ML19106A241

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796 - Kerr Mcgee Cimarron Water Samples - Oct 2001
ML19106A241
Person / Time
Site: 07000925
Issue date: 10/31/2001
From: Condra D
Oak Ridge Institute for Science & Education
To: Jacqwan Walker
NRC Region 4
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Download: ML19106A241 (4)


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OAK RIDGE INSTITUTE FOR SCIENCE AND EDUCATION October 31, 2001 Ms. Judith Walker U.S. Nuclear Regulatory Commission Region IV Harris Tower 611 Ryan Plaza Drive - Suite 400 Arlington, TX 76011-8064

SUBJECT:

REPORT FOR ANALYSIS OF THE WATER SAMPLES FROM KERR-MCGEE CIMARRON, CRESCENT, OKLAHOMA (DOCKET NO.70-925; RFTA NO.01-015)

Dear Ms. Walker:

The Environmental Survey and Site Assessment Program (ESSAP) of the Oak Ridge Institute for Science and Education (ORISE) received 13 water samples collected on September 5, 2001 at the Kerr-McGee Cimarron facility in Crescent, Oklahoma. The samples were initially screened by gamma spectroscopy (Procedure CPI Revision 11) to determine if there was evidence of quantifiable concentrations of gamma emitting radionuclides. Next, each sample was analyzed for gross alpha and beta activity (Procedures APl Rev. 12 and CP3 Rev. 1), isotopic uranium by alpha spectroscopy (Procedures AP3 Rev. 15 and CP2 Rev.

10) and Tc-99 analysis (Procedure AP5 Rev. 11 and CP4 Rev. 1).

The gamma spectroscopy screening identified one sample (W003) in which uranium was quantified above the minimum detectable concentration (MDC). No other gamma-emitting radionuclides were identified.

The results for gross alpha and beta, uranium isotopic, and Tc-99 are presented in Tables 1, 2, and 3, respectively.

ESSAP's Quality Control (QC) procedures were followed for these analyses. The daily QC and detector background for the counting instrumentation used in the analyses were within acceptable limits.

Please contact me at (865) 241-3242 or Wade Ivey at (865) 576-9184 should you have any questions.

Sincerely, Dale Condra Laboratory Manager Environmental Survey and Site Assessment Program RDC:WPI:ar Attachments cc:

G.

Purdy, NRC/NMSS/fWFN 7F27 E.

Knox-Davin, NRC/NMSS/fWFN 8A23 E.

Garcia, NRC/Region IV W. Beck, ORISE/ESSAP E. Abelquist, ORISE/ESSAP T.

Vitkus, ORISE/ESSAP Fiten96 P. 0. BOX 117, OAK RIDGE, TENNESSEE 37831-01 17 Operated by Oak Ridge Associated Universities for the U.S. Department of Energy

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ESSAPID 796W001 796W002 796W003 796W004 796W005 796W006 796W007 796W008 796W009 796W010 796W011 796W012 796W013 TABLEl CONCENTRATIONS OF TOTAL ALPHA AND BETA IN WATER SAMPLES KERR-McGEE CIMARRON CRESCENT,OKLAHOMA Concentrations (pCi/L)

NRCR-IVID Gross Alpha Gross Beta 1314-1282 0.2+/-2.5 8

0.15 +/-2.6 1315-1283 360+/-30 90+/- 10 TMW-13-1284 2940+/-230 680+/-70 1316-1285 67.6 +/- 9.1 9.1 +/- 3.1 1344-1286 11.0 +/- 4.7 22.2+/-6.2 1336A-1287 52.6+/- 8.5 630+/-60 1208-1288 200+/-20 2450+/-250 1311-1289 4.4 +/- 1.5 2.9 +/- 1.2 1206-1290 120 +/- 10 41.7 +/- 4.3 1312-1291 90+/- 10 520+/-40 1330-1292 34.0 +/- 6.4 26.1 +/-4.2 1328-1293 23 +/- 13 Ob+/- 10 1329-1294 20.5 +/-4.7 34.0+/-4.8

'"Uncertainties represent the 95% confidence level. based on propagating the.nncertainties.

bZero value due to rounding.

ESSAPID NRCR-IVID 796W001 1314-1282 796W002 1315-1283 796W003 1MW-13-1284 796W004 1316-1285 796W005 1344-1286 796W006 1336A-1287 796W007 1208-1288 796W008 1311-1289 796W009 1206-1290 796W010 1312-1291 796W011 1330-1292 796W012 1328-1293 796WOI3 1329-1294 TABLE2 CONCENTRATION OF URANIUM ISOTOPES IN WATER SAMPLES KERR-McGEE CIMARRON CRESCENT, OKLAHOMA Radionuclide Concentrations (pCi/L)

U-234 U-235 U-238 1.17 +/- 0.49 8

0.19 +/- 0.24 0.55 +/-0.29 220+/-20 11.8 +/- 1.9 160+/- 10 1830+/-330 90+/-20 1040 +/- 190 36.4 +/- 3.8 1.90+/-0.63 17.4 +/- 2.1 1.32 +/- 0.50 0.05 +/- 0.17 1.24 +/- 0.46 19.2 +/-2.3 0.79+/-0.39 6.2 +/- 1.1 27.8 +/- 3.2 1.54+/-0.55 8.1 +/- 1.3 1.12 +/- 0.47 0.28 +/-0.26 1.44 +/- 0.48 80.0+/-7.5 3.22+/-0.86 22.0+/-2.6 35.8 +/-3.7 1.33 +/-0.51 11.7 +/- 1.6 10.4 +/- 1.5 0.73+/-0.39 3.64 +/- 0.79 19.7 +/-2.4 0.47 +/-0.33 10.2+/- 1.5 4.33+/-0.90 0.24+/-0.22 2.66 +/- 0.68 "Uncertainties represent the 95% confidence level, based on propagating the uncertainties.

Total Uranium 1.91 +/- 0.62 390+/-20 2960+/-380 55.7 +/-4.4 2.61 +/-0.70 26.2 +/-2.6 37.4 +/-3.5 2.84+/-0.72 110 +/- 10 48.8 +/-4.1 14.8 +/- 1.7 30.4 +/-2.8 7.2 +/- 1.1

TABLE3 CONCENTRATION OF TECHNETIUM-99 IN WATER SAMPLES KERR-McGEE CIMARRON CRESCENT,OKLAHOMA ESSAPID NRCR-IVID Tc-99 Concentrations (pCi/L) 796W001 1314-1282 1.6 +/- 9.la 796W002 1315-1283 7.8 +/- 9.3 796W003 TMW-13-1284 460+/-10**

796W004 1316-1285 5.6 +/- 9.3 796W005 1344-1286 3.0+/-9.2 796W006 1336A-1287 1050 +/- 80 796W007.

1208-1288 2570+/- 190 796W008 1311-1289 0.9+/- 9.1 796W009 1206-1290 100+/- 20 796W010 1312-1291 1030+/-80 796W011 1330-1292 35+/- 10 796W012 1328-1293 2.5 +/- 9.2 796W013 1329-1294

-6.2+/-8.9 8Uncertainties represent the 95% confidence level, based on propagating the uncertainties.