ML20203J261

Provides Response to RAI on Certificate Amend Request Dealing W/Seal Exhaust Pump Overflows in Buildings X-330 & X-333

ML20203J261
Person / Time
Site:	Portsmouth Gaseous Diffusion Plant
Issue date:	02/20/1998
From:	Toelle S UNITED STATES ENRICHMENT CORP. (USEC)
To:	Paperiello C NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM), NRC OFFICE OF NUCLEAR MATERIAL SAFETY & SAFEGUARDS (NMSS)
References
GDP-98-0027, GDP-98-27, TAC-L32031, NUDOCS 9803040034
Download: ML20203J261 (9)

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USEC

, A Glot.at Energy Company February 20,1998 0DP 98 0027 Dr. Cml J. l'aperiello Director,00 ice of Nuclear Material Safety and Safeguards Attention: Document Control Desk U.S. Nuclear Regulatory Commission Washington, D.C. 20555-0001 Portsmouth Gaseous I)iffusion Plant (POltTS)

Docket No. 70 7002 Response to Request for Additional information Certincate Amendment Request Deletion of Seal Exhaust Pump Overflows in llulldings X-330 and X 333

Dear Dr. Paperiello:

The purpose of this letter is to provide a response to the NRC's request (TAC No. L32031) for additional information on the Certificate Amendment Request (CAR) dealing with the seal exhaust pump overflows in buildings X-330 and X 333. The request for additional information was provided to USEC in Reference I and identified additional information required by NRC to allow final action to be taken on the subject Certificate Amendment Request. Enclosure I to this letter provides USEC's response to the request fbr additional information.

USEC has reviewed Enclosure 1 (Detailed Description of Change) and Enclosure 3 (Significance Determination), which were previously transmitted in our May 6,1997 Certificate Amendment Request (Reference 2), and has detennined that the conclusions of these enclosures are still valid.

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Dr. Carl J. Paperiello February 20,1998 ODP 98 0027, Page 2 t

This submittal completes USEC's response to the request for additional information (TAC No.

L32031) provided in Reference 1. There are no new commitments contained in this submittal. Any questions related to this subject should be directed to Mr. Mark Smith at (301) $64 3244.

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Sincerely,

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S. A.

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Steven A.Tocile l

I Nuclear Regulatory Assurance & Pc,licy Manager

!!nclosure: As Stated i

cc: NRC Region 111 Ollice NRC kesident inspector PODP 1

NRC Resident inspector-PORTS DOli Regulatory Oversight Manager L-

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Dr. Carl J. Paperiello February 20,1998 ODP 98 0027, Page 3 REFERENCES

1) NRC Letter from Yawar 11. Paraz.o Mr. James 11. Miller,"Portsmouth certificate Amendment Request Deletion of TSR 2.2.4.1 Entitled " Seal Exhaust Pump Overflows (TAC No. L32031),"

dated January 16,1998,

2) US!!C Letter ODP 97-0041, Mr. James 11. Miller to Dr. Carl J. Paperiello, "Portsmouth Gaseous Diffusion Plant (PORTS). Docket No. 70 7002 Certificate Amendment Request Deletion of Seal Exhaust Pump Overflows in llulldings X 330 and X 333," dated May 6,1997.

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linclosure i GDP 98 0027 Page 1 of 7 Itesponse to AdditionalInfbrmation lleguest Deletion of Seal fixhaust Pump Overnows (TAC No. L32031)

Quotion No.1:

Please pmvide documented evidence of the hydroembon oil properties or the maximum range of such properties used in the PollTS Seal lixhaust Pumps (i.e., manufacturers' data sheet or equivalent). Please include: molecular weight, additives, viscosity breakdown temperatures, etc.

Enponse:

The Material Safety Data Sheets (hiSDSs) fbr the oils used in PollTS vacuum pumps are enclosed.

In addition, product specification sheets are included Ibr the KW100 and the llLP ilD32 oils.

Specine oils are typically used for each type of vacuum pump (e.g. Kinney KD 300 pump uses linergol lil.P ilD32 oil, Kinney KT-300C and the Stokes pumps use Pacemaker 11W68 oil, Kinney KT-1701.P pump uses KV 100 oil); however, any of these oils, as well as process lube oil could be substituted in any pump. The h1SDSs and product infbrmation sheets provided do not contain all of the information requested, llowever, the infbrmation provided confirms that these oils would react in a similar manner with UF,. as those evaluated Ibr the NCS controls.

Quation No. 2; Please provide documented evidence of the maximum quantity of antioxidant additive and its chemical ibnn Ibr the hydrocarbon oil ofinterest.

Itesnonse:

llased on conversations with the manufacturer, the maximum concentration of antioxidant additive is less than 1% which is below the threshold limit ihr hiSDS reportability and thus is not shown on the MSDSs provided by the manufacturer.

Question No. 3:

Please provide documented evidence of the experimental volume detenninations for the S/li pumps in all areas covered by the amendment request. Please include a description of the method used and the uncertainty associated with such measurements including the manufacturers' tolerances. Also provide the maximum volumes for S/li pumps that PollTS commits to maintaining,.

linclosure i GDp 98 0027 Page 2 of 7 1

itesponse; The volume of the seal exhaust pumps used in Areas 1,2, and 3 have been detennined by

!!ngineering and these volume detenninations are documented as follows:

KT 300C 23.5 galloits (including oil from discharge valve line)

KD400 19.5 gallons: 3.5 gallons in pump,1416 galhms in oil demister Stokes

6.7 galloris

4.25 gallons in purnp,2.45 gallor.s in separator & piping Kinney 7.45 gallons: 5.0 gallons in pump,2.45 gallons in separator & piping in general, most of the measurements were perfin.ned by filling the pumps and then draining the contents into measured containers. For interconnecting piping that could not be filled using nonnal filling techniques (e.g. without oil spilling onto the floor), calculations were perfonned using nominal pipe dimensions and lengths. Please note that the KD 300 pumps were measured up to the top of the pump where the fill hole is heated; this is also the same basic elevation of the overflow lines currently installed.

As shown in the NCSAs fbr the Seal lixhaust Stations 1,2, and 3, which are available at the site for review, PoltTS is committed to limiting pump volumes fbr the Seal lixhaust stations. For the Area 3 Station, pumps have been analyzed safe to a maximum volume of 11.5 gallons; an overflow is required to limit the fill volume to 9.2 gallons if the pump volume exceeds 9.2 gallons. The actual volume of pumps in the Area 3 Station is 6.7 to 7.45 gallons. For Areas 1 and 2, pumps have been analyzed safe to a maximum volume of 33 gallons; an overflow is required to limit the fill volume to 27 gallons if the pump volume exceeds 27 gallons. The maximum volume of the new KT-100C pumps is 23.5 gallons and the maximum volume of the KD.300s, including the separators is less than 20 gallons.

The primary reason for requesting the Amet ' tent was to allow PoltTS to take credit for new pumps procured with total volumes less than those that required overflows. In addition, since the combination of the pump configuration and administrative controls (e.g. controls on type and movement of portable containers relative to the seal exhaust pumps, controls on enrichment allowed, etc.) provides double contingency thr the seal exhaust stations, no Technical Safety llequirements (TSits) would be required based on TSit 3.11.5 and SAll Section 5.2. For those pumps that did not have overflows originally installed, the actual maximum volume is less than the NCS A requirements.

Question No. 4:

Please provide a short technical discussion of the controls relied upon Ibr not exceeding the enrichment level (br each seal exhaust station of interest and a discussioWjustification of the reliability / availability of such controls.

GDP 98 0027 Page 3 of 7

Response

'lhe controls relied upon for enrichment are described in the NCSA/lis governing the operation of Seal fixhaust Stations for Areas 1,2, and 3 and are summarized as follows: The X 333 Iluilding limit is 3% enrichment and there is no tie from the X 333 Seal Exhaust Station to the X 330 Iluilding. The X 330 Arca 3 Seal lixhaust station is limited to 10% enrichment which is the maximum enrichment pennitted in the X 330 lluilding and it has no ties to the X 326 Ilullding. 'the X 330 Area 2 Seal Exhaust station is limited to 5% enrichment and has administrative controls specified in the NCSA to prevent tie in of the Area 2 station to areas with enrichment potentially exceeding 5%. lloundary block valves segregating the seal exhaust headers between Area 2 and Area 3 are closed, locked, tagged and verified. In addition, Area 2 is prohibited from providing backup seal exhaust capability for Area 3. The Area 3 station can be used to provide backup capability for the Area 2 station; however, controls for returning the Area 2 station to service aller such a condition are described in the NCSA for assuring that the Area 2 station is not valved in to any equipment with an enrichment potentially higher than 5%.

Qaqstion No. 5:

Please provide a discussion of the differences between the Stokes Penwalt Pumps and the Kinney pumps since the experimental data establishing the upper limit on uranium loading is based upon Stokes Penwalt pumps at the Paducah Site. Specifically, provide information concerning any DifTerential Pressure filter difTerences in addition to other pertinent information.

Resoonse:

Infonnation, consisting of Seal Exhaust Station flow schematics and pump technical description and vendor schematics, was received from the Paducah site System Engineer on the Stokes Penwalt pumps utilized in the seal exhaust stations at PGDP. Afler review of the information provided, there is no significant difference in the seal exhaust pump operation with respect to the potential for uranium contamination or the uranium concentrations that may be experienced in the pump oil. The seal exhaust stations are arranged with the alumina traps preceding the pumps. The pumps are rotating piston, positive displacement pumps utilizing oil to provide lubrication and a seal between the pump impeller and the pump wall. Each pump has an oil mist eliminator (filter) after the pump.

A comparison of the Stokes Penwalt pump information to the pumps used at Portsmouth did not identify any filter difTerences which would affect uranium loading of the pump oil.

Question No. 6:

Please provide justification for the extended range of applicability of the uranium loading graph provided to the NRC concerning uranium settling in oil over time for the range of 17 wt% to 40

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f.nclo$ule 1 GDp 98 0027 Page 4 of 7 wt% Also, provide a discussion / justification of the tune frame for settling considered in this graph and how such periods relate to settling over extended periods of time (i.e., days to weeks).

Iksponse; The enclosed graph provides a summary of data collected during pump experiments conducted at PORTS in which small amounts of UF,, were fed to a pump (2 grams / shot; I shot every two hours (br eight hours per day; a total of eight grams per day from day 1 through day $4) and oil withdrawn 2

fbr smnpling (25 cc oil / day; pump volume of 600 cc) was replaced with clean oil. The oil samples withdrawn were allowed to settle overnight (typically 16 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />) which resulted in separation of two phases (a free liquid and a colloidal suspension with the consistency of grease hereafter referred to as " sludge"). The oil and sludge were analyzed separately fbr uranium concentration and the graph shows the uranium concentration of oil, sludge, and the oil plus sludge average concentration Ihr each sample taken. No data was collected on the elTects of further settling beyond that mentioned above. For the test described above, the uranium remained suspended within the colloidal suspension and in the oil. As indicated by the data, there was little difTetence between the concentration of uranium in the oil and in the sludge. The increase in uranium concentration in the oil / sludge from day $$ to day 60 was due to a doubling of the UF fed to the vacuum pump during this period (16 grams UF,,/ day).

Questlanh042; Please provide a discussion /justificatloa of the heat of reaction temperature effects on expected viscosity rise and how this relates to maximum uranhun loading prior to pump failure (i.e., since pump shutdown relies upon the UF. oil reaction to increase the density and viscosity of the oil, the heat of reaction c1Tect on " holding down" the etrective viscosity rise must be considered when establishing acceptable / predictable control properties), please consider both a rapid addition of UF6 and a slow or sporadic UF addition over time. Also, please provide a discussion of the maximum uranium loading expected prior to pump failure for a hydrocarbon oil that has had viscosity breakdown due to normal and extended use prior to oil change, licspcmc; There has been no data specifica!!y collected identifying the heat of reaction temperature effects on viscosity rise in pump oil and how this relates to uranium loading prior to pump failure. Ilowever, an assessment of the potential clTects may be made based on the type of reaction involved and the GDP operating experience.

UF. is reactive with liquid hydrocarbons resulting in conversion of the hydrocarbon to perfluorocarbons. The type of reaction products generated is dependent on the strength of the fluorinating agent, the temperature of the reaction, and the influence of system parameters (e.g.

Enclosure !

ODP 98 0027 Page 5 of 7 reactant contact time, heat transfer capability, etc.) The reaction processes are believed to proceed through free radical formation, fluorine substitution for hydrogen, and hydrogen Duoride elimination.

The liF elimination can also result in either ring formation or olefm formation with some unsaturated hydrocarbon being found in the final reaction products. Paraffinic hydrocarbons may be converted to flunrocarbons of the same chain length in mild fluorinating reactions with the formation of dimerization and fluorine substitution in more vigorous reactions. A more detailed discussion of this topic is found in }UETO-143," Reaction of Uranium 11exafluoride with 11ydrocarbon Oil", which is available at the site. The anticipated effects of rapid addition of UF. versus a slow, sporadic addition of UF. is discussed below, in reviewing this discussion, it is important to note that the chemical traps which precede the seal exhaust pumps will remove the UF from slow, sporadic additions until the traps become saturated at which time degradation of the oil will occur fairly rapidly.

A rapid Mdition of UF. will likely result in signi0 cant formation of alkylfluorides and dimers in addition to oleOn formation. The alkylfluorides and dimers would result in a more rapid increase in viscosity than from predominant formation of olefins. According to the " hole theory" for explaining viscosity efTects, the formation of alkylfluorides and dimers would increase the viscosity of the oil more rapidly than would be the case with formation of the olefins. The effect is that the viscosity would increase by a factor of 10100 very quickly at a uranium concentration of 10 20 weight percent. The calculated viscosity increase for formation of monomer / dimer mixtures versus olefin formation is shown in Figure 1 (taken from K/ETO 143). While it is possible for an increase in temperature of about 20 degrees C to occur (pumps have water cooling jackets which would remove much of the heat of reaction), this would have minimal impact on the viscosity increase as shown in Figure 2 (taken from IUETO 143). Operating experience at PORTS and PGDP has indicated that for rapid addition of UF. to seal exhaust pumps, the maximum uranium concentration observed has been 30 weight percent; most of the time the concentrations observed at pump failure have been less than 23%.

A slow addition of UF would also result in a mixture of reaction products being formed. During the lower concentration stages of the reaction, it is likely that the reaction would be dominated by formation of the olefins. As the oil /UF. reaction progresses, fonnation of dimers and alkyl fluorides would increase due te occupation of the more reactive sites in the oil molecules. As a result, the viscosity increase would be more gradual.110 wever, as shown in Figure 1, the predicted viscosity increase of the mixture would still increase by about two orders of magnitude at a concentration of 30 weight percent. Further, as shown by the PORTS test where increments of oil were added to the vacuum pumps as samples were withdran (see response to Question 6), a steady state concentration of about 18 weight percent was achieved (although enough uranium was fed to the pump to have produced a concentration of about 35 weight percent). This data indicates that a uranium concentration of 30 weight percent provides a practical rtaximum for pump operation prior to shutdown due to viscosity increases. The efTect of temperature increase would be even less important for this scenario due to the cooling provided to the pumps; however, as noted for the rapid

0Dp 98 0027 Pagc 6 cf 7 scaction scenario, the cfTect of temperature would be minor relative to the overall viscosity increases that would occur.

No data has been collected that would indicate the potential reaction concentrations of oil that had a viscosity breakdown due to normal / extended use prior to a pump change. In general, for highly refined parafinnic oils such as used in the seal exhaust pumps, a viscosity breakdown would occur only through high temperature operation (which does not occur in these pumps) or by reaction with strong oxidizing agents (which is the reaction of concern with UF.). It would not appear likely for any reaction mechanism, other than those discussed above, to be of concern.

i

GDP 98 0027 Page 7 of 7 I,lST OF NITACllMENTS 1.

hiaterial Safety Data Sheet (htSDS) and product data for Kinney Products 2.

Material Safety Data Sheet (MSDS) for Pacemaker 11%68 Vacuum oil 3.

Material Safety Data Sheet (MSDS) and product data for Energol llLP ilD 32 Oil 4.

Material Specification for Portsmouth process lube oil 5.

Graph of uranium in oil loading from PORTS tests.

6.

1 igures 1 and 2 from K/ETO 143

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MNNr' m.to. (617) 828 9500 rx._.

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rAxNo. (617)828 5612 un n Centlement Attached are Product Data and Material Safety Data shoots for Kinney Products per your request.

DATA SHEETS PRODUCT -

PRODUCT MATERIAL SAFETY A.

Kinseal Yacuum Sealant D250-71 L._ J D250-72 i i

for pump assembly B.

Type A Vacuum Pump Oil D250-73 I

I D250-74 I

I std. for single stage pumps,.010 Torr C.

Super X Yacuum Pump 011 D250-75 L_._.I D250-76 I

i std. for compound pumps,.001 Torr D.

Kinlube Vacuum Pump Fluid D250-77 M

D250-78 1

i fire resistant phosphate ester E.

Kinney LT Vacuum Pump 011 D250-81 I

I D250-82 O

is sim!!ar to KV100 but is a mult!

viscosity o!! plus demulsifier additive for severe duty operation and/or low temperature starting.

F.

F50 Sillcone Vacuum Pump F1uld D250-83 I

I D2$D "84 i

i O.

OCR Vacuum Pump Fluid D250-87 !

D250-88 I

i highly rafined hydrocarbon H.

Kinney KV100 Vacuum Pump Oil

' D250-89 D250-90 *

!s similar to Type A with higher viscosity and R and O additives.

Now standard for all KT pumps I.

Kinney KV475 Yacuum Booster Oil D250-92 1

i D250-93 i

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. for blowers.

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Halovac 100/125 Fluid D250-94 i

I D250-95 i

i Halocarbon/chlorotrifluoroethylene K.

Fomblin Y-LVAC 25/6-16/6 D250-96 i

i D250-97 i

I perfluote polyather L.

UCON Fluid LB-300X

.D250-98 : L._.,1 D250-99 i

~I for brakefluid M.

Kinney XV-150 Vacuum Blower Oil D250-108 i J

D250-109 F ~~~T

, N.

. Mercury for McLeod Gauge-D250-115 L_

J O.

.LR o!! for Liquid Ring Pumps D250-119 L_

I D120-120 i i

Very truly yours, A. H. Bornemann aos W smeer emem m osoes rm. an ea ece. Chief Engi.n.e er. m e-vc m e m so.=. in

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1 Material Safety Data Sheet i

May be u*.ed to compty wra U.S. Department of Labor CDtA's Harard Cornmuni:stion Standard.

Ox:upatjenal Cafety and Health Administrat6eri 23 CTR 1910.1200. Standard mu::t be (Non-Mandatory Form) cormsted for spet:$c requve ments Fcrm 4 proved OMB No.1210 0072 icDemi (As u:nxt cri tatet erf th)

USER NO.

KINNEY KV-100 OIL Yacuum Pume Lubricant hv O!rur sosess am not umwm2 E any som is n:t anna-** or as wiiw a mwi. rv soace mu: os maws e mese. cw Section 1 u.wmers tume KINNEY D250-90 K!NNEY YACUUM COMPANY t.w w :y %.s tvunr 617-628-9500 m2ms vuncw, ax cry, im av & cam /

_MS TURNPIKE STREET Towrmetaumtw forinva a 617-828-9500 CANTON, MA 02021 Nay'4,1994 r+wre ce ns. (coomaa A. H. DORNEM ANN Gection il - lle='dous ingardients/ldentity infortnation Haramms comnerwa tr.cse cr ment wac common teamwsn ott= une o

omt* Pet.

AccM Tt.V r s.-m

% tccc,v a Chemient Family: Refined Paraffinic 8

SMG/M Patroleum tubo 011 011 Mtst/Vaeor Wolghted 8 HR.

Exnosure limit

__ _C A S NOS. 64742-54-7 None of the lubricant components are defined as hazardous in accordance with 20CFR1910.12 However, the exoosure limit coolies to the oil mist / vapor in the discharge of mechanical vacuum pumos. See Section VII-Other Precautions.

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__ For other physical oronerties and information, see Kinney Data Sheet D 250-89.

Section ill - PWC6.i ical Characterie%

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% casy (No. y At atmosehnele pressure 'F.

>400 vaar Pressure (erse ti94 0.88 At 20'C Mcit ng Point

<.010 vapor cw pr.. y tot Applicabl ew, n,

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toutalay n waw-we. n G)-

% by volume NIL N o a u... ano m ar Amber oil with mild odor.

Section IV - Five and t.'xpk=L i Hazard Data P.aso Pws (uamm "M

>450*F (COC) avnmanie umns O.9 va.

Enrvurano a'=$a 7.0 Foam, dry chemical powder, carbon dioxide.

so cw rn Ivana r,=-nos Wear self-contained breathing apparatus in confined area.

Use water to coolitre -exposed containers, ano to cisperse vapors trom unignateo follis.

Urutumi Fue and r W Hamams None. NFPA RATING: 1-H/1-F/O-R p

1 Section V - ReactMty Data I

my urmaow Corotreis to And m.,

incom:,atibihty Wafensts te he#vi STRONG OXIDANTS SUCH AS LIQUID OXYGEN AND CULORINE N W"'

SHOK2, CARBON MON 0XIDE AND DIOXIDE, SULFUR OXIDES H u:vuous v.nf oces Cuown to Aos Pyymeruaron W.:. N a Cocur x

Section VI - Health Hazard Data C&T4 y-at:

NTP7 W W@W MNW pg pg NO ikMe(s) of t/ttry:

Innesabon?

Shn?

Ingescon7 LGnsanc Sfttm ms EXPOSURE TO OIL HIST MAY CAUSE IRRITATION TO MAY CAUSE NAUSEA, STCHACE

'of Pstem as _op VAP_0H TN EXCESS AP ~

MYE CONTACT.' PROLONGED' 8't?MT?TvP FrT?r Ann WT?M TPPT?A? Ton on cPAteps.

LIMIT (SEE SECT VII)

MAY CAUSE_DREATffING SKTN CONTACT MAY LEAD IRRITATION,. HEADACHE AliD TO SKIN DISORDERS.

NAUSFA.

N M EMS

• REMOVE TO FRESH AIR REMOVE OILY CLOTHING DO NOT INDUCE VOMITING WASH WITH WATER AND C0AP.

FLUSH EYES WITU CLEAN MAttp

$,,neir[M; HOT KNOWN. IF IRRITATION PERSISTS SEE A PHYSICIAN Section Vil - Precautions for Safe Handling and Use Stora to Be Taken irl Case Mmenal is Mea'aed or Speal MECHANICAL CLEAN UP - USE OIL ABSORBANT (SPEPD DRY).

. wopus.t conTATvvp eTyvet_tto mn e CALLONS, HAX. 55 GALLON IsRUM. - NOT SUBJECT TO RELEASE REPORTS PER SARA TITLE III (313 )

FOR CIIP.MICALS IN 40 CFR372 Wa;netx=-='Ur.4 W. NOT FLUSH SPILLS OR USED OIL INTO DRAINS OR WATERNAYS. USE NORMAL IND IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Precautons to Be Taken gHarumng and bW STORE DELOW 120 P IN CLOSED METAL OR PLASTIC CONT ~ AINER. PREVENT M CONTAINER CLOSURE TO RETAIN PUYSICAL CHARACHERISTICS.

oew, ris!.stens VACUUM PUMP DISCEARCE MUST BE, FILTERED TO AVOID EXCESSIVE OIL USE AND OIL MISTN APOR CONCENTRATIO'l INSIDE PER OSHA AND OUTSIDE PER EPA.

Section VH1,. Control Measures Raowntry Protectat Ch4 hpe)

NONE WEEDED.FOR NORMAL USE t

Ventitaton Lecal Exhatat TO COMPLY WITH OIL LLST/ VAPOR LIMIT, PUMP FILTER DISCHARGE NITH ANY RESIDUAL SMOKE AND PRIMARILY VAPOR ODOR HAY NEED TO BE PIPED OUTSIDE, SUBJECT TO PUMP CAPACITY AND POOM VOLUME, WITH PROTECTION AGAINS,T ENTRY OF' RAIN OR I"g[ Y p'ROTECT AGAINST OIL TRANSFER SPLASHI USE IF SENSITIVE TO OIL u

h*' Pro 5ccW8 Cmo9 or Eqvipment NONE REQUIRED APPLY GOOD HOUSEKEEPING AND HYGIEW PRACTICE

= _ _. _ _.

..., CEOMETRIO SYMD01.S DWG. tD.

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CENERAI DESCRIPTION

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Kinney KV100 oil is used for single stage a:achanical vacuuza pumps with ultiaate vacuum specific ti Thir product is a b1}end of sjivent-refined paraffinic base oils with R and 0 and defoamer additives a ons of.010 torr.

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PI1YSICAL PROPEtTIES METUDD SPECIAI. INFORMATION 1.

Gravity API, 60*F 30 D287-2.

riash point, CDC

• F 430 D 92-

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1) This product. is not defined as hazardous in accordanc with 29CFR1910.120C'. Per OSHA Hazard r*n imication 3.

Fire Point, COC ~-

• F

,, 530 D 92-I.aw of Nove:mber,25,.1985, specipl handling or-4.

Pour point.

• P 10 D 97%

labeling precautions are not required.

However, 5.

Viscosity SUS at 100*F 500-525 D2161-(por OSHA 29 CPR Part,1910, Subpart 3, Toxic and 210*F.. 64 CST at 40*C 100 Dazardous Substances, Para. 1910.1000 Air Cont n'ainants) exposure to oil znist must be limited 6.

Viscosity index 95 D2270-to'n concentration of 5 NC/n3 for.an a hour

• time 7.

Color 2.0 D1500-weighted average.. The diischarge of a vacuum pump 8.

Neutralization No 0.05 D974-

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must be f11 tared to avoid excessive oil znist 9.

Cerrosion, 3 hrs - 212*f I D130-concentration.

10. Carbon residue, 1 max..

0.05 DS24-

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11. Em21sion test

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D1401-23

12. roam test A Material Safety Data Eheet is available on request DS92-(D-250- 90 ).

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13. Density, Ibs/ gal 7 34

14. Vapor pressure, zum hg

<.005 3)

(Kinney test) -

NFPA (Nat. Fire Prot. Assoc.) rating a 110

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4) This oil is approved as a lubricant with no food Sold in the following contal,n2r sizes:

I gallon - Part no. 203019-0000 5 gallon - Part no. 203020-0000

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55 gallon - Part no. 202991-0000

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.REF. PUMP TEST TAG PtO.

807919-A000 DensEMSCCS IN INCITES TOLERAttCES UhtisS OINEAWISE ntAT't.

initEss OTitERWISE SPECIFIED.

MiGU1.AR A I/2*

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SPECIFIEC FRACT70N DEC.

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11 250 9802 Product Name: Pacemaker HV 68 Vacuum Pump Oil Manufacturer's Name: Lt. Pine Scientific Company Emnrgency Telephone Number: 318-491 6215 Effective Date: None Listed 4

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TEL NUMEEA! AND ADDRE!!!

Q-/? 'J3 PHONE: 708/388-4030 FAX: 702/388-4084 LA PlHE SCIEHilflC COMPANY 1 *C.6 WEsif RN AV / PO BOX 780 (LUE ]SLAND IL 60406-0750 hl ~MD Yl$0Q

-: s T'rade Name:

Pacemaker HV-68 des.u d//r M.4.///77 M b Commodity Code:

34-105 Synonyms:

Lubricating 011 CAS Reg. No.:

64741 88 4 Citgo Index No. (CIN):

0246 Technical Coptar.t:. ( 9J ).),43 5..- 5.9J 3....

Medical Emerg'ency:

(318)~491'-6215 MATEPI AL )(AZARD EVALUATION (Per OSKA's Hazard Communication Standard (29 CFR Part 1910.1200])

(OHCS)

Health:

Non H.ir.a rdons. (OHrs)

Precautionary Statement:

None.

1. GENERIC COMFOSITION/ COMPONENTS Corepone n t s CAS #

'4 Hazard Data Refined Petroleum 6t?41-SB-4 ~ 100 Oral:

LD50(rat): >15g/kg 011(s)

Eye:

Practically Non-Irritating Skin:

Practically Non-Irritating 3

Ihln:

LC50/4H(rat): >$,000mg/m ND = No Data NA SCMeaAppTiegvMano coamoamon I

LAS/34-105

gcL II.

PHYSICA DATA Physical,H uard Classification (Per 29 CFR Part 1910.1200)

No Combustible No Oxidizer N

Compressed Gas NT Pyrophoric A

No Explosive E Reactivity No Flammable

{

Yes Stable NT~ Unstable No 0 i-c Peroxide Boiling Point, 760 mmHg, Heiting Paint, 'C(*F): NA eC(*F): 383(721) l Vapor Pressure, mmHg (25'C):

-1.5x10'5 Specific Gravity (H 0=1): 0.88 Solubility in H 0, % By Vt.: Negligible-2 2

Vape,r Density (Air:1):>1 Evaporation Rate

""1(Butyl Acetate =1)

<1

% Volatiles By Vol.:

Negligible pH of Undiluted Product:

ND Appearance and Odor:

Amber liquid, bland odor III.

FIRE AND EXPLOS10N DATA Flash Point, COC, 'C(*F): 232(450)

NFPA*

Flash Point, PH, 'C(*F):

228(441)

Health:

1 Fire Point, COC, 'C(*F):

266(510)

Flammability:

1 Reactivity:

0 Flammable Limits in Air, '/,Vol.:

Lower: ND Upper: ND Extinguishinghedia: CO, dry chemical, foam or water fog.

2 Special Fire Fighting Procedure:

None.

Unusual Fire or Explosion Hazard:

Water may cause frothing.

CCitgo assignment based on our evaluation per NFPA guidelines.

Hazard. Rating least-0; slight 1; moderate-2;. high-3; extreme-4.- '-

KD = No Data NA susWerJppA4 g6tt4cno conponanon LAS/34-10$

_ -. ~ ~ _.

. ~. -

.. - - _ ~ - =.. - -... - -. -.. -

,..g..........

g3 n

D J

IV.

RE_ ACTIVITY DATA i -

Stabilify:' Yes Stable

. No Uns. table

, p.

- Conditions Contributing to Instability: None.

- kncompatibility:

Strong oxidants. ',.;

f' i

Hazardous Decomposition Produch (thermal, unless otherwise specified):

CO, CO '

2 l

Conditiot.a Contributing to Hazardous Polymerization: None.

V.

SPILL OR LEAK PROCEDURES' 4

. : :--E.%C.edures.iI,Ha_ter,ial. is.. spill.ed4

...-d Remove sources of heat or ignition, provide adequate ventilation, contain leak.

Absorb small_ spills with suitable material such as rags, straw or sand.

Report spills as required to appropriate authorities.

i Waste Disposal:

r It is the responsibility of the _ user to deter:nine if the material is a hazardous'_ waste at the time.of disposal.

Check before disposing to be sure you are in compliance with all applicable laws and regulatioas.

4-t 4

e i

• - Protective measures "during-repair = and inaintenasce~'of' co'aninin'aiid"sciuipiiinti 4

- Referito(Section Vll - Special _ Protection Information.

Avoid prolonged contact with used oil, wash _ skin t'oroughly with soap and

.. water.

' ND = No Data-

. N# apePeenApprM 40FFMND CORPORANON LAS/31-105

, r, " '

[

l

.VIr HEALTH RAZARD DATA--

J Health,R.azgrd Classification (Per 29 CFR Part 1910.1200)--

4y No-Carcinogen.-

....No... Co rro s ive -

No Animal Carcinogen No

Irritant No Suspect Carcinogen No Sensitizer No Hutagen No Teratogen No-Highly Toxic j No-Target Organ No Tox'.a Product listed as carcinogen or potential carcinogen by

NTP N_ o_..

IARC No, OSHA N_o_,

OTHER No.

Toxicity Summary:

flightly toxic, 1 pt.. to 1 qt. is approximate lethal oral dose for 150 lb. human adult.

Major. Route (s)' of Entry:

Inhalation of fumes.

Acute Exposure Symptoms:

Inhalation:

1.ow. risk of inhalation. In enclosed spaces or whe; hot, vapors may. reach concen,,t. rations sufficient to cause drowsiness, dizzi-cause chemical pneumonitis.

Dermal Contect: Transient, slight irritation.

Eye

Contact:

May be-mildly irritating.

Ingestion:

Generally low toxicity. Very large amounts may cause generalized depression, headache, drowsiness, nausea, vomiting or diarrhea.

Small doses may produce irritation and diarrhea.

Chronic Exposure:

Prolonged and/or frequent contact may cause drying, cracking (dermatitis) or folliculitis, Repeated, excessive exposure to mists or fumes may induce pulmonary irritation or chronic bronchitis.

Other'Special

-Effects:

.None expected.

First Aid and Emergency Procedures for Acute Effect Inhalation:

Remove to fresh air. Respiratory support if necessary.

Seek medical aid.

Dermal:

Wash with soap'and water. Do not wear heavily contaminated clothing before laundstino Eyes:

Flush with large volumes of water. See physician if any complications arise.

--In ge s t io n ;

Do not induce vomiting. Seek medical aid.

Injection:

Subcutaneous injection is a medical emergency.

seek medical aid immediately.

- Notes to Physician:. Following...gewion, at i viscosity of about 350 SUS (100'F),

'the" risk -of-aapiration into-the lungs is remote,.but. cuf fed. tube, lavage is still recommended for large quantities.

Aspirated material may.cause chemio l pneumonitis or lipoid pneumonia.

Subcutaneous or intramuscular injection requires prompt surgical debridement.

If. not familiar with technique,. seek skilled advice.

ND :-No Data NA steNannApp}.(1 dA&No conPonAnon LAS/34-105 m

d' VII.

SPECIAL PROTECTION INTORMATION

s

• v-Ventilation Requiremerits: Ventilation is required when work place exposures exceed TLV.

Permitted Thres 'ald Agency:

OSHA OSHA ACGIH ACGIH Air Concentrations:

Year:

1972 1985 1985-86 1985-86 PEL TWA STEL Type:

{WA ppm:

3 rag /m :

5 5

5 10 Specific Personal Protective Equipment:

Respiratory:

Normally none required.

If high vapor or mist concentrations expected - use respirator approved for organic vapors and mists.

Ey-':

Safety goggles, or chemical splash goggles if splashing is anticipated.

Dermal:

Oil impervious gloves if f requent or prolonged contact is expected.

Other Clothing or Equipment: Wear body-covering work clothes to avoid prolonged

-- --- r 6r~repested exposure.

Launddr soiled work clothes before reuse.

. _. =

VIII. TRANSPORTATION AND SPECIAL PRECAUTIONS Hazardous Material Placard / Label: None.

Storage:

Stcre belos 150'F.

Do not apply high heat or flame to cor.tainer. Keep separate from strong oxidizing agents.

DOT Information:

DOT /UN Shipping Name:

Petroleum Lubricating Oil.

DOT Hazard Class:

Non-Hazardous.

DOT /UN Hazard Identification Number:

None assigned, DOT Shipping Container Restrictions:

None.

COT Placard:

None.

Caution:

Empty containers may contain product residue which could include flammable or explosive vapors.

Consult appropriate Federal, State and Local authorities before reusing,

~

reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this product.

Label:

Non-Ha:ardous.

(OHCS)

All statements, information, and data provided in this material safety data sheet cre believed to be accurate and reliable, but are presented without guarantee, warranty, or responsibility of any kind, expressed or implied, on our part. Users should make their own investigations to determine the suitability of the information or products for their particular purpose. Nothing contained herein is intended as permission, inducement or recommendation to violate any laws o-to Practice any invention covered by existing patents.

ND = No Data NA aus:;aengglet c0Mut.o u om w.

LAC /M-105

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...=.~..~.... -

ProcluctIn ormation BP ENERGOLS HLP-HD PRODUCT DESCRIPTION In the selection of an oil from this chart, Energol K1f HD Oils are premium quauty, progres* to heavier viscosity as operating pres.

antiwear, hydraulic oils designed to provide sures increase or nnge of temperature increases.

maximum pump Ufc and trouble free service in Whenever possible, refer to original equipment industrial and moblic hydraunc systems. They manufacturer's recommendation for viscosity possess proven protection against wear, out-standing e'xidation and thermal stability, and are gades.

abic to satisfy low ambient tempenture applics-tions in appropriate viscosity grades. These properties make them suiuble for vane, scar or

• Anti wcar Minimizes repairs and downtime.

piston type hydraulic pumps and motors.

• Anti rust Protects against rust and Energol HLP.HD Olls exceed all AGMA R & O Gear Oil requirements for the lubrication of cotrosion.

enclosed industrial gear drives and give excellent

. Antl.cxidant. Resists sludging and extends results on the F2G Test.

se M eeIdc.

• Anti-foam Supresses foam.

APPLICATION

• Law temperature fluidity Extends the Energo! HLP HD ous are recommended for many useful ambient ternpenture operating range uses in commercial, indusulal and construction

'YPul'd 28 I Il "';

CUALIFICATIONS

• Circ 21stmg systems

. Vicken,Inc.35VQ25A:

• Misc applicators y,2950 5 Mobile Hydraulic Systems

• Destings joumal, entifrictic'n 1286 5 Industrial Hydraulic Systems

• Electric motors

• Hagglunds Denison:

• Hydrauuc systems (including high pressure gy.0, gy.2 systeme

. CincinnatiMilacron:

• Genent hand oilinB P48; Energot MLP HD 32

• Machine tools P-69; Energol HLP HD 68 P70: Energol HLP HD 46

. Gear cases

• Texule machincrY

• Racine Hydraulles:

S 106: Petrolcum Hydrau3e Fluids Recommendations GENERAL RECOMMENDATIONS FOR HYDRAULIC SYSTEMS Pump Type EnergolHIP-HD j

Yanc, Gear and Axial 32,46 or 68

~

Piston Pumps ou Gear Pumps requiring 100 heavy oi!

Proven the World Over. Here for You Today.

02? e L C. !ha O! 4 :illrRC 1 W.Ub f V!M.Ab INu V:t 1:10T0VILLE

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TYPICAL PROPERTIES ENERGOL HLP-HD Test Method 32 46 68 100 220 Grade (ISO VG) 1 2

3 5

I AGMA No.

Gravity.* AP D287 31.4 30.1 29.6 27.5 27.2 Viscosity, Kin.:

D445 33.3 46.2 62.5 96.4 207.5 cStS40' C 5.5 6.7 8.1 11.0 18.2 cst 9i00* C Viscosity, D2161 171.6 283.6 323.7 501.9 1095 SUS S100* F 44.7 48.7 53.4 64.0 93.0 SUSW210* F Viscosity Indes D2270 100 98 97 96 96 Pour Point,' C(* F)

D97 34( 29)

-32( 26)

-29(-20) 20(-4)

-18(0)

Flash Point.' C(* F)

D92 205(400) 215(420) 227(440) 237(459) 261(502)

Color D1500 1.0 1.0 Lt.i L3.0 4.0 Rust Preventive Test DEES Procedures A&B,24 hr.

pass pass pass pass pass oxidation Test,:hr. D943 3000+

3000+

3000+

2000+

1500+

0.04 0.04 0.04 0.04 0.04 Zinc, wt.%

1 l

k ows SP OIL evenc.mp.n, J

200 Putne sque,.

cwew.on4ma S 4c0 824 722e

~~

MATERIAL

' SAFETY DATA SHEET e

Stores Number 11-815-3000 Product Name: Energol HLP HD 32 Manufacturer's Name: BP Oil Company Emergency Telephone Number: 800-321-8642 or 800-424-9300 Effective Date: 7/7/93 l

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BP OIL MATERIAL SAFETY DATA SHEET 51/1l 24-HOUR EMERGENCY ASSISTANCE GENERAL ASSISTANCE NFPA FIRE HAZARD SYMBOL BP America:800 3218642 216 441 8106 CHEMTREC Assist:800-424 9300

, A, U "',,*"'

3

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1.$$ght MSDS Number >

1311 Version #: 2

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'5"

MANUFACTURER / SUPPLIER: BP Oil Company ADDRESS: 200 Public Square, Cleveland, OH 44114 2375

.Jf d / f-J r e_

h%EfM30D.UO'IslDENTIEIGAHO'NMhiffsiEEiiddDEEN TRADE NAME:

ENERGOL HLP-HD 32 CAS NUMBER:.

M(XTURE SYNONYM (S):

LUBRICATING Oll; HYDRAULIC Olt CHEMICAL FAMILY:

HYDROCARBON MOLECULAR FORMULA: MIXTURE MOLECULAR WEIGHT:

ND PRODUCT CODE:

P 3398/3407 HIERARCHY: 050.060

1. i$gE3ODUCT#AZAIRD;

SUMMARY

digIM@@MWsMf@fs' W4EifNY5ME l

N HEALTH PoSSIBLE ASPIRATION HA"ARD IF SWALLOWED--CAN ENTER LUNG MAY BE IRRITATING TO THE SKIN, EYES AND RESPIRATORY TRACT REACTIVITY STABLE s

th$RWDU97MQuTg@ZMDJNiiO@M@ns's9 QpV@@@NNMMM@

x INGESTION:

Mty cause gastrointestir.al disturbances.

nmiting and diarrhea.

Symptoms may include irritation, nausea, Aspiration into lunga may cause pneumonitis.

SKIN:

SLIGHTLY IRRITATING.

Repeated or prolonged contact may result redness, itching, in defatting, oil acne, h2nted material may causeinflammation, cracking and possible secondary infection.

thermal burns. High pressure skin injections are SERIOUS Contact with MEDICAL EMERGENCIES.

Injury may not appear serious at first; within a few hours, tissue will become swollen, discolored and extremely painful (see Notes to Physician 7section).

'pyright @ 1980, NationalFire Protection Assoc., AfA 02269.

's reprinted materialis not the complete and otticial position of the NFPA nn tha tarwan as e..u:--*

. s. :-- '. -.

I

.s.

N N-EYE:

SLIGHTLY IRRITATINO. Contact with heated material may cause thermal burns.

HALATION:

k f e. 3 H:y cause respiratory tgac r.it a t. ion.

Exposure to high concentrations of dense oil tists may lead to oil pneumonia.

SPECIAL TOX1C EFFECTS:

IARC has detemined that there is inadequate evidence for the carcinogenicity of higbly-refined oils in humans and experi. mental animals.

(IARC Class--3).

NEIRSTlAlDMc8MMQWh#d@itiKESMWMfMMM$i!@#M?:l%Ms%#lF#5?-%%g INGESTION:

DO NOT INDUCE VOMITING BICAUSE OF DAUGER OF ASPIRATING LIQUID INTO LUNGS.

If spontaneous vcmiting occurs, monitor for breathing difficulty. Get immediate medical attention.

SKIN CONTACT:

Wash area of contact thoroughly Remove contaminated clothing and launder before reuse.

with soap and water. Get medict1 attention if irritation persists. Thermal burns require im: mediate medical attention. High pressure skin injections are SERIOUS MEDICAL EMERGENCIES. Get in:=ediate medical attention.

EYE CONTACT:

Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Get medical attention if irritation persists. Thermal burns require imediate medical attention.

INHALATION:

Get medical attention if irritation Rcmove affected person from source of exposure.

persists.

n - -...

. ~., - - -

$-..5NOTESKORHYSICI AN%%3MMEf5 MEW:ME:MGEEN###MM$.

--- - ~

-. -.MMMfW@M@Rsh l

A:piration of petroleum hydrocarbons may cause severe pneumonitis (oil pneumonia).

Vomiting should not be induced. In unc.onscious victims, use of ah andotracheal tube should b: considered if gastric lavage in undertaken. In case of skin injection, prompt debridement of the wound is necessary to minimi:e necrosis and tissue loss.

%@S$$ALERnOJ#@p$1WC@AIlOMs$s?$M. esnFM$nMi$5Ga@Wils@!!$Wj EYE PROTECTION:

Avoid eye contact with this material. Wear safety glasses or chemical goggles.

Provide en eyewash station in the work area.

SKIN PROTECTION:

Avoid skin contact. When working with this substance, wear appropriate chemical protective gloves.

Depending upon conditions of use, additional protection may be necessary such as face shield, apron, anacover s, etc.

RESPIRATORY PROTECTION:

If exposure limits are exceeded or if irritation is experienced, NIOSH approved respiratory protection shou'id be worn, ventilation and other forms of' engineering NO = No Data 1311 /Page 2 of 6 NA = Not Applicable

, s.

'~

4

.m

'c62tralo cro often the proferred me:ns for centro 11ing eEhateal exposures. Respiratory

• pr:tection may_be needed for non-routine or emergency situations.

@WM*@f@(S):Jg;]T[3K. gg,ggy,ggMQijQ@jM,@CK@Q94

?

B lLING POINT:

> als.33 c (425.oo F) 9 76o.oo HMHG SPECIFIC GRAVIT(:

0.s73 e 15.6/15.6 c:

MELTING POINT:

NA-

% VOLAllLG:

NEGLIGIBLE VAPOR PRESSURE:

NEGLIGIsLE EVAPORATION RATE (WATERS 1): VERY SLOW VAPOR DENSITY (AIR =1):

HE.AVIER VISCOSITY:

> 150 sus e to c

% SOLUBILITY IN WATER:

NEGLIGIBLE OCTANOldWATER PART: TION COEFFICIENT: ND POUR POINT: ND

-pH:

.ND=

APFEARANCE/ ODOR: LIQUID.

<) MiD N X$(U@ M hM R $ $ U 3 fs @ MMO+b sih$tdAN N O5bI Nitb 5 FLASH. POINT:

204.000 c (400 F)

AUTOlGNITION TEMPERATURE:

ND FLAMMABILITY _ LIMITS IN AIR (% BY VOL.) LOWER:

NA FLAMMABILITY LIMITS IN AIR (% BY VOL) UPPER:

NA

- BASIC FIREFIGHTING PROCEDURES:

- U:o water spray, dry chemical, foam or carbon dioxide to extinguish fire. Water or foam

'may cause frothing, with further application leading to boilover. Use water spray to cool firo-exposed containers, structures and to protect personnel. Use water to flush spills twry from sources of ignition. Do not flush down public sewers or other drainage systems.

_Expssed firefighters must wear HSHA/NIOSH approved positive pressure self-contained br cthing apparatus with full face mask and full protective clothing.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

combustible at high temperatures.

Irritating or toxic substances-may be emitted upon th:rmal decomposition.

' !EIb$kN5kN/;Il ;[h%$ilh. j@'t h(fkhMNy^,hdMkhhk.$

~

l STABILITY /INCOMPATIBILTY:

stable under conditions of normal use. Avoid contact with strong oxidizers.

HAZARDOUS REACTIONS / DECOMPOSITION PRODUCTS:

Combustion may produce oxides of carbon, sulfur, phosphorus and reactive hydrocarbons.

- MNMQNMWAlf NfgiMADON!@s@###$$@MfgMidfistin{py((Mi$$$$$)gyd

-- SPILL OR RELEASE TO THE ENVIRONMENT:

If your' facility or operatiog har an " Oil or Hazardous substance contingency, Pitn", activate its procedures, s

ND a No Data 1311 /Page 3 of 6

- NA = Not Applicable -...

s.,

D on chtuld b3

.-- Take imruediate steps to step cod contcin the cpill.

CO exercised regarding personnel safety and exposure to the spilled material.

-- For technical advise and assistance related to chemicals, contact CHDfTREC (800/424-9300) and your local fire department.

-- Notify the National Response Center, if required. Also notify appropriate ctate and local regulatory agencies, the LEPC and the SERC.

Contact the local Coast cuard if the release is into a waterway.

Emergency Action:

K cp unnecessary people away.

Keep ignition sources out of area.

Spill or Leak Procedure:

Small spills: Take up with sand or other Step leak if you can do it without risk.

ne combustibis absorbent material and place into containers for later disposal.

Large spills: Dike far ahead of liquid spill for later disposal.

Notification:

Any spill or release, or substantial threat of release, of this material to navigable v:ter (virtually any surface water) surficient to cause a visible sheen upon the water

~

as required cuct be reported immediately to the National Response Center (800/424-8802),

Failure to report may result in substantial civil and criminal by U.S. Federal Law.

Also contact the Coast cuard and appropriate state and local regulatory p:naltier.

cg:ncies.

WASTE DISPOSAL:

is not specifically listed as a hazardous This substance, when discarded or disposed of, v2cte in Federal regulationes however it could be characteristically hazardous if it is censidered toxic, cor.osive, ignitable, or reactive,according to Federal definitions (40 it could be desiguated as hazardous according to state Additionally, CFR 261).

This substance could also become a hazardous waste if it is mixed with or regulations.

Check 40 CFR 261 to determine whether it is a comes in contact with a hazardous vaste.

If it is a hazardous waste, regulations at 40 CFR 262, 263, 264, 268 and h :ardous waste.

Chemical additions, processing or otherwise altering this material may make 270 apply.

inaccurate or the waste management information presented in this MSDS incomplete, otherwise inappropriate.

The transportation, storage, treatment, and disposal of this wast'e material must be ccaducted in compliance with all applicable Federal, state, and local regulations.

S ARA TITLE 111 INFORMATION:

Listed below are the hazard categories for the Superfitnd Amendments and Reauthorization Act (SARA) Section 311/312 (40 CFR 370):

Pressure Hazard: - Reactivity Hazard: -

Delayed Hazard:-

Fire Hazard:

Immediate Hazard:

ADDITION AL ENVIRONMENTAL REGULATORY INFORMATION:

There msy be specific regulations at the local, regional or state level that pertain to this material.

1311/Page 4 of 6 ND = No Data NA = Not Applicable

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....D9EWiniSEMilniW6_, W. e u,uM3sise,,.?WEF#es

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@..REGut!ATORWINFOBMATION%rs.@.

All components of this product are listed on the TSCA inventory. All components of this product are listed on the Canadian DSL Inventory.

MSi?EGML9RECXOTiONS/SORRl!EM ENTALEI NEOR M ATIO NMHff@M@A@@@@lMMfM HANDLING / STORAGE:

store in tightly closed containers in cool, dry, isolated, well-ventilated area away from heet, sources of ignition and incompatibles.

Do not store ir unlabeled containers.

Do not eat, drink or smoke in areas of use or storage.

Uso good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Remove contaminated clothing and clean before reuse. Wash thoroughly after work using soap and water.

1 EMPTY CONTAINERS:

Empty containers may contain toxic, flammable / combustible or explosive residue or vapors.

Do not cut, grind, drill, weld, reuse or dispose containers unless adequate precautions cro taken against these hazards.

1. MTR AN$[QRTATIONifWWUljEM$NTSRDOMESTICjliAtjD)}M#$$$$$$55#$@MdMAEA@

D.O.T. PROPER SHIPPING NAME (49 CFR 172.101):

PETROLEUM OIL, N.O.I.B.N.

D.O.T. HAZARD CLASS (49 CFR 172.101):

NOT RECULATED UN/NA CODE (49 CFR 172.10.):

NOT REGULATED PACKING GROUP (40 CFR 172.101):

NOT REGULATED BILL OF LADING DESCRIPTION (49 CFR 172.202):

PETROLEUM OIL, N.O.I.B.N.

D.O.T. LABELS REQUIRED (49 CFR 172.101):

NOT REGULATED D.O.T. PLACARDS REQUIRED (49 CFR 172.504):

NOT RECULATED pg$1.N_G_R,.E. D~IENT_S../H,E_Ai!T..IEH. AZ..A_RD,!.!N EO,,RM A.. TIO.NnM_. A, _$ca. sMGM.gis@SE_

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-m COMPONENT l

CAS NO.

l l EXPOSURE LIMITS - REF.

Dietillates, hydrotreated 64742-54-7 40-55 5 mg/m3 TLV; 10 mg/m3 STEL (ACGIH) heavy paraffinic for oil mist, mineral y 5 mg/m3 PEL (OSHA) for oil mist, mineral 5 mg/m3 TWA; 10 mg/m3 STEL (NIOSH) for oil mist, mineral Solvent dowaxed distillate, 64742-65-0 40-55 5 mg/m3 TLv 10 mg/m3 STEL (ACCIH) heavy paraffinic for oil mist, mineral 5 mg/m3 PEL (OSHA) for oil mist, mir.aral 5 mg/m3 TWA; 10 mg/m3 STEL (NIOSH) for oil mist, mineral The OSHA Permissible Exposure Limits listed above were promulgated by OSHA in 1989. This standard was vacated by the U.S. court of Appeals for the Eleventh Circuit.

Exposure limits defined in specific chemical standards found in ND = No Data 1311 /Page 5 cf 6

' NA = Not Applicable

=.

• E 24',,

,29 CFR 1910.1031-1048 crc nst covered by this ruling end 1%cill carsreeable.

REVISION DATE: 07 Jul 1993 REPLACES SHEET DATED:

02 nov 1990.

COMPLETED BY: BP OlL HSEQ DEPARTMENT r

NOTICE: The information presented hereinis based on data considered to be acerate as of the date of preparation of this Material Safety Data Sheet However, no warranty or representaton, express or impGed,is made as to be accuracy or completeness of the foregoing deta and safety informaton, nor is any authorization given or lenpled to practice any patented invention vnthout a license, in addiden, no responsiblity can be assumed by wndor for any damage or injury resulting from abnormal use,imm any faaure to a&ere to recommended practices, or from any hazards inherent in the news of the, product i-e h

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BP Oil RECOMMENDED LABEL DATA ENERGOL HLP-HD 32 POSSIBLE ASPIRATION HAZARD IF SWALLOWED-CAN ENTER LUNGS AND CAUSE DAMAGE MAY BE IRRITATING TO THE SKIN, EYES AND RESPIRATORY TRACT B:fsre using this product, read the MSDS which contains more detailed. precautionary me cures, handling instructions and emergency procedures.

4RPR EC AUTlO N ARWST41EMENTSj@ti@@lSWhl@$i(Mids @n#M@sh;W4 hem y

Avoid prolonged or repeated contact with skin and clothing.

If contact is unavoidable, v:cr protective clothing, face protaction and gloves. Use with adequate ventilation.

Atter handling, wash thoroughly with soap and water.

1. dfilRSTIAlDh@;@SM1"We@M*2!s@sMMMMd;p@$@$$Md$$dsMy@MM%

INGESTION:

DO NOT INDUCE VOMITING BECAUSE OF DANGER OF ASPIRATING LIQUID INTO LUNGS.

If spontaneous vomiting occurs, monitor for breathing difficulty. cet immediat medical attention.

SKIN CONTACT:

Remove contaminated clothing and launder before reuse. Wash area of contact thoroughly with soap and water, cet medical attention if irritation persists.

Thermal burns require immediate medical attention. Nigh pressure skin injections are SERIOUS HEDICAL MIERGENCIES. Cet immediate medical attention.

EYE CONTACT:

Flush immediately with large smounts ef water for at least 15 minutes.

Eyelids should be held away from the eyeball to ensure thorough rinsing. cet medical attention if irritatin persists. Thermal burns require immediate medical attention.

INHALATION:

Remove affected parnon from source of expo ~ure.

cet medical attention if irritation p;rsists.

55B ASICjElR EsFIGHTING;P&OCEDU RESEilQMyi$$kf@h@[#;@ipspyii5sijdM@jffdg@@@ v Uco water spray, dry chemical, foam or carbon dioxide to extinguish fire. Water or foam may cause frothing, with further application leading to boilover. Use water spray to cool fire-exposed containers, structures and to protect personnel. Use water to flush spills cv:y from sources of ignition. Do not flush down public sewers or other drainage systems. Fxposed firefighters must wear MSKA/NIOSH epproved positive pressure self-contained breathing apparitus with full face mask and full protective clothing.

9 +.. bkSF!!!:LRORAEAK P.ROCE. DURE?b FIW3A M >' QW54RMFO?dlWiiW"Ef?WCMWER R.N$j i stop leak if you can do it without risk. Small spills: Take up with sand or other i noncembustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. figTR4fjS PORTATION !R EOUIR EMENTSjEnWSMARNWM%FPMWHMMWNM%Bnyp7@ BILL OF LADit4G DESCRIPTIOt1(49 CFR 172.202): PETROLEUM OIL, N.O.I.B.N. 0.0.T. LABELS REQUIRED (49 CFR 172.101): TOT REGULATED @dEMf!T?/iC.ONTAINER.S?$%Meyd&CiM+rXc iWRMiMPWW6M 7ti9ip6?@BW ATTENT:cui E=pty containers may contain toxic, flamable/ combust (bis or,axplosive residise or vapora. grind, drill, weld, rouse or dispose containers un?.t,as adequate precautions Do not cut, cro taken against these hazards. CBSERVE ALL PRECAUTIONARY LABELING. d@J N G R E DJ ENTS"INiiOR MATIO N kui!R$9MMEEWE! MENS #MIGMSNW#NM+W The following component (s) of this product are listed in accordance with right-to-know 1cvs Component (s): CAS Number: Distillates, hydrotreated 64742-54-7 heavy paraffinic solvent dowaxed distillate, 64742-65-0 heavy paraffinic [hMMANUFACIU.RER D,E]%IIIS@@$2%$$$$@M$$$$M46W@gM$@@$W663@5$$$$$ BP Oil Company 200 Public Square, Cleveland, OH 44114-2375 FOR ANY CHEMICAL EMERGENCY CALL CHEMTREC (600) 424 9300 Cencral Assistance: 216-441-8106 Iseue Date: 07-jul-1993 v NO = No Data 1311 /Page 2 of 2 NA = Not Applicable

PORTSMOUTH GASEOUS DIFFUSION PLANT Material Specification PROCESS LUBE OIL MS-6.1 - MR 11-Rev.1 Prepared by: N Approved by:MO. - Date: f*l/- PR f/2-/,d 2-Effective Date: Procedure Abstract: In Hand: Yes _ No.L Safety Related/ Safety System .,x Quality Related Nonquality Related _ Temporary / Expiration Date Record of Changes Change Letter Affected Page(s) Effective Date Expiration Date i l Next.3 -year review required no later than: 9/Z//95 ' Date Xhe&3

MARTIN MARIETTA ENERGY SYSTEMS, INC. PORTSMOIJrli GASEOUS DIFFUSION PLANT 4 MATERIAL SPECIFICATION Number: MS-6.1 - MR 11 Orig. Date: 8/1/80 Revised Date: 8/26/92 Reviewed Date: Reviewed By: Page 1 of 4 TITLE: PROCESS LUBE OIL TABLE OF CONTENTS 1.0 SCOPE 2.0 RANGE OF OPERATING CONDITIONS 3.0 REQUIREMENTS 4.0 MISCIBILITY 5.0 CONTAINERS 6.0 BASIS OF ACCEPTANCE 7.0 INSTRUCTIONS APPROVALS: kOk' pd' 1((2 Prepared By: Cascade Operations fkeL-or inc Maintenance 4 Appr 'IM Technical Services c / 916-92.- Environm tal on 01 X7tOO)

Number: MS 6.1 MR 11 - Page 2 of 4

Title:

PROCESS LUBE OIL 1.0 SCOPE This specification covers one grade of lubricating oil to be used as makeup oil in large plant systems to lubricate axial flow and centrifugal compressors. In addition, it will be used in the respective compressor drive motors. 2.0 RANGE OF OPERATING CONDrrIONS The systems in which this oil will be used will be continuously circulating gravity feed lubrication systems with 5 to 10 psig pressure at the bearing inlet. 'E The inlet temperature o,f the oil to the bearings shall be a maximum of 12 F and the outlet temperature should not exceed 180'F. 4 The ambient temperature condition of the lubrication system will be controlled between 80'F and 130*F. ~ The speed of the units vary but will not exceed 12,000 rpm. 3.0 REQUIREMENTS Each oil shipment must be certified to meet the following general and specific requirements, This material shall be a premium quality, highly refined and filtered, W Em strength petroleum oil. It shall be free of contaminants, rust, asphaltenes, resins, soaps, solids, semi-solids, abrasive matter or other sediment, and foam inhibited, and shall be chemically stable under normal operating conditions. The vendor shall provide written certification that the product contains no PCBs.

1. Nature of base oil 100% mineral

2. Type of base oil Paraffinic

3. Gravity: API at 60*F; ASTM D287 (latest revision) 29-31

4. Viscosity: SSU 100*F; ASTM D445 (latest revision) 290-360

- 5. Viscosity:- SSU 130'F; ASTM D445 (latest revision) 130-170

6. Viscosity: SSU 210'F; ASTM D445 (latest revision) 50-56

7. Viscosity: Index: Min., Dean & Davis or ASTM D2270 (latest 85 revision)

- 8. Color: Max.; ASTM D1500 (latest revision) 2 9.- Flash Point: 'F Min.; COC; ASTM D92 (latest revision) 440 - X7HP&3

Number: MS 6.1 - MR 11 Page 3 of 4

Title:

PROCESS LUBE OIL

10. Fire Point: 'F Min.; COC; ASTM D92 (latest revision) 500

11. Pour Point: 'F Max.; ASTM D97 (latest revision) 10

12. Carbon Radtse: % Max.; Ramsbottom ASTM D524 (latest 0.08 revision)

13. Neutralization Number: mg KOH/ gram oil: Max.; ASTM D974 0.10 (latest revision)

14. Corrosion n.

Copper strip test; 3 hours at 210'F, ASTM D130 (latest Pass revision) (no or very slight tarnish) b. Distilled water and synthetic sea water: ASTM D665 (latest Pass revision) (No nistf

15. Foaming characteristics; ASTM D892 (latest revision), Max, of 25 Pass mL at both 75' and 200'F, no foam after 10 min. settling in each test.

16. Oxidation test; ASTM D2272 (latest revision), minutes min.

205

17. Aniline Point: 'F Min.; ASTM D611 (latest revision) 200

18.

• Phenol Type Oxidation Inhibitor: % max 0.7

19. Ash: %; ASTM D874 (latest revision)

.005

20. Sediment: %; ASTM D96 (latest revision)

Nil

21. Water content: clear, bright, and hot cup negative.

Pass

22. PCB content (Electron Capture Detector Gas Chromatograph).

Pass Nondetectable,

• It is preferred that no oxidation inhibitor other than'the phenol type inhibitor be used in the oil. If any other inhibitor is added, it shall be identified to the buyer so that its compatibility to the buyer's systems can be evaluated.

4.0 MISCIBILITY For purposes of evaluation, miscibility is defined as a homogeneous mixture of the subn.itted oil with a composite sample" of the presently used oil. The following tow tests will be performed by the buyer to determine whether the oil is miscible with the presently used oil. X7te&3

Number: MS-6.1 - MR 11 Page 4 of 4

Title:

PROCESS LUBE OIL 4 J.1 A 1:1 sample mixture of the new oil and the composite sample shall be thoroughly mixed and shaken at 150'F, and given a visual inspection to ensure a homogeneous i - mixture. The sample mixture shall then be tested for color according to D1500, latest revision. The color number result should not be greater than a test result taken on the composite sa.mple alone. 4.2 A precipitation test, as described under ASTM D91, latest revision, shall be conducted on a 1:1 sample mixture of the new oil and the composite sample. The result of this i test should not exceed 0.05 mL. 5.0 CONTAINERS The following containers will be suitable for this material: Tank trucks. 4 6,0 BASIS OF ACCEL'I'ANCE The material must be easily identifiable as to brand name and number, specification number, and purchase order number. Any material which fails to meet the requirements of this specification is subject to reject'.on and return to vendor at the vendor's expense. For the disposition of material which does not pass the specifications, see Testing Specification MS-1.1-TR 6, or latest revision. 7.0 INSTRUCTIONS Please provide complete comparative data including brand names for your product. Consideration of material shall depend on completeness of comparative data provided. 4 NOTE: The Specific and General Requirements are unpublished Business Confidential specifications which shall not be advertised by name. ~ Stores No: 44-L5-4800 /I-8/5- @ O0 Requesting Department: 810

• • The composite sample shall consist of a mixture of one pint of oil from the drain tank (s) of each unit in operation.

W XH43 -

~ W4070ErTe T9: Wa vsJ v40 ouv suwu wt@Atrwwieuwst Ln'a ~ te%x r = URANIUM in OIL Actualvs.ncoretical 35 ,0* 30 ,e J 25 y w M41*%tds f 20 u S }l g% 0 Sg 60 70

• • P c Numy,f 30 O

10 20 l + Uin OIL & SLUDGE _,_ U in OIL _e_ U in SLUDGE + Theor, U ss-model Note: Wi h sample no. 55, UF6 increased from 8 to 16 grams /d t i

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_._...... _. _ _.. ~ _ _. _ _-._ _. Ld.120 (8 30-96)- REGULATORY CORRESPONDENCE REVIEW AND CONCURRENCE i-Summary (Log 4 Me kc;ect) USECfDRIS-DocketNo:70-7002 Resco.m ~ Letter / Report Nc; l RoguestforAdattionaunformatiothCartificateAmendmentRaquest-Dslation.of Seal (Serial or Event) [ Exhaustfump.OverflowsJaBuildingsle330_andX-333 - GDP 98-0027 A pv Preparer: A. Stone /M Smith Due Date: 2/20/98 0 Notary Required O Fee Reauired l Closed Commitments (List BPS ts): l I i Area of Comments Organization Review Concurrence Signature /Date Review

• O Administrative Support Manager O Custamer Service / Product Scheduling Mgr O Engineering Manager 0 Enrichment Plant Manager l

0 Environmental. Safety and Health Manager j O Maintenance Manager t l 0 Materials Management Manager n Operations Manager O Plant Shift Superintendents Manager O Production Support Manager j O Safety, Safeguards, and Quality Managst j O S'te and Facilities Support Manager ' O Training & Procedures Manager l 0 Work Control Manager O Legal Counsel O L 0 Nuclear Regulatory Affairs Manager O GeneralManager O USEC Nuc Reg Assurance & Policy Mgr ~ I W USEC Vice President. Production // w1 d# # O USEC Executive Vice President g .e/, 4#LLt

• AREA OF REVIEW:

LEFT MARGIN SIDESARS ON THE CORRESPONDENCE INDICATES AREAS OF ORGANIZATIONAL REVIEW RESPONSIBILITIES. d ; Organization supplied input verify and concur that the information contained in the document is complete and accurate in all material respects to the best of your knowledge. O Organisation concumnc..ith information i. required. i Final Sent to the Regulator (Date/ initials): Intemal Distribution Completed: 1 4 c. ei+L -y w -m y.4y-.. ,4 7-7--4-em ,m y w-Ty .w t-- w w

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