030 i 0.002 08-12-93 285 0.013 0.003 02-18-93 286 0.038 i 0.004 08-19-93 NDc l
02-25-93 286 0.042 t 0.003 08-26-93 286 0.016 i 0.003 03-04-93 288 0.034 0.004 09-02-93 286 0.016 i 0.003 I
03-11-93 283 0.022 i 0.003 09-10-93 326a 0.017 0.003 b
l 03-17-93 246b 0.018 i 0.004 09-16-93 244 0.015 i 0.003 03-25-93 325a 0.017 i 0.003 09-23-93 285 0.017 i 0.003 04-01-93 287 0.014 i 0.003 09-30-93 285 0.012 i 0.003 1st Qtr. Meants.d.
0.0311 0.010 3rd Qtr. Meanis.d.
0.015 i 0.002 04-08-93 285 0.014 i 0.003 10-07-93 287 0.024 i 0.003 04-15-93 285 0.013 i 0.003 10-14-93 285 0.031 i 0.004 04-22-93 284 0.016 i 0.003 10-21-93 286 0.029 i 0.004 i
04-29-93 286 0.024 0.003 10-28-93.
285 0.023 0.004 05-06-93 285 0.013 t 0.003 11-04-93 287 0.015 0.003 05-13-93 286 0.017 i 0.003 11-11-93 286 0.029 i 0.004 l
05-20-93 284 0.018 i 0.003 11-18-93 285 0.030 0.004 05-27-93 286 0.018 i 0.003 11-24-93 244D 0.032 i 0.004 06-03-93 284 0.010 i 0.003 12-02-93 326a 0.045 0.004 06-10-93 286 0.012 0.003 12-09-93 286 0.032 i 0.004 06-17-93 281 0.016 i 0.002 12-16-93 286 0.030 i 0.004 D
0.021 i 0.004 06-24-93 290 0.021 0.003 12-22-93 244 07-01-93 286 0.015 0.003 12-30-93 328a 0.031 0.003 2nd Qtr. Meanis.d.
0.016 1 0.004 4th Qtr. Meanis.d.
0.029 1 0.007 Cumulative Average:
0.023 Previous Annual Average:
0.024 a Eight-day collection.
Six-day collection.
C ND - No Data; sample lost in shipment.
6 l
i DUANE. ARNOLD Table 4.
Airborne particulates and charcoal canisters Analyses:
Gross beta and iodine-131 a Location:
D-5 (Palo)
Units:
pCi/n@
l Collection:
Continuous, weekly exchange.
i Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
E b
0.047 i 0.004 07-08-93 284 0.017 0.003 01-07-93 326 01-14-93 285 0.035 t 0.004 07-15-93 285 0.013 0.003 01-22-93 326b 0.030 0.003 07-22-93 284 0.011 t 0.003 01-28-93 244c 0.026 i 0.004 07-30-93 329b 0.016 i 0.003 b
0.026 i 0.004 08-05-93 239c 0.015 i 0.003 02-05-93 286 02-11-93 285C 0.029 i 0.002 08-12-93 286 0.012 0.003 02-18-93 285 0.036 0.004 08-19-93 NDd 02-25-93 286 0.038 t 0.003 08-26-93 286 0.016 0.003 03-04-93 287 0.042 i 0.004 09-02-93 286 0.016 i 0.003 l
03-11-93 283 0.024 t 0.003 09-10-93 326b 0.019 0.003 03-17-93 245C 0.021 0.004 09-16-93 245c 0.015 i 0.003 b
0.018 i 0.003 09-23-93 286 0.016 i 0.003 03-25-93 326 04-01-93 286 0.014 i 0.003 09-30-93 285 0.015 i 0.003 l
Ist Qtr. Meanis.d.
0.030i 0.009 3rd Qtr. Meanis.d.
0.015 1 0.002 04-08-93 283 0.010 i 0.003 10-07-93 285 0.022 i 0.004 04-15-93 285 0.012 t 0.003 10-14-93 288 0.028 i 0.004 04-22-93 286 0.015 i 0.003 10-21-93 285 0.037 0.004 04-29-93 285 0.021 0.003 10-28-93 284 0.024 t 0.004 05-06-93 285 0.011 0.003 11-04-93 288 0.016 0.003 j
05-13-93 285 0.018 t 0.003 11-11-93 286 0.028 t 0.004 i
05-20-93 285 0.014 i 0.003 11-18-93 285C 0.032 i 0.004 05-27-93 286 0.016 i 0.003 11-24-93 244 0.033 0.004 06-03-93 284 0.010 t 0.003 12-02-93 327b 0.048 i 0.004 06-10-93 286 0.012 t 0.003 12-09-93 NDe 06-17-93 283 0.011 i 0.002 12-16-93 286 0.029 i 0.004 06-24-93 288 0.018 i 0.003 12-22-93 245c 0.023 0.004 07-01-93 287 0.012 i 0.003 12-30-93 327b 0.034 i 0.002 2nd Qtr. Meanis.d.
0.014 t 0.003 4th Qtr. Meanis.d.
0.030 t 0.008
(
Cumulative Average:
0.022 Previous Annual Average:
0.024
^ Iodine-131 concentrations are <0.07 pCi/m' unless otherwise noted.
b Eight-day collection.
C Six-day collection.
d ND - No Data; sample lost in shipment.
- ND - No Data; sample lost in collection.
7
. ~.
DUANE ARNOLD Table 5.
Airborne particulates Analyses:
Gross beta Location:
D-6 (Center Point) 3 Units:
pCi/m Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
E 01-07-93 326a 0.051 0.004 07-08-93 284 0.020 0.003 01-14-93 285 0.037 0.004 07-15-93 286 0.015 0.003 01-22-93 326^
0.033 i 0.004 07-22-93 284 0.016 0.003 01-28-93 244b 0.024 t 0.004 07-30-93 332a 0.016 i 0.003 02-05-93 2868 0.030 t 0.004 08-05-93 238b 0.014 i 0.003 02-11-93 284b 0.031 0.003 08-12-93 286 0.015 0.003 02-18-93 286 0.036 i 0.004 08-19-93 NDd 02-25-93 286 0.039 0.003 08-26-93 286 0.019 0.003 03-04-93 288 0.038 t 0.004 09-02-93 286 0.015 0.003 03-11-93 283 0.024 0.003 09-10-93 326a 0.018 i 0.003 03-17-93 245b 0.021 t 0.004 09-16-93 245b 0.015 i 0.003 03-25-93 326a 0.019 t 0.003 09-23-93 286 0.014 t 0.003 04-01-93 286 0.012 t 0.003 09-30-93 285 0.011 i 0.003 1st Qtr. Meants.d.
0.030 1 0.010 3rd Qtr. Meanis.d.
0.016 0.002 04-08-93 282 0.012 i 0.003 10-07-93 284 0.022 i 0.003 04-15-93 285 0.013 i 0.003 10-14-93 250 0.029 i 0.004 04-22-93 286 0.015 0.003 10-21-93 277 0.026 0.004 04-29-93 285 0.025 i 0.003 10-28-93 251 0.019 i 0.004 05-06-93 286 0.015 0.003 11-04-93 287 0.013 0.003 05-13-93 286 0.019 t 0.003 11-11-93 261 0.027 0.004 05-20-93 285 0.016 i 0.003 11-18-93 283 0.025 i 0.004 1
05-27-93 284 0.017 i 0.003 11-24-93 243b 0.027 i 0.004 06-03 93 284 0.014 i 0.003 12-02-93 326a 0.040 1 0.004 06-10-93 286 0.014 t 0.003 12-09-93 284 0.030 i 0.004 06-17-93 224c 0.021 i 0.003 12-16-93 285 0.026 i 0.004 b
06-24-93 288 0.021 t 0.003 12-22-93 245 0.024 i 0.004 07-01-93 287 0.015 i 0.003 12-30-93 328a 0.028 i 0.003 2nd Qtr. Meands.d.
0.017 1 0.004 4th Qtr. Meants.d.
0.026 1 0.006 Cumulative Average:
0.022 Previous Annual Average:
0.024
^ Eight-day collection.
Six-day collection, Low volume due to power shut off.
d ND - No Data; sample lost in shipment.
8
DUANE ARNOLD Table 6.
Airborne particulates and charcoal canisters Analyses:
Gross beta and iodine-131 8 Location:
D-7 (Shellsburg) 3 Units:
pCi/m Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
E b
0.049 i 0.004 07-08-93 284 0.019 i 0.003 01-07-93 326 01-14-93 285 0.036 0.003 07-15-93 285 0.013 0.003 01-22-93 330b 0.033 i 0.003 07-22-93 284 0.014 i 0.003 01-28-93 247c 0.020 0.004 07-30-93 329b 0.013 i 0.003 b
0.015 0.003 08-05-93 239C 0.016 i 0.003 02-05-93 289 02-11-93 287C 0.031 t 0.002 08-12-93 286 0.017 t 0.003 02-18-93 285 0.028 i 0.004 08-19-93 NDd 02-25-93 286 0.027 0.002 08-26-93 286 0.022 i 0.003 1
03-04-93 288 0.038 0.004 09-02-93 286 0.014 i 0.003 03-11-93 284 0.025 0.003 09-10-93 326b 0.016 0.003 03-17-93 246C 0.018 i 0.004 09-16-93 245C 0.013 1 0.003 03-25-93 326b 0.019 i 0.003 09-23-93 286 0.011 i 0.003 q
04-01-93 286 0.013 t 0.003 09-30-93 285 0.010 0.003 J
1st Qtr. Meants.d.
0.027 1 0.010 3rd Qtr. Mean s.d.
0.015 1 0.003 l
~
04-08-93 283 0.012 1 0.003 10-07-93 285 0.018 i 0.003 04-15-93 285 0.008 i 0.003 10-14-93 288 0.025 i 0.003 04-22-93 286 0.013 1 0.003 10-21-93 285 0.029 0.004 04-29-93 285 0.020 i 0.003 10-28-93 286 0.014 i 0.003 05-06-93 284 0.012 i 0.003 11-04-93 288 0.010 i 0.003 05-13-93 285 0.017 i 0.003 11-11-93 286 0.025 i 0.003 05-20-93 285 0.015 i 0.003 11-18-93 284 0.032 i 0.004 05-27-93 286 0.014 i 0.003 11-24-93 244C 0.029 i 0.004 06-03-93 284 0.007 i 0.002 12-02-93 327b 0.054 i 0.004 06-10-93 285 0.012 i 0.003 12-09-93 285 0.041 i 0.004 06 17-93 283 0.020 i 0.002 12-16-93 286 0.037 f 0.004 06-24-93 288 0.022 0.003 12-22-93 245C 0.028 i 0.004 07-01-93 287 0.014 i 0.003 12-30-93 327b 0.031 i 0.003 2nd Qtr. Meanis.d.
0.014 i 0.004 4th Qtr. Meanis.d.
0.029 i 0.011 Cumulative Average:
0.021 Previous Annual Average:
0.021
" Iodine-131 concentrations are <0.07 pCi/m unless otherwise noted.
3 b
Eight-day collection.
C Six-day collection.
d ND - No Data; sample lost in shipment.
9
DUANE JJRNOLD Table 7.
Airbbrne particulates and charcoal canisters Analyses:
Gass beta and iodine-131 8 Location:
D-8 (Urbana) 3 Units:
pCi/m Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD DE ILO1 b
0.048 0.004 07-08-93 284 0.020 0.003 01-07-93 326 01-14 93 285 0.037 t 0.004 07-15-93 286 0.013 1 0.003 b
0.034 i 0.004 07-22-93 284 0.014 i 0.003 01-22-93 326 d
01-28-93 244c 0.026 i 0.004 07-30-93 255 0.016 0.003 b
02-05-93 286 0.024 0.004 08-05-93 235C 0.013 t 0.003 02-11-93 284C 0.028 i 0.002 08-12-93 286 0.014 1 0.003 02-18-93 285 0.033 0.004 08-19-93 NDe 02-25-93 286 0.035 i 0.003 08-26-93 278 0.021 0.003 03-04-93 287 0.036 i 0.004 09-02-93 282 0.014 1 0.003 b
03-11-93 283 0.025 i 0.003 09-10-93 330 0.018 i 0.003 03-17-93 245C 0.021 i 0.004 09-16-93 245C 0.016 0.003 b
03-25-93 326 0.018 i 0.003 09-23-93 286 0.017 i 0.003 04-01-93 286 0.012 i 0.003 09-30-93 285 0.014 i 0.003 1st Qtr. Meanis.d.
0.029 1 0.009 3rd Qtr. Meanis.d.
0.016 1 0.003 04-08-93 283 0.008 i 0.003 10-07-93 285 0.021 0.003 04-15-93 285 0.014 0.003 10-14-93 288 0.024 0.003 04-22-93 286 0.018 i 0.003 10-21-93 285 0.036 t 0.004 04-29-93 285 0.024 i 0.003 10-28-93 284 0.021 i 0.003 05 06-93 286 0.013 i 0.003 11-04-93 288 0.016 i 0.003 05-13-93 286 0.015 0.003 11-11-93 286 0.027 0.004 05-20-93 285 0.017 i 0.003 11-18-93 284 0.025 i 0.004 05-27-93 286 0.016 i 0.003 11-24-93 244C 0.030 i 0.004 b
06-03-93 284 0.012 i 0.003 12-02-93 327 0.044 t 0.004 06-10-93 286 0.014 i 0.003 12-09-93 285 0.032 i 0.004 06-17-93 283 0.017 i 0.002 12-16-93 286 0.025 i 0.004 06-24-93 288 0.017 0.003 12-22-93 245C 0.019 i 0.004 b
07-01-93 284 0.014 i 0.003 12-30-93 327 0.029 t 0.003 1
2nd Qtr. Mean s.d.
0.015 1 0.004 4th Qtr. Meanis.d.
0.027 1 0.007 Cumulative Average:
0.022 Previous Annual Average:
0.023
" Iodine-131 concentrations are <0.07 pCi/m unless otherwise noted.
2 Eight-day collection.
Six-day collection.
d Low volume due to power shut off.
- ND - No Data; sample lost in shipment.
10
DUANE ARNOLD-Table 8.
Airborne particulates Analyses:
Gross beta Location:
D-10 (Atkins)
Units:
pCi/n@
Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
E 01-07-93 326a 0.052 0.004 07-08-93 286 0.018 i 0.003 01-14-93 285 0.035 t 0.004 07-15-93 284 0.018 i 0.003 01-22-93 314a 0.034 i 0.004 07-22-93 285 0.013 0.003 b
0.026 0.004 07-30-93 290 0.016 i 0.003 l
01-28-93 245 b
0.013 i 0.003 02-05-93 285a 0.025 i 0.004 08-05-93 242 b
0.027 1 0.002 08-12-93 283 0.015 t 0.003 l
02-11-93 286 l
02-18-93 286 0.037 0.004 08-19-93 NDc l
02-25-93 285 0.034 0.003 08-26-93 286 0.023 t 0.003 03-04-93 287 0.035 i 0.004 09-02-93 286 0.019 i 0.003 03-11-93 284 0.023 0.003 09-10-93 327a 0.016 i 0.003 b
b 0.020 i 0.004 09-16-93 244 0.018 i 0.003 03-17-93 245 03-25-93 327^
0.016 0.003 09-23-93 285 0.017 i 0.003 04-01-93 285 0.011
- 0.003 09-30-93 285 0.013 0.003 1st Qtr. Meanis.d.
0.029 1 0.010 3rd Qtr. Meanis.d.
0.017 1 0.003 04-08-93 285 0.009 i 0.003 10-07-93 285 0.021 i 0.003 04-15-93 286 0.011 i 0.003 10-14-93 287 0.027 i 0.004 04-22-93 284 0.016 1 0.003 10-21-93 286 0.032 0.004 04-29-93 285 0.022 i 0.003 10-28-93 285 0.020 i 0.003 05-06-93 286 0.014 i 0.003 11-04-93 287 0.013 i 0.003 05-13-93 286 0.020 i 0.003 11-11-93 286 0.028 0.004 05-20-93 285 0.015 i 0.003 11-18-93 285 0.028 i 0.004 05-27-93 287 0.017 0.003 11-24-93 245b 0.026 i 0.004 06-03-93 283 0.010 i 0.003 12-02-93 326a 0.044 i 0.004 06-10-93 287 0.013 t 0.003 12-09-93 287 0.033 i 0.004 06-17-93 280 0.019 i 0.002 12-16-93 284 0.029 i 0.004 06-24-93 291 0.018 0.003 12-22-93 244b 0.029 i 0.004 07-01-93 286 0.014 i 0.003 12-30-93 327a 0.030 i 0.003 2nd Qtr. Meanis.d.
0.015 1 0.004 4th Qtr. Meants.d.
0.028 i 0.007 Cumulative Average:
0.022 Previous Annual Average:
0.023 Eight-day collection.
b Six-day collection.
c ND - No Data; sample lost in shipment.
11
i DUANE ARNOLD 1
Table 9.
Airborne particulates and charcoal canisters Analyses:
Gross beta and iodine-131 a Location:
D-11 (Toddville)
Units:
pCi/d Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
E b
0.054 t 0.004 '
07-08-93 285 0.019 i 0.003 01-07-93 325 01-14-93 285 0.034 i 0.004 07-15-93 NDd 01-22-93 326b 0.038 0.004 07-22-93 240 0.016 i 0.003 01-28-93 245c 0.024 i 0.004 07-30-93 330b 0.012 i 0.003 b
0.027 i 0.004 08-05-93 240C 0.015 i 0.003 02-05-93 285 02-11-93 284c 0.029 0.002 08-12-93 285 0.013 0.003 02-18-93 286 0.034 i 0.004 08-19-93 NDe 02-25-93 286 0.035 t 0.003 08-26-93 286 0.019 i 0.003 03-04-93 288 0.036 0.004 09-02-93 286 0.015 i 0.003 03-11-93 283 0.026 t 0.003 09-10-93 326b 0.018 0.003 03-17-93 246c 0.022 i 0.004 09-16-93 244c 0.016 0.003 b
0.018 i 0.003 09-23-93 286 0.017 1 0.003 03-25-93 324 04-01-93 286 0.011 i 0.003 09-30-93 285 0.013 i 0.003 1st Qtr. Meants.d.
0.030 i 0.010 3rd Qtr. Meanis.d.
0.016 1 0.002 l
04-08-93 285 0.011 1 0.003 10-07-93 284 0.021 0.003 04-15-93 285 0.014 0.003 10-14-93 288 0.024 i 0.003 04-22-93 284 0.014 i 0.003 10-21-93 286 0.030 i 0.004 04-29-93 285 0.024 0.003 10-28-93 285 0.018 i 0.003 05-06-93 286 0.014 i 0.003 11-04-93 287 0.013 i 0.003 05-13-93 285 0.017 i 0.003 11-11-93 287 0.024 0.003 05-20-93 284 0.014 i 0.003 11-18-93 285 0.024 i 0.004 05-27-93 288 0.013 i 0.003 11-24-93 244c 0.026 i 0.004 06-03-93 284 0.010 i 0.003 12-02-93 327b 0.045 i 0.004 06-10-93 285 0.014 i 0.003 12-09-93 286 0.030 i 0.004 06-17-93 282 0.018 i 0.002 12-16-93 285 0.023 i 0.004 06-24-93 289 0.018 i 0.003 12-22-93 245c 0.023 i 0.004 4
b 0.030 i 0.003 07-01-93 286 0.014 i 0.003 12-30-93 327 2nd Qtr. Meants.d.
0.015 i 0.003 4th Qtr. Meanis.d.
0.025 1 0.007 Cumulative Average:
0.022 Previous Annual Average:
0.023
^ Iodine-131 concentrations are <0.07 pCi/m unless otherwise noted, 2
b Eight-day collection.
C Six-day collection.
d ND - No Data; no power to sampler.
' ND - No Data; sample lost in shipment.
12
,,t 4
m
DUANE ARNOLD.
Table 10. Airborne particulates Analyses:
Gross beta Location:
D-13 (Alburnett) 3 Units:
pCi/nr Collection:
Continuous, weekly exchange.
Date Volume Date Voltune Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD Dal 021 01-07-93 325a 0.048 0.004 07-08-93 284 0.019 i 0.003 01-14-93 285 0.038 0.004 07-15-93 286 0.012 0.003 01-22-93 326a 0.036 0.004 07-22-93 284 0.014 i 0.003 b
0.026 i 0.004 07-30-93 332a 0.014 i 0.003 01-28-93 244 b
02-05-93 286a 0.026 i 0.004 08-05-93 238 0.015 i 0.003 02-11-93 284b 0.032 i 0.003 08-12-93 286 0.013 i 0.003 02-18-93 285 0.034 0.004 08-19-93 NDC 02-25-93 286 0.035 i 0.003 08-26-93 286 0.017 0.003 03-04-93 288 0.037 i 0.004 09-02-93 286 0.015 i 0.003 03-11-93 283 0.024 i 0.003 09-10-93 326a 0.015 i 0.003 b
03-17-93 245b 0.021 0.004 09-16-93 245 0.016 i 0.003 03-25-93 326a 0.020 i 0.003 09-23-93 286 0.015 0.003 04-01-93 286 0.014 i 0.003 09-30-93 235 0.013 0.003 1st Qtr. Meants.d.
0.030 i 0.009 3rd Qtr. Mean s.d.
0.015 t 0.002 04-08-93 283 0.009 i 0.003 10-07-93 284 0.021 t 0.003 04-15-93 285 0.015 0.003 10-14-93 288 0.024 0.003 04-22-93 286 0.014 t 0.003 10-21-93 285 0.033 i 0.004 04-29-93 285 0.025 t 0.003 10-28-93 284 0.017 0.003 05-06-93 286 0.014 i 0.003 11-04-93 288 0.014 t 0.003 05-13-93 286 0.017 i 0.003 11-11-93 290 0.024 i 0.003 05-20-93 285 0.016 i 0.003 11-18-93 284 0.027 0.004 05-27-93 284 0.016 i 0.003 11-24-93 244b 0.031 i 0.004 06-03-93 284 0.011 0.003 12-02-93 327a 0.045 0.004 06-10-93 286 0.015 i 0.003 12-09-93 285 0.033 i 0.004 06-17-93 283 0.022 i 0.002 12-16-93 286 0.032 i 0.004 b
06-24-93 287 0.021 i 0.003 12-22-93 245 0.022 i 0.004 07-01-93 287 0.015 i 0.003 12-30-93 328a 0.027 i 0.003 2nd Qtr. Meants.d.
0.016 i 0.004 4th Qtr. Meanis.d.
0.027 i 0.008 g
Cumulative Average:
0.022 Previous Annual Average:
0.024 8 Eight-day collection.
Six-day collection.
C ND - No Data; sample lost in shipment.
13 l
i
DUANE ARNOLD' Table 11. Airborne particulates and charcoal canisters Analyses:
Gross beta and iodine-131 3 Location:
D-15 (On-site)
Units:
pCi/n@
Collection:
Continuous, weekly exchange.
~
Date Volume Date Volume Collected (m3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD E
E 01-07-93 325b 0.045 0.004 07-08-93 284 0.014 0.003 01-14-93 285 0.037 i 0.004 07-15-93 285 0.009 0.003 01-22-93 327b 0.037 0.004 07-22-93 284 0.011 t 0.003 b
0.010 0.002 01-28-93 244C 0.024 i 0.004 07-30-93 331 b
0.025 i 0.004 08-05-93 239 C 0.011 0.003 02-05-93 286 02-11-93 285C 0.027 1 0.002 08-12-93 285 0.012 0.003 02-18-93 285 0.028 t 0.004 08-19-93 NDd 02-25-93 286 0.030 1 0.003 08-26-93 286 0.015 0.003 03-04-93 288 0.037 0.004 09-02-93
'286 0.013 0.003 b
03-11-93 283 0.021 1 0.003 09-10-93 326 0.014 i 0.003 03-17-93 245C 0.020 i 0.004 09-16-93 245c 0.016 t 0.003 03-25-93 325b 0.017 0.003 09-23-93 285 0.012 i 0.003 04-01-93 286 0.012 i 0.003 09-30-93 285 0.012 0.003 1st Qtr. Meanis.d.
0.028 i 0.009 3rd Qtr. Meanis.d.
0.012 i o.002 04-08-93 283 0.010 i 0.003 10-07-93 167*
0.018 i 0.005 04-15-93 285 0.009 i 0.003 10-14-93 242 0.021 i 0.004 04-22-93 286 0.014 i 0.003 10-21-93 285 0.026 i 0.004 04-29-93 285 0.018 i 0.003 10-28-93 284 0.016 0.003 05-06-93 285 0.012 1 0.003 11-04-93 288 0.013 i 0.003 05-13-93 285 0.015 0.003 11-11-93 286 0.020
- 0.003 05-20-93 285 0.014 i 0.003 11-18-93 285 0.024 i 0.004 05-27-93 286 0.012 0.003 11-24-93 244C 0.028 0.004 b
0.036 i 0.003 06-03-93 284 0.007 i 0.002 12-02-93 327 06-10-93 280 0.011 i 0.003 12-09-93 285 0.031 i 0.004 06-17-93 283 0.013 i 0.002 12-16-93 286 0.024 i 0.004 06-24-93 288 0.015 i 0.003 12-22-93 244C 0.018 i 0.004 b
07-01-93 286 0.011 0.003 12-30-93 328 0.026 i 0.003 2nd Qtr. Meants.d.
0 012 1 0.003 4th Qtr. Meants.d.
0.023 1 0.006 Cumulative Average:
0.019 Previous Annual Average:
0.019
" Iodine-131 concentrations are <0.07 pCi/m unles, othenvise noted.
2 b Eight-day collection.
C Six-day collection.
d ND - No Data; sample lost in shipment.
- Low volume due to electricity found off.
34
l DUANE ARNOLD.
Table 12. Airborne particulates Analyses:
Gross beta Location:
D-16 (on-site) 3 Units:
pCi/m Collection:
Continuous, weekly exchange.
Date Volume Date Volume Collected (m 3)
Gross Beta Collected (m3)
Gross Beta Reauired LLD Qal Qal 01-07-93 322 0.050 0.004 07-08-93 284 0.017 0.003 01-14-93 275 0.041 0.004 07-15-93 285 0.013 i 0.003 01-22-93 323a 0.036-1 0.004 07-22-93 284 0.012 0.003 b
0.024 1 0.004 07-30-93 333a 0.014 i 0.003 01-28-93 241 02-05-93 283 0.025 0.004 08-05-93 239b 0.017 0.003 8
02-11-93 285b 0.022 i 0.002 08-12-93 285 0.017 i 0.003 02-18-93 285 0.028 i 0.004 08-19-93 NDc 02-25-93 286 0.028 i 0.003 08-26-93 286 0.019 i 0.003 03-04-93 287 0.028 i 0.003 09-02-93 285 0.019 i 0.003 03-11-93 283 0.023 i 0.003 09-10-93 326a 0.014 i 0.003 b
0.016 1 0.003 09-16-93 245b 0.014 i 0.003 03-17-93 245 03-25-93 326a 0.014 t 0.003 09-23-93 285 0.015 0.003 04-01-93 286 0.010 t 0.003 09-30-93 286 0.012 i 0.003 i
1st Qtr. Meants.d.
0.027 1 0.011 3rd Qtr. Meanis.d.
0.015 1 0.002 04-08-93 283 0.008 0.003 10-07-93 285 0.020 i 0.003 04-15-93 285 0.009 0.003 10-14-93 288 0.025 i 0.003 04-22-93 286 0.013 0.003 10-21-93 285 0.030 i 0.004 04-29-93 285 0.022 i 0.003 10-28-93 284 0.023 i 0.004 05-06-93 286 0.012 d: 0.003 11-04-93 288 0.013 i 0.003 05-13-93 286 0.013 0.003 11-11-93 286 0.025 0.003 05-20-93 284 0.014 i 0.003 11-18-93 285 0.030 t 0.004 05-27-93 286 0.015 0.003 11-24-93 244b 0.029 i 0.004 06-03-93 284 0.009 i 0.002 12-02-93 327a 0.041 0.004 06-10-93 286 0.012 0.003 12-09-93 285 0.031 i 0.004 06-17-93 283 0.016 0.002 12-16-93 286 0.028 i 0.004 b
0.021 i 0.004 06-24-93 288 0.020 0.003 12-22-93 244 07-01-93 286 0.014 i 0.003 12-30-93 326^
0.025 i 0.003 2nd Qtr. Meanis.d.
0.014 1 0.004 4th Qtr. Meants.d.
0.026 1 0.006 Cumulative Average:
0.021 Previous Annual Average:
0.021
^ Eight-day collection.
b Six-day collection.
c ND - No Data; sample lost in shipment.
15
I 1
Table 13. Airborne particulate samples, quarterly composites of weekly samples, analysis for gamma-emitting isotopes,1993.
Sample Description and Activity (pCi/m3) 1st Qtr.
2nd Qtr.
3rd Qtr.
4th Qtr.
D-1 Lab Code DAP-3502 DAP-3617 DAP-3733 DAP-3853 3
Volume (m )
3780 3711 3421 3717 Be-7 0.068i0.015 0.08510.018 0.078i0.027 0.073i0.018 Nb-95
<0.0004
<0.0006
<0.0008
<0.0007 Zr-95
<0.0021
<0.0016
<0.0012
<0.0013 Ru-103
<0.0007
<0.0008
<0.0012
<0.0004 1
Ru-106
<0.0056
<0.0039
<0.0093
<0.0055 Cs-134
<0.0003
<0.0003
<0.0005
<0.0008 Cs-137
<0.0003
<0.0007
<0.0005
<0.0005 Ce-141
<0.0011
<0.0024
<0.0030
<0.0018 Ce-144
<0.0052
<0.0059
<0.0058
<0.0065 1
D-2 Lab Code DAP-3503 D AP-3618 DAP-3734 DAP-3854 3
Volume (m )
3819 3711 3426 3724 Be-7 0.053i0.012 0.071i0.016 0.062i0.023 0.063i0.015 Nb-95
<0.0008
<0.0008
<0.0008
<0.0006 Zr-95
<0.0017
<0.0009
<0.0012
<0.0007 Ru-103
<0.0006
<0.0009
<0.0007
<0.0007 Ru-106
<0.0039
<0.0059
<0.0050
<0.0046 Cs-134
<0.0003
<0.0009
<0.0012
<0.0003 Cs-137
<0.0005
<0.0008
<0.0005
<0.0003 Ce-141
<0.0022
<0.0012
<0.0026
<0.0013 Ce-144
<0.0054
<0.0037
<0.0037
<0.0057 16
Table 13. Airborne particulate samples, quarterly composites of weekly samples, analysis for gamma-emitting isotopes,1993 (continued).
Sample Descriotion and Activity (pCi/m3) 1st Qtr.
2nd Qtr.
3rd Qtr.
4th Qtr.
D-3 Lab Code DAP-3504 DAP-3619 DAP-3735 DAP-3855 3
Volume (m )
3851 3708 3424 3739 Be-7 0.064i0.014 0.061i0.017 0.066i0.021 0.065i0.016 Nb-95
<0.0006
<0.0017
<0.0008
<0.0009 Zr-95
<0.0008
<0.0012
<0.0018
<0.0012 Ru-103
<0.0004
<0.0008
<0.0010
<0.0006 Ru-106
<0.0036
<0.0096
<0.010
<0.0057 Cs-134
<0.0004
<0.0006
<0.0006
<0.0006 i
<0.0004
<0.0004
<0.0005
<0.0008 Ce-141
<0.0018
<0.0017
<0.0024
<0.0019 Ce-144
<0.0044
<0.0036
<0.C"54
<0.0062 D-5 Lab Code DAP-3505 DAP-3620 DAP-3736 DAP-3856 3
Volume (m )
3750 3708 3421 3430 Be-7 0.049i0.014 0.06210.018 0.056i0.021 0.089i0.017 Nb-95
<0.0013
<0.0006
<0.0008
<0.0013 j
Zr-95
<0.0006
<0.0011
<0.0016
<0.0008 Ru-103
<0.0017
<0.0011
<0.0007
<0.0014 Ru-106
<0.0036
<0.011
<0.0071
<0.0058 Cs-134
<0.0005
<0.0004
<0.0005
<0.0004 Cs-137
<0.0005
<0.0003
<0.0005
<0.0008 Ce-141
<0.0012
<0.0024
<0.0019
<0.0020 Ce-144
<0.0045
<0.0063
<0.0075
<0.0070 l
l T
17
Table 13. Airborne particulate samples, quarterly composites of weekly samples, analysis for gamma-emitting isotopes,1993 (continued).
i Sample Description and Activity (pCi/m3) 1st Qtr.
2nd Qtr.
3rd Qtr.
4th Qtr.
l D-6 Lab Code DAP-3506 DAP-3621 DAP-3737 DAP-3857 3
Volume (m )
3751 3648 3424 3604 Be-7 0.075f0.028 0.065i0.020 0.063 0.020 0.063i0.015 Nb-95
<0.0015
<0.0007
<0.0008
<0.0005 Zr-95
<0.0020
<0.0010
<0.0012
<0.0012 Ru-103
<0.0010
<0.0006
<0.0012
<0.0006 Ru-106
<0.0075
<0.011
<0.0071
<0.0096 Cs-134
<0.0007
<0.0005
<0.0006
<0.0007 Cs-137
<0.0009
<0.0011
<0.0006
<0.0009 Ce-141
<0.0027
<0.0028
<0.0024
<0.0022 Ce-144
<0.0057
<0.0058
<0.0038
<0.0051 D-7 Lab Code DAP-3507 DAP-3622 DAP-3738 DAP-3716 3
Volume (m )
3765 3706 3421 3716 Be-7 0.05510.016 0.065i0.016 0.082i0.017 0.071i0.016 Nb-95
<0.0010
<0.0007
<0.0021
<0.0005 Zr-95
<0.0006
<0.0020
<0.0025
<0.0011 Ru-103
<0.0015
<0.0014
<0.0019
<0.0005 Ru-106
<0.0091
<0.0046
<0.010
<0.0074 Cs-134
<0.0007
<0.0009
<0.0009
<0.0007 Cs-137
<0.0004
<0.0007
<0.0011
<0.0006 Ce-141
<0.0010
<0.0024
<0.0024
<0.0013 Ce-144
<0.0042
<0.0071
<0.0058
<0.0042 18
d Table 13. Airborne particulate samples, quarterly composites of weekly samples analysis for gamma-eraitting isotopes,1993 (continued).
Sample Description and Activity (pCi/m3) 1st Qtr.
2nd Qtr.
3rd Qtr.
4th Qtr.
D-8 Lab Code DAP-3508 DAP-3623 DAP-3739 DAP-3859 3
Volume (m )
3749 3707 3336 3714 Be-7 0.058i0.015 0.085i0.019 0.06610.018 0.063 0.016 Nb-95
<0.0014
<0.0006
<0.0021
<0.0005 Zr-95
<0.0018
<0.0009
<0.0027
<0.0007 Ru-103
<0.0005
<0.0011
<0.0018
<0.0012 Ru-106
<0.0071
<0.0094
<0.0089
<0.0039 Cs-134
<0.0007
<0.0004
<0.0008
<0.0008 Cs-137
<0.0005
<0.0005
<0.0010
<0.0007 Ce-141
<0.0021
<0.0012
<0.0017
<0.0025 Ce-144
<0.0056
<0.0042
<0.0049
<0.0062 D-10 Lab Code DAP-3509 DAP-3624 DAP-3740 DAP-3860 Volume (m3) 3740 3711 3383 3714 Be-7 0.06410.017 0.076i0.016 0.059i0.021 0.063i0.019 Nb-95
<0.0012
<0.0009
<0.0012
<0.0007 Zr-95
<0.0009
<0.0020
<0.0017
<0.0007 Ru-103
<0.0004
<0.0017
<0.0012
<0.0005 Ru-106
<0.0086
<0.0048
<0.0042
<0.0039 Cs-134
<0.0004
<0.0010
<0.0004
<0.0008 Cs-137
<0.0009
<0.0006
<0.0007
<0.0005 Ce-141
<0.0025
<0.0022
<0.0015
<0.0020 Ce-144
<0.0031
<0.0030
<0.0047
<0.0028 b
10
Table 13. Airborne particulate samples, quarterly composites of weekly samples, analysis for gamma-emitting isotopes,1993 (continued).
3 Sample Description and Activity (pCi/m )
1st Qtr.
2nd Qtr.
3rd Qtr.
4th Qtr.
D-11 Lab Code DAP-3510 DAP-3625 DAP-3741 DAP-3861 3
Volume (m )
3749 3708 3093 3716 Be-7 0.05010.014 0.086i0.018 0.061i0.017 0.065i0.017 Nb-95
<0.0006
<0.0006
<0.0010
<0.0007 Zr-95
<0.0012
<0.0008
<0.0012
<0.0007 Ru-103
<0.0012
<0.0007
<0.0013
<0.0010 Ru-106
<0.0047
<0.0055
<0.0060
<0.0076 Cs-134
<0.0008
<0.0004
<0.0004
<0.0006 Cs-137
<0.0004
<0.0003
<0.0009
<0.0006 Ce-141
<0.0012
<0.0002
<0.0023
<0.0022 Ce-144
<0.0064
<0.0065
<0.0066
<0.0061 D-13 Lab Code DAP-3511 DAP-3626 DAP-3742 DAP-3862 3
Volume (m )
3749 3707 3424 3718 Be-7 0.058i0.009 0.09310.019 0.048i0.020 0.06610.015 Nb-95
<0.0018
<0.0007
<0.0007
<0.0013 Zr-95
<0.0022
<0.0008
<0.0018
<0.0008 Ru-103
<0.0014
<0.0006
<0.0018
<0.0004 Ru-106
<0.0084
<0.0060
<0.0081
<0.0029 Cs-134
<0.0009
<0.0006
<0.0006
<0.0010 Cs-137
<0.0008
<0.0004
<0.0004
<0.0007 Ce-141
<0.0020
<0.0020
<0.0021
<0.0020 Ce-144
<0.0049
<0.0053
<0.0063
<0.0055 l
20
l Table 13. Airborne particulate samples, quarterly composites of weekly samples, analysis l
for gamma-emitting isotopes,1993 (continued).
l Sample Description and Activity (pCi/m3)
Ist Qtr.
2nd Qtr.
3rd Qtr.
4th Qtr.
D-15 Lab Code DAP-3512 DAP-3627 DAP-3743 DAP-3863 3
Volume (m )
3750 3701 3421 3551 I
Be-7 0.049i0.009 0.050i0.014 0.044i0.018 0.06610.016 l
Nb-95
<0.0015
<0.0006
<0.0007
<0.0013 Zr-95
<0.0021
<0.0014
<0.0017
<0.0002 Ru-103
<0.0012
<0.0009
<0.0007
<0.0007 Ru-106
<0.0066
<0.0059
<0.0038
<0.0054 Cs-134
<0.0007
<0.0006
<0.0006
<0.0004 Cs-137
<0.0009
<0.0005
<0.0004
<0.0007 l
Ce-141
<0.0010
<0.0017
<0.0033
<0.0011 l
Ce-144
<0.0026
<0.0055
<0.0047
<0.0041 l
D-16 i
Lab Code DAP-3513 DAP-3628 DAP-3477 DAP-3713 3
Volume (m )
3727 3708 3423 3713 Be-7 0.041i0.008 0.063i0.016 0.061i0.016 0.062i0.016 Nb-95
<0.0014
<0.0007
<0.0007
<0.0011 Zr-95
<0.0016
<0.0010
<0.0010
<0.0007 Ru-103
<0.0009
<0.0010
<0.0017
<0.0008 Ru-106
<0.0054
<0.0043
<0.0038
<0.0061 Cs-134
<0.0007
<0.0003
<0.0008
<0.0003 Cs-137
<0.0006
<0.0005
<0.0004
<0.0005 Ce-141
<0.0012
<0.0018
<0.0018.
<0.0009 Ce-144
<0.0029
<0.0046
<0.0034
<0.0066 21
i 1
1 Table 14. Ambient gamma radiation (TLD), quarterly exposure,1993.
Location mR/91 days No.
1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Air Particulate Locations D-1 12.910.4 13.2i0.2 14.li0.3 12.010.2 D-2 15.6i0.3 13.0i0.3 13.4 0.2 14.110.3 D-3 15.3 0.3 12.5i0.3 13.8i0.2 13.410.2 D-5 15.li0.2 14.2i0.2 14.7i0.2 13.3i0.2 D-6 15.8i0.3 13.5i0.3 14.110.3 12.0i0.3 D-7 13.4i0.4 15.li0.2 14.li0.3 14.6i0.3 D-8 11.810.4 15.010.2 18.410.3 15.4i0.2 D-10 14.li0.2 14.910.2 15.6i0.2 15.5i0.3 D-11 12.8i0.3 14.2i0.4 14.810.2 13.li0.3 D-13 13.110.3 13.0 0.2 15.5i0.2 15.8f0.2 D-15 16.5io.3 14.710.3 15.6i0.2 14.2i0.4 D-16 14.3 0.3 M.0 0.3 15.4f0.2 14.0 0.2 Mean i s.d.
14.2il.4 13.9i0.9 15.0il.3 14.0tl.3 i
Within 0.5 Mile of Stack
)
2 D-18 16.2i0.3 16.4i0.3 14.2i0.2 15.610.3 D-19 16.4i0.4 16.610.2 13.li0.2 15.3i0.4 D-20 19.li0.4 17.010.3 16.0i0.2 15.8i0.2 D-21 16.0i0.3 15.7i0.3 13.910.4 15.8i0.2 D-22 12.7i0.2 15.7i0.2 17.710.2 14.3i0.2 D-23 14.4i0.3 13.7t0.3 12.510.2 12.li0.2 D-28 16.Si0.3 18.6i0.2 17.0i0.4 16.010.3 i
D-29 19.li0.5 20.410.3 17.310.4 18.510.3
~
D-30 20.li0.5 21.010.5 17.810.3 17.7t0.2 D-31 22.4i0.4 23.9i0.2 20.5i0.4 19.3i0.4 D-32 19.8i0.4 19.410.2 19.5i0.3 17.4i0.2 D-82 15.6i0.7 14.210.3 12.910.2 13.310.2 D-83 18.0i0.4 17.8i0.3 16.712.6 15.5i0.3 D-84 16.510.3 17.7i0.4 16.6i0.2 14.7i0.2 D-85 15.410.3 17.3i0.3 16.li0.3 14.410.2 D-86 15.9i0.5 20.610.3 18.0i0.3 17.3t0.3 D-91 14.4f0.4 17.1 0.3 17.2 0.4 17.0f0.2 Mean i s.d.
17.0i2.5 17.812.6 16.312.3 15.9il.9 22
Table 14. Ambient gamma radiation (TLD), quarterly exposure (continued)
Location mR/91 days No.
1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Within 1.0 Mile of Stack D-43 12.li0.4 17.9i0.3 14.910.2 14.8f0.2 D-44 19.810.4 19.8i0.3 19.li0.2 18.9i0.2 D-45 15.2i0.3 17.910.4 14.3i0.2 14.410.3 D-46 19.410.8 20.8t0.3 17.9i0.2 16.910.3 D-47 21.010.8 17.8i0.3 18.910.2 17.7i0.2 D-48 18.7i0.2 21.li0.3 13.8t0.4 18.3 0.2 Mean i s.d.
17.7i3.4 19.2il.5 16.512.4 16.8il.9 Within 3.0 Miles of Stack D-33 13.6i0.2 13.710.2 11.910.2 12.410.2 D-34 14.410.3 15.810.2 16.5i0.8 13.710.3 D-35 14.3i0.4 16.0i0.3 14.210.3 15.4i0.4 D-36 16.410.5 16.2i0.2 16.9i0.3 13.0i0.3 D-37 21.4i0.3 21.6i0.3 19.4i0.3 19.4i0.3 D-38 19.2i0.7 17.8i0.3 16.9i0.2 15.410.2 D-39 18.0i0.2 18.0i0.3 16.7i0.3 15.810.3 D-40 17.2i0.5 16.010.3 14.010.4 14.7i0.3 D-41 15.8 0.5 17.7 0.4 15.6i0.2 15.8 0.2 Mean t s.d.
16.7i2.5 17.0 2.2 15.8i2.2 15.li2.0 23
--re
l'
\\
i l
l Table 15. Milk samples, anal ses for iodine-131 and gamma-emitting isotopes.
i Collection: Mont ly during non grazing season (October 1 through April 30);
j biweekly during grazing season (May 1 through September 30) i j
Date Lab Concentration (oCi/L) l Collected Code 1-131 K-40 Cs-134 Cs-137 Ba-140 La-140 I
Indicator Location D i 01-05-93 DMI-8823,4 <1.0 1250i100
<15
<18
<60
<15 i
02-03-93
-8881
< 1.0 1270i140
<15
<18
<60
<15 03-02-93
-8963
< 1.0 1390i120
<15
<18
<60
<15 4
04-06-93
-9032
< 1.0 1380i160
<15
<18
<60
<15 05-04-93
-9105
< 1.0 1470il70
<15
<18
<60
<15 i
05-18-93
-9176
<1.0 1650i140
<15
<18
<60
<15 06-03 -9251
<1.0 1300il50
<15
<18
<60
<15 06-15-93
-9313
<1.0 1420i160
<15
<18
<60
<15 f
06-29-93
-9378
<1.0 1520i180
' 15
<18
<60
<15 07-13-93
-9455
<1.0 1440i100
<15
<18
<60
<15 l
07-27-93
-9519
<1.0 1480t170
<15
<10
<60
<15 i
08-10-93
-9607
<1.0 1470t160
<15
<18
<60
<15 4
08-24-93
-9673
<1.0 1500i150
<15
<18
<60
<15 i
09-08-93
-9745,6 <1.0 13701130
<15
<18
<60
<15 i
09-21-93
-9843
< 1.0 1390il70
<15
<18
<60
<15 10-05-93
-9885
< 1.0 1370i130
<15
<18
<60
<15 i
11-02-93
-0026
< 1.0 1310il70
<15
<18
<60
<15 12-07-93
-0126
<1.0 1140il70
<15
<18
<60
<15 i
i i
i i
i 1
e i
i i
24
~.
4 Table 15. Milk samples, analyses for iodine-131 and gamma-emitting isotopes (continued).
Date Lab Concentration (oCi/L)
Collected Code I-131 K-40 Cs-134 C's-137 Ba-140 La-140 Indicator Location D-93 01-05-93 NSa 02-03-93 NS l
03-02-93 DMI-8964
< 1.0 1460i160
<15
<18
<60
<15 04-06-93
-9033
< 1.0 1650i190
<15
<18
<60
<15 05-04-93
-9106
< 1.0 1590il50 (15
<18
<60
<15 3
05-18-93
-9177
< 1.0 1580il70
<15
<18
<60
<15 06-03-93
-9252
<1.0-1630il50
<15
<18
<60
<15 06-15-93
-9314
< 1.0 1550 150
<15
<18
<60
<15 06-29-93
-9379
<1.0 1800t130
<15
<18
<60
<15 07-13-93
-9456
<1.0 1560i200
<15
<18
<60
<15 07-27-93
-9520
< 1.0 1790i200
<15
<18
<60
<15 08-10 93
-9608
< 1.0 1660i200
<15
<18
<60
<15 08-24-93
-9674
<1.0 1760i140
<15
<18
<60
<15 09-08-93
-9747
< 1.0 1690i140
<15
<18
<60
<15 09-21-93
-9844
< 1.0 1740 130
<15
<18
<60
<15 10-05-93
-9886
< 1.0 1620i130
<15
<18
<60
<15 11-02-93
-0027
< 1.0 1370il20
<15
<18
<60
<15 12-07-93 NSa Location D-94 01-05-93 DMI 8825
< 1.0 1050t120
<15
<18
<60
<15 02-03-93
-8882
<1.0 950t140
<15
<18
<60
<15 03-02-93
-8965
< 1.0 1230t140
<15
<18
<60
<15 04-06-93
-9034
<1.0 1380il50
<15
<18
<60
<15 05-04-93
-9107
<1.0 1420il70
<15
<18
<60
<15 05-18-93
-9178
< 1.0 1350il70
<15
<18
<60
<15 06-03-93
-9253
< 1.0 820i140
<15
<18
<60
<15 06-15-93
-9315
<1.0 1110il50
<15
<18
<60
<15 06-29-93
-9380
<1.0 980t100
<15
<18
<60
<15 07-10-93 NDb a NS = No Sample; sample not available.
b ND = No Data; as of 07-10-93, D-94 removed from program due to cows being sold.
25
i Table 15. Milk samples, analyses for iodine 131 and gamma-emitting isotopes (continued).
4 Date Lab Concentration (oCi/D Collected Code I-131 K-40 Cs-134 C's-137 Ba-140 La-140 Indicator Location D-96 l
l 01-05-93 DMI-8826
< 1.0 1440il70
<15
<18
<60
<15 02-06-93
-8883
< 1.0 1480il50
<15
<18
<60
<15 j
03-02-93
-8966
< 1.0 1320i110
<15
<18
<60
<15 1
04-06-93
-9035
< 1.0 1440i120
<15
<18
<60
<15 05-04-93
-9108
<1.0 1380i140
<15
<18
<60
<15 05-18-93
-9179
< 1.0 1400i180
<15
<18
<60
<15 06-03-93
-9254
< 1.0 1410il70
<15
<18
<60
<15 06-15-93
-9316
< 1.0 1510i180
<15
<18
<60
<15 06-29-93
-9381
< 1.0 1480t130
<15
<18
<60
<15 07-13-93
-9457
<1.0 1330i180
<15
<18
<60
<15 07-27-93
-9521
<1.0 1340il70
<15
<18
<60
<15 08-10-93
-9609
< 1.0 1520i200
<15
<18
<60
<15 08-24-93
-9675
< 1.0 1400i180
<15
<18
<60
<15 09-08-93
-9748
< 1.0 1440i150
<16
<18
<60
<15 09-21-93
-9845
< 1.0 1280i180
<15
<18
<60
<15 10-05-93
-9887
< 1.0 1310t160
<15
<18
<60
<15 11-02-93
-0028
< 1.0 1400i130
<15
<18
<60
<15 12-07-93
-0127
< 1.0 1430i160
<15
<18
<60
<15 i
Location D-101 l
01-05-93 NSa 02-06-93 NS t
03-02 93 NS 04-06-93 NS
)
05-04-93 NS 05-18-93 DMI-9180
< 1.0 1530i160
<15
<18
<60
<15 i
06-03-93
-9255
< 1.0 1670i160
<15
<18
<60
<15 06-15-93
-9317
< 1.0 1750i160
<15
<18
<60
<15 06-29-93
-9382
< 1.0 1920i190
<15
<18
<60
<15 07-13-93
-9458
<1.0 1700il70
<15
<18
<60
<15 1
07-27-93
-9522
< 1.0 1740i180
<15
<18
<60
<15 08-11-93
-9610
< 1.0 1840i140
<15
<18
<60
<15 08-24-93
-9676
< 1.0 1890i140
<15
<18
<60
<15 09-08 93
-9749
< 1.0 1680i130
<15
<18
<60
<15 09-25-93
-9846
< 1.0 1340il50
<15
<18
<60
<15 10-05-93
-9888
<1.0 1500i180
<15
<18
<60
<15 11-02-93
-0029
< 1.0 1670t130
<15
<18 60
<15 12-07-93 N@
a NS = no sample; sample not available.
26 1
Table 15. Milk samples, analyses for iodine-131 and gamma-emitting isotopes (continued).
Date Lab Concentration (pCi/L)
Collected Code 1-131 K-40 Cs-134 Cs-137 Ba-140 La 140 Indicator Location D-106 01-05-93 DMI-8828
< 1.0 1480il70
<15
<18
<60
<15 02-06-93
-8885
< 1.0 1390i160
<15
<18
<60
<15 03-02-93
-8968
< 1.0 1600il50
<15
<18
<60
<15 04-06-93
-9037
< 1.0 1330i140
<15
<18
<60
<15 03-04-93
-9110,11 <1.0 1400i110
<15
<18
<60
<15 05-18-93
-9182
< 1.0 1200i160
<15
<18
<60
<15 06-03-93
-9257,8 <1.0 1390i90
<15
<18
<60
<15 06-15-93
-9318
< 1.0 1520i160
<15
<18
<60
<15 06-79-93
-9384
< 1.0 1190i150
<15
<18
<60
<15 07-13-93
-9460
<1.0 1180i160
<15
<18
<60
<15 07-27-93
-9524
<1.0 1250t150
<15
<18
<60
<15 08-10-93
-9612
< 1.0 1280i120
<15
<18
<60
<15 08-24-93
-9678
< 1.0 1140i120
<15
<18
<60
<15 09-08-93
-9751
< 1.0 1230 160
<15
<18
<60
<15 09-21-93
-9848
< 1.0 1260i150
<15
<18
<60
<15 10-05-93
-9889
< 1.0 14201160
<15
<18
<60
<15 11-02-93
-0031
< 1.0 1380i130
<15
<15
<60
<15 12-07-93 NSa Control Location D-105 01-05-93 DMI-8827
< 1.0 1400i150
<15
<18
<60
<15 02-06-93
-8884
< 1.0 1270i120
<15
<18
<60
<15 03-02-93
-8967
< 1.0 1240t140
<15
<18
<60
<15 04-06-93
-9036
< 1.0 1220t140
<15
<18
<60
<15 05-04-93
-9109
<1.0 1320i180
<15
<18
<60
<15 05-18-93
-9181
< 1.0 1420i160
<15
<18
<60
<15 06-03-93
-9256
<1.0 1480i190
<15
<18
<60
<15 06-15-93
-9329
< 1.0 1230t150
<15
<18
<60
<15 06-29-93
-9383
< 1.0 1440i140
<15
<18
<60
<15 07-13-93
-9459
< 1.0 1590*190
<15
<18
<60
<15 07-27-93
-9523
< 1.0 1450il70
<15
<18
<60
<15 08-10-93
-9611
< 1.0 1320il70
<15
<18
<60
<15 08-24-93
-9677
< 1.0 1440i190
<15
<18
<60
<15 09-08-93
-9750
< 1.0 1390i160
<15
<18
<60
<15 09-21-93
-9847
< 1.0 1340il50
<15
<18
<60
<15 10-05-93
-9890
< 1.0 1310t160
<15
<18
<60
<15 11-02-93
-0030
< 1.0 1500i230
<15
<18
<60
<15 12-07-93
-0128
< 1.0 1330t160
<15
<18
<60
<15 aNS = no sample; location removed from program as of 12-07-93.
27
Table 16. Ground water samples, analysis for gross beta and tritium.
Collection: Quarterly,1993.
Location and Lab Concentration oCi/L Collection Period Code Gross Beta H-3 D:li3 Treated Municipal Water 1st Quarter DWW-1128 2.4i0.6
<330 2nd Quarter
-2443 1.8i0.5
<330 3rd Quarter
-3405 2.010.5
<330 4th Quarter
-4420 2.90.8 s33D Annual Mean i s.d.
2.310.5
<330 D.5A Inlet to Municipal Water Treatment 1st Quarter DWW-1129 3.0i0.6
<330 2nd Quarter
-2444, 5 2.610.4
<330 3rd Quarter
-3406 3.810.9
<330 4th Quarter
-4421 2.6+0.8 s330 Annual Mean t s.d.
3.010.6
<330 D-55 On-site Well 1st Quarter DWW-1130
<0.8
<330 2nd Quarter
-2446
<0.8
<330 3rd Quarter
-3407 1.110.5
<330 4th Quarter
-4422 sL2 533D Annual Mean t s.d.
1.li0.5
<330 D-5Z Bull Farm 1st Quarter DWW-1131 1.2i0.5
<330 2nd Quarter
-2447
<0.8
<330 3rd Quarter
-3408 1.4i0.5
<330 4th Quarter
-4423 1.5i0.7 s330 Annual Mean i s.d.
1.4i0.2
<330 28
Table 16. Ground water samples, analysis for gross beta and tritium,(continued):
Locatior, and Lab Concentration oCi/L Collection Per;od Code Gross Beta H-3 D-5B Franz Farm 1st Quarter DWW-1132 5.9i0.7
<330 2nd Quarter
-2448 7.210.8
<330 3rd Quarter
-3409 6.4i0.7
<330 4th Quarter
-4424 8.3tl.1
<330 Annual Mean i s.d.
7.0il.0
<330 D-72 Van Note Farm 1st Quarter DWW-1133
<0.8
<330 2nd Quarter
-2449
<0.8
<330 3rd Quarter
-3410
<0.8
<330 4th Quarter
-4425 sL2
<330 Annual Mean i s d.
<1.2
<330 1
29
Table 17 Vegetation samples (broadleaf), analysis for I-131 and gamma-emitting. isotopes.
Collection: Annually.
J J
Sample Description and Activity (pCi/g wet) l Indicator Control Location D 58 D-72 D-105 i
Date Collected 07-13-93 07-13-93 07-13-93 Type Cabbage Lettuce Lettuce
)
Lab Code DVE-1559 DVE-1560 DVE-1541 I-131
<0.026
<0.040
<0.082a K-40 2.10i0.32 2.22i0.20 4.88il.36 Mn-54
<0.013
<0.009
<0.059 Co-58
<0.006
<0.008
<0.056 Co-60
<0.005
<0.004
<0.073 Nb-95
<0.008
<0.012
<0.059 Zr-95
<0.017
<0.019
<0.10 Ru-103
<0.008
<0.011
<0.067 Ru-106
<0.081
<0.10
<0.56 Cs-134
<0.006
<0.005
<0.056 i
<0.009
<0.011
<0.064 Ce-141
<0.024
<0.019
<0.089 4
Ce-144
<0.043
<0.042
<0.37 1
Location D-94 D-106 i
Date Collected 06-30-93 07-13-93 Type Lettuce Cabbage Lab Code DVE-1529 DVE-1542 1-131
<0.034
<0.009 i
K-40 2.25i0.57 2.14i0.22 Mn-54
<0.021
<0.009 Co-58
<0.021
<0.008 Co-60
<0.014
<0.010 Nb-95
<0.024
<0.009 Zr-95
<0.028
<0.013
{
Ru 103
<0.014
<0.009 Ru-106
< 0.26
<0.069 Cs-134
<0.019 '
<0.008 Cs-137
<0.018
<0.009 Ce-141
<0.039
<0.011 Ce-144
<0.098
<0.049 aLLD of <0.060 not reached due to small sample size (40 grams).
l
l
\\
l
' Table 18. Vegetation samples (hay and grain), analysis for gamma-emitting isotopes.
Collection: Annually.
Sample Description and Activity (pCi/g wet)
Indicator Location D-16 D-58 D-63 D-72 Date Collected 08-10 93 08-10-93 08-10-93 08-10-93 Type Hay Hay Hay Hay Lab Code DVE-1589 DVE-1590 DVE-1591 DVE-1592 K-40 3.35i0.64 19.27i0.81 5.98i0.87 21.56i0.88 Mn-54
<0.029
<0.029
<0.028
<0.023 Co-58
<0.015
<0.029
<0.041
<0.029 -
<0.012
<0.032
<0.013
<0.033 i
Nb-95
<0.038
<0.033
<0.034
<0.015 Zr-95
<0.045
<0.054
<0.061
<0.052.
Ru-103
<0.033
<0.029
<0.020
<0.017
'l Ru-106
<0.15
<0.24
<0.24
<0.22 Cs-134
<0.026
<0.025
<0.020
<0.013 Cs-137
<0.029
<0.031
<0.038
<0.031 Ce-141
<0.060
<0.040
<0.035
<0.032 Ce-144
<0.17
<0.016
<0.28
< 0.13 l
l Location D-93 D-94 D-106 D-105 (C)
Date Collected 08-10-93 08-20-93 08-10-93 08-10-93 Type Hay Hay Hay Hay Lab Code DVE-1593 DVE-1622 DVE-1595 DVE-1594 K-40 8.45fl.38 19.71il.15 21.68 1.02 16.06tl.32 Mn-54
<0.029
<0.042
<0.035
<0.046 Co-58
<0.069
<0.072
<0.035
<0.020 l
<0.064
<0.041
<0.039
<0.034 Nb-95
<0.070
<0.028
<0.039
<0.052 l
Zr-95
<0.11
<0.087
<0.061
<0.054 Ru-103
<0.060
<0.027
<0.036
<0.029 Ru-106
<0.30
<0.27
<0.31
<0.34 Cs-134
<0.048
<0.051
<0.029
<0.027 Cs-137
<0.042
<0.049 0.047i0.029
<0.040.
Ce-141
<0.055
<0.041
<0.049
<0.042 Ce-144
<0.36
<0.16
<0.20
<0.23 t
I 31
l Table 18. Vegetation samples, analysis for gamma-emitting isotopes (continued).
Collection: Annually.
]
Sample Desciption and Activity (pCi/g wet)
Indicator Location D-57 D-58 D-63 D-72 D-16 Date Collected 10-12-93 10-12-93 10-12-93 10-12-93 10-06-93 Type Corn Corn Corn Corn Beans Lab Code DVE-1718 DVE-1719 DVE-1720 DVE-1721 DVE-1717 K-40 2.86i0.34 3.02i0.34 2.13i0.25 2.1910.26 11.2310.40 Mn-54
<0.007
<0.010
<0.008
<0.004
<0.014 Co-58
<d.007
<0.006
<0.007
<0.005
<0.013 Co-60
<0.004
<0.007
<0.003
<0.003
<0.015 Nb-95
<0.009
<0.003
<0.006
<0.004
<0.015 Zr-95
<0.007
<0.011
<0.013
<0.009
<0.023 Ru-103
<0.007
<0.011
<0.012
<0.008
<0.013 Ru-106
<0.039
<0.098
<0.027
<0.054
<0.11 Cs-134
<0.008
<0.005
<0.007
<0.005
<0.011 Cs-137
<0.004
<0.008
<0.006
<0.005 0.036i0.011 Ce-141
<0.015
<0.021
<0.011
<0.008
<0.018 Ce-144
<0.046
<0.079
<0.033
<0.039
<0.078 Indicator Control Location D-93 D-94 D-106 D-105 Date Collected 10-12-93 10-12-93 10-12-93 10-12-93 Type Corn Corn Corn Corn Lab Code DVE-1722 DVE-1723 DVE-1725 DVE-1724 K-40 2.29i0.28 2.36i0.32 2.87i0.31 2.86i0.30 Mn-54
<0.002
<0.004
<0.006
<0.006 Co-58
<0.007
<0.003
<0.008
<0.003 Co-60
<0.003
<0.007
<0.005
<0.003 Nb-95
<0.006
<0.010
<0.007
<0.007 Zr-95
<0.011
<0.007
<0.007
<0.016 Ru-103
<0.011
<0.008
<0.008
<0.006 Ru-106
<0.082
<0.066
<0.056
<0.092 i
Cs-134
<0.005
<0.008
<0.005
<0.009 Cs-137
<0.002
<0.004
<0.004
<0.005 Ce-141
<0.014
<0.016
<0.014
<0.019 Ce-144
<0.074
<0.045
<0.071
<0.067 32
Table 19-Surface water samples, analysis for iodine-131 and gamma-emitting isotopes.
Collection: Monthly.
Sample Description and Concentration (pCi/L)
Indicator D Plant Intake Date Collected 01-26-93 02-24-93 03-29-93 04-21-93 05-19-93 06-23-93 Lab Code DSW-9129 DSW-9965 DSW-1124 DSW-1512 DSW-1865 DSW-2439 I-131
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 Date Collected 07-28-93 08-25-93 09-22-93 10-27-93 11-23-93 12-21-93 Lab Code DSW-2778 DSW-3087 DSW-3401 DSW-3797 DSW-4111 DSW-4416 q
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 33
i j
i
)
Table 19. Surface water samples, analysis for iodine-131 and gamma-emitting isotopes.
Collection: Monthly.
Sample Description and Concentration (pCi/L)
Indicator D Plant Discharce Date Collected ~ 01-26-93 02-24-93 03-29-93 04-21-93 05-19-93 06-23-93 Lab Code DSW-9130 DSW-9966 DSW-1125 DSW-1513 DSW-1866 DSW-2440 I-131
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 Date Collected 07-28-93 08-25-93 09-22-93 10-27-93 11-23-93 12-21-93 Lab Code DSW-2779 DSW-3088 DSW-3402 DSW-3798 DSW-4112 DSW-4417 i
i 1-131
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 4
Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 1
Zn-65
<30
<30
<30
<30
<30
<30 i
Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 34
9 j
Table 19. Surface water samples, analysis for iodine-131 and gamma-emitting isotopes.
Collection: Monthly.
Sample Description and Concentration (pCi/L)
I Indicator D Pleasant Creek Date Collected 01-26-93 02-24-93 03-29-93 04-21-93 05-24-93 06-30-93 Lab Code DSW-9131 DSW-9967 DSW-1126 DSW-1514 DSW-1867 DSW-2441 I-131
<15
<15
<15
<15
<15
<15 hin-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 l
Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 Date Collected 07-30-93 08-31-93 09-28-93 10-27-93 112443 12-15-93 i
Lab Code DSW-2780 DSW-3089 DSW-3403 DSW-3794 DSW-4113 DSW-4418 I-131
<15
<15
<15
<15
<15
<15 4
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 i
i 35
j Table 19. Surface water samples, analysis for iodine-131 and gamma-emitting isotopes.
Collection: Monthly.
Sample Description and Concentration (pCi/L)
Indicator D Lewis Access Date Collected 01-26-93 02-24-93 03-24-93 04-21-93 05-24 93 06-30-93 I
Lab Code DSW-9128 DF W-9963,4 DSW-1123 DSW-1511 DSW-1864 DSW 2438 I-131
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 l
Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 j.
Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18'
<18
<18
<18
<18
(
Ba-140
<60
<60
<60
<60
<60
<60 j
La-140
<15
<15
<15
<15
<15
<15 Date Collected 07-30-93 08-31-93 09-28-93 10-27-93 11-24-93 12-15 93
[
Lab Code DSW-2777 DSW-3085,6 DSW-3400 DSW-3796 DSW-4110 DSW-4415 l
<15
<15
<15
<15
<15
<15 l
l Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15
i Table 19. Surface water samples, analysis for lodine-131 and gam.ma-emitting isbtopes.
Collection: Monthly.
Sample Description and Concentration (pCi/L)
Control D-107 - Plant Sewace Discharce Date Collected 01-26-93 02-24-U 03-29-93 04-21-93 05-24-93 06-30-93 Lab Code DSW-9132,3 DSW-9968 DSW 1127 DSW-1515 DSW 1868 DSW-2442 K-40a 18.9 17.3 16.4 14.70 12.11 9.08 1-131
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co 60
<15
<15
<15
<15
<15
<15 Zn-65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 Date Collected 07-30 93 08-31-93 09-28-93 10-27-93 11-24 93 12-15-93 Lab Code DSW-2781 DSW-3090 DSW-3404 DSW-3800 DSW-4114 DSW-4419 K-40a 12.98 14.70 19.90 18.16 14.70 15.57 I
<15
<15
<15
<15
<15
<15 Mn-54
<15
<15
<15
<15
<15
<15 Fe-59
<30
<30
<30
<30
<30
<30 Co-58
<15
<15
<15
<15
<15
<15 Co-60
<15
<15
<15
<15
<15
<15 Zn 65
<30
<30
<30
<30
<30
<30 Nb-95
<15
<15
<15
<15
<15
<15 Zr-95
<30
<30
<30
<30
<30
<30 Cs-134
<15
<15
<15
<15
<15
<15 Cs-137
<18
<18
<18
<18
<18
<18 Ba-140
<60
<60
<60
<60
<60
<60 La-140
<15
<15
<15
<15
<15
<15 a Analyzed by flame photometry.
I l
37 1
.. e Table 21. Surface water samples, quarterly composites of monthly samples, analysis for tritium,1993.
Location and Lab Concentration (oCi/L)
Collection Period Code H-3 Indicator D:50 1st Quarter DSW-1135
<330 2nd Quarter
-2451
<330 3rd Quarter
-3413
<330 4th Quarter
-4452 s31Q Annual Mean s'
<330 D-51 1st Quarter DSW-1136
<330 2nd Quarter
-2452
<330 3rd Quarter
-3414
<330 4th Quarter
-4453 s33D Annual Mean s.d.
<330 DAS 1st Quarter DSW-1138
<330 2nd Quarter
-2453
<330 3rd Quarter
-3415
<330 4th Quarter
-4454 133D Annual Mean s.d.
<330 D-107 1st Quarter DSW-1139
<330 2nd Quarter
-2454
<330 3rd Quarter
-3416
<330 4th Quarter
-4455 s33D Annual Mean i s.d.
<330 Control D:.42 1st Quarter DSW-1134
<330 2nd Quarter
-2450
<330 3rd Quarter
-3412
<330 4th Quarter
-4451 s33D Annual Mean i s.d.
<330 38
E Table 22. Fish samples, analysis of edible portion for gamma-emitting isotopes.
Collection: Semiannuallya.
Sample Description and Concentration (pCi/g wet)
Indicator Downstream D-61 Date Collected 10-21-93 10-21-93 Type Carpsucker Carp Lab Code DF-2277 DF-2278 K-40 2.83i0.36 2.77i0.38 Mn-54
<0.015
<0.012 Co-58
<0.006
<0.015 Co-60
<0.012
<0.010 Fe-59
<0.039
<0.030 Zn-65
<0.024
<0.031 Nb-95
<0.027
<0.006 Zr-95
<0.032
<0.022 Ru-103
<0.019
<0.009 Ru-106
<0.11
<0.14 Cs-134
<0.014
<0.017 Cs-137
<0.017
<0.017 Ce-141
<0.042
<0.011 Ce-144
<0.11
<0.058 Control Upstream D-49 Date Collected 10-21-93 10-21-93 Type Carpsucker Carp Lab Code DF-2274 DF-2275, 6 K-40 2.7410.62 2.62i0.46 Mn-54
<0.014
<0.021 Co-58
<0.024
<0.017 Co-60
<0.032
<0.008 Fe-59
<0.042
<0.051 Zn-65
<0.027
<0.033 Nb-95
<0.027
<0.021 Zr-95
<0.052
<0.042 Ru-103
<0.021
<0.026 Ru-106
<0.22
<0.18 Cs-134
<0.012
<0.021 Cs-137
<0.014
<0.023 Ce-141
<0.024
<0.051 Ce-144
<0.16
<0.078 a No fish were collected during the first half of 1993 due to high river water levels.
39
2 Table 23. River sediment samples, analysis for gamma-emitting isotopes.
Collection: Semiannually.
a Sample Description and Concentration (pCi/g dry) l Control Location D-49 D-50 Date Collected 09-24-93 10-07-93 Lab Code DBS-1333 DBS-1351 K-40 8.51i0.43 9.07io.52 hin-54
<0.014
<0.012 l
Co-58
<0.022
<0.007 i
<0.006
<0.018 Nb-95
<0.047
<0.020 Zr-95
<0.043
<0.036 Ru-103
<0.028
<0.038 l
Ru-106
<0.13
<0.057 l
Cs-134
<0.014
<0.012 i
Cs-137 0.029i0.016
<0.018 Ce-141
<0.036
<0.059 Ce-144
<0.092
<0.053 Indicator Location D-51 D-51 D-107 D-107 Date Collected 09-24-93 10-07-93 09-24-93 10-07-93 Lab Code DBS-1334 DBS-1352 DBS-1335 DBS-1353 K-40 9.39 0.48 9.91i0.56 7.16i0.40 7.23i0.38 Mn-54
<0.015
<0.019
<0.012
<0.013 Co-58
<0.008
<0.009
<0.014
<0.007 l
<0.013
<0.026 0.035i0.012
<0.018 Nb-95
<0.014
<0.020
<0.017
<0.008 Zr-95
<0.040
<0.040
<0.038
<0.024 Ru-103
<0.011
<0.013
<0.014
<0.015 Ru-106
<0.060
< 0.14
<0.12
<0.090 Cs-134
<0.016
<0.012
<0.013
<0.011 Cs-137 0.02510.014 0.02910.016
<0.014 0.02410.014 Ce-141
<0.051
<0.064
<0.063
<0.019 Ce-144
<0.095
<0.13
<0.094
<0.058 a No river sediment samples were collected during the first half of 1993 due to high river water levels.
l 40
r 1
4 6
- 8 Table 24.
Precipitation samples, analysis for gamma-emitting isotopes.
Collection: Monthly,1993.
Sample Description and Concentration (pCi/L)
Collection Period January February March April Lab Code DP-1212 DP-1228 DP-1236 DP-1239 Mn-54
<4.1
<3.7
<3.3
<6.9 Fe-59
<10.9
<10.1
<6.4
<16.4 Co-58
<4.9
<3.9
<2.9
<6.9 Co-60
<4.7
<3.9
<3.4
<7.5 Zn-65
<10.5
<7.8
<7.0
<14.9 Nb-95
<5.8
<4.8
<3.0
< 8.4 Zr-95
<8.8
. <7.0
<5.4
<12.9 I-131
< 15.9
<15.0
<3.6
<9.6 Cs-134
<4.4
<3.5
<3.1
< 7.1 Cs-137
<4.1
<3.6
<3.4
<6.6 Ba-140
<33.6
<31.1
<12.5
<32.2 La-140
<12.2
<7.4
<3.7
<7.5 i
Collection Period May June July August Lab Code DP-1247 DP-1262 DP-1271 DP-1280 Mn-54
<13.1
<3.5
<3.8
<3.6 Fe-59
<16.1
<3.4
<7.2
<8.3 i
l Co-58
< 6.9
<3.0
<3.4
<2.1 i
<6.4
<3.9
<3.8
<4.0 l
Zn-65
<12.0
<2,1
<5.2
<6.0 l
Nb-95
<8.8
<4.2
<4.1
<4.2 l
Zr-95
<9.2
<3.8
<5.6
<10.3 I-131
<7.8
<4.9
<5.4
<5.0 Cs-134
<9.9
<3.9
<2.8
<2.8 Cs-137
<10.9
<3.8
<2.9
<3.8 Ba-140
<33.0
<29.6
<20.5
<20.8 l
La-140
< 6.9
<5.6
<3.3
<2.0 i
l Collection Period September October November December l
Lab Code DP-1282 DP-1291 DP-1300 DP-1308
(
<2.8
<8.0
<6.7
<3.8 Fe-59
<8.3
<17.6
<13.7
<5.2 i
Co-58
<5.6
<7.0
<5.6
<6.6 Co-60
<2.8
<9.0
<3.2
<4.6 Zn-65
<7.6
<18.6
<15.9
<11.6 Nb-95
<2.3
<9.4
<4.8
<5.5 Zr-95
<7.6
<14.2
<14.1
<8.4 I-131
<4.9
<19.0
<8.7
<13.3 Cs-134
<4.4
< 6.9
<6.7
<5.2 Cs-137
<4.7
<7.0
<7.7
<4.5 Ba-140
<20.3
<47.3
<9.7
- <19.6 La-140
<4.6
< 8.1
<3.4
<6.3 I
l 41
t Table 25. Precipitation samples, quarterly composites of monthly samples, analysis for tritium,1993.
i Location and Collection Period Lab Concentration (pCi/L)
Code H-3 1st Quarter DP-1237
<330 2nd Quarter
-1263
<330 3rd Quarter
-1283
<330 4th Quarter
-1309
<330 NOTE: Page 43 is intentionally left out.
4 4
I 5
4 e
'I l
l 1
42
o e
Table 27. Soil samples, analysis for gamma-emitting isotopes.
Collection: Annually.
Sample Description and Concentration (pCi/g dry)
Location D-15 D-16 Date Collected 10-12-93 10-12-93 Lab Code DSO-821 DSO-822 Sr-90 0.043i0.010 0.074 0.014 K-40 16.33i0.69 11.04i0.50 Mn-54
<0.021
<0.019 Co-58
<0.026
<0.024 Co-60
<0.034
<0.018 Nb-95
<0030
<0.023 Zr-95
<C.042
<0.037 Ru-103
<0.020
<0.013 Ru-106
<0.15
<0.11 Cs-134
<0.017
<0.014 Cs-137 0.22i0.03 0.31i0.03 Ce-141
<0.084
<0.038
' 0.12
<0.099 Ce-144 C