ML20217N502

Responds to RAI on Certificate Amend Request Dealing W/Seal Exhaust Pump Overflows in Buildings E-330 & X-333

ML20217N502
Person / Time
Site:	Portsmouth Gaseous Diffusion Plant
Issue date:	02/20/1998
From:	Toelle S UNITED STATES ENRICHMENT CORP. (USEC)
To:	Paperiello C NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM), NRC OFFICE OF NUCLEAR MATERIAL SAFETY & SAFEGUARDS (NMSS)
Shared Package
ML20217N506	List: ML20217N502 ML20217N526
References
GDP-98-0027, GDP-98-27, TAC-L32031, NUDOCS 9803090053
Download: ML20217N502 (31)

Text

1-Tep L v(CSEC

1. g l

1 A Global Energy Company

/

)

February 20,1998 GDP 98-0027 Dr. Carl J. Paperiello Director, Office of Nuclear Material Safety and Safeguards Attention: Document Control Desk I

U.S. Nuclear Regulatory Commission Washington, D.C. 20555-0001 i

Portsmouth Gaseous Diffusion Plant (PORTS)

Docket No. 70-7002 Response to Request for Additional Information Certificate Amendment Request-Deletion of Seal Exhaust Pump Overflows in Buildings X-330 and X-333 Dear Dr. Paperiello.

The purpose of this letter is to provide a response to the NRC's request (TAC No. L32031) for

]

additional information on the Certificate Amendment Tequest (CAR) dealing with the seal exhaust pump overflows in buildings X-330 and X-333. The request for additional information was provided to USEC in Reference 1 and identified additional information required by NRC to allow final action to be taken on the subject Certificate Amendment Request. Enclosure 1 to this letter provides USEC's response to the request for additional information.

l USEC has reviewed Enclosure 1 (Detailed Description of Change) and Enclosure 3 (Significance Determination), which were previously transmitted in our May 6,1997 Certificate Amendment Request (Reference 2), and has determined that the conclusions of thes: enclosures are still valid.

i l

/

I

BR1888

M88] iga lililitilli!Iluti!Illliti

/

C, 6903 Itodiedy Drke 13cthewla. NID 20H1 -1818 Telephone 301- % -3200 Fn 301-%-3201 herpJ/www.usce.com Offics in thermore. C.\\ l'aducah. KY Ibris m outh 0 1I hhingon. DC M Q2 S

' 4'

.]

Dr. Carl J. Paperiello F.ebruary 20,1998 GDP 98-0027, Page 2 This submittal completes USEC's response to the request for additional information (TAC No.

L32031) provided in Reference 1. There are no new commitments contained in this submittal. Any l

questions related to this subject should be directed to Mr. Mark Smith at (301) 564-3244.

Sincerely, r

i S. A.

I Steven A.Toelle Nuclear Regulatory Assurance & Policy Manager

Enclosure:

As Stated cc: NRC Region III Office NRC Resident inspector-PGDPp )

NRC Resident Inspector - PORTS DOE Regulatory Oversight Manager 1

l l-

.)

t '

l l

Dr. Carl J. Paperiello l

F,ebruary 20,1998 GDP 98-0027, Page 3 l

REFERENCES

1) NRC Letter from Yawar H. Faraz to Mr. James H. Miller,"Portsmouth Certificate Amendment Request - Deletion of TSR 2.2.4.1 Entitled " Seal Exhaust Pump Overflows (TAC No. L32031),"

dated January 16,1998.

2) USEC Letter GDP 97-0041, Mr. James

!ler to Dr. Carl J. Paperiello, "Portsmouth Gaseous Diffusion Plant (PORTS)-Docket No. 70-hi-Certificate Amendment Request-Deletion of Seal Exhaust Pump Overflows in Buildings X-330 and X-333," dated May 6,1997.

{

D e

GDP 98-0027 Page 1 of 7 i

Response to Additional Information Request Deletion of Seal Exhaust Pump Overflows (TAC No. L32031)

Ouestion NM Please provide documented evidence of the hydrocarbon oil properties or the maximum range of such propertic.s used in the PORTS Seal Exhaust Pumps (i.e., manufacturers' data sheet or equivalent). Plea:e include: molecular weight, additives viscosity breakdown temperatures, etc.

l Resoonse:

l l

The Material Safety Data Sheets (MSDSs) for the oils used in PORTS vacuum pumps are enclosed.

l In addition, product specificadon sheets are included for the KV-100 and the HLP-HD32 oils.

Specific oils are typically used for each type of vacuum pump (e.g. Kinney KD-300 pump uses Energol HLP-HD32 oil, Kinney KT-300C and the Stokes pumps use Pacemaker HV-68 oil, Kinney

- KT-170LP pump uscs KV-100 oil); however, any of these oils, as well as process lube oil could be substituted in any pump. The MSDSs and product information sheets provided do not contain all of the information requested. Howere., the information provided confirms that these oils would i

react in a similar manner with UF as those evaluated for the NCS controls.

i Ouestion No. 2:

I Please provide doeuraented evidence cf the maximum quantity of antioxidant additive and its l

chemical form for the hydrocarbon oil ofinterest.

l Resoonse:

/

Based on conversations with the manufacturer, the maximum concentration of antioxidant additive is less than 1% which is below the threshold limit for MSDS reportability and thus is not shown on the MSDSs provided by the manufacturer.

l.

Question No. 3:

Please provide documented evidence of the experimental volume determinations for the S/E pumps in all areas covered by tl e amendment request. Please indude a description of the method used and the uncertainty associated with such measurements including the manufacturers' tolerances. Also provide the maximum volumes for S/E pumps that PORTS commits to maintaining.

9 I

GDP 98-0027 Page 2 of 7 Resoonse:

The volume of the seal exhaust pumps used in Areas 1, 2, and 3 have been determined by Engineering and these volume determinations are documented as follows:

l KT-300C 23.5 gallons (including oil from discharge valve line) i KD-300 19.5 gallons: 3.5 gallons in pump,14-16 gallcns in oil demister Stokes

6.7 gallons

4.25 gallons in pump,2.45 gallons in separator & piping i

Kinney 7.45 gallons: 5.0 gallons in pump,2.45 gallons in separator & piping in general, most of the measurements were performed by filling the pumps and then draining the contents into measured containers. For interconnecting piping that could not be filled using normal filling techniques (e.g. without oil spilling onto the floor), calculations were performed using nominal pipe dimensions and lengths. Please note that the KD-300 pumps were measured up to the top of the pump where the fill hole is located; this is also the same basic elevation of the overflow lines currently installed.

As shown in the NCSAs for the Seal Exhaust Stations 1,2, and 3, which are available at the site for review, PORTS is conunitted to limiting pump volumes for the Seal Exhu:st stations. For the Area 3 Station, pumps have been analyzed safe to a maximum volume of 11.5 gallons; an overflow is

~

required to limit the fill volume to 9.2 gallons if the pump volume exceeds 9.2 gallons. The actual volume of pumps in the Area 3 Station is 6.7 to 7.45 gallons. For Areas 1 and 2. pumps have been analyzed safe to a maximum volume of 33 gallons; an overflow is required to limit the fill volume to 27 gallons if the pump volume exceeds 27 gallone. The maximum volume of the new KT-100C pumps is 23.5 gallons and the maximum volume of the KD-300s, including the separators is less than 20 gallons.

The primary reason for requesting the Amendment was to allow PORTS to take credit for new pumps procured with total volumes less than those that required overflows. In addition, since the combination of the pump configuration and administrative controls (e.g. controls on type and movement of portable containers relative to the seal exhaust pumps, controls on enrichment allowed, etc.) provides double contingency for the seal exhaust stations, no Technical Safety Requirements (TSRs) would be required based on TSR 3.11.5 and SAR Section 5.2. For those pumps that did not have overflows originally installed. the actual maximum volume is less than the NCSA requirements.

Question No. 4:

l Please provide a short technical discussion of the controls relied upon for not exceeding the enrichment level for each seal exhaust station of interest and a discussion / justification of the reliability / availability of such controls.

l

t e

GDP 98-0027 Page 3 of 7 Resnonse:

The controls relied upon for enrichment are described in the NCSA/Es governing the operation of Seal Exhaust Stations for Areas 1,2, and 3 and are summarized as follows: The X-333 Building limit'is 3% enrichment and there is no tie from the X-333 Seal Exhaust Station to the X-330 Building. The X-330 Area 3 Seal Exhaust station is limited to 10% enrichment which is the maximum enrichment permitted in the X-330 Building and it has no ties to the X-326 Building. The X-330 Area 2 Seal Exhaust station is limited to 5% enrichment and has administrative controls specified in the NCSA to prevent tie-in of the Area 2 station to areas with enrichment potentially l

exceeding 5%. Boundary block valves segregating the seal exhaust headers between Area 2 and i

Area 3 are closed, locked, tagged and verified.' In addition, Area 2 is prohibited from providing backup seal exhaust capability for Area 3. The, Area 3 station can be used to provide backup

-capability for the Area 2 station; however, controls for returning the Area 2 station to service after such a condition are described in the NCSA for assuring that the Area 2 station is not valved in to any equipment with an enrichment potentially higher than 5%.

Ouestion No. 5:

Please provide a discussion of the differences between the Stokes-Penwalt Pumps and the Kinney pumps since the experimental data establishing the upper limit on uranium loading is based upon Stokes-Penwalt pumps at the Paducah Site. Specifically, provide information concerning any L

Differential Pressure filter differences in addition to other pertinent information.

1 Resnonse:

i Information, consisting of Seal Exhaust Station flow schematics and pump technical description and vendor schematics. was received from the Paducah site System Engineer on the Stokes-Penwalt pumps utilized in the seal exhaust stations at PGDP. After review of the information provided, there is no significant difference in the seal exhaust pump operation with respect to the potential for uranium contamination or the uranium concentrations that may be experienced in the pump oil. The seal exhaust stations are arranged with the alumina traps preceding the pumps. The pumps are rotating piston, positive displacement pumps utilizing oil to provide lubrication and a seal between the pump impeller and the pump wall. Each pump has an oil mist eliminator (filter) after the pump.

A comparison of the Stokes-Penwalt pump information to the pumps used at Portsmouth did not 1

(

identify any filter differences which would affect uranium loading of the pump oil.

Ouestion No. 6:

Please provide justification for the extended range of applicability of the uranium loading graph provided to the NRC concerning uranium settling in oil over time for the range of 17 wt% to 40 I

t

.J t

GDP 98-0027 Page 4 of 7 wt%. Also, provide a discussion / justification of the time fiame for settling considered in this graph and how such periods relate to settling over extended periods of time (i.e., days to weeks).

Resoonse:

The enclosed graph provides a summary of data collected during pump experiments conducted at PORTS in which small amounts of UF were fed to a pump (2 grams / shot; I shot every two hours 6

for eight hours per day; a total of eight grams per day from day 1 through day 54) and oil withdrawn for sampling (25 cc oil / day; pump volume of 600 cc) was replaced with clean oil. The oil samples withdrawn were allowed to settle ovemight (typically 16-24 hours) which resulted in separation of two phases (a free liquid and a colloidal suspension with the consistency of grease hereafter referred to as " sludge"). The oil and sludge were analyzed separately for uranium concentration and the graph shows the uranium concentration of oil, sludge, and the oil plus sludge average concentration for each sample taken. No data was collected on the effects of further settling beyond that mentioned above. For the test described above, the uranium remained suspended within the colloidal suspension and in the oil. As indicated by the data, there was little difference between the concentration of uranium in the oil and in the sludge. The increase in uranium concentration m the oil / sludge from day 55 to day 60 was due to a doubling of the UF fed to the vacuum pump during this period (16 grams UF./ day).

Question No.7:

Please provide a discussion / justification of the heat of reaction temperature effects on expected viscosity rise and how this relates to maximum uranium loading prior to pump failure (i.e., since pump shutdown relies upon the UF. - oil reaction to increase the density and viscosity of the oil, the heat of reaction effect on " holding down" the effective viscosity rise must be considered when establishing acceptable / predictable control properties). Please consider both a rapid addition of UF6 and a slow or sporadic UF addition over time. Also, please provide a discussion of the maximum i

uranium loading expected prior to pump failure for a hydrocarbon oil that has had viscosity q

breakdown due to normal and extended use prior to oil change.

Resconse:

There has been no data specifically collected identifying the heat of reaccion temperature effects on viscosity rise in pump oil and how this relates to uranium loading prior to pump failure. However, an assessment of the potential effects may be made based on the type of reaction involved and the GDP operating experience.

UF. is reactive with liquid hydrocarbons resulting in conversion of the hydrocarbon to perfluorocarbons. The type of reaction products generated is dependent on the strength of the fluorinating agent, the temperature of the reaction. and the influence of system parameters (e.g.

i

r s

l GDP 98-0027 Page 5 of 7 reactant contact time, heat transfer capability, etc.) The reaction processes are believed to proceed through free radical formation, fluorine substitution for hydrogen, and hydrogen fluoride elimination.

The HF elimination can also result in either ring formation or olefin formation with some unsaturated hydrocarbon being found in the final reaction products. Paraffinic hydrocarbons may be converted to fluorocarbons of the same chain length in mild fluorinating reactions with the formation of dimerization and fluorine substitution in more vigorous reactions. A more detailed discussion of this i

topic is found in K/ETO-143, " Reaction of Uranium Hexafluoride with Hydrocarbon Oil", which is available at the site. The anticipated effects of rapid addition of UF versus a slow, sporadic j

addition of UF. is discussed below. In reviewing this discussion, it is important to note that the j

chemical traps which precede the seal exhaust pumps will remove the UF. from slow, sporadic additions until the traps become saturated at which time degradation of the oil will occur fairly rapidly.

{

A rapid addition of UF will like'y result in significant formation of alkylfluorides and dimers in addition to olefin formation. The alkylfluorides and dimers would result in a more rapid increase in viscosity than from predominant formation of olefins. According to the " hole theory" for explaining viscosity effects, the fom1ation of alkylfluorides and dimers would increase the viscosity i

of the oil more rapidly than would be the case with formation of the olefins. The effect is that the viscosity would increase by a facter of 10-100 very quickly at a uranium concentration of 10-20 weight percent. The calculated viscosity increase for formation of monomer / dimer mixtures versus olefin formation is shown in Figure 1 (taken from K/ETO-143). While it is possible for an increase in temperature of about 20 degrees C to occur (pumps have water cooling jackets which would remove much of the heat of reaction), this would have minimal impact on the viscosity increase as shown in Figure 2 (taken from K/ETO-143). Operating experience at PORTS and PGDP has indicated that for rapid addition of UF to seal exhaust pumps, the maximum uranium concentration observed has been 30 weight percent; most of the time the concentrations observed at pump failure have been less than 23%.

A slow addition of UF, would also result in a mixture of reaction products being formed. During the lower concentration stages of the reaction, it is likely that the reaction would be dominated by formation of the olefins. As the oil /UF. reaction progresses, formation of dimers and alkyl fluorides would increase due to occupation of the more reactive sites in the oil molecules. As a result, the i

viscosity increase would be more gradual. However, as shown in Figure 1, the predicted viscosity increase of the mixture would still increase by about two orders of magni:ude at a concentration of 30 weight percent. Further, as shown by the PORTS test where increments of oil were added to the vacuum pumps as samples were withdrawn (see response to Question 6). a steady state concentration of about 18 weight percent was achieved (although enough uranium was fed to the pump to have produced a concentration of about 35 weight percent). This data indicates that a uranium concentration of 30 weight percent provides a practical maximum for pump operation prior to shutdown due to viscosity increases. The effect of temperature increase would be even less important for this scenario due to the cooling provided to the pumps; however. as noted for the rapid 1

i l

l 1

GDP 98-0027 Page 6 of 7 reaction scenario, the effect of temperature would be minor relative to the overall viscosity increases that would occur.

No data has been collected that would indicate the potential reaction concentrations of oil that had a viscosity breakdown due to nonnal/ extended use prior to a pump change. In general, for highly a

refined parafinnic oils such as used in the seal exhaust pumps, a viscosity breakdown would occur only through high temperature operation (which does not occur in these pumps) or by reaction with strong oxidizing agents (which is the reaction of concern with UF.). It would not appear likely for any reaction mechanism, other than those discussed above, to be of concern.

3 i

I

.D GDP 98-0027 Page 7 of 7 l

LIST OF ATTACHMENTS.

l 1.

Material Safety Data Sheet (MSDS) and product data for Kinney Products j

2.

Material Safety Data Sheet (MSDS) for Pacemaker HV-68 Vacuum Oil i

3.

Material Safety Data Sheet (MSDS) and product data for Energol HLP-HD 32 Oil 4.

Mr -rial Specification for Portsmouth process lube oil

)

S.

Cr ph of uranium in oil loading from PORTS tests.

l 6.

Figures 1 and 2 from K/ETO-143 i

i i

i l

l 6

7 su crvuve mnav ankes vwess (i} U 01/001 e.

Qx

"" NO-NNuy vacuuu A;;;.;M;;" coumudrAbd6L KINNEY VACUUM mou MM/r/b MmmON WM8f~

TEL NO. (617) 828-9500 ExL-- DUE F'MNO. (617) 828-5612 no. g&

i l

Gentlemen:

(

Attached are Product Data and Material Safety Data sheets for Kinney Products i

per your request.

DATA SHEEh

_ PRODUCT -

l PRODUCT MATERIAL SAFETY A.

Kinseal Vacuum Sealant D250-71 L___I D250-72 i

i l

for pump assembly l

B.

Type A Vacuum Pump Oil D250-73 I I

D250-74 1

I i

std. for single stage pumps,.010 Torr C.

Super X Yacuum Pump Oil D250-75 W D250-76 I

i l

std. for compound pumps,.001 Torr I

l D.

Kinlube Vacuum Pump Fluid D250-77 M D250-78 ~ !

1 4

fire resistant phosphate ester E.

Kinney LT Vacuum Pump Oil D250-81 i

I D250-82 O

is similar to KV100 but is a multi viscosity oil plus demulsifier additive for severe duty opera' tion and/or low temperature starting.

F.

F50 Ellicone Vacuum Pump Fluid D250-83 I'

D2f0 ~84 i

i G.

OCR Vacuum Pump Fluid D250-87 1 4

D250-88 L__ _.1 highly refined hydrocarbon H.

Kinney KV100 Vacuum Pump Oil

' D250-89 D250-90 t

is similar to Type A with higher i

viscosity and R and O additives.

j Now standard for all KT pumps

)

1.

Kinney KV475 Vacuun- @ ster Oil D250-92 1

8 D250-93 I

i i

. for blowers.

J.

Halovac 100/125 Pluid D250-94 i

I D250-95 n

Halocarbon/chlorotrifluoroethylene K.

Fomblin Y-LVAC 25/6-16/6 D250-96 i

I

'D250-97 e

i perfluoro polyether L.

UCON Fluid LB-300X I

2250-98 1___,_f.

'D250-99 e

for brakefluid M.

Kinney KV-150 Vacuum Blower Oil D250-108 i i

D250-109 i I

N.

. Mercury for McLeod Gauge-D250-115 1 O.

.LR oil for Liquid Ring Pumps D250-119 L,

L D120-120 L._

J Very truly yours, A. H. Bornemann l

.--. --. m.....-. Chief, Engineer __

l

I

• l 7p' Material Safety Data Sheet May be used to mmply wkh U.S. Department of Labor OSHA's Hazard Ccir...ize;on Standard.

Occupational Safety and Health Administration 29 CFR 1910.1200. Standard must be (Non-Mandatory Form) consteted for specific reouvements.

Form Approved OMB No.1218-0072 toomTY (As Unw atlabelext UE)

USER NO.

KINNEY KV-100 OIL Vacuum Pumo Lubricant Nan

• Blank maces are not pomwred,1 any hm k not =T 'Me h

.h---; m e.e-me mece muur be morned e kwcan mar.

Secdon1 Manuousurer's Name KINNEY D250-90 KINNEY VACUUM COMPANY Ca Wi Telephone Number

~

Adoress (Nunour, sonst csy, m and 72F cuan).

617-828-9500 495 TURNPfRE STREBT u,.

Nummer er :..:.. --.

617-828-9500 CANTON, MA 02021

' '"May*4,1994 e-of rs=; _ (queanno A. H. BORNEMANN Secdon H -- Haas.% :s.2'=.Aa i ist...ation v

Hazareous C mems (somene Chammal -i. 6 em-umas

--i Name(s))

OSHA PE.

ACGlH T1.V r =.--- M

% l:--2 -4 Chemical Family: Refined Paraffinic 5MG/M '

Petroleum Lc.be Oil Oil Mist /Vaoor Weighted 8 HR.

CAS NOS. 64742-54-7

__ Exoosure limit

~

s None of the lubricant components are defined as herdous in accordance with 29C However, the exoosure limit applies to the oil mist / vapor in the discharge of mechan vacuum pumos. See Section VII-Other Precautions.

For other ohvsical oroperties and information, see Kinney Data Sheet D 250-89.

Section Hi ~ Ptr$;M L a ChmEc ?='=__

"T; Poire

=-

r-2 cc:j (Hro - 1)

At atmoscheele pressure 'F.

>400 Vapor Preeuwe tem Hg4 0.88 i

i At 20*C Melting Point

<.010 vapor c, f (An - 1)

Tot Applicabl {

. s=;

ame 1

>l -

i sois=j in waner-pu Ac.we. )

<<1,

% by volume NIL e -. me odor j

Amber oil with mild odor.

i W=-5 IV - Fire and f ; '

". Hazard Data Rash Pown (Memod used

>450*F (COC)

.~.-H Umns UEl.

.9 E ;

r.4 undia 7.0 Foam, dry chemical powder, carbon dioxide.

somew rve sgrang ememowes Wear self-contained breathing apparatus in confined area.

Use water to cool nre -exposed contamers, ano to asperse vapors trom umgnu soills.

unusus rve ano examman Hammas None. NFPA RATING: 1-H/1-F/O-R

Section V - Reactivity Data Stacey Unsumie Conditions to Avoid Statae X

FLAME incompetitWiity (Matertais to AW STRONG OXIDANTS SUCH AS LIQUID OXYGEN AND CELORINE SMOKE, CARBON MONOXIDE AND DIOXIDE, SULFUR OXIDES Hazarocum.

May Nr C _ =si to Avoid

,wri - --wi W4 Not ME y

Section VI - Health Hazard Data Caranogermany:

NTP7 pg W%W NO NO Route (s)of Rej; trmalabon?

Skin?

Ingesson?

Ses ano wnguems EXPOSURE TO OIL MIST MAY CAUSE IRRITATION TO MAY CAUSE NAUSEA; STOMACE

'of Encoeure OR VAPOR IN ErcRSS OF swM T*TVR si1n awn Wi+M TDDT*ATTOM OM cMAMDE.

LIMIT (SEE SECT. VII MAY CAUSE BREATRING )

EYE CONTACT.' PROLONGED

• SITN CONTACT MAY-LEAD IRRITATION,. HEADACE AND TO SKIN DISORDERS.

. NAUSEA.

7"8 #

'. REMOVE T FRESH AIR REMOVE OTLY CLOTHING DO NOT INDUCE VOMITING NASE WITH NATER AND SOAP.

FLUSE EYES WITH CLEAN NATER Generapy A0gravaisd; NOT KNOWN. IF IRRITATION PERSISTS SEE A PHYSICIAN vyr-:=~e, Section Vil-Precautions for Safe Haadfing and Use Steps to Be Takett in Case Matenal is Reisesed or Spised

_ MECHANICAL CLEAN UP - USE OIL ABSORB' ANT (SPEED DRY MOMMAT. cnMTATwwp eT'am__tiv mo M s.

GALLONS, HAX. 55 GALLON DRUM. - NOT SUBJECT TO REL.ASE REPORTS PER SARA TITLE FOR CBEMICALS IN 40 CFR372

\\

6

--e uomed

.bE NOT FLUSE SPILLS OR USED OIL INTO DRAINS OR WATERWAYS USE NORMAL INDUSTRIAL METHOD IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS, Pr - =r : to Be Taken y.f.' CLOSED hTAL OR PLASTIC CONTAI and S; ; -

STORE BELOW 120 P IN

{

NER. PREVENT MOISTURE ACCUMULATION AT CONTAINER CLOSURE TO RETAIN PHYSICAL CHARACHERISTICS.

Omer r.- - -54w

_ VACUUM PUMP DISCHARGE MUST BE FILTERED TO AVOID EXCESSIVE OI CONCENTRATION INSIDE PER OSHA AND CUTSIDE PER EPA.

Section Vill -,- Cor trol Measures Y

NONE NEEDED FOR NORMAL USE ventiistian Local Ezheist TO COMPLY WITH OIL MIST / VAPOR LIMIT, ~ PUMP F,ILTER DISCHARGE WITH ANY RESIDUAL SMOKE AND PRIMARILY VAPOR OEOR MAY NEED TO BE PIPE 3 OUTSIDE, SUB TO PUMP CAPACITY AND ROOM VOLUME, WITE PROTECTION AGAINST ENTRY OF

• RAIN Protecave Gkms USE IF SENSITIVE TO OIL Eye Pnnecion USE TO PROTECT AGAINST OIL TRANSFER SPLASHING NONE REQUIRED

~*" -~

APPLY GOOD HOUSEKEEPINC AND HYGIENE PRACTICE

SUD

'[

Qd U B S M'

PHI M

EL CEE ISN S

1 1111987.G 54321 P

TK G

F R

ISS o

43210 E

E I

H hi E

DOO l

0

.Y TN d

Y in N

1 S

sn E

H HS VDFECCHCV VPFFG I

e R

E i

aeomaoaoi ioil r C

py A

S O

I 3

n

(

C RN p naurruls s u.r aa A

r L

W 551 Kosml brtoc crosv L

oK

.T I

t iri soorro o

hi dV D

I SH ggg h

n tt insa s

sp P t

P u1 E

EL aaa e

npyeo il i

ioopy c0 S

I lll i

E er, snroi t

tilo O

t0 C

t Q

lll f

ye t

e t s,n z y

yns iA P

R S

i ooo o

sl a

nnn l

tsb ei t

iC S,t t n P E

io I

1 l

eus sd3i nS U

,t,I R

si P

o sr/

tu o

dT S

• C I

a I

T l

T w

t,e g

,e h n e

FOC6 E

i O

PPP i

s u.m4w o m===sEe

)

a r

xa a

CO0 S

bs N

e FST w

aaa

,n l

n v

RPO s"oN t-t

=.m=t

==

AEL rrr g

u

}C e

1 a

F e' u CCE ttt m

i m rw is m-21 ns m

xinuiE.so TIR c

v e

nr

=r IFA nnn o

h a2 000 F

• 410

.=w

=c OI de s

EN n

t.s meEc N.D C

.o o.o n

g c sw d

.x 1 e

F o

e t

2 e

n, g.siouWa e t em e

a CPF r

E ff

. se uc S

222

,l o

e a

,= n c..a uw U

000 n

. f a

m

a r

. c=/se r

N 233 e

6 ae oe wra a

r n

AL 900 r

1s u

i eoys.es iv euM=t ONE 921

<7 0I0291651543 vi en s

s t

=u EGS 109 s

50400300 en

.=n

==sm ei

=m C. US i

03 0

00 0

0 00 ng v

e e

000 z

04 5

5 tl e

ne e=e an LO 000 e

5 s

r rc e

5 e

a AT e.aw

a s

cm a*a e

r m

RH 000 s

2 r

.i im "rs E

000 5.,

es m

m*te e

s

• i AR ft o

ass ss c

o e

e ia co n*s=w IW cm ""

aa

/I ng w

e " *".r m t

a 2S ao ee n-r

• E d

r m

DDDDDDD DDDDD A

p e D

D S

M 81S1912 2

2 S

ac A

gR C

A 9423752 19998 HT rh T

A A

E B

T c yW L

2040407 67227 EH aa Yx N

E L - - 00 1% - - -

T fn 4

E HT fi 7

'D OE ic 9

E DS na 7

A N

T il U

B c

v ba ac i

st i

eu ra 4

3 2

o 1

S ip R

)

)

1 E

)

P lu

.F E

sm C

p T

N

( A cmw'tCD( lLwT I

ws h

F D

oueooapaaih A

i P

i P

- M nsi H

U s

A 2a ctg a'tarenzebwti L

tw E

H 5t e

h ar lo I

t hs hi cAK C

P o

aI 0e n b t c m d O if 2p N

Rh

(

u H K i

N r.

teeoioSn 9r F

orN AI T

l a

i r

d n n u Hg N C o O

au t

r u N N D

E t

9a af casa oFd R

nl mrN I N A

S i

0 l

'tlaen pvRu M

dt C E T

T s

E n~E.

iivntS2re1c A

i noE AYFA-F

) S a

otet 5

O T

a i

, a narr)su9em9t T

0m nrY RS A

p r

f

. raa e

b cb1 I

eo VK H

d sCae

- a ea=

s=;

t e t P u r.0 i O

at u==

p e

e eg sV A V E

r t

c s

N ne r

=

m C -

E N

o P

y d.e i x a R t, 1 d

-== = C eNA U 1 T

.O v

r t.opn i22n E

w=w 0 v

n o c P o,5 0 o nE D 0 e

o D

o sRC M5 d

t a

da M

sean 0t a

i' o u ec

=E s

a h f r,s r s.

t

~

oAU fu c

T P

8 a

a.

ve e

,t 1

d c.4 ob R

a9 e

U 0

s A

o 5

P1r8Pf am CI e U H

7 s

S id s

eH m

I P

9 a

s h

diUor1t a 9 e,5 e i s GM es S

rn rp Y

1 o

e

~

s' G e

e c / o.a,0 n O

9 l

e La e M u

.c N

I -

e op Od ac

.. '. D t

xh tp S c a'M i

~

A L

A b

)

.O di e.

3l1S eHa df 0

r l

er 9urcAs R

..L 0

i r

a sg fm1bei ii u=u==S 0

c a

tc seo Bh ia v o. a' 0 p q p r

a t

a

= = =.

i r

au1aa

{

n i

v vt t1; i 'zz ei wu r

R

^N t

n a

efa 0trhaa E

$ E g

i nm0 earr

.s o er

.Y X

w l

oa n

D T

i a

i 8su 0,z.d n d d s

2 H

d o

5

.Q t

b lv tA 1Cu o

h i

ah iT 1os 0

D 1

c mcobroHnm f

W n

1 iuue xoda i D..

D a

W s

.O 6

~

o 0

o sur iw u'n 2

t 0

5

.O n

tm

• l ceon H

f 1

0 t i vria 0

o r

pim ao c c 0

- N n

a c 8

.O o

e umi d

q mot d,r to t

9 u

p e

ir o

j e

d od r

n a r

s t

n c

a

r 1

1 i

MATERIAL SAFETY DATA SHEET j

i i

s Stores Number

\\

l 11-250-9802 Product Name: Pacemaker HV-68 Vacuum Pump Oil j

1 Manufacturer's Name: La Pine Scientific Company Emergency Telephone Number: 318-491-6215 l

Effective Date: None Listed l

1 l

l i

l w

i

\\

.....i

~

g/

TEL NUMBERS AND ADDRESS:

A l?-75 PHONE: 708/388-4030

/

6 FAX: 708/388-4084 LA PINE SCIENTIFIC-COMPANY L'.636 WESTERN AV / PO BOX 780 BLUE ISLAND IL 60406-0780 i

hY &Df$0Q

s T'rade Name:

Pacemaker HV-68 Jon//yrZ/

h Commodity Code: 34-105 Synonyms:

Lubricating 011-CAS Reg. No.:

64741-88-4 Citgo Index No. (CIN):

0246 l

Technical

Contact:

_( 918 ).. R5.-J_9,3 3

.......... _3 "Metlicil' Emfrgency:

(318)'491^-6215

{

MATERIAL HAZARD EVALUATION (Per OSHA's Hazard Communication Standard [29 CFR Part 1910.1200])

(OHCS)

Health:

No n -lia za rdou s. (OHCS)

Precautionary Statement:

None.

I. GENERIC COMPOSITION / COMPONENTS Components CAS (1 Hazard Data Refined Petroleum 64741-88-4 100 Oral:

LD50(rat): >15g/kg Oil (s)

Eye:

Practically Non-Irritating Skin:

Practically Non-Irritating Ihin: LC50/4H(rat): >5,000mg/m 3 E

ND = No Data NN 29@langyprpf ggurpeno compont.rion LAS/34-105

j99 L e

II.

PHYSICAL DATA Physical H yard Classification (Per 29 CFR Part 1910.1200)

No Combustible No Oxidizer No Compressed Gas No Pyrophoric No Explosive No Reactivity No Flammable

}

Yes Stable No Organic Peroxide No Unstable Boiling Point, 760 mmHg, Melting Point, *C(*F): NA

'C(*F):

383(721) 1

-5 Vapor Pressure, c=Hg (25'C):

-1.5x10 Specific Gravity (H 0=1):

0.88 2

Solubility in H 0, % By Wt.:

Negligible 2

Vapor Density (Air:1):>l Evaporation Rate

"""i(Butyl Acetate =1): <1

% Volatiles By Vol..

Negligible pH of Undiluted Product:

ND Appearance and Odor: Amber liquid, bland odor III.

FIRE AND EXPLOSION DATA Flash Point, COC, "C("F): 232(450)

NFPA*

Flash Point, PM, 'C(*F):

228(441)

Health:

1 Fire. Point, COC, *C( F):

266(510)

Flammability:

1 Reactivity:

0 Flammable limits in Air, % Vol.:

Lower: ND Upper: ND Extinguishingfiedia: CO ' dry chemical, foam or water fog.

2 Special Fire Fighting Procedure:

None.

Unusual Fire or Explosion Hazard:

Water may cause frothing.

i

• Citgo assignment based on our evaluation per NFPA guidelines.

. Haza rd. Rating least-0;. slight-1 ;. moderate-2 ;- high-3;- extrene-4;

~^^

ND = No Data l

NA; 28V&dDPM%8ttADNQ CORPORAUoN LAS/34-105 a

,_.g.;

.1.

WS l

i e

l IV.

REACTIVITY DATA l

StabilfEy:' Yes Stable

. No Uns. table me Con'ditions Contributing to' Instability: None.

l-kncompatibility:

Strong oxidants. ;\\

Etzardous Decomposition Products (thermal, unless otherwise specified):

~

CO, CO '

2 I

C:nditions Contributing to Hazardous Po'lymerization: None.

V.

SPILL OR LEAK PROCEDURES

.,..PIs.ce dure s.,.i f.,(la t,e r,ia 1., i s.. s pi 11,e d.:

.y.

--.-.h Remove sources of heat or ignition, provide adequate ventilation, contain leak.

Absorb small spills with suitable material such as rags, straw or sand. Report spills as required to appropriate authorities.

Vaste Disposal:

It is the responsibility of the user to determine if the material is a hazardous waste at the time of disposal.

Check before disposing to be sure you are in compliance with all applicable laws and regulations.

w Protective measures 'during repair and' hsin' ten'ance~df' co'afa' min'aEid^efuipsinii Refer to Section VII - Special Protection Information.

j Avoid prolonged contact with used oil, wash skin thoroughly with soap and l

water.

I 1

ND = No Data d4 ks150enAF;9M 60g/1gno componanon LAS/3!.-105

yf 1

VI.

HEALTH HAZARD DATA Health.liazard Classification (Per 29 CFR Part 1910.1200)

--r e -

No-Carcinogen -

..No-.. Corrosive No Animal Carcinogen No Irritant No Suspect Carcinogen No Sensitizer i

No Mutagen No Teratogen No Highly Toxic j No Target Organ J

No Toxic j

Product listed as carciriogen or potential carcinogen by:

NTPIJo, IARC No, OSHA No, OTHER No.

o Toxicity Summary:

Slightly toxic, 1 pt. to 1 qt. is approximate lethal oral dose j

for 150 lb. human adult.

Major Route (s) of Entry:

Inhalation of fumes.

Acute Exposure Symptoms:

Inhalation:

Low risk of inhalation.

In enclosed spaces or when hot, vapors

~

may reach concentrations suf ficient to cause drowsiness, dizzi-riesi, hesdichE riau'ssa',' or~ Iung irritation.

Mists above TLV may cause chemical pneumonitis.

Dermal

Contact:

Transient, slight irritation.

Eye

Contact:

May be mildly irritating.

Ingestion:

Generally low toxicity. Very large amounts may cause generalized depression, headache, drowsiness, nausea, vomiting or diarrhea.

Small doses may produce irritation and diarrhea.

J Chronic Exposure.

Prolonged and/or frequent contact may cause drying, cracking (dermatitis) or folliculitis. Repeated, excessive exposure to mists or fumes may induce pulmenary irritation or chronic bronchitis.

Other Special Effects:

None expected.

First Aid and Emergency Procedures for Acute Effect Inhalation:

kemove to fresh air.

Respiratory support if necessary.

Seek medical aid.

Dermal:

Wash with soap and water. Do not wear heavily contaminated clothing before laundering.

Eyes:

Flush with large volumes of water.

See physician if any complications arise.

Ingestion:

Do not induce vomiting.

Seek medical aid.

Injection:

Subcutaneous injection is a nedical emergency seek medical aid immediately.

Notes to Physician:

Following ingestion, at a viscosity of about 350 SUS (100 F),

the risk -of-aspiration into the lungs-is remote,.but cuffed. tube.

lavage is still recommended for large quantities.

Aspirated material may cause chemical pneumonitis or lipoid pneumonia.

Subcutaneous or intramuscular injection requires prompt surgical debridement.

If not familiar with technique, seek skilled advice.

j 1

ND = No Data NA steMSnMaliS&h AthNo CoHPORATioN LAS/34-105

f";;'

VII. SPECIAL PROTECTION INFORMATION

w "t'entilation Requirements : Ventilation is required when work place exposures exceed TLV.

Permitted Threshold Agency:

OSHA OSHA ACGIH ACGIH Air Concentrations:

Year:

1972 1985 1985-86 1985-86 Type:

{WA PEL TWA STEL ppm:

3 mg/m :

5 5

5 10 Specific Personal Protective Equipment:

Respiratory: Normally none required.

If high vapor or mist concentrations expected - use respirator approved for organic vapors and mists.

Eyes:

Safety goggles, or chemical splash goggles if splashing is anticipated.

Dermal:

Oil impervious gloves if frequent or prolonged contact is expected.

Other Clothing or Equipment: Wear body-covering work clothes to avoid prolonged

~ ~~ " ~ 5r Tepes t'e'd expos u re. Launder soiled work clothes before reuse.

VIII.

TRANSPORTATION AND SPECIAL PRECAUTIONS Hazardous Material Placard / Label: None.

Storage:

Store below 150*F.

Do not apply high heat or flame to container. Keep separate from strong oxidizing agents.

DOT Information:

DOT /UN Shipping Name:

Petroleum Lubricating Oil.

DOT Hazard Class:

Non-Hazardous.

DOT /UN Hazard Identification Number: None assigned.

D0T Shipping Container Restrictions: None.

EOT Placard:

None.

Caution:

Empty containers may contain product residue which could include flammable or explosive vapors.

Consult appfbpriate Fede'ral, State and Local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this product.

Label: Non-Hazardous.

(OHCS)

All statements, information, and data provided in this material safety data sheet are believed to be accurate and reliable, but 'are presented without guarantee, warranty, or responsibility of any kind, expressed or implied, on our part. Users should make their own investigations to determine the suitability of the information or productr tar their particular purpose.

Nothing contained herein is intended as permissien. Inducement or recommendation to violate any laws or to practice any invention covered by existing patents.

h!D = No Data NA sungcynyyp},1 cat 4sM.o u. wow w -

hAS/ 34 - 2 M i

.m_.

_ _ ~

I BP OlL PYOductIn OYMGliOH ENERGOLS HLP-HD j

PRODUCT DESCRIPTION In the selection of an oil from this cha.rt.

Energol HLP-HD Oils are premium quality, antiwear, hydraulic oils designed to provide progress to heavier viscosity as openting pres-sures increase or range of temperature increases, maximum pump life and trouble free service in industrial and moblic hydraulic systems. They Whenever possible, refer to original equipment man'#acrurt:r's recommendation for viscosity possess proven protection against wear, out-standing oxidation and thermal stability, and are grudes.

able to satisfy low ambient-temperature applica-tions in appropriate viscosity grades. Rcse FEATURES properties make them suitabic for vane, gear or

• Anti-Mar-Minim 12.e5 repairs and downtime.

)

piston type hydraulic pumps and motors.

J Energol HLP.HD Oils exceed all AGMA R & O

• Artti-nast Protects against rust and Gear Oil requirements for the lubrication of corrosion.

encloseciindustrial gear drives and give exec 11cnt

. Anil-oxidant. Resists sludging and extends results on the FZG Test.

,,,, gee t;ge,

• Anti-foam-Supresses foam.

APPLICATION

• Low temperature fluidity - Extends the Energet MLP HD oils are recommended for many useful ambient temperature operating range uses in commercial, industdal and construction typified as follows:

QUAllFICATIONS

• Circulating systems

• Vickers,Inc. 35VQ25A-li

• Ml58 3PP cators g.2950-5 Mobile Hydraulic Systems

Dearings. journal,

antifriction 1286 5 Industrial Hydraulic Systems

• Electric motors

. Hagglunds Denison

" Hydraulic systems (including high pressure gy.0, HF-2 systems)

• CincinnatiMilacron:

• General hand oiling p.68: Enersol MLP HD 52

• Machine tools P-69; Energo! HIP-HD 68 P-70: Energol HLP-HD 46

• Gear cases

• Textile machinery

• R.acine Hydraulics:

S-106: Petroleum Hydraulic Fluids Recornmendations GENERAL RECOMMENDATIONS FOR HYDRAULIC SYSTEMS Pump Type Energol HLP-HD Vanc, Gear and Axial y, 46 or 68 Piston Pumps Oil Gear Pumps requiring 100 heavy oil Proven the World Over. Here for You Today.

02r20 O. [WSd 0: 4 ' U lry.I 1 (Blub TUKl.,:iAb 1Nu U:,r l'IOT0VILLE 30.1100 r.

/. Waas

)

1 I

i j

+

i

(

TYPICAL PROPERTIES ENERGOL HLP-HD Test Method 32 46 68 100 220 Grade (ISO VG) 1 2

3 5

AGMA No.

Gravity,

• API D287 31.4 30.1 29.6 27.5 27.2 Viscosity, Kin.:

D445 cst @40' C 33.3 46.2 62.5 96.4 207.5 l

cSte100* C 5.5 6.7 8.1 11.0 18.2 Viscosity, 02161 SUSO100* F 171.6 283.6 323.7 501.9 10S5 SUS @210* F 44.7 48.7 53.4 64.0 93.0 Vlecosityindex D2270 100 98 97 96 96 Pour Polnt

• C(* F)

D97 34(-29)

-32(-25)

-29(-20)

. 20(-4)

-18(0)

Flash Point." C(* F)

D92 205(400) 215(420) 227(440) 237(459) 261(502) color D1500 1,0 1.0 Lt.5 L3.0 4.0 Rust Preventive Test D665 Procedures A&B,24 hr.

pass pass pass pass pass OxidationTest,:hr. D943 3000+

3000+

3000+

2000+

1500+

i Zinc, wt.%

0.04 0.04 0.04 0.04 0.04 l

l l

I

(;

BP OIL aP en cornpen, 200 Public Square Clevelana.OM e41is N824-7229

~

MATERIAL SAFETY DATA SHEET Stores Number 11-815-3000 Product Name: Energol HLP-HD 32 Manufacturer's Name: BP Oil Company Emergency Telephone Number: 800-321-8642 or 800-424-9300 Effective Date: 7/7/93 l

l

waik )wu'az N

BP OIL MATERIAL SAFETY DATA SHEET Sli1l 24-HOUR EMERGENCY ASSISTANCE GENERAL ASSISTANCE NFPA FIRE HAZARD SYMBOL BP America: 800-321-8642 216-441 8106 A

4Ew CHEMTREC Assist:800-424-9300 F=== r m n.m.

e 1

ww.

.a

1. y 1

0 MSDS Number >

1-Sight 1311 Version #: 2 0 insgnTeant s

T.=

1 MANUFACTURER / SUPPLIER: BP Oil Company-ADDRESS: 200 Public Square, Cleveland, OH 44114-2375 g_ /f@

PISPEQQDQTilDENUFJGhTidRuf5EM$sini2&nfareFan i

~

r TRADE NAME:

ENERGOL HLP-HD 32 CAS NUMBER:.

MIXTURE SYNONYM (S):

LUBRICATING Oll: HYDRAULIC OlL CHEMICAL FAMILY:

HYOROCARBON MOLECULAR FORMULA: MIXTURE MOLECULAR WEIGHT:

ND PRODUCT CODE:

-P 3398/3407 HIERARCHY: 050.060 r

.(

HEALTH POSSIBLE ASPIRATION HAZARD IF St GLOWED--CAN ENTER LUNGS AND CAUSE DAMAGE MAY BE IRRITATING TO THE SKIN, LIES AND RESPIRATORY TRACT REACTIVITY STABLE b

T s

INGESTION:

M y cause gastrointestinal disturuances.

Aspiration into lungs may cause pneumonitis. Symptoms may include ir vrtiting and diarrhea.

SKIN:

SLIGHTLY IRRITATING.

Repeated or prolonged contact may result redar,s s, itching, inflammation, in defatting, oil acne, honted material may cause thermal burns. cracking and possible secondary infection.

Contact with High pressure skin injections are SERIOUS MEDICAL EMERGENCIES.

Injury may not appear serious at first; within a few hours, tissue will become swollen, discolored and extremely painful (see Notes

~

to PhysicianIsection).

'pyright @ 1960, NationalFire Protection Assoc., MA 02269.

s reprinted materialis not the complete and official position of the NFPA on tha rararam as *~. u:~~*

.-*.:-~-----

...C,.

N-EYE:

SLIGHTLY IRRITATING. Contact with heated material may cause thermal burns.

k f e..1 INHALATION:

H:y cause respiratory tga' titation. Exposure to high concentrations of dense oil mists may lead to oil pneumonia.

SPECIAL TOXIC EFFECTS:

IARC has~ determined that there is inadequate evidence for the carcinogenicity of highly-refined oils in humans and experimental animals.

(IARC Class--3).

&S&??5SkUW kW?Ykhb5?YY$5?$

INGESTION:

DO NOT INDUCE VOMITING BECAUSE OF DANGER OF ASPIRATING LIQUID INTO LUNGS.

If spontaneous vomiting, occurs, monitor for breathing difficulty. Get immediate medical attention.

SKIN CONTACT:

Remove contaminated clothing and launder before reuse. Wash area of contact thoroughly with soap and water..Get medical attention if irritation persists. Thermal burns require immediate medical attention. High pressure skin injections are SERIOUS MEDICAL EMERGENCIES. Get insnediate medical attention.

EYE CONTACT:

Flush issnediately with large amounts of water for at least 15 minutes. Eyelids should be hold away from the eyeball to ensure thorough rinsL*,g.

Get medical attention if irritation persists. Thermal burns require immediate medical attention.

INHALATION:

R:. move affected person from source of exposure. Get medical attention if irritation persists.

.h t I

?

Aspiration of petroleum hydrocarbons may cause severe pneumonitis (oil pneumonia).

Vomiting should not be induced. In unconscious victims, use of ah andotracheal tube should be considered if gastric lavage is undertaken. In-case of skin injection, prompt dsbridement of the wound is necessary to minimize necrosis and tissue loss.

e t$5&f&[W

$ik$i$ lKRQi???N? ??!!

EYE PROTECTION:

Avoid eye contact with this material. Wear safety glasses or chemical goggles.

Provide an eyewash station in the work area.

SKIN PROTECTION:

Avoid skin contact. When working with this substance, wear appropriate chemical protective gloves. Depending upon conditions of use, additional protection may be necessary such as face shield, apron, armcovers, etc.

I RESPIRATORY PROTECTION:

If exposure limits are exceeded or if irritation is experienced, NIOSH approved respiratory protection should be worn. Ventilation and other forms of' engineering ND = No Data 1311 /Page 2 of 6 NA = Not Applicable

' cont.rolo cro of ten the preferred maans for controlling c!M:isal exposures.

Respiratory protection may be needed for non-routine or emergency situatiosa.

BEEHYafenEPEORMDES$$sFi$$$$$$$$@@NB@D$@l5MMW$$$isi$$$wed BOILING POINT:

> 218.33 c (425.Oo F) G 7 60. o o IOGIO SPECIFIC GRAVITY:

0.873 e 15.6/15.6 c MELTING POINT:

NA

% VOLATILE:

NEGLIGIBLE VAPOR PRESSURE:

NEGLIGIBLE EVAPORATION RATE (WATER =1): VEar slow VAPOR DENSITY (AIR =1):

HEAVIER

~

VISCOSITY:

> 150 sus s 40 c

% SOLUBILITY IN WATER:

NEGLI0IBLE OCTANOUWATER PARTITION COEFFICIENT: ND i

POUR POINT: ND pH:

ND APPEARANCE / ODOR: LIQUID.

i EMNEMEMlNjMMNkMI5E!5ENN5NN!5/Nd53MNMENN5NNdN5EIN FLASH: POINT:

204.000 c (400 F)

)

AUTOlGNITION TEMPERATURE:

ND FLAMMABILITY, LIMITS IN AIR (% BY VOL.) LOWER:

NA FLAMMABILITY LIMITS IN AIR (% BY VOL.) UPPER:

NA

(

l BASIC FIREFIGHTING PROCEDURES:

Uso water spray, dry chemical, foem or carbon dioxide to extinguish fire. Water or foam may cause frothing, with further application leading to boilover. Use water spray to cool fire-exposed containers, structures and to protect personnel. Use water to flush spills cwry from sources of ignition. Do *1ot flush down public sewers or other drainage systems.

Exposed firefighterm must wear MSHA/NIoSH approved positive pressure self-contained broathing apparatus with full face mask and full protective clothing.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

ccmbustibic at high temperatures. Irritating or toxic substances may be emitted upon th:rmal decomposition.

glgnEsBTgE(#ATA'hQ@M@@gf@gg@j@@gg@j*S$yjgM STABILITY /INCOMPATIBILTY:

stchie under conditions of normal use.

Avoid contact with strong oxidizers.

i HAZARDOUS REACTIONS /DECOMPOS(TION PROC.UCTS:

Combustion may produce oxides of carbon, sulfur, phosphorus and reactive hydrocarbons.

[f$fENV@DNMENTAWNE0W4ATJond$ndhn21@#Mnf8 moi %WM SPILL OR RELEASE TO THE ENVIRONMENT:

If your facility or operation,has an " oil or Hazardous Substance contingency, Plan", activate its procedures.

ND No Data NA - Not Applicable 1311/Page 3 of 6

p l

n.

s

-- Tako ima: disto stcpc to-stop and contain tha spill. Cc D on cheuld bs exercised regarding personnel safety and exposure to thevspilled material.

-- For technical advise and assistance related to chemicals, contact CHEMTREC (800/424-9300) and your local fire department.

-- Notify the National Response Center, if required. Also notify appropriate ctate and local regulatory agencies, the LEPC and'the SERC.

Contact the l

local Coast Guard'if the release is into a waterway.

l l

Emergency Actio u.

Keep unnecessary people away.

Keep ignition sources out of area.

Spiller Leak Procedure:

step leak if you can do it without risk Small spills: Take up with sand or other l

nsacombustible absorbent material and place into containers for later disposal. Large

~

l-spills: Dike far ahead of liquid spill for later dispose 1.

[

Natification:

of this material to narigable Any spiil or release, or substantial threat of release, watcr (virtually any surface water) sufficient to cause a visible sheen upon the water must be reported inunediately to the National Response Center (800/424-6802), as required I

by U.s. Federal Law.

Failure to report may result in substantial civil and criminal p nalties.' Also contact the Coast Guard and appropriate s, tate and local regulatory

cg:ncies.

WASTE DISPOSAL:

i

.This substance, when discarded or disposed of, is not specifically listed as a hazardous wacte in Federal regulations; however it could be characteristically hazardous if it is L

L censidered toxic, corrosive, ignitable, or reactive,according to Federal definitions (40-CFR 261). - Additionally, it could be designated as hazardous according to ~ state,

i l

regulations. This substance could also become a hazardous waste if it is mixed with or ccmes in contact with a hazardous waste. Check 40 CFR 261 to determine whether it is a h::ardous waste. If it is a hazardous waste, regulations at 40 CFR 262, 263, 264, 268 and 270 apply. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or

'otherwise itaappropriate.

Tho transportation, storage, treatment, and disposal of this wast'e material must be cenducted in compliance with all applicable Federal, sitate, and local regulations.

- SdRA TITLE IllINFORMATION:

Licted below are the hazard categories for the superfUnd 7.msndments and Reauthorization Act (SARA) Section 311/312 (40 CFR 370):

Immediate Hazard:

Delayed Hazard:-

Fire Hazard:,,_ Pressure Hazard: - Reactivity Hazard: -

ADDITIONAL ENVIRONMENTAL REGULATORY INFORMATION:

There may be specific regulations at the local, regional or state level that pertain to this material.

l ND = No Data 1311 /Page 4 of 6 l

NA = Not Applicable I

r p.

t

~

l MBEDMQRYnRMERATinR4MWWAMit!n6@GiWiMS$s$i~MMMM@%WC,,R9 All components of this product are listed on the TSCA inventory. All components of this product are listed on the Canadian DSL Inventory.

1

! Ei5NhM.ECX0In8S/SQRPliEMEliTAEINFEORMXTIQW42FfMS MS.%?DINEi!

HANDLING / STORAGE:

Store in tightly closed containers in cool, dry, isolated, well-ventilated area away from hact, sources of-ignition and incompatibles. Do not store in unlabeled containers.

Do not eat, drink or smoke in areas of use or storage.

Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Remove contaminated clothing and clean before reuse. Wash thoroughly after work using soap and water.

EMPTY CONTAINERS:

Empty containers may contain toxic, flammable / combustible or explosive residne or vapors.

Do not cut, grind, drill, weld, reuse or dispose containers unless adequate precautions are taken against these hazards.

htWSPJBTAllOMnfoQin@nRTSi(qbMESTMil NDfE!Wd@ @#i!@@bMMM D.O.T. PROPER SHIPPING NAME (49 CFR 172.101):

PETROLEUM OIL, N.O.I.B.N.

D.O.T. HAZARD' CLASS (49 CFR 172.101):

NOT RIGULATED UN/NA CODE (49 CFR 172.101):

NOT REGULATED PACKING GROUP (49 CFR 172.101):

NOT REGULATED BILL OF LADING DESCRIPTION (49 CFR 172.202):

PETROLEUM OIL, N.O.I.B.N.

D.O.T. LABELS MEQUIRED (49 CFR 172.101):

NOT REGULATED i

D.O.T. PLACARDS REQUIRFD (49 CFR 172.504):

NOT REGULATED i@.i.N_G__RE,.,_01EN.. T.S._/RE.,_XOT,_flM. A.. ZA_R_my. NEO..m_M_ATIO._H,i@ sun _sV.s.2N#mWM5%,.m*w*M8

. -- D R

Wak E

i mm m

s._- t mm

-m,_

m i

COMPONENT l

CAS No.

I l EXPOSURE LIMITS - RET.

Dictillates, hydrotreated 64742-54-7 40-55 5 mg/m3 TLV; 10 mg/m3 STEL (ACGIH) hsavy paraffinic for oil-mist, mineral 4*5 mg/m3 PEL (OSHA) for oil mist, mineral 5 mg/m3 TWA; 10 mg/m3 STEL (NIOSH) for oil mist, mineral Solvent devaxe4 distillate, 64742-65-0 40-55 5 mg/m3 TLV; 10 mg/m3 STEL (ACGIH) heavy paraffinic for oil mist, mineral 5 mg/m3 PEL (OSHA) for oil mist, mineral 5 mg/m3 TWA; 10 mg/m3 STEL (NIOSH) for oil mist, mineral The OSHA Permissible Exposure Limits listed above were promulgated by OSHA in 1989.

This standard was vacated by the U.S. Court of Appeals for the Eleventh Circuit.

Exposure lLmits defined in specific chemical standards found in ND = No Data 1311/Page 5 of 6 NA = Not Applicable

1 :: :s 29 CFR 1910.1001-1048 cro not covered by this ruling cna at%ALtill cnferceable.

REVISION DATE: 07-Jul-1993 REPLACES SHEET DATED:

02-nov-1990 c

COMPLETED BY: BP OIL HSEQ DEPARTMENT.

l i

NOTICE: The informadon presented herein is based on data considered to be acaJrate as of the date of preparation of mis Material Safety Data Sheet. However, no warranty or representation, express or impEed,is made as to the accuracy or completeness of the foregoing data and safety information, nor is any aut+h given or impEed to practice any patented inver.6cn without a license. In addtion, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal usc from any i'

failure to adere to recommenced practices, or from any hazards inherent in the nature of JN, product, l

l i

1

)

l 6

• l l

1311 /Page 6 of 6 ND = Nc Data NA = Not Applicable l

ga BP OIL RECOMMENDED LABEL DATA ENERGOL HLP-HD 32

=

POSSIBLE ASPIRATION HAZARD IF SWALLOWED-CAN ENTER LUNGS AND CAUSE DAMAGE MAY BE IRRITATING TO THE SKIN, EYES AND RESPIRATORY TRACT Refere us'ing this product, read the MSDS which contains more detailed precautionary mencures, handling instructions and emergency proceduras.

MMRSMMROfMSMM4TAMENISMMRMMy@hipsgegggsM@##tsMiikst#ifd$gg Avoid prolonged or repeated contact with skin and clothing.

If contact is unavoidable, w:cr protective clothing, face protection and gloves. Use with adequate ventilation.

After handling, wash thoroughly with soap and water.

NNNRS MIDI $M@$I!55 M $d$$ @ k M M d NIN$NMM@k$ih$ M $ M NINE$$kl5M44NMI l

LNGESTION:

DO NOT INDUCE VOMITING BECAUSE OF DANGER OF ASPIRATING LIQUID INTO LUNGS.

If spontaneous vomiting occurs, monitor for breathing difficulty. Get immediate medical attention.

SKIN CONTACT:

Remove contaminated clothing and launder before reuse. Wash area of contact thoroughly with soap and water. Get medical attention if irritation persists. Thermal burns require i=msdiate medical attention. High pressure skin injections are SERIOUS MEDICAL EMERGENCIES. Get i= mediate medical attention.

EYE CONTACT:

Fluch immediately with large amounts of water for at least 15 minutes.

Eyelids should be held away from the eyeball to ensure thorough rinsing. Get medical atten*. ion if irritation persists. Thermal burns require i=meciate medical attention.

INHALATION:

Remove affected person from source of exposure. Get medical attention if irritation p:rcists.

_.,.. J

[M, MMMSWQ$O@@@,gpRggyng_g{W@WgiggMjp@@@MR@,@i!R$m)

,_,,,n.._,.,_-.w_nwnm,-

._,c Uso water spray, dry cha=ical, foam or carbon dioxide to extinguish fire. Water or foam may cause frothing, with further application leading to boilover. Use water spray to cool fire-erposed containers, structures and to protect personnel. Use water to flush spills cwcy from sources of ignition. Do not flush down public sewers or other drainage systems.

Exposed firefighters must wear MSHA/NIOSH approved positive pressure self-contained brostbing apparatus with full face mask and full protective clothing.

l l

.. ~.. -

s s

!sisgil11ROR!!1EAl@RBOQEDURER$$$$EfMfMr@$E);nN$5?&9TQ@RsNSES5pgSq$g*ig$$gg stop leak if you can do it without risk. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal.

$MANSRQRTATION!REQUIREMENTSyl@MNTi%2Ms#M$9hTx $14sss%CWlRQ BILL OF LADING DESCRIPTION (49 CFR 172.202):

PETROLEUM OIL, N.O.I.B'.N.

l D.O.T. LABELS REQUIRED (49 CFR 172.101):

NOT REGULATED r

i l

REEMPJNLCONT/0NE.RSy@yfj$s9EkMii%MM$i?&@MW59tM@MKj@@E%%)ll$sijngpgg ATTENTION! l Empty containers may contain coxic, flam able/ combustible or explosivo residue or vapors. D3 not cut, grind, drill, weld, reuse or dispose containers unless adequate precautions era taken against these ha:ards, OBSERVE ALL PRECAUTIONARY LABELING. FA11t GREDIENISINF#8MMIOff$$$$if!E$$$$LER$$A%%%MlT5%$R*32$$$M%$$2N l The following component (s) of this product are listed in accordance with right-to-know l laws: Component (s): CAS Number: Dictillates, hydrotreated 64742-54-7 heavy paraffinic solvent dewaxed distillate, 64742-65-0 hsavy paraffinic M&M$Q33@p%ppit!g$@)$i$$$d%MMWi@$M@PWln$$i@$ BP Oil Company l 200 Public square, Cleveland, OH 44114-2375 FOR ANY CHEMICAL EMERGENCY CALL CHEMTREC (800) 424 9300 General Assistsrce 216-441-8106 Iscue Date: 07-jul-1993 y l ND = No Data 1311 /Page 2 of 2 NA = Not Applicable l I}}