Text

State of Florida Department of Environmental Protection, Conditions of Certification
	ML100980527
Person / Time
Site:	Crystal River
Issue date:	08/28/2009
From:	; State of FL, Dept of Environmental Protection
To:	; Office of Nuclear Reactor Regulation
References
	3F1109-06, TAC ME0278 PA 77-09A2
	Download: ML100980527 (374)
	v • d • e

{{#Wiki_filter:STATE OF FLORIDA DEPARTMENT OF ENVIRONMENTAL PROTECTION Conditions of Certification Progress Energy Florida Crystal River Energy Complex Unit 3 Nuclear Power Plant Unit 4 and Unit 5 Fossil Plant PA 77-09A2 August 28, 2008

State of Florida Department of Environmental Protection Progress Energy Florida Crystal River Units 3, 4 and 5 Case No. PA 77-09A2 CONDITIONS OF CERTIFICATION Modified 08/28/08 Table of Contents Page I. CERTIFICATIO N CO NTRO L ............................................................................. I II. APPLICABLE RULES ............................................ III. DEFINITIO NS ......................................................................................................... 1 IV. G ENERA L CO NDITIO NS .................................................................................... 2 A. Facilities O peration .................................................................................... .. 2 B. Records Maintained at the Facility .................................................................... 3 C. Change in Discharge ........................................................................................ 3 D. Noncom pliance Notification .............................................................................. 3 E. Adverse Im pact .................................................................................................. 4 F. Right of Entry ................................................................................................. 4 G . Enforcem ent .................................................................................................. 4 H. Revocation or Suspension ................................................................................ 5 I. Civil and Crim inal Liability ................................................................................ 5 J. Property Rights ................................................................................................. 5 K. Severability .................................................................................................... 6 L. Review of Site Certification .............................................................................. 6 M. Procedural Rights ............................................................................................. 6 N. Modification of Conditions ............................................................................... 6 0 . Transfer of Certification .................................................................................... 7 P. S a fe ty ................................................................................................................... 7 Q. Screening ................................................ 7 R. Toxic, Deleterious or Hazardous Materials ...................................................... 7 S. Noise ............................................................................................................ 8 T. Flood Control Protection ...................................... 8 Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification

U. Historical or Archaeological Finds .................................................................... 8 V. Endangered and Threatened Species ............................. 8 W . D ispute R esolution ........................................................................................ .. 8 X. Laboratories And Quality Assurance ............................................................... 8 Y. Procedures For Post-Certification Submittals .................................................. 9 Z. Potable Water Supply System ...................................................................... 10 V. CONSTRUCTION ............................................................................................. 10 A. Standards and Review of Plans ..................................................................... 10 B. C o ntro l Me a s u re s ............................................................................................... 1 1. C. Environmental Control Program .................................................................... 12 D. R e p o rtin g ....................................................................................................... . . 13 E. Construction in Waters of the State ................................................................ 13 F. Transformer and Electric Switching Gear ...................................................... 13 VI. Unit 4 & Unit 5 Specific Conditions ............................................................... 13 A. A ir ....................................................................................................................... 13

1. R e p o rtin g .................................................................................................. . . 14

2. Coal Characteristics and Contracts ........................................................... 14

3. C oal Inform ation ...................................................................................... . . 14

4. Natu ra l G as ............................................................................................. . . 15 B. Wate r D ischarges ......................................................................................... . . 15

1. Plant Effluents and Receiving Body of Water ............................................. 15 C. Water Monitoring Programs ........................................................................... 16

1. C hem ical Monitoring ................................................................................ . . 16

2. Groundwater Monitoring ............................................................................. 17 D. Percolation Pond Monitoring Requirements .................................................... 17 E. FGD Scrubber Blowdown 188............................

F. Southwest Florida Water Management District (SWFWMD) - Groundwater ..... 18

1. Withdrawal Quantities and Facilities ............................................................... 18

2. Submit Reports/Data ................................................................................. 18

3. Environmental Impacts, Monitoring, and Mitigation: Environmental Assessment 19

4. Alternative Water Supply Implementation .................................................. 20

5. Compliance Reporting ............................................................................... 22 Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification ii

6. Pum page Reporting .................................................................................. 23

7. Distribution Flexibility .................................................................................. 24

8. Water quality sam pling ............................................................................... 24

9. We lls ............................................................................................................... 28

10. Standard Conditions .................................................................................. 29 G . Solid W astes .................................................................................................. 31 H. Ash Landfill and Coal Piles ............................................................................. 32

1. Ash Landfill ................................................................................................ 32

2. Ash Relocation Due to Installation of New Access Road to Support the Units 4

     & 5 Clean Air Project .........................................................................................                      32

3. Coal Pile .................................................................................................... 34 VII. Unit 3 Specific conditions ............................................................................... 35 A. A ir ....................................................................................................................... 35 B. Water Discharges ........................................................................................... 35 C. G roundwater- SW FWMD ............................................................................. 35 D. G roundwater - FDEP .................................................................................... 36 E. Environm ental Resource Review ................................................................... 36 F. Dom estic Wastewater Treatm ent .................................................................. 37 G. Radiological .................................................................................................... 37

1. Decom m issioning ...................................................................................... 37

2. Em ergency Plan ........................................................................................ 37

3. Radiological Release Lim itations ................................................................ 37

4. Monitoring .................................................................................................. 38

5. Reservation of Legal Rights ........................................................................ 38 VIII. Florida Departm ent of Transportation ........................................................... 39 A. Access Management to the State Highway System ...................................... 39 B. Overweight or Overdim ensional Loads ........................................................... 39 C. Use of State of Florida Right of Way or Transportation Facilities ................... 39 D. Standards ...................................................................................................... 39 E. Drainage ......................................................................................................... 39 F. Use of Air Space ............................................................................................ 40 G. Best Managem ent Practices ........................................................................... 40 IX. History ........................................................................................................ 40 Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification iii

Ambient Air Monitoring Locations .............................................. 42 : Leachate Monitoring and Testing ................................................ 43 : Discharge Monitoring Report ....................................................... 46 List of Appendices Appendix A Current Title V Air Operation Permit Appendix B Air Construction Permit 0170004-013-AC Appendix C Air Construction Permit 0170004-014-AC Appendix D Air PSD Permit PSD-FL-383 Appendix E Air PSD Permit PSD-FL-392 Appendix F NPDES Permit FL0036366 Appendix G NPDES Permit FL0000159 Appendix H WUP 20004695.004 Appendix I IWW Permit FLA016960 Appendix J IWW Permit FLA118753 Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-ý09A2 Conditions of Certification iv

I. CERTIFICATION CONTROL A. Pursuant to s. 403.501-518, F.S., the Florida Electrical Power Plant Siting Act, this certification is issued to Progress Energy Florida, Inc (PEF) as owner/operator of Crystal River Energy Complex. The Department recognizes that Nuclear Unit 3 and Fossil Units 4 and 5 are under the control of different divisions of PEF. Unless otherwise specified, PEF shall be responsible for the compliance with the conditions herein. Violation of any conditions specific to Units 3, 4, or 5 shall solely affect the license of the responsible generating units. Under the control of these Conditions of Certification PEF will operate a 1437 MW (nominal) facility consisting of two coal-fired Units No. 4 and No. 5 (and ancillary equipment), and one 1,080 MW (nominal) nuclear plant Unit 3. These units are located on a 4,738 -acre site which is located at Township 17, Range 16, Citrus County, Florida. Existing Units 1 and 2 are not subject to this certification or these conditions. B. The general and specific conditions contained in these Conditions of Certification, unless specifically amended or modified, are binding upon the licensee and shall apply to the construction and operation of the certified facility. If a conflict should occur between the design criteria of this project and the Conditions of Certification, the Conditions shall prevail unless amended or modified. I1. APPLICABLE RULES The construction and operation of the certified facility shall be in accordance with all applicable provisions of Florida Statutes and Department and Water Management District rules, including the following regulations: [Southwest Florida WMD: 40D-1, 40D-2, 40D-3, 40D-4, 40D-8,40D-21, 40D-40] 62-4, 62-17, 62-256, 62-296, 62-297, 62-301, 62-302, 62-531, 62-532, 62-550, 62-555, 62-560, 62-600, 62-601, 62-604, 62-610, 62-620, 62-621, 62-650, 62-699, 62-660, 62-701, 62-762, 62-767, 62-769, and 62-770, Florida Administrative Code (F.A.C.), or their successors as they are renumbered. Ill. DEFINITIONS The meaning of terms used herein shall be governed by the definitions contained in Chapter 403, Florida Statutes, and any regulation adopted pursuant thereto. In the event of any dispute over the meaning of a term used in these general or special conditions which is not defined in such statutes or regulations, such dispute shall be resolved by reference to the most relevant definitions contained in any other state or federal statute or regulation or, in the alternative by the use of the commonly accepted meaning as determined by the Department. As used herein: A. "Application" shall mean the Site Certification Application (SCA) for the certified facility, as supplemented. B. "DEP" or Department shall mean the Florida Department of Environmental Protection. C. "DHR" shall mean the Florida Department of State, Division of Historical Resources. D. "Emergency conditions" shall mean urgent circumstances involving Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification

potential adverse consequences to human life or property as a result of weather conditions or other calamity, and necessitating new or replacement gas pipeline, transmission lines, or access facilities. E. "Facility" shall mean the certified electrical power generation facility and all associated structures, including but not limited to: nuclear steam generating unit, fossil steam boilers, steam turbine generators, transformers, associated transmission lines, substations, fuel and water storage tanks, air and water pollution control equipment, storm water control ponds and facilities, cooling towers, ash landfill, coal pile and related structures. F. "Feasible" or "practicable" shall mean reasonably achievable considering a balance of land use impacts, environmental impacts, engineering constraints, and costs. G. "FFWCC" shall mean the Florida Fish and Wildlife Conservation Commission. H. "Licensee" means an applicant that has obtained a certification order for the subject project.

1. "NPDES permit" shall mean the federal National Pollutant Discharge Permit System permit issued in accordance with the federal Clean Water Act.

J. "Power plant" shall mean the electric power generating plant and associated structures to be modified or constructed on the certified site, as generally depicted in the Application. K. "Project" shall mean the Units 3, 4 and 5 electrical power generating facility and all associated facilities. L. "PSD permit" shall mean the federal Prevention of Significant Deterioration air emissions permit issued in accordance with the federal Clean Air Act. M. "SWFWMD" shall mean the Southwest Florida Water Management District. N. "Title V permit" shall mean the federal permit issued in accordance with Title V of the federal Clean Air Act IV. GENERAL CONDITIONS These General Conditions shall be applicable to all areas of the certified site. Compliance with the General Conditions shall be the joint responsibility of Progress Energy Nuclear Plant (Unit 3) and Progress Energy Fossil Fuel Plant (Units 4 and 5). Any violation of a General Condition shall be a violation by Progress Energy Florida. A. Facilities Operation

1. The Licensee shall at all times properly operate and maintain the facility and related appurtenances, and systems of treatment and control that are installed and used to achieve compliance with the conditions of this certification, and are required by Department rules. This provision includes the operation of backup or auxiliary facilities or similar systems when necessary to achieve compliance with the Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 2

conditions of the approval and when required by Department rules.

2. In the event of a prolonged [thirty (30) days or more] equipment malfunction or shutdown of pollution control equipment, facility operation may be allowed to resume and continue to take place 'under an appropriate Department order, provided that the licensee demonstrates that such operation will be in compliance with all applicable ambient air quality standards and PSD increments, water quality standards-and rules, solid waste rules, domestic wastewater rules and industrial wastewater rules. During such malfunction or shutdown, the operation of the facility shall comply with all other requirements of this certification and all applicable state and federal emission and effluent standards not affected by the malfunction or shutdown.

B. Records Maintained at the Facility

1. These Conditions of Certification or a copy thereof shall be kept at the work site of the approved activity.

2. The licensee shall hold at the facility, or other location designated by this approval, records of all monitoring information, including all calibration and maintenance records and all original strip chart recordings for continuous monitoring instrumentation required by this approval, copies of all reports required by this approval, and records of all data used to complete the application for this approval. These materials shall be retained at least three (3) years from the date of the sample, measurement, report, or application unless otherwise specified by Department rule.

The licensee shall provide copies of these records to the Department upon request. If the licensee becomes aware of relevant facts that were not submitted or were incorrect in any report to the Department, such facts or information shall be promptly submitted or corrected. C. Change in Discharge All discharges or emissions authorized herein shall be consistent with the terms and conditions of this certification. The discharge of any regulated pollutant not identified in the application, or more frequently than, or at a level in excess of that authorized herein, shall constitute a violation of the certification. Any anticipated facility expansions, production increases, or process modifications which may result in new, different or increased discharges or pollutants, change in fuel, or expansion in steam generating capacity must be reported by submission of an application for amendment or modification pursuant to Chapter 403.516, F.S. D. Noncompliance Notification If, for any reason, the licensee does not comply with or is unable to comply with any limitation specified in this certification, the licensee shall notify the Southwest District Office of the Department by telephone during the working day that said noncompliance occurs. After normal business hours, the licensee shall report any condition that poses a public health threat to the State Warning Point at telephone number (850) 413-9911 or (850) 413-9912. The licensee shall confirm this situation to the DEP District Office in writing within seventy-two (72) hours of becoming aware of such conditions and shall supply the following information: Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 3

1. A description of the discharge and cause of noncompliance; and,

2. The period of noncompliance, including exact dates and times; or, if not corrected, the anticipated time the noncompliance is expected to continue, and,

3. Steps being taken to reduce, eliminate and prevent recurrence of the non-complying event.

E. Adverse Impact The licensee shall take all reasonable steps to minimize any adverse impact resulting from noncompliance with any limitation specified in this certification, including such accelerated or additional monitoring as necessary to determine the nature and impact of the non-complying event. F. Right of Entry The licensee shall allow authorized Department personnel, including authorized representatives of the Florida Department of Environmental Protection, Water Management Districts, and/or United States Environmental Protection Agency, when applicable, upon presentation of credentials or other documents as may be required by law, and at reasonable times, and recognizing the security that must be maintained at the facility, depending upon the nature of the concern being investigated:

1. To enter upon the licensee's premises where an effluent source is located or in which records are required to be kept under the terms and conditions of this permit; and,

2. To have access to and copy any records required to be kept under the conditions of this certification; and,

3. To inspect and observe the permitted facilities, equipment, practices, or operations regulated or required under these Conditions to determine compliance with the approved plans, specifications and conditions of this certification;

and,

4. To sample or monitor any substances or parameters at any location necessary to assure compliance with these Conditions or Department rules.

G. Enforcement

1. The terms, conditions, requirements, limitations and restrictions set forth in these Conditions of Certification are binding and enforceable pursuant to Sections 403.141, 403.161, 403.514. Any noncompliance with a Condition of Certification or condition of a federally delegated or approved permit constitutes a violation of chapter 403, F.S., and is grounds for enforcement action, permit termination, permit revocation, or permit revision. The Licensee is placed on notice that the Department will review this approval periodically and may initiate enforcement action for any violation of these conditions.

2. All records, notes, monitoring data and other information relating to the construction or operation of this certified source which are submitted to the Department may be used by the Department as evidence in any enforcement case Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 4

involving the certified source arising under the Florida Statutes or Department rules, except where such evidence shall only be used to the extent it is consistent with the Florida Rules of Civil Procedure and appropriate evidentiary rules. H. Revocation or Suspension This certification may be suspended or revoked pursuant to Section 403.512, Florida Statutes, or for violations of any of these Conditions of Certification. This approval is valid only for the specific processes and operations identified within the application and indicated in the approved drawings or exhibits. Any unauthorized deviation from the approved drawings, exhibits, specifications, or conditions of this approval may constitute grounds for revocation and enforcement action by the Department. Any enforcement action, including suspension and revocation, shall only affect the certified facilities that are the cause of such action, and other facilities at the Crystal River Energy Complex shall remain unaffected by such action. I. Civil and Criminal Liability

1. This certification does not relieve the licensee from civil or criminal penalties for noncompliance with any conditions of this certification, applicable rules or regulations of the Department, or Chapter 403, Florida Statutes, or regulations thereunder.

2. This certification does not relieve the licensee from liability for harm or injury to human health or welfare, animal or plant life, or property caused by the construction or operation of this permitted source, or from penalties therefore; nor does it allow the licensee to cause pollution in contravention of Florida Statutes and Department rules, unless specifically authorized by an order from the Department.

3. As provided in Subsections 403.087(7), 403.511, and 403.722(5),

F.S., the issuance of this certification does not convey any vested rights or any exclusive privileges. Neither does it authorize any injury to public or private property or any invasion of personal rights, nor any infringement of federal, state, or local laws or regulations. This approval is not a waiver of any other Department approval that may be required for other aspects of the total project under federally delegated programs.

4. Subject to Section 403.511, Florida Statutes, this certification shall not preclude the institution of any legal action or relieve the licensee from any responsibilities or penalties established pursuant to any other applicable State Statutes or regulations.

J. Property Rights The issuance of this certification does not convey any property rights in either real or personal property, or any exclusive privileges, nor does it authorize any injury to public or private property or any invasion of personal rights, nor any infringement of Federal, State or local laws or regulations. The applicant shall obtain title, lease or right of use from the State of Florida, to any sovereign submerged lands utilized by the project. Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 5

K. Severability The provisions of this certification are severable, and if any provision of this certification, or the application of any provision of this certification to any circumstances, is held invalid, the application of such provision to other circumstances and the remainder of the certification shall not be affected thereby. L. Review of Site Certification The certification shall be final unless revised, revoked or suspended pursuant to law. At least every five years from the date of issuance of certification the Department will review all monitoring data that has been submitted to it during the preceding five-year period for the purposes of determining the extent of the Licensee's compliance with the conditions of this certification and the environmental impact of this facility. Such review will be repeated at least every five years thereafter. M. Procedural Rights Except as specified in Chapter 403, F.S., or Chapter 62-17, F.A.C., no term or condition of certification shall be interpreted to preclude the post-certification exercise by the licensee of whatever procedural rights it may have under Chapter 120, F.S., including those related to rule-making proceedings. N. Modification of Conditions The conditions of this certification may be modified in the following manner:

1. Pursuant to Subsection 403.516(1), Florida Statutes, the Siting Board hereby delegates to the Secretary of the Department of Environmental Protection the authority to modify, after notice and opportunity for hearing, any conditions herein which would not otherwise require approval from the Siting Board.

2. This certification shall be automatically modified to conform to any subsequent amendments, modifications, or renewals made by the Department under a federally delegated or approved program to any separately issued Prevention of Significant Deterioration (PSD) permit, Title V air permit, or National Pollutant Discharge Elimination System (NPDES) permit for the certified facility. The Permittee shall send each party to the original certification proceedings (at the party's last known address as shown in the record of such proceeding) notice of requests for modifications or renewals of the above listed permits if the request involves a new or modified relief mechanism (e.g., mixing zone, variance, etc.) from standards, a relaxation of conditions included in the permit due to state permitting requirements, or the inclusion of less restrictive air emission limitations in the air permits. The Department shall notify all parties to the certification proceeding of any intent to modify conditions under this section prior to taking final agency action.

3. All other modifications to these conditions shall be made in accordance with Section 403.516, Florida Statutes.

4. Any modification to these conditions shall only affect the units or other facilities that are the subject of the modification request or the Department's Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 6

proposed order of modification.

0. Transfer of Certification This certification is transferable only upon Department approval in accordance with Section 403.516, F.S., and Rules 62-17.211(3) and 62-730.300, F.A.C., as applicable. The licensee shall be liable for any noncompliance of the approved activity until the transfer is approved by the Department.

P. Safety The overall design, layout, and operation of the facilities shall be such as to minimize hazards to humans and the environment. Security control measures shall be utilized to prevent exposure of the public to hazardous conditions. The applicable Federal Occupational Safety and Health Standards shall be complied with during construction and operation. Q. Screening The Licensee shall provide screening of the site to the extent feasible through the use of aesthetically acceptable structures, vegetated earthen walls and/or existing or planted vegetation. R. Toxic, Deleterious or Hazardous Materials

1. The Licensee shall not discharge to surface waters wastes which are acutely toxic, or present in concentrations which are carcinogenic, mutagenic, or teratogenic to human beings or to significant locally occurring wildlife or aquatic species.

The Licensee shall not discharge to ground waters wastes in concentrations which, alone or in combination with other substances, or components of discharges (whether thermal or non-thermal) are carcinogenic, mutagenic, teratogenic, or toxic to human beings (unless specific criteria are established for such components in Section 62-520.420, F.A.C.) or are acutely toxic to indigenous species of significance to the aquatic community within surface waters affected by the ground water at the point of contact with surface waters.

2. The licensee shall report all spills of materials having potential to significantly pollute surface or ground waters and which are not confined to a building or similar containment structure, by telephone immediately after discovery of such spill.

The licensee shall submit a written report within forty-eight hours, excluding weekends, from the original notification. The telephone report shall be submitted by calling the DEP District Office Industrial Wastewater Compliance/Enforcement Section. After normal business hours, the licensee shall contact the State Warning Point by calling (850) 413-9911 or (850) 413-9912. The written report shall include, but not be limited to, a detailed description of how the spill occurred, the name and chemical make-up (include any MSDS sheets) of the substance, the amount spilled, the time and date of the spill, the name and title of the person who first reported the spill, the size and extent of the spill and surface types (impervious, ground, water bodies, etc.) it impacted, the cleanup procedures used and status of completion, and include a map or aerial photograph showing the extent and paths of the material flow. Any deviation from this requirement must receive prior approval from the Department. Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 7

S. Noise Construction noise shall not exceed noise criteria or any applicable requirements of Citrus County. T. Flood Control Protection Any new facilities for the certified facilities or associated facilities shall be constructed in such a manner as to comply with the appropriate County flood protection requirements, which may include flood proofing or raising the elevation of the new or expanded facilities above the 100-year flood level. However, existing facilities are not required to be modified to comply with such flood control protection standards. U. Historical or Archaeological Finds If historical or archaeological artifacts, such as Indian canoes, are discovered at any time within the certified site, the licensee shall notify the DEP District office and the Bureau of Historic Preservation, Division of Historical Resources, R.A. Gray Building, Tallahassee, Florida 32399, telephone number (850) 487-2073. V. Endangered and Threatened Species Prior to start of construction, the licensee shall survey the portion of the certified site which may be affected by construction for endangered and threatened species of animal and plant life. Plant species listed as endangered or threatened by the federal government and plant species listed as endangered by the state shall be transplanted to an appropriate area if practicable. Gopher tortoises and any commensals on the rare or endangered species list shall be relocated after consultation with the FFWCC. A relocation program, as approved by the FFWCC, shall be followed. Entombment of gopher tortoises shall not be allowed. W. Dispute Resolution If a situation arises in which mutual agreement cannot be reached between the Licensee and an agency exercising its regulatory jurisdiction under these conditions, then the matter shall be immediately referred to the Division of Administrative Hearings (DOAH) for disposition in accordance with the provisions of Chapter 120, F.S. X. Laboratories And Quality Assurance

1. The licensee shall ensure that all laboratory analytical data submitted to the Department, as required by this Certification, are from a laboratory which has a currently valid and Department approved Comprehensive Quality Assurance Plan (CompQAP) or a CompQAP pending approval for all parameters being reported, as required by Chapter 62-160, F.A.C.

2. The licensee shall ensure that all samples required pursuant to this certification are taken by an 'appropriately trained technician following EPA and Department approved sampling procedures and chain-of-custody requirements in accordance with Rule 62-160, F.A.C. All chain-of-custody records shall be retained on-site for at least three (3) years and made available to the Department immediately upon Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 8

request.

3. Records of monitoring information shall include:

the date, exact place, and time of sampling or measurements; a) the person responsible for performing the sampling or measurements; b) the dates analyses were performed; c) the person responsible for performing the analyses; d) the analytical techniques or methods used; and, e) the results of such analyses. Y. Procedures For Post-Certification Submittals

1. The licensee shall provide within 90 days after certification a complete summary of those submittals identified in the Conditions of Certification where due-dates for information required of the licensee are identified. Such submittals shall include, but are not limited to, monitoring reports, management plans, wildlife surveys, etc. The summary shall be provided to the Siting Coordination Office and any affected agency or agency subunit to whom the submittal is required to be provided, in a sortable spreadsheet, via CD and hard copy, in the format identified below or equivalent. (62-17.191, F.A.C.)

Condition Requirement and timeframe Due Date Name of Agency or Number agency subunit to whom the submittal is required to be provided

2. Purpose of Submittals: Conditions of Certification which provide for the post-certification submittal of information to DEP or other agencies by the licensee are for the purpose of facilitating monitoring by the Department of the effects arising from the certified facilities. This monitoring is for DEP to assure, in consultation with other agencies with applicable regulatory jurisdiction, continued compliance with the conditions of certification, without any further agency action.

3. Filings: All post-certification submittals of information by the licensee or copies of applications for separate federal permits which are to be issued by Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 9

State agencies are to be filed with DEP Siting Office. Copies of each submittal shall also be simultaneously copied to any other agency indicated in the specific conditions requiring the post-certification submittals.

4. Completeness: The DEP shall promptly review each post-certification submittal for completeness. This review shall include consultation with the other agencies receiving the post-certification submittal. For the purposes of this condition, completeness shall mean that the information submitted is both complete and sufficient. If the submittal is found to be incomplete, the licensee shall be so notified.

Failure to issue such a notice within forty-five (45) days after filing of the submittal shall constitute a finding of completeness. (62-17.191, F.A.C.)

5. Interagency Meetings: Within sixty (60) days of the filing of a complete post-certification submittal, DEP may conduct an interagency meeting with other agencies which received copies of the submittal. The purpose of such an interagency meeting shall be for the agencies with regulatory jurisdiction over the matters addressed in the post-certification submittal to discuss whether reasonable assurance of compliance with the conditions of certification has been provided. Failure of any agency to attend an interagency meeting shall not be grounds for DEP to withhold a determination of compliance with these conditions nor to delay the time frames for review established by these conditions.

6. Reasonable Assurance of Compliance: Within ninety (90) days of the filing of a complete post-certification submittal, unless another date is specified herein, DEP shall give written notification to the licensee and the agencies to which the post-certification information was submitted of its determination whether there is reasonable assurance of compliance with the conditions of certification. If it is determined that reasonable assurance has not been provided, the licensee shall be notified with particularity and possible corrective measures suggested. Failure to notify the licensee in writing within ninety (90) days of receipt of a complete post-certification submittal shall constitute a determination of reasonable assurance of compliance.

Z. Potable Water Supply System The potable water supply system shall be designed and operated in conformance with Chapter 17-22, FAC. Information as required in 17-22.05 shall be submitted to the Department prior to construction and operation. The operator of the potable water supply system shall be certified in accordance with Chapter 17-23, FAC. Potable water for Unit 3 shall continue to be provided by the separate potable water treatment system operated by Units 1 and 2. V. CONSTRUCTION A. Standards and Review of Plans

1. All construction at the certified facility shall be pursuant to the design standards presented in the application or amended application and the standards or plans and drawings submitted and signed by an engineer registered in the state of Florida. Specific Southwest DEP District Office acceptance of plans will be required based upon a determination of consistency with approved design concepts, Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 10

regulations, and these conditions prior to initiation of construction of any: industrial waste treatment facility; domestic waste treatment facility; potable water treatment and supply system; ground water monitoring system, storm water runoff system; solid waste disposal area; and hazardous or toxic handling facility or area. The Licensee shall present specific plans for these facilities for review by the DEP Southwest District Office at least ninety (90) days prior to construction of those portions of the facility for which the plans are then being submitted, unless other time limits are specified in the following conditions herein. Review and approval or disapproval shall be accomplished in accordance with Chapter 120, F.S., or these conditions of certification as applicable. The licensee shall not proceed with construction without a written authorization from the Department.

2. The Department must be notified in writing and prior written approval obtained for any material change, modification, or revision to be made to the project during construction which is in conflict with these conditions of certification. If there is any material change, modification, or revision made to a project approved by the Department without this prior written approval, the project will be considered to have been constructed without departmental approval, the construction will not be cleared for service, and the construction will be considered a violation of the conditions of certification.

3. Ninety (90) days prior to the anticipated date of first operation, the Licensee shall provide the Southwest District and the Siting coordination Office of the Department with an itemized list of any changes made to the facility design and operation plans that would affect a change in discharge as referenced in Condition IV.C.

since the time of the approval of these conditions. This pre-operational review of the final design and operation shall demonstrate continued compliance with Department rules and standards.

4. Final drainage plans illustrating any new or modified stormwater treatment facilities and conveyances for construction phases of the certified facility site shall be submitted to the DEP Southwest District Manager and the SWFWMD as applicable for review and approval prior to construction of any such conveyance or facility. The Department shall indicate its approval or disapproval within 60 days of the submittal. Analysis report of the produced ground samples shall be submitted 30 days before surface water discharge begins.

B. Control Measures During construction and plant operation, necessary measures shall be used to settle, filter, treat or absorb silt containing or pollutant laden stormwater runoff to limit the suspended solids to 50 mg/1 or less at the POD during rainfall periods not less than the 10-year, 24-hour rainfall, and to prevent an increase in turbidity to more than 50 Jackson Turbidity Units above background in waters of the State. Control measures shall consist at the minimum, of filters, sediment traps, barriers, berms or vegetative planting. Exposed or disturbed soil shall be protected as soon as possible to minimize silt and sediment laden runoff. The pH shall be kept within the range of 6.0 to 8.5, after opportunity for reasonable mixing as defined in II.A.8. Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 11

Any open burning in connection with initial land clearing shall be in accordance with Chapter 62-256, F.A.C., Chapter 51-2, F.A.C., Uniform Fire Code Section 33.101 Addendum, and any other applicable County regulation. Any burning of construction-generated material, after initial land clearing that is allowed to be burned in accordance with Chapter 62-256, F.A.C., shall be reviewed by the DEP Southwest District office in conjunction with the Division of Forestry and any other county regulations that may apply. Burning shall not occur if not approved by the appropriate agency or if the Department or the Division of Forestry has issued a ban on burning due to fire safety conditions or due to air pollution conditions. Disposal of sanitary wastes from construction toilet facilities shall be in accordance with applicable regulations of the appropriate local health agency. The sewage treatment plant shall be operated in accordance with Chapters 17-3, 17-16, and 17-19, F.A.C. Solid wastes resulting from construction shall be disposed of in accordance with the applicable regulations of Chapter 62-701, F.A.C. Construction noise shall not exceed noise criteria or any applicable requirements of Citrus County. To mitigate the effects of noise produced by any steam blowout of steam boiler tubes, the licensee shall conduct reasonable public awareness campaigns prior to such activities to forewarn the public that may be affected by the noise of the estimated time and duration of the noise. The licensee shall employ proper odor and dust control techniques to minimize odor and fugitive dust emissions. The applicant shall employ control techniques sufficient to prevent nuisance conditions which interfere with enjoyment of residents of adjoining property. Directly associated transmission lines from the facility electric switchyard to existing transmission lines shall be maintained in accordance with the application and the appropriate state and federal regulations concerning use of herbicides. The Licensee shall notify the Department of the type of herbicides to be used at least 60 days prior to their first use. The licensee shall develop the site so as to retain the buffer of natural vegetation as described in the Units 4 and 5 application and in Condition IV.Q. Screening. Dewatering operations during construction shall be carried out in accordance with Rule 62-621.300(2), F.A.C. C. Environmental Control Program An environmental control program shall be established under the supervision of a Florida registered professional engineer or other qualified person to assure that all construction activities conform to applicable environmental regulations and the applicable conditions of certification. If a violation of standards, harmful effects or irreversible environmental damage not anticipated by the application or the evidence presented at the certification hearing are detected during construction, the Licensee shall notify the DEP Siting Office and Southwest District Office as required by Condition Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 12

IV. D., Noncompliance Notification. D. Reporting Notice of commencement of construction shall be submitted to the Siting Coordination Office and the DEP Southwest District Office within fifteen (15) days of initiation. Starting three (3) months after construction commences, a quarterly construction status report shall be submitted to the DEP Southwest District Office. The report shall be a short narrative describing the progress of construction. E. Construction in Waters of the State No construction on sovereignty submerged lands shall commence without obtaining lease or title from the Department of Environmental Protection Natural Resources. Construction of intake and discharge structures should be done in a manner to minimize turbidity. Sheet piles or turbidity screens should be used if necessary to prevent turbidity in excess of 50 JTU above background beyond 150 meters from the POD and/or construction site. F. Transformer and Electric Switching Gear The foundations for any new or modified transformers, capacitors, and switching gear necessary for Crystal River Units 3, 4 and 5 to connect to the existing transmission system shall be constructed of an impervious material and shall be constructed in such a manner to allow complete collection and recovery of any spills or leakage of oily, toxic, or hazardous substances. VI. UNIT 4 & UNIT 5 SPECIFIC CONDITIONS The following Specific Conditions shall apply only to Unit 4 and Unit 5. Compliance with these Specific Conditions shall be the responsibility of Progress Energy (Fossil). A. Air The construction and operation of the Units No. 4 and 5 at the Crystal River steam electric plant site shall be in accordance with all applicable provisions of the Chapters 62-210 through 62-297, and 62-702, Florida Administrative Code. Title V Air Operation Permit 0170004-015-AV, Air Construction Permits 0170004-013-AC and 0170004-014-AC (including subsequent modifications), and PSD permit PSD-FL-383 (including subsequent modifications) are inicorporated by reference herein as part of this Certification and attached as Appendix A through Appendix D. The provisions of the above shall be conditions of this certification. The licensee shall comply with the substantive provisions and limitations set forth in Title V Air Operation Permit Number 0170004-015-AV, Air Construction Permits 017004-013-AC and 017004-014-AC, and PSD permit PSD-FL-383 as part of these Conditions of Certification, and as those provisions may be modified, amended, or renewed in the future by the Department. Such provisions shall be fully enforceable as conditions of this certification. Any violation of such provisions shall be a violation of these Conditions of Certification. Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 13

In addition to the foregoing, the Licensee shall comply with the following specific conditions of certification: Note that Sections 2 and 3 below (in italics) will be automatically deleted once a Title V permit is issued signifying the successful start-up and operation of the flue gas desulfurization system:

1. Reporting a) For each unit, stack monitoring, fuel usage and fuel analysis data shall be reported to the Department on a quarterly basis commencing with the start of commercial operation in accordance with 40 CFR, Part 60, Section 60.7, and in accordance with Section 17-2.08, FAC.

b) Ambient air monitoring data shall be reported to the Department quarterly commencing on the date of certification by the last day of the month following the quarterly reporting period utilizing the SAROAD or other format approved by the Department in writing. c) Beginning one month after certification the licensee shall submit to the Department a quarterly status report briefly outlining progress made on engineering design and purchase of major pieces of equipment (including control equipment). All reports and information required to be submitted under this condition shall be submitted to the Administrator of Power Plant Siting, Department of Environmental Regulation, 2600 Blair Stone Road, Tallahassee, Florida 32301.

2. Coal Characteristicsand Contracts Before approval can be grantedby the Departmentfor use of control devices, characteristicsof the coal to be fired must be known. Therefore, before these approvals are granted, the licensee must submit to the Departmentcopies of coal contracts which should include the expected sulfur content, ash content, and heat content of the coal to be fired. These data will be used by the Departmentin its evaluation of the adequacy of the control devices. Also, the licensee must demonstrate the ability to acquire a low sulfur coal supply of sufficient length to enable the installation of sulfur removal equipment if the supplies of low sulfur coal should not become available or be discontinued. Therefore, the coal contractsmust be for a period of at least five (5) years from the date of start-up of the boiler.

3. Coal Information As an alternative to the submittal of contracts for purchase of coal under condition E above, the licensee may submit the following information:

a) The name of the coal supplier; b) The sulfur content, ash content, and heat content of the coal as specified in the purchase contracts; c) The location of the coal deposits covered by the contract (including mine name and seam); d) The date by which the first delivery of coal will be made; e) The duration of the contract; and Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 14

0 An opinion of counsel for the licensee that the contracts are legally binding.

4. Natural Gas Natural Gas may be used as a startup and low-load flame stabilization fuel in Unit 4 and Unit 5.

B. Water Discharges Any discharges into any waters of the State during construction and operation of the Units 4 & 5 shall be in accordance with all applicable provisions of Chapter 17-3, Florida Administrative Code and 40 CFR 423, Effluent Guidelines and Standardsfor Steam Electric Power GeneratingPoint Source Category and with NPDES permit no. FL 0036366-006-1W1 S/NR (attached as Appendix F) as well as any subsequent modifications, amendments and/or renewals. Also, the Licensee shall comply with the following conditions of certification:

1. PlantEffluents and Receiving Body of Water For discharges made from the power plant the following conditions would apply:

a) Receiving Body of Water (RBW) The receiving body of water will be determined by the Department to be those waters affected which are considered to be waters of the State within the definition of Chapter 403, Florida Statutes. b) Point of Discharge (POD) The point of discharge will be determined by the Department to be where the effluent physically enters the waters of the State. c) Thermal Mixing Zone The zone of thermal mixing for cooling tower blowdown shall not extend beyond the western end of the north bank of the existing discharge canal. During discharge, the blowdown from the cooling tower for Units No. 4 & 5 shall be withdrawn at the point of lowest temperature of the recirculating cooling water prior to the addition of makeup water. d) Chemical Wastes and Boiler Blowdown All discharges of low volume wastes (demineralizer regeneration, cooling tower basin cleaning wastes, floor drainage, sample drains and similar wastes), metal cleaning wastes (including preheater and fireside wash) and boiler blowdown shall comply with Chapter 17-3. If violations of Chapter 17-3 occur, corrective action shall be taken. These wastewaters shall be discharged to an adequately sized and constructed percolation pond. e) Coal Pile and Ash Landfill Runoff Coal pile runoff and ash landfill runoff from less than 10-year 24-hour rainfall shall be treated if required by Special Condition IV.F.8. and discharged Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 15

to an adequately sized and constructed percolation ditch system. f) Cooling Tower Blowdown The cooling tower blowdown shall contain no detectable amounts of materials added for corrosion inhibition, unless prior approval for use of such material has been granted by the Department upon demonstration that the discharge is not toxic to aquatic life, does not contain priority pollutants and will not result in pollutant concentrations in excess of water quality standards. g) Chlorine The quantity of free available chlorine discharged in the blowdown from the cooling tower shall not exceed 0.5 mg/I at any one time and shall not exceed 0.2 mg/I as an average. Neither free available chlorine nor total residual chlorine may be discharged from either unit for more than two hours in any one day and Units 4 or 5 may not discharge chlorine while any other unit is discharging chlorine. h) pH The pH of all discharges shall be such that the pH of water in the discharge canal shall be within the range of 6.0 to 8.5, at a distance of 150 meters from the POD into the canal. i) Polychlorinated Biphenyl Compounds There shall be no discharge of polychlorinated biphenyl compounds. C. Water Monitoring Programs The Licensee shall monitor and report to the Department the listed parameters on the basis specified herein. The methods and procedures utilized shall receive written approval by the Department. The monitoring program may be reviewed' annually by the Department, and a determination may be made as to the necessity and extent of continuation, and may be modified in accordance with Condition N of the General Conditions of Certification.

1. Chemical Monitoring The following parameters shall be monitored as shown during discharge commencing with the start of commercial operation of the first unit and reported quarterly to the Department:

Parameter Location Sample Type Frequency Flow, Groundwater Well field Pipeline Recorder Totalizer Flow, Discharge C.T. Outfall* Recorder Totalizer Conductivity C.T. Outfall Recorder Continuous pH C.T. Outfall Grab** Daily Temperature C.T. Outfall Recorder Continuous Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 16

TDS C.T. Outfall Grab Weekly Total Residual Oxidants C.T. Outfall Recorder Continuous

Cooling Tower Outfall Pipe
- Representative Sample

2. GroundwaterMonitoring a) The groundwater levels shall be monitored continuously at wells as approved by Southwest Florida Water Management District. Chemical analyses shall be made on samples from all monitored wells identified in Condition III.F.

below. The location, frequency and selected chemical analyses shall be as given in Condition III.F. b) The groundwater monitoring program shall be implemented at least one year prior to operation of Crystal River No. 4. The chemical analyses shall be in accord with the latest edition of Standard Methods for the Analysis of Water and Wastewater. The data shall be submitted within 30 days of collection/analysis to the Southwest Florida Water Management District (SWFWMD) and to the DEP Southwest District Office. c) Conductivity and heavy metals shall be monitored in wells around all ash disposal sites and coal piles. D. Percolation Pond Monitoring Requirements

1. Upon beginning operation of the coal pile runoff and leachate treatment system, the licensee shall sample and analyze the wastewater in the percolation pond for the following parameters on a quarterly basis: pH, specific conductance, total recoverable arsenic, total recoverable barium, total chlorides, total recoverable iron, total recoverable magnesium, total recoverable sodium, total dissolved solids, total recoverable vanadium, and total recoverable zinc. Results shall be submitted in accordance with Condition VI.D.3 below.

2. Ifthe appropriate primary ground water quality criteria specified in Chapter 62-520, Florida Administrative Code (F.A.C.) is not met in the percolation pond for the parameters listed in Condition VI.D.1., the Department shall re-evaluate the licensee's current monitoring requirements and may require the licensee to submit a proposed ground water monitoring plan in accordance with Rule 62-522.600, F.A.C., for this percolation pond system.

3. Effluent monitoring test results shall be submitted on Part A of DEP Form 62-620.910(10) (Attachment 3). Results shall be submitted with the DMR for each month listed in the following schedule.

Sample Period Report Due Date January - March April 28 April - June July 28 July - September October 28 Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 17

October - December I January 28

4. The permittee shall make copies of the attached DMR form(s) and shall submit the original completed DMR form(s) to the Siting Office and a copy to the Department's SWD, Industrial Wastewater Program.

E. FGD Scrubber Blowdown FGD scrubber blowdown wastewater shall be discharged to treatment systems outside of the Unit 4 & 5 Certified area. Any such receiving treatment system shall be permitted in accordance with all applicable requirements. F. Southwest Florida Water Management District (SWFWMD) - Groundwater

1. Withdrawal Quantitiesand Facilities Water Allocation Average Well Casing/Depth District ID/Owner ID Gallons per Day Feet STATUS I/PW-1 250,000 35/200 EXISTING 2/PW-2 250,000 47/200 EXISTING 3/PW-3 250,000 60/200 EXISTING 4/PW-4 250,000 41/200 EXISTING 5/PW-5 521,520 35/200 EXISTING 6/PW-6 521,520 50/200 EXISTING 7/PW-7 521,520 50/200 EXISTING 14/PW-8 521,520 50/200 PROPOSED 15/PW-9a 521,520 50/200 PROPOSED 16/PW-10a 521,520 50/200 PROPOSED Total All Wells 4,309,000

2. Submit Reports/Data All reports and data required by these conditions of certification shall be submitted to the SWFWMD according to the due dates contained in the specific condition. If the report or data is received on or before the tenth day of the month following data collection, it shall be deemed as a timely submittal. The Licensee may use the SWFWMD's website to submit data, plans or reports online. To set up an account, the Licensee can address the request to permitdata@watermatters.org. All mailed reports and data are to be sent to:

Permit Data Section, Regulation Performance Management Department Southwest Florida Water Management SWFWMD Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 18

2379 Broad Street Brooksville, Florida 34604-6899 Submission on plans and reports: Unless submitted online or otherwise indicated in the special condition, the original and two copies of each plan and report required herein. Submission of Data: Unless submitted online or otherwise indicated in the special condition, an original (no copies) is required for data submittals such as meter readings and/or pumpage, rainfall, water level, evapotranspiration, or water quality data.

3. EnvironmentalImpacts, Monitoring, and Mitigation:

EnvironmentalAssessment

a. Environmental Monitoring Plan Licensee shall submit an Environmental Monitoring Plan for SWFWMD review and approval within 90 days of conditions of certification issuance.

The monitoring plan, at a minimum shall utilize the SWFWMD's Wetland Assessment Procedure to evaluate the relative condition of surface waters and wetlands in areas affected by water withdrawals of Licensee. Upon SWFWMD approval, the plan shall be implemented and monitoring reports shall be provided in the annual monitoring report required by Condition No. C.6. After two years of monitoring following groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, the Licensee may request the SWFWMD release the Licensee from monitoring. If the SWFWMD concurs with the request, the SWFWMD will request DEP modify the conditions of certification to remove the monitoring condition.

b. Data Collection:

Licensee shall maintain and monitor the environmental monitoring sites included in the approved monitoring plan. Water levels for monitor wells and staff gauges for the sites included in the monitoring plan shall be referenced to National Geodetic Vertical Datum (NGVD) and reported in a form acceptable to the SWFWMD by the 10th day of each month for the preceding month. The time and date that the elevation is taken shall be included. Any changes to the methods or frequency of monitoring for any of these data collection programs must be approved by the SWFWMD.

c. Staff Gauges:

Licensee shall install and thereafter maintain SWFWMD-approved staff gauges and shall report measurements of water levels, as indicated in the monitoring plan. Water levels shall be recorded and reported to the SWFWMD on or before the tenth day of the following month. To the maximum extent possible, water levels shall be recorded as indicated in the monitoring plan. The frequency of recording may be modified by the SWFWMD as necessary to ensure protection of the resource. Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 19

d. Rain Gauges:

Licensee shall maintain a continuous recording rain gauge within the area. Total daily rainfall shall be recorded at this station and submitted to the SWFWMD (on SWFWMD forms or on line) on or before the tenth day of the following month. The reporting period for these data shall begin on the first day of each month and end on the last day of each month.

e. Data Handling:

Licensee shall monitor water levels in the monitor wells and piezometers as specified in the monitoring plan. Reports of the data shall be submitted to the SWFWMD in a form acceptable to the SWFWMD. All data shall be referenced to NGVD. The frequency of water-level recording may be modified by the SWFWMD as necessary to ensure the protection of the resource.

f. Annual Environmental Monitoring Reports Licensee shall submit an annual environmental monitoring data summary by January 1st of each year for the preceding water year (October 1 -

September 30). The Annual Monitoring Report shall include all raw data, essential graphs, tables, and text. Monitoring progress at each site shall be summarized in the Annual Monitoring Report, as specified below. Licensee shall submit three copies of the Annual Monitoring Report each year. Interpretive reports of wellfield environmental conditions shall incorporate all environmental monitoring sites used. The Annual Monitoring Report shall assess relationships between water level fluctuations, well pumpage, atmospheric conditions, and drainage factors related to the environmental condition of the wetlands and surface waters in the vicinity of the conditions of certification area. Pumpage data, wetland, water level data collected from the aquifer and for the region, and environmental parameters collected at the wellfield and in the. region shall be used for the report results. Statistical trend analysis, such as double-mass curve analysis, multiple linear regression, time series analysis and/or factor analysis shall be performed to analyze the interactions of rainfall and pumpage on surficial water levels, potentiometric levels in the semi-confined aquifers, surface waters, and wetland water levels, rate of soil subsidence, and evidence of vegetational succession. Data shall be obtained through field measurements and aerial photo interpretation. A brief summary of any recommended changes to the monitoring requirements shall be provided.

4. Alternative Water Supply Implementation The Licensee shall investigate the development of one or more alternative water supply projects to supply the water supply demands to offset all or a portion of the groundwater allocated by these conditions of certification. Alternative water supplies include seawater desalination, brackish surface or ground water, water that has been reclaimed after one or more uses, stormwater, and any other water supply source designated as non-traditional for a water supply planning region in the applicable regional water supply plan. Unless the Environmental Monitoring specified in Condition 2. above and the aquifer performance testing indicate that adverse environmental impacts are not occurring and are not predicted to occur, the Licensee Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 20

shall either mitigate impacts in accordance with a plan accepted by the SWFWMD, or, select and implement an alternative water supply project, in accordance with the following schedule: a.. Within 6 months of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, the Licensee shall submit for SWFWMD approval, an Alternative Water Supply Plan. The Alternative Water Supply Plan shall evaluate, identify, and propose alternative water supply development of at least three million two hundred thousand (3,200,000) gallons per day (gpd).

b. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, Licensee shall submit to SWFWMD, a preliminary design of the approved alternative water supply project that the Licensee will implement.

c. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, the Licensee shall provide an analysis of environmental conditions as specified in Condition C. above. If SWFWMD determines that adverse environmental impacts are not occurring and not predicted to occur, the Licensee may seek an extension of time or waiver for implementing the alternative water supply project. If SWFWMD determines that adverse environmental impacts are occurring or are predicted to occur, the alternative water supply project schedule must be maintained. If adverse environmental impacts are occurring or predicted to occur, the alternative water supply quantity required to be developed will be determined based upon a revised hydrogeologic evaluation performed by the Licensee and accepted by SWFWMD.

d. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, submit to the Florida Department of Environmental Protection and SWFWMD, applications for authorization to develop and use at least 3,200,000 gpd of water from the project as appropriate, unless an extension of time or waiver has been granted by SWFWMD.

e. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, submit to SWFWMD an alternative water supply implementation schedule detailing the dates when construction will begin and end, and the date when water will be delivered from the project for use by the Licensee. In no event shall the time when water is supplied by the project be more than more than 4 years after groundwater use has risen to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, unless an extension of time for just cause or otherwise modified in writing by SWFWMD has been granted by SWFWMD.

Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 21

f. Compliance with the Alternative Water Supply Implementation Schedule is required by the Licensee, unless extended or otherwise modified in writing by SWFWMD. Each year, by March 1, after the water use triggers described above, the Licensee shall submit to SWFWMD a status report describing the progress made on the Alternative Water Supply Implementation Schedule, including the specific actions taken to meet the requirements set forth above. If the project has fallen behind schedule, Licensee shall provide just cause for the delay and/or explain how the Licensee will comply with the schedule described herein.

5. Compliance Reporting The Licensee shall submit a compliance report beginning January 28, 2013 and at 5 year intervals after the issuance date of these conditions of certification. The report must contain sufficient information to demonstrate reasonable assurance that the withdrawals and use of water authorized by these conditions of certification continue to meet the substantive requirements set forth in Chapter 40D-2, F.A.C., and SWFWMD's Water Use Permit Information Manual Part B, Basis of Review.

The compliance report must include:

a. Information documenting water demands and updated demand projections demonstrating that allocations from all sources in the conditions of certification will continue to be needed for the remainder of the conditions of certification duration;

b. Documentation verifying that the sources are capable of supplying the needs authorized by these conditions of certification without causing harm to water and water-related resources;

c. Documentation verifying that the use of water is efficient and that the Licensee is implementing all feasible water conservation measures;

e. An updated ground water modeling analysis and data analysis demonstrating that the use of groundwater does not interfere with legal uses existing at the time of issuance of this modification of the conditions of certification;

f. An updated ground water modeling analysis, along with statistical analyses of water-level and wetland monitoring data, demonstrating that the use does not cause adverse impacts to wetlands, and surface waters, or violations of MFLs;

g. Documentation that ground water withdrawals by the Licensee are not causing or contributing to significant saltwater intrusion, including but not limited to review and statistical analyses of groundwater level and water quality data collected by the Licensee under these conditions of certification;

h. Information demonstrating that the lowest quality source of water is being used to meet the water demands.

Following review of this report, SWFWMD may seek modification of the conditions of certification to ensure that the use continues to meet the substantive conditions for the consumptive use of water as set forth in Section 373.223, F.S., and Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 22

Chapter 40D-2, F.A.C.

6. Pumpage Reporting Licensee shall meter withdrawals and record meter readings from each withdrawal point and water supply line on a monthly basis within the last week of the month. The meter readings shall be reported to the SWFWMD on or before the tenth day of the following month. If a metered withdrawal is not utilized during a given month, the meter report shall be submitted to the SWFWMD indicating the same meter reading as was submitted the previous month. The following withdrawals shall be metered:

Withdrawal facilities that are not yet constructed shall install meters on SWFWMD ID Nos. 5, 6, 7,14,15,16, Licensee ID Nos. PW-5, PW-6, PW-7, PW-8, PW-9a, PW-10a, within 90 days of completion of construction of the withdrawal facilities. Licensee shall continue to maintain and operate existing, non-resettable, totalizing flow meters or other flow measuring devices as approved by the Brooksville Regulation Department Director on SWFWMD ID Nos. 1, 2, 3, 4, Licensee ID Nos. PW-1, PW-2, PW-3, PW-4. All meters shall adhere to the following descriptions and shall be installed and maintained as follows:

a. The meters shall be non-resettable, totalizing flow meters with totalizers of sufficient capacity to retain total gallon data for a minimum of the three highest consecutive months. If other measuring devices or other accounting methods are proposed, Licensee shall submit documentation that the other measuring devices or accounting method meet the stipulations listed in this condition, prior to installation.

Approval for other measuring devices or accounting methods shall be obtained in writing from the Brooksville Regulation Department Director.

b. Flow meters or other approved devices shall have and maintain accuracy within five percent of the actual flow as installed.

c. The flow meter-water piping system shall be designed for inline field access for meter accuracy testing. The meter shall be tested for accuracy on-site, as installed, every five years beginning from the date of its installation for new meters or from the date of initial issuance of these conditions of certification containing the metering condition with an accuracy-test requirement for existing meters, unless Licensee submits documentation to the satisfaction of the SWFWMD that a longer period of time for testing is warranted. The test shall be performed by a person certified to use the test equipment. Ifthe actual flow is found to be greater than five percent different from the measured flow, within 30 days, Licensee shall have the meter re-calibrated, repaired, or replaced. Documentation of the test and a certificate of re-calibration, if applicable, shall be submitted within 30 days of each test or recalibration.

If the accounting method involves a meter belonging to another entity or to the water supplier, Licensee shall submit documentation from the owner/ supplier that the meter readings continue to be accurate to five percent of the actual flow as installed. Such Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 23

documentation is subject to approval by the SFWMD.

d. The meter shall be installed according to the manufacturer's instructions for achieving accurate flow to the specifications above, or it shall be installed in a straight length of pipe with at least an upstream length equal to ten times the outside pipe diameter and a downstream length equal to two times the outside pipe diameter. If sufficient pipe length is not available, flow straightening vanes shall be used in the upstream line.

e. If the meter or other flow measuring device malfunctions or has to be removed from the water supply line for maintenance or repair, Licensee shall notify the SWFWMD within 30 days of discovery and replace it with a repaired or new meter, subject to the same specifications given above. The repaired or replacement meter shall be installed within 30 days of discovery. If the meter is removed for any other reason, it shall be replaced with another meter having the same specifications given above, or the meter shall be reinstalled within 30 days of its removal. In either event, a fully functioning meter shall not be off the water supplies line for more than 60 consecutive days.

f. While the meter is being repaired or replaced, Licensee shall provide an estimate of the water supply quantities used by multiplying the number of hours the water supply was used by the capacity of the pump or mainline diameter. The estimate of the number of gallons used each month during that period shall be noted as an estimate when it is submitted to theSWFWMD.

g. In the event a new meter is installed to replace a broken meter, the replacement meter and its installation shall meet the specifications of this condition. Licensee shall notify the SWFWMD of the replacement with the first submittal of meter readings from the new meter.

7. DistributionFlexibility The average day, peak monthly, and maximum daily, if applicable, quantities for District ID No(s) 1, 2, 3, 4, 5, 6,7, 14, 15, 16 Licensee ID No(s). PW-1, PW-2, PW-3, PW-4, PW-5, PW-6, PW-7, PW-8, PW-9a, PW-10a shown above in the production withdrawal table are estimates based on historic and projected distribution of pumpage, and are for water use inventory and impact analysis purposes. The quantities listed in the table for these individual sources are not intended to dictate the distribution of pumpage from the withdrawal sources. The Licensee may make adjustments in pumpage distribution as necessary up to 125 percent on an average basis, up to 125 percent on a peak monthly basis, so long as adverse environmental impacts do not result and other conditions of this certification are complied with. In all cases, the total average annual daily withdrawal and the total peak monthly daily withdrawal are limited to the quantities set forth above.

8. Water quality sampling

a. Water quality samples shall be collected and analyzed for parameters and at the frequencies specified below. Water quality samples from production wells shall be collected from all wells, unless infeasible. If sampling is Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 24

infeasible, Licensee shall indicate the reason for not sampling on the water quality data form. Water quality samples shall be analyzed by a laboratory certified by the Florida Department of Health utilizing the standards and methods applicable to the parameters analyzed and to the water use pursuant to Chapter 64E-1, Florida Administrative Code, "Certification of Environmental Testing Laboratories". At a minimum, water quality samples shall be collected after pumping the well at its normal rate for a pumping time specified in the table below, or to a constant temperature, pH, and conductivity. In addition, Licensee's sampling procedure shall follow the handling and chain of custody procedures designated by the certified laboratory which will undertake the analysis. Any variance in sampling and/or analytical methods shall have prior approval of the Brooksville Regulation Department Director. Reports of the analyses shall be submitted to the Permit Data Section, Regulation Performance Management Department, (using SWFWMD forms) on or before the tenth day of the following month, and shall include the signature of an authorized representative and certification number of the certified laboratory which undertook the analysis. The parameters and frequencies of sampling and analyses may be modified by the Brooksville Regulation Department Director, as necessary to ensure the protection of the resource. Minimum Pumping Ditrict ID Licensee ID Time Sampling No. No. (minutes Parameter Frequency 1 PW-1 20 minutes Chlorides, February, May, Sulfates, August, and and T.D.S. November 2 PW-2 20 minutes 3 PW-3 20 minutes 4 PW-4 20 minutes 5 PW-5 20 minutes 6 PW-6 20 minutes 7 PW-7 20 minutes 14 PW-8 20 minutes 15 PW-9a 20 minutes 16 PW-10a 20 minutes Water quality samples shall be collected quarterly and on the same week of the months specified. Analyses shall be performed according to procedures outlined in the current edition of Standard Methods for the Examination of Water and Wastewater by the American Public Health Association- American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or Methods for Chemical Analyses of Water and Wastes by the U.S. Environmental Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of. Certification 25.

Protection Agency (EPA).

b. Water quality samples from monitor wells shall be collected and analyzed for the District ID No., parameter(s), and frequency(ies) specified in'the table below. Water quality samples shall be collected after pumping the monitor wells(s) to a constant temperature, pH, and conductivity. Sampling method(s) shall be designed to collect water quality samples that are chemically representative of the zone to be sampled. Water quality samples shall be analyzed by a laboratory certified by the Florida Department of Health utilizing the standards and methods applicable to the parameters analyzed and to the water use pursuant to Chapter 64E-1, Florida Administrative Code, "Certification of Environmental Testing Laboratories". The Permittee's sampling procedure(s) shall follow the handling and chain of custody procedures designated by the certified laboratory which will undertake the analysis. A report describing the sampling and chain of custody procedures shall be included with the first data submitted after the date this permit is granted, and upon any change in sampling and/or analytical method(s). Any variance in sampling and/or analytical methods shall have prior approval of the SWFWMD. Reports of the analyses shall be submitted on SWFWMD forms on or before the tenth day of the following month, and shall include the signature of an authorized representative and certification number of the certified laboratory that undertook the analysis. The parameters and frequency of sampling and analysis may be modified by the SWFWMD as necessary to ensure the protection of the resource.

District I District Sample ID No. Licensee ID No. Parameter Frequency 8 MZ-21 Chlorides, May, September 9 MZ-2D Sulfates, and TDS 10 MZ-2S 11 MZ-1S 12 MZ-1 I 13 MZ-1 D Water quality samples shall be collected based on the following timetable: Semi-annually Same week of months specified Analyses shall be performed according to procedures outlined in the current edition of Standard Methods for the Examination of Water and Wastewater by the American Public Health Association-American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or Methods for Chemical Analyses of Water and Wastes by the U.S. Environmental Protection Agency (EPA). Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 26

c. The SWFWMD reserves the right to set chloride, sulfate or TDS concentration limits on any production well in the future, based on data collected and after a sufficient data base has been established to determine limits. These limits shall be required after discussions with the Licensee. At such time as the concentration in any water sample reaches or exceeds the designated concentration limits, the Licensee shall take appropriate action to reduce concentrations to below those set for the particular well. If the SWFWMD determines that long-term upward trends or other significant water quality changes are occurring, the SWFWMD may reconsider the quantities included in these conditions of certification.

d. During drilling of District ID Nos. 14, 15, 16, Licensee ID Nos. PW-8, PW-9a, PW-10a, water quality samples shall be collected at intervals of the change of drill rod or 30 feet, which ever is less, from 150 feet to a maximum depth of five feet above the bottom of the well. Regardless of the specified sample collection interval, a sample shall be collected from the depth which corresponds to five feet above the bottom of the well. Samples shall be collected during reverse air drilling, or other appropriate method with prior approval by the SWFWMD.

Samples shall be analyzed by a certified laboratory for Chloride, Sulfate, and Specific Conductivity. Licensee's sampling procedure shall follow the handling and chain of custody procedures designated by the certified laboratory which will undertake the analysis. Reports of the analyses shall be submitted to the Permit Data Section, Regulation Performance Management Department (using SWFWMD forms) within thirty days of sampling, and shall include the signature of an authorized representative and the certification number of the Florida Department of Health certified laboratory utilizing the standards and methods applicable to the parameters analyzed and to the water use pursuant to Chapter 64E-1, Florida Administrative Code, "Certification of Environmental Testing Laboratories". Analyses shall be performed according to procedures outlined in the current edition of Standard Methods for the Examination of Water and Wastewater by the American Public Health Association-American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or by Methods for Chemical Analvses of Water and Wastes by the U.S. Environmental Protection Agency (EPA).

e. Monthly water levels for monitor wells for the sites included in the table below shall be referenced to NGVD, and reported in a form acceptable to the SWFWMD by the tenth day of each month for the preceding month. The time and date that the elevation is taken shall be included. Changes to the methodology, extent, or frequency of monitoring at any of these sites may be modified by the SWFWMD, as necessary to ensure the protection of the resources.

Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 27

District ID. No Licensee Site No. 8 MZ-21 9 MZ-2D 10 MZ-2S I1 MZ-IS 12 MZ-1I 13 MZ-1D

9. Wells

a. Wells not in use with no installed pumping equipment shall be capped or valved in a water tight manner in accordance with Rule 62-532.500(3)(a)(4), F.A.C.

b. Within 90 days of the completion of each proposed well, Licensee shall submit to the SWFWMD specific capacity (well testing) information from any test performed by the Water Well Contractor or pump installer on the well. This information shall include:

i. Static water level before pumping ii. Duration of test pumping iii. Gallons per minute pumped iv. Final water level measured during pumping If step-drawdown tests were performed, the information listed above shall be submitted for each step.

c. Within 90 days of construction, Licensee shall submit to the Permit Data Section, Regulation Performance Management Department, the specific locations of District ID Nos. 14, 15, 16 Licensee ID Nos. PW-8, PW-9a, PW-10a, on an original blue line aerial with a minimum scale of one inch equals 800 feet, or by latitude/longitude. Intake and mainline diameters for each of the above pumps shall be reported at the time of location reporting.

d. For the purpose of determining site-specific transmissivity, a step drawdown and a multi well constant rate test shall be performed on one or more of the following: District ID Nos. 14, 15, 16 Licensee ID Nos. PW-8, PW-9a, PW-10a, after the wells have been fully developed. The test shall be performed in accordance with the specifications set forth in Design Aid 3, Water Use Permit Information Manual and an Aquifer Performance Testing (APT) Plan submitted to and approved by the SWFWMD.

The APT Plan shall be submitted to the SWFWMD, within 90 days of the approval of the modification of the conditions of certification. The APT shall be conducted by the Licensee within 6 months of construction of the wells included in the APT Plan and prior to the use of any of the wells constructed for the APT'S. All recorded raw data shall be Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 28

submitted to the SWFWMD within thirty (30) days of completion of the APT.

e. Within sixty (60) days, the Licensee shall designate one individual responsible for receiving and responding to the SWFWMD notices and correspondence related to these conditions of certification. Notification to the SWFWMD of the designee, including address and telephone number shall be in written form.

f. Within 90 days of conditions of certification issuance, Licensee shall develop and implement a Water Conservation Plan (Plan) that includes practices currently employed or planned. For planned components, include an estimated time-frame for implementation for each. The Plan must indicate that technically and economically feasible water conservation opportunities have been or will be employed.

g. The lowest quality water source, including reclaimed water, surface water and stormwater, must be used for each consumptive use authorized by these conditions of certification when available, except when Licensee demonstrates that the use of the lower quality water source is determined to be not economically, environmentally, or technologically feasible, in accordance with the SWFWMD's Water Use Permit Information Manual Part B, Basis of Review, Sections 4.4 and 4.1 1.

h. Wetlands and other surface waters may not be adversely impacted as a result of the water use authorized by these conditions of certification. If unacceptable adverse impacts occur, the SWFWMD will request that DEP revoke these conditions of certification in whole or in part to curtail or abate the unacceptable adverse impacts, unless the impacts can be mitigated by Licensee.

10. StandardConditions Licensee shall comply with the following Standard Conditions:

a. If any of the statements in the application and in the supporting data are found to be untrue and inaccurate, or if Licensee fails to comply with all of the provisions of Chapter 373, F.S., Chapter 40D, or the conditions set forth herein, the SWFWMD shall seek revocation of any conditions of certification.

b. These conditions of certification are imposed based on information provided by Licensee demonstrating that the use of water is reasonable and beneficial, consistent with the public interest, and will not interfere with any existing legal use of water. If, during the term of this certification, it is determined by the SWFWMD that the use is not reasonable and beneficial, in the public interest, or does impact an existing legal use of water, the SWFWMD shall seek modification these conditions of certification or revocation of the certification authorized by DEP.

c. Licensee shall not deviate from any of the SWFWMD-imposed conditions of this certification without written approval by the Department and the SWFWMD.

d. In the event the SWFWMD declares that a Water Shortage exists pursuant to Chapter 40D-21, Licensee agrees that portions of these conditions of certification shall be modified, or declared inactive as necessary to address the water Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 29

shortage.

e. The SWFWMD shall collect water samples from any withdrawal point listed in these conditions of certification or shall require Licensee to submit water samples when the SWFWMD determines there is a potential for adverse impacts to water quality.

f. Licensee shall provide access to an authorized SWFWMD representative to enter the property at any reasonable time to inspect the facility and make environmental or hydrologic assessments. Licensee shall either accompany the SWFWMD staff onto the property or make provision for access onto the property.

g. Licensee shall cease or reduce any surface water withdrawals as directed by the SWFWMD if water levels in surface water fall below applicable minimum water level established in Chapter 40D-8 or rates of flow in streams fall below the minimum levels established in Chapter 40D-8.

h. Licensee shall cease or reduce withdrawals if water levels in aquifers fall below the minimum levels established by the SWFWMD.

i. Licensee shall practice water conservation to increase the efficiency of transport, application, and use, as well as to decrease waste and to minimize runoff from the property. At such time as the SWFWMD adopts specific conservation requirements for Licensee's water use classification, these conditions of certification shall be modified accordingly.

j. The SWFWMD may establish special regulations for Water Use Caution Areas. At such time as the Governing Board adopts such provisions, these conditions of certification shall be subject to them upon notice and after a reasonable period for compliance.

k. Licensee shall mitigate any adverse impact to existing legal uses caused by withdrawals. When adverse impacts occur or are imminent, Licensee shall be required to mitigate the impacts. Adverse impacts include:

i. A reduction in water levels which impairs the ability of the well to produce water; ii. Significant reduction in levels or flows in water bodies such as lakes, impoundments, wetlands, springs, streams or other watercourses; or iii. Significant inducement of natural or manmade contaminants into a water supply or into a usable portion of any aquifer water body.

I. Licensee shall mitigate any adverse impact to environmental features or offsite land uses as a result of withdrawals. When adverse impacts occur or are imminent, the Licensee shall be required to mitigate the impacts. Adverse impacts include:

i. Significant reduction in levels or flows in water bodies such as lakes, impoundments, wetlands, springs, streams or other watercourses; ii. Sinkholes or subsidence caused by reduction in water Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 30

levels; iii. Damage to crops and other vegetation causing financial harm to the owner; and iv. Damage to the habitat of endangered or threatened species.

m. When necessary to analyze impacts to the water resource or existing users, Licensee shall be required to install flow metering or other measuring devices to record withdrawal quantities and submit the data to the SWFWMD.

n. A SWFWMD identification tag shall be prominently displayed at each withdrawal point by permanently affixing the tag to the withdrawal facility.

0. Licensee shall notify the SWFWMD within 30 days of the sale or conveyance of permitted water withdrawal facilities or the land on which the facilities are located.

p. The annual average daily withdrawal quantity is determined by calculating the total quantity of water to be withdrawn over a one year period, divided by 365 days, which results in a gallons per day (gpd) quantity pursuant to Basis of Review, Section 3.2, Permitted Withdrawal Quantities. This is a running 12-month average, whereby each month the annual average daily quantity is recalculated based on the previous 12-month pumpage.

G. Solid Wastes No later than December 31, 2008 or 180 days prior to the initial operation of Unit 4 and 5 FGD scrubbers (whichever occurs first), the licensee shall submit a site-wide Coal Combustion By-Product (CCP)/Solid Waste Materials Management Plan that addresses operations of the fossil generating units to the Department's SWD Office and Siting Office for review and approval. The plan shall, at a minimum, include the following information:

1. descriptions and procedures for all applicable processes for on-site storage practices and management of CCPs, solid wastes and industrial by-products at the site.

2. plans or methods to minimize waste streams, and maximize beneficial use opportunities of CCPs;

3. methods for preventing or minimizing the release of contaminants to the environment, including (as applicable) leachate collection and control methods that meet the requirements of Chapter 62-701. F.A.C.;

4. certification for the above information, as appropriate, by a Professional Engineer registered in the state of Florida.

The Department shall indicate its approval or disapproval of the submitted plans, drawings, maps, analyses and contingency plans within 90 days of the originally submitted information. In the event that the Department requires additional information for the licensee to complete, and the Department to approve the CCP/Solid Waste Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 31

Materials Management Plan, the Department shall make a written request to the licensee for additional information no later than 30 days after receipt of the originally submitted information. H. Ash Landfill and Coal Piles

1. Ash Landfill a) PEF shall designate a portion of the site as a temporary ash landfill. Associated with the temporary landfill shall be certain sites for the testing and monitoring of leachates and ash pile liners.

b) Adequate geophysical testing shall be conducted to determine if solution cavities are present under the landfill area. If such cavities are located, such cavities shall be sealed off and stabilized. c) The proposed ash landfill area shall be monitored and studied pursuant to a detailed leachate testing and monitoring program to be submitted by PEF to the Department within 30 days of certification for review and approval, rejection, or modification within 60 days thereafter. The detailed leachate testing. and monitoring program shall be consistent with the conceptual leachate monitoring program attached and incorporated herein as Attachment 2. d) After approval of the program by the Department, PEF shall conduct the approved testing and monitoring program under the supervision of the Department. Results of the program shall be submitted to the Department for its review and consideration on a monthly basis. e) The results of the program will be used by the Department in determining whether PEF has affirmatively demonstrated that Florida Water Quality Standards (62-520 and 62-550, F.A.C.) will not be violated in determining the zone of discharge and in determining the need for a liner. f) Ifthe Department determines that PEF has failed to affirmatively demonstrate that Florida Water Quality Standards (62-520 and 62-550, F.A.C.) will not be violated, PEF shall present to the Department, within 90 days of such determination, a plan of correction (which may include, if appropriate, a semi-permeable liner) for review and approval by the Department and for timely implementation by PEF, or PEF shall place an impermeable liner under the final ash landfill site and shall remove all ash from the temporary landfill site and place it on the lined landfill location. g) The final cover shall be in compliance with Chapter 62-701, F.A.C., and at least 12" of clay or sufficient suitable liner material shall be placed on the top and exposed sides of each finished landfill cell. Sufficient topsoil to support vegetation shall be placed over the top and side clay liner. The top and exposed sides of the ash landfill shall be vegetated to control erosion.

2. Ash Relocation Due to Installationof New Access Road to Support the Units 4 & 5 Clean Air Project a) Prior to commencement of modifications/additions to the existing access road located along the south and west perimeters of the ash storage Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 32

area the Licensee shall submit the following items to the DEP SWD Office and Siting Office :

i. a figure, aerial photograph or plan sheet identifying the area where the ash to be removed will be re-located; ii. plan sheets of existing (pre-construction) conditions and final contours of the ash landfill affected by the access road installation; and iii. a figure, aerial photograph or plan sheet showing the location and details of any collapsed surface cavities/sinkholes found on the site relative to the ash landfill and proposed access road project.

b) The working face slopes of the relocated ash shall be no steeper than 4H:IV, unless prior approval from the Department's SWD Solid Waste Section and the Siting Office for an alternative slope is obtained. c) The filtered stormwater drainage downslope of the working face shall not discharge outside the contact stormwater or Industrial Wastewater system. d) Within 90 days following completion of the access road and restoration of the final cover on the ash landfill in the affected portions, the Licensee shall submit to the Department's SWD Office and Siting Office the following information:

i. a final survey of the affected portions of the closed ash landfill that demonstrates that the slopes are no steeper than 4H:IV; ii. documentation that the clay cover, if used, is no less than 12 inches thick; iii. hydraulic conductivity testing results on the constructed clay layer, if used, (5 tests for the first acre, then 1 test/acre/lift for every other acre). Testing should be carried out in accordance with ASTM Method D5084 or equivalent; and Iv. certification for the above information by a Professional Engineer registered in the state of Florida.

v. A geosynthetic clay liner (GCL) or other alternative liner system may be used; however, prior to the installation of any alternative liner system, the Licensee shall submit a complete proposed plan to the Department's SWD Solid Waste Section and Siting Office for review and approval.

The plan shall, at a minimum, include specifications for the Construction Quality Assurance Plan and drawings showing the location of the liner cover, soil cover for the liner, and any other relevant information that may be applicable for the type of alternative liner system being proposed. The Department shall indicate its approval or disapproval of the submitted plan within 90 days of the originally submitted information. In the event that the Department requires additional information for the licensee to complete, and the Department to approve the GCL or alternative liner system, the Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 33

Department shall make a written request to the licensee for additional information no later than 30 days after receipt of the originally submitted information.

3. Coal Pile a) Prior to initial operation of the Unit 4 and 5 FGD scrubber systems, the licensee shall install an impervious liner system beneath the Unit 4 and 5 coal pile storage area and associated stormwater runoff/leachate collection, storage, and treatment ponds.

b) The liner system shall be designed and of sufficient impervious material to provide for a hydraulic conductivity equal to, or less than 10-7 cm/sec. c) Prior to initial construction of each liner installation, the licensee shall submit a complete proposed plan of the liner system to the Department's SWD Solid Waste Section and the Siting Office for review and approval. Each liner installation plan shall, at a minimum, include the following information:

i. design drawings, calculations, and specifications of the proposed liner system; ii. The Construction Quality Assurance Plan (CQA);

iii. slope stability calculations that demonstrate that the proposed slope will be stable with a 1.5 factor of safety; iv. anchoring details for the liner systems;

v. permeability (hydraulic conductivity) and specifications for the "crusher run" material (or for alternate material if used);

vi. procedures for ensuring that the clay liners will not be damaged from future coal removal operations; vii. the thickness (and unit weight) of material that will be placed above the GCL on the slopes and specification of the slope of the GCL sub-grade; viii. piping details that show how the coal pile runoff water will be discharged from the coal pile runoff ponds to the coal pile runoff settling ponds; ix. any other relevant information that may be applicable for the type of alternative liner system being proposed; and

x. certification for the above information by a Professional Engineer registered in the state of Florida.

The Department shall indicate its approval or disapproval of a submitted liner system plan within 90 days of the originally submitted information. In the event that the Department requires additional information for the licensee to complete, and the Department to approve the liner system, the Department shall make a written request to the licensee for additional information no later than 30 days after receipt of the originally submitted information. Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 34

d) Handling and monitoring of the coal pile and associated wastes shall be in accordance with the site-wide Coal Combustion By-Product (CCP)/Solid Waste Materials Management Plan for the fossil units required by Special Condition V. Solid Wastes. VII. UNIT 3 SPECIFIC CONDITIONS The following Specific Conditions shall apply only to Unit 3. Compliance with these Specific Conditions shall be the responsibility of the Progress Energy (Nuclear). A. Air The construction and operation of the Unit No. 3 nuclear plant site shall be in accordance with all applicable provisions of Chapters 62-210 through 62-297, and 62-702, Florida Administrative Code. Title V Air Operation Permit 0170004-015-AV, and PSD-FL-392 (017004-018-AC) including subsequent modifications are incorporated by reference herein as part of this Certification and attached as Appendix A and Appendix E. The provisions of the above shall be conditions of this certification. The licensee shall comply with the substantive provisions and limitations set forth in Title V Air Operation Permit Number 0170004-015-AV and Air Construction Permit PSD-FL-392 as part of these Conditions of Certification, and as those provisions may be modified, amended, or renewed in the future by the Department. Such provisions shall be fully enforceable as conditions of this certification. Any violation of such provisions shall be a violation of these Conditions of Certification. B. Water Discharges Any discharges into any waters of the State during construction and operation of Unit 3 shall be in accordance with all applicable provisions of Chapter 17-3, Florida Administrative Code and 40 CFR 423, Effluent Guidelinesand Standardsfor Steam Electric Power GeneratingPoint Source Category and with NPDES permit no. FL0000159 (attached as Appendix G) as well as any subsequent modifications, amendments and/or renewals. A copy of all subsequent renewal and modification applications shall also be sent to the St. Martins Marsh & Big Bend Seagrass Aquatic Preserve of the Office of Coastal and Aquatic Managed Areas, and to the Florida Fish and Wildlife Conservation Commission, Office of Policy and Stakeholder Coordination. C. Groundwater - SWFWMD No groundwater use by Unit 3 is authorized by these Conditions of Certification. Potable water demand for Unit 3 shall continue to be met by water use authorized under Water Use Permit (WUP) No. 2004695.004 issued by the Southwest Florida Water Management District. (Attached as Appendix H) WUP No. 2004695.004 authorizes 1,000,000 gallons per day (annual average) and 1,500,000 gpd (peak month) for boiler makeup, pollution control, and potable water needs at Units 1, 2 and 3. PEF shall abide by the conditions of WUP No. 2004695.004 and any modification or renewal thereof for the continued authorized use of groundwater in the operation of Unit

3. Such provisions shall be fully enforceable as conditions of this certification. Any Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 35

violation of such provisions, where it is determined that Unit 3 is the cause, shall be a violation of these Conditions of Certification. D. Groundwater - FDEP No groundwater discharge by Unit 3 is authorized by these Conditions of Certification. IWW Permit FLA016960 (attached as Appendix 1)issued by the FDEP authorizes the discharge of industrial waste water from Unit 3 to a common percolation pond system. PEF shall abide by the conditions of IWW FLA 016960 and any modification or renewal thereof for the continued authorized discharge of industrial waste water to ground water by the operation of Unit 3. Such provisions shall be fully enforceable as conditions of this certification. Any violation of such provisions, where it is determined that Unit 3 is the cause, shall be a violation of these Conditions of Certification. E. Environmental Resource Review

1. At least 90 days prior to construction of the South Cooling Tower, the licensee shall provide to the DEP SWD office all information necessary for a complete Environmental Resource Permit application including the engineering drawings and supporting documentation necessary to demonstrate that the stormwater runoff from the proposed project will be treated and attenuated in accordance with Rules 40D-4, 40D-40 and 40D-400, F.A.C, and a Wetland Mitigation Plan if applicable.

The drawings and documentation shall be signed, sealed and dated by a professional engineer registered in the State of Florida.

2. Within 60 days following certification, and prior to construction of any construction laydown and parking areas associated with Unit 3, the licensee shall provide to the DEP SWD office all information necessary for a complete Environmental Resource Permit application including the engineering drawings and supporting documentation necessary to demonstrate that the stormwater runoff from the proposed project will be treated and attenuated in accordance with Rules 40D-4, 40D-41 and 40D-42, F.A.C, and a Wetland Mitigation Plan if applicable. The drawings and documentation shall be signed, sealed and dated by a professional engineer registered in the State of Florida.

3. Prior to the commencement of construction, the Department shall conduct a timely review of the submitted information and request the correction of any errors and omissions to complete the application information. This shall be done in accordance with timeframes established in Chapter 120.60, F.S. and Rule 62-4.055, F.A.C.

4. The Department shall notify the licensee in writing that the information is complete upon review of all requested information and the correction of any errors or omissions. Construction shall not begin until the Department has provided written notification of approval of the project including the Wetland Mitigation Plan as applicable. Such approval or denial shall be provided within 30 days following completeness of the application information.

5. Turbidity and sediments must be controlled to prevent violations of Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 36

water quality pursuant to Rule 62-302.500, 62-302 .530(70) and 62-4.242 Florida Administrative Code (FAC). Best Management Practices, as specified in the Florida Stormwater, Erosion and Sedimentation Control Inspectors Manual, shall be installed and maintained at all locations where the possibility of transferring suspended solids into wetlands and/or surface waters due to the permitted activity. If site-specific conditions require additional measures, then the applicant shall implement them as necessary to prevent adverse impacts to wetlands and/or surface waters.

6. The existing ambient water quality within Outstanding Florida Waters shall not be lowered as a result of the proposed activity, except as authorized by the FDEP under 62-4.242(2) FAC.

7. Prior to start of construction, PEF shall prepare a Storm Water Pollution Prevention Plan and submit a copy of the National Pollutant Discharge Elimination System (NPDES) Notice of Intent (NOI) to use a Construction Generic Permit (CGP) for stormwater discharges (as applicable) to DEP.

F. Domestic Wastewater Treatment Domestic wastewater from Unit 3 shall be treated by the Crystal River Units 1, 2, and 3 Sewage Treatment Plant as authorized by Domestic Wastewater Facility Permit FLAI 18753 issued by the DEP SW District (attached as Appendix J). PEF shall abide by the conditions of permit No. FLA1 18753 and any modification or renewal thereof for the continued authorized treatment of domestic wastewater from Unit 3. Such provisions shall be fully enforceable as conditions of this certification. Any violation of such provisions, where it is determined that Unit 3 is the cause, shall be a violation of these Conditions of Certification. G. Radiological

1. Decommissioning Upon application to the NRC for authority to decommission the plant, the applicant shall provide the Department a copy of the plan submitted to NRC for radioactive materials removal and/or containment for the site. Should the Department's review of the written plan reveal deficiencies, the Department shall bring such deficiencies to the attention of the applicant and the NRC and maintains the right to initiate a request, consistent with NRC procedural requirements that remedial action be taken to correct the deficiencies.

2. Emergency Plan The applicant shall work with the State Division of Emergency Management in the Department of Community Affairs and the State Department of Health, Bureau of Radiation Control, and Citrus and Levy Counties in bi-annually updating the emergency procedures and evacuation planning as necessary, including but not limited to improvements in communication and warning systems and in updating predicted plume overlays.

3. RadiologicalRelease Limitations The recommendation in the Power Plant Site Certification Analysis Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 37

that certification be issued is based in part upon the fact that in order to obtain a construction permit and operating license from NRC, the applicant must comply with all applicable regulations, requirements, and standards of the U.S. Nuclear Regulatory Commission (NRC) which limit the release of radioactive materials in solid waste, liquid or gaseous effluents to the environment. The above NRC regulations, requirements and standards include the following: a) Standards for Protection Against Radiation, U.S. Nuclear Regulatory Commission Rules and Regulations, Title 10, Chapter 1, Part 20, Code of Federal Regulations, as presently in effect or hereafter amended. b) Limitations and conditions for the controlled release of radioactive materials in solid, liquid and gaseous effluents contained in the Radiological Environmental Monitoring Program required by Title 10, 10 CFR 50, Appendix I as presently in effect or hereafter amended.. The Department has the statutory duty to insure that the location and operation of Crystal River Unit 3 will produce minimal adverse effects on human health, the environment, the ecology and the land and its wildlife, and the ecology of State waters and their aquatic life. (Fla. Stat. Section 403.502.) The Department has determined that the construction and operation of Crystal River Unit 3 must comply with the above radiological release limitations in order to minimize adverse effects on human health and the environment. This certification is conditioned upon full compliance by the applicant with the applicable above regulations, requirements and standards. The NRC has the duty and responsibility imposed by statute, to enforce compliance by the applicant with NRC standards and technical specifications, to assure that the construction and operation of Crystal River Unit 3 will be in accord with the common defense and security and will provide adequate protection to the health and safety of the public. See Section 103(d) of the Atomic Energy Act, 42 U.S.C. section 2133(d) (1970); accord. 42 U.S.C. section 2332(a) (1970) including any subsequent revisions. However, should the Department determine that the NRC has failed to discharge its duty and responsibility, it may bring any such deficiencies to the attention of the applicant and the NRC, and maintains the right to initiate a request, consistent with NRC procedural requirements, that appropriate enforcement action be taken to correct the deficiencies.

4. Monitoring The applicant shall comply with the most recent Department of Health Environmental Surveillance Agreement or its equivalent or future replacement.

Should the Department of Health determine that additional monitoring is required, it may take appropriate action to require such monitoring by modification of this condition of certification.

5. Reservation of Legal Rights The Department recognizes that the NRC has exclusive authority in certain areas related to the construction and operation of Crystal River Unit 3. These Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 38

conditions of certification do no limit, expand or supersede any federal requirement or restriction under federal law, regulation, or regulatory approval or license. Compliance with the conditions herein does not constitute a waiver of the applicant's responsibility to comply with all applicable NRC requirements. Applicant's acceptance of these radiological conditions of certification does not, in and of itself, constitute a waiver by Applicant of any claim that any such radiological conditions are invalid under the doctrine of federal preemption or otherwise by law. VIII. FLORIDA DEPARTMENT OF TRANSPORTATION A. Access Management to the State Highway System Any access to the State Highway System will be subject to the requirements of Rule Chapter 14-96, State Highway System Connection Permits, and 14-97 Access Management Classification System and Standards, F.A.C. B. Overweight or Overdimensional Loads Operation of overweight or overdimensional loads by the applicant on State transportation facilities during construction and operation of the utility facility will be subject to safety and permitting requirements of Chapter 316, F.S., and Rule Chapter 14-26, Safety Regulations and Permit Fees for Overweight and Overdimensional Vehicles, F.A.C.. C. Use of State of Florida Right of Way or Transportation Facilities All usage and crossing of State of Florida right of way or transportation facilities will be subject to Rule Chapter 14-46, Utilities Installation or Adjustment, F.A.C.; Florida Department of Transportation's (FDOT) Utility Accommodation Manual (Document 710-020-001); Design Standards for Design, Construction, Maintenance and Utility Operation on the State Highway System; Standard Specifications for Road and Bridge Construction; and pertinent sections of the FDOT's Project Development and Environmental Manual. US 19 has been identified as a Florida Intrastate Highway System (FIHS) and Strategic Intermodal System's (SIS) facilities. The placement of any transmission line or pipeline should take into consideration the planned widening of these facilities. The cost of relocating or reconstructing a transmission line or pipeline will be borne by the applicant to the extent required by Section 337.403, F.S., and Rule Chapter 14-46, F.A.C. D. Standards The manual on Uniform Traffic Control Devices; FDOT's Design Standards for Design, Construction, Maintenance and Utility Operation on the State Highway System; FDOT's Standard Specifications for Road and Bridge Construction; FDOT's Utility Accommodation Manual; and pertinent sections of the FDOT's Project Development and Environmental Manual will be adhered to in all circumstances involving the State highway System and other transportation facilities. E. Drainage Any drainage onto State of Florida right of way and transportation facilities will be subject to the requirements of Rule Chapter 14-86, Drainage Connections, Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 39

F.A.C., including the attainment of any permit required thereby. F. Use of Air Space Any newly proposed structure or alteration of an existing structure will be subject to the requirements of Chapter 333, F.S., and Rule 14-60.009, Airspace Protection, F.A.C. Additionally, notification to the Federal Aviation Administration (FAA) is required prior to beginning construction, if the structure exceeds notification requirements of 14 CFR Part 77, Objects Affecting Navigable Airspace, Subpart B, Notice of Construction or Alteration. Notification will be provided to FAA Southern Region Headquarters using FAA Form 7460-1, Notice of Proposed Construction or Alteration in accordance with instructions therein. A subsequent Determination by the FAA stating that the structure exceeds any federal obstruction standard of 14 CFR Part 77, Subpart C for any structure that is located within a 10-nautical-mile radius of the geographical center of a public-use airport or military airfield in Florida will be required to submit information for an Airspace Obstruction Permit from the DFOT or variance from local government depending on the entity with jurisdictional authority over the site of the proposed structure. The FAA Determination regarding the structure serves only as a review of its impact on federal airspace and is not an authorization to proceed with any construction. However, FAA recommendations for marking and/or lighting of the proposed structure are made mandatory by Florida law. For a site under FDOT jurisdiction, application will be made by submitting FDOT Form 725-040-11, Airspace Obstruction Permit Application, in accordance with the instructions therein. G. Best Management Practices Traffic control during facility construction and maintenance will be subject to the standards contained in the Manual on Uniform Traffic Control Devices; Rule Chapter 14-94, Statewide Minimum Level of Service Standards, F.A.C.; FDOT's Design Standards for Design, Construction, Maintenance and Utility Operation on the State highway System; FDOT's Standard Specifications for Road and Bridge Construction; and FDOT's Utility Accommodation Manual, whichever is more stringent. It is recommended that the applicant encourage transportation demand management techniques by doing the following:

1. Placing a bulletin board on site for car pooling advertisements.

2. Requiring that heavy construction vehicles remain onsite for the duration of construction to the extent practicable.

If the applicant uses contractors for the delivery of any overweight or overdimensional loads to the site during construction, the applicant should ensure that its contractors adhere to the necessary standards and receive the necessary permits required under Chapter 316, F.S., and Rule Chapter 14-26, Safety Regulations and Permit Fees for Overweight and Overdimensional Vehicles, F.A.C. IX. HISTORY Certification Issued 11/21/78; signed by Governor Askew Modified 02/22/80; signed by Governor Graham Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 40

Modified 05/22/80; signed by Secretary Varn Modified 05/04/82; signed by Secretary Tschinkel Modified 06/29/82; signed by Governor Graham Modified 02/02/84; signed by Secretary Tschinkel Modified 07/03/84; signed by Governor Graham. Letter Modification 03/28/88; signed by Hamilton Oven Jr. Modified 06/10/96; signed by Secretary Wetherell Modification Denial 03/02/98; signed by Secretary Wetherell Modification 02/01/05; signed by Program Administrator Oven Modified 06/22/06; signed by Program Administrator Oven Modified 11/29/07; signed by Program Administrator Halpin Modified 08/07/08; signed by Program Administrator. Halpin Modified 08/28/08; signed by Governor Crist Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 1Conditions of Certification 41

ATTACHMENT 1: AMBIENT AIR MONITORING LOCATIONS Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 42

ATTACHMENT 2: LEACHATE MONITORING AND TESTING PROGRESS ENERGY FLORIDA CRYSTAL RIVER UNITS 4 AND 5 PROPOSED LEACHATE MONITORING AND TESTING I. Computerized and manual literature search with the objective of obtaining an adequate data base from literature. I1. Pre-operational Water Table Monitoring Program with the objective to acquire 12-month baseline. Install 12 shallow peizometer well points Install 2 deep peizometer well points Monitor water table level

                       - 1 well-recorder to establish degree of tidal influences - one month
                       - 13 wells - weekly Monitor in situ (pH, conductance, redox, dissolved oxygen) - weekly (all wells)

Monitor key water quality indicators - monthly (4 wells) Monitor extended water quality indicators - quarterly (4 wells) Monitor rainfall and evaporation - weekly Develop flow net and water budget I1l. Laboratory screening of ash from low pyritic sulfur coal with the objective of evaluation of leachate formation and attenuation reactions. The program will establish the following:

              - Percolation rates of compacted ash (fly and bottom ash)
              - Solute release rates
              - Limestone neutralization effectiveness
              - Clay liner effectiveness
              - Correlate extended and key water quality indicators
              - Total ash leachate capacity
              - Active area vs. Inactive area leachate rates
              - Available fractions of solutes Techniques for screening:
                       - Shake test (fly, bottom ash)
                       - Column leaching (6-10 months)

Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 43

(1) Compacted fly ash (lifts and liners) (2) Alternative lifts of ash and limestone (3) Ash with clay liner (4) Ash with compacted limerock and fly ash liner IV. Evaluate leachate attenuation in subsoil and water table aquifer.

               - Oxidation - reduction
               - Chemical precipitation/solubility/pH/Eh
               - Adsorption isotherms
               - Ion exchange capacity
               - Metals content of limerock V.      Cost-effectiveness evaluation of alternative liners
               - Water quality criteria
               - Biological effects
               - Cost of leachate control and treatment
               - Cost of runoff control and treatment VI. Develop final design for field test cell program defined in paragraph VII below.

VII. Field test cells program with the objective of verifying. Monitor water budget

                      - Direct infiltration rates
                      - Direct runoff
                      - Direct rainfall
                      - Water table Potential test cell configuration
                      - Ash with compacted fly ash liner only
                      - Ash with compacted limestone and fly ash liner
                      - Alternative lifts of ash and limestone with compacted fly ash liner
                      - Ash with selected clay liner
                      - Alternative caps and vegetation Monitor leachate formation and attenuation
                      - 4 well clusters per cell at three depths
                      - Weekly water table elevations in situ water quality from all wells (pH, conductance, redox, dissolved oxygen)

Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 44

                      - Monthly key indicators from 2 clusters per cell
                      - Quarterly extended indicators from 2 per cell
                      - 2 base well points shall be maintained up slope of the active area VIII. Evaluate leachate management program results and develop final design of ash storage area.

IX. Periodic reports on the progress of this program will be submitted to the Department for its information and review. X. In situ water quality indicators pH Redox Conductance Dissolved Oxygen XI. Key water quality indicators - monthly Conductance Cadmium pH Zinc Redox Copper Dissolved Oxygen Nickel Temperature Selenium Color Chromium Turbidity Arsenic Chloride Beryllium Iron Mercury Lead XII. Extended water quality indicators - quarterly Key indicators plus: Total Dissolved Solids Gross Alpha Suspended Solids Aluminum Barium Calcium Magnesium Sodium Molybdenum Vanadium Cobalt Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 45

ATTACHMENT 3: DISCHARGE MONITORING REPORT Florida Department of Environmental Protection PEF CREC Units 3, 4, and 5 PA77-09A2 Conditions of Certification 46

Attacl i nt 3 DEPARTMENT OF ENVIRONMENTAL PROTECTION IMARGE MONITORING REPORT - PART A DRAFT When Completed mail this report to: Department of Environmental Protection, Wastewater Compliance Evaluation Section, MS 3551, 2600 Blair Stone Road, Tallahassee, FL 32399-2400 0 PERMITTEE NAME: Progress Energy Florida PERMIT NUMBER PA 77-09J (Siting Certification) MAILING ADDRESS: 15760 Powerline Street, MAC CN77 Crystal River, FL 34428 LIMIT: Final REPORT: Quarterly CLASS SIZE: Major GROUP: Industrial FACILITY: PEF Crystal River Units 4&5 LOCATION 15760 Powerline Street MONITORING GROUP NUMBER: G-001 US Highway 19 & Powerline Road MONITORING GROUP DESC: Crystal River Units 4 & 5 Percolation Ponds Crystal River, FL 34428 COUNTY: Citrus NO DISCHARGE FROM SITE:E] MONITORING PERIOD From: To Parameter Quantity or Loading Units Quality or Concentration Units No. Frequency of Sample Type Ex. Analysis pH Sample Measurement PARM Code 00400" I Permit Report Report SU Quarterly In-situ Mon. Site No. EFF-4 Requirement (Min.) (Max.) Specific Conductance Sample Measurement PARM Code 00095 1 . Permit Report . UMHO/CM Quarterly In-situ Mon. Site No. EFF-4 Requirement (Max.) Arsenic, Total Recoverable Sample Measurement PARM Code 00978 1 Permit Report UG/L Quarterly Grab Mon. Site No. EFF-4 Requirement (Max.) Barium, Total Recoverable Sample Measurement PARM Code 01009 I Permit Report MG/L Quarterly. Grab Mon. Site No. EFF-4 Requirement (Max.) Chloride (as Cl) Sample Measurement PARM"Code 00940 1- Permit Report MG/L Quarterly Grab Mon. Site No. EFF-4 Requirement (Max.) Iron, Total Recoverable Sample Measurement PARM Code 00980 1 Permit Report MG/L Quarterly Grab Mon. Site No. EFF-4 Requirement (Max.) I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT ISIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO IDATE (YY/MM/DD) COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here): DEP Form 62-620.910(10), Effective Nov. 29, 1994 Progress Energy Florida Siting Certification Crystal River Units 4 & 5 Case No. PA 77-09J

FACILITY: 9 PEF Crystal River Units 4&5 Attaclifnt 3 DISCHARGE MONITORING REPOW- PART A DRAFT (Continued) MONITORING GROUP NUMBER: G-001 9 PERMIT NUMBER: PA 77-09J MONITORING PERIOD From- To Parameter Quantity or Loading Units Quality or Concentration Units No. Frequency of Sample Type Ex. Analysis Magnesium, Total Recoverable Sample Measurement PARM Code 00921 .1 Permit .- Report MG/L" Quarterly " Grab Mon. Site No. EFF-4 Requirement _ __ (Max.) Sodium, Total Recoverable Sample Measurement PARM Code 00923i 1 Permit .Report MG/L. Quarterly - Grab Mon. Site No. EFF-4 Requirement . . (Max.) Solids, Total Dissolved (TDS) Sample Measurement PARMCode 70295 1. Permit " Report MG/L - Quarterly Grab Mon. Siue No. EFF-4 Requirement -"(Max.) Vanadium, Total Recoverable Sample Measurement pARM Code 01128 1 Permit Report MG/L Quarterly Grab Mon, Site No. EFF-4 Requirement (Max.) Zinc, Total Recoverable Sample Measurement PARM Code 0i94 I . Permit " Report MG/L.. Quarterly Grab Mon. Site No. EFF-4 Requirement __ __(Max.)______ Sample Measurement

                            -        Permit Requirement Sample Measurement Permit Requirement                     __. _.      _-_                                            . --                    -     .      ..

Sample Measurement Permit. _______________Requirement Sample Measurement

                          -   --     Permit
               ..                . ~~~~Requirement..                                         '**                    ,

Sample Measurement

       .       -                     Permit..

_____________...._______ lRequirement 0_ ___.________ DEP Form 62-620.910(10), Effective Nov. 29, 1994 Progress Energy Florida Siting Certification Crystal River Units 4 & 5 Case No. PA 77-09J

Attac/, nt 3 INSTRUCTIONS FOR COMPLETING THE WASIW TER DISCHARGE MONITORING REPORT Read these instructions as well as the SUPPLEMENTAL INSTRUCTIONS FOR COMPLETING THE WASTEWATER DISCHARGE MONITORING REPORT before completing the DMR. Hard copies and/or electronic copies of the required parts of the DMR were provided with the permit. All required information shall be completed in full and typed or printed in ink. A signed, original DMR shall be mailed to the address printed on the DMR by the 8th of the 2 month following the monitoring period. The DMR shall not be submitted before the end of the monitoring period. The DMR consists of three parts-A, B, and D-all of which may or may not be applicable to every facility. Facilities may have one or more Part A's for reporting effluent or reclaimed water data. All domestic wastewater facilities will have a Part B for reporting daily sample results. Part D is used for reporting ground water monitoring well data. When results are not available, the following codes should be used on parts A and D ofthe DMR and an explanation provided where appropriate. Note: Codes used on Part B for raw data are different. CODE DESCRIPTION/INSTRUCTIONS CODE DESCRIPTION/INSTRUCTIONS ANC Analysis not conducted. NOD No discharge from/to site. DRY Dry Well OPS Operations were shutdown so no sample could be taken. FLD Flood disaster. OTH Other. Please enter an explanation of why monitoring data were not available. IFS Insufficient flow for sampling. SEF Sampling equipment failure. LS Lost sample. MNR Monitoring not required this period. When reporting analytical results that fall below a laboratory's reported method detection limits or practical quantification limits, the following instructions should be used: I. Results greater than or equal to the PQL shall be reported as the measured quantity.

2. Results less than the PQL and greater than or equal to the MDL shall be reported as the laboratory's MDL value. These values shall be deemed equal to the MDL when necessary to calculate an average for that parameter and when determining compliance with permit limits.

3. Results less than the MDL shall be reported by entering a less than sign ("<") followed by the laboratory's MDL value, e.g. < 0.001. A value of one-half the MDL or one-half the effluent limit, whichever is lower, shall be used for that sample when necessary to calculate an average for that parameter. Values less than the MDL are considered to demonstrate compliance with an effluent limitation.

PART A -DISCHARGE MONITORING REPORT (DMR) Part A of the DMR is comprised of one or more sections, each having its own header information. Facility information is preprinted in the header as well as the monitoring group number, whether the limits and monitoring requirements are interim or final, and the required submittal frequency (e.g. monthly, annually, quarterly, etc.). Submit Part A based on the required reporting frequency in the header and the instructions shown in the permit. The following should be completed by the permittee or authorized representative: No Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data or codes to be entered for all of the parameters on the DMR for the entire monitoring group number; however, if the monitoring group includes other monitoring locations (e.g., influent sampling), the "NOD" code should be used to individually denote those parameters for which there was no discharge. Monitoring Period: Enter the month, day, and year for the first and last day of the monitoring period (i.e. the month, the quarter, the year, etc.) during which the data on this report were collected and analyzed. Sample Measurement: Before filling in sample measurements in the table, check to see that the data collected correspond to the limit indicated on the DMR (i.e. interim or final) and that the data correspond to the monitoring group number in the header. Enter the data or calculated results for each parameter on this row in the non-shaded area above the limit. Be sure the result being entered corresponds to the appropriate statistical base code (e.g. annual average, monthly average, single sample maximum, etc.) and units. No. Ex.: Enter the number ofsample measurements during the monitoring period that exceeded the permit limit for each parameter in the non-shaded area. If none, enter zero. Frequency of Analysis: The shaded areas in this column contain the minimum number of times the measurement is required to be made according to the permit. Enter the actual number of times the measurement was made in the space above the shaded area. Sample Type: The shaded areas in this column contain the type of sample (e.g. grab, composite, continuous) required by the permit. Enter the actual sample type that was taken in the space above the shaded area. Signature: This report must be signed in accordance with Rule 62-620.305, F.A.C. Type or print the name and title of the signing official. Include the telephone number where the official may be reached in the event there are questions concerning this report. Enter the date when the report is signed. Comment and Explanation of Any Violations: Use this area to explain any exceedances, any upset or by-pass events, or other items which require explanation. If more space is needed, reference all attachments in this area. DEP Form 62-620.910(10), effective November 29, 1994

PART B - DAI*0MPLE RESULTS Attac*nt 3 Monitoring Period: Enter the month, day, and year for the first and last day of the monitoring period (i.e. the month, the quarter, the year, etc.) during which the data on this report were collected and analyzed. Daily Monitoring Results: Transfer all analytical data from your facility's laboratory or a contract laboratory's data sheets for all day(s) that samples were collected. Record the data in the units indicated. Table t in Chapter 62-160, F.A.C., contains a complete list of all the data qualifier codes that your laboratory may use when reporting analytical results. However, when transferring numerical results onto Part B of the DMR, only the following data qualifier codes should be used and an explanation provided where appropriate. CODE DESCRIPTION/INSTRUCTIONS

     <        The compound was analyzed for but not detected.

A Value reported.is the mean (average) of two or more determinations. i Estimated value, value not accurate. Q Sample held beyond the actual holding time. Y Laboratory analysis was from an unpreserved or improperly preserved sample. Add the results to get the Total and divide by the number of days in the month to get the Monthly Average. Plant Staffing: List the name, certificate number, and class of all state certified operators operating the facility during the monitoring period. Use additional sheets as necessary. PART D - GROUND WATER MONITORING REPORT Monitoring Period: Enter the month, day, and year for the first and last day of the monitoring period (i.e. the month, the quarter, the year, etc.) during which the data on this report were collected and analyzed. Date Sample Obtained: Enter the date the sample was taken. Also, check whether or not the well was purged before sampling. Time Sample Obtained: Enter the time the sample was taken. Sample Measurement: Record the results of the analysis. If the result was below the minimum detection limit, indicate that. Detection Limits: Record the detection limits of the analytical methods used. Analysis Method: Indicate the analytical method used. Record the method number from Chapter 62-160 or Chapter 62-601, F.AC., or from other sources. Sampling Equipment Used: Indicate the procedure used to collect the sample (e.g. airlift, bucket/bailer, centrifugal pump, etc.) Samples Filtered: Indicate whether the sample obtained was filtered by laboratory (L), filtered in field (F), or unfiltered (N). Signature: This report must be signed in accordance with Rule 62-620.305, F.A.C. Type or print the name and title of the signing official. Include the telephone number where the official may be reached in the event there are questions concerning this report. Enter the date when the report is signed. Comments and Explanation: Use this space to make any comments on or explanations of results that are unexpected. If more space is needed, reference all attachments in this area. SPECIAL INSTRUCTIONS FOR LIMITED WET WEATHER DISCHARGES Flow (Limited Wet Weather Discharge): Enter the measured average flow rate during the period of discharge or divide gallons discharged by duration of discharge (converted into days). Record in million gallons per day (MGD). Flow (Upstream): Enter the average flow rate in the receiving stream upstream from the point of discharge for the period of discharge. The average flow rate can be calculated based on two measurements; one made at the start and one made at the end of the discharge period. Measurements are to be made at the upstream gauging station described in the permit. Actual Stream Dilution Ratio: To calculate the Actual Stream Dilution Ratio, divide the average upstream flow rate by the average discharge flow rate. Enter the Actual Stream Dilution Ratio accurate to the nearest 0.1. No. of Days the SDF > Stream Dilution Ratio: For each day ofdischarge, compare the minimum Stream Dilution Factor (SDF) from the permit to the calculated Stream Dilution Ratio. On Part B of the DMR, enter an asterisk (*) if the SDF is greater than the Stream Dilution Ratio on any day of discharge. On Part A of the DMR, add up the days with an "" and record the total number of days the Stream Dilution Factor was greater than the Stream Dilution Ratio. CBOD,: Enter the average CBODs of the reclaimed water discharged during the period shown in duration ofdischarge. TKN: Enter the average TKN of the reclaimed water discharged during the period shown in duration of discharge. Actual Rainfall: Enter the actual rainfall for each day on Part B. Enter the actual cumulative rainfall to date for this calendar year and the actual total monthly rainfall on Part A. The cumulative rainfall to date for this calendar year is the total amount of rain, in inches, that has been recorded since January 1 of the current year through the month for which this DMR contains data. Rainfall During Average Rainfall Year: On Part A, enter the total monthly rainfall during the average rainfall year and the cumulative rainfall for the average rainfall year. The cumulative rainfall for the average rainfall year is the amount of rain, in inches, which fell during the average rainfall year from January through the month for which this DMR contains data. No. of Days LWAVlD Activated During Calendar Year: Enter the cumulative number of days that the limited wet weather discharge was activated since January I of the current year. Reason for Discharge: Attach to the DMR a brief explanation of the factors contributing to the need to activate the limited \vet weather discharge. DEP Fo-r 62-620.91(tt0), effective November 29, 1994

Appendix A. Current Title V Air Operation Permit Appendix B Air Construction Permit 0170004-013-AC Appendix C Air Construction Permit 0170004-014-AC Appendix D Air PSD Permit PSD-FL-383 Appendix E Air PSD Permit PSD-FL-392 Appendix F NPDES Permit FL0036366 Appendix G NPDES Permit FL0000159 Appendix H WUP 20004695.004 Appendix I IWW Permit FLA016960 Appendix J IWW Permit FLA118753 Hydrology H-5

1. Crystal River Nuclear DMR Data, permit No. FLOO000159

2. Crystal River South DMR Data, permit No. FLOO000159

_ _ __ _Crystal River D ear DMR Data Permit No. FL00000159 'Beg DateA.. O I.Q-Max -A aM, MNODI-AvgC -Ma )-Avg NODI-Max NODI-Min 1/1/04 1 2/1/04 196-Hour Menidia Beryllina P-DOF (CR3) P-DOF NODI=9 1/1/04 2/1/04 196-Hour Menidia Beryllina Q-DOF (CR3) I -DOF

                                                                                                                                                                              --.. i-. .     .. .                         NODI=9 1/1/04           2/1/04       196-Hour Mysidopsis Bahia P-DOF (CR3)                P-DOF                                                                                                                                    NODI=9 1/1/04         2/1/04I96-            our Mysidopsis Bahia Q-DOF (CR3)              Q-DOF                                                                                                                                    NOD 1=9 1/1/04 V           i    2/1/04         Ammonia 1-DOF (CR3)                                1-DOF                                                                                                                   NODI=9 1/1/04                          Ammonia P-DO2(CR3)                                 P-DOF                                 - __... ____.......

NODI=9 1/1/04 2/1/04 Copper Total Recov - DOF (CR3) DOF SI-- NODI=9 NODI=9 1/1/04 2/1/04 Copper-trol - D013 (CR3) D013 NODI=9 NODI*9 1/1/04 2/1/04 Flow - IFG (CR3) IFG 0.000047 0.00145 0.00197 0.0794 1/1/04 2/1/04 Flow-CD System DOF (CR3) DOE . 0 0 1/1/04 2/1/04 Elow-ECST DOE (CR3) DOF S . 0.000197 0.001S4 1/1/04 2/1/04 Flow-Intake - DOF (CR3) DOF 15.6 15.6 1/1/04 2/1/04 Hydrazine P-DOF (CR3) P-DOF NODI=9 1/1/04 2/1/04 lHydroquinone 1-DOE (CR3) . .....- 1- .- NODI=9 1/1/04 2/1/04 Hydroquinone P-DOE (CR3) -i P-DOE -- NODI=9 1/1/04 1Iron Total Recov - DOE (CR3) DOE 4 NODI=9 NODI=9 1/1/04 2/1/04 . Morpholine 1-DOF (CR3) 1-DOF 1 51 .3 1/1/04 1 2/1/04 ýMorpholine P-DOE (CR3) -i- P-DOF NODI=9 1/1/04 2/1/04 !Number of Batches - IFE (CR3) IFE *1 1 1/1/04 2/1/04 [Oil and Grease - DOF (CR3) DOF NODI=9 1/1/04 2/1/04 lOil and Grease - CD and ECST DOF (CR3) DOF 2.C 6.4

                                                                                                                                                                                                        -- i 1/1/04      i    2/1/04         ioi and Grease - IFE (CR3)                           IFE                                                                                                                     0.5     0.5 1/1/04           2/1/04       'Oil and Grease    - IFG (CR3)                         IFG              2.9 16                             15.6                  -                                   -

1/1/04 2/1/04 IpH - Background - DOF (CR3) DOF 8.1 8.23 - .- 1/1/04 21/04 pH - Calc Limit - DOF (CR3) DOE 7.1 8.5 1/1/04 2/1/04 pH - Difference - DOF (CR3) DOF 0.98 -0.26 1/1/04 2/1/04 pH - Effluent - DOF (CR3) DOF 8.08 8.24 . 1/1/04 2/1/04 pH - IFE (CR3) jIFE NODI=B NODI=B 1/1/04 2/1/04 pH -IFG (CR3) IFG .. 8.08 8.88 1/1/04 1 2/1/04 Resid Ox -Time of Discharge D013 (CR3) D013 0 1/1/04 2/1/04 -- Spectrus CT1300 - Clamtrol DOF (CR3) DOF NODI=B 1/1/04 2/1/04 ýTemp Rise - D013 (CR3) D013 1 15. 04 16.6 1/1/04 2/1/04 ITemp-Discharge - D013 (CR3) D013 74. .4 84 I 1/1/04 i 2/1/04 !Temp-lntake - D013 (CR3) D013 5 66.4 10/21/2009 Page 1

Crystal River

ear DMR Data Permit No. FL00000159 Begi date . -. End-Date ; < ...... t 1PARAMETER.NAME.Ag

                                                                                                     . C-Mi      C-Max                 QODI-Max                          NODI-Min 1/1/04               2/1/04    iTotal Copper - DOF (CR3)                                                                                           NOOI=9       NODI=9
                                                                     -  -ji _   DOE _

1/1/04 2/1/04 iTotal Copper - IFG (CR3) IFG NODI=9 1/1/04 _ 2/1/04 iTotal Iron- DOF (CR3) DOE NODI=9 jNODI=9 1/1/04 2/1/04 Total Iron- IFG (CR3) IFG I INODI=9 1/1/04 2/1/04 Total Residual Ox 1-D013 (CR3) 1-D013 NOD1=9 NOD1=9 1/1/04 2/1/04 TSS - CD and ECST DOF (CR3) T~DOF NODI=B NODI=B 1/1/04 2/1/04 TSS - Clamtrol - DOF (CR3) DOF 66.7 72.4 1/1/04 2/1/04 ITSS - DOF (CR3) DOF NODI=9 NODI=9 1/1/04 21/04 iTSS - IFE (CR3) IFE I NODI=B NODI=B 1/1/04 21/04 TSS - IFG (CR3) IFG 8.8 17.7 1/1/04 2/1/04 Turbidity - DOF (CR3) DOF I 22 1/1/04 -2/1/04-. ITurbidity - Effluent DOF (CR3) DOF 5.4 2/1/04 3/1/04 196-Hour Menidia Beryllina P-DOF CR3) 1 P-DOF NOD1=9 2/1/04 _ 3/1/04 196-Hour Menidia Beryllina Q-DOF CR3) Q-DOF . NODI=9 I 2/1/04 3/1/04 196-Hour Mysidopsis Bahia P-DOE ( CR3) P-DOF P NODI=9 2/1/04 3/1/04 196-Hour Mysidopsis Bahia Q-DOF CR3) Q-DO E . NODI=9 2/1/04 3/1/04 Ammonia 1-DOF (CR3) 1-DOF NODI=9 2/1/04 3/1/04 !Ammonia P-DOF (CR3) I P-DOE NO. .. =9 2/1/04 3/1/04 Copper Total Recov - DOF (CR3) DOF NODI=9 NODI=9 D014 2/1/04 3/1/04 Copper-trol - D013 (CR3) NODI=9 NODI=9 2/1/04 3/1/04 Flow - IFE (CR3) IFE 0 0 2/1/04 3/1/04 Flow - IFG (CR3) IFG"

                                                                                                    -TF                            0.0183 0.0836 2/1/04               3/1/04 2/1/04               3/1/04     .Flow-CD System DOF (CR3)                      DOF                                                   0      0 2/1/04        _      3/1/04      Flow-ECST DOF (CR3)                           DOF                                                  102  0.0105 2/1/04               3/1/04      Flow-Intake - DOF (CR3)                       DOF                                                 15.82  19.38 2/1/04               3/1/04      Hydrazine 1-DOF (CR3)                        1-DOF                                                              , NODI=9i 2/1/04               3/1/04      Hydrazine P-DOF (CR3)                        P-DOF                                                              I NODI=9 2/1/04               3/1/04    lHydroquinone 1-DOF (CR3)                      1-DOF                                                                NODI=9 2/1/04               3/1/04      Hydroquinone P-DOF (CR3)                     P-DOF                                                                NODI=9 2/1/04       t       3/1/04      Iron Total Recov - DOE (CR3)                  DOF                                                                 NO01=9       N001=9 2/1/04   -           3/1/04    iMorpholine 1-DOF (CR3)                        1-DOF         41.1                                                                       --

2/1/04 3/1/04 IMorpholine P-DOF (CR3) P-DOF NODI:=9 2/1/04 3/1/04 Number of Batches - IFE (CR3) IFE 0 0 Oil and Grease - DOF (CR3) DOF

                                                                                                                -i    1.... . - .2 NODI=9 2/1/04               3/1/04 3/1/04      Oil and Grease - CD and ECST DOF CR3)         DOF           0.5                     1.2 2/1/04 10/21/2009                                                                                  Page 2

9 Crystal River ear DMR Data Penmi Bbgnatej .EndDate ""?.-PARAMETERR NAME - ut 2/1/04 3/1/04 1OilandGrease-IFE(CR3) IFE 1 NODI=9 NODI=9 2/1/04 3/1/04 oil and Grease - IFG (CR3) IFG 1.6 4.5 1 2/1/04 3/1/04 pH - Background - DOF (CR3) DOF 7.97 I 8.14 2/1/04 3/1/04 pH - Calc Limit - DOF (CR3) DOF 8 .5 . 1 n7 2/1/041 3/1/04 pH - Difference - DOF (CR3) DOF -0.31 2/1/04 3/1/04 pH - Effluent - DOF (CR3) DOE -T 8.04 8.19 JI. ... .. i. .. . .. !.. . . . 2/1/04 3/1/04 IpH- IE(CR3) I- E I NODI=9 NODI=9 2/1/04 3/1/04 pHE -I G(CR3) lFG 7.61 8.81 2/1/04 3/1/04 Resid Ox - Time of Discharge D013 (CR3) i D013 0 2/1/04- 3/1/04 _ Spectrus CT1300 - Cla mtrol DOF (CR3) DOE NODI=B 2/1/04 3/1/04 Temp Rise - D013 (CR3) D013 13.2 14.9 1 2/1/04 3/1/04 Temp-Discharge - D013 (CR3) D013 74 78.6 2/1/04 3/1/04 ITemp-Intake - D013 (CR3) D013 60.8 66.1 2/1/04 3/1/04 1Total Copper - DOF (CR3) DOE NODI=9 NODI=9 2/1/04 3/1/04 ITotal Copper - IFG (CR3) IFG NODI=9 2/1/04 3/1/04 ITotal Iron- DOF (CR3) DOF NODI=9 NODI=9 2/1/04 3/1/04 iTotal Iron- IFG (CR3) IFG NODI=9 2/1/04 3/1/04 iTotal Residual Ox 1-D013 (CR3) _1-D .... -13 NODI=9 iNODI=9 2/1/04 3/1/04 !TSS - CD and ECST DOF (CR3) DOF NODI=B NODI=B 2/1/04 1 3/1/04 ITSS - Clamtrol - DOF (CR3) DOF 2/1/04 3/1/04 ITSS -CD (CR3) DOE 52.4 57.3 2/1/04 3/1/04 1TSS -IFE (CR3) IFE NODI=9 NODI=9 2/1/04 3/1/04 ITSS - IFG (CR3) IFG NODI=9 1~NODI=9 2/1/04 3/1/04 Turbidity - DOF (CR3) DEF 9.32 -- -- ~i-16.4 2/1/04 3/1/04 ýTurbidity - Effluent DDF (CR3) _ DOF 15.4 f 3/1/04 4/1/04 T96-Hour Menitia Beryllina P-DOF (CR3) P-DOF 5.1 3/1/04 4/1/04 196-Hour Menidia Beryllina Q-DOF (CR3) Q-DOF NODI=9 3/1/04 4/1/04 196-Hour Mysieopsis Bahia P-DOF (CR3) P-DOF NODI=9 3/1/04 4/1/04 196-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NODI=9 3/1/04 4/1/04 -Ammonia1-DOF (CR3) 1-DOF NODI=9 3/1/04 4//0 Amoi 1-OE(R3..._1-O

NODI=9 ---

3/1/04 4/1/04 IAmmonia P-DOF (CR3) P-DOF E NO 01=9 3/1/04 4/1/04 Copper Total Recov - DOF (CR3) DOFE 1NODI=9 NODI=9 3/1/04 4/1/04 ]Copper-trol- D013 (CR3) D015 iNODI=9 NODI=9 3/1/04 4/1/04 Flow-IFE(CR3) IFE 0 0 3/1/04 4/1/04 Flow - IFG (CR3) IlFG 0.0173 0.0806 10/21/2009 Page 3

Crystal River S ear DMR Data Permit No. FL00000159 i te Da EiatEnd -* PARAMETER.NAME , ;OutaIL'. C*Avg. C-Min C-Max W 4.; Q-Avg N NODI-Max NODI-Min 3/1/04 4/1/04 Flow-CD System DOF (CR3) DOE 0.00953 0.163 3/1/04 4/1/04 Flow-ECST DOF (CR3) DOE I 0.00038 0.00749 3/1/04 4/1/04 Flow-Intake - DOF (CR3) DOE 15.73 16.96 3/1/04 4/1/04 Hydrazine 1-DOF (CR3) 1-DOE NODI=9 3/1/04 4/1/04 Hydrazine P-DOF (CR3) P-DOE NOD1=9 3/1/04 4/1/04 Hydroquinone 1-DOF (CR3) 1-DOE NODI=9 3/1/04 4/1/04 Hydroquinone P-DOF (CR3) P-DO F NODI=9 NODI=9 3/1/04 4/1/04 Iron Total Recov - DOF (CR3) DOE 3/1/04 4/1/04 Morpholine 1-DOF (CR3) 1-DOE 28.5 3/1/04 4/1/04 Morpholine P-DOF (CR3) ilOF P-DOE-7 NOD1=9 3/1/04 4/1/04 Number of Batches - IFE (CR3) lEE 0 0 3/1/04 4/1/04 lOil and Grease - DOF (CR3) DOF NODI=9 1.3 3/1/04 4/1/04 Oil and Grease - CD and ECST DOF (CR3) DOE 0.7 4/1/04 Oil and Grease - lEE (CR3) lEE NODI=9 NOD1=9 3/1/04 3/1/04 4/1/04 Oil and Grease - IFG (CR3) lEG 1.55 7 3/1/04 4/1/04 ] pH - Background - DOF (CR3) DOF 8.02 8.12 ____o_ i -- F

                            - Calc Limit - DOF (CR3)                                                      8.5            .. --. .

3/1/04 4/1/04 -pH DOF 7.02 1.01 -0.37 3/1/04 4/1/04 pH - Difference - DOF (CR3) DOEF 3/1/04 4/1/04 IpH - Effluent - DOF (CR3) 8.03 8.13 DOE 3/1/04 4/1/04 pH - IFE (CR3) NODI=9 NODI=9 3/1/04 4/1/04 pH - IFG (CR3) lEG 8.22 8.95 3/1/04 4/1/04 Resid Ox - Time of Discharge D013 (CR3) D013 0 3/1/04 4/1/04 Spectrus CT1300 - Clamtrol DOF (CR3) DOE NODI=B 4/1/04 Temp Rise - D013 (CR3) 17.4 3/1/04 - DO013 ~- - - 13.4 i 3/1/04 4/1/04 Temp-Discharge - D013 (CR3) D0131 81.2 88.1 3/1/04 4/1/04 Temp-Intake - D013 (CR3) D013 67.8 73 [Total Copper - DO (CR3) DFE 3/1/04 4/1/04 DOE NODI=9 NODI=9 Total Copper - lEG (CR3) 3/1/04 4/1/04 lEG NODI=9 Total Iron- DOF(CR3) , II 3/1/04 4/1/04 DOF NODI=9 NODI=9 Total Iron- lEG (CR3) 3/1/04 4/1/04 IFG~ NODI=9 3/1/04 4/1/04 Total Residual Ox 1-D013 (CR3) 1-DO13 NODI=9 NODI=9 3/1/04 4/1/04 ITSS - CD and ECST DOF (CR3) NODI=B NODI=B 3/1/04 4/1/04 TSS - Clamtrol - DOF (CR3) DOF 79.9 123.8 3/1/04 4/1/04 ITSS - DOF (CR3) DOF NODI=9 *NODI=9 3/1/04 4/1/04 ITSS -IFE (CR3) NODI=9 NODI=9 10/21/2009 Page 4

0 Crystal River *ear DMR Data Permit No. FL00000159 E.PARAMETERNAME - .1 -OutallC-Max,` .Q,-QAvgv Q-MaMax 'NODI-Min 3/1/04 4/1/04 JTSS - IFG (CR3) IFG 3.57 8.3 3/1/04 4/1/04 'Turbidity - DOE (CR3) I--- DOF 19.1 3/1/04 4/1/04 Turbidity - Effluent DOF (CR3) DOE i 9.1 4/1/04 5/1/04 96-Hour Menidia Beryllina P-DOE (CR3) P-DOE NODI=9 4/1/04 5/1/04 !96-Hour Menidia Beryllina Q-DOE (CR3) O Q-DOE NODI=9 4/1/04 5/1/04 96-Hour Mysidopsis Bahia P-DOE (CR3) P-DOE NODI=9 4/1/04 5/1/04 96-Hour Mysidopsis Bahia Q-DOE (CR3)__ Q-DOE NODI=9 4/1/04 5/1/04 jAmmonia 1-DOF (CR3) 1-DOE NODI=9 4/1/04 5/1/04 lAmmonia P-DOE (CR3) P-DOE NODI=9 DOE O NODI=9 NODI=9 i 4/1/04 5/1/04 Copper Total Recov - DOE (CR3) 4/1/04 5/1/04 ICopper-trol - D013 (CR3) _ D016 t IF-NODI=9 NODI=9 4/1/04 } 5/1/04 Elow - IEE (CR3) lEE 0 0.0149 -* 0 4/1/04 5/1/04 Flow - IEG (CR3) IFG 0.077 I 4/1/04 5/1/04 Flow-CD System DOF (CR3) DOE ........ Ii 0 4/1/04 5/1/04 Flow-ECST DOE (CR3) -IDOF 0.00252 0.0 15 4/1/04 5/1/04 Flow-Intake - DOE (CR3) DOE 16.29 18.32 4/1/04 Hydrazine 1-DOE (CR3) 1-DOE NOD 1=9 4/1/04 5/1/04 Hydrazine P-DOE (CR3) P-DOE NODI=9 4/1/04 5/1/04 IHydroquinone 1-DOE (CR3) 1-DOE NOD 1=9 4/1/04 5/1/04 lHydroquinone P-DOE (CR3) P-DOE NO. . .=9 4/1/04 5/1/04 Iron Total Recov - DOE (CR3) DOE O 0 NODI=9 NOD 1=9 4/1/04 5/1/04 Morpholine 1-DOE (CR3) 1-DOE 0 i 0 25.7 4/1/04 5/1/04 IMorpholine P-DOE (CR3) P-DOE NODI=9 _T 4/1/04 5/1/04 Number of Batches - IFE (CR3) IFE 4/1/04 5/1/04 Oil and Grease - DOF (CR3) DOF I ___ .. ... NODI=9 4/1/04 1 5/1/04 Oil and Grease - CD and ECST DOF (CR3) DOF 3.4 7 i. . . . .. . - 4/1/04 5/1/04 Oil and Grease- lE (CR3)- IFE NODI=9 NODI=9 4/1/04 1 5/1/04 1Oil and Grease - lEG (CR3) ___ ___ lEG 2.14 6.5 4/1/04 5/1/04 pH - Background - DOE (CR3) DOE I ~ ~~~7.89.......... 8.12 4/1/04 5/1/04 pH - Calc Limit_- DOE (CR3) DOE 6.89 I 8.5 4/1/04 5/1/04 pH - Difference - DOE (CR3) DOE 0.98 -0.37 4/1/04 5/1/04 2pH - Effluent - DOE (CR3) DOE 7.87 8.13 4/1/04 5/1/04 pH - IFE (CR3) IlEE NOD1=9 NODI=9 4/1/04 5/1/04 pH - lEG (CR3) ._lEG 8.46 8.73 4/1/04 5/1/04 iResid Ox- Time of Discharge D013 (CR3) I D013 0 10/21/2009 Page 5

Crystal River R ear DMR Data 0 Permit No. FL00000159 B4nat <OBe Ed~ate in~

                             .     ~~~~~~~~~~~~~           NAM PARAMETaR NAMED-Minn.

______________________________________________ C ______

                                                                                                                                   -:Ota     Q-Av Q-Max,,'        NODI-AvgIN6-a-1 'ND-i

________1_______9__________ I 4/1/04 5/1/04 ISpectrus CT1300 - Clamtrol DOF (CR3) DOF I NODI=B

4/1/ 04 5/1/04 Temp Rise - D013 (CR3) D013 14.2 15.9 95.4 4/l/ 04 5/1/04 Temp-Discharge - D013 (CR3) D013 86 5/1/04 Temp-Intake D013 (CR3) D013 71.7 78.5 -4/1/ 04 - 4/l/ 04 5/1/04 Total Copper - DOF (CR3) DOF NO D 1 NODI=9 IFG -- l 4/l/ 004 5/1/04 _Total Copper - IFG (CR3) NODI=9 4/1/ 04 5/1/04 ITotal Iron- DOF (CR3) -~DOE ____ NODI=9 NODI=9 4/l//04 5/1/04 ITotal Iron- IFG (CR3) IFG NOD1=9 4/l/ 04 5/1/04 Total Residual Ox 1-D013 (CR3) 1-D013 NOD1=9 NODI=9 4/1/ 04 5/1/04 TSS - CD and ECST DOE (CR3) DOF NODI=B NODI=B 4/1/ 04 [ 5/1/04 TSS - Clamtrol - DOF (CR3) DOF 48.2 59.9 4/1/ 04 1 5/1/04 TSS - DOE (CR3) DOF _ NODI=9 NODI=9 4/l/ 04 1 5/1/04 TSS - IFE (CR3) IFE _ NODI=9 NOD1=9 4/l/ 04 5/1/04 -ITSS - IFG (CR3) IFG 7.61 9.8 4/1/ 04 5/1/04 Turbidity - DOF (CR3) DOE 18 4/l/ 04 5/1/04 _Turbidity - Effluent DOF (CR3) DOF 9.1 5/l/ 04 1 6/1/04 196-Hour Menidia Beryllina P-DOF (CR3) NODI=9 _P-DOE 5/1/ 04 I 6/1/04 196-Hour Menidia Beryllina Q-DOF (CR3) O-DOF NODI=9 5/l/ 04 6/1/04 96-Hour Mysidopsis Bahia P-DOF (CR3) P-DOF NODI=9 5/l/ 04 6/1/04 ý6-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NODI=9 __7 5/l/ 04-] 6/1/04 -Ammonia 1-DOF (CR3) 1-DOF I NODI=9 5/l/ 04 6/1/04 Ammonia P-DOF (CR3) P-DOF NODI=9 5/l/ 04 6/1/04 _ICopper Total Recov - DOE (CR3) NODI=9 NODI=9 5/l/ 04 6/1/04 Copper-trol - D013 (CR3) DOE1 NODI=9 NODI=9 5/l/ 04 - 6/1/04 Flow - IFE (CR3) lEE 0 .000047 0.0014 Flow - IFG (CR3)

                                                                                  -i 5/l/ 04         6/1/04                                                                                                                       0.0191       0.079 5/1/ 04         6/1/04      Flow-CD System DOF (CR3)                                       IEGI         ___                                      0           0 DOE 5/l/ 04         6/1/04      IFlow-ECST DOF (CR3)                                                                                             0.00095      0.015 DOE 5/l/ 04         6/1/04      Flow-Intake - DOF (CR3)                                                                                           15.58       16.34 5/1/ 04         6/1/04      Hydrazine 1-DOF (CR3)                                     I   1-DOF                  -                                                         NO 01=9 5/1/ 04         6/1/04      Hydrazine P-DOF (CR3)                                          P-DOF                                                                           NO 01=9 I              ___                 J 5/l/ 04         6/1/04    1Hydroquinone 1-DOF (CR3)                                   I1-DOE                                                                               NO01=9 5/l/ 04         6/1/04      Hydroquinone P-DOF (CR3)                                                                                                                       NODI=9 P1-°°DOE7 5/1/i 04    [   6/1/04      Iron Total Recov - DOF (CR3)                                   DOE                                                                             NODI=9    NODI=9 5/l/i04_        6/1/04      Morpholine 1-DOF (CR3)                                        1-DOE               27 10/21/2009                                                                                                  Page 6

Crystal River Dear DMR Data Permit No. FL00000159 date jEnd Datei< Ký .PARAMETE§R'NAME -" Out

                                                                 ~OtI[:

P-DOF C-

                                                                              ;~Vg
                                                                                          <  <CMn.<CMx
                                                                                                        -.-       ~
                                                                                                                          -A QAvg QMax-ý NODIAvV NODI=9 ND-Min NODI-IMaxNO 5/1/04         6/1/04  Morpholine P-DOF (CR3) 5/1/04         6/1/04   Number of Batches - FE (CR3)                 IFE                                                    1    1 Oil and Grease - DOF (CR3)                   DOF                                                                        NODI=9 5/1/04         6/1/04 5/1/04     [   6/1/04  Oil and Grease - CD and ECST DOF (CR3)       DOF           0. 35                         1    j 5/1/04         6/1/04  Oil and Grease - IFE (CR3)                    IFE                                                                 8.9     8.9 5/1/04         6/1/04   Oil and Grease - IFG (CR3)                   IFG     -    0. 91                        2.4 5/1/04         6/1/04   pH - Background - DOF (CR3)                 DOF                         8.01          8.2 5/1/04         6/1/04   pH - Calc Limit - DOF (CR3)                 DOF                         7.01           8.5 5/1/04         6/1/04   pH - Difference - DOF (CR3)                 DOF                         0.97         -0.28 5/1/04     [   6/1/04   pH - Effluent - DOF (CR3)                   DOF                         7.98         8.22 5/1/04         6/1/04   pH - IFE (CR3)                               IFE                                                                        8.35      8.35 6/1/04   pH    IFG (CR3)                              IFG                        8.51           8.9 5/1/04                      -

5/1/04 6/1/04 Resid Ox - Time of Discharge D013 (CR3) D013 0 5/1/04 1 6/1/04 Spectrus CT1300 - Cla mtrol DOF (CR3) DOF I NODI=B 5/1/04 6/1/04 !Temp Rise - D013 (CR3) D013 1 29 15.3 5/1/04 6/1/04 Temp-Discharge - D013 (CR3) D013 92D.9 96.1 5/1/04 6/1/04 Temp-Intake - D013 (CR3) D013 8C -87.4 Total Copper - DOF (CR3) D0F NODI=9 NODI=9 5/1/04 6/1/04 5/1/04 f 6/1/04 Total Copper - IFG (CR3) IFG ---- NODI=9 5/1/04 { 6/1/04 Total Iron- DOF (CR3) D0F NODI=9 NODI=9 5/1/04 6/1/04 Total Iron- IFG (CR3) IFG NOD1=9 5/1/04 6/1/04 Total Residual Ox 1-D013 (CR3) 1-DO13 NODi=9 NODI=9 5/1/04 6/1/04 TSS - CD and ECST DOF (CR3) NODI=B NODI=B DOF 58 5/1/04 6/1/04 TSS - Clamtrol - DOF (CR3) .9 113 5/1/04 6/1/04 TSS - DOF (CR3) DOF NOD1=9 NOD1=9 5/1/04 j 6/1/04 TSS - IFE (CR3) lEE NODI=B NODI=B3 5/1/04 6/1/04 TSS - IFG (CR3) IFG 6.' 41 11.7 5/1/04 6/1/04 Turbidity - DOF (CR3) DDOF 20 5/1/04 6/1/04 Turbidity - Effluent DOF (CR3) DOF 12.8 6/1/04 7/1/04 96-Hour Menidia Beryllina P-DOF (CR3) P-DOF - _ NOD1=9 6/1/04 7/1/04 96-Hour Menidia Beryllina Q-DOF (CR3) Q-DOF - NOD1=9 6/1/04 7/1/04 96-Hour Mysidopsis Bahia P-DOF (CR3) P-DOEF 7[_ NODt=9 6/1/04 7/1/04 96-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NOD1=9 6/1/04 7/1/04 Ammonia 1-DOF (CR3) 1-DOF NODI=9 6/1/04 7/1/04 Ammonia P-DOF (CR3) P-DOF NODI=9 10/21/2009 Page 7

Crystal River ear DMR Data Permit No. FLOO000159

          , :_,       II.                   -'11 .. .. 11..-        1           II - C-',g               'cMa nd Date Iei~ae~               K~PARAMETERNAME                      ut<.   '"                               '-:  Q-v C'a.           Q-., a 1"irj.       NOI
                                                                                                                                               ",6" -  g. NODW-Ma  NODII-Min 6/1/04           7/1/04      Copper Total Recov - DOF (CR3)              DOF                                                                     NODI=9     NODI=9 6/1/04           7/1/04      Copper-trol- 0013 (CR3)                    D018                                                                     NODI=9     NODI=9 6/1/04           7/1/04      Flow - IFE (CR3)                              IFE                                            0               0 6/1/04           7/1/04      Flow - IFG (CR3)                             IFG                                         0.0178           0.0791 6/1/04           7/1/04      Flow-CD System DOF (CR3)                    DOF                                              0               0 6/1/04           7/1/04      FIow-ECST DOF (CR3)                         DOF                                          0.00156         0.0142 6/1/04           7/1/04      Flow-Intake - DOF (CR3)                     DOF                                           17.98             20.3 iHydrazine 1-DOF (CR3)                      1-DOF                                                                    NODI=9
                                                                    -IF 6/1/04           7/1/04 6/1/04           7/1/04     jHydrazine P-DOF (CR3)                      P-DOF                                                                    NODI=9 6/1/04           7/1/04      Hydroquinone 1-DOF (CR3)                   1-DOF                                                                    NOI0=9 6/1/04           7/1/04      Hydroquinone P-DOF (CR3)                   P-DOF                                                                    NODI=9 6/1/04           7/1/04      Iron Total Recov - DOF (CR3)                DOF                                                                     NODI=9     NODI=9 6/1/04           7/1/04      Morpholine 1-DOF (CR3)                     1-DOF         31.4       ___

6/1/04 7/1/04 Morpholine P-DOF (CR3) P-DOF NODI=9 6/1/04 7/1/04 Number of Batches - IFE (CR3) IFE 0 0 6/1/04 7/1/04 jOil and Grease - DOF (CR3) DOF NODI=9 6/1/04 7/1/04 Oil and Grease - CD and ECST DOF (CR3) DOF 0.35 6/1/04 7/1/04 Oil and Grease - IFE (CR3) IFE NODI=9 NODI=9 6/1/04 7/1/04 Oil and Grease - IFG (CR3) IFG 1.39 4.4 6/1/04 7/1/04 pH - Background - DOF (CR3) DOF 8.08 8.23 6/1/04 7/1/04 pH - Calc Limit - DOF (CR3) DOF 7.08 8.5 6/1/04 7/1/04 pH - Difference - DOF (CR3) , 0.91 -0.31

                                                                                                                             - -I..

DOF I 6/1/04 7/1/04 jpH - Effluent - DOF (CR3) DOF 7.97 8.19 6/1/04 7/1/04 pH - IFE (CR3) IFE NODI=9I NODI=9 6/1/04 7/1/04 pH - IFG (CR3) IDFG 8.74 8.95 6/1/04 7/1/04 Resid Ox - Time of Discharge D013 (CR3) D013 0 6/1/04 7/1/04 Spectrus CT1300 - Clamtrol DOF (CR3) DOE NODI=B 6/1/04 7/1/04 TempRise - 0013 (CR3)__ D013 6.5 8 6/1/04 7/1/04 ITemp-Discharge - D013 (CR3) D013 94.1 96.8 6/1/04 7/1/04 -Temp-Intake - D013 (CR3) D013 87.6 90.7 6/1/04 7/1/04 ITotlnCopper - DOF (CR3) DOF NODI=9 - NODI=9 6/1/04 7/1/04 ITotal Copper - OFG (CR3) NODI=9 6/1/04 7/1/04 ITotal Iron- DOF (CR3) DOF NOD1=9 NODI=9 6/1/04 7/1/04 ýTotal Iron- IFG (CR3) IFG NODI=9 6/1/04 [ 7/1/04 ITotal Residual Ox 1-0013 (CR3) 1-D013 NODI=9 NODI=9 10/21/2009 Page 8

Crystal River S ear DMR Data Permit No. FL00000159

Begin date I End Date -' .PARAMETER NAME 06 tall , 'C-Ag.:, C-Min. C-Max Q-Avg Q-Max NODI-Avg NODI-Max NODI-Min 6/1/ '04 1 7/1/04 ITSS - CD and ECST DOF (CR3) DOF NODI=B NODI=B 6/l/ '04 7/1/04 TSS - Clamtrol - DOF (CR3) 0 OF 84.2 121.6 04 7/1/04 ITSS- DOF (CR3) [_U OF

                                                                                                      -t      -                                                NODI=9         NODI=9 6/1/ '04           '711104      _TSS - 'FE (CR3)                            I .1 6/l/                                                                            FE                                                                           NODI=9         NODI=9 6/l/ '04           7/1/04        ITSS- IFG (CR3)            __I_

FG 4.37 10.1 6/l/'04 7/1/04 Turbidity - DOF (CR3) D)OF 22.7 i

                                                                                  )OF                                  10.2 6/l/ '04           7/1/04         Turbidity -  Effluent DOE (CR3) 7/l/ '04           8/1/04         96-Hour Menidia Beryllina P-DOF (CR3)      P- DOF                                                       i                                            NODI=9 7/l/ '04           8/1/04        196-Hour Menidia Beryllina Q-DOF (CR3)      Q- DOF      [                                                                                             NODI=9 7/l/ '04           8/1/04         96-Hour Mysidopsis Bahia P-DOF (CR3)       P- DOF                                             I                                                      NODI:9 N001=9 7/l/ /04           8/1/04        196-Hour Mysidopsis Bahia Q-DOF (CR3)       Q-DOF                 -i F    __                      NDI=

7/l/ '04 _. 8/1/04 lAmmonia 1-DOF (CR3) 1- DOF NODI=9 7/l/'04 8/1/04 Ammonia P-DOF (CR3) 7/1/ '04 8/1/04 Copper Total Recov- DOF (CR3) D NODI=9

                                                                                                                                                                               .NODI9 DOE 019 7/l/ '04           8/1/04        ICopper-trol - D013 (CR3)                   D(                                                           I            F     NODI=9         NODI=9 7/l/ '04           8/1/04        lFlow - IFE (CR3)                             I                                                    0   1          0 7/l/ '04           8/1/04         Flow-IFG (CR3)                               IFG      I_                                       0.0193        0.0798 7/l/ '04           8/1/04         Flow-CD System DOF (CR3)                    D                                                     O              0 7/l/ '04           8/1/04         Flow-ECST DOF (CR3)                         D0OF                                             F0.00167        0.0151
                                                                                  )OF 7/l/ '04           8/1/04         Flow-Intake - DOF (CR3)                     D                                                   15.9          203*

7/l/ '04 8/1/04 Hydrazne 1-DOE (CR3) 1-1DOF NODI=9 ' D0F I I 7/l/ '04 8/1/04 Hydrazine P-DOF (CR3) P-1 - -~N F N 7/l/ '04 8/1/04 IHydroquinone 1-DOF (CR3) 1- D0F F ODI=9 7/l/ 04 8/1/04 _ Hydroquinone P-DOF (CR3) P-iDOF F F __NOD1=9 7/l/ 04 8/1/04 Iron Total Recov - DOF (CR3) K D)OFj DOE DOF _22.9 NODI=9 [ NODI=9 I 7/l/ 04 8/1/04 Morpholine 1-DOF (CR3) 1-1DOF 7/1/ 04 8/1/04 Morpholine P-DOF (CR3) P-I _NODI=9 ~ _ 7/l/ 04 8/1/04 Number of Batches - IFE (CR3) IIOFE 00 7/l/ 04 8/1/04 _Oil and Grease - DOF (CR3) D 4.4i i F NODN=9 OF 1.1 7/l/ 04 8/1/04 Oil and Grease - CD and ECST DOF (CR3) DFOE 7/l/ 04 8/1/04 Oil and Grease-IFE (CR3) II NODI=C . NODI=C OF FG 0.82 7/l/ 04 8/1/04 1Oil and Grease - IFG (CR3) IF 1.9 . 8.17 I 7/l/ 04 8/1/04 ppH- Background - DOF (CR3) I DOF 7.97

                                                                                                                                                        'i, i

7/l/ 04 8/1/04 PH - Calc Limit - DOF (CR3) D 6.97 I 8.5 7/l/ 04 8/1/04 [pH - Difference - DOF (CR3) D 0.94 0.29 10/21/2009 Page 9

0 Crystal River ear DMR Data Permit No. FL00000159 dt Bei ndate P<,ARAMETER-NAME Outalt C-Avg C.,M in! C-Max, QAvg Q Q°Max.. NODI-Avg; NODI-Max "NODI-Min i 7/1/04 8/1/04 pH - Effluent - DOF (CR3) DOF 7.9 1 8.21 IFE 7/1/04 8/1/04 pH - IFE (CR3) Ii IFG 7.7 1 8.84 NODI=C NODI=C 7/1/04 8/1/04 pH - IFG (CR3) 7/1/04 8/1/04 Resid Ox - Time of Discharge D013 (CR3) D013 -- 0 8/1/04 Spectrus CT1300 - Clamtrol DOF (CR3) DOE NODI=B 7/1/04 7/1/04 8/1/04 Temp Rise - D013 (CR3) 0013 6.4 9.8 i _ 7/1/04 D013 94.1 96.2 I ! 8/1/U4 ilemp-Ulscnarge - D013_ (IC1) 7/1/04 8/1/04 Temp-Intake - D013 (CR3) _ D013 87.6 _ 90.8 7/1/04 8/1/04 Total Copper - DOF (CR3) DOF NODI=9 NO 01=9 7/1/04 1 8/1/04 Total Copper - IFG (CR3) IFG NODI=9 7/1/04 8/1/04 Total Iron- DOF (CR3) DOF NOD1=9 NO001=9 7/1/04 . 8/1/04 Total Iron- IFG (CR3) IFG NODI=9 7/1/04 8/1/04 Total Residual Ox 1-D013 (CR3) 1-D013 NODI=9 NO 01=9

                                                                                                                       ~ .. . ...
                                                                                                                     - -i1           i. .

NODI=B NOD1=B 7/1/04 8/1/04 ITSS - CD and ECST DOF (CR3) DOE _ 7/1/04 8/1/04 [TSS- Clamtrol - D0F (CR3) DOF 49 55.7 7/1/04 8/1/04 TSS- DOF (CR3) - _ DOF - NODI=9 NODI=9I IFE NODI=C 7/1/04 8/1/04 TSS - IFE (CR3) 7/1/04 8/1/04 TSS - IFG (CR3) IFG 16.55 52.1 7/1/04 8/1/04 Turbidity - DOF (CR3) DOF 21.8 7/1/04 8/1/04 Turbidity - Effluent DOF (CR3) DOF 12 8/1/04 9/1/04 96-Hour Menidia Beryllina P-DOF (CR3) P-DOF NODI=9 8/1/04 9/1/04 96-Hour Menidia Beryllina Q-DOF (CR3) Q-DOF NODI=9 8/1/04 9/1/04 96-Hour Mysidopsis Bahia P-DOF (CR3) P-DOF NODI=9 8/1/04 9/1/04 96-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NODI=9 Ii 8/1/04 9/1/04 jAmmonia 1-DOF (CR3) 1-DOF NODI=9 8/1/04 9/1/04 Ammonia P-DOF (CR3) P-DOF NODI=9 8/1/04 9/1/04 _lCopper Total Recov - DOF (CR3) DOF NOE01=9 NODI=9 8/1/04 9/1/04 Copper-trol - D013 (CR3) D020 NO 01=9 NODI=9 8/1/04 9/1/04 Flow - IEE (CR3) IFE _ 0.000043 0.0134 iFG 8/1/04 9/1/04 Flow - IFG (CR3) 0.0189 0.0781 I _______ 8/1/04 9/1/04 Flow-CD System DOF (CR3) DOF 0 0 8/1/04 9/1/04 Flow-ECST DOF (CR3) DOF 0.00144 0.00749

                                                                                                       ~~~~~1~~L 8/1/04         9/1/04     Flow-Intake - DOF (CR3)                       DOF                                                    15.67       17.88 8/1/04         9/1/04     Hydrazine 1-DOF (CR3)                        1-DOE                                                                        NODI=9 8/1/04   -     9/1/04   iHydrazine P-DOF (CR3)                         P-DOE                                                                        N001=9 10/21/2009                                                                          Page 10

Crystal River s ear DMR Data Permit No. FL00000159 ~Begin date End Date, ~ PARAMETER NAME ~ ~ Outal ~C-Avg, CMin C-Max __"i-Avg ODIMa

                                                                                                                                                  .06-'Avgý 'NODI-Max NODI-M6"!Vin Hydroquinone 1-DOF (CR3)                         _  1-DOE                                                       NODI=9 8/1/04            9/1/04 8/1/04             9/1/04         Hydroquinone P-DOE (CR3)                           P-DOE    _           1                                      NODI=9 DOE                                                        NODI=9      NODI=9 8/1/04             9/1/04         Iron Total Recov - DOF (CR3) 8/1/04             9/1/04         Morpholine 1-DOF (CR3)                             1-DOF        26.6     I 8/1/04            9/1/04         Morpholine P-DOF (CR3)                              P-DOE           --                                    1 NODI=9 1 i 8/1/04             9/1/04         Number of Batches - lEE (CR3)                        IEE 8/1/04             9/1/04        Oil and Grease - DOE (CR3)                           DOF                                                                    NODI=9 8/1/04             9/1/04        Oil and Grease - CD and ECST DOF (CR3)               DOE         0.97 1                      1 8/1/04             9/1/04         Oil and Grease - IFE (CR3)                           IFE 8/1/04             9/1/04         Oil and Grease - lEG (CR3)                           IEG        0.84 1------

8/1/04 9/1/04 pH - Background - DOE (CR3) DOE 7.74 8. 8/1/04 9/1/04 pH - Calc Limit - DOF (CR3) DOE 6.74 8.5 1.22 0.3'4 8/1/04 9/1/04 pH - Difference - DOE (CR3) j i DOF FE 8/1/04 9/1/04 pH - Effluent - DOF (CR3) _ DOF i 7.96 8.1 6 8/1/04 9/1/04 pH - lEE (CR3) 6.82 6.82 8/1/04 9/1/04 pH - lEG (CR3) lEG 7.75 8.95 8/1/04 9/1/04 Resid Ox - Time of Discharge DC31*3 (CR3) D013 0 F( 8/1/04 9/1/04 Spectrus CT1300 - Clamtrol DOF R3) DOE DF NODI=B 8/1/04 9/1/04 Temp Rise - D013 (CR3) D013 8.1 11.2 8/1/04 9/1/04 Temp-Discharge - D013 (CR3) D013 93.8 96.2 8/1/04 9/1/04 Temp-Intake - D013 (CR3) D013 85.7 88.2 8/1/04 9/1/04 Total Copper - DOE (CR3) DOE NODI=9 NODI=9 8/1/04 9/1/04 Total Copper - lEG (CR3) NODI=9 8/1/04 9/1/04 fTotal Iron- DOE (CR3) DOE NODI=9 NODI=9 8/1/04 9/1/04 Total Iron- lEG (CR3) lEG NODI:9 8/1/04 9/1/04 Total Residual Ox 1-D013 (CR3) 1-D013 NODI=9 NODI=9 8/1/04 9/1/04 -TSS - CD and ECST DOE (CR3) DOE NODI=B NODI=B 8/1/04 9/1/04 ITSS - Clamtrol - DOE (CR3) DOE 35 I 49.3 8/1/04 9/1/04 TSS_- DOE (CR3) I DOE NODI=9 NODI=9 8/1/04 9/1/04 TSS - lEE (CR3) lEE NODI=B NODI=B 8/1/04 9/1/04 ITSS - lEG (CR3) IEG 7.8 13 8/1/04 9/1/04 Turbidity - DOE (CR3) DOE 23.6 9/1/04 -Turbidity-----Effluent DOE (CR3) 8/1/04 DOE _ i 12.2 9/1/04 10/1/04

               - 9/1/04 10/1/04_____    96-Hour Menidia
                                  ý96----..oi,            Beryllina Meniclia Ber     --a P-DOE ( CR3)    P-DOE                                                                            NODI=9 9/1/04            10/1/04       196-Hour Menidia Beryllina Q-DOF (CR3)               Q-DOEF                                                                           NODI=9 10/21/2009                                                                                      Page 11

0 Crystal River s ear DMR Data Permit No. FL00000159 -__________________________ Be indate EndDate PAAEE NAM C-MmN0I-~ C-Max. Ma. NOIIa ______ - Oual C-v C4Min. C'Max_____ Q-Avg .. k-Mx NDAv NOIax OIMn 10/1/04 196-Hour Mysidopsis Bahia P-DOF (CR3) P-DOF NODI=9 9/1/04 10/1/04 96-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NOD-=9 9/1/04 9/1/04 10/1/04 Ammonia 1-DOF (CR3) 1-DOF NODI=9 9/1/04 10/1/04 Ammonia P-DOF (CR3) P-DOF NODI=9I 9/1/04 10/1/04 Copper Total Recov- DOF (CR3) DOF NOI7NODI=9 9/1/04 10/1/04 lCopper-trol - D013 (CR3) D021 NOD1=9 NODI=9 9/1/04 10/1/04 Flow - IFE (CR3) IFE 0.000042 0 0.0013 9/1/04 10/1/04 lFlow - FG (CR3) I DFG 0.0123 0.0778 9/1/04 10/1/04 JFlow-CD System DOF (CR3) D0F 0.0078o4 0.235 9/1/04 10/1/04 Flow-ECST DOF (CR3) DOF - 0.00194 0.015 F 9/1/04 10/1/04 Flow-Intake - DOF (CR3) DOF 16.54 20.3 9/1/04 10/1/04 Hydrazine 1-DOF (CR3) 1-DOF NODI=9 9/1/04 10/1/04 Hydrazine P-DOF (CR3) P-DOF NODI=9 iF 9/1/04 F 10/1/04 [Hydroquinone 1-DOF (CR3) 1-DOF NODI=9f - 9/1/04 - 10/1/04 ýHydroquinone P-DOF (CR3) P-DOF NODI=9 lF 9/1/04 10/1/04 Iron Total Recov - DOF (CR3) DOF NODI=9 INODI=9 t 1-DOF 38.2 J 9/1/04 10/1/04 Morpholine 1-DOF (CR3) 9/1/04 10/1/04 Morpholine P-DOF (CR3) P-DOF I 1 NODI=9 IFE 1 1 9/1/04 10/1/04 Number of Batches - IFE (CR3) 9/1/04 10/1/04 ýOil and Grease - DOF (CR3) DOF N001=9 9/1/04 !10/1/04 TOil and Grease - CD and ECST DOF (CR3) DOE 0.23 9/1/04 [ 10/1/04 Oil and Grease - IFE (CR3) -IFE 0.7 0.7 10/1/04 Oil and Grease - IFG (CR3) lEG 9/1/04 2.35 8.6 9/1/04 10/1/04 pH - Background - DOF (CR3) _ DOF 7.64 8.08 9/1/04 10/1/04 pH - Calc Limit - DOF (CR3) DOF 6.64 8.5 9/1/04 10/1/04 pH - Difference - DOF (CR3) DOF I 1.05 -0.35 9/1/04 10/1/04 PH- Effluent-DOE (CR3) DOE 7.69 8.15 9/1/04 10/1/04 !pH-lEE (CR3) IFE 6.6 6.6 9/1/04 10/1/04 pH - IFG (CR3) IFG ] 8.3 8.93 9/1/04 10/1/04 Resid Ox- Time of Discharge D013 (CR3) D013 0 9/1/04 10/1/04 ISpectrus CT1300 - Clamtrol DOF (CR3) DOF NODI=B 10/1/04 ITempRise - D013 (CR3) _ D013 9/1/04 10.1 13.4 9/1/04 10/1/04 Temp-Discharge - D013 (CR3) D013 I.. 92 101.9 9/1/04 10/1/04 ITemp-Intake - D013 (CR3) D013 82.1 88.4 9/1/04 10/1/04 ýTotal Copper - DOF (CR3) DOF NODI:=9 NODI=9 10/21/2009 Page 12

Crystal River sear DMR Data ABegin date ~End<Date< .. PARAMETERNAME 9/1/04 10/1/04 ITotal Copper -IFG (CR3) NODI=9 9/1/04 10/1/04 ITotal Iron- DOF (CR3) DOF i NODI=9 NODI=9 9/1/04 10/1/04 ITotal Iron- IFG (CR3) lEG NODI=9 9/1/04 10/1/04 Total Residual Ox 1-D013 (CR3) 1_-ID013 NODI=9 NODI=9 9/1/04 10/1/04 TSS - CD and ECST DOE (CR3) DOE NODI=B KNODI=B 9/1/04 10/1/04 -TSS - Clamtrol - DOF (CR3) DOF 46.3 53.5 NODI=9 NODI=9 9/1/04 10/1/04 JTSS- DOF (CR3) DOE' -_ 9/1/04 10/1/04 TSS-IFE (CR3) lFE NODI13jNODI=B 9/1/04 10/1/04 TSS - IFG (CR3) IOFG 5.67 _ 12 9/1/04 10/1/04 Turbidity - DOF (CR3) 21.8 9/1/04 10/1/04 Turbidity - Effluent DOF (CR3) DOF _j_ 22.3 10/1/04 11/1/04 96-Hour Menidia Beryllina P-DOF (CR3) P-DOF I NODI=9 10/1/04 11/1/04 96-Hour Menidia Beryllina Q-DOF (CR3) 0-DOF NODI=9 10/1/04 11/1/04 96-Hour Mysidopsis Bahia P-DOF (CR3) P-DOF NODI=9 10/1/04 11/1/04 196-Hour Mysidopsis Bahia Q-DOF (CR3) 0-DOE NODI=9 10/1/04 { 11/1/04 lAmmonia 1-DOF (CR3) 1-DOF NODI=9 10/1/04 T 11/1/04 !Ammonia P-DOF (CR3) P-DOF NOD 1=9 10/1/04 I 11/1/04 Copper Total Recov - DOF (CR3) DOF NODI=9 NODI=9 10/1/041 11/1/04 Copper-trol - D013 (CR3) D022 NODI=9 \IODI=9 10/1/04 11/1/04 Flow - IFE (CR3) IFE 0 0 10/1/04 11/1/04 Flow - IFG (CR3) IFG . . 0.02.11 0.0812 10/1/04 1 11/1/04 IFlow-CD System DOF (CR3) DOF 0 0 10/1/04 i 11/1/04 1Flow-ECST DOF (CR3) DOF 0.00757 10/1/04 j 11/1/04 Flow-Intake - DOF (CR3) DOE _ 15.9 20.3 10/1/04 11/1/04 Hydrazine 1-DOF (CR3) 1-DOF NODI=9 10/1/04 10/l04--Hydrazine 11/1/04 P-DOE (CR3) Hydroquinone 1-DOF (CR3)

                                                                       ....i D-P-DOE F]T:-- .i ..

NODI=9 10/1/04 11/1/04 IHydroquinone P-DOF (CR3) P-DOF NODI=9 F 10/1/04 11/1/04 Iron Total Recov - DOF (CR3) DOE flDI=9 10/1/04 11/1/04 Morpholine 1-DOF (CR3) 1-DOF 37.4 10/1/04 F_11/1/04 -IMorpholine P-DOE (CR3) P-DOF NODI=9

                                                                         !     IFE  I 10/1/04           11/1/04      Number of Batches - IFE (CR3)                                                                                 0         0

2. 8 10/1/04 [ 11/1/04 lOil and Grease - DOF (CR3) DOE NODI=9 10/1/04 11/1/04 lOil and Grease - CD and ECST DOF (CR3) DOF 1.47 -

10/1/04 I 11/1/04 Oil and Grease - IFE (CR3) iFE [ NODI=C , NODI=C 10/21/2009 Page 13

0 Crystal River Sear DMR Data Permit No. FL00000159

                                                                      'j   ,ýOutal ):*lg C-Avg        -Min .a. , C-Max  ,-,Q-Avg:  , Q-Max    D.*..I          NODIM Begindate*      EndDate            <          PARAMETER-NAME 10/1/04        11/1/04        Oil and Grease - IFG (CR3)                       IFG         1.62                    5.4 10/1/04        11/1/04        pH - Background - DOF (CR3)                     DOE                     7.18        7.88 10/1/04         11/1/04      }pH- Calc Limit- DOF (CR3)        _              DOE                      6.5          8.5 10/1/04        11/1/04        pH - Difference - DOF (CR3)                     DOE                     1.26        -0.52 10/1/04         11/1/04      IpH - Effluent_- DOF (CR3)     _                  DOE                    7.65         7.98 10/1/04         11/1/04       pH-IFE (CR3)                                     lEE                                                                     NODI=C  NODI=C-10/1/04         11/1/04       pH  -   FG (CR3)                           I                            8.48        8.97 10/1/04         11/1/04       Resid Ox -Time of Discharge D013 (CR3)[         D013                                   0 10/1/04         11/1/04       Spectrus CT1300 - Clamtrol DOF (CR3)  _          DOFE                                                                    NODI=B 10/1/04    1    11/1/04      ITemp Rise - D013 (CR3)                          D013         12.4                    14.3 10/1/04    1    11/1/04      iTemp-Discharge - D013 (CR3)                     D013         91.6                    95.4 10/1/04         11/1/04      {Temp-lntake - D013 (CR3)

D013 79.2 84.6 10/1/04 11/1/04 !Total Copper - DOF (CR3) DOF NO 01=9 N001=9 10/1/04 11/1/04 ITotal Copper - IFG (CR3) _ IFG NODI=9 10/1/04 11/1/04 TTotal Iron- DOF (CR3) DOF NODI=9 NODI=9 10/1/04 11/1/04 Total Iron- lIG (CR3) IFGG NODI=9 10/1/04 [ 11/1/04 ITotal Residual Ox 1-D013 (CR3) 1-DO13 NOD1=9 NODI=9 10/1/04 11/1/04 ýTSS - CD and ECST DOF (CR3) DOE NODI=B N001=8 73.1 i 107.5 10/1/04 11/1/04 LTSS -Clamtrol - DOE_(CR3) DOE 10/1/041 1/1/04 TS - DOE

                      ._. ....... c    (CR3)       -f 10/1/04         11/1/04      !TSS   - DOF (CR3)                                DOE                                                          NODI=9     NODI=9 10/1/04         11/1/04      ITSS-IFE (CR3)                                    lEE                                                          NODI=C     NODI=C 10/1/04         11/1/04      !TSS -IFG (CR3)

IEG 10.55 19.3 10/1/04 11/1/04 Turbidity - DOF (CR3) DOE 28.7 10/1/04 11/1/04 {Turbidity - Effluent DOF (CR3) DOE 11.5 11/1/04 12/1/04 196-Hour Menidia Beryllina P-DOF (CR3)_ _ P-DOE NODI=9 11/1/04 12/1/04 96-Hour Menidia Beryllina Q-DOF (CR3) 0.-DOE NODI=9 11/1/04 F 12/1/04 96-Hour Mysidopsis Bahia P-DOF (CR3) P-DOF NODI=9 11/1/04 1 12/1/04 196-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NODI=9 11/1/04 12/1/04 Ammonia 1-DOF (CR3) 1-DOF NODI=9 11/1/04 12/1/04 [Ammonia P-DOF (CR3) I P-DOF NODI=9 11/1/04 12/1/04 Copper Total Recov - DOF (CR3) DOF NODI=9 NODI=9 11/1/04 12/1/04 [Copper-trol - D013 (CR3) D023 NODI=9 NODI=9 11/1/04 12/1/04 Flow - lFE (CR3) - iFE 0 0 11/1/04 12/1/04 [Flow - IFG (CR3) IFG 0M0178 0.0791 11/1/04 12/1/04 Flow-CD System DOF (CR3) DOF 0 0

                                                                                                                                                   - L 10/21/2009                                                                                Page 14

Crystal River Dear DMR Data Permit No. FL00000159 Begin date End Date Iv< PARAMETER NAME j Outall SC-Ay: C-!lin I CMax- QAvg` Q-Max: NODI-Avg I'NODI-Max NoOi-Min 11/1/04 11/1/04 12/1/04 12/1/04 jFlow-ECST DOF (CR3) Flow-Intake - DOF (CR3) DOF DOF 1 0.00297 15.87 0.0151 20.88 11/1/04 12/1/04 Hydrazine 1-DOF (CR3) 1-DOE NOD1=9 11/1/04 12/1/04 Hydrazine P-DOF (CR3) P-DOF NOD1=9 11/1/04 4 12/1/04 ýHydroquinone 1-DOF (CR3) - 1-DOF NOM=~9 11/1/04 12/1/04 !Hydroquinone P-DOF (CR3) P-DOF NOD1=9 11/1/04 1 12/1/04 lIron Total Recov - DOF (CR3) DOF _ _ _7 NOD1=9 NODI=9 11/1/04 12/1/04 Morpholine 1-DOF (CR3) 1-DOF 36.8 11/1/04 12/1/04 Morpholine P-DOF (CR3) P-DOF NOD 1=9 11/1/04 12/1/04 Number of Batches-IFE (CR3) i tE - 0 0 11/1/04 12/1/04 jOil and Grease - DOF (CR3) DOF NOD1=9 11/1/04 12/1/04 Oil and Grease - CD and ECST DOF (CR3) I DOF 1.89 4.4 11/1/04 12/1/04 !Oil and Grease - IFE (CR3) I lFE NODI=C NODI=C 11/1/04 12/1/04 ýOil and Grease - IFG (CR3) IFG 0.98 2.7 11/1/04 - 12/1/04 pH - Background - DOF (CR3) DOF 7.57 7,96 11/1/04 12/1/04 pH - Calc Limit - DOF (CR3) DOF 6.57 8.5 11/1/04 12/1/04 _pH - Difference - DOF (CR3) __D_.DOE 1.33 -0.41 11/1/04 12/1/04 pH - Effluent - DOF (CR3) DOF 7.9 8.09 11/1/04 12/1/04 pH - IFE (CR3) IFE NODI=C NODI=C 11/1/04 12/1/04 _pH - IFG (CR3) IFG 8.15 8.76 11/1/04 12/1/04 Resid Ox - Time of Discharge D013 (CR3) D013 0 11/1/04 I12/1/04 Spectrus CT1300 - Clamtrol DOF (CR3) DOF NODI=B 11/1/04 12/1/04 ITemp Rise - D013 (CR3) D013 14.2 -i-- 15.5 11/1/04 12/1/04 ýTemp-Discharge - D013 (CR3) D013 86.2 95.7 11/1/04 12/1/04 Temp-Intake - D013 (CR3) D013 72 80.4 11/1/04 12/1/04 iTotal Copper- DOF (CR3) DOF NOD1=9 NOD1=9 11/1/04 12/1/04 ITotal Copper - IFG (CR3) IFG NOD1-9 11/1/04 12/1/04 ITotal Iron- DOF (CR3) DOF NOD,=9 NOD1=9 11/1/04 i NOD,=9

            ,1 12/1/04    ITotal Iron- IFG (CR3)                          IFG 11/1/04 12/1/04    iTotal Residual Ox 1-D013 (CR3)              1-D013                                                       NOD1-9     NODI=9 11/1/04 12/1/04    ýTSS - CD and ECST DOF (CR3)                   DOF                                                        NODI=B     NODI=B 11/1/04 12/1/04    JTSS - Clamtrol - DOF (CR3)                    DOF          55                    69.2 11/1/04 12/1/04    jTSS - DOF (CR3)                               DOE                                                        NODI=9     NODI=9 11/1/04 11/1/04 F   12/1/04    ITSS    - IFE (CR3)                             lE                                                        NODI=C     NODI=C 12/1/04    iTSS - lEG (CR3)                                 EG        19.52                  36.6 10/21/2009                                                                         Page 15

Crystal River D~ear DMVR Data Permit No. FL00000159

                                                                                                         ~.> v -!`i. M In Ci              _A Q     ax               -  - IvjO  IM x   O I

_____End_ 'Begin. datf, .j~~EE

                                  -                  PARAEE              NAMa NAME-'t~
                                                                                            -,'4-

_______ C-Avj __________ _____________ -v ND-OD ax N6iii I D_______-Min________ 11/1/04 12/1/04 Turbidity - DOF (CR3) DOF 30.2 11/1/04 12/1/04 !Turbidity - Effluent DOF (CR3) DO0 26.4 1/1/05 196-Hour Menidia Beryllina P-DOF (CR3) P-DOF NOD1=9 12/1/04 12/1/04 1/1/05 96-Hour Menidia Beryllina Q-DOF (CR3) i Q-DOF NODI=9 12/1/04 1/1/5 96-Hour Mysiopsis Bahia P-DO (CR3) P-DOF NOD1=9 12/1/04 1 1/1/05 i96-Hour Mysilopsis Bahia Q-DOF(CR3) Q-DOF NODI=9 12/1/04_1 1/1/05 Tmonia-1-DOE (CR3) __ 1-DOE - __ _LTT_-_ - - - .NODI=9 12/1/04 1/1/05 Fmow P-DOFE (CR3) FE NODI=9 12/1/04 1/1/015 Copper Total Recov - DOE (CR3) DOF I-- NODI=9 NODI=9 12/1/04 1/1/05 Copper-trol - D013 (CR3) D024 NODI=9 NODI=9 12/1/04 F[ 1/1/05 Flow - lEE (CR3) D0F 0.000045 0.0014 12/1/04 1/1/05 Flow - l (CR3) FG IFG 0.0168 0.077 12/1/04 1/1/05 Flow-CD System DOF(CR3) 1-DOF 0 0 12/1/04L 1/1/05 EIow-ECST DOF (CR3) DOF 0.0024 0.0 15 12/1/04 1/1/05 Floqw-intake - DOF(CR3) DOF 15.71 18.2 12/1/04 1/1/05 }Hydrazine 1-DOF (CR3) 1-DOF NODI=9 12/1/04 1/1/05 Hydrazine P-DO (CR3) F I P-DOF NODI=9 12/1/04[ 1/1/05 MHydroquinone 1-DOF (CR3) 1-DOF JNOD1=9 12/1/04 1/1/05 Hydroquinone P-DOF (CR3) P-DOF I NODI=9 IL-12/1/04 1/1/05 Iron Total Recov - DOFE (CR3) DOFE i NODI=9 NODI=9 12/1/04 1/1/05 Morpholine 1-DOF(CR3) 1-DOF 36.3 12/1/04 1/1/05 Morpholine P-DO (CR3) E P-DOF NODI=9 12/1/04 1/1/05 Number of BatchesIFE - (CR3) IFE 1 I 1 12/1/04 1/1/05 lo0l and Grease - DOF(CR3) DOF NODI=9 12/1/04 1/1/05 land Grease - CD and ECST DOE (CR3) plo DOF 2.65 6.9 12/1/04 1/1/05 i and Grease - DFE (CR3) lFE 0.4 0.4 3.91 12/1/04 1/1/05 Oil and Grease - lFG (CR3) lFG 7.5 12/1/04 1/1/0L5 _ pH - Background - DOE (CR3) DOE . 7.8 8.03 12/1/04 1/1/05 pH - Calc Limit - DOE (CR3) DOE 6.8 8.5 iI 12/1/04 1/1/05 pH - Difference - DOE (CR3) 'l~DOE 0.99 -0.4 I 12/1/04 [ 1/1/05 pH - Effluent - DOF (CR3) DOF 7.79 8.1 ! lFE 6.84 12/1/04 T 1/1/05 pH- FE (CR3) 6.84 12/1/04 1/1/05 _ pH - iFG (CR3) IFG 8.73 i 12/1/04 1/1/05 Resid Ox - Time of Discharge D013 (CR3) D013 0 -- 12/1/04 1/1/05 /Spectrus CT1300 - Clamtrol DOF (CR3) DOF NODI=B 10/21/2009 Page 16

Crystal River tear DMR Data Permit No. FL00000159 EndDate .PAAMETERNAME

1, vutaI ACMin C-Max O-Av -Max NOD-Avg NODI-Max NODI-Min Begi date 12/1/04 1/05 ITemp Rise - D013 (CR3) D013 14.7 16.1 12/1/04 1/1/05 !Temp-Discharge - D013 (CR3) D013 75.3 86.4 12/1/04 1/1/05 iTemp-Intake - D013 (CR3) D013 60.6 71 12/1/04 1/1/05 ITotal Copper - DOF (CR3) DOF N°DI-9 NODI=9 12/1/04 1/1/05 Total Copper - IFG (CR3) IFG NODI=9 12/1/04 1/1/05 ITotal Iron- DOF (CR3) D0F NODI=9 NODI=9 12/1/04 1/1/05 ITotal Iron- IFG (CR3) IFG NODI=9 12/1/04 1/1/05 ITotal Residual Ox 1-D013 (CR3) 1-D013 NODI=9 NODI=9 __ _!

T NODI=B NODI=B 12/1/04 1/1/05 ITSS - CD and ECST DOF (CR3) DOF 12/1/04 1/1/05 [TSS - Clamtrol - DOF (CR3) DOF 46.3 46.3 12/1/04 1/1/05 ITSS- DOF (CR3) DOF . NOD1=9 NODI=9 12/1/04 1/1/05 TSS-IFE (CR3) IFE N0D1=B NODI=B 12/1/04 1/1/05 TSS - IFG (CR3) IFG -_5.03 7.2 12/1/04 1 1/1/05 Turbidity - DOF (CR3) DOF I 19.6 12/1/04 1/1/05 Turbidity - Effluent DOF (CR3) DOF -113.2 1/1/05 2/1/05 96-Hour Menidia Beryllina P-DOF (CR3) P-DOF t NODI=9

                                                                                                                                   !                         NODI=9 1/1/05          2/1/05    96-Hour Menidia Beryllina Q-DOF (CR3)[    Q-DOF 1/1/05      1   2/1/05   196-Hour Mysidopsis Bahia P-DOF (CR3)       P-DOF                                                                                  NODI=9 Q-DOF                   -i                                                              N-DI0=9 1/1/05          2/1/05    96-Hour Mysidopsis Bahia Q-DOF (CR3) 1/1/05          2/1/05    Ammonia 1-DOF (CR3)                     i  1-DOF                                                           NODI=9 1/1/05          2/1/05    Ammonia P-DOF (CR3)                        P-DOF                                                           NODI=9 1/1/05          2/1/05   lCopper Total Recov - DOF (CR3)              DOF                                                            NODI-9   NODI=9 1/1/05          2/1/05   tCopper-trol - D013 (CR3)                    D025                                                           NODI=9   NODI=9 1/1/05          2/1/05    Flow - IFE (CR3)                             IFE                                        0         0 1/1/05          2/1/05    Flow - IFG (CR3)                             IFG                                     0.0189    0,081 1/1/05          2/1/05   iEIow-CD System DOF (CR3)                    DOF                                         0         0 1/1/05          2/1/05    IFow-ECST DOF (CR3)                         DOF                                     0.000972   0.0152 1/1/05          2/1/05    Flow-Intake - DOF (CR3)                     DOF                                       15.58     16.41 1/1/05          2/111O5   Hyd r a zine 1-DOFCR)          -           1-DDE                                                           NODI=9 1/1/05          2/1/05    Hydrazine P-DOF (CR3)                      P-DOF                                                           NO 01=9 1/1/05          2/1/05    Hydroquinone 1-DOF (CR3)                   1-DOF                                                           NODI=9 1/1/05          2/1/05   tHydroquinone P-DOF (CR3)                   P-DOF                                                           NO D1=9 1/1/05          2/1/05    Iron Total Recov - DOF (CR3)                DOF                                                            NODI=9   NODI=9 1/1/05          2/1/05    Morpholine 1-DOF (CR3)                     1-DOF         33.3 1/1/05          2/1/05    Morpholine P-DOF (CR3)                     P-DOF                                                           NODI=9 10/21/2009                                                                       Page 17

Crystal River S ear DMR Data Permit No. FL00000159 Bein date En Date P~ARAMETER NM tal CAg C-Mm> 1 C-Max Q-Avg Q-Ma NODI-Avg NOIDI-',Max NODI-Min 1/1/05 2/1/05 Number of Batches - IFE (CR3) IFE 0 0 1/1/05 2/1/05 !Oil and Grease - DOF (CR3) DOF NODI=9 i 1/1/05 2/1/05 lOil and Grease - CD and ECST DOF (CR3) DOF 0.12 0.5 1/1/05 2/1/05 Oil and Grease - IFE (CR3) IFE NODI=C NODI=C S 5.6 1/1/05 2/1/05 Oil and Grease - IFG (CR3) IFG 2.39 1/1/05 2/1/05 pH - Background - DOF (CR3) 7.81 8.11 1/1/105 2/1/05 -pH_- Caic Limit - DOF (CR3) D)OE 6.81 8.5 1/1/05 2/1/05 .1/1/05 2/1/s5 ]pH - Difference - DOF (CR3) DOF 1.02 -0.38

 /1/05         -21/05    JpH - Effluent - DOF (CR3)                       DOE                    7.83      8.12
 /1105       -  2/1:/05   pH - IFE (CR3)                                    IFE                                                              NODI=C            NODI=C pH  - IFG_(CR3)      .    .        . .. . .      IFG                   8.33      8.95 1/1/05          2/1/05 1/1/05    [     2/1/05    Resid Ox - Time of Discharge D013 (CR3)        D013                                0 1/1/05          2/1/05   ISpectrus CT1300 - Clamtrol DOF (CR3)            DOF                                                                NODI=B
                         !Temp Rise - D013 (CR3)                          D013         14.3                159.

1/1/05 2/1/05 1/1/05 2/1/05 Temp-Discharge - D013 (CR3) D013 75.3 85.3 1/1/05 2/1/05 .[Temp-intake - D013 (CR3) D013 60.9 69.5 .. . .F - .. . . ..- .I Total Copper- DOE (CR3) DOF NODI=9 NODI=9 1/1/05 2/1/05 Total Copper - IFG (CR3) IFG NODI=9 1/1/05 2/1/05 1/1/05 2/1/05 ITotal Iron- DOF (CR3) DOE NODI=9 NOD,=9 1/1/05 V 2/1/05 iTotal Iron- IFG (CR3) IFG NODI=9

                        ]Total   Residual Ox 1-D013 (CR3)               1-D0137                                              NODI=9          NODI=9 1/1/05          2/1/05 TSS- CD and ECST DOF (CR3)                      DOF                                                NODI=B          NODI=B 1/1/05          2/1/05 ITSS - Clamtrol - DOF (CR3)     _-               DOF          56.1                58.7 1/1/05          2/1/05 FTSS- DOF (CR3)                                  DOF                                                NODI=9          NODI=9 1/1/05          2/1/05 1/1/05          2/1/05   ITSS - IFE (CR3)                                  IFE                                               NODI=C          NODI=C 1/1/05      1   2/1/05    TSS - IFG (CR3)                                 IDFG         5.18               10.11 Turbidity  - DOF (CR3)                          DOE                             25.4 1/1/05          2/1/05   ITurbidity - Effluent DOF (CR3)                  DOE                              8.01 2/1/05           3/1/05   196-Hour Menidia Beryllina P-DOF (CR3)       -__P-DOEj_                                                                               NOD1-9 2/1/05           3/1/5     96-Hour Menidia Beryllina Q-DOF (CR3)         Q-DOF                                                                              --  NOD019 2/1/05           3/1/05  Hour Mysidopsis Bahia P-DOF (CR3)            P-DOFE                                                                                NODI=9 2/1/05           3/1/05   196-Hour Mysidopsis Bahia Q-DOF (CR3)          Q-DOF      1                                                                   --      NODI=9 2/1/05           3/1/05  -Ammonia 1-DOF (CR3)                             1-DOF                                             INODI=9 2/1/05           3/1/05    Ammonia P-DOF (CR3)                            P-DOF                                               NODI=9 2/1/05           3/1/05   )Coppe r Total Recov    - DOF (CR3)              DOF      I                                         NODI=9          NOOI=9 10/21/2009                                                                           Page 18

Crystal RiverN#ear DMR Data Permit No. FLOO000159 ~Begin datej i!outall!?:f 'C-Avg* LI C-Min C'Max I- Q-.Avg9 Q-Max. - NONDI-Avg NODI-M ax NODI-Min End Dat PARAMETER- NAME,. 2/1/05 3/1/05 Copper-trol - D013 (CR3) D026 NODI=9 NODI=9 2/1/05 3/1/05 Flow - IFE (CR3) IFE 0 0 2/1/05 3/1/05 Flow - IFG (CR3) IFG 0.0179 0.0791 2/1/05 3/1/o5 iFlow-CD System DOF (CR3) DOE- 0 0 2/1/05 3/1/05 IFlow-ECST DOF (CR3) 0.00268 0.0152 2/1/05 3/1/05 Flow-Intake - DOF (CR3) DOF 15.7 18.65* 2/1/05 3/1/05 Hydrazine I-DOF (CR3) I-DOE NODI=9 2/1/05 3/1/05 Hydrazine P-DOF (CR3) P-DOF NODI=9 2/1/05 3/1/05 Hydroquinone 1-DOF (CR3) 1-DOF i NODI=9 2/1/05 3/1/05 Hydroquinone P-DOF (CR3) P-DOF NODI=9 2/1/05 3/1/05 Iron Total Recov - DOF (CR3) DOF NOD0=9 NOD 1=9 Morpholine 1-DOF (CR3) 1-DOF 29.3 2/1/05 3/1/05 2/1/05 3/1/05 Moirpholine P-DOF (CR3) P-DOF NODI=9 2/1/05 3/1/05 Number of Batches - IFE (CR3) IFE 0 0 1 2/1/05 3/1/05 Oil and Grease - DOF (CR3) DOF NODI=9 2/1/05 3/1/05 Oil and Grease - CD and ECST DOF (CR3) 1.11 4.1 2/1/05 3/1/05 Oil and Grease - IFE (CR3) IFE NODI=C NODI=C 2/1/05 3/1/05 !Oil and Grease - IFG (CR3) IFG 2.41 11.2 8.08 2/1/05 3/1/05 pH - Background - DOF (CR3) DOF 6.83 2/1/05 3/1/05 pH - Calc Limit - DOF (CR3) DOF 6.83 8.5 2/1/05 3/1/05 pH - Difference - DOF (CR3) DOF 1.04 -0.42 2/1/05 3/1/05 pH - Effluent - DOF (CR3) 7.87 8.14 2/1/05 3/1/05 pH-IFE (CR3) IFE NODI=C NODI=C 2/11/05 3/1/05 pH -I FG (CR3) IFG 8.61 8.94 2/1/05 3/1/05 Resid Ox - Time of Discharge D013 (CR3) D013 0 2/1/05 3/1/05 Spectrus CT1300 - Clamtrol DOF (CR3) DOF SNODI=B 2/1/05 3/1/05 Temp Rise - D013 (CR3) D013 13.5 15.1 2/1/05 3/1/05 Temp-Discharge - D013 (CR3) D013 75.3 81.3 2/1/05 3/1/05 iTemp-Intake - D013 (CR3) D013 T 61.8 66.6 2/1/05 3/1/05 Total Copper - DOF (CR3) DOF NODI=9 NODI=9 2/1/05 3/1/05 Total Copper - IFG (CR3) lEG

                                                                                                                          --1-----~~  -

NODI=9 Total Iron- DOF (CR3) 2/1/05 3/1/05 DOF -i rNODI=9 NODI=9 2/1/05 3/1/05 Total Iron- IFG (CR3) IFG INODI=9 2/1/05 3/1/05 Total Residual Ox 1-D013 (CR3) I-DO13 NODI=9 NODI=9 2/1/05 3/1/05 TSS - CD and ECST DOE (CR3) DOFE SNOD..B I NODI=B 10/21/2009 Page 19

Crystal River Dear DMR Data Permit No. FL00000159 .Begin date ~End Date '~ .~,.PARAMETER NAME,< utaIl O~li .. C;C~ C-max, v i Q-Max T NOIAgNOIMxI N,.D -~jl

                                                                                                                                                  -v'ý       N      l-I~~

________________ OIi 2/1/05 3/1/05 TSS - Clamtrol - D0F (CR3) DOF 40.2 47.3 2/1/05 3/1/05 TSS - DOF (CR3) DOF NOD=k9 NODI=9 2/1/05 F 3/1/05 iTSS-IFE (CR3) IFE NODI=C NODI=C 2/1/05 3/1/05 TSS - IFG (CR3) IFG 9.21 23.21 J 2/1/05 3/1/05 Turbidity - DOF (CR3) DO_ _ 15.5 2/1/05 3/1/05 Turbidity - Effluent DOF (CR3) 3.82 PDOE _____________ 3/1/05 4/1/05 96-Hour Menidia Beryllina P-DOF (CR3) -h NODI=9 0-DOE 3/1/05 4/1/05 96-Hour Menidia Beryllina Q-DOF (CR3) NODI=9 3/1/05 4/1/05 96-Hour Mysidopsis Bahia P-DOF (CR3) P-DOE NODI=9 I 3/1/05 4/1/05 196-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOFr lEE { NODI=9 I 3/1/05 4/1/05 Ammonia 1-DOF (CR3) .1-DOEF NODI

                                                                                                                                                   =9 3/1/05         4/1/05       Ammonia P-DOF (CR3)                     P-DOE                                                                  NODI :9 NOII 3/1/05         4/1/05       Copper Total Recov - DOF (CR3)            DOE                                                                  NODI 3/1/05         4/1/05       Copper-trol - D013 (CR3)                 D027                                                                  NODI =9           NODI=9 3/1/05         4/1/05       Flow    - IFE (CR3)                                                                           0         0 lEG 3/1/05         4/1/05       Flow    - IFG (CR3)                                                                        0.012      0.079 3/1/05         4/1/05       Flow-CD System DOF (CR3)                  DOF                                                 0         0 3/1/05         4/1/05       Flow-ECST DOF (CR3)                       DOF                                            u.0         0.0076 3/1/05         4/1/05       Flow-Intake - DOF (CR3)                                                                      17.3  i  20.3 3/1/05         4/1/05       Hydrazine 1-DOF (CR3)                                                                                          NODI
                                                                                                                                                    =9    '

3/1/05 4/1/05 Hydrazine P-DOF (CR3) P-DOF NODI: 3/1/05 4/1/05 Hydroquinone 1-DOF (CR3) 1-DOF NODI=

                                                                                                                                                    --9 I 3/1/05         4/1/05       Hydroquinone P-DOF (CR3)                 P-DOF                                        7-                       NODI==9 3/1/05         4/1/05       Iron Total Recov - DOF (CR3)                                                                                   NODI=
                                                                                                                                                    --9 {
                                                                                                                                                        =9           I=

3/1/05 4/1/05 Morpholine 1-DOF (CR3) 1-DOE I-DFE 19.1 4/1/05 jMorpholine P-DOF (CR3) I =9i NODI=9 3/1/05 P-DOF _ NODI= I-3/1/05 4/1/05 Number of Batches - IFE (CR3) IFE 0 0 3/1/05 4/1/05 Oil and Grease - DOF (CR3) DOF B NODI;9 3/1/05 4/1/05 Oil and Grease - CD and ECST DOF (CR3) DOF NODI= PDOE =C '; NODI=C 3/1/05 4/1/05 Oil and Grease - IFE (CR3) NODI= 3/1/05 4/1/05 Oil and Grease - IFG (CR3) lEG 0.22 0.6 3/1/05 4/1/05 pH - Background - DOF (CR3) DOF 7.81 8 3/1/05 4/1/05 pH - Calc Limit - DOF (CR3) DOF 6.81 I 8.5 3/1/05 4/1/05 PpH - Difference - DOF (CR3) D0F 0.94 -0.34 DOF 7.75 3/1/05 4/1/05 pH - Effluent - DOE (CR3)

                                                                                                 .1L 8.16                        i 10/21/2009                                                                         Page 20

Crystal River Dear DMR Data Permit No. FL00000159 'B~e& date~a~ End'Date'Y > _ _

_~_utall ___ _g _ _ Min

_*_C _ C-M a* K& Q -Avg . Q-M ax. -,1: NODI-Avg - NýaooI-M ax I NODI-M in IFE NODI=C I NODI=C 3/1/05 4/1/05 PHo IFE (CR3) - 3/1/05 4/1/05 pH - IFG (CR3) IFG 8.48 8.78 3/1/05 4/1/05 Resid Ox --Time of Discharge D013 (CR3) D013 0 DOF NODI=B 3/1/05 4/1/05 Spectrus CT1300 - Clamtrol DOF (CR3) 3/1/05 4/1/05 Temp Rise - D013 (CR3) D013 14.5 1- 15.9 3/1/05 4/1/05 Temp-Discharge - D013 (CR3) D013 80.3 88.9 3/1/05 4/1/05 Temp-Intake - D013 (CR3) D013 65.8 73.4 Total Copper - DOF (CR3) DOF NODI=9 NODI=9 3/1/05 4/1/05 Total Copper - IFG (CR3) IFG NODI=9 3/1/05 4/1/05 3/1/05 4/1/05 Total Iron- DOF (CR3) DOF NODI=9 NODI=9 3/1/05 4/1/05 ITotal Iron- lFG (CR3) lFG NODI=9 3/1/05 4/1/05 Total Residual Ox 1-D013 (CR3) 1-D013 NODI=9 NODI=9 3/1/05 4/1/05 TSS - CD and ECST DOE (CR3) DOE NODI=B NODI=B 3/1/05 4/1/05 ITSS - Clamtrol - DOF (CR3) DOF 53.2 70.7 3/1/05 4/1/05 TSS - DOF (CR3) DOF NODI=9 NODI=9 3/1/05 4/1/05 TSS -IFE (CR3) 1 IFE NODI=C NODI=C 3/1/05 4/1/05 ITSS - lEG (CR3) IFG 6.82 10.62 3/1/05 4/1/05 ITurbidity - DOF (CR3) DOF 21.9 3/1/05 4/1/05 ITurbidity - Effluent DOF (CR3) DOF - 14 _____-v 4/1/05 5/1/05 96-Hour Menidia Beryllina P-DOF (CR3) P-DOF NODI=9 4/1/05 5/1/05 96-Hour Menidia Beryllina Q-DOF (CR3) Q-DOF NODI=9 P-DOE 4/1/05 5/1/05 96-Hour Mysidopsis Bahia P-DOF (CR3) NODI=9 4/1/05 5/1/05 96-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NODI=9 4/1/05 5/1/05 Ammonia 1-DOF (CR3) I-DOF NODI=9 4/1/05 5/1/05 Ammonia P-DOF (CR3) P-DOE NODI=9 4/1/05 5/1/05 Copper Total Recov - DOF (CR3) I DOE NODI=9 NCIDlz9 4/1/05 5/1/05 jCopper-trol - D013 (CR3) D028 NODI=9 NODI=9 4/1/05 5/1/05 Flow - IFE (CR3) IFE 0.000048 0.00144 4/1/05 5/1/05 Flow- lFG (CR3) lEG 0.022 0.079 D0F 4/1/05 5/1/05 Flow-CD System DOF (CR3) - DOF 0 0 4/1/05 5/1/05 Flow-ECST DOF (CR3) -_ DOF 0.00202 0.0 151 4/1/05 5/1/05 jFlow-lntake - DOF (CR3) DOE 15.58 17.53 4/1/05 5/1/05 Hydrazine 1-DOF (CR3) 1-DOF ! NODI=9 N. 4/1/05 5/1/05 Hydrazine P-DOF (CR3) P-DOF NODI=9 5/1/05 lHydroquinone 1-DOF (CR3) NODI=9 4/1/05 1-DOF 10/21/2009 Page 21

0 Crystal River sear DM R Data [BegindateY Enid Date <P 4ARAMETERJ4AME i < iOUta 11 NODI=9 4/1/05 5/1/05 Hydroquinone P-DOF (CR3) I P-DOF NODI=9 NODI=9 4/1/05 5/1/05 Iron Total Recov - DOF (CR3) DOF 4/1/05 5/1/05 Morpholine 1-DOF (CR3) 1-DOF 27,5-F I N i 4/1/05 5/1/05 Morpholine P-DOF (CR3) P-DOF i : INUUI=9

                                                                                                                                        ,   1 4/1/05           5/1/05      Number of Batches - IFE (CR3)                   IFE i

I_ I NODI=9 4/1/05 5/1/05 Oil and Grease - DOF (CR3) j DOF I i DOF 0.53 2.5 4/1/05 5/1/05 Oil and Grease - CD and ECST DOF (CR3) INODI=B ] NODI=B 4/1/05 5/1/05 Oil and Grease - IFE (CR3) IFE IFG 1.2 i 8.4 4/1/05 5/1/05 Oil and Grease - IFG (CR3) [ 4/1/05 5/1/05 pH - Background - DOF (CR3) DOF I I 2.7 8.12 4/1/05 5/1/05 pH - Calc Limit - DOF (CR3) DOF 6.7 8.5 I 11 4/1/05 5/1/05 pH - Difference - DOF (CR3) DOE L 7.8 4/1/05 5/1/05 pH - Effluent - DOF (CR3) lEF I / 8.2 IFE 6.74 6.74 4/1/05 5/1/05 pH - IFE (CR3) IFG 8.47 8.87 4/1/05 5/1/05 pH - IFG (CR3) 4/1/05 5/1/05 Resid Ox -Time of Discharge D013 (CR3) 0013 0 5/1/05 Spectrus CT1300 - Clamtrol DOF (CR3) _DO1 ___ NODI=BI 4/1/05 4/1/05 5/1/05 Temp Rise - D013 (CR3) D013 13.8 14.9 4/1/05 5/1/05 Temp-Discharge - D013 (CR3) D013 85.3 91.1 - 4/1/05 5/1/05 Temp-Intake - D013 (CR3) D013 71.5 75.3 4/1/05 5/1/05 Total Copper - DOF (CR3) DOF INODI=9 NODI=9 4/1/05 5/1/05 Total Copper - IFG (CR3) IFG NODI=9 INODI=9 NODI=9 4/1/05 5/1/05 Total Iron- DOF (CR3) DOE _ NODI-9 4/1/05 5/1/05 Total Iron- IFG (CR3) lFG - Total Residual Ox 1-D013 (CR3) I1-DO13 NODI=9 NODI=9 4/1/05 5/1/05 5/1/05 TSS - CD and ECST DOF (CR3) NODI=B NODI=B 4/1/05 4/1/05 5/1/05 TSS - Clamtrol - DOF (CR3) DOE r 61.9 _ ~~72.7 - 5/1/05 TSS - DOF (CR3) DOF NODI=9 NODI=9 4/1/05 - TSS - IFE (CR3) IFE 7.5 7.5 4/1/05 5/1/05 4/1/05 5/1/05 TSS - IFG (CR3) IFG 8.9 --- 13.9 - - 4/1/05 5/1/05 Turbidity - DOF (CR3) DOF 7 ________24.2-- 4/1/05 5/1/05 Turbidity - Effluent DOF (CR3) DOF

                                                                                                     -6.9 P-DOF                                                                                         NO0   =9 5/1/05          6/1/05      96-Hour Menidia Beryllina P-DOF (CR3) 5/1/05          6/1/05      96-Hour Menidia Beryllina Q-DOF (CR3)  [     Q-DOF P-DOF N

NODI=9 NODI=9 5/1/05 6/1/05 196-Hour Mysidopsis Bahia P-DOF (CR3) 10/21/2009 Page 22

Crystal River Dear DMR Data Permit No. FL00000159 KBegin date EdDate~ ýPARAMETEIR NAME ; b ufaiLI -v 1;jj7C-Mn C-Max-, -Av Ql-Max NODI-Avg" NDMaXý I-i 4 6/1/05 196-Hour Mysidopsis Bahia Q-DOF (CR3) 0Q-DOF NINODI=9 5/1/05 5/1/05 6/1/05 Ammonia 1-DOF (CR3) 1-DOF Ammonia P-DOF (CR3) P-DOF NODI=9 - 5/1/05 6/1/05 DOF NODI=9 NODI=9 5/1/05 6/1/05 Copper Total Recov - DOF (CR3) 6/1/05 Copper-trol - D013 (CR3) D029 N D NODI=9 N00D=9 5/1/05 5/1/05 6/1/05 Flow - IEE (CR3) IFE ___ 0 0 5/1/05 6/1/05 Elow - lFG (CR3) IFG _______ _____0.0155_ 0.07596 5/1/05 6/1/05 [Flow-CD System DOF (CR3) DOE 0

                                                                   -J 5/1/05           6/1/05   Flow-ECST DOF (CR3)                             DOF                                                                               0.015 1 0.01 5/1/05           6/1/05   Flow-intake - DOF (CR3)                         DOF                                                                                   20 5/1/05           6/1/05 lHydrazine 1-DOF (CR3)                          1-DOF                                                                                         NODI=9 5/1/05           6/1/05 lHydrazine P-DOF (CR3)                          P-DOF                                                                                         NODI=9 5/1/05           6/1/05 iHydroquinone 1-DOF (CR3)                       1-DOF                                                                                         NODI=9 5/1/05           6/1/05   Hydroquinone P-DOF (CR3)                      P-DOF                                                                                         NODI=9
                                                                                                                                                         .f.

5/1/05 6/1/05 Iron Total Recov - DOE (CR3) DOF NOD1=9 NODI=9 I 5/1/05 6/1/05 Morpholine*1-DOF (CR3) 1-DOF 23.9 - I i NODI=9 i 5/1/05 6/1/05 lMorpholine P-DOF (CR3) P-DOF I IFE 0 o 5/1/05 6/1/05 Number of Batches - IFE (CR3) 0-5/1/05 6/1/05 Oil and Grease - DOF (CR3) DOF NODI=9 6/1/05 'Oil and Grease - CD and ECST DOF (CR3) DOE 0.52 5/1/05 1 5/1/05 6/1/05 Oil and Grease - IFE (CR3) IFE NODI=C NODI=C 6/1/05 Oil and Grease - IFG (CR3) IFG 70.6- 6.4 _ 5/1/05 T 5/1/05 6/1/05 pH - Background - DOF (CR3) DOF 7.75 8.2 5/1/05 6/1/05 pH - Calc Limit - DOF (CR3) DOF 6.75 8.5 5/1/05 6/1/05 pH - Difference - DOF (CR3) DOF 1.22 -0.37

                                                                                                                                                                                          -i ... .  .   . . .

5/1/05 6/1/05 pH - Effluent - DOF (CR3) DOF 7.97 8.13 I OO= 5/1/05 6/1/05 pH - IFE (CR3) _ _IFE I NODI=C 5/1/05 6/1/05 pH - IFG (CR3) IFG { 8.43 8.79 I 5/1/05 6/1/05 Resid Ox - Time of Discharge D013 (CR3) D013 I. - 5/1/05 6/1/05 Spectrus CT1300 - Clamtrol DOF (CR3) DOF NODI=B 5/1/05 6/1/05 Temp Rise - D013 (CR3) D013 11.6 13.5 _ 5/1/05 6/1/05 iTemp-Discharge - D013 (CR3) D013 91 95.5

                                                                                                              .......... ...... .5-.s--

85-.... 5/1/05 6/1/05 Temp-Intake - D013_(CR3) D013 79.4 .. 5.. .

                                                                                                                               . 85-i        .   . .

5/1/05 6/1/05 -Total Copper - DOF (CR3) DOF NODI=9 NODI=9 5/1/05 6/1/05 ITotal Copper - IFG (CR3) IFG NODI=9 10/21/2009 Page 23

Crystal River ear DMR Data Permit No. FL00000159 SBegin aate- End Da*e " .Mvg NOM N6'M'n NODPARAMETERN ITotal Iron- DOF (CR3) DOE NODI=9 NODI=9 5/1/05 6/1/05 5/1/05 5/1/05 6/1/05 6/1/05 iTotal Iron- IFG (CR3) ITotal Residual Ox 1-D013 (CR3) I 1oo1__I--__ l-D0F13 NODI=9 NODI=9 NOD =9 ITSS - CD and ECST DOF (CR3) _DOE] NODI=B NODI=B 5/1/05 6/1/05 5/1/05 6/1/05 TSS - Clamtrol - DOF (CR3) DOF 46.5 48.6 NODI=9 NODI=9 5/1/05 6/1/05 TSS - DOF (CR3) DOF I 5/1/05 6/1/05 TSS-IFE (CR3) IFEE .NODI=C NODI=C IFG 7.59 11. 86 5/1/05 6/1/05 ]TSS - IFG (CR3) 5/1/05 6/1/05 Turbidity - DOF (CR3) DOF 14 .5 9.555 5/1/05 6/1/05 Turbidity - Effluent DOF (CR3) DOF 196-Hour Menidia Beryllina P-DOF (CR3) P-DOF NODI=9 6/1/05 7/1/05 - . . . . . . .. . . 7/1/05 196-Hour Menidia Beryllina Q-DOF (CR3) Q-DOF N .. .=9 6/1/05 6/1/05 7/1/05 196-Hour Mysidopsis Bahia P-DOF (CR3) P-DOF NODI=9 6/1/05 7/1/05 196-Hour Mysidopsis Bahia Q-DOF (CR3) Q-DOF NODI=9 6/1/05 7/1/05 ýAmmonia 1-DOF (CR3) 1-DOF NODI=9 6/1/05 6/1/05 7/1/05 Ammonia P-DOF (CR3) P-DOF I Ii NODI=9 6/1/05 7/1/05 Copper Total Recov - DOF (CR3) DOF NODI=9 NODI=9 6/1/05 7/1/05 iCopper-trol - D013 (CR3) D030 NODI=9 NODI=9 7/1/0S Flow - IFE (CR3) IFE 0 01 6/1/05 6/1/OS 7/1/05 Flow - IFG (CR3) IFG 0.01 7 I 0.076 7/1/05 Flow-CD System DOF (CR3) 1 DOF 0 !1 0 3 6/1/05 7/1/05 jFIow-ECST DOF (CR3) DOF 0.003 6 0.016 6/1/05 7/1/05 Flow-Intake - DOF (CR3) DOF 15.9 7 18.1 6/1/05 7/1/05 lHydrazine 1-DOF (CR3) 1-DOF N001=9 6/1/05 7/1/05 Hydrazine P-DOE (CR3) P-DOF NODI=9 6/1/05 7/1/05 jHydroquinone 1-DOF (CR3) 1-DOF NO0I=9 6/1/05 7/1/05 !Hydroquinone P-DOF (CR3) P-DOF NODI=9 6/1/05 7/1/05 iron Total Recov - DOF (CR3) DOE ..... i_ NODI=9 NODI=9 6/1/05 7/1/05 IMorpholine 1-DOF (CR3) 1-DOE 22.2 1Morpholine P-DOF (CR3) _T 6/1/05 7/1/05 P-DOE NOD;9 1 i 6/1/05 7/1/05 !Number of Batches - IFE (CR3) IFE 0 0

                                                                                                        ~1 6/1/05           7/1/05   !Oil and Grease - DOF_(CR3)__                  DOE                                                                                       NODI=9

_1 D0_F 6/1/05 7/1/05 jOil and Grease - CD and ECST DOF (CR3) 0.45 2 6/1/05 1 7/1/05 1Oil and Grease - IFE (CR3) IFE NODI=C NODI=C 6/1/05 7/1/05 Oil and Grease - IFG (CR3) IFG 0.71 2.1 10/21/2009 Page 24

Crystal River NMear DMR Data Permit No. FL00000O159 P4lW E AEO~utaIIll CM, in_____

                                                                                                                                                                ,.C-I'Max: yQ-Avg'-V     Q-Max-    NODI-I~Avg, NOI'-MNl~Wax NODI-Min' Begin date            End Date~                                                                                       C-yi

__________ M.AAEE 6/1/05 7/1/05 JpH - Background- DOF (CR3) DOF 8 8.24 6/1/05 7/1/05 IpH - Calc Limit - DOF (CR3) DOF 7 8.5 6/1/05 7/1/05 pH - Difference - DOF (CR3) DOF 0.99 -0.32 6/1/05 7/1/05 pH - Effluent - DOF (CR3) DOF j 7.99 8.28 6/1/05 71/05 JpH-IFE (CR3) IFE _ -F NODI=C NODI=C 6/1/05 7/1/05 pH - lFG (CR3) lEG 8.43 8.94 1 6/1/05 7/1/05 Resid Ox - Time of Discharge D013 (CR3) D013 6/1/05 7/1/05 ISpectrus CT1300 - Clamtrol DOF (CR3) DDE __ NODI=B 6/1/05 7/1/05 iTemp Rise - D013 (CR3) T D013 - 8.6 11.9 6/1/05 7/1/05 ITemp-Discharge - D013 (CR3) 0013 93.3 95.6 6/1/05 7/1/05 Temp-Intake - D013 (CR3) D013 I 84.7 89.6 6/1/05 7/1/05 !Total Copper - DOF (CR3) - DOF NODI=9 NODI=9 6/1/05 7/1/05 Total Copper - IFG (CR3) _ IFG NODI=9 6/1/05 7/1/05 Total Iron- DOF (CR3) DOF NO 01=9 NODI=9 6/1/05 7/1/05 Total Iron- IFG (CR3) IFG NODI=9 6/1/05 7/1/05 Total Residual Ox 1-D013 (CR3) 1-DO13 NODI=9 DOF ! NODI=B NJODI=B 6/1/05 7/1/05 TSS - CD and ECST DOF (CR3) _ 6/1/05 7/1/05 ITSS - Clamtrol - DOF (CR3) DDF 45.7 72 6/1/05 7/1/05 ITSS - DOF (CR3) 1 DOE NODI=9 NJODI=9 6/1/05 7/1/05 TSS-IEE(CR3) IFE J NODI=C JODI=C 11 6/1/05 7/1/05 TSS - IFG (CR3) _ _IFG -- 7-6/1/05 7/1/05 Turbidity - DOE (CR3) DOF 24 6/1/05 7/1/05 ]Turbidity - Effluent D0F (CR3) DOF 10.2 7/1/05 7/31/05 196-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OEF 100

                                                                                                                                                                                                -i 7/1/05                7/31/05               ý96-Hour Menidia Beryllina Q-D-ODF (CR3)        Q-D-OOF                                                                                                                         NODI=9 7/1/05                7/31/05                96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2i     P-D-OOF                                          100 7/1/05                7/31/05                96-Hour Mysidopsis Bahia Q-D-O0F (CR3)         Q-D-00F                           -                                                                                             NODI=9 1-731/0.5F.ow.-.-.-......                           Q.                                          .       -   . .    .            .   .  ...

7/1/05 7/1/05 7/31/05 Flow - I-OFE (CR3) v2 J I-OFD 0.00009 0.0014 7/1/05 7/31/O 5 Flw I-FCR )v l*OFG -*. . .. .. ..... - ....... .... 0.02 0.08 7/1/05 05 Flow-CD System D-DOF (CR3) v2 0D-OF 0 0 7/1/05 7/31/05 - Flow-ECST D-DDF (CR3) v2 . D-DF - I 0.0032 7/1/05 7/31/05 Flow-lntake- D-00F (CR3) Q D-0F. 15.7 i 18.8 7/1/05 8/1/05 Hydrazine 1-D-OOF (CR3) v2 1-D-OEF NODI=9 7/1/05 8/1/05 Hydrazine P-D-00F (CR3) v2 P-D-O0F . . NODI=9 7/1/05 8/1/05 lHydroquinone 1-D-DDE (CR3) v2 1-D-DFE NOD ,-9 10/21/2009 Page 25

Crystal River sear DMR Data Permit No. FL00000159 End Date PARAMIETER NAMVEeOtl I NODI-Max 140DI-Min Begin date, C-Ayg C-Min -Max . - Q-Max , NODI-Avg 7/1/05 8/1/05 lHydroquinone P-D-OOF(CR3) v2 P-D-OOF NODI=9 7/1/05 8/1/05 Morpholine 1-D-OOF (CR3)v2 1-D-OOF 18.6 NODI=9 7/1/05 8/1/05 IMorpholine P-D-OOF (CR3) v2 P-D-OOF 7/1/05 7/31/05 Number of Batches - -OFE (CR3) v2 -OFE 7/1/05 7/31/05 Oil and Grease - D-OOF (CR3) v2 D-OOF NC)D1=9 7/1/05 7/31/05 Oil and Grease - I-OFE (CR3) v2 I-OFE 1.32 2.6 7/1/05 7/31/05 Oil and Grease - I-OFG (CR3)v2 v I-OFG 0.77 2.7 7/1/05 7/31/05 pH - Background - D-OOF (CR3) v2 D-OOF 7.87 8.26 7/1/05 7/31/05 pH - CaIc Limit - D-OOF (CR3) v2 D-OOF 6.87 8.5 7/1/05 7/31/05 pH - Difference - D-OOF (CR3) v2 D-OOF 1.14 -0.34 7/1/05 7/31/05 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.01 8.31 7/1/05 7/31/05 'pH - I-OFE (CR3) v2 I-OFE 7.01 7.35 7/1/05 7/31/05 pH - I-OFG (CR3) v2 i-OFG 8.61 8.99 7/1/05 7/31/05 Residual Ox - Time of Discharge D013 (CR3) D013 0 7/1/05 8/1/05 ýSpectrus CT1300 - D-OOF (CR3) v2 D-OOF 2.3 7/1/05 8/1/05 Spectrus CT1300 - DOOF (CR3) v2 -- DOOF 2.3 7/1/05 8/1/05 ]Spectrus CT1300 - DOOF (CR3) v2a DOOF 1.5 7/1/05 7/31/05 - Temp Rise- D013 (CR3) v2 D013 - 7.2 10.4 7/1/05 7/31/05_ ITemp-Discharge - D013 (CR3) v2 D013 94.3 96 7/1/05 7/31/05 ITemp-Intake - D013 (CR3) v2 D013 87.1 90.4 7/1/05

 -,111O5          8/1/05     [Total Ammonia 1-D-OOF (CR3) v2                     1-D-OOF                                                          NODI=9 7/1/05~          8/1/05     !Total Ammonia P-D-OOF (CR3) 2                     P-D-OOF                                                           NODI=9 7/1/05           8/1/05     ITotal Copper - DOOF (CR3) v2                        DOOF                                                            NODI=9      NODI=9 7/1/05          7/31/05     iTotal Copper      - i-OFG (CR3) v2                   I-OFG                                                                      NODI=9 7/1/0            8/1/05      Total Iron- D-OOF (CR3) v2                          D-00F      .                    -v                              NODI=9  J   NODI=9 7/1/05          7/31/05      Total Iron- I-OFG (CR3) v2                           I-OFG                                                                      NODI=9 7/1/05           8/1/05     ITotal Recoverable Copper - D-OOF (CR3) v2           D-OOF                                                           NODI=9      NODI=9 7/1/05           8/1/05    ITotal      Recoverable Iron - D-OOF (CR3) v2         D-OOF    -

__ I NODI=9 NOD 1=9 7/1/05 7/31/05 ITotal Residual Ox 1-DO13 (CR3) v2 - 1-DO13 NO 01=9 NOD 1=9

                                                                                                                                      -r 7/1/05           8/1/05     ITSS   -  CD and ECST D-OOF (CR3) v2                 D-OOF                                                           NODI=9      NODI=9 7/1/05          7/31/05     ITSS   - I-OFE  (CR3)v2                               I-OFE         2.7                      5.4     .

7/31/05 ITSS I-OFG (CR3)v2 I-OFG 1~'~ 14.6 I 7/1/05 - 7.2 7/1/05 8/1/05 ITSS P-D-OOF (CR3) v2 P-D-OOF1 NODI=9

                                                                                                                 -.1-                             NODI=9 7/1/05           8/1/05     ITSS Q-D-OOF (CR3) 2                               Q-D-OOF                                                                       NODI=9
 //.L/U      I    8/1/05     ITurbidity - Background - D-OOF (CR3) v2             D-OOF                                                                       NODI=9 10/21/2009                                                                                   Page 26

Crystal River # ar DMR Data Permit No. FL00000159 [Begin date End Date

                        ---;*                   PARAMETER NAME                  OUtall            vg       C-Mi      C-M   Q-Avg , Q-Max    NODI-Avg    NODI-Max NODI,   1i 7/1/05          8/1/05         Turbidity - Calc Limit - D-OOF (CR3) v2       0-DOE                                                                    NODI=9 I        i NOOI=9 7/1/05          8/1/05         Turbidity  - Difference D-O0F (CR3) v2    -   D-00F 0-00 F                                                                   NODI=9 7/1/05          8/1/05         Turbidity - Effluent D-O0F (CR3) v2
                                                                                -D-OOE 7/31/05         8/31/05        ý96-Hour Menidia Beryllina P-D-OOF (CR3)       D-0-OOF                                                                  NNOD         1=

7/31/05 8/31/05 96-Hour Menidia Beryllina Q-D-OOF (CR3) NODI=9 7/31/05 8/31/05 96-Hour Mysicopsis Bahi~a P-D-OOF-(CR3) v2 P-D-OFD NOD1=9 1 7/31/05 8/31/05 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF 7/31/05 8/31/05 Flow - I-OFE (CR3) v2 I-OFE 0 0 I-OFG I 7/31/05 8/31/05 Flow - I-OFG (CR3)v2 0.02 7/31/05 8/31/05 Flow-CD System D-OOF (CR3) v2 D-OOF 0 0 7/31/05 8/31/05 Flow-ECST D-OOF (CR3) v2 D-OOF 0.003 0.015 7/31/05 8/31/05 Flow-Intake - D-OOF (CR3) v2 D-OOF 15.68 18.38 7/31/05__ 8/31/05 Number of Batches - I-DFE (CR3) v2 I-0FE 0 0 7/31/05 8/31/05 ýOil and Grease - D-OOF (CR3) v2 D-00 F NODI=9 7/31/05 8/31/05 Oil and Grease OFE (CR3) v2 I-OFE NODI=C NODI=C

                                                                              -- I-0FG -- '

7/31105 / o oand Grease-,-o-FCG -(CvR )..v2.. ... 0.86 2.7 D-OOF l 7/31/05 1 8/31/05 pH - Background - D-OOF (CR3) v2 7.85 8.31 7/31/05 8/31/05 pH - Caic Limit - D-O0F (CR3) v2 6.85 8.5 7/31/05 8/31/05 pH - Difference OE (CR3)_Q D-00F 1.16 -0.22 D-OOF 7/31/05 8/31/05 pH - Effluent - D-OOF (CR3) v2 8.01 8.38 7/31/05 T-8/31/05 pH - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 7i 7/31/05 8/31/05 pH - I-OFG (CR3) v2 I-OFG 8.05 8.85 7/31/05 8/31/05 Residual Ox - Time of Discharge D013 (CR3) D013 0 7/31/05 8/31/05 Temp Rise - D013 (CR3) v2 D013 6.6 9.7 7/31/05 8/31/05 ITemp-Discharge - D013 (CR3) v2 D013 94.6 96.1 7/31/05 8/31/05 !Temp-lntake - D013 (CR3) v2 D013 88 90.8 7/31/05 8/31/05 'Total Copper - I-OFG (CR3) v2 I-OFG 7/31/05 8/31/05 Total Iron- I-OFG (CR3) v2 I-OFG NOD 1=9 7/31/05 8/31/05 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 NODI=9 7/31/05 8/31/05 FTSS - I-OFE (CR3) v2 I-DFE NODI=C NODI=C 7/31/05 8/31/05 TSS - I-OFG (CR3) v2 I-OFG 3.1 10.3 8/1/05 9/1/0 Hydrazine 1-D-OOF (CR3) v2 1-D-DOF j NOD1=9 8/1/05 9/1/05 Hydrazine P-D-OOF (CR3) v2 P-D-OOF NODN=9 8/1/05 9/1/05 Hydroquinone 1-D-DOF (CR3) v2 1-D-OOF NODI=9 - 8/1/05 9/1/05 ýHydroquinone P-D-O00 (CR3)v2 NODI=9 10/21/2009 Page 27

Crystal River 9 ear DMR Data Permit No. FL00000159

Beginclate,. .... End'at

_________________ I-Av I -Outall/}C-v _____g __ _ ~C:Mn~-'-a&

                                                                                                                 -Min~9  C-Max QAg          QMxx Q__ M' ND-v NOD-Ag      N.

OIMxIND-i D- Ma_-Min NODI 8/1/05 9/1/05 I Morpholine 1-D-OOF (CR3) v2 1-D-OOF 15.8 8/1/05 9/1/05 [Morpholine P-D-OOF (CR3) v2 P-D-OOF 8/1/05 9/1/05 [Spectrus CT1300- DOOF (CR3) v2 DOOF V 15.8 2.25 NOD1=9 8/1/05 9/1/05 ]Total Ammonia 1-D-OOF (CR3) v2 1-D-0OF NODI=9 8/1/05 9/1/05 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF NOD1=9 - 8/1/05 9/1/05 ITotal Copper - DOOF (CR3) v2 DOOF NODI=9 i NODI=9 ________ " ______

NODI=9 NODI=9 8/1/05 9/1/05 ITotal Iron- D-OOF (CR3) v2 D-OOF 8/1/05 9/1/05 ITotal Recoverable Copper - D-O0F (CR3) v2 D-OOF
NODI=9 NODI=9 8/1/05 9/1/05 ýTotal Recoverable Iron - D-OOF (CR3) v2 D-OOF NODI=B NODI=9 8/1/05 9/1/05 ITSS - CD and ECST D-O0F (CR3) v2 D-OOF NODI=9 NODI=B I ITSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 8/1/05 9/1/05 NODI=9 8/1/05 9/1/05 ITSS Q-D-OOF (CR3) v2 Q-D-OOF NOD1=9 8/1/05 9/1/05 Turbidity - Background - D-OOF (CR3) v2 D-OOF NODI=9 8/1/05 9/1/05 ITurbidity - Calc Limit - D-OOF (CR3) v2 D-OOF NODI=9 8/1/05 9/1/05 Turbidity - Difference D-00F (CR3) v2 D-OOF NODI=9 8/1/05 9/1/05 ITurbidity - Effluent D-O0F (CR3) v2 D-0OF NOD 1=9 8/31/05 10/1/05 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >10 (Y/.

8/31/05 10/1/05 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NNOI=9 8/31/05 10/1/05 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF >10 (Y/. 8/31/05 10/1/05 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 8/31/05 10/1/05 Flow - I-OFE (CR3) v2 I-OFE 0 8/31/05 10/1/05 Flow - I-OFG (CR3) v2 I-OFG 0.024 0.075 8/31/05 10/1/05 IFlow-CD System D-OOF (CR3) v2 D-OOF 0 8/31/05 10/1/05 Flow-ECST D-O0F (CR3) v2 D-OOF 70.004 0.015 10/1/05 Flow-Intake - D-OOF (CR3) v2 D-OOF 17.5 24.57 8/31/05 8/31/05 10/1/05 Number of Batches - I-OFE (CR3) v2 I-OFE 0 0 8/31/05 10/1/05 Oil and Grease - D-OOF (CR3) v2 D-OOF NOD1=9 8/31/05 10/1/05 Oil and Grease - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 8/31/05 10/1/05 7Oil and Grease - I-OFG (CR3) v2 I-OFG 1.43 4.9 8/31/05 10/1/05 pH - Background - D-O0F (CR3) v2 D-OOF 7.74 8.25 I 8/31/05 10/1/05 pH - Calc Limit - D-ODF (CR3) v2 D-OOF 8.5 8/31/05 10/1/05 IpH - Difference - D-O0F (CR3) v2 D-OOF 0.93 -0.28 8/31/05 10/1/05 pH - Effluent - D-OOF (CR3) v2 I D-0OF 7.78 8.22 - . .. 8/31/05 8/31/05 10/1/05 10/1/05 pH - I-OFE (CR3) v2 I-OFE NODI=C NODI=C pH - I-0FG (CR3) v2 I-0FG 8.64 8.96 r .L 10/21/2009 Page 28

Crystal River Dear DMR Data

                                                                                          *Permit v,    No. FL00000159

.Begin dateJ End DateY K- .PARAMETERNAME ~ 'utall;$ C-Avg. . C-M.n LwaX Q-AV, Q.!,A' Q,-Max, "NOD1-Avg -.NODI-Max NODI-M in 8/31/05 10/1/05 Residual Ox - Time of Discharge D013 (CR3) D013 0 I1 8/31/05 10/1/05 ITemp Rise - D013 (CR3) v2 D013 9.5 12.5 8/31/05 10/1/05 iTemp-Discharge - D013 (CR3) v2 D013 93 _ 95.6 8/31/05 10/1/05 - Temp-Intake - D013 (CR3) v2 D013 83.6 [ _ 86.2 I-0FG NODI=9 8/31/05 - 10/1/05 ITotal Copper-I-0FG (CR3)v2 i-OFG NODI=9 8/31/05 10/1/05 - !Total Iron- ,-OFG (CR3) v2 8/31/05 10/1/05 iTotal Residual Ox 1-D013 (CR3) v2 1-D013 NOD,=9 NODI=9 8/31/05 - 10/1/05 TSS - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 8/31/05 10/1/05 TSS-I-OFG (CR3)v2 I-OFG 2.6 8.5 9/1/05 10/1/05 iHydrazine 1-D-OOF (CR3) v2 1-D-0OF NODI=9 9/1/05 10/1/05 __ Hydrazine P-D-OOF (CR3) v2 P-D-0OF NODI=9 9/1/05 10/1/05 [Hydroquinone 1-D-OOF (CR3) v2 1-D-OF NODI=9 9/1/05 10/1/05 Hydroquinone P-D-00F (CR3)v2 P-D-OOF NODI=9 9/1/05 10/1/05 Morpholine I-D-OOF (CR3) v2 1-D-0OF 15.9 9/1/05 f 10/1/05 1Morpholine P-D-OOF (CR3) v2 Q P-D-OOF 'JODI=9 9/1/05 1 10/1/05 -Spectrus CT1300 - DOOF (CR3) v2 DOOF _ _ I_ 2.3 9/1/05 [ 10/1/05 Total Ammonia 1-D-OOF (CR3) v2 1-0-OEF ________________1 4ODl=9 9/1/05 10/1/05 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF QODI=9 9/1/05 10/1/05 ITotal Copper - DOOF (CR3) v2 DOOF NODI=9

                                                                                                                                                                            ~ODI=9 9/1/05       L 10/1/05          Total Iron- D-OOF (CR3) v2                      D-00F                                                                                                 NOOI=9 9/1/05           10/1/05        Total Recoverable Copper - D-OOF (CR3) v2F      D-OOF                                                                                     ~ODI=9      NODI=9 9/1/05       1   10/1/05       ITotal Recoverable iron    - D-0OF (CR3) v2      D-OOF                                                                                      ODuI=93    NODI=9 9/1/05       1   10/1/05       ITSS - CD and ECST D-OOF (CR3) v2                D-0OF                                                                    ~~-1             ~ODI=B      NODI=B 9/1/05           10/1/05       ITssP-D-OOF    (CR3)V2                          P-D-OOF                                                                                     JODI=9     NODI=9 9/1/05       1   10/1/05        TSS Q-D-OOF (CR3) v2                        IQ-D-OOF                                                                                       JODI=9     NODI=9 9/1/05           10/1/05        Turbidity - Background - D-OOF (CR3) v2         D-OOF                                                                                                 NODI=9

______________ I 9/1/05 10/1/05 Turbidity - Calc Limit - D-O0F (CR3) v2 D-OOF *1 NODI=9 9/1/05 10/1/05 Turbidity - Difference D-OOF (CR3) v2 D-OOF NODI=9 9/1/05 10/1/05 Turbidity - Effluent D-OF (CR3) v2 D-OOF NODI=9 10/1/05 11/1/05 196-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF NOD1=9 10/1/05 11/1/05 196-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NO 01=9 10/1/05 11/1/05 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF - -I-... NODI=9 10/1/05 F 11/1/05 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 10/1/05 11/1/05 Flow - I-OFE (CR3) v2 I-OFE i 0.0005 0 .00 15 10/1/05 11/1105 IFlow - -OFG (CR3)v2 I-OFG

                                                                                                             -I---._______________

0.021 I 0.079 10/21/2009 Page 29

0 Crystal River s ear DMR Data Permit No. FL00000159

                                                                                         ~OutII~C-in
                                                                                               .- C-Ag    -Ma.   $.-Av~      QMax  NODI-Avg:  NO0DI-Max%,- NODI-Mi' 10/1/05        11/1/05    Flow-CD System D-OOF (CR3) v2                D-00F                                          0.12     0.38 10/1/05        11/1/05  !FIow-ECST D-OOF (CR3) v2                      D-00F                                         U. UU-J  0.015 10/1/05        11/1/05    Flow-Intake - D-00F (CR3) v2                 D-OOF F    17.1    29.52 10/1/05        11/1/05    Hydrazine 1-D-O0F (CR3) v2                 1-D-OOF                                                         N01I=9 10/1/05        11/1/05    Hydrazine P-D-OOF (CR3)v2                  P-D-OOF                                                         NODI=9 10/1/05        11/1/05  THydroquinone 1-D-OOF (CR3) v2               1-D-00FK                                                        NODI=9 10/1/05    1   11/1/05  ]Hydroquinone P-D-OOF (CR3) v2               P-D-OOF                                             1. .        NODI=9I 10/1/05        11/1/05 7Morpholine 1-D-OOF (CR3) v2                  1-D-OOF        25.71 10/1/05        11/1/05    Morpholine P-D-OOF (CR3) v2                P-D-OOF                                                         NODI=9 10/1/05        11/1/05    Number of Batches - I-OFE (CR3) v2           I-OFE 7                                                   1 10/1/05        11/1/05   ýOil and Grease - D-OOF (CR3) v2              D-OOF     I                                                              NODI=9 10/1/05        11/1/O       il and Grease - I-0FE (CR3) v2             I-0FE    I     2.3                   2.3 10/1/05        11/1/05    Oil and Grease - I-OFG (CR3) v2              I-OFG         3.19                   6.2 10/1/05        11/1/05    pHH-Background - D-OOF (CR3) v2              D-OOF     Ii                7.92    8.16 10/1/05        11/1/05    pH - Effluent - D-OOF (CR3) v2               D-OOF   -i-                 7.91    8.24 i

10/1/05 11/1/05 pH - I-OFE (CR3) v2 I-OFE 6.74 b. 74 10/1/05 11/1/05 pH - I-OFG (CR3) v2 I-OFG 8.39 8 .9 10/1/05 11/1/05 Residual Ox - Time of Discharge D013 (CR3) D013 0 10/1/05 11/1/05 ISpectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 10/1/05 11/1/05 Temp Rise - D013 (CR3) v2 D013 12.3 15 .9

                                                                               -i                         95 .5 10/1/05        11/1/05   ITemp-Discharge - D013 (CR3) v2               D013          89.5 10/1/05        11/1/05    Temp-Intake - D013 (CR3) v2  Q               D013          77.1                  84 .3 F

10/1/05 11/1/05 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NODI=9 10/1/05 11/1/05 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9I 10/1/05 11/1/05 [Total Copper - DOOF (CR3) Q DOOF NODI=9 NODI=9 10/1/05 11/1/05 Total Copper - I-OFG (CR3) v2 I-OFG N001=9 10/1/05 11/1/05 'Total Iron- D-O0F (CR3) v2 D-00F NODI=9 NODI=9 l101/5 - 11/1/05 ITotalIron- I-OFG (CR3) v2 I-OFG NODI=9 10/1/05 11/1/05 Total Recoverable Copper - D-OOF (CR3) v2 D-00F NODI=9 NODI=9 10/1/05 11/1/05 ýTotal Recoverable Iron - D-OOF (CR3) v2 D-00F NODI1=9 - NODI=9 10/1/05 11/1/05 ýTotal Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 NODI=9 10/1/05 11/1/05 TSS - CD and ECST D-OOF (CR3) v2 D-OOF NODI=B NODI=B 10/1/05 1 11/1/05 TSS - I-OFE (CR3) v2 I-OFE 0.3 0.3 10/1/05 11/1/05 TSS - I-OFG (CR3) v2 I-OFG 17.59 32.6 10/1/05 11/1/05 ISS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 10/21/2009 Page 30

Crystal River #ear DMR Data D~rmif Mki I *1 IIIIL IIV, I1 n I IIV lfl sfto Begin date EndDate ~ PARAM ETE-RNAE 06utall ; C*Avg ;

C-Min : ;*C-Max I: Q-Avg Q*Max "NODI-Avg NOD-Max 'NODI-Min 10/1/05 11/1/05 ITSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9 D-00F L NODI=9 10/1/05 11/1/05 ITurbidity - Background - D-OOF (CR3) v2 D-OOF -

NODI=9 10/1/05 11/1/05 iTurbidity - Calc Limit - D-OOF (CR3) v2 T D-OOF _ NODI=9 10/1/05 11/1/05 ITurbidity - Difference D-OOF (CR3) v2 D-OOF I NODI=9 10/1/05 11/1/05 !Turbidity - Effluent D-OOF (CR3) v2 Menidia Beryllina P-D-OOF (CR3) P-D-OOF NODI=9 11/1/05 12/1/05 1 96-Hour Q-D-OOF NODI=9 11/1/05 12/1/05 196-Hour Menidia Beryllina Q-D-OOF (CR3) 11/1/05 12/1/05 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-00F` T NODI=9 Q-D-OOF NODI=9 11/1/05 12/1/05 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) _ I-OFE Y 0.00005 0.0 1014 11/1/05 12/1/05 lFlow- I-OFE (CR3) v2 I-OFG 0.005 01.8 11/1/05 12/1/05 Flow - I-OFG (CR3) v2 D-OOF 0 0 11/1/05 12/1/05 Flow-CD System D-OOF (CR3) v2 Flow-ECST D-OOF (CR3) v2 D-OOF 0.001 0. 015 11/1/05 12/1/05 D-OOF 25.66 431.49 11/1/05 12/1/05 Flow-Intake - D-OOF (CR3) v2 11/1/05 12/1/05 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 _.N°D,- __. . .. . . 11/1/05 12/1/05 Hydrazine P-D-OOF (CR3) v2 P-D-OOF NODI=9 1 11/1/05 12/1/05 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI=9 11/1/05 12/1/05 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF 1 NO 01=9 11/1/05 12/1/05 Morpholine 1-D-OOF (CR3) v2 1-D-00F 9.34 . 11/1/05 12/1/05 Morpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9 11/1/05 12/1/05 'Number of Batches - I-OFE (CR3) v2 11/1/05 12/1/05 ]Oil and Grease - D-OOF (CR3) v2 D-OOF NO DI=9 11/1/05 12/1/05 Oil and Grease - I-OFE (CR3) v2 I-OFE 4 -- K 4 11/1/05 I-OFG 6.2 6.3 1 12/1/05 Toil and Grease - I-OFG (CR3) v2 11/1/05 12/1/05 pH - Background - D-OOF (CR3) v2 D-OOF 7.97 8.1 11/1/05 12/1/05 pH - Effluent - D-OOF (CR3) v2 D-OOF 7.97 8.1 11/1/05 L 12/1/05 pH - I-OFE (CR3) v2 I-OFE 7.29 7.29 11/1/05 12/1/05 pH - I-OFG (CR3) v2 I-OFG 8.25 8.58 11/1/05 12/1/05 IResidual Ox - Time of Discharge D013 (CR3) D013 0 11/1/05 12/1/05 1Spectrus CT1300 - DOOF (CR3) v2 DOOF NOD 11/1/05 12/1/05 ]Temp Rise - D013 (CR3) v2 D013 9.1 15.3 11/1/O5 12/1/05 ]Temp-Discharge - D013 (CR3) v2 D013 76.9 88.5 11/1/05 12/1/05 ITemp-Intake - D013 (CR3) v2 D013 67.9 73.6 11/1/05 12/1/05 !Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NODI=9 11/1/05 12/1/05 NODI=9

                          ýTotal Ammonia P-D-00F (CR3) v2             I P-D-00F        I 10/21/2009                                                                                    Page 31

Crystal River

ear DMR Data Permit No. FL00000159 Toa.oPARAMETER NACv2E CuA9 tv -min,,,x, CM -, Q-Avg .-Q-Max' NODI-Avg NODI-Max NODI-Min 9,e'in~date2 En DOOF NUL1=9 NODI=9 11/1/05 12/1/05 Total Copper - DOOF (CR3) v2 I-OFG -- NOD1=9 11/1/05 12/1/05 Total Copper - l-OFG (CR3) v2 D-OOF] NOD1=9 NODI=9 11/1/05 12/1/05 Total Iron- D-OOF (CR3) v2 T!

I-OFG NO 01=9 11/1/05 12/1/05 Total Rron- (CR3) v2 l-OFG FD-00F NODl=9 NOD1=9 v2 11/1/05 12/1/05 Total Recoverable Copper - D-OOF (CR3) D-OOF N001=9 NODI=9 11/1/05 12/1/05 Total Recoverable Iron - D-OOF (CR3) v2 1-D013 NODI=9 NODI=9 11/1/05 12/1/05 Total Residual Ox 1-D013 (CR3) v2 TSS - CD and ECST D-OOF (CR3) v2 D-OOF 4.2 NODl=B 11/1/05 12/1/05

                                                                                                                                                               ~1~~

12/1/05 TSS - I-OFE (CR.3) v2 I-OFE 3 3 11/1/05 TSS - I-OFG (CR3) v2 I-OFG 9.4 12.6 11/1/05 12/1/05 P-D-OOF N001=9 NODI=9 11/1/05 12/1/05 ITSS P-D-OOF (CR3) v2 11/1/05 NODI=9 NODI=9 12/1/05 ITSS Q-D-O0F (CR3) v2 O-0-00 F 11/1/05 12/1/05 Turbidity - Background - D-OOF (CR3) v2 D-OOF NODI=9 11/1/05 NODI=9 12/1/05 Turbidity - Calc Limit - D-OOF (CR3) v2 D-00F 11/1/05 12/1/05 jTurbidity - Difference D-OOF (CR3) v2 D-00F N001=9 12/1/05 Turbidity - Effluent D-OOF (CR3) v2 D-00F NODI=9 11/1/05 12/1/05 1/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100% NODI=9 12/1/05 1/1/06 196-Hour Menidia Beryllina Q-D-O0F (CR3) Q-D-OOF 12/1/05 1/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-00F >N100/ NODI=9 12/1/05 1/1/06 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-0OF 12/1/05 1/1/06 Flow - I-OFE (CR3) v2 I-OFE 0 0 12/1/05 1/1/06 Flow - IL0FG (CR3) v2 I-OFG 0.015 0.081 12/1/05 1/1/06 Flow-CD System D-OOF (CR3) v2 D-OOF 0.013 0.42 12/1/05 1/1/06 Flow-ECST D-OOF (CR3) v2 D-0OF 0.002 0.015 0 12/1/05 1/1/06 Flow-Intake - D-OOF (CR3) v2 0D-OF 21.52 43.4 12/1/05 1/1/06 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 12/1/05 1/1/06 Hydrazine P-D-00F (CR3) v2 P-D-OOF NODI=9 12/1/05 1/1/06 Hydroquinone 1-D-OOF (CR3) v2 1-D-0OF NODI=9 12/1/05 1/1/06 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 12/1/05 1/1/06 Morpholine 1-D-OOF (CR3) v2 T 1-D-OOF 57.81 12/1/05 1/1/06 Morpholine P-D-OOF (CR3) v2 P-D-OOF 0 NODI=9 12/1/05 1/1/06 Number of Batches - I-OFE (CR3) v2 I-OFE 0 12/1/05 1/1/06 Oil and Grease - D-OOF (CR3) v2 D-OF NOD I=E 12/1/05 1/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 12/1/05 1/1/06 Oil and Grease - I-OFG (CR3)_v2 l-OFG 6.51 -J 12.3 10/21/2009 Page 32

Crystal River Dear DMR Data Permit No. FL00000159 12/date - EndDate -,OPARAMETERuNAME outl _ _C-_*_g- .CMinC -. C-Ma, x (!Avg I Q-M~ax~ .NODI-AVgJ :NODI-Max .NODII-Min 12/1/05 1/1/06 pH - Background - D-OOF (CR3) v2 D-OOF 7.91 8.12

           -    1/1/06       pH - Effluent - D-OOF (CR3) v2               D-00F                                7.99     8.18 12/1/05 pH - I-OFE (CR3) v2                          I-OFE                                                                                        NODI=C      NODI=C 12/1/05     -    1/1/06 12/1/05          1/1/06       pH - I-0FG (CR3) Q2                          I-0FG                                7.72     8.83 12/1/05          1/1/06       Residual Ox -Time of Discharge D013 (CR3)    D013 12/1/05          1/1/06       Spectrus CT1300 - DOOF (CR3) v2              DOOF     '                                    2.13 12/1/05          1/1/06       Temp Rise_- D013 (CR3) v2                    D013             12.5                          17.2 12/1/05          1/1/06       Temp-Discharge     - D013 (CR3) v2           D013             70.9                     1   77.5 12/1/05          1/1/06       Temp-Intake - D013 (CR3) v2                  D013             58.3                         64.8 12/1/05          1/1/06       Total Ammonia 1-D-OOF (CR3) v2             1-D-OOF                                                                               NODI=9 12/1/05          1/1/06      jTotal Ammonia P-D-O0F (CR3) v2             P-D-OOF                                                                           i   NOD1=9 12/1/05          1/1/06      ITotal Copper - DOOF (CR3)v2  Q               DOOF         _        _          -[

__NODI=9 i NOD1=9 12/1/05 1/1/06 Total Copper l-OFG (CR3) v2

                                             -                            I-OFG                                                                                        NOD1=9 12/1/05          1/1/06       Total Iron- D-OOF (CR3)v2                    D-OOF                                                                               NODI=9   NODI=9 12/1/05          1/1/06       Total Iron- I-OFG (CR3) v2                   I-OFG                                                                                        NODI=9 12/1/05          1/1/06       Total Recoverable Copper - D-OOF (CR3) v2    D-..F.._.                                                                           NODI=9   NOD1=9
             -  1/1/06       Total Recoverable Iron - D-0OF (CR3)v2 Q     D-0OF                         I 12/1/05                                                                                                                                                        NODI=9   NODI=9 12/1/05          1/1/06       Total Residual Ox 1-DO13 (CR3) v2           1-DO13                                                                               NODI=9   NODI=9 1/1/06       TSS - CD and ECST D-OOF (CR3) v2             D-OOF                                           9.3                                 NODI=B 12/1/05 12/1/05          1/1/06       TSS - I-OFE (CR3) v2                          I-OFE                                                                              NODI=C   NODI=C 12/1/05          1/1/06       TSS - '-0FG (CR3)v2  Q                    i-OFG                8.4       J                    10 12/1/05          1/1/06       TSS P-D-OOF (CR3)v2                        P-D-OOF                           4_                                                  NODI=9   NOD1=9 12/1/05          1/1/06       TSS Q-D-OOF (CR3) v2                       Q-D-OOF                                                                               NODI=9   N-O001=9 12/1/05          1/1/06       Turbidity - Background - D-ODF (CR3)v2       D-OOF                                                                                        NODI=9 12/1/05          1/1/06       Turbidity - Calc Limit - D-ODF (CR3) v2      D-OOF                                                                                        NO 01=9 0.7.

12/1/05 1/1/06 J-Turbidity - Difference D-DOF (CR3) v2 D-0-DOF NODI=9 12/1/05 7 1/1/06 Turbidity - Effluent D-ODF (CR3) v2 D-0OF NOD1=9 1/1/06 2/1/06 6-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF NODI=9 1/1/06 2/1/06 96-Hour Menidia Beryllina Q-D-00F (CR3) Q-D-OOF NODI=9 1/1/06 2/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF r NODI=9 1/1/06 2/1/06 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF 1 NOD1=9 1/1/06 2/1/06 Flow - -OFE (CR3) v2 I-0EE I - 0.00007 0.0015 1/1/06 2/1/06 . Flow - -OFG (CR3) Q v-0FG 0.013 0).078 1/1/06 2/1/06 - Flow-CD System D-ODF (CR3) Q 0-OE 1/1/06 1 2/1/06 Flow-ECST 0-DOE (CR3) v2 D-OOF - - 0.002 1 1.015 10/21/2009 Page 33

Crystal River t ar DMR Data Permit No. FL00000159 'P in dFs. P-1 rl+ I II ~I A, F, - n,ftajtnrýaMtA ftrI:A ..I

                                                                                                                                                        ..naA~
                                                                                                                                                           .r%     NIA fl-tv.,    M 1/1/06           2/1/06   Flow-I ntake - D-OOF (CR3) v2                    D-00F1'                                       18.32       29.52        I 1-D-OOF Hydrazine 1-D-OOF (CR3) v2                                                                                                  NODI=9 1/1/06           2/1/06 P-D-OOF                                       I Hydrazine P-D-OOF (CR3) v2                                                                                                  NODI=9 1/1/06           2/1/06 1-D-OOF 2/1/06    Hydroquinone 1-D-OOF (CR3) v2                                                                                              NODI=9 1/1/06 1/1/06           2/1/06   Hydroquinone P-D-OOF (CR3) v2                  P-D-OOF                                                                      NODI=9 1/1/06           2/1/06   Morpholine 1-D-00F (CR3) v2                    1-D-OOF     i   57.98 1/1/06           2/1/06    Morpholine P-D-OOF (CR3) v2                   P-D-OOF                                                                      NODI=9 1/1/06           2/1/06    Number of Batches - -OFE (CR3)  v2              I-OFE                                            ~1~~         1 I

1/1/06 2/1/06 Oil and Grease - I-OE(CR3) v2 D-00F NODI=9 1/1/06 2/1/06 Oil and Grease - D-OFE (CR3) v2 I-0FE 5.5 NOD1=B I ] 3.37 1/1/06 2/1/06 Oil and Grease - I-OFG (CR3) v2 I-OFG 1.97 1/1/06 2/1/06 pH - Background - D-OOF (CR3) v2 D-00F 7.91 8.12 1/1/06 2/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.06 8.2 1/1/06 2/1/06 pH - I-OFE (CR3) v2 I-OFE 6.95 7.08 I 1/1/06 2/1/06 pH - I-OFG (CR3) v2 I-OFG 8.52 8.9 I.- 1/1/06 2/1/06 Residual Ox - Time of Discharge D013 (CR3) D013 0 1/1/06 2/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 1 1/1/06 2/1/06 Temp Rise - D013 (CR3) v2 D013 14.2 17.81 1/1/06 2/1/06 jTemp-Discharge - D013 (CR3) v2 D013 73.8 81.3 1/1/06 2/1/06 Temp-Intake - D013 (CR3) v2 D013 59.8 1 66.4 - 1/1/06 2/1/06 Total Ammonia 1-D-O0F (CR3) v2 1-D-OOF i NODI=9 1/1/06 2/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 1/1/06 2/1/06 Total Copper - DOOF (CR3) v2 -DOOF NODI=9 NOD1=9 1/1/06 2/1/06 Total Copper - I-OFG (CR3) v2 I-OFG I NODI=9 1 2/1/06 Total Iron- D-OOF (CR3) v2 D-OFG NODI=9 NODI=9 1/1/06 2/1/06 ITotal Iron- I-OFG (CR3) v2 1-0FG NODI=9 1/1/06 2/1/06 [Total Recoverable Copper - D-OOF (CR3) v2 D-OOF 7- NODI=9 T NODI=9 1/1/06 2/1/06 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 1/1/06 2/1/06 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 NODI=9 1/1/06 2/1/06 TSS - CD and ECST D-OOF (CR3) v2 D-OOF NODI=B 1/1/06 2/1/06 TSS - I-OFE (CR3) v2 I-OFE 3.3 3.9 1/1/06 2/1/06 TSS - I-OFG (CR3) v2 I-OFG 8.57 16.3[- 1/1/06 2/1/06 TSS P-D-OOF (CR3)2 P-D-OOF NODI=9 NODI=9 1/1/06 2/1/06 TSS Q-D-OOF (CR3) 2 Q-D-OOF NODI=9 NODI=9 1/1/06 I 2/1/06 lTurbidity - Background - D-00F (CR3) v2 D-OOF [ I NODI=9 10/21/2009 Page 34

Crystal River sear DMR Data Permit No. FL00000159 K-*Kd t.1bK7 nd* iat*iu_

                         ¢.       ;*< PAR~;*
                                           .METER.,NANl;l           ~J.-[                   AgMa A*g>.                               Q-!A g'         NODI-AVg    N.DI Max NODI-Min.

1/1/06 2/1/06 ITurbidity - Calc Limit - D-OF (CR3) v2 D-OOF NODI=9 D-OOF NODI=9 1/1/06 2/1/06 Turbidity - Difference D-OOF ýCR3) v2 -

                                                                          !-D-00F                                                                            NODI=9 1/1/06         2/1/06     ITurbidity - Effluent D-OOF (CR3) v2 P-D-OOF                               II          _
                                                                                                                                                                        >100 2/1/06         3/1/06      96-Hour Menidia Beryllina P-D-OOF (CR3)   1 96-Hour Menidia Beryllina Q-D-OOF (CF3)   1 Q-D-OOF                                                                                      NOD1=9 2/1/06         3/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v21     P-D-OOF                                                                                    IODI=H 2/1/06         3/1/06 2/1/06         3/1/06      96-Hour Mysidopsis Bahia Q-D-OOF (CF3)__       Q-D-OOF                                                                                   N1OD1=9 2/1/06     L   3/1/06      Flow   - I-OFE (CR3) v2                          I-OFE                                                0        0 2/1/06     f   3/1/06      Flow  -  1-0FG (CR3) v2                          I-0FG                                             0.014     0.075 2/1/06         3/1/06      Flow-CD System D-OOF (CR3) v2                   D-OOF                                                 0        0 2/1/06         3/1/06      Flow-ECST D-OOF (CR3) v2                        D-OOF                                              0.003     0.015 2/1/06     1   3/1/06      Flow-intake - D-OOF (CR3) v2                    D-OOF                                              15.82      29.5 2/1/06         3/1/06      Hydrazine 1-D-OOF (CR3) v2                     1--D-OF                                                              NODI=9 2/1/06         3/1/06      Hydrazine P-D-OOF (CR3) v2                     P-D-OOF                                                              NO ,1=9 2/1/06 2/1/06 2/1/06 3/1/06 3/1/06 3/1/06 Hydroquinone 1-D-OOF (CR3) v2 FHydroquinone P-D-OOF (CR3) v2 Morpholine 1-D-OOF (CR3) v2 1-D-OOF P-D-OOF 1-D-OOF iii  41.93 NO 01=9 NODI=9 I---------

2/1/06 3/1/06 Morpholine P-D-OOF (CR3) v2 P-D-DOF [ IIULjI=:7 2/1/06 3/1/06 Number of Batches - I-OFE (CR3) v2 I-OFE 0 0 2/1/06 3/1/06 Oil and Grease - D-OOF (CR3) v2 D-00F NODI=9 2/1/06 3/1/06 Oil and Grease - I-OFE (CR3) v2 I-0FE NODI=C NIfl ~I 6.5 2/1/06 ] 3/1/06 Oil and Grease - I-0FG (CR3) v2 I-OFG 3.07 2/1/06 3/1/06 pH - Background - D-OOF (CR3) v2 D-00F 7.96 l 8.17 1 2/1/06 3/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.06 8.18 I-2/1/06 3/1/06 pH - I-OFE (CR3) v2 I-0EE NODI=C NODI=C I -0FG 2/1/06 3/1/06 pH - I-OFG (CR3) v2 8.55 8.75 2/1/06 3/1/06 Residual Ox - Time of Discharge D013 CR3)1 D013 0 2/1/06 3/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.15 I 2/1/06 3/1/06 Temp Rise - D013 (CR3) v2 D013 15.6 17 _ 2/1/06 3/1/06 ITemp-Discharge - D013 (CR3) v2 D013 83,4 2/1/06 3/1/06 Temp-Intake - D013 (CR3) v2 D013 59.6 66.1 2/1/06 3/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-00F 2/1/06 [ 3/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-O0F

.t-

__t__ NODI=9 2/1/06 3/1/06 ITotal Copper - DOOF (CR3) v2 DOOF NODI=9 NODI=9 2/1/06 1 3/1/06 ITotal Copper - I-0FG (CR3) v2 I-OFG NODI=9 10/21/2009 Page 35

Crystal River Dear DMR Data Permit No. FL00000159 Begin dat En aePARAMETER-NAME ' C-Av -min, CMiax ' Q-Avg Q-Maxý '11NODI-Avg_., NODI-Max 1NODI-Min' 2/1/06 3/1/06 D-OOF NODI=9 l-- NODI=9 Total Iron- D-OOF (CR3) v2 2/1/06 2/1/06 2/1/06 3/1/06 3/1/06 3/1/06 JTotal ITotal Iron- I-OFG (CR3) v2 Recoverable Copper - D-OOF (CR3) V Total Recoverable iron - D-OOF (CR3) v2 J2 I-OFG D-00F D-OOF NODI=9 NODI=9 i NODI=9 NODI=9 NODI=9 2/1/06 3/1/06 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 N001=9 D-OOF 2/1/06 3/1/06 TSS - CD and ECST D-OOF (CR3) v2 NODI=B NODI=B I-0IFE 2/1/06 3/1/06 TSS - I-OFE (CR3) v2 NODI=C NODI=C 2/1/06 3/1/06 TSS - I-OFG (CR3) v2 I-OFG 6.71 20 2/1/06 3/1/06 TSS P-D-OOF (CR3) v2 P-D-OOF_- -N DI__ NODI=9 Q-D-00F 2/1/06 TSS Q-D-OOF (CR3) v2 NODI=9 NODI=9 3/1/06 D-OOF 2/1/06 3/1/06 Turbidity - Background - D-OOF (CR3) v2 N001=9 2/1/06 3/1/06 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF NODI=9 2/1/06 3/1/06 Turbidity - Difference D-O0F (CR3) v2 D-OOF NODI=9 2/1/06 3/1/06 Turbidity - Effluent D-OOF (CR3) v2 D-OOF NODI=9 3/1/06 4/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100 3/1/06 4/1/06 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 4/1/06 3/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v:2jP-D-OOF _ >100 4/1/06 I 3/1/06 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF _ _ NODI=9 4/1/06 3/1/06 4/1/06 Flow - I-OFE (CR3) v2 I-OFE j 0.00002 0.0007 3/1/06 4/1/06 Flow - I-OFG (CR3) v2 I-OFG 0.0045 0.0728 _______ I~1 3/1/06 Flow-CD System D-OOF (CR3) v2 D-0OF 0.0043 1.2487 4/1/06 3/1/06 4/1/06 Flow-ECST D-OOF (CR3) v2 D-OOF 0.0015 0.0078 3/1/06 Flow-Intake - D-OOF (CR3) v2 D-OOF 19.92 29.S2 3/1/06 3/1/06 4/1/06 4/1/06 Hydrazine 1-D-OOF (CR3) v2 Hydrazine P-D-OOF (CR3) v2 1-D-OOF F P-D-OOF I NODI=9 NODI-9 4/1/06 3/1/06 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI=9 4/1/06 3/1/06 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 4/1/06 [- 3/1/06 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 30.8 4/1/06 3/1/06 Morpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9 4/1/06 3/1/06 Number of Batches - I-OFE (CR3) v2 I-OFE 1 4/1/06 3/1/06 Oil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 4/1/06 3/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE 2.12 I 2.12 4/1/06 3/1/06 ]Oi'1 and Grease - I-OFG (CR3) v2 I-OFG 2.43 2.5 4/1/06 3/1/06 4/1/106 IpH - Background - D-OOF (CR3) v2 D-00F D-O0F , I 8.16 8.17 --F -[ - _ 3/1/06 v2 8.08 8.17 _pH- Effluent - D-OOF (CR3) 10/21/2009 Page 36

Crystal River Dear DMR Data Permit No. FL00000159 Begi 1ndate 4EnDte6 -I PARAMETER NAME 8 ut'all j L-Mvg. C-i CU-Max QAg, Q ax N -Ag NDI-Max ND-i 3/1/06 4/1/06 pH - I-OFE (CR3) v2 I-0FE 6.77 6.77 3/1/06 4/1/06 pH - l-OFG (CR3) v2 I-OFG 8.48 8.55 0 I-3/1/06 4/1/06 lResidual Ox-Time of Discharge D013 (CR3)L D013 3/1/06 4/1/06 ]Spectrus CT1300 - DOOF (CR3) v2 - DOOF 2.3 3/1/06 4/1/06 ITemp Rise - D013 (CR3) v2 D013 13.4 17.1 3/1/06 4/1/06 ITemp-Discharge - D013 (CR3) v2 D013 I 80.3 89.9 3/1/06 4/1/06 ITemp-Intake - D013 (CR3) v2 D013 67 72.9 3/1/06 4/1/06 ITotal Ammonia 1-D-OEF (CR3) v2 1-0-00F NODI=9 3/1/06 4/1/06 1Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 I 3/1/06 4/1/06 ]Total Copper - DOOF (CR3) v2 DOOF NODI=9 NODI=9 3/1/06 4/1/06 ITotal Copper - I-OFG (CR3) v2 t-OFG NODI=9 3/1/06 4/1/06 iTotal Iron- D-OOF (CR3) v2 D-OOF NO 01=9 NODI=9 3/1/06 4/1/06 ]Total Iron- I-OFG (CR3) v2 I-OFG NOD 1=9 3/1/06 4/1/06 ITotal Recoverable Copper - D-O0F (CR3) v2 0-00DF NODI=9 NO 01=9 0-00 F NODI=9 NODI=9 3/1/06 4/1/06 ITotal Recoverable Iron - D-OOF (CR3) v2 ITotal Residual Ox 1-D013 (CR3) v2 1-D013 INODI=9 NODI=9 3/1/06 1 4/1/06 3/1/06 4/1/06 ýTSS - CD and ECST D-OOF (CR3) v2 D-OOF u NODI=B NOW=B 3/1/06 4/1/06 ITSS - I-OFE (CR3) v2 I-OFE 11.3 11.3 3/1/06 4/1/06 TSS - I-OFG (CR3) v2 I-OFG 4.97 r 3/1/06 4/1/06 TSS P-D-OOF (CR3)v2 P-D-OF NODI=9 '4001=9 r 3/1/06 4/1/06 ýTSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 '4001=9 3/1/06 4/1/06 ýTurbidity - Background - D-OOF (CR3) v2 D-OOF

                                                                                                                                                        '4001=9 3/1/06          4/1/06       Turbidity - Calc Limit - D-OOF (CR3) v2      D-OOF NODI=9 3/1/06          4/1/06       Turbidity_- Difference D-OOF (CR3) v2        D-OOF NODI=9 3/1/06           4/1/06     ITurbidity - Effluent D-00F (CR3) v2          D-00F 4/1/06           5/1/06      96-Hour Menidia Beryllina P-D-OOF (CR3)    P-D-0FW                                                                                   NODI=9 4/1/06           5/1/06     196-Hour Menidia Beryllina Q-D-00F (CR3)    Q-D-OOF                                                                                   NODI=9 4/1/06           5/1/06     196-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF      I                                                                     NODI=

NODI=9 jL 4/1/06 5/1/06 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 4/1/06 5/1/06 Flow - I-OFE (CR3)v2 I-OFE 0 0 4/1/06 5/1/06 Flow - I-OFG (CR3) v2 I-OFG 1.0203_- 0.0807 4/1/06 5/1/06 Flow-CD System D-OOF (CR3) v2 D-OOF F I ___ 4/1/06 5/1/06 Flow-ECST D-OOF (CR3) v2 D-OOF 0.045 0.0153 4/1/06 5/1/06 Flow-Intake - D-OOF (CR3) v2 D-OOF 16.53 31.3 4/1/06 5/1/06 _ Hydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 10/21/2009 Page 37

Crystal River Dear DMR Data iBegicatewI EndDa **e PARAMETER NAME O'utall C-AC-M 4/1/06 5/1/06 IHydrazine P--O-00 <CR3)>v2 I -o-ooF NODI=9 4/1/06 5/11/06 jHydroquinone 1-D-00F (CR3)v2 i1-D-00F NODI=9 4/1/06 { _ _5/1/06 Hydroquinone P-D-OOF (CR3)_v2 P-D'00F ___ N001=9 4/l/ 5/1/06 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 1 28.9 . 4/1/06 5/1/06 IMorpholine P-D-OOF (CR3) v2 P-D-00F I NODI=9 4/1/06 5/1/06 Number of Batches - I-OFE (CR3) v2 I-0FE I 0 0 4/1/06 5/1/06 Oil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 4/1/06 5/1/06 Oil and Grease - I-OFE (CR3)v2 I-OFE NODI=C NODI=C 4/1/06 5/1/06 Oil and Grease - I-OFG (CR3) v2 I-OFG NODI=B NODI=B 4/1/06 5/1/06 pH - Background - D-OOF (CR3) v2 D-OOF 7.89 8.1 7 4/1/06 5/1/06 pH - Effluent - D-DDF (CR3) v2 D-O0F 7.89 8.1 8 4/1/06 5/1/06 pH- I-OFE (CR3) v2 I-OFE NODI=C NODI=C 1 4/1/06 5/1/06 pH - '-0FG (CR3) v2 I-0FG 8.48 8.9 6 4/1/06 1 5/1/06 Residual Ox - Time of Discharge D013 (CR3) D013 . 0 4/1/06 1 5/1/06 ISpectrus CT1300 - DO00 (CR3) v2 I DOOF 2.3 5 4/1/06 5/1/06 Temp Rise - D013 (CR3) v2 D013 14.4 1 16. 7 4/1/06 5/1/06 [Temp-Discharge - D013 (CR3) v2 D013 89.3 95. 7 4/1/06 5/1/06 Temp-Intake - D013 (CR3) v2 D013 74.9 81. 7 4/1/06 5/1/06 T-ota monia 1--0O CR3)v2 1-0D-OF-4/1/06 5/1/06 jTotal Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 4/1/06 5/1/06 Copper - D0F (CR3) v2 PTotal D0OOF NODI=9 4/1/06 } 5/1/06 Total Copper -I-OFG (CR3)v2 I-0FG NODI=9 NOD 1=9 4/1/06 5/1/06 ITotal Iron- D-OOF (CR3) v2 D-00 F NODI=9 4/1/06 4/1/06

             }     5/1/06 5/1/06 Total Iron- I-FG (CR3) v2 ITotal ro               Copper - D-00F (CR3) v2 I-OFG D-OOFD............-i NODI=9      N001=9 4/1/06              5/1/06             Total Irovea-ble IonD-F-    (CR3) v2     v          D-OF                                                                   -. NODI=9 4/1/06              5/1/06 4/1/06 ~~           ~

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                                                                       ~       ~ ~           :00- ,O
                                                                                             -OF
                                                                                                      ......... ... _                 ......            NOD-1=9 P   NODI=9 NOD1=9  P   NODI=9 4/1/06              5/1/06            ITotal Residual Ox 1-D013 (CR3) v2                  1-D013                                                         NOD1=9      NODI=9 4/1/06              5/1/06             TLSS  - CD and ECST D-00F (CR3) v2                  D---OF -     .     ...    . . . ....   .  ...    . . .

NODI=B NODI-B 4/1/06 5/1/06 ITSS - ,-FE (CR3) v2 I-0FE . 6 NODI=C NODI=I-C 4/1/06 4/1/061 4/1/06 I 5/1/06 5/1/06 5/1/06 ITSS -D-OOG (CR3)v2 ITSS P-D-OOF (CR3)v2 ITss Q-D-00F (CR3) v2 I'-OGF P-D-OOF Q-D-OOF 693 8 NODI=9 NODI=9 ii I NODI=9 NODI=9 4/1/06

5/1/06 }Turbidity - Background - D-OOF (CR3) v2 D-DOF NODI=9 I

I 4/1/06 I 5/1/06 Turbidity - Calc Limit - D-O0F (CR3) v2 -D-OF NODI=9 4/1/06 . 5/1/06 Turbidity - Difference D-ODF (CR3)v2 0D-0F SNODI=9 10/21/2009 Page 38

0 Crystal River

Permit No. FL00000159 ear DMR Data gifBgi'adeate d *.**;.:

                       .**, .*-*"*   *   .* . *  ,, *. ,  .*  :*,  :*,,,* , *..;.:, ,*..* *,* ,* ',*   '- * -. . * *,,   t. V ,* . .,* ,* *.. C'7MinAAM

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S________ ________ I~-~-.---. I - 4/1/06 5/1/06 ITurbidity - Effluent D-OOF (CR3) v2 D-OOF NODI=9

              ]   6/1/06           196-Hour Menidia Beryllina P-D-OOF (CR3)                        P-D-OOF                                                                                                                                    NODI=E 5/1/06 5/1/06             6/1/06             96-Hour Menidia Beryllina Q-D-OOF (CR3)                       Q-D-OOF                                                                                                                                    NODI=E 5/1/06                                96-Hour Mysidopsis Bahia P-D-OOF (CR3)               v2I      P-D-OOF                                                                                                                                    NODI=E 5/1/06             6/1/06             96-Hour Mysidopsis Bahia Q-D-OOF (CR3)                        Q-D-OOF                                                                                                                                    NODI=E 5/1/06             6/1/06             Flow - I-OFE (CR3) v2                                            I-OFE                                                                         0.000023        0.00071 5/1/06             6/1/06             Flow - I-OFG (CR3) v2                                           I-OFG                                                                            0.00255       0.0791 5/1/06             6/1/06             Flow-CD System D-OOF (CR3) v2                                   D-OOF                                                                                0            0 5/1/06             6/1/06           IFlow-ECST D-OOF (CR3) v2                                         D-OOF                                                                          0.000245        0.00759 5/1/06             6/1/06             Flow-Intake - D-OOF (CR3) v2                                    D-OOF                                                                              15.58         20.3 5/1/06             6/1/06             Hydrazine 1-D-OOF (CR3) v2                                     1-D-OOF                                                                                                     NODI=9         . . . . ..... -.. ..

5/1/06 6/1/06 Hydrazine P--OOF (CR3) v2Q P-D-OOF 4 i 4 NODI=9 N001=9 5/1/06 6/1/06 lHydroquinone 1-D-OOF (CR3) v2 1-D-OOF I_ I 5/1/06 6/1/06 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NOD0=9 5/1/06 6/1/06 1yMorpholine 1-D-OOF (CR3) v2 1-D-OOF 43.58 5/1/06 6/1/06 iMorpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9 5/1/06 6/1/06 Number of Batches - I-OFE (CR3) v2 I-OFE 1 1 5/1/06 6/1/06 iOil and Grease - D-OOF (CR3) v2 D-OOF NOD 1=9 5/1/06 6/1/06 Oil and Grease - -OFE (CR3) v2 I-OFE 5/1/06 6/1/06 Oil and Grease - I-OFG (CR3) v2 I-OFG i 0.69 3.3 7 5/1/06 6/1/06 pH - Background - D-OOF (CR3) v2 D-OOF I 7.99 8.1 2 5/1/06 6/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF J 7.99 8.2 7; 5/1/06 6/1/06 pH - I-OFE (CR3) v2 I-OFE ! 6.53 6.5 3 . 5/1/06 6/1/06 pH - I-OFG (CR3) v2 I-OFG 8.76 8.91-3 I I 5/1/06 } 6/1/06 IResidual Ox -Time of Discharge D013 (CR3)1 D013 0 -D_ 5/1/06 j 6/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.2' 1 5 I 5/1/06 6/1/06 iTemp Rise - D013 (CR3) v2 D013 13.4 15.;2 _! 5/1/06 6/1/06 iTemp-Discharge - D013 (CR3) v2 D013 91.8 96.: 3 5/1/06 6/1/06 Temp-Intake - D013 (CR3) v2 D013 78.4 84.: 5/1/06 6/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NO01=9 5/1/06 6/1/06 !Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NOD1=9 5/1/06 6/1/06 ITotal Copper- DOOF (CR3) v2 DOOF j NODI=9 NODI=9 ITotal 5/1/06 1 6/1/06 Copper - I-OFG (CR3) v2 I-OFG _ - - I NODI=9 5/1/06-1 6/1/06 'Total Iron- D-OOF (CR3) v2 D-00F NODI=9 5/1/06 6/1/06 ITotal Iron- I-OFG (CR3) v2 I-OFG NODI=9 10/21/2009 Page 39

Crystal River Bear DMR Data <Begin date End Date ~ PARKAMETEILRJNAME utI NODI-.AvgI INODI-Max NOD.I-Min 5/1/06 6/1/06 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 5/1/06 6/1/06 [Total Recoverable Iron - D-OF (CR3) v2 D-OOF NODI=9 NODI=9 5/1/06 6/1/06 ITotal Residual Ox 1-D013 (CR3) v2 I 1-D013 NODI=9 . NODI=9 5/1/06 6/1/06 iTSS - CD and ECST D-0OF (CR3) v2 I D-OOF NODI=B NODI=B 5/1/06 6/1/06 TSS - (-0FE (CR3) v2 I-0FE 29 29 ___ 5/1/06 I 6/1/06 ITSS - I-OFG (CR3) v2 1 I-OFG 12.72 24 5/1/06 1 6/1/06 ITSS P-D-OOF (CR3) v2 P-D-OOF - NODI=9 NODI=9 5/1/06 6/1/06 ITSS Q-D-00F (CR3) v2 j Q-D-OOF NODI=9 NODI=9 5/1/06 6/1/06 ITurbidity - Background - D-OOF (CR3) v2 D-OOF NOD 1=9 5/1/06 1 6/1/06 ITurbidity - Calc Limit- D-OOF (CR3) v2 D-00F NOD.. =9 5/1/06 6/1/06 ITurbidity - Difference D-OOF (CR3) v2 D-OOF NODI=9 5/1/06 6/1/06 Turbidity - Effluent D-OOF (CR3) v2 D-OOF NODI=9 6/1/06 7/1/06 [96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF NODI=9 6/1/06 7/1/06 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 6/1/06 7/1/06 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-00F NO 01=9 6/1/06 7/1/06 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 6/1/06 7/1/06 Flow - -FE (CR3) v2 I-OFE 0 0 6/1/06 7/1/06 Flow - I-OFG (CR3) v2 I-OFG 0.0122 0.074814 6/1/06 7/1/06 Flow-CD System D-OOF (CR3) v2 D-0OF 0 0 6/1/06 7/1/06 1Flow-ECST D-OOF (CR3) v2 D-0OF 0.0015 0.01495 6/1/06 7/1/06 Flow-Intake - D-OOF (CR3) v2 D-OOF 15.91 34.27 6/1/06 7/1/06 lHydrazine 1-D-OOF (CR3) v2 1-D-OOF MI_._ N1001=9 i NT 6/1/06 7/1/06 IHydrazine P-D-OOF (CR3)v2 P-D-OOF OD1=9 6/1/06 7/1/06 Hydroquinone 1-D-OOF(CR3) v2 1-D-OOF INODI0=9 __6/1/06 7/1/06 iHydroquinone P-D-OOF (CR3) v2 P-D-OOF 1001=9 6/1/06 7/1/06 Morpholine 1-D-OOF (CR3) v2 1-D-00F 38.35 6/1/06 [ 7/1/06 Morpholine P-D-OOF (CR3) v2 PD-OOF IODI=9 6/1/06 7/1/06 Number of Batches - I-OFE (CR3) v2 - -OFE 0 0 6/1/06 7/1/06 Oil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 6/1/06 7/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE INIODI=C NODI=C 6/1/06 7/1/06 Oil and Grease - I-OFG (CR3) v2 I-OFG 0.85 2 6/1/06 7/1/06 pH - Background - D-OOF (CR3) v2 D-OOF 7.66 8.12 I7 6/1/06 7/1/06 1pH - Effluent - D-OOF (CR3) v2 D-OOF 7.94 F 8.12 6/1/06 7/1/06 pH - I-OFE (CR3) v2 I-OFE 1~ NOD I=C NODI=C 6/1/06 7/1/06 pH- I-OFG (CR3) v2 I-OFG 8.38 8.46 10/21/2009 Page 40

Crystal River ear DMR Data Permit No. FL00000159

Begin date* _End DateL PARAMETER NAMEj OutaIV <C-Agj.;CMf CaiyQ-Avg Q-a, ND-Ag. OI-a bIMin 6/1/06 7/1/06 Residual Ox - Time of Discharge D013 (CR3)I D013 0 6/1/06 7/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 6/1/06 7/1/06 Temp Rise - D013 (CR3) v2 D013T 9.8 -[ 13.3 6/1/06 7/1/06 -Temp-Discharge - D013 (CR3) v2 D013 93 95.9

__F 6/1/06 7/1/06 Temp-Intake - D013 (CR3) v2 D013 83.2 87.4 I9 NODI=9 6/1/06 7/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF 6/1/06 . 7/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-00F NODI=9 6/1/06 7/1/06 Total Copper - DOOF (CR3) v2 DOOF NODI=9 NODI=9 6/1/06 7/1/06 ITotal Copper - I-OFG (CR3) v2 I-OFG NODI=9 6/1/06 7/1/06 iTotal Iron- D-OOF (CR3) v2 D-OOF NODI=9 NOD1=9 6/1/06 7/1/06 iTotal Iron- I-OFG (CR3) v2 I-OFG NODI=9 6/1/06 - 7/1/06 Total Recoverable Copper - D-OOF (CR3) v2 D-00F NODI=9 NODI=9 6/1/06 [ 7/i/06 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF NODI=9 6/1/06 7/1/06 Total Residual Ox 1-D013 (CR3) v2 1-DO13 N001=9 NODI=9 I __________ ________ D-00F 6 /1/06 j 7/1/06 -TSS - CD and ECST D-OOF (CR3) v2 I ____ - .-.- -. :.. - ........ -- L NODI=B NODI=B 6/1/06 - 7/1/06 TSS - ,-OFE (CR3) v2 I-OFE NODI=C NODI=C 7/1/06 TSS - I-OFG (CR3) v2 I-OFG 9.87 . . . . . . . 6/1/06 j - 6/1/06 7/1/06 ITSS P-D-00F (CR3) v2 P-D-OOF __ I _ NODI=9 NODI=9 6/1/06 7/1/06 ITSS Q-D-OOF (CR3) v2 Q-D-OOF ----7 I NODI=9 NODI=9 6/1/06 7/1/06 Turbidity - Background - D-OOF (CR3) v2 D-00F

                                                                                                           ~~1~                                                                             NODI=9 6/1/06              7/1/06       Turbidity - Calc Limit - D-O0F (CR3) v2            D-OOF                                                                                                 NODI=9 6/1/06              7/1/06                                                                                                                                                                N NODI=9

[Turbidity - Difference D-OOF (CR3) v2 D-00F NODI=9 6/1/06 7/1/06 Turbidity - Effluent D-O0F (CR3) v2 D-OOF J I ___ 7/1/06 8/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100 I ___ 7/1/06 8/1/06 96-Hour Menidia Beryllina Q-D-OOF (CR3) 0Q-D-OOF NODI=9 7/1/06 8/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF >100 7/1/06 8/1/06 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 T _ . . . . . . . . . 7/1/06 8/1/06 Flow - I-OFE (CR3) v2 I-OFE 0 7/1/06 8/1/06 Flow - I-OFG (CR3) v2 I-OFG 0.01365 0.07802 7/1/06 8/1/06 Flow-CD System D-OOF (CR3) v2 D-OOF 0__ _ ] _ 0 7/1/06 8/1/06 Flow-ECST D-OOF (CR3) v2 D-OOF 0.00192 0.014906 7/1/06 8/1/06 Flow-Intake - D-O0F (CR3) v2 D-OOF 15.65 29.52 7/1/06 8/1/06 Hydrazine 1-D-OOF (CR3) v2 1-D-00F NODI=9 7/1/06 8/1/06 Hydrazine P-D-OOF (CR3) v2 P-D-OOF _ _NODI=9 7/1/06 8/1/06 Hydroquinone 1-D-OOF (CR3) v2 _______ 1~~~ 1-D-00F ! NODI=9 10/21/2009 Page 41

Crystal River DIear DMR Data Permit No. FL00000159 Begin dat End ate P E ' C-vg* ., C-Min C* Max ; l, Q-Avg Q-Max NODI-Avg NODI-Max ý NODI-Min 7/1/06 8/1/06 !Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 7/1/06 8/1/06 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 43.83 7/1/06 8/1/06 Morpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9 7/1/06 8/1/06 Number of Batches - -OFE (CR3) v2 I-0 FE 0 ! 0 7/1/06 8/1/06 Oil and Grease - D-OOF (CR3) v2 NODI=9 7/1/06 8/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 7/1/06 8/1/06 Oil and Grease - I-OFG (CR3) v2 l-OFG 0.85 1.75 7/1/06 8/1/06 pH - Background - D-OOF (CR3) v2 D-00F 7.88 8.34 7/1/06 8/1/06 pH - Effluent - D-OOI(CR3) v2 7.93 8.34 7/1/06 8/1/06 pH - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 7/1/06 8/1/06 pH - I-OFG (CR3) v2 l-OFG 8.31 8.71 7/1/06 8/1/06 Residual IOx -Time of Discharge D013 (CR3)- 0D13 . i. 0 7/1/06 8/1/06 [Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.2 7/1/06 8/1/06 ITemp Rise - D013 (CR3) v2 D013 7.4 9.1 7/1/06 8/1/06 ITemp-Discharge - D013 (CR3) Q D013 93.8 96 7/1/06 8/1/06 Temp-Intake - D013 (CR3) v2 D013 86.4 789.4A 7/1/06 8/1/06 Total Ammonia 1-0-O0E (CR3) v2 1-D-00F NODI=9 7/1/06 8/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 7/1/06 8/1/06 Total Copper - DOOF (CR3) v2 DOOF NODI=9 7/1/06 8/1/06 Total Copper - I-OFG (CR3) v2 I-OFG NOD1=9 7/1/06 8/1/06 Total Iron- D-OOF (CR3) v2 D-00F NODI=9 NOD1=9 7/1/06 8/1/06 ITotal Iron- I-OFG (CR3) v2 I-0FG NO001=9 7/2/06 8/1/06 iTotal Recoverable Copper - D-O00 (CR3) v2 D-OOF NODI=9 NODI=9 7/1/06 8/1/06 Total Recoverable Iron - D-OOF (CR3) v2 D-00F NODi-=9 NOD1=9 7/1/06 8/1/06 _[Total Residual Ox 1-0013 (CR3) v2 1-DO13 7.61 NO 01=9 NOD1=9 7/1/06 8/1/06 TSS - CD and ECST D-OOF (CR3) v2 D-00F NODI=B NODI=B 7/1/06 8/1/06 ýTSS - -OFE (CR3) v2 I-OFE NODi=C NODI=C 7/1/06 8/1/06 TSS - I-OFG (CR3) v2 I-0FG 12.7 7/1/06 8/1/061 TSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NOD1=9 7/1/06 8/1/06 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9 7/1/06 8/1/06 ýTurbidity - Background - D-OOF (CR3) v2 D-OOF NODI=9 7/1/06 8/1/06 [Turbidity - Calc Limit- D-00F (CR3) v2 D-ODF NOD1=9 7/1/06 8/1/06 Turbidity - Difference D-O0F (CR3) v2 D-OOF NOD 1=9 7/1/06 8/1/06 ITurbidity - Effluent D-O0F (CR3) v2 D-O0F NODI=9 8/1/06 9/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF T- NODI=9

                                                                                                                                               -1 10/21/2009                                                                                    Page 42

Crystal River tear DMR Data Permit No. FL00000159 B8egin dat EndDate PARAMETER nae.V NAME 71 7ual q Avg ~ CM -a - Q-Max NODI-Max' NODI-Min OI -&ggOtI,~<CA 9/1/06 96-Hour Menidia Beryllina Q-D-OOF (CR3) I Q-D-OOF NODI=9 8/1/06 8/1/06 9/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 1 P-D-00F NODI=9 9/1/06 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 8/1/06 II 0 o- 0 8/1/06 9/1/06 Flow - I-OFE (CR3) v2 I-OFE 8/1/06 9/1/06 Flow - I-OFG (CR3) v2 I-OFG 0.010757 0.076952 8/1/06 9/1/06 Flow-CD System D-OOF (CR3) v2 D-OOF 0.017798 0.551746 8/1/06 9/1/06 Flow-ECST D-OOF (CR3) v2 D-OOF 0.001858! 0.0147 8/1/06 9/1/06 Flow-Intake - D-OOF (CR3) v2 D-OOF 18.15 43.49 8/1/06 9/1/06 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF I NODI=9 8/1/06 9/1/06 Hydrazine P-D-OOF (CR3) v2 2 P-D-OOF NOD 1=9 8/1/06 9/1/06 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI=9 8/1/06 9/1/06 Hydroquinone P-D-OOF (CR3) Q P-D-OOF NODI=9 8/1/06 9/1/06 Morpholine 1-D-O0F (CR3) v2 1-D-OOF 27 .6 NODI=9 8/1/06 9/1/06 Morpholine P-D-OOF (CR3) v2 P-D-OOF 8/1/06 9/1/06 Number of Batches - I-OFE (CR3) v2 I-OFE 0 0 8/1/06 9/1/06 ýOil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 8/1/06 9/1/06 Oil and Grease - -OFE (CR3) v2 I-OFE NODI=C NODI=C Oil and Grease - I-OFG (CR3) v2 I-OFG 2. 13 4 8/1/06 9/1/06 8/1/06 9/1/06 pH - Background - D-OOF (CR3) v2 D-OOF 8.1 8.36 8/1/06 9/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.1 8.26 8/1/06 9/1/06 pH - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 8/1/06 9/1/06 pH - I-OFG (CR3) v2 I-OFG 8.26 i 8.86 8/1/06 9/1/06 Residual Ox - Time of Discharge D013 (CR3) D013 0 8/1/06 9/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 8/1/06 9/1/06 Temp Rise - D013 (CR3) v2 D013 6. .4 8.4 8/1/06 9/1/06 Temp-Discharge - D013 (CR3) v2 D013 93 87-. 963 1 8/1/06 9/1/06 Temp-Intake - D013 (CR3) v2 D013 87 .4 90 8/1/06 9/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NOD.=9 8/1/06 9/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 8/1/06 9/1/06 ITotal Copper - DOOF (CR3) v2 D00F NOD1=9 8/1/06 9/1/06 Total Copper - I-OFG (CR3) v2 I-OFG NODI=9 1 _ __ _ I I 8/1/06 9/1/06 Total Iron- D-OOF (CR3) v2 D-OOF TI NODI=9 NODI=9 8/1/06 9/1/06 9/1/06 Total Iron- I-OFG (CR3) v2 ITotal Recoverable Copper - D-ooF (CR3) v2 f-OFG D-ooF _____ I. ... . . NODI=9

                                                                                                                                                               -oD,29 8/1/06                                                                                                                                            NODI=9 8/1/06          9/1/06  Total Recoverable Iron -D-OOF (CR3) v2      I  D-OOF                          t1                                          NOD1=9 10/21/2009                                                                          Page 43

Crystal River #ear DMR Data Permit No. FL00000159 I> 'Outa NODI-M X NODI-Min 'Be~gin date~ End Dateý JPARA'1ETER~'NAMV E *** Outall !. , *Cl ... CM-Avg*, Ma,, 8/1/06 9/1/06 Total Residual Ox 1-D013 (CR3) v2 - 1-D013 NODI=9 NODI=9 8/1/06 9/1/06 TSS - CO and ECST D-OOF (CR3) v2 NODJ=B 8/1/06 9/1/06 I-TSS-

                                -FE (CR3) v2                                 I-OFE                                                                  NODI=C      NODI=C 8/1/06         9/1/06   TSS - I-OFG (CR3) v2                              i-OFG            9. 01                     10.3 8/1/06         9/1/06  ITSS P-D-OOF (CR3) v2                         -   P-D-OOF                                                                  NODI=9      NODI=9 Q-D-OOF                                                                  NODI=9      NOD 1=9 8/1/06 8/1/06 9/1/06 9/1/06 TSS Q-D-OOF (CR3) v2 Turbidity - Background - D-OOF (CR3) v2 SD-OOF 1 D-00F                                     ___7_

1,~ NODI=9 8/1/06 9/1/06 Turbidity - Calc Limit - D-OOF (CR3) v2 NODI=9

NODI=9 NODI=9 8/1/06 9/1/06 Turbidity - Difference D-OOF (CR3) v2 D-00F 8/1/06 9/1/06 Turbidity - Effluent D-OOF (CR3) v2 D-OOF 9/1/06 10/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3 P-D-OOF >100

3) Q-D-OOF 9/1/06 10/1/06 96-Hour Menidia Beryllina Q-D-OOF (CR3 NODI=9 9/1/06 10/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3 )v2 P-D-OOF _ >100 9/1/06 10/1/06 96-Hour Mysidopsis Bahia Q-D-OOF (CR3 Q-D-OOF i NODI=9 9/1/06 10/1/06 Flow - I-OFE (CR3) v2 I-OFE _____0.000043 0.000043 9/1/06 10/1/06 I-OFG 0.002636 0.01266 Flow - I-OFG (CR3) v2 9/1/06 10/1/06 Flow-CD System D-OOF (CR3) v2 D-OOF 0 9/1/06 10/1/06 Flow-ECST D-OOF (CR3) v2 D-OOF 0.001974 0.00505 9/1/06 F10/1/06 Flow-Intake - D-OOF (CR3) v2 D-OOF 17.78 34.27 9/1/06 10/1/06 Hydrazine 1-D-O0F (CR3) v2 1-D-OOF0 !iF NODI=9 9/1/06 10/1/06 Hydrazine P-D-OOF (CR3) v2 P-D-OOF I- NODI=9 9/1/06 10/1/06 Hydroquinone 1-D-OF (CR3) v2 1-D-0OF

                                                                                                     '7i                                            NODI=9 9/1/06        10/1/06  Hydroquinone P-D-OOF (CR3) v2                    P-D-OOF                                                                  NODI=9 9/1/06        10/1/06  Morpholine 1-D-OOF (CR3) v2                      1-D-OOF          38.

1 9/1/06 10/1/06 Morpholine P-D-OOF (CR3) v2 NODI=9 1 i...... . l; T-,~ -- 9/1/06 10/1/06 Number of Batches - I-OFE (CR3) v2 1 9/1/06 10/1/06 Oil and Grease - D-O0F (CR3) v2 D-OOF NODI=9 9/1/06 10/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE 3 3.87 9/1/06 10/1/06 Oil and Grease - I-OFG (CR3) v2 l-OFG 1.7'9 2.43 9/1/06 10/1/06 pH - Background - D-OOF (CR3) v2 ,- D-OOF 7 8.06 8.22 9/1/06 10/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.12 8.26 9/1/06 10/1/06 pH - I-OFE (CR3) v2 I-OFE 7.13 7.13 9/1/06 10/1/06 pH - I-OFG (CR3) v2 I-OFG 8.36 8.73 1 - 1 9/1/06 10/1/06 Residual Ox -Time of Discharge D01 .3 (CR3) D013 0 9/1/06 10/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 10/21/2009 Page 44

Crystal River *ear DMR Data .Begin.ct El Date , PARAM utall _ETERNAME 9/1/06 10/1/06 .Temp Rise - D013 (CR3) v2 D013 8.9 12.7 9/1/06 10/1/06 Temp-Discharge - D013 (CR3) v2 D013 95.4 __ 9/1/06 10/1/06 Temp-Intake - D013 (CR3) v2 D013 86.7 9/1/06 10/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NO0=9 9/1/06 10/1/06 ITotal Ammonia P-D-00F (CR3) v2 P-D-OOF NODI=9 9/1/06 10/1/06 Total Copper - DOOF (CR3) v2 DOOF NODI=9 9/1/06 10/1/06 jTotal Copper - I-OFG (CR3) v2 I-OFG NODI=9 9/1/06 10/1/06 Total Iron- D-OOF (CR3) v2 D-OOF NODI=9 NODI=9

                                                                                                                                                  - - . ... - .. . . . . . r- -

9/1/06k 10/1/06 Total Iron- I-OFG (CR3) v2 I-OFG NODI=9 9/1/06 10/1/06 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 9/1/06 10/1/06 Total Recoverable Iron - D-O0F (CR3) v2 i D-OOF NODI=9 .. NODI=9 11.3_______ ___ NODI=9 I NODI=9 9/1/06 10/1/06 Total Residual Ox 1-D013 (CR3)v2 1-D013 9/1/06 10/1/06 TSS - CD and ECST D-OOF (CR3) v2 D-OOF NODI=B NO)DI=B

                                                                                                                                   -I--

9/1/06 10/1/06 [TSS - I-OFE (CR3) v2 -OFE 11.3 9/1/06 10/1/06 -TSS - I-OFG (CR3) v2 I-OFG 15.53 35.2 9/1/06 10/1/06 JTSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 9/1/06 1 10/1/06 ITSS Q-D-OOF (CR3)v2 QI C-D-OOF NODI=9 NODI=9 9/1/06 " 10/1/06 Turbidity - Background - D-OOF (CR3) v2 D-OOF NI00=9 9/1/06 10/1/06 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF N NODI=9 9/1/06 10/1/06 Turbidity - Difference D-OOF (CR3) v2 D-O0F I _ NODI=9 0 9/1/06 _10/1/06 Turbidity - Effluent D-0OF (CR3) v2 D-OOF NODI=9 10/1/06 j 11/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3) I P-D-[0F NODI=9 10/1/06 11/1/06 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF -0 NODI=9 10/1/06 1 11/1/06 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF T N001=9 10/1/06 11/1/06 96-Hour Mysidopsis Bahia QL-D-00F (CR3) Q-D-OOF NODI=9 10/1/06 11/1/06 1Flow - I-OFE (CR3) v2 I-OFE 0 10/1/06 11/1/06 Flow - I-OFG (CR3) v2 I-OFG 0.07594 0.0 11608 10/1/06 11/1/06 [Flow-CD System D-O0F (CR3) v2 D-00 F 0 - SD-OOF 10/1/06 11/1/06 1Flow-ECST D-OOF (CR3) v2 0.0009645 0.015034 10/1/06 11/1/06 lFlow-lntake - D-OF (CR3) v2 D-OOF 15.59 I . 52 10/1/06 L 11/1/06 lHydrazine -D-OOF (CR3) v2 1-D-OOF NODI=9 10/1/06 11/1/06 1Hydrazine P-D-OOF (CR3) v2 P-D-OOF NODI=9 10/1/06 11/1/06 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI-=9 10/1/06 11/1/06 jHydroquinone P-D-OOF (CR3)v2 P-D-OOF NODI=9 1 10/1/06 11/1/06 jMorpholine 1-D-OOF (CR3) v2 1-D-OOF -~28.4 10/21/2009 Page 45

Crystal River ear DMR Data Permit No. FL00000159 Begin da te ki1dýDatel 'ý' PARAMETER -NA'ME Outair C-M C-M

                                                                                                                     ' a.      AY 9 Ci Max     N6 Diý
                                                                                                                                                    ý;A vg,      -Max       N.ODI-Mi, NODI=9 I

10/1/06 11/1/06 Morpholine P-D-OOF (CR3) v2 JP-D-OOF 10/1/06 11/1/06 Number of Batches - I-OFE (CR3) v2 I-0FE I__ o0 0 10/1/06 11/1/06 Oil and Grease - D-OOF (CR3) v2 *NODI=9 ___D-OOF~ 10/1/06 11/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE NODI=C NODI=C i 4.87 - 10/1/06 11/1/06 ]Oil and Grease - I-OFG (CR3) v2 I-OFG 2.35 10/1/06 11/1/06 pH - Background - D-OOF (CR3) v2 D-00F 7.99 8.07 10/1/06 11/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.05 8.15 10/1/06 11/1/06 pH - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 10/1/06 11/1/06 pH - I-OFG (CR3) v2 Q1 I-OFG 8.1 8.79 10/1/06 11/1/06 Residual Ox - Time of Discharge D013 (CR3) D013 - 0 DOOF 10/1/06 11/1/06 Spectrus CT1300 - DOOF (CR3) v2 2.3 10/1/06 11/1/06 Temp Rise - D013 (CR3) v2 D013 14.4 16.4 I 10/1/06 11/1/06 Temp-Discharge - D013 (CR3) v2 D013 90.1 95.7 10/1/06 11/1/06 Temp-Intake - D013 (CR3) v2 D013 75.8 82.9 10/1/06 11/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF INODI=9 10/1/06 11/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 10/1/06 11/1/06 -Total Copper - DOOF (CR3) v2 DOOF NODI= 9 10/1/06 11/1/06 Total Copper - I-OFG (CR3) v2 I-OFG NODI=9 10/1/06 11/1/06 Total Iron- D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 10/1/06 11/1/06 Total Iron- I-OFG (CR3) v2 I-OFG NODI=9 10/1/06 11/1/06 ITotal Recoverable Copper - D-00F (CR3) Q 0-OOF 0-00 F INODI=9 NODI=9 10/1/06 11/1/06 Total Recoverable Iron - D-O0F (CR3) v2 D-OOF NODk=9 N001=9 10/1/06 11/1/06 Total Residual Ox 1-D013 (CR3) v2 1-D013 NO 01=9 NODI=9 10/1/06 11/1/06 TSS - CD and ECST D-OOF (CR3) v2 D-OOF NODI=B NODI=B 10/1/06 11/1/06 TSS - I-OFE (CR3) v2 I-OFE NODI=CI NODI=C 10/1/06 11/1/06 TSS - I-OFG (CR3) v2 I-OFG 26.6 __ I 471.6 10/1/06 11/1/06 TSS P-D-OOF (CR3) v2 P-D-OOF INODI=9 NODI=9 10/1/06 11/1/06 TSS Q-D-OOF (CR3) v2 Q-D-OOF --- -- NODI=9 NOD/=9 10/1/06 11/1/06 Turbidity - Background - D-O0F (CR3) v2 D-OOF L_____________ t NODI=9 10/1/06 11/1/06 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF NOD1=9 10/1/06 11/1/06 Turbidity - Difference D-OOF (CR3) v2 D-OOF NODI=9 10/1/06 11/1/06 11/1/06 Turbidity - Effluent D-OOF (CR3) v2 D-OOF Ii 7. NOD 1=9 12/1/06 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-00F >100 11/1/06 12/1/06 196-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-00F NODI=9 11/1/06 12/1/06 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF 10/21/2009 Page 46

CrystaI River Arear DMR Data Permit No. FL00000159 "Min ax -I'NODI AV i,ýNODI-Max 1,,N0IDlWin -6 gi n dat, End Date I ,z PARAMETER -NAME - 'ý , ý, -I:,,": 6tifl C-Av 9 11/1/06 f 12/1/06 96-Hour Mysidopsis Bahia Q-D-00F (CR3) Q-D-OOF III i NODI=9 11/1/06 12/1/06 Flow - -OFE (CR3) v2 I-OFE 0 11/1/06 12/1/06 Flow - I-0FG (CR3) v2 I-OFG 0.009116 0.074674 11/1/06 12/1/06 Flow-CD System D-OOF (CR3) v2 D-OOF 0 0 11/1/06 12/1/06 Flow-ECST D-OOF (CR3) v2 0.001956 0.014967 D-600 11/1/06 12/1/06 Flow-Intake - D-OOF (CR3) v2 16.44 20.44 11/1/06 [ 12/1/06 lHydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 11/1/06 12/1/06 Hydrazine P-D-OOF (CR3) v2 P-D-00F~ NODI=9 11/1/06 12/1/06 lHydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI=9 11/1/06 12/1/06 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 37.12 -- Hi-11/1/06 1 2/1/06 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 11/1/06 f 12/1/06 Morpholine P-D-OOF (CR3) v2 NODI=9 11/1/06 12/1/06 INumber of Batches - I-OFE (CR3) v2 I-OFE 0 0 11/1/06 12/1/06 Oil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 11/1/06 12/1/06 Oil and Grease - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 11/1/06 12/1/06 oil and Grease** I-OFG (CR3)v2 I-OFG 1.15 1.38 11/1/06 12/1/06 pH - Background - D-OOF (CR3) v2 D-OOF 8.04 8.15 11/1/06 12/1/06 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.06 8.19 11/1/06 12/1/06 pH - I-OFE (CR3) v2 I-0FE NODI=C NODI=C 11/1/06 12/1/06 - I-OFG (CR3) v2 I-OFG 8.38 8.96 11/1/06 12/1/06 Residual Ox -Time of Discharge D013 (CR3) D013 11/1/06 12/1/06 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 It 11/1/06 12/1/06 Temp Rise - D013 (CR3) v2 D013 15.7 17.6 11/1/06 12/1/06 Temp-Discharge - D013 (CR3) v2 D013 80.8 88.5 11/1/06 12/1/06 Temp-Intake - D013 (CR3) v2 D013 65.1 82.9 11/1/06 12/1/06 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF INODI=9 11/1/06 12/1/06 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF N001=9 11/1/06 12/1/06 Total Copper - DOOF (CR3) v2 DOOF NO0=9 11/1/06 12/1/06 Total Copper - I-OFG (CR3) v2 I-OFG NODI=9 11/1/06 12/1/06 Total Iron- D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 11/1/06 12/1/06 Total Iron- I-OFG (CR3) v2 NODI=9 I-OFG 11/1/06 12/1/06 jTotal Recoverable Copper - D-OOF (CR3) v2 D-OOF NODI=9 11/1/06 12/1/06 ITotal Recoverable Iron - D-OOF (CFR3) v2 D-OOF NODI=9 NOD1=9 11/1/06 12/1/06 1-D013 NODI=9 NODI=9 _- T JTotal Residual Ox 1-0013_(CR3) v2 11/1/06 12/1/06 TSS - CD and ECST D-OOF (CR3) v2 D-00F 1.32 NODI=B 10/21/2009 Page 47

Crystal River Alear DMR Data Permit No. FL00000159 .Begiridate End Date PARAMETER-N'AME J OL/tall CAv.g C<in C-Max X ~ ~ -a

A________________ý,', . Nb- OIMx NbDI-Min: NODI=C NODI=C I 11/1/06 12/1/06 TSS - -OFE (CR3) v2 I-OFE 11/1/06 12/1/06 TSS - I-OFG (CR3) v2 I-OFG 24.15 34.2 11/1/06 12/1/06 TSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NOD1=9 Q-D-OOF i NOD1=9 NODI=9 11/1/06 12/1/06 TSS Q-D-OOF (CR3) v2 Background - D-OOF (CR3) v2 D-OOF NOD1=9 11/1/06 12/1/06 Turbidity - 11/1/06 12/1/06 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF I NODI=9 12/1/06 Turbidity - Difference D-OOF (CR3) v2 D-OOF NODI=9 11/1/06 11/1/06 12/1/06 Turbidity - Effluent D-OOF (CR3)v2 96-Hour Menidia Beryllina P-D-OOF (CR3) D-OOF { P-D-O0F F _-T T- NODI=9 NODI=9 12/1/06 1/1/07 I 1/1/07 96-Hour Menidia Beryllina O.-D-OOF (CR3) 1 Q-D-OOF NODI=9 12/1/06 12/1/06 1/1/07 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 1 P-D-OOF I ND01=9 12/1/06 1/1/07 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF _ i NOD1=9 12/1/06 1/1/07 Flow-I-OFE (CR3) v2 j I-0FE 0.000045 0.001404 12/1/06 1/1/07 Flow - I-OFG (CR3)V2 I-OFG 0.010111 0.082106 12/1/06 1/1/07 Flow-CD System D-OOF (CR3)v2 Q D-OF 0 o0 i 12/1/06 1/1/07 Flow-ECST D-OOF (CR3) v2 D-OOF 0.001926 0.007633 12/1/06 1/1/07 Flow-Intake - D-OOF (CR3) v2 D-OOF 17.32 34.27 I 12/1/06 1/1/07 Hydrazine 1-D-OOF (CR3) v2 1-D-0OF i NODI=9 12/1/06 1/1/07 Hydrazine P-D-OOF (CR3) v2 P-D-OOF I NODI=9 12/1/06 12/1/06 1/1/07 1/1/07 Hydroquinone 1-D-OOF (CR3) v2 Hydroquinone P-D-OOF (CR3) v2 1-D-OOF P-D-OOF

                                                                                                                                           !        i NOD/=9 NOD,:9 12/1/06          1/1/07   Morpholine 1-D-OOF (CR3) v2                   1-D-OOF           27.3 12/1/06          1/1/07   Morpholine P-D-OOF (CR3) v2                   P-D-OOF                                                       1   -I-NODI=9 12/1/06          1/1/07   Number of Batches - I-OFE (CR3) v2               I-OFE                                           ___. . ..k __1 _ _.. .... ..

12/1/06 1/1/07 Oil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 12/1/06 1/1/07 Oil and Grease - I-OFE (CR3) v2 I-OFE 0.12 0.12 12/1/06 1/1/07 Oil and Grease - I-OFG (CR3) v2 I-OFG 2.39 2.88 12/1/06 1/1/07 pH - Background - D-OOF (CR3) v2 D-OOF -____ 7.99 8.24 12/1/06 1/1/07 pH - Effluent - D-OOF (CR3) v2 D-OOF t 8.05 8.15 12/1/06 1/1/07 pH - I-OFE (CR3) v2 I-OFE I_ 6.62 . 6.62 12/1/06 1/1/07 pH - I-OFG (CR3) v2 t-0FG 8.63 8.91 12/1/06 1/1/07 Residual Ox - Time of Discharge D013 (CR3)1 D013 12/1/06 1/1/07 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 12/1/06 1/1/07 Temp Rise - D013 (CR3) v2 D013 16.2 17.3 12/1/06 } 1/1/07 {Temp-Discharge - D013 (CR3) v2 D013 79.3 85.7 10/21/2009 Page 48

C Crystal River NAear DMR Data Permit No. FL00000159 En ate .-- ~ PARAMETER NAM Outal

                                                                        ýý.

Begin d,ate I a,ý C C-A i i l -MmfnT*

                                                                                                            ,,.. Min C-
                                                                                                                     .1 I

C-(:.Max ;;-

                                                                                                                               -Ma Q-Avg j    <Q-Max
                                                                                                                                                                        -cNODI-Avg NODI-Max i.NODI-Min 12/1/06         1/1/07     Temp-Intake - D013 (CR3) v2                     D013            63.1 12/1/06         1/1/07     Total Ammonia 1-D-OOF (CR3) v2                1-D-OOF      I                                                                                        NODI=9 F

12/1/06 1/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-00F - N001=9 12/1/06 1/1/07 Total Copper - DOOF (CR3) v2 DOOF NODI=9 12/1/06 1/1/07 Total Copper- I-OFG (CR3) v2 I-OFG NODI=9 12/1/06 1/1/07 Total Iron- D-OOF (CR3) v2 D-OOF N001=9 N001=9 12/1/06 1/1/07 Total Iron- I-OFG (CR3) v2 I-OFG NOD1=9 12/1/06 1/1/07 Total Recoverable Copper - D-OOF (CR3) v2 D-00F II NODI=9 NOD1=9 12/1/06 1/1/07 Total Recoverable Iron - D-ODF (CR3) v2 D-00F ! NODI=9 NODI=9 12/1/06 1/1/07 Total Residual Ox 1-D013 (CR3) v2 1-DO13 NODI=9__I NODI=9 12/1/06 1/1/07 TSS - CD and ECST D-OOF (CR3) v2 D-OOF NODI=B NODI=B 12/1/06 1/1/07 TSS - I-OFE (CR3) v2 I-OFE NODI=B NODI=B 12/1/06 1/1/07 TSS - I-OFG (CR3) v2 I-OFG 25.1 32.6 12/1/06 1/1/07 TSS P-D-OOF (CR3) v2 P-D-O0F NODI=9 NODI=9 12/1/06 1/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9 12/1/06 1/1/07 Turbidity - Background - D-OOF (CR3) v2 D-OOF ______________I. NODI=9 12/1/06 1/1/07 ]Turbidity - Calc Limit - D-OOF (CR3) v2 D-00F - NOIDI=9 12/1/06 1/1/07 Turbidity - Difference D-OOF (CR3) v2 0-00 F NODI=9 D-00 F NODk9I 12/1/06 1/1/07 Turbidity - Effluent D-OOF (CR3) v2 1/1/07 2/1/07 96-Hour Menidia Beryllina P-D-OOF (CR3) >100 P-D-00

                                                                         -D-OOF F

1/1/07 2/1/07 96-Hour Menidia Beryllina Q-D-OOF (CR3) NO[ DI=9 _____r__ 00 1/1/07 2/1/07 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 1/1/07 2/1/07 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) NO[ Dl=9 I-OFE I 1/1/07 2/1/07 Flow - I-OFE (CR3) v2 0~ 0 I-0FG _I 1/1/07 2/1/07 Flow - I-OFG (CR3) v2 D-0OF - 0.012476 0.083365 1/1/07 2/1/07 Flow-CD System D-OOF (CR3) v2 0 1/1/07 2/1/07 Flow-ECST D-OOF (CR3) v2 P -D-OOF I .0.000965 0.007664

                                                                                                                                                         -v 1/1/07         2/1/07      Flow-Intake - D-OF (CR3) v2               '             H                                                     I_    16.82            29.52 1/1/07         2/1/07      Hydrazine 1-D-OOF (CR3) v2                   1-D-00F                                                                                               NODI=9 R-D-OOF 1/1/07         2/1/07      Hydrazine P-D-OOF (CR3) v2 D -OOF 1-D-OOF                                                                          I-                   NODI=9 1/1/07         2/1/07    [ Hydroquinone 1-D-OOF (CR3) v2                1-0 -00F                                                                                              NODI=9 1/1/07         2/1/07      Hydroquinone P-D-OOF (CR3) v2                P-D-OOF                                                                                                NOD1=9 1/1/07         2/1/07     i-Morpholine 1-D-OOF (CR3) v2                  1-DOOE7         27.24 1/1/07         2/1/07    iMorpholine P-D-OOF (CR3) v2                                                                                                                          NODI=9 1/1/07         2/1/07      Number of Batches - I-OFE (CR3) v2                                                                                       0 --i         0 10/21/2009                                                                              Page 49

Crystal River ear DMR Data Begin date End Date PARAMETERNAME Outall 1/1/07 2/1/07 Oil and Grease - D-OOF (CR3) v2 D-OOF 1/1/07 2/1/07 FOil and Grease - I-OFE (CR3) v2 I-OFE T 1/1/07 2/1/07 IOil and Grease - I-OFG (CR3) v2 I-OFG 1.1 3 1/1/07 2/1/07 pH - Background - D-OOF (CR3) v2 D-OOF 8.02 , 8.12 1/1/07 2/1/07 pH - Effluent - D-°°F (CR3) v2 D-00F 8.12 8.24 1/1/07 2/1/07 ]pH-l-OFE (CR3) v2 I-OFE NODI=C NODI=C 1/1/07 2/1/07 [pH - I-0FG (CR3) v2 I-OFG 8,52 8.96 1/1/07 2/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 0 1/1/07 2/1/07 Spectrus CT1300 - DOOF (CR3) v2 __DOOF 2.25 1/1/07 2/1/07 ITemp Rise - D013 (CR3) v2 D013 16.3 17.5 1/1/07 2/1/07 ITemp-Discharge - D013 (CR3) v2 D013 78.9 87.3 1/1/07 - 2/1/07 )Temp-lntake - D013 (CR3)v2 Q D013 62.7 70.5 1/1/07 2/1/07 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NODI=9 1/1/07 2/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 . 1/1/07 2/1/07 Total Copper - DOOF (CR3) v2 D00F NODI=9 1/1/07 2/1/07 Total Copper - I-0FG (CR3) v2 I-0FG NODI=9 1/1/07 2/1/07 iTotal Iron- D-DOF (CR3) v2 D-DOF NODI=9 NODI=9 1/1/07 2/1/07 Total Iron- I-OFG (CR3) v2 I-0FG NODI=9 1/1/07 2/1/07 Total Recoverable Copper - D-DOF (CR3) v2 0-ODF NODI=9 NODI=9 1/1/07 2/1/07 Total Recoverable Iron - D-DOF (CR3) v2 D-DOF NODI=9 NODI=9 1/1/07 2/1/07 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 i NODI=9 1/1/07 2/1/07 ITSS - CD and ECST D-ODF (CR3) v2 D-ODF NODI=B NODI=B 1/1/07 2/1/07 TSS - I-DFE (CR3) v2 I-DFE NODI=C -NODI=C 1/1/07 2/1/07 TSS - I-0FG (CR3) v2 I-0FG 12.97 23.7 1/1/07 2/1/07 ITSS P-D-O0F (CR3) v2 P-D-OOF N ODI=9 NODI=9 1/1/07 2/1/07 ITSS Q-D-OOF (CR3) v2 IQ-D'Ot N ODI=9 iNODI=9 1/1/07 2/1/07 [Turbidity - Background - D-DOF (CR3) v2 D-ODF NODI=9 1/1/07 2/1/07 _Turbidity - Calc Limit - D-OOF (CR3) v2 . D-DOF NODI=9 1/1/07 2/1/07 Turbidity - Difference D-DOF (CR3) v2 D-ODF NODI=9 1/1/07 2/1/07 -Turbidity - Effluent 0-OF (CR3) Q2 D0-OD NO 01=9 2/1/07 3/1/07 96-Hour Menidia Beryllina P-D-DOE (CR3) P-D-OOE NODI=9 2/1/07 3/1/07 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 2/1/07 3/1/07 96-Hour Mysi-dopsis Bahia P-D-OOF (CR3) v21 P-D-OOF NODI=9 2/1/07 3/1/07 96-Hour Mysidopsis Bahia Q-D-OO (CR3) IQ-D-OOF NOD1=9 2/1/07 3/1/07 Elow - l-OEE (CR3) v2 -OFE 0 0 10/21/2009 Page 50

Crystal River ear DMR Data Permit No. FL00000159 Begin date* fEnd DateI< ;PAR' E"T E'Ri NA M E V OutaIK iCA~.>~.CMg7 C-M; Avg': j Q-4'-: - Q-"axý NODII-Avg .NODI-Max I NODI-Min 2/1/07 3/1/07 Flow - I-OFG (CR3) v2 I-OFG 0.0164356 0.080137 2/1/07 3/1/07 Flow-CD System D-OOF (CR3) V2 D-OOF _ 0.0029857 0.0836 2/1/07 3/1/07 F*ow-ECST D-OOF (CR3) v2 D-OOF 0.00053557 0.007546 NO -F--=- 2/1/07 3/1/07 Flow-Intake - D-OOF (CR3) v2 D-OOF 16.27 29.52 2/1/07 3/1/07 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF

                                                                                                                                           ~1~ NOD1=9 2/1/07          3/1/07  IHydrazine P-D-OOF (CR3) v2                   P-D-OOF 2/1/07          3/1/07   Hydroquinone 1-D-OOF (CR3) v2                1-D-OOF                                                                   NODI=9                   --

2/1/07 3/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 2/1/07 3/1/07 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 42.4 2/1/07 3/1/07 Morpholine P-D-OOF (CR3) v2 P-D-OOF NOD1=9 2/1/07 3/1/07 Number of Batches- -OFE (CR3)v2 I-OFE _ 0 0 2/1/07 3/1/07 1Oil and Grease - D-OOF (CR3) v2 j D-OOF NODI=9 2/1/07 ! 3/1/07 Oil and Grease - I-OFE (CR3) v2 I-OFE I _I NODI=C NODI=C 2/1/07 3/1/07 Oil and Grease - I-OFG (CR3) v2 I-OFG 1.72 3.36 2/1/07 3/1/07 pH - Background - D-OOF (CR3) v2 D-OOF 8.02 8.19 2/1/07 3/1/07 pH - Effluent - D-OOF (CR3)v2 Q D-OOF 8 8.19 2/1/07 3/1/07 pH - -OFE (CR3)v2 I-OFE I NODI=C NODI=C 2/1/07 3/1/07 pH - I-OFG (CR3) v2 I-OFG 1 8.5 8.95 2/1/07 3/1/07 Residual Ox - Time of Discharge D013 (CR3)1 D013 0

                                                                                                                                           -I-2/1/07     -    3/1/07  Spectrus CT1300 - DOOF (CR3) v2                DOOF                                     2.3 3/1/07  Temp Rise - D013 (CR3) v2                      D013            15.6 2/1/07                                                                                                         17.8 2/1/07          3/1/07 ITemp-Discharge - D013 (CR3) v2                 D013            74.6      ,             83.6 2/1/07          3/1/07 ITemp-Intake - D013 (CR3) v2                    D013             59                     70.5 2/1/07          3/1/07 ITotal Ammonia 1-D-OOF (CR3) v2               1-D-OOF                                                                   NO 01=9 2/1/07     1    3/1/07  _Total Ammonia P-D-OOF (CR3) v2              P-D-OOF                                                                   NO 01=9
                                                                                                                                                                       -I   -

2/1/07 3/1/07 Total Copper - DOOF (CR3) v DOOF NO 01=9 2/1/07 3/1/07 Total Copper - I-OFG (CR3) v2 I-OFG I NODI=9 2/1/07 3/1/07 iTotal Iron- D-O0F (CR3) v2 D-OOF NOD1=9 NODI=9 2/1/07 3/1/07 ýTotal Iron- I-OFG (CR3)v2 I-OFG NODI=9 2/1/07 3/1/07 'Total Recoverable Copper - D-O0F (CR3) v2 D-OOF NOD1=9 NODI=9 2/1/07 3/1/07 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF NODI=9 NOD1=9 2/1/07 3/1/07 ITotal Residual Ox 1-D013 (CR3) v2 1-D013 - NODI=9 NOD1=9 2/1/07 3/1/07 TSS - CD and ECST D-O0F (CR3) v2 D-OOF -T NOD1= B NODI=B 2/1/07 3/1/07 ITSS-I-OFE (CR3)v2 I-OFE J NODI=C NODI=C 2/1/07 3/1/07 ITSS - I-OFG (CR3) v2 I-OFG 9.91 I 16.5 10/21/2009 Page 51

Crystal River I ear DMR Data Permit No. FL00000159

Begin dat COutall-Min NODI-Avg NODI-Max NODI-Min e En Dt PARAMETERNAME 2/1/07 3/1/07 ITSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 2/1/07 3/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9

                                                                                                      -I-2/1/07           3/1/07    Turbidity - Background - D-OOF (CR3) v2  Q         D-OOF                                                                        NODI=9 2/1/07           3/1/07   ITurbidity - Calc Limit - D-OOF (CR3) v2            D-OOF                                                                        NOD1=9 2/1/07           3/1/07    Turbidity - Difference D-OOF (CR3) v2              D-OOF                 T                                                      NODI=9 2/1/07           3/1/07    Turbidity - Effluent D-OOF (CR3) v2                D-OOF                                                                        NODI=9 3/1/07         _14/1/07    96-Hour Menidia Beryllina P-D-OOF (CR3)           P-D-OOF                                                                                 >100 4/1/07               Menidia Beryllina 196-Hour Mysidopsis             Q-D-OOF (CR3)      Q-D-OOF                                                                                NODI=9 4/1/07                            Bahia P-D-OOF (CR3)v2796-Hour 3/1/07 4/1/07   196-Hour Mysidopsis Bahia Q-D-OOF (CR3)            P-D-OOF                                                                                 >100 3/1/07 3/1/07           4/1/07    Flow   - -aFE(CR3) v2                          I  Q-D-OOF                                                                                NOD1=9 3/1/07           4/1/07    Flow - I-OFG (CR3) v2                               I-OFE                                     0.00004526 0.001403 3/1/07                                                                         I-OFG                                      0.0140278 0.077695
                 -4/1/07     Flow-CD System D-OOF (CR3) v2                      D-OOF                                                     0 3/1/07 4/1/07    Flow-ECST D-OOF (CR3) v2                           D-OOF                                       0.003832  0.014967 3/1/07 4/1/07    Flow-Intake - D-OOF (CR3) v2                       D-OOF                                        19.1607   34.272 3/1/07 4/1/07    Hydrazine 1-0-OOF (CR3) Q                         1-D-OOF                                                            NODI=9 3/1/07 4/1/07 - jHydrazineP-D-OOF (CR3) v2                         P-D-OOF NOD1=9...

3/1/07 S 4/107 4/1/07 yrqunn jHydroquinone _ _--OCR)2i 1-D-OOF (CR3) v2 1-D-00F NODI=9 3/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 3/1/07 4/1/07 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 29.4 3/1/07 4/1/07 I-M-orpholine P-D-OOF (CR3) v2 P-D-OOF NO0.=9 3/1/07 4/1/07 ýNumber of Batches - I-OFE (CR3) v2 I-OFE 1 1 3/1/07 4/1/07 ýOil and Grease - D-OOF (CR3) v2 NODI=9 3/1/07 3/1/07 4/1/07 ýOil and Grease - I-OFE (CR3) v2 I-OFE 0.50 0.50 3/1/07 4/1/07 Oil and Grease - I-OFG (CR3) v2 I-OFG 2.02 5.12 3/1/07 t 4/1/07 pH - Background - D-OOF (CR3) v2 D-OOF 7.9 8.22 3/1/07 4/1/07 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.05 8.19 3/1/07 4/1/07 pH - -OFE (CR3) v2 I-OFE 6.11 6.11 3/1/07 4/1/07 pH - '-OFG (CR3) v2 I-OFG 8.45 8.98 3/1/07 4/1/07 [Residual Ox -Time of Discharge D013 (CR3) 0013 0 3/1/07 4/1/07 !Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 3/1/07 4/1/07 Temp Rise- D013 (CR3) v2 D013 15.7 18.3 3/1/07 4/1/07 .Temp-Discharge - D013 (CR3) v2 D013 83.7 90.8 3/1/07 4/1/07 ITemp-Intake - D013 (CR3) v2 D013 68.1 73.8 3/1/07 4/1/07 rTotal Ammonia 1-D-OOF (CR3) v2 1-D-OOF I NODI=9 10/21/2009 Page 52

Crystal River Dlear DMR Data Permit No. FL00000159 Begin date End Date PARAMETER-NAME Outat C-Avg C-(Q-Max C-iiax Q vg I NODI-Max........n 3/1/07 4/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI= 3/1/07 4/1/07 ITotal Copper - DOOF (CR3) v2 DOOF Iýý 0ODI= 99 3/1/07 4/1/07 ýTotal Copper - I-OFG (CR3) v2 l-OFG j NODI=9 3/1/07 A/ /0-7 T,÷-I _ r) ICDO I,) D-OOF NODI=9 NODI=9 9't/ ./J-/U/ I .JLa IIU.II- L.-JU~J.I H%,-I\.J/ V* 3/1/07 4/1/07 Total Iron- I-OFG (CR3) v2 I-OFG NODI=9 4/1/07 ITotal Recoverable Copper - D-OOF (CR3) v2 3/1/07 4/1/07 ýTotal Recoverable Iron - D-OOF (CR3) v2 - D-OOF NODI=9 NODI=9 3/1/07 D-OOF I- NODI=9 I NODI=9 3/1/07 4/1/07 [Total Residual Ox 1-D013 (CR3) v2 1-D013 NO-i=9 NODI=9 3/1/07 4/1/07 ITSS - CD and ECST D-OOF (CR3) v2 D-OOF NODI=B NODI=B 3/1/07 4/1/07 TSS - -OFE (CR3) v2 I-OFE 9.20 9.20 3/1/07 4/1/07 ýTSS - I-OFG (CR3) v2 I-OFG 12.72 23.8 3/1/07 4/1/07 ITSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NOD1=9 3/1/07 4/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9 3/1/07 4/1/07 ýTurbidity - Background - D-OOF (CR3) v2 D-OOF NODI=9 3/1/07 4/1/07 'Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF NODI=9 3/1/07 4/1/07 Turbidity - Difference D-OOF (CR3) v2 D-OOF NO..=9 3/1/07 4/1/07 Turbidity - Effluent D-OOF (CR3) v2 NODI=9 4/1/07 1 5/1/017 196-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF NODI=9 4/1/07 5/1/07 196-Hour Menidia Beryllina Q-D-OOF (CR3)r Q-D-OOF NODI=9 4/1/07 5/1/07 196-Hour Mysidopsis Bahia P-D-00F (CR3) v21 P-D-OOF -1 NODI=9 4/1/07 5/1/07 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF 4/1/07 5/1/07 Flow - I-OFE (CR3) v2 I-OFE 0 0 4/1/07 5/1/07 Flow - l-OFG (CR3) v2 I-OFG I326 0.01785 0.07909 4/1/07 5/1/07 Flow-CD System D-OOF (CR3) v2 D-OOF 0 0 4/1/07 5/1/07 jFlow-ECST D-OOF (CR3) v2 D-OOF 0.000719 0.014154 4/1/07 5/1/07 Flow-Intake - D-O0F (CR3) v2 D-OOF 15.64 29.52 4/1/07 5/1/07 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 4/1/07 5/1/07 Hydrazine P-D-OOF (CR3) v2 P-D-OOF NODI=9 4/1/07 5/1/07 lHydroquinone 1-D-OOF (CR3) v2 1-D-0OF NODI=9 4/1/07 5/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 32.69 4/1/07 5/1/07 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 4/1/07 5/1/07 Morpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9 4/1/07 5/1/07 Number of Batches - I-OFE (CR3) v2 I-OFE 0 0 4/1/07 5/1/07 Oil and Grease - D-OOF (CR3) v2 D-OOF i NODI=9 4/1/07 5/1/07 Oil and Grease - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 10/21/2009 Page 53

Crystal River

ear DMR Data Permit No. FL00000159 Beginudate En Dat PARAMETER NAME . Outa*.* C-Avg D-'Avg J*D*in'*a N0Dl-'Max"1"NOD,*.N..I-Min 4/1/07 5/1/07 Oil and Grease - I-OFG (CR3) v2 I-OFG 3.47 9.37 4/1/07 5/1/07 pH - Background - D-OOF (CR3) v2 D-OOF 8.04 8.21 I _____

4/1/07 5/1/07 pH- Effluent - D-OOF (CR3) v2 - D-00F 8.08 8.15 4/1/07 5/1/07 pH - I-OFE (CR3) v2 I-OFE NODI=C NODI=C 4/1/07 5/1/07 pH - I-OFG (CR3) v2 I-OFG 8.56 8.97 4/1/07 5/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 0 I 4/1/07 5/1/07 iSpectrus CT1300 - DOOF (CR3) v2 DOOF 2.2 I 15.4 4/1/07 5/1/07 ITemp Rise - D013 (CR3) v2 D013 16.6 4/1/07 5/1/07 jTemp-Discharge - D013 (CR3) v2 D013 85.7 94.1 4/1/07 1 5/1/07 jTemp-Intake - D013 (CR3) v2 D013 70.4 77.5 4/1/07 5/1/07 ITotal Ammonia 1-D-OOF (CR3) v2 1-D-OOF N 001=9 4/1/07 5/1/07 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 4/1/07 5/1/07 Total Copper - DOOF (CR3) v2 DOOF NO0D1=9 4/1/07 5/1/07 ITotal Copper - I-OFG (CR3) v2 I-OFG NODI=9 NODI=9 NODI=9 4/1/07 5/1/07 ITotal Iron- D-OOF (CR3) v2 D-OOF 4/1/07 5/1/07 iTotal Iron- I-OFG (CR3) v2 I-OFG NODI=9 D-OOF 4/1/07 5/1/07 Total Recoverable Copper - D-OOF (CR3) v2 NODI=9 NOD 1=9 5/1/07 ITotal Recoverable Iron - D-OOF (CR3).v2 i NOD0I=9 4/1/07 D-00 F NODI=9 4/1/07 5/1/07 !Total Residual Ox 1-DO13 (CR3) v2 1-DO13 NODI=9 NODI=9 4/1/07 5/1/07 ITSS - CD and ECST D-OOF (CR3) v2 D-00F NODI=B NOD l=B 4/1/07 1 5/1/07 ITSS-l-OFE (CR3)v2 I-0FE NODI=C NOD l=C 4/1/07 f 5/1/07 ITSS - I-OFG (CR3) v2 I-OFG 24.34 57.4 4/1/07" 5/1/07 ITSS P-D-OOF (CR3) v2 P-D-OOF NOD1=9 NODI=9 4/1/07 5/1/07 ITSS Q-D-OOF (CR3) v2 Q-D-OOF D-OOF NODI=9 4/1/07 5/1/07 ITurbidity - Background - D-OOF (CR3) v2 D-00F 4/1/07 5/1/07 Turbidity - Calc Limit - D-OOF (CR3) v2 NODI=9 4/1/07 J 5/1/07 !Turbidity - Difference D-O0F (CR3)v2 Q D-00F NODI=9 4/1/07 5/1/07 ITurbidity - Effluent D-OOF (CR3) v2 NODI=9 5/1/07 -F-6/1/07 i96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF - 1 >100 5/1/07 { 6/1/07 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF IJ- NODI=9 5/1/07 6/1/07 ]96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF >100 I ', 5/1/07 _ 6/1/07 196-Hour Mysidopsis Bahia Q-D-00F (CR3) Q-D-00F NODI=9 5/1/07 6/1/07 Flow - I-OFE (CR3) v2 I-0FE 0.0000216 0.00067 5/1/07 6/1/07 Flow - I-OFG (CR3) v2 I-OFG 0.01460229 0.078441 5/1/07 . 6/1/07 Flow-CD System D-OOF (CR3) v2 D-OOF 0 0 10/21/2009 Page 54

Crystal River Dear DMR Data Permit No. FL00000159

Begin date*! End Date OutaI .

                                                                      ,PARAMETERNAME  C-Avg~      C.MiKn ,C-M'ax~      ,Q-AvgI     Q-Max      NODI-Avg   NODI-Max  INODI-Min 5/1/07     1    6/1/07   Flow-ECST D-OOF (CR3) v2                     D-OOF                                       0.00236965    0.014939 6/1/07   Flow-Intake - D-OOF (CR3) v2                 D-00F                                        15.90771      34.272 6/1/07   Hydrazine 1-D-00F (CR3)      v2      1-    1-D-00F                                                                  NODI=9 5/1/07 5/1/07          6/1/07   Hydrazine P-D-OOF (CR3) v2                 P-D-OOF                                                                  NODI=9 5/1/07          6/1/07   Hydroquinone 1-D-O0F (CR3) v2              1-D-OOF                                                                  NODI=9 6/1/07  *Hydroquinone P-D-OOF (CR3) v2              P-D-OOF                                                                  NODI=9 5/1/07                                                                                                                       K 5/1/07          6/1/07   Morpholine 1-D-OOF (CR3) v2                1-D-OOF          31.5 5/1/07          6/1/07   Morpholine P-D-OOF (CR3) v2                 P-D-OOF                                                                 NO D1=9 1

5/1/07 6/1/07 Number of Batches - I-OFE (CR3) v2 I-OFE 1 5/1/07 6/1/07 Oil and Grease - D-OOF (CR3) v2 D-OOF _1 NOD1=9 5/1/07 6/1/07 Oil and Grease - I-OFE (CR3) v2 I-OFE 0.75 0.75 5/1/07 6/1/07 JOil and Grease - I-OFG (CR3) v2 I-OFG 3 5/1/07 6/1/07 pH - Background - D-OOF (CR3) v2 D-OOF 7.98 8.17 5/1/07 6/1/07 pH - Effluent - D-OOF (CR3) v2 D-OOF ________ 8.04 8.35 5/1/07 6/1/07 pH - I-OFE (CR3) v2 Q I-OFE 6.341 6.34 5/1/07 6/1/07 pH - I-OFG (CR3) v2 I-OFG 8.6 8.91 5/1/07 6/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 0 5/1/07 6/1/07 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 _ 5/1/07 6/1/07 Temp Rise - D013 (CR3) v2 D013 12.7_ 16.1 5/1/07 6/1/07 Temp-Discharge - D013 (CR3) v2 D013 95.4 5/1/07 6/1/07 Temp-Intake - D013 (CR3) v2 0013 7 1 81.7 5/1/07 6/1/07 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF NODI=9 5/1/07 6/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 5/1/07 6/1/07 Total Copper - DOOF (CR3) v2 DOOF 1-NODI=9 5/1/07 6/1/07 Total Copper - I-OFG (CR3) v2 I-OFG NOD '1=9 5/1/07 6/1/07 Total Iron- D-OOF (CR3) v2 D-00F NOD1=9 NOD 1=9 5/1/07 6/1/07 Total Iron- I-OFG (CR3) v2 I-OFG NOD 1=9 5/1/07 6/1/07 Total Recoverable Copper - D-OOF (CR3) v2 F NODI=9 Total Recoverable Iron - D-OOF (CR3) v2 -i 5/1/07 6/1/07 D-O0F NOD 1=9 NODI=9 5/1/07 6/1/07 Total Residual Ox 1-D013 (CR3) v2 1-DO13 NODI=9 NODI=9I 5/1/07 6/1/07 TSS - CD and ECST D-OOF (CR3) v2 D-00F 0.! -- i NODI=B ' \JODI=B 5/1/07 6/1/07 TSS- I-OFE (CR3) v2 I-OFE 0.3 3-7 5/1/07 6/1/07 TSS - I-OFG (CR3) v2 I-OFG 10.37 28. 4 5/1/07 6/1/07 TSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NO00l=9 5/1/07 6/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 'NODI=9 10/21/2009 Page 55

0 Crystal River Dear DMR Data 0 Permit No. FL00000159 Be t.ria6te7L I'Rt<IVIL INMIIMa OutaIP. Outal, C-A C7hdt -Av Q-Max I NODI-Avg NODI-MxI 2 NODI-Mm Min* NODI=9 5/1/07 6/1/07 ITurbidity - Background - D-O0F (CR3) v2 D-0OF I _ iTurbidity - Calc Limit - D-OOF (CR3) v2 D-0OF NODI=9 5/1/07 6/1/07 4-Turbidity - Difference D-O0F (CR3) v2 D-OOF -Fi NODI=9 5/1/07 6/1/07 D-00F NODI=9 5/1/07 6/1/07 Turbidity - Effluent D-O0F (CR3) v2 96-Hour Menidia Beryllina P-D-00F (CR3) P-D-OOF NODI=9 6/1/07 7/1/07 196-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 6/1/07 7/1/07 7/1/07 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF NODI=9 6/1/07 7/1/07 /96-Hour Mysidopsis Bahia Q-D-OOF (CR3) I Q-D-00F NODI=9 6/1/07 6/1/07 7/1/07 Flow - I-0FE (CR3) v2 I-OFE 0.000046 0.00139 6/1/07 7/1/07 Flow - I-OFG (CR3) v2 I-OFG 0.020854 0.09248 1 6/1/07 7/1/07 Flow-CD System D-OOF (CR3) v2 D-0OF -I 0 0 6/1/07 7/1/07 Flow-ECST D-O0F (CR3) v2 D-0OF 0.002039 0.015295 6/1/07 7/1/07 ]Flow-Intake - D-O0F (CR3) v2 D-0OF 15 .9388 29.S2 6/1/07 7/1/07 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 6/1/07 7/1/07 Hydrazine P-D-OOF (CR3) v2 P-D-00F NODI=9 6/1/07 7/1/07 Hydroquinone 1-D-OOF (CR3) v2 1-D-0OF NODI=9 6/1/07 7/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NO 01=9 6/1/07 7/1/07 Morpholine 1-D-O0F (CR3) v2 1-0DOOF 29.61 1 6/1/07 7/1/07 IMorpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9 1 6/1/07 7/1/07 Number of Batches - I-OFE (CR3) v2 I-OFE i 6/1/07 7/1/07 Oil and Grease - D-O0F (CR3) v2 D-OOF NODI=9 i 2.12 6/1/07 7/1/07 Oil and Grease - I-OFE (CR3) v2 I-OFE 2.12 6/1/07 7/1/07 Oil and Grease -I-FG (CR3) v2 I-0FG 2.08 4.25 6/1/07 7/1/07 /pH - Background OF (CR3) v2 0-OoF 8.01 8.38 I _ 6/1/07 T 7/1/07 pHN-Effluent - D-OOF (CR3) v2 D-00F

                                                                                               -It 8.01     8.33 6/1/07          7/107      pH  - I-OFE (CR3) v2                           I-OFE                     6.65 1   6.65 6/1/07    -     7/1/07     pH - I-OFG (CR3) v2                            I-OFG

[ 8.48 8.92 6/1/07 7/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 0 6/1/07 7/1/07 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.35 v2 9.7 6/1/07 7/1/07 Temp Rise - 0013 (CR3) D013 9.7 13.9 92.5 6/1/07 7/1/07 ITemp-Discharge - D013 (CR3) v2 I D013 92.5 82.8 87.4 6/1/07 7/1/07 FTemp-Intake - D013 (CR3) v2 v D013 82.8 6/1/07 7/1/07 Total Ammonia 1-D-O0F (CR3) v2 1-D-00F NODI=9 6/1/07 7/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 6/1/07 7/1/07 FTotal Copper - DOOF (CR3)v2 Q DOOF NODI=9 NODI=9 L 10/21/2009 Page 56

Crystal River S ear DMR Data Permit No. FL00000159 0 ~Begin dae EdDt AAMTRNM ual C.Avg< . ~C-Min ~ C-Mac Q-v -a OIAg ~NODI-,Max ND-i 6/1/07 7/1/07 Total Copper - I-OFG (CR3) v2 I-OFG NODI=9 6/1/07 7/1/07 Total Iron- D-OOF (CR3) v2 D-OOF F NODI=9 NODI=9 6/1/07 7/1/07 Total Iron- I-OFG (CR3) v2 I-OFG NODI=9 r-- 6/1/07 7/1/07 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF - NODI=9 NODI=9 6/1/07 7/1/07 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF NODI=9 6/1/07 7/1/07 'Total Residual Ox 1-D013 (CR3) v2 1-DO13 _ NODI=9 NODI=B 6/1/07 7/1/07 TSS - CD and ECST D-OOF (CR3) v2 D-OOF NOD l=B 6/1/07 7/1/07 TSS - I-OFE (CR3) v2 Q I-OFE 1.9 1.9 6/1/07 7/1/07 TSS - I-OFG (CR3) v2 I-OFG 12.75 27.8 6/1/07 7/1/07 ITSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 6/1/07 7/1/07 ITSS Q-D-OOF (CR3) v2 Q-D-OOF NODI-9 NODI=9 6/1/07 7/1/07 iTurbidity - Background - D-OOF (CR3) v2 D-OOF NODI=9 6/1/07 7/1/07 ýTurbidity - Calc Limit - D-OOF (CR3) v2 D-OOF NOD1=9 6/1/07 7/1/07 Turbidity - Difference D-OOF (CR3) v2 D-00F NOD1=9 6/1/07 7/1/07 Turbidity - Effluent D-OOF (CR3) v2 D-00F NO 01=9 7/1/07 8/1/07 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100 7/1/07 8/1/07 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NOD1=9 7/1/07 -8/1/07 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 1 P-D-OOF >100 7/1/07 8/1/07 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NO 01=9 7/1/07 8/1/07 Flow - I-OFE (CR3) v2 I-0FE 0.0000464 0.00 1438 7/1/07 8/1/07 Flow - l-OFG (CR3) 2 l-OFG 0.0166295 0.079225 7/1/07 8/1/07 Flow-CD System D-OOF (CR3) v2 D-OOF 0 0 7/1/07 8/1/07 Flow-ECST D-OOF (CR3) v2 D-00F 0.003447 0.01S286 7/1/07 8/1/07 Flow-Intake - D-OOF (CR3) v2 D-O 14.886 29.52 7/1/07 8/1/07 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF NODI=9 7/1/07 8/1/07 Hydrazine P-D-OOF (CR3) v2 P-D-OOF . 1. . } NODI=9 7/1/07 8/1/07 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI=9 7/1/07 8/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF 1. . NODI=9 7/1/07 8/1/07 [Morpholine 1-D-OOF (CR3) v2 1-D-OOF 16.567 7/1/07 8/1/07 Morpholine P-D-OOF (CR3) v2 P-D-OOF NOD 1=9 7/1/07 8/1/07 Number of Batches - I-OFE (CR3) v2 I-OFE 7/1/07 8/1/07 Oil and Grease - D-OOF (CR3) v2 D-OOF] 1 NODI=9 7/1/07 8/1/07 Oil and Grease - I-OFE (CR3) v2 I-OFE 3.63 3.63 7/1/07 8/1/07 Oil and Grease - I-OFG (CR3) v2 I-OFG I 0.62 1.63 7/1/07 8/1/07 pH - Background - D-O0F (CR3) v2 D-OOF 7.94 8.11 10/21/2009 Page 57

9 Crystal River ear DMR Data Permit Nn FI flNlNlIA1* ii.t ndDt E~ at g;PARAMETER~NM,~ NAE Outa I)C~ VgX CI-M n C'm*I CMx~~QAg-ax,-

                                                                                                                      ;.MI NDAv      NODIAg i--Min NOIMax.ND i

I i I 7/1/07 8/1/07 pH - Effluent - D-OOF (CR3) v2 D-OOF 7.98 8.18 8/1/07 pH - I-OFE (CR3) v2 - -OFE - -I--

7/1/07 6.7 6.7 F - 7/1/07 8/1/07 pH - I-OFG (CR3) v2 I-OFG 8.56 8.98 7/1/07 8/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 0 7/1/07 8/1/07 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.35 7/1/07 8/1/07 Temp Rise - D013 (CR3) v2 D013 7 8.9

                                                                                                                                     ~ 7/1/07         8/1/07  Temp-Discharge - D013 (CR3) v2                  D013          94.2                         96.6 7/1/07         8/1/07  Temp-Intake - D013 (CR3) v2                     D013          87.2                         94.9 7/1/07         8/1/07  Total Ammonia 1-D-OOF (CR3) v2                1-D-OOF                                                                                  NODI=9 7/1/07         8/1/07  Total Ammonia P-D-OOF (CR3) v2                P-D-OOF                                                                                  NODI=9   -

7/1/07 8/1/07 Total Copper - DOOF (CR3) v2 DOOF NODI=9 NODI=9 7/1/07 8/1/07 Total Copper - I-0FG (CR3) v2 I-OFG I NODI=9 I_ 7/1/07 8/1/07 Total Iron- D-OOF (CR3) v2 D-0OF NODI=9 NODI=9 7/1/07 8/1/07 Total Iron- I-DFG (CR3) v2 I-OFG NoD19 I i 7/1/07 8/1/07 Total Recoverable Copper - D-O0F (CR3) v2 D-DOF NODI=9 NODI=9 7/1/07 8/1/07 Total Recoverable Iron - D-ODF (CR3) v2 D-DOF NODI=9 NODI=9 7/1/07 8/1/07 Total Residual Ox 1-D013 (CR3) v2 1-D013 1 __________ NODI=9 NOD1=9 7/1/07 7/1/07 8/1/07 8/1/07 TSS - CD and ECST D-ODF (CR3) v2 ITSS - I-DFE (CR3) v2 D-DOF I-OFE 1 0 0 I ___ ____ 0 0 7/1/07 8/1/07 -TSS - I-0FG (CR3) v2 I-0FG 5.27 9.6 7/1/07 8/1/07 TSS P-D-OOF (CR3) v2 P-D-0EF NOD1=9 NODI=9 7/1/07 8/1/07 TSS Q-D-O0F (CR3) v2 Q-D-00F NODI=9 NOD1=9 7/1/07 8/1/07 Turbidity - Background - D-DDF (CR3) v2 D-00F NODI=9 7/1/07 8/1/07 Turbidity - Calc Limit - D-ODF (CR3) v2 D-00F NODI=9 D-00F 7/1/07 8/1/07 Turbidity - Difference D-OOF (CR3) v2 NODI=9 D-00F 7/1/07 8/1/07 Turbidity - Effluent D-ODF (CR3) v2 NODI=9 96-Hour Menidia Beryllina P-D-O0F (CR3) P-D-00F 8/1/07 9/1/07 NODI=9 8/1/07 9/1/07 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-00F NODI=9 P-D-DEF 8/1/07 9/1/07 96-Hour Mysidopsis Bahia P-D-OOF (CR3) Q NODI=9 Q-D-DEF 8/1/07 9/1/07 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) NODI=9 I-0OFE 8/1/07 9/1/07 Flow - I-DFE (CR3) v2 0.00004106 0.001273 TI-OFG 8/1/07 9/1/07 Flow - I-0FG (CR3) v2 0.0192484 0.079628-D-OEF 8/1/07 9/1/07 Flow-CD System D-DOF (CR3) v2 "-D-0OF 0 10 8/1/07 9/1/07 Flow-ECST D-DOF (CR3) v2 0.00295496 0015238 T D-OEF 8/1/07 9/1/07 Flow-Intake - D-DDF (CR3) v2 16.78129 43.488 10/21/2009 Page 58

Crystal River Wear DMR Data Permit No. FL00000159 L

 ,BgndaeJ     EndDaIae                 PAA ETRNA         EOutall,                      Av                      -Max CCMn    1Q-Avg,~-QMx             NODI)-Avgl       'NODI-MaxND-i 8/1/07          9/1/07    Hydrazine 1-D-OOF (CR3) v2                   1-D-OOF                                                                  NODI=9 8/1/07          9/1/07  iHydrazine P-D-OOF (CR3) v2          -

I -- N007 NODI=9 8/1/07 9/1/07 1Hydroquinone 1-D-OOF (CR3) v2 P-D-OOF.1____ _______ ___ NODI=9 - ! 8/1/07 9/1/07 Hydroquinone P-D-OOF (CR3) v2 - NODI=9 I Ii 8/1/07 9/1/07 Morpholine 1-D-OOF (CR3) v2 P-D-OOF NODI=9 I 8/1/07 9/1/07 Morpholine P-D-OOF (CR3) v2 1 i 1 _ _ 8/1/07 9/1/07 lNumber of Batches - I-OFE (CR3) v2 PD-OOF 8/1/07 9/1/07 Oil and Grease - D-O0F (CR3) v2 NODI=9 8/1/07 9/1/07 Oil and Grease - I-0FE (CR3) v2 I-OFE 0.75 0.75 8/1/07 9/1/07 {Oil and Grease - I-OFG (CR3) v2 - I-OFG 1.26 3 i 8/1/07 9/1/7 pH - Background - D-O0F (CR3) v2 D-OOF 7.96 813 8/1/07 9/1/07 pH - Effluent - D-ODF (CR3) v2 D-OOF 7.94 8.25 8/1/07 9/1/07 pH - I-OFE (CR3) v2 I-OFE 6.87 6.87 8/1/07 9/1/07 pH - I-OFG (CR3) v2 I-OFG 8.56 8.98 -Fl ... .. .. ..- 8/1/07 9/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 __o 0 8/1/07 9/1/07 Spectrus CT1300 - DOOF (CR3) v2 DOOF 8/1/07 9/1/07 Temp Rise - D013 (CR3) v2 F- D013 6.1 10.2 8/1/07 8/1/07 8/1/07 9/1/07 9/1/07 9/1/07 Temp-Discharge - D013 (CR3) v2 Temp-Intake - D013 (CR3) v2 Total Ammonia 1-D-ODF (CR3) v2 _____~1*-~ D013 D013 1-D-OOF 93.9 87.8 + 96.3 90.8 I.

                                                                                                                                ---            NODI=9     -

8/1/07 9/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 8/1/07 8/1/07 9/1/07 9/1/07 Total Copper - DOOF (CR3) v2 Total Copper - I-OFG (CR3) v2 121 DOOF I-OFG NO 01=9 NODI=9 NODI=9 8/1/07 9/1/07 ýTotal Iron- D-OOF (CR3) v2 D-OOF NODI=9- NODI=9 8/1/07 9/1/07 Total Iron- I-OFG (CR3) v2 I-OFG NODI=9 8/1/07 9/1/07 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF ___ NODI=91 NODI=9 8/1/07 9/1/07 [Total Recoverable Iron - D-OOF (CR3) v2 D-00F NODI=9 NODI=9 N00l9 8/1/07 9/1/07 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 8/1/07 9/1/07 [TSS - CD and ECST D-OOF (CR3) v2 D-OOF 0 0 8/1/07 9/1/07 TSS - I-OFE (CR3) v2 I-OFE 2.6 2.6 8/1/07 9/1/07 ITSS - I-OFG (CR3) v2 I-OFG 12.98 27.8 8/1/07 9/1/07 TSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 8/1/07 9/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9 8/1/07 9/1/07 Turbidity - Background - D-OOF (CR3) v2 D-00F NODI=9 8/1/07 9/1/07 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF NODI=9 10/21/2009 Page 59

Crystal River Dear DMR Data Permit No. FL00000159 Beindae~ End D'ate' ____________________l

                                         ~    AAMETER NAME>'1:                               C-I~&          CIla       .

Avg"vg' 0 -Max Qu~V

                                                                                                                                                   -vg NODI-'Avg   NDIMx        ODMi 8/1/07      1   9/1/07         ITurbidity - Difference D-OOF (CR3) v2            D-OOF                                                                                                 NODl'=9 8/1/07          9/1/07         ýTurbidity - Effluent D-OOF (CR3) v2        }     D-OOF                                                                                                  0OD1=9 9/1/07         10/1/07          96-Hour Menidia Beryllina P-D-OOF (CR3)         P-D-OOF                                                                                                             >100 9/1/07         10/1/07         196-Hour Menidia Beryllina Q-D-OOF (CR3)         Q-D-OOF                                                                                                            NODI=9 9/1/07         10/1/07         196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2j      P-D-OOF                                                                                                             >100
                                                                                                                                                                                              -TF 9/1/07         10/1/07          96-Hour Mysidopsis Bahia Q-D-OOF (CR3)          Q-D-OOF                                                                                                            NODI=9 9/1/07         10/1/07          Flow - I-OFE (CR3) v2                             I-OFE                                                              0            0 9/1/07         10/1/07          FlowI - I-OFG (CR3) v2                            I-OFG                                                         0.0072181    0.0 77932 9/1/07         10/1/07          Flow-CD System D-OOF (CR3) v2                    D-OOF                                                                0           0 9/1/07         10/1/07          Flow-ECST D-OOF (CR3) v2                         D-OOF                                                         0.00251846    0.0 '15525 9/1/07         10/1/07          Flow-Intake - D-OOF (CR3) v2                     D-OOF                                                          16,472733     3' 4.272

_____ I 9/1/07 10/1/07 Hydrazine 1-D-OOF (CR3) v2 I1-D-OOF NODI=9 9/1/07 10/1/07 Hydrazine P-D-OOF (CR3) v2 1 P-D-OOF NODI=9 9/1/07 10/1/07 {Hydroquinone 1-D-OOF (CR3) v2 J 1-D-OOF NODI=9 I. _________________ ___________ 9/1/07 10/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF I. ____________ i -~ ___________ NODl=9 9/1/07 10/1/07 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 24.075 9/1/07 10/1/07 Morpholine P-D-OOF (CR3) v2 P-D-OOF 101 0 9/1/07 10/1/07 Number of Batches - I-OFE (CR3) v2 1 I-OFE 9/1/07 10/1/07 Oil and Grease - D-OOF (CR3) v2 D-OOF NODI=9 9/1/07 10/1/07 Oil and Grease - I-OFE (CR3) v2 F NODI=C 1 NODI=C I 9/1/07 10/1/07 Oil and Grease - I-OFG (CR3) v2 I-OFG 2.67 11 4.25 I _____ 9/1/07 10/1/07 ipH - Background- D-OOF (CR3) v2 D-OOF 8.02 8.05 9/1/07 10/1/07 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.01 8.05 9/1/07 10/1/07 pH - I-OFE (CR3) v2 -OFE _-_ I NODI=C NODI=C 9/1/07 10107 pH -I-OFG (CR3) v2 I-OFG 8.75 -_8.91 10/1/07 Residual Ox - Time of Discharge D013 (CR3) D013 - 0 9/1/07 9/1/07 10/1/07 Spectrus CT1300 - DOOF (CR3) v2 - DOOF 2.3 9/1/07 10/1/07 ]Temp Rise -D013 (CR3) v2 D013 9.5 14.1 D013 93.6 96 9/1/07 10/1/07 ýTemp-Discharge - D013 (CR3) v2 9/1/07 10/1/07 Temp-Intake - D013 (CR3) v2 0013 84 88.4

                                                                                                                                           ~1______

9/1/07 10/1/07 iTotal Ammonia 1-D-OOF (CR3) v2 I1-D-0OF 1 NODI=9~ 9/1/07 10/1/07 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF 1 NODI=9 9/1/07 10/1/07 ITotal Copper - DOOF (CR3) v2 DOOF 1 P NODI=9- NODI=9 9/1/07 10/1/07 FTotal Copper - I-OFG (CR3) v2 I-OFG NODI=9 9/1/07 10/1/07 ýTotal Iron- D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 10/21/2009 Page 60

Crystal River ear DMR Data Permit No. FL00000159 Begin date. End Date PARAETERNAME I'~4C-Av Oua< ýMin J 7Ma _Q-Avg Q-IVMax OIA NODI-Max NODP-Min,-, 9/1/07 10/1/07 Total Iron- I-OFG (CR3) v2 I-OFG NODI=9 9/1/07 10/1/07 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 9/1/07 10/1/07 Total Recoverable Iron - D-O0F (CR3) v2 D-OOF NOD,1=9 1 NODI=9 9/1/07 10/1/07 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 NODI=9 9/1/07 10/1/07 TSS - CD and ECST D-O0F (CR3) v2 D-OOF NODI=B NODI=B 9/1/07 10/1/07 TSS - I-OFE (CR3) v2 I-OFE NODI=C NODI= I-OFG 20.7 24. 4 9/1/07 10/1/07 TSS - I-0FG (CR3) v2 9/1/07 10/1/07 TSS P-D-OOF (CR3) v2 P-D-00F I-- NODI=9 NODI=9 9/1/07 10/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF ~~~~1 NODI=9 NODI=9 9/1/07 10/1/07 Turbidity - Background - D-O0F (CR3) v2 D-OOF NOD1=9 9/1/07 10/1/07 Turbidity - Calc Limit - D-OOF (CR3) v2 D-ODF NODI=9 9/1/07 10/1/07 Turbidity - Difference D-OOF (CR3) v2 D-OOF NODI=9 9/1/07 10/1/07 Turbidity - Effluent D-DOF (CR3) v2 D-OF NODI=9 10/1/07 11/1/07 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF NODI=9 10/1/07 11/1/07 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 10/1/07 11/1/07 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OF NODI=9 10/1/07 11/1/07 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF NODI=9 i 10/1/07 11/1/07 Flow - I-DFE (CR3) v2 I-0FE 0.00004329 0.001342 10/1/07 11/1/07 Flow - I-0FG (CR3) v2 I-0FG S0.0204636 0.079089 10/1/07 11/1/07 Flow-CD System D-ODF (CR3) v2 D-ODF 10/1/07 11/1/07 Flow-ECST D-OOF (CR3) v2 D-ODF 0.0049225 0.015388 10/1/07 11/1/07 Flow-Intake - D-ODF (CR3) v2 D-ODF 15.831871 ! 34.272 10/1/07 11/1/07 Hydrazine 1-D-ODF (CR3) v2 1-D-O0F NODI=9 10/1/07 11/1/07 Hydrazine P-D-OOF (CR3) v2 P-D-OOF II - NOD1=9 10/1/07 11/1/07 Hydroquinone 1-D-DDF (CR3) v2 1-D-OOF NODI=9 10/1/07 11/1/07 Hydroquinone P-D-O0F (CR3) v2 P-D-00F NODI=9 jF-10/1/07 11/1/07 Morpholine 1-D-ODF (CR3) v2 1-D-00F 24.02 10/1/07 11/1/07 Morpholine P-D-O0F (CR3) v2 P-D-OOF NODI=9 10/1/07 11/1/07 Number of Batches - I-OFE (CR3) v2 I-DFE I

                                                                                                                         ! 1      I       1   I 10/1/07        11/1/07    Oil and Grease - D-ODF (CR3) v2               D-O0F                                                                               NODI=9 10/1/07        11/1/07    Oil and Grease - I-DFE (CR3) v2                I-DFE        0.38                     0.38 10/1/07        11/1/07   1Oil and Grease - I-OFG (CR3) v2                I-0FG         1.28                    2.75 10/1/07        11/1/07  jpH - Background - D-DOF (CR3) v2               D-ODF                       7.88       8.08 D-00F 10/1/07        11/1/07    pH  - Effluent
                                   -     - D-DD  (CR3) v2                                           7.95        8.1 10/1/07        11/1ý/07   pH  - I-DEE (CR3) v2                           I-0FE     [                6.9        6.9 10/21/2009                                                                           Page 61

Crystal River sear DMR Data Permit No. FL00000159 NAME Outal C-Max - NODI-Avg I

Begin date End Date PARAMETER,,NIAE I I i I = I 10/1/07 11/1/07 pH - I-OFG (CR3) v2 I-OFG 8.37 8.87 10/1/07 11/1/07 Residual Ox -Time of Discharge D013 (CR3) D013 0 10/1/07 11/1/07 Spectrus CT1300 - DOOF (CR3) v2_____ DOOF 2.25 10/1/07 11/1/07 Temp Rise - D013 (CR3) v2 D013 I.4.1 16.9 10/1/07 11/1/07 Temp-Discharge - D013 (CR3) v2 D013 9 2.4 95.8 10/1/07 11/1/07 Temp-Intake - D013 (CR3) v2 D013 7'8.4 ______________

82.3 10/1/07 11/1/07 ITotal Ammonia 1-D-OOF (CR3) v2 1-D-00F I NODI=9 NODI=9 I 10/1/07 11/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF Total Copper - DOOF (CR3) v2 DOOF NODI=9 NODI=9 10/1/07 11/1/07 10/1/07 11/1/07 Total Copper - I-OFG (CR3) v2 I-0FG NODI=9 11/1/07 Total Iron- D-O0F (CR3) v2 D-0OF NODI=9 NODI-=9 10/1/07 10/1/07 11/1/07 [Total Iron- I-0FG (CR3) v2 I-OFG NODI=9 10/1/07 11/1/07 Total Recoverable Copper - D-ODF (CR3) v2 D-DOF NODI=9 NODI=9 10/1/07 11/1/07 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF NODI=9 NODI=9 10/1/07 11/1/07 -Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 NODI=9 10/1/07 11/1/07 TSS - CD and ECST D-O0F (CR3) v2 D-0OF NODI=B NODI=B 10/1/07 11/1/07 TSS - -OFE (CR3) v2 -OFE 5.3 5.3 10/1/07 11/1/07 TSS - I-OFG (CR3) v2 I-0EG 7.45 9.5 10/1/07 11/1/07 TSS P-D-OOF (CR3) v2 P-D-OOF NODI=9 NODI=9 10/1/07 11/1/07 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9 NODI=9 10/1/07 11/1/07 Turbidity - Background - D-OOF (CR3) v2 T D-0OF NODi9 10/1/07 11/1/07 Turbidity - Calc Limit - D-OOF (CR3) v2 D-O0F NODI=9 10/1/07 11/1/07 Turbidity - Difference D-O0F (CR3) v2 D-0OF NODI=9 10/1/07 11/1/07 Turbidity - Effluent D-OOF (CR3) v2 D-OOF NODI=9 11/1/07 12/1/07 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-O0F >100 11/1/07 12/1/07 ý96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 11/1/07 12/1/07 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2] P-D-OOF >100 11/1/07 12/1/07 196-Hour Mysidopsis Bahia Q-D-O0F (CR3) Q-D-OOF NODI=9 11/1/07 12/1/07 Flow - I-0FE (CR3) v2 I-0FE 0.0001643 0.001485 11/1/07 12/1/07 !Flow - I-FG (CR3)v2 I-FG 0.0150499 0.080949 11/1/07 12/1/07 Flow-CD System D-O0F (CR3) v2 D-O0F 0.015957 0.478712 11/1/07 12/1/07 Flow-ECST D-DOF (CR3) v2 D-DOF 0.0024677 0.013463 11/1/07 12/1/07 1Flow-Intake - D-O0F (CR3) v2 D-0OF 25.55567 36.242 11/1/07 12/1/07 Hydrazine 1-D-O0F (CR3) v2 1-D-ODF NODI=9 11/1/07 12/1/07 -Hydrazine P-D-OOF (CR3) v2 P-D-OOF NODI=9 10/21/2009 Page 62

Crystal River Sear DMR Data Permit No. FL00000159 ~Begi ae EdDt AAEE NAME OUt II7 C-Avg& Cs.... C-Max Av Q-Max. NOIAgj OIMxNDI-Min 11/1/07 12/1/07 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF NODI=9 11/1/07 12/1/07 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF NODI=9 11/1/07 12/1/07 Morpholine 1-D-OOF (CR3) v2 Q 1-D-OOF 18.35 11/1/07 12/1/07 Morpholine P-D-OOF (CR3) v2 P-D-OOF NODI=9

                                                                                                                -Ii        1                                     T 11/1/07        12/1/07  Number of Batches - I-0FE (CR3) v2                I-OFE                                      1
                                                                                                                                    . . . ...     - NODI=9 11/1/07        12/1/07  Oil and Grease - D-OOF (CR3) v2                 D-OOF 11/1/07        12/1/07  Oil and Grease - I-OFE (CR3) v2                   I-OFE        8.41              16.25 11/1/07        12/1/07  Oil and Grease - I-OFG (CR3) v2                 D-OFG          0.9               2.13 11/1/07        12/1/07  pH - Background - D-OF (CR3) v2                 D-OOF                    8.08    8.14 11/1/07        12/1/07  pH - Effluent - D-OOF (CR3) v2 1

D-OOF I-OFE 8 7.09 8.12 7.86 { -- 11/1/07 12/1/07 pH - I-OFE (CR3) v2 11/1/07 12/1/07 pH - I-OFG (CR3) v2 I-OFG 7.55 8.71 11/1/07 12/1/07 Residual Ox - Time of Discharge D013 (CR3)i D013 0 11/1/07 12/1/07 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.2 11/1/07 12/1/07 Temp Rise - D013 (CR3) v2 D013 13.3 18.3 11/1/07 12/1/07 Temp-Discharge - D013 (CR3) v2 D013 80.3 1 91.4 11/1/07 12/1/07 Temp-Intake -_D013 (CR3) - D013 67 72.9 11/1/07 12/1/07 Total Ammonia 1-D-OOF (CR3) v 1-D-OOF NODI=9 11/1/07 12/1/07 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF NODI=9 11/1/07 12/1/07 iTotal Copper - DOOF (CR3) v2 DOOF NODI=9 NODI=9 11/1/07 F 12/1/07 Total Copper - I-OFG (CR3) v2 I-OFG J NODI=9 11/1/07 12/1/07 ITotal Iron- D-OOF (CR3) v2 D-OOF NO-D01=-9

                                                                                                                                   -N.        __!_    NODl=9 r

11/1/07 1 12/1/07 !Total Iron-l-0FG (CR3)v2 I-OFG NCDI=9 11/1/07 12/1/07 iTotal Recoverable Copper 00F (CR3) v2 0-00F NODI=9 11/1/07 12/1/07 ITotal Recoverable Iron - D-OOF (CR3) v2 D-OOF N001=9

                                                                                                                                .NODI=9              NODI=9 11/1/07        12/1/07 ITotal Residual Ox 1-D013 (CR3) v2               1-D013                                                     NODI=9            NODI=9 11/1/07        12/1/07 ITSS - CD and ECST D-OOF (CR3) v2                D-OOF          1.91               2.5 11/1/07        12/1/07 iTSS - I-OFE     (CR3) v2        _    _I-OFE                    7.91               9,5 11/1/07        12/1/07 ITSS   -  I-OFG (CR3) v2                     i"-I-0FG           25.1              52.2 NODI=9 11/1/07        12/1/07 TSS P-D-OOF (CR3)v2      Q                      P-D-OOF                                                                       N001=9 11/1/07        12/1/07 ITSS Q-D-00F (CR3) v2                        I  Q-D-OOF IINODI=9 1NODI=9 11/1/07        12/1/07 ITurbidity - Background - D-OOF (CR3) v2         D-OOF                  1!~                                                 INODI=9 11/1/07    1   12/1/07 LTurbidity - Calc Limit - D-OOF (CR3)v2    Q      D-0OF                                                                       NODI=9
                                                                                                                                                  -  I-- --- - -

11/1/07 12/1/07 Turbidity - Difference D-OOF (CR3) v2 Q D-OOF NODI=9 11/1/07 12/1/07 ITurbidity - Effluent D-OOF (CR3) v2 _ D-OOFI 10/21/2009 Page 63

Crystal River Sear DMR Data Permit No. FL00000159 >Begin dateI ~End Date> I.>> PAR~AMETER NAME> I~itaiI Ou- C-Avg I-~ I C-i C-I>. Ma V I.~ L.~7 V I.OD-v N-v -4 ,NDMax 0-a .1 NODI-Min: I*____________ ___________

                 ..     .   ... I/.... . . . . . ... ... ... . . ........                     S~            ."     -.        -               ...     .~     ~

1/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF NODI=9 12/1/07 1/1/08 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF NODI=9 12/1/07 1/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2I P-D-OOF NODI=9 12/1/07 12/1/07 1/1/08 96-Hour Mysidopsis v2 Bahia -D-0F (CR3) 1 Q-D-OOF NODI=9 12/1/07 1/1/08 1/1/08 Flow - I-OFE (CR3) v2 Flow - I-0FG (CR3) v2 I-OFE 0.0000901 F 0.001486 12/1/07 I-OFG 0.0161466 0.078531 12/1/07 1/1/08 Flow-CD System D-OOF (CR3) v2 D-OOF 0.01368087 0.424107 12/1/07 1/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF ! 0.00144487 0.01576 12/1/07 1/1/08 Flow-Intake - D-OOF (CR3) v2 D-00F 19.326 42.6 12/1/07 1/1/08 Hydrazine 1-D-OOF (CR3) v2 1-D-00F NODI=9 12/1/07 1/1/08 Hydrazine P-D-OOF (CR3) v2 P-D-OOF NODI=9 1/1/08 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF

                                                                                                                                                                                   -   I-  NODI=9 12/1/07 12/1/07         1/1/V/08   Hydroquinone P-D-OOF (CR3) v2                              P-D-OOF                                                                                             NODI=9 1

12/1/07 1/1/08 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 37.46 12/1/07 1/1/08 Morpholine P-D-OOF (CR3) v2 P-D-OOF NOD1=9 1 12/1/07 1/1/08 [INumber of Batches - I-OFE (CR3) v2 I-OFE 12/1/07 1/1/08 Oil and Grease - D-OOF (CR3) v2 D-00F N001=9 12/1/07 1/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE 1.98 3.75 12/1/07 1/1/08 Oil and Grease - I-OFG (CR3) v2 I-OFG 1.46 3 12/1/07 1/1/08 pH - Background - D-OOF (CR3) v2 D-OOF 8.05 8.12 12/1/07 1/1/08 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.15 12/1/07 1/1/08 pH - I-OFE (CR3) v2 I-OFE 7.28 7.77

                                                                                                           . .....   .  . ..   . 8.

7.6 . .. 12/1/07 1/1/08 pH - l-OFG (CR3) v2 t-OFG 8.84 12/1/07 1/1/08 Residual Ox- Time of Discharge D013 (CR3) D013 0 12/1/07 1/1/08 ISpectrus CT1300 - DOOF (CR3) v2 DOOF 2.2

                                                                                                                                                                   -. . . i 1Temp Rise - D013 (CR3) v2 12/1/07 12/1/07
           -I     1/1/08 1/1/08   ITemp-Discharge - D013 (CR3) v2 D013 D013 13.9 78.8 17.1 87.5 12/1/07          1/1/08  lTemp-lntake - D013 (CR3) v2                                   D013           65.6                                   71.6 12/1/07          1/1/08   ITotal Ammonia 1-D-OOF (CR3) v2                             1-D-OOF                                                                                             NODI=9 12/1/07          1/1/08    Total Ammonia P-D-OOF (CR3) v2                             P-D-OOF                                                                                             NODi=9 12/1/07          1/1/08   ITotal Copper - DOOF (CR3) v2                                 DOOF                                                                                              NODI=9      NODI=9 12/1/07          1/1/08   ITotal Copper - I-OFG (CR3) v2                                l-OFG                                                                                                     -   NODI=9 12/1/07          1/1/08   ITotal Iron- D-OOF (CR3) v2                                   D-OOF                                                                                         __NODI=9   VN     001=9 12/1/07          1/1/08   !Total Iron- I-OFG (CR3) v2                                   I-OFG                                                                                                       INODI=9 12/1/07          1/1/08   iTotal Recoverable Copper - D-OOF (CR3) v2                    D-OOF                                                                                             NODI=9      NODI=9 10/21/2009                                                                                           Page 64.

Crystal River O ear DMR Data Permit No. FL00000159 8#ndat~e I End Date, PARAMETER~ NAME ~ /uaI -C -m I Tý CM -v

                                                                                                                                                     . ax .LNO-v

~: - ----

0IM~IND-i 12/1/07 1/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-00F NODI=9 INODIk9 12/1/07 1/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 NODI=9 I NODI=9 12/1/07 1/1/08 TSS - CD and ECST D-OOF (CR3) v2 D-ODF 3.45 8.56 12/1/07 1/1/08 {TSS - I-OFE (CR3) v2 I-OFE 7.97 11.8 12/1/07 1/1/08 TSS - I-OFG (CR3) v2 I-OFG 10.37 17.9 P-D-00F NOD1=9 NOD1=9 12/1/07 1/1/08 TSS P-D-OOF (CR3) v2 12/1/07 1/1/08 TSS Q-D-OOF (CR3) v2 Q-D-OOF NODI=9I NODI=9 D-OOF NO001=9 12/1/07 1/1/08 Turbidity - Background - D-OOF (CR3) v2 12/1/07 1/1/08 Turbidity - Calc Limit - D-0OF (CR3) v2 D-OOF 0-00 F N001=9 12/1/07 1/1/08 Turbidity - Difference D-DOF (CR3) v2 NODI=9 0-00 F D-00F NOD1=9 12/1/07 1/1/08 Turbidity - Effluent D-0OF (CR3) v2 1/1/08 2/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100 1/1/08 2/1/08 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF MNR 1/1/08 2/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF >100 1/1/08 2/1/08 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF MNR 1/1/08 2/1/08 Flow - I-OFE (CR3) v2 I-OFE 0.00008929 0.001422 1/1/08 2/1/08 Flow - I-OFG (CR3) v2 I-OFG 0.0140983 0.082896 1/1/08 2/1/08 Flow-CD System D-OOF (CR3) v2 D-OOF 0 1/1/08 2/1/08 Flow-ECST D-OOF (CR3) v2 D-00F 0.003434 0.015474 1/1/08 2/1/08 Flow-Intake - D-OOF (CR3) v2 D-DOF 18.21 29.52 1/1/08 2/1/08 Hydrazine 1-D-OOF (CR3) v2 1-D-00F MNR 1/1/08 2/1/08 Hydrazine P-D-OOF (CR3) v2 P-D-OOF MNR 1/1/08 2/1/08 jHydroquinone 1-D-OOF (CR3) v2 1-D-00F - i*- MNR 1/1/08 2/1/08 1Hydroquinone P-D-OOF_(CR3) v2 P-D-00F MNR 2/1/08 -Morpholine -D-OOF (CR3) v2 1/1/08 2/1/08 Morpholine P-D-OOF (CR3) v2 1-D-00F 39.2667 MNR 1/1/08 2/1/08 Numberhofin -- sOE (CR3)v he P-D-OOF 1/1/08 2/1/08 Number of Batches - -OFE (CR3) v2 1 1_ I-OFE 1/1/08 MNR 1/1/08 2/1/08 Oil and Grease - D-00F (CR3) v2 D-ODF 11/08 <.4 1 M<1.4 2/1/08 Oil and Grease - I-OFE (CR3) 2 I-OFE

                                                                                                                                                                      <1.4            <1.4 2/1/08     Oil and Grease - 1*-: G(CR3) v2                  I-OFG 1/1/08          2/1/08     pH - Background - D-ODF (CR3) v2                D-ODF                             7.99        8.13 1/1/08          2/1/08     pH - Effluent - D-OOF (CR3) v2 1/1/08                                                                     D-ODF                             7.98        8.15 2/1/08     pH - I-OFE (CR3) v2                              I-0FE                            86.3        6.88            I    --

1/1/08 S 8.46 2/1/08 pH - I-0FG (CR3) v2 I-OFG 8.77 1/1/08 2/1/08 -Residual Ox - Time of Discharge D013 (CR3) D013 0 o 10/21/2009 Page 65

Crystal River B ear DMR Data Permit No. FL00000159 Begin..... End.Date R METE M Outall C-Avg

C-OIA " x I'Avg N-Max NODI-Max NO NOMDI-Ma 1/1/08 2/1/08 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.15 1/1/08 2/1/08 _ Temp Rise - D013 (CR3) v2 D013 17.3 19.7 I 1/1/08 2/1/08 ýTemp-Discharge - D013 (CR3) v2 D013 75.2 82.4

                                                                                                                                         -I-1/1/08           2/1/08      ]Temp-Intake - D013 (CR3) v2                     D013               58.2                 67.8 1/1/08          2/1/08       iTotal Ammonia 1-D-OOF (CR3) v2               1-D-OOF           ___         -i                                            MNR 1/1/08           2/1/08        lTotal Ammonia P-D-OOF (CR3) v2              P-D-00F                                                                     MNR 1/1/08           2/1/08      ITotal Copper - DOOF (CR3) v2                    DO                                                                        MNR      MNR 1/1/08           2/1/08   ITotal Copper - I-OFG (CR3) v2                      I-0FG        -                                                                    MNR 1/1/08           2/1/08       Total Iron- D-OOF (CR3) v2                     D-OOF                                                                      MNR     MNR 1/1/08     [    2/1/08       Total Iron- OFG (CR3)v2         _,-OF-G                                                                                           MNR
  //08       1   2/1/08   _Total Recoverable Copper - D-OOF (CR3)v2      Q   D-0OF                                                                      MNR     MNR 1/1/08           2/1/08      ITotal Recoverable iron - D-OOF (CR3)    v2     D-OOF                                                                      MNR     MNR 1/1/08           2/1/08       ýTotal Residual Ox 1-D013 (CR3) v2             1-D013          _        _                                                 MNR     MNR 1/1/08           2/1/08      iTSS - CD and ECST D-OOF (CR3) v2               D-OOF                                                                      <4.0     <4.0 1/1/08          2/1/08      1TSS     I-OFE (CR3)v2                            I
                                                                                                                                                        <4.0     <4.0 1/1/08          2/1/08       ITSS - i-OFG_(CR3) v2                           i-OFG             1044                  12.5 1/1/08          2/1/08       ITSS P-D-OOF (CR3) v2                         P-D-OOF                                                                     MNR     MNR 11/08           2/1/08       ITSS O,-D-OF (CR3) v2                         O.-D-OOF                                                                    MNR     MNR 11/08           2/1/08       Turbidity    - Background - D-OOF (CR3) v2      D-OOF       .                                                                      MNR 1/1/08          2/1/08       Turbidity - Calc Limit - D-OOF (CR3) v2         D-OOF                                                                              MNR 1/1/08          2/1/08       Turbidity - Difference D-OOF (CR3) v2           D-OOF                                                                              MNR 1/1/08          2/1/08       Turbidity - Effluent D-OOF (CR3) v2             D-OOF     j    _-                                                                 MNR 2/1/08           3/1/08        96-Hour Menidia Beryllina P-D-OOF (CR3)      P-D-OOF                                                                                      MNR 2/1/08           3/1/08        96-Hour Menidia Beryllina Q-D-OOF (CR3)      Q-D-OOF      _                                                                               MNR 2/1/08           3/1/08       196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2    P-D-OOF j                                                                                    MNR 2/1/08           3/1/08        96-Hour Mysidopsis Bahia Q-D-OOF (CR3)       Q-D-OOF                                                                                      MNR 2/1/08           3/1/08       Flow - I-OFE (CR3) v2                           I-OFE   -    -
                                                                                                                            -10.0001452  J 0.001504 2/1/08           3/1/08        Flow - I-OFG (CR3) v2                          I-OFG                                             0.018045     0.081122 2/1/08           3/1/08        Flow-CD System D-OOF (CR3) v2                 D-OOF                                                    0          0 2/1/08           3/1/08        Flow-ECST D-OOF (CR3) v2                      D-OOF                                             0.0024545 1,0.014629 2/1/08           3/1/08        Flow-Intake - D-OOF (CR3) v2                  D-00F 2/1/08           3/1/08       Hydra          -D-OOF (CR3) v2                1-D-OOF           _

16.97887 1129.52 2/1/08 3/1/08 Hydrazine P-D-OOF (CR3) 2 P-D-OOF MNR 2/1/08 3/1/08 Hydrazine P-D-OOF (CR3)v2 P-D-OOF MNR 2/1/08 3/1/08 - Hydroquinone P-D-OOF (CR3) v2 p-D-OOF MNR 66-O(R)2_ MNR __ -- O Pageuion 210/2208 310 8 10/21/2009 Page 66

Crystal River Permit O* ear DMR Data No. FLOO000159 Ei~d~Date PARAMETER NAME

v, jBegin date En Date,L,-tal* PARAMETER-NAME .C-A. . . C-Min

                                                                                                             ... .. ......       Q-Max   .      NODA.        NODI-Max NODI-Min 2/1/08          3/1/08           Morpholine 1-D-OOF (CR3) v2                 1-D-OOF         27.1 2/1/08          3/1/08           Morpholine P-D-OOF (CR3)v2                  P-D-OOF                                                           MNR 1  .   . ...   .   . .

I-OFE 1_ 2/1/08 3/1/08 -Number of Batches - I-0FE (CR3) v2 2/1/08 3/1/08 Oil and Grease - D-OOF (CR3) v2 D-00F MNR 2/1/08 3/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE <1.4 <1.4 2/1/08 3/1/08 Ol and Grease -I-OFG(CR3) v2 I-OFG 2.13 <1.4 2/1/08 3/1/08 pH - Background - D-OOF (CR3) v2 D-0OF 8.04 8.11 2/1/08 3/1/08 jpH - Effluent - D-O0F (CR3) v2 D-OOF 8.02 8.13 2/1/08 3/1/08 pH - I-OFE (CR3)v2 I-OFE 6.41 6.51 2/1/08 T 3/1/08 pH - I-OFG (CR3) v2 I-OFG 7.73 8.94 7 2/1/08 3/1/08 Residual Ox - Time of Discharge D013 (CR3) D013 0 2/1/08 3/1/08 ISpectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 2/1/08 3/1/08 ITemp Rise - D013 (CR3) v2 D013 16.7 18.2 T 3/1/08 ITemp-Discharge - D013 (CR3) v2 D013 2/1/08 80.1 87 2/1/08 3/1/08 ýTemp-Intake - D013 (CR3) v2 D013 63.6 69.3 2/1/08 3/1/08 'Total Ammonia 1-D-OF (CR3) v2 1-D-OOF MNR 2/1/08 3/1/08 ýTotal Ammonia P-D-OOF (CR3) v2 P-D-OOF MVNR 2/1/08 3/1/08 Total Copper - DOOF (CR3)v2 DOOF MNR MNR 2/1/08 1 3/1/08 ITotal Copper - I-0FG (CR3)v2 I-OFG MNR 2/1/08 3/1/08 Total Iron- D-OOF (CR3) v2 D-0OF MVNR MNR 2/1/08 3/1/08 Total Iron- I-OFG (CR3) v2 I-OFG MNR 2/1/08 3/1/08 Total Recoverable Copper - D-OOF (CR3) v2 D-DOF MNR I MNR 2/1/08 3/1/08 Total Recoverable Iron - D-O0F (CR3) v2 D-OOF MNR MNR 2/1/08 3/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR MNR 2/1/08 3/1/08 TSS - CD and ECST D-O0F (CR3) v2 D-OOF <4.0 <4.0 2/1/08 3/1/08 TSS - I-OFE (CR3) v2 I-OFE <4.0 <4.0 2/1/08 -7 3/1/08 TSS - l-OFG (CR3)v2 I-OFG 16.72 35.1 1 2/1/08 3/1/08 ITSS P-D-OOF (CR3) v2 P-D-OOF I1 MNR MNR 2/1/08 3/1/08 ITSS Q-D-00F (CR3) v2 Q-D-OOF MNR MNR 2/1/08 3/1/08 ITurbidity - Background - D-0OF (CR3) v2 D-OOF MNR 2/1/08 3/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 2/1/08 3/1/08 ITurbidity - Difference D-OOF (CR3)v2 0-00F MNR 2/1/08 3/1/08 ITurbidity - Effluent D-00F (CR3) v2 D-OOF MNR 3/1/08 4/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100 3/1/08 4/1/08 196-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF MNR 10/21/2009 Page 67

Crystal River 19 ear DMR Data Permit No. FL00000159 Bga AL En Dat NAME -AVIT ______ a[ 'CM 'Mxg Q-Maxi-"1 NObI-Avg NODI-Max- N.,ODI-Min 3/1/08 4/1/08 196-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF >100 3/1/08 4/1/08 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF Ii- V MNR 3/1/08 4/1/08 Flow - -OFE (CR3) v2 I-OFE 0.0000474 0.001468 0.013905 0.076952 3/1/08 I 4/1/08 Flow - I-OFG (CR3) v2 I-OFG 3/1/08 4/1/08 Flow-CD System D-00F (CR3) v2 D-OOF 0.047654 0.572129 3/1/08 4/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF 0.0017784 0.014336 3/1/08 4/1/08 IFlow-Intake - D-OOF (CR3) v2 D-0OF 23.718645 [43.488 3/1/08 4/1/08 Hydrazine 1-D-OOF (CR3) Q2 1-D-OOF q MNR 3/1/08 4/1/08 LHydrazine P-D-OOF (CR3) v2 P-D-OOF MNR 3/1/08 1 4/1/08 Hydroquinone 1-D-OOF (CR3) v 1-D-OOF MNR 3/1/08 4/1/08 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF MNR 3/1/08 4/1/08 FMorpholine 1-D-OOF (CR3) v2 I-D-OOF 17.196 3/1/08 4/1/08 Morpholine P-D-OOF (CR3) v2 P-D-OOF MNR - 3/1/08 4/1/08 Number of Batches - I-OFE (CR3) v2 I-OFE S1 1 3/1/08 4/1/08 jOil and Grease - D-OOF (CR3) v2 D-OOF MNR 3/1/08 4/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE <1.4 <1.4 3/1/08 4/1/08 lOll and Grease - I-OFG (CR3) v2 I-OFG 2.38 <1.4 i 3/1/08 4/1/08 pH - Background - D-OOF (CR3) v2 D-OOF 7.98 8.1 3/1/08 4/1/08 [pH - Effluent - D-OOF (CR3) v2 D-OOF 8.1 - 8.14 3/1/08 4/1/08 pH - I-OFE (CR3) v2 I-OFE 6.96 6.96 3/1/08 4/1/08 pH - I-OFG (CR3) v2 I-OFG 7.79 8.59 3/1/08 4/1/08 Residual Ox - Time of Discharge D013 (CR3) D013 0 3/1/08 4/1/08 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 3/1/08 4/1/08 ITemp Rise - D013 (CR3) v2 D013 10.5 17.7 II 3/1/08 4/1/08 ITemp-Discharge - DO13 (CR3) v2 j D013 fI_ 7 87.8 3/1/08 4/1/08 Temp-Intake - D013 (CR3) v2 D013 65.6- 71.4 3/1/08 4/1/08 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF MNR 3/1/08 4/1/08 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF MNR 3/1/08 4/1/08 _Total Copper - DOOF (CR3) v2 DOOF MNR MNR 3/1/08 4/1/08 Total Copper - I-OFG (CR3)v2 I-OFG MNR SMNR 3/1/08 4/1/08 Total Iron- D-OOF (CR3) v2 D-OOF MNR MNR 3/1/08 4/1/08 1TotalIron- I-OFG (CR3) v2 I-OFG MNR 3/1/08 4/1/08 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF I MNR MNR MNR 3/1/08 4/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF MNR 3/1/08 4/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR 10/21/2009 Page 68

Crystal River 9 ~ear DMR Data Permit No. FLOO000159 1 SBegindateg End Date: .... PARAMETER NAME Outall I*C-Avg4 C-MinY K C.Max .. -AVg Q-Max NODI-Avg NODI-Max NODI-Min 3/1/08 4/1/08 TSS - CD and ECST D-OOF (CR3) v2 D-OOF <4.0 I <4.0 3/1/08 4/1/08 ITSS - -OFE (CR3) v2 -OFE <4.0 <4.0 3/1/08 4/1/08 TSS - I-OFG (CR3) v2 I-OFG 9.03 13.4 i 3/1/08 4/1/08 TSS P-D-OOF (CR3) v2 P-D-OOFE MNR MNR __31108 4/1/08 TSS Q-D-OOF (CR3) v2 Q-D-OOF MNR MNR 3/1/08 4/1/08 Turbidity - Background - D-OOF (CR3) v2 D-OOF MNR 3/1/08 4/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 3/1/08 1 4/1/08 Turbidity - Difference D-OOF (CR3) v2-_ D-OOF MNR 3/1/08 4/1/08 Turbidity - Effluent D-OOF (CR3) v2 D-OOF MNR 4/1/08 5/1/08 ý96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF MNR 4/1/08 5/1/08 ]96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF 4/1/08 5/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF MNR 4/1/08 5/1/08 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) v Q-D-OOF MNR 4/1/08 5/1/0 19-Hu Mysiopsi Baha QD________Q-DO NR 4/1/08 5/1/08 Flow - I-OFE (CR3) v2 -IFE 0.0000477 0.001432 4/1/08 5/1/08 Fiow - l-OFG (CR3) v2 I-OFG 0.020021 0.079821 4/1/08 5/1/08 Flow-CD System D-OOF (CR3) v2 D-OOF 0 0 4/1/08 5/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF 0.002767 0.014376 4/1/08 5/1/08 Flow-Intake - D-OOF (CR3)v2 D-OOF 17.318 29.52 4/1/08 5/1/08 ýHydrazine 1-D-OOF (CR3) v2 1-D-OOF MNR 4/1/08 5/1/08 Hydrazine P-D-OOF (CR3) v2 P-D-OOF MNR 4/1/08 5/1/08 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF MNR 4/1/08 5/1/08 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF MNR 4/1/08 5/1/08 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 38.7 4/1/08 5/1/08 Morpholine P-D-OOF (CR3) v2 P-D-OOF MNR 4/1/08 5/1/08 Number of Batches - I-OFE (CR3) v2 -OFE 1 4/1/08 I 5/1/08 - Oi and Grease - D-OOF (CR3) v2 D-OOF MNR F 4/1/08 5/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE _. <1.4 <1.4 4/1/08 -v5/1/08 -Oil and Grease - I-OFG (CR3) v2 I-OFG 1.5 <1.4 4/1/08 5/1/08 pH - Background - D-OOF (CR3) v2 D-OOF 7.97 8.16 4/1/08 5/1/08 pH - Effluent - D-OOF (CR3) v2 D-OOF 7.99 8.13 4/1/08 5/1/08 ýpH - I-OFE (CR3) v2 I-OFE 7.21 7.21 4/1/08 5/1/08 -pH - I-OFG (CR3) v2 I-OFG 8.64 8.9 4/1/08 5/1/08 Residual Ox - Time of Discharge D013 (CR3) D013 0 4/1/08 5/1/08 jSpectrus CT1300 - DOOF (CR3) v2 DOOF 2.25 4/1/08 5/1/08 iTemp Rise - D013 (CR3)v2 D013 14.6 17.3 1~ 10/21/2009 Page 69

Crystal River Sear DMR Data Begnin ate End Date . ARAME -T R NA14E outlII 4/1/08 5/1/08 jTemp-Discharge - D013 (CR3) v2 D013 88.6 i 93.5 4/1/08 5/1/08 ITemp-Intake - D013 (CR3) v2 D013 73.5 79.3 4/1/08 5/1/08 ITotal Ammonia 1-D-OOF (CR3) v2 1-D-0OF MNR 4/1/08 5/1/08 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF .MNR I 4/1/08 5/1/08 5/1/08 FTotal Copper - DOOF (CR3) v2 Total Copper - I-0FG (CR3) v2 7 DOOF I-0FG MNR MNR 4/1/08 MNR 4/1/08 5/1/08 ITotal Iron- D-OOF (CR3) v2 0D-OF IMNR MNR 4/1/08 5/1/08 Total Iron- I-OFG (CR3) v2 I-OFG MNR 4/1/08 5/1/08 Total Recoverable Copper - D-O0F (CR3) v21 D-OOF MNR MNR 4/1/08 5/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF IMNRI MNR 4/1/08 5/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 -__MNR MNR 4/1/08 1 5/1/08 TSS - CD and ECST D-OOF (CR3) v2 D-OOF <4.0 <4.0 4/1/08 5/1/08 TSS - i-OFE (CR3) v2 I-OFE 5.8 _ 5.8 4/1/08 5/1/08 TSS - I-OFG (CR3) v2 I-OFG 10.59 I 22.4 4/1/08 5/1/08 TSS P-D-OOF (CR3) v2 P-D-OOF MNR MNR 4/1/08 5/1/08 TSS Q-D-OOF (CR3) v2 Q-D-OOF MNR MNR 4/1/08 5/1/08 Turbidity - Background - D-ODF (CR3) v2 D-OOF MNR 4/1/08 5/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 4/1/08 5/1/08 Turbidity - Difference D-O0F (CR3) v2 D-OOF MNR 4/1/08 5/1/08 Turbidity - Effluent D-OOF (CR3) v2 D-OOF 5/1/08 6/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF >100 5/1/08 6/1/08 96-Hour Menidia Beryllina Q-D-OOF (CR3) P-D-OOF

MNR 5/1/08 6/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOFp i- * <100 5/1/08 6/1/08 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF MNR 5/1/08 6/1/08 Flow - I-0FE (CR3) v2 I-OFE 4.7097E-05 0.00146 5/1/08 6/1/08 Flow - I-OFG (CR3) v2 I-OFG

                                                                                                            !_0.021762       0.078866 5/1/08      [   6/1/08    Flow-CD System D-OOF (CR3) v2                D-OOF 7       0            0 5/1/08          6/1/08    Flow-ECST D-OOF (CR3) v2                     D-OOF                               [0.001127         0.00718 5/1/08          6/1/08   IFlow-intake - D-OOF (CR3) v2                 D-00F I

I16.934 I

                                                                                                                           ! 34.272 5/1/08 5/1/08 6/1/08 6/1/08 Hydrazine 1-D-OOF (CR3) v2 Hydrazine P 1-D-00F P-D-OOF                fI           -                             MVNR 6/1/08    Hydroquinone 1-D-OOF (CR3) v2              1-D-00F                                                           MVNR 5/1/08 5/1/08          6/1/08    Hydroquinone P-D-OOF (CR3) v2              P-D-OOF
                                                                                           -iI                                          MINR 1-D-OOF                                                           MNR 5/1/08          6/1/08    Morpholine 1-D-OOF (CR3) v2 5/1/08          6/1/08    Morpholine P-D-OOF (CR3) v2                 P-D-OOF MNR 10/21/2009                                                                       Page 70

Crystal River Bear DMR Data Permit No. FL00000159

Be gindate.i -End.Datel PAR NAME -V C-Min_. tC-Max Q-v -ax N0DI-Avg [_ NODI-Max -NODI-Min 1

5/1/08 6/1/08 Number of Batches - I-OFE (CR3)v2 I-OFE -i 1 D-OOF MNR 5/1/08 6/1/08 tOil and Grease - D-OOF (CR3) v2 6/1/08 Oil and Grease - I-OFE (CR3) v2 __I-OFE 2.5 . I 2.5 5/1/08 2 <1.4 5/1/08 6/1/08 Oil and Grease - I-OFG (CR3) v2 I-OFG 5/1/08 6/1/08 pH - Background - D-OOF (CR3) v2 D-OOF 88.18 5/1/08 6/1/08 _pH- Effluent- D-O0F (CR3) v2 D-OOF 8.02 8.22 5/1/08 6/1/08 pH - I-OFE (CR3) v2 -OFE 7.28 7.28 5/1/08 6/1/08 {pH - I-OFG (CR3) v2 I-OFG 8.52 8.85 5/1/08 6/1/08 Residual Ox - Time of Discharge D013 (CR3) D013 10 2.25 5/1/08 6/1/08 Spectrus CT1300 - DOOF (CR3) v2 DOOF 6/1/08 Temp Rise - D013 (CR3) v2 D013 13.7 16.1 5/1/08 6/1/08 Temp-Discharge - D013 (CR3) v2 D013 5/1/08 92 95.7 6/1/08 Temp-intake 1D013 (CR3) v2 D013 5/1/08 78.4 83 6/1/08 Total Ammonia 1-D-OOF (CR3) v2 1-D-ODF MNR 5/1/08 5/1/08 1 6/1/08 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF MNR 6/1108 -[Total Copper- DOOF (CR3)v2 DOOF MNR MNR 5/1/08 MNR 6/1/08 ITotal Copper - I-OFG (CR3) v2 I-OFG 5/1/08 MNR 6/1/08 Total Iron- D-OOF (CR3) v2 D-OOF MNR 5/1/08 I 6/1/08 Total Iron- I-OFG (CR3) v2 I-OFG MNR 5/1/08 6/1/08 Total Recoverable Copper - D-O0F (CR3) v2 D-OOF MNR 5/1/08 MNR 5/1/08 6/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF MNR MVNR 5/1/08

                                                                                                                                      . .. ... . .i.... .MNR-
                                                                                                                                   - -i..                           MNR 6/1/08     ITotal Residual Ox 1-DO13 (CR3) v2          T1-D013 5/1/08          6/1/08    _TSS-CD and ECST D-OOF (CR3)v2      Q              D-OOF                                                                     <4.0      <4.0 5/1/08          6/1/08      TSS - I-OFE (CR3) v2                              I-OFE I-OFG

__ __ 43 <4.0 <4.0 5/1/08 6/1/08 ITSS - I-OFG (CR3) v2 25 5/1/08 6/1/08 ITSS P-D-OOF (CR3) v2 P-D-OOF iMNR MNR 5/1/08 6/1/08 ITSS Q-D-OOF (CR3) v2 Q-D-OOF IMNR MNR 5/1/08 6/1/08 Turbidity - Background - D-OOF (CR3) v2 1 D-OOF 1 -- MVNR 5/1/08 6/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MVNR 5/1/08 6/1/08 Turbidity - Difference D-OOF (CR3) v2 Q D-OOF MVNR D-OF I__I 5/1/08 6/1/08 Turbidity - Effluent D-OOF (CR3) v2 MVNR 6/1/08 7/1/08 [96-Hour Menidia Beryllina P-D-OOF (CR3) [ P-D-OOF MVNR 6/1/08 7/1/08 [96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF MVNR 6/1/08 7/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF MNR 6/1/08 7/1/08 196-Hour Mysidopsis Bahia Q-D-OOF (CR3) [ Q-D-OOF MNR 10/21/2009 Page 71

0 Crystal River sear Permit No. FL00000159 DMR Data ~Begin date E~nd Date -. PARAMETER~ NAM LOutall vg. .. CýMih -Mxi~ Q-Mx NODIAVaýNOIMn 6/1/08 7/1/08 Flow - I-OFE (CR3) v2 I-OFE 0 0 6/1/08 7/1/08 Flow - I-OFG (CR3) v2 I-OFG 0.01704 0.081784 6/1/08 7/1/08 Flow-CD System D-OOF (CR3) v2 D-OOF

                                                                                                               -IJ 7             0 0.002129 0

0.014517 6/1/08 7/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF 6/1/08 7/1/08 Flow-Intake - D-OOF (CR3) v2 D-OOF 15.675 20.304 3987 6/1/08 7/1/08 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF MNR 6/1/08 7/1/08 Hydrazine P-D-OOF (CR3) v2 P-D-OOF MNR 7/1/08 3 Hydroquinone 1-D-OOF MNIR 6/1/08 (CR3) v2 1-D-OOF 7/1/08 Hydroquinone P-D-OOF (CR3) v2 6/1/08 P-D-OOF IVNR 7/1/08 Morpholine 1-D-OOF (CR3) v2 6/1/08 1-D-OOF I 7/1/08 Morpholine P-D-OOF (CR3) v2 6/1/08 P-D-OOF MNR 6/1/08 7/1/08 Number of Batches - I-OFE (CR3) v2 I-OFE 0 0 6/1/08 _Oil7/1/08 and Grease - D-OOF (CR3) v2 D-OOF MINR 6/1/08 7/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE NOD NOD 6/1/08 7/1/08 Oil and Grease - I-OFG (CR3) v2 I-OFG 1.5 <1.4 6/1/08 7/1/08 pH - Background - D-OOF (CR3) v2 D-OOF 8.05 8.14 I _ 6/1/08 7/1/08 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.05 8 .18 6/1/08 7/1/08 [pH - I-OFE (CR3) v2 I-OFE I ___ NOD NOD 6/1/08 7/1/08 pH - I-OFG (CR3) v2 I-OFG 8.41 8 .86 I _ _ _ I 6/1/08 7/1/08 Residual Ox -Time of Discharge D013 (CR3) D013 0 6/1/08 7/1/08 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 6/1/08 7/1/08 Temp Rise - D013 (CR3) v2 D013 1 8.2 11 6/1/08 7/1/08 [Temp-Discharge - D013 (CR3) v2 D013 90.3 9 5.8 6/1/08 7/1/08 Temp-lntake - D013 (CR3) v2 D013 82.2 88 6/1/08 7/1/08 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF - _ MVNR 6/1/08 7/1/08 Total Ammonia P-D-OOF (CR3) v2 Q P-D-OOF __ MINR 6/1/08 7/1/08 Total Copper- DOOF (CR3) v2 DOOF _ _T INR IVN MNR 6/1/08 7/1/08 Total Copper - I-OFG (CR3) v2 I-OFG -- MNR 6/1/08 7/1/08 Total Iron- D-OOF (CR3) v2 D-OOF __ MNR MINR 6/1/08 7/1/08 Total Iron- I-OFG (CR3) v2 I-OFG MNR I MNR 6/1/08 7/1/08 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF IMNR MINR 6/1/08 7/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF IMNR MNR 6/1/08 7/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR 6/1/08 7/1/08 TSS - CD and ECST D-OOF (CR3) v2 D-OOF <4.0 <4.0 6/1/08 7/1/08 TSS - I-OFE (CR3) v2 I-OFE NOD NOD= 10/21/2009 Page 72

Crystal River A ar DMR Data Permit No. FL00000159 Begin date End Date I<< PARAMETER NAMEI OutaII, C.A v C-Myin Q-vC-Max Q-v NoDIl-Avgj NODI-Max NOIDI-Min 6/1/08 7/1/08 TSS - I-OFG (CR3) v2 I-OFG 14. 25 26.2 MNR I MNR 6/1/08 7/1/08 -TSS P-D-OOF (CR3) v2 P-D-OOF ~1 7/1/08 TSS Q-D-OOF (CR3) v2 Q-D-OOF MNR IMNR 6/1/08 7/1/08 Turbidity - Background - D-OOF (CR3) v2 D-OOF MNR 6/1/08 7/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 6/1/08 7/1/08 Turbidity - Difference D-OOF (CR3) v2 D-OOF MNR 6/1/08 Turbidity - Effluent D-OOF (CR3) v2 D-OOF MNR 6/1/08 7/1/08 7/1/08 8/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF 0TH 8/1/08 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF MNR 7/1/08 7/1/08 8/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF MTH 7/1/08 8/1/08 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF MNR 7/1/08 8/1/08 Flow - I-OFE (CR3) v2 *I-OFE 0.000042 1 0.001301 7/1/08 8/1/08 Flow - I-OFG (CR3) v2 I-OFG 0.01985 0.08189 7/1/08 8/1/08 Flow-CD System D-DOF (CR3) v2 D-OOF 0 S0.0015718 0.013967l 7/1/08 8/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF D-OOF 16.6797 20.304 7/1/08 8/1/08 Flow-Intake DOF (CR3) Q2 7/1/08 8/1/08 Hydrazine 1-D-OOF (CR3) Q2 1-D-OOF MNR 7/1/08 8/1/08 Hydrazine P-D-OOF (CR3) v2 F-D-OOF MNR 7/1/08 8/1/08 Hydroquinone 1-D-OOF (CR3) v2 11-D-OOF MNR Hydroquinone P-D-OOF (CR3) v2 P'-D-OOF MNR 7/1/08 8/1/08 - 7i 7/1/08 8/1/08 Morpholine 1-D-OOF (CR3) v2 1-0-ODF 33.838 1 J 7/1/08 8/1/08 Morpholine P-D-OOF (CR3) v2 P-D-OOF MNR S 1 7/1/08 8/1/08 Number of Batches - I-OFE (CR3) v2 I-DFE 8/1/08 Oil and Grease - D-OOF (CR3) v2 D-OOF MNR 7/1/08 7/1/08 8/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE <1.4 <1.4 7/1/08 8/1/08 Oil and Grease - I-OFG (CR3) v2 I-OFG 1.74 3.85 7/1/08 8/1/088 pH - Background - D-OOF (CR3) v2 D-OOF 8.05 8.15 7/1/08 8/1/08 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.04 8.19 7/1/08 8/1/08 pH - I-OFE (CR3) v2 I-OFE 6.94 6.94 -F-7/1/08 8/1/08 pH - I-OFG (CR3) v2 I-OFG 8.1 8.99 7/1/08 8/1/08 Residual Ox - Time of Discharge D013 (CR3) D013 0 7/1/08 8/1/08 Spectrus CT1300 - DOOF (CR3) v2 DO7 2.3 7/1/08 8/1/08 Temp Rise - D013 (CR3) v2 0013 7.4 9.5 7/1/08 8/1/08 Temp-Discharge - D013 (CR3) v2 D013 93.7 96.3 7/1/08 8/1/08 Temp-Intake - D013 (CR3) v2 D013 86.4 89.7 10/21/2009 Page 73

Crystal River iear DMR Data Permit No. FL00000O159 Begin date En\Dt PARAMETER-NAME Outall CAg -i C-ax. Q-A~vg Q-Max ND-v NODI-ax NODI-Min

                                                                                     ]             I       I         I           I           i       ,

7/1/08 8/1/08 Total Ammonia 1-D-OOF (CR3) v2 j 1-D-OOF MNR 7/1/08 8/1/08 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF MNR 7/1/08 8/1/08 ]Total Copper - DOOF (CR3) v2 DOOF MNR MNR 7/1/08 8/1/08 Total Copper - I-OFG (CR3) v2 I-0FG MNR 7/1/08 8/1/08 Total Iron- D-OOF (CR3) v2 D-OOF MNR MNR 7/1/08 8/1/08 Total Iron- I-OFG (CR3) v2 I-OFG MNR 7/1/08 8/1/08 Total Recoverable Copper - D-O0F (CR3) v2, D-OOF MNR MNR 7/1/08 8/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF MNR i- MNR 7/1/08 8/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR MNR 7/1/08 8/1/08 TSS - CD and ECST D-OOF (CR3) v2 D-OOF <4.0 <4.0 7/1/08 8/1/08 TSS - I-OFE (CR3) v2 I-OFE <4.0 <4.0 7/1/08 8/1/08 TSS- I-OFG (CR3) v2 I -OFG 22.74 33.3 7/1/08 8/1/08 TSS P-D-OOF (CR3) v2 P-D-OOF MNR MNR 1 7/1/08 8/1/08 TSS Q-D-OOF (CR3) Q l Q-D-OOF - I -- MNR MNR 7/1/08 8/1/08 Turbidity - Background - D-OOF (CR3) v2 D-OOF MNR 7/1/08 8/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 7/1/08 8/1/08 Turbidity_- Difference D-OOF (CR3) v2 j D-OOF I MNR 7/1/08 8/1/08 Turbidity - Effluent D-OOF (CR3) v2 D-OOF -- MNR 8/1/08 9/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF OPS 8/1/08 9/1/08 96-Hour Menidia Beryllina Q-D-OEF (CR3) Q-D-OOF I MNR 8/1/08 9/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF OPS 8/1/08 9/1/08 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) I Q-D-OOF MNR 8/1/08 9/1/08 Flow - I-OFE (CR3) v2 _H I-DE 0 0 8/1/08 9/1/08 [Flow - I-OFG (CR3) v2 I-OFG 0.018452 0.074815 8/1/08 9/1/08 Flow-CD System D-OOF (CR3) v2 D-OOF 0.0217335 0.67374 8/1/08 9/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF 0.002045 0.007381 8/1/08 9/1/08 IFlow-Intake - D-OOF (CR3) Q D-O0F 17.748774 29.52 8/1/08 9/1/08 Hydrazine 1-D-O0F (CR3) v2 1-D-O0F MNR 8/1/08 9/1/08 Hydrazine P-D-OOF (CR3) v2 P-D-OOF MNR 8/1/08 9/1/08 lHydroquinone 1-D-OOF (CR3) v2 1 1-D-DOF MNR 8/1/08 9/1/08 ]Hydroquinone P-D-OOF (CR3) v2 P-D-O0F MNR 8/1/08 9/1/08 Morpholine 1-D-O0F (CR3) v2 1-D-DOF 23.94 8/1/08 9/1/08 iMorpholine P-D-OOF (CR3)v2 P-D-OOF MNR 8/1/08 9/1/08 Number of Batches - I-DFE (CR3) v2 I-OFE 0 0 8/1/08 9/1/08 Oil and Grease - D-OOF (CR3) v2 D-DDF MNR 10/21/2009 Page 74

C Crystal River siear DMR Data Permit No. FL00000159

 ~B~ ~         ndate'                 PARAMETER NAME>:;7                                   Avgw     C->   -- C-Maxw                   A,.:        v_____

u-,v~uvax D W____ NODI-Mifl 9/1/08 Oil and Grease - I-OFE (CR3) v2 I-OFE NOD NOD 8/1/08 8/1/08 9/1/08 Oil and Grease - I-OFG (CR3) v2 I-OFG 1.41 5.75 8/1/08 9/1/08 pH - Background - D-OOF (CR3) v2 D-00F 7.9 8.17 8/1/08 9/1/08 pH - Effluent - D-OOF (CR3) v2 D-OOF 7.95 8.12 I-OFE NOD NOD 8/1/08 9/1/08 pH - I-OFE (CR3) v2 8.21 8.91 8/1/08 9/1/08 pH - I-OFG (CR3) v2 I-OFG 8/1/08 9/1/08 Residual Ox - Time of Discharge D013 (CR3) D013 0 8/1/08 9/1/08 Spectrus CT1300 - DOOF (CR3) v2 DOOF 0 8/1/08 9/1/08 [Temp Rise - D013 (CR3) v2 D013 8.3 12.4 8/1/08 9/1/08 Temp-Discharge - D013 (CR3) v2 D013 92 95.8 8/1/08 9/1/08 Temp-Intake - D013 (CR3) v2 D013 82.9 88 8/1/08 9/1/08 Total Ammonia 1-D-00F (CR3) v2 1-0-O0F MNR 8/1/08 9/1/08 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF MVNR 8/1/08 9/1/08 ITotal Copper - DOOF (CR3) v2 D00F MVNR MNR 8/1/08 9/1/08 [Total Copper - I-0FG (CR3) v2 I-OFG MNR 8/1/08 9/1/08 [Total Iron- D-DOF (CR3) v2 0D-DF MNR 8/1/08 9/1/08 ITotal Iron- I-OFG (CR3) v2Q I-OFG [N R MNR 8/1/08 9/1/08 ITotal Recoverable Copper - D-OOF (CR3) v2 I D-OOF MNR 8/1/08 [Total Recoverable Iron - D-OOF (CR3) v2 D-OOF MNR MNR 1-9/1/08 8/1/08 9/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR MNR 8/1/08 9/1/08 TSS - CD and ECST 0-DE (CR3) v2 0 <4.0 <4.0 8/1/08 9/1/08 TSS - I-OFE (CR3) v2 I-OFE NO D NOD 8/1/08 9/1/08 TSS - I-OFG (CR3) v2 I-OFG 22.24 40.7 8/1/08 9/1/08 TSS P-D-00F (CR3) v2 P-D-O0F MNR MNR 8/1/08 9/1/08 [TSS Q-D-OOF (CR3) v2 Q-D-OOF MNR MNR 8/1/08 1 9/1/08 [Turbidity - Background - D-OOF (CR3) v2 D-OOF MNR 8/1/08 1-9/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 8/1/08 9/1/08 Turbidity - Difference D-DOF (CR3) v2 D-DOF MNR 8/1/08 9/1/08 Turbidity - Effluent D-DOF (CR3) v2 D-DOF MNR 9/1/08 10/1/08 96-Hour Menidia Beryllina P-D-00F (CR3) I P-D-OOF OTH 9/1/08 10/j/08 96-Hour Menidia Bery lina Q-D-O* (CR3) I -D-OOF MVNR 9/1/08 I10/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF OTH 9/1/08 10/1/08 [96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-00F MNR 9/1/08 10/1/08 [Flow - I-OFE (CR3) v2 I-OFE 0.001268 1 0.000042 9/1/08 10/1/08 IFlow - -OFG (CR3) v2 i -OEG 0.023498 0.07798 10/21/2009 Page 75

Crystal River Oear DMR Data Permit No. FL00000159 Begin date End Date ' PRMENA uta..

                                                                            .C-.Avg1.                ,"      i         C-ax        Q-Avg   Q-Max   N0DI-Avg        NODI-Max   NODI-Min I             I 9/1/08          10/1/08    Flow-CD System D-OOF (CR3) v2                  D-OOF I

0 0 9/1/08 10/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF 0.003261 0.014277 --',I-9/1/08 10/1/08 Flow-Intake - D-OOF (CR3) v2 D-OOF 15.782367 20.3 9/1/08 10/1/08 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF MNR i 9/1/08 10/1/08 Hydrazine P-D-OOF (CR3) v2 P-D-OOF

                                                                                                                                  !                  MNR MNR 9/1/08          10/1/08    Hydroquinone 1-D-OOF (CR3) v2                1-D-OOF
                                                                                                                              !MNR                   MNR MVNR 9/1/08          10/1/08   lHydroquinone P-D-OOF(CR3) v2                 P-D-00F         _

9/1/08 10/1/08 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 34.18 10/1/08 Morpholine P-D-OOF (CR3)v2 Q P-D-OOF 9/1/08 MNR

                                                                                                                           ..  -               1 9/1/08          10/1/08    Number of Batches - I-OFE (CR3) v2             I-OFE                   T -         ...- .                1 9/1/08          10/1/08    Oil and Grease - D-OOF (CR3) v2                D-OOF       _                                                                             MNR 9/1/08          10/1/08    Oil and Grease   - I-OFE (CR3) v2              I-OFE           2.34        9               2.34 9/1/08          10/1/08    Oil and Grease - I-OFG (CR3) v2                I-OFG           1.43         ______4.37 9/1/08          10/1/08    pH - Background - D-OOF (CR3) v2               D-OOF                   J    7.91           8.16 9/1/08          10/1/08    pH - Effluent - D-OOF (CR3) v2                 D-OOF                        7.98           8.16 9/1/08          10/1/08    pH - I-OFE (CR3) v2                            I-OFE                                                                                     6.75       6.75 9/1/08          10/1/08    pH - I-OFG (CR3) v2                            I-OFG                        8.58           8.94 9/1/08          10/1/08    Residual Ox -Time of Discharge D013 (CR3)      D013-                                    _  2.15 9/1/08          10/1/08    Spectrus CT1300 - DOOF (CR3) v2                DOOF 9/1/08          10/1/08    Temp Rise - D013 (CR3) v2        _D013                          7.4
                                                                                                        ,I          ,I 9.5 9/1/08          10/1/08   ITemp-Discharge - D013 (CR3) v2                 D013            93.7    I                I  96.3 9/1/08          10/1/08    Temp-lntake - D013 (CR3) v2                    D013            86.4                        89.7 9/1/08         10/1/08    ITotal Ammonia 1-D-OOF (CR3) v2               1-D-OOF                                                                     MNR 9/1/08          10/1/08   !Total Ammonia P-D-00F (CR3) v2               P-D-OOF                                                                     MNR 9/1/08          10/1/08    Total Copper - DOOF (CR3) v2              !    DOOF                                                                      MNR             MNR 9/1/08         10/1/08     Total Copper - I-OFG (CR3) v2               I-OFG                                                                                        MNR 9/1/08         10/1/08    ýTotal Iron- D-OOF (CR3) v2                     D-OOF                                                                     MNR             MNR 9/1/08         10/1/08     Total Iron- l-OFG (CR3) v.                     I-OFG                                                                                     MNR 9/1/08         10/1/08     Total Recoverable Copper - D-OOF (CR3) v2      D-00 F                                                                    MNR             MNR 9/1/08         10/1/08    iTotal Recoverable Iron - D-OOF (CR3) v2        D-OOF                                                                     MNR             MNR 9/1/08         10/1/08    iTotal Residual Ox 1-D013 (CR3) v2             1-D013                                                                     MNR             MNR 9/1/08         10/1/08    !TSS - CD and ECST D-OOF (CR3) v2               D-OOF                                                                     <4.0            <4.0 9/1/08         10/1/08    JTSS - I-OFE (CR3)v2                            IiOFE                                                                      <4              <4 9/1/08          10/1/08  -TSS    - I-OFG (CR3) v2                          I-OFG           9.65                        25.7 9/1/08          10/1/08    ITSS P-D-OOF (CR3) v2                         P-D-OOF                                                                    MNR              MNR    I 10/21/2009                                                                              Page 76

Crystal River f ear DMR Data Permit No. FL00000159 4?,~.P'IA RAMETERN[NAIiE.ý Kw j;J.K~C-a ND-i MNR IMNR 9/1/08 10/1/08 TSS Q-D-OOF (CR3) v2 Q-D-OOF i 10/1/08 Turbidity - Background - D-OOF (CR3) v2 D-OOF 1 MNR I 9/1/08 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF t MNR i -- 9/1/08 10/1/08 t 9/1/08 10/1/08 Turbidity - Difference D-OOF (CR3) v2 D-OOF I. I ! MVNR D-00F MNR 9/1/08 10/1/08 Turbidity - Effluent D-OOF (CR3) v2 10/1/08 11/1/08 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF MNR 10/1/08 11/1/08 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF MNR 0 10/1/08 11/1/08 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF -- I- - MVNR 10/1/08 11/1/08 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-00F MNR 10/1/08 11/1/08 Flow - I-OFE (CR3) v2 I-OFE 0.00003871 0.0012 10/1/08 11/1/08 Flow - I-OFG (CR3) v2 I-OFG 0.019636

                                                                                                                               -!0.00003711   0.080388  [

10/1/08 11/1/08 Flow-CD System D-OOF (CR3) v2 D-OOF 01 10/1/08 11/1/08 Flow-ECST D-OOF (CR3) v2 D-OOF 0.013985

                                                                                                     - .1                                              1i 10/1/08           11/1/08    Flow-Intake - D-OOF (CR3) v2                      D-OOF                                              15.882645  K     21 10/1/08           11/1/08    Hydrazine 1-D-OOF (CR3) v2                       1-D-OOF        _                                iI                             MNR 10/1/08           11/1/08    Hydrazine P-D-OOF (CR3) v2                       P-D-OOF                                                                        MNR N

10/1/08 11/1/08 lHydroquinone 1-D-OOF (CR3) v2 1-D-OOF T MNR M 10/1/08 11/1/08 -Hydroquinone P-D-OOF (CR3)v2 P-D-OOF MVNNR 10/1/08 11/1/08 Morpholine 1-D-OOF (CR3) v2 1-D-OOF I 38.556 10/1/08 11/1/08 [Morpholine P-D-OOF (CR3) v2 P-D-OOF _ MVNNR 1 10/1/08 11/1/08 Number of Batches - I-OFE (CR3) v2 I-OFE ~1~~~~ V 10/1/08 1/1/08 Oil and Grease - 0-OOF (CR3) Q2 D ~~1 10/1/08 11/1/08 Oil and Grease - D-OFE (CR3) v2 ID-OFE 1.5 10/1/08 11/1/08 Oil and Grease - I-OFG (CR3) v2 l-OFG--*

                                                                                     .                              2.38      i                              <1.4
                                                                                                                          -- E-10/1/08           11/1/08    pH - Background - D-OOF (CR3) v2                  D-OOF                        7.91     8.16 Jl 10/1/08           11/1/08    pH-   Effluent - D-OOF (CR3) v2        -          D-OOF                                 o,.LJ 10/1/08           11/1/08   pH   - I-OFE (CR3) v2                            I-OFE                                                                                                      6.84                      6.84 10/1/08           11/1/08    pH  - I-OFG (CR3)v2                           -    I-OFG                       6.62      8.8 A.-

10/1/08 11/1/08 Residual Ox - Time of Discharge D013 (CR3)1 D013 0 10/1/08 11/1/08 ISpectrus CT1300 - DOOF (CR3) v2 DOOF 2.2 10/1/08 11/1/08 ITemp Rise- D013 (CR3) v2 J D013 13.6 16.6 10/1/08 11/1/08 ITemp-Discharge - D013 (CR3) v2 1D013 [ 5.9 95.8 10/1/08 11/1/08 FTemp-Intake - D013 (CR3)v2 D013 72.4 81.9 10/1/08 11/1/08 ITotal Ammonia 1-D-OOF (CR3) v2 1-D-OOF MNR 10/1/08 11/1/08 Total Ammonia P-D-OOF (CR3) v2 }P-D-OOF _ VN R 10/21/2009 Page 77

Crystal River S ear DMR Data Permit No. FL00000159 eg pa Begindate L' E....Date.. EdDt k .** ...... ... ',* PARAMETER-NAME

                                                                 **   *@ ... -*    Outa Outal C-Avg C-C-i n'" i    C,'Max*,

C-a I Q-A........~ v Q-Max h NODI-Avg~ NODIkMax DI-i i I I I I I 11/1/08 Total Copper - DOOF (CR3) v2 DOOF MNR MNR 10/1/08 10/1/08 11/1/08 Total Copper - I-OFG (CR3) v2 I-OFG IJ- MNR 11/1/08 Total Iron- D-OOF (CR3) v2 D-OOF MNR MNR 10/1/08 MNR 10/1/08 11/1/08 Total Iron- I-OFG (CR3) v2 Total Recoverable Copper - D-OOF (CR3) v2 I-OFG D-OOF

                                                                                                                                   !                                MNR           MNR 10/1/08         11/1/08 10/1/08          11/1/08        Total Recoverable Iron - D-O0F (CR3) v2            D-OOF                                                                            MNR           MNR 11/1/08         Total Residual Ox 1-DO13 (CR3) v2                 1-D013                                                                            MNR          MNR 10/1/08 10/1/08          11/1/08       ITSS  - CD and ECST D-OOF (CR3) v2                  D-OOF                                                                             <4.0         <4.0 10/1/08          11/1/08       ]TSS - I-OFE (CR3) v2                                I-OFE                                                                             <4           <4 10/1/08          11/1/08      ITSS - ,-FG (CR3)v2   Q                               -OFG         7.62                   i   9.5 10/1/08          11/1/08       ITSS P-D-OOF (CR3) v2                              P-D-OOF                                                                            MNR          MNR 10/1/08          11/1/08       !TSS Q-D-OOF (CR3) v2                  _          Q-D-OOF     .                                                                      MVNR          MNR 10/1/08       -- 111/1/08  ---- Tur-bidity - Background -0D-00F (CR3) v2           D-OOF                                           4--                                            MVNR D-00-COF                                                                                       MNR 10/1/08          11/1/08 JTurbidity - Calc Limit - D-OOF (CR3) v2 10/1/08          11/1/08        Turbility - Difference D-OOF (CR3) v2              0                                                                                          MNR 10/1/08          11/1/08       iTurbidity - Effluent D-OOF (CR3) v2                D-OOF                                                                                          MNR 11/1/08          12/1/08        96-Hour Menidia Beryllina P-D-OOF (CR3)           P-D-OOF                                                                                                >100 11/1/08          12/1/08        96-Hour Menidia Beryllina Q-D-OOF (CR3)          Q-D-OOF                                                                                                 MNR 11/1/08          12/1/08        996-Hour Mysidopsis Bahia P-D-OOF (CR3) v21       P-D-OOF     I                                                                                          >100 11/1/08          12/1/08        96-Hour Mysidopsis Bahia Q-D-OOF (CR3)           Q-D-OOF     }                                                                                           MNR 11/1/08          12/1/08       !Flow - I-OFE (CR3) v2                               I-OFE     I                                       0.000043        0.001281 11/1/08          12/1/08        Flow - I-OFG (CR3) v2                               I-OFG                                             0.023665      1  0.08383 11/1/08          12/1/08        Flow-CD System D-OOF (CR3) v2                      D-OOF                                                   0              0 11/1/08          12/1/08        Flow-ECST D-OOF (CR3) v2                           D-O0       I                                         0.0014        0.013769 12/1/08       IFlow-Intake - D-OOF (CR3) v2                       D-OOF 11/1/08                                                                           1-D-OOF                                              17.69467         29.52 12/1/08        Hydrazinel-D-00F(CR3) v2 11/1/08                                                                           P-D-OOF                                                                            MNR 12/1/08       iHydrazine P-D-OOF (CR3) v2 11/1/08          12/1/08        Hydroquinone 1-D-OOF (CR3) v2                     1-D-OOF                                                                            MNR 11/1/08          12/1/08       1Hydroquinone P-D-OOF (CR3) v2                     P-D-OOF     1                                                                      MNR 11/1/08          12/1/08   -    Morpholine    1-D-OOF_(CR3)v2                   1-D-OOF         27.96                                                               .     .    .NR 11/1/08          12/1/08       IMorpholine P-D-OOF (CR3) v2                       P-D-OOF       2 11/1/08          12/1/08         Nb                              ___0                                                                                                MNR I-OFE                                                  1 1    I 11/1/08          12/l/          Number of Batches - I-OFE (CR3) v2 11/1/08          12/1/08       1Oil and Grease - D-OOF (CR3) v2                    D-OOF                                                                                          MNR 11/1/08          12/1/08     lOil and Grease     - I-OFE (CR3)v2                    I-OFE                                                                            <1.4         <1.4 11/1/08          12/1/08        Oil and Grease   - i-OFG (CR3)v2                    I-OFG        2.54                      10.5 10/21/2009                                                                                     Page 78

Crystal River S ear DMR Data Permit No FLOO000159 IBeg dateg .End Date .ARAMETER..NAME Outa C-Avg ~C-Min\ C-ua -Avg Q-Max NODI-Avg ND-Ma OD-i 11/1/08 12/1/08 pHH-Background - D-OOF (CR3) v2 D-OOF 8 8.5 11/1/08 12/1/08 pH - Effluent - D-OOF (CR3) v2 D-OOF S 7.89 i 8.21 11/1/08 12/1/08 pH - I-OFE (CR3) v2 I-OFE 7.05 7.05 11/1/08 12/1/08 pH - I-OFG (CR3) v2 I-OFG 8.33 8.66 11/1/08 12/1/08 [Residual Ox -Time of Discharge D013 (CR3)- D013 0 11/1/08 12/1/08 Spectrus CT1300 - DOOF (CR3) v2 DOOF 2.3 F 11/1/08 12/1/08 ITemp Rise- D013 (CR3) v2 D013 16.6 i 18.1 11/1/08 12/1/08 Temp-Discharge - D013 (CR3)v2 0013 73.4 90.3 11/1/08 12/1/08 ITemp-Intake - D013 (CR3) v2 Q D013 64.6 78 11/1/08 12/1/08 !Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF MNR 11/1/08 12/1/08 iTotal Ammonia P-D-OOF (CR3) v2 P-D-OOF MNR 11/1/08 12/1/08 Total Copper - DOOF (CR3) v2 DOOF MNR MNR 11/1/08 12/1/08 'Total Copper - I-OFG (CR3) v2 I-OFG MNR 11/1/08 _ 12/1/08 Total Iron- D-OOF (CR3) v2 - D-OOF MNR MNR 11/1/08 12/1/08 Total Iron- I-OFG (CR3)2 I-OFG MNR 11/1/08 12/1/08 Total Recoverable Copper - D-OOF (CR3) v2 D-0OF MNR MNR 11/1/08 12/1/08 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF MNR MNR 11/1/08 12/1/08 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR MNR 11/1/08 j 12/1/08 TSS - CD and ECST D-OOF (CR3) v2 D-OOF <4.0 <4.0 11/1/08 12/1/08 Tss-l-OFE (CR3)v 2 / -OFE <4 <4 11/1/08 12/1/08 ITSS - I-OFG (CR3) v2 I-OFG 10.09 19.9 11/1/08 12/1/08 iTSS P-D-OOF (CR3) v2 P-D-OOF MNR MNR 11/1/08 12/1/08 ITSS Q-D-OOF (CR3) v2 Q-D-OOF MNR MNR 11/1/08 12/1/08 ITurbidity - Background - D-OOF (CR3) v2 D-OOF MNR 11/1/08 12/1/08 iTurbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR

  -1/1/08          12/1/08    -Turbidity - Difference D-OOF (CR3) v2                  D-OOF    ,                                                                       MNR Ii 11/1/08           12/1/08      Turbidity  - Effluent    OF (CR3) 2                     0-OF
                                                                                        --                                                                             MNR 12/1/08           1/1/09       96-Hour Menidia Beryllina P-D-OOF (CR3)        IP-D-OOF                                                                                         MNR 12/1/08           1/1/09       96-Hour Menidia Beryllina Q-D-OOF (CR3)             Q-D-OOF                                                                                  1  MNR 12/1/08           1/1/09      196-Hour Mysidopsis Bahia P-D-OOF (CR3) v21          P-D-OOF                                                                                     MNR 12/1/08           1/1/09       96-Hour Mysidopsis Bahia Q-D-OOF (CR3)              Q-D-OOF                                                                                     MNR 12/1/08           1/1/09      FFlow  - I-OFE (CR3) v2                                kOFE                                      3.9935E-05         0.001238 12/1/08           1/1/09       Flow - I-OFG (CR3) v2                                 I-OFG                                      0.0225981         0.084223 12/1/08           1/1/09       Flow-CD System D-OOF (CR3) v2                         D-OOF                                     10 0

12/1/08 1/1/09 Flow-ECST D-OOF (CR3)v2 D-00F 3 114 16 0.06 j 0.0 1382 10/21/2009 Page 79

Crystal River Sear DMR Data Permit No. FL00000159 Ben dPARAMETER NAME Outall C-Avg C-Mn _-Max_____ ... Q-Avg, .. Q-Max` NOD -Avg- NODI-Max> NODI-Min D-00F 19.12455 29.52 12/1/08 1/1/09 Flow-Intake - D-OOF (CR3)v2 1-D-OF 12/1/08 1/1/09 Hydrazine 1-D-OOF (CR3) v2 v1NR P-D-OOF 12/1/08 1/1/09 Hydrazine P-D-OOF (CR3) v2 vINR 1-D-OOF 12/1/08 1/1/09 lHydroquinone 1-D-OOF (CR3) v2 MANR 12/1/08 1/1/09 Hydroquinone P-D-00F (CR3) v2 P-D-OOF I-

                                                                                                                                 ----------------..                vINR
                                                                                                                               -.-.-             K 12/1/08        1/1/09  1orpholine I-D-OOF (CR3) Qv                     1-D-OOF          31.056 12/1/08        1/1/09  Morpholine P-D-OOF (CR3) v2                     P-D-OOF                                                                                      vINR 12/1/08      - 1/1/09  Number of Batches        - I-OFE (CR3) v2         I-OFE                                                                            1 12/1/08        1/1/09  Oil and Grease - D-OF (CR3) v2                    D-OOF                                                                                                  MNR 12/1/08        1/1/09  Oil and Grease - I-OFE (CR3) v2                   I-OFE             1.62                 1.62 1.46 12/1/08        1/1/09 [Oil and Grease     - I-OFG (CR3) v2               I-OFG                                  5.75 12/1/08        1/1/09  pH - Background - D-OOF (CR3) v2                  D-00F                        7.97       8.1 12/1/08        1/1/09  pH - Effluent - D-O0F (CR3) v2                    D-OOF                        8.04      8.16 12/1/08        1/1/09 [pH  -    -OFE (CR3) v2                            I-OFE                                                                                                   7.11     7.11 12/1/08        1/1/09  pH  -   I-OFG (CR3) v2                            I-OFG                        7.88      8.89 12/1/08        1/1/09  Residual Ox - Time of Discharge D013 (CR3)        D013 12/1/08        1/1/09 ISpectrus CT1300 - DOOF (CR3) v2                   DOOF                                     2.4 12/1/08        1/1/09 ýTemp Rise - D013 (CR3) v2                         D013      j       16.3                   18 12/1/08        1/1/09 ITemp-Discharge - D013 (CR3) v2                    D013__            78.2                 85.1 12/1/08        1/1/09  Temp-Intake - D013 (CR3) v2                       0013              61.8                  66.6 12/1/08        1/1/09  Total Ammonia 1-D-OOF (CR3) v2                  1-D-OOF       _                                                                              MNR 12/1/08        1/1/09  Total Ammonia P-D-OOF (CR3) v2                  P-D-OOF      _                                                                               MNR 12/1/08        1/1/09  Total Copper - DOOF (CR3) v2                      DOOF                                                                                       MNR         Mv1NR 12/1/08        1/1/09 ITotal Copper - I-OFG (CR3) v2                     I-OFG                                                                                                  MNR 12/1/08        1/1/09  Total Iron- D-OOF (CR3) v2                        D-OOF                                                                                      MNR         MNR 12/1/08        1/1/09  Total Iron- I-OFG (CR3) v2                        I-0FG                                                                                                  MNR M

12/1/08 1/1/09 Total Recoverable Copper - D-OOF (CR3) v2 D-00F NR MNR 12/1/08 1/1/09 Total Recoverable Iron QOF (CR3) v2 D-OOF MNR i MNR 12/1/08 1/1/09 Total Residual Ox 1-Do13 (CR3) v2 1-D013 MNR MNR 12/1/08 1/1/09 TSS - CIDand ECST D-OOF (CR3) v2 D-OOF I <4.0 <4.0 12/1/08 1/1/09 TSS - I-OFE (CR3) v2 I-OFE <4 <4 12/1/08 1/1/09 ýTSS - I-OFG (CR3) v2 I-OFG 20.68 3 7.6 12/1/08 1/1/09 TSS P-D-OOF (CR3) v2 P-D-OOF , I MNR MNR 12/1/08 1/1/09 TSS Q-D-OOF (CR3) 2 Q-D-OOF MNR L MNR FD-OOF ___ 12/1/08 1/1/09 Turbidity - Background - D-OOF (CR3) v2 MNR 10/21/2009 Page 80

Crystal River Dear DMR Data Permit No. FL00000159 at-Begn[ n Dtý PARAMETER NAME OU1 ý,T~ Cn-~ Ca -vg -ax NODI-Avg. NNobM ND-Min. 12/1/08 1/1/09 Turbidity - Calc Limit - D-OOF (CR3) v2 I MNR I D-OOF _ 1/1/09 Turbidity - Difference D-OOF (CR3) v2 MNR 12/1/08 12/1/08 1/1/09 1/1/09 2/1/09 Turbidity - Effluent D-OOF (CR3) v2 96-Hour Menidia Beryllina P-D-O0F (CR3) oOOOF P-D-OEF 0 MNR

                                                                                                                                                                              > 100 96-Hour Menidia Beryllina Q-D-OOF (CR3)      Q-D-OOF                                                                                                    MNR 1/1/09         2/1/09 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2     P-D-OOF                                                                                                  > 100 1/1/09          2/1/09 96-Hour Mysidopsis Bahia Q-D-OOF (CR3)        Q-D-O0F i                                                                            MNR 1/1/09         2/1/09 1/1/09          2/1/09  Flow - I-OFE (CR3) v2                           I-OFE                                                                 0
                                                                                                                                                            -I-    ---      -

I-0FG 0.0192939 0.082759 1/1/09 2/1/09 Flow - I-OFG (CR3) v2 1/1/09 2/1/09 Flow-CD System D-OOF (CR3) v2 D-OOF 0.00874113 0.270975 1/1/09 2/1/09 Flow-ECST D-OOF (CR3) v2 D-OOF 0.0020959 0.013998 SD-OOF 18.608 34.272 1/1/09 2/1/09 Flow-Intake - D-OOF (CR3) v2 1/1/09 2/1/09 Hydrazine 1-D-O0F (CR3) v2 1-D-OOF MNR 1/1/09 2/1/09 Hydrazine P-D-O0F (CR3) v2 P-D-00F 7-- MNR 2/1/09 Hydroquinone 1-D-OOF (CR3) v2 1D-00F 1/1/09 MNR P-D-00F MNR 1/1/09 2/1/09 Hydroquinone P-D-00F (CR3) v2 1/1/09 2/1/09 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 31.49 ___I MNR 1/1/09 2/1/09 Morpholine P-D-OOF (CR3) v2 P-D-OOF 1/1/09 2/1/09 Number of Batches - I-OFE (CR3) v2 -L I-OFE .I 0 Oil and Grease - D-OOF (CR3) v2 D-00F MNR 1/1/09 2/1/09 1/1/09 2/1/09 Oil and Grease - I-OFE (CR3) v2 I-OFE NOD NOD 1/1/09 2/1/09 Oil and Grease - I-OFG (CR3) v2 I-OFG ! 1.4 2.63 1/1/09 2/1/09 'pH - Background - D-OOF (CR3) v2 C-OOF 8.02 1 8.16 1/1/09 2/1/09 tpH - Effluent- D-OOF (CR3) v2 D-OOF 8.01 8.21 NOD Fi7 1/1/09 2/1/09 pH - I-OFE (CR3) v2 I-OFE NOD 1/1/09 2/1/09 pH - I-OFG (CR3) v2 I-OFG - ... . .. 8.06 8.89 1/1/09 2/1/09 Residual Ox -Time of Discharge D013 (CR3) D013 0 1/1/09 2/1/09 Spectrus CT1300 - DOOF (CR3) v2 DOOF 1.92 1/1/09 2/1/09 Temp Rise - D013 (CR3) v2 D013 -14.8 17.8 . . 1/1/09 2/1/09 Temp-Discharge - D013 (CR3) v2 D013 73.9 1[~84.8 1/1/09 2/1/09 Temp-Intake - D013 (CR3) v2 D013 59.2 -I- 68.3 ~1 -. 1/1/09 2/1/09 Total Ammonia 1-D-DOF (CR3) v2 J 1-D-OOF MNR 1/1/09 2/1/09 Total Ammonia P-D-OOF (CR3) v2 P-D-0OF MNR

                                                                                                                     -______1 1/1/09         2/1/09  Total  Copper - DOF (CR3) v2                    DOOF                                                                         MNR           MNR 1/1/09         2/1/09  Total Copper - I-OFG (CR3) v2                    -OFG                                                                                      MNR     I 10/21/2009                                                                              Page 81

Crystal River Sear DMR Data Permit No. FL00000159 Be Riidate> Dat E*!nd . 'PARAMETER NAME 0.i6tali~ D-OOF

h. AP C-Min

.~~>

IC-Mane - i-Aw I -M~x NODfI-Avoi _________ I N 61 aflIM U I. NODI-`Min-1/1/09 2/1/09 Total Iron- D-OOF (CR3) v2 D-OOF lii - IMNR MNR 1/1/09 2/1/09 Total Iron- I-OFG (CR3) v2 1/1/09 2/1/09 [Total Recoverable Copper v - D-OOF (CR3) I-OFG MNR D-OOF MNR MNR 1/1/09 2/1/09 ITotal Recoverable Iron - D-OOF (CR3) v2 D-OOF _, _ ,_ MNR MNR I-1/1/09 2/1/09 ITotal Residual Ox 1-D013 (CR3) v2 1-DO13 MVNR MVNR 1/1/09 2/1/09 TSS - CD and ECST D-OOF (CR3) v2 D-OF _ 1 _ <4.0 <4.0 1/1/09 -2/1/09 ITSS -I-OFE (ca3) v2 .-OFE l - i " NOD 1 NOD 1/1/09 1/1/09 2/1/09 2/1/09 TSS - I-OFG (CR3) v2 TSS P-D-OOF (CR3) v2 I-OFG 14.38 1_ 23.7 P-D-OOF _ _ _ _ MNR MNR 1/1/09 2/1/09 ITSS Q-D-OOF (CR3) v2 Q-D-OOF MNR MNR 1/1/09 2/1/09 [Turbidity - Background - D-OOF (CR3) v2 D-OOF MNR 1/1/09 2/1/09 [Turbidity - Calc Limit - D-OOF (CR3) v2 __D-OOF

                                                                                 -00__  [__-            I

___ MNR 1/1/09 2/1/09 Turbidity - Difference D-OOF (CR3) v2 SD-OOF ID-OOF_ __ MNR 1/1/09 2/1/09 Turbidity - Effluent D-OOF (CR3) v2 MNR 2/1/09 3/1/09 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF MNR 2/1/09 3/1/09 96-Hour Menidia Beryllina O-D-OOF (CR3) Q-D-OOF MNR 2/1/09 3/1/09 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF MNR 2/1/09 3/1/09 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-OOF MNR 2/1/09 3/1/09 Flow - I-OFE (CR3) v2 I-OFE 0.000046 0.001296 2/1/09 3/1/09 Flow - I-OFG (CR3) v2 I-OFG _ I -F0.02011 0.08355 2/1/09 3/1/09 -Flow-COD System D-OOF (CR3) V2 T 0.00652 0.182539 2/1/09 3/1/09 Flow-ECST D-OOF (CR3) v2 D-OOF D-OOF I- - 0.00394 0.014088 2/1/09 3/1/09 Flow-Intake - D-OOF (CR3) v2 18.586 29.52 _ 2/1/09 3/1/09 Hydrazine 1-D-OOF (CR3) v2 I 1-D-OOF I MVNR 2/1/09 3/1/09 Hydrazine P-D-OOF (CR3) v2 P-D-OOF IF MNR 2/1/09 3/1/09 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF 2/1/09 3/1/09 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF - MNR 2/1/09 3/1/09 Morpholine 1-D-OF (CR3) v2 1-D-OOF 41.56 2/1/09 3/1/09 Morpholine P-D-OF (CR3) v2 P-D-OF MNR 2/1/09 3/1/09 Number of Batches - I-OFE (CR3) v2 1 -OFE 2/1/09 3/1/09 Oil and Grease - D-OOF (CR3) v2 D-OOF MNR I *I _ _ 2/1/09 3/1/09 Oil and Grease - I-OFE (CR3) v2 I-OFE < 1.4 < 1.4 2/1/09 3/1/09 Oil and Grease - I-OFG (CR3) v2 Q-0FG I 2.07 2/1/09 3/1/09 pH - Background - D-OOF (CR3) v2 D-OOF 8 8.17 - 2/1/09 3/1/09 PH - Effluent - D-OOF (CR3) v2 D-OOF F 8.12 8.2 _ _ _ 10/21/2009 Page 82

Crystal River

ear DMR Data Permit No. FL00000159 Begin date ~End Date~i PArRAMVETER-NM 06tall~ ,

C-vg, 7.<:C-Avg J , M

                                                                                                          . ',*C-Min*.    ,<C-..

, C -Ma N* x>. < k .Av.g.

O.A 9g . PQ .Max _M"

                                                                                                                                                                       *7' ' - O       4
                                                                                                                                                                                    -Av 1, NODI-Ma r; OI,Ma JNoI-g  O IM n x "NODI-Min 2/1/09           3/1/09      PH      - i-OFE (CR3) v2                            I-OFE                                                                                                           6.95       6.95 8.23         8 2/1/09           3/1/09     ]pH - i-OFG (CR3) v2                                    I-OFG                                        .98 0

2/1/09 3/1/09 Residual Ox - Time of Discharge D013 (CR3)- D013 2/1/09 3/1/092Spectrus CT1300 - DOOF (CR3) j DOOF MNR 1 2/1/09 3/1/09 Temp Rise - D013 (CR3) v2 D013 13.6 L7.4 2/1/09 3/1/09 Temp-Discharge - D013 (CR3) v2 D013 72.2 8 0.4 3/1/09 Temp-Intake - D013 (CR3)v2 D013 58.7 64 2/1/09 ----- F 2/1/09 3/1/09 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF MNR 2/1/09 3/1/09 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF MNR i 2/1/09 3/1/09 iTotal Copper - DOOF (CR3) v2 DOOF T MNR MNR 2/1/09 3/1/09 _Total Copper - I-OFG (CR3) v2 I-OFG MNR 2/1/09 3/1/09 ýTotal Iron- D-OOF (CR3) v2 D-OOF MNR I. .NR 2/1/09 3/1/09 ITotal Iron- I-OFG (CR3) v2 I-OFG MNR MN 2/1/09 3/1/09 ýTotal Recoverable Copper - D-OOF (CR3) v2 D-OOF MNR MNR T-. 2/1/09 -3/1/09 ]Total Recoverable Iron - D-OOF (CR3) v2 D-OOF NR IMNR 2/1/09 3/1/09 Total Residual Ox 1-D013 (CR3) v2 1-D013 MNR MNR 2/1/09 3/1/09 jTSS- CD and ECST D-OOF (CR3) v2 D-OOF < 4.0 < 4.0 2/1/09 3/1/09 1TSS - I-OFE (CR3) v2 I-OFE <4 <4 2/1/09 3/1/09 ITSS - I-OFG (CR3) v2 I-OFG 13.95 2 3.9 2/1/09 3/1/09 {TSS P-D-OOF (CR3) v2 P-D-OOF MNR MNR 2/1/09 3/1/09 TSS Q-D-OOF (CR3) v2 Q-D-OOF L MNR I MNR 2/1/09 3/1/09 Turbidity - Background - D-OOF (CR3) v2 D-OOF I~-~VI NR 2/1/09 3/1/09 Turbidity - Calc Limit - D-ODF (CR3) v2 D-00F MNR _ 2/1/09 3/1/09 Turbidity - Difference D-0DF (CR3) v2 D-DDF MNR 7 2/1/09 3/1/09 -Turbidity - Effluent D-DDF (CR3) v2 D-ODF MNR 3/1/09 4/1/09 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF _j i > 100 3/1/09 4/1/09 j96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF 3/1/09 4/1/09 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v21 P-D-OOF -

                                                                                                                                                                                                           > 100 3/1/09 3/1/09           4/1/09 4/1/09      96-Hour TFlow              Mysidopsis
                                        -,-OFE  (CR3)2   Bahia Q-D-v2F (CR3)

Q'-OFE Q-D-E0F 7E7I MNR 3/1/109 4/1/109 IFlow -,-OFG (CR3)vQ,-OFG I! 0.000037 0.001154 3/1/09 4/1/091 _Flow-CD System D-00F (CR3)2 Q 0.02015 0.083083 D-OOF 0 0 3/1/09 i 4/1/09 Flow-ECST D-OOF (CR3) v2 D-OOF 0.00132971[ 0.013977 3/1/09 4/1/09 Flow-Intake - D-ooF (CR3) v2 D-OOF S17.886 29.52 3/1/09 4/1/09 Hydrazine 1-D-DDF (CR3) v2 1-D-ODF - _ MNR 10/21/2009 Page 83

Crystal River I ear DMR Data

    -Begi~date En DtePARAMETER-"NAME 3/1/09           4/1/09   jHydrazine P-D-OOF (CR3) v2                                                                              MNR   I 3/1/09           4/1/09 --Hydroquinone 1-D-OOF (CR3) v2                                                                      -     MNR 3/1/09           4/1/09   lHydroquinone P-D-OOF (CR3) v2                                                                        I_ _NR 3/1/09           4/1/09   (Morpholine 1-D-OOF (CR3) v2 3/1/09           4/1/09    Morpholine P-D-OOF (CR3) v2                      P-D-OOF                                          _I    MNR       _

__ L 3/1/09 4/1/09 Number of Batches - I-OFE (CR3) v2 I-OFE ___ _J_ *1 1 __K 1 MNR 3/1/09 4/1/09 Oil and Grease - D-OOF (CR3) v D-OOF 3/1/09 4/1/09 Oil and Grease - I-OFE (CR3) v2 I-OFE S < 1.4 < 1.4 3/1/09 4/1/09 jOil and Grease - I-OFG (CR3) v2 I-OFG 2.63 S < 1.4 SD-00F 3/1/09 4/1/09 pH - Background - D-OOF (CR3) v2 8.04 8.12 3/1/09 4/1/09 pH - Effluent - D-OOF (CR3) v2 0D-OF 8.02 8.13 3/1/09 4/1/09 pH - I-OFE (CR3) v2 I-OFE 6.84 6.84 3/1/09 4/1/09 ]pH - I-OFG (CR3) v2 I-OFG 7.88 8.99 3/1/09 4/1/09 Residual Ox - Time of Discharge D013 (CR3) 0D013 0 3/1/09 4/1/09 Spectrus CT1300 - DOOF (CR3) v2 DOOF 1.9 4/1/09 Temp Rise - 0013 (CR3) v I D013 14.8 16.5 3/1/09 3/1/09 4/1/09 Temp-Discharge - D013 (CR3) v2 D013 81.5 91 3/1/09 4/1/09 Temp-Intake - 0013 (CR3) v2 D013 66.8 _ 74.1 3/1/09 4/1/09 ITotal Ammonia I-D-OOF (CR3) Q2 I 1-D-OOF MNR 3/1/09 4/1/09 ITotal Ammonia P-D-OOF (CR3) v2 P-D-OOF MNR 3/1/09 4/1/09 Total Copper - DOOF (CR3) v2 DOOF MNR MNR 3/1/09 4/1/09 jTotal Copper- I-OFG (CR3) v2 I-OFG I MNR 3/1/09 4/1/09 ITotal Iron- D-OOF (CR3) v2 D-OOF MINR MNR 3/1/09 4/1/09 ITotal Iron- I-OFG (CR3) v2 I-OFG MNR 3/1/09 4/1/09 ITotal Recoverable Copper - D-OOF (CR3) v2 DIOOF MNR MNR 3/1/09 4/1/09 Total Recoverable Iron - D-OOF (CR3) v2 L D-OOF MNR MNR 3/1/09 4/1/09 ITotal Residual Ox 1-D013 (CR3) v2 I 1-D013 MNR MNR( 3/1/09 4/1/09 TSS- CD and ECST D-OOF (CR3) v2 D-OOF < 4.0 <4.0 3/1/09 4/1/09 .TSS - I-OFE (CR3) v2 l-OFE <4 <4 3/1/09 4/1/09 TSS - I-OFG (CR3) v2 I-OFG 12.68 ( 22.5 3/1/09 4/1/09 TSS P-D-0vF (CR3) v P-D-OOF MNR MNR 3/1/09 4/1/09 TSS Q-D-OOF (CR3) v2 0Q-D-OOF MNR MNR 3/1/09 4/1/09 Turbidity - Background - D-OOF (CR3) v2 ( D-OOF MNR 3/1/09 4/1/09 (Turbidity - Calc Limit - D-OEF (CR3) v2 Q D-OOF MNR 3/1/09 4/1/09 (Turbidity - Difference D-OOF (CR3) v2 ( D-DOF i MNR 10/21/2009 Page 84

Crystal River tear DMR Data Permit No. FL00000159 Begin date >End Date ~>~~PARAMETER-NAME~ Outall!. 3/1/09 4/1/09 Turbidity - Effluent D-OOF (CR3) v2 D-0OF 4/1/09 5/1/09 96-Hour Menidia Beryllina P-D-OOF (CR3) -OOF 4/1/09 5/1/09 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-00F 4/1/09 5/1/09 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF 4/1/09 5/1/09 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) Q-D-00F 4/1/09 5/1/09 Flow - I-OFE (CR3) v2 I-OFE 4/1/09 5/1/09 Flow - ,-OFG (CR3) v2 l-OFG - 4/1/09 5/1/09 Flow-CD System D-OOF (CR3) v2 D-OOF _ 5/1/09 4/1/09 Flow-ECST D-OOF (CR3) v2 - / D-OOF 5/1/09 4/1/09 Flow-Intake - D-OOF (CR3) v2 D-OOF 5/1/09 4/1/09 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF 5/1/09 4/1/09 Hydrazine P-D-OOF (CR3) v2 P-D-OOF 5/1/09 4/1/09 Hydroquinone 1-D-OOF (CR3) v2 1-D-00F 5/1/09 4/1/09 Hydroquinone P-D-OOF (CR3) v2 P-D-OOF 5/1/09 4/1/09 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 5/1/09 4/1/09 Morpholine P-D-OOF (CR3) v2 P-D-OOF 5/1/09 4/1/09 Number of Batches - I-OFE (CR3) v2 I-OFE 4/1/09 5/1/09 Oil and Grease - D-OOF (CR3) v2 D-OOF 4/1/09 5/1/09 Oil and Grease - I-OFE (CR3) v2 I-DEE 4/1/09 5/1/09 Oil and Grease - I-OFG (CR3) v2 4/1/09 5/1/09 pH - Background - D-OOF (CR3) v2 D-OOF 8.11 4/1/09 5/1/09 pH - Effluent - D-OOF (CR3) v2 D-OOF 8.05 4/1/09 5/1/09 pH - I-OFE (CR3) v2 I-OFE 4/1/09 5/1/09 pH - I-OFG (CR3) v2 I-OFG 6.05 4/1/09 5/1/09 Residual Ox - Time of Discharge D013 (CR3) D013 4/1/09 5/1/09 Spectrus CT1300 - DOOF (CR3) v2 DOOF 4/1/09 5/1/09 Temp Rise - D013 (CR3) v2 D013 4/1/09 5/1/09 Temp-Discharge - D013 (CR3) v2 D013 4/1/09 5/1/09 Temp-Intake - D013 (CR3) v2 D013 4/1/09 5/1/09 Total Ammonia 1-D-OOF (CR3) v2 1-D-OOF 4/1/09 5/1/09 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF 4/1/09 5/1/09 Total Copper - DOOF (CR3) v2 DOOF 4/1/09 5/1/09 Total Copper - I-0FG (CR3) v2 I-OFG 4/1/09 5/1/09 Total Iron- D-OOF (CR3) v2 D-OOF 4/1/09 5/1/09 Total Iron- I-OFG (CR3) v2 I-OFG 10/21/2009 Page 85

Crystal River s ear DMR Data Permit No. FL00000159 Begin date

Eind Date ~.PARA M ETER....N`AME~ 6 af I C-CgM 1n' C:

CMax,- Avg 4/1/09 5/1/09 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF MNR MNR 4/1/09 5/1/09 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF MNR 4/1/09 5/1/09 Total Residual Ox 1-D013 (CR3) v2 1-DO13 MNR MNR 4/1/09 5/1/09 TSS - CD and ECST D-OOF (CR3) v2 D-OOF <4.0 <4.0 4/1/09 5/1/09 TSS - I-OFE (CR3) v2 I-OFE 10.3 10.3 14.9 4/1/09 5/1/09 TSS - I-OFG (CR3) v2 I-OFG 4/1/09 5/1/09 TSS P-D-OOF (CR3) v2 P-D-OOF MNR MNR 4/1/09 5/1/09 TSS Q-D-OOF (CR3) v2 Q-D-OOF MNR MNR 4/1/09 5/1/09 Turbidity - Background - D-0OF (CR3) v2 D-00F MNR II _ _ I 4/1/09 5/1/09 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF MNR 4/1/09 5/1/09 Turbidity - Difference D-OOF (CR3) v2 D-OOF I___ i _ MNR 4/1/09 5/1/09 iTurbidity - Effluent D-OOF (CR3) v2 D-OOF MVNR 5/1/09 6/1/09 96-Hour Menidia Beryllina P-D-OOF (CR3) P-D-OOF > 100 5/1/09 6/1/09 96-Hour Menidia Beryllina Q-D-OOF (CR3) Q-D-OOF MNR 5/1/09 6/1/09 96-Hour Mysidopsis Bahia P-D-OOF (CR3) v2 P-D-OOF > 100 5/1/09 6/1/09 96-Hour Mysidopsis Bahia Q-D-OOF (CR3) - Q-D-OOF MNR 5/1/09 6/1/09 Flow - I-OFE (CR3) v2 I-0FE 1 -10.00004213 0.001306 5/1/09 6/1/09 Flow - I-OFG (CR3) v2 I-OFG 0.01956 0.081227 5/1/09 6/1/09 Flow-CD System D-OOF (CR3) v2 D-OOF 0.0- 0 5/1/09 6/1/09 Flow-ECST D-OOF (CR3) v2 D-OOF 0.00339 0.014345 5/1/09 6/1/09 Flow-lntake - D-OOF (CR3) v2 D-00F 21.825 34.272 5/1/09 6/1/09 Hydrazine 1-D-OOF (CR3) v2 1-D-OOF 'MNR 5/1/09 6/1/09 Hydrazine P-D-OOF (CR3) v2 P-D-OOF MNR 5/1/09 6/1/09 Hydroquinone 1-D-OOF (CR3) v2 1-D-OOF IMNR 5/1/09 6/1/09 Hydroquinone P-D-OOF (CR3) v2 P-D-00F IMNR 5/1/09 6/1/09 Morpholine 1-D-OOF (CR3) v2 1-D-OOF 20.5 5/1/09 6/1/09 Morpholine P-D-OOF (CR3) v2 P-D-OOF MNR N 5/1/09 6/1/09 Number of Batches - l-OFE (CR3) v2 I-OFE 1 _ 1 5/1/09 6/1/09 JOil and Grease - D-OOF (CR3) v2 D-OOF INR 5/1/09 6/1/09 Oil and Grease - I-OFE (CR3) v2 I-OFE 2 2 5/1/09 5/1/09 6/1/09 6/1/09 Oil and Grease - I-OFG (CR3) v2

                          .pH - Background - D-OOF (CR3) v2 I-OFG D-OOF                         7.94           8.16
                                                                                                                          -I--                           < 1.4 < 1.4 5/1/09           6/1/09      pH  - Effluent - D-OOF (CR3) Q             D-OOF                         8.01           8.16 5/1/09           6/1/09      pH  - I-OFE (CR3) v2                        I-FE                                        8.8                                        6.1   6.1 5/1/09           6/1/09      pH  - I-OFG (CR3) v2                        I-0FG                        8.2 10/21/2009                                                                             Page 86

Crystal River t ear DMR Data Permit No. FL00000159

Begini date. .>Ehd Date PAAMTE NAM C-ivia Kut6 Y-Av _NO.N-Avg NODI-M, 5/1/09 6/1/09 Residual Ox - Time of Discharge D013 (CR3) D013 0 5/1/09 6/1/09 Spectrus CT1300 - DOOF (CR3) v2 DOOF 1.8 I _ ,'_ __

5/1/09 6/1/09 Temp Rise - D013 (CR3)v2 D013 12.6 14.7 _ _ ! I 5/1/09 6/1/09 Temp-Discharge - D013 (CR3) v2 0013 91.7 95.6 I 5/1/09 6/1/09 Temp-lntake - D013 (CR3) v2 D013 79.3 85.1 _ ! i ! 5/1/09 6/1/09 Total Ammonia 1-D-OOF (CR3)v2 1-D-OOF _ _IMNR 5/1/09 6/1/09 Total Ammonia P-D-OOF (CR3) v2 P-D-OOF i1MNR ! -i-- 5/1/09 6/1/09 Total Copper- DOOF (CR3) v2 DOOF II MNR iMNR 5/1/09 6/1/09 iTotal Copper - l-OFG (CR3)v2 -- ,-0___Ii__ MNR i 5/1/09 6/1/09 Total Iron- D-OOF (CR3) v2 D-OOF ___MNR IMNR 5/1/09 6/1/09 Total Iron- I-OFG (CR3) v2 I-OFG _ _ _ .. I I I.. MN.NR . ... 5/1/09 6/1/09 Total Recoverable Copper - D-OOF (CR3) v2 D-OOF __ I ! MNR IMNR 5/1/09 6/1/09 Total Recoverable Iron - D-OOF (CR3) v2 D-OOF _ I - MNR MNR 5/1/09 6/1/09 Total Residual Ox 1-D013 (CR3) v2 1-D013 __IVNR MNR 5/1/09 6/1/09 TSS - CD and ECST D-OOF (CR3) v2 D-OOFQII < 4.0 < 4.0 5/1/09 6/1/09 TSS - I-OFE (CR3) v2 -OFE __10.2 10.2 5/1/09 6/1/09 TSS - I-OFG (CR3) v2 I-0FG 7.67 13.9 5/1/09 6/1/09 TSS P-D-OOF (CR3) v2 P-D-00F j _ I MNR IMNR 5/1/09 6/1/09 TSS Q-D-OOF (CR3) v2 Q-D-OOF ___NR IMNR 5/1/09 6/1/09 Turbidity - Background - D-O0F (CR3)v2 D-OOF _ _I __MNR 5/1/09 6/1/09 Turbidity - Calc Limit - D-OOF (CR3) v2 D-OOF 1ItMNR MNR 5/1/09 6/1/09 Turbidity - Difference D-OOF (CR3) v2 D-OOF 1 5 / 1 09 1 6 /1/0 9 ,T urbidity - Efflu ent D-OOF( CR3 ) v 2 D-OOF ... . . . .. . _ _. . . . . . . . . __ -MN R .. . .i . . ... . .. 10/21/2009 Page 87

Crystal River South DMR Data Permit No. FL00000159 date EDte PARAAETERNA ABein utl Ag C-Min Q-Ma-. NODI-Avg NODI-Max N

                                                                                                                                         *NODI-Min 1/1/04          2/1/04   Flow - Doll (CRS)                       Do11                                15S1        1556.8 1/1/04          2/1/04   Flow - Intake - D071 (CRS)              D071                                   0          0 1/1/04          2/1/04   Flow - Intake - D072 (CRS)              D072                                   0          0 1/1/04          2/1/04   Resid Ox - Dis Time - D071 (CRS)        D071                           0 1/1/04          2/1/04   Resid Ox - Dis Time - D072 (CRS)        D072                           0 1/1/04          2/1/04   Resid Ox - Dis Time P-DOll (CRS)       P-DOll                          0 1/1/04          2/1/04   Resid Ox - Dis Time P-D012 (CRS)       P-DO12                          0 1/1/04          2/1/04   Temp Rise - DOll (CRS)                  0011        15.4             16.6 1/1/04          2/l/04   Temp Rise-- D012 (CRS)

D012 15.4 16.6 1/1/04 2/1/04 ITemp-Discharge - D01 1 (CRS) 0011 74.4 84 1/1/04 2/1/04 iTemp-Discharge - D012 (CRS) D012 74.4 84 1/1/04 2/1/04 Temp-intake - D012 (CRS) 1/1/04 - 2/1/04 Temp-Intake - D012 (CRS) _ Doll 59 66.4 D012L 59 66.4 2/1/04 3/1/04 Flow - Doll (CRS) ] 0011 V 1410.5 1556.8 2/1/04 *l 3/1/04 Flow - Intake - D071 (CRS) 0 0 2/1/04 F 3/1/04 Flow - Intake - D072 (CRS) D072 0 0 2/1/04 3/1/04 Resid Ox - Dis Time - D071 (CRS) D071 0 2/1/04 3/1/04 Resid Ox - Dis Time - D072 (CRS) D072 So 0 2/1/04 3/1/04 Resid Ox - Dis Time P-DOll (CRS) P-DOll 2/1/04 3/1/04 Resid Ox - Dis Time P-D012 (CRS) P-D012 0 O ---- 2/1/04 3/1/04 Temp Rise - Doll (CRS) D011 13.2 13.2 14.9 2/1/04 2/1/04 3/1/04 3/1/04 __Temp Rise - D012 (CRS) ITemp-Discharge - Doll (CRS)

                                                             -T D012 D011         74 14.9 78.6 0012   -

2/1/04 3/1/04 Temp-Discharge - D012 (CRS) 74 78.6 Temp-Intake - DOll (CRS) 66.1 2/1/04 3/1/04 Temp-Intake - D012 (CRS) D012 60.8 66.1 3/1/04 3/1/04 4/1/04 Fow- Dol *(*(CR5) 0011 1391.9 1556.8 3/1/04 !Flow - Intake - D071 (CRS) D071 0 0 4/1/04 3/1/04 Flow - Intake- D072 (CRS) D072 0 0 4/1/04 3/1/04 pH - Background D071 (CR5) 7-D071 8.1 8.1 4/1/04 3/1/04 4/1/04 pH - Background D072 (CRS) 7-D071 7 8.1 8.1 3/1/04 pH - Effluent - P-D071 (CRS) P-D071 8.1 3/1/04 4/1/04 8.1 pH-Effluent - P-D072 (CRS) P-D072 8.1 3/1/04 4/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D071 1 -0.4 10/21/2009 Page 1

Crystal River South DMR Data Permit No. FL00000159 Begin date I End Date K PARAMETERNAME ' OutalI C-Avg C7Min 3/1/04 4/1/04 pH - Ex of Calc Limit - R-D072 (CRS) R-D072 1 -0.4 3/1/04 4/1/04 pH -Calc Limit - Q-D071 (CRS) Q-D071 7.1 8.5 7.1 8.5 3/1/04 4/1/04 pH -Calc Limit - Q-D072 (CRS) Q-D072 3/1/04 4/1/04 Resid Ox - Dis Time - D071 (CRS) D071 0 3/1/04 4/1/04 Resid Ox - Dis Time - D072 (CRS) D072 F 0 3/1/04 4/1/04 Resid Ox - Dis Time P-DO11 (CRS) P-DO11 0 3/1/04 4/1/04 Resid Ox - Dis Time P-D012 (CRS) P-DO12 0 3/1/04 4/1/04 ITemp Rise - D011 (CRS) D011 13.4 17,4 3/1/04 4/1/04 Temp Rise - D012 (CRS) D012 13.4 17.4 3/1/04 4/1/04 Temp-Discharge - D011 (CRS) D011 81.2 88.1 3/1/04 4/1/04 Temp-Discharge - D012 (CRS) D012 81.2 88.1 3/1/04 4/1/04 Temp-Intake - D011 (CRS) D011 67.8 73 3/1/04 4/1/04 jTemp-Intake - D012 (CRS) D012 67.8 73 5/1/04 Flow - D011 (CRS) D011 1446.8 1556.8 4/1/04 Flow - Intake - D071 (CRS) D071 0.01 0,03 4/1/04 5/1/04 4/1/04 5/1/04 Flow - Intake - D072 (CRS) D072 75.02 184.73 4/1/04 5/1/04 pH - Background D071 (CRS) T 7-D071 8 -8

                                                                                            -   8 4/1/04        5/1/04      pH - Background D072 (CRS)            7-D072 4/1/04        5/1/04      pH - Effluent - P-D071 (CRS)              P-D071              =,

7.9 4/1/04 5/1/04 pH - Effluent - P-D072 (CRS) P-D072 8 S 8 4/1/04 5/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D071 I -0.5 4/1/04 5/1/04 pH - Ex of Calc Limit - R-D072 (CRS) R-D072 1 -0.5 4/1/04 5/1/04 pH -Calc Limit - Q-D071 (CRS) Q-D071 6.9 8.5 4/1/04 5/1/04 ýpH -Calc Limit - Q-D072 (CRS) Q-0072 7 8.5 4/1/04 5/1/o4 Resid Ox - Dis Time - D071 (CRS) 0071 0 4/1/04 5/1/04 Resid Ox - Dis Time - D072 (CRS) 70072 0 4/1/04 5/1/04 Resid Ox - Dis Time P-Do11 (CRS) P-DO11 0 4/1/04 5/1/04 I-Resid Ox - Dis Time P-D012 (CRS) P-0012 4/1/04 5/1/04 Temp Rise - Doll (CR5) TD011- 14.2 15.9 4/1/04 5/1/04 Temp Rise - D012 (CRS) D012 14.2 15.9 4/1/04 5/1/04 ýTemp-Discharge - D011 (CRS) D011 86 95.4 4/1/04 5/1/04 _ Temp-Discharge - D012 (CRS) D012 86 95.4 4/1/04 5/1/04 ýTemp-Intake - D011 (CRS) 0011 71.7 78.5 4/1/04 5/1/04 ITemp-Intake - D012 (CRS) 0012 I 71.7 78.5 10/21/2009 Page 2

0 Crystal River South DMR Data Permit No. FL00000159 Begin date End Date PARAMETER NAME Outalf C-Avg, c-M ax Q-AVg Qm",` :1: =Dl-A'vg NODIIMax:,j -Min 5/1/04 6/1/04 Flow- D011 (CRS) D011 1709.6

1774.8

i. . . . . . . T . .. . . . . . . . ..

5/1/04 6/1/04 Flow - Intake - D071 (CRS) D071 142.07 502.47 148.78 I I NOD.-M. 5/1/04 6/1/04 Flow - Intake - D072 (CRS) D072 474.8 pH - Background D071 (CRS) 7-D071 8.2 8.2 .. . . ... .__...i __......... 5/1/04 6/1/04 pH - Background D072 (CRS) 8.2 5/1/04 6/1/04 7-D072 8.2 8.2 5/1/04 6/1/04 pH - Effluent - P-D071 (CRS) P-D071 8.2 8.2 5/1/04 6/1/04 pH - Effluent - P-D072 (CRS) P-D072 8.2 8.2 R-D071 1~ -0.3 5/1/04 6/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D072 1 -0.3 5/1/04 6/1/04 pH - Ex of Calc Limit - R-D072 (CRS) 5/1/04 6/1/04 pH -Calc Limit - Q-D071 (CRS) Q-D071 7.2 8.5 5/1/04 6/1/04 pH -Calc Limit - Q-D072 (CRS) Q-D072 7.2 8.5 5/1/04 6/1/04 Resid Ox - Dis Time - D071 (CRS) D071 0 5/1/04 6/1/04 Resid Ox - Dis Time - D072 (CRS) D072 0 5/1/04 6/1/04 Resid Ox - Dis Time P-DO11 (CRS) P-DO11 0 5/1/04 6/1/04 Resid Ox - Dis Time P-D012 (CRS) P-DO12 0 5/1/04 6/1/04 Temp Rise - D011 (CRS) D011 12 15.3 5/1/04 6/1/04 Temp Rise - D012 (CRS) D012 12 15.3 5/1/04 6/1/04 Temp-Discharge - D011 (CRS) D011 92.9 96.1

                                                                                                         +-i-5/1/04         6/1/04  Temp-Discharge - D012 (CRS)             D012       92.9               96.1 T-5/1/04         6/1/04  Temp-Intake - D011 (CRS)                D011       80.9               87.4 5/1/04      j  6/1/04  Temp-Intake - D012 (CRS)                D012       80.9               87.4 6/1/04         7/1/04  Flow - DOl1 (CRS)                       D011                                          1760.4   1774.8 7-6/1/04         7/1/04  Flow - Intake - D071 (CRS)              D071                                          491.73     504 6/1/04         7/1/04  Flow - Intake - D072 (CRS)              D072                                          477.27     504 6/1/04         7/1/04  pH - Background D071 (CRS)         7-D071                  8.2     8.2 6/1/04         7/1/04  pH - Background D072 (CRS)         7-D072                  8.2     8.2 6/1/04         7/1/04  pH - Effluent - P-D071 (CRS)           P-D071                  8.3     8.3 6/1/04         7/1/04  pH - Effluent - P-D072 (CRS)           P-D072                  8.3     8.3 6/1/04         7/1/04  pH - Ex of Calc Limit - R-D071 (CRS)   R-D071                         -0.2 I1 6/1/04         7/1/04  pH - Ex of Calc Limit - R-D072 (CRS)   R-D072                          0.2       ~~~1~~

6/1/04 7/1/04 pH -Calc Limit - Q-D071 (CRS) - Q-D071 7.3 8.5 6/1/04 7/1/04 pH -Calc Limit - Q-D072 (CRS) Q-D072 7.3 8.5 ii 6/1/04 7/1/04 Resid Ox - Dis Time - D071 (CRS) D071 0 I I i 6/1/04 7/1/04 Resid Ox - Dis Time - D072 (CRS) D072 0 .] 10/21/2009 Page 3

Crystal River South DMR Data Permit No. FL00000159 Begi dae End DateJý\":> 1 ARAMETEW NAM -C___ax Q-vg 0-Mi Q-ax NOIA.ND-Max INODI-Min-6/1/04 7/1/04 Resid Ox - Dis Time P-DO11 (CRS) P-DOll 0 71 t 6/1/04 7/1/04 Resid Ox - Dis Time P-D012 (CRS) P-D012 0 6/1/04 1 7/1/04 Temp Rise - DO11 (CRS) D0ll 6.5 6/1/04 7/1/04 Temp Rise - D012 (CRS) D012 6.5 6/1/04 ] 7/1/04 Temp-Discharge - DO11 (CRS) D0ll i 94.1 96.8 6/1/04 7/1/04 Temp-Discharge - D012 (CRS) D012 94.1 96.8 6/1/04 1 7/1/04 Temp-Intake - D011 (CRS) DO11 87.6 90.7 6/1/04 7/1/04 Temp-Intake - D012 (CRS) D012 87.6 90.7 7/1/04 8/1/04 Flow - DO11 (CRS) DO11 1739.8 1774.8 7/1/04 8/1/04 Flow - Intake - D071 (CRS) D071 480.15 504 7/1/04 8/1/04 Flow -Intake- D072 (CRS) - D072 I 473.41 504 7/1/04 8/1/04 pH - Background D071 (CRS) 7 7-D071 8.1 8.1 7/1/04 I 8/1/04 pH - Background D072 (CRS) j 7-D072 8.1 7/1/04 8/1/04 pH - Effluent - P-D071 (CR5) P-D071 8.2 8.2 7/1/04 8/1/04 pH - Effluent - P-D072 (CRS) P-D072 8.2 8.2 7/1/04 8/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D071 i -0.3 7/1/04 8/1/04 IpH - Ex of Calc Limit - R-D072 (CRS) R-D072 -0.3 7/1/04 8/1/04 pH -Calc Limit - Q-D071 (CRS) Q-D071 7.2 8.5 7/1/04 8/1/04 _pH-Calc Limit - Q-D072 (CRS) Q-D072 7.2 8.5 7/1/04 8/1/04 Resid Ox - Dis Time- D071 (CRS) D071 0 7/1/04 8/1/04 Resid Ox--Dis Time- 0072 (CR5) D072 0 7/1/04 8/1/04 Resid Ox - Dis Time P-DO11 (CRS) P-Do11 0-- 7/1/04 8/1/04 Resid Ox - Dis Time P-D012 (CR5) P-D012 0 7/1/04 7/1/04 I 810 8/1/04 ** Rise -*Doll *Ol Temp (CR) Do1 6.4. 9.8 7/1/04 _ 8/1/04 Temp Rise - D012 (CRS) D012 6.4 9.8 -- -**- ~ -- iF 7/1/04 8/1/04 Temp-Discharge - D011 (CRS) D011 94.1 96.2 7/1/04 8/1/04 Temp-Discharge - D012 (CRS) D012 94.1 96.2 7/1/04 8/1/04 [Temp-lntake - D011 (CRS) D011 87.6 90.8 7/1/04 1 8/1/04 ITemp-Intake - D012 (CRS) 1 D012 87.6 90.8 8/1/04 9/1/04 Flow- DO11 (CRS) Do11 1713.9 1774.8 8/1/04 9/1/04 Flow - Intake - D071 (CRS) D071 ]1 430.95 504 8/1/04 F 9/1/04 Flow - Intake- D072 (CRS) D072 430.12 504 ! 8/1/04 9/1/04 pH - Background D071 (CRS) 7-D071 8.1 8.1 8/1/04 9/1/04 pH - Background DO72 (CRS) 7-D072 8.1 8.1 i 10/21/2009 Page 4

Crystal River Suth DMR Data 0 Permit No. FL00000159 Begin datei ~EndDt~ K dDt ~ 2AAEENMVC-a _____________ ~ ~ ~ TR,,A ~ EOutall'- ~ _____ ~ ~A ~ ~ ~ ~.- ~> ~ KQMx ~ 6.Mx 1 _ OIAv OIMx Di______________________ ND-i b~-Mn _0_____'j 8/1/04 9/1/04 pH - Effluent - P-D071 (CRS) P-D071 8. 1 8.1 8/1/04 9/1/04 pH - Effluent - P-D072 (CRS) P-0072 8.:2 8.2 1 -0.4 8/1/04 9/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D071 1 8/1/04 9/1/04 pH - Ex of Calc Limit - R-D072 (CRS) R-D072 Q-D071 7.: 1

                                                                                                                -0.3 8.5 r

8/1/04 9/1/04 pH -Calc Limit D071 (CRS) 8/1/04 9/1/04 pH -Calc Limit - Q-D072 (CRS) Q-0072 7.22 8.5 8/1/04 9/1/04 Resid Ox - Dis Time - D071 (CRS) D071 0 8/1/04 9/1/04 Resid Ox - Dis Time - D072 (CRS) D072 0 8/1/04 9/1/04 __ Resid Ox - Dis-Time P-DO11 (CRS) P-Do11 0 8/1/04 9/1/04 Resid Ox - Dis Time P-D012 (CRS) P-DO12 0 8/1/04 9/1/04 Temp Rise - D011 (CRS) D011 8.1 11.2 8/1/04 9/1/04 Temp Rise - D012 (CRS) D012 8.1 11.2 ITemp-Discharge - D011 (CRS) D011 93.8 96.2 8/1/04 9/1/04 8/1/04 9/1/04 ITemp-Discharge - D012 (CR5) D012 93.8 tF D011l 8/1/04 9/1/04 iTemp-Intake - D011 (CRS) 85.7 88.2

                                                                                               -F-8/1/04        9/1/04     ITemp-Intake - D012 (CRS)                 J       D012       85.7                     88.2 1.6 9/1/04        10/1/04    -Arsenic - DOH (CRS)                               DOH 9/1/04        10/1/04      Cadmium - DOH (CRS)                              DOH                                  3.6 9/1/04        10/1/04     [Chromium - DOH (CRS)                                                                   13 DOH 9/1/04        10/1/04      Copper - DOH (CRS)                                                                   2-60 9/1/04        10/1/04      Flow - D011 (CR5)                                0011 -                                      16E       1774.8 9/1/04        9/30/04      Flow - DOH (CRS)                                 DOH                                                     0.5 9/1/04        10/1/04      Flow - Intake - D071 (CRS)                       D071                                        251 .14    504 9/1/04        10/1/04      Flow - Intake - D072 (CRS)                       D072                                        1701.72 s , . ..

504 9/1/04 10/1/04 Iron - DOH (CRS) DOH I 77000 9/1/04 10/1/04 iLead - DOH (CRS) DOH 2.2 9/1/04 10/1/04 Mercury - DOH (CRS) DOH 0.1uU 9/1/04 10/1/04 Nickel - DOH (CRS) DOH 360 9/1/04 10/1/04 pH - Background D071 (CRS) 7-D071 8 8 9/1/04 10/1/04 pH - Background D072 (CRS) 7-D072 8 8 9/1/04 9/30/04 pH - Background - DOH (CRS) DOH 8 8 9/1/04 9/30/04 pH - Calc Limit - DOH (CRS) DOH 7 8.5 9/1/04 9/30/04 IpH - Difference - DOH (CRS) DOH -4.3 -5.8 9/1/04 9/30/04 1pH - Effluent - DOH (CRS) DOH 2.7 2.7 . 10/21/2009 Page 5

Crystal River South DMR Data Permit No. FL00000159 SNtaI - g MI ' Q--Max ODI g ýegin~dt Ed j{~~~EP~~~d~~~Date.~~~~~.

                   .DaW,                             ý         rku     OuAv

__________NAM C-i C-Max(', -v . ______- N"D-vg NODI-Max ,.OD-i N D-i 9/1/04 10/1/04 pH - Effluent - P-D071 (CRS) P-D071 ___ 8 8 8 9/1/04 10/1/04 pH - Effluent - P-D072 (CRS) P-D072 8 9/1/04 10/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D071

                                                                                                               -0.5 9/1/04       10/1/04      pH - Ex of Calc Limit - R-D072 (CRS)         R-D072        .

I .! 9/1/04 10/1/04 7pH-Cac Limit- Q-D071 (CR5) D071 o- 7 8.51 9/1/04 10/1/04 pH -Cae c Limit - Q-D072 (CRS) Q-D072 _____ 7 8.5__ 9/1/04 10/1/04 Resid Ox - Dis Time - D071 (CRS) D071 - 0 _ _ 9/1/04 10/1/04 Resid Ox - Dis Time - D072 (CRS) D072 - 0 9/1/04 10/1/04 ýResid Ox - Dis Time P-DO12 (CRS) P-DO1 0 9/1/04 10/1/04 iResid Ox - Dis Time P-D012 (CR5) P-D012 0 9/1/04 10/1/04 LSeienium - &OH (CRS) DOH 1.5 9/1/04 10/1/04 Temp Rise - D011 (CRS) D~ll I 10.1 13.4 9/1/04 10/1/04 Temp Rise - D012 (CRS) D012 10.1 13.4 9/1/04 10/1/04 Temp-Discharge - D011 (CRS) D011 92 101.9 9/1/04 10/1/04 Temp-Discharge - D012 (CRS) __ D012 92 101.9 9/1/04 10/1/04 Temp-Intake - D011 (CRS) D011 82.1 88.4 9/1/04 10/1/04 Temp-Intake - D012 (CRS) D012 82.1 88.4 9/1/04 10/1/04 TSS - DOH (CRS) DOH 17 9/1/04 10/1/04 iVanadium - DOH (CRS) DOH 10 U 9/1/04 10/1/04 Zinc - DOH (CRS) DOH 820

                                                                                                                    . ... F 10/1/04      11/1/04      F1low - DOll (CRS)                            D011                                                1691.8        1774.7 10/1/04      11/1/04     ]Flow - Intake - D071 (CRS)                    D071                                                128.57          252 10/1/04      11/1/04      Flow - Intake - D072 (CRS)                    D072                                                284.47          504     !

10/1/04 11/1/04 pH - Background D071 (CRS) 7-D071 8 8 10/1/04 11/1/04 pH - Background D072 (CRS) 7-D072 8 8 10/1/04 11/1/04 pH - Effluent - P-D071 (CRS) P-D071 7.9 7.9 10/1/04 11/1/04 pH - Effluent - P-D072 (CRS) P-D072 7.9 7.9 10/1/04 11/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-E)071 0.9 -0.6 7 1-10/1/04 11/1/04 pH - Ex of Calc Limit - R-D072 (CRS) R-E)072 0.9 -0.6 10/1/04 11/1/04 pH -Calc Limit - Q-D071 (CRS) Q-D071 7 8.5 10/1/04 11/1/04 pH -Calc Limit - Q-D072 (CRS) Q-D072 7 8.5 10/1/04 10/1/04 11/1/04 11/1/04 Resid Ox- Dis Time- D071 (CRS) Resid Ox - Dis Time - D072 (CRS) D071 D072 0 ~~~1~ 0

         -I-10/1/04       11/1/04      R      Ox- Dis Time P-DO11 (CRS)            P-DO11       -                1~           0 10/21/2009                                                                                 Page 6

0 Crystal River South DMR Data Permit No. FL00000159 Begin date End-Date , PARAMETER-NAME oufall CVA~g4 ~C-Min~ C-Maxv 10/1/04 11/1/04 IResid Ox - Dis Time P-D012 (CRS) I P-D012 0 10/1/04 11/1/04 Temp Rise - D011 (CRS) D011 12.4 14.3 10/1/04 11/1/04 TempRise - D012 (CRS) D012 12.4 14.3 10/1/04 11/1/04 iTemp-Discharge - D011 (CRS) D0o1 91.6 95.4 10/1/04 11/1/04 ITemp-Discharge - D012 (CRS) D012- 91.6 95.4 10/1/04 11/1/04 iTemp-Intake - D011 (CRS) D011 1 79.2 84.6 10/1/04 11/1/04 ITemp-Intake - D012 (CRS) D012 79.2 84.6 11/1/04 12/1/04 -Flow-Do1I(CRS) DO1 1587.6 1611.9 11/1/04 12/1/04 Flow - Intake - D071 (CRS) D071 0 0 11/1/04 12/1/04 Flow - Intake - D072 (CRS) D072 I 43.34 80.37 11/1/04 12/1/04 pH - Background D071 (CRS) 7-0071 I 8.2 8.2 11/1/04 12/1/04 IpH - Background D072 (CR5) 7-D072 8.2 8.2 11/1/04 12/1/04 pH - Effluent - P-D071 (CR5) P-D071 8 8 11/1/04 12/1/04 pH - Effluent - P-D072 (CR5) P-D072 ! 8-7 8 11/1/04 12/1/04 pH - Ex of Calc Limit - R-D071 (CRS) R-D071 0.8 -0.5 11/1/04 12/1/04 pH - Ex of Calc Limit - R-D072 (CRS) R-D072 0.8 -0.5 11/1/04 12/1/04 pH -Calc Limit - Q-D071 (CRS) Q-D071 7.2 8.5 11/1/04 12/1/04 pH -Calc Limit - Q-D072 (CRS) Q-D072 7.2 8.5 11/1/04 12/1/04 Resid Ox - Dis Time - D071 (CRS) D071 0 11/1/04 12/1/04 Resid Ox - Dis Time - D072 (CRS) D072 __ 0 11/1/04 12/1/04 Resid Ox - Dis Time P-DO11 (CRS) P-DOll 0 11/1/04 12/1/04 Resid Ox - Dis Time P-D012 (CRS) P-D012 11/1/04 12/1/04 Temp Rise - D011 (CRS) D1 1 . 14.2 ___15.5 11/1/04 12/1/04 Temp Rise - D012 (CRS) 0012 14.2 15.5 11/1/04 12/1/04 Temp-Discharge - D011 (CRS) Doll 8 - 95.7 11/1/04 11/1/04 12/1/04 12/1/04 Temp-Discharge - D012 (CRS) Temp-Intake - D011 (CRS) D012 D011 86.2 72 95 7 80.4

                                                                                                                    *1-11/1/04       12/1/04    Temp-Intake - D012 (CRS)                  012         72                    80.4 12/1/04        1/1/05     Flow - D011 (CR5)                       D011                                     159 8*

3.4 1611.9 I 12/1/04 1 1/1/05 Flow - Intake - D071 (CRS) D071 / 0 o~~ 0 I 12/1/04 1/1/05 Flow - Intake - D072 (CRS) D072 0 I -~___ 12/1/04 1/1/05 pH - Background D071 (CRS) 7-D071 8.1 8.1 12/1/04 12/1/04 1/1/05 1/1/05 pH - Background D072 (CRS) pH - Effluent - P-D071 (CRS) 7-D072 8.1 8.1 L - ___ P-D071 8.1 L 8.1 10/21/2009 Page 7

0 Crystal River South DMR Data Permit No. FL00000159 8 1d Ef~idi Dat j PIRM E '-NAME-- }:,I!otaii c-Avg-. tJ C11Mirii

                                                                                                             -,    C--M~ax)C       Q-Avg":      :.O--.
                                                                                                                                                   "      --fb'.-N- D4gNODI-Ag Maflfxl NODI-Min.

12/1/04 1/1/05 pH - Effluent - P-D072 (CRS) P-D072 _ 8 8 12/1/04 1/1/05 pH - Ex of Calc Limit - R-D071 (CR: 1 -0.4 ~~1~~~ 12/1/04 1/1/05 pH - Ex of Calc Limit - R-D072 (CR. s) R-D072 0.9 -0.5 12/1/04 1/1/05 pH -Calc Limit - Q-D071 (CR5) Q-D071 7.1 8.5 12/1/04 /11/05 pH -Calc Limit - Q-D072 (CRS) Q-D072 7.1 8.5 ____ 12/1/04 1/1/05 Resid Ox - Dis Time - D071 (CRS) 0 D071 12/1/04 1/1/05 Resid Ox - Dis Time - D072 (CRS) o 0 0 Resid Ox - Dis Time P-DOll (CR5) P-D011 12/1/04 1/1/05 1/1/05 Resid Ox - Dis Time P-D012 (CRS) P-DO12 o ! 12/1/04 12/1/04 1/1/05 Temp Rise - DOll (CRS) Doll 14.7 16.1 12/1/04 1/1/05 Temp Rise - D012 (CRS) D012 14.7 16.1 I_- 12/1/04 1/1/05 Temp-Discharge - Doll (CRS) D011 75.3 86.4 12/1/04 1/1/05 Temp-Discharge - D012 (CRS) D012 75.3 86.4 I 12/1/04 1/1/05 Temp-Intake - Doll (CRS) j Do011 _ 60.6 71 _ 12/1/04 1/1/05 Temp-Intake - D012 (CRS) D012 60.6 71 1/1/05 2/1/05 Flow - Doll (CRS) D011 1586.1 1611.9 0071 o o i 1/1/05 1/1/05 2/1/05 2/1/05 Flow - Intake - D071 (CRS) Flow - Intake - D072 (CRS) D. 072

                                                                                                                                   ....o0. ...i        0 1/1/05       2/1/05    ipH - Background D071 (CR5)                 7-D071                           8.2         8.2 1/1/05       2/1/05     pH - Background D072 (CRS)                 7-D072                           8.2         8.2 1/1/05       2/1/05     Resid Ox - Dis Time - D071 (CRS)                D071                                          0 1/1/05       2/1/05    ýResid Ox - Dis Time-0D072 (CRS)               oo72 D0_                                           0 1/1/05       2/1/05     Resid Ox - Dis Time P-DO11 (CRS)

JP-DOll 0 1/1/05 2/1/05 Resid Ox - Dis Time P-D012 (CRS) P-DO12 . . .. . 1 0 1/1/05 2/1/05 ,Temp Rise - D011 (CRS) D011 14.3 j 15.9 1/1/05 2/1/05 iTemp Rise- D012 (CRS) D012 14.3 15., 1/1/05 2/1/05 Temp-Discharge - D011 (CRS) Doll 75.3 3 85.- 1/1/05 2/1/05 7Temp-Discharge - D012 (CRS) D012 p75.3 1/1/05 2/1/05 Temp-Intake - Doll (CRS) D011 60.9 69.5 1/1/05 2/1/05 Temp-Intake - D012 (CRS) D012 . _60.9 L 1 69.5

                                                                                  }__                                                        I 2/1/05       3/1/05     Flow - D011 (CRS)                               Doll                                                       1525          1611.9     1 2/1/05       3/1/05     Flow - Intake - D071 (CRS)                      D071                         I                                o   1 2/1/05       3/1/05     Flow - Intake - D072 (CRS)                      D072                     -_                                   0o              0 2/1/05       3/1/05   IpH I    - Background D071 (CRS)                   D7-071    _                    8.1         8.1 10/21/2009                                                                              Page 8

0 0 Crystal River South DMR Data Permit No. FL00000159 > *Begin date End Date PARAMETER-*NAME Outal, C-Avg :' "

Min 4-Max; I .Q-Avg" K1.QMax !O!l-Avg NOD -Max NODI-Min 2/1/05 3/1/05 pH - Background D072 (CRS) 7-D072 8.1 8.1 2/1/05 3/1/05 Resid Ox - Dis Time - D071 (CRS) D071 0 2/1/05 3/1/05 Resid Ox - Dis Time - D072 (CRS) D072 --- o 2/1/05 3/1/05 Resid Ox - Dis Time P-D011 (CRS) P-D011 0 2/1/05 3/1/05 Resid Ox - Dis Time P-DO12 (CRS) P-D012 0 2/1/05 3/1/05 Temp Rise - DOll (CRS) D011 13.5 15.1 2/1/05 3/1/05 Temp Rise - D012 (CRS) D012 13.5 15.1 2/1/05 3/1/05 Temp-Discharge - DOll (CRS) D011 75.3 81.3 2/1/05 3/1/05 Temp-Discharge - D012 (CRS) D012 75.3 81.3 2/1/05 3/1/05 Temp-Intake - D011 (CRS) DOll 61.8 66.6 2/1/05 3/1/05 Temp-Intake - D012 (CRS) DO12 - 61.8 66.6- I 3/1/05 4/1/05 Flow - DOll (CRS) D011 iJ 1585.8 1611.9 3/1/05 4/1/05 Flow - Intake - D071 (CRS) D071 30.31 59.09 3/1/05 4/1/05 Flow - Intake - D072 (CRS) D072 23.01 50.65 3/1/O5 4/1/05 pH - Background D071 (CRS) 7-D071 .05 8.05 3/1/O5 4/1/05 pH - Background D072 (CRS) 7-D072 8.05 8.05 .

_. I- ~-----~-. 3/1/05 4/1/05 Resid Ox - Dis Time - D071 (CRS) D071 - 0 3/1/05 4/1/05 Resid Ox - Dis Time - D072 (CRS) D072 0 3/1/O5 4/1/05 Resid Ox - Dis Time P-D011 (CRS) P-DOll 0 3/1/O5 4/1/05 Resid Ox - Dis Time P-D012 (CRS) P-D012 __F 0 3/1/05 4/1/05 Temp Rise - D011 (CRS) D011 14.5 15.,9 3/1/05 4/1/105 Temp Rise - D012 (CRS) 15.9 D012 14.5 3/1/os 4/1/05 Temp-Discharge - D011 (CRS) D011 80.3 88.9 3/1/05 4/1/05 Temp-Discharge - D012 (CRS) D012 80.3 88.9 3/1/05 4/1/105 Temp-Intake - D011 (CRS) D011 65.8 3/1/os 4/1/05 -1 _ 73.4 Temp-Intake - D012 (CRS) D012 65.8 4/1/05 s/1/os Flow - D011 (CRS) D011 1495.8 1611.9 4/1/05 5/1/os Flow - Intake - D071 (CRS) D071 26.78 j 26.78 4/1/05 5/1/05 Flow - Intake - D072 (CRS) D072 72.28 72.28 4/1/05 4/1/05 5/1/os 5/1/05 I - - - - - - - - --- - -- - - - - - --I_ Resid Ox - Dis Time - D071 (CRS) Resid Ox - Dis Time - D072 (CRS) D071 D072

                                                                                                                                   /0 f   0    K I    _____

4/1/05 5/1/os Resid Ox - Dis Time P-D011 (CRS) P-D011 4/1/OS 4/1/05 5/1/05 5/1/05 Resid Ox - Dis Time P-D012 (CRS) Temp Rise - D011 (CRS) P-DO12 D011 13.8 i ___ _____ 0 4.9 1_ 10/21/2009 Page 9

0 Crystal River South DMR Data Permit No. FL00000159 2Begin date. End~ -vl In C-Max.g_: C-MinK-AM AM Y NODflI axM ,O 4/1/05 5/1/05 Temp Rise - D012 (CRS) D012 13.8 14.9 Temp-Discharge - D011 (CRS) D011 85.3 4/1/05 5/1/05 91,1 1 4/1/05 5/1/05 Temp-Discharge - D012 (CRS) D012 85.3 91. 5/1/05 Temp-Intake - D011 (CRS) D011 71.5 75.3 4/1/05 i 75.3 4/1/05 5/1/05 Temp-Intake - D012 (CRS) D012 71.5 6/1/05 Flow - D011 (CRS) D011 1663.1 1693.3 5/1/05 5/1/05 6/1/05 Flow - Intake - D071 (CRS) FDOll1 0071 85.53 294.53 5/1/05 6/1/05 Flow - Intake - D072 (CRS) D072 124.66 395.44 5/1/05 6/1/05 JpH - Background D071 (CRS) 7-D071 8.02 8.02 5/1/05 6/1/05 pH - Effluent - P-D071 (CRS) P-D071 8.2 8.2 5/1/05 6/1/05 pH - Ex of Calc Limit - R-D071 (CRS) R-D071 1.2 -0.3 5/1/05 6/1/05 pH -Calc Limit - Q-D071 (CRS) Q-D071 7.02 8.5 5/1/o5 6/1/05 Resid Ox - Dis Time - D071 (CRS) D071 5/1/05 6/1/05 Resid Ox - Dis Time - D072 (CRS) D072 _ o - 5/1/05 6/1/05 Resid Ox - Dis Time P-DO11 (CRS) P-Do11 0 5/1/05 6/1/05 Resid Ox - Dis Time P-D012 (CR5) P-DO12 5/1/05 6/1/05 iTemp Rise - D011 (CRS) 0011 11.6 13.5 I 5/1/05 6/1/05 Temp Rise - D012 (CRS) D012 11.67, 5/1/05 6/1/05 Temp-Discharge - D011 (CRS) D011 91 95.5 5/1/05 S 9S.5 6/1/05 Temp-Discharge - D012 (CRS) D012 91 5/1/o5 6/1/05 Temp-Intake - D011 (CRS) D011 79.4 I7 85.5 5/1/os 6/1/05 Temp-lntake - D012 (CRS) D012 79.4 85.5 6/1/05 7/1/05 Flow - D011 (CRS) D011 i 1684.5 1696.3 6/1/05 7/1/05 Flow - Intake - D071 (CRS) D071 358.34 504 6/1/05 7/1/05 Flow - Intake -D072 (CRS) D072 364.94 504 6/1/05 7/1/05 Flow D-600 (CRS) v2 D-600 0.01 6/1/05 7/1/05 pH - Background D071 (CRS) 7-D071 8.08 8.08 i 6/1/05 7/1/05 pH - Background D072 (CRS) 7-D072 8.08 S8.08 6/1/05 7/1/05 pH - Effluent - P-D071 (CRS) P-D071 8.15 8.15 6/1/05 7/1/05 pH - Effluent - P-D072 (CRS) P-D072 8.17 8.17 6/1/05 7/1/05 pH - Ex of Calc Limit - R-D071 (CRS) R-D0717 1.1 -0.35 6/1/05 7/1/05 pH - Ex of Calc Limit - R-D072 (CRS) -0.33 R-D072 1.1 6/1/05 7/1/05 pH -Calc Limit - Q-D071 (CRS) Q-D071 I 7.08 8.5 ~1~~ 6/1/05 7/1/05 pH -Calc Limit - Q-D072 (CRS) 8.5 Q-D072 7.08 10/21/2009 Page 10

Crystal River South DMR Data Permit No. FL00000159 Begin date EndoDate

Bgh~a~e;]*,En~'.Dte ;]*.;:J* ;PARAMETER.. NAME* . *.d outall-- . CAvg;*.f:--- -t.m. ;: C-~ x

                                                                                                                          ':.T*Max!*i..            .i;'i:       x.  ýNl -A OD I-Max'vg*
                                                                                                                                                                                ,       NODI-Min 6/1/05            7/1/05      Resid Ox - Dis Time - D071 (CRS)                D071                                               0 4

6/1/05 7/1/05 Resid Ox - Dis Time - D072 (CRS) D072 0 6/1/05 7/1/05 Resid Ox - Dis Time P-DOll (CRS) P-D011 0

                                                                    -       I 6/1/05            7/1/05       Resid Ox - Dis Time P-D012 (CRS)              P-DO12                                              0 6/1/05            7/1/05      Temp Rise - Doll (CRS)                          Dol1          8.6                                11.9 6/1/05            7/1/05     JTemp Rise - D012 (CRS)                          D012          8.6                                11.9 6/1/05            7/1/05      Temp-Discharge - Doll (CRS)                     Doll         93.3                                95.6 6/1/05            7/1/05      Temp-Discharge - D012 (CRS)                     D012         93.3                                95.6 6/1/05            7/1/05      Temp-Intake - Doll (CRS)                        DOll         84.7                         4      89.6 6/1/05            7/1/05      Temp-Intake - D012 (CRS)                        D012         84.7                         T      89.6 6/1/05            7/1/05      Total Recoverable Iron D-600 (CRS) v2           D-600                                           17000 7/1/05            8/1/05       Flow - Doll (CRS) v2                           Doll                                                         1664          1693.3 7/1/05            8/1 /05     Flow - Intake - D071 (CRS) v2                   D071                                                        443.82          504 7/l/05                /05    IFlow -  Intake - D072 (CRS) v2                  D072                                                        478.24          504 I

7/1/05 7/1/05 8/1,/05 8/11/05 Flow D-600 (CRS) v2 pH - Background D071 (CRS) v2 D-600 7-D071 8.3 V 0.01 I 7/1/05 8/1 /05 pH - Background D072 (CRS) v2 7-D072 8.3 8.3 l 7/1/05 8/1 /05 pH - Effluent - P-D071 (CRS) v2 P-D071 8.4 8.4 7/1/05 8/1 /05 pH - Effluent - P-D072 (CRS) v2 P-D072 8.4 8.4 7/1/05 8/1 /05 pH - Ex of Calc Limit - R-D071 (CR5) v2 R-D071 1.1

                                                                                                                                -0.1

___ 1.1 7/1/05 8/1/05 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 7/1/05 8/1/05 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.3 8.5 7/1/05 8/1/05 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.3 08.5 7/1/05 8/1/05 Resid Ox - Dis Time - D071 (CRS) v2 D071 - _ _ _0 . .. . .. 7/1/05 8/1/05 Resid Ox - Dis Time - D072 (CR5) v2 D072 0 7/1/05 8/1/05 Resid Ox - Dis Time P-DOll (CRS) v2 P-DO11 - 7/1/05 8/1/05 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012{ 0 7/1/05 8/1/05 Temp Rise - Doll (CRS) v2 Doll 7.2 10.4 7/1/05 8/1/05 Temp Rise - D012 (CRS) v2 D012 7.2 10.4 94.3 7/1/05 8/1/05 Temp-Discharge - Doll (CRS) v2 D*Oll I 94.3 T 96 7/1/05 8/1/05 Temp-Discharge - D012 (CR5) v2 I D0o12 7 I 96 7/1/05 8/1/05 Temp-Intake - Doll (CRS) v2 Doll 87.1 1 - 90.4 7/1/05 8/1/05 ITemp-Intake - D012 (CRS) v2 0012 87.1 - 90.4 - i 7/1/05 8/l/05 TTotal Recoverable Iron D-600 (CRS) v2 1900 D-600 ! 10/21/2009 Page 11

0 Crystal River South DMR Data Permit No. FL00000159 Bgndt EnDae PAAMTE NA EOtl CMn CMx 'Ag Q-Avg Q-Max., 1;ýNODI-Ayg, .,.NOD.I-Ma( 'NODI-Min-8/1/05 9/1/05 Flow - DOll (CRS) v2 D011 1682.5 1693.3 8/1/05 9/1/05 Flow - Intake - 0071 (CRS) v2 0071 497.73 504 8/1/05 9/1/05 Flow - Intake - 0072 (CRS) v2 D072 T 501.29 504 8/1/05 9/1/05 Flow D-600 (CRS) v2 D-600 0.03 8/1/05 9/1/05 pH - Background D071 (CRS) v2 7-DO71 8.15 -8.15 -i! 8/1/OS 1 9/1/05 pH - Background D072 (CRS) v2 7-0072 8.15 8.15 8/1/05 9/1/05 pH - Effluent - P-D071 (CRS) v2 P-D071 8.27 8.27 8/1/05 9/1/05 - pH - Effluent - P-D072 (CRS) v2 P-D072 8.27 1 -8.27 8/1/05 9/1/05 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1.1 -0.23 I -_ i 8/1/05 9/1/05 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 1.11 -0.23 8/1/o5 9/1/05 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.15 8.5 8/1/05 9/1/05 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.15 8.5 8/1/05 9/1/05 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 8/1/05 9/1/05 Resid Ox - Dis Time - D072 (CRS) v2 D072 - 0 P-D0ll 8/1/05 9/1/05 Resid Ox - Dis Time P-DOll (CRS) v2 0 8/1/05 9/1/05 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 - 7 0 9.7 8/1/05 9/1/05 {Temp Rise - D011 (CRS) v2 DO11 6.6 9.7 8/1/05 1 9/1/05 [Temp Rise - D012 (CRS) v2 D012 6.6 8/1/05 9/1/05 [Temp-Discharge - D011 (CRS) v2 D011 94.6 96.1 flfIll q4) 8/1/05 9/1/05 [Temp-Discharge - D012 (CRS) v2 96.1 8/1/05 9/1/05 Temp-Intake - DOll (CRS) v2 DOll 88 90.8 --- i--- 8/1/05 9/1/05 Temp-Intake - D012 (CRS) v2 D012 88 90.8 8/1/05 9/1/05 9/1/05 L 9/1/05 10/1/05 10/1/05 Total Recoverable Iron D-600 (CRS) v2 Flow - DOll (CRS) v2 Flow - Intake - D071 (CR5) v2 D-600 D011 D071 18000 1653.9 336.75 1693.33 504 9/1/05 10/1/05 Flow - Intake - D072 (CRS) v2 D072 [ I 328.97 504 9/1/05 10/1/05 [Flow D-600 (CRS) v2 0-600 0.07 8.01 8.01 9/1/05 10/1/05 pH - Background D071 (CRS) v2 7-D071 8.01 8.01 9/1/05 10/1/05 JpH - Background D072 (CRS) v2 7-D072 9/1/05 10/1/05 pH - Effluent - P-D071 (CRS) v2 P-D071I 8.1 8.1 9/1/05 10/1/05 pH - Effluent - P-D072 (CRS) v2 P-D072 8.09 8.09 9/1/05 J 10/1/o5 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071} 1.1 1.1

                                                                                                          -0.4
                                                                                                         -0.41 9/1/05        10/1/05   pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 9/1/05        10/1/o5   pH -Calc Limit - Q-D071 (CR5) v2        Q-D071                          7.01        8.5 10/21/2009                                                                    Page 12

0 Crystal River South DMR Data Permit No. FL00000159 Beidat End Date, PARA N4ETERNAME~2 Outall C-,Ay4+ C-Pax C-Min QAvg Q-Max NODl-Avig,,-'NODIWMax NO'DI-Min, 9/1/05 10/1/05 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.01 8.51 9/1/05 10/1/05 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 9/1/05 10/1/05 Resid Ox - Dis Time - D072 (CRS) v2 D072 9/1/05 10/1/05 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 9/1/05 10/1/05 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 o ii 9/1/05 10/1/05 Temp Rise - D011 (CRS) v2 D011 L 9.5 12.5 I I 9/1/05 10/1/05 Temp Rise - D012 (CRS) v2 D012 9.5 12.5 9/1/05 10/1/05 Temp-Discharge - D011 (CRS) v2 D011 93 95.6 95.6] 9/1/05 10/1/05 Temp-Discharge - D012 (CRS) v2 D012 93 9/1/05 10/1/05 Temp-Intake - D011 (CRS) v2 D011 83.6 86.2 _ 9/1/05 10/1/05 Temp-Intake - D012 (CRS) v2 D012 83.6 86.2 9/1/05 10/1/05 Total Recoverable Iron D-600 (CRS) v2 D-600 18000 Flow - D011 (CRS) v2 D011 1621.6 1759.7 10/1/05 11/1/05 10/1/05 11/1/05 Flow - Intake - D071 (CRS) v2 D071 274.8 504 10/1/05 11/1/05 Flow - Intake - D072 (CRS) v2 D072 177.98 504 10/1/05 11/1/05 Flow D-600 (CRS) v2 D-600 i 0.05 10/1/05 11/1/05 pH - Background D071 (CRS) v2 7-D071 8.12 8.12 10/1/05 11/1/05 pH - Background D072 (CRS) v2 7-D072 8.12 S8.12 8-09 F I_ 10/1/o5 11/1/05 pH - Effluent - P-D071 (CRS) v2 P-D071 _ 8.09 8.08 10/1/05 11/1/05 pH - Effluent - P-D072 (CRS) v2 P-D072 8.08 10/1/05 11/1/05 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1 -0.41

                                                                                                 --0.42-,

10/1/05 11/1/05 ]pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 1 10/1/05 11/1/05 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.12 8.5 10/1/05 11/1/05 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.12 8.5 10/1/05 11/1/05 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 10/1/05 11/1/05 Resid Ox - Dis Time - D072 (CRS) v2 D072 P-D011 0 10/1/05 11/1/05 [Resid Ox - Dis Time P-DO11 (CRS) v2 10/1/05 11/1/05 jResid Ox - Dis Time P-D012 (CRS) v2 P-DO12 - ~0 10/1/05 11/1/05 ýTemp Rise - D011 (CRS) v2 D011 12.3 84.3 15.9 10/1/05 11/1/05 ITemp Rise-D012 (CRS) v2 D012 I 12.3 15.9 10/1/05 11/1/05 .Temp-Discharge - D011 (CRS) v2 D011 _89.5 95.5 10/1/05 11/1/05 JTemp-Discharge - D012 (CRS) v2 D012 89.5 95.5 I__ 10/1/05 11/1/05 ITemp-Intake - D011 (CRS) v2 D011 77.1 84.3 10/1/05 11/1/05 jTemp-Intake - D012 (CRS) v2 001o2 77.1 10/21/2009 Page 13

0 Crystal River South DMR Data Permit No. FL00000159 ~Begin date4 End Date ~PARAMETER-NAME~ Outal C-Av 1/2C-Min)

                         *,*e*,,* *     **   $ * ,*J* ,*,* , * ....................................

T D-10/1/05 11/1/05 ITotal Recoverable Iron D-600 (CRS) v2 600 11/l/05 12/1/05 Flow - D011 (CRS) v2 D(011 1256.9 1579.2 D(071 0 0 11/1/05 12/1105 Flow - Intake - D071 (CRS) v2 1I ________________________i_

                                                                                                                               )72 11/1/05       12/1/05         lFlow - Intake - D072 (CRS) v2                                                                 D(                                           0           0 1111/05       12/1/05             Flow D-600 (CRS) v2                                                                       D-600                                                   0.03 11/1/05       12/1/05             Resid Ox - Dis Time - D071 (CRS) v2                                                        D(071                            0
                                                                                                                               )72                            0 11/1/05       12/1/05             Resid Ox - Dis Time - D072 (CRS) v2                                                        D(

11/1/05 12/1/05 Resid Ox - Dis Time P-DO11 (CRS) v2 P-r)011 0 11/l/05 12/1/05 Resid Ox - Dis Time P-D012 (CRS) v2 P-I)012 0 11/1/05 12/1/05 iTemp Rise - DOll (CRS) v2 Dl011 15.3 11/1/05 12/1/05 {Temp Rise - D012 (CRS) v2 Dl012 15.3 11/1/05 12/1/05 Temp-Discharge - DOll (CRS) v2 D(Oili 88.5 11/1/05 12/1/05 Temp-Discharge - D012 (CRS) v2 D(012 88.5 11/1/05 12/1/05 Temp-Intake - DOll (CRS) v2 D(Oil 73.6 11/1/05 12/1/05 [Temp-Intake - D012 (CRS) v2 D012 73.6 11/1/05 12/1/05 iTotal Recoverable Iron D-600 (CRS) v2 D-600 12000 12/1/05 1/1/06 [Flow - DOll (CRS) v2 DOll 1544.8 "_ 1612.9 12/1/05 1/1/06 Flow - Intake - D071 (CRS) v2 D071 o 0 _ 12/1/o5 1/1/06 Flow - Intake - D072 (CRS) v2 D072 0 0 I 12/1/05 1/1/06 Flow D-600 (CRS) v2 - 1 D-600 Kr0.02 12/1/05 1/1/06 Resid Ox - Dis Time - D071 (CRS) v2 D071 F-- 12/1/05 1/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 12/1/05 1/1/06 j Resid Ox - Dis Time P-DOll (CRS) v2 P-DOll . -- 12/1/05 1/1/06 jResid Ox - Dis Time P-D012 (CRS) v2 P-D012 12/1/05 1/1/06 iTemp Rise - DOll (CRS) v2 DOll 12.5 17.2 12/1/05 1/1/06 iTemp Rise - D012 (CRS) v2 D012 12.5 17.2 12/1/05 1/1/06 iTemp-Discharge - D011 (CRS) v2 Doll 70.9 77.5 12/1/05 1/1/06 ýTemp-Discharge - D012 (CRS) v2 D012 T 70.9 77.5 12/1/05 1/1/06 iTemp-Intake - DOll (CRS) v2 Doll 58.3 64.8 12/1/05 1/1/06 iTemp-lntake -D012 (CRS) v2 D012 58.3 64.8 12/1/05 1/1/06 [Total Recoverable Iron D-600 (CRS) v2 D-600 1700 1/1/06 2/1/06 Flow - D011 (CRS) v2 Doll 1562.2 1611.9 1/1/06 2/1/06 Flow - Intake - D071 (CRS) v2 D071 0 0 1/1/06 2/1/06 Flow - Intake - D072 (CRS) v2 D072 0 0 10/21/2009 Page 14

0 Crystal River South o DMVR Data Permit No. FL00000159 Begin date ~End Date ' PARAMETER-NAME ~tiK 00611 CŽAvg 1.i .Min: 1/1/06 2/1/06 Flow D-600 (CR5) v2 D-600 0.01 - 1/1/06 2/1/06 Resid Ox - Dis Time - D071 (CRS) v2 D071 1/1/06 2/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 1/1/06 2/1/06 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 1/1/06 2/1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 1/1/06 2/1/06 Temp Rise - DO11 (CRS) v2 D011 14.2 17.8 1/1/06 2/1/06 iTemp Rise - D012 (CRS) v2 D012 14.2 17.8 1/1/06 2/1/06 Temp-Discharge - D011 (CRS) v2 D011 73.8 81.3 1/1/06 2/1/06 Temp-Discharge - D012 (CRS) v2 D012 73.8 81.3 1/1/06 2/1/06 Temp-lntake - D011 (CRS) v2 D011 59.8 66.4 1/1/06 2/1/06 Temp-Intake - D012 (CRS) v2 D012 59.8 66.4 1/1/06 2/1/06 ITotal Recoverable Iron D-600 (CRS) v2 D-600 35000 2/1/06 3/1/06 Flow - D011 (CRS) v2 D011 1571.8 1611.9 2/1/06 3/1/06 Flow - Intake - D071 (CRS) v2 D071 12.95 16.78 2/1/06 3/1/06 Flow - Intake - D072 (CRS) v2 D072 T 20.43 38.82 2/1/06 3/1/06 Flow D-600 (CRS) v2 D-600 0.02 2/1/06 3/1/06 Resid Ox - Dis Time - D071 (CR5) v2 0D71 0 2/1/06 3/1/06 Resid Ox - Dis Time- D072 (CRS) v2 D072 0 2/1/06 3/1/06 Resid Ox - Dis Time P-DOll (CRS) v2 P-DOll -- 0 _ 2/1/06 3/1/06 lResid Ox - Dis Time P-DO12 (CRS) v2 P-DO12 0 2/1/06 3/1/06 Temp Rise - D011 (CRS) v2 DOll 15.6___ 17 2/1/06 3/1/06 ITemp Rise - D012 (CRS) v2 D012 15.6 17 2/1/06 3/1/06 ITemp-Discharge - D011 (CRS) v2 D011 75.2 83.4 2/1/06 3/1/06 FTemp-Discharge - D012 (CRS) v2 D012 75.2 83.4 2/1/06 3/1/06 Temp-Intake - D011 (CRS) v2 D011 59.6 66.1 2/1/06 3/1/06 Temp-intake - D012 (CRS) v2 D012 59.6 66.1 2/1/06 3/1/06 iTotal Recoverable Iron D-600 (CRS) v2 D-600 53000 3/1/06 4/1/06 Flow- D011 (CRS)v2 00D11 1583.9 1611. 9 3/1/06 4/1/06 Flow - Intake - D071 (CRS) v2 D071 0 0 3/1/06 4/1/06 Flow - Intake - D072 (CRS) v2 D072 - 0 3/1/06 4/1/06 Flow D-600 (CRS) v2 D-600 ! 00 3/1/06 4/1/06 Resid Ox - Dis Time - D071 (CR5) v2 D071 0 0 . f I____1 3/1/06 4/1/06 Resid Ox - Dis Time- D072 (CRS) v2 D072 _ 0 _ 3/1/06 4/1/06 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 - I 10/21/2009 Page 15

Crystal River South DMR Data Permit No. FL00000159 ~Begin date End Date PARAMETER NAME Outall C-Avg jC-Min~ C-Max 7 Q-Avg <IQ-Max I i NODI-Avg i NODI-Max INODI-Min i ! i 3/1/06 4/1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 3/1/06 4/1/06 Temp Rise - D011 (CRS) v2 D011 13.4 17.1 3/1/06 4/1/06 Temp Rise - D012 (CRS) v2 D012 13.4 17.1 3/1/06 4/1/06 Temp-Discharge - D011 (CRS) v2 D011 80.3 89.9 3/1/06 4/1/06 Temp-Discharge - D012 (CRS) v2 D012 80.3 89.9 3/1/06 4/1/06 Temp-Intake - D011 (CRS) v2 D011 67 72.9 3/1/06 4/1/06 Temp-Intake - D012 (CRS) v2 D012 67 72.9 3/1/06 4/1/06 ýTotal Recoverable Iron D-600 (CRS) v2 D-600 4/1/06 5/1/06 Flow - D011 (CRS) v2 - 1 DO11 1590.6 1611.9 4/1/06 5/1/06 /Flow - Intake - D071 (CRS) v2 D071 0 0 4/1/06 5/1/06 Flow - Intake - D072 (CRS) v2 D072 481 504 4/1/06 5/1/06 - Flow D-600 (CRS) v2 D-600 0.05 4/1/06 5/1/06 pH - Background D071 (CRS) v2 7-D071 7.93 7.93 4/1/06 5/1/06 pH - Background D072 (CRS) v2 7-D072 7.93 7.93 4/1/06 5/1/06 !pH - Effluent - P-D071 (CRS) v2 P-D071 8.09 8.09 4/1/06 [ 5/1/06 pH - Effluent - P-D072 (CR5) v2 P-D072 8.16 8.16 4/1/06 5/1/06 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1.2 -0.41 4/1/06 5/1/06 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 1.2 -0.34 4/1/06 5/1/06 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 6.93 8.5 4/1/06 5/1/06 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 6.93 8.5 4/1/06 5/1/06 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 4/1/06 - 5/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 4/1/06 5/1/06 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 4/1/06 5/1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 4/1/06 5/1/06 Temp Rise - D011 (CRS) v2 Do11 14.4 16.7 4/1/06 5/1/06 iTemp Rise - D012 (CRS) v2 D012 14.4 16.7 4/1/06 5/1/06 ITemp-Discharge - D011 (CRS) v2 D011 89.3 95.7 4/1/06 5/1/06 Temp-Discharge - D012 (CRS) v2 - D012 89.3 95.7 4/1/06 5/1/06 Temp-Intake - D011 (CRS) v2 D011 74.9 _-K 81.7 74.9 4/1/06 5/1/06 Temp-Intake - D012 (CRS) v2 D012 81.7 4/1/06 5/1/06 ýTotal Recoverable Iron D-600 (CRS) v2 D-600 NODI=G 5/1/06 6/1/06 Flow - D011 (CRS) v2 D011 1684.9 1693.3 5/1/06 6/1/06 Flow - Intake - D071 (CRS) v2 D071 110.36 504 -I 5/1/06 6/1/06 Flow - Intake - D072 (CR5) v2 D072 274.33 504 10/21/2009 Page 16

Crystal River South DMR Data Permit No. FL00000159 Begin dae EdDate PARAMETER-NAME ~~ OutaW<l C-Av - NODI'-Max NODI-Min 5/1/06 6/1/06 Flow D-600 (CRS) v2 D-600 5/1/06 6/1/06 pH - Background D071 (CRS) v2 7-D071 8 5/1/06 6/1/06 7-D072 8 I 8 PH - Background D072 (CRS) v2 i.11 5/1/06 6/1/06 pH - Effluent - P-D071 (CRS) v2 P-D071 8 8.11 1.1 5/1/06 6/1/06 PH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 -0.39 5/1/06 6/1/06 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7 8.5 8.5 5/1/06 6/ 1/06 pH -Calc Limit - O-D072 (CR5) v2 Q-D072 7 5/1/06 1/06 6/ 1/06 Resid Ox - Dis TimeD-D071 (CR5) Resid Ox- Dis Time- D072 (CRS) v2 v2 071 0072 t

                                                                                                                        ----0
                                                                                                                 ~00          __

5/1/06 6/ 1/06 iResid Ox - Dis Time P-D07l (CRS) v2 P-D07l 0 5/1/06 6/ ,1/06 Resid Ox -Dis Time P-DO12 (CRS) v2 P-DOl2 5/1/06 6/ 1/06 Resid Ox - Ois Time P-D012 (CR5) v2 P-DO12 - 0 5/1/06 6/ 1/06 Temp Rise - D011 (CRS) v2 D011 13.4 15.2 __.r 5/1/06 6/ 1/06 Temp Rise - D012 (CRS) v2 D012 13.4 7~i 5/1/06 6/ 1/06 [Temp-Discharge - D011 (CRS) v2 D011 91.8 96.1 1/06 Temp-Discharge - D012 (CRS) I D012 5/1/06 6/ 91.8 1/06 Temp-Intake - D011 (CR5) v2 D011 5/1/06 6/ 78.4 84.3 5/1/06 6/ 1/06 Temp-Intake - D012 (CR5)v2 0D12 78.4 84.3 11000 5/1/06 6/ 1/06 Total Recoverable Iron D-600 (CRS) v2 D-600 6/1/06 7/ 1/06 Flow - Do11 (CRS) v2 D011 1648 1693.3 6/1/06 7/ 1/06 Flow - Intake - D071 (CRS) v2 D071 397.16 611.66 6/1/06 7/ 1/06 Flow - Intake - D072 (CRS) v2 D072 411.46 600.52 6/1/06 7/ 1/06 Flow 0-600 (CR5) v2 0-600 . I.

                                                                                                                                     ....        0.02 6/1/06      7/ 1/06   pH - Background D071 (CRS) v2          [ 7-D071                          8.13 8.13 6/1/06      7/ 1/06   pH - Background 0072 (CRS) v2            7-0o72                          8.13 6/1/06      7/ 1/06   pH - Effluent - P-D071 (CRS) v2              P-D071                          8.15           8.15 6/1/06      7/ 1/06   pH - Effluent - P-D072 (CRS) v2              P-D072                   F         -8.14       8.14 6/1/06      7/ 1/06   pH - Ex of Calc Limit - R-D071 (CRS)  v2Q    R-D071f                                       -0.35 1          -0.36 6/1/06      7/ 1/06   pH - Ex of Calc Limit - R-D072 (CRS) v2      R-D072    I 6/1/06      7/ 1/06   pH -Calc Limit - Q-D071 (CRS) v2             Q-D071                                          8.5 6/1/06      7/ 1/06   pH -Calc Limit - Q-D072 (CRS) v2          IQ-072                             7.13            8.5 6/1/06      7/ 1/06   Resid Ox - Dis Time - 0071 (CR5) v2            D071                          7.13_____-

__ 0 o 6/1/06 7/ 1/06 Resid Ox - Dis Time - D072 (CRS) v2 0 D072 I 0 1/06 Resid Ox - Dis Time P-D0ll (CR5) v2 P-D0ll 6/1/06 7/ 1/06 Resid Ox - Dis Time P-D011 (CRS) v2 P-D011 1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 6/1/06 7/1 -i 0 10/21/2009 Page 17

0 Crystal River South DMR Data Permit No. FL00000159 t Endl*Date .... ARAMETER*'*'

                                                       "..NAM
                                                           , :     -*.ti--*-   * ;.e,-         * , - :*       -C,    n.

Begin dateý 6/1/06 7/1/06 Temp Rise - D011 (CR5) v2 D011 9.8 13.3 6/1/06 7/1/06 {Temp Rise-D012 (CRS) v2 D012 9.8 13.3 6/1/06 7/1/06 Temp-Discharge - Do11 (CRS) v2 D011 93 95.9 6/1/06 7/1/06 Temp-Discharge - D012 (CRS) v2 D012 __9 I 95.9 6/1/06 7/1/06 ITemnp-Intake - D011 (CRS) Q Don1 83.2 I 87.4 6/1/06 7/1/06 ITemp-lntake - D012 (CR5) v2 D012 83.2 87.4 1 7/1/06 Total Recoverable Iron 0-600 (CRS)v2 D-600 6/1/06 31000 7/1/06 8/1/06 Flow- 011 (CRS) v2 D011 1645.4 I 1693.3 7/1/06 8/1/06 'Flow - Intake - D071 (CRS)v2 D071 I - 487.4 i 604.81 7/1/06 8/1/06 Flow - Intake -D072 (CRS)v2 0072--D72 528.33 596.22 7/1/06 8/1/06 Flow D-600 (CRS) v2 0-600 0.05 7/1/06 8/1/06 pH - Background D071 (CRS) v2 7-071 8.28 8.28 ! 7/1/06 8/1/06 pH - Background D072 (CRS) v2 7-D072 8 28 8.28 --- q S 8.16 7/1/06 8/1/06 -pH - Effluent - P-D071 (CRS) v2 P-D071 8.16 I l 7/1/06 8/1/06 pH - Effluent - P-D072 (CRS) v2 P-D072 8.17 8.17 7/1/06 8/1/06 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 0.9 -0.34 7/1/06 8/1/06 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 0.9 -0.33 i .... 7/1/06 8/1/06 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.22 8.5 -i--- 7/1/06 8/1/06 pH -Calc Limit - Q-D072 (CR5) v 7.28 8.5 7/1/06 8/1/06 Resid Ox - Dis Time - D071 (CR) v2 D071 0 7/1/06 8/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072

                                                                                                                           --0 o0         I 7/1/06         8/1/06      Resid Ox - Dis Time P-DO11 (CRS) v2                  P-DO11 7/1/06         8/1/06      Resid Ox - Dis Time P-D012 (CRS) v2                  P-D012                                 10 F--

7/1/06 8/1/06 iTemp Rise- DOll (CRS) v2 DOll 7.4 9.1 7/1/06 8/1/06 iTemp Rise - D012 (CRS) v2 D012 7.4 _ 9.1 7/1/06 8/1/06 iTemp-Discharge - D011 (CRS) v2 0011 93.8 96 7/1/06 8/1/06 Temp-Discharge - D012 (CRS) v2 D012 93.8 96 7/1/06 8/1/06 Temp-Intake - D01 (CRS)v2QDOl 86.4 89.4 _ 7/1/06 8/1/06 Temp-lntake - D012 (CRS) v2 D0012 I 86.4 89.4 ! 7/1/06 8/1/06 Total Recoverable Iron D-600 (CRS) v2 D-600 3700 8/1/06 9/1/06 Flow - D011 (CRS) v2 D011 1646. 1693.3 7 -I--. 8/1/06 9/1/06 Flow - Intake - D071 (CRS) v2 D071 511.8 643.68 8/1/06 9/1/06 Flow - Intake - D072 (CRS) v2 D072 525.6 *6 623.52 8/1/06 9/1/06 Flow 0-600 (CRS) v2 0-600 D 0.01 10/21/2009 Page 18

0 Crystal River South DMR Data Permit No. FL00000159 X';AI'*PR E~TER*NAME*, Out Outal[ I -Avg CM'in `C-Mý Q-Avg Q-Max. ,NODI-Avg NODI-Max NoDiiMin Begi* date End Date , RAM -N I Oua*

                                                                     .                 ,<j 8/1/06       9/1/06    pH - Background D071 (CRS) v2            7-D071                       7.96          7.96 8/1/06       9/1/06    pH  -   Background D072 (CRS) v2         7-D072                       7.96          7.96
                                                                                                                                    '        I   _    _  _

8/1/06 9/1/06 pH - Effluent - P-D071 (CRS) v2 P-D071 8.04 8.04 8/1/06 9/1/06 pH - Effluent - P-D072 (CRS) v2 P-D072 8.08 8.08 1.1 -0.46 8/1/06 9/1/06 pH - Exof Cavc Limit - R-D071 (CRS) v2 R-D071

                                                                                                 -1.1   -

8/1/06 9/1/06 pH - Ex of CaIc Limit - R-D072 (CRS) v2 R-D072 8/1/06 9/1/06 pH -Calc Limit - Q-D071 (CR5) v2 Q-D071 6.96 8.5 i 8/1/06 9/1/06 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 I1 6.96 2 8.5 8/1/06 9/1/06 Resid Ox- Dis Time - D071 (CRS) v2 D071 0 8/1/06 9/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 8/1/06 9/1/06 Resid Ox - Dis Time P-DOll (CRS) v2 P-DOll V -- 0 8/1/06 9/1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 8/1/06 9/1/06 Temp Rise -0i01 (CR5) v2 012I 6.4 8/1/06 9/1/06 Temp Rise - D012 (CR5) v2 D012 6.4 8.4 8/1/06 9/1/06 Temp-Discharge - D01o (CRS) v2 D01o 93.8 96.3 8/1/06 9/1/06 Temp-Discharge - D012 (CRS) v2 D012 T- 9318 96.3 8/1/06 9/1/06 Temp-Intake - D01o (CRS) v2 D01l 87.4 90 7-8/1/06 9/1/06 Temp-Intake - D012 (CRS) v2 D012 87A4 90 8/1/06 9/1/06 Total Recoverable iron D-600 (CRS) v2 D-600 7100 1F 9/1/06 10/1/06 Flow - D011 (CRS) v2 Doll ;63.7 1693.3 9/1/06 10/1/06 Flow - Intake - D071 (CRS) v2 D071 37 0.12 513.84 9/1/06 10/1/06 TFlow - Intake - D072 (CRS) v2 D072 4333.56 519.81 9/1/06 10/1/06 Flow D-600 (CRS) v2 -600 D 0.02 9/1/06 10/1/06 pH - Background D071 (CRS) v2 7-0071 7.97 7.97 9/1/06 10/1/06 pH - Background D072 (CRS) v2 7-D072 -7.97-7 7.97 9/1/06 10/1/06 pH - Effluent - P-D071 (CRS) v2 P-D071 8.07 8.07 9/1/06 10/1/06 IpH - Effluent - P-D072 (CRS) v2 P-D072 8.08 8.08 i

                                                                                                                                -T 9/1/06      10/1/06  jpH - Ex of Calc Limit - R-D071 (CRS) v2       R-D071                                    -0.43 9/1/06      10/1/06    pH - Ex of Calc Limit - R-D072 (CRS) v2      R-D072                       1.1          -0.42 9/1/06      10/1/06    pH -Calc Limit - Q-D071 (CRS) v2             Q-D071                       6.97     _1 8.5 9/1/06      10/1/06    pH -Calc Limit D072 (CRS) v2             0Q-D072                      6.97           8.5 9/1/06      10/1/06    Resid Ox - Dis Time - D071 (CRS) v2            D071                                       0  _

9/1/06 10/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 I 9/1/06 10/1/06 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 _ 10/21/2009 Page 19

0 Crystal River South DMR Data Permit No. FL00000159 Bei aePRAEE En ae AEOutaIIl ~C-Avg C-Mm n C-Max Q-Avg .Q-max NODI-Avg NODI-Max 1NODI-Min 9/1/06 10/1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 i 0 -F D011 9/1/06 10/1/06 Temp Rise - D011 (CRS) v2 8.9 12.7 9/1/06 10/1/06 ITemp Rise - D012 (CRS) v2 D012 -1 8.9 12.7 10/1/06 Temp-Discharge - D011 (CRS) v2 D011 92.2 i 95.4 9/1/06 9/1/06 10/1/06 Temp-Discharge - D012 (CRS) v2 D012 92.2 95.4 9/1/06 10/1/06 ITemp-Intake - DOll (CRS) v2 D011 83.2 86.7 9/1/06 10/1/06 Temp-Intake - D012 (CRS) v2 D012 83.2 I 86.7 9/1/06 10/1/06 [Total Recoverable Iron D-600 (CRS) v2 0-600 23000 10/1/06 11/1/06 Flow - D011 (CRS) v2 DOll 1543 1693.3 1 i 10/1/06 11/1/06 Flow - Intake - D071 (CRS) v2 D071 233.29 252 10/1/06 11/1/06 Flow - Intake - D072 (CRS) v2 D072 45.83 79.66 10/1/06 10/1/06 11/1/06 11/1/06 Flow D-600 (CRS) v2 pH - Background D071 (CRS) v2 D-600 7-D071

                                                                                                           -I-                            --- I-0.02   I NODI=E    NODI=E 10/1/06      11/1/06     pH - Background D072 (CRS) v2       7-D072                                                                                                 NODI=E    NODI=E I

10/1/06 11/1/06 pH - Effluent - P-D071 (CRS) v2 P-D071 NODI=E NODI=E 10/1/06 11/1/06 pH - Effluent - P-D072 (CRS) v2 P-D072 NODI=E NODt=E 10/1/06 11/1/06 IpH - Ex of Calc Limit - R-D071 (CR5) v2 R-D071 NODI=E 10/1/06 11/1/06 1pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 NODI=E i1NODI=E NODI=E 10/1/06 11/1/06 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 I - NODI=E NODI=E 10/1/06 11/1/06 pH -Calc Limit - Q-D072 (CRS) v2 OQ-D072 NODI=E NODI=E 10/1/06 11/1/06 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 10/1/06 11/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 10/1/06 11/1/06 Resid Ox - Dis Time P-DO11 (CRS) v2 P-Do11 0 10/1/06 11/1/06 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 10/1/06 11/1/06 Temp Rise - D011 (CRS) v2 Doll 14.4 16.4

                                                                                                                  --16.4 - 7 10/1/06      11/1/06     Temp Rise - D012 (CRS) v2                D012         14.4                                  9. 7 10/1/06      11/1/06    Temp-Discharge - D011 (CRS)v Q            D011         90.1                                  95.7 10/1/06      11/1/06     Temp-Discharge - D012 (CRS) v2           D012         90.1                                    295.79 10/1/06      11/1/06     Temp-Intake - D011 (CRS) v2              D011         75. 8                                 82.91 10/1/06      11/1/06    Temp-Intake - D012 (CRS) v2               D012         75. 8                                 82.93 23000 10/1/06      11/1/06    Total Recoverable Iron D-600 CRS) v2     D-600 11/1/06      12/1/06     Flow - D011 (CRS) v2                     0011      _

1568.6 1612.9 iiI 11/1/06 12/1/06 Flow - Intake - D071 (CRS) v2 D071 0 0 11/1/06 12/1/06 Flow - Intake - D072 (CRS) v2 D072 0.71 4.98 10/21/2009 Page 20

Crystal River South DMR Data Permit No. FL00000159 Bein dat '~End Date PARAMETER NAME~ Outall C-Av c-M-I ,v -a I-aOIv OIMxND-i 11/1/06 12/1/06 Flow D-600 (CRS) v2 D-600 0.02 11/1/06 12/1/06 pH - Background D071 (CRS) v2 7-D071 NODI=E NODI=E 11/1/06 12/1/06 pH - Background D072 (CRS) v2 7-D072 NOD =9 NODI=9 11/1/06 12/1/06 pH - Effluent - P-D071 (CRS) v2 P-D071 NOD1= E NODI=E 11/1/06 12/1/06 pH - Effluent - P-D072 (CRS) v2 P-D072 NOD1=9 NODI=9 11/1/06 12/1/06 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 NOD1= E NODI=E 11/1/06 11/1/06 12/1/06 12/1/06 pH - Ex of Calc Limit - R-D072 (CRS) v2 pH -Calc Limit - Q-D071 (CRS) v2 R-D072 Q-D071

                                                                                                              ~.l.

N001=9 NODI=E 1 NODI=9 NODI=E 11/1/06 12/1/06 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 NODI=9 NODI=9 11/1/06 12/1/06 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 11/1/06 12/1/06 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 11/1/06 12/1/06 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 11/1/06 12/1/06 Resid Ox - Dis Time P-D012 (CR5) v2 P-D012 0 11/1/06 12/1/06 Temp Rise - DO11 (CRS) v2 D011 15.7 17.6 1 15.7 11/1/06 12/1/06 Temp Rise - D012 (CRS) v2 D012 17.6 11/1/06 12/1/06 Temp-Discharge - D011 (CRS) v2 D011 80.8 88.5 11/1/06 12/1/06 Temp-Discharge - D012 (CRS) v2 D012 80.8 88.5 11/1/06 12/1/06 Temp-Intake - D011 (CRS) v2 D011 65.1 72,2 11/1/06 12/1/06 Temp-Intake - D012 (CRS) v2 D012 65.1 72.2 11/1/06 12/1/06 Total Recoverable Iron D-600 (CRS) v2 D-600 16000 12/1/06 1/1/07 Flow - D011 (CRS) v2 D011 1544.6 1612.9 12/1/06 1/1/07 Flow - Intake - D071 (CRS) v2 D071 0 0 12/1/06 1/1/07 Flow - Intake - D072 (CRS) v2 D072 01 0 12/1/06 1/1/07 Flow D-600 (CRS) v2 D-600 0.03 i 1 12/1/06 1/1/07 I pH - Background D071 (CRS) v2 7-D071 1 NODI=E NO 1= E 12/1/06 1/1/07 pH - Background D072 (CRS) v2 7-D072 NODI=9 NODI=9 12/1/06 1/1/07 pH - Effluent - P-D071 (CRS) v2 P-D071 NODI=E NODI=E 12/1/06 1/1/07 I pH - Effluent - P-D072 (CRS) v2 P-D072 NODI=9 NODI=9 4 12/1/06 1/1/07 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1NODI=E NODI=E 12/1/06 1/1/07 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 NODI=9 NODI=9 12/1/06 1/1/07 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 NODI=E NODI=E 12/1/06 1/1/07 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 NODI=9 NODI=9 12/1/06 1/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 12/1/06 1/1/07 Resid Ox - Dis Time - D072 (CRS) v2 0072 0 L __________ L I 10/21/2009 Page 21

0 Crystal River South DMR Data Permit No. FL00000159 ________t ~ -ax~ Q-Avg I Q-MaxA NODI-Avg NODI-Max NODI-Min 12/1/06 1/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-D011 0 12/1/06 1/1/07 Resid Ox - Dis Time P-D012 (CRS)_v2 P-D012 0 Temp Rise - D0ll (CRS) v2 Doll 16.2 12/1/06 1/1/07 17.3 Temp Rise - D012 (CRS) v2 D012 16.2 12/1/06 1/1/07 7 17.3 12/1/06 12/1/06 1/1/07 1/1/07 Temp-Discharge - D012 (CR5) v2 Temp-Discharge - D012 (CRS) v2 D011 D012 79.3 79.3 85.7 85.7 IV 12/1/06 Temp-Intake - D01o (CRS)v2 D01l 63.1 1/1/07 68.3 12/1/06 Temp-Intake - D012 (CRS) v2 D012 63.1 1/1/07 68.3 12/1/06 111/07 Total Recoverable Iron D-600 (CRS) v2 D-600 580 1/1/07 2/1/07 Flow - D011 (CRS) v2 D011l 1523.5 1573 1/1/07 2/1/07 Flow - Intake - D071 (CRS) v2 D071 21.53 21.53 - 1/1/07 2/1/07 Flow - Intake - D072 (CRS) v2 D072 17.76 43.48 1/1/07 1/1/07 2/1/07 Flow D-600 (CR5) v2 D-600 0.01 1/1/07 2/1/07 pH - Background D071 (CRS) v2 7-D071 NOD1=9 NODI=9 1/1/07 2/1/07 pH - Background D072 (CRS) v2 I 7-D072 NODI=9 NODI=9 1/1/07 2/1/07 pH - Effluent - P-D071 (CRS) v2 P-D071 NODI=9 NO001=9 1/1/07 2/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 NOD1=9 NODI=9 1/1/07 2/1/07 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 NODI=9 NODI=9 1/1/07 2/1/07 pH - Ex of Calc Limit - R-D072 (CRS) v2 Q R-D072 NODI=9 NODI=9 2/1/07 pH -Calc Limit - 0.-D071 (CR5) v2 Q-D071 NODI=9 NODI=9 1/1/07 1/1/07 2/1/07 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 NODI=9 NODI=9 1/1/07 2/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0

                                                                                                                                       -F 1/1/07       2/1/07  Resid Ox  - Dis Time  -   D072 (CRS) v2      D072                          0 T

1/1/07 2/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 1/1/07 2/1/07 Resid Ox - Dis Time P-D012 (CR5) v2 P-D012 0 1/1/07 2/1/07 Temp Rise - D011 (CRS) v2 D011 16.3 17.5 1/1/07 2/1/07 Temp Rise - D012 (CRS) v2 D012 16.3 17.5 1/1/07 2/1/07 Temp-Discharge - D011 (CRS) v2 D011 78.9 87.3 1/1/07 2/1/07 Temp-Discharge - D012 (CRS) v2 D012 78.9 87.3 1/1/07 2/1/07 Temp-Intake - D011 (CRS) v2 D011 62.7 70.5 1/1/07 2/1/07 Temp-Intake - D012 (CRS) v2 D012 I 62.7 70.5 2/1/07 2/1/07 Total Recoverable Iron D-600 (CRS) v2 D-600 770 2/1/07 3/1/07 Flow - D011 (CRS) v2 D011 1319.7 1553.5 2/1/107 3/1/07 Flow - Intake - D071 (CR5) v2 D071 0 0 10/21/2009 Page 22

0 Crystal River South DMR Data Permit No. FL00000159 Beg.n.d.t.End.Date.... Begi date E Da P'ARAMETER NAME Outall Av C-Av. M...... Min .- C-MaxK........... *'Q-Av Q-A ..... .. .....NODI-Avg Q-Max . ...o... .. NOD... M..

                                                                                                                                         ... . .....*-NODIMax            .. ..

2/1/07 3/1/07 Flow - Intake - D072 (CRS) v2 D072 22.33 22.33 2/1/07 3/1/07 Flow D-600 (CRS) v2 D-600 0.03 211107 3/1/07 pH - Background D071 (CRS) v2 7-D071 N0D0-=9 NODI=9 2/1/07 3/1/07 pH - Background D072 (CRS) v2 7-D072 NODI=9 NODI=9

NODI=9 2/1/07 3/1/07 pH_- Effluent - P-D071 (CRS) v2 " P-DO71_I NODI=9 NO 01=9 2/1/07 3/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 NODI=9 N001=9 2/1/07 3/1/07 pH - Ex of Calc Limit - R-D071 (CRS) v2 ER-D071
NODI=9 NO 01=9 2/1/07 3/1/07 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 NODI=9 NODI=9 2/1/07 3/1/07 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071_2 NODI=9 2/1/07 3/1/07 pH -CaIc Limit D072 (CRS) v2 Q-D072 NO 01=9 2/1/07 3/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 2/1/07 3/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 -

2/1/07 3/1/07 Resid Ox - Dis Time P-D011 (CRS) v2 P-DOll 0 2/1/07 3/1/07 P-DO12 0 i Resid Ox - Dis Time P-D012 (CRS) v2 t D011 2/1/07 3/1/07 Temp Rise - D011 (CRS) v2 15.6 17.8 2/1/07 3/1/07 Temp Rise - D012 (CRS) v2 D012 15.6 17.8 D011 2/1/07 3/1/07 ]Temp-Discharge - D011 (CRS) v2 74.6 2/1/07 3/1/07 ýTemp-Discharge - D012 (CRS) v2 D012 74.6 83.6

                                                                                                                                      +/-L 2/1/07        3/1/07  Temp-Intake - D011 (CRS) v2                D011         59                66.3 2/1/07       3/1/07  Temp-Intake     -   D012 (CRS) v2          D012         59                 66.3 2/1/07 3/1/07 3/1/07 4/1/07 Total Recoverable Iron D-600 (CRS) v2 Flow - D011 (CRS) v2 DO011 D-600    _                     8700 1328.2    1478.3 D071 3/1/07        4/1/07  Flow - Intake - D071 (CRS) v2                                                                     0i       0 3/1/07        4/1/07  Flow - Intake - D072 (CRS) v2 i D072 I                                                2.25    11.16 3/1/07        4/1/07  Flow D-600 (CRS) v2                        0-600                                                         0.01 3/1/07        4/1/07  pH - Background D071 (CRS) v2         7-D071                                                                               ,    NODI=E   NOD1=E 3/1/07        4/1/07  pH - Background D072 (CRS) v2        7-D072                                                                                     NODI=E   NODI=E 4/1/07  pH - Effluent - P-D071 (CR5) v2 3/1/07                                                         P-D071                                                                                     NODI=E   NODI=E 4/1/07  pH - Effluent - P-D072 (CRS) v2 3/1/07                                                         P-D072                                                                                     NODI=E   NODI=E 4/1/07  pH - Ex of Cafc Limit - R-D071 (CRS) v2 3/1/07                                                         R-D071                                                                                     NOD l=E  NODI=E 4/1/07  pH - Ex of Calc Limit - R-D072 (CRS) v2 3/1/07        4/1/07  pH -Calc Limit - Q-D071        (CRS) v2     R-D072                                                                                     NOD[ =.E NODI=E 3/1/07                                                         Q-D071                                                                                     NODI=E   NODI=E Q-0072 3/1/07        4/1/07  pH -Calc Limit    -  Q-D072 (CRS) v2                                                                                          I     NODI=E 00D71 3/1/07        4/1/07  Resid Ox  - Dis Time    - D071 (CRS) v2                                     0 10/21/2009                                                                 Page 23

0 Crystal River South DMR Data Permit No. FL00000159 Begin date End Date PARAMETER-NAME O6utall C-Avg' -Min 3/1/07 4/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 3/1/07 4/1/07 Resid Ox - Dis Time P-DOll (CRS) v2 P-Do11 0 [ 3/1/07 4/1/07 IResid Ox - Dis Time P-D012 (CR5) v2 P-D012 0 i 3/1/07 4/1/07 Temp Rise - D011 (CRS) v2 D011 15.7 18.3 3/1/07 4/1/07 Temp Rise - D012 (CRS) v2 D012 15.7 18.3 3/1/07 4/1/07 Temp-Discharge - DOll (CRS) v2 D011 83.7 90.8 3/1/07 4/1/07 Temp-Discharge - D012 (CRS) v2 D012 83.7 90.8 3/1/07 4/1/07 Temp-Intake - DO11 (CRS) v2 DO11 68.1 73.8 D012 68.1 73.8 3/1/07 4/1/07 Temp-Intake - D012 (CRS) v2 Total Recoverable Iron D-600 (CRS) v2 D-600 310 3/1/07 4/1/07 4/1/07 5/1/07 Flow - DO11 (CRS) v2 DOll 1224.8 1230.2 1 I 4/1/07 5/1/07 Flow - Intake - D071 (CRS) v2 D071 _ 3.33 10.76 t i 4/1/07 5/1/07 Flow - Intake - D072 (CRS) v2 D072 11.48 I 30.24 I 4/1/07 5/1/07 Flow D-600 (CRS) v2 D-600 S0.02 i 4/1/07 5/1/07 pH - Background D071 (CRS) v2 7-D071 NODI=9 NODI=9 4/1/07 5/1/07 pH - Background D072 (CRS) v2 7-D072 NOD1=9 NOD=9 4/1/07 5/1/07 pH - Effluent - P-D071 (CRS) v2 P-D071 NODI=9 NODI=9 4/1/07 5/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 NOD1= NODI=9 NODI=9 4/1/07 5/1/07 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 I -

                                                                                                          --     -          i               NODI=9 N001=9 4/1/07        5/1/07   pH - Ex of Calc Limit - R-D072 (CRS) v2   R-D072                                                                     NODI=9 NODI=9 4/1/07        5/1/07   pH -Calc Limit - Q-D071 (CRS) v2          Q-D071                                                                     NODI=9 NODI=9 4/1/07        5/1/07   pH -Calc Limit - Q-D072 (CRS) v2          Q-D072                                                                     NOD [=9 4/1/07        5/1/07   Resid Ox - Dis Time - D071 (CRS) v2     . D071                               0 I           i-      - .

4/1/07 5/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 ' 0 4/1/07 5/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 4/1/07 5/1/07 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 4/1/07 5/1/07 Temp Rise - D011 (CRS) v2 D011 15.4 16.6 4/1/07 5/1/07 Temp Rise - D012 (CRS) v2 D012 15.4 16.6 4/1/07 5/1/07 ITemp-Discharge - D011 (CRS) v2 D011 85.7 94.1 4/1/07 5/1/07 Temp-Discharge - D012 (CRS) v2 D012 85.7 94.1 4/1/07 5/1/07 Temp-Intake - D011 (CRS) v2 D011 70.4 77.5 4/1/07 5/1/07 Temp-Intake - D012 (CRS) v2 D012 70.4 77.5 4/1/07 5/1/07 Total Recoverable Iron D-600 (CRS) v2 D-600 450 5/1/07 6/1/07 Flow - D011 (CRS) v2 D011 1407 1637 10/21/2009 Page 24

Crystal River South DMR Data Permit No. FL00000159 PARAMETER NAME Outall I Cvg C-Mn

                                                                                             --         Max   Q-vg   Q-Max       NODIAvgg NODI-Max NODI-Min,

Begin date End Date 6/1/07 Flow - Intake - D071 (CRS) v2 D071 114.87 397.33 5/1/07 5/1/07 6/1/07 Flow - Intake - D072 (CRS) v2 D072 328.37 549.3 6/1/07 Flow D-600 (CRS) v2 D-600 NODI=9 5/1/07 5/1/07 6/1/07 ipH - Background D071 (CRS) v2 7-D071 7.9 7.9 5/1/07 6/1/07 pH - Background D072 (CRS) v2 D072 7.9 7.9 5/1/07 6/1/07 pH - Effluent - P-D071 (CRS) v2 7 8.03 8.03 P-D071 5/1/07 6/1/07 pH - Effluent - P-D072 (CRS) v2 8.04 8.04 P-D072 pH - Ex of Calc Limit - R-D071 (CRS) Vv2 R-D071 1.1 -0.47 5/1/07 6/1/07 1.1 5/1/07 6/1/07 pH - Ex of Calc Limit - R-D072 (CRS) Vv2 R-D072 -0.46 5/1/07 6/1/07 pH -CaIc Limit - Q-D071 (CRS) v2 Q-D071 6.9 8.5 5/1/07 6/1/07 pH -Calc Limit - Q-D072 (CRS) v2 6.9 8.5 Q-D072 D071 0 5/1/07 6/1/07 Resid Ox - Dis Time - D071 (CRS) v2 5/1/07 6/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 F

5/1/07 6/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 5/1/07 6/1/07 5/1/07 6/1/07 Temp Rise - D011 (CRS) v2 Temp Rise - D012 (CRS) v2 D011 D012 12.7 12.7

                                                                                                  -I-  16.1 16.1                 -v 5/1/07        6/1/07 6/1/07    Temp-Discharge - D011 (CRS) v2                D011                            95.4                   ~1 5/1/07                                                                            89.9 5/1/07        6/1/07    Temp-Discharge - D012 (CRS) v2                D012        89.9                95.4 5/1/07        6/1/07    Temp-Intake - D011 (CRS) v2                   D011        77.1                81.7 5/1/07        6/1/07    Temp-Intake - D012 (CRS) v2                   D012        77.1               81.7 5/1/07        6/1/07    Total Recoverable Iron D-600 (CRS) v2         D-600                                                               NODI=9 6/1/07        7/1/07    Flow - D011 (CRS) v2                          D011                                   1665.5 1693.3 6/1/07        7/1/07    Flow - Intake - D071 (CRS) v2                 D071                                   433.86 578.35 6/1/07        7/1/07    Flow - Intake - D072 (CRS) v2                 D072                                   420.83 572.54 6/1/07        7/1/07    Flow D-600 (CRS) v2                           0-600                                           0.02 6/1/07        7/1/07    pH - Background D071 (CR5) v2        I   7-D071                 8.13      8.13 6/1/07        7/1/07    pH - Background D072 (CRS) v2            7-D072                 8.13      8.13 6/1/07        7/1/07   'pH - Effluent - P-D071 (CRS) v2              P-D071                  8.2       8.2 6/1/07        7/1/07    pH - Effluent - P-D072 (CR) v2               P-D72                  8.24      8.24 6/1/07        7/1/07    pH - Ex of Calc Limit - R-D071 (CR5)v2Q      R-071                   1.1      -0.3 6/1/07        7/1/07    pH - Ex of Calc Limit - R-D072 (CRS) v2      R-D072                  1.1     -0.26 6/1/07        7/1/07     H -Calc Limit - Q-D071 (CRS) v2             Q-D071                 7.13       8.5 6/1/07        7/1/07    pH -Calc Limit - Q-D072 (CRS) v2         JQ-D072                    7.13       8.5 10/21/2009                                                                      Page 25

0 Crystal River South DMR Data Permit No. FL00000159 Begin, date En Dat PAAEE AEOtl C-AVg Ij C-Min C-Ma x Q-Avgj ~Q-Max4 ~NDI-Avg NODI-Max ~NODI-Min 6/1/07 7/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0

                                                              -I-                                     0 6/1/07       7/1/07  Resid Ox - Dis Time - D072 (CRS) v2            D072 0

6/1/07 7/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 6/1/07 7/1/07 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 6/1/07 7/1/07 Temp Rise - D011 (CRS) v2 i D011 9.7 13.9 17 6/1/07 7/1/07 Temp Rise - D012 (CRS) v2 D012 9.7 13.9 6/1/07 7/1/07 Temp-Discharge - DOll (CRS) v2 D011 92.5 95.6 I1 6/1/07 7/1/07 Temp-Discharge - D012 (CRS) v2 D012 92.5 95.6 6/1/07 7/1/07 Temp-Intake - D011 (CRS) v2 D01l 82.8 87.4 6/1/07 7/1/07 Temp-Intake - D012 (CRS) v2 D012 82.8 6/1/07 7/1/07 Total Recoverable Iron D-600 (CRS) v2 D-600 850 7/1/07 8/1/07 Flow - D011 (CRS) v2 D011 1674.3 171 .3.7 7/1/07 8/1/07 Flow - Intake - D071 (CRS) v2 D071 581.46 643 .68 7/1/07 8/1/07 Flow - Intake - D072 (CRS) v2 D072 575.91 623 .52

                                                                                                               -   I 7/1/07       8/1/07 [Flow D-600 (CRS) v2                            D-600                                             0.104 7/1/07       8/1/07 IpH - Background 11~

D071 (CRS) Q2 7-D071 pH - Background D072 (CRS) v2 7-D072 8.02 8.02 --I. 7/1/07 8/1/07 8.02 8.02 7/1/07 8/1/07 pH - Effluent - P-D071 (CRS)v2 P-D071 8/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 8.07 8.07 7/1/07 v2 -D07 8.09 8.09 7/1/07 8/1/07 pH - Ex of Calc Limit - R-D071 (CRS) 1.1 -0.43 7/1/07 8/1/07 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 i.1 -0.41 7/1/07 8/1/07 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.02 8.5 -I 7/1/07 8/1/07 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.02 8.5 I 7/1/07 8/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 7/1/07 8/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 7/1/07 8/1/07 Resid Ox - Dis Time P-DOll (CRS) v2 P-DO11 0 7/1/07 8/1/07 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 7/1/07 8/1/07 Temp Rise - D011 (CRS) Q D011 7 8.9 7/1/07 8/1/07 Temp Rise - D012 (CRS) v2 D012 7 8.9 7/1/07 8/1/07 Temp-Discharge - D011 (CRS) v2 D011 94.2 96.6 7/1/07 8/1/07 Temp-Discharge - D012 (CRS) v2 D012 94.2 96.6 7/1/07 8/1/07 Temp-Intake - D011 (CRS) v2 D011 87.2 94.9 ---- F 7/1/07 8/1/07 Temp-Intake - D012 (CRS) v2 D012 87.2 7/1/07 8/1/07 Total Recoverable Iron D-600 (CRS) v2 D-600 800 10/21/2009 Page 26

0 Crystal River South DMR Data 0 Permit No. FL00000159 Bei dae EdDt PARAMETERB~ihd~te,NAME~~ ~Ed~Dae Ou~tall~z~. C-Av.g_. ~. ~C-Min C-Max Q-Mx I OD'Min NI-a 0QAv N6DI-Mi 8/1/07 9/1/07 Flow - DO11 (CRS) v2 D011 1658.8 1713.7 D071 573.53 643.68 8/1/07 9/1/07 Flow - Intake - D071 (CRS) v2 Flow - Intake - D072 (CRS) v2 D072 559.48 623.52 8/1/07 9/1/07 i-D-600 0.01 8/1/07 9/1/07 Flow D-600 (CRS) v2 9/1/07 pH Background 7-DO71 (CRS) v2 7-D071 8.02 8.02 8/1/07 - - 9/1/07 pH - Background D072 (CRS) v2 7-D072 8.02 8.02 8/1/07 9/1/07 pH - Effluent - P-D071 (CRS) v2 P-D071 8.12 8.12 8/1/07 9/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 8.15 8.15 8/1/07 9/1/07 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1.1 -0.38 8/1/07 8/1/07 9/1/07 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 _r 1.1 -0.35 IF F1 8/1/07 9/1/07 1pH -Calc Limit - O-D071 (CR5) v2 Q-D071 7.02 8.5 8/1/07 9/1/07 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.02 8.5 8/1/07 9/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 8/1/07 9/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 8/1/07 9/1/07 Resid Ox - Dis Time P-DOll (CRS) v2 P-DOll 0 8/1/07 9/1/07 Resid Ox - Dis Time P-DO12 (CRS) v2 P-D012 0 8/1/07 9/1/07 Temp Rise - DOll (CRS) v2 D011 6,1 10.2 8/1/07 9/1/07 Temp Rise - D012 (CRS) v2 D012 6.1 10.2 8/1/07 9/1/07 Temp-Discharge - D011 (CRS) v2 D011 93.9 96.3 8/1/07 9/1/07 ITemp-Discharge - D012 (CRS) v2 D012 93.9 96.3 8/1/07 9/1/07 Temp-Intake - D011 (CRS) v2 D011 87.8 90.8 8/1/07 9/1/07 Temp-Intake - D012 (CRS) v2 D012 87.8 90.8 8/1/07 9/1/07 Total Recoverable Iron D-600 (CRS) v2 D:600 880 9/1/07 10/1/07 Flow - D011 (CRS) v2 D011 1696.5 1713.7 9/1/07 10/1/07 Flow - Intake - 0071 (CR5) 2 0071 425.85 550.36 9/1/07 10/1/07 Flow - Intake - D072 (CRS) v2 D072 393.09 593.6 9/1/07 10/1/07 Flow D-600 (CRS) v2 D-600 0.02 9/1/07 10/1/07 pH - Background D071 (CRS) v2 7-D071 8.02 8.02 9/1/07 10/1/07 PH - Background D072 (CRS) v2 7-D072 8.02 8.02 9/1/07 10/1/07 pH - Effluent - P-D071 (CRS) v2 P-D071 8.14 8.14-2 9/1/07 10/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 8.15 8.15 9/1/07 10/1/07 IpH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1.1 -0.36 8. 9/1/07 10/1/07 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 1.1 -0.35 9/1/07 10/1/07 -pH-talcLimit - Q-D071 (CRS) v2 Q-D071 7.02 10/21/2009 Page 27

Crystal River South DMR Data Permit No. FL00000159 EnDaePRMTRNAME Bgndt Oual C-v C-Mm H C-Max Q-Av~g Q-Max; NODI-Avg NODI-Max NOD[-Mlin 9/1/07 10/1/07 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.02 8.5 D)071 9/1/07 10/1/07 Resid Ox - Dis Time - D071 (CRS) v2 i 0 D072 9/1/07 10/1/07 Resid Ox - Dis Time - D072 (CRS) v2 0 9/1/07 10/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-Do11 0 9/1/07 10/1/07 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 9/1/07 10/1/07 Temp Rise - D011 (CRS) v2 D011 9.5 14.1 9/1/07 D012 9.5 14.1 10/1/07 ITemp Rise - D012 (CRS) v2 9/1/07 10/1/07 J Temp-Discharge - D011 (CRS) v2 D011 93.6 96 9/1/07 10/1/07 Temp-Discharge - D012 (CRS) v2 D012 93.6 96 9/1/07 10/1/07 iTemp-lntake - D011 (CRS) v2 D011 84 88.4 9/1/07 10/1/07 Temp-Intake - D012 (CRS) v2 D012 84 88.4 9/1/07 10/1/07 Total Recoverable Iron D-600 (CRS) v2 D-600 2800 10/1/07 11/1/07 jFlow - D01 (CRS) v2 I DOll1 1696.7 1713.7 Flow - Intake - D071 (CRS) v2 F- D071 i 214,4 252.06 10/1/07 11/1/07 10/1/07 11/1/07 Flow - Intake - D072 (CRS) v2 D072 I 199.41 504 10/1/07 11/1/07 Flow D-600 (CRS) v2 D-600_i 0.04 10/1/07 11/1/07 pH - Background D071 (CRS) v2 7-0071 8.02 8.02 10/1/07 11/1/07 pH - Background D072 (CRS) v2 7-Do72 8.02 iF 8.02 10/1/07 11/1/07 pH - Effluent - P-D071 (CRS) v2 T P-D071 -1 8.08 8.08 10/1/07 11/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 8.11 8.11 10/1/07 11/1/07 pH - Ex of Calc Limit - R-D071 (CRS) V2 R-D071 1.1 -0.42 10/1/07 11/1/07 pH - Ex of Calc Limit - R-D072 (CR5) v2 R-D072 1.1 -0.39 10/1/07 11/1/07 pH -Calc Limit - Q-D071 (CR5) Q( Q-D071 7.02 8.5 10/1/07 11/1/07 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.02 8.5 10/1/07 11/1/07 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 10/1/07 11/1/07 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 10/1/07 11/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-Do11 0 10/1/07 11/1/07 IResid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 10/1/07 j 11/1/07 ITemp Rise - D011 (CRS) v2 D011 14.1 16.9 10/1/07 11/1/07 ITemp Rise - D012 (CRS) v2 D012 14.1 16.9 10/1/07 11/1/07 ]Temp-Discharge - D011 (CRS) v2 D011 92.4 95.8 10/1/07 11/1/07 ITemp-Discharge - D012 (CRS) v2 D012 92.4 95.8 10/1/07 11/1/07 Temp-Intake - D011 (CRS) v2 D011 78.4 82.3 10/1/07 w 11/1/07 Temp-Intake - D012 (CRS) v2 D012 78.4 82.3 10/21/2009 Page 28

Crystal River 'South DMR Data Permit No. FL00000159 Begin date -End Date ~ PARAMETERNAME~ Outall C-Avg C-Min~j C-Max j.Q-Avg Q-NMax< NODI-Avg : NODI-Max . NODI-Min i 10/1/07 11/1/07 Total Recoverable Iron D-600 (CRS) v2- D-600 1400 11/1/07 12/1/07 Flow - D011 (CRS) v2 D011 1352.06 1612.99 11/1/07 12/1/07 Flow - Intake - D071 (CRS) v2 D071 141.8 141.8 11/1/07 12/1/07 Flow - Intake - D072 (CRS) v2 D072 181 181 11/1/07 12/1/07 Flow D-600 (CRS) v2 D-600 0.01 11/1/07 12/1/07 pH - Background D072 (CRS) v2 7-D072 8.12 8.12 11/1/07 12/1/07 pH - Effluent - P-D072 (CRS) v2 P-D072 8.13 8.13 11/1/07 12/1/07 IpH - Ex of Calc Limit- R-D072 (CRS) v2 R-D072 1 -0.37 I 11/1/07 12/1/07 pH -Calc Limit - Q-D072 (CRS)v2 Q Q-D072 7.12 8.5 11/1/07 12/1/07 Resid Ox - Dis Time - 0071 (CRS) v2 0071 11/1/07 K 12/1/07 Resid Ox - Dis Time - D072 (CRS) v2 0072 0 11/1/07 12/1/07 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DOll 0 11/1/07 12/1/07 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 11/1/07 7 12/1/07 iTemp Rise - D011 (CRS) v2 i D011 13.3 18.3 11/1/07 12/1/07 iTemp Rise - D012 (CRS)v2 0 D12 13.3 18 .3 11/1/07 12/1/07 !lTemp-Discharge - D011 (CRS) v2 D11 80.3 91.4 11/1/07 12/1/07 Temp-Discharge - D012 (CRS) v2 D012 r 80.3 91.4 11/1/07 12/1/07 Temp-Intake - DOll (CRS) v2 Doll 67 72.9 11/1/07 12/1/07 iTemp-Intake - D012 (CRS) v2 D012 67 72.9 11/1/07 7 -12/1/07 -Total Recoverable Iron D-600 (CRS)v2 D-600 960 12/1/07 1/1/08 Flow - D011 (CRS) v2 D011 1544.8 1613 12/1/07 1/1/08 Flow - Intake - D071 (CRS) v2 D071 155.58 171.75 12/1/07 1/1/08 Flow - Intake - D072 (CRS) v2 D072 248.87 350,09 12/1/07 1 1/1/08 Flow 0-600 (CRS) v2 0-600 NODI=9 12/1/07 1/1/08 ýpH - Background D071 (CRS) v2 7-D071 8.12 8.12 12/1/07 1/1/08 pH - Background D072 (CRS) v2 7-D072 8.12 8.12 12/1/07 1/1/08 pH - Effluent - P-D071 (CRS) v2 P-D071 8.13 8.13 8.13 12/1/07 1/1/08 H~- Effluent - P-D072 (CRS) v2 P-D072 8.13 1 12/1/07 1/1/08 1pH- Ex of Calc Limit- R-D071 (CRS) v2 R-D071 -0.37 1 12/1/07 1/1/08 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 -0.37 12/1/07 1/1/08 pH.-Calc Limit - 0.-D071 (CRS) v2 j Q-D071 7.12 8.5 12/1/07 1/1/08 ýpH -Calc Limit - Q-0072 (CRS) v2 Q-0072 1 7.12 8.5 12/1/07 1/1/08 Resid Ox - Dis Time - 0071 (CRS)v2 Q0071 0 12/1/07 1/1/08 Resid Ox - Dis Time - 0072 (CRS) v2 0072 0 10/21/2009 Page 29

0 Crystal River South DMR Data Permit No. FL00000159 Scoginda~te End Date f PARAMETERZ NAME Oual _____ -AVC C-MCMaiQd Q-Aa NOIAv ND-axý NO Min. 12/1/07 1/1/08 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 12/1/07 1/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 12/1/07 1/1/08 Temp Rise - 0011 (CRS) v2 Do11 13.9 17.1 12/1/07 1/1/08 Temp Rise - D012 (CRS) v2 D012 13.9 17.1 12/1/07 1/1/08 Temp-Discharge - DO11 (CRS) v2 Do11 78.8 87.5 12/1/07 1/1/08 -ITemp-Discharge - D012 (CRS) v2 D012 78.8 1 87.5 12/1/07 1/1/08 Temp-Intake - DO11 (CRS) v2 Do11 65.6 71.6 12/1/07 1/1/08 ITemp-Intake - D012 (CRS) v2 D012 65.6 71.6 12/1/07 1/1/08 iTotal Recoverable Iron D-600 (CRS )v2 D-600 NlODI=9 12/1/07 1/1/08 ITotal Residual Ox 1-DOll (CRS) v2 1-DO11 1001=9 NODI=9 N 12/1/07 1/1/08 ýTotal Residual Ox 1-D012 (CR5) v2 1-D012 001=9 1/1/08 2/1/08 Flow - DO11 (CRS) v2 oD11 1494.4 1514 j 1/1/08 2/1/08 1Flow - Intake - D071 (CRS) v2 D071 0 0 1/1/08 2/1/08 Flow - Intake- D072 (CRS) v2 D072 0 1/1/08 2/1/08 Flow D-600 (CRS) v2 D-600 0.01 1/1/08 2/1/08 pH - Background D071 (CRS) v2 7-D071 VMNR MNR 1/1/08 2/1/08 pH - Effluent - P-D071 (CRS) v2 P-D071 - VMNR MNR 1/1/08 2/1/08 pH - Ex of CaIc Limit - R-D071 (CRS) v2 R-D071 I __ MNR MNR 1/1/08 2/1/08 pH -Calc Limit - Q-D071 (CRS) v2 _ Q-D071 MNR MNR 1/1/08 2/1/08 Resid Ox - Dis Time - D071 (CRS) v2 D071 2/1/08 0 1/1/08 Resid Ox - Dis Time - D072 (CRS) v2 D072 tP-D011 0 1/1/08 2/1/08 lResid Ox - Dis Time P-DO11 (CRS) v2 I 0 1/1/08 2/1/08 [Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 1/1/08 2/1/08 ITemp Rise - D011 (CRS) v2 17.3 19.7 1/1/08 2/1/08 Temp Rise - D012 (CRS) v2 D012 17.3 19.7 1/1/08 2/1/08 Temp-Discharge - Doll (CRS) v2 D011 75.2 82.4 I 1/1/08 2/1/08 Temp-Discharge - D012 (CRS) v2 D012 I 75.2 I 82.4 1/1/08 2/1/08 Temp-Intake - Do11 (CRS) v2 D011 58.2 67.8 1/1/08 2/1/08 Temp-Intake - D012 (CRS) v2 D012 58.2 67.8 1/1/08 2/1/08 Total Recoverable Iron D-600 (CRS) v2 D-600 4000 -2 1/1/08 2/1/08 Total Residual Ox 1-D011 (CR5) v2 1-D011 1/1/08 2/1/08 Total Residual Ox 1-D012 (CRS) v2 1-DO12 MVNR MINR 2/1/08 3/1/08 Flow - D011 (CRS) v2 0011 IJ 502.1 1 1518.2 _ _ 2/1/08 3/1/08 Flow - Intake - D071 (CRS) v2 D071 0 1 0 10/21/2009 Page 30

Crystal River South DMR Data Permit No. FL00000159 .Begindate Date Enri'd I; PARAMETERNAME Outall C-Avig C-MiMm .- . Q-.*g QMax

                                                                                                                    .NODI-Avg         NODI-Max NODI-Min 3/1/08     Flow - Intake - D072 (CRS) v2             I  D072                                      0             0 2/1/08                                                           J-2/1/08       3/1/08     Flow D-600 (CRS) v2                          D-600                                                  0.03 2/1/08       3/1/08     pH - Background D071 (CRS) v2           7-D071                                                             MNR      MNR 3/1/08     pH  - Background D072 (CRS) v2          7-D072                                                             MNR      MNR 21/08        3/1/08     pH - Effluent - P-D071 (CRS) v2             P-D071                                                             VMNR     MNR MNR      MNR 2/1/08       3/1/08     pH - Effluent - P-D072 (CRS) v2             P-D072 2/1/08       3/1/08     p_
                          )H - Ex of Calc Limit - R-D071 (CR5) v2    R-D071                                                             MNR      MNR 2/1/08       3/1/08     pH - Ex of Calc Limit - R-D072 (CRS) v2     R-D072                                                             VMNR     MNR 2/1/08       3/1/08    IpH -Calc Limit - Q-D071 (CRS) v2            Q-D071                                                             MNR      MNR 2/1/08       3/1/08   IpH -Calc Limit - Q-D072_(CRS) v2             Q-D072                                                             MNR      MNR 2/1/08       3/1/08     Resid Ox - Dis Time - D071 (CRS) v2          D071                           0 2/1/08       3/1/08     Resid Ox - Dis Time - D072 (CRS) v2          D072                           0 2/1/08       3/1/08     Resid Ox - Dis Time P-DO11 (CRS) v2         P-Doll                          0 2/1/08       3/1/08     Resid Ox - Dis Time P-D012 (CRS) v2         P-DO12                          0 2/1/08       3/1/08     Temp Rise - D011 (CRS) v2                    D011        16.7             18.2 2/1/08       3/1/08     Temp Rise - D012 (CRS) v2                    D012        16,7             18.2 2/1/08       3/1/08  _ Temp-Discharge - D011 (CRS) v2                D011        80.1              87 2/1/08       3/1/08     Temp-Discharge     - D012 (CRS) v2           D012        80.1              87 2/1/08       3/1/08     Temp-lntake - D011 (CRS) v2                  Doll        63.6             69.3 2/1/08       3/1/08    FTemp-lntake - D012 (CRS) v2                  0012        63.6             69.3 2/1/08       3/1/08    ITotal Recoverable Iron D-600 (CRS) v2        D-600                       7800 2/1/08       3/1/08     Total Residual Ox 1-DO11 (CRS) v2           1-Do11                                                       MNR   MNR 2/1/08       3/1/08    Total Residual Ox 1-D012 (CRS) v2            1-0012                                                       MNR   MNR 3/1/08       4/1/08     Flow - Dol (CRS) v2                          D011                                   1426.6         1613 3/1/08       4/1/08     Flow - Intake - D071 (CRS) v2                D071                                    29.14         51.21 3/1/08       4/1/08     Flow - Intake - D072 (CRS) v2                D072                                    13.56         13.56 3/1/08       4/1/08     Flow D-600 (CRS) v2                          D-600                                                  0.02 3/1/08       4/1/08  -jpH - Background D071 (CRS) v2            7-D071                 8.07  8.07 3/1/08       4/1/08     pH - Background D072 (CRS) v2           7-D072                 8.07  8.07 3/1/08       4/1/08     pH - Effluent - P-D071 (CRS) v2             P-D071                 8.12  8.12 3/1/08       4/1/08     pH  - Effluent - P-D072 (CRS) v2            P-D072                 8.12   8.12 3/1/08       4/1/08     pH  - Ex of Caic Limit - R-D071 (CRS) v2    R-D071                 1.1   -0.38 3/1/08       4/1/08     pH - Ex of Calc Limit - R-D072 (CRS) v2     R-D072                 1.1   -0.38 1

3/1/08 4/1/08 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.07 8.57 10/21/2009 Page 31

0 Crystal River South DMR Data Permit No. FL00000159 Begin date End____ Dae PAA EE NAME < 0utall j C7Avg. - CIMin 3/1/08 4/1/08 pH -Calc Limit - Q-D072 (CRS) v2 CQ-D072 - _ 7.07 1 8.5 I 3/1/08 4/1/08 Resid Ox - Dis Time - D071 (CRS) v2 -1 D00711 L1* 3/1/08 4/1/08 Resid Ox - Dis Time - D072 (CRS) v2 D072_II 0 3/1/08 4/1/08 Resid Ox - Dis Time P-D011 (CRS) v2 P-DO11 - _ 0 F 3/1/08 4/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 3/1/08 4/1/08 jTemp Rise - D011 (CRS) v2 D011 I 10.5 17.7 - 3/1/8 4/1/08 Temp Rise - D012 (CRS) v2 D012 10.5 17.7 i 3/1/08 4/1/08 Temp-Discharge - D011 (CRS) v2 D011 76 87.8 H 3/1/08 4/1/08 Temp-Discharge - D012 (CRS) v2 D012 76 87.8 3/1/08 4/1/08 Temp-Intake - DOll (CRS) v2 Do11 65.6 i 71.4 1 3/1/08 4/1/08 Temp-Intake - D012 (CRS) v2 D012 65.6 71,4 3/1/08 4/1/08 Total Recoverable Iron D-600 (CRS) v2 D-6001 1200 3/1/08 4/1/08 Total Residual Ox 1-D011 (CRS) v2 1-DO11 0 MNR MNR 0 T 3/1/08 4/1/08 Total Residual Ox 1-D012 (CRS) v2 1-D012 MNR MNR 3/1/08 4/1/08 1Total Residual Ox 1-D071 (CRS)v2 1-D071 1 i MNR MNR 3/1/08 4/1/08 Total Residual Ox 1-D072 (CRS) v2 1-D072 0 4/1/08 5/1/08 Flow- D011 (CRS)v2 Q011 1612 4/1/08 5/1/08 Flow - Intake - D071 (CRS)v2 D071 [ 252 4/1/08 5/1/08 Flow -Intake- D072 (CRS)v2 D072 1 _ ! 1 80.24 I 195.75 4/1/08 5/1/08 Flow D-600 (CRS)v2 D-600 0,02 4/1/08 5/1/08 pH - Background D071 (CRS) v2 7-D071 4/1/08 5/1/08 pH - Background D072 (CRS) v2 7-D072 8 I iF-4/1/08 5/1/08 Resid Ox - Dis Time - D071 (CRS)v2 D071 4/1/08 5/1/08 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 4/1/08 5/1/08 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 o0 4/1/08 5/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 17.3 4/1/08 5/1/08 Temp Rise - D011 (CRS) v2 D011 4/1/08 5/1/08 Temp Rise - D012 (CRS) v2 D012 14,6 17.3 4/1/08 5/1/08 Temp-Discharge - D011 (CRS) v2 D011 88.6 93.5 4/1/08 5/1/08 Temp-Discharge - D012 (CRS) v2 D012 88.6 93.5 4/1/08 5/1/08 Temp-Intake - D011 (CRS) v2 D011 73.5 4/1/08 5/1/08 Temp-Intake - D012 (CRS) v2 D012 73.5 4/1/08 5/1/08 [Total Recoverable Iron D-600 (CRS) v2 D-600 4/1/08 5/1/08 Total Residual Ox 1-D011 (CRS) v2 1-D011 MNR 1

                                                                                                                      -   MINR 10/21/2009                                                                 Page 32

0 Crystal River South DMR Data Permit No. FL00000159 d Be--ginda.e> E ;'DaeA .TE. NAME O l vg ** C-m*M -,CMax "

                                                                                                                 <Q-Avg          ..

aQMax NIDI-Avg NODI-Max INODI-Min 4/1/08 5/1/08 Total Residual Ox 1-D012 (CRS) v2 1-D012 IMNR 1MNR 4/1/08 5/1/08 Total Residual Ox 1-D071 (CRS) v2Q1-071 IMNR IMNR 4/1/08 5/1/08 Total Residual Ox 1-D072 (CRS) v2 J 1-D072 MNR MNR 5/1/08 6/1/08 Flow - DO11 (CRS) v2 Do11 1701 1713.7 75.79 5/1/08 6/1/08 Flow - Intake - D071 (CRS) v2 D071 252 5/1/08 6/1/08 Flow - Intake - D072 (CRS) v2 D072 181.81 367.33 9 5/1/08 6/1/08 Flow 0-600 (CRS) v2 j D-600 0 I NODI=- 5/1/08 6/1/08 pH - Background D071 (CR5) v2 7-D071 8.07 8.07 5/1/08 6/1/08 pH - Background D072 (CRS) v2 7-D072 8.07 8.07 5/1/08 6/1/08 pH - Effluent - P-D071 (CRS) v2 P-D071 8.1 8.12 5/1/08 6/1/08 pH - Effluent - P-D072 (CR5) v2 P-D072 8.12 5/1/08 6/1/08 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 -0.4 5/1/08 6/1/08 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 -0.38 I i 5/1/08 6/1/08 pH -Calc Limit - Q-D071 (CRS) v2 Q-TD71 7.07 I 8.5 5/1/08 6/1/08 pH -Calc Limit - Q-D072 (CRS) v2 I Q-D072 1 707 85 5/1/08 6/1/08 Resid Ox - Dis Time - 0071 (CRS) v2 D071 0 5/1/08 6/1/08 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 5/1/08 6/1/08 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 5/1/08 6/1/08 Resid Ox - Dis Time P-D012 (CR5) v2 P-D012 0 5/1/08 6/1/08 Temp Rise - D011 (CRS) v2 D011 13.7 16.1 -I- I .. .. . .. . . 5/1/08 6/1/08 Temp Rise - D012 (CRS) v2 D012 13.7 16.1 5/1/8 6/1/08 Temp-Discharge - Dol (CR5) v2 Doll _92 95.7

                                                                                                 ~17 5/1/08       6/1/08    Temp-Discharge - D012 (CRS) v2               D012           92                     95,7 5/1/08       6/1/08    Temp-Intake - D011 (CRS) v2                  D011         78.4                      83 5/1/08       6/1/08    Temp-Intake - 0012 (CRS) v2                  0012         78.4                      83 5/1/08       6/1/08    Total Recoverable Iron D-600 (CRS) v2        0-600                                                                           NOD1=9 5/1/08       6/1/08    Total Residual Ox 1-D011 (CRS) v2           1-DO11o                                                                MNR        MNR 5/1/08       6/1/08    Total Residual Ox 1-D012 (CRS) v2           1-D012                                                                 MVNR       MVNR 5/1/08       6/1/08    Total Residual Ox 1-D071 (CRS) v2           1-D071     --

INR MNR-5/1/08 6/1/08 Total Residual Ox 1-D072 (CRS) v2 1-D072 MNR MNR 6/1/08 7/1/08 Flow - Do11 (CRS) v2 D011 1692.3 1713.7 6/1/08 7/1/08 Flow - Intake - D071 (CRS) v2 D071 455.63 635.11 - I - 6/1/08 7/1/08 Flow - Intake - 0072 (CRS) v2 D072 504.03 623.52 6/1/08 7/1/08 Flow D-600 (CRS) v2 D-600 0.02 10/21/2009 Page 33

Crystal River South DMR Data Permit No. FL00000159 Bei ae End Date ~ P~A ARIAMETER NAME 7ual kA i 6/1/08 7/1/08 pH - Background D071 (CRS) v2 7-D071 8.24 6/1/08 7/1/08 pH - Background D072 (CRS) v2 7-D072 8.24 6/1/08 7/1/08 pH - Effluent - P-0071 (CR5) v2 P-D071 8.14 8.14

                                                                                                                               - 6/1/08          7/1/08     pH - Effluent - P-D072 (CRS) v2             P-D072                 8.14    8.14 6/1/08          7/1/08     pH - Ex of Calc Limit - R-D071 (CRS) v2     R-D071                  0.9   -0.36 6/1/08        6/1/08 ~~

7/ / 8 7/1/08 -1pH ~ ~ ~ pRC i i Limit

                              - Ex of Calc     ~
                                              - 0      ~

1 ( R ) (CRS)

                                                - R-D072   v     v v2    -0071 R-D072                  0.9   -0.36 6/1/08          7/1/08   j         OpH
                              -Calc  Limit- Q-D071 (CRS) v2           Q-D071                 7.24     8.5 6/1/08          7/1/08      RH-Calc Limit - Q-D072 (CRS) v2               0-D072              7.24     8.5 6/1/08          7/1/08     Resid Ox - Dis Time - DO71 (CRS) v2          D071                             0 6/1/08          7/1/08     Resid Ox - Dis Time - D072 (CRS) v2          D072 6/1/08          7/1/08     Resid Ox - Dis Time P-D011 (CRS) Q          P-Do11 0

6/1/08 7/1/08 Resid Ox - Dis Time P-Dv12 (CRS) 2 P-D012 0 6/1/08 7/1/08 Temp Rise - D011 (CRS) v2 D011 8.2 _ 11 - 6/1/08 7/1/08 Temp Rise - Dc12 (CRS) v2 D012 8.2 - 6/1/08 7/1/08 Temp-Discharge - D011 (CRS)v2 Do11 90.3 95.8 6/1/08 7/1/08 Temp-Discharge - D012 (CRS) v2 D012 95.8 6/1/08 7/1/08 Temp-lntake - D011 (CRS) v2 D011 88 L 6/1/08 7/1/08 jTemp-Intake - D012 (CRS) v2 D012 88 6/1/08 7/1/08 Total Recoverable Iron D-600 (CRS) v2 D-600 1300 i -- v 6/1/08 f 7/1/08 {Total Residual Ox 1-D011 (CRS) v2 1-Do11 2 MVNR MVNR 6/1/08 7/1/08 {Total Residual Ox 1-D012 (CRS) v2 1-D012 MVNR IVN 6/1/08 7/1/08 Total Residual Ox 1-D071 (CRS) v2 1-D071 MNR IVMNR 6/1/08 7/1/08 Total Residual Ox 1-D072 (CRS) v2 1-D072 MNR MNR 7/1 /08 8/1/08 Flow - D011 (CRS) v2 D011 1419.3 1612 7/1/08 8/1/08 Flow - Intake - D071 (CRS) v2 D071 530.17 643.6 8 7/1/08 8/1/08 Flow - Intake - D072 (CRS) v2 D072 518.77 623.5 7/1/08 8/1/08 Flow D-600 (CRS) v2 D-600 0.03 7/1/08 8--/1/08 pH - Background D071 (CRS) v2 7-D071 8.3 7/1/08 8/1/08 pH - Background D072 (CRS) v2 7-D072 8.3 7/1/08 8/11108 pH - Effluent - P-D071 (CRS) v2 P-D071 8.2 7/1/08 8/1/08 pH - Effluent - P-D072 (CRS) v2 P-D072 8.2 I 7/1/08 8/1/08 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 -0.36 7/1/08 8/1/08 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 0.36 7/1/08 8/1/08 pH -CaIc Limit - Q-D071 (CRS) v2 Q-D071 8.5 10/21/2009 Page 34

Crystal River South DMR Data Permit No. FL00000159 Begin date ~EndDate PARAMETER NAME Outall CAvg C-Mm C-Max IQ-ANg Q-Max -A NODIMax NODI-Min 7/1/08 8/1/08 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.28 8.5 7/1/08 8/1/08 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 7/1/08 8/1/08 Resid Ox - Dis Time - D072 (CRS) v2 D072 - 7 0 7/1/08 8/1/08 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 7/1/08 8/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 l 9 o~ 7/1/08 8/1/08 Temp Rise - DO11 (CRS) v2 Do11 7.4 9.5 7/1/08 8/1/08 Temp Rise - D012 (CRS) v2 D012 7.4 9.5 7/1/08 8/1/08 Temp-Discharge - DO11 (CRS) v2 DO11 93.7 96.3 7/1/08 8/1/08 Temp-Discharge - D012 (CRS) v2 D012 96.3 7/1/08 8/1/08 Temp-Intake - DO11 (CRS) v2 D0ll 86.4 89.7 86.4 7/1/08 8/1/08 Temp-Intake - D012 (CR5) v2 D012 89.7 7/1/08 8/1/08 ITotal Recoverable Iron D-600 (CRS) v2 D-600 620 7/1/08 8/1/08 jTotal Residual Ox 1-Do11 (CRS) v2 1-Do11 MNR MNR 7/1/08 I 8/1/08 Total Residual Ox 1-D012 (CRS) v2 1-0012 MNR MNR 7/1/08 8/1/08 Total Residual Ox 1-D071 (CRS) v2 1-D071 MNR MNR 7/1/08 8/1/08 Total Residual Ox 1-D072 (CRS) v2 1-1072 MNR MNR 8/1/08 9/1/08 Arsenic - D-OOH (CRS) v2 DOH NODI=9 8/1/08 9/1/08 Cadmiuc - D-OOH (CRS)v2 DOH NODI=9 8/1/08 9/1/08 Chromium - D-OOH (CRS) v2 DOH IF NODI=9 8/1/08 9/1/08 Copper - D-OOH (CRS) v2 DOH NO 01=9 8/1/08 9/1/08 Flow - D011 (CRS) v2 Q Do11 1681.38 1713.69 8/1/08 9/1/08 Flow - Intake - D071 (CRS) v2 _ D071 349.43 582 8/1/08 9/1/08 Flow - Intake - D072 (CRS) v2 D072 380.63 565.47 4-8/1/08 9/1/08 Flow D-600 (CRS) v2 D-600 0.31 8/1/08 9/1/08 Iron__ - D-OOH (CR5) v2 D-OOH NODI=9 8/1/08 9/1/08 Lead - D-OOH (CRS) v2 D-OOH D-OOH NODI=9 8/1/08 9/1/08 Mercury - D-OOH (CRS) v2 - 8/1/08 9/1/08 Nickel - D-OOH (CRS) v2 D-OOH NODI=9 8/1/08 9/1/08 ipH- Background 071 (CR5) v2 7-0071 NCDI=9 8/1/08 9/1/08 pH - Background D072 (CRS) v2 1 7-D072 8.3 8.3 83 8.3 8/1/08 9/1/08 pH - Effluent - P-D071 (CRS) v2 P-D071 8.2 8.2 8/1/08 9/1/08 pH - Effluent - P-D072 (CRS) v2 P-D072 8.2 8.2 8/1/08 9/1/08 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 0.9 0.3 9/1/08 pH - Ex of Calc Limit- R-D072 (CRS) v2j R-D072 0.3 8/1/08 0.9 10/21/2009 Page 35

0 Crystal River South DMR Data Permit No. FL00000159

                   .~                        R~AM~~y~ouall Date'~~                            c, n           C-i
                                                                                       -%-g      -a     ~    QAvg Q;ig2  Q-Max    N!ODi-Avg    NODI-a      NODI-Min 8/1/08       9/1/08    pH -Calc Limit - Q-D071 (CRS) v2         Q-D071                      7.28   8.5 8/1/08      9/1/08     pH -Calc Limit - Q-D072 (CRS) v2         Q-D072            -         7.28   8.5 8/1/08       9/1/08    Resid Ox - Dis Time - D071 (CRS) v2       D071                               0 8/1/08       9/1/08    Resid Ox - Dis Time - D072 (CRS) v2       D072 9/1/08    Resid Ox - Dis Time P-DOll (CRS) v2    FP-D011 o

01 __ 8/1/08 0 - 8/1/08 9/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 8/1/08 9/1/08 Selenium - D-00H (CRS) v2 2 D-00H INODI=9 8/1/08 9/1/08 Temp Rise - DOll (CRS) v2 D011 8.3 12.4 8/1/08 9/1/08 Temp Rise - D012 (CRS) v2 1 0012 8.3 12.4 8/1/08 9/1/08 Temp-Discharge - D011 (CRS) v2 D011 92.1 94.9 8/1/08 9/1/08 Temp-Discharge - D012 (CRS) v2 D012 92 95.8 8/1/08 9/1/08 Temp-Intake - D011 (CRS) v2 D011 82.9 88 _ 8/1/08 9/1/08 Temp-Intake - D012 (CRS) v2 D012 82.9 88 8/1/08 9/1/08 Total Recoverable Iron D-600 (CRS) v2 D-600 1800 8/1/08 9/1/08 Total Residual Ox 1-D011 (CRS) V2 1-DOll MVNR IVNR 8/1/08 9/1/08 Total Residual Ox 1-D012 (CRS) v2 1-DO12 I MNR I MNR 8/1/08 9/1/08 Total Residual Ox 1-D072 (CRS) v2 1-D072 INR I MNR 8/1/08 9/1/08 TSS - D-OOH (CRS) v2 D-OOH D-00 H

                                                                                   --I                                                      N001=9 8/1/08       9/1/08    Vanadium - D-OOH (CRS) v2                                                                                             NODI=9  -

8/1/08 9/1/08 Zinc - D-OOH (CRS) v2 D-001H NODI=9 9/1/08 10/1/08 Arsenic - D-OOH (CRS) v2 DOH 9/1/08 10/1/08 Arsenic - DOC1 (CRS) v2 DOC1 82 9/1/08 10/1/08 Cadmium - D-OOH (CRS) v2 DOH 9/1/08 10/1/08 Cadmium - DOCI (CRS) v2 DOC1 1 9/1/08 10/1/08 Chromium - D-00H (CRS) v2 DOH 9/1/08 10/1/08 Chromium - DOC1 (CRS) v2 DOC1 IDOHI <4 9/1/08 10/1/08 Copper - D-OOH (CRS) v2 9/1/08 10/1/08 Copper - DOC1 (CRS) v2 DOC1 2.2 9/1/08 10/1/08 Flow - D011 (CRS) v2 0011 1712.7 1476.2 9/1/08 10/1/08 Flow - D0C1 (CRS) v2 DOCI 0.9 0.9 9/1/08 101/08 Flow - Intake - D071 (CRS) v2 D071 442.22 549M09 9/1/08 10/1/08 Flow - In take - D072 (CRS) v2 D072 275.65 505.41 9/1/08 9/1/08 10/1/08 10/1/08 Flow D-600 (CRS) v2 Iron - D-OOH (CRS) v2 D-600 ___- __ 0.19 D-OOH 10/21/2009 Page 36

0 Crystal River South DMR Data Permit No. FL00000159 outall C-Avg C-Min, V9

Begin date EndDate PARAMETERNAME 9/1/08 10/1/08 Iron - DOC1 (CRS) v2 DOC1 9/1/08 10/1/08 Lead - D-OOH (CRS) v2 DOH DOC1 <1 9/1/08 10/1/08 Lead - DOC1 (CRS) v2 9/1/08 10/1/08 1Mercury - D-OOH (CRS) v2 D-00H 9/1/08 10/1/08 Mercury - DOC1 (CRS) v2 DOC1 <0.1I 9/1/08 10/1/08 Nickel - D-OOH (CRS) v2

                                                                        -{D-00H 9/1/08          10/1/08   Nickel - DOC1 (CRS) v2                          DOC1                                    <1.0 9/1/08          10/1/08   Oil and Grease - DOCI (CRS) v2                  DOCI 9/1/08          10/1/08   pH - Background D071 (CRS) v2             7-D071 9/1/08          10/1/08   pH - Background D072 (CRS) v2         I    7-D072 9/1/08          10/1/08   pH - Background - DOC1 (CRS) v2         T       DOC1 9/1/08          10/1/08   pH - Calc Limit - DOC1 (CRS) v2                 DOC1
             -P 9/1/08          10/1/08   pH - Difference - DOC1 (CRS) v2                 DOC1                           -      I 9/1/08           10/1/08  pH - Effluent - DOC1 (CRS) v2                   DOCI 9/1/08          10/1/08   pH - Effluent - P-D071 (CRS) v2                P-D071 9/1/08        l10/1/08    pH - Effluent - P-D072 (CRS) v2                P-D072 9/1/08           10/1/08  pH - Ex of Calc Limit - R-D072 (CRS) v2        R-D072 9/1/08           10/1/08  pH -Calc Limit - Q-D072 (CRS) v2              Q-D072 9/1/08           10/1/08  Resid Ox - Dis Time - D071 (CRS) v2             D071 9/1/08           10/1/08  Resid Ox - Dis Time - D072 (CRS) v2             D072 9/1/08           10/1/08  Resid Ox - Dis Time P-DOll (CRS) v2            P-DOll                                J 9/1/08          10/1/08   Resid Ox - Dis Time P-D012 (CRS) v2            P-D012 9/1/08          10/1/08   Selenium - D-00H (CRS) v2                      D-00H 9/1/08          10/1/08  ISelenium - DOCI (CRS) v2                        DOC1 9/1/08          10/1/08   Temp Rise - D011 (CRS) v2                       D011 9/1/08          10/1/08   Temp Rise - D012 (CRS) v2                       D012 9/1/08          10/1/08   Temp-Discharge - D011 (CRS) v2                  D011 9/1/08          10/1/08   Temp-Discharge - 0012 (CRS) v2                  D012 9/1/08          10/1/08   Temp-Intake - D011 (CRS) v2                     D011 9/1/08          10/1/08   Temp-Intake - D012 (CRS) v2                     D012 9/1/08          10/1/08   Total Recoverable Iron D-600 (CRS) v2           D-600 9/1/08          10/1/08   Total Residual Ox 1-D011 (CRS) v2Q             1-Doll                            MNR    MNR 9/1/08          10/1/08   Total Residual Ox 1-D012 (CRS) v2              1-D012                            MNR    MNR 9/1/08          10/1/08  tTotal Residual Ox 1-0071 (CRS) v2              1-D071                            MNR  i MNR 10/21/2009                                                                           Page 37

0 Crystal River South DMR Data Permit No. FL00000159 Beiae EdDate ~ PARAMETERNAME Outall C-Avg C-i ----- 06 0_____ Win'_______ 1-D072 MNR MNR 9/1/08 10/1/08 Total Residual Ox 1-D072 (CRS) v2 9/1/08 10/1/08 TSS - D-OOH (CRS) v2 D-OOH 9/1/08 10/1/08 TSS - DOC1 (CRS) v2 DOC1 21 21 9/1/08 10/1/08 IVanadium - D-OOH (CRS) v2 D-OOH 9/1/08 10/1/08 Zinc - D-OOH (CRS) v2 D-OOH 9/1/08 10/1/08 Zinc - DOCI (CRS) '2 DOC1 5.9 10/1/08 11/1/08 Flow - D011 (CRS) v2 DOll

                                                                 -DO                                        1610.2       1352 10/1/08      11/1/08  Flow - DOC1 (CRS) v2                        DOC1                                          0      _       0 10/1/08      11/1/08  Flow - Intake - D071 (CRS) v2               D071                                        0.96         0.96 10/1/08      11/1/08  Flow - Intake - D072 (CRS) v2               D072                                         0              0 11/1/08  Flow D-600 (CRS) v2                        D-600                                                                        SEF 10/1/08 10/1/08      11/1/08  pH - Background D071 (CRS) v2       { 7-D071                  8.45     8.45 10/1/08      11/1/08  pH - Background D072 (CRS) v2       T 7-D072                  8.45     8.45 10/1/08      11/1/08  pH - Background - DOC1 (CRS) v2             DOCI                     0        0 pH - Calc Limit - DOC1 (CRS) v2                                      0        0                                     -T 00 10/1/08      11/1/08                                              DOCI 10/1/08      11/1/08  pH - Difference - DOC1 (CRS) v2             DOC1                     0 10/1/08      11/1/08  pH - Effluent - DOCI (CRS) v2               DOC1                     0 o    I  _
                                                                                                                   ~1           ________

pH - Effluent - P-D071 (CRS) v2 P-D071 8.14 8.14 10/1/08 11/1/08 10/1/08 11/1/08 pH - Effluent - P-D072 (CRS) v2 P-D072 8.12 8.12 10/1/08 11/1/08 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 0.7 -0.36 0.7 -0.38 I1 10/1/08 11/1/08 PH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 Q-D071 7.45 10/1/08 11/1/08 IpH -Calc Limit - Q-D071 (CRS) v2 8.5 10/1/08 11/1/08 IpH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.45 8.5 10/1/08 11/1/08 Resid Ox - Dis Time - D071 (CRS) v2 D071 -- 0 7 10/1/08 11/1/08 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 L 10/1/08 11/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 DOll 10/1/08 11/1/08 Temp Rise - D011 (CR5) v2 14.1 16.6 D011 10/1/08 11/1/08 Temp Rise - D012 (CRS) v2 0012 14.1 16.6 10/1/08 11/1/08 Temp-Discharge - D011 (CRS) v2 88.7 93.7 10/1/08 11/1/08 Temp-Discharge - D012 (CRS) v2 D012 88.7 93.7 10/1/08 11/1/08 Temp-Intake - D011 (CRS) v2 D011-- j 74.7 81.9 10/1/08 11/1/08 Temp-Intake - D012 (CRS) v2 D012 74.7 81.9 D-600 10/1/08 11/1/08 Total Recoverable Iron D-600 (CRS) v2 SEF MNR . MNR 10/1/08 11/1/08 Total Residual Ox 1-D011 (CRS) v2 1-Do11 10/21/2009 Page 38

0 Crystal River South DMR Data Permit No. FL00000159 Begin date ~End Date ~PARAMETER NAMES OUtall 7C-Aye :I ~C-Min 10/1/08 11/1/08 Total Residual Ox 1-D012 (CRS) v2 1-DO12 iI MNR MNR . 10/1/08 11/1/08 Total Residual Ox 1-D071 (CRS) v2 1-D071 MNR MNR 10/1/08 11/1/08 Total Residual Ox 1-D072 (CRS) v2 1-D072 I MNR i MNR 11/1/08 12/1/08 Flow - D011 (CRS) v2 D011 1579.07 1612.99 . 11/1/08 12/1/08 Flow - DOC1 (CRS) v2 DOC1 0 0 _ _ 11/1/08 12/1/08 Flow - Intake - D071 (CRS) v2 D071 11/1/08 12/1/08 Flow - Inta ke - 0072 (CR5) v2 D072 0 0 __ _____ ___ _ 11/1/08 12/1/08 Flow 0-600 (CR5) v2 D-600 - __ 0.70 ! 11/1/08 12/1/08 pH - Background D071 (CRS) v2 7-D071 II MNR MNR 11/1/08 12/1/08 pH - Background D072 (CRS) v2 7-D072 _ _ 1 MNR IMVNR 11/1/08 12/1/08 pH - Background - DOC1 (CRS) v2 DOC1 0 11/1/08 12/1/08 pH - Calc Limit - DOC1 (CRS) v2 DOC1 0 0 11/1/08 12/1/08 pH - Difference - DOC1 (CRS) v2 DOC1 0 0 I _ _ 11/1/08 12/1/08 pH - Effluent - DOC1 (CRS) v2 DOC1 0 0 11/1/08 12/1/08 pH - Effluent - P-D071 (CRS) v2 P-D071 MVNR MVNR_ 11/1/08 12/1/08 pH - Effluent - P-D072 (CRS) v2 P-D072 MIVNR iMNR 11/1/08 12/1/08 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 I MNR MNR 11/1/08 12/1/08 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 MNR IMNR 11/1/08 12/1/08 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 MNR MNR 11/1/08 12/1/08 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 MNR I- NR 11/1/08 12/1/08 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 11/1/08 12/1/08 Resid Ox - Dis Time P-DO11 (CRS) v2 P-Do11 0 11/1/08 12/1/08 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 11/1/08 12/1/08 Temp Rise - D011 (CRS) v2 D011 14.6 17.3 11/1/08 12/1/08 Temp Rise - D012 (CRS) v2 D012 14.6 17.3 11/1/08 12/1/08 Temp-Discharge - D011 (CRS) v2 D011 88.7 92 11/1/08 12/1/08 ITemp-Discharge - D012 (CRS) v2 D012 88.7 92 !IVN IVN 11/1/08 12/1/08 ITemp-Intake - DO11 (CRS) v2 D011 73.5 79.3 11/1/08 12/1/08 Temp-Intake - D012 (CRS) v2 D012 73.5 79.3 11/1/08 12/1/08 iTotal Recoverable Iron D-600 (CRS) v2 I D-600 MNR__ 4.6 __ 11/1/08 12/1/08 Total Residual Ox 1-D011 (CRS) v2 1-D011 iI 11/1/08 12/1/08 -Total Residual Ox 1-D012 (CRS) v2 1-D012 -- MNR I MNR 11/1/08 12/1/08 1-D071

                                                                                                               - I1 ITotal Residual Ox 1-D071 (CRS) v2       -

MNR MNR 11/1/08 12/1/08 ITotal Residual Ox 1-D072 (CRS) v2 I-D072 10/21/2009 Page 39

0 Crystal River South DMR Data Permit No. FL00000159 Begin ,datejj End Date, PA. WRAMETER NAME~ ~Outall C-Av.g, j C-Mirn C. _____ QzAvg> Q-Max NODI-Avg~ NODI-Max~ NODI-Min 12/1/08 1/1/09 Flow - D-OOH (CRS) v2 DOH 0 12/1/08 1/1/09 Flow - D011 (CRS) v2 DE)ll 1597.4 1613 1/1/09 Flow - DOC1 (CRS) v2 DOC1 0 0 12/1/08 1/1/09 Flow - DOC2 (CRS) v2 DOC2 0 0 12/1/08 1/1/09 Flow - Intake - D071 (CRS) v2 D071 0 0 12/1/08 1/1/09 Flow - Intake - D072 (CRS) v2 D072 0 0 12/1/08 0.02 12/1/08 1/1/09 Flow D-600 (CRS) v2 D-600 12/1/08 1/1/09 pH - Background D071 (CRS) v2 7-D071 MNR MNR 1/1/09 pH - Background D072 (CRS) v2 7-D072 MNR MNR 12/1/08 12/1/08 1/1/09 pH - Background - DOC1 (CRS) v2 DOC1 0 0 J 12/1/08 1/1/09 pH - Calc Limit - DOC1 (CRS) v2 DOC1 0 0 12/1/08 1/1/09 pH - Difference - DOC1 (CRS) v2 DOC1 0 0 12/1/08 1/1/09 pH - Effluent - DOCl (CRS) v2 DOC1 0 0 12/1/08 1/1/09 pH - Effluent - P-D071 (CRS) v2 P-D071 MNR 7 MNR 12/1/08 1/1/09 pH - Effluent - P-D072 (CRS) v2 P-D072 MNR MNR 12/1/08 1/1/09 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 MNR MNR 12/1/08 1/1/09 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 MNR MNR 12/1/08 1/1/09 IH -Calc Limit - Q-D071 (CRS) v2 Q-D071 MNR MNR 12/1/08 1/1/09 pH -Calc Limit - O.-D072 (CRS) v2 Q-D072 MNR MNR 1/1/09 Resid Ox - Dis Time - D071 (CR5) v2 12/1/08 D071 0 12/1/08 1/1/09 Resid Ox - Dis Time - D072 (CRS) v2 D072 MNR 12/1/08 1/1/09 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 12/1/08 1/1/09 Resid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 12/1/08 1/1/09 Temp Rise - Do11 (CRS) v2 D011 16.3 18 12/1/08 1/1/09 [Temp Rise - D012 (CRS) v2 D012 16.3 18 12/1/08 1/1/09 Temp-Discharge - D011 (CRS) v2 D011 78.2 85.1 12/1/08 1/1/09 Temp-Discharge - D012 (CRS) v2 D012 78.2 85.1 12/1/08 1/1/09 Temp-Intake - D011 (CRS) v2 D011 61.8 66.6 12/1/08 1/1/09 Temp-Intake - D012 (CRS) v2 D012 61.8 66.6 12/1/08 1/1/09 Total Recoverable Iron D-600 (CRS) v2 D-600 4900 12/1/08 1/1/09 Total Residual Ox 1-D011 (CRS) v2 1-DO11 7MNR _ MNR 12/1/08 1/1/09 Total Residual Ox 1-D012 (CRS) v2 1-D012 MNR MNR 12/1/08 1/1/09 Total Residual Ox 1-D071 (CRS) v2 1-D071 MNR MNR 12/1/08 1/1/09 Total Residual Ox 1-D072 (CRS) v2 1-D072 MNR MNR 10/21/2009 Page 40

Crystal River South DMR Data Permit No. FL00000159 Begin~~~~~ ~ ~ ~ de, -Mm;

                                                                                                '      CMx'  1 -QAg      -         -ax   NOD-Avg   NqODI-Max     ND-i 1/1/09        2/1/09        Flow - D-OOH (CRS) v2
                                                                   -1 DOH                                                       0 D011                                   1544.7        1612.99 1/1/09        2/1/09        Flow - D011 (CRS) v2 1/1/09        2/1/09        Flow - DOC1 (CRS) v2                          DOC1                                     0         / 0o 1/1/09        2/1/09        Flow - DOC2 (CRS) v2                          DOC2                                     0                 0 0071                                     0 1/1/09        2/1/09        Flow - Intake - D071 (CRS) v2 1/1/09        2/1/09        Flow - Intake - D072 (CRS) v2                 D072                                     0                 0 1/1/09        2/1/09        Flow D-600 (CRS) v2                           D-600                                                    0.02 1/1/09        2/1/09        pH - Background D071 (CRS) v2            7-D071                                                                       MNR            MNR i

1/1/09 2/1/09 pH - Background D072 (CRS) v2 7-D072 MNR MNR 1/1/09 pH - Background - DOC1 (CRS) v2 0 2/1/09 DOC1 0 --i-. 1/1/09 2/1/09 pH - Calc Limit - DOC1 (CRS) v2 DOCI 0 1/1/09 2/1/09 pH - Difference - DOC1 (CRS) v2 DOCI 0 DOC1 0 1/1/09 2/1/09 pH - Effluent - DOC1 (CRS) v2 0 1/1/09 2/1/09 pH - Effluent - P-D071 (CRS) v2 P-D071 MNR IVMNI' 1/1/09 2/1/09 pH - Effluent - P-D072 (CRS) v2 P-D072 MNR MNR 1/1/09 2/1/09 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 MNR MNR 2/1/09 pH - Ex of Caic Limit - R-D072 (CR5) v2 R-D072 MNR MNR 1/1/09 1/1/09 2/1/09 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 MNR MNR 1/1/09 2/1/09 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 MNR MNR 1/1/09 2/1/09 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 1/1/09 2/1/09 Resid Ox - Dis Time - D072 (CRS) v2 D072 MNR I 11/09 2/1/09 lResid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 1/1/09 2/1/09 IResid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 1/1/09 2/1/09 Temp Rise - D011 (CRS) v2 D011 14.8 17.8 I I 1/1/09 2/1/09 Temp Rise - D012 (CRS)v2 D012 17.8 1/1/09 2/1/09 Temp-Discharge - D011 (CRS) v2 D011 84.8 2/1/09 Temp-Discharge - D012 (CRS) 2 D012 1/1/09 73.9 84.8

                                                                                                                       -I____

1/1/09 2/1/09 Temp-Intake - D011 (CRS) v2 D011 68.3

                                                                                                                                                 !F 1/1/09        2/1/09        Temp-Intake - D012 (CRS) v2                   D012        59.2               68.3 1/1/09        2/1/09        Total Recoverable Iron D-600 (CRS) v2         D-600                         2800  "

1/1/09 2/1/09 Total Residual Ox 1-D011 (CRS) v2 1-D011 F- MNR MNR 1/1/09 - 2/1/09 Total Residual Ox 1-D012 (CRS) v2 1-D012

MNR MNR 1/1/09 2/1/09 ITotal Residual Ox 1-D071 (CRS) v2 1-D071 I MNR I NR I

1/1/09 2/1/09 Total Residual Ox 1-D072 (CRS) v2 1-D072 I , ! MNR MNR 10/21/2009 Page 41

Crystal River South DMR Data Permit No. FL00000159 Bgndt EnDae PAAAEE,,EOtll CAg CMn CMx Q-Avg QMx NODI-Avg ' NOOI-Max ND-i 2/1/0 9 3/1/09 Flow - D-OOH (CRS) v2 DOH 0 2/1/0 9 3/1/09 Flow - D011 (CRS) v2 D011 1504.5 1612.1 2/1/0 9 3/1/09 Flow - Intake- 0071 (CR5) v2 D071 0 0 2/1/0 9 3/1/09 Flow - Intake - D072 (CRS) v2 D072 10.94 10.94 2/1/0 9 3/1/09 Flow D-600 (CRS) v2 D-600 0.07 2/1/0 9 3/1/09 pH - Background D071 (CRS) v2 7-D071 MNR MNR 2/1/0 9 3/1/09 pH -Background D072 (CRS) v2 7-D072 8.29 8,29 2/1/0 3/1/09 pH - Effluent - P-D071 (CRS) v2 P-D071 MNR MNR 2/1/0 9 3/1/09 pH - Effluent - P-D072 (CRS) v2 P-D072 8.13 8.13 2/1/0 9 -- 3/1/09 ]pH- Ex of Calc Limit - R-D071 (CRS) v2 R-D071 MNR MNR 2/1/0 9 3/1/09 pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 -0.37 0.8 2/1/0 9 [ 3/1/09 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 MNR MNR 2/1/0 9 3/1/09 j pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 I- 8.5 7.29 2/1/0 9 3/1/09 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 2/1/0 9 3/1/09 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 4-2/1/0 9 3/1/09 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 2/1/0 9 3/1/09 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 0 2/1/0 9 3/1/09 Temp Rise - D011 (CRS) v2 D011 13.6 17.4 2/1/0 9 3/1/09 Temp Rise - D012 (CRS) v2 D012 13.6 17.4 2/1/0 9 3/1/09 Temp-Discharge - D011 (CRS) v2 D011 72.2 80.4 2/1/0:9 3/1/09 ýTemp-Discharge - D012 (CRS) v2 D012 72.2 80.4 2/1/0:9 3/1/09 'Temp-Intake - DO11 (CRS) v2 D011

                                                                              ~1   58.7              64 2/1/0:9          3/1/09   Temp-Intake - D012 (CRS) v2                   D012        58.7              64 2/1/0 9          3/1/09   Total Recoverable Iron D-600 (CRS) v2         D-600                        640 2/1/0 9 2/1/0 9 3/1/09 3/1/09 Total Residual Ox 1-DO11 (CRS) v2 Total Residual Ox 1-D012 (CRS) v2

_Total(CRS) v2 Residual Ox 1-D071 1-Do11 1-D012 i1-D071 ii MNR MNR MNR MNR 9 3/1/09 2/1/0!9 3/1/09 Total Residual Ox 1-D072 (CRS) v2 1-D071 MNR MNR 2/1/0! 0 0 3/1/019 4/1/09 Flow - D-OOH (CRS) v2 DOH 0 3/1/019 4/1/09 Flow - D0ll (CRS) v2 D011 1571.46 1602.05 3/1/0!9 4/1/09 Flow - Intake - D071 (CRS) v2 D071 36.7 62.38 3/1/099 4/1/09 Flow - Intake - D072 (CRS) v2 D072 39.46 65,11 3/1/09 4/1/09 [Flow D-600 (CRS) v2 T D-600 0 3/1/09 4/1/09 pH - Background D071 (CRS) v2 7-D071 8.29 8.29 10/21/2009 Page 42

Crystal River South DMR Data Permit No. FL00000159 Endiitedat Begin PAAMTENIVEAv- ,bta C ndi

                                                                                                ;ý~"1                           Q-Ma    I NOIAv-gý.          Max,   oi7   n 3/1/09            411109     pH - Background 0072 (CRS) v2            7-D072               !                                                      8.29      i  8.29 3/1/09            4/1/09     pH - Effluent - P-D071 (CRS) v2              P-D071                    8.11       8.111 3/1/09            4/1/09     pH - Effluent - P-D072 (CRS) v2              P-D072                                                                      8.13         8.13 3/1/09            4/1/09     pH - Ex of Calc Limit - R-D071 (CRS) v2      R-D071                     0.8       -0.39 3/1/09            4/1/09     pH - Ex of Calc Limit - R-D072 (CRS) v2      R-D072                                                                ....! -0.37        0.8 3/1/09            4/1/09     pH -Calc Limit - Q-D071 (CRS) v2          IQ-D071                           .29     8.5 3/1/09            4/1/09     pH -Calc Limit - Q-D072 (CRS) v2             Q-D072                                                                       8.5         7.29 0

3/1/09 4/1/09 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 3/1/09 4/1/09 Resid Ox - Dis Time - D072 (CRS) v2 D072 3/1/09 4/1/09 Resid Ox - Dis Time P-DO11 (CRS) v2 P-DO11 0 3/1/09 4/1/09 Resid Ox - Dis Time P-D012 (CRS) v2 P-D012 I D011 T 1 0 F-3/1/09 4/1/09 iTemp Rise - DOll (CRS) v2 14.8 i 16.5 14.8 16.5 3/1/09 4/1/09 Temp Rise - D012 (CRS) v2 D012 I-T 3/1/09 4/1/09 Temp-Discharge - D011 (CRS) v2 D011 81.5 -7 91 3/1/09 4/1/09 Temp-Discharge - D012 (CRS) v2 D012 81.5 91 3/1/09 4/1/09 Temp-Intake - D011 (CRS) v2 D011 66.8 F -74.1 l 74.1 3/1/09 1 4/1/09 Temp-Intake - D012 (CRS) v2 D012 66.8 3/1/09 4/1/09 Total Recoverable Iron D-600 (CRS) v2 D-600 MNR 3/1/09 4/1/09 ITotal Residual Ox 1-Do11 (CRS) v2 1-D011 MNR MNR 3/1/09 1-D012 MNR MNR 4/1/09 Total Residual Ox 1-DO12 (CRS) v2 t1-D071 3/1/09 4/1/09 -Total Residual Ox 1-D071 (CRS) v2 MNR MNR 3/1/09 4/1/09 Total Residual Ox 1-D072 (CRS) v2 1-D072 MNR MNR 4/1/09 5/1/09 Flowt- DOl (CRS)O 2 D011 1580.6 1607.6 4/1/09 - 5/1/09 Flow - Intake - D071 (CRS) v2 D071 160.25 253.1 4/1/09 S5/1/09 Flow - Intake - D072 (CRS) v2 D072 7'.89 23.62 Flow D-600 (CRS) v2 4/1/09 5/1/09 5/1/09 pH - Background D071 (CRS) v2 D-600 IT 0.12 4/1/09 7-D071 8.11 8.11 4/1/09 5/1/09 pH - Background D072 (CRS) v2 7-D072 8.11 - 8.11 4/1/09 5/1/09 pH - Effluent - P-D071 (CRS) v2 P-D071 8.19 8.19 4/1/09 5/1/09 pH - Effluent - P-D072 (CRS) v2 P-D072 8.19 8.19 4/1/09 5/1/09 pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 1.11 -0.31 4/1/09 5/1/09 [pH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 -0.31 4/1/09 5/1/09 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 S7.11 7.11 il 8.5 4/1/09 5/1/09 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 8.5 I 10/21/2009 Page 43

0 0 Crystal River South DMR Data Permit No. FL00000159 KBegin datej End Datef PARAMETER-NAME~>~7WOty C-4vC jFC-Min CMaxj Q-Mg-Qax N0DI-Avg j:NODII-Max ,'NODII-Min' 4/1/09 5/1/09 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 4/1/09 5/1/09 Resid Ox - Dis Time - 0072 (CRS) v2 0072 0 4/1/09 5/1/09 iResid Ox - Dis Time P-DO11 (CRS) v2 P-Do11 0 4/1/09 5/1/09 iResid Ox - Dis Time P-D012 (CRS) v2 P-DO12 0 -I 4/1/09 5/1/09 Temp Rise - D011 (CRS) v2 D011 14.8 17.2 4/1/09 5/1/09 [Temp Rise - D012 (CRS) v2 D012 15.7 17.2 D011 87.6 93.9 4/1/09 5/1/09 Temp-Discharge - D011 (CRS) v2 87.6 4/1/09 5/1/09 ITemp-Discharge - D012 (CRS) v2 D012 93.9 4/1/09 5/1/09 Temp-Intake - D011 (CRS) v2 DOll 72 77.1 4/1/09 5/1/09 Temp-lntake - D012 (CRS) v2 D012 72 77.1 4/1/09 5/1/09 Total Recoverable Iron D-600 (CRS) v2 D-600 5000 5/1/09 Total Residual Ox 1-D011 (CRS) v2 ]i MNR MN 4/1/09 4/1/09 5/1/09 Total Residual Ox 1-DO12 (CRS) v2 1-Do11 1-DO12 I JiMNR MNR 5/1/09 Total Residual Ox 1-D071 (CRS) v2 MVNRr _____ 4/1/09 1-D071 5/1/09 Total Residual Ox 1-D072 (CRS) v2 4/1/09 1-D072 MNR MNR 5/1/09 6/1/09 FFIow - D011 (CRS) v2 D011 IF 1664.4 1690.1 5/1/09 6/1/09 Flow - Intake - D071 (CRS) v2 D071 335.93 505.46 5/1/09 6/1/09 Flow - Intake - D072 (CRS) v2 D072 I! 179.84 375.14 5/1/09 6/1/09 Flow D-600 (CRS) v2 D-600 0.05 5/1/09 6/1/09 pH - Background D071 (CRS) v2 7-D071 8.11 8.11 5/1/09 6/1/09 pH - Background D072 (CRS) v2 7-D072 8.11 8.11 5/1/09 6/1/09 pH - Effluent - P-D071 (CRS) v2 P-D071 8.14 8.14 - 5/1/09 6/1/09 IpH - Effluent - P-D072 (CRS) v2 P-D072 8.17 8.17 i 1 5/1/09 6/1/09 {pH - Ex of Calc Limit - R-D071 (CRS) v2 R-D071 -0.36 1.1 5/1/09 6/1/09 IpH - Ex of Calc Limit - R-D072 (CRS) v2 R-D072 rI

                                                                                                    -0.33                        ji     --- ___

5/1/09 6/1/09 pH -Calc Limit - Q-D071 (CRS) v2 Q-D071 7.11 8.5 5/1/09 6/1/09 pH -Calc Limit - Q-D072 (CRS) v2 Q-D072 7.11 8.5 5/1/09 6/1/09 Resid Ox - Dis Time - D071 (CRS) v2 D071 0 5/1/09 6/1/09 Resid Ox - Dis Time - D072 (CRS) v2 D072 0 5/1/09 6/1/09 lResid Ox - Dis Time P-DO11 (CRS) v2 P-DOll j - 0 j-5/1/09 6/1/09 ýResid Ox - Dis Time P-D012 (CR5) v2 P-D012 0 5/1/09 6/1/09 Temp Rise - D011 (CRS) v2 D011 12.6 14.7 7 - 5/1/09 6/1/09 Temp Rise - D012 (CRS) v2 0012 14.7 12.6 5/1/09 6/1/09 Temp-Discharge - D011 (CRS) v2 0011 95.6 91.7 I I l I 10/21/2009 Page 44

Crystal River South DMR Data Permit No. FL00000159 E-d Dat < " NAME yutall C- vARAMETER C x Q-Ayg aC-VinNOD-Av DIAx 0OI-a NOIg

N6DI-Maxj,,_NOOI-Mi6.'

6/1/09 6/1/09 Temp-Discharge -D012 (CRS) v2 Temp-_ntake - D011 (CRS) 2 O012 D011 91.7 79.3 21 95.6 85.1 I i 6/1/09 Temp-Intake - D012 (CRS) v2 D012 79.3 85.1 6/1/09 Total Recoverable Iron D-600 (CRS) v2 D-600 i1 5600 I 6/1/09 Total Residual Ox 1-Do11 (CRS) v2 1-D0111! .... . MNR MNR 6/1/09 Total Residual Ox 1-D012 (CRS) v2 1-D012 ____l_._---iMNR MNR 6/1/09 Total Residual Ox 1-D071 (CRS) v2 1-D071 IVMNR MNR 6/1/09 Total Residual Ox 1-D072 (CRS)v2 1-D072J I_____ MNR I INR 10/21/2009 Page 45

Hydrology H-6

1. Crystal River Incident Log Sheet

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becomrink aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessari', use back of form for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

7/13/2007; - 05:00 A.M.; Ceased at - 06:00

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

6,000 gals; Treated Drinking Water with a residual chlorine level of 2.5 ppm

4. Location of incident.

Pall Microfiltration (MF) Unit; Crystal River South, south side of water treatment building.

5. Source and cause.

Pall MF Unit - Storage Tank overflow. MF system tripped, water from the site potable water storage tank back-flowed into the MF storage tank. The MF storage tank has an overflow pipe that discharges to the ground.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

The overflow pipe will be piped to the lab sump to prevent discharge to ground (Note: this was already planned.)

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Water released onto the asphalt roadway. Water flow east to the storm drain, and west to the Unit 1 intake area. Flowed into site intake canal at both locations. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 7/13/2007, 08:30 (verbal); 10:00 (written)

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Doug Yowell called Nita Ostermann, FDEP SW Dist. Office @ 10:45 AM on 7/13/07 Agency Contacted: FDEP State Warning Point: Report/Log No: 4597 1-800-320-0519 Operator Name: ID 417 Date/Time Called In: 10:55 AM on 7/13/07 National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:TEnvironmental & Rad Control\License Renewal Needs List\H-7 Chlorine Spill Units I and 2 July 2007.doc

Crystal River Incident Log Sheet LAEnvironmental & Rad Control\License Renewal Needs List\H-7 Chlorine Spill Units I and 2 July 2007.doc

Progress Energy Larry Hatchcr Plant Manager Crystal River Fossil Plant June 25, 2009 Ms. Ilia Balcom Manager, Industrial Wastewater Compliance Florida Department of Environmental Protection Southwest District 13051 N. Telecom Parkway Temple Terrace, FL 33637-0926

Dear Ms. Balcom:

Re: Progress Energy Florida, Inc. Crystal River Units 1, 2, & 3 Upset Thermal Limit Excursion Follow Up Notification - NPDES Permit No. FLOOOO 159 Per General Condition 20 of the subject permit, the following information is being provided in response to an incident that was called in to Mr. James Womble, FDEP, by Mr. Doug Yowell, Progress Energy Florida, Inc. (PEF) on June 21, 2009. Please note that this event resulted in an upset condition with a subsequent exceedence of permitted thermal limits. Event description On Sunday, June 21, 2009, at approximately 3:00 PM, the POD discharge temperature for Crystal River Units 1, 2, & 3 exceeded the NPDES permit 3-hr rolling average (3-hr RA) temperature limit of 96.5 °F. The measured temperature continued above this limit for approximately 120 minutes until 5:00 PM, at which time the 3-hr RA fell below the 96.5 OF limit. Maximum 3-hr RA temperature measured during this time was 96.7 OF. At approximately 1:00 PM, Unit I load was at 389 MW and Unit 2 was at 466 MW. Inlet temperature was 88.9 OF while the POD 3-hr RA temperature was 95.9 TF. High tide was recorded at approximately 1:20 PM. To maintain compliance with the POD temperature limit, load reductions in both Units I

& 2 began shortly after 1:00 PM. By 1:40 PM, load was reduced to 324 MW from U-1 and 335 MW from U-2. The POD temperature at this time was still at 95.91 °F. By approximately 2:00 PM, Unit 1 had been further derated to 219 MW. Unit 2 was maintained at approximately 339 MW. At this time, it was noted that the POD temperature had increased to 96.1 OF, and that no significant changes to the intake temperature had occurred (i.e. still approximately 88.9 °F).

Progress Energy Florida, InC. 15760 W. Powerline Street Crystal River, FL34428

Beginning approximately 2:30 PM, it was noted that the intake temperature began to rise, corresponding with the outgoing tide. Load reductions continued such that by 3:00 PM, U-1 had been reduced to 123 MW and U-2 to 153 MW. Intake temperatures were approximately 89.3 OF. It was at this time that the 3-hr RA was first observed to go over the limit. The 3-hr RA temperature at approximately 3:00 PM was 96.56 OF. Intake temperatures continued to rise and peaked at 89.5 'F at around 4:40 PM. At the time of the event ambient conditions were extreme and had been for several days prior to the event as evidenced by several heat advisories posted by the National Weather Service. The tide had been incoming since 8:00 AM. A review of tidal information the following day revealed unusually high and low tides during June 21. After the tide started going out at approximately 1:20 PM, the instantaneous discharge canal temperature started increasing at a high rate . Furthermore, exceptional heat and corresponding high wet bulb temperatures (i.e. high humidity levels) served to lower the efficiency of the helper and modular cooling towers, all of which were in operation during this time. In the days since this event, both Units I and 2 have been significantly derated during a majority of the time to ensure compliance with the POD temperature limits contained in the NPDES permit. However, given that we have experienced these extreme conditions this early in the season, our concern is that as we proceed on into the summer, that extreme ambient conditions may again occur, particularly at a time when load reductions may not be feasible due to electrical grid stability issues. We will keep the Department informed as far in advance as possible should such a scenario appear imminent. If you have any questions regarding this event, please contact Mr. Doug Yowell at (727) 820-5228. Sincerely, Larry Hatcher Fossil Plant Manager Certified

Bee: Jim Holt, NA2C Rob Odom, CN77 Dan Kemp, PEB17B2 Paul Lewis, Jr., TL68 Brenda Brickhouse, PEB903 Tom Lawery, PEF134 Nick Maltese, CN77 Erika Tuchbaum-Biro, CN77 Patty West, PEF903 Glenn Dooley, EC37 Frieda Frando, NAI B Brandon Barr, PA3A I Certified Mail: 7008 1300 0002 2610 5270

Crystal River Unit 3 Incident Log Sheet Note: This form to be completed for all oil, chemical or waste water spills/leaks. Report all such incidents to: Brandon Barr 352-464-7403 In addition all spills in excess of 1000 gallons must be reported ivithin 24 hours of becoming aware of the s/L/ to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Brandon Barr

2. Date, time and status (ongoing or ceased) of spill.

6/02/2009 3:00 pm buried pipe leak discovered. The system that the pipe belongs to was unknown at this point. 6/03/2009 approximately 2:30 pm buried pipe leak was repaired and confirmed to be a sanitary sewer line.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

     - list type).

Approximately 3 ft2 of paved surface was covered with sanitary waste water from a pipe leading from a sump that is part of the collection system for CRS Domestic WWTP, FLA0118753. Since it is not known how long the pipe had been leaking, an actual volume of waste water leakage is difficult to estimate. Conservatively, 1 yd3 of dirt was wetted with the fluid that leaked from the pipe. Assuming a porosity of 0.3, we can conclude that about 20 gallons of waste water was needed to fully saturate this amount of dirt (the dirt was not fully saturated). The breach through the paved surface may have resulted in some evaporation, making the leakage amount slightly greater than 20 gallons. Overall,

     <25 gallons of sanitary waste water is expected to have leaked from the pipe.

4. Location of incident.

North of warehouses under paved road, but south of the Site Access Road.

5. Source and cause.

Approximately a 1 '/2 inch diameter PVC pipe that leads from a sump for CR3 warehouses had a '/ diameter hole with about a 4 inch long crack propagating from the hole. The pipe failure is expected to be from the combination of old pipe, PVC material used instead of HDPE or other material less brittle than PVC, the shallow depth of the pipe (the pipe is buried about 2 ft deep), and the use of heavy equipment in the area.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Spill was onto paved surface. The area had lime applied around the edges, and then sandbags were placed around the area in case more leakage occurred during the excavation. A contractor was called onsite to repair the pipe. The sump was pumped before work began to ensure that no waste water would be flowing through the line while work was being done. The dirt around the pipe break was excavated and placed on plastic to prevent contamination of other surfaces. After the pipe was repaired, lime was spread over the exposed area. Then the excavated dirt was treated with lime as it was backfilled into the area where it was removed from.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Paved surface approximately 3 ft2. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell 6/3/2009 4:26 pm

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

Doug Yowell reported spill to Jamie Lewis FDEP Southwest District @ 4:47 pm on 6/3/2009.

Crystal River Unit 3 Incident Log Sheet Agency Contacted: FDEP State Warning Point: Report/Log No: N/A 1-800-320-0519 Operator Name: Date/Time Called [n: National Response Center: Report/Log No: N/A 1-800-424-8802 Operator Name: Date/Time Called In:

CR3 Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. If necessary, use back of form for additional comments In addition all spills in excess of 1000 gallons must be reported within 24 hours of becomin2 aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility.

1. Name of person(s) responding to incident and completing this form.

Carolyn Johnson, Senior Environmental Specialist - CR3/Michael Shrader, Lead Environmental Specialist - PEF

2. Date, time and status (ongoing or ceased) of spill.

9-21-2007 19:00 hours Ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW -

list type). An overflow of Instrument Air Heater IAHE-6B was noticed trickling to a storm drain. The drain was immediately covered and the water was redirected until it could be contained. The apparent cause was a stuck valve where the domestic water was entering the system. This allowed IAHE-6B to overflow less than 5 gallons of treated water into the nearby storm drain. This water was treated with small amounts of Spectrus NX 1100, Spectrus NX 1103, Dianodic 2140 and Foamtrol AF1440 and the MSDSs are attached below.

4. Location of incident.

CR3 on the berm within the fenced area.

5. Source and cause.

The excess water being added was caused by a stuck valve; therefore, allowing more water than normal to enter IAHE-6B, overflowing, and diluting the existing concentration of chemicals in the treated water. It is expected that due to the length of piping this overflow would have been spread across the surface area and may have evaporated. However, the rain from the day following this overflow may have carried a small portion of this treated water to the discharge canal.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

The drain was immediately covered and the water was redirected until it could be contained.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Less than 5 gallons entered the storm drain. It is not certain that any reached the discharge canal. To beh¢om ed Iyv Site :'Anvironmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Mike Shrader was contacted on 9/21/2007 at 2030.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

Mike Shrader determined that the spill would be reportable upon verification that spill may have reached the discharge canal due to a subsequent rainfall event. Notification made to Ilia Balcom IWW Compliance Section, SW District, FDEP at 0900 on September 25, 2007. Agency Contacted: FDEP State Warning Point: Report/Log No: N/A - Spill was < 1,000 gal. 1-800-320-0519 Operator Name: Date/Time Called In:

CR3 Incident Log Sheet National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: NX-1100.pdf (487 I'JX-1103.pdf (193 Dianodic 2140.pdf AF 1440.pdf (133 KB) KB) (200 KB) KB)

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical or waste water spills/leaks. Report all such incidents to: Erika Tuchbaum-Biro (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spil to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back offinrm for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Erika Tuchbaum-Biro

2. Date, time and status (ongoing or ceased) of spill.

4/16/2009 10:10 am. Leak ceased.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

    - list type).
    <50 gallons of treated domestic waste water clear well effluent.

4. Location of incident.

South domestic wastewater plant.

5. Source and cause.

A pump motor was being changed out and the associated valve was not completely closed. When the second associated pump turned on the clear well effluent spilled over to the piping where the valve was not completely closed.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Spill was onto graveled area and no pool of fluid accumulated.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Graveled area approximately 2 feet by 3 feet was wet when the leak was discovered. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell 4/16/2009 12:00pm

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

Doug Yowell reported spill to SW DEP. Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In:

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Cathie Loudenslager (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware ofrthe spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Nick Maltese coordinating a response, Cathie Loudenslager completing the form.

2. Date, time and status (ongoing or ceased) of spill.

02-27-08 1530 the Crystal River South front office sewer line to the lift station backed up into the front office and some leakage occurred to the environmental in the area of the cleanout. A small amount is still leaking from the cleanout cap.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Approximately 10-15 gallons of domestic waste water were spilled in a grassy area next to the road.

4. Location of incident:

Crystal River south plant, north of and adjacent to the front office around the line cleanout for the sewer line going to the lift station.

5. Source and cause:

Unknown at this time, suspect plug in the line.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

The spill is being responded to by responder's and contractors. Any soil impact will be treated with lime.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Grassy/ dirt area about 5' x 7'. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Pat Garner 02-27-08 1540

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Domestic Wastewater spill Unit I and 2 February 2008.doc

Crystal River Incident Log Sheet Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Domestic Wastewater spill Unit I and 2 February 2008.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical or waste water spills/leaks. Report all such incidents to: Erika Tuchbaum-Biro (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spil to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Erika Tuchbaum-Biro

2. Date, time and status (ongoing or ceased) of spill.

04/01/2009 08:15pm. Leak ceased.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

     - list type).
     <100 gallons of hydraulic fluid.

4. Location of incident.

South Coal Yard.

5. Source and cause.

Failure of accumulator on the E-Crane. Located on the counterweight cylinder.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Emergency response was notified and laborers deployed with oil spill clean-up materials.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Hydraulic fluid spilled onto coal which was scooped and placed onto active coal pile. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Bob Stafford 727-820-5538

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

No reporting was required due to no impact on navigable waters. Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In:

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Erika Tuchbaum-Biro (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments I. Name of person(s) responding to incident and completing this form. Erika Tuchbaum-Biro

2. Date, time and status (ongoing or ceased) of spill.

Release identified: 10:30 AM 8/18/2008

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Discharged approximately 2 gallons of hydraulic oil from an oil/water separator that had overflowed and was immediately contained in the area of the spill. After a rain event the residual oil that was in the storm drain (approximately 300 feet long) approximately 2-3 ounces entered the Crystal River Energy Complex discharge canal during the containment process.

4. Location of incident.

West end of Crystal River Helper Cooling Towers

5. Source and cause.

Hydraulic oil from an oil/water separator that had overflowed.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Oil that came out of the separator went into the storm drain which first goes to a retention pond with a weir where the majority or the oil was recovered. An oil collection boom system was placed both in the retention pond around the weir leading to the discharge canal and around the point of discharge into the canal where any visible sheen was cleaned up.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Discharge canal was impacted in a small area along the northern edge of the canal just west of the helper cooling towers. The area within the spill boomed is estimated to be a 10 foot x 15 square foot area of water. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Bob Stafford, 8/18/2008 5:30 p.m.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Bob Stafford notified NRC, EPA Region IV, FDEP, Coast Guard Agency Contacted: FDEP State Warning Point: Report/Log No: 6504 1-800-320-0519 Operator Name: #416 Date/Time Called In: 8/18/2008 6:40 National Response Center: Report/Log No: 881036 1-800-424-8802 Operator Name: Mr. Hollowood L:\Environmental & Rad Control\License Renewal Needs List\H-7 Hydraulic Oil spill Units I and 2 August 2008.doc

Crystal River Incident Log Sheet Date/Time Called In: 8/18/2008 5:30pm L:\Environmental & Rad Control\License Renewal Needs List\H-7 Hydraulic Oil spill Units I and 2 August 2008.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) If necessary,use back of form for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

3/20/07; 15:00; System Out of Service, being tagged out for repair. Work is being planned, and pipe should be repaired this evening, so system can be placed back into service.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

200 to 500 gallons Industrial Waste Water from CR South

4. Location of incident.

15 feet downstream where IWW line exits the pipe trench and heads up the hill to the percolation ponds.

5. Source and cause.

This is a 10 inch diameter fiberglass pipe which is leaking at a flange joint.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Leaking waste water is soaking into the ground and/or draining back into the pipe trench. (Note: the pipe trench ties back into Sump No. 10 which would then pump back into this same line.)

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Approximate 10 to 15 feet by 2 feet wide area of lime rock soil. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, EHSS, 3/20/07, approximately 15:15.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:Environmental & Rad Control\License Renewal Needs List\H-7 Industrial Wastewater Pipe Leak Unit I and 2 March 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

8/1/2007 10:00; ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

650 gallons of neutralized industrial waste waster

4. Location of incident.

CRS IWW line; underground line location: south of Unit 1 stack

5. Source and cause.

Neutralized industrial waste water from the waste neutralization system (pH tested at 7). Contractor digging trench for conduit replacement. IWW pipe was already exposed but backhoe operator accidentally hit line and punctured it.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Water lab was immediately notified and they shut down the tank pumps. Majority of waste water soaked into dirt inside trench, some water ran on to asphalt road and nearby rocked area. No water entered the intake canal.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Waste water was retained primarily in the trench (2 ft wide by 20 ft long); or immediately around the trench. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 8/1/2007; 11:30 AM.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Doug Yowell contacted Nita Ostermann, FDEP SW Dist. office at 2:12 PM on 8/1/07 Aiency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:kEnvironmental & Rad Control\License Renewal Needs List\H-7 Industrial WW leak July 2007.doc

Crystal River Incident Log Sheet L:\Environmental & Rad Control\License Renewal Needs List\H-7 Industrial WW leak July 2007.doc

Crystal River South- Units 1&2 Revised Spill Incident Log Sheet February 26, 2008 Permit No. FLOOOO 159

1. Name of person(s) responding to incident and completing this form.

Joe Bocek, Lab Tech, Crystal River Units 1&2, Responder Catherine Loudenslager, Environmental Specialist, Crystal River Units 1&2, Completer of form

2. Date, time and status (ongoing or ceased) of spill.

Spill was discovered on February 17, 2008, at 3:15 PM, Status is ongoing

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

  - list type).

Released treated industrial waste water from low conductivity tank, of neutral pH at Crystal River Units 1&2. The location of release was upstream of the tank. The water is normally discharged into the percolation pond. Spilled quantity is estimated to approximately 100 gallons.

4. Location of incident.

Industrial waste water line rupture is located on the south side of the CR 1&2 tank area on south side of laboratory and north side of the intake canal. Water was contained - no impact to surface water occurred during this event.

5. Source and cause.

The cause of the event is believed to be failure of a previous repair on the underground waste water line.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Water that pooled in the area was recovered via a super-sucker truck and transported to the percolation pond for proper disposal. The water line only leaks a small amount when the pump is operated. The line was rewrapped and repaired on 2/19/08. The repaired location was monitored to ensure no further leakage. On February 25, it was discovered that the repair failed. Therefore, a 40 to 50 foot section of the piping will be replaced and the work completed by February 27, 2008.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

The released industrial waste water did not impact surface water during the event. The water pooled in a grass/gravel area to the north of the canal. Area was excavated and sandbagged to ensure no water will be released to any surface water. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Patricia A. Garner was contacted on 2/18108 at 1430 hrs.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

   " Patricia A. Garner, EHSS Sr. Environmental Specialist, reported incident to Mr. James Womble, FDEP-SW District Office, on February 18, 2008 at 3:23 p.m.
   " Mr. James Womble, FDEP-SW District Office, was notified of this new development.

This log serves as written notification and was originally forwarded to Mr. Womble on February 22, 2008. This revised log was forwarded to Mr. Womble on February 26, 2008. This incident did not require notification to any other agency.

Crystal River South - Units l&2 Revised Spill Incident Log Sheet February 26, 2008 Permit No. FLOOOO 159

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

11/9/07 15:15 to 11/9/07 15:45; now ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Estimated 25 gpm x 30 minutes = 750 gallons, service water from CRN.

4. Location of incident.

Air release valve on the service water transfer line between CRN and CRS, located at the north end of the pipe bridge across the discharge canal.

5. Source and cause.

CRN was in the process of transferring service water to CRS to support Unit I startup. Spray was noticed by nuclear security and reported at 15:15. CRN transfer pumps were shut down and the line isolated at 15:40. Additional spray (pressure release) occurred for about 5 minutes. A hole was found in a flange at an air release valve on the pipe at the leak. Sample collected and analyzed for free residual chlorine (0.8 ppm) and pH (9.9). These values are consistent with normal CRN treated water. WR will be initiated to repair the flange.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Water sprayed directly into the discharge canal. No way to prevent discharge.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Treated water released into the discharge canal. No adverse environmental or biological impact was seen. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 11/9/07, 16:00, by telephone.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Aa~ency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: L:Environmental & Rad Control\License Renewal Needs List\H-7 Service Water Tranfer Line Units I and 2 November 2007.doc

Crystal River Incident Log Sheet National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:Environmental & Rad ControlkLicense Renewal Needs List\H-7 Service Water Tranfer Line Units I and 2 November 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and/or completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

7/22/07; @ approx. 11:00 AM; Ceased (Tech nearby able to immediately secure)

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Approx. 300 - 500 gallons; neutral pH industrial waste water.

4. Location of incident.

CRS Low Conductivity Tank

5. Source and cause.

Overflow of low conductivity industrial waste water tank; tank level indicator failure.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Manually started tank pumps to lower tank level.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Ground area around tank; tank sits inside a berm. All waste water contained inside of berm. pH of water was 7.2 To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 7/23/07. 08:30 AM

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Doug Yowell called Nita Ostermann, FDEP @ 10:50 AM on July 23, 2007 Agency Contacted: FDEP State Warning Point: Report/Log No: N/A 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: N/A 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs ListfH-7 Tank Overflow Units I and 2 July 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back of form for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

7/18/07 - Time unknown for sure, probably at about 3 AM; now ceased (ceased at 6:30 AM)

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Low Conductivity Plant Waste Water; 5,000 gallon estimate (Max) consisting of moderate pH industrial wastewater.

4. Location of incident.

CRS, Low Conductivity Waste Water Tank 5 Source and cause. Low Conductivity Waste Water Tank; failed tank level indicator

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Tank sits inside a dirt berm; most of the overflow was contained within the berm and allowed to soak in. (Note: Pumps were turned on manually, maintenance will repair the level indicator as soon as water soaks in to the ground.) Water still in the berm was tested for~pH on Wednesday 7/18/07 and found to be pH = 8.1.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Mostly contained within a dirt berm. Less than 1,000 gallons spilled into the intake canal. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 7/18/2007, 07:50

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Doug Vowell called Nita Ostermann, FDEP SW District Office on 7/18/07 @ approx. 3:00 PM Agency Contacted: FDEP State Warning Point: Report/Log No: 4818 1-800-320-0519 Operator Name: ID 415 Date/Time Called In: 7/19/07 @ 7:00 AM by D. Yowell National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:.\Environmental & Rad Control\License Renewal Needs List\H-7 Tank Overflow Units I and 2 July 2007 2.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back of form for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

6/1/2007 - 10:15 PM; now ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Low Conductivity Plant Waste Water; 2,100 gallon estimate (140 gpm x 15 min) consisting largely of demineralized (ultra-pure) water from R.O. flushing activity.

4. Location of incident.

CRS, Low Conductivity Waste Water Tank

5. Source and cause.

Low Conductivity Waste Water Tank; failed tank level indicator

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Tank sits inside a dirt berm; all the overflow was contained within the berm and allowed to soak in. (Note: Pumps were turned on manually, mechanics responded and repaired level indicator by 2:30 AM on 6/2/07.) Water still in the berm was tested for pi on Saturday 6/2/07 and found to be pH = 7.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Contained within a pervious dirt berm. No water spilled into the intake canal. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 6/4/2007, 07:20

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Douig Yowel! called ia Osternmain a'the 1" @ 7:45 -AM an .]une 4, 2007. and State f

                                                           /:1                                               'ffi1, Pointper beoii'ow Agency Contacted:

FDEP State Warning Point: Report/Log No: 3486 1-800-320-0519 Operator Name: ID 410 Date/Time Called In: June 4, 200 7 (d 9:05 AM (called in b* Doug Yowell) National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Tank Overflow Units I and 2 June 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware oflthe spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back offormnfor additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

11/06/07 06:00 ceased.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Approximately 5,000 gallons of untreated (neutral pH) industrial waste water from the Low Conductivity Tank. Approximately 100 gallons of this made it into the intake canal.

4. Location of incident.

CRS, Low Conductivity Tank

5. Source and cause.

Tank level indication became stuck which allowed the tank to fill up and overflow. Normally, tank level indication is used to turn pumps on and off automatically. Unknown why it became stuck, but it has been a problem in the past due to lime buildup. Possibly related to the well water line flushing that has occurred due to the well line breaks on 11/3/07 and 11/5/07.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Pumps turned on and placed in manual. WR written to fix level indication.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Tank is surrounded by a dirt berm which held most of the water. Some of the water seeped past the area where the berm comes into contact with the CR3 stainless steel tank. This amount is estimated at about 100 gallons and it flowed into the intake canal at the CRS water front. Water was tested with Litmus Paper at pH =7. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 11/6/07, 09:30 by phone message and email.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Doug Xowell notified Ilia Balcom, FDEP SW District Office @ 10:35 AM on 11/6/07 Agency Contacted: FDEP State Warning Point: Report/Log No: 7564 1-800-320-0519 Operator Name: Operator No. 417 Date/Time Called In: 11/06/2007 @ 10:45 AM Called In By: Doug Yowell L:\Environmental & Rad Control\License Renewal Needs List-H-7 Tank Overflow Units I and 2 November 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this lorm.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

6/27/07 8 P.M.; ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

25 to 50 gallons, final treated sewage plant effluent (chlorinated).

4. Location of incident.

CRS Sewage Treatment Plant - Permit No. FLA118753

5. Source and cause.

Failure at coupling on PVC line, after discharge pump, to the waste neutralization tank.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Pump was shut down, PVC pipe was re-glued and re-seated into the coupling. Leak stopped.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Small area on-ground beneath pump. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 6/28/07, 08:30

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

FDEP, State Warning Point, National Response Center). Doug Yowell notified Vicki Wheeler of FDEP on 6/29/07 @ 1:50 PM. Agency Contacted: FDEP State Warning Point: Report/Log No: NA - Spill was less than 1000 gal. 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Treatment Plant Effluent Spill June 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical or waste water spills/leaks. Report all such incidents to: Erika Tuchbaum-Biro (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the sill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back offrorm for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Erika Tuchbaum-Biro

2. Date, time and status (ongoing or ceased) of spill.

Reported by the lab at 08:30 4/27/2009. Leak has been diverted to sump which leads to percolation ponds.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

    - list type).
    <25 gallons of low conductivity neutralization waste water with a ph of 7.75.

4. Location of incident.

Just north of the intake canal behind the waste neutralization tank at the south plant.

5. Source and cause.

Rubber boot on fiberglass piping started leaking.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Spill was contained and a work order for the leak to be fixed was issued.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Gravel area of approximately 2feet by ifoot had been wetted. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell 4/27/2009 2:30pm

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center). Doug Yowell called James Womble, FDEP @

2:40 pm on April 27, 2009 and gave a verbal report. Agency Contacted: FDEP State Warning Point: Report/Log No: N/A spill was < 1000 gallons 1.-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: N/A 1-800-424-8802 Operator Name: Date/Time Called In:

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becomin2 aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

11/5/2007 approx. 9 PM to 11/5/2007 approx. 11 PM; ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

48,000 gals (2 hrs x 400 gpm x 60 m/hr); Untreated well water.

4. Location of incident.

CRS North Well Line, along the plant access road near the site Administration Building.

5. Source and cause.

Break in the 8 inch transite water pipe, probably caused by the high pressure surges associated with the new Pall Microfiltration System.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Line isolated.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Untreated water released onto the road surface and adjacent storm ditch. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 11/06/07, 09:30 by phone message and email.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). AgZency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Water Line Break November 2007.docx

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming awareof the spil to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back offoirmfor additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

9/25/2007; Evening (10:30 PM); ceased (at 12:00 midnight on 9/25/2007)

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

    - list type).

1.5 hours x 250 gpm = 22,500 gallons.

4. Location of incident.

Near the rail road spur going to CRN, CRS well line located along the south side of the road, next to the wetland area.

5. Source and cause.

Untreated production well water. A leak had developed at joint on this line, and had been repaired earlier this same day. A few hours later the repair failed. The line is now out of service pending new repair.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Line take out of service. Contractor (Paverite) to re-repair the line.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Untreated well water released to road surface (and thence to the storm drainage ditch along the north side) and into adjacent wetland area. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell; 9/25/07; 09:30 (telephone message); Pat Garner 9/25/07; 10:10 (by phone)

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

9/26/2007 - E2ISS

Conclusion:

Per Mike Shrader and Pat Garner, since this is raw water (untreated). there is no reporting requirement. Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Water Line Break Units I and 2 September 2007_2.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the sill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

9/27/2007; 05:15; ceased at 07:15 on 9/27/2007)

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

     - list type).

2 hours x 750 gpm = 90,000 gallons.

4. Location of incident.

Just East of the entrance to the Site Access Control Point (ACP) next to the 25 MPH speed limit sign, north side of the access road.

5. Source and cause.

Untreated production well water. Line blew out. Investigation revealed that the speed limit sign placement probably caused a buried rock to be pushed against the existing transite pipe. This appears to have created a weak point that caused the blow out. The sign was put in circa 2002-2003 at the time of construction of the ACP.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Line take out of service. Contractor (Paverite) to repair the line.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Untreated well water released to ground surface and thence to the storm drainage ditch along the north side of the road. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Pat Garner 9/27/07; 12:30; via this written report/email.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

9/2.7/2007 - EHSS

Conclusion:

Per Mike Shrader and Pat Garner, since this is raw water (untreated), there is no reporting requirement. Aaency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Water Line Break Units I and 2 September 2007_3.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Erika Tuchbaum/Biro (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Cathie Loudenslager - prepared form Marty Bartough- 7021 - response to incident

2. Date, time and status (ongoing or ceased) of spill.

Release identified: 3 p.m. on 7/23/08 Ceased: approximately 9:00 p.m. on 7/23/08.

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

Total release estimated at 1-5 gallons of dripping service water (treated groundwater). Water was from service water lines over the discharge canal that developed leaks. Released water entered a concrete enclosure then flowed to the discharge canal. Most of the water that leaked was contained with very little spilled to the canal (< 5 gal).

4. Location of incident.

Crystal River Units 1&2 Canal

5. Source and cause.

Release was caused by leaks that developed in the 1", 4" and 2" service water lines that are near the lime rock conveyor. This allowed approximately 1-5 gallons of service water to enter the canal.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

The spill was contained, isolated, and vacuum trucked out. The lines were immediately repaired.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Approximately 1-5 gallons of service water was released in a leak of service water lines over the canal. Most of the leak was contained in a concrete bermed area, where it was subsequently removed by vacuum truck. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell, 7/24/08/10:00 AM

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Doug Yowell contacted James Womble, FDEP - SW District, on July 25, 2008, at around 1:30 PM. Agency Contacted: FDEP State Warning Point: Report/Log No: N/A 1-800-320-0519 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Water Line Leak Units 1 and 2 Juy 2007.doc

Crystal River Incident Log Sheet National Response Center: Report/Log No: N/A 1-800-424-8802 Operator Name: Date/Time Called In: I LAEnvironmental & Rad Control\License Renewal Needs List\H-7 Water Line Leak Units I and 2 Juy 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming aware of the spil to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

10/2/2007; 16:30; ceased at 17:30 on 10/1/07

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

     - list type).

1 hour x 400 gpm = 24,000 gallons (estimate)

4. Location of incident.

Alley behind CRS water lab. Pall surge tank overflow into the alley thence into the canal from both directions. West over the embankment into the canal near the CR l&2 intake structure, east to the storm drain and out into the canal at the CR3 intake structure. Discharge created a red/brown plume at the point of discharge; however, no effect was seen in the discharge canal. Overflow from tanks normally goes to the CRS chemical sump (via a fire hose) - however, flow was too large and this small hose could not handle it. It appears that a slug of turbid water coming in from the well lines caused the Pall System to trip. Normally this should cause the high level switches in the external surge tanks to shut down the main control valve. This did not happen. The external surge tanks overflowed onto the alley way.

5. Source and cause.

Untreated production well water. Water was very turbid, red/brown color. Cause under investigation.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

None

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Untreated well water released to the asphalt alley way and thence to the intake canal water. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Pat Garner 10/2/07; 17:30; via telephone message; 10/3/07 10:15 via telephone conversation.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Water Spill Units I and 2 October 2007.doc

Crystal River Incident Log Sheet L:AEnvironmental & Rad Control\License Renewal Needs List\H-7 Water Spill Units 1 and 2 October 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of'becoming aware of the jpill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

9/24/2007; Evening (10:45 PM per MPW data); ceased (at 06:00 on 9/25/2007)

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW

     - list type).

7.25 hours x 750 pgm = 326,250 gallons.

4. Location of incident.

Just East of the pop-up security gate after the site ACP checkpoint. CRS well line located along the north side of the road, next to the storm drainage ditch.

5. Source and cause.

Untreated production well water. Line failure, cause unknown. It was noted that there is an existing repair on the line about 2 feet downstream of the break. It was also noted that PVC conduit (installed within the past year) runs about one foot above the top of the water line. Additionally, there are Jersey barriers sitting on the ground surface directly above the location of the water line.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Line take out of service. Contractor (Paverite) to repair the line.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

The line break caused a "blow out" of dirt and rock into the adjacent storm drain. Estimated quantity of dirt removed be the blow out is approximately 5 cubic yards. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

Doug Yowell; 9/25/07; 09:30 (telephone message); Pat Garner 9/25/07; 10:10 (by phone)

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept., State Warning Point, National Response Center).

9/25/2007 - EH-ISS

Conclusion:

Per Mike Shrader and Pat Garner, since this is raw water (untreated). there is no reporting requirement. A$ency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: L:\Environmental & Rad Control\License Renewal Needs List\H-7 Well line break Units I and 2 September 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becomin2 aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments

1. Name of person(s) responding to incident and completing this form.

Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

11/3/2007 at 4PM; to 11/3/2007 at 6PM; ceased

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

48,000 gallons; untreated well water

4. Location of incident.

On the "south" CRS well line, between Unit I and Unit 3, approx. 55 feet East of UI rollup door.

5. Source and cause.

Production well water (south well line); pipe rupture (8 inch transite pipe)

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Well line isolated at approx. 6PM. Hole in asphalt excavated line repaired on 11/4/07.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Water released onto asphalt parking/road way, thence to stormdrain, thence to discharge canal. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: 1-800-424-8802 Operator Name: Date/Time Called In: LAEnvironmental & Rad Control\License Renewal Needs List\H-7 Well Water Spill Units I and 2 November 2007.doc

Crystal River Incident Log Sheet Note: This form to be completed for all oil, chemical, or waste water spills/leaks. Report all such incidents to: Ron Johnson (464-7909) or Cyndy Wilkinson (464-7739) In addition all spills in excess of 1000 gallons must be reported within 24 hours of becoming" aware of the spill to the following: STATE WARNING POINT TOLL FREE NUMBER 1-800-320-0519 EHSS personnel will make this phone call on behalf of the facility. If necessary, use back ofform for additionalcomments I. Name of person(s) responding to incident and completing this form. Ron Johnson

2. Date, time and status (ongoing or ceased) of spill.

10/10/07; 13:00; ceased (duration was about 12 hours)

3. Estimated amount of discharge and type of product spilled (i.e. oil, fuel, chemicals, domestic/industrial WW - list type).

1,000 gallons (Estimate); Raw Water from production wells;

4. Location of incident.

CRS, waste neutralization tank sump, ground area behind the sump.

5. Source and cause.

MPW pressure relief valve overflow normally is routed to the low conductivity tank. A vestigial valve and piping (that was supposed to have been removed) was opened by the temporary MPW technician. He did not know that this valve and drain line was not supposed to be used. The flow through this line is too large and potentially can cause the waste neutralization tank to fill up and overflow. This tank is a batch neutralization process. It did not overflow during this event, however, the sump receiving the raw water overflow did overflow into the surrounding ground area. No water spilled into the adjacent intake canal.

6. Precautionary measures taken (whether the spill was contained and cleanup actions taken or planned).

Raw water allowed to soak into ground.

7. Extent of contamination (brief description of area contaminated - include details if spilled on impervious surface or on grass/gravel areas).

Dirt/soil area surround the waste water tanks, south of the water lab, adjacent to the intake canal. To be completed by Site Environmental Personnel:

8. Name, Date/Time of EHSS person contacted.

9. If incident is reportable, list other persons or agencies contacted - include date and time (i.e.County Health Dept.,

State Warning Point, National Response Center). Agency Contacted: FDEP State Warning Point: Report/Log No: 1-800-320-0519 Operator Name: Date/Time Called In: National Response Center: Report/Log No: L:AEnvironmental & Rad Control\License Renewal Needs List\H-7 Well Water Spill Units I and 2 October 2007.doc

Crystal River Incident Log Sheet 1-800-424-8802 Operator Name: Date/Time Called In: L:Environmental & Rad Control\License Renewal Needs List\H-7 Well Water Spill Units 1 and 2 October 2007.doc

Hydrology H-8

1. Groundwater Flow Study Report

ETnHydIll, LILC consulting hydrogeologistsand weilfield technology services 0 0 Groundwater Flow Study Report 0 Progress Energy Florida 0 CRo3 Power Generating Facility 0 Crystal River Energy Complex G-Cystal River, Florida 0 0 Producedby: S 9 EnHydro, LLC 334 East Lake Rd.

  #173 S  Palm Harbor, FL 34685-2427 9  Ph (813) 293-0740 Fax (813) 448-9322 S

ProducedFor: 0 Progress Energy Florida S 15760 West Power Line St. Crystal River Unit 3 MAC PAB3 S Crystal River, FL 34428 January 22, 2007 334 East Lake Rd., #M73 Pahn Harbor, FL 34685-2427 w ph - 813.293.0740, fax - 813.448.9322

0 0 January 22, 2007 BEII¶I dhlo©9 1L](c Progress Energy Florida - CR-3 Groundwater Flow Study Report 0 0 Professional Certification 0 In accordance with provisions in Chapter 492, Florida Statutes, I hereby certify 0 that I have examined this Groundwater Flow Study Report and attest that it has been reviewed and approved by the undersigned Florida Professional Geologist. 0 EnHydro, LLC has prepared this report in a manner consistent with sound geologic practices and that level of care and skill ordinarily exercised by members of the profession currently practicing in the same locality under similar 0 circumstances. Information provided to EnHydro, LLC by client representatives, agents, and other consultants has been accepted in good faith and is assumed to be accurate. 0 0 0 0 Signature 0 H. Cliff Harrison, P.G. Registered Professional Geologist 0 Registration No. 1926, State of Florida 0 EnHydro, LLC 0 Geology Business License GB504, State of Florida 40 0 01 Date I. I.

0 0 q

0. T tIny~dbr(o) LL(C consulting hydrogeologists and wellfeld technology seruices 0

0 Groundwater Flow Study Report 0 Progress Energy Florida 0 CR-3 Power Generating Facility 0 Crystal River Energy Complex Crystal River, Florida S 0 Producedby: 0 EnHydro, LLC 334 East Lake Rd.

   #173 Palm Harbor, FL 34685-2427 Ph (813) 293-0740 0  Fax (813) 448-9322 S

0 ProducedFor: Progress Energy Florida 15760 West Power Line St. Crystal River Unit 3 MAC PAB3 Crystal River, FL 34428 January 22, 2007 334 East Lake Rd., #J73 Palm Harbor, FL 34685-2427

ph - 813.293.0740, fax - 813.448.9322

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     *January           22, 2007 Progress Energy Florida - CR-3 Groundwater Flow Study Report n        yd          o       LI

TABLE OF CONTENTS
PROFESSIONAL CERTIFICATION ...........................................................

1.0 INTRODUCTION

........................................................................ 1-1

1.1 PUR PO SE ....................................................................... 1-1
1.2 O BJECTIV ES ................................................................... 1-1 0 2.0 FACILITY BACKGROUND ........................................................... 2-1
2.1 LO CATIO N ...................................................................... 2-1 2.2 SITE GEOLOGY AND HYDROGEOLOGY ............................. 2-1
3.0 GROUNDWATER LEVEL MONITORING WELLS ............................ 3-1 3.1 WELL CONSTRUCTION DESIGN........................................ 3-1 3.2 UNDERGROUND UTILITY CLEARANCE ............................... 3-4 3.3 WELL INSTALLATION AND DEVELOPMENT ..... ............ 3-4 4.0 GROUNDWATER LEVEL DATA COLLECTION .............................. 4-1 4.1 METHODOLOGY ...................................... ..................... 4-1 4.2 DATA COLLECTION RESULTS ........................................... 4-2 4.3 GROUNDWATER LEVEL MAPPING & CONTOURING ............. 4-2 5.0 DISCUSSION ....................................................................... 5-

6.0 CONCLUSION

S ................................................................ 6-1 APPENDIX A - MONITORING WELL ELEVATION SURVEY RESULTS APPENDIX B - WATER LEVEL GRAPHS

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0 0 4 January 22, 2007 Progress Energy Florida - CR-3 Groundwater Flow Study Report IEi[~Ty 111(U) f]LL(C 0 0 S S LIST OF TABLES TABLE 1 W ELL CONSTRUCTION DETAILS ......................................................... 3-8 0 0 TABLE 2 WATER LEVEL DATA

SUMMARY

......................................................... 4-3 0

0 LIST OF FIGURES S FIGURE 1 SITE LOCATION MAP....................................................................... 2-2 FIGURE 2 SHALLOW MONITORING WELL CONSTRUCTION DETAILS ...................... 3-2 0 FIGURE 3 DEEP MONITORING WELL CONSTRUCTION DETAILS ............................ 3-3 S FIGURE 4 SITE-WIDE MONITORING WELL MAP .................................................... 3-5 0 FIGURE 5 CR-3 FACILITY AREA MONITORING WELL MAP ..................................... 3-6 FIGURE 6 SITE-WIDE HIGH GROUNDWATER LEVELS .......................................... 4-5 FIGURE 7 SITE-WIDE LOW GROUNDWATER LEVELS ........................................... 4-6 FIGURE 8 SITE-WIDE AVERAGE GROUNDWATER LEVELS ................................... 4-7 FIGURE 9 CR-3 AREA SHALLOW HIGH GROUNDWATER LEVELS ........................... 4-8 FIGURE 10 CR-3 AREA SHALLOW LOW GROUNDWATER LEVELS ........................... 4-9 FIGURE 11 CR-3 AREA SHALLOW AVERAGE GROUNDWATER LEVELS ................. 4-10 FIGURE 12 CR-3 AREA DEEP HIGH GROUNDWATER LEVELS ......... .......... 4-11 FIGURE 13 CR-3 AREA DEEP LOW GROUNDWATER LEVELS ................................ 4-12 FIGURE 14 CR-3 AREA DEEP AVERAGE GROUNDWATER LEVELS ........................ 4-13

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0 January 22, 2007 A q Progress Energy Florida - CR-3 Groundwater Flow Study Report

1.0 INTRODUCTION

1.1 PURPOSE
Progress Energy Florida (PEF) requested that EnHydro, LLC (EnHydro) conduct a
detailed groundwater flow study and prepare a groundwater flow map for the area 0 around the CR-3 Power Generating Facility (CR-3) at the Crystal River Energy Complex in Crystal River, Florida. The purpose of the study is to comply with Nuclear Regulatory Comission requirements that all nuclear power generating facilities develop Monitoring, Response, and Reaction Plans to be implemented in the event of a release of radioactive water or other fluids to the groundwater. Previous reports prepared by PEF, including the Groundwater Monitoring Plan - Florida Power Corporation, Crystal River
Energy Complex (Dames & Moore - April, 1995) did not incorporate a sufficient density
of monitoring wells in the vicinity of CR-3 for development of realistic estimates of
groundwater flow direction. Accordingly, PEF authorized EnHydro to install 10 new
shallow and three new deep groundwater monitoring wells surrounding CR-3 from which accurate groundwater elevation data could be collected, and to develop a groundwater flow map for the area.
1.2 OBJECTIVES
The primary objective of the Groundwater Flow Study was to generate sufficient data to
characterize the groundwater flow in the vicinity of the CR-3 Facility. Specific objectives
included:
Installation of a sufficient number of groundwater monitoring wells to adequately characterize the groundwater flow regime in the vicinity of CR-3;
Collection of groundwater elevation data on a frequent enough interval and over a sufficiently long time period to conceptualize any fluctuations in the
groundwater flow regime as a result of the influence of tidal cycles in the adjacent
intake and outfall canals; and

Preparation of groundwater elevation contour maps with groundwater flow
direction vectors depicting the groundwater flow regime in the study area.

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  *January            22, 2007,                                      E&TH~ydhr'o LILC Progress Energy Florida - CR-3 Groundwater Flow Study Report

2.0 FACILITY BACKGROUND
2.1 LOCATION
The Crystal River Energy Complex is located near the Gulf of Mexico in Citrus County,
Florida (Figure 1). The facility encompasses approximately 4,750 acres and is situated
in portions of Sections 28 through 36, Township 17 South, Range 16 East and in portions of Sections 3. 4, 5, 9, and 10, Township 18 South, Range 16 East. There are 0 five power generating units at the Complex. Units 1, 2, 4, and 5 are coal-fired; Unit 3 (CR-3) is nuclear powered.

4 Units 1, 2, and 3 are located on the south side of the Complex. Associated

impoundment areas include two ash storage ponds, an evaporationlpercolation system,
and a coal storage area with a runoff collection ditch. Units 4 and 5 are located on the
north side of the Complex. Associated impoundment areas include a coal storage area with an associated runoff collection ditch, and evaporation/percolation pond system, and an ash landfill with a runoff collection ditch.

2.2 SITE GEOLOGY AND HYDROGEOLOGY note - much of the background information on the site geology and hydrogeology is directly reproducedor interpreted from the GroundwaterMonitoring Plan - Dames &Moore - April, 1995. The western portion of the facility is located within the coastal swamps, which are part of the irregular shoreline. This area has been interpreted as relict, drowned karst topography, where insufficient sand is available to form beaches. The karst terrain was develop4d through the dissolution of the underlying limestone and dolomite resulting in numerous swamps, lakes, and shallow sinkholes. Surface drainage is poorly developed or absent. Thin sediments have accumulated upon the exposed Eocene limestone. The features may represent a young shoreline. The nearby offshore area is covered by a thin clastic sediment veneer and is characterized by a karst platform with limestone outcrops, sinks, and a few submarine springs.

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Progress22, January EnHydrI , LLC 2007Florida - CR-3 Groundwater Flow Study Report Energy 0

Soils in and around the site arenearly level and poorly drained. In the eastern part of
the site, the dominant soil association is the Broward-Boca association. This association
consists of sandy soils underlain by limestone. To the west, these soils are nearly
saturated and are classified as members of either the freshwater swamp or saltwater
marsh association. The soils are subject to frequent and prolonged flooding.
The site geology is consistent with geology and hydrogeology of the coastal swamps
with low marine terraces inland which have formed on a paleokarst peneplain. The 0 Crystal River Shelf Embayment (coastal swamp area) exhibits a sediment (sand)
starved, low wave energy environment resulting in little to no sediment accumulation.

The karst limestone surface in the vicinity of the percolation and ash ponds was originally bare to thinly covered with swamp-related muck soils, sand, and clayey sand in depressions (pockets) prior to the original site development in the late 1960's. Solution of the limestone is still occurring within both small scale and large scale features. A highly irregular array of small scale (centimeters to meters) pits, depressions, borings, etchings, and pinnacles are being altered by the acid marsh waters and root penetration. Small sinkholes or dolines are associated with the small scale karst actions. The larger

scale karst features (tens to hundreds of meters) result from aggressive

*     (undersaturated) groundwater being concentrated in rectilinear fractures, creating long

linear depressions at the surface and underground channels and caverns.

Soil boring programs conducted in the past at various areas around the Complex have

indicated that voids, where encountered, are generally to be found within 50 ft of the
land surface. Studies have shown that the shallow portion of the Floridan Aquifer
beneath the site consists of two primary zones in the Inglis Formation: 1) a zone from
the surface to approximately 30 ft below land surface (bls), and 2) a zone extending from
between 40 and 60 ft bls down to where the Inglis and Avon Park Formations interface.
The upper zone contains many large interconnected solution cavities and channels that
are highly permeable, whereas the solid, unfractured limestone in between the two
zones has a much lower permeability. The lower zone (40 to 60 ft bls) contains smaller
voids and solution channels that are not as transmissive, as those in the upper zone.
There is a general upward flow gradient (discharge) in the Floridan Aquifer at the site..

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January 22, 2007 1En Hy Dh' LLC Progress Energy Florida - CR-3 Groundwater Flow Study Report

3.0 GROUNDWATER LEVEL MONITORING WELLS 0
3.1 WELL CONSTRUCTION DESIGN

 *Construction                     diagrams and plans provided to EnHydro by PEF, as well as personal
 *communications                        with drillers and geologists with first-hand experience at the site,

indicated that voids, caverns, and channels within the Inglis Formation (down to

  *approximately                     90 - 120 ft bis) were grouted with large volumes of cement as part of the subsurface grouting programs undertaken prior to the construction of the CR-3 facility-0                 The presence of large volumes of cement in the subsurface could act as a barrier to groundwater flow, altering the natural groundwater flow pathways. Also, the area around CR-3 is almost entirely paved, reducing the infiltration of rainfall into the shallow aquifer, this will also tend to alter the natural groundwater flow pathways. Because of these alterations, the close proximity of the intake and discharge canals, and the duat-layered nature of the Upper Floridan Aquifer beneath the site, it was determined that a network of shallow wells surrounding the CR-3 facility would be necessary for an accurate

determination of the groundwater flow pathways beneath the site. To determine if there is any difference in the groundwater flow direction between the upper and lower zones of the aquifer or if there is any significant upward flow beneath the site, it was decided to install three deeper monitoring wells within the network.

The monitoring wells were constructed of two-inch diameter Schedule 40 PVC well casing and screen. The screened intervals are 10 ft long, and are capped on the bottom ends with a PVC cap or plug. A filter pack of 20130-grade silica sand was emplaced around the screened interval, extending to at least one foot above the screen. A one-foot thick bentonite hole plug seal was place above the filter pack, followed by a one-foot thick fine (30/65 grade) sand seal. The wells were then grouted to land surface with Portland cement. The 10 shallow wells were constructed with approximately 20 ft of two-inch PVC well casing above the screened intervals; total depth was targeted at 30 ft bls, dependant on site-specific geology. The three deep wells were constructed identically to the shallow wells, with the exception that the deep wells were targeted for 70 -80Jft bls; the deep wells were constructed with 60 - 70 ft of PVC well casing above the screens. Construction details of the wells are provided in Figure 2 and Figure 3. I 1-

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January 22, 2007 En[y1m , LLC Progress Energy Florida - CR-3 Groundwater Flow Study Report o 3.2 UNDERGROUND UTILITY CLEARANCE

Prior to commencing drilling, each of the chosen well sites was investigated with Ground 0 Penetrating Radar (GPR). Subsurface Evaluations, Inc. (SEI) provided a GPR Operator
who inspected an area of 10-ft x 10-ft or greater around each of the chosen drilling sites
with a portable GPR unit. Paint marks were placed on the ground over any suspected
below-ground obstructions; these marks were transferred to paper sketches for 0 reference and archiving. Some of the drilling sites required modification to the originally-chosen locations due to either underground obstructions or to overhead power lines.

Safe drilling sites were eventually successfully identified at sufficient locations to provide adequate coverage around the CR-3 Facility for the development of groundwater flow maps. 3.3 WELL INSTALLATION AND DEVELOPMENT To verify that the resultant CR-3 groundwater flow maps would be in agreement with larger-scale (site-wide) patterns of groundwater flow, it was decided that the K

groundwater elevation monitoring effort would include all available shallow monitoring wells across the Crystal River Energy Complex. Figure 4 depicts the locations of all of
the shallow monitoring wells at the Complex. Figure 5 shows the locations of all of the

   *   ~new        wells installed around the CR-3 Facility, including both shallow and deep wells. The

three deep wells (CR3-1D, CR3-3D, and CR3-6D) were installed adjacent to wells CR3-

   **1         S, CR3-3S, and CR3-6S.                                                            -,

The wells were drilled by Grosch Drilling Company of Dublin, Georgia using a Foremost
dual-rotary, direct-air drilling rig. This type of rig allows the driller to advance an 8-inch

    *        -diameter conductor casing down the drilled hole following closely behind the drill bit, without the use of drilling mud or other fluids. Cuttings and groundwater are discharged 0         from the hole by the action of compressed air jetted out of the drill bit, which subsequently carries cuttings and groundwater up the annulus between the drill rod and the conductor casing. The discharged cuttings and groundwater were directed into a containment trailer to minimize the discharge of these materials onto the ground.

Cutting samples were collected on 10-ft intervals for field screening with an Organic 0 : Vapor Analyzer for the possible presence of petroleum products in the groundwater. 0 4-

S. *9*******@@e@OSeeS .9............. 444466* MW-.2R 9 MWo*2* mw-i 0 D 0 Mw-2tR MW-280 M CR3-9G Q CR34-1 D 00 CR34 CR3-15G E 000 CR

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                                 @CR3-4 CR3-5GR.3-5G C

Intake PEF -Crystal River CR-3 Flow Study EnHydro, LLC Citrus County, Florida Monitoring Well Site Map 0DATE 01/08/07) I m CR-3 Area

1"=300' ORAWNB,:DS Ft G"L!R 55 I I RGURE

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January 22. 2007 En(~111Q, ILIL(L Progress Energy Florida - CR-3 Groundwater Flow Study Report
None of the samples collected exhibited any trace of organic vapors. Additionally, one
sample was collected from each borehole for analysis by PEF for the presence of
radioactive isotopes; none of the samples collected exhibited any trace of radioactivity.
After the cuttings and discharged groundwater had been cleared (the absence of 0 petroleum products or radioactive isotopes had been verified), the cuttings and water were disposed of in a landfill area designated by PEF.

Prior to reaching the target depth for the wells (approximately 30 ft bis for the shallow wells, and approximately 75 ft bls for the deep wells) an EnHydro hydrogeologist examined the rock cuttings as drilling progressed; lithologic characteristics (porous,

permeable limestone versus dense, impermeable mudstone) were used to determine the
actual final depth of the wells. Upon reaching the final depth, the drill bit was withdrawn
from inside the conductor casing and the well string (casing, screen, and end cap) was
lowered through the conductor casing to the total depth of the well. A silica sand filter
pack (20130 grade) was emplaced around the screened interval as the conductor casing was slowly withdrawn from the hole. The filter pack was extended to at least one foot above the top of the screened interval. Next, a seal was created on top of the fitter pack by emplacing a one-foot thick layer of bentonite hole plug, topped with a one-foot thick
layer of fine silica sand (30165 grade). Finally, the conductor casing was completely
removed from the hole as the remainder of the hole was backfilled with neat Portland cement. Each well was completed with a flush-mount bolt-down cover.

Following completion of the well construction, the location and measuring point (top of casing) elevation of each well was surveyed by Glenn Price Surveying, of Dade City, Florida. Survey results are presented in Appendix A. Each well was then developed for at least one hour or until the water produced by the well had cleared as much as was possible. The wells were developed using an air-ift eductor pipe, and the discharged water was directed into a holding tank. The collected water was disposed in a site percolation pond settling basin as directed by PEF. After allowing the wells to recover for at least 24 hours, static water levels were collected from each well. Well construction details and initial static water levels are presented in Table 1. 7-

January 22, 2007 IEIH dy l (, LILC Progress Energy Florida - CR-3 Groundwater Flow Study Report 0 Table 1 - Groundwater Elevation Monitoring Well Construction Details S 0 Water Table 0 Well ID Measuring Point Total Depth Depth to Water Elevation 0 Elevation (ft bmp) (ft bmp) (ft NGVD29) (ft NGVD29) 1119106 1119106 0 CR3-IS 8.07 30.59 5.48 2.59 0 CR3-1D 8.23 68.29 5.24 2.99 0 CR3-2 8.25 29.99 5.63 2.62 0 CR3-3S 7.90 30.18 5.36 2.54 0 CR3-3D 8.62 78.74 6.18 2.44 CR3-4 9.05 30.23 6.95 2.10 0 CR3-5 9.08 30.14 7.89 1.19 0 CR3-6S 10.18 24.92 8.42 1.76 CR3-6D 10.22 75.39 8.94 1.28 CR3-7 8.87 30.22 7.18 1.69 CR3-8 10.51 29.34 8.98 1.53 CR3-9 9.96 28.57 9.33 0.63 CR3-*1 8.72 30.17 6.64 2.08 0 0 0 0 0 0 0 0 0 S 0 0 0 0 0 0 - 3-8 - S

4.0 GROUNDWATER LEVEL DATA COLLECTION 4.1 METHODOLOGY

*Because                  of the close proximity of the site to the tidally-influenced intake and discharge canals, it was hypothesized that the groundwater elevation data collected from the

monitoring wells would display some degree of tidal fluctuation in groundwater

*elevations                 over the course of a tidal cycle. In coastal areas affected by the action of
 *tides,              it is common to see such a fluctuation in groundwater levels within monitoring

wells. Because of this and several other factors it was decided to collect water levels in

 *the               wells for a minimum of 72 hours in order to have a higher likelihood of capturing

valid, easily interpreted groundwater elevation level data. Other factors pertinent to this decision include:- 1) the tidal cycle along the Gulf of Mexico in Florida is "mixed' (both diurnal and semi-diumal tides are experienced; in other words, some days have one 0

high and one low tide, while other days have two high and two low tides); 2) tidal ranges vary in amplitude throughout the month from about one-half foot to nearly three feet; and

3) tidal response in groundwater monitoring wells tends to decrease in magnitude, and increase in lag time, as one moves further from the coast. In order to adequately correlate the recorded groundwater elevations in the monitoring wells with actual tidal fluctuations, additional measuring points were established in the intake and outfall canals. Drop pipes were secured to the guard railing at one location along each of the two canals, and the location and elevation of the measuring points on the drop pipes were surveyed.

Each of the 13 new groundwater elevation monitoring wells, the two canal level monitoring drop pipes, and the 10 existing shallow monitoring wells were equipped with an InSitu, Inc. Hermit water level datalogger. Water depths (ft bmp) were measured with an electric water level tape immediately prior to installation of each datalogger, and were converted to elevation (ft NGVD29) for the initial programming of the datalogger, in this way, the water levels recorded by the dataloggers were direct readings of water level elevation (ft NGVD29). The dataloggers were set to record water levels for the period of approximately November 27 - December 1, 2006. Following the test period, the water levels were once again measured with an electric water level tape to verify that the data reference points had not drifted during the test. i 1 -

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January 22, 2007L Progress Energy Florida - CR-3 Groundwater Flow Study Report
4.2 DATA COLLECTION RESULTS
The groundwater elevation data collected from each of the monitoring wells and the tidal
elevation readings from the intakeldischarge canals were input into Excel spreadsheets for graphing. No data reduction or post-processing was required. A summary of the groundwater elevation data is presented as Table 2; graphs of the water level data are presented in Appendix B.

All of the data sets collected from the wells in the CR-3 area exhibit expected patterns of groundwater elevation fluctuation. Wells MW-1, MW-2R, MW-12R, and MW-21R exhibit

minor fluctuations in groundwater elevation; this is to be expected, as these wells are the
furthest from the tidal influence of the intake and discharge canals. Of all of the wells,
only well MW-7 exhibited unusual groundwater elevation data; the graph appears to "O indicate that well MW-7 is affected by periodic discharges of water to a surface collection

-* system near the well. For this reason, data from well MW-7 was not used in the - subsequent contouring of the recorded water levels.

4.3 GROUNDWATER LEVEL MAPPING & CONTOURING Each of the groundwater elevation datasets exhibited a sinuous curve when graphed.

Because of the dampening effect of the passage of the tidal pressure curve through the rock and soils of the aquifer, the response of the wells to tidal changes is not instantaneous. This results in a lag time in the elevation fluctuations within the wells with respect to the tidal changes in the intake/discharge canals. Additionally, tidal ranges (amplitude) vary throughout the monthly tidal cycle. The time period of November 28, 2006 (10:00 pm) through November 30, 2006 (4:00 pm) was chosen as the most stable portion of the tidal record, in which at least three complete tidal cycles (sequential high and low tides) exhibited nearly equal high and low measurements. The observed tidal range was from approximately -0.5 ft NGVD29 to +2.25 ft NGVD29. 2-

January 22. 2007 E1fLWhl]ydill(U)q ILLC Progress Energy Florida - CR-3 Groundwater Flow Study Report Table 2 - Groundwater Elevations (11128106 @ 22:00 - 11130106 @ 16:00) 0 0 Well ID Measuring Point High Level Low Level Average Level Elevation (ft NGVD29) (ft NGVD29) (ft NGVD29) (ft NGVD29) 0 TIDAL DATA 0 INTAKE 7.415 2.395 -0.723 0.838 0 DISCHARGE 6.142 2.365 -0.914 0.744 0 SHALLOW WELLS CR3-1S 8.065 2.999 2.550 2.758 0 CR3-2 8.252 2.568 2.102 2.321 CR3-3S 7.902 2.537 2.001 2.255 CR3-4 9.052 2.520 1.766. 2.127 0 CR3-5 9.082 2.234 0.901 1.558 CR3-6S 10.182 2.303 1.096 1.697 0 CR3-7 8.872 2.346 1.089 1.711 CR3-8 10.512 2.858 1.766 2.302 CR3-9 9.955 2.385 0.839 1.606 CR3-10 81715 2.458 1.578 2.005 0 MW-1 7.318 2.664 2.616 2.642 0 MW-2R 10.075 3.098 3.062 3.080 0 MW-12R 9.781 3.192 3.164 3.176 0 MW-16 13.998 2.025 0.465 1.248 MW-21R 10.392 3.104 3.064 3.084 MW-27 11.312 2.338 2.047 2.166 0 MW-28 8.218 2.256 1.602 1.917 0 MW-29 11.715 2660 1.381 1.899 0 MWIF-2 11.788 2.124 -0.087 0.980 0 DEEP WELLS 0 CR3-1D 8.225 2.364 1.883 2.110 0 CR3-3D 8622 2.521 1.973 2.232 CR3-6D 10.222 1.755 0.568 1.152 QUESTIONABLE WELLS MW-7 8.622 3.977 3.018 3M222 0 00 0

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0 January 22, 2007 E ~ d o ff( Progress Energy Florida - CR-3 Groundwater Flow Study Report 0

To investigate whether the groundwater flow direction changes throughout-the changing
tidal cycle, whether the deep zone of the aquifer exhibits different flow patterns than the
shallow zone and whether the observed groundwater flow patterns in the vicinity of the
CR-3 Facility are consistent with the groundwater flow patterns across the entire Crystal
River Energy Complex, multiple groundwater elevation maps were prepared for
comparison. Three sets (low, high, and average elevations) of groundwater elevation
contour maps were prepared each of the following sets of wells: 1) the shallow
monitoring well data in the vicinity of the CR-3 Facility; 2) the deep wells in the CR-3 area; and 3) for all of the shallow wells across the Complex.

The groundwater elevation data was imported into a SURFER dataset and used to produce contours maps of the groundwater elevations for each of the conditions described above (high, low, and average water levels). These contours were then overlaid on the base site maps, truncated in areas where the contour lines crossed the intake and discharge canals (assumed to be flat), and annotated with arrows depicting the approximate direction of groundwater flow. These maps are presented as Figures 6

 *  - 8 (site-wide high, low, and average shallow water levels), Figures 9 - 11 (CR-3 area high, low, and average shallow water levels), and Figures 12 - 14 (CR-3 area high, low, and average deep water levels).

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   -z         Approximate Direction of Groundwater Flow  1"=-300   1DATE: 01/22/07 DRAV*BY:OS FIGURE   9

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-~-=        Approximate Direction of Groundwater Flow 1  u"=300' DAT  01/2/07        .BY. S I

FIGURE~ 10 10 FIGURE

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      -::==       Approximate Direction of Groundwater Flow                 1"00 0AI~01/22/07 [DRAWN~ BY.DS             FIGURE   12

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B I ____________________________________________ Y PEF - Crystal River (2.999) Legend, Water Levels 11/28/06 0 22:00 through CR-3 Flow Study 11/30/06 0 16:00 (ft. NGVD) EnHydro, LLC Citrus County, Florida 2.6- Groundwater Contour 0 GEOLOGIST: CH CR-3 Area - Deep Wells

                                                        '"PRO)MTE =CAL.E Low Water Levels SApproximate    Direction of Groundwater Flow   1"=-300'       DATE 01/22/07   DRA'IN BY:DS            FIGURE  13

E I D (2.999) Water Levels 11/28/06 0 22:00 through 2.6-..-- 11/30/06 0 16:00 (ft. NGVD) Groundwater Contour ..... [EnHydro, LLC G',. = PEF - Crystal River CR-3 Flow Study Citrus County, Florida CR-3 Area - Deep Wells Average Water Levers eBY:os SApproximate Direction of Groundwater Flow 1"=300' DoAT: 01/22/07 IDRAVM FIGURE 14

January 22, 2007 EnHyd12 , LLC Progress Energy Florida - CR-3 Groundwater Flow Study Report

5.0 DISCUSSION
The shallow groundwater gradients across the Complex and in the immediate vicinity of
the CR-3 Facility are fairly consistent with the expected patterns, as are the deep
groundwater gradients beneath the CR-3 Facility. Groundwater flow is generally to the
west-southwest, with obvious discharge towards the intake and discharge canals. At the
locations of distant monitoring wells MW-1, MW-2R, MW-12r, and MW-21R the shallow
groundwater levels exhibit very little fluctuation (<0.1 ft) between high and low tidal stages. The groundwater elevations in the vicinity of the CR-3 Facility, however, exhibit as much as one foot of fluctuation. This situation indicates that the groundwater gradient 0 is not static; rather, the gradient is steepest at low tide conditions and flattest at high tide.

In the CR-3 area, groundwater mounding is observed in the vicinity of well CR3-8, especially at high tide conditions. This is to be expected, as well CR3-8 is located in an isolated, rather large (for the site) grassy area which is likely to receive much more direct fresh 4C recharge from rainfall (fresh water) over time than the nearby paved areas. This

water recharge is likely to form a "lens", or pocket of fresher water 'floating" on the
brackish native groundwater due to density differences. A similar phenomenon is
observed on islands, in which the rainfall recharge forms a distinct freshwater lens within the shallowest saturated zone of the aquifer (known as the Ghyben-Herzberg Effect).

The deep wells in the CR-3 area exhibit similar westward groundwater flow patterns as in the shallow zone of the aquifer. As only three wells were available for contouring, the contour lines and flow patterns inferred from the data are not as detailed as those in the

         -shallow zone where three times the number of data points were available. The data indicate a slight downward groundwater flow gradient from the shallow to the deeper zones of the aquifer, opposite of the gradient observed elsewhere in the area. This is likely a result of the previously-mentioned effects of the foundation grouting that took place prior to the construction of the CR-3 Facility; large amounts of solid cement in the shallow zone of the aquifer likely act as a dam, "backing up' or mounding the groundwater against the natural westward gradient and causing slightly increased groundwater levels above pre-construction conditions.

1 -

6.0 CONCLUSION

S

 *The                  primary objective of the Groundwater Flow Study was to generate sufficient data to
 *characterize                   the groundwater flow in the vicinity of the CR-3 Facility. Specific objectives
 *included:

0

Installation of a sufficient number of groundwater monitoring wells to adequately

  *characterize                          the groundwater flow regime in the vicinity of CR-3; 0    Collection of groundwater elevation data on a frequent enough interval and over a sufficiently long time period to conceptualize any fluctuations in the 0

groundwater flow regime as a result of the influence of tidal cycles in the adjacent intake and outfall canals; and

Preparation of groundwater elevation contour maps with groundwater flow

  *direction                         vectors depicting the groundwater flow regime in the study area.

The groundwater elevation data collected from the new and existing monitoring wells

  *was                  sufficient for the preparation of the required groundwater elevation contour maps.
  *Groundwater                     flows beneath the CR-3 Facility are generally to the west to west-
   *southwest                   in both the shallow and deep zones of the aquifer.          The short lag time obetween high and low tide levels and the high and low water elevation levels in the CR-3
   *area                wells (less than two hours, in the case of most of the downgradient wells) indicates

that the hydraulic conductivity of the aquifer is relatively high, possibly on the order of 1000 ft/day as indicated by earlier well testing in the area; this is ameliorated by the relatively low (< 3 ft) groundwater gradient in the area, which provides a low driving force on the groundwater flow. Groundwater tracer tests in the vicinity of the CR-3 Facility, however, would be the only way to obtain empirical measurements of the actual groundwater flow velocity in the study area.

Monitoring wells CR-5, CR-6S, CR-6D, CR-7, CR-B, and CR-9 are appropriate for long-term monitoring to detect the presence of any unknown release of water containing elevated levels of radioactive isotopes. In the absence of any other controls and monitoring programs, the potential relatively high transmissivity of the limestone in the 1 -

0 January22, 2007 MIiydI D, LLC Progress Energy Florida - CR-3 Groundwater Flow Study Report

Upper Floridan Aquifer and the associated rapid transit time of water within the aquifer
(due to the pervasive presence of small- to large-scale voids and channels within the
limestone) would make it prudent to sample the wells on at least a monthly basis to
ensure that a possible release of radioactive water to the intake/discharge canals does

*not           go undetected for an unacceptable length of time. However. in light of the leak
*detection            programs that PEF currently has in place (frequent walkdowns of equipment,

internal inspections of tanks, monitoring of tank levels, and other surveillances),

0quarterly sampling of the wells should be sufficient to supplement the existing leak detection monitoring programs at the CR-3 Facility. 0 0 Wells CR3-2, CR3-4 and CR3-10 should also be monitored on the same quarterly frequency as the aforementioned wells. for the purpose of background comparison. Sampling of the wells should be conducted by purging and sampling the wells following

*the            Florida Department of Environmental Protection's (FDEP'S) Standard Operating Procedures for the sampling of groundwater monitoring wells.

0 S 0 S S S S S S S S S S S S S 2 -

ProgressEnergy Florida- C stal River Power Plant Section 28, 32 & 33, Township I South, Range 16 East Citrus County, 1 lorida

                                           £    5 32 4.80 4N004' E444,

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ProgressEnergy Florida- CrystalRiver PowerPlant Section 28, 32 & 33, Township 17 South, Range 16 East Citrus County, Florida MW-i MfW-i MWIF-2 lii I AW7MW-U2 MW-16 IF T MW-29 InaeDicharge Q'a, A ACM I Glenn Price- Surveying -e,--,,4- I.- , I~I~JI~IZ,,He~..LLCI i//I-I fl-i Q~flM~4*F~flIPl4Ol

ProgressEnergy Florida- Crystal River Power Plant Section 28, 32 & 33, Township 17 South, Range 16 East Citrus County, Florida IV I o' R~li

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m M Barometric Pressure 30,25 30.2 30.15 E 30.1 30.05 30 11/28/06 11/28/06 11/29/06 11129/06 11/30/06 11/30/06 1211106 0:00 12/106 12J2106 0:00 11/27/06 11/27/06 0:00 12:00 0:00 12:00 0:00 12:00 0:00 12:00 12:00 w w V MW

INTAKE 4 3.5 3 2.5 2 da A, 1.5 2t 1 0.5 0

  -0.5 11127/06 11/27106 11/28/06 11/28/06  11/29/06   11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00   12:00     0:00    12:00      0:00      12:00     0:00     12:00                12:00

0 0 00 0 0 0 00 0 00 0 0 a 0 0 Discharge 4 3.5 3 2.5 2 1.5 1 0,5 0 -0.5 Y 44 -IT Iý . .... v5 I.. I IIll* l A v I n T mll* r vi I-4 11/27/06 11/27/06 11/28/06 11/28/06 11 i29/06 11/29/06 11/30/06 11/30/06 1211t06 0:00 12/1/06 1212106 0:00 0:00 12.00 0:00 12:00 0:00 12:00 0:00 12:00 12:00

CR3-IS 4 3.5 3 2.5 2 a z 1.5 1 0.5 0

 -0.5
   -1                                                        ~-        ~

11127/06 11/27/06 11/26/06 11/28/06 11/29/06 11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00 12:00 0:00 12:00 0:00 12:00 0:00 12:00 12:00

CR3-ID 4-3.5 . 3 2.5 1.5 0.5 0 -0.5 . 11/27/06 11/27/06 11/28/06 11/28/06 11/29/06 11/29/06 11/30/06 11130106 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00 12:00 0:00 12:00 0:00 I2:00 0:00 12:00

12:00

se 0046. oo-A104 S *OO**@o@@@S 0go 6-000..600 CR3-2 4 3.5 3 A Nk J40 Sk 2 l=1.5 0.5 0

 -0.5 "1

11/27/06 11/27/06 11/28/06 11/28/06 11/29/06 11129/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00 12:00 0:00 12:00 0:00 12:00 0:00 12:00 12:00

CR3-3S 4 3.5 3 2.5 2 YON,/ = 1.5 0.5 0

 -0.5
   -1 11/27/06 11/27/06  11/28/06 11/28/06 11/29106  11/29106 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00   12:00      0:00    12:00     0:00      12:00    0:00    12:00                 12:00

ooooo~ooo ooooo~esoosoooooooooogooO-R3

                              ~CR3-3D 4

3.5 3 2.5 2 ~1,5 0.5 0

-0.5
  -1 110227/06 11/27/06 11/28/06  11/28/06      11/29/06    11129106 11/30(06 11130/06 1211/06 0:00 12/1/05 12/2/06 0:00 0.:00    12:00     0:00     12:00          0:00        12:00    0:00    12:00                 12:00

000 **oooooooooooo*o A0600,6660669606069*66 CR3-4 4 3.5 3 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ v__ ___ _ _1____ 2.5 2 a 1.5 1 0.5 0

     -0.5
       -1 11/27/06 11/27/06     11/28/06      11/28/06 11/29/06       11/29/06        11/30/06        11/30/06 12/1/06 0:00  12/1/06 12/2/06 0:00 0:00    12:00          0:00        12:00     0:00           12:00            0:00           12:00                 12:00

CR~-5

'4 3.5 3

2.5 Alk 2 S1, 0.5 0 -0.5

 -1 11)27106 V1/27/06 11/28/06 11128/06  11/29/06  11129106 11/30/06 11130106 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00  12:00      0:00     12:00      0:00     12:00    0:00     12:00                12:00

CR3-6S 4 3.5 3 lift 2.5 2 1.5 I 0.5 0 -0.5

  -I 11/I, 27/06 11/27/06 11/28/06 11/28106 11/29/06   11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00    12:00     0:00      12:00     0:00    12:00                 12:00 0:00      12:00

0700 0 00 00 100"0 OO 0 O O0 I664 CR3-GD 4. 3.5 3 2.5 1. 0.5 0

 -0.5
        .I . . . .    ." . . .'                             .  . . .  . .    .  . . .  .  .  .   . . .  .

11/27/06 11/28/06 11/28/06 11129/06 11/29/06 11130/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 11/27/06 12:00 0:00 12:00 0:00 12:00 n'nn 19:?.no 1ini 0:00

CR3-7 3.5 3. 2.5 2AA A

                                        !v 0.5                       .........                                                            .

-0.5 " 11/27/06 11/27/06 11/28/06 11/28/06 11129/06 11/29106 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00 12:00 0:00 12:00 0:00 12:00 0:00 12:00 12:00

CR3-8 4 3.5 3 2.5 2 1 0.5 0 -0.5 11/27/06 11/27/06 11/28/06 11/28/06 11/29/06 11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00 12:00 0:00 12:00 0:00 12:00 0:00 12:00 12:00

CR3-9 4 3.5 3 2.5 2 g 1.5 I I X1 k/ k-v v 0.5 0

  -0.5
    -1 11/27/06 11/27/06 11/28/06 11/28/06  11/29/06  11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00   12:00     0:00    12:00      0:00     12:00     0:00    12:00                 12:00

CR3-l0 4 3.5 3 2.5 2 S1.5 v 1 0.5 0 -0.5

 -1 11/27/06 11/27/06 11/28/06 11/28/06 11/29/06  11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00    12:00     0:00    12:00     0:00     12:00     0:00    122:00                12:00

MW-I 4 3.5 3 2.5 2 ~1. 5 1 0.5 0

-0.5
  -1 11/27/06 11127/06 11/28/06 11/28/06 11/29106  11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00   12:00     0:00    12:00     0:00     12:00     0:00    12:00                 12:00

MW-2R 4.00 350 I 3.00 2.50 ......... 2.00_ c 1.50 1.00 . .... 0.50 -_____ 0.00.

 -0.50 11/27/06   11127106 11/28/06      11/28/06 11/29106    11/29/06 11/30/06 11/30/06 12/11060:00 12/1/06 12/2/06 0:00 12:00     0:00        12:00     0:00   12:O0                10.                 I 0:00       12:00    0:00

000 MW-7 3.5 4 3. 2.5. 2.

   ~1.5 1~

0.5

    -0 .5 11/27/06 11/27/06 11/28/06 11128106 11/29/06  11/29/06 11/30/06 11/30/06 12/1/06 0:00  1211/06 12/2/06 0:00 0:00   12:00     0:00    12:00     0:00     12:00      0:00   12:00                  12:00

MW-12R 4 3.5 3 2.5 2 S1.5 1 0.5 0

.0.5
  -1 11/28/06 11/28106 11129/06   11/29/06 11130106 11130/06 1211/06 0:00 1211/06 122MM 0:00 11127/06 11/27/06 0:00    12:00     0:00    12:00     0:00      12:00     0:00     12:00                12:00

0000 000000 000000*0000000000000 MW-l6 4 3.5 3 2.5 2 r1.5 1 IV 0.5 NOF 0 fF

  -0.5
     -1 11127/06 11/27106   11/28/06 1 128/06 11/29/06  11/29/06   11/30/06    11/30/06 12/1/06 0:00 12)1/06 12/2/06 0:00 0:00   12:00       0:00     12:00    0:00     12:00       0:00       12:00                 12:00

MW.21R 4 3.5 3 2.5 2

==1.5 1

   -0.5 0
  -04.5
                                                                ~IY1             7
     -1 11/27/06 11/27/06 11/28/06 11/28/06 11/29/06  11/29/06 11/30/06  11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00   12:00     0:00    12:00     0:00      12:00    0:00     12:00                 12:00

MW-27 4 3.5 3 2.5 2 Owl- 'Mooo-ol

1.5 1

0.5 0

   -0.5
     -1 11/27/06 11/27/06  11/28/06 11/28/06   11/29/06  11/29/06 11/30/06 11/30/06 12/1/06 0:00 12/1/06 12/2/06 0:00 0:00   12:00      0:00    12:00       0:00     12:00     0:00    12:00                 12:00

MW-28 4 3.5 3 2.5 2 = 1.5 0.5 0

-0.5
   .1 ! ,--~

11/27/06 11/27/06 11/28/06 11/28/06 11/29/06 11/29/06 11/30/06 11/30/06 1211106 0:00 12/1/06 1212/06 0:00 0:00 12:00 0:00 12:00 0:00 12:00 0:00 12:00 12:00

MW-29 4 3.5 3 2.5 2 IL 9 v = 1.5 0.5 0

 -0.5
   .1 11/27/06 11/27/06 11/28/06 11/28/06 11/29/06  11/29/06 11/30/05 11/30/06 12/1/06 0:00 12/1/06 1212106 0:00 0:00    12:00                 12:00 0:00   12:00     0:00    12:00     0:00     12:00

0o:U 00:U 00:0 o' 00,0 oo:z 00:0 00.ZL 00:0 00:0 90/Z"* , 904M1~ 00:0 9own? Moen~ 90IOC/IL L 0 90 vk C)z le 9Te Z'-IIMI

Hydrology H-9

1. A copy of reference SWEC, 1985 is provided in the response to AQ-3

2. It is not practical to reconstruct the Revision 29 version of the Final Safety Analysis Report (FSAR). A copy of the FSAR was provided in the CD submitted with the license renewal application. A copy of the Current version of the FSAR should be available from the NRC Crystal River 3 Project Manager.

Hydrology Additional Documents Requested

Hydrology Reference Request 1

1. Thermal Plume Assessment Plan of Study

                                                                                               -1f jProgress Energy VIA CERTITIED MAIL September 17, 2007 Mr. Bala Nori Florida Department of Environmental Protection 2600 Blair Stone Road Tallahassee, FL 32399-2400
        .Re:     Progress Energy Florida,. Inc. - Crystal River Units 1, 2, and. 3 NPDES Permit No. FLOOOO159 Thermal Plume Assessment Plan of Study

Dear Mr. Nori:

Enclosed please find three (3) copies of a draft biological evaluation plan of study (POS) for the Department's review. You'll recall that we agreed to defer submittal of the Crystal River Units 1,, 2, and 3 POS pending approval of the Bartow POS. The Bartow POS was subsequently approved by FDEP in late June of this year. If you or others within FDEP have questions concerning this information, please contact me at (727) 820-5410. Sincerely, David A. Bruzek Lead Environmental Specialist Progress Energy Florida, Inc. Progress Energy Florida, Inc,

E3 Cf,:) Se 'V,/ irO 0tj Tracking Summary Tracking Numbers Tracking Number. 3206 4734 374 Type: Package Status: Delivered Delivered On: 09/18/2007 9:40 A.M, Delivered To: TALLAHASSEE, FL, US Signed By: HERRING Service: NEXT DAY AIR Tracking results provided by UPS: 09/18/2007 11:32 A.M. ET NOTICE: UPS authorizes you to use UPS tracking systems solely to track shipments tendered by or for you to UPS for delivery and for no other purpose. Any other use of UPS tracking systems and information is strictly prohibited. Copv0 L~ a n D' V w oi0R00o"w D1,Exf'ms si~wrNel MýA C atsutei$ A.ia4 gttaa Cot it a aIr,. F] NUMA J206 473 437 4 71AýA -I V7A 1)AY W

t~~lC., J ___________It RERENCI-NUIOU Alillf nfigCtlfiPklI Ft 4t ata a 5 attaI.c~ ,n4 June Mooney PEF 903 Environmental, Health & Safety Services - POG ~ I St' 5ý Progress Energy Florida P;'O, Box 14042 7 St. Petersburg, FL 33733 fZ~L i" L aaaacaa ElY LiF]

                                                                                                                           -~a a"              L so a~AS~YS     UPSACOrNO CS t 4CRCpjzar CARfC              NO     tmjqýw'-)N - pl;.

UATY, Thaa) PARTY'5 COMPCANY NAMi Mr, Bala Nori FL Dept. of Environmental Protection ______________ C 'a'- Ct,) Cos ------- 1

                                                                   ~tCCt.

2600 BlairStone Road

LJ Os Tallahassee, FL 32399-2400 Of 5m~mmd '. meqto CMee CCCCC' Cti~ ait,ea'aSC Ad J)f.O S cwft--S-- X Itu P

                                                                                                       -1WeA        /ý-      dWI16d IIHI IlIIilIlil I til 1!1111     IIll                 818191128 1i87 S                                                       SH(PPER's COPY

PLAN OF STUDY FOR A THERMAL PLUME ASSESSMENT CRYSTAL RIVER UNITS 1, 2, and 3 CITRUS COUNTY, FLORIDA September 2007 Submitted by: Progress Energy Florida, Inc. 299 First Avenue North St. Petersburg, Florida. 33701

TABLE OF CONTENTS

1.0 INTRODUCTION

AND APPROACH 3 2.0 PLAN OF STUDY 5 2.1 Phase I - Monitoring to Determine the Spatial and Temporal Distribution of theCrystal River Plant Thermal Plume 5 2.1.1 Thermal Plume Delineation .5 2.1.2 Sampling Frequency 6 2.1.3 Environmental Measurements 6 2.1.4 Water Quality Assessment 6 2.1.5 Data Management 6 2.1.6 Data Analysis and Results 6 2.1.7 QA/QC Plan 7 2.1.8 Reporting Requirements 7 2.2 Phase 11- Conduct a Biological Assessment of Seagrass Beds and Benthic Macroinvertebrates Impacted From the Thermal Plume 7 2:2.1 Characterization of the Spatial Distribution of Seagrass Beds Likely Affected by the Thermal Plume 7 2.2.2 Characterization of the Benthic Community Potentially Affected by the Thermal Plume 7 LIST OF FIGURES Figure 1. Crystal River Plant Site Layout Figure 2. Proposed Sampling Locations Figure 3, Historical Thermal Plume Profiles 2

1.0 INTRODUCTION

AND APPROACH As part of the National Pollutant Discharge Elimination System (NPDES) permit for the Crystal River Units 1, 2, and 3, Progress Energy Florida, Inc. (PEF) is required to develop a Plan of Study (POS) in accordance with Rule 62-302.520(1), F.A.C. This plan shall be designed to determine any effects on biological communities from the thermal plume discharge to Crystal Bay. The POS .shall address monitoring of the thermal plume, submerged seagrasses, benthic macroinvertebrates, and shall include a proposed implementation schedule and reporting requirements. The POS shall identify data provided by other existing programs as well as any additional monitoring to be conducted by PEF as necessary. To understand how to characterize potential impacts to seagrass beds and benthic organisms exposed to the thermal release from the Crystal River Energy Complex, this plan of study is structured as a phased approach that will initially focus on determining and understanding the spatial and temporal distribution of the thermal plume under various environmental and plant operating conditions. Once the location of the plume has been established, (Phase I) it will then be possible to determine how and where to evaluate potential impacts to seagrass beds and benthic organisms exposed to the thermal plume (Phase I1). The Crystal River Energy Complex is located on an approximately 5,000 acre site near the Gulf of Mexico in Citrus County, Florida. The Complex is approximately 7.5 miles northwest of the City of Crystal River, within the coastal salt marsh of west central Florida (Figurel). The complex contains five electric generating units. Units .1 (400 MW) and 2 (500 MW) are coal-fired and Unit 3 (890 MW) is a nuclear-fueled electric generating plant located within the Complex. These three units utilize once-through condenser cooling and are authorized to discharge cooling water by NPDES permit No. FL0000159. Units 4 (640 MW) and 5 (640 MW) are coal-fired units and utilize closed cycle cooling with natural draft cooling towers. Unit 4 and.5 withdraw water for cooling tower makeup from the discharge canal of Units 1, 2, and 3. During certaintimes of the year (May 1 through October 31), once-through helper cooling towers are operated to reduce the thermal discharge from Units 1, 2, and 3. The helper cooling towers cool a portion of the heated water which has passed through the condensers from Units 1,2, 2and,3 and then discharge the cooled water back into the discharge canal. The helper cooling towers are operated as necessaryto ensure that the discharge temperature does not exceed the current permit maximum of 96,5 0 F as a three-hour rolling average at the point of discharge into the Gulf of Mexico. Source water for Units 1, 2, and 3 is withdrawn from a common canal located south of the units which extends into the Gulf of Mexico, a Class III marine water. NPDES Permit No. 0000159 authorizes the following for Crystal River Units 1, 2, and 3: Operation of an industrialwastewater treatment and disposal system to serve the referenced facility. The facility consists of two fossil-fueled units (Unit #1 and Unit #2) and a nuclear fuel-fired unit (Unit #3) The units have a combined daily flow of 1898 MGD and a total nameplate rating of 1854.8 MW. The facility discharge consists of once-through condenser cooling water, treated auxiliary cooing water; treated-sluice ash water, treated coal pile rainfall runoff, canal debris wash water, and treated non-radioactive wastes/radiationwaste. Treated effluent is discharged to the site discharge canal.thence to the Gulf of MexicO, a Class Ill marine water, and a wetland area of the Gulf of Mexico. The most recent study to evaluate the impact of the thermal plume at Crystal River was conducted in 1983 - 1984. As part of a 316 Demonstration, physical studies.were conducted in. Crystal Bay to collect data for hydrodynamic and hydrothermal modeling. The models were designed to characterize hydrodynamic conditions within the study area, and using that data, simulate the thermal discharge resulting from the operation of Crystal River. Units 1, 2, and .3 under various environmental conditions.

3

To provide comprehensive, synoptic thermal data, thermographs were .deployed at 51 near-surface stations throughout the study area. At 21 of these stations, thermographs were also deployed at subsurface stations for detection of stratification. Meteorological, bathymetric, current, and tide data were also collected in support of the hydro-dynamic modeling effort. Thermal plume delineation was accomplished during the study period under incoming and outgoing diurnal and semi-diurnal tide conditions. Sampling was conducted during August and January when the in situ study was in progress. Boat crews synoptically sampled four basins near the discharge point measuring conductivity and temperature searching for bottom separation of the thermal plume. The far-field modeling effort for Crystal River Energy Complexwas conducted with CAFE-i and DISPER-1, a pair of two-dimensional finite-element mathematical models developed at the Massachusetts Institute of Technology. The objectives of the far-field modeling were to determine the. far-field thermal plume configuration and determine the station effects on far-field meroplankton concentrations (source.water body analysis). The selection of a near-field model for the Crystal River Energy Complex was based upon an examination of the results of the thermal plume delineation surveys. No significant or consistent plume stratification could be detected due either to temperature or salinity. Thus, the near-field modeling was conducted utilizing a model which describes a plume uniformly distributed over the water depth. The results of the near-field model were used to modify the isotherm locations predicted by the far-field model. The far-field model supplied an approximate distribution to the average temperature in the region of the point of discharge and the near-field model provided the detailed distribution. Upon examination of the thermal plumes obtained from physical data collected, the only phases of the tide which exhibited any substantial near-field behavior were ebb tide and low water slack. Near field behavior was apparent by the existence of locally elongated isotherms which follow and enclose a jet emerging from the point of discharge. Furthermore, data supported the conclusion that heated water is primarily confined to the dredged discharge.canal throughout its length, especially at low tide levels. True near-field plume behayior did not begin until the discharge emerged from the channel into the bay (Figure 3). Thermal plume simulation results agreed well with results from the biological and water quality sampling portions of the 316 study. Basin 1, nearest the point of discharge was consistently exposed to water with temperature elevated 5- 8 C.. above ambient. On ebb or low slack tides, however, the largest:volume of the thermal discharge was confined to the dredged channel adjacent to the discharge spoil. The plume at that point tends toward the southwest, but rapidly becomes well mixed in the relatively shallow water. On floodor high tides, the plume effect is lacking as the discharge spreads quickly over more of the bay. Little variation was seen in the summer or winter cases. Simulations represented worst case, full load operation. Interpretation of the results was complicated by low salinity and sedimentation experienced in.Crystal Bay. Particularly with benthic communities, the effects of salinity and sedimentation are very similar to thermal effects, and this was demonstrated by faunal similarities observed between northern area stations and those in area affected by the thermal discharge. As a result of findings from this study, Florida Power Corporation reached a tentative agreement with the U. S. Environmental Protection Agency (EPA) and Florida Department of Environmental Regulation (FDER) in March 1988 outlining a 3-phased approach towards mitigating impacts from the once-.through cooling water system at Units 1, 2, and 3. FPC agreed to install helper cooling towers to reduce thermal impacts, construct and operate a multi-species fish hatchery to address impingement and entrainment impacts, and implement a 15% reduction in overall cooling water flow from November 1 through April to.further reduce impingement and entrainment impacts. 4

Four mechanical draft helper cooling towers designed to cool approximately one-half the condenser cooling water discharged from Crystal River Units 1, 2, and 3 were installed and began operation in 1993. The cooler tower discharge water is reintroduced and mixed in the discharge canal to achieve a three hour average maximum temperature of 96.5 OF at the point of discharge. 2.0 PLAN OF STUDY The objective of this POS is to assess the potential impacts of the thermal plume from current operation of Crystal River Units 1, 2, and 3 on submerged grasses, benthic macroinvertebrates, and other aquatic species, as appropriate. This POS is divided into the following phases and sections: 2.1 Monitoring to Determine the Spatial and Temporal Distribution of the Crystal River Enerqy Complex Thermal Plume The objective of this phase is to understand the spatial persistence and temporal distribution of the thermal plume as it relates to current plant operations and ambient environmental conditions. 2.1.1 Thermal Plum Delineation Earlier physical studies provided detailed near-field and far-field thermal plume simulations correlated with extensive physical data collected in and around Crystal Bay. A fairly accurate account of thermal plume spatial and temporal performance was determined from those studies. However, those studies were completed prior to the installation and operation of the helper cooling towers and the resulting NPDES permit condition of a maximum thermal discharge temperature of 96.5 0 F as a three-hour rolling average at the point of discharge into the Gulf of Mexico. This POS is designed to assess the spatial distribution of the thermal plume resulting from the operation of Crystal River Units 1, 2, and 3 and helper cooling towers. To map the spatial distribution of the thermal plume a total of 20 sampling stations will be synoptically. monitored twice monthly from April through October. Sampling station locations are-shown in Figure 2 and are based in part on expected plume trajectoriesfrom model simulations run during the previous 316.study. Exact station locations~will bedetermined during the first field effort using GPS. Station location is grid based to enhance statistical analysis and interpolation. Each synoptic survey will take place prior toslack water for both ebb and flood tidal cycles. Surface and bottom temperature, dissolved oxygen, and salinity measurements will be taken at each station. Secchi disc depth will be determined at each station as a measure of light penetration. If water depth at a sampling site is less than one meter, only surface (0.2m) measurements will be taken. To supplement the synoptic surveys three continuous recorders (datasonde) will be placed at key locations to measure temperature, dissolved oxygen, and salinity 24 hours prior to and after each synoptic survey. A fourth datasonde will be placed as a control south of Crystal Bay outside of the area influenced by the thermal plume. Datasondes will be suspended near the bottom through bottom anchoring and surface floats. The datasondes will be programmed to record data every 15 minutes. The datasondes will. provide.a continuous.record of temperature, salinity, and dissolved oxygen concentrations during each survey period for areas that are expected to be within the thermal plume, as Well as a control. The objective of this study will be to characterize the fate of the thermal plume under present plant operating conditions. The mapping effort will include the establishment of isotherms associated with the thermal plume. The gradient of thermal contours will provide data to establish areas within and outside of the thermal plume, allow comparison to previous modeling results, and dictate location of biological sampling stations. If conditions are encountered that indicate 5

the proposed stations will not allow an adequate delineation of the thermal plume, select stations will be moved or additional stations will be added for adequate temperature mapping. 2.1.2 Samplinq Frequency Synoptic surveys will be conducted twice monthly from April through October during slack low and high tides in order to collect data during worst case, full power demand conditions. This will provide information on the effect of plant operating conditions including worst case on the fate of the thermal plume. Sampling will begin just prior to a slack flood or ebb tide. It is anticipated that sampling will begin in the spring of 2008 pending approval of this POS by the FDEP. 2.1.3 Environmental Measurements Concurrent with each survey air temperature, wind speed, direction, rainfall, cloud cover and general weather conditions will be observed and recorded. Meteorological data will be obtained from the meteorological tower operated on the Crystal River Energy Complex site. Also, tide height data will-be recorded, and plant operational parameters will be collected foreach sampling event. 2.1.4 Water Quality Assessment In addition to synoptic water quality sampling (temperature, dissolved oxygen, and salinity), mid-depth water samples will be collected once per tidal cycle and once per month at five stations. These samples will be analyzed for dissolved organic carbon, ortho-phosphate, nitrate/nitrite, ammonia, and turbidity. Methods and holding times will follow appropriate 40 CFR Part 136 and FDEP SOP.guidelines.. Stations to be sampled for water quality parameters are shown in Figure 3. 2.1.5 Data Manaqement Field and laboratory data sheets will be used to record raw data. All. field data will be entered into an ACCESS database with identifiers of station, date, and depth to allow for full analysis of data. 2.1.6 Data Analysis and Results To determine the fate of the thermal plume under various plant and environmental conditions, data from April through October will be collected and analyzed. Isothermal contours will be generated for 1.0 0C.isotherms. Since previous studies indicated little vertical stratification, isotherms will be considered to be consistent throughout the water column. These isotherms will be compared to near-field isotherms generated during the 1985 316 Demonstration Study. With no significant changes in-hydrology or topography it may be possible to compare results from this study to prior conclusions. This will be determined as data.becomes available. The datasonde results will be used to provide information on temperature and dissolved oxygen concentrations at selected areas during periods that bracket the surveys. A comparison will be made between day and. night dissolved oxygen concentrations to assess any temperature-dissolved oxygen interactions. To supplement.the thermal plume mapping and assist in determining what additional studies, if any, will be required to evaluate the impact of the existing thermal plume on seagrass beds, available. GIS data and maps will be collected and layered With thermal plume. data. In addition, the isotherm mapping will provide data to identify if, and where, benthic sampling, should be conducted.to be representative of the various temperature contours, as welltas identify 6

background temperature areas for comparative purposes. It will also be used to assess the relevancy of the 1985 benthic studies to current isotherm distributions. 2.1.7 QA/QC Plan It is the policy of the EHSS Department to ensure that all biological activities (field, laboratory, and reporting) are accurate, complete, and repeatable. This policy is accomplished by developing a system of activities outlined in the EHSS Biology Program QA Manual. This manual includes both administrative and technical activities. Vendors performing biological studies for EHSS must comply with the criteria and guidance outlined in the QA manual. 2.1.8 Reporting Requirements Progress reports will be issued quarterly and will present thermal plume mapping information for temperature, salinity, and dissolved oxygen along with water quality information that is available. A final report will be prepared within 6 months of the last sampling to discuss the fate of the thermal plume, the assessment of potential biological impacts from available information and recommendations for Phase II sampling. 2.2 Phase II - Conduct a Biological Assessment of Seagrass Beds and Benthic Macroinvertebrates Impacted from the Thermal Plume 2.2.1 Characterization of the Spatial Distribution of Seaqrass Beds Likely Affected by the Thermal Plume The scope of this study will be deferred until the spatial and temporal extent of the thermal plume is defined and an appropYriate Plan of Study can be prepared and submitted to FDEP for approval. 2.2.2 Characterization of the Benthic Community Potentially Affected by the Thermal Plume The scope of this study will be deferred until the spatial and temporal extent of the thermal plume is~defined and an appropriate Plan of Study can be prepared and submitted to FDEP for approval. 7

9 0 Figure 3. Historical Thermal Plume Profiles

       'OVA
            = Datasonde Locations

1. Ba'e. CWJ fXO-hargo

                       ~LUt C      LXM C ET ER S                                  rIHiElIMAL PLUME~ $IMUILA 1 I0N
                                                                            ,sT -SUMAMER LOW WATER1 [LA-,

CRY"rAL R4IVER1 316 STUI)IES

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Hydrology Reference Request 4

1. Consumptive Water Use permit and Data (2 documents)

Southwest Florida 2379 Broad Street, Brooksville. Florida 34604-6899 WItteranragementDistrict (352) 796-7211 or 1-800-423-1476 (FL only) SUNCOM 628-4150 TDD only 1-800-231-6103 (FL only) On the Internet at: WaterMataers.org An teý Bartow Service Office Lecanto Service Office Sarasota Service Office Tampa Service Office 170 Century Boulovard Suite 226 6750 Fruroville Road 7601 Highway 301 North Bartow, iorida 33830-7700 3600 West Sovereign Path Sarasota, Florida 34240-9711 Tampa. Florida 33637-6759 (863) 534-1448 or Lecarito, RForda 34461-8070 (941) 377-3722 or (813) 985-7481 or 1-800-492-7862 FLonly) (352) 527-8131 1-800-320-3503 (FL onzy) 1-800-836-0797 (FL only) SUNCOM 572-6200 SUNCOM 531-6900 SUNCOM 578-2070 Judith C. Whitehead November 26, 2007 Chair, Hernando RECEIVED Neil Combee Vice Chair. Polk Todd Pressman DEC 0 4 2007 Secretary. Pinellas Bernie Cumbie Jennifer E. Clos*hey Florida Power Corporation, Progress Energy FL, Inc., and Environmental Services Treasurer, Hillsborough Crystal River South 'Unit 1; .2 and.3 Thomas G. Dabney 15760 West Power Line Road Sarasota Crystal River, FL 34428 Patricia M. Glass Manatee Heidi B. McCree Subject' Permit Transmittal Letter Hillsborough Individual Water Use Permit No. 20004695.004 Ronald E. Oalaey Pasco

Dear Mr. Cumbie:

Sallie Parks I Pinellas Marltza Rovira-Forino This Water Use Permit was approved by the District Governing Board subject to all terms and Hiltsborough conditions set forth in the approved Permit. Patsy C. Symons DeSoto Please be advised that the Governing Board has formulated a water shortage plan as referenced in Condition 4 of the Stan dard Water Use Permit Conditions and will implement such a plan during periods of water shortage. You will be notified during a declared water shortage of any change in David L Moore the conditionsof your Permit or any suspension of your Permit, or of any restriction on your use of Executive Director water for the duration of any declared water shortage.. William S. Biloeky General Counsel The ID tags foryour withdrawals shall be'installed by a District representative. This representative will attempt to contact.you within 30 days to discuss placement of your tags. If you have any questions or concerns regarding your tags, please contactSandy Semegen at extension 4349, in the Brooksville Regulation Department- If you have any questions or concerns regarding your permit or any other information, please.contact this office at extension 4360. Sincerely, Pau/ONeil, Jr., P.E., Department Director Regulation Performance Management PWO:jjm

Enclosures:

Approved Permit cc: File Of Record Patricia Garner, RE.M., ProgressEnergy Florida, Inc.

SOUTHWEST FLORIDA WATER MANAGEMENT DISTRICT WATER USE INDIVIDUAL PERMIT NO. 20004695.004 EXPIRATION DATE: November 26, 2017 I PERMIT ISSUE DATE. November 26, 2007 The. Permittee is responsible for submitting an application to renew this permit no sooner than one year prior to the expiration date, and no later than the end of the last business day before the expiration date, whether or not the Permittee receives.prior notification by mail. Failure to submit a renewal application prior to the expiration date and continuing to withdraw water after the expiration date is a violation of Chapter 373, Florida Statutes, and Chapter 40D-2, Florida Administrative Code, and may result in a monetary penalty and/or loss of the right to use the water. Issuance of arenewal of this permit is contingent upon District approval. TYPE OF APPLICATION: Renewal GRANTED TO: Florida Power Corporation, Progress Energy FL, ln6., and Crystal River.South Unit 1, 2 and 3 15760 West Power Line Road Crystal River, FL 34428 PROJECT NAME: Crystal River South Power Plant WATER USE CAUTION AREA: N!A PROPERTY LOCATION: 5,125.7 owned acres in Citrus County, approximately 3 miles westof Red Level. ABSTRACT: Thisis.a renewal for an existing water use.permit for cooling andother operational uses for power plant Units !, .2, and 3. The Annual Average quantity is .1,000,Q0Q gallons per day (gpd) and the Peak Month.quantity is 1,500,000 gpd. The quantities are based on historical usage and projected demands through the 10-year permit term. The permit includes Special Conditions that.require:monthly rejporting of metered pumpage, monthly reporting ,of water quality from District ID 4, monthly reporting,.of water levels from District 1I 7, capping of unused wells, submittal of a water, conservation report by October 1,2012, pumpage'distribution flexibility, and potential permit modification as a result of the.,ongoing site certification process. CHANGES:FROM PRIOR PERMIT: There are nochanges from the prior permit. Permit Information Staff Existing Requested. Recommendation 2007 2017 2017

  -Annual Average:   (gpd)                                         .. ___OOO___0_0_0 Ground Water                                 1,000,000            1,000,000                   1,600,000 Surface Water                                         0                     0:.                        0.

Peak Month (gpd)_ Ground Water 1,500,000 1,500,000 1,500,000 Surface Water 0 0 0 Population Served N./A N"A N/A

Permit No.. 20004695.004 Page 2 November 26 2007 Permit Information (continued) Staff Existing Requested Recommendation 2007 2017 2017 Annual Average Permitted Quantities N /A N/A N /A (gpd) ,. Imports (gpd) N/A N/ A N/A Exports (gpd) N/A N/A N/A Treatment Loss (gpd) N/A N/A N/A Gross Use (gpd) N/A N/ A N/A Gross Per Capita (gpd/person) N /A N /A N/A Adjustments: Significant Uses (gpd) N/A N/A N IA Environmental Mitigation (gpd) N /A N/A N/A Reclaimed Water Offsets *N /A N/A N/A Adjusted Gross Per Capita (gpdf/person) N /,A N./.A N /A Residential Use (gpd) N /A N/ A N/A Residential Per Capita (gpd/person) NI A N/A N/A Unaccounted Water Use (gpd): N /A N /A N/A Average. daily use during: the highest water use month. jFACILITY NAME:. Crystal River South Power Plant I SPECIAL CONDITIONS: All conditions referring to approval~by the Regulation Department Director, Resource Regulation,.shall refer tothe Director, Brooksville Regulation Department, Resource Regulation.

1. All reports and data required. by conditions of the permit shall be submitted'to the District according to, the due dates contained in thespecific,condition. If the report or data is received on or before the tenth day of the month following data coliection,.itshall be deemed as a timely submittal. The Permittee may use:the District's website.to submit data, plans or reports.online. To set up an account, the Permittee can address the request t6.permitdata@watermattets.org; All mailed reports and data are.to be sent to',

Permit' Data Section, Regulation Performance Management Department Southwest Florida Water Management District 2379 Broad Street Brooksville, Florida. 34604-6899 Submission oof. plans and re.ports: Unless submitted online or otherwiseindicated in. the special condition, the:original and two copie.s..of.each plan and report, such:as. conservation plans, environmentalanalyses, aquifer-test results, per capita annual reports, etc. are required.

Permit No.: 20004695.004 Page 3 November 26, 2007 Submission of data: Un!ess otherwise indicated in the special condition, an original (no copies) is required for data submittals such as crop report forms, meter readings and/or pumpage, rainfall, water level evapotranspiration, or water quality data.

2. The Permittee shall meter withdrawals from surface waters andfor the ground water resources, and meter readings from each withdrawal facility shall be recorded on a monthly basis within the last week of the month. The meter readings shall be reported to the Data Management Section, Regulation Performance Management Department on or before the tenth day of the following month. District~supplied scanning forms shall be used to submit the meter readings unless another arrangementfor submission of this data has been approved by the District. The following withdrawal facilities shall be metered:

Existing permitted withdrawal facilities shall continue to be metered with non-resettable, totalizing flow meters or other flow measuringdevices as approved by the Regulation Department Director, District ID Nos. 1, 2, 3, 4 and 5, Permittee.ID Nos. PW1A, PW1B, SPW3, SPW4 and SPW5 The meters shall adhere to the followingdescriptions and shall be installed or maintained as follows: A. The meters shall be non-resettable, totalizing flow meters that have a totalizer of sufficient magnitude to retain total gallon data for a minimum of the three highest consecutive months permitted quantities. If other measuring devices are proposed, prior to installation, approval.shall be obtained in writing from the Regulation Department Director. B. The Permittee shall report non-use on all metered standby withdrawal facilities on the scanning form or approvedalternative reporting method. C. If a metered Withdrawal facility is not used. duringany given month, the meter report shall be submitted to the District indicating the same meter reading as was submitted the previous month. D. The flow meters or other approved devices shall have and maintain an accuracy within five percent of the-actual flow as installed; E. Accuracy testing requirements: 1.. For newly metered wi thdrawal points, the flow meter installation shall be designed.for inline field access for meter accuracy testing.

2. The meters*hall betested.for accuracy on-site, as.instaIled, every five years beginnirg from the date of its installation for new-meters or from the date of initial issuance of this permit containing the metering condition with an accuracy test requirement for ex<isting meters.

3. The testing frequency will be decreased if the Permittee demonstrates to the satisfaction of the District that:a longer period of time for testing is warranted.

4. The test will be~accepted by the District only if performed by a: person knowledgeable in thetesting equipment used:

5. If the actual flowis fouund to be greater than 5%,different from the measured flow, within 30 days,,the Permittee shall have the meter re-calibrated, repaired, or replaced.,'whichever isý necessary. Documentation of thetest and a certificate .of-re-calibratibn, if applicable, .shall be submitted within 30 days of each test or re-calibration.

F_ The meter shall be installed according to the manufacturer's instructions for achieving accurate flow to the. specifications above; or it shall. be installed in a straight length of pipe"where there is at least.an upstream length equal to ten (10) times the dutside.pipe diameter: and a downstreamlength equal to 'two (2)

Permit No.: 20004695.004 Page 4 November 26, 2007 times the outside pipe diameter. Where there is not at least a length of ten diameters upstream available, flow straightening vanes shall be used in the upstream line. G. Broken or malfunctioning rneter:

1. If the meter or other flow measuring device malfunctions or breaks, the Permittee shall notify the District within 15 days of discovering the malfunction or breakage.

2. The meter must be replaced with a repaired or new meter, subject to the same specifications given above, within 30 days of the discovery.

3. If themeter is removed from the withdrawal point for any other reason, it shall be replaced with another meter having the same specifications given above, or-the meter shall be reinstalled within 30 days of its removal from the withdrawal. In either event, a fully functioning meter shall not be off the withdrawal point for more than 60 consecutive days.

H. While the meter is not. functioning correctly, the Permittee shall keep track of the total amount of time the withdrawal point was used for each month and multiply those minutes times the'pump capacity (in gallons per minute) for total gallons-The estimate of the. number of gallons used each month during that period shall be submitted on District.,scan ning forms and noted as estimated per instructions on the form. If the data is submitted by ahother approved, method, the fact that it is estimated must be indicated. The reason for the necessity to estimate purrpage shall be. reported With the estimate. In the event a new meter is installed to replace a broken meter, it and its installation shall meet the specifications of this condition. The permittee shall notify the District of the replacement with the first'submittal of meter readings from the new meter.

3. Any:Wells not in:use, and in which pumping equipment.is not installed' shall be capped or valved in a water tight manner in accordance'with:Subsection 62-532.500(3)(a)(4), FIA;C.

4. The quantities authorized.by this permit, include sufficient water for Crystal River Units 1,.

2, and 3. Unit3. is currently undergoing site ceartification through the Florida Department of Environmental Protection. If water quantities are authorized for Unit 3 through the site certification .process, thepermittee shall; within::30 days of the, site certification, apply to modify and reduce :the quantities authorized under this-water use permit, to the quantities required for only Units 1 and 2. .5. " Water quality samples shall be.collected.and analyzed for parameters, and frequency(ies) ,specified below. VWater quality samples from production wells shall be collected Whether or not the well is bseing used, unless infeasible. If sampling is infeasible, the Permittee shall .indicate the reason for not sampling on the water quality data form. Water quality samples shall be analyzed by. a. Department of Health and. Rehabilitative Services (DHRS) certified laboratory under Environmental Laboratory Certification General Category 1'. 'Ata minimum; water'quality.samples shall be collected after pumping the well at its normal rate for a pumping time specified in the table .below, or to a constant temperature,,pH, and conductivity. In addition, the Permittee~ssampling procedure shall follow the handling and.chain of custody procedures designated by the ,certified laboratory 'Which will .undertake analysis, Any varian ce in sampling and/or analytical methods shall have prior approval of the Reg'ulation Department Director, Re sourceRegulation. Reports of the anaIyses:shall be submitted to the.:Permit Data Section- Records. and Data Department, (using District forms) pn..onor bef6re the tenth day of the following moh.th, and shall include the signature of the authorized representative: and certification number of the certified laboratory which undertook the.ainalyses. The parameteis and frequency of sampling and analysis may be rmodified b.tthe Regulation Delpartmenet Diirectbr, :Resburce Regulation, as necessary to ensure:.the. protection of the resou'rce.

Permit No.: 20004695.004 Page 5 November 146, 2007 Water quality samples shall be collected based on the following timetable: Monthly Same week of each month Analyses shall be performed according to the procedures outlined in the current edition of Standard Methods for the Examination of Water and Wastewater by the American Public Health Association:-American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or Methods for Chemical Analyses of Water and Wastes by the US Environmental Protection Agency (EPA). 6, The average day, peak monthly, and maximum daily, if applicable, quantities for District ID Nos. 3; 4, and 5, Permittee ID Nos. SPW3, SPW4, and SPW5, shown below in the production withdrawal table are estimates based on historicland/or projected distribution of pumpage, and are for water use inventory and impact analysis purposes. The quantities, listed in the table for these individual sources are not intended to dictate the distribution of pumpage from the permitted sources. The Permittee may make adjustments in pumpage distribution as necessary up to 440,000 gallons per day (gpd) on and average basis and up to 570,000 gpd on a peak monthly basis forthe individual wells, so long as. adverse environmental impacts do not result and other conditions of this: Permit are complied with. In all cases, the total average annual daily withdrawal and the total peak monthly withdrawal are limited to the quantities set forth above..

7. The Permittee shall monitor water levels in the monitor well as.specified in the table below. Reports of the data shall b.e submitted to the Permit Data Section Records.and Data Department, in a form acceptable to the District, AIidata shall be referenced to National Geodetic Vertical Datum (NGVD). The frequency of water-level recording may be modified by the Regulation Departrnent Director, Resource Regulation,as necessary to.ensure the. protection of the iresoUrce.

District Permittee Latitude/ ALuifer[ Recordiing ID No0 ID No. Lon.itude _Frequency. 7 MONW 2857441823824 Floridan Daily Recording Frequency Recordina Time Continuous Recording Continuous hourly basis: The.maximum and minimum.of.the 24-hour values (continuous recording) for each day shail be calculated, and only the maximum and minimum values for each day shall be

       ,reported to the:Permit Data Section, Records and Data Department. The time and date.

that the water level is measured shall be repolteld with the data.

8. The Permittee shall continue: to carry out the provisions-of its water conservation plan:.

submittedwith the application for .the duration of this permit. The Permittee shall submit a progres-s report by October 1, 2012.

Permit No.: 20004695.004 Page 6 November 26, 2007 WITHDRAWAL POINT QUANTITY TABLE Water use from these withdrawal points are restricted to the quantities given below: L.D. NO. DEPTH PERMITTEE/ DIAM. TTL./CSD.FT. GALLONS PER DAY DISTRICT (IN.) (feet bls) USE AVERAGE PEAK MONTH PW1A /1 5 42 /42 1 25,000 37,500 PVW1B / 2 a 42/42 1 25,000 37,500 SPW3 /3 10 90/36 I 380,000 570,000 SPW4/4 10 125/37 1 285,000 427,500 SPW5 / 5 10 72/ UNK 1 285,000 427,500 I = Industrial WITHDRAWAL POINT LOCATION TABLE DISTRICT I.D. NO. LATITUDEILONGITUDE SECTIONITOWNSHIPIRANGE 1 285744.59/824156.39 33/17/16 2 .285743.30/824156.18 33/17/16 3 285735.96/823804.53 31/17/17 4 285736.05/823808.88 36/17/16 5 285735.75/823819.13 36/17/116 STANDARD CONDITIONS: The Permittee .reference shall comply as Exhibit "A.' and with madethea Standard. Conditions attachedhereto, incorporated herein by part hereof, Authori ,dignature SOUTHWEST FLORIDA WATER MANAGEMENT DISTRICT This permit, issued under.the provision of Chapter 373, Florida Statutes and Florida Administrative Code 40D-2, authorizes the Permittee to withdraw the quantities outlined above, and may require various activities to be performedby the Permittee as described in the permit, including.the Special.Conditions. This permit does not convey to the Permittee any property

rights.or. privileges other than those specified herein, nor relieve the Permittee from complying with. any applicable local government, state, or federal law, rule, or ordinance.

Permit No.: 20004695.004 Page 7 November '46, 2007 40D-2 Exhibit "A" WATER USE PERMITSTANDARD CONDITIONS If any of the statements in the application and in the supporting data are found to be untrue and inaccurate, or if the Permittee fails to comply with ai lof the provisions. of Chapter 373, F.S., Chapter 40D, or the conditions set forth herein, the Governing Board shall revoke this permit in accordance with Rule 40D-2.341, following notice and hearing.

2. This oermit is issued based on information provided by the Permittee demonstrating that the use of water is reasonable and beneficial, consistent With the public interest, and will not interfere with any existing legal use of water. If, during the term of the permit, it is determined by the District that the use is not reasonable and beneficial, in the public interest, or does impact an existing legal use of water, the Governing Board shall modify this permit or shall revoke this permit following notice and hearing.

3, The Permittee shall not deviate from any of the terms or conditions of this permit-without Written approval by the District.

4. In the event the District declares that a Water Shortage exists pursuant to Chapter 40D-21. the District shall alter, modify, or declare inactive all or parts of this permit as necessary to address the water shortage.

5. The District shall collect water samples from any withdrawal point listed in the:permit or shall require the Permittee to submit watersamples when the District determines there is a potential for adverse imnpacts to water quality,

6. The Permittee shall provide access:to an authorized District representative to enter the property at any reasonable time to inspect the facility and make environmental or hydrologic assessments.

The Permittee shall either accompany District staff onto the property or make provision for access onto the property.

7. Issuance of this permitdoes not exempt the permittee from any other District permitting requirements.

The Permittee shall cease or reduce surface water withdrawal as directed by the Di~trict if water levels in lakes fa!l below applicable minimum water level established in Chapter 40D.-8 or rates of flow in streams fall belowi the minimum levels.established in Chapter 40DM8,

9. The Permittee shall cease, or reduce withdrawal as directed by the District if water levels in.

aquifers fall below the minimum levels~established by the Governing Board. 10, The Permittee shall practice water conservation to increase the efficiency of transport, application, and use, as-well as to decrease waste and tOminimize runoff from the property. At such time as the Governing Board.adopts specific conseýrvation requirements. for the Permittee's water use classification, this permit shall be subject to those requirements .uponn otice and after a reasonable period for compliance.

11. The District may establish special regulations for'Water Use Caution Areas: At:such time as the Governing Board. adopts such provisions, this permnit shall be subject to them upon notice and after a reasonable period for compliance,

Permit No., 20004695,004 Page 8 November 26, 2007

12. The Permittee shall mitigate any adverse impact to existing legal uses caused by withdrawals.

When adverse impacts occur or are imminent, the District shall require the Permittee to mitigate the impacts. Adverse impacts include: A. A reduction in water levels which impairs the ability of the well to produce wateri B. Significant reduction in levels or flows in water bodies such as lakes, impoundments, wetlands, springs, streams or other watercourses; or C. Significant inducement of natural or manmade contaminants into a water supply or into a usable portion of any aquifer water body.

13. The Permittee shall mitigate any adverse impact to environmental features or offsite land uses as a result of withdrawals. When adverse impacts occur or are imminent, the District shall require the Permittee to mitigate the impacts. Adverse impacts include-A. Signi-ficant reduction in levels or flows in water bodies such as lakes, impoundments, wetlands, springs, streams or other watercourses; B. Sinkholes or subsidence caused by reduction in water levels, C. Damage to crops and other vegetation causing financial harm to the.owner; and D. Damage to the habitat of endangered or threatened species.

14. When necessary to analyze impacts to the water resource or existing users, the District shall require the Permittee to install flow metering or other measuring devices to record withdrawal quantities and submit the data to the District.

15, *A District identification tag shall be prominently displayed at each withdrawal point by permanently affixing the tag to the withdrawal facility.

16. Notwithstanding the provisions of Rule 40D-1.6,105, F.A.C., persons who wish to continue the water use permitted herein and 'Who have acquired ownership or legal control of permitted water withdrawal fabilities or the land on which the facilities are located must apply to transfer the permit to themselves within 45 days of acquiring ownership or legal control of the water withdrawal facilities or the land.

17. All permits issued pursuant to these Rules are contingent upomncontinued ownershipor legal control of all property on which pumps, wells, diversions or other water withdrawal facilities are located.

R. 08/08/2007

4C1ON

                    %                      ~
                                              .FloridaIDepartment of.                    fCharlie                       Grist Governor Environmental Protection                                            Jeff Kottkamp Lt. Governor SA.Bob                                                   Martinez Center P LORL                       .                           2600 Blair Stone Road                           Michael W. Sole

_____ _ -T Tallahassee, Florida 32399-2400 Secretary August 7, 2008

                                 - CERTIFIED MAIL - RETURN RECEIPT REQUESTED -

Mr. Michael Shrader Lead Environmental Specialist Progress Energy Florida, Inc. St. Petersburg, FL 33733 RE: Crystal River Energy Complex Modification to Conditions of Certification DEP Case Number PA 77-09L OGC Case Number 08-0597 FINAL ORDER MODIFYING CONDITIONS OF CERTIFICATION

Dear Mr. Shrader:

The Florida Pollution Control Board issued the Site Certification for the Progress Energy Florida's (PEF) Crystal River Units 4 and 5 on November 21, 1978. This certification authorized the construction and operation of two 640 MW coal-fire power plant units (Units 4 and 5) and ancillary facilities. The Department of Environmental Protection (Department) has modified the Conditions of Certification by Final Order on eleven other occasions by final orders. The Department has reviewed PEF's petition dated April 3, 2008 for modification to the Conditions of Certification. The Department has also initiated additional modifications. Pursuant to 403.516 (1) (c), Florida Statutes ("F.S."), the Department may modify the terms and conditions of a site Certification upon its own initiative. On or before June 9, 2008, all parties to the certification proceeding were provided with notice by certified mail of the Department's intent to modify the Conditions of Certification for this facility, along with a copy of the proposed Order Modifying Conditions of Certification. On June 27, 2008, notice of the Department's intent to modify the Conditions of Certification for this facility was published on the Florida Administrative Weekly (FAW). Pursuant to Section 403.516, Florida Statutes ("F.S."), and Rule 62-17.211, Florida Administrative Code ("F.A.C."), all parties to the certification proceeding have 45 days from the issuance of notice by mail to such party's last address of record in which to file a written objection to the modification; that any person who is not already a party to the certification proceeding and whose substantial interests will be affected by the requested modification has 30 days from the date of publication of the public notice in the Florida Administrative Weekly to object in writing; that failure to act within the time frame constitutes a waiver of the right to' become a party; and that the Department will issue an Order Modifying the Conditions of Certification for this facility if no written objections are received by the Department. No objections to the modification have been received by the Department. The Conditions of Certification for the Crystal River Units 4 and 5 are hereby modified as follows: General No Change OSpecial "More Protection, Less Process" www. dep.stateft.us

I. No change. II. Water Discharges A. No change. B. Water Monitoring Programs

1. No change

2. Groundwater Monitoring

a. No change

b. The groundwater monitoring program shall be implemented at least one year prior to operation of Crystal River No. 4. The chemical analyses shall be in accord with the latest edition of StandardMethods for the Analysis of Water and Wastewater. The data shall be submitted within 30 days of collection/analysis to the Southwest Florida Water Management District (SWFWMD) and to the DPR DEP Southwest District Office.

c.. No change C. through D. No Change III. Southwest Florida Water Manaizement District (SWvFWMD)- Groundwater A. Gen"ra The use of gr-eundwater- from a linear well field for-plant scr.'ice water-fer-Units 4 and 5 shall be m~inimfized to the greatest extent pr-aeticable, but in no case shall excseed 3 mgd an a m-axim-um-daily basis from any new wells or-1.0 mgd on an average annual basis. B. Well C-riterift The submissien cf well logs and test results and lecatien, design and constructionl o wells to provide plant sern'iee water-shall be in accordac-me With applieable-rules ofthe Department Af Envirenmental Regulation and the cut~hwest Flor-ida Watcer Management Distr~ict (SWFIAMD). Total water use per-month shall be reported menthly to SVXNWAD commencing ~With the stait of censtructi on.

r. WPMl W-thdr-Awnl I omitk T'%T'*T'* ? - +/-1-- -* 1

1 - -

tc m-a-eR A-60emplined aver-age a-;;;;ula-I ;wtnarfawa if ci 91910,19,01 eaffel

                                                                               ........ 1 ___.'tl--I ....... 1 -£1 t*/*t'* /*t't/'t ---- 11--*---

fr4i~ Is; autnRzEWH eccmIncal Witnlarawa r-ate not ex I ".1 Q-uuu-uuu gaaiins AUrmal a Slinale o water ner-da ZWith a maximu4m o . ^ 3.0a day. Withdrawals may be made from a linear-well field consisting ot up to seven (7),wells whose-lecations afe or-eser-ibed in the table below10. WITHDPRAWVAL POIN GALLONS P~ER DAYL PEF Well No. LATITUDE LONCITUDE MAXIMUM AVERAGE P-W-4 29-4q-36 82 37 49S 74 ý00 45 9-,-7 P-W4 2&-3q-36 82 3712 756-O 4-54,*4 PV329--57-36 8*2 37 36 q56;000 459-,g*, P-W-4 2_ _ _ __3692-4q40 7-561O0 459-,3-7,, P)"4 28-57-46 S2-37--44 2,6,* 0 ....- PW-6 289-57--36 82 37 !8 7&6-00 PCm--b- 2Mai5mum 82 37 13 7-56,000* PEF CR MOD L PA 77-09L Final Order Page 2 of 16

             *Wells    PW 5, PW 6, and PW :7 are, not. in curr ent use and shallkonly be used in emer-gencey situations. if mor-ea th;an the existinig four-wells are placed into. opcr~atiote te aeage wit*hdrvA~awa rateý limit for-eacah 'wel4wil def-ault to 262,500 GED.

D. Water Use Re0teF010H Said-'N vaterv is restricted to uses other: than main steamfeenaen sing. Any chhnge in the use d f ;A , ý11 A.A. or W FeEm Fe a E) tat ____ ___ t7TI. E.Emer-gency Shortages heevntan emer-gency water shoflage should be declafed pursuant to Sectio 373.1:75 In or- 373 .246, P.S., by Southwest Florida Water-Manageffient District, for an area including the location ot these withdrawal points, the Depanment, pursuanAt to Sectioni 103.5 16, F. S., may alter, modit', or-declare to be inactive, all or pafls of Special Condition MI.A4G. An -author-izedWater. Management District reprcsentativc, at aniy r-easonable timet, myetrheproepeft; to inspect the facilities. F. Monitorming and Reportingý PREP shall, within the time limits her-einafter set fofth, complete the following items, and if it fails to complete them by the specified time, then Special Condition 1-1-.A G; sh-all -auto-matically become nul~l And void.

1. PEP shall install and continuouisly maintain totalizing flow measuirement devices on withdrawail point(s) as listed. Said devices shall have and maintain an accuracy within five perceent oa the aemual flow under the installed operating conditions.

Licen~see, shalntift' the Distr-ict upon completionf of new installation prior to commencement of withdra-wal. Alterna.tive -flo~wmeasuring systems may be substituted upon wriffen approval by the Dirvetor of the Regulatog', Division of SWFWMTh in adv.anse of installation.

2. P-EF sh-all sub-mit to SWPWMVND, of fonns available from the District, a recred of pumpage foar each meter installed in F. 1. above. Said pumpage shall be proevided cn a monthly basis.

Repofls will be sent to: Chief-, Proceessinig and Records Sout~hvest Florida Water Management District

                                         § 5060 U.S. Highway 411, South Brooeksville, Flor-ida 33512

3. PEF shall matintain and operate eontinuotus water level r-ecorders on wells M4Z 21, M4Z 2D, and PW 7 located at Progr-ess Ener-gy PFloida pump test site. in Citrus_ Cout', Florida. PEP shall manually mfeasurfe water-levels monthly in wells M4Z 2S, MZ i S, M4Z 1I and M4Z i D. Detailed hydroegraphs of water- level fluemuations shall be constructed with the data collected from the water level recorder-s and shall be submifted to SX'.X'TALD monfthl.

4. Water quality canaysis shall be pefr-fored of water-withdr-awn from each preodution well and from wells MZ ;21- an;d-MZ 2DW. The water- samples coellected from each of theI repfe,_rencet~d wells shall be collected immediately after-removal by pumping of a quantit' of'water equýal to two casing volumes. The 'water qutalitý' analyses shall be perfoeffed montnhly dur-ing the first year-of operation, four-times (Januar-y, May, September- and December-) dur-ing the second year-and twice each ye~ar (May and September) ther-eafter. Results shall be submitted to SWVATVhD by the fifteenth (15th) day of the month follc'wing the month during 'which sucah analyses 'were perfor-med. Testing for the follo'wing constituents is r-equired:

CAICalIium M.agnesium 'Sodium PEP CR MOD L PA 77-09L Final Order Page 3 of 16

Potassium Bicar-bonate Sulfate Chloride Nirt Total1 Dissolved Solid Spec~ific Conductance Groess Alpha Radiation Total Phosphate Radium 226 (only if gro~ss Alpha is greater-than 15 pci/i)/

5. in the event that SXXTFWM4D determines there is a significant change in the water' quality, the Depaiflment pur-suanitto Section 103.5 16, F.S., mnay r-eguircthe Licensee to reduae orces withdf-awal from these groundwater- sources-.

G. Minimum Water-Level Restrictions

                    . .The Department and SWWM4D ma"., at a ffiture dlate pursui; tto Section 403.5 16, F.S.,4 w .ra.a.,.......+.....                   . .  .............             ... ---.-... ..........-       -   -........        ...   .

withdrawals, which may r-equtire PEF to r-educe or-cease withdr-awal froma these groundwater sourcees at times w'hen water levels fall belo.w, these minimums. H. Leachate

1. Comnpliance Leachate from the as;,h la-ndfill, coal storage piles, plant drainis coallecetion pondA, canal retention system and ditches shall not contaminat w atrofthe State (inceludinig both sur-face and gr-oundwatrs) in excess of the limitations of Chapter 17 3, FAC.

2. Menitoring A menitor-ing well system shall be used, cen ith operation, to determine ;vhether or- not leac-hate -fromthe plant dr-ains collecation pond, canRals, ditches, the ash landfill and coal pile is reaching the groeundwater in violation of Chapter 17 3. The Licensee shall keep a

'monthly r-ecord of the monitor-ing results and shall notif' the Southwest districtA Office of the Department and the Sout*hwest Florida Watgr. Manoagement DistriK+ct+. when. ;said measu.r.em.ents exceed water quality standars. A quarter"ly summaT' of the.results of mnitoring s be provided to the Sot*hwest District Manager. The proposed menitoring wla bc submi.ted to the Dcpai*nment for approval pfieo-toinstallation.

3. C effective Action NVhen the leachate monitoring system indicates to the Depafment violation otf the groundwater quality standards of Chapter- 17 3, FAC, the appropr-iate ditches, pond, ash landfill, or coal pile shall be sealed, rolocated or- closed, or: the operation of the affected facility shall be altered in sham-anner as to assure the Department that no s~ignificant eontsm-ination4 of the gr-oundwater: will oeeew.

A. Withdrawal Quantities and Facilities District ID/Owner ID Water Allocation Average Well CasinE/Depth Gallons per Day Feet STATUS 1/PW-1 250,000 35/200 EXISTING 2/PW-2 250,000 47/200 EXISTING 3/PW-3 250, 60/200 EXISTING 4/PW-4 250,000 41/200 EXISTING 5/PW-5 521,520 35/200 EXISTING 6/PW-6 521,520 50/200 EXISTING 7/PW-7 521,520 50/200 EXISTING 14/PW-8 521,520 50/200 PROPOSED 15/PW-9a 521,520 50/200 PROPOSED PEF CR MOD L PA 77-09L Final Order Page 4 of 16

         .16/PW-10a                                521,520                               50/200        PROPOSED Total All Wells                             4,309,000 B.          Submit Reports/Data All reports and data required by these conditions of certification shall be submitted to the SWFWMD according to the due dates contained in the specific condition. If the report or data is received on or before the tenth day of the month following data collection, it shall be deemedas a timely submittal.

The Licensee may use the SWFWMD's website to submit data, plans or reports online. To set up an account, the Licensee can address the request to permitdata(a2watermatters.org. All mailed reports and data are to be sent to: Permit Data Section, Regulation Performance Management Department Southwest Florida Water Management SWFWMD 2379 Broad Street Brooksville, Florida 34604-6899 Submission on plans and reports: Unless submitted online or otherwise indicated in the special condition, the original and two copies of each plan and report required herein; Submission of Data: Unless submitted online or otherwise indicated in the special Ar rfrvifl~c*;-'l (nannna,* , rlroA f^r Act, c.lrn,ýttclc cnnh cc rtcr -r,1/-A/ r...nnc r nmncn A rainfall, water level, evapotranspiration, or water quality data. C. Environmental Impacts, Monitoring, and Mitigation: Environmental Assessment

1. Environmental Monitoring Plan Licensee shall submit an Environmental Monitoring Plan for SWFWMD review and approval within 90 days of conditions of certification issuance. The monitoring plan, at a minimum shall utilize the SWFWMD's Wetland Assessment Procedure to evaluate the relative condition of surface waters and wetlands in areas affected by water withdrawals of Licensee. Upon SWFWMD approval, the plan shall be implemented and monitoring reports shall be provided in the annual monitoring report required by Condition No. C.6. After two years of monitoring following groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, the Licensee may request the SWFWMD release the Licensee from monitoring. If the SWFWMD concurs with the request, the SWFWMD will request DEP modify the conditions of certification to remove the monitoring condition.

2. Data Collection:

Licensee shall maintain and monitor the environmental monitoring sites included in the approved monitoring plan. Water levels for monitor wells and staff gauges for the sites included in the monitoring plan shall be referenced to National Geodetic Vertical Datum (NGVD) and reported in a form acceptable to the SWFWMD by the 10th day of each month for the preceding month. The time and date that the elevation is taken shall be included. Any changes to the methods or frequency of monitoring for any of these data collection programs must be approved by the SWFWMD.

3. Licensee shall install and thereafter maintain SWFWMD-approved staff gauges and shall report measurements of water levels, as indicated in the monitoring plan. Water levels shall'be' recorded and reported to the SWFWMD on or before the tenth day of the following month. To the maximum extent possible, water levels shall be recorded as indicated in the monitoring plan. The frequency of recording may be modified by the SWFWMD as necessary to ensure protection of the resource.

PEF CR MOD L PA 77-09L Final Order Page 5 of 16

4. Licensee shall maintain a continuous recording rain gauge within the area. Total.

daily rainfall shall be recorded at this station and submitted to the SWFWMD (on SWFWMD forms or on line) on or before the tenth day of the following month. The reporting period for these data shall begin on the first day of each month and end on the last day of each month.

5. Licensee shall monitor water levels in the monitor wells and piezometers as specified in the monitoring plan. Reports of the data shall be submitted to the SWFWMD in a form acceptable to the SWFWMD. All data shall be referenced to NGVD. The frequency of water-level recording may be modified by the SWFWMD as necessary to ensure the protection of the resource.

6. Annual Environmental Monitoring Reports Licensee shall submit an annual environmental monitoring data summary by January 1st of each year for the preceding water year (October 1 - September 30). The Annual Monitoring Report shall include all raw data, essential graphs, tables, and text. Monitoring progress at each site shall be summarized in the Annual Monitoring Report, as specified below. Licensee shall submit three copies of the Annual Monitoring Report each year. Interpretive reports of wellfield environmental conditions shall incorporate all environmental monitoring sites used. The Annual Monitoring Report shall assess relationships between water level fluctuations, well pumpage, atmospheric conditions, anddrainage factors related to the environmental condition of the wetlands and surface waters in the vicinity of the conditions of certification area. Pumpage data, wetland, water level data collected from the aquifer and for the region, and environmental parameters collected at the wellfield and in the region shall be used for the report results. Statistical trend analysis, such as double-mass curve analysis, multiple linear regression, time series analysis and/or factor analysis shall be performed to analyze the interactions of rainfall and pumpage on surficial water levels, potentiometric levels in the semi-confined aquifers, surface waters, and wetland water levels, rate of soil subsidence, and evidence of vegetational succession.

Data shall be obtained through field measurements and aerial photo interpretation. A brief summary of any recommended changes to the monitoring requirements shall be provided. D. Alternative Water Supply Implementation The Licensee shall investigate the development of one or more alternative water supply projects to supply the water supply demands to offset all or a portion of the groundwater allocated by these conditions of certification. Alternative water supplies include seawater desalination, brackish surface or ground water, water that has been reclaimed after one or more uses, stormwater, and any other water supply source designated as non-traditional for a water supply planning region in the applicable' regional water supply plan. Unless the Environmental Monitoring specified in Condition 2. above and the aquifer performance testing indicate that adverse environmental impacts are not occurring and are not predicted to occur, the Licensee shall either mitigate impacts in accordance with a plan accepted by the SWFWMD, or, select and implement an alternative water supply proiect, in accordance with the following schedule:

1. Within 6 months of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, the Licensee shall submit for SWFWMD approval, an Alternative Water Supply Plan. The Alternative Water Supply Plan shall evaluate, identify, and propose alternative water supply development of at least three-million two hundred thousand (3,200,000) gallons per day (gpd).

2. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, Licensee shall submit to SWFWMD, a preliminary design of the approved alternative water supply project that the Licensee will implement.

3. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included ina this site certification, the PEF CR MOD L PA 77-09L Final Order Page 6 of 16

Licensee shall provide an analysis of environmental conditions as specified in Condition C. above. If SWFWMD determines that adverse environmental impacts are not occurring and not predicted to occur, the Licensee may seek an extension of time or waiver for implementing the alternative water supply project. If SWFWMID determines that adverse environmental impacts are occurring or are predicted to occur, the alternative water supply project schedule must be maintained. If adverse environmental impacts are occurring or predicted to occur, the alternative water supply quantity required to be developed will be determined based upon a revised hydrogeologic evaluation performed by the Licensee and accepted by SWFWMD.

4. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, submit to the Florida Department of Environmental Protection and SWFWMD, applications for authorization to develop and use at least 3,200,000 gpd of water from the proiect as appropriate, unless an extension of time or waiver has been granted by SWFWMD.

5. Within 2 years of groundwater use rising to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, submit to SWFWMD an alternative water supply implementation schedule detailing the dates when construction will begin and end, and the date when water will be delivered from the project for use by the Licensee. In no event shall the time when water is supplied by the project be more than more than 4 years after groundwater use has risen to more than 3 million gallons per day (average annual daily withdrawal quantity) from all the wells included in this site certification, unless an extension of time for just cause or otherwise modified in writing by SWFWMD has been granted by SWFWMD.

6. Compliance with the Alternative Water Supply Implementation Schedule is required by the Licensee, unless extended or otherwise modified in writing by SWFWMD. Each year, by March 1, after the water use triggers described above, the Licensee shall submit to SWFWMD a status report describing the progress made on the Alternative Water Supply Implementation Schedule, including the specific actions taken to meet the requirements set forth above. If the project has fallen behind schedule, Licensee shall provide Just cause for the delay and/or explain how the Licensee will comply with the schedule described herein.

E. Compliance Reporting The Licensee shall submit a compliance report beginning January 28, 2013 and at 5 year intervals after the issuance date of these conditions of certification. The report must contain sufficient, information to demonstrate reasonable assurance that the withdrawals and use of water authorized by these conditions of certification continue to meet the substantive requirements set forth in Chapter 40D-2, F.A.C., and SWFWMD's Water Use Permit Information Manual Part B, Basis of Review. The compliance report must include:

1. Information documenting water demands and updated demand projections demonstrating that allocations from all sources in the conditions of certification will continue to be needed for the remainder of the conditions of certification duration:

2. Documentation verifying that the sources are capable of supplying the needs authorized by these conditions of certification without causing harm to water and water-related resources:

3. Documentation verifying that the use of water is efficient and that the Licensee is implementing all feasible water conservation measures;

4. An updated ground water modeling analysis and data analysis demonstrating that the use of groundwater does not interfere with legal uses existing at the time of issuance of this p modification of the conditions of certification; PEF CR MOD L PA 77-09L Final Order Page 7 of 16

5. An updated ground water modeling analysis, along with statistical analyses of water-level and wetland monitoring data, demonstrating that the use does not cause adverse impacts to wetlands, and surface waters, or violations of MFLs;

6. Documentation that ground water withdrawals by the Licensee are not causing or contributing to significant saltwater intrusion, including but not limited to review and statistical analyses of groundwater level and water quality data collected by the Licensee under these conditions of certification;

7. Information demonstrating that the lowest quality source of water is being used to meet the water demands.

Following review of this report, SWFWMD may seek modification of the conditions of certification to ensure that the use continues to meet the substantive conditions for the consumptive use of water as set forth in Section 373.223, F.S., and Chapter 40D-2, F.A.C. F. Pumpage Reporting Licensee shall meter withdrawals and record meter readings from each withdrawal point and water supply line on a monthly basis within the last week of the month. The meter readings shall be reported to the SWFWMD on or before the tenth day of the following month. If a metered withdrawal is not utilized during a given month, the meter report shall be submitted to the SWFWMD indicating the same meter reading as was submitted the previous month. The following withdrawals shall be metered: Withdrawal facilities that are not yet constructed shall install meters on SWFWMD ID Nos. 5. 6. 7. 14. 15. 16. Licensee ID Nos. PW-5. PW-6. PW-7, PW-8. PW-9a. PW-10a, within 90 days of completion of construction of the withdrawal facilities. Licensee shall continue to maintain and operate existing, non-resettable, totalizing flow meters or other flow measuring devices as approved by the Brooksville Regulation Department Director on SWFWMD ID Nos. 1. 2. 3. 4. Licensee ID Nos. PW-1. PW-2. PW-3. PW-4. All meters shall adlhere to the following descriptions and shall be installed and maintained as follows:

1. The meters shall be non-resettable, totalizing flow meters with totalizers of sufficient capacity to retain total gallon data for a minimum of the three highest consecutive months. If other measuring devices or other accounting methods are proposed, Licensee shall submit documentation that the other measuring devices or accounting method meet the stipulations listed in this condition, prior to installation. Approval for other measuring devices or accounting methods shall be obtained in writing from the Brooksville Regulation Department Director.

2. Flow meters or other approved devices shall have and maintain accuracy within five percent of the actual flow as installed.

3. The flow meter-water piping system shall be designed for inline field access for meter accuracy testing. The meter shall be tested for accuracy on-site, as installed, every five years beginning from the date of its installation for new meters or from the date of initial issuance of these conditions of certification containing the metering condition with an accuracy-test requirement for existing meters, unless Licensee submits documentation to the satisfaction of the SWFWMD that a longer period of time for testing is warranted. The test shall be performed by a person certified to use the test equipment. If the actual flow is found to be greater than five percent different from the measured flo,*>

within 30 days, Licensee shall have the meter re- calibrated, repaired, or replaced. Documentation of the test and a certificate of re-calibration, if applicable, shall be submitted within 30 days of each test or recalibration. If the accounting method involves a meter belonging to another entity or to the water supplier, Licensee shall submit documentation from the owner/ supplier that the meter readings continue to be accurate to five percent of the actual flow as installed. Such documentation is subject to approval by the SFWMD. PEF CR MOD L PA 77-09L Final Order Page 8 of 16

4. The meter shall be installed according to the manufacturer's instructions for achieving accurate flow to the specifications above, or it shall be installed in a straight length of pipe with at least an upstream length equal to ten times the outside pipe diameter and a downstream length equal to two times the outside pipe diameter. If sufficient pipe length is not available, flow straightening vanes shall be used in the upstream line.

5. If the meter or other flow measuring device malfunctions or has to be removed from the water supply line for maintenance or repair, Licensee shall notify the SWFWMD within 30 days of discovery and replace it with a repaired or new meter, subject to the same specifications given above.

The repaired or replacement meter shall be installed within 30 days of discovery. If the meter is removed for any other reason, it shall be replaced with another meter having the same specifications given above, or the meter shall be reinstalled within 30 days of its removal. In either event, a fully functioning meter shall not be off the water supplies line for more than 60 consecutive days.

6. While the meter is being repaired or replaced, Licensee shall provide an estimate of the water supply quantities used by multiplying the number of hours the water supply was used by the capacity of the pump or mainline diameter. The estimate of the number of gallons used each month during that period shall be noted as an estimate when it is submitted to theSWFWMD.

7. In the event a new meter is installed to replace a broken meter, the replacement meter and its installation shall meet the specifications of this condition. Licensee shall notify the SWFWMD of the replacement with the first submittal of meter readings from the new meter.

G. Distribution Flexibility The average day, peak monthly, and maximum daily, if applicable, quantities for District ID No(s) 1, 2, 3, 4, 5, 6,7, 14, 15, 16 Licensee ID No(s). PW-1, PW-2, PW-3, PW-4, PW-5. PW-6, PW-7, PW-8, PW-9a. PW-10a shown above in the production withdrawal table are estimates based on historic and projected distribution of pumpage, and are for water use inventory and impact analysis purposes. The quantities listedin the table for these individual sources are not intended to dictate the distribution of pumpage from the withdrawal sources. The Licensee may make adjustments in pumpage distribution as necessary up to 125 percent on an average basis, up to 125 percent on a peak monthly basis, so long as adverse environmental impacts do not result and other conditions of this certification are complied with. In all cases, the total average annual daily withdrawal and the total peak monthly daily withdrawal are limited to the quantities set forth above. H. Water quality sampling

1. Water quality samples shall be collected and analyzed for parameters and at the frequencies specified below. Water quality samples from production wells shall be collected from all wells, unless infeasible. If sampling is infeasible, Licensee shall indicate the reason for not sampling on the water quality data form. Water quality samples shall be analyzed by a laboratory certified by the Florida Department of Health utilizing the standards and methods applicable to the parameters analyzed and to the water use pursuant to Chapter 64E- 1, Florida Administrative Code, "Certification of Environmental Testing Laboratories". At a minimum, water quality samples shall be collected after pumping the well at its normal rate for a pumping time specified in the table below, or to a constant temperature, pH, and conductivity. In addition, Licensee's sampling procedure shall follow the handling and chain of custody procedures designated by the certified laboratory which will undertake the analysis.

Any variance in sampling and/or analytical methods shall have prior approval of the Brooksville Regulation Department Director. Reports of the analyses shall be submitted to the Permit Data Section, Regulation Performance Management Department. (using SWFWMD forms) on or before the tenth day of the following month, and shall include the signature of an authorized representative and certification number of the certified laboratory which undertook the analysis. The parameters and frequencies of PEF CR MOD L PA 77-09L Final Order Page 9 of 16

0 sampling and analyses may be modified by the Brooksville Regulation Department Director, as necessary to ensure the protection of the resource. Ditrict ID No. Licensee ID No. Minimum Parameter Sampling Pumping Time Frequency (minutes 1 PW-1 20 minutes Chlorides, February, May, Sulfates, and August, and T.D.S. November 2 PW-2 20 minutes PW-3 20 minutes 4 PW-4 20 minutes 5 PW-5 20 minutes 6 PW-6 20 minutes 7 PW-7 20 minutes 14 PW-8 20 minutes 15 PW-9a 20 minutes 16 PW-10a 20 minutes Water quality samples shall be collected quarterly and on the same week of the months specified. Analyses shall be performed according to procedures outlined in the current edition of Standard Methods for the Examination of Water and Wastewater by the American Public Health Association-American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or Methods for Chemical Analyses of Water and Wastes by the U.S. Environmental Protection Agency (EPA).

2. Water quality samples from monitor wells shall be collected and analyzed for the District ID No., parameter(s), and frequency(ies) specified in the table below. Water quality samples shall be collected after pumping the monitor wells(s) to a constant temperature, pH, and conductivity.

Sampling method(s) shall be designed to collect water quality samples that are chemically representative of the zone to be sampled. Water quality samples shall be analyzed by a laboratory certified by the Florida Department of Health utilizing the standards and methods applicable to the parameters analyzed and to the water use pursuant to Chapter 64E-1, Florida Administrative Code, "Certification of Environmental Testing Laboratories". The Permittee's sampling procedure(s) shall follow the handling and chain of custody procedures designated by the certified laboratory which will undertake the analysis.. A report describing the sampling and chain of custody procedures shall be included with the first data submitted after the date this permit is granted, and upon any change in sampling and/or analytical, method(s). Any variance in sampling and/or analytical methods shall have prior approval of the SWFWMD. Reports of the analyses shall be submitted on SWFWMD forms on or before the tentlrday of the following month, and shall include the signature of an authorized representative and certification number of the certified laboratory that undertook the analysis; The parameters and frequency of sampling and analysis may be modified by the SWFWMD as necessary to ensure the protection of the resource. PEF CR MOD L PA 77-09L Final Order Page 10 of 16

District ID No. Licensee ID No. Parameter Sample Frequency

8 MZ-21 Chlorides, May, September 9 MZ-2D Sulfates, and TDS 10 MZ-2S 1I MZ-1S 12 MZ-11 13 MZ-1D Water quality samples shall be collected based on the following timetable:

Semi-annually Same week of months specified

Analyses shall be performed according to procedures outlined in the current edition of Standard Methods for the Examination of Water andWastewater by the American Public Health Association-American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or Methods for Chemical Analyses of Water and Wastes by the U.S. Environmental Protection Agency (EPA).

3. The SWFWMD reserves the right to set chloride, sulfate or TDS concentration limits on any production well in the future, based on data collected and after a sufficient data base has been established to determine limits. These limits shall be required after discussions with the Licensee. At such time as the concentration in any water sample reaches or exceeds the designated concentration limits, the Licensee shall take appropriate action to reduce concentrations to below those set for the particular well. If the SWFWMD determines that long-term upward trends or other significant water quality changes are occurring, the SWFWMID may reconsider the quantities included in these conditions of certification.

4. During drilling of District ID Nos. 14. 15, 16, Licensee ID Nos. PW-8. PW-9a, PW-lOa, water quality samples shall be collected at intervals of the change of drill rod or 30 feet, which ever is less, from 150 feet to a maximum depth of five feet above the bottom of the well. Regardless of the specified sample collection interval, a sample shall be collected from the depth which corresponds' to five feet above the bottom of the well. Samples shall be collected during reverse air drilling, or other appropriate method with prior approval by the SWFWMD.

Samples shall be analyzed by a certified laboratory for Chloride, Sulfate, and Specific Conductivity. Licensee's sampling procedure shall follow the handling and chain of custody procedures designated by the certified laboratory which will undertake the analysis. Reports of the analyses shall be submitted to the Permit Data Section, Regulation Performance Management Department (using SWFWMD forms) within thirty days of sampling, and shall include the signature of an authorized representative and the certification number of the Florida Department of Health certified laboratory utilizing the standards and methods applicable to the parameters analyzed and to the water use pursuantto Chapter 64E-1, Florida Administrative Code, "Certification of Environmental Testing Laboratories";. Analyses shall be performed according to procedures outlined in the current edition of Standard Methods for the Examination of Water and Wastewater by the American Public Health Association-American Water Works Association-Water Pollution Control Federation (APHA-AWWA-WPCF) or by Methods for Chemical Analyses of Water and Wastes by the U.S. Environmental Protection Agency (EPA). PEF CR MOD L PA 77-09L Final Order Page 11 of 16

5. Monthly water levels for monitor wells for the sites included in the table below shall be referenced to NGVD, and reported in a form acceptable to the SWFWMD by the tenth day of each month for the preceding month. The time and date that the elevation is taken shall be included.

Changes to the methodology, extent, or frequency of monitoring at any of these sites may be modified by the SWFWMD, as necessary to ensure the protection of the resources. District ID. No Licensee Site No. 8 MZ-21 9 MZ-2D 10 MZ-2S 11 MZ-1S 12 MZ-1I 13 MZ-1D I. Wells

1. Wells not in use with no installed pumping equipment shall be capped or valved in a water tight manner in accordance with Rule 62-532.500(3)(a)(4). F.A.C.

2. Within 90 days of the completion of each proposed well, Licensee shall submit to the SWFWMD specific capacity (well testing) information from any test performed by the Water Well Contractor or pump installer on the well. This information shall include:

a. Static water level before pumping

b. Duration of test pumping

c. Gallons per minute pumped

d. Final water level measured during pumping If step-drawdown tests were performed, the information listed above shall be

.submitted for each step.

3. Within 90 days of construction, Licensee shall submit to the Permit Data Section, Regulation Performance Management Department, the specific locations of District ID Nos. 14, 15, 16 Licensee ID Nos. PW-8, PW-9a, PW-10a, on an original blue line aerial with a minimum scale of one inch equals 800 feet, or by latitude/longitude. Intake and mainline diameters for each of the above pumps shall be reported at the time of location reporting.

4. For the purpose of determining site-specific transmissivity, a step drawdown and a multi well constant rate test shall be performed on one or more of the following: District ID Nos. 14, 15, 16 Licensee ID Nos. PW-8, PW-9a, PW-10a, after the wells have been fully developed. The test shall be performed in accordance with the specifications set forth in Design Aid 3, Water Use Permit Information Manual and an Aquifer Performance Testing (APT) Plan submitted to and approved by the SWFWMD.

The APT Plan shall be submitted to the SWFWMD, within 90 days of the approval of the modification of the conditions of certification. The APT shall be conducted by the Licensee within 6 months of construction of the wells included in the APT Plan and prior to the use of any of the wells constructed for the APT'S. All recorded raw data shall be submitted to the SWFWMD within thirty (30) days of completion of the APT.

5. Within sixty (60) days, the Licensee shall designate one individual responsible for receiving and responding to the SWFWMD notices and correspondence related to these conditions of PEF CR MOD L PA 77-09L Final Order Page 12 of 16

certification. Notification to the'SWFWMD:of the designee, including address and telephone number shall be in written form.

6. Within 90 days of conditions of certification issuance, Licensee shall develop and implement a Water Conservation Plan (Plan) that includes practices currently employed or planned. For planned components, include an estimated time-frame for implementation for each. The Plan must indicate that technically and'economically feasible water conservation opportunities have been or will be employed.

7. The lowest quality water source, including reclaimed water, surface water and stormwater, must be used for each consumptive use authorized, by these conditions of certification when available, except when Licensee demonstrates that the rise of the lower quality water source is determined to be not economically, environmentally, or technologically feasible, in' accordance with the SWFWMD's Water Use Permit Information Manual Part B, Basis of Review, Sections 4.4 and 4.1 1.

8. Wetlands and other surface waters may not be adversely impacted as a result of the water use authorized by these conditions of certification. If unacceptable adverse impacts occur, the VXIV*TXTL. xVAll rnl j,oc thatfIPP . rawn l- tha O-nnnlitnne nfl-,frt;fin n t'nn in xxrhn1, nr in nVrt tn Sr1rfl nr abate the unacceptable adverse impacts, unless the impacts can be mitigated by Licensee.

J. Standard Conditions Licensee shall comply with the following Standard Conditions:

1. If any of the statements in the application and in the supporting data are found to be untrue and inaccurate, or if Licensee fails to comply with all of the provisions of Chapter 373, F.S.,

Chapter 40D, or the conditions set forth herein, the SWFWMD shall seek revocation of any conditions of certification.

2. These conditions of certification are imposed based on information provided by Licensee demonstrating that the use of water is reasonable and beneficial, consistent with the public interest, and will not interfere with any existing legal use of water. If, during the term of this certification, it is determined by the SWFWMD that the use is not reasonable and beneficial, in the public interest, or does impact an existing legal use of water, the SWFWMD shall seek modification these conditions of certification or revocation of the certification authorized by DEP.

3. Licensee shall not deviate from any of the SWFWMD- imposed conditions of this certification without written approval by the Department, and the SWFWMD.

4. In the event the SWFWMD declares that a Water Shortage exists pursuant to Chapter 40D-21, Licensee agrees that portions of these conditions of certification shall be modified, or declared inactive as necessary to address the water shortage.

5. The SWFWMD shall collect water samples from any withdrawal point listed in these conditions of certification or shall require Licensee to submit water samples when the SWFWMD determines there is a potential for adverse impacts to water quality.

6. Licensee shall provide access to an authorized SWFWMD representative to enter the property at any reasonable time to inspect the facility and make environmental or hydrologic assessments. Licensee shall either accompany the SWFWMD staff onto the property or make provision for access onto the property.

7. Licensee shall cease or reduce any surface water withdrawals as directed by the SWFWMD if water levels in surface water fall below applicable minimum water level established in Chanter 40D-8 or rates of flow in streams fall below the minimum levels established in Chanter 40D-8.

8. Licensee shall cease or reduce withdrawals if water levels in aquifers fall below the minimum levels established by the SWFWMD.

PEF CR MOD L PA 77-09L Final Order Page 13 of 16

0 9. Licensee shall practice water conservation to increase the efficiency of transport, application, and use, as well as to decrease waste and to-minimize runoff from the property. At such time. as the SWFVWMD adopts specific conservation requirements for Licensee's water use classification, these conditions of certification shall be modified accordingly.

10. The SWFWMD may establish special regulations for Water Use Caution Areas.

At such time as the Governing Board adopts such provisions, these conditions of certification shall be subject to them upon notice and after a reasonable period for compliance. 1 1i. Licensee shall mitigate any adverse impact to existing legal uses caused by

withdrawals. When adverse impacts occur or are imminent, Licensee shall be required to mitigate the impacts. Adverse impacts include:

a. A reduction in water levels which impairs the ability of the well to

produce water:

b. Significant reduction in levels or flows in water bodies such as lakes, impoundments, wetlands, springs, streams Or other watercourses: or

c. Significant inducement of natural or manmade contaminants into a water supply or into a usable portion of any aquifer water body.

12. Licensee shall mitigate any adverse impact to environmental features or offsite landuses as a result of withdrawals. When adverse impacts occur or are imminent, the Licensee shall be required to mitigate the impacts. Adverse impacts include:

a. Significant reduction in levels or flows in water bodies such as lakes, impoundments, wetlands, springs, streams or other watercourses;

b. Sinkholes or subsidence caused by reduction in water levels;

c. Damage to crops and other vegetation causing financial harm to the owner, and

d. Damage to the habitat of endangered or threatened species.

13. When necessary to analyze impacts to the water resource or existing users, Licensee shall be required to install flow metering or other measuring devices to record withdrawal quantities and submit the data to the SWFWMD.

14. A SWFWMD identification tag shall be prominently displayed at each withdrawal point by permanently affixing the tag to the withdrawal facility.

15. Licensee shall notify the SWFWMD within 30 days of the sale or conveyance of permitted water withdrawal facilities or the land on which the facilities are located.

16. The annual average daily withdrawal quantity is determined by calculating the total quantity of water to be withdrawn over a one year period, divided by 365 days, whicli results in a gallons per day (gpd) quantity pursuant to Basis of Review, Section 3.2, Permitted Withdrawal Quantities. This is a running 12-month average, whereby each month the annual average daily quantity is recalculated based on the previous 12-month pumpage.

IV-XIII. No Change A complete set of the Conditions of Certification (including attachments) can be viewed and downloaded from the following website: http://www.dep.state.fl.us/siting/Highlights/conditions.htm. Copies of the Conditions of Certification and/or attachments may also be obtained by contacting Michael P. Halpin, P.E., Administrator, Siting Coordination Office, Department of Environmental Protection, 2600 Blair Stone Road, M.S. 48, Tallahassee, Florida 32399-2400, (850) 245-8002. PEF CR MOD L PA 77-09L Final Order Page 14 of 16

Any. aýrtyfto the this Ord'r hasairigtto seek judidciail 'review. f itpursumft to Section 120.68;, Florida Staiutes by filing a Notice of Appeal, pursuant io Rule-9,l1OIFlorida Rules of Appellate Procedure, with, Ahe Cl1erk of the Deepartment of'Environfi-ental Prote'tion in the Orfce of General Co unsel, 3900 dCrimonwealthBou levrd, M;S. 35,Tallahassee, Florida 3239943000, and by filing a,copy of the Notice

.ofAppeal, accompanied by the' applicable filing fees, With the appropriate SWFWMD Courtof Appeal' The Notice of Appealndust b. °filied within thirty days from the date ithis:Order is filed with the.Clerk of the De~partment of Environmenotal Protection. Executed in Tal1ahass~ee Florida. Michael P. Halp-in, P.E. " Adminisirator, Siting Coordination Offce, FILING AND ACKNOWLEDGMENT FILED, on this date; pursuant to §120.52 Florida, Statutes;,with the' designated _Depa)'tment Clerk,. receipt of Which is hereby acknowledged. L2AL2J IAJUA IDAe PEFCR MOD L PA 77-09L. FýinalOrder Page 15.of ;16

Service List: CC by email (return receipt requested): James Antista, Esquire Kelly Martinson, Esquire Fish and Wildlife Conservation Commission Department of Community Affairs 6230 South Meridian Street 2555 Shumard Oak Blvd. Tallahassee, FL 32399-1600 Tallahassee, Florida 32399-2100 iames.antista(afwc.state.fl.us kelly.martinson@dca.state.fl.us Kimberly Menchion, Esq. Toni Sturtevant, Esquire Assistant General Counsel Department of Environmental Protection Department of Transportation 3900 Commonwealth Blvd. 605 Suwannee Street, MS 58 Mail Station 35 Tallahassee, FL 32399-0458 Tallahassee, FL 32399-3000 kimberlv.menchiona~dot.state.fl.us toni.sturtevant@dep.state.fl.us Jennifer Brubaker, Attorney Supervisor Martha A. Moore, Esquire Florida Public Service Commission Southwest FL Water Management District Office of General Counsel 2379 Broad Street 2450 Shumard Oak Boulevard Brooksville, FL 34604-6899 Tallahassee, FL 32399-0850 martha.moore@swfwmd.state.fl.us ibrubakegpsc.state.fl.us Doug Roberts, Esquire Fred Landt, Esq. Hopping Green & Sams, P.A. Withlacoochee Regional Planning Council P.O Box 6526 Post Office Box 2045 Tallahassee, Florida 32317 Ocala, FL 34478 drobertsghgslaw.com I fl3swim47@aol.com Robert Battista, Esq. Kevin A. Smith, Director Office of the Citrus County Attorney Sue Farnsworth, Environmental Planner 110 N. Apopka Avenue Citrus County Development Department Inverness, FL 34450 3600 W. Sovereign Path, Suite 140 Cheryl.clamer(abocc.citrus.fl.us Lecanto, FL 34461 Kevin.smith(bocc.citrus.fl.us R. Alex Glenn Progress Energy Florida, LLC Post Office Box 14042 St. Petersburg, FL 33733 alex.ulenn(apgnmail.com PEF CR MOD L PA 77-09L Final Order Page 16 of 16

Hydrology Reference Request 5

1. Production Well Data. A map of well locations is provided in the response to H-1.

Progress Energy - Crystal River Energy Complex 0 Crystal River Units 1,2,3 Production Wells Permitted Yield (gpd) Total Cased Diameter Depth (ft. Depth (ft. Well No. (In.) bls) bls) avg. peak mo. la 5 42 42 25,000 37,500 lb 5 42 42 25,000 37,500 3 10 90 36 380,000 570,000 4 10 125 37 285,000 427,500 5 10 72 unk 285,000 427,500 Total = 1,000,000 1,500,000 Crystal River Units 4&5 Production Wells Permitted Yield (gpd) Total Cased Diameter Depth (ft. Depth (ft. Well No. (In.) bls) bls) avg. peak mo. 1 10 200 35 250,000 281,250 2 10 200 47 250,000 281,250 3 10 200 60 250,000 281,250 4 10 200 41 250,000 281,250 5 10 200 35 521,520 586,710 6 10 200 50 521,520 586,710 7 10 200 50 521,520 586,710 8 10 200 50 521,520 586,710 9 10 200 50 521,520 586,710 10 10 200 50 521,520 58671 Total = 4,129,120

tA AC

                                                                                                                          .,e £040 SOUTHERN ANALYTICAL LABORATORIES,                                                                INC.

1 10 BAYVIEW BOULEVARD, OLDSMAR, FL 34877 813-855-1844 fax813-855-2218B

                                                                                                                 ~LI~Id~

Progress Energy Inc. August 7, 2009 15760 West Power Line Street Project No: 94054 CN77-Cyndy Wilkinson Crystal River, FL 34428-Laboratory Report Project Name Quarterly Production Wells Analyses - Crystal River North Sample Description PW-2 Matrix Groundwater SAL Sample Number 94054.02 Date/Time Collected 08/05109 07:05 Date/Time Received 08105109 08:46 Parameters Units Results Method Detection Date/Time Date/Time Analyst Limit Analyzed Prep Field Parameter Specific Conductance umhos/cm 503 DEP FT1200 08/05/09 07:05 LRW Water Temperature C 23.0 DEP FT1400 08/05/09 07:05 LRW pH Units 7.0 DEP FT1100 08/05/09 07:05 LRW Dissolved Oxygen mg/I 1.1 DEP FT1500 08/05/09 07:05 LRW Turbidity NTU 1.4 DEP FT1600 08/05/09 07:05 LRW lnpr-anics Chloride mg/I 10 EPA 300.0 0.05 08106/09 03:34 VWC Sulfate mg/I 4.9 EPA 300.0 0.2 08/06/09 03:34 VWC Total Dissolved Solids mg/I 220 SM 2540C 10 08/07/09 10:50 08/05/09 11:40 EPL FDOH Laboratory No. E84129 Francis I. Daniels, Laboratory Director NIELAP Accredited Leslie C. Boardman, Q. A. Manager Page 1 of 8

                                                                                                                  ~    AC SOUTHERN ANALYTICAL                                   LABORATORIES, INC.

110 BAYVIEW BOULEVARD, OLOSMAR, FL 34677 813-855-1844 fax 813-855-2218 Progress Energy Inc. August 7, 2009 15760 West Power Line Street Project No: 94054 CN77-Cyndy Wilkinson Crystal River, FL 34428-Laboratory Report Project Name Quarterly Production Wells Analyses - Crystal River North Sample Description PW-3 Matrix Groundwater SAL Sample Number 94054.03 Date/Time Collected 08105109 07:15 Date/Time Received 08105109 08:46 Parameters Units Results Method Detection Date/Time Date/Time Analyst Limit Analyzed Prep Field Parameter Specific Conductance umhos/cm 445 DEP FT1200 08/05/09 07:15 LRW Water Temperature C 22.9 DEP FT1400 08/05/09 07:15 LRW pH Units 7.0 DEP FT1100 08/05/09 07:15 LRW Dissolved Oxygen mg/I 1.2 DEP FT1500 08/05/09 07:15 LRW Turbidity NTU 0.80 DEP FT1600 08/05/09 07:15 LRW Inorganics Chloride mg/I 8.8 EPA 300.0 0.05 08/06/09 03:51 VWC Sulfate mg/I 4.7 EPA 300.0 0.2 08/06/09 03:51 VWC Total Dissolved Solids mg/I 210 SM 2540C 10 08/07/09 10:50 08/05109 11:40 EPL FDOH Laboratory No. E84129 Francis I. Daniels, Laboratory Director NELAP Accredited Leslie C. Boardman, Q. A. Manager Page 2 of 8

0~ A~CoC SOUTHERN ANALYTICAL LABORATORIES, INC. 110 BAYVIEWBOULEVARD, OLDSMAR, FL 34677 813-855-1844 faxB13-855-2218 Progress Energy Inc. August 7, 2009 15760 West Power Line Street Project No: 94054 CN77-Cyndy Wilkinson Crystal River, FL 34428-Laboratory Report Footnotes Test results presented in this report meet all the requirements of the NELAC standards. A statement of estimated uncertainty of test results is available upon request. For methods marked with ***,all QC criteria have been met for this method which is equivalent to a SAL certified method. FDOH Laboratory No. E84129 Approved By: Francis I. Daniels, Laboratory Director NELAP Accredited Leslie C. Boardman, Q. A. Manager Page 3 of 8

0 0 SLProj oct No. OHS SOUTHERN ANALYTICAL LABORATORIES, INC. 110 BAYVIEW BOULEVARD. OLDSMAR, FL 34877 8113-855-1 844 fax 81 _*B5---P.1 8 Client Name Contact / Phone: Progress Energy Inc. Cyndy Wilkinson 352/464-7739 Project Name / Location Quarterly Production Wells Analyses - Crystal River North Samles:(Sinaur) (.*<*PARAMETER I CONTAINER DES CRI PTION1 Samplers: (Signature) _ __ Matrix Codes: DW-Drinking Water WW-Wastewater SW-SurfaceWater SL-Sludge SO-Soil Z GW-Groundwater SA-Saline Water 0-Other o-: R-Reagent Water G0 o, oo x '-Cl CU E 6 tio SampleDescription a I.- 1 0( _,,_ ___ 25 01 PW-1 Cl- GW X I ...... 1 02 JPW-2 0 0 1 GW _ X I I- 1 03 PW-3 41' O7 GW X 1 "o CD 04 PW-4 is

                              -jl                     L-                      _"               Gw            x         1                               ___                      ___                         1 0o Containers Prepared/lDaterirfe:'                    6 ,1       Received:                             D*/*     Jii,         Seal ntact?                         Y N *A        instructionsl Remarks Relinquished    a

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Sanples itact upon arrNal? N WA Relinqe DI m- Received Datefrime Received on Ice? Terlp- N NA Wr'1i "UL RelinquishV'" DaleTie Received: OatefTire: Proper preservatives indicated?

Rec'd w ithin holding tinmn? N WA P ospumts Relinquished: Date/rime: Received: Dateflime. .PV Volatiles rec'd w/out headspace y N PRoper containers used? Relinquished: Date/Time: Received: )aterTime: c/N WA Chna of Cu11dyJ1 Re.Dale MIMI/0 Chain of Custody

SOUTHERN ANALYTICAL LABORATORIES, INC. 1 10 BAYVIEW BOULEVARD, OLOSMAR, FL 34677 813-655-1644 FAX 81 3-855-221 8 A GROUNDWATER SAMPLING LOG 1

Contact:

Cyndy Wilkinson I Progress Energy, Inc. Location: Crystal River Plant I

Contact:

I Cyndy Wilkinson aw Client Name: Phone: 3521464-7739 I Progress Enrgy, Inc. I Phone:l3/4-79 Date Sampled " SAL Project Project Name Quarterly Production Wells PW-1 Sample ID GPS LAf Well Number / Q1 GPSLONG PURGING DATA WELL WELL Screen Static Depth to PURGE PP GP DIAMETER CAPACITY Interval I UNK To UNK Water (Feet) PUMP CODE IBP (inches) (gal/ft) (Feet) Water (Feet __ PUMP CODE IBP TOTAL WELL REFERENCE GROUND WATER TUBING TUBING DEPTH (Feet) ELEVATION ELEVATION DIAMETER CAPACITY (NGVD) (REFERENCE-STATIC) (Inches) (gal/ft) Purge Technique: q Submerged Screen (1,1/4,1/4 Well) q Submerged Screen 1EQ Volume, 3, 3 Minutes) q Partially Su bmerged Screen (1 Well, 3,3 minutes) WELL VOLUME = (TOTAL DEPTH - STATIC DEPTH) x WELL CAPICITY = ( 0.00 _

ONE WELL 1/4 WELL 1 3 WELL 1 5 WELL VOLUME [VOLUME IVOLUMES VOLUMES EQUIPMENT VOLUME = PUMP VOLUME + (TUBING CAPACITY X TUBING LEGNTH) + FLOW CELL VOLUME PUMP TUBING FLOW CELL EQUIPMENT VOLUME LEGNTH I VOLUME VOLUME INITIAL TUBING LEGNTH FINAL TUBING LEGNTH PURGE PURGE TIME TOTAL IN WELL (FEET) IN WELL (FEET) TIME START END PURGED VOUE TOTAL VOLUME PURGE Depth to pH TEMP SP COND DO TURBIDITY COLOR ODOR TIME PURGED PURED RAE Water (SU) (oC) (uS/cm) (mg/L) (NTUs) (Describe) (Describe)

(Gallons) PURGED RATE(gpm) (Feet) (A <0.2) (A <0.2) (A <5%) (% SAT <20) (<20 NTU) (Gallons) Well Capacity (gallons/foot): 0.75"=0.02, 1.25"=0.06, 2"=0.16. 3"=0.37, 4"=0.65, 5"=1.02, 6"=1.47, 12"5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 SAMPLING DATA SAMPLED BY / COMPANY SAMPLER(S) (PRINT) SIGNATURES: TUBING MATERIAL CODE PP PE NP TL TT SAMPLE TUBING LEGNTH SAMPLE PUMP FLOW RATE (CIRCLE ONE) IN WELL (FEET) (mL/min) SAMPLING SAMPLING FIELD CLEANING INITIATED ENDED CLEANED STEPS FIELD Y FILTER SIZE DUPLICATE Y N VOC COLLECTED BY Y N N/A SEMI-VOLS COLLECTED Y N N/A FILTERED? N -m) REVERSE FLOW? THROUGH TRAP? PRESERVATION CHECKED LIST PRESERVATIVES IN FIELD? Y N N/A ADDED CONDITIONS COMMENTS PUMP CODES: PP=Peristalttc Pump, GP= Submersible Grundfos Pump. IBP= In-place Bladder Pump TUBING MATERIAL CODES: PP= Polypropylene, PE= Polyethylene, NP= Non-inert Plastic, TL= Teflon Lined, TT= Teflon i Reviewed B1:37- Date:1 Progress Energy Crystal River North Q PW FS.xls Revision Date 01/18/2005 Page 5 of 8

SOUTHERN ANALYTICAL LABORATORIES, INC. 1 10 BAYVIEW BOULEVARD, OLOSMAR, FL 34677 B13-855-1844 FAX 813-855-2218 A GROUNDWATER SAMPLING LOG 352/464-7739 Energy, Inc. Progress Energy, Inc. Location: Crystal River Plant I

Contact:

Cyndy Wilkinson I U Client Name: I Phone: 352/464-7739 I w Date Sampled /)1 q SAL Project Project Name Quartedy Production Wells Well Number PW-2 Sample _________________________________________, ID ,0' ___ GPS GPS LAT_ LONG_____________ PURGING DATA WELL WELL Screen DIAMETER CAPACITY Interval I UNK To UNK Static Depth to PURGE PP GP (Inches) (gal/ft) (Feet) Water (Feet) PUMP CODE tBP REFERENCE GROUND WATER TUBING TUBING TOTAL WELL ELEVATION ELEVATION DIAMETER CAPACITY DEPTH (Feet) (NGVD) (REFERENCE-STATIC) (Inches) (gal/ft) Purge Technique: q Submerged Screen (1,1/4,1/4 Well) q Submerged Screen (1EQ Volume, 3, 3 Minutes) q Partially Submerged Screen (1 Well, 3,3 minutes) WELL VOLUME = (TOTAL DEPTH - STATIC DEPTH) x WELL CAPICITY = ( 0._0__ ONE WELL 1/4 WELL 1_3 WELL I 5WELL VOLUME VOLUME I VOLUMES VOLUMES EQUIPMENT VOLUME = PUMP VOLUME + (TUBING CAPACITY X TUBING LEGNTH) + FLOW CELL VOLUME PUMP TUBING FLOW CELL EQUIPMENT VOLUME LEGNTH VOLUME VOLUME INITIAL TUBING LEGNTH FINAL TUBING LEGNTH PURGE PURGE TIME TOTAL IN WELL (FEET) IN WELL (FEET) TIME START END PURGED VOUE TOTAL VOLUME VOLUME PURGE Depth to pH TEMP SP COND DO TURBIDITY COLOR ODOR TIME PURGED Water (SU) (oC) (uS/cm) (mg/L) (NTUs) ______ Gallons) (Gallons) (Gallons) PURGED RATE (gpm) (Feet) ______ (A <0.2) (A <0.2) (A <5%) (% SAT <20) (<20 NTU) (Describe) (Describe) 7Ll Well Capacity (gallons/foot): 0.75"=0.02, 1.25"=0.06, 2"=0.16, 3"=0.37. 4"=0.65, 5"=1.02, 6"=1.47, 12"5.88 TUBING INSIDE DIA. CAPACITY (GalFft): 1/8'- 0.0006; 3/16" = 0.0014; 1/4" =0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 SAMPLING DATA SAMPLED BY / COMPANY SAMPLER(S) (PRINT) SIGNATURES: TUBING MATERIAL CODE PP PE NP TL TT SAMPLE TUBING LEGNTH SAMPLE PUMP FLOW RATE (CIRCLE ONE) IN WELL (FEET) (mL/min) SAMPLING SAMPLING FIELD Y N CLEANING INITIATED ENDED CLEANED STEPS FIELD FILTER SIZE DUPLICATE Y N VOC COLLECTED BY SEMI-VOLS COLLECTED Y N N/A FILTERED? Y (pm) DICT I REVERSE FLOW? ' N N/A THROUGH TRAP? PRESERVATION CHECKED LIST PRESERVATIVES IN FIELD? ADDED WEATHER CONDITIONS COMMENTS PUMP CODES: PP=Peristaltic Pump, GP= Submersible Grundfos Pump, IBP= In-place Bladder Pump TUBING MATERIAL CODES: PP= Polypropylene, PE= Polyethylene, NP= Non-inert Plastic, TL= Teflon Lined, TT= Teflon Reviewed By:J I Date:l Progress Energy Crystal River North Q PW FS.xls Revision Date 01/18/2005 Page 6 of 8

SOUTHERN ANALYTICAL LABORATORIES, INC. 110 BAYVIEW BOULEVARD, OLDSMAR, FL 34677 813-855-1844 FAX 813-855-2218 GROUNDWATER SAMPLING LOG Progress Energy, Inc. Location: r Crystal River Plant 1

Contact:

U Cyndy Wilkinson aw Client Name: U I Phone:l 352/464-7739 I Date Sampled I SAL Project Project Name Quarterly Production Wells PW-3 Sample ID GPS LAT

                                                                                                   - A3

[Well Number GPS LONG PURGING DATA WELL DIAMETER WELL CAPACITY Screen Interval LINK To LINK Static Depth to PURGE PP GP (Inches) (gal/ft) (Feet) I Water (Feet) PUMP CODE IBP TOTAL WELL REFERENCE GROUND WATER TUBING TUBING DEPTH (Feet) ELEVATION ELEVATION DIAMETER CAPACITY (NGVD) (REFERENCE-STATIC) (Inches) (gal/ft) Purge Technique: q Submerged Screen (1,1/4,1/4 Well) q Submerged Screen (IEQ Volume, 3, 3 Minutes) q Partially Submerged Screen (1 Well, 3,3 minutes) WELL VOLUME = (TOTAL DEPTH - STATIC DEPTH) x'WELL CAPICITY 0.56 ONE WELL 1/4 WELL 1 3 WELL 5 WELL VOLUME, VOLUMEI VOLUMES VOLUMES EQUIPMENT VOLUME = PUMP VOLUME + (TUBING CAPACITY X TUBING LEGNTH) + FLOW CELL VOLUME PUMP TUBING FLOW CELL EQUIPMENT VOLUME LEGNTH VOLUME VOLUME INITIAL TUBING LEGNTH FINAL TUBING LEGNTH PURGE PURGE TIME TOTAL IN WELL (FEET) IN WELL (FEET) TIME START END PURGED VOUE TOTAL VOLUME PURGE Depth to pH TEMP SP COND DO TURBIDITY COLOR ODOR TIME PURGED Water (SU) (oC) (uS/cm) (mg/L) (NTUs) Cribe (DeR (Gallons)(aln) PURGED RATE (gpm) (Feet) (A <0.2) (A <0.2) (A <5%) (% SAT <20) (<20 NTU) (Describe) (Describe) (Gallons)

7. oY')L 0191" /I. z3 ?.7 Ie Well Capacity (gallons/foot): 0.75"=0.02, 1.25"=0.06, 2"=0.16, 3"=0.37, 4"=0.65, 5"=1.02, 6"=1.47, 12"5.88 TUBING INSIDE DIA. CAPACITY (GalJFt.): 1/8"=0.0006; 3/16"=0.0014; 1/4"=0.0026: 5/16"=00004; 3/8"=0.006; 1/2"=0.010; 5/8"=0.016 SAMPLING DATA Progress Energy Crystal River North Q PW FS.xls Revision Date 01118/2005 Page 7 of 8

SOUTHERN ANALYTICAL LABORATORIES, INC. 110 BAYVIEW BOULEVARD, OLDSMAR, FL 34677 813-855-1 844 FAX 81 3-855-2218 GROUNDWATER SAMPLING LOG A RIe 324473 ln Cynvnu Crystal~--- CnntRr.t- WilKInson Progress Energy, Inc. Crystal River Plant I f'onfact: Phone: 352/464-7739 w Client Name: Location: I Date Sampled I _ _--__SAL 51 Q, Proec Project Name Quarterly Production Wells Well Number PW-4 Sample ID *0,!j GPS GPS L-.d_# LONG G LAT PURGING DATA WELL WELL Screen Static Depth to DIAMETER (Inches) CAPACITY (gal/ft), Interval (Feet) I UNK To UNK Water Water (et) (Feet) PUMP CODE IBP TOTAL WELL REFERENCE GROUND WATER TUBING TUBING DE ee)(NGVD) DEPTH (FeeL) TH( ELEVATION (REFERENCE-STATIC) ELEVATION DIAMETER (inches) CAPACITY (gal/ft) Purge Technique: q Submerged Screen (1,1/4,1/4 Well) q Submerged Screen 1EQ Volume, 3, 3 Minutes) q Partially Submerged Screen (1 Well, 3,3 minutes) WELL VOLUME = (TOTAL DEPTH - STATIC DEPTH) x WELL CAPICITY = ( 0_.00 ) - I ONE WELL 1/4 WELL 3 WELL 5 WELL VOLUME VOLUME VOLUMES VOLUMES EQUIPMENT VOLUME = PUMP VOLUME + (TUBING CAPACITY X TUBING LEGNTH) + FLOW CELL VOLUME PUMP TUBING FLOW CELL EQUIPMENT VOLUME LEGNTH VOLUME VOLUME INITIAL TUBING LEGNTH FINAL TUBING LEGNTH PURGE PURGE TIME TOTAL IN WELL (FEET) IN WELL (FEET) TIME START END PURGED VOLUME PURGE Depth to pH TEMP SP COND DO TURBIDITY COLOR ODOR TIME PURGED POURE RTE Water (SU) (oC) (uS/cm) (mg/L) (NTUs) (Describe) (Describe) (Gallons) _________________________(G allons) _______________ (Feet) (A <0.2) (A <0.2) (A <5%) (% SAT <20) ______________________________ (<20 NTU) Well Capacity (gallons/foot): 0.75"=0.02, 1.25"=0.06, 2"=0.16, 3"=0.37, 4"=0.65, 5"=1.02, 6"=1.47, 12"5.88 TUBING INSIDE DIA. CAPACITY (Gal/Ft.): 1/8" = 0.0006; 3/16"= 0.00147 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 SAMPLING DATA SAMPLED BY J COMPANY SAMPLER(S) (PRINT) SIGNATURES: TUBING MATERIAL CODE PP PE NP TL TT SAMPLE TUBING LEGNTH SAMPLE PUMP FLOW RATE (CIRCLE ONE) IN WELL (FEET) (mL/min) SAMPLING SAMPLING FIELD CLEANING INITIATED ENDED CLEANED Y STEPS FIELD FILTER SIZE DUPLICATE Y N VOC COLLECTED BY Y N N/A SEMI-VOLS COLLECTED Y FILTERED? N (mrn REVERSE FLOW? THROUGH TRAP? Y N N/A PRESERVATION CHECKED LIST PRESERVATIVES IN FIELD? ADDED WEATHER 1-H t) ~ i.c ~~x CONDITIONS COMMENTS PUMP CODES: PP=Peristaltic Pump, GP= Submersible Grundfos Pump, IBP= tn-place Bladder Pump TUBING MATERIAL CODES: PP= Polypropylene, PE= Polyethylene, NP= Non-inert Plastic, TL= Teflon Lined, TT= Teflon Reviewed By:J I Date:l Progress Energy Crystal River North Q PW FS.xls Revision Date 01/18/2005 Page 8 of 8

Southern Analytical Laboratories, Inc. 110 Bayview Blvd. Invoice Oldsmar, FL 34677 Date Invoice # 08/07/2009 102269 Bill To Patti Yates Progress Energy 15760 W. Power Line St. Crystal River, Florida 34428

AGCo4 SOUTHERN ANALYTICAL LABORATORIES, INC. 1 10 BAYVIEW BOULEVARD, OLDSMAR, FL 34677 813-B55-1844 fax 813-855-221 B a: Progress Energy Inc. September 22, 2009 15760 West Power Line Street Project No: 95608 CN77 Crystal River, FL 34428-Laboratory Report Project Name CRS Units I and 2 Sample Description PW-4 Matrix Groundwater SAL Sample Number 95608.01 Date/Time Collected 09/14/09 14:00 Date/Time Received 09/16/09 10:05 Parameters Units Results Method Detection Date/Time Date/Time Analyst Limit Analyzed Prep Inor-qanics Chloride mg/I 12 EPA 300.0 0.05 09/16/09 21:50 VWC Sulfate mg/I 9.9 EPA 300.0 0.2 09/16/09 21:50 VWC Total Dissolved Solids mg/I 230 SM 2540C 10 09/19/09 13:25 09/16/09 15:10 EPL FDOH Laboratory No. E84129 Francis I. Daniels, Laboratory Director NELAP Accredited Leslie C. Boardman, Q. A. Manager Page 1 of 3

SOUTHERN ANALYTICAL LABORATORIES, INC. 110 BAYVIEW BOULEVARD, OLOSMAR, FL 34677 81 3-855-1 844 fax 813-855-2218 Progress Energy Inc. September 22, 2009 15760 West Power Line Street Project No: 95608 CN77 Crystal River, FL 34428-Laboratory Report Footnotes

*k Test results presented in this report meet all the requirements of the NELAC standards.

A statement of estimated uncertainty of test results is available upon request. For methods marked with ***, all QC criteria have been met for this method which is equivalent to a SAL certified method. FDOH Laboratory No. E84129 Approved By: Francis I. Daniels, Laboratory Director NELAP Accredited Leslie C. Boardman, Q. A. Manager Page 2 of 3

RN ANALYTICAL LABORATORIES, INC. SAL Project No.-q! iioi* ,OULEVARD, OLDSMAR, FL 34677 813-855-1844 fax 813-865-2218 s nt Klame Contact i Phone: F(_,q Project Name / Loction - - Turn Around Time Reduested (*Surcharges may apply) CAe 1'i7'!S 24 Hour* 4)48Hour- 5 Bus. Days* [] 10 Bus. Days 03

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PARAMETER I CONTAINER DESCRIPTION DW-Drinking Water WW-Wastewater -*

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Contairm Pre a Seal intact?.l Relinquish ibrVýL Sanples intact upon arrival?

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Relinq W/A Data/Time: , _ f Received on ire? Ternp Dtme I NVA Reiihed {)atefrime: B~ved: Daeme TJ roper preservatives indicated? Rec'd w ithin holing tirez W/A Liale/Time: Recerved; Date/Time: Volatiles recd w/out heads pact L Proper containers used? I. Date/Time: Received: Date/Time: Rehnqw uisJ't~ 0N/A of R-Dat. la

Southern Analytical Laboratories, Inc. 110 Bayview Blvd. Invoice Oldsmar, FL 34677 Bill To Patty Yates Progress Energy 15760 West Power Line St. Crystal River, Florida 34428

Hydrology Reference Request 6

1. Environmental Management Plan

PROGRESS ENERGY - CRYSTAL RIVER ENERGY COMPLEX ENVIRONMENTAL MAINAGEMENT PLAN Conditions of Certification PA-77-09K Citrus County, Florida Prepared by: EnHydro, LLC 334 East Lake Rd., #,173 Palm Harbor, FL 34685-2427 Quest Ecology Inc. 735 Lakeview Dr. Wimauma, FL 353598 QUEST e c o I o gy Preparedfor: Progress Energy 15760 West Power Line. St. Crystal River, Florida 34428-6708

PROGRESS ENERGY - CRYSTAL ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K PROGRESS ENERGY - CRYSTAL RIVER ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K

1.0 INTRODUCTION

Progress Energy's Crystal River Energy Complex is located in Citrus County, Florida. Water use needs require the withdrawal of groundwater for plant operation and air pollution control. Groundwater wells for the plant are located along a power line corridor in Sections 31 and 32, Range 17 East, Township 17 South, in Citrus County, Florida (Figure 1). Currently there are four (4) active groundwater wells, three (3) installed wells which are not yet active, and three (3) additional wells that have been permitted and are currently being constructed. Condition #2 of the Conditions of Certification #PA-77-09K requires an Environmental Management Plan (EMP) be created to address the concerns of drawv-down effects on surface waters and wetlands in the vicinity of the wellfield. The Southwest Florida Water Management District's (SWFWMD's) approval is being sought for the EMP proposed in this document. 2.0 METHODOLOGY Monitoring methodology proposed for this project incorporates the use of the Wetland Assessment Procedure (WAP), and is further supported by hydrologic data collection fromi monitoring of shallow groundwater levels using piezometers and staff gages and by collecting rainfall data using a recording rain gauge. These methods are proposed in order to detect potential changes in shallow groundwater levels and changes in vegetation zonation within the cone of influence of the wellfield. WAP Monitoring The WAP was originally developed by the District in 2000 as part of the Environmental Management Plan (EMP - March 4, 2000), a plan for the collection of data to be used in the management of the Central System Weltfields included in Tampa Bay Water's Consolidated Water Use Permit. The objective of the WAP is to collect information on vegetation, hydrology, soils, and other pertinent variables in monitored wetlands to accurately characterize the ongoing, biological condition and health of each wetland. It is important to understand that although the WAP seeks to document and monitor many aspects of wetland health, many of these aspects are not the procedure's focus. Many wetlands are also subject to negative health impacts caused by surrounding land management and drainagepractices, encroaching development, cattle operations, exotic plant species introduction, disease, and other variables. The WAP attempts to focusonthe-collection ofdata that will, be used to assess biologic changes caused by the hydrologiceffects of groundwater withdrawals.

PROGRESS ENERGY - CRYSTAL ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K The results of the WAP include health assessment scores, observations, and other general information. One critical aspect of the procedure is the written documentation that explains various decisions made by the evaluator, as well as a written., ongoing history of the Progress Energy monitoring sites. The written explanations and comments are intended to document the evaluator's logic in deriving scores, provide a basis for ongoing quality control (as well as future correction of errors), and provide the evaluator the ability to document potentially important wetland health-related observations that may not be fully included in the current procedure. Therefore, it is important to realize that the written explanations, comments, and history are essential products of the WAP, and should not be considered optional. In-depth methods of the WAP transect set-up and evaluating the WAP procedure can be found at the following website: The WAP will take place bi-annually, typically in May/June and December. Standard WAP procedure only requires monitoring annually and is typically conducted in May/June. A report documentingall results will be submitted to the District annually. Hydrologic Monitoring A shallow piezometer will be installed within the upland directly adjacent to each of the WAP transect locations. Piezometer installation will be conducted by a licensed well driller under the supervision of an EnHydro professional geologist. The piezometers will be installed such that they intersect, thefirst water-bearing zone beneath land surface. The piezometers will be constructed of two-inch diameter Schedule 40 PVC well casing, internally-threaded to a 10-ft section of 0.010-ineh slotted well screen. A staff gage will be installed in the deepest portion of each of the wetlands proposed for WAP Transects and located at the "end" of each transect. Staff gage elevations and piezometer elevations will be surveyed by a licensed surveyor and referenced to National .Geodetic Vertical. Datum (NGVD). Monitoring of staff gages and peizometers will be conducted on a bi-weekly basis (twice per month, same weeks each month) by Progress Energy or theirdesignee. Water levels will be collected and date and time recorded at each staffgage and piezometer location. An additional staff gage (hydrologic monitoring station) will also be established within each of two (2) pond sites which appear to hold water on a permanent*or semi-permanent basis. Locations of these two (2) hydrologic monitoring stations along with the WAP wetlands are provided on Figure 2.

,Approximate locations of WAP transect piezometers and staff gages are provide in Figure 3.

Photographs of the two (2) ponds proposed for hydrologic "monitoring stations are provided in Appendix A. Water leVel data will be submitted to the District on a District-approved form by the 10' day .of each month for the preceding:month. Total daily rainfall will be recorded utilizing a continuous recording gauge in. the vicinity. Daily rainfall data will be submitted monthly to the District prior to the tenth day of the followg month.

PROGRESS ENERGY -CRYSTAL ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K Proposed WAP Transect Locations Four (4) WAP transects are proposed within three (3) herbaceous and/or shrubby wetland systems (Figure 2). Wetlands were systematically chosen based on positioning within the predicted 0.3-6 drawdown contours, discussions held with District staff, a field review of wetlands to determine optimal situation, and property access. Concentric rings of drawdown potential were considered when choosing the wetlands. Drawdow-n affect should be most evident near the center of tile drawdown, so the initial focus was made on wetlands near the center of the wellfield alignment During meetings held with District staff, several wetlands were identified as preferable and review of these wetlands was given priority. Field review of wetlands (September 10, 2008 and again on October 28!h w/ District staff) took into consideration which wetlands were most likely to include at least two of the three target hydrologic zones (Transitional, Outer Deep, and Deep) as described in the WAP procedure. Additionally, preference was placed onwetlands that had indicators of historic normal pool and an intact or a relatively natural historic wetland / upland edge. Property access was also a concern and is still being coordinated for Wetland # 1. Proposed monitoring wetlands and the number of transects is described in detail below and graphically represented in Figure 3. Wetland #1 Wetland #1 is a large, shallow herbaceous marsh with a central shrubby wetland. This system transitions from a relatively wide transitional zone through an outer deep zone and finally into a deep shrubby pocket, which is dominated by a button bush (Cephalanthus occidentalis) community. Demarcation of the WAP zones will be conducted during the establishment of transects. Two (2) transects are proposed for this wetland system with.estimated locations provided on Figure

3. A photograph provided in Appendix A was taken along the proposed transect gradient. Final positioning of transects will be determined during the field installation andbased on best conditions and fieldjudgment. A natural wetland edge (saw palmetto fringe) still exists on the northeastern side of this wetland and will assist in defining historic normal pool levels. Species observed within this wetland including dominant,, subdominant, and observed vegetation areprovided, in Table I along with WAP classification.

PROGRESS ENERGY - CRYSTAL ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K Table 1: Wetland #1 - Documented Vegetation SPECIES COMMON NAME STATUS* CLASS Andropgon vinicus -. Broomsedge bluestem AD Observed Axonopus sp. Carpet grass AD Dominant Cephalanthusoccidentali,ý Buttonbush D Observed Cladium Jamaicense Sawgrass _- Observed Coreopsis floridana Florida tickseed Observed Diodia virginiana Rough button-weed ___ Dominant Eupatorium capillifblium Dogfennel AD Subdominant Eupatorium leptophyllum Falsefennel OD Subdominant Hydrocotyle umbellata _Pennywort OD Observed Hvptis /alaa Musky mint Observed Muhlenbergiacapillaris Ilairgrass I Dominant PPhyla nodi ora Frog-fruit AD I Dominant Pluchea odorala Sweetscent Observed Phichearosea Rosy camphorweed OD Observed Rhvnchospora colorata _Starrush white top Observed Sagiltarialancifolia Bulltongue arrowhead Observed Setariaparviflora Knotroot foxtail AD Observed AD - Adaptive, T - Transitional, OD - OuterrDeep, D - Deep Wetland #2 Wetland #2 is a moderate-sized herbaceous marsh with a deep-water center. This system may be-impacted by future activity to be permitted for the Suncoast Parkway extension,. We are currently coordinating with environmental staff working on that project to confirm impact potential. It is proposed that this wetland be maintained as part of this monitoring plan until these possible impacts occur: in the future. Impacts from this roadway project may not occur for many years, and valuable data may be collected in the interim. This system transitions from a relativelynarrow transitionaI zone to a deep-water pond dominated by white water-lily (Nymrphaea odorata). Demarcation ofthe. WAP zones will be conducted during the establishment of transects. Vehicular activity documented along the wetland edge does occur and may create some problems in maintaining transect poles and evaluation of the wetland. One (1) transect is proposed for this wetland system with an estimated location provided on Figure,3. Photographs provided in Appendix A were taken along the proposed transect gradient facing the upland and wetland. Final positioning of transect will be determined during the field installation and based on best conditions and field judgment. A natural wetland edge(saw palmetto fringe) still exists around the majority of this wetland and will assist in defining the historic norial'pool. Specics observed within this wetland including dominant, subdominant, and observed vegetation are provided in Table 2 along with. the WAP classification.

PROGRESS ENERGY - CRYSTAL ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K Table 2: Wetland #2 - Documented Vegetation SPECIES COMMON NAME ISTATU WAPS *[ CLASS Andropogon virginicus BrooS. AS DoCinant __________________________________ osedRe bluesteml AD JDmnn Axonopus sp. ,Carpet grass_ AD Subdominant Cephalanthusoccidentalis Buttonbush , ) Observed Eupatorium capillifolium Dogfennel AD Observed Fuirenascirpoidea Umbrella-sedge __Subdominant Ludwig ens _ Red-leaf ludwigia . .. Observed Nvmphaea odorata Whfite water-lily _ _Dominant Panicum hemitomon j MaidencaneJ Subdomi inant Phyla nodiflora Frog-fruit } AD Observed 11

AD - Adaptive, T- Transitional, OD - Outer Deep, D - Deep Wetland #3 Wetland;#3 is a moderate-sized herbaceous marshwith a central shrubby area. This system transitions from a transitional zone through an outer deep zone and finally into a deep pocket which is vegetated by a southern.willow (Salix caroliniana)area. Demarcation of the WAP zones will be conducted during the establishment of transects.

One (I) transect is proposed-for this wetland system with an estimated location provided on Figure 3. Photographs provided in Appendix A were taken along the proposed transect gradient facing the upland and wetland. Final positioning of transect will be determined during field installation and based on best conditions: and field judgment. A natural wetland edge (saw palmetto fringe) still exists along the, majority of the wetland. perimeter and will assist in defining the historic normal pool. Speciesobserved within, this wetland including dominant, subdominant, and observed vegetation are provided in Table 3 along with WAP classification.

PROGRESS ENERGY - CRYSTAL ENERGY COMPLEX ENVIRONMENTAL MANAGEMENT PLAN Conditions of Certification PA-77-09K Table 3: Wetland #3 - Documented Vegetation SPECIES I COMMON NAME

                                                                                    ~WAP STAT       JS   CASS Axonop~ussp.                                Carpet grass              AD         Observed Centella asiatica                              Spadeleaf                 T         Observed Cladiumjamaicense                                Sawgrass                           Observed Diodia virginiana                         Rough button-weed             OD         Dominant patOriumn cagpiltfolum                            Dogfennel                AD         Observed Eupatorium leptophnlum                             Falsefennel              OD         Observed Fuirenascirpoidea                            Umbrella-sedge                       Subdominant Hyptis alata                               Musky mint                           Observed Muhlenbergiacapillaries                            Hairgrass                          Observed Phyla nodiflora                                Frog-fruit              AD       Subdominant Pluchearosea                             Rosy camphorweed              OD         Observed Rhnchospora colorata                        , Starrush white top                    -Observed Saceharum giganteum                       Sugarcane plumegrass            OD       Subdominant Sagittariasp.                               Arrow-head..                         Observed Salix caroliniana                           Southern, willow            OD       Subdominant Spartina bakeri                            Sand cordgrass                         Observed

AD - Adaptive, T - Transitional, OD - Outer Deep, D - Deep 3.0 REPORTING As required by permit conditions, a summary report documenting the collected environmentatlmonitoring data will be prepared on an annual basis. The annual report shall be submitted tothe District by January I'* of each year and will summarize data from the previous water year (October I' - September 3 0 th).

Hydrologic and rainfall data shall also. be submitted on a monthly basis as described above and additionally will be compiled into the annual.report. Analysis~of hydrologic data and results of WAP monitoringwill be incorporated into each annual report and wilfcomply with conditions outlined within the permit. Table 4: Monitoring & Reporting Schedule

                *TASK                          RECORDING FREQUENCY                 REPORTING Water Level Measurement.(staff gages)          Bi-weekly (twice per month)          Monthly Water Level Measurement (piezometers)           Bi-weekly (twice per month)          Monthly WAP Assessment                  Semi-annually (MayMoJut

Rainfiill Daily & December) MonthlyE Annually

FIGURES 0-3 Mapped SE.13 )L Extent O0

                                   \0 Power Plant
                  *                     ~\ Welilf aid 40 I?

NORVLELL SRYýNT HWY N I I. WOZELLO TRL Progress Energy, Crystal River N Citrus County, Florida QU, .S 1- Figure 1 Sot: o gy Location 0 2 .735 Lake&w Onve V6Lmauma, FL 33598 Tel. 813.6420799 Miles Fax 813.642o3&0

N Progress Energy, Crystal River Citrus County, Florida QUE ST S e Ito yg Figure 2 0 1,000 735.Lakeview Drive Monitoring .Stations Wimaurma, FL 33598 Feet Tel 813.642.0799 Fax.813,642.0380 V J I

7 Legend J7 Hydrologic Station 0 Piezometer N Progress Energy, Crystal River W +E Citrus County, Florida S QUE ST ec- ology Figure 3 0 500 735"Lakeview Drive WAP Stations Wimauma, FL 33598 Feet Tel. 813.642.0799 Fax 813,642.0380 Id

APPENDIX A Photographic Documentation

Hydrologic Monitoring Station #1 - September 10, 2008 - Northeast side facing southwest. 7ý1,,--' ý,1 Hydrologic Monitoring Station #2,- September: 10, 2008,- East side facing west.

Wetland #1 - Proposed WAP Transect.- September 10, 2008 -Facing wetland. Wetland #2 - Proposed WAP Transect - September 10, 2008 - Facing upland. WCUand i 7Z - rroposeO WAr t ransect -. ?epteniner iv, zum~-

Wetland #3 -. Proposed, WAP Transect - September 10, 2008 - Facing upland. Wetland #3 - Proposect WAP i ransect - Neptemoer Iu, zLuuO

                                                        - Pacing wetiana}}

v t e Letter Sequence Other
TAC:ME0278, Elimination of Hydrogen Recombiners and Change to Hydrogen and Oxygen Monitors (Approved, Closed)
Initiation Request, Request Acceptance Supplement Administration Withholding Request Acceptance, Withholding Request Acceptance Meeting, Meeting Questions 20 April 2009 3 August 2009 10 August 2009 20 August 2009 14 August 2009 14 August 2009 11 September 2009 20 August 2009 31 August 2009 31 August 2009 31 August 2009 2 September 2009 22 September 2009 15 October 2009 3 November 2009 27 October 2009 1 December 2009 30 November 2009 2 February 2010 21 May 2010 2 June 2010 8 July 2010 8 July 2010 14 October 2010 8 November 2010 16 November 2010 31 March 2011 10 June 2011 30 June 2011 8 November 2011 Answers 9 October 2009 11 May 2009 11 September 2009 11 September 2009 18 September 2009 30 September 2009 2 October 2009 13 October 2009 22 October 2009 5 November 2009 12 November 2009 3 December 2009 30 December 2009 27 January 2010 3 March 2010 1 April 2010 5 November 2009 1 April 2010 21 June 2010 28 June 2010 28 June 2010 9 August 2010 12 November 2010 23 November 2010 16 December 2010 29 December 2010 25 February 2011 15 March 2011 26 April 2011 15 June 2011 20 July 2011 29 November 2011 Results Approval, Approval, Approval Other: 3F1109-06, State of Florida Department of Environmental Protection, Conditions of Certification, 3F1209-04, Response to Follow-up to Progress Energy RAI Responses on CR-3 SAMA Evaluation, ML090090233, ML090210171, ML090350657, ML090420362, ML090780840, ML091200415, ML091660559, ML091820465, ML092600889, ML092610309, ML093200023, ML093520079, ML100050166, ML100980517, ML100980519, ML100980520, ML100980523, ML100980524, ML100980525, ML100980526, ML100980528, ML101110235, ML101320401, ML101460577, ML110250183, ML110410597, ML110460629, ML110820185, ML110880294, ML11137A009, ML11140A100, ML11180A275, ML11343A639, ML12117A260, ML12213A058, ML12346A011
MONTHYEAR2009-06-10 [Table View]

3F1109-06, State of Florida Department of Environmental Protection, Conditions of Certification

Text

Dear Ms. Balcom:

Conclusion:

Conclusion:

Conclusion:

1.0 INTRODUCTION

6.0 CONCLUSION

SUMMARY

1.0 INTRODUCTION

6.0 CONCLUSION

Dear Mr. Nori:

1.0 INTRODUCTION

1.0 INTRODUCTION

Dear Mr. Cumbie:

Enclosures:

Dear Mr. Shrader:

Contact:

Contact:

Contact:

Contact:

1.0 INTRODUCTION

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