ML19095B099

Appendix E, On-Site Lab Waste Sample Data, Gamma Spec Reports - UNC-IMC-2002-S-P-7

ML19095B099
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Issue date:	03/01/2018
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• • • • • G A M M A S P E C T R U M A N A L Y S I S *****

Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2002\\UNC-IMC-200 Report Generated On : 5/15/2017 10:46:31 AM Sample Title : W3H-IMC-2002-S-P-7 Sample Description :

Sample Identification : IMC-2002-S-P-7 Sample Type :

Sample Geometry : cylinder Peak Locate Threshold : 3.00 Peak Locate Range (in channels) : 40 - 8192 Peak Area Range (in channels) : 40 - 8192 Identification Energy Tolerance : 1.000 keV Sample Size : 3.645E+002 grams Sample Taken On : 5/1/2017 12:00:00 AM Acquisition Started : 5/10/2017 2:17:45 PM Live Time : 1800.0 seconds Real Time : 1800.5 seconds Dead Time : 0.03 %

Energy Calibration Used Done On : 4/13/2017 Efficiency Calibration Used Done On : 5/15/2017 Efficiency ID : H-IMC-2002-S-P-7

Peak Analysis Report 5/15/2017 10:46:31 AM Page 1

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Detector Name: 8566 Sample

Title:

W3H-IMC-2002-S-P-7 Peak Analysis Performed on: 5/15/2017 10:46:25 AM Peak Analysis From Channel: 40 Peak Analysis To Channel: 8192 Peak ROI ROI Peak Energy FWHM Net Peak Net Area Continuum No. start end centroid (keV) (keV) Area Uncert. Counts F 1 57-70 65.32 16.46 0.66 3.15E+002 35.75 1.89E+002 F 2 205-219 213.40 53.51 0.70 1.45E+002 22.66 1.58E+002 M 3 286-314 291.12 72.96 0.76 1.25E+002 52.52 2.03E+002 m 4 286-314 299.38 75.03 0.77 2.92E+002 106.08 2.12E+002 m 5 286-314 308.58 77.33 0.78 1.62E+002 62.25 2.16E+002 M 6 332-364 337.18 84.49 0.75 3.53E+002 38.17 1.90E+002 m 7 332-364 348.83 87.40 0.76 6.92E+001 22.40 2.39E+002 m 8 332-364 359.56 90.09 0.77 1.67E+002 28.62 2.49E+002 F 9 365-388 373.05 93.46 1.12 2.54E+002 120.45 3.64E+002 F 10 428-442 436.99 109.47 0.86 1.01E+002 88.54 1.90E+002 F 11 567-579 574.38 143.85 0.88 4.57E+002 41.31 1.38E+002 F 12 645-659 652.54 163.41 0.83 2.11E+002 86.16 1.18E+002 F 13 734-749 741.72 185.72 0.95 2.02E+003 146.28 1.04E+002 F 14 815-826 819.75 205.25 0.85 1.67E+002 26.52 5.85E+001 F 15 947-958 952.86 238.56 0.75 1.39E+002 26.61 8.40E+001 F 16 1175-1186 1179.98 295.40 0.84 4.27E+001 46.19 3.96E+001 F 17 1399-1410 1405.11 351.73 0.92 7.04E+001 19.57 3.96E+001 F 18 2031-2050 2039.63 510.52 2.02 6.25E+001 17.26 3.00E+001 F 19 2322-2336 2328.85 582.89 1.42 5.57E+001 17.34 2.50E+001 F 20 2425-2439 2432.19 608.75 1.54 4.65E+001 16.83 2.88E+001 F 21 5823-5849 5835.35 1460.38 2.98 2.00E+002 28.61 1.05E+001 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:46:31 AM Page 2

• • • • • N U C L I D E I D E N T I F I C A T I O N R E P O R T *****

Sample

Title:

W3H-IMC-2002-S-P-7 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201

.................... IDENTIFIED NUCLIDES....................

Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty K-40 0.969 1460.82* 10.66 9.96450E+000 1.65956E+000 Pb-212 0.942 74.82* 10.28 2.16785E+000 9.00092E-001 77.11* 17.10 7.03175E-001 3.05045E-001 86.83 2.07 87.35* 3.97 1.18879E+000 4.53015E-001 89.78* 1.46 7.69227E+000 2.02588E+000 115.18 0.60 238.63* 43.60 3.04261E-001 7.57070E-002 300.09 3.30 BI-214 0.185 76.86* 0.55 2.20629E+001 9.59168E+000 79.29 0.91 609.32* 45.49 2.51182E-001 9.56399E-002 665.45 1.53 768.36 4.89 806.18 1.26 934.06 3.11 1120.29 14.92 1155.21 1.63 1238.11 5.83 1280.98 1.43 1377.67 3.99 1385.31 0.79 1401.52 1.33 1407.99 2.39 1509.21 2.13 1583.20 0.70 1661.27 1.05 1729.59 2.88 1764.49 15.30 1847.43 2.03 2118.51 1.16 2204.06 4.92 2447.70 1.55 PB-214 0.846 74.82* 5.80 3.84232E+000 1.63196E+000 77.11* 9.70 1.23962E+000 5.49219E-001 86.83 1.70 87.35* 2.24 2.10691E+000 8.22794E-001 89.78* 0.82 1.36960E+001 3.79753E+000 241.99 7.25 258.76 0.53 295.22* 18.42 2.72378E-001 2.97569E-001 351.93* 35.60 2.77553E-001 8.72389E-002

Interference Corrected Activity Report 5/15/2017 10:46:31 AM Page 3 Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty PB-214 0.846 785.96 1.06 839.07 0.58 Ra-226 0.883 81.07 0.20 83.79* 0.32 7.59999E+001 1.73184E+001 186.21* 3.64 4.31684E+001 7.95427E+000 U-234 0.988 53.20* 0.12 1.45416E+002 4.17012E+001 120.90 0.04 U-235 0.998 89.96* 3.43 3.27422E+000 8.68652E-001 93.35* 5.54 3.03053E+000 1.56344E+000 104.82 0.69 105.60 1.31 108.58 0.50 109.19* 1.66 3.90634E+000 3.54823E+000 143.76* 10.96 2.81254E+000 6.11038E-001 163.36* 5.08 2.97428E+000 1.33821E+000 194.94 0.63 202.12 1.08 205.32* 5.02 2.80421E+000 6.28528E-001

• = Energy line found in the spectrum.

@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence index threshold = 0.10 Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:46:31 AM Page 4

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Nuclide Wt mean Wt mean Nuclide Id Activity Activity Name Confidence (pCi/gram) Uncertainty K-40 0.969 9.964499E+000 1.659557E+000 Pb-212 0.942 3.461718E-001 7.206998E-002 BI-214 0.185 2.517374E-001 9.561975E-002 PB-214 0.846 3.063297E-001 8.227004E-002 Ra-226 0.883 4.888774E+001 7.228307E+000 U-234 0.988 1.454159E+002 4.170123E+001 U-235 0.998 2.887900E+000 3.603074E-001

? = nuclide is part of an undetermined solution X = nuclide rejected by the interference analysis

@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:46:31 AM Page 5

• • • • • • • • • • U N I D E N T I F I E D P E A K S **********

Peak Locate Performed on: 5/15/2017 10:46:24 AM Peak Locate From Channel: 40 Peak Locate To Channel: 8192 Peak Energy Peak Size in Peak CPS Peak Tol.

No. (keV) Counts per Second % Uncertainty Type Nuclide F 1 16.46 1.7473E-001 11.37 M 3 72.96 6.9624E-002 41.91 F 18 510.52 3.4743E-002 27.61 F 19 582.89 3.0965E-002 31.12 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Nuclide MDA Report 5/15/2017 10:46:31 AM Page 6

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Detector Name: 8566 Sample Geometry: cylinder Sample

Title:

W3H-IMC-2002-S-P-7 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ K-40 1460.82* 10.66 9.753E-001 9.75E-001 9.964E+000 4.202E-00 Pb-210 46.54 4.25 2.719E+000 2.72E+000 1.856E+000 1.306E+00 BI-212 727.33 6.67 1.877E+000 1.88E+000 6.767E-001 8.796E-00 785.37 1.10 1.148E+001 2.187E+000 5.358E+00 1078.62 0.56 2.785E+001 1.894E+001 1.294E+00 1620.50 1.47 9.098E+000 -5.125E+000 4.014E+00

+ Pb-212 74.82* 10.28 5.224E-001 1.11E-001 2.168E+000 2.512E-00 77.11* 17.10 3.086E-001 7.032E-001 1.484E-00 86.83 2.07 4.022E+000 -6.263E+000 1.966E+00 87.35* 3.97 1.283E+000 1.189E+000 6.182E-00 89.78* 1.46 3.503E+000 7.692E+000 1.689E+00 115.18 0.60 9.252E+000 -2.057E+000 4.481E+00 238.63* 43.60 1.106E-001 3.043E-001 5.231E-00 300.09 3.30 2.016E+000 2.242E-001 9.590E-00

+ BI-214 76.86* 0.55 9.682E+000 1.58E-001 2.206E+001 4.657E+00 79.29 0.91 8.734E+000 3.475E-001 4.258E+00 609.32* 45.49 1.576E-001 2.512E-001 7.150E-00 665.45 1.53 7.663E+000 3.074E+000 3.595E+00 768.36 4.89 2.606E+000 7.331E-001 1.218E+00 806.18 1.26 8.928E+000 -2.350E+000 4.122E+00 934.06 3.11 3.977E+000 -7.695E-001 1.830E+00 1120.29 14.92 1.087E+000 -6.288E-001 5.050E-00 1155.21 1.63 9.514E+000 -1.921E+000 4.395E+00 1238.11 5.83 2.924E+000 1.471E+000 1.355E+00 1280.98 1.43 1.125E+001 -1.327E+000 5.177E+00 1377.67 3.99 3.681E+000 1.698E+000 1.669E+00 1385.31 0.79 1.694E+001 2.349E+000 7.601E+00 1401.52 1.33 1.088E+001 1.522E+000 4.916E+00 1407.99 2.39 6.420E+000 1.076E-001 2.919E+00 1509.21 2.13 6.784E+000 4.706E+000 3.045E+00 1583.20 0.70 2.023E+001 -1.011E+001 9.020E+00 1661.27 1.05 8.532E+000 -1.704E-001 3.497E+00 1729.59 2.88 4.312E+000 -1.694E+000 1.866E+00 1764.49 15.30 1.104E+000 6.593E-001 4.965E-00 1847.43 2.03 6.100E+000 1.458E-001 2.611E+00

> 2118.51 1.16 0.000E+000 0.000E+000 0.000E+00

> 2204.06 4.92 0.000E+000 0.000E+000 0.000E+00

> 2447.70 1.55 0.000E+000 0.000E+000 0.000E+00

+ PB-214 74.82* 5.80 9.260E-001 1.32E-001 3.842E+000 4.452E-00 77.11* 9.70 5.440E-001 1.240E+000 2.616E-00 86.83 1.70 4.898E+000 -7.626E+000 2.394E+00 87.35* 2.24 2.274E+000 2.107E+000 1.096E+00

Nuclide MDA Report 5/15/2017 10:46:31 AM Page 7 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ PB-214 89.78* 0.82 6.236E+000 1.32E-001 1.370E+001 3.007E+00 241.99 7.25 1.175E+000 -3.559E-001 5.692E-00 258.76 0.53 9.522E+000 2.371E+000 4.498E+00 295.22* 18.42 2.130E-001 2.724E-001 9.789E-00 351.93* 35.60 1.317E-001 2.776E-001 6.053E-00 785.96 1.06 1.195E+001 1.201E+000 5.575E+00 839.07 0.58 2.238E+001 4.184E+000 1.042E+00

+ Ra-226 81.07 0.20 3.431E+001 1.30E+000 7.847E+000 1.666E+00 83.79* 0.32 1.440E+001 7.600E+001 6.909E+00 186.21* 3.64 1.303E+000 4.317E+001 6.223E-00 AC-228 89.96 1.90 7.704E+011 1.18E+011 -1.299E+012 3.760E+01 93.35 3.10 4.688E+011 -1.131E+012 2.288E+01 99.51 1.26 7.808E+011 -3.983E+011 3.770E+01 105.60 0.74 1.564E+012 7.851E+011 7.595E+01 129.07 2.42 4.098E+011 -1.799E+011 1.979E+01 153.98 0.72 1.395E+012 3.338E+011 6.725E+01 209.25 3.89 2.994E+011 -5.393E+010 1.440E+01 214.85 0.76 1.338E+012 1.402E+012 6.389E+01 270.24 3.46 3.071E+011 1.329E+011 1.455E+01 328.00 2.95 4.158E+011 1.492E+011 1.964E+01 338.32 11.27 1.261E+011 9.447E+010 5.993E+01 409.46 1.92 7.351E+011 -4.007E+011 3.453E+01 463.00 4.40 3.706E+011 -9.535E+010 1.743E+01 562.50 0.87 2.205E+012 1.850E+012 1.035E+01 674.75 2.10 1.015E+012 -8.713E+010 4.740E+01 726.86 0.62 3.888E+012 1.085E+012 1.822E+01 755.32 1.00 2.179E+012 -2.248E+012 1.011E+01 772.29 1.49 1.656E+012 9.007E+011 7.742E+01 794.95 4.25 5.880E+011 3.477E+010 2.746E+01 830.49 0.54 4.361E+012 2.176E+012 2.022E+01 835.71 1.61 1.543E+012 3.953E+011 7.182E+01 840.38 0.91 2.827E+012 2.008E+012 1.318E+01 904.20 0.77 3.762E+012 -5.714E+012 1.761E+01 911.20 25.80 1.180E+011 3.517E+010 5.539E+01 964.77 4.99 6.558E+011 8.541E+011 3.083E+01 968.97 15.80 2.067E+011 1.682E+011 9.715E+01 1247.08 0.50 6.381E+012 -1.624E+012 2.948E+01 1459.14 0.83 8.992E+012 2.581E+013 4.329E+01 1495.91 0.86 2.981E+012 1.316E+012 1.326E+01 1588.20 3.22 8.879E+011 4.559E+010 3.977E+01 1630.63 1.51 1.634E+012 -8.508E+011 7.158E+01 TH-230 67.67 0.38 2.030E+001 2.03E+001 1.232E+000 9.848E+00 PA-234 742.81 0.11 1.183E+002 1.41E+001 2.069E+001 5.536E+00 766.42 0.32 3.877E+001 -1.109E+001 1.808E+00 1001.03 0.84 1.406E+001 -2.273E+001 6.409E+00 TH-234 63.29 3.70 2.069E+000 2.07E+000 -8.335E-001 1.001E+00 92.38 2.13 4.052E+000 1.359E+001 1.984E+00 92.80 2.10 3.862E+000 9.477E-001 1.888E+00 112.81 0.21 2.648E+001 2.842E+000 1.283E+00

+ U-234 53.20* 0.12 8.015E+001 8.01E+001 1.454E+002 3.872E+00 120.90 0.04 1.587E+002 7.756E+001 7.687E+00

Nuclide MDA Report 5/15/2017 10:46:31 AM Page 8 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ U-235 89.96* 3.43 1.491E+000 4.02E-001 3.274E+000 7.189E-00 93.35* 5.54 1.708E+000 3.031E+000 8.380E-00 104.82 0.69 8.793E+000 9.002E+000 4.269E+00 105.60 1.31 4.587E+000 2.302E+000 2.227E+00 108.58 0.50 1.257E+001 2.368E+000 6.111E+00 109.19* 1.66 3.374E+000 3.906E+000 1.635E+00 143.76* 10.96 4.019E-001 2.813E+000 1.926E-00 163.36* 5.08 8.948E-001 2.974E+000 4.283E-00 194.94 0.63 7.654E+000 4.825E+000 3.654E+00 202.12 1.08 6.366E+000 -6.519E+000 3.079E+00 205.32* 5.02 7.119E-001 2.804E+000 3.333E-00

+ = Nuclide identified during the nuclide identification

• = Energy line found in the spectrum

> = MDA value not calculated

@ = Half-life too short to be able to perform the decay correction

5/15/2017 10:46:31 LACE Lace v3.2.1 Page 1

• • • • L I N E A C T I V I T Y C O N S I S T E N C Y E V A L U A T O R ***

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Analysis using Key Line Activities

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Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2002\\UNC-IMC-200 Equation used to calculate plot: ln(Ratio) = A + B*ln(Energy) where: Ratio = Activity/KL Activity Notes:

'^' Denotes Key Line energy

• All uncertainties quoted at 1.96 sigma Nuclide Energy Activity Activity Ratio[%Uncert] A B (keV) (pCi/gram) %Uncert* [uncert]

K-40 1460.8 ^ 9.96E+000 16.655 Pb-212 74.8 2.17E+000 41.520 7.125[48.405] 9.94 -1.791 77.1 7.03E-001 43.381 2.311[50.010] [ 0.391]

87.3 1.19E+000 38.107 3.907[45.511]

89.8 7.69E+000 26.337 25.282[36.232]

238.6 ^ 3.04E-001 24.882 1.000[35.189]

BI-214 76.9 2.21E+001 43.474 87.836[57.791] 13.86 -2.162 609.3 ^ 2.51E-001 38.076 1.000[53.847] [ 0.382]

PB-214 74.8 3.84E+000 42.473 13.844[52.839] 10.55 -1.787 77.1 1.24E+000 44.305 4.466[54.322] [ 0.337]

87.3 2.11E+000 39.052 7.591[50.130]

89.8 1.37E+001 27.727 49.346[41.914]

295.2 2.72E-001 109.24 0.981[113.68]

351.9 ^ 2.78E-001 31.431 1.000[44.451]

Ra-226 83.8 7.60E+001 22.787 1.761[29.305] 3.70 -0.708 186.2 ^ 4.32E+001 18.426 1.000[26.058] [ 0.491]

U-234 53.2 ^ 1.45E+002 28.677 U-235 90.0 3.27E+000 26.530 1.164[34.291] 0.96 -0.184 93.3 3.03E+000 51.590 1.078[55.978] [ 0.509]

109.2 3.91E+000 90.833 1.389[93.395]

143.8 ^ 2.81E+000 21.726 1.000[30.725]

163.4 2.97E+000 44.993 1.058[49.963]

205.3 2.80E+000 22.414 0.997[31.215]