ML19095A947

Appendix E, On-Site Lab Waste Sample Data, Gamma Spec Reports - UNC-GFLU-2123-S-P-2

ML19095A947
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Site:	07000371
Issue date:	03/01/2018
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To:	NRC Region 1
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• • • • • G A M M A S P E C T R U M A N A L Y S I S *****

Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2123\\UNC-GFLU-21 Report Generated On : 7/6/2017 10:11:12 AM Sample Title : UNC-GFLU-2123-S-P-2 Sample Description :

Sample Identification : UNC-GFLU-2123-S-Sample Type :

Sample Geometry : cylinder Peak Locate Threshold : 3.00 Peak Locate Range (in channels) : 40 - 8192 Peak Area Range (in channels) : 40 - 8192 Identification Energy Tolerance : 1.000 keV Sample Size : 3.476E+002 grams Sample Taken On : 6/1/2017 2:00:00 PM Acquisition Started : 6/5/2017 10:07:04 AM Live Time : 1800.0 seconds Real Time : 1800.5 seconds Dead Time : 0.03 %

Energy Calibration Used Done On : 4/13/2017 Efficiency Calibration Used Done On : 7/6/2017 Efficiency ID : H-IMC-2002-S-P-5

Peak Analysis Report 7/6/2017 10:11:12 AM Page 1

• • • • • P E A K A N A L Y S I S R E P O R T *****

Detector Name: 8566 Sample

Title:

UNC-GFLU-2123-S-P-2 Peak Analysis Performed on: 7/6/2017 10:11:08 AM Peak Analysis From Channel: 40 Peak Analysis To Channel: 8192 Peak ROI ROI Peak Energy FWHM Net Peak Net Area Continuum No. start end centroid (keV) (keV) Area Uncert. Counts F 1 208-219 213.00 53.41 0.59 4.06E+001 41.22 5.40E+001 M 2 296-315 299.49 75.06 0.68 1.24E+002 23.54 8.70E+001 m 3 296-315 308.02 77.19 0.69 7.68E+001 19.54 1.16E+002 F 4 344-353 349.88 87.67 0.20 2.98E+001 11.55 9.17E+001 F 5 571-579 573.52 143.63 0.50 5.70E+001 19.05 5.96E+001 F 6 736-751 741.83 185.75 0.90 4.03E+002 101.70 7.60E+001 F 7 814-825 820.25 205.37 0.68 3.56E+001 36.33 3.60E+001 F 8 946-957 952.91 238.57 0.90 9.38E+001 20.91 4.50E+001 F 9 1174-1183 1178.63 295.06 0.79 2.77E+001 13.84 2.90E+001 F 10 1400- 1411 1405.15 351.74 1.12 4.60E+001 16.42 2.88E+001 F 11 2425-2441 2433.40 609.06 1.38 5.34E+001 16.67 2.27E+001 F 12 5823-5847 5835.25 1460.35 2.51 1.41E+002 24.60 1.11E+001 F 13 7045-7060 7052.42 1764.94 1.72 1.36E+001 9.18 4.00E+000 M = First peak in a multiplet region m = Other peak in a multiplet region F = Fitted singlet Errors quoted at 1.960 sigma

Interference Corrected Activity Report 7/6/2017 10:11:12 AM Page 2

• • • • • N U C L I D E I D E N T I F I C A T I O N R E P O R T *****

Sample

Title:

UNC-GFLU-2123-S-P-2 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201

.................... IDENTIFIED NUCLIDES....................

Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty K-40 0.965 1460.82* 10.66 6.67822E+000 1.26622E+000 Pb-212 0.998 74.82* 10.28 7.77436E-001 1.81398E-001 77.11* 17.10 2.84400E-001 8.16994E-002 86.83 2.07 87.35* 3.97 4.42895E-001 1.80536E-001 89.78 1.46 115.18 0.60 238.63* 43.60 1.90261E-001 4.65428E-002 300.09 3.30 BI-214 0.443 76.86* 0.55 8.92337E+000 2.57593E+000 79.29 0.91 609.32* 45.49 2.71165E-001 8.70700E-002 665.45 1.53 768.36 4.89 806.18 1.26 934.06 3.11 1120.29 14.92 1155.21 1.63 1238.11 5.83 1280.98 1.43 1377.67 3.99 1385.31 0.79 1401.52 1.33 1407.99 2.39 1509.21 2.13 1583.20 0.70 1661.27 1.05 1729.59 2.88 1764.49* 15.30 5.32001E-001 3.61658E-001 1847.43 2.03 2118.51 1.16 2204.06 4.92 2447.70 1.55 PB-214 0.849 74.82* 5.80 1.37794E+000 3.44340E-001 77.11* 9.70 5.01365E-001 1.50934E-001 86.83 1.70 87.35* 2.24 7.84952E-001 3.26911E-001 89.78 0.82 241.99 7.25 258.76 0.53 295.22* 18.42 1.63476E-001 8.31111E-002 351.93* 35.60 1.68774E-001 6.19226E-002

Interference Corrected Activity Report 7/6/2017 10:11:12 AM Page 3 Nuclide Id Energy Yield Activity Activity Name Confidence (keV) (%) (pCi/gram) Uncertainty PB-214 0.849 785.96 1.06 839.07 0.58 Ra-226 0.971 81.07 0.20 83.79 0.32 186.21* 3.64 7.90834E+000 2.16488E+000 U-234 0.994 53.20* 0.12 3.26819E+001 3.35494E+001 120.90 0.04 U-235 0.999 89.96 3.43 93.35 5.54 104.82 0.69 105.60 1.31 108.58 0.50 109.19 1.66 143.76* 10.96 3.16868E-001 1.11056E-001 163.36 5.08 194.94 0.63 202.12 1.08 205.32* 5.02 5.49172E-001 5.63004E-001

• = Energy line found in the spectrum.

@ = Energy line not used for Weighted Mean Activity Energy Tolerance : 1.000 keV Nuclide confidence index threshold = 0.10 Errors quoted at 1.960 sigma

Interference Corrected Activity Report 7/6/2017 10:11:12 AM Page 4

• • • • • I N T E R F E R E N C E C O R R E C T E D R E P O R T *****

Nuclide Wt mean Wt mean Nuclide Id Activity Activity Name Confidence (pCi/gram) Uncertainty K-40 0.965 6.678221E+000 1.266215E+000 Pb-212 0.998 2.153317E-001 3.921464E-002 BI-214 0.443 2.839109E-001 8.459858E-002 PB-214 0.849 1.830681E-001 4.698489E-002 Ra-226 0.971 7.908343E+000 2.164884E+000 U-234 0.994 3.268192E+001 3.354938E+001 U-235 0.999 3.255685E-001 1.089566E-001

? = nuclide is part of an undetermined solution X = nuclide rejected by the interference analysis

@ = nuclide contains energy lines not used in Weighted Mean Activity Errors quoted at 1.960 sigma

• • • • • • • • • • U N I D E N T I F I E D P E A K S **********

Peak Locate Performed on: 7/6/2017 10:11:08 AM Peak Locate From Channel: 40 Peak Locate To Channel: 8192 Peak Energy Peak Size in Peak CPS Peak Tol.

No. (keV) Counts per Second % Uncertainty Type Nuclide All peaks were identified.

Nuclide MDA Report 7/6/2017 10:11:12 AM Page 5

• • • • • N U C L I D E M D A R E P O R T *****

Detector Name: 8566 Sample Geometry: cylinder Sample

Title:

UNC-GFLU-2123-S-P-2 Nuclide Library Used: C:\\GENIE2K\\CAMFILES\\UNC 2017 NLB 0328201 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ K-40 1460.82* 10.66 9.339E-001 9.34E-001 6.678E+000 4.027E-00 Pb-210 46.54 4.25 1.602E+000 1.60E+000 7.341E-001 7.598E-00 BI-212 727.33 6.67 1.449E+000 1.45E+000 -1.438E+000 6.691E-00 785.37 1.10 9.336E+000 1.145E+000 4.307E+00 1078.62 0.56 2.372E+001 -2.164E-001 1.092E+00 1620.50 1.47 6.295E+000 -6.232E-001 2.636E+00

+ Pb-212 74.82* 10.28 2.902E-001 7.62E-002 7.774E-001 1.366E-00 77.11* 17.10 1.956E-001 2.844E-001 9.279E-00 86.83 2.07 2.213E+000 -7.108E-001 1.068E+00 87.35* 3.97 8.048E-001 4.429E-001 3.823E-00 89.78 1.46 2.809E+000 6.809E-001 1.350E+00 115.18 0.60 5.330E+000 -3.330E+000 2.536E+00 238.63* 43.60 7.623E-002 1.903E-001 3.537E-00 300.09 3.30 1.699E+000 -5.774E-001 8.040E-00

+ BI-214 76.86* 0.55 6.137E+000 1.37E-001 8.923E+000 2.911E+00 79.29 0.91 5.201E+000 2.103E+000 2.508E+00 609.32* 45.49 1.373E-001 2.712E-001 6.178E-00 665.45 1.53 6.613E+000 4.615E+000 3.084E+00 768.36 4.89 2.371E+000 6.106E-001 1.106E+00 806.18 1.26 9.318E+000 7.602E+000 4.336E+00 934.06 3.11 3.947E+000 -9.353E-001 1.823E+00 1120.29 14.92 1.080E+000 4.934E-001 5.032E-00 1155.21 1.63 8.947E+000 -4.010E+000 4.130E+00 1238.11 5.83 2.682E+000 1.097E+000 1.239E+00 1280.98 1.43 9.286E+000 2.682E+000 4.216E+00 1377.67 3.99 3.300E+000 -2.147E-001 1.486E+00 1385.31 0.79 1.845E+001 1.000E+001 8.398E+00 1401.52 1.33 9.370E+000 3.348E+000 4.188E+00 1407.99 2.39 5.510E+000 2.482E+000 2.478E+00 1509.21 2.13 6.240E+000 3.997E+000 2.789E+00 1583.20 0.70 1.892E+001 -7.371E+000 8.417E+00 1661.27 1.05 1.156E+001 -1.220E+000 5.047E+00 1729.59 2.88 4.482E+000 1.239E+000 1.964E+00 1764.49* 15.30 4.527E-001 5.320E-001 1.732E-00 1847.43 2.03 6.417E+000 3.452E+000 2.790E+00

> 2118.51 1.16 0.000E+000 0.000E+000 0.000E+00

> 2204.06 4.92 0.000E+000 0.000E+000 0.000E+00

> 2447.70 1.55 0.000E+000 0.000E+000 0.000E+00

+ PB-214 74.82* 5.80 5.143E-001 1.06E-001 1.378E+000 2.421E-00 77.11* 9.70 3.448E-001 5.014E-001 1.636E-00 86.83 1.70 2.694E+000 -8.655E-001 1.300E+00 87.35* 2.24 1.426E+000 7.850E-001 6.776E-00

Nuclide MDA Report 7/6/2017 10:11:12 AM Page 6 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ PB-214 89.78 0.82 5.001E+000 1.06E-001 1.212E+000 2.404E+00 241.99 7.25 8.841E-001 -8.277E-001 4.253E-00 258.76 0.53 8.558E+000 1.673E+000 4.035E+00 295.22* 18.42 1.641E-001 1.635E-001 7.405E-00 351.93* 35.60 1.061E-001 1.688E-001 4.806E-00 785.96 1.06 9.619E+000 -9.928E-002 4.433E+00 839.07 0.58 1.911E+001 -4.446E+000 8.827E+00

+ Ra-226 81.07 0.20 1.990E+001 1.03E+000 -7.984E+000 9.524E+00 83.79 0.32 1.420E+001 7.462E+000 6.848E+00 186.21* 3.64 1.028E+000 7.908E+000 4.875E-00 AC-228 89.96 1.90 7.637E+004 1.87E+004 -1.362E+003 3.680E+00 93.35 3.10 4.339E+004 -6.496E+004 2.086E+00 99.51 1.26 8.251E+004 -3.154E+004 3.922E+00 105.60 0.74 1.485E+005 -2.630E+004 7.080E+00 129.07 2.42 4.740E+004 3.258E+004 2.262E+00 153.98 0.72 1.666E+005 1.013E+005 7.936E+00 209.25 3.89 3.501E+004 -6.710E+002 1.659E+00 214.85 0.76 1.810E+005 1.063E+005 8.573E+00 270.24 3.46 4.753E+004 -1.511E+004 2.247E+00 328.00 2.95 5.804E+004 -1.504E+004 2.717E+00 338.32 11.27 1.870E+004 4.250E+003 8.852E+00 409.46 1.92 1.155E+005 1.804E+004 5.415E+00 463.00 4.40 5.555E+004 -1.767E+004 2.600E+00 562.50 0.87 3.563E+005 1.159E+005 1.672E+00 674.75 2.10 1.409E+005 -2.305E+004 6.501E+00 726.86 0.62 5.412E+005 -2.934E+004 2.508E+00 755.32 1.00 3.449E+005 -4.984E+004 1.597E+00 772.29 1.49 2.542E+005 9.459E+004 1.183E+00 794.95 4.25 8.128E+004 1.844E+004 3.749E+00 830.49 0.54 6.971E+005 -1.701E+005 3.228E+00 835.71 1.61 2.432E+005 1.322E+005 1.129E+00 840.38 0.91 4.218E+005 2.009E+005 1.954E+00 904.20 0.77 5.926E+005 -3.916E+004 2.768E+00 911.20 25.80 1.910E+004 1.211E+004 8.965E+00 964.77 4.99 9.618E+004 4.878E+004 4.490E+00 968.97 15.80 2.963E+004 -3.504E+003 1.380E+00 1247.08 0.50 9.216E+005 -1.560E+005 4.211E+00 1459.14 0.83 1.272E+006 3.004E+006 6.087E+00 1495.91 0.86 4.017E+005 -2.407E+005 1.738E+00 1588.20 3.22 1.537E+005 6.873E+004 6.922E+00 1630.63 1.51 2.311E+005 -7.060E+004 9.895E+00 TH-230 67.67 0.38 1.110E+001 1.11E+001 -1.341E+000 5.297E+00 PA-234 742.81 0.11 1.032E+002 1.43E+001 -2.847E+001 4.804E+00 766.42 0.32 3.599E+001 1.090E+001 1.677E+00 1001.03 0.84 1.428E+001 -8.069E+000 6.554E+00 TH-234 63.29 3.70 1.330E+000 1.33E+000 4.566E-001 6.368E-00 92.38 2.13 2.130E+000 3.277E+000 1.028E+00 92.80 2.10 2.069E+000 -2.755E-001 9.971E-00 112.81 0.21 1.579E+001 -1.759E+000 7.530E+00

+ U-234 53.20* 0.12 3.585E+001 3.59E+001 3.268E+001 1.684E+00 120.90 0.04 8.914E+001 3.693E+000 4.235E+00

Nuclide MDA Report 7/6/2017 10:11:12 AM Page 7 Nuclide Energy Yield Line MDA Nuclide MDA Activity Dec. Leve Name (keV) (%) (pCi/gram) (pCi/gram) (pCi/gram) (pCi/gram

+ U-235 89.96 3.43 1.274E+000 2.21E-001 -2.272E-002 6.140E-00 93.35 5.54 7.312E-001 -1.095E+000 3.515E-00 104.82 0.69 4.816E+000 1.919E+000 2.296E+00 105.60 1.31 2.526E+000 -4.474E-001 1.204E+00 108.58 0.50 6.728E+000 -6.258E+000 3.210E+00 109.19 1.66 1.980E+000 -2.910E+000 9.440E-00 143.76* 10.96 2.210E-001 3.169E-001 1.030E-00 163.36 5.08 7.828E-001 2.783E-001 3.740E-00 194.94 0.63 6.167E+000 -3.223E+000 2.924E+00 202.12 1.08 4.234E+000 1.962E+000 2.021E+00 205.32* 5.02 5.229E-001 5.492E-001 2.406E-00

+ = Nuclide identified during the nuclide identification

• = Energy line found in the spectrum

> = MDA value not calculated

@ = Half-life too short to be able to perform the decay correction

7/6/2017 10:11:12 LACE Lace v3.2.1 Page 1

• • • • L I N E A C T I V I T Y C O N S I S T E N C Y E V A L U A T O R ***

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Analysis using Key Line Activities

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Filename: C:\\GENIE2K\\CAMFILES\\UNC 2017\\IMC Samples\\IMC-2123\\UNC-GFLU-21 Equation used to calculate plot: ln(Ratio) = A + B*ln(Energy) where: Ratio = Activity/KL Activity Notes:

'^' Denotes Key Line energy

• All uncertainties quoted at 1.96 sigma Nuclide Energy Activity Activity Ratio[%Uncert] A B (keV) (pCi/gram) %Uncert* [uncert]

K-40 1460.8 ^ 6.68E+000 18.960 Pb-212 74.8 7.77E-001 23.333 4.086[33.806] 4.66 -0.853 77.1 2.84E-001 28.727 1.495[37.731] [ 0.367]

87.3 4.43E-001 40.763 2.328[47.540]

238.6 ^ 1.90E-001 24.463 1.000[34.595]

BI-214 76.9 8.92E+000 28.867 32.908[43.178] 8.66 -1.240 609.3 ^ 2.71E-001 32.110 1.000[45.410] [ 0.236]

1764.5 5.32E-001 67.981 1.962[75.182]

PB-214 74.8 1.38E+000 24.990 8.164[44.392] 6.54 -1.132 77.1 5.01E-001 30.105 2.971[47.460] [ 0.340]

87.3 7.85E-001 41.647 4.651[55.503]

295.2 1.63E-001 50.840 0.969[62.696]

351.9 ^ 1.69E-001 36.690 1.000[51.887]

Ra-226 186.2 ^ 7.91E+000 27.375 U-234 53.2 ^ 3.27E+001 102.65 U-235 143.8 ^ 3.17E-001 35.048 1.000[49.565] -7.67 1.543 205.3 5.49E-001 102.51 1.733[108.34] [ 3.343]