Text

(DCPP) 4th Quarter 2022 Report on Discharge Self-Monitoring
	ML23038A053
Person / Time
Site:	Diablo Canyon
Issue date:	01/18/2023
From:	Cortina D; Pacific Gas & Electric Co
To:	; Office of Nuclear Reactor Regulation, State of CA, Regional Water Quality Control Bd
References
	DCL-2023-502
	Download: ML23038A053 (1)
	v • d • e

,

PG&E Letter DCL-2023-502 I

January 18, 2023 Diablo Canyon Power Plant P. 0. Box 56 Avila Beach, CA 93424

Electronic Submission CIWQS Web Application California Regional Water Quality Control Board_

Central Coast Region Attn: Monitoring arid Reporting Review Section-895 Aerovista, Suite #101 San Luis Obispo, CA 93401-7906 In accordance with Order 90-09, NPDES No. CA0003751, the 4th Quarter 2022 report on Discharge Self-Monitoring at Diablo Canyon Power Plant (DCPP) is provided. This letter and supporting documents have been attached to the California Integrated Water Quality System (CIWQS) web application data submittal for the period. Discharge Self-Monitoring (DMR) Forms are includecj in the submittal.

Facility Name:

Address:

.Contact Person:

Job

Title:

Phone Number:

WDR/NPDES Order Number:

Type of Report: (check one)

Quarter: (check one):

Year:

Viol~tion(s) (Place an X by the appropriate choice).:

Pacific Gas & Electric Company Diablo Canyon Power Plant P.O. Box 56 Avila Beach, CA 93424 Trevor Rebel Manager, Environmental Protection (805) 441-5435 Order No. 90-09, NPDES No. CA0003751 QUARTERLY

~

ANNUAL 4th 2022 (Annual Reports for DCPP are Jan-Dec)

~ No (there are no violations to report)

Yes

PG&E Letter DCL-2023-502 CRWQCB Central Coast Region January 18, 2023 Page 2.

If Yes is marked (complete a-g):

a) Parameter(s) in Violation:

b) Section(s) of WDR/NPDES Violated:

c) Reported Value(s):

d) WDR/NPDES Limit/Condition:

e) Dates of Violation(s):

(reference page of report/data sheet) f) Explanation of Cause(s):

(attach additional information as needed) g) Corrective Action(s):

(attach additional information as needed)

(If "YES", see overview section of attached report)

PG&E Letter DCL-2023-502 CRWQCB Central Coast Region January 18, 2023 Page 3

I certify under penalty of law that this document, the CIWQS data submittal, and all associated attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. The results of the influent and effluent monitoring presented are the observed results of the measurements and analyses required by the monitoring program, and is neither an assertion of the adequacy of any instrument reading or analytical result, nor an endorsement of the appropriateness of any analytical or measurement procedure. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

If you have any questions or concerns regarding the report provided, or require additional information, please contact Trevor Rebel at (805) 441-5435.

Sincerely, Name:

David Cortina

Title:

Manager, Chemistry and Environmental Operations - Diab/a Canyon Power Plant 2023502/dma/nrh

PG&E Letter DCL-2023-502 CRWQCB Central Coast Region January 18, 2023 Page 4 cc:

Hardcopy Print-Out of CIWQS Web Application Submittal:

Mahdi Hayes NRC Senior Resident Inspector U.S. Nuclear Regulatory Commission Diablo Canyon Power Plant 104/5 Regional Administrator Licensing Assistant, Operations Branch U.S. Nuclear Regulatory Commission Region IV 1600 East Lamar Boulevard Arlington, TX 76011-4511 U.S. Nuclear Regulatory Commission Document Control Desk Washington, D.C. 20555-0001

PACIFIC GAS AND ELECTRIC COMPANY Fourth Quarter 2022 REPORT ON DISCHARGE MONITORING AT DIABLO CANYON POWER PLANT TABLE OF CONTENTS

~

OVERVIEW............................................-..... *............................... 1

SUMMARY

OF MONITORING PROGRAM A.

. 8.

C.

Monitoring of Plant Influent and Effluent.............-............. 2 Monitoring of Receiving Waters....................................... 3.

Sodium Bromide Treatment Program.............................. 3 APPENDIX 1: NPDES Discharge Points

OVERVIEW

1. During the 4th quarter of 2022, discharges occurred from Discharge Paths 001 (once through cooling water), 001B, 001D, 001E, 001F, 001G, 001H, 001J, 001L, 001N, 001P, 002, 003, 004, and 005 through 015. No discharges occurred from Discharge Paths 0011, 001 K, 001 M, 016 and 017. A list of all permit discharge pathways, including name and number, is provided in Appendix 1.

2. The substances listed in Table B of the California Ocean Plan were each analyz~d for and reported in the permit renewal appffcation and application updates for Diablo Canyon Power Plant (DCPP) submitted in 1994, 2001, and 2011. There have been no changes in activities conducted at the plant that would have significantly affected the results previously reported in the above referenced documents. Ocean Plan Table B substances not analyzed for this quarter were not added to any plant discharge streams.

3. Required annual reporting parameter for pathway 001 N Sludge Monitoring - quantity (during removal). Approximately 24.73 tons of water-saturated sludge was removed from the Diablo Canyon Sanitary Wastewater Treatment Unit in October 2022. The solid fraction of this material was measured at 1.1 %, making the removed mass 0.27 tons.

The method used by ES Babcock Labs for the annual Oil & Grease (HEM) in Sludge was EPA method 1664B. California ELAP does not currently support certification of this method matrix combination or any method for Oil & Grease in Sludge.

4. During the 4th Quarter of 2022, maintenance activities that required draining of closed cooling water systems were performed and are summarized below. PG&E received concurrence from the CCRWQCB in response to letters dated July 19, 1995 (PG&E Letter DCL-95-156), May 23, 1996 (PG&E Letter DCL-96-522), and May 19, 1997 *

(PG&E Letter DCL-97-533) regarding the use of glutaraldehyde and isothiazolin to control microbiological growth and corrosion in DCPP's closed cooling water systems.

Discharges are drained at a flow rate such that the chronic toxicity level remains below the "No Observable Effect Concentration" (NOEC) at NPDES Discharge 001.

Volume Glutaraldehyde lsothiazolin Total Oil & Grease Date System Suspended (gallons)

(mg/I)

(mg/I as Ci-)

Solids (mg/I)

(mg/I) 10/20/22 Unit-2 sew 2180 n/a 0.630

<2.0

<1.4

5. 8 events affected the results of continuous chlorine monitoring at Discharge 001 during the 4th Quarter 2022. For these events, an engineering evaluation was subsequently completed as authorized by the Regional Board in accordance with PG&E's January 5, 1994 letter. Engineering evaluations were based on condenser water box chlorine-measurements, recorded chemical injection rates, circulating water pump status, and discharge chlorine readings before and after the periods in question. Based on these factors, ~stimates for results during the affected periods were generated. Event intervals, affected monitor, number of affected results, the cause(s), and corrective action(s) have been tabulated below. Results from the engineering evaluations were all below the applicable 89-µg/L Ocean Plan calculated discharge limit.

Interval Affected Affected Cause Corrective Actions Monitor Readings 10/19/22 -

U1 6

Biofouling of the monitor

_ Monitor cleaned and 10/20/22 returned to service 11/14/22 U1 1

Biofouling of the monitor Monitor cleaned and returned to service 11/20/22 -

U1 6

Biofouling of the monitor Monitor cleaned and 11/21/22 returned to service 11/10/22 -

U2 9

Biofouling of the monitor

Monitor cleaned and 11/17/22 returned to service.

12/6/22 -

U2 5

Biofouling of the monitor Monitor cleaned and 12/7/22 returned to service 12/13/22 U2 1

Biofouling of the monitor Monitor cleaned and returned to service 12/16/22 U2 1

Biofouling of the monitor Monitor cleaned and returned to service 12/22/22 -

Monitor cleaned and I

12/24/22 U2 12 Biofouling of the monitor returned to service

6. During review of the 4th Quarter third-party laboratory analytical data, it was discovered that the sample collection time was incorrectly recorded on the chain of custody and subsequently reported incorrectly on the analytical report for the intake metals analysis.

Follow-up investigation revealed that the sample time was incorrectly recorded an hour

earlier than the sample was collected.

SUMMARY

OF MONITORING PROGRAM A.

Monitoring of Plant Influent and Effluent

1. The results of the 2022 October, November, and December plant influent and effluent monitoring have been reported via the CIWQS web application to which this letter is attached.

2. The laboratory report for one acute bioassay on water sampled from Discharge 001, performed Nov 9th through Nov 12th, 2022, is attached to this CIWQS application submittal. The acute bioassay results show that toxicity was 0.00 TUa.

3. The laboratory report for one chronic bioassay on water sampled from Discharge 001, performed Nov 9th through Nov 11 th, 2022, is attached to this CIWQS application submittal. The chronic bioassay results show that toxicity was 1.00 TUc (no chronic toxicity).

B.

Monitoring of Receiving Waters

1.

Ecological Studies at Diablo Canyon Ecological studies in the vicinity of Diablo Cove conducted during the fourth quarter continued under the Diablo Canyon Receiving Water Monitoring Program (RWMP) as requested in a letter from the Central Coast Regional Water Quality Control Board (CCRWQCB) dated December 9, 1998, and as detailed in a letter (PG&E Letter DCL-99-503) dated January 8, 1 ~99. This program includes tasks from the Ecological Monitoring Program (EMP) with additional stations and increased.

sampling frequencies. The RWMP replaces the EMP and the Thermal Effects Monitoring Program (TEMP).

2.

In Situ Bioassay Results of the Mussel Watch Program will be reported to the CCRWQCB directly from the Moss Landing Marine Laboratories MLML (administered by San Jose State University) in their periodic report for this program.

C.

Sodium Bromide Treatment Program Diablo Canyon Power Plant is continuing the use of sodium bromide and sodium hypochlorite to control macrofouling growth for both Units. Both circulating water conduits of each Unit can be chemically treated simultaneously. Each treated conduit typically receives a twenty-minute injection every four hours (six injections a day) of sodium bromide in combination with sodium hypochlorite.

Each chemical injection treatment attempts to achieve a target concentration in the range of 250-300 parts per billion (ppb) Total Residual Oxidant (TRO) when measured at the inlet waterbox of the condenser. Discharge TRO concentrations measured at the plant outfall remained below NPDES permit limitations and the calculated Ocean Plan limit throughout the quarter, with exception of the event described in Overview Item 6.

Both Unit~1 conduits were treated with simultaneous injections of sodium bromide and sodium hypochlorite six times per day throughout most of the.4th Quarter. An extended interruption in Unit-1 Conduit 1-2 treatment occurred during mid-October due to scheduled maintenance on the injection system discharge header. Three brief interruptions also occurred in late-October and mid-November due to scheduled intake maintenance activities.

Unit-2 sodium bromide injections were secured in early-October in preparation for the scheduled 2R23 refueling outage. All chemical injections to Unit-2 Conduits were subsequently secured from mid-October through mid-November during the scheduled 2R23 refueling outage. Chemical treatment of Unit-2 was then initiated in late-November following outage completion. Unit-2 conduit treatment continued for the remainder of the 4th Quarter.

APPENDIX 1 DIABLO CANYON POWER PLANT NPDES DISCHARGE POINTS DISCHARGE NUMBER DESCRIPTION 001 Once-Though Cooling Water 001 A Firewater Systems 001 B Auxiliary Salt Water Cooling System 001 C Discharge Deleted 001 D Liquid Radioactive Waste Treatment System 001 E Service Cooling Water System 001 F Turbine BuildinA Sump 001 G Make-Up Water System Waste Effluent.

001 H Condensate Demineralizer Regenerant 001 I Seawater Evaporator Slowdown 001 J Condensate Purnps Discharge Header Overboard 001 K Condenser Tube S,heet Leak Detection Dump Tank Overboard 001 L Steam Generator Slowdown 001 M Wastewater Holding and Treatment System 001 N Sanitary Wastewater Treatment*

System 001 P Seawater Reverse Osmosis System Slowdown 002 Intake Structure Building Floor Drains 003 Intake Screen Wash 004 Bio Lab and Storm Water Runoff 005,008,009,013,014,015 Yard Storm Drains 006,007,010, 011,012 Storm Water Runoff 016 Bio Lab Seawater Supply Pump Valve Drain 017 Seawater Reverse Osmosis System_

Slowdown Drain

CIWQS Web Application Submittal Print Out and Attached :Supporting-Documents

eSMR PDF Report Summary: Quarterly SMR ( MONNPDES ) report for Q4 2022 Summary: Quarterly SMR ( MONNPDES ) report for 04 2022 submitted by david cortina (Chemistry and Environmental Services Manager) on Facility Name: PG&E Diablo Canyon Power Plant Waterboard Office:

Region 3 - Central Coast Report Effective Dates:. 10/01/2022 - 12/31/2022 No Discharge Periods Name ::

Diablo M-001 Diablo M-0010 Diablo M-00lF Diablo M-00lG Diablo M-0OlH Diablo M-001I Diablo M-00lJ Diablo M-00lK Diablo M-00lL Diablo M-0OlM Diablo M-00lN Diablo M-00lP Diablo M-002 Diablo M-003 Diablo M-004 Diablo M-005 Diablo M-008 Diablo M-009 Diablo M-013 Diablo M-015 Diablo M-016 Diablo M-017 Diablo M-INF Self-Determined Violations No Violations Entered Attachments

,. * : <.. DescriptiQn,.

Page 1 of 31 Order Number:

R3-199'0-0009 Case Worker:

Peter Von Langen

/ '.: .

.. /::Dates

'con'iments 10/01/2022 - 12/31/2022 Plant Seawater Evaporators no longer in service.

12/01/2022 12/31/2022 10/01/2022 - 12/31/2022 Plant Condenser Tube Sheet Leak Detection Dump Tank no longer in service.

10/01/2022 - 12/31/2022 Waste Holding and Treatment System (WHAT) not discharged during 4Q22.

Discharge is intermittent, used as reauired.

10/01/2022 - 12/31/2022 Bio Lab Seawater Supply Line Valve Box not drained during 4Q22. No effluent discharaed.

10/01/2022 - 12/31/2022 Seawater RO System Blowdown Line not drained during 4Q22. Discharge rarelv used.

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11/03/2022 13:10:00 1

11 m.,,r,n-,-,

12/01/2022 10:10:00 1

,.,,n, nn-,-,

10/12/2022 09:35:00

1 1 ()/7 "Jn()??

10/12/2022 09:35:00 1

1 n11-,,-,,.,-,-,

11/03/2022 10:40:00 1

11,,,.,,,-,,,.,-,

12/01/2022 10:28:00 1

1., /C\\l,-,,,.,.,

10/13/2022 09:15:00 1

1 nl'>7/?()')'>

Page 5 of 31

..*. *" MOL,

.Result; ML,

Units'.'.

RL.

ND 9.7 mg/Kg

= 6.4 SU

= 10000 mg/Kg

= 76000 mg/Kg

= 11 ppth

= 740 mg/Kg ND mg/L

=8 mg/L

= 6.4 mg/L ND mg/L ND mg/L

= 7,6 SU

= 7.81 SU

= 8.27 SU ND mg/L

= 7.8 SU

= 7.83 SU

= 8.26 SU ND ug/L 1.4 2

1.4 1.4

.06

'Rfitf~wr: * * '";;"

,.?:

Priority;

*i

QA*Codes Comment~

No No No No No No No No No No No No No No No No No No No Data Source*

CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF Analytical Cal culated_01172023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_01172023.

zip

"* ':1 '

y, '¢ol!~hi6n.*. <,cSample Method,, ""'Type, i Location

.. Depth ( mF* ' - ;.. Matrix M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF Calculated Values

*:*con~.c1:10.;

'Method,.

De th m water water water water water water water water water water water water water water water water water water sali!ple'

,,,Type, *

fMafrix

,*\\:?:?/ ' '.::(,:::-:;~,;\\~~3;;:, ~,,

,,<~~.. '\\J:~h

Parallleter,

.. i'..

. ':'\\,. Arialvtical Methocf. '::: *

Cadmium, Total E200.8 Cyanide, Total (as CN)

A4500CC Lead, Total E200.8 Mercury, Total E1631 PCB-1016 SW8082 PCB-1221 SW8082 PCB-1232 SW8082 PCB-1242 SW8082 PCB-1248 SW8082 PCB-1254 SW8082 PCB-1260 SW8082 pH A4500H pH A4500H pH A4500H Phenols, Chlorinated DU Phenols, Non-chlorinated DU Silver, Total E200.8 Titanium, Total DU 10/13/2022 ND

.003 09:15:00 l

ug/L No 1nn? nn??

10/13/2022 ND 09:15:00 1

mg/L 1 nnF.nn??

10/13/2022 ND 09:15:00 1

ug/L 1nn7nr,-,-,

10/13/2022 OQ:15:00 1 n,1,,-,n-,-,

10/13/2022 09:15:00 11,n-:,.nnr, 10/13/2022 09:15:00 11,r,-:,.r,r,-,-,

10/13/2022 09:15:00 71,n-:,.r,r,-,-,

10/13/2022 09:15:00 11,n-:,.nn??

10/13/2022 09:15:00 11m,,-,r,-,-,

10/13/2022 09:15:00 11,n-:,.nn-,-,

10/13/2022 09:15:00 11,n-:,.nr,-,-,

10/06/2022 09:40:00

-,nmF.r>nT>

11/04/2022 09:03:00 11 ",-,r,-,-,

12/01/2022 09:15:00

,-,,r,,,-,,,-,-,

10/13/2022 09:15:00

, n11 onn-,-,

10/13/2022 09:15:00 1n11n,-,r,-,-,

10/13/2022 09:15:00

, nn7,.,,,.,.,

10/13/2022 09:15:00 A

1 1

1

'sa~pie D~til,

. Field 'R.ep, Sample Time; * -

Lab Rep,,

Anal sis Date..

-lab Batch*:.;A Page 6 of 31 DNQ 0.18 ng/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

= 7.93 SU

= 7.7 SU

= 8.09 SU ND ug/L ND ug/L DNQ 0.006 ug/L ND mg/L

.02

.05

.06

.5

.032

.567 3.031

.004

.02

.00074

.005 No No No No No No No No No No No No No No No No No

Mofa?' i';Revie1,\\(1; J\\11.L, ;

Priority,

RV A Codes CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zio CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal

.culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip

, c:Jiiei:tio,t

'"sampie

,s:,,,

,'(

Sample Qate; * '.Field Rep,

(}/

, /;,,,

,* s'iteliiew

,,., :,., *. '(.* ::<

,1,t*' **:

~esult; ;

,, tJIDL, Method,'

Type, Parameter, San1pleiime, Li!b Rep, ML,",

,*Priority, Location Deoth Cril):

, '*Matrix Calculation Tvoe

", Analvsis Date

,, Lab.Batch

Units,

,RL QA Codes

Comments :,,

',Data Source<,,,'

M-001 Chlorine Usage 10/01/2022

= 337 Monthly avg result.

CDF _Analytical_Cal 00:00:00 1

No water 30-Day Avg of Daily Avgs lb/day See Attachment 1, culated_0ll 72023.

1 '"'",-,,.,-,-,

Tab 2 zip M-001 Chlorine Usage 11/01/2022

= 387 Monthly avg result.

CDF _Analytical_Cal 1

No water 30-Day Avg of Daily Avgs 00:00:00 lb/day See Attachment 1, culated_0ll 72023.

1, *--,-.,.,-,-.

Tab 3 zip M-001 Chlorine Usage 12/01/2022

= 450 Monthly avg result.

CDF _Analytical_Cal 1

No water 30-Day Avg of Daily Avgs 00:00:00 lb/day See Attachment 1, culated_0ll 72023.

1 ?/,1 /?()??

Tab 4 zip M-001 Chlorine, Total Residual 10/01/2022

= 31 Monthly avg result.

CDF _Analytical_Cal No water 30-Day Avg of Daily Maxs 00:00:00 1

ug/L See Attachment 1, culated_0ll 72023.

1nn,nn-,-,

Tab 2 zip M-001 Chlorine, Total Residual 11/01/2022

= 42 Monthly avg result.

CDF _Analytical_Cal 00:00:00 1

No See Attachment 1, water 30-Day Avg of Daily Maxs ug/l culated_0l172023.

111-:,nnn??

Tab 3 zip M-001 Chlorine. Total Residual 12/01/2022

= 44 Monthly avg result.

CDF _Analytical_Cal 00:00:00 1

No water 30-Day Avg of Daily Maxs ug/l See Attachment l, culated_0ll 72023.

1 ?/:il,-,,.,-,-,

Tab 4 zip M-001 Flow 10/01/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

,nm,,-,n-,-,

zip M-001 Flow 10/02/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

1('\\/('\\')/')('\\')')

zio M-001 Flow 10/03/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

, nm-:inn??

zip M-001 Flow 10/04/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

, "'"A,-,,.,-,-,

zio M-001 Flow 10/05/2022

= 2486 CDF_Analytical_ Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

1 nm~nn??

zip M-001 Flow 10/06/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

,n,n,;r,r,-,-,

zip M-001 Flow 10/07/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

1nm7nn,,

zip Flow 10/08/2022

= 2486 CDF _Analytical_Cal M-001 No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

,M"")(1')')

zip Flow 10/09/2022

= 2486 CDF _Analytical_Cal M-001 No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

,,.,,,.,,,,-,n-,-,

zio Flow 10/10/2022

= 2486 CDF _Analytical_Cal M-001 No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

1('\\/1(1/')('\\')')

zio M-001 Flow 10/11/2022

= 2486 CDF _Analytical_Cal No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

1n111,-,,.,-,-,

zip Flow 10/12/2022

= 2486 CDF _Analytical_Cal M-001 Daily Discharge 00:00:00 1

No water MGD culated_0ll 72023.

1 (\\/1 ?/?r\\??

zip Flow 10/13/2022

= 2486 CDF _Analytical_Cal M-001 No water Daily Discharge 00:00:00 1

MGD culated_0l 172023.

1(1/1-:l/')('\\')')

zip Page 7 of 31

1/.}

, if{

Collection*'.. *, s.:. nliiii!':< :

'\\ '{>. ~".,,,c: _:ii{

/~'ainpl~ Date,,

.fii;;1d Rep]::.,

- - /'

i:'\\"<

'*ies~~;;\\ ;r-ioi.:,

1.Jteviewi' k t;,

'< *)It

'.§"'r~:..

Method,.,

"~?::-'

I Location/

Type,'.*,*.

.,,}

Parameter, Sample Time/.

Lab Rep;,,

, ML, i>rioraty, 1,.,

Death (m)*** I.*

Matrix':'.

i:aicu'lation Tvce,

Analv:Sis Date.

Lali*Batch*

Unit:S' RL *.. *QA codes I -c,-*,i::cirrirri'erits <;;*.*

i>ata s;;iirc:~

Flow 10/14/2022

= 2486 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

culated_01172023.

MGD 1 ()fl 11/?nT'J zip Flow 10/15/2022

= 2486 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_0l172023.

1 "'l 'i/?O??

zip M-001 Flow 10/16/2022

= 1931 No CDF _Analytical_Cal water Daily Discharge 00:00:00 1

MGD culated_01172023.

..,.,.... c,..,,............

zip Flow 10/17/2022

= 1862 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

, n117 /?O??

zip Flow 10/18/2022

= 1291 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_0l172023.

1n11Rnn,?

zip Flow 10/19/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

1 n11 Q/?O??

zip Flow 10/20/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_01172023.

,nnnnn??

zip Flow 10/21/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_01172023.

, nn 1 /?O??

zip Flow 10/22/2022

= 1239 CDF _Analytical_Cal M-001 00:00:00 1

No culated_01172023.

water Daily Discharge MGD 1nn,r,n-,-,

zio M-001 Flow 10/23/2022

= 1239 No CDF _Analytical_Cal water Daily Discharge 00:00:00 1

MGD culated_0l172023.

, nn,nn??

zip Flow 10/24/2022

= 1239 No CDF _Analytical_Cal M-001 00:00:00 1

water Daily Discharge MGD culated_0l172023.

1nr>l[/?f)'.)'.)

zip Flow 10/25/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_01172023.

,nnr:.nn"l"J zip Flow 10/26/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_01172023.

,,.,..~-*----

zip Flow 10/27/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_0ll 72023, 1 ()J?7 /?0?~

zic Flow 10/28/2022

= 1239 CDF _Analytical_Cal M-001 No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

,nnP.nn,..,

zip Flow 10/29/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

,nnann??

zip Flow 10/30/2022

= 1239 No CDF _Analytical_Cal M-001 00:00:00 1

water Daily Discharge MGD culated_0ll 72023.

1 'l/'lO/?O??

zip Flow 10/31/2022

= 1239 CDF _Analytical_Cal M-001 No water Daily Discharge 00:00:00 1

MGD culated_0ll 72023.

l O"l /?n??

zip Flow ll/01/2022

= 1239 No CDF _Analytical_Cal M-001 water Daily Discha_rge 00:00:00 1

MGD culated_01172023.

11 '"l nn?,

zip Page 8 of 31

M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water Flow Parameter, *

- calculationTvne..

Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge

,' Sample Date; ; fi~ld Rep;,\\

T I MDL,

!'iieview

' SamplkTiITle,

Lab Rep,.'

R~suit:

ML,

<.:Priority, Analvsis Date Lafraatch *

/** Units RL

QA Codes 11/02/2022 00:00:00

,,,rnnr,-,-,

11/03/2022 00:00:00 11 m-,,nn??

11/04/2022 00:00:00 711111,nr,-,-,

11/05/2022 00:00:00

,,,n~nn-,-,

11/06/2022 00:00:00 11,n"nn??

11/07/2022 00:00:00 77,n7,-,r,-,-,

11/08/2022 00:00:00

,, JnQ/?(1')')

11/09/2022 00:00:00 11 inann??

11/10/2022 00:00:00 11 /1 r,r,r,-,-,

11/11/2022 00:00:00

,, 11, rrn,,

11/12/2022 00:00:00 1111-,r>n??

11/13/2022 00:00:00 1,,,..,,-,r,-,-,

11/14/2022 00:00:00 11 /1 A/?n?,

11/15/2022 00:00:00 71 /7 ~,-,,,-,-,

11/16/2022 00:00:00 11 /1 "-nr,,-,

11/17/2022 00:00:00

,, /17/')(1')')

11/18/2022 00:00:00

,, n ann-,-,

11/19/2022 00:00:00 1111 ann??

11/20/2022 00:00:00

,, r,r,r,r,-,-,

Page 9 of 31 1

1 1

= 1239 MGD

= i239 MGD

= 1239 MGD

. = 1239 MGD

= 1239 MGD

= 1535 MGD

= 1862 MGD

= 1862 MGD No No No No No No No No No No No No No No No No No No No

. iComrilents*

. '. Data Source *. \\ *.

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Sampl~ Date; *.

,sarnpleTirne,:.

"Analvsis Date*.

11/21/2022 00:00:00 11 /?1/?Cn'>

11/22/2022 00:00:00 11 n?nn??

11/23/2022 00:00:00 11/24/2022 00:00:00 11 nl!nn??

ll/25/2022 00:00:00 11nr;J?n??

11/26/2022 00:00:00 11 l?f,/?O??

11/27/2022 00:00:00 11rnnn??

11/28/2022 00:00:00 7 1,-,o,-,,-.-,-,

11/29/2022 00:00:00

,,nonn?,

11/30/2022 00:00:00

,,,.,nnn??

12/01/2022

00:00:00 1 ?/01 nn-,-,

12/02/2022 00:00:00

,,,m,nn??

12/03/2022 00:00:00 12/04/2022 00:00:00

,-,m,inn?,

12/05/2022 00:00:00

,-,,r,r:,nn??

12/06/2022 00:00:00

,-,,n,;nn,?

12/07/2022 00:00:00 1'>/07/?11??

12/08/2022 00:00:00 12/09/2022 00:00:00

,-,inonn??

Page 10 of 31 1

1 1

= 1932 MGD

= 1862 MGD

= 2390 MGD

= 2486 MGD

= 2486 MGD No No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll72023.

zip CDF _Analytical_Cal cu lated -'-01172023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_0l 172023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip

1* **<:

***'...* Coll~ctiriri\\1/C: sci'mp.'iil>'

Method,*

Type{;

Lo~~tion*.

t>eoth (m)

. Matrix*.

/;'.". f{\\ara:~te;, \\ ir *

. :Calc*ulatlon Tvoe M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge M-001 water Flow Daily Discharge SamplewDate;., :':~' Ff~ld:Rep,~

Sample,Time.,

Lab*Rep; **

Analvsis:oate ***. Lab Batch 12/10/2022 00:00:00 1

,-,,,n,-,n-,-,

12/11/2022 00:00:00 1

1 ?/11 /")/Y)?

12/12/2022 00:00:00 1

1?/1'">nn-,-,

12/13/2022 00:00:00 1

1?11-:inn?">

12/14/2022 00:00:00 1

1?/1Al?/l?")

12/15/2022 00:00:00 1

1?/1 ~/?ll??

12/16/2022 00:00:00

, -,,, c:.nn-,-,

12/17/2022 00:00:00 1 ")/171?/l")")

12/18/2022 00:00:00 1 ?/1 Q/'){\\')')

12/19/2022 00:00:00 1 ?/1 Q/")/l?"l 12/20/2022 00:00:00 1 ?l?ll/?/l?")

12/21/2022 00:00:00

,-,,-,, nn?-,

12/22/2022 00:00:00 1 ?l")')/")/l??

12/23/2022 00:00:00 1?f?'O/')r,-,-,

12/24/2022 00:00:00 l ?f?A,-,r,-,-,

12/25/2022 00:00:00

,.,,.,~/"){\\")")

12/26/2022 00:00:00

,-,,-,,::.nn-,-,

12/27/2022 00:00:00 1 ")/")7/")/l")'"l 12/28/2022 00:00:00 7-,nonn-,-,

Page 11 of 31 1

1 1

MDC. R':viiW

... ~esult, Mi.;

~nonty,

- - Units.\\

RL\\t QA Codes

= 2486 MGD

= 2486 MGD.

= 2486 MGD

= 2486 MGD No No No No No No No No No No No No No No No No No No No

>t. r

. :.Data 56urce:* :

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated Oll72023.

ZiD CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip*

CDF _Analytical_Cal culated Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

zio CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

.',.. Jf ;f> Collectiori,.

, ; : <l'll~thod/

.(c:icatio~

. ;Death (in)

M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 Sample I *v

'.'\\;"..

"\\.

. ~~~;i~ ; I :1":f(. :.i~*rci~;;;Jt~e water water water water water water water water water water water water water water water water water water water Flow Daily Discharge Flow Daily Discharge Flow Daily Discharge Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average 12/29/2022 00:00:00

, ?l?Q/?0??

12/30/2022 00:00:00 1 ?1'10/?0??

12/31/2022 00:00:00

,..,,,,,n,n, 10/01/2022 00:00:00 10/01 /')(\\')')

10/02/2022 00:00:00

, (\\/(\\')/?(\\??

10/03/2022 00:00:00

,nm,nn,,

10/04/2022 00:00:00 1(\\/r\\Al?r\\?'l 10/05/2022 00:00:00 1 ""'~,....,.,........

10/06/2022 00:00:00

, (\\/(\\",/?(\\??

10/07/2022 00:00:00 1 ')/07/?0??

10/08/2022 00:00:00 1 ()/OR/?O??

10/09/2022 00:00:00 1(\\<M'><'>O??

10/10/2022 00:00:00

.,,...,.,,....,,ri??

10/11/2022 00:00:00

, "111 nn,,

10/12/2022 00:00:00 1 "'l ?/?O??

10/13/2022 00:00:00

, n,,,t?O??

10/14/2022 00:00:00 10/1 A.J?O??

10/15/2022 00:00:00 1 (\\/1 ~/')(\\')')

10/16/2022 00:00:00 1 (\\/1 ",/?0??

Page 12 of 31 1

1 1

Result/*

t.fnits

= 2486 MGD

= 76.2 Degrees F

= 75.8 Degrees F

= 74.8 Degrees F

= 74.3 Degrees F

= 74.6 Degrees F

= 75.9 Degrees F

= 76.1 Degrees F

= 75.6 Degrees F

= 75.2 Degrees F

= 75.8 Degrees F

= 76 Degrees F

= 75.7 Degrees F

= 75.9 Degrees F

= 73.7 Degrees F

= 69,5 Degrees F MDL,/, ?'Review.1.,...... *;,;.

Mt,.

Priority(

RL

' QA Codes No No No No No No No No No No No No No No No No No No No

?<

'*;,~~,,,

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

' ;;r: *;

'i""ctinecl:iori

,. l~;t:r:

h

'.. *. ;;,;/*

. :::;;, sampie bate;.

FieJd Rep,

,~y***~*

MDL, ilieview+I:. :. l

.*.*1)~!~1::{

,Method,

Par_;meter

s~mple iime1*

,~~~ult,

'::'.t"-

Lab Rep,*.

.ML,"

Priority,

w"*,

Locatirin*

Depth (m)

Calculation Tvoe

. Analvsis Date Lab Batch Units.

'RL QA Codes

'Comments

.Data Source M-001 Temperature 10/17/2022

= 69.7 No CDF _Analytical_Cal water 24-hour Average 00:00:00 1

Degrees F culated_Oll72023, 1 (\\/17 f?fl??

zip M-001 Temperature 10/18/2022

= 75.5 CDF _Analytical'-Cal 00:00:00 1

No water 24-hour Average Degrees F culated_Oll72023.

, fl/1 ~/?(\\??

zip M-001 Temperature 10/19/2022

= 76,5 CDF _Analytical_Cal 00:00:00 1

No water 24-hour Average Degrees F culated_Oll 72023.

, (\\/1 Q/'){\\')')

zio M-001 Temperature 10/20/2022

= 77.2 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Ol 172023.

l (\\/?()/')fl')')

zip M-001 Temperature 10/21/2022

= 77.3 CDF _Analytical_Cal 00:00:00 1

No water 24-hour Average Degrees F culated_Oll 72023, 1nn1 l?O??

zip.

M-001 Temperature 10/22/2022

= 77.7 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1 (\\/')')f?fl??

zip M-001 Temperature 10/23/2022

= 77.1 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

, (\\/?">J?fl')')

zip Temperature 10/24/2022

= 76.8 CDF _Analytical_Cal M-001 No water 24-hour Average 00:00:00 1

Degrees F culated_Oll72023.

l n,-, /')A')')

zip M-001 Temperature 10/25/2022

= 77.2 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Oll72023.

1 (\\/')~/?fl??

zip M-001 Temperature 10/26/2022

= 75.1 No CDF _Analytical_Cal water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1nn{'.rJ(l')')

zip Temperature 10/27/2022

= 74.4 CDF _Analytical_Cal M-001 No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

, nn,nn??

zip M-001 Temperature 10/28/2022

= 75.3 No CDF _Analytical_Cal water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1nno,1')fl')')

zip M-001 Temperature 10/29/2022

= 75.3 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1no')A,-,A-,')

zip M-001 Temperature 10/30/2022

= 74.8 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1 (\\/<11/?fl??

zip M-001 Temperature 10/31/2022

= 74.4 CDF _Analytical_Cal No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

, n,.,1 /?fl??

zip Temperature ll/01/2022

= 74.9 CDF _Analytical_Cal M-001 00:00:00 1

No water 24-hour Average Degrees F culated_Oll 72023.

1im1no??

zio Temperature ll/02/2022

= 74.9 CDF _Analytical_Cal M-001 00:00:00 1

No water 24-hour Average Degrees F culated_Oll 72023.

11 /{\\'}/')(\\?')

zip M-001 Temperature ll/03/2022

= 74 No CDF _Analytical_Cal water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1' On">O'>A-,')

zip Temperature ll/04/2022

= 73.3 No CDF _Analytical_Cal M-001 water 24-hour Average

00:00:00 1

Degrees F culated_Oll 72023.

11,n4/')fl')?

zip Page 13 of 31

M-001 M-001 M-001 M-001 M-001 M-001

(

M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 water water water water water water water water water water water water water water water water water water water Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Sarppl~g13t~;

':.'.field Rep, 0 Sample Tiirie;i *.

Lab Rep'.."

Anatvsis Date

Lab Batch 11/05/2022 00:00:00

,,m~nn,,

11/06/2022 00:00:00 11 lnfi/?O??

11/07/2022 00:00:00 11,A~,-.A,')

11/08/2022 00:00:00

,, mqnn,,

11/09/2022 00:00:00

,, mrinn,,

11/10/2022 00:00:00

,,,, nnn??

11/11/2022 00:00:00 11/11/?0??

11/12/2022 00:00:00 1111,nn,,

11/13/2022 00:00:00

, 111 '>nn?,

11/14/2022 00:00:00

, 111,inn,-i 11/15/2022 00:00:00

,,,, ~nn,?

11/16/2022 00:00:00 11 /1 "-1?0??

11/17/2022 00:00:00 11 /1 7 /')(\\,,

11/18/2022 00:00:00 1111 R/?0??

11/19/2022 00:00:00 1111 ano??

11/20/2022 00:00:00

,, r>')/70??

11/21/2022 00:00:00

.,,n1nn??

11/22/2022 00:00:00 11,,-.1?0??

11/23/2022 00:00:00

,, n-:,,nn??

Page 14 of 31 1

1 1

= 73.2 Degrees F

= 72.9 Degrees F

= 73.7 Degrees F

= 74.2 Degrees F

= 74.3 Degrees F

= 72.2 Degrees F

= 67.3 Degrees F

= 66.9 Degrees F

= 66.7 Degrees F

= 66.9 Degrees F

= 67.2 Degrees F

= 66.9 Degrees F

= 67.1 Degrees F

= 67.3 Degrees F

= 66.9 Degrees F

= 67.1 Degrees F

= 66.6 Degrees F

= 67.5 Degrees F

= 67.6 Degrees F No No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Oll72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip

... '.",* Y'. ' 'Ci>llectii:>n

,*),,

Methe>~, i, Loc'atiorf I Depth Cm),

M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001

']sample :,r

'Type:.

,*** > *'Y'<c

. }:

, Par~{meter, Matrix I

water water water water water water water water water water water water water water water water water water water

. Calcidation Tvoe Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average

S'al~iPle* Date, "'*

Sample Time;'

Analvsis Date 11/24/2022 00:00:00 111?4/70??

11/25/2022 00:00:00

,, r><;/?O??

11/26/2022 00:00:00 11,-,,, -~~~~

11/27/2022 00:00:00 11,-,-, /?O??

11/28/2022 00:00:00

,, t'l'l/?O??

11/29/2022 00:00:00

,, nrinn??

11/30/2022 00:00:00 111,n/?O??

12/01/2022 00:00:00

,-.. M

,-,A")')

12/02/2022 00:00:00 1 ?/0?/70??

12/03/2022 00:00:00 1-im-:,,nn??

12/04/2022 00:00:00 1 ?tnll/?0??

12/05/2022 00:00:00 1-i,n<,,J?o??

12/06/2022 00:00:00 12/07/2022 00:00:00 1 ?tn7J?n??

12/08/2022 00:00:00 1 ?tnA/?0??

12/09/2022 00:00:00 1 ?/00/?0??

12/10/2022 00:00:00 1?/l 01-in-i-i 12/11/2022 00:00:00 1 ?/11 /?0??

12/12/2022 00:00:00 1'll1')/?0?'J Field.Rep; Lab Rep,.

Lab Batch.

1 1

1 Page 15 of 31

Result,

- .units

= 66 Degrees F

= 69.5 Degrees F

= 70.2 Degrees F

= 73.2 Degrees F

= 74.6 Degrees F

= 74.5 Degrees F

= 74.6 Degrees F

= 75 Degrees F

= 75.4 Degrees F

= 75.5 Degrees F

= 75.3 Degrees F

= 75.9 Degrees F

= 76.2 Degrees F

= 76.3 Degrees F

= 77 Degrees F

= 76.9 Degrees F

= 77 Degrees F

= 76.7 Degrees F

= 77 Degrees F

'.'r;;fa ML.'

RL

/." **Review Priorit:y, QA Codes*

No No No No No No No No No No No No No No No No No No No

Comments CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal

culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water Temperature 24-hourAverage Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hoi.Jr Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average 12/13/2022 00:00:00

, '.)/1,nn??

12/14/2022 00:00:00 1'.l/lil/?O??

12/15/2022 00:00:00

,,.,,, <;f'.)('l'.)'.)

12/16/2022 00:00:00 12/17/2022 00:00:00 1 '.l/17 /?O??

12/18/2022 00:00:00

, '.)Jl Q/'.)(l'.)'.)

12/19/2022 00:00:00

,.,,, Q/'.)0'.)'.)

12/20/2022 00:00:00 12/21/2022 00:00:00 1 ">/2100??

12/22/2022 00:00:00

, ")J'.)'.)/?0??

12/23/2022 00:00:00

,-,n-,.nn??

12/24/2022 00:00:00 1 "'"11?0'.)'.)

12/25/2022 00:00:00

,..,,...,C'J")(\\")')

12/26/2022 00:00:00

,.,,.,.,f'.)('l'.)")

12/27/2022 00:00:00 1'.l/?7/?0??

12/28/2022 00:00:00 l '.l/'.lP./?O??

12/29/2022 00:00:00 l'.)/'.)Q/')07?

12/30/2022 00:00:00 1 ">t,n,-,n-,-,

12/31/2022 00:00:00

,,.,,-,.,nn'.l?

Page 16 of 31 1

1 1

= 76.7 Degrees F

= 76.2 Degrees F

= 76.3 Degrees F

= 76.2 Degrees F

= 76 Degrees F

= 75.9 Degrees F

= 75.7 Degrees F

= 75.6 Degrees F

= 75.5 Degrees F

= 75.4 Degrees F

= 75.3 Degrees F

= 75.7 Degrees F

= 75.8 Degrees F

= 75.9 Degrees F

= 75.8 Degrees F

= 75.4 Degrees F

= 75.6 Degrees F

= 75.7 Degrees F No No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

'Location Collectitin S~inple

, Met~~d*,,

, Typ"e_.

.. o*eoth (m).. i Jt,Matriic M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water

- C:.'!.aramete*r, '\\

Calculation Tvoe Temperature Daily Maximum Temperature Daily Maximum Temperature Daily Maximum Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background

sampie pate,

.Y s.ampleTime, Analvsis Date*

10/01/2022 00:00:00

, n1<1 nn??

11/01/2022 00:00:00

,,nnno??

12/01/2022 00:00:00

,.,,.,, /')('\\')')

10/01/2022 00:00:00 70/0100??

10/02/2022 00:00:00 l()/()")/70??

10/03/2022 00:00:00 1nm-:,,nn??

10/04/2022 00:00:00

'"'".nn??

10/05/2022 00:00:00

..,..,.,,.,c,~n-:>?

10/06/2022 00:00:00 lMnF,J?n??

10/07/2022 00:00:00

, r,m7no??

10/08/2022 00:00:00 1 "'l'lA/?n??

10/09/2022 00:00:00

, r,mann??

10/10/2022 00:00:00

'""")"')')

10/11/2022 00:00:00 1n111nn-n 10/12/2022 00:00:00

, r,11-.nn??

10/13/2022 00:00:00

, "" -:,no??

10/14/2022 00:00:00

, ""Ano??

10/15/2022 00:00:00 1 n/1 C /70??

10/16/2022 00:00:00 1n11F.J?n??

. Field Rep;

':'Lah Rep,, '

. Lab Batch" :c:**

1 1

1 Page 17 of 31

...

MDL, dieviElW:.. 7 Result, ili "';,ML~

.F!rfority, :*

eJ, Units

"' RL > QA codes

... comments.***

= 77.7 Degrees F

= 74.9 Degrees F

= 77 Degrees F

= 19.9 Degrees F

= 20.1 Degrees F

= 19.8 Degrees F

= 19.9 Degrees F

= 19.8 Degrees F

= 19.9 Degrees F

= 19.8 Degrees F

= 19.8 Deg_rees F

= 19.8 Degrees F

= 19.9 Degrees F

= 19.8 Degrees F

= 16.8 Degrees F

= 12.7 Degrees F No No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Ol172023.

zip CDF Analytical Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_01172023.

zip

M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water M-001 water Temperature Delta from Background Temperature.

Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delt_a from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background 10/17/2022 00:00:00 1(l/17/?0??

).0/18/2022 00:00:00 1 fHl Q./?0??

10/19/2022 00:00:00 1"1101')()')')

10/20/2022 00:00:00

,,-,,~,,;-,, ',

10/21/2022 00:00:00 1 nn1 nn??

10/22/2022 00:00:00 10/')')/')()')')

10/23/2022 00:00:00 1 ""J"-1?0??

10/24/2022 00:00:00 1 Al-,,-,/"I-,-,

10/25/2022 00:00:00 1 "'"~l?n??

10/26/2022 00:00:00

, rinF.J?O??

10/27/2022 00:00:00 10/?7/?0??

10/28/2022 00:00:00

, nno.no??

10/29/2022 00:00:00 1A,--.r,nn??

10/30/2022 00:00:00 11)1"-()/?0??

10/31/2022 00:00:00 1 l)l"-1 /?O??

11/01/2022 00:00:00 111()1 /?0??

11/02/2022 00:00:00 11m--.nn??

11/03/2022 00:00:00 11,n-:,,-,",,,,

11/04/2022 00:00:00 11 ll"IO/')()')')

Page 18 of 31 1

1 1

= 13 No Degrees F

= 18.8 Degrees F

= 19.9 Degrees F

20.2 Degrees i

= 20.3 Degrees F

= 20.2 Degrees F

= 20.1 Degrees F

= 20.2 Degrees F

= 20.3 Degrees F

= 20.4 Degrees F

= 20 Degrees F

= 20.1 Degrees F

= 20.2 Degrees F

= 20.1 Degrees F

= 20.2 Degrees F No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated 01172023.

zi~

CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated_Oll72023.

zip

' *. >:*;: r:::

Crillection Method;.,.

1

, Location* I Deoth (in)

M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 Sample xType,;

'Matrix' water water water water water water water water water water water water water water water water water water water

...,.. <*, '?

Parameter;

'Calculation Tvoe

Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background Temperature Delta from Background

. 'Sample,'oate/'.. Field R~p,

'.Sample Time,

Lab Rep;.

~nalvsis. Date Lab Batch 11/05/2022 00:00:00

,, m~nn??

. 11/06/2022 00:00:00 11,n,;nn??

11/07/2022 00:00:00

,.,,t'\\....,,....,.,,..... -.

11/08/2022 00:00:00 11,no.nn??

11/09/2022 00:00:00 11 '"'1/?n??

11/10/2022 00:00:00 1, /1 (\\/?(\\??

11/11/2022 00:00:00 11111nn??

11/12/2022 00:00:00 1 1/1..,,..,,.....,..,

11/13/2022 00:00:00 1111 c,nn??

11/14/2022 00:00:00 1111.nn??

11/15/2022 00:00:00 1, 11 son??

11/16/2022 00:00:00 1111,:,nn??

11/17/2022 00:00:00 1111~,..,,.....,..,

11/18/2022 00:00:00 1111 R/?n??

11/19/2022 00:00:00 1111 ann??

11/20/2022 00:00:00 11nnnn??

11/21/2022 00:00:00 11n1nn??

11/22/2022 00:00:00 11 ;,*,..,

11/23/2022 00:00:00 11n-:,.nn??

Page 19 of 31 1

1 1

. ;Result,'.

Units

= 20.1 Degrees F

= 20.3 Degrees F

= 20.2 Degrees F

= 20.1 Degrees F

= 18.2 Degrees F

= 13.6 Degrees F

= 13.5 Degrees F

=13.4 Degrees F

= 13.3 Degrees F

= 13.4 Degrees F

= 13.3 Degrees F

= 12.8 Degrees F

= 13.3 Degrees F

= 13.3 Degrees F w,

MDL **

iteview

' ML/ * ~i'iority, RL QA Codes No No No No No No*

No No No No No No No No No No No No No

- y,,,.,,,,,..,;**

.f~~mments

. Data Source CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zi~

CDF Analytical Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

I'.;;

,./(.

Collecti6n',

- IVl~thocl,

Locatii:m,

Deoth Cm)

M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 Temperature 11/24/2022 water Delta from Background

, ~?~~?~~~-,

Temperature 11/25/2022 water Delta from Background 00:00:00 1

Temperature water Delta from Background Temperature water*

Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Bac~ground l,,..,~,..,~..,..,

11/26/2022 00:00:00 1

,,,..,,;,,-,r,-,-,

11/27/2022 00:00:00 1

11,-.,-,,-,,,-,-,

11/28/2022 00:00:00 1

11 /')QI')(\\')')

11/29/2022 00:00:00 1

11/30/2022 00:00:00 1

111-:,_r,nn,,

12/01/2022 00:00:00 1

1,m,,,n??

12/02/2022 00:00:00 1

l -,,n-,r,r,-,-,

12/03/2022 00:00:00 1

l -

12/04/2022 00:00:00 1 '1/nAl')(l??

12/05/2022 00:00:00 1 ')/(\\~/?<1??

12/06/2022 00:00:00

,-,,n,:,,-,r,-,-,

12/07/2022 00:00:00

....,,......,.... l"\\"'"'I"")

12/08/2022 00:00:00 1 ?mRnn,,

12/09/2022 00:00:00 1')/(\\(l/')()')')

12/10/2022 00:00:00

, -,,, (\\/')(\\')')

12/11/2022 00:00:00 1 ?/11 /')(\\')')

12/12/2022 00:00:00

, -,,, ')/')(\\')')

Page 20 of31 1

1 1

= 11.8 Degrees F

= 14.8 Degrees F

= 15.5 Degrees F

= 18.4 Degrees F

= 19.3 Degrees F

= 19.2 Degrees F

= 19.3 Degrees F

= 19.5 Degrees F

= 19.3 Degrees F

= 19.4 Degrees F

= 19.5 Degrees F

= 19.4 Degrees F

= 19.5 Degrees F

= 19.6 Degrees F

= 19.7 Degrees F No No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated 01172023.

zio CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF Analytical Cal culated 01172023.

zip CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip

M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 M-001 Col~eC1:.iOn,,,:,

Method/

Deoth Im)*

',$.~mPle,:-<-~, '~">

-> \\~\\

"'C

' Type, Paraineter;

Matrix Calculation Tvoe Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background Temperature water Delta from Background

'.,SampiEi\\bate;;

, S~mpie Time/* '

Analvsis'. Date 12/13/2022 00:00:00

, -,,, -,r,r,-,-,

12/14/2022 00:00:00 l '>17 A f')C,")")

12/15/2022 00:00:00

, -,,, "'nn-,-,

12/16/2022 00:00:00

,-,1,... nr,-,-,

12/17/2022 00:00:00 1 ?/l 7nn??

12/18/2022 00:00:00 17...,.. -- - - -

12/19/2022 00:00:00

,-,,,ann-,-,

12/20/2022 00:00:00 l?nnnn-,-,

12/21/2022 00:00:00

,,n,nn-,-,

12/22/2022 00:00:00 12/23/2022 00:00:00 12/24/2022 00:00:00 1 -,,-,,,-,,,-,-,

12/25/2022 00:00:00

, -,,-,,;,nn??

12/26/2022 00:00:00 12/27/2022 00:00:00

,-.n7nn-,-,

12/28/2022 00:00:00 7-.1-,01'>r,??

12/29/2022 00:00:00

,-,,-.nnn??

12/30/2022 00:00:00 l--,.*,.,-,,

12/31/2022 00:00:00

,-,,.,,nn-,-,

If8id:Rep<f

Lab*Rep,'*

Lab Batch 1

1 1

Page 21 of 31

,*,A,,

Re~utt;

units*

= 19.8 Degrees F

= 19.6 Degrees F

= 19.7 Degrees F

= 19.6 Degrees F

= 19.7 Degrees F

= 19.8 Degrees F

= 19.9 Degrees F

,;,,0,i.,*' '.ReView2 ML, '

Priority, RL.. \\ QA Codes No No No No No No No No No No No No No No No No No ND No Data Source.

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll 72023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll 72023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

M-001 water M-001 water M-001 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-0010 water M-00lF water M-00lF water M-00lF water M-00lF water Temperature Mthly Avg of Daily Avgs Temperature Mthly Avg of Daily Avgs Temperature Mthly Avg of Daily Avgs Cadmium, Total 90-Day Mean Chromium (Total) 90-Day Mean Copper, Total 90-Day Mean Lead, Total 90-Day Mean Mercury, Total 90-Day"Mean Nickel, Total 90-Day Mean Oil and Grease 90-Day Mean Silver, Total 90-Day Mean Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Zinc, Total 90-Day Mean Cadmium, Total 7-Day Average (Mean)

Chromium (Total) 7-Day Average (Mean)

Copper, Total 7-Day Average (Mean)

Lead, Total 7-Day Average (Mean) sampiii o~te,.,

Sampie.;Time, Analvsis Date:

10/01/2022 00:00:00 7 nl"Cl1 /70??

11/01/2022 00:00:00 11,.,nnn-r, 12/01/2022 00:00:00 1?/':\\l /?O??

10/05/2022 00:00:00 11 r>"',/?O??

10/05/2022 00:00:00 11 '""',/?O??

10/05/2022 00:00:00 11 l'l"',/70??

10/05/2022 00:00:00 11 r>"',/?O??

10/05/2022 00:00:00 11 rF nn-i-i 10/05/2022 00:00:00 11 n~/?O??

10/04/2022 00:00:00 1 'lr>A/?O??

10/05/2022 00:00:00 11 n<:,t?O??

10/04/2022 00:00:0ci 1 nnAJ?O??

ll/03/2022 00:00:00 1111.. nn-i-i 12/06/2022 00:00:00 1 'lf'">'l/70??

10/05/2022 00:00:00 11 n~nn?-i 10/01/2022 00:00:00 1n1nAnn-,-,

10/01/2022 00:00:00 1 nmAOO??

10/01/2022 00:00:00 1 l"\\lr\\01""1"\\..,,...,

10/01/2022 00:00:00 1 (\\/(\\Qr)(\\')')

Page 22 of 31 1

1 1

= 75.3 Degrees F

= 70.4 Degrees F

= 76 Degrees F DNQ 0.13 ug/L ND ug/L DNQ 1.8 ug/L DNQ 1.1 ug/L ND ug/L ND ug/L DNQ 1.4 mg/L ND ug/L

<5 mg/L

= 40 ug/L ND ug/L

= 88 ug/L

= 6.6 ug/L ND ug/L

.078

.5 2.6

.9 5

.34 2.5

.08 1.8 1.4 5

.39 5

5 5

No No No No No No No No No No No No No No No No No No No

.***.*.:,i'cx,, *!/. ~;

}6ata s~'urce CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zio See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~ated_on 72o23.

See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~~ated_Oll 72023*

See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~~ated_on 72o23.

See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~ated_on 72o23.

See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~~ated_on72o23.

See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~ated_on 72o23.

Quarterly avg CDF _Analytical_Cal result. See Att. 1, culated_0ll 72023.

Tabs 1, 5, 6, 7 zip See Attachment 2, CDF_Analytical_Cal Contract Lab Report culated_0ll 72023.

zip Monthly avg result.

CDF _Analytical_Cal See Attachment 1, culated_0ll72023.

Tab 5 zip Monthly avg result.

CDF _Analytical_Cal See Attachment 1, culated_0ll72023.

Tab 6 zip Monthly avg result.

CDF _Analytical_Cal See Attachment 1, culated 0ll72023.

Tab 7 zip See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~ated_on 72o23.

CDF _Analytical_Cal culated_0ll72023.

zip CDF _Analytical_Cal culated_0ll72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip

Location M-00lF M-00lF M-00lF M-00lF M-00lF M-00lF M-00lF M-00lH M-00lH M-00lH M-00lH M-00lH M-00lH M-00lH M-00lH M-00lH M-00lH M-00lH M-001]

',Collectiori§,

Method, Deoth (ml.

sam 0ple':

Type, i';"Matrix:,

water water water water water water water water water water water water water water water water water water water i ;/ '.

Sainpl~ Date; Field Rep,

. Paraineter; Sample Time, Lab Rep, Calculatior\\_Tvoe..

-_-*- Analvsis Date **, Lab* Batch..

Mercury, Total 7-Day Average (Mean)

Nickel, Total 7-Day Average (Mean)

Silver, Total 7-Day Average (Mean)

Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Zinc, Total 7-Day Average (Mean)

Cadmium, Total 90-Day Mean Chromium (Total) 90-Day Mean Copper, Total 90-Day Mean Lead, Total 90-Day Mean Mercury, Total 90-Day Mean Nickel. Total 90-Day Mean Oil and Grease 90-Day Mean Silver, Total 90-Day Mean Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Zinc, Total 90-Day Mean Oil and Grease 90-Day Mean 10/01/2022 00:00:00 1

1n,nQr,n-,-,

10/01/2022 00:00:00 1

, (\\{(\\Q{')(\\')')

10/01/2022 00:00:00 1

, n,nQr,n-,-,

12/02/2022 08:10:00 1

,-,m-,nn??

10/05/2022 09:45:00 1

, nm~,-,n-,-,

11/01/2022 11:55:00 1

' /(\\1,-,,.,-,-,

10/01/2022 00:00:00 1

, n1nQnn-,-,

10/03/2022 00:00:00 1

, -i,nr:.nn-i-i 10/03/2022 00:00:00

,-,,n,;.nn-,-,

10/03/2022 00:00:00 1-i1nr:.1-in-,-,

10/03/2022 00:00:00

,-,,n,;.nn-,-,

10/03/2022 00:00:00 1 '){nF,f">(\\')')

10/03/2022 00:00:00 1')/(\\C.{')f\\')')

10/01/2022 00:00:00 10/03/2022 00:00:00 *

,-,mF.nnr, 10/04/2022 00:00:00

, n*n*{')(\\')')

11/02/2022 00:00:00 11 JnAnn-,-,

10/03/2022 00:00:00 10/16/2022 18:15:00

,nn-::,_r,n-,-,

Page 23 of 31 1

1 1

'y ">,}',:::

Result>'

.Units' ND ug/L

= 96 ug/L ND ug/L

=7 mg/L DNQ 2 mg/L DNQ2 mg/L

= 17.3 ug/L ND ug/L

= 27 ug/L

= 73 ug/L ND ug/L ND ug/L

= 20 ug/L ND mg/L ND ug/L ND mg/L ND mg/L

= 17 ug/L ND mgJL

'MDL,.

ML, RL

.08 5

2 5

5 5

.08 1.4 5

2 2

1.4 Review

<, * *~

f

Priority, QA Codes.*

. Comments *

'Data ;ource No See Attachment 2, CDF _Analytical_Cal Contract Lab Report ~~~ated 01172023.

No CDF _Analytical_Cal culated_0ll 72023.

zip No No No No No No No No No No No No No No No No No Monthly avg result.

See Attachment 1.

Tab 13 Monthly avg result.

See Attachment 1, Tab 11 Monthly avg result.

See Attachment 1, Tab 12 Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Avg result for qtrly samples. See Att 1, Tab 1 Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Reoort Monthly avg result.

See Attachment 1, Tab 11 Monthly avg result.

See Attachment 1, Tab 12 Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated 01172023.

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M-OOlL water M-OOlL water M-OOlL water M-OOlL water M-OOlL water M-OOll water M-OOll water M-OOll water M-OOll water M-OOll water M-OOll water M-OOlL water M-OOlN water M-OOlN water M-OOlN water M-OOlN water M-OOlN water M-OOlN water M-OOlN water Cadmium, Total 90-Day Mean Chromium (Total) 90-Day Mean Copper, Total 90-Day Mean Lead, Total 90-Day Mean Mercury, Total 90-Day Mean Nickel, Total 90-Day Mean Oil and Grease 90-Day Mean Silver, Total 90-Day Mean Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Zinc, Total 90-Day Mean Oil and Grease 30-Day Avg of Daily Avgs

Oil and Grease 30-Day Avg of Daily Avgs Oil and Grease 30-Day Avg of Daily Avgs Settleable Solids 30-Day Average Settleable Solids 30-Day Average Settleable Solids 30-Day Average Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs

~ampl~;Date,

/f~Id Re~:r:,,;;;: ',. '"'*,*,,, MDL, Sample.Ti Ille,\\.,, Lab Rep,',,,

Result; ML,,

c.Analvsis Date

'Lab Batch,;<,.'..,;Urifi:s/'

RL 10/05/2022 ND 5

00:00:00 1

ug/L 1">tn7/?0?">

10/05/2022 00:00:00 10/05/2022 00:00:00 1">tr'7/?f1')')

10/05/2022 00:00:00 1 ?tn7 /?0??

10/05/2022 00:00:00 l ?tn7 /?0?-,

10/05/2022 00:00:00 10/05/2022 00:00:00 1 fl"'~/?fl??

10/05/2022 00:00:00

,-,,n7,-,n-,-,

10/05/2022 00:00:00

, n,n~r,r,-,-,

11/16/2022 00:00:00 11 n~nn-,-,

12/02/2022 00:00:00

,-,,n-,,-,r,-,-,

10/05/2022 00:00:00 1 ?tn7 /?f1??

10/04/2022 00:00:00 10/?~/')()')')

ll/03/2022 00:00:00 1.,.......................,...,

12/08/2022 00:00:00 1 ?/?7 /?0??

ll/03/2022 00:00:00 11 f?Rt-,n-,-,

10/04/2022 00:00:00 1"'~C/')()')')

12/08/2022 00:00:00 1 ?/?7 /?fl??

10/04/2022 00:00:00 1 n*~~nn-,-,

Page 24 of 31 1

1 1

1 ND ug/L ND ug/L ND ug/L ND ug/L ND ug/l ND mg/l ND ug/L '

ND mg/L ND mg/l ND mg/L ND ug/L DNQ 1.5 mg/l DNQ 1.6 mg/l DNQ 1.5 mg/l

= 0.3 mill DNQ 0.1 ml/L DNQ 0.1 ml/l

=8 mg/l 5

5 5

.08 5

1.4 5

2 2

2 5

1.5 5

.1

.1 No No No No No No No No No No No No No No No No No No No Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Avg result for qtrly samples. See Att 1, Tab 1 Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Monthly avg result.

See Attachment 1, Tab 11 Monthly avg result.

See Attachment 1, Tab 12 Monthly avg result.

See Attachment 1, Tab 13 Qtrly avg-Att 1 Tab 1 & Att 2 Contract Lab Report Monthly avg - Att 1 Tab 8 & Att 2 Contr.

Lab Rpt.

Monthly avg - Att 1 Tab 9 & Att 2 Contr.

Lab Rpt, Monthly avg - Att 1 Tab 10 & Att 2 Contr. Lab Rpt.

Monthly avg - Att 1 Tab 9 & Att 2 Contr.

Lab Rpt.

Monthly avg - Att 1 Tab 8 & Att 2 Contr.

Lab Rpt.

Monthly avg - Att 1 Tab 10 & Att 2 Contr. Lab Rpt.

Monthly avg - Att 1 Tab 8 & Att 2 Contr.

Lab Rpt.

" ***.'}'

Oat~ S<>"u;cet '

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

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zio CDF _Analytical_Cal cu lated _01172023.

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zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

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CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll 72023.

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___J

}5;:

,,,:.cMolelet.h!iotidp.~.'.*,

S~niple:

.. Type' '.'V Location,. Deoth (m)

Matri~"'

M-OOlN water M-OOlN water M-OOlP water M-OOlP water M-OOlP water M-002 water M-002 water M-002 water M-002 water M-002 water M-002 water M-002 water M-003 water M-003 water M-003 water M-INF water M-INF water M-INF water M-INF water Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs pH Daily Average (Mean) pH Daily Average (Mean) pH Daily Average (Mean)

Oil and Grease 90-Day Mean pH Daily Average (Mean) pH Daily Average (Mean) pH Daily Average (Mean)

Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Total Suspended Solids (TSS) 30-Day Avg of Daily Avgs Ammonia, Total (as NJ 30-Day Avg of Daily Avgs Chromium (Total) 90-Day Mean Copper, Total 90-Day Mean Nickel, Total 90-Day Mean sa111i:i1e bate~

Sample Time; Analvsis Date 11/03/2022 00:00:00 11 nr>./?n??

12/08/2022 00:00:00 1?1nnn?')

10/03/2022 10:30:00

'()/(\\":,/")(\\")")

11/01/2022 11:32:00 11m1nn-n 12/01/2022 09:00:00 1?1mnn??

10/06/2022 00:00:00 1 nm7!?n??

10/06/2022 00:00:00 1n/(\\c/?n??

11/03/2022 00:00:00 11'"_,,,.,"-,-,

12/01/2022 00:00:00 1-i/(\\1/?n??

11/03/2022 00:00:00 11 /(\\'0,/?()')')

12/01/2022 00:00:00

, -i,n, nn??

10/06/2022 00:00:00

,n/(\\,:.r,r,-,?

10/12/2022 10:10:00 1 "",.,,-,"-,-,

11/03/2022 13:10:00 11,n-:,.nn??

12/01/2022 00:00:00 l"J/(\\1/?n??

10/31/2022

09:25:00 11 /(\\f'./?fl??

10/06/2022 00:00:00 1 ?/(\\1 /?fl??

10/06/2022 00:00:00 1-*- *----

10/06/2022 00:00:00

,-,,r,,nn??

/1: ield Rep; :'.' ;. >);:, >>y

. '.Lab Rel), <*,

Result, Lab *eatch '."

. Units 1

1 1

= 11 mg/L

=7 mg/L

= 7.6 SU

= 7.2 SU

= 7.8 SU ND mg/L

= 7.9 SU

= 7.8 SU

= 8.1 SU DNQ 2 mg/L DNQ 2 mg/L ND mg/L

=6 mg/L

=8 mg/L DNQ 2 mg/L ND mg/L ND ug/L ND ug/L

= 13 ug/L Page 25 of 31

MDL,

.. ML,****

RL 1.4 2

5 2

2 2

5

.09 5

5 Reviev/;[?

F'riority, QA Codes No No No No No No No No No No No No No No No No No No No Comments Monthly avg - Att 1 Tab 9 & Att 2 Contr.

Lab Rpt.

Monthly avg - Att 1 Tab 10 & Att 2 Contr. Lab Rpt.

See Attachment #1.

Tab 11 See Attachment #1, Tab 12 Data source CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Ol 172023.

zio CDF _Analytical_Cal culated_Oll72023.

zip See Attachment #l, CDF _Analytical_Cal Tab 13 culated_Oll72023.

zip Avg result for qtrly CDF _Analytical_Cal samples. See Att 1, culated_Oll72023.

Tab 1 zip See Attachment #1, CDF _Analytical_Cal Tab ll culated_Oll72023.

zip See Attachment #l, CDF _Analytical_Cal Tab 12 culated_Oll72023.

zip See Attachment #l, CDF _Analytical_Cal Tab 13 culated_Oll72023.

zip Monthly avg result.

See Attachment l, Tab 12 Monthly avg result.

See Attachment 1, Tab 13 Monthly avg result.

See Attachment 1, Tab 11 Monthly avg result.

See Attachment 1, Tab 12 Monthly avg result.

See Attachment 1, Tab 13 See Attachment 2, Contract Lab Report Qtrly avg-Att 1 Tab 1

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF Analytical Cal culated Oll72023.

zio.

CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

- zip Qtrly avg-Att l Tab CDF _Analytical_Cal 1

culated_Oll 72023.

zip

.Otrly avg-Att 1 Tab CDF _Analytical_Cal 1

culated_Oll72023.

zip

Met.~od,,

Llic~ii~n Depth (ml M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average 10/01/2022 00:00:00 1nm1nn-r, 10/02/2022 00:00:00 1 OJO?i?n"J"J 10/03/2022 00:00:00

,,.,,,.,-,,.,r,-,-,

10/04/2022 00:00:00 11"'1?0??

10/05/2022 00:00:00 1n,n<;J?O??

10/06/2022 00:00:00 1n1nr:.nn??

10/07/2022 00:00:00

, 0/07 nn??

10/08/2022 00:00:00

, r,morin')'J 10/09/2022 00:00:00 1r.monn??

10/10/2022 00:00:00 1 r.110/?0??

10/11/2022 00:00:00 1 nn 1 /?O??

10/12/2022 00:00:00

, r.n ?/?O??

10/13/2022 00:00:00

, "" -:inn"J?

10/14/2022 00:00:00 1 (\\/1, /')(\\')')

10/15/2022 00:00:00

, f',/1 <;f')f',')')

10/16/2022 00:00:00

,nnr:.nn"J"J 10/17/2022 00:00:00 1 nn 1nn??

10/18/2022 00:00:00 1 r,11 o,-,r,-,-,

10/19/2022 00:00:00

, r.,, onn?,

Page 26 of 31 1

1 1,

1 1

= 56,3 Degrees F

= 55,9 Degrees F *

= 54.9 Degrees F

= 54.2 Degrees F

= 54.8 Degrees F

= 56 Degrees F

= 56.3 Degrees F

= 55.7 Degrees F

= 55.4 Degrees F

= 56 Degrees F

= 56.2 Degrees F

= 55.8 Degrees F

= 56.1 Degrees F

= 56.9 Degrees F

= 56.8 Degrees F

= 56.7 Degrees F

= 56.6 Degrees F No No No No No No No No No No No No No No No No No No

Data Source * **

CDF _Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Oll 72023.

zio CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated_Oll72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll72023.

zip

Location M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF

,t: ollecti~n. ;,

.'Method, Deotli On) water water water water water water water water water water water water water water water water water water water Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Sarriple Date,'.

sample Tlrfie, Analvsis Date 10/20/2022 00:00:00 1nnnnn??

10/21/2022 00:00:00 1rw,1nn??

10/22/2022 00:00:00 1,,,..,..,,..,,...,,.,

10/23/2022 00:00:00

,nrn,nn??

10/24/2022 00:00:00

,,,,.,~nn??

10/25/2022 00:00:00 1nnc..nn??

10/26/2022 00:00:00 1nnc,nn??

10/27/2022 00:00:00

,,..,.,-,,.,n,,

10/28/2022 00:00:00 1nn'l.1?n??

10/29/2022 00:00:00

, nnnnn??

10/30/2022 00:00:00 1 nr:innn??

10/31/2022 00:00:00 1 n,-,1 /?O??

ll/01/2022 00:00:00

,,m,nn,,

11/02/2022 00:00:00 11,n-,J?n??

11/03/2022 00:00:00 11,n-:i.nn??

11/04/2022 00:00:00 11,n,inn??

11/05/2022 00:00:00 11,nc..nn??

ll/06/2022

.00:00:00 11 /f\\"-/')f\\')')

ll/07/2022 00:00:00 11,n-,nn??

. l'ield. ReJjJiI, 0 Lal:!ll.ep/

Lab Batch<

1 1

1 Page 27 of 31 MDL,,. }/l,ElvieW;1:,I),'.,.,.

.Result, I: ML;

'Priority;,

Units i.,

RL

IOA Codes ***,. Coinments*:

= 57 Degrees F

= 57.5 Degrees F

= 57 Degrees F

= 56.6 Degrees F

= 57 Degrees F

= 54.8 Degrees F

= 54.1 Degrees F

= 54.9 Degrees F

= 55.3 Degrees F

= 54.7 Degrees F

= 54.2 Degrees F

= 54.7 Degrees F

= 53.9 Degrees F

= 53.1 Degrees F

= 52.6 Degrees F

= 53.5 Degrees F No No No No No No No No No No No No No No No No No No No

- 1: **;?i:

Data Source CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll 72023.

zip CDF _Analytical Cal culated Oll72023.

zip CDF _Analytical_Cal culated Oll 72023.

zip CDF Analytical Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF._Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_01172023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Ol172023.

zip CDF Analytical Cal culated 01172023.

zip CDF _Analytical_Cal culated_Ol172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF M-INF water water water water water water water water water water water water water water water water water water water Temperature 24-hour Average Temperature 24-.hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperafure 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average 11/08/2022 00:00:00 1

11 mqnfl??

11/09/2022 00:00:00 J.

11 /flQl')fl??

11/10/2022 00:00:00 1

1'""'~~~~

11/11/2022 00:00:00 11 /11 /?fl??

11/12/2022 00:00:00 11 /1 ?/?fl??

11/13/2022 00:00:00 11 /1 '.'l/?fl??

11/14/2022 00:00:00 11/14/?fl??

11/15/2022 00:00:00 1111 r,.nfl??

11/16/2022 00:00:00 11 /1 F./?fl??

11/17/2022 00:00:00 11 /17/?fl??

11/18/2022 00:00:00 11 11 A/?fl?')

11/19/2022 00:00:00 11 /1 Q/?fl??

11/20/2022 00:00:00 11 nnnn-n 11/21/2022 00:00:00 11 n1 /?fl??

11/22/2022 00:00:00 11 /??f?fl??

11/23/2022 00:00:00 11 /?C,,/?fl??

11/24/2022 00:00:00 11 r>A/?fl??

11/25/2022 00:00:00 1.,,-..........,...........

11/26/2022 00:00:00 11 /')&;/?fl??

Page 28 of 31 1

1 1

1

.*~1~J,t;;, '"~.. ~:,17,~~~2:~~f;!,1:;:1::rc':*... *';:,....,,..,..

,\\;

Units*.:

RL. IOA Codes Commerits,;..;.,

, Data source**'..

= 54 No CDF _Analytical_Cal Degrees F culated_0ll72023.

= 54.2 Degrees F

= 54 Degrees F

= 53.7 Degrees F

= 53.3 Degrees F

= 53.2 Degrees F

= 53.4 Degrees F

= 53.8 Degrees F

= 53.6 Degrees F

= 53.7 Degrees F

= 54 Degrees F

= 53.6 Degrees F

= 53.8 Degrees F

= 54.2 Degrees F

= 54.3 Degrees F

= 54.2 Degrees F

= 54.7 Degrees F

= 54.7 Degrees F No No No No No No No No No No No No No No No No No No zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated 01172023.

zio CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0l 172023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_0l 172023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0ll72023.

zip

,.,. .;'* ' l'i Collecti,on sa'mpie'

/,(

,,, \\i

'} 5 Sii'riiple' D~t!!,'

Fiiiid ~ep;~.:

,.,7 -~-

t-101.,.*

iieview' y,

i

.*. Method; *

Type, 1>.irametJh Sample Time,

.Result;

,}

1'\\

"if' i.ocation

. I.ab Rep,

'.Ml.,** Priority,

Depth (m)

Matrix Calculation lVPe Analvsis Date *

.Lab Batch Units*** '*'.-RL QA Codes Comments Dat:a So~rce Temperature 11/27/2022

= 54.8 No CDF _Analytical_Cal M-INF water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

111?7/?0')?

zip Temperature 11/28/2022

= 55.3 CDF _Analytical_Cal M-INF 00:00:00 1

No water 24-hour Average Degrees F culated_Oll 72023.

1 7 nRJ?n??

zip M-INF Temperature 11/29/2022

= 55.3 No CDF _Analytical_Cal water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1,,,,.,,..,,.,..,?

zip Temperature 11/30/2022

= 55.3 No CDF _Analytical_Cal M-INF water 24-hour Average 00:00:00 1

Degrees F culated_Oll72023.

,, r:i.nnn??

zip Temperature 12/01/2022

= 55.7 CDF _Analytical_Cal M-INF 00:00:00 1

No water 24-hour Average Degrees F culated_Oll 72023.

,..,,ri,nn??

zip Temperature 12/02/2022

= 56.1 CDF _Analytical_Cal M-INF 00:00:00 1

No water 24-hour Average culated_Oll 72023.

1 ?/0?/?0??

Degrees F zip Temperature 12/03/2022

= 56 No CDF _Analytical_Cal M-INF 00:00:00 1

water 24-hour Average Degrees F culated_Oll72023.

l?">/?n??

zip Temperature 12/04/2022

= 56 No CDF _Analytical_Cal M-INF 00:00:00 1

culated_Oll72023.

water 24-hour Average Degrees F zip Temperature 12/05/2022

= 56.5 No CDF _Analytical_Cal M-INF 00:00:00 1

water 24-hour Average Degrees F culated_Oll 72023.

1 ?m~nn??

zip Temperature 12/06/2022

= 56.8 No CDF _Analytical_Cal M-INF 00:00:00 1

water 24-hour Average Degrees F culated_Oll 72023.

1 "),C,f:,f?(l??

zio Temperature 12/07/2022

= 56.8 CDF _Analytical_Cal M-INF

00:00:00 1

No water 24-hour Average Degrees F culated_Oll72023.

1?In7/?(l??

zip Temperature 12/08/2022

= 57.6 No CDF _Analytical_Cal M-INF water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

,..,mo.nn??

zip Temperature 12/09/2022

= 57.4 No CDF _Analytical_Cal M-INF 00:00:00 1

water 24-hour Average Degrees F culated_Oll 72023.

zip M-INF Temperature

12/10/2022

= 57,5 No CDF _Analytical_Cal water 24-hour Average 00:00:00 1

Degrees F culated_Ol 172023.

l?/1(]/?fl??

zip Temperature 12/11/2022

= 57.1 CDF _Analytical_Cal M-INF No water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

1 ?/11 J?(l??

zip Temperature 12/12/2022

= 57.3 No CDF _Analytical_Cal M-INF water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

l?/1 ?/?(l??

zip Temperature 12/13/2022

= 56.9 No CDF _Analytical_Cal M-INF 00:00:00 1

water 24-hour Average Degrees F culated_Oll 72023.

1?/l"J./?(l??

zip Temperature 12/14/2022

= 56.6 No CDF _Analytical_Cal M-INF 00:00:00 1

culated_Oll 72023.

water 24-hour Average Degrees F l ?/1 A 1-,r,-,-,

zip Temperature 12/15/2022

= 56.6 No CDF _Analytical_Cal M-INF water 24-hour Average 00:00:00 1

Degrees F culated_Oll 72023.

,..,,, ~nn?,

zip Page 29 of 31

M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water M-INF water Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24-hciur Average Temperature 24-hour Average Temperature 24-hour Average Temperature 24:hour Average Temperature 24-hour Average Temperature Daily Maximum Temperature Daily Maximum Temperature Daily Maximum 12/16/2022 00:00:00

,..,,, F.l?n??

12/17/2022 00:00:00

,..,,, 7 l?n??

12/18/2022 00:00:00 1 -,,, A/?n??

12/19/2022 00:00:00

,.,,, rinn??

12/20/2022 00:00:00

,..,nnnn??

12/21/2022 00:00:00 1 ?/?1 /7n??

12/22/2022 00:00:00

,-,n-,nn??

12/23/2022 00:00:00 12/24/2022 00:00:00

,-,,-,~/'){\\')')

12/25/2022 00:00:00

,.,,,,~nn??

12/26/2022 00:00:00

,-,,-,c;nn-,-,

12/27/2022 00:00:00

,-,n7nn??

12/28/2022 00:00:00

,-,,-,or,n??

12/29/2022 00:00:00

,-,,-,nnn??

12/30/2022 06:00:00

,-,qnnn??

12/31/2022 00:00:00

, -,q1 nn??

10/01/2022 00:00:00

, n1-:,1on??

11/01/2022 00:00:00 11 /":lM'>~'>'>

12/01/2022 00:00:00 1?1:i1 nn??

Page 30 of 31 1

1 1

1

= 56.5 Degrees F

= 56.3 Degrees F

= 56.2 Degrees F

= 56.1 Degrees F

= 56 Degrees F

= 55.9 Degrees F

= 55.8 Degrees F

= 55.7 Degrees F

= 55.6 Degrees F

= 56 Degrees F

= 56.1 Degrees F

= 56.2 Degrees F

= 56 Degrees F

= 55.6 Degrees F

= 55.7 Degrees F

= 55.8 Degrees F

= 57.5 Degrees F

= 55,3 Degrees F

= 57.6 Degrees F No No No No No No No No No No No No No No No No No No No CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF Analytical Cal culated 01172023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF Analytical Cal culated_Oll 72023.

zio CDF _Analytical_Cal culated_Oll 72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Ol 172023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated 01172023.

zip CDF _Analytical_Cal culated_Oll72023.

zip CDF _Analytical_Cal culated_Oll 72023.

zip

M-INF water M-INF water M-INF water M-INF water Lab Batches No Lab Batch Data Available/ Reported Questionnaire No Questionnaire Available Certificate Temperature Mthly Avg of Daily Avgs Temperature Mthly Avg of Daily Avgs Temperature Mthly Avg of Daily Avgs Zinc, Total 90-Day Mean 10/01/2022 00:00:00

,nr=n nn??

11/01/2022 00:00:00 11n.nnn?J 12/01/2022 00:00:00 1?n.1 nn??

10/06/2022 00:00:00 nm11:in:i:i 1

1 1

1

= 55.9 Degrees F

= 54 Degrees F

= 56.3 Degrees F ND ug/L No No No 5

No Qtrly avg-Att 1 Tab 1

CDF _Analytical_Cal culated_0ll72023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip CDF _Analytical_Cal culated_0l 172023.

zip CDF _Analytical_Cal culated_0ll 72023.

zip I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

I certify that I am david cortina and am authorized to submit this report on behalf of PG&E Diablo Canyon Power Plant. I understand that I am submitting the following report(s):

- Quarterly SMR ( MONNPDES ) report for Q4 2022 (due 01/20/2023)

I understand that data submitted in this report(s) can be used by authorized agencies for water quality management related analyses and enforcement actions, if required.

I am also aware that my user ID, password, and answer to a challenge question constitute my electronic signature and any information I indicate I am electronically certifying contains my signature. I understand that my electronic signature is the legal equivalent of my handwritten signature. I certify that I have not violated any term in my Electronic Signature Agreement and that I am otherwise without any reason to believe that the confidentiality of my password and challenge question answers have been compromised now or at any time prior'to this submission. I understand that this attestation of fact pertains to the implementation, oversight, and enforcement of a federal environmental program and must be true to the best of my knowledge.

Name:

david cortina

Title:

Chemistry and Environmental Services Manager Page 31 of 31

CIWQS Web Application State DMR Forms {eDMR)

Incorporated with Quarterly CIWQS eSMR Data Submittal

NPDES Permit#: CA0003751 DMR NODls

)i ':??'}',\\:,.L

\\,,~{Sf

'.'*\\'YT* T'

\\, 't' Feijture - LS

Moni:tori'ng. Period *

,.i'.,

.., :( ",.

..r 002-Q 10/01/2022 - 12/31/2022 003-Q 10/01/2022 - 12/31/2022 004-Q 10/01/2022 - 12/31/2022 0lG-M 10/01/2022 - 10/31/2022 0lG-M 11/01/2022 - 11/30/2022 0lG-M 12/01/2022 - 12/31/2022 0lG-Q 10/01/2022 - 12/31/2022 0lH-M 10/01/2022 - 10/31/2022 0lH-M 11/01/2022 - 11/30/2022 0lH-M 12/01/2022 - 12/3,1/2022 01I-M 10/01/2022 - 10/31/2022 01I-M 11/01/2022 - ll/3Q/2022 01I-M 12/01/2022 - 12/31/2022 Generated on 01/18/2023 at 15:36 PST eSMR PDF Summary: DMR Facility: PG AND E DIABLO CANYON POWER PLANT NODI Code<

"', '.ct:_t,)/ "'" 1?/. y '

. 'NODLOe!i,cript,iob'

'* (

y,;;:':.<..; ; '> >it ' :J :*

' >c:*,

B Below Detection Limit/No Detection B

Below Detection Limit/No Detection B

Below Detection Limit/No Detection C

No Discharge C

No Discharge Page 1 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT 011-Q 10/01/2022 - 12/31/2022 C

No Discharge 0lJ-M 10/01/2022 - 10/31/2022 B

Below Detection Limit/No Detection 0lJ-M 11/01/2022 -11/30/2022 B

Below Detection Limit/No Detection 0lJ-M 12/01/2022 - 12/31/2022.

C No Discharge 0lJ-Q 10/01/2022 - 12/31/2022 B

Below Detection Limit/No Detection 0lK-M 10/01/2022 - 10/31/2022

C No Discharge 0lK-M 11/01/2022 - 11/30/2022 C

No Discharge 0lK-M 12/01/2022 - 12/31/2022 C

No Discharge 0lK-Q 10/01/2022 - 12/31/2022 C

No Discharge 0ll-Q 10/01/2022 - 12/31/2022 B

Below Detection Limit/No Detection 0lM-M 10/01/2022 - 10/31/2022 C

No Discharge

0lM-M 11/01/2022 - 11/30/2022 C

No Discharge 12/01/2022 - 12/31/2022 C

No Discharge 0lM-Q 10/01/2022 - 12/31/2022 C

No Discharge 0lP-Q.

10/01/2022 - 12/31/2022 B

Below Detection Limit/No Detection DMR Parameters

Generated on 01/18/2023 at 1.5:36 PST*

Page 2 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT Feature - LS:

001-M

\\

Monitoring Period: l0/01/2022-10/31/2022

1

~~r~m

,: :.s*,,, "l:'ff:'i

</; 11\\,' Q2: I} :L

,: ?!':

,, ;: }*,,

, Arialy>

's"ample

1..hc, 'Sea'

'.Pa'i-arn Text

. Ql..

. C:l*,*,,,,'* *c2

.* C3.~

Exc:ur count Type:,

/){~f> ',_ :

. Freq

\\..,.

... j,,,

J.,:'

8.0 SU 8.0 SU 1

0 00400 pH Minimum Maximum Monthly GRAB Chromium, total NODI: B NODI: B 1

0 01034 (as c*r) 6 Month lnstantaneou Median s Maximum Copper, total NODI: B NODI: B 1

0 01042 6 Month lnstantaneou (as Cu)

Median s Maximum Nickel, total (as 13.1 ug/L 13.9 ug/L 1

0 01067 Ni) 6 Month lnstantaneou Monthly GRAB Median s Maximum Zinc, total (as NODI: B NODI: B 1

0 01092 6 Month lnstantaneou Zn)

Median s Maximum Flow, in conduit 1886.0 MGD 2486.0 MGD 1

0 50050 or thru 30 Day Daily Daily RCORDR treatment plant Average Maximum Chlorine, total 38.0 ug/L 63.0 ug/L 1

0 50060 residual 6 Month lnstantaneou See Permit GRAB Median

s Maximum 10672.0 1

0 81400 Chlorine usage lb/mo Monthly RCORDR Monthly Total Temperature, 75.3 deg F 77.7 deg F s

0 00011 water deg.

Daily Daily Continuous RCORDR fahrenheit Average Maximum Temperature, NODI: 9 NODI: 9 T

0 00011 water deg.

Daily Daily fahrenheit Averaqe Maximum Generated on 01/18/2023 at 15:36 PST Page 3 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT y

- F~a1:ure} LS:, OOl~M

,, {/'"<f... *****

.*::::ift:;..

';It!r:JL/

. : Monitoring Period: 11101/2022~ 11/30/2022

*: oc '. eat *.a.~~~. : ~ra r,n **',e,:~~' 1w:,Y,j?!~lf,CI:

'.~ i ::, 3/4< ~.~\\:;*fz\\; '*!r' ).~cjii~~.' f;F.,:]" ~Et: I t ',: ~~!:ftJ\\:f.1 C~y raf.* r;':';'f'i-'~q~!i'~~ :x '; Typ"e :*.

1 0

00400 pH 1

0 01034 Chromium, total (as Cr) 1 0

01042 Copper, total (as Cu) 1 0

01067 Nickel. total (as Ni) 1 0

01092 Zinc, total (as Zn).

Flow, in conduit 1

0 50050 or thru treatment plant 1

0 50060 Chlorine, total residual 1

0 81400 Chlorine usage Temperature, s

0 00011 water deg.

fahrenheit Temperature, T

0 00011 water deg.

fahrenheit Generated on 01/18/2023 at 15:36 PST

1809.0 MGD 2486.0 MGD 30 Day Daily Averaqe Maximum 11276.0 lb/mo Monthly Total 7.8 SU 7.8 SU Minimum NODI: B 6 Month Median NODI: B 6 Month Median 13.6 ug/L.

6 Month Median NODl:B 6 Month Median

Maximum, NODI: B lnstantaneou s Maximum NODI: B lnstantaneou s Maximum 13.6 ug/L lnstantaneou s Maximum NODI: B lnstantaneou

s Maximum 35.0 ug/L 75.0 ug/L 6 Month lnstantaneou Median s Maximum 70.4 deg F Daily Averaqe NODI: 9 Daily Averaqe 74.9 deg F Daily Maximum NODI: 9 Daily Maximum Monthly GRAB Monthly GRAB Daily RCORDR See Permit GRAB Monthly RCORDR Continuous RCORDR Page 4 of 37

NPDES Permit#: CA0003751 Feature - l.S:

001-M I

J<

.*;... * /\\, *,, ', '

'(pc s,~. P~,falll P~r~lll?!:t~t

1 0

1 0

s 0

T 0

00400 pH 01034 Chromium, total (as Cr) 01042 01092 50050 50060 81400 00011 00011 Copper, total (as Cu)

Zinc, total (as Zn)

Flow, in conduit or thru treatment plant Chlorine, total residual Chlorine usage Temperature, water deg.

fahrenheit Temperature, water deg.

fahrenheit Generated on 01/18/2023 at 15:36 PST 2486.0 MGD 30 Day Average 2486.0 MGD Daily Maximum 13952.0 lb/mo Monthly Total Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring,Period: l2/01/2O22 -12/31/2022 8.0 SU Minimum NODI: B 6 Month Median NODI: B 6 Month Median 13.9 ug/L 6 Month Median NODI: B 6 Month Median 36.0 ug/L 6 Month Median 19.6 deg F Daily Average NODI: 9 Daily Averaqe 8.0 SU Maximum NODI: B lnstantaneou s Maximum NODI: B lnstantaneou s Maximum 14.2 ug/L lnstantaneou s Maximum NODI: B lnstantaneou s Maximum 60.0 ug/L lnstantaneou s Maximum 19.9 deg F Daily Maximum NODI: 9 Daily Maximum Monthly GRAB Monthly GRAB Daily RCORDR See Permit GRAB Monthly RCORDR Continuous RCORDR Page 5 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLOCANYON_POWER PLANT

---._ E~aturEf--*~s:: :1001,,Q:::.***

r~i~*\\ ~;:~;i11 ;~,,~~.:~;,~ii;*\\

Nitrogen, 20.0 ug/L NODI: B 1

0 00610 ammonia total 6 Month lnstantaneou Quarterly GRAB (as N)

Median s Maximum Toxicity, final NODI: B NODI: B 1

0 61406 cone toxicity units

)

6 Month Daily Median Maximum

/

,r Generated on 01/18/2023 at 15:36 PST Page 6 of 37

NPDES Permit#: CA0003751 Feature - LS:

002-M 1

0 1

0 00400 00530 pH Solids, total suspended Generated on 01/18/2023 at 15:36 PST 7.6 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 10/01/2022 - 10/31/2022 NODI: B 30 Day Avera e 7.6 SU Maximum NODI: B*

Daily Maximum Monthly GRAB Page 7 of 37

NPDES Permit#: CA0003751 1

0 1

0 00400 00530

\\

pH Solids, total suspended Generated on 01/18/2023 at 15:36 PST 7.8 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT

- ... ;Me>r1itorin9*1>'eriod})l't/Pl/iCJ2 2'.:* :(J./i61io~r*

NODI: Q 30 Day Avera e 7.8 SU Maximum NODI: Q Daily Maximum

E~caf."F"*Aifaly1t:, '.'.'"*safi!tp

'igo;~pi(. Fr~~ :' "'*tYP:

Monthly GRAB Page 8 of37

NPDES Permit#: CA0003751 Feature - LS:

1 0

00400 1

0 00530 pH Solids, total suspended Generated on 01/18/2023 at 15:36 PST 8.1 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 12/01/2022 -12/31/2022

NODI: Q 30 Day Avera e 8.1 SU Maximum NODI: Q Daily Maximum j.Exeor::..Artaly,*t Sampl~:

/qoLJr,t

.F~:eA):t..,.. Typ~.

Monthly GRAB Page 9 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT 7.6 SU 7.6 SU 1

0 00400 pH Minimum Maximum Monthly GRAB Solids, tot.al 6.0 mg/L 6.0 mg/L 1

0 00530 suspended 30 Day Daily See Permit GRAB Avera e Maximum Generated on 01/18/2023 at 15:36 PST Page 10 of 37

NPDES Permit#: CA0003751 1

0 1

0 00400 00530-,

pH Solids, total suspended Generated on 01/lB/2023 at 15:36 PST 7.8 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 11/01/2022.- 11/30/2022 8.0 mg/L 30 Day Avera e 7.8 SU Maximum 8.0 mg/L Daily Maximum Monthly GRAB See Permit GRAB Page 11 of 37

NPDES Permit#: CA0003751 1

0 1

0 00400 00530 pH Solids, total suspended Generated on 01/18/2023 at 15:36 PST 8.3 SU Minimum Facility: PG AND. E DIABLO CANYON POWER PLANT NODI: Q 30 Day Avera e 8.3 SU Maximum NODI: Q Daily Maximum Monthly GRAB Page 12 of 37

NPDES Permit#: CA0003751 Feature - LS:

_/;/_', * ;,

,~~<: >

i,\\1 ',,,

. rarjm P~ram'iext

' 1 0

00400 pH Generated on 01/18/2023 at 15:36 PST 7.8 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 10/01/20?2 - 10/31/2022 7.8 SU Maximum Monthly GRAB Page 13 of 37

NPDES Permit #: CA0003751 1

0 00400 pH Generated on 01/18/2023 at 15:36 PST 7.8 SU Minimum Facility: PG AND E DIABLO"CANYON POWER PLANT

. 7.8 SU Maximum Monthly GRAB Page 14 of 37

NPDES Permit#: CA0003751 Fei)ture - LS:

004-M 1

0 00400 pH Generated on 01/18/2023 at 15:36 PST 8.3 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT

.* Monitoring Period: 12/01/2022 -12/31/2022 8.3 SU Maximum Monthly GRAB Page 15 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIAB LO CANYON POWER PLANT Moni1:C>fing;Petiod},lQ/01/202.2i*lP/31/2022, Solids, total

<5.0 mg/L 13.0 mg/L 1

0 00530 suspended 30 Day Daily Monthly GRAB Avera e.

Maximum Copper, total NODI: 9 NODI: 9 1

0 01042 (as Cu}

30 Day Daily Avera e Maximum Iron, total (as NODI: 9 NODI: 9 1

0 01045 30 Day Daily Fe}

Avera e Maximum Generated on 01/18/2023.at 15:36 PST Page 16 of 37

NPDES Permit #: CA0003751 Feature - LS; 01D-M V :, \\ *;r;, \\ <,?'

tac is:ea '. Pa'rcirn ;Pai-~nt f~xt:.

1 0

00530 Solids, total suspended 1

0 01042 Copper, total (as Cu) 1 0

01045 Iron, total (as Fe)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring.Period: 11/01/2022:. 11/30/2022

<5.0 mg/L 30 Day Avera e NODI: 9 30 Day Avera e NODI: 9 30 Day Avera e 32.0 mg/L Daily Maximum NODI: 9 Daily Maximum

.NODI: 9 Daily Maximum

'. S a':n1'p1e Tyi),e GRAB Page 17 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT

.*Feature;:,, LS:

Q:J;D-M Monitoring Period: 12/01/29:22:*, 12/31/?,022 Solids, total

<5.0 mg/L 13.0 mg/L 1

0

00530 suspended 30 Day Daily Monthly GRAB Avera e Maximum Copper, total NODI: 9 NODI: 9 1

0 01042

{as Cu) 30 Day Daily*

Avera e Maximum Iron, total (as NODI: 9 NODI: 9 1

0 01045 Fe) 30 Day Daily Avera e Maximum Generated on 01/18/2023 at 15:36 PST Page 18 of 37_

NPDES Permit#: CA0003751 Featu,re - LS:

OlD-Q 1

0 00556 Oil & Grease 1

0 01027 Cadmium, total (as Cd) 1 0

01034 Chromium, total (as Cr) 1 0

01042 Copper, total (as Cu) 1 0

01051 Lead, total (as Pb) 1 0

01067 Nickel, total (as Ni) 1 0

01077 Silver, total (as Ag) 1 0

01092 Zinc, total (as Zn) 1 0

71900 Mercury, total (as Hg)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 10/01/2022 - 12/31/2022 NODI: Q NODI: Q 30 Day Daily Averaqe Maximum NODI: Q Daily Maximum NODI: B Daily Maximum NODI: Q Daily Maximum NODI: Q Daily Maximum NODI: B Daily Maximum NODI: B Daily Maximum 0.04 mg/L Daily Maximum NODI: B Daily Maximum

',1:'xc\\1('

Analy i¢,9qrit

, f:req,:::

Quarterly COMPOS Page 19 of 37

NPDES Permit#: CA0003751 1

0 00530 Solids, total suspended 1

0 00556 Oil & Grease 1

0 01042 Copper, total (as Cu) 1 0

01045 Iron, total (as Fe)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT NODI: Q 30 Day Avera e

NODI: Q 30 Day Avera e NODI: 9 30 Day Avera e NODI: 9 30 Day Avera e NODI: Q Daily Maximum NODI: Q Daily Maximum NODI: 9 Daily Maximum NODI: 9 Daily Maximum Page 20 of 37

NPDES Permit#: CA0003751 Feature - LS:

OlF-M Loe. s'~a Param Param Text

'.i < is:;,:: ***

1 0

00530 1

0 00556 1

0 01042 1

0 01045 Solids, total suspended Oil & Grease Copper, total (as Cu)

Iron, total (as Fe)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT

Monitoring Period: 11/01/2022 -11/30/2022 NODI: Q 30 Day Averaqe NODI: B 30 Day Average NODI: 9 30 Day Averaqe NODI: 9 30 Day Averaqe NODI: Q Daily Maximum NODI: B Daily Maximum NODI: 9 Daily Maximum NODI: 9 Daily Maximum Page 21 of 37

NPDES Permit#: CA0003751 Feature... LSf. QlF-M 1

0 00530 Solids, total suspended 1

0 00556 Oil & Grease 1

0 01042 Copper, total (as Cu) 1 0

01045 Iron, total (as Fe)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT

.;Morlitorin~.PetiodJ.12/01/202Zc 12/31/2022 7.0 mg/L 30 Day Avera e NODI: Q 30 Day Avera e NODI: 9 30 Day Avera e NODI: 9 30 Day Avera e 7.0 mg/L Daily Maximum NODI: Q Daily Maximum NODI: 9 Daily~

Maximum NODI: 9 Daily Maximum Monthly GRAB Page 22 of 37

NPDES Permit#: CA0003751 Feature - LS:

OlF-Q 1

0 01027 Cadmium, total (as Cd) 1 0

01034 Chromium, total (as Cr) 1 0

01042 Copper, total (as Cu) 1 0

01051 Lead, total (as Pb) 1 0

01067 Nickel, total (as Ni) 1 0

01077 Silver, total (as Ag) 1 0

01092 Zinc, total (as Zn) 1 0

71900 Mercury, total (as Hg)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 10/01/2022 -12/31/2022 NODI: B Daily Maximum 0.088 mg/L Daily Maximum 0.007 mg/L Daily Maximum NODI: B Daily Maximum 0.096 mg/L Daily Maximum NODI: B Daily Maximum 0.017 mg/L Daily Maximum NODI: B Daily Maximum Quarterly COMPOS Quarterly COMPOS Quarterly COMPOS Quarterly COMPOS Page 23 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT NODI: B NODI: B 1

0 00556 Oil & Grease 30 Day Daily Averaqe Maximum Cadmium, total NODI: B 1

0 01027 (as Cd)

Daily Maximum Chromium, total 0.027 mg/L 1

0 01034 (as Cr)

Daily Maximum Quarterly COMPOS Copper, total 0.073 mg/L 1

0 01042

'(as Cu)

Daily Maximum Quarterly COMPOS Lead, total (as NODI: B 1

0 01051 Pb)

Daily Maximum Nickel, total (as 0.02 mg/L 1

0 01067 Ni)

Daily Maximum Quarterly COMPOS Silver, total (as NODI: B 1

0 01077 Ag)

Daily Maximum Zinc, total (as 0.017 mg/L 1

0 01092 Zn)

Daily Maximum Quarterly COMPOS Mercury, total NODI: B 1

0 71900 (as Hg)

Daily Maximum Generated on 01/18/2023 at 15:36 PST Page 24 of 37

--- ------~-

NPDES Permit#: CA0003751

,, \\/;~: '[">'

1 0

00530 Solids, total suspended 1

0 01042 Copper, total (as Cu) 1 0

01045 Iron, total (as Fe)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 10/01/2022-10/31/2022 NODI: B 30 Day Avera e NODI: 9 30 Day Avera e NODI: 9 30 Day Avera e NODI: B Daily Maximum NODI: 9 Daily Maximum NODI: 9 Daily Maximum Ex(:ur *:, 'Analy,. s'amplEf

.Coiant~

fr:,~q-

,,.;:;TYP~L*>

Page 25 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT Solids, total NODI: B NODI: B 1

0 00530 suspended 30 Day Daily Avera e Maximum Copper, total NODI: 9 NODI: 9 1

0 01042 30 Day Daily (as Cu)

Avera e Maximum Iron, total (as NODI: 9 NODI: 9 1

0 01045 Fe) 30 Day Daily Avera e Maximum Generated on 01/18/2023 at 15:36 PST Page 26 of 37

NPDES Permit#: CA0003751 f:Lf'.".::"**,-' ;,

1 0

00530 Solids, total suspended 1

0 01042 Copper, total (as Cu) 1 0

01045 Iron, total (as Fe)

Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 12/01/2022 - 12/31/2022, NODI: B 30 Day Avera e NODI: 9 30 Day Avera e NODI: 9 30 Day Avera e NODI: B Daily Maximum NODI: 9 Daily Maximum NODI: 9 Daily Maximum

... : Excures,.

... COUl'lt

't:sa0:,pl~

Type,

/}

Page 27 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT Solids, total 8.0 mg/L 18.0 mg/L 1

0 00530 suspended 30 Day Daily

. Weekly

COMPOS Avera e Maximum

Solids, NODI: Q NODI: Q 1

0 00545 settleable 30 Day Daily Avera e Maximum NODI: Q NODI: Q 1

0 00556 Oil & Grease 30 Day Daily Avera e

.Maximum Generated on 01/18/2023 at 15:36 PST' Page 28 of 37

NPDES Permit#: CA0003751 Feature - LS:

0 00530 1

0 00545 1

0 00556 OlN-M Solids, total suspended

Solids, settleable Oil & Grease Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Per:iod: 11/01/2022:. 11/30/2022 11.0 mg/L 29.0 mg/L 30 Day Daily Weekly COMPOS Average Maximum NODI: Q NODI: Q 30 Day Daily Averaqe

Maximum NODI: Q NODI: Q

30 Day Daily Averaqe Maximum Page 29 of 37

NPDES Permit#: CA0003751 1

0 1

0 r~r~ntiia

<'Y,c ~i,. "'",

00530 00545 00556 Solids, total suspended

Solids, settleable Oil & Grease Generated on 01/18/2023 at 15:36 PST Facility: PG AND E DIABLO CANYON POWER PLANT 7.0 mg/L 30 Day Avera e NODI: Q 30 Day Avera e NODI: Q 30 Day Avera e 14.0 mg/L Daily Maximum NODI: Q Daily Maximum NODI: Q

Daily Maximum Weekly COMPOS Page 30 of 37

NPDES Permit#: CA0003751

,,fr'.<'.::

....,>*\\'

[

.* oc.$,~a 1

0 00400 pH 1

0 00530 Solids, total suspended Generated on 01/18/2023 at 15:36 PST 7.6 SU

Minimum Facility: PG AND E DIABLO CANYON POWER PLANT Monitoring Period: 10/01/2022 - 10/31/2022 8.0 mg/L 30 Day Avera e 7.6 SU Maximum 8.0 mg/L Daily Maximum Monthly GRAB Monthly GRAB Page 31 of 37

NPDES Permit#: CA0003751 1

0 1

0 00400 00530 pH Solids, total suspended Generated on 01/18/2023 at 15:36 PST -

7.2 SU Minimum Facility: PG AND E DIABLO CANYON POWER PLANT 7.2 SU Maximum Monthly GRAB 6.0 mg/L 6.0 mg/L 30 Day Daily Monthly GRAB Avera e Maximum Page 32 of 37

NPDES Permit#: CA0003751

feature -.lSr 1

0 00400 1

0 00530 pH Solids, total suspended Generated on 01/18/2023 at 15:36 PST 7.8 SU

Minimum.

Facility: PG AND E DIABLO CANYON POWER PLANT NOD(: B 30 Day Avera e 7.8 SU Maximum NODI: B Daily Maximum Monthly GRAB Page 33 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT Temperature, 57.5 deg F G

0 00011 water deg.

Daily Continuous

RCORDR fahrenheit,

Maximum 7.9 SU 7.9 SU G

0 00400 pH Minimum Maximum Monthly GRAB Generated on 01/18/2023 at 15:36 PST Page 34 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT

F,eature 7;LS: JNF~M

~to{: :.!e~?! !~f ff~ ~!r)*ffi/~ixt*

Temperature, 55.3 deg F G

0 000],l water deg.

Daily Continuous RCORDR fahrenheit Maximum 7.7 SU.

7.7 SU G

0 00400 pH Minimum Maximum Monthly GRAB Generated on 01/18/2023 at 15:36 P~T Page 35 of 37

NPDES Permit#: CA0003751 Facility: PG AND E DIABLO CANYON POWER PLANT Temperature, 57.6 deg F G

0 00011 water deg.

Daily Continuous RCORDR fahrenheit Maximum 8.1 SU 8.l"SU G

0 00400 pH Minimum Maximum Monthly GRAB Generated on 01/18/2023 at 15:36 PST Page 36 of 37

NPDES Permit#: CA0003751 Featute -LS:

INf~Q,. '

Nitrogen, G

0 00610 ammonia total (as N)

G 0

01034 Chromium, total (as Cr)

G 0

01042 Copper, total (as Cu)

G 0

01067 Nickel, total (as Ni)

Certificate Facility: PG AND E DIABLO CANYON POWER PLANT NODI: B Daily Maximum NODI: B Daily Maximum NODI: B Daily Maximum 13.0 ug/L Daily Maximum Quarterly GRAB I certify under penalty of law that all data submitted, including attachments, were prepared under my direction in accordance with* a system designed to assure that qualified personnel properly gather and evaluate the information submitted *. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of a fine or imprisonment, for knowing violations. m certify that I am david cortina and am authorized to submit this report on behalf of PACIFIC GAS and ELECTRIC COMPANY.

I understand that I am submitting an NPDES Discharge Monitoring. Report (DMR) for the period* ending 10/31/2022 and I understand that data submitted in this report can be used by authorized agencies for.water quality management related analyses and enforcement actions, if required.

Entry of my name and title below indicate my certification of this report of my understanding of the above conditions.

Name: david cortina

Title:

Date: 01/18/2023 - 14:18:08 Generated on 01/18/2023 at 15:36 PST Page 37 of 37

DCL-2023-502, (DCPP) 4th Quarter 2022 Report on Discharge Self-Monitoring

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DCL-2023-502, (DCPP) 4th Quarter 2022 Report on Discharge Self-Monitoring

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