ML20108C585

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Radioactive Effluent Release Rept 1995 FPC Crystal River - Unit 3
ML20108C585
Person / Time
Site: Crystal River Duke Energy icon.png
Issue date: 12/31/1995
From:
FLORIDA POWER CORP.
To:
Shared Package
ML20108C579 List:
References
NUDOCS 9605070039
Download: ML20108C585 (15)
v • d • e


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RADI0 ACTIVE EFFLUENT RELEASE REPORT '

1995 1

FLORIDA POWER CORPORATION CRYSTAL RIVER - UNIT 3 Facility Operating License No. DPR-72 Docket No. 50.-302 Prepared By: h,[ S CE>c)O Chemrad Specialist JI Approved By: /r/ [ /

~ Manager, Nuclear themistry' Date: ffD4ffd

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9605070039 960430 PDR ADOCK 05000302 R PDR

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CONTENTS i.

Introduction ... .. . . ... .................. 1

[ . Tabular Data Summa'r tes  !

4 Gaseous Eff1sents - Quarters 1 & 2 ... .. . . . .. 2 i- Gaseous E'f1sents - Quarters 3 & 4 ... . . .... 4 l Liquid Effluents - Quarters 1 & 2 .. . ..... ..... 6  ;

, Liquid Effluents - Quarters 3 & 4 . . ..... ......... 9 A ,

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4 Radwaste Shipments .. .. . .. . ... .... .. .. 12 l

[_ Unplanned Releases ......... .,.. . .. . ........ 13 )

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. Radioactive Waste Treatment Systems . .... ........ . 13 f Environmental Radiological Monitoring Program . . . ... 13 i

j Effluent Monitor Instrument Operability , . . .. ....... 13 l a

1- ODCM & PCP Changes .. .... .. . ...... ...... 13.

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INTRODUCTION i

This report is submitted as required by ODCM section 6.5. The following information is included:

A summary of the quantities of radioactive liquid and gaseous effluents and solid i waste released from the plant.  !

A Ilst and description of unplanned releases to unrestricted areas. l t

A description of any changes to the: )

i Process Control Feogram (PCP), and i

Offsite Dose Calculation Manual (00CM).

significant changes to any radioactive waste treatment system. l A list of new dose calculation location changes identified by the annual land-use census. ,

Information relating to effluent monttors or required supporting instrumentation i being inoperable for 30 or more days. I l

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. TABLE 1 EFFLUENT AND WASTE DISPOSAL REPORT - 1995 GASEOUS EFFLUENTS - SLB01ATION OF ALL RELEASES I

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Unit Quarter Quarter Est. Tetal 1 2 Erro- %

l A. Fission and Activation Gases. l l

1. Total Release Ci 3.48E+00 2.02E-01 30 ,
2. Average Release Rate For Period uti/sec 4.48E-01 2.56E-02
3. Percent of Technical Specification Limit  % 3.00E-03 2.79E-04 B. Iodines
1. Total lodine - 131 Ci 0.00E+00 0.00E+00 3E i
2. Average Release kate for Period uCi/sec 0.00E+00 0.00E+00
3. Percent of Technical Specification Limit 1 0.00E+00 0.00E+00 f C. Particulates*
1. Particulates with Half-Lives > 8 Days Ci 4.22E-07 0.00E+00 33
2. Average Release Rate For Period uti/sec 5.42E-08 0.00E+00

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3. Percent of Technical Specification Limit  % 2.39E-02 1.90E-02
4. Gross Alpha Radioactivity C1 0.00E+00 5.80E-08 D. Tritium l
1. Total Release Cl 7.39E+00 5.95E+00 33
2. Average Release Rate for Period uti/sec 9.50E-01 7.57E-01
3. Percent of Technical Specification Limit  % 2.39E-02 1.90E-02
  • The sum of the particulates reported on this page may be less than the sum from Table 2, as Table 2 includes all particulates, while this table only those with half-lives greater than 8 days.

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i TABLE 2 j EFFLUENT AND idASTE DISPOSAL REPORT - 1995 I

GASEOUS EFFLUENTS - GROUND LEVEL RELEASES i

'i CONTINUOUS MODE BATCH MODE l Nuclides Released l Unit Quarter 1 l Quarter 2 Ouarter 1 l Ouarter 2 i

j 1. Fission Gases l Argon-41 C1 Krypton-85 C1 2.99E-01 1.56E-01

Krypton-85m C1
Krypton-87 C1 j Krypton-88 Ci j Xenon-131m C1 5.79E-03 4

Xenon-133 C1 1.91E-01 4.51E-02 Xenon-133m C1 2.46E+00 1.05E-03 2 Xenon-135 C1 5.27E-01 1.54E-04

j. Xenon-135m Ci Xenon-138 Ci l

1 Total for Period Ci 2.99E+00 0.00 4.97E-01 F.02E-01 4

i 2. Jodines t

l lodine-131 C1 j lodine-132 C1 lodine-133 Ci lodine-135 C1 f Ci

! Total for Period 0.00 0.00 0.00 0.00 4

3. Particulates Zine-72 Ci Cobalt-58 C1 Cobalt-60 C1 Strontium-89 Ci Strontium-90 Ci Yttrium-93 Ci Tin-113 C1 Cadu t um-113m Ci Indium-113m C1 Cesium-134 C1 Ces tun-137 C1 4.22E-07 Cesium-138 Ci Barium-139 Ci tanthanum-142 Ci Cerium-143 C1 Cerium-144 C1 Rhenium-188 Ci Total for Period C1 4.22E-07 0.00 0.00 0.00 3

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  • TABLE 3 J

j EFFLIENT AND WASTE DISPOSAL REPORT - 1995 l

GASEOUS EFFLUENTS - $1BGETION OF ALL RELEASES l Unit Quarter Quarter Est. Total  !

3 4 Error % ,

A. Fission and Activation Gases

1. Total Release Ci 1.27E+00 1.35E+00 30
2. Average Release Rate For Period uCi/sec 1.59E-01 1.70E-01
3. Percent of Technical Specification Limit  % 1.78E-03 2.26E-03
8. Iodines  ;
1. Total todine - 131 Ci 0.00E+00 0.00E+00 30
2. Average Release Rate for Period uti/sec 'O.00E+00 0.00E+00
3. Percent of Technical Specification Limit  % 0.00E+00 0.00E+00 4 C. Particulates*

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1. Particulates with Half-Lives > 8 Days C1 1.70E-06 1.49E-06 30
2. Average Release Rate For Period sci /sec 1.51E-01 1.88E-01 l
3. Percent of Technical Specification Limit  % 1.14E-02 1.43E-02
4. Gross Alpha Radioactivity Ci 5.76E-09 0.00E+00 D. Tritium
1. Total Release Cl 3.51E+00 4.19E+00 30
2. Average Release Rate for Period uti/sae 4.4?E-01 5 28E-01
3. Percent of Technical Specification Limit  % 1.14E-02 1.43E-02
  • The sum of the particulates reported on this page may be less than the sum from Table 1 2, as Table 2 includes all particulates, while this table only those with half-lives i greater than 8 days.

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TABLE 4 EFFLUENT AND WASTE DISPOSAL REPORT - 1995

) GASEOUS EFFLUENTS - GROUND LEVEL RELEASES i

l CONTINUOUS MODE' 8ATCH MODE J

! l Nacitdes Released l Unit Quarter 3 l Quarter 4 Quarter 3 I Quarter 4 t

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1. Fission Gases

! i Argen-41 Ci Krweton-85 Ci 5.17E-07 1.62E-01 j Kr y: ton-85m C1 2.32E-07 l Kry: ton-87 C1 Krv ton-88 Ci j Xe :n-131m C1 1.90E-02 Xe*:n-133 Ci 6.43E-01 5.53E-07 1.89E-01 5.27E-01 Xe*:n-133m Ci 1.25E-03 Xe en-135 C1 4.32E-01 6.41E-01 2.18E-03

Xe*on-135m Ci Xeron-138 Ci i

Total for Period Cl 1.08E+00 6.41E-01 1.90E-01 1.11E-01 l

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I 1 4 2. lodines i locine-131 Ci l loatne-132 Ct Incine-133 Ci

} lootne-135 Ci l

Tctal for Period Ci 0.00 0.00 0.00 0.00 I

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3. Particulates t

Zime-72 Ci l Ci 1.32E-06 i Coca lt-58 l

Cetait-60 Ci Strontium-89 Ci Strontium-90 C1 Yttrium-93 C1 2.89E-09 i itn-ll3 Ct 9.01E-07 Cassium-113m C1 1.69E-07 Indlun-llha C1 1.18E-06 {

Cesium-134 C1 Cesium-137 C1 2.98E-07 Cesium-138 C1 Barium-139 C1 2.53E-06 l Lanthanum-142 C1 Cerium-143 Ci 4.80E-07 I

Cerium-144 C1 R henium-188 Ci Total for Period Ci 2.37E-06 4.34E-06 0.00 1.72E-07

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- TABLE 5 EFFLlH T AND WASTE DISPOSAL REPORT - 1995 LIQUID EFFLUENTS - Sup04ATION OF ALL RELEASES Unit Quarter Quarter Est. Total 1 2 Error %

A. Fission and Activat :n Products t

1. Total Release (Not *9cluding tritium. C1 1.43E-02 1.10E-02 25 i gases, alpha) l
2. ~ Average diluted co :entration during #Cl/ml 4.51E-11 3.23E-11 period
3. Percent of applicat'e Limit  % 2.00E-01 1.74E-01 B. Tritium
1. Total Release Ci 5.95E+01 1.72E+02 30
2. Average diluted cor:entration during uCi/mi 1.87E-07 4.98E-07 ,

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3. Percent of applica:'e Limit  % 1.87E-03 4.98E-03 C. Dissolved and entra ned gases 1
1. Total release C1 3.31E-02 1.35E-02 25 l
2. Average diluted co-centration during #C1/m1 1.04E-10 3.96E-11 period
3. Percent of applica:?e Limit  % 5.20E-05 1.98E-05 D. Gross alpha radioactivity l
1. Total Release Cl 1.05E-04 2.96E-05 30 E. Volume of Vaste re' eased (prior to dilution)  !
1. Batch and Continuo.s Modes Liters 5.59E+06 1.09E+07 10 F. Volume of dilution mater used during period
1. Batch and continuo.s Modes Liters 3.17E+11 3.41E+11 10 6

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EFFLUENT AND WASTE DISPOSAL REPORT - 1995 I LIQUID EFTLUENTS i

CONTINUOUS MODE BATCH MODE Nuclides Released Unit Quarter 1 Quarter 2 Quarter 1 Quarter 2

Sodium-24 C1 Chromium-51 C1 5.85E-05 Manganese-54 Ct 6.51E-05 3.32E-05 l 2. 0EE-05

, Mancanese-56 Ci 4

Iron-55 C1 8.94E-03 7.94E-03 Iron-59 Cl Cobalt-57 C1 3.15E-06 3.28E-06 Coba lt-58 C1 1.21E-03 2.82E-04 Cobalt-60 C1 1.02E-03 8.28E-04 Zinc-65 Ci Zine-72 Ct Strontium-85 C1 1.75E-06 4.60E-06 Strontium-89 Ci 8.53E-05 1.67E-05 Strontium-90 C1 1.05E-05 4.89E-06 j Strontium-92 C1 1.17E-04 1.35E-04 j Yttrtym-92 C1 Yttrium-93 C1 Bromine-82 Ct Niobium-95 C1 2.20E-05 1.83E-05 Niobium-97 Cl 5.95E-04 6.77E-04 Z ircon t um-95 C1 6.55E-06  ;

Zirconium-97 Ct 7.05E-06 1.20E-05 1 Molybdinum-99 C1 2.06E-04 T echnet ium-99M C1 4.32E-04 4.22E-05 Technetium-101 Cl Ruthenium-103 Cl Ruthenium-106 Cl 7.09E-05 2.91E 06 Stiver-110m C1 3.45E-04 4.04E-04 Tin-113 Cl 1.31E-05 Indium-113m Ci ., 1.88E-05 Cassium-113m Ct Antimony-122 Ci 7.125-06 5.12E-07 Anttmony-124 Ct 1.3Pi-05 Antimony-125 C1 2.3~4E-04 7. 64E -05 Tellurium-129 Ct Tellurtum-132 Ct lodine-131 C1 1.f 8E-05 1.73E-06 lodine-132 C1 2.40E-05 lodine-133 C1 1. ( 9E-05 2.60E-05 lodine-135 Cl 1.85E 05 Cesium-134 C1 1. 26E-04 2.61E-05 Ces t um-137 C1 5.15E-04 2. 00E-04 Cesium-138 C1 2. 2 DE-05 Bartum-139 Cl Barium-140 Cl 8.37E-06 8.29E-06 Lanthanum-140 - C1 1.75E-04 Cerium-143 C1 1.83E-05 Cerium-144 Ct 2.15E-05 R hen t um-188 C1 3.37E-05 Neptuntum-239 C1 5.17E-07 Total for Period Ci 0.00 0.00 1.43E-02 1. ! DE-02 7

TABLE 6 (CONTINUED)

EFFLUENT AND WASTE DISPOSAL REPORT - 1995 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Otssolved &

Entrained Gasses Unit Quarter 1 Quarter 2 Quarter 1 Quarter 2 Argon-41 C1 Krypten-85 Cl 4.10E-04 1.08E-03 Krypton-85m Cl 1.07E-05 Krypton-87 C1 Krypton-88 Ci Xenon-131m Cl Xenon-133 C1 3.03E-02 1.20E-02 Xenon-133m C1 3.90E-04 6.69E-05 Xenon-135 C1 2.03E-03 4.05E-04  !

Xenon-135m Ci Total for Period Ci 0.00 0.00 3.31E-02 1,36E-02 l Tritium l C1 l 0.00 l 0.00 l 5.95E+01 l 1.71E+02 l I

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TABLE 7 EFFLUENT AND WASTE DISPOSAL REPORT - 1995 LIQUID EFFLUENTS - $LBMATION OF ALL RELEASES tinit Quarter Quarter Est. Total 3 4 Error %

A. Fission and Activation Products

1. Total Release (Not including tritium, C1 8.35E-03 1.66E-01 25 gases, alpha)
2. Average diluted roncentration during uti/mi 2.42E-11 4.83E-10 period
3. Percent of applicable Limit  % 1.78E-01 6.43E+00 B. Tritium
1. Total Release C1 1.87E+02 3.87E+02 30
2. Average diluted concentration during gCl/ml 5.42E-07 1.13E-06 period
3. Percent of applicable Limit  % 5.42E-03 1.13E-02 C. Dissolved and entrained gases I ,
1. Total release Ci 3.04E-02 5.88E-02 25
2. Average diluted concentration during pC1/ml 8.83E-11 1.71E-10 period
3. Percent of applicable Limit  % 4.42E-05 8.55E-05 D. Gross alpha radioactivity ,
1. Total Release Cl 5.09E-05 2.70E-05 30 E. Volume of Waste released (prior to dilution)
1. Batch and Continuous Modes Liters 6.40E+06 5.37E+06 10 F. Volume of dilution water used during period
1. Batch and continuous Modes Liters 3.45E+11 3.44E+11 10 i

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i EFFLUENT AND WASTE DISPOSAL REPORT - 1995 LIQUID EFFLUENTS {

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CONTINUOUS MODE BATCH H0DE f Nuclides Released Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 1 Sodium-24 C1 5.14E-06 1.35E-05

Chromium-51 C1 1.23E-06 j Manganese-54 C1 2.00E-04 4.96E-03 j Manganese-56 C1 7.00E-06 Iron-55 C1 8.67E-04 1.29E-03 l Iron-59 Ci '

l Coba lt-57 C1 2.92E-04 j Coba lt-58 C1 5.79E-04 2.51E-03 Coba lt-60 C1 3.63E-02 8.96E-02 Zinc-65 C1 Zinc-72 Ci Strontium-85 Ci 3.32E-07 Strontium-89 Cl '

Strontium-90 C1 8.28E-06 4.77E-06 Strontium-92 Ci 1.43E-04 Yttrium-92 Ci i Yttrium-93 C1 2.19E-04  ;

Bromine-82 Ct Niobium-95 C1 3.58E-05 3.05E-05 Niobium-95m C1 3.07E-05 Ntobium-97 C1 8.05E-04 Zirconium-95 Ci Zirconium-97 C1 4.91E-06 1.85E-03 Molybdtnum-99 C1 Technet i um-99m C1 8.67E-05 6.49E-05 Technetium-101 C1 1.02E-05 Rut henium-103 Ci Rut heni um-106 C1 7.50E-05 1.26E-02 S ilver-110m Cl 6.65E-04 3.63E-02 '

Tin-113 C1 5.87E-05 Indtum-113m C1 7.98E-05 l Cada t um-113m Ct Antimony-122 C1 1.21E-07 l Antimony-124 Ci  !

Antimony-125 Cl 7.05E-04 5.48E-03 l Tellurium-129 Ci Tellurtun-132 C1 1.16E-05 lodine-131 C1 6.76E-06 4.14E-04 lodine-132 C1 lodine-133 C1 4.39E-05 3.83E-04 lodine-135 Ci 9.19E-06 Cesium-134 Ci 6.23E-05 2.96E-03 Cesium-137 C1 3.51E-04 4.60E-03 Bar t um-139 C1 2.20E-05 Bartum-140 Ci Lanthanum-140 Ci Certua-143 Cl 1.79E-05 Certum-144 Ci 1.70E-03 Rhentum-188 , C1 4.01E-05 Total for Period Ci 0.00 0.00 8.35E-03 1.66E-01 10

TABLE 8 (CONTINUED)

EFFLUENT AND WASTE DISPOSAL REPORT - 1995 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Dissolved &

Entrained Gasses Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Argon-41 C1 Krypton-85 C1 7.78E-05 Krypton-85m Ci Krypton-87 C1 Krypton-88 C1 Xenon-131m C1 2.58E-04 3.44E-04 Xenon-133 C1 3.00E-02 5.77E-02 Xenon-133m C1 4.27E-05 2.09E-04 Xenon-135 C1 1.63E-04 3.76E-04 Xenon-135m Ct Total for Period Cl 0.00 0.00 3.04E-02 5.88E-02 l Trttlum l C1 l 0.00 l 0.00 l 1.87E+02 l 3.87E+02 l 11

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  • TABLE 9 EFFLUENT AND WASTE DISPOSAL REPORT - 1995 SOLIO WASTE AND IRRADIATED FUEL SHIPMENTS A. SOLID WASTE SHIPPE0 0FFSITE FOR PROCES$1NG AN0/0R BURIAL (Non-trradiated fuel)
1. Type of Waste Unit 12 month peric,d Est. Total Error %
a. Spent restns, filter sludges, evaporator bottoms, etc. m3 4.32E+01 25 Cl 1.21E-02
b. Dry compressible waste, contaminated equipment, etc. m3 1.06E+02 25 C1 1.66E-01 .
c. Irradiated components, control rods, etc. m3 0.00 Ci 0.00
d. Other (describe): Aspha lt m3 5.02E+00 25 Ci 7.11E-03 2, Estimate of major nuclide composition (by type of waste in %)*

Cs-137 39.1 00-60 2.7 C-14 34.2

a. Cs-134 14.5 H-3 7.2 Ni-163 1.1 Fe-55 29.9 Ni-63 9.7 Co-58 5.3
b. Co-60 14.0 C-14 9.4 C-14 9.4 L :37 12.6 C.

C-14 9.3 N1-63 9.6

d. Fe-55 29,9 Co-60 14.0 Cs-137 12.5 3 Solid Vaste disposition l Number of Shipments Mode of Transportation Destination j 2 Exclusive Use Vehicle Barnwell, SC (CNSI) 4 Exclusive Use Vehicle Oak Ridge, TN (SEG)  !

Type a wastes were shipped in Liners. Type b and d wastes were shipped in strong tight containers, i IRRADIATED FUEL SHIPMENTS (Disposition)

Number of Shipme.its Mode of Transportation Destination 0 N/A N/A

  • Curie values and principle radionuclides are estimates based on a combination of direct and fadirect methoos.

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  • Unpler.ned Releases i 1

There vers no unplanc.ed gaseous or Liquid releases.

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Radioactive Weste Treatment Systems

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l There were no significant changes to radioactive waste treatment systems.

l l Radiological Environmental Monitoring Program 1

The June. 1991, land-use census did not identify any new dose calculation locations.

f Effluent Monitor Instrument Operability 1 ,

! Required effluent monitor instrumentation was not out of service for more than 30 days.  !

1 ODCM & PCP Changes l

1 The PCP was not revised during 1995 .

j The ODCM was not revised during 1995.

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