ML20247A346
| ML20247A346 | |
| Person / Time | |
|---|---|
| Site: | Crystal River  |
| Issue date: | 12/31/1997 |
| From: | Ezzell P FLORIDA POWER CORP. |
| To: | |
| Shared Package | |
| ML20247A343 | List: |
| References | |
| NUDOCS 9805060034 | |
| Download: ML20247A346 (16) | |
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FLORIDA POWER CORPORATION i
CRYSTAL RIVER UNIT 3 l
DOCKET NUMBER 50-302/ LICENSE NUMBER DPR-72 l
ATTACHMENT A
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i RADIOACTIVE EFFLUENT RELEASE REPORT - 1997 I
9805060034 980430 PDR ADOCK 05000302 R
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RADI0 ACTIVE EFFLUENT RELEASE REPORT 1997 FLORIDA POWER CORPORATION CRYSTAL RIVER - UNIT 3 Facility Operating License No. DPR-72 Docket No. 50-302 l-l l
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Prepared By:
hM_ C d ea d T cmrad Specialist II d,
Approved By:
a Manager, Nuclear Chemistry Date:
4/A7/4R 1
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l CONTENTS l
Introduction 1
Tabular Data Sunenaries l
Gaseous Effluents - Quarters 1 & 2 2
l Gaseous Effluents - Quarters 3 & 4 4
Liquid Effluents - Quarters 1 & 2 6
Liquid Effluents - Quarters 3 & 4 9
Radweste Shipments 12 Unplained Releases 13 Radioactive Waste Treatment Systems 13 Environmental Radiological Monitoring Program 13 13 Effluent Monitor Instrument Operability.
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i INTRODUCTION j
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This report is submitted as required by ODCH section 6.5.
The following information is j
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A summary of the quantities of radioactive liquid and gaseous effluents and solid l
l waste released from the plant.
l A list and description of unplanned releases to unrestricted areas.
A description of any changes to the:
l Process Control Program (PCP), and Offsite Dose Calculation Manual (ODCM).
i Significant changes to any radioactive waste treatment system.
A list of new dose calculation location changes identified by the annus1 land-use census.
Information relating to effluent monitors or required supporting instrumentation being inoperable for 30 or more days.
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TABLE 1 EFFLUENT AND M STE DISPOSAL REPORT - 1997 GASEOUS EFFLUENTS - StSetATION OF ALL RELEASES Unit Quarter Quarter Est. Total 1
2 Error %
-A.
Fission and Activation Gases-1.
Total Release -
Ci 5.65E-01 3.19E-02 30 1
2.
Average Release Rate For Period uti/sec 7.26E-02 4.06E-03 3.
Percent of Technical Specification Limit 5.82E-04 7.52E-05 B.
Iodines 1.
Total Iodine - 131 Ci 0.00E+00 0.00E+00
-30 2.
Average Release Rate for Period
'pCi/sec 0.00E+00 0.00E+00 3.
Percent sf Technical Specification Limit 0.00E+00 0.00E+00
.C.
Particulate
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Particulate with Half-Lives > 8 Days Ci 0.00E+00 1.35E-07 30 2.
Average Release Rate For Period uti/sec 0.00E+00 1.71E-08 3.
Percent of Technical Specification Limit 0.00E+00 9.62E-03 4.
Gross Alpha Radioactivity Ci 0.00E+00 0.00E+00
. D.
Tritium 1.
Total Release Ci 2.60E+00 3.01E+00 30 2.
Average Release Rate for Period pC1/sec 3.35E-01 3.82E-01 3.
Percent of Technical Specification Limit 8.33E-03 9.62E-03
- The sum of the particulate reported on this page may be less than the sum from Table 2, as Table 2 includes all particulate, while this table includes only those with half-s
-lives greater than 8 days.
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l TABLE 2 EFFLUENT AND WASTE O!SPOSAL REPORT - 1997
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GASEOUS EFFLUENTS - GROUND LEVEL RELEASES 1
I CONTINUOUS MODE BATCH MODE I
l Nuclides Released l Unit Quarter 1 l
Quarter 2 Quarter 1 l
Quarter 2
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1.
Fission Gases
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l Argon-41 Ci Krypton-85 C1 Krypton-85m Ci 8.01E-02 2.00E-02 Krypton-87 Ct Krypton-88 C1 l
Xenon-131m C1 3.53E-06 1
Xenon-133 C1 4.37E-01 Xenon-133m Ci Xenon-135 C1 4.77E-02 1.19E-02 Xenon-135m Cl Xenon-138 Ci 1
Total for Period Ci 5.64E-01 3.19E-02 0.00E+00 0.00E+00 1
2.
Iodines i
lodine-131 C1 i
Iodine-132 C1 Iodine-133 C1 lodine-135 C1 Ct I
Total for Period 0.00E+00 0.00E+00 0.00E+00 0.00E+00 i
3.
Particulate Zinc-72 C1 4.56E-08 Coba lt-58 Cl 1.35E-07 Cobalt-60 Ct Strontium-89 C1 Strontium-90 Cl Yttrium-93 C1 Tin-113 Ci j
Cachium-113m Ci Telurium-132 Ci 1.33E-08 1.98E-08 Cestum-134 C1 Cesium-137 C1 Cestum-138 Ci Barium-139 C1 Lanthanum-142 C1 Cerium-143 C1 1.68E-07 Cerium-144 C1 Rhentum-188 Ci Total for Period C1 1.81E-07 2.00E-07 0.00E+00 0.00E+00 3
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TABLE 3 EFFLUENT AND WASTE DISPOSAL REPORT - 1997 GASEOUS EFFLUENTS - SlDMATION OF ALL RELEASES Unit Quarter Quarter Est. Total 3
4 Error %
A.
Fission and Activation Gases 1.
Total Release C1 4.88E-01 0.00E+00 30 2.
Average Release Rate For Period uC1/sec 6.14E-02 0.00E+00 3.
Percent of Technical Specification Limit 3.16E-04 0.00E+00 B.
lodines 1.
Total Iodine - 131 Ci 0.00E+00 0.00E+00 30 2.
Average Release Rate for Period uCi/sec 0.00E+00 0.00E+00 3.
Percent of Technical Specification Limit 0.00E+00 0.00E+00 C.
Particulate
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Particulate with Half-Lives > 8 Days Cl 0.00E+00 9.59E-05 30 2.
Average Release Rate For Period uti/sec 0.00E+00 1.21E-05 3.
Percent of Technical Specification Limit 0.00E+00 2.08E-03 4.
Gross Alpha Radioactivity Ci 0.00E+00 0.00E+00 D.
Tritium 1.
Total Release C1 4.47E+00 6.50E-01 30 2.
Average Release Rate for Period pct /sec 5.62E-01 8.17E-02 3.
Percent of Technical Specification Limit 1.43E-02 2.08E-03
- The sum of the particulate reported on this page may be less than the sum from Table 4, as Table 4 includes all particulate, while this table includes only those with half-lives greater than 8 days.
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TABLE 4 EFFLUENT AND WASTE DISPOSAL REPORT - 1997 GASEDUS IFFLt D TS - GROUND LEVEL RELEASES CONTINUOUS H0DE BATCH HODE l Nuclides Released l Unit Quarter 3 l
Quarter 4 Quarter 3 I
Quarter 4 1.
Fission Gases Argon-41 C1 Krypton-85 C1 1.29E-01 Krypton-85m C1 Krypton-87 Ci Krypton-88 C1 Xenon-131m Ci 3.59E-01 9.62E-07 Xenon-133 C1 Xenon-133m Ci Xenon-135 C1 Xenon-13 5m C1 Xenon-138 Ci Total for Period Ci 3.59E-01 0.00E+00 1.29E-01 0.00E+00 2.
Iodines lodine-131 C1 lodine-132 Ci Iodine-133 C1 Iodine-135 Ci Total for Period Ci 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.
Particulate Zinc-72 C1 Cobalt-58 Ci Cobalt-60 Ci Strontium-89 Ci Strontium-90 Ci Yttrium-93 Ci Tin-113 C1 Cadnium-113m C1 9.59E-05 Indium-113m C1 Cesium-134 C1 Cesium-137 C1 Cesium-138 C's Barium-139 C1 9.12E-07 Lanthanum-142 C1 Cerium-143 C1 Cerium-144 C1 Rhenium-188 C1 Total for Period Ci 9.12E-07 9.59E-05 0.00E+00 0.00E+00 5
14BLE 5 EFFLUENT AND WASTE DISPOSAL REPORT - 1997 l
LIQUID EFFLUENTS - SLSetATION OF ALL RELEASES Unit Quarter Quarter Est. Total 1
2 Error %
A.
Fission and Activation Products 1.
Total Release (Not including tritium, Cl 8.66E-02 6.48E-02 25 gases, alpha) 2.
Average diluted concentration during gCt/mi 3.28E-10 2.11E-10 period l
3.
Percent of applicable Limit 1.20E-01 7.85E-02 l
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B.
Tritium 1.
Total Release Cl 2.27E+01 3.11E+01 30 l
2.
Average diluted concentration during pC1/ml 8.60E-08 1.01E-07 l
period 3.
Percent of applicable Limit 8.60E-04 1.01E-03 C Dissolved and entrained gases 1.
Total release Ci 0.00C+00 1.18E-05 25 2.
Average diluted concentration during pct /mi 0.00E+00 3.48E-14 period 3.
Percent of applicable Limit 0.00E+00 1.01E-03 D.
Gross alpha radioactivity l
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Total Release Ci 0.00E+00 0.00E+00 30 E.
Volume of Waste released (prior to dilution) 1.
Batch and Continuous Modes Liters 4.07E+0S 9.05E+05 10 F.
Volume of dilution water used during period 1.
Batch and continuous Modes Liters 2.64E+11 3.07E+11 10 l
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TABLE 6 EFFLUENT AND WASTE DISPOSAL REPORT - 1997 LIQUID EFFLUENTS CONTINU0ll5 MODE BATCH H00E Nuclides Released Unit Quarter 1 Quarter 2 Quarter 1 Quarter 2 Sodium-24 C1 Chromium-51 Ci Manganese-54 C1 1.38E-03 1.43E-03 Manganese-56 C1 2.89E-06 Iron-55 C1 2.95E-03 7.90E-03 Iron-59 Ci Cobalt-57 C1 e.80E-04 Coba lt-58 C1 2.33E-03 4.46E-03 Cobalt-60 C1 l.34E-02 1.80E-02 Copper-64 C1 1.90E-04 Zine-72 C1 Strontium-85 Ci Strontium-89 Ci Strontium-90 Ci Strontium-92 C1 Yttrium-92 C1 Yttrium-93 C1
__Bremtne-82 Ci Niobium-95 Ci 6.13E-05 N lobiwn-97 C1 Zirconium-95 C1 1.63E-04 Zirconium-97 Ci 2.81E-03 9.8?E-04 Molybdinum-99 Ci Technettum-99M C1 Technetium-101 C1 Ruthenium-103 Ci Ruthenium-106 Ci 1.89E-03 4.24E-03 S i lver-110m Ci 5.70E-02 1.94E-0?
Tin-113 Ci 9.14E-05 9.90E-06 Indium-113m C1 1.31E-04 1.39E-05 Cadn t um-113m Ci Antimony-122 Ci Antimony-124 C1 1.98E-04 4.83E-05 Antimony-125 C1 3.16E-03 7.30E-03 Tellurium-129 C1 1.97E-06 Tellurium-132 Ct 1.67E-07 Iodine-131 C1 lodine-132 Ci lodine-133 Ci lodine-135 C1 Cesium-134 Ci 4.44E-05 Cesium-137 C1 4.86E-CS 3.83E-04 Cesium-138 C1 2.20E-05 8arium-139 C1 8arium-140 Ci Lanthanum-140 C1 Cerium-143 C1 Cerium-144 C1 5.17E-04 9.89E-05 Rhenium-188 C1 3.09E-07 Neptunium-239 Ci Total for Period C1 0.00E+0C 0.00E+00 8.61E-02 6.49E-02 7
TABLE 6 (CONTINUED)
EFFLENT AND WASTE DISPOSAL REPORT - 1997 LIQUID EFFL E NTS CONTINUOUS MODE BATCH MODE Otssolved &
Entrained Gasses Unit Quarter 1 Quarter 2 Quarter 1 Quarter 2 Argon-41 Ci Krypton-85 C1 Krypton-85m Cl Krypton-87 C1 1.18E-05 Krypton-88 C1 Xenon-131m Ci Xenon-13a C1 Xenon-133m C1 Xenon-135 C1 Xenon-135m C1 Total for Period Cl 0.00E+00 0.00E+00 0.00E+00 1.18E-05 l Tritium l Ci l 0.00E+00 l
0.00E+00 l
2.13+01 l
3.12E+01 l
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TABLE 7 I
EFFLUENT AND WASTE DISPOSAL REPORT - 1997 l
LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES Unit Quarter Quarter Est. Total 3
4 Error %
A.
Fission and Activation Products 1.
Total Release (Not including tritium, C1 1.08-01 5.81E-02 25 gases, alpha) 2.
Average diluted concentration during yC1/ml 2.62E-10 1.27E-10 period 3.
Percent of applicable Limit 1.73E-01 2.44E-02 B.
Tritium 1.
Total Release Cl 1.38E+01 9.51E+00 30 2.
Average diluted concentration during pCi/ml 3.34E-08 2.09E-08 period 3.
Percent of applicable Limit 3.34E-04 2.09E-04 C.
Dissolved and entrained gases 1.
Total release C1 4.04E-05 5.13E-07 25 2.
Average diluted concentration during pC1/ml 9.78E-14 1.13E-15 period 3.
Percent of applicable Limit 3.34E-04 2.09E 34 D.
Gross alpha radioactivity 1.
Total Release Cl 0.00E+00 0.00E+00 30 E.
Volume of Waste released (prior to dilution) 1.
Batch and Continuous Modes Liters 8.98E+05 4.13E+05 10 F.
Volume of dilution water used during period 1.
Batch and continuous Modes Liters 4.13E+11 4.56E+11 10 9
TABLE 8 EFFLUENT AND )dASTE DISPOSAL REPORT - 1997 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE
_Nuclides Released Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Sodium-24 C1 Chromium-51 Ci 1.35E-04 8.39E-04 Manganese-54 C1 3.01E-03 2.96E-04 j
Manganese-56 Ci l
Iron-55 C1 6.83E-03 2.06E-03 j
Iron-59 C1 l
Cobalt-57 C1 1.66E-04 8.60E-08 l
Cobalt-58 C1 2.26E-03 3.14E-04 Cobalt-60 Cl 3.47E-02 8.71E-03
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l Zinc-65 Ci Zine-72 Ci 6.36E-08 Strontium-85 C1 1.45E-07 Strontium-89 Ci Strontium-90 C1 1.91E-05 Strontium-92 C1 Yttrium-91 Ci 8.21E-04 Yttrium-93 C1 Bromine-82 Ci Niobium-95 C1 1.00E-05 1.14E-07 l
Niobium-95m Ci Niobium-97 Ci Zirconium-95 Ct 4.10E-04 l
Zirconium-97 C1 1.82E-03 9.37E-04 Molybdinum-99 C1 l
Technetium-99m Ct Technetium-101 Ci Ruthenium-103 C1 Ruthenium-106 C1 1.02E-02 2.23E-03 Silver-110m C1 3.72E-02 1.84E-02 Tin-113 C1 1.93E-04 l
Indium-113m C1 2.65E-04 Cadmium-113m Ci Antimony-122 Ci Antimony-124 C1
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Antimony-125 C1 8.47E-03 2.42E-02 Tellurium-129 C1 Tellurium-132 Ci 9.99E-06 Iodine-131 C1 lodine-132 Ci Iodine-133 Ci lodine-135 Cl Cesium-134 Ci 6.72E-06 2.10E-07 Cesium-137 Ci 1.34E-04 1.71E-05 Barium-139 Ci Barium-140 Ci tanthanum-140 C1 Cerium-143 C1 Cerium-144 C1 1.10E-03 Rhenium-188 C1 i
Total for Period Ci 0.00E+00 0.00E+00 1.08E-01 5.80E-02 10 l
i TABLE 8 (CONTINUED)
EFFLUENT AND WASTE DISPOSAL REPORT - 1997 LIQUID EFFLUENTS CONTINUOUS NODE BATCH MODE Dissolved &
Entrained Gasses Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Argon-41 Ci Krypton-85 C1 3.39E-05 Krypton-85m Ci Krypton-87 C1 I
Krypton-88 C1 Xenon-131m C1 2.23E-06 Xenon-133 C1 4.28E-0C Xenon-133m Ci Xenon-135 Ci Xenon-135m C1 5.13E-07 Total for Period Ci 0.00E+00 0.00E+00 4.04E-05 5.13E-07 l Tritium l C1 1 0.00E+00 l
0.00E+00 l
1.38E+01 l
9.57E+00 l
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TABLE 9 EFFLUENT AND idASTE DISPOSAL REPORT - 1997 SOLID idASTE AND IRRADIATED FIEL SHIPIENTS A.
SOLID WASTE SHIPPE0 0FFSITE FOR FR0 CESSING AND/0R BURIAL (Non-irradiated fuel) 1.
Type of Waste Unit 12 month period Est. Total Error %
a.
Spent resins. filter sludges, evaporator bottoms, etc.
m3 1.42E+02 25 C1 3.08E+01 b.
Dry compressible waste, contaminated equtpment, etc.
m3 5.98E+02 25 C1 1.25E+00 c.
Irradiated components, control rods, etc.
m3 0.00E+00 Ci 0.00E+00 d.
Other(describe): 011 m3 1.30E+00 25 Ci 3.20E-01 2.
Estimate of ma.jor nuclide composition (by type of waste in %)*
'a.
Co-60 20.8 Cs-137 S.S Fe-55 30.0 Ag 110m 16.2 b.
Ni-63 19.9 Cs-137 2.9 Co-60 19.2 i
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Solid Waste disposition i
' Number of Shipments Mode of Transportation Destination
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2 Exclusive Use Casks Barnwell, SC (CNSI) 14 ExclusiveUseFlatbeds(13)
Dak Ridge, TN (SEG) l ExclusiveUseCasks(1) 6 Exclusive Use Flatbeds Clive, UT (En<trocare)
Type a wastes were shipped in liners. Type b and d wastes were shipped in strong tight containers.
l IRRADIATED FUEL SH1PMENTS (Disposition)
Number of Shipments
. Mode of Transportation Destination 0
N/A N/A
. Curie values and principle radionuclides are estimates based on a combination of direct and indirect methods.
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9 a
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Unplanned Releases There were no unplanned gaseous or liquid releases.
Radioactive Waste Treatnent Systems There were no significant changes to the radioactive waste treatment systems.
Radiological Environmental Monitoring Program The June, 1997 land-use census did not identify any new dose calculation locations.
Effluent Monitor Instrtament Operability Required effluent monitor instrumentation was not out of service for more than 30 days during 1997.
Sp3cial Reports 97-03 and 97-08 were submitted to the Nuclear Regulatory Commission because the Post Accident Sampling System Mid and High Range Noble Gas monitors for the Reactor Bui1 ding and Auxiliary Building were inoperable for more than seven days.
DDCM & PCP Changcs The PCP was not revised during 1997.
The ODCM was revised three times during 1997.
ODCM Revision 21. Approved for issuance on 4/3/97. Revised to 1) clarify the term " degassing" as it applies to Waste Gas Decay Tank sampling, 2) provide for separate fixed setpoints for laundry tank and Evaporator Condensate Storage Tank (ECST) releases, 3) delete an unnecessary definition for " independent verification", 4) broaden the scope of the power change sampling requirements, and 5) clarify the distinction between requirements and considerations for sampling the Reactor Building when the hatches (personnel and equipment) are open.
ODCM Revision 22. Approved for issuance on 7/28/97. Revised to clarify the requirements for making changes to the ODCM.
00CM Revision 23. Approved for issuance on 12/16/97. Revised to clarify the Surveillance Requirement for the Waste Gas Decay Tank Curie determination.
A complete copy of the ODCM is being submitted with this report. Affected pages have been marked.
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