ML19095B088

Appendix E, On-Site Lab Waste Sample Data, Gamma Spec Reports - UNC-IMC-2002-S-P-4

ML19095B088
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Site:	07000371
Issue date:	03/01/2018
From:	Cabrera Services
To:	NRC Region 1
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• • • • • G A M M A S P E C T R U M A N A L Y S I S *****

Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2002\\UNC-IMC-200 Report Generated On : 5/15/2017 10:43:32 AM Sample Title : W3H-IMC-2002-S-P-4 Sample Description :

Sample Identification : IMC-2002-S-P-4 Sample Type :

Sample Geometry : cylinder Peak Locate Threshold : 3.00 Peak Locate Range (in channels) : 40 - 8192 Peak Area Range (in channels) : 40 - 8192 Identification Energy Tolerance : 1.000 keV Sample Size : 2.374E+002 grams Sample Taken On : 5/3/2017 12:00:00 AM Acquisition Started : 5/9/2017 12:12:01 PM Live Time : 1800.0 seconds Real Time : 1800.4 seconds Dead Time : 0.02 %

Energy Calibration Used Done On : 4/13/2017 Efficiency Calibration Used Done On : 5/15/2017 Efficiency ID : H-IMC-2002-S-P-4

Peak Analysis Report 5/15/2017 10:43:32 AM Page 1

• • • • • P E A K A N A L Y S I S R E P O R T *****

Detector Name: 8566 Sample

Title:

W3H-IMC-2002-S-P-4 Peak Analysis Performed on: 5/15/2017 10:43:28 AM Peak Analysis From Channel: 40 Peak Analysis To Channel: 8192 Peak ROI ROI Peak Energy FWHM Net Peak Net Area Continuum No. start end centroid (keV) (keV) Area Uncert. Counts F 1 98-107 102.71 25.81 0.54 5.38E+001 17.83 6.50E+001 F 2 207-219 213.52 53.54 0.88 8.50E+001 63.56 7.58E+001 M 3 295-315 299.35 75.02 0.52 1.04E+002 26.96 1.62E+002 m 4 295-315 308.62 77.34 0.52 5.40E+001 19.62 1.19E+002 F 5 332-344 337.54 84.58 0.86 1.92E+002 26.53 1.13E+002 F 6 355-364 359.69 90.12 0.51 5.88E+001 20.90 1.12E+002 F 7 366-378 372.86 93.42 1.05 1.32E+002 96.33 8.67E+001 F 8 567-581 574.34 143.84 0.81 2.21E+002 29.30 1.05E+002 F 9 647-658 652.81 163.47 0.88 9.10E+001 20.72 7.05E+001 F 10 736-751 741.93 185.77 0.91 1.03E+003 60.49 7.80E+001 F 11 813-828 820.68 205.48 0.70 8.76E+001 49.23 5.00E+001 F 12 945-958 953.77 238.79 0.56 9.74E+001 49.28 4.20E+001 F 13 1173-1183 1178.66 295.06 0.75 2.73E+001 13.62 2.97E+001 F 14 1400- 1412 1405.77 351.90 0.94 3.81E+001 15.06 3.12E+001 F 15 2322-2336 2329.66 583.10 1.13 2.93E+001 13.68 2.38E+001 F 16 2425-2438 2431.75 608.64 1.46 3.46E+001 14.62 2.10E+001 F 17 4469-4482 4475.87 1120.17 1.14 1.38E+001 9.17 8.75E+000 F 18 5822-5851 5836.12 1460.57 2.84 1.47E+002 24.56 6.67E+000 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:43:32 AM Page 2

• • • • • N U C L I D E I D E N T I F I C A T I O N R E P O R T *****

Sample

Title:

W3H-IMC-2002-S-P-4 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201

.................... IDENTIFIED NUCLIDES....................

Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty K-40 0.990 1460.82* 10.66 1.01443E+001 1.90226E+000 Pb-212 0.995 74.82* 10.28 9.17388E-001 3.01556E-001 77.11* 17.10 2.80774E-001 1.16621E-001 86.83 2.07 87.35 3.97 89.78* 1.46 3.32885E+000 1.35678E+000 115.18 0.60 238.63* 43.60 2.84365E-001 1.50826E-001 300.09 3.30 BI-214 0.453 76.86* 0.55 8.80961E+000 3.66767E+000 79.29 0.91 609.32* 45.49 2.53612E-001 1.11323E-001 665.45 1.53 768.36 4.89 806.18 1.26 934.06 3.11 1120.29* 14.92 5.39814E-001 3.62267E-001 1155.21 1.63 1238.11 5.83 1280.98 1.43 1377.67 3.99 1385.31 0.79 1401.52 1.33 1407.99 2.39 1509.21 2.13 1583.20 0.70 1661.27 1.05 1729.59 2.88 1764.49 15.30 1847.43 2.03 2118.51 1.16 2204.06 4.92 2447.70 1.55 PB-214 0.851 74.82* 5.80 1.62599E+000 5.53928E-001 77.11* 9.70 4.94973E-001 2.10363E-001 86.83 1.70 87.35 2.24 89.78* 0.82 5.92699E+000 2.46980E+000 241.99 7.25 258.76 0.53 295.22* 18.42 2.32746E-001 1.21636E-001 351.93* 35.60 2.01955E-001 8.51190E-002

Interference Corrected Activity Report 5/15/2017 10:43:32 AM Page 3 Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty PB-214 0.851 785.96 1.06 839.07 0.58 Ra-226 0.885 81.07 0.20 83.79* 0.32 5.01826E+001 1.22309E+001 186.21* 3.64 2.90777E+001 5.21067E+000 U-234 0.985 53.20* 0.12 9.34350E+001 7.33965E+001 120.90 0.04 U-235 0.998 89.96* 3.43 1.41694E+000 5.79293E-001 93.35* 5.54 1.95020E+000 1.47568E+000 104.82 0.69 105.60 1.31 108.58 0.50 109.19 1.66 143.76* 10.96 1.76249E+000 4.19190E-001 163.36* 5.08 1.67953E+000 4.94920E-001 194.94 0.63 202.12 1.08 205.32* 5.02 1.94152E+000 1.13423E+000

• = Energy line found in the spectrum.

@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence index threshold = 0.10 Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:43:32 AM Page 4

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Nuclide Wt mean Wt mean Nuclide Id Activity Activity Name Confidence (pCi/gram) Uncertainty K-40 0.990 1.014427E+001 1.902263E+000 Pb-212 0.995 2.504199E-001 9.133370E-002 BI-214 0.453 2.757138E-001 1.063812E-001 PB-214 0.851 2.078749E-001 6.820181E-002 Ra-226 0.885 3.231980E+001 4.793765E+000 U-234 0.985 9.343500E+001 7.339649E+001 U-235 0.998 1.646829E+000 2.661505E-001

? = nuclide is part of an undetermined solution X = nuclide rejected by the interference analysis

@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 1.960 sigma

Interference Corrected Activity Report 5/15/2017 10:43:32 AM Page 5

• • • • • • • • • • U N I D E N T I F I E D P E A K S **********

Peak Locate Performed on: 5/15/2017 10:43:28 AM Peak Locate From Channel: 40 Peak Locate To Channel: 8192 Peak Energy Peak Size in Peak CPS Peak Tol.

No. (keV) Counts per Second % Uncertainty Type Nuclide F 1 25.81 2.9874E-002 33.16 F 15 583.10 1.6259E-002 46.74 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Nuclide MDA Report 5/15/2017 10:43:32 AM Page 6

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Detector Name: 8566 Sample Geometry: cylinder Sample

Title:

W3H-IMC-2002-S-P-4 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ K-40 1460.82* 10.66 1.144E+000 1.14E+000 1.014E+001 4.788E-00 Pb-210 46.54 4.25 2.313E+000 2.31E+000 2.074E+000 1.100E+00 BI-212 727.33 6.67 2.232E+000 2.23E+000 -1.874E+000 1.036E+00 785.37 1.10 1.391E+001 2.820E+000 6.430E+00 1078.62 0.56 3.264E+001 -8.914E+000 1.496E+00 1620.50 1.47 1.202E+001 1.537E+000 5.265E+00

+ Pb-212 74.82* 10.28 5.472E-001 1.11E-001 9.174E-001 2.617E-00 77.11* 17.10 2.774E-001 2.808E-001 1.317E-00 86.83 2.07 3.658E+000 1.954E+000 1.774E+00 87.35 3.97 1.682E+000 1.016E+000 8.127E-00 89.78* 1.46 3.365E+000 3.329E+000 1.606E+00 115.18 0.60 8.705E+000 2.157E+000 4.168E+00 238.63* 43.60 1.112E-001 2.844E-001 5.163E-00 300.09 3.30 2.360E+000 -2.390E+000 1.114E+00

+ BI-214 76.86* 0.55 8.704E+000 1.83E-001 8.810E+000 4.131E+00 79.29 0.91 7.800E+000 7.076E-001 3.770E+00 609.32* 45.49 1.826E-001 2.536E-001 8.139E-00 665.45 1.53 8.703E+000 5.422E+000 4.030E+00 768.36 4.89 3.625E+000 2.500E+000 1.697E+00 806.18 1.26 1.196E+001 -2.642E+000 5.513E+00 934.06 3.11 5.668E+000 -3.174E+000 2.617E+00 1120.29* 14.92 6.289E-001 5.398E-001 2.614E-00 1155.21 1.63 1.196E+001 -1.748E+000 5.482E+00 1238.11 5.83 4.034E+000 3.321E+000 1.869E+00 1280.98 1.43 1.311E+001 -3.435E+000 5.933E+00 1377.67 3.99 4.944E+000 3.303E+000 2.234E+00 1385.31 0.79 2.644E+001 3.741E+000 1.202E+00 1401.52 1.33 1.198E+001 -2.313E+000 5.268E+00 1407.99 2.39 6.682E+000 -2.398E+000 2.938E+00 1509.21 2.13 7.369E+000 -1.481E+000 3.203E+00 1583.20 0.70 3.013E+001 -5.106E+000 1.355E+00 1661.27 1.05 1.536E+001 -4.138E+000 6.612E+00 1729.59 2.88 5.986E+000 1.994E+000 2.590E+00 1764.49 15.30 1.311E+000 6.673E-001 5.783E-00 1847.43 2.03 7.841E+000 1.035E+000 3.311E+00

> 2118.51 1.16 0.000E+000 0.000E+000 0.000E+00

> 2204.06 4.92 0.000E+000 0.000E+000 0.000E+00

> 2447.70 1.55 0.000E+000 0.000E+000 0.000E+00

+ PB-214 74.82* 5.80 9.699E-001 1.62E-001 1.626E+000 4.638E-00 77.11* 9.70 4.891E-001 4.950E-001 2.321E-00 86.83 1.70 4.454E+000 2.379E+000 2.161E+00 87.35 2.24 2.982E+000 1.801E+000 1.440E+00

Nuclide MDA Report 5/15/2017 10:43:32 AM Page 7 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ PB-214 89.78* 0.82 5.991E+000 1.62E-001 5.927E+000 2.859E+00 241.99 7.25 1.233E+000 -9.226E-001 5.924E-00 258.76 0.53 1.251E+001 -2.435E+000 5.905E+00 295.22* 18.42 2.444E-001 2.327E-001 1.107E-00 351.93* 35.60 1.620E-001 2.020E-001 7.383E-00 785.96 1.06 1.434E+001 -4.026E-001 6.623E+00 839.07 0.58 2.893E+001 5.942E+000 1.341E+00

+ Ra-226 81.07 0.20 2.984E+001 1.50E+000 9.846E+000 1.432E+00 83.79* 0.32 1.699E+001 5.018E+001 8.139E+00 186.21* 3.64 1.495E+000 2.908E+001 7.095E-00 AC-228 89.96 1.90 1.640E+008 3.60E+007 1.154E+008 7.931E+00 93.35 3.10 9.719E+007 1.248E+008 4.697E+00 99.51 1.26 1.840E+008 -1.022E+007 8.805E+00 105.60 0.74 3.279E+008 -4.841E+008 1.572E+00 129.07 2.42 9.775E+007 -3.590E+007 4.675E+00 153.98 0.72 3.370E+008 -8.836E+007 1.608E+00 209.25 3.89 7.370E+007 2.875E+007 3.506E+00 214.85 0.76 3.408E+008 1.402E+008 1.610E+00 270.24 3.46 8.981E+007 0.000E+000 4.235E+00 328.00 2.95 1.265E+008 -7.832E+007 5.960E+00 338.32 11.27 3.595E+007 -1.132E+007 1.699E+00 409.46 1.92 2.079E+008 -1.401E+008 9.687E+00 463.00 4.40 1.078E+008 2.845E+007 5.036E+00 562.50 0.87 5.843E+008 -8.058E+006 2.704E+00 674.75 2.10 3.099E+008 2.114E+008 1.441E+00 726.86 0.62 1.101E+009 -7.855E+008 5.110E+00 755.32 1.00 7.735E+008 2.004E+008 3.614E+00 772.29 1.49 4.927E+008 1.025E+008 2.290E+00 794.95 4.25 1.746E+008 6.133E+007 8.107E+00 830.49 0.54 1.322E+009 -3.890E+008 6.096E+00 835.71 1.61 4.827E+008 1.695E+008 2.241E+00 840.38 0.91 8.299E+008 -2.852E+008 3.843E+00 904.20 0.77 1.144E+009 -5.300E+008 5.332E+00 911.20 25.80 3.883E+007 4.102E+007 1.825E+00 964.77 4.99 1.786E+008 -6.206E+007 8.298E+00 968.97 15.80 6.057E+007 4.659E+007 2.828E+00 1247.08 0.50 1.788E+009 -4.270E+008 8.151E+00 1459.14 0.83 2.568E+009 6.330E+009 1.229E+00 1495.91 0.86 8.237E+008 1.523E+008 3.581E+00 1588.20 3.22 2.907E+008 1.492E+007 1.302E+00 1630.63 1.51 5.351E+008 6.844E+007 2.345E+00 TH-230 67.67 0.38 1.732E+001 1.73E+001 1.575E+001 8.307E+00 PA-234 742.81 0.11 1.389E+002 2.31E+001 7.594E+000 6.431E+00 766.42 0.32 5.583E+001 1.879E-001 2.614E+00 1001.03 0.84 2.306E+001 8.707E+000 1.068E+00 TH-234 63.29 3.70 1.868E+000 1.87E+000 -2.547E-001 8.951E-00 92.38 2.13 3.498E+000 8.297E+000 1.697E+00 92.80 2.10 3.332E+000 3.549E+000 1.613E+00 112.81 0.21 2.557E+001 -3.726E+001 1.226E+00

+ U-234 53.20* 0.12 5.902E+001 5.90E+001 9.344E+001 2.802E+00 120.90 0.04 1.612E+002 8.927E+001 7.742E+00

Nuclide MDA Report 5/15/2017 10:43:32 AM Page 8 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ U-235 89.96* 3.43 1.432E+000 4.77E-001 1.417E+000 6.835E-00 93.35* 5.54 8.445E-001 1.950E+000 4.023E-00 104.82 0.69 7.967E+000 5.356E+000 3.824E+00 105.60 1.31 4.072E+000 -6.011E+000 1.953E+00 108.58 0.50 1.190E+001 2.340E+000 5.731E+00 109.19 1.66 3.502E+000 -2.026E-001 1.685E+00 143.76* 10.96 4.768E-001 1.762E+000 2.276E-00 163.36* 5.08 8.565E-001 1.680E+000 4.033E-00 194.94 0.63 9.328E+000 -1.819E+000 4.435E+00 202.12 1.08 6.845E+000 -1.016E-001 3.285E+00 205.32* 5.02 9.534E-001 1.942E+000 4.467E-00

+ = Nuclide identified during the nuclide identification

• = Energy line found in the spectrum

> = MDA value not calculated

@ = Half-life too short to be able to perform the decay correction

5/15/2017 10:43:33 LACE Lace v3.2.1 Page 1

• • • • L I N E A C T I V I T Y C O N S I S T E N C Y E V A L U A T O R ***

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Analysis using Key Line Activities

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Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2002\\UNC-IMC-200 Equation used to calculate plot: ln(Ratio) = A + B*ln(Energy) where: Ratio = Activity/KL Activity Notes:

'^' Denotes Key Line energy

• All uncertainties quoted at 1.96 sigma Nuclide Energy Activity Activity Ratio[%Uncert] A B (keV) (pCi/gram) %Uncert* [uncert]

K-40 1460.8 ^ 1.01E+001 18.752 Pb-212 74.8 9.17E-001 32.871 3.226[62.400] 4.80 -0.833 77.1 2.81E-001 41.535 0.987[67.368] [ 0.759]

89.8 3.33E+000 40.758 11.706[66.891]

238.6 ^ 2.84E-001 53.040 1.000[75.009]

BI-214 76.9 8.81E+000 41.633 34.737[60.498] 9.11 -1.315 609.3 ^ 2.54E-001 43.895 1.000[62.077] [ 0.332]

1120.3 5.40E-001 67.110 2.129[80.190]

PB-214 74.8 1.63E+000 34.067 8.051[54.194] 8.07 -1.368 77.1 4.95E-001 42.500 2.451[59.855] [ 0.393]

89.8 5.93E+000 41.670 29.348[59.269]

295.2 2.33E-001 52.261 1.152[67.139]

351.9 ^ 2.02E-001 42.147 1.000[59.605]

Ra-226 83.8 5.02E+001 24.373 1.726[30.251] 3.57 -0.683 186.2 ^ 2.91E+001 17.920 1.000[25.342] [ 0.494]

U-234 53.2 ^ 9.34E+001 78.554 U-235 90.0 1.42E+000 40.883 0.804[47.298] -1.20 0.236 93.3 1.95E+000 75.669 1.106[79.318] [ 0.774]

143.8 ^ 1.76E+000 23.784 1.000[33.636]

163.4 1.68E+000 29.468 0.953[37.868]

205.3 1.94E+000 58.420 1.102[63.076]