Text

Excerpts from Radwaste,Environ Monitoring & Occupational Personnel Radiation Exposure,Jan-June 1977.
	ML19256F446
Person / Time
Site:	Quad Cities
Issue date:	06/30/1977
From:	; COMMONWEALTH EDISON CO.
To:	;
Shared Package
ML19256F405	List: ML19256F412; ML19256F416; ML19256F418; ML19256F419; ML19256F421; ML19256F423; ML19256F425; ML19256F431; ML19256F434; ML19256F441; ML19256F446; ML19256F450; ML19256F472; ML19256F475;
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	FOIA-79-491 NUDOCS 7912190152
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F QUAD CITIES STATION RADIOACTIVE WASTE, ENVIRONMENTAL MONITORING AND OCCUPATIONAL PERSONNEL RADIATION EXPOSURE b

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e JANUARY THROUGH JUNE 1977 i -

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SUMMARY

e-Gaseous and liquid effluents for the period remained at a fraction of the Technical Specification limits. Calculations of environmental concen-trations based on effluent, Mississippi River flow, and meteorological data ,

for the period indicate that consumption by the public of radionuclides attributable to the plant will not exceed the quantity of those radionuclides h.

that result from continuous exposure to the concentration values listed in Appendix B, Table II, of 10CFR20. Gamma radiation exposure from noble gases released to the atmosphere represented the critical pathway for the period '

I with a maximum individual dose estimated to be 0.04 mrem for tha six-month period, when a shielding and occupancy factor to two is assuted. Environ-mental monitoring results confirm that dose via other pathways was not signi- ..

ficant.

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'l i N9 tyMm n~ ~ v-~in cr mn% . -mm -a=x. _- : .,,1 1.0 EFFLUENTS . 'f.

1.1 GASEOUS EFFLUENTS TO THE ATMOSPHERE Measured concentrations and isotopic composition of noble gasec, radioiodine, and particulate radioactivity released to the atmosphere during the period January to June 1977, are listed in Table 1.1-1. A six-month total cf 1.65 E+04 curies of noble gases was released during the period. Average release rates during either quarter of the period did not exceed 0.3% of tha Technical Specification limit.

A total of 0.32 curies of I-131 and 1.18 curies of I-133 were re-leased during the six-month period.

Six-month total of 0.28 curies of beta-gamma emitters and 1.1 E-05 curier of alpha emitters were released as airborne particulate matter.

1.2 LIOUIDS RELEASED TO MISCISSIPPI RIVER A total of 7.2 E+06 liters of radioactive liquid wastes containing 1.03 curies (excluding tritium) were discharged from the station. These wastes were released at an average concentration of 3.23 E-09 Ci/ml which is 3.2%of the Technical Specification releases limit for unidentified radioactivity. During the same period,14.7 curies of tritium and 5.3 E-04 curies of alpha radioactivity were released. Quarterly release estimates and principal radionuclides in liquid effluents are given in Table 1.2-1.

The maximum concentration of radioactivity, above background, in the Quad Cities Unit 1/2 discharge canal during the period was computed to be 4.09 E-07 uCi/ml.

2.0 SOLID RADIOACTIVE WASTE The total amount of solid waste pacLiged for disposal was cubic feet during the six-month period. The total amount of radioactivity involved was calculated to be 6.8 E+03 curies. Solid radioactive wastes were shipped to either Nuclear Engineering Company, Sheffield, Illinois, or Morehead, Kentucky, or Chemical Nuclear Services, Barnwell, So. Carolina.

Date, volume and radioactivity of each shipment are shown in Table 2.0-1.

1625 284

. . 3,3 ' . '

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. ??"Q4 TABLE 1.1-1 q.

? .' ,

QUAD CITIES NUCLEAR POWER STATION

'f 1 f

a

y EFFLUENT AND WASTE DISPOSAL SEMI ANNUAL REPORT 1977

.! GASEQUS EFFLUENTS-SUMMATION OF ALL RELEASES i n e quarter Quarter Est. Total l .

Unit 1st 2nd Error. %

A. Fission & Activation Gases v

C1 1.31E+04 3.43E+03

-i 1. Total release Averace release rate for period uCi/see 1.68E+03 4.36E+02

$, , 2.

i e 3 a. Percent of Tech. Spec. limit 6.05E-02 Chimney % 1.57E-01 j [ b. Percent of Tech. Spec limit Stack % 3.14E-01 < LDL t

I B. lodines

b Total iodine-131 C1 1 71E-01 1.53E-01 1.

F' i 2.20E-02 1.94E-02 i 2. Averace release rate for oeriod uC1/sec

3. a. Percent of Tech. Spec. limit station 1.24E+00 ef~tei{' % 1.44E+00

+

u?

u,a f

'&.ua r.; C. Part.iculates e

a 1 Particulates with half-lives > 8 days Ci 1.24E-01 1.65E-01

2. Averace release rate for period uC1/see 1.59E-02 2.12E-02 ,

3 Gross alpha radioactivity 1.47E-06 9.57E-06 .

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=.6-u_ e_.AJ._2rsahed-adM;.dsKh;chssmman:Sg.c g we s.,.y w m ,u g

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TABLE 1.1-1 (Cont'd)

-f EFFLUENT AND WASTE DISPOSAL SEMI ANNUAL REPORT 1977

'~'

," GASEOUS EFFLUENTS-SUMMATION OF ALL RELEASES vi

'b]

Ntal 7 Quarter Quarter Est. Total Unit 1st 2nd Error, %

k4 4 7

D. Tritium Total release Cl 9.65E+00 1.56E+01 3.

2. Averace release rate for period uCi/sec 1.23E+00 2.01E+00

1

't i

f W

t o

j 1625 286 ._

5 A

uY~E52.L'.3:1?$ %?]ha2'I X&N2l:C.%wk 2.%' % i.?..-w:.J;1w JD -' 2t3k% D.L. . A

j -J TABLE 1.1-1 (Cont'd)

QUAD CITIES NUCLEAR POWER STATION

.5 M &.

E' :

3 EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1977

' .4 GASEOUS EFFLUENTS- Elevated Release Continuous Mode Batch Mode g

Nuclides Released Unit $s 2nd

. 1. Fission gases l

i I

Kr-85 C1 ( LDL ( LD'.

K r-8 % CI 5.61E+02 2.18E+02

~

K r-87 C1 2.10E+01 1.97E+01 K r-88 C1 5.36E+02 2.64E+02 Xe-133 Ci 4.67E+03 1.31E+03 Xe-135 C1 7.28E+03 1.61E+03 xe-13% CI ( LDL ( LDL

}

( LDL (LDL

] X e-132 Ci Id Kr83m Cl .< lDL (LDL Cl

'6

, Unidentified Ci ( LDL ILDL

Total for Period C1 1.31E+04 3.43E+03

2. lodines Wi (t f ~

1-131 Ci 1.43E-01 1.16E-01

, .g 2 1-n3 Cl 5.07E-01 5.67E-01 4e $

.jN I-13g C1 1.25E-01 3.33E-01

= :p;'

Ci 7.75E-01 1.02E+00 U-j Total for Period 8 -

4.:q

~. <

1625 287 kn

/,:4p 6 l: *L

a- - a.e s.xvacsw & m g 1-4 gg;m;..;.yg g g y g x;;c;.g ,3 g_- .

r J

. t TABLE 1.1-1 (Cont'd)

EFFLUENT AND WASTE DISPOSAL SEMI ANNUAL REPORT 1977 GASEOUS EFFLUENTS- Elevated Release Continuous Mode Batch Mode Quarter Quarter quarter Quarter Nuclides Released Unit 1st 2nd 3 Particulates S r-89 Cl 1.09E-02 Sr-90 Ci 4.82E-05 C s-1 % Ci 2.01E-04 5.21E-04 Cs-137 Ci 5.58E-04 1.38E-03 Ba-lho Ci 9.99E-03 1.63E-02 La-lho Ci 1.34E-02 1.02E-02 Mn54 C1 2.40E-06 ( LDL co60 ci 3.88E-04 1.20E-03 1131 Ci 8.47E-03 (LDL Ce141 C1 2.04E-04 2.43E-04 Ci (LDL 4.38E-05 Ci CI Ci Ci .

C1 CI Unidentifled C1 6.89E-02 1625 288 -

7 i

wN

.<. % w i6KX:sskiJ 2LIG C % G L a s a,,; 3 f;,~;~2gGL;;.;g& &;ggszgxuaq

a TABLE 1.1-1 (Cont'd)

, QUAD CITIES NUCLEAR POWER STATION a

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1977 GASEOUS EFFLUENTS- Ground Level Release Continuous Mode Batch Mode Quarter quarter Quarter Quarter Nuclides Released Unit 1st 2nd

1. Fission gases K r.-8 g Ci < lDL (LDL Kr-8 % Ci 3.47E-01 4LDL K r-87 Ci 4.00E-03 (LDL K r-88 C1 3.67E-01 (LDL xe_133 Ci 3.41E+00 (LDL Xe-13g Ci 2.84E+00 (LDL Ci < lDL (LDL X e-13 %

Xe-138 C1 4LDL (LDL CI CI Ci <LDL 4LDL Unidentified Total for Period Ci 6.97E+00 ( LDL

2. lodines Ci 2.80E-02 3.66E-02

~

I-131 Ci 5.87E-02 5.70E-02

_i33 Ci 2.26E-02 2.01E-02

,_33g C. 1.09E-01 1.14E-01 Total for Period b

4 1625 289 ..

8 L

2 2 ACS S a.J2nt.?J M-2 X tun & G: % hi,Cd.25.R.%tu b;. n K M L-AL J u

}

s % 2 2 L'2.g

r -4 I 6 TABLE 1.1-1 (Cont'd) #

I 1977 q EFFLUENT AND WASTE DISPOSAL SEMI ANNUAL REPORT d

GASEOUS EFFLUENTS. Ground Level Release "d

Continuous Mode Batch Mode -

Quarter Quarter Quarter y Quarter M Nuclides Released Uni t 1st 2nd 4 e

3 Particulates 'h 1

~

Sr-89 Ci 8.40E-04 -

+

Sr oO CI 2.31E-05 A

C s.1 % Ci 3.56E-04 5.25E-04 C1 5.03E-04 8.04E-04 Cs-137 Cl 1.35E-03 1.19E-03 Ba.140 f La-140 Ci 1.54E-03 2.85E-03 ,{

Cr51 Ci 5.66E-04 2.34E-03 Ci 2.40E-05 6.32E-05 Mn54 CoS8 C1 4.25E-06 5.26E-05 Co60 Ci 4.53E-04 1.10E-03 1131 C1 3.71E-03 2.54E-03 Ag110m Ci 1.75E-05 dLDL l Zn65 Ci (LDL 5.16E-05 Cs136 C1 4.LDL 6.80E-05 Zr95 Ci ( LDL 3.12E-05 8.42E-05 )

Nb95 Ci (LDL i C1 Unidentified Ci 1.81E-03 9 1625 290 -l

. i a :.. a xx:.:, :.a,5:..x.w z..a;e;...~.:s v. ,.. y :,2:g; g cg g g ,_.

, yy ,g, .;.g

2

f. .

TABLE 1.2-1 b

,q'gi QUAD CITIES HUCLEAR POWER STATION A

?:

i ;

EFFLUENT AND VASTE DISPOSAL SEMIANNUAL REPORT 1977 l LIQUID EFFLUENTS-SUMMATION OF ALL RELEASES Quarter Quarter Est. Total Unit 1st 2nd Error, %

A. Fission and Activation Products

1. Total release (not including tritium. cases, aloha) Ci 6.19E-01 4.20E-01 2 Average diluted concentration durinn period uC1/mi 4.04E-09 2.43E-09 9 3. Percent of anolicable limit % 4.04E+00 2.43E+00 4 Maximum diluted concentration durino period uCi/mi 4.09E-07 7 17E-08 1,B. ,

Tritium

1. Total release Ci 9.24E+00 5.5E+00 2 Average diluted concentration durine oeriod uC1/mi 6.04E-08 3.2E-08

3. Percent of aoolicable limit % 2.01E-03 1.07E-03 C. Dissolved and Entrained Gases Ci < LDL (LDL

. 1. Total release Q 2 Average diluted concentration uti/ml < LDL durine oeriod (LDL

% N/A N/A

3. Percent of soolicable limit D. Gross Alpha Radioactivity a

n ~

1. Total release Cl 1.45E-04 3.86E-04

~

2. Averace concentration released uC1/mi 9.50E-13 2.25E-12 4

4; kh, E. Volume of waste released (prior

O to dilution) Liters 4.26E+06 2.97E+06 i

%'![ - F. Volume of dilution water used durine period Liters 1.53E+11 1 72E+11

{ ~[

5]&5 r%

~

lo 1625 291 m

bhz [ 75Lh I4 7[Mh .FM(*[lt/_D [_k , , .h fg {. ,Q -_ , ,5 -

] { .-3 ,f

4

' ~

TABLE 1.2-1 (Cont'd) ,

QUAD CITIES NUCLEAR POWER STATION ;

EFFLUENT AND WASTE DISPOSAL SEMI ANNUAL REPORT 1977 LIQUID EFFLUENTS Continuous Mode Batch Mode Quarter Quarter Quarter Quarter il Unit 1st 2nd Sr-89 Ci 2.98E-03 Sr oO Ci 3 15E-04 5.35E-02 5.40E-02

, m 3h 1 Cl Cs-137 C1 1.74E-01 8.68E-02 1-131 Ci 7.85E-02 9.83E-04 Co-58 Ci i.06E-03 1.49E-03 Co-60 Ci 6.96E-02 6.93E-02

~

Ci < LDL (LDL Fe-59

~

Zn-65 Ci 3.35E-05 < Lot Mn-Sh C1 1.44E-03 2.50E-03 Cr-51 C1 2.57E-03 2.85E-04 2r oS C1 (LDL 7.45E-05 Nb-95 C; ( LDL 7.45E-05 Mo c9 Ci ( LDL ( LDL Aal10m Ci 7.63E-05 < tot Ci < LDL (LDL Ba-lho Cs136 C1 2.78E-05 4 tot ,

La-lho Cl 1.69E-02 (LDL -

un c6 CI < LDL 3.33E-04 !

Unidentified Cl 1.91E-01

. Tota! for Period (above) Ci 4.27E-01 .

_Xe-133 Ci <LDL 4LDL i '-

Xe-135 Ci i/9 E 109 4.LDL (LDL iULJ L/L

. -i h II

~4<.cus..w -ac4.CO. 2 ZalGNW.2a;;.>hui M gwwg= .r'tL~n;mgw,,gg(3.yg 33

TABLE 2.0-1 f4

f. .i SOLID RADI0 ACTIVE WASTE

SUMMARY

(A

k. IlNITS 1/2 QllAD-CITIES STA's 40N y'

n Disposition of Material Volume (ft') Curies Disposition of Material Volume (ft3) Curies d Date Co. Trans. Burial Site Per Shipment Per Shipment Date_ Co. Trans. Hurial Site Per Shipment Per Shipment Sheffield, IL 44.1 10.10 2/02 CN Sheffield, IL 44.1 4.68 I' 1/03 CN " 0.01 ilN 102.9 7.00 2/02 IIN 384.0 d 1/03 " 0.31

" 44.1 10.44 2/02 hri 514.5 d 1/04 CN

" 8.35 2/02 IIN 147.0 0.02 f, 1/04 CN 44.1

" 102.9 3.73 2/03 IIN 132.3 2.26 t 1/04 IIN " 6.82

" 4.58 2/07 51.45 h 1/05 llN 102.9 44.1 5.35 2/07 IIN ilN 106.65 12.14

(- 1/06 CN

" 102.9 2.66 2/09 IIN

" 102.9 3.20 L 1/10 Ir "

3.61 a 1/10 CN 44.1 10.35 2/10 CN 44.1

" 7.72 1/11 IIN

" 688.35 0.14 2/10 ilN 73.5 102.9 4.65 I, 1/12 liN

" 102.9 7.53 2/11 IIN 44.1 8.77 2/14 IIN 51.45- 2.61 b 1/13 CN 44.1 10.10 2/14 CN 44.1 22.04 6 1/13 CN

" 9.85 2/16 102.9 10.10

,- 1/14 CN 44.1 IIN 1/17 IIN 102.9 3.24 2/16 CN 44.1 4.68

[. - "

44.1 15.20 6 " 1/18 CN 44.1 5.08 2/17 CN 44.1 8.68 2/18 IIN 433.65 0.50 J/19 CN " 5.18

' " 44.1 10.02 2/18 IIN 102.9 1/20 CN "

5.08 ilN 95.5 4.26 2/21 IIN 102.9 l 1/20 "

~,

" 44.1 6.35 2/22 IIN 102.9 3.79 1/21 CN "

44.1 9.52 2/23 IIN 88.2 3.36 1/21 CN "

y[ "

132.3 3.57 2/23 IIN 102.9 4.93 1/24 IIN "

" 132.3 3.89 2/24 IIN 51.45 4.68

'O 1/26 IIN "

6 1/26 CN 44.1 4.76 2/24 IIN 102.9 10.37 9 1/28 IIN 132.3 3.78 2/24 CN 44.1 5.34 L. 1/31 IIN 102.9 4.76 2/25 CN 44.1 8.77

~

2/28 CN 44.1 1.82 y 2,498.45ft 3' 165.93ft3 2/28 CN 44.1 7.01

/ per month per month 2/28 IIN 102.9 7.56 g 3,357.15ft 3 168.4ft3 h

g3 TN.)

per month per month

(,7 Q K.;

Ul)J-liittman Nuclear and Development CN-Chemical Nuclear Co. for Co. for burial at Nuclear Engr' g Burial at Nuclear Engr'g l6

? Co., Inc. Co., Inc.

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[ TABLE 2.0-1 (Cont'd)

p SOLID RADIDACTIVE WASTE

SUMMARY

r[ UNITS 1/2 QUAD-CITIES STATION

,{.

e- Disposition of Material Volume (ft3) Curles Disposition of Material Volume (ft3) Curies

]'}' '

Day 4/01 Co. Trans.

CN Burial Site Per Sheffield, IL Shipment _Per Shipment 150.0 15.00 Date 5/02 Co. Trans. Burial Site Per Shipment Per Shiprent CN Barnwell, SC 195.0 289.95

p. ' 4/01 CN 150.0 10.70 5/03 IlN Sheffleid, IL 52.5 8.06

,3, 4/01 CN Barnwell, SC 85.0 6.00 5/03 IIN "

105.0 9.49 T 4/04 IIN Sheffield, IL 105.0 3.70 5/04 "

IIN 105.0 5.85 h 4/05 CN "

195.0 73.51 5/05 IIN "

82.5 19.54 h

Tt 4/05 4/06 llN "

90.0 90.0 3.59 5/06 CN "

195.0 90.54 IIN 4.04 5/06 CN Barnwell, SC 85.0 332.50

/ 74 4/07 IIN "

105.0 6.35 u-)

5/09 IIN Sheffield, IL 105.0 13.61 Ch C 4/08 IIN "

630.0 0.30 5/10 llN "

105.0 13.89 N N- 4/11 IIN 105.0 7.75 5/10 CN Barnwell SC 195.0 220.53 9; 4/11 CN "

150.0 47.48 5/11 "

Lf")

CN 195.0 169.77 i's 4/12 CN "

45.0 3.34 5/11 IIN Sheffield, IL 105.0 9.94 N

.,h "

4/12 HN 88.2 4.89 5/11 IIN "

585.0 0.10

T 4/13 IIN "

105.0 8.18 5/12 IIN "

105.0 19.12

~

I 4/12 CN Barnwell, SC 142.0 12.00 5/13 CN "

85.0 18.34

_ 4/14 IIN Sheffield, IL 105.0 7.50 5/15 IIN "

52.5 20.27 d 4/14 CN "

150.0 23.74 5/16 ilN "

52.5 14.53 ifi 4/14 CN Barnwell, SC 195.0 147.02 5/16 IIN "

63.0 6.71 y 4/15 HN Sheffield, IL 103.5 4.42 5/18 IIN "

1,155.0 0.13

% 4/18 CN 195.0 141.48 5/20 llN "

360.0 0.14 fiC 4/18 4/19 IIN IIN 105.0 105.0 1.61 3.92 3,983.0ft 3 1262.00ft3 per month per month

$ 4/20 CN "

150.0 4.58

(*. 4/21 IIN 105.0 7.21 g 4/21 CN Barnwell, SC 85.0 2390.00 fu 4/22 IIN Sheffield, II. 532.5 0.10 b' 4/22 HN "

90.0 8.18 E 4/25 IIN "

97.2 4.09 k 4/25 IIN "

97.5 2.25 k's 4/27 IIN 90.0 2.26 f,{ 4/27 IIN "

60.0 12.70 IIN- liittman Nuclear and Development 9.< 4/27 CN 150.0 76.40 Co. for burial at Nuclear Engr'g Co., Inc.

ty 4/28 CN "

150.0 114.60

(

f 4/2B 4/2B llN CN Barnwell, SC 308.0 85.0 0.06 CN- Lhemical Nuclear Co. for

" 380.00 burial at Nuclear Engr'g Co., Inc.

4/29 CN Sheffield, IL 82.5 19.88 4/30 CN Barnwell, SC 150.0 59.35 f _

5,426.4ft3 4,306ft3 f@,h{ per month per month

4, .1 .

p 3

0:

( TAllLE 2.0-1 (Cont'd)

SOLII) RADI0 ACTIVE WASTE

SUMMARY

1 UNITS 1/2 Ir/ QUAD-CITIES STATION hA '

Disposition of Haterial Volume (ft 3) Cu rles Disposition of Material Volume (ft3) Curies a Date Co. Trans. Hurial Site Per Shipment Per Shipment Date Co. Trans. Burial Site Per Shipment Per Shipment h

% 6/01 CN Sheffield, IL 45.0 2.83 6/20 IIN Sheffield, IL 105.0 7.86 fU 6/01 IIN 52.5 10.35 6/21 CN 45.0 4.31 if 6/02 CN "

195.0 84.89 6/22 IIN 495.0 0.13 s 6/02 CN 195.0 90.54 6/23 CN 45.0 3.42

{R g 6/02 IIN 105.0 6.19 6/23 IIN 105.0 13.03 p,{ 6/05 CN "

195.0 79.23 6/24 CN 45.0 6.51

1. .

6/06 ilN 1080.0 0.003 6/24 IIN 102.9 6.38 fd; 6/06 CN 195.0 45.27 6/27 CN 45.0 8.02

&N 6/07 IIN 120.0 5.01 6/27 ilN 105.0 6.44

((

(L 6/08 6/10 IIN ilN 120.0 82.5 5.45 17.74 6/27 6/28 CN IIN 45.0 645.0 9.02 0.20 ft 6/13 IIN "

120.0 2.62 6/29 IIN 102.9 16.63 f, 6/14 CN "

45.0 3.01 6/30 CN 45.0 5.59

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ML19256F446

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