ML103200148: Difference between revisions

From kanterella
Jump to navigation Jump to search
(Created page by program invented by StriderTol)
(StriderTol Bot change)
 
(One intermediate revision by the same user not shown)
Line 15: Line 15:


=Text=
=Text=
{{#Wiki_filter:ENCLOSURE4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
{{#Wiki_filter:ENCLOSURE4 Response to RAI 15.3.1 - 1.a.
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 WBN Unit 2 Post-LOCA Boric Acid Precipitation Control Analysis Introduction The purpose of a Post-LOCA Long Term Cooling Boric Acid Precipitation Control Analysis is to determine the appropriate time to realign sump recirculation to hot leg recirculation in order to flush the core of highly concentrated boric acid. This is referred to as hot leg switchover (HLSO)time (i.e., simultaneous injection).
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 WBN Unit 2 Post-LOCA Boric Acid Precipitation Control Analysis Introduction The purpose of a Post-LOCA Long Term Cooling Boric Acid Precipitation Control Analysis is to determine the appropriate time to realign sump recirculation to hot leg recirculation in order to flush the core of highly concentrated boric acid. This is referred to as hot leg switchover (HLSO) time (i.e., simultaneous injection).
The injection and sump recirculation ECCS modes are described in Section 6.3 of the Unit 2 FSAR 6.3. Boric acid precipitation during long term cooling is addressed in Section 6.3.2.2 of the Unit 2 FSAR. Operator actions to prevent boric acid precipitation are described in Sections 6.3.2.17 and 15.2.13.2 of the Unit 2 FSAR. The switchover from injection mode to cold leg recirculation mode and the switchover from cold leg recirculation mode to hot leg recirculation mode are described in the Tables 6.3-3 and Table 6.3-3a of the Unit 2 FSAR.Input Parameters, Assumptions, and Acceptance Criteria The major inputs to the boric acid precipitation calculation include core power assumptions and assumptions for boron concentrations and water volume/masses for significant contributors to the containment sump. The input parameters used in the WBN Unit 2 boric acid precipitation calculations are given in Table 1 (page E4-3).The boric acid precipitation calculation model is based on the following assumptions:
The injection and sump recirculation ECCS modes are described in Section 6.3 of the Unit 2 FSAR 6.3. Boric acid precipitation during long term cooling is addressed in Section 6.3.2.2 of the Unit 2 FSAR. Operator actions to prevent boric acid precipitation are described in Sections 6.3.2.17 and 15.2.13.2 of the Unit 2 FSAR. The switchover from injection mode to cold leg recirculation mode and the switchover from cold leg recirculation mode to hot leg recirculation mode are described in the Tables 6.3-3 and Table 6.3-3a of the Unit 2 FSAR.
* The boric acid concentration in the core region is computed over time with consideration of the effect of core voiding on liquid mixing volume. Voiding is calculated using the Modified Yeh Correlation described in Reference 1.o The core mixing volume used in the calculations is shown to be conservative with respect to the potential negative effects of loop pressure drop on core mixing volume.o The liquid mixing volume used in the calculation includes 50% of the lower plenum volume.The boric acid concentration limit is the experimentally determined boric acid solubility limit as reported in Reference 2 and summarized in Table 2 (page E4-6). For large breaks and large small breaks, the effect of containment or RCS pressure above atmospheric pressure is not credited and the boric acid solubility limit at 212'F is assumed. For large small breaks where RCS depressurization is not complete or for even smaller small breaks where the RCS might be at elevated pressures at hot leg switchover time, the solubility limit associated with the saturation temperature of water at the associated elevated pressure is credited.The decay heat generation rate for both boric acid accumulation and decay heat removal is based on the 1971 American Nuclear Society Standard for an infinite operating time with 20% uncertainty.
Input Parameters,Assumptions, and Acceptance Criteria The major inputs to the boric acid precipitation calculation include core power assumptions and assumptions for boron concentrations and water volume/masses for significant contributors to the containment sump. The input parameters used in the WBN Unit 2 boric acid precipitation calculations are given in Table 1 (page E4-3).
The assumed core power includes a multiplier to address instrument uncertainty as identified by Section 1.A of 10 CFR 50, Appendix K.* The effect of containment sump pH additives on increasing the boric acid solubility limit is not credited.E4-1 ENCLOSURE4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
The boric acid precipitation calculation model is based on the following assumptions:
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 For SBLOCA scenarios, the analysis does not assume a specific start time for cooldown/depressurization in the emergency procedures, nor does it assume depressurization to some minimum pressure at hot leg switchover time. WBN Unit 2 is designed so that high pressure SI provides hot leg recirculation flow. As such, it is not necessary to depressurize the RCS to get effective core dilution flow. For the purpose of defining expected scenarios, it is expected that operators will begin cooldown/depressurization within 1 hour of the initiation of the event.The boric acid concentration of the make-up safety injection water during the injection phase is assumed to be at the Technical Specifications maximum RWST boron concentration.
* The boric acid concentration in the core region is computed over time with consideration of the effect of core voiding on liquid mixing volume. Voiding is calculated using the Modified Yeh Correlation described in Reference 1.
The boric acid concentration of the make-up safety injection water during the sump recirculation phase is a time-based calculated maximum sump boron concentration.
o   The core mixing volume used in the calculations is shown to be conservative with respect to the potential negative effects of loop pressure drop on core mixing volume.
The boric acid concentration of the make-up safety injection water during the transition from injection phase to sump recirculation phase is time based calculated average of the safety injection water source (RWST or sump)." The sump boron concentration is calculated over time using the maximum mass and maximum boron concentrations for significant boron sources, and minimum mass and maximum boron concentrations for significant dilution sources.* ECCS recirculation flows are evaluated by comparing minimum safety injection pump flows to the flows necessary to provide decay heat removal and core dilution for breaks in either the hot leg or cold leg.The above methodology meets NRC stated requirements in Reference 3 and is consistent with the interim methodology reported in Reference 4.The methodology was also consistent with the methodology used to support the recent Unit 1 TPBAR license amendment request and related USNRC SER (References 7, 8 and 9) with one exception; the use of time-based containment sump flood-up calculations and the resulting ECCS flow boron concentrations.
o   The liquid mixing volume used in the calculation includes 50% of the lower plenum volume.
Whereas the analysis for Unit 1 assumed that all sump liquid constituents reside in the sump immediately after a LOCA, the analysis for Unit 2 considered specific ice melt and RWST draindown rates to calculate the sump boron concentration over time. The Unit 2 results show a slower rate boric acid buildup as compared to Unit 1 primarily due to the higher RWST and Accumulator boron concentrations assumed in the Unit 1 analysis.E4-2 ENCLOSURE4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
The boric acid concentration limit is the experimentally determined boric acid solubility limit as reported in Reference 2 and summarized in Table 2 (page E4-6). For large breaks and large small breaks, the effect of containment or RCS pressure above atmospheric pressure is not credited and the boric acid solubility limit at 212'F is assumed. For large small breaks where RCS depressurization is not complete or for even smaller small breaks where the RCS might be at elevated pressures at hot leg switchover time, the solubility limit associated with the saturation temperature of water at the associated elevated pressure is credited.
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Table I Cooling Analysis Input Values Parameter Value WBN Unit 2 Post-LOCA Long-Term Analyzed Core Power 3459 MWt Analyzed Core Power Uncertainty 0.06% (added to core power listed above)Decay Heat Standard 1971 ANS, Infinite Operation, plus 20% (10 CFR 50, Appendix K)H 3 BO 3 Solubility Limit 27.53 weight percent RWST Boron Concentration (max) 3300 ppm RWST Delivered Volume (max) 380,000 gal RWST Temperature (min) 60°F Accumulator Boron Conc. (max) 3300 ppm Accumulator Liquid Volume 1095 ft3 x 4 Accumulator Tank Temperature 40°F BIT Boron Concentration 3300 ppm BIT Liquid Volume 900 gal BIT Tank Temperature 60°F Ice Bed Boron Concentration*
The decay heat generation rate for both boric acid accumulation and decay heat removal is based on the 1971 American Nuclear Society Standard for an infinite operating time with 20% uncertainty. The assumed core power includes a multiplier to address instrument uncertainty as identified by Section 1.A of 10 CFR 50, Appendix K.
2000 Ice Bed Mass (min) 2,404,500 Ibm Ice Bed Mass (max) 3,000,000 Ibm RCS Boron Concentration 2000 ppm RCS Volume 11,683.5 ft3 Mixing Volume (Calculated)
* The effect of containment sump pH additives on increasing the boric acid solubility limit is not credited.
See Tables 1A and lB.Mixing Volume Void Fraction Modified Yeh Correlation Lower Plenum Volume Volume 50%Volume Above Bottom of HL Not Credited Lower Plenum Subcooling Not Credited* Boron is in the form of Sodium Tetraborate (Na 2 B4O0).E4-3 ENCLOSURE 4 Response to RAI 15.3.1 -l.a.Tennessee Valley Authority  
E4-1
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Table 1A Vessel/Core Region Boric Acid Mixing Volume (LBLOCA)Time (sec)1000 2000 3000 5000 10000 15000 20000 30000 40000 Volume (ft)738.2 784.3 814.1 850.3 895.4 919.8 936.3 958.4 973.7 E4-4 ENCLOSURE 4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
 
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Table 1B Vessel/Core Region Boric Acid Mixing Volume (SBLOCA)Time (sec)1000 2000 3000 5000 10000 15000 20000 30000 40000 Volume 888.3 926.2 950.9 981.0 1019.1 1039.9 1055.2 1075.7 1089.7 E4-5 ENCLOSURE 4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
ENCLOSURE4 Response to RAI 15.3.1 - 1.a.
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Table 2 -Boric Acid Solution Solubility Limit Solubility Solubility g H3B03/100 g of g H3B03/100 g of Temperature, 0 C (OF) Solution in H 2 0 Temperature, °C (OF) Solution in H 2 0 P = 1 Atmosphere 75 (167) 17.41 0(32) 2.70 80(176) 19.06 5(41) 3.14 85 (185) 21.01 10(50) 3.51 90 (194) 23.27 15 (59) 4.17 95 (203) 25.22 20(68) 4.65 100(212) 27.53 25(77) 5.43 103.3 (217.9) 29.27 30 (86) 6.34 P = PSAT 35(95) 7.19 107.8 (226.0) 31.47 40 (104) 8.17 117.1 (242.8) 36.69 45(113) 9.32 126.7 (260.1) 42.34 50 (122) 10.23 136.3 (277.3) 48.81 55 (131) 11.54 143.3 (289.9) 54.79 60 (140) 12.97 151.5 (304.7) 62.22 65 (149) 14.42 159.4 (318.9) 70.67 70 (158) 15.75 171 (339.8) = Congruent Melting of H 3 B0 3 E4-6 ENCLOSURE4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 For SBLOCA scenarios, the analysis does not assume a specific start time for cooldown/depressurization in the emergency procedures, nor does it assume depressurization to some minimum pressure at hot leg switchover time. WBN Unit 2 is designed so that high pressure SI provides hot leg recirculation flow. As such, it is not necessary to depressurize the RCS to get effective core dilution flow. For the purpose of defining expected scenarios, it is expected that operators will begin cooldown/depressurization within 1 hour of the initiation of the event.
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Description of Analyses and Evaluations The purpose of the boric acid precipitation analysis is to demonstrate that the maximum boric acid concentration in the core remains below the solubility limit, thereby preventing the precipitation of boric acid in the core. If boric acid were to precipitate in the core region, the precipitate might prevent water from remaining in contact with the fuel cladding and, consequently, result in the core temperature not being maintained at an acceptably low value.The boric acid precipitation analysis determines the appropriate time for switching some or all ECCS recirculation flow to the hot leg and verifies that there is sufficient dilution flow through the core to halt and reverse the concentration of the boric acid solution.Prior to sump recirculation, core cooling is addressed by the Large Break LOCA analysis that demonstrates core reflood with stable and sustained quench and by the small break LOCA analysis that demonstrates core recovery.
The boric acid concentration of the make-up safety injection water during the injection phase is assumed to be at the Technical Specifications maximum RWST boron concentration. The boric acid concentration of the make-up safety injection water during the sump recirculation phase is a time-based calculated maximum sump boron concentration. The boric acid concentration of the make-up safety injection water during the transition from injection phase to sump recirculation phase is time based calculated average of the safety injection water source (RWST or sump).
After an SBLOCA, RCS system will refill, depressurize and eventually enter into shutdown cooling, or will depressurize and remain in sump recirculation indefinitely.
"   The sump boron concentration is calculated over time using the maximum mass and maximum boron concentrations for significant boron sources, and minimum mass and maximum boron concentrations for significant dilution sources.
With the switch to sump recirculation, long term cooling is addressed by demonstrating that the core remains covered with two-phase mixture in the long term, thereby ensuring that the core temperature is maintained at an acceptably low value.Paragraph (b)(5) of 10 CFR 50.46 is satisfied when the fuel in the core is quenched, the switch from injection to recirculation phases is complete, and the recirculation flow is large enough to match the boil-off rate. ECCS pump availability and specific flow path alignments may reduce ECCS recirculation flow as compared to the flows available during the injection phase. After the switch to hot leg recirculation, core flow sufficient to dilute the core or prevent boric acid buildup, by definition, exceeds core boil-off and therefore provides core cooling.The Long Term Cooling Analysis described here supports the Post-LOCA Boric Acid Precipitation Control Plan presented in Table 3 (provided in Attachment 7). The flowchart in Figure 2 (provided in Attachment
* ECCS recirculation flows are evaluated by comparing minimum safety injection pump flows to the flows necessary to provide decay heat removal and core dilution for breaks in either the hot leg or cold leg.
: 7) shows the applicability of the calculations to the specific post-LOCA scenarios.
The above methodology meets NRC stated requirements in Reference 3 and is consistent with the interim methodology reported in Reference 4.
Large Break LOCA Large breaks (double-ended guillotine down to approximately 1.0 ft 2) will rapidly depressurize to very near containment pressure with no operator action. The 14.7 psia boric acid precipitation calculation models this scenario and calculates the boric acid build-up for the limiting condition of a cold leg break. Dilution and core cooling flows are confirmed for 14.7 psia RCS backpressure.
The methodology was also consistent with the methodology used to support the recent Unit 1 TPBAR license amendment request and related USNRC SER (References 7, 8 and 9) with one exception; the use of time-based containment sump flood-up calculations and the resulting ECCS flow boron concentrations. Whereas the analysis for Unit 1 assumed that all sump liquid constituents reside in the sump immediately after a LOCA, the analysis for Unit 2 considered specific ice melt and RWST draindown rates to calculate the sump boron concentration over time. The Unit 2 results show a slower rate boric acid buildup as compared to Unit 1 primarily due to the higher RWST and Accumulator boron concentrations assumed in the Unit 1 analysis.
After hot leg switchover, the hot leg injected flow will provide immediate core dilution for a cold leg break. If the break is in the hot leg, injected ECCS flow to the cold leg is sufficient to prevent the buildup of boric acid in the core prior to and after switchover to hot leg recirculation.
E4-2
Large breaks that lead to rapid RWST draindown represent the limiting case for recirculation flow requirements.
 
For plants that see ECCS flow reductions during recirculation (such as WBN Unit 1 where low head pump flow provides suction to the high head and charging pumps and a portion of its flow may be diverted to containment spray), ECCS flow during sump recirculation is evaluated.
ENCLOSURE4 Response to RAI 15.3.1 - 1.a.
E4-7 ENCLOSURE4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table I WBN Unit 2 Post-LOCA Long-Term Cooling Analysis Input Values Parameter Value Analyzed Core Power                       3459 MWt Analyzed Core Power Uncertainty           0.06% (added to core power listed above)
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Large Small Break LOCA Large small breaks (approximately 0.2 -1.0 ft 2) will depressurize to relatively low pressures (before the potential for boric acid precipitation) with no operator action. The 120 psia boric acid precipitation calculation models this scenario and calculates the boric acid build-up for the limiting condition of a cold leg break. The 120 psia calculations consider less core voiding, a lower hfg, and do not credit SI subcooling to reduce core boil-off.
Decay Heat Standard                       1971 ANS, Infinite Operation, plus 20% (10 CFR 50, Appendix K)
After hot leg switchover, as with large breaks, the hot leg injected flow will provide core dilution for cold leg breaks and cold leg injected flow will prevent buildup of boric acid in the core for hot leg breaks. Dilution and decay heat removal flows are confirmed as adequate at 120 psia RCS backpressure.
H3BO 3 Solubility Limit                   27.53 weight percent RWST Boron Concentration (max)             3300 ppm RWST Delivered Volume (max)               380,000 gal RWST Temperature (min)                     60°F Accumulator Boron Conc. (max)             3300 ppm Accumulator Liquid Volume                 1095 ft3 x 4 Accumulator Tank Temperature               40°F BIT Boron Concentration                   3300 ppm BIT Liquid Volume                         900 gal BIT Tank Temperature                       60°F Ice Bed Boron Concentration*               2000 Ice Bed Mass (min)                         2,404,500 Ibm Ice Bed Mass (max)                         3,000,000 Ibm RCS Boron Concentration                   2000 ppm RCS Volume                                 11,683.5 ft3 Mixing Volume (Calculated)                 See Tables 1A and lB.
Core dilution flow will provide effective core cooling.Small Break LOCA For small breaks (approximately 0.005 -0.2 ft 2), emergency procedures will instruct operators to take action to depressurize and cool down the RCS. It is expected that this process will begin within 1 hour after the event. Depressurization to 120 psia (the threshold for boric acid precipitation concerns) may occur before or after hot leg switchover time. In either case, the boric acid buildup at hot leg switchover time is conservatively represented by that calculated for the 120 psia RCS backpressure scenario since this calculation takes no credit for SI subcooling, nor any beneficial effects of the operator action (such as reduced net core boil-off due to condensation in, and resultant reflux from, the steam generators).
Mixing Volume Void Fraction               Modified Yeh Correlation Lower Plenum Volume                       Volume 50%
If 120 psia is reached before hot leg switchover time, the core dilution flow after hot leg switchover, which is confirmed as adequate for 120 psia backpressure, will provide effective core dilution.
Volume Above Bottom of HL                 Not Credited Lower Plenum Subcooling                   Not Credited
If at hot leg switchover time, the 120 psia has not been reached, boric acid precipitation will not occur so long as the RCS remains above this pressure since water and boric acid are miscible at the saturation temperature for these pressures.
* Boron is in the form of Sodium Tetraborate (Na 2B4O0).
Even if the RCS pressure is above 120 psia at 12 hours after the LOCA with no core dilution flow, the total boric acid in the core will be well below the saturation limit at the corresponding saturation temperature.
E4-3
Furthermore, if after 12 hours with no dilution flow and the RCS depressurized at the maximum cooldown rate allowed by procedure, flushing flow will be established and the core will be diluted prior to reaching the boric acid precipitation point. If subcooled core conditions are reached either before or after hot leg switchover, boric acid precipitation is not a concern since there will be no net boiling in the core. If subcooled core entry conditions are not reached, the operators will continue to depressurize the RCS under controlled conditions.
 
Sump recirculation will continue, decay heat in the core will decrease, and core dilution flow will prevent the buildup of boric acid. Eventually, subcooled core conditions will be reached and the system will be put into shutdown cooling, or it will remain in indefinite recirculation cooling. It is important to note that WBN Unit 2 is designed so that high pressure SI provides hot leg recirculation flow. As such, it is not necessary to depressurize the RCS to get effective core dilution flow.Very Small Break LOCA For very small breaks (less than approximately 0.005 ft 2), emergency procedures will instruct operators to take action to depressurize the RCS. Because the break is small, subcooled conditions will be reached prior to depressurization to 120 psia (the threshold for boric acid precipitation concerns).
ENCLOSURE 4 Response to RAI 15.3.1 - l.a.
Natural circulation, if lost, will be quickly restored.
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table 1A Vessel/Core Region Boric Acid Mixing Volume (LBLOCA)
While in natural circulation, boric acid precipitation is not a concern because the core region will not be stagnant.When subcooled conditions occur, net core boiling will cease and boric acid will not accumulate.
Time     Volume (sec)       (ft) 1000        738.2 2000        784.3 3000        814.1 5000        850.3 10000        895.4 15000        919.8 20000        936.3 30000        958.4 40000        973.7 E4-4
E4-8 ENCLOSURE4 Response to RAI 15.3.1 -l.a.Tennessee Valley Authority  
 
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Eventually, the RCS will be depressurized under controlled conditions to shutdown cooling entry conditions, or continued natural circulation and sump recirculation will keep the boric acid from accumulating in the core.Results To address large break LOCAs, post-LOCA boric acid precipitation control calculations for 14.7 psia demonstrate that a 3 hour HLSO time to establish simultaneous hot leg and cold leg recirculation will prevent the precipitation of boric acid in the reactor vessel. Figure 3 (provided in Attachment
ENCLOSURE 4 Response to RAI 15.3.1 - 1.a.
: 7) shows the buildup of boric acid versus time and the boric acid solubility limit used for this scenario.
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table 1B Vessel/Core Region Boric Acid Mixing Volume (SBLOCA)
Figure 3 also shows the dilution effect of the hot leg injected flow after simultaneous hot leg and cold leg recirculation is established.
Time     Volume (sec) 1000         888.3 2000         926.2 3000          950.9 5000          981.0 10000        1019.1 15000        1039.9 20000        1055.2 30000        1075.7 40000        1089.7 E4-5
To address small break LOCAs, post-LOCA boric acid precipitation control calculations for 120 psia were performed.
 
These calculations show that there is considerable margin to the boric acid solubility limit at the designated switchover time for this scenario.
ENCLOSURE 4 Response to RAI 15.3.1 - 1.a.
The 120 psia calculations consider less core voiding, a lower hfg, and do not credit SI subcooling to reduce core boil-off.
Tennessee Valley Authority   - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table 2 - Boric Acid Solution Solubility Limit Solubility                                       Solubility g H3B03/100 g of                                 g H3B03/100 g of Temperature, 0 C (OF)   Solution in H20      Temperature, °C (OF)       Solution in H20 P = 1 Atmosphere                         75 (167)                   17.41 0(32)                       2.70               80(176)                   19.06 5(41)                       3.14               85 (185)                   21.01 10(50)                       3.51               90 (194)                   23.27 15 (59)                     4.17               95 (203)                   25.22 20(68)                       4.65             100(212)                   27.53 25(77)                       5.43         103.3 (217.9)                   29.27 30 (86)                     6.34                         P = PSAT 35(95)                       7.19         107.8 (226.0)                   31.47 40 (104)                     8.17         117.1 (242.8)                   36.69 45(113)                       9.32         126.7 (260.1)                   42.34 50 (122)                     10.23         136.3 (277.3)                   48.81 55 (131)                     11.54         143.3 (289.9)                   54.79 60 (140)                     12.97         151.5 (304.7)                   62.22 65 (149)                     14.42         159.4 (318.9)                   70.67 70 (158)                     15.75         171 (339.8) = Congruent Melting of H3 B0 3 E4-6
Since the boric acid buildup calculations for this scenario apply to RCS pressures of 30 to 120 psia, the boric acid solubility for the saturation temperature of water at 30 psia was credited.
 
Figure 4 (provided in Attachment
ENCLOSURE4 Response to RAI 15.3.1 - 1.a.
: 7) shows the buildup of boric acid versus time and the solubility limit appropriate for this scenario.
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Descriptionof Analyses and Evaluations The purpose of the boric acid precipitation analysis is to demonstrate that the maximum boric acid concentration in the core remains below the solubility limit, thereby preventing the precipitation of boric acid in the core. If boric acid were to precipitate in the core region, the precipitate might prevent water from remaining in contact with the fuel cladding and, consequently, result in the core temperature not being maintained at an acceptably low value.
Figure 4 also shows the dilution effect of the hot leg injected flow after simultaneous hot leg and cold leg flow is established.
The boric acid precipitation analysis determines the appropriate time for switching some or all ECCS recirculation flow to the hot leg and verifies that there is sufficient dilution flow through the core to halt and reverse the concentration of the boric acid solution.
In the unlikely event that the RCS pressure remains above a saturation pressure of 120 psia (and corresponding saturation temperature) at hot leg switchover time, boric acid precipitation will not occur since the total boric acid in the core will be well below the saturation limit at the elevated pressure saturation temperature.
Prior to sump recirculation, core cooling is addressed by the Large Break LOCA analysis that demonstrates core reflood with stable and sustained quench and by the small break LOCA analysis that demonstrates core recovery. After an SBLOCA, RCS system will refill, depressurize and eventually enter into shutdown cooling, or will depressurize and remain in sump recirculation indefinitely. With the switch to sump recirculation, long term cooling is addressed by demonstrating that the core remains covered with two-phase mixture in the long term, thereby ensuring that the core temperature is maintained at an acceptably low value.
In order to demonstrate the effectiveness of hot leg dilution flow for this scenario, calculations were performed for a hypothetical condition where there would be no hot leg dilution flow for 12 hours. Figure 5 (provided in Attachment
Paragraph (b)(5) of 10 CFR 50.46 is satisfied when the fuel in the core is quenched, the switch from injection to recirculation phases is complete, and the recirculation flow is large enough to match the boil-off rate. ECCS pump availability and specific flow path alignments may reduce ECCS recirculation flow as compared to the flows available during the injection phase. After the switch to hot leg recirculation, core flow sufficient to dilute the core or prevent boric acid buildup, by definition, exceeds core boil-off and therefore provides core cooling.
: 7) shows the boric acid concentration in the core with the RCS at 120 psia for 12 hours assuming no SG heat removal, no dilution flow, and no benefit of reduced steaming due to SI subcooling.
The Long Term Cooling Analysis described here supports the Post-LOCA Boric Acid Precipitation Control Plan presented in Table 3 (provided in Attachment 7). The flowchart in Figure 2 (provided in Attachment 7) shows the applicability of the calculations to the specific post-LOCA scenarios.
At 12 hours, the boric acid concentration is still below the boric acid solubility limit at the saturation temperature at 120 psia. Figure 5 also shows that if hot leg flow is established at 12 hours and the RCS is at saturation and is then cooled (with corresponding depressurization) at a cooldown rate of 100°F/hr, boric acid precipitation will not occur. The resulting hot leg dilution flow maintains the boric acid concentration in the core well below the solubility limit, even as the solubility limit is reduced due to the RCS cooldown.
Large Break LOCA Large breaks (double-ended guillotine down to approximately 1.0 ft2) will rapidly depressurize to very near containment pressure with no operator action. The 14.7 psia boric acid precipitation calculation models this scenario and calculates the boric acid build-up for the limiting condition of a cold leg break. Dilution and core cooling flows are confirmed for 14.7 psia RCS backpressure. After hot leg switchover, the hot leg injected flow will provide immediate core dilution for a cold leg break. If the break is in the hot leg, injected ECCS flow to the cold leg is sufficient to prevent the buildup of boric acid in the core prior to and after switchover to hot leg recirculation.
For WBN Unit 2, hot leg dilution flow is provided by the SI pumps which would provide dilution flow at RCS pressures well above 120 psia.Calculations were performed to support an early switchover to hot leg or simultaneous injection.
Large breaks that lead to rapid RWST draindown represent the limiting case for recirculation flow requirements. For plants that see ECCS flow reductions during recirculation (such as WBN Unit 1 where low head pump flow provides suction to the high head and charging pumps and a portion of its flow may be diverted to containment spray), ECCS flow during sump recirculation is evaluated.
Two aspects of early switchover were considered:
E4-7
the hot leg entrainment threshold and core cooling. If switchover occurs too early, injected SI in the hot legs might be carried around the loops and might not be available for core cooling and dilution.
 
Entrainment threshold calculations similar to those reported in Reference 5 demonstrated that significant hot leg entrainment would not occur after 63 minutes. Calculations showed that either hot leg or cold leg flows are sufficient to provide core cooling flow at 3 hours after the LOCA.E4-9 ENCLOSURE4 Response to RAI 15.3.1 -1.a.Tennessee Valley'Authority  
ENCLOSURE4 Response to RAI 15.3.1 - 1.a.
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 Assessments were made of the effect of loop pressure drop and downcomer boiling on the core mixing volume by performing calculations similar to those reported to the NRC in References 5 and 6. In all cases, the core region mixing volume assumed in the boric acid buildup calculation was found to be conservatively small in relation to the collapsed liquid volume based on loop pressure drop and available downcomer head.The effect of the refilling of the pump suction leg loop seals was also assessed by performing calculations similar to those reported to the NRC in References 5 and 6. While the simultaneous complete closure of all four loop seals would depress the core mixture to slightly below that associated with the core mixing volume, the expected duration of the depression would be brief. Brief core mixture level depressions would have the benefit of promoting mixing between the core region and lower plenum by cycling liquid back and forth between the core region, lower plenum and downcomer.
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Large Small Break LOCA Large small breaks (approximately 0.2 - 1.0 ft2 ) will depressurize to relatively low pressures (before the potential for boric acid precipitation) with no operator action. The 120 psia boric acid precipitation calculation models this scenario and calculates the boric acid build-up for the limiting condition of a cold leg break. The 120 psia calculations consider less core voiding, a lower hfg, and do not credit SI subcooling to reduce core boil-off. After hot leg switchover, as with large breaks, the hot leg injected flow will provide core dilution for cold leg breaks and cold leg injected flow will prevent buildup of boric acid in the core for hot leg breaks. Dilution and decay heat removal flows are confirmed as adequate at 120 psia RCS backpressure. Core dilution flow will provide effective core cooling.
Small Break LOCA For small breaks (approximately 0.005 - 0.2 ft2), emergency procedures will instruct operators to take action to depressurize and cool down the RCS. It is expected that this process will begin within 1 hour after the event. Depressurization to 120 psia (the threshold for boric acid precipitation concerns) may occur before or after hot leg switchover time. In either case, the boric acid buildup at hot leg switchover time is conservatively represented by that calculated for the 120 psia RCS backpressure scenario since this calculation takes no credit for SI subcooling, nor any beneficial effects of the operator action (such as reduced net core boil-off due to condensation in, and resultant reflux from, the steam generators). If 120 psia is reached before hot leg switchover time, the core dilution flow after hot leg switchover, which is confirmed as adequate for 120 psia backpressure, will provide effective core dilution. If at hot leg switchover time, the 120 psia has not been reached, boric acid precipitation will not occur so long as the RCS remains above this pressure since water and boric acid are miscible at the saturation temperature for these pressures. Even if the RCS pressure is above 120 psia at 12 hours after the LOCA with no core dilution flow, the total boric acid in the core will be well below the saturation limit at the corresponding saturation temperature. Furthermore, if after 12 hours with no dilution flow and the RCS depressurized at the maximum cooldown rate allowed by procedure, flushing flow will be established and the core will be diluted prior to reaching the boric acid precipitation point. If subcooled core conditions are reached either before or after hot leg switchover, boric acid precipitation is not a concern since there will be no net boiling in the core. If subcooled core entry conditions are not reached, the operators will continue to depressurize the RCS under controlled conditions. Sump recirculation will continue, decay heat in the core will decrease, and core dilution flow will prevent the buildup of boric acid. Eventually, subcooled core conditions will be reached and the system will be put into shutdown cooling, or it will remain in indefinite recirculation cooling. It is important to note that WBN Unit 2 is designed so that high pressure SI provides hot leg recirculation flow. As such, it is not necessary to depressurize the RCS to get effective core dilution flow.
Very Small Break LOCA For very small breaks (less than approximately 0.005 ft 2), emergency procedures will instruct operators to take action to depressurize the RCS. Because the break is small, subcooled conditions will be reached prior to depressurization to 120 psia (the threshold for boric acid precipitation concerns). Natural circulation, if lost, will be quickly restored. While in natural circulation, boric acid precipitation is not a concern because the core region will not be stagnant.
When subcooled conditions occur, net core boiling will cease and boric acid will not accumulate.
E4-8
 
ENCLOSURE4 Response to RAI 15.3.1 - l.a.
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Eventually, the RCS will be depressurized under controlled conditions to shutdown cooling entry conditions, or continued natural circulation and sump recirculation will keep the boric acid from accumulating in the core.
Results To address large break LOCAs, post-LOCA boric acid precipitation control calculations for 14.7 psia demonstrate that a 3 hour HLSO time to establish simultaneous hot leg and cold leg recirculation will prevent the precipitation of boric acid in the reactor vessel. Figure 3 (provided in Attachment 7) shows the buildup of boric acid versus time and the boric acid solubility limit used for this scenario. Figure 3 also shows the dilution effect of the hot leg injected flow after simultaneous hot leg and cold leg recirculation is established.
To address small break LOCAs, post-LOCA boric acid precipitation control calculations for 120 psia were performed. These calculations show that there is considerable margin to the boric acid solubility limit at the designated switchover time for this scenario. The 120 psia calculations consider less core voiding, a lower hfg, and do not credit SI subcooling to reduce core boil-off. Since the boric acid buildup calculations for this scenario apply to RCS pressures of 30 to 120 psia, the boric acid solubility for the saturation temperature of water at 30 psia was credited. Figure 4 (provided in Attachment 7) shows the buildup of boric acid versus time and the solubility limit appropriate for this scenario. Figure 4 also shows the dilution effect of the hot leg injected flow after simultaneous hot leg and cold leg flow is established.
In the unlikely event that the RCS pressure remains above a saturation pressure of 120 psia (and corresponding saturation temperature) at hot leg switchover time, boric acid precipitation will not occur since the total boric acid in the core will be well below the saturation limit at the elevated pressure saturation temperature. In order to demonstrate the effectiveness of hot leg dilution flow for this scenario, calculations were performed for a hypothetical condition where there would be no hot leg dilution flow for 12 hours. Figure 5 (provided in Attachment 7) shows the boric acid concentration in the core with the RCS at 120 psia for 12 hours assuming no SG heat removal, no dilution flow, and no benefit of reduced steaming due to SI subcooling. At 12 hours, the boric acid concentration is still below the boric acid solubility limit at the saturation temperature at 120 psia. Figure 5 also shows that if hot leg flow is established at 12 hours and the RCS is at saturation and is then cooled (with corresponding depressurization) at a cooldown rate of 100°F/hr, boric acid precipitation will not occur. The resulting hot leg dilution flow maintains the boric acid concentration in the core well below the solubility limit, even as the solubility limit is reduced due to the RCS cooldown. For WBN Unit 2, hot leg dilution flow is provided by the SI pumps which would provide dilution flow at RCS pressures well above 120 psia.
Calculations were performed to support an early switchover to hot leg or simultaneous injection.
Two aspects of early switchover were considered: the hot leg entrainment threshold and core cooling. If switchover occurs too early, injected SI in the hot legs might be carried around the loops and might not be available for core cooling and dilution. Entrainment threshold calculations similar to those reported in Reference 5 demonstrated that significant hot leg entrainment would not occur after 63 minutes. Calculations showed that either hot leg or cold leg flows are sufficient to provide core cooling flow at 3 hours after the LOCA.
E4-9
 
ENCLOSURE4 Response to RAI 15.3.1 - 1.a.
Tennessee Valley'Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Assessments were made of the effect of loop pressure drop and downcomer boiling on the core mixing volume by performing calculations similar to those reported to the NRC in References 5 and 6. In all cases, the core region mixing volume assumed in the boric acid buildup calculation was found to be conservatively small in relation to the collapsed liquid volume based on loop pressure drop and available downcomer head.
The effect of the refilling of the pump suction leg loop seals was also assessed by performing calculations similar to those reported to the NRC in References 5 and 6. While the simultaneous complete closure of all four loop seals would depress the core mixture to slightly below that associated with the core mixing volume, the expected duration of the depression would be brief. Brief core mixture level depressions would have the benefit of promoting mixing between the core region and lower plenum by cycling liquid back and forth between the core region, lower plenum and downcomer.
An assessment was made of the effect of boric acid plate-out in the SGs by performing.
An assessment was made of the effect of boric acid plate-out in the SGs by performing.
calculations similar to those reported to the NRC in Reference
calculations similar to those reported to the NRC in Reference 6. These calculations show that, with 10% entrainment for 1.5 hour, the total boric acid mass entrained would deposit a coating of approximately 0.003 inch over 10 feet of SG tubes. This coating would not significantly increase loop resistance or depress the core mixture level.
: 6. These calculations show that, with 10% entrainment for 1.5 hour, the total boric acid mass entrained would deposit a coating of approximately 0.003 inch over 10 feet of SG tubes. This coating would not significantly increase loop resistance or depress the core mixture level.An assessment was- made concerning the potential for boric acid precipitation at the hot leg injection point or at colder regions of the vessel. A simplified demonstration calculation showed that the mixing of injected SI with the highly borated solution in the reactor vessel would not initiate boric acid precipitation at the injection point. This calculation ignored temperature and boric acid gradients and assumed effective mixing with no differentiation between different mixing mechanisms such as diffusion (thermal or molecular) and density-driven convection within the vessel. The assessment also concluded that the heating of the injected water as it travels to the core region (either from the downcomer or hot leg) and the expected density-driven mixing mechanisms in the vessel would make it unlikely that significant temperature or boric acid gradients would exist. These conclusions were consistent with those reported to the NRC in Reference 6.Summary and Conclusions Post-LOCA HLSO calculations were completed for the WBN Unit 2 Completion Project. These calculations demonstrate the acceptability of the planned Unit 2 HLSO time of 3 hours (consistent with Unit 1). Switchover to hot leg recirculation at 3 hours will limit the maximum core region boric acid concentration to 18.59 weight percent allowing for 8.94 weight percent margin to the atmospheric pressure solubility limit of 27.53 weight percent.The core mass boil-off rates were calculated to be 43.86 Ibm/sec (328.7 gpm) for a HLSO time of 3 hours. Hot leg recirculation flows were reviewed and found to be adequate to ensure core cooling and to provide core dilution after HLSO realignment.
An assessment was- made concerning the potential for boric acid precipitation at the hot leg injection point or at colder regions of the vessel. A simplified demonstration calculation showed that the mixing of injected SI with the highly borated solution in the reactor vessel would not initiate boric acid precipitation at the injection point. This calculation ignored temperature and boric acid gradients and assumed effective mixing with no differentiation between different mixing mechanisms such as diffusion (thermal or molecular) and density-driven convection within the vessel. The assessment also concluded that the heating of the injected water as it travels to the core region (either from the downcomer or hot leg) and the expected density-driven mixing mechanisms in the vessel would make it unlikely that significant temperature or boric acid gradients would exist. These conclusions were consistent with those reported to the NRC in Reference 6.
E4-10 ENCLOSURE 4 Response to RAI 15.3.1 -1.a.Tennessee Valley Authority  
Summary and Conclusions Post-LOCA HLSO calculations were completed for the WBN Unit 2 Completion Project. These calculations demonstrate the acceptability of the planned Unit 2 HLSO time of 3 hours (consistent with Unit 1). Switchover to hot leg recirculation at 3 hours will limit the maximum core region boric acid concentration to 18.59 weight percent allowing for 8.94 weight percent margin to the atmospheric pressure solubility limit of 27.53 weight percent.
-Watts Bar Nuclear Plant -Unit 2, Docket No. 50-391 References
The core mass boil-off rates were calculated to be 43.86 Ibm/sec (328.7 gpm) for a HLSO time of 3 hours. Hot leg recirculation flows were reviewed and found to be adequate to ensure core cooling and to provide core dilution after HLSO realignment.
: 1. H. C. Yeh, "Modification of Void Fraction Calculation," Proceedings of the Fourth International Topical Meeting on Nuclear Thermal-Hydraulics, Operations and Safety, Volume 1, Taipei, Taiwan, June 6,1988 2. P. Cohen, 1980 (Originally published in 1969), Water Coolant Technology of Power Reactors, Chapter 6, "Chemical Shim Controland pH Effect," ANS-USEC Monograph 3. Letter dated August 1, 2005 from R. A. Gramm, U. S. Nuclear Regulatory Commission to J. A. Gresham, Westinghouse Electric Company, "Suspension of NRC Approval for Use of Westinghouse Topical Report CENPD-254-P, 'Post LOCA Long Term Cooling Model' Due to Discovery of Non-conservative Modeling Assumptions During Calculations Audit" 4. NRC/RPCL-06-119, "Summary of August 23, 2006 Meeting with the Pressurized Water Reactor Owners Group (PWROG) to Discuss the Status of Program to Establish Consistent Criteria for Post Loss-of-Coolant (LOCA) Calculations," October 19, 2006 (ADAMS Accession No. ML062690017)
E4-10
 
ENCLOSURE 4 Response to RAI 15.3.1 - 1.a.
Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 References
: 1. H. C. Yeh, "Modification of Void Fraction Calculation," Proceedings of the Fourth International Topical Meeting on Nuclear Thermal-Hydraulics, Operations and Safety, Volume 1, Taipei, Taiwan, June 6,1988
: 2. P. Cohen, 1980 (Originally published in 1969), Water Coolant Technology of Power Reactors, Chapter 6, "Chemical Shim Controland pH Effect," ANS-USEC Monograph
: 3. Letter dated August 1, 2005 from R. A. Gramm, U. S. Nuclear Regulatory Commission to J. A. Gresham, Westinghouse Electric Company, "Suspension of NRC Approval for Use of Westinghouse Topical Report CENPD-254-P, 'Post LOCA Long Term Cooling Model' Due to Discovery of Non-conservative Modeling Assumptions During Calculations Audit"
: 4. NRC/RPCL-06-119, "Summary of August 23, 2006 Meeting with the Pressurized Water Reactor Owners Group (PWROG) to Discuss the Status of Program to Establish Consistent Criteria for Post Loss-of-Coolant (LOCA) Calculations," October 19, 2006 (ADAMS Accession No. ML062690017)
: 5. Letter L-05-112, FirstEnergy Nuclear Operating Company to USNRC, "Responses to a Request for Additional Information in Support of License Amendment Request Nos. 302 and 173", July 8, 2005 (ADAMS Accession No. ML051940575)
: 5. Letter L-05-112, FirstEnergy Nuclear Operating Company to USNRC, "Responses to a Request for Additional Information in Support of License Amendment Request Nos. 302 and 173", July 8, 2005 (ADAMS Accession No. ML051940575)
: 6. Letter L-05-169, FirstEnergy Nuclear Operating Company to USNRC, "Responses to a Request for Additional Information (RAI dated September 30, 2005) in Support of License Amendment Request Nos. 302 and 173," November 21, 2005 (ADAMS Accession No.ML053290133)
: 6. Letter L-05-169, FirstEnergy Nuclear Operating Company to USNRC, "Responses to a Request for Additional Information (RAI dated September 30, 2005) in Support of License Amendment Request Nos. 302 and 173," November 21, 2005 (ADAMS Accession No. ML053290133)
: 7. Letter from Tennessee Valley Authority (TVA) to USNRC, "Watts Bar Nuclear Plant (WBN)Unit 1 -Response to Request for Additional Information Re: Watts Bar Emergency Core Cooling System Boron Requirements (TAC No. MD9396), December 31, 2008 (ADAMS Accession No. ML090220255)
: 7. Letter from Tennessee Valley Authority (TVA) to USNRC, "Watts Bar Nuclear Plant (WBN)
: 8. Letter from USNRC to Tennessee Valley Authority (TVA), "Watts Bar Nuclear Plant, Unit 1 -Issuance of Amendment Regarding the Maximum Number of Tritium Producing Burnable Assembly Rods in the Reactor Core (TAC No. MD9396)," May 04, 2009 (ADAMS Accession No. ML090920506)
Unit 1 - Response to Request for Additional Information Re: Watts Bar Emergency Core Cooling System Boron Requirements (TAC No. MD9396), December 31, 2008 (ADAMS Accession No. ML090220255)
: 9. NRC Audit of Post-LOCA Boric Acid Precipitation Analyses to Support "Tennessee Valley Authority License Amendment Request for Watts Bar Nuclear Plant Unit 1 to Revise Boron Requirements for Cold Leg Accumulators and Refueling Water Storage Tank", Westinghouse Energy Center, Monroeville, PA, September 29th and 30th, 2008.E4-11}}
: 8. Letter from USNRC to Tennessee Valley Authority (TVA), "Watts Bar Nuclear Plant, Unit 1 -
Issuance of Amendment Regarding the Maximum Number of Tritium Producing Burnable Assembly Rods in the Reactor Core (TAC No. MD9396)," May 04, 2009 (ADAMS Accession No. ML090920506)
: 9. NRC Audit of Post-LOCA Boric Acid Precipitation Analyses to Support "Tennessee Valley Authority License Amendment Request for Watts Bar Nuclear Plant Unit 1 to Revise Boron Requirements for Cold Leg Accumulators and Refueling Water Storage Tank",
Westinghouse Energy Center, Monroeville, PA, September 29th and 30th, 2008.
E4-11}}

Latest revision as of 11:08, 11 March 2020

Post-LOCA Boric Acid Precipitation Control Analysis - Response to RAI 15.3.1 - 1.a
ML103200148
Person / Time
Site: Watts Bar Tennessee Valley Authority icon.png
Issue date: 11/09/2010
From:
Tennessee Valley Authority
To:
Office of Nuclear Reactor Regulation
References
Download: ML103200148 (11)


Text

ENCLOSURE4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 WBN Unit 2 Post-LOCA Boric Acid Precipitation Control Analysis Introduction The purpose of a Post-LOCA Long Term Cooling Boric Acid Precipitation Control Analysis is to determine the appropriate time to realign sump recirculation to hot leg recirculation in order to flush the core of highly concentrated boric acid. This is referred to as hot leg switchover (HLSO) time (i.e., simultaneous injection).

The injection and sump recirculation ECCS modes are described in Section 6.3 of the Unit 2 FSAR 6.3. Boric acid precipitation during long term cooling is addressed in Section 6.3.2.2 of the Unit 2 FSAR. Operator actions to prevent boric acid precipitation are described in Sections 6.3.2.17 and 15.2.13.2 of the Unit 2 FSAR. The switchover from injection mode to cold leg recirculation mode and the switchover from cold leg recirculation mode to hot leg recirculation mode are described in the Tables 6.3-3 and Table 6.3-3a of the Unit 2 FSAR.

Input Parameters,Assumptions, and Acceptance Criteria The major inputs to the boric acid precipitation calculation include core power assumptions and assumptions for boron concentrations and water volume/masses for significant contributors to the containment sump. The input parameters used in the WBN Unit 2 boric acid precipitation calculations are given in Table 1 (page E4-3).

The boric acid precipitation calculation model is based on the following assumptions:

  • The boric acid concentration in the core region is computed over time with consideration of the effect of core voiding on liquid mixing volume. Voiding is calculated using the Modified Yeh Correlation described in Reference 1.

o The core mixing volume used in the calculations is shown to be conservative with respect to the potential negative effects of loop pressure drop on core mixing volume.

o The liquid mixing volume used in the calculation includes 50% of the lower plenum volume.

The boric acid concentration limit is the experimentally determined boric acid solubility limit as reported in Reference 2 and summarized in Table 2 (page E4-6). For large breaks and large small breaks, the effect of containment or RCS pressure above atmospheric pressure is not credited and the boric acid solubility limit at 212'F is assumed. For large small breaks where RCS depressurization is not complete or for even smaller small breaks where the RCS might be at elevated pressures at hot leg switchover time, the solubility limit associated with the saturation temperature of water at the associated elevated pressure is credited.

The decay heat generation rate for both boric acid accumulation and decay heat removal is based on the 1971 American Nuclear Society Standard for an infinite operating time with 20% uncertainty. The assumed core power includes a multiplier to address instrument uncertainty as identified by Section 1.A of 10 CFR 50, Appendix K.

  • The effect of containment sump pH additives on increasing the boric acid solubility limit is not credited.

E4-1

ENCLOSURE4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 For SBLOCA scenarios, the analysis does not assume a specific start time for cooldown/depressurization in the emergency procedures, nor does it assume depressurization to some minimum pressure at hot leg switchover time. WBN Unit 2 is designed so that high pressure SI provides hot leg recirculation flow. As such, it is not necessary to depressurize the RCS to get effective core dilution flow. For the purpose of defining expected scenarios, it is expected that operators will begin cooldown/depressurization within 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> of the initiation of the event.

The boric acid concentration of the make-up safety injection water during the injection phase is assumed to be at the Technical Specifications maximum RWST boron concentration. The boric acid concentration of the make-up safety injection water during the sump recirculation phase is a time-based calculated maximum sump boron concentration. The boric acid concentration of the make-up safety injection water during the transition from injection phase to sump recirculation phase is time based calculated average of the safety injection water source (RWST or sump).

" The sump boron concentration is calculated over time using the maximum mass and maximum boron concentrations for significant boron sources, and minimum mass and maximum boron concentrations for significant dilution sources.

  • ECCS recirculation flows are evaluated by comparing minimum safety injection pump flows to the flows necessary to provide decay heat removal and core dilution for breaks in either the hot leg or cold leg.

The above methodology meets NRC stated requirements in Reference 3 and is consistent with the interim methodology reported in Reference 4.

The methodology was also consistent with the methodology used to support the recent Unit 1 TPBAR license amendment request and related USNRC SER (References 7, 8 and 9) with one exception; the use of time-based containment sump flood-up calculations and the resulting ECCS flow boron concentrations. Whereas the analysis for Unit 1 assumed that all sump liquid constituents reside in the sump immediately after a LOCA, the analysis for Unit 2 considered specific ice melt and RWST draindown rates to calculate the sump boron concentration over time. The Unit 2 results show a slower rate boric acid buildup as compared to Unit 1 primarily due to the higher RWST and Accumulator boron concentrations assumed in the Unit 1 analysis.

E4-2

ENCLOSURE4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table I WBN Unit 2 Post-LOCA Long-Term Cooling Analysis Input Values Parameter Value Analyzed Core Power 3459 MWt Analyzed Core Power Uncertainty 0.06% (added to core power listed above)

Decay Heat Standard 1971 ANS, Infinite Operation, plus 20% (10 CFR 50, Appendix K)

H3BO 3 Solubility Limit 27.53 weight percent RWST Boron Concentration (max) 3300 ppm RWST Delivered Volume (max) 380,000 gal RWST Temperature (min) 60°F Accumulator Boron Conc. (max) 3300 ppm Accumulator Liquid Volume 1095 ft3 x 4 Accumulator Tank Temperature 40°F BIT Boron Concentration 3300 ppm BIT Liquid Volume 900 gal BIT Tank Temperature 60°F Ice Bed Boron Concentration* 2000 Ice Bed Mass (min) 2,404,500 Ibm Ice Bed Mass (max) 3,000,000 Ibm RCS Boron Concentration 2000 ppm RCS Volume 11,683.5 ft3 Mixing Volume (Calculated) See Tables 1A and lB.

Mixing Volume Void Fraction Modified Yeh Correlation Lower Plenum Volume Volume 50%

Volume Above Bottom of HL Not Credited Lower Plenum Subcooling Not Credited

E4-3

ENCLOSURE 4 Response to RAI 15.3.1 - l.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table 1A Vessel/Core Region Boric Acid Mixing Volume (LBLOCA)

Time Volume (sec) (ft) 1000 738.2 2000 784.3 3000 814.1 5000 850.3 10000 895.4 15000 919.8 20000 936.3 30000 958.4 40000 973.7 E4-4

ENCLOSURE 4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table 1B Vessel/Core Region Boric Acid Mixing Volume (SBLOCA)

Time Volume (sec) 1000 888.3 2000 926.2 3000 950.9 5000 981.0 10000 1019.1 15000 1039.9 20000 1055.2 30000 1075.7 40000 1089.7 E4-5

ENCLOSURE 4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Table 2 - Boric Acid Solution Solubility Limit Solubility Solubility g H3B03/100 g of g H3B03/100 g of Temperature, 0 C (OF) Solution in H20 Temperature, °C (OF) Solution in H20 P = 1 Atmosphere 75 (167) 17.41 0(32) 2.70 80(176) 19.06 5(41) 3.14 85 (185) 21.01 10(50) 3.51 90 (194) 23.27 15 (59) 4.17 95 (203) 25.22 20(68) 4.65 100(212) 27.53 25(77) 5.43 103.3 (217.9) 29.27 30 (86) 6.34 P = PSAT 35(95) 7.19 107.8 (226.0) 31.47 40 (104) 8.17 117.1 (242.8) 36.69 45(113) 9.32 126.7 (260.1) 42.34 50 (122) 10.23 136.3 (277.3) 48.81 55 (131) 11.54 143.3 (289.9) 54.79 60 (140) 12.97 151.5 (304.7) 62.22 65 (149) 14.42 159.4 (318.9) 70.67 70 (158) 15.75 171 (339.8) = Congruent Melting of H3 B0 3 E4-6

ENCLOSURE4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Descriptionof Analyses and Evaluations The purpose of the boric acid precipitation analysis is to demonstrate that the maximum boric acid concentration in the core remains below the solubility limit, thereby preventing the precipitation of boric acid in the core. If boric acid were to precipitate in the core region, the precipitate might prevent water from remaining in contact with the fuel cladding and, consequently, result in the core temperature not being maintained at an acceptably low value.

The boric acid precipitation analysis determines the appropriate time for switching some or all ECCS recirculation flow to the hot leg and verifies that there is sufficient dilution flow through the core to halt and reverse the concentration of the boric acid solution.

Prior to sump recirculation, core cooling is addressed by the Large Break LOCA analysis that demonstrates core reflood with stable and sustained quench and by the small break LOCA analysis that demonstrates core recovery. After an SBLOCA, RCS system will refill, depressurize and eventually enter into shutdown cooling, or will depressurize and remain in sump recirculation indefinitely. With the switch to sump recirculation, long term cooling is addressed by demonstrating that the core remains covered with two-phase mixture in the long term, thereby ensuring that the core temperature is maintained at an acceptably low value.

Paragraph (b)(5) of 10 CFR 50.46 is satisfied when the fuel in the core is quenched, the switch from injection to recirculation phases is complete, and the recirculation flow is large enough to match the boil-off rate. ECCS pump availability and specific flow path alignments may reduce ECCS recirculation flow as compared to the flows available during the injection phase. After the switch to hot leg recirculation, core flow sufficient to dilute the core or prevent boric acid buildup, by definition, exceeds core boil-off and therefore provides core cooling.

The Long Term Cooling Analysis described here supports the Post-LOCA Boric Acid Precipitation Control Plan presented in Table 3 (provided in Attachment 7). The flowchart in Figure 2 (provided in Attachment 7) shows the applicability of the calculations to the specific post-LOCA scenarios.

Large Break LOCA Large breaks (double-ended guillotine down to approximately 1.0 ft2) will rapidly depressurize to very near containment pressure with no operator action. The 14.7 psia boric acid precipitation calculation models this scenario and calculates the boric acid build-up for the limiting condition of a cold leg break. Dilution and core cooling flows are confirmed for 14.7 psia RCS backpressure. After hot leg switchover, the hot leg injected flow will provide immediate core dilution for a cold leg break. If the break is in the hot leg, injected ECCS flow to the cold leg is sufficient to prevent the buildup of boric acid in the core prior to and after switchover to hot leg recirculation.

Large breaks that lead to rapid RWST draindown represent the limiting case for recirculation flow requirements. For plants that see ECCS flow reductions during recirculation (such as WBN Unit 1 where low head pump flow provides suction to the high head and charging pumps and a portion of its flow may be diverted to containment spray), ECCS flow during sump recirculation is evaluated.

E4-7

ENCLOSURE4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Large Small Break LOCA Large small breaks (approximately 0.2 - 1.0 ft2 ) will depressurize to relatively low pressures (before the potential for boric acid precipitation) with no operator action. The 120 psia boric acid precipitation calculation models this scenario and calculates the boric acid build-up for the limiting condition of a cold leg break. The 120 psia calculations consider less core voiding, a lower hfg, and do not credit SI subcooling to reduce core boil-off. After hot leg switchover, as with large breaks, the hot leg injected flow will provide core dilution for cold leg breaks and cold leg injected flow will prevent buildup of boric acid in the core for hot leg breaks. Dilution and decay heat removal flows are confirmed as adequate at 120 psia RCS backpressure. Core dilution flow will provide effective core cooling.

Small Break LOCA For small breaks (approximately 0.005 - 0.2 ft2), emergency procedures will instruct operators to take action to depressurize and cool down the RCS. It is expected that this process will begin within 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> after the event. Depressurization to 120 psia (the threshold for boric acid precipitation concerns) may occur before or after hot leg switchover time. In either case, the boric acid buildup at hot leg switchover time is conservatively represented by that calculated for the 120 psia RCS backpressure scenario since this calculation takes no credit for SI subcooling, nor any beneficial effects of the operator action (such as reduced net core boil-off due to condensation in, and resultant reflux from, the steam generators). If 120 psia is reached before hot leg switchover time, the core dilution flow after hot leg switchover, which is confirmed as adequate for 120 psia backpressure, will provide effective core dilution. If at hot leg switchover time, the 120 psia has not been reached, boric acid precipitation will not occur so long as the RCS remains above this pressure since water and boric acid are miscible at the saturation temperature for these pressures. Even if the RCS pressure is above 120 psia at 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br /> after the LOCA with no core dilution flow, the total boric acid in the core will be well below the saturation limit at the corresponding saturation temperature. Furthermore, if after 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br /> with no dilution flow and the RCS depressurized at the maximum cooldown rate allowed by procedure, flushing flow will be established and the core will be diluted prior to reaching the boric acid precipitation point. If subcooled core conditions are reached either before or after hot leg switchover, boric acid precipitation is not a concern since there will be no net boiling in the core. If subcooled core entry conditions are not reached, the operators will continue to depressurize the RCS under controlled conditions. Sump recirculation will continue, decay heat in the core will decrease, and core dilution flow will prevent the buildup of boric acid. Eventually, subcooled core conditions will be reached and the system will be put into shutdown cooling, or it will remain in indefinite recirculation cooling. It is important to note that WBN Unit 2 is designed so that high pressure SI provides hot leg recirculation flow. As such, it is not necessary to depressurize the RCS to get effective core dilution flow.

Very Small Break LOCA For very small breaks (less than approximately 0.005 ft 2), emergency procedures will instruct operators to take action to depressurize the RCS. Because the break is small, subcooled conditions will be reached prior to depressurization to 120 psia (the threshold for boric acid precipitation concerns). Natural circulation, if lost, will be quickly restored. While in natural circulation, boric acid precipitation is not a concern because the core region will not be stagnant.

When subcooled conditions occur, net core boiling will cease and boric acid will not accumulate.

E4-8

ENCLOSURE4 Response to RAI 15.3.1 - l.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Eventually, the RCS will be depressurized under controlled conditions to shutdown cooling entry conditions, or continued natural circulation and sump recirculation will keep the boric acid from accumulating in the core.

Results To address large break LOCAs, post-LOCA boric acid precipitation control calculations for 14.7 psia demonstrate that a 3 hour3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br /> HLSO time to establish simultaneous hot leg and cold leg recirculation will prevent the precipitation of boric acid in the reactor vessel. Figure 3 (provided in Attachment 7) shows the buildup of boric acid versus time and the boric acid solubility limit used for this scenario. Figure 3 also shows the dilution effect of the hot leg injected flow after simultaneous hot leg and cold leg recirculation is established.

To address small break LOCAs, post-LOCA boric acid precipitation control calculations for 120 psia were performed. These calculations show that there is considerable margin to the boric acid solubility limit at the designated switchover time for this scenario. The 120 psia calculations consider less core voiding, a lower hfg, and do not credit SI subcooling to reduce core boil-off. Since the boric acid buildup calculations for this scenario apply to RCS pressures of 30 to 120 psia, the boric acid solubility for the saturation temperature of water at 30 psia was credited. Figure 4 (provided in Attachment 7) shows the buildup of boric acid versus time and the solubility limit appropriate for this scenario. Figure 4 also shows the dilution effect of the hot leg injected flow after simultaneous hot leg and cold leg flow is established.

In the unlikely event that the RCS pressure remains above a saturation pressure of 120 psia (and corresponding saturation temperature) at hot leg switchover time, boric acid precipitation will not occur since the total boric acid in the core will be well below the saturation limit at the elevated pressure saturation temperature. In order to demonstrate the effectiveness of hot leg dilution flow for this scenario, calculations were performed for a hypothetical condition where there would be no hot leg dilution flow for 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />. Figure 5 (provided in Attachment 7) shows the boric acid concentration in the core with the RCS at 120 psia for 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br /> assuming no SG heat removal, no dilution flow, and no benefit of reduced steaming due to SI subcooling. At 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />, the boric acid concentration is still below the boric acid solubility limit at the saturation temperature at 120 psia. Figure 5 also shows that if hot leg flow is established at 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br /> and the RCS is at saturation and is then cooled (with corresponding depressurization) at a cooldown rate of 100°F/hr, boric acid precipitation will not occur. The resulting hot leg dilution flow maintains the boric acid concentration in the core well below the solubility limit, even as the solubility limit is reduced due to the RCS cooldown. For WBN Unit 2, hot leg dilution flow is provided by the SI pumps which would provide dilution flow at RCS pressures well above 120 psia.

Calculations were performed to support an early switchover to hot leg or simultaneous injection.

Two aspects of early switchover were considered: the hot leg entrainment threshold and core cooling. If switchover occurs too early, injected SI in the hot legs might be carried around the loops and might not be available for core cooling and dilution. Entrainment threshold calculations similar to those reported in Reference 5 demonstrated that significant hot leg entrainment would not occur after 63 minutes. Calculations showed that either hot leg or cold leg flows are sufficient to provide core cooling flow at 3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br /> after the LOCA.

E4-9

ENCLOSURE4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley'Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 Assessments were made of the effect of loop pressure drop and downcomer boiling on the core mixing volume by performing calculations similar to those reported to the NRC in References 5 and 6. In all cases, the core region mixing volume assumed in the boric acid buildup calculation was found to be conservatively small in relation to the collapsed liquid volume based on loop pressure drop and available downcomer head.

The effect of the refilling of the pump suction leg loop seals was also assessed by performing calculations similar to those reported to the NRC in References 5 and 6. While the simultaneous complete closure of all four loop seals would depress the core mixture to slightly below that associated with the core mixing volume, the expected duration of the depression would be brief. Brief core mixture level depressions would have the benefit of promoting mixing between the core region and lower plenum by cycling liquid back and forth between the core region, lower plenum and downcomer.

An assessment was made of the effect of boric acid plate-out in the SGs by performing.

calculations similar to those reported to the NRC in Reference 6. These calculations show that, with 10% entrainment for 1.5 hour5.787037e-5 days <br />0.00139 hours <br />8.267196e-6 weeks <br />1.9025e-6 months <br />, the total boric acid mass entrained would deposit a coating of approximately 0.003 inch over 10 feet of SG tubes. This coating would not significantly increase loop resistance or depress the core mixture level.

An assessment was- made concerning the potential for boric acid precipitation at the hot leg injection point or at colder regions of the vessel. A simplified demonstration calculation showed that the mixing of injected SI with the highly borated solution in the reactor vessel would not initiate boric acid precipitation at the injection point. This calculation ignored temperature and boric acid gradients and assumed effective mixing with no differentiation between different mixing mechanisms such as diffusion (thermal or molecular) and density-driven convection within the vessel. The assessment also concluded that the heating of the injected water as it travels to the core region (either from the downcomer or hot leg) and the expected density-driven mixing mechanisms in the vessel would make it unlikely that significant temperature or boric acid gradients would exist. These conclusions were consistent with those reported to the NRC in Reference 6.

Summary and Conclusions Post-LOCA HLSO calculations were completed for the WBN Unit 2 Completion Project. These calculations demonstrate the acceptability of the planned Unit 2 HLSO time of 3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br /> (consistent with Unit 1). Switchover to hot leg recirculation at 3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br /> will limit the maximum core region boric acid concentration to 18.59 weight percent allowing for 8.94 weight percent margin to the atmospheric pressure solubility limit of 27.53 weight percent.

The core mass boil-off rates were calculated to be 43.86 Ibm/sec (328.7 gpm) for a HLSO time of 3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />. Hot leg recirculation flows were reviewed and found to be adequate to ensure core cooling and to provide core dilution after HLSO realignment.

E4-10

ENCLOSURE 4 Response to RAI 15.3.1 - 1.a.

Tennessee Valley Authority - Watts Bar Nuclear Plant - Unit 2, Docket No. 50-391 References

1. H. C. Yeh, "Modification of Void Fraction Calculation," Proceedings of the Fourth International Topical Meeting on Nuclear Thermal-Hydraulics, Operations and Safety, Volume 1, Taipei, Taiwan, June 6,1988
2. P. Cohen, 1980 (Originally published in 1969), Water Coolant Technology of Power Reactors, Chapter 6, "Chemical Shim Controland pH Effect," ANS-USEC Monograph
3. Letter dated August 1, 2005 from R. A. Gramm, U. S. Nuclear Regulatory Commission to J. A. Gresham, Westinghouse Electric Company, "Suspension of NRC Approval for Use of Westinghouse Topical Report CENPD-254-P, 'Post LOCA Long Term Cooling Model' Due to Discovery of Non-conservative Modeling Assumptions During Calculations Audit"
4. NRC/RPCL-06-119, "Summary of August 23, 2006 Meeting with the Pressurized Water Reactor Owners Group (PWROG) to Discuss the Status of Program to Establish Consistent Criteria for Post Loss-of-Coolant (LOCA) Calculations," October 19, 2006 (ADAMS Accession No. ML062690017)
5. Letter L-05-112, FirstEnergy Nuclear Operating Company to USNRC, "Responses to a Request for Additional Information in Support of License Amendment Request Nos. 302 and 173", July 8, 2005 (ADAMS Accession No. ML051940575)
6. Letter L-05-169, FirstEnergy Nuclear Operating Company to USNRC, "Responses to a Request for Additional Information (RAI dated September 30, 2005) in Support of License Amendment Request Nos. 302 and 173," November 21, 2005 (ADAMS Accession No. ML053290133)
7. Letter from Tennessee Valley Authority (TVA) to USNRC, "Watts Bar Nuclear Plant (WBN)

Unit 1 - Response to Request for Additional Information Re: Watts Bar Emergency Core Cooling System Boron Requirements (TAC No. MD9396), December 31, 2008 (ADAMS Accession No. ML090220255)

8. Letter from USNRC to Tennessee Valley Authority (TVA), "Watts Bar Nuclear Plant, Unit 1 -

Issuance of Amendment Regarding the Maximum Number of Tritium Producing Burnable Assembly Rods in the Reactor Core (TAC No. MD9396)," May 04, 2009 (ADAMS Accession No. ML090920506)

9. NRC Audit of Post-LOCA Boric Acid Precipitation Analyses to Support "Tennessee Valley Authority License Amendment Request for Watts Bar Nuclear Plant Unit 1 to Revise Boron Requirements for Cold Leg Accumulators and Refueling Water Storage Tank",

Westinghouse Energy Center, Monroeville, PA, September 29th and 30th, 2008.

E4-11