ML19295G702

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Revised Final Status Survey (FSS) Report - Phase 2, Eberline Analytical Reports
ML19295G702
Person / Time
Site: Zion  File:ZionSolutions icon.png
Issue date: 02/13/2018
From:
ZionSolutions
To:
Office of Nuclear Material Safety and Safeguards
Shared Package
ML19295G627 List:
References
ZS-2019-0090
Download: ML19295G702 (42)
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Text

EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD EBERLINE OAK RIDGE, TENNESSEE 37830 SERVICES PHONE (865) 481-0683 FAX (865) 483-1+621 EBS-OR-43348 February 13, 2018 Alex Bohacheff Zion Solutions, LLC 101 Shiloh Blvd Zion, IL 60099 CASE NARRATIVE Work Order# 18-02001-0R SAMPLE RECEIPT This work order contains three solid samples received 02/01/2018. Samples were analyzed for Total Strontium, Tritium, Nickel-63 and by Gamma Spectroscopy.

CLIENT ID LAB ID B 1021101FIFC005CV 18-02001-04 B 1021101FIFC006CV 18-02001-05 B 102110IFIFC008CV 18-02001-06 ANALYTICAL METHODS Total Strontium was analyzed using EIChroM Method SRWOI Modified. Tritium was performed using Method LANL ER-210 Modified. Nickel-63 was performed using Method ASTM 3500-Ni Modified.

Gamma Spectroscopy was performed using EPA Method 901.1 Modified.

Laboratory qualifiers are as follows:

U - Result is less than the MDA.

ANALYTICAL RES UL TS Combined Standard Uncertainty is reported at 2-sigma value.

Minimum Detectable Activity (MDA) values for data represented in this report are sample-specific.

MDA measurements are determined based on factors and conditions including instrument settings, aliquot size and matrix type.

TOTAL STRONTIUM Samples were prepared by aliquoting as appropriate and leaching in HN0 3

  • Samples were diluted appropriately. Strontium recovery carriers were added to each sample. Chemical separations were conducted using selective extractions. Strontium precipitated was mounted on tared filter media.

Chemical recovery was determined by Strontium carrier mass determinations. Sample was counted by gas flow proportional counting and corrected for Yttrium-90 ingrowth.

Page 1 of 3

[192]

ANALYTICAL RESULTS CONTINUED TOTAL STRONTIUM CONTINUED Samples demonstrated acceptable results for all Total Strontium analyses. Strontium-90 results are reported from Total Strontium. Chemical recovery was acceptable for all samples. The Total Strontium method blank demonstrated an acceptable result. Results for the Total Strontium duplicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Total Strontium laboratory control sample demonstrated an acceptable percent recovery.

TRITIUM A representative aliquot of each sample was equilibrated with Tritium free water. Equilibrates were transferred into round-bottomed distillation flasks and attached to single stage stills. A portion of each middle distillation fraction was transferred to a liquid scintillation vial and cocktail was added. Samples were then counted by beta liquid scintillation.

Samples demonstrated acceptable results for all Tritium analyses. The Tritium method blank demonstrated an acceptable result. Results for the Tritium duplicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Tritium laboratory control sample demonstrated an acceptable percent recovery.

NICKEL-63 A representative aliquot of each sample was leached in HN0 3

  • Leachates were placed in an appropriately sized beaker. Stable elemental Nickel carrier was added to each sample prior to digestion. Samples were digested in concentrated Nitric acid. After digestion, sample pH was adjusted and Nickel-63 was precipitated selectively with Dimethylglyoxime. Precipitates were selectively separated, redissolved, and residual acid was effectively neutralized. Sample residuals were placed into scintillation vials, scintillation cocktail was added and Nickel-63 activity was determined by beta liquid scintillation.

Samples demonstrated acceptable results for all Nickel-63 analyses. All results except the laboratory control sample demonstrated slightly high method detection limits. The Nickel-63 method blank demonstrated an acceptable result. Results for the Nickel-63 duplicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Nickel-63 laboratory control sample demonstrated an acceptable percent recovery.

GAMMA SPECTROSCOPY Samples for Gamma Spectroscopy analysis were prepared by transferring a known mass/aliquot of each homogenized sample to a standard geometry container. Samples were counted on High Purity Germanium (HPGe) gamma ray detectors.

Samples demonstrated acceptable results for all gamma-emitting radionuclides as reported. Some results demonstrated slightly high method detection limits. Some sample results are greater than the method detection limits. These results are rep01ied from the Canberra Gamma Apex "Nuclide MDA Report" and are not positive. These results are qualified as non-detect (U). The method blank demonstrated acceptable results for all radionuclides as rep01ied. Results for the Cobalt-60 and Europium-152 replicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Cobalt-60 and Cesium-137 laboratory control sample demonstrated an acceptable percent recovery.

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[193]

CERTIFICATION OF ACCURACY I ce1iify that this data rep01i is in compliance with the terms and conditions of the Purchase Order, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the cognizant project manager or his/her designee to be accurate as verified by the following signature.

Date: 2/13/2018 Eberline J\nalytical wants and encourages your feedback regarding our performance providing radioanalytical services. Please visit http://cbcrlineanalytical.com/ to provide us with feedback on our services.

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[194]

Printed: 211312018 8:53 AM Page 1 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02001 Eberline Analytical ____Zion Solutions, LLC Purchase Order:

SDG:

677118 _____ ,, ____

--- ---- --*-- ___ ,_ ------- ----------------~----- ---~--*-*-*-*----"-----*----* ----~*

Final Report of Analysis r----w 101 Shiloh Blvd Analysis_ Category: ENVIRONMENTAL

    • - -~*--*--------*-*--------"- -- "------- ... **------

Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier

Units 18-02001-01 LCS KNOWN 02/01/18 00:00 2/1/2018 2/2/2018 18-02001 i Tritium LANL ER-210 Modified 2.46E+02 8.86E+OO pCi/g

>--------- **--------*-----------*-- ~ -----  ;-----~-----"'"' --*

18-02001-01  ! LCS SPIKE 02/01/18 00:00 2/1/2018 2/2/2018 18-02001 , Tritium LANL ER-210 Modified / 2.42E+02 5.76E+OO 1.47E+01 3.63E+OO pCi/g 18-02001-02 ; MBL BLANK 02/01/18 00:00

*-----',-"om"" 2/1/2018 2/2/2018

___,_,_,,_______________ 18-02001 Tritium

'""""'" LANL ER-210 Modified -3.75E-01 2.12E+OO 2.12E+OO 3.67E+OO u pCi/g 18-02001-03 i DUP

' B102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/2/2018 18-02001 Tritium LANL ER-210 Modified  ;

9.25E+01 6.29E+OO  ; 8.15E+OO 7.24E+OO 01/31/18 09:00 2/1/2018 2/2/2018 18-02001 Tritium LANL ER-210 Modified 9.30E+01 6.31E+OO 8.18E+OO 7.25E+OO pCi/g--

18-02001-04 DO B102110IFIFC005CV i

2/1/2018 18-02001-05 TRG B1021101FIFC006CV 01/31/18 09:35 2/2/2018 18-02001 Tritium LANL ER-210 Modified 2.04E+02 1.21E+01 1.67E+01 1.32E+01 pCi/g 18-02001-06 j TRG B1021101FIFC008CV 01/31/1810:12 2/1/2018 2/2/2018 18-02001 Tritium LANL ER-210 Modified 2.64E+01 9.04E+OO 9.16E+OO 1.43E+01 pCi/g

.---------- ---,,-- ,, ___ ,_,_,,-,,,,,m _ _ _ _ _ _ _ _ _ _ _ "'"-

i 18-02001-01 LCS  ! KNOWN 02/01 /18 00:00 2/1/2018 2/1/2018 18-02001

""""-,--,~-----~-~"

Nickel-63 ASTM 3500-Ni Modified  : 1.50E+03 4.51E+01 pCi/g 18-02001-01 LCS SPIKE 02/01/18 00:00 , 2/1/2018 2/1/2018 18-02001 Nickel-63 ASTM 3500-Ni Modified  ; 1.46E+03 i 8.86E+OO 8.63E+01 2.00E+OO pCi/g 18-02001-02  ! MBL BLANK 02/01/18 00:00  : 2/1/2018 2/1/2018 18-02001 ; Nickel-63 ASTM 3500-Ni Modified  : O.OOE+OO 1.18E+OO 1.18E+OO 2.03E+OO u pCi/g 18-02001-03 i DUP B1021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Nickel-63 ASTM 3500-Ni Modified i 4.19E+OO 4.65E+OO 4.65E+OO 7.80E+OO u pCi/g 18-02001-04 i DO B10211 OIFIFC005CV 01/31/18 09:00 I 2/1/2018 2/1/2018 18-02001 ' Nickel-63 ASTM 3500-Ni Modified I 4.36E+OO i 4.49E+OO  ; 4.50E+OO 7.53E+OO u pCi/g 18-02001-05 i TRG B102110IFIFC006CV 01/31/18 09:35 ,,_,, _______ ' 2/1/2018 18-02001 Nickel-63 ASTM 3500-Ni Modified i 4.94E+OO  : 4.47E+OO 4.48E+OO 7.47E+OO u pCi/g 18-02001-06 i TRG B102110IFIFC008CV 01/31/18 10:12  ! 2/1/2018 2/1/2018 18-02001 Nickel-63 ASTM 3500-Ni Modified 5.99E+OO  ! 4.59E+OO ' 4.60E+OO 7.63E+OO u pCi/g i  ; i i

18-ULUU 1-U I ; LCS KNOWN 02/01/18 00:00 2/1/2018 2/5/2018 18-02001 Strontium-90 EIChroM SRW01 Modified j 5.22E+01 2.93E-01 pCi/g

--,-~---------"----*----*---*-----------

18-02001-01 i LCS SPIKE 02/01/18 00:00 2/1/2018

  • ---~-----,--,,-----------:

2/5/2018 18-02001 Strontium-90 EIChroM SRW01 Modified i 5.94E+01 2.41E+OO

  • 2.08E+01 9.77E-01 pCi/g 18-02001-02 ; BLANK 02/01/18 00:00 2/1/2018 2/5/2018 18-02001 Strontium-90 EIChroM SRW01 Modified : 6.74E-01
  • 4.72E-01 5.27E-01 7.51E-01 u pCi/g MBL ,'

18-02001-03 : DUP B1021101FIFC005CV 01/31/18 09:00 2/1/2018 2/5/2018 18-02001 Strontium-90 EIChroM SRW01 Modified I 8.68E-01 i 3.79E-01  ! 4.84E-01 5.47E-01 oCi/q

--" -- 8-02001-04 DO B102110IFIFC005CV 01/31/18 09:00  : 2/1/2018 2/5/2018 18-02001 Strontium-90 EIChroM SRW01 Modified i 8.51E-01  : 4.07E-01 5.03E-01 6.10E-01 pCi/g 18-02001-05 , TRG B1021101FIFC006CV 01/31/18 09:35 i 2/1/2018 2/5/2018 18-02001 i Strontium-90 EIChroM SRW01 Modified  ! 5.76E-01  ! 4.50E-01 4.93E-01 7.32E-01 u pCi/g 18-02001-06 i TRG B1021101FIFC008CV 01/31/18 10:12  : 2/1/2018 2/5/2018 18-02001 i Strontium-90 EIChroM SRW01 Modified  ! 8.11E-01 i 4.91E-01 i 5.66E-01 7.80E-01 pCi/g

~----,----*. *--  ! j

!  ! i 18-02001-01 LCS KNOWN 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 ' Cobalt-60 EPA901.1 Modified  ; 2.71E+02  : 1.06E+01 i pCi/g 18-02001-01  ! LCS KNOWN 02/01 /18 00:00 i 2/1/2018 2/1/2018 18-02001 ; Cesium-137 EPA 901.1 Modified  : 1.69E+02  : 6.75E+OO i pCi/g 18-02001-01 LCS SPIKE 02/01/18 00:00  ; 2/1/2018 2/1/2018 18-02001 ' Cobalt-60 EPA 901.1 Modified 2.85E+02 1.76E+01 2.29E+01 2.08E+OO pCi/g

I 18-02001-01 i LCS SPIKE 02/01/18 00
00  ! 2/1/2018 2/1/2018 18-02001 ! Cesium-137 EPA901.1 Modified i 1.94E+02 '. 3.21E+01 3.36E+01 2.34E+OO pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Norrnal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERVICES EBERLINE 601 SCARBORO ROAD OAK RIDGE, CAL CORPORATION -----------------------

TN 37830 865/481-0683 FAX 865/483-4621 [195]

Printed: 2/13/2018 8:53 AM Page 2 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02001 Eberline Analytical Zion Solutions, LLC SDG:

Purchase Order: 677118

""" '"""'""m" -~----- *------ ---,-~

Final Report of Analysis 101 Shiloh Blvd Analysis Category: ENVIRONMENTAL

,*-----*---- --~- --*-------,--"'-- "----

so Zion, IL 60099 Sample Matrix:

Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02001-02 MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001

****---,,-,-*"-*-*-~--------""'""_________,,_,,,-,,,,,--,----*----

Actinium-228 EPA 901.1 Modified  : -2.63E-01

' 3.12E-01 3.12E-01 3.26E-01 u pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 Silver-108m EPA 901.1 Modified ' 3.85E-02 5.03E-02 5.03E-02 5.78E-02 u pCi/g 18-02001-02 MBL BLANK 02/01 /18 00:00 2/1/2018 2/1/2018 18-02001 Americium-241 EPA 901.1 Modified -1.46E-02 6.91E-02 6.91E-02 9.75E-02 u pCi/g 18-02001-02

~"----*----

MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 Barium-133 EPA 901.1 Modified 1.32E-02 6.10E-02 ' 6.10E-02 9.33E-02 u pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00 2/1/2018

,,,,,_" __ ,, __ 2/1/2018

,,, 18-02001 Bismuth-214 EPA 901.1 Modified 1.72E-02 1.03E-01 1.03E-01 1.76E-01 u pCi/g 18-02001-02 MBL BLANK

--*--*--*--**----~-----****-----------

02/01 /18 00:00 2/1/2018 2/1/2018 18-02001 , Cobalt-60 EPA 901.1 Modified 3.95E-02 ' 4.87E-02 4.88E-02 1.15E-01 u i pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00 2/1/2018 '

2/1/2018 18-02001 Cesium-134

,,_.__ _ _ ,,m_, __ ,, _ _ _ _ ,ow""

EPA 901.1 Modified 1.28E-03 6.45E-02 6.45E-02 9.29E-02 u pCi/g 18-02001-02

--~------

MBL BLANK

' ---,--- 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 Cesium-137 EPA 901.1 Modified 4.53E-02 6.31E-02 6.31E-02 1.20E-01 u pCUg 18-02001-02 MBL BLANK ___ ,,, 02/01 /18 00:00 2/1/2018 2/1/2018 ' 18-02001 Europium-152 EPA 901.1 Modified -5.14E-02 i 1.91E-01 1.91E-01 1.44E-01 u  ; pCi/g

*-**-'"':-"-****-*-*"-"'=--**-***---" --  :

18-02001-02 MBL BLANK 02/01/18 00:00  ! 2/1/2018 2/1/2018 18-02001 r:=ui,,,,r--*~*11-154 EPA 901.1 Modified 2.16E-02 1.14E-01 1.14E-01 7.04E-02 u pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00 ' 2/1/2018 2/1/2018 18-02001 LUl"'l"'~':1-

"'"' EPA 901.1 Modified 5.98E-03 5.00E-02 5.00E-02 1.00E-01

' u pCi/g 18-02001-02 i MBL BLANK 02/01/18 00:00 ' 2/1/2018 2/1/2018 18-02001  ! Holmium-166m EPA 901.1 Modified 2.53E-02 1.06E-01 1.06E-01 6.81E-02 u  ; pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 i lodine-129 EPA 901.1 Modified 6.95E-02 1.02E-01 1.03E-01 1.67E-01 u . pCi/g 18-02001-02 i

~------'.---- .

MBL BLANK

      • --~-, __,

02/01/18 00:00 2/1/2018 2/1/2018 18-02001 Potassium-40 EPA 901.1 Modified i 9.69E-02 ' 1.90E-01 1.90E-01 7.13E-01 u pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00  ! 2/1/2018 2/1/2018 , 18-02001 Manganese-54 EPA 901.1 Modified ' O.OOE+OO 6.80E-02 6.80E-02 1.06E-01 u pCi/g 18-02001-02 ; MBL BLANK 02/01/18 00:00  : 2/1/2018 2/1/2018 18-02001 Niobium-94 EPA 901.1 Modified -3.07E-02 ' 7.76E-02 ' 7.76E-02 8.11E-02 u pCi/g 18-02001-02 MBL BLANK 02/01/18 00:00,,____,_,,,,,,_,,,,,,

2/1/2018 _____,,,__ 2/1/2018 18-02001 i Lead-210

--*-**"'-*-----*-~--*,----*

EPA 901.1 Modified 7.35E-01 : 7.13E-01 7.14E-01 1.22E+OO u ' pCi/g 18-02001-02 MBL ___

BLANK

" ___ ,. 02/01/18 00:00 i 2/1/2018 2/1/2018 18-02001 Lead-212 EPA 901.1 Modified -1.68E-02 : 6.19E-02 . 6.20E-02 9.02E-02 u  : pCi/g 10 -~= --00

' MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 I Lead-214 EPA 901.1 Modified 9.50E-02 8.23E-02 8.24E-02 1.68E-01 u pCi/g 18-02001-02 , MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 1.3-02001_ ; n -***~:c*~:c: ,-15 EPA 901.1 Modified -8.51E-02 ! 9.21E-02 9.22E-02 1.22E-01 u '

pCi/g 10 =~= ~:  :

___ ,,_ u 18-02001-02 ,

MBL MBL BLANK BLANK,,

02/01/18 00:00 02/01 /18 00:00 2/1/2018 2/1/2018

--,=--

2/1/2018 2/1/2018 18-02001 18-02001 I

Radium-226

'~"""V"J *-

1£0 EPA 901.1 Modified EPA 901.1 Modified 1.72E-02 3.30E-02 i 1.03E-01 1.07E-01 1.03E-01 1.07E-01 1.76E-01 1.91E-01 u pCi/g pCi/g 18-02001-02 MBL BLANK ,,, ____ 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 Thorium-234 EPA 901.1 Modified 3.97E-01 ! 6.07E-01 6.07E-01 1.00E+OO u pCi/g 18-02001-02 i MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 : Thallium-208 EPA901.1 Modified 2.72E-02 i 1.67E-01  : 1.67E-01 2.79E-01 u pCi/g 18-02001-02 : MBL BLANK 02/01/18 00:00 2/1/2018 2/1/2018 18-02001 : Uranium-235 EPA 901.1 Modified  : 4.56E-01 i 5.82E-01 5.82E-01 3.46E-01 u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Nonmal Sample;DO=Duplicate Original;U=Non-detect EBERLINE Al YT!CAL CORPORATION r--------------- -----------------------

601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [196]

Printed: 2/13/2018 8:53 AM Page 3 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02001 Eberline Analytical , ........

__ Zion Solutions, LLC SDG:

Purchase Order: 677118 c -- --~-A,,A,~--- '"-*-----------*-----------"*-------- -------~,-- ***-**--*~----**-"-*-"-*m____,,__._,_,m ____""'~

Final Report of Analysis ,............. 101 Shiloh Blvd Analvsis Category: ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so .

Lab Sample Client Sample Receipt Analysis Batch Report Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units ID Type ID i

18-02001-03 DUP 81021101FIFC005CV 01/31/18 09:00 2/1/2018 : 2/1/2018 18-02001 Actinium-228 EPA 901.1 Modified  : -4.81E-01 2.41E+OO 2.41E+OO 3.52E+OO u pCi/g

-fo-ULUU t-03 DUP 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Silver-108m EPA901.1 Modified 1.35E+OO 7.68E-01 7.72E-01 5.69E-01 u pCi/g 18-02001-03 : DUP ,,_, __,,,,___,,,_._____~*-**----**

_____8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Americium-241 EPA901.1 Modified i i

4.48E-01  :

5.57E-01 5.57E-01 8.59E-01 u pCi/g 18-02001-03 : DUP 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001

,,,,m~"----**----------.,,,,,.,,,,m,~-*----'"'~"".'"'-"_"_,o,-----**

8arium-133 EPA 901.1 Modified  : -1.10E-02 6.57E-01 6.57E-01 8.51E-01 u pCi/g 18-02001-03 DUP  : 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 8ismuth-214 EPA 901.1 Modified  : 8.63E-01 1.07E+OO 1.07E+OO 1.78E+OO u pCi/g 18-02001-03 : DUP B1021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Cobalt-60 EPA 901.1 Modified 7.89E+OO  : 8.15E-01 9.10E-01 6.71E-01 pCi/g 18-02001-03 DUP 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 __,,, _____

Cesium-134 EPA 901.1 Modified 2.13E-01 4.30E-01 4.30E-01 8.41E-01 u  : pCi/g

~--- --~-------*-*-----*------ .

18-02001-03 DUP 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Cesium-137 EPA 901.1 Modified 4.22E+OO 1.12E+OO 1.14E+OO 1.34E+OO pCi/g

- i 18-02001-03 DUP 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001

  • Europium-152 EPA 901.1 Modified 1.61E+02 8.83E+OO 1.21E+01 3.53E+OO pCi/g

01/31/18 09:00 2/1/2018 2/1/2018 18-02001 ;  !=cc .;'c::: 15-. EPA 901.1 Modified 4.32E+OO  : 1.41E+OO 1.42E+OO 2.71E+OO u pCi/g 18-02001-03 DUP 810211 OIFIFC005CV  :

DUP 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 1  !=cc '"'c::: 155 EPA 901.1 Modified 3.23E-01 i 9.48E-01  : 9.48E-01 1.42E+OO u pCi/g

'-- -----,---"----~-------

18-02001-03 : DUP 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Holmium-166m EPA 901.1 Modified 1.01E+OO i 1.16E+OO 1.17E+OO 6.81E-01 u pCi/g

    • -------~---* ------,----------*-------  :

18-02001-03 DUP 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 : 2/1/2018 , 18-02001 lodine-129 EPA 901.1 Modified 9.24E-01 ! 2.56E-01 2.60E-01 4.23E-01 u pCi/g 18-02001-03 DUP i 81021101FIFC005CV 01/31/18 09:00 i 2/1/2018 2/1/2018 18-02001 , Potassium-40 EPA 901.1 Modified  ! 1.13E+01 i

4.24E+OO . 4.28E+OO 8.19E+OO u pCi/g 18-02001-03 i DUP 8102110IFIFC005CV 01/31/18 09:00  : 2/1/2018 2/1/2018 18-02001 ~.~""M""""'"""" !5.A EPA 901.1 Modified -6.28E-01  ! 6.83E-01 6.84E-01 9.41E-01 u pCi/g 18-02001-03 . DUP 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Niobium-94 EPA901.1 Modified  : -2.24E+OO , 1.21E+OO 1.22E+OO 9.03E-01 . u pCi/g 18-02001-03 DUP B102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 : Lead-210 EPA 901.1 Modified  ! 1.83E+02 1.69E+01 1.93E+01 1.49E+01  : pCi/g 18-02001-03 : DUP 8102110IFIFC005CV 01/31/18 09:00 _________ __________

2/1/2018 2/1/2018 18-02001 _____Lead-212

,,, __ EPA 901.1 Modified 6.28E-01 : 9.17E-01 9.18E-01 1.11E+OO u pCi/g 18-02001-03 ' DUP ,,,, __

81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Lead-214 EPA 901.1 Modified 6.42E-01  : 1.19E+OO 1.19E+OO 1.46E+OO u pCi/g 18-02001-03 DUP 8102110IFIFC005CV 01/31/18 09:00  : 2/1/2018 2/1/2018 18-02001 Promethium-145 EPA 901.1 Modified -5.65E+01 i 4.56E+OO  : 5.40E+OO 1.55E+OO u . pCi/g

---18-02001-03  :

DUP 8102110IFIFC005CV 01/31/18 09:00 i 2/1/2018 2/1/2018 18-02001 ' Radium-226 EPA901.1 Modified i 8.63E-01 i 1.07E+OO 1.07E+OO 1.78E+OO i u pCi/g i

18-02001-03 : DUP 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 ; Antimony-125 EPA 901.1 Modified  : -9.10E-01 1.44E+OO 1.44E+OO 1.76E+OO u pCi/g 18-02001-03 i DUP . 81021101FIFC005CV 01/31/18 09:00 2/1/2018 . 2/1/2018 18-02001 Thorium-234 EPA 901.1 Modified 7.34E+OO 5.44E+OO 5.46E+OO 8.58E+OO u pCi/g 18-02001-03 DUP B102110IFIFC005CV 01/31/18 09:00  ; 2/1/2018 2/1/2018 18-02001 Thallium-208 EPA 901.1 Modified -4.02E-01  : 1.61E+OO 1.61E+OO 1.34E+OO u pCi/g i

18-02001-03 DUP B102110IFIFC005CV 01/31/18 09:00  : 2/1/2018 2/1/2018 18-02001 . Uranium-235 EPA901.1 Modified 9.22E-01  : 7.75E+OO 7.75E+OO 3.91E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ,;;-]\EBERLINE J!!/ SERV CES EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [197]

Printed: 2/13/2018 8:53 AM Page 4 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02001 Eberline Analytical SDG:

Final Report of Analysis

_____ Zion Solutions,_ LLC .....

1--------~---~--;---**n*----~-~-t-~-~-0B_9_*~---*-d**-*********-*-*********-***-------***---*-----*-**-*-*-*** A~a~::P~:~~~r~: * -*

Purchase Order: 677118

~~VI RON MENT4L---** _ ....... ------------*******-----------**

Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date Analyte Method Result cu CSU MDA Qualifier ID Units 18-02001-04 DO B 10211 OIFIFC005CV 01/31/18 09:00 211/2018 2/1/2018 18-02001 Actinium-228 EPA 901. 1 Modified  : 1.78E+OO 2.38E+OO 2.38E+OO 3.69E+OO U pCi/g 18~02001-04  ; ___DO ...,,,;,,,___________________________________

B102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Silver-108m EPA 901.1 Modified 1.06E+OO 7.49E-01 7.51E-01 6.26E-01 U pCi/g ___

,__ ______:,....... l---***-----------*-----*-*-**--****** ----------------1-------**--**----------**---'-----~----------,.,; ......______________________________________ _;,,,,,,;:,, ~

18-02001-04 DO B102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 : Americium-241 EPA901.1 Modified  ; -3.25E-01 5.48E-01 5.48E-01 7.88E-01 , U pCi/g 18-02001-04 DO 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Barium-133 EPA901.1 Modified 5.13E-01 7.15E-01 7.15E-01 8.30E-01 U pCi/g

~~-------------,--,-------- ------ ----------- - - ----------------------------------------------------- ---,!--*-******

18-02001-04 DO 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Bismuth-214 EPA901.1 Modified , 1.30E+OO  : 7.34E-01 7.37E-01 9.76E-01 pCi/g 18-02001-04 DO 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Cobalt-60 EPA 901.1 Modified ' 7.40E+OO 7.64E_-0_1________ 8_.5_3_E-_o._1________4_._01___E_-_0_1_________________.P_Cil:::...g _______...

~------------------------"'

18-02001-04 DO B102110IFIFC005CV 01/31/18 09:00 ' 2/1/2018 2/1/2018 18-02001 Cesium-134 EPA901.1 Modified ( -1.SOE-02 4.49E-01 4.49E-01 8.63E-01 U pCi/g

-'""""' ,-------~---.---,-,=,ov __,,_,_._,_,_,m_,________

18-02001-04 DO 8102110IFIFC005CV 01/31/18 09:00 ' 2/1/2018 2/1/2018 18-02001 Cesium-137 EPA901.1 Modified , 4.02E+OO 1.02E+OO 1.04E+OO 1.17E+OO pCi/g

  • -*-------*----*-***-----*-*-* -- --,-.-----+*-**-*-***--**---*-----*-*--***-1*-----------*--i*****--*-*******---*****----------*-*-**---------'-***::...---1 18-02001-04 DO 8102110IFIFC005CV 01/31/1809:00 2/1/2018 2/1/2018 18-02001 Europium-152 EPA901.1 Modified  ; 1.54E+02 , 8.50E+OO 1.16E+01 2.83E+OO pCi/g l-****-***------***-***-*---*--*-****-*--***---*------**--*-----1-*- - - - - - - - - - - - - - - - - - - - - -..,_.,, _ _ _ "----*-*+---..C.---+----*-**************--------+--*-**------------*-**:---*------------*-**------*--'...------4 18-02001-04 DO 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Europium-154 EPA 901.1 Modified ' 5.56E+OO 1.63E+OO ' 1.66E+OO 3.10E+OO U pCi/g

*---'---------------------+-------------------------*--

18-02001-04 DO 810211 OIFIFC005CV 01/31/~~~:~~: * .2:'2:~~~~--2!11_2:~~- 18-020::.1______~_':'fOP~~-':::2_:iS_l-*--*E__ PA_90_1_._1___ M_o__d ___d___+---

___i___fi e '-1_.s_s_E_-0___1____,__ 9_.5_1E_-_0_1____:.._____9_.s_1_E_-0_1___ ,___1,,A 2_E_+_o_o______u__________:__

___ ~~--:-'.~"---*****--1 18-02001-04 j DO 8102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Holmium-166m EPA 901.1 Modified -1.33E-01 _4_._34_E__-_01____;__4_.3__4___E_-0_1_____ 6_.7_7_E-_0_1 __, _______u _____....,..__,~_ v__"__~c__---l 18-02001-04 ; DO 81021101FIFC005CV 01/31/18 09:00 211/2018 2/1/2018 18-02001 lodine-129 EPA901.1 Modified i 7.46E-01 , 2.64E-01 2.67E-01 4.20E-01 U pCi/g

                • ---*-*-*------~----***---*-******-**--*--------,---~-------------~-----------~,.-----*-------------+--*****-*---------*---*********-----***---.;---------------------****-*------"*--**=------!

18-02001-04 DO 8102110IFIFC005CV 01/31/1809:00 2/1/2018 211/2018 18-02001 Potassium-40 EPA901.1 Modified  ; 5.82E+OO : 3.82E+OO 3.84E+OO 6.75E+OO U pCi/g

*******-*-----**-------1-****-**-----------*-*******--*--***----;-------*----*-****+***************-**-------------r**----------*-*-------**---------*------****--**-*'***.....:-----1

__ 18_-0_2_0__0_1_-_0__ 4 ___;_ _D_o____s___1___0__2_1____1___0___1_F_1_F_c

__o_o_s_c _______-+-_0_1,~2!1~_99 oo_-+_2,_1,_2_0_18___2_1112_~~~---* 18-02001 1 Ma.~-~a.-~=-~-==~--,--E_P_A_90_1_.1_M__od___ifi_,e_d__,__:_9_.8_3_E_-0_2___s._s_sE_-_0_1_____s_.s_s_E_-0_1__________9__.1_1_E-_0_1____u__________,P_cu...:;_

__v 9 ____

1 1 18-02001-04 DO 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Niobium-94 EPA901.1 Modified  ; -2.43E+OO ' 1.15E+OO 1.16E+OO 9.32E-01 U , pCi/g 1-----------*-+-***-**-***----------*-*----+---------****--+***--*--*-*--**------*-****-***-**--******-'----*-*---***--t***-***-------***---+-------*-----*-*--*-'-*-*--*-----------*----'---'-----'--***-**---I 18-02001-04 DO 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 ; Lead-210 EPA 901.1 Modified 1.93E+02 1.73E+01 i 1.99E+01 1.43E+01 pCi/q 18-02001-04 DO i 81021101FIFC005CV 01/31/18 09:00 2/1/2018 , 2/1/2018 18-02001 : Lead-212 EPA 901.1 Modified 7.08E-01 8.79E-01 8.80E-01 1.16E+OO U pCi/q 18-02001-04 DO ' 810211 OIFIFC005CV 01 /31 /18 09:00 *.*.,..,,2_,_1,_2_0_18_____2__, __1_,_2___0___1___8____1_8_-0___2_00_1_,:___L__e_a_d_-_2_1

_ __4___+**---E_P_A_9_0_1__.__1______M

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__ ,e_d_.;___1._09__E_+_o_o_ _1_.0_9_E_+_oo____,'.....__1_.0_9_E+_o_o_____1. 33___E____+___o__o____

__ u___________;P_;_Ci/.:::.....g_,

18-02001-04 ' DO  : 8102110IFIFC005CV 01/31/1809:00 2/1/2018 2/1/2018 18-02001 . Promethium-145 EPA901.1 Modified -5.65E+01 4.57E+OO 5.41E+OO 1.52E+OO U pCi/g I-*-----*-**,**-**------*--****--*-----*---+--------------*-*********-----* **----------------*-**---****--l---------****-****-*-----*-*--.:.---***------------*--------------'---'--";-,.-1 18-02001-04 i DO B102110IFIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 Radium-226 EPA 901.1 Modified ' 1.30E+OO 7.34E-01 7.37E-01 9.76E-01 pCi/g l--18-_0 __2__0__0____1_-_0_4_1-__D_o____.,__s_1_02_1_1_01FIFC005CV 01/31/18 09:00  : 2/1/2018 2/1/2018 18-02001 ' Antimony-125 EPA 901.1 Modified -9.96E-01 1.59E+OO  ; 1.59E+OO 1.91E+OO U pCi/q 18-02001-04 DO 81021101FIFC005CV 01/31/1809:00 2/1/2018 2/1/2018 18-02001 Thorium-234 EPA901.1 Modified -1.60E+OO : 5.51E+OO 5.52E+OO 8.09E+OO U pCi/g 18-02001-04  ! DO  : 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 i Thallium-208 EPA 901.1 Modified -2.49E-01 ' 1.53E+OO 1.53E+OO 1.42E+OO U pCi/g 18-02001-04 DO 81021101FIFC005CV 01/31/18 09:00 2/1/2018 2/1/2018 18-02001 i Uranium-235 EPA 901.1 Modified 2.60E+OO  : 7.96E+OO 7.96E+OO 4.02E+OO U  : pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERVICES EBERUNE 601 SCARBORO ROAD OAK RIDGE, TN 37830 ALYT!CAL ON 865/481-0683 FAX 865/483-4621 [198]

Printed: 2/13/2018 8:53 AM Page 5 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02001 Eberline Analytical ,,.,..,.,..

Zion Solutions, LLC _,,m _____ ,,,,_,,mm _ _ _ _ __. _ _ _ _ _ _ _ _

SDG:

Purchase Order: 677118

--~~--- *-------*---*-

Final Report of Analysis 101 Shiloh Blvd *----,

Analysis Category: ENVIRONMENTAL Zion, IL 60099 Sample Matrix:

so Lab Sample Client Sample Receipt Analysis Batch Report Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units ID Type ID 18-02001-05 TRG 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Actinium-228 EPA 901.1 Modified  : 1.73E+OO 2.90E+OO 2.90E+OO 4.35E+OO u pCi/g

            • -- 1--***-

18-02001-05 TRG 810211 OIFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Silver-108m EPA901.1 Modified . 1.25E+OO 9.53E-01 9.55E-01 8.18E-01 u pCi/g

,----------------,*--*-**-*-------- ,._.m_ _ _ _ ,_,,,,,_,,,.,, --,-mmmo*m~---

0

~~2.')01-05 i TRG 81021101FIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Americium-241 EPA 901.1 Modified  ; -5.49E-01  : 8.49E-01 8.49E-01 1.05E+OO u pCi/g 18-02001-05 TRG 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 8arium-133 EPA 901.1 Modified 4.71E-01 7.36E-01 7.36E-01 1.09E+OO u pCi/g

*----------*-- ------*--------- ~-*--------,-(------*-----------------------*-------,,------*---~--

18-02001-05 TRG 81021101FIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 8ismuth-214 EPA 901.1 Modified  : 7.70E-01 1.48E+OO 1.48E+OO 1.79E+OO u pCi/g

-*----* ----~-"' *-*----- *-*

18-02001-05 TRG 810211 OIFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Cobalt-60 EPA 901.1 Modified i 1.74E+01 1.30E+OO 1.58E+OO 8.79E-01 pCi/g 18-02001-05 TRG , __ ___________

8102110IFIFC006CV 01/31/18 09:35

,,,,,.,,--~--------- ~---------~ ----------------'~--=--------- 2/1/2018 ,,,_, ________

2/1/2018 18-02001 ,___, _,_,__Cesium-134

_, ____v_"---*=-- EPA 901.1 Modified

-3.18E-01 7.02E-01 7.02E-01 1.00E+OO u pCi/g 18-02001-05 TRG 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Cesium-137 EPA 901.1 Modified -2.16E-02 8.65E-01  ! .65E-01 1.26E+OO u pCi/g 18-02001-05 ; TRG 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 '. Europium-152 EPA 901.1 Modified  : 2.36E+02 8.46E+OO 1.48E+01 4.41E+OO pCi/g

~--------------~-**- """

18-02001-05 TRG 81021101FIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Europium-154 EPA 901.1 Modified i 8.68E+OO 1.82E+OO 1.87E+OO 3.37E+OO u pCi/g

~--*-* :-~----- --------  :

18-02001-05 TRG 81021101FIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 : Europium- EPA 901.1 Modified 3.29E+OO 1.09E+OO 1.11E+OO 1.74E+OO u pCi/g 18-02001-05 18-02001-05 18-02001-05 TRG TRG TRG B102110IFIFC006CV

-**------*--,,,,.,------------"~-------------~

81021101FIFC006CV 8102110IFIFC006CV

---*-~

01/31/18 09:35 01/31/18 09:35 01/31/18 09:35 2/1/2018 2/1/2018 2/1/2018 2/1/2018 2/1/2018 2/1/2018 18-02001 18-02001 18-02001 Holmium-166m lodine-129 Potassium-40

. ~:~:1~~t~=H~r EPA 901.1 Modified 01 6.74E+OO 1 :

1.46E+OO 8.19E-01 3.90E+OO 1.46E+OO

! .21E-01 2.91E+OO 6.61E-01 1.05E+OO 6.58E+OO u

u pCi/g pCi/g pCi/g 02001-05 1-05 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 - EPA 901.1 Modified i -3.61E-01  ! 8.32E-01  ! .32E-01 1.18E+OO u pCi/g TRG 81021101FIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Niobium-94 EPA 901.1 Modified [ -8.49E-01  ; 1.16E+OO 1.16E+OO 1.06E+OO u pCi/g

-* 18-02001-05 TRG 81021101FIFC006CV

- 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 : Lead-210 EPA 901.1 Modified  ! 3.39E+02 3.00E+01 2.47E+01 2.36E+01 u pCi/g 18-02001-05 : TRG 810211 OIFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 : 18-02001 Lead-212 EPA 901.1 Modified i 4.96E-01 6.12E-01 { .13E-01 1.37E+OO u pCi/g 18-02001-05

TRG 81021101FIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Lead-214 EPA 901.1 Modified i 4.97E-01  : 1.06E+OO 1.06E+OO 1.72E+OO u pCi/g 18-02001-05 TRG 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 ' Promethium-145 EPA 901.1 Modified i 2.48E+01 3.68E+OO ".90E+OO 4.14E+OO u pCi/g 18-02001-05 TRG 81021101FIFC006CV

  • - ----------*-------------------------~-~---

01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Radium-226 EPA 901.1 Modified i

7.70E-01 1.48E+OO 1.48E+OO 1.79E+OO u pCi/g 02001-05

---=-"""

TRG 810211 OIFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 o, ____ , ______ ,

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' ' *****-"J. '""""' EPA 901.1 Modified ) -9.13E-01 1.74E+OO 1.74E+OO 2.46E+OO u pCi/g 18-02001-05 TRG 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 Thorium-234 EPA 901.1 Modified i 2.30E+OO 8.06E+OO E.06E+OO 1.03E+01 u pCi/g 02001-05 8102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001 ; Thallium-208 EPA 901.1 Modified  : 3.56E-01 1.19E+OO

. 1.19E+OO 9.28E-01 u pCi/g

TRG i B102110IFIFC006CV 01/31/18 09:35 2/1/2018 2/1/2018 18-02001
  • 11~~-: .. - '1".>t:

EPA901.1 Modified  : 4.10E+OO 8.37E+OO c.37E+OO 3.87E+OO u pCi/g 18-02001-05 : TRG CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERVICES I EBERLINE I 601 ANAL YT!CAL CORPORA T!ON SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/ 483-4621 [199]

Printed: 2/13/2018 8:53 AM Page 6 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02001 Eberline Analytical f*

Zion Solutions, LLC --------h~-*-

SDG:

Purchase Order.* 677118

,m--*- *----"*--- ----*--*- "'""'"""'"'f""

Final Report of Analysis 101 Shiloh Blvd Analysis Category ENVIRONMENTAL Zion, IL 60099 Sample Matrix.* so Lab Sample Client Sample Receipt Analysis Batch Report Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units ID Type ID  :

18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 Actinium-228 EPA 901-1 Modified 5.34E-01 1.66E+OO  : L66E+OO 2.60E+OO u pCiig

- - - - - - *-----,--*-- *------~~"'

18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 Silver-108m EPA90U Modified  :

5.48E-02 4.55E-01 4.55E-01 4.66E-01 u pCi/g 18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 Americium-241 EPA 901.1 Modified -4.12E-01 6.17E-01 6.17E-01 7.23E-01 u pCi/g 18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 8arium-133 EPA 901.1 Modified  : -3.09E-02 2.31E-01  : 2.31E-01 7.31E-01 u  : pCi/g

~--------'-----*~.-------------*-*'--*

18-02001-06

  • TRG 81021101FIFC008CV 01/31/1810:12 2/1/2018 2/112018 18-02001 8ismuth-214 EPA 901.1 Modified 1.03E+OO 8.51E-01 8.52E-01 1.42E+OO u pCi/g 18-02001-06 TRG 8102110IFIFC008CV 01131/18 10:12 21112018 21112018 18-02001 Cobalt-60 EPA 901.1 Modified 2.32E+OO 4.53E-01 4.68E-01 3.77E-01 pCilg

*--"'*-*--~*-*------*---------*---------*---- --* ---- .. ,,,--*- ----*~---*--*----*-*-*--*-*-*-- '

18-02001-06 TRG 81021101FIFC008CV 01/31118 10:12 211/2018 2/1/2018 18-02001 Cesium-134 EPA901.1 Modified 1.27E-01 2.15E-01 2.15E-01 5.26E-01 u pCi/g 18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12 2/1/2018 18-02001 Cesium-137 EPA 901.1 Modified -6.01E-01 5.17E-01  : 5.18E-01 6.30E-01 u pCi/g

---*-*-*------*-----*--*-----~"'**--*--- ------

18-02001-06 TRG  : 81021101FIFC008CV 01/31/1810:12 2/1/2018

  • 2/1/2018 18-02001 Europium-152 EPA 901.1 Modified  : 4.80E+01 2.42E+OO 3.45E+OO 2.48E+OO pCi/g 18-02001-06 : TRG 8102110! -~ " 01/31/18 10:12 2/1/2018 : 2/1/2018 18-02001 ~v,v~,v, ,54 EPA 901.1 Modified 8.13E-01 : 8.90E-01 8.91E-01 1.65E+OO u ' pCi/g
u 18-02001-06 TRG ' 8102110IFIFC008CV 01/31/18 10
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--*-r--*-*** --

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  • 2/1/2018 18-02001 Holmium-166m EPA 901.1 Modified 5.45E-01 7.19E-01 7.20E-01 4.62E-01 u pCi/g

~--,-~v~;------*-*-*-- -"*---**

18-02001-06 TRG 8102110IFIFC008CV 01/31/1810:12 i 2/1/2018 2/1/2018 18-02001 lodine-129 EPA901.1 Modified 7.56E-02 2.62E-01 2.62E-01 3.42E-01 u pCi/g 18-02001-06

  • TRG 8102110IFIFC008CV 01/31/18 10:12 ' 2/1/2018 2/1/2018 18-02001 Potassium-40 EPA 901.1 Modified 8.65E+OO 5.35E+OO 5.37E+OO 8.28E+OO pCiig 18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12  : 2/1/2018 : 2/1/2018 18-02001 ***-**;::,-* *- - C EPA 901.1 Modified  : 4.72E-02 4.13E-01 4.13E-01 6.38E-01 u pCi/g 18-02001-06 i TRG 8102110JFIFC008CV 01/31/1810:12 2/1/2018 2/1/2018 18-02001 Niobium-94 EPA 901.1 Modified  : -4.73E-01 7.49E-01 7.49E-01 6.18E-01 u pCiig
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- ~

-*-----------=

01/31/18 10:12 2/1/2018 2/1/2018 18-02001 Lead-210 EPA 901.1 Modified 6.98E+01 9.62E+OO 1.03E+01 1.10E+01 pCi/g 18-02001-06 18-02001-06 TRG TRG 81021101FIFC008CV 01131/18 10:12  : 2/1/2018 2/1/2018 18-02001 Lead-212 EPA 901.1 Modified

' 1.99E-01 3.92E-01 3.92E-01 7.70E-01 u pCilg 18-02001-06 : TRG 81021101FIFC008CV 01/31/18 10:12  ; 2/1/2018 2/1/2018 18-02001 Lead-214 EPA 901.1 Modified 2.06E+OO 7.72E-01  : 7.79E-01 2.74E+OO u pCi/g 18-02001-06 : TRG 8102110IFIFC008CV 01/31/18 10:12  : 2/1/2018 : 2/1/2018 18-02001  ! Promethium-145 EPA 901.1 Modified 2.54E+OO  : 1.39E+OO 1.40E+OO 1.85E+OO u pCi/g

~02001-06 I TRG 8102110IFIFC008CV 01/31/18 10:12 i 2/1/2018 2/1/2018 18-02001 Radium-226 EPA 901.1 Modified 1.03E+OO 8.51E-01 8.52E-01 1.42E+OO u pCi/g 18-02001-06 TRG 81021101FIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 ..

'-,,..,.,v.,, --

,~o EPA901.1 Modified 9.33E-01 9.98E-01 1.00E+OO 1.62E+OO u  : pCi/g 02001-06 :

TRG

---81021101FIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 Thorium-234 EPA 901.1 Modified 7.40E+OO  : 5.74E+OO 5.76E+OO 8.09E+OO u pCi/g

"'"""'------* =-*----~~--*---------  :

18-02001-06 : TRG 81021101FIFC008CV 01/31/1810:12 2/1/2018 2/1/2018 18-02001 Thallium-208 EPA901.1 Modified 7.91E-02 1.33E+OO  :

1.33E+OO 1.68E+OO u pCi/g 18-02001-06 ' TRG 8102110IFIFC008CV 01/31/18 10:12 2/1/2018 2/1/2018 18-02001 ' Uranium-235 EPA 901.1 Modified -5.02E-02 4.07E+OO 4.07E+OO 2.67E+OO u  : pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Nonmal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERViCES I

i EBERLINE ANALYTICAL CORPORA T!ON I 601 SCARBORO ROAD OAK RIDGE, TN 7-83-0--8-6-5/_4_8_1--0-6_8_3__F_A_X_8_65/483-4621 [200]

ZS-WM-131 Revision 0 Information Use ZIOr~SOLUTIONSiu RECD fEB O1 2018 Attachment 1 - Chain-of-Custody Form 1a-02001 Sample ID Sample Matrix Sample Sample Container Sample Date Sample Time Analysis Preservative Remarks Log Type Type Vol Unit Type Qty B102110IFIFC005CV NIA Concrete Concrete 57.94 cm3 Puck l 1/31/2018 0900 HTD None 0.0"-0.5" Bl02110IFIFC006CV NIA Concrete Concrete 57.94 cm3 Puck l 1/31/2018 0935 HTD None 0.0"-0.5" B102110IFIFC008CV NIA Concrete Concrete 57.94 cm3 Puck l 1/31/2018 1012 HTD None 0.0"-0.5" Laboratory: Date Submitted To Lab: Ship Container No.: Cooler Temperature: Airbill Number:

Eberline Labs NIA NIA Relinquished by: Date Time: Received by: Date: (nun/dd/yyyy): Time:

(nun/dd/yyyy):

J. ALEX BOHACHEFF 1-=?1-ri /J./.':?f 1rJJa n+ fr JZ/cktr 'I OJ /3// 7.0f'&

Date: (1mri/dd/yyyy):

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Time:

Time: Received by:

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Relinquished by: Date (m1n/dd/yyyy):

. ()/ ~3 (~ ZtJ}g I 6;'()() fe,J fx_ OJ/31/20/x ft;oo Relinquished by:

Relinquished by:

Date (1mn/dd/yyyy):

Date Time:

Time:

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Da'te: (mm/dd/yyyy):

J.-1-/g' Date: (nun/dd/yyyy):

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Comments ANALYSIS 5 ROC-HTD RE: Email to Mike McDougall PRIORITY 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> turnaround PO# 677118

[201]

EBERLINE ANALYTICAL CORPORATIOf\1 601 SCARBORO ROAD BERLINE OAK RIDGE, TENNESSEE :57830 SERVICES PHONE (865) 481-068:5 FAX (865) 483-4621 EBS-OR-43352 February 13, 2018 Alex Bohacheff Zion Solutions, LLC 101 Shiloh Blvd Zion, IL 60099 CASE NARRATIVE Work Order# 18-02009-0R SAMPLE RECEIPT This work order contains thirteen solid samples received 02/02/2018. Samples were analyzed for Total Strontium, Tritium, Nickel-63 and by Gamma Spectroscopy.

CLIENT ID LAB ID CLIENT ID LAB ID Bl021 l01FIWC001CV 18-02009-04 B102110FIWC019CV 18-02009-11 B 102110IFIWC003CV 18-02009-05 B 10211 OFIWC020CV 18-02009-12 B 102110IFIWC004CV 18-02009-06 Bl02110FIWC014CV 18-02009-13 B 10211 OFIFC003CV 18-02009-07 B102l 10FIWC018CV 18-02009-14 B 10211 OFIFC021 CV 18-02009-08 B102l l0FIWC0l6CV 18-02009-15 Bl02110FIWC015CV 18-02009-09 Bl02l l0IFIWC019CV 18-02009-16 B 102110FIWC017CV 18-02009-10 ANALYTICAL METHODS Total Strontium was analyzed using EIChroM Method SRWOl Modified. Tritium was performed using Method LANL ER-210 Modified. Nickel-63 was performed using Method ASTM 3500-Ni Modified.

Gamma Spectroscopy was performed using EPA Method 901. 1 Modified.

Laboratory qualifiers are as follows:

U - Result is less than the MDA.

ANALYTICAL RESULTS Combined Standard Uncertainty is reported at 2-sigma value.

Minimum Detectable Activity (MDA) values for data represented in this report are sample-specific.

MDA measurements are determined based on factors and conditions including instrument settings, aliquot size and matrix type.

Page 1 of 3

[202]

ANALYTICAL RESULTS CONTINUED TOT AL STRONTIUM Samples were prepared by aliquoting as appropriate and leaching in HN0 3

  • Samples were diluted appropriately. Strontium recovery carriers were added to each sample. Chemical separations were conducted using selective extractions. Strontium precipitate was mounted on tared filter media. Chemical recovery was determined by Strontium carrier mass determinations. Samples were counted by gas flow propmtional counting and corrected for Yttrium-90 ingrowth.

Samples demonstrated acceptable results for all Total Strontium analyses. Strontium-90 results are repmted from Total Strontium. Chemical recovery was acceptable for all samples. The Total Strontium method blank demonstrated an acceptable result. Results for the Total Strontium duplicate demonstrated a high relative percent difference; however, normalized difference is within acceptable limits for the analytical technique. Results for the Total Strontium laboratory control sample demonstrated an acceptable percent recovery.

TRITIUM A representative aliquot of each sample was equilibrated with Tritium free water. Equilibrates were transferred into round-bottomed distillation flasks and attached to single stage stills. A portion of each middle distillation fraction was transferred to a liquid scintillation vial and cocktail was added. Samples were then counted by beta liquid scintillation.

Samples demonstrated acceptable results for all Tritium analyses. The Tritium method blank demonstrated an acceptable result. Results for the Tritium duplicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Tritium laboratory control sample demonstrated an acceptable percent recovery.

NICKEL-63 A representative aliquot of each sample was leached in HN0 3

  • Leachates were placed in an appropriately sized beaker. Stable elemental Nickel carrier was added to each sample prior to digestion. Samples were digested in concentrated Nitric acid. After digestion, sample pH was adjusted and Nickel-63 was precipitated selectively with Dimethylglyoxime. Precipitates were selectively separated, redissolved and residual acid was effectively neutralized. Sample residuals were placed into scintillation vials, scintillation cocktail was added and Nickel-63 activity was determined by beta liquid scintillation.

Samples demonstrated acceptable results for all Nickel-63 analyses. All results demonstrated slightly high method detection limits. The Nickel-63 method blank demonstrated an acceptable result. Results for the Nickel-63 duplicate demonstrated a high relative percent difference and normalized difference. Results for the duplicate sample were biased positive because of chemical interferences. Due to this condition only results from the duplicate original sample should be used for all intents and purposes. Results for the Nickel-63 laboratory control sample demonstrated an acceptable percent recovery.

GAMMA SPECTROSCOPY Samples for Gamma Spectroscopy analysis were prepared by transferring a known mass/aliquot of each homogenized sample to a standard geometry container. Samples were counted on High Purity Germanium (HPGe) gamma ray detectors.

Page 2 of 3

[203]

ANALYTICAL RESULTS CONTINUED GAMMA SPECTROSCOPY CONTINUED Samples demonstrated acceptable results for all gamma-emitting radionuclides as reported. Some results demonstrated slightly high method detection limits. Some sample results are greater than the method detection limits. These results are rep01ted from the Canberra Gamma Apex "Nuclide MDA Report" and are not positive. These results are qualified as non-detect (U). The method blank demonstrated acceptable results for all radionuclides as reported. Results for the Cobalt-60, Cesium-137 and Europium-152 replicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Cobalt-60 and Cesium-137 laboratory control sample demonstrated an acceptable percent recovery.

CERTIFICATION OF ACCURACY I ce1tify that this data report is in compliance with the terms and conditions of the Purchase Order, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the cognizant project manager or his/her designee to be ccu ate as verified by the following signature .

......"~,..

' , .....- ~ -10 M.R. McDougall Laboratory Manage!"

Date: 2/13/2018 Eberline /\nalytieal wants and encourages your feedback regarding our performance providing radioanalytieal services. Please visit http://eberlineanalytical.com/ to provide us with i'eedback on our services.

Page 3 of 3

[204]

Printed: 211312018 8:54 AM Page 1 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical Zion Solutions, LL~_

SDG:

Purchase Order: 677118 Final Report of Analysis ,--- 101 Shiloh Blvd Analysis ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier

Units 18-02009-01 LCS KNOWN 02/02/18 00:00 2/2/2018 2/5/2018 18-02009 Tritium LANL ER-210 Modified 226E+02  : 8.14E+OO pCi/g

,------------------,~-------s,~,_-m, ________ '"""

18-02009-01 LCS SPIKE 02/02/18 00:00 212/2018 21512018 18-02009 Tritium LANL ER-210 Modified 2.17E+02 7.97E+OO 1.45E+01 5-53E+OO pCilg

' ,__,o_,_,m, _ _ _ , _ , , , _ , ~ - - - - - - - -

  • 18-02009-02 MBL BLANK 02102/18 00:00 21212018 21512018 18-02009 Tritium LANL ER-210 Modified : -U2E+OO 3.04E+OO 3.04E+OO 5.36E+OO u pCi/g 18-02009-03  : DUP B102110IFIWC001CV 01/31118 13:20 2/2/2018 2/512018 18-02009 Tritium LANL ER-210 Modified : 8.78E+01 1-61E+01 1-69E+01 227E+01 pCilg

-10 " " " " " l"\A l  :

DO B102110IF1WC001CV 01131/1813:20 212/2018 21512018 18-02009 Tritium LANL ER-210 Modified i 8-33E+01  : 1.63E+01 UOE+01 2.33E+01 pCi/g 18-02009-05 TRG B102110IF1WC003CV 01/31/18 13:55 18-02009 ;

--*------- *----- ------ ' 212/2018 2/5/2018 Tritium LANL ER-210 Modified 1-13E+02 1.48E+01 1.61E+01 1.92E+01 pCi/g an M TRG B102110IFIWC004CV 01131118 14:20  : 212/2018 21512018 18-02009 Tritium LANL ER-210 Modified 120E+02  : U7E+01 1-89E+01 2-37E+01 pCi/g I

18-02009-07 TRG B102110FIFC003CV 01131118 12:37  : 2/212018 2/512018 18-02009 : Tritium LANL ER-210 Modified 1-69E+02 2.04E+01 2.25E+01 2.59E+01 pCi/g 18-02009-08 TRG 610211 OFIFC021 CV 01/31/18 13:00 j 2/2/2018 2/5/2018 18-02009 : Tritium LANL ER-210 Modified 129E+02 1 -88E+01  : 2.01E+01 2.52E+01 pCilg 18-02009-09 TRG B102110FIWC015CV 01/31/18 14:43 2/2/2018 2/5/2018 18-02009 I Tritium LANL ER-210 Modified 122E+02 1-62E+01 U5E+01 2.11E+01 pCi/g

~-------- ----"--------*------------  :

18-02009-10 l TRG B102110F1WC017CV 01/31/18 15:07 i 2/2/2018 2/5/2018 18-02009 Tritium LANL ER-210 Modified 121E+02  : 1.52E+01 1.67E+01 1.95E+01 pCi/g 18-02009-11 TRG B102110FIWC019CV ,, ____ ------

01/31/18 15:30 i 2/2/2018 2/5/2018 18-02009 ' Tritium LANL ER-210 Modified 3.86E+02 i 2.19E+01 3.08E+01 2.02E+01 pCi/g 18-02009-12 TRG B102110FIWC020CV 02/01/18 08:12  ! 2/2/2018 2/5/2018 18-02009 Tritium LANL ER-210 Modified : 228E+02 2.33E+01  : 2.66E+01 2.80E+01 pCi/g I

18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56  ! 2/2/2018 2/512018 18-02009 Tritium LANL ER-210 Modified 1-52E+02 1.94E+01 2.12E+01 2.50E+01 pCilg 18-02009-14  : TRG I

B102110FIWC018CV 02101118 09:38 21212018 21512018 18-02009 Tritium LANL ER-210 Modified

. """"' *- / ------' 1.52E+02 1.82E+01 2.01E+01 2.31E+01 pCi/g

-15 TRG B102110FIWC016CV 02/01/18 10:00 i 21212018 : 2/5/20 i8 18-02009 ' Tritium LANL ER-210 1.53E+01 1.64E+01 2.05E+01 pCi/g 18-02009-16 TRG B102110IFIWC019CV 02/01/18

""""'"""_,_,___,_,____ , 2/2/2018 ' 2/5/2018 18-02009

__,,_ * ,,,,,__,,,,,,_,,,_,__ m*=-*-*--'~*-*--*** Tritium LANL ER-210 Modified ; 2.46E+02 2.14E+01 ' 2.55E+01 2.42E+01 pCi/g 18-02009-01  : LCS KNOWN 02/02/18 00:00  : 2/2/2018 : 2/5/2018 ___________________

18-02009  : Nickel-63" _______ ASTM 3500-Ni Modified ; 1.49E+03 : 4.46E+01 pCilg 18-02009-01 i LCS

  • SPIKE 02/02/18 00:00  : 2/2/2018 2/5/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified 1.45E+03 : 9.42E+OO 8.55E+01 2.26E+OO pCi/g 18-02009-02 MBL  : BLANK 02/02/18 00:00 2/2/2018 , 2/5/2018 18-02009 f Nickel-63 ASTM 3500-Ni Modified -4.88E-01 1.36E+OO 1.36E+OO 2.35E+OO u pCi/g 18-02009-03 ! DUP B102110IF1WC001CV 01/31/18 13:20 2/2/2018 2/5/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified ' 3.36E+OO 5.32E+OO  : 5.32E+OO 8.98E+OO u i pCi/g 18-02009-04 i DO B102110IFIWC001CV 01/31/18 13:20 2/2/2018 ' 2/5/2018 18-02009 ' Nickel-63 ASTM 3500-Ni Modified : 3.36E+OO i 5.32E+OO  : 5.32E+OO 8.98E+OO u pCi/g

,x.<1,0 *~ i B102110IFIWC003CV 01/31/18 13:55 i 2/2/2018 2/5/2018 18-02009 ' Nickel-63 ASTM 3500-Ni Modified i 2.83E+01 5.29E+OO  : 5.55E+OO 8.02E+OO pCi/g 18-02009-06 TRG B102110IF1WC004CV 01/31/18 14:20  : 2/2/2018 2/5/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified 1.62E+01 4.90E+OO , 4.99E+OO 7.78E+OO pCi/g 18-ULUU~-07 ; TRG B102110FIFC003CV 01/31/18 12:37 2/2/2018 2/5/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified 3.11E+OO 5.53E+OO 5.54E+OO 9.36E+OO u pCi/g n

-*~---~--.---

Mi TRG B102110FIFC021CV 01/31/18 13:00  : 2/2/2018 2/6/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified : 4.27E+OO 5.09E+OO 5.10E+OO 8.56E+OO u pCi/g 18-02009-09 ; TRG B102110FIWC015CV 01/31/18 14:43 2/2/2018 2/6/2018 18-02009 : Nickel-63 ASTM 3500-Ni Modified 6.91E+OO i 5.00E+OO 5.02E+OO 8.31E+OO u pCi/g 18-02009-10 ' TRG B102110FIWC017CV 01/31/1815:07 2/2/2018 2/6/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified -8.12E-01 5.68E+OO 5.68E+OO 9.76E+OO u pCi/g 18-02009-11  : TRG B102110FIWC019CV 01/31/18  : 2/2/2018 2/6/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified 9.28E+OO 5.64E+OO 5.66E+OO 9.30E+OO u pCi/g

' B 10211 OFIWC020CV 02/01/18 08:12 2/6/2018 18-02009 i 18-02009-12 : TRG  ! 2/2/2018 Nickel-63 ASTM 3500-Ni Modified 1.51E+01  : 5.52E+OO 5.59E+OO 8.88E+OO : pCi/g 18-02009-13 ' TRG B102110F1WC014CV 02/01/18 08:56 i 2/2/2018 2/6/2018 18-02009 ' Nickel-63 ASTM 3500-Ni Modified : 5.61E+OO 4.76E+OO 4.77E+OO 7.94E+OO u pCi/g 18-02009-14 i TRG i B102110FIWC018CV 02/01/18 09:38  ; 2/2/2018 2/6/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified 3.75E+OO 5.94E+OO 5.94E+OO 1.00E+01 u pCi/g

,,=*-,,---------

18-02009-15 TRG B102110FIWC016CV 02/01/18 10:00 ' 2/2/2018 2/6/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified : O.OOE+OO 5.57E+OO 5.57E+OO 9.54E+OO u pCi/g

~-~-~---------

18-02009-16 TRG B102110IF1WC019CV 02/01/18 10:38 2/2/2018 2/6/2018 18-02009 Nickel-63 ASTM 3500-Ni Modified 3.69E+OO 5.27E+OO  : 5.27E+OO 8.88E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE AL YTICAL CORPOR.ATION

[205]

' 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621

Printed: 2/13/2018 8:54 AM Page 2 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical , ...

Zion Solutions, LLC...... _________ _______________

SDG:

Purchase Order: . 677118

--,c~ ,_,,

Final Report of Analysis 101 Shiloh Blvd Analvsis c~::;;;:;. ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Sample i Lab Sample Client Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier i  : Units 18-02009-01 LCS KNOWN 02/02/18 00:00 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 5.36E+01 3.00E-01 pCi/g i----*--*--*--*

18-02009-01

,,, ,,_, SPIKE

----- f------

02/02/18 00:00 2/2/2018

"*"-~"-----------*---~-----------,

2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 5.75E+01 2.36E+OO 2.02E+01 1.08E+OO pCi/g 18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 5.75E-01 5.38E-01 5.74E-01 8.90E-01 u pCi/g

  • - - I-18-02009-03 DUP 8102110IFIWC001CV

--"'------- """"""'-----------------------~ ------- *------

01/31/1813:20 ,,, ________ ______________.,_,~,,-----*--

2/2/2018 ,.,,. 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified -6.26E-02 .

4.09E-01 4.10E-01 7A2E-01  : u pCi/g 18-02009-04 DO B102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified : 4.72E-01 3.75E-01 4.09E-01 6.09E-01 u pCi/g

-~--*----------------*------------,----*""'"'"'

18-02009-05 TRG 1----------------~---------,,--_., 8102110IFIWC003CV

___________ , ,_______________ --*- 01/31/1813:55 2/2/2018

___________,,__,,___~------------ 2/6/2018 18-02009

---~ Strontium-90 EIChroM SRW01 Modified 5.50E-01 4.14E-01 4.57E-01 6.72E-01 u pCi/g 18-02009-06 F""""'-~--------~ -----

TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018

-*-----*~_,,,_;_,_____~--------*,----*,--", ..........,:

2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 6.88E-01 5.02E-01 . 5.56E-01 8.15E-01 u pCi/g 18-02009-07 TRG B102110FIFC003CV 01/31/18 12:37 2/2/2018 2/6/2018 18-02009 ; Strontium-90 EIChroM SRW01 Modified 2.09E-01 : 5.09E-01 5.14E-01 8.86E-01 u pCi/g 18-02009-08 :

  • ---m=,_,,,

TRG 8102110FIFC021CV 01/31/18 13:00

'.--*--*-"==---*----*=------*-'""*=--*------*---* ~ r----*---w.--m,,_ *'""'

2/2/2018 ,,,,, _____

2/6/2018

_______ ~ ___ ,,,_

18-02009 Strontium-90 EIChroM SRW01 Modified i 6.83E-01 : 4.51E-01 5.10E-01 7.18E-01 u pCi/g 18-02009-09 TRG 8102110FIWC015CV 01/31/18 14:43 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified : 4.50E-01 4.42E-O 4.69E-01 7.35E-01 u pCi/g 18-02009-10

--**-----*~ ___

TRG ,:_, ________

8102110FIWC017CV ___ " _______ 01/31/1815:07 2/2/2018 2/6/2018 18-02009 : Strontium-90 EIChroM SRW01 Modified 5.13E-01 4.98E-01  : 5.29E-01 8.27E-01 u pCi/g 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 9.00E-01 i 4.96E-01 5.87E-01 7.74E-01 : pCi/g

. B 10211 OFIWC020CV 02/01/18 08:12 2/2/2018 2/6/2018 18-02009 ' Strontium-90 EIChroM SRW01 Modified 5.64E-01 : 4_16E-01  : 4.60E-01 6.72E-01 u pCi/g

02009-13 TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 3.55E-01 4.39E-01 4.56E-01 7.41E-01 : u pCi/g 18-02009-14 ; TRG
  • 8102110FIWC018CV 02/01/18 09:38 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 4.56E-01 : 4.55E-01 4.81E-01 7.57E-01 u pCi/g 18-02009-15 .......,' TRG ,, 8102110FIWC016CV

~--

02/01 /18 10:00 2/2/2018 2/6/2018 18-02009 Strontium-90 EIChroM SRW01 Modified 5.59E-01 : 5.06E-01 5.42E-01 8.35E-01 u pCi/g 18-02009-16 TRG 81021101FIWC019CV 02/01/18 10:38 2/2/2018__ 2/6/2018 18-02009 i _,,, ___

Strontium-90 EIChroM SRW01 Modified 1.77E-01 4.90E-01  : 4.93E-01 8.54E-01 u pCi/g l  :

*-----~------*------

18-02009-01 LCS KNOWN 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA 901.1 Modified 2.71E+02 1.06E+01  : pCi/g 18-02009-01 LCS KNOWN 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 : Cesium-137 EPA 901.1 Modified 1.69E+02 6.75E+OO .. pCi/g an na LCS SPIKE 02/02/18 00:00  : 2/2/2018 2/2/2018 18-02009 , Cobalt-60 EPA 901-1 Modified 2.89E+02 1.78E+01 2.32E+01 2.27E+OO pCi/g 18-02009-01 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901.1 Modified 1.91E+02 3.15E+01 3_30E+01 2,33E+OO  :

LCS SPIKE  : pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE ALYT!CAL ON 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/ 481-0683 FAX 865/483-4621 [206]

Printed: 2/13/2018 8:54 AM Page 3 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical _____ Zion Solutions, LLC ________ --*

SOG:

Purchase Order: 677118

  • - ""-'"'"-,-~---

Final Report of Analysis 101 Shiloh Blvd Analysis Category: ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report Date Analyte Method Result cu CSU MDA Qualifier ID Type ID Date Date ID Units 18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA 901-1 Modified 5AOE-02 1AOE-01 1AOE-01 2A2E-01 u pCi/g 18-02009-02 ___________

,---*-----'---------~------------ '

,,;; MBL BLANK

~""'"" _____ ___,,,,_,,_____, - *- 02/02/18 00:00 2/2/2018 2/2/2018

  • ----------~-----*-------

18-02009'""" __ ,_,, ____

00,v~, * ,uoH, EPA901.1 Modified -3A6E-02 5A2E-02 i 5A2E-02 4.97E-02 u pCi/g 18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901. 1 Modified -3A2E-03 1.56E-02 1.56E-02 6.45E-02 u pCi/g

  • - ---- -- *--*-s----- ---~

18-02009-02 ' MBL BLANK 02/02/18 00:00

_ _ _ _ ,____ ,,,,,,,,=-*--2/2/2018 2/2/2018 18-02009 Barium-133 EPA 901.1 Modified -1A9E-02 4.28E-02 4.28E-02 6.27E-02 u pCi/g

~------*-----*------------- ----------- ---**--------- ----

18-02009-02 . MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 : Bismuth-214 EPA 901. 1 Modified  : 4.35E-02 8A1E-02  : 8A1E-02 1A5E-01 u pCi/g

-~--- .

18-02009-02 :

MBL BLANK ,-----~_,, ________ 02/02/18 00:00 2/2/2018 2/2/2018 18-02009

-~--,--------* .,,,,

Cobalt-60 EPA 901. 1 Modified -1.88E-02 4.67E-02 4.67E-02 5.14E-02 u pCi/g 18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA901.1 Modified -1.08E-02 4.30E-02

' 4.30E-02 6.30E-02 u pCi/g

-*--------*------------,--------------------~------, -- ,m_,e_, _ _ _ _ _ V _______-

,-------,-,-------~---*-

18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901. 1 Modified 4A4E-02 . 3.81E-02 3.82E-02 7A8E-02 u pCi/g 18-02009-02

  • MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 ,  ::::u, -,*-* "- i 52 EPA 901.1 Modified i 4.66E-02 1.25E-01 1.25E-01 1.12E-01 u pCi/g

-10 "'-'"'"'"' fVl  :

MBL BLANK 02/02/18 00:00 2/2/2018

. 2/2/2018 2/2/2018 18-02009 ~~.-,.~:- 154 EPA 901. 1 Modified i -9.79E-02 : 1.13E-01 1.13E-01 5.91E-02 u pCi/g 18-02009-02  ! MBL BLANK 02/02/18 00:00

,--~--

2/2/2018 18-02009 Europium-155 EPA 901.1 Modified . -2.76E-02 . 3A7E-02 3A7E-02 6A3E-02 u pCi/Q 18-02009-02

  • MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA 901. 1 Modified  ! -3.89E-02 9.36E-02 9.37E-02 4.28E-02 u pCi/g 18-02009-02 : MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 i lodine-129 EPA 901.1 Modified / 1.60E-02 6.74E-02 . 6.74E-02 1.04E-01 u pCi/g 18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Potassium-40 EPA 901. 1 Modified I -4.04E-03 : 3.14E-01 3.14E-01 5.82E-01 u pCi/g

---'------- i  :

18-02009-02 ; MBL  : BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 ; iL .. ,_.. ___ ' EPA 901.1 Modified 1A3E-02 3.96E-02 3.96E-02 6.59E-02

' u pCi/g

, o _n?nna. M [

MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 i Niobium-94 EPA 901.1 Modified 6.20E-03 1.54E-02 1.54E-02 6.22E-02 u pCi/g 18-ULUW-02 / MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 i Lead-210 EPA901.1 Modified  ; 2.46E-01 : 4.79E-01 4.79E-01 7A8E-01 u pCi/g

-~------,  :

18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 , Lead-212 EPA 901.1 Modified . 4.56E-02 4.61E-02 4.61E-02 7.93E-02 u pCi/g 18-02009-02 MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009

  • Lead-214 EPA901.1 Modified ' 1.65E-03 6.78E-02 6.78E-02 1.06E-01 u pCi/g 18-02009-02 : MBL BLANK 02/02/18 00:00 2/2/2018
  • 2/2/2018 18-02009 ; Promethium-145 EPA 901.1 Modified i 5.17E-03 6.62E-02

. 6.62E-02 1.01E-01

. u pCi/g 18-02009-02 i MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 ' Radium-226 EPA 901. 1 Modified  : 4.35E-02 8.41E-02 8A1E-02 1A5E-01 . u pCi/g 18-02009-02

~----i MBL BLANK 02/02/18 00:00 . 2/2/2018 2/2/2018 18-02009 ' Antimony-125 EPA 901. 1 Modified i 7.14E-03

  • 4.55E-02 4.55E-02 1.SOE-01 u . pCi/g

--18-02009-02 18-02009-02 :

MBL MBL BLANK BLANK 02/02/18 00:00 02/02/18 00:00 2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02Q09 i i Thorium-234 Tham,*- OM EPA 901.1 Modified EPA 901. 1 Modified 4.65E-01 6.76E-02 4A5E-01 1.07E-01 i

4A6E-01 1.07E-01 7.29E-01 1.93E-01 u

u pCi/g pCi/g 18-02009-02 ; MBL BLANK 02/02/18 00:00 2/2/2018 2/2/2018 18-02009 Uranium-235 EPA 901.1 Modified  ! 1.06E-01 3A1E-01 3A1E-01 2.33E-01 u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect I

I EBERLINE ANALYTICAL CORPOR1~ TION I 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [207]

Printed: 2/13/2018 8:54 AM Page 4 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical .,.,..........

SDG:

,-,,~---- Zion. Solutions, LLC **- _____ ---------*---, ,,, ,_,__v,,,--,~, _ , , _

- i***---*

Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd .J.----** ENVIRONMENTAL

- .. Analysis .... '.":',[';!..!.:..

so Zion, IL 60099 Sample Matrix:

Lab Sample Client Sample Receipt Analysis ' Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier

' Units 18-02009-03 DUP r-""'----*-*------~-...,....,----

81021101FIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA901.1 Modified 7.76E-01 1.91E+OO 1.91E+OO 3.18E+OO u pCiiQ 18-02009-03 DUP B102110IFIWC001CV

"-"v---,---* -*-*-------* ---------*-*-----,--,---------

01/31/18 __________ 2/2/2018

__, 13:20 21212018 18-02009 Silver-108m EPA901.1 Modified ' 7.85E-01 6.43E-01 6.45E-01 6.01E-01 u pCi/g 18-02009-03 DUP B102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Americium-241 EPA901.1 Modified -1.23E+OO 6.92E-01 6.95E-01 8.02E-01 u pCi/Q 18-02009-03 : DUP B102110IFIWC001CV 01/31/1813:20 2/212018 2/2/2018 18-02009 , Barium-133 EPA 901. 1 Modified -2.32E+OO 7.14E-01 7.24E-01 8.14E-01 u pCi/g 02009-03

-*-- -~--~----*--------

DUP 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA 901.1 Modified 6.42E-01 1.06E+OO 1.06E+OO 1.58E+OO u pCi/Q

..--*--*--------*'---*-~-*--------~------*----*--- --------,,,-----*------*- ***------*---------~------

18-02009-03 DUP 81021101FIWC001CV 01/31/18 13:20 2/2/2018 212/2018

---..---.-------- m>>.-**""""-*"*-------------*----

18-02009 Cobalt-60 EPA 901.1 Modified  : 1.74E+01 1.22E+OO 1.51E+OO 8.80E-01 pCi/g 18-02009-03 DUP 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 , 2/2/2018 18-02009 : Cesium-134 EPA901.1 Modified  : -8.82E-02 ' 5.04E-01 5.04E-01 7.26E-01 u pCi/Q 18-02009-03 OUP B102110IFIWC001CV 01/31/18 ______

_,_,,,13:20 2/2/2018

.. ,,w , _ _ _ _ _ _ _ _ _ _ _ _ _ ,, _ _18-02009

_- ______ .__.,.. _ _ Cesium-137

_ _ _ _._.,, EPA 901. 1 Modified  : 2.21E+OO

' 8.16E-01 8.24E-01 1.19E+OO pCi/g

________..____DUP.... ____-----"*----

02009-03 18-02009-03 ,,, DUP 81021101FIWC001CV

.. ~*------,----~----*--..--*-*-

B1021101FIWC001CV 01/31/18 13:20 01/31/1813:20 212/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02009

c:c 0 ,_,, ,. 152 Europium-154 EPA 901.1 Modified EPA 901. 1 Modified i

1.60E+02 6.57E+OO i 7.25E+OO 1.46E+OO 1.10E+01 1.50E+OO 3.27E+OO 2.58E+OO u pCi/Q pCiig 18-02009-03 OUP 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 --*

CC, --

  • a*-* 155 EPA901.1 Modified l 1.33E+OO 9.25E-01 9.27E-01 1.47E+OO u pCi/Q 18-02009-03 ; DUP 81021101FIWC001CV 01/31/18 13:20 2/2/2018 ' 2/2/2018 18-02009 Holmium-166m EPA 901.1 Modified  : 5.04E-01 9.40E-01 9.40E-01 5.18E-01 u pCi/g 18-02009-03 DUP 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 : lodine-129 EPA 901. 1 Modified 1.47E+OO 3.80E-01 3.87E-01 1.49E+OO u . pCiig

- - - ..*-*--*-----*---..--,---*-*..--------" i 18-02009-03 DUP B102110IFIWC001CV 01/31/1813:20 2/2/2018 2/2/2018 ' 18-02009 Potassium-40 EPA 901.1 Modified 5.06E+OO 3.50E+OO 3.51E+OO 6.82E+OO u pCi/g 18-02009-03 : DUP 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 C EPA 901.1 Modified ' -5.95E-02  : 5.53E-01 5.53E-01 8.00E-01 u pCiig 18-02009-03 DUP ____ _________

B102110IFIWC001CV 01/31/18 13:20

___- 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA 901. 1 Modified -1.52E+OO

' 8.68E-01 8.71E-01 7.53E-01 u pCi/g

. .....~-------------------*-----***------------* i 18-02009-03 DUP B1021101FIWC001CV 01/31/18 13:20 2/2/2018 .,. 2/2/2018 18-02009 Lead-210 EPA 901.1 Modified  : 2.79E+02 2.37E+01 ' 2.77E+01 1.88E+01 u pCiig

- *-*---,------ ~------*..---- >--* .,,, *--~----------

18-02009-03 DUP 81021101FIWC001CV 01/31/18 13:20 ' 2/2/2018 2/212018 18-02009 Lead-212 EPA 901. 1 Modified  : 4.21E-01 5.84E-01 5.85E-01 9.39E-01 u pCi/g 18-02009-03 : OUP B1021101FIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 , Lead-214 EPA 901.1 Modified l 2.75E+OO 1.06E+OO 1.07E+OO 1.61E+OO u pCi/g 18-02009-03 DUP B1021101FIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Promethium-145 EPA901.1 Modified 5.25E+OO 1.90E+OO 1.92E+OO 2.44E+OO u pCi/g

- * - - -..=*-*----*- ------------------~-- _, __,__,,,,_,,_,___..,_w~-------------,,,_____,,.,,_,_,,, . __ _.,.,,,=-*-*-,w, i'

18-02009-03 DUP B102110IFIWC001CV 01/31/1813:20 2/2/2018 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified 6.42E-01 1.06E+OO 1.06E+OO 1.58E+OO u pCi/g 18-02009-03

......,._.__ OUP B1021101FIWC001CV 01/31/18 13:20 2/2/2018 212/2018 18-02009 Antimony-125 EPA 901.1 Modified -4.83E-01 1.25E+OO 1.25E+OO 1.79E+OO u pCiig 18-02009-03 DUP  : 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 i Thorium-234 EPA 901.1 Modified i 4.65E+OO 6.75E+OO 6.75E+OO 8.73E+OO u pCi/g 18-02009-03 DUP B102110IFIWC001CV 01/31/18 13:20 i 2/212018 ' 2/2/2018 18-02009 ' Thallium-208 EPA 901.1 Modified i 1.67E+OO 1.65E+OO  : 1.65E+OO 1.45E+OO u pCi/g 18-02009-03 ' DUP 8102110IFIWC001CV 01/31/1813:20 2/2/2018 2/2/2018 18-02009 Uranium-235 EPA 901. 1 Modified

' -3.06E-01 4.98E+OO 4.98E+OO 3.22E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERVJCES EBERUNE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [208]

Printed: 2/13/2018 8:54 AM Page 5 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical '

___,,_ ..... Zion Solutions,_LLC -**-********-*** ----*-

SOG:

Purchase Order: 677118 Final Report of Analysis ,_____ 101 Shiloh Blvd Analvsis Category: ENVIRONMENTAL so Zion, IL 60099 Sample Matrix:

Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02009-04 DO 8102110IFIWC001CV

...... f- 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA 901.1 Modified  : 1.75E+OO 2.03E+OO 2.04E+OO 3.09E+OO u pCi/g 18-02009-04 DO B102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901.1 Modified 7.08E-01 6.13E-01 6.14E-01 5.67E-01 u pCi/g 18-02009-04 DO . 810211 OIFIWC001 CV 01/31/18 13:20 . 2/2/2018 2/2/2018 18-02009 Americium-241 EPA901.1 Modified  : -3.90E-01 6.47E-01 6.47E-01 7.99E-01 u  : pCi/g 18-02009-04

,,,,,,. DO 8102110IFIWC001CV

  • 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Barium-133

,,,,,,, _ _ .,, _ _ _ _ _ _ , _ _ _,._.,.,. _ _ _ _ _ _ _ _ ,,,,,,.,,,.a,,, _ _ ,,,,,,,,,,,"-**-*-*w* ______ ,,,_,,,,

EPA 901.1 Modified -9.45E-02 2.72E-01 2.72E-01 8.08E-01 u pCi/g 18-02009-04 DO 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA 901.1 Modified 2.03E-01 1.01E+OO 1.01E+OO 1.48E+OO u pCi/g 18-02009-04 DO 81021101FIWC001CV 01/31/1813:20 2/2/2018 2/2/2018 18-02009 Cobalt-SO EPA 901.1 Modified 1.51E+01 1.09E+OO 1.34E+OO 8.04E-01 pCi/g

--*-----*--*--*-* ,,,,,,.,,,,,,,,,,,,,, _ _ ,_,,,,,,,,,,_,,,,,, ' " ' " " - ~ w - - -

1"-Mnna n DO 8102110IFIWC001CV 01/31/18 13:20 I 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA901.1 Modified -4.15E-01 4.87E-01 4.87E-01 6.74E-01 u pCi/g

---** ----------*----***--~*-*---------------*  :

18-02009-04 DO 8102110IFIWC001CV 01/31/1813:20 2/2/2018

  • 2/2/2018 18-02009 Cesium-137 EPA 901.1 Modified 2.48E+OO 9.07E-01 9.16E-01 1.32E+OO I pCi/g 18-02009-04 ' DO 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 : 2/2/2018 18-02009 Europium-152 EPA 901.1 Modified  : 1.55E+02 6.36E+OO 1.02E+01 3.34E+OO pCi/g 18-02009-04 DO 81021101FIWC001CV 01/31/1813:20 2/2/2018 2/2/2018 18-02009 Europium-154 EPA901.1 Modified 6.87E+OO 1.44E+OO 1.48E+OO 2.55E+OO u pCi/g 18-02009-04 DO ____ ,,,,. _______ .,_,,

8102110IFIWC001CV _____ _____ 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified 9.86E-01 8.77E-01 8.78E-01 1.40E+OO u pCi/g

-*------~---*-*-

18-02009-04

  • DO 81021101FIWC001CV 01131/18 13:20  : 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA901.1 Modified

': 7.86E-01 . 8.94E-01 8.95E-01 5.13E-01 u pCi/g

- * - - /"\A DO 81021101FIWC001CV 01/31/1813:20  : 2/2/2018 , 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified 1.26E+OO 3.39E-01 3.45E-01 1.51E+OO u pCi/g 18-02009-04 DO 81021101FIWC001CV 01/31/18 18-02009 Potassium-40 EPA 901.1 Modified 6.78E+OO 2.89E+OO 2.91E+OO 9.53E+OO u pCi/g

... _.."_ .. ___ - I 18-02009-04 DO 81021101FIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 , 18-02009 EPA 901.1 Modified -5.69E-02 5.27E-01 5.27E-01 7.66E-01 u pCi/g 18-02009-04

...---.--------~--

DO B 10211 OIFIWC001 CV 01/31/18 3:20 i 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA 901.1 Modified

' -1.81E+OO  ! 8.53E-01 ' 8.59E-01 7.18E-01 u . pCi/g

--**----------* --*--*---*---*-*-'"'-- --~,---~ ------,----------*:---*-------------~-*--- ' ---  :

18-02009-04 DO 8102110IFIWC001CV 01/31/1813:20 2/2/2018 2/2/2018 18-02009 Lead-210 EPA 901.1 Modified 2.40E+02 2.09E+01 2.43E+01 1.77E+01 u I pCi/g

- . - - -.. --4-----. ------* ---~----,------- *------,--------------*---*---m--,-,-,o,--~--A-*

18-02009-04 , ______

DO 81021101FIWC001CV 01/31/18 13:20 i 2/2/2018 2/2/2018 18-02009 Lead-212 EPA 901.1 Modified 3.59E-01 : 5.58E-01 i 5.58E-01 8.95E-01 u pCi/g 18-02009-04 DO 81021101FIWC001CV 01/31/18 1320 i 2/2/2018 2/2/2018 18-02009 Lead-214 EPA 901.1 Modified 2.00E+OO 8.77E-01 8.83E-01 1.64E+OO pCi/g 18-02009-04 DO 81021101FIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 1

Promethium-145 EPA 901.1 Modified 4.33E+OO 1.79E+OO 1.80E+OO 2.29E+OO u pCi/g 18-02009-04  :' DO 81021101FIWC001CV 01/31/18 13:20 I 2/2/2018 , 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified  ! 2.03E-01 1.01E+OO 1.01E+OO 1.48E+OO u pCi/g 18-02009-04 DO 8102110IFIWC001CV 01/31/1813:20 i 2/2/2018 : 2/2/2018 18-02009 Antimony-125 EPA 901.1 Modified -1.20E-01 1.19E+OO  : 1.19E+OO 1.72E+OO u pCi/g

  • n n
DO 81021101FIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Thorium-234

* ,,,,,,~----

EPA 901.1 Modified  ! 7.78E+OO  : 6.28E+OO  : 6.30E+OO 8.33E+OO u ' pCi/g 18-02009-04 l DO . 8102110IFIWC001CV 01/31/18 13:20 2/2/2018 2/2/2018 18-02009 Thallium-208 EPA901.1 Modified  : -1.99E-01 8.20E-01 8.20E-01 1.32E+OO u pCi/g 18-02009-04 : DO 8102110IFIWC001CV 01/31/1813:20 ' 2/2/2018 2/2/2018 18-02009 : Uranium-235 EPA 901.1 Modified ' -2.50E-01 4.85E+OO 4.85E+OO 3.16E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERVICES II EBERUNE ANAL YT!CAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [209]

Printed: 2/13/2018 8:54 AM Page 6 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical *********-

'"_, _____ Zion Solutions, LLC SDG:

Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd Analysis ENVIRONMENTAL so Zion, IL 60099 Sample Matrix:

Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02009-05 TRG 8102110IFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18--02009 Actinium-228 EPA 901.1 Modified i 2.89E-01 1.33E+OO 1.33E+OO 1.98E+OO u pCi/g

/""-------* ____ u 18-02009-05 TRG ,, 81021101FIWC003CV 01/31/1813:55 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901.1 Modified 6.49E-01 : 4.28E-01 4.29E-01 4.35E-01 pCi/g 18-02009-05 , TRG 8102110IFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901.1 Modified -6.91E-02 3.21E-01 i 3.21E-01 4.68E-01 : u pCi/g 18-02009-05 TRG 81021101FIWC003CV

- * * - - - - - - - ~ - - - , _ . , _ _ _ _ _ _ _ _ _ _ _m _ _ _m 01/31/1813:55 2/2/2018 2/2/2018 18-02009 8arium-133 EPA 901.1 Modified -1.64E-02 4.21E-01 4.21E-01 5.37E-01 u pCi/g 18-02009-05 TRG 8102110IFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 8ismuth-214 EPA 901.1 Modified 5.85E-01 7.19E-01  : 7.19E-01 1.20E+OO u pCi/g 18-02009-05 TRG 8102110IFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA 901.1 Modified 4.85E+OO 4.77E-01 5.38E-01 4.42E-01 pCi/g

=------*  : ---*---- ~--------------

18-02009-05 TRG 81021101FIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA 901.1 Modified -1.91E-02 2.59E-01 2.59E-01 4.88E-01 u pCi/g 18-02009-05 ' 8102110IFIWC003CV 01/31/1813:55 2/2/2018 2/2/2018 18-02009 137 EPA 901.1 Modified 3.74E+01 5.90E+OO

pCi/g

**------------~------,,m TRG ___,_,________ --------------  : 6.20E+OO 8.62E-01 18-02009-05 TRG 81021101FIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 Europium-152 EPA 901.1 Modified 1.05E+02 5.49E+OO 7.70E+OO 2.06E+OO pCi/g 18-02009-05 ' TRG 810211 OIFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018

-- 18-02009 LUl~r--*-,11-154 EPA 901.1 Modified 3.88E+OO 9.23E-01  : 9.44E-01 1.68E+OO u  : pCi/g 18-02009-05

 : ___TRG 810211 OIFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 i Europium-155 EPA901.1 Modified i 1.22E+OO i 8.83E-01 8.85E-01 1.42E+OO u pCi/g 18-02009-05 TRG 81021101FIWC003CV 01/31/1813:55 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA 901.1 Modified 6.60E-02 6.38E-01  : 6.39E-01 3.94E-01 u oCi/g 18--02009-05 : TRG 81021101FIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 ; lodine-129 EPA 901.1 Modified 1.07E-01 1.83E-01  : 1.83E-01 2.46E-01 u i pCi/g 18-02009-05 TRG B102110IFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 Potassium-40 EPA 901.1 Modified i 6.76E+OO  ! 1.97E+OO 2.00E+OO 5.06E+OO pCi/g

: 2/2/2018 : 2/2/2018 18-02009-05 / TRG 810211 OIFIWC003CV 01/31/18 13:55 18-02009  ! ***-* *o-* .* ** ' EPA 901.1 Modified i 2.47E-01 : 3.45E-01 3.45E-01 5.25E-01 u pCi/g 18-02009-05 : TRG 8102110IFIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 ' Niobium-94 EPA 901.1 Modified i -2.07E+OO  ! 6.89E-01 6.97E-01 5.00E-01 u pCi/g 18--02009-05 : TRG 81021101FIWC003CV 01/31/18 13:55 i 2/2/2018 2/2/2018 __________

18-02009 .,_, ______ , ___ ._

Lead-210 EPA901.1 Modified  : 1.26E+02  : 1.06E+01 1.25E+01 8.17E+OO pCi/g 18-02009-05 : TRG 81021101FIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 Lead-212 EPA901.1 Modified 4.36E-02 5.35E-01 5.35E-01 6.82E-01 u pCi/g 18-02009-05 : TRG B102110IF1WC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18-02009 i Lead-214 EPA 901.1 Modified 1.29E-01 7.13E-01 i 7.13E-01 9.02E-01 u pCi/g 18-02009-05 TRG 810211 OIFIWC003CV

  • _ _ _ _ ,N _ _ _ _ _ _ " " - " - - ' " "

01/31/18 13:55 2/2/2018 2/2/2018 : 18-02009 , Promethium-145 EPA 901.1 Modified  : -3.87E+01 2.86E+OO 3.49E+OO 8.47E-01 u oCi/Q 18-02009-05 j TRG  : B1021101FIWC003CV 01/31/18 13:55  : 2/2/2018 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified i 5.85E-01 7.19E-01 7.19E-01 1.20E+OO u pCi/g 18-02009-05 i TRG  ! 81021101FIWC003CV 01/31/1813:55  : 2/2/2018

2/2/2018 2/2/2018 18-02009 '""""'" *~--* EPA 901.1 Modified  :

-8.12E-02 1.01E+OO 1.01E+OO 1.28E+OO u oCi/g 18-02009-05 : TRG 81021101FIWC003CV 01/31/18 13:55 2/2/2018 18-02009 '. Thorium-234 EPA 901.1 Modified 1.49E+OO 3.17E+OO 3.17E+OO 4.74E+OO u pCi/g

**-*"'"""'----------------~--

18-02009-05 , TRG  : 8102110IFIWC003CV 01/31/18 13:55  ; 2/2/2018 2/2/2018 18-02009 Thallium-208 EPA 901.1 Modified  : 4.48E-01 8.78E-01 8.78E-01 6.96E-01 u pCi/g 18-02009-05 TRG 81021101FIWC003CV 01/31/18 13:55 2/2/2018 2/2/2018 18--02009 Uranium-235 EPA 901.1 Modified  ! 3.50E-01 4.67E+OO 4.67E+OO 2.40E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect I

I NE Al YT!CAL ON

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Printed: 2/13/2018 8:54 AM Page 7 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical .,,,_,,_ Zion Solutions, LLC **--- _____ ,,

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Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd Ana/vsis Garegory. ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date Analyte Method Result cu CSU MDA Qualifier ID Units 18-02009-06 TRG B1021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA 901.1 Modified i 9.67E-01 2.24E+OO 2.24E+OO 3.31E+OO u pCi/q 18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 . 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901.1 Modified 7.87E-01 7.08E-01 7.09E-01 6.11E-01 u pCi/g an M: TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009

  • Americium-241 EPA 901.1 Modified  : -1.29E-01 6.24E-01 6.24E-01 7.82E-01 u pCi/g 18-02009-06 TRG 81021101FIWC004CV 01/31/1814:20 2/2/2018 2/2/2018 18-02009 Barium-133 EPA 901.1 Modified  : -1.23E-01 2.22E-01 2.22E-01 8.00E-01 u pCi/g 18-02009-06 TRG ___ ,,, ______ ,

81021101FIWC004CV _____________ ____ __ ___

,,, 01/31/18 14:20

., 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA901.1 Modified 1.61E+OO 1.08E+OO 1.08E+OO 1.98E+OO u pCi/g 18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 ' Cobalt-60 EPA 901.1 Modified  ! 1.13E+01 9.06E-01 1.08E+OO 7.32E-01 pCi/g 18-02009-06 , TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA 901.1 Modified 2.02E-01 3.35E-01 3.35E-01 7.52E-01 u pCi/g 18-02009-06 TRG i

81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901.1 Modified 1.58E-01 ; 6.44E-01 6.44E-01 9.48E-01 u pCi/g r-*-*---**---.-.,, ------- ------------ -----~--~---"' ------------*-**------*----------~---- """'"-""*-*-*

18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 ~u,

  • -* 152 EPA 901.1 Modified 1.69E+02 7.04E+OO 1.12E+01 3.25E+OO ' pCi/g t--*------------"*---------

18-02009-06 . TRG . B102110IFIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009  !:'cc**'c:- 154 EPA 901.1 Modified 5.51E+OO 1.38E+OO 1.41E+OO 2.52E+OO u pCi/g 18-02009-06 ' TRG . 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified i 1.61E+OO 7.94E-01 7.98E-01 1.27E+OO u pCi/g 18-02009-06 : TRG B1021101FIWC004CV 01/31/18 14:20  ! 2/2/2018 2/2/2018 : 18-02009 : Holmium-166m EPA 901.1 Modified  : -6.20E-01 1.08E+OO 1.08E+OO 4.93E-01 u . pCi/g 18-02009-06 ; TRG 81021101FIWC004CV 01/31/18 14:20  : 2/2/2018 2/2/2018 : 18-02009 : lodine-129 EPA 901.1 Modified ' 9.30E-01 6.37E-01 ' 6.39E-01 8.20E-01 : u pCi/g 18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018

  • 2/2/2018 18-02009 Potassium-40 EPA 901.1 Modified 5.65E+OO 3.48E+OO 3.49E+OO 5.57E+OO u pCi/g 18-02009-06 TRG B102110IFIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 ' .. *-**;:;,*

EPA 901.1 Modified 2.13E-02 5.98E-01 5.98E-01 8.77E-01 u pCi/g

-*--0-,------------~---------------------------*

18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA 901.1 Modified -1.16E+OO  : 9.22E-01 9.24E-01 8.14E-01 u pCi/g

<--:n ---- --

n~

18-02009-06 TRG TRG B1021101FIWC004CV 81021101FIWC004CV 01/31/1814:20 01/31/18 14:20 2/2/2018 2/2/2018

,-,---,.~-,--~------.---*,-,_,

2/2/2018 2/2/2018 18-02009 18-02009 Lead-210 Lead-212 EPA 901.1 Modified EPA901.1 Modified

2.70E+02 2.16E-01 2.39E+01 5.35E-01 2.76E+01 5.35E-01 1.87E+01 1.01E+OO u u pCi/g pCi/g 18-02009-06  : TRG B1021101FIWC004CV

- 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Lead-214 EPA 901.1 Modified

-1.37E+OO  : 9.72E-01

. 9.75E-01 1.31E+OO u pCi/q 18-02009-06 ; TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Promethium-145 EPA 901.1 Modified 1.57E+01 / 2.75E+OO 2.86E+OO 3.23E+OO u pCi/g

'--------*-------:------~--- . -------  :

18-02009-06 TRG B1021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified 1.61E+OO

' 1.08E+OO 1.08E+OO 1.98E+OO u ' pCi/g

~------*-

~Mnna_nc . TRG B1021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Antimony-125 EPA 901.1 Modified 6.12E-01 1.26E+OO 1.26E+OO 1.85E+OO u pCi/g 18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Thorium-234 EPA 901.1 Modified 4.47E+OO 6.05E+OO  : 6.06E+OO 7.84E+OO u pCi/g 18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20 2/2/2018 2/2/2018 18-02009 Thallium-208 EPA 901.1 Modified -1.09E-01 . 9.07E-01 9.07E-01 9.51E-01 u pCi/g 18-02009-06 TRG 81021101FIWC004CV 01/31/18 14:20  : 2/2/2018 2/2/2018 18-02009 Uranium-235 EPA 901.1 Modified -1.90E+OO

6.16E+OO 6.16E+OO 2.92E+OO : u  : pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

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Printed: 2/1312018 8:54 AM Page 8 of 17 Report To: Work Order Details:

Eberline Analytical J Alex Bohacheff >Nm*--*S.o SOG: 18-02009

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Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID  ; Type ID Date Date Date ID Analyte Method Result cu CSU MDA

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18-02009-07 18-02009-07 ,

TRG

___TRG 8102110FIFC003CV 8102110FIFC003CV 01/31/18 12:37 01/31/18

_ _ _ _ _12:37 2/2/2018

_ _ _ _ ,,,,,_,. __2/2/2018 2/2/2018 2/2/2018 M_,,__, _ _ , _______ ,,,

18-02009 18-02009 Actinium-228 Silver-108m

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  • EPA 901.1 Modified EPA 901.1 Modified  ;

2.36E+OO 1.15E+OO 2.11E+OO 6.25E-01 2.12E+OO 6.28E-01 3.06E+OO 4.77E-01 u pCi/g pCi/g 18-02009-07 TRG B102110FIFC003CV 01/31/1812:37 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901.1 Modified -2.22E-01 4.82E-01 4.82E-01 6.84E-01 u pCi/g 18-02009-07 '

18-02009-07 TRG TRG 8102110FIFC003CV 810211 OFIFC003CV

,,,,,,,,,_. _________ ,,, 01/31/18 12:37 01/31/18 12:37 2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02009 8arium-133 8ismuth-214 EPA 901.1 Modified EPA901.1 Modified

-8.85E-02 1.21E+OO 4.36E-01 6.15E-01 4.36E-01 6.18E-01 6.28E-01 6.54E-01 u pCi/g pCi/g

* . --- -~---"'-*--

18-02009-07 ; TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA 901.1 Modified 5.47E+OO 5.99E-01 6.62E-01 5.99E-01 pCi/g 18-02009-07 TRG 810211 OFIFC003CV

"""--*----**o* -* ---------------- ------------------*

01/31/18 12:37 ' 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA901.1 Modified  ; 3.86E-03 2.12E-01 2.12E-01 5.84E-01 u pCi/g

  • -------~---------** ----~-----~-----*** *-*---------.-*-------*---*---------=*mm,_, _________ ,__ '""""'- ,--------

18-02009-07 , TRG B102110FIFC003CV 01/31/1812:37 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901.1 Modified 2.95E-02 5.64E-01 5.64E-01 7.66E-01 u pCi/g

  • --"-~--*---------------------*"';'"  ; 02009-07  : TRG 8102110FIFC003CV

---"-,----------~*-------~--------------------~---------

01/31/18 12:37  ; 2/2/2018 2/2/2018 18-02009 Europium-152 EPA 901.1 Modified t 9.32E+01 3.89E+OO 6.16E+OO 2.30E+OO pCi/g 18-02009-07 TRG 810211 OFIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 I Europium-154 EPA 901.1 Modified ' 3.39E+OO 1.03E+OO 1.0SE+OO 1.17E+OO pCi/g 18-02009-07 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified  : 1.81E+OO 7.24E-01 7.30E-01 1.04E+OO u pCi/g

,...------~-~--"--""

18-02009-07 ; TRG 8102110FIFC003CV 01/31/18 12:37 2/2/201 2/2/2018 18-02009 , Holmium-166m EPA 901.1 Modified  ; 4.44E-01 7.11E-01 7.11E-01 4.26E-01 u pCi/g 18-02009-07 : TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified  : -2.89E+OO : 1.15E+OO  ; 1.16E+OO 1.34E+OO u pCi/g

*** -------------- I 18-02009-07 TRG 810211 OFIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Potassium-40 EPA 901.1 Modified 8.06E+OO 3.00E+OO 3.03E+OO 6.09E+OO u pCi/g

- ---*-r-*----- -- ~-.--- ' ------------ --~--*---s--- --

18-02009-07 TRG B102110FIFC003CV

- - - - * - - - , - - - , _ , _ _ _ _ _ _ _,,_ _ _, _ _ _ w _ _ _ _ _ _ _ _, ~ - - - - -

01/31/18 12:37 2/2/2018 . 2/2/2018 18-02009 ~-~ ...... '!-1""' "'"'"' :.. EPA 901.1 Modified [ 3.38E-01 5.84E-01 5.84E-01 8.14E-01 u pCi/g 18-02009-07 TRG B102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA901.1 Modified 2.23E+OO 7.62E-01  ; 7.71E-01 7.13E-01 u pCi/g

,~_n?nno. TRG 8102110FIFC003CV 01/31/18 12:37

--.- 2/2/2018 2/2/2018 18-02009 Lead-210 EPA 901.1 Modified i; 2.49E+02 2.55E+01 2.85E+01 2.75E+01 I pCi/g 18-02009-07 TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 : Lead-212 EPA 901.1 Modified 9.94E-02  ; 3.55E-01 3.55E-01 7.92E-01 u pCi/g 18-02009-07 j TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Lead-214 EPA 901.1 Modified 5.38E-01 6.15E-01 6.15E-01 1.02E+OO u pCi/g 18-02009-07

~ --------.------

TRG B102110FIFC003CV 01/31/1812:37  ; 2/2/2018 2/2/2018 18-02009 : Promethium-145 EPA 901.1 Modified 4.45E+01 5.63E+OO 6.08E+OO 3.42E+OO u pCi/g I

18-02009-07 TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified 1.21E+OO  ! 6.15E-01 I 6.18E-01 6.54E-01  ; pCi/g 18-02009-07 ; TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 ' 2/2/2018 18-02009 Antimony-125 EPA 901.1 Modified 4.34E-01 9.49E-01  ;

9.SOE-01 1.43E+OO u pCi/g 18-02009-07 : TRG B102110FIFC003CV 01/31/18 12:37  ; 2/2/2018 I 2/2/2018 18-02009 , Thorium-234 EPA 901.1 Modified i 7.58E-01 4.47E+OO 4.47E+OO 6.46E+OO u pCi/g 18-02009-07 ! TRG 8102110FIFC003CV 01/31/18 12:37 2/2/2018 2/2/2018 18-02009 Thallium-208 EPA 901.1 Modified  : -1.08E-02 1.33E+OO 1.33E+OO 1.02E+OO u pCi/g 18-02009-0 I  ;

TRG 8102110FIFC003CV 01/31/18 12:37  ; 2/2/2018 2/2/2018 18-02009 : Uranium-235 EPA 901.1 Modified i -2.49E+OO 4.70E+OO  ! 4.70E+OO 2.60E+OO I u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect ON 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [212]

Printed: 211312018 8:54 AM Page 9 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical SDG:

~--, Zion Solutions,_ LLC ____,,,,, -'-- "'"'"""'_,_, ' " " ' ' ' " ~ ' -

Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd Analysis Ca,cyv,y. ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02009-08 TRG 8102110FIFC021CV 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA901.1 Modified 1.44E+OO  : 1.43E+OO 1.43E+OO 2.23E+OO u pCi/g

  • ------~ ----------- --------

18-02009-08 i-,-,-~.-------,--: --~---,_,,_,,.

TRG 8102110FIFC021CV

____,,_,,_,,__ 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 Si1ver-108m EPA 901.1 Modified i 7.44E-01 4.80E-01 4.82E-01 3.70E-01 u pCi/g

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18-02009-08 ____________ TRG ----------

B102110FIFC021CV 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901.1 Modified  ; -9.63E-02 3.29E-01 3.29E-01 4.86E-01 u pCi/Q 18-02009-08 TRG B102110FIFC021CV 01/31/18 13:00

-*---------------,-- 2/2/2018 2/2/2018 18-02009

,,~,----- Barium-133 EPA 901.1 Modified 1.23E-01 4.21E-01 4.21E-01 5.42E-01 u pCi/g 18-02009-08 TRG B102110FIFC021CV 01/31/18 13:00  ; 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA 901.1 Modified  : 5.92E-01 8.09E-01 8.10E-01 1.23E+OO u pCi/Q 18-02009-08

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TRG B102110FIFC021CV 01/31/1813:00 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA 901.1 Modified 4.49E+OO 5.00E-01 5.51E-01 5.34E-01 . pCi/g

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18-02009-08 0------------.-----,,,,___ TRG B102110FIFC021CV 01/31/18 13:00  : 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA 901.1 Modified -7.35E-01 4.42E-01 4.44E-01 5.46E-01 u . pCi/g 18-02009-08 ; TRG B102110FIFC021CV 01/31/18 13:00

,,,,,,,_________2/2/2018 2/2/2018

.------,,.,m 18-02009

__,___ _,_, _______Cesium-137,__,_, __._.,<

EPA 901.1 Modified i -3.20E-01 4.36E-01 4.36E-01 6.07E-01 u pCi/g 18-02009-08 ' TRG 8102110FIFC021CV 01/31/1813:00 2/2/2018 2/2/2018 18-02009 Europium-152 EPA901.1 Modified 1.02E+02 5.51E+OO 7.58E+OO 2.09E+OO pCi/Q 1--------,-,--,-,0'_,,_,_ _ _ _ ,_V._

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18-02009-08 TRG B102110FIFC021CV 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 , Europium-154 EPA 901.1 Modified 2.95E+OO  ;

9.60E-01 . 9.72E-01 1.80E+OO u pCi/g 18-02009-08 TRG B102110FIFC021CV 01/31/1813:00 ' 2/2/2018 2/2/2018 18-02009 cu,-**-*,,_ 55 EPA 901.1 Modified 2.18E-01 5.61E-01 5.61E-01 8.40E-01 u pCi/g

--*----"-- """"'----------*"--------*---~---

18-02009-08 TRG 8102110FIFC021CV 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA 901.1 Modified 2.76E-01 ; 7.18E-01 7.18E-01 4.18E-01 u pCi/g

>--*---"'"'~------------*--------*-----*---

18-02009-08 18-02009-08

  • TRG TRG B102110FIFC021CV B102110FIFC021CV 01/31/18 13:00 01/31/18 13:00 2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02009 ;

lodine-129 Potassium-40 EPA 901.1 Modified EPA 901.1 Modified 6.95E-01 4.97E+OO

1.64E-01 2.41E+OO 1.68E-01 2.42E+OO 2.72E-01 7.04E+OO u

u pCi/Q pCi/g 18-02009-08 TRG B102110FIFC021CV 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 ' ***-**.:,-**-

C EPA901.1 Modified -1.28E-01 : 4.23E-01  : 4.23E-01 6.08E-01 u pCi/g 18-02009-08 i TRG 8102110FIFC021CV 01/31/1813:00 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA 901.1 Modified -1.46E+OO  : 7.41E-01 7.45E-01 5.72E-01 u pCi/g 18-02009-08 TRG 8102110FIFC021CV , _____________ '_______

___ 01/31/18 ,, 2/2/2018 18-02009 Lead-210 EPA901.1 Modified 1.35E+02

' 1.17E+01 1.36E+01 9.13E+OO pCi/g 18-02009-08 TRG 8102110FIFC021CV ___

01/31/18

,, 13:00 2/2/2018 ____________________

2/2/2018 18-02009 ,.. _______ Lead-212 , _____ EPA901.1 Modified  : 2.05E-01

' 5.73E-01 5.73E-01 7.01E-01 u . pCi/g 18-02009-08 ;

18-02009-08 TRG TRG B102110FIFC021CV

"-*-----~-------

B102110FIFC021CV 01/31/18 13:00

  • ----- --*-------~-

01/31/18 13:00 2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02009 ' Promethium-145 Lead-214 EPA 901.1 Modified EPA 901.1 Modified 2.36E-01

-4.14E+01

7.16E-01 3.25E+OO 7.16E-01 3.88E+OO 9.05E-01 9.65E-01 u

u pCi/g pCi/g 18-02009-08 18-02009-08 TRG TRG

8102110FIFC021CV

*--------*--------~ ------~--

B102110FIFC021CV 01/31/18 13:00 . 2/2/2018 01/31/18 13:00 . 2/2/2018 2/2/2018 18-02009 2/2/2018 18-02009 Radium-226 ... ______EPA 901.1 Modified Antimony-125 EPA 901.1 Modified 5.92E-01

-2.44E-01

! 8.09E-01 9.12E-01 8.10E-01 9.12E-01 1.23E+OO 1.15E+OO u

u pCi/g pCi/g f-..-*--  : ------- -

18-02009-08 TRG  : 8102110FIFC021CV 01/31/18 13:00  : 2/2/2018 2/2/2018 18-02009 Thorium-234 EPA 901.1 Modified 4.09E+OO 3.13E+OO 3.13E+OO 4.94E+OO u pCi/g 18-02009-08 i TRG B102110FIFC021CV 01/31/18 13:00 2/2/2018 2/2/2018 18-02009 ; Thallium-208 EPA 901.1 Modified 6.95E-02 9.75E-01 9.75E-01 1.15E+OO u pCi/g 18-02009-08

  • TRG B102110FIFC021CV 01/31/18 13:00 .* 2/2/2018 2/2/2018 18-02009 : Uranium-235 EPA 901.1 Modified -1.46E+OO 4.95E+OO 4.95E+OO 2.38E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect I

I EBERUNE CAL CORPOR,ATI

~ScARsoRo RoAD OAK R1DGE, :6~--3-7-8-30--8-65/48i=-o6s_3_FAx_s_6_5_/483=4-6-2i [213]

Printed: 2/1312018 8:54 AM Page 10 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical ___ Zion Solutions,LLC ___ _ Purchase Order:

SDG:

677118 Final Report of Analysis 101 Shiloh Blvd Analysis Cc<<v,;viy. ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02009-09 TRG B102110FIWC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA901.1 Modified -3.28E-01 1.55E+OO 1.55E+OO 2.24E+OO U pCi/g

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18-02009-09 TRG B102110FIWC015CV 01/31/18 14:43 ' 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901.1 Mo***d--ifi-,e--d--,-****_**5*-.0-6E---0**1*******-5*.2**e***E*****_**o**1***---5-_2**-7E---0-1--*-6-.4_0_E___ 01-----**u* pCi/g 18-02009-09 TRG B102110FIWC015CV 01/31/1814:43  : 2/2/2018 2/2/2018 18-02009 Barium-133 EPA901.1 Modified -1.30E*--*0*1*-**********3***.-3-9E---o-1***--3-.3*9***E**-_*0***1*********'"--e*-.5-1***E*--o-1-**-******* u--*****-******'p-Ci/"--g********I

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18-02009-09 TRG B102110FIWC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA901.1 Modified -1.50E-01 3.73E-01 3.73E-01 5.31E-01 U pCi/g

      • -***--:..--------****-***--------------*---+************---*******-*----*-+***-*---**********---*-*****-***-****-*--------------,---*-*********-*-...:...:.::~---*---!

18-02009-09 : TRG B102110FIWC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA901.1 Modified 1.11E+OO 4.67E-01 4.70E-01 1.10E+OO pCi/g

,__=:~===*-~*~---M**-=*-=-=!==-T*-_R-_G*--~~-_-_--8~1-~2-_1__-1-~-~I-_VJ-_C_0_1*~**=C=V=*=======--*-=;::o::.:_1_i3..:1:/.:1..8:_1:..:4:..:4..:3_*....::21:.::2::.:/2::.:0_1..::..8*_*_-...:.2:f2.,:.'.:2.0:_1_:_8:__*_=-~1.:.8~-0::2:.::-0..:0.::..;;...:*_**_~E;u.=ro:;P:i~u:.:m**.-:.*.*_-_1:.*:5:*..:*2*::.:*=l-[-==-=-..::E=P-:A:..:9=0:.-1=*:*1-_;M-.:o-..::d-i::.fi-,e~d*==*--~_:'..=~..:1*:.::*3..:1..::E+_0::2:._;--:-5::*.::..86::E:.+..::.0.0:..*...., .*....:8:.::::*92::-E_+::...:_00--:-....::2:.::3:3:..::E+_.:O::O:._;______..*.... ___!:'.::'.:

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--**--- *--*****-**********--** ****-*********---+--*-----*-**--r*-*-----********************----*********-*....:*--*-'C....--..J.**----*-**-*-*****-...;....--.*****-.....;....._ _ _ _..~...;.....::.:.._ ....*....--:..--.**----*--*******'....::....:::..._--1 18-02009-09 TRG B102110FIWC015CV 01/31/1814:43 ! 2/2/2018 2/2/2018 18-02009 Europium-155 EPA901.1 Modified i 2.15E+OO 7.23E-01 7.31E-01 1.15E+OO U pCi/g

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18-02009-09 ' TRG B102110F1WC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 lodine-129 EPA901.1 Modified 1.16E+OO , 2.73E-01 2.80E-01 1.17E+OO U oCi/a 18-02009-09  ! TRG B102110FIWC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 Potassium-40 EPA901.1 Modified , 6.37E+OO 2.55E+OO 2.57E+OO 4.23E+OO pCi/g I-***-----...---**--:-----------*******-*--------+----------------***-**-*---- -*-**------******---+-******-*---***---**---!*---*-****---:--*-*-***---********-------------**-*------*--***------:...::....- ...

18-02009-09 TRG  : B102110FIWC015CV 01/31/18 14:43 2/2/2018 2/2/2018 18-02009 Manganese-54 EPA 901.1 Modified 3.27E-01  : 4.13E-01 4.14E-01 6.21E-01 U pCi/g 18-02009-09 : TRG B102110FIWC015CV 01/31/1814:43  : 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA901.1 Modified  : -1.40E+OO : 6.94E-01 , 6.98E-01 5.56E-01 U 18-02009-09 : TRG B102110F1WC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 Lead-210 EPA901.1 Modified 2.05E+02  : 1.76E+01 2.05E+01 1.40E+01 U pCl/g-**-**

          • --*-----*1**--*-**-****--*-------*--**---*-*-**-****-----*--******--*-*---1-*********** *******--**---*******-*---~*----*-*--*-*'----******-*****---*----------*---*----********--.:........~..--.I 18-02009-09 ' TRG B102110F1WC015CV 01/31/1814:43  : 2/2/2018 2/2/2018 18-02009 , Lead-212 EPA901.1 Modified 2.93E-01 3.76E-01 3.76E-01 7.11E-01 U pCi/g 18-02009-09 i TRG / B102110FIWC015_cv _____......**+-o_11-3_11_.1_.8__1_4:_43~--2i_2i__2_0_18____.2__,_2..1.2.._o_.1..8_____1_8_-0_2_00_9_,_ .........L...e .._ad_-_.2__ 14____+--E_P__A.__9_o_1_-*1_M_o_d_ifi_,e_d.*...........;..,2_._3_4_E_+_o_o~ ..--5*****8-3_E__-_0_1_ _ _5_.9_6_E_-o_1___.___9_._5_7_E_-_o_._1. ___._.. ____ *....*.__;P:.......Ci/.::...g.....*...j 18-02009-09 ! TRG B102110F1WC015CV 01/31/18 14:43 l 2/2/2018 2/2/2018 18-02009 I Promethium-145 EPA 901.1 Modified 3.07E+OO . 1.41E+OO 1.42E+OO 1.80E+OO U pCi/g 18-02009-09 TRG B102110F1WC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 Radium-226 EPA901.1 Modified 4.77E-01  : 7.91E-01 7.92E-01 1.17E+OO U oCi/a 11iR-rio"cirl9-n;-r--:;:;:;~*---;;::im;:;-;-;JFru;;;:;;:;-;;;~v---*-******----i-o**

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18-02009-09 . TRG B102110FIWC015CV 01/31/1814:43 2/2/2018 2/2/2018 18-02009 : Thallium-208 EPA901.1 Modified , 3.93E-01 7.70E-01 , 7.71E-01 1.03E+OO U oCi/a 18-02009-09 i TRG B102110F1WC015CV 01/31/1814:43 .* 2/2/2018 2/2/2018 18-02009 Uranium-235 EPA901.1 Modified  : -1.84E+OO 3.83E+OO 3.83E+OO 2.43E+OO U pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

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EBERLINE SERVICES 601 SCARBORO ROAD OAK RIDGE, CAL CORPORATION TN 37830 865/481-0683 FAX 865/483-4621 [214]

Printed: 2/13/2018 8:54 AM Page 11 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical Zion Solutions. LLC

-+***

SDG:

r . .*.-:;.':;;ic Order: 677118 Final Report of Analysis 101 Shiloh Blvd Analysis

'" _______ Category:

ENVIRONMENTAL

    • - """""'"'--~-----*-------------*-*

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  • Actinium-228 EPA 901.1 Modified 6.62E-01 1.89E+OO 1.89E+OO 2.79E+OO u pCiig 18-02009-10 TRG B102110FIWC017CV 01/31/18 15:07 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901.1 Modified 6.93E-01  : 6.13E-01 6.14E-01 5.30E-01 u pCi/g

*-----'" ------- ----"'~---------*  :

18-02009-10 TRG B102110FIWC017CV 01/31/1815:07 2/2/2018 2/2/2018 18-02009 Americium-241 EPA901.1 Modified -4.49E-01 5.74E-01 5.75E-01 7 08E-01 u pCi/g

u 18-02009-10 : TRG B102110FIWC017CV ____________ ____________

01/31/1815:07 ,,,

2/2/2018 2/2/2018 18-02009 Barium-133

"'"'"--------,--~----*--'"' EPA 901.1 Modified 2.48E-01 3.74E-01 3.74E-01 7.25E-01 pCi/g 18-02009-10 ' TRG B102110FIWC017CV 01/31/18 15:07 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA 901.1 Modified 1.43E+OO i 1.16E+OO 1.16E+OO 1.68E+OO u pCi/g

  • -----,,-----------------*------.-----~--------.--

18-02009-10 18-02009-10

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-**- ---------*=---------.

18-02009-10

TRG ______ _____________

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.---,,----~---------,------------'"-----

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---*---------------,---""~'-"'

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*-*-'"'"* __,, __________ ______ 01/31/18 15:07  ! 2/2/2018 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified  : 8.32E-01  : 5.67E-01 5.69E-01 7.27E-01 u oCi/q 18-02009-10 18-02009-10 TRG

  • ---*-----",------~----,,,,,

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  • 2/2/2018 18-02009 ; Niobium-94 EPA 901.1 Modified -8.36E-01 7.84E-01 7.85E-01 7.10E-01 u pCi/g i 2/2/2018 EPA 901.1 Modified 2.33E+02 2.05E+01 2.37E+01 1.56E+01 u pCi/g 18-02009-10 TRG B102110FIWC017CV 01/31/1815:07 2/2/2018 18-02009 Lead-210  !

---**-----------------*"*-~-*---------~ _________ ____

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  • 2.45E+OO 2.58E+OO 2.76E+OO u pCi/g 18-02009-10 TRG B102110FIWC017CV 01/31/18 15:07 2/2/2018
  • 2/2/2018 18-02009 ! Radium-226 EPA 901.1 Modified 1.43E+OO 1.16E+OO 1.16E+OO 1.68E+OO u pCi/g 18-02009-10 , TRG B 10211 OFIWC017CV 01/31/18 15:07  : 2/2/2018
  • 2/2/2018 18-02009 : ~,::':,,_.. 125 EPA 901.1 Modified -6.38E-01 1.16E+OO 1.16E+OO 1.65E+OO : u pCi/g 18-02009-10 ( TRG B102110FIWC017CV 01/31/18 15:07  : 2/2/2018 2/2/2018 18-02009 Thorium-234 EPA 901.1 Modified 7.20E-01 5.41E+OO 5.41E+OO 6.88E+OO u pCiig 18-02009-10 TRG B102110F1WC017CV 01/31/18 15:07 2/2/2018 2/2/2018 18-02009 ' Thallium-208 EPA 901.1 Modified 5.40E-01 9.98E-01 9.98E-01 1.02E+OO u pCi/g 01/31/18 15:07

*-*-*-----~*-

2/2/2018 2/2/2018 18-02009 Uranium-235 EPA 901.1 Modified -3.44E+OO 5.50E+OO 5.50E+OO 2.55E+OO u pCi/g 18-02009-10 ' TRG B102110F1WC017CV CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect SCARBORO ROAD OAK RIDGE, 865/481-0683 FAX 865/483-4621 [215]

Printed: 2/13/2018 8:54 AM Page 12 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical ___ Zion Solutions, LLC __________

SDG:

Purchase Order: 677118

*-------*-----,----*---------------,-------*--------- ,-.---------~----------------------------------

Final Report of Analysis f-----**

101 Shiloh Blvd .. .... Analysis Category: _ _________

ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report Date Analyte Method Result cu CSU MDA Qualifier ID Type ID Date Date  :

ID  :

Units

u 18-02009-11 18-02009-11 TRG TRG 8102110FIWC019CV 8102110FIWC019CV 01/31/18 15:30

~---

01/31/18 15:30

. 2/2/2018 2/2/2018 2/2/2018 18-02009 2/2/2018 18-02009 Actinium-228 Silver-108m EPA 901.1 Modified EPA 901.1 Modified 2.31E+OO 8.70E-01 1.71E+OO 5.73E-01 1.72E+OO 5.75E-01 2.65E+OO 4.42E-01 u pCi/g pCi/g 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30  : 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901.1 Modified 1.36E-01 3.79E-01 3.79E-01 5.67E-01 u pCi/g

--~-------------*--------

18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 Barium-133 EPA901.1 Modified 2.46E-01 5.06E-01 5.06E-01 6.24E-01 u pCi/g 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 ' 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA 901.1 Modified  : 1.68E+OO 7.70E-01 7.75E-01 1.53E+OO pCi/g 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA 901.1 Modified 8.89E+OO 7.44E-01 8.73E-01 6.22E-01 pCi/g

~- ---------* ----

18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 i 2/2/2018 2/2/2018 18-02009

  • -*--------------.* Cesium-134

"--*---,--- EPA 901.1 Modified  : 1.04E-02

' 1.63E-01 1.63E-01 6.10E-01 u pCi/g 18-02009-11 TRG 8102110FIWC019CV

,.,.--------------------,- ------------* 01/31/1815:30 01/31/18 15:30 2/2/2018 ,

2/2/2018 :

2/2/2018 2/2/2018 18-02009 18-02009 Cesium-137 Europium-152 EPA 901.1 Modified EPA 901.1 Modified 6.75E+OO 1.53E+02 i 1.35E+OO 7.84E+OO 1.39E+OO 1.11E+01 1.25E+OO 2.24E+OO pCi/g pCi/g 18-02009-11 TRG 8102110FIWC019CV i 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 Europium-154 EPA901.1 Modified i 7.05E+OO 1.32E+OO 1.37E+OO 2.39E+OO u pCi/g

*--""'-----------------------*---~----------,

18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified 4.31E-01 6.52E-01 6.52E-01 9.73E-01 u pCi/g 18-02009-11

' TRG 8102110FIWC019CV 01/31/18 15:30  : 2/2/2018 2/2/2018 18-02009

,-------------,,-,--*----*-------~- ---- ,, ----------*--

Holmium-166m EPA 901.1 Modified 2.56E-01 ' 8.04E-01  : 8.04E-01 4.76E-01 u pCi/g 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified

. 7.33E-01 2.07E-01 2.10E-01 3.15E-01 u pCi/g 18-02009-11  : TRG 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 Potassium-40 EPA 901.1 Modified 9.49E+OO 2.99E+OO 3.03E+OO 7.58E+OO pCi/g 18-02009-11  : TRG 8102110FIWC019CV 01/31/1815:30 2/2/2018 2/2/2018 18-02009 ---- .. "-""" .. r EPA 901.1 Modified -1.42E-01 : 4.75E-01 4.75E-01 6.84E-01 u pCi/g 18-02009-11 TRG 8102110FIWC019CV --- .

01/31/18 15:30 2/2/2018 2/2/2018 ___,,18-02009 Niobium-94 EPA 901.1 Modified  :' -2.70E+OO , 9.11E-01 9.22E-01 6.37E-01 u pCi/g 18-02009-11

~,,,,,

18-02009-11

*--~

. _ ,TRG TRG

~-"'-*-=--------*-----

8102110FIWC019CV 8102110FIWC019CV

, ____ __ , ___ , 01/31/18 15:30 2/2/2018

*---,-,------------*----~-----------"""'

01/31/18 15:30 2/2/2018 2/2/2018 2/2/2018 18-02009 ______Lead-210 18-02009 Lead-212 EPA 901.1 Modified EPA 901.1 Modified 2.09E+02 3.58E-01 1.66E+01 6.16E-01 i 1.97E+01 6.17E-01 1.06E+01 8.04E-01 u pCi/g pCi/g

-*--------- ""'""-'""~-------- ---***-------..------~---**----*--,~----*- i 18-02009-11 TRG ___B102110FIWC019CV

, __ ,, ______ 01/31/18 15:30 18-02009

... 2/2/2018 2/2/2018 -*-----"*---*-------"*-------*"'""""" Lead-214 EPA901.1 Modified  : -1.35E-01 8.14E-01 8.14E-01 1.01E+OO u  : pCi/g

~,,,~--** -----------

18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018 2/2/2018 18-02009 Promethium-145 EPA 901.1 Modified i -6.21E+01 4.42E+OO 5.45E+OO 1.16E+OO  : u pCi/g

*  ;--*--*--- ---,,,*------,-- r-------------------__,,,,,~---- ---;- '"""'"~----,-,

18-02009-* TRG 8102110FIWC019CV 01/31/18 15:30  ! 2/2/2018 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified i 1.68E+OO 7.70E-01 7.75E-01 1.53E+OO pCUg 18-02009-11 , __ TRG 8102110FIWC019CV 01/31/18 15:30 i 2/2/2018 2/2/2018 18-02009 l'"\l,., *** _ .. , ,,..., EPA 901.1 Modified i -1.78E-01 1.05E+OO 1.05E+OO 1.35E+OO u pCi/g 18-02009-11 TRG 8102110FIWC019CV _,_,

01/31/18____ 15:30 ' 2/2/2018 2/2/2018

--~-----*

18-02009 Thorium-234

-~----"'"

EPA 901.1 Modified i 8.43E-01 3.84E+OO 3.84E+OO 5.67E+OO u pCi/g 18-02009-11 TRG 8102110FIWC019CV 01/31/18 15:30 2/2/2018

  • 2/2/2018 18-02009 ; Thallium-208 EPA 901.1 Modified  : -4.75E-01 1.16E+OO

' 1.16E+OO 9.27E-01 u pCi/g 18-02009-11  : TRG 8102110FIWC019CV 01/31/18 15:30 . 2/2/2018 2/2/2018 18-02009 ' Uranium-235 EPA 901.1 Modified i 5.28E+OO : 6.08E+OO 6.08E+OO 2.81E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERVICES 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [216]

Printed: 2/13/2018 8:54 AM Page 13 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical Zion Solutions, LLC Purchase SDG:

Order: 677118

,,e _ _ _ _

Final Report of Analysis 101 Shiloh Blvd <.;aregory ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02009-12 TRG B102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 : Actinium-228 EPA 901-1 Modified  : 1.28E+OO 1.38E+OO L39E+OO 2.10E+OO u pCi/g 18-02009-12 TRG ,,, _____ " ______ ,

B102110F1WC020CV ___ ,,,,--,-----*- ,

02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901-1 Modified  : 5.36E-01 4.34E-01 4.34E-01 3.74E-01 u pCi/g 18-02009-12 TRG 810211 OFIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Americium-241 EPA 901-1 Modified -1WE-01 4.14E-01 4.14E-01 5.15E-01 u pCi/g

-*----*----~------*--------"-*------- ,,,,.,

18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 8arium-133 EPA 901-1 Modified -6.59E-02 3.60E-01 3.60E-01 5.18E-01 u pCi/g

*-----~------*----*-----~------* ----------

18-02009-12 TRG 8102110FIWC020CV

...............______,,,,______ ""'-"--*-------------w,= 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 8ismuth-214 EPA 901-1 Modified 3.55E-01 6.75E-01 . 6.75E-01 1-00E+OO u pCi/g 18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 : Cobalt-60 EPA 901-1 Modified 7.92E+OO 5.99E-01 7-24E-01 3.68E-01 pCi/g

  • -"*----------------*----~-----~----------

18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA 901-1 Modified -4.01E-02 3.21E-01 3.21E-01 4-64E-01 u pCi/g 18-02009-12,, TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901-1 Modified 4.31E-01 4.08E-01 4.09E-01 6.08E-01 u pCi/g 18-02009-12 TRG 810211 OFIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Europium-152 EPA 901-1 Modified 1.06E+02 3.83E+OO 6.66E+OO 2.11E+OO pCi/g

!------~~---------*---~'

18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 ' Eu, *c*-* ,.- 154 EPA 901.1 Modified  : 2.91E+OO  : 8.12E-01 . 8.26E-01 1.47E+OO u pCi/g 18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901-1 Modified 8.56E-01 ! 5.17E-01 5.19E-01 8.23E-01 u pCi/g

- """"' ------------~-------------  :

18-02009-12 : TRG 810211 OFIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA 901.1 Modified -5.06E-01

' 6.59E-01 6.60E-01 3.15E-01 u pCi/g 18-02009-12 TRG B102110FIWC020CV f--,,,,-*-*----~-------*--*--------*-*--*-*="'---*---*--

18-02009-12 TRG 8102110FIWC020CV

__ ,_,,,, _____"'"~----*------

02/01/18 08:12 02/01/18 08:12 2/2/2018 2/2/2018 2/2/2018 2/2/2018

~-----

18-02009 :

lodine-129 Potassium-40 EPA 901.1 Modified EPA 901.1 Modified 7.35E-01 6.27E+OO 3.83E-01 2.26E+OO 3.84E-01 2.28E+OO 4.98E-01 4.01E+OO u

u pCi/g pCi/g 18-02009-12 TRG B102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Manganese-54 EPA 901.1 Modified -1.85E-01 3.69E-01 3.69E-01 5.20E-01 u pCi/g

  • -,=-------.---------- -------------,,=---------  : 2/2/2018 """',------"' ~ ----------

18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 18-02009 Niobium-94 EPA 901.1 Modified -2.75E-01 5.53E-01 5.53E-01 4.91E-01 u pCi/g 18-02009-12 TRG  : B102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Lead-210 EPA 901.1 Modified t 1.53E+02 1.37E+01 1.58E+01 1.10E+01 u pCi/g 18-02009-12  ! TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Lead-212 EPA 901.1 Modified ' 1.39E-01 3-45E-01 3-45E-01 6.52E-01 u pCi/g

~-------------------------*-----------

18-02009-12 , TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Lead-214 EPA 901.1 Modified -7.62E-01

' 6.27E-01 6.28E-01 8.58E-01 u oCi/q 18-02009-12 , TRG B102110FIWC020CV 02/01/18 08:12 l 2/2/2018 2/2/2018 18-02009 , Promethium-145 EPA 901.1 Modified 7.86E+OO 1.56E+OO 1.61E+OO 1.88E+OO u oCi/q 18-02009-12 : TRG 8102110FIWC020CV 02/01/18 08:12 i 2/2/2018 ' 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified 3.55E-01 : 6.75E-01 6.75E-01 1.00E+OO u pCi/g

u 18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009

~-----*------------------------~----------------,

Antimonv-125 EPA901.1 Modified ' 4.33E-01 8.16E-01 8.16E-01 1.20E+OO pCiig 18-02009-12 : TRG  ; 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Thorium-234 EPA 901.1 Modified 47E-03 3.99E+OO 3.99E+OO 5.03E+OO u pCi/g 18-02009-12 TRG 8102110FIWC020CV 02/01/18 08:12 2/2/2018 2/2/2018 18-02009 Thallium-208 EPA901.1 Modified 7.36E-01 ! 1-09E+OO 1.09E+OO 6.06E-01 u pCi/g f-.-----  ; --

18-02009-12 TRG 810211 OFIWC020CV 02/01/18 08:12 ' 2/2/2018 2/2/2018 18-02009 Uranium-235 EPA 901.1 Modified ' 1.12E+OO 3.95E+OO 3.95E+OO 1.83E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE SERViCES 865/481-0683 FAX 865/483-4621 [217]

Printed: 211312018 8:54 AM Page 14 of 17 Report To: Work Order Details:

Eberline Analytical J Alex Bohacheff --*

SDG: 18-02009 ***-

Zion Solutions, LLC ________ ,, __________

Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd Analysis Category:

  • y-=-"- -

ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report ID Type ID Date Date Date ID Analyte Method  ! Result cu CSU MDA Qualifier Units 18-02009-13 I TRG B102110FIWC014CV 02101 /18 08:56 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA901.1 Modified -8.70E-01 1.75E+OO 1.75E+OO 2.50E+OO u pCi/g 18-02009-13 : TRG 8102110FIWC014CV 02/01/18 08:56  : 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901.1 Modified 2.42E-01 5.38E-01 5.38E-01 4.96E-01 u pCi/g 18-02009-13 TRG 8102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 Americium-241 EPA901.1 Modified -9.73E-01 6.00E-01 6.03E-01 7.04E-01 u pCi/g I

18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 Barium-133 EPA 901.1 Modified -1.44E-01 2.44E-01 2.45E-01 7.17E-01 u pCi/g

*---~-------,----------- ----------*-

18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA901.1 Modified 7.53E-01 8.61E-01 8.62E-01 1.30E+OO u pCi/g

*----*------..----~---- ---"

18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 : 2/2/2018 18-02009 Cobalt-60 EPA 901.1 Modified  : 8.07E+OO 6.91E-01 8.06E-01

7.22E-01 : pCi/g I

18-02009-13 TRG 8102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 ________ ___________,

Cesium-134 EPA 901.1 Modified -2.36E-01 4.21E-01 4.21E-01 5.93E-01 u pCi/g 18-02009-13 TRG 8102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901.1 Modified 5.93E-01 4.66E-01 4.67E-01 7.55E-01 u pCi/g

,-------------------- I 18-02009- 3 I TRG B102110FIWC014CV 02/01/18 08:56  : 2/2/2018 2/2/2018 18-02009 Europium-152 EPA 901.1 Modified 1.29E+02 5.40E+OO 8.54E+OO 3.03E+OO pCi/g 18-02009-13 TRG B102110FIWC014CV 02/01 /18 08:56  : 2/2/2018 2/2/2018 18-02009 Europium-154 EPA 901.1 Modified 3.62E+OO 1.03E+OO I 1.05E+OO 1.89E+OO u pCi/g 18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified 1.93E+OO  ; 7.85E-01 11E-01 1.27E+OO u pCi/g 18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56  ; 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA901.1 Modified i 1.67E-01 7.99E-01 7.99E-01 4.51E-01 u pCi/g 18-02009-13 I TRG 8102110FIWC014CV 02/01 /18 08:56 212/2018 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified 1.25E+OO 3.42E-01 3.48E-01 1.34E+OO u pCVg 18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56  ! 2/2/2018 : 2/2/2018 18-02009 Potassium-40 EPA 901.1 Modified 3.87E+OO 2.80E+OO 2.81E+OO 5.30E+OO u pCi/g 18-02009-13 TRG B102110FIWC014CV 02/01 /18 08:56  : 2/2/2018 2/2/2018 18-02009 '. ,.,_,,"_,, ___ : EPA901.1 Modified -1.59E-01 i 4.50E-01 4.50E-01 6.46E-01 u pCi/g 18-02009-13 TRG 8102110FIWC014CV 02/01 /18 08:56 2/212018 : 2/2/2018 18-02009 i Niobium-94 EPA 901.1 Modified -1.22E+OO : 7.14E-01 7.17E-01 5.95E-01 u  : pCi/g 18-02009-13 : TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 : Lead-210 EPA 901.1 Modified 2.19E+02 i 1.90E+01 2.21E+01 1.62E+01 u pCi/g 18-02009-13 ; TRG I B102110FIWC014CV 02/01/18 08:56 2/2/2018 I 2/2/2018 18-02009 : Lead-212 EPA 901.1 Modified i

-3.57E-02  : 3.36E-01 3.36E-01 7.80E-01 u  ;

pCi/g 18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56  : 2/2/2018 2/2/2018 18-02009 Lead-214 EPA901.1 Modified 2.02E+OO  : 7.36E-01 7.43E-01 1.45E+OO pCi/g u

~--------- _" ____________

18-02009-13 TRG 8102110FIWC014CV 02/01/18 08:56 212/2018 2/2/2018 18-02009 Promethium-145 EPA 901.1 Modified 3.43E+OO 1.62E+OO 1.63E+OO 2.08E+OO pCi/g u

18-02009-13  : TRG B102110FIWC014CV 02/01/18 08:56 2/2/2018 2/2/2018 18-02009 Radium-226 EPA901.1 Modified 7.53E-01 i 8.61E-01 8.62E-01 1.30E+OO pCi/g 18-02009-13 TRG B102110FIWC014CV 02/01/18 08:56 i 2/2/2018 i 2/2/2018 18-02009 I Antimony-*125 EPA 901.1 Modified .88E-01 i 1.06E+OO 1.06E+OO 1.55E+OO : u pCi/g

___18-02009-13 i TRG _______

B102110FIWC014CV 02101/18 08:56 I 2/212018 21212018 18-02009 , Thorium-234 EPA 901.1 Modified 2.85E+OO i 5.86E+OO 5.87E+OO 7.52E+OO u pCi/g 18-02009-13 TRG 8102110FIWC014CV 02/01/18 08:56 2/212018 2/2/2018 18-02009 : Thallium-208 EPA 901.1 Modified 5.28E-02 5.69E-01 5.69E-01 1.18E+OO u pCi/g 18-02009-13 TRG 8102110FIWC014CV 02/01/18 08:56 2/212018 ' 2/2/2018 18-02009 i Uranium-235 EPA 901.1 Modified 1.90E-01 4.27E+OO 4.27E+OO 2.71E+OO u pCVg CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE Al YTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [218]

Printed: 2/13/2018 8:54 AM Page 15 of 17 Report To: Work Order Details:

18-02009 Eberline Analytical __ ____JZion ,,,,,,,

Alex Bohacheff Solutions,_ LLC ___ ,

SDG:

Purchase Order: 677118

--*--*-*, ._, . ._ .. ~

ms, Final Report of Analysis 101 Shiloh Blvd r,,+o--

--~-:::,-Y ENVIRONMENTAL so Zion, IL 60099 Sample Matrix:

Lab Sample Client Sample Receipt Analysis Batch Report ID Date Date Analyte Method Result cu CSU MDA Qualifier ID Type Date ID Units 18-02009-14 TRG 8102110FIWC018CV 02/01 /18 09:38 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA 901.1 Modified  ; -8.63E-01 2A4E+OO 2.44E+OO 3.22E+OO u pCi/g 18-02009-14 TRG B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Silver-108m EPA 901.1 Modified 1.26E+OO 6.99E-01 7.02E-01 5.22E-01 u pCi/g 18-02009-14 TRG 8102110FIWC018CV 02/01/18 09:38 i 2/2/201 2/2/2018 18-02009 Americium-241 EPA901.1 Modified  : -4.21E-01 5.22E-01 5.22E-01 7.37E-01 u pCi/g 18-02009-14 ; TRG 8102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Barium-133 EPA 901.1 Modified 3.94E-01 4.64E-01 i 4.64E-01 6.97E-01 u pCi/g

' TRG B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Bismuth-214 EPA 901.1 Modified 4.64E-01 8.80E-01  : 8.80E-01 1.32E+OO u pCi/g 18-02009-14 ' TRG 8102110FIWC018CV 02/01 /18 09:38 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA901.1 Modified  : 7.87E+OO 7.54E-01 8.55E-01 6.54E-01 pCi/g

~ -,------- ._,,,,,_*=*"""'" ,.,.,,, ------------------*  ;

18-02009-14 TRG B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Cesium-134 EPA 901.1 Modified -2.17E-01 4.41E-01 4A2E-01 6.24E-01 u pCi/g

--*------~--.....---------~-------*-------- ----- ----* ------*

18-02009-14 TRG 8102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA 901.1 Modified ' 1.17E-01 6.66E-01 ' 6.66E-01 9.04E-01 u pCi/g

-- -*----*,,s--.,, --*  ;

18-02009-14 TRG B102110FIWC018CV 02/01/18 09:38  ; 2/2/2018 2/2/2018 18-02009 ~u, -e*-* e,- [ 52 EPA901.1 Modified 1.10E+02 4.36E+OO 7.13E+OO 3.38E+OO pCi/g

~----- -----------------*  ;  ;

18-02009-14 , TRG B 10211 OFIWC018CV 02/01 /18 09:38 2/2/2018 2/2/2018 18-02009 cu, -e--* ..- I54 EPA 901.1 Modified 2.89E+OO ' 1.26E+OO 1.27E+OO 2.18E+OO u pCi/g 18-02009-14 ; TRG B102110FIWC018CV 02/01/18 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified  ; 1.29E+OO 7.69E-01 7.72E-01 1.11E+OO u pCi/g 18-02009-14 i TRG B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009

**-------~------------------*------*-"'"

Holmium-166m EPA 901.1 Modified  ; 5.71E-01 : 1.04E+OO 1.04E+OO 4.72E-01 u pCi/g 18-02009-14 i TRG B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified -3.55E+OO 1.29E+OO  ; 1.30E+OO 1.45E+OO u pCi/g

,rn

  • - -~

18-02009-14

  • ~

TRG TRG B102110FIWC018CV B102110FIWC018CV 02/01/18 09:38 02/01 /18 09:38 i

2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 Potassium-40 18-02009 : ,.,_,,"_" ___ :

EPA 901. 1 Modified EPA 901.1 Modified 4.52E+OO 1.63E-01 3.01E+OO 6.35E-01 '

3.02E+OO 6.36E-01 7.77E+OO 8.64E-01 u

u pCi/g pCi/g 02009-14 '

TRG B102110FIWC018CV

  • -----~--_,,_,,

8102110FIWC018CV

__, . 02/01/18 09:38

---"--~--

02/01/18 09:38 2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02009 Niobium-94 Lead-210 EPA901.1 Modified EPA 901.1 Modified  ;

5.19E-02 2.55E+02 2.31E-01 2.54E+01

' 2.31E-01 2.86E+01 7.75E-01 2.81E+01 u pCi/g pCi/g 18-02009-14 TRG i 18-02009-14 :

-*----*-----'--=-

TRG 8102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 ,.,,_ -~-----

Lead-212 EPA 901.1 Modified

' 7.16E-01 5.49E-01 5.50E-01 1.80E+OO u pCi/g 18-02009-14 TRG  ; B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Lead-214 EPA 901.1 Modified i -8.42E-02 ' 7.90E-01 ' 7.90E-01 1.14E+OO u pCi/g

~--*---*----*=*"*-------*----*"'*------,, *------------

18-02009-14  ! TRG 8102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Promethium-145 EPA 901. 1 Modified ' 6.11E+01 7.55E+OO  : 8.18E+OO 3.81E+OO u pCi/g 18-02009-14 i TRG ' B102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Radium-226 EPA 901. 1 Modified 4.64E-01 8.80E-01 8.80E-01 1.32E+OO u pCi/g 18-02009-14 i TRG 8102110FIWC018CV 02/01/18 09:38 2/2/2018 2/2/2018 18-02009 Antimony-125 EPA 901.1 Modified 1.14E+OO 1.07E+OO 1.08E+OO 1.63E+OO u pCi/g

-~- ----- l"'t i TRG 8102110FIWC018CV 02/01/18 09:38

2/2/2018 ; 2/2/2018 18-02009 Thorium-234 EPA 901.1 Modified -3.33E+OO ; 4.91E+OO 4.92E+OO 6.93E+OO u pCi/g 18-02009-14 TRG B102110FIWC018CV 02/01/18 09:38 ___,,,____

2/2/2018 2/2/2018 18-02009 ' Thallium-208 EPA 901. 1 Modified 2.99E-01 1.49E+OO 1.49E+OO 1.37E+OO u pCi/g 18-02009-14 , TRG B102110FIWC018CV 02/01 /18 09:38

' 2/2/2018 2/2/2018 18-02009 Uranium-235 EPA 901.1 Modified -1.45E+OO 3.89E+OO 3.89E+OO 2.70E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE , EBERLINE CAL 'v ON SERViCES i 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [219]

Printed: 211312018 8:54 AM Page 16 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical ...

_________ ,_ Zion Solutions, ,--------- LLC ,,,,,,,,-,-*---- ,,,,,,._

SDG:

n;;,-::;.~::;:;e Order:

_____ 677118

-*~-*----A---*-----* ~.w-Final Report of Analysis 101 Shiloh Blvd Analysis Category: ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report Analyte Method Result cu CSU MDA Qualifier ID Type ID Date Date Date ID Units 18-02009-15 TRG B102110FIWC016CV 02/01 /18 10:00 2/2/2018 2/2/2018 18-02009 Actinium-228 EPA 901.1 Modified -1.56E-01 1.55E+OO 1.55E+OO 2.27E+OO u pCi/g

--*-*-------------* v--**---*-*-*----***-*-------*-------

18-02009-15 TRG B102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 : Silver-108m EPA 901.1 Modified 8.37E-01 4.77E-01 4.78E-01 4.44E-01 u pCi/g 18-02009-15 : TRG 8102110FIWC016CV 02/01/18 10:00

. 2/2/2018 2/2/2018 18-02009 : Americium-241 EPA 901.1 Modified -2.42E-02 3.75E-01 3.75E-01 5.76E-01 u pCi/g i

18-02009-15 TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Barium-133 EPA 901.1 Modified 2.19E-02 4.06E-01 4.06E-01 5.95E-01 u pCi/g 18-02009-15 ' TRG 8102110FIWC016CV

--*---.--"--*------.------,,~------~*-----------

02/01/18 10:00 i 2/2/2018 2/2/2018

--~-*-*-***-**-

18-02009 Bismuth-214 EPA 901.1 Modified i 9.47E-01 . 8.01E-01 8.02E-01 1.30E+OO u pCi/g 18-02009-15 TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Cobalt-60 EPA901.1 Modified 3.95E+OO 4.32E-01 4.77E-01 2.63E-01 pCi/g i

18-02009-15 i TRG 8102110FIWC016CV /01/18 10:00 2/2/2018 2/2/2018 18-02009 Cesium-134

=-*s--,,.,,-,w---~=--"

EPA 901.1 Modified 1.04E-01 2.63E-01 2.63E-01 5.06E-01 u pCi/g 18-02009-15 : TRG . 8102110FIWC016CV /01/1810:00 2/2/2018 2/2/2018

" " " " " " " * - - - - - - * - - ,,,_ " " * - * - . - * = - - ' " " " ' __ ,_,,. ____ ,

18-02009 Cesium-137

,,,,,_,__,v _ _ _ _ _ EPA 901.1 Modified i 4.06E-01 4.60E-01 . 4.60E-01 6.95E-01 u pCi/g 18-02009-15 i TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Europium-152 EPA 901.1 Modified 8.22E+01 3.27E+OO 5.33E+OO 2.28E+OO  : pCi/g 18-02009-15 i i u TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Europium-1 EPA 901.1 Modified  : 2.28E+OO 8.68E-01 8.76E-01 1.66E+OO pCi/g 18-02009-15 TRG B102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 -L..YlVtJIYIII-,-.,-.,

<C< EPA 901.1 Modified i 1.03E+OO  : 8.71E-01  : 8.73E-01 1.23E+OO u oCi/q 18-02009-15 , TRG 8102110FIWC016CV 02/01 /18 10:00 i 2/2/2018 2/2/2018 18-02009 Holmium-166m EPA 901.1 Modified i -2.61E-01 7.31E-01 . 7.31E-01 3.45E-01 u pCi/g

"----~-------,--------"-"'~--------------,-*, .

18-02009-15 i TRG 8102110FIWC016CV 02/01 /18 10:00 2/2/2018

---,-------~-----------*--

2/2/2018 18-02009 lodine-129

=--------

EPA 901.1 Modified 1.43E+OO  : 4.83E-01 4.88E-01 1.96E+OO u pCi/g 18-02009-15 , TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Potassium-40 EPA 901.1 Modified 5.97E+OO 2.84E+OO 2.86E+OO 4.13E+OO pCiig 18-02009-15 TRG 8102110FIWC016CV

,=*-=w, ___ ,_ _ _ " _________ ""'"'--

02/01/18 10:00 i 2/2/2018 2/2/2018 18-02009 : - EPA 901.1 Modified i -6.45E-02 i 4.17E-01 4.17E-01 6.04E-01 u pCi/g 18-02009-15 : TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Niobium-94 EPA901.1 Modified i 9.50E-02 1.91E-01 i 1.91E-01 5.98E-01 u  : pCi/g 18-02009-15 , TRG B102110FIWC016CV 02/01/18 10:00 2/2/2018

  • 2/2/2018 18-02009 Lead-210 EPA901.1 Modified 1.31E+02 i 1.28E+01 1.45E+01 1.31E+01 u pCi/g 18-02009-15 TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Lead-212 EPA 901.1 Modified 1.59E-01 3.76E-01 3.76E-01 7.19E-01 u pCi/g 18-02009-15 TRG B102110FIWC016CV 02/01/18 10:00 i 2/2/2018 2/2/2018 18-02009 Lead-214 EPA901.1 Modified ' -1.12E+OO , 7.14E-01 i 7.16E-01 9.43E-01 u pCi/g 18-02009-15 TRG B102110FIWC016CV 02/01/1810:00 2/2/2018 2/2/2018 18-02009 Promethium-145 EPA 901.1 Modified  : 7.28E+OO i 1.82E+OO 1.85E+OO 2.28E+OO u pCi/g 18-02009-15 . TRG 8102110FIWC016CV 02/01/18 10:00 i 2/2/2018 ' 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified 9.47E-01 8.01E-01 8.02E-01 1.30E+OO u pCi/g 18-02009-15 TRG 8102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 i n, ...... - .. , *-- EPA901.1 Modified i 2.20E-01 . 9.11E-01 i 9.11E-01 1.34E+OO u '
pCi/g

!-----------(

18-02009-15 TRG 8102110FIWC016CV 02/01 /18 10:00 i 2/2/2018 2/2/2018 18-02009 i Thorium-234 EPA 901.1 Modified 6.18E-01 i 4.52E+OO 4.52E+OO 5.80E+OO u . pCi/g

j , --

18-02009-15 TRG B102110FIWC016CV 02/01/18 10:00 2/2/2018 2/2/2018 18-02009 Thallium-208 EPA 901.1 Modified i 5.94E-02 8.09E-01 8.09E-01 9.42E-01 u pCi/g r---~-------~--,

18-02009-15 TRG 8102110FIWC016CV 02/01 /18 10:00 2/2/2018 2/2/2018 18-02009 i Uranium-235 EPA 901.1 Modified i -7.76E-01 4.19E+OO 4.19E+OO 2.08E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

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EBERLINE SERVICES I

I EBERLINE ANALYTICAL CORPORA Ti ON I 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [220]

Printed: 2/1312018 8:54 AM Page 17 of 17 Report To: Work Order Details:

J Alex Bohacheff 18-02009 Eberline Analytical , ......

______ ,,__ ,_,Zion_Solutions, LLC _

SOG:

Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd ___ Analysis Category: _ ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample Receipt Analysis Batch Report Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units ID Type ID 18-02009-16 TRG B102110IFIWC019CV 02/01/18 10:38 2/212018 2/2/2018 18-02009 Actinium-228 EPA 901.1 Modified ' 1.34E-01 1.95E+OO 1.95E+OO 2.88E+OO u pCi/g 18-02009-16 TRG B102110IFIWC019CV __ , __ 02/01/18 10:38 2/2/2018 2/2/2018 ----- ____ __________

18-02009 ' Silver-108m EPA 901.1 Modified 8.34E-01 5.92E-01 5.94E-01 4.44E-01 u pCi/g

_ _ _ _ _ ,,m,~'->" _____ ,_,_

18-02009-16 TRG B10211 OIFIWC019CV 02/01/1810:38 2/2/2018 212/2018 18-02009 Americium-241 EPA901.1 Modified -1.33E-01  : 3.86E-01 3.86E-01 5.69E-01 u pCiig i-------**** ***--*--

18-02009-16 TRG B102110IFIWC019CV 02/01/18 10:38 2/2/2018 2/2/2018 18-02009 Barium-133 EPA 901. 1 Modified -2.37E-01 5.38E-01 5.38E-01 6.43E-01 u pCi/g r----- ""-'"-----"-'"' --

18-02009-16 TRG B102110IFIWC019CV

,==------------*""-~',"""'"'"'*----------------=--*-------

, ___ 02/01/1810:38 2/2/2018 2/2/2018 18-02009 'Bismuth-214 EPA 901. 1 Modified ' -1.40E-01 9.59E-01 9.59E-01 1.39E+OO u pCi/g 18-02009-16 18-02009-16 TRG TRG B102110IFIWC019CV B102110IFIWC019CV 02/01/1810:38 02/01/18 10:38 2/2/2018 2/2/2018 2/2/2018 2/2/2018 18-02009 18-02009 i Cobalt-60 Cesium-134 EPA901.1 Modified EPA 901. 1 Modified i 8.42E+OO

-4. 16E-01 7.26E-01 4.66E-01 8.45E-01 4.66E-01 4.79E-01 6.38E-01 u pCiig pCiig 18-02009-16 TRG  : B1021101FIWC019CV 02101/18 10:38

' 2/2/2018 2/2/2018 18-02009 Cesium-137 EPA901.1 Modified  : 6.83E-01 6.30E-01 6.31E-01 1.03E+OO u pCi/g 18-02009-16 TRG B102110IFIWC019CV 02/01/1810:38 2/2/2018 2/2/2018 18-02009 , Europium-152 EPA 901.1 Modified  : 1.45E+02 7.66E+OO 1.07E+01 2.57E+OO pCi/g 18-02009-16 TRG ' B102110IFIWC019CV 02/01/18 10:38 2/2/2018 2/2/2018 18-02009 Europium-154 EPA 901.1 Modified  : 2.96E+OO 1.17E+OO 1.18E+OO 2.06E+OO u  : pCi/g

~-----~- -------

18-02009-16 TRG B1021101FIWC019CV 02/01/18 10:38 2/2/2018 2/2/2018 18-02009 Europium-155 EPA 901.1 Modified ' 3.39E-01 6.90E-01 6.90E-01 1.02E+OO u pCi/g

* . '""-------------~----

18-02009-16 TRG  : B102110IFIWC019CV 02/01/18 10:38  : 212/2018 2/2/2018 18-02009 : Holmium-166m EPA 901.1 Modified 3.44E-01  : 8.59E-01 8.59E-01 4.82E-01 u pCiig 18-02009-16

---~-*---"'--"""'--'-*"

TRG B102110IFIWC019CV _____ , ___ .,_, 02/01/18 10:38 2/2/2018 i 2/2/2018 18-02009 lodine-129 EPA 901.1 Modified i.08E+OO ' 2.05E-01 2.13E-01 3.39E-01 :

u pCi/g 18-02009-16 TRG B102110IFIWC019CV 02/01/18 10:38 212/2018 2/2/2018 18-02009 , 10 EPA 901.1 Modified 6.81E+OO ' 3.43E+OO 3.45E+OO 6.02E+OO pCi/g 18-02009-16 : B102110IFIWC019CV 02101 /18 10:38 212/2018 2/2/2018 18-02009 ' Manganese-54 EPA901.1 Modified

' 1.15E-01 5.13E-01 5.13E-01 7.61E-01 u pCi/g TRG 18-02009-16 TRG B102110IFIWC019CV 02/01/18 10:38 I 21212018 212/2018 18-02009 Niobium-94 EPA 901.1 Modified 2.40E-01 3.07E-01 3.08E-01 7.09E-01 u  :

pCi/g

~-----*------------*--

B102110IFIWC019CV 02/01/18 10:38 2/2/2018 2/2/2018 18-02009 : Lead-210 EPA 901.1 Modified 2.05E+02 1.67E+01 1.98E+01 1.14E+01 . pCi/g 18-02009-16 TRG B1021101FIWC019CV 02/01/18 10:38 212/2018

  • 2/2/2018 18-02009 Lead-212 EPA 901.1 Modified 2.00E-01 4.62E-01 4.62E-01 8.20E-01 u pCi/g 18-02009-16 ' B102110IFIWC019CV 02/01/18 10,38 ' 21212018 , 2/2/2018 18-02009 , Lead-214 EPA 901.1 Modified 5.20E-01 8.68E-01 8.69E-01 1.03E+OO u pCi/g

=------------------- -------------------------------~-"""

18-02009-16 : TRG B102110IFIWC019CV 02/01/1810:38 . 2/2/2018 2/2/2018 18-02009 Promethium-145 EPA901.1 Modified i -6.21E+01

' 4.57E+OO 5.57E+OO 1.27E+OO u pCi/g 18-02009-16 ! TRG B102110IFIWC019CV 02/01/18 10:38 2/212018 2/2/2018 18-02009 Radium-226 EPA 901.1 Modified  : -1.40E-01 9.59E-01 9.59E-01 1.39E+OO : u pCi/g 18-02009-16 ' TRG B102110IFIWC019CV 02/01/18 10:38 212/2018 2/2/2018 18-02009 ~, .* ,,,o,,, >L~ EPA901.1 Modified -7.37E-01 . 1.12E+OO

  • 1.12E+OO 1.38E+OO u pCi/g 18-02009-16 ' TRG B102110IFIWC019CV 02/01/1810:38  : 212/2018 2/2/2018 18-02009 j Thorium-234 EPA 901.1 Modified 2.96E+OO 4.02E+OO 4.03E+OO 6.03E+OO u pCi/g 02009-16

, --**~ ---,-------

u TRG B102110IFIWC019CV 02/01/18 10:38 ' 2/2/2018 2/2/2018 18-02009 i Thallium-208 EPA 901.1 Modified 4.64E-01 8.21E-01 8.21E-01 1.22E+OO i pCi/g 18-02009-16 TRG i B102110IFIWC019CV 02/01/18 10,38  : 2/2/2018 2/2/2018 18-02009  ! Uranium-235 EPA 901.1 Modified 4.83E-01 5.91E+OO 5.91E+OO 2.88E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

( ~

EBERLINE SERViCES EBERUNE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [221]

ZS-WM-131 Revision 0 ZI()NSOLUTIONSru: Information Use 18 -02009 REC'D FEBO 2 2018 Attachment 1 - Cliain-of-Custody Form Sample ID Sample Mat1ix Sample Sample Container Sample Date Sample Time Analysis Preservative Remarks Log Type Type Vol Unit Type Qty Bl02110IFIWCOOICV NIA Concrete Concrete 57.94 cm3 Puck 1 1/31/2018 1320 HTD None 0.0"-0.5" Bl02110IFIWC003CV NIA Concrete Concrete 57.94 cm3 Puck 1 1/31/2018 1355 HTD None 0.0"-0.5" 1

Bl02110IFIWC004CV Bl02110FIFC003CV NIA NIA Concrete Concrete Concrete Concrete 57.94 57.94 cm3 cm3 Puck Puck 1

l 1/31/2018 1/31/2018 1420 1237 HTD HTD None None 0.0"-0.5" 0.0"-0.5" B102110FIFC021CV NIA Concrete Concrete 57.94 cm3 Puck 1 1/31/2018 1300 HTD None 0.0"-0.5" Bl02110FIWC015CV NIA Concrete Concrete 57.94 cm 3 Puck l 1/31/2018 1443 HTD None 0.0"-0.5"

\v B102110FIWC017CV NIA Concrete Concrete 57.94 cm3 Puck l 1/3112018 1507 HTD None 0.0"-0.5"

\\ Bl02110FIWC019CV NIA Concrete Concrete 57.94 cm3 Puck l 1/31/2018 1530 HTD None 0.0"-0.5" Bl02110FIWC020CV NIA Concrete Concrete 57.94 cm3 Puck 1 211/2018 0812 HTD None 0.0"-0.5" Bl02110FIWC014CV NIA Concrete Concrete 57.94 cm3 Puck l 211/2018 0856 HTD None 0.0"-0.5" Bl02110FIWC018CV NIA Concrete Concrete 57.94 cm3 Puck l 211/2018 0938 HTD None 0.0"-0.5" Bl02110FIWC016CV NIA Concrete Concrete 57.94 cm3 Puck 1 211/2018 1000 HTD None 0.0"-0.5" Bl02l10IFIWC019CV NIA Concrete Concrete 57.94 cm3 Puck l 211/2018 1038 HTD None 0.0"-0.5"

[222]

ZS-WM-131 Revision 0 ZI<)NSOLUTIONSiu: REC'D FEB O2 2018 Information Use

- oz OO9 Laboratory: Date Submitted To Lab: Ship Container No.: Cooler Temperature: Airbill Number:

Eberline Labs NIA Relinquished by: Date Time: Received by: Date: (rnrn/dd/yyyy): Time:

(mm/ dd/yyyy):

J. ALEX BOHACHEFF Relinquished by:

t>::J./o{ ~oJB { 3'-1 S Time: Received by:

0i/0.1 ho1 g Date: (rnrn/dd/yyyy):

(3L/.0 Time:

fil'rh, rJ l ~'ltrf Relinquished by:

ftdt:A Date: (min/dd/yyyy):

(6:00 Time:

Dae (mm/dd/yyyy):

2.-~-i V o</ l 5 Relinquished by: Date Time: Date: (mm/dd/yyyy): Time:

(mm/dd/yyyy):

Comments ANALYSIS 5 ROC-HTD

REFERENCE:

Email to Mike McDougall PRIORITY 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> turnaround PO# 677118

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EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD BERLINE OAK RIDGE, TENNESSEE 37830 SERVICES PHONE (865) 481-0683 FAX (865) 483--L,621 EBS-OR-43353 February 13, 2018 Alex Bohacheff Zion Solutions, LLC 101 Shiloh Blvd Zion, IL 60099 CASE NARRATIVE Work Order # 18-02018-0R SAMPLE RECEIPT This work order contains three solid samples received 02/03/2018. Samples were analyzed for Total Strontium, Tritium, Nickel-63 and by Gamma Spectroscopy.

CLIENT ID LAB ID B 10211 OIFIWCOl OCV 18-02018-04 Bl02110IFIWC0l 1CV 18-02018-05 B 10211 OIFIWCO l 8CV 18-02018-06 ANALYTICAL METHODS Total Strontium was analyzed using EIChroM Method SRWOl Modified. Tritium was performed using Method LANL ER-210 Modified. Nickel-63 was performed using Method ASTM 3500-Ni Modified.

Gamma Spectroscopy was perf01med using EPA Method 901.1 Modified.

Laboratory qualifiers are as follows:

U - Result is less than the MDA.

ANALYTICAL RES UL TS Combined Standard Uncertainty is reported at 2-sigma value.

Minimum Detectable Activity (MDA) values for data represented in this report are sample-specific.

MDA measurements are determined based on factors and conditions including instrument settings, aliquot size and matrix type.

TOT AL STRONTIUM Samples were prepared by aliquoting as appropriate and leaching in HN0 3 . Samples were diluted appropriately. Strontium recovery carriers were added to each sample. Chemical separations were conducted using selective extractions. Strontium precipitate was mounted on tared filter media. Chemical recovery was determined by Strontium carrier mass determinations. Samples were counted by gas flow proportional counting and corrected for Yttrium-90 ingrowth.

Page 1 of 3

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ANALYTICAL RESULTS CONTINUED TOT AL STRONTIUM CONTINUED Samples demonstrated acceptable results for all Total Strontium analyses. Strontium-90 results are reported from Total Strontium. Chemical recovery was acceptable for all samples. The Total Strontium method blank demonstrated an acceptable result. Results for the Total Strontium duplicate demonstrated a slightly high relative percent difference; however, normalized difference is within acceptable limits for the analytical technique. Results for the Total Strontium laboratory control sample demonstrated an acceptable percent recovery.

TRITIUM A representative aliquot of each sample was equilibrated with Tritium free water. Equilibrates were transferred into round-bottomed distillation flasks and attached to single stage stills. A portion of each middle distillation fraction was transferred to a liquid scintillation vial and cocktail was added. Samples were then counted by beta liquid scintillation.

Samples demonstrated acceptable results for all Tritium analyses. Results for laboratory fraction -05 (Client ID: B 10211 OIFIWCO 11 CV) demonstrated a slightly high method detection limit. The Tritium method blank demonstrated an acceptable result. Results for the Tritium duplicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Tritium laboratory control sample demonstrated an acceptable percent recovery.

NICKEL-63 A representative aliquot of each sample was leached in HN03

  • Leachates were placed in an appropriately sized beaker. Stable elemental Nickel carrier was added to each sample prior to digestion. Samples were digested in concentrated Nitric acid. After digestion, sample pH was adjusted and Nickel-63 was precipitated selectively with Dimethylglyoxime. Precipitates were selectively separated, redissolved and residual acid was effectively neutralized. Sample residuals were placed into scintillation vials, scintillation cocktail was added and Nickel-63 activity was determined by beta liquid scintillation.

Samples demonstrated acceptable results for all Nickel-63 analyses. All results demonstrated slightly high method detection limits. The Nickel-63 method blank demonstrated an acceptable result. Results for the Nickel-63 duplicate demonstrated a high relative percent difference and normalized difference. In this case duplicate variations were caused by the heterogeneous sample nature. Results for the Nickel-63 laboratory control sample demonstrated an acceptable percent recovery.

GAMMA SPECTROSCOPY Samples for Gamma Spectroscopy analysis were prepared by transferring a known mass/aliquot of each homogenized sample to a standard geometry container. Samples were counted on High Purity Germanium (HPGe) gamma ray detectors.

Samples demonstrated acceptable results for all gamma-emitting radionuclides as reported. Some results demonstrated slightly high method detection limits. Some sample results are greater than the method detection limits. These results are reported from the Canberra Gamma Apex "Nuclide MDA Report" and are not positive. These results are qualified as non-detect (U). The method blank demonstrated acceptable results for all radionuclides as reported. Results for the Cesium-13 7 and Potassium-40 replicate Page 2 of 3

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ANALYTICAL RESULTS CONTINUED GAMMA SPECTROSCOPY CONTINUED demonstrated a slightly high relative percent difference; however, normalized difference is within acceptable limits for the analytical technique. Results for the Europium-152 replicate demonstrated a high relative percent difference and normalized difference. In this case duplicate variations were caused by the heterogeneous sample nature. Results for the Cobalt-60 and Cesium-137 laboratory control sample demonstrated an acceptable percent recovery.

CERTIFICATION OF ACCURACY I ce1tify that this data report is in compliance with the terms and conditions of the Purchase Order, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the cognizant project manager or his/her

( t*ig~:'.','° be accurate as verified by the following signature.

' '~-~*-~\

M.R. McDougan--*- * ,\ \

Laboratory Manager \ \

Date: 2/13/2018 Eberline Analytical wants and encourages your feedback regarding our performance providing radioanalytical services. Please visit http://eberlineanalytical.com/ to provide us with feedback on our services, Page 3 of 3

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Printed: 2/13/2018 2:25 PM Page 1 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02018 Eberline Analytical ,.

_____Zion Solutions, LLC _ ___,,_

SDG:

Purchase Order: 677118 Final Report of Analysis 101 Shiloh Blvd

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,, ______ Analysis_Category- ENVIRONMENTAL _____ ,, ___ *-----

Zion, IL 60099 Sample Matrix.* so '"""

Lab Sample Client Sample Receipt Analysis Batch  : Report ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA Qualifier Units 18-02018-01 LCS KNOWN 02/03/18 00:00 2/3/2018 2/6/2018 18-02018 Tritium LANL ER-210 Modified 2.25E+02 8.11E+OO  : pCiig f-----~----.-------.----------,,----~ ---------------" -* ""'"'"'_,.,,_,_

18-02018-01 LCS SPIKE 02/03118 00:00 2/3/2018 2/6/2018 18-02018 Tritium LANL ER-210 Modified 2.13E+02 5.47E+OO 1.31E+01 3.72E+OO pCi/g

""*-----~---------""'""""--*-"- ----" '

18-02018-02 I---- -----

MBL BLANK 02/03/18 00:00 ' 2/3/2018 217/2018 18-02018 Tritium LANL ER-210 Modified ! -1.30E+OO , 2.13E+OO 2.13E+OO 3.72E+OO u pCi/g 18-02018-03 DUP B102110IFIWC010CV 02/01/18 13:10 2/3/2018 217/2018 18-02018 Tritium LANL ER-210 Modified ! 5.14E+01 ' 9.74E+OO 1.02E+01 1.45E+01 ' pCi/g DO B102110IFIWC010CV 02/01/18 13:10 ' 2/3/2018 217/2018 18-02018 Tritium LANL ER-210 Modified ' 5.01E+01  : 9.74E+OO 1.01E+01 1.46E+01 pCi/g 18-02018-05 TRG 8102110IFIWC011CV 02/01/1814:30 2/3/2018 217/2018 18-02018 Tritium LANL ER-210 Modified 3.16E+OO i 7.44E+OO ' 7.45E+OO 1.27E+01 u pCi/g

"""" ---0-------------*""-~---------"--- *------*---' '

18-02018-06 ; TRG 810211 OIFIWC018CV 02/01/18 13:50 2/3/2018 217/2018 18-02018 i Tritium LANL ER-210 Modified 1.65E+02 , 1.26E+01 1.56E+01 1.52E+01 pCi/g

~----

18-02018-01

KNOWN 02/03/18 00:00 2/3/2018 2/6/2018 18-02018 Nickel-63 ASTM 3500-Ni Modified LCS 1.51E+03 4.54E+01 pCi/g 18-02018-01  : LCS SPIKE 02/03/18 00:00 2/3/2018 2/6/2018 18-02018 : Nickel-63 ASTM 3500-Ni Modified 1.18E+03  : 8.76E+OO 7.00E+01 2.30E+OO pCi/g 18-02018-02 MBL BLANK 02/03/18 00:00  : 2/3/2018 2/6/2018 18-02018 I Nickel-63 ASTM 3500-Ni Modified 1.04E+OO 1.31E+OO . 1.31E+OO 2.20E+OO u pCi/g 18-02018-03 ! DUP B1021101FIWC010CV 02/01/1813:10 2/3/2018 2/6/2018 18-02018 Nickel-63 ASTM 3500-Ni  : 1 11 . 5.28E+OO 5.33E+OO 8.60E+OO pCi/g 18-02018-04 DO B102110IFIWC010CV 02/01/1813:10 2/3/2018 2/6/2018 18-02018 Nickel-63 ASTM 3500-Ni Modified ! 4.94E+01 6.24E+OO 6.89E+OO 8.89E+OO pCi/g f--------------------,--------- -----------*,-----~'<------------ ,' -------  ; '

18-02018-05 TRG B102110IFIWC011CV 02/01/18 14:30 2/3/2018 2/6/2018 18-02018 Nickel-63 ASTM 3500-Ni Modified 1.01E+01 5.12E+OO 5.16E+OO 8.38E+OO pCiig 18-02018-06 TRG B1021101FIWC018CV 02/01/18 13:50 2/3/2018 2/6/2018 18-02018 : Nickel-63 ASTM 3500-Ni Modified 1.32E+01 5.71E+OO  : 5.77E+OO 9.28E+OO pCi/g 18-02018-01  : LCS KNOWN 02/03/18 00:00 . 2/3/2018

  • 2/6/2018 18-02018 i Strontium-90 EIChroM SRW01 Modified 5.25E+01 2.94E-01  !  :

pCi/g 18-02018-01  : LCS SPIKE 02/03/18 00:00 2/3/2018 2/6/2018 18-02018 ' Strontium-90 EIChroM SRW01 Modified 4.11E+01 1.84E+OO  : 1.44E+01 9.12E-01 : pCi/g 18-0201  ;

MBL

~-*-------------------------------------

BLANK 02/03/18 00:00 2/3/2018 2/6/2018 18-02018

---,-*---------,-,-,0------~-*--,----

Strontium-90 EIChroM SRW01 Modified 4.20E-01  : 5.30E-01 ' 5.50E-01 8.98E-01 u  : pCi/g 18-02018-03 DUP B102110IFIWC010CV 02/01/18 13:10 2/3/2018 2/6/2018 18-02018

~----------*---~---------~-----

Strontium-90 EIChroM SRW01 Modified 4.29E-01 5.02E-01 5.24E-01 8.45E-01 u pCi/g

. 810211 OIFIWC01 OCV . u 18-0201 f-,-----

18-02018-05 :

TRG

. --------~--

8102110IFIWC011CV 02/01/18 13:10 02/01/18 14:30

. 2/3/2018 2/3/2018 2/6/2018 2/6/2018 18-02018 18-02018 i Strontium-90 Strontium-90 EIChroM SRW01 Modified EIChroM SRW01 Modified 3.23E-01 4.96E-01 i

5.36E-01 6.11E-01  :

5.48E-01 6.35E-01 9.20E-01 1.03E+OO u  :

pCi/q pCi/g

- 2/6/2018 -.---,

18-02018-06 : TRG B1021101FIWC018CV 02/01/18 13:50  : 2/3/2018 18-02018 Strontium-90 EIChroM SRW01 Modified 1.61E+OO

  • 6.17E-01 8.33E-01 9.09E-01 . pCi/g i  ! i 18-02018-01  ; LCS KNOWN 02/03/18 00:00  : 2/3/2018 2/5/2018 18-02018 : Cobalt-60 EPA 901.1 Modified 2.71E+02 i 1.06E+01 pCi/q

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18-02018-01  : LCS KNOWN 02/03/18 00:00  : 2/3/2018 2/5/2018 18-02018 ! Cesium-137 EPA 901.1 Modified 1.69E+02  ! 6.75E+OO  : pCi/g 18-02018-01 LCS SPIKE 02/03/18 00:00 2/3/2018 2/5/2018 18-02018

  • Cobalt-60 EPA901.1 Modified 2.88E+02 1

1.77E+01  : 2.31E+01 2.16E+OO pCi/g 18-02018-01

.' LCS I SPIKE 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 Cesium-137 EPA 901.1 Modified 1.91E+02 . 3.16E+01  : 3.31E+01 2.83E+OO

. pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Nonmal Sample;DO=Duplicate Original;U=Non-detect

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- EBERLINE EBERLINE ANALYTICAL CORPOR.A TION SERViCES 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [227]

Printed: 2/13/2018 2:25 PM Page 2 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02018 Eberline Analytical Zion Solutions, LLC

... ,. SDG:

Purchase Order: 677118

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18-02018-02 MBL BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 Silver-108m EPA 901.1 Modified 3.57E-02 5.73E-02 5.74E-02 7.09E-02 u pCUg 18-02018-02 MBL BLANK

- -----**-**-*---- -~---**-*--*-""'--------,-*--*--*--------------

02/03/18 00:00 . 2/3/2018 2/5/2018 18-02018 Americium-241 EPA 901.1 Modified  : 2.01E-02* 3.22E-02 3.22E-02 1.11E-01 u pCi/g 18-02018-02 MBL BLANK 02/03/18 00:00 : 2/3/2018 2/5/2018 18-02018 Barium-133 EPA 901.1 Modified 8.22E-03 5.55E-02 5.55E-02 9.35E-02 u pCi/g

---*-*--*--->---------~--**---*-~-*---**-*

18-02018-02 MBL  : BLANK 02/03/18 00:00 2/3/2018 2/5/2018

~-- ,-*--"____,,,,,,--* ----*----------,,~----------"-""-,~--- 18-02018 Bismuth-214 EPA 901.1 Modified 1.83E-02  ; 1.44E-01 1.44E-01 2.10E-01 . u  ; pCVg 18-02018-02 MBL I BLANK 02/03/18 00 :00 2/3/2018 2/5/2018 18-02018 Cobalt-60 EPA 901.1 Modified 2.86E-02 4.80E-02 4.80E-02 1.12E-01 u pCi/g

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"~ I MBL BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 Cesium-134 EPA 901.1 Modified -6.15E-02 9.22E-02  : 9.22E-02 9.34E-02 u  ; pCi/g 18-02018-02 ; MBL BLANK 02/03/18 00:00 . 2/3/2018 2/5/2018 18-02018 j Cesium-137 EPA 901.1 Modified -6.98E-03 8.06E-02 8.06E-02 1.13E-01 u pCiig 1:: *- - n~ i MBL BLANK 02/03/18 00:00  :

2/3/2018 2/5/2018 18-02018 ' Europium-152 EPA901.1 Modified  :

2.49E-02 6.25E-02 6.26E-02 1.44E-01 u pCi/g 18-02018-02 , MBL BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 * ::v, v~,v, 154 EPA901.1 Modified -1.04E-01 2.01E-01 2.01E-01 7.75E-02 u pCi/g 18-02018-02 ........,.;_ MBL BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 Europium-155 EPA 901.1 Modified -6.67E-03 6.56E-02

. 6.56E-02 9.50E-02 u pCi/g 18-02018-02 MBL BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 Holmium-166m EPA 901.1 Modified 2.47E-02 . 9.99E-02 9.99E-02 5.93E-02 i u pCi/g

~Jilit+/- BLANK BLANK 02/03/18 00:00 02/03/18 00:00

2/3/2018
2/3/2018 I 2/5/2018 2/5/2018 18-02018 I 18-02018 lodine-129 Potassium-40 EPA 901.1 Modified EPA901.1 Modified

-4.49E-02 9.69E-02

' 7.97E-02 5.49E-01 7.97E-02 5.49E-01 1.55E-01 1.04E+OO

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pCiig pCi/g 18-02018-02 MBL BLANK 02/03/18 00:00 2/3/2018 ' 2/5/2018 18-02018 C EPA901.1 Modified -3.18E-03 4.68E-02 4.68E-02 7.64E-02 u pCiig 18-02018-02

  • 1 MBL BLANK 02/03/18 00:00 i

I 2/3/2018 2/5/2018 18-02018 Niobium-94 EPA 901.1 Modified 1.45E-02 5.29E-02 5.29E-02 8.66E-02

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2/3/2018

- 2/5/2018 - - -

18-02018 Lead-212 EPA 901.1 Modified 3.45E-03  ; 6.80E-02 6.80E-02 1.08E-01 u pCi/g 18-02018-02 ,

' MBL i

BLANK 02/03/18 00:00 I 2/3/2018 , 2/5/2018 18-02018

  • Lead-214 EPA901.1 Modified 6.64E-02 6.95E-02 6.96E-02 1.45E-01 u pCi/g 18-02018-02 . MBL I BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 1 Promethium-145 EPA 901.1 Modified 6.50E-02  : 8.77E-02 8.78E-02 1.49E-01

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~ i Radium-226 EPA 901.1 Modified 1.83E-02 1.44E-01 1.44E-01 2.10E-01 u pCi/g 18-02018-02 MBL BLANK 02/03/18 00:00 2/3/2018 2/5/2018 18-02018 Antimony-125 EPA 901.1 Modified -4.08E-02 1.64E-01 I 1.64E-01 2.21E-01 u i pCi/g i

18-02018-02 MBL BLANK 02/03/18 00:00 I 2/3/2018 i 2/5/2018 18-02018 Thorium-234 EPA901.1 Modified 7.08E-01 6.47E-01 6.48E-01 1.12E+OO u pCi/g

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  • 18-02018 Uranium-235 EPA 901.1 Modified -4.37E-01 6.11E-01 i 6.12E-01 3.22E-01 u I pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE ORPORATION SERV!CES 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [228]

Printed: 211312018 2:25 PM Page 3 of 6 Report To: Work Order Details:

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---~---------*-

02/08/18 13:10  ; 2/3/2018 2/5/2018 18-02018 Americium-241 EPA 901.1 Modified -4.02E-01 4.19E-01 4.19E-01 5.77E-01 u pCi/g 18-02018-03 I 18-02018-03 DUP 81021101FIWC010CV 02/08/18 13:10 213/2018 2/5/2018 18-02018 Barium-133 EPA 901.1 Modified -5.93E-02  : 4.98E-01 4.98E-01 6.29E-01 u pCi/g 18-02018-03 DUP I

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,v-v ........ ,,...-vv B1021101FIWC010CV 02/08/18 13:10 2/3/2018 i 2/5/2018 18-02018 Holmium-166m EPA 901.1 Modified 2.06E-01 8.78E-01 8.78E-01 5.18E-01 u  : pCi/g 18-02018-03 DUP i B102110IFIWC010CV 02/08/1813:10 2/3/2018 2/5/2018 18-02018 lodine-129

__.,,.~-- EPA 901.1 Modified 2.91E-01 2.15E-01 i 2.15E-01 3.18E-01 u pCi/g

~*"~--*-. ---~--*-  : i 18-02018-03 DUP B102110IFIWC010CV 02/08/18 13:10  : 2/3/2018 2/5/2018 18-02018 Potassium-40 EPA 901.1 Modified 4.85E+OO 2.41E+OO 2.42E+OO 1.43E+OO pCi/g 18-02018-03 i DUP 81021101FIWC010CV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 [ ... - ... -. <

EPA 901.1 Modified  : -1.84E-01  : 2.05E-01 2.05E-01 7.57E-01 u pCi/g 18-02018-03 i DUP B102110IFIWC010CV 02/08/18 13:10 ' 2/3/2018 2/5/2018 18-02018  ! Niobium-94 EPA 901.1 Modified -2.02E+OO i 9.56E-01 9.61E-01 6.97E-01 u  : pCi/g 18-02018-03 DUP i B102110IFIWC010CV 02/08/18 13:10 I 2/3/2018 2/5/2018 18-02018 Lead-210 EPA901.1 Modified 1.25E+02 1.18E+01 I 1.35E+01 1.07E+01 i pCiig 18-02018-03 : DUP B 10211 OIFIWC01 OCV 02/08/18 13:10 i 2/3/2018 2/5/2018 18-02018 Lead-212 EPA901.1 Modified 4.05E-02 I 6.70E-01 I 6.70E-01 8.57E-01 u i pCi/g 18-02018-03 DUP 810211 OIFIWC01 OCV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 Lead-214 EPA 901.1 Modified 7.28E-01 I

9.57E-01 9.58E-01 1.08E+OO u pCi/g 18-02018-03 I DUP i B1021101FIWC010CV 02/08/18 13:10  ! 2/3/2018 2/5/2018 18-02018 Promethium-145 EPA 901.1 Modified -3.87E+01  : 3.27E+OO I 3.83E+OO 1.16E+OO u pCi/g

<n

  • - M: DUP  : B102110IFIWC010CV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 : Radium-226 EPA901.1 Modified 3.00E-01 9.87E-01  ! 9.87E-01 1.48E+OO  : u pCi/g

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  • - M! DUP B102110IFIWC010CV 02/08/18 13:10 213/2018 i 2/5/2018 18-02018 Antimony-125 EPA 901.1 Modified 1.94E-01 1.03E+OO 1 1.03E+OO 1.37E+OO I

u  : pCi/g 18-02018-03 I DUP B1021101FIWC010CV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 I Thon,*- oo, EPA 901.1 Modified 1.66E+OO  : 4.19E+OO 4.19E+OO 6.34E+OO u i pCi/g 18-02018-03 DUP 8102110IFIWC010CV 02/08/18 13:10 i 2/3/2018 2/5/2018 18-02018 I Thallium-208 EPA 901.1 Modified -8.42E-01 i 1.19E+OO i 1.19E+OO  : 1.04E+OO u i pCi/g 18-02018-03 i DUP I B1021101FIWC010CV 02108/18 13:10 213/2018 2/5/2018 18-02018 : Uranium-235 EPA 901.1 Modified -3.20E+OO i 6.19E+OO 6.19E+OO 3.17E+OO u i pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect EBERLINE EBERUNE ANAL YT!CAL ON SERVICES 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [229]

Printed: 2/13/2018 2:25 PM Page 4 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02018 Eberline Analytical SDG:

Purchase Order:

*M"¥¥¥O-*¥ 677118

-*-*- Zion Solutions, _LLC ____*-***** -----------

Final Report of Analysis 101 Shiloh Blvd Analysis Category: ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Lab Sample Client Sample l Receipt Analysis Batch Report Analyte Method Result cu CSU MDA Qualifier ID Type ID Date Date Date ID Units 18-0201$..04 DO B1021101FIWC010CV 02/08/1813:10 2/3/2018 2/5/2018 18-02018 Actinium-228 EPA 901.1 Modified -5.66E-01 2.74E+OO 2.74E+OO 3.99E+OO u pCi/g

~------*0--*--". --**---------------** l 1&-02018-04 DO B1021101FIWC010CV 02/08/18 13:10  : 2/3/2018 2/5/2018 18-02018 Silver-108m EPA901.1 Modified 3.08E-01 8.50E-01 8.50E-01 6.82E-01 u pCi/g 18-02018-04 ; DO 81021101FIWC010CV 02/08/18 13:10  : 2/3/2018 2/5/2018 18-02018 i Americium-241 EPA 901.1 Modified i 5.59E-01  : 7.05E-01 7.05E-01 1.11E+OO u pCi/g 18-0201$..04 I DO I 8102110IFIWC010CV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 i 8arium-133 EPA 901.1 Modified 8.79E-01

' 5.42E-01 5.44E-01 9.26E-01 u pCi/g 18-0201&-04 DO 8102110IFIWC010CV 02/08/1813:10 l 2/3/2018 2/5/2018 1&-02018 8ismuth-214 EPA 901.1 Modified 1.02E+OO  :; 1.36E+OO 1.36E+OO 2.07E+OO u pCi/g 18-02018-04 : DO 81021101FIWC010CV ________,_,,

02/08/1813:10 ______

2/3/2018 2/5/2018 18-02018 Cobalt-60 EPA 901.1 Modified 9.17E+OO 9.70E-01 1.08E+OO 6.78E-01 pCi/g 1&-02018-04 DO 8102110IFIWC010CV 02/08/18 13:10

' 2/3/2018 2/5/2018 18-02018 Cesium-134 EPA 901.1 Modified I 1.04E-01 3.24E-01 I 3.24E-01 9.28E-01 u pCi/g 02018-04

- - * - -DO -

  • I 8102110IFIWC010CV 02/08/18 13:10 I 2/3/2018 2/5/2018 18-02018 ; Cesium-137 EPA 901.1 Modified i 8.54E-01 I 8.59E-01  ! 8.60E-01 1.43E+OO u pCi/g

.. n *-

DO B102110IFIWC010CV 02/08/1813:10 1 2/3/2018 2/5/2018 18-02018 , Europium-152 EPA 901.1 Modified 1.64E+02 i 6.91E+OO 1.09E+01 3.96E+OO pCi/g 18-0201$..04 I DO 81021101FIWC010CV 02/08/1813:10 2/3/2018 2/5/2018 18-02018 j  !::~*-s*-*<<-154 EPA 901.1 Modified 4.92E+OO  ! 1.64E+OO ' 1.66E+OO 3.21E+OO u pCi/g 18-0201$..04 i DO 8102110IFIWC010CV 02/08/18 13: 10  : 2/3/2018 2/5/2018 18-02018 cu,-~*-* ,i- i 55 EPA 901.1 Modified 1.49E+OO  ; 1.70E+OO i 1.70E+OO 2.85E+OO u pCi/g 1&-02018-04 ; DO 81021101FIWC010CV 02/08/18 13:10 2/3/2018 ' 2/5/2018 18-02018 , Holmium-166m EPA 901.1 Modified -7.12E-01 1.22E+OO i 1.22E+OO 8.19E-01 u pCi/g 1&-02018-04 ; DO 81021101FIWC010CV 02/08/18 13:10 I 2/3/2018 , 2/5/2018 18-02018 i lodine-129 EPA 901.1 Modified 3.87E+OO 3.92E+OO I 3.93E+OO 5.34E+OO u pCi/g 18-02018-04 1 DO 8102110IFIWC010CV 02/08/1813:10 , 2/3/2018 2/5/2018 18-02018 Potassium-40 EPA 901.1 Modified 7.15E+OO 4.48E+OO  : 4.49E+OO 8.45E+OO I

u pCi/g i

1&-02018-04 : DO 810211 OIFIWC01 OCV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 l ,.,_,,M_,, ___ : EPA 901.1 Modified -4.26E-01  ; 6.75E-01 6.76E-01 9.57E-01 u I pCi/g 18-02018-04 I DO ' B102110IFIWC010CV 02/08/18 13:10  : 2/3/2018 2/5/2018 18-02018 Niobium-94 EPA901.1 Modified 4.65E-01 i 5.08E-01 I 5.09E-01 9.96E-01 u pCi/g

  • ; 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 Lead-210 EPA901.1 Modified 3.78E+02 4.69E+01 5.07E+01 3.00E+01  : pCi/g an *- 81021 ,OIFIWC010CV
  • - DO  !

18-02018-04 DO 8102110IFIWC010CV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 I Lead-212 EPA 901.1 Modified -3.82E-02 f 8.55E-01 i 8.55E-01 1.33E+OO u pCi/g 18-0201s..04 I DO ' B102110IFIWC010CV 02/08/1813:10 2/3/2018 2/5/2018 18-02018 I Lead-214 EPA 901.1 Modified 1.16E+OO 1.07E+OO  ! 1.07E+OO 1.77E+OO u I pCi/g 18-0201$..04 : DO 81021101FIWC010CV 02/08/1813:10 , 2/3/2018 2/5/2018 18-02018 .... ,_, '"

  • - EPA 901.1 Modified -2.09E+02 i 3.93E+01 4.07E+01 6.12E+OO u pCi/g

~e-:::~:-G"' i DO 81021101FIWC010CV 02/08/1813:10  ! 2/3/2018 2/5/2018 18-02018 i Radium-226 EPA 901.1 Modified 1.02E+OO 1.36E+OO 2.07E+OO u pCi/g 18-02018-04 / DO

' 810211u1e1vv1,,u ,vvV 02/08/18 13:10 i 2/3/2018 2/5/2018 18-02018 j Antimony-125 EPA901.1 Modified -8.46E-01 l~.66E+OO 1.66E+OO 2.03E+OO I u i pCi/g i.

18-02018-04 DO  ! 810211 OIFIWC01 OCV 02/08/18 13:10 2/3/2018 2/5/2018 18-02018 i Th-"**- 00

  • EPA 901.1 Modified 7.74E-01 .02E+OO 7.02E+OO 1.04E+01 u pCi/g 18-02018-04  ! DO 81021101FIWC010CV 02/08/18 13:10 i 2/3/2018 2/5/2018 18-02018 ! Thallium-208 EPA 901.1 Modified -1.95E+OO .70E+OO i 1.71E+OO 1.69E+OO 1 u pCi/g
  • n
i DO 8102110IFIWC010CV 02/08/18 13:10 ' 2/3/2018 2/5/2018 18-02018 ! ,, ........ ;., ..... _?':!,t:;.

EPA 901.1 Modified 3.67E+OO  !

9.37E+OO  ! 9.37E+OO 4.76E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Norrnal Sample;DO=Duplicate Original;U=Non-detect I EBERLINE AL YTI CAL CORPC_R_.A_T_I_O_N_____.

601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [230]

Printed: 2/13/2018 2:25 PM Page 5 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02018 Eberline Analytical ---"*'" -,N,, ..,_ "'--------.****-'-*--*-*--* ******----*--*-----.-*m *----****-****-----****-------*----**--***-*-

-*-*--* Zion Solutions, LLC ______ ----- ------------------*--*--*

Purchase Order:

.,,_, SDG:

677118 Final Report of Analysis ___ ,, __101

_,,_ Shiloh Blvd

---------~---*---~ ***----------~--~-- Analvsis Cateaorv:

ENVIRONMENTAL so Zion, IL 60099 Sample Matrix:

  • Lab Sample Client Sample  : Receipt Analysis Batch / Report Analyte Method Result cu CSU MDA Qualifier ID

' Type ID Date Date Date ID l Units 18-02018-05 TRG 81021101FIWC011CV 02/08/1814:30 2/3/2018 2/5/2018 18-02018 Actinium-228 EPA 901.1 Modified 6.25E-01  : 6.01E-01 6.01E-01 1.10E+OO u pCi/g 18-02018--05 TRG 81021101FIWC011CV 02/08/18 14:30 l 2/3/2018 2/5/2018 18-02018

  • Silver-108m EPA 901.1 Modified 2.49E-02 1.34E-01 1.34E-01 1.67E-01 u pCi/g 18-02018-05 i TRG 8102110IFIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Arnencium-241 EPA 901.1 Modified -2.66E-01 2.88E-01 2.88E-01 3.17E-01 u  : pCi/g 18-02018-05 TRG 8102110IFIWC011CV 02/08/18 14:30  : 2/3/2018 2/5/2018 18-02018 8arium-133 EPA 901.1 Modified 7.34E-03 1.18E-01 1.18E-01 3.17E-01 u pCi/g 18-02018-05 : TRG . 8102110IFIWC011CV 02/08/18 14:30  : 2/3/2018 2/5/2018 18-02018 : 8ismuth-214 EPA 901.1 Modified 8.45E-01 3.05E-01 3.09E-01 5.92E-01 I pCi/g 18-02018-05 j TRG 810211 OIFIWC011 CV 02/08/18 14:30  : 2/3/2018 2/5/2018 18-02018 Cobalt-60 EPA 901.1 Modified 6.31E-02 1.96E-01 1.96E-01 3.08E-01 u pCi/g 18-02018-05 , TRG 8102110IFIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 : Cesium-134 EPA 901.1 Modified -4.12E-03 ' 6.81E-02 6.81E-02  : 2.79E-01 u .

i / pCi/g 18-02018--05  ! TRG 81021101FIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 i Cesium-137 EPA 901.1 Modified -3.59E-02 1.56E-01 1.56E-01 2.32E-01 u pCi/g 18-02018-05 : TRG 81021101FIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Europium-152 EPA 901.1 Modified 3.64E+OO  : 4.34E-01 4.72E-01 8.63E-01 pCi/g 18-02018-05 i TRG 810211 OIFIWC011 CV 02/08/18 14:30 2/3/2018 2/5/2018 i 18-02018 Europium-154 EPA901.1 Modified -3.80E-02  : 2.11E-01 2.11E-01 5.58E-01  : u  : pCi/g 18-02018--05 TRG B102110IFIWC011CV 02/08/18 14:30 2/3/2018 ! 2/5/2018 18-02018 :v, veov, 155 EPA 901.1 Modified 1.22E-01 2.82E-01 2.82E-01 4.77E-01 u pCi/g 18--02018--05 TRG f--*--------:-----,,----.

81021101FIWC011CV

.. 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Holmium-166m EPA 901.1 Modified -1.18E-02  : 2.19E-01 2.19E-01 2.02E-01 u pCi/g 18-02018-05 TRG 81021101FIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 lodine-129 EPA 901.1 Modified -6.36E-03  : 8.45E-02 8.45E-02 1.10E-01 i u pCi/g 18-02018-05 : TRG B102110IFIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Potassium-40 EPA901.1 Modified 8.79E+OO 2.33E+OO 2.37E+OO 1.18E+OO pCi/g 18-020 18-05 : TRG 8102110IFIWC011CV 02/08/18 14:30 i 2/3/2018 , 2/5/2018 18-02018 : ....... ~ ................. ..,C EPA 901.1 Modified -8.25E-03 I 7.65E-02 7.65E-02 1.94E-01 u pCi/g 18-02018-05 i TRG 81021101FIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Niobium-94 EPA 901.1 Modified -3.16E-02 1.53E-01 1.53E-01 2.07E-01 u pCi/g

1 18-02018-05 i TRG 8102110IFIWC011 CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Lead-210 EPA 901.1 Modified 3.81E+OO 2.30E+OO 2.31E+OO 3.67E+OO  :  : pCi/g 18-02018-05 i TRG  : 8102110IFIWC011CV 02/08/18 14:30

' 2/3/2018 2/5/2018 18-02018 I Lead-212 EPA 901.1 Modified 2.41E-01  : 2.74E-01 . 2.75E-01 4.58E-01 u pCi/g 18-02018--05 : TRG 81021101FIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 : 18-02018 I Lead-214 EPA 901.1 Modified 9.06E-01 3.03E-01 3.07E-01 1.06E+OO u I pCi/g 18-02018--05  ! TRG 8102110IFIWC011CV 02/08/18 14:30 i 2/3/2018 2/5/2018 18-02018 I Promethium-145 EPA 901.1 Modified -2.41E-01

' 3.56E-01 3.56E-01 4.27E-01 u pCi/g 18-02018-05 I TRG 8102110IFIWC011CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 Radium-226 EPA 901.1 Modified 8.45E-01 I 3.05E-01 3.09E-01 5.92E-01 pCi/g 18-02018-05 TRG i

B102110IFIWC011CV 02/08/18 14:30 2/3/2018 I 2/5/2018 18--02018 : ~ ........... *~~ EPA 901.1 Modified -1.10E-01 3.66E-01 3.66E-01 5.36E-01  : u I pCi/g 18-02018-05 TRG B102110IFIWC011CV 02/08/18 14:30  : 2/3/2018 , 2/5/2018 18-02018 I Thorium-234 EPA 901.1 Modified 4.67E+OO  : 3.76E+OO 3.76E+OO 6.18E+OO u pCi/g

---* Tt ...::::~. ::: 1 18-02018-05 TRG 810211 OIFIWC011 CV 02/08/18 14:30 2/3/2018 2/5/2018 18-02018 EPA901.1 Modified i 1.06E+OO 6.53E-01 I 6.55E-01 9.86E-01 pCi/g 18--02018--05 TRG 81021101FIWC011CV 02/08/18 14:30  ! 2/3/2018 2/5/2018 18-02018 i Uranium-235 EPA 901.1 Modified -6.70E-01 1.67E+OO 1.67E+OO 1.11E+OO u pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma};MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

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EBERLINE SERV!CES I EBERLINE 601 SCARBORO ROAD OAK RIDGE, TN 37830 AL YTICAL CORPORATION 865/481-0683 FAX 865/483-4621 [231]

Printed: 2/13/2018 2:25 PM Page 6 of 6 Report To: Work Order Details:

J Alex Bohacheff 18-02018 Eberline Analytical ------****----'""'*---*-**---*~'-**se*--- .

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Final Report of Analysis 101 Shiloh Blvd

-"--------------~------------------ Analysis :-*-~-* ENVIRONMENTAL Zion, IL 60099 Sample Matrix: so Client Sample Receipt Analysis Batch Lab Sample Report

Date Date Date ID Analyte Method Result cu CSU MDA Qualifier ID Type ID Units 18-02018-06 TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 j Actinium-228 EPA 901.1 Modified -4.18E-01 2.23E+OO 2.23E+OO 3.22E+OO u pCi/g 18-02018-06 j TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018  ! Silver-108m EPA 901.1 Modified i 1.27E+OO 7.20E-01 7.23E-01 6.68E-01 u pCi/g 18-02018-06 TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 Americium-241 EPA 901.1 Modified 1.80E-01 7.93E-01 7.93E-01 1.01E+OO u pCi/g 18-02018-06 : TRG B102110IFIWC018CV 02/08/18 13:50  : 2/3/2018 2/5/2018 18-02018 Barium-133 EPA 901.1 Modified -7.91E-02  ! 3.27E-01 i 3.27E-01 9.71E-01 u pCi/g 18-02018-06 :

TRG __ _____ _______

B102110IFIWC018CV

, , 02/08/18 13:50 i 2/3/2018 2/5/2018 18-02018 , Bismuth-214 EPA 901.1 Modified 1.28E+OO 1.24E+OO  : 1.24E+OO  : 1.42E+OO u pCi/g 18-02018-06 TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 , Cobalt-60 EPA 901.1 Modified ' 1.34E+01 9.82E-01 1.20E+OO 1.02E+OO pCi/g 18-02018-06 ; TRG  ! B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 ' Cesium-134 EPA 901.1 Modified -1.39E-02  ! 3.37E-01 3.37E-01 7.68E-01 u pCi/g 18-02018-06 TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 I Cesium-137 EPA 901.1 Modified  : 4.94E-02  : 6.40E-01 i 6.40E-01 9.34E-01 u pCi/g

<--**----~'*--

18-02018-06 TRG B1021101FIWC018CV 02/08/18 13:50

--- 2/3/2018 2/5/2018

~---------

18-02018 i Europium-152 EPA 901.1 Modified 2.23E+02 7.75E+OO  ; 1.38E+01 4.54E+OO  : pCi/g 18-02018-06 ; TRG j B1021101FIWC018CV 02/08/18 13:50  : 2/3/2018 2/5/2018 18-02018 : Europium-154 EPA 901.1 Modified 7.20E+OO  ; 1.47E+OO  : 1.52E+OO 2.62E+OO u pCi/g 18-02018-06 l TRG B1021101FIWC018CV 02/08/18 13:50  : 2/3/2018 2/5/2018 18-02018 : Europium-155 EPA901.1 Modified  ! 2.83E+OO  : 1.11E+OO i 1.12E+OO 1.77E+OO . u pCi/g 18-02018-06 i TRG B1021101FIWC018CV 02/08/18 13:50 i 2/3/2018 2/5/2018 18-02018 Holmium-166m EPA901.1 Modified  ! -3.13E-01  ! 1.06E+OO 1.06E+OO 6.27E-01 u  : pCi/g 18-02018-06 I TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 lodine-129 EPA901.1 Modified 1.19E+OO  : 3.37E-01  : 3.42E-01 1.59E+OO u ' pCi/g

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8102110IFIWC018CV 02/08/18 13:50  : 2/3/2018 2/5/2018 18-02018 : Potassium-40 EPA 901.1 Modified  : 5.18E+OO  : 3.56E+OO 3.57E+OO 5.24E+OO  : u  : pCi/g 18-02018-06 TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018  : "

'"'""~"""""'"' ....r EPA 901.1 Modified 8.46E-02  : 6.07E-01 . 6.07E-01 8.91E-01 u pCi/g 18-02018-06 i TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 ' Niobium-94 EPA 901.1 Modified -2.90E+OO  : 1.04E+OO  : 1.05E+OO 7.84E-01  : u  :

pCi/g 18-02018-06 i TRG i B10211u1c1vv1.,u1o1.,v 02/08/18 13:50  : 2/3/2018 2/5/2018 18-02018 Lead-210 EPA 901.1 Modified 2.85E+02 ' 2.44E+01 2.85E+01 1.95E+01  : u pCi/g 18-02018-06 : TRG  : 8102110IFIWC018CV 02/08/18 13:50  : 2/3/2018 2/5/2018 18-02018 : Lead-212 EPA 901.1 Modified -8.63E-01  ! 6.84E-01  : 6.85E-01 1.04E+OO u pCi/g 18-02018-06 I TRG 81021101FIWC018CV 02/08/18 13:50  : 2/3/2018 ; 2/5/2018 18-02018 : Lead-214 EPA 901.1 Modified 4.36E+OO j 1.20E+OO 1.22E+OO 3.37E+OO  ! pCi/g 18-02018-06 i TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018

  • 2/5/2018 18-02018 Promethium-145 EPA 901.1 Modified i 6.90E+OO  ! 1.96E+OO 1.99E+OO 2.50E+OO  ! u  : pCi/g 18-02018-06 TRG B102110IFIWC018CV 02/08/1813:50
2/3/2018 : 2/5/2018 18-02018 ! Radium-226 EPA901.1 Modified i 1.28E+OO  : 1.24E+OO l 1.24E+OO 1.42E+OO u  : pCi/g 18-02018-06 ' ~ 8102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 i Antimony-125 EPA 901.1 Modified -6.13E-03 ' 1.40E+OO  : 1.40E+OO 2.02E+OO  : u I pCi/g 18-02018-06 j 18-02018-06 TRG TRG B1021101FIWC018CV B1021101FIWC018CV 02/08/18 13:50 02/08/18 13:50  !

2/3/2018 ,

2/3/2018 2/5/2018 2/5/2018 18-02018 18-02018

  • i Thorium-234 Thallium-208 EPA901.1 Modified EPA 901.1 Modified 9.50E-01 1.13E+OO 7.89E+OO 1.79E+OO 7.89E+OO 1.79E+OO 1.01E+01 1.28E+OO u

u pCi/g pCi/g 18-02018-06 ; TRG B102110IFIWC018CV 02/08/18 13:50 2/3/2018 2/5/2018 18-02018 : Uranium-235 EPA 901.1 Modified -4.75E+OO  ; 5.96E+OO 5.97E+OO 3.87E+OO i u  : pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect

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  • EBERLINE SERVICES SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 [232]

ZS-WM-131 Revision 0 ZIONSOLUTIONSru 1 a-0201s Information Use An Energ:,-Solufiona Con1)8ny REC'D FEB O3 2018 Attachment 1 - Chain-of-Custody Form Sample ID Sample Matrix Sample Sample Container Sample Date Sample Time Analysis Preservative Remarks Log Type Type Vol Unit Type Qty 6 ROC.

B102110IFIWC010CV NIA Concrete Concrete 57.94 cm3 Puck  ! 211/2018 1310 HTD None 0.0"-0.5" 5 Koc B102110IFIWC011CV NIA Concrete Concrete 57.94 cm3 Puck  ! 211/2018 1430 HTD None 0.0"-0.5" 5 ROC.

B102110IFIWCOI8CV NIA Concrete Concrete 57.94 cm3 Puck  ! 211/2018 1350 HTD None 0.0"-0.5" Laboratory: Date Submitted To Lab: Ship Container No.: Cooler Temperature: Airbill Number: re.cl/}(

Eberline Labs NIA NIA

<is! 0 7 DfifS 67r/J Relinquished by: Date Time: Received by: Date: (mmlddlyyyy): Time:

(mmlddlyyyy):

OJ./of)io.ro J~ijg J. ALEX BOHACHEFF 6 -:J./~ 1/ :J.I>/$ I ~-Sc> /(,'£ [ fl. ..J..,,.;-

Relinquished by: Date Time: Received by: Date: (mmldd/yyyy): Time:

F:idJa1) F Ki'Cskf;, f Relinquished by:

(m1n/dd/2It O)JO

  • C>/8 Date I 0700 Time:

ftd l'/, (5)Jo2/~,rs Date: (m1n/dd/yyyy):

D'700 Time:

(m1n/ddlyyyy):

,R:~aJ

""2.~J. l V 0~50

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Relinquished by: Date Time: VReceiver v' Date: (nun/dd/yyyy): Time:

(mm/dd/yyyy ):

Comments ANALYSIS 5 ROC-HTD RE: Email to Mike McDougall PRIORITY 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> turnaround PO# 677118

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