ML19095B091

Appendix E, On-Site Lab Waste Sample Data, Gamma Spec Reports - UNC-IMC-2002-S-P-5

ML19095B091
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Site:	07000371
Issue date:	03/01/2018
From:	Cabrera Services
To:	NRC Region 1
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• • • • • G A M M A S P E C T R U M A N A L Y S I S *****

Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2002\\UNC-IMC-200 Report Generated On : 5/15/2017 10:44:31 AM Sample Title : W3H-IMC-2002-S-P-5 Sample Description :

Sample Identification : IMC-2002-S-P-5 Sample Type :

Sample Geometry : cylinder Peak Locate Threshold : 3.00 Peak Locate Range (in channels) : 40 - 8192 Peak Area Range (in channels) : 40 - 8192 Identification Energy Tolerance : 1.000 keV Sample Size : 2.594E+002 grams Sample Taken On : 5/1/2017 12:00:00 AM Acquisition Started : 5/10/2017 11:26:42 AM Live Time : 1800.0 seconds Real Time : 1800.5 seconds Dead Time : 0.03 %

Energy Calibration Used Done On : 4/13/2017 Efficiency Calibration Used Done On : 5/15/2017 Efficiency ID : H-IMC-2002-S-P-5

Peak Analysis Report 5/15/2017 10:44:31 AM Page 1

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Detector Name: 8566 Sample

Title:

W3H-IMC-2002-S-P-5 Peak Analysis Performed on: 5/15/2017 10:44:18 AM Peak Analysis From Channel: 40 Peak Analysis To Channel: 8192 Peak ROI ROI Peak Energy FWHM Net Peak Net Area Continuum No. start end centroid (keV) (keV) Area Uncert. Counts F 1 59-70 65.36 16.47 0.81 4.99E+002 122.99 1.83E+002 F 2 97-109 102.98 25.88 0.59 1.06E+002 21.90 9.75E+001 F 3 209-219 213.24 53.47 0.70 1.26E+002 22.39 9.17E+001 M 4 286-313 291.53 73.06 0.87 1.48E+002 66.89 1.55E+002 m 5 286-313 299.55 75.07 0.87 2.55E+002 101.78 1.87E+002 m 6 286-313 308.14 77.22 0.88 9.97E+001 44.23 1.74E+002 F 7 332-344 337.29 84.52 0.81 3.29E+002 35.27 1.95E+002 F 8 354-364 359.98 90.19 0.82 1.39E+002 89.83 1.32E+002 F 9 365-378 373.76 93.64 0.60 1.63E+002 87.03 2.08E+002 F 10 480- 489 483.92 121.21 0.55 4.49E+001 60.99 1.05E+002 F 11 570- 581 574.62 143.91 0.81 4.03E+002 39.06 1.01E+002 F 12 647-659 652.46 163.38 0.83 1.65E+002 89.19 1.11E+002 F 13 735-751 741.97 185.78 0.90 1.89E+003 81.76 1.15E+002 F 14 815-826 820.12 205.34 0.85 1.38E+002 24.05 4.65E+001 F 15 946-959 953.37 238.69 0.96 1.00E+002 69.65 6.48E+001 F 16 1175-1184 1178.70 295.07 0.60 3.17E+001 13.42 2.40E+001 F 17 1401-1411 1405.83 351.91 0.95 4.38E+001 16.50 3.19E+001 F 18 2427-2441 2433.61 609.11 1.35 4.08E+001 14.88 1.75E+001 F 19 5825-5849 5836.61 1460.69 2.43 1.43E+002 24.45 6.94E+000 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:44:31 AM Page 2

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Sample

Title:

W3H-IMC-2002-S-P-5 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201

.................... IDENTIFIED NUCLIDES....................

Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty K-40 0.997 1460.82* 10.66 9.08051E+000 1.73808E+000 Pb-212 0.910 74.82* 10.28 2.14597E+000 9.61113E-001 77.11* 17.10 4.95018E-001 2.41084E-001 86.83 2.07 87.35 3.97 89.78* 1.46 7.45971E+000 5.03940E+000 115.18 0.60 238.63* 43.60 2.72019E-001 1.94144E-001 300.09 3.30 BI-214 0.220 76.86* 0.55 1.55318E+001 7.57717E+000 79.29 0.91 609.32* 45.49 2.77350E-001 1.06320E-001 665.45 1.53 768.36 4.89 806.18 1.26 934.06 3.11 1120.29 14.92 1155.21 1.63 1238.11 5.83 1280.98 1.43 1377.67 3.99 1385.31 0.79 1401.52 1.33 1407.99 2.39 1509.21 2.13 1583.20 0.70 1661.27 1.05 1729.59 2.88 1764.49 15.30 1847.43 2.03 2118.51 1.16 2204.06 4.92 2447.70 1.55 PB-214 0.795 74.82* 5.80 3.80354E+000 1.73715E+000 77.11* 9.70 8.72661E-001 4.32205E-001 86.83 1.70 87.35 2.24 89.78* 0.82 1.32819E+001 9.04620E+000 241.99 7.25 258.76 0.53 295.22* 18.42 2.50814E-001 1.13328E-001 351.93* 35.60 2.15608E-001 8.71331E-002

Interference Corrected Activity Report 5/15/2017 10:44:31 AM Page 3 Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty PB-214 0.795 785.96 1.06 839.07 0.58 Ra-226 0.888 81.07 0.20 83.79* 0.32 8.18253E+001 1.86106E+001 186.21* 3.64 4.98206E+001 8.70549E+000 U-234 0.987 53.20* 0.12 1.35211E+002 4.04897E+001 120.90* 0.04 9.88570E+001 1.38415E+002 U-235 0.996 89.96* 3.43 3.17524E+000 2.14743E+000 93.35* 5.54 2.28079E+000 1.29950E+000 104.82 0.69 105.60 1.31 108.58 0.50 109.19 1.66 143.76* 10.96 3.00311E+000 6.61040E-001 163.36* 5.08 2.85244E+000 1.62817E+000 194.94 0.63 202.12 1.08 205.32* 5.02 2.85334E+000 6.71810E-001

• = Energy line found in the spectrum.

@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence index threshold = 0.10 Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:44:31 AM Page 4

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Nuclide Wt mean Wt mean Nuclide Id Activity Activity Name Confidence (pCi/gram) Uncertainty K-40 0.997 9.080512E+000 1.738081E+000 Pb-212 0.910 3.460324E-001 1.498456E-001 BI-214 0.220 2.773965E-001 1.062963E-001 PB-214 0.795 2.339807E-001 6.850283E-002 Ra-226 0.888 5.556628E+001 7.885426E+000 U-234 0.987 1.323458E+002 3.886110E+001 U-235 0.996 2.858756E+000 4.170746E-001

? = nuclide is part of an undetermined solution X = nuclide rejected by the interference analysis

@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:44:31 AM Page 5

• • • • • • • • • • U N I D E N T I F I E D P E A K S **********

Peak Locate Performed on: 5/15/2017 10:44:18 AM Peak Locate From Channel: 40 Peak Locate To Channel: 8192 Peak Energy Peak Size in Peak CPS Peak Tol.

No. (keV) Counts per Second % Uncertainty Type Nuclide F 1 16.47 2.7738E-001 24.63 F 2 25.88 5.8809E-002 20.69 M 4 73.06 8.2070E-002 45.28 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Nuclide MDA Report 5/15/2017 10:44:31 AM Page 6

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Detector Name: 8566 Sample Geometry: cylinder Sample

Title:

W3H-IMC-2002-S-P-5 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ K-40 1460.82* 10.66 1.026E+000 1.03E+000 9.081E+000 4.267E-00 Pb-210 46.54 4.25 2.692E+000 2.69E+000 2.994E+000 1.291E+00 BI-212 727.33 6.67 2.014E+000 2.01E+000 -7.433E-001 9.325E-00 785.37 1.10 1.355E+001 2.148E+000 6.289E+00 1078.62 0.56 3.082E+001 -3.073E+000 1.415E+00 1620.50 1.47 1.108E+001 1.417E+000 4.855E+00

+ Pb-212 74.82* 10.28 5.596E-001 1.27E-001 2.146E+000 2.684E-00 77.11* 17.10 3.182E-001 4.950E-001 1.524E-00 86.83 2.07 4.158E+000 1.304E+000 2.027E+00 87.35 3.97 1.810E+000 6.783E-001 8.781E-00 89.78* 1.46 3.554E+000 7.460E+000 1.705E+00 115.18 0.60 1.023E+001 -1.601E+000 4.942E+00 238.63* 43.60 1.267E-001 2.720E-001 5.966E-00 300.09 3.30 2.204E+000 4.498E-003 1.041E+00

+ BI-214 76.86* 0.55 9.984E+000 1.59E-001 1.553E+001 4.781E+00 79.29 0.91 8.249E+000 -3.860E+000 4.000E+00 609.32* 45.49 1.588E-001 2.774E-001 7.019E-00 665.45 1.53 8.668E+000 1.826E+000 4.036E+00 768.36 4.89 3.376E+000 3.544E+000 1.581E+00 806.18 1.26 1.200E+001 7.423E+000 5.567E+00 934.06 3.11 4.934E+000 -1.782E+000 2.266E+00 1120.29 14.92 1.337E+000 7.133E-001 6.194E-00 1155.21 1.63 1.176E+001 -8.709E-001 5.420E+00 1238.11 5.83 3.493E+000 -8.201E-001 1.610E+00 1280.98 1.43 1.374E+001 2.537E+000 6.298E+00 1377.67 3.99 4.697E+000 9.619E-001 2.129E+00 1385.31 0.79 2.123E+001 -3.906E+000 9.511E+00 1401.52 1.33 1.256E+001 8.207E-001 5.612E+00 1407.99 2.39 7.505E+000 -4.883E-001 3.381E+00 1509.21 2.13 7.538E+000 3.717E+000 3.325E+00 1583.20 0.70 2.636E+001 4.422E+000 1.178E+00 1661.27 1.05 1.506E+001 2.907E-001 6.549E+00 1729.59 2.88 5.686E+000 3.114E+000 2.472E+00 1764.49 15.30 1.460E+000 3.733E-001 6.587E-00 1847.43 2.03 7.227E+000 9.543E-001 3.052E+00

> 2118.51 1.16 0.000E+000 0.000E+000 0.000E+00

> 2204.06 4.92 0.000E+000 0.000E+000 0.000E+00

> 2447.70 1.55 0.000E+000 0.000E+000 0.000E+00

+ PB-214 74.82* 5.80 9.918E-001 1.46E-001 3.804E+000 4.757E-00 77.11* 9.70 5.610E-001 8.727E-001 2.686E-00 86.83 1.70 5.063E+000 1.588E+000 2.468E+00 87.35 2.24 3.208E+000 1.202E+000 1.556E+00

Nuclide MDA Report 5/15/2017 10:44:31 AM Page 7 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ PB-214 89.78* 0.82 6.328E+000 1.46E-001 1.328E+001 3.035E+00 241.99 7.25 1.200E+000 -2.856E-001 5.777E-00 258.76 0.53 1.043E+001 -8.581E+000 4.888E+00 295.22* 18.42 2.020E-001 2.508E-001 9.028E-00 351.93* 35.60 1.458E-001 2.156E-001 6.626E-00 785.96 1.06 1.421E+001 -1.064E-001 6.600E+00 839.07 0.58 2.337E+001 -1.505E+001 1.071E+00

+ Ra-226 81.07 0.20 3.472E+001 1.71E+000 2.098E+000 1.679E+00 83.79* 0.32 2.102E+001 8.183E+001 1.017E+00 186.21* 3.64 1.710E+000 4.982E+001 8.194E-00 AC-228 89.96 1.90 5.691E+011 9.97E+010 6.429E+011 2.767E+01 93.35 3.10 3.601E+011 -5.197E+011 1.753E+01 99.51 1.26 5.411E+011 -6.986E+011 2.591E+01 105.60 0.74 1.229E+012 -2.224E+011 5.952E+01 129.07 2.42 3.340E+011 -5.990E+010 1.609E+01 153.98 0.72 1.061E+012 2.537E+011 5.081E+01 209.25 3.89 2.356E+011 -1.357E+011 1.127E+01 214.85 0.76 9.613E+011 -7.354E+011 4.538E+01 270.24 3.46 2.513E+011 2.858E+010 1.183E+01 328.00 2.95 3.230E+011 7.706E+009 1.511E+01 338.32 11.27 1.073E+011 8.334E+010 5.084E+01 409.46 1.92 6.781E+011 -4.351E+011 3.188E+01 463.00 4.40 3.007E+011 8.414E+010 1.403E+01 562.50 0.87 1.960E+012 1.674E+012 9.179E+01 674.75 2.10 9.531E+011 3.931E+011 4.458E+01 726.86 0.62 2.971E+012 -1.571E+012 1.374E+01 755.32 1.00 2.043E+012 8.125E+011 9.498E+01 772.29 1.49 1.444E+012 -6.243E+011 6.725E+01 794.95 4.25 4.962E+011 7.869E+010 2.303E+01 830.49 0.54 4.321E+012 3.070E+012 2.015E+01 835.71 1.61 1.278E+012 -2.045E+011 5.902E+01 840.38 0.91 2.047E+012 -1.243E+012 9.362E+01 904.20 0.77 3.102E+012 -2.952E+012 1.441E+01 911.20 25.80 9.971E+010 5.814E+010 4.655E+01 964.77 4.99 5.269E+011 2.218E+011 2.455E+01 968.97 15.80 1.594E+011 1.501E+010 7.402E+01 1247.08 0.50 6.055E+012 3.000E+011 2.803E+01 1459.14 0.83 7.334E+012 1.743E+013 3.513E+01 1495.91 0.86 2.042E+012 -1.276E+012 8.686E+01 1588.20 3.22 7.776E+011 -3.029E+011 3.459E+01 1630.63 1.51 1.515E+012 -5.434E+011 6.639E+01 TH-230 67.67 0.38 1.826E+001 1.83E+001 -1.839E+000 8.790E+00 PA-234 742.81 0.11 1.319E+002 2.00E+001 -8.032E+000 6.118E+00 766.42 0.32 4.998E+001 2.955E+000 2.334E+00 1001.03 0.84 1.996E+001 1.893E+000 9.191E+00 TH-234 63.29 3.70 1.910E+000 1.91E+000 -3.986E-001 9.172E-00 92.38 2.13 4.169E+000 1.041E+001 2.035E+00 92.80 2.10 4.092E+000 4.172E+000 1.996E+00 112.81 0.21 2.856E+001 -4.220E+001 1.379E+00

+ U-234 53.20* 0.12 5.994E+001 5.99E+001 1.352E+002 2.851E+00 120.90* 0.04 1.172E+002 9.886E+001 5.564E+00

Nuclide MDA Report 5/15/2017 10:44:31 AM Page 8 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ U-235 89.96* 3.43 1.513E+000 4.09E-001 3.175E+000 7.256E-00 93.35* 5.54 1.246E+000 2.281E+000 6.042E-00 104.82 0.69 9.407E+000 9.415E+000 4.553E+00 105.60 1.31 4.971E+000 -8.993E-001 2.407E+00 108.58 0.50 1.374E+001 -2.559E+000 6.663E+00 109.19 1.66 4.058E+000 -1.061E+000 1.967E+00 143.76* 10.96 4.091E-001 3.003E+000 1.945E-00 163.36* 5.08 1.013E+000 2.852E+000 4.833E-00 194.94 0.63 8.828E+000 1.223E+000 4.200E+00 202.12 1.08 7.213E+000 -2.724E+000 3.478E+00 205.32* 5.02 7.886E-001 2.853E+000 3.663E-00

+ = Nuclide identified during the nuclide identification

• = Energy line found in the spectrum

> = MDA value not calculated

@ = Half-life too short to be able to perform the decay correction

5/15/2017 10:44:31 LACE Lace v3.2.1 Page 1

• • • • L I N E A C T I V I T Y C O N S I S T E N C Y E V A L U A T O R ***

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Analysis using Key Line Activities

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Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2002\\UNC-IMC-200 Equation used to calculate plot: ln(Ratio) = A + B*ln(Energy) where: Ratio = Activity/KL Activity Notes:

'^' Denotes Key Line energy

• All uncertainties quoted at 1.96 sigma Nuclide Energy Activity Activity Ratio[%Uncert] A B (keV) (pCi/gram) %Uncert* [uncert]

K-40 1460.8 ^ 9.08E+000 19.141 Pb-212 74.8 2.15E+000 44.787 7.889[84.260] 8.18 -1.453 77.1 4.95E-001 48.702 1.820[86.405] [ 1.019]

89.8 7.46E+000 67.555 27.424[98.273]

238.6 ^ 2.72E-001 71.371 1.000[100.93]

BI-214 76.9 1.55E+001 48.785 56.001[62.044] 12.47 -1.944 609.3 ^ 2.77E-001 38.334 1.000[54.213] [ 0.398]

PB-214 74.8 3.80E+000 45.672 17.641[60.985] 10.20 -1.742 77.1 8.73E-001 49.527 4.047[63.923] [ 0.399]

89.8 1.33E+001 68.109 61.602[79.196]

295.2 2.51E-001 45.184 1.163[60.620]

351.9 ^ 2.16E-001 40.413 1.000[57.152]

Ra-226 83.8 8.18E+001 22.744 1.642[28.682] 3.25 -0.621 186.2 ^ 4.98E+001 17.474 1.000[24.712] [ 0.474]

U-234 53.2 ^ 1.35E+002 29.945 1.000[42.349] 1.52 -0.381 120.9 9.89E+001 140.01 0.731[143.18] [ 1.819]

U-235 90.0 3.18E+000 67.631 1.057[71.122] -0.41 0.072 93.3 2.28E+000 56.976 0.759[61.080] [ 0.691]

143.8 ^ 3.00E+000 22.012 1.000[31.129]

163.4 2.85E+000 57.080 0.950[61.177]

205.3 2.85E+000 23.545 0.950[32.232]