ML19178A104
| ML19178A104 | |
| Person / Time | |
|---|---|
| Site: | Zion File:ZionSolutions icon.png |
| Issue date: | 06/20/2019 |
| From: | Yetter R ZionSolutions |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| MML19178A106 | List: |
| References | |
| ZS-2019-0043 | |
| Download: ML19178A104 (199) | |
Text
ZION STATION RESTORATION PROJECT FINAL STATUS SURVEY RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223 Revision 1 June 2019
~
= ZIONSOLUTIONSLLC-An EnergySo/utions Company
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
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Summary of Changes in this Revision:
- Rev. 1: Revised Release Record. Changes include the following; Added additional acronyms to List of Acronyms and Abbreviations Corrected spelling errors Corrected version of NAD.
Spelled out acronyms used 1st time in text Added statement pertaining to subsurface soil sampling during FSS Added statement pertaining to selection of reported values for results <MDC Corrected use of MARSSIM 2000 software Added units to header for Table 9 Corrected sample ID number presentation in Tables 9, 13, 15 and 17 Corrected sample ID number presentation in text.
Changed investigation level for scanning to be consistent with Table 11 Added clarifying language for inferring HTD concentrations Corrected title to Table H.1 of NUREG-1757 Renumbered the Attachments such that the gamma spec and Eberline reports were last.
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PREPARED BY / DATE:
20 June 2019 R. F. Yetter III, Junior Technical Assistant Date REVIEWED BY / DATE:
20 June 2019 R. Decker, Radiological Engineer Date APPROVED BY / DATE:
20 June 2019 D. Wojtkowiak, C/LT Manager Date
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
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TABLE OF CONTENTS
- 1.
EXECUTIVE
SUMMARY
..................................................................................................... 7
- 2.
SURVEY UNIT DESCRIPTION........................................................................................... 7
- 3.
CLASSIFICATION BASIS.................................................................................................... 8
- 4.
DATA QUALITY OBJECTIVES (DQO)........................................................................... 10
- 5.
SURVEY DESIGN................................................................................................................ 14
- 6.
SURVEY IMPLEMENTATION.......................................................................................... 21
- 7.
SURVEY RESULTS.............................................................................................................. 22
- 8.
QUALITY CONTROL......................................................................................................... 29
- 9.
INVESTIGATIONS AND RESULTS................................................................................. 29
- 10.
REMEDIATION AND RESULTS................................................................................... 29
- 11.
CHANGES FROM THE FINAL STATUS SURVEY PLAN........................................ 29
- 12.
DATA QUALITY ASSESSMENT (DQA)...................................................................... 29
- 13.
ANOMALIES..................................................................................................................... 30
- 14.
CONCLUSION.................................................................................................................. 30
- 15.
REFERENCES................................................................................................................... 31
- 16.
ATTACHMENTS.............................................................................................................. 32 ATTACHMENT 1 - FIGURES AND MAPS............................................................................ 33 ATTACHMENT 2 - SCAN DATA......................................................................................... 38 ATTACHMENT 3 - CONSULTATION TRIGGERS FOR RESIDENTIAL AND COMMERCIAL/INDUSTRIAL SOIL CONTAMINATION............................. 46 ATTACHMENT 4 - QC SAMPLE ASSESSMENT................................................................... 48 ATTACHMENT 5 - GRAPHICAL PRESENTATIONS.............................................................. 50 ATTACHMENT 6 - SAMPLE ANALYTICAL REPORTS.......................................................... 56 ATTACHMENT 7 - EBERLINE ANALYTICAL REPORTS....................................................... 57 187
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LIST OF ACRONYMS AND ABBREVIATIONS ALARA As Low As Reasonably Achievable AMCG Average Member of the Critical Group BcDCGL Base Case Soil DCGLs CoC Chain-of-Custody cpm Counts per minute DQA Data Quality Assessment DQO Data Quality Objective DCGL Derived Concentration Guideline Level EMC Elevated Measurement Comparison FSS Final Status Survey GPS Global Positioning System HTD Hard to Detect IC Insignificant Dose Contributor ISOCS In Situ Object Counting System LBGR Lower Bound of the Gray Region LTP License Termination Plan MARSSIM Multi-Agency Radiation Survey and Site Investigation Manual MDC Minimum Detectable Concentration MDCR Minimum Detectable Count Rate NAD North American Datum NaI Sodium Iodide OpDCGL Operational Derived Concentration Guideline Level QAPP Quality Assurance Project Plan (for Characterization and FSS)
QC Quality Control RE Radiological Engineer ROC Radionuclides of Concern SOF Sum-of-Fraction
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TSD Technical Support Document UBGR Upper Bound of the Gray Region UCL Upper Confidence Level VSP Visual Sample Plan ZNPS Zion Nuclear Power Station ZSRP Zion Station Restoration Project
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- 1.
EXECUTIVE
SUMMARY
This Final Status Survey (FSS) Release Record for survey unit 10223, Power Block Beach Area, has been generated for the Zion Station Restoration Project (ZSRP) in accordance with ZionSolutions procedure ZS-LT-300-001-005, Final Status Survey Data Reporting (Reference 1) and satisfies the requirements of Section 5.11 of the Zion Station Restoration Project License Termination Plan (LTP) (Reference 2).
A Final Status Survey (FSS) package (L3-10223-F) was developed in accordance with ZionSolutions procedure ZS-LT-300-001-001, Final Status Survey Package Development (Reference 3), the ZSRP LTP, and with guidance from NUREG-1575, Revision 1, Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM)
(Reference 4).
This open land survey unit has a MARSSIM classification of 3. A survey plan was designed based upon use of the Sign Test as the nonparametric statistical test for compliance. Both the Type I () and Type II () decision error rates were set at 0.05.
Fourteen (14) randomly located surface soil samples were acquired from the survey unit.
In addition, surface scanning was performed on 5% of the total surface area in the survey unit. The analytical results for all soil samples taken in survey unit 10223 indicate that the Sum-of-Fraction (SOF) for each sample, considering the concentration of all applicable Radionuclides of Concern (ROC), either by direct measurement or by inference, is less than 0.5 when applying the respective Operational Derived Concentration Guideline Levels (OpDCGL). Therefore, the null hypothesis is rejected and survey unit 10223 is acceptable for unrestricted release.
- 2.
SURVEY UNIT DESCRIPTION Power Block Beach Area, survey unit 10223, is an impacted Class 3 open land survey unit. It is bounded by Class 1 survey units 12101, 12102, 12103, 12204A, 12204B, 12204C, 12112, and 12203D to the west; Class 3 survey unit 10224 to the south; Class 3 survey unit 10222 to the north; and Lake Michigan to the east. The area of the survey unit is 12,371 m2.
The topography of the survey unit is mainly flat with some small dips and depressions.
The soil is loam and beach sand. The terrain consists of beach sand, beach grass, and small trees. Solid physical items such as rocks, driftwood, and chain-link fencing are present in the area.
The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Illinois State Plane System North American Datum (NAD) 1983 East. The
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reference coordinates associated with this survey unit are denoted on Figure 1 located in.
Picture 1 - Survey Unit 10223
- 3.
CLASSIFICATION BASIS Survey unit 10223 was classified in accordance with ZionSolutions procedure ZS-LT-300-001-002, Survey Unit Classification (Reference 5).
Impacted Class 3 open land survey unit 10223 was originally identified as non-impacted by the Historical Site Assessment (HSA) (Reference 6). Because of the survey units proximity to impacted survey units, it was reclassified as a Class 3 survey unit. There are below grade structures as the Circulating Water system suction and discharge tunnels run under this survey unit from the Crib House to Lake Michigan. The HSA does not cite any processes and/or incidents involving the use and/or handling of radioactive material in this open land survey.
Characterization surveys were performed in this survey unit from July 24, 2013, through August 14, 2013. The survey design for this survey unit called for the acquisition of seven (7) surface soil samples taken at random locations and thirteen (13) surface soil samples taken at judgmental locations. The survey design also required the acquisition of subsurface soil samples at two (2) random locations and five (5) subsurface soil samples taken at judgmental locations to a depth of three-meters.
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Six-thousand one-hundred and eighty-six (6,186) square meters or approximately 50% of the total surface area in the survey unit was scanned using a Ludlum Model 2350-1 and a Model 44-10 Sodium Iodide (NaI) detector with the scan alarm set-point set at the Minimum Detectable Count Rate (MDCR) plus background (see Figure 2). For the area scanned, the average observed background in the survey unit was 1,584 counts per minute (cpm). The average observed scan measurement was 1,788 cpm with a maximum observed measurement of 2,277 cpm. The scans did not identify any areas of elevated activity.
Twenty (20) surface soil samples and one (1) Quality Control (QC) split sample were acquired and analyzed by the on-site gamma spectroscopy system. Seven (7) subsurface samples were taken to a depth of three meters. Subsurface soil samples were composited and analyzed in one-meter intervals, resulting in twenty-one (21) subsurface soil samples.
All subsurface soil samples were analyzed by the on-site gamma spectroscopy system. No plant-derived radionuclides greater than the respective Minimum Detectable Concentration (MDC) of the instrument were detected in any sample in this survey unit.
The locations of scan areas and surface soil samples taken during characterization in survey unit 10223 are illustrated on Figure 2 in Attachment 1. A summary of the analysis results for the surface soil samples taken during site characterization is presented in Table 1.
Table 1 - Statistical Quantities for Cs-137 and Co-60 from the 2013 Characterization Survey Statistical Quantities Cs-137 Co-60 (pCi/g)
(pCi/g)
Minimum Value :
0.02 0.02 Maximum Value :
0.08 0.07 Mean :
0.06 0.06 Median :
0.06 0.06 Standard Deviation :
0.015 0.014 A Radiological Engineer (RE) performed a visual inspection and walk-down of the survey unit on 04/21/2016 prior to performing FSS. The purpose of the walk-down was to assess the physical condition of the survey unit, evaluate access points and travel paths, and identify potentially hazardous conditions. A final classification assessment was performed in accordance with procedure ZS-LT-300-001-002, Survey Unit Classification as part of the survey design for FSS.
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Based upon completion of Survey Unit Classification Basis for final classification, which included a review of the historic information, the results of the Characterization Survey data, and completion of a final Survey Unit Classification Worksheet, it was concluded that there was a low probability for the presence of residual radioactivity in soils in concentrations greater than 50% of the OpDCGLs, justifying a final survey unit classification of Class 3.
- 4.
DATA QUALITY OBJECTIVES (DQO)
Final Status Survey planning and design hinges on coherence with the Data Quality Objective (DQO) process to ensure, through compliance with explicitly defined inputs and boundaries, that the primary objective of the survey is satisfied. The DQO process is described in the ZSRP LTP in accordance with MARSSIM. The appropriate design for a given survey will be developed using the DQO process as outlined in Appendix D of MARSSIM.
The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would indicate that residual activity within the survey unit does not exceed the release criteria. Therefore, the survey unit would satisfy the primary objective of the FSS sample plan.
The primary objective of the FSS sample plan is to demonstrate that the level of residual radioactivity in survey unit 10223 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).
ZionSolutions Technical Support Document (TSD)11-001, Potential Radionuclides of Concern during the Decommissioning of Zion Station (Reference 7) established the basis for an initial suite of potential ROC for the decommissioning of the Zion Nuclear Power Station (ZNPS). LTP Chapter 2 provides detailed characterization data that describes the results of surveys taken of soils. Surface and subsurface soil samples were taken in each impacted open land survey units and analyzed for the presence of plant-derived radionuclides. The results of surface and subsurface soil characterization in the impacted area surrounding ZNPS indicate that there is minimal residual radioactivity in soil.
Consequently, due to the absence of any significant source term in soil, the suite of ROC
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and radionuclide mixture derived for non-activated concrete was considered as a reasonably conservative mixture to apply to soils for FSS planning and implementation.
LTP Chapter 6, section 6.5.2 discusses the process used to derive the ROC for the decommissioning of ZNPS, including the elimination of insignificant dose contributors (IC) from the initial suite. Based upon the analysis of the mixture, it was determined that Co-60, Ni-63, Sr-90, Cs-134 and Cs-137 accounted for 99.5% of all dose in the non-activated contaminated concrete mixes.
Table 2 presents the ROC for the decommissioning of soils at ZNPS and the normalized mixture fractions based on the radionuclide mixture.
Table 2 - Dose Significant Radionuclides and Mixture Radionuclide
% of Total Activity (normalized)(1)(2)
Co-60 0.92%
Cs-134 0.01%
Cs-137 75.32%
Ni-63 23.71%
Sr-90 0.05%
(1) Based on maximum percent of total activity from Table 20 of TSD 14-019, normalized to one for the dose significant radionuclides.
(2) Does not include dose significant radionuclides for activated concrete (H-3, Eu-152, Eu-154).
A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity. This is done through the development of DCGLs.
The DCGLs represent average levels of radioactivity above background levels and are presented in terms of surface or mass activity concentrations. Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soils.
Surface soil is defined as soil residing in the first 0.15 m layer of soil. A subsurface soil category, which is defined as a layer of soil beginning at the surface but extending to a depth of 1.0 m is also assessed to allow for flexibility in compliance demonstration if contamination deeper than 0.15 m is encountered. Site-specific DCGLs for soil were calculated for both the 0.15 m and 1.0 m thicknesses. Based on characterization data and historic information, there are no expectations of encountering a source term geometry that is comprised of a clean surface layer of soil over a contaminated subsurface soil layer.
ZionSolutions TSD 14-011, Soil Area Factors (Reference 8) and LTP Chapter 6, section 6.8 provides the exposure scenarios and modeling parameters that were used to
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calculate the site-specific DCGLs for soils (referred to as Base Case Soil DCGLs
[BcDCGL] in this Release Record).
At ZNPS, compliance is demonstrated through the summation of dose from four distinct source terms for the end-state (basements, soils, buried pipe and groundwater). Basements are comprised of the summation of four structural source terms (surfaces, embedded pipe, penetrations and fill). When applied to soil, the DCGLs are expressed in units of activity per unit of mass (pCi/g). The unity rule is applied when there is more than one ROC.
The measurement results for each singular ROC present in the mixture are compared against their respective DCGL to derive a dose fraction.
The surface and subsurface soil BcDCGLs for the unrestricted release of open land survey units are provided in Table 3 and Table 4, respectively. The IC dose percentage of 10%
was used to adjust the DCGLs in soils to account for the dose from the eliminated IC radionuclides.
Table 3 - Base Case DCGLs for Surface Soils (BcDCGLSS)
Radionuclide Surface Soil DCGL (pCi/g)
Co-60 4.26 Cs-134 6.77 Cs-137 14.18 Ni-63 3,572.10 Sr-90 12.09 Table 4 - Base Case DCGLs for Subsurface Soils (BcDCGLSB)
Radionuclide Subsurface Soil DCGL (pCi/g)
Co-60 3.44 Cs-134 4.44 Cs-137 7.75 Ni-63 763.02 Sr-90 1.66 Each radionuclide-specific BcDCGL is equivalent to the level of residual radioactivity (above background levels) that could, when considered independently, result in a Total Effective Dose Equivalent (TEDE) of 25 mrem per year to an Average Member of the
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Critical Group (AMCG). To ensure that the summation of dose from each source term is less than or equal to 25 mrem/year after all FSS is completed, the BcDCGLs are reduced based on an expected, or a priori, fraction of the 25 mrem/year dose limit from each source term. The reduced DCGLs, or Operational DCGLs, can be related to the BcDCGLs as an expected fraction of dose based on an a priori assessment of what the expected dose should be, which are based on the results of site characterization, process knowledge and the extent of planned remediation. The OpDCGL is then used as the DCGL for the FSS design of the survey unit (calculation of surrogate DCGLs, investigations levels, etc.). Details of the OpDCGLs derived for each dose component and the basis for the applied a priori dose fractions are provided in ZionSolutions TSD 17-004, Operational Derived Concentration Guideline Levels for Final Status Survey (Reference 9).
The OpDCGLs for the FSS of surface and subsurface soils are presented in Table 5 and Table 6, respectively.
Table 5 - Operational DCGLs for Surface Soils (OpDCGLSS)
Radionuclide Surface Soil DCGL (pCi/g)
Co-60 1.091 Cs-134 1.733 Cs-137 3.630 Ni-63 914.458 Sr-90 3.095 Table 6 - Operational DCGLs for Subsurface Soils (OpDCGLSB)
Radionuclide Subsurface Soil DCGL (pCi/g)
Co-60 0.881 Cs-134 1.137 Cs-137 1.984 Ni-63 195.333 Sr-90 0.425 In accordance with NUREG-1757, Appendix G, if the HSA indicates that there is no likelihood of substantial subsurface residual radioactivity, subsurface surveys are not
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necessary. The HSA as well as the results of the extensive characterization of subsurface soils in the impacted area surrounding the Zion facility have shown that there is minimal residual radioactivity in subsurface soil. Consequently, Zion proposes to perform minimal subsurface sampling during FSS.
Instrument DQOs included a verification of the ability of the survey instrument to detect the radiation(s) of interest relative to the OpDCGL. Survey instrument response checks were required prior to issuance and after the instrument had been used. Control and accountability of survey instruments was required to assure the quality and prevent the loss of data.
As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. The actual recorded value was used as the recorded FSS result for measurement and/or sample values that are less than MDC. Negative values were recorded as zero. For radionuclides less than MDC, the value representing the highest abundance was selected. Results were not reported as less than MDC (< MDC).
Sample report summaries included unique sample identification, analytical method, radionuclide, result, uncertainty, laboratory data qualifiers, units, and the observed MDC.
In accordance with the LTP, for laboratory analysis, MDCs less than 10% of the OpDCGL were preferable while MDCs up to 50% of the OpDCGL were acceptable. The minimum acceptable MDC for measurements obtained using field instruments was 50 percent of the applicable OpDCGL.
- 5.
SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. Guidance for preparing FSS plans is provided in procedure ZS-LT-300-001-001 Final Status Survey Package Development. The FSS plan uses an integrated sample design that combines scanning surveys and sampling which can be either random or judgmental.
The DQO process determined that Co-60, Ni-63, Sr-90, Cs-134 and Cs-137 would be the ROC in survey unit 10223. Concentrations for Hard-to-Detect (HTD) ROC Ni-63 and Sr-90 are inferred using a surrogate approach. Cs-137 is the principle surrogate radionuclide for Sr-90 and Co-60 is the principle surrogate radionuclide for Ni-63. The mean, maximum and 95% Upper Confidence Level (UCL) of the surrogate ratios for concrete core samples taken in the Auxiliary Building basement were calculated in ZionSolutions TSD 14-019, Radionuclides of Concern for Soil and Basement Fill Model Source Terms (Reference 10) and are presented in Table 7. The maximum ratios will be used in
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the surrogate calculations during FSS unless area specific ratios are determined by continuing characterization.
Table 7 - Surrogate Ratios Ratios Auxiliary Building Mean Max 95% UCL Ni-63/Co-60 44.143 180.450 154.632 Sr-90/Cs-137 0.001 0.002 0.002 For the FSS of survey unit 10223, the surrogate OpDCGLs for Co-60 and Cs-137 were computed based on the maximum ratios from Table 7.
The equation for calculating a surrogate DCGL is as follows:
Equation 1
=
1
1
+
2 2+
3 3+
Where:
DCGLSur
= Surrogate radionuclide DCGL DCGL2,3n = DCGL for radionuclides to be represented by the surrogate Rn
= Ratio of concentration (or nuclide mixture fraction) of radionuclide n to surrogate radionuclide Using the OpDCGLs presented in Table 5 and the maximum ratios from Table 7, the following surrogate calculations were performed:
Equation 2 (137) =
1
1 3.630(137)+
0.002 3.095(90)
= 3.622 /
The surrogate OpDCGL that was used for Cs-137 in this survey unit for direct comparison of sample results to demonstrate compliance is 3.622 pCi/g.
Equation 3 (60) =
1
1 1.091(60)+
180.45 914.458(63)
= 0.898 /
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The surrogate OpDCGL that was used for Co-60 in this survey unit for direct comparison of sample results to demonstrate compliance is 0.898 pCi/g.
The action level for investigation in a Class 3 open land survey unit is 50% of the OpDCGL. The surrogate DCGL for Co-60 while inferring Ni-63 is 0.898 pCi/g, and the surrogate DCGL for Cs-137 while inferring Sr-90 is 3.622 pCi/g. Using the normalized mixture for gamma-emitting ROC from Table 2, the surrogate adjusted gamma DCGL is then calculated as follows:
Equation 4
() =
1
0.012 0.898(60)+ 0.00001 1.733134+
0.988 3.622(137)
= 3.494 /
The surrogate adjusted gamma DCGL equals 3.494 pCi/g. The action levels for survey unit 10223 are based on 50% of the DCGL and are presented in Table 8.
Table 8 - Action Levels for Survey Unit 10223 ROC DCGL (pCi/g)
Co-60 (1) 0.449 Cs-134 (2) 0.867 Cs-137 (3) 1.811 Gross Gamma (4) 1.747 (1)
Based on 50% of surrogate adjusted DCGL of 0.898 pCi/g for Co-60 while inferring Ni-63 (2)
Based on 50% of OpDCGL (3)
Based on 50% of surrogate adjusted DCGL of 3.622 pCi/g for Cs-137 while inferring Sr-90 (4)
Based on 50% of normalized surrogate adjusted DCGLs of 3.494 pCi/g for gamma-emitting ROC The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation. This approach was conservative since it included background Cs-137 as part of the sample set.
The Elevated Measurement Comparison (EMC) did not apply to this survey unit since it is a Class 3 survey unit and discrete, elevated areas of contamination were not expected.
The number of soil samples for FSS was determined in accordance with procedure ZS-LT-300-001-001 Final Status Survey Package Development. The relative shift (/) for the
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survey unit data set is defined as shift (), which is the Upper Bound of the Gray Region (UBGR), or the DCGL (SOF of 1) minus the Lower Bound of the Gray Region (LBGR)
(SOF of 0.5), divided by sigma (), which is the standard deviation of the data set used for survey design. The optimal value for / should range between 1 and 3. The largest value the / can have is 3. If the / exceeds 3, then the value of 3 will be used for /.
The relative shift was calculated using a sigma value of 0.015 for Cs-137 from the characterization (Table 1). The / for survey unit 10223 was calculated as follows:
Equation 5
/
=
0.5/0.015
=
33.33 As the calculated relative shift (33.33) was greater than 3, then a value of 3 was used as the adjusted /. Both the Type I error, or value and the Type II error, or value was set at 0.05. The sample size from Table 5.5 of MARSSIM that equates to the Type I and Type II error of 0.05 for use with the Sign Test is an N value of 14.
A Prospective Power Curve was generated using MARSSIM 2000, a software package developed for implementation of MARSSIM in support of the decommissioning license termination rule (10CFR20, Subpart E). The result of the MARSSIM 2000 computer run showed adequate power for the survey design. The survey design specified fourteen (14) surface soil samples for non-parametric statistical testing.
As the survey unit was classified as Class 3, sample locations were selected at random.
The random locations of the surface soil samples were selected using Visual Sample Plan (VSP), in accordance with ZS-LT-300-001-001. Input parameters included use of Bing or Google Maps aerial photographs and the random sampling tool set with a predetermined number (14) of sample points. These coordinates were integrated with a GPS to locate sample locations in the field. Sample measurement locations for the surface soil samples taken for random design are listed with the GPS coordinates in Table 9.
ZSRP LTP Chapter 5, section 5.1 states that soil samples will be collected during FSS to confirm the HTD to surrogate radionuclide ratios (Table 7). Ten percent (10%) of the FSS samples collected from open land survey units will be analyzed for HTD ROC. Only HTD radionuclides included as ROC (Ni-63 and Sr-90 for soils) will be analyzed in the FSS confirmatory samples. For soil samples with positive results for both a HTD ROC and the corresponding surrogate radionuclide (Cs-137 or Co-60), the HTD surrogate ratio will be derived and compared against the maximum ratio (see Table 7). The maximum ratios (Table 7) will be used unless specific survey information supports the use of a surrogate ratio that is specific to the area. In these cases, the survey unit-specific radiological data and the derived surrogate ratios will be submitted to the NRC for approval. If approved, then the survey unit-specific ratios used and the survey data
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serving as the basis for the surrogate ratios will be documented in the release record for the survey unit.
Table 9 - Random Sample Measurement Locations MEASUREMENT ID NORTHING (meters)
EASTING (meters)
L3-10223A-FRGS-001-SS 641786.437 343826.945 L3-10223A-FRGS-002-SS 641809.6930 343823.8490 L3-10223A-FRGS-003-SS 641816.162 343856.732 L3-10223A-FRGS-004-SS 641781.6639 343817.6321 L3-10223A-FRGS-005-SS 641753.6349 343819.7044 L3-10223A-FRGS-006-SS 641740.8151 343816.1351 L3-10223A-FRGS-007-SS 641725.6058 343813.4875 L3-10223A-FRGS-008-SS 641683.5622 343807.2706 L3-10223A-FRGS-009-SS 641665.6818 343798.8509 L3-10223A-FRGS-010-SS 641652.0295 343790.6922 L3-10223A-FRGS-011-SS 641637.8154 343797.0872 L3-10223A-FRGS-012-SS 641624.0005 343784.4753 L3-10223A-FRGS-013-SS 641609.9859 343772.0415 L3-10223A-FRGS-014-SS 641600.7779 343785.7995 Fourteen (14) surface soil samples were required for the non-parametric statistical test (sample size N = 14).
A map of the surface soil sample locations and the In Situ Object Counting System (ISOCS) measurement location are provided in Figure 4 in Attachment 1.
The selection of one (1) soil sample met the requirement that 10% of the samples collected for the FSS of survey unit 10223 be analyzed for HTD ROC. Sample number L3-10223A-FRGS-004-SS was selected. The selected sample was sent off-site (Eberline Analytical) for analysis of the HTD ROC as specified in LTP Chapter 5, section 5.1.
The implementation of quality control measures as referenced by LTP Chapter 5, section 5.9 and ZionSolutions ZS-LT-01, Quality Assurance Project Plan (for Characterization and FSS) (QAPP) (Reference 11) includes the collection of a soil sample for split sample analysis on 5% of the soil samples taken in a survey unit with the locations
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selected at random. One (1) surface soil sample, L3-10223A-FQGS-014-SS was selected randomly for split sample analysis for the FSS of this survey unit.
LTP Chapter 5, section 5.6.4.4 and Table 5-24 specifies that for Class 3 survey units, judgmental (biased) surface scans will be performed on areas with the greatest potential of contamination. For open land areas, this may include surface drainage areas and collection points. The fraction of scanning coverage required for survey unit 10223 was determined during the DQO process with the total amount and location(s) based on the likelihood of finding elevated activity during FSS. Based on the HSA, the results of the characterization survey, and the operational use of this survey unit, fourteen (14) different scan areas representing 630 m2, or approximately 5% of the survey unit, of surface area was chosen at random. A map of the scan grid locations are provided in Figure 4.
For this Class 3 open land survey unit, the Investigation Levels for area scanning and soil sample measurement results are those levels specified in LTP Chapter 5, Table 5-25 and are reproduced below in Table 10.
Table 10 - Investigation Levels Classification Scan Investigation Levels Direct Investigation Levels Class 3
>Operational DCGL or >MDCscan if MDCscan is greater than Operational DCGL
>0.5 Operational DCGL
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Table 11 provides a synopsis of the survey design for survey unit 10223.
Table 11 - Synopsis of Survey Design FEATURE DESIGN CRITERIA BASIS Survey Unit Land Area 12,371 m2 GPS measurements of area Number of Measurements (N) 14 (random)
- = 0.015
- UBGR = SOF of 1
- LBGR = SOF of 0.5
- Type I error = 0.05
- Type II error = 0.05
- / = 3 (adjusted)
(MARSSIM Table 5.5)
Grid Spacing Random (LTP Chapter 5, section 5.6.4.5.2)
DCGLs
- Co 1.091 pCi/g
- Cs-134 - 1.733 pCi/g
- Cs-137 - 3.630 pCi/g
- Ni 914.458 pCi/g
- Sr 3.095 pCi/g Operational DCGLs for Surface Soils, (LTP Chapter 5, Table 5-7)
HTD ROC Analysis One (1) surface soil samples selected for HTD ROC analysis (LTP Chapter 5, section 5.1)
Soil Investigation Level
>0.5 Operational DCGL (LTP Chapter 5, Table 5-25)
Scan Survey Area Coverage 630 m2 or ~5% areal coverage Judgmental areal coverage, (LTP Chapter 5, Table 5-24)
Scan Investigation Level
>Operational DCGL or >MDCscan if MDCscan is greater than Operational DCGL (LTP Chapter 5, Table 5-25)
QC One (1) surface soil sample selected randomly for split sample analysis (LTP Chapter 5, section 5.9)
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- 6.
SURVEY IMPLEMENTATION For survey unit 10223, compliance with the unrestricted release criteria was demonstrated through a combination of surface scanning with a Ludlum Model 44-10 gamma detector and the sampling of surface soil for isotopic analysis. In accordance with the LTP Chapter 5, section 5.7.1.6.2, no subsurface soil sample(s) will be taken as part of the survey design in Class 3 open land survey units. However, if during the performance of FSS, the analysis of a surface soil sample, or the results of a surface gamma scan indicated the potential presence of residual radioactivity at a concentration of 75% of the subsurface OpDCGL, then a biased subsurface soil sample(s) would have been taken to the appropriate depth within the area of concern as part of the investigation. This threshold was not encountered during the FSS of survey unit 10223. Consequently, no subsurface soil samples were collected during FSS.
In addition, LTP Chapter 5, section 5.1 states that if levels of residual gamma radioactivity in an individual soil sample exceed a SOF of 0.1, then the sample(s) will be analyzed for HTD ROC. This threshold was not encountered during the FSS of survey unit 10223.
FSS field activities were conducted under FSS Sample Plan L3-10223-F. FSS Sample Plan L3-10223-F included DQOs, survey design, detailed FSS instructions, job safety analysis, and related procedures for reference. A Field Log (ZS-LT-300-001-001 4) was used to document field activities and other information pertaining to the performance of the FSS.
FSS field activities were projected to take eight (8) working days to complete. Daily briefings were conducted to discuss the expectations for job performance and to review safety aspects of the job. The survey required field activities were performed during normal working hours starting on and concluding on April 25, 2016.
The fourteen (14) random surface soil sample locations were marked with flags based on GPS coordinates provided by VSP. Around each surface soil sample location, a 44 m2 scan area was marked out. A total of fourteen (14) different scan areas were established, constituting an areal scan coverage of 630 m2, or approximately 5% of the surface area in survey unit 10223. Background was assessed in the survey unit and it was determined that, using an Ludlum 2350-1 paired with a Model 44-10 (2 x 2) NaI detector, background ranged from 2,459 cpm up to 3,115 cpm.
All designated scan areas as denoted on Figure 4 in Attachment 1 were scanned using a Ludlum 2350-1 paired with a Model 44-10 (2 x 2) NaI detector operated in the rate-meter mode and using audio response. The probe was positioned as close to the ground as possible and was moved at a scan speed of approximately 0.25 meters per second. In accordance with ZionSolutions TSD 11-004, Ludlum Model 44-10 Detector Sensitivity
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(Reference 12), scan MDC was sufficient to detect residual radioactivity at the action level (adjusted gross gamma DCGL of 1.747 pCi/g, which was based on 50% of the normalized surrogate adjusted OpDCGLs for gamma emitting ROC). Complete scan results are provided in Attachment 2.
In accordance with FSS design, fourteen (14) surface soil samples were collected at random locations. Each surface soil sample consisted of 1 liter of soil. The sample media was sifted to remove stones and other media larger than 1 centimeter in diameter. All collected soil samples were controlled, transported, stored, and transferred to the on-site laboratory using Chain-of-Custody (CoC) process from ZionSolutions procedure ZS-LT-100-001-004, Sample Media Preparation (Reference 13).
One (1) sample (L3-10223A-FRGS-004-SS) was selected for HTD radionuclide analysis.
The implementation of survey specific QC measures included the collection of one (1) sample (L3-10223A-FQGS-014-SS) for split sample analysis.
- 7.
SURVEY RESULTS The scan areas identified in the FSS plan were scanned for elevated radiation levels. No elevated measurement locations were identified by surface scan. Table 12 provides an overview of the scan results. Complete scan results are provided in Attachment 2.
Table 12 - Synopsis of Scan Results Scan Area Highest Logged Reading Action Level(1) # of Scan Alarms Investigation Samples (cpm)
(cpm)
GS001 2460 3412 None None GS002 2910 3412 None None GS003 3320 3412 None None GS004 2990 3412 None None GS005 3000 3412 None None GS006 2940 3412 None None GS007 2960 3412 None None
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Table 12 (continued) - Synopsis of Scan Results Scan Area Highest Logged Reading Action Level(1) # of Scan Alarms Investigation Samples (cpm)
(cpm)
GS008 2740 3917 None None GS009 2790 3917 None None GS010 3350 3917 None None GS011 3830 3917 None None GS012 3870 3917 None None GS013 3380 3917 None None GS014 3710 3917 None None
- 1) The action level is based on the measurement Minimum Detectable Count Rate (MDCR) plus background in accordance with the FSS plan The on-site laboratory analyzed the fourteen (14) soil samples taken for non-parametric statistical testing using the on-site gamma spectroscopy system. A summary of the fourteen (14) samples collected for non-parametric statistical testing results is provided in Table 13. The results for the gamma emitting ROC (Co-60, Cs-134 and Cs-137) presented in Table 13 are the measured values from gamma spectroscopy analysis. The results for HTD ROC were inferred using the ratios presented in Table 7. Gamma spectroscopy results (summarized in Table 14) revealed no samples above MDC for Cs-137, Co-60 or Cs-134. The mean of the gamma spectroscopic analysis results for the sample population indicated that Cs-137 was present at levels lower than the concentrations of Cs-137 expected to be found in off-site soil at within the vicinity of the ZNPS as presented in ZionSolutions TSD 13-004, Examination of Cs-137 Global Fallout in Soils at Zion Station (Reference 14). The complete gamma spectroscopy reports are presented in Attachment 6. The basic statistics for the random sample population are summarized in Table 14.
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Table 13 - Summary of Gamma Spectroscopy Results for Surface Soil Samples Comprising the Statistical Sample Population MEASUREMENT ID Co-60(1)
Cs-134(1)
Cs-137(1)
Ni-63(2)
Sr-90(2)
(pCi/g)
(pCi/g)
(pCi/g)
(pCi/g)
(pCi/g)
L3-10223A-FRGS-001-SS 1.03E-02 7.10E-03 0.00E+00 1.86E+00 0.00E+00 L3-10223A-FRGS-002-SS 1.28E-02 1.04E-02 0.00E+00 2.31E+00 0.00E+00 L3-10223A-FRGS-003-SS 2.65E-03 3.57E-03 5.54E-04 4.78E-01 1.11E-06 L3-10223A-FRGS-004-SS 0.00E+00 6.93E-03 1.77E-02 0.00E+00 3.54E-05 L3-10223A-FRGS-005-SS 4.25E-03 9.23E-03 3.02E-03 7.67E-01 6.04E-06 L3-10223A-FRGS-006-SS 1.59E-03 1.21E-02 1.09E-02 2.87E-01 2.18E-05 L3-10223A-FRGS-007-SS 3.56E-03 5.20E-04 6.16E-03 6.42E-01 1.23E-05 L3-10223A-FRGS-008-SS 0.00E+00 2.70E-03 1.02E-02 0.00E+00 2.04E-05 L3-10223A-FRGS-009-SS 7.59E-03 4.86E-03 3.75E-03 1.37E+00 7.50E-06 L3-10223A-FRGS-010-SS 1.54E-02 2.09E-02 1.38E-02 2.78E+00 2.76E-05 L3-10223A-FRGS-011-SS 3.61E-03 8.53E-03 1.00E-02 6.51E-01 2.00E-05 L3-10223A-FRGS-012-SS 1.58E-03 2.67E-03 3.56E-03 2.85E-01 7.12E-06 L3-10223A-FRGS-013-SS 0.00E+00 2.79E-03 3.70E-03 0.00E+00 7.40E-06 L3-10223A-FRGS-014-SS 9.41E-03 9.32E-03 6.88E-03 1.70E+00 1.38E-05 Note:
Table 14 - Basic Statistical Properties of Random Sample Population ROC Mean Median Max Min Std. Dev.
BcDCGL Avg. SOF Avg. Dose (pCi/g)
(pCi/g)
(pCi/g)
(pCi/g)
(pCi/g) per ROC Per ROC Co-60 5.20E-03 3.59E-03 1.54E-02 0.00E+00 5.05E-03 4.26 1.22E-03 3.05E-02 Cs-134 7.26E-03 7.02E-03 2.09E-02 5.20E-04 5.23E-03 6.77 1.07E-03 2.68E-02 Cs-137 6.44E-03 4.96E-03 1.77E-02 0.00E+00 5.41E-03 14.18 4.54E-04 1.14E-02 Ni-63 9.37E-01 6.47E-01 2.78E+00 0.00E+00 9.11E-01 3572.1 2.62E-04 6.56E-03 Sr-90 1.29E-05 9.91E-06 3.54E-05 0.00E+00 1.08E-05 12.09 1.07E-06 2.67E-05 The off-site laboratory, Eberline Analytical, originally processed one (1) sample selected for HTD ROC analysis as specified in the survey design. Sample number L3-10223A-FRGS-004-SS was selected. Only HTD radionuclides included as ROC (Ni-63 and Sr-90 for soils) were included in the analysis. The result of the analysis indicated positive Sr-90 at a concentration greater than the MDC but within the range of uncertainty for the analysis. No other ROC were positively identified by the sample analysis. The
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assessment of the analytical results postulated the possibility that the result for Sr-90 was due to a false positive. As an investigation to the anomalous Sr-90 identification, another aliquot (L3-10223A-FRGS-004-SS) of the same sample was analyzed by Eberline, which revealed no ROC greater than MDC.
As a further investigation, a sample from an adjacent location in the survey unit, sample number L3-10223A-FRGS-003-SS, was also sent off-site for HTD analysis. The results of the analysis for L3-10223A-FRGS-003-SS revealed positive Cs-137 and Sr-90 at concentrations greater than MDC. While the Cs-137 result appeared to be legitimate as the observed concentration was significantly greater than MDC and within the expected range for the ROC as presented in ZionSolutions TSD 13-004, the result for Sr-90 was again, positively detected at a concentration greater than the MDC but within the range of uncertainty for the analysis. An additional sample, L3-10223A-FRGS-005-SS was submitted to Eberline for HTD analysis. The results again indicated positive Sr-90 at concentrations above the MDC but within the range of uncertainty. The C/LT group had discussions with the laboratory about these results. The laboratory also believed that the reported results for Sr-90 were possibly false positives. As confirmation, the sample aliquot for sample number L3-10223A-FRGS-003-SS was reanalyzed. The reanalysis results did not indicate concentrations of any ROC greater than MDC. As it was determined by the reanalysis that Sr-90 was not present in the samples at concentrations greater than MDC, no reassessment of the HTD ratio was required and the maximum ratios from Table 7 were used to infer the concentrations of Ni-63 and Sr-90. The results of the HTD analysis and re-analysis are provided in Table 15.
Table 15 - Off-Site Analysis Results (Eberline Analytical) for Sample ID #s L3-10223A-FRGS-003-SS, L3-10223A-FRGS-004-SS and L3-10223A-FRGS-005-SS Sample # L3-10223A-FRGS-004-SS (initial analysis)
>MDC (pCi/g)
(pCi/g)
(pCi/g)
Co-60 1.29E-02 1.47E-02 1.62E-02 No Cs-134 1.85E-03 5.88E-03 2.29E-02 No Cs-137 5.77E-03 1.18E-02 1.84E-02 No Ni-63 8.22E-01 1.30E+00 2.20E+00 No Sr-90 9.84E-01 3.37E-01 6.09E-01 Yes
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Table 15 (continued) - Off-Site Analysis Results (Eberline Analytical) for Sample ID #s L3-10223A-FRGS-003-SS, L3-10223A-FRGS-004-SS and L3-10223A-FRGS-005-SS Sample # L3-10223A-FRGS-004-SS (reanalysis)
>MDC (pCi/g)
(pCi/g)
(pCi/g)
Co-60 2.37E-02 4.44E-02 5.95E-02 No Cs-134 1.77E-02 1.71E-02 7.22E-02 No Cs-137 2.07E-02 3.81E-02 5.62E-02 No Ni-63
-4.17E-01 6.58E-01 1.14E+00 No Sr-90 2.44E-01 2.14E-01 4.32E-01 No Sample # L3-10223A-FRGS-005-SS ROC Result (pCi/g)
Uncertainty (pCi/g)
MDC (pCi/g)
>MDC Co-60 9.45E-03 2.47E-02 3.15E-02 No Cs-134
-5.75E-03 1.89E-02 4.35E-02 No Cs-137 1.83E-02 2.26E-02 3.79E-02 No Ni-63
-1.42E-01 6.79E-01 1.17E+00 No Sr-90 5.66E-01 2.11E-01 3.89E-01 Yes Sample # L3-10223A-FRGS-003-SS (initial analysis)
ROC Result (pCi/g)
Uncertainty (pCi/g)
MDC (pCi/g)
>MDC Co-60 2.96E-02 4.43E-02 6.13E-02 No Cs-134
-6.71E-03 3.68E-02 8.99E-02 No Cs-137 3.67E-01 7.80E-02 9.46E-02 Yes Ni-63 4.49E-02 6.47E-01 1.11E+00 No Sr-90 5.26E-01 2.47E-01 4.76E-01 Yes
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Table 15 (continued) - Off-Site Analysis Results (Eberline Analytical) for Sample ID #s L3-10223A-FRGS-003-SS, L3-10223A-FRGS-004-SS and L3-10223A-FRGS-005-SS Sample # L3-10223A-FRGS-003-SS (reanalysis)
ROC Result (pCi/g)
Uncertainty (pCi/g)
MDC (pCi/g)
>MDC Co-60
-6.17E-02 8.84E-02 1.08E-01 No Cs-134
-3.18E-02 7.84E-02 1.88E-01 No Cs-137
-2.49E-02 5.61E-02 7.85E-02 No Ni-63 7.41E-01 1.76E+00 2.99E+00 No Sr-90 4.88E-01 2.47E-01 5.72E-01 No The implementation of survey specific QC measures included the collection of one (1) sample (L3-10223A-FQGS-014-SS) for split sample analysis. The on-site laboratory analyzed the designated QC sample using the on-site gamma spectroscopy system. A summary of the analytical results for the QC sample is provided in Table 16. Gamma spectroscopy results (summarized in Table 16) revealed no concentration of ROC above MDC. The concentrations for Ni-63 and Sr-90 were inferred based on the maximum ratio as specified in Table 7.
Table 16 - Summary of Gamma Spectroscopy Results for QC Surface Soil Sample MEASUREMENT ID Co-60(1)
Cs-134(1)
Cs-137(1)
Ni-63(2)
Sr-90(2)
(pCi/g)
(pCi/g)
(pCi/g)
(pCi/g)
(pCi/g)
L3-10223A-FQGS-014-SS 7.34E-03 1.86E-02 1.63E-02 1.32E+00 3.26E-05 Note:
The SOF or unity rule is the mathematical test used to evaluate compliance with radiological criteria for license termination when more than one radionuclide has been determined to be potentially present. The equation for the unity rule is:
Equation 5 1
2 2
1 1
+
+
DCGL C
DCGL C
DCGL C
n n
Where:
Cn
= concentration of radionuclide n DCGLn
= DCGL of radionuclide n.
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The results of the unity rule calculation for the ROC in the random sample population for survey unit 10223 are provided in Table 17.
Table 17 -
Sum-of-Fractions for Individual Surface Soil Samples (Random)
MEASUREMENT ID FRACTION OF OpDCGL OpSOF Co-60 Cs-134 Cs-137 Ni-63 Sr-90 L3-10223A-FRGS-001-SS 0.0094 0.0041 0.0000 0.0020 0.0000 0.0156 L3-10223A-FRGS-002-SS 0.0117 0.0060 0.0000 0.0025 0.0000 0.0203 L3-10223A-FRGS-003-SS 0.0024 0.0021 0.0002 0.0005 0.0000 0.0052 L3-10223A-FRGS-004-SS 0.0000 0.0040 0.0049 0.0000 0.0000 0.0089 L3-10223A-FRGS-005-SS 0.0039 0.0053 0.0008 0.0008 0.0000 0.0109 L3-10223A-FRGS-006-SS 0.0015 0.0070 0.0030 0.0003 0.0000 0.0118 L3-10223A-FRGS-007-SS 0.0033 0.0003 0.0017 0.0007 0.0000 0.0060 L3-10223A-FRGS-008-SS 0.0000 0.0016 0.0028 0.0000 0.0000 0.0044 L3-10223A-FRGS-009-SS 0.0070 0.0028 0.0010 0.0015 0.0000 0.0123 L3-10223A-FRGS-010-SS 0.0141 0.0121 0.0038 0.0030 0.0000 0.0330 L3-10223A-FRGS-011-SS 0.0033 0.0049 0.0028 0.0007 0.0000 0.0117 L3-10223A-FRGS-012-SS 0.0014 0.0015 0.0010 0.0003 0.0000 0.0043 L3-10223A-FRGS-013-SS 0.0000 0.0016 0.0010 0.0000 0.0000 0.0026 L3-10223A-FRGS-014-SS 0.0086 0.0054 0.0019 0.0019 0.0000 0.0178 Random Measurements Number of Random Measurements =
14
- of Random Measurements with OpSOF > 1 =
0
- of Random Measurements with OpSOF > 0.1 (HTD Assessment) =
0 Max Individual Random Measurement OpSOF =
0.0330 Mean Random Measurement OpSOF =
0.0118 Table 18 - Sum-of-Fractions for QC Surface Soil Samples MEASUREMENT ID FRACTION OF OpDCGL OpSOF Co-60 Cs-134 Cs-137 Ni-63 Sr-90 L3-10223A-FQGS-014-SS 0.0067 0.0107 0.0045 0.0014 0.0000 0.0234 The mean BcSOF for survey unit 10223 is 0.0030 which equates to a dose of 0.0752 mrem/yr TEDE.
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The mean of all identified isotopes are less than the Consultation Triggers for Residential and Commercial/Industrial Soil Contamination depicted in Table H.1 of NUREG 1757, Vol.1, Rev. 2 (MOU Table 1). The full table is included in Attachment 3 of this Release Record.
- 8.
QUALITY CONTROL The on-site laboratory processed one (1) split sample, L3-10223A-FQGS-014-SS, using gamma spectroscopy analysis. The data was evaluated using USNRC acceptance criteria specified in Inspection Procedure No. 84750, Radioactive Waste Treatment, and Effluent and Environmental Monitoring (Reference 15). There was acceptable agreement between field split results. Refer to Attachment 4 for data and quality control analysis results.
- 9.
INVESTIGATIONS AND RESULTS No investigations were performed during the performance or analyses of the survey.
- 10.
REMEDIATION AND RESULTS Historically, no radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit prior to or as a result of the FSS. Chapter 4 of the ZSRP LTP determined that remediation beyond that required to meet the release criteria is unnecessary and that the remaining residual radioactivity in soil was ALARA.
- 11.
CHANGES FROM THE FINAL STATUS SURVEY PLAN Procedure ZS-LT-300-001-001, Final Status Survey Package Development states, If a selected location is found to be either inaccessible or unsuitable, then the location will be adjusted to the closest adjacent suitable location. In these cases, a notation will be made in Attachment 14, FSS Field Log, and the coordinates of the new location documented.
Six (6) sample locations (#s 1, 3, 6, 9, 11 and 14) were relocated due to the elevated lake level. Approximately half of the survey unit was covered in water during FSS. Details of the surface soil sample locations and the water level is provided in Figure 4 on.
- 12.
DATA QUALITY ASSESSMENT (DQA)
The DQO sample design and data were reviewed in accordance with ZionSolutions procedure ZS-LT-300-001-004, Final Status Survey Data Assessment (Reference 16) for completeness and consistency. Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that
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the survey unit was properly designated as Class 3. The sampling design had adequate power as indicated by the Retrospective Power Curve.
The analytical results of all samples were less than a SOF of one. Additionally, the maximum activity for each ROC did not exceed 10% of their respective OpDCGL for surface soils. Although MARSSIM states that the Sign Test need not be performed in the instance that no measurements surpass the DCGL, the test was conducted to demonstrate coherence to the statistical principles of the DQO process. The Sign Test was performed on the data and compared to the original assumptions of the DQOs. The evaluation of the Sign Test results clearly demonstrates that the survey unit passes the unrestricted release criteria, thus, the null hypothesis is rejected.
The preliminary data review consisted of calculating basic statistical quantities (e.g.,
mean, median, standard deviation). All data was considered valid including negative values, zeros, values reported below the MDC, and values with uncertainties greater than two standard deviations. The mean and median values for each ROC were well below the respective OpDCGLs. Also, the retrospective power curve shows that a sufficient number of samples were collected to achieve the desired power. Therefore, the survey unit meets the unrestricted release criteria with adequate power as required by the DQOs.
The data for Co-60 and Cs-137 is represented graphically through a frequency plot and a quantile plot. All graphical representations are provided in Attachment 5.
- 13.
ANOMALIES No anomalies were observed during the performance or analyses of the survey.
- 14.
CONCLUSION Survey unit 10223 has met the DQOs of the FSS plan. The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved. The EMC for soils was not applicable and remediation was not required.
All identified ROC were used for statistical testing to determine the adequacy of the survey unit for FSS. Evaluation of the data shows that none of the ROC concentration values exceeds the OpDCGL or any investigational levels; therefore, in accordance with the LTP Section 5.10, the survey unit meets the release criteria.
The sample data passed the Sign Test. The null hypothesis was rejected. The Retrospective Power Curve showed that adequate power was achieved. The survey unit is properly classified as Class 3.
The mean SOF, when the analytical results were compared to the Base Case DCGLs, was
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0.0030, which results in a dose contribution from soil in survey unit 10223 of 0.0752 mrem/yr TEDE, based on the average concentration of the ROC in samples used for non-parametric statistical sampling.
Survey unit 10223 is acceptable for unrestricted release.
- 15.
REFERENCES
- 1. ZionSolutions procedure ZS-LT-300-001-005, Final Status Survey Data Reporting
- 2. Zion Station Restoration Project License Termination Plan
- 3. ZionSolutions procedure ZS-LT-300-001-001, Final Status Survey Package Development
- 4. NUREG-1575, Revision 1, Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM)
- 5. ZionSolutions procedure ZS-LT-300-001-002, Survey Unit Classification
- 6. Historical Site Assessment (HSA)
- 7. ZionSolutions TSD 11-001, Potential Radionuclides of Concern during the Decommissioning of Zion Station
- 8. ZionSolutions TSD 14-011, Soil Area Factors
- 9. ZionSolutions TSD 17-004, Operational Derived Concentration Guideline Levels for Final Status Survey
- 10. ZionSolutions TSD 14-019, Radionuclides of Concern for Soil and Basement Fill Model Source Terms
- 11. ZionSolutions ZS-LT-01, Quality Assurance Project Plan (for Characterization and FSS) (QAPP)
- 12. ZionSolutions TSD 11-004, Ludlum Model 44-10 Detector Sensitivity
- 13. ZionSolutions procedure ZS-LT-100-001-004, Sample Media Preparation
- 14. ZionSolutions TSD 13-004, Examination of Cs-137 Global Fallout in Soils at Zion Station
- 15. U.S. NRC Inspection Procedure No. 84750, Radioactive Waste Treatment, and Effluent and Environmental Monitoring
- 16. ZionSolutions procedure ZS-LT-300-001-004, Final Status Survey Data Assessment
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- 16.
ATTACHMENTS - Figures and Maps - Scan Data - Consultation Triggers For Residential And Commercial/
Industrial Soil Contamination - QC Sample Assessment - Graphical Presentations - Sample Analytical Reports - Eberline Analytical Reports
[33]
ATTACHMENT 1 FIGURES AND MAPS
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Figure 1 Survey Unit 10223 Boundary
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Figure 2 Survey Unit 10223 Characterization Survey Scan Areas
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Figure 3 Survey Unit 10223 Characterization Survey Sample Locations
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Figure 4 Survey Unit 10223 Final Status Survey
[38]
ATTACHMENT 2 SCAN DATA
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Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR316938 293136 10223 GS014 4/25/2016 10:19 3710 2885 3917 No 44-10 PR316938 293136 10223 GS014 4/25/2016 10:20 3530 2885 3917 No 44-10 PR316938 293136 10223 GS014 4/25/2016 10:20 3510 2885 3917 No 44-10 PR316938 293136 10223 GS014 4/25/2016 10:20 3530 2885 3917 No 44-10 PR316938 293136 10223 GS014 4/25/2016 10:21 3390 2885 3917 No 44-10 PR316938 293136 10223 GS013 4/25/2016 10:26 3370 2885 3917 No 44-10 PR316938 293136 10223 GS013 4/25/2016 10:26 3060 2885 3917 No 44-10 PR316938 293136 10223 GS013 4/25/2016 10:27 3310 2885 3917 No 44-10 PR316938 293136 10223 GS013 4/25/2016 10:27 3200 2885 3917 No 44-10 PR316938 293136 10223 GS013 4/25/2016 10:27 3380 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:29 3870 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:30 3120 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:30 3410 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:30 3000 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:30 3300 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:31 3190 2885 3917 No 44-10 PR316938 293136 10223 GS012 4/25/2016 10:32 3060 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:24 2910 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:27 2930 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:27 2580 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:27 3680 2885 3917 No
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[40]
Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR316938 293136 10223 GS011 4/25/2016 12:28 2600 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:28 3830 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:28 3060 2885 3917 No 44-10 PR316938 293136 10223 GS011 4/25/2016 12:29 3030 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:53 3350 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:53 3150 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:53 2930 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:54 2430 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:54 3010 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:57 3060 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:58 2980 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:58 3160 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:58 2720 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:58 2910 2885 3917 No 44-10 PR316938 293136 10223 GS010 4/25/2016 12:59 2800 2885 3917 No 44-10 PR316938 293136 10223 GS009 4/25/2016 13:00 2790 2885 3917 No 44-10 PR316938 293136 10223 GS009 4/25/2016 13:00 2430 2885 3917 No 44-10 PR316938 293136 10223 GS009 4/25/2016 13:01 2730 2885 3917 No 44-10 PR316938 293136 10223 GS009 4/25/2016 13:02 2650 2885 3917 No 44-10 PR316938 293136 10223 GS009 4/25/2016 13:02 2380 2885 3917 No 44-10 PR316938 293136 10223 GS009 4/25/2016 13:03 2490 2885 3917 No
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[41]
Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR316938 293136 10223 GS009 4/25/2016 13:03 2340 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:05 2740 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:05 2410 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:05 2260 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:06 2580 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:06 2290 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:06 2200 2885 3917 No 44-10 PR316938 293136 10223 GS008 4/25/2016 13:07 2450 2885 3917 No 44-10 PR308037 266657 10223 GS007 4/25/2016 9:56 2330 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 9:56 2620 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 9:57 2590 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 9:58 2390 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 9:58 2480 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 9:59 2550 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 10:00 2350 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 10:00 2960 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 10:00 2710 2459 3412 No 44-10 PR308037 266657 10223 GS007 4/25/2016 10:01 2290 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:05 2120 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:06 2270 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:06 2100 2459 3412 No
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[42]
Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR308037 266657 10223 GS006 4/25/2016 10:07 2450 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:08 2670 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:08 2540 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:09 2490 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:10 2600 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:10 2940 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:11 2820 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:11 2710 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:12 2680 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:12 2840 2459 3412 No 44-10 PR308037 266657 10223 GS006 4/25/2016 10:12 2840 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:14 2950 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:14 3000 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:15 2740 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:16 2630 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:17 2310 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:18 2790 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:18 2540 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:20 2330 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:20 2170 2459 3412 No 44-10 PR308037 266657 10223 GS005 4/25/2016 10:21 2160 2459 3412 No
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[43]
Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR308037 266657 10223 GS004 4/25/2016 10:24 2280 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:25 2210 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:25 2990 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:26 2690 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:27 2110 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:28 2090 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:29 2250 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:29 1970 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:30 1880 2459 3412 No 44-10 PR308037 266657 10223 GS004 4/25/2016 10:31 1990 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:30 2840 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:31 2900 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:32 2710 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:33 2640 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:34 2910 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:35 2380 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:35 2660 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:36 3320 2459 3412 No 44-10 PR308037 266657 10223 GS003 4/25/2016 12:36 2920 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:38 2820 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:39 2780 2459 3412 No
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[44]
Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR308037 266657 10223 GS002 4/25/2016 12:39 2730 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:40 2590 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:40 2910 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:41 2710 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:42 2790 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:42 2370 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:43 2290 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:44 2350 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:44 2280 2459 3412 No 44-10 PR308037 266657 10223 GS002 4/25/2016 12:44 2410 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:48 2460 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:49 2180 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:50 2220 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:50 2100 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:51 2140 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:51 2120 2459 3412 No 44-10 PR308037 266657 10223 GS001 4/25/2016 12:52 1890 2459 3412 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:27 3490 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:28 3580 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:28 3250 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:29 3560 3115 4187 No
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[45]
Detector Type Detector ID M2350-1 ID Survey Unit Location Date/Time Scan Logged Result Avg
Background
Action Level Scan Alarms (cpm)
(cpm)
(cpm) 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:30 3350 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:31 3250 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:31 3410 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:32 2950 3115 4187 No 44-10 PR308037 266657 10223 QGS014 4/25/2016 13:32 3040 3115 4187 No
[46]
ATTACHMENT 3 CONSULTATION TRIGGERS FOR RESIDENTIAL AND COMMERCIAL/INDUSTRIAL SOIL CONTAMINATION
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[47]
[48]
ATTACHMENT 4 QC SAMPLE ASSESSMENT
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[49]
Duplicate Sample Assessment Survey Unit #
10223 Survey Unit Name Power Block Beach Area Sample Plan #
L3-10223F Sample
Description:
Comparison of split samples collected from surface soil samples from location
- 14 and analyzed using gamma spectroscopy by on-site HpGe System. The standard samples were L3-10223A-FRGS-014-SS and comparison sample L3-10223A-FQGS-014-SS.
STANDARD COMPARISON ROC Activity Value Standard Error Resolution Agreement Range Activity Value Standard Error Compariso n Ratio Acceptable (Y/N)
K-40 4.24E+00 8.73E-01 4.86 0.5-2.0 4.84E+00 9.37E-01 0.88 Y
Comments/Corrective Actions: There was acceptable agreement. No further action is necessary.
Table is provided to show acceptance criteria used to assess split samples.
Performed By:
Date:
06/20/2019 Reviewed by:
Date:
06/20/2019 RF Yetter III J. Graham
[50]
ATTACHMENT 5 GRAPHICAL PRESENTATIONS
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[51]
Quantile Plot for Co-60 Survey Unit: 10223 Survey Unit Name: Open Land - Power Block Beach Area Mean:
5.01E-03 pCi/g
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[52]
Quantile Plot for Cs-137 Survey Unit: 10223 Survey Unit Name: Open Land - Power Block Beach Area Mean:
6.44E-03 pCi/g
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[53]
Histogram for Co-60 Survey Unit: 10223 Survey Unit Name:
Open Land - Power Block Beach Area Mean:
5.01E-03 pCi/g Median:
3.59E-03 pCi/g ST DEV: 0.00519718 Skew: 0.80481718 Upper Value Observation Frequency Observation 2.57E-03 6
43%
5.13E-03 3
21%
7.70E-03 1
7%
1.03E-02 2
14%
1.28E-02 1
7%
1.54E-02 1
7%
TOTAL 14
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[54]
Histogram for Cs-137 Survey Unit: 10223 Survey Unit Name:
Open Land - Power Block Beach Area Mean:
6.44E-03 pCi/g Median:
4.96E-03 pCi/g ST DEV: 0.00540839 Skew: 0.66152695 Upper Value Observation Frequency Observation 2.95E-03 3
21%
5.90E-03 4
29%
8.85E-03 2
14%
1.18E-02 3
21%
1.48E-02 1
7%
1.77E-02 1
7%
TOTAL 14
FSS RELEASE RECORD POWER BLOCK BEACH AREA SURVEY UNIT 10223, Revision 1
[55]
Retrospective Power Curve for Survey Unit 10223
[56]
ATTACHMENT 6 SAMPLE ANALYTICAL REPORTS
[57]
4/27/2016 8:46:48AM Analysis f"<eport for 27-Apr-16-10002 L310223AFRGS001SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10002
- L310223AFRGS001SS (DRIED)
- 1 L 130G Soil Sample
- 1. 787E+03 grams
- Default
- 4/25/2016 1:30;00PM
- 4/27/2016 8:36:07AM
- 130G 1 L Sand Sample
- JWelch
- P40818B
- 130G Sand
- 600.0 seconds
- 601.1 seconds
- 0.18 %
- 2.80
- 120- 8192
- 120- 8192
- 1.000FWHM
_ 1/27/2016
- 1/5/2015
, 14743 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 8:46:17AM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Pagel of8
[58]
1/27/2016 8:46:48AM Analysis Report for 27-Apr-16-10002 M
m M
m L310223AFRGS001SS (DRIED}
Peak
~n.arn11 RO!
-**-*::1, No.
(keV) start 1
77.13 305 -
2 186.00 741 -
3 238.58 949 -
4 241.87 949 -
5 295.11 1174 -
6 299.97 1174 -
7 338.14 1347 -
8 351. 77 1402 -
9 582.91 2324 -
10 609.20 2430 -
11 911.18 3635 -
12 968. 82 3867 -
13 1460.90 5833 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 316 751 974 974 1205 1205 1359 1414 2340 2445 3652 3882 5853 Peak Net Peak Net Area Centroid Area Uncertainty 309.59 6.78E+Ol 35.42 744.65 2.60E+Ol 26.79 954.82 2.71E+02 34.57 967.96 4.80E+Ol 17.39 1180.78
- 1. OOE+02 21.35 1200.21 1.99E+Ol 12.95 1352.78 5.82E+Ol 25.06 1407.28 l.41E+02 27.51 2331.42
- 1. 02E+02 23.61 2436.56 1.12E+02 24.33 3644.44 6.55E+Ol 17.53 3875.05 4.53E+Ol
- 16. 76 5844.57 1.09E+02 21.99 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity P11ge 2 of8 Continuum Tentative Counts Nuclide 1.62E+02 Pb214-XR Pb212-XR 1.26E+02 Ra-226 U-235 1.05E+02 Pb-212 1.01E+02 Pb-214 6.06E+Ol Pb-214 Eu-152 7.29E+Ol Th-227 Pa-231 Pb-212 8.55E+Ol Ac-228 4.22E+Ol Pb-214 Bi-211 2.72E+Ol Tl-.'.2 08 2.67E+Ol Bi-2 14 9.03E+OO Ac-228 2.13E+Ol A.c-228 9.08E+OO K-40 Activity Caine Name Confidence
{keV)
(pCilgrams)
Uncertainty Corr K-40
- 1. 00 1 460.82 10.66 3.79E+OO 8.30E-01 miss Tl-208
- 0. 99 583.19
- 't
- 85. 00 2.39E-01 6.22E-02 miss Pb-:12
- 1. 00 115.18 0.60 238.63 43.60 6.78E-01
- 1. 40E-01 miss 300.09 3.30 7.62E-01 5.11E-01 miss Pb212-XR
- 1. 00 74.82 10.28 77.11 17. 10
- 1. 20E+OO
- 6. 72E-01 miss 87.35 3.97 89.78
- 1. 46
[59]
4/27/2016 8:46:48AM Page 3 of8 Analysis Report for 27-Apr-16-10002 L310223AFRGS001 SS (DRIED)
Nuclide Id Energy Yield{°/o)
Activity Activity Caine Name Confidence
{keV)
(pCilgrams)
Uncertainty Corr Bi-214
- 1. 00 609.32 45.49 5.02E-Ol 1.25E-01
!Iliss 768.36 4.89 806.18
- 1. 26 934.06 3.11 1120.29 14.92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377.67 3.99 1385.31 0.79 1401.52
- 1. 33 1407.99 2.39 1509.21 2.13 1 661. 27
- 1. 05 1729.59 2.88 1764.49 15.30 1847.43 2.03 2118.51
- 1. 16 Pb-214 0, 99 241.99 7.25 7.29E-0 1 2. 89E-01 miss 295.22 18.42 6.BOE-0 1 1.81E-01 miss 351.93 35.60 5.53E-0 1
- 1. 40E-01 miss 785. 96
- 1. 06 Pb214-XR
- 1. 00 74.82 5.80 77.11
- 9. 70
- 2. llE+OO 1.20E+OO miss 87.35 2.24 89.78 0.82 Ra-226 0.99 186.21 3.64 6.94E-0 1 7.25E-01 miss Ac-228 0.99 129.07 2.42 209.25 3.89 270.24 3.46 328.00 2.95 338.32
- 11. 27
- 7. 04E-01 3.24E-01 miss 409.46
- 1. 92 463.00 4.40 794.95 4.25 911. 20 25.80 6.BlE-01 1.91E-01 miss 964.77 4.99 968. 97 15.80 8.02E-01 3.05E-01 miss 1588.20 3.22 U-235 0.99 143.76 10. 96 163.33 5.08 185.71 57.20 4.42E-02 4.61E-02 miss 202.11
- 1. 08 205.31 5.01
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma
[60]
Analysis Report for 27-Apr-16-10002 L310223AFRGS001SS (DRIED)
Coincidence correction performed.
free ;;; No coincidence correction required.
miss ;;; Nuclide energy was not found in the coincidence library.
4/27/2016 8:4S:48AM INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Name Id Activity Activity Confidence (pCilgrams)
Uncertainty K-40 1.000 3.79E+OO 8.30E-01 Tl-208 0.995 2.39E-01 6.22E-02 X
Bi-211 0.970 Pb-212
- 1. 000 6.84E-01 1.35E-01
?
Pb212-XR
- 1. 000 1.20E+OO
- 6. 72E-01 Bi-214
- 1. 000 5.02E-01 1.25E-01 Pb-214 0.999 6.17E-01 1.03E-01
?
Pb214-XR
- 1. 000
- 2. llE+OO 1.20E+OO
?
Ra-226 0.997 6.94E-01 7.25E-01 Ac-228 0.999 7.13E-01
- 1. 45E-01 X
Pa-231
- 1. 000
?
U-235 0. 996 4.42E-02 4.61E-02
?
nuclide is part of an undetermined solution X
nuclide rejected by the interference analysis nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Page 4 of8 Comments
[61]
4/27/2016 8:46:48AM Analysis Report for 27-Apr-16-1 0002 L310223AFRGS001SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (ke V)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 8:46:17AM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield{%)
Activity NuclideMDA LineMDA Name (keV)
(pCilgrams)
(pCi/grams)
(pCi/grams)
+
K-40 1460.82 10.66 3.79E+OO 4.79E-01 4.79E-01
+
Cr-51 320.08 9.91 l.74E-02 3.80E-01 3.80E-Ol
+
Mn-54 834.85 99.98 2.07E-03 4.22E-02 4.22E-02
+
Co-58 810.76 99.45 3.54E-03 4.02E-02 4.02E-D2 1674.73
- 0. 52
- 1. 58E+D0 8.68E+OO
+
Co-60 1173.23 99.85
-1.15E-02 3.42E-02 3.42E-02 1332.49 99.98 1.03E-02 4.52E-02
+
Nb-94 702.65 99.81
-3.76E-04
- 2. 41E-02 3.76E-02 871. 09 99.89
-9.97E-03 2.41E-02
+
Ag-108m 79.13 6.60 8.30E-02 2.98E-02 1.37E+OO 433.94 90.50
-1.29E-02 2.98E-02 614.28 89.80
-4.95E-03 3.99E-02 722. 94 90.80 7.25E-03 4.21E-0~
+
Sn-113 255.13 2.11 1.68E-01
- 5. 14E-02 l.42E+OO 391.70
- 64. 97
- 1. 16E-02 5.14E-02
+
Cs-134 475.36
- 1. 48 6.83E-Ol 3.64E-02 2.49E+OO 563.25 8.34 5.59E-02 3.88E-01 569.33 15.37
-8.48E-03 2.12E-01 604. 72 S7.62 7.lOE-03 3.64E-02 Page 5 of8 Tolerance Nuclide Caine Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[62]
4/27/2016 8:46:48AM Page 6 of8 Analysis Report for 27-Apr-16-10002 L310223AFRGS001SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCUgrams)
(pCi!grams)
Corr Cs-134 795.86 85.46 6.40E-03 3.64E-02 4.99E-02 miss 801.95 8.69 4.91E-0~
- 3. 71E-01 miss 1038.61 0.99
-1.38E+OO 2.'75E+OO miss 1167. 97
- 1. 79
-1.26E-01 l.90E+OO miss 1365.1 9 3.02 4.66E-01 1.40E+OO miss
+
Cs-137 661.66 85.10
-2.75E-02 2.74E-02 2.74E-02 miss
+
Eu-152 121.78 28.67 1.97E-02 1.19E-01 1.37E-01 miss 244.70 7.61 3.08E-02 4.36E-01 miss 295.94 0.45
- 1. 53E+Ol l.38E+Ol miss 344.28
- 26. 60
-5.73E-03 l.19E-01 miss 36'7. 7 9 0.86 3.06E-01 4.02E+D0 miss 411.12 2.24
-6.53E-01 l.45E+OO miss 443.96 2.83 6.62E-02 1.13E+OO miss 488.68 0.42
-2.16E+OO 7.88E+OO miss 563.99 0.49
-2.90E+OO 5.57E+OO miss 586.26 0.46
-1.82E+OO 8.44E+OO miss 67 8. 62 0.47
-1.99E+OO 6.57E+OO miss 688.67 0.86 6.85E-01 4.31E+D0 miss 719. 35 0.28
-4.68E+OO 9.85E+00 miss 778.90
- 12. 96
-8.06E-02 2.00E-01 miss 810.45 0.32 1.99E+OO 1.22E+Ol miss 867.37 4.26
-4.0SE-02 8.57E-01 miss 919.33 0.43 1.91E+OO 9.47E+OO miss 964. 0 8 14.65
- 1. 57E-01 3.71E-01 miss 1085.87 10.24
-8.41E-02 3.17E-01 miss 1089.74
- 1. 73
-5.90E-01 1.88E+OO miss 1112. 07
- 13. 69 5.98E-02 3.36E-01 miss 1212.95
- 1. 43
-3.57E-01
- 2. llE+OO miss 1249.94 0.19
-1. 55E+Ol 2.47E+Ol miss 1299.14
- 1. 63 3.97E-01 2.25E+OO miss 1408. 01 21.07 6.09E-02 2.41E-01 miss 1457.64 0.50
-5.03E+OO l.33E+Ol miss 1528.10 0.28 O.OOE+OO 3.67E+OO miss
+
Eu-154 123.07 40.40
-4.41E-02 8. 49E-02 8.49E-02 miss 247.93 6.89 3.0lE-01 5.40E-01 miss 591.76 4.95 3.40E-01 8.40E-01 miss 692.42
- 1. 78
-1.32E-01 2.09E+OO miss 723. 30 20.06 -1. 24E-01 l.50E-01 miss 756.80 4.52 l.BOE-01 9.12E-Ol miss 873.18 12.08
-7.lBE-02 3.04E-01 miss 996.29 10.48 5.lOE-02 3.27E-01 miss 1004.76 18.01
-1.06E-02 l.71E-01 miss 1274.43 34.80
-1. 2 BE-02 1.04E-01 miss 1596.48
- 1. 80
-4. 96E-Ol 1.62E+OO miss
+
Eu-155 45.30
- 1. 31 1.42E+OO 2.40E-01 2.68E+Ol miss 60.01
- 1. 22 8.80E+OO 2.66E+Ol miss 86.55 30.70
-1.23E-01 2.41E-01 miss 105.31 21.10
-l.87E-02 2.40E-Ol miss
+
Tl-208 583.19 85.00 2.39E-Ol 5.30E-02 5.30E-02 miss
+
Bi-211 351.07 13.02 1.51E+OO 2.75E-01 2.75E-01 miss
+
Pb-211 404.85 3.78 4.41E-01 9.17E-01 9.17E-01 miss
[63]
4/27/2016 8:46:48AM Page 7 of8 Analysis Raport for 27-Apr-16-10002 L310223AFRGS001SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi/grams)
(pCi/grams)
(pCilgrams)
Corr Pb-211 427.09
- 1. 76
-1.43E-01 9.17E-01 1.77E+OO miss 832.01 3.52 3.03E-01 l.19E+OO miss
+
Bi-212 39.86
- 1. 06 9.24E-01 1.02E+OO
- 2. 61E+Ol miss 727. 33 6.67 8.81E-01 l.02E+OO miss 785.37 1.10 5.13E-01 3.lOE+OO miss 1620.50
- 1. 47 8.17E-01 2.93E+OO miss
+
Pb-212 115.18 0.60 1.51E+OO 9.14E-02 7.91E+OO miss 23g,53 43.60 6.78E-01 9.14E-02 miss 300.09
-1, 3.30 7.62E-01 1.18E+00 miss
+
Pb212-XR 74.82 10.28 1.53E+00 9.58E-01 1.55E+OO miss 77.11 17.10 1.20E+OO 9.58E-01 miss 87.35 3.97
- 1. lOE+OO l.98E+OO miss 89.78
- 1. 46 3.05E+OO 4.93E+OO miss
+
Bi-214 60 9. 32 45.49 5.02E-01
- 1. 0lE-01 l.OlE-01 miss 768.36 4.89 7.84E-01 1.24E+00 miss 806.18
- 1. 26
- 1. 43E+OO 3.54E+00 miss 934.06 3.11 4.86E-01 1.53E+OO miss 1120.29
- 14. 92 5.68E-01 6.23E-01 miss 1155. 21
- 1. 63 2.47E-01 2.52E+OO miss 1238.12 5.83 6.57E-01 1.13E+OO miss 1280.98
- 1. 43
-1.34E-01 1.72E+0D miss 1377.67 3.99 8.86E-01 1.67E+0D miss 1385.31 0.79 O.OOE+OO 4.16E+OO miss 1401.52
- 1. 33
-4.61E-01 2.SOE+OO miss 1407.99 2.39 5.36E-01 2.12E+OO miss 1509.21 2.13 1.17E+00 2.82E+OO miss 1661.27
- 1. 05 1.56E+00 4.68E+OO miss 1729.59 2.88 5.62E-01 1.76E+OO miss 1764.49 15.30 6.09E-01 7.12E-01 miss 1847.43 2.03 4.67E-01 2.85E+OO miss 2118.51 1.16 O.OOE+OO O.OOE+OO miss
+
Pb-214 24 1.99 7.25 7.29E-01 l. OOE-01 5.43E-01 miss 295.22 18.42 6.80E-01 l.92E-01 miss 351.93 35.60 5.53E-01 l.OOE-01 miss 785. 96
- 1. 06
-4.48E-01 2.75E+OO miss
+
Pb214-XR 74.82 5.80 2.71E+OO
- 1. 69E+OO 2.75E+OO miss 77.11 9.70
- 2. llE+OO 1.69E+OO miss 87.35 2.24 1.95E+00 3.50E+OO miss 89.78 0.82 5.43E+OO 8.78E+OO miss
+
Ra-226 186.21
~l-3.64 6.94E-01
- 1. 16E+OO 1.16E+OO miss
+
Ac-~28 129.07 2.42
- 1. 09E+OO
- l. 43E-01 l.87E+OO miss 209.25 3.89 7.24E-01 l.05E+00 miss 270.24 3.46 4.lOE-01 1.18E+OO miss 328.00 2.95 4.22E-01 1.37E+OO miss 338.32
- 11. 27 7.04E-01 4.28E-Ol miss 409.46
- 1. 92
- 8. llE-01 1.86E+OO miss 463.00 4.40 6.lOE-01 1.09E+OO miss 794.95 4.25 3.74E-01 1.08E+OO miss 911. 20 25.80 6.81E-01 1.43E-01 miss 964. 77 4.99 3.17E-01 1.09E+OO miss 968.97 15.80 8.02E-01 3.38E-01 miss
[64]
4/27/2016 8:46:48AM Page 8 of8 Analysis RejJort for 27-Apr-16-10002 L310223AFRGS001SS (DRIED)
IJucJide Energy Yield(%)
ActiYity NuclideMDA LineMDA Coinc:
Name (keV)
(pCi/grams)
(pCUgrams)
(pCi/grams)
Corr Ac-228 1588.20 3.22 4.13E-01 l.43E-01 l.60E+OO miss
+
Pa-231 27.36 10.30 2.16E-01 1.30E+OO 3.19E+OO miss 283.69
- 1. 70
-5.35E-01 1.80E+OO miss 300.07 2.47
- 1. 02E+OO
- 1. 58E+OO miss 302.65 2.20
-2.43E-01 1.30E+OO miss 330.06
- 1. 40 1.92E-02 2.58E+OO miss
+
Th-234 92.38 2.13 1.60E+OO 3.22E+OO 3.22E+OO miss 92.80 2.10 l.54E+OO
- 3. 31E+OO miss 112. 81 0.21 1.15E+Ol 2.26E+Ol miss
+
U-235 143.76
- 10. 96
-3.37E-02 7.39E-02 3.49E-01 miss 163.33 5.08
-4.66E-02 6.36E-01 miss 185.71 57.20 4.42E-02 7.39E-02 miss 202.11
- 1. 08
-6.17E-01 3.04E+OO miss 205.31 5.01 l.91E-01 6.83E-01 miss
+
Am-241 59.54 35.90
-1. lSE-01 8. 53E-01 8.53E-01 miss
+
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> - MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[65]
120 110 100 90-80
~
.-< 1 70 V)
+-'
C:
0 60 u
so 40 9
..c "'
X
..c 0..
30 1i'.
.... 9
~
20 u..
10 0
1000 I
(X)
~
I
'i=
2000 3000 0000014743.CNF 4000 5000 channel Live Time 600.000 sec Real Time 601.090 sec Start:
1 -0. l(kev) stop : 8192 2047.O(kev)
Acq. start wed Apr 2 7 08: 36: 07 2016 6000 7000 8000
[66]
4/27/2016 9:08:18AM
~~~pex-Gamma Analysis Report for 27-Apr-16-10003 L310223AFRGS002SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
. 27-Apr-16-10003
- L310223AFRGS002SS (DRIED)
- 1 L 130G Soil Sample 1. 768E +03 grams
- Default
- 4/25/2016 1 :25:00PM
- 4/27/2016 8:57:37AM
- 130G 1 L Sand Sample
- JWelch
- P40818B
- 130G Sand
- 600.0 seconds
- 601.1 seconds
- 0.18 %
- 2.80
- 120-8192
- 120-8192
- 1.000FWHM
- 1/27/2016
- 1/5/2015
- 14744 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 9:07:47AM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Page 1 of8
[67]
Analysis Report for 27-Apr-16-10003 L310223AFRGS002SS (DRIED)
Peak Energy ROI No.
(keV) start 1
238.53 946 -
2 295.18 1174 -
3 351.83 1403 -
4 583.06 2326 -
5 609.08 2430 -
6 910.92 3636 -
7 1460.70 5834 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 961 1186 1414 2340 2444 3651 5853 4/27/2016 9:08:18AM Peak Net Peak Net Area Centroid Area Uncertainty 954.63
- 1. 66E+02
- 41. 33 1181.04 6.81E+Ol 24.43 1407.51 1.07E+02 25.15 2332.01 6.22E+Ol 20.16 2436.08 8.lOE+Ol 21.10 3643.40 5.26E+Ol
- 14. 96 5843.75 l.19E+02
- 22. 67 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Page2 of8 Continuum Tentative Counts Nuclide 1.74E+02 Pb-212 6.18E+Ol Pb-214 Eu-152 4.49E+Ol Pb-214 Bi-211 3.16E+Ol Tl-208 2.40E+Ol Bi-214 2.77E+OO Ac-228 7.99E+OO K-40 Activity Coinc Name Confidence (keV)
(pCilgrams)
Uncertainty Corr K-40 0.99 1460.82 10.66 4.17E+OO 8.73E-01 miss Tl-208 0.99 583.19 85.00
- 1. 4 7E-01 5.08E-02 miss Pb-212 0.99 115.18 0.60 238.63 43.60 4.21E-01 1.25E-01 miss 300.09 3.30 Bi-214 0.99 609.32 45.49 3.68E-01
- 1. 0 6E-01 miss 768.36 4.89 806.18 1.26 934.06
- 3. 11 1120.29 14.92 1155.21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385. 31 0.79 1401.52
- 1. 33 1407.99 2.39 1509.21 2.13 1661. 27
- 1. 05
[68]
Analysis Report for 27-Apr-16-10003 L310223AFRGS002SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214 0.99 1729.59 1764.49 1847.43 2118.51 Pb-214
- 1. 00 241.99 295.22 351.93 785. 96 Ac-228 0.48 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964.77 968. 97 1588.20
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
2.88 15.30 2.03 1.16 7.25 18.42 35.60
- 1. 06 2.42 3.89 3.46 2.95
- 11. 27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 9:08:18AM Page 3 of8 Activity Activity Coinc (pCilgrams)
Uncertainty Corr 4.67E-01 1. 84E-01 miss 4.23E-01 l.21E-01 mis~
5.53E-01 1. 64E-01 miss INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCilgrams)
Uncertainty K-40 0.999 4.17E+OO 8.73E-01 Tl-208 0.999
- 1. 4 7E-01 5.0BE-02 X
Bi-211 0. 965 Pb-212 0.999 4.21E-Ol 1.25E-Ol
[69]
Analysis Report for 27-Apr-16-10003
?
=
X
=
L310223AFRGS002SS (DRIED)
Nuclide Nuclide Name Id Confidence Bi-214
- 0. 99S Pb-214
- 1. 000 Ac-228 0.481 nuclide is part of an undetermined solution nuclide rejected by the interference analysis 4/27/2016 Wt mean Activity (pCilgrams) 3.68E-01 4.36E-01 5.53E-01
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 9:08:18AM Page 4 of8 Wt mean Comments Activity Uncertainty l.06E-01 1.0lE-01
- 1. 64E-01
[70]
4/27/2016 9:08:18AM Analysis Report for 27-Apr-16-10003
+
+
+
+
+
+
+
+
+
L310223AFRGS002SS (DRIED)
Peak Locate Perfom,ed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy {keV)
All peaks were identified.
M = First peak in a multiplet region rn = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigrna UNIDENTIFIED PEAKS
- 4/27/2016 9:07:47AM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCi/grams)
(pCi!grams)
(pCi/grams)
K-40 1460.82
- 10. 66 4.17E+OO 4.50E-01 4.50E-01 Cr-51 320.08 9.91 8.34E-02 3.58E-01 3.58E-Ol Mn-54 834.85 99.98 2.07E-03 3.85E-02 3.85E-02 Co-58 810.76 99.45
-8. llE-03 2.38E-02 2.38E-02 1674.73 0.52
-4.08E-01 6.00E+DO Co-60 1173.23 99.85 l.28E-02 3.75E-02 3.86E-02 133~.49 99.98
-5.lSE-03 3.75E-02 Nb-94 702.65 99.81 4.09E-03 3.44E-02 3.80E-02 871. 09 99.89 8.32E-03 3.44E-02 Ag-108m 79.13 6.60 4.0lE-01 2.72E-02
- l. 37E+OO 433.94 90.50 4.70E-03
- 2. 72E-02 614.28 89.80
-1.91E-02 3.67E-02 722. 94 90.80 3.30E-03 3.07E-02 Sn-113 255.13 2.11
- 1. 51E-01 3.35E-02
- 1. 56E+OO 391.70
- 64. 97
-6.BlE-03 3.35E-02 Cs-134 475.36
- 1. 48 1.13E+OO
- 2. 7':'E-02 2.38E+OO 563.25 8.34 1.34E-01 4.SSE-01 569.33 15.37
-6.43E-03 2.24E-01 604. 72 97.62
-4.30E-03
- 2. 77E-02 Page 5 of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[71]
4/27/2016 9:08:18AM Page 6 of8 Analysis Report for 27-Apr-16-10003 L310223AFRGS002SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCUgrams)
(pCilgrams)
(pCi/grams)
Corr Cs-134 795.86 85.46
-5.25E-02 3.0BE-01 miss 1038.61 0.99
-1.87E+OO 2.78E+OO miss 1167.97
- 1. 79
-4.0SE-01 1.31E+OO miss 1365.19 3.02
- 1. 51E-01 1.09E+OO miss
+
Cs-137 661.66 85.10 -l.07E-03 3.09E-02 3.09E-02 miss
+
Eu-152 121. 78 28.67 3.89E-02 1.02E-01 l.31E-01 miss 244.,0 7.61
-1.97E-01 3.90E-01 miss 295.94 0.45
-3. llE-01 l.21E+Ol miss 344.28 26.60
-7.34E-03 1.02E-01 miss 367.79 0.86 8.SOE-01 3.61E+OO miss 411. 12 2.24 2.36E-01 1.54E+OO miss 443. 96 2.83 6.23E-01 1.25E+OO miss 488.68 0.42
-1.21E+OO 6.35E+OO miss 563.99 0.49
- 1. 76E+OO
- 6. 96E+OO miss 586.26 0.46
-1.58E+OO 6.58E+OO miss 678.62 0.47
- 1. 73E+OO 8.54E+OO miss 688.6 7 0.86 2.61E-01 4.15E+OO miss 71S.35 0.28 5.23E+OO 1.24E+Ol miss 778.90 12.96
-5.33E-02 l.75E-01 miss 810.45 0.32
-1.13E+OO 8.39E+OO miss 867.37 4.26 2.0 l E-01 8.67E-01 miss 919.33 0.43 1.49E+OO 8.99E+OO miss 964. 08 14.65 2.00E-01 3.75E-01 miss 1085.87 10.24 1.91E-02 3.57E-D1 miss 1089.74
- 1. 73 3.78E-01 1.9DE+OO miss 1112. 07
- 13. 69
-2.58E-02 2.lOE-01 miss 1212.95
- 1. 43
-l.54E+OO l.69E+OO miss 1249.94 0.19 2.52E+0D l.90E+Ol miss 1299.14
- 1. 63
-1.81E-D1 l.55E+OO miss 1408.01 21.07 3.69E-D2 2.07E-01 miss 1457.64 0.50
-l.19E+Ol l.44E+Ol miss 1528. 10 0.28 l.37E+OO l.OlE+Ol miss
+
Eu-154 123.07 40.40
-2.SOE-02 8.58E-02 8.58E-02 miss 247.93 6.89
-2.20E-01 4.03E-01 miss 591.76 4.95
-5.15E-02 6.lSE-01 miss 692.42
- 1. 78 9.12E-01 2.55E+OO miss 723. 30 20.06
- 1. 27E-02 l.52E-Ol miss 756.80 4.52 1.86E-01 8.82E-01 miss 873.18 12.08
-l.16E-Ol 2.02E-01 miss 996.29 10.48
-5.95E-02 2.02E-01 miss 1004.76
- 18. 01
-1.07E-02 1.73E-01 miss 1274.43 34.80
-1.39E-03 1.05E-01 miss 1596.48
- 1. 80 4.17E-01 2.07E+OO miss
+
Eu-155 45.30
- 1. 31 8.58E+OO 2.0SE-01 2.32E+Ol miss 60.01
- 1. 22 3.56E+OO 2.08E+Ol miss 86.55 30.70 3.73E-02 2.13E-01 miss 105.31 21.10
-3.86E-02 2.0SE-01 miss
+
Tl-208 583.19 85.00
- 1. 4 7E-Ol 5.51E-02 5.51E-02 miss
+
Bi-211 351. 07 13.02 1.16E+OO 2.86E-01 2.86E-01 miss
+
Pb-211 404.85 3.78 2.06E-02
- 7. 7'7E-01 7.77E-01 miss
[72]
4/27/2016 9:08:18AM Page 7 of8 Analysis Report for 27-Apr-16-10003 L310223AFRGS002SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCUgrams)
(pCilgrams)
(pCi!grams)
Corr Pb-211 427.09
- 1. 76
-9.03E-02 7.77E-01 1.67E+OO miss 832.01 3.52 2.31E-01 1.02E+OO miss
+
Bi-212 39.36
- 1. 06 4. 96E+OO 8.21E-01 2.35E+Ol miss 727. 33 6.67 5.06E-01 8.21E-01 miss 785.37 1.10
-3.26E-01 2.91E+OO miss 1620.50
- 1. 47 9.46E-01 3.31E+OO miss
+
Pb-212 115. 18 0.60
-6. 96E-01 1.42E-01 5.93E+OO miss 238.63 43.60 4.21E-01 l.42E-01 miss 300.09 3.30 4.~lE-01
- 1. llE+OO miss
+
Pb212-XR 74.82 10.28
-2.13E-02 7.58E-01
- l. llE+OO miss 77. 11 17.10 5.89E-01 7.58E-01 miss 87.35 3.97
- 1. 03E+OO
- 1. 71E+OO miss 89.78
- 1. 46 9.82E-01 4.lOE+OO miss
+
Bi-214 609.32
'/,
45.49 3.68E-01 9.45E-02 9.45E-02 miss 768.36 4.89 6.75E-01 l.OSE+OO miss 806.18
- 1. 26 6.7C1E-01 3.13E+OO miss 934.06 3.11 2.07E-01 l.25E+OO miss 1120.29 14.92 3.77E-Ol 5.41E-01 miss 1155. 21
- 1. 63 3.22E-01 2.55E+OO miss 1238.12 5.83 7.39E-01 1. llE+OO miss 1280.98
- 1. 43 7.92E-01 3.55E+OO miss 1377. 67 3.99 5.50E-01 l.42E+OO miss 1385. 31 0.79
-3.88E-01 3.33E+OO miss 14 01. 52
- 1. 33 3.89E-02 2.53E+OO miss 1 407.99 2.39 3.25E-01 l.82E+OO miss 1509.21 2.13 3.85E-01 2.16E+OO miss 1661.27
- 1. 05 9.35E-01 4.24E+OO miss 1729.59 2.88
- 2. 77E-01 l.59E+OO miss 1764.49 15.30 4.43E-01 6.18E-01 miss 1847.43 2.03 2.74E-02 2.04E+OO miss 2118. 51
- 1. 16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241.99 7.25 5.04E-01
- 1. 04E-01 6.31E-01 miss 295.22 18.42 4.67E-01 2.22E-01 miss 351.93 35.60 4.23E-01
- 1. 04E-Ol miss 785. 96
- 1. 06
-3.70E-01 3.03E+OO miss
+
Pb214-XR 74.82 5.80
-3.78E-02
- l. 34E+OO l.97E+OO miss 77.11 9.70 1.04E+OO l.34E+OO miss 87.35 2.24 1.83E+OO 3.03E+OO miss 89.78 0.82 1.75E+OO 7.30E+OO miss
+
Ra-226 186.21
- 3. 61 1.00E+OO
- 1. llE+OO
- 1. llE+OO miss
+
Ac-228 129. 07 2.42 6.82E-02 9.16E-02 l.52E+OO miss 209.25 3.89 6.23E-Ol 8.68E-01 miss 270.24 3.46 4.90E-01 1. llE+OO miss 328.00 2.95 3.67E-01 1.19E+OO miss 338.32
- 11..27 6.20E-01 4.85E-01 miss 409.46
- 1. 92 1.17E-02
- l. 65E+OO miss 463.00 4.40 5.65E-01 9.15E-01 miss 794.95 4.25 9.98E-01 l.34E+OO miss 911. 20 25.80 5.53E-01 9.16E-02 miss 964.77 4.99 5.67E-01 l.lOE+OO miss 968.97 15.80
'1.35E-01 4.89E-01 miss
[73]
4/27/2016 9:08:18AM Page 8 of8 Analysis Report for 27-Apr-16-10003 L310223AFRGS002SS (DRIED)
Nuclide Energy Yield(%)
Activity Nuc/ideMDA LineMDA Coinc Name (keV)
(pCi/grams)
(pCUgrams)
(pCi!grams)
Corr Ac-228 1588.20 3.22 5.41E-01 9.16E-02 1.74E+OO miss
+
Pa-231 27.36 10.30
-1.74E-01 1.lOE+OO 2.42E+OO miss 283.69
- 1. 70
-6.02E-01 l.67E+OO miss 300.07 2.47 5.63E-01 1.48E+OO miss 302.65 2.20
-5.72E-01 1.lOE+OO miss 330.06
- 1. 40
-4.30E-01 2.18E+OO miss
+
Th-234 92.38 2.13 6.51E-01 2.83E+OO 2.83E+OO miss 92.80 2.10 2.06E+OO 3.lOE+OO miss 112. 81 0.21
- 3. llE+OO 1. 97E+01 miss
+
U-235 143.76
- 10. 96 5.39E-02
- 6. 96E-02 3.27E-01 miss 163.33 5.08 2.71E-01 6.36E-01 miss 185.71 57.20 4.lOE-02 6.96E-02 miss 202. 11
- 1. 08 8.57E-01 2.79E+OO miss 205.31 5.01
-5.62E-02 5.97E-01 miss
+
Am-241 59.54 35.90 7.53E-02 7. 77E-01 7.77E-01 miss
+
= Nuclide identified during the nuclide identification
~ Energy line found in the spectrum
"' MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDAvalue is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[74]
VI
.j-.J C:
- II 60 55 50 45 40 35 8 30 25 20 15 10 5
1000 2000
~
"&i 3000 0000014744.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :601.070 sec Start:
1: -0. l(kev) stop : 8192: 2047.O(kev)
Acq. start :wed Apr 27 08: 57: 37 2016 6000 7000 8000
[75]
4/27/2016 12:37:22P~v1 Analysis Report for 27-Apr-16-10008 L310223AFRGS003SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10008
- L310223AFRGS003SS (DRIED)
- 1 L 130G Soil Sample
- 1. 724E +03 grams
- Default
- 4/25/2016 1 :20:00PM
- 4/27/2016 12:26:43PM
- 130G 1 L Sand Sample
- JWelch
- P11314X2
- 130G Sand
- 600.0 seconds
- 600.5 seconds
- 0.08%
- 2.80
- 120 - 8192
- 120 - 8192
- 1.000FWHM
- 1/27/2016
- 11/26/2012
- 14749 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 12:36:48PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance otrm '1 Pt\\.l n~D 1ih~J,tg C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Page 1 of8
[76]
4/27/2016 12:37:22PM Page 2 ofS Analysis Report for 27-Apr-16-10008 L310223AFRGS003SS (DRIED)
Peak Energy ROI No.
{keV) start 1
238.68 946 -
2 235.44 1176 -
3 338.37 1349 -
4 352.11 1402 -
5 609.48 2430 -
6 1120.73 4476 -
7 14 61. 30 5833 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 960 1188 1360 1414 2445 4487 5854 Peak Net Peak NetArea Continuum Centroid Area Uncertainty Counts 955.06 1.04E+02
- 29. 96 8.39E+Ol 1181. 80 5.79E+Ol 20.27 3.42E+Ol 1353.32 2.73E+Ol
- 14. 62 2.33E+Ol 1408.23 7.70E+Ol 20.89 2.80E+Ol 2436.85 5.34E+Ol 17.,3 1.92E+Ol 4481.50 l.93E+Ol 9.48 3.43E+OO 5844.52 l.75E+02
- 26. 80 3.15E+OO NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCilgrams)
Uncertainty K-40 0.98 1460.82 10.66 5.68E+OO 9.97E-01 Pb-212
- 1. 00 115.18
- 0. 60 238.63 43.60 2.40E-Ol 7.93E-02 300.09 3.30 Bi-214 0.99 609.32 45.49 2. 24E-01 7.92E-02 768.36 4.89 806.18
- 1. 26 934.06 3. 11 1120.29
- 14. 92
- 3. 71E-01
- 1. 85E-01 1155.21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385. 31
- 0. 79 1 401.52
- 1. 33 1 407.99 2.39 1509.21 2.13 1661.27
- 1. 05 1729.59 2.88 Tentative Nuclide Pb-212 Pb-214 Eu-152 Ac-228 Pb-214 Bi-211 Bi-21~
Bi-214 K-40 Coinc Corr miss miss miss miss
[77]
Analysis Report for 27-Arr-16-10008 L310223AFRGS003SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214 0.99 1764.49 1847.43 2118. 51 Pb-214 0.99 241.99 295.22 351.93 785.96 Ac-228 0.57 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964.77 968. 97 1588.20
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
15.30 2.03 1.16 7.25 18.42 35.60
- 1. 06 2.42 3.89 3.46 2.95 11.27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 12:37:22PM Page 3 of8 Activity Activity Coinc (pCilgrams)
Uncertainty Corr 3. 64E-0 1 1.40E-01 miss 2.82E-O l 8.88E-02 miss 3.08E-01
- 1. 72E-01 miss INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCilgrams)
Uncertainty K-40 0.986 5.68E+OO 9.97E-01 X
Bi-211 0.936 Pb-212
- 1. 000 2.40E-01 7.93E-02 Bi-214 0.998 2.47E-01 7.28E-02 Pb-214
- 0. 998 3.06E-01 7.SOE-02
[78]
Analysis Report for 27-Apr-16-10008
? =
X =
L310223AFRGS003SS {DRIED)
Nuclide Nuclide Name Id Confidence Ac-228 0.575 nuclide is part of an undetermined solution nuclide rejected by the interference analysis 4/27/2016 Wt mean Activity (pCilgrams) 3.08E-01
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 12:37:22PM Pagc4 of8 wt mean Comments Activity Uncertainty l.72E-01
[79]
4/27/2016 12:37:22PM Analysis Report for 27-Apr-16-10008
+
+
+
+
+
+
+
+
+
L310223AFRGS003SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (ke V)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 12:36:48PM
- 120
- 8192 Peak CPS {°/o)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCi!grams)
(pCilgrams)
(pCi/grams)
K-40 1460.82 10.66 5.68E+OO 3.02E-01 3.02E-01 Cr-51 320.08 9.91 2.72E-02 2.26E-Ol 2.26E-01 Mn-54 834.85 99.98 4.90E-03
- 3. llE-02
- 3. llE-02 Co-58 810.76 99.45 7.02E-03 2.85E-02 2.85E-02 1674.73 0.52 O.OOE+OO 2.04E+OO Co-60 1173.23 99.85 2.65E-03
- 8. 71E-03 3.56E-02 1332.49 99.98 O.OOE+OO
- 8. 71E-03 Nb-94 702.65 99.81
-9.37E-04 2.26E-02 2.97E-02 871. 09 99.89
-2.63E-03 2.26E-02 Ag-108m 79.13 6.60
-7.22E-03 2.19E-02 6.47E-01 433.94 90.50 9.60E-03 2.SlE-02 614.28 89.80 O.OOE+OO 2.30E-02 722.94 90.80
-3.74E-03 2.19E-02 Sn-113 255.13 2. 11 2.08E-01 3.48E-02 1.0lE+OO 391.70 64.97
-7.13E-03 3.48E-02 Cs-134 475.36
- 1. 48 2.29E-01 2.56E-02 1.73E+OO 563.25 8.34
-1.13E-02 2.85E-01 569.33 15.37 1.35E-02 1.68E-Ol 604.72 97.62 O. OOE+OO 2.5t:iE-02 Page S of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[80]
A l'l7/'ln~ a "Tf4'.ll4',U IV
~ 2:37:22P~v1 Page 6 of8 Analysis Report for 27-Apr-16-10008 L310223AFRGS003SS (DRIED)
,.,uclide Energy Vi,nl,l/0/..1 A"f;.,;.fu 1-!uc!idc AfDA LineMDA Ccin::
- *"--*-, IUJ r,v*****,1 Name (keV)
(pCUgrams)
(pCilgrams)
(pCi!grams)
Corr Cs-134 795.86 85.46 3.57E-03 2.56E-02 3.51E-02 miss 801.95 8.69
-2.65E-02 2.85E-01 miss 1038. 61 0.99
-7. 61E-01 2.57E+OO miss 1167.97
- 1. 79 1.03E+OO 2.48E+OO miss 1365.19 3.02 O.OOE+OO
- 2. 94E-01 miss
+
Cs-137 661.66 85.10 5.54E-04
- 3. llE-02
- 3. llE-02 miss
+
Eu-152 121.78 28.67 2.09E-02 8.17E-02 8.17E-02 miss 244.70 7.61 1.26E-02 3.16E-01 miss 295.94 0.45 l.15E+Ol l. OOE+Ol miss 344.28 26.60 3.lOE-02 9.71E-02 miss 367.79 0.86
-3.33E-02
- 2. 60E+OO miss 411. 12 2.24
-2.38E-01 l.03E+OO miss 443. 96 2.83 2.89E-01 9.46E-01 miss 488.68 0.42
-5.03E-01 5.87E+OO miss 563.99 0.49 8.13E-01 5.21E+OO miss 586.2; 0.46
-3.50E+OO 4.86E+OO miss 678.62 0.47 l.59E+OO 6.14E+OO miss 688.67 0.86 4.03E-02 2.60E+OO miss 719.35 0.28 1.05E+OO 9.20E+OO miss 778.90 12.96
-l.21E-01 l.87E-01 miss 810.45 0.32 4.0lE-01 7.76E+OO miss 867.37 4.26 2.94E-01 8.54E-01 miss 919.33 0.43
- 8. llE-01 7.08E+OO miss 964. 08 14.65
-l.78E-02 1.65E-01 miss 1085.87 10.24
-4.24E-02 3.60E-01 miss 1089.74
- 1. 73
-8.15E-02 2.30E+OO miss 1112. 07
- 13. 69 5.78E-02 3.31E-01 miss 1212.95
- 1. 43
-2.12E-01 2.28E+OO miss 1249.94 0.19
-6. 96E+OO 2.45E+Ol miss 1299.14
- 1. 63
-5.84E-01 l.43E+OO miss 1408.01
- 21. 07 4.38E-02 l.91E-01 miss 1457.64 0.50
-9.68E+OO 1.03E+Ol miss 1528.10 0.28 l.27E+OO 9.32E+OO miss t
Eu-154 123.07
- 40. 40
-l.95E-02 5.25E-02 5.25E-02 miss 247.93 6.89
-3.80E-02 3.0lE-01 miss 591.76 4.95
-1.89E-03 4.55E-01 miss 692.42
- 1. 78 5.13E-01 l.86E+OO miss 723. 30 20.06 5.91E-02 l.51E-01 miss 756.80 4.52
-l.06E-01 7.35E-Ol miss 873.18 12.08
-l.85E-02 l.87E-01 miss 996.29 10.48 7.79E-02 3.33E-01 miss 1004.76 18.01
-6.19E-02
- 1. 38E-01 miss 1274.43 34.80 3.17E-02 l.08E-01 miss 1596. 48
- 1. 80
-2.05E-01 l.91E+OO miss Eu-155 45.30
- 1. 31 1.66E+OO
- 1. 12E-01 6.16E+OO miss 60.01
- 1. 22
-3.86E+OO 6.38E+OO miss 86.55 30.70
-1.78E-02 l.12E-Ol miss 105.31 21.10
-7. 92E-03 l.16E-01 miss
+
Tl-208 583.19 85.00 6.93E-02 6.60E-02 6.60E-02 miss
+
Bi-211 351.07 13.02
- 7. 71E-01 2.14E-01 2.14E-01 miss
+
Pb-211 404.85 3.78 l.76E-01 6.91E-01 6.91E-01 miss
[81]
4/27/2016 12:37:22PM Page 7 of8 Analysis Report for 27-Apr-16-10008 L310223AFRGS003SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCi/grams)
(pCi/grams)
Co" Pb-211 427.09
- 1. 76
-7.08E-01 6.91E-01 9.15E-01 miss 832. 01 3.52
-1.73E-01 8.04E-01 miss
+
Bi-212 39.86
- 1. 06 2.llE-01 6.87E-01 8.0lE+OO miss 727. 33 6.67 2.25E-01 6.88E-01 miss 785.37
- 1. 10
-7.34E-02 3.09E+OO miss 1620.50
- 1. 4 7 O.OOE+OO 6.87E-01 miss
+
Pb-212 115.18 0.60 1.57E+OO 8.95E-02 4.56E+OO miss 238.63 43.60 2.40E-01
- 8. 95E-02 miss 300.09 3.30 2.33E-01 8.16E-01 miss
+
Pb212-XR 74.82
- 10. 28 3.52E-01 4.19E-01 6.90E-01 miss 77.11 17.10 4.16E-01 4.19E-01 miss 87.35 3.97 4.82E-01 9.70E-01 miss 89.78
- 1. 4 E:
8.lOE-01 2.54E+OO miss
+
Bi-214 609.32 45.49 2.24E-01 8.08E-02 8.08E-02 miss 768.36 4.89 3.26E-01 8.89E-01 miss 806.18
- 1. 26 6.20E-01 2.39E+OO miss 934.06 3.11 4.lOE-01 1.30E+OO miss 1120.~9 14. 92
- 3. 71E-01 l.65E-01 miss 11 55. 21
- 1. 63
-1.28E-01 l.93E+OO miss 1238.12 5.83 1.25E-01 7.41E-01 miss 1280.98
- 1. 43 1.09E+OO 2.86E+OO miss 1377.67 3.99 9.lOE-01 1.50E+OO miss 1385. 31 0.79 O.OOE+OO l.13E+OO miss 1401. 52
- 1. 33 2.87E-01
- 2. 70E+OO miss 1407.99 2.39 3.85E-Ol l.68E+OO miss 1509. 21 2.13
-7. llE-02
- 1. 22E+OO miss 1661. 27
- 1. 05 O.OOE+OO 9.83E-01 miss 1729.59 2.88 5.45E-01 1.64E+OO miss 1764.49 15.30 2.lOE-01 4.54E-01 miss 1847.43 2.03
-7.60E-02 l.49E+OO miss 2118. 51
- 1. 16 O.OOE+O()
O.OOE+OO miss
+
Pb-214 241.99 7.25
- 1. 85E-01 7. 82E-02 4.0lE-01 miss 295.22 18.42 3.64E-01 1.56E-01 miss 351.93 35.60 2.82E-01 7.82E-02 miss 1 85.96
- 1. 06 2.17E+OO 4.03E+OO miss
+
Pb214-XR 74.82 5.80 6.24E-01 7.38E-01
- 1. 22E+OO miss
- 77. 11 9.70 7.34E-01 7.38E-01 miss 87.35 2.24 8.54E-01 1.72E+OO miss 89.78 0.82 1.44E+OO 4.51E+OO miss
+
Ra-226 186.21 3.64 5.26E-01 7.95E-01 7.95E-01 miss
+
Ac-228 129.07 2.42 4.62E-Ol 2.20E-01
- 1. llE+OO miss 209.25 3.89 4.80E-01 7.09E-Ol miss 270.24 3.46 6.63E-01 9.04E-01 miss 323. 00 2.95 4.19E-01 9.46E-01 miss 338.32 11. 27 3.08E-01 2.20E-01 miss 409.46
- 1. 92 4.45E-01 1.42E+OO miss 463. 00 4.40 3.95E-01 8.45E-01 miss 794.95 4.25 3.76E-02 7.05E-01 miss 911. 20 25.80 3.lSE-01 2.98E-01 miss 964. 77 4.99
-4.35E-02 4.85E-01 miss 968.97 15.80 2.04E-01 3.53E-01 miss
[82]
4/27/2016 12:37:22PM Page 8 of8 Analysis Report for 27-Apr-16-10008 L310223AFRGS003SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCi/grams)
(pCi/grams)
(pCi!grams)
Corr Ac-228 1588.20 3.22 O.OOE+OO 2.20E-01 3.09E-01 miss
+
Pa-231 27.36 10.30 O.OOE+OO 9.94E-02 9.94E-02 miss 283.69
- 1. 70
-8.30E-02 1.42E+OO miss 300.07 2.47
- 3. llE-01
- l. 09E+OO miss 302.65 2.20
-5.67E-Ol 8.93E-01 miss 330.06
- 1. 40
-2.45E-01 1.49E+OO miss
+
Th-234 92.38 2.13
- .62E-01
- 1. 90E+OO
- 1. 90E+OO miss 92.80 2.10 7.57E-01 2.03E+DO miss 112. 81 0.21
-6.49E-01 l.20E+Ol miss
+
0-235 143.76
- 10. 96 4.46E-02 4.94E-02 2.17E-01 miss 163.33 5.08 2.25E-01 5.06E-01 miss 185. 71 57.20 3.22E-02
- 4. 94E-02 miss 202. 11
- 1. 08
- l. 85E-01 1. 91E+OO miss 205.31
- 5. 01
-1.28E-01 4.06E-01 miss
+
Am-241 59.54 35.90
-5.08E-02 2.47E-01 2.47E-01 miss
+
"' Nuclide identified during the nuclide identification
- Energy line found in the spectrum
- MDA value not calculated
- Half-life too short to be able to perform the decay correction
?
- CAUTION
free ;: No coincidence correction required.
miss ;: Nuclide energy was not found in the coincidence library.
[83]
[84]
Analysis Report for 27-Apr-16-1 0009 L310223AFRGS004SS (DRIED) 4/27/2016 12:37:58PM GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number 27-Apr-16-10009 L310223AFRGS004SS (DRIED) 1L 130G Soil Sample 1.672E+03 grams Default 4/25/2016 1:15:00PM 4/27/2016 12:26:58PM 130G 1 L Sand Sample JWelch
. P40818B
! 130G Sand
- 600.0 seconds
- 601.0 seconds
- 0.17 %
- 2.80
- 120 - 8192
- 120 - 8192
- 1.000FWHM
- 1/27/2016
- 1/5/2015
- 14750 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 12
- 37:27PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Page 1 of7
[85]
4/27/2016 12:37:58PM Page 2 of7 Analysis Report for 27-Apr-16-10009 L310223AFRGS004SS (DRIED)
Peak t=narr,11 RO!
-**-*::1,1 No.
(keV) start 1
238.61 951 -
2 295. 17 1174 -
3 351.91 1403 -
4 533.15 2326 -
5 609.21 2430 -
6 1460.53 5833 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma RO!
end 961 1188 1416 2339 2443 5852 Peak Net Peak Net Area,.. __.,_.... _
VVJl&nlUUIII Centroid Area Uncertainty Counts 954.92 7.'"75E+01 28.24 9.90E+Ol 1181. 00 6.02E+O l 24.15
- 5. 96E+Ol 1407.82 7.63E+Ol
- 20. 65 2.54E+Ol 2332.38 3.42E+Ol 14.22
- 1. 36E+Ol 2436.59
- 5. 77E+Ol
- 16. 77
- 1. 06E+Ol 5843.07 1.26E+02 23.07 5.71E+OO NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCilgrams)
Uncertainty K-40 0.99 1 460.82
~**
10.66 4.67E+OO 9.46E-01 Tl-208
- 1. 00 583.19 85.00 8.53E-02 3.69E-02 Pb-212
- 1. 00 115.18 0.60 238.63 43.60 2.08E-01 8.28E-02 300.09 3.30 Bi-214
- 1. 00 609.32 45.49 2.77E-01
- 8. 72E-02 768.36 4.89 806.18
- 1. 26 934.06
- 3. 11 1120.29
- 14. 92 1155.21
- 1. 63 1238. 12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385. 31
- 0. 79 1401.52
- 1. 33 1407.99 2.39 1509.21 2.13 1661. 27
- 1. 05 1729.59 2.88 Tentative Nuclide Pb-212 Pb-2 14 Eu-152 Pb-214 Bi-211 Tl-208 Bi-2 14 K-40 Coinc Corr miss miss miss miss
[86]
Analysis Report for 27-Apr-16-10009 L310223AFRGS004SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214
- 1. 00 1764.49 1847.43 2118. 51 Pb-214
- 1. 00 241.99 295.22 351.93 785. 96
- = Energy line found in the spectrum.
= Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold= 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
- 15. 30 2.03 1.16 7.25 18.42 35.60
- 1. 06 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 12:37:58PM Page 3 of7 Activity Activity Coinc (pCilgrams)
Uncertainty Corr 4.37E-01
Bi-211 Pb-212 Bi-214 Pb-214 Nuclide Id Confidence 0.995 1. 000 0.958 1. 000
- 1. 000
- 1. 000
?
=
nuclide is part of an undetermined solution X
=
nuclide rejected by the interference analysis Wt mean Activity (pCilgrams) 4.67E+OO 8.53E-02 2.08E-01 2.77E-01 3.46E-01
=
nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Wt mean Comments Activity Uncertainty 9.46E-01 3.69E-02 8.28E-02
- 8. 72E-02 8.88E-02
[87]
4/27/2016 12:37:58PM Analysis Report for 27-Apr-16-10009
+
+
+
+
+
+
+
+
+
L310223AFRGS004SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.00Dsigma UNIDENTIFIED PEAKS
- 4/27/2016 12:37:27PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCilgrams)
(pCUgrams)
(pCi/grams)
K-40 1460.82
- 10. 66 4.67E+OO 4.21E-01 4.21E-01 Cr-51 320.08 9.91 3.36E-02 3.35E-01 3.35E-01 Mn-54 834.85 99.98
-7.91E-04 3.26E-02 3.26E-02 Co-58 810.76 99.45
-2.41E-03 2.92E-02
~.92E-02 1674.73 0.52 8.63E-01 6.35E+OO Co-60 1173.23 99.85
-2.18E-03 3.42E-02 4.08E-02 1332.49 99.98
-l.05E-03 3.42E-02 Nb-94 702.65 99.81
-2.33E-03 2.58E-02 3.16E-02 871.09 99.89
-9.26E-04 2.58E-02 Ag-108rn 79.13 6.60 5.78E-01 3.19E-02 1.40E+OO 433.94 90.50
-4.76E-03 3.19E-02 614.28 89.80
-1.57E-03 3.21E-02 722. 94 90.80
- 1. 41E-02 3.81E-02 Sn-113 255.13 2.11
-5.34E-01 4.56E-02 1.18E+OO 391. 70 64.97 3.24E-03 4.56E-02 Cs-134 475.36
- 1. 48 5.13E-01 3.15E-02 1.98E+OO 563.25 8.34
-1.79E-02 4.34E-01 569.33 15.37 8.70E-02 2.65E-01 604.72 97.62
-l.49E-04 3.15E-02 Page 4 of7 Tolerance Nuclide Caine Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[88]
4/27/2016 12:37:58PM Page 5 of7 Analysis Report for 27-Apr-16-10009 L310223AFRGS004SS (DRIED}
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCl/grams)
(pCi!grams)
(pCi!grams)
Corr Cs-134 795.86 85.46 6.93E-03
- 3. 15E-02
- 4. 60E-02 miss 801.95 8.69
- 1. OlE-01
- 4. 55E-01 miss 1038.61 0.99
-2.24E-01 3.80E+OO miss 1167.97
- 1. 79
-4.54E-01
- 2. 48E+OO miss 1365.19 3.02 O.OOE+OO 3.37E-01 miss
+
Cs-137 661.66 85.10
- 1. 77E-02 4.93E-02
- 4. 93E-02 miss
+
Eu-152 121.78 28.67 2.78E-02 1.04E-01 l.20E-01 miss 244.70 7.61
-1.43E-01 3.33E-01 miss 295.94 0.45 1.12E+Ol l.19E+Ol miss 344.28 26.60
-2.47E-02 1.04E-01 miss 367.79 0.86
-7.69E-01 3.37E+OO miss 411.12 2.24
-7.27E-02 1.18E+OO miss 443. 96 2.83 6.84E-02 1.17E+OO miss 488.68 0.42 2.68E-01 6.31E+OO miss 563.99 0.49
-1.19E+OO 7.04E+OO miss 586.26 0.46
-1.1 lE+OO 6.53E+OO miss 67 8. 62 0.47 7.06E-01 7.03E+OO miss 688.67 0.86
-1.69E+OO 2.98E+OO miss 719.35 0.28
- 1. 1 7E+OO 1.05E+Ol miss 778.90
- 12. 96 5.97E-03 2.61E-01 miss 810.45 0.32
-2.95E+OO
- 7. 65E+OO miss 867.37 4.26
- 1. 41E-01 7.81E-01 miss 919.33 0.43 2.SlE-01 6.26E+OO miss 964.03 14.65 8.42E-02 3.05E-01 miss 1085.87 10.24 6.14E-02 3.39E-01 miss 1089.74
- 1. 73
-3.73E-Ol 1.73E+OO miss 1112.07
- 13. 69
-6.83E-03 2.87E-01 miss 1212.35
- 1. 43
-4.16E-01 2.25E+OO miss 1249.94 0.19 4.27E+OO 2.64E+Ol miss 1299.14
- 1. 63 O.OOE+OO 2.40E+OO miss 1408.01 21.07 2.34E-02 2.19E-01 miss 1457.64 0.50
-8.51E+OO l.53E+Ol miss 1528.10 0.28
-1.86E+OO l.35E+Ol miss t-Eu-154 123.07 40.40 5.26E-03 8.08E-02 8.08E-02 miss 247.93 6.89 6.17E-02 4.lBE-01 miss 591.76 4.95 5.77E-03 4.66E-01 miss 692.42
- 1. 78
-2.38E-01 1.89E+OO miss 723.30 20.06 1.73E-02 1.47E-01 miss 756.80 4.52
-1.63E-01 5.19E-01 miss 873.18 12.08
-l.19E-01 2.14E-01 miss 996.29 10.48 9.69E-03 3.49E-01 miss 1004.76 18.01
-4.02E-02 2.23E-01 miss 1274.43 34.80 2.20E-02 1.23E-01 miss 1596.48
- 1. 80
-4.12E-01 l.73E+OO miss
+
Eu-155 45.30
- 1. 31 2.64E-01 2.04E-01 1.82E+Ol miss 60.01
- 1. 22 8.20E+OO 2.20E+Ol miss 86.55 30.70 1.53E-02 2.0BE-01 miss 105.31 21.10 1.38E-02 2.04E-01 miss
+
Tl-208 583.19 85.00 8.53E-02 4.00E-02 4.00E-02 miss
+
Bi-211 351.07 13.02 8.76E-Ol 2.39E-01 2.39E-01 miss
+
Pb-211 404.85 3.78
-2.lOE-01 6.16E-01 6.16E-01 miss
[89]
4/27/2016 12:37:58PM Page 6 of7 Analysis Report for 27-Apr-16-10009 L310223AFRGS004SS (DRIED)
Nuclide Energy Yield{°/::)
Activity NuclideMDA LineMDA r*
"o:nc Name (keV)
(pCi/grams)
(pCl/grams)
(pCi/grams)
Corr Pb-211 427.09
- 1. 76
-2.78E-03 6.16E-01 1.46E+OO miss 832. 01 3.52 l.27E-02 9.19E-01 miss
+
Bi-212 39.36
- 1. 06 9.16E-01 6.43E-01
- 2. 08E+Ol miss 727.33 6.67 3.31E-01 6.43E-01 miss 785.37
- 1. 10 5.49E-01 3.32E+OO miss 1620.50
- 1. 47 7.27E-02 2.70E+OO miss
+
Pb-212 115.18 0.60 1.27E+OO 1.05E-01 6.44E+OO miss 238.63 43.60 2.08E-01 1.05E-01 miss 300.09 3.30
-3.07E-02 8.48E-01 miss
+
Pb212-~~R 74.82
- 10. 28 1.0lE+OO 7.59E-Ol l.27E+OO miss 77. 11 17.10 6.43E-01 7.59E-01 miss 87.35 3.97 7.44E-01 1. 66E+OO miss 89.78
- 1. 46 6.00E-01 4.20E+OO miss
+
Bi-214 609.J2 45.49 2.77E-01 6.92E-02 6.92E-02 miss 769.36 4.89
- 1. 43E-01 8.28E-01 miss 806.18
- 1. 26
-7.99E-Ol 2.51E+OO miss 934.06
- 3. 11
- 1. 83E-01 1.41E+OO miss 1120.29 14.92 4.63E-01 5.40E-01 miss 1155. 21
- 1. 63 l.86E-01
~.90E+OO miss 1238.12 5.83 l.89E-01 7.88E-01 miss 1280.98
- 1. 43 1.04E+OO 3.53E+OO miss 1377.67 3.99 2.30E-01 l.14E+OO miss 1385.31 0.79 O.OOE+OO 1.29E+OO miss 1401. 52
- 1. 33 6.17E-01 3.lOE+OO miss 1407.99 2.39 2.06E-01 l.93E+OO miss 1509.21 2.13 O.OOE+OO 5.14E-01 miss 1661.27
- 1. 05 l.56E-01 3.87E+OO miss 1729.59 2.88 1.56E-01 l.15E+OO miss 1764.49 15.30 1.98E-01 5.20E-01 miss 1847.43 2.03 2.32E-01 1.71E+OO miss 2118.51 1.16 O.OOE+OO 0.00E+OO miss
+
Pb-214 241. 99 7.25 4.66E-01 8. 74E-02 5.68E-01 miss 295.22 18.42 4.37E-01 2.41E-01 miss 351.93 35.60 3.20E-01 8.74E-02 miss 785. 36
- 1. 06 2.45E-02 3.21E+OO miss
+
Pb214-XR 74.82 5.80 1.78E+OO 1.34E+OO 2.26E+OO miss 77.11 9.70 1.13E+OO 1.34E+OO miss 87.35 2.24 1.32E+OO 2.94E+OO miss 89.78 0.82 l.07E+OO 7.48E+OO miss
+
Ra-226 186.21 3.64 2.89E-01 8.53E-01 8.53E-01 miss
+
Ac-228 12 9. 07 2.42
- 1. 66E-01 3.29E-01 1.SOE+OO miss 209.25 3.89 5.08E-01 9.08E-01 miss 270.24 3.46 6.44E-01 9.98E-01 miss 328. 00 2.95
-1.17E-01
- 1. 03E+OO miss 333.32 11. 27 3.35E-01
- 4. 0lE-01 miss 409.46
- 1. 92 2.43E-01
- 1. 51E+OO miE"S 463. 00 4.40 4.50E-01 9.46E-01 miss 794.95 4.25 3.13E-01 9.23E-01 miss 911. 20 25.80 3.34E-01 3.36E-Ol miss 964.77 4.99 l.54E-01 8.96E-01 miss 968. 97 15.80 1.42E-01 3.29E-01 miss
[90]
Analysis Report for 27-Apr-16-10009
+
+
+
+
+
L310223AFRGS004SS (DRIED)
Nuclide Energy Yield(%)
Activity Name (keV)
(pCilgrams)
Ac-228 1588.20 3.22 3.92E-01 Pa-231 27.36 10.30
-8.49E-01 283.69
- 1. 70
-5.75E-01 300.07 2.47
-4.lOE-02 30~.65 2.20 1.84E-01 330.06
- 1. 40 4.79E-01 Th-234 92.38 2.13
-1.35E-01 92.80 2.10 1.27E+OO 112. 81 0.21 5.02E+OO U-235 143.76 10.96
-7.23E-02 163.33 5.08
-1.56E-01 185. 71 57.20 2.62E-02 202.11
- 1. 08 6.33E-01 205.31 5.01
-8.15E-02 Am-241 59.54 35.90 7.22E-01
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
.,,, MDA value not calculated
"' Half-life too short to be able to perform the decay correction 4/27/2016 NuclideMDA (pCi/grams) 3.29E-Ol 1.13E+OO 2.92E+OO 5.90E-02 8.57E-01
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
12:37:58PM Page 7 of7 LineMDA Coinc (pCi!grams)
Corr l.41E+OO miss 2.26E+OO miss 1.59E+OO miss l.13E+OO miss
- .45E+OO miss 2.41E+OO miss 2.92E+OO miss 3.09E+OO miss 1.95E+Ol miss 3.05E-01 miss 5.02E-01 miss 5.90E-02 miss 2.69E+OO miss 5.00E-01 miss 8.57E-01 miss
[91]
60 55 50 45- -
40
..c 35 C1.
VJ
+-'
s::
- J 8 30 25 20 15 10 5
0 1000
~
..c C1.
~
a, 2000 3000 0000014750.CNF 4000 channel 5000 Live Time :600.000 sec Real Ti me : 601. 050 sec start:
1: -0. l(kev)
Stop : 8192: 2047. O(kev)
Acq. start :wed Apr 27 12: 26: SB 2016 6000 7000 8000
[92]
4/27/2016 1 :04:09PM
~~jl.pex-Gamma Analysis Report for 27-Apr-16-10010 L310223AFRGS005SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10010
- L310223AFRGS005SS (DRIED)
- 1 L 130G Soil Sample 1.810E+03 grams
- Default
- 4/25/2016 1:00:00PM
- 4/27/2016 12:53:33PM
- 130G 1 L Sand Sample
- JWelch
- P11314X2
- 130G Sand
- 600.0 seconds
- 600.4 seconds
- 0.07%
- 2.80
- 120- 8192
- 120 - 8192
- 1.000FWHM
- 1/27/2016
- 11/26/2012
- 14751 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 1 :03:37PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Page I of8
[93]
Analysis Report for 27-Apr-16-10010 L310223AFRGS005SS (DRIED)
Peak Energy ROI No.
(keV) start 1
- 76. 94 306 -
2 238.70 950 -
3 295.17 1176 -
4 351.99 1402 -
5 583.29 2326 -
6 609.55 2429 -
7 911.54 3640 -
8 1461. 30 58 34 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 315 960 1186 1414 2338 2443 3651 5855 4/27/2016 1:04:09PM Peak Net Peak Net Area Centroid Area Uncertainty 308.99 3.24E+Ol 22.54 955.10 l.03E+02 27.47 1180.73 2.97E+Ol 15.72 1407. 77 6.76E+O l 22.46 2332.14
- 2. 72E+Ol 13.44 2437.13 4.35E+Ol 15.80 3644.65 2.24E+Ol 10.88 5844.54 2.14E+02 30.28 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDE$
Nuclide Id Energy Yield(%)
Activity Page 2 of8 Continuum Tentative Counts Nuclide 6.93E+Ol Pb214-;3 Pb21~-Y.~
7.17E+Ol Pb-212 2.66E+Ol Pb-214 Eu-152 5.09E+Ol Pb-214 Bi-211 l.56E+Ol Tl-208 l.SlE+Ol Bi-214 7.18E+OO Ac-228 1.21E+Ol K-40 Activity Coinc Name Confidence (keV)
(pCilgrams)
Uncertainty Corr K-40 0.98 1460.82 10.66 6.59E+OO
- 1. 09E+OO miss Tl-208 0.99 583.19 85.00 5.66E-02 2.88E-02 miss Pb-212
- 1. 00 115.18 0.60 238.63 43.60 2.27E-01 7.06E-02 miss 300.09 3.30 Pb212-XR 0.99 74.82 10.28 77.11 17. 10 3.14E-01 2.28E-01 miss 87.35 3.97 89.78
- 1. 46 Bi-214
- 0. 99 609.32 45.49
- l. 74E-Ol 6.66E-02 miss 768.36
':l. 89 806.18
- 1. 26 934.06 3. 11 1120.29 14.92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43
[94]
Analysis Report for 27-Apr-16-10010 L310223AFRGS005SS (DRIED)
Nuclide Id Energy Name Confidence
{keV)
Bi-214 0.99 1377. 67 1385. 31 1401.52 1407.99 1509.21 1661.27 1729.59 1764.49 1847.43 2118.51 Pb-214
- 1. 00 241.99 295.22 351.93 785.96 Pb214-XR 0.99 74.82 77.11 87.35 89.78 Ac-228 0.99 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964. 77 968. 97 1588.20
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
3.99 0.79
- 1. 33 2.39 2.13
- 1. 05 2.88 15.30
- 2. 03
- 1. 16 7.25 18.42 35.60
- 1. 06 5.80 9.70 2.24 0.82 2.42 3.89 3.46 2.95
- 11. 27
- 1. 92 4.40
- 4. 25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 1:04:09PM Page3of8 Activity Activity Coinc (pCi/grams)
Uncertainty Co" 1.78E-01 9. 84E-02 miss 2.36E-01 8.69E-02 miss 5.53E-01 4.0SE-01 miss 2.08E-01 l.02E-01 miss INTERFERENCE CORRECTED REPORT
[95]
Analysis Report for 27-Apr-16-10010 X
?
?
? =
X L310223AFRGS005SS (DRIED)
Nuclide Name K-,rn Tl-208 Bi-211 Pb-212 Pb212-XR Bi-214 PL,-214 Pb214-XR Ac-228 Nuclide Id Confidence 0.986 0.999 0.949
- 1. 000 0.999 0.999 1.000 0.999 0.998 nuclide is part of an undetermined solution nuclide rejected by the interference analysis
'1/27/2016 1 :04:09PM Wt mean Wt mean Activity Activity (pCilgrams)
Uncertainty 6.59E+OO 1.09E+OO 5.66E-02 2.88E-02 2.27E-01 7.06E-02 3.14E-01 2.28E-01 1.74E-01 6.66E-02 2.lOE-01 6.52E-02 5.53E-01 4.0SE-01 2.08E-01 1.02E-01
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Page 4 of8 Comments
[96]
4/27/2016 1 :04:09PM Analysis Report for 27-Apr-16-10010
+
+
+
+
+
+
+
+
+
L310223AFRGS005SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F ; Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 1 :03:37PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCi/grams)
(pC/lgrams)
(pCi/grams)
K-40 1460.82
- 10. 66 6.59E+OO 4.BOE-01 4.80E-01 Cr-51 320.08 9.91 1.44E-01 2.77E-01 2.77E-01 Mn-54 834.85 99.98
-4.52E-03 2.43E-02 2.43E-02 Co-58 810.76 99.45 9.42E-03 3.19E-02 3.19E-02 1674.73
- 0. 52 O.OOE+OO 1.94E+OO Co-60 1173.23 99.85 2.29E-03 3.98E-02 3.98E-02 1332.49 99.98 4.25E-03 4.60E-02 Nb-94 702.65 99.81 2.0lE-03 2.78E-02 2.83E-02 871.09 99.89 2.22E-03 2.78E-02 Ag-108m 79.13 6.60 9.93E-02 2.52E-02 6.0SE-01 433.94 90.50
- 2. 71E-03 2.52E-02 614.28 89.80
- 1. 22E-03 2.67E-02 722.94 90.80 5.25E-03 3.17E-0~
Sn-113 255.13 2. 11 5.09E-02 3.93E-02 1.05E+OO 391.70
- 64. 97 2.02E-02 3.93E-02 Cs-134 475.36
- 1. 48
- 1. 04E-01
- 3. 3":'E-02 1.65E+OO 563.25 8.34 7.57E-02 3.29E-Ol 569.33 15.37 4.37E-02 1.97E-01 604. 72 97.62 9.23E-03 3.37E-02 Page 5 of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[97]
4/27/2016 1:04:09PM Page 6 of8 Analysis Report for 27-Apr-16-10010 L310223AFRGS005SS (DRIED)
Nuclide Energy Yield{°/o)
Activity Nuclide MDA LineMDA Caine Name (keV)
(pCilgrams)
(pCUgrams)
(pCi!grams)
Corr Cs-134 795.86 85.46 8.72E-03 3.37E-02 4.05E-02 miss 801.95 8.69
-1.26E-02 3.03E-01 miss 1038.61 0.99
-1.76E-01 3.17E+OO miss 1167. 97
- 1. 7()
-6.63E-01 2.22E+OO miss 1365.19 3.02 2.57E-01 l.12E+OO miss
+
Cs-137 661.66 85.10 3.02E-03 3, 59E-02 3.59E-02 mi ss
+
Eu-152 121. 7 8 28.67 2.76E-02 6.91E-02 8.43E-02 miss 244.70 7.61
-7.61E-02 2.80E-01 miss 295.94 0.45
-1.23E-01 7.66E+OO miss 344.28 26.60
-2.31E-02 6.91E-02 mi ~s 367.79 0.86
-7.61E-01 1.95E+OO miss 411. 12 2.24 l.43E-02 1.21E+D0 miss 443. 96 2.83 4.48E-02 8.62E-Ol miss 488.68 0.42
-1.22E+D0 6.21E+OO miss 563.99 0.49
-2.42E+OO 4. 96E+OO miss 586.26 0.46
-3.69E+OO 5.44E+OO miss 678.62 0.47
-1. 38E+OO 3.85E+OO miss 688.67 0.86 1.92E-01 3.46E+D0 miss 719. 35 0.28 l.18E+OO 1.lOE+Ol miss 778.90
- 12. 96
-4.83E-02 l.99E-01 miss 810.45 0.32
-l.31E+OO 9.00E+OO miss 867.37 4.26 7.22E-02 7.lOE-01 miss 919.33 0.43
-1.50E+OO 4.13E+D0 miss 964.08 14.65
-5.36E-D2 l.82E-D1 miss 1085.87 10.24 1.87E-03 2.43E-Ol miss 1089.74
- 1. 73 8.88E-02 2.19E+OO miss 1112. 07
- 13. 69
-6.17E-02 2.99E-01 miss 1212.95
- 1. 43
-8.95E-D1
- 2. 17E+OO.miss 1249.94 0.19 4.44E+D0 2.19E+Ol miss 1299.14
- 1. 63 6.09E-D1 2.78E+OO miss 1408. 01
- 21. 07 5.2DE-03 1.9S.E-01 miss 1457.64 0.50
-5.31E+OO l.14E+Ol miss 1528. 10 0.28 O.OOE+OO 3.26E+OO miss Eu-154 123.07 40.40
-8.33E-03 5. 41E-02 5.41E-02 miss 247.93 6.89
-9.21E-02 3.04E-Ol miss 591.76
- 4. 95
-1. 0lE-01 5.09E-01 miss 692.42
- 1. 78
-5.03E-01 8.22E-01 miss 723.30 20.06 3.57E-02 1.53E-01 miss 756.80
- 4. 52
-1. 0lE-01
- 6. llE-01 miss 873.18 12.08 6.39E-03 2.30E-01 miss 996. 2 9
- 10. 48
-7.06E-02 2.91E-01 miss 1004.76 18.01
-4.0lE-02
- 1. 32E-01 miss 1274.43 34.80
-6.92E-02 9.21E-02 miss 1596. 48
- 1. 80 O.OOE+OO 5.3DE-01 miss
+
Eu-155 45.30
- 1. 31
-2.20E+OO
- 1. 28E-01 5.54E+OO miss 60.01
- 1. 22 2.04E+OO 8.16E+OO miss
- 86. 55 30.:0 6.51E-02 1.35E-01 miss 105.31
- 21. 10
-2.22E-02
- 1. 28E-01 miss
+
Tl-208 583.19
- 85. 00 5.66E-02 3.46E-02 3.46E-02 miss
+
Bi-211 351.07
- 13. 02 6.44E-01
~.66E-01 2.66E-01 miss
+
Pb-211 404.85 3.78
- 1. 71E-Ol 6.33E-01 n.33E-01 miss
[98]
4/27/2016 1 :04:09PM Page 7 of8 Analysis Report for 27-Apr-16-10010 L310223AFRGS005SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi/grams)
(pCi!grams)
(pCi!grams)
Corr Pb-211 427.09
- 1. 76
-8.63E-02 6.33E-01 l.14E+OO miss 832.01 3.52 8.23E-02 7.65E-01 miss
+
Bi-212 39.86
- 1. 06
-6.34E-01 5.79E-01 5.92E+OO miss 727. 33 6.67 2.31E-01 5.79E-01 miss 785.37 1.10
-7.62E-02
- 2. llE+OO miss 1620.50
- 1. 47 8.83E-01 3.17E+OO miss
+
Pb-212 115.18 0.60
-2.89£-01 7.28E-02 4.15E+OO miss 238.63 43.60 2.27E-01 7.28E-02 miss 300.09 3.30 3.81E-01 9.09E-Ol miss
+
Pb212-XR 74.82 10.28 2.35E-01 3.36E-01 5.89E-01 miss 77. 11 17.10 3.14E-Ol 3.36E-01 miss 87.35 3.97 2.49E-Ol 9.57E-01 miss 89.78
- 1. 46
- 1. 09E+OO 2.32E+OO miss Bi-214 609.32 45.49 1.74E-01 6.81E-02 6.81E-02 miss 768.36 4.89 2.31E-01 7.88E-01 miss 806.18
- 1. 26
-4.0SE-01 2.09E+OO miss 934.06 3.11 8.79E-02 9.39E-01 miss 1120.29 14.92 2.25E-01
- 4. llE-01 miss 1155.21
- 1. 63 3.78E-01
- 2. 71E+OO miss 1238.12 5.83 4.39E-01 1.07E+OO miss 1280.98
- 1. 43
-4.06E-01 2.24E+OO miss 1377.67 3.99 5.51E-01 l.18E+OO miss 1385. 31 0.79
- 7. 96E-01 3.69E+OO miss 1401. 52
- 1. 33
-3.08E-01 1.76E+OO miss 1407.99 2.39 4.57E-02 l.75E+OO miss 1509.21 2.13
-1.35E-01 l.16E+OO miss 1661.27
- 1. 05 O.OOE+OO 9.37E-01 miss 1729.59 2.88
-1.14E-01 9.56E-01 miss 1764.49 15.30 1.77E-01 4.13E-01 miss 1847.43 2.03 3.86E-01 1.79E+OO miss 2118.51 1.16 O.OOE+OO O.OOE+OO miss Pb-214 241.99 7.25 2.76E-01 9. 72E-02 4.43E-01 miss 295.22 18.42 l.78E-01 1.28E-01 miss 351.93 35.60 2.36E-Ol
- 9. 72E-02 miss 785.96
- 1. 06
-3.28E-01 2.19E+OO miss f-Pb214-XR 74.82 5.80 4.16E-01 5.93E-01 1.04E+OO miss 77. 11 9.70 5.53E-01 5.93E-Ol miss 87.35 2.24 4.40E-01 l.70E+OO miss 89.78 0.82 l.93E+OO 4.14E+OO miss
+
Ra-226 186.21 3.64 2.84E-01 7.lSE-01 7.lSE-01 miss
+
Ac-228 129.07 2.42 5.02E-Ol l.07E-01
- l. llE+OO miss 209.25 3.89 2.57E-01 7.03E-01 miss 270.24 3.46 2.54E-01 7.81E-01 miss 328.00 2.95 5.13E-01 9.0lE-01 miss 338.32
- 11. 27 3.48E-01 3.45E-Ol miss 409.46
- 1. 92 1.33E-01 1.26E+OO miss 463.00 4.40 3.83E-01 8.23E-01 miss 794.95 4.25
-9.14E-02 7.69E-01 miss 911.20 25.80 2.0BE-01 l.07E-01 miss 964.77 4.99
-l.09E-01 6.52E-01 miss 968.97 15.80 8.94E-02 3.26E-01 miss
[99]
Analysis Report for 27-Apr-16-10010
+
+
+
+
+
L310223AFRGS005SS (DRIED)
Nuclide Energy Yield(%}
Activity Name (keV)
(pCilgrams)
Ac-228 1588.20 3.22 2.33E-01 Pa-231 27.3f; 10.30 0.00E+OO 283.69
- 1. 70 2.66E-01 300.07 2.47 5.08E-01 302.65 2.20
-4.43E-01 330.06
- 1. 40
-7.43E-01 Th-234 92.38 2.13 2.32E-Ol 92.80 2.10
- l. 12E+OO 112. 81 0.21 7.83E-01 U-235 143.76 10.96 9.71E-02 163.33 5.08
-6.95E-02 185. 71 57.20
-2.63E-03 202.11
- 1. 08 5.53E-01 205.31 5.01
-6.26E-02 Am-241 59.54 35.90 5.84E-0~
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
= MDA value not calculated
= Half-life too short to be able to perform the decay correction 4/27/2016 Nuclide MDA (pCilgrams) 1.07E-01 9.46E-02
- l. BlE+OO 4.25E-02 2.78E-01
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
1 :04:09PM Page 8 of8 LineMDA Caine (pCi/grams)
Corr 1.31E+OO miss 9.46E-02 miss l.23E+OO miss l.21E+OO miss 9.25E-01 miss l.28E+OO miss l.81E+OO miss 1.98E+OO miss 1.19E+Ol miss 2.26E-01 miss 3.71E-01 miss 4.25E-02 miss
- 1. 99E+OO miss 3.66E-01 miss 2.78E-01 miss
[100]
60 55 50 45 -
40 I
35
~
+-'
C
=:J 8 30 25 20
>f-
~
15
..c X
~
10 5
0 1000
.... 2 f~wL~.J 2000 3000 0000014751.CNF
~
~
4000 5000 Channel Live Time :600.000 sec Real Till!e :600.430 sec start:
1: -0.2(kev) stop : 8192: 2047.4(kev)
Acq. start :wed Apr 27 12:53:33 2016 6000 7000 8000
[101]
4/27/2016 1 :04:46PM
~§~pex-Gamma Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range {in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10011
- L310223AFRGS006SS (DRIED)
- 1 L 130G Soil Sample
- 1. 776E+03 grams
- Default
- 4/25/2016 12:55:00PM
- 4/27/2016 12:53:47PM
- 130G 1 L Sand Sample
- JWelch
- P408188
, 130G Sand
- 600.0 seconds
- 601.1 seconds
- 0.19 %
- 2.80
- 120 - 8192
- 120 - 8192
- 1.000FWHM
- 1/27/2016
- 1/5/2015
- 14752 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 1 :04:1 SPM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Can berra\\Apex\\Root\\Default\\Libra ry\\Zion Li b-BN L. N LB
- 1.000FWHM Page 1 of8
[102]
4/27/2016 1:04:46PM Page 2 of8 Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS (DRIED)
Peak Energy ROI No.
(keV) start 1
238.62 946 -
2 295.19 1174 -
3 338.22 1349 -
4 351.92 1400 -
5 583.06 2326 -
6 608.97 2428 -
7 1460.54 5834 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 962 1187 1358 1415 2337 2445 5852 Peak Net Peak NetArea Continuum Centroid Area Uncertainty Counts 954.97
- l. 03E+02 35.26 1.29E+02 1181.10 3.87E+O l
- 23. 94 7.46E+Ol 1353.10 2.18E+Ol 1 4.78 3.24E+Ol 1407.85 7.68E+Ol 22.76
- 4. 04E+Ol 2332.01 2.72E+O l 1 4.28 2.16E+Ol 2435.64 8.0lE+Ol 1 8.50 3.74E+OO 5843.14 l.63E+02
- 26. 05 5.43E+OO NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCilgrams)
Uncertainty K-40 0.99 1460.82
- 10. 66 5.69E+OO
- 1. 03E+OO Tl-208 0.99 583.19
- 85. 00 6.39E-02 3.44E-02 Pb-212
- 1. 00 115.18 0.60 238.63 43.60 2.59E-01 9.83E-02 300.09 3.30 Bi-214 0.99 609.32 45.49 3.62E-0l 9.43E-02 768.36 4.89 806.18
- 1. 26 934.06 3. 11 1120.29 14.92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377.67 3.99 1385.31 0.79 1401.52
- 1. 33 1407.99 2.39 1509.21 2.13 1661.27
- 1. 05 Tentative Nuclide Pb-212 Pb-2l<ci Eu-152 Ac-228 Pb-214 Bi-211 Tl-208 Bi-214 K-40 Coinc Corr miss miss miss miss
[103]
Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214 0.99 1729_59 1764.49 1847.43 2118. 51 Pb-214
- 1. 00 241.99 295.22 351.93 785.96 Ac-228
- 1. ()0 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964. 77 968. 97 1588.20
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance: 1.000FWHM Nuclide confidence index threshold ~ 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
2.88 15.30 2.03 1.16 7.25 18.42 35.60
- 1. 06 2.42 3.89 3.46 2.95
- 11. 27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 1:04:46PM Page 3 of8 Activity Activity Caine (pCilgrams)
Uncertainty Co" 2.65E-Ol
- 1. 85E-01 miss INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCilgrams)
Uncertainty K-40
- 0. 995 5.69E+OO 1.03E+OO Tl-208
- 0. 999 6.39E-02 3.44E-02 X
Bi-211 0.957 Pb-212
- 1. 000
- 2. 59E-01 9.83E-02
[104]
Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS (DRIED)
Nuclide Nuclide Name Id Confidence Bi-214 0.997 Pb-214
- 1. 000 Ac-228 1.000
?
= nuclide is part of an undetermined solution X
= nuclide rejected by the interference analysis 4/27/2016 Wt mean Activity (pCilgrams) 3.62E-01 2.93E-01 2.66E-01
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 1 :04:46PM Page4 of8 Wt mean Comments Activity Uncertainty 9.43E-02 8.74E-02
- 1. 85E-01
[105]
4/27/2016 1 :04:46PM Analysis Report for 27-Apr-16-10011
+
+
+
+
+
+
+
+
+
L310223AFRGS006SS (DRIED}
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 1:04:15PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Defau lt\\Library\\Z I ON LI B-BN L. NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCilgrams)
(pCilgrams)
(pCilgrams)
K-40 1460.82 10.66 5.69E+OO 3.85E-01 3.85E-01 Cr-51 320. 08 9.91 9.57E-02 2.74E-Ol 2.74E-01 Mn-54 834.85 99.98 7.73E-03 4.63E-02 4.63E-02 Co-58 810.76 99.45
-1.28E-03
- 2. 3:E-02 2.37E-02 1674.73 0.52 8.13E-01 5.98E+OO Co-60 1173.23 99.85
- 1. 29E-02 4.55E-02 4.80E-02 1332. 49 99.98
- 1. 59E-03 4.55E-02 Nb-94 702.65 99.81
-7.09E-04 3.14E-02 3.60E-02 871.09 99.89 1. 96E-03 3.14E-02 Ag-108m 79.13 6.60 3.73E-01 3.00E-02 l.30E+OO 433.94 90.50 8.BOE-04 3.00E-02 614.28 89.80 1.80E-02 4.0lE-02 722. 94 90.80
-3.56E-03 3.33E-02 Sn-113 255.13 2.11 7.34E-02 4.45E-02 1.32E+OO 391.70 64.97
- 1. 56E-02 4.45E-02 Cs-134 475.36
- 1. 48
-1.lOE-01 3.50E-02 1.96E+OO 563.25 8.34 7.22E-02 4.0BE-01 569.33 15.37 8.45E-02 2.32E-01 604. 72 97.62 1.21E-02 3.50E-02 Page 5 of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[106]
4/27/2016 1:04:46PM Page 6 of8 Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCi/grams)
(pCi!grams)
Corr Cs-134 795.86 85.46 7.69E-03 3.SOE-02 5.02E-02 miss 801.95 8.69 l.19E-03 3.43E-01 miss 1038.61
- 0. 99 2.36E-01 3.58E+OO miss 1167. 97
- 1. 79
-l.27E-01 2.14E+OO miss 1365.19 3.02 O.OOE+OO 3.17E-01 miss
+
Cs-137 661. 66 85.10
- 1. 09E-02 4.06E-02
- 4. 06E-02 miss
+
Eu-152 121.78 28.67
-2.0BE-02 S.82E-02 l.lOE-01 miss 244.70 7.61
-1. 46E-01 3.22E-01 miss 295.94 0.45 5.08E+OO 9.93E+OO miss 344.28 26.60
- 1. 48E-02 9.82E-02 miss 367.79 0.86 9.94E-01 3.17E+OO miss 41 1.12 2.24 2.63E-01 1.27E+OO miss 443. 96 2.83
-1.29E-01 7.03E-01 miss 488.68 0.42
-2.44E+OO 5.52E+OO miss 563.99 0.49 2.55E+OO 7.21E+OO miss 586.26 0.46
-2.88E+OO 5.24E+OO miss 678.62 0.47
-2.62E+OO 5.63E+D0 miss 688.67 0.86 7.31E-Ol
- 3. 91E+OO miss 719. 35 0.28
-1. 28E+O 0 1.16E+Ol miss 778. 90
- 12. 96
-6.24E-02 l.74E-01 miss 810.45 0.32 8.41E-01 7.21E+OO miss 867.37 4.26 1.02E-02 9.19E-01 miss 919.33 0.43
-1. 72E+OO 7.'12E+OO miss 964.08 14.65 6.24E-02 3.19E-01 miss 1085.87 lU.24
-1.14E-01 2.18E-01 miss 1089. 7 4
- 1. 73 5.74E-01 2.79E+OO miss 1112. 07 13.69
-5.03E-02 2.42E-01 miss 1212.95
- 1. 43 3.21E-01 3.22E+OO miss 1249.94 0.19 3.63E+OO 2.64E+Ol miss 1299.14
- 1. 63
-2.70E-01
- l. 54E+OO miss 1408.01
- 21. 07 5.15E-CJ2 1.85E-01 miss 1457.64 0.50
-6.0lE+OO 1.23E+Ol miss 1528.10 0.28 l.27E+OO 1.27E+Ol miss
+
Eu-154 123.07 40. 40
-1.83E-03 7. 83E-02 7.83E-02 miss 247.93 6.89
-7.49E-02 3.76E-01 miss 591.76 4.95 8.97E-02 5.35E-01 miss 692.42
- 1. 78
-l.61E-01 1.36E+OO miss 723. 30 20.06
-9.98E-03 l.51E-01 miss 756.80 4.52
-3.95E-02 6.33E-01 miss 873.18 12.08 -l.44E-02 2.33E-Ol miss 996.29 10.48 1.41E-D1
- 4. llE-01 miss 1004.76 18.01 5.15E-02 2.40E-01 miss 1274.43 34.80
-1.66E-02 8.99E-02 miss 1596.48
- 1. 80
-3.88E-01 1.63E+OO miss
+
Eu-155 45.30
- 1. 31
- 4. 78E+OO
- 1. 76E-01 1.93E+Ol miss 60.01
- 1. 22 9.D4E-01 2.07E+Ol mis['
86.55 30.70 7.00E-03 1.99E-Ol miss 105.31 21.10
-4.72E-02 1.76E-Ol miss
+
Tl-208 583.19 85.00 6.39E-02 4.40E-02 4.40E-02 miss
+
Bi-211 351.07
- 13. 02 8.29E-01 2.87E-Ol 2.87E-01 miss
+
Pb-211 404.85 3.78
-3.29E-02 6.52E-01 6.52E-01 miss
[107]
4/27/2016 1:04:46PM Page 7 of8 Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS {DRIED)
Nuclide Energy Yield{°.Ai)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi/grams)
(pCilgrams)
(pCi/grams)
Corr Pb-211 427.09
- 1. 76
-4.40E-01 6.52E-01 l.29E+OO miss 832.01 3.52
-2.40E-01 l.14E+OO miss
+
Bi-212 39.86
- 1. 06 2.lOE+OO 6.99E-01
- 2. 21E+01 miss 727. 33 6.67 3.59E-01 6.99E-01 miss 785.37
- 1. 10 1.60E+OO 3.86E+OO miss 1620.50
- 1. 47
- 1. D3E-01 2.54E+OO miss
+
Pb-212 115.18 0.60 l.13E+OO 1.27E-01
- 5. 98E+OO miss 238.63 43.60 2.59E-01 l.27E-01 miss 300.09 3.30 4.14E-01 1.04E+OO miss
+
Pb212-XR 74.82 10.2C 4.19E-01 6.94E-01
- 1. llE+OO miss 77.11 17.10 5.91E-01 6.94E-01 miss 87.35 3.97
- 1. 15E+OO l.66E+OO miss 89.78
- 1. 46
-5.67E-03 3.26E+OO miss
+
Bi-214 609.32 45.49 3.62E-01 4.69E-02
~.69E-02 miss 768.36 4.89 l.98E-01 8.56E-01 miss 806.18
- 1. 26 1.79E+OO 3.42E+OO miss 934.06 3.11 3.79E-01 l.33E+OO miss 1120.29 14.92 2.02E-01 4.30E-01 miss 1155. 21
- 1. 63
- l. 41E+OO 3.64E+OO miss 1238.12 5.83
- 5. 77E-01 1.03E+OO miss 1280.98
- 1. 43
-2.36E-01 3.09E+OO miss 1377. 67 3.99 2.36E-Ol 1.07E+OO miss 1385.31 0.79 O.OOE+OO
- 1. 22E+OO miss 1401.52
- 1. 33 3.87E-02 1.99E+OO miss 1407.99 2.39 4.53E-01 1.63E+D0 miss 1509.21 2.13 3.66E-D1 1.93E+OO miss 1661.27
- 1. 05 1.18E+OO 4.22E+OO miss 1729.59 2.88 5.89E-01 1.77E+OO miss 1764.49 15.30 2.35E-01 4.90E-01 miss 1847.43 2.03 8.74E-01 2.63E+OO miss 2118.51 1.16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241.99 7.25 4.37E-01 l. 05E-01 5.55E-01 miss 295.22 18.42 2.65E-01 2.48E-01 miss 351.93 35.60 3.03E-01 1.05E-01 miss 785. 96
- 1. 06 l.73E+OO 3.84E+D0 miss
+
Pb214-XR 74.82 5.80 7.42E-01 1.22E+OO
- 1. 96E+OO miss 77.11 9.70 1.04E+OO
- 1. 22E+OO miss 87.35 2.24 2.04E+OO 2.94E+D0 miss 89.78 0.82 -l.OlE-02 5.8DE+OO miss
+
Ra-226 186.21 3.64 3.62E-01 8.84E-01 8.84E-01 miss
+
Ac-228 129.07 2.42 2.61E-01 2.62E-01
- 1. 31E+OO miss 209.25 3.89 3.63E-01 8.45E-01 miss 270.24 3.46 4.32E-01 9.98E-01 miss 328.00 2.95 3.lOE-01 1.12E+OO miss 338.32 11.27 2.66E-01 2.62E-01 miss 409.46
- 1. 92 5.33E-01 l.59E+OO miss 463.00 4.40 2.84E-01 6.75E-01 miss 794.95 4.25 5.36E-01 l.13E+OO miss 911. 20 25.80 2.94E-01 3.08E-Ol miss 964.77 4.99
- 2. 96E-01 9.79E-Ol miss 968. 97 15.80
- 2. 96E-01 4.28E-01 miss
[108]
4/27/2016 1:04:46PM Page 8 of8 Analysis Report for 27-Apr-16-10011 L310223AFRGS006SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LinP-MDA co;n,;
Name (keV)
(pCi!grams)
(pCi!grams)
(pCi!grams)
Corr Ac-228 1588.20 3.22 2.05E-02 2.62E-Ol l.33E+OO miss
+
Pa-231 27.36 10.30 7.20E-01 1.09E+OO 2.54E+OO miss 283.69
- 1. 70
- l. 13E+OO 1. 94E+OO miss 300.07
- 2. 47 5.53E-Ol l.38E+OO miss 302.65 2.20
-7.22E-Ol l.09E+OO miss 330.06
- 1. 40 2.51E-Ol 2.06E+OO miss
+
Th-234 92.38 2.13 6.94E-01 2.81E+OO 2.81E+OO miss 92.80 2.10 1.58E+OO 2.97E+OO miss 112. 81 0.21 1.66E+OO 1. 62E+Ol miss
+
U-235 143.76
- 10. 96 6.52E-02 5.92E-02 2.73E-01 miss 163.33 5.08 8.60E-02 5.75E-Ol miss 185. 71 57.20 4.33E-02
- 5. 92E-02 miss 202.11
- 1. 08 6.30E-Ol 2.40E+OO miss 205.31 5.01
-2.35E-02 5.02E-01 miss
+
Am-241 59.54 35.90 3.41E-01 7. 62E-01
- 7. 62E-01 miss
+
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
= MDA value not calculated Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[109]
V'l
+-'
C:
60 55 50 40 35 8 30 25 20 15 10 5
1000 2000 3000 0000014752.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :601.120 sec start:
1: -0. l(kev) stop : 8192: 2047. O(kev)
Acq. start :wed Apr 27 1U3:47 2016 6000 7000 8000
[110]
4/27/2016 2:26:15PM
~a~pex-Gam111a Analysis Report for 27-Apr-16-10012 L310223AFRGS007SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10012
- L310223AFRGS007SS (DRIED)
- 1 L 130G Soil Sample 1.726E+03 grams
- Default
- 4/25/2016 12:50:00PM
- 4/27/2016 2:15:38PM
- 130G 1LSand Sample
- JWelch
- P11314X2
- 130G Sand
- 600.0 seconds
- 600.5 seconds
- 0.08%
- 2.80
- 120-8192
- 120 -8192
- 1.000FWHM
- 1/27/2016
- 11/26/2012
- 14753 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 2:25:43PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Page 1 of8
[111]
Analysis Report for 27-Apr-16-10012 L310223AFRGS007SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214
- 1. 00 1407.99 1509.21 1661.27 1729.59 1764.49 18 47.43 2118. 51 Pb-214 0. 99 241.99 295.22 351.93 785. 96 Ra-226 0.99 186.21 Ac-228 0.57 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964. 77 968. 97 1588.20 Th-232 0.98 63.81 U-235 0.99 143.76 163.33 185. 71 202.11 205.31
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction perfomied.
free = No coincidence correction required.
Yield(%)
2.39 2.13
- 1. 05 2.88 15.30 2.03 1.16 7.25 18.42 35.60
- 1. 06 3.64 2.42 3.89 3.46 2.95 11.27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 0.26 10. 96 5.08 57.20
- 1. 08 5.01 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 2:26:15PM Page3 of 8 Activity Activity Coinc (pCilgrams)
Uncertainty Corr 2.68E-01 2. 60E-01 miss 3.49E-01 9.90E-02 miss 9.14E-01
- 4. 96E-Ol miss 3.17E-01 1.91E-01 miss 1. 92E+Ol 2. 0SE+Ol mis s
- 5. 82E-02 3.16E-02 miss INTERFERENCE CORRECTED REPORT
[112]
Analysis Report for 27-Apr-16-1 0012 L310223AFRGS007SS (DRIED)
Nuclide Nuclide Name Id Confidence K-40 0.980 Tl-208 0.998 X
Bi-211 0.943 Pb-212 1.000 Bi-214 1.000 Pb-214 0.999
?
Ra-226 0.994 Ac-228 0.575 Th-232 0.981
?
U-235 0.999
?
= nuclide is part of an undetermined solution X
= nuclide rejected by the interference analysis 4/27/2016 2:26: 15PM Wt mean Wt mean Activity Activity (pCilgrams)
Uncertainty
- 4. 96E+OO 9.17E-Ol l.27E-01 4.16E-02 2.78E-01 9.00E-02 3.05E-01 8.51E-02 3.39E-01 9.25E-02 9.14E-01 4.96E-01 3.17E-01 1.91E-01
- 1. 92E+Ol 2.0SE+Ol 5.82E-02 3.16E-02
= nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Page 4 of8 Comments
[113]
4/27/2016 2:26:1 SPM Analysis Report for 27-Apr-16-10012
+
+
+
+
+
+
+
+
+
L310223AFRGS007SS {DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy {keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 2
- 25:43PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZJON LIB-BNL.NLB Nuclide Energy Yield(%)
Activity Nuc/ideMDA LineMDA Name (keV)
(pCUgrams)
(pCi/grams)
(pCilgrams)
K-40 1460.82 10.66 4. 96E+OO 2.83E-01 2.83E-01 Cr-51 320.08 9.91 7.60E-02 2.61E-Ol 2.61E-01 Mn-54 834.85 99.98
- 6. 71E-03 3.56E-02 3.56E-02 Cc-58 810.76 99.45 3.56E-03 3.56E-02 3.56E-02 1674.73 0.52 7.53E-01 5.54E+OO Co-60 1173.23 99.85
- 7. llE-03 3.86E-02 3.88E-02 1332. 49 99.98 3.56E-03 3.86E-02 Nb-94 702.65 99.81 4.91E-04 1.79E-02 2.7GE-02 871.09 99.89
-6.88E-03 1.79E-02 Ag-108m 79.13 6.60
-5.27E-02 2.78E-02 7.29E-Ol 433.94 90.50
-6.68E-03 2.78E-02 614.28 89.80
-3.42E-03 2.80E-02 722. 94 90.80 1.49E-03 3.09E-02 Sn-113 255.13 2.11 3.78E-01 3.48E-02 1.15E+OO 391.70 64.97 5.86E-03 3.48E-02 Cs-134 475.36
- 1. 48
-4.09E-01 2.75E-02 1.31E+OO 563.25 8.34
-5.94E-02 2.34E-01 569.33 15.37 5.23E-02 1.88E-01 604.72 97.62 5.20E-04 2.75E-02 Page 5 of8 Tolerance Nuclide Caine Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[114]
4/27/2016 2:26:15PM Page 6 of8 Analysis Report for 27-Apr-16-10012 L310223AFRGS007SS (DRIED)
Nuclide Energy Yield{%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCi/grams)
(pCilgrams)
(pCilgrams)
Corr Cs-134 795.86 85.46 6.30E-03 2.75E-02
- 4. 46E-02 miss 801. 95 8.69 9.39E-02
- 3. 97E-01 miss 1038.61 0.99
-7.37E-01
- 2. 03E+OO miss 1167.97
- 1. 79
-1.30E-01 1.98E+OO miss 1365.19 3.02 9.31E-02 l.OlE+OO miss
+
Cs-137 661.66
- 85. 10 6.16E-03 3.56E-02 3.56E-02 miss
+
Eu-152 121.78 28.67 2.96E-02 9.08E-02 9.93E-0'.2 miss 244.70
- 7. 61
-3.74E-02 2.78E-01 miss 295.94 0.45 1.40E+01 1.06E+01 miss 344.28
- 26. 60 1.30E-02 9.0BE-02 miss 367.79 0.86
-1.03E+OO 2.20E+OO miss 411.12 2.24
-1. 43E-02 1.13E+OO miss 443. 96 2.83 8.68E-02 8.14E-01 miss 488.68 0.42 2.49E+OO 7.08E+OO miss 563.99 0.49
-1. llE+OO 3.43E+OO miss 586.26 0.46
-2.36E+OO 6.07E+OO miss 678.62 0.47 2.62E+OO 7.25E+OO miss 688.67 0.86 1.61E-01
- 3. 63E+OO miss 719.35 0.28
-4.64E+OO 8.24E+OO miss 778.90 12.96 4.27E-02 2.76E-01 miss 810.45 0.32 3.09E-01 1.08E+01 miss 867.37 4.26
-3.22E-01 5.27E-01 miss 919.33 0.43 2.61E+OO 7.72E+OO miss 964. 08 14.65 4.14E-02 3.22E-01 miss 1085.87 10.24
-4. 71E-02 2.55E-01 miss 1089.74
- 1. 73
-1.16E-01 1.75E+OO miss 1112.07 13.69 2.98E-02 2.73E-01 miss 1212.95
- 1. 43
-l.97E-Ol 1.97E+OO miss 1249.94 0.19 7.SOE+OO 2.14E+Ol miss 1299.14
- 1. 63 9.80E-01 2.92E+OO miss 1408.01 21.07 3.00E-0'.2 2.08E-01 miss 1457.64 0.50
-1.89E+01 8.21E+OO miss 1528.10 0.28 1.26E+OO 9.30E+OO miss
+
Eu-154 123.07 40.40
-9.80E-03 2. 43E-02 6.60E-02 miss 247.93 6.89
-5.lOE-02 3.19E-01 miss 591.76 4.95
-2.27E-02 5.34E-01 miss 692.42
- 1. 78
-5.86E-02 l.54E+OO miss 723.30 20.06
-2.18E-02
- 1. 2E-01 miss 756.80 4.52
-6.52E-02 6.41E-Ol miss 873.18 12.08 6.12E-02 2.42E-01 miss 996.29 10.43 5.92E-02 3.58E-01 miss 1004.76 18.01 1.14E-01 2.59E-01 miss 1274.43 34.80 O.OOE+OO 2.43E-02 miss 1596.48
- 1. 80
-1.80E-01 1.51E+OO miss
+
Eu-155 45.30
- 1. 31
- 1. 71E+OO l.40E-01 6.15E+OO miss
- 60. 01
- 1. 22
-1.49E+OO 7.48E+OO miss 86.55 30.70 3.39E-02 l.42E-01 miss 105. 31
- 21. 10 1.67E-02 1.40E-01 miss
+
Tl-208 583.19
- 85. 00 1.27E-01 3.85E-02 3.85E-02 miss
+
Bi-211 351.07
- 13. 02 9.54E-Ol 2.06E-01 2.06E-01 miss
+
Pb-211 404.85 3.78
-1. 72E-01
- 5. 72E-01
- 5. 72E-01 miss
[115]
4/27/2016 2:26:15PM Page 7 of8 Analysis Report for 27-Apr-16-10012 L310223AFRGS007SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCi/grams)
(pCilgrams)
(pCilgrams)
Corr Pb-211 427.09
- 1. 76 2.72E-01
- 5. 72E-01 l.71E+OO miss 832.01 3.52
-1.52E-01 7.19E-01 miss
+
Bi-212 39.86
- 1. 06 3.09E+OO 6.49E-01 8.74E+OO miss 727. 33 6.67 3.41E-01 6.49E-Ol miss 785.37 1.10
-6.39E-01 2.90E+OO miss 1620.50
- 1. 47 O.OOE+OO 6.86E-01 miss
+
Pb-212 115.18 0.60
-1.44E-01
- 1. 04E-01 4.00E+OO miss 238.63 43.60 2.78E-Ol 1.04E-01 miss 300.09 3.30 5.25E-01 1.0lE+OO miss
+
Pb212-XR 74.82 10.28 4.70E-01 4.58E-01 7.0lE-01 miss 77.11 17.10 5.57E-01 4.58E-01 miss 87.35 3.97 4.89E-01 1.07E+OO miss 89.78
- 1. 46
- 1. 94E-01 2.40E+OO miss
+
Bi-214 609.32 45.49 3.05E-01 5.77E-02 5.77E-02 miss 768.36 4.89
- 3. 71E-01 8.27E-01 miss 806.18
- 1. 26 2.73E-01 2.74E+OO miss 934.06
- 3. 11 1.75E-01 1.07E+OO miss 1120.29
- 14. 92 2.90E-01 4.62E-01 miss 1155.21
- 1. 6, 1.42E+OO 3.12E+OO miss 1238.12 5.83 2.99E-01 l.06E+OO miss 1280.98
- 1. 43 9.23E-01 2.86E+OO miss 1377. 67 3.99 1.70E-01 1.08Et00 miss 1385. 31 0.79 O.OOE+OO 1.13E+OO miss 1401.52
- 1. 33 O.OOE+OO 6.79E-01 miss 1407.99 2.39 2.64E-Ol 1.83E+OO miss 1509.21 2.13 4.97E-01 l.78E+OO miss 1661.27
- 1. 05 3.63E-01 2.67E+OO miss 1729.59 2.88 2.72E-01 1.26E+OO miss 1764.49 15.30 3.49E-01 5.39E-01 miss 1847.43 2.03 2.02E-01 1.49E+OO miss 2118.51
- 1. 16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241. 9 9 7.25 4.25E-01 7. 53E-02 4.79E-01 miss 295.22 18.42 2.68E-01 4.17E-Ol miss 351.93 35.60 3.49E-01 7.53E-02 miss 785.96
- 1. 06 5.82E-01 3.56E+OO miss
+
Pb214-XR 74.82 5.80 8.32E-01 8.0BE-01 l.24E+OO miss 77.11 9.70 9.82E-01 8.08E-01 miss 87.35 2.24 8.67E-01 1.90E+OO miss 89.78 0.82 3.45E-01 4.28E+OO miss
+
Ra-226 186.21 3.64 9.14E-01 6.71E-01
- 6. 71E-01 miss
+
Ac-228 129.07 2.42
-5.17E-02 2.52E-01 1.06E+OO miss 209.25 3.89 2.41E-01 6.58E-01 miss 270.24 3.46 7.67E-02 7.74E-01 miss 328.00 2.95 2.82E-01 8.97E-01 miss 338.32 11.2'7 3.17E-01 2.61E-01 miss 409.46
- 1. 92 2.12E-01 1.32E+OO miss 463.00 4.40 1.06E-01 5.98E-01 miss 794.95 4.25 3.40E-01 9.35E-01 miss 911. 20 25.80 l.89E-Ol 2.52E-01 miss 964. 77 4.99 3.64E-Ol 1.05E+OO miss 968. 97 15.80 1.85E-01 3.80E-01 miss
[116]
4/27/2016 2:26:iSPM Page 8 of8 Analysis Report for 27-Apr-16-10012 L310223AFRGS007SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCl/grams)
(pCUgrams)
(pCi!grams)
Corr Ac-228 1588.20 3.22 3.42E-01 2.52E-01 l.23E+OO miss
+
Pa-231 27.36 10.30 O.OOE+OO 9.92E-02 9.92E-02 miss 283.69
- 1. 70 3.lOE-01 1.45E+OO miss 300.07 2.47 7.02E-Ol l.36E+OO miss 302.65 2.20 4.19E-Ol l.17E+OO miss 330.06
- 1. 40
-1.29E+OO l.34E+OO miss
+
Th-234 92.38 2.13
- 1. 37E+OO 2. 13E+OO 2.13E+OO miss
- 92. 80 2.10
- 1. 40E+OO 2.17E+OO miss 112. 81 0.21 2.86E+OO l.27E+Ol miss
+
U-235 143.76
- 10. 96 2.35E-02 4.27E-02 2.24E-01 miss 163.33 5.08 3.84E-02 4.48E-01 miss 185.71 57.20 5.82E-02 4.27E-02 miss 202. 11
- 1. 08 2.91E-Ol 2.17E+OO miss 205.31 5.01 1.12E-01
- 4. 72E-01 mis.s
+
Am-241 59.54 35.90
+
-= Nuclide identified during the nuclide identification
- =
- Energy line found in the spectrum
> = MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[117]
V)
-I-'
C:
- s 60 S
C'.I 50 45 40 35 8 30 25 20 15 10 5
1000 2000 3000 0000014753.CNF 4000 channel 5000 Live Time
- 600.000 sec Real Time
- 600. 510 sec start:
1: -0.2(kev)
Stop : 8192 :2047.4(kev)
Acq. start :wed Apr 27 14: 15: 38 2016 6000 7000 8000
[118]
4/27/2016 2:26:52PM Page I of8
~~~pex-Gamma Analysis Report for 27-Apr-16-10013 L310223AFRGS008SS (DRIED)
GAMMA SPECTRUM ANAL YS/S Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10013
- L310223AFRGS008SS (DRIED) 1L 130G Soil Sample 1.684E+03 grams
- Default
- 4/25/2016 1:40:00PM
- 4/27/2016 2:15:48PM
- 130G 1L Sand Sample
- JWelch
- P408188
- 130G Sand
- 600.0 seconds
- 601.0 seconds
- 0.16%
- 2.80
- 120 - 8192
- 120 - 8192
- 1.000FWHM
- 1/27/2016
- 1/5/2015
- 14754 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 2:26:21PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM I;/~
l/-J7-ll/
[119]
Analysis Report for 27-Apr-16-10013 L310223AFRGS008SS (DRIED)
Peak Energy ROI No.
(keV) start 1
238.59 950 -
2 295.08 1177 -
3 338.35 1350 -
4 352.02 1400 -
5 583.14 2327 -
6 609.22 2428 -
7 1460.44 5834 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 960 1186 1358 1414 2337 2444 5851 4/27/2016 2:26:52PM Peak Net Peak Net Area Centroid Area Uncertainty 954.85 8.lOE+Ol 27.82 1180. 67 2.lSE+Ol 15.02 1353. 61 1.36E+Ol 12.83 1408.26 6.95E+Ol 20.36 2332.34 2.50E+Ol 13.88 2436.63 6.84E+Ol 19.16 5842.74
- 1. 01E+02
- 21. 25 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Page 2 of8 Continuum Tentative Counts Nuclide 9.40E+01 Pb-212 2.90E+01 Pb-214 Eu-152 2.88E+Ol Ac-228
- 2. 71E+Ol Pb-214 Bi-211 2.20E+Ol Tl-208 1. 72E+Ol Bi-2 14 1.04E+Ol K-40 Activity Caine Name Confidence (keV)
(pCilgrams)
Uncertainty Corr K-40 0.99 1460.82 10.66
- 3. 71E+OO 8.45E-01 miss Tl-208
- 1. 00 583.19
- 85. 00 6.20E-02 3.52E-02 miss Bi-211
- 0. 94 351.07 13.02 7.92E-01 2.65E-01 miss Pb-212
- 1. 00 115.18 0.60 238.63 43.60 2.16E-01 8.lBE-02 miss 300.09 3.30 Bi-214
- 1. 00 609.32 45.49 3.26E-01 9.95E-02 miss 768.36 4.89 806.13
- 1. 26 934.06
- 3. 11 1120.29 14.92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385. 31 0.79 1401.52
- 1. 33 1407.99 2.39 1509.21 2.13
[120]
Analysis Report for 27-Apr-16-10013 L310223AFRGS008SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214
- 1. 00 1 661. 27 1729.59 1764.49 1847.43 2118.51 Pb-214 0. 99 241.99 295.22 351.93 785. 96 Ac-228
- 1. 00 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964. 77 968. 97 1588.20
- = Energy line found in the spectrum.
- -= Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
- 1. 05 2.88 15.30 2.03 1.16 7.25
- 18. 42 35.60
- 1. 06 2.42 3.89 3.46 2.95
- 11. 27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 2 :26:52PM Page 3 of8 Activity Activity Coinc (pCilgrams)
Uncertainty Corr
- l. 67E-01 miss INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCi/grams)
Uncertainty K-40 0.991 3.71E+OO 8.45E-01 Tl-208
- 1. 000 6.20E-02 3.52E-0:2 Bi-211 0.946 3.68E-Ol 4.02E-01
[121]
Analysfs Report for 27-Apr-16-10013 L310223AFRGS008SS (DRIED)
Nuclide Nuclide Name Id Confidence Pb-212
- 1. 000 Bi-214 1. 000 Pb-214 0.999 Ac-228 1. 000
?
= nuclide is part of an undetermined solution X = nuclide rejected by the interference analysis 4/27/2016 Wt mean Activity (pCi/grams) 2.16E-01 3.26E-01 1.55E-01 1.75E-01
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 2:26:52PM Page4 of8 Wt mean Comments Activity Uncertainty 8.18E-02 9.95E-02
- 1. llE-01 1.67E-01
[122]
4/27/l016 2:26:52PM Analysis Report for 27-Apr-16-10013
+
+
+
+
+
+
+
+
+
L310223AFRGS008SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV)
All peaks were identified.
M "' First peak in a multiplet region m "'Other peak in a multiplet region F "' Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 2:26:21PM
- 120
- 8192 Peak CPS ("/a)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCi/grams)
(pCilgrams)
(pCi/grams)
K-40 1460.82 10.66 3.71E+OO 5.20E-01 5.20E-01 Cr-51 320.08 9.91
-l.08E-01 2.23E-01 2.23E-01 Mn-54 834.85 99.98
-3.59E-03 2.50E-02 2.50E-02 Co-58 810.76 99.45
-4.49E-03 2.SOE-02 2.SOE-02 1674.73 0.52 1.36E+OO 9.23E+D0 Co-60 1173.23 99.85
-7.38E-03 3.63E-02 3.63E-02 1332.49 99.98
-4.18E-03 3.94E-02 Nb-94 702.65 99.81 9.73E-03 2.56E-02 3.14E-02 871.09 99.89
-4.60E-04 2.56E-02 Ag-108m 79.13 6.60
-3.68E-01 2.49E-02 l.22E+OO 433.94 90.50
- 1. 77E-03 3.58E-02 614.28 89.80
- 2. 11 7.26E-02 3.52E-02 l.27E+OO 391.70 64.97
-l.lOE-02 3.52E-02 Cs-134 475.36
- 1. 48 4.66E-02 3.65E-02 l.97E+OO 563.25 8.34
-2.97E-02 2.97E-01 569.33 15.37 2.70E-03 l.90E-01 604.72 97.62
-1.68E-03 3.86E-02 Page 5 of8 Tolerance Nuclide Caine Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[123]
4/27/2016 2:26:52PM Page 6 of8 Analysis Report for 27-Apr-16-10013 L31D223AFRGS008SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCilgrams)
(pCVgrams)
(pCi!grams)
Corr Cs-134 795.86 85.46
-4.31E-03 3.65E-02 3.65E-02 miss 801. 95 8.69 5.26E-02 4.24E-01 miss 1038.61 0.99
-5.76E-01 3.38E+OO miss 1167.97
- 1. 79 5.36E-02 2.25E+OO miss 1365.19 3.02 O.OOE+OO 3.35E-01 miss
+
Cs-137 661.66 85.10 1.02E-02 4. 70E-02 4.70E-02 miss
+
Eu-152 121.78 28.67
-1. 28E-02 9.58E-02 l.05E-01 miss 244.70 7.61
-5.46E-02 2.81E-01 miss 295.94 0.45
-9.89E-02 8.37E+00 miss 344.28 26.60
-2.00E-02 9.58E-02 miss 367.79 0.86
-3.48E-01 3.09E+OO miss 411.12 2.24
- l. 39E-01 l.29E+OO miss 443. 96 2.83 9.26E-02 9.79E-01 miss 488.68 0.42 6.33E-01 7.0SE+OO miss 563.99 0.49 2.94E-01 5.04E+OO miss 586.26 0.46
-5.52E-02 8.0lE+OO miss 678. 62 0.47
-1.04E+OO 8.24E+OO miss 688.67 0.86 1.46E+OO 4.57E+OO miss 719.35 0.28 4.64E+OO 1.45E+Ol miss 778.90 12.96
-7.57E-02 l.45E-01 miss 810.45 0.32
-l.82E-01 8.81E+OO miss 867.37 4.26 3.94E-02 6.95E-01 miss 919.33 0.43 2.23E-01 7.20E+OO miss 964. 08 14.65 7.74E-02 2.85E-01 miss 1085.87
- 10. 24
-1.43E-01 2.30E-01 miss 1089.74
- 1. 73 6.09E-01
- 2. 78E+OO mi ss 1112.07
- 13. 69 3.90E-02 2.85E-01 miss 1212.95
- 1. 43
- 1. 61E-01 2.60E+OO miss 1249.94 0.19 6.36E+OO 2.94E+Ol miss 1299.14
- 1. 63
-5.38E-01 2.06E+OO miss 1408.01 21.07
-2.59E-03 1.33E-01 miss 1457.64 0.50
-1. 87E+01 1.24E+Ol miss 1528. 10 0.28 O.OOE+OO 3.90E+OO miss
+
Eu-154 123. 07 40.40
-1.60E-02 7.28E-02 7.28E-02 miss 247.93 6.89
- 1. 71E-01 4.06E-01 miss 591.76 4.95 1.14E-01 6.82E-01 miss 692.42
- 1. 78
-5.77E-01 9.80E-01 miss 723. 30 20.06 1.37E-02
- 1. 46E-01 mi ss 756.80 4.52 2.60E-01 1.0lE+OO miss 873.18 12.08
-3.81E-02 2.75E-01 miss 996. 2 9 10.48
-6.09E-02
- 3. llE-01 miss 1004.76 18.01 O.OOE+OO 1.24E-01 miss 1274.43 34.80 1.24E-02 9.48E-02 miss 1596.48
- 1. 80 4.67E-01 2.17E+OO miss
+
Eu-155 45.30
- 1. 31
-4.97E+OO
- 1. 80E-01 1.93E+Ol miss 60.01
- 1. 22
-4.,4E+OO 1.88E+Ol miss 86.55 30.70
-1.81E-02 1.80E-01 miss 105.31 21.10 4.98E-02 1.97E-01 miss
+
Tl-208 583.19 85.00 6.20E-02 4.59E-02 4.59E-02 miss
+
Bi-211 351.07 13.02 7.92E-01 2.50E-01 2.50E-Ol miss
+
Pb-211 404.85 3.78 3.66E-02 5.59E-01 7.22E-01 miss
[124]
4/27/2016 2:26:52PM Page 7 of&
Analysis Report for 27-Apr-16-10013 L310223AFRGS008SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCi/grams)
(pCilgrams)
(pCilgrams)
Corr Pb-211 427.09
- 1. 76
-4.33E-01 5.59E-01 l.45E+OO miss 832. 01 3.52
-1.0lE-01
.:i.59E-01 miss
+
Bi-212 39.86
- 1. 06
-4.72E+OO 6.65E-01 1.89E+Ol miss 727.33 6.67 2.96E-01 6.65E-01 miss 785.37 1.10
-8. 17E-01 2.17E+OO miss 1620.50
- 1. 47
-2.89E-01 2.68E+OO miss
+
Pb-212 115.18 0.60 4.26E-01 l.OOE-01 5.89E+OO miss 238.63 43.60 2.16E-01 l.OOE-01 miss 300.09 3.30 4.44E-01 l.02E+OO miss
+
Pb212-XR 74.82 10.28 4.18E-01 6.16E-01 l.16E+OO miss 77.11 17.10 3.75E-02 6.16E-01 miss 87.35 3.97 2.95E-01 1.47E+OO miss 89.78
- 1. 46 l.89E+OO 3.75E+OO miss
+
Bi-21 4 609.32 45.49 3.26E-01 8.88E-02 8.88E-02 miss 768.36 4.89 4.32E-01 9.75E-01 miss 806.18
- 1. 26
-6.90E-02 2.49E+OO miss 934.06 3.11 2.68E-01 1.40E+OO miss 1120.~9 14.92 2.06E-01 4.40E-01 miss 1155. 21
- 1. 63 6.19E-01 2.45E+OO miss 1238.12 5.83
-1.40E-01 9.95E-01 miss 1280.98
- 1. 43 3.55E-01 2.31E+OO miss 1377. 67 3.99 4.52E-01 1.33E+OO miss 1385.31 0.79
- 1. 41E+OO 5.70E+OO miss 1401.52
- 1. 33
-9.52E-02 3.08E+OO miss 1407.99 2.39
-2.28E-02 1.17E+OO miss 1509.21 2.13 3.06E-01 2.03E+OO miss 1661.27
- 1. 05 8.27E-01 3.84E+OO miss 1729.59 2.88 3.lOE-01 1.44E+OO miss 1764.49 15.30 3.92E-01 5.96E-01 miss 1847.43 2.03 5.76E-02 l.70E+OO miss 2118. 51
- 1. 16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241. 99 7.25 6.14E-01 9. 15E-02 6.06E-01 miss 295.22 18.42 1.55E-01 1.60E-01 miss 351.93 35.60 2.89E-Ol 9.15E-02 miss 785.96
- 1. 06
-1.62E+OO 1.79E+OO miss
+
Pb214-XR 74.82 5.80 7.40E-01
- 1. 09E+OO 2.05E+DO miss 77.11 9.70 6.61E-02 1.09E+OO miss 87.35 2.24 5.22E-01 2.60E+OO miss 89.78 0.82 3.37E+OO 6.67E+OO miss
+
Ra-226 186.21 3.64 2.38E-01 8.91E-01 8.91E-01 miss
+
Ac-228 129.07 2.42 8.70E-01 2.29E-01
- 1. 47E+OO miss 209.25 3.89 3.22E-01 7.79E-01 miss 270.24 3.46 1.93E-01 8.90E-01 miss 328.00 2.95 2.36E-01 1.03E+OO miss 338.32
- 11. 27 l.75E-01 2.57E-01 miss 409.46
- 1. 92 3.13E-02 1.56E+OO miss 463.00 4.40 4.17E-01 8.47E-01 miss 794.95 4.25 7.12E-02 8.60E-01 miss 911.20 25.80
- 1. 02E-01 2.29E-01 miss 964.77 4.99 2.09E-01 7.77E-Ol miss 968. 97 15.80
- 3. llE-01 4.41E-Ol miss
[125]
4/27/2016 2:26:52PM Page 8 of8 Analysis Report for 27-Apr-16-10013 L310223AFRGS008SS (DRIED)
Nuclide Energy Yield(%)
Activity Nuc/ideMDA LineMDA Coint; Name (keV)
(pCi/grams)
(pCi/grams)
(pCi/grams)
Corr Ac-228 1588.20 3.22
- 1. 30E-01 2.29E-01 l.21E+OO miss
+
Pa-231 27.36 10.30
-4.66E-01 1.23E+OO 1.8CE+OO miss 283.69
- 1. 70
-5.30E-01 1.48E+OO miss 300.07 2.47 5.93E-01 l. 36E+OO miss 302.65
'.2.20
-4. 27E-02 l.23E+OO miss 330.06
- 1. 40
-1.59E-01 1. 92E+OO miss
+
Th-234 92.38 2.13 1.97E+OO 2. 93E+OO
- 2. 93E+OO miss 92.80 2.10 3.17E+OO 3.13E+OO miss 112. 81 0.21
-8.65E-03
- 1. 68E+Ol miss
+
U-235 143.76 10.96
-6.91E-03 5.BOE-02 2.72E-01 miss 163.33 5.08
-9.14E-02 4.56E-01 miss 185.71 57.20 2.03E-02 5.80E-02 miss 202.11
- 1. 08 5.92E-01 2.76E+OO miss 205.31 5.01
-2.44E-01 4.47E-01 miss
+
Am-241 59.54 35.90 2.28E-01 7.40E-01 7.40E-01 miss
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> = MDA value not calculated
~ Half-life too short to be able to perform the decay correction
? = CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[126]
60 55 50 40 35 Vl
.µ C:
- J 8 30
~
9
..Q 25 20 15 10 i
5 G
1000
.... 9 00
- &i 2000 3000 0000014754.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :600.990 sec start:
1: -0.l(kev) stop : 8192: 2047. O(kev)
Acq. start : wed Apr 2 7 14: 15: 48 2016 6000 7000 8000
[127]
4/27/2016 2:55:13PM Analysis Report for 27-Apr-16-10014 L310223AFRGS009SS (ORI ED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10014
- L310223AFRGS009$$ (DRIED)
- 1 L 130G Soil Sample 1.637E+03 grams
- Default
- 4/25/2016 1:45:00PM
- 4/27/2016 2:44:33PM 130G 1 L Sand Sample JWelch P11314X2 130G Sand 600.0 seconds 600.4 seconds
- 0.06%
- 2.80
- 120- 8192
- 120-8192
- 1.000FWHM
- 1/27/2016
- 11/26/2012
- 14755 PEAK WITH N/0 REPORT Peak Analysis Performed on
- 4/27/2016 2:54:41PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance C:\\Can berra\\Apex\\Root\\Default\\Llbrary\\Zion Li b-BN L. NLB
- 1.000FWHM Page I of7
[128]
4/27/2016 2:55:13PM Page 2 of7 Analysis Report for 27-Apr-16-10014 L310223AFRGS009SS (DRIED)
Peak Energy ROI No.
(keV) start l
238.63 950 -
2 352.05 1401 -
3 583.53 2328 -
4 609.69 2432 -
5 14 61. 35 5834 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 961 1413 2338 2443 5855 Peak Net Peak Net Area Continuum Centroid Area Uncertainty Counts 954.84 6.62E+Ol
- 24. 67 6.35E+Ol 1408.00 4.26E+Ol
- 16. 32 2.08E+Ol 2333.12 2.12E+Ol
- 12. 32 l.57E+Ol 2437.67 4.38E+O l 1 4. 91 1.05E+Ol 5844.74 1.25E+02
- 23. 02 5.90E+OO NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Activity Name Confidence (keV)
(pCilgrams)
Uncertainty K-40 0.98 1460.82 10.66 4.26E+OO 8.67E-01 Tl-208 0.99 583.19 85.00 4.87E-02 2.89E-02 Bi-211 0.94 351.07
- 13. 02 4.49E-Ol
- 1. 87E-01 Pb-212
- 1. 00 115. 18 0.60 238.63 43.60 1.61E-01 6.54E-02 300.09 3.30 Bi-214 0.99 609.32 45.49 1.94E-01 7.00E-02 768.36 4.89 806.18
- 1. 26 934.06
- 3. 11 1120.29 14.92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385. 31 0.79 1401. 52
- 1. 33 1407.99 2.39 1509.21 2.13 1661. 27
- 1. 05 1729.59 2.88 1764.49 15.30 Tentative Nuclide Pb-212 Pb-214 Bi-2 11 Tl-208 Bi-214 K-40 Coinc Corr miss miss miss miss miss
[129]
Analysis Report for 27-Apr-16-10014 L310223AFRGS009SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214 0.99 1847.43 2118. 51 Pb-214
- 1. 00 241.99 295.22 351.93 785.96
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold= 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
2.03
- 1. 16 7.25 18.42 35.60
- 1. 06 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 2:55:13PM Page 3 of7 Activity Activity Coinc (pCilgrams)
Uncertainty Corr
?
Bi-211 Pb-~12 Bi-214
?
Pb-214 Nuclide Id Confidence 0.983 0.993 0.942
- 1. 000 0.997
- 1. 000
?
=
nuclide is part of an undetermined solution X
-; nuclide rejected by the interference analysis Wt mean Activity (pCilgrams) 4.26E+OO 4.87E-02 4.49E-01 1.61E-01 1.94E-01 1.64E-01
=
nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Wt mean Comments Activity Uncertainty 8.67E-01 2.89E-02 l.87E-01 6.54E-02 7.00E-02 6.82E-02
[130]
4/27/2016 2:55: 13PM Analysis Report for 27-Apr-16-10014
+
+
+
+
+
+
+
+
+
L310223AFRGS009SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy {keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 2:54:41 PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZJON LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCi/grams)
(pCilgrams)
(pCl/grams)
K-40 1460.82 10.66 4.26E+OO 3.97E-01 3.97E-01 Cr-51 320.08 9.91 6.39E-02 2.67E-01 2.67E-01 Mn-54 834.85 99.98 5.00E-03 2.32E-02 2.32E-02 Co-58 810.76 99.45 O.OOE+OO 6.77E-03 6.77E-03 1674.73 0.52 0.00E+OO 2.15E+OO Co-60 1173.23 99.85
-5.50E-03 3.36E-02 3.36E-02 1332.49 99.98 7.59E-03 3.65E-02 Nb-94 702.65 99.81 5.43E-03 2.39E-02 2.39E-02 871.09 99.89 1.05E-02 3.36E-02 Ag-108m 79.13 6.60
-1.29E-01 2.31E-02 5.79E-01 433.94 90.50
-3.52E-04 2.64E-02 614.28 89.80 l.35E-03 2, 96E-02 722.94 90.80
-1.04E-02 2.31E-02 Sn-113 255.13 2. 11 2.07E-01 3.85E-02 l.19E+OO 391.70 64.97
-9.91E-03 3.85E-02 Cs-134 475.36
- 1. 48
-6.21E-01 2.90E-02 8.47E-01 563.25 8.34 7.99E-02 3.44E-Ol 569.33 15.37 O.OOE+OO 3.39E-02 604. 72
- 97. 62 4.86E-03 2.90E-02 Page 4 of7 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[131]
4/27/2016 2:55:13PM Page 5 of 7 Analysis Report for 27-Apr-16-10014 L310223AFRGS009SS (DRIED)
Nuclide Energy Yield(%)
Activity Nuclide MDA LineMDA Coinc Name (keV)
(pCJ/grams)
(pCl/grams)
(pCl!grams)
Corr Cs -13 4 795. 86 85.46
- 1. 4 6E- 02 2. 90E- 02
- 3. 04E-02 miss 801. 95 8.69
- 3. 57E- 02
- 3. OOE- 01 miss 1 038. 61 0.99 7. 12E- 01
- 3. 14E+ OO miss 1167. 97
- 1. 79 7. 45E- 01 2.76E+OO miss 1365. 19 3.02 3. 44 E-0 1
- _. 23E+OO miss
+
Cs-137 661. 66 85.10 3. 75E- 03 3.76E- 02 3. 76E-02 miss
+
Eu-152 121. 78 28. 67 2. 82E- 03 4. 54E- 02
- 7. 66E- 02 miss 244. 70 7.61
-1. 38E- 01
- 2. 67E- 01 miss 295. 94 0. 45 1. 52E+OO
- 7. 09E+ OO miss 344. 28 26.60
-2. 20E- 03 7.17E- 02 miss 367. 79 0. 86
-2. 43E-01 2.16E+OO miss 411.12
- 2. ::!4
-2.61E- 01 l.09E+OO miss 443. 96 2. 83
-2. 52E-01 6. lSE-01 miss 488. 68 0.42
- 1. 81E+OO 6.18E+OO miss 563. 99 0. 49 2.41E+OO 6. 17E+OO miss 586. 26 0.46
-3.34E+OO
- 6. 4 OE+OO miss 678. 62 0. 47
- 3. 06E- 01 4. 94E+OO miss 688. 67 0.86
- 1. l 7E- 01 3.06E+OO miss 719. 35 0. 28
- 4. 65E+OO 1. 21E+Ol miss 778. 90
- 12. 96
- 1. 22E- 02
- 1. 97E- 01 miss 810. 45 0. 32 O.OOE+OO 2.06E+OO miss 867. 37 4.26
-4.99E- 02 4.41E-Ol miss 919. 33 0. 43 3.52E- 01 8. 14E+OO miss 964. 08 14.65
- 1. l 7E-02 2.25E- 01 miss 1085. 87 10.24
- l.70E- 01 2. 13E- 01 miss 1089. 74
- 1. 73
- 1. 06E- 01
- 1. 85E+OO miss 1112. 07 13.69 -3. 46E- 02 2. 64E- 01 mi ss 1212. 95
- 1. 43 2. 87E-01 2.68E+OO miss 1249. 94 0. 19
- 1. 23E+OO 1. 60E+Ol miss 1 299. 14
- 1. 63 9. 75E- 01 3.08E+OO miss 1408. 01
- 21. 07 O. OOE+OO 4. 54E- 02 miss 1 457. 64 0. 50
-6. 90E+OO 8.66E+OO miss 1528. 10 0.28 O.OOE+OO 3.61E+OO miss
+
Eu-154 123. 07 40. 40 3.42E- 03 5.65E-02 5.65E- 02 miss 247. 93 6.89
- 1. 36E- 01
- 1. 90E - 01 miss 591. 76 4. 95
-9. 97E- 02 4. 79E- 01 miss 692. 42
- 1. 78 3.87E-01 1. 62E+OO miss 723. 30 20. 06
-8. 83E- 02 8. 29E- 02 miss 756.80 4. 52
- 1. 29E- 01 6. 19E- 01 miss 873.18 12. 08 l. 77E-03 2. 55E-01 miss 996. 29 10. 48
-3. 34E-03 3.21E- 01 miss 1004.76 18.01 5.22E- 03 1.69E- 01 miss 1274. 43 34.80 2.39E-02
- 1. 02E- 01 miss 1596. 48
- 1. 80 3.52E- 01 2. 0lE+OO miss
+
Eu-155 45.30
- 1. 31 9.56E- 01 1.12E- 01 6.12E+OO mi~s 60.01
- 1. 22
- 2. 18E+OO 6.14E+OO miss 86.55 30.70 3. 24E- 02 l.2 9E- 01 miss 105.31 21.10 3.98E- 02 1.12E-01 miss
+
Tl-208 583.19 85.00 4.87E- 02
- 3. 72E- 02 3.72E- 02 miss
+
Bi - 211 351. 07 13. 02 4. 49E-01 1.98£- 01 1. 98E- 01 miss
+
Pb - 211 404. 85 3.78 -l.42E-01 5.66E-01 5. 66E-01 miss
[132]
4/?.7/2016 2 :55:13PM Page 6 of7 Analysis Report for 27-Apr-16-10014 L310223AFRGS009SS (DRIED)
Nuclide Energy Yield{°/o)
Activity Nuclide MDA LineMDA Caine Name (keV)
(pCi/grams)
(pCi/grams)
(pCi/grams)
Corr Pb-211 427.09
- 1. 76 9.31E-02 5.66E-01 l.17E+OO miss 832.01 3.52 2.29E-01 8.46E-01 miss
+
Bi-212 39.86
- 1. 06
-3.07E-01 4.79E-01 6.82E+OO miss 727.33 6.67
-8.SOE-03
- 4. 79E-01 miss 785.37 1.10
-5.78E-01 1.59E+OO miss 1620.50
- 1. 47 O.OOE+OO 7.24E-01 miss
+
Pb-212 115.18
- 0. 60 4.90E-01 8.07E-02
- 3. 62E+OO miss 238.63 43.60
- 1. 61E-01 8.07E-02 miss 300.09 3.30 4.03E-01 B.39E-01 miss
+
Pb212-XR 74.82 10.28 4.31E-01 3.65E-01 6.71E-01 miss 77.11
- 17. 10 3.68E-01 3.65E-01 miss 87.35 3.97
- 3. 1 8E-01
- 9. 96E-01 miss 89.78
- 1. 46
-7.99E-01 2.02E+OO miss
+
Bi-'.214 609.32 45.49
- 1. 94E-01 6.20E-02 6.20E-02 miss 768.36 4.89
-3.60E-02 4.46E-01 miss 806.18
- 1. 26
-9.61E-02 2.52E+OO miss 934.06
- 3. 11
-1.51E-01 8.02E-01 miss 1120.29
- 14. 92 3.lOE-01 4.66E-01 miss 1155.21
- 1. 63 5.40E-02 2.03E+OO miss 1238.12 5.83 4.22E-01 9.22E-01 miss 1280.98
- 1. 43 6.58E-02 2.76E+OO miss 1377.67 3.99
-9.95E-02 1.05E+OO miss 1385. 31 0.79 O.OOE+OO 1.19E+OO miss 1401.52
- 1. 33 3.02E-01 2.46E+OO miss 1407.99 2.39 O.OOE+OO 3.99E-01 miss 1509.21 2.13 O.OOE+OO 4.73E-01 miss 1661.27
- 1. 05 9.57E-02 2.82E+OO miss 1729.59 2.88 2.87E-01 1.33E+OO miss 1764.49 15.30 1.65E-01 3.87E-01 miss 1847.43 2.03
-1.07E-01 1.57E+00 miss 2118. 51 1.16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241.99 7.25 5.77E-02 7.25E-02 3.83E-01 miss 295.22 18.42
- 1. 13E-01 1.87E-01 miss 351.93 35.60 1.64E-01 7.25E-02 miss 785. 96
- 1. 06 3.75E-02 2.09E+OO miss
+
Pb214-XR 74.82 5.80 7.64E-01 6.44E-01 1.19E+OO miss 77. 11 9.70 6.48E-01 6.44E-01 miss 87.35 2.24 5.64E-01 1.76E+OO miss 89.78 0.82
-1.42E+OO 3.61E+OO miss
+
Ra-226 186.21 3.64
- 1. llE-01 6.38E-01 6.38E-01 miss
+
Ac-228 129.07 2.42 2.21E-01 2.46E-01 9.15E-01 miss 209.25 3.89 1.36E-01 5.56E-01 miss 270.24 3.46 1.14E-01 7.28E-01 miss 328.00 2.95
-1.66E-01 6.66E-01 miss 338.32 11. 27 2.37E-01 3.29E-01 miss 409.46
- 1. 92 1.46E-01 1.44E+OO miss 463.00 4.40 1.89E-01
- 4. 96E-01 miss 794.95 4.25
- 1. 33E-01 8.SOE-01 miss 911. 20 25.80
- 1. 87E-01 2.46E-01 miss 964. 77 4.99 7.33E-02 7.21E-01 miss 968.97 15.80
- 1. 28E-01 3.03E-Ol miss
[133]
4/27/2016 2:55:13PM Page 7 of7 Analysis Report for 27-Apr-16-10014 L310223AFRGS009SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCUgrams)
(pCilgrams)
Corr Ac-228 1588.20 3.22
-l.55E-01 2.46E-01 8.85E-01 miss
+
Pa-231 27.36 10.30 O. OOE+OO
- 1. 0SE-01 1.0SE-01 miss 283.69
- 1. 70 6.73E-01 1. 64E+OO miss 300.07 2.47 5.38E-01 l.12E+OO miss 302.65 2.20 2.74E-01 9.83E-01 miss 330.06
- 1. 40
-2.32E-01 l.49E+OO miss
+
Th-234 92.38 2.13
-1.89E-01
- 1. 72E+OO 1.72E+OO miss 92.80 2.10 6.94E-01
- l. 83E+OO miss 112. 81 0.21
-3.77E+OO 1.02E+Ol miss
+
U-235 143.76 10. 96
-2.41E-02 4.13E-0~
- 1. 76E-01 miss 163.33 5.08 1.24E-01 3.70E-Ol miss 185.71 57.20 7.83E-03 4.13E-02 miss 202.11
- 1. 08 1.45E-Ol 1.G3E+OO miss 205.31 5.01
-7.32E-02 3.54E-01 miss
+
Am-241 59.54 35.90 2.04E-02 2.29E-01 2.29E-01 miss
+ = Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> = MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[134]
Vl
+-'
C
- I 60 55 50 40 35 8 30 25 20 15 10
~
I 1000 2000 3000 0000014755.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :600.370 sec start:
1: -0. 2(kev) stop : 8192: 2047.4(kev)
Acq. Start :wed Apr 27 14:44: 33 2016 6000 7000 8000
[135]
4/27/2016 2:55:49PM Page 1 of8
~pex-Gamma Analysis Report for 27-Apr-16-10015 L310223AFRGS01 OSS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10015
- L310223AFRGS010SS (DRIED)
- 1 L 130G Soil Sample 1.894E+03 grams
- Default
- 4/25/2016 1 :50:00PM
- 4/27/2016 2:44:43PM
- 130G 1LSand Sample JWelch
- P40818B
- 130G Sand
- 600.0 seconds
- 601.0 seconds
- 0.17 %
- 2.80
- 120- 8192
- 120- 8192
- 1.000FWHM
- 1/27/2016
- 1/5/2015
- 14756 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 2:55:19PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C :\\Ca nberra\\Apex\\Root\\Defau lt\\Library\\Zi on Li b-BN L.N LB
- 1.000FWHM
&J~
4-07-/0
[136]
4/27/2016 L:55:49PM Analysis Report for 27-Apr-16-10015 M
m M
m L310223AFRGS010SS (DRIED)
PHk Energy ROI No.
(keV) start 1
74.70 295 -
2 77.12 295 -
3 238.61 948 -
4 295.25 1173 -
5 300.03 1173 -
6 338. 17 1346 -
7 351.92 1400 -
8 583. 17 2325 -
9 609. 18 2429 -
10 910.90 3636 -
11 968. 63 3868 -
12 1120. 51 4477 -
13 1460.42 5832 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 316 316 961 1206 1206 1359 1415 2339 2443 3651 3880 4488 5852 Peak NetPeak Net Area Centroid Area Uncertainty 299.89 3.91E+Ol l8.45 309.56 5.47E+Ol 1 9. 90 954.94 2.33E+02 4c5.21 1181. 34 9.36E+O l
- 20. 67 1200.45 3.29E+Ol 13.21 1352.90
- 5. 07E+Ol 23.50 1407.87 l.28E+02
- 29. 25 2332.45 9.51E+Ol 23.01 2436.47 1.46E+02
- 25. 72 3643.30 5.45E+Ol 1 6.98 3874.29 2.64E+Ol 12.99 4482.04 2.47E+O l 11.58 5842.66 l.16E+02 22.25 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Page 2 of8 Continuum Tentative Counts Nuclide
- 1. 39E+02 Pb214-XR Pb212-XR
- 1. 35E+02 Pb214-XR Pb212-XR 2.01E+02 Pb-212 6.33E+Ol Pb-214 Eu-152 4.30E+Ol Pa-231 Pb-212 Th-227 7.06E+Ol Ac-228 6.62E+Ol Pb-214 Bi-211 2.98E+Ol Tl-208 1.51E+Ol Bi-214
- 1. 51E+Ol Ac-228
- 1. 51E+Ol Ac-228 8.69E+OO Bi-2 14
- 6. llE+OO K-40 Activity Coinc Name Confidence (keV)
(pCilgrams)
Uncertainty Corr K-40
- 0. 99 1460.82
- 10. 66 3.79E+OO 7.98E-01 miss Tl-208
- 1. 00 583.19 85.00 2.lOE-01 5.66E-02 miss Pb-212
- 1. 00 115.18 0.60 238.63 43.60 5.50E-01 l.39E-01 miss 300.09
- 3.30 l.19E+OO 5.15E-01 miss Pb212-XR
- 1. 00 74.82 10.28
- l. 23E+OO 6.33E-01 miss 77.11
- 17. 10 9.12E-Ol 3.81E-01 miss 87.35 3.97 89.78
- 1. 46
[137]
4/27/2016 2 :55:49PM Page 3 of8 Analysis Report for 27-Apr-16-10015 L310223AFRGS010SS (DRIED)
Nuclide Id Energy Yield(%)
11r.tivitv
/1rtivitu Caine Name Confidence (keV)
(pCilgrams)
Uncertainty Corr Bi-214 0.99 609.32 45.49
- 6. 21E-0 1
- 1. 32E-01 miss 768.36 4.89 806.18
- 1. 26 934.06 3. 11 1120.29 14.92 4.79E-0 1 2.28E-01 miss 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385. 31 0.79 1401.52
- 1. 33 1407.99 2.39 1509.21 2.13 1661.27
- 1. 05 1729.59 2.88 1764.49 15.30 1847.43 2.03 2118. 51 1.16 Pb-214
- 1. 00 241.99 7.25 295.22 18.42 5.99E-01 l.64E-01 miss 351.93 35.60 4.74E-01 l.32E-01 miss 785. 96
- 1. 06 Ac-228 0.99 129.07 2.42 209.25 3.89 270.24 3.46 328.00 2.95 338.32
- 11. 27 5.79E-01 2.84E-01 miss 409.46
- 1. 92 463.00 4.40 794.95 4.25 911. 20
- 25.80 5.34E-01 1.73E-01 miss 964. 77 4.99 968. 97 15.80 4.41E-01 2.20E-01 miss 1588.20 3.22 Pa-231 0.69 27.36 10.30 283.69
- 1. 70 300.07 2.47 l.59E+OC
- 7. 17E-01 miss 302.65 2.20 330.06
- 1. 40
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold= 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[138]
4/27/2016 2:55:49PM Analysis Report for 27-Apr-16-10015 L310223AFRGS010SS (DRIED)
INTERFERENCE CORRECTED REPORT Nuclide Name K-40 Tl-208 X
Bi-211 Pb-212 Pb212-XR Bi-214 Pb-214 X
Pb214-XR Ac-228 Pa-231 Nuclide Id Confidence 0.990 1.000 0.956 1.000 1.000 0.999
- 1. 000
- 1. 000 0.997 0.694
?
X
=
nuclide is part of an undetermined solution nuclide rejected by the interference analysis Wt mean Activity (pCi/grams) 3.79E+OO 2.lOE-01 5.SOE-01
- 9. 96E-01 5.86E-01 5.~4E-01 5.14E-01 8.55E-01
= nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Wt mean Activity Uncertainty 7.98E-01 5.66E-02 l.39E-01 3.26E-01 1.14E-01 l.03E-01 1.23E-01 7.llE-01 Page 4 of8 Comments
[139]
4/27/2016
~:55:49PM Analysis Report for 27-Apr-16-10015
+
+
+
+
+
+
+
+
+
L310223AFRGS010SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 2:55:19PM
- 120
- 8192 Peak CPS (D/o)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCi/grams)
(pCi/grams)
(pCi!grams)
K-40 1460.82
".'(
10.66 3.79E+OO 3.89E-01 3.89E-01 Cr-51 320.08 9.91
- l. 15E-Ol
-1. 36E-02 2.23E-02 2.23E-02 1674.73 0.52 O. OOE+OO 2.06E+OO Co-60 1173.23 99.85 1.54E-02 3.02E-02 4.50E-02 1332.49 99.98
-l.86E-03 3.02E-02 Nb-94 702.65 99.81 1.42E-02 2.64E-02 3.86E-02 871.09 99.89 9.54E-04 2.64E-02 Ag-108m 79.13 6.60
-3.65E-Ol 3.60E-02 l.19E+OO 433.94 90.50 1.69E-02 3.79E-02 614.28 89.80 1.24E-02 3.60E-02 722. 94 90.80
- 1. l 9E-02 3.78E-02 Sn-113 255.13
- 2. 11
-5.49E-01 4.86E-02 l.24E+OO 391.70 64.97
-2.22E-03 4.86E-02 Cs-134 475.36
- 1. 48
- 2. 04E-01
- 4. 20E-02 2.08E+OO 563.25 8.34 4.74E-02 3.66E-Ol 569.33 15.37 2.40E-03 2.00E-01 604.72 97.62 2.09E-02 4.20E-02 Page 5 of 8 Tolerance Nuclide Caine Corr miss free miss miss mi s s miss miss miss miss miss miss miss miss free free miss mis s miss miss
[140]
4/27/2016 2:55:49PM Page 6 of8 Analysis Report for 27-Apr-16-10015 L310223AFRGS010SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCl/grams)
(pCi!grams)
Corr Cs-134 795.86 85.46 1.82E-02 4.20E-02 5.61E-02 miss 801.95 8.69
-4.90E-02 3.21E-01 miss 1038.61 0.99 3.73E-01 3.66E+OO miss 1167.97
- 1. 79 1.91E-01 2.00E+OO miss 1365. 19 3.02 1. 31E-01 l.18E+OO miss
+
Cs-137 661. 66
- 85. 10 1.38E-02 4.18E-02 4.18E-02 miss
+
Eu-152 121. 78 28.67
-5.61E-02 7.51E-02 l.15E-Ol miss 244. 70 7.61
-l.03E-02 4.05E-01 miss 295.94 0.45
- 1. 60E+01 1.27E+Ol miss 344.28 26.60
-5.53E-03 l.22E-01 miss 367.79 0.86
-4.95E-01 3.55E+OO miss 411. 12 2.24
-3.03E-01 l.48E+OO miss 443. 96 2.83
- 1. 96E-01 l.23E+OO miss 488.68 0.42 1.06E+OO
- 7. 16E+OO miss 563.99 0.4S
-1.59E+OO 6.21E+OO miss 586.26 0.46
-4.61E+OO 6.81E+OO miss 678.62 0.47 1.83E+OO 6.60E+OO miss 688.67 0.86 6.39E-Ol 3.66E+OO miss 719.35 0.28
-2.36E+OO 8.33E+OO miss 778.90 12.96
-l.22E-01 2.64E-01 miss 810.45 0.32
-l.94E+OO 8.74E+OO miss 867.37 4.26
- 2. 96E-01 8.61E-01 miss 919.33 0.43
-7.93E-01 6.41E+OO miss 964. 08 14.65
- 1. 03E-01 3.38E-01 miss 1085.87 10.24 O.OOE+OO 7.51E-02 miss 1089.74
- 1. 73 3.06E-01 1.53E+OO miss 1112. 07
- 13. 69
-2.59E-02 2.77E-01 miss 1212. 95
- 1. 43 5.65E-01 3.57E+OO miss 1249.94 0.19
-8.0lE+OO 1.21E+Ol miss 1299.14
- 1. 63
-l.97E-01 l.45E+OO miss 1408.01 21.07 2.30E-03 l.49E-01 miss 1457.64 0.50 O.OOE+OO l.43E+Ol miss 1528.10 0.28 O.OOE+OO 3.46E+OO miss
+
Eu-154 123.07
- 40. 40 2.81E-02 8.43E-02 9.12E-02 miss 247.93 6.89 1.05E-01 4.64E-01 miss 591.76 4.95 6.12E-02 5.39E-01 miss 692.42
- 1. 78
-5.79E-01 1.27E+OO miss 723.30 20.06
- 1. 65E-02 1.62E-01 miss 756.80
- 4. 52
-4.39E-02
- 6. 96E-01 miss 873.18 12.08
- 4. 40E-02 2.44E-01 miss 996.29 10.48 7.87E-02 3.36E-01 miss 1004.76
- 18. 01
-4.00E-02 1.lOE-01 miss 1274.43 34.80
- 7. 7BE-03 8.43E-02 miss 1596.48
- 1. 80 2.08E-01 1.53E+OO miss
+
Eu-155 45.30
- 1. 31 8.97E+OO l.96E-Ol 2.24E+Ol miss 60.01
- 1. 22
-4.66E+0D 2.09E+D1 miss 86.55 30.70 8.39E-02 2.37E-01 miss 105.31 21.10
-1. 44E-01
- 1. 96E-01 miss
+
Tl-208 583.19 85.00 2.lOE-01 5.02E-02 5.02E-02 miss
+
Bi-211 351.07 13.02 1.30E+OO 3.36E-01 3.36E-01 miss
+
Pb-211 404.85 3.78
-4.04E-02 8.44E-01 8.44E-01 miss
[141]
4/27/2016 2:55:49PM Page 7 of8 Analysis Report for 27-Apr-16-10015 L310223AFRGS010SS (DRIED)
Nuclide FnAmv
01 Yield{%)
Activity Nul'flirle Mf>JJ LineMDA Coinc Name (keV)
(pCilgrams)
(pCUgrams)
(pCi/grams)
Corr Pb-211 427.09
- 1. 76 2.58E-02 8.44E-01 l.62E+OO miss 832.01 3.52 2.09E-02 l.OlE+OO miss
+
Bi-212 39.86
- 1. 06
-2.24E-01 9.32E-01 2.32E+Ol miss 727. 33 6.67
- 7. 96E-01 9.32E-01 miss 785.37
- 1. 10
-1.04E+OO 2.93E+OO miss 1620.50
- 1. 47 2.41E-01 2.39E+OO miss
+
Pb-212 115.18 0.60 7.49E-01
- l. 36E-01 6.79E+OO miss 238.63 43.60 5.50E-01 l.36E-01 miss 300.09 3.30 l.19E+OO 8.77E-01 miss
+
Pb212-XR 74.82 10.28 1.23E+OO 6.83E-01
- 1. 31E+OO miss 77.11 17.10 9.12E-01 6.83E-Ol miss 87.35 3.97
- 1. 37E+OO l.84E+OO miss 89.78
- 1. 46 2.94E+OO 4.56E+OO miss
+
Bi-214 609.32 45.49 6.21E-01 7.21E-02 7.21E-02 miss 768.36 4.89 4.99E-01 l.03E+OO miss 806.18
- 1. 26 2.45E-01 2.60E+OO miss 934.06 3.11
-6.31E-02 1.24E+OO miss 1120.29 14.92 4.79E-01 2.43E-01 miss 1155.21
- 1. 63 5.99E-01 2.88E+OO miss 1238.12 5.83 2.74E-01 l.16E+OO miss 1280.98
- 1. 43 7.57E-01 3.12E+OO miss 1377. 67 3.99 6.14E-01
- 1. 33E+OO miss 1385. 31 0.79
- l. 46E+OO 5.07E+OO miss 1401.52
- 1. 33
-3.27E-01 2.36E+OO miss 1407.99 2.39 2.02E-02 1.31E+OO miss 1509.21 2.13 1.92E-01 1.81E+OO miss 1661. 27
- 1. 05 9.19E-01
- 3. 96E+OO miss 1729.59 2.88
-2.41E-01 1.02E+OO miss 1764.49
- 15. 30 5.57E-Ol 6.59E-01 miss 1847.43 2.03 2.05E-01 1.51E+OO miss 2118.51
- 1. 16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241.99
- 7. 25 9.09E-01 1.23E-01 7.00E-01 miss 295.22 18.42 5.99E-01 l.85E-01 miss 351.93 35.60 4.74E-01 1.23E-01 miss 785.96
- 1. 06 2.31E-01 3.24E+OO miss
+
Pb214-XR 74.82 5.80 2.18E+OO l.20E+OO 2.32E+OO miss 77.11 9.70
- l. 61E+OO 1.20E+OO miss 87.35 2.24 2.44E+OO 3.26E+OO miss 89.78 0.82 5.23E+OO
- 8. llE+OO miss
+
Ra-226 186.21 3.64 5.35E-01
- 1. 0BE+OO l.08E+OO miss
+
Ac-228 129.07 2.42 5.63E-01
- 1. 62E-Ol 1.70E+OO miss 209.25 3.89 1.37E-01 9.04E-01 miss 270.24 3.46 l.47E-01
- 1. llE+OO miss 328.00 2.95 3.78E-01 l.19E+OO miss 338.32
- 11. 27 5.79E-01 3.82E-01 miss 409.46
- 1. 92 2.89E-01 1.84E+OO miss 463.00 4.40 8.71E-01 1.13E+OO miss 794.95 4.25 4.40E-01
- 1. 22E+OO miss 911. 20 25.80 5.34E-Ol 1.62E-01 miss 964.,7 4.99 3.97E-01 1.06E+OO miss 968.97 15.80 4.41E-01 2.63E-01 miss
[142]
4/27/2016 2:55:49P~v1 Page 8 of8 Analysis Report for 27-Apr-16-10015 L310223AFRGS010SS (DRIED)
Nuclide Fn~rrn,
-**-*.:11 Yield(%)
Activity Nu,-lirl~ Mnti Line MD/J.
Caine Name (keV)
(pCilgrams)
(pCUgrams)
(pCilgrams)
Corr Ac-228 1588.20 3.22 5.67E-01 l.62E-01 l.73E+OO miss
+
Pa-231 27.36 10.30 4.04E-01 l.17E+OO 2.85E+OO miss 283.69
- 1. 70
-2.78E-01 l.82E+OO miss 300.07 2.47 1.59E+OO l.17E+OO miss 302.65 2.20
-1. 19E-01 l.19E+OO miss 330.06
- 1. 40 l.34E-01 2.26E+OO miss
+
Th-234 92.38 2.13 4.75E-01 2. 96E+OO
- 2. 96E+OO miss 92.80
- 2. 10 3.29E-01
- 2. 98E+OO miss 112. 81 0.21 6.81E+OO
- 2. llE+Ol miss
+
0-235 143.76 10.96 9.45E-02 7.23E-02
- 3. 55E-01 miss 163.33 5.08
-2.12E-Ol
- 6. 1 9E-01 miss 185.71 57.20 6.36E-02 7.23E-02 miss 202. 11
- 1. 08 6.37E-Ol
- 2. 90E+OO miss 205.31 5.01 l.94E-01 6.24E-01 miss
+
Arn-241 59.54 35.90 2.17E-01 7.46E-01 7.46E-Ol miss
+ = Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> = MDA value not calculated
@,. Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[143]
80 70
~
V')
.j..l C:
- I 0 u 60 50 40
~
-k 30 1
20
~J 1000 2000 3000 0000014756.CNF 4000 channel 5000 Live Time :600.000 sec Rea 1 Ti me : 601. 010 sec start:
1: -0. l(kev) stop : 8192: 2047. O(kev)
Acq. Start :wed Apr 27 14 :44:43 2016 6000 7000 8000
[144]
4/27/2016 3:27:40PM Analysis Report for 27-Apr-16-10016 L310223AFRGS011SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live lime Real lime Dead lime Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10016
- L310223AFRGS011SS (DRIED)
- 1L 130G Soil Sample 1.755E+03 grams
- Default
- 4/25/2016 12:45:00PM
- 4/27/2016 3:17:01PM
- 130G 1L Sand Sample
- JWelch
- P11314X2
- 130G Sand
- 600.0 seconds
- 600.5 seconds
- 0.08 %
- 2.80
- 120- 8192
- 120- 8192
- 1.000FWHM
- 1/27/2016
- 11/26/2012
- 14757 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 3:27:06PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
. 1.000FWHM Page I of8
[145]
4/27/2016
- 3:27:40PM Analysis Report for 27-Apr-16-10016 M
m L310223AFRGS011 SS (DRIED)
Peak Energy ROI No.
(keV) start 1
74.80 295 -
2 77.19 295 -
3 238.64 949 -
4 295.26 1176 -
5 352.04 1401 -
6 609.55 2430 -
7 911. 63 3639 -
8 1461.19 5835 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 315 315 960 1187 1414 2444 3650 5854 Peak Net Peak Net Area Centroid Area Uncertainty 300.43 2.lOE+Ol 12.31 309.99 3.64E+Ol 14.68 954.89 7.90E+O l 24.22 1181.11 2.88E+Ol 17.46 1407.97 4.78E+Ol
- 18. 64 2437.11 5.22E+Ol 17.23 3645.02 2.41E+O l 11.40 5844.08
- 1. 62E+02 26.01 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Page 2 of8 Continuum Tentative Counts Nuclide 5.61E+Ol Pb214-B Pb212-XR 4.17E+Ol Pb214-XR Pb212-XR 5.40E+Ol Pb-212 3.44E+Ol Pb-214 Eu-152 3..25E+Ol Pb-214 Bi-211 1.77E+Ol Bi-21';
7.81E+OO Ac-228 5.71E+OO K-40 Activity Coinc Name Confidence (keV)
(pCilgrams)
Uncertainty Co" K-40 0.99 1460.82
- 10.66
- 5. 15E+OO 9.40E-01 mis s Pb-212
- 1. 00 115.18 0.60 238.63 43.60 1.79E-01 6.21E-02 miss 300.09 3.30 Pb212-XR
- 1. 00 74.82 10.28
- 3. 77E-01 2.34E-01 miss 77. 11
- 17. 10
- 3. 61E-Ol
- 1. 63E-01 miss 87.35 3.97 89.78
- 1. 46 Bi-214 0.99 609.32 45.49
- 2. 15E-01 7.57E-02 miss 768.36 4.89 806.18
- 1. 26 934.06 3. 11 1120.29 14.92 1155.21
- 1. 63 1238.12 5.83 1280.98
- 1. 43
[146]
Analysis Report for 27-Apr-16-10016 L310223AFRGS011 SS {DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214 0.99 1377. 67 1385. 31 1401.52 1407.99 1509.21 1661.27 1729.59 1764.49 1847.43 2118. 51 Pb-214
- 1. 00 241.99 295.22 351.93 785.96 Ac-228 0.99 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964. 77 968. 97 1588.20
- = Energy line found in the spectrum.
- - Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold= 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
3.99 0.79
- 1. 33 2.39 2.13
- 1. 05 2.88 15.30 2.03 1.16 7.25 18.42 35.60
- 1. 06 2.42 3.89 3.46 2.95 11.27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 3:27:40PM Page 3 of8 Activity Activity Coinc (pCilgrams)
Uncertainty Co" l.78E-01 1.12E-01 miss
[147]
Analysis Report for 27-Apr-16-10016 X
L310223AFRGS011SS (DRIED)
Nuclide Nuclide Name Id Confidence K-40 0.992 Bi-211 0.943 Pb-212 1.000 Pb212-XR
- 1. 000 Bi-214 0.999 Pb-214
- 1. 000 Pb214-XR
- 1. 000 Ac-228 0.997
?
nuclide is part of an undetermined solution X
nuclide rejected by the interference analysis 4/27/2016 Wt mean Activity (pCilgrams) 5.15E+OO l.79E-Ol 3.66E-Ol 2.lSE-01
- 1. 74E-01 2.30E-01 nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 3:27:40PM Page -1 of8 Wt mean Comments Activity Uncertainty 9.40E-01 6.21E-02 1.34E-01 7.57E-02 6.08E-02
- l. llE-01
[148]
4/27/2016 3:27:40PM Analysis Report for 27-Apr-16-10016
+
+
+
+
+
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy {keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 3:27:06PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCUgrams)
(pCUgrams)
(pCi/grams)
K-40 1460.82 10.66 5.15E+OO 3.62E-01 3.62E-01 Cr-51 320.08 9.91 9.59E-02 2.49E-01 2.49E-01 Mn-54 834.85 99.98 5.13E-03 3.05E-02 3.05E-02 Co-58 810.76 99.45
-3.89E-03 2.17E-02 2.17E-02 1674.73 0.52 O.OOE+OO 2.0lE+OO Co-60 1173.23 99.85
-9.43E-03 3.14E-02 3.14E-02 Page 5 of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss 1332.49 99.98
- 3. 61E-03 3.40E-02 miss
+
Nb-94 702.65 99.81 3.BOE-03 1.92E-02 1.92E-02 miss 871. 09 99.89 1.99E-03 2.22E-02 miss
+
Ag-108m 79.13 6.60
- 1. 19E-01 2.50E-02 6.02E-01 miss 433.94 90.50
-5.09E-03 2.60E-02 miss 614.28 89.80
-8.41E-04 2.53E-02 miss 722. 94 90.80
-5.80E-03 2.50E-02 miss
+
Sn-113 255.13
- 2. 11
-2. 71E-01 3.42E-02 8.26E-01 free 391. 70 64.97
- l. llE-02 3.42E-02 free
+
Cs-134 475.36
- 1. 48
-3.26E-01 3.04E-02 1.41E+OO miss 563.25 8.34
-l.71E-02 2.57E-Ol miss 569.33 15.37
-4.21E-02 8.60E-02 miss 604. 72
- 97. 62 8.53E-03 3.04E-02 miss
[149]
4/27/2016 3:27:40PM Page 6 of8 Analysis Report for 27-Apr-16-10016 L310223AFRGS011SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCi/grams)
(pCilgrams)
(pCilgrams)
Corr Cs-134 795.86 85.46
-2.63E-03 3.04E-02 3.45E-02 miss 801. 95 8.69 l.52E-02
- 3. 13E-01 miss 1038. 61 0.99 3.28E-01 3.27E+OO miss 1167.97
- 1. 79 O.OOE+OO 4.39E-01 miss 1365. 19 3.02 O.OOE+OO
- 2. 89E-01 miss
+
Cs-137 661. 6 6
- 85. 10 1.00E-02 3.50E-02
- 3. SOE-02 miss
+
Eu-152 121.78 28.67 l.16E-02 6.22E-02
- 7. 45E-0~ miss 244.70 7.61
-2.58E-02 2.74E-01 miss 295.94 0.45 6.44E+OO 8.46E+OO miss 344.28 26.60
-1.84E-02 6.22E-02 miss 367.79
- 0. 86
-1.00E-01 2.78E+OO miss 41 1.12 2.24
-1.83E-02 9.61E-01 miss 443. 96 2.83 4.07E-01 9.67E-01 miss 488.68 0.42
-1. 54E-01 5.04E+OO miss 563.99 0.49
-3.63E-02 4.36E+OO miss 58 6. 2 6 0.46
-1.67E+OO 5.97E+OO miss 678.62 0.47
-3.57E-02
- 5. 14E+OO miss 688.67 0.86
-1.15E+OO 2.21E+OO miss 719. 35 0.28 2.51E-01 9.04E+OO miss 778.90 12.96 4.lOE-02 2.24E-01 miss 810.45 0.32
-1.24E+OO 6.58E+OO miss 867.37 4.26
- 2. llE-01 7.88E-01 miss 919.33 0.43 1.74E+OO
- 6. 96E+OO miss 964.08 14.65 8.19E-02 2.77E-Ol miss 1085.87 10.24
-3.86E-03 2.SlE-01 miss 1089.74
- 1. 73 9.79E-01 2.67E+OO miss 1112. 07
- 13. 69
- 1. 17E-02 2.46E-01 miss 1212.95
- 1. 43
-1.56E-01
- 2. 50E+OO miss 1249.94 0.19
-5.13E+OO 2.lOE+Ol miss 1299. 14
- 1. 63
-1.64E-01 l.41E+OO miss 1408. 01
- 21. 07 3.13E-02 1.45E-01 miss 1457.64 0.50
-6.34E+OO 4.95E+OO miss 1528.10 0.28 O.OOE+OO 3.37E+OO miss i-Eu-154 123.07 40.40
-1.16E-02 5. 05E-02 5.05E-D2 miss 247.93 6.89
-6.70E-02 2.56E-01 miss 591. 76 4.95
-6.33E-02 4.47E-01 miss 692.42
- 1. 78 1.43E-01 1.73E+OO mi ss 723. 30 20.06
-2.63E-02 1.13E-01 miss 756.80 4.52
-1.50E-01 5.17E-01 miss 873.18 12.08 1.65E-02 1.46E-01 miss 996.29
- 10. 48 7.90E-02 3.00E-01 miss 1004.76 18.01 3.49E-02 2.D6E-01 miss 1274.43 34.80 1.BlE-02 l.24E-Ol miss 1596. 48
- 1. 80 O.OOE+OO 5.46E-01 miss
+
Eu-155 45.30
- 1. 31
-2.46E+OO 1.25E-01 4.SOE+OO miss 60.01
- 1. 22
-7.17E-01 6.76E+OO miss 86.55 30.70 4.21E-02 1.25E-01 miss 105.31 21.10 5.95E-02 1.36E-01 miss
+
Tl-208 583.19 85.00 6.57E-02 6.40E-02 6.40E-02 miss
+
Bi-211 351.07 13.02 4.70E-01 2.29E-01 2.29E-01 miss
+
Pb-211 404.85
- 3. 78
-3.lOE-01 4.91E-Ol 4.91E-01 miss
[150]
4/27/2016 3:27:40PM Page 7 of8 Analysis Report for 27-Apr-16-10016 L310223AFRGS011SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coiru; Name (keV)
(pCi/grams)
(pCilgrams)
(pCi/grams)
Corr Pb-211 427.09
- 1. '7 6 5.88E-01 4.91E-01 l.45E+OO miss 832. 01 3.52
-1. 2 OE-01 6.lOE-01 miss
+
Bi-212 39.86
- 1. 06
-2.02E+OO 4.76E-01 6.83E+OO miss 727. 33 6.67 4.76E-02 4.76E-01 miss 785.37 1.10 l.25E+OO 3.21E+OO miss 1620.50
- 1. 47 3.43E-01
- 2. 69E+OO miss
+
Pb-212 115.18 0.60
- 1. 29E-02 6.75E-02 3.63E+OO miss 238.63 43.60 1.79E-01 6.75E-02 miss 300.09 3.30 8.45E-02 6.80E-01 miss
+
Pb212-;~R 74.82 10.28 3.77E-01 2.3 7E-01 4.90E-01 miss 77.11 17.10 3.61E-01 2.37E-Ol miss 87.35 3.97
-5.08E-02 8.40E-01 miss 89.78
- 1. 46 3.48E-01 2.19E+OO miss
+
Bi-214 609.32 45.49 2.15E-01 7.50E-02 7.50E-02 miss 768.36 4.89 2.87E-01 7.47E-01 miss 806.18
- 1. 26 2.69E-01
- 2. 69E+OO miss 934.06 3.11 2.31E-01 l.06E+OO miss 1120. 29 14.92 1.76E-01 3.68E-01 miss 1155.21
- 1. 63
-9.57E-01 2.12E+OO miss 1238.12 5.83 3.17E-01 8.19E-01 miss 1280.98
- 1. 43 2.30E-01 3.03E+OO miss 1377. 67 3.99
-2.21E-01 5.98E-01 miss 1385.31 0.79 4.lOE-01 3.02E+OO miss 1401. 52
- 1. 33 3.26E-01
- 2. 96E+OO miss 1407.99 2.39 2.75E-01 1.28E+OO miss 1509.21 2.13 2.33E-02 1.51E+OO miss 1661. 27
- 1. 05
- 1. 43E+OO 4.29E+OO miss 1729.59 2.88 1.34E-01 9.86E-01 miss 1764.49 15.30 2.16E-01 4.46E-01 miss 1 847.43 2.03 l.99E-01 1.46E+OO miss 2118.51 1.16 0.00E+OO O.OOE+OO miss
+
Pb-214 241.99 7.25
- 1. 12E-01
- 8. 3:E-02 3.37E-01 miss 295.22 18.42 1.78E-01 1.57E-01 miss 351. 93 35.60
- 1. 72E-01 8.37E-02 miss 785. 36
- 1. 06 4.90E-01
- 2. 96E+OO miss
+
Pb214-XR 74.82 5.30 6.69E-01 4.19E-01 8.69E-01 miss 77.11 9.70 6.36E-01 4.19E-01 miss 87.35 2.24
-9.0lE-02 l.49E+OO miss 89.78 0.82 6.20E-01
- 3. 91E+OO miss
+
Ra-226 186.21 3.64
- 4. 23E-02 6.39E-01 6.39E-01 miss
+
Ac-228 129.07 2.42 2.54E-01 l.17E-01 9.55E-01 miss 209.25 3.89
-l.14E-01 4.91E-01 miss 270.24 3.46
- 1. 23E-01 6.61E-01 miss 328.00 2.95 2.99E-01 8.07E-01 miss 338.32
- 11. 27 1.86E-01 2.82E-01 miss 409.46
- 1. 92 2.13E-01
- 1. 24E+OO miss 463.00
- 4. 40 2.34E-01 6.40E-01 miss 794.95 4.25 2.74E-01 7.93E-01 miss 911. 20 25.80 2.30E-01 l.17E-01 miss 964.77 4.99 l.42E-02 7.23E-01 miss 968.97 15.80 l.38E-01 3.16E-01 miss
[151]
4/27/2016 3:27:40PM Page 8 of8 Analysis Report for 27-Apr-16-10016 L310223AFRGS011SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCilgrams)
(pCi/grams)
Corr Ac-228 1588.20 3.22 2.67E-02
- 1. 1 ":'E-01 l.21E+OO miss
+
Pa-231 27.36 10.30 O.OOE+OO 9.76E-02 9.76E-02 miss 283.69
- 1. 70 2.64E-01 l.35E+OO miss 300.07 2.47 1.13E-01 9.08E-01 miss 302.65 2.20 1.32E-02 8.35E-01 miss 330.06
- 1. 40
-l.97E-01 l.39E+OO miss
+
Th-234 92.38 2.13 9.73E-01 1.85E+OO 1.87E+OO miss 92.80
- 2. 10
- 1. 05E+OO l.85E+OO miss 112. 81 0.21
-9.04E-02 l.14E+Ol miss
+
U-235 143.76 10.96
-5.18E-02 3.78E-02 l.68E-01 miss 163.33 5.08 1.21E-01 4.0BE-01 miss 185.71 57.20 8.21E-04 3.78E-02 miss 202.11
- 1. 08
-1. 77E-02 1.63E+OO miss 205.31 5.01 1.0BE-01 4.46E-01 miss
+
Artt-241 59.54 35.90 2.89E-02 2.43E-01 2.43E-01 miss
+ = Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> = MDA value not calculated
= Half-life too short to be able to perform the decay correction
? = CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[152]
60 55 50 45 40 35 V)
.j-1 C:
8 30
~
I
~
25 20 15 10 5
0 1000
~
9
-~ "'
2000 3000 0000014757.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :600.490 sec Start:
1: -0.2(kev)
Stop : 8192:2047.4(kev)
Acq. start :wed Apr 27 H:17:01 2016 6000 7000 8000
[153]
4/27/2016 3:28:17PM Analysis Report for 27-Apr-16-10017 L310223AFRGS012SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Rear Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10017
- L310223AFRGS012SS (DRIED)
- 1L 130G Soil Sample 1.806E+03 grams
- Default
- 4/25/2016 12:40:00PM
- 4/27/2016 3:17:17PM
- 130G 1L Sand Sample
- JWelch
- P408188
. 130G Sand
- 600.0 seconds
- 600.9 seconds
- 0.15%
- 2.80
- 120-8192
- 120 - 8192
- 1.000FWHM
- 1/27/2016
- 1/5/2015
- 14758 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 3:27:46PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB
- 1.000FWHM Pagelof8
[154]
4/27/2016 3:28:17PM Page 2 of8 Amdysis Report for 27-Apr-16-10017 L310223AFRGS012SS (DRIED)
Peak Energy ROI ROI Peak Net Peak Net Area Continuum Tentative No.
(keV) start end Centroid Area Uncertainty Counts Nuclide 1
77.18 306 -
314 309.77 3.27E+Ol 28.31
- l. 31E+02 Pb214-XR Pb212-XR 2
238.50 949 -
961 954.48
- 1. 49E+02 37.22 l.46E+02 Pb-212 3
277.13 1103 -
1112 1108. 90 2.04E+O l 1 7.17 4.73E+Ol ~a H3 r 1,.-.,.0 Y 4
295.39 1175 -
1187 1181.89 5.83E+O l 24.07 6.54E+Ol Pb-214 Eu-152 5
338.25 1345 -
1358 1353. 20 5.09E+Ol 20.39 4.41E+Ol Ac-228 6
351.83 1402 -
1415 1407. 51 l.16E+02 25.09 3.48E+Ol Pb-214 Bi-2 11 7
582.95 2324 -
2339 2331.56 7.02E+Ol 20.35 2.56E+Ol Tl-208 8
609.22 2431 -
2442 2436.61 9.19E+Ol 21.98 2.62E+Ol Bi-214 9
910.67 3635 -
3649 36<12.39 3.12E+O l 15.58 2.56E+Ol Ac-228 10 968. 82 3870 -
3881 3875.05 2.21E+O l 9.76
- 1. 72E+OO Ac-228 11 1120. 07 4475 -
4487 4480.27 l.44E+O l 10.06
- 1. llE+Ol Bi-214 12 1460.64 5833 -
5852 5843.51
- 1. 07E+02 20.98 2.87E+OO K-40 M = First peak in a multiplet region
~-;/
w,,;.rf r, m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield{%)
Activity Activity Coinc Name Confidence (keV)
(pCi/grams)
Uncertainty Corr K-40 0.99 1460. 82 10.66 3.65E+OO 7.86E-Ol miss Tl-208 0.99 583.19
- 85.00 l.6~E-01 5.09E-02 miss Pb-212 0.99 115. 18 0.60 238.63
- 43.60 3.69E-01 1.lOE-01 miss 300.09 3.30 Pb212-XR
- 1. 00 74.82 10.28
- 77. 11 17.10 5.70E-01 5.07E-01 miss 87.35 3.97 89.78
- 1. 46 Bi-214 0.99 609.32 45.49 4.09E-01
- 1. 09E-01 miss 768.36 4.89 806.18
- 1. 26 934.06 3. 11
[155]
4/27/2016 3:28:17PM Page 3 of8 Analysis Report for 27-Apr-16-10017 L310223AFRGS012SS (DRIED)
Nuclide Id Energy Yield(%)
Activity Activity Caine Name Confidence (keV)
(pCilgrams)
Uncertainty Corr Bi-214 0.99 1120.29
- 14. 92 2.94E-01 2.06E-Ol miss 1155.21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377. 67 3.99 1385.31 0.79 1401.52
- 1. 33 1407.99 2.39 1509.21
- 2. 13 1661.27
- 1. 05 1729.59 2.88 1764.49 15.30 1847.43 2.03 2118.51
- 1. 16 Pb-214 0, 99 241.99 7.25 295.22 18.42 3.92E-01 l.74E-01 miss 351.93 35.60 4.49E-01 l.21E-01 miss 785.96
- 1. 06 Pb214-XR
- 1. 00 74.82 5.80 77. 11 9.70 l. OOE+OO
- 8. 98E-01 miss 87.35 2.24 89.78 0.82 Ac-228
- 0. 99 129.07 2.42 209.25 3.89 270.24 3.46 328. 00 2.95 338.32..
11.27 6.lOE-01 2. 64E-01 miss 409.46
- 1. 92 463. 00 4.40 794.95 4.25 911. 20 25.80
- 3. 21E-01 1.63E-01 miss 964.77 4.99 968.97 15.80 3.88E-01 1.74E-01 miss 1588.20 3.22
.. - Energy line found in the spectrum.
- - Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[156]
4/27/2016 3:28:17PM Analysis Report for 27-Apr-16-10017 L310223AFRGS012SS (DRIED) itvTERFERENCE CORRECTED REPORT X
?
?
?
=
X
=
=c Nuclide Name K-40 Tl-208 Bi-211 Pb-212 Pb212-XR Bi-214 Pb-214 Pb214-XR Ac-228 Nuclide Id Confidence 0.998 0. 996 0.965 0.999 1.000 0.999 0.999
- 1. 000 0.994 nuclide is part of an undetermined solution nuclide rejected by the interference analysis Wt mean Activity (pCilgrams) 3.65E+OO l.62E-01 3.69E-01 5.70E-01 3.84E-01 4.30E-01 1.00E+OO
- 3. 95E-01 nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Wt mean Activity Uncertainty 7.86E-01 5.09E-02 1.lOE-01 5.07E-Ol 9.67E-02 9.93E-02 8.98E-01
- 1. OBE-01 Page4 of 8 Comments
[157]
4127/2016 3:28:17PM Analysis Report for 27-Apr-16-10017
+
+
+
+
+
+
+
+
+
L310223AFRGS012SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV) 3
'277.13 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 3:27:46PM
- 120 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty
- 3. 39205E-02 42.17 Peak Type Tol.
NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield{°/,,)
Activity NuclideMDA LineMDA Name (keV)
(pCi/grams)
(pCi!grams)
(pCilgrams)
K-40 1460.82 10.66 3.65E+OO 3.04E-Ol 3.04E-01 Cr-51 320.08
- 9. 91 1.20E-Ol 3.19E-01 3.19E-01 Mn-54 834.85 99.98 7.95E-03 3.29E-02 3.29E-02 Co-58 810.76 99.45
- 1. 26E-03 3.55E-02 3.55E-02 1674.73 0.52
- 1. 70E+OO 9.61E+OO Co-60 1173.23 99.85
-2.69E-03 2.31E-02 2.31E-02 1332.49 99.98
- 1. 58E-03 4.lOE-02 Nb-94 702.65 99.81
- 1. OOE-02 3.09E-02 3.89E-02 871.09 99.89
-2.14E-03 3.09E-02 Ag-108m 79.13 6.60
-1. 80E-Ol 3.08E-02 1.31E+OO 433.94 90.50
-1. 20E-03 3.08E-02 614.28 89.80 7.62E-03
- 4. llE-02 722. 94 90.80
-7.92E-03 3.53E-02 Sn-113 255.13 2.11
-7.94E-03 3.88E-02
- 1. 50E+OO 391.70 64.97
-1.07E-02 3.88E-02 Cs-134 475.36
- 1. 48
-6.62E-02 3.75E-02 2.33E+OO 563.25 8.34 4.61E-02 4.49E-01 569.33 15.37 3.27E-02 l.89E-Ol Page 5 of8 Tolerance Nuclide Caine Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss
[158]
4/27/2016 3:28:17PM Page 6 of8 Analysis Report for 27-Apr-16-10017 L310223AFRGS012SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCi/grams)
(pCilgrams)
(pCi/grams)
Corr Cs-134 604. 72 97.62 2.67E-03 3.75E-02 3.75E-02 miss 795.86 85.46 1.66E-02 4. 94E-02 miss 801.95 8.69 4.02E-02
- 3. 68E-01 miss 1038.61 0.99
- 1. 50E+OO 4.13E+OO miss 1167.97
- 1. 79 5.50E-01 2.29E+OO miss 1365.19 3.02
-3.95E-01 8.49E-01 miss
+
Cs-137 661.66
- 85. 10 3.56E-03 3.99E-02
- 3. 99E-02 miss
+
Eu-152 121. 78 28.67
-2.38E-02
- 1. 09E-01 l.18E-01 miss 244.70 7.61 9.65E-02
- 3. 95E-01 miss 2 95. 94 0.45 9.29E+OO l. 12E+Ol miss 344.28 26.60
-2.90E-02 l.09E-01 miss 367.79 0.86 4.15E-01 3.23E+OO miss 411.12 2.24
-8.29E-01 9.74E-01 miss 443.96 2.83
-3.97E-0 1 6.91E-Ol miss 488.68 0.42 4.97E-02 7.22E+OO miss 563.99 0.49 5.87E-01 7.36E+OO miss 586.26 0.46
-4.49E+OO 6.44E+OO miss 678. 62 0.47
-2.92E+OO 3.39E+OO miss 688.67 0.86 -l.89E+OO 3.35E+OO miss 719.35 0.28 4.67E-01 1.47E+Ol miss 778.90
- 12. 96
-6.75E-02
- 1. 98E-01 miss 810.45 0.32
- 1. 43E+OO l.21E+Ol miss 867.37 4.26
-2.51E-03 7.23E-01 miss 919.33 0.43 1.35E+OO 8.18E+OO miss 964. 08 14.65 l.03E-01 2.99E-01 miss 1085.87
- 10. 24 1.89E-01 4.62E-01 miss 1089.74
- 1. 73
-1.0lE+OO 1.27E+OO miss 1112. 07 13.69 7.65E-02 3.85E-01 miss 1212.95
- 1. 43
- 4. llE-01 2.95E+OO miss 1249.94 0.19
-1.19E+Ol l.61E+Ol miss 1299.14
- 1. 63 3.24E-01 1.92E+OO miss 1408.01 21.07 3.30E-02 l.82E-Ol miss 1457.64 0.50 O.OOE+OO l.37E+Ol miss 1528.10 0.28 O.OOE+OO 3.63E+OO miss
+
Eu-154 123.07 40.40
-8.88E-03 8.50E-02 8.5DE-02 miss 247.93 6.89
- 1. 53E-01 4.54E-01 miss 591.76 4.95
-6.0lE-03 6.36E-01 miss 692.42
- 1. 78
-1.48E-02 1.86E+OO miss 723.30 20.06
-9.44E-03 1.60E-01 miss 756.80 4.52 1.96E-01 7.78E-01 miss 873.18 12.08
-2.49E-02 2.29E-01 miss 996.29 10.48
-1.79E-02 2.90E-01 miss 1 004.76 18.01
-1.71E-02
- l. 89E-Ol miss 1274.43 34.80 4.62E-02
- 1. 43E-01 miss 1596.48
- 1. 80
-5.45E-Ol 1.60E+OO miss Eu-155 45.30
- 1. 31 4.85E+OO 2.08E-01 2.13E+Ol miss
- 60. 01
- 1. 22
-6.24E+OO 2.17E+Ol miss 86.55 30.70 1.64E-02 2.17E-01 miss 105.31 21.10 7.25E-02 2.08E-01 miss
+
Tl-208 583.19 85.00 1.62E-01
- 5. 0lE-02 5.0lE-02 miss
+
Bi-211 351.07 13.02 1.23E+D0 2.55E-01 2.SSE-01 miss
[159]
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Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi/grams)
(pCilgrams)
(pCi/grams)
Corr
+
Pb-211 404.85 3.78
-l.35E-02 7.61E-01
- 7. 61E-01 miss 427.09
- 1. 76
-4.59E-01 l.70E+OO miss 832.01 3.52
-1.18E-02 8.50E-01 miss
+
Bi-212 39.86
- 1. 06
-1. 02E+Ol 8.21E-01 2.17E+01 miss 727. 33 6.67 6.91E-01 8.21E-01 miss 785.37
- 1. 10 1.48E+OO 3.95E+OO miss 1620.50
- 1. 47 8.92E-01 3.24E+OO miss
+
Pb-212 115.18 0.60
-3.76E-01 1.21E-01 6.60E+OO miss 238.63 43.60 3.69E-01 1.21E-01 miss 300.09 3.30 2.74E-01 9.66E-01 miss
+
Pb212-XR 74.82 10.28 6.87E-01 7.89E-01 l.29E+OO miss 77. 11 17.10 5.70E-01 7.89E-01 miss 87.35 3.97 6.88E-01 1.77E+OO miss 89.78
- 1. 46
-2.97E-01 3.63E+OO miss
+
Bi-214 609.32 45.49 4.09E-01 9.06E-02 9.06E-02 miss 768.36 4.89 3.33E-02 7.25E-01 miss 806. 18
- 1. 26 6.69E-01 3.36E+OO miss 934. 06 3. 11 1.07E+OO 1.85E+OO miss 1120.29 14.92 2.94E-01 2.76E-01 miss 1155. 21
- 1. 63 2.44E-01 2.49E+OO miss 1238.12 5.83 4.91E-01 1.12E+OO miss 1280.98
- 1. 43
- l. 21E+OO 3.27E+OO miss 1377.67 3.99 7.0lE-01 1.39E+OO miss 1385. 31 0.79 l.63E+OO 5.81E+OO miss 1401.52
- 1. 33 3.BlE-02 l.96E+OO miss 1407.99 2.39 2.90E-01 l.60E+OO miss 1509.21 2.13 2.77E-01 2.llE+OO miss 1661.27
- 1. 05 8.03E-01 4.15E+OO miss 1729.59 2.88 3.07E-01 1.74E+OO miss 1764.49 15.30 4.43E-01 6.05E-01 miss 1847.43 2.03
- 1. 2 9E+OO 3.03E+OO miss 2118. 51 1.16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241.99 7.25 5.79E-01 9. 31E-02 6.18E-01 miss 295.22 18.42 3.92E-Ol 2.24E-01 miss 351.93 35.60 4.49E-01 9.31E-02 miss 785. 96
- 1. 06
-1.21E+OO 3.19E+OO miss
+
Pb214-XR 74.82 5.80
- 1. 22E+OO 1.39E+OO 2.29E+OO miss 77. 11 9.70 1.00E+OO 1.39E+OO mi ss 87.35 2.24 1.22E+OO 3.14E+OO miss 89.78 0.82
-5.28E-01 6.47E+OO miss
+
Ra-226 186.21 3.64 7.23E-01
- 1. llE+OO 1. llE+OO miss
+
Ac-228 129.07 2.42 3.30E-01
- 1. 22E-01 1.55E+OO miss 209.25 3.89 7.03E-01 9.14E-01 mi~s 270.24 3.46
-5.13E-02 9.68E-01 miss 328. 00 2.95 4.27E-01 1.23E+OO miss 338.32
- 11. 27 6.lOE-01 3.19E-01 miss 409.46
- 1. 92 3.46E-Ol l.66E+OO miss 463. 00 4.40 4.45E-01 9.53E-01 miss 794.95 4.25 2.37E-01 9.91E-01 miss 911. 20 25.80 3.21E-01
- 2. llE-01 miss 964. 77 4.99 4.94E-01 9.63E-01 miss
[160]
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Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCi/grams)
(pCi!grams)
Corr Ac-228 968.97 15.80 3.88E-01
- l. 22E-01 1.22E-01 miss 1588.20 3.22 4.72E-Ol
- l. 71E+OO miss
+
Pa-231 27.36 10.30
-4.46E-01
- 1. 29E+OO 2.58E+00 miss 283.69
- 1. 70
-3.37E-01 1.55E+OO miss 300.07 2.47 3.66E-Ol l.29E+OO miss 302.65 2.20
-6.36E-02 l. 34E+OO miss 330.06
- 1. 40
-5.82E-01 2.13E+OO miss
+
Th-234 92.38 2.13 7.58E-01 3. 09E+OO 3.09E+OO miss 92.80 2.10 7.86E-01 3.14E+OO miss 112. 81 0.21 5.06E+OO 2.12E+Ol miss
+
U-235 143.76
- 10. 96 7.87E-02 7.00E-02 3.14E-01 miss 163.33 5.08 4.03E-02 6.23E-01 miss 185,71 57.20 5.66E-02 7.00E-02 miss 202.11
- 1. 08
-4.63E-01
- 2. 61E+OO miss 205.31 5.01
-1.56E-01 4. 94E-01 miss
+
Am-241 59.54 35.90
- 1. 21E-01 8.34E-01 8.34E-01 miss
+
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum
= MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent wlth Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[161]
60 55 50 45 40 35 II)
.j..l a:
C:
- I
~
B 30
..c a:
X
~
..c 25 20 15 10 5
0 1000 2000 3000 0000014758.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :600. 900 sec start:
1: -0. l(kev) stop : 8192: 2047.O(kev)
Acq. start :wed Apr 27 15: 17: 1~ 2016 6000 7000 8000
[162]
dt?7t?orn 3:47:51PM 7\\pex-Gamma Analysis Report for 27-Apr-16-10018 L310223AFRGS013SS (DRIED)
GAMMA SPECTRUM ANALYSIS Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live Time Real Time Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description Sample Number
- 27-Apr-16-10018
- L310223AFRGS013SS (DRIED)
- 1 L 130G Soil Sample 1.568E+03 grams
- Default
- 4/25/2016 12:35:00PM
- 4/27/2016 3:37:14PM
- 130G 1 L Sand Sample
- JWelch
- P11314X2
- 130G Sand i 600.0 seconds
- 600.5 seconds
- 0.09%
- 2.80
- 120-8192
- 120-8192
- 1.000FWHM
- 1/27/2016
- 11/26/2012
- 14759 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 3:47:18PM Ji Peak Analysis From Channel
- 120
/7 Peak Analysis To Channel
- 8192 o/-
Tentative NID Library
- C:\\Canberra\\Apex\\Root\\Default\\Library\\Zion Lib-BNL.NLB l/- ') 7-1/ A Peak Match Tolerance
- 1.000FWHM (j
/'f" Pagel of8
[163]
Analysis Report for 27-Apr-16-10018 L310223AFRGS013SS (DRIED)
Peak Energy ROI No.
{keV) start 1
238.66 951 -
2 352.07 1402 -
3 609.44 2430 -
4 911. 4 7 3640 -
5 1461.42 5836 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 960 1414 2442 3650 5854 4/27/2016 3:47:51PM Peak Net Peak Net Area Centroid Area Uncertainty 954.95 6.35E+O l
- 22. 01 1408.08 5.llE+Ol 17.20 2436.69 3.34E+Ol 12.57 3644.38 2.13E+Ol 9.51 5845.03 l.50E+D2 25.75 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Page 2 of8 Continuum Tentative Counts Nuclide 4.90E+Ol Pb-212 1.98E+Ol Pb-2 1.,J Bi-211 5.llE+OO Bi-214 1.47E+OO Ac-228 1.32E+Ol K-40 Activity Coinc Name Confidence (keV)
(pCilgrams)
Uncertainty Corr K-40 0.97 1460.82
- 10. 66 5.35E+OO
- 1. 03E+OO miss Bi-211 0.94 351.07 13.02 5.63E-01 2.lOE-01 miss Pb-212
- 1. 00 115.18 0.60 238.63 43.60 1.61E-01
- 6. 1 6E-02 miss 300.09 3.30 Bi-214
- 1. 00 609.32 45.49 1.55E-01 6.lOE-02 miss 768.36
- 4. 89 806.18
- 1. 26 934.06
- 3. 11 1120. 29
- 14. 92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377.67 3.99 1385. 31 0.79 1401.52
- 1. 33 1 407.99 2.39 1509.21 2.13 1661.27
- 1. 05 1729.59 2.88 1764.49 15.30 1847.43 2.03
[164]
Analysis Report for 27-Apr-16-10018 L310223AFRGS013SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214
- 1. 00 2118. 51 Pb-214 0.5 1 241.99 295.22 351.93 785.96 Ac-2 28 0.99 129.07 209.25 270.24 32 8.00 338.32 409.46 463.00 794.95 911. 20 964. 77 968.97 1588.2 0
- = Energy line found in the spectrum.
- ;; Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000FWHM Nuclide confidence index threshold = 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
1.16 7.25 18.42
- 35. 60
- 1. 06 2.42 3.89 3.46 2.95 11.27
- 1. 92 4.40
':l. 25 25.80 4.99
- 15. 80 3.22 miss ;; Nuclide energy was not found in the coincidence library.
4/27/2016 3:47:51PM Page 3 of8 Activity Activity Caine (pCilgrams)
Uncertainty Corr 2.06E-Ol 7. 67E-02 miss 2.2 7E-01
- l. 03E- 01 miss INTERFERENCE CORRECTED REPORT Nuclide Nuclide Wt mean Wt mean Comments Name Id Activity Activity Confidence (pCilgrams)
Uncertainty K-40 0.978 5.35E+OO
- 1. 03E+OO
?
Bi-211 0.940 5.63E-01 2.lOE-01 Pb-212
- 1. 000 1.61E-01 6.16E-02 Bi-214
- 1. 000 1.55E-01 6.lOE-02
?
Pb-214 0.512 2.06E-01 7.67E-02 Ac-228 0.999 2.27E-Ol 1.03E-01
[165]
Analysis Report for 27-Apr-16-10018 L310223AFRGS013SS {DRIED}
?
= nuclide is part of an undetermined solution X
= nuclide rejected by the interference analysis
@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 4/27/2016 3:47:51 PM Page 4 of8
[166]
4/27/2016 3:47:51 PM Analysis Report for 27-Apr-16-10018
+
+
+
+
+
+
+
+
+
L310223AFRGS013SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channer Peak No.
Energy (keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 3:47:18PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCVgrams)
(pCi/grams)
(pCi/grams)
K-40 1460.82 10.66 5.35E+OO 5.SSE-01 5.55E-01 Cr-51 320.08 9.91
-6.20E-02 2.39E-Ol 2.39E-01 Mn-54 834.85 99.98
-l.41E-03 3.13E-02 3.13E-02 Co-58 810.76 99.45
-2.83E-03 2.43E-02 2.43E-02 1674.73 0.52 O.OOE+OO 2.25E+DO Co-60 1173.23 99.85
-1.91E-02 9.58E-03 3.03E-02 1332.49 99.98 O.OOE+OO 9.58E-03 Nb-94 702.65 99.81
-2.16E-03 2.88E-02 3.04E-02 871.09 99.89
-1.78E-03 2.88E-02 Ag-108m 79.13 6.60
-2.26E-01 2.21E-02 5.41E-01 433.94 90.50
-8.27E-04
- 2. 21E-02 614.28 89.80 2.45E-03 3.09E-02 722.94 90.80
-1.32E-02 3.12E-02 Sn-113 255.13
- 2. 11 8.41E-02 2.90E-02 l.18E+OO 391. 7 0 64.97
-1.42E-02 2.90E-02 Cs-134 475.36
- 1. 48
-5.93E-01 2.58E-02
- l. 29E+OO 563.25 8.34
-7.47E-02 3.14E-01 569.33 15.37
-3.14E-02 l.41E-01 Page 5 of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss 604. 72 97.62 2.79E-03 2.58E-02 miss
[167]
4/27/2016 3:47:51PM Page 6 of8 Analysis Report for 27-Apr-16-10018 L310223AFRGS013SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCilgrams)
(pCilgrams)
Corr Cs-134 795.86 85.46 9.82E-03 2.58E-02 4.43E-02 miss 801.95 8.69
-l.21E-01 2.14E-01 miss 1038.61 0.99 5.07E-02 2.83E+OO miss 1167. 97
- 1. 79
-4.67E-01
- l. 95E+OO miss 1365.19 3.02 l.20E-01 8.80E-01 miss
+
Cs-137 661. 66 85.10 3.70E-03 3.14E-02 3.14E-02 miss
+
Eu-152 121.78 28.67 6.75E-03 5.18E-02 8.SlE-02 miss 244.70 7.61
-2.79E-02 2.68E-01 miss 295.94 0.45 4.71E+OO 7.66E+OO miss 344.28 26.60 5.31E-03 8.85E-02 miss 367.79 0.86 1.12E-01 3.llE+DO miss 411.12 2.24
-4.20E-01 7.71E-01 miss 443.96 2.83
-1.03E-01 6.43E-01 miss 488.68 0.42
-5.40E-01 6.46E+OO miss 563.99 0.49
- 1. 79E+OO 6.44E+OO miss 586.26 0.46
-1.0SE+OO 6.28E+OO miss 678.62 0.47 5.99E-01 6.76E+DO miss 688.67 0.86
-8.20E-01 2.47E+OO miss 719.35 0.28 4.70E+OO l.40E+Ol miss 778.90 12.96 O.OOE+OO 5.18E-02 miss 810.45 0.32 4.40E-02 8.54E+OO miss 867.37 4.26 7.03E-02 7.SlE-01 miss 919.33 0.43 5.40E-02 9.14E+OO miss 964. 08 14.65 2.28E-02 2.lOE-01 miss 1085.87 10.24
-3.89E-02 2.81E-01 miss 1089.74
- 1. 73 3.84E-01 2.15E+OO miss 1112.07
- 13. 69
-2.38E-02 2.76E-01 miss 1212.95
- 1. 43
- 1. 89E-Ol 3.29E+OO miss 1249.94 0.19 8.55E-Ol l.93E+Ol miss 1299. 14
- 1. 63
-3.06E-01 l.99E+OO miss 1408.01
- 21. 07
-2.25E-02 l.88E-01 miss 1457.64 0.50
-l.69E+Ol 9.87E+OO miss 1528.10 0.28
-l.19E+OO l.02E+Ol miss
+
Eu-154 123.07 40.40 l.53E-02 5. 90E-02 5.90E-02 miss 247.93 6.89
-7.73E-02 2.75E-01 miss 591.76 4.95
-l.67E-02 5.00E-01 miss 692.42
- 1. 78 7.17E-03 l.39E+OO miss 723. 30 20.06
-6.37E-03 l.41E-01 miss 756.80 4.52 9.86E-02 7.59E-01 miss 873.18 12.08
-7.38E-02 2.38E-01 miss 996.29 10.48
-3.88E-02
- 3. OlE-01 miss 1004.76 18.01
-3.68E-02 2.31E-01 miss 1274.43 34.80 4.23E-03 7.26E-02 miss 1596.48
- 1. 80 3.67E-Ol 2.lOE+OO miss
+
Eu-155 45.30
- 1. 31
-2.12E+OO l.29E-01 4.16E+OO miss 60.01
- 1. 22
-2.07E+OO 7.39E+OO mis s 86.55
- 30. 70
- 6. llE-02 l.29E-Ol miss 105.31
- 21. 10 5.92E-02 l.36E-01 miss
+
Tl-208 583.19
- 85. 00 5.71E-02 6.34E-02 6.34E-02 miss
+
Bi-211 351.07 13.02 5.63E-Ol 2.03E-01 2.03E-01 miss
+
Pb-211 404.85 3.78
- 7. 96E-02 5.03E-01 5.03E-01 miss
[168]
4/27/2016 3:47:51PM Page 7 of8 Analysis Reporf: for 27-Apr-16-10018 L310223AFRGS013SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCUgrams)
(pCUgrams)
(pCi!grams)
Corr Pb-211 427.09
- 1. 76
-2.24E-01 5.03E-01 1. OlE+OO miss 832.01 3.52 9.81E-03 9.64E-01 miss
+
Bi-212 39.86
- 1. 06
-l.70E+OO 5.33E-01 6.22E+OO miss 727. 33 6.67 2.23E-01 5.33E-Ol miss 785.37 1.10 7.39E-01
- 2. 96E+OO miss 1620.50
- 1. 47 5.58E-01 2.59E+OO miss
+
Pb-212 115.18 0.60
-4.32E-02 7.02E-02
- 3. 68E+OO miss 238.63 43.60 1.61E-01 7.02E-02 miss 300.09 3.30 1.75E-01 8.76E-01 miss
+
Pb212-XR 74.82 10.28 3.13E-01 3.14E-Ol 6.59E-01 miss 77. 11 17.10 l.22E-01 3.14E-01 miss 87.35 3.97 4.28E-01 9.40E-Ol miss 89.78
- 1. 46
-2.47E-01 2.33E+OO miss
+
Bi-214 609.32 45.49 1.55E-01 4.98E-02
- 4. 98E-02 miss 768.36 4.89
- 1. 09E-01 6.03E-01 miss 806.18
- 1. 26 5.21E-01 3.0lE+OO miss 934.06
- 3. 11 2.91E-Ol 1.27E+OO miss 1120.29 14.92 l.75E-01
- 3. 98E-01 miss 1155. 21
- 1. 63 l.15E+OO
- 2. 96E+OO miss 1238.12 5.83
-2.06E-ul 5.36E-01 miss 1280.98
- 1. 43 2.75E-01 2.59E+OO miss 1377. 67 3.99
-7.79E-02 6.69E-01 miss 1385. 31 0.79 4.59E-01 3.38E+OO miss 1401.52
- 1. 33 3.26E-01 3.32E+OO miss 1407.99 2.39
-1.98E-01 l.66E+OO miss 1509.21 2.13 O.OOE+OO 4.94E-01 miss 1661. 27
- 1. 05 1.50E-01 2.94E+OO miss 1729.59 2.88
-2.62E-01 l.lOE+OO miss 1764.49 15.30 l.70E-01 4.30E-01 miss 1847.43 2.03 6.68E-01 2.40E+OO miss 2118.51 1.16 O.OOE+OO O.OOE+OO miss
+
Pb-214 241.99 7.25 l.68E-01 7. 41E-02 4.27E-01 miss 295.22 18.42 1.80E-01 2.04E-Ol miss 351.93 35.60 2.06E-01 7.41E-02 miss 785. 96
- 1. 06
- 6. llE-01 3.08E+OO miss Pb214-XR 74.82 5.80 5.54E-01 5.53E-01 l.17E+OO miss 77. 11 9.70 2.14E-01 5.53E-01 miss 87.35 2.24 7.59E-01 1.67E+OO miss 89.78 0.82
-4.40E-01 4.16E+OO miss
+
Ra-226 186.21 3.64 1.72E-01 6.53E-01 6.53E-01 miss
+
Ac-228 129.07 2.42 8.69E-02
- 6. 96E-02 9.14E-01 miss 209.25 3.89 l.19E-01 6.SOE-01 miss 270.24 3.46 2.32E-01 7.BOE-01 miss 328.00 2.95 6.37E-01 9.88E-01 miss 338.32
- 11. 27 2.17E-01 3.04E-01 miss 409.46
- 1. 92 4.73E-01 1.39E+OO miss 463.00 4.40 2.29E-01 7.70E-Ol miss 794.95 4.25 4.70E-01 9.85E-01 miss 911.20 25.80 2.27E-01
- 6. 96E-02 miss 964. 77 4.99 6.38E-03 6.18E-01 miss 968. 37 15.80 2.48E-02 2.38E-01 miss
[169]
4/27/2016 3:47:51PM Page 8 of 8 Analysis Report, for 27-Apr-16-10018 L310223AFRGS013SS (DRIED)
Nuclide Energy Yield{%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCi/grams)
(pCi!grams)
Corr rtC-228 1588.20 3.22 O.OOE+OO
- 6. 96E-02 3.40E-01 miss
+
Pa-231 27.36 10.30 O.OOE+OO
- 1. 09E-01 1.09E-01 miss 283.69
- 1. 70
-2.07E-01 l.22E+OO miss 300.07 2.47 2.33E-01 l.17E+OO miss 302.65 2.20
-4.84E-02 8.84E-01 miss 330.06
- 1. 40
-9.07E-01 1.38E+OO miss
+
Th-234 92.38 2.13 4.95E-01 1. 73E+OO 1.80E+OO miss 92.80 2.10
-3.49E-02 1.73E+OO miss 112.81 0.21 4.53E-01 l.19E+Ol miss
+
U-235 143.76 10.96
-4.31E-03 4.06E-02 1.89E-01 miss 163.33 5.08
- 1. 04E-02 4.18E-Ol miss 185.71 57.20 7.35E-03 4.06E-02 miss 202. 11
- 1. 08 5.48E-01 1.83E+OO miss 205.31 5.01 8.66E-02 4.lOE-01 miss
+
Am-241 59.54 35.90 l.OOE-01 3. 00E-01 3.00E-01 miss
+
.,,. Nuclide identified during the nuclide identification
= Energy line found in the spectrum
"' MDA value not calculated
"' Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[170]
40 35 Vl
+-'
C:
- s 8 30 25 20
~
~
..c...
15 10
- ~
0 1000
~
J:
- i a,
2000 3000 0000014759.CNF 4000 channel 5000 Live Time
- 60-0.000 sec Real Time
- 600.520 sec start:
1: -0.2(kev)
Stop : 8l92:2047.4(kev)
Acq. start :wed Apr 27 15: 37: 14 2016 6000 7000 8000
[171]
4/27/2016 3:48:28PM Page 1 of8
--=----==. ~.7\\pex-Gamma Analysis Report for 27-Apr-16-10019 L310223AFRGS014SS (DRIED)
Sample Identification Sample Description Sample Type Unit Sample Point Sample Size Facility Sample Taken On Acquisition Started Procedure Operator Detector Name Geometry Live lime Real lime Dead Time Peak Locate Threshold Peak Locate Range (in channels)
Peak Area Range (in channels)
Identification Energy Tolerance GAMMA SPECTRUM ANALYSIS
- 27-Apr-16-10019
- L310223AFRGS014SS (DRIED)
- 1 L 130G Soil Sample 1.848E+03 grams
- Default
- 4/25/2016 1:55:00PM
- 4/27/2016 3:37:25PM
,; 130G 1L Sand Sample
,; JWelch
- P408188
- 130G Sand
- 600.0 seconds
- 601.0 seconds
- 0.16 %
- 2.80
- 120- 8192
. 120-8192
- 1.000FWHM
.1JJ
~--"i.. r&
Energy Calibration Used Done On Efficiency Calibration Used Done On Efficiency Calibration Description
- 1/27/2016
- 1/5/2015
~_5;?~
Sample Number
- 14760 PEAK WITH NID REPORT Peak Analysis Performed on
- 4/27/2016 3:47:57PM Peak Analysis From Channel Peak Analysis To Channel
- 120
- 8192 Tentative NID Library Peak Match Tolerance
- C :\\Ca nberra\\Apex\\Root\\Default\\Libra ry\\Zion Lib-B NLN LB
- 1.000FWHM
[172]
Analysis R~port for 27-Apr-16-10019 L310223AFRGS014SS (DRIED)
Peak Energy ROI No.
(keV) start 1
185.94 739 -
2 238.55 948 -
3 295.11 1176 -
4 351. 86 1398 -
5 583.00 2325 -
6 609.20 2431 -
7 768.36 3069 -
8 1460.51 5832 -
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma ROI end 750 962 1189 1414 2337 2444 3078 5851 4/27/2016 3:48:28PM Peak Net Peak N,:,t.4,,,.~
Centroid Area Uncertainty 744.43 2.72E+Ol 27.58 954.68
- 1. 46E+02 41.91 1180.78 6.58E+O l 24.01 1407.62
- 9. 77E+O l 27.39 2331.76 6.76E+Ol 18.16 2436.55 7.07E+Ol 20.98 3073.09 1.31E+Ol 8.23 5843.01 1.27E+02
- 23. 63 NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LlB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield(%)
Activity Page 2 of8 r.nnfinuurn Tentative Counts Nuclide
- 1. 96E+02 Pb-212 5.64E+Ol Pb-214 Eu-152 6.67E+Ol Pb-214 Bi-21 1 1.28E+Ol Tl-208 3.25E+Ol Bi-214 3.80E+OO Bi-214
- 1. 09E+Ol K-40 Activity Coinc Name Confidence (keV)
(pCilgrams)
Uncertainty Corr K-40 0.99 1 460.82
- 10. 66 4.24E+OO 8.73E-01 miss Tl-208 0.99 583.19
- 85. 00 1.53E-01 4.49E-02 miss Pb-212
- 1. 00 115.18 0.60 238.63 43.60 3.54E-01 l. 17E-01 miss 300.09 3.30 Bi-214
- 1. 00 609.32 45.49 3.07E-01 9.84E-0:2 miss 768.36 4.89 6.18E-01 3.95E-01 miss 806.18
- 1. 26 934.06
- 3. 11 1120.29 14.92 1155. 21
- 1. 63 1238.12 5.83 1280.98
- 1. 43 1377.67 3.99 1385.31 0.79 1401. 52
- 1. 33 1407.99 2.39
[173]
Analysis Report for 27-Apr-16-10019 L310223AFRGS014SS (DRIED)
?
nuclide is part of an undetermined solution X
nuclide rejected by the interference analysis nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma 4/27/2016 3:48:28PM Page4 of8
[174]
4/2//2016 3:48:28PM Analysis R~port for 27-Apr-16-10019
+
+
+
+
+
+
+
+
+
L310223AFRGS014SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy {keV)
All peaks were identified.
M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 3:47:57PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCilgrams)
(pCi/grams)
(pCi/grams)
K-40 1460.82
- 10. 66 4.24E+OO 4.89E-01 4.89E-01 Cr-51 320.08 9.91 2.22E-02 3.25E-01 3.25E-01 Mn-54 834.85 99.98 8.53E-03 3.89E-02 3.89E-02 Co-58 810.76 99.45
-8.19E-04 3.69E-02 3.69E-02 1674.73 0.52
- 1. 56E+OO 7.26E+OO Co-60 1173.23 99.85 9.41E-03 3.59E-02 5.12E-02 1332. 49 99.98
-2.06E-03 3.59E-02 Nb-94 702.65 99.81 l.35E-03 3.27E-02 3.27E-02 871.09 99.89 3.35E-03 3.30E-02 Ag-108m 79.13 6.60
-l.37E-01 3.0lE-02 1.14E+OO 433.94 90.50 6.92E-04
- 3. OlE-02 614.28 89.80
-8.79E-03 3.33E-02 722. 94 90.80
-1.43E-02 3.45E-02 Sn-113 255.13 2.11
-4.33E-01 4.58E-02 l.32E+D0 391.70 64.97 4.94E-03 4.58E-02 Cs-134 475.36
- 1. 48
-7. 21E-01 3.36E-02 l.70E+OO 563.25 8.34 5.80E-02 3.57E-01 569.33 15.37 3.20E-02 2.23E-01 604. 72 97.62
-3.95E-03 3.36E-02 Page 5 of8 Tolerance Nuclide Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss miss
[175]
4/27/2016 3:48:28PM Page 6 of 8 Analysis R!ilport for 27-Apr-16-10019 L310223AFRGS014SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCilgrams)
(pCi/grams)
(pCilgrams)
Corr Cs-134 795.86 85.46 9.32E-03 3.36E-02 5.22E-02 miss 801.95 8.69
-5.48E-02 2.55E-01 miss 1038.61 0.99
-8.91E-01 3.08E+OO miss 1167.97
- 1. 79 5.37E-01 2.24E+OO miss 1365.19 3.02 1.23E-01 1.21E+OO miss
+
Cs-137 661.66 85.10 6.88E-03 3.22E-02 3.22E-02 miss
+
Eu-152 121. 78 28.67 3.35E-02 l.15E-01
- 1. 32E-01 miss 244.70 7.61
-l.47E-01 3.39E-01 miss 295.94 0.45 l.SOE+Ol l.15E+Ol miss 344.28 2 6. 60 3.73E-0:2 1.15E-01 miss 367.79 0.86 9.39E-01 3.81E+OO miss 411.12 2.24
-2.16E-01 1.31E+OO mist 443.96 2.83
- 3. 71E-Ol l.06E+OO miss 488.68 0.42
-2.27E+OO 6.08E+OO miss 563.99 0.49
-3.49E-01 5.74E+OO miss 586.26 0.46
-3.71E+OO 6.65E+OO miss 678.62 0.47
-2.05E+OO 6.77E+OO miss 688.67 0.86
-4.63E-02 4.17E+OO miss 719.35 0.28
-3.04E+OO l.04E+01 miss 778.90
- 12. 96
-7.50E-02 2.36E-01 miss 810.45 0.32
-1.55E+OO 1.05E+Ol miss 867.37 4.26 8.57E-02 7.06E-01 miss 919.33 0.43 l.OSE+OO 6.56E+OO miss 964.08 14.65 2.32E-01 4.13E-01 miss 1085.87 10.24 8.88E-02 4.0lE-01 miss 1089.74
- 1. 73 1.93E-01 2.38E+OO miss 1112. 07
- 13. 69
-1.30E-02 2.83E-01 miss 1212.95
- 1. 43 2.67E-01 2.64E+OO miss 1249.94 0.19
-l.59E+OO 2.22E+Ol miss 1299.14
- 1. 63
-4.90E-01 1.48E+OO miss 1408.01
- 21. 07 1.29E-Ol 2.75E-01 miss 1457.64 0.50 O.OOE+OO 1.70E+Ol miss 1528.10 0.28 5.62E-01 9.66E+OO miss Eu-154 123.07 40.40 1.90E-02 8, 75E-02 8.75E-02 miss 247.93 6.89 9.04E-02 4.23E-01 miss 591. 76 4.95 2.98E-Ol 6.83E-01 miss 692.42
- 1. 78
-8.49E-01 l.46E+OO miss 723.30 20.06 O.OOE+OO l.84E-Ol miss 756.80 4.52 O.OOE+OO l.37E-Ol miss 873.18 12.08
-3.30E-02 l.93E-01 miss 996.29 10.48 9.55E-02 3.45E-01 miss 1004.76 18.01 3.90E-02 2.56E-01 miss 1274.43 34.80 l.90E-02 1.00E-01 miss 1596.48
- 1. 80
-2.40E-01 l.98E+OO miss
+
Eu-155 45.30
- 1. 31
- 4. 61E+OO 2.12E-01 2.16E+Ol miss 60.01
- 1. 22 8.24E+OO 2.29E+Ol miss 86.55 30.70
-l.38E-02 2.14E-01 miss 105.31 21.10 l.12E-Ol 2.12E-01 miss
+
Tl-208 583.19 85.00 1.53E-Ol 3.48E-02 3.48E-02 miss
+
Bi-211 351. 07 13.02 1.0lE+OO 3.52E-01 3.52E-01 miss
+
Pb-211 404.85 3.78 l.19E-01 7.45E-01 8.65E-01 miss
[176]
4/27/2016 3:48:28PM Page 7 of8 Analysis Report for 27-Apr-16-10019 L310223AFRGS014SS (DRIED)
Nuclide Energy Yield(OJ:,)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi/grams)
(pCilgrams)
(pCi/grams)
Corr Pb-211 427.09
- 1. 76
-8.80E-02 7.45E-01 l.40E+OO miss 832.01 3.52
-3.50E-01 7.45E-01 miss
+
Bi-212 39.86
- 1. 06 l. lOE-01 6.92E-01 2.25E+Ol miss 727. 33 6.67 8.83E-02 6.92E-01 miss 785.37
- 1. 10 9.22E-01 3.70E+OO miss 1620.50
- 1. 47 9.87E-02
- 2. 44E+OO miss
+
Pb-212 115.18 0.60 6.93E-01
- 1. 43E-01 6.25E+OO miss 238.63 43.60 3.54E-01 l.43E-01 miss 300.09 3.30 2.22E-01 1. lOE+OO miss
+
Pb212-XR 74.82 10.28 3.35E-01 7.25E-01 l.20E+OO miss 77. 11 17.10 4.83E-01 7.25E-01 miss 87.35 3.97 1.16E+OO 1.77E+OO miss 89.78
- 1. 46
- 1. 72E+OO 4.08E+OO miss
+
Bi-214 609.32 45.49 3.07E-01
- l. OlE-01 1.0lE-01 miss 768.36
- 4. 89 6.18E-01 4.32E-Ol miss 806.18
- 1. 26
-l.81E-01 2.27E+OO miss 934.06 3.11
-l.lOE-01 l.02E+OO miss 1120.29
- 14. 92 4.05E-01 4.99E-01 miss 1155. 21
- 1. 63 5.97E-02 2.23E+OO miss 1238.12 5.83 6.73E-01 1.13E+OO miss 1280.98
- 1. 43 9.38E-01 3.19E+OO miss 1377. 67 3.99 3.67E-01 l.29E+OO miss 1385. 31 0.79
-3.09E-01 4.02E+OO miss 1401.52
- 1. 33 8.09E-Ol 3.13E+OO miss 1407.99 2.39 l.13E+OO 2.42E+D0 miss 1509.21 2.13 3.44E-01 l.60E+OO miss 1661. 27
- 1. 05 2.83E-01 3.5DE+OO miss 1729.59 2.88
-7.07E-01 l.04E+OO miss 1764.49 15.30 4.39E-D1 6.35E-Ol miss 1847.43 2.03 O.OOE+OO 5.68E-01 miss 2118.51
- 1. 16 O.OOE+OO O. OOE+OO miss Pb-214 241.99 7.25 3.79E-01
- 1. 29E-01 5.65E-01 miss 295.22 18.42 4.32E-Ol 2.09E-01 miss 351.93 35.60 3.71E-01 l.29E-Ol miss 785.96
- 1. 06 1.84E-01 3.32E+OO miss Pb214-XR 74.82 5.80 5.95E-01 1.28E+OO 2.13E+OO miss 77. 11 9.70 8.52E-01 1.28E+OO miss 87.35 2.24 2.05E+OO 3.14E+OO miss 89.78 0.82 3.06E+OO 7.26E+OO miss
+
Ra-226 186.21 3.64 7.04E-01
- 1. 15E+OO 1.15E+OO miss
+
Ac-228 129.07 2.42
- 5. 71E-01 3.19E-01 1.47E+OO miss 209.25 3.89 4.87E-Ol 9.lOE-01 miss 270.24 3.46
-2.02E-01 9.03E-D1 miss 328.00 2.95 2.16E-D1 l.12E+D0 miss 338.32
- 11. 27 5.73E-01 4.77E-01 miss 409.46
- 1. 92 6.15E-01 l.67E+OO miss 463.00
- 4. 40 8.67E-01 l.08E+OO miss 794.95 4.25 7.93E-01
- 1. 22E+OO miss 911. 20 25.80 3.21E-Ol 3.19E-01 miss 964.77 4.99 3.38E-Ol l.18E+OO miss 968.97 15.80
- 4. 96E-01 5.17E-Ol miss
[177]
4/27/2016 3:48:28PM Page 8 of8 Analysis Report for 27-Apr-16-10019 L310223AFRGS014SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Caine Name (keV)
(pCilgrams)
(pCi!grams)
(pCi!grams)
Corr Ac-228 1588.20 3.22 5.92E-01 3.19E-01 1.55E+OO miss
+
Pa-231 27.36 10.30 4.04E-01
- l. 22E+OO 2.71E+OO miss 283.69
- 1. 70
-5.38E-01 1.31E+OO miss 300.07 2.47 2.97E-01 1.48E+OO miss 302.65 2.20
-4.33E-01 1.22E+OO miss 330.06
- 1. 40 3.07E-Ol 2.27E+OO miss
+
Th-234 92.38 2.13 4.93E-01 3. 04E+OO 3.04E+OO miss 92.80 2.10 1.14E+OO 3.13E+OO miss 112.81 0.21
-4.38E+OO l.67E+Ol miss
+
0-235 143.76
- 10. 96
- 3. llE-02 7.35E-02 2.95E-01 miss 163.33 5.08 4.87E-02 5.BlE-01 miss 185. 71 57.20 4.48E-02 7.35E-02 miss 202.11
- 1. 08 3.40E-Ol 2.55E+OO miss 205.31 5.01
-9.91E-02 5.20E-01 miss
+
Am-241 59.54 35.90
-2.06E-02 7.54E-01 7.54E-01 miss
+ = Nuclide identified during the nuclide identification
= Energy line found in the spectrum
> = MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
= CAUTION: MDA value is inconsistent with Currie MDA at 95% confidence level Coincidence correction performed.
free = No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[178]
V)
C:
- s 60 55 50 40 35 8 30 25 20 15 10 5
00 1000 2000 3000 0000014760.CNF 4000 channel 5000 Live Time :600.000 sec Real Time :600.980 sec start:
1: -0. l(kev) stop : 8192: 2047.O(kev)
Acq. start :wed Apr 27 15:37:25 2016
= !
6000 7000 8000
[179]
4/27/2016 4 :09:42PM Page2 of8 Analysis Report for 27-Apr-16-10020 L310223AFQGS014SS (DRIED)
Peak Energy ROI ROI Peak NetPeak Net Area Continuum Tentative No.
(keV) start end Centroid Area Uncertainty Counts Nuclide M
1 74.85 297 -
314 300.62 4.93E+Ol 18.18 9.12E+01 Pb214-XR Pb212-XR m
2 77.00 297 -
314 309.24 6.27E+01
- 19. 52 9.26E+Ol Pb214-~~R Pb212-XR 3
238.73 949 -
960 955.22
- 1. 73E+02 35.26 1.10E+02 Pb-212 4
295.28 1175 -
1188 1181.18 5.32E+Ol 22.16 4.97E+Ol Pb-214 Eu-152 5
338.67 1349 -
1361 1354.51 3.68E+Ol 18.65 4.24E+Ol Ac-228 6
352.04 1402 -
1416 1407.97 1.29E+02
- 26. 45 3.70E+Ol Pb-~14 Bi-211 7
510.75 2037 -
2048 2042.21 2.95E+Ol 15.69 2.89E+Ol
- * * *
- AIIIN-.$1(
8 583.12 2324 -
2337 2331. 49 4.25E+Ol 17.03 2.50E+Ol Tl-208 9
609.41 2430 -
2443 2436.56 7.75E+Ol 21.43 3.09E+Ol Bi-214 10 911. 42 3638 -
3650 3644.17 3.83E+Ol 15.02 1.73E+Ol Ac-228 11 969.1 7 3868 -
3882 3875.18 3.90E+01 14.18 1.00E+Ol Ac-228 12 1120.59 4475 -
4486 4480.92 1.95E+Ol 10.32
- 6. 96E+OO Bi-214 13 14 61. 25 5836 -
5854 5844.33
- 1. 4 7E+02 25.37 l.23E+Ol K-40
=t'P~
M = First peak in a multiplet region
,,,.wr, m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma NUCLIDE IDENTIFICATION REPORT Nuclide Library Used
- C:\\Canberra\\Apex\\Root\\Default\\Library\\ZION LIB-BNL.NLB IDENTIFIED NUCLIDES Nuclide Id Energy Yield{%)
Activity Activity Coinc Name Confidence
{keV)
(pCilgrams)
Uncertainty Corr K-40 0.98 1460.82
- 10. 66 4.84E+OO
- 9. 37E-01 miss Tl-208
- 1. 00 583.19 85.00 9.45E-02
- 3. 96E-02 miss Pb-212
- 1. 00 115.18 0.60 238.63 43.60 4.07E-01
- 1. 06E-01 miss 300.09 3.30 Pb212-XR
- 1. 00 74.82
- 10. 28
- 9. 16E-01 3.87E-01 miss 77. 11 17.10
- 6. 49E-01 2.42E-Ol miss 87.35 3.97 89.78
- 1. 46 Bi-214
- 0. 99 609.32 45.49 3.32E-01
- 1. 00E-01 miss 768.36 4.89
[180]
Analysis Report for 27-Apr-16-10020 L310223AFQGS014SS (DRIED)
Nuclide Id Energy Name Confidence (keV)
Bi-214 0.99 806.18 934.06 1120.29 1155. 21 1238.12 1280.98 1377.67 1385. 31 1401. 52 1407.99 1509.21 1661.27 1729.59 1764.49 1847.43 2118. 51 Pb-214 0. 99 241.99 295.22 351.93 785. 96 Ac-228 0.99 129.07 209.25 270.24 328.00 338.32 409.46 463.00 794.95 911. 20 964.77 968. 97 1588.20
- = Energy line found in the spectrum.
- = Manually added nuclide.
? = Manually edited nuclide.
@ = Energy line not used for Weighted Mean Activity Energy Tolerance: 1.000FWHM Nuclide confidence index threshold= 0.30 Errors quoted at 2.000sigma Coincidence correction performed.
free = No coincidence correction required.
Yield(%)
- 1. 26 3.11 14.92
- 1. 63 5.83
- 1. 43 3.99 0.79
- 1. 33 2.39 2.13
- 1. 05 2.88 15.30 2.03 1.16 7.25 18.42 35.60
- 1. 06 2.42 3.89 3.46 2.95
- 11. 27
- 1. 92 4.40 4.25 25.80 4.99 15.80 3.22 miss = Nuclide energy was not found in the coincidence library.
4/27/2016 4:09:42PM Page :l of8 Activity Activity Coinc (pCi!grams)
Uncertainty Corr 3.83E-01
- 2. 05E-01 miss 3.41E-Ol
- 1. 52E-01 miss 4.83E-O:
- l. 25E-01 miss 4.23E-01 2.25E-01 miss 3.80E-Ol
- 1. 52E-01 miss 6.58E-01 2.46E-01 miss INTERFERENCE CORRECTED REPORT
[181]
Analysis Report for 27-Apr-16-10020 X
X L310223AFQGS014SS (DRIED)
Nuclide Name K-40 Tl-208 Bi-211 Pb-212 Pb212-XR Bi-214 Pb-214 Pb214-XR Ac-228 Nuclide Id Confidence
- 0. 989
- 1. 000
- 0. 943
- 1. 000
- 1. 000
- 0. 999
- 0. 999
- 1. 000
- 0. 998
?
= nuclide is part of an undetermined solution X
= nuclide rejected by the interference analysis 4/27/2016 4:09:42PM Wt mean Wt mean Activity Activity (pCilgrams)
Uncertainty 4.84E+OO 9.37E-01 9.45E-02 3.96E-02 4.07E-01 1.06E-01 7.24E-01 2.0SE-01 3.42E-01 9.00E-02 4.26E-01 9.68E-02 4.48E-01
- 1. 12E-01
==
nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 2.000sigma Page 4 of8 Comments
[182]
4/27/2016 4:09:42PM Analysis Report for 27-Apr-16-10020
+
+
+
+
+
+
+
+
+
L310223AFQGS014SS (DRIED)
Peak Locate Performed on Peak Locate From Channel Peak Locate To Channel Peak No.
Energy (keV) 7 510.75 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 2.000sigma UNIDENTIFIED PEAKS
- 4/27/2016 4:09:10PM
- 120
- 8192 Peak CPS(%)
Peak Size (CPS)
Uncertainty 4.92424E-02 26.56 Peak Type NUCLIDE MDA REPORT Nuclide Library Used
- C :\\Ca nberra\\Apex\\Root\\Default\\Li brary\\ZI ON LIB-BN L. N LB Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Name (keV)
(pCUgrams)
(pCi/grams)
(pCilgrams)
K-40 1460.82 10.66 4.84E+OO
- 4. 96E-Ol
- 4. 96E-01 Cr-51 320.08 9.91
-1.32E-01 2.21E-01 2.21E-01 Mn-54 834.85
~9.98 2.12E-02 4.86E-02 4.86E-02 Co-58 810.76 99.45 5.65E-03 4.04E-02 4.04E-02 1674.73 0.52 4.81E-01 5.66E+OO Co-60 1173.23 99.85 7.68E-03 3.53E-02 5.04E-02 1332.49 99.98 7.34E-03 3.53E-02 Nb-94 702.65 99.81 9.31E-03 2.98E-02 3.23E-02 871. 09 99.89 9.91E-03 2.98E-02 Ag-lOBm 79.13 6.60
-9.64E-02 2.86E-02 7.44E-01 433. '.)4 90.50 6,44E-03 3.09E-02 614.28 89.80
-4.BOE-03 2.86E-02 722. 94 90.80
-2.0lE-03 2.89E-02 Sn-113 255.13 2.11 6.22E-01 4.21E-02 l.45E+OO 391.70 64.97 8.58E-04 4.21E-02 Cs-134 475.36
- 1. 48
-l.31E+OO 3.32E-02 1.46E+OO 563.25 8.34 1.63E-02 3.70E-01 569.33 15.37 4.BSE-03 1.46E-01 Page 5 of8 Tolerance Nuclide
/1-tv 1/-5( (
Coinc Corr miss free miss miss miss miss miss miss miss miss miss miss miss free free miss miss miss
[183]
4/27/2016 4:09:.42PM Page 6 of8 Analysis Report for 27-Apr-16-10020 L310223AFQGS014SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCVgrams)
(pCUgrams)
(pCilgrams)
Corr Cs-134 604. 72 97.62
-1.59E-03 3.32E-02 3.32E-02 miss 795.86 85.46 1.86E-02 4.96E-02 miss 801.95 8.69
- 1. 32E-01 4.71E-01 miss 1038. 61 0.99 2.82E-01 3.39E+OO miss 1167.97
- 1. 79 l.99E-01 3.05E+OO miss 1365. 19 3.02 l.58E-02 i.03E+OO miss
+
Cs-137 661.66 85.10 l.63E-02 4.39E-02 4.39E-02 miss
+
Eu-152 121.78 28.67 2.39E-02 7.58E-02 l.OOE-01 miss 244.70 7.61
-5.27E-02 3.43E-01 miss 295.94 0.45 l.03E+Ol l.03E+Ol miss 344.28 26.60 4.34E-03 l.08E-01 miss 367.79
- 0. 86
-l.91E-01 3.30E+OO miss 411. 12 2.24
-4.54E-01 8.70E-Ol miss 443. 96 2.83 3.68E-01 8.78E-Ol miss 488.68 0.42
-l.99E+OO 4.79E+OO miss 563.99 0.49 3.0lE-01 5.97E+OO miss 586.26 0.46
-1.63E+OO 6.20E+OO miss 678.62 0.47
-5.92E-01 6.26E+OO miss 688.67 0.86 2.67E-01 3.48E+OO miss 719.35 0.28 5.73E+OO
- 1. 42E+Ol miss 778.90
- 12. 96 7.39E-03 2.13E-01 miss 810.45 0.32 2.00E+OO 1.23E+Ol miss 867.37 4.26 4.06E-02 7.60E-01 miss 919.33 0.43
-1.lOE+OO 6.47E+OO misc:
964. 08 14.65 1.34E-01 3.16E-Ol miss 1085.87 10.24 O.OOE+OO 7.58E-02 miss 1089.74
- 1. 73 9.54E-01 2.50E+OO miss 1112. 07 13.69
-1.16E-01 1.98E-01 miss 1212.95
- 1. 43
- 1. 96E-01 3.05E+OO miss 1249.94 0.19
-5.47E+OO 1.79E+Ol miss 1299.14
- 1. 63 9.45E-02 2.14E+OO miss 1408.01 21.07 4.64E-03 1.95E-01 miss 1457.64 0.50
-7.04E+OO 9.15E+OO miss 1528.10 0.28 1.84E-01 l.20E+Ol miss
+
Eu-154 123. 07 40.40 2.44E-02 7.24E-02 7.24E-02 miss 247.93 6.89
-9.55E-04 3.90E-01 miss 591. 7 6 4.95 l.54E-02 5.BOE-01 miss 692.42
- 1. 78 5.98E-02 1.69E+OO miss 723.30 20.06
-3.21E-02 l.17E-Ol miss 756.80 4.52 1.lBE-01 7.92E-01 miss 873.18 12.08
-9.24E-02
- l. 51E-01 miss 996.29 10.48 3.95E-02 3.89E-01 miss 1004. 76 18.01 4.80E-02
- l. 99E-01 miss 1274.43 34.80
- 2. 71E-02 1.lOE-01 miss 1596.48
- 1. 80 -l.31E-Ol 1.95E+OO miss
+
Eu-155 45.30
- 1. 31 1.28E-01 1.53E-01 7.37E+OO miss 60.01
- 1. 22
-1.23E+OO 8.21E+OO miss 86.55 30.70 4.38E-02 1.70E-01 miss 105.31 21.10 8.43E-02 l.53E-01 miss
+
Tl-208 583.19 85.00 9.45E-02 4.61E-02 4.61E-02 miss
+
Bi-211 351.07 13.02 1.32E+OO 2.54E-01 2.54E-01 miss
[184]
4/27/2016 4:09:42PM Page 7 of8 Analysis Report for 27-Apr-16-10020 L310223AFQGS014SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi!grams)
(pCi!grams)
(pCi/grams)
Corr
+
Pb-211 404.85 3.78
-3.32E-01 6.7,E-01 6.77E-01 miss 427.09
- 1. 76
-4.27E-01 l.22E+OO miss 832. 01 3.52
- 1. 39E-02 l.14E+OO miss
+
Bi-212 39.86
- 1. 06 2.30E-01 7.20E-Ol 8.55E+OO miss 727. 33 6.67 2.84E-01 7.20E-Ol miss 785.37 1.10
- 1. 2 6E+OO 3.15E+OO miss 1620.50
- 1. 47
- 3. 72E-01 2.40E+OO miss
+
Pb-212 115.18 0.60 2.63E+OO 9.73E-02 5.32E+DO miss 238.63 43.60 4.07E-01 9.73E-02 miss 300.09 3.30 5.78E-01 l.02E+OO miss
+
Pb212-XR 74.82
- 10. 28 9.16E-01 3.56E-Ol 6.34E-01 miss 77. 11 17.10 6.49E-01 3.56E-01 miss 87.35
- 3. 97 4.17E-01 l.25E+OO miss 89.78
- 1. 46 1.63E+OO 3.lOE+OO miss Bi-214 609.32 45.49 3.32E-01 9.77E-02 9.77E-02 miss 768.36 4.89 6.67E-01 1.07E+OO miss 806.18
- 1. 26
-4. 96E-01 1.37E+OO miss 934.06 3.11 5.16E-01 l.33E+OO miss 1120.29 14.92 3.83E-01 2.25E-01 miss 1155.21
- 1. 63
-1. 31E-01 2.58E+OO miss 1238.12 5.83
- l. 91E-01 8.50E-Ol miss 1280.98
- 1. 43
- 1. 40E+OO 3.88E+OO miss 1377. 67 3.99 6.02E-01 1.53E+OO miss 1385. 31 0.79 4.26E-01 3.13E+OO miss 1401. 52
- 1. 33 7.04E-01 3.08E+D0 miss 14 07.99 2.39 4.08E-02 l.72E+OO miss 1509.21 2.13 8.46E-01 2.22E+OO miss 1661. 27
- 1. 05
- 7. 72E-01 3.99E+OO miss 1729.59 2.88 8.!:i2E-Ol 2.09E+OO miss 1764.49 15.30 5.05E-01 6.24E-01 miss 1847.43 2.03
-1.81E-01 2.22E+OO miss 2118.51 1.16 O.OOE+OO O.OOE+OO miss
+
Pb-2 1 4 241.99 7.25 4.74E-01 9.29E-02 5.36E-01 miss 295.22 18.42 3.41E-01 l.93E-01 miss 351.93 35.60 4.83E-01 9.29E-02 miss 785.96
- 1. 06 1.35E+OO 3.27E+OO miss
+
Ph214-XR 74.82 5.80 1.62E+OO 6.27E-01 1.12E+OO miss 77. 11 9.70 1.14E+OO 6.27E-01 miss 87.35 2.24 7.39E-01 2.22E+OO miss 89.78 0.82 2.90E+OO 5.52E+OO miss
+
Ra-226 186.21 3.64
- 6. 71E-Ol 9.lOE-01 9.lOE-01 miss
+
Ac-:228 129.07 2.42 1.73E-01 1.65E-01 l.21E+D0 miss 209.25 3.89 4.81E-Ol 8.16E-01 miss 270.24 3.46 9.52E-02 9.74E-Ol miss 328. 00 2.95 5.17E-01
- 1. 14E+OO miss 338.32
- 11. 27 4.23E-01 2.99E-01 miss 409.46
- 1. 92 7.40E-01
- 1. 60E+OO miss 463. 00 4.40 4.SlE-01 9.17E-01 miss 794.95 4.25 3.02E-01 9.94E-01 miss 911.20 25.80 3.80E-Ol 1.65E-01 miss 964. 77 4.99 4.61E-01 9.65E-01 miss
[185]
4/27/2016 4:09:42PM Page 8 of8 Analysis Report for 27-Apr-16-10020 L310223AFQGS014SS (DRIED)
Nuclide Energy Yield(%)
Activity NuclideMDA LineMDA Coinc Name (keV)
(pCi!grams)
(pCilgrams)
(pCi/grams)
Corr Ac-228 968. 97 15.80 6.58E-01 l.65E-01 2.32E-01 miss 1588.20 3.22 7.81E-01 1. 85E+OO miss
+
Pa-231 2,.36 10.30 O.OOE+OO
- 1. 0 lE-01 l.OlE-01 miss 283.69
- 1. 70 4.87E-01
- l. 73E+OO miss 300.07
- 2. 47 7.72E-01
- l. 36E+OO miss 302.65 2.20
-~.73E-01 9.91E-01 miss 330.06
- 1. 40
-7. 96E-01 l. 58E+OO miss
+
Th-234 92.38 2.13
- l. 86E+OO 2.43E+OO 2.44E+OO miss 92. 80
- 2. 10 1.47E+OO 2.43E+OO miss 112. 31
- 0. 21 6.69E+OO
'.:.. 4 7E+Ol miss
+
U-235 143.76
- 10. 96 1.09E-01 5.37E-02 2.82E-01 miss 163.33 5.08 7.67E-03 4.94E-Ol miss 185. 71 57.20 2.03E-02 5.37E-02 miss 202.11
- 1. 08 5.03E-01 2.37E+OO miss 205.31
- 5. 01 2.93E-02 5.16E-01 miss
+
Am-241 59.54 35.90 4.24E-02 3.02E-01 3.02E-01 miss
+
= Nuclide identified during the nuclide identification
= Energy line found in the spectrum MDA value not calculated
= Half-life too short to be able to perform the decay correction
?
- CAUTION
free "'No coincidence correction required.
miss = Nuclide energy was not found in the coincidence library.
[186]
40 35 V'l s::
- s 8 30 25
~
L, Q.
20 9
a, 15 t
~
co
~
I u 10 5
1000 2000 3000 0000014761.CNF co
~
~
I co SJ u <
4000 channel
- &i 5000 Live Time :600.000 sec Real Time :600.470 sec start:
1: -0.2(kev) stop : 8192: 2047. 4(kev)
Acq. start :wed Apr 27 15: 59: OB 2016 6000 7000 8000
ATTACHMENT 7 EBERLINE ANALYTICAL REPORTS
[187]
Printed: 6/14/2018 8:55 AM Page 1 of 2 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units 17-10053-01 LCS KNOWN 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 1.35E+02 5.27E+00 pCi/g 17-10053-01 LCS KNOWN 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 8.44E+01 3.38E+00 pCi/g 17-10053-01 LCS SPIKE 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 1.30E+02 7.87E+00 1.03E+01 9.20E-01 pCi/g 17-10053-01 LCS SPIKE 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 8.23E+01 1.01E+01 1.09E+01 1.58E+00 pCi/g 17-10053-02 MBL BLANK 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 1.49E-02 1.43E-02 1.43E-02 2.53E-02 U
pCi/g 17-10053-02 MBL BLANK 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified 1.20E-04 9.67E-03 9.67E-03 2.25E-02 U
pCi/g 17-10053-02 MBL BLANK 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 3.18E-03 1.51E-02 1.51E-02 2.46E-02 U
pCi/g 17-10053-02 MBL BLANK 10/11/17 00:00 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 8.01E-02 1.97E-01 1.97E-01 3.19E-01 U
pCi/g 17-10053-03 DUP L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 3.20E-02 4.42E-02 4.42E-02 5.93E-02 U
pCi/g 17-10053-03 DUP L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified
-7.97E-01 2.03E-01 2.07E-01 8.98E-02 U
pCi/g 17-10053-03 DUP L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 3.32E-01 7.60E-02 7.79E-02 9.44E-02 pCi/g 17-10053-03 DUP L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 1.40E+01 1.57E+00 1.73E+00 7.85E-01 pCi/g 17-10053-04 DO L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 4.93E-02 4.81E-02 4.82E-02 5.54E-02 U
pCi/g 17-10053-04 DO L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified 1.42E-02 3.07E-02 3.07E-02 9.48E-02 U
pCi/g 17-10053-04 DO L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 3.42E-01 7.70E-02 7.89E-02 9.48E-02 pCi/g 17-10053-04 DO L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 1.37E+01 1.67E+00 1.81E+00 1.20E+00 pCi/g 17-10053-05 TRG L310219BFRGS007SSA 09/27/16 10:05 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified
-2.85E-03 2.42E-02 2.42E-02 3.05E-02 U
pCi/g 17-10053-05 TRG L310219BFRGS007SSA 09/27/16 10:05 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified
-2.56E-03 1.67E-02 1.67E-02 3.83E-02 U
pCi/g 17-10053-05 TRG L310219BFRGS007SSA 09/27/16 10:05 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 2.13E-02 2.21E-02 2.22E-02 3.62E-02 U
pCi/g 17-10053-05 TRG L310219BFRGS007SSA 09/27/16 10:05 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 4.71E+00 6.50E-01 6.93E-01 3.92E-01 pCi/g 17-10053-06 TRG L310223AFRGS003SSB 04/25/16 13:20 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 2.96E-02 4.43E-02 4.44E-02 6.13E-02 U
pCi/g 17-10053-06 TRG L310223AFRGS003SSB 04/25/16 13:20 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified
-6.71E-03 3.68E-02 3.68E-02 8.99E-02 U
pCi/g 17-10053-06 TRG L310223AFRGS003SSB 04/25/16 13:20 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 3.67E-01 7.80E-02 8.02E-02 9.46E-02 pCi/g 17-10053-06 TRG L310223AFRGS003SSB 04/25/16 13:20 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 6.97E+00 1.04E+00 1.10E+00 6.48E-01 pCi/g 17-10053-07 TRG L310223AFRGS004SSB 04/25/16 13:15 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 2.37E-02 4.44E-02 4.44E-02 5.95E-02 U
pCi/g 17-10053-07 TRG L310223AFRGS004SSB 04/25/16 13:15 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified 1.77E-02 1.71E-02 1.71E-02 7.22E-02 U
pCi/g 17-10053-07 TRG L310223AFRGS004SSB 04/25/16 13:15 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 2.07E-02 3.81E-02 3.81E-02 5.62E-02 U
pCi/g 17-10053-07 TRG L310223AFRGS004SSB 04/25/16 13:15 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 6.62E+00 9.64E-01 1.02E+00 6.62E-01 pCi/g Zion, IL 60099 Work Order Details:
671498 17-10053 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Alex Bohacheff Zion Solutions 101 Shiloh Blvd CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[188]
Printed: 6/14/2018 8:55 AM Page 2 of 2 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units Zion, IL 60099 Work Order Details:
671498 17-10053 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Alex Bohacheff Zion Solutions 101 Shiloh Blvd 17-10053-08 TRG L310223AFRGS005SSA 04/25/16 13:00 10/11/2017 10/13/2017 17-10053 Cobalt-60 EPA 901.1 Modified 9.45E-03 2.47E-02 2.47E-02 3.15E-02 U
pCi/g 17-10053-08 TRG L310223AFRGS005SSA 04/25/16 13:00 10/11/2017 10/13/2017 17-10053 Cesium-134 EPA 901.1 Modified
-5.75E-03 1.89E-02 1.90E-02 4.35E-02 U
pCi/g 17-10053-08 TRG L310223AFRGS005SSA 04/25/16 13:00 10/11/2017 10/13/2017 17-10053 Cesium-137 EPA 901.1 Modified 1.83E-02 2.26E-02 2.26E-02 3.79E-02 U
pCi/g 17-10053-08 TRG L310223AFRGS005SSA 04/25/16 13:00 10/11/2017 10/13/2017 17-10053 Potassium-40 EPA 901.1 Modified 4.77E+00 6.79E-01 7.22E-01 4.80E-01 pCi/g 17-10053-01 LCS KNOWN 10/11/17 00:00 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified 1.59E+03 4.78E+01 pCi/g 17-10053-01 LCS SPIKE 10/11/17 00:00 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified 1.71E+03 1.02E+01 1.01E+02 2.33E+00 pCi/g 17-10053-02 MBL BLANK 10/11/17 00:00 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified
-2.82E-01 1.35E+00 1.35E+00 2.32E+00 U
pCi/g 17-10053-03 DUP L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified
-2.01E-01 7.18E-01 7.19E-01 1.24E+00 U
pCi/g 17-10053-04 DO L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified 2.91E-01 7.05E-01 7.06E-01 1.20E+00 U
pCi/g 17-10053-05 TRG L310219BFRGS007SSA 09/27/16 10:05 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified
-2.31E-01 6.62E-01 6.62E-01 1.14E+00 U
pCi/g 17-10053-06 TRG L310223AFRGS003SSB 04/25/16 13:20 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified 4.49E-02 6.47E-01 6.47E-01 1.11E+00 U
pCi/g 17-10053-07 TRG L310223AFRGS004SSB 04/25/16 13:15 10/11/2017 10/18/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified
-4.17E-01 6.58E-01 6.59E-01 1.14E+00 U
pCi/g 17-10053-08 TRG L310223AFRGS005SSA 04/25/16 13:00 10/11/2017 10/19/2017 17-10053 Nickel-63 ASTM 3500-Ni Modified
-1.42E-01 6.79E-01 6.79E-01 1.17E+00 U
pCi/g 17-10053-01 LCS KNOWN 10/11/17 00:00 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 6.89E+01 3.86E-01 pCi/g 17-10053-01 LCS SPIKE 10/11/17 00:00 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 7.40E+01 1.95E+00 1.03E+01 1.04E+00 pCi/g 17-10053-02 MBL BLANK 10/11/17 00:00 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 2.17E-01 1.94E-01 1.97E-01 3.90E-01 U
pCi/g 17-10053-03 DUP L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 5.95E-01 2.43E-01 2.57E-01 4.58E-01 pCi/g 17-10053-04 DO L310213AFRGS006SSB 04/13/16 13:15 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 4.41E-01 2.17E-01 2.25E-01 4.14E-01 pCi/g 17-10053-05 TRG L310219BFRGS007SSA 09/27/16 10:05 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 3.37E-01 2.24E-01 2.28E-01 4.41E-01 U
pCi/g 17-10053-06 TRG L310223AFRGS003SSB 04/25/16 13:20 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 5.26E-01 2.47E-01 2.58E-01 4.76E-01 pCi/g 17-10053-07 TRG L310223AFRGS004SSB 04/25/16 13:15 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 2.44E-01 2.14E-01 2.17E-01 4.32E-01 U
pCi/g 17-10053-08 TRG L310223AFRGS005SSA 04/25/16 13:00 10/11/2017 10/19/2017 17-10053 Strontium-90 EIChroM SRW01 Modified 5.66E-01 2.11E-01 2.25E-01 3.89E-01 pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[189]
Printed: 6/14/2018 8:56 AM Page 1 of 6 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units 17-03011-01 LCS KNOWN 03/03/17 00:00 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.51E+03 4.52E+01 pCi/g 17-03011-01 LCS SPIKE 03/03/17 00:00 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.52E+03 9.33E+00 9.01E+01 2.11E+00 pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.58E+00 1.27E+00 1.27E+00 2.11E+00 U
pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 2.19E+00 1.39E+00 1.39E+00 2.29E+00 U
pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.71E+00 1.37E+00 1.37E+00 2.28E+00 U
pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 3.46E+00 1.39E+00 1.40E+00 2.25E+00 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 2.88E-01 1.36E+00 1.36E+00 2.31E+00 U
pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified
-1.69E+00 1.65E+00 1.65E+00 2.90E+00 U
pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 6.89E-01 1.40E+00 1.40E+00 2.37E+00 U
pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 8.22E-01 1.30E+00 1.30E+00 2.20E+00 U
pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.06E+00 1.27E+00 1.27E+00 2.13E+00 U
pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 3.84E+00 1.40E+00 1.42E+00 2.25E+00 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/14/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 2.34E+00 1.48E+00 1.49E+00 2.44E+00 U
pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/15/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.97E+00 1.36E+00 1.37E+00 2.26E+00 U
pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/15/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.09E+00 1.42E+00 1.42E+00 2.39E+00 U
pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/15/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 9.12E-01 1.44E+00 1.44E+00 2.44E+00 U
pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/15/2017 17-03011 Nickel-63 ASTM 3500-Ni Modified 1.02E+01 1.52E+00 1.64E+00 2.24E+00 pCi/g 17-03011-01 LCS KNOWN 03/03/17 00:00 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 5.43E+01 3.04E-01 pCi/g 17-03011-01 LCS SPIKE 03/03/17 00:00 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 6.16E+01 1.65E+00 2.15E+01 8.24E-01 pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified
-2.14E-02 4.23E-01 4.23E-01 9.04E-01 U
pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 7.78E-01 3.45E-01 4.39E-01 6.48E-01 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 5.42E-01 3.48E-01 3.96E-01 6.83E-01 U
pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 3.59E-01 3.59E-01 3.81E-01 7.29E-01 U
pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 3.97E-01 3.66E-01 3.91E-01 7.40E-01 U
pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 5.85E-01 4.17E-01 4.64E-01 8.27E-01 U
pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 6.39E-02 3.97E-01 3.98E-01 8.41E-01 U
pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 9.84E-01 3.37E-01 4.80E-01 6.09E-01 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 4.59E-01 3.45E-01 3.80E-01 6.86E-01 U
pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 6.36E-01 3.86E-01 4.45E-01 7.54E-01 U
pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 8.09E-01 4.19E-01 5.05E-01 8.12E-01 U
pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 7.29E-01 3.98E-01 4.72E-01 7.75E-01 U
pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 3.09E-01 3.90E-01 4.04E-01 8.00E-01 U
pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 1.03E-01 3.61E-01 3.62E-01 7.59E-01 U
pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/27/2017 17-03011 Strontium-90 EIChroM SRW01 Modified 5.03E-01 3.78E-01 4.17E-01 7.53E-01 U
pCi/g Zion, IL 60099 Work Order Details:
671498 17-03011 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Patricia Giza Zion Solutions 101 Shiloh Blvd CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank; DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[190]
Printed: 6/14/2018 8:56 AM Page 2 of 6 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units Zion, IL 60099 Work Order Details:
671498 17-03011 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Patricia Giza Zion Solutions 101 Shiloh Blvd 17-03011-01 LCS KNOWN 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 6.21E+01 2.48E+00 pCi/g 17-03011-01 LCS KNOWN 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 3.94E+01 1.58E+00 pCi/g 17-03011-01 LCS SPIKE 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 7.58E+01 5.03E+00 6.36E+00 6.59E-01 pCi/g 17-03011-01 LCS SPIKE 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 4.44E+01 4.02E+00 4.62E+00 6.97E-01 pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 4.74E-02 4.81E-02 4.82E-02 8.85E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 1.72E-02 2.56E-02 2.57E-02 4.39E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 1.29E-02 1.46E-02 1.46E-02 2.73E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified
-1.28E-04 1.27E-02 1.27E-02 1.91E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 6.40E-03 1.48E-02 1.48E-02 2.34E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 1.37E-01 1.68E-01 1.69E-01 3.28E-01 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 6.28E-03 1.70E-02 1.70E-02 2.64E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified
-3.01E-03 2.42E-02 2.42E-02 3.65E-02 U
pCi/g 17-03011-02 MBL BLANK 03/03/17 00:00 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified
-5.23E-03 4.16E-02 4.16E-02 6.34E-02 U
pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 4.11E-01 1.33E-01 1.34E-01 2.02E-01 pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 4.84E-01 1.17E-01 1.19E-01 1.04E-01 pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified
-2.54E-03 3.32E-02 3.32E-02 4.18E-02 U
pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 2.64E-04 1.18E-02 1.18E-02 4.72E-02 U
pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 5.75E-02 4.30E-02 4.31E-02 7.05E-02 U
pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 1.01E+01 1.11E+00 1.23E+00 4.65E-01 pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 4.00E-01 5.25E-02 5.64E-02 8.50E-02 pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.90E-01 1.31E-01 1.33E-01 9.32E-02 pCi/g 17-03011-03 DUP L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.46E-01 6.92E-02 7.04E-02 5.39E-02 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 4.23E-01 1.04E-01 1.06E-01 2.03E-01 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 4.66E-01 1.11E-01 1.13E-01 8.49E-02 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 4.50E-04 3.33E-02 3.33E-02 3.46E-02 U
pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified
-5.96E-03 1.09E-02 1.09E-02 4.15E-02 U
pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 6.04E-02 3.06E-02 3.08E-02 4.76E-02 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 1.02E+01 1.13E+00 1.24E+00 5.53E-01 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 3.75E-01 5.11E-02 5.46E-02 8.70E-02 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 4.00E-01 1.33E-01 1.35E-01 1.11E-01 pCi/g 17-03011-04 DO L310212AFRGS002SS-A 05/11/16 10:30 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 1.86E-01 6.47E-02 6.54E-02 6.95E-02 pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank; DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[191]
Printed: 6/14/2018 8:56 AM Page 3 of 6 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units Zion, IL 60099 Work Order Details:
671498 17-03011 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Patricia Giza Zion Solutions 101 Shiloh Blvd 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 3.95E-01 6.68E-02 6.98E-02 2.26E-01 pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 3.88E-01 6.28E-02 6.59E-02 8.04E-02 pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 1.89E-02 2.04E-02 2.04E-02 2.86E-02 U
pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified
-3.06E-03 1.04E-02 1.04E-02 2.78E-02 U
pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 4.11E-01 6.15E-02 6.50E-02 3.88E-02 pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 6.85E+00 8.02E-01 8.76E-01 2.60E-01 pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 3.45E-01 5.27E-02 5.56E-02 4.16E-02 pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.73E-01 6.08E-02 6.37E-02 7.27E-02 pCi/g 17-03011-05 TRG L310213AFRGS008SS-A 04/14/16 08:00 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 3.93E-01 7.55E-02 7.82E-02 6.80E-02 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 3.14E-01 1.00E-01 1.02E-01 1.05E-01 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 3.82E-01 7.07E-02 7.34E-02 7.96E-02 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 2.05E-03 1.95E-02 1.95E-02 2.33E-02 U
pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 4.00E-03 6.34E-03 6.34E-03 2.49E-02 U
pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 2.25E-02 2.00E-02 2.01E-02 3.30E-02 U
pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 8.06E+00 1.03E+00 1.11E+00 4.94E-01 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 3.61E-01 1.24E-01 1.26E-01 6.77E-02 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.73E-01 1.30E-01 1.31E-01 6.84E-02 pCi/g 17-03011-06 TRG L310219AFRGS006SS-A 10/03/16 09:10 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.87E-01 7.16E-02 7.31E-02 5.18E-02 pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 2.85E-01 1.06E-01 1.07E-01 2.08E-01 pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 4.30E-01 9.29E-02 9.55E-02 1.27E-01 pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 1.61E-03 9.25E-03 9.25E-03 5.27E-02 U
pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 8.33E-03 1.55E-02 1.55E-02 4.39E-02 U
pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 6.93E-01 1.06E-01 1.12E-01 6.05E-02 pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 4.65E+00 7.78E-01 8.14E-01 5.30E-01 pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 5.59E-02 5.32E-02 5.33E-02 1.04E-01 U
pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.45E-01 8.88E-02 9.05E-02 1.15E-01 pCi/g 17-03011-07 TRG L310219BFRGS004SS-A 09/27/16 08:25 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.39E-01 8.59E-02 8.67E-02 1.47E-01 pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank; DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[192]
Printed: 6/14/2018 8:56 AM Page 4 of 6 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units Zion, IL 60099 Work Order Details:
671498 17-03011 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Patricia Giza Zion Solutions 101 Shiloh Blvd 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 2.93E-01 1.05E-01 1.06E-01 2.39E-01 pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 3.41E-01 6.34E-02 6.57E-02 1.35E-01 pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified
-3.32E-02 4.28E-02 4.28E-02 5.98E-02 U
pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 6.49E-03 2.04E-02 2.04E-02 4.57E-02 U
pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 4.03E-01 7.19E-02 7.49E-02 8.51E-02 pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 8.03E+00 1.20E+00 1.27E+00 6.92E-01 pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 3.68E-01 5.53E-02 5.84E-02 1.09E-01 pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 2.92E-01 6.40E-02 6.57E-02 1.03E-01 pCi/g 17-03011-08 TRG L310220CRFGS002SS-A 05/23/16 14:30 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 4.27E-01 1.02E-01 1.04E-01 1.72E-01 pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 2.67E-01 1.03E-01 1.03E-01 7.51E-02 pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 3.06E-01 6.14E-02 6.33E-02 6.49E-02 pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 1.29E-02 1.47E-02 1.47E-02 1.62E-02 U
pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 1.85E-03 5.88E-03 5.88E-03 2.29E-02 U
pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 5.77E-03 1.18E-02 1.18E-02 1.84E-02 U
pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 4.97E+00 6.50E-01 6.98E-01 3.09E-01 pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 2.92E-01 9.35E-02 9.47E-02 5.97E-02 pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.26E-01 1.09E-01 1.11E-01 5.08E-02 pCi/g 17-03011-09 TRG L310223AFRGS004SS-A 04/25/16 13:15 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.49E-01 6.26E-02 6.39E-02 6.96E-02 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 4.56E-01 8.81E-02 9.11E-02 1.90E-01 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 3.52E-01 1.14E-01 1.16E-01 7.67E-02 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified
-1.95E-03 2.38E-02 2.38E-02 2.96E-02 U
pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified
-2.43E-03 1.04E-02 1.04E-02 3.39E-02 U
pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 1.68E-02 1.97E-02 1.97E-02 3.18E-02 U
pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 5.89E+00 7.05E-01 7.67E-01 4.46E-01 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 5.13E-01 5.35E-02 5.96E-02 8.50E-02 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 4.53E-01 1.30E-01 1.32E-01 6.76E-02 pCi/g 17-03011-10 TRG L310224AFRGS004SS-A 06/02/16 12:40 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 3.20E-01 6.85E-02 7.04E-02 3.88E-02 pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank; DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[193]
Printed: 6/14/2018 8:56 AM Page 5 of 6 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units Zion, IL 60099 Work Order Details:
671498 17-03011 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Patricia Giza Zion Solutions 101 Shiloh Blvd 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 3.10E-01 1.38E-01 1.39E-01 2.87E-01 pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 2.90E-01 8.05E-02 8.19E-02 1.08E-01 pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified
-1.08E-02 4.50E-02 4.50E-02 5.74E-02 U
pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 7.65E-03 1.58E-02 1.58E-02 4.69E-02 U
pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 3.28E-01 6.71E-02 6.92E-02 8.42E-02 pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 9.77E+00 1.40E+00 1.49E+00 6.37E-01 pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 3.17E-01 5.43E-02 5.66E-02 9.23E-02 pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.38E-01 7.09E-02 7.30E-02 1.13E-01 pCi/g 17-03011-11 TRG L310301AFRGS003SS-A 06/14/16 13:27 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 3.08E-01 1.13E-01 1.14E-01 1.65E-01 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 4.28E-01 8.53E-02 8.80E-02 1.50E-01 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 3.40E-01 7.01E-02 7.22E-02 9.44E-02 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 1.84E-02 2.40E-02 2.40E-02 3.33E-02 U
pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified
-2.32E-02 2.89E-02 2.89E-02 3.14E-02 U
pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 2.81E-02 2.43E-02 2.43E-02 3.95E-02 U
pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 7.18E+00 8.97E-01 9.70E-01 5.24E-01 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 5.13E-01 7.92E-02 8.35E-02 6.71E-02 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.46E-01 5.95E-02 6.21E-02 7.38E-02 pCi/g 17-03011-12 TRG L310212AFJGS019SS-A 05/16/16 10:45 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 3.96E-01 8.55E-02 8.78E-02 1.12E-01 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Actinium-228 LANL ER-130 Modified 2.89E-01 1.08E-01 1.09E-01 1.71E-01 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Bismuth-214 LANL ER-130 Modified 4.18E-01 8.65E-02 8.91E-02 7.83E-02 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Cobalt-60 LANL ER-130 Modified 6.19E-03 2.06E-02 2.06E-02 2.63E-02 U
pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Cesium-134 LANL ER-130 Modified 6.73E-03 1.17E-02 1.17E-02 2.91E-02 U
pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Cesium-137 LANL ER-130 Modified 6.84E-02 2.08E-02 2.11E-02 3.89E-02 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Potassium-40 LANL ER-130 Modified 7.14E+00 9.28E-01 9.97E-01 4.26E-01 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Lead-212 LANL ER-130 Modified 3.24E-01 1.13E-01 1.15E-01 9.05E-02 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Lead-214 LANL ER-130 Modified 3.61E-01 1.29E-01 1.30E-01 5.38E-02 pCi/g 17-03011-13 TRG L310219AFRJS019SS-A 09/27/16 12:30 3/3/2017 3/6/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.52E-01 7.63E-02 7.74E-02 1.17E-01 pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank; DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[194]
Printed: 6/14/2018 8:56 AM Page 6 of 6 SDG:
Purchase Order:
Analysis Category:
Sample Matrix:
Lab ID Sample Type Client ID Sample Date Receipt Date Analysis Date Batch ID Analyte Method Result CU CSU MDA Qualifier Report Units Zion, IL 60099 Work Order Details:
671498 17-03011 SO ENVIRONMENTAL Eberline Analytical Final Report of Analysis Report To:
Patricia Giza Zion Solutions 101 Shiloh Blvd 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Actinium-228 LANL ER-130 Modified 2.73E-01 9.62E-02 9.72E-02 1.03E-01 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Bismuth-214 LANL ER-130 Modified 2.99E-01 6.02E-02 6.21E-02 6.14E-02 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Cobalt-60 LANL ER-130 Modified 2.51E-02 1.55E-02 1.56E-02 2.24E-02 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Cesium-134 LANL ER-130 Modified
-5.07E-03 9.42E-03 9.43E-03 2.76E-02 U
pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Cesium-137 LANL ER-130 Modified 3.38E-01 4.02E-02 4.38E-02 3.33E-02 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Potassium-40 LANL ER-130 Modified 6.77E+00 8.72E-01 9.39E-01 3.88E-01 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Lead-212 LANL ER-130 Modified 3.17E-01 1.10E-01 1.11E-01 6.70E-02 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Lead-214 LANL ER-130 Modified 2.31E-01 8.83E-02 8.91E-02 5.75E-02 pCi/g 17-03011-14 TRG L310220CFRGS009SS-A 05/02/16 14:00 3/3/2017 3/7/2017 17-03011 Thallium-208 LANL ER-130 Modified 3.12E-01 7.53E-02 7.70E-02 5.09E-02 pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Actinium-228 LANL ER-130 Modified 3.28E-01 5.75E-02 5.99E-02 1.19E-01 pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Bismuth-214 LANL ER-130 Modified 2.77E-01 5.55E-02 5.72E-02 7.49E-02 pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Cobalt-60 LANL ER-130 Modified 2.22E-03 1.65E-02 1.65E-02 2.20E-02 U
pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Cesium-134 LANL ER-130 Modified 2.87E-03 6.84E-03 6.84E-03 1.89E-02 U
pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Cesium-137 LANL ER-130 Modified 2.03E-02 1.30E-02 1.30E-02 2.04E-02 U
pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Potassium-40 LANL ER-130 Modified 6.22E+00 6.92E-01 7.62E-01 2.36E-01 pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Lead-212 LANL ER-130 Modified 2.87E-01 4.16E-02 4.42E-02 4.20E-02 pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Lead-214 LANL ER-130 Modified 2.66E-01 4.22E-02 4.44E-02 4.27E-02 pCi/g 17-03011-15 TRG L310224AFRGS012SS-A 06/02/16 14:16 3/3/2017 3/7/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.87E-01 5.58E-02 5.77E-02 4.54E-02 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Actinium-228 LANL ER-130 Modified 3.84E-01 1.09E-01 1.11E-01 2.05E-01 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Bismuth-214 LANL ER-130 Modified 2.85E-01 9.70E-02 9.81E-02 1.05E-01 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Cobalt-60 LANL ER-130 Modified 8.55E-03 3.20E-02 3.20E-02 5.09E-02 U
pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Cesium-134 LANL ER-130 Modified 1.76E-03 1.48E-02 1.48E-02 4.53E-02 U
pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Cesium-137 LANL ER-130 Modified 3.37E-01 6.23E-02 6.46E-02 7.54E-02 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Potassium-40 LANL ER-130 Modified 6.05E+00 8.31E-01 8.87E-01 5.71E-01 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Lead-212 LANL ER-130 Modified 4.33E-01 5.83E-02 6.23E-02 8.32E-02 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Lead-214 LANL ER-130 Modified 3.29E-01 1.49E-01 1.50E-01 1.23E-01 pCi/g 17-03011-16 TRG L310301AFIGS017SS-A 06/14/16 13:40 3/3/2017 3/7/2017 17-03011 Thallium-208 LANL ER-130 Modified 2.56E-01 8.59E-02 8.69E-02 1.05E-01 pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (2-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank; DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
[195]
[196]
Printed: 3/27/2019 3:32 PM Eberline Analytical Final Report of Analysis Lab Client ID ID MBL BLANK DUP L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C LCS KNOWN SPIKE BLANK L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C 19-03018-02 MBL BLANK 19-03018-03 DUP L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C 19-03018-01 LCS KNOWN 19-03018-01 LCS KNOWN 19-03018-01 LCS SPIKE 19-03018-01 SPIKE Page 1 of 4 Report To:
Worl< Order Details:
Patricia Giza SDG:
19-03018
,,,-~--------,---------------------------*
Zion Solutions Purchase Order:
677118 2701 Deborah Ave Analysis Cater;ory: *--~NVIRONMENTAL _____.
Zion, IL 60099 Sample Matrix:
SO Sample Receipt Analysis Date Date Date Method I Result cu CSU MDA
- Qualifier Report I
Units 03/07/19 00:00 3/7/2019 4,55E+01 03/07 /19 00:00 3/7/2019 Nickel-63 1.30E+01 8,93E+01 3.11E+OO pCi/g 03/07/19 00:00 3/7/2019 1.82E+OO 1.82E+OO 3.08E+OO u
pCi/g 04/25/16 13:20 3/7/2019 1.72E+OO 1.72E+OO 2.97E+OO u
04/25/16 13:20 3/7/2019 I 7.41E-01. 1.76E+OO 1,76E+OO 2,99E+OO i u
pCi/g 03/07 /19 00:00 EIChroM SRW01 Modified 5,02E+01 2.81E-01 03/07 /19 00:00 EIChroM SRW01 Modified 4.02E+01 1.23E+OO 1.41E+01 03/07 /19 00:00 EIChroM SRW01 Modified 3,05E-01 4.12E-01 4.26E-01 04/25/16 13:20 EIChroM SRW01 Modified 4.38E-01 2.61E-01 04/25/16 13:20 EIChroM SRW01 Modified 4.88E-01 1 2.47E-01 3,00E-01 03/07/19 00:00 LANL ER-210 Modified 2.10E+02' 7.57E+OO 7.80E+OO 1.35E+01 3.39E+OO 3.39E+OO LANL ER-210 Modified 3.89E+OO 3,89E+OO LANL ER-210 Modified O.OOE+OO I 3.86E+OO 3.86E+OO EPA 901.1 Modified 1.31E+02 5.10E+OO EPA 901.1 Modified 8.26E+01 3.39E+OO EPA 901.1 Modified 1.49E+02 9.61E+OO EPA 901.1 Modified 1 9.35E+01 1.02E+01 CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Nonnal Sample;DO=Duplicate Original;U=Non-detect
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ANALYTICAL EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621
[197]
Printed: 3/27/2019 3:32 PM Page 2 of 4 Report To:
Work Order Details:
Eberline Analytical Patricia Giza SDG:'
19-03018
~~*---
-~~*---*--*~----,~~--------~~*------
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Zion Solutions Purchase Order:
677118 Final Report of Analysis 2701 Deborah Ave ENVIRONMENTAL
~--=-------------
Zion, IL 60099 Sample Matrix:
so Lab Sample Client Sample Analysis Analyte Method Result cu CSU Qualifier, Report ID Type ID Date Date MDA Units 19-03018-02 MBL BLANK 03/07 /19 00:00 Actinium-228 EPA 901.1 Modified 1.08E-01 19-03018-02 MBL Silver-108m 19-03018-02 MBL BLANK Americium-241 19-03018-02 MBL BLANK Barium-133 19-03018-02 BLANK Bismuth-214 19-03018-02 MBL BLANK Cobalt-60 19-03018-02 MBL BLANK Cesium-134 19-03018-02 MBL BLANK 19-03018-02 MBL BLANK 19-03018-02 MBL BLANK 19-03018-02 MBL BLANK 19-03018-02 MBL BLANK 19-03018-02 MBL BLANK 03/07 /19 00:00 EPA 901.1 19-03018-02 MBL BLANK 03/07 /19 00:00 EPA 901.1 19-03018-02 MBL BLANK 03/07/19 00:00 EPA 901.1 19-03018-02 BLANK 03/07 /19 00:00 19-03018-02 MBL BLANK 03/07/19 00:00 EPA 901.1 Modified 19-03018-02 MBL BLANK 03/07/19 00:00 EPA 901.1 Modified 19-03018-02 MBL BLANK 03/07/19 00:00 EPA 901.1 Modified 19-03018-02 BLANK 03/07/19 00:00 Lead-214 EPA 901.1 Modified 19-03018-02 MBL BLANK 03/07/19 00:00 EPA 901.1 Modified BLANK 03/07/19 00:00 '
Radium-226 EPA 901.1 Modified BLANK 03/07/19 00:00 Antimony-125 EPA901.1 Modified BLANK 03/07/19 00:00 3/7/2019 BLANK 03/07/19 00:00 3/7/2019 EPA 901.1 9.32E-02 1.51E-01 BLANK 03/07/19 00:00 3/7/2019 EPA 901.1 1.35E-01 1.35E-01, 2.03E-01 CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
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EBERLINE
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ANALYTICAL EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621 u
pCi/g u
pCi/g u
pCi/g u
u u
pCi/g u
u u
pCi/g pCi/g
[198]
Printed: 312712019 3:32 PM Eberline Analytical Final Report of Analysis Lab ID 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 19-03018-03 Sample Type DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP DUP Client ID L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C Report To:
Patricia Giza Zion Solutions 2701 Deborah Ave 1-----------------------------+-
Zion, IL 60099 Sample Receipt j Analysis Date Date Date Analyte 04/25/16 13:20 Actinium-228 04/25/16 13:20 Silver-108m 04/25/16 13:20 Americium-241 04/25/16 13:20 Barium-133 04/25/16 13:20 Bismuth-214 04/25/16 13:20 Cobalt-60 Cesium-134 04/25/16 13:20 04/25/16 13:20 04/25/16 13:20 04/25/16 13:20 Thorium-234 04/25/16 13:20 Thallium-208 04/25/16 13:20 Uranium-235 Page 3 of 4 Work Order Details:
SOG:
19-03018 Purchase Order:
677118
~
Analysis Category:,_
ENVIRONMENTAL Sample Matrix:
so Method
/
CSU EPA 901.1 Modified EPA 901.1 Modified EPA 901.1 Modified EPA 901. 1 Modified EPA 901.1 Modified EPA 901.1 Modified MDA Report Units CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
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ANALYTICAL EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621
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Printed: 3/27/2019 3:32 PM Eberline Analytical Final Report of Analysis Lab Sample ID Type 19-03018-04 DO Client ID L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C 19-03018-04 L3-10223A FRGS-003 SS-C 19-03018-04 L3-10223A FRGS-003 SS-C 19-03018-04 L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 L3-10223A FRGS-003 SS-C L3-10223A FRGS-003 SS-C Page 4 of 4 Report To:
Work Order Details:
Patricia Giza SDG:
- 19-03018 Zion Solutions Purchase Order:
677118
!-------------------**-*-------- ---**--*-----*-0------*-*---------------*---1 2701 D'!.!>~_ra_h_A_v.'!. _______ ****---**---
___ Analysis Category:J Zion, IL 60099 Sample Matrix:
Sample Date Analysis Date Batch ID 19-03018 19-03018 19-03018 19-03018 Analyte Method Actinium-228 Silver-108m EPA 901.1 Americium-241 EPA 901.1 Barium-133 EPA 901.1 Bismuth-214 EPA 901.1 Cobalt-60 EPA 901.1 Cesium-134 so cu CSU MDA 1.81E-01 1.83E-01 3.78E-01 3.45E-02' 6.40E-02 u
1.17E-01 1.17E-01 1.76E-01 u
1.26E-01. 1.60E-01 u
1.42E-01 2.34E-01 1.08E-01 u
u L3-10223A FRGS-003 ss-c __ -4 _______ _;_ ___ --i----+--*--C--------*1---------*----i----1--...:::.-...o----i---....;---u*--i__:___;_~....
19-03018-04 DO L3-10223A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C
t------
19-03018-04 DO L3-10223A FRGS-003 SS-C
._..1_9_-0_3_0_18_-_04-. __
D_o_--il~-1022~A FRGS-003 SS-C 19-03018-04 DO L3-10223A FRGS-003 SS-C Anlimony-125 Thorium-234 Thallium-208 Uranium-235 EPA 901.1 Modified U
pCi/g pCi/g
---'--*---'---C-.--J 2.78E-01 I 4.76E-01 '
U pCi/g CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample;MBL=Blank;DUP=Duplicate;TRG=Normal Sample;DO=Duplicate Original;U=Non-detect
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EBERLINE
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ANALYTICAL EBERLINE ANALYTICAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621