ML061730287

2005 Air Pollutant Emissions Inventory Report for Entergy Nuclear Vermont Yankee, LLC

ML061730287
Person / Time
Site:	Vermont Yankee
Issue date:	01/26/2006
From:	Dewald L, Wender S Entergy Nuclear Northeast
To:	Riley D Office of Nuclear Reactor Regulation, State of VT, Agency of Natural Resources
References
%dam200610
Download: ML061730287 (14)

Text

Entergy Nuclear Northeast Entergy Nuclear Operations, Inc.

Vermont Yankee 322 Governor Hunt Rd.

Vernon, VT 05354 Tel 802-257-7711 26 Janiiary 2006 Mr. Daniel Riley, Environmental Engineer Vermont Agency of Natural Resources Department of Environmental Conservation Air Pollution Control Division Building 3 South 103 South Main Street Waterbury, VT 05671-0402

Subject:

2005 Air Pollutant Emissions Inventory Report for Entergy Nuclear Vermont Yankee, LLC. Facility ID WM 2335.

Dear Mr. Riley:

Enclosed is Entergy Nuclear Vermont Yankee's air emissions inventory report for 2005.

Total air emissions from significant activities, which includes the house heating boilers and the waste oil burners, was 9.07 tons for the year. Vermont Yankee does not include emissions from the emergency diesel generators (A and B), the John Deere diesel, or the emergency diesel fire pump toward the total tonnage in this inventory report as these emergency generators, each of which operate less than one hundred hours per year, are considered 'insignificant activities under the State regulations.

The cooling tower particulate emissions calculations for the mechanical draft cooling towers are based on the drift and drift rate, and as in 2004, remain conservatively high.

The cooling towers operated for 2,149 hours0.00172 days <br />0.0414 hours <br />2.463624e-4 weeks <br />5.66945e-5 months <br /> during 2005. The operating hours were utilized in calculating the 2005 PM emissions.

PM Emissions (TPY) = Drift gpm x 8.33 lbs/gal x TDS x 60 min/hr x hrs/yr of operation x 1 ton/2000 lbs

= 72.0 gpm x 8.33 lbs/gal x (62 lbs/1000000.lbs) x 60 min/hr x 2149 x 1 tonr2000 lbs The calculations for the 2005 emission data for cooling tower hazardous air contaminants (HAC) consider the miscibility of the product constituent and the water circulated through the cooling towers versus percentage of water loss through evaporation when the towers are running. The circulating water flow through the cooling towers is approximately 360,000 gallons per minute (gpm), and based on the FinalEnvironmental Statement Related to the Operation of Vermont Yankee Nuclear Power Corporation 1

published by the Nuclear Regulatory Commission, 5,000 gpm is lost through cooling tower evaporation. The HAC emissions from the cooling towers are insignificant and do not exceed any action levels outlined in Appendix C of the Vermont Air Pollution Control Regulations.

Cooling Towers Pollutant Tons lbs/8 hours Action level (bs/8hrs)

Particulate Matter 2.4 Dodecylguanidine Hydrochloride 0.001 0.002 0.025 Ethyl Alcohol 0.0004 0.001 2,330 Glutaraldehyde 0.008 0.015 340 Isopropyl Alcohol 0.0005 0.001 63 Total 2.41 This submittal does not include additional hazardous air contaminant (HAC) emissions inventory, as those would be associated with routine maintenance activities, such as painting and cleaning, and are therefore not subject to any State reporting requirements.

Please do not hesitate to call if you have questions or concerns with the enclosed information.

• Sincerely, Entergy Nuclear Vermont Yankee, LLC Lynn DeWald Samuel A. Wender IV Environmental Specialist Chemistry Superintendent 802-258-5526 802-258-5650 2

Supporting Calculations A. SPECTRUS NX-1104 Isopropy1 Alcohol I(400 gals/yr) x (8.24 lbs/gal) x (2.4%) x (1 ton/2,000 Ibs) x (5,000 gpm/360,000 gpm) =0.0005 tons/yr Ethyl Alcohol (400 gals/yr) x (8.24 lbs/gal) x (1.8%) x (1 ton/2,000 lbs) x (5,000 gpm/360,000 gpm) = 0.0004 tons/yr Dodecylauanidine Hydrochloride (400 gals/yr) x (8.24 lbs/gal) x (5%) x (1 ton/2,000 Ibs) x (5,000 gpmn/360,000 gpm) = 0.001 tons/yr B. NALCO H-550 Glutaraldehvde (50% Solution)

(250 gals/yr) x (9.4 lbs/gal) x (50%) x (1 ton/2,000 lbs) x (5,000 gpm/360,000 gpm) = 0.008 tons/yr 3

CERTIFICATION OF DATA ACCURACY For Purposes of Emission Calculations This form Inust be signed by an individual responsible for ihe completion and certification of the data contained in the forms attached which are intended to meet both the requirements of State Statute {10 V.S.A. 555 (c) and 3 v.S.A. 2822 (j)(1)(B)} and the requirements for "Emission Statements" contained in the Federal Clean Air Act as amended in 1990. Certification indicates that the signatory takes legal responsibility for the accuracy of the information on the form.

The datapresentedherein represents the best availableinformation and is true, accurate,and complete to the'best of my knowledge.

Print Full Name Print Full Title Dtof2Signa1tu(o SiTlhtureN Date of Signature Telephone Number Received JAN 4 2006

• .N?

.~,'. .4 r

Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The information displayed on this form is that which Is currently on file for your.

facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005 . Please revied the information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there Is a value, but it Is incorrect for 2005, cross out the value and in its place write the correct value.

If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form [ b4.1rb n~ A Id .

Facility ID WM2335 Source

Description:

house heating boilers (2)

Stack Number: 1 1

Source Number:

1 Segment Number:

Source Classification Code: 1-03-005-01 Operational Data:

Hours Per Day: Winter Throughput (%)

Days Per Week: Spring Throughput (%): 30J Weeks Per Year: Summer Throughput (%): 0 0-.

Hours Per Year: Autumn Throughput (%) 31 (Over)

Combustion Source (continued)

FuelType: FUEL OIL (#2) 2005 Fuel Consumption (supply units) : 14 o,'q',

Av. Sulfr Content of Fuel(%): - Ash Content of Fuel (%):jj. J (Pleasesupply a current estimate of mid-rangesulfur content)

Maximum Heat Input (million BTU/hr):

Burner Rating: Boiler Rating: /4,5. LLZ

• Maximum Actual Firing Rate (million BTIJ/hr): IiIi Percent Space Heat: I0Jj .

Percent Process Heat: 0II Stack Parameters:

Stack Number: l Stack/Duct Discharge Height (feet) : 87.9 Stack/Duct Inner Diameter at Exit (inches) 27.6 Exit Gas Temperature (deg. F) : 151 J Flow Rate at Exit (actual FT3/min) :119,915 I I If an air pollution control, device for the source exists inspect the following information and correct if necessary.:

TSP Control Device: none Theoretical Efficiency: F7"0]

S02 Control Device: none ITheoretical Efficiency: j__...

NOx Control Device:I none ] Theoretical Efficiency: _

VOC Control Devicej none . Theoretical Efficiency: 0 CO Control Device: . none Theoretical Efficiency:.

LZ~

If an estimated emission rate exists, please supply the information below .

Estimated Emission Rate*

Basis of Estimate : [

If test data 4 years old or less is available.

zJ

Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar' year 2004 or the most recent year available. The Information must be updated to calendar year 2005. Please review the information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there is a value, but it is incorrect for 2005, cross out'the value and in Its place write the correct value.

If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name.: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form UL-Lr\ V1L i'(2)de(I) I Cd I.

Facility.ID- WM2335 Source

Description:

ywae oil furnace (2)

Stack Number: 2 Source Number: 2 Seement Number: 1 Source Classlflcation Code: 1-02-004-01 Operational Data:

Hours Per Day: 0 Winter Throughput (%) 50 Days Per Week: 0j Spring Throughput (%): L0il "

Weeks Per Year: 0 Summer Throughput (%): 0 Hours Per Year: 1-7L-0-0-7 Autumn Throughput (%) :1 50" (Over)

Combustion Source (continued)

Fuel Type:- FUEL OIL (#6) 2005 Fuel Consumption: (supply units): [ S * ( * . *ei4 .c.

Av. Sulfpr Content of Fuel (%): '/,5 Ash Content of Fuel (%):

(Pleasesupply a curreuntestimateof mid-rangesulfur content)

Maximum Heat Input (million BTU/hr):

Burner Rating: Boiler Rating:

Maximum Actual Firing Rate (million BTU/hr):

Percent Space Heat: 1O0 Percent Process Heat: 0 Stack Parameters:

Stack Number: 2 Stack/Duct Discharge Height (feet): 21.0 6 Stack/Duct Ifiner Diameter at Exit (inches) :7.9 Exit Gas Temperature (deg. F): . 250*

Flow.Rate at Exit (actual FT3/min): 1,992 If an air pollution control device for the source exists inspect the following information and correct if necessary:

TSP Control Device: none Theoretical Effciency:

S02 Control Device: I.none

• Theoretical Efficiency: f 0]

NOx Control Device: I none Theoretical Efficiency:

VOC Control Devicef none .* Theoretical Efficiencyi*EZ I CO Control Device: Fnone - Theoretical Efficiency:.j ]

If an estimated emission rate exists, please supply the information below:

Estimated Emission Raie*. :1 Basis of Estimate:

• If test data 4 years old or less is available.

Vermont Agency of Natural Resources ProcessSource 2005 Air Pollutant Emissions Inventory For CriteriaPollutants The information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review the information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there Is a value, but it Is incorrect for 2005, cross out the value and in its place write the correct value.

If you have *questions,or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form: 1 I Facility ID : WM2335 Source

Description:

Particulate Emissions from Cooling Tower Stack Number: 5 Source Number: 5 Segment Number: 1 Source Classification Code: 3-85-001-01 Operational Data:

LHoursPerDay i Winter Throughput (%): j 0 DaysPerWeek: Spring Throughput (%): I zfo S WeeksPerYear: Ii Summer Throughput (%): CO." to HoursPerYear: FT, I'~F? Autumn Throughput (%): [I 1o o.4 ;oi5' (Over)

Process Source (continued)

Raw Materials Input*:-

• Aol

-ype q,!uanuty Product Materials Output*.:

Type Quantity I I I:

• Information in this section only necessary if accurate figures for stack flow rate and hours of operation cannot be supplied.

Stack Parameters:

Stack Number: 5 Stack/Duct Discharge Height (Feet) :

Stack/Duct Inner Diameter at Exit (Inches): I I0.0 Exit Gas Temperature (Deg Y) : I i70i I

Flow Rate at Exit (Actual FT3/Min) : I0 If there is an airpollution control device on this source inspect the following information and correct if necessary:

PM Control Device: Fnone Theoretical Efficiency (%): [j 01 If available, supply theoretical efficiencies for:

PMIO Efficiency (%).:

PM.Efiiec(%/):[Z I (NOTE: This Information will not affect the Air Registration Feý Estimate).

If an estimated emission rate exists for PM, supply the information below .

Estimated Emission Rate* [

Basis of Estimate:

1. .If test data 4 years old or less Is available.

Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The information displayed on this form Is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or.the most recent year available. The information must be updated to calendar year 2005. Please revieiv the information contained In the boxes. If there is no value in a box, write in the correct 2005 value. If there is a value, but it is incorrect for 2005, cross out the value and in its place write the correct value.

If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form ýj )_f% bewcz H_

Facility ID WM2335 Source

Description:

Emergency Diesels (2) - 1675 hp Stack Number: 3 Source Number: 3 Seement Number: 1 Source Classification Code: 2-02-004-01 Operational Data:

Hours Per Day: Z 0I J Winter Throughput (%) L1325.

Days Per Week: 0 Spring Throughput (%):

Weeks Per Year: EI 0iI Summer Throughput (%): .251J Hours Per Year: '59::; Autumn Throughput (%): 2.

• L- 7", VCe (Over) 15>

Combustion Source (continued)

Fuel Type: FUEL OIL (#2) 2005 Fuel Consumption: (supply units): , 0/5 Av. Sulfur Content of Fuel (%): [OYZ- Ash Content of Fuel (%): 0.005 (Pleasesupply a currentestimate of mid-rangesulfur content)

Maximum Heat Input (million BTU/hr):

BumerRating: Boller Rating: Jj2"4IJ Maximum Actual Firing Rate (million BTU/hr): *I O Percent Space Heat: W Percent Process Heat:

Stack Parameters:

Stack Number: 3

.Stack/Duct Discharge Height (feet): [29.8 Stack/Duct Inner Diameter at Exit (inches): 27.6*

Exit Gas Temperature (deg. F): "180.

Flow Rate at Exit (actual FT3/min) :63,983 If an air pollution control device for the source exists inspect the following information and correct if necessary:

TSP Control Device: none Theoretical Efficiency: [ -I S02 Control Device: none 1Theoretical Efficiency:

NOx Conirol Device: none -Theoretical Efficiency: .

VOC Control Devicei none i Theoretical Efficiency: i 0i

• CO Control Device: none Theoretical Efficiency: L'In If an estimated emission rate exists, please supply-the information below:

Estimated Emisslon Rate*

Basis of Estimate:

• If test data 4 years old or less is available.

Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available.'The Information must be updated to calendar year 2005. Please revied the information contained in the boxes. If there is no value In a box, write in the correct 2005 value. If there is a value, but It is incorrect for 2005, cross out the value and.

in its place write the correct value.

If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name : ENTERGY NUCLEAR VERMONT YANKEE

. Person Completing Inventory Form I+~YeAAdJ. IzIIzzii Facility ID WM2335 Source

Description:

235 hp John Deere Diesel Stack Number:' 4 Source Number: 4.

I1.

Seament Number:

Source Classification Code: 2-01-001-02 Operational Data:

251 Hours Per Day: 0 Winter Throughput (%)

25 Days Per Week: [Z 0 *Spring Throughput (%):

Weeks Per Year: [Z .0 Summer Throughput (%): 5 Hours Per Year: Autumn Throughput (%) :1 25

. (Over)

Combustion Source (continued)

Fuel Type: FUEL OIL (#2) 2005 Fuel Consumption : (supply units): Li" ILl s Av. Sulfur Content of Fuel (%): j,-- Ash Content of Fuel(%): 0.005 (Pleasesapply a currentestimate of mid-rangesulfur content)

Maximum Heat Input (million BTU/hr):

Burner Rating: ojIjBoiler Rating: I i Maximum Actual Firing Rate (million BTU/hr): jj 0"[

Percent Space Heat:

Percent Process Heat:

Stack Parameters:

Stack Number: 4 Stack/Duct Discharge Height (feet) " 12.5I II Stack/Duct Inner Diameter atExit (inches).:3.9 Exit Gas Temperature (deg. F): 180 Flow Rate at Exit (actuil FT3/min) :4,301 If an air pollution control device for the source exists inspect the following information and correct if necessary:

TSP Control Device: none Theoretical Efficiency: F WI S02 Control Device: none*" Theoretical Efficiency: I01 NOx Control Device:1 none Theoretical Efficiency:

VOC Control Devicei none -Theoretical Efficiency:

CO Control Device:- none Theoretical Efficiency:

If an estimated emission rate exists, please supply the information below: I o Estimated Emission Rate*:

Basis oof stlmate: .

• If test data"4 years old or less is available.