ML20245F019

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Radiological Environ Operating Rept for 1988
ML20245F019
Person / Time
Site: Fort Calhoun Omaha Public Power District icon.png
Issue date: 12/31/1988
From:
OMAHA PUBLIC POWER DISTRICT
To:
NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
LIC-89-387, NUDOCS 8905020236
Download: ML20245F019 (40)


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.f ' ENVIRONMENTAL MONITORING.- -

., TECHNICALSPECIFICATION(5.9.4b.). .

J . January'1, 1988 to December 31, 1988

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c. ;v 5.9.4.b' . Radiological' Environmental Operatina Reoort -

-1(a): .The number, of. sample locations, sample collection frequency and the number of samples collected this period?

for each class of sample is delineated in Table 1.

. A complete summary of the program findings is' presented i_n Table 2. For each type- of analysis of each sampled medium this-table considers separately all- indicator locations, all control locations and the-location with. the. highest

. annual'mean result. For each-of these classes, the table specifies the following:

(1) .The total number of analyses.:

(2) The: fraction of these' yielding detectable .results l(i.e.,. results above the highest lower limit of '

detection.for the period).

'(3) .The average, lowest,.and highest results.

i In addition, the distance and direction relative to the O Reactor Containment- Building are specified for the location with the highest annual mean, t . .

Table 3 'is.a listing of missed-samples.

(b) Results obtained show background levels of radioactivity

-in the environmental . samples. collected in 1988. The-residual'effect of previous nuclear tests was detected in one silt. sample (cesium-137). No station effect on the environment was indicate.

.(c) -See Appendix A for Interlaboratory Comparison, Appendix B is a description of the data re;orting conventions for Appendix A.

(d) See Table 4 for land use survey.

(e) The limits of Technical Specification 2.1.3 were not exceeded by the primary coolant during the reporting period.

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1 ..T Table 1. Sample Collection Program.

Number of Sampl es Collection Sampl e Collected Sample Class Frequency Locations This Period Background Radiation (TLD) Quarterly Eleven (11) 42 Air Particulate Weekly Five (5) 261 Airborne Iodine Weekly Five (5) 261

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TABLE'3'

. LISTING OF filSSED SAMPLES Expected Collection Sample Type Location Date Reason Well Water OWW-A ~1st Qtr.- No data available 0WW-B. 1st Qtr.- due to frozen pump.

-OWW-C 'Ist Qtr.

Airborne' OAH 05-09-88 Pump switch left in Particulate "off" position.-

g TLD OFD 2nd Qtr. TLD missing due to vandalism..

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TLD ~0FK 4th Qtr. TLD missing due to-vandalism.

- Well Water OWW-A 4th Qtr.. No data available 0WW-B 4th Qtr. due to frozen pump.

0WW-C 4th Qtr.

i lA.--__________. _ _ _ - - - - - - _ _ -

t i.- , i Appendix A Interlaboratory Comparison Program Results fl0TE: TIllL participates in intercomparison studies administered by U.S. EPA Envi ronmental flonitoring Systems Laboratory, Las Vegas, Nevada. The results are reported in Appendix A. Also reported are results of in-house spikes and blanks. Appendix A is updated twice a year and the complete Appendix is included in January and July monthly reports only.

Please refer to January and July Reports for information.

9 Janu ary, 1989 A-1

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-. a l 3 Appendix A "

l Interlaboratory Comparison Program Results )

Teledyne Isotopes flidwest Laboratory (formerly Hazleton Environmental Scienc s) j has participated in interlaboratory comparison (crosscheck) programs since the i formulation of its quality control program in December 1971. These programs are operated by agencies which supply environmental-type samples (e.g., milk or water) containing concentrations of radionuclides known to the issuing agency but not to participant laboratories. The purpose of such a program is to provide an independent check on the laboratory's analytical procedures and to alert it to  !

any possible problems. ,

Participant laboratories measure the concentrations of specified radionuclides and report them to the issuing agency. Several months later, the agency reports the known values to the participant laboratories and specifies control limits. l Results consistently higher or lower than the known values or outside the control limits indicate a need to check the instruments or procedures used.  ;

The results in Table A-1 were obtained through participation in the environmental sample crosscheck program for. milk, water, air filters, and food samples during i the period liay 1984 through flovember,1988. This program has been conducted by l the U.S. Environmental Protection Agency Intercomparison and Calibration Section, Quality Assurance Branch, Environmental fionitoring and Support Laboratory, Las  ;

Vegas, llevada.

The results in Table A-2 were obtained for thermoluminescent dosimeters (TLD's) during the period 1976,1977,1979,1980,1984, and 1985-1986 through partici-pation in the Second, Third, Fourth, Fif th, Seventh, and Eighth International Intercomparison of Environmental Dosimeters under the sponsorships listed in Table A-2. .

Table A-3 lists results of the analyses on in-house spiked samples.

Table A-4 lists results of the analyses on in-house " blank" samples.

Attachment B lists acceptance criteria for " spiked" samples.

Addendum to Appendix A provides explanation for out of limit results.

l ,

A-2 ,

.. 4-Table. 'A-1.. U.S. ' Environmental Protection Agency's crosscheck program, com-parison of EPA and Teledyne Isotopes Midwest Laboratory results for milk, water, air filters, and food samples,1984 through 1988.a Concentration in pCi/lb Lab' Sample .Date TIML Result EPA Resultd Code Type Collected Analysis i2ac Is, N=1 Control Limits STW-358. Water May 1984 :Gr. alpha 3.0f0.6 3i5.0 0.0-11.7 Gr. beta 6.7tl.2 6t5.0 0.0-14.7 STM-366 Milk June 1984- Sr-89 21i3.1 25i5.0 16.3-33.7 Sr-90 13f2.0 17tl.5 14.4-19.6 I-131 4615.3 4316.0 32.6-53.4

, Cs-137 '3814.0 35i5.0 26.3-43.7 K 1577f172 1496i75 1336-1626 STW-368 Water July 1984 Gr. alpha 5.111.1 615.0 0.0-14.7 Gr. beta 11.9i2.4 13i5.0 4.3-21.7 STW-369' Water August 1984 I-131 34.3i5.0 34.0i6.0 23.6-44.4 STW-370 Water August 1984 H-3 30031253 28171356 2200-3434 STF-371- Food July 1984 Sr-89 22.0t5.3 25.015.0 14.3-33.7 Sr-90 14.7i3.1 20.0 1.5 17.4-22.6 6 I-131 <172 39.0i6.0 28.6-49.4 Cs-137 24.0i5.3 25,015.0 14.3-33.7 K 25031132 2605i130 2379-2831 STAF-372 . Air August 1984 Gr. alpha 15.311.2 17i5.0 8.3-25.7 Filter Gr. beta 56.010.0 5115.0 42.3-59.7 Sr-90 14.3fl.2 1811.5 15.6-20.4 Cs-137 21.0i2.0 1515.0 6.3-23.7 STW-375 Water Sept 1984 Ra-226 5.110.4 4.910.7 3.6-6.2 Ra-228 2.2i0.1 2.310.4 1.7-2.9 STW-377 Water Sept 1984 Gr. alpha 3.3tl.2 5.015.0 0.0-13.7 Gr. beta 12.7i2.3 16.015.0 7.3-24.7 STW-379 Water Oct 1984 H-3 2860i312 2810t205 2454-3166 STW-380 Water Oct 1984 Cr-51 <36 4015.0 31.3-48.7 Co-60 20.3fl.2 2015.0 11.3-28.7 Zn-65 150i8.1 ' 147i5.0 138.3-155.7 Ru-106 <30 4715.0 36.3-55.7 Cs-134 31.317.0 3115.0 22.3-39.7 Cs-137 26.7tl.2 2415.0 15.3-32.7 A-3  !

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.. 't-stable A-1. (continued)

Concentration in pCi/lb Lab Sample- Date TIML Result EPA Resultd Code' Type Collected Analysis i2oc Is, N=1 Control Limits STM-382 Milk Oct 1984 Sr-89 15.714.2 22i5.0 13.3-30.7 Sr-90 12. 7il . 2 16fl.5 13.4-18.6 I-131 41.7i3.1 4216.0 31.6-42.4 Cs-137 31.316.1 32i5.0 23.3-40.7 K 1447166 1517i76 1386-1648 STW-384 Water G:t 1984- Gr. alpha 9.7tl.2. 1415.0 5.3-22.7 (Blind) Sample A Ra-226 3.310.2 3.010.5 2.2-3.8 Ra-228 3.411.6 2.110.3 1.6-2.6 tiranium nae 5.0 6.0 0.0-15.4 Sample'B Gr. beta 48.3i5.0 64i5.0 55.3-72.7 Sr-89 10.714.6 11f5.0- 2.3-19.7 Sr-90 7.3fl.2 12il.5 9.4-14.6 Co-60 16.3tl.2 1415.0 5.3-22.7'

'Cs-134 <2 215.0 0.0-10.7 Cs-137 16.711.2 1415.0 5.3-22.7 i

STAF-387- Air Nov 1984 .Gr. alpha 18.7il.2 15i5.0 6.3-23.7 Filter Gr. beta 59.0i5.3 52i5.0 43.3-60.7 Sr-90 18.311.2 21il.5 18.4-23.6 Cs-137 10.311.2 10i5.0 1.3-18.7 STW-388 . Water Dec 1984 I-131 28.012.0 36t6.0 25.6-36.4 STW-389 Water Dec 1984 H-3 35831110 3182t360 2558-3806 STW-391 Water Dec 1984 Ra-226 8.4tl.7 8.611.3 6.4-10.8 i Ra-228 3.li0.2 4.110.6 3.0-5.2 i

STW-392- Water -Jan 1985 Sr-89 <3.0 3.0t5.0 0.0-11.7 Sr-90 27.3i5.2 30.011.5 27.4-32.6 STW-393 Water Jan 1985 Gr. alpha 3.3tl.2 Si5.0 0.0-13.7 Gr. beta 17.313.0 15i5.0 6.3-23.7 l

STF-395 Food Jan 1985 Gr. alpha 4.712.3 6.015.0 0.0-14.7 l Gr. beta 11.3tl.2 15.015.0 6.3-23.7 Sr-89 25.316.4 34.0i5.0 25.3-42.8 Sr-90 27.018.8 '26. 0il . 5 23.4-28.6 .

l- I-131 38.0i2.0 35.016.0 24.6-45.4  ;

Cs-137 32.712.4 29.015.0 20.3-37.7 l K 1410i212 1382il20 1174-1590 A-4

.. 1

' Table A-1. (continued).

Concentration in pCi/lb Lab Sample:. Date TIML Result EPA Resultd Code Type- Collected Analysis 12ac is, N=1 - Control Limits STW-397 Water. Feb-1985- Cr-51 <29 48i5.0 39.3-56.7 Co-60 21.3t3.0 2015.0 11.3-28.7 Zn-65 53.7t5.0 5515.0 46.3-63.7 t Ru-106 <23. 2515.0 16.3-33.7 Cs-134 32.3tl.2 35t5.0 26.3-43.7 Cs-137 25.3t3.0 25t5.0 16.3-33.7 STW-398 Water Feb 1985. H-3 38691319 37961634 3162-4430 STM-400 Milk March 1985' I-131 7.3i2.4 9.010.9 7.4-10.6 STW-402 Water March 1985 Ra-226 4.6i0.6 5.0i0.8 3.7-6.3 Ra-228 <0.8 9.0il.4 6.7-11.3 Reanalysis Ra-228- 9.0i0.4 STW-404 ' Water March 1985- Gr. alpha .4.7t2.3 6i5.0 0.0-14.7 Gr. beta 11.3fl.2 1515.0 6.3-23.7 STAF-405 Air: March 1985 Gr. alpha 9.3 1.0 10.0i5.0 1.3-18.7 Filter Gr. beta 42.0il.1 36.0i5.0 27.3-44.7 Sr-90 13.3tl.0 15.0il.5 12.4-17.6 Cs-137 6.3fl.0 6.0f5.0 0.0-14.7 STW-407 Water April 1985 I-131 8.0i0.0 7.510.8 6.2-8.8 l STW-408 Water April 1985 H-3 3399il50 35591630 2929-4189 STW-409 Water April 1985 (Blind) Gr. alpha 29.7tl.8 32.0i5.0 23.3-40.7 Sample A Ra-226 4.410.2 4.110.6 3.1-5.1 Ra-228 nae 6.210.9 4.6-7.8 3 Uranium nae 7.016.0 0.0-17.4 {

l Sample B Gr. beta 74.3111.8 72.0i5.0 63.3-80.7 Sr-89 12.3 7.6 10.0i5.0 1.3-18.7 Sr-90 14.712.4 15.0il.5 12.4-17.6 L Co-60 14.7i2.4 15.0i5.0 6.3-23.7 Cs-134 12.0i2.0 15.0i5.0 6.3-23.7 Cs-137 14.012.0 ' 12.0i5.0 3.3-20.7 1

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.. r Table A-1. (continued)

. Concentration in pCi/lb Lab Sample .Date TIML Result EPA Resultd Code Type Collected Analysis i2ac Is, N=1 Control Limits i STW-413 Water May 1985 Sr-89 36.0t12.4 39.0i5.0 30.3-47.7 I Sr-90 14.3i4.2 15.0il.5 12.4-17.6 STW-414 Water May 1985 Gr. alpha 8.3i4.1 12.0i5.0 3.3-20.7 Gr. beta 8.7tl.2 11.0i5.0 2.3-19.7 STW-416 Water June 1985 Cr-51 44.7i6.0 44.0i5.0 45.3-52.7 Co-60 14.3tl.2 14.0i5.0 5.3-22.7 Zn-65 50.3i7.0 47.0i5.0 38.3-55.7 Ru-106 55.3i5.8 62.0i5.0 53.3-70.7 l 32.7tl.2 Cs-134 35.0i5.0 26.3 '3.7 Cs-137 22.7i2.4 20.0i5.0 11.3-28.7 STW-418 Water June 1985 H-3 2446i132 2416i351 1807-3025 STM-421 ' Mil k' June 1985 Sr-89 10.3i4.6 11.Di5.0 2.3-19.7 Sr-90 9.0i2.0 11.Dil.5 8.4-13.6 I-131 11.7tl.2 11.0i6.0 0.6-21.4 Cs-137 12.7tl.2 11.Di5.0 2.3-19.7 K 1512 62 1525f132 1393-1657 STW-423 Water July 1985 Gr. alpha 5.0i0.0 11.0i5.0 2.3-19.7 Gr. beta 5.0i2.0 8.0i5.0 0.0-16.7 STW-425 Water August 1985 I-131 25.7i3.0 33.016.0 22.6-43.4 STW-426 Water August 1985 H-3 4363i83 4480i447 3704-5256 STAF-427 Air August 1985 Gr. alpha 11.310.6 13.015.0 4.3-21.7 Fil ter Gr. beta 46.0il.0 44.Di5.0 35.3-52.7

.Sr-90 17.7i0.6 18.0il.5 15.4-20.6 Cs-137 10.3i0.6 8.0i5.0 0.0-16.7 STW-429 Water Sept 1985 Sr-83 15.7i0.6 20.0i5.0 11.3-28.7 Sr-90 7.0f0.0 7.0il.5 4.4-9.6 STW-430 Water Sept 1985 Ra-226 8.210.3 8.9il.3 6.6-11.1 Ra-228 4.li0.3 4.6i0.7 3.4-5.8  ;

l STW-431 Water Sept 1985 Gr. alpha 4.710.6 . 8.0i5.0 0.0-16.7 Gr. beta 4.7tl.2 8.0i5.0 0.0-16.7 A-6

& a -

Table A-1. (continued)

Concentration in pCi/lb Lab Sample Date TIML Result EPA Resultd Code Type Collected Analysis i20c 15, N=1 Control Limits STW-433 Water Oct 1985 Cr-51 <13 21.015.0 12.3-29.7 Co-60 19.310.6 20.015.0 11.3-28.7 Zn-65 19.710.6 19.0i5.0 10.3-27.7 Ru-106 <19 20.0f5.0' 11.3-28.7-Cs-134 17.0il.0 20.015.0 11.3-28.7 Cs-137 19.3fl.2 20.0f5.0 11.3-28.7 STW-435 Water Oct 1985 H-3 1957i50 1974i345 1376-2572 STW-436 Water Oct 1985 437 -(Blind) i Sample A Gr. alpha 53.0il.0 52.0i13 29.4-74.6 Ra-226 5.9i0.1 6.3fl.0 4.1-7.9 Ra-228 8.210.1 10.lil.5 7.5-12.7 Uranium NA0 8.0i10.4 0.0-18.4 Sample B Gr. beta 85.7i2.5 75.015.0 76.3-83.7 Sr-89 21.3fl.5 27.0i5.0 18.3-35.7 Sr-90 10.3t0.6 9.0il.5 6.4-11.6 Co-60 18.311.2 18.015.0 9.3-26.7 Cs-134 16.3tl.2 18.0i5.0 9.3-26.7 Cs-137 19.0il.0 18.0i5.0 9.3-26.7 STM-439 Milk Oct 1985 Sr-89 50.3i0.6 48.0i5.0 39.3-56.7 Sr-90 23.3i0.6 26.0il.5 23.4-28.6 l

I-131 45.7i3.2 42.016.0 31.6-52.4 Cs-137 60.7i0.6 56.015.0 47.3-64.7 K 1547129 1540i77 1406-1674 STW-441 Water Nov 1985 Gr. alpha 5.310.6 10.015.0 1.3-18.7 Gr. beta 11.7tl.2 13.0i5.0 4.3-21.7 STW-443 Water Dec 1985 I-131 46.712.1 45.0i6.0 34.6-55.4 STW-444 Water Dec 1985 Ra-226 6.5i0.1 7.lil.1 5.2-9.0 Ra-228 6.110.1 7.3fl.1 5.4-9.2 STW-445 Water Jan 1986 Sr-89 29.712.5 31.Di5.0 22.3-39.7 Sr-90 13.7 0.6 "

15.011.5 12.4-17.6 STW-446 Water Jan 1986 Gr. alpha 3.0i0.0 3.015.0 0.0-11.7 l Gr. beta 5.310.6 7.015.0 0.0-15.7 A-7 i

' I

(

(:

.: >. +;o ,

Table A-1. (hontinued)

Concentration in pCi/lb L Lab Sample Date TIML Result EPA Resultd Code Type Collec ted Analysis 120c Is, N=1 Control Limits STF-447 Food Jan 1986 :3r-89 24.3t2.5 25.0t5.0 16.3-33.7 Sr-90 17.3i0.6 10.0il.5 7.4-12.6 I-131 22.712.3 20.0i6.0 9.6-30.4 Cs-137 16.3i0.6 15.0i5.0 6.3-23.7 K 927146 950t144 701-1199 STW-448 Water Feb 1986 Cr-51 45.0i3.6 38.015.0 29.3-46.7 Co-60 19.7tl.5- 18.015.0 9.3-26.7 Zn-65 44.0i3.5 40.0i5.0 31.3-48.7 Ru '06 <9.0 0.0i5.0 0.0-8.7 Cs-134 28.312.3 30.0t5.0 21.3-38.7 Cs-137 23.7i0.6 22.015.0 13.3-30.7 STW-449 Water Feb 1986 H-3 5176i48 52271525 4317-6137' ,

J STW-450 Water Feb 1986 -U total 8.0i0.0 9.0i6.0 0.0-19.4 STM-451 Milk Feb 1986 I-131 7.0i0.0 9.0i6.0 0.0-19.4 STW-452 Water March 1986 Ra-226 3.810.1 4.li0.6 3.0-5.2 g Ra-228 11.0i0.5 12.4tl.8 9.2-15.5 STW-453 Water- March 1986 Gr. alpha 6.710.6 15.0t5.0 6.3-23.7 Gr. beta 7.310.6 8.015.0 0.0-16.7 STW-454 Water April-1986 I-131 7. 0i0. 0 9.0i6.0 0.0-19.4 STW-455 ' Water April 1986 456 (Blind)

Sample A Gr. alpha 15.0il.0 17.015.0 8.3-25.7 Ra-226 3.110.1 2.9i0.4 2.1-3.7 Ra-228 1.510.2 2.0i0.3 1.5-2.5 n Uranium 4.7i0.6 5.0i6.0 0.0-15.4 i

Sample 8 Gr. beta 28.711.2 35.0i5.0 26.3-43.7 Sr-89 5.710.6 7.Di5.0 0.0-15.7 Sr-90 7.0i0.0 7.0tl.5 4.4-9.6 Co-60 10.7tl.5 10.0 5.0 1.3-18.7 Cs-134 4.0il.7 -

5.015.0 0.0-13.7 Cs-137 5.3i0.6 5.015.0 0.0-13.7 A-8 1

i t

, e <

l Table A-1. (continued)

Concentration in pCi/lb f- Lab Sample Date TIML Result EPA Resultd Code Type Collected Analysis f20c Is, N=1 Control Limits l

STAF-457 Air April 1986 Gr. alpha 13.710.6 15.0i5.0 6.3-23.7 L Filter Gr. beta 46.3i0.6 47.0i5.0 38.3-55.7 l Sr-90 14.7i0.6 18.0tl.5 15.4-20.6 Cs-137 10.710.6 10.015.0 1.3-18.7 STU-458 Urine April 1986 Tritium 4313f70 4423i189 4096-4750 STW-459 Water May 1986 Sr-89 4.3i0.6 5.0i5.0 0.0-13.7 i Sr-90 5.0i0.0 5.0il.5 2.4-7.6 l STW-460 Water May 1986 Gr. alpha 5.310.6 8.015.0 0.0-16.7 Gr. beta 11.3fl.2 15.015.0 6.3-23.7 STW-461 Water June 1986 Cr-51 <9.0 0.015.0 0.0-8.7 l Co-60 66.0il.0 66.0i5.0 57.3-74.7 i Zn-65 87.3tl.5 86.015.0 77.3-94.7 Ru-106 39.7i2.5 50.015.0 41.3-58.7 Cs-134 49.3i2.5 49.0i5.0 40.3-57.7 Cs-137 10.3tl.5 10.0i5.0 1.3-18.7 i STW-462 Water June 1986 Tritium 3427t25 3125i361 2499-3751 STM-464 Milk June 1986 Sr-89 <1.0 0.015.0 0.0-8.7 Sr-90 15.310.6 16.0*1.5 13.4-18.6 I-131 48.312.3 41.Di6.0 30.6-51.4 Cs-137 43.711.5 31.015.0 22.3-39.7 K 15671114 1600i80 1461-1739 STW-465 Water July 1986 Gr. alpha 4.710.6 6.015.0 0.0-14.7 Gr. beta 18.711.2 18.0i5.0 9.3-26.7 STW-467 Water August 1986 I-131 30.3 0.6 45.016.0 34.4-55.4 1

STW-468 Water August 1986 Pu-239 11.310.6 10.lil.0 8.3-11.9 STW-469 Water August 1986 Uranium 4.0 0.0 4.016.0 0.0-14.4 STAF-470 Air Sept 1986 Gr. alpha 19.311.5 22.015.0 13.3-30.7 471 Filter Gr. beta 64.0 2.6 66.015.0 57.3-74.7 472 Sr-90 22.0il.0 -

22.015.0 19.4-24.6 i Cs-137 25.711.5 22.015.0 13.3-30.7 j i

STW-473 Water Sept 1986 Ra-226 6.010.1 6.li0.9 4.5-7.7 )

Ra-228 8.711.1 9.lil.4 6.7-11.5 l A-9

[1 ,

+ n 1 ,

l- 1

' Table A-1. (continued).

1 Concentration in pCi/lb Lab Sample Date TIML Result EPA Resultd Code Type Collected Analysis i20c Is, N=1 Control Limits l

STW-474 Water Sept 1986 Gr. alpha 16.3i3.2 15.0i5.0 6.3-23.7 Gr. beta

, 9.0il.0 8.0i5.0 0.0-16.7 l-STW-4 75 Water Oct 1986 Cr-51 63.315.5 59.0i5.0 50.3-67.7 Co-60 ' 31.0i2.0 31.0i5.0 22.3-39.7 Zn-65, 87.3tS.9 85.0i5.0 76.3-93.7 Ru-106 74.7i7.4 74.015.0 65.3-82.7 Cs-134~ 25.710.6 28.0i5.0 19.3-36.7 Cs-137- 46.3tl.5 44.0i5.0 35.3-52.7 STW-476 Water Oct 1986 H-3 5918i60 5973tS97 4938-7008 SPW-477 Water: Oct 1986 478 (Blind)

Sample A Gr. alpha 34.016.0 40.0 5.0 31.3-48.7 Ra-226 5.810.2 6.0i0.9 4.4-7.6 Ra-228 2.7tl.0 5.0i0.8 3.7-6.3 Uranium 11.0f0.0 10.016.0 0.0-20.4 Sample B Gr. beta 38.7tl.2 51.0i5.0 42.3-59.7 Sr-89 5.0f0.0 10.0i5.0 1.3-18.7 Sr-90 3.010.0 4.011.5 1.4-6.6 Co-60 24.7tl.2 24.015.0 15.3-32.7 '

Cs-134 11.0 2.0 12.0i5.0 3.3-20.7 Cs-137 9.3tl.2 8.0i5.0 0.0-16.7 STM-479 Milk Nov 1986 Sr-89 7.7tl.2 9.015.0 0.3-17.7 Sr-90 1.010.0 0.011.5 0.0-2.6 I-131 52.3 3.1 49.0i6.0 38.6-59.4 Cs-137 45.7*3.1 39.0i5.0 30.3-47.7 K 1489i104 1565i78 1430-1700 STU-480 Urine .Nov 1986 H-3 5540 26 5257i912 4345-6169 STW-481 Water Nov 1986 Gr. alpha 12.014.0 20.015.0 11.3-28.7 Gr. beta 20.0i3.5 20.015.0 11.3-28.7 STW-482 Water Dec 1986 Ra-226 6.7i0.2 '

6.8tl.0 5.0-8.6 Ra-228 5.2i0.2 11.lil.7 8.2-14.0 STW-483 Water Jan 1987 Sr-89 19.715.0 25.0i5.0 16.3-33.7

, Sr-90 21.0i2.0 25.011.5 22.4-27.6 A-10

n.

Table'A-1. (continued).

Concentration in pCi/lb Lab Sample Date TIML Result EPA Resultd Code Type Collected Analysis i20c Is, N=1 Control Limits STW-484 Water Jan 1987 Pu-239 17.0i2.3 16.7tl.7 13.8-19.6 STF-486 Food Jan 1987 Sr-90 36.014.0 49.0i10.0 31.7-66.3 L I-131 78.0i3.4 78.0i8.0 64.1-91.9 Cs-137 89.7i3.0 84.015.0 75.3-92.7 K 942iS6 980i49 895-1065 STF-487 Food Jan 1987. SR-90 2.0i0.0 ---

(Blank) 1-131 <3 ---

Cs-137 <2 . --- ,

K 993i102 ---

STW-488 Water Feb 1987- Co-60 49.0i0.0 50.015.0 41.3-58.7 Zn-65 96.0i7.2 91.0f5.0 82.3-99.7 Ru-106 92.0f20.2 100.0i5.0 91.3-108.7 Cs-134 53.Di3.4 59.0i5.0 50.3-67.7 Cs-137 89.3i4.6 87.015.0 78.3-95.7 STW-489 Water Feb 1987 H-3 4130i140 42091420 '3479-4939 STW-490 Water Feb 1987 Uranium 8.3tl.2 8.016.0 0.0-18.4-STM-491 Milk Feb 1987 I-131 10.010.0 9.010.9 7.4-10.6 STW-492 Water Mar 1987 Gr. alpha 3.7tl.2 3.015.0 0.0-11.7 Gr. beta 11.3tl.2 13.015.3 4.3-21.7 STW-493 Water Mar 1987 Ra-226 7.010.1 7.3t1 . 5.4-9.2 Ra-228 7.li2.3 7.Sil.1 5.5-9.5 STW-494 Water Apr 1987 I-131 8.0i0.0 7.010.7 5.8-8.2

, STAF-495 Air Apr 1987 Gr. alpha 15.0i0.0 14.0i5.0 5.3-22.7 cilter Gr. beta 41.Di2.0 43.0i5.0 34.3-51.7 Sr-90 16.3tl.2 17.0il.5 14.4-19.6 Cs-137 7.010.0 8.015.0 0.0-16.7 STW-496 Water Apr 1987 497 (Blind) ,

Sample A Gr. alpha 30.711.2 30.0i8.0 16.1-43.9 Ra-226 3.910.2 3.910.6 2.9-4.9 Ra-228 4.9i0.9 4.010.6 3.0-5.0 Uranium 5.0f0.0 5. 016.0 0.0-15.4 A-11

a .

l l

Table A-1. (continued) I l

Concentration in pCi/lb i Lab Sample- Date TIML Result EPA Resultd Code Type Collected Analysis i2ac is, N=1 Control Limits STW-496 Water .Apr 1987 497 (Blind)

Sample B Gr. Beta 69.319.4 66.0i5.0 57.3-74.7 i Sr-89 16.313.0 19.015.0 10.3-27.7 1 Sr-90 10.0f0.0 10.0il.5 7.4-12.6 Co-60 8.313.0 8.015.0 0.0-16.7 Cs-134 19.0f2.0 20.015.0 11.3-28.7 Cs-137 14.711.2 15.015.0 6.3-23.7  :

l STU-498 Urine Apr 1987 H-3 60171494 5620i795 4647-6593 STW-499 Water May 1987 Sr-89 38.Di6.0 41.0i5.0 32.3-49.7 Sr-90 21.012.0 20.Dil.5 17.4-22.6 STW-500 Water May 1987 Gr. alpha 9.013.4 11.0i5.0 2.3-19.7 Gr. beta 10.3fl.2 7.0i5.0 0.0-15.7 STW-501 Water June 1987 Cr-51 40.018.0 41.015.0 32.3-49.7 Co-60 60.3i3.0 64.0i5.0 55.3-72.7 Zn-65 11.315.0 10.015.0 1.3-18.7 Ru-106 78.316.4 75.015.0 66.3-83.7 Cs-134 36.7i3.0 40.015.0 31.3-48.7 Cs-137 80.314.2 80.015.0 71.3-88.7 STW-502 Water June 1987 H-3 2906186 2895i357 2277-3513 STW-503 Water June 1987 Ra-226 6.910.1 7.3tl.1 5.4-9.2 Ra-228 13.3fl.0 15.2i2.3 11.2-19.2 STM-504 Milk June 1987 Sr-89 57.014.3 69.0i5.0 60.3-77.7 Sr-90 32.0tl.0 35.011.5 32.4-37.6 I-131 64.0 2.0 59.016.0 48.6-69.4 Cs-137 77.7i0.6 74.015.0 65.3-82.7 K 1383t17 1525176 1393-1657 STW-505 Water July 1987 Gr. alpha 2.310.7 5.015.0 0.0-13.7 Gr. beta 4.011.0 5.0i5.0 0.0-13.7 STF-506 Food July 1987 I-131 82.714.6 80.018.0 66.1-93.9 Cs-137 53.713.0 " 50.015.0 41.3-58.7 '

K 1548157 1680184 1534-1826 STW-507 Water Aug 1987 I-131 45.7i4.2 48.016.0 37.6-58.4 STW-508 Water Aug 1987 Pu-239 5.810.2 5.3i0.5 4.4-6.2 l

A-12 j

g . g t,;

.: ,e '

T abl e ' A-l '. (contin'ed).

u Concentration in pCi/lb L abL ' Sample Date TIM. Result EPA Resultd.

C ode - Type- Collected Analysis $2ac Is, N=1 Control Limits STW-509 Water Aug' 1987 U ranium 13.320.3 13.026.0 2.6-23.4 STAF-510 : Air . Aug 1987 Gr. alpha 9 .7 20 .4 10.015.0' .1.3-18.7 Filter Gr. beta 28.320.6 30.015.0 21.3-38.7 S r-90 10.020.9 10.0il.5 7.4-12.6 i Cs-137 10.011.0 10.015.0 1.3-18.7 STW-51'1 Water Sept 1987 . R a-226 9.920.1 9.711.5 7.2-12.2 R a-228 8.1il.4 6.3il.0 4.6-8.0 STW-512 Water ' Sept 1987 G r. alpha 2 .0 20 .6 4.025.0 0.0-12.7 G r. bets 11.3 1.3 12.025.0 3.3-20.7 STW-513 Water' Oct 1987 H-3 4473 100- 44922449 3714-5270 l

\

. STW-514 Water Oct 1987 (B1ind)

Sampie A G r. alpha 29.322.6 28.027.0 15.9-40.1 4.820.7 3.6-6.1 R a-226 4 .9 20 .1 F R a-P.28 4.211.0 3.620.5 2~7-4.5 Vranium 3.0 d0.1 3 .0 26 .0 0.0-13.4 L

Sample B S r-89 14.3 1.3 16.0 5.0 7.3-24.7 S r-90 9.720.4 10.0il.5 7.4-12.6 C o-60 16.7 3.0 16.0 15.0 7.3-24.7 Cs-134 16.7 2.3 16.025.0 7.3-24.7' C s-137 24.3 3.3 24.025.0 15.3-32.7 STW-516 Water Oct 1987 C r-51 80.3 17.5 70.0 5.0 61.3-78.7 C o-60 16.0$2.3 15.025.0 6.3-23.7 Z n.-65 46 .325 .6 46.0 t5 .0 37.3-54.7 R u-106 57.3215.4 61.015.0 52.3-69.7 C s-134 23.722.5 25.015.0 16.3-33.7 Cs-137 51.7 3.2 51.025.0 42.3-59.7 STU-517 U rine Nov 1987 H-3 7267 100 7432 743 6145-8719 STW-518 Water Nov 1987 . G r. alpha 3 .0 22 .0 7.0 5.0 0.0-15.7 G r. beta 15.722.3 ' 19.025.0 10.3-27.7 STW-519 Water Dec 1987 I-131 26.013.0 26.0 6.0 15.6-36.4 l A-13

_ _ _ _ _ _ _ _ _ _ _ . _ _ . _ _ _ _ _ _ _ _ _ _ _ _ . . I

.. s Table A-1. (continued)

Concentration in pCi/lb g Lab Sample Date TIH. Result EPA Resultd Code Type Collected Analysis 2ac is, N=1 Control Limits-STW-520 Water Dec 1987 R a-226 5 .1 20 .8 4.820.7 3.6-6.0 R a-228 3.420.1 ,5.320.8- 3.9-6.7 STW-521 Water J an 1988 S r-89 27.325.0 30.025.0 21.3-38.7 4 S r-90 15.3 1.2 15.0 1.5 12 .4-17.6  !

STW-523 Water J an 1988 G r. alpha 2 .3 21 .2 4.025.0 0.0-12.7 Gr. beta 7.711.2 8.0 5.0 0.0-16.7 STF-524 F ood . J an 1988 S r-89 44.024.0- 46.0 5.0 37.3-54.7 Sr&90 53.0 2.0 55.012.8 50.2-59.8 I-131 102.324.2 102.0110.2 84.3-119.7 C s-137 95.726.4 91.0 5.0 82.3-99.7 K 1010.7 158.5 1230.0261 .5 1123.5-1336.5 STW-525' Water Feb 1988 C&60 69.3 2.3 69.025.0 60.3-77.7 Z n-65 99.0 3.4 94.019.4 77.7-110.3

'Ru-106 92.7 14.4 105.0 10.5 86.8-123.2 Cs-134 61.728.0 64.0 5.0 55.3-72.7 Cs-137 99.713.0 94.015.0 85.3-102.7 STW-526 Water Feb 1988 H-3 3453 103 33272362 2700-3954 STW-527 Water Feb 1988 Uranium 3.020.0 3.026.0 0.0-13.4 STM-538 Milk Feb 1988 I-131 4.7 1.2 4.0 0.4 3.3-4.7 STW-529 Water Mar 1988 R a-226 7.120.6 7.611.1 5.6-9.6 R a-228 nae 7.7 1.2 5.7-9.7 STW-530 Water Mar 1988 G r. alpha 4 .3 #,1.2 6.025.0 0.0-14.7  !

G r. beta 13.3 1.3 13.0 5.0 4.3-21.7 STAF-531 Air Mar 1988 G r. alpha 21.0 2.0 20.0 5.0 11.3-28.7 Filter G r. beta 48.0 0.0 50.0 5.0 41.3-58.7 S r-90 16.7 1.2 17.0il.5 14.4-19.6 Cs-137 18.7 1.3 16.015.0 7.3-24.7 i STW-532 .Water Apr 1988 I-131 9.0 2.0 7.520.8 6.2-8.8 A-14 4

l

-E

~L.. m. ( .

q Table A-1.- (continued)

Concentration in pCi/lb Lab' Sample Date TIML Result EPA Resultd l Code- Type Collected Analysis 12ac Is, N=1 Control Limits .I I

L o STW-533 Water Apr 1988-534 (Blind)

Sample A Gr. alpha NDf 46.0 11.0 27.0-65.0 Ra-226 ND 6.4 1.0 4.7-8.1 Ra-228 ND 5.610.8 4.2-7.0 Uranium 6.0i0.0 6.0 6.0 0.0-16.4 Sample B Gr. beta HD 57.0 5.0 48.3-65.7 Sr-89 3.3 1.2 5.0 5.0- 0.0-13.7 Sr-90 5.3 1.2 5.0 1.5 2.4-7.6 Co-60 63.311.3 50.015.0 41.3-58.7 Cs-134 7.711.2 7.015.0 0.0-15.7 Cs-137 8.321.2 7.0 5.0 0.0-15.7 STU-535 Urine Apr 1988 H-3 6483 155 6202 620 5128-7276 STU-536 Water- .Apr 1988 Sr-89 14.7 1.3 20.0 5.0 11.3-28.7 Sr-90 20.012.0 20.0tl.5 17.4-22.6 STW-538 Water June 1988- Cr-51 331.7113.0 302.0130.0 250.0-354.0-Co-60 16.0 2.0 15.0 5.0 6.3-23.7 Zn-65 107.7 11.4 101.0 10.0 83.7-118.3 Ru-106 191.3211.0 195.0 20.0 160.4-229.6 Cs-134 18.314.6 20.0 5.0 11.3-28.7 Cs-137 26.3 1.2 25.015.0 16.3-33.7 STW-539 Water June 1988 H-3 5586292 55651557 4600-6530 STH-541 Milk June 1908 Sr-89 33.7 11.4 40.015.0 31.3-48.7 Sr-90 55.315.8 60.0 3.0 54.8-65.2 1-131 103.713.1 94.0 9.0 78.4-109.6 Cs-137 52.7 3.1 51.0 5.0 42.3-59.7 K 1586.7223.1 1600.0180.0 1461.4-1738.6 STW-542 Water July 1988 Gr. alpha 8.7 4.2 15.0 5.0 6.3-23.7 Gr. beta 5.3 1.2 4.015.0 0.0-12.7 ST F-543 food July 1988 Sr-89 ND 33.025.0 24.3-41.7 Sr-90 ND 34.012.0 30.5-37.5 I-131 115.025.3 - 107.0t11.0 88.0-126.0 Cs-137 52.7 6.4 49.0 5.0 40.3-57.7 K 1190.0 66.1 1240.0 62.0 1132.6-1347.4 A-15

m7 -

g c .,

y  ;, , O Table A-1.- '(cont inued ) .

Concentration in pCi/l b Lab- ' Sample- Date . TIML Result __ EPA Resultd Code -Type Collected Analysis ibc Is,.fl=1 Control Limits STW-544',-Water Aug 1988' I-131 80.0 0.0 76.018.0 62.1-89.9 STW-545 Water Aug-1988 Pu-239 11.0t0.2 10.211.0 8.5-11.9 STW-546 Water Aug 1988 Uranium 6.0i0.0- 6.0 6.0 0.0-16.4 STAF-547 Air Aug' 1988 -

Gr. alpha 8.010.0 8.025.0 0.0-16.7 Filter Gr. beta .26.3 1.2 29.0 5.0 20.3-37.7-Sr-90 8.022.0 8.021.5 5.4-10.6 Cs-137 13.0t2.0 12.0 5.0 3.3-20.7 STW-548 Water Sep 1988 Ra-226 9.3 0.5 8.4 2.6 6.2-10.6 Ra-228 5.8 0.4 5.4 1.6 4.0-6.8 STW-549 -Water. Sep 1988 Gr. alpha 7.022.0 8.0 5.0 0.0-16.7 Gr. beta 11.3 1.2 10.0 5.0 1.3-18.7 STW-550 Water Oct'1988 Cr-51 252.0 14.0 251.0 25.0 207.7-294.3 Co-60 26.022.0 25.0 5.0 16.3-33.7 Zn-65 158.3t10.2 151.0 15.0 125.0-177.0 Ru-106 153.019.2 152.0 15.0 126.0-178.0 Cs-134 28.7 5.0 25.0 5.0 16.3-33.7 Cs-137 16.311.2 15.0 5.0 6.3-23.7 STW-551 Water Oct 1988 H-3 2333.31127.0 2316.0 350.0 1709.8-2927.2 STU-555 Urine flov 1988 -H-3 3030.0 208.8 3025.0 359.0 2403.2-3646.8 i l

STW-556 Water flov 1988 Gr. alpha 9.023.5 9.0 5.0 0.3-17.7 Gr. beta 9.7 1.2- 9.025.0 -0.3-17.7 a Results obtained by Teledyne Isotopes flidwest Laboratory as a participant in the environmental sample crosscheck program operated by the Intercomparison and Cali- l bration Section, Quality Assurance Branch, Environmental Monitoring and Support .,

Laboratory, U. S. Environmental Protection Agency (EPA), Las Vegas, flevada. l b All results are in the pCi/1, except for elemental potassium (K) data in milk, I which are in mg/1; air f.ilter samples, which are in pC1/ filter; and food, which is in og/kg.

- c Unless otherwise indicated, the TIttL results are giver, as the mean 2 standard deviations for three determinations.

d USEPA results are presented as the known values and expected laboratory precision (1s,1 determination) and control limits as defined by EPA.

e flA = tiot analyzed.

f fl0 = No data, llot analyzed due to relocation of the lab.

A-16 I i

j C __.___________-.___._.______

l p 7 7 3 2 9 7 1 1 4 3 eai 1 1 1 1 1 1 1 1 1 1 g( c 4 8 5 2 0 0 9 2 8 7 a i . . . . .

r t 6 8 1 6 6 2 3 0 5 0 e r

_ 1 1 3 8 1 1 4 3 7 9

_ v a

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f e f s

1 Table A-3. In-house spiked samples.

Concentration in pCi/1-Lab Sample Date TIML Result Known Expected Code Type Collected Analysis n=3 Activity Precision 1s, n=3a

'QC-MI-6 Milk Feb. 1986 Sr-89 6.0il.9 6.4f3.0 8.7 Sr-90 14.2il.7 12.9i2.0 5.2 I-131 34.2i3.8 35.213.5 10.4 Cs-134 32.0il.8 27.3t5.0 8.7 Cs-137 35.812.1 35.0i5.0 8.7

.QC-W-14 Water Mar. 1986 Sr-89 1.Si0.4 1.6tl.0 7.1 Sr-90 2.4i0.2 2.4i2.0 4.2 QC-W-15 Water Apr. 1986 I-131 44.912.4 41.5t7.0 10.6 00-60 10.611.7' 12.li5.0 7.lb Cs-134 30.2i2.4 25.8i8.0 7.lb Cs-137 21.9fl.9 19.9i5.0 7.lb QC-MI-7 Milk Apr. 1986 I-131 39.7i3.3 41.Si7.0 10.4 Cs-134 28.7f2.8 25.8i8.0 8.7-Cs-137 21.2i2.8 19.9i5.0 8.7 SPW-1 Water May 1986 Gross alpha 15.811.8 18.0i5.0 Sc QC-W-16 Water June 1986 Gross alpha 16.2i0.7 16.9t2.5 8.7 Gross beta 38.4i3.5 30.2i5.0 8.7 QC-MI-9 Milk June 1986 Sr-89 <1.0 0.0 7.lb Sr-90 12.6fl.8 13.3i3.0 4.2b I-131 38.9t7.0 34. 8i 7.0 10.4 Cs-134 33.0i3.4 36.li5.0 8.7 Cs-137 38.Si2.8 39.0i5.0 8.7 SPW-2 Water June 1986 Gross alpha 16.8tl.8 18.0t5.0 Sc SPW-3 Water June 1986 Gross alpha 17.7 0.8 18.0i5.0 Sc QC-W-18 Water Sep. 1986 Cs-134 34.7t5.6 31.3i5.0 8.7 Cs-137 51.li7.0 43.318.0 8.7 QC-W-19 Water Sep. 1986 Sr-89 13.614.k 15.6i3.5 7.lb Sr-90 6.4fl.6 6.2i2.0 4.2b l

A-20 j i

l . .

e  :

C _ ___ _ _ _

i

g 4s-c +; ;

+ , .

Table ' A-3.' 'In-house spiked sampi.es (continued)

Concentration in pCi/1 Lab. Sample. Date TIML. Result Known. Expected-

CodeJ', Type- - Collec ted Analysis n=3 Activityf. Precision 1s, n=3a i" Water .Oct. 1986 Co 19.212.2 18.Sf3.0- 8.7 QC-W 21--

' Cs-134- 31.715.2 25.618.0 8.7 Cs-137 23.8tl.0 21.615.0- 8.7 QC-MI-11' Milk .Oct 1986 Sr-89 12.3fl.8 14.3i3.0 8.7 QC-W-20~ Water Nov. 1986 d-3 3855i180 39601350 520b QC-W-22l Water Dec. 1986 Gross alpha 9.8 1.4 11.214.0 8.7 Gross beta 21.7t2.0 23.8i5.0 8.7 QC-W-23 Water Jan. 1987 I-131 29.8t2.5 27.9f3.0 10.4 QC-MI-12 Milk Jan. 1987 I-131- 36.5fl.3 32.615.0 10.4

, Cs-137 32.614.2 27.418.0 8.7 SPM-13 Milk Jan 1987 Sr-89 10.4f2.1 12.2i4.0 8.7 Sr-90 14.6i1.6 12.6t3.0 5.2 I-131 49.5fl.2 54.918.0- 10.4

'Cs-134 11.6 0.0 8.7 Cs-137 33.3i0.6 27.'418.0 8.7 SPW-24 Water' Mar 1987 Sr-89 24.713.6 25.915.0 8.7 Sr-90 23.9i3.8 22.818.0 ' 5. 2 SPW-25 Water Apr 1987 I-131 28.0il.9 29.315.0 10.6 SPM-14 Milk Apr 1987 I-131 25.0i2.2 23.9t5.0 10.4-Cs-134 <2.1 0.0. 8.7 Cs-137 34.2i2.0 27.2i7.0 8.7 SPW-26 .W ater Jun 1987 H-3 3422i100 3362i300- 520 Co-60 24.8il.4 26.5i7.0 8.7 Cs-134 <2.0 0.0 8.7 Cs-137 21.2i0.5 21.6t7.0 8.7 Gr. alpha 8. 5f* ,9 10.li4.0 SPW-27 Water Jun 1987 8.7 Gr. beta 22.6.2.9 21.2i5.0 8.7  :

SPW-28 Water Jun 1987 Gr. alpha 8.7il.3 10.lf4.0 8.7 Gr. beta 12.2i5.2 9.413.0 8.7 I

1 A-21

'i -

ay ., ;


]

.; y ,y :. y l

. Table' A-3. LI n-house L spiked samples ' (cont inued)'-

)

n c Concentration in pC f/1 p Lab SampleL Date. TIML Resielt

~-

Known Expected '

.l Code Type! -

Colle::ted .Aqalysis m3 Activity ' ' P recision 1 s , n=3 a i* Water

.SPW-29 'Jun 1987 Gr. alpha 16.411.3 18.925.0 8.7 -

p G r. beta 15.924.0- 11.8t4.0 8.7 SP M-15 ' Milk Jul 1987 S r-89 I-131:

'19.421.6 43.520.7'

'18.823.5 45.3t7.0 5.2 10.4 j

C s-134 17.922.2 16.015.3 8.7 Cs-137 25.411.8 22.725.0 8.7

~

iSPW .Water- Sep 1987 S r-89 17.5 3.0 14.325.0 8.7 p

S r-90 18.412.2 17.5 t2.2 5.2 SPW-31 Water- 0ct 1987 - H-3 20531939 2059 306 520 SPW-321 Water Dec 1987 Gr. alpha 8.611.0 10.125.0 8.7 Gr. beta 15.220.1 .13.113.0 8.7

'SP W-33 ' Water-'

Dec 1987 Gr. alpha 7.7 1.4 10.115.0 8.7 Gr. beta 10.9 1.0 ~7.9 3.0 8.7L S' PW-34 Water Dec 1987 Gr. alpha 4.020.9 5.1 3.0. 8.7 Gr. beta 9.420.9 7.923.0 8.7 SPM-16 Milk J an 1988 Sn-89 31.726.0 31.8 4.7- 8.7'

~ S r-90 27.8 3.5 25.512.7 8.7 I-131 23.2 5.0 26.430.5 10.4 C s-134 24.226.0 23.822.3 8.7 Cs-137 - 25.126.0 26.530.8 8 .7- -

SP M-17 Milk Feb 1988 I-131 10.6 tl .2 14.3 1.6 10.4 SPW-35 Water Feb 1988. I-131 9.7 1.1 11.6 1.1- '10.4

-SPW-36 Water Feb 1988 I-131 10.5 1.3 11.6 1.0 10.4 SPW-37 Water Mar 1988 S r-89 19.818.0 17.122.0 8.7 S r-90 17.3 t5.0 18.720.9 5.2 SPM-18' Milk Apr 1988 I-131 26.7 5.0 33.212.3 10.4

. C s-134 30.2 5.0 31.332.1 8.7 Cs-137 26.215.0 29.9 tl .4 8.7 l

l i-A-22 L <

Table A-3. In-house spiked samples (continued) l Concentration in pCi/l Lab Sample Date TIML Result Known Expected Code Type Collected Analysis n=3 Activity Precision 1s, n=3a

~~~ l SPW-38 Water Apr 1988 I-131 14.225.0 17.121.1 10.4 SPK-39 Water Apr 1988 H-3 4176 500 4439 31 724 SPW-40 Water Apr 1988 Co-60 26.124.0 23.7 0.5' 8.7 Cs-134 29.224.5 25.4 2.6 8.7 C3-137 26.2i4.0 26.6 2.3 8.7 SPW-41 Water Jun 1988 Gr. alpha 13.115.0 12.320.4 8.7 Gr. beta 20.1 5.0 22.6tl.0 8.7 SPS-42 Milk Jul 1988 Sr-89 15.1 1.6 16.4 5.0 8.7 Sr-90 18.0 0.6 18.3 5.0 8.7 I-131 88.424.9 86.6 8.0 10.4 Cs-137 22.7 0.8 20.8 6.0 8.7 SPW-43 Water Sep 1988 Sr-89 48.5 3.3 50.8 8.0 8.7 Sr-90 10.911.0 11.413.5 5.2 SPW-44 Water Oct 1988 Co-60 20.9 3.2 21.4 3.5 8.7 Cs-134 38.711.6 33.0 6.0 8.7 Cs-137 19.0 2.4 21.0 3.5 8.7 SPW-45 Water Oct 1988 I-131 22.220.6 23.3 3.5 10.4 SPW-46 Water Oct 1988 H-3 4109 43 41532500 724 SPS-46 Milk Oct 1988 1-131 59.8t0.9 60.6 9.0 10.4 Cs-134 49.6 1.8 48.6 7.5 8.7 Cs-137 25.8 4.6 24.724.0 8.7 Water Dec 1988 Gr. alpha 11.5 2.3 15.2 5.0 8.7 SPW-47 Gr. beta 26.5 2.0 25.7 5.0 8.7 a n=3 unless noted otherwise.

b n=2.

c n=1.

l A-23 l

i u

... .. [. ,,

Table: A-.4 . - In-house " blank" samples.

v Concentration in pCf/1 Acceptance

-l5_th. - , Sample - Date- Re sul ts '. Criteria Cdde Type. Collec ted Analysis (4.66a) (4.660) h SL-1 D.I~. Water' Nov. 1985 Gross alpha <0.1- <1 Gross beta- <0.4 <4 BL-2. 0.I~. Water Nov. 1985 Cs-137 (gama) <1.9 <10 BL-3 D.I.~ Water Nov. 1985 Sr-89 <0.5 <5 Sr <0.6 <1 f BL-5 D.I. Water Nov. 1985. Ra-226 <0.4 <1 Ra-228 <0.4 <1 SPW-22651 0.I. Water Apr. 1985 Gross alpha <0.6 <1 Gross beta . <2.2 <4 Sr-89 <0.2 <5 Sr-90 -<0.4 <1 1-131 <0.2 <1 Cs-137(gamma) <7.4 <10-h

.BL D.I. Water Apr. 1986 Gross alpha <0.4 <1

< BL-7 0.I. Water Apr. 1986 Gross alpha <0.4 <1 BL-8 D.I. Water June 1986 Gross alpha <0.4 <1

'BL-9 D.I. Water June 1986 Gross alpha <0.3 <1 SPW-3185 0.I. Water Jan 1987 Ra-226 <0.1 <1 c Ra-228 <0.9 <1 SPS-3292 Milk Jan 1987 I-131 <0.1 <1 Cs-134 <6.2 <10 Ts-137 <6.4 <10 SPW-3554 D.I. Water Feb 1987 H-3 <180 <300 Gross beta <2.6 <4 SPS-3555 Milk Feb 1987 Sr-89 <0.6 <5 Sr-90 1.9i0.4a <1 SPS-3731- Milk Mar 1987 Cs-134 <2.2 <10 Cs-137 <2.5 <10 1

l a low level (1 - 4 pC1/1) of Sr-90 concentration in milk is not unusual.

A-24 i

.. 's .

Table A-4. In-house " blank" samples (continued).

]

l 1

Concentration in pCi/l Acceptance Lab Sample Date Results Criteria Code Type Collec ted Analysis (4.66o ) (4.66o )

SPS-3732 0.I. Water Mar 1987 Sr-89 <0.9 <5 Sr-90 <0.8 <1 1-131 <0.3 <1 Co-60 <2.3 <10 Cs-134 (gamma) <2.2 <10 Cs-137 (gamma) <2.4 <10 Ra-226 <0.1 <1 Ra-228 <1.0 <1 Np-237 <0.04 <1 Th-230 <0.05 <0.1 Th-232 <0.02 <0.1 U-234 <0.05 <0.1 U-235 <0.03 <0.1 U-238 <0.03 <0.1 SPS-4023 Milk May 1987 I-131 <0.1 <1 SPS-4203 D.I. Water May 1987 Gross alpha <0.7 <1 Gross beta <1.7 <4 SPS-4204 Milk May 1987 Sr-89 <0.5 <5 Sr-90 2.410.6a <1 SPS-4390 Milk Jun 1987 Cs-134 <4.7 <10 Cs-137 <5.2 <10 SPS-4391 D.I. Water Jun 1987 Sr-89 <0.4 <5 Sr-90 <0.4 <1 1-121 <0.1 <1 Co-60 <3.8 <10 Cs-137 <5.7 <10 Ra-226 <0.1 <1 Ra-228 <0.9 <1 SPW-4627 D.I. Water Aug 1987 Gross alpha <0.5 1 Gross beta <1.4 <4 Tritium <150 SPS-4628 Milk Aug 1987 Sr-89 40.6 <5 Sr-90 2.4 0.6a <1  ;

SPS-4847 Milk Sep 1987 Cs-134 <4.4 <10 Cs-137 <5.3 <10 a low level (1 - 4 pCi/1) of Sr-90 concentration in milk is not unusual.

A-25

i s l

. .. ., i Table A-4. In-house " blank" samples (continued).

Concentration in pCi/l Acceptance Lab Sample Date Results Criteria Code Type Collected Analysis (4.66 o ) (4.66 o )

SPS-4848 D.I. Water S'ep 1987 I-131 ed .2 <1 SPW-4849 D.I. Water Sep 1987 C o-60 <4.1 <10 C s-134 <4 .8 <10 C s-137 <4 .0 <10 S r-89 <0 .7 <5 S r-90 <0 .7 <1 SPW-4850 D.I. Water Sep 1987 Th-228 <0 .04 <1 Th-232 <0 .8 <1 U-234 <0.03 <1 U-235 <0 .0 3 <1 U-238 <0.02 <1 An-241 <0.0 6 <1 Co 242 <0.04 <1 R a-226 <0 .1 <1 R a-228 <1.0 <2 SPW-4859 0.1. Water Oct 1987 F e-55 <0 .5 <1 SPS-5348 Milk Dec 1987 C s-134 <2 .3 <10 C s-137 <2 .5 <10 SPW-5384 D.I. Water Dec 1987 C o-60 2.8 <10 C s-134 <2 .6 <10 C s-137 <2 .8 <10 1-131 <0 .2 <1 R a-226 <0 .1 <1 R a-228 <1.2 <2 S r-89 <0 .5 <1 S r-90 <0 .4 <1 SPW-5385 0.I. Water Nov 1987 G r. alpha <0 .4 <1 l G r. beta <2 .2 <4 F e-55 <0 . 3 <1 l

SPS-5386 Milk J an 1988 I-131 <0 .1 <1 )

SPW-5448 " Dead" Water J an 1988 H-3 , <177 <300 A-26

_______________a

.a.

.. .. v. . .

Table A-4. In-house " blank" samples (continued).

Concentration in pCi/l Acceptance Lab Sample Date Results Criteri a Code Type Collected Analysis (4.66 ) (4.66 )

SPS-5615 Milk Mar 1988 Cs-134 <2.4 <10 Cs-137 <2.5 <10 I-131 <0.3 <1 ,

Sr-89 <0.4 <5 Sr-90 2.410. 5 a <1 SPS-5650 D.I. Water Mar 1988 Th-228 <0.3 <1 Th-230 <0.04 <1 Th-232 <0.05 <1 U-234 <0.03 <1 U-235 <0.03 <1 U-238 <0.03 <1 Am-241 <0.06 <1 Cm-242 <0.01 <1 Pu-238 <0.08 <1 Pu-240 (0.02 <1 SPS-6090 flil k Jul 1988 Sr-89 <0.5 <1 Sr-90 1.80.5 a <1 1-131 <0.4 <1 Cs-137 <0.4 <10 SPW-6209 Water Jul 1988 Fe-55 <0.8 <1 SPW-6292 Water Sep 1988 Sr-89 <0.7 <1 Sr-90 <0.7 <1 SPS-6477- Milk Oct 1988 I-131 <0.2 <1 Cs-134 <6.1 <10 Cs-137 <5.9 <10

]

SPW-6478 Water Oct 1988 I-131 <0.2 <1 SPW-6479 Water Oct 1988 Co-60 <5.7 <10 Cs-134 <3.7 <10 Cs-137 <4.3 <10 SPW-6480 Water Oct 1988 H-3 <170 <300 SPW-6625 Water Dec 1988 Gr. alpha ' <0.7 <1 Gr. beta <1.9 <4 a Low level (1 - 4 pCi/1) of Sr-90 concentration in milk is not unusual.

A-27

f s}[ y; ,

TIML-BLIND-01' Revision 0, 12-29-86 ATTACHMENT 8 ACCEPTANCE CRITERIA FOR " SPIKED" SAMPLES LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSESa One Standard Deviation Analysis Level for Single Determination Gamma Emitters 5 to 100 pCi/ liter or kg 5 pCi/ liter

>100 pCi/ liter or kg 5% of known value Strontium-896 5 to 50 pCi/ liter or kg 5 pCi/ liter

>50 pCi/ liter or kg 10% of known value Strontium-90b 2 to 30 pC1/ liter or kg 3.0 pCi/ liter

>30 pCi/ liter of kg 10% of known value Potassium >0.1 g/ liter or kg 5% of known value Gross Alpha <20 pCi/ liter 5 pCi/ liter

>20 pC1/ liter 25% of known value Gross Beta <100 pCi/ liter 5 pCi/ liter

>100 pCi/ liter 5% of known value Tritium <4,000 pCi/ liter is=(pCi/ liter)-=

169.85 x (known).0933

>4,000 pCi/ liter 10% of known value Radium-226, <0.1 pCi/ liter 15% of known value

-Radium-228 Plutonium 0.1 pCi/ liter, gram, 10% of known value or sample Iodine-131, b <55 pCi/ liter 6 pCi/ liter Iodine-129 >55 pCi/ liter 10% of known value Uranium-238, <35 pCi/ liter 6 rJi/ liter Nickel-63 b, >35 pCi/ liter 15% of known value Technetium-99b Iron-55b 50 to 100 pCi/ liter l0 pCi/ liter 10% of known value

  • From EPA publication, " Environmental Radioactivity Laboratory Intercompari-b son Studies Program, Fiscal Year 1981-1982, EPA-600/4-81-004. .

TIML limit.

1 I

A-28

_, .____ - - - - - - ---_ _ _ = _ _ - - - _ - _ _ _ _ _ _ _ - _ _ - - _ - _ _ _ _ _ -

W j .. .

c . , , . .

  • ADDEflDUM TO APPEflDIX A

, !The. followi.ng is 'an explanation of the reasons why certain samples were outside the control li.mit specified by the Environmental ~ Protection Agency for the Interlabora-tory Comparison Program starting January 1987.

I i

. . .. EPA Lab Code Analysis TIHL Result Control Limit Explanation

' STil-504. .Sr-89 ,

57.0 4.3 60.3-77.7 Milk had high fat content which Sr-90 32.0!1.0 32.4-37.6 made analyses difficult. Ad-dition of errors to TIf1L result would ' put values within EPA control limits. EPA also had the same problem in analyzing its own sample.

I STW-511 Ra-228 8.1 1.4 4.6-8.0 TIf!L results are usually within EPA control limits. A.nalysis

of the next ' sample was within

} EPA control limits. flo further i- action is planned.

STW-516 Cr-51 80.3 17.5 61.3-78.7 Results in the past have been within EPA control limits and TIML will monitor the situation

in the future.

I- ST F-524 K 1010.7 158.5 1123.5-1336.5 Error in transferrance of data.

Correct data'was 1105 33.

Results in the past have been within the limits and TIML will monitor the situation in the future.

STW-532 I-131 9.0 2.0 6.2-8.3 Sample recounted after 12 days.

The average result was 8.811.7 (within EPA control limits).

The sample was recounted in order to check the decay.

Results in the past have been within the limits and TINL will continue to monitor the situ-ation in the future.

STU-534 Co-60 63.3 1.3 41.3-58.7 High level of Co-60 was due to contamination of beaker.

Beaker was discarded upon dis-

>- c ove ry of contamination and sample was recounted. Recount results were 53.213.6 and

50.922.4. _.

A-29 f:

c'.g 'l g . , . -. 3, . ,

4 I

1 I

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4 L

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i il 1

Appendix B Data Reporting Conventions 1

i 1

i l

l k

l

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i B-1

L g yr:., 7..- +

1 Data Reporting Conventions 1.0. All activities, except gross alpha and gross beta, are decay corrected to collection time or the end of the collection period.

2.0. Single Measurements l' Each single measurement is reported as follows:

xis where x .= value of the measurement; s = 2a counting uncertainty (corresponding to the 95% confidence level).

In cases where the activity is found to be below the lower limit of detection L it is reported as

-<L where L = is the lower limit of detection based on 4.660 uncertainty for a background sample.

3.0. Duplicate Analyses-3.1. Individual results: x1 i s1 xg t sg Reported r;sult: xis where x = (1/2) (x1 + x2) s = (1/2) s 2,3j 3.2. Individual results: <L1

<Lg Reported result: <L where L = lower of L1 and L2 3.3. Individual results: x s j

<L Reported result: x i s if x > L;

)

<L otherwise l

s B-2 l

- 4.0. Computation of Averages and Standard Deviations l .t 4.1- Averages and standard deviations listed in the tables are computed from all _ of th individual. measurements over the period averaged;.

for example, un annual standard deviation would not be the average of quarterly standard deviations. The average li and standard

~ deviation (s) of a set of n numbers x1, x2, . . . xn are defined.

as follows:

x= hex s= I(*~*)2 n-1 4.2 Values below the highest lower 1imit of detection are not included in the average.

4.3 If all of the values in the averaging group are less than the

-highest LLD, the highest LLD is reported.

4.4 If.all'but one of the values are less than the highest LLD, the single value x and associated two sigma error is reported.

4.5. -In rounding off, the following rules are followed:

4.5.1, If the figure following those to be retained is less than 5, the figure is dropped, and the retained figures are kept unchanged . As an example,11.443 is rounded off to 11.44.

4.5.2 If the figure following those to be retained is greater than 5, the figure is dropped, and the last retained figure is raised by 1. As an example,11.446 is rounded off to 11.45.

4.5.3. If the figure following those to be retained is 5, and if there are no figures other than zeros beyond the five, the figure 5 is dropped, and the last-place figure retained is increased by one if it is an odr'. number or it is kept unchanged if an even number. As an example,11.435 is l

rounded off to 11.44, while 11.425 is rounded off to 11.42. j i

l l

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Omaha Public Power District 1623 Harney Omaha. Nebraska 68102 2247 )

402/536-4000 1

1 April 28, 1989 LIC-89-387 1

U. S. Nuclear Regulatory Commission  !

Attn: Document Control Desk l Mail Station PI-137 )

Washington, DC 20555 i l

Reference:

Docket No. 50-285 l

Gentlemen:

SUBJECT:

Radiological Environmental Operating Report for 1988 Please find enclosed one (1) copy of the Radiological Environmental Operating Report, containing the data taken in the radiological environmental monitoring program, in accordance with the ODCM for the period January 1, 1988 to December 31, 1988. The report is submitted in accordance with the Fort Calhoun Station Technical Specifications 5.9.4.b Radiological Environmental Operating Reports.

Sincerely, h w )? S n

/K. J. Norris Division Manager Nuclear Operations KJM/jak Attachments c: LeBoeuf, Lamb, Leiby & MacRae R. D. Martin, NRC Regional Administrator P. D. Milano, NRC Project Manager P. H. Harrell, NRC Senior Resident Inspector American Nuclear Insurers Roger Cochran, University of Iowa Hygienic Lab dh Y

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kit /he d p a /)nds/ & S 6  ! I o c gggg i0 l S oGC o O l

b 45 5124 Employmen Ith EQJ Opportunity L >