Text

Renewal of the Crystal River Units 1, 2 and 3 Industrial Wastewater Permit FL0000159
	ML13081A018
Person / Time
Site:	Crystal River
Issue date:	03/06/2013
From:	Hobbs T; Duke Energy Corp
To:	; Document Control Desk, Office of Nuclear Reactor Regulation
References
	3F0313-03
	Download: ML13081A018 (255)
	v • d • e

PDuke Energy Crystal River Nuclear Plant Docket No. 50-302 Operating License No. DPR-72 Ref: ITS Appendix B March 6, 2013 3F0313-03 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, DC 20555-0001

Subject:

Crystal River Unit 3 - Renewal of the Crystal River Units 1, 2 and 3 Industrial Wastewater Permit FLO000 159

Dear Sir:

In accordance with the Environmental Protection Plan (Non-Radiological) Improved Technical Specifications (ITS) for Crystal River Unit 3 (CR-3), Section 3.2.4, Florida Power Corporation, hereby provides a copy of the National Pollutant Discharge Elimination System (NPDES) Permit Renewal application that was submitted to the Florida Department of Environmental Protection (FDEP).

The NPDES Permit encompasses Crystal River Units 1, 2 and 3, and is renewed every five (5) years. The current NPDES permit, whose expiration date is August 31, 2013, was issued for an eighteen month duration on March 6, 2012. This shortened permit duration was a result of the settlement agreement that was reached following the Florida Wildlife Federation and Sierra Club petition for an administrative hearing challenging FDEP's notice of intent for renewal of this permit.

No new regulatory commitments are made in this letter.

If you have any questions regarding this submittal, please contact Ms. Erika Tuchbaum-Biro, Senior Environmental Specialist at (352) 464-7909.

Sincerely, Terry Hob s Plant General Manager TH/ff

Attachment:

Crystal River Units 1, 2 & 3 - NPDES Permit Renewal Application xc: Regional Administrator, Region II Senior Resident Inspector NRR Project Manager Crystal River Nuclear Plant 15760 W. Power Line Street Crystal River, FL 34428

FLORIDA POWER CORPORATION DOCKET NUMBER 50 - 302 / LICENSE NUMBER DPR - 72 ATTACHMENT CRYSTAL RIVER UNITS 1, 2 & 3 -

NPDES PERMIT RENEWAL APPLICATION

Progress Energy Florida, Inc.

Crystal River Units 1, 2, & 3 NPDES Permit Renewal Application NPDES Permit No. FL0000159 Submitted February 28, 2013

jProgress Energy Robby A. Odom Station Manager, Crystal River Fossil Plant &Fuel Operations VIA NEXT DAY DELIVERY February 28, 2013 Mr. Marc Harris, P.E.

Supervisor, Power Plant NPDES Permitting Industrial Wastewater Section Florida Department of Environmental Protection 2600 Blair Stone Road, MS 3545 Tallahassee, FL 32399-2400 Re: Progress Energy Florida, Inc. -Crystal River Units 1, 2, & 3 NPDES Permit Renewal Application - FLOOQ0159

Dear Mr. Harris:

Submitted for your review is one (1) hard copy along with an electronic version on a compact disk (CD) of the completed application forms and supporting documentation for renewal of the subject NPDES permit. An additional electronic copy of the application has been sent to Ms.

Mauryn McDonald, P.E., at the FDEP - Southwest District Office. A check for the application fee in the amount of $7,500.00 is also enclosed.

Please contact Mr. Doug Yowell at (727) 820-5228 should you have questions concerning this submittal.

Sincerely, Robby A. Odom Station Manager, Crystal River Fossil Plant & Fuel Operations cc: Mauryn McDonald, P.E.

FDEP - Southwest District Office

WASTEWATER FACILITY OR ACTIVITY PERMIT APPLICATION FORM 1 GENERAL INFORMATION I - IDENTIFICATION NUMBER:

Facility ID FL0000159 II - CHARACTERISTICS:

INSTRUCTIONS: Complete the questions below to determine whether you need to submit any permit application forms to the Department of Environmental Protection. If you answer "yes" to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question. Mark "X" in the blank in the third column if the supplemental form is attached. If you answer "no" to each question, you need not submit any of these forms. You may answer "no" if your activity is excluded from permit requirements. See Section B of the instructions. See also, Section C of the instructions for definitions of the terms used here.

SPECIFIC QUESTIONS YES NO FORM ATTACHED A. Is this facility a domestic wastewater facility which X results in a discharge to surface or ground waters?

B. Does or will this facility (either existing or proposed) include a concentrated animal feeding operation or aquatic animal X production facility which results in a discharge to waters?

C. Does or will this facility (other than those describe in A. or B.)

discharge process wastewater, or non-process wastewater regulated by X 2CS effluent guidelines or new source performance standards, to surface waters?

D. Does or will this facility (other than those described in A. or B.) X (Separate COC) discharge process wastewater to ground waters?

E. Does or will this facility discharge non-process wastewater, not regulated by effluent guidelines or new source performance standards, to X surface waters?

F. Does or will this facility discharge non-process wastewater to X (Separate COC) ground waters?

G. Does or will this facility discharge stormwater associated with X (Separate MSGP) industrial activity to surface waters?

H. Is this facility a non-discharging/closed loop recycle system? X I. Is this facility a public water system whose primary purpose is the production of potable water for public consumption and which discharges demineralization concentrate to surface water or X groundwater?

III - NAME OF FACILITY: (80 characters and spaces)

Crystal River Power Plant Units 1, 2, 3 1-13 DEP Form 62-620.910(l)

(Effective July 7,.2006)

Facility ID FL0000159 IV - FACILITY CONTACT: (A. 30 characters and spaces)

A. Name and Title (Last, first, & title) B. Phone (area code & no.)

Yowell, Douglas W. 727-820-5228 V - FACILITY MAILING ADDRESS: (A. 30 characters and spaces; B. 25 characters and spaces)

A. Street or P.O. Box: P.O. Box 14042, PEF-903 B. City or Town: St. Petersburg I State: FL Zip Code: 33733 VI - FACILITY LOCATION: (A. 30 characters and spaces; B. 24 characters and spaces; C. 3 spaces (if known); D.

25 characters and spaces; E. 2 spaces; F. 9 spaces)

A. Street, Route or Other Specific Identifier: 15760 W. Power Line St.

B. County Name: Citrus C. County Code (if known):

D. City or Town: Crystal River E. State: FL -FF. Zip Code: 34428 VII - SIC CODES: (4-digit, in order of priority)

I. Code #: 4911 (Specify) Electric Svc. 2. Code #: (Specify)

3. Code #: (Specify) 4. Code #: (Specify)

VIII - OPERATOR INFORMATION: (A. 40 characters and spaces; B. 1 character; C. 1 character (if other, specify);

D. 12 characters; E. 30 characters and spaces; F. 25 characters and spaces; G. 2 characters; H. 9 characters)

A. Name: Progress Energy Florida, Inc B. Is the name in VIII A. the owner?

ZYes E]No

ýC Status of Operator. -* (code) (specify) D. Phone No.:

F ='Federal' S State;. P*= Private; p Utility 352-501-5682 0O Other; M"Public ý(other than F Or S).i: ..

E. Street or P. 0. Box: 15760 W. Power Line St.

F. City or Town: Crystal River G. State: FL H. Zip Code: 34428 IX - INDIAN LAND:

A. Is the facility located on Indian lands? Ej Yes Z No 1-14 DEP Form 62-620.910(1)

(Effective July 7, 2006)

Facility ID) FLOOOOIS59 X - EX ISTI NG ENVI RONM ENTAL PERM ITS:

A.. NPDES PernitNo. BIUIC Permit No, C. Other (specify) D. Other (specify)

FL0000159 N/A COC PA :77.091' FLA .18753 -DWW XIo -MAP.: Attach to this. application a topgraphic map Ofthe:ara extending.to at least one mile -eyonrldproperty boun Te nap: musts~IoW the outline.6f the facility, the location of each of its exist*ig andproposed intakeiand d*i*harge structuresi. lmeacrfditi azardous..waste treatment. storage. or disposaltfacilitiesond each well where itiin'ecIs fllwds tn:1dlrground; sp*qgji.g Inc* +l.en.fl rs..and other: surace wat, r bodi+s ifi.Vith*e p irca.: See 'ifnt stb

.. ,iivt pce. r~e+qie meents.*

II \ii l:Xi+RE OF 'BUSINESS (provide a ,b~ri~f'descri~tion)

Crystal River Units I & 2a afired stred i cfi generating faci.itis.

Crstal:River* Unit 3 is rititd.niWlea r-poow'ered stea.. .*l ne..I......

XI\I. - CERTIFICATION siee ihstruetibihs)

I celt id6'r..*lty of law ttiaL .thave .ersonal!! di. id and amfomiliar withl:the information submittedin this.

q~ilicaitinidjalI igdccnts anid thta~t; based 'on iy !iniquiryOfthosepiersons,ifimediately responsiblefor obtaining.

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Form 1,Section XI - Maps

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FORM ,

2CS2CS ~FLORýA2 WASTEWATER APPLICATION FOR PERMIT TO DISCHARGE PROCESS WASTEWATER FROM NEW OR EXISTING INDUSTRIAL WASTEWATER FACILITIES TO SURFACE WATERS Facility I.D. Number: FL0000159 Please print or type information in the appropriate areas.

I OUTFALL LOCATION For each outfall, list the X,Y coordinates and the name of the receiving water.

(latitude/longitude to the nearest 15 seconds)

A. Outfall B. Latitude C. Longitude D. Name of Receiving Water No. (List) Deg. Min. Sec. Deg. Min. Sec.

D-01 1 28 57 31.1 82 42 00.7 Discharge Canal then to Crystal Bay D-012 28 57 31.1 82 42 02.5 Discharge Canal then to Crystal Bay D-091 28 57 24.0 82 42 00.4 Intake Canal then to Discharge Canal D-092 28 57 23.2 82 42 01.9 Intake Canal then to Discharge Canal D-093 28 57 21.6 82 41 56.2 Intake Canal then to Discharge Canal D-094 28 57 34.4 82 42 30.4 Discharge Canal then to Crystal Bay NA - - - - - - intentionally left blank II OUTFALL DESIGN A. Outfall B. Design Configuration and C. D. E. Elevation F. Receiving No. (List) Construction Materials Distance Diameter of Discharge Water Depth from shore Invert (MSL) at POD (MSL)

D-01 1 (4) Fiberglass Pipes 6 ft. 6 ft. - 5 ft. - 12 ft.

D-012 (4) Fiberglass Pipes 6 ft. 6 ft. - 5 ft. - 12 ft.

D-091 (1) Concrete Pipe 2 ft. 2 ft. + 2 ft. - 20 ft.

D-092 (1) Fiberglass Pipe 3 ft. 1 ft. - 1 ft. - 20 ft.

D-093 (1) Steel Pipe 0 ft. 18 in. - 4 ft. - 20 ft.

D-094 Concrete Pipe 1 ft. 24 in. + 2 ft. - 12 ft.

DEP Form 62-620.910(5) 2CS-16 Effective November 29, 1994

FORM 2CS WASTEWATER APPLICATION FOR PERMIT TO DISCHARGE PROCESS WASTEWATER FROM NEW OR EXISTING INDUSTRIAL WASTEWATER FACILITIES TO SURFACE WATERS Facility I.D. Number: FLO000159 Please print or type information in the appropriate areas.

I OUTFALL LOCATION For each outfall, list the X,Y coordinates and the name of the receiving water.

(latitude/longitude to the nearest 15 seconds)

A. Outfall B. Latitude C. Longitude D. Name of Receiving Water No. (List) Deg. Min. Sec. Deg. Min. Sec.

D-095 28 57 21.8 82 41 54.5 Intake Canal then to Discharge Canal D-C2R 28 57 23 82 42 30 Intake Canal then to Discharge Canal D-00F 28 57 31.5 82 41 56.5 Discharge Canal then to Crystal Bay I-FG 28 57 31.5 82 41 56.5 Internal Outfall through D-00F I-FE 28 57 31.5 82 41 56.5 Internal Outfall through D-00F D-00H 28 57 08.8 82 42 12.7 To marshland then to Crystal Bay N/A - I - - - - intentionally left blank 11 OUTFALL DESIGN A. Outfall B. Design Configuration and C. D. E. Elevation F. Receiving No. (List) Construction Materials Distance Diameter of Discharge Water Depth from shore Invert (MSL) at POD (MSL)

D-095 Temporary Pump Placement N/A N/A - 20 ft.

D-C2R Temporary Pump Placement/flex. discharge hoses 2-ft. (2) 4-in 0-ft. - 20 ft.

D-OOF (2) Concrete Pipes 0 ft. 4 ft. -9 ft. - 12 ft.

I-FG Tank that dischages internally to D-00F N/A 4 in. N/A Internal Outfall I-FE (2) tanks that discharge internally to D-OOF N/A 2.5 in. N/A Internal Outfall D-00H (1) Steel Pipe N/A 1 ft. unk. N/A DEP For,,62-620.910(5) 2CS-16 Maeci-e NovembCT29. 1994

FORM 2CS WASTEWATER APPLICATION FOR PERMIT TO DISCHARGE PROCESS WASTEWATER FROM NEW OR EXISTING INDUSTRIAL WASTEWATER FACILITIES TO SURFACE WATERS Facility I.D. Number: FL0000159 Please print or type information in the appropriate areas.

I OUTFALL LOCATION For each outfall, list the X,Y coordinates and the name of the receiving water.

(latitude/longitude to the nearest 15 seconds)

A. Outfall B. Latitude C. Longitude D. Name of Receiving Water No. (List) Deg. Min. Sec. Deg. Min. Sec.

D-071 28 57 34.2 82 42 32.5 Discharge Canal then to Crystal Bay D-072 28 57 35.2 82 42 48.8 Discharge Canal then to Crystal Bay N/A - - - - - - intentionally left blank N/A - intentionally left blank N/A - intentionally left blank N/A - intentionally left blank N/A - intentionally left blank 11 OUTFALL DESIGN A. Outfall B. Design Configuration and C. D. E. Elevation F. Receiving No. (List) Construction Materials Distance Diameter of Discharge Water Depth from shore Invert (MSL) at POD (MSL)

D-071 Concrete Trough 50 ft. 24 ft. - 3 ft. - 12 ft.

D-072 Concrete Trough 50 ft. 24 ft. - 3 ft. - 12 ft.

t .t .t. t DEP Form 62-620.910(5) 2CS-16 Effective November 29. 1994

Facility l.D. Number: FL0000159 III RECEIVING WATER INFORMATION For each surface water that will receive effluent, supply the following information:

A. Name of Receiving Water B. Check One C. D. Type of Classification Receiving Water Fresh Salt or Brackish (Sec Ch.62-302, F.A.C.) (canal, river, lake, etc.)

Crystal Bay El 0 Class III Gulf Intake Canal El 0 Class III Canal E] E]

E] 1:1 E. Minimum 7-day 10-year low flow of the receiving water at each outfall (if appropriate).

F. Identify and describe the flow of effluent from each outfall to a major body of water. A suitably marked map or aerial photograph may be used.

G. Do you request a mixing zone under Rule 62-4.244, F.A.C.? If yes, for what parameters or pollutants?

IV FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined (e.g., for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

B. For each outfall, provide a description of:

I. All operations contributing wastewater to the effluent; including process wastewater, sanitary wastewater, cooling water, and stonnwater runoff;

2. The average flow contributed by each operation; and

3. The treatment received by the wastewater.

Use the space on the next page. Continue on additional sheets, if necessary.

DEP Form 62-620.910(5) 2C5-17 Effective November 29, 1994

IV B. Contd. Facility I.D. Number: FI-0000159 (1) (2) Operation(s) Contributing Flow (3) Treatment Outfall No. (a) Operation (list) (b) Avg. Flow (a) Description (b) List Code from (List) & Units Table 2CS-I D-01 I Once through cond. cooling water 446.4 mgd (see attachment 4) 4-A 2F D-012 Once through cond. cooling water 472.3 mgd (see attachment 4) 4-A 2F D-091 Unit I intake screen wash water 3.11 mgd (see attachment 4) 4-A I-T D-092 Unit 2 intake screen wash water 3.11 mgd (see attachment 4) 4-A I-T D-093 Unit 3 intake screen wash water 5.3 mgd (see attachment 4) 4-A 1-T D-094 Helper Cooling Tower 3.11 mgd (see attachment 4) 4-A I-T intake screen wash water D-095 U-3 Emergency Pump Test Discharge 0.009 mgd (see attachment 4) 4-A DEP Form 62-620.910(5) 2CS-18 Effective November 29, 1994

IV B. Contd. Facility I.D. Number: FLOO00159 (1) (2) Operation(s) Contributing Flow (3) Treatment Outfall No. (a) Operation (list) (b) Avg. Flow (a) Description (b) List Code from (List) & Units Table 2CS-1 D-C2R Plant IWW Treatment Pond Overflow Intermittent (see attachment 4) I-U 1-Y 4-A D-00F Heat Decay System - Once through 43.5 mgd (see attachment 4) 4-A 2-F/H non-contact cooling water (includes ECST internal discharge) 0.002 ECST Discharge 2-J I-FG Secondary Drain Tank (SDT) 0.081 mgd (see attachment 4) 1-0 2-K xx I-FE Laundry & Shower Sump Tank 0.080 (see attachment 4) 2-K 1-Q D-OOH Coal Pile Runoff Intermittent (see attachment 4) 1-U 1-Y 4-A D-071 Helper Cooling Tower once-through 494.64 mgd (see attachment 4) 2-F 4-A cooling water D-072 Helper Cooling Tower once-through 494.64 mgd (see attachment 4) 2-F 4-A cooling water DEP Form62-620.910(5) 2CS-18 Effective November 29, IN94

IV Contd. Facility I.D. Number: FL0000159 C. Except for storm runoff, leaks, or spills, are any of the discharges described in Items 11-A or B intermittent or seasonal?

[ Yes (complete the following table) El No (go to D. below)

(3) Frequency (4) Flow (1) Outfall t2)Operation(s) (a) Days per (b) Months (a) Flow Rate (b) Total Volume No. (List) Contributing Flow(List) Week per Yr. (in mgd) (specify with units) (c) Duration (specify avg.) (specify Long Term Avg. Max. Daily Long Term Avg. Max. Daily (in days) avg.)

D-095 U-3 Emergency Pump Tcst Discharge I 6 0.009 0.009 0.009 gpp 0.009 gpd D-C2R IW\VW Treatment Pond Overflow unk. < I N/A N/A N/A N/A N/A D Coal Pile runoff uk. <I N/A N/A N/A N/A N/A D-071 Helper Cooling Toweronce-through cooling water 7 6 494.64 494.64 89,035.2 mg 89,035.2 mg Io D-072 Helper Cooling Tower once-through cooling water 7 6 494.64 494.64 89,035.2 mg 89,035.2 mg 180 D-094 Helper Cooling Tower Intake Screen Backvash 7 6 3.11 3.11 559.8 mg 559.8 mg 180 N/A (intentionally Icfl blank-) - - - - -

D. Describe practices to be followed to ensure adequate wastewater treatment during emergencies such as power loss and equipment failures causing shutdown of pollution abatement equipment of the proposed/permitted facilities.

E. List the method(s) and location(s) of flow measurement.

V PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility?

Z Yes (complete Item V-B) E] No (go to Section VI)

B. Are the limitations in the applicable guideline expressed in terms of production (or other measure of operation)?

El _Yes (complete Item V-C) Z No (go to Section VI)

C. If you answered "yes" to Item V-B, list the quantity which represents an actual measurement of your level of production, expressed in the terms and units used in the applicable effluent guideline, and indicate the affected outfalls.

1.AVERAGE DAILY PRODUCTION 2. Affected Outfalls

a. Quantity per Day b. Units of Measure c. Operation, Product, Materials, Etc. (specify) (list outfall nos.)

N/A DEP Forn,62-620.910(5) 2CS-19 Effective November 29, 1994

Facility I.D. Number: FL0000159 VI IMPROVEMENTS A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement order, enforcement compliance schedule letter, stipulations, court orders, and grant or loan conditions.

Z Yes (complete the following table) El No (go to Item VI-B)

1. Identification of Condition, 2. Affected Outfalls 3. Brief Description 4. Final Compliance Date Agreement, Etc. a. No. b. Source of Discharge of Project a. Required B. Projected (See Attachment 5)

B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual or planned schedules for construction.

F Mark "X" if description of additional control programs is attached.

VII INTAKE AND EFFLUENT CHARACTERISTICS A, B, & C: See instructions before proceeding--Complete one set of tables for each outfall -- Annotate the outfall number in the space provided. NOTE: Tables VII-A, VII-B, and VII-C are included on separate sheets number VII-I through VII-9.

D. Use the space below to list any of the pollutants listed in Table 2CS-3 of the instructions, which you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in your possession.

1. Pollutant 2. Source 1.Pollutant 2. Source N/A DEP Form 62-620.910(5) 2CS-20 Ef ective November 29. 1994

Facility I.D. Number: FLO000159 VIII POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item VII-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or by-product?

DYES (list all such pollutants below) Z NO (go to IX)

IX BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years?

Z YES (identify the test(s) and describe their purposes below) [] NO (go to Section X)

Acute and/or Chronic WET performed bi-monthly or quarterly (initially) and semi-annually on Outfall D-OOF in conjunction with treatment of the Heat Decay System using Betz CT 1300 (ClamTrol) - see attachment 6 for summary of results.

Testing performed by Hydrosphere Research, 11842 Research Circle, Alachua, FL 32615 FL-NELAP Cert. # EE82295 X CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm?

E YES (list the name, address, telephone number, and certification number of, and pollutants analyzed by each such laboratory or firm below) LI NO (go to Section XI)

A. Name B. Address C. Telephone D. Pollutants Analyzed (list)

(area code & no.)

(see att. 5, Supplement No. 1)

DEP Form 62-620.910(5) 2CS-21 Effective November 29. 1994

Facility I.D. Number: FL0000159 XI CONNECTION TO REGIONAL POTW A. Indicate the relationship between this project and area regional planning for wastewater treatment. List steps to be taken for this industrial wastewater facility to become part of an area-wide wastewater treatment system.

N/A XII-A CERTIFICATIONS FOR NEW OR MODIFIED FACILITIES This is to certify the engineering features of this pollution control project have been designed by me and found to be in conformity with sound engineering principles, applicable to the treatment and disposal of pollutants characterized in the permit application. There is reasonable assurance, in my professional judgment, that the pollution control facilities, when properly maintained and operated, will discharge an effluent that complies with all applicable statutes of the State of Florida and the rules of the Department. It is also agreed that the undersigned, if authorized by the owner, will furnish the applicant a set of instructions for the proper maintenance and operation of the pollution control facilities and, if applicable, pollution sources.

Signature Company Name Address Name (please type)

(Affix Seal) Florida Registration No.:

Telephone No::

Date I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

Name & Official Title (Please type or print) Signature Telephone No. (area code & No.) Date Signed DEl' Form~ 62-620.910(5) 2CS-22 Effective Nov'ember

29. 1994

XII-l-CERrnFlCATIONS FOR PERMIIT RENEWALS This to cnrtitf the'enginecring features of this.pollution control .project have been examined by me and Ibund to be in

.conlbrmity with sound enrgineering. principles. applicablceto the treatment and disposal of pollutants characterized in ihe permii application; Thre. is reasonatble assurance, in niy professional. judgment, that tge pollution control facilities, when properly maintained anid operated, wil Idischnrge an effluent that. complies with all applicable .statutes of the State of' Florida And the rulcs of the Dcpartment.

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_______,_____.________________________,___ ,\ddress: Cn ti i,¢ Cvpany Nu Mdrss.

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gatiering:the information, Ihe irifbrmbtion, submitted is, t9 thebest of:ny knowledge and belie*l true, accurate, and

.c6iptetede I ,m 1arthat the:rezaro signifidant penalties foe. submitling fals6 infformation including the possibility of fine and i'ptipnment for:kno.wing vyilations-kl~nby A, Outum,ý SltaionfiMa imý,Ckstal PRivFos0itPltrnI &Fil 011s Napinc& OfficialtTitle (Pleasetype .... orp

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Facility ID. Number: FL0000159 Outfall No. Intake PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional)

Pollutant a. Max. Daily Value b. Max. 30-day Value c. Annual Avg. Value d. No. of a. Concentration b. Mass a. LonTerm Av.Value b. No. of (I) Conc. (2) Mass (l) Conc. (2) Mass (l Conc. (2) Mass Analyses (I) Conc. (21 Mass Analyses aCaxu*xaumBuheniA <2 1 mg/L

b. Chemical Oxygen 1420 1 mg/L Demand (COD)

c. Total Organic 8.2 1 mg/L Carbon (TOC)

d. Total Suspended 16.0 I mg/L Solids (TSSI I I e.Total Ningojn (as N) 1.4 1.01 4 mg/L f Total Phosphorus (as P) 0.11 0.061 4 mg/L

g. Ammonia (as N) < 0.02 1 mg/L

h. Flow - actual or Value Value Value Value projected

i. Flow - design Value Value Value Value

j. Specific Conductivity Value 34,733 Value Value I umhos/cm Value

k. Temperature (winter) Value30.5 Value Value 18.6 20 °C Value I. Temperature (summer) Value28.4 Value Value 34.2 18 Value m.. pH Min. 7.52 1 M. 8.50 Mi.. IMax. 49 STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Conc. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Conc... (2) Mass (I) Conc. (2) Mass (I) Conc. (21 Mass (I) Conc. (2) Mass

a. Bromide El [] 37.4 I mg/L (24949-67-91

b. Chlorine, El l < 0. 1 1 mg/L Total Residual

c. Color E I El 45.0 I PCU

d. Fecal Coliform El El <2 1 CFUII00 mI

e. Fluoride C < 5.0 I mg/L (16984-48-8)

f. Nitrate-Nitrite 13 0.900 0.313 4 mg/L (as N) I I I VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. Intake

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass

g. Nitrogen. Total 03 0l 0.74 I mg/L Organic (as N)

b. Oil and grease 0 < 1.3 I mg/L

i. Phosphorus, Total 0 0 0.11 0.061 4 mg/L (as P) (7723-14-0)

.... .. .... t.. . . *: ........ ____,_: _________ _______,__,g*'71!

(II Alpha, Total 0 El 3.72 (+/- 1.84) I pCi/L (2) Beta, Total 01 13 1 pCi/L (3) Radium, Total 0 [ < 1.68 (+/- I pCUL 0.985)

(4) Radium 226, Total 01 El < 0.95 (+/- I pCi/L 0.624)

k. Sulfate (as S04 E0 01 1,600 I mg/L (14808-79-8)

1. Sulfide (as S) 01 03 < 1.0 I mg/L

m. Sulfite (as SO3) 03 01 < 10 I mg/L (14265-45-3) 1

n. Surfactants E0 E0 0.38 I mg/L

o. Aluminum, Total 0 03 0.094 (I) I mg/L (7429-90-5)

p. Barium. Total 01 01 0.012 t mg/L (7440-39-3)

q. Boron, Total 01 03 3.3 I mg/L (7440-42-8)

r. Cobalt, Total 01 01 < 0.005 1 mg/L (7440-48-4) 1

s. Iron, Total 01 El 0.16 I mg/L (7439-89-6)

t. Maagnesium, Total 01 El 898.0 1 mg/L (7439-95-4)

u. Molybdenum, Total 0l 01 0.0074 (I) I mg/L (7439-98-7)

v. Manganese, Total 0 D < 0.0125 I mg/L (7439-96-5) 1

w. Tin, Total 0l 01 < 0.025 t mg/L (7440-31-5)

x. Titanium, Total C3 [0 < 0.025 I mg/L (7440-32-6)

VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. Intake PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to detcrmine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions tor additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

t. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. lifavailable) testing lieved lieved (if available) (if available) required present absent (I) Cone. I (2) Mass (t) Cone.

2t)MCone.)[.(2)

Mass [1)Mass Analyses (1) Conc. (2) Mass Analyses iMFTALS,4CYAN1DE.AND3T'TOItHEOtS.ý..

,"5J:. . ",, _. .". .. :.

I M. Antimony, Total El E] El < 5.0 1 ug/L (7440-36-0) 2M. Arsenic, Total El 0"l < 5.0 I ug/L (7723-14-0) 3M. Beryllium, Total l El El < 0.25 t ug/L (7440-41-7) 4M. Cadmium, Total El El El < 0.50 1 ug/L (7440-43-9) 5M. Chromium, Total E El El < 2.5 1 ug/L (7440-47-3) 6M. Copper, Total El El l < 4.6 t ug/L (7440-50-8) 7M. Lead, Total El El El < 2.5 1 ug/L (7439-92-1) 8M. Mercury, Total El [El E 0.000911 t ug/L (7439-97-6) 9M. Nickel, Total El El E < 2.5 I ug/L (7440-02-0)

IOM. Selenium, Total El E l < 7.5 1 ug/L (7782-49-2)

I IM.Silver, Total El El El <0.25 1 ug/L (7440-22-4) 12M. Thallium. Total El El E < 2.5 1 ug/L (7440-28-0) 13M. Zinc, Total l El l < 10.0 t ug/L (7440-66-6) 14M. Cyanide. Total El El E < 5.0 t ug/L (57-12-5) 15M. Phenols, Total El El < 5.0 1 ug/L 2,3,7,8-Tetra- El El 0 chlorodibenzo-P- Dioxin (I1764-01-6) 77 IV.Acrolein [] [ ] <10.0 1 ug/L (107-02-8) 2V. Acrylonitrile < 5.0 1 g/L (107-13-1) 1 1 T VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. Intake

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Conc. (2) Mass (1) Conc. (2) Mass )nc (2) Mass CC 1 - VOLATILE COM, ,UNDS (pontinual ,

IRACF1ON : ,,' "-

3V. Benzene Ql EL El < 0.50 1 ug/L (71-43-2) 4V. Bis IChloromethyl) Ether 11 0 0 (542-88-1) 5V. Bromoform < 0.50 ug/L (75-25-2) 6V. Carbon Tetrachloride 0l 11 El < 0.50 I ug/L (56-23-5) 1 7V Chlorobenzene El El El < 0.40 I ug/L (108-90-7) 8V. Chlorodi- l El El < 0.25 I ug/L bromomethane ( 24 1) 9V. Chloroethane 0l El El < 0.61 I ug/L (74-00-3)

IOV. 2-Chloro-ethylvinyl l El El < 5.0 I ug/L Ether ( 10-75-8)

I IV. Chloroform El El El <0.50 I ug/L (67-86-3) 12V. Dichloro- 0l El El < 0.30 t ug/L bromomethane (75-24-4) 13V. Dichloro- El El El < 0.50 I ug/L difluotmmthane (75-71-8) 14V. IJ -Dichloroethane l El El <0.50 I ug/L (75-34-3) 1 1 15V. 1,2-Dichloroethane EL El El <050 I ug/L 1107-06-2) 16V. 1,1-Dichloroethylene l E El < 0.50 I ug/L (75-35-4) 17V. 1,2,-Dichloropmpane El El El < 0.50 1 ug/L (78-87-5) 18V. 1,3-Dichlompropylene l El l < 0.50 1 ug/L (542-75-6) 1 1 19V. Ethylbenzene l El l < 0.50 1 ug/L (100-41-4) 20V. Methyl Bromide El El El < 0.50 I ug/L (74-83-9) 21V. Methyl Chloride l El l < 0.50 I ug/L (74-87-3) 22V. Methylene Chloride 0l El El < 2.5 I ug/L (74-98-2) 1 1 23V. 1.1,2.2-Tetra- 0l El El <0.17 I ug/L chloroethane (79-34-5) _

24V. Tetrachloroethylene El El El < 0.50 I ug/L (127-18-4)1 VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO00O159 Outfall No. Intake

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

G.CUthS.FRAGCtON -V.OL IT,IEI51COM f UNDi (cdnt ttll)

(I)Conc. [ (2) Mass (1)e

,. < *9 (2) Mass (I) Conc.

)

(2) Mass S _____._,

25V. Toluene (108-88-3) 11 El El < 0.50 I ug/L 26V. 1,2-Trans- E E El < 0.50 I ug/L Dichlotnethvlene (156-60-5) 27V. 1,12-Trichloaetra E E E] < 0.50 I ug/L (71-55-6) 28V. l.1,2-Trichlomethane l El < 0.50 I ug/L (79-00-5) 29V. Trichloroethylene 0l El El < 0.50 I ug/L (79-01-6) 1 1 1 30V. Trichloro- U E El < 0.66 I ug/L fluoromethane (75-69-4) 31V. Vinyl Chloride l E El < 0.53 1 ug/L (75-01-4)

IA. 2-Chlorophenol l El 74m El < 0.78

- -ý 1 ug/L

-W -ý (95-57-8) 2A. 2,4-Dichlorophenol El El El < 0.64 I ug/L (120-83-2) 3A. 2,4-Dimethylphenol El El El < 1.8 I ug/L (105-67-9) 4A. 4,6-Dinitro-O-Cresol El El El < 1.5 1 ug/L (534-53-I) 5A. 2,4-Dinitrophenol El [1 1 < 1.8 I ug/L (51-28-5) 6A. 2-Nitrophenol El El El < 0.93 I ug/L (88-75-5) 7A. 4-Nitrophenol El [E El < 1.2 I ug/L (100-02-7) 8A P-Chloro-M-Cresol l El El < 0.71 I ug/L (59-50-7) 9A Pentachlorophenol E] El El < 0.76 I ug/L (87-86-5) 10A Phenol 0 0 0 < 0.62 I ug/L (108-95-2)

I I A 2,4.5-Trichloro- El El El < 0.79 I ug/L phenol (88-06-2)

I B. Acenaphthene 0 0 0 <0.018 ug/L (63-32-9) 2B. Acenaphtylene 11 El 11 < 0.017 1 ug/L (208-96-8) 3B. Anthracene 0 11 13 < 0.018 I ug/L (120-12-71 4B. Benzidine El El < 0.88 1 ug/L (92-87-5) 1 VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. Intake

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses 5B. Benzo (a) Anthracene required l

F_ present El absent El (I) Cone.

< 0.013 (2) Mass (t) Cone. (2) Mass (1) Cone. (2) Mass I ug/L (1) Cone. (2) Mass (56-55-3) 6B. Benzo (a) Pyrene l El El < 0.021 1 ug/L (50-32-8) 7B. 3,4-Beruo-fluoranthene El El E] < 0.016 I ug/L (205-99-2) 8B. Benzo (ghOi Perylene El 1: El < 0.016 I ug/L (191-24-2) 9B. Benzo (k) Fluoranflthe(207- El El El < 0.022 I ug/L 08-9) 10B. Bis (2-CkdnthmrEy) El El El < 3.4 1 ug/L Methane (H 1-91-1)

I I B. Bis (2-chloroet*hl El El El < 0.86 I ug/L Ether (111-44-4) 12B. Bis (2-Cwtvp ) El El El < 0.84 1 ug/L Ether (102-60-1) 13B. Bis (2-Ethylhe.xy) l El El < 0.92 I ug/L Phthalate (117-81-7) 14B. 4-Bromophenyl l El l < 0.77 I ug/L Phenyl Ether (101-55-3) 15B Butyl Benzyl Phthalate El El < 0.83 I ug/L (84-68-7) 16B. 2-Chlounapthalene El El l < 0.92 I ug/L (91-58-7) 17B. 4-Chlorophenyl l El l < 0.72 I ug/L Phenyl Ether (7005-72-3) 18B. Chrysene l El l < 0.015 I ug/L (218-01-9) 19B. Dibenzo (a,h) El El El < 0.018 I ug/L Anthracene (53-70-3) 20B. 1,2-Dichlomhbenr El 0l El < 0.78 I ug/L (95-50-l) 21B. 1,3-Dichlonrbenzene l El l < 0.87 I ug/L (541-73-1) 22B. 1,4-Dichlornbenzene l El l < 0.88 I ug/L (106-46-7) 23B. 3,3-Dichlombenzidine l El El < 0.79 I ug/L (92-94-1) 24B. Diethyl Phthalate l El El < 0.59 I ug/L (84-66-2) 25B. Dimethyl Phthalate El El El < 0.73 1 ug/L (131-11-3) 26B. Di-N-Butyl Phthalate El El El < 0.47 I ug/L (84-74-2) 27B. 2,4-Dinitrotoluene El El El < 0.61 1 ug/L (121-14-2) 28B. 2,6-Dinitrotoluene El El El < 0.73 1 ug/L (606-20-2)

VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility 1D. Number: FLO000159 Outfall No. Intake

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a.. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (I) Cone. (2) Mass (l) Conc. (2) Mass (I) Cone. (2) Mass 29B. Di-N-Octyl Phthalate El El El < 1.0 I ug/L (117-84-0) 30B. 1,2-Diphenylhydrazine l El El < 0.76 I ug/L (asm.4fo*eiiae)( 122-66-7) 31 B. Fluoranthene l El 0l < 0.012 1 ug/L (206-44-0) 32B. Fluorene (86-73-7) El 11 < 0.011 I ug/L 33B. Hexachlorobenzene l 13l < 0.92 I ug/L (118-74-1) 34B. Hexachlorobutadiene El El E] < 1.2 I ug/L (87-68-3) 35B. FLQH=d. n El [l E] < 1.5 I ug/L (77-47-4) 36B. Hexachloroethane l El l < 0.82 I ug/L (67-72-I) 37B. Indeno (I.2.3-ci1) El 0l El < 0.018 I ug/L Pyrene ( 193-39-5) 38B. Isophorone El El < 0.84 I ug/L (78-59-1) 390. Naphthalene El 1: E] < 0.015 I ug/L (91-20-3) 40B. Nitrobenzene C1 El El < 1.3 I ug/L (98-95-9) 41B N-Ni sodira El < I.I I ug/L (62-75-9) 42B. N-Nitrosodi-N- El El El < 1.1 I ug/L Propylamnine (621-64-7) 43B. N-Nitro- El El El <0.57 I ug/L sodiphenylamine (8&30-6) 44B Phenanthrene El 0] l < 0.016 I ug/L (85-01-8) 45B. Pyrene (129-00-0) El 0l 0l < 0.0097 1 ug/L 46B. 12,4-Trichlorubenrene l 0l El < 0.95 I ug/L (120-82-1)

IP. Aldrin (309-00-2) El El 0 2P. -BHC (319-84-6) El El 0 3P -BHC (319-85-7) El El 0 4P. -BHC (58-89-9) El El 0 5P. -BHC (319-86-8) El El 0 VII-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. Intake

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (I) Conc. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass 6P. Chlordane (57-74-9) 11 51 0 7P. 4,4'-DDT (50-29-3) 5 0 0 11 8P. 4,4'-DDE (72-55-9) 0] E0 0 9P. 4,4'-DDD (72-54-8) 0 0 0 lOP. Dieldrin (60-57-1) 0:1 0 0 I I P. -Endosulfan 0 0 0 (115-29-7) 12P. -Endosulfan 0 0 0 (115-29-7) 13P. Endosulfan Sulfate 0 0 0 (1031-07-8) 14P. Endrin (72-20-8) 0 0 0 15P. Endrin Aldehyde 0 0 0 (7421-92-4) 16P. Heptachlor 0l 0 0 (76-44-8) 17P. Heptachlor Epoxide 0 0 0 (1024-57-3) 18P. PCB-1242 0 0 0 (53469-21-9) 19P. PCB-1254 0 0 0 (11097-69-1) 20P. PCB-1221 0 0 0 (11104-28-2) 21P. PCB-1232 01 0] 0 (11141-16-5) 22P. PCB-1248 0 0 0 (12672-29-6) 23P. PCB-1260 0 0 0 (11096-82-5) 24P. PCB-1016 0 0I (12674-11-2) 25P. Toxaphene 0 0 [

(8001-35-2)

VII-8 DER Fomx 62-620,910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. POD PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional)

Pollutant a. Max. DailI Value b. Max. 30-day Value c. Annual Avg. Value d. No. of a. Concentration b. Mass a. Long Term Avsg. Value b. No. of (I) Conc. (2) Mass (I) Cone. (2) Mass (I) Conc. (2) Mass Analyses (I) Conc. 12) Mass Analyses aorucamvs xxihmiuA 169 I mg/L O%=,e,* ,urd (CBOD)

b. Chemical Oxygen 2170 I mg/L Demand (COD)

c. Total Organic 9.3 I mg/L Carbon (TOC)

d. Total Suspended < 5.0 1 mg/L Solids (TSS) e.'TotalNitruen (asN) 0.95 0.715 4 mngL f Total Phosphonts (as P) 0.096 0.060 4 mg1/L

g. Ammonia (as N) 0.041 (I) I mg/L

h. Flow - actual or Value Value Value Value projected

i. Flow - design Value Value Value Value

j. Specific Conductivity Value 36,936 Value Value I umhos/cm Value

k. Temperature (winter) Value35.7 Value Value 23.3 20 °C Value I. Temperature (summer) Value35.6 Value Value 30.2 18 *C Value m.. PH Min.7 6.71 Mi M . I STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollittant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Conc. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Cone... (2) Mass (I) Conc. (2) Mass (1) Cone. (2) Mass (I) Conc. (2) Mass

a. Bromide 0 0 33.4 I mg/L (24949-67-9)

b. Chlorine, 0 < 0. 1 mg/L Total Residual

c. Color 0l 01 45 I PCU

d. Fecal Coliform E] 01 2.0 I CFU/100 mL

e. Fluoride 0] 0] < 5.0 I mg/L (16984-48-8)

f. Nitrate-Nitrite 0 03 0.081 0.035 4 mg/L (as N)

VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FLOOOO 159 Outfall No. POD

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if availavailable) vailable) Analyses Analyses present absent s (1) Con. (2) Mass (1) Conc. (2) Mass (p) Conc. (2) Mass (i) Conc. (2) Mass

g. Nitrogen, Total 0.83 I mg/L Organic (as N)

h. Oil and grease 1:1 0 < 1.3 1 mg/L

i. Phosphorus. Total [] 11 0.096 0.060 4 mg/L (as P) (7723-14-0)

(1) Alpha, Tota 1 1: E 4.17(+/- 1.48) 1 pCi/L (2) Beta, Total [ I] pCi/L (3) Radium, Total El 11 < 1.61 (+/- I pCi/L 0.992)

(4) Radium 226, Total El El 0.944 (+/- 1 pCi/L 0.630)

k. Sulfate (as SO ) El 0" 1,510 1 mg/L (14808-79-8)

I. Sulfide (as S) El El < 1.0 I mg/L

m. Sulfite (as SO 3 ) 0l 0l < 10 1 mg/L (14265-45-3)

n. Surfactants El El 0.44 I mg/L

o. Aluminum, Total El El 0.460 I mg/L (7429-90-5)

p. Barium, Total El El 0.012 I mg/L (7440-39-3)

q. Boron, Total El El 3.01 I mg/L (7440-42-8)

r. Cobalt, Total El El < 0.005 I mg/L (7440-48-4)

s. Iron, Total El El 0.685 I mg/L (7439-89-6)

t. Maagnesium, Total El El 855 I mg/L (7439-95-4)

u. Molybdenum, Total El El 0.0075 (I) I mg/L (7439-98-7)

v. Manganese, Total l El < 0.0025 I mg/L (7439-96-5)

w. Tin, Total 0l El < 0.025 I mg/L (7440-31-5)

x. Titanium. Total El El < 0.25 1 mg/L (7440-32-6)

Vll-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO00O159 Outfall No. POD PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (j)Cone. (2)Mass (I)Conc. 3(2) Mass (1())Con. 1(2) Mass (1)Conc. (2) Mass

'NETAL$. CyA3.jDE;AND.T OTAUPHENOLS'."4 5 C .. . . _ .. __ ... .. sqe..

IM.Antimony. Total 51 51 5l < 5.0 1 ug/L (7440-36-0) 2M. Arsenic, Total 5 < 5.0 1 ug/L (7723-14-0) 3M. Bervllium. Total 5 < 0.25 1 ug/L (7440-41-7) 4M. Cadmium, Total 5 5 < 0.50 1 ug/L (7440-43-9) 5M. Chromium, Total 5 5 5 < 2.5 1 ug/L (7440-47-3) 6M. Copper, Total 5 5 5 < 4.6 1 ug/L (7440-50-8) 7M. Lead, Total 0 51 5l < 2.5 1 ug/L (7439 1) 8M. Mercury, Total 0 51 E] 0.00145 1 ug/L (7439-97-6) 1 1 1 9M. Nickel, Total 5 5 < 2.5 I ug/L (7440-02-0) 10M. Selenium, Total 5 < 7.5 I ug/L (7782-49-2) 11M. Silver, Total 5 51 0 5 < 0.25 I ug/L (7440-22-4) 12M. Thallium, Total 5 < 2.5 I ug/L (7440-28-0) 13M. Zinc, Total 5 < 10.0 I ug/L (7440-66-6) 14M. Cyanide, Total 5 < 5.0 I ug/L (57-12-5) 15M. Phenols. Total < 5.0 ug/L 2,3,7,8-Tetra- 0 10 chlorodibenzo-P-Dioxin (764-01-6) 7 IV. Acroiein [1 < I 0.0 I ug/L T

L] CJ (107-02-8) 1 1 2V. Acrylonitrile t E] I < 5.0 1 ug/L (107-13-1)

VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. POD

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (1) Conc. (2) Mass (I) Conc. (2) Mass (I)_C_7.. (2) Mass

ýG/NiS/iFRýAVC~TfON::'VOLATIIJ (ýOMPUNDS(iS e,, .u-.:xi::>. ,

3V. Benzene l El l < 0.50 I ug/L (71-43-2) 4V. Bis (Chloromethyl) Ether 0l 0l 0 (542-88-1) 5V. Bromoform l El (] < 0.50 I ug/L (75-25-2) 6V. Carbon Tetrachloride 11 11 El < 0.50 I ug/L (56-23-5) 7V Chlorobenzene 11 El 13 < 0.40 I ug/L (108-90-7) 8V. Chlorodi- 11 El El < 0.25 I ug/L bromomethane (124 I) 9V. Chloroethane l El El < 0.61 I ug/L (74-00-3) 10V. 2-Chloro-ethylvinyl l El El < 5.0 1 ug/L Ether (110-75-8)

I V. Chloroform El El El < 0.50 I ug/L (67-86-3) 12V. Dichloro- l El El < 0.30 I ug/L bromomethane (75-24-4) 13V. Dichloro- El El l < 0.50 I ug/L difuomethane (75-71-8) 14V. It,-Diehloroethane El [E [E <0.50 1 ug/L (75-34-3) 15V. 1,2-Dichloroethane El El El < 0.50 I ug/L 1107-06-2) 16V. I, I-Dichloroethylene El El El < 0.71 1 ug/L (75-35-4) 17V. 1,2,-Dichlormpmopane El El El < 0.50 1 ug/L (78-87-5)

I 8V. 1,3-Dichlorupmpylene l El El < 0.50 1 ug/L (542-75-6) 19V. Ethylbenzene l El El < 0.50 I ug/L (100-41-4) 20V. Methyl Bromide l El El < 0.50 I ug/L (74-83-9) 21IV. Methyl Chloride El El E < 0.50 I ug/L (74-87-3) 22V. Methylene Chloride El El El < 2.5 I ug/L (74-98-2) 1 1 1 1 1 1 1 23V. 1,1,2,2-Tetra- El El El <0.17 aug/L chloroethane (79-34-5) 24V. Tetrachloroethylene El El El < 0.50 I ug/L (127-18-4)

VI14 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. POD

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent JJ Gc/MISFRACTION -. VOLA3LEcLOMR.O.UN DS (continued) .

(I) Conc.

(2) Mass

[...

(I) Conc. (2) Mass (l)Conc. (2) Mass (I) Conc. (2) Mass 25V. Toluene (108-88-3) l El El < 0.50 I ug/L 26V. 1,2-Trans- El El El < 0.50 1 ug/L Dichlomaethylene (156-60-5) 27V. 1,1,2-Tfichlolts.rane El El El < 0.50 I ug/L (71-55-6) 28V. lI,2-Trichklooethane El El l < 0.50 I ug/L (79-00-5) 29V. Trichloroethylene El El El < 0.50 I ug/L (79-01-6) 30V. Trichloro- El El l < 0.66 I ug/L fluoromethane (75-69-4) 3IV. Vinyl Chloride l El El < 0.53 I ug/L (75-01-4)

IA. 2-Chlorophenol El El El < 1.3 1 ug/L (95-57-8) 2A. 2,4-Dichlorophenol El El El < I I ug/L (120-83-2) .

3A. 2,4-Dimethylphenol El El El < 2.9 1 ug/L (105-67-9) 4A. 4.6-Dinitro-O-Cresol l El El < 2.4 1 ug/L (534-53-1) 5A. 2,4-Dinitrophenol l El El < 2.9 1 ug/L (51-28-5) 6A. 2-Nitrophenol El El El < 1.5 I ug/L (88-75-5) 7A. 4-Nitrophenol l l El < 2.0 I ug/L (100-02-7) 8A P-Chloro-M-Cresol El El El < 1. I I ug/L (59-50-7) 9A Pentachlorophenol El El El < 1.2 1 ug/L (87-86-5) 10A Phenol l El El < 1.0 I ug/L (108-95-2)

I A 2,4,5-Trichloro- El El El < 1.3 I ug/L phenol (88-06-2)

I B. Acenaphthene 0 l1El < 0.036 I ug/L (63-32-9) 2B. Acenaphtylene l El < 0.035 1 ug/L (208-96-8) _ _

3B. Anthracene (120-12-7)

41. Benzidine l

l El El

< 0.036

< 1.4 7 I I

ug/L ug/L (92-87-5)

VII-5 DER Fom 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. POD

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (ifavailable) testing lieved lieved (if available) {ifavailable) Analyses Analyses required present absent

{1) Conc. (2) Mass (1) Conc. (2) Mass (l)Conc. 12) Mass (1) Conc. 12) Mass 5B. Benzo (a) Anthracene l El El < 0.025 1 ug/L (56-55-3) 6B. Benzo (a) Pyrene l El El < 0.042 1 ug/L (50-32-8) 7B. 3,4-Bervo-fluornthene l El El < 0.031 1 ug/L (205-99-2) 8B. Benzo (Rhi) Petylene l E [] < 0.033 1 ug/L (191-24-2) 9B. Benzo (4) Fluoranthene(207- l El E < 0.044 I ug/L 08-9) 10B. Bis P-Ch/lbroa . El El < 5.4 I ug/L Methane (111 I1)

I lB. Bis (2-chloroethyl) El El El < 1.4 I ug/L Ether (I H 4) 12B. Bis1ý?QOzpIYW El El El < 1.3 I ug/L Ether (102-60-I) 13B. Bis (2-EittylheAyI) El El El < 1.5 I ug/L Phthalate ( 117-81-7) 14B. 4-Bromophenyl El El El < 1.2 I ug/L Phenyl Ether 1101-55-3) 15B Butyl Benzyl Phthalate El El El < 1.3 I ug/L (84-68-7) 16B. 2-Chlonphlhaiene El El El < 1.5 I ug/L (91-58-7) 17B. 4-Chlorophenyl El El El < 1.1 I ug/L Phenyl Ether (7005-72-3) 18B. Chrysene El El El < 0.029 1 ug/L (218-01-9) 19B. Dibenzo (a.h) El El El < 0.036 1 ug/L Anthracene (53-70-3) 20B. 1,2-Dichlo*,orenene El El El < 1.3 1 ug/L (95-50-I) 1 211B. 1,3-Dichlombenzene El El El < 1.4 I ug/L (541-73-1) 22B. 1,4-Dichlombenzene El El El < 1.4 1 ug/L (10&46-7) 23B. 3,-$Dichlorubenzidine El El El < 1.3 I ug/L (92-94-4) 24B. Diethyl Phthalate El El El < 0.94 1 ug/L (84-66-2) 1 1 1 25B. Dimethyl Phthalate El El El < 1.2 1 ug/L (131-11-3) 26B. Di-N-Butyl Phthalate El El El < 0.76 I ug/L (84-74-2) 27B. 2,4-Dinitrotoluene El El El < 0.98 I ug/L (121-14-2) 28B. 2,6-Dinitrotoluene El El El < 1.2 I ug/L (606-20-2) 1 1 1 1 1 1 VII-6 DER Fom 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. POD

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a.. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (I) Cone. (2) Mass (I) Conc. (2) Mass (I) Cone. (2) Mass 29B. Di-N-Octyl Phthalate Q El El < 1.7 I ug/L (117-84-0) 30B. 1,2-Diphenylhydrazine C3 El 1: < 1.2 I ug/L (asAZrbY tnve) (12--66-7) 31 B. Fluoranthene l El El < 0.023 1 ug/L 1206-44-0) 32B. Fluorene (86-73-7) l El l < 0.021 I ug/L 33B. Hexachlorobenzene l El El < 1.5 I ug/L (118-74-1) 34B. Hexachlorobutadiene El 11 < 2.0 I ug/L (87-68-3) 35B. FI-bdax,* El El El < 2.4 I ug/L (77-47-4) 36B. Hexachloroethane El El El < 1.3 I ug/L (67-72-I) 37B. Indeno (1.2.3-cd) l El l < 0.036 I ug/L Pyrene (193-39-5) 38B. Isophorone El El El < 1.3 I ug/L (78-59-1) 39B. Naphthalene El El El < 0.029 1 ug/L (91-20-3) 40B. Nitrobenzene l El l < 2.0 I ug/L (98-95-9) 5 41B N-Niuxlxnrhy"rrin El El El < 1.8 I ug/L (62-75-9) 42B. N-Nitrosodi-N- El El El < 1.7 I ug/L Propylamine (621-64-7) 43B. N-Nitro- El El El < 0.92 I ug/L sodiphenylamine (86-30-6) 44B Phenanthrene El El El < 0.031 I ug/L (85-01-8) 45B. Pyrene (129-00-0) El El El < 0.019 I ug/L 46B. lU4-Tbchloktttenzene l El El < 1.5 1 ug/L IP. Aldrin (309-00-2) El El 0 2P. -BHC (319-84-6) El El [

3P -BHC (319-85-7) El El 0 4P. -BHC (58-89-9) El El 0 5P. -8HC (319-86-8) El El 0 V11-7 DER Fomi 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. POD

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass 6P. Chlordane (57-74-9) El El 0 7P. 4,4'-DDT (50-29-3) El C3 10 8P. 4,4'-DDE (72-55-9) El El E 9P. 4,4'-DDD (72-54-8) El El 0 lOP. Dieldrin (60-57-I) El El 0 I I P. -Endosulfan El El 0 (115-29-7) 12P. -Endosulfan E3 E3 0 (115-29-7) 13P. Endosulfan Sulfate El El 0D (1031-07-8) 14P. Endrin (72-20-8) El El 0 15P. Endrin Aldehyde El El ED (7421-92-4) 16P. Heptachlor El El [

(76-44-8) 17P. Heptachlor Epoxide El El 0 (1024-57-3) 18P. PCB-1242 El El ED (53469-21-9) 19P. PCB-1254 El El 0 (11097-69-1) 20P. PCB-1221 El El 0 (11104-28-2) 21P. PCB-1232 0E 0 (11141-16-5) 22P. PCB-1248 El El 0 (12672-29-6) 23P. PCB-1260 El El 0 (11096-82-5) 24P. PCB-1016 El El 0 (12674-11-2) 25P. Toxaphene El El 0 (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-011 PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional)

Pollutant a. Max. Daily Value b. Max. 30-day Value c. Annual AN'g.Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (I) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass Analyses (I) Cone. (2) Mass Analyses anmwanxes Bfxuiimu <2 I mg/L

b. Chemical Oxygen 1460 1 mg/L Demand (COD)

c. Total Organic 8.0 1 mg/L Carbon (TOC)

d. Total Suspended 22.5 I mg/L Solids (TSS) e.Total Nitrogen (as N) 0.65 I mg/L f Total Phosphorus (as P) 0.062(I) I mg/L g.Ammonia (as N) <0.02 I mg/L

h. Flow - actual or Value 446.4 Value 446.4 Value MGD Value projected I I II

i. Flow - design Value 446.4 Value 446.4 Value MGD Value

j. Spific Conductivity Value 38.076 Value Value I umhos/cm Value

k. Temperature (winter) Value35.l Value Value 22.6 12 °C Value I. Temperature (summer) 1 Value39.7 Value Value 34.0 12 .C Value m..PH H.8 Min. Mn 8 8Max.

1 Min. 1 STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Conc. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Conc... (2) Mass (I) Conc. (2) Mass (I) Conc. (21 Mass (1)

IConc. (2) Mass

a. Bromide E] '- 46.1 I mg/L (24949-67-9)

b. Chlorine. 0 0 < 3 I mg/L Total Residual

c. Color 0 [0 35.0 I PCU

d. Fecal Coliform 0 01 < 2 I CFU/100 mL

e. Fluoride 0 0 < 1.2 I mg/L (16984-48-8)

f. Nitrate-Nitrite 0 0] 0.053 I mg/L (as N) I I I I I VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. D-011

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses preuent absent (I) Conc. (2) Mass (I) Conc. (2) Mass (I) Cone. (2) Mass (1) Conc. (2) Mass

g. Nitrogen, Total El El 0.60 I mg/L Organic (as N)

h. Oil and grease l El < 1.5 1 mg/L

i. Phosphorus, Total El El 0.062 (I) I mg/L (as P) (7723-14-0)

(1) Alpha, Total 6.01 1.73) I pCi/L (2) Beta, Total El 11 249 ( 96.7) I pCi/L (3) Radium, Total El El 1.61 (+/- I pCi/L 0.998)

(4) Radium 226, Total El 0l 1.07 (+/- I pCi!L 0.619)

k. Sulfate (as SO 4 ) El El 1,640 I mg/L (14808-79-8)

I. Sulfide (as S) El El 3.3 I mg/L

m. Sulfite (as SO3) 0l E < 10 I mg/L (14265-45-3)

n. Surfactants El El 0.47 I mg/L

o. Aluminum, Total l El < 0.5 I mg/L (7429-90-5)

p. Barium, Total El El < 0.050 I mg/L (7440-39-3)

q. Boron, Total El El 3.2 I mg/L (7440-42-8)

r. Cobalt, Total l El < 0.005 I mg/L (7440-48-4)

s. Iron, Total El El 0.475 I mg/L (7439-89-6)

t. Maagnesium, Total El El 896 I mg/L (7439-95-4) 1

u. Molybdenum, Total El El 0.0082 (I) 1 mg/L (7439-98-7)

v. Manganese, Total El El < 0.002 I mg/L (7439-96-5) sw.Tin, Total l El < 0.025 I mg/L (7440-31-5)

X.Titanium, Total El El < 0.005 I mg/L (7440-32-6) 1 1 VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-011 PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4,dinitroplhenol, or 2-methyl-4.6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outtall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS No. (if available)

MTLWY$DF,.4NDTOTALýPHENQ0S I M. Antimony, Total 0 a.

testing reqired

b. be-lieved present Tf7 E

c. be-lieved a(2)

El

a. Maximum Daily Value

< 5.0 Mass

b. Max. 30-day Value (if available)

(1)c.... 12)Mass K

c. Long Term Avg. Value (if available)

(1Cone. (2) Mass

d. No. of Analyses I

]nc..

a. Cone.

ug/L

b. Mass a. Long Term Avg. Value

() (2) Mass

b. No. of Analyses (7440-36-0) 2M. Arsenic, Total 0 E l < 5.0 I ug/L (7723-14-0) 3M. Beryllium, Total 0 E1 E < 0.50 I ug/L (7440-41-7I 4M. Cadmium, Total 0 E E < 0.50 I ug/L (7440-43-9) 5M. Chromium, Total 0 E E < 2.5 T ug/L (7440-47-3) 6M. Copper, Total 09 El El < 4.6 I ug/L (7440-50-8) 7M. Lead, Total 10 El El 0.55 (l) I ug/L (7439-92-I) 8M. Mercury, Total 0 El El 0.000809 1 ug/L (7439-97-6) 9M. Nickel, Total 0 El E < 2.5 I ug/L (7440-02-0) 10M. Selenium, Total 0 E l < 7.5 I ug/L (7782-49-2)

I IM. Silver, Total 0 El El < 0.25 I ug/L (7440-22-4) 12M. Thallium, Total 0 El < 0.50 I ug/L (7440-28-0) 13M. Zinc, Total 0 E l < 10.0 I ug/L (7440-66-6) 14M. Cyanide, Total 0 El l <5.0 I ug/L (57-12-5) 15M. Phenols, Total 0 El El < 5.0 I ug/L 2,3.7,8-Tetra- [] 0 0 chlorodibenzo-P-Dioxin

( 1764-01-6)

IV. Acrolein [] [] []

(107-02-8) 2V. Acrylonitrile [ ] [

(107-13-1)

VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-01 I

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

(.)Con.. (2)Mass (1)Cone. (2) Mass ()C .Conc (2) Mass (1) Cone... (2) Mass

!GC*/M.S.FRACTION: `'Y .T`LE°.COMPOUNDS :(co`iued,? * ****:*** i!i**..** ... :<* .*:*;;!...,A*:;. ; *,". .*,,**** .::::: .... .. ,.: *.,,'.:

3V. Benzene a1 _ _ _

(71-43-2) 4V. Bis (Chloromethyl) Ether El El 0 (542-88-I) 5V. Bromoform tn I] 0 (75-25-2) 6V. Carbon Tetrachloride 0l 1: 0 (56-23-5) 7V Chlorobenzene El Q3 0 (108-90-7) 8V. Chlorodi- 13 13 0 bromomethane (124 I) 9V. Chloroethane 11 El 0 (74-00-3) 10V. 2-Chloro-ethylvinyl El 0l 0 Ether ( 110-75-8)

It V. Chloroform 11 0l 0 (67-86-3) 12V. Dichloro- 13 El 0 bromomethane (75-24-4) 13V. Dichloro- 11 0l 0 difluomrnmethan (75-71-8) 14V. l.I-Dichloroethane 0l 11 0 (75-34-3) 15V. 1,2-Dichloroethane El El 0 (107-06-2) 16V. II-Dichloroethylene 0l 0 0 (75-35-4) 17V. 1,2,-Dichloroptopane El El 0 (78-87-5) 18V. 1,3-Dichhlomqylene 0l El 0 (542-75-6) 19V. Ethylbenzene El El 0 (100-41-4) 20V. Methyl Bromide 0l El 0 (74-83-9) 21 V. Methyl Chloride El El 0o (74-87-3) 22V. Methylene Chloride El El 0 (74-98-2) 23V. 1,1,2,2-Tetra- El El 0 chloroethane (79-34-5) 24V. Tetrachloroethylene El El 0 (127-18-4)

V11-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOO0O159 Outfall No. D-01 I

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value C.Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (Ij o nc. [2) Mass (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass

,C,*,SR'A'MON.-.YOLATILEICO.IPOUNDS (ontiudu". , , . .. . .... . " , <

25V. Toluene (108-88-3) 1 0 0 26V. 1,2-Trans- 0 0 0 Dichlouethylene (156-60-5) 27V. l,l,-Trichlomethane 0 1 0D (71-55-6) 28V. l,I,2-Trichloxetuane 01 0l 0 (79-M5) I I 29V. Trichloroethylene 0 01 0D (79-01-6) 30V. Trichloro- 01 0l 0 fluoromethane (75-69-4) 31V. Vinyl Chloride E0 0:1 0 (75-01-4)

IA. 2-Chlorophenol 01 0 0 (95-57-8) 2A. 2,4-Dichlorophenol 0l 0] 0 (120-83-2) 3A. 2,4-Dimethylphenol 0 0 0 (105-67-9) 4A. 4,6-Dinitro-O-Cresol 0 0 0 (534-53-1) 5A. 2,4-Dinitrophenol 0] 0l 0 (51-28-5) 1 6A. 2-Nitrophenol 0:1 0 0 (88-75-5) 7A. 4-Nitrophenol 0] 0 0 (100-02-7) 8A P-Chloro-M-Cresol 0 0 0 (59-50-7) 9A Pentachlorophenol 0l 01 0 (87-86-5) 10A Phenol 0 0 0 (108-95-2)

I IA 2,4,5-Trichloro- 0l 0 0 phenol (88-06-2)

I B. Acenaphthene 11 El 10 (63-32-9) 2B. Acenaphtylene 0 00 (208-96-8) _____ ____ ________________________________ ______

3B. Anthracene 0 0 0 (120-12-7) 4B. Benzidine 01 0] 0 (92-87-5)

VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-OI I

2. Mark "X 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass (I) Conc. (2) Mass 5B. Benzo (a) Anthracene El El 0 (56-55-3) 6B. Benzo (a) Pyrene C] 01 ED (50-32-8) 1 1 7B. 3,4-Benzo-fluobrande El EJ 0 (205-99-2) 8B. Benzo (ghi) Perylene 11 1 0 (191-24-2) 9B. Benzo (k) luorarnthe(207- 0 0 0 08-9) 10B. Bis (2ýCh/oroaMwy) 11 01 09 Methane (I 11 1)

I I B. Bis (2-chioroethyl) 11 0 0 Ether (111-44-4) 12B. Bis O*a1 E 0 0 Ether (102 l) 13B. Bis (2-EtltylheAyl) 13 0 0 Phthalate (117-81-7) 14B. 4-Bromophenyl El El 0 Phenyl Ether (I01-55-3) 15B Butyl Benzyl Phthalate El 0 0 (84-68-7) 116B.2-CCloromnapl-alene E E (91-58-7) 17B. 4-Chlorophenyl 11 El 0 Phenyl Ether (7005-72-3) 18B. Chrysene El 0 0 (218-01-9) 19B. Dibenzo (a.h) 0 [ 0 Anthracene (53-70-3) 20B. 1,2-Dicthloeerkene 0l 0 0 (95-50-I) 21B. 1,3-Dichlorobenzene 0 0 0 (541-73-1) 22B. 1,4-Dichlorobenzene 0 0 0 (106-46-7) 23B. 3,3-Dichlorobenzidine El 0 0 (92-94-1) 24B. Diethyl Phthalate El 0 0 (84-66-2) 25B. Dimethyl Phthalate El 0 0 (131-11-3) 26B. Di-N-Butyl Phthalate El El S (84-74-2) 27B. 2,4-Dinitrotoluene 0 0 0 (121-14-2) 1 28B. 2,6-Dinitrotoluene 01 El 0]

(606-20-2)

VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-0 11

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Cone. (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass 29B. Di-N-Octyl Phthalate 0] 0 (I 17-84-0) 30B. 1,2-Diphenylhydrazine Fl F 0 (avAz )mw")(1 7) 31 B. Fluoranthene 0l Fl 0 (206-44-0) 32B. Fluorene (86-73-7) Fl Fl 0 33B. Hexachlorobenzene Fl Fl 0 (118-74-1) 34B. Hexachlorobutadiene Fl Fl 0 (87-68-3) 35B. Hata.yimntr Fl Fl 0 (77-47-4) 36B. Hexachloroetharie El 11 0 (67-72-1) 37B. Indeno (1.2.3-cd) 03 Fl 0 Pyrene (193-39-5) 38B. Isophorone 0l 0 El (78-59-1) 39B. Naphthalene Fl Fl 0 (91-20-3) 40B. Nitrobenzene El 0l z (98-95-9) 41lN-Nh*irnine Bl Fl [

(62-75-9) 42B. N-Nitrosodi-N- Fl Fl 0 Propylamine (621-64-7) 43B. N-Nitro- El Fl 0 sodiphenylamine (86-30t6) 44B Phenanthrene Fl Fl 0 (85-01-8) 45B. Pyrene (129-00-0) Fl Fl 0 46B. 1,14-Trichlobenzene Fl Fl 0 I P. Aldrin (309-00-2) FL Fl 0 2P. -BHC (319-84-6) 13 Fl [

3P -BHC (319-85-7) El Fl 0 4P. -BHC (58-89-9) Fl Fl 0 5P. -BHC (319-86-8) Fl Fl 0 VII-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-01 I

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass 6P. Chlordane (57-74-9) EJ El ED 7P. 4,4'-DDT (50-29-3) El El 0 8P. 4,4'-DDE (72-55-9) 0l 11 0 9P. 4,4'-DDD (72-54-8) El El 0 lOP. Dieldrin (60-57-I)1) El 0 I IP. -Endosulfan El El 0 (115-29-7) 12P. -Endosulfan E- El 0 (115-29-7) 13P. Endosulfan Sulfate El l [0 (1031-07-8) 14P. Endrin (72-20-8) El El 0 15P. Endrin Aldehyde El El 0 (7421-92-4) 16P. Heptachlor El El 0 (76-44-8) 17P. Heptachlor Epoxide El El [

(1024-57-3) 18P. PCB-1242 El El 0 (53469-21-9) 19P. PCB-1254 El El 0 (11097-69-1) 20P. PCB-1221 El El 0 (I 1104-28-2) 211P.PCB-1232 El El 0D (11141-16-5) 22P. PCB-1248 E] El 0 (12672-29-6) 23P. PCB-1260 El El 0 (I 1096-B2-5)_____ __________ __________

24P. PCB-1016 El El 0R (12674-11-2) 25P. Toxaphene El El 0 (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-012 PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional)

Pollutant a. Max. Daily Value b. Max. 30-day Value c. Annual Avg. Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (I) Cone. (2) Mass (I) Cone. (2) Mass (1) Conc. (2) Mass Analyses 1) Cone. (2) Mass Analyses aflCxnelauu BuleA 2.8 I mg/L Oeg* t*dad (C'BOD)

b. Chemical Oxygen 618 I mg/L Demand (COD)

c. Total Organic 9.6 1 mg/L Carbon (TOC)

d. Total Suspended 11.5 I mg/L Solids (TSS)

e. Tal Nitrogen (as N) 0.66 1 mgg/L f Total Phosphorus las P) 0.053 (I) I mg/L

g. Ammonia (as N) < 0.020 I mg/L

h. Flow - actual or Value 472.3 Value 472.3 Value MGD Value projected

i. Flow - design Value 472.3 Value 472.3 Value MGD Value

j. Specific Condtctivity Value 36.957 Value Value umhos/cm Value

k. Temperature (winter) Value35.0 Value Value 22.4 12 1CValue I. Temoerature (summer) Value38.9 Value Value 31.7 12 °C Value M.. pH 7iN. 98~7 Min. Max. I STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, its an eftluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optionalm I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Cone. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (_)Cone... (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass

a. Bromide El 11 45.6 1 mg/L (24949-67-9)

b. Chlorine, El l < 3.5 1 mg/L Total Residual

c. Color El I] 30.0 I PCU

d. Fecal Coliform El El 2.0 I CFU/100 mL

e. Fluoride 11 0l < 1.2 1 mg/L (16984-48-8)

f. Nitrate-Nitrite El El 0.056 I mg/L (as N) I I I Vll-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B3 Contd. Facility ID. Number FLO0000159 Outfall No. D-012

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (I) Conc. (2) Mass (I) Conc. (2) Mass (I) Conc. (2) Mass (1) Conc. (2) Mass

g. Nitrogen, Total 0 0 0.60 I mg/L Organic (as N)

h. Oil and grease 5 < 1.4 I mg/L

i. Phosphorus, Total 0 01 0.053 (I) I mg/L (as P) (7723-14-0)

(I) Alpha, Total E0 [5 5.74 (+/- 1.83) 1 pCi/L (2) Beta, Total 5l 5l < 113 (+1- I pCi/L 65.8)

(3) Radium, Total 5] E5 1.57 (+/- 1.01) I pCi/L (4) Radium 226, Total 5 0.753 (+/- 1 pCi/L 0.560)

k. Sulfate (as SO4 ) 5 0 1,650 I mg/L (14808-79-8)

I. Sulfide (as S) 5 < 1.0 I mg/L

m. Sulfite (as SO3 ) 5] 5 < 10 I mg/L (14265-45-3)

n. Surfactants 0 5 0.40 I mg/L

o. Aluminum, Total 5 < 5.0 I mg/L (7429-90-5)

p. Barium, Total 51 53 < 0.050 1 mg/L (7440-39-3)

q. Boron. Total 51 5] 3.25 1 mg/L (7440-42-8)

r. Cobalt, Total 51 51 < 0.005 I mg/L (7440-48-4)

s. Iron, Total 0l 01 0.229 (I) 1 mg/L (7439-89-6)

t. Maagnesium, Total 0l 01 901 I mg/L (7439-95-4)

u. Molybdenum, Total 5 51 0.0082 (l) 1 mg/L (7439-98-7)

v. Manganese, Total 0] 01 < 0.025 I mg/L (7439-96-5)

w. Tin, Total 5] 0] < 0.025 1 mg/L (7440-31-5)

x. Titanium, Total (7440-32-6) 5 < 0.005 T 1 mg/L VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-012 PART C - If you arc a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, aerylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (l) Conc.. (2) Mass (t)Conc. Mass (1)Conc. (2) Mass

[(2) (1)Co. ]

I M. Antimony, Total 0 El < 5.0 I ug/L (7440-36-0) 2M. Arsenic, Total 10 El El <5.0 I ug/L (7723-14-0) 3M. Beryllium, Total 0 El El < 0.050 I ug/L (7440-41-7) 4M. Cadmium, Total 0 El E < 0.50 t ug/L (7440-43-9) 5M. Chromium, Total 0 El l < 2.5 1 ug/L (7440-47-3) 6M. Copper, Total 0 El El < 0.93 1 ug/L (7440-50-8) 7M. Lead. Total 0 El El < 0.50 I ug/L (7439-92-1 )

8M. Mercury, Total 0 l El 0.000873 1 ug/L (7439-97-6) 9M. Nickel, Total 0 El E] < 2.5 1 ug/L (7440-02-0) 10M. Selenium. Total 0 El El < 7.5 1 ug/L (7782-49-2) 1IM. Silver, Total 0 El < 0.050 I ug/L (7440-22-4) 12M. Thallium, Total [ 0 < 0.50 I ug/L (7440-28-0) 13M. Zinc, Total 0 El < 10.0 1 ug/L (7440-66-6) 14M. Cyanide, Total 0 El < 5.0 I ug/L (57-12-5) 15M. Phenols, Total 0 E ] < 5.0 I ug/L 2,3,7,8-Tetra- Li chlorodibenzo-P-Dioxin

( 1764-01-6 )

IV. Acrolein Li [] [

(107-02-8) 1 2V. Acrylonitrile 0 0 0 (107-13-I) 1 VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-012

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent ___F (1) Conc. (2) Mass (1) Cone. (2) Mass (1) Conc (2) Mass, _1)Conc. (2) Mass 3V. Benzene 01 0] 0 (71-43-2) 4V. Bis (Chloromethyl) Ether 0 0 0 (542-88-1) 5V. Bromoform 0 0 0 (75-25-2) 6V. Carbon Tetrachloride 0 0 0 (56-23-5) 7V Chlorobenzene 0 0 0 (108-90-7) 8V. Chlorodi- 0 0 0 bromomethane (124 I) 9V. Chloroethane i 0 0 (74-00-3)

IOV. 2-Chloro-ethylvinyl 0 0 0 Ether (110-75-8) 1IV. Chloroform 0 0 0 (67-86-3) 12V. Dichloro- 0 0 0 bromomethane (75-24-4) 13V. Dichloro- 0 0 0 difluomtxnme.u (75.71-8) 14V. I,I-Dichloroethane 0l 0:1 0 (75-34-3) 15V. 1,2-Dichloroethane 0 0 0 (107-06-2) 16V. II-Dichloroethylene 0 01 0 (75-35-4) 17V. 1,2,-Dichloropmpane 0 0 0 (78-87-5) 18V. 1,3-Dichloropropylene 0 0 S (542-75-6) 19V. Ethylbenzene 0 0 0 (100-41-4) 20V. Methyl Bromide 0 0 0 (74-83-9) 21 V. Methyl Chloride 0 0 0 (74-87-3) 22V. Methylene Chloride 0: [0 0 174-98-2) 1 1 1 1 1__11__11_

23V. 1,1,2,2-Tetra- 0 0 0 chloroethane (79-34-5) 24V. Tetrachloroethylene 0 0 0 (127-18-4)

VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-012

2. Mark "X" 3. Effient 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing jI.-d lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. [(2) Mass (1) Cone. 2 IC)o 2)Ms 1Co.[(2Mas1C... (2) Mass

£C IMSýRACTION? VOLATILECýZONIPOUNDS: (on~t. .. =_." ____ .:_ . 7 . *'__::_..........

25V.Toluene (108-88-3) ... El 0o 26V. 1,2-Trans- El El ED Dichlormethvlene 0156-60-5) 27V. I,12-Tricshlomethare 0 (71-55-6) 28V. 1,1,2-Ttichlorthane El El 0 (79-00-5) 29V. Trichloroethylene El El 0 (79-01-6) 30V. Trichloro- El El *]

fluoromethane (75-69-4) 31V. Vinyl Chloride El El 0 (75-01-4)

IA. 2-Chlorophenol El El 0 (95-57-8) 2A. 2,4-Dichlorophenol El El 0D (120-83-2) 3A. 2,4-Dimethylphenol El El ']

(105-67-9) 4A. 4,6-Dinitro-O-Cresol El El 0 (534-53-I) 5A. 2.4-Dinitrophenol El El 0 (51-28-5) 6A. 2-Nitrophenol El El 0 (88-75-5) 7A. 4-Nitrophenol El El 1 (100-02-7) 8A P-Chloro-M-Cresol El El 0 (59-50-7) 9A Pentachlorophenol El El 0 (87-86-5)

IOA Phenol El El 0 (108-95-2)

I A 2,4.5-Trichloro- El El 0 phenol (88-06-2)

I B. Acenaphthene [] 0 z (63-32-9) 2B. Acenaphtylene El El 12 (208-96-8) 3B. Anthracene El El 0 (120-12-7) 4B. Benzidine El El 0]

(92-87-5)

VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-012

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Cone. (2) Mass (1) Conc. (2) Mass (1) Cone. (2) Mass (1) Conc. (2) Mass 5B. Benzo (a) Anthracene El El 0 (56-55-3) 6B. Benzo (a) Pyrene El El 0 (50-32-8) 7B. 3,4-13enzo-fluoranthene [] El 0 (205-99-2) 8B. Benzo (ghi) Perylene r- El 0 (191-24-2) 9B. Benzo (k)Fluomrhene(207- El E] 0 08-9) 10B.Bis (2TCId/ehy,) E E Methane ( 11-91-1) 111B.Bis (2-chloroethyl) El El 0 Ether (1-44-4) 12B. Bis ý i*b*o El El 0 Ether (102-60-1) 13B. Bis (2-Ethylhcxyl) El El 0 Phthalate (117-81-7) 14B. 4-Bromophenyl El El 0 Phenyl Ether ( 101-55-3) 15B Butyl Benzyl Phthalate El El 0 (84-68-7) 16B. 2-Chldommph'ialene El El 0 (91-58-7) 17B. 4-Chlorophenyl El El 0 Phenyl Ether (7005-72-3) 18B. Chrysene El El 0 (218-01-9) 19B. Dibenzo (a.h) El El 0 Anthracene (53-70-3) 20B. 1,2-Dichlorobenzene El El 0 (95-50-1) 21 B. 1,3-Dichlorobenzene El El 0 (541-73-1) 22B. 1,4-Dichlorobenzene El El 0 (106-46-7) 231B. 3,3-Dichlorbenzidine El El ID (92-94-I) 24B. Diethyl Phthalate El El 0 (84-66-2) 25B. Dimethyl Phthalate El El 0 (131-I1-3) 26B. Di-N-Butyl Phthalate El El 10 (84-74-2) 27B. 2,4-Dinitrotoluene El El 0 (121-14-2) 28B. 2,6-Dinitrotoluene El El N (606-20-2) 1_1 VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-012

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (ifavailable) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Cone. (2) Mass (I) Conc. (2) Mass 29B. Di-N-Octyl Phthalate El r- 0 (117-84-0) 30B. 1,2-Diphenylhydrazine El El 0 (asAzobcn,)x( 122-66-7) 31B. Fluoranthene El 0l 1 (206-44-0) 32B. Fluorene (86-73-7) 11 El 0 33B. Hexachlorobenzene El 0l 0 (118-74-1) 34B. Hexachlorbutadiene El 0l 0 (87-68-3) 35B. Fbadtm)dp = El E 0 (77-47-4) 36B. Hexachloroethane El El 0 167-72-1) 37B. Indeno (1.2.3-cd) El El 0 Pyrene (193-39-5) 38B. Isophorone El El 0 (78-59-I) 39B. Naphthalene El El []

(91-20-3) 40B. Nitrobenzene El El 0 (98-95-9) 41B N-Nkusodi n El El 0 (62-75-9) 42B. N-Nitrosodi-N- El El 10 Propylamine (621-64-7) 43B. N-Nitro- El El __

sodiphenylamine (86-30.6) 44B Phenanthrene El El 0 (85-01-8) 45B. Pyrene (129-00-0) El El 0 46B. 1,2,4-Trichloruberzene El El 0 IP. Aldrin (309-00-2) El El 0 2P. -BHC (319-84-6) El El 0 3P -BHC (319-85-7) El El 0 4P. -BHC (58-89-9) E] El 0 5P. -BHC (319-86-8) El El 0 VII-7 DER Foms62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-012

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long TernmAvg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass 6P. Chlordane (57-74-9) E 0 0 7P. 4,4'-DDT (50-29-3) 0 0 0 8P. 4,4'-DDE (72-55-9) 0 0 0 9P. 4,4'-DDD (72-54-8) 0 0 0 lOP. Dieldrin (60-57-) ) 0 0 1IP. -Endosulfan 0 0 0 (115-29-7) 12P. -Endosulfan 0l 0l 0 (115-29-7) 13P. Endosulfan Sulfate E0 0:1 0 (1031-07-8) 14P. Endrin (72-20-8) 01 0 0 15P. Endrin Aldehyde 0l 0l 0 (7421-92-4) 16P. Heptachlor 0 0 0 (76-44-8) 17P. Heptachlor Epoxide 0 0 0 (1024-57-3) 18P. PCB-1242 0l E0 0 (53469-21-9) 19P. PCB-1254 0l 0l 0 (11097-69-1) 20P. PCB-1221 0l 01 0 (11104-28-2) 21P. PCB-1232 0 0 0 (11141-16-5) 22P. PCB-1248 0 0 0 (12672-29-6) 23P. PCB-1260 0l 01 0 (11096-82-51 1 1 1 24P. PCB-1016 0] 01 S (12674-11-2) 25P. Toxaphene 0 0 0 (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOH PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

ViI. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional)

Pollutant a. Max. Daily Value b. Max. 30-day Value c. Annual Avg. Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass Analyses () Cone. (2) Mass Analyses a.C wsBucit < 2.0 I mg/L

b. Chemical Oxygen 38.2 I mg/L Demand (COD)

c. Total Organic 1.2 1 mg/L Carbon (TOC)

d. Total Suspended < 5.0 I mg/L Solids (TSS)

e. Total Nitu, n (as N) 4.6 I mg/L f Total Phosphous (as P) < 0.050 1 mg/L g.Ammonia las N) 4.7 1 mg/L

h. Flow - actual or Value N/A Value Value Value projected

i. Flow - design Value N/A Value Value Value

j. Specific Conductivitry Value 5727 Value Value umhos/cm Value

k. Temperature (winter) Valuel 7.04 Value Value *C Value

1. Temperature (summer) Value Value Value °C Value m.. pH Min. 2.7 x 1Min. M ax. I I STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Cone. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Cone... (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass

a. Bromide l El < 1.0 1 mg/L (24949-67-9)

b. Chlorine, El 0 mg/L Total Residual

c. Color El El 70.0 I PCU

d. Fecal Coliform l 0 < 2.0 I CFU/IO0 mL

e. Fluoride El El 3.8 1 mg/L (16984-48-8)

f. Nitrate-Nitrite El El 0.040 (I) I mg/L (as N)

VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FLO000159 Outfall No. D-OOH

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (I) Conc. (2) Mass (I) Conc. (2) Mass (I) Conc. (2) Mass (t) Conc. (2) Mass

g. Nitrogen, Total l El < 0.25 1 mg/L Organic (as N)

h. Oil and grease El El < 1.4 I mg/L

i. Phosphorus, Total l El < 0.050 I mg/L (as P) (7123-14-0)

(I) Alpha, Total El 11 7.29 3.03) I pCi/L (2) Beta, Total E ] < 8.54 (+/- I pCi/L 5.28)

(3) Radium, Total 1 El 0.399 (+/- I pCi/L 0.660)

(4) Radium 226, Total 0 < 0.718 (+/- I pCi/L 0.348)

k. Sulfate (as SO 4 ) El El 4,900 I mg/L (14808-79-8)

I. Sulfide (as S) l El < 1.0 1 mg/L

m. Sulfite (as SOA) El El not analyzed (14265-45-3)

n. Surfactants El [1 < 0.059 I mg/L

o. Aluminum, Total El El 184 I mg/L (7429-90-5)

p. Barium, Total l 0 < 0.050 I mg/L (7440-39-3)

q. Boron, Total 0l El 0.455 I mg/L (7440-42-8)

r. Cobalt, Total El El 0.916 I mg/L (7440-48-4)

s. Iron, Total El El 305 I mg/L (7439-89-6) 1

t. Maagnesium, Total El 0 198 I mg/L (7439-95-4)

u. Molybdenum, Total l El < 0.005 I mg/L (7439-98-7)

v. Manganese, Total El El 21.7 1 mg/L (7439-96-5)

w. Tin, Total l 0 < 0.025 1 mg/L (7440-31-5)

x. Titanium, Total l El < 0.005 I mg/L (7440-32-6)

VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOH PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (l)Conc. [ (2) Mass (l)Cone [ (2)Mass (I)Conc.[, (2) Mass[ (1)Conc. (2) Mass MT 1SCY.AN1D&l,"ANDd)T,0 A ENH.0?~S. ___ _______ ________ ___

I M. Antimony, Total l El EJ < 5.0 ug/L (7440-36-0) 2M. Arsenic, Total 0l E l < 50.0 1 ug/L (7723-14-0) 3M. Beryllium. Total El 0l El 73.6 1 ug/L (7440-41-7) 4M. Cadmium, Total El El El 22.1 1 ug/L (7440-43-9) 5M. Chromium, Total El El 0l 81.2 I ug/L (7440-47-3) 6M. Copper, Total El El El 361 I ug/L (7440-50-8) 7M. Lead, Total El El El 1.4 I ug/L (7439-92-I) 8M. Mercury. Total El El El 0.0309 I ug/L (7439-97-6) 9M. Nickel, Total El El 0 1850 I ug/L (7440-02-0) 10M. Selenium, Total El El El 13.8 (I) I ug/L (7782-49-2) tI M. Silver, Total El El El <0.25 I ug/L (7440-22-4) 12M. Thallium, Total El 0 El 3.8 1 ug/L (7440-28-0) 13M. Zinc, Total El El El 6720 I ug/L (7440-66-6) 14M. Cyanide, Total El El ] < 5.0 I ug/L (57-12-5) 15M. Phenols, Total 0 El El < 5.0 I ug/L 2,3,7,8-Tetra-7* r [ ] [ .............

chlorodibenzo- P-Dioxin (1764-01-6)

IV. Acrolein E] L] L] < 10.0 1 ug/L (107-02-8) 2V. Acrylonitrile [] 1:1 D < 5.0 1 ug/L (107-13-1)

VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-00H

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- e. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (r)Cu....tbet2) Mass (1)Cone. [ (2) Mass (1) Cone. (2) Mass (1)Cone.... (2) Mass 3V. Benzene El El EL < 0.50 I ug/L (71-43-2) 4V. Bis (Chloromethyl) Ether El 0 10 (542-88-1) 5V. Bromoform 0l 0 0 < 0.50 I ug/L (75-25-2) 6V. Carbon Tetrachloride 0l 0l 0l < 0.50 I ug/L (56-23-5) 1 1 1 1 7V Chlorobenzene El 1 0l l < 0.40 I ug/L (108-90-7) 8V. Chlorodi- 0l 0l 0 < 0.25 I ug/L bromomethane (124 I) 9V. Chloroethane 0 0 El < 0.61 1 ug/L (74-00-3) 10V. 2-Chloro-ethylvinyl El El E < 5.0 1 ug/L Ether 110-75-8) 1IV. Chloroform El El El < 0.50 1 ug/L (67-86-3) 12V. Dichloro- El El El <0.30 I ug/L bromomethane (75-24-4) 13V. Dichloro- l El E < 0.50 1 ug/L difluorommeth (75-71-8) 14V. I,I--Dichloroethane El El El <0.50 1 ug/L (75-34-3) 15V. 1,2-Dichloroethane El El 0l < 0.50 1 ug/L (107-06-2) 16V. I,-Dichlomethylene El El El <0.71 I ug/L (75-35-4) 17V. 1,2,-Dichloruprupane El E E < 0.50 I ug/L (78-87-5) 18V. 1,3-DicNh*opmopylene El El El < 0.50 1 ug/L (542-75-6) 19V. Ethylbenzene l El E < 0.50 I ug/L (100-41-4) 20V. Methyl Bromide l El E < 0.50 1 ug/L (74-83-9) 21 V. Methyl Chloride El El El < 0.50 1 ug/L (74-87-3) 22V. Methylene Chloride l El E < 2.5 1 ug/L (74-98-2) 1 1 1 23V. Il.,2,2-Tetra- El El El <0.17 1 ug/L chloroethane (79-34-5) 1 1 24V. Tetrachloroethylene El El El < 0.50 1 ug/L (127-18-4)

VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-OOH

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I)Conc 1 (2) Mass (I) Conc. ] (2) Mass (1)ss C (I) Cone. (2) Mass

ý.GAISFRACT.IONC-WgOL'AULE:COMPOUNDSY(*onoiiiid). ______ '_ .. ,..

25V. Toluene (108-88-3) 0l 0l El < 0.50 I ug/L 26V. 1,2-Trans- 11 El El < 0.50 1 ug/L DichloToethylene (156-60-5) 27V. 1,12-Trichlotuethane 0l l [] < 0.50 I ug/L (71-55-6) 28V. I,I,2-Trichlonethdne l El El < 0.50 I ug/L (79-&5) 29V. Trichloroethylene l El El < 0.50 I ug/L (79-01-6) 30V. Trichloro- Ul E E] < 0.66 I ug/L fluoromethane (75-69-4) 31 V. Vinyl Chloride El El ED <0.53 1 ug/L (75-01-4)

IA. 2-Chlorophenol < 0.65 ug/L (95-57-8) 2A. 2,4-Dichlorophenol l El El < 0.53 I ug/L (120-83-2) 3A. 2,4-Dimethylphenol El El El < 1.5 I ug/L (105-67-9) 4A. 4,6-Dinitro-O-Cresol l El El < 1.3 I ug/L (534-53-1) 5A. 2,4-Dinitrophenol El El El < 1.5 1 ug/L (51-28-5) 6A. 2-Nitrophenol [E El < 0.77 I ug/L (88-75-5) 7A. 4-Nitrophenol El El El < 1.0 1 ug/L (100-02-7) 8A P-Chloro-M-Cresol El El < 0.59 I ug/L (59-50-7) 9A Pentachlorophenol l El El < 0.63 I ug/L (87-86-5) 1OAPhenol El El El < 0.51 I ug/L (108-95-2) 1 A 2.4,5-Trichloro- El El El < 0.66 1 ug/L phenol (88-06-2) lB. Acenaphthene [] < 0.037 1 ug/L (63-32-9) 2B. Acenaphtylene El El El < 0.035 1 ug/L (208-96-8) 3B. Anthracene [E [l El < 0.037 I ug/L (120-12-7) -C:] C3 [I < 0.73 1 g/L 4B. Benzidine El - E E <073 I ug/L (92-87-5) 1 VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-001-1

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

_______________ (I) Cone. (2) Mass (I) Conc. (2) Mass (1) Cone. (2) Mass (I) Conc. (2) Mass 5B. Benzo (a) Anthracene El 11 El < 0.026 I ug/L (56-55-3) 6B. Benzo (a) Pyrene l El [] < 0.043 1 ug/L (50-32-8) 7B. 3,4-Beno-fluoranthetn El El E < 0.031 I ug/L (205-99-2) 8B. Benzo (ghi)Perylene El1 l < 0.033 1 ug/L (191-24-2) 9B. Benzo (k) Fluoh rar(207- ] El l < 0.045 I ug/L 08-9) 10B. Bis -2Chtaahh/a' .) 11 El El < 2.8 I ug/L Methane (111 1)

I I B. Bis (2-chloroethyl) El El C] < 0.71 I ug/L Ether(l 11-44-4) 1 1 12B. Bis *"Oibv&W O El El El <0.69 1 ug/L Ether (102-60-1) 13B. Bis (2-Ethylhexyl) El El El < 0.76 I ug/L Phthalate (117-81-7) 14B. 4-Bromophenyl El El El < 0.64 1 ug/L Phenyl Ether (101-55-3) 15B Butyl Benzyl Phthalate El El El < 0.68 I ug/L (84-68-7) 16B. 2-Chlronaplthalee El El l < 0.76 I ug/L (91-58-7) 17B. 4-Chlorophenyl El El < 0.59 I ug/L Phenyl Ether (7005-72-3) 18B. Chrysene El El < 0.029 1 ug/L (218-01-9) 19B. Dibenzo (a,h) El El El < 0.037 1 ug/L Anthracene (53-70-3) 20B. 1,2-Dichlorobenzene l l El < 0.65 1 ug/L (95-50-1) 21B. 1,3-Dichlombenzene El El El < 0.72 1 ug/L (541-73-1) 22B. 1,4-Dichlorobenzene El El l < 0.73 I ug/L (106A46-7) 23B. 3,3-Dichlorobenzidine l El El < 0.66 I ug/L (92-94-1)__ _ _ __ _ __ _ _

24B. Diethyl Phthalate l El El < 0.48 1 ug/L (84-66-2) 25B. Dimethyl Phthalate l El El < 0.61 I ug/L (131-11-3) 26B. Di-N-Butyl Phthalate El El El < 0.39 I ug/L (84-74-2) 27B. 2,4-Dinitrotoluene l El El < 0.50 I ug/L (121-14-2) 28B. 2,6-Dinitrotoluene l El El < 0.61 I ug/L (606-20-2)

VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOH

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass 29B. Di-N-Octyl Phthalate 0l 0 El < 0.85 1 ug/L (117-84-0) 30B. 1,2-Diphenylhydrazire 0 0l 0l < 0.63 1 ug/L (asAs2Lcettt(l22-66-7) __ ______ ___ __ ____

31B. Fluoranthene 0 0l 0 < 0.024 1 ug/L (206-44-0) 32B. Fluorene (86-73-7) 0 0 0 < 0.022 1 ug/L 33B. Hexachlorobenzene 0 0 0 < 0.76 I ug/L (118-74-1) 34B. Hexachlorobutadiene 0 0 [l < 1.0 I ug/L (87-68-3) 35B.FHedixeyiid 0l El 0 < 1.2 I ug/L (77-47-4) 36B. Hexachloroethane 0 0 0 < 0.67 1 ug/L (67-72-1) 37B. Indeno (1.2.3-cd) 0l 0l 0l < 0.037 I ug/L Pyrene (193-39-5) 38B. Isophorone 0l 0l 0 < 0.69 1 ug/L (78-59-1) 39B. Naphthalene 0 0 0 < 0.029 I ug/L (91-20-3) 40B. Nitrobenzene [] [] 0l < 1.0 1 ug/L (98-95-9) 1 41B N-Nain ,tar'ne 0l [] 0 < 0.92 I ug/L (62-75-9) 42B. N-Nitrosodi-N- 0l 0 0 < 0.89 I ug/L Propylamine (621-64-7) 43B. N-Nitro- 0l 0 0 < 0.47 I ug/L sodiphenylamine (86-30-6) 44B Phenanthrene 0l 0l 0 < 0.031 1 ug/L (85-01-8) 45B. Pyrene (129-00-0) 0l 0 0l < 0.020 I ug/L 46B. 1Z4-Tichlombeaene 0l 0l 0 < 0.79 I ug/L (120-82-1)

IP. Aldrin (309-00-2) [] 0l 0 2P. -BHC (319-84-6) 0l 0 1 3P -BHC (319-85-7) 0l 0 ED 4P. -BHC (58-89-9) 0 0l 0 5P. -BHC (319-86-8) 0 0l 0 VII-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOH

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (ifavailable) Analyses Analyses required present absent (I) Conc. (2) Mass (l) Conc. (2) Mass (I) Conc. (21 Mass (l) Conc. (2) Mass 6P. Chlordane (57-74-9) 13 0l 0 7P. 4,4'-DDT (50-29-3) 0l 0l 0 8P. 4,4'-DDE (72-55-9) 0l 0l 0 9P. 4,4'-DDD (72-54-8) 0l 0l 0 lOP. Dieldrin (60-57-1) 0l 0l 0 I 1P. -Endosulfan 0l 0l 0 (115-29-7) 12P. -Endosulfan 0l [] 0 (115-29-7) 13P. Endosulfan Sulfate 0l -l 0 (1031-07-8) 14P. Endrin (72-20-8) El 0l 0 15P. Endrin Aldehyde 0l 0l 0 (7421-92-4) 16P. Heptachlor 0 0 10 (76-44-8) 17P. Heptachlor Epoxide 0l 0 10 (1024-57-3) 18P. PCB-1242 0l 0l 0 (53469-21-9) 19P. PCB-1254 0l 0l 0 (11097-69-1) 20P. PCB-1221 0l 0l 0 (11104-28-2) f 21P. PCB-1232 0l 0l z*

(11141-16-5) 22P. PCB-1248 0l El z (12672-29-6) 23P. PCB-1260 0l El 0 (11096-82-5) 24P. PCB-1016 El El 0 (12674-11-21 25P. Toxaphene 0l El S (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-OOF PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. ComDlete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional_

Pollutant a. Max. Dail Value b. Max. 30-day Value c. Annual A" g. Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of

()Conc.

A (2) Mass (1) Conc. (2) Mass (1) Cone. (2) Mass Analyses (1) Conc. (2) Mass Anal'ses aC.tbm*x. Bi < 3.0 1 mg/L

b. Chemical Oxygen 1440 1 mg/L Demand (COD)

c. Total Organic 8.1 I mg/L Carbon (TOC)

d. Total Suspended 13.5 I mg/L Solids (TSS)

e. Total Nitnmn(as N) 1.0 I mg/L f Total Pho'phruxs (as P) < 0.050 I mg/L

g. Ammonia (as N) 0.35 I mg/L

h. Flow - actual or Value 43.5 Value 43.5 Value MGD Value projected

i. Flow - design Value 43.5 Value 43.5 Value MOD Value

j. Specific Conductivity Value 34,565 Value Value I umhos/cm Value

k. Temperature (winter) Valuel9.8 Value Value I ICValue I. Temperature (summer) I Value38.5 Value Value °C Value mi.. pH Min. 7.7 5 Min. Max. 27 STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Cone. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent 1ll Cone... (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass (1) Conc. (2) Mass

a. Bromide 11 El 38.8 I mg/L (24949-67-9)

b. Chlorine, 11 C] < 3.5 I mg/L Total Residual

c. Color 11 11 20.0 1 PCU

d. Fecal Coliform 11 [] 6.0 I CFU/100 mL

e. Fluoride C3 C 5.6 (1) I mg/L (16984-48-8)

f. Nitrate-Nitrite C 0 0.031 (I) I mg/L (as N)

VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. D-OOF

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (1) Conc. (2) Mass (I) Conc. (2) Mass (I) Conc. (2) Mass (I) Conc. (2) Mass

g. Nitrogen. Total El El 0.63 I mg/L Organic (as N)

h. Oil and grease l El < 1.4 I mg/L

i. Phosphorus, Total El El < 0.050 I mg/L (as P) (7723-14-0)

J~i Radi~actii*t,) * ....

-* ::* :=*'?*'"% ... :' .... *.... "*

(1) Alpha, Total l El 4.39(+/- 1.55) 1 pCi/L (2) Beta, Total El El 346 (+/- 108) I pCi/L (3) Radium, Total El El 1.36(+/- I pCi!L 0.967)

(4) Radium 226, Total El l < 0.0867 (+/- I pCi/L 0.550)

k. Sulfate (as S04 )l El 1,780 I mg/L (14808-79-8)

1. Sulfide (as S) l El < 1.0 I mg/L

m. Sulfite (as S03 El l < 10 I mg/L (14265-45-3)

n. Surfactants El El 0.48 I mg/L

o. Aluminum, Total El [E 0.0957 (l) I mg/L (7429-90-5)

p. Barium, Total El [E 0.0127 I mg/L (7440-39-3)

q. Boron, Total El El 3.39 I mg/L (7440-42-8)

r. Cobalt, Total l El < 0.005 I mg/L (7440-48-4)

s. Iron, Total El El 0.134 I mg/L (7439-89-6)

I. Maagnesium, Total El 0l 890 I mg/L (7439-95-4)

u. Molybdenum, Total El El 0.0079 (l) 1 mg/L (7439-98-7)

v. Manganese. Total El l < 0.012 1 mg/L (7439-96-5)

w. Tin, Total El 11 < 0.025 1 mg/L (7440-31-5)

x. Titanium, Total El El <0.050 1 mg/L (7440-32-6) 1___ I VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO00O159 Outfall No. D-OOF PART C - If you arc a primary industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acroleit, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (t)Cone. ] (2) Mass (l)Co... [(2) Mass (I)Conc. (2)_Mass (I)Conc. ((2) Mass I M. Antimony, Total 0 E El < 5.0 I ug/L (7440-36-0) 2M. Arsenic. Total 0 E l < 5.0 I ug/L (7723-14-0) 3M. Beryllium, Total 0 El l < 0.25 1 ug/L (7440-41-7) 4M. Cadmium, Total 0 El l < 0.50 I ug/L (7440-43-9) 5M. Chromium, Total 0 0l El < 12.5 I ug/L (7440-47-3) 6M. Copper, Total 09 El El 1.8 I ug/L (7440-50-8) 7M. Lead, Total 0 El El < 0.50 1 ug/L (7439-92-I) 8M. Mercury, Total 0 El El 0.000899 1 ug/L (7439-97-6) 1 9M. Nickel, Total 10 El El < 2.5 I ug/L (7440-02-0)

IOM. Selenium, Total El E] < 7.5 I ug/L (7782-49-2)

I IM. Silver, Total 0 El 11 < 2.5 I ug/L (7440-22-4) 12M. Thallium, Total 0 E < 0.50 I ug/L (7440-28-0) 13M. Zinc. Total 0 E E < 10.0 I ug/L (7440-66-6) 14M. Cyanide, Total 0 E l < 5.0 I ug/L (57-12-5) 15M. Phenols, Total < 5.0 1 ug/L 2,3,7,8-Tetra- El El 0 chlorodibenzo-P-Diosin

( 1764-01-6)

IV. Acrolein [] [ ] < I0.0 ... . . .I 1- "ug/L (107-02-8) 2V. Acrylonitrile 0] [] [] < 5.0 1 ugL (107-13-1)

VII-3 DER Form 62-620,910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-OOF

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1)Cone. (2)Mass (l)Cone. I')as ()o*

(2)Mass (,)Con. IMs

'GOfMSFRAMON- O1[ýtECOMPOIJN ( U ý&ti))

3V. Benzene l l El < 0.50 I ugiL (71-43-2) 4V. Bis (Chloromethyl) Ether 1 0l S (542-88-1) 5V. Bromoform El E E < 0.50 I ug/L (75-25-2) 6V. Carbon Tetrachloride 13 0l 11 < 0.50 I ug/L (56-23-5) 7V Chlorobenzene 11 El El < 0.40 I ug/L (108-90-7) 8V. Chlorodi- El 0l 11 < 0.25 1 ug/L bromomethane (124 I) 9V. Chloroethane El El El < 0.61 I ug/L (74-00-3)

IOV. 2-Chloro-ethylvinyl l El El < 5.0 1 ug/L Ether (110-75-8) 11V. Chloroform El El 0J < 0.50 I ug/L (67-86-3) 12V. Dichloro- 11 El 0l < 0.30 1 ug/L bromomethane (75-24-4) 13V. Dichloro- El El El < 0.50 I ug/L difluosnme-ane (75-71-8) 14V. 1.1-Dichloroethane El El Fi < 0.50 I ug/L (75-34-3) 15V. 1,2-Dichloroethane 11 El 11 < 0.50 I ug/L (107-06-2) 16V. I,-Dichloroethylene El El [] <0.71 I ug/L (75-35-4) 17V. 1,2,-Dichlompmpane El El El < 0.50 I ug/L (78-87-5) 18V. 1,3-Dichloropmpylene El El El < 0.50 I ug/L (542-75-6) 1 1 19V. Ethylbenzene 0l El El < 0.50 1 ug/L (100-41-4) 20V. Methyl Bromide 11 El 0l < 0.50 1 ug/L (74-83-9) 2IV. Methyl Chloride El El El < 0.50 I ug/L (74-87-3) 22V. Methylene Chloride 13 El El < 2.5 I ug/L (74-98-2) 23V. 1,1,2,2-Tetra- El El El <0.17 1 ug/L chloroethane (79-34-5) 24V. Tetrachloroethylene El E E] < 0.50 I ug/L (127-18-4)

VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOF

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent 1 (1) Conc. (2) Mass (I) Conc. 1(2) Mass (1) Cone. I (2) Mass (l)Conc. (2) Mass kGN-1MSVRXGT9ON~O - IEC ]UNDSI cttii"~I ~ U I ~ I~

25V. Toluene (108-88-3) El 0- El < 0.50 I ug/L 26V. 1.2-Trans- El El 13 < 0.50 I ug/L Dichlomethylene (156-60-5) 27V. I,I,2-Trichloroethanre El 11 11 < 0.50 I ug/L (71-55-6) t3 28V. I,1,2-Trichloodhane 0l El < 0.50 I ug/L (79-00-5) 29V. Trichloroethylene El 0l El < 0.50 I ug/L (79-01-6) 1 1 1 1 30V. Trichloro- l El El < 0.66 I ug/L fluoromethane (75-69-4) 31V. Vinyl Chloride El El El < 0.53 I ug/L (75-01-4)

IA. 2-Chlorophenol El El El < 0.63 1 ug/L (95-57-8) 2A. 2,4-Dichlorophenol El El El < 0.52 I ug/L (120-83-2) 3A. 2,4-Dimethylphenol El El El < 1.5 1 ug/L (105-67-9) 4A. 4,6-Dinitro-O-Cresol El El El < 1.2 1 ug/L (534-53-I) 5A. 2,4-Dinitrophenol El El El < 1.5 I ug/L (51-28-5) 6A. 2-Nitrophenol El El El < 0.75 I ug/L (88-75-5) 7A. 4-Nitrophenol El El El < 1.0 1 ug/L (100-02-7) 8A P-Chloro-M-Cresol El El El < 0.58 I ug/L (59-50-7) 9A Pentachlorophenol El El El < 0.61 1 ug/L (87-86-5) 1OA Phenol El El El < 0.50 1 ug/L (108-95-2)

II A 2,4,5-Trichloro- El El El < 0.64 I ugfL phenol (88-06-2)

I B. Acenaphthene [:1 < 0.018 1 ug/L (63-32-9) 2B. Acenaphtylene El El El < 0.017 I ug/L (208-96-8) 3B. Anthracene El El El < 0.018 I ug/L (120-12-7) 4B. Benzidine El El E0 < 0.72 I ug/L (92-87-5) 1 1 1 VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-OOF

2. Mark "X" 3. Efluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

________________ (I) Conc. (2) Mass (1) Cone. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass 5B. Benzo (a) Anthracene 11 El El < 0.012 I ug/L (56-55-3) 6B. Benzo (a) Pyrene El 11 El < 0.021 1 ug/L (50-32-8) 7B. 3,4-Benzo-fluoranthene E E]

El < 0.015 I ug/L (205-99-2) 8B. Benzo (ghi} Perylene El E l < 0.016 1 ug/L (191-24-2) 9B. Benzo (k) Fluotunthene (207- l El l < 0.022 1 ug/L 08-9)

I0B. Bis (2-Ch/oroa/W) E E El < 2.7 I ug/L Methane (111 1)

I I B. Bis (2-chloroethyl) El l El < 0.70 1 ug/L Ether ( 111-44-4) 1 12B. Bis j Vpq4 El El El <0.68 I ug/L Ether (102-60-1) 13B. Bis (2-Elhylhexyl) El El El < 0.74 I ug/L Phthalate (117-81-7) 14B. 4-Bromophenyl l El l < 0.62 1 ug/L Phenyl Ether (101-55-3) 15B Butyl Benzyl Phthalate l El El <0.67 I ug/L (84-68-7) 1 1 16B. 2-Chlotonaphthalene El El l < 0.74 I ug/L (91-58-7) 17B. 4-Chlorophenyl l El E < 0.58 I ug/L Phenyl Ether (7005-72-3) 18B. Chrysene El El < 0.014 1 ug/L (218-01-9) 19B. Dibenzo (a,h) l El l < 0.018 I ug/L Anthracene (53-70-3) 20B. 1,2-Dichlorobenzee El El El < 0.63 I ug/L (95-50-1) 21B. 1,3-Dichlorobenzene El El < 0.71 I ug/L (541-73-I) 22B. 1,4-Dichlombenzene l El l < 0.72 I ug/L (106-46-7) 23B. 3,3-Dichlerbenzidine l El El < 0.64 I ug/L 192-94-I) 1 24B. Diethyl Phthalate l El El < 0.47 I ug/L (84-66-2) 25B. Dimethyl Phthalate El El El < 0.60 I ug/L (131-I 1-3) 26B. Di-N-Butyl Phthalate El El El < 0.38 I ug/L (84-74-2) 1 27B. 2,4-Dinitrotoluene El [E El < 0.49 I ug/L (121-14-2) 28B. 2,6-Dinitrotoluene El El El < 0.60 1 ug/L (606-20-2)

VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOF

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b, Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass (1) Cone. (2) Mass 29B. Di-N-Octyl Phthalate "1 0l 0 < 0.84 I ug/L (117-84-0) 30B. 1.2-Diphenylhydtazine 01 0l 0 < 0.61 I ug/L (aszobeuizzte)(I22-66-7) 311. Fluoranthene El 0l 0l < 0.011 I ug/L (206-44-0) 32B. Fluorene (86-73-7) El 0l 0l < 0.010 1 ug/L 33B. Hexachlorobenzene 0l 0l 0l < 0.74 I ug/L (118-74-1) _ _ _ _I 34B. Hexachlorobutadiene l 0l 0l < 1.0 I ug/L (87-68-3) 35B. H=ediadoin El 0l E0 < 1.2 I ug/L (77-47-4) 36B. Hexachloroethane E0 El 0 < 0.66 I ug/L (67-72-1) 37B. Indeno (1.2.3-cd.) El El E <0.018 I ug/L Pyrene (193-39-5) 1 38B. Isophorone 0l 0l 0l < 0.68 I ug/L (78-59-1) 39B. Naphthalene 0l 0l 0l < 0.014 I ug/L (91-20-3) 40B. Nitrobenzene El El El < 1.0 I ug/L (98-95-9) 41B N-Nk* din[]irr E E El < 0.90 I ug/L (62-75-9) 1 42B. N-Nitrosodi-N- El El 0l < 0.87 I ug/L Propylamine (621-64-7) 43B. N-Nitro- EL El El < 0.46 I ug/L sodiphenylamine (86-30-6) 44B Phenanthrene El El 0l < 0.015 I ug/L (85-01-8) 45B. Pyrene (129-00-0) 0 El El < 0.0094 I ug/L 46B. 12,4-Trichlorobenzene El El El < 0.77 I ug/L (120-82-1)

I P. Aldrin (309-00-2) El El 0 2P. -BHC (319-84-6) 0l El 0 3P -BHC (319-85-7) El El 0 4P. -BHC (58-89-9) El El 0 5P. -BHC (319-86-8) El El 0 VII-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-OOF

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (1) Conc. (2) Mass (I) Cone. (2) Mass (I) Corc. (2) Mass 6P. Chlordane (57-74-9) 0 01 ED 7P. 4,4'-DDT (50-29-3) 0 0 10 8P. 4,4'-DDE (72-55-9) 01 0] 0 9P. 4,4'-DDD (72-54-8) 0 0 [

lOP. Dieldrin (60-57-1) 0i 0 I I P. -Endosulfan 01 0] 0 (115-29-71 12P. -Endosulfan 0 0 0o (115-29-7) 13P. Endosulfan Sulfate 0 0 0 (1031-07-8) 14P. Endrin (72-20-8) E0 0 0 15P. Endrin Aldehyde 0 0 0 (7421-92-4) 16P. Heptachlor 0 0 0 (76-44-8) 17P. Heptachlor Epoxide 0 0 0 (1024-57-3) 18P. PCB-1242 0 0 0 (53469-21-9) 19P. PCB-1254 0 0 0 (11097-69-1) 20P. PCB-1221 0 0 [

(11104-28-2) 21P. PCB-1232 0:1 0 0 (11141-16-5) 22P. PCB-1248 i 0 0 (12672-29-6) 23P. PCB-1260 0 0 0 (11096-82-5) 24P. PCB-1016 0l 0 N (12674-11-2) 25P. Toxaphene 0 0 0 (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-FG (SDT-1)

PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same fonnat.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optionalS Pollutant a. Max. Daily Value b. Max. 30-day Value c. Annual Av%.Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (I) Conc. (2) Mass (I) Conc. (2) Mass (I) Cone. (2) Mass Analyses (I) Conc. (2) Mass Analyses aCab~urmab Rxs 3.79 I mg/L Ox* n tDmQrd(C__0_

b. Chemical Oxygen 65.2 I mg/L Demand (COD)

c. Total Organic 16.2 I mg/L Carbon (TOC)

d. Total Suspended 47.0 25.07 12.75 26 mg/L Solids (TSS)

e. Total Nitrogen (as N) 6.35 I m_/L ETotal Phosphous as P) 0.334 1 mg/L g.Ammonia (as N) 1.45 1 mg[/L

h. Flow - actual or Value 0.0852 Value 0.0811 Value 0.0167 26 mgd Value projected

i. Flow - design Value Value Value Value

,.Specific Conductivity Value 424 Value Value I umhos/cm Value

k. Temperature (winter) Value19.0 Value Value I C Value 1.Temperature (summer) Value Value Value °C Value m.. pH Min. 7.4 Mi 8.7 Mi.. . "Max 26 STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark columt 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optionall

1. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Cone. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Cone... (2) Mass (I) Cone. (2) Mass (1) Cone. (2) Mass (1) Conc. (2) Mass

a. Bromide El El 1.85 I mg/L (24949-67-9)

b. Chlorine, 0 0 Total Residual

c. Color 0 0 40 1 PCU

d. Fecal Coliform 0 z

e. Fluoride E0 0l 0.140 I mg/L (16984-48-8)

f. Nitrate-Nitrite 0l 01 0.0482 I mg/L (as N) I VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FLOOOO 159 Outfall No. I-FG (SDT-l)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (l) Conc. (2) Mass (1) Conc. (2) Mass (t) Conc. (2) Mass (1) Conc. (2) Mass

g. Nitrogen, Total El El 4.85 1 mg/L Organic (as N)

h. Oil and grease 0l El 12.5 8.29 2.63 26 mg/L

i. Phosphorus, Total El El 0.334 I mg/L (as P) (7723-14-0)

(1) Alpha, Total 0l [1 < 2.75 (+- pCiL 2.40)

(2) Beta, Total El El 20.6 (+/- 4.22) 1 pCifL (3) Radium, Total El El 0.728 (+/- 1 pCi/L 0.499)

(4) Radium 226, Total El El 1.19 (+/- I pCi/L 0.398)

k. Sulfate (as SO 4 ) El El 15.2 I mg/L (14808-79-8)

I. Sulfide (as S) l El < 0.033 I mg/L

m. Sulfite (as SO3) El El N/A (14265-45-3)

n. Surfactants El El 0.0184 (I) mg/L

o. Aluminum, Total El El 0.117 I mg/L (7429-90-5)

p. Barium, Total El El 0.00827 I mg/L (7440-39-3)

q. Boron, Total El El 0.0525 I mg/L (7440-42-8)

r. Cobalt, Total El El 0.00042 (I) 1 mg/L (7440-48-4)

s. Iron, Total El El 1.21 1 mg/L (7439-89-6)

t. Maagnesium, Total El El 12.0 I mg/L (7439-95-4)

u. Molybdenum, Total El El 0.512 I mg/L (7439-98-7)

v. Manganese, Total El El 0.0278 1 mg/L (7439-96-5)

w. Tin, Total El l < 0.001 1 mg/L (7440-3 1-5)

x. Titanium, Total El El 0.00273 I mg/L (7440-32-6)

DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-FG (SDT-l)

PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

t. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses reurd presn asn (I) Conc. (2) Mass (l)Coac. 2.)Mass (I) Conc. (2) Mass (,)Conc. (2) Mass

'METALS, CYANIt)ErANVtTOTAL PHEN9QjLS§'

I M. Antimony, Total 11 E5 11 < 0.600 I ug/L (7440-36-0) 2M. Arsenic, Total El El El 3.49 (I) 1 ug/L (7723-14-0) 3M. Beryllium. Total 1 El l < 0.200 I ug/L (7440-41-7) 4M. Cadmium, Total El El El 0.128 1 ug/L (744043-91 1 1 1 1 1 1 5M. Chromium, Total 11 1.25(1) 1 ug/L (7440-47-3) 6M. Copper. Total El El El Pending (7440-50-8) 7M. Lead, Total El El El 3.38 1 ug/L (7439-92-1) 8M. Mercury. Total El El El 0.0173 t ug/L (7439-97-6) 1 1 1 1 1 9M. Nickel, Total El El E] 162 I ug/L (7440-02-0) 10M. Selenium, Total El El El 8.59 I ug/L (778249-2) 1IM. Silver, Total l El El < 0.200 1 ug/L (7440-22-4) 12M. Thallium, Total l El] E] 0.160(l) I ugfL (7440-28-0) 1 1 1 1 1 13M. Zinc, Total El El El 0.0945 1 mg/L (7440-66-6) 14M. Cyanide, Total El El El < 1.67 1 ug/L (57-12-5) 15M. Phenols, Total El El El pending I ug/L 2,3.7,8-Tetra- L1 1 11 chlorodibenzo-P-Dioxin (1764-01-6)

IV. Acrolein 0] 1:1 [ < 1.50 1 ug/L (107-02-8) 2V. Acrylonitrile El El E < 1.50 I ug/L (107-13-1)

VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOOOO 159 Outfall No. I-FG (SDT-1)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. T(2) Mas (1)Conc. (2) Mass f0/,S*FACTJON.-VOATI .. WCOMPOUN Ws* -.* ,;..*,t,%.*-* :i.*=.4, * **7. *. : '* *?!.u..o.,. .....

3V. Benzene 0l El Ul < 0.300 1 ug/L (71-43-2) 4V. Bis (Chloromethyl) Ether [] El 0 (542-88-I) 5V. Bromoform El El 0l < 0.300 I ug/L (75-25-2) 6V. Carbon Tetrachloride El 11 < 0.300 I ug/L (56-23-5) 7V Chlorobenzene El El El < 0.300 t ug/L (108-90-7) 8V. Chlorodi- l El El 0.880(l) I ug/L bromomethane ( 124 I) 9V. Chloroethane l El El < 0.300 I ug/L (74-00-3)

IOV. 2-Chloro-ethylvinyl [] El El Pending Ether (I 10-75-8)

I IV. Chloroform El El Dl < 0.300 1 ug/L (67-86-3) 12V. Dichloro- El El El < 0.300 I ug/L bromomethane (75-24-4) 13V. Dichloro- El El l < 0.300 1 ug/L difluoromethane (75-71-8) 14V. tI-Dichloroethane El El El <0.300 I ug/L (75-34-3) 15V. 1,2-Dichloroethane [El El El < 0.300 1 ug/L (107-06-2) 16V. I, I-Dicloroethylene El El El < 0.300 I ug/L (75-35-4) 17V. 1,2,-Dichlompmprpne El El El < 0.300 1 ug/L (78-87-5) 18V. 1,3-Dicomprnqyere El El El < 0.300 I ug/L (542-75-6) 19V. Ethylbenzene l El El < 0.300 I ug/L (100-41-4) 20V. Methyl Bromide El El El < 0.300 I ug/L (74-83-9) 21 V. Methyl Chloride El El El < 0.300 I ug/L (74-87-3) 22V. Methylene Chloride El El El < 1.00 I ug/L (74-98-2) 1 23V. 1,1,2,2-Tetra- El El El <0.300 1 ug/L chloroethane (79-34-5) 1 1 24V. Tetrachloroethylene El El l < 0.300 1 ug/L (127-18-4)

VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FFL0000159 Outfall No. I-FG (SDT-1)

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. No.

Pollutant and CAS (if available) a.

testing b. be-lieved c. be-lieved a. Maximum Daily Value b. Max. 30-day Value (if available) e. Long(ifTerm Avg. Value available) d. No. of Analyses a. Cone. b. Mass a. Long Term Avg. Value b. No. of Analyses required present absent 0l)Con_. [ (2)Mass Mass (l)CCne (l))oCo.e. [(2)(2) Mass (1)Con.. MCone. () (2) Mass GC/N18IFILXWHON - VOLATILE COM.P051 L ".6tim d. <nu'.efl ___ . . . .. ___

25V. Toluene (108-88-3) C1 11 0l 0.630 (I) I ug/L 26V. 1,2-Trans- El El El < 0.300 1 ug/L Dichlomethyloene 0156-60-5) 27V. l,I,2-Tfichlomnnha El El El < 0.300 I ug/L (71-55-6) 28V. 1,1,2-Trichlomehaier El El El < 0.300 1 ug/L (7To,605) 29V. Trichloroethylene 0l 11 11 < 0.300 I ugfL (79-01-6) 1 30V. Trichloro- 11 0l El <0.300 I ug/L fluoromethane (75-69-4) 31V. Vinyl Chloride El El El < 0.300 I ugfL (75-01-4)

IA. 2-Chlorophenol El J;C/ý&,El

,-.- El pending (95-57-8) 2A. 2,4-Dichlorophenol El El El pending (120-83-2) 3A. 2,4-Dimethylphenol El El El pending (105-67-9) 4A. 4,6-Dinitro-O-Cresol El El El pending (534-53-1) 1 1 1 5A. 2,4-Dinitrophenol El El El pending (5 1-28-5) 6A. 2-Nitrophenol El El El pending (88-75-5) 7A. 4-Nitrophenol El El El pending (100-02-7) 8A P-Chloro-M-Cresol El El El pending (59-50-7) 9A Pentachlorophenol El El El pending (87-86-5) 10A Phenol El El El pending (108-95-2) 1IA 2,4,5-Trichloro- E E El pending phenol (88-06-2)

I B. Acenaphihene El El El pending (63-32-9) 2B. Acenaphtylene El El El pending (208-96-8) 3B. Anthracene E1 - E E pending (120-12-7) 4B. Benzidine - - El El pending (92-87-5) 1_1_1_1 VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOOOO 159 Outfall No. I-FG (SDT-I)

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

____________presentabsent (I) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass 5B. Benzo (a) Anthracene (56- El El El pending 55-3) 6B. Benzo (a) Pyrene El El El pending (50-32-8) 7B. 3,4-Benzo-fluoranthere El El 11 pending (205-99-2) 8B. Benzo (ghi Perylene El El 0l pending (191-24-2) 9B. Benzo (k) FRoranthene (207- El El El pending 08-9) 10B. Bis (2-Chlbocaihaty) El El El pending Methane ( 111 1)

I lB. Bis (2-chlorocthyl) El El El pending Ether (111-44-4) 12B. Bis ý20Amrlo El El El pending Ether ( 102 1) 13B. Bis (2-Eihylheyl) El El El pending Phthalate (117-81-7) 14B. 4-Bromophenyl El El El pending Phenyl Ether( 1001-55-3)

(5B Butyl Benzyl Phthalate El El El pending (84-68-7) 16B. 2-Chlormapllhalene El El El pending (91-58-7) 17B. 4-Chlorophenyl El El El pending Phenyl Ether (7005-72-3) 18B. Chrysene El El El pending (218-01-9) 19B. Dibenzo (a.h) El El El pending Anthracene (53-70-3) f 20B. 1.2-Dichlorobenzene El El El pending (95-50-1) 21 B. 1,3-Dichlorobenzene El El El pending (541-73-1) 22B. 1,4-Dichlombenzene El E] El pending (106-46-7) 23B. 3,3-Dichlodmtnzidine El El El pending (92 1) 24B. Diethyl Phthalate El El El pending (84-66-2) 25B. Dimethyl Phthalate El El El pending (131-11-3) 26B. Di-N-Butyl Phthalate El El El pending (84-74-2) 1 27B. 2,4-Dinitrotoluene El El El pending (121-14-2) 28B. 2,6-Dinitrotoluene El El El pending (606-20-2)

VIl-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOO0O159 Outfall No. I-FG (SDT- 1)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Conc. (2) Mass (I) Conc. (2) Mass (l) Conc. (2) Mass (I) Conc. (2) Mass 29B. Di-N-Octyl Phthalate 0 0 0 pending (117-84-0) 30B. 1,2-Diphentylhydrazine 01 0 C] ] pending (as AAzobanmtc)(122-66-7) I I I 1 1 31B. Fluoranthene 0 0 0 pending (206-44-0) 32B. Fluorene (86-73-7) 0 0 0 pending 33B. Hexachlorobenzene 11 E0 El pending (118-74-1) 34B. Hexachlorobutadiene 01 0l 0] pending (87-68-3) 1 35B. Hmxd yiLwxrtie 01 0l 0 pending (77-47-4) 36B. Hexachloroethane 0 11 0 pending (67-72-1) 37B. Indeno (1.2.3-cd) 0] 0 0:1 pending Pyrene (193-39-5) 38B. Isophorone El 0l El pending (78-59-1) 39B. Naphthalene 0 0 0 pending (91-20-3) 40B. Nitrobenzene 0 0 0 pending (98-95-9) 416 N-NBm, r1 0 0Eraf 0 pending (62-75-9) 42B. N-Nitrosodi-N- 0 0 0 pending Propylamine (621-64-7) 43B. N-Nitro-sodiphenylamine El 01 El pending (86-30-6) 44B Phenanthrene E0 01 0] pending (85-01-8) 45 B. Pyrene (129-00-0) El 01 0] pending 46B. 122A-Tnihlorornzene 01 0l [] pending (120-82-1)

IP. Aldrin (309-00-2) 01 E0 0 2P. -BHC (319-84-6) 01 01 0 3P -BHC (319-85-7) 0l 01 z 4P. -BHC (58-89-9) 0 01 0 5P. -BHC (319-86-8) 01 0l 0 VT)-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-FG (SDT-1)

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass 6P. Chlordane (57-74-9) El 0ED 7P. 4,4'-DDT (50-29-3) El El 0 8P. 4,4'-DDE (72-55-9) El El 0 9P. 4.4'-DDD (72-54-8) 11 El 0 lOP. Dieldrin (60-57-1) El 0l 0 IIP. -Endosulfan 11 El 0 (115-29-7) 12P. -Endosulfan El El 0 (115-29-7) 13P. Endosulfan Sulfate El El 0 (1031-07-8) 14P. Endrin (72-20-8) [] El [

15P. Endrin Aldehyde El El 0 (7421-92-4) 16P. Heptachlor 0l El 0 (76-44-8) 17P. Heptachlor Epoxide 0l El 0 (1024-57-3) 18P. PCB-1242 El El z (53469-21-9) 19P. PCB-1254 El El [

(11097-69-1) 20P. PCB-1221 El El 0 (11104-28-2) 21P. PCB-1232 El El 0 (11141-16-5) 22P. PCB-1248 El El 0 (12672-29-6) 23P. PCB-1260 El El 0 (11096-82-5) 24P. PCB-1016 El El 0 (12674-11-2) 25P. Toxaphene El El 0 (8001-35-2) 1 VTI-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. I-FE (LSST)

PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional Pollutant a. Max. Daily Value b. Max. 30-da, Value c. Annual Av . Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (I) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass Analyses (1)Conc, (2) Mass Analyses atotuathts kdmi"4a- N/A gn Demal (CBoD)

b. Chemical Oxygen 122 1 mg/L Demand (COD)

c. Total Organic 27.0 I mg/L Carbon (TOC)

d. Total Suspended 47.0 24.5 7.2 25 mg/L Solids (TSS)

e. TotalNiaougpn(asN) 9.34 1 mg/L f Total Phosphorus (as P) 2.43 I mg/L

g. Ammonia (as N) 3.24 I mg/L

h. Flow - actual or Value 0.0821 Value 0.0800 Value 0.0081 25 mgd Value projected

i. Flow - design Value Value Value I Value

j. Specific Conductiv'ity Value 561 Value Value I umhos/cm Value

k. Temperature (winter) Value27.0 Value Value I °C Value I. Temperature (summer) Value Value Value oC Value m..pH Min. 6.1 x8.8 Min. Max. 25 STANDARDLUNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optionalI I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Conc. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (ifavailable) Value (if available) Analyses Value Analyses present absent (I) Cone... (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass (1) Conc. (2) Mass

a. Bromide El El 0.0835 (I) I mg/L (24949-67-9)

b. Chlorine, El E Total Residual

c. Color El150 1 PCU

d. Fecal Coliform El 0

e. Fluoride El El 0.140 I mg/L (16984-48-8)

f. Nitrate-Nitrite El El 0.008 I mg/L (as N) I I Vll-1 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FLO000159 Outfall No. I-FE (LSST)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (1) Cone. (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass S)

g. Nitrogen, Total 6.10 1 mg/L Organic (as N)

n. Oil and grease 8.39 7.54 2.81 25 mg/L

i. Phosphorus, Total El El 2.43 I mg/L (as P) (7723-14-0)

(p ) Alpha, Total El <l0.501 1 pCi/L 2.71)

(2) Beta, Total 114 (+/- 8.86) 1 pCi/L (3) Radium, Total El [I < 0.0177 0.339)

I pCi/L (4) Radium 226, Total 0.692(+/- I pCi/L 0.282)

k. Sulfate (as SO4 (14808-79-8)

El 45.7 I mg/L 1.Sulfide (as S) [ ] pending

m. Sulfite (as S03 ) El 1:1 N/A (14263-5-45-3)

n. Surfactants T l 0l 0.146 I mg/L

o. Aluminum, Total El 0l 0.0843 I mg/L (7429-90-5)

p. Barium, Total El El 0.0663 1 mg/L (7440-39-3)

q. Boron, Total [ ] 1.020 I mg/L (7440-42-8)

r. Cobalt, Total El El 0.0013 I mg/L (7440-48-4)

s. Iron, Total [ ] 2.11 I mg/L (7439-89-6)

t. Maagnesium, Total [ ] 5.52 I mg/L (7439-95-4)

u. Molybdenum, Total [ ] 0.731 I mg/L (7439-98-7)

v. Manganese, Total [ ] 0.150 1 mg/L (7439-96-5)

w. Tin, Total 11 [] < 0.001 1 mg/L (7440-31-5)

x. Titanium, Total [ ] <001I.0 mg/L (7440-32-6) 1 1 VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOO0O159 Outfall No. I-FE (LSST)

PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark colunm 2b for acrolein, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outtfll. See instructions for additional details and requirements,

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a.. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (ifavailable) Analyses Analyses required present absent (1).... e. (2) Mass (1)Con. (2)1Mass Cone.

.... s (,)Cc ... (2) Mass

ýMETAL*SKCYANtID Ei AND TOTAL P4 ENO ES : , - ,1 .ý:S -::.,.:..J,)4" , , , .,, . 4 ,r , ,.

IM. Antimony, Total [I El [E 0.612(1) I ug/L (7440-36-0) 2M. Arsenic, Total El El El < 1.66 I ug/L (7723-14-0) 3M. Beryllium, Total l El l < 0.200 I ug/L (7440-41-7) 4M. Cadmium, Total l El El 0.092(1) 1 ug/L (7440-43-9) 5M. Chromium, Total 0l El El 623 I ug/L (7440-47-3) 6M. Copper. Total El El El 15.4 1 ug/L (7440-50-8) 7M. Lead, Total 0E El 14.6 I ug/L (7439-92-1) 8M. Mercury, Total El El El pending (7439-97-6) 9M. Nickel, Total El 0l El 59.6 1 ug/L (7440-02-0) 10M. Selenium, Total El El El < 1.50 I ug/L (7782-49-2)

I I M. Silver, Total El 0 El 0.356(I) I ug/L (7440-22-4) 12M. Thallium, Total l El l < 0. 125 I ug/L (7440-28-0) 13M. Zinc, Total El El El 0.0922 I mg/L (7440-66-6) 14M. Cyanide. Total El El El 2.171l) I ug/L (57-12-5) 1 15M. Phenols, Total El El [1 24.0 1 ug/L 2,3,7,8-Tetra- 0] [] [

chlorodibenzo-P- Dioxin

( 1764-01-6)

IV. Acrolein [] [ ] < I.50u ........ I ug/L (W07-02-9) 2V. Acrylonitrile El < 1.50 1 ug!L (107-13-1) 1 1 _ 1 __1,7 ____

VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. I-FE (LSST)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (ifavailable) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

*GCMS O*VI.*.TILE lQM (1)Conc.

UNI1*(contin tel)*

( (2) Mass (1)Cone. ] (2) Mass (I)Cone.. (2) Mass

__,__ :* j,.:** _ " ',**:,.::*

(j)Cnc.

Co

,=:?-.

(2) i:,

Mass 3V. Benzene 11 El El < 0.300 I ug/L (7 1-43-2) 4V. Bis (Chloromethyl) Ether El El [

(542-88-I) 5V. Bromoform l El l < 0.300 I ug/L (75-25-2) 6V. Carbon Tetrachloride 11 El El < 0.300 I ug/L (56-23-5) 7V Chlorobenzene l El El < 0.300 I ug/L (108-90-7) 8V. Chlorodi- l El El < 0.300 I ug/L bromomethane (124 I) 9V. Chloroethane El El < 0.300 I ug/L (74-00-3)

IyV. 2-Chloro-ethylvinyl El El El Pending Ether ( 10-75-8) 1IV. Chloroform El El < 0.300 I ug/L 167-86-3) 12V. Dichloro- l El l < 0.300 I ug/L bromomethane (75-24-4) 13V. Dichloro- El El El < 0.300 I ug/L difluonomethane (75-71-8) 14V. Il-Dichloroethane El El El < 0.300 I ug/L (75-34-3) 15V. 1,2-Dichloroethane El El El < 0.300 1 ug/L (107-06-2) 16V. I,I-Dichloroethylene El El El < 0.300 1 ug/L (75-35-4) 17V. 1.2.-Dichlotoppane El El El < 0.300 I ug/L (78-87-5) 18V. 1,3-Dichlompropylene El El El <0.300 1 ug/L (542-75-6) 19V. Ethylbenzene El El El < 0.300 I ug/L (100-41-4) 20V. Methyl Bromide El El El < 0.300 1 ug/L (74-83-9) 21 V. Methyl Chloride El El El < 0.300 I ug/L (74-87-3) 22V. Methylene Chloride El El El < 1.00 I ug/L (74-98-2) 23V. 1,1,2,2-Tetm- l El] Cl < 0.300 I ug/L chloroethane (79-34-5) 24V. Tetrachloroethylene El El El <0.300 1 ug/L (127-7-18-4)

VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-FE (LSST)

1. Pollutant and CAS No. (if available) a..

testing

2. Mark "X"

b. be-lieved

1. be-lieved

a. Maximum Daily Value

3. Effuent

b. Max. 30-day Value (if available)

c. Long Term Avg. Value (if available)

d. No. of Analyses

4. Units

a. Conc. b. Mass

5. Intake (optional)

a. Long Term Avg. Value b. No. of Analyses required present absent

________ -_____ (l)Cone. 12)Mass

( (l)Conc. j (2) Mass (I) Conc. 1-(2) Mass] (I) Conc. [ (2) Mass 25V. Toluene (108-88-3) 0] 01 03 < 0.300 I ug/L 26V. 1,2-Trans- 0 0 < 0.300 I ug/L Dichlomedsylene (156-60-5) 27V. ,12-Thichloroethane 0 0 < 0.300 I ug/L (71-55-6) lr 28V. I,1.2-Trichlouethane 0 0 < 0.300 1 ug/L (79-00-5) 29V. Trichloroethylene 0 0 < 0.300 I ug/L (79-01-6) 30V. Trichloro- 0l 01 0l < 0.300 I ug/L fluoromethane (75-69-4) 3 1V. Vinyl Chloride 0 < 0.300 I ug/L (75-01I-4)

IA. 2-Chlorophenol 0 0 0 < 3.26 1 ug/L (95-57-8) 2A. 2,4-Dichlorophenol 0 0 < 3.26 I ug/L (120-83-2) 3A. 2,4-Dimethylphenol 0 0 < 3.26 1 ug/L (105-67-9) 4A. 4,6-Dinitro-O-Cresol 0 0 < 3.26 1 ug/L (534-53-1) 5A. 2,4-Dinitrophenol 0 0 < 5.43 1 ug/L (51-28-5) 6A. 2-Nitrophenol < 3.26 I ug/L (88-75-5) 7A. 4-Nitrophenol 01 0l 01 < 3.26 I ug/L (100-02-7) 8A P-Chloro-M-Cresol 0 0 < 3.26 I ug/L (59-50-7) 9A Pentachlorophenol 0 0 < 3.26 I ug/L (87-86-5) 1OAPhenol 0 < 3.26 1 ug/L (108-95-2)

I IA 2,4,5-Trichloro- 0l [0 E0 < 3.26 1 ug/L phenol (88-06-2)

I B. Acenaphthene El < U.326 1 ug/L (63-32-9) 2B. Acenaphtylene 0] 0 0 < 0.326 I ug/L (208-96-8) 3B. Anthracene - ] 0 0 < 0.326 I ug/L (120-12-7) 4B. Benzidine - 0 - 0 ] < 3.26 1 ug/L (92-87-5) 1___1 __1 VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. I-FE (LSST)

2. Mark "X' 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass (I) Conc. (2) Mass 5B. Benzo (a) Anthracene l El El < 0.326 1 ug/L (56-55-3) 6B. Benzo (a) Pyrene l El El < 0.478 I ug/L (50-32-8) 7B. 3,4-Berwo-fluoranthene l El El < 0.326 I ug/L (205-99-2) 8B. Benzo (ghi) Perylene El 0l El < 0.326 I ug/L (191-24-2) 1 1 1 9B. Benzo (k) Fluorarahene (207- El El El < 0.326 1 ug/L 08-9) 10B. Bis t2.Ch/auatDAy) El El El < 3.26 I ug/L Methane ( 11 I1)

I8B. Bis (2-chloroethyl) l El l < 3.26 1 ug/L Ether ( 111-44-4) 12B. Bis O npz. El El El < 3.26 1 ug/L Ether (102 1) 13B. Bis (2-Ethvlhxyl El El El < 3.26 1 ug/L Phthalate (117-8 1-7) 14B. 4-Bromophenyl l El El < 3.26 I ug/L Phenyl Ether ( 10 1-55-3) 15B Butyl Benzyl Phthalate l El l < 3.26 I ug/L (84-68-7) 16B. 2-Chloronaphlhlene El E l < 0.326 I ug/L (91-58-7) 17B. 4-Chlorophenyl l El l < 3.26 I ug/L Phenyl Ether (7005-72-3) 18B. Chrysene l El l < 0.326 1 ug/L (2 18-01-9) 19B. Dibenzo (a.h) El El El < 0.326 1 ug/L Anthracene (53-70-3) 20B. 1,2-DihlcIbenzone l El l < 3.26 I ug/L (95-50-I) 21B. 1,3-Dichlonjbenzene l El El < 3.26 I ug/L (541-73-1) 22B. 1,4-Dichlorobenzene l El l < 3.26 I ug/L (106-46-7) 23B. 33-Dichlomberzidine E] El El < 3.26 1 ug/L (92-94-1) 24B. Diethyl Phthalate El El El < 3.26 1 ug/L (84-66-2) 1 25B. Dimethyl Phthalate El El El < 3.26 I ug/L (131-11-3) 26B. Di-N-Butyl Phthalate El El El < 3.26 I ug/L (84-74-2) 27B. 2,4-Dinitrotoluene l El El < 3.26 1 ug/L (121-14-2) 28B. 2,6-Dinitrotoluene l El El < 3.26 1 ug/L (606-20-2) 1 1 VII-6 DER Fomi 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO00O159 Outfall No. I-FE (LSST)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Conc. (2) Mass (I) Cone. (2) Mass (I) Conc. (2) Mass (1) Conc. (2) Mass 29B. Di-N-Octyl Phthalate 0 0 < 3.26 I ug/L (117-84-0) 308. 1,2-Diphenylhydrazine 0 0 < 3.26 I ug/L (aszob-) (I L)-66-71) 31B. Fluoranthene 0 0l 01 < 0.326 I ug/L (206-44-0) 32B. Fluorene (86-73-7) 0 < 0.326 1 ug/L 33B. Hexachlorobenzene 0 0 < 3.26 1 ug/L (118-74-1) 34B. Hexachlorobutadiene 0] 0 3 < 3.26 1 ug/L (87-68-3) 35B. HNedt*4nr 0] 0 < 3.26 I ug/L (77-47-4) 36B. Hexachloroethane 0 0 [ < 3.26 1 ug/L (67-72-I) 37B. Indeno (1.2.3-cd) 0 < 0.326. I ug/L Pyrene (193-39-5) 38B. lsophorone 0 0 < 3.26 I ug/L (78-59-1) 39B. Naphthalene 0l 0:1 0 < 0.326 1 ug/L (91-20-3) 40B. Nitrobenzene 0 0 < 3.26 I ugIL (98-95-9) 41BN-Ninxthr, l'lanie 0 0 0 < 3.26 I ug/L (62-75-9) 42B. N-Nitrosodi-N- 0 0 0 < 3.26 I ug/L Propylamine (621-64-7) 43B. N-Nitro- 01 0l 0] < 3.26 I ug/L sodiphenylamine (86-30-6) 44B Phenanthrene 01 0l 01 < 0.326 I ug/L (85-01-8) 45B. Pyrene (129-00-0) 0 < 0.326 I ug/L 46B. 1I2,4-Tfichloroberene 0 0l 0 < 3.26 1 ug/L (120-8 2- 1)V O

IP. Aldrin (309-00-2) U 0 0 2P. -BHC (319-84-6) 01 0:1 0 3P -BHC (319-85-7) 0] 0 0 4P. -BHC (58-89-9) 03 0 0 5P. -BHC (319-86-8) 0l 01 0 VII-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. I-FE (LSST)

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass 6P. Chlordane (57-74-9) 0 0 0 7P. 4,4'-DDT (50-29-3) 0 0 0 8P. 4,4'-DDE (72-55-9) 01 0 0 9P. 4,4'-DDD (72-54-8) 0 0 0 lOP. Dieldrin (60-57-1) 0l 0 0 l IP. -Endosulfan 0] 0 0 (115-29-7) 12P. -Endosulfan 0 0 0 (115-29-7) 13P. Endosulfan Sulfate 0 01 0 (1031-07-8) 14P. Endrin (72-20-8) 0 0 0 15P. Endrin Aldehyde 0 0 0 (7421-92-4) 16P. Heptachlor 0 0 [

(76-44-8) 17P. Heptachlor Epoxide 0] 0:1 0 (1024-57-3) 18P. PCB-1242 0 01 E (53469-21-9) 19P. PCB-1254 0 0 0 (11097-69-I) 20P. PCB-1221 0 E0 0D (11104-28-2) 21P. PCB-1232 0 [0 0 (11141-16-5) 22P. PCB-1248 00 0 (12672-29-6) 23P. PCB-1260 0 0 0 (11096-82-5) 24P. PCB-1016 0 0 0 112674-11-2) 25P. Toxaphene 0 0 0 (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. ECST PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for everpollutnt in this table. Complete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional Pollutant a. Max. Daily Value b. Max. 30-day Value c. Annual Av . Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass Analyses (I) Cone. (2) Mass Analyses a C*srantns BuchamLA N/A I mg/L Oyl*w D_ __rd _C___)

b. Chemical Oxygen 36.3 1 mg/L Demand (COD)

c. Total Organic 0.461 (1) 1 mg/L Carbon (TOC)

d. Total Suspended < 4.0 < 4.0 < 2.0 23 mg/L Solids (TSS)

e. Total Niteng (as N) 0.114 I mgnL f Total Phosphonus (as P) < 0.017 1 mg1L

g. Ammonia (as N) 0.0502 I mgIL

h. Flow - actual or Value 0.0145 Value 0.0130 Value 0.0020 25 mgd Value projected

i. Flow - design Value Value Value I Value

j. Specific Conductivity Value 5.0 Value Value I umhos/cm Value

k. Temperature (winter) Value Value Value *C Value I. Temperature (summer) Value Value Value °C Value m.. pH Min. 5.47 M,5.47 Mit. M 1 STANDARD UNITS _

PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Cone. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Cone... (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass

a. Bromide El 0l < 0.067 1 mg/L (24949-67-9)

b. Chlorine, El [

Total Residual

c. Color 0l 11 < 5.0 I PCU

d. Fecal Coliform El 0

e. Fluoride El 11 < 0.033 I mg/L (16984-48-8)

f. Nitrate-Nitrite El 0l 0.0748 I mg/L (as N)

VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-13 Contd. Facility ID. Number FLOO00159 Outfall No. ECST

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass (1) Conc. (2) Mass

g. Nitrogen, Total 0 11 < 0.033 1 mg/L Organic (as N)

h. Oil and grease 0 11 3.7 2.9 < 1.5 25 mg/L

i. Phosphorus, Total : El < 0.017 1 mg/L (as P) (7723-14-0)

(I) Alpha, Total El Dl < 0.500 (+- pCi/L 2.52 (2) Beta, Total 11 0l 105 (+/- 8.55) I pCi/L (3) Radium, Total l El < 0.207 I 1+/- pCi/L 0.404)

(4) Radium 226. Total l El < 0.384 (+/- I pCi/L 0.295)

k. Sulfate (as SO4) El E 0.516 I mg/L (14808-79-8)

I. Sulfide (as S) l El < 0.033 I mg/L

m. Sulfite (as SOA) El 0l N/A (14265-45-3)

n. Surfactants l El < 0.032 1 mg/L

o. Aluminum, Total l El < 0.015 1 mg/L (7429-90-5)

p. Barium, Total l El < 0.0005 1 mg/L (7440-39-3)

q. Boron. Total El 164.0 1l I mg/L (7440-42-8)

r. Cobalt, Total El El < 0.0001 1 mg/L (7440-48-4)

s. Iron, Total El El 0.012 (l) 1 mg/L (7439-89-6)

I. Maagnesium, Total l El < 0.010 I mg/L (7439-95-4)

u. Molybdenum, Total El El < 0.000167 I mg/L (7439-98-7)

v. Manganese, Total El El < 0.001 1 mg/L (7439-96-5)

w. Tin, Total El El < 0.001 1 mg/L (7440-3 I-5)

x. Titanium. Total l El < 0.001 I mg/L (7440-32-6) 1 VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOO0O159 Outfall No. ECST PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you nmust test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you mutst either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

t. Pollutant and CAS a.. b. be- e.be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

_METAL_______,_ND TTAL*PhE(4fl(S.J*?i* '.*.5!*

(T)AConN. t(2) Mass (t)Co.... _(2)Mass

.. !..2*.,.. .. ' :..

(1)zCone.

T =

Ma- t2

"$r.*:!:**

([)Co..

?..*....,

(2) Mass s.

IM. Antimony, Total 0 < 0600 1 ug/L (7440-36-0) 2M. Arsenic, Total 0 0 0 < 1.66 1 ug/L (7723-14-0) 3M. Beryllium, Total 01 0l 01 < 0.200 1 ug/L (7440-41-7) 4M. Cadmium, Total 0 < 0.030 I ug/L (7440-43-9) 5M. Chromium, Total 0 0 < 1.00 1 ug/L (7440-47-3) 6M. Copper, Total 01 0l 0l 2. 0 I ug/L (7440-50-8) 7M. Lead, Total 0 < 0.500 I ug/L (7439-92-I) 8M. Mercury, Total [] 0 01 0.000842 I ug/L (7439-97-6) 9M. Nickel, Total 0l 0 0 < 0.500 1 ug/L (7440-02-0) 10M. Selenium, Total 01 0 < 1.50 I ug/L (7782-49-2) 1IM. Silver. Total 0] 0l 0l < 0.200 1 ug/L (7440-22-4) 12M. Thallium, Total 0 11 l < 0. 125 1 ug/L (7440-28-0) 13M. Zinc, Total 0 0 51.4 I ug/L (7440-66-6) 14M. Cyanide, Total 0 0 0 < 1.67 1 ug/L (57-12-5) 15M. Phenols, Total 0 0 0 < 1.67 I ug/L 2,3,7,8-Tetra- 0] []

chlorodibenzo-P- Dioxin (1764-01-6)

IV. Acrolein [] [

D] < 1.50 I ug/L (107-02-8) 2V. Acrylonitrile < ug/L (107-13-1)

VII-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. ECST

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Conc. (2) Mass (1) Cone. (2) Mass (1) Conc. (2) Mass 0 (I)Conc.

3V. Benzene EL Li EL < 0.300 1 ug/L (71-43-2) 4V. Bis (Chloromethyl) Ether 11 13 0 (542-88-I) 5V. Bromoform El El El < 0.300 I ug/L (75-25-2) 6V. Carbon Tetrachloride [] El El < 0.300 1 ug/L (56-23-5) 7V Chlorobenzene El 11 El < 0.300 1 ug/L (108-90-7) 8V. Chlorodi- [] 11 E- < 0.300 I ug/L bromomethane (124 1) 9V. Chloroethane [] El 11 < 0.300 I ug/L (74-00-3) tOV. 2-Chloro-ethylvinyl 0l El El < 1.50 I ug/L Ether (110-75-8) 1 1 1 I V. Chloroform El El El < 0.300 I ug/L (67-86-3) 12V. Dichloro- l 11] El < 0.300 1 ug/L bromomethane (75-24-4) 13V. Dichloro- El 11 0l < 0.300 I ug/L difluorxmethane (75-71-8) 14V. I,I-Dichloroethane 11 El [J < 0.300 I ug/L (75-34-3) 15V. 1,2-Dichloroethane 0 11 0 < 0.300 1 ug/L (107-06-2) 16V. I,1-DichlNoroethylene 13 El 13 < 0.300 1 ug/L (75-35-4) 17V. 1,2,-Dichloropropane 11 El El < 0.300 1 ug/L (78-87-5) 18V. 1,3-Dichl ipropylene El El El < 0.300 I ug/L (542-75-6) 1 1 19V. Ethylbenzene l El El < 0.300 1 ug/L (100-41-4) 20V. Methyl Bromide El El El < 0.300 1 ug/L (74-83-9) 21V. Methyl Chloride El El El < 0.300 I ug/L (74-87-3) 22V. Methylene Chloride El El El < 1.00 I ug/L (74-98-2) 1 1 1 1 23V. 1,1,2,2-Tetra- El El El <0.300 I ug/L chloroethane (79-34-5) 1 24V. Tetrachloroethylene [j El l < 0.300 1 ug/L (127-18-4)

VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO00O159 Outfall No. ECST

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing required lieved lieved present absent T - - - --

(l)Cone. (2) Mass (if available)

(l)Conc. (2) Mass (if available)

(1) Conc.

f 2) Mass j Analyses Cn (I)Conc.

( Mass (2) Mass Analyses 25V. Toluene (108-88-3) 0] El < 0.300 I ug/L 26V. 1,2-Trans- 0l El 1] < 0.300 I ug/L Dichlomethylene (156-60-5) 27V. 1,12-Ttichlotuethane 11 El El < 0.300 1 ug/L (71-55-6) 28V. l,l,2-Ttichloroethane El El El < 0.300 I ug/L (79-00-5) 29V. Trichloroethylene l El El < 0.300 1 ug/L (79-01-6) 30V. Trichloro- l El El < 0.300 1 ug/L fluoromethane (75-69-4) 31V. Vinyl Chloride l El El < 0.300 1 ug/L (75-01I4)

IA. 2-Chlorophenol < 2.83 1 ug/L (95-57-8) 2A. 2.4-Dichlorophenol l El El < 2.83 1 ug/L (120-83-2) 3A. 2,4-Dimethylphenol l El [] < 2.83 1 ug/L (105-67-9) 4A. 4,6-Dinitro-O-Cresol C1 El 0l < 2.83 1 ug/L (534-53-1) 5A. 2,4-Dinitrophenol El E 0- < 4.72 1 ug/L (51-28-5) 6A. 2-Nitrophenol El El l < 2.83 1 ug/L (88-75-5) 7A. 4-Nitrophenol l El [] < 2.83 1 ug/L (100-02-7) 8A P-Chloro-M-Cresol l El El < 2.83 I ug/L (59-50-7) 9A Pentachlorophenol El El El < 2.83 1 ug/L (87-86-5) 10A Phenol El El l < 2.83 1 ug/L (108-95-2)

I IA 2,4,5-Trichloro- l El El < 2.83 I ug/L phenol (88-06-2)

B. Acenaphthene < 0.283 1I ug/L (63-32-9) 2B. Acenaphtylene El El E] < 0.283 I ug/L (208-96-8) 3B. Anthracene El El E - <0.283 1 ug/L (120-12-7) 1 4B. Benzidine l El El <2.83 1 ug/L 192-87-5)

V1l-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. ECST

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent

____________sentabsent_(I) Conc. (2) Mass (I) Conc. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass 5B. Benzo (a) Anthracene l El El < 0.283 1 ug/L (56-55-3) 6B. Benzo (a) Pyrene 0l El El < 0.415 1 ug/L (50-32-8) 7B. 34-Berjo-fluorantie 1 E < 0.283 1 ug/L (205-99-2) 8B. Benzo (ghi, Perylene El El 0l < 0.283 1 ug/L (191-24-2) 9B. Benzo (A)Fluoanthene (207- 1 El l < 0.283 I ug/L 08-9) 10B. Bis (2-Chfa/varosy El C]

E E < 2.83 1 ug/L Methane (111-91-I) 1 I I B. Bis (2-chloroelhyl) 0l El [I < 2.83 1 ug/L Ether ( 11-44-4) 1 12B. Bis .2'*~q p4 E <283 1 ug/L Ether ( 102 1) 13B. Bis (2-EthyIhexyIl) l El E0 < 2.83 1 ug/L Phthalate (117-81-7) 14B. 4-Bromophenyl [] El El < 2.83 I ug/L Phenyl Ether (101-55-3) 15B Butyl Benzyl Phthalate El 11 0l < 2.83 I ug/L (84-68-7) 1 1 16B. 2-Chlounaphthalene 0 0 < 0.283 1 ug/L (91-58-7) 17B. 4-Chlorophenyl l El l < 2.83 1 ug/L Phenyl Ether (7005-72-3) 18B. Chrysene [I El < 0.283 I ug/L (218-01-9) 19B. Dibenzo (a.h) EL El 0l < 0.283 I ug/L Anthracene (53-70-3) 20B. 1,2-Dichlorobenzene L El l < 2.83 I ug/L (95-50-1) 211B. 13-Dichlombenzene El El < 2.83 I ug/L (541-73-1) 22B. 1,4-Dichlorobenzene l El El < 2.83 I ug/L (106-46-7) 23B. 3,3-Dichlombenzidine l El El < 2.83 I ug/L (92-94-I) 24B. Diethyl Phthalate El E El < 2.83 I ug/L (84-66-2) 25B. Dimethyl Phthalate l El El < 2.83 I ug/L (131-11-3) 26B. Di-N-Butyl Phthalate EL El El < 2.83 I ug/L (84-74-2) 27B. 2,4-Dinitrotoluene El El El < 2.83 I ug/L (121-14-2) 28B. 2,6-Dinitrotoluene El El El < 2.83 I ug/L (606-20-2) 1_1 VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. ECST

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass 29B. Di-N-Octyl Phthalate 11 El El < 2.83 I ug/L (117-84-0) 30B. 1,2-Diphenylhydrazine l El El < 2.83 1 ug/L (asAzoreizmto) ( I22)-66-7) 31B. Fluoranthene [] El E] < 0.283 I ug/L (206-44-0) 32B. Fluorene (86-73-7) 1 El El < 0.283 I ug/L 33B. Hexachlorobenzene 11 11 El < 2.83 1 ug/L (118-74-1) 1 34B. Hexachlorobutadiete 11 El El < 2.83 I ug/L (87-68-3) 35B. H= 5d 7e 11 El < 2.83 I ug/L (77-47-4) 36B. Hexachloroethane l El] El < 2.83 I ug/L (67-72-1) 37B. Indeno (1.2.3-cd) 11 El 0l < 0.283 I ug/L Pyrene (193-39-5) 38B. Isophorone El El El < 2.83 1 ug/L (78-59-1) 39B. Naphthalene El El El < 0.283 1 ug/L (91-20-3) 40B. Nitrobenzene El El El < 2.83 I ug/L (98-95-9) 41B N-Niatetlanine El El El <2.83 I ug/L (62-75-9) 42B. N-Nitrosodi-N- El El El < 2.83 I ug/L Propylamine (621-64-7) 43B. N-Nitro- l El El < 2.83 I ug/L sodiphenylamine (86-30-63 44B Phenanthrene El El El < 0.283 1 ug/L (85-0 1-8) 45B. Pyrene 1129-00-0) El El El < 0.283 I ug/L 46B. I2,4-Ttichlomberznae l El El < 2.83 1 ug/L (120-82-1)1 I P. Aldrin (309-00-2) El Eli E 2P. -BHC (319-84-6) El El 0 3P -BHC (319-85-7) El 0l 0 4P. -BHC (58-89-9) El El 0 5P. -BHC (319-86-8) 11 El 0 V11-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. ECST

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I) Conc. (2) Mass (I) Conc. (2) Mass (I) Conc. (2) Mass (1) Conc. (2) Mass 6P. Chlordane (57-74-9) 0 01 0D 7P. 4,4'-DDT (50-29-3) 0 0 z 8P. 4,4'-DDE (72-55-9) 01 0 0 9P. 4,4'-DDD (72-54-8) 03 0 0 lOP. Dieldrin (60-57-1) 0 0 0 II P. -Endosulfan 0 0 0 (115-29-7) 12P. -Endosulfan 0 0 0 (115-29-7) 13P. Endosulfan Sulfate 0] 0] 10 (1031-07-8) 14P. Endrin (72-20-8) 0 0 0 15P. Endrin Aldehyde 0 0 0 (7421-92-4) 16P. Heptachlor 0:1 0 0 (76-44-8) 17P. Heptachlor Epoxide 03 0 0 (1024-57-3) 18P. PCB-1242 01 01 0 (53469-21-9) 1 19P. PCB-1254 01 01 0 (11097-69-1) 20P. PCB-1221 0 0 0 (11104-28-2) 21P. PCB-1232 03 0 0 (11141-16-5) 22P. PCB-1248 01 01 0 (12672-29-6) 23P. PCB-1260 0 0 0 (11096-82-5) 24P. PCB-1016 0 01 10 (12674-11-2) 25P. Toxaphene 0 0 0 (18001-35-2)

V1I-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-C2R PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results of at least one analysis for every pollutant in this table. Cornlete one table for each outfall. See instructions for additional details.

I. 2. Effluent 3.. Units 4. Intake (optional)

Pollutant a. Max. Daily Value b. Max. 30-da y Value c. Annual A' z. Value d. No. of a. Concentration b. Mass a. Long Term Avg. Value b. No. of (1) Conc. (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass Analyses (1) Conc. (2) Mass Analyses aCrmb Bu -rit < 3.0 I mg/L GIy Damsd lC_0_)

b. Chemical Oxygen 2020 I mg/L Demand (COD)

c. Total Organic 16.7 I mg/L Carbon (TOC)

d. Total Suspended 53 34.2 5 mg/L Solids (TSS) e.Total Nitrgen (as N) 18.7 1 mI/L f Total Phosphorus (as P) < 0.050 1 mg._fL g.Ammonia (as N) 1.2 1 mgL

h. Flow - actual or Value N/A Value Value Value projected I I I

i. Flow - design Value N/A Value Value 1 Value

j. Specific Conductivity Value 15.740 Value Value I umhos/cm Value

k. Temperature (winter) Valuel8.9 Value Value I °C Value I. Temperature (summer) Value Value Value °C Value m.. pH Min. 7.5 Min. STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column.2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additonal details and requirements.

2. Mark "X" 3. Effluent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. be- b. be a. Maximum Daily b. Max. 30-day Value c. Long Term Avg. d. No. of a. Cone. b. Mass a. Long Term Avg. b. No. of No. (if available) lieved lieved Value (if available) Value (if available) Analyses Value Analyses present absent (I) Cone... (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass (1) Cone. (2) Mass

a. Bromide El El 58.6 I mg/L (24949-67-9)

b. Chlorine. El El 0.1 I mg/L Total Residual

c. Color El El 50.0 I PCU

d. Fecal Coliform El 11 < 2.0 I CFU/100 mL

e. Fluoride El El 25.3 I mg/L (16984-48-8)

f. Nitrate-Nitrite El El 14.7 1 mg/L (as N) I I I I VII-I DER Form 62-620.910(5)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. D-C2R

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a .be- b. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) lieved lieved (if available) (if available) Analyses Analyses present absent (1) Conc. (2) Mass (I) Cone. (2) Mass (I) Conc. (2) Mass (1) Conc. (2) Mass

g. Nitrogen, Total 11 0l 2.8 I mg/L Organic (as N)

h. Oil and grease 11 0l < 1.2 < 1.15 2 mg/L

i. Phosphorus, Total 0l 0l < 0.050 1 mg/L (as P) (7723-14-0)

,4 i .;*; ,'...... ,* . _______ _...._ _ _ _ _

(I) Alpha, Total 0 [] 63.3(+/- 11.8) 1 pCi/L (2) Beta, Total 0l El <27.1 (+/- I pCi/L 16.0)

(3) Radium, Total 0l [l 11.5 (+/- 2.70) 1 pCi/L (4) Radium 226, Total 0l El 11.2 (+/- 2.41) I pCiIL

k. Sulfate (as SO 4 ) 0l 0l 1.290 I mg/L (14808-79-8)

1. Sulfide (as S) 0l 0l < 1.0 I mg/L

m. Sulfite (as SOs) 0l 0 < 10 I mgfL (14265-45-3)

n. Surfactants 0l El 0.78 1 mg/L

o. Aluminum, Total 0l 0l < 0.050 I mg/L (7429-90-5)

p. Barium, Total 0l 0l 0.258 I mg/L (7440-39-3)

q. Boron, Total 0l El 306 1 mg/L (7440-42-8)

r. Cobalt, Total El El 0.0115 1 mg/L (7440-48-4)

s. Iron, Total El El 0.071 (1) 1 mg/L (7439-89-6)

t. Maagnesium, Total El El 1,940 1 mg/L (7439-95-4)

u. Molybdenum, Total El 0l 0.0295 I mg/L (7439-98-7)

v. Manganese, Total El El 3.350 1 mg/L (7439-96-5)

w. Tin, Total El El < 0.025 I mg/L (7440-31-5) 1 1

x. Titanium, Total El El < 0.025 1 mg/L (7440-32-6)

VII-2 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-C2R PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, non-process wastewatcr outfalls, and non-required GC/MS fractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolcin, acrylonitrile, 2,4,dinitrophenol, or 2-methyl.4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements.

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (I)C.n... ]()Ms I) .. (2)2)s

]()Mas () .. Mass )_Co... (2)Mass I M. Antimony, Total El El [1 < 5.0 I ugfL (7440-36-0) 2M. Arsenic, Total El El 11 4.0(1) I ugfL (7723-14-0) 3M. Beryllium, Total El E l < 0.50 I ug/L (7440-41-7) 4M. Cadmium, Total El El El 65.0 I ug/L (7440-43-9) 5M. Chromium, Total El El El < 4.0 I ug/L (7440-47-3) 6M. Copper, Total El El El 12.0 I ug/L (7440-50-8) 7M. Lead, Total El El El 2.1 (1) 1 ug/L (7439-92-I) 8M. Mercury, Total El El El 0.013 I ug/L (7439-97-6) 9M. Nickel, Total El El El 200 I ug/L (7440-02-0) 10M. Selenium, Total El El El 1.0 I ug/L (7782-49-2)

I1M. Silver, Total El El El 0.079 (l) t ug/L (7440-22-4) 12M. Thallium, Total El El El 6.6 I ug/L (7440-28-0) 13M. Zinc, Total El El El 68.0 (1) 1 ug/L (7440-66-6) 14M. Cyanide, Total El El El 33.0 I ug/L (57-12-5) 15M. Phenols, Total El El < 5.0 I ug/L 2,3,7,8-Tetra- -10 _

chlorodibenzo- P-Dioxin

( 1764-01-6)

IV. Acrolein El 0] El < 10.0 1 ug/L (107-02-8) 2V. Acrylonitrile [I El [- < 5.0 1 ug/L (107-13-1) 1 VI1-3 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-C2R

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Anlyses required present absent (1) Coce. (2) Mass (I) Cone. (2 Mass (l Con. I (1)Cone Mass ScTO*.vnlAýTlibElCOMWOUN0s9 .

3V. Benzene [] [ ] < 0.50 I ug/L (71-43-2) 4V. Bis (Chloromethyl) Ether El El 0 (542-88-1) 1 1 5V. Bromoform 0l El El < 0.50 1 ug/L (75-25-2) 6V. Carbon Tetrachloride l El El < 0.50 I ug/L (56-23-5) 7V Chlorobenzene El 11 El < 0.40 I ug/L (108-90-7) 8V. Chlorodi- l El El < 0.25 I ug/L bromomethane (124-8-I)_

9V. Chloroethane l El El < 0.61 I ugIL (74-00-3)

IOV. 2-Chloro-ethylvinyl El C1 El < 5.0 1 ug/L Ether (110-75-8) 1IV. Chloroform EL 0l El < 0.50 I ungL (67-86-3) 12V. Dichloro- L Cl El < 0.30 I ug/L bromomethane (75-24-4) 13V. Dichloro- [I E[l < 0.50 I ug/L diIucrunrttone 175-71-8) 14V. 1,1-Dichloroethane Ul C3 C3 < 0.50 1 ug/L (75-34-3) 15V. 1,2-Dichloroethane 0l Cl 0 < 0.50 1 ug/L (107-06-2) 16V. I, I-Dichloroethylene El []l E < 0.71 1 ug/L (75-35-4) 17V. 1,2.-Dichloropmpane El 0l El < 0.50 1 ug/L (78-87-5) 18V. 1,3-Dichlomprpylene El El < 0.50 1 ug/L (542-75-6) 19V. Ethylbenzene El El El < 0.50 I ug/L (100-41-4) 20V. Methyl Bromide El El El < 0.50 1 ug/L (74-83-9) 21V. Methyl Chloride El El El < 0.50 1 ug/L (74-87-3) 1 22V. Methylene Chloride El El El < 2.5 1 ug/L (74-98-2) 23V. 1.1,2,2-Tetra- El El El <0.17 I ug/L chloroethane (79-34-5) 24V. Tetrachloroethylene El El El < 0.50 1 ug/L (127-18-4) 1 VII-4 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOOOO 159 Outfall No. D-C2R

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

t. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (l)Cone. J (2) Mass (t)Cone. j (2) Mass (I) Cone. (I)Cone.

(1(2)Mass (!2) Mass 25V. Toluene (108-88-3) El El El < 0.50 I ug/L 26V. 1,2-Trans- El El El < 0.50 I ug/L Dib*lio*ieth-yle( (156-60-5) 27V. 1,1,2-Trichlomentnae El 0 < 0.50 1 ug/L (71-55-6) 28V. l,l.2-Trichlomethane [I El El < 0.50 I ug/L (79-00-5) 29V. Trichloroethylene El El <l

< 0.50 I ug/L (79-01-6) 30V. Trichloro- CI El C] < 0.66 I ug/L fluoromethane (75-69-4) 3IV. Vinyl Chloride El El El < 0.53 I ug/L (75-01-4)

IA. 2-Chlorophenol U U U < 6.4 1 ug/L (95-57-8) 2A. 2,4-Dichlorophenol l El El < 5.3 I ug/L (120-83-2) 3A. 2,4-Dimethylphenol El El El < 15.0 I ug/L (105-67-9) 4A. 4,6-Dinitro-O-Cresol El El fl < 12.5 I ug/L (534-53-I) 1 5A. 2,4-Dinitrophenol El El El < 14.9 I ug/L (51-28-5) 6A. 2-Nitrophenol El El El < 7.7 1 ug/L (88-75-5) 7A. 4-Nitrophenol El El El < 10.2 I ug/L (100-02-7) 8A P-Chloro-M-Cresol El El El < 5.9 I ugfL (59-50-7) 1 1 1 1 9A Pentaehlorophenol El El El < 6.2 I ug/L (87-86-5)

IElA Phenol El l El < 5.I 1 ug/L (108-95-2)

I IA 2,4,5-Trichloro- l El El < 6.5 I ug/L Eohenol (88-06-112I).

IB. Acenaphthene U] 11 [ < 0.0 18 I ug/L (63-32-9)1 2B. Acenaphtylene El [1 [E < 0.017 I ug/L (208-96-8) 3B. Anthracene El - E E < 0.018 I ug/L (120-12-7) 4B. Benzidine [] [ ] < 7.3 1 ug/L (92-87-5)

VII-5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOOOO 159 Outfall No. D-C2R

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

1. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (I) Cone. (2) Mass (1) Cone. (2) Mass (I) Cone. (2) Mass 5B. Benzo (a) Anthracene (56- El El El <0.012 I ug/L 55-3) 6B. Benzo (a) Pyrene 11 El El < 0.021 I ug/L (50-32-8) 7B. 3,4-Benzo-fluor dthene El El El < 0.015 I ug/L (205-99-2) 8B. Benzo (gh! Perylene l El l < 0.0016 I ug/L (191-24-2) 9B. Benzo (k) Elwaranthr (207- 0l El El < 0.022 I ug/L 08-9) 1______ 1_____________ ___________

10B. Bis (.Ch/oereutx.n) El El El < 27.9 I ug/L Methane (111-91-1)

I I B. Bis (2-chloroethvl) El El E < 7.1 I ug/L Ether (I 11-44-4) 12B. Bis ý2-navpqt # El1 El El < 6.9 I ug/L Ether (102 1) 13B. Bis (2-Et ylhe. l) El E El < 7.6 I ug/L Phthalate (I 17-81I-7) 1 14B. 4-Bromophenyl El El El < 6.3 I ug/L Phenyl Ether (101-55-3) 15B Butyl Benzyl Phthalate El El El < 6.8 1 ug/L (84-68-7) 16B. 2-Chlobn-naphlttlene El El El < 7.6 I ug/L (91-58-7) 17B. 4-Chlorophenyl l El l < 5.9 1 ug/L Pheny* Ether (7005-72-3) 18B. Chrysene El El [E < 0.014 1 ug/L (218-01-91 19B. Dibenzo (a.h) l E El < 0.018 I ug/L Anthracene (53-70-3) 20B. 1,2-Dichlotbenzene El El El < 6.4 I ug/L (95-50-1) 21B. 1,3-Dichlorobezene E El E < 7.2 1 ug/L (541-73-1) 1 1 22B. 1,4-Dichlorobenzene El El El < 7.3 I ug/L (106-46-7) 23B. 3,3"Diehlorvberidine El El l < 6.5 I ug/L (92-94-1) 24B. Diethyl Phthalate El El El < 4.8 I ug/L (84-66-21 25B. Dimethyl Phthalate El El El < 6.1 I ug/L (131-11-3)1 1 26B. Di-N-Butyl Phthalate El El El < 3.9 I ug/L (84-74-2) 27B. 2,4-Dinitrotoluene El El El < 5.0 I ug/L (121-14-2) 1 1 28B. 2.6-Dinitrotoluene EL El [E < 6.1 I ug/L (606-20-2)

VII-6 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FLOO O 159 Outfall No. D-C2R

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

I. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Cone. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (1) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass (I) Cone. (2) Mass 29B. Di-N-Octyl Phthalate l El El < 8.5 I ug/L (117-84-0) 30B. 1,2-Dipheny1ythdazine 11 El 11 < 6.2 I ug/L (asAomwrcre) ( 122-66-7) 31B. Fluoranthene El El El < 0.011 I ug/L (206-44-0) 32B. Fluorene (86-73-7) El E3 El < 0.010 I ug/L 33B. Hexachlorobenzene Cl Cl C3 < 7.6 1 ug/L (118-74-1) 34B. Hexachlombutadiene C E El < 10.2 I ug/L (87-68-3) 35B. ,H,=fiu)dpn dm El El El < 12.1 ug/L (77-47-4) 36B. Hexachloroethane El El El < 6.7 I ugfL (67-72-1) 37B. Indeno (1.2.3-cd) l E1 El < 0.018 1 ug/L Pyrene (193-39-5) 38B. Isophorone El El El < 6.9 I ug/L (78-59-I) 39B. Naphthalene El El El < 0.014 I ug/L (91-20-3) 40B. Nitrobenzene El El El < 10.3 I ug/L (98-95-9) 41B N-NitnH ni r El El < 9.2 I ug/L (62-75-9) 42B. N-Nitrosodi-N- El El El < 8.9 I ug/L Propylamine (621-64-7) 43B. N-Nitro-sodiphenylamine El El El < 4.7 I ug/L (86-30-6) 44B Phenanthrene l El El < 0.015 1 ug/L (85-01-8) 45B. Pyrene (129-00-0) El El El < 0.0095 I ug/L 46B. 124-Tichlombraene El El El < 7.9 I ug/L (120-82-1)1 I P. Aldrin (309-00-2) El El 0 2P. -BHC (319-84-6) El El 0 3P -BHC (319-85-7) El El 0 4P. -BHC (58-89-9) El El [

5P. -BHC (319-86-8) El El 0 VfI-7 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-C2R

2. Mark "X" 3. Effuent 4. Units 5. Intake (optional)

t. Pollutant and CAS a. b. be- c. be- a. Maximum Daily Value b. Max. 30-day Value c. Long Term Avg. Value d. No. of a. Conc. b. Mass a. Long Term Avg. Value b. No. of No. (if available) testing lieved lieved (if available) (if available) Analyses Analyses required present absent (t) Conc. (2) Mass (I) Conc. (2) Mass (1) Conc. (2) Mass (I) Conc. (2) Mass 6P. Chlordane (57-74-9) E5 0l 0 7P. 4,4'-DDT (50-29-3) 0 1 0 8P. 4.4'-DDE (72-55-9) 01 1 0 9P. 4,4'-DDD (72-54-8) 01 0 09 tOP. Dieldrin (60-57-1) 01 0l 0 IIP. -Endosulfan 0 0l z (115-29-7) 12P. -Endosulfan 1 0 0 (115-29-7) 13P. Endosulfan Sulfate 0l 0] 0 (1031-07-8) 14P. Endrin (72-20-8) 0 0 0 15P. Endrin Aldehyde 0 0 0 (7421-92-4) 16P. Heptachlor 0 5 0 (76-44-8) 17P. Heptachlor Epoxide 01 0 (1024-57-3) 18P. PCB-1242 0 0 0 (53469-21-9) 19P. PCB-1254 11 0 0 (I 1097-69-1) 20P. PCB-1221 0 0 0 (II104-28-2) 21P. PCB-1232 0] 01 19 (11141-16-5) 22P. PCB-1248 0 0 0 (12672-29-6) 23P. PCB-1260 0l 01 E (11096-82-5) 24P. PCB-1016 0 0 0 (12674-11-2) 25P. Toxaphene 0 0 0 (8001-35-2)

VII-8 DER Form 62-620.910(5)2CS, Effective November 29, 1994

ATTACHMENT 2- OUTFALL LOCATIONS Crystal River Units 1, 2, & 3 NPDES Discharge Outfalls - FLOO001 59

= existing outfall/effluent sampling point

= proposed alternate outfall/effluent samplinq point D-00F (includes I-FG & I-FE)

POD D-072 D-094 D-011 D-071 D-012 D-C2R2 (proposed)

D-095 I D-092 D-091 D-093 I D-C2R D-OOH

ATTACHMENT 3- FLOW DIAGRAMS Crystal River Units 1, 2, & 3 NPDES Process Flow Diagram - FLOO001 59 FGD Treatment Pond Emergency Overflow (subject to bypass provisions in the event of discharge into ERP SWMS)

I ERP SWMS Discharge D-07 1 EFF-10A (494.64)

C D-011 C:

'I)

CU CL)

0) Coal Pile Runoff Basin EFF-10B (494 64) Emergency Overflow D-OOH Legend EFF-9 1 (Initermniei)

- Flowpath

< ............. Alternate Flowpath

<-- - - Proposed Alternate Flowpath Existing Sample Point 9

POD o Proposed Sample Point EFF-3D Notes:

Not to Scale

Doesnot include all storm water outfalls (Max. Flowrate, MGD)

Crystal Bay *Flows are maximum expected and can be significantly less based on operatingmode and equipmentin service

Crystal River Unit 3 Process Flow Diag ram Outfall D-095 Note - Diagramupdated to reflect CR3 SAFSTOR C ondition B.5.b. Pump Test I Treated Groundwater -7 1 IWW Perc.

Pond (alt.)

Clamtrol injection Note: Outfalls are listed in the ovals with associated sampling points in parentheses & Progress Energy

ATTACHMENT 4 WASTE WATER DESCRIPTION The following contains descriptions of the contributory wastewater streams and wastewater treatment employed at Crystal River Units 1, 2, & 3. Descriptions of chemical usage and chemicals that have the potential to be discharged via the permitted outfalls are provided in attachment 8.

D-011 and D-012 Once through cooling water The Crystal River Power Plant Unit 1 (D-01 1) and Unit 2 (D-012), utilize once through non-contact cooling water (OTCW) withdrawn from Crystal Bay via the Units 1, 2, 3, intake canal. With the announced retirement of Unit 3 on February 5, 2013, this unit will no longer discharge OTCW. It has not discharged OTCW since September 2009.

The water is circulated through the facilities and discharged back in to Crystal Bay via the Units 1, 2, & 3 main discharge canal. Special Condition I.C.1 1 allows for an on-line mechanical condenser cleaning systems, as well as use of oxidizing biocides, however, current practice is to take the Units 1 and 2 condensers out of service for manual cleaning.

o Method of flow measurement D-01 1, D-012 flows are calculated based on pump curves/flow testing and time of operation.

D-OOF Nuclear Services and Decay Heat Seawater System Even with the announced retirement of Unit 3, this system will be in operation for the foreseeable future. The Nuclear Services and Decay Heat Seawater system also referred to as the Raw Water (RW) system is comprised of two "sub-systems". One sub-system services the nuclear services closed cycle cooling water system heat exchangers, also referred to as the RW/SW system. The other sub-system services the decay heat closed cycle cooling system heat exchangers, also referred to as the RW/DC system.

This outfall consists of once through cooling water as well as discharges from internal processes as described in I-FE and I-FG. Progress Energy is also authorized to treat the process that supplies this discharge with a biocide. This biocide is known as Clamtrol (Spectrus CT1 300) which is injected into the system approximately every 21 days. The current permit requires chronic Whole Effluent Toxicity (WET) testing quarterly, with the option to reduce this frequency to semi-annually following four passing quarterly tests and review/approval by the Department.

o Method of flow measurement

D-00F flow is determined by pump design rating and pump logs that are maintained by the computer data logging system.

I

I-FE Laundry Shower and Sump Tanks (LSST)

This system, associated with the recently retired Unit 3, will be in operation for the foreseeable future due to continued operation of the spent fuel pool and other systems.

The LSSTs utilize cartridge and bag filters to control total suspended solids (TSS).

Additionally, this outfall can be directed to the ECST (rad-waste treatment system) for further treatment depending on radiological sample results. The treated wastewater is discharged by batch releases via an internal outfall (I-FE) to outfall D-O0F. The wastestreams treated in this system consist of the following:

Laundry Shower and Sump Tanks (LSSTs)

This wastewater includes miscellaneous low volume waste streams (per 40 CFR 423) including, but are not limited to:

laundry wash water

mop water

floor drain wastewater

laboratory wastewater from the primary laboratory, regent laboratory, and the annex laboratory.

leakage from auxiliary plant systems

wastewater from hydrolasing activities (past activity that may occur in the future).

o Method of flow measurement

I-FE flows are determined by flow instrumentation or tank level change.

I-FG

Station Drain Tank-1 (SDT-1)

The SDT-1 system (non-radwaste treatment system) will also remain in place for the foreseeable future. This system employs oil/water separation to control oil and grease (O&G) as well as mixing to aid in buffering pH. The treated wastewater is discharged by batch releases via an internal outfall through outfall D-O0F. CR3 also has the ability to route this discharge to the on-site industrial wastewater percolation pond under COC PA 77-09P (Att. H) either directly from the turbine building sump or from SDT-I.

The wastestreams treated in SDT-1 consist of the following:

Station Drain Tank (SDT-1) System This wastewater includes miscellaneous low volume waste streams (per 40 CFR 423) including, but are not limited to:

turbine building floor drains

turbine building sump

turbine building equipment drains

laboratory wastes from system evaluation

intermediate cooling system and water supply laboratory waste

water leakage from auxiliary plant systems 2

Station Drain Tank (SDT-1) System (cont.)

wastewater from hydrolasing activities (past activity that may occur in the future).

miscellaneous secondary-side system drainage/leak-off

generic equipment wash water o Method of flow measurement a I-FG flows are determined by flow instrumentation or tank level change.

Evaporator Condensate Storage Tanks (ECST) & Building Sumps The ECST system (rad-waste treatment system) utilizes an ion exchange system as pollution control. Spent resins are sluiced to a spent resin storage tank along with other spent resins (i.e., those used to polish water used for the spent fuel pool), whereby they are then disposed off-site. The treated sluice water is then discharged by batch releases via the ECST internal outfall through outfall D-00F. The treated wastewater is then discharged by batch releases via an internal outfall through outfall D-OOF.

ECST System:

A Miscellaneous Waste Storage Tank (MWST) receives low-volume wastestreams from a number of sources consisting mostly of sump and floor drains within the reactor and auxiliary buildings. Attachment 3 contains a diagram detailing inputs to the MWST. Please note that, per NRC regulations, wastewater from these internal CR3 outfalls are required to be monitored and meet limits for several radionuclides.

This wastewater includes miscellaneous low volume waste streams (per 40 CFR 423) including, but not limited to:

auxiliary building sump

auxiliary building floor drains

auxiliary building equipment drains

reactor building sump

miscellaneous primary-side system drainage

steam generator cleaning process wastewater

laundry shower and sump tank discharge (alternate flowpath) o Method of flow measurement 0 ECST flows are determined by flow instrumentation or tank level change.

D-091, D-092. D-093 and D-094 Screen Water Wash D-091, D-092, D-093 and D-094 are discharges produced when water from the intake canal (for outfalls D-091, D-092 and D-093) and discharge canal (for outfall D-094) are used to wash debris from the rotating traveling screens protecting the intake pumps at Units 1 and 2; the raw water pumps at Unit 3, and also the Helper Cooling Towers.

3

These outfalls discharge to the intake canal (for outfalls D-091, D-092) into the Unit 3 intake tunnel behind the bar racks (outfall D-093); and discharge canal (for outfall D-094).

D-071 and D-072 Helper Cooling Tower - Once through cooling water The Helper Cooling Towers (HCTs) withdraw water directly from the site discharge canal for additional cooling. The once through cooling water is then directed back to the discharge canal through outfalls D-071 and D-072. In addition, the HCTs are permitted to inject an oxidizing biocide to control biofouling although this treatment system is currently not in service.

o Method of flow measurement D-071 and D-072 flows are measured using pump times and design flows.

D-OOH Coal Pile Runoff Runoff from the coal pile is captured in a collection ditch and pond system. This system has a single valved outfall. This outfall can be allowed to discharge to a marshy area south of the coal pile storage area. The valve that serves this outfall is kept in the closed position, and only opened manually during emergency conditions to protect berm integrity. Discharge can also be accomplished with the use of portable pumps.

This discharge has not been used due to the adequacy of the overall capacity and percolation capability of the pond system; however the outfall should be maintained for future emergency use if needed.

o Method of flow measurement

In the event the outfall valve was to be opened during emergency conditions allowing a discharge, flow would be estimated based on discharge pipe size and duration of discharge or determined by pump capacity and pump run time should portable pumps be used.

D-C2R Plant Waste Water Pond System Wastewater discharged via this outfall would be the result of emergency discharge from the Units 1, 2, and 3 Industrial Wastewater (IWW) evaporation/percolation pond system.

This system receives various low volume wastes from Units 1, 2 & 3 including the discharge from Units 1 & 2 domestic wastewater treatment plant and Treated FGD blowdown from Units 4 & 5. These discharges are monitored in accordance with COC PA 77-09P (Att. H). This outfall is currently permitted to discharge to the site intake canal.

4

o Method of flow measurement Discharges via D-C2R can only be accomplished with the use of portable pumps. Flows are determined by pump capacity and run time.

D-095 - B.5.b. Backup Pump Test Discharge Per Nuclear Regulatory Commission (NRC) guidance, the CR3 facility is required to maintain a backup, independently-powered, portable water supply pump to provide an emergency source of water for various activities such as fire-fighting, containment spray, flooding the Spent Fuel Pool, etc. The directive also mandates that the pump be tested periodically. During testing events, which are required once every 2 months, the pump will be operated for approximately 30 minutes at 300 gpm producing a discharge of approximately 9,000 gallons of service water (treated groundwater), with an annual test using intake canal water (seawater). Water is discharged back into the intake canal within the vicinity of the CR3 intake structure.

Various Potential Miscellaneous Discharges

Treated Groundwater At Crystal River, all groundwater is treated to drinking water standards by lime softening or microfiltration/R.O. processes. This water is then chlorinated and used as potable and/or service water. The service water typically enters the surface water, or is discharged to the ground, by incidental leak offs, bar rack cleaning, pump bearing seals, fugitive dust suppression, and various other flushing/draining activities, including, but not limited to, releases during piping repair, replacement or abandonment; flushing of lines for testing/maintenance; pump priming activities; flushing of heat exchangers; and from pressure relief valves. At Crystal River Units 1, 2, and 3, the estimated release from continuous sources is approximately 118 GPM with an additional 23 GPM from non-continuous sources. This treated water enters the intake and/or discharge canal at various locations which includes storm drains, the facilities' intake structures, and at the Helper Cooling Tower intake structures. A small but undetermined amount of service water may be discharged during routine plant operations. Additionally, treated water may be used in an emergency in place of screen wash water and for fire-fighting training activities or from other fire suppression systems. The treated water would be used if the screen wash pumps failed or were unable to keep up with traveling screen fouling as may be caused by excessive influx of sea grass. At times, untreated groundwater is used for the processes listed above and has the potential to be discharged in lieu of treated groundwater.

" AC Condensate At times, uncontaminated condensate from the outside of various HVAC, air handling or other heat exchange systems, has the potential to be discharged via the various storm water outfalls.

5

. Coal Coal may be discharged to the intake canal in the course of barge unloading operations or incidental spillage from the coal conveyor system. These releases are minimized through the use of Best Management Practices. Coal is recovered from the canal on a periodic basis.

Pesticide/Herbicide Use Pesticides/herbicides are used at various locations around the plant site. These products are applied by licensed applicators to reduce insect infestations around buildings and to control vegetation. These products are applied away from locations where aquatic contact is probable. The exception is herbicide application along the intake/discharge canals where licensed applicators apply FIFRA-approved herbicides due to requirements of the Marine Transportation Safety Act (MTSA), which requires that vegetation be controlled at these areas to enhance surveillance activities.

" Miscellaneous Discharges Various containment structures and electrical manholes/vaults are drained of storm water from time to time via one of the permitted outfalls. Before such water is drained, it is inspected for oil sheen and/or excessive turbidity/color and only allowed to be drained if no unusual conditions are noted.

" Unit 3 Activities It is unknown at this time the exact types and volumes of discharges that may be associated with Crystal River Unit 3 SAFSTOR activities. We anticipate that most will be via existing permitted outfalls - I-FE, I-FG or the ECST. It is possible that small amounts of drain water, involving either seawater or treated groundwater, may be discharged via the old condenser discharge outfall (D-01 3). These are expected to be minimal and of short duration.

6

ATTACHMENT 5 Form 2CS - Section IV.D.

1. Power generating facilities are interconnected to the electrical grid, and, therefore have a reliable backup power supply. In addition, CR3 maintains backup emergency diesel generators as part of NRC requirements relative to redundant backup power supply. However, in the unlikely event of complete power loss, several discharge outfalls, such as condenser discharges, etc., would cease since these discharges are dependent on electric-powered water supply pumps.

In the event of loss of essential pollution control equipment, the discharges would be stopped pending return to service.

Form 2CS - Section VI - Improvements

1. Administrative Order (A.O. -024-TL) issued during the last permit renewal requires the Permittee to submit a feasibility study report (Report) for engineering options to meet the marine water impingement mortality reduction requirements of the final regulations for 316(b).

2. Permit Section VI.1 requires continued implementation of a Best Management Practices Pollution Prevention Plan (BMP3). CR123 continues to maintain the plan and provide updates to the plan as needed.

Form 2CS - Section VII - Intake and Effluent Characteristics - Clarification

1. Given the lack of historic discharge from D-OOH - South Coal Pile Runoff Basin, which is designed to contain a 10-yr, 24-hr. rainfall event and has rarely ever discharged, we collected grab samples from the perimeter ditch/pond system directly in front of the outfall location, and hence, these samples likely represent worst-case conditions should this outfall discharge.

2. During the weeks immediately following Tropical Storm Debby in late June 2012, D-C2R experienced a discharge lasting approximately nine (9) days. During that time, samples for certain parameters were collected pursuant to existing NPDES permit condition. These results are summarized as a supplement to this attachment. These results are also provided in Form 2CS for the sampled parameters. However, since this outfall historically does not discharge, remaining Form 2CS parameters were collected within the percolation pond in the vicinity of D-C2R. These sample results also likely reflect the worst-case conditions should this outfall discharge in the future.

I

3. In order to more accurately characterize discharges entering Crystal Bay from the site discharge canal, sampling was performed at the Point of Discharge (POD) located at the end of the canal. The sampling point is delineated in the existing NPDES permit as EFF-3D. A complete suite of Form 2CS parameters,Section VII, Parts A, B, and C (exclusive of pesticides) is provided, as are intake sample results.

Miscellaneous Additional Clarification to Form 2CS Application Many of these issues were discussed in a pre-application meeting and subsequent conversations with the Department:

For those parameters for which routine DMR data is collected, we summarized data from October 2010 through December 2012 for inclusion in applicable Form 2CS parts for that outfall.

Results below the Method Detection Limit (MDL) are reported as "less-than" (<)

the MDL. Results between the MDL and the Practical Quantitation Limit (PQL) are reported and provided with an 1"" code.

Twenty four-hour composite samples were collected for Outfalls D-01 1, D-012, D-OOF, the Intake Canal, and at the POD. This applied to all analyses that require a composite sample except for low-level mercury and those parameters for which composite samples are not allowed (i.e. field parameters, oil & grease, etc.). Per the Department's instructions, we performed low-level mercury sampling and analysis on a single grab sample. Mercury results on the forms are provided in micrograms per liter (pg/L).

Form 2CS states that single grab samples would be acceptable for those outfalls taken from holding ponds or impoundments with a retention time of greater than 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months . At Crystal River Unit 3, there are a number of internal outfalls that discharge via "batch" releases from tanks. These include the SDT-1, LSSTs, and ECST system releases. Given that these tanks have the ability to have retention times of greater than 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months (i.e. only one tank release occurs within a 24-hour period), we believe that single grab samples accurately characterize the discharges from these tanks, and hence, would be representative of the discharge. Current NPDES permit requirements reflect these batch releases in that single grab samples are required for NPDES compliance sampling purposes.

" Form 2CS,Section VII instructions requires sampling of all non-storm water outfalls for all parameters in Parts A and B. However, for Part C parameters, it appears that all "non-process wastewater outfalls" only require analyses of Part C parameters through total phenols (i.e. excludes requiring to analyze for dioxin, GC/MS-Volatiles, GC/MS Acid Compounds, and GC/MS Base-Neutral Compounds).

2

Per previous discussions with the Department, we believe, and the Department concurs, that non-contact cooling water would be considered a non-process wastewater. Accordingly, we sampled and analyzed for those parameters on Parts A and B and Part C through total phenols for Outfalls D-011, and D-012.

For all other outfalls, including D-001, I-FE, I-FG, ECST, D-00H, D-C2R and the intake and POD, we analyzed for the complete Part C list (exclusive of pesticides) in addition to all Part A and B parameters.

" Samples were not collected for the Part C, GC/MS Volatile compound 4v. - Bis (Chloromethly) Ether. There are few, if any, labs that are certified to perform this analysis. Per USEPA Document EPA-600/S4-81-062 relative to performing analysis of haloethers in industrial and municipal wastewaters, this particular haloether was dropped from the study due to its extreme volatility and hydrolytic instability.

Sampling was not performed on Outfalls D-071 and D-072 - the helper cooling tower discharges, since these have been off-line since early fall and only run seasonally. Sampling of these outfalls will be performed once the towers become operational with results forwarded to the Department as an addendum to this application.

" As with the previous permit renewal sampling involving CR3, NRC guidance allows samples collected from the CR3 internal outfalls (I-FE, I-FG, and ECST system discharges) to be analyzed only by laboratories that have a valid Radioactive Material License (RML). Consequently, arrangements were again made with GEL Laboratories, LLC, in Charleston, SC, to perform these analyses.

GEL has both a radioactive material license and is NELAC certified in Florida for the analyses required to be performed. However, due to the distance, results for those parameters with short holding times would not be valid. Consequently, during the last permit renewal, the Department waived the sampling requirements for these short holding time parameters.

" During recent sampling of the CR3 internal outfalls, the I-FG (SDT-1) samples for semi-volatile parameters, and the VOC 2-Chloroethylvinyl ether for I-FG and I-FE (LSST)I, were broken in transit. Sampling has been rescheduled and results will be forwarded to the Department at a later date as an addendum to this application. Difficulties were also encountered with the low-level mercury, copper, and/or sulfide samples from outfalls I-FE (SDT-1) and/or I-FG (LSST).

Re-sample results will also be included as a later addendum. Finally, due to the infrequent operation of the B.5.b. pump (outfall D-095), sample collection was delayed such that results will also be included in a later addendum.

" The contract lab performing analyses for the Units 1 & 2 outfalls, including intake and POD samples inadvertently failed to conduct analyses for gross beta on the intake and POD samples. Additional samples will be collected with results forwarded in the later addendum.

" Stormwater outfalls D-100 - D-600 are now covered under a separate MSGP.

3

Reauested Reissued Permit Chanaes Progress Energy requests the following changes and clarifications be made to the reissued NPDES permit. Details regarding existing and/or new chemical usage are provided in Attachment 7.

Announced Retirement of Crystal River Unit 3: On February 5, 2013, the Company announced the retirement of Crystal River Unit 3 (CR3). This Unit had been off-line since September 2009. As a result of the announcement, two (2) outfalls are no longer expected to discharge. These are D-01 3 - the CR3 condenser cooling water discharge, and the CD (condensate) system. However, all of the remaining existing CR3 NPDES outfalls, including D-OOF, I-FG, I-FE, the ECST, D-093 (intake screen wash water), and D-095 (the backup emergency pump test discharge), are expected to discharge for the foreseeable future.

Application of Water Quality-Based Effluent Limits (WQBELs): As stated in the previous permit renewal application, the main discharge canal is a discrete conveyance (point source) and therefore any applicable WQBELs should apply downstream of the final existing permitted outfall point (D-072).

D-C2R backup outfall point: Currently, Outfall D-C2R - Emergency IWW percolation pond discharge, is permitted to discharge to the site intake canal. This was due to the anticipated construction of the Helper Cooling Tower South (HCTS) associated with the CR3 power uprate. Given the CR3 retirement announcement, the HCTS will not be constructed. Therefore, we request that D-C2R have an alternate discharge point to the site discharge canal in the vicinity of the original D-0C2 outfall.

4

- Supplemental No. 1 Form 2CS,Section X., Contract Analysis Information Name Address Telephone Pollutants Analyzed (list)

Pace Analytical 8 East Tower Circle, (386) 672 5668 All parameters Services, Inc. Ormond Beach, FL 32174 (excluding fecal (Ormond Beach, FL) coliform, LL Hg, and FL DOH No E83079 Rads.)

Pace Analytical 1209 Tech Blvd., Suite (813) 627-0003 Fecal coliform.

Services, Inc. 207, Tampa, FL 33619 (Tampa, FL)

FL DOH No. E84973 Pace Analytical 1638 Roseytown Road, (724) 850-5600 Gross Alpha, Gross Services, Inc. Suite 2-3-4 Beta, Total Radium (Pittsburgh, PA) Greensburg, PA 15601 and Radium 226 FL DOH No. E87683 Pace Analytical 1241 Bellevue Street, (920) 469-2436 Low-level Hg Services, Inc. Suite 9 (Green Bay, WI) Green Bay, WI 54302 FL DOH No. E87948 GEL Laboratories, P.O. Box 30172 (843) 556-8171 All for CR3 internal LLC Charleston, SC 29417 outfalls (I-FE, I-FG, FL DOH No. E87156 ECST, and outfall D-095).

2Progress Energy Robby A. Odom Plant Manager, Crystal Rive r, Fossil Plant.& Fuel Operations September' 13,.2012 Submitted via.erfmail: to:

SRachel: McGraw~i*del.State. fl~us Foidad Departmenti.. f bnvirbhmental Pr0tectib~r Southwest,Di strict"Office...

IndUstrialV stewate-13051.N eeo~ bka

.Temrple Terftace. FL.33637.

DejlR Ms. M6Graw.

Re: ProgresS Energy Florida Crystal River Uriiisl,i2:

Permit 10i N PD.ES:CýFL000019-1 IWfIS;

.R.e-sUbrmittal of D,MR Part"Afor Outfall D*C21R

As. stated in.;the coyer l.etter 'associated with transmittal othe fJuly,, 2012 DMRs for the subject permit,.

enclosed is ýai, re-,submitted :copy.<of DMR.Part:.A for Qutfall D2.C2R. Also. enclosed is a supplemental documenht With attacrlnenhts exilaining exceedences associated with-discharges from this outfall. 'As

.previously rePoed to~o*~.~ Department" discharge from.,this'outfall was a: direct cnsequence.of Tropical Storm"Debby~ du.ring.which, the site had one event that exceeded the.25-yr,.24-hr rainfallitotal.

if you should have any qcuestions concerning.this Ifformation, p!ease .ohtact.Erika TuchbaumBiriof:my*,

,staff at (352) 464-7,909 or Doug Yowell at.(727): 820-5228.

obyA.Mldor Pl.t Mnager, Crystal .River Fossil Plant & Fuel Ofperatiohs-Eticlsures.

2Progress Energy cc:: Pat Garner -:PEF-903 File: 1252013 Effective with DMR's:sub.mitted in May 2012, submilialis are .nade via email of scanned documents to the SW District only.. Submittals are made toethe ftacility inspector.

FDEP Facility .nspector:.

Rachel McGraw Rachel. Mle(c rawgzis, .deitatde.fui.v

ý(813) 632-7600, extension,334.

Template for Stbjeit Line:

OmR :Sub mittalfor.montdhyegr: NPDES FL000011, 56ý0O.1 sW Teinpffte. !r emaill' s-qage:..

Raehei..

Attached is the MIonIl,.Year NPDYFS:*k.submittal for Cr.ystal River SoUth6. N.DES:t FLiOOO(00 59O001-IVIS".;

I woldd appreciatewa reply email to acqknowiedgereceipt.

Th'iank 'you.

2 ,Proress Eeg

,September 7,2012,.

SSubjeCt~ ~Supplement to Discharge:Monitoring Report for July, 2012 "PDES, Permit No, FL0000t59" Progress.Energy Florida, Inc.: (PEF) - Crystal(River Units 1, 2,& 3:

Dischr.ges from Outfall D-C2R On July20. 2012, PýF submitted, via e-mail notice to the Departmentipursuaht t6 SectiOn.X., 'General Condition 17 of the subject permit thatwe: had anticipated exceedence of certain permit limits involving potential discharges 6from Outfall DI-C2.R as

a. result of Tropical. Sto-.m(T.S.). Debby. T.his was preceded by other e-mails ahd conversations, s. as we'llas post-event conversations with. the De partment. The followingý contains asummary.of thoses discharges.and the events leading up to them. In addition,.

Department staff vi6ewed the discharge. occurring during a routine,,annual NPDES

,inspection on July 24,:2012.:

'iBackgrodund:

Beginning on June.21i,2012, the Crystal RiverEnergy Complex (CREC) began to experience the effecis of Tropical Storm Delbiby (TS Debby). During.the TS (from approximately. June, 21 through. June 28), the site received. approximately 2.2.5rinches of rainfall with aPpproximately ,9in'ches .fallingiduring a single 24 hour2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months time period ending on June :25. this latter event exceede6d the 25-yeair, 24-hr rainfall event totalffor the site, This was.followed by.a num'ber of rainfall events from July 10 through July:.31. During that 3-week period, 'the site' received an additional 13.5,inches of rainfall.

On June*25, 201. 1the Goerno rsigned Executive Orde6rNo,12-140, and a second".

.amended, order onJulyl 25, 201.2,, which.extended the first order for .aother 30 da'.ys in several counties, inclfuiing Citrus.County. Therefore, all discharges from D-C2R.

occurred within the:time frames of the initialand a .mended. orders.

D-C2 D:Dischairge. Details:

On July, 20, 2012, ýat approximately 6:30'pm, disckarge frorn D-C2R cinmmenced from' IWW pond,"no. 4. As you, know, this outfall is an emergency discharge point frri the Crystal River Units .1,2, & 3 Industrial Wastewater (IWW) pond' system. This outfall.

discharges to the sitei intake canali and replaces .Outfall.D-0C2, which, formerly disicharged to the site: discharge canarIl. The-discharge wasý performed: utilizing two, (2) 2,000 gpm pumps'that pumped Wate rfro0m: IW'Wpond nor 4 into`the: site intake canal.

IElevation in pond,.4at the start of pumping was 17.68 ft:NGVD. Seeattachment 1 for flow summary*.

Pumping continued more or less continuously (except for brief intervals for pump. re-,

fueling/maintenance): until 6:00 am on July 29, 2012.when the elevation of pond;#4 reached-approximately 8.00 ft. NGVD. During this time, a total of 47.64 million gallons

'was discharged via OutfallD-C2R. Maximum daily flow was,5.76 mgd, while the monthlykaverage daily flow was. 1.54 mgd (calculated by taking total flow and averaging.

over 31 days in the month as described. in FDEP instructions. relative to reporting.flow data: on DMRs).

TheNPDES permit requirement for this. outfall, is :to collect total suspended solids .(TSS),

3/veek: Oil &.Grease .(O&G) 1/week; and.the remaining parameters (mostly metals)o 1imonth. These. results are: summarized in Part Akof the Discharge Monitoring Repbrt

.(DMR)...

In conjunction With this..sampling, PEF also performed sampling: for these same..

parameters in the intakecanal upstream of'the:D-C2R discharge, and in the 'site discharge canal at the POD prior to entry into the Gulf of Mexico. These, results ,areý

/provided as&an attachment to* this supplemental report with comparison to theClass :lll iMarine WQBELs. This sampling was Conducted onJuly 23bto allow for t1eoreticaltravel timethrugh'the, system: such, thatte samples woulddODreflect discharges* from. D-.

There werefourparameters-that exceeded.permit limits: monthly average for TS;.:and daily maximum for cadmium, copper,.and nickel. With respect to the monthly.TSS, this, value was influenced by:;a single'high resiult obtained near the end of the discharge, We, suspect that, as the pond. was, lowered to:the target elevation, this sample reflected

,entrainment of solidsfrom the, pondbottom.

Reg'arding there mhaininrg exceede"nces, as discussed with the bepartmeint 'prirto commencing discharge',it Was ýagreed' to collect saimples from' the finalpointof

discharge (PQD),within the main, n site'dis'charge canal priorwt ent)ring the Gulf. As stated above, this sampling Was performed approximiately ,3 days after dischairgefrom D-C2R commenced such that the POD discharge would reflect discharges ftrm D-C2R.

All of these results, including those, for,cadmium, 'o'pPerand nickel, were:;below the Class Iil Marine Water Quality Limits.

Summary:

Given that the discharge from D-C2R.was a result of T... Debby, during which) and after, th~e site received extensive rainfall,: including a.single.24 hour2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months period duringwhich

.9.01tinches .of rainfal1l wa.s recorded.atthe site (for"Crystal RiveR , this exceeded the 25-yr, 24-4h*rrainfalleve nt total of* 860 inches),,we beliiev **this qualifiesas anupset ipursuant to Sýection.iX, General.Condition:23::of the subject NPDES. permit. Additionally,,

these discharges from D-C2R occurred within: time frames of the Govern*s:onrsginal and

,:extended emergency orders issued as a result of the tropical stotm.

Attachment 1 NPDES* Permit No. FL0001059 D-.C2.R D1ischarge - July 2012.

FlowSummary*

Hr*.e*ters PumOp.1 (102) Pump2 (051)

IWW Pond #4 Elciý.-

5t a rt/Check .ThIeo ,Reading Diff Reading (ft..NGVD) 7/.20/2012: 6:30 PM :.6 893 1,875 1.7.86 "7/21/2012.Z .. ,6;906 1,*888:

9:00 AM 7if.:

13:

7/22/012, 4:00 PM 7 1,895 7.

7:00.AM 6,929 1,909 4:00,PM 6,937 7"

,7/23/=2o0 7:0,0 AM 6,9.52 1,932o

3:30PM. 6,958 ,1,937' 7/24i/212 ?:OOAM 6,976 3:00 PM 6,984 1,965.

7:00"AM 7,00 0. **7. 1,979 3:30 PM 7,007 78, 1,987 7'/26/i2di2' 7:00. AM: 7,023.

3:00 P.M 7,031 2,011 15 "7:00,AM 7/27/201.2 7,047: 2,026; 3:00PM 16* .2,035 7,055

,7/24/2012. 8:00 AM 7,0721. >2,OS 1 2t6!

3:00,PM 2 057 8.00 7/9/2012., 7:00'AM '7,093' :2,072 19.7

total hrs

2.00 8

=8 total (dakys)

~urnpzcapac. gpm each 6~0 totallflow per. p0mp= 23,640,000

.. Z, iotal1 flow (gal)Y 47,640,000.

total flow (Mg) 47.64 avg. daily flow overentire m.onth = .mrgd'monthly.avg. daily flow',

m:maxx daily flow (mgd) = 3.7 60. mgd

DEPARTMENT OFVENViRONMENTAL PROTECTiON DISCHARGE MONITORING REPORT - PART A When Completed iiiil::thisreport to; Departmentot' fvironhicnital Protection.Waste'water Compliance Evaluation Section. MS 355.1 '26008ai:rStonc Road. Tallahassee, FL 3239,9-2400 PERMrrr[EE. NAMf-.: Progrcss Etergy. Frlrida (PEF) "PERMtrNUMB3ER: *FL,0000159-013-IW.l 5:,

MAILING ADDRESS:. :15760 Power LinerStreet Crystal RAicr,***rida 34428-6708. -LIMiT; REPORT FREQUENCY: Monthly CL.Ss SIZE: MA PROGRAM: Industrial FACILITY: Crystal RivrU.nits; 12 & 3 MONITORING GROUP NUMBER: D-C2R

'LOCATI'ON: 15760 W Power.Line St.: MONITORING GROUP DESCRIPTIONI: Industrial Wasteic6nOdisystem.4 itewaler (Unit I and 2 combined) (formerly D-UC2y..

Crystal Riyeir Fl6rida 34428-6701 MRE.$U3mirFTED DMR:

OFuNFnC; Citr-*w' NO.DISCHARGE FROM SIrE:

JMION.*T1R.1NG PERIOD ED From: o7/0i12012 0To:

7/31U2012

.OFFICE:

Soutfwest~D istrict.

___________" ___ ____"____ _________ " _______ _______ F.________ . ...... ....

S 1..4..... ....

. Ex. . ./,alysis _________

Pnnetl att o oai6ý nm6 , "r ,, ,. " *"'*

units 'Nn c':of., Sapl

_________.. Measurerimen _______ _______ M - ________..,__ discharging _______

PARM:CoW 05 I- .0 Pcrmi,. , * .port, . 7>.'"ort- . .W .\ wDhin4i -Calculateid imon.-Site Wo.TVWZ R~equirement, M~v: ~ ~ x. - --- ~. discharging Ga Oil and Grease Sample .. ; : <1.2 .',2 . 0. Weekl'whcn Grab Measur~ement .,..1 . .. .. i-.,dischariging P AR M. Cod e .005 5 6 , . .' . .. ** v : 50 ,g 5 /L - .Gr. .

w Mont SiteNo. E"F6. ReqtSiire i.em._..,___. _____"___" .... " = ' "(Mo.Avg.) ., ay MLt.): ,_,__ dischairing Solids. Total Suwpend SamIe ***** **** 342 ... .... 3/Week. when Griab McAasuremem ... ..

__"_"_'"_... discharein _

........ .. t" 30 .0 00.0..

1 W e....ek,%hen 'Ga.b--

Mon: SiteNo. EFE-6 Req.urement "M&.. 0 MonthlyA&c whaarn . "

Arsenic. Total cvýoyerable Sample .o 2 2".. 0 Monthly. whenr Grab

_Measurement : * . discharging VAR C,ýode 009,78" 1 Permit - ' *.**** 36101.1 36,0-- Mo ,tWhly;;wbeit Grab Mon..Site No.EFF6 E" . . .Reqire t: *" " """s:aigiitg (MoAyg)*:

Cadmiuni[. Total. Reeo,.rale Sampk 65 65 . 2 M0ti,-len Grab Measuri-ment l dischariin _

a M co.** "".."r'*: " ,mit "'.Grab Mon. Site No..EFl*-6s - Requirement."

.. "_"_: " _ M u vg. (fa.Ml .ax.).-.

.dia go..

Chromitirnr-tal Recoeratble Samp le, ***? -'.c4 <;4 0 Monthly,:when I Grab Measureimcntt._ _,_., .... *... ...... discharging

ýA -M: cP,,,i:i.s"... . ... . . -50.0 91 Monthly.,,f,.,, Grab EF,-6 RC4U i men t .M.6...Sitc," (Mo:Av),.: (Day.Max.) discharging

1ccrti:lddor Nndit I w.** tkat4this, docuinti, anid all attachments were prepared .uldr i t1 dxir' tiisn or superv-ision in accoidance with a system designed to assure that qualified persnanel properly gather and evaluate tie iiformnation slbiitted. Based on my iinjtiryofihe s eeu. nanage t~hes ntm. or those r ecl t b fo ibnnlt he infornation the infonration submitted is. t the best ofity lo*twledge and bieif trie. aceurate. and complete. I am avare -that there. are signiltiran incttsdlg the possibi,*

Inrealties lor subnlining.f6:C faleM ia.tb tri.' ioiy file and. anj pnsoie.ntentfoqrknc.W g *iolations; h~AR~1TE PINIPLO EFCtIFOFICR R IJHQRIZD'Gt Robby AXOdom. SWtai6n.Manager COMMENT AND EXPIANATN*OFANIY' SeeiSupplemenuil Aftadmeln nts

.u'..

. tirzt, 14'4ý 91_41n 01A, In, C&T-4". ý1--

DISCHARGE MONITORINGýREOpLORT - PART A"(Continued)

FACI-rY, rogess~tcrga Florida -Ctstisra1River Tlnizs 1,2.& 3 MONITORING GROU.*P *DZ2R. PERMIT NUMBER: FL0000159-013'-IWIS.

'NUr1ORN

)AONITORINGAPERIQO~ From: 07/01/2012 To: 07131/2012

.....am tr .. ... . ." QuantiVt or1o iioino MUits.

i:Qca litl:iiConc tian Units :No. Frequency of Sample Type

..................... . _EE..

x.... An aly sis Cop..ot17al Recoverable

Siplc . 12 12 2 'Monthly. when Grab

.... Measurement " . '__ "_ ._" .... _____ discharain _

PARM"Code01 t19 .P"" <."." 1 , : ' 3 . Monthly. when Grab Mon- Site No. EFF*6 . Requiremen. (M6.Avy *.") (Day.Ma.v) discharging __. __.. __..,_,

.ead- Total Recoverable. Sample 2 2 0 Monthly,: when Grab measurenint, _______

vtp~Axod Mdn. Site No EFFý.6 0.1114 1 Permit Requiremen *:.*t

$4*~

... ' '*":: *" *" `:'*i ': ., :(MO'Av: 5*~'

6"Vg.) 8.51

" .": (Day.Max.)".*.. ugILiv .. -diachain discharging ~Grab iron. Tonl Recoverable Samnple.. 0.02, 0.02 0 MonthlyN ihen Grab Mca'surerrnhtdseaalg PARM Code 009.8.0 1. Permit .. ..... 0.3 Mdischarging.

ngL G Mon..Site No. EFF-6 :... .... Rcq.

r... _*_"." Avg;) (Da*(% . .ax.). discharging, Mrctur.-. Total Rcco'.'crabl" Sample *** 0.013 0,613 0 Monthly,.when Grab Measurenwrir _ _ discharing.

PARM_"_Code _ __ 71901>_ t.2 _ I "__

_ .....PMilrmihen permi:, __........... '_______._,. ** .. . o*A *': ___::*( ,,

0025 * <MaxS,:.:: ,>!*dischargina _ _ _ _

Grab _

Mon. Site No.. EF.FW 6 R. uireme.t _ ... ... " . .A.. "

Nickel. otal Reioerablc Saipl& **** . ..... ***. .200. 200 2 Monthly: when Grab

.Measurm n . .......... .... . .. 8n ...discharging, PARPMdm074 i . .3 . .83 M.onthlvwhen '. Grab.

Mon. SiteNo- EFF6-6K R iuirementr. (M Av)

_______ _____- diS:1Wchatifls Selenium. Total Rewkovrable klt< asur :min Saimple *"***.

, "*- I1 0 dsc agn Month~lywhen Grab.

PARM.Code.98I Permi..t 71 .,71 isehar'in' Gab" M, ,Site ,W "EFF.6 Requiremient _ _ _ _ _ ... ___." " .MU..) (MoAvg) (Dv discharging, .

pH " Sample " : " ***. 81 . : . , 8.1 :0 'Monthly. when "In-situ

-. .... .. ,Measurem.nt ...... "__. .________ _ _ _ _ . su. discharlging PAR*M Code 0400 7 ic*il' . . R... Report IM.n, ily ,h.en . .n.situ Mon. Si;ieq i " Requiremet' ° (Day.M.. (Day.Max) Y_."_ dischargiJi .. ".. ..*,.....

pH Sample**** ****, 75 7** 7.9 0 Monthlv whmn In-shit

Mea~i~mrerntfni.

" .:3 ... .**. ______....__.. . .discharging.

6 Se.rmit 5:. " MonthilyWhen :. :Insijtu .

Mon. Si No.,EIF-6 te ,Requirceint .. .... . .....

.... ... discharging.

Zinc. Total Recoverable Sample2 141*** . ***** 3 3 0 Montily. when Grab

..... Fs'. .- --

-Of..... t Me.suremen.

i--.. 86 ug/L "" discharging

... :....I.Per it.86.t....86 .8. Monthly,'when

Grab Mon. Site No. EFF-. " Requifemcnt . (Mo.AvLL.) (Day.Max.) . ischa'"g" . .

... . *=..=.... =* * ; . .,.:: :i: ::,:, =. . .... : ,ii * *,:*.*.. .. .. :" "

P*e2of 2

Attachment 6

Request to Continue 316(a) Variance

316(b) Information

Progress Energy offers the following information regarding continuance of the 316(a) variance:

1. Studies completed in 1985 led to the conclusion that thermal discharges from the operation of Units 1, 2, & 3 were having an impact involving seagrass in the vicinity of the discharge into Crystal Bay. The permittee proposed installation of helper cooling towers which would return the discharge temperatures to approximate levels that existed prior to the operation of Unit 3.

2. EPA/FDEP accepted the proposal and granted the permittee a Section 316(a) variance which permitted the use of the helper cooling towers to limit the impacts to pre-Unit 3 levels and imposed a temperature limit of 96.5 0 F expressed as a 3-hour rolling average. To meet these levels, Units 1 & 2 may be to de-rated at certain times, particularly when intake temperatures are high. A predictive model is employed to ensure compliance with the thermal limit.

3. The concept of a multi-species marine hatchery to mitigate fisheries impacts in Crystal Bay was developed as an innovative, cost-effective alternative to conventional engineering solutions to address Sections 316(a) and (b) of the Clean Water Act (CWA). The Crystal River Mariculture Center became part of the negotiated settlement and will remain operational as part of the existing 316(a) variance demonstration.

4. Administrative Order AO-024-TL that accompanied the reissued NPDES permit in March, 2012, required the submittal of a thermal Plan of Study (POS). The POS was subsequently submitted to the Department. It is anticipated that a revised POS may be required to reflect retirement of Crystal River Unit 3.

5. There are no immediate planned changes to Crystal River Units 1 and 2 that will significantly change the plant operating conditions or load. However, due to the announced retirement of Unit 3, there will no longer be condenser cooling water discharge associated with approximately 890 MW of generation, effectively cutting the amount of heated discharge water by one-half.

6. Current plans are for the new Levy County Nuclear Plant (LNP) cooling tower blowdown to discharge into the Crystal River Units 1, 2 & 3 discharge canal. However, the LNP discharge will not occur until potentially year 2022 and therefore, will not impact the existing Unit 1, 2, & 3 discharge canal temperatures during the life of the reissued NPDES permit.

Based on the above information, we believe the size of the thermal plume will not increase beyond existing conditions and therefore, that the thermal variance be continued. In fact, due to the retirement of Crystal River Unit 3, the thermal plume is expected to be greatly reduced to pre-Unit 3 levels.

316(b) Information In accordance with Section 316(b) of the Clean Water Act and Rule 62-620.100(3)(z) F.A.C.,

compliance with the rules relative to cooling water intake structures are determined on a case-by-case best professional judgment (BPJ) basis pending issuance of the final 316(b) rule expected June 27, 2013.

Due to the retirement of Crystal River Unit 3, intake flows used to support condenser cooling (approximately 979.2 mgd), will no longer be required, thus reducing the amount of intake flow of Units 1, 2, & 3 combined by roughly one-half. The only intake flow involving CR3 that will continue is approximately 43.5 mgd used for the spent fuel pool heat decay system. For the foreseeable future, Units 1 and 2 will continue to operate at their current designed intake flow rates of approximately 918.7 mgd (combined).

Attachment 7 Chemical Usage/Discharge Below are descriptions of chemicals used at CR123 that have the potential to be discharged via one of the NPDES-permitted outfalls. Material Safety Data Sheets (MSDSs) are attached.

Other chemical usage is also partially described in attachment 4.

D-OOF Even with the announced retirement of CR3, the heat decay system (a non-contact cooling water system associated with the spent fuel pool) will continue to operate for the foreseeable future. Chemical use for the Nuclear Services and Decay Heat Seawater System (also known as the Raw Water or RW system) currently involves use of the molluscicide, Spectrus CT1 300 (also generically referred to as "Clamtrol"), manufactured by GE Betz. Target concentrations during treatment are maintained at < 2.5 mg/L. No changes to the existing treatment regime as outlined in the current NPDES permit are anticipated.

Secondary-Side Chemical Usage The secondary side steam cycle (non-radioactive cycle) has been in a lay-up condition since September 2009. Since that time, part of the system is in dry lay-up; other parts are in wet lay-up. Evaluations are underway to determine a long-term solution for this system. Currently small amounts hydrazine, morpholine, hydroquinone and ammonia are used as maintenance chemicals in the wet lay-up portion with the only discharges coming from minor leaks or small bleed and feed operations. Consequently, discharges of wastewater containing these chemicals are anticipated to be much less than as described in the previous permit renewal application.

Reactor Cavity Cleaning Activities Historically, during outages, the reactor cavity had undergone cleaning and decontamination.

Two chemicals were used for this activity, which are Neutral Multi-Use Cleaner and Crud Remover. The first uses hydrogen peroxide as the active ingredient, while the second is a sodium hydroxide-based product. During these cleaning operations, a majority of this product was collected and disposed off-site. However, a small portion contained in rinse water had the ability to be sent through the ECST system (radwaste treatment system). Given the small amount of this product that makes up the ECST discharge, the final discharge concentrations were virtually immeasurable.

It is unknown at this time if further reactor cavity cleaning activities will occur. However, it's expected that any future cleaning that may occur will follow prior protocols stated above. The Department will be notified in advance of any significant changes from past reactor cavity cleaning practice.

Instrument Air Heat Exchangers CR3 utilizes closed-cycle mechanical draft evaporative cooling towers. These include the Instrument Air Heat Exchangers (IAHE) 6B and 6C. These cooling towers are part of a heat exchange system that cools various instrument air compressors at CR3. The water source for these towers is treated groundwater (service water).

Currently, the station uses two GE Betz products, Spectrus OX903 and Continuum AT901 to control scaling and corrosion (MSDSs attached). Concentrations of Spectrus OX903 are expected to be maintained at 5 ppm within the towers, while concentrations of Continuum AT901 are expected to be 30 ppm. Typically, the IAHE towers discharge to the SDT-1 system at 1-5 gpm each (only one tower is in service and therefore only 1 of the 2 towers discharges to the SDT-1 at any one time). The SDT-1 tank has a volume of 100,000 gallons, and only one SDT-1 tank release occurs during a day, resulting in a dilution factor of 0.072 (5 gpm x 1440 minutes = 7200 gallons/100,000 gallons SDT-1 tank volume = 0.072). The SDT-1 discharges at a maximum flow rate of 0.0852 mgd to the D-0OF system which has an average flow rate of 43.5 mgd, resulting in additional dilution factor of 0.002. Applying the concentration above would result in worst-case discharge concentrations of 0.007 ppm for Spectrus OX903 and 0.004 ppm for Continuum AT901 from the D-O0F outfall.

In addition to the above-named products, the IAHE system has the ability to utilize Nalco 71iD5, an anti-foaming additive that is a direct replacement for the previously-permitted GE Betz Foamtrol product. The anti-foaming agent is only used when foaming is a problem. It has actually not been used for several years.

Antifouling Coatings Over the life of the current NPDES permit, Progress Energy has obtained several authorizations relative to the use of the copper-based anti-fouling coating Ameron ABC#3. Monitoring data previously submitted to the Department to evaluate the release of copper have shown no exceedences to the Class III marine water quality standard for copper. This finding was subsequently acknowledged by the Department in a letter dated June 4, 2002.

Based on these previous conclusions and the fact that the Department has historically authorized use of this product, we request that intermittent use of the product be allowed. Past usage had involved re-coating the CR3 condenser inlet water boxes, pump suction housings, and inlet screen sensing tubes approximately once every two years or when a system is replaced. Given that the condenser cooling water system will no longer operate, it's expected that future use of this product would be limited to the heat decay system intake components only.

In addition to use of this product at CR3, we request that the same systems at CR 1&2, i.e. the inlet/outlet water boxes, circulating and screen wash pump suction housings, and packing drains on the circulating water screen wash pumps, also be allowed to utilize Ameron ABC#3 as a part of routine maintenance activity.

As with all applications involving this product, the product will be applied per manufacturer's instructions and allowed to completely cure before the system is placed back into operation.

Attachment 8 - Supplemental Material Safety Data Sheets For chemicals used and have the potential to be discharged via one of the NPDES-permitted outfalls under FLOO00159.

" Sodium Hypochlorite

" Sodium Bromide

" Actibrom (sodium bromide with surfactant added)

" Sodium Bisulfite

" Sodium Metabisulfite

" Hydrazine (Cortrol OS5010)

" Morpholine

" Hydroquinone

" Ammonium Hydroxide

" Spectrus CT1300 (Clamtrol)

Nalco 71 D5 (anti-foaming agent)

" Spectrus OX903

" Continuum AT901

" Neutral Multi-Use Cleaner

" Crud Remover

" Hydrochloric Acid

" Sulfuric Acid

" Sodium Hydroxide

" Ameron ABC#3

ODYSSEY MANUFACTURING CO.

MATERIAL SAFETY DATA SHEET REVISED 7/2/00 SECTION I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ODYSSEY MANUFACTURING CO. EMERGENCY RESPONSE NUMBER:

1484 Massaro Boulevard 1-800-ODYSSEY (FLORIDA)

Tampa, Florida 33619 1-813-635-0339 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months ) 1-813-635-0339 SUBSTANCE: SODIUM HYPOCHLORITE TRADE NAME: Ultra-CHLOR CHEMICAL NAME/SYNONYMS: Sodium Hypochlorite Solution, Bleach Solution, Bleach Liquor, Hypo-solution, Bleach, and Liquid Bleach.

CAS NUMBER: 7681-52-9 CHEMICAL FAMILY: Alkali FORMULA: NaOCI DOT PROPER SHIPPING NAME: Hypochlorite Solution DOT HAZARD CLASS: 8 (Corrosive) PG 11I; PG II (For solutions greater than 16% available chlorine)

DOT IDENTIFICATION NO: UN 1791 RQ: 100 pounds DOT EMERGENCY GUIDE NO: 154 SECTION !1 COMPOSITION, INFORMATION ON INGREDIENTS INGREDIENT(S):

Sodium Hypochlorite (NaOC1) 10.0 - 20.0% wt Sodium Hydroxide (NaOH) 0.1 - 0.4% wt Water (H 20) 79.7 - 89.9% wt SECTION III HAZARDS IDENTIFICATION NFPA CLASSIFICATION (SCALE 0-4): Health=2 Fire=0 Reactivity-l EC CLASSIFICATION (ASSIGNED): C (Corrosive)

EMERGENCY OVERVIEW COLOR: Yellow PHYSICAL FORM: Liquid ODOR: Chlorine Odor MAJOR HEALTH HAZARDS: Respiratory Tract Bums, Skin Bums, Mucous Membrane Bums, and Eye Irritation HAZARDOUS MIXTURES WITH OTHER LIQUIDS, SOLIDS, OR GASES: Reacts violently with acids liberating chlorine gas. Also reacts with organic substance. When heated, gives off oxygen that may increase fire hazard.

I

POTENTIAL HEALTH EFFECTS INHALATION:

SHORT TERM EXPOSURE: Irritation to respiratory tract. May have same as effects reported in other routes of exposure, bums, blisters, nausea, difficulty breathing, and lung congestion.

" LONG TERM EXPOSURE: Same as effects reported in short term exposure.

SKIN CONTACT:

" SHORT TERM EXPOSURE: Irritant, reddening of the skin. May have bums, blisters, and itching

" LONG TERM EXPOSURE: Same as effects reported in short term exposure.

EYE CONTACT:

" SHORT TERM EXPOSURE: Irritation (possibly severe), possible eye damage

" LONG TERM EXPOSURE: Same as effects reported in short term exposure.

INGESTION:

" SHORT TERM EXPOSURE: Bums, vomiting stomach pain, disorientation, bluish skin color, convulsions, coma

LONG TERM EXPOSURE: Same as effects reported in short term exposure.

CARCINOGEN STATUS OSHA: N NTP: N IARC: N SECTION IV FIRST AID MEASURES INHALATION: Remove from exposure and get fresh air. Use a bag valve mask or similar device to perform artificial respiration (rescue breathing) if needed. Keep wamn and at rest. Get medical attention immediately if artificial respiration is required.

SKIN CONTACT: Remove contaminated clothing, jewelry, and shoes immediately. Flush affected area with large amounts of water, preferably a safety shower. Use soap or mild detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes). For bums, cover affected area securely with sterile, dry, loose fitting dressing. If skin is burned, get medical attention immediately.

EYE CONTACT: Wash eyes immediately with large amounts of water, occasionally lifting upper and lower lids, until no evidence of chemical remains (at least 15 minutes). Continue irrigating with a normal saline solution until ready to transport to physician. Cover with sterile bandages. Get medical attention inmmediately.

INGESTION: Rinse mouth with water. Drink large quantities of milk (water if no milk is available). Milk of magnesia may be helpful. DO NOT USE ACIDIC ANTIDOTES SUCH AS SODIUM BICARBONATE.

When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, do not induce vomiting and turn their head to the side. Never make an unconscious person vomit or drink fluids. Get medical attention.

NOTE TO PHYSICIAN: For inhalation, consider oxygen. For ingestion, avoid gastric lavage, emesis, sodium bicarbonate and acid solutions. Consider the use of antacids.

SECTION V FIRE FIGHTING MEASURES FLASH POINT: Non-flammable FLAMMABLE LIMITS: Non-flammable FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Oxidizer. This material will react with some metals and cause liberation of oxygen. May ignite or explode on contact with combustible materials. Toxic fumes can be liberated by contact with acid or heat.

EXTINGUISHING MEDIA: Regular dry chemical, carbon dioxide, water, or foam suitable for surrounding fire.

For large fires, use regular foam or flood with fine water spray.

FIRE FIGHTING: Wear self-contained breathing apparatus and full protective clothing. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Do not get water directly on material. For large fires, flood with fine water spray. Reduce vapors with water spray. Apply water from a protected location or from a safe distance. Avoid body contact or inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

2

SECTION VI ACCIDENTAL RELEASE MEASURES OCCUPATIONAL RELEASE: Do not touch spilled material. Stop leak if possible without personal risk. For small spills, collect spilled material in appropriate container for disposal and consider absorbing with sand or other non-combustible material (e.g., do not use sawdust or other combustible material). Be advised, however, that the use of absorbing material is creating hazardous waste and this absorbing material must now be disposed of properly. Collect spilled material in appropriate container for disposal. For small dry spills, move containers away from spill to a safe area. For large spills, dike for later disposal. If possible, do not allow material to enter sewers, streams, ponds or storm conduits as concentrated solutions will seriously injure aquatic life. Keep unnecessary people away, isolate hazard area and deny entry. Contain in as small an area as possible, such as a holding area for dilution and neutralization. Contain spill in plastic drums when available. Dispose of in accordance with Federal, State, and local regulations. Personnel engaged in cleanup operations must be equipped with NIOSH approved respirator protection, rubber boots, gloves, and clothing to avoid body contact.

Reportable Quantity (RQ): 100 pounds. Notify Local Emergency Planning Committee and State Emergency Response Conmuission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800) 424-8802 (USA) or (202) 426-2675 (USA).

ADVANCE PLANNING: Plan in advance for an occupational release and have necessary equipment and neutralization agents on-site. Contact Odyssey Manufacturing for assistance.

SECTION VII HANDLING AND STORAGE Store in vented, closed containers that provide protection from direct sunlight. Keep separated from incompatible substances and do not store near acids, heat, or oxidizable materials or organics. When handling, do not mix with other cleaning agents that may liberate chlorine gas vapors (e.g., acidic agents).

Store and handle in accordance with all current regulations and standards including NFPA 430 Code for the Storage of Liquid and Oxidizing Materials.

SECTION VIII EXPOSURE CONTROLS AND PERSONNEL PROTECTION EXPOSURE LIMITS: 2 mg/m3 AIHA recommended STEL 15 minute(s) for Sodium Hypochlorite VENTILATION: Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.

EYE PROTECTION: Splash goggles are preferred to a faceshield. Another option is to wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

CLOTHING: It is recommended to wear appropriate chemical resistant clothing to avoid body contact such as a rubber apron or rain suit. Boots are preferred for footwear.

GLOVES: Wear appropriate chemical resistant gloves.

RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory protection may be needed.

Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use.

Any chemical cartridge respirator with organic vapor cartridge(s).

Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s)

Any air-purifying respirator with a full facepiece and an organic vapor canister

" Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply (Use for Unknown Concentrations or those that may be Immediately Dangerous to Life or Health)

" Any self-contained breathing apparatus with a full facepiece (Use for High Concentrations or those which are immediately Dangerous to Life or Health)

SECTION IX PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL APPEARANCE: Liquid APPEARANCE AND ODOR: Clear - Chlorine odor like household bleach.

COLOR: Greenish -Yellowish cast MOLECULAR WEIGHT: 74.44 MOLECULAR FORMULA: Na-O-CI 3

BOILING POINT: Degrades at 230 Degrees Fahrenheit FREEZING POINT: 7 Degrees Fahrenheit SPECIFIC GRAVITY: 1.15 - 1.17 at 60 Degrees Fahrenheit PH: Approximately 11 - 13 VAPOR PRESSURE (mm HG): Vapor Pressure of water + decomposition product Vapor Pressure VAPOR DENSITY: Not Available SOLUBILITY IN WATER: Complete VOLATILITY: Not Available EVAPORATION RATE: >1 COEFFICIENT OF WATER /OIL DISTRIBUTION: Not Available SECTION X STABILITY AND REACTIVITY REACTIVITY: Stable at normal temperatures and pressure.

CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Dangerous gases may accumulate in confined spaces. May ignite or explode on contact with combustible materials.

INCOMPATIBLES: Acids, metals, amines, combustible materials, reducing agents. Specific reactions with sodium hypochlorite include the following:

ACIDS: Violent reaction.

ALUMINUM: Corrosive action.

AMINES: Form explosive chloramines.

AMMONIA: Form explosive chloramines.

AMMONIUM SALTS: May form explosive product.

BENZYL CYANIDE (ACIDIFIED): Explosive reaction.

CELLOLOSE: Violent reaction ETHYLENEIMINE: Forms explosive 1-chloroethyleneimine.

FORMIC ACID: Explosive mixture.

METHANOL: May form explosive compound.

NITROGEN COMPOUNDS: Forms explosive N-chloro compounds.

ORGANIC AND COMBUSTIBLE MATERIALS: Fire and explosion hazard.

OXALIC ACID: Intense reaction REDUCING AGENTS: Fire and explosion hazard ZINC: Corrosive HAZARDOUS DECOMPOSITION:

Thermal decomposition products - Chlorine and Hydrochloric Acid Vapors Decomposition Products - Hypochlorous Acid Vapors POLYMERIZATION: Will not polymerize.

SECTION XI SODIUM HYPOCHLORITE TOXILOGICAL INFORMATION IRRITATION DATA: 10 mg eyes - rabbit moderate TOXICITY DATA:

1gm/ kg oral-woman; TDLo; 45mg/kg intravenous-man TDLo; 5800 mg/ kg oral-mouse LD50; 140 mg/ kq/9 week(s) continuous oral-rat TDLo CARCINOGEN STATUS: According to the IARC, animal inadequate evidence, human no adequate data, Group 3 (Hypochlorite salts)

LOCAL EFFECTS:

Corrosive: inhalation, skin contact, eye, ingestion hazards ACUTE TOXICITYLEVEL:

Slightly Toxic if ingested MUTAGENIC DATA:

Mutation in micro organisms - Salmonella typhimurium 1mg / plate (-S9); DNA repair - Escherichiacoli 20ug/

disc; DNA damage - Esoherichiacoli 420 umol/L; phage inhibition capacity - Esoherichiacoli 103 ug/ well; micronucleus test - non-mammalian species multiple 200 ppb; cytogenetic analysis - non-mammalian species multiple 120 ug/ L; cytogenetic analysis - human lymphocyte 100 ppm 24hour(s); sister chromatid exchange -

human embryo 149 mg/ L; cytogenetic analysis - hamster lung 100 mg/ L HEALTH EFFECTS:

INHA LA TION ACUTE EXPOSURE: May cause severe bronchial irritation, sore throat with possible blistering, coughing, 4

stomatitis, nausea, labored breathing, shortness of breath and pulmonary epedema. 10-20 rmg/m3 causes burning of the nose and throat; 40-60 rmg/m3 may be fatal. If sufficient amounts are absorbed, may cause effects as detailed in acute ingestion.

CHRONIC EXPOSURE: No data available.

SKIN CONTACT ACUTE EXPOSURE: Extent of damage depends on concentration, pH, volume of solution and duration of contact. May cause redness, pain, blistering, itchy eczema and chemical burns. Sensitization reactions are possible in previously exposed persons.

CHRONIC EXPOSURE: Effects depend on concentration and duration of exposure. Repeated or prolonged contact with corrosive substances may result in dermatitis or effects similar to acute exposure. Allergic dermatitis has also been reported.

EYE CONTACT ACUTE EXPOSURE: May cause redness, pain, and blurred vision. Solutions of 5% splashed in human eyes have caused a burning sensation and later only slight superficial disturbance of the corneal epitheliumn which cleared completely in the next day or two without special treatment. However, one animal study reports a 5%

solution causing only moderate irritation with clearing within 7 days. A higher concentration of 15% tested on rabbit eyes caused inmmediate severe pain, hemorrhages, rapid onset of ground-glass appearance of the corneal epithelium, moderate bluish edema of the whole cornea, chemosis and discharge for several days.

Such eyes have sometimes healed in 2-3 weeks with slight or no residual corneal damage but they had neovascularization of the conjunctiva and distortion of the nictitating membrane by scarring.

CHRONIC EXPOSURE: Depending on concentration and duration of exposure, symptoms may be as those of acute exposure.

INGESTION ACUTE EXPOSURE: May cause irritation and erosion of the mucous membranes, vomiting (possibly bloody) and abdominal pain and spasms. A drop in blood pressure, shallow respiration, edema (possibly severe) of pharynx, larynx, and glottis, confusion, convulsions, delirium and coma may occur. Cyanosis and circulatory collapse are possible. Esophageal or gastric perforation and strictures are rare. Death may occur, usually due to complications of severe local injury such as toxemia, shock, perforations, hemorrhage, infection and obstruction. Massive ingestions may produce fatal hyperchloremic metabolic acidosis or aspiration pneumonitis.

CHRONIC EXPOSURE: Sensitization reactions are reported in individuals who are exposed in small amounts through their water supply. High doses have caused sperm abnormality in mice.

SECTION X11 ECOLOGICAL INFORMATION ECOTOXICITY DATA:

FISH TOXICITY: 94.0 ug/L 96h hour(s) LC50 (Mortality) Cutthroat trout (Oncorhynchus clarki)

INVERTEBRATE TOXICITY: 31.6 ug/L 7 hour8.101852e-5 days 0.00194 hours 1.157407e-5 weeks 2.6635e-6 months (s) 1C50 (Species Diversity) Protozoan phylum (Protozoa)

ALGAL TOXICITY: 90 ug/L 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months (s) LC50 (Mortality) Algae, phytoplankton, algai mat (Algae)

PHYTOTOXICITY: 230 ug/L 35 hour4.050926e-4 days 0.00972 hours 5.787037e-5 weeks 1.33175e-5 months (s) (Biomass) Curled pondweed (Potamogeton crispus)

OTHER TOXICITY: 2.1 ug/L 28 day(s) (Chlorophyll) Aquatic community (Aquatic community)

ENVIRONMENTAL

SUMMARY

Highly toxic to aquatic life.

SECTION XIII DISPOSAL CONSIDERATIONS Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): DOO. Dispose in accordance with all applicable regulations.

SECTION XIV TRANSPORT INFORMATION U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER: Sodium Hypochlorite) - UN 1791 U.S. DOT 49 CER 172.101 HAZARD CLASS OR DIVISION: 8 U.S. DOT 49 CFR 172. 101 PACKING GROUP: III (less than 16% available chlorine) / 11(16% or more available chlorine)

U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS: Corrosive U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:

EXCEPTIONS: 49 CFR 173.154 5

NON- BULK PACKAGING: 49 CFR 173.203 (less than 16% available chlorine) / 49 CFR 173.202 (16% or more available chlorine)

BULK PACKAGING: 49 CFR 173.241 (less than 16% available chlorine) /: 49 CFR 173.242 (16% or more available chlorine)

U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:

PASSENGER AIRCRAFT OR RAILCAR: 5 LITERS / (less than 16% available chlorine) / I LITERS (16% or more available chlorine)

CARGO AIRCRAFT ONLY: 60 LITERS / (less than 16% available chlorine) /30 LITERS (16% or more available chlorine)

SECTION XV REGULATORY INFORMATION U.S. REGULATIONS TSCA INVENTORY STATUS: Y TSCA 12(b) EXPORT NOTIFICATION: Not listed.

CERCLA SECTION 103 (40CFR302.4): Y SODIUM HYPOCHLORITE: 100 LBS RQ SARA SECTION 302 (40CFR355.30) : N SARA SECTION 304 (40CFR355.40) : N SARA SECTION 313 (40CFR372.65) : N SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.2 1):

ACUTE: Y CHRONIC: N FIRE: N REACTIVE: N SUDDEN RELEASE: N OSHA PROCESS SAFETY (29CFRlS 10.119): N STATE REGULATIONS:

California Proposition 65: N EUROPEAN REGULATIONS:

EC NUMBER (BINECS) : 231-668-3 EC RISK AND SAFETY PHRASES:

R 31 Contact with acids liberates toxic gas.

R 34 Causes bums.

S V2 Keep locked-up and out of reach of children.

S 28b After contact with skin, wash immediately with plenty of soap and water.

S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

S 50 Do not mix with incompatible materials.

CONCENTRATION LIMITS:

C>10% C R 31-34 5%<=C<=10% Xi R 31-36/38 GERMAN REGULATIONS:

WATER HAZARD CLASS (WGK) : 2 (Official German Classification)

SECTION XVI OTHER INFORMATION For additional information, contact our technical service department.

Information contained in this MSDS refers only to the specific material designated and does not relate to any process or use involving other materials. This information is based on data believed to be reliable, and the Product is intended to be used in a manner that is customary and reasonably foreseeable. Since actual use and handling are beyond our control, no warranty, express or implied, is made and no liability is assumed by Odyssey Manufacturing in connection with the use of this infonnation.

6

APPLIED SPECIALTIES, INC. 07254740-1 33555 PIN OAK PARKWAY AS-740 September 11, 2007 AVON LAKE, OHIO 44012 TELEPHONE (440) 933-9442 EMERGENCY: (216) 973-6118 MATERIAL SAFETY DATA SECTION 1 MATERIAL IDENTIFICATION PRODUCT NAME OR AS-740 EPA # 5185-451-46982 SYNONYMS Sodium Bromide Biocide SECTION 2 INGREDIENTS AND HAZARDS COMPONENT CAS. NUMBER % TWA/CEILING REFERENCE Sodium Bromide 7647-15-6 40% Not Established Emergency Overview: Odorless, Colorless Liquid. CAUTION: May Be Harmful If Swallowed. May Cause Skin, And Eye Irritation With Redness And Swelling. Do Not Get In Eyes, On Skin Or On Clothing. Wash With Soap And Water After Handling. Remove Contaminated Clothing And Wash Before Use. Keep Container Tightly Closed. Use Only With Adequate Ventilation.

SECTION 3 REGULATORY INFORMATION OSHA STATUS This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard TSCA STATUS This substance is subject to regulation under FIFRA and is therefore exempt US Toxic Substance Control Act Inventory listing requirements.

CERCLA REPORTABLE QUANTITY None listed SARA TITLE II:

SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCE) Not listed SECTION 311/312 (HAZARDOUS SUBSTANCES Classification Under Section 311/312 of SARA (40 CFR 370): Acute (Y ) Chronic ( Y ) Fire (N) Reactive (N) Pressure (N)

SECTION 313 SUPPLIER NOTIFICATION: None listed RCRA STATUS Not regulated as supplied OSHA, ACGIH, NTP & IARC STATUS None listed HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 0 MINIMAL 1 SLIGHT HAZARD HEALTH - 1 FIRE- 0 REACTIVITY- 0 2 MODERATE HAZARD 3 SERIOUS HAZARD 4 SEVERE HAZARD Chemical identity of some ingredients may be withheld as confidential as permitted by 29 CFR 1910.1200 and various State right to know laws.

Page 1

APPLIED SPECIALTIES, INC. 07254740-1 33555 PIN OAK PARKWAY AS-740 September 11, 2007 AVON LAKE, OHIO 44012 TELEPHONE (440) 933-9442 EMERGENCY: (216) 973-6118 SECTION 4 HEALTH HAZARD AND PROTECTION DATA TARGET ORGANS Eyes Skin Respiratory System ROUTES OF ENTRY INTO BODY Skin or Eye Contact, Inhalation, Ingestion SIGNS AND SYMPTOMS OF EXPOSURE:

Moderate eye irritant. May cause tearing with redness, and pain. Prolonged and excessive inhalation or ingestion may cause rashes, central nervous system depression and emaciation and, in severe cases, psychoses and mental deterioration; severity depends on concentration and duration of contact. May cause respiratory irritation. Overdose may cause gastrointestinal or cardiovascular irregularities. Sodium Bromide has been shown to cause embryo-fetal toxicity and malformations in rats at dose levels that also produce maternal toxicity. The No-Observed Effect Level is 100 mg/kg/day, and the Acceptable Daily Intake for sodium bromide from food and drinking water in humans is 1 mg/kg/day. Comparable high does of sodium chloride (table salt) similarly cause malformation, embryo-fetal toxicity and maternal toxicity in mice.

TOXICOLOGICAL INFORMATION Acute: Dermal LD50: >20000mg/kg (Rabbits) Oral LD50: >5000mg/kg (Rats)

Eye: May Cause Irritation Skin: Not expected to be irritating to the skin.

Reproductive Effects: A 3 generation Study in rats fed 4800 mg/kg showed a decrease in fertility; no effects were observed at lower levels according to the literature.

PROTECTIVE EQUIPMENT REQUIRED:

Employees should be required to use impervious clothing, rubber gloves, over boots, safety glasses with side shields as a minimum and other appropriate protective clothing to prevent skin contact. Employees shall be required to use splash-proof safety goggles (ANSI Z87.1 or equivalent) where the material may contact the eyes in addition to face shield. Clothing wet with product should be placed in a closed container until provisions are made for it to be discarded or laundered. Any clothing that becomes wet with the material should be removed immediately and not re-worn until the clothing has been properly cleaned. The employer should provide an eye wash fountain and quick drench shower within the immediate work area for emergency use.

RESPIRATORY: Use only in well ventilated areas. Where the potential for excessive exposures exists which cannot be controlled by mechanical means, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations. ESCAPE & FIRE FIGHTING: Use self-contained breathing apparatus (pressure demand MSHA/NIOSH approved or equivalent) and full protective gear.

FIRST AID SKIN CONTACT: Wash affected skin thoroughly with mild soap and plenty of water. Remove and wash contaminated clothing thoroughly before re-use. Get medical attention immediately for any sign of irritation.

EYE CONTACT: If material gets into the eyes, flush the eyes immediately with large amounts of water for at least 30 minutes, lifting the lower and upper lids occasionally. Get MEDICAL attention immediately. Contact lenses should not be worn when working with this substance or any other chemicals.

INHALATION: Remove to fresh air. Keep person quiet and warm. Ifperson is not breathing call 911 then give artificial respiration and Get medical attention immediately. Treat symptomatically and supportively.

INGESTION: Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Get medical attention immediately & Contact poison control center. Ifvomiting occurs, keep head lower than hips to prevent aspiration. Do not induce vomiting unless told to do so by poison control or a medical doctor. Have person sip a glass of water ifalert and able to swallow.

NOTE TO PHYSICIAN: Treat symptomatically and supportively. The following antidote for Bromide poisoning has been recommended. The decision to administer any antidote should be made only by qualified medical personnel. Give Sodium Chloride, 1 gram every hour in water or as salt tablets; for severe involvement give normal saline, 1 liter every 8 hours9.259259e-5 days 0.00222 hours 1.322751e-5 weeks 3.044e-6 months to a maximum of 2 liters per day. Sodium chloride therapy must be continued until the blood bromide level drops below 50mg/dL.

Simultaneous administration of diuretics is also useful. (Driesback, Handbook of Poisoning, 12th Ed.)

Page 2

APPLIED SPECIALTIES, INC. 07254740-1 33555 PIN OAK PARKWAY AS-740 September 11, 2007 AVON LAKE, OHIO 44012 TELEPHONE (440) 933-9442 EMERGENCY: (216) 973-6118 SECTION 5 PHYSICAL DESCRIPTION APPEARANCE AND ODOR Colorless clear liquid; odorless.

BOILING POINT 103 C (217F) to 104 C (219F)

MELTING POINT Not applicable FLASH POINT Not Flammable VAPOR PRESSURE No data SPECIFIC GRAVITY 1.43 +/- 0.02 g/ml PRODUCT pH 7.00 (+/- 0.5)

SOLUBILITY IN WATER Soluble SECTION 6 INCOMPATIBILITIES AND STORAGE Hazardous polymerization will not occur.

Stable under normal conditions. Can evolve hydrogen bromide/bromine when strongly heated.

Hazardous decomposition products: hydrogen bromide, bromide gas and sodium oxide.

Incompatible with strong acids and strong oxidizers.

Store in a dry, well-ventilated area. Keep containers tightly closed when not in use. Store at OF or above.

SECTION 7 REGULATIONS/OSHA OSHA Standard 29 CFR 1910.1200 HAZARD COMMUNICATION OSHA Standard 29 CFR 1910.1000 AIR CONTAMINANTS Table Z-1 OSHA Standard 29 CFR 1910.94 VENTILATION OSHA Standard 29 CFR 1910.134 RESPIRATORY PROTECTION OSHA Standard 29 CFR 1910.20 ACCESS TO EMPLOYEE EXPOSURE OSHA Standard 29 CFR 1910.132 PERSONAL PROTECTIVE EQUIPMENT OSHA Standard 29 CFR 1910.141 SANITATION OSHA Standard 29 CFR 1910.151 MEDICAL SERVICES AND FIRST AID OSHA Standard 29 CFR 1910.133 EYE AND FACE PROTECTION SECTION 8 EMERGENCY HANDLING OF HAZARDOUS MATERIALS IF MATERIAL IS ON FIRE OR INVOLVED IN FIRE: .

Negligible fire hazard when exposed to heat or flame. Product is non-combustible as supplied. Use water, foam, carbon dioxide or dry chemical to extinguish fire as appropriate to surrounding fire. Fire may result into the release of toxic fumes of bromine, hydrogen bromide and sodium oxide. Product may react with some metals (aluminum, zinc, tin, etc.) to release flammable hydrogen gas. Move container from fire area ifyou can without risk. Apply cooling water to sides to keep cool. Do not use water directly on material.

IF MATERIAL IS NOT ON FIRE OR NOT INVOLVED INFIRE: Keep material out of water sources and sewers.

PERSONAL DANGER SITUATION PROTECTION:

Keep upwind. Avoid breathing dust/vapors/fumes from material. Avoid bodily contact with material. Wear boots, protective gloves and gas-tight goggles. Wear full protective clothing including SCBA (regular FIRE FIGHTERS' gear is inadequate).

Page 3

APPLIED SPECIALTIES, INC. 07254740-1 33555 PIN OAK PARKWAY AS-740 September 11, 2007 AVON LAKE, OHIO 44012 TELEPHONE (440) 933-9442 EMERGENCY: (216) 973-6118 SECTION 9 SPILL, LEAK AND DISPOSAL PROCEDURES Persons not wearing protective equipment and clothing should be restricted from spill areas until clean-up has been completed. If AS-740 is spilled, take the following steps:

1- Ventilate area. Contain spills immediately with inert materials (sand, earth). The floor may be slippery, exercise caution to avoid falls.

2- Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. Wash spill site after material pickup is complete.

3- Incinerate any material and the absorbent material in accordance to all FEDERAL, STATE, AND LOCAL REGULATIONS.

NOTE: DO NOT wash or pour AS-740 into any surface waters or streams or directly into sewers.

SECTION 10 SHIPPING AND TRANSPORTATION DATA PROPER SHIPPING NAME Disinfectant, NOIBN other than Medicinal HAZARD CLASS Not Regulated IDENTIFICATION NUMBER None LABEL REQUIRED None SECTION 11 ECOLOGICAL INFORMATION This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes, streams, pond or estuaries, oceans, or other waters unless in accordance with the requirements of a NPDES permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.

H. Garcia-Munoz / A Scheurman This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation and verification. Before using any product, read its label carefully and completely.

Page 4

APPLIED SPECIALTIES, INC. 07254740-1 33555 PIN OAK PARKWAY AS-740 September 11, 2007 AVON LAKE, OHIO 44012 TELEPHONE (440) 933-9442 EMERGENCY: (216) 973-6118 PENNSYLVANIA and MASSACHUSETTS RIGHT-TO-KNOW INFORMATION:

The following comprises the CHEMICAL IDENTIFICATION LIST CAS#

Water 7732-18-5 Sodium Bromide 7647-15-6 NEW JERSEY RIGHT-TO-KNOW TOTAL INGREDIENTS LABEL:

CAS#

Water 7732-18-5 Sodium Bromide 7647-15-6 CALIFORNIA PROPOSITION 65:

This product does not contain toxic chemicals currently on the California list of known carcinoqens and reproductive toxins Pursuant to the California Safe Drinking Water and Toxic Enforcement Act of 1986 (proposition 65), this information is provided. This law requires that" clear and reasonable warning " be provided to any individual, knowingly or intentionally exposed to any substances identified by the state as being cancer or reproductive hazards unless, it can be shown that the exposure poses "no significant risk". Based on available data, the following chemicals listed by Proposition 65 may be present in this product:

NONE Page 5

SAFETY DATA SHEET AVONALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

11. 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ACTI-BROM(R) 1338 APPLICATION: CHLORINE ENHANCER, BIODISPERSANT COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704MIHMIS RATING HEALTH: 1/1 FLAMMABILITY: 0/0 INSTABILITY: 0/ 0 OTHER:

0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme

12. 1 COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous.

Hazardous Substance(s) CAS NO % (w/w)

Sodium Bromide 7647-15-6 30- 60

13. 1HAZARDS IDENTIFICATION

"*EMERGENCY OVERVIEW**

WARNING HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES MODERATE EYE IRRITATION.

Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse.

Wear suitable protective clothing, gloves and eye/face protection.

Not flammable or combustible.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

EYE CONTACT:

Can cause mild to moderate irritation.

SKIN CONTACT:

May cause irritation with prolonged contact.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/11

t ~NALCO SAFETY DATA SHI-EIT

)04" ALCOPRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC INGESTION:

Not a likely route of exposure. May be harmful if swallowed.

INHALATION:

Not a likely route of exposure. Repeated or prolonged exposure may irritate the respiratory tract.

SYMPTOMS OF EXPOSURE:

Acute :

A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic :

A review of available data does not identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

HUMAN HEALTH HAZARDS - CHRONIC:

No adverse effects expected other than those mentioned above.

4. FIRST AID MEASURES EYE CONTACT:

Immediately flush eye with water for at least 15 minutes while holding eyelids open. If irritation persists, repeat flushing. Get immediate medical attention.

SKIN CONTACT:

Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician.

INGESTION:

If swallowed, induce vomiting only if victim is conscious and not convulsing. Give 240 to 300 mL of water. DO NOT attempt to give anything by mouth to an unconscious or convulsing person. Get prompt medical attention.

INHALATION:

Remove to fresh air, treat symptomatically. Get medical attention.

IF SWALLOWED: Induce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person.

IF IN EYES: Flush eyes with plenty of water. Get medical attention if irritation persists.

IF ON SKIN: Wash with plenty of soap and water. Get medical attention.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

Nalco Company 1601 W. Diehl Road s Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/11

SAFETY DATA SHEET A4NALCO (800) 424-9300 (24 Hours) CHEMTREC

15. 1 FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA:

Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

Not flammable or combustible.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Stop or reduce any leaks if it is safe to do so. Do not touch spilled material. Ventilate spill area if possible. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.

7. HANDLING AND STORAGE HANDLING:

Avoid eye and skin contact. Do not take internally. Ensure all containers are labeled. Keep the containers closed when not in use.

STORAGE CONDITIONS:

Store the containers tightly closed.

18. 1 EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:

This product does not contain any substance that has an established exposure limit.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/11

SAFETY DATA SHEET A4NALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC ENGINEERING MEASURES:

General ventilation is recommended.

RESPIRATORY PROTECTION:

Respiratory protection is not normally needed.

HAND PROTECTION:

Neoprene gloves, Nitrile gloves, Butyl gloves, PVC gloves SKIN PROTECTION:

Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.

EYE PROTECTION:

Wear chemical splash goggles.

HYGIENE RECOMMENDATIONS:

Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

HUMAN EXPOSURE CHARACTERIZATION:

Based on our recommended product application and personal protective equipment, the potential human exposure is:

Moderate

19. 1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Colorless ODOR None SPECIFIC GRAVITY 1.43 - 1.49 @ 77 0 F / 25 -C DENSITY 12.0 - 12.4 lb/gal SOLUBILITY IN WATER Complete pH (100 %) 4.0 - 9.0 VISCOSITY 5 cps @ 72 'F / 22 0C FREEZING POINT -13 'F /-25 'C BOILING POINT 230 F/ 110 'C VAPOR PRESSURE 7.6 mm Hg @ 68 'F / 20 0C VOC CONTENT 0.00 %

Note: These physical properties are typical values for this product and are subject to change.

Nalco Company 1601 W. Diehl Roads Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/11

SAFETY DATA SHEET rd NALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC 110. 1 STABILITY AND REACTIVITY STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

Freezing temperatures.

MATERIALS TO AVOID:

Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxicvapors. Reducing agents HAZARDOUS DECOMPOSITION PRODUCTS:

Under acidic conditions: Hydrogen bromide

11. 1TOXICOLOGICAL INFORMATION The following results are for a similar product.

ACUTE ORAL TOXICITY:

Species LD50 Test Descriptor Rat > 5,000 mg/kg Similar Product Rating : Non-Hazardous ACUTE DERMAL TOXICITY:

Species LD50 Test Descriptor Rabbit > 2,000 mg/kg Similar Product Rating : Non-Hazardous PRIMARY SKIN IRRITATION:

Draize Score Test Descriptor 0.4 18.0 Similar Product Rating : Minimally irritating Not irritating PRIMARY EYE IRRITATION:

Draize Score Test Descriptor 10.8 / 110.0 Similar Product Rating : Practically non-irritating SENSITIZATION:

This product is not expected to be a sensitizer.

Nalco Company 1601 W. Diehl Roads Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/11

SAFETY DATA SHEET A4NALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CARCINOGENICITY:

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION:

Based on our hazard characterization, the potential human hazard is: Low 112. 1ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:

The following results are for the product.

ACUTE FISH RESULTS:

Species Exposure LC50 Test Descriptor Rainbow Trout 96 hrs > 1,000 mg/I Product Bluegill Sunfish 96 hrs > 1,000 mg/I Product Fathead Minnow 96 hrs > 1,000 mg/I Product Guppy 96 hrs 538 mg/I Product Sheepshead Minnow 96 hrs 0.19 mg/I HOBr (Generated from NaBr)

Rainbow Trout 96 hrs 0.23 mg/I HOBr (Generated from NaBr)

Fathead Minnow 96 hrs 0.097 mg/I HOBr (Generated from NaBr)

Bluegill Sunfish 96 hrs 0.52 mg/I HOBr (Generated from NaBr)

Inland Silverside 96.00 hrs > 5,000.000 mg/I Product ACUTE INVERTEBRATE RESULTS :

Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs > 1,000 mg/I Product Mysid Shrimp (Mysidopsis 96.00 hrs 1,827.000 Product bahia) mg/I Mysid Shrimp (Mysidopsis 96 hrs 0.17 mg/I HOBr (Generated from NaBr) bahia)

American Oyster 96 hrs 0.54 mg/i HOBr (Generated from NaBr)

Daphnia magna 48 hrs 0.038 mg/I HOBr (Generated from NaBr)

PERSISTENCY AND DEGRADATION:

Total Organic Carbon (TOC)' 2,000 mg/I Chemical Oxygen Demand (COD): 53,000 mg/I Biological Oxygen Demand (BOD): This material is an oxidizing biocide and is not expected to persist in the environment.

Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not applicable.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/11

SAFETY DATA SHEET t04 NALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC MOBILITY:

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.

If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment

<5% 30-50% 50-70%

The portion in water is expected to be soluble or dispersible.

BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: High Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Moderate If released into the environment, see CERCLA/SUPERFUND in Section 15.

113. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.

METAL CONTAINERS: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. APLASTIC CONTAINERS: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.

114. 1TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/11

SAFETY DATA SHEET tAt NALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION

15. REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information.

NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.

Sodium Bromide: Non-Hazardous CERCLA/SUPERFUND, 40 CFR 117, 302:

Notification of spills of this product is not required.

SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:

X Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/11

SAFETY DATA SHEET NALCOAW" ALCOPRODUCT .oo ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:

When use situations necessitate compliance with FDA regulations, this product is acceptable under: the following use conditions.

This product may be used to treat pulp and papermill water systems in situations requiring FDA sanction provided the bromide concentration in the water is kept below 22 ppm. The product must be used in conjunction with an oxidant such as bleach or gaseous chlorine. Follow instructions for use in pulp and papermill on the product label.

FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):

EPA Reg. No. 1706-168 In all cases follow instructions on the product label.

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 /formerly Sec. 307, 40 CFR 116.4 /formerly Sec. 311 :

None of the substances are specifically listed in the regulation.

CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :

None of the substances are specifically listed in the regulation.

CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

STATE RIGHT TO KNOW LAWS:

This product is a registered biocide and is exempt from State Right to Know Labelling Laws.

NATIONAL REGULATIONS, CANADA:

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

Pesticide controlled products are not regulated under WHMIS.

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

Nalco Company 1601 W. Diehl Road s Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/11

SAFETY DATA SHEET t NALCO .oc

)04" ALCOPRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).

CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC).

EUROPE The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).

KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)

NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.

PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).

116. 1OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:

The human risk is: Low

The environmental risk is: Moderate Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.

This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 10/11

SAFETY DATA SHEET

)4NALCO PRODUCT ACTI-BROM(R) 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insightl CD-ROM Version), Ariel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPSI CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPSfI CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight[I CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS] CD-ROM Version), Micromedex, Inc., Englewood, CO.

Ariel Insight[l (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insightl CD-ROM Version), Ariel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPSOI CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 10/10/2008 Version Number: 1.14 Nalco Company 1601 W. Diehl Road* Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 11 / 11

Applied Specialties, Inc. 071499838-5 33555 Pin Oak Parkway AS-9838 May 29, 2007 Avon Lake, Ohio 44012 Telephone (440) 933-9442 Emergency: (216) 973-6118 MATERIAL SAFETY DATA SECTION 1 MATERIAL IDENTIFICATION PRODUCT NAME OR AS-9838 SYNONYMS BOILER WATER TREATMENT SECTION 2 INGREDIENTS AND HAZARDS COMPONENT CAS. NUMBER TWA/CEILING REFERENCE Sodium Bisulfite 7631-90-5 5 mg/m 3 ACGIH EMERGENCY OVERVIEW: Clear Liquid, Sulfurous Odor. CAUTION! May Cause Eye Irritation And Burns. May Cause Skin Irritation. Harmful If Ingested Or Inhaled. May Cause Reactions In Sulfite Sensitive Individuals.

SECTION 3 REGULATORY INFORMATION OSHA STATUS This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard TSCA STATUS All components are listed CERCLA REPORTABLE QUANTITY Sodium Bisulfite -5,000 lbs.

SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCE) Not Listed SECTION 3111312 (HAZARDOUS SUBSTANCES)

Classification Under Section 311/312 of SARA (40 CFR 370): Acute (Yes) Chronic (No) Fire (No) Reactive (N) Pressure (No)

SECTION 313 (TOXIC CHEMICALS): None RCRA STATUS Not Regulated.

NTP, OSHA, ACGIH & IARC STATUS Not listed HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 0 MINIMAL 1 SLIGHT HAZARD HEALTH - 2 FIRE - 0 REACTIVITY -0 2 MODERATE HAZARD 3 SERIOUS HAZARD 4 SEVERE HAZARD Chemical identity of some ingredients may be withheld as confidential as permitted by 29 CFR 1910.1200 and various State right to know laws.

Page I

Applied Specialties, Inc. 071499838-5 33555 Pin Oak Parkway AS-9838 May 29, 2007 Avon Lake, Ohio 44012 Telephone (440) 933-9442 Emergency: (216) 973-6118 SECTION 4 HEALTH HAZARD AND PROTECTION DATA TARGET ORGANS Eyes Skin Gastrointestinal System Respiratory System Mucous Membranes Pulmonary Tract ROUTES OF ENTRY INTO BODY Inhalation Ingestion Skin Or Eye Contact SIGNS AND SYMPTOMS OF EXPOSURE Eye Irritation And Burns Skin Irritation Gastrointestinal Distress Eye Reddness & Itching Tearing Or Blurry Vision Coughing Chest Tightness Mucous Membrane Irritation Respiratory Irritation Dermatitis Nausea Vomiting Diarrhea Headache Note: May Cause Severe Reactions In Asthmatics And Sulfite Sensitive Individuals.

PROTECTIVE EQUIPMENT REQUIRED:

Employees should be provided with and required to use impervious clothing such as apron, boots, pants and jacket, gloves, splash goggles or safety glasses as a minimum and other appropriate protective clothing to prevent skin contact. Employees shall be provided with and required to use splash-proof safety goggles where the material may contact the eyes in addition to face shield. Appropriate gloves include those made from neoprene and nitrile. Clothing wet with product should be placed in a closed container until provisions are made for it to be discarded or laundered.

If the clothing is to be laundered the person performing the laundering should be informed of the hazardous properties of the material. Any clothing that becomes wet with the material should be removed immediately and not reworn until the clothing has been properly cleaned. RESPIRATOR SELECTION - Use only in well ventilated areas. Where the potential for excessive exposures exists which cannot be controlled by mechanical means, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations. ESCAPE & FIRE FIGHTING - Self-contained breathing apparatus with a face-piece operated in a pressure demand or other positive-pressure mode.

FIRST AID SKIN CONTACT: Skin that becomes contaminated should be washed or showered with large amounts of water to remove any chemical from skin. Contaminated clothing should be removed and the skin washed with soap and water.

Clothing should be washed before it is reused. Discard contaminated footwear, which can not be decontaminated. If irritation persists, seek medical attention.

EYE CONTACT: If material gets into the eyes, flush the eyes immediately with large amounts of water for at least 30 minutes, lifting the lower and upper lids occasionally. Get MEDICAL attention immediately. Contact lenses should not be worn when working with this substance or any other chemical. Eyewash should be available.

INHALATION: If a person breathes in large amounts of product mist, move the person to fresh air. If breathing has stopped, perform artificial respiration. Keep the affected person warm and at rest. Get medical attention as soon as possible.

INGESTION: Ifconscious, give 2 glasses of water. Get medical attention immediately. Never give anything by mouth to an unconscious person.

Page 2

Applied Specialties, Inc. 071499838-5 33555 Pin Oak Parkway AS-9838 May 29, 2007 Avon Lake, Ohio 44012 Telephone (440) 933-9442 Emergency: (216) 973-6118 SECTION 5 PHYSICAL DESCRIPTION APPEARANCE AND ODOR Clear liquid; sulfurous odor.

BOILING POINT Not determined MELTING POINT Not applicable FLASH POINT Not applicable VAPOR PRESSURE Not determined SPECIFIC GRAVITY 1.336 +/- 0.02 g/ml PRODUCT pH 5.55 +/- 0.50 standard pH units SOLUBILITY IN WATER Complete SECTION 6 INCOMPATIBILITIES AND STORAGE Stable Hazardous Polymerization Will Not Occur Keep Containers Closed When Not In Use. Do Not Store In Unlined Steel Drums Or Equipment Store Containers With Labels Visible SECTION 7 REGULATIONS/OSHA OSHA Standard 29 CFR 1910.1200 HAZARD COMMUNICATION OSHA Standard 29 CFR 1910.1000 AIR CONTAMINANTS Table Z-1 OSHA Standard 29 CFR 1910.94 VENTILATION OSHA Standard 29 CFR 1910.134 RESPIRATORY PROTECTION OSHA Standard 29 CFR 1910.20 ACCESS TO EMPLOYEE EXPOSURE OSHA Standard 29 CFR 1910.132 PERSONAL PROTECTIVE EQUIPMENT OSHA Standard 29 CFR 1910.141 SANITATION OSHA Standard 29 CFR 1910.151 MEDICAL SERVICES AND FIRST AID OSHA Standard 29 CFR 1910.133 EYE AND FACE PROTECTION SECTION 8 EMERGENCY HANDLING OF HAZARDOUS MATERIALS IF MATERIAL IS ON FIRE OR INVOLVED IN FIRE:

Use water, alcohol foam or carbon dioxide CO 2 or dry chemical extinguishers or any agents suitable for surrounding fire. Keep material out of water sources and sewers.

IF MATERIAL IS NOT ON FIRE OR NOT INVOLVED IN FIRE: Keep material out of water sources and sewers.

PERSONAL DANGER SITUATION PROTECTION:

Keep upwind. Avoid breathing dust/vapors/fumes from material. Avoid bodily contact with material. Wear boots, protective gloves and gas-tight goggles. Wear full protective clothing (regular FIRE FIGHTERS' gear is inadequate).

Page 3

Applied Specialties, Inc. 071499838-5 33555 Pin Oak Parkway AS-9838 May 29, 2007 Avon Lake, Ohio 44012 Telephone (440) 933-9442 Emergency: (216) 973-6118 SECTION 9 SPILL, LEAK AND DISPOSAL PROCEDURES Persons not wearing protective equipment and clothing should be restricted from spill areas until clean-up has been completed. If AS-9838 is spilled, take the following steps:

1. Ventilate the spill area. Contain by diking.

2. Collect spilled material using an approved liquid vacuum for reuse.

3. Apply an absorbing compound to any residual material and shovel into a disposal drum.

4. Discard any vacuumed material and the absorbent material in accordance to all FEDERAL, STATE AND LOCAL REGULATIONS.

NOTE: DO NOT wash or pour AS-9838 into any surface waters or streams or directly into sewers.

SECTION 10 SHIPPING AND TRANSPORTATION DATA Drums and/or Bulk < 1,396 gallons or 15,355 lbs.

PROPER SHIPPING NAME Compounds, Boiler Cleansing, Preserving, Scale Preventing Or Scale Removing Liquid HAZARD CLASS None NFMC RATING 50093 SUB 2 LABEL REQUIRED None Bulk > 1,396 gallons or 15,355 lbs.

PROPER SHIPPING NAME Environmentally Hazardous Substance, Liquid, N. 0. S.,

(Sodium Bisulfite)

HAZARD CLASS 9 IDENTIFICATION NUMBER UN3082 PACKAGING GROUP III LABEL REQUIRED Class 9 T. L. Molnar/ H. Garcia-Mufioz This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation and verification. Before using any product, read its label carefully and completely.

Page 4

Applied Specialties, Inc. 071499838-5 33555 Pin Oak Parkway AS-9838 May 29, 2007 Avon Lake, Ohio 44012 Telephone (440) 933-9442 Emergency: (216) 973-6118 PENNSYLVANIA RIGHT-TO-KNOW INFORMATION The following comprises the CHEMICAL IDENTIFICATION list under PENNSYLVANIA RIGHT-TO-KNOW:

CAS #

Water 7732-18-5 Sodium Bisulfite 7631-90-5 Sodium Sulfite 7757-83-7 Potassium Bisulfite 7773-03-7 Potassium Sulfite 10117-38-7 NEW JERSEY RIGHT-TO-KNOW TOTAL INGREDIENTS LABEL:

CAS #

Water 7732-18-5 Sodium Bisulfite 7631-90-5 Sodium Sulfite 7757-83-7 Potassium Bisulfite 7773-03-7 Potassium Sulfite 10117-38-7 CALIFORNIA PROPOSITION 65:

This product does not contain toxic chemicals currently on the California list of known carcinogens and reproductive toxins Pursuant to the California Safe Drinking Water and Toxic Enforcement Act of 1986 (proposition 65), this information is provided. This law requires that" clear and reasonable warning" be provided to any individual, knowingly or intentionally exposed to any substances identified by the state as being cancer or reproductive hazards unless, it can be shown that the exposure poses "no significant risk". Based on available data, the following chemicals listed by Proposition 65 may be present in this product:

NO SUBSTANCES FOUND TO BE PRESENT IN DETECTABLE LEVELS.

Page 5

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

*

Section 1 - Chemical Product and Company Identification ***

Chemical Name: Sodium Metabisulphite (Technical, Photo and Food Grades) or Sodium Metabisulfite Product Use: For Commercial Use Synonyms: Disulfurous acid, Disodium salt, Fertisilo; Pyrosulfurous acid, disodium salt; Sodium disulfite; Disodium pyrosulfite; Sodium pyrosulfite.

Supplier Information Chem One Ltd. Phone: (713) 896-9966 8017 Pinemont Drive, Suite 100 Fax: (713) 896-7540 Houston, Texas 77040-6519 Emergency # (800) 424-9300 or (703) 527-3887 General Comments: FOR COMMERCIAL USE ONLY; NOT TO BE USED AS A PESTICIDE.

NOTE: Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service.

*

Section 2 - Composition / Information on Ingredients ***

I CAS # Component ]P erent 17681-57-4 1Sodium Metabisulfite > 95%

Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Sulfites.

Component Information/Information on Non-Hazardous Components This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

*

Section 3 - Hazards Identification ***

Emergency Overview Sodium Metabisulfite is a white crystal or white/yellow powder form. May cause severe allergic reaction in asthmatics and sulfite sensitive individuals. May be harmful if swallowed. May cause eye, skin and respiratory tract irritation. This product is not flammable. Thermal decomposition of this product produces irritating vapors and toxic gases (e.g. sulfur dioxide), which may increase fire hazard due to the flammability of sulfur dioxide. Emergency responders should wear proper personal protective equipment for the releases to which they are responding.

Hazard Statements WARNING! CAUSES SKIN AND EYE IRRITATION. HARMFUL IF INHALED. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. Keep from contact with clothing. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing dusts or particulates. Avoid prolonged or repeated contact with skin. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. WARNING! Contact with acids, water or ice releases sulfur dioxide gas which may be harmful or deadly if inhaled. Use of this product in confined spaces may cause suffocation leading to death. Do not use in unventilated areas such as in the holds of fishing boats, walk-in coolers or confined spaces. Use only in ventilated areas.

Potential Health Effects: Eyes Exposure to particulates or solution of this product may cause stinging, tearing and redness. Prolonged contact with solutions of this product may cause conjunctivitis, ulceration and comeal abnormalities.

Potential Health Effects: Skin This product can cause irritation of the skin, especially after prolonged exposures. Repeated skin contact may lead to skin sensitization, an allergic reaction and dermatitis (red, cracked skin). Skin contact can cause allergic skin reaction in susceptible individuals, with symptoms including itching, rash and welts.

Potential Health Effects: Ingestion Ingestion of this product can irritate the tissues of the mouth, esophagus, and other tissues of the digestive system. Symptoms of exposure can include central nervous system depression, gastrointestinal and cardiac abnormalities, and violent colic. Sulfite compounds, such as this product, can cause a severe allergic reaction in sensitive individuals and some asthmatics, which can be life-threatening.

Potential Health Effects: Inhalation Breathing dusts or particulates generated by this product can lead to irritation of the nose, throat or respiratory system. Symptoms of such exposure could include coughing and sneezing. This product can cause an asthma-like allergy with symptoms such as shortness of breath, wheezing, coughing, urticaria, angioedema, nasal congestion, nasal polyp swelling and chest tightness. Severe general (anaphylactic) reactions can occur, which can be life-threatening in some cases.

HMIS Ratings: Health Hazard: 2* Fire Hazard: 0 Physical Hazard: 1 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard Date: 09/09/98 09:52:46 Page 1 of8 Revision Date: 10/22/07 4:23 PM SEP Issue Date: 09/09/98 09:52:46IssueCLW PagelI of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

[ * *

Section 4 - First Aid Measures * *

First Aid: Eyes In case of contact with eyes, rinse immediately with plenty of water for at least 20 minutes. Seek immediate medical attention if any adverse effect occurs.

First Aid: Skin Remove all contaminated clothing. For skin contact, wash thoroughly with soap and water for at least 20 minutes. Seek immediate medical attention if irritation develops or persists.

First Aid: Ingestion Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim rinse mouth thoroughly with water, if conscious. Contact a physician or poison control center immediately. Never give anything by mouth to a victim who is unconscious or having convulsions.

First Aid: Inhalation Remove source of contamination or move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Get immediate medical attention.

First Aid: Notes to Physician Provide general supportive measures and treat symptomatically.

- - Section 5 - Fire Fighting Measures * **

Flash Point: Not flammable Method Used: Not applicable Upper Flammable Limit (UEL): Not applicable Lower Flammable Limit (LEL): Not applicable Auto Ignition: Not applicable Flammability Classification: Not applicable Rate of Burning: Not applicable General Fire Hazards When involved in a fire, this material may decompose and produce irritating vapors, acrid smoke and toxic gases (i.e. sulfur oxides and sodium oxides). Contact with acids, water and ice produces sulfur oxide, which presents a fire hazard due to its flammability.

Sodium Metabisulfite is a reducing agent and reacts explosively with oxidizers.

Hazardous Combustion Products Sodium sulfide and sulfur oxides.

Extinguishing Media In case of fire, use water fog, dry chemical, carbon dioxide or regular foam.

Fire Fighting Equipment/Instructions Firefighters should wear full protective clothing including self-contained breathing apparatus. If possible control runoff from fire control or dilution water to prevent environmental contamination.

NFPA Ratings: Health: 2 Fire: 0 Reactivity: 1 Other:

Hazard Scale: 0 = Minimal 1= Slight 2 = Moderate 3 = Serious 4 = Severe

*

Section 6 - Accidental Release Measures Containment Procedures Stop the flow of material, if this can be done without risk. Contain the discharged material. If sweeping of a contaminated area is necessary use a dust suppressant agent, which does not react with product (see Section 10 for incompatibility information).

Clean-Up Procedures Small releases can be cleaned-up wearing gloves, goggles and suitable body protection. In case of a large spill (in which excessive dusts can be generated), clear the affected area, protect people, and respond with trained personnel. Place all spill residues in an appropriate container and seal. Thoroughly wash the area after a spill or leak clean-up. Prevent spill rinsate from contamination of storm drains, sewers, soil or groundwater.

Evacuation Procedures Evacuate the area promptly and keep upwind of the spilled material. Isolate the spill area to prevent people from entering. In case of large spills, follow all facility emergency response procedures.

Special Procedures Remove soiled clothing and launder before reuse. Avoid all skin contact with the spilled material. Have emergency equipment readily available.

Page 2 of 8 Revision Date: 10/22/07 4:23 PM SEP Issue Date: 09/09/98 09:52:46IssueCLW Date: 09/09/98 09:52:46 Page 2 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

*

Section 7 - Handling and Storage Handling Procedures Do not breathe dust. Avoid all contact with skin and eyes. Use this product only with adequate ventilation. Wash thoroughly after handling. Avoid accumulation of dusts of this product. Remove contaminated clothing immediately. Keep in dust-tight containers. Keep away from all heat sources. Individuals responsible for the procurement, use or application of Sodium Metabisulfite must familiarize themselves with the appropriate safety and handling precautions involved. Specifically, for the prevention of Black Spot on shrimp, Sodium Metabisulfite should only be used as a dilute (1.25%) solution and only in well-ventilated area. NEVER USE SODIUM METABISULFITE IN A DRY FORM DIRECTLY ON THE SHRIMP AND NEVER IN A CONFINED SPACE SUCH AS THE HOLD OF A SHRIMP BOAT OR A WALK-IN COOLER. DEADLY SULFUR DIOXIDE GAS CAN BE GENERATED AND ACCUMULATED IN CONFINED SPACES, CREATING AN EXTREMELY HAZARDOUS CONDITION WHICH CAN CAUSE SUFFOCATION LEADING TO DEATH.

Storage Procedures All employees who handle this material should be trained to handle it safely. Open containers slowly on a stable surface. Containers of this product must be properly labeled. Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with care. Keep this product in an airtight container. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged. Do not store this material in open or unlabeled containers. Limit quantity of material stored.

Section 8 - Exposure Controls / Personal Protection ***

Exposure Guidelines A: General Product Information Sulfur Dioxide, which is released slowly at ambient temperatures from this material, has established exposure limits as follows:

ACGIH: 5.2 mg/m 3 TWA 13 mg/m3 STEL OSHA: 13 mg/m 3 TWA; 5 mg/m3(Vacated 1989 PEL) 13 mg/m 3 (Vacated 1989 PEL)

NIOSH: 5 mg/m3 TWA 13 mg/m 3 STEL 100 ppm (IDLH)

DFG MAKs 5.3 mg/mr3 TWA (Inhalable fraction of the aerosol)

I*MAK 15 min., average value, 1-hr interval B: Component Exposure Limits The exposure limits given are for Sodium Metabisulfite (7681-57-4).

ACGIH: 5 mg/mr3 TWA NIOSH: 5 mg/mr3 TWA Engineering Controls Use mechanical ventilation such as dilution and local exhaust, necessary for use in enclosed or confined spaces due to the slow release of sulfur dioxide. Use a corrosion-resistant ventilation system and exhaust directly to the outside. Treatment of exhaust gases may be required to prevent environmental contamination. Supply ample air replacement.

PERSONAL PROTECTIVE EQUIPMENT The following information on appropriatePersonalProtective Equipment is provided to assist employers in complying with OSHA regulationsfound in 29 CFR Subpart I (beginningat 1910.132). Pleasereference applicableregulations and standardsfor relevant details.

Personal Protective Equipment: Eyes/Face Wear safety glasses (or goggles). If necessary, refer to U.S. OSHA 29 CFR 1910.133.

Personal Protective Equipment: Skin Wear impervious gloves, boots and coveralls to avoid skin contact. Gloves should be tested to determine their suitability for prolonged contact with this material. If necessary, refer to U.S. OSHA 29 CFR 1910.138.

Issue Date: 09/09/98 09:52:46 CLW Page 3 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

*

Section 8 - Exposure Controls / Personal Protection (Continued) * *

Personal Protective Equipment: Respiratory If airborne concentration is high, use an appropriate respirator or dust mask. If airborne concentrations are above the applicable exposure limits, use NIOSH-approved respiratory protection. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).

Personal Protective Equipment: General Wash hands thoroughly after handling material. Do not eat, drink or smoke in work areas. Have a safety shower or eyewash fountain available. Use good hygiene practices when handling this material, including changing and laundering work clothes after use. Discard contaminated shoes and leather goods.

1* *

Section 9 - Physical & Chemical Properties **

Physical Properties: Additional Information The data provided in this section are to be used for product safety handling purposes. Please refer to Product Data Sheets, Certificates of Conformity or Certificates of Analysis for chemical and physical data for determinations of quality and for formulation purposes.

Appearance: White to yellowish crystalline powder Odor: Mild odor of rotten eggs (sulfurous)

Physical State: Solid pH: 4.5-5 (10% solution)

Vapor Pressure: Not applicable Vapor Density: Not applicable Boiling Point: Not applicable Freezing/Melting Point: 302 deg F (150 deg C)

Solubility (H20): 40% @ 20 deg C Specific Gravity: 1.4 (H20 = 1)

Softening Point: Decomposes upon heating Particle Size: Not determined Molecular Weight: 190.13 Bulk Density: 1.48 g/cc Chemical Formula: Na2S205

Section 10 - Chemical Stability & Reactivity Information ***

Chemical Stability Product is normally stable. Sodium Metabisulfite is air and moisture sensitive and releases sulfur dioxide slowly at ambient temperatures. Sodium Metabisulfite will decompose on heating to form sodium sulfate.

Chemical Stability: Conditions to Avoid Avoid moisture, high temperatures, exposure to air and incompatible materials.

Incompatibility This material is incompatible with strong oxidizers, sodium nitrite and alkalis. Sodium Metabisulfite may produce sulfur dioxide gas when in contact with acids and/or water and ice. Large-scale addition of solid sodium disulfite to an unstirred and too-concentrated solution of sodium nitrite may cause a vigorous exothermic reaction.

Hazardous Decomposition Products of thermal decomposition include sodium sulfate, sulfur oxides, and sodium oxide. Products of hydrolysis include sodium dioxide.

Hazardous Polymerization Will not occur.

*

Section 11 - Toxicological Information ***

Acute and Chronic Toxicity A: General Product Information May cause eye, skin, nose, throat and respiratory tract irritation. May be harmful if swallowed.

Chronic: Long term skin overexposure to this product may lead to dermatitis (red, itchy skin). Prolonged or repeated contact may cause allergic respiratory and skin reactions in sensitive individuals. Respiratory sensitization can be life-threatening in some cases.

B: Component Analysis - LD50/LC50 Sodium Metabisulfite (7681-57-4):

LD 50-lntravenous-rat: 115 mg/kg; LD 50-Parenteral-mouse: 910 mg/kg; LD 5o-Oral-mouse: 5989 mg/kg; LDLo-Intravenous-mouse:

1220 mg/kg; LD 50-Intravenous-rabbit: 1220 mg/kg Issue Date: 09/09/98 09:52:46 CLW Page 4 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

- - Section 11 - Toxicological Information (Continued) * *

Acute and Chronic Toxicity (continued):

B: Component Analysis - TDLo/LDLo Sodium Metabisulfite (7681-57-4):

LDLo-lntravenous-rabbit: 192 mg/kg; TDLo-Oral-rat: 75 mg/kg/15 days-continuous: Kidney, Urethra, Bladder: other changes; Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: phosphatases, Enzyme inhibition, induction, or change in blood or tissue levels:- dehydrogenases; TDLo - Oral - pig: 562 gn/kg/48 weeks-continuous: Liver: changes in liver weight Kidney, Urethra, Bladder: changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain; TDLo-Oral-rat: 20 gn/kg: multigenerations: Reproductive: Effects on Newborn: stillbirth; TDLo-Oral-rat: 40 gm/kg:

multigenerations: Reproductive: Effects on Newborn: weaning or lactation index (e.g., # alive at weaning per # alive at day 4);

Cytogenetic analysis-hamster Ovary: 180 pg/L; Sister chromatid exchange: Rodent-hamster Ovary: 200 pg/L; TDLo-Subcutaneous-mouse: 806 mg/kg/26 weeks-intermittent: Tumorigenic: equivocal tumorigenic agent by RTECS criteria Skin and Appendages:

tumors; TDLo-Oral-mouse: 14 gnmkg: female 8-12 day(s) after conception: Reproductive: Effects on Newborn: other neonatal measures or effects; TDLo-Parenteral-mouse: 60 mg/kg: female 8 day(s) after conception: Reproductive: Effects on Embryo or Fetus: fetotoxicity (except death, e.g., stunted fetus), Specific Developmental Abnormalities: musculoskeletal system Carcinogenicity A: General Product Information No information available.

B: Component Carcinogenicity Sodium Metabisulfite (7681-57-4)

ACGIH: TLV-A4 - Not classifiable as a Human Carcinogen Sulfur Dioxide (decomposition product)

ACGIH: TLV-A4 - Not classifiable as a Human Carcinogen IARC: Group 3 - Not classifiable as to carcinogenicity in humans.

Epidemiology Sodium metabisulfite has caused severe allergic reactions in asthmatics and sulfite sensitive individuals.

Neurotoxicity Has not been identified.

Mutagenicity Human mutation data are available for Sodium Metabisulfite, these data were obtained during clinical studies on specific human tissues exposed to high doses of this compound.

Teratogenicity Clinical studies on test animals exposed to relatively high doses of Sodium Metabisulfite provided teratogenic data.

Other Toxicological Information No information available.

*

Section 12 - Ecological Information ***

Ecotoxicity A: General Product Information This product is expected to be harmful to aquatic life in low concentration.

B: Ecotoxicity No information available.

Environmental Fate Sodium Metabisulfite:

Water Solubility = 470 g/L (20'C).

Chemical Oxygen Demand (COD) = 165 mg oxygen/g compound

- Section 13 - Disposal Considerations **

US EPA Waste Number & Descriptions A: General Product Information Sodium Metabisulfite is considered hazardous to the environment in aqueous solutions. EPA waste number for reactivity (D003) may be applicable to wastes of this product.

of 8 Revision Date: 10/22/07 4:23 PM SEP Issue Date: 09/09/98 09:52:46IssueCLWDate: 09/09/98 09:52:46 Page 55 of 8 Page Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

*

Section 13 - Disposal Considerations (Continued)

US EPA Waste Number & Descriptions (continued):

B: Component Waste Numbers No EPA Waste Numbers are applicable for this product's components.

Disposal Instructions All wastes must be handled in accordance with local, state and federal regulations or with regulations of Canada and its Provinces.

This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.

** Section 14 - Transportation Information ***

NOTE: The shipping classification information in this section (Section 14) is meant as a guide to the overall classification of the product. However, transportation classifications may be subject to change with changes in package size. Consult shipper requirements under l.M.O., I.C.A.O. (I.A.T.A.) and 49 CFR to assure regulatory compliance.

US DOT Information Shipping Name: Not Regulated Hazard Class: Not Classified UN/NA #: Not Classified Packing Group: None Required Label(s): None International Air Transport Association (IATA)

For Shipments by Air transport: We classify this product as hazardous (Class 9) when shipped by air because 49 CFR 173.140 (a).

"For the purposes of this subchapter, miscellaneous hazardous material (Class 9) means a material which presents a hazard during transportation, but which does not meet the definition of any other hazard class. This class includes: (a) Any material which has an anesthetic, noxious, or other similar property which could cause extreme annoyance or discomfort to a flight crew member so as to prevent the correct performance of assigned duties."

UN: UN 3077 Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s. (sodium metabisulfite)

Hazard Class: 9 Packing Group: Ill Passenger & Cargo Aircraft Packing Instruction: 911 Passenger & Cargo Aircraft Maximum Net Quantity: 400 kg Limited Quantity Packing Instruction (Passenger & Cargo Aircraft): Y911 Limited Quantity Maximum Net Quantity (Passenger & Cargo Aircraft): 30 kg Special Provisions: A97 A 149 ERG Code: 9L International Maritime Organization (I.M.O.) Classification Sodium Metabisulfite is not regulated under I.M.O.

*

Section 15 - Regulatory Information ***

US Federal Regulations A: General Product Information No additional information.

B: Component Analysis This material does not contain any chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A),

SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).

SARA 302 There are no specific Threshold Planning Quantities for Sodium Metabisulfite. The default Federal MSDS (EHS TPQ) submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20.

C: Sara 311/312 Tier II Hazard Ratings:

Component CAS # Fire Reactivity Pressure Immediate Chronic Hazard Hazard Hazard Health Hazard Health Hazard Sodium Metabisulfite 7681-57-4 No Yes No Yes Yes Revision Date: 10/22/07 4:23 PM SEP Date: 09/09/98 09:52:46 Issue Date: 09/09/98 09:52:46IssueCLW of 88 Page 66 of Page Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

*

Section 15 - Regulatory Information (Continued)

US Federal Regulations (continued)

U.S. State Regulations A: General Product Information California Proposition 65 Sodium Metabisulfite is not on the California Proposition 65 chemical lists.

B: Component Analysis - State The following components appear on one or more of the following state hazardous substance lists:

Component CAS # CA FL MA IMN INJ PAI Sodium Metabisulfite 7681-57-4 Yes Yes Yes Yes Yes No Other Regulations A: General Product Information No other information available.

B: Component Analysis - Inventory Component TCAS# TSCA DSL IEINCS Sodium Metabisulfite 7681-57-4 Yes Yes Yes C: Component Analysis - WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:

Component ICAS # I Minimum Concentration Sodium Metabisulfite 7681-57-4 1 percent ANSI LABELING (Z129.1):

WARNING! MAY BE FATAL IF SWALLOWED. CAUSES SKIN AND EYE IRRITATION. HARMFUL IF INHALED. MAY CAUSE ALLERGIC SKIN AND SEVERE RESPIRATORY REACTION. RESPIRATORY REACTIONS MAY BE LIFE-THREATENING. Keep from contact with clothing. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing dusts or particulates. Avoid prolonged or repeated contact with skin. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, faceshields, suitable body protection, and NIOSH!MSHA-approved respiratory protection, as appropriate. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO2 , or "alcohol" foam. IN CASE OF SPILL: Absorb spill with inert material. Place residue in suitable container. Consult Material Safety Data Sheet for additional information.

Issue Date: 09/09/98 09:52:46 CLW Page 7 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143 11 *** Section 16 - Other Information Other Information Chem One Ltd. ("Chem One") shall not be responsible for the use of any information, product, method, or apparatus herein presented ("Information"), and you must make your own determination as to its suitability and completeness for your own use, for the protection of the environment, and for health and safety purposes. You assume the entire risk of relying on this Information.

In no event shall Chem One be responsible for damages of any nature whatsoever resulting from the use of this product or products, or reliance upon this Information. By providing this Information, Chem One neither can nor intends to control the method or manner by which you use, handle, store, or transport Chem One products. If any materials are mentioned that are not Chem One products, appropriate industrial hygiene and other safety precautions reconmmended by their manufacturers should be observed. Chem One makes no representations or warranties, either express or implied of merchantability, fitness for a particular purpose or of any other nature regarding this information, and nothing herein waives any of Chem One's conditions of sale. This information could include technical inaccuracies or typographical errors. Chem One may make improvements and/or changes in the product (s) and/or the program (s) described in this information at any time. If you have any questions, please contact us at Tel. 713-896-9966 or E-mail us at Safetvy(aichemone.com.

Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration

Contact:

Sue Palmer-Koleman, PhD Contact Phone: (713) 896-9966 Revision Log 08/28/00 4:23 PM SEP Changed company name, Sect 1 and 16, from Corporation to Ltd.

06/02/01 9:31 AM HDF Checked exposure limits; made changes to Sect 9; overall review, add SARA 311/312 Haz Ratings.

08/20/01 3:20 PM CLJ Add Shipments by Air information to Section 14, Changed contact to Sue, non-800 Chemtrec Num.

02/18/02 11:13 AM HDF Up-date of SARA Hazard Ratings.

11/20/03 11:50 AM HDF General review and up-date of entire MSDS. Up-graded Section 10 Reactivity Information. Up-date of HMIS categories. Up-date of Section 8. Up-date of Section 14.

06/22/05 1:18 pm SEP Updated IATA Section 14 10/22/07 4:23 PM SEP Updated IATA Section 14 This is the end ofMSDS # C 1-143 Issue Date: 09/09/98 09:52:46 CLW Page 8 of 8 Revision Date: 10/22/07 4:23 PM SEP

GE Water & Process Technologies Issue Date: 29-APR-2009 Material Safety Data Sheet Supercedes: 10-NOV-2000 CORTROL OS5010 1 Identification Identification of substance or preparation CORTROL OS5010 Product Application Area Water based dissolved oxygen scavenger/metal passivator.

Company/Undertaking Identification GE Betz, Inc.

4636 Somerton Road Trevose, PA 19053 T 215 355-3300, F 215 953 5524 Emergency Telephone (800) 877-1940 Prepared by Product Stewardship Group: T 215-355-3300 Prepared on: 29-APR-2009 2 Hazard(s) identification EMERGENCY OVERVIEW DANGER Severe irritant to the skin. Absorbed by skin. Potential sensitizer. Corrosive to the eyes. Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract.

DOT hazard: Toxic Odor: Ammonia; Appearance: Colorless To Light Brown, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:

dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; Toxic; Severe irritant to the skin.

Absorbed by skin. Potential sensitizer.

ACUTE EYE EFFECTS:

Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:

Primary route of exposure;Vapors, gases, mists and/or aerosols Substance or Preparation: CORTROL OS5010 Page 1

cause irritation to the upper respiratory tract.

INGESTION EFFECTS:

Toxic; May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses.

TARGET ORGANS:

Repeated exposure may cause skin sensitization and/or toxicity to the liver, kidney, nervous system, and blood system. Component(s) may cause reproductive toxicity at maternal toxic levels. Limited evidence for increased risk of cancer.

MEDICAL CONDITIONS AGGRAVATED:

Pre-existing skin, liver or kidney disorders.

SYMPTOMS OF EXPOSURE:

Inhalation of vapors/mists/aerosols cause eye, nose, throat and lung irritation. Skin contact may cause redness, itching, dermatitis, or skin sensitization.

3 Composition I information on ingredients Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.

HAZARDOUS INGREDIENTS:

Cas# Chemical Name Range(w/w%)

302-01-2 HYDRAZINE 30-60 Corrosive; highly toxic (by skin absorption); toxic (by ingestion); possible human carcinogen (IARC=2B; NTP=anticipated) and liver, kidney, blood or reproductive toxin 4 First-aid measures SKIN CONTACT:

URGENT! Wash thoroughly with soap and water. Remove contaminated clothing. Get immediate medical attention. Thoroughly wash clothing before reuse.

EYE CONTACT:

URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.

INHALATION:

Remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. Get immediate medical attention.

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.

Substance or Preparation: CORTROL OS5010 Page 2

Rinse mouth with plenty of water. Dilute contents of stomach using 4-10 fluid ounces (120-300 mL) of milk or water.

NOTES TO PHYSICIANS:

Material is corrosive. It may not be advisable to induce vomiting.

Possible mucosal damage may contraindicate the use of gastric lavage.

5 Fire-fighting measures FIRE FIGHTING INSTRUCTIONS:

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:

oxides of nitrogen, ammonia FLASH POINT:

> 200F > 93C P-M(CC)

MISCELLANEOUS:

Toxic UN 3293;Emergency Response Guide #152 6 Accidental release measures PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.

Isolate spill by diking. Dilute spill to a 5% or less concentration. Neutralize with an equal amount of a 5% or less concentration of a hypochlorite solution.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.

7 Handling and storage HANDLING:

Basic. Vent slowly before opening. Do not mix with acidic material.

STORAGE:

Keep containers closed when not in use. Store in cool ventilated location. Store away from oxidizers. Shelf life 360 days.

8 Exposure controls / personal protection EXPOSURE LIMITS CHEMICAL NAME HYDRAZINE PEL (OSHA): 1.0 PPM(SKIN)

TLV (ACGIH) : 0.01 PPM(SKIN)-A3 ENGINEERING CONTROLS:

Adequate ventilation to maintain air contaminants below exposure Substance or Preparation: CORTROL OS5010 Page 3

limits.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

An air-supplying respirator (positive pressure full facepiece) may be needed for this product.

SKIN PROTECTION:

gauntlet type butyl or PVC gloves, impervious full body protective suit, rubber boots-- Wash off after each use.

Replace as necessary.

EYE PROTECTION:

splash proof chemical goggles, face shield 9 Physical and chemical properties Specific Grav.(70F,21C) 1.026 Vapor Pressure (mmHG) - 18.0 Freeze Point (F) < -30 Vapor Density (air=l) ~ 1.00 Freeze Point (C) < -34 Viscosity(cps 70F,21C) 10 % Solubility (water) 100.0 Odor Ammonia Appearance Colorless To Light Brown Physical State Liquid Flash Point P-M(CC) > 200F > 93C pH 1% Sol. (approx.) 10.5 Evaporation Rate (Ether=l) < 1.00 Percent VOC: 0.0 NA = not applicable ND = not determined 10 Stability and reactivity CHEMICAL STABILITY:

Stable under normal storage conditions.

POSSIBILITY OF HAZARDOUS REACTIONS:

No known hazardous reactions.

INCOMPATIBILITIES:

May react with strong oxidizers.

DECOMPOSITION PRODUCTS:

oxides of nitrogen, ammonia 11 Toxicological information Oral LD50 RAT: 185 mg/kg Reproductive Toxicity ANIMALS:

NOTE - Effects only at maternal toxic levels Carcinogenicity ANIMALS: Positive NOTE - Suspect human carcinogen Dermal LD50 RABBIT: 420 mg/kg Inhalation LC50 RAT: 1,600 ppm/4hr Non-Ames Mutagenicity : Positive Substance or Preparation: CORTROL OS5010 Page 4

12 Ecological information AQUATIC TOXICOLOGY No Data Available.

BIODEGRADATION No Data Available.

13 Disposal considerations If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is U133=Hydrazine.

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14 Transport information DOT HAZARD: Toxic PROPER SHIPPING NAME: HYDRAZINE AQUEOUS SOLUTION 6.1, UN 3293, PG III, RQ DOT EMERGENCY RESPONSE GUIDE #: 152 Note: Some containers may be DOT exempt, please check BOL for exact container classification 15 Regulatory information TSCA:

All components of this product are included on or are in compliance with the U.S. TSCA regulations.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

0.3 gallons due to HYDRAZINE; NSF Registered and/or meets USDA (according to 1998 Guidelines):

Registration number: Not Registered SARA SECTION 312 HAZARD CLASS:

Immediate(acute) ;Delayed(Chronic)

SARA SECTION 302 CHEMICALS:

CAS# CHEMICAL NAME 302-01-2 HYDRAZINE SARA SECTION 313 CHEMICALS:

CAS# CHEMICAL NAME RANGE 302-01-2 HYDRAZINE 31.0-40.0%

CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):

This product contains one or more ingredients known to the state of California to cause cancer.

Substance or Preparation: CORTROL OS5010 Page 5

MICHIGAN REGULATORY INFORMATION CAS# CHEMICAL NAME 302-01-2 HYDRAZINE 16 Other information HMIS vII CODE TRANSLATION Health 3 Serious Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special NONE No special Hazard (1) Protective Equipment X Ask Your Supervisor (1) refer to section 8 of MSDS for additional protective equipment recommendations.

CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 26-OCT-2000 ** NEW **

10-NOV-2000 4 26-OCT-2000 29-APR-2009 4,5,7,10 10-NOV-2000 Substance or Preparation: CORTROL OS5010 Page 6

FisherScientific Part of Thermo Fisher Scientifc MATERIAL SAFETY DATA SHEET ISection 1 - Chemical Product and Company Identification MSDS Name: Morpholine Catalog AC158680000, AC158680010, AC158680025, AC158680050, AC415160000. AC415160030 Numbers: AC415160030, AC415160050, 41516-5000, M263-1 Synonyms: 1-Oxa-4-azacyclohexane; Tetrahydro-2H-1.4-oxazine.

Company Identification, Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 For information in the US, call: 201-796-7100 Emergency Number US: 201-796-7100 CHEMTREC Phone Number, US: 800-424-9300

!Section 2.- Composion, Information on Ingredients CAS#: 110-91-8 Chemical Name: Morpholine EINECS#: 203-815-4 ols: C 10 2012112 34 I Section 3 - Hazards Identification I EMERGENCY OVERVIEW Dangeri Flammable liquid and vapor. Hygroscoplc (absorbs moisture from the air). Harmful if swallowed, inhaled, or absorbed through the skin, Causes bums by all exposure routes. Target Organs: Blood, kidneys, central nervous system, liver, spleen, lungs, respiratory system, eyes, skin.

Potential Health Effects Eye: Causes eye bums. Lachrymator (substance which increases the fiowof tears).

Skin: Harmful if absorbed through the skin. Causes skin bums.

Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Possible aspiration hazard, May cause lung damage.

Inhalation: Harmful if inhaled. Causes chemical burns to the respiratory tract.

Chronic: May cause liver and kidney damage. Repeated exposure may cause damage to the spleen. Chronic inhalation can cause pneumoconiosis. Adverse reproductive effects have been reported In animals.

Laboratory experiments have resulted in mutagenic effects. Chronic exposure may cause blood effects.

Exposure to high concentrations may cause central nervous system depression. Animal studies have reported the development of tumors.

Section 4- First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid Immediately.

Skin; Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes,

Ingestion: Potential for aspiration if swallowed: Get medical aid immediately.. Do riot induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs naturally, have victim lean forward.

Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately, Ifbreathing is difficult, give oxygen. bo'not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce*artiflci~lr-espiration with the aid of a pocket: mask equipped with a one-way valve or o0her proper respiratory medical deviceý Notes to Physician; Section 5 - Fire*Fightifg Measures.

General As in any fire, weaf a self-containecdlbreathinig~apparatus in Oressu*r-demand,.MSHAJNIOSH Information:* (approved or equivalent), and full protective:geaýr. Vapors mray forn an *ixplosive, mixture with air'.

Va pors can trael .to a sourceof Ignition and fash back.iWill,.burn if involved in a fire. Containers; may, explodeirf thd heat of a fire. Flammable liquid and vapor..

Extinguishing Use water spraoytocool fire-exposed: containers.,Use foam!sdry chemical, or ,c*rSbodihxide.

Media; Auto Ignition 255 degC ( 491.00 dog F).

Temperature:

Flash"0Po int: 32 deg.C ( 89.60 deg F)

Explosion 2 vol %

Limits: Lower:.

Explosion 11.2 viol %

Limits: Upper:

NFPA Rating:,health: 3; :fl'ammability: 3; instabilfty- 1:,

Section 6.*Accideritati: Rlease:Measures%

General UseIproper personal piecvve equipmentaS"indicated in.Se6ion*.

Information:

Spills/Leaks: Absbrb spillwith imemt rltaterialV(eg.. vermiculitI;=sanid ac i sste. ithnI etcone.otain e, .Wear-a:

Ss~if',ntained b.6eathing=apparatUs atnd'appr'prate*porsorIa protecti6n..(Se E osure0onir61s, Personal Plot&ction`s6etion) Renmgovieall sucsofigniton. Usea *p . I dhemical ehter theenvironment. * * "" "... t" .

.a . .t...... .e.... .

Sec tlon4 - Ha. lin. nd. .d Usespark-proof tools and exploslon proof equipment, D0onotget i*neyes, on sktn 0or on cl6thlTa!e precautionary measures against static discharges. Keep away from heat, spans-and flame. Do not'irngest or, Inhal.e. Use ohly in a chemical fume hood.

,Storage: Keep. away ftomi.sources~of ignitian;..Store ina cool, dry place. Store'.in a tighily.closed contalner.

Flarnmables-are.a

.... . .. .. Section ... 8- Exp'osure Controls, ... Personal. Protection 3Ls

,CJ ihemical .Name ACGfI" I [OSHA -, FinaliEsI

['OSH

-- ------ 7 ------ - -I I morpholine [20 ppm; Skin .2,0. .ppm TWA:. 70 [20. p5pm1 TWA; "70. 1 1 potential IM,9/M3 TWA 14.I I signif'icant 'pýpTDLN(o. l.(10t

.ohcribution. to Li I

+.'*-*'.,,r-

- ~1by

~I..

t-'-'-"

&utaneous r oýthe eI'

--+- . --

-*7.

=

7-

' * :*=*.* : "*

OSHAVVaatd Oki~: Morph6line 20 pmTV;70:rmglm3 TWA En glneering Control0s:

Use~exploslon-proof ve*ntilation equipment.,Facilities storing or utilizing.this miater(olshouldbe equipped with an eyewashfacility anda*safety shower. Use only under a chemical fume hood.'..'

Exposure Lirnmi Personal Protective Equipment

Eyes: Wear appropriate prolective eyeglasses or chemical safety goggles as described by OSHAseye.and face protection.regulations in 29 CFR1910.133 or European Standard EN166.

Skin:. Wear appropriate ptrtective gloves to prevent.skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.,

Respirators: A respiratory protectio program- hat-meets OSHA's 29 CFR 10.1 34.and ANSI Z88.2 requirements or European Standard EN 1491 must be followed whenever Workplace conditions warrant respirator use.

[............... Section 9:,-Physical and Chemical Properties Physical State: Liquid Color: APHA: 15 max, Odor:. haracteristic odor pH: Not available Va por Press.ure: '. .11 . bar. 20 deg C Vapor Densit':. 3.0 (airl.).

EvaporationRate: Notavailable VIPcosity 2.23 cP @ 20 deg C Boiling Point: 126 130 deg C @ 760 mmriHg Freezihg/Melting Point ,5deg C (23.00*F)

Decomposition Temperature: Not available So lubiliy itn water.,Miscible SpecificGravl~tyiDensity: 0.990

.Molecular;Eormula- =CAH9NO Molecular WeightV 87.12

.. .. . . .. Section*10;- Stability and:ReactivIt.y . . . .. ..... .........

Chemical Stability* Hygroscdpkc: absorbsmoisture or water from the air,.

Cgndiio~nsVtb 'Avoid,'.: ,tnc0.rniipatible matedras!,,ignition sources. excesshe~t. expps'ure to moist airbo w~terý incompatibilities with Other .'Strong bxi.iziig agents.:acids, aluminumr, nitriles (eg.: acetonitrile, mnthyl.

Hazardobus2edomppsit6n* Nitrogehoxides,.carbon: monoxide, carbon dioxide; ammonia.

Pi.odu ct..

Hazardous Polymerization. Has.notl;ien..reported. . ........

RTECS#: CAS# 110-91-8: QD6475000 LD50/LC50: RTECS. .

CAS#110-91-8: Dralze test, bbit'eye:2 mg Severe;"

Dralze tbst, -abbit, skin: 9956 rg/4H Severe:;

lnhalatio6nmouse: LC50 1i:320 mglrf3t2H1; lnhalation;,r*at: LC5§=8000;ppmI8H;:

Oral, OQral, mobuseý:

rat:, LD50=-*145052m5'rig/kg; `

mg/kg;

500 uLkg;K bSkin,.bit:,L050-CarcinogenicitI: Moipholine- lARC:'poup 3 (nogt classifiable),

Other: See actualentry in,RTECS~foe.rcompleteliiforrmatioi.

Section *ý .J- . ifo.. tbni .c.6g`. .....

Ecoto'xicity Vaefe ~hi LC5~0 .(J1rn0gý; 24WH'; Unspecified.

F..h:..

ihiegilliSunfish:

.. LCQ=350i.0mg/L; 96 Hr.; Static conditions, 184*22 Bactria: Phytbactierium phosphorehm: EC50=37mg/L; 30Irin.,; Milcbtx test, Other: ..Do hot empty into drai6,s.

I ~~Section 13 -isoal Coi'isidJe:***

Dispose of in a manner consistent With federal, state,.and local regulations.

i S*e.ition 14- Transport Ilnf.or ,intion I:

US'DOT

,Shipping Name: MORPHOLINE' Hazard C6ass; 8 UN Number-'UN2054 Packing Group-I4

'-Canada TDG."

Shipping' Name;, MORPHOLINE, Haz.ard'Class:.8 UN Nimrbe,: UN2054 Packing Group;:l.

Section:15.- Requl~ator Ibformation.

Europeanllnternational.Regulations.

Eyd*rpean .LbelingWin Adcrdancewith EC Directives%

Hazard Symbilios: C R.isk Ph.rqses Rk160Famima6lIe.

R 20/21/22 Harrnfulb iynhalation, in contact withskin an, if swallowed.

R 34 Causes*b*rns.

SafetY Ph~s'e: *

S 23 Do not inhale gas/furnes/vaeOur/sprayY.

.S 36; Wear suitable protective clothing.

S 45,In case 6fobdcident4orif you feel unw e ,medicaladvice Immediately (show the iabelSwhere poslble).

!WGK.(Wapter Dan.ger/Protection)

Ck$# 11091-8:2.

.'Canada .

,CAS#1tfoz191-8islisted on C0nadasSL, LisL.

.CanadianNWHMifClassifiGatlons:.B2,i Bib, This pr6duct hasbeeh'Sifi*i acordance With the hazard criteriaof the Controlled Pro*0*cts

ý,.Regulations and the;MSDS.. nltains all of the information.re.,lred by those reulations.

SCAS#.**tl1isited on .Cna.. a's Indredient.DisclosureList.

&S:F'eder~i~i oTSCA',

CAS#&!i 0-91is 11!1i S.eddh the TSCA Inventory.

.. c i 16...

... .t .Se i. o r,.tio n . .. ,*nf

"..MSDS Creation Date. 6... .1999 .. ............

Revision #13. Dat6 307ii608ý,

Revisionswere..made inSections:..33, 6 6,5, 89i

'7, 610,11 the~informatlon above is believedtobe accurate and represents the best.information currently available to- us. However, we make.nowarranty of merchantibility or any other warranty expresrsor

iftiplied, with respect to such information, an.we :asume no0 iability rieulit[g frot M6.use. Users shoui*dmake',their owririnvestigations todetermind.thelsuitabilityýof the infdrmnation'f0r their-Oiarticuiar .urposes. Inlno event'shall the comp anybe:Iiable for ny clai is ses,., or damages of any thirdp"artyadr for:lost profit.:or any special, indirect; incidental, consequential,. r exemplary

damageshowsoevearising" even if the-company. ha been.advised of.the possibility of such

Science Lab.com

.chmicas &Laboratory Equipment Personal E Protection Material Safety Data Sheet Hydroquinone MSDS Seton1 Ceial Produc and Copan Idetiicaio Product Name: Hydroquinone Contact Information:

Catalog Codes: SLH 1351, SLH2197 Sciencelab.com, Inc.

14025 Smith Rd.

CAS#: 123-31-9 Houston, Texas 77396 RTECS: MX3500000 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 TSCA: TSCA 8(b) inventory: Hydroquinone Order Online: ScienceLab.com CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:

Synonym: 1,4-Benzenediol 1-800-424-9300 Chemical Name: 1,4-Dihydroxybenzene International CHEMTREC, call: 1-703-527-3887 Chemical Formula: C6H4(OH)2 For non-emergency assistance, call: 1-281-441-4400 Composition:

Name CAS # % by Weight Hydroquinone 123-31-9 100 Toxicological Data on Ingredients: Hydroquinone: ORAL (LD50): Acute: 320 mg/kg [Rat.]. DERMAL (LD50): Acute: 5970 mg/kg [Mammal].

Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, the nervous system, mucous membranes.

Repeated or prolonged exposure to the substance can produce target organs damage.

Eye

Contact:

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

p. 1

Skin

Contact:

After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.

Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin

Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.

Ingestion:

Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and' Explosion Data :>.*...:

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: 515.56°C (960'F)

Flash Points: CLOSED CUP: 165°C (329°F).

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, C02).

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Combustible when exposed to heat or flame.

Special Remarks on Explosion Hazards: Not available.

SSection'6: Accidental Release Measures . .:.

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill:

Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

p7: Hanling And aSnct.Storage.:

Precautions:

p. 2

Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents, alkalis.

Storage:

Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents.

Sectiond8.: ExposuLe Contr lspersqnal protection, Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Personal Protection:

Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Exposure Limits:

TWA: 0.4 (ppm) TWA: 2 (mg/m3) Consult local authorities for acceptable exposure limits.

Section 9:i Physical and Chemical Properties ",

Physical state and appearance: Solid. (Crystals solid.)

Odor: Not available.

Taste: Not available.

Molecular Weight: 110.11 g/mole Color: White.

pH (1% solnlwater): 7 [Neutral.]

Boiling Point: 286°C (546.8°F)

Melting Point: 170°C (338°F)

Critical Temperature: Not available.

Specific Gravity: 1.33 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: 3.81 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

lonicity (in Water): Not available.

Dispersion Properties: See solubility in water, methanol, diethyl ether.

Solubility: Soluble in cold water, hot water, methanol, diethyl ether.

p. 3

Section 10: Stability andýReactivity Data' Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Reactive with oxidizing agents, alkalis.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Air and light sensitive.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

Section 11.: Toxicological Information Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:

Acute oral toxicity (LD50): 320 mg/kg [Rat.]. Acute dermal toxicity (LD50): 5970 mg/kg [Mammal].

Chronic Effects on Humans: The substance is toxic to lungs, the nervous system, mucous membranes.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: An allergen.

Special Remarks on other Toxic Effects on Humans: Material is irritating to mucous membranes and upper respiratory tract.

Sectidn 12: Ecobogicalnlon*m atiodn Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.

Special Remarks on the Products of Biodegradation: Not available.

Section13: Disposal C nsiderati*"n Waste Disposal:

... .~~ Section 14: Transport In-fo pion

-inrma DOT Classification: CLASS 6.1 Poisonous material.

Identification: : Hydroquinone: UN2662 PG: III Special Provisions for Transport: Not available.

p. 4

Section 15: Other Regulato rynformatiin Federal and State Regulations:

Pennsylvania RTK: Hydroquinone Massachusetts RTK: Hydroquinone TSCA 8(b) inventory: Hydroquinone SARA 302/304/311/312 extremely hazardous substances: Hydroquinone SARA 313 toxic chemical notification and release reporting:

Hydroquinone CERCLA: Hazardous substances.: Hydroquinone Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):

CLASS D-1 B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC): R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 2 Fire Hazard: 1 Reactivity: 0 Personal Protection: E National Fire Protection Association (U.S.A.):

Health: 2 Flammability: 1 Reactivity: 0 Specific hazard:

Protective Equipment:

Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

Sec§q"tio

" 1"6: Other Info mation __ ' ;*A.

References:

-Hawley, G.G.. The Condensed Chemical Dictionary, l1 e ed., New York N.Y., Van Nostrand Reinold, 1987. -Material safety data sheet emitted by: la Commission de la SantA© et de la SA©curitA©du Travail du QuA©bec. -SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of Chemical Safety Data, Edition II. -Guide de la loi et du rA',glement sur le transport des marchandises dangeureuses au canada. Centre de conformitA© internatinal LtA©e. 1986.

Other Special Considerations: Not available.

Created: 10/11/2005 12:06 PM Last Updated: 06/09/2012 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warrantyof merchantabilityor any other warranty,express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for theirparticularpurposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequentialor exemplary damages, howsoever arising,even if ScienceLab.com has been advised of the possibilityof such damages.

p. 5

MATERIAL SAFETY DATA SHEET A;&ANTori

1. Product and Company Identification Material name AMMONIUM HYDROXIDE Version # 08 Revision date 03-06-2012 CAS # Mixture Product Codes J.T.Baker: 0889, 4807, 5358, 5604, 5817, 5820, 5980, 5993, 7874, 9717, 9718, 9719, 9721, 9729, 9731, 9733, 9741, 9743 Macron: 0127, 3246, 3256, 3258, 3261, 37826, 6665, H893, IM0889, IM5980, V006, V188, V222, V649, V893, XL002, XM187, XM189 Synonym(s) Ammonia aqueous

Ammonia solutions Manufacturer Avantor Performance Materials, Inc.

Address 3477 Corporate Parkway Suite #200 Center Valley, PA 18034 US Customer Service 855-282-6867 24 Hour Emergency 908-859-2151 Chemtrec 800-424-9300

2. Hazards Identification Emergency overview DANGER Corrosive. Causes severe skin and eye burns. Causes digestive tract burns. Harmful if swallowed.

Mist or vapor extremely irritating to eyes and respiratory tract.

OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

Potential health effects Routes of exposure Ingestion. Inhalation. Skin contact. Eye contact.

Eyes Corrosive. Causes severe eye burns. Vapor or spray may cause eye damage, impaired sight or blindness.

Skin Corrosive. Causes severe skin burns.

Inhalation Corrosive. May cause damage to mucous membranes in nose, throat, lungs and bronchial system.

Ingestion Harmful if swallowed. Corrosive. Ingestion may produce bums to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract.

Target organs Eyes. Skin. Respiratory system.

Chronic effects Corrosive. Prolonged contact causes serious tissue damage.

Potential environmental effects Expected to be very toxic to aquatic organisms.

3. Composition / Information on Ingredients Hazardous components CAS # Percent AMMONIUM HYDROXIDE 1336-21-6 18-72 Non-hazardous comoonents CAS # Percent WATER 7732-18-5 28 - 82 Composition comments Contains 10 - 35% NH3.

Material name: AMMONIUM HYDROXIDE MSDS US COV MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 1/7

4. First Aid Measures First aid procedures Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. In case of irritation from airborne exposure, move to fresh air. Get medical attention immediately.

Skin contact Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician or poison control center immediately. Wash clothing separately before reuse. Destroy or thoroughly clean contaminated shoes.

Inhalation Move to fresh air. If breathing stops, provide artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs.

Notes to physician Keep victim under observation. Treat symptomatically.

General advice In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Show this safety data sheet to the doctor in attendance. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire Fighting Measures Flammable properties The product is not flammable. No unusual fire or explosion hazards noted.

Extinguishing media Suitable extinguishing Water spray. Carbon dioxide (C02). Dry chemical powder. Foam.

media Unsuitable extinguishing None known.

media Protection of firefighters Specific hazards arising Fire may produce irritating, corrosive and/or toxic gases.

from the chemical Protective equipment and Use water spray to cool unopened containers. Self-contained breathing apparatus and full precautions for firefighters protective clothing must be worn in case of fire. Cool containers exposed to flames with water until well after the fire is out.

Special protective equipment for Wear full protective clothing, including helmet, self-contained positive pressure or pressure fire-fighters demand breathing apparatus, protective clothing and face mask. Wear self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode when fighting fires.

Specific methods In the event of fire and/or explosion do not breathe fumes.

6. Accidental Release Measures Personal precautions Wear appropriate protective equipment and clothing during clean-up. Keep unnecessary personnel away. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering them. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Local authorities should be advised if significant spillages cannot be contained.

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.

Methods for containment Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or confined areas. Dike the spilled material, where this is possible.

Material name: AMMONIUM HYDROXIDE MSDS US COy MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 2/7

Methods for deaning up Large Spills: Neutralize spill area and washings with dilute acetic acid. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Dike far ahead of spill for later disposal.

Small Spills: Neutralize spill area and washings with dilute acetic acid. Wipe up with absorbent material (e.g. cloth, fleece). Collect in a non-combustible container for prompt disposal.

Never return spills in original containers for re-use. Clean surface thoroughly to remove residual contamination. Clean up in accordance with all applicable regulations.

J. T. Baker NEUTRACITO-2 or BuCAIM caustic neutralizers are recommended for spills of solutions of this product.

7. Handling and Storage Handling Wear appropriate personal protective equipment. Do not breathe mist or vapor. Do not get in eyes, on skin, on clothing. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Do not eat, drink or smoke when using the product. Considerable heat is generated when water or acid is added, therefore when making solutions always add the caustic to the water or acid with constant stirring. See Section 8 of the MSDS for Personal Protective Equipment.

Storage Do not store in metal containers. Keep tightly closed in a dry, cool and well-ventilated place.

8. Exposure Controls / Personal Protection ACGIH Components Type Value AMMONIUM HYDROXIDE (1336-21-6) STEL 35.0000 ppm TWA 25.0000 ppm Occupational exposure limits U.S. - OSHA Components Type Value AMMONIUM HYDROXIDE (1336-21-6) PEL 50.0000 ppm 35.0000 mg/m3 Engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Explosion proof exhaust ventilation should be used.

Personal protective equipment Eye/ face protection Chemical goggles and face shield are recommended.

Skin protection Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant gloves.

Respiratory protection Ifengineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respirator type: Chemical respirator with specific cartridge and full facepiece providing protection against the compound of concern.

General hygeine Provide eyewash station and safety shower. Always observe good personal hygiene measures, considerations such as washing after handling the material and before eating, drinking, and/or smoking.

Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical & Chemical Properties Appearance Clear.

Color Colorless.

Odor Ammoniacal.

Odor threshold Not available.

Material name: AMMONIUM HYDROXIDE MSDS US COV MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 3/7

Physical state Liquid.

Form Liquid.

pH 13.8 (29% NH3)

Melting point -101.6 -F (-74.4 0C) (28.5% NH3)

Freezing point -101.6 -F (-74.4 0C) (28.5% NH3)

Boiling point 81 -F (27.2 =C) (29.4% NH3)

Flash point Not available.

Evaporation rate Not available.

Flammability limits in air, upper, 28 % (NH3)

% by volume Flammability limits in air, lower, 15 % (NH3)

% by volume Vapor pressure 287.971 kPa Specific gravity 0.9 (28% NH3)

Relative density Not available.

Solubility (water) Not available.

Partition coefficient Not available (n-octanol/water)

Decomposition temperature Not available.

Molecular weight 35.05 Molecular formula H5-N-O

10. Chemical Stability & Reactivity Information Chemical stability Stable under normal temperature conditions.

Conditions to avoid Excessive heat.

Incompatible materials Strong oxidizing agents. Water. Acids. Metals. Halogens. Nitromethane.

Hazardous decomposition Ammonia. Nitrogen oxides (NOx).

products Possibility of hazardous Hazardous polymerization does not occur.

reactions

11. Toxicological Information Toxicological data Components Test Results AMMONIUM HYDROXIDE (1336-21-6) Acute Oral LD50 Rat: 350 mg/kg Sensitization Not a skin sensitizer.

Acute effects Harmful if swallowed.

Local effects Causes severe burns. Mist or vapor extremely irritating to eyes and respiratory tract.

Chronic effects Corrosive. Prolonged contact causes serious tissue damage.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

Skin corrosion/irritation Corrosive to skin and eyes.

Epidemiology No epidemiological data is available for this product.

Mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Reproductive effects Contains no ingredient listed as toxic to reproduction Teratogenicity No data available to indicate product or any components present at greater than 0.1% may cause birth defects.

Symptoms and target Corrosive effects.

organs Material name: AMMONIUM HYDROXIDE MSDS us coY MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 4/7

Further information Danger of very serious irreversible effects. Symptoms may be delayed.

12. Ecological Information Ecotoxicological data Components Test Results Components Test Results AMMONIUM HYDROXIDE (1336-21-6) LC50 Water flea (Daphnia magna): 0.66 mg/I 48.00 hours0 days 0 hours 0 weeks 0 months LC50 Western mosquitofish (Gambusia affinis): 15 mg/I 96.00 hours0 days 0 hours 0 weeks 0 months Ecotoxicity Expected to be very toxic to aquatic organisms.

Environmental effects Very toxic to aquatic organisms. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Persistence and Expected to be readily biodegradable.

degradability Partition coefficient Not available (n-octanol/water)

13. Disposal Considerations Waste codes D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]

Disposal instructions Dispose of this material and its container to hazardous or special waste collection point.

Incinerate the material under controlled conditions in an approved incinerator. All wastes must be handled in accordance with local, state and federal regulations.

Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container is emptied. Offer rinsed packaging material to local recycling facilities.

14. Transport Information DOT Basic shipping requirements:

UN number UN2672 Proper shipping name Ammonia solution (with 10 - 35% ammonia)

Hazard class 8 Packing group III Additional information:

Special provisions 1B3, IP8, T7, TP1 Basic shipping requirements:

Labels required 8 Additional information:

Packaging exceptions 154 Packaging non bulk 203 Packaging bulk 241 ERG number 154 IATA Basic shipping requirements:

UN number 2672 Proper shipping name Ammonia solution (with 10 - 35% ammonia)

Hazard class 8 Packing group III Additional information:

ERG code 8L IMDG Basic shipping requirements:

UN number 2672 Proper shipping name AMMONIA SOLUTION (WITH 10 - 35% AMMONIA)

Material name: AMMONIUM HYDROXIDE MSDS US COV MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 5/7

Hazard class 8 Packing group III A c-e 1ýb

//02ir=,,Ný /Azr Il X, '.

DOT IATA IMDG

15. Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

All components are on the U.S. EPA TSCA Inventory List.

US EPCRA (SARA Title Ill) Section 313 - Toxic Chemical: De minimis concentration AMMONIUM HYDROXIDE (CAS 1336-21-6) 1.0 %

US EPCRA (SARA Title Ill) Section 313 - Toxic Chemical: Listed substance AMMONIUM HYDROXIDE (CAS 1336-21-6) Listed.

CERCLA (Superfund) reportable quantity AMMONIUM HYDROXIDE: 1000.0000 Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 311 hazardous Yes chemical Inventory status Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes

A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.

US - Pennsylvania RTK - Hazardous Substances: Listed substance AMMONIUM HYDROXIDE (CAS 1336-21-6) Listed.

Material name: AMMONIUM HYDROXIDE MSDS us coV MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 6/7

Saf-T-Data Health: 2 - Moderate (Poison)

Flammability: 1 - Slight Reactivity: 1 - Slight

Contact:

4 - Extreme (Corrosive)

Lab Protective Equip: D - GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: WS - White Stripe (Store Separately)

16. Labeling Info Label Hazard Warning DANGER Corrosive. Causes severe skin and eye burns. Causes digestive tract burns. Harmful if swallowed.

Mist or vapor extremely irritating to eyes and respiratory tract.

Label Precautions Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Do not taste or swallow.

Use only with adequate ventilation. Wash thoroughly after handling. Keep container tightly closed in a cool, well-ventilated place.

Label First Aid Immediately flush eyes with plenty of water for at least 15 minutes. Immediately flush skin with plenty of water. If gaslfume/vapor/dustlmist from the material is inhaled, remove the affected person immediately to fresh air. Get medical attention immediately. IF SWALLOWED:

Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance.

17. Other Information NFPA ratings Health: 3 Flammability: 1 Instability: 0 Disclaimer THE INFORMATION PRESENTED IN THIS MATERIAL SAFETY DATA SHEET (MSDS/SDS)

WAS PREPARED BY TECHNICAL PERSONNEL BASED ON DATA THAT THEY BELIEVE IN THEIR GOOD FAITH JUDGMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED HEREIN IS PROVIDED "AS IS," AND AVANTOR PERFORMANCE MATERIALS MAKES AND GIVES NO REPRESENTATIONS OR WARRANTIES WHATSOEVER, AND EXPRESSLY DISCLAIMS ALL WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT TO WHICH IT RELATES, WHETHER EXPRESS, IMPLIED, OR STATUTORY, INCLUDING WITHOUT LIMITATION, WARRANTIES OF ACCURACY, COMPLETENESS, MERCHANTABILITY, NON-INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY, STABILITY, AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES ARISING FROM COURSE OF DEALING, COURSE OF PERFORMANCE, OR USAGE OF TRADE. THIS MSDS/SDS IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT, AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER AND CONDITIONS OF USE, HANDLING, STORAGE, OR DISPOSAL OF THE PRODUCT. INDIVIDUALS RECEIVING THIS MSDS/SDS MUST ALWAYS EXERCISE THEIR OWN INDEPENDENT JUDGMENT IN DETERMINING THE APPROPRIATENESS OF SUCH ISSUES. ACCORDINGLY, AVANTOR PERFORMANCE MATERIALS ASSUMES NO LIABILITY WHATSOEVER FOR THE USE OF OR RELIANCE UPON THIS INFORMATION. NO SUGGESTIONS FOR USE ARE INTENDED AS, AND NOTHING HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL, STATE, LOCAL, OR FOREIGN LAWS. AVANTOR PERFORMANCE MATERIALS REMINDS YOU THAT IT IS YOUR LEGAL DUTY TO MAKE ALL INFORMATION IN THIS MSDS/SDS AVAILABLE TO YOUR EMPLOYEES.

Issue date 03-06-2012 Material name: AMMONIUM HYDROXIDE MSDSus cOv MSDS ID: A5916 Version #: 08 Revision date: 03-06-2012 7/7

GE Water & Process Technologies Issue Date: 12-FEB-2009 Material Safety Data Sheet Supercedes: 10-DEC-2007 SPECTRUS CT1 300 1 Identification Identification of substance or preparation SPECTRUS CT1300 Product Application Area Water-based microbial control agent.

Company/Undertaking Identification GE Betz, Inc.

4636 Somerton Road Trevose, PA 19053 T 215 355-3300, F 215 953 5524 Emergency Telephone (800) 877-1940 Prepared by Product Stewardship Group: T 215-355-3300 Prepared on: 12-FEB-2009 2 Hazard(s) identification EMERGENCY OVERVIEW DANGER Corrosive to skin. Potential skin sensitizer. Corrosive to the eyes. Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract.

DOT hazard: Corrosive to skin, Flammable Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:

dry chemical, carbon dioxide or foam--Avoid water if possible.

POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; Corrosive to skin. Potential skin sensitizer.

ACUTE EYE EFFECTS:

Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:

Vapors, gases, mists and/or aerosols may cause irritation to upper Substance or Preparation: SPECTRUS CTI 300 Page I

respiratory tract.

INGESTION EFFECTS:

Toxic; May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses.

TARGET ORGANS:

Prolonged or repeated exposures may cause CNS depression, tissue narcoses, skin sensitization, and/or toxicity to the liver and kidney.

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSURE:

Inhalation of vapors/mists/aerosols may cause eye, nose, throat and lung irritation. Skin contact may cause severe irritation or burns.

3 Composition / information on ingredients Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.

HAZARDOUS INGREDIENTS:

Cas# Chemical Name Range(w/w%)

68424-85-1 (CI2-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE 40-70 Corrosive (eyes and skin);toxic (by ingestion) 64-17-5 ETHYL ALCOHOL 7-13 Flammable liquid; irritant (eyes); may cause CNS depression; potential liver, kidney, brain, heart and male reproductive toxin; produced mutagenic effects in germ cells and somatic cells (in vivo) 4 First-aid measures SKIN CONTACT:

URGENT! Wash thoroughly with soap and water. Remove contaminated clothing. Get immediate medical attention. Thoroughly wash clothing before reuse.

EYE CONTACT:

URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.

INHALATION:

Remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. Get immediate medical attention.

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive Substance or Preparation: SPECTRUS CT1300 Page 2

victim. Dilute contents of stomach. Induce vomiting by one of the standard methods. Immediately contact a physician.

NOTES TO PHYSICIANS:

Material is corrosive. It may not be advisable to induce vomiting.

Possible mucosal damage may contraindicate the use of gastric lavage.

5 Fire-fighting measures FIRE FIGHTING INSTRUCTIONS:

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical, carbon dioxide or foam--Avoid water if possible.

HAZARDOUS DECOMPOSITION PRODUCTS:

oxides of carbon and nitrogen, hydrogen chloride FLASH POINT:

130F 54C P-M(CC)

MISCELLANEOUS:

Corrosive to skin, Flammable UN 2920;Emergency Response Guide 4132 6 Accidental release measures PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.

Remove ignition sources. Flush area with water. Spread sand/grit.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to label instructions.

7 Handling and storage HANDLING:

Combustible. Corrosive to skin and/or eyes.

STORAGE:

Keep containers closed when not in use. Keep away from flames or sparks. Bond containers during filling or discharge when performed at temperatures at or above the product flash point. Shelf life 360 days.

8 Exposure controls / personal protection EXPOSURE LIMITS CHEMICAL NAME (C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE PEL (OSHA): NOT DETERMINED TLV (ACGIH) : NOT DETERMINED ETHYL ALCOHOL Substance or Preparation: SPECTRUS CT1 300 Page 3

PEL (OSHA) : 1,000 PPM TLV (ACGIH) : 1,000 PPM ENGINEERING CONTROLS:

Adequate ventilation to maintain air contaminants below exposure limits.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use organic vapor cartridges and any of the following particulate respirators: N95, N99, N100, R95, R99, R100, P95, P99 or P100.

SKIN PROTECTION:

gauntlet-type rubber, butyl or neoprene gloves, chemical resistant apron -- Wash off after each use. Replace as necessary.

EYE PROTECTION:

splash proof chemical goggles, face shield 9 Physical and chemical properties Specific Grav.(70F,21C) 0.965 Vapor Pressure (mmHG) 44.0 Freeze Point (F) -7 Vapor Density (air=l) < 1.00 Freeze Point (C) -22 Viscosity(cps 70F,21C) 73 % Solubility (water) 100.0 Odor Mild Appearance Colorless To Yellow Physical State Liquid Flash Point P-M(CC) 130F 54C pH As Is (approx.) 8.9 Evaporation Rate (Ether=l) < 1.00 Percent VOC: ND NA = not applicable ND = not determined 10 Stability and reactivity CHEMICAL STABILITY:

Stable under normal storage conditions.

POSSIBILITY OF HAZARDOUS REACTIONS:

INCOMPATIBILITIES:

May react with strong oxidizers.

DECOMPOSITION PRODUCTS:

oxides of carbon and nitrogen, hydrogen chloride 11 Toxicological information Substance or Preparation: SPECTRUS CT1300 Page 4

Oral LD50 RAT: 445 mg/kg Dermal LD50 RABBIT: >1,800 mg/kg Skin Sensitization G.PIG: NEGATIVE NOTE - Active component was neither a photoallergen nor a skin sensitizer 12 Ecological information AQUATIC TOXICOLOGY Annelida(Lumbriculus variegatus) 96 Hour Acute Toxicity LC50= 1.47; LCl0= .37 mg/L Benthic Crustacean(Gammerus pseutolimnaeus) 96 Hour Acute Toxicity LC50= .07 mg/L Ceriodaphnia 48 Hour Static Renewal Bioassay LC50= .35; No Effect Level= .15 mg/L Ceriodaphnia 7 Day Chronic Bioassay IC25 = .098 mg/L Channel Catfish 96 Hour Acute Toxicity LC50= .86; No Effect Level= .54 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay LC50= .04; No Effect Level= .026 mg/L Daphnia magna 48 Hour Static Acute Bioassay LC50= .11; No Effect Level= .06 mg/L Daphnia pulex 48 Hour Static Renewal Bioassay LC50= .05; No Effect Level= .031 mg/L Fathead Minnow 7 Day Chronic Bioassay IC25 = .259 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay LC50= .72; No Effect Level= .41 mg/L Freshwater Snail(Physa sp.) 96 Hour Acute Toxicity LC50= .46; No Effect Level= .36 mg/L Menidia beryllina (Silversides) 96 Hour Flow-Thru Bioassay LC50= .62; No Effect Level= .35 mg/L Midge larvae (Chironomus tentans) 96 Hour Acute Toxicity LC50= .5; No Effect Level= .13 mg/L Mysid Shrimp 96 Hour Flow-Thru Bioassay LC50= .16; No Effect Level= .03 mg/L Rainbow Trout 96 Hour Flow-Thru Bioassay LC50= 2; No Effect Level= 1.2 mg/L Sheepshead Minnow 96 Hour Flow-Thru Bioassay LC50= 1.76; No Effect Level= 1 mg/L No Data Available.

BIODEGRADATION BOD-28 (mg/g): 156 BOD-5 (mg/g): 43 COD (mg/g): 1470 TOC (mg/g): 380 13 Disposal considerations Substance or Preparation: SPECTRUS CT1300 Page 5

If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Exempt D001 per 40 CFR 261.21(a) (1).

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14 Transport information DOT HAZARD: Corrosive to skin, Flammable PROPER SHIPPING NAME: CORROSIVE LIQUIDS, FLAMMABLE, N.O.S.(QUATERNARY AMMONIUM COMPOUNDS, ETHYL ALCOHOL) 8(3), UN 2920, PG II DOT EMERGENCY RESPONSE GUIDE #: 132 Note: Some containers may be DOT exempt, please check BOL for exact container classification 15 Regulatory information TSCA:

This is an EPA registered biocide and is exempt from TSCA inventory requirements.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:

3876- 149 FOOD AND DRUG ADMINISTRATION:

21 CFR 176.300 (slimicides for wet end use)

When used in this specified application, all ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a) (4).

NSF Registered and/or meets USDA (according to 1998 Guidelines):

Registration number: Not Registered G5, G7 SARA SECTION 312 HAZARD CLASS:

Immediate(acute);Delayed(Chronic);Fire SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:

No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):

No regulated constituents present MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 Other information Substance or Preparation: SPECTRUS CT1300 Page 6

HMIS vii CODE TRANSLATION Health 3 Serious Hazard Fire 2 Moderate Hazard Reactivity 0 Minimal Hazard Special CORR DOT corrosive (1) Protective Equipment D Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations.

CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 18-NOV-1997 *A NEW **

27-FEB-1998 15 18-NOV-1997 15-MAY-1998 2 27-FEB-1998 20-MAY-1998 11 15-MAY-1998 17-AUG-1998 15 20-MAY-1998 27-OCT-1998 ;EDIT:9 17-AUG-1998 12-NOV-1998 ;EDIT:9 27-OCT-1998 03-MAY-2000 12 12-NOV-1998 05-JUL-2001 12 03-MAY-2000 24-SEP-2001 3,4,5,7,8,14,16 05-JUL-2001 16-NOV-2001 12 24-SEP-2001 30-DEC-2005 13;EDIT:15 16-NOV-2001 19-DEC-2006 13;EDIT:15 30-DEC-2005 05-APR-2007 2 19-DEC-2006 10-DEC-2007 5,7,8,10 05-APR-2007 12-FEB-2009 12 10-DEC-2007 Substance or Preparation: SPECTRUS CT1300 Page 7

SAFETY DATA SHEET PRODUCT r4NALCO NALCO 71 D5 PLUS EMERGENCY TELEPHONE NUMBER(S)

(800)"424-93001(24 Hours) CHEMTREC S1. CIHEMICAL PRODUCT AND COMPANYIDAENTIFICATION P1R514DUCT NAME: NALCO.71D5,PLUS APPCAT1ON*.ATIFOAM.

COMPANYý IDETIFIG6ATIoN:paloCpn

-,01'W.Diehl Road

Naperville, Illinois:

6Q563-1 198*

.EMER.EtY,TELEPHONENUMBER(S).:. (800) 424-9300,(24 Hours). CHEMTREC NFFtA 704M/HIHIS RATING HEALTH:ý 212, "FLAMMABILITY: 212: INSTABILITY.: 0A/0 ýOTHER:

0 --Insignificant ,i =Slight 2,= oderate 3=High 4-Extr.emrne =Chioir eaih Hazard 2., COMPOSITION/INFORMATION ON INGREDIENTS' . . ......

Our hazard evaluation. hasidentified the f010owing .cmicalsubstance(s):as hazardous. ConsultiSectint15 for th*e*

naturMeof the hazad(s).:

-Hazardous,,u66btance(,)i. ,cAS:NO Paraffin Wax 8002-74-2 040 1.01 Hydotreated Light Distillate 64142417-8 1 0.0- 20.D0 Straight'Run MiddleDistillate 6Z4741-44-2 qypopytene GiycOi. `2$3'2Z-69-4 '5s.0 10'0.

"All ,hý6 :: h ,1% Proprietary

'Proprietary 1.0- 5:.0

. IFicA I .... ..RDSIDEN

--**EMERGENCY OVERVIEW"

ornobustiblel. Repeatd exposurekmay cause skip;dryness or cracking.

Keep away from' he~".l<6ep away fio sour~esifnition - No Srhgking. Keep cnta.er tightlýcty:sd. Do hot'getJ6 eye*6,-n: skin, olcthing. Avoid4b'eathing ap6?. ,Use(withedeqiateyentilation: -Ifeezing. Protect productfdr' 1)6 riot~takeinternallVInJ case of cbntadc.iwith 'yes,i.nseihfmmediately:withplenty of water-and seek edical advice., Afte c*rii A.with skin, wash immediately with plenty of. soap'hd:*ater..

Wear .iuitable protectiveclothing, glovs and eye/face porotection...

C*6ibustible Liquid-, may form combustible mn ixturesat r above the flash point., Eimpty,,pr~uct:'coritajners Maiy.

contaih product resdude Do not prdegsurize, cutj bsat, weld, or exposbecontainers toflaime or other' es of ighiti6nŽ May:evolve oxides'6f"calrbon (COx&4,nder fire'or-t"0ions.

PRIMARY RQUTES OF EXPOSURE:

Eye,jSkin, Inhalation

....... Nal. Co...pan 1601 W; Diehl Road .-Naperville IllInois 60563-1198 (630)3051000:

F.r :6dditionhlpd60is of an! MSDS visit www.nalco.coftiahdrequest access.

1/12

SAFETY DATA SHEET PRODUCT 4 ALCO N NALCO 71D5.PLUS EMERGENCY TELEPHONE NUMBER(S)

'(800) 42+09300_(24H0urs)., CHEMTREC..

HUMAN HEALTH HAZARDS.- ACUTE:

EYE CONTACT:

Can c(ause moderatirmritation:

SKI CRiNONTACT>:

.Freqent or prqol6ngd hntact with product may df.at and dry.thesk` in leeading o. iscOr*ibrt arid: dermatitis.%

t]NGE1STION:'i: * , .: "

Not aJikely rout:bf:eXp6ibs.. May cause nausea and vomiting. Can cause chernjcato I uqia if.aspirated into" Iu~iigfbo!owing i~nestin:r an-cusedentra n system depression. Ther_ may bemay

.teivus ftati:id.to-he gastfr0intestinal tract.

I.NHALATION:

iRepe~teýdor prolonged exposure may irtati the'rsjrtory tract.

SYMPTQMs OF EXPO0SURE:

-Acute<

hala~tienof highoco..ncentrations of. organic solventsc..aine. cause nausea, di zzness,, omitig,s.up~or:or uncoriiojusness:*

Cr:eqen or " with prouct mypf.a...

"gpqdontact ...the ski, leadingto...... ......

AGGRAVATION O'F'EXISTING CONDrTONS!:

Skli'n contact may ag gravate an existing dermiatiti~c6iidition,,

14 iFIRST AID MEASURES.

EYE CONTACT:,~

me~diatety, f~h'ey~e w.it".*wa.tekrf t east 1.5.min.ites while hotding eye!dpelid op Get medical'attentior-p S K~iN.CO NTACT. .. ":. ..

Immiediately wa~sh witp~nty of.soap and water. If..yrnptoms " :Ip.:- medi"al a&dice" INGESTION:

Do nbt i nd uce Voioriting:. contains petroleum distillate~s.,and/or arornrtic o S01vents Ifd hnious, WasIJOut m oUth hdgi*

waterltodrink. Get medical attention ".

IN..ALATIN Remlove to freshair. tieat**.ympto0maically. If sV jmt~ deveeop, meek.rredical, adice.

NOTE TO PHYSICIAN,:

.Bad on the. indi vidual reactiorsO f"the .patient,.the physician'ju~ gn should..e:Used to coitib6 sym~torS arnd:,

Kclirical condition..

NalidoCompany 16801, W. Djehl,'Road%, Naperville, Illinois 6056371198; (630)305-1000 For additi6hal: copies of an MSDS visit.Www. nal coicom andriequest accs..

2V1- -

SAFETY DATA SHEET PRODUCT 4'NALCO NALCO.71D5.PLUS

":EMERGENCY TELEPHONE NUMBER(S)

(800),424930."0(24 Hours):. CHEMTREC

5. FIRE FIGHTING MEASURES FLASH POINT:. 1:9170'1925C ('PGMCC)

EXTINGUISHING MEDIA'.. .

Aickho.ib fca Cakbo"dioxid6e,P6am, Dry6pwder, Other inguishing o'gepsuitable:fo.rCass Bfr es, For Irge fires.

.se.wa~ter s0pray or fdgfthoroughiydretnchihgthe buIming materil" .

Watermistfmay be used to cool cIsed*00nainers '

UNSUITABLE EXTING.U ISHING ME DIA DO not use water unle6s flooding:amounts are available.,

FIRE AND EXPLOSION HAZARD:

,Combustible Liquid; may form coýbustible miiýures:at or above the4ashipolint .rmpty prodiUct containers may.contaih, product residue..Do fnot pressurize;..* Iea.,

d,&.or expose .o.n ta . tOfla er~tl our cesf.gnitionU.May evolve oxides.'oficarboi (Ox).(onder fire conditions,,

.:SPECIAL PROTECTIVE. EQUIPMENT FORFIREFIGHI:TING:

w~a r a full face.positive-press.ure .slfc . bieda.thn aapparatus a. protectiveSul,.

n .0f..firei I ACCIDENT.ALRELEASE MEASURES. ...

[.6 PIERSONAL PRECAUIONS:

METHODS FOR CLANING UNP

'.MALLSPILLS: So'aaupspillpwiothabsorbte t..e aterials.Place r mipduesia-suitable.,covred, prpierlyulbeledt ,

.,ntaine ,Wash affectedl arean iaRGE. SPILLS. Cfontain liquideuirg absnrbent material, by diggihg t s csfignitiby.

Sdiking. Reclaim into reco0Very it r salvage drums or tarek truck forpiroper disposal, Clean acontamriiatedbsu*af

.elswt,.

iater

.. or aqueous cleaning agehts, Contact andapproved!waste.hauler for disposal P of contaminated, rec ed,*

mnaterial., .Dispose of miateral in *mpliance with reg.*tions irnd!e.d in Setin 13 ( 'isPotsal.

Costion)..n ENVIRONMENTAL P pRECAUTINSr:

prevente.a -afrom e sesor waterw ays .

..nterng ..'.. :..

HANDLING. CLEANING P : :;

Jswith adeqUate ventilation. Keep.the,,aor firnerscl.o dPwherninot in use. ."Do::notu* in locations;*where p apyors

.ieley o traytb weldi.n flAmes .. .orPitther h sliurfaces. .Vaors are .h hetVmiteritharl,

.R.rGEs b ijr',.. canrenlh orinb

..une- dis.tri iti D di.rpotne e a.!lyrI*:

d snot breathe vapors/gases/dust.. .. t..getleyesonm skin,.on.

s clthing.

Havee rgeno y eaqu leit.a(fi g fig ..ptll s; laks, etfro'eadi: w y dasitable..Ehsuoealof cnains.are labeldove Ili~~~:3 NDSOR* 12*NLNG materia... pNalco .. Cotmpany 1601 W. Qiehl Roady Naperviilenilclinois 60563-.198 -.(630)305-1000....

" v For additiongak Wopies wfn MSDSvisitw nalco~com.and reques..access "

A CSAFETY DATA SHEET

" * ;NALCO 71 D5: PLUS EMERGENCY'TELEPHONENUMBER(S)

(800) 424-9300(24,Hours) CHEMTREC,

,STOQAGE CONDITIONS:"

Store-away from heat and sources of ignition. Store s~pa~rately firom ohxidizers. Sto re th-e cbnt6!ners tightly closed.

Use pro runding proceUdres. Have appropriate fire extinguishers available*inand hear the. storagearea. Store in suiaL beledacontainers, Connectionhsýmust be grounded to avoid electrical charaes. Keepat temperatures above' 18 'C EXPOSUREO8 CONTROLSIPERSONA 'PROTECTION .... ..... . .... ..... .

OCCUPATIONAL EXPOSURE LIMITS-: .

pEpsure guidelineshaven6t"been established forUhi*;r6uct. AVailabibe'expostur&lifits f6orthe substance(s) are-shwh ;below.

Substan-d6 s) Cateoory: 'pW ngm3 NnStnad Oif!M qM ý(!ist) OS "Z./E. s

.P~i*,, axtin,ir .(Fume. .. rrWA. 2 ENGINEERING MEASURES:

Theuei6f local exlaust vetiiabiinis te*rcmme hded to*c*itro6 em ssions near *he source..Labrato*y sppshould I

,bea. qdJi'qina fluehood. Pr ide'mrn*onical a Ientilationm of c paed .... . .

R EsPiRATO Rhuef Js"o'r, alROTECace:itT air supplie d .

breath~a~pparatusis recommended, a filter;material depends on the a tmutad typo, of cheni6als bei:

hand~elld. Cbnsi.den !he Use of filt. type: M*lticontaiinarit, cartridge:; gith a Patculate~pfilt&' In ey6t4'6f

emerency or planned entry into unknown~cOncentration a positly:prssure, fullkfacepiece.SCBA sho lId . i use&,, If' respiratory protectio~n is re~qjiredinstitutea completeispiratory pIdiction prodra' incIulin*!selection, fi testing, train inm.mainte Ianpne and inso):ection. .

HAND 'PROTECTION::

Whenhhandling ,tisproduct the. Use of chemical gauntlels is recoriimended. TleChoicedof*rk glo6e6ý&pends on.

work conditions an.d what chemicals are handled. Pleas'e contact the.-PPE manufactu.rer f.r.dv.ce on whoat type of glove nmaterial maynbe suitable._ Gloves should be replabce immediatelyif signrs, oegr6a"t6n;are, obsed-NpiroO ,: ; *re hSeeallsa ,, cherica resistant ...0,5 cm,,

.. .:AfU W*hen~haridi~'fhis~prodct, tlr'use,6f1dveral:i ,~~ ¢.lssa{ ao'nd~bber bets&'P rbcommn~ir ' ~i shckeru s eogross exposure ss ossib"ie" e

!EYE .P."QT*[ECTION ;

We'ar, chemicalsplas ii goggles.,

HYPGIENE.RtbbMMENDATION:S .,,

KeeP-an eye'*whf availavble. 'Kepfa safety.shbwer available, 'if*lothing is contaniiated, removze clotbing, tfounti and: thoroughly'wash theaffeted area. Lpunder cobnt~nfated t ,lways wash thor'pughly fter handling chemicals, Whe*n'Kindling this prOduct nevereat,t drink or fm*ke.

.. . .... , . ... . : . * .' . " * * * . . . c : . . * * . . .. "* ". ,; : * :: .

Nalco Comparny 1601 W .Naperville,, Illinois 60563-11.98' ý%(630)305-1000

-iehlRoad For additibnal *,copies-of.anMSDSýviSit www.nalco:com anid, request access.

4/12

SAFETY: DATA SHEET, 4¥NALCO PROD U.DCT NALC'O;71D5 PLUS EMERGENCY TELEPHONE NUMBER(S)"

(800),424-9300 (24 Hoursl.. CHEMTREC..

,HUMAN EXPOSURE. CHARACTERIZATION :

Based on our recommended product- apication, ad personial protective equipment, the pothential hUiman exposure: s:-

lopdi

Mod6rate 9.. PHYSICAL AND CHEMICAL PRO.PERT!ES; .

PHySiALSTATTE Liquid APPEARANCE Clear Ught.yellow ODORHydrocarboni SP EC.F.lC .GRA.VITY 0.84 @ 77 F /25 ,"C

, DENSITY -0 lb/gal SO4LJBILITYIN WATER4ý Insoluble, VISCOSITY 10 "p 7 0FIJ2 PRECIPITATION'POINT 50 =F I10 4d POR OINT OF-50 F 5-45 0C 27 0F 132.2 'C INITIAL BOILlN*,POINT 0

VA.OR PE.. .... J5.-1 mmHg, @ 100 ,/37.8<-.

Nate::These phyiical properties are. typical Valuesfor this.p tand;ae subjec t.tochange.

IO.- STABILITYAND REACTIVITY' , 7.. ...

i*S*A~lU*

S TA'B"IL'TY:

StabI nerrorkl'idi~fs HAZARDOUS.P.OLY..MERIZATION:.

Hazartdouspolyie.ization will not occur.

CONDITIONS TOA/OID..:.

Ieat: a'd sourceS of ignitibn'idcluding static.discharges. Extrehrs of temperature keep at temperatures a e18 'C' MATERIALS TO AVOID:

bhtontbcil stirong oxidizor(l!§ p e eroxid&eohi meit~sitiric id.hfte

. hý4rý6 6cne o)yen permanganate)may generate.tat; explosons and/o toxvapors.. Bases.Cotactvtsng.a kaIe g.

amm I nia and it~swbui bs, carbonatds;, soij Voie(asi) potassium%hydoie die.climhdroxie I cyanide; sulfide. hypochlorites. chlort~es) m ilsatteringor.boili n and toxic vaois.

"AR:DOwUS.DECOMPOSITION PRODUCTS:.

Under fire ondit*ons: Oxides' farbon A.. ..

.1 I t. OXIOLOGALINFOM..

Theý6iibwing results ar6f0.,he.product.

.Nalc"Company 16.0.1 . Dieh.I Roa Naperville, llinois60563-1198`. (630)305.1000 For additiorialI.opies of an

.... . .. . . =:*.. . = 5 11*2 -"nalco.

MSDSvisit www, . . com . and.* request'acc-ess. "

SAFETY DATA SHEET

ýPRODUCT

'4NALCO NALCO 71D5 PLUS1 EMERGENCY.TELEPHONE NUMBER(S)

....... (800)424-9300:(2?4Hours) CHEM.TREC ACUTE ORAL TOXICITY Species: Rat

'LD50 > ,1.5,380 mg/kg Test Descripto*r: Product AC pE tERMAIOXiCITY:-

Species,: Rabit

.LD506>ý 310;38 mgI4l

ýTesfes4*60trr: Product

,PRIMARYSI.Ni,,RRITA.ION:

Species: 'Rabbit D.raize Scor?: 3.1 /8.0 Test DescrRitpr: :Product, PRIAR EE IRRITA ION:

Species: Ra~bbit Draize Sdore: 6s0 ii10O0:

Test DesI.por: PrNOduct SENSITIZATION:

This produp't is not exp*tdt to be as~hnitizer.,

rzýCARCIN0GENICITY::.

None of thie* sbstancesiir)' this ptodukct :reisted aýcarcinogensb the International AgenCy for Reseaich -on Canrceif

!(IARC), the National Toxicology Programf (NTP) or the AmericarnConference of Govemmenta ndustrialiHygienists, HUMAHAARDCHARACTER QATION 1Baseb:ih6d6 aard characterizatiorthe pobehtita[hii-an hazard is:, Moderate,

.. . . ... . ~ * *... .. ................, ...

12.. EGOLOGIGAL:INFORMATION EOTOXICOLOGICAL EFFECTS:

"The followiingresults arelfor the Pprduct.;

.ACUTE FISH.RESULTS

,5 cies .S..... . .. Ex..su.... .... Test Descriptor

.C.O I'Bluegill Sunfisti -.96 hrs.7 1121 mg/i Similar"Product

Rainbow Trout 96lhrs. 3-10m/I Product,

FatheadMinhnw " 96hrst > 190fmg/I I SiniilarPr*luct, .. ..

a Cy........ 16..1 W W i......................

ehl Road ,;Naperille:Illinbis 60563-1198. (630)305-1000, For...additional

".. . ... "- .. an MSDS§visit copies of . .' . ..6 /1 2wnalc0:coýn

. . .:and'r'equest

. access.

SAFETY DATA SHEET PRODUCT PNALCO NALCO,71 D5 PLUS EMERGENCY TELEPHONE NUMBER(S) ...............

(800) 424-9300 (24 Hours) CHEMTREC

.ACUTE IN V ERTEBRATE R ESU LTS. ... ...................... ........

Species.:

Dahniaaa

=,Ceriodaphnnadubia'

. " Ek.oire

,,,,,48,hrs 48 hrs:

LC55 220 ig/Il 4.32m1/l.

'EC5 :

130

' m 1, "TestDescritor' Product' SimilarProdui I

PERSISTENCY ANpfloD EGRApATION.

Total Orga ,nic Carb6on'(TdCY: 195,870 tog Chemica Oxygen DemJan'COD)=: 2:200 000 mg/lI Bioogial xygen Demand(O D) j IncubationhPeiridd Vale Test Descr[tar-

. .. ........ ... 102A40,rbi / I.m ... Product OECD 301:,D (Closed Bottle) 28 Day M7080%.

heWorganjq;.pbrfion of this preparation is'exp~cted toý l*inherepti!bi6degrada!bIe.

MOBI'1LITY, Thi:e.nvir*onmrentafate was estiimated usingaqIevetlI Ill fugcity model embedded in the EPl"(estimation program interface) Suit eTMV, provided,by the US EPA_. The. modelassunies a steady state condition between the fotal irput'and:

output. Thelevel III rmodel does'not require quilibriu-nbetween the defined meia,, The informa..tion proVdied is,:

intended to give the user a geheral estimate of the environmental fate of this prpduct under the defined conditions of

'the miodels.

if released into.th*e environment this material isexpected to distributeto.the ait,- ater and sil/sedimentrin the.

apprcirjimateýý#p..pt~~m 'l~&;ti!r*

ctve peretages; respective p rcenta es; .. . .... .. ...

Air . . -, "W t'r. ' Soil/Sediment 10-33 1...... 0 / ..............

..... 30 -'50. I .0/6, 30:-50%/o The pofotinln wateis: expectedltofloat onthe surface.

BIQACG UMULATION POTENTIAL This prep,;. ;Ri,*n or. aterial i{snoit ,pected: bioaccumulate..

ENVIRONMENTAL HAZARD ANDj EkPOSURE CHARACTERIZATION Based on-o*ur haza.rd characteraati, th,*,OotentilaLenvironm* ental hazard is, Low.

,:expps*}ronbour

.Based recommended i~si:"High uctappli6-ati6n.and the pr duct's'.characteristi , the potefiti~lerivir nmental If released into the ehNvironmnent; see CERCLA.SUPERFND'in Section 15.'

I

[i13., I,:DISPOSAL .CONSIDERATIONS I 1 11l

....... ".. IA: * - - 0 =tN' . .. :""i :N .... ... . . ... .. ..................... . .

Iftlfjý:pfoyct b*ecomes~a waste, it is not=a:hazadous waste aS'defined b*'the.R~eource Cinseratin and Rekovery, Act;(*cRA 40'&CFR 261,::'snice it does not' have the characterstics f Subpad OG, Pisted ?i*r is it under u

Nalc ,Company 1601l:W'.. Diehl.Road* Nap6rvilevillinois 6056 31198:(63.0)305-1000 FOr additional copiesf'Ofan:MSDS vlsit.Wnalco.com and request access.

71[12

SAFETY.DATA: SHEET

ýPRODUCT

`ýNALCO NA LCO 71 D5PLUS

.EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) ..CHEMTREC As a' non-hazadous waste, it is not subject to federal, regulation. Cbnsult state or local regulation foranyadditional handling, treatmentor di Posal requirements. For di'sposal,. contacta pr0perl./licensedwaste freatmn&M st6yrage.

dispos~afovrrycjingfacility,ddisp~ s~a,.r,0 r..[,ec ..

i~n.........t.. ......

.... .. . ....... .......... .., , I 114.... ... *..

ITRANSPORT INFORMATION .1.

The;i nformationih this section is foiý reference 0nly*bnd shouldniot Lake theplace of a shipping papeIr (bilil of lading)*

specifi.'.cto an order. Please.nbte that t e6proper. S.h.ipping: Name i Had Class mayH ary by packaging,,pr..rties..,

andOmrode of transportation. Typical Propr Shipping Names forthis product are as follows.

LAND TRANSPORT:

For'Pakages Less Than Or Equal To: 119:Gallons:.

ro~ea_ Shippihg Name,: PROU~tISNOT:REGULATED 'DURING.

TRANSPORTATION

.Fo~r.P acgages .G.,reaterr..fhn, !.l.9da~l~ons*:

Prr6 *Shipping Name .e ':. COMBUSTIBLE LIQUID, NO1 ,,

Te nch Nane(s)`;" .PETRO'LEUJM HYDROCARBON.,

'UN4I&4oD : .NA1: 993:.,

Hazard Class -Primary.:

Packing GroUp:

~Flashý Poiht:'

AIRITRANPORT (AAOIA.T.A)

.Pro. i' Si5 hipping.."Narn e.. PRODUCT IS INOT REGUILATEýDURING TRANSPORTATION MARINETRANS PORT (IMDGl1MO):

PROD*UCT :IS. NOT: REGULAT.D DURI NG Proper Shipping Name:. TRANSPORTATION,'.. . -"". " '..,.7*

15. REGULATORY INFORMATION ...

,This.section conta;insadditional information that may have relevahce to regulatory ,omp,liancel. 1he inforiation i* this,

',sectioitisforureference on!y. It is not exhaustive, antidshouldnobe* bo rehed'upon taki- the pdadeof anrndvIualiz&

complianceor hdiar asseostent. Naco accep:ts n: liability f6r4he usei0f this infori0aation, NATIONAL REGULATIONS*. USA:

.,OSHA HAZARD 6OMMUNICATION RULE, 29 CFR,1910.120b:

Based*on.our hazard.evaluation., the following substance(s) in this product is/are .hazakidous'and fe:reason().isare.

showni below.

Paraff hwax:* Exposute Limit Hydrotreated Light Distillate: *Expopsure Limit "Nlco,Comp3any 1601 V.: Diehl .R6jd Napeuyi~l@,llliraoiS 6056371198.-(630)305,1,000.

For additional copies of an MSDs:,visit ww.nalcoiom and requast access.

.. . . .. ~~B/ 12.. .

,SAFETY DATFA:SHEET SPRODUCT

~NALCO NALCO 71D5 PLUS EM ERGENCY TELEPHONE NUMBER(S).

,(800)4.24ý9300(24. Hours)ý 7CHEMTREC Straight Run Middle Distillate,: Comrbustible., HARMFUL Polyoropylene Glycol: E-pbsure, Limit Aliphatic alcohiol: Combustible.,.

Aliphatic alcohol: Combusilbli..

CERCLA/SUPERFUND,. 40CFR:302':

Notification of spills of this product,.is;notf1eqUit.t`,.

SARA/SUPERFUND AMENDMENTS A.NRDIEATUT.1ORiZTION ACT*OF 1986 (TITLEIll).-.SE.TI0NS 302i 31 1 312, AND 313a

.SECTION 3027-EXTREMELY HAZARDOUS SUBSTANC-E'SI "hisproduct.doesinot:contain substances. listed ifl.App"adix.A(40t and FR*3155)':

B as9an Extremely . Hazardous'Substanc SSECTiNS 31I 1AN*:ý32- *MATERIAL, SAFEETY DATA SHEET!REQUIREMENTS(40 CER 370):

Orhaiard eValuif"i hli~sf.6und thii prout totehzifuý Ti.pouctýs~h'du~ld b'e r-ior~te~d.Under' theollbwi indicati EPA hazard *teg~riS .

meiate ZDlayed (Adute Ielhl-~a' ye (Chrhic) Health Ha*zard:

Fire Hazard~

- Sudden Rele4se of presure'HAzar.

- Reaciive Hazard :

Under SARA 311 and 312. the EPA has". esfablishied th6esfiold.*uantities.o for th ..re....n*.*t;f.hazardous.,chemica The current threshoids are':500 pounds or4thethreshold planning quantity (TPQ), whchevervis lower for extremely hazardous substances ancd1 0,000.pounds for all ..other haza:rdous chemicals.

SEGTION 313:-ýLIST ýTOFTOX)IC CHEMICALS'(40 CFR 372)`

This product des hot. contain substances on the..1i!s!ofToxi&:emi*ls TOXIC SUBSTANCES CONTROL ACT (TSCA),:". .

The substances in this preparation. are irinuded0n"0orexempted.fron tn:e-TSCA 8(b. ln(vento (40 CFR 710)

NSF NON-FOOD COMPOUNDS REGISTRATI.ON PROGRAM (forr*er *USDA ULstof ..P0ptie'ry Substances &

Non-Food Compounds):..

.NSF Registration number for this product.is :.A138905:

This productis accepbtable for treatment of,cool"n4ndýrt~ 0ater (9, in ýgn4 Orouh'0 food!ýje~

F.EDERAL WATER POLLUTION, CONTROLACt: CLAN wAlTERACT; .40'C'FR 401A.15~rbi eý3,4 116.4/ formerly Seci'o. 31. ,ryS'4$

This product may contain trace levels. (<O. 1./' for rcin6gens.**1% 611 Isted under the regulation. Additional.comppnents may: e~,unitentiopally~prýe, n 6t;. trace, evels.

Substanc, s)I 7citatiohs. -

a Naphthaleinhe. ].:

i.

. s~i*.*A*;* S~e*;3* : ... .... . :....... ' :* :; ::

Sulfuric Acid: j8,c 31:1

Nalco Company 1601 W2 Diehl Road. N4.aep.illep,!l!irnis 60563-,1198 ,,'(630)305-1000I For additional copies of-an MSDS:visit www.halco-com and tequest access.

.9112

SAFETY DAT.ASHEET PRODUCT:

~NALCO NALCO 71D5PLUS EMERGENCY TELEPHONE NUMBER(S)

(800) 424,9300 (24 Hours) CHEMTREC

~~~~~....*..

...... . . ...

1

* *~...... ... . . ..

ý-CLEAN AIR ACTS, sec. 112 (Hazard.us.Air POllutants, as amended by 40 CFR 63), sec. 602 (40. CFR82,.C.ass Iahd.

.Ozone Depleting "Substances):,:

Thisjproduct mayconai n t race .evets*(0,1%forcarcinogens, ,<,% all otherisubstances).of the following..SjbStance(s) listed i nder the regulation. Additionalp npoanents may..e unirtentionally.:reent at trace levels.

'Substande(ý Citations ...........

,ýiNaphthaIene Sec. 1~1 CALIFORNIA PROPOSITION 65::

Substances knowtothe State of 'California.tiobause cance rnd~or rep~rddnctrveioxic*cyar present as an impurty or, residue..

MICHIGAN CRITICALMATERIALS:

Sub'stances listed Under this r:gUlationar.e not .i.tenttonally..'dded orexpected to be* pesent;n this product. Lised comrponents may bpresentbtftrace levels.

STATE RIGHT TJO KNOW LAWS:

Thee oIlbwIng substanceesarkdisclbsed fr coim0Olfiance with State Right tb&KnoW: Lbs§

Paraffin Wax 8002-74-2 Aiiphata.lcohoIl Proprieta y Aliphat allcohol Proprietary:*.

Straight* Iun*Middle piDstlate 64741,.44-,2 iNTERINATiONAL CiHIEMICAL CONTROL LIAWS, CANADIAN:ENIRO-NMENTAL,.PROTECTION ACT (CEPA)..,

Th sbtac()iri~this preparafto~n are inhiuWed in~pr exempitec tram.teoesi0 AUSTRALIA A....s.. es.. t with the NahonallIndustWialClhemrcaIs NoticacatioS& Assessmint Scheme (NItC.N S)*. , . * " .. . . ... .

All substanceS inthts prodtuc com'ply with thf&fP6visions ob the, Envir6onmental Administrtlion ofNewvChemical Subgtances and-aro listed on"tie Inventory *f Existing Chemical Substances China (IECGS,3.

IihUbij.stae in t eparatidVavp been revieed forp&mpiance withthe .NCS... EIN]EC 6 veintob' Nalco Company 1601 W.DiehlRoad:.; Naperville, Illinoiý 60563-11980(630)305-1000

For additionali:opies of an.MSDSvisit www.nalco.dom and requestaccess,.

.l2. .

SAFETY DATA SHEET

..PRODUCTF PNALCO

i ... . .. . ...... ...

EMERGENCY TELEPHONENUMBER(S) ... ...........

(800) 424.9300 (24 Hours), CHEMTREC " ... ...... ,

JAPAN Al.il substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical' Substances and are listed on the Existing and New.Chemical Substances IRst (ENCS).

KOREA ...

All substances in this product comply with the Toxic. Chemical Contirol Law (TCCL) and are listed on the Existing.

Chemicals. Ust (ECL)

NEW ZEALAND.

All sbstace.s in.this producct.conply with th.e Hazardous Substarnces and New Organisms.(HSNO) Act 1996,and are listed6rdri.are exemptfrom, the New Z*alanad iventory. of Chemicals,

. P::HIL~~iP'P,,iI~iE*S.:::.

.. ls *!is~btan~s ir this prducto:o mly with.the.Republic Act 6969 (RA 696.9and are listed on the Philippines Inventory bf:Chemicals &:Chemical Substances (PICCS),.

16. OTHER INFORMATION . . ......

Due to our of exposures commitment Based onStewardship, this productto Product we haveuse our recommended evaluated the human.

of this product, and eny..ormta hazards Wevhave.chataleiizerdthe product's and k.ouc Whaverpnt racteiizs edtheproductes general risk, This information should provide assistance for your.own riskmanagement .iataines:.We have evaluated our product's risk as follows:

The human risk is: Moderate

The environmental risk .is: Low Aiy.use.inconsistenit withh our*r6commendations may affect the risk characterization. Our sales representative will

'asKsist.yo.O. determine if-your prodoct.app!cation4is cnsistent With our recommendations. Together we can implenmentan appropriaterisk management priocess.

This~product material.safety data.sheet provides health and *fety information. The product is to be used in .

appIicationsiconsistent with our.prt'tý;t literatur*. Iriiduals handling this product should be informedof the.,

.recommended safety precatitiOns and should have access to this information, For any other uses, exposures should be *valua~ted 6o that appropriate handlihg practice and training programscan be established to insuresafe workplace opeirations.. Please.consultyour.local. ale's reiprenstativee forany further information.

..REFERENCES

. , * ~ , ', ~

Threshold Limil"Vaiues"for Chemical Substances and Physical Agents and Biological.Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel InsightTM CD-ROM Vergion),*.Arel Research Corp.,

ýBethesda, MD.,

HazardousSubstances Data*Bank. National Libra* of Medicine, Beth*sda,aMaryland (TOMES. CPS. CD-ROM:

Version), MicrornedeX, nc., Englewood, CO.

IARC Mo.nographs."oilthe E~valuiation of the ng.... id IRh.. ...'f...

Carcinogenic Risk ofChemicals to Man, Geneva:, World Health Organization, InternationalAgency for Research on Cancer,

.. ..... ...... .. . . . ..:o o .... .

Nalco Company 1601 W. DiehI Road- Naperville, Illinois.60563-1198 * (630)305ý1000 For add*itonaF opies of an MSDSvisit www.natcoxcom and request acbess.

.ii11 12.

SAFETY DATA SHEET P4NALCO PRODUCT 41111hoii .NALCO@ 71D5 PLUS EMERGENCY TELEPHONENUMBER(S)

"(800) 424o9300 (24:Hours) CHEMTREC Risk Infor n£tegraed ,Version)

IC.D-ROM. ... aton .yser".U.S.: Environmental

" E. t PrbtecatioVnAgenc Washington,. DC. (TOMES CPST Mr:romedex, Inc.,.E nglewood .O0O.;

AnriuaIlReport on Ca.rcinogensi Najional Toxicology Program, U.S. Depafftmehtfof Health and Human ServiCes; Public Health. ServiCe.

TiteI029<ýdCde,.f Fed4&lionRegulati ns* prtf114O8ubdpart Z:T6ox:c and Hazardous Substances, Occup;ationalSafety.ý andi .H,*a!!h."t (OSHA),(ArIhnsght*.D-RM MA.dmrstr` Verion), Ari Resarch&p&., Bethesda, MU.

Registry of*Toxic*.E,.cts `fChemi.calSubstances; Nation0j(nhtitutf*1or Occupaptonal Safety and Health, Cinqnnti, OH, (TOMES CPS' CD-ROM Verfsioh,), Micome deX. Inc.: Eniglewood, CO.

programI),n ArieHns-ight" (An integrated guide to industrial chemicals:covered undermajor regujlatory. and advisory North ;Amenc iModule,..W est~fn iEurpean .iModuple,Chemical lnventories Module'and*.the GenersMd:Mlule (Arie, InsightýTm CD-ROM-Version), Adiel Resarc,h COrp.:.BethesdaMD..

Thd T6ratogen i".,mation Syteim',;Q.iivreSiiy~bCWashingtoh.f Seattle, WAX (TOMES .GcP.Sm CROM ersion)

Micromedex, Inc.*. "nglewo6od,* C

'Pepaired By ":,Priduct Seety'epartment:

Date issued 03/11i2.201 .

Vpri;LonIuNm ber,. 124, Nalcbo Company 1601 W.: Diehl. Road Naperville, llllinois 60563-1198"- (630Q)30,511,00

. m and request

For additional copies ofa'n ..iSDSvisit,WvW.nalco.ncb

.12 T /12, . access..

Water & Process Technologies '5 C l Spectrus* 0X903 Solid Microbiological Control Agent 0 Simple, dependable, convenient Typical Applications a Compact, hands- off automated feeder Spectrus 0X903 is also EPA registered for use in

Improved worker safety brewery pasteurisers, air washer systems, non-

No handling of potentially hazardous liquids potable reverse osmosis systems and pulp and paper mills.

Eliminates the risk of chemical spillage.

98% active ingredient Treatment and Feeding Requirements

Fast acting and non-foaming Proper treatment levels of Spectrus OX903 depend on a Powerful bromine based antimicrobial many factors, such as system cleanliness, microbial species, nutrient concentration, temperature, pH, sys-

Produces a total halogen residual tem half-life, and conditions particular to a given in-Description and Use stallation. The product should be used in accordance with control procedures that GE Infrastructure Water Spectrus* 0X903 is a specially formulated organic & Process Technologies establishes for a specific ap-bromine based biocide that is fully compatible with plication.

halogens.

Spectrus 0X903 is designed to be fed via RediFeed' Spectrus 0X903 controls bacterial, fungol and algal equipment, using good quality water. Feed is con-slimes in recirculating cooling water in commercial trolled by a simple and accurate halogen test.

and industrial cooling systems.

Tanks, pumps, valves and associated piping should Control of microbial populations in cooling systems is be made of polyethylene or most other common essential in order to prevent biofouling. Biofouling in plastics.

heat exchangers and cooling tower fill reduces heat transfer efficiency leading to higher energy costs. General Properties Biofouling can also damage equipment through mi-Physical properties of Spectrus 0X903 ore shown on crobiologicolly influenced corrosion (MIC) and force the Safety Data Sheet, a copy of which is available unscheduled shutdowns, or extended turnarounds, resulting in lost production. upon request.

Biofouling in cooling system can provide an ideal en- Packaging Information vironment for proliferation of Legionello bacteria, the Spectrus OX903 is a solid, available in a customised cause of Legionnaires disease. The active in Spectrus polyethylene container. Contact your GE representa-0X903 has proven highly effective against Legionello tive for details.

bacteria in laboratory tests. However, chemical treatment alone will not be effective in reducing Storage health hazards associated with Legionello bacteria. Store Spectrus OX903 at ambient temperatures and System design, location, maintenance practices and keep dry.

awareness of personnel are essential elements of a successful risk reduction programme. Safety Precautions A Safety Data Sheet containing detailed information about this product is available upon request.

Visit us online at www.gewoter.com Global Heodq uarters Americas Europe/Middle East/Africo Asio/Poafic

'Trademark of General Electric Company; may be registered in one or more countries. E-PFcSpectrvsOX903-E N.doc cC:t -05

GE Woter &Process Technologies Issue Date: 24-JUN-2009 Material Safety Data Sheet Supercedes: 24-JUL-2008 SPECTRUS OX903 1 Identification Identification of substance or preparation SPECTRUS OX903 Product Application Area Solid microbial control agent.

Company/Undertaking Identification GE Betz, Inc.

4636 Somerton Road Trevose, PA 19053 T 215 355-3300, F 215 953 5524 Emergency Telephone (800) 877-1940 Prepared by Product Stewardship Group: T 215-355-3300 Prepared on: 24-JUN-2009 2 Hazard(s) identification EMERGENCY OVERVIEW DANGER May cause moderate irritation to the skin. Potential skin sensitizer. Corrosive to the eyes. Mists/aerosols cause irritation to the upper respiratory tract.

DOT hazard: Toxic Odor: Mild; Appearance: White, Powder Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:

dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; May cause moderate irritation to the skin. Potential skin sensitizer.

ACUTE EYE EFFECTS:

Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:

Primary route of exposure;Highly Toxic;Mists/aerosols cause Substance or Preparation: SPECTRUS OX903 Page 1

irritation to the upper respiratory tract.

INGESTION EFFECTS:

Toxic; May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses.

TARGET ORGANS:

Repeated skin contact may cause sensitization.

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSURE:

Causes redness or itching of skin, possibly leading to burns (dependent on the length of exposure).

3 Composition / information on ingredients Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.

HAZARDOUS INGREDIENTS:

Cas# Chemical Name Range(w/w%)

10222-01-2 DBNPA (2,2-DIBROMO-3-NITRILOPROPIONAMIDE)60-100 Corrosive (eyes); highly toxic(by inhalation);

toxic(by ingestion); potential sensitizer 4 First-aid measures SKIN CONTACT:

Wash thoroughly with soap and water for at least 15 minutes.

Remove contaminated clothing. Thoroughly wash clothing before reuse. Get immediate medical attention.

EYE CONTACT:

URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.

INHALATION:

Remove to fresh air. Apply necessary first aid treatment.

Immediately contact a physician.

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician. Wash mouth with water. Do not give water to drink.

NOTES TO PHYSICIANS:

Material is corrosive. It may not be advisable to induce vomiting.

Possible mucosal damage may contraindicate the use of gastric lavage.

Substance or Preparation: SPECTRUS 0X903 Page 2

5 Fire-fighting measures FIRE FIGHTING INSTRUCTIONS:

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:

elemental oxides FLASH POINT:

> 200F > 93C P-M(CC)

MISCELLANEOUS:

Toxic UN 2811;Emergency Response Guide #154 6 Accidental release measures PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.

Flush area with water. Spread sand/grit. Neutralize with soda ash.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to label instructions.

7 Handling and storage HANDLING:

Corrosive to eyes.

STORAGE:

Keep containers closed when not in use. Keep dry. Store below 140F (60C). Store away from reducing agents and oxidizers.

8 Exposure controls / personal protection EXPOSURE LIMITS CHEMICAL NAME DBNPA (2,2-DIBROMO-3-NITRILOPROPIONAMIDE)

PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED MISC: Note- manufacturer's recommended exposure limit: 2 mg/m3(ceiling)-for powder.

ENGINEERING CONTROLS:

Adequate ventilation to maintain air contaminants below exposure limits.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER Substance or Preparation: SPECTRUS OX903 Page 3

WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use a respirator with organic vapor/acid gas cartridges and dust/mist prefilters.

SKIN PROTECTION:

butyl gloves-- Wash off after each use. Replace as necessary.

EYE PROTECTION:

airtight chemical goggles 9 Physical and chemical properties Density NO DATA Vapor Pressure (mmHG) < 0.1 Freeze Point (F) NA Vapor Density (air=l) < 1.00 Freeze Point (C) NA Viscosity(cps 70F,21C) NA % Solubility (water) 1.5 Odor Mild Appearance White Physical State Powder Flash Point P-M(CC) > 200F > 93C pH 1.5% Solution (approx.) 6.8 Evaporation Rate (Ether=l) < 1.00 Percent VOC: 0.0 NA = not applicable ND = not determined 10 Stability and reactivity CHEMICAL STABILITY:

Stable under normal storage conditions.

POSSIBILITY OF HAZARDOUS REACTIONS:

No known hazardous reactions.

INCOMPATIBILITIES:

Above 120 deg. C bromine, cyanogen bromide and dibromoacetonitrile are formed. May react with bases or strong oxidizers.

DECOMPOSITION PRODUCTS:

elemental oxides 11 Toxicological information Oral LD50 RAT: 308 mg/kg Dermal LD50 RAT: >2000 mg/kg Inhalation LC50 RAT: 0.32 mg/l/4hour 12 Ecological information AQUATIC TOXICOLOGY Bluegill Sunfish 96 Hour Static Acute Bioassay LC50= 32.5 mg/L Daphnia magna 21 Day Flow-Thru Life-Cycle Chronic Bioassay Reproduction EC50= 3.25; Reproduction NOEL= 1.75 mg/L Substance or Preparation: SPECTRUS 0X903 Page 4

Daphnia magna 48 Hour Static Renewal Bioassay LC50= 16.5; No Effect Level= 10.75 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay LC50= 43.5; No Effect Level= 15.5 mg/L Rainbow Trout 96 Hour Static Acute Bioassay LC50= 11.5; No Effect Level= 9 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay LC50= 35 mg/L BIODEGRADATION No Data Available.

13 Disposal considerations If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14 Transport information DOT HAZARD: Toxic PROPER SHIPPING NAME: TOXIC SOLID,ORGANIC,N.O.S.(2,2-DIBROMO-3-NITR ILOPROPIONAMIDE) 6.1, UN2811, PG II DOT EMERGENCY RESPONSE GUIDE #: 154 Note: Some containers may be DOT exempt, please check BOL for exact container classification 15 Regulatory information TSCA:

This is an EPA registered biocide and is exempt from TSCA inventory requirements.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:

8622-56-3876 NSF Registered and/or meets USDA (according to 1998 Guidelines):

Registration number: 140721 Category Code(s):

G5 Cooling and retort water treatment products - all food processing areas G7 Boiler treatment products - all food processing areas/nonfood contact SARA SECTION 312 HAZARD CLASS:

Immediate(acute);Delayed(Chronic);Reactive SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:

No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION Substance or Preparation: SPECTRUS 0X903 Page 5

CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):

No regulated constituents present MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 Other information HMIS VII CODE TRANSLATION Health Serious Hazard Fire 1 Slight Hazard Reactivity 21 Slight Hazard Special NONE No special Hazard (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.

CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES HSDS status: 23-JAN-2001 ** NEW **

15 23-MAR-2001 23-JAN-2001 15 10-AUG-2001 23-MAR-2001 15 24-SEP-2002 10-AUG-2001 21-OCT-2002 12 24-SEP-2002 20-NOV-2003 15 21-OCT-2002 24-JUL-2008 11 20-NOV-2003 24-JUN-2009 10,15 24-JUL-2008 Substance or Preparation: SPECTRUS 0X903 Page 6

Water & Process Technologies ::4, -j-Continuum* AT901 Alkaline Phosphate Cooling Water Treatment

" Cost effective solid concentrate Typical Applications

Improved worker safety Continuum AT901 is a combined corrosion inhibitor,

No handling of potentially hazardous liquids scale inhibitor and dispersant product for alkaline

Eliminates the risk of chemical spillage pH phosphate based programmes. The product al-

Corrosion inhibitor and deposit control blend lows the application of inorganic and organic phos-phates to promote the formation of a persistent

Maximises corrosion protection of mild steel protective oxide film on steel surfaces without the without the use of heavy metals formation of calcium phosphate scale deposits. The

Contains azole for protection of copper metal- polymeric component within the product inhibits lurgies the precipitation of calcium phosphate. The Contin-

Molybdate traced uum treatment programme is also designed to in-hibit corrosion of copper metallurgies and to control Description and Use fouling caused by suspended solids and inorganic scales, such as calcium carbonate.

Continuum* AT901 is a blend of inhibitors designed to control corrosion, scale formation and fouling, in Treatment and Feeding Requirements an alkaline phosphate treatment programme, within open evaporative cooling systems. Contin- Proper treatment levels of Continuum AT901 de-uum AT901 provides oll the benefits of Continuum pend on many factors, such as corrosion and scale technology in a single product. potential, and conditions particular to a given in-stallation. The product should be used in accor-The anti-nucleating and dispersant properties of the dance with control procedures that GE proprietary organic agents in the product extend Infrastructure Water & Process Technologies estab-the solubility of calcium, carbonate, phosphate and lishes for a specific application.

iron salts to prevent scale and other deposit forma-tion. This allows cooling systems to be operated in Continuum AT901 is designed to be fed via highly buffered, alkaline environments, eliminating RediFeed" equipment, using good quality water to the need to feed hazardous acid for pH control. produce a solution of convenient strength. Feed is controlled by a simple and accurate orthophos-Continuum AT901 protects many commonly used phate or molybdate test.

metals from corrosion by forming a protective, in-hibiting film on the metal surface. Whilst the corro- Tanks, pumps, valves and associated piping should sivity of waters decreases in alkaline pH conditions, be made of Hastalloy, mild steel, stainless steel, it is still necessary to chemically treat to inhibit cor- polyethylene or most other common plastics.

rosion, especially in cooling systems containing copper or copper alloy metallurgies.

Visit us online at www.gewoter.com Global Headquarters Americas Europe/lMiddle East/Africa Asia/Pocific

Tiademork of Generol Eectric Company: may be registered in one or more countries. E-PFcContinuumATg01lEN.doc Oct-05

General Properties Physical properties of Continuum AT901 are shown on the Safety Data Sheet, a copy of which is avail-able upon request.

Packaging Information Continuum AT901 is a solid blend, available in a customised polyethylene container. Contact your GE representative for details.

Storage Store Continuum AT901 at ambient temperatures and keep dry.

Safety Precautions A Safety Data Sheet containing detailed information about this product is available upon request.

Page 2 Foct Sheet

GE Water & Process Technologies Issue Date: 18-JUN-2009 Material Safety Data Sheet Supercedes: 28-MAY-2009 CONTINUUM AT901 1 Identification Identification of substance or preparation CONTINUUM AT901 Product Application Area Solid corrosion inhibitor/deposit control agent Company/Undertaking Identification GE Betz, Inc.

4636 Somerton Road Trevose, PA 19053 T 215 355-3300, F 215 953 5524 Emergency Telephone (800) 877-1940 Prepared by Product Stewardship Group: T 215-355-3300 Prepared on: 18-JUN-2009 2 Hazard(s) identification EMERGENCY OVERVIEW CAUTION May cause moderate irritation to the skin. Corrosive to the eyes.

Dusts may cause irritation to the upper respiratory tract.

DOT hazard is not applicable Odor: Slight; Appearance: Yellow To Brown, Solid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:

dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; May cause moderate irritation to the skin.

ACUTE EYE EFFECTS:

Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:

Primary route of exposure;Dusts may cause irritation to the upper respiratory tract.

Substance or Preparation: CONTINUUM AT901 Page 1

INGESTION EFFECTS:

May cause gastrointestinal irritation.

TARGET ORGANS:

Prolonged or repeated exposures may cause toxicity to the nervous system and lung.

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSURE:

Inhalation of dust and/or vapors may cause eye, nose, throat and respiratory tract irritation.

3 Composition / information on ingredients Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.

HAZARDOUS INGREDIENTS:

Cas# Chemical Name Range(w/w%)

7601-54-9 TRISODIUM PHOSPHATE (SODIUM PHOSPHATE,TRIBASIC) 7-13 Irritant (eyes) 15217-42-2 I-H-BENZOTRIAZOLE, SODIUM SALT 7-13 Irritant (eyes and skin); potential nervous system toxin 40372-66-5 1,2,4-BUTANETRICARBOXYLIC ACID, 2-PHOSPHONO-, SODIUM 7-13 SALT Irritant (eyes) 7558-79-4 DISODIUM PHOSPHATE (SODIUM PHOSPHATE, DIBASIC) 3-7 Irritant (eyes) 7631-95-0 SODIUM MOLYBDATE (MOLYBDIC ACID,DISODIUM SALT) 3-7 Potential irritant (respiratory); potential lung toxicity 4 First-aid measures SKIN CONTACT:

Wash thoroughly with soap and water. Remove contaminated clothing.

Thoroughly wash clothing before reuse. Get medical attention if irritation develops or persists.

EYE CONTACT:

URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.

INHALATION:

If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.

INGESTION:

Substance or Preparation: CONTINUUM AT901 Page 2

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.

Dilute contents of stomach using 2-8 fluid ounces (60-240 mL) of milk or water.

NOTES TO PHYSICIANS:

No special instructions 5 Fire-fighting measures FIRE FIGHTING INSTRUCTIONS:

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:

elemental oxides FLASH POINT:

> 200F > 93C P-M(CC) 6 Accidental release measures PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Sweep up and remove. Minimize dust generation.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.

7 Handling and storage HANDLING:

Clean spill immediately. Wash contaminated skin promptly.

STORAGE:

Keep containers closed when not in use. Protect from freezing and high temperature storage. Avoid moisture contamination. Do not store near strong acids, alkalies or oxidizers.

8 Exposure controls / personal protection EXPOSURE LIMITS CHEMICAL NAME TRISODIUM PHOSPHATE (SODIUM PHOSPHATE,TRIBASIC)

PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED l-H-BENZOTRIAZOLE, SODIUM SALT PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED 1,2,4-BUTANETRICARBOXYLIC ACID, 2-PHOSPHONO-, SODIUM SALT PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED Substance or Preparation: CONTINUUM AT901 Page 3

DISODIUM PHOSPHATE (SODIUM PHOSPHATE, DIBASTC)

PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED SODIUM MOLYBDATE (MOLYBDIC ACID, DISODIUM SALT)

PEL (OSHA): 5 MG/M3(AS Mo)

TLV (ACGIH): 0.5 MG/M3(AS Mo) RESPIRABLE FRACTION

8) EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

ENGINEERING CONTROLS:

Adequate ventilation to maintain air contaminants below exposure limits.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use any of the following particulate respirators: N95, N99, N100, R95, R99, R100, P95, P99 or P100.

SKIN PROTECTION:

rubber, butyl, viton or neoprene gloves -- Wash off after each use. Replace as necessary.

EYE PROTECTION:

airtight chemical goggles 9 Physical and chemical properties Density NO DATA Vapor Pressure (mmHG) < 1.0 Freeze Point (F) NA Vapor Density (air=l) < 1.00 Freeze Point (C) NA Viscosity(cps 70F,21C) NA % Solubility (water) ~ 10.0 Odor Slight Appearance Yellow To Brown Physical State Solid Flash Point P-M(CC) > 200F > 93C pH 1% Sol. (approx.) ~ 11.0 Evaporation Rate (Ether=l) < 1.00 Percent VOC: 0.0 NA = not applicable ND = not determined 10 Stability and reactivity Substance or Preparation: CONTINUUM AT901 Page 4

CHEMICAL STABILITY:

Stable under normal storage conditions.

POSSIBILITY OF HAZARDOUS REACTIONS:

No known hazardous reactions.

INCOMPATIBILITIES:

May react with strong oxidizers.

DECOMPOSITION PRODUCTS:

elemental oxides 11 Toxicological information No Data Available.

12 Ecological information AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Renewal Bioassay (pH adjusted)

LC50= 1670; No Effect Level= 820 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay (pH adjusted)

LC50= 1060; No Effect Level= 824 mg/L BIODEGRADATION No Data Available.

13 Disposal considerations If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14 Transport information DOT HAZARD: Not Applicable PROPER SHIPPING NAME:

DOT EMERGENCY RESPONSE GUIDE #: Not applicable Note: Some containers may be DOT exempt, please check BOL for exact container classification 15 Regulatory information TSCA:

All components of this product are included on or are in compliance with the U.S. TSCA regulations.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds NSF Registered and/or meets USDA (according to 1998 Guidelines):

Substance or Preparation: CONTINUUM AT901 Page 5

Registration number: 140951 Category Code(s):

G5 Cooling and retort water treatment products - all food processing areas G7 Boiler treatment products - all food processing areas/nonfood contact SARA SECTION 312 HAZARD CLASS:

Immediate(acute);Delayed(Chronic)

SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:

No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):

No regulated constituents present MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 Other information HMIS vII CODE TRANSLATION Health 2 Moderate Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special NONE No special Hazard (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.

CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 14-JUL-2000 ** NEW **

03-OCT-2001 15 14-JUL-2000 09-JAN-2002 2,3,8 03-OCT-2001 10-JAN-2003 2, 7, 8 09-JAN-2002 24-MAR-2005 2 10-JAN-2003 26-MAY-2006 8 24-MAR-2005 15-MAY-2009 4,8, 10,15 26-MAY-2006 28-MAY-2009 3,6,8,15 15-MAY-2009 18-JUN-2009 15 28-MAY-2009 Substance or Preparation: CONTINUUM AT901 Page 6

CORPORATE eXPReSS MSD X: MSDS 5ES6400 1 Environmental Way Halzrd Rtting HMIS NFPA Broomfield, CO 80021 Health 1 1 Business Phone: 1.888.203.5101 Flammability 0 0 24-HR MEDICAL AND DOT EMERGENCIES: 1.888.322.0912 Reactivity 0 0 Special None None MATERIAL SAFETY DATA SHEET Conamfes with ANSI Z400.1 Formal SECTION 1: PRODUCT IDMUTIPICTION Preduct: NEUTRAL MULTI-USE CLEANER Sustainable Earth" 64 MSOS CODE: SESAOO.1007 This MSDS applies to Product Numbers: SEB6401, SEB6402QM. SEB6404HM, SEB6405, SEB6409, SEB6409T, SEB6415 and SEB6434 GENERIC DESCRIPTION DATE ISSUED SUPERSEDES PRWPARED BY Concentrated General Purpose Cleaner 10-1-07 6-1-07 Regu~ltory Specialist SECTION 2: COMPOSITION AND INFORMATION ON INGREDIENTS Co"moneroi %by Vw. CAs =0os.t LQ Hydrogen Peroxide 0.5-1.0 7722-84-1 OSHAIWA: 1.4 mgt ORAL 1510 moflg (tat)

ACGIW TWA: 1.4 mg/m3 OERMAL 4040 mg/ (ra)

VAPOR 2000 ng/m° 44ns (rat)

Alcohol Ethoxylate 10-15 6843946-3 Not Established Water 60-100 7732-18"5 Not Established SECTION 3: HAZARD DNTIFICATION Primary Entry Routes: Skin Contact Signs & Symptoms of Exposure: Incidental sldn conlact Isnot expected to cause any-elnfficantrA inUr . We" Ovf e u.. stood an Omeda Mts M vfto ftes.ng prouma is not corosive anm wlm prolonged skin contact or eye contact may cause slight reddenxn but will be non-inrltatIng. This product has a low potential for skin absorption based upon review of the absorption informatlon, provided by Individual Ingredlents manufacturers.

SECTIN C~ FI'llT AID.MAWSURES Emegency First Aid Procedures: SKIN CONTACT: Rinse skin thoroughly with water. EYE CONTACT:

Flush eyes with water for 15-20 minutes. if reddening occurs and persists then get prompt medical aid.

INGESTION: Drink large amounts of water. consult a p.hyicUan.

24-HR MEDICAL EMERGENCY PHONE: 1.888,322.0912 SECTION 5: FIRE FIGHTING MEASURES Rash Point: None- This product is not considered a fire hazard, nor wIB it support combustion. EXtinguishing Media: Use standard firefighting measures to extinguish fires Involving this materiaW (water spray, dry chemicals or foam).

SECTION & ACCWETAL RELEASE MEASURES Ru"" or Spl Recover liquid with wet mo"p or wet vacuum. Flush residue to Iry sew water Use car. floor may become slippery. AN Federal, State and Loca. reuletlons should.be carefully followed. 0tsc-ardd.product is not .

hazardous waste according to RCRA. 40 CFR 261.

L .. SETK N .-..*A."G "?.... AND STORAGE Keep out or reach of?chhlaen. Avod and prongd skin contact.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION R.plrry Preti~oun; No opeow requkommevesvudetnonnit use condtons. ProtveaW oveO : No sPect requirements for normal uSe condtions. Eye Protection: No special requirements for normal use conditions.

Other Protective Measures: None

Corporate Express Material Safety Data Sheet Page 2 - NEUTRAL MULTI-USE CLEANER Sustainable Earth* 64 SEB6400.1007 SECTION : PHYSICAL AND CHEMICAL PROPERTIES Appew'anosOdor: Yellow Liquid Boiling Paint: >212F Evep. Rate: NA pH Concentrated Form: 0.6 VaporDensty:ND VaporPresare: -0.0 SpedficGravity: 1.01 SolublIftyin Water. Soluble %Volatlle: 100 V.O.C. Content (by weight): <1%

SECTION 10: STAB3LITY AND REACTIVITY Neutral Mui-U.. Cleaner Is stable and non-reecive.

SECTION 11: TOXICOLOGICAL INFORMATION Oral Toxicity: This product Is non-toxic based upon curent Pnformaon avaable to Corporate Express and provided by a, Ingrfljeffl -rnufwctowr. ft e.loU t &oute oral 1.14 values grealarthn >:5QC for rots and acute demon"1Da values greater than >2gfKg for rabbits. No PBT$" This product contalns none of the persistent. bloaccumulaltve and toxic chemicals (PET) as listed by EPA. dioxins &furans. towraphene. PCBs, Mirex Mercury &compounds. Octachloroslyrmne. alkyl4ead. DDT, Hexachlorobenzene, aldrinkdleldrin, benzo(a)pyrene and clordam. No Butyl: Contains no 2-butoxyethanol (butyl), No fndosrlim M mu8aved upon Wbdrog~m poidaed by mauwfe,*marn of all Ingredients used to manufacture this product, none of the ingredients used In this product contain APE. OPE. NPE or dibutyl plithalate.

SECTION 12: ECOLOGICAL INFORMATION The organic Ingredients am readily bIod4erdable based upon the Modlfied OECD screening lesale M*MIpdtucrs use. It wiln biodegrade In sewage systems and/or the environment. Contains no nonyt phenol ettoxylates or alkypheolv ethoxylates (APE). No Ingredients used to make this product am listed in the toxic release Inventory (TRI) chemicals M under Superfun Amendments and Reauthorization Act (SARA) Title 0I.,Section 313. This product contains no ozone-depletig chlorinated compounds as specified by the Montreal Protocol. This product contains no paradichlorobenzene 1,4-toxene, soaum hypochlortte. NTA or sodium EDTK SUcmtONi42 DISOA.WNIEAIM Wste Disposal Informatton: Wasle Isposal informaIon: No special method. Observe all applicable Federal. State and Local regulations, rules andlor ordinances regarding disposal of non-hazardous materials. Discarded product Is not a hazardous waste according to RCRA, 40 CFR 211 This product is not considered a hazardous waste as defined in WAC 173-303-070 or as charecterled

i*nWA 173-03-090. Obt-alvl' applic6ble Fedeal. 04.4. end Local "gulaelonm. mde &dor ordinances regarding disposal of non-hazardous materials.

SgCTION 14: TRANSPORT INFORMATION DOT EMERGENCY 244iR: 1.888.322.0912 U.S. DOT Class: Not Regulated DOT Shipping Name: Compound. Cleaning Liguld SECTION 1S: REGULATORY INFORMATION SARA Thi* ISectkin 313 ad 0CtFR Prt 372noificton: See sectIon 2.

No Ingedients in this product ame curently lted as carcinoges by NTP. IARC or 0SHA. AMcomponents of this product me isted or are excluded frorn listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substanoe Inventory.

SECTION I16: OTHER INFORMATION AIIaysfllowla directions cAift whe usin tor any othe chemical product. It Inforatio about thi producl.1I required. please contact CORPORATE EXPRESS at 1.868203.5101 or visit our webs 9ie at WlffcomorsleexMsLM Keep MSD Sheets Mfoed and od anized In an area kCeeSAlbll to wolters accw g to the "=az- dCwmwnld 8tnds.

jut,

.4f1t injinwruato.,

sdmwav-nohnd orthis nspsessdmo .Uasnal tomjuicd &S~jynw1~ssn sm'sin a prssusded the hefl I),ii A1vr o/lmrwhwmsaJ'itly vf (~qvrnrl sr./lnws &spr'wss*wpou,.

for a pwit*rpdare te-Ustn nswR(ant Noats' rrsponatlhfe/," with made rtiqw.*

r'ifylna Sn ttee ranurmunAM.111 is lt*sful*,nilena4 ds l Ifw1heýr' Slvud l wao nmsw n.E ptowdrd io any rhiydparatm. C1e arereWp-lbk1r jhsmsv WqJJ& stl Iss r.tasl~mt lasora' hr rq4W1drA: dts-is ,wre qtshe tr4brmatkon0-d s:(ihr*WuoIS ym afthe with thiRsAWN,

, ý_Zoý Lo MATERIAL SAFETY DATA SHEET MO M PRODUCT BULLETIN 03 Physical/Chemical Properties Physical Formo: Yellow liquid with bland odor.

Chemical Product and Company Identification Boiling Point: 2120 E Freezing Point: 28' F Product Name: CRUD REMOVER PPC Catalog Number: 03 "Vapor PressurelDensity: Not Determined. pH: 13.5.

Manufacturers Name and Address: Solubilitv inWater: 100%. Specific Gravity (water= 1): 1.08.

Protective Products Corp., Box 246, Johnston, IA50131 Evaporation Rate (hutylacelate= I): <1.

Product Use: Cleaner/Degreaser Stability and Reactivity 24 Hr. Emergency Telephone: 888-772-1277 Information Telephone: 515-986-5070 Chemical Stability: 100%.

Issue Date: 04.01-05 Prepared by: Dean Bibler Hazardous Polymerization: Will not occur.

Hazardous Decomposition Products: None known.

Composition/Information on Ingredients Incompatibility: Will attack aluminum upon prolonged contact due to Hazardous Components: Sodium Hydroxide CAS #1310-73-2 <4% alkaline nature.

2-Butoxyethanol CAS #111-76-2 <11% Toxicological Information Hazardous Identification Non-carcinogenic, non-mutagenic, essentially non-hazardous when HMIS and NFPA IHazard Ratings: used as directed following cautionary information.

Health - 1, Flammability - 0, Reactivity -0. Ecological Information Skin: Can cause drying, cracking; burns with prolonged contact.

Eyes: Can cause irritation, redness; burns with prolonged contact. Fully biodegradable as determined by individual laboratory testing.

Ingestion: Can cause tissue damage in mouth and throat if swallowed. Neutralize product waste with citric acid and dispose of in Inhalation: Vapor and mist can cause irritation; minor burns to nose accordance with all local, state and federal regulations.

and mucous linings. Disposal Considerations First Aid Measures This product is not considered a hazardous waste when Skin: Flush with plenty of cool water;, remove any affected clothing. disposed of properly. See "Ecological Information" above.

Eyes: Flush with cool water immediately for 15 minutes; rinse with Transport Information boric acid solution, get medical attention.

Ingestion: Drink copious amounts of acidic fruit juice or milk; do not This product is not regulated.

induce vomiting;, get medical attention. Regulatory Information Inhalation: Move to fresh air. Treat symptomatically.

This document has been prepared according to OSHA Standard 29 CFR 1910-1200.

Fire Fighting Measures It isyour responsibility and legal duty to make all information inthis MSDS avail-None. Non-flammable solution. able to our employees, and to anyone who requests this information after product purchase.

Accidental Release measures TSCA: All product components are listed on or exempted from the Large Spills: Flush affected area with water; neutralize with citric acid; Toxic Substance Control Act inventory list.

flush to sewer with water. CERCLA None.

Small Spills: Absorb with paper towels, newspapers, SARA Title III: None.

vermiculite, etc. Flush area with water: mop dry. CAProp 65: None.

Handling and Storage Other Information Storage: Keep from freezing. Keep away from food products. The information contained herein is believed to be accurate, based on current com-Handling: Avoid breathing mist and vapors. Use with adequate ponent MSDS knowledge mid experience. Itis provided independently of any sale of ventilation. Avoid contact with eyes, skin, clothing. Do not ingest. this product for purpose of hazard communication as part of PPC's product safety Wash thoroughly after handling. Rinse all bulk containers prior to program. It isnot intended to constitute performance information concerning this disposal. product. No responsibility is assumed that the information is sufficient or correct in all cases. No express or implied warranty of merchantability or fitness for particular Exposure Controls/Personal Protection purpose ismade with respect to the product or the information contained herein.

General Use: No specific protection required, use appropriately as per This information and product are prowided on the condition that the user shall directions on label. make determination as to the suitability for a particular purpose, and on the condi-Ventilation: Local fan; good general ventilation. tion that user shall assume all risks of use thereof.

Eye Protection: Safety glasses or goggles.

Skin Protection: Rubber gloves; appropriate clothing.

Respiratory Protection: Approved chemical mask if spraying bulk product at full strength. www.protectiveproductscorp.com Recommended Decontamination Facilities: Eyebath, washing facilities, Products that WORK!

safety shower.

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OIL DIESELTIRES GREASE INK BLOOD SOAPSCUM STAINS BUGS ALSO LOOSENS BOLTS!

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1S09001:2000 Certified LT Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Section 1 - Chemical Product and Company Identification MSDS Name:

Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Catalog Numbers:

LC14970, LCI5000, LC15050, LC15070, LC15090, LC15100, LC15130, LC15150, LC15170, LC15200, LC15220, LC15240, LC15250, LC15280, LC15290, LC15300, LC15320, LC15330, LC15340, LC15345, LC15360, LC15370, LC15380 Synonyms:

Muriatic acid, chlorohydric acid Company Identification:

LabChem, Inc.

200 William Pitt Way Pittsburgh, PA 15238 Company Phone Number:

(412) 826-5230 Emergency Phone Number:

(800) 424-9300 CHEMTREC Phone Number:

(800) 424-9300 Section 2 - Composition, Information on Ingredients 7732-18-5 Water balance 7647-01-0 .. ydro en chloride 0.5 -50 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: Colorless liquid Danger! Corrosive. Causes severe eye and skin burns. Causes severe digestive and respiratorytract burns.

Target Organs:None.

Potential Health Effects Eye:

Vapors are irritating to the eye, liquid contact may result in clouding of the cornea, erosion, up to total corneal opacification and loss of the eye.

Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Skin:

May cause severe burns and ulceration. Skin may turn brown-yellow. Deep burns are slow to heal and scarring may occur.

Ingestion:

Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.

Inhalation:

May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Palpitation, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema may result from inhalation exposure.

Chronic:

Chronic exposure may result in dental erosion, jaw necrosis, respiratory disease, dermatitis, conjunctivitis, corneal scarring and fever.

Section 4 - First Aid Measures Eyes:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until chemical is gone. Get medical aid at once. SPEEDY ACTION IS CRITICAL!

Skin:

Get medical aid at once. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. SPEEDY ACTION IS CRITICAL!

Ingestion:

Do NOT induce vomiting. Give conscious victim 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid at once.

Inhalation:

Get medical aid at once. Move victim to fresh air immediately. Give artificial respiration if necessary. If breathing is difficult, give oxygen.

Notes to Physician:

Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures General Information:

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.

Extinguishing Media:

For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam.

Autoignition Temperature:

Not applicable.

Flash Point:

Not applicable.

NFPA Rating:

CAS# 7732-18-5: Not published.

CAS# 7647-01-0: Health - 3; flammability - 0; reactivity - 1.

Ix Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Explosion Limits:

Lower: No information Upper: No information Section 6 - Accidental Release Measures General Information:

Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:

Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal. Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - Handling and Storage Handling:

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Do not allow contact with water. Use caution when opening.

Storage:

Store in a cool, dry area. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection Engineering Controls:

Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.

Exposure Limits IChemical Name: ACGIH~ NIOSH OSH Water None of the None of the None of the components are on this components are on this components are on this list. list. list.

Hydrogen chloride None of the None of the C 5 ppm; C 7 mg/m3; components are on this components are on this list. list.

OSHA Vacated PELs Personal Protective Equipment Eyes:

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.

Skin:

Wear appropriate protective gloves to prevent skin exposure.

Clothing:

Wear appropriate protective clothing to prevent skin exposure.

Ix Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Respirators:

Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.

Section 9 - Physical and Chemical Properties Physical State: Liquid Color: Colorless Odor: Pungent at high concentrations pH: Acidic (<7)

Vapor Pressure: 14 mm Hg @ 20°C Vapor Density: 0.7 (Air=l)

Evaporation Rate: >1 (ether=l)

Viscosity: No information found.

Boiling Point: 212-227*F Freezing/Melting Point: 32°F (0.00°C)

Decomposition Temperature: No information found.

Solubility in water: No information found.

Specific Gravity/Density: 1.0-1.2 (Water=l)

Molecular Formula: HCI Molecular Weight 36.46 Section 10 - Stability and Reactivity Chemical Stability:

Stable under normal temperatures and pressures.

Conditions to Avoid:

High temperatures, strong oxidants.

Incompatibilities with Other Materials Acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde),

amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine),

carbamates (e.g. carbanolate, carbofuran), caustics (e.g. ammonia, ammonium hydrozide, calcium hydroxide, potassium hydroxide, sodium hydroxide), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), fluorides (inorganic, e.g. ammonium fluoride, calcium fluoride, cesium fluoride), hydrocarbons (aromatic, e.g. benzene, chrysene, cumene, toluene), halo.

Hazardous Decomposition Products Hydrogen chloride, hydrogen gas.

Hazardous Polymerization Has not been reported.

IT Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Section 11 -Toxicological Information RTECS:

CAS# 7732-18-5: ZC0 I10000.

CAS# 7647-01-0: MW4025000.

LD50/LC50:

CAS# 7732-18-5:

Oral, rat: LD50 = >90 mL/kg.

CAS# 7647-01-0:

Inhalation, mouse: LC50 = 1108 ppm/l H Inhalation, rat: LC50 =3124 ppm/IH Oral, rabbit: LD50 = 900 mg/kg.

Carcinogenicity:

CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65.

CAS# 7647-01-0 ACGIH: Not listed.

California: Not listed.

NIOSH: Not listed.

NTP: Not listed.

OSHA: Not listed.

IARC: Group 3 Epidemiology:

No information available.

Teratogenicity:

Embryo or Fetus: Stunted fetus, ihl-rat TCLO=450 mg/m3/1 H Specific Developmental Abnormalities: homeostatis, ihl-rat TCLO=450 mg/m3/l H Reproductive:

No information available.

Mutagenicity Sln-dmg-ihl: 100 ppm/24H sln-dmg-orl: 100 ppm cyt-grh-par:20 mg cyt-ham lung:30 mmol/l cyt-ovr-ham:8 mmol/l Neurotoxicity No information found.

Section 12 - Ecological Information Ecotoxicity:

Trout LCIOO=10 mg/l/24H Shrimp LC50=100-330 ppm Starfish LC50=100-330 mg/l/48H Shore crab LC50=240 mgfl/48H Chronic plant toxicity= 100 ppm Fish-toxicity LC50:862 mg/I Environmental:

Substance will neutralize soil carbonate-based components.

Physical:

No information available.

Other:

None.

Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, O.O1N-6.25N Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations.

Section 14 - Transport Information US DOT 1% to 40% W/W 0.5% to 1% W/W 0% to 0.5% W/W Shipping Name: Hydrochloric acid solution Hydrochloric acid solution Not regulated Hazard Class: 8 8 UN Number: UN1789 UN1789 Packing Group: PG II PG Ill Section 15 - Regulatory Information US Federal TSCA CAS# 7732-18-5 is listed on the TSCA Inventory.

CAS# 7647-01-0 is listed on the TSCA Inventory.

SARA Reportable Quantities (RQ)

CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg)

CERCLA/SARA Section 313 This material contains Hydrogen chloride (CAS# 7647-01-0, 1-50%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

OSHA - Highly Hazardous CAS# 7647-01-0 is considered highly hazardous by OSHA.

US State State Right to Know Hydrogen chloride can be found on the following state Right-to-Know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.

California Regulations European/International Regulations Canadian DSL/NDSL CAS# 7732-18-5 is listed on Canada's DSL List.

CAS# 7647-01-0 is listed on Canada's DSL List.

Canada Ingredient Disclosure List CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.

CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.

Section 16 - Other Information MSDS Creation Date: November 1, 1997

IT Material Safety Data Sheet Hydrochloric acid solutions, 0.5%-50% v/v, 0.01N-6.25N Revision Date: September 19, 2007 Injbrmation in this MSDS is from available publishedsources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resultingfromn the use of this MSDS. The user must determine suitability of this informationfor his application.

MA.ERIAL SAFETY, DATA SHEET 1f CHEMICAL PRODUCT &COMPANY IDENTIFICATION

'TRADE NAME(S). SULFURIC ACID

,CAS NUMBER *7664.93-9 MSDS NUMBER.

,PRODUC 6CODE: ND SYNONyM(S) IL O*FVITRIOL MANUFACPTURPIE e:Kctiýuttur ProcsCom-P'anY, SUPPLIER PO BSo2256 67201 Chemirec:800D424-930

.Releence.Koch Subsidiary:

Koch SuItur Products Company

ePHONENUMBERS- GENERAL. ASSISTANCE 8-5(M-F, CSIT) 316-828-3019

-5(M-F. C§T MSDS 318-828-8488 Assistance 2 ,c MPOSITION. INFORMATION ON INGREDIENTS

( Ingredient Na .ame CAS Number . Co.centrallaon* Epou Ums/ Health Hazards SULFURICACID 7668.93-9: "t 100% I mgfm3 B-HourTWA (oSHA)

!I mglm3.8-Hour TWA (ACGIH)

3. mg,'3 15-Min STEL (ACGIH).

'Values do*nOteflect'abeolut* milmums d madmums; these values tetypcal which may yrafrm tlMe to tDtIe.

,,, ,HAZARDS 16ENTIFICATION.

EMERG:.ENCY OVERVIEW DANGERI

ýHEALTH HAZARDS:. .

MAY BE CORROSIVE TO THE SKIN, EYES AND RESPIRATORYTRACT".

ASPIRAT1ON HAZARD IF SWALLOWED-CAN ENTER ILUNGS AND CAUSE DAMOAGE(

CANCER HAZARD.

SEE°'TOXICOLOGIdAL INFORMATION. (,SECT*ON 1), FOR MORE: INFORiMATION:"N FLAMMABILITY HAZARD, NON1COMBUSTIBLE.

REAC TIVITY H4A *RS..

.M:AY EACT V.* TL..

WIT W .ATE ND= No a =NA-Not:ApPic.40 Printel On 4/2312002 ... .7. .

'Material Id,5371 Trade Name SULFURIC ACID

POTENTIAL HEALTH EFFECTS,SKIN CORROSIVE. ComaC!? may cause reddening, itching, Inflarnmallod, bums. blistering and possibly severe tissue damage. Repe*t*ed r prokloged contact tissue may result tn drying', redderting; itchingpain.

damage. . inillammation, with cracldng and possivte econ6dary Infectlon POTENTIAL HEALTH EFFECTS, EYE

CORROSIVE. Exposure may casesevere burns, destruction of eye isi.nw.ad iblepermanent Injury or

ýblindrness. Prolonged:or repeated exposure may cause irritation and corjurict~tiVs.

,POTENTIAL HEALTH EFFECTS, INHALATION EXTREMELY IRRITATING AND CORROSIVE. May,ause svaere bums and fissue damage to the 'espiratory tract. Symptoms may include~thtoat burns, constrictlon of 1te wrndpo (bnorospisms), severe puImonary edema and death. depending onthe concentration and duration of:exposurem Overexposure to thIs materiia may caýus yemicda ga cldi*g tergel organ effects listed under IToxicologcail Information" (Section 1 '1.

Other specific symnptoms of exposure kr Ii.sted ucndrcf T[oxlcological informii (Section 11).

POTENTIAL HEALTH EFFECTS. INGESTION CORROSIVE. May cause painful I*ntatton end burning'offtha mouth and thioat, painful swallowing, lab.lIred breathing bu. s or perforation of the gastrotnIestinal.tract leading to Wtcoeral0n cnd secondary infection.

.Corrsve damage to the stomach and esophagus may be delayed.

Aspiration Into: lungs may cause chemical pneumonia:and lung damage.:

,Overexposure to this maeial" may cause systernic damaje' Including m tagtoraiffects iifed under

! On!orgaarn"(Seon.1)."f

,1.Toxo -

Ohetri spetic syomptos 6 poPure are'list u ndei 'Toirlcdogic~ll In*fonhiti. ..(Setoirli ii).

4' FIRST AID MEASURES; SKIN*

Immediately 1Iushjldn with plent of water, for atl iaMAsiSmr"i's whil it~ii ~hn n shoes.: GE--IMM**ATE MEDICAL ATTENTION.

Place c6ntinaIted clof!ing In.nos. coat er for storage unil ilaunderedar dlscarded.. If clW.lnrg Isto be lnI0'rrW pero laundeiredi,of,* pef. mn Iolmnna , . .

oprtiro ... .. . ..ii .

rpris prp ... ...dotar~a

e. . . l t athg* :

I. ... *. ,

ea ther gos EYE

>Flush.Immedlatefy .wfitt largeamnounts of water fo.at least 15 minutes. EYe.Ids should be held away from me eyeball to enstrdthorough risin.'GET IMMEDIATE MEDICAL:ATTENT!O.*

'INHALATION SRemove to fresh air. If o ang Institute 1e rescu hing. i breatIng lýfiflcult, ensrrealrwajvls citarý keep affected person warm an*la rest.:GET IMMEDIATE&MEDICAL ATTENTIN.

INGESTION II victim is conscious and alert, give13 gassas of water tiidiute stomach cntents. Rinse mouth *o witv, water. W:notainduce vomitinigunless directed by medlia p'ejr nal. Never jvd anyhing by m.ou.h t.0.!

unconscIousperson. If spontaneous vomiling oPCcur" lPp be ow hps opreve asplration and oriitar fo breathing dfficully.

Keep allected person warm and at rest. GET IMMEdIAT TMEDICAL A NTT*N,*

5 FIRE-fGHTING MEASURES, HAZARDOUS COMBUSTION PRODCTS Decomposes to form sulfurf dioxde and sýulur Woxid.e.

ND a'No'Data NA -Not Applicable Print6d.r 4k2312002 2V 71 Material Id5371 Trd Name SULFURIC ACID

'EXTINGUISHING MEDIA Use carbon doxide or

chimicil to exilinguish fire.

BASICFIRE FIGHTING PROCEDURES:

Do'not addw~ater to acid. Wateri~pplied directly results in evolution ofi heat and splattering of acid. Acid can reacti itlhmetalssifp to liberate distance. flammable hydirgen gas. es ally whder-diluled with w-aer. Evacuate area and a

fight fire from Use waler sporay tococlaac cent structures Ando protect personnel.:Do nor!gitwater inside suffun, acid

containers. Shutofl1 sourceaof flow if posibie. Stay amwy fronm storage tank ends, Withdraw immediately in case of rising uhrdx tfrom venting safety .de disdoloration of storage tankidue to tire.

'iceoany Firelighteljr must wear MStWNI09Hdappr postive pressure breatlflng apparatus IS.BA). wth.lull face

.mask: ard: full protective equipment'.

UNUSUAL FItRE 1.* .:oStINW'AZARS Materiai wiiliniot burn.

RepaS wi"th Most metakis rtowde rn gast Wc:can foim.an ixiiýsivmixture. wthair.,,

Flash Point ND

Ati",fgnitl* otemperalure NQ F..a nm ailtty Units in Air",.Low r ,% Vol-me .by ND F'aimmtablilhy Umits in Air, Upper, %Wby Volume ND.

6 A6.0IDENTL RELEASEWMEASURES EMERGENCY ACTION Keep unnacessaey people away; isodate hazard area and deny*nýji.. Stay u-pwind. tsolate for 1/2 mile in. all directions if tank, rail car or tank truck Is involvedlin fire, Evacuate ateae9re&nxdagr by release as required.

..(See Dipo<sure.CntrtPer~nal protectiOn+.Seclio :8):. . .... **" . .

ENVIRONMENTAL PRECAUTIONS:

.. product is released tothe environment,. take Immediate siepsto st.op-a :contain release. Caption should be exerclse"d rega-rring personnel safely and exposure Itreo 1.hrelease.* x.*uc Notify'!ocal.Kthortles and:the

'+Nal.onal Response Ceniter, if requ Iid.

SPILL OR LEAK PROCEDURE:

.C*.p unnecessary deople vawy. Isblate area for a least 50410 mitfem (i60-3ýO.det) topresve put iAc safety. For large spills, consider itial evcuationbr at least 300meters (1000 feet).

re spills may be netralized wih dilute alkaline sotullon. of s&di ashor lrime..Step teak:when sale to do so.

See Exposure Controls'Personal Prolection (Sectlio:8).

7" HANDLINGASTORAGE:

Ti m r u o

k ed Inasic or pastio tined contaIners. Do e aleni+,s o equipments.mesidve* acso.eds. ..

Do not eat. drink orj..ioke'n. .easof use op storage.

STORAGSE

.Avoid .ontac't....t co.st.l.. e.matel.".. water. metalý. andalkalies. Store in avented, ntainer.Sulfurtc acid reactsith most metals.to produce f oggas .hich.can forman explosive mixture athlr..

Empty on*nea.nerm7p ti" resiue. DOm rio reuse with'out adequate precautiors.

N.O...No' Da..:.NA:.. Not Applic.ble.

. .. .7 P rinted On 42..... 3: .

Material Id5371 Tr.e N*e SULFURIC ACIO:

8 EXPOSURE CONTROLS [PERSONAL PROTECTION ENGINEERING CONTROLS Ventilation and:other fWorris of engineering. controls are the preferred. means for controlling exposures.

EYE:PROTECTION: PERSONAL PROTECTION EQUIPMENT.(PPE)

Wear chemlcal.safety:gogglez and face'shield: Have eye washing facilities readily available wherwey6r contact' can occur.

SKIN PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)

Avoi skin contact with this malerial. Useappropriate chemical protective gloves, when handlihg-Additional protection tiayVbe necessar. to prevent skincontact includinguse of:apron,,gaur*lLts boats, impervious protective suit and face shield or splash goggles. Provide safety showers at any location 'whereskin.

cotc can occur.

Use gpood personal hygiene.

.RESPIRATORY PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)

A NIOSWIMSHA approved air purlfying res*prator with an appr ate acid das ,.caniser mayb&

cartrid

,9appropriate under certain cwrcumstanceSwerairor.emconcentrations'aie exected 10to ""xedeps ure

.limits. Protection provided byair pUrifyihg respirators is limitedi. Use-a positive prei--zirair supplied rspiator:

it there is any: potential *oran uncontroiledi release, exposure levels are noitknow,.or any'other citcumstances, where air purifying respirators may not-provideeadequate protection;.

0(9, PHYSICAL &,CHEMICAL, PROFPERTIES.

ODORANDUAPPEARANCE COLO RLESS TOQCLU DYOIYLOOKING UCUID WITH A PUNGEF*TWOR, or* ,,.* ,...

a lnf- AT *I.7 5 - * .3 <11 I"....<!

Pereltin olPoint ND yaw Pressure AT 100 -F.(7-85% 8d93-,9%d,9%.)

Vajior Der"ty ND OctanotN/ater Parn. ND Volatile Organic NO PourlPoin ND pH Value. c Freezing Pointý i-85% -40) IF, 85%,1(40), IF, 9% :(-2§) ',9%ýi F,9i 4 F viscosity. ND Evaporation Rate N Molecular Formula, H2SO4' Molecular Weight 98.0 hemicail Family MINERAL ACID Odor Threshold ND 10loSTABILITY & REACTIVITY' STABILITYr/NCOMPATIBILITY Avoid contact with water.

Inborpanible with combustible. ateraWswatb**metals aM alkalies. See pcts unde Habiing .*

Storage (Section 7).

NO = No Data NANo:: cabIe " ' . Printed:Oni 4/2 00" .. 417 Material id537t Trade Name:SULFURIGACID.

KAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS Decomposes t"o ni sulfur doxide and sulfur trioxide.

1.1 TOXICOLOGICAL. INFORMATION ROUTES OF EXPOSURE lnthlation, ingestlon, skin and eye contact.

11350 LD50-:Sulturic ACid, Rat Oral , 2*40 mg/k.

TOXICOLOGICAL DATA:

Acute or chronic overexposure to this rnaterial or its'com'ponents may cause tystemlictoxicity, Jncluing adverse effects to the folowing: kidney. liver, teeth, respiratory and cardiovascular systems.

Exposure to components of this.materf..iday causo.lhe follo0ing specific symptoms, depending oft.the concentrabonl and duration of exposuree8-.lacks enamel of teeth, vomitlng, clammy Skin, w6ak and rai pse.d

Other symptoms of exposure may include the following: shallow., respiratio chronic bro.chitis, lunguti. fun*c changes and scanty unne.

"CARCINOGENICITY.

lIARC#has determIned that the Is sufficient evidlenceitor thec

gnlciy.loccupalijo'n'al osure Io strong.inorganic acid mists containing sulluric;a0cd *hum (IAR*: Class 1)..

PIRE-ýEXISTING CONDITIONS AGGRAVATED 3YI EXPOSURE

'Pre-ex~tirgirnidical corxiti onswhi h may be aggravated by ex~oelcu lre~o h lnad 12'.ECOLOGICALt INFO.R MATION: .

ECOTOXICOLOGICAL INFORMATION".

ND%

13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL

-thisproduct as suplied,.when dlscarded or disposed ol,; Is ahazardous waste.according to.Federall fegulations (40.CFR 261.)laue JIts corrosiVity.and reactbvity, Under the Resource Co0seiafton anud Recovery Act (RCRA). Itis the responsibility of-the user of the product to detemine, at the timhe of disposal, whethei the mataial is ahazardous wvste ubjlot to RCRA.

The -ransportatio storage, treament and dcisp ofACRA Waste materal must be conducted in c pll .

with 40 CFFI 262 263, 264. 268 and 270. Dis can occur rnly In properly permitted facilities. Check state and local regu ation for any. additional requirements is these may be more restrictive than federal laews and-reguations. Chemical 'aldionsI.pmcesing orotheiwise-altering this materal.may make the waste.

. nageinentinftoniatlnpwesonte*tdtOthisMSDS Incomplete,. naccuatorotherwlsenapprq tate. DIsoA Of thIs:material must be ,onductedin 0corlance w.tt altl.,edera, stale and Iocal regulations.

1*4 .TRANSPORTINFORMATION.

btIL OF LADING -".BUJK (U, S.. DOT)

RO,"Sulfuric Acid, 8,.UN1 830, PG II (use with more lhan 51%ac.d).

RQ, Sulfuric Acid, B,.UN2796,P.G II (use witivnotmoie tha,'51% acid)ý BILL OF LADING - NON-BULK(U. S. DOT)

RO, Sulfuric Acid, 8, UN1830, PG II iuso with more thAn 51%.acid)

R0. Sulfuric AcId, 8, UN2796, PG 11(use with not more th'an51%. acid'),

NO = No Data NA.* NoWAplc. . .. Prle 043o02 " . * 'a 7 Maerial Id,5371 TradeName SULFUIC ACID

u. s. Departmnent of transportation. (DOT) Requirements, General Transportation fnnoatlon, :for Bulk Shipments Proper Shipping.Name Soouric Acid Hazard Class JO: UNINA Code UN27.

Uw*766:

Packaging Group PG ii Labels Required C"oribsive Placards Required Corrosive, uNNi*8 (>s56,) ii96(=5)

Ftepontableuantiiy Se~eReguatarinry ltrmatibnI(S General Transportatlon Informatin.for.Non.Bul& Shipments Proper Shipping Name SuIlurdc Acid, Hazard Class UN/NA Code UN1B30,,UN2796 Packaging Group PGiI Labels Requlred"

roav.

Placards Required Corrosive;.UN O(51%).Ul 2796 (-c Repoirtable Ouaftlity - See Regulatoiy Infor~mation (Stection 15 The above description may not cover shipping i.nall caseslle.ase6 Consult 49 CFR 17'2.01 for specifc Ipp~ng information.-.

15: REGULATORY INFO.RMATiON..

FEDERA.CREGULATIONS .

A !ngrents afire tie TSCA iventory or an rnot required to", bellit on ihe.TSCA Inrenoy.

1Thtispr*duct;, as supphiedcontains sulfuric acidcl, a Hazardous Substance as per *CFR .Part 32.* *and .rt Extremely Hazardri "Sutancb as 4*er40CFR Part 355.lThereportabaequan ffo;sulturlc acid:.s.1000 19pounds. Arry relea~se of thls product equal to or exceedintg the reportable quant.ity must be reported. totie~

National Resp.o~ns~e ýC'enter .(800424-8802) am pnpdt state and local reg'ulatory. agencies as described Iii 40 CFR. Port 302.6and.d4 CFR 355A40, reapectlvely. F a oire11pbrlmay res-ult'liisWbstantfal civil:ý ..

cIiminai per Ieis.lheck.stat and lb6al regulations f anyadditolnal requiramentsas'these maybe more:

rebsictIve federal lan aws and reguilat.ons ..

This prodluct1 ~nAins one or mrnoe coniyponents; desint~ed as hazardous substances or tcoj pollu~tant Spursuant to .he:ijedral Clean WaterýAct(40,CFl3 iI84Tabe A;. 40 CFR 401.15). Aryunpeimittn .

Introduction Clean Water ol6ils Ad ircuct Fackilli as. Intoa must facilifty :torm nobly.thie

or wastewater wteriate .nclngdlscharge~mayconstitute athiS wotinoafl prmoduct,,

the

theg afore e t e at*nt.arg

... . . .. .. . . . . thl . . . It SThis productcontairn'one or m.'e substances llsted as hazardo*u*oxlc or 44am alrpolluuInder a*Je Section. 1121 dthe.CeanAir*ct."

TIhere. may 6e.specilo regulations at the:l.oca. regional or.state/pro*'ical level thatbpertain toi fs pmuci STi.AREGULATIONS ".

Based a*. avainlable inf.ormation this product does not contain my components or che,*nicas currently krviwnto

.the State of CaJifomla ~t'oc'ause cancer bIr. 51th dlefecs or reproductiVe har at levels w dch ,would be sujctt

..Pmpation 65. Reforru~lation, use or proces*sing of this product "myaffect its composition and require re-evaluationi.... " : * *

,SAA TITLE ill RATINGS Immediale Hazard: X Delay.Hazard: X Fe *.Hazard: ' Pressure Hazard:

Reactivity Hazard: X NFPA RATINGS Hah3 Flammability 0 eactivity 2 Special Hazards, W ND do DatdNA I 1 o Apiciable

... Priated On 4r&23'202/7 617 Material irS 5371 Trade.Name suLFURIC ACID

HMIS RATINGS Health 3" Flamm/A.l1iy 0 Reactivily '2 Following ingredients of this p roductare listed In SARA313 SARA Usted InrdientName AS.Number Maximurn1%.

"SULFURIC ACID 7564-93.9 100.0 16.OTHER INFORLATIObN DISCLAIMER, NOTICE: .TheInformation p.mwsnted'herein Is.based'on data consldered to be accurate:as qofihe date of' priearation ofýitW Material Safety bDiaaSheet. However, MSDS may:nori be sediasa,`9cmm**a.I, spediflcafon stfeet at maf".actur*er.sellre,

' and no.warranty orrepr.esentation, eýpweSSed or*.nplied, t*mande

a. to the acfcy. ,oo;pfehensivenes:ofthe fo*e*going data and sfely infrma*ioni,.nor 4san.t. ..zaion.

gven Or mpi`ed top`actý any Paeee10nivention wight a`Icense IInaddin, nIur , wbllity b can

'a ' ". d~ ~~a4damage by "ssumed

'm = by dendprforor injury:*Wsuting IN from , abnormal

""*" use, from

.... " aryfailure

. to.adhere to

.recommended

. . ... practces,,or r, from any hazards .inherintinmthe nature

. ..naur.. oth1.6 p ,

th prod,uct,. , + * + * , .

Current RevisionDate 23-Ap.-2002 RepiWcesSheet.Dated. i9 pr-20(2l Cbomplete...By.saety& EraY ergerYAR onse; Kocn Indutries; Inc..

ýND =No Da4t"NA= Not11" . ." Plifte~dOnl -4/2312002 7.1 47 Matertal Id 5371' .Tade Name.SUIL~UIICý ACID,

SODIUM HYDROXIDE .Page 1.of 8 MSDS Number: S4034 *** ** Effectivei'Date: 05/04/07.* * * *Supercedes: 1071//04 From:~~~~ M~ldmtBk~IcMallinctrodr ,

1" POW*

AitnW"~w~gvyW0ift *U4I bp *qdad toc~

Q*6, (

SODM HYROXIE

1. Product Identification, Synonyms: Caustic,.soda;>lye;. sodiu*h:ýydro'xiad,*'o 1sodj hydrate CAS.No.: 1310,73-2, Molecular Weight: 40.00

'Chemical Formula: NaOH Product Codes:,

JT. Baker: 415089, 3*7171, 3718, 3721, 3722, 3723, 3728,,3734, 3736 5.04%5, 5565 MlinckrIo: 766f 7680,7708,"7712, 7772)779--

2. CompositionInformati1on on ingredients Ingrpedient CAS No Perhent. Hazardous Sod.,--.-Hyd--*--id---. -, -9 -.. 0.

,3 Hazards Identification' Km ergency ,oerview

SODIUM1HYDROXIDE" Page2 of8 POISON! DANGER! CORROSIVE. MAY BE FATAL IF SWALLOWED.

HARAFUL IF, INHALED. CAUSES BURNS TO ANY AREA. OF CONTACT.

REACTS WITH WATER, ACIDS AND OTHER MATERIALS.

SAV4'-DATA(tin) Ratings (Provided here for your cpnvenience)

Health Rating: 4 Exteme (Poison).

FJammability Rating 0- None.

Reactivity Rating: 2- Mode.rate Contact Rating.:4 -.Extremel(Corrosive)

Lab Protective: Equip: GOGGLES & SHFELD;1 LAB, COAT & APRON; VENT H4OOD; PROPER GLOVES" Stoge Clo.."ICodie:tWft ipe (Store Sepately)

PotentialHe*althE1ff0ets tInhalation:.

LYSevereirrtant. Effects.e om halation of dust or tist vary fromomnlitati.n to serious.

am*age 0f the uipper respiratory tract, depending on severity ofeposure. Symptoms may include sneezing, sore hroat or r* ynose. Sevjrepnemoniismay ccur.:

Ingetion: :

S".Corrosive. Swallowing may cause. severe burns of mouth,*thoat,: And stomah Severe:

. .scarrig darr.h~ea, of flltissueýýand death:may result Symptoms may include bleeding,. vomiting,.

in'blood.pres.re.Damage, may appe~,r days after. erexpo~s,.ure.

Skin Contact.

Corrosive! Contact with skin can6cause irritation or severe burns'- d srig*withdge*ttr exposures..

'Eye

Contact:

.:Corrosive! Causes irritation of eyes, and..with greater exposuris. it qca cause burs that may reslt in permaneit ipairment of vision, even blindnesS.

Prolonged contactowitbdilute solutions§or dt h s tiveeffect upon tissue

Aggravation of Pre4existing Condtfiobs

Persons with pro-existing skin disordersor *eye problems.or impaired respiratory function may .be more susceptible to the effectsof the.sibs6tsce.

4.:First Aid Measu res:

Inhalation:

Removeto fresh air. "fnotbreathing, give artificial respiratioIfeatg is dilt, give..

o...0xygen,..Calla..physician.

Ingestion:

DO NOT INDUCE VOM N! Give lrge quantities of water or milk if available. Never give .anythingby mouth to an unconscious person. Get medical attention immediately.

SkinContact:

.Immediately flush skin with plenty of water for at least 15 mjiutes wWile removing

SODIUM HYDROXIDE Page 3 of 8 contaminated clothing and shoes. Call a physician, imnediately. Wash clothingbefore reuse' Eye

Contact:

Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical. attention immediately.

Note&to Physician:

Perform .endoscopy in all cases .ofsuspected sodium hydroxide ingestion., In cases of severe esophageal :co rosion,. the use of therapeutic doses-of steroids should, be consiIdered. General supportive measures with continual monitoring of gas exchange, acid-base balance, "electrolytesandfluid .ntake are. also required.

5. Fire,Figh Measures Fi'e":.

Not ons6deredi to: be.a fire hazard. Hot or molten material can reactvi.olntlyvwith water.,

Canrepact With certain. metals, such as-aluminum, to, generate fla:mable hydrogen.g

Explosion:,

Not considered topbe an explosion hazard.

'Fire Extinguishing Media:

Use any means suitableb forextinguishing surrounding fire. Adding.water to. causic solution

-generateslarge atnounts of heat.

Special Information:

In the*event of a fire, wear full.protective lothingband NIosI{approved self-contined.

'.breathing apparatus with full facepiece operated inf the pressuredemand or other:positive,.

presstre mode.

6 Accidental Release Measures Ventilate*area of leak-or spill. Keep unnecessary and unprotected people away lrom area of spill*.'.Wear ,approprate peorsonaIl.protective* equipmenta.as specified in Section 8. Spills:.Pick up and placein a suitable. container for rechahation or,disposal, using a method that does not generate.duk. Do not flush caustic residues to the sewer. Residues from spillscan be, diluted with water, neutral*zewith. dihlute acid'such as acetic, hydrochloric or sulfuric.

Absorb neutralý,ed caustic residue on clay, vemiculite or other inert substance and package.

in:asuitable: container for disposal.

U'S Regulations (CERCLA) require reporting spills and releases to-soil, water ad air in excess .-of reportable quantities. The toll free number for ,t*eUS CoaýstGuardlNational Respone Center is (800)424*8802.

7. Handling and Storage,

SODIUM HYDROXIDE Page 4. of 8 Keep in a tightly closed container, Protect from physical damage. Store in acool, dry, ventilated area away from sources. of heat, moisture and incompatibilities. Al.ays add.the caustic to water while stirring; never the reverse. Containers of this material may be hazardous when empty sincelthey retain: product residues (dust, solids); obsereall warnings and. precautions listed: for the product. Do not store with aluminum or magnesium.

Do not mix with acids or organic materials.

8. Exposure Controls/Pers0nal Protection Airborne Exposure Limits:

OSHA 0 Perssible Exposure Lmiit PEL):

.2.mg,/n3 Ceiling,

- ACIH Treshld imit Valule (TtLV):.

r2g/m3"Ceiling.

Ventilation System:

system of local and/or general exhaust.is recommended to keep employee:exposures below the Airborne Exposure Limits. Local exhaust.ventilationis generally prefered, because it can control the emissions of the contaminant at its source,.preventing dispersion of it into the general work area. Please refer to the ACGIH.doc uent,.!ndustrial Ventilation, A Manual ofRecommendedaPractices,mast recent edition, for details.

personal Respirators (NIOSH Approved):

If the exposure limit is: exceeded and engineering controls are not feasible,, ahalf facepie..

particulate respirator (NIOSHWtype'N95 or better filters) may be.wormnfor up to ten times the, exposoure limit or.the maximum: use. concentration sp*cified by the appiropriate regulatory agency or respirator supplier, whicheverfis lowest.. A full-ace piece articulate respirator (NIOSH type:N100 filters) may be worn up to 50 times the exposure:limit, o the maximum use concentration specified by the appropriate regulatory agency, or respirator supplierý,

whichever is lowest. If oil particles (e.g. lubricats, cuiting fluids, glycerine, etc.) are present, use a NIOSH type: R or P filter. For 'emergencies or instan'eswh ere,the exposure levels a're not knownuse a flill-facepiece pos'iti"ve-pr'essu~re, air-su'pplied respirator.

WARNING:: Aii-puifying respiirators do not Dpr*tect workers in oxygen-deficient atm~osph.eres..

Skin Protection:.

Wear impervious protective clothing, includingboots, gloves, Thib coat, apron or cove s, as appropriate, to prevent skin contact.,

Eye Protetion:

Use chemical safety goggles ,and/or a full f'adce shield. wh ere splashing is possible.Mafintain eye wah* fountai andf quick-drench facilitiesinw*wok ar* '

90 Physical and, Chemicl Properies Appearance:.

White, deliquescent pellets ordlakes,

.Odor:

Oýdorless.

"S6olubiity:

SODIUM HYDROXIDE Page 5 of &

Ill. g/l00 g of water.

Specific Gravity:.

2.13 pH:

13 - 14 (0.5% soln.)

% Volatiles by vol:ume @ 2IC (70F);

0 Boiling P.oint:ý 1390C (2534F)

Melting Point:

3.1 8C (604F)

Vap0or Density (AirO):

VaPor Pressure (mm Hg):

RNegligible.

Evaporation Rate (BuAc=1):.-.

No information.found-.

10. Stab'ilifty St.ab]' and Reacivt

:adi:gct~ '-i f f&Wadeh Stabil Sta.bleunder.ordinary conditions of uselaid.torage.. Vey h*gmrscopic. -aisloWly pickqUp molstrfom air.and ract wth carbon dioxdeeofrom air.to rm sodiu lcarboate,.

Hazrdo usDecomposition Products:..

Sobdiumn oxide.:Decomposgition by reaction wiqth c.ertain*metals. releases flammnabl e and explosigve hydrogen gas.

H1az'ardous . Pfolymerizat Will not occu. ; itio:

Incompatibilities:

Sodilu hydroide in contact with acidsand organc halogcn compounds, especially trichloroethylene, may causes V.iolent reactions. Contact with nitrdmethane. ndother similar nitro-compounds causes formation of shoek-sensitive salts;. Contact with metals such *as aluminum, mandesium, tin, and zinc cause formation of.,flabmablehydrogen g..a. Sodium hydroxide, eveh in fairly diltesolUtionreacts readily'th Various*sugars to:*'ro.ducp carbon. monoxide. Precaiutionssould betaken micludingoinonftoring.tbe tank atmosphere for carbon monoxide to ensure safety of personnel, before, vessel entry.

iConditions to Avoid:

Mpistore, dustin&and incompatibles.

S1. Toieological information, Irritation d&atain,

b*bit: 500 mg/241I severe; eye rabbit: 50 ug024H severe; investigated as a mui tagen . .. ..

.--- \CancerLis\--.....- .. ...- -,. &," .:.--.--- - -

SODIUM HYDROXIDE Page 6 of 8

..--.- NTP Carcinogen---

Ingredient BKnown Anticipated IARC ,ategory Sodium Hydroxide (1.3:10-73-2) No No None

12. Ecological Information Environmeiital'Fate:

No information'tound.

viro nmental: Toxi i8t:

DNk snoiatlon foud. t

13. Disposal Considerations Whatever cannot besaved for recovery or recychi' should be handled a hazardous Waste and sent to a RCRA approved waste faciiity. Processig, Use o continatioaoof thi product may change the waste management optioins.State a;nd local diposaltregu ations:

may differ ftrnnfederaldisposal regulatio*.Dispose:of container and unused0contenfin aco6rdance wiihjederal. stateand local requirements.

14. Transport Information Domestic (Land, D.O.T.),

Prope. Shipping mM AHýDRQ E, SOLID Hazaird Class:*

UN/NA: UN 1.823' Pack~ing~Group :Z1 Information reported for producdSiz: 300LB jwternationaf(WaierJ.MLO.

Priope'r Shipping"Nam~e:. SODIUM HYDROXIDE, SOLID, Hazard Class: 8 UN/NA: UNI 823 Infonnation reported for producksize:ý 300LB6

15. Regulato Information

.-----Chem/ba-1 Inventory Stat us -'Part 1\ ------.--------- ------

SODIUM HYDROXIDE. Page 7 of 8 "Ingredient TSCA PC Japan Australia Sodium Hydroxi.:de.. (:..1310-73-2) Yes Yes Yes Yes

.Chemkcal

'.---- Inventory Status -. Part 2\ ------------ --------------

.*.Canada--

ingredient Korea DSL NDSL Phil, Sodiu4H'droxide. (1310-73-2).. .yes Yes No Yes

-\Federal, State . Interna~tional Regulations:. Part 1\------------

-SARA 3.02 SARA 313:4.-' ------

Ingredient RQ~ TPQ List Chemical 'Catýg'.

-- - -- - -- - -- -- - -- - -- - -- - --- '% *i *- ..----

Sodiuim.Hydroxide: (1310-73-2) No , NO No No

-\Federal.., Interna.ona. Regulations .ate Part 2\ ----------------

-RCOA- -TSCA-lagredient' CERCLA 261.33 8(d)

Soiu.I4ydroxide (1310-73-2f, .1000 No No Chemical Weapons Convention:ii..No TSCA 12i(b): No CDTA: No SARA 311/312: Acute: Yes . Chr*on.oqi. No Fire**No Pressure: No.

Reactivity: Yes :(Pure SoiiSid)

Australian Hazchem Code: 2R '

Poison Schedule: 86' WIOMIS:

This MSDS has bee prepared accrding6to the hazad cri*tria.of the Controlled Products Regulations (CPR,) and the MSDS contains all ofthe in.formationrequired by the CPR.

1160 Other Inforiation NFPA:Ratings: Health: 3 Flammability: . Reactivity: 1:

L*..el Hazard Warning: ..

POISON! DANGER! CORROSIVE. MAY BE FATAL IF SWALLOWED;. ARMFUL IF INHALEDI CAUSES BURNS TO.ANyAREA OF CONTACT. REACTS WITH WATER, ACDS AND OTHER MATERIALS.

.Label Precautions'.

Do not'get in eyes, on kini..oron T lothi g ....

Do not brathe dust.

Keep contaier.closed.

Use only with equate ventilation.

Wash thorouhy after handling..

Label First Aid:

If swallowed, DO NOT iNDUCE VOMlTINOM. Give large quantities of water. Never give anything by mouth to an unconscious person. In. case of contact, immediately flush eyes: or skin w.ith plenty of water for at least 15 minutes while removing contantinted loohingand

SODIUM HYDROXIDEa Page 8.of 8 shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing give artificial respirationAIf breathing is, difficult, give oxygen. In all cases get medical attention immediately.

Product Use; Laboratoi Reagent.

Revision Information:

No Changes,.

Disclaimer:.

Mallinckrodt Baker, Infi.provides the information contained herein in good faith but makes no. representation as to its comprehensiveness or accuracy. This document, is intended only as a guide to theý:appropriate precautionary handling of the material ,Iy a properly trained person u.ing thisproduct.,IndividUals receiving the information m.itbust ,xercisetalr eiindependent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES.NO REPRESENTATIONS ORXWARRANTIES, EITHER EXPRESS OR IMPLIED..

INCLUDING WT.HOUT LIMITATION ANY WARRANTIES OF RCHANTABILITY,, :FITNESS FOR A. PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SETFORTH HEREIN OR THEPRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WIELL NOT:1)E.RESPONSIBLE FOR DAMAGES: RESULTING' FROM USE OF OR RELIANCE UPON THIS INFORMATION.

Prepared by: EnvironmentalHealth,& Safety, Phone Number. (314) 654*.1*600(U.S.A.)

ODectvive 20011581EC w United Kingdoii X)

SAFET T DATA SHEET ABC 3 AN'T1FOULING AIMERON 41.1 . dentfi~cvjor of the preparation and Of he company Product name ABC 3 ANýiFOUL INCt S~$ no. ,v-V(J2,3SAk Adea oDfanpflic'ti For*.professional use onlfy.

Prodqct use TIN~ FREE SELF POLISHlING ANTIFOULONC suoplierilMatitýaclurer Afflefon B.V.,

J.F Kermnedylaan.7 P;O., Box-6,4190Cvedemle TýIlephoneino,.

F.ax f0.ý 4.(31) 345-58.7 587

'numbe'r Sustnces-presenti 9 a hathe!~ or rena zrdwithin the mnezn~n of the angerosS stn s 0~rei~S7S4~EEC.jAS K~l~~h number ;:1:......... ...!.

[21 5-27D-7?

71k 4,

I2O*m S5 13 144 3,- 2 ,"4- R50,153 d0~50-09-7 '232-.475-7 P.43 R57, "Xylenc .0 -248-8 3 1.-2 xn - R202,.

)0"; R37, R41 R4,3-

.R.50/53 1.-4 1-4 F. R Ii (n,R2 0

Seasect3iO 1t3 for- the full te.Ac of.alhe lphraseS

O~cuptI~i~lexpsur ~mtvavailab*ý 4ere t!~e Inston

3. HazardsIde~itffi~tion ....

Theprpabton5.ified .as cang e,6U s ccordinglo OffecOve 199.9!45/Ec an aedret*

It iZ~s~i1catior qi XPý R22.

R41.

l~ysi 1tt00*'ntciCýiPazarC1 ~ m~

Humailhe~fth h~azard H-arrfrlluitI swafllwed.

To>dc ty inhiaftion.

Risk &fsefious. damage tb, qyes.

May caus'e sýnrisjfim Oon by.-skin cont;4cl.

.PVI ironmerrtal hazards Very.7o. c to .aqUalIC Drg inkMS. May CZaUselong-terrm adverse eOeclifl the aq~uaic en, fronment ~----'-

ASIC. NTIFOULING SFirSit-Eid measures easurems "l.~

Neverr*.ve.

Gene~ral In all cases of doubl or whon .ympto0ns persist,. se k medicalzatention, ari"thing by mouth.t0ca.n unconscious person, is, Inhalation Remove to fresh 2ir.. Keep person warm arn at rest. I not brea thing. iUbreathing I3y irrecular crr? raspiiaý'orv arrest occur. provide arii c,-oIraspiration or oxygen by mouthý If unonscious, place*In rocover posltin Lrolned peronrieL Givy no:hing Remove coniaminated clothýih arnd shoes. Wash skin (thr uqgh!y x.th soap end Skin Contact watf.or use recocnised s.!n cleansar. Do not use soIvets, or thinners, Eye contact Check for .andremove.any concnt lenses. lmrhediatelv..iush ev.ys wIth running water.Ior .o leas. 05.minutps,. keepir, eyelids open.

___________________ Kelip soiwam m at rdr.;0 ho nt iný:l~e vom-rifr'g.

5 Fre-fi Ugtng me-asures Exgt n~omne ig ei hilohl-re-sisfst'nffam. CO pmwdcr5, waler, spray.

Not to 6uS'di `:WaOIr jet, Fire wli4&6dns ltk moke. Exposuii&tdde-'oomP'osltion products flay IRcommifengdtons I cause a heal~th har.ppprteretngappa'ratus maw berquld.C c~losed containsrs expo~ad t6 fi.re with water, Do nr,*,reiessb runoll fromnrl~ir-o sewers mrate'r~w;ayVs-16, :Nciderital releas e measiar~s . ...

dr misOrl Person-al precautiors Exclude sobrceds of Igrnition and ventilat the arevaAvoid breathing ,apour Refer to pratective mreasures listedin :sections;,7 and 8.

Contain,ahd *collect spillage with no*n*-rombustiblt, arbstorbenl matenzi Om. s-nd.

Spill erth a. aptac6 irniýftainer for dispil eerth, germiculfte or *oirrmaceoui not aiioW*o. enter drtins~orl accor-jing. to locl regulat~ons (~sesection 13).* Do Ii old watercoUr!%es, P e'aIy clean with a ldlar~ent, Avoid usirl~.i~ otents..aUlhOrldles in produc0*-hc*trmnate$ a:kis, riversor sewer..inform Ihne:'ppropriale wilh local reguIatloit, .- .

,accord*and

.Note:: See.0sectonM 8 for persorlI protectlyvýequipri-efllt and secttonl13 for WO$ý cnSPsz4at

17. Handlingand -toraqe fioors. Vapours, may torrnt.

HadlngVapoums21e fheai/ief tht~air and rnhy spread-aloaig concent~tion~o~vurst ai6~r -. voia vabou~cnra~f5hge' tat~

. Nfimit"a, OcncontraliofllesPirO

An~addliki% the Or ddc thtlol~d~ tbe us~m inrea`Ee'6q- rmhý.~tfa(dlgt qupnitSO1 be.

a.nd1O()t sue? s o iqlinzvýbe e&:,I~ded

~atc To ei~i~a fttqv a s r ~ ~ m 8~ connec; to e tv n frln

'Tonr ndFlQecuIC sn"6(lb P dud ansfk>eirth -Srdnd

.clothing: antg flvors: should 64 Oft. cvndulr4gýy~e, fromnhe4 wit:0parisd fitre~.Ns m-<i~

tfgh0' closed. Ke"p'.#

Keep contlaln r used'l tol should be

'n, se.Avoid Uhe Inthalationio.ds. att spry Avioid njaactwit ýsKi f ~

the aopkp li~tin of tis prs~~~ o aat~

-ntiMs zi--Nng fro m SZnan111,91 hlmtfa 15.dep~hbtdr~rayh Eating.. drfnking 3an: smokaing hii0 as hrodý and. fie be fore han-dldd; storerd anld processed. *66kir

?;Oti;lo ap' opfla~tepfOOhPýsra~'P 05CllvaqLiiprrient (see section 8)

Nev r uise pi6ýsurecý cmp nty.Conaie Is'n~ot 3 presslureyves~l ~~Skpi

Connalnerm made fromr the ~sarriai.halrlai as thii original one.,

Comply..witil the health and safety awor'k laws.

ABC.ý TIFOULING

7. Haridir0.9 and storage___ ____________

v~rtlaton b&Th4~tc~

s urli~tvO ~nt~ii oaicj~e;ard soilv&n vab~our ;n all cases, In such circums irarf's hey' sirould ý-;ear a.cdrmpreszed air-fed respiraw~r during thie spraying prckless and urilil su-h 6rn at th; particu~lates anid solvent

'vapouJ- coricenlraclor has fallen belowi the exposure. limit5, Stoag :Store iniaccordarice ~vlth,!ccýI rdquladons. Observe label PraCau Lionls. Storq tze!ýeen: 5 to 4.0ýC (41 tno (14,F). Store in aoo~l, wl- lldarea~away firnm wrCo rrigtnis en8. ignition sources:

mbtc Keep aw'~ roam.'ý 6jdfng agehits, strong atl.kalls,stCong acids.

,,t6 smo .kiIn.g. thciu~rl.sej urvi ocess Containers that have be~eooned 'Lt tiemdafefullyresiialdz nd kipt upright foqrevent!&a~kage; Onnot em~nty mididrains..

B. & ' ure contrbfs/'personail prt-ctih Enginee'ring. rnasti,,r~s, PrvtVae~l sain her6 reasonably/pra ctirable,%thjs should~bel, Itiese ate not suffil it 16qltntain cocnrt~sc~parl lacl;~o and solvent' j'apuur.u b of64 the O2L, suitý ble te, rl yprtco jlntrdient ram a t~ni~ouclmt VVO-EL Qjnjted khndm(K: 1/2005).

SU~"$ i152n~ I~m nutoDs I' emirni Allors F~rn:All tf.S' 8 horihurS

,STEt. 7 porn 5 niintiteirrinutes., Forrm' Alorms

ýTWA2- 50 plarii: 8 hoy~/oj Foftt-r:Ais rm, .~n

~ee. ýI10-VEL (United' Kihgdorn (UK),'112005). Skn STEL:.'141 nig/irnt I5 m~nut/mihuies. r-rm. Al I' forrisi

'STaEL110 TOwpn . &iw l forbms Form:rillOe 1

'TIMA: -220 rnjitm kh6U i~hq5 Form All fol-rns TWA?. 5.0ppm I uhu Fn'h A~l formis

ý,-Eihylb~j 6se. * .WSWL(VfliteNd gdorn (UK),~tO 1205.Slin

.~j55rutlmnues ~ Forni

. _STFU2A25 aorim 16,rnirmtemilinup-z, Fa&n Allfom

.4 I7W~Nx. 100 ppmn 8:Q ho FormA!1rn uftlCLf e1Uwedto canceniia-tons'ab9~ th :oxpC're Umrl~rlI I

-;;kpprfleace.. 14j,le tt-,gjd/orwetqipql of the drvy painl RiM w.tgvetetot5 aitrh~zdi. 5adnfittrqso he Used whareve-tPossibe !

.:piatr prte Iveqw-pi-ý,eL should~ ~(~d Skin ard body, Peraonn~el shioutd weenifai ~ ng rd a'ftufr$P'flbrea o N

.temperauer~l~yt~b irs Hands, GlaYq5 ~Fr d9edadI1~A5 9rirod ~ves~ iri~

Banrcem M,, ept pral,ýecflh~e exposedf are~as of the s~ln pui:.hould 66ot be apoUed:once cxposA 'its oc~urrad.ý mpw'ýL21P The. user mpsl. che,;k.Wattte finhW choice of ty.Pe of Glo6ve &elec~led f~r hanctliflg this product 15 1lne F_ u,se sifetr ýyý104e06Q-Apoblect agoln l2p;O-a vironm~ lt~[OXP~----------rs Odgur -Solvent.

Colour Flash poin~t, ýCIoseq rujp'25C (ITT(et~a~i 100-10 KU@ 2-C ASTM 0-562, Rlelative C604iit"Y -95. 'CI 7

ABk_. aNTIFOULING _______

19. Physical andi chemical properties ____________

Vapour pressure 10 7:.:Pi~(80,a. mm Solubility InsoL)uolO ri,Coidlivat.ý-: ht)water:,

Auto-ignition Ternperat~r6:. Tbe lo~esl :4nolsi vsfaijr i$4id.+/-85*C ý.7aý0)(-ývr-t)ppi--d)

ýSlnsve 603er re'cmmotnoenoe lorkv and hndi~n o conn~tions (see secvIon 7),

.Hazardous de~pmposlllorl rodtjucts Caron r~n:d, abndo~q mk~~dsrit~e~

Keep muzy frdrni~te WIIbmowngi mtaterials to. Pieen irong-ýax thrrnic re.ýc ton~odcfising g§ l.sg~I~i~f~~

7T IogicaI inlasf xi frm.aupion~ and Tftmfe i no data avatlabe oii mse pmviredonitseIL Thepr1fparat 16n hzasbe enZsee fo~it~ a~ellf~

sctions2 and (o

&5Walf%

ExPOSUre To onomporine solvenit vaP~qr concenritions in emresz~of trle ialedýO. C~~~aevosure Iirnitlm4ayrsutjt in /ers hedltll erfectSUChýas 1u OUS.Mernbrne and resfregion(ysys~em fthilatiori and adverse effec's on the; c~f nervouves Aidrtdy$. liver a rm:,nmal m4'y ývoie mre of *he above ffecs bysialQn khrotig\

skn Syrnptomsamlslps ~tvud.ft --. eiadkiie. dlzznCs!T!a tigue,: muscular Wieakness, dmyinelskIýd, in xi~

losC~osi scsýRontact with Irtepr.epa (atio mpyeUse. remvinarl t JrMrth sinr~UI3Q[gfrK] io)(In:-afIIcc cntmacl dermalitis eind aI4ýqo.Ajo hr,,ugh Ite sktri-,If spl101`Md F!tpe 0yR5s': 17~

tidjay cau~1t-ýIl~atl~iorarnd.:e~ersilbe darnag e.

Corisesins 4ca lophony v-:ýtaISO) key produge arn aiterqic .rddction.

dvaa8tinbie n tfi,-epreparaliol 115611'.

C tjatisnb e~o h agt Prepa0atSons DfrclIvBe-The prepzarol ton-q,_el3~~e ootgte~neftoa Ero l*:*1*It .

PrCOditiVdelfte ___1_ >1.000e zmlclt ma)ý(EO 4a hoiur/hours n.1.90igt LepOmnis macro t~ it'shir 30 n~

p~mea PimiPh8ue$ 4L6OhOUrihoUrS 230:6rn9It, ECA~

I ,50 ý8 hou .r~houfs 2310 rny![

scenedesnii utsoi~t )01^ 4OýhOý 1 :12550 mg/f

.dr.nrykhv Mkiss 96hourlhours, A30rgt 96 10 mg/iI PmphISPOreasL~) rthqJt 50m/

Pimepmelete pone~as(LC5Q ~o~3~ 832g11 cRss 96 hourihours

.y On~Oyrlh, 9/

ecr~hfl4S(LCo) 'i~ourkthurv,no Lepois

-h~i LCM~) 96ýhour/HoUr*,

COtifljq 12,.3mo/t

.LePorn s rad'ochfJ(C) g 13hurioust.4 qati~ maoni (EC50)Y 48 houtahoun I.,048 rMg /i.

Pimephates &OmbrlýW(Lao). 98 ltcurcfurs 0,00a cr19/I

~LeOri5c~chn.Si ~ hour/houri

ý :98 0,0097 mgfl Onco 'rnytchusrnkS 96 hour/hoitirs 0..27 mg411 (LCSO).

7

- ~~ ~ ?eil~~~~~~~~0

tutt L5)6 JthWO M9II

ABC~ NTIFOULIN(3 a112. Ecolo~ic-aI information ObybeIz qaDphNs:ia nare (ECiO) 48 flourthours 2 93 mqiI 9 aphni~a mapna (EC5O)ý .48.hourthou~s 2.97 mgA S.ýýerensstium~capnrioomutum 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months !hocur 7.2 rngII Onccrhyncahus mykýss 96 hourthours 4-,2 rr~ic Pimeophal~s promnals LC501 .96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months !hotis 9.09 rngil eo'-c0Ia reftcula (LC50~ 'S5 hoW!u.0 rs M93 .1g 13.. Disposal ccnsidier'Wior'is .........

to ndi~nldwta cn!Cr 6rains cr:MirerctUrses.

Di'sposc f i*o'idina 10 all feder'al. rten locel applicable qutatOris;'

Ha~rous ~steThoct~s~fict tJýprdukfirmy nelet thie c 6fol ftd~for 3 haz r ~s dte.,

ý114. Tran~sport Offor m.- .....

Transport wfthin tisers prpTr..rseIs-always trzvlispori in ciosed ~ii <f~and securO. 'Ensure cha4, persorhs trainsoor~lng ihe prtdluct R-now '."hst COdCf lrith e\e~nt afWnqCn1deriiirsp.lliag UN, numnber UN 1253 Transport1 documneritInane Pala~.

Specid provision 540 ADRIRIrJ Class 3 HluKemje~r puh'ber ',

Rac~dnq gr cup il UN~n~umber U1.263 Prbpeir i;hlpping name IM06 CLa66 Eme"rency soheduis' UNn61u..m.bey ý.UNi263, props-er silipping name-~

tcAOitAtA Cla~ssifl~ntZrn pac~king group' lCA0~A~tA I ~ib.

____ ABC,___NTIFUULING

.5 Rugwafdry informnation EUreuain The PridVO jS clal3sra an faaif kw ;jj~iV in ~r AnYw. the, recuvt:

Hazard syrnb~ot/syrnbols Toxic, 'Daingeroujsý for the envirommennt.

!ýJsk.pOrasbs R23m roic býJnhlaaic~

022 ýHznifun f zi, -d.e

ýR1- .Pisk of erious damag~tio eres.

a43- Mzt' cause S suisption tby skijn cOntactt.

M5OM-2 Veryio to aqei6 sns~n~ oa-01 in.the aquai~c envoftir T ýer~aves S23- Do hot orepIhe vapour i'spray.

S.2.4 Avoid COAL.act 41th'skim.

S26- Inc~s fcna~wr'ys ne mmtari Mhprttof watýr and seek%

S3739-~arsUi~abie af)Os.y vnd ey.ý&face prcec~ibn~.

S38 In~c~se of* suu`-'nt venUlatndi, w-eiaf suit~bersiaoyeu~t S45. In case. oftaccidept or it.you feel unwell', eklmedicai advrre immedizfthV C6J1 phony

dUstrta I Use oni~ nt~a~~ aasetde o osiueh.Tehorair uer ue Thewnf n. esrqjmc by Olther Ootaltlh SrId S~aftey l~tonhe roisiorý of thfb natio~na.l fbeath anjd sae!eý Elf worn regu~lgtons aopliy ioltbe~bu t s-Pbodiscl, i work,,

This. prodauct deIc&i rntnemonsztng bio-tfdes and coriplles wits .hte Tr Iyrallonali Coernion ondlhe.Contr-cl OHarmrfut Aif(.ouhg 'Sysem a$dtd by[O clober 2001; (MO ~i1e

.Typ 6f Aht~joujlg:ý s~m -rin free-self-p 1ýhikg

,Nphe of paint:ý A.BC3 Antfouileg~

Ndt~:.

me Thiss~hohiribAlli { tenttrelAli O'jfr prodluct contaiers canitngi 'hit n~m,~cti~t~iththe[M Corwertion (AFSCNF2) Thls ',ap >lies! to al91 colburs Of ihis~produk A6tive~virýdin'p ia (A o. f37Z360.4) dlhCO'pp&Coxtdd (PAS -P-'. 1317-304-).

jl& Oter, forittidn CEPE Clgssificat~on ...

'* 1 . .

retelfred to. in sections 2 and 3Unite.d KIngdorm IK R26.- veloxic ' y inhalation.,

rýb R2~~. ~iatian.

0R6Ov Ho-~tainlu tby inhalulton.

202. tu)' by in31 hI~to6 AnS i conp Ct wi Ih skin',

aflowe&if I2mu'd 1R48422- Harmfuh.1danger of serioul is~r dmpto-health Dy' pro qngedeOsuei R17 . Imitartig to respiratory sjsiteir.

R3/3nItating- to respirator,/ systemeand skin.

Fk3. Hntaung to ,s~kjn.

R50153 yenj toAdaot arut~vic lr;,m~casin~e ad-vere effects tný lhellnforrra'.tlon In tisitafety Diitz Sheit is required pursuant to,ELJ ire6AVv# 0i115iEEP~prnd it~s'amendmerits..

Date of prinhtng: vyz00~.

Date of Issue 1(17(2006.

ABIL ANT1FOULING 116 Oter 4 informalion Notice to read-ei

.The Information in This. SOS is based on the presentsta.te of our knowleCge~arid'oncurrentlaws. The product is~not to be used for purposes other than those specified under section 1 without ftrst obtaining written hantirtt i.,nstrutions.,If is always the responsibility of the user to takee f necessary steps.,to fulfil (he

.demands.setou.. in. the local rules and tegislaton. The information in thks SOS is meant to be a description of hoe safety requ*frements for our produc.,It is not. robe.considered a.guaraneeeof the prod~ct's propgriles.

3F0313-03, Renewal of the Crystal River Units 1, 2 and 3 Industrial Wastewater Permit FL0000159

Contents

Text

Subject:

Dear Sir:

Attachment:

Dear Mr. Harris:

SUMMARY

Contact:

Contact:

Contact:

Contact:

References:

Contact:

Contact:

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3F0313-03, Renewal of the Crystal River Units 1, 2 and 3 Industrial Wastewater Permit FL0000159

Text

Subject:

Dear Sir:

Attachment:

Dear Mr. Harris:

SUMMARY

Contact:

Contact:

Contact:

Contact:

References:

Contact:

Contact:

Contact:

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