ML14139A025
| ML14139A025 | |
| Person / Time | |
|---|---|
| Site: | Monticello  |
| Issue date: | 05/15/2014 |
| From: | Northern States Power Co, Xcel Energy |
| To: | Office of Nuclear Reactor Regulation |
| References | |
| Download: ML14139A025 (101) | |
Text
ENCLOSUREI RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM JANUARY 1 - DECEMBER 31, 2013 100 pages follow
" h-l- Environmental, Inc.
p1$i-o1I Midwest Laboratory 700 Landwehr Road
- Northbrook. IL 60062-2310 phone (847) 564-0700
- fax (847) 564-4517 XCEL ENERGY CORPORATION MONTICELLO NUCLEAR GENERATING PLANT DOCKET NO. 50-263 LICENSE NO. DPR-22 ANNUAL REPORT TO THE UNITED STATES NUCLEAR REGULATORY COMMISSION Radiological Environmental Monitoring Program January 1 to December 31, 2013 Prepared under Contract by ENVIRONMENTAL, Inc.
Midwest Laboratory.
Project No. 8010 Approved: S-13-20 (
Laboratory Manager Bo Grob, MaSg
PREFACE The staff of Environmental, Inc., Midwest Laboratory was responsible for the acquisition of data presented in this report. Samples were collected by personnel of the Monticello Nuclear Generating Plant, operated by Northern States Power Co. -Minnesota for XCEL Energy Corporation. This report was prepared by Environmental, Inc., Midwest Laboratory.
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TABLE OF CONTENTS No. Paqe P refa c e ................................................................................................................................ ii List of T a ble s ....................................................................................................................... iv List of Figures ............................................................................................................ v
1.0 INTRODUCTION
........................................................................................................... 1 2 .0 S UMMARY.......................................................................................................................... 2 3.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP) .................. 3 3.1 Program Design and Data Interpretation ........................................................ 3 3.2 Program Description ....................................................................................... 4 3.3 Program Execution ............................................................................................ 5 3.4 Program Modifications ..................................................................................... 5 3.5 Laboratory Procedures ..................................................................................... 6 3.6 Land Use Census ............................................................................................ 6 4.0 RESULTS AND DISCUSSION ..................................................................................... 7 4.1 Atmospheric Nuclear Detonations and Nuclear Accidents .......... .................. 7 4.2 Sum mary of Preoperational Data .................................................................... 7 4.3 Program Findings .......................................... 8 5.0 FIGURES AND TABLES .............................................................................................. 12
6.0 REFERENCES
.................................................................................................................. 24 APPENDICES A Interlaboratory Comparison Program Results ............................................................... A-1 B Data Reporting Conventions ....................................................................................... B-1 C Maximum Permissible Concentrations of Radioactivity in Air and Water Above Natural Background in Unrestricted Area ....................................................... C-1 D Sampling Location Maps .............................................................................................. D-1 E Ground W ater Monitoring W ell Samples .................................................................... E-1 iii
LIST OF TABLES No. Title Page 5.1 Sample Collection and Analysis Program ................................................................. 13 5.2 Sampling Locations .................................................................................................. 14 5.3 Missed Collections and Analyses ............................................................................. 17 5.4 Radiation Environmental Monitoring Program Summary ........................................... 20 The following tables are in the Appendices:
Appendix A A-1 Interlaboratory Comparison Program Results ......................................................... Al-1 A-2 Thermoluminescent dosimeters (TLDs) ......................................................................... A2-1 A -3 In-house S piked Sam ples .............................................................................................. A 3-1 A -4 In-house "Blank" Sam ples .............................................................................................. A 4-1.
A-5 In-house "Duplicate" Samples ................................................................................... A5-1 A-6 Department of Energy MAPEP comparison results ....................................................... A6-1 A-7 Environmental Resources Associates, Crosscheck Program Results (EM L study replacem ent) ................................................................................... A 7-1 Attachment A: Acceptance criteria for spiked samples ............................................... A2 Appendix C C-1 Maximum Permissible Concentrations of Radioactivity in air and water above background in unrestricted areas ..................................................................... C-2 Appendix E E-1 Sample Collection and Analysis Program, Ground Water .............................................. E-6 E-2 Sampling Locations for Ground Water Monitoring Wells ................................................ E-6 E-3 Ground Water Monitoring Program Summary ................................................................ E-7 E-4 Results of Analyses, Ground Water Monitoring Program ............................................... E-9 iv
LIST OF FIGURES No. Title Page 5-1 Offsite Ambient Radiation (TLDs), inner versus outer ring locations ..................................... 18 5-2 Airborne Particulates; analysis for gross beta, average mean of all indicator locations versus control location ........................................................................................ 19 The following figures are located in the Appendices:
Appendix D D-1 Sample collection and analysis program: TLD locations, In ne r R ing ................................................................................................................................ D-2 D-2 Sample collection and analysis program: TLD locations, O ute r R ing .............................................................................................................................. D-3 D-3 Sample collection and analysis program: TLD locations, C o n tro ls .................................................................................................................................... D -4 D-4 Sample collection and analysis program: Radiation Environmental Monitoring Program, Milk sa m p ling lo catio ns ........................................................................................ ................... D -5 D-5 Sample collection and analysis program: Radiation Environmental Monitoring Program, Sludge, Ground water and Shoreline sampling locations ........................................................ D-6 Appendix E E-1 Sample collection and analysis program:
Ground water, On-site monitoring well locations ..................................................................... E-8 V
1.0 INTRODUCTION
This report summarizes and interprets results of the Radiological Environmental Monitoring Program (REMP) conducted by Environmental, Inc., Midwest Laboratory for the Monticello Nuclear Generating Plant, Monticello, Minnesota, during the period January - December, 2013.
This Program monitors the levels of radioactivity in the air, terrestrial, and aquatic ehvironments in order to assess the impact of the Plant on its surroundings.
Tabulations of the individual analyses made during the year are not included in this report. These data are included in a reference document (Environmental, Inc., Midwest Laboratory, 2014a) available at the Monticello Nuclear Generating Plant, Chemistry and Radiation Protection Department.
The Monticello Nuclear Generating Plant is a boiling water reactor with a nominal generating capacity of 600 MWe. It is located on the Mississippi River in Wright County, Minnesota, owned by Xcel Energy Corporation and operated by Northern States Power Co.-Minnesota. Initial criticality was achieved on December 10, 1970. Full power was achieved March 5, 1971 and commercial operation began on June 30, 1971.
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2.0
SUMMARY
The Radiological Environmental Monitoring Program (REMP) required by the U.S. Nuclear Regulatory Commission (NRC) Technical Specifications and the Offsite Dose Calculation Manual (ODCM) for the Monticello Nuclear Generating Plant is described. Results for the year 2013 are summarized and discussed.
Program findings show background levels of radioactivity in the environmental samples collected in the vicinity of the Monticello Nuclear Generating Plant.
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3.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP) 3.1 Program Design and Data Interpretation The purpose of the Radiological Environmental Monitoring Program (REMP) at the Monticello Nuclear Generating Plant is to assess the impact of the Plant on its environment. For this purpose, samples are collected from the air, terrestrial, and aquatic environments and analyzed for radioactive content. In addition, ambient gamma radiation levels are monitored by thermoluminescent dosimeters (TLD's).
Sources of environmental radiation include the following:
(1) Natural background radiation arising from cosmic rays and primordial radionuclides; (2) Fallout from atmospheric nuclear detonations; (3) Releases from nuclear power plants; (4) Industrial and medical radioactive waste; and (5) Fallout from nuclear accidents.
In interpreting the data, effects due to the Plant must be distinguished from those due to other sources.
A major interpretive aid in assessment of these effects is the design of the monitoring program at the Monticello Plant which is based on the indicator-control concept. Most types of samples are collected both at indicator locations (nearby, downwind, or downstream) and at control locations (distant, upwind, or upstream). A plant effect would be indicated if the radiation level at an indicator location was significantly larger than that at the control location. The difference would have to be greater than could be accounted for by typical fluctuations in radiation levels arising from other sources.
An additional interpretive technique involves analyses for specific radionuclides present in environmental samples collected from the Plant site. The Plant's monitoring program includes analyses for tritium and iodine-131. Most samples are also analyzed for gamma-emitting isotopes with results for the following groups quantified: zirconium-95, cesium-137, cerium-144, beryllium-7, and potassium-40. The first three gamma-emitting isotopes were selected as radiological impact indicators because of the different characteristic proportions in which they appear in the fission product mix produced by a nuclear reactor and that produced by a nuclear detonation.
Each of the three isotopes is produced in roughly equivalent amounts by a reactor: each constitutes about 10% of the total activity of fission products 10 days after reactor shutdown. On the other hand, 10 days after a nuclear explosion, the contributions of zirconium-95, cerium-144, and cesium-137 to the activity of the resulting debris are in the approximate ratio 4:1:0.03 (Eisenbud, 1963). Beryllium-7 is of cosmogenic origin and potassium-40 is a naturally-occurring isotope. They were chosen as calibration monitors and should not be considered as radiological impact indicators. The other group quantified consists of niobium-95, ruthenium-103 and -106, cesium-134, barium-lanthanum-140, and cerium-141. These isotopes are released in small quantities by nuclear power plants, but to date their major source of injection into the general environment has been atmospheric nuclear testing. Nuclides of the final group, manganese-54, iron-59, cobalt-58 and -60, and zinc-65, are activation products and arise from activation of corrosion products. They are typical components of a nuclear power plant's effluents, but are not produced in significant quantities by nuclear detonations.
Other means of distinguishing sources of environmental radiation are employed in interpreting the data. Current radiation levels are compared with previous levels, including those measured before the plant became operational. Results of the Plant's Monitoring Program can be related to those obtained in other parts of the world. Finally, results can be related to events known to cause elevated levels of radiation in the environment, e.g., atmospheric nuclear detonations.
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3.2 Pro-gram Description The sampling and analysis schedule for the Radiological Environmental Monitoring Program (REMP) at the Monticello Plant is summarized in Table 5.1 and briefly reviewed below. Table 5.2 defines the sampling location codes used in Table 5.1 and specifies for each location its type (indicator or control) and its distance, direction, and sector relative to the plant site. To assure that sampling is carried out in a reproducible manner, detailed sampling procedures have been prescribed (Monticello Generating Plant REMP Surveillances, Current Revision). Maps of sampling locations are included in Appendix D.
To monitor the air environment, airborne particulates are collected on membrane filters by continuous pumping at five locations. Also, airborne iodine is collected by continuous pumping through charcoal filters at all of these locations. Filters are changed and counted weekly.
Particulate filters are analyzed for gross beta activity and charcoal filters for iodine-131. Quarterly composites of particulate filters from each location are determined by gamma spectroscopy. One of the five locations is a control (M-1), and four are indicators (M-2, M-3, M-4, M-5). One of the indicators is located in the geographical sector expected to be most susceptible to any atmospheric emissions from the Plant (highest D/Q sector).
Ambient gamma radiation is monitored at forty locations, using CaSO4 :Dy dosimeters with four sensitive areas at each location: fourteen in an inner ring in the general area of the site boundary, sixteen in the outer ring within 4-5 mile radius, six at special interest locations and four control locations, outside a 10 mile radius from the plant. They are replaced and measured quarterly.
As substitute for dairy sampling, pasture grass and vegetation are collected from locations M-41, M-42 and M-43 (C). The samples are analyzed for iodine-1 31 and other gamma emitting isotopes.
Vegetables, corn and potatoes are collected annually if fields are irrigated by water in which liquid radioactive effluent has been discharged. Analysis is done for gamma-emitting isotopes.
Ground water is monitored by quarterly collections from three off-site locations (one control and two indicators) and one on-site Plant well. To prevent possible groundwater contamination due to plant operations, samples from nineteen on-site monitoring wells are collected and analyzed for tritium and gamma emitting isotopes. The Ground Water Monitoring Program is further described in Appendix E.
Quarterly collections of storm water runoff were added to monitor another possible pathway to the groundwater aquifer. The samples are also analyzed for tritium and gamma emitting isotopes.
River water is collected weekly at two locations, one upstream of the plant and one downstream.
Monthly composites are analyzed for gamma-emitting isotopes. Quarterly composites are analyzed for tritium.
Drinking water is collected weekly from the City of Minneapolis water supply, which is taken from the Mississippi River downstream of the Plant. Monthly composites are analyzed for gross beta, iodine-1 31, and gamma-emitting isotopes. Quarterly composites are analyzed for tritium.
The aquatic environment is also monitored by semi-annual upstream and downstream collections of fish, invertebrates, and shoreline sediments. Shoreline sediment is also collected from one downstream recreational location. All samples are analyzed for gamma-emitting isotopes.
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3.3 Pro-gram Execution The Program was executed as described in the preceding section with the following exceptions:
(1) Air Particulates / Air Iodine:
M-01, No air particulate / air iodine sample was available for the week ending January 16, 2013, the sampler failed due to a faulty toggle switch.
M-01, A partial air particulate / air iodine sample (54 M 3) was collected for the week ending May 1, 2013, due to sampler failure. No air particulate / air iodine sample was available for the week ending May 8, 2013, due to sampler failure. The vacuum pump was replaced.
M-02, No air particulate sample was collected for the week ending November 27, 2013, the filter was misaligned in the holder.
(2) Surface Water:
Surface water was not collected at location M-08 for the months of January, February, March and December, 2013, due to unsafe ice conditions.
(3) Well Water:
Well water was not collected at location MW-27 in January, 2013. No water was available from the outside tap.
(4) Drinking Water (M-14):
No sample was available for the January 13, 2013 collection. The sample was damaged in shipment. The drinking water sample for May 7, 2013 was lost during shipping.
No drinking water sample was available November 18, 2013. The sample was missed.
(5) Milk There was no goat milk available from locations M-16 and M-17 in 2013. Goats are no longer milked at location M-16, the herd has been sold.
Deviations from the program are summarized in Table 5.3.
3.4 Program Modifications Milk sampling was dropped from the REMP in 2013. The indicator location M-16 discontinued dairy operations.
Modifications to the Groundwater monitoring program are detailed in Appendix E.
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3.5 Laboratory Procedures The iodine-131 analyses in milk and drinking water were made using a sensitive radiochemical procedure which involves separation of the iodine using an ion-exchange method and solvent extraction and subsequent beta counting.
Gamma-spectroscopic analyses are performed using high-purity germanium (HPGe) detectors.
Levels of iodine-131 in cabbage and natural vegetation and concentrations of airborne iodine-1 31 in charcoal samples were determined by gamma spectroscopy.
Tritium concentrations are determined by liquid scintillation.
Analytical Procedures used by Environmental, Inc. are on file and are available for inspection.
Procedures are based on those prescribed by the Health and Safety Laboratory of the U.S. Dep't of Energy, Edition 28, 1997, U.S. Environmental Protection Agency for Measurement of Radioactivity in Drinking Water, 1980, and the U.S. Environmental Protection Agency, EERF, Radiochemical Procedures Manual, 1984.
Environmental, Inc., Midwest Laboratory has a comprehensive quality control/quality assurance program designed to assure the reliability of data obtained. Details of the QA Program are presented elsewhere (Environmental, Inc., Midwest Laboratory, 2012). The QA Program includes participation in Interlaboratory Comparison (crosscheck) Programs. Results obtained in the crosscheck programs are presented in Appendix A.
3.6 Land Use Census In accordance with the MNGP Chemistry Manual, Procedure 1.05.41, "Annual Land Use Census and Critical Receptor Identification", a land use census shall be conducted and shall identify the location of the nearest milk animal, the nearest residence, and the nearest garden of greater than 500 ft 2 producing fresh leafy vegetables, in each of the 16 meteorological sectors within a distance of 5 miles. The census shall also identify the locations of all milk animals and all 500 ft 2 or greater gardens producing broad leaf vegetation in each of the meteorological sectors within a distance of three miles. This census shall be conducted at least once per year between the dates of May 1 and October 31. New locations shall be added to the radiation environmental monitoring program within 30 days and sampling locations having lower calculated doses or a lower dose commitment may be deleted from this monitoring program after October 31 of the year in which the land use census was conducted.
The 2013 land use census was conducted between September 10 and September 16, 2013.
Closer gardens were identified in the E and S sectors, resulting in revised D/Q values greater than 20%. Improved GPS software resulted in slight changes to sector assignments. The highest D/Q value for nearest garden was calculated in the SE sector. The highest D/Q location for nearest resident did not change from the 2012 census. There were no milk animals found within a five mile radius of the plant. The goat milk farm in the SSE sector has sold off the herd.
A new site for critical receptor was identified in the 2013 census, located in the SE sector, 1.1 miles from the plant. The Offsite Dose Calculation Manual (ODCM) will be revised to reflect the changes.
Details of the land use census are contained in the Land Use Census and Critical Receptor Report, Monticello Nuclear Generating Plant, Chemistry and Radiation Protection Department.
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4.0 RESULTS AND DISCUSSION All of the scheduled collections and analyses were made except those listed in Table 5.3.
All results are summarized in Table 5.4 in a format recommended by the Nuclear Regulatory Commission in Regulatory Guide 4.8. For each type of analysis of each sampled medium, this table lists the mean and range for all indicator locations and for all control locations. The locations with. the highest mean and range are also shown.
4.1 Atmospheric Nuclear Detonations and Nuclear Accidents There were no reported accidents involving significant release to the environment at nuclear reactor facilities in 2013. The Fukushima Daiichi nuclear accident occurred March 11, 2011.
There were no reported atmospheric nuclear tests in 2013. The last reported test was conducted on October 16, 1980 by the People's Republic of China.
4.2 Summary of Preoperational Data The following constitutes a summary of preoperational studies conducted at the Monticello Nuclear Generating Plant during the years 1968 to 1970, to determine background levels expected in the environment, and provided, where applicable, as a means for comparison with present day levels. Strict comparisons, however, are difficult to make, since background levels of radiation were much higher in these years due to radioactive fallout from the atmosphere. Gross beta measurements in fallout averaged 20,600 pCi/m 3 in 1969 and 12,000 pCi/m 3 in 1970. These levels are reflected throughout the various media tested.
In the air environment, ambient gamma radiation (TLDs) averaged 9.1 mRem/4 weeks during preoperational studies (1970). Gross beta in air particulates in 1969 and 1970 averaged 0.20 pCi/m 3. Present day levels have stabilized at around 0.025 pCi/m 3. Airborne radioiodine remained below detection levels.m 3 In the terrestrial environment of 1968 to 1970, milk, agricultural crops, and soil were monitored. In milk samples, low levels of Cs-1 37 and Sr-90 were detected. Cs-137 levels averaged 16.7 pCi/L.
Soybean crop measurements in 1969 averaged 35.5 pCi/g for gross beta and 0.3 pCi/g for Cs-137. Gross beta measured in soil averaged 51.7 pCi/g . Present day measurements for cesium-137 are below detection levels in milk and agricultural crops.
The aqueous environment was monitored by testing of river water, bottom sediments, fish, aquatic vegetation, and periphyton. Specific location comparison of drinking, river, and well water concentrations for tritium and gross beta are not possible. However, tritium background levels, measured at seven separate locations from 1968 to 1970, averaged 970 pCi/L. Present day environmental samples measure below detection levels. Values for gross beta, measured from 1968 to 1970, averaged 9.8 pCi/L in upstream and downstream Mississippi River water, 4.4 pCi/L for well waters, and 18.6 pCi/L for lake waters. Gamma emitters were below the lower limit of detection (LLD). In shoreline sediments, gross beta background levels in 1970 averaged 49.8 pCi/g for both upstream and downstream samples. Cs-137 activity averaged 0.10 pCi/g for both upstream and downstream samples. Low levels of Cs-137, occasionally observed today can still be attributed to residual activity from atmospheric fallout. Gross beta levels in fish flesh averaged 5.3 pCi/g in 1968 and 1969. Cs-137, measured in 1969 and 1970, averaged 0.044 pCi/g. Gross beta background levels, in 1970, for aquatic vegetation, algae, and periphyton samples measured 86.7 pCi/g, 76.5 pCi/g, and 28.1 pCi/g respectively.
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4.3 Program Findings Results obtained show background levels of radioactivity in environmental samples collected outside of the Site Protected Area in 2013. The trace levels of strontium-90 and cesium-137, still measurable in soil and sediment samples, are generally attributed to deposition of fallout from previous decades.
Tritium was identified in some groundwater samples collected within the site Protected Area.
Ambient Radiation (TLD's)
Ambient radiation was measured in the general area of the site boundary, at an outer ring 4 - 5 mi.
distant from the Plant, at special interest areas and at four control locations. The means were similar for both inner and outer rings (14.4 and 14.0 mRem/91 days, respectively). The mean for special interest locations was 14.0 mRem/91 days and the mean for the control locations was 15.5 mRem/91 days. Dose rates measured at the inner and outer ring locations were similar to those observed from 1998 through 2012 and are tabulated below. No plant effect on ambient gamma radiation is indicated (Figure 5-1).
Year Inner Ring Outer Ring Dose rate Rem/91 days) 1998 15.0 14.4 1999 15.1 14.3 2000 15.1 14.5 2001 14.3 13.7 2002 15.9 14.8 2003 15.6 15.0 2004 16.0 15.4 2005 15.6 15.2 2006 16.5 15.6 2007 16.1 15.1 2008 15.2 14.6 2009 14.9 14.4 2010 14.7 14.3 2011 14.8 14.3 2012 16.2 15.5 2013 14.4 14.0 Ambient gamma radiation as measured by thermoluminescent dosimetry.
Average quarterly dose rates, Inner vs. Outer Ring locations 8
Airborne Particulates The average annual gross beta concentrations in airborne particulates were almost identical at both indicator and control locations (0.029 and 0.032 pCi/m 3,respectively), similar to levels observed from 1998 through 2012. The results are tabulated below.
Year Indicators Control Concentration pCi/m 3) 1998 0.023 0.023 1999 0.023 0.025 2000 0.027 0.026 2001 0.027 0.026 2002 0.028 0.028 2003 0.027 0.027 2004 0.024 0.024 2005 0.025 0.025 2006 0.024 0.025 2007 0.027 0.028 2008 0.028 0.029 2009 0.029 0.030 2010 0.026 0.026 2011 0.029 0.027 2012 0.032 0.031 2013 0.029 0.032 Average annual gross beta concentrations in airborne particulates.
Typically, the highest average readings occur during the months of January and December, and the first and fourth quarters, as observed in 1998 through 2013.
Gamma spectroscopic analysis of quarterly composites of air particulate filters yielded similar results for indicator and control locations. Beryllium-7, which is produced continuously in the upper atmosphere by cosmic radiation (Arnold and AI-Salih, 1955) was detected in all samples, with an average activity of 0.065 pCi/im3 for all locations. All other gamma-emitting isotopes were below their respective LLD limits.
Airborne Iodine 3
Weekly levels of airborne iodine-131 were below the lower limit of detection (LLD) of 0.03 pCi/m in all samples.
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River Water and Drinking Water Tritium activity measured below 500 pCi/L in all samples. Gross beta activity in Minneapolis drinking water averaged 2.6 pCi/L and was similar to average levels observed from 1998 through 2012. Gross beta averages are tabulated below.
Year Gross Beta (pCi/L) Year Gross Beta (pCi/L) 1998 2.4 2006 2.1 1999 2.2 2007 2.8 2000 2.5 2008 2.1 2001 2.5 2009 2.3 2002 2.9 2010 2.9 2003 3.0 2011 2.2 2004 2.7 2012 2.4 2005 2.8 2013 2.6 Average annual concentrations; Gross beta in drinking water.
Comparisons with data reported by the USEPA for Minneapolis drinking water samples collected from 1980 through 2005 indicate that concentrations of these nuclides are remaining fairly constant. Gamma-emitting isotopes were below detection limits in all surface water samples.
There was no indication of a plant effect.
Well Water At the four indicator and control locations, tritium measured below 500 pCi/L for all samples.
Gamma isotopic results were below detection limits.
The data for 2013 were consistent with previous years results and no plant operational effects were indicated.
Pasture Grass Pasture grass was collected in July, August and September, 2013. Iodine-131 concentrations measured below 0.034 pCi/g wet weight in all samples. With the exceptions of naturally-occurring beryllium-7 and potassium-40, no other gamma-emitting isotopes were detected.
Crops A vegetation collection was not required for 2013. No crops, within five miles of the plant, were found using irrigation water from the Mississippi River.
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Fish Fish were collected in May and September. Flesh was separated from the bones and analyzed by gamma spectroscopy. Only naturally-occurring potassium-40 was found in the upstream and downstream samples (3.27 and 3.19 pCi/g wet weight, respectively). Other gamma-emitting isotopes remained below detection limits. There was no indication of a plant effect.
Invertebrates Samples were collected in August and October, 2013, and analyzed by gamma spectroscopy. All gamma-emitting isotopes, with the exception of naturally-occurring potassium-40 were below detection limits. There was no indication of any plant effect.
Shoreline Sediments Upstream, downstream and downstream recreational area shoreline sediment collections were made in August and October, 2013, and analyzed for gamma-emitting isotopes. Low levels of cesium-137 were detected in two downstream samples (M-15), at an average concentration of 0.0035 pCi/g dry weight. Similar levels of activity and distribution have been observed since 1978, and are indicative of the influence of fallout deposition. Naturally-occurring beryllium-7 and potassium-40 were also detected. There was no indication of a plant effect.
Ground Water Monitoring Program Monitoring Wells (on-site)
Measurable tritium above 500 pCi/L was detected in 11 of 114 samples collected from the nineteen on-site monitoring wells. The activities ranged from 566 to 15,124 pCi/L, similar or slightly higher than concentrations seen in 2011 and 2012. The highest activities were observed at well MW-09A.
Gamma isotopic measurements were below detection limits.
Stormwater Run-off (on-site)
No tritium was detected in any of the four stormwater runoff samples submitted for analysis in 2013. Gamma isotopic analysis results measured below detection limits.
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5.0 FIGURES AND TABLES 12
Table 5.1. Sample collection and analysis program, Monticello Nuclear Generating Plant.
Collection Analysis Location Type and Type and Medium No. Codes (and Type) a Frequency b Frequency c Ambient radiation 40 M-01A- M-14A, M-01B - M-16B C/Q Ambient gamma (TLDs) M-01S - M-06S, M-01C - M-04C Airborne Particulates 5 M-1(C), M-2, M-3, M-4, M-5 CNV GB, GS (QC of each location)
Airborne Iodine 5 M-I(C), M-2, M-3, M-4, M-5 CAN 1-131 Pasture grass, Vegetation d 3 M-41, M-42, M-43(C) 3x/year GS Surface water 2 M-8(C), M-9 GNV GS(MC), H-3(QC)
Drinking water 1 M-14 GAN GB(MC), 1-131 (MC)
Well water 4 M-11, M-12, M-27, M-43(C) G/Q H-3, GS On-site monitoring wells 5 M-36 to M-40 G/Q H-3, GS 19 M-33 to M-35, M-44 to M-54 G/M H-3, GS Edible cultivated crops e.
Leafy Vegetable 2 M-27, Available Producer (C) G/A 1-131 Corn 1 M-1 9 G/A GS Potatoes 1 M-21 G/A GS Fish 2 M-8(C), M-9 G/SA GS (one species, edible portion)
Periphyton or invertebrates 2 M-8(C), M-9 G/SA GS Shoreline sediment 3 M-8(C), M-9, M-15 G/SA GS a Location codes are defined in Table 5.2. Control stations are indicated by (C). All other stations are indicators.
b Collection type is coded as follows: C/ = continuous, G/ = grab. Collection frequency is coded as follows:
W- weekly, M = monthly, Q = quarterly, SA = semiannually, A = annually.
C Analysis type is coded as follows: GB = gross beta, GS = gamma spectroscopy, H-3 = tritium, 1-131 = iodine-131.
Analysis frequency is coded as follows: MC = monthly composite, QC = quarterly composite.
d Pasture grass and vegetation collections added to supplement dairy sampling.
"Collected only if the plant discharges radioactive effluent into the river, then only from river irrigated fields.
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Table 5.2. Sampling locations, Monticello Nuclear Generating Plant.
Distance and Code Type a Collection Site Sample Type ' Direction from Reactor M-1 C Air Station M-1 AP, Al 11.0 mi @ 307°/NW M-2 Air Station M-2 AP, Al 0.8 mi @ 140°/SE M-3 Air Station M-3 AP, Al 0.6 mi @ 104°/ESE M-4 Air Station M-4 AP, Al 0.8 mi @ 147°/SSE M-5 Air Station M-5 AP, Al 2.6 mi @ 134°/SE M-8 C Upstream of Plant Intake SW, SS, BO, F < 1000' upstream M-9 Downstream of Plant Discharge SW, SS, BO, F < 1000' downstream M-11 City of Monticello WW 3.3 mi @ 127°/SE M-1 2 Plant Well #1 WWN 0.26 mi @ 252°/WSW M-14 City of Minneapolis DW 37.0 mi @ 132°/SE M-1 5 Montissippi Park SS 1.27 mi @ 114°/ESE M-19 River Irrigated Corn Field C VE M-21 River Irrigated Potato Field c VE M-27 Wise residence c VE, WW 0.64 mi @ 207°/SSW M-33 Monitoring Well #1 WW 593' @ 299°/WNW M-34 Monitoring Well #2 WW 749' @ 301 -/WNW M-35 Monitoring Well #3 WW 770' @ 304°/NW M-36 Monitoring Well #4 WW 0.1 mi @ 25°/NNE M-37 Monitoring Well #5 WW 0.1 mi @ 253°/WSW M-38 Monitoring Well #6 WW 229' @ 228°/SW M-39 Monitoring Well #7 WW 0.2 mi @ 66°/ENE M-40 Monitoring Well #8 WW 0.3 mi @ 150°/SSE M-41 Training Center VE 0.8 mi @ 151 */SSE M-42 Biology Station Road VE 0.6 mi @ 134°/SE M-43 C Imholte Farm ME, WW 12.3 mi @ 313°/NW M-44 Monitoring Well #9 WW 0.1 mi @ 310°/NW M-45 Monitoring Well #10 WW 0.1 mi @ 292°/WNW M-46 Monitoring Well #11 WW 0.1 mi @ 283°/WNW M-47 Monitoring Well #12A WW 0.1 mi @ 330°/NW M-48 Monitoring Well #12B WW 0.1 mi @ 326°/NW M-49 Monitoring Well #13A WW 0.12 mi @ 316°/NW M-50 Monitoring Well #13B WW 0.12 mi @ 316°/NW M-51 Monitoring Well #9B WW 0.1 mi @ 310'/NW M-52 Monitoring Well #14 WW 0.17 mi @ 306°/NW M-53 Monitoring Well #15A WW 751'@ 14°/NNE M-54 Monitoring Well #15B WW 750' @ 14°/NNE Storm water Runoff 0.1 mi @ 27°/NE 14
Table 5.2. Sampling locations, Monticello Nuclear Generating Plant.
Distance and Code Type' Collection Site Sample Type" Direction from Reactor General Area of the Site Boundary M-01A Sherburne Ave. So. TLD 0.75 mi @ 353°/N M-02A Sherburne Ave. So. TLD 0.79 mi @ 23°/NNE M-03A Sherburne Ave. So. TLD 1.29 mi @ 55°/NE M-04A Biology Station Road TLD 0.5 mi @ 86°/E M-O5A Biology Station Road TLD 0.48 mi @ 11 8°/ESE M-06A Biology Station Road TLD 0.54 mi @ 135°/SE M-07A County Road 75 TLD 0.5 mi @ 155°/SSE M-08A County Road 75 TLD 0.48 mi @ 1720/S M-09A County Road 75 TLD 0.38 mi @ 209°/SSW M-1OA County Road 75 TLD 0.38 mi @ 226°/SW M-1 1A County Road 75 TLD 0.4 mi @ 239°ANSW M-12A County Road 75 TLD 0.5 mi @ 262°NV M-13A North Boundary Road TLD 0.89 mi @ 324°/NW M-14A North Boundary Road TLD 0.78 mi @ 334 0 /NNW Approximately 4 to 5 miles Distant from the Plant M-01B Sherco #1 Air Station TLD 4.66 mi @ 02'/N M-02B County Road 11 TLD 4.4 mi @ 180 /NNE M-03B County Road 73 &81 TLD 4.3 mi @ 51 0/NE M-04B County Road 73 (196th St.) TLD 4.2 mi @ 670 /ENE M-05B City of Big Lake TLD 4.3 mi @ 89°/E M-06B County Road 14 and 196th St. TLD 4.3 mi @ 117°/ESE M-07B Monte Industrial Drive TLD 4.3 mi @ 136°/SE M-08B Residence, Hwy 25 & Davidson Ave. TLD 4.6 mi @ 162°/SSE M-09B Weinand Farm TLD 4.7 mi @ 178°/S M-1OB Reisewitz Farm, Acacia Ave. TLD 4.2 mi @ 2040/SSW M-11B Vanlith Farm, 97th Ave. TLD 4.0 mi @ 228°/SW M-12B Lake Maria State Park TLD 4.2 mi @ 254°/WSW M-13B Bridgewater Station TLD 4.1 mi @ 270°/W M-14B Anderson Residence, Cty Rd. 111 TLD 4.3 mi @ 289°/NNW M-15B Red Oak Wild Bird Farm TLD 4.3 mi @ 309 0/NW M-16B Sand Plain Research Farm TLD 4.4 mi @ 341 "/NNW 15
Table 5.2. Sampling locations, Monticello Nuclear Generating Plant.
Distance and Code Typea Collection Site Sample TypeD Direction from Reactor Special Interest Locations M-01S Osowski Fun Market TLD 0.66 mi @ 242°/WSW M-02S Krone Residence TLD 0.5 mi @ 224°/SW M-03S Big Oaks Park TLD 1.53 mi @ 102°/ESE M-04S Pinewood School TLD 2.3 mi @ 131 °/SE M-05S Rivercrest Christian Academy TLD 3.0 mi @ 118°/ESE M-06S Monte Public Works TLD 2.6 mi @ 134°/SE M-01C C Kirchenbauer Farm TLD 11.5 mi @ 323°/NW M-02C C County Roads 4 and 15 TLD 11.2 mi @ 47°/NE M-03C C County Rd 19 and Jason Ave. TLD 11.6 mi @ 130°/SE M-04C C Maple Lake Water Tower TLD 10.3 mi @ 226°/ SW Protected Area ISFSI-1 ISFSI-1 (neutron) and 1-01 (gamma) TLD NE corner of ISFSI ISFSI-2 ISFSI-2 (neutron) and 1-02 (gamma) TLD North side of ISFSI, center ISFSI-3 ISFSI-3 (neutron) and 1"03 (gamma) TLD NW corner of ISFSI ISFSI-4 ISFSI-4 (neutron) and 1-04 (gamma) TLD West side of ISFSI, middle ISFSI-5 ISFSI-5 (neutron) and 1-05 (gamma) TLD West side of ISFSI, at center of array ISFSI-6 ISFSI-6 (neutron) and 1-06 (gamma) TLD SW comer of ISFSI ISFSI-7 ISFSI-7 (neutron) and 1-07 (gamma) TLD South side of ISFSI, center ISFSI-8 ISFSI-8 (neutron) and 1-08 (gamma) TLD SE corner of ISFSI ISFSI-9 ISFSI-9 (neutron) and 1-09 (gamma) TLD East side of ISFSI, at center of array ISFSI-10 ISFSI-10 (neutron) and 1-10 (gamma) TLD East side of ISFSI, middle ISFSI-1 1 ISFSI-1 1 (neutron) and I-11 (gamma) TLD OCA fence south, on exit road ISFSI-12 ISFSI-12 (neutron) and 1-12 (gamma) TLD OCA fence middle, on exit road ISFSI-13 ISFSI-13 (neutron) and 1-13 (gamma) TLD OCA fence north, on exit road ISFSI-14 ISFSI-14 (neutron) TLD Posted with TLD M12A ISFSI-1 5 ISFSI-1 5 (neutron) TLD Posted with TLD M10 A ISFSI-16 ISFSI-16 (neutron) TLD Posted with TLD M02S Neutron Control A C TLD Posted with TLD M03C Neutron Control B C TLD Posted with TLD M04C Neutron Control C C TLD Posted with TLD M02C Neutron Control D C TLD Posted with TLD M01C a "C"denotes control location. All other locations are indicators.
Sample Codes: AP Airborne particulates F Fish Al Airborne Iodine SW River Water BS Bottom (river) sediments SS Shoreline Sediments BO Bottom organisms TLD Thermoluminescent Dosimeter DW Drinking Water VE Vegetation / vegetables WW Well Water Collected only if the plant discharges radioactive effluent into the river, then only from river irrigated fields.
16
Table 5.3. MISSED COLLECTIONS AND ANALYSES All required samples were collected and analyzed as scheduled with the following exceptions:
Collection Reason for not Sample Analysis Location (s) Date or conducting REMP Plans for Preventing Type Period as required Recurrence WW Gamma, H-3 M-014 1/13/2013 Sample damaged in shipment. None Required AP/AI Beta, 1-131 M-01 1/16/2013 Bad toggle switch. Sampler pump replaced.
SW Gamma M-008 Jan. 2013 Water frozen entire month; None Required no composite.
WW Gamma, H-3 M-027 1/24/2013 Residence vacant, None Required water turned off.
SW Gamma M-008 Feb. 2013 Water frozen entire month; None Required no composite.
SW Gamma M-008 Mar. 2013 Water frozen entire month; None Required no composite.
SW H-3 M-008 1st Qtr. 2013 Water frozen entire quarter; None Required no composite.
AP/AI Beta, 1-131 M-01 5/1/2013 Broken switch. Sampler pump replaced.
WW Gamma, H-3 M-014 5/7/2013 Sample lost in shipment. None Required AP/AI Beta, 1-131 M-01 5/8/2013 Vacuum leak. Sampler pump replaced.
WW Gamma, H-3 M-014 11/18/2013 No sample taken. Technician coached on proper turnover.
AP/AI Beta, 1-131 M-02 11/27/2013 Filter misaligned in holder, Technician coached on light particulate collected, verification practices.
SW Gamma M-008 Dec. 2013 Water frozen entire month; None Required no composite.
17
Figure 5-1. Offsite Ambient Radiation (TLDs); Inner Ring versus Outer Ring locations.
20 19 18 17 16 15 14 E 13 12 11 10 0)
Co 0) 0)
0 0 0 N
C0
~ 0 M t 0D L
0D (D
0D I-0D Co 0D M) 0CD
- 0) 0) C) 0 0) 0 0 0 D 0 0) 03 0 03 0 0
- N C.4 (N ( (N (N (N (N (N N ( N 18
Figure 5-2. Airborne Particulates; analysis for gross beta, average mean of all indicator locations versus control location.
W-- Indicators (M-2, 3, 4, 5)
Control (M-1)
C-----
0.035 0.033 0.031 2/
0.0297"'___
\
0.025
/ /'* /
/ /
0.023 O/ /
C.
0.021 0.019 0.017 0.015 CO M 0 04 0 0 0o 0- 0 0 M 0 0 CV 4 04 04 01 0\ 04 04 01 01 0 N 01 0 19
Table 5.4 Radiological Environmental Monitoring Program Summary Name of Facility Monticello Nuclear Generatinq Plant Docket No. 50-263 Location of Facility Wright, Minnesota Reporting Period January-December, 2013
( County, State)
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLD' Mean (F)c Mean (F)c Mean (F)c Routine (Units) Analysesa Range' Locationd Rangec Rangec Results' Direct Radiation TLD (Inner Ring, Gamma 56 3.0 14.4 (56/56) M-13A 16.1 (4/4) (See Control 0 General Area at (10.9-18.6) 1.1 mi @ 317°/NW (13.5-18.3) below.)
Site Boundary) mRem/91 days)
TLD (Outer Ring, Gamma 64 3.0 14 (64/64) M-10B 15.8 (4/4) (See Control 0 4-5 mi. distant) (10.4-19.1) 4.4 mi @ 206°/SSW (13.6-19.1) below.)
mRem/91 days)
TLD (Special Gamma 24 3.0 14.0 (24/24) M-06S, Mont. Pub. Wks. 17.1 (4/4) (See Control 0
- Interest Areas) (10.8-17.8) 2.7 mi @ 136°/SE (16.7-17.8) below.)
mRem/91 days)
TLD (Control) Gamma 16 3.0 None M-03C, Rte. 19 & Jason, 16.4 (4/4) 15.5 (16/16) 0 mRem/91 days) 11.6 mi @ 130°/SE (15.5-16.8) (11.8-18.8)
Airborne Pathway Airborne GB 256 0.002 0.029 (207/207) M-1 (C), Air Station 0.032 (49/49) 0.032 (49/49) 0 Particulates (0.007-0.074) 11.0 mi @ 307°/NW (0.011-0.070) (0.011-0.070) 3 (pCi/m )
GS 20 Be-7 0.015 0.064 (16/16) M-5, Air Station 0.072 (4/4) 0.067 (4/4) 0 (0.042-0.088) 2.6 mi @ 134°/SE (0.047-0.088) (0.046-0.092)
Mn-54 0.0011 < LLD < LLD 0 Co-58 0.0009 < LLD < LLD 0 Co-60 0.0008 < LLD < LLD 0 Zn-65 0.0015 < LLD < LLD 0 Zr-Nb-95 0.0012 < LLD < LLD 0 Ru-103 0.0012 < LLD < LLD 0 Ru-106 0.0091 < LLD - < LLD 0 Cs-1 34 0.0008 < LLD < LLD 0 Cs-137 0.0010 < LLD < LLD 0 Ba-La-140. 0.0022 < LLD < LLD 0 te-141 0.0019 < LLD < LLD 0 Ce-144 0.0050 < LLD < LLD 0 Airborne Iodine 1-131 256 0.03 < LLD < LLD 0 3
(pCi/m )
20
Table 5.4 Radiological Environmental Monitoring Program Summary Name of Facility Monticello Nuclear Generating Plant Docket No. 50-263 Location of Facility Wright, Minnesota Reporting Period January-December, 2013
( County, State )
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLDb Mean (F)c Mean (F)c Mean (F)c Routine (Units) Analyses'. Range' Locationd Rangec Rangec Resultse Waterborne Pathway River Water (pCi/L) H-3 7 500 < LLD < LLD 0 GS 20 Mn-54 10 < LLD < LLD 0 Fe-59 30 < LLD < LLD 0 Co-58 10 < LLD - < LLD 0 Co-60 10 < LLD - < LLD 0 Zn-65 30 < LLD - < LLD 0 Zr-Nb-95 15 < LLD - < LLD 0 Cs-134 10 < LLD - < LLD 0 Cs-137 10 < LLD - < LLD 0 Ba-La-140 15 < LLD - < LLD 0 Ce-144 29 < LLD - < LLD 0 Drinking Water GB 12 1.0 2.6 (12/12) M-14, Minneapolis 2.6 (12/12) None 0 0
(pCi/L) (1.5-3.2) 37.0 mi. @ 132 /SE (1.5-3.2) 1-131 12 1.0 < LLD None 0 H-3 4 500 < LLD None 0 GS 12 Mn-54 10 < LLD None 0 Fe-59 30 < LLD None 0 Co-58 10 < LLD None 0 Co-60 10 < LLD None 0 Zn-65 30 < LLD None 0 Zr-Nb-95 15 < LLD None 0 Cs-134 10 < LLD - None 0 Cs-137 10 < LLD None 0 Ba-La-140 15 < LLD - None 0 Ce-144 51 < LLD None 0 Well Water H-3 15 500 < LLD - < LLD 0 (pCi/L) GS 15 Mn-54 10 < LLD - -< LLD 0 Fe-59 30 < LLD - -< LLD 0 Co-58 10 < LLD - -< LLD 0 Co-60 10 < LLD - - < LLD 0 Zn-65 30 < LLD - - < LLD 0 Zr-Nb-95 15 < LLD - - < LLD 0 Cs-134 10 < LLD - - < LLD 0 Cs-137 10 < LLD - - < LLD 0 Ba-La-140 . 15 < LLD - - < LLD 0 Ce-144 57 < LLD - - < LLD 0 21
Table 5.4 Radiological Environmental Monitoring Program Summary Name of Facility Monticello Nuclear Generatino Plant Docket No. 50-263 Location of Facility Wright, Minnesota Reporting Period January-December, 2013 (County, State)
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLD b Mean (F)M Mean (F)' Mean (F)c Routine 0
(Units) Analyses' Rangec Locationd Rangec Rangec Results Waterborne Pathway Invertebrates GS 4 (pCi/g wet) Be-7 0.84 < LLD < LLD 0 K-40 1.04 < LLD < LLD 0 Mn-54 0.067 < LLD < LLD 0 Fe-59 0.18 < LLD < LLD 0 Co-58 0.074 < LLD < LLD 0 Co-60 0.048 < LLD < LLD 0 Zn-65 0.12 < LLD < LLD 0 Zr-Nb-95 0.13 < LLD < LLD 0 Ru-103 0.092 < LLD < LLD 0 Ru-106 0.56 < LLD < LLD 0 Cs-134 0.059 < LLD < LLD 0 Cs-137 0.065 < LLD < LLD 0 Ba-La-140 0.37 < LLD < LLD 0 Ce-144 0.35 < LLD < LLD 0 Shoreline GS 6 Sediments Be-7 0.24 0.35 (2/4) M-09, Downstream 0.42 (112) < LLD 0 (pCi/g dry) (0.27-0.42) < 1000' of discharge K-40 0.10 9.96 (4/4) M-15, Montissippi Park 10.58 (2/2) 9.96 (2/2) 0 (8.62-10.92) 1.27 mi @ 114°/ESE (10.23-10.92) (9.71-10.21)
Mn-54 0.020 < LLD < LLD 0 Fe-59 0.061 < LLD < LLD 0 Co-58 0.024 < LLD < LLD 0 Co-60 0.012 < LLD < LLD 0 Zn-65 0.053 < LLD < LLD 0 Nb-95 0.028 < LLD < LLD 0 Zr-95 0.057 < LLD < LLD 0 Ru-1 03 0.028 < LLD < LLD 0 Ru-106 0.13 < LLD < LLD 0 Cs-134 0.015 < LLD < LLD 0 Cs-137 0.019 0.035 (2/4) M-15, Montissippi Park 0.035 (2/2) < LLD 0 (0.022-0.049) 1.27 mi @ 114'/ESE (0.022-0.049)
Ba-La-140 0.11 < LLD < LLD 0 Ce-144 0.13 < LLD < LLD 0 22
Table 5.4 Radiological Environmental Monitoring Program Summary Name of Facility Monticello Nuclear Generating Plant Docket No. 50-263 Location of Facility Wright, Minnesota Reporting Period January-December, 2013
( County, State)
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLDb Mean (F)' Mean (F)c Mean (F)c Routine (Units) Analysesa Range' Locationd Range' Range' Resultse Ingestion Pathway Vegetation GS 9 (Pasture Grass, Mn-54. 0.016 < LLD < LLD 0 Weeds, Leaves) Fe-59 0.026 < LLD < LLD 0 Co-58 0.014 < LLD < LLD 0 (pCi/gwet) Co-60 0.014 < LLD < LLD 0 Zn-65 0.031 < LLD < LLD 0 Nb-95 0.019 < LLD < LLD 0 1-131 0.034 < LLD < LLD 0 Cs-134 0.016 < LLD < LLD 0 Cs-137 0.017 < LLD < LLD 0 Fish GS 4 (pCi/g wet) K-40 0.10 3.27 (2/2) M-09, Downstream 3.27 (2/2) 3.19 (2/2) 0 (2.91-3.64) < 1000' of discharge (2.91-3.64) (2.99-3.38)
Mn-54 0.013 < LLD < LLD 0 Fe-59 0.034 < LLD - < LLD 0 Co-58 0.009 < LLD - < LLD 0 Co-60 0.013 < LLD - < LLD 0 Zn-65 0.017 < LLD - < LLD 0 Zr-Nb-95 0.012 < LLD - < LLD 0 Cs-134 0.006 < LLD - < LLD 0 Cs-137 0.013 < LLD - < LLD 0 Ba-La-140 0.019 < LLD - < LLD 0 Ce-144 0.091 < LLD - < LLD 0 GB = gross beta, GS = gamma scan.
b LLD = nominal lower limit of detection based on a 4.66 sigma counting error for background sample.
c Mean and range are based on detectable measurements only. Fraction of detectable measurements at specified locations is indicated in parentheses (F).
d Locations are specified: (1) by name, and/or station code and (2) by distance (miles) and direction relative to reactor site.
o Non-routine results are those which exceed ten times the control station value. If no control station value is available, the result is considered non-routine if it exceeds ten time the typical preoperational value for the medium or location.
23
6.0 REFERENCES
CITED Arnold, J. R. and H. A. AI-Salih. 1955. Beryllium-7 Produced by Cosmic Rays. Science 121: 451-453.
Eisenbud, M. 1963. Environmental Radioactivity, McGraw-Hill, New York, New York, pp. 213, 275, 276.
ATI Environmental, Inc., Midwest Laboratory.
2001a through 2014a. Radiation Environmental Monitoring for Monticello Nuclear Generating Plant, Complete Analysis Data Tables, January-December, 2000 through 2013.
2001b through 2014b. Radiation Environmental Monitoring for Prairie Island Nuclear Generating Plant, Complete Analysis Data Tables, January - December, 2000 through 2013.
1984a to 2000a. (formerly Teledyne Brown Engineering Environmental Services, Midwest Laboratory)
Radiation Environmental Monitoring for Monticello Nuclear Generating Plant, Complete Analysis Data Tables, January - December, 1983 through 1999.
1984b to 2000b. (formerly Teledyne Brown Engineering Environmental Services, Midwest Laboratory)
Radiation Environmental Monitoring for Prairie Island Nuclear Generating Plant, Complete Analysis Data Tables, January - December, 1983 through 1999. :?
1979a to 1983a. (formerly Hazleton Environmental Sciences Corporation) Radiation Environmental Monitoring for Monticello Nuclear Generating Plant, Complete Analysis Data Tables, January - December, 1978 through 1982.
1979b to 1983b. (formerly Hazleton Environmental Sciences Corporation) Radiation Environmental Monitoring for Prairie Island Nuclear Generating Plant, Complete Analysis Data Tables, January -
December, 1978 through 1982.
2009. Quality Assurance Program Manual, Rev. 3, 14 November 2012.
2009. Quality Control Procedures Manual, Rev. 2, 08 July 2009.
2009. Quality Control Program, Rev. 2, 12 November 2009.
Gold, S., H.W. Barkhau, B. Shlein, and B. Kahn, 1964. Measurement of Naturally Occurring Radionuclides in Air, in the Natural Environment, University of Chicago Press, Illinois, 369-382.
National Center for Radiological Health, 1968. Radiological Health and Data Reports, Vol. 9, Number 12, 730-746.
Northern States Power Company.
1969 through 1971. Monticello Nuclear Generating Plant, Environmental Radiation Monitoring Program, Annual Report, June 18, 1968 to December 31, 1968, 1969, 1970. Minneapolis, Minnesota.
1978 through 2008. Monticello Nuclear Generating Plant, Annual Radiation Environmental Monitoring Report to the U.S. Nuclear Regulatory Commission, January 1, to December 31, 1977 through 2007.
24
6.0 REFERENCES
CITED (continued)
U.S. Dep't of Energy 1997 HASL-300, Edition 28, Procedures Manual, Environmental Measurements Laboratory, New York, NY.
U.S. Environmental Protection Agency.
1980. Prescribed Procedures for Measurement of Radioactivity in Drinking Water, Cincinnati, Ohio (EPA-600/4-80-032).
1984. Eastern Environmental Radiation Facility, Radiochemistry Procedures Manual, Montgomery, Alabama (EPA-520/5-84-006).
2009. RadNet, formerly Environmental Radiation Ambient Monitoring System, Gross Beta in Air, Gross Beta in Drinking Water (MN) 1981- 2005.
Wilson, D. W., G. M. Ward and J. E. Johnson. 1969. In Environmental Contamination by Radioactive Materials, International Atomic Energy Agency. p.125.
Xcel Energy Corporation.
2009 to 2013. Monticello Nuclear Generating Plant, .Annual Radiation Environmental Monitoring Report to the U.S. Nuclear Regulatory Commission, January 1 to December 31, 2008 through 2012. Minneapolis, Minnesota.
2009 to 2013. Prairie Island Nuclear Generating Plant, Annual Radiation Environmental Monitoring Report to the U.S. Nuclear Regulatory Commission, January 1 to December 31, 2008 through 2012.
Minneapolis, Minnesota.
25
14,A~ Environmental, Inc.
Midwest Laboratory 700 Lgindwehr Road - Northbrook. IL 6006242310 phone (847) 564-0700 . fax (847) 564-45.17 APPENDIX A INTERLABORATORY COMPARISON PROGRAM RESULTS NOTE: Environmental Inc., Midwest Laboratory participates in intercomparison studies administered by Environmental Resources Associates, and serves as a replacement for studies conducted previously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. Results are reported in Appendix A. TLD Intercomparison results, in-house spikes, blanks, duplicates and mixed analyte performance evaluation program results are also reported. Appendix A is updated four times a year; the complete Appendix is included in March, June, September and December monthly progress reports only.
January through December, 2013
Appendix A Interlaboratory Comparison Proqram Results Environmental, Inc., Midwest Laboratory has participated in interlaboratory comparison (crosscheck) programs since the formulation of its quality control program in December 1971. These programs are operated by agencies which supply environmental type samples containing concentrations of radionuclides known to the issuing agency but not to participant laboratories. The purpose of such a program is to provide an independent check on a laboratory's analytical procedures and to alert it of any possible problems.
Participant laboratories measure the concentration of specified radionuclides and report them to the issuingagency. Several months later, the agency reports the known values to the participant laboratories and specifies control limits. Results consistently higher or lower than the known values or outside the control limits indicate a need to check the instruments or procedures used.
Results in Table A-1 were obtained through participation in the environmental sample crosscheck program administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada.
Table A-2 lists results for thermoluminescent dosimeters (TLDs), via International Intercomparison of Environmental Dosimeters, when available, and internal laboratory testing.
Table A-3 lists results of the analyses on in-house "spiked" samples for the past twelve months. All samples are prepared using NIST traceable sources. Data for previous years available upon request.
Table A-4 lists results of the analyses on in-house "blank" samples for the past twelve months. Data for previous years available upon request.
Table A-5 lists REMP specific analytical results from the in-house "duplicate" program for the past twelve months. Acceptance is based on the difference of the results being less than the sum of the errors. Complete analytical data for duplicate analyses is available upon request.
The results in Table A-6 were obtained through participation in the Mixed Analyte Performance Evaluation Program.
Results in Table A-7 were obtained through participation in the environmental sample crosscheck program administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the Environmental Measurement Laboratory Quality Assessment Program (EML).
Attachment A lists the laboratory precision at the 1 sigma level for various analyses. The acceptance criteria in Table A-3 is set at +/- 2 sigma.
Out-of-limit results are explained directly below the result.
Al
Attachment A ACCEPTANCE CRITERIA FOR "SPIKED" SAMPLES LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSESa One standard deviation Analysis Level for single determination Gamma Emitters 5 to 100 pCi/liter or kg 5.0 pCi/liter
> 100 pCi/liter or kg 5% of known value Strontium-89b 5 to 50 pCi/liter or kg 5.0 pCi/liter
> 50 DCi/liter or kg 10% of known value Strontium-90b 2 to 30 pCi/liter or kg 5.0 pCi/liter
> 30 pCi/liter or kg 10% of known value Potassium-40 > 0.1 g/liter or kg 5% of known value Gross alpha -520 pCi/liter 5.0 pCi/liter
> 20 pCi/liter 25% of known value Gross beta < 100 pCi/liter 5.0 pCi/liter
> 100 pCi/liter 5% of known value Tritium < 4,000 pCi/liter +1o =
0 0 933 169.85 x (known)
> 4,000 pCi/liter 10% of known value Radium-226,-228 > 0.1 pCi/liter 15% of known value Plutonium > 0.1 pCi/liter, gram, or sample 10% of known value Iodine-131, < 55 pCi/liter 6 pCi/liter Iodine-1 2 9 b > 55 pCi/liter 10% of known value Uranium-238, < 35 pCi/liter 6 pCi/liter Nickel-63b > 35 pCi/liter 15% of known value Technetium-99b Iron-55b 50 to 100 pCi/liter 10 pCi/liter
> 100 pCi/liter 10% of known value Other Analyses b 20% of known value a From EPA publication, "Environmental Radioactivity Laboratory Intercomparison Studies Program, Fiscal Year, 1981-1982, EPA-600/4-81-004.
b Laboratory limit.
A2
TABLE A-1. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.
.Concentration (pCi/L)
Lab Code Date Analysis Laboratory ERA Control Result b Result c Limits Acceptance ERW-76 01/07/13 Ra-226 10.04 +/- 0.55 9.91 7.42 -11.60 Pass ERW-76 01/07/13 Ra-228 6.11 +/- 1.29 5.22 3.14 -6.96 Pass ERW-76 01/07/13 Uranium 5.90 +/- 0.58 5.96 4.47-7.13 Pass ERW-1593 04/08/13 Sr-89 43.60 +/- 4.32 41.30 31.60 - 48.40 Pass ERW-1593 04/08/13 Sr-90 23.20 4- 1.70 23.90 17.20 - 28.00 Pass ERW-1596 04/08/13 Ba-1 33 74.80 +/- 4.00 82.10 69.00 - 90.30 Pass ERW-1596 04/08/13 Co-60 65.50 +/- 3.42 65.90 69.30 - 75.00 Pass ERW-1596 04/08/13 Cs-1 34 41.10 +/- 3.47 42.80 34.20 - 47.10 Pass ERW-1 596 04/08/13 Cs-1 37 42.30 +/- 4.03 41.70 37.00 - 48.80 Pass ERW-1 596 04/08/13 Zn-65 200.3 +/- 10.1 189.0 170.0 - 222.0 Pass ERW-1 598 04/08/13 Gr. Alpha 34.30 +/- 1.98 40.80 21.10 - 51.90 Pass ERW-1.598 04/08/13 Gr. Beta 18.70 +/- 0.98 21.60 13.00 - 29.70 Pass ERW-1600 04/08/13 1-131 23.00 +/- 1.10 23.80 19.70 - 28.30 Pass ERW-1600 04/08/13 1-131(G). 23.48 +/- 9.44 23.80 19.70 - 28.30 Pass ERW-1605 04/08/13 Ra-226 16.30 +/- 0.70 15.40 11.50 - 17.70 Pass ERW-1605 04/08/13 Ra-228 5.32 +/- 1.30 4.36 2.54 - 5.98 Pass ERW-1605 04/08/13 Uranium 57.30 +/- 4.20 61.20 49.80 - 67.90 Pass ERW-1606 04/08/13 H-3 4041 +/- 194 4050 3450 - 4460 Pass ERW-6009 10/07/13 Sr-89 22.00 +/- 2.80 21.90 14.40 +/- 28.20 Pass ERW-6009 10/07/13 Sr-90 17.10 +/- 2.55 18.10 12.80 +/- 21.50 Pass ERW-6012 10/07/13 Ba-1 33 48.20 +/- 4.29 54.20 44.70 +/- 59.90 Pass ERW-6012 10/07/13 Co-60 100.8 +/- 4.7 102.0 91.80 +/- 114.00 Pass ERW-6012 10/07/13 Cs-1 34 87.30 +/- 4.35 86.70 71.10 +/- 95.40 Pass ERW-6012 10/07/13 Cs-1 37 199.6 +/- 7.4 206.0 185.0 - 228.0 Pass ERW-6012 10/07/13 Zn-65 356.2.+/- 13.2 333.0 300.0 - 389.0 Pass ERW-6015 10/07/13 Gr. Alpha 30.70 +/- 11.90 42.80 22.20 +/- 54.30 Pass ERW-6015 10/07/13 Gr. Beta 25.70 +/- 6.48 32.20 20.80 +/- 39.90 Pass ERW-6019 10/07/13 1-131 22.50 +/- 1.01 23.60 19.60 +/- 28.00 Pass ERW-6022 10/07/13 Ra-226 12.70 +/- 1.62 12.10 9.04 +/- 14.00 Pass d
ERW-6022 10/07/13 Ra-228 5.70 +/- 0.56 4.02 2.30 +/- 5.59 Fail ERW-6022 10/07/13 Uranium 6.59 +/- 0.38 6.24 4.70 +/- 7.44 Pass ERW-6024 10/07/13 H-3 18397 +/-695 17700 .15500 -19500 Pass a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency testing in drinking water conducted by Environmental Resources Associates (ERA).
b Unless otherwise indicated, the laboratory result is given as the mean +/- standard deviation for three determinations.
c Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits as provided by ERA.
d The reported result was obtained in the first cycle of counting. It can be positively biased due to extra beta counts contributed by Pb-214 and Bi-214 daughters of Rn-222. Result of second cycle of counting 4.47 p-iIL.
Al-1
TABLE A-2. Thermoluminescent Dosimetry, (TLD, CaSO 4 : Dy Cards).
mR Lab Code Date Known Lab Result Control Description Value + 2 sigma Limits Acceptance Environmental, Inc.
2013-1 5/6/2013 40 cm. 34.26 39.92 +/- 2.67 23.98 -44.54 Pass 2013-1 5/6/2013 50 cm. 21.93 25.44 +/- 3.31 15.35 - 28.51 Pass 2013-1 5/6/2013 60 cm. 15.23 15.88 +/- 1.12 10.66 - 19.80 Pass 2013-1 5/6/2013 70 cm. 11.19 10.89 +/- 0.66 7.83 - 14.55 Pass 2013-1 5/6/2013 80 cm. 8.57 9.21 +/- 0.41 6.00-11.14 Pass 2013-1 516/2013 90 cm. 6.77 6.52 +/- 0.34 4.74 - 8.80 Pass 2013-1 5/6/2013 100 cm. 5.48 5.02 +/- 0.53 3.84 -7.12 Pass 2013-1 5/6/2013 110 cm. 4.53 4.51 +/- 0.34 3.17 -5.89 Pass 2013-1 5/6/2013 120 cm. 3.81 4.28 +/- 0.35 2.67 -4.95 Pass 2013-1 5/6/2013 135 cm. 3.01 2.64 +/- 0.18 2.11 -3.91 Pass 2013-1 5/6/2013 150 cm. 2.44 2.10 +/- 0.25 1.71 -3.17 Pass 2013-1 5/6/2013 180 cm. 1.69 1.78 +/- 0.33 1.18 -2.20 Pass Environmental, Inc.
2013-2 11/18/2013 50cm. 19.93 22.75 +/- 3.67 13.95 -25.91 Pass 2013-2 11/18/2013 60 cm. 13.84 15.75 +/- 1.94 9.69 - 17.99 Pass 2013-2 11/18/2013 70 cm. 10.17 11.24 +/- 0.88 7.12 - 13.22 Pass 2013-2 11/18/2013 75 cm. 8.86 9.18 +/- 1.23 6.20 -11.52 Pass.
201 3-2 11/18/2013 80 cm. 7.79 7.81 +/- 1.10 5.45 -10.13 Pass 2013-2 11/18/2013 90 cm. 6.15 5.98 +/- 0.90 4.31 - 8.00 Pass 2013-2 11/18/2013 100 cm. 4.98 5.13 +/- 0.73 3.49 - 6.47 Pass 2013-2 11/18/2013 110 cm. 4.12 3.87 +/- 0.32 2.88 - 5.36 Pass 2013-2 11/18/2013 120 cm. 3.46 3.11 +/- 0.39 2.42 -4.50 Pass 2013-2 11/18/2013 135 cm. 2.73 2.71 +/- 0.83 1.91 -3.55 Pass 2013-2 11/18/2013 150 cm. 2.21 2.11 +/- 0.63 1.55 -2.87 Pass 2013-2 11/18/2013 180 cm. 1.54 1.81 +/- 0.10 1.08 -2.00 Pass A2-1
TABLE A-3. In-House "Spiked" Samples Concentration (pCi/L)a Lab Code b Date Analysis Laboratory results Known Control 2s, n=1 c Activity Limits d Acceptance SPW-66 1/9/2013 Tc-99 1009 +/-5 1078 754.9 - 1402.0 Pass SPW-1891 1/18/2013 Ra-228 35.60 +/- 2.75 30.85 21.60 - 40.11 Pass SPSO-12313S 1/23/2013 Tc-99 103.5 +/-2.2 107.8 75.46 - 140.14 Pass SPMI-264 1/25/2013 Cs-1 34 110.9 +/-6.7 107.5 96.73 -118.23 Pass SPMI-264 1/25/2013 Cs-137 82.84 +/- 7.47 77.48 67.48 - 87.48 Pass SPMI-264 1/25/2013 Sr-90 38.19 +/- 1.49 40.11 32.09 -48.13 Pass SPW-266 1/25/2013 Co-60 46.89 +/- 4.68 44.48 34.48 - 54.48 Pass SPW-266 1/25/2013 Cs-134 105.9 +/- 8.0 107.5 96.73 - 118.23 Pass SPW-266 1/25/2013 Cs-1 37 42.17 +/- 5.65 39.49 29.49 - 49.49 Pass SPW-266 1/25/2013 Sr-90 39.84 +/- 1.65 40.11 32.09 - 48.13 Pass SPAP-376 2/1/2013 Gr. Beta 44.20 +/- 0.11 45.68 27.41 - 63.95 Pass SPAP-378 2/1/2013 Cs-134 3.71 +/- 0.65 3.87 2.32 - 5.42 Pass SPAP-378 2/1/2013 Cs-137 97.47 +/- 2.50 102.9 92.61 -113.19 Pass SPW-391 2/1/2013 H-3 63719 +/- 703 65626 52501 -78751 Pass SPW-380 2/10/2013 Ni-63 217.0 +/- 3.7 205:3 143.7 - 266.9 Pass W-30413 3/4/2013 Gr. Alpha 19.77 +/- 0.40 20.00 10.00 - 30.00 Pass W-30413 3/4/2013 Gr. Beta 30.48 +/- 0.34 30.90 20.90 - 40.90 Pass W-30713 3/7/2013 Ra-226 18.06 +/- 0.51 16.70 11.69 - 21.71 Pass W-42713 4/27/2013 Gr. Alpha 20.67 +/- 0.40 20.00 10.00 - 30.00 Pass W-42713 4/27/2013 Gr. Beta 28.44 +/- 0.32 30.90 20.90 - 40.90 Pass WW-2870 5/7/2013 Co-60 166.1 +/- 7.4 161.6 145.4 - 177.8 Pass WW-2870 5/7/2013 Cs-137 161.2 +/- 9.3 149.0 134.1 - 163.9 Pass WW-2870 5/7/2013 H-3 6853 +/- 250 6735 5388 - 8082 Pass W-53113 5/31/2013 Ra-226 16.83 +/- 0.41 16.70 11.69 - 21.71 Pass SPAP-3332 6/19/2013 Am-241 4.60 +/- 0.14 4.00 2.40 - 5.60 Pass SPW-3334 6/19/2013 Th-230 4.36 +/- 0.34 4.00 2.40 - 5.60 Pass SPW-3458 6/24/2013 C-1 4 3825 +/- 13 4736 2842 - 6630 Pass SPAP-3529 6/27/2013 Cs-134 3.49 +/- 1.26 3.30 1.98 -4.62 Pass SPAP-3529 6/27/2013 Cs-137 102,0 +/-2.9 101.1 90.99 - 111.21 Pass SPAP-3531 6/27/2013 Gr. Beta 45.64 +/- 0.11 45.42 27.25 - 63.59 Pass SPF-3533 6/27/2013 Cs-134 1.31 +/- 0.14 1.50 0.90 -2.10 Pass SPF-3533 6/27/2013 Cs-137 2.77 +/- 0.27 2.43 1.46 - 3.40 Pass SPW-3535 6/27/2013 Ni-63 204.3 +/- 3.5 204.8 143.4 - 266.2 Pass SPW-3537 6/27/2013 Tc-99 104.5 +/- 1.7 107.8 75.46 - 140.14 Pass SPW-3539 6/27/2013 Fe-55 97015 +/- 860 90677 72542 - 108812 Pass SPW-1893 6/28/2013 Ra-228 30.16 -2.73 30.85 21.60 - 40.11 Pass A3-1
TABLE A-3. In-House "Spiked" Samples Concentration (pCi/L)a Lab Code b Date Analysis Laboratory results Known Control 2s, n=l c Activity Limits d Acceptance SPW-72913S 7/29/2013 Tc-99 126.6 +/- 2.2 107.8 75.46 +/- 140.14 Pass SPW-4373 7/31/2013 Cs-1 34 91.71 +/- 6.02 90.94 80.94 +/- 100.94 Pass SPW-4373 7/31/2013 Cs-137 83.05 +/- 7.20 76.57 66.57 +/- 86.57 Pass SPW-4373 7/31/2013 Sr-90 39.28 +/- 1.77 39.64 31. 7 11 +/- 47.57 Pass SPW-4374 7/31/2013 Sr-90 42.17 +/- 1.71 39.64 31.71 +/- 47.57 Pass SPMI-4376 7/31/2013 Cs-134 82.22 - 7.23 90.94 80.94 +/- 100.94 Pass SPMI-4376 7/31/2013 Cs-137 83.31 -8.29 76.57 66.57 +/- 86.57 Pass SPMI-4376A 7/31/2013 Sr-90 35.00 +/- 1.63 39.64 31.71 +/- 47.57 Pass W-73113 7/31/2013 Ra-226 17.61 +/- 0.41 16.70 11.69 +/-21.71 Pass SPS-4514 8/5/2013 Sr-90 78.63 +/- 2.95 79.28 63.42 +/- 95.14 Pass W-82013 8/20/2013 Gr. Alpha 21.53 +/- 0.45 20.00 10.00 +/- 30.00 Pass W-82013 8/20/2013 Gr. Beta .28.03 +/- 0.32 30.90 20.90 +/- 40.90 Pass SPW-1894 8/28/2013 Ra-228 32.49 +/- 3.00 30.85 21.60 +/- 40.11 Pass W-90913 9/9/2013 Gr. Alpha 19.08 +/- 0.51 20.10 10.05 +/- 30.15 Pass W-90913 9/9/2013 Gr. Beta 32.12 +/- 0.35 32.10 22.10 +/-.42.10 Pass WW-5623 10/3/2013 Co-60 157.0 +/- 7.0 155.3 139.8 - 170.8 Pass WW-5623 10/3/2013 Cs-137 156.0 +/-8.8 148.1 133.3 - 162.9 Pass WW-5623 10/3/2013 H-3 6590 +/- 245 6322 5058 - 7586 Pass WW-5750 10/3/2013 Co-60 87.00 +/- 7.80 77.40 77.00 +/- 97.00 Pass WW-5750 10/3/2013 Cs-137 82.30 +/- 7.80 78.80 68.80 +/- 88.80 Pass WW-5750 10/3/2013 H-3 6181 +/- 238 6322 5058 - 7586 Pass W-1 02813 10/28/2013 Ra-226 15.69 +/- 0.37 16.70 11.69 +/- 21.71 Pass SPW-1 898 12/17/2013 Ra-228 28.15 +/- 2.37 30.85 21.60 +/- 40.11 Pass W-122313 12/23/2013 Gr. Alpha 20.96 +/- 0.47 20.10 10.05 +/- 30.15 Pass W-122313 12/23/2013 Gr. Beta 31.00 +/- 0.34 32.10 22.10 +/-42.10 Pass a Liquid sample results are reported in pCi/Liter, air filters( pCi/m 3), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).
Laboratory codes : W (Water), MI (milk), AP (air filter), SO (soil), VE (vegetation), CH (charcoal canister), F (fish), U (urine).
c Results are based on single determinations.
d Control limits are established from the precision values listed in Attachment A of this report, adjusted to +/- 2s.
NOTE: For fish, Jello is used for the Spike matrix. For Vegetation, cabbage is used for the Spike matrix.
A3-2
TABLE A-4. In-House "Blank" Samples Concentration (pCi/L)a Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance Type LLD Activityc Criteria (4.66 a)
SPW-67 Water 1/9/2013 Tc-99 1.10 0.69 4. 0.68 10 SPW-190 Water 1/18/2013 Ra-228 0.74 0.66 +/- 0.43 2 SPW-1901 Water 1/18/2013 Ra-228 0.74 0.66 +/- 0.43 2 SPMI-263 Milk 1/25/2013 Sr-90 0.64 0.31 +/- 0.34 1 SPMI-263 Milk 1/25/2013 Sr-90 0.64 0.31 +/- 0.34 1 SPW-265 Water 1/25/2013 Co-60 2.86 2.10 +/- 1.72 10 SPW-265 Water 1/25/2013 Cs-134 2.98 2.25 +/- 1.57 10 SPW-265 Water 1/25/2013 Cs-137 2.71 0.44 +/- 1.61 10 SPW-266 Water 1/25/2013 Sr-90 0.72 -0.12 +/- 0.32 1 SPAP-375 Air Filter 2/1/2013 Gr. Beta 0.003 0.016 +/- 0.003 0.010 SPAP-377 Air Filter 2/1/2013 Co-60 2.31 -0.34 +/- 1.75 100 SPAP-377 Air Filter 2/1/2013 Cs-1 34 2.72 1.22 +/- 1.62 100 SPAP-377 Air Filter 2/1/2013 Cs-137 1.50 -0.52 +/- 1.80 100 SPW-391 Water 2/1/2013 H-3 92.04 -29.44 +/- 69.24 200 SPW-379 Water 2/10/2013 Ni-63 2.11 0.91 +/- 1.30 20 W-30413 Water 3/4/2013 Gr. Alpha 0.35 0.08 +/- 0.26 1 W-30413 Water 3/4/2013 Gr:' Beta 0.73 0.10 +/- 0.51 3.2 W-30713 Water 3/7/2013 Ra-226 0.031 0.032 +/- 0.024 1 W-42713 Water 4/27/2013 Gr. Alpha 0.45 -0.14 +/- 0.30 1 W-42713 Water 4/27/2013 Gr. Beta 0.72 -0.23 +/- 0.50 3.2 W-53113 Water 5/31/2013 Ra-226 0.03 0.01 +/-0.02 1 SPW-3335 Water 6/19/2013 Th-230 0.01 0.01 +/- 0.01 1 SPW-3459 Water 6/24/2013 C-14 10.89 10.44 +/- 6.82 200 SPAP-3528 Air Filter 6/27/2013 Cs-134 2.10 -0.98 +/- 1.11 100 SPAP-3528 Air Filter 6/27/2013 Cs-1 37 2.71 -0.24 +/- 1.36 100 SPAP-3530 Air Filter 6/27/2013 Gr. Beta 0.004 0.018 +/- 0.003 0.010 SPF-3532 Fish 6/27/2013 Cs-134 8.38 -1.39 +/- 5.69 100 SPF-3532 Fish 6/27/2013 Cs-137 8.37 -1.88 +/- 6.41 100 SPW-3534 Water 6/27/2013 Ni-63 2.47 -1.04 +/- 1.48 20 SPW-3536 Water 6/27/2013 Tc-99 1.15 -1.11 +/- 0.68 10 SPW-3538 water 6/27/2013 Fe-55 170.27 -17.50 +/- 102.70 1000 SPW-1903 Water 6/28/2013 Ra-228 0.85 -0.02 +/- 0.39 2 A4-1
TABLE A-4. In-House "Blank" Samples Concentration (pCi/L)a Lab Code Sample Date Analysis" Laboratory results (4.66a) Acceptance Type .LLD Activityc Criteria (4.66 o)
SPW-72913B Water 7/29/2013 Tc-99 1.44 -0.33 +/- 0:87 10 SPW-4372 Water 7/31/2013 Co-60 1.41 -1.42 +/- 3.00 10 SPW-4372 Water 7/31/2013 Cs-134 3.68 -2.66 +/- 3.46 10 SPW-4372 Water 7/31/2013 Cs-137 3.53 0.29 +/- 3.31 10 SPMI-4375 Milk 7/31/2013 Co-60 3.92 2.65 +/- 2.26 10 SPMI-4375 Milk 7/31/2013 Cs-134 4.67 0.68 +/- 2.54 10 SPMI-4375 Milk 7/31/2013 Cs-137 4.79 1.30 +/- 2.68 10 SPMI-4375 Milk 7/31/2013 Sr-90 0.57 0.32 +/- 0.30 1 W-73113 Water 7/31/2013 Ra-226 0.02 0.04 +/- 0.02 1 SPS-4515 Powder 8/5/2013 Sr-90 0.09 -0.01 +/- 0.04 1 W-82013 Water 8/20/2013 Gr. Alpha 0.42 -0.15 +/- 0.28 1 W-82013 Water 8/20/2013 Gr. Beta 0.74 -0.24 +/- 0.51 3.2 SPW-1904 Water 8/28/2013 Ra-228 0.96 0.85 +/- 0.56 2 CHW-90913 Water 9/9/2013 Gr. Alpha 0.25 0.20 +/- 0.29 1 CHW-90913 Water 9/9/2013 Gr. Beta 0.49 -0.18 +/- 0.53 3.2 CHW-102013 Water 10/20/2013 Gr. Alpha 0.29 0.24 +/- 0.33 1 CHW-102013 Water 10/20/2013 Gr. Beta 0.54 -0.32 +/- 0.54 3.2 W-102813 Water 10/28/2013 Ra-226 0.02 0.02 +/- 0.01 1 SPW-1908 Water 12/17/2013 Ra-228 0.69 0.55 +/- 0.39 2 CHW-122313 Water 12/23/2013 Gr. Alpha 0.25 -0.09 +/- 0.26 1 CHW-122313 Water 12/23/2013 Gr. Beta 0.48 0.05 +/- 0.53 3.2 CHW-122713 Water 12/27/2013 Gr. Alpha 0.28 0.04 +/- 0.31 1 CHW-122713 Water 12/27/2013 Gr. Beta 0.49 -0.33 +/- 0.53 3.2 Liquid sample results are reported in pCi/Liter, air filters( pCi/M3 ), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).
b 1-131 (G); iodine-131 as analyzed by gamma spectroscopy.
c Activity reported is a net activity result.
A4-2
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance CF-41, 42 1/2/2013 Gr. Beta 8.45 +/- 0.37 7.90 +/- 0.35 8.17 +/- 0.26 Pass.
CF-41, 42 1/2/2013 Sr-90 0.030 +/- 0.015 0.029 +/- 0.014 0.030 +/- 0.010 Pass SWT-8243, 8244 1/2/2013 Gr. Beta 1.07 +/- 0.54 0.98 +/- 0.51 1.03 +/- 0.37 Pass AP-8454, 8455 1/2/2013 Be-7 0.053 +/- 0.010 0.042 +/- 0.010 0.048 +/- 0.007 Pass AP-8517, 8518 1/3/2013 Be-7 0.051 +/- 0.015 0.049 +/- 0.017 0.050 +/- 0.011 Pass MI-62, 63 1/8/2013 K-40 1317.70 +/- 91.70 1351.90 +/- 72.50 1334.80 +/- 58.45 Pass WW-151, 152 1/8/2013 H-3 222.70 +/- 81.00 289.70 +/- 84.10 256.20 +/- 58.38 Pass SG-107, 108 1/11/2013 Ra-226 55.20 +/- 5.53 58.60 +/- 5.94 56.90 +/- 4.06 Pass SG-107, 108 1/11/2013 Ra-228 71.60 +/- 1.10 74.30 +/- 1.70 72.95 +/- 1.01 Pass SG-130, 131 1/14/2013 Ra-226 3.91 +/- 0.20 3.45 +/- 0.27 3.68 +/- 0.17 Pass SG-130, 131 1/14/2013 Ra-228 2.40 +/- 0.33 2.70 +/- 0.39 2.55 +/- 0.26 Pass WW-277, 278 1/17/2013 H-3 159.71 +/- 77.91 196.57 +/- 79.72 178.14 +/- 55.73 Pass WW-256, 257 1/22/2013 H-3 502.70 +/- 93.40 483.30 +/- 92.60 493.00 +/- 65.76 Pass DW-40010, 40011 1/24/2013 Ra-226 2.55 +/- 0.18 2.86 +/- 0.20 2.71 +/- 0.13 Pass DW-40010, 40011 1/24/2013 Ra-228 1.78 +/- 0.62 2.22 +/- 0.62 2.00 +/- 0.44 Pass SWT-361, 362 1/29/2013 Gr. Beta 0.90 +/- 0.40 1.01 +/- 0.38 0.96 +/- 0.28 Pass DW-484, 485 1/29/2013 Gr. Beta 14.85 +/- 1.93 14.81 +/- 2.06 14.83 +/- 1.41 Pass S-945, 946 1/29/2013 Cs-1 37 14.50 +/- 0.18 14.45 +/- 0.19 14.48 +/- 0.13 Pass S-945, 946 1/29/2013 K-40 7.90 +/- 0.74 8.00 +/- 0.73 7.95 +/- 0.52 Pass S-340, 341 1/31/2013 Cs-1 37 0.16 +/- 0.05 0.15 +/- 0.06 0.15 +/- 0.04 Pass S-340, 341 1/31/2013 K-40 17.35 +/- 1.34 19.75 +/- 1.25 18.55 +/- 0.92 Pass AP-463, 464 1/31/2013 Be-7 0.27 +/- 0.10 0.26 +/- 0.10 0.26 +/- 0.07 Pass MI-631, 632 2/13/2013 K-40 1350.50 +/- 105.20 1413.70 +/- 85.94 1382.10 +/- 67.92 Pass WW-769, 770 2/25/2013 Gr. Beta 1.20 +/- 0.33 1.35 +/- 0.34 1.28 +/- 0.24 Pass DW-736, 737 2/26/2013 Gr. Beta 1.09 +/- 0.54 1.57 +/- 0.58 1.33 +/- 0.40 Pass SWU-790, 791 2/26/2013 Gr. Beta 2.68 +/- 0.96 2.08 +/- 0.95 2.38 +/- 0.67 Pass W-925, 926 2/27/2013 H-3 2265.00 +/- 153.00 2329.00 +/- 154.00 2297.00 +/- 108.54 Pass AP-1034, 1035 3/7/2013 Be-7 0.17 +/- 0.08 0.16 +/- 0.09 0.17 +/- 0.06 Pass MI-1076, 1077 3/13/2013 .K-40 1347.70 +/- 99.32 1396.10 +/- 108.00 1371.90 +/- 73.36 Pass CH-1118, 1119 3/14/2013 1-131(G) 109.41 +/- 5.69 103.88 +/- 7.76 106.65 +/- 4.81 Pass WW-1221, 1222 3/1.4/2013 H-3 452.11 +/- 97.43 403.29 +/- 95.46 427.70 +/- 68.20 Pass P-1368, 1369 3/15/2013 H-3 735.24 +/- 113.99 666.04 +/- 111.41 700.64 +/- 79.70 Pass DW-40017, 40018 3/19/2013 Gr. Alpha 1.43 +/- 0.94 1.61 +/- 1.00 1.52 +/- 0.69 Pass MI-1473, 1474 4/1/2013 K-40 1618.00 +/- 107.00 1767.00 +/- 129.00 1692.50 +/- 83.80 Pass AP-2014, 2015 4/1/2013 Be-7 0.055 +/- 0.008 0.057 +/- 0.006 0.056 +/- 0.005 Pass DW-40023, 40024 4/1/2013 Ra-226 2.29 +/- 0.18 2.54 +/- 0.20 2.42 +/- 0.13 Pass DW-40023, 40024 4/1/2013 Ra-228 2.99 +/- 0.69 2.96 +/- 0.67 2.98 +/- 0.48 Pass SWU-736, 737 4/2/2013 Gr. Beta 4.80 +/- 0.95 4.43 +/- 0.86 4.62 +/- 0.64 Pass AP-2035, 2036 4/2/2013 Be-7 0.070 +/- 0.013 0.065 +/- 0.013 0.068 +/- 0.009 Pass BS-1680, 1681 4/8/2013 K-40 1995.30 +/- 265.70 1992.00 +/- 289.40 1993.65 +/- 196.44 Pass SW-1638, 1639 4/9/2013 H-3 1350.77 +/- 130.08 1320.45 +/- 129.25 1335.61 +/- 91.69 Pass A5-1
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance WW-2394,2395 4/9/2013 H-3 348.08 +/- 88.40 302.43 +/- 86.41 325.25 +/- 61.81 Pass DW-40035, 40036 4/12/2013 Ra-226 1.36 +/- 0.15 1.29 +/- 0.13 1.33 +/- 0.10 Pass DW-40035, 40036 4/12/2013 Ra-228 1.22 +/- 0.49 1.38 +/- 0.53 1.30 +/- 0.36 Pass MI-1825, 1826 4/15/2013 K-40 1290.20 +/- 113.80 1378.60 +/- 91.99 1334.40 +/- 73.17 Pass MI-1825, 1826 4/15/2013 Sr-90 0.68 +/-0.32 0.46 +/- 0.31 0.57 +/- 0.22 Pass DW-40049, 40050 4/15/2013 Gr. Alpha 1.88 +/- 0.69 2.51 +/- 0.71 2.20 +/- 0.50 Pass WW-1909, 1910 4/16/2013 H-3 2145.68 +/- 156.65 2108.32 +/- 155.80 2127.00 +/- 110.47 Pass DW-40064, 40065 4/23/2013 Gr. Alpha 1.95 +/- 0.79 1.80 +/- 0.81 1.88 +/- 0.57 Pass DW-40066, 40067 4/23/2013 Ra-226 1.98 +/- 0.17 1.66 +/- 0.16 1.82 +/- 0.12 Pass DW-40066, 40067 4/23/2013 Ra-228 2.30 +/- 0.59 2.32 +/- 0.59 2.31 +/- 0.42 Pass F-2225, 2226 5/1/2013 K-40 2.81 +/- 0.37 2.67 +/- 0.39 2.74 +/- 0.27 Pass BS-2267, 2268 5/1/2013 K-40 13.46 + 0.64 13.59 +/- 0.62 13.52 +/- 0.45 Pass SG-2235, 2236 5/2/2013 Ac-228 18.30 +/- 0.60 18.50 +/- 0.60 18.40 +/- 0.42 Pass SG-2235, 2236 5/2/2013 Gr. Alpha 54.00 +/- 3.70 51.90 +/- 3.40 52.95 +/- 2.51 Pass SG-2235, 2236 5/2/2013 Pb-214 11.30 +/- 0.30 11.20 +/- 0.20 11.25 +/- 0.18 Pass AP-2288, 2289 5/212013 Be-7 0.19 +0.10 0.19 +/- 0.08 0.19 +/- 0.07 Pass WW-3091,3092 5/2/2013 H-3 1107.91 +/- 153.49 1263.37 +/- 157.43 1185.64 +/- 109.94 Pass SW-2373, 2374 5/8/2013 H-3 324.80 + 86.81 364.61 +/- 88.53 344.71 +/- 62.00 Pass W-2352,2353 5/9/2013 Ra-226 0.91 + 0.20 1.29 +/- 0.22 1.10 +/- 0.15 Pass W-2352,2353 5/9/2013 Ra-228 1.28 00.87 1.03 +/- 0.94 1.16 +/- 0.64 Pass CF-2499, 2500 5/13/2013 K-40 11.52 + 0.45 12.55 +/- 0.61 12.04 +/- 0.38 Pass F-3987, 3988 5/20/2013 K-40 3.07 +/- 0.48 3.05 +/- 0.43 3.06 +/- 0.32 Pass BS-4113, 4114 5/20/2013 K-40 8.06 +/- 0.44 7.99 +/- 0.44 8.02 +/- 0.31 Pass SO-2902, 2903 5/22/2013 Th-228 0.57 + 0.07 0.51 +/- 0.06 0.54 +/- 0.05 Pass SO-2902, 2903 5/22/2013 Th-230 0.39 +/- 0.06 0.40 +/- 0.05 0.40 +/- 0.04 Pass SO-2902, 2903 5/22/2013 Th-232 0.55 +/- 0.07 0.62 +/- 0.06 0.59 +/- 0.05 Pass WW-2776, 2777 5/23/2013 H-3 261.76 +/- 100.85 283.17 +/- 101.68 272.46 +/- 71.61 Pass WW-2818, 2819 5123/2013 H-3 999.35 +/- 126.15 880.63 +/- 122.43 939.99 +/- 87.90 Pass S-7271, 7272 5/27/2013 Cs-137 2.82 +/- 0.10 2.91 +/- 0.09 2.86 +/- 0.07 Pass S-7271, 7272 5/27/2013 K-40 21.52 +/- 0.97 21.13 +/- 1.02 21.32 +/- 0.70 Pass P-2923, 2924 5/29/2013 H-3 441.31 +/- 92.75 374.30 +/- 89.94 407.80 +/- 64.60 Pass WW-3133, 3134 6/1/2013 H-3 278.42 +/- 86.54 209.45 +/- 83.44 243.93 +/- 60.11 Pass WW-3049, 3050 6/5/2013 H-3 156.08 +/- 79.16 244.66 +/- 83.86 200.37 +/- 57.66 Pass DW-40079, 40080 6/5/2013 Ra-226 6.67 +/- 0.30 7.03 +/- 0.35 6.85 +/- 0.23 Pass DW-40079, 40080 6/5/2013 Ra-228 5.55 +/- 0.75 6.11 +/- 0.77 5.83 +/- 0.54 Pass DW-40089, 40090 6/5/2013 Gr. Alpha 6.82 +/- 0.90 5.64 +/- 1.02 6.23 +/- 0.68 Pass DW-40091, 40092 6/5/2013 Ra-226 3.44 +/- 0.19 3.66 +/- 0.19 3.55 +/- 0.13 Pass DW-40091, 40092 6/5/2013 Ra-228 3.70 +/- 0.68 4.69 +/- 0.73 4.20 +/- 0.50 Pass DW-40103, 40104 6/5/2013 Ra-226 0.98 +/- 0.22 0.62 +/- 0.15 0.80 +/- 0.13 Pass MI-3154, 3155 6/12/2013 K-40 1513.00 +/- 128.10 1456.70 +/- 110.30 1484.85 +/- 84.52 Pass-P-3385, 3386 6/14/2013 H-3 236.88 +/- 87.87 242.87 +/- 88.14 239.88 +/- 62.23 Pass F-3776, 3777 6/16/2013 Cs-1 37 0.039 +/- 0.015 0.048 +/- 0.019 0.044 +/- 0.012 Pass F-3776, 3777 6/16/2013 Gr. Beta 4.52 +/- 0.09 4.63 +/- 0.09 4.57 +/- 0.06 Pass F-3776, 3777 6/16/2013 K-40 3.40 +/- 0.41 3.52 +/- 0.39 3.46 +/- 0.29 Pass A5-2
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance S-3238, 3239 6/17/2013 Be-7 1139.80 +/- 215.00 1102.00 +/- 194.70 1120.90 +/- 145.03 Pass S-3238, 3239 6/17/2013 Cs-1 34 26.23 +/- 13.23 39.91 +/- 11.73 33.07 +/- 8.84 Pass S-3238, 3239 6/17/2013 Cs-1 37 72.75 +/- 25.99 85.91 +/- 22.58 79.33 +/- 17.21 Pass S-3238, 3239 6/17/2013 K-40 21847.00 +/- 656.50 22158.00 +/- 622.80 22002.50 +/- 452.46 Pass SO-3343, 3344 6117/2013 Cs-137 0.087 +/- 0.022 0.084 +/- 0.017 0.086 +/- 0.014 Pass SO-3343, 3344 6/17/2013 K-40 8.90 +/- 0.53 9.47 +/- 0.49 9.19 +/- 0.36 Pass DW-40118, 40119 6/26/2013 Gr. Alpha 3.56 +/- 1.07 4.51 +/- 0.96 4.04 +/- 0.72 Pass DW-40118, 40119 6/26/2013 Ra-226 2.52 +/- 0.22 2.48 +/- 0.19 2.50 +/- 0.15 Pass DW-40118, 40119 6/26/2013 Ra-228 2.75 +/- 0.71 2.86 +/- 0.75 2.81 +/- 0.52 Pass WW-3583, 3584 6/27/2013 H-3 6732.57 +/- 246.74 6807.94 +/- 247.98 6770.26 +/- 174.91 Pass AP-4092, 4093 6/28/2013 Be-7 0.078 +/- 0.015 0.083 +/- 0.017 0.080 +/- 0.011 Pass E-3608, 3609 7/1/2013 K-40 1.28 +/- 0.13 1.29 +/- 0.11 1.28 +/- 0.09 Pass MI-3629, 3630 7/1/2013 K-40 1840.70 +/- 130.10 1804.90 +/- 143.00 1822.80 +/- 96.66 Pass AP-4050, 4051 7/1/2013 Be-7 0.094 +/- 0.009 0.093 +/- 0.009 0.093 +/- 0.006 Pass DW-40134, 40135 7/1/2013 Ra-226 1.75 +/- 0.15 1.56 +/- 0.15 1.66 +/- 0.11 Pass D.W-40134, 40135 7/1/2013 Ra-228 2.07 +/- 0.60 1.61 +/- 0.57 1.84 +/- 0.41 Pass AP-4071, 4072 7/3/2013 Be-7 0.066 +/- 0.009 0.069 +/- 0.011 0.067 +/- 0.007 Pass DW-40144, 40145 7/9/2013 Gr. Alpha 3.66 +/- 0.85 2.85 +/- 0.79 3.26 +/- 0.58 Pass DW-40146, 40147 7/9/2013 Ra-226 0.70 +/- 0.11 0.72 +/- 0.11 0.71 +/- 0.08 Pass DW-40146, 40147 7/9/2013 Ra-228 1.00 +/- 0.58 0.70 +/- 0.52 0.85 +/- 0.39 Pass VE-3818, 3819 7/9/2013 Be-7 0.41 +/- 0.11 0.46 +/- 0.18 0.43 +/- 0.11 Pass VE-3818, 3819 7/9/2013 K-40 4.67 +/- 0.30 4.52 +/- 0.43 4.60 +/- 0.26 Pass XW-4646, 4647 7/15/2013 H-3 465.00 +/- 111.00 525.00 +/- 114.00 495.00 +/- 79.56 Pass WW-4134, 4135 7/16/2013 H-3 315.86 +/- 123.54 264.98 +/- 121.78 290.42 +/- 86.73 Pass AP-4155, 4156 7/18/2013 Be-7 0.20 +/- 0.11 0.16 +/- 0.09 0.18 +/- 0.07 Pass MI-4218, 4219 7/22/2013 K-40 1426.80 +/- 117.50 1335.70 +/- 110.60 1381.25 +/- 80.68 Pass MI-4218, 4219 7/22/2013 Sr-90 0.62 +/- 0.32 0.67 +/- 0.32 0.65 +/- 0.23 Pass WVV-4239, 4240 7/23/2013 H-3 223.71 +/- 92.64 221.74 +/- 92.56 222.73 +/- 65.48 Pass WW-4394, 4395 7/30/2013 Gr. Alpha 2.63 +/- 1.49 2.57 +/- 1.11 2.60 +/- 0.93 Pass WW-4394, 4395 7/30/2013 Gr. Beta 3.72 +/- 1.17 2.63 +/- 1.29 3.18 +/- 0.87 Pass WW-4394, 4395 7/30/2013 H-3 271.50 +/- 91.30 297.60 +/- 91.50 284.55 +/- 64.63 Pass SWU-4478, 4479 7/30/2013 Gr. Beta 2.07 +/- 0.54 2.24 +/- 0.55 2.16 +/- 0.39 Pass DW-40159, 40160 7/31/2013 Ra-226 3.39 +/- 0.63 2.39 +/- 0.45 2.89 +/- 0.39 Pass DW-40159; 40160 7/31/2013 Ra-228 3.29 +/- 0.73 2.94 +/- 0.68 3.12 +/- 0.50 Pass VE-4436, 4437 8/1/2013 Be-7 0.98 +/- 0.21 0.89 +/- 0.17 0.94 +/- 0.14 Pass VE-4436, 4437 8/1/2013 K-40 3.95 +/- 0.39 3.75 +/- 0.31 3.85 +/- 0.25 Pass G-4457, 4458 8/1/2013 Be-7 0.78 +/- 0.19 0.67 +/- 0.16 0.72 +/- 0.12 Pass G-4457, 4458 8/1/2013 Gr. Beta 6.15 +/- 0.14 6.10 +/- 0.14 6.13 +/- 0.10 Pass G-4457, 4458 8/1/2013 K-40 4.25 +/- 0.36 4.60 +/- 0.41 4.42 +/- 0.27 Pass VE-4520, 4521 8/1/2013 K-40 2.20 +/- 0.16 2.09 +/- 0.17 2.15 +/- 0.12 Pass WVVW-4772, 4773 8/6/2013 H-3 143.80 +/- 86.70 157.80 +/- 87.30 150.80 +/- 61.52 Pass A5-3
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance VE-4709, 4710 8/8/2013 Gr. Beta 31.40 +/- 1.00 30.70 +/- 1.00 31.05 +/- 0.71 Pass VE-4709, 4710 8/8/2013 H-3 1504.00 +/- 132.00 1468.00 +/- 131.00 1486.00 +/- 92.99 Pass VE-4709, 4710 8/8/2013 U-233/4 0.009 +/- 0.002 0.005 +/- 0.002 0.007 +/- 0.001 Pass VE-4709, 4710 8/8/2013 U-238 0.005 +/- 0.002 0.004 +/- 0.001 0.005 +/- 0.001 Pass WW-4562, 4563 8/8/2013 H-3 208.82 +/- 105.55 213.13 +/- 105.73 210.97 +/- 74.70 Pass SG-4651, 4652 8/13/2013 Gr. Alpha 29.00 +/- 3.10 28.80 +/- 3.20 28.90 +/- 2.23 Pass SG-4651, 4652 8/13/2013 Gr. Beta 34.10 +/- 1.80 34.00 +/- 1.80 34.05 +/- 1.27 Pass SG-4651, 4652 8/13/2013 Ra-226 9.00 +/- 0.20 8.70 +/- 0.20 8.85 +/- 0.14 Pass VE-4835, 4836 8/13/2013 K-40 3.01 +/- 0.24 3.08 +/- 0.28 3.04 +/- 0.19 Pass WW-4877, 4878 8/14/2013 H-3 217.35 +/- 87.57 276.63 +/- 90.20 246.99 +/- 62.86 Pass LW-4856, 4857 8/15/2013 Gr. Beta 0.96 +/- 0.40 0.94 +/- 0.38 0.95 +/- 0.28 Pass W-4982, 4983 8/16/2013 H-3 757.43 +/- 112.40 767.56 +/- 112.76 762.50 +/- 79.60 Pass VE-4919, 4920 8/19/2013 K-40 4891.90 +/- 407.90 4907.40 +/- 350.40 4899.65 +/- 268.87 Pass VE-4919, 4920 8/19/2013 Be-7 470.50 +/- 159.60 325.10 +/- 104.10 397.80 +/- 95.27 Pass DW-40184, 40185 8/19/2013 Ra-228 2.35 +/- 0.72 2.53 +/- 0.70 2.44 +/- 0.50 Pass DW-40184, 40185 8/19/2013 Ra-228 1.44 +/- 0.35 2.30 +/- 0.56 1.87 +/- 0.33 Pass AP-5003, 5004 8/22/2013 Be-7 0.23 +/- 0.10 0.21 +/- 0.10 0.22 +/- 0.07 Pass LW-5229, 5230 8/29/2013 Gr. Beta 1.09 +/- 0.86 2.28 +/- 0.96 1.69 +/- 0.64 Pass SS-5333, 5334 9/3/2013 Cs-137 89.20 +/- 41.60 97.80 +/- 34.60 93.50 +/- 27.05 Pass SS-5333, 5334 9/3/2013 K-40 11893.00 +/- 681.30 12353.00 +/- 778.90 12123.00 +/- 517.41 Pass VE-5313, 5314 9/3/2013 K-40 1.84 +/- 0.20 1.85 +/- 0.20 1.85 +/- 0.14 Pass VE-5313, 5314 9/3/2013 Gr. Beta 2.38 +/- 0.04 2.43 +/- 0.04 2.41 +/- 0.03 Pass WW-5617, 5618 9/5/2013 H-3 1987.00 +/- 147.00 2094.00 +/- 150.00 2040.50 +/- 105.01 Pass AP-5355, 5356 9/5/2013 Be-7 0.22 +/- 0.12 0.27 +/- 0.14 0.25 +/- 0.09 Pass XW-5694, 5695 9/8/2013 C-14 0.94 +/- 0.09 0.78 +/- 0.10 0.86 +/- 0.07 Pass VE-5409, 5410 9/9/2013 K-40 3.60 +/- 0.26 3.33 +/- 0.29 3.46 +/- 0.19 Pass AP-5430, 5431 9/12/2013 Be-7 0.26 +/- 0.10 0.26 +/- 0.10 0.26 +/- 0.07 Pass MI-5401, 5402 9/12/2013 K-40 1404.60 +/- 114.10 1356.10 +/- 128.60 1380.35 +/- 85.96 Pass WW-5451, 5452 9/12/2013 H-3 196.66 +/- 84.44 200.78 +/- 84.64 198.72 +/- 59.78 Pass MI-5484, 5485 9/16/2013 K-40 1398.50 +/- 88.93 1364.60 +/- 113.30 1381.55 +/- 72.02 Pass WW-5568, 5569 9/17/2013 H-3 274.69 +/- 87.95 203.72 +/- 84.71 239.20 +/- 61.05 Pass BS-5764, 5765 9/20/2013 Cs-1 37 0.40 +/- 0.03 0.37 +/- 0.02 0.39 +/- 0.02 Pass BS-5764, 5765 9/20/2013 K-40 17.97 +/- 0.59 17.54 +/- 0.55 17.76 +/- 0.40 Pass VE-5638, 5639 9/23/2013 K-40 4.15 +/- 0.33 4.46 +/- 0.38 4.31 +/- 0.25 Pass WWN-5596, 5597 9/23/2013 Gr. Beta 5.97 +/- 1.39 5.95 +/- 1.45 5.96 +/- 1.01 Pass G-5680, 5681 9/25/2013 Be-7 0.36 +/- 0.13 0.35 +/- 0.09 0.35 +/- 0.08 Pass G-5680, 5681 9/25/2013 Gr. Beta 3.81 +/- 0.11 3.77 +/- 0.11 3.79 +/- 0.08 Pass G-5680, 5681 9/25/2013 K-40 3.23 +/- 0.32 2.99 +/- 0.24 3.11 +/- 0.20 Pass S-5659, 5660 9/26/2013 Ac-228 1.19 +/- 0.21 1.06 +/- 0.21 1.13 +/- 0.15 Pass S-5659, 5660 9/26/2013 Cs-1 37 0.13 +/- 0.04 0.14 +/- 0.05 0.14 +/- 0.03 Pass S-5659, 5660 9/26/2013 K-40 16.08 +/- 1.39 16.65 +/- 1.46 16.37 +/- 1.01 Pass S-5659, 5660 9/26/2013 Pb-214 0.97 +/- 0.15 1.10 +/- 0.16 1.04 +/- 0.11 Pass AP-6345, 6346 9/30/2013 Be-7 0.077 +/- 0.010 0.081 +/- 0.008 0.079 +/- 0.006 Pass AP-6366, 6367 9/30/2013 Be-7 0.078 +/- 0.012 0.083 +/- 0.014 0.081 +/- 0.009 Pass A5-4
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance DW-5701, 5702 9/30/2013 Gr. Beta 14.48 +/- 2.04 13.32 +/- 1.84 13.90 +/- 1.37 Pass SG-5722, 5723 9/30/2013 Ra-226 12.41 +/- 0.47 11.98 +/- 0.59 12.20 +/- 0.38 Pass SG-5722, 5723 9/30/2013 Ra-228 7.84 +/- 0.71 8.13 +/- 0.97 7.99 +/- 0.60 Pass G-5806, 5807 10/1/2013 Be-7 3.26 +/- 0.30 3.11 +/- 0.13 3.19 +/- 0.16 Pass G-5806, 5807 10/1/2013 K-40 6.65 +/-0.21 6.68 +/- 0.50 6.67 +/- 0.27 Pass SG-5827, 5828 10/1/2013 Ac-228 4.08 +/- 0.33 3.92 +/- 0.40 4.00 +/- 0.26 Pass SG-5827, 5828 10/1/2013 K-40 2.55 +/- 0.65 2.37 +/- 0.63 2.46 +/- 0.45 Pass SG-5827, 5828 10/1/2013 Pb-214 3.82 +/- 0.17 3.93 +/- 0.20 3.88 +/- 0.13 Pass VE-5848, 5849 10/1/2013 K-40 1.62 +/- 0.16 1.57 +/- 0.14 1.60 +0.11 Pass AP-6408, 6409 10/3/2013 Be-7 0.072 +/- 0.015 0.063 +/- 0.012 0.068 +/- 0.010 Pass f-5954, 5955 10/3/2013 K-40 2.74 +/- 0.36 .3.02 +/- 0.34 2.88 + 0.25 Pass P-6035, 6036 10/7/2013 H-3 198.41 +/- 85.00 288.60 +/- 89.15 243.51 +/- 61.59 Pass SG-6115, 6116 10/8/2013 Ac-228 5.22 +/- 0.50 4.87 +/- 0.48 5.05 +/- 0.35 Pass SG-6115, 6116 10/8/2013 K-40 5.61 +/- 1.08 6.61 +/- 1.04 6.11 +/-0.75 Pass
,SG-6115, 6116 10/8/2013 Pb-214 4.29 +/- 0.24 4.24 +/- 0.20 4.27 +/- 0.16 Pass VE-6136, 6137 10/8/2013 Be-7 0.55 +/- 0.18 0.60 +/- 0.15 0.58 +/-0.12 Pass VE-6136, 6137 10/8/2013 K-40 2.78 +/- 0.35 2.61 +/- 0.33 2.69 +/- 0.24 Pass WW-6198, 6199 10/8/2013 H-3 12973.70 +/- 332.60 12757.80 +/- 330.00 12865.75 +/- 234.27 Pass VE-6240, 6241 10/9/2013 K-40 14.29 +/- 0.29 14.95 +/- 0.54 14.62 +/- 0.31 Pass W-5996, 5997 10/9/2013 Gr. Alpha 3.87 +/- 1.18 4.07 +/- 1.08 3.97 +/- 0.80 Pass W-5996, 5997 10/9/2013 Gr. Beta 9.82 +/- 0.85 8.53 +/- 0.82 9.18 +/- 0.59 Pass W-5996, 5997 10/9/2013 Ra-228 3.42 +/- 1.02 3.39 +/- 1.01 3.41 +/- 0.72 Pass DW-40224, 40225 10/11/2013 Ra-226 0.62 +/- 0.10 0.76 +/- 0.10 0.69 +/- 0.07 Pass DW-40224, 40225 10/11/2013 Ra-228 0.87 +/- 0.55 1.00 +/- 0.54 0.94 +/- 0.39 Pass WW-6219, 6220 10/11/2013 H-3 455.41 +/- 111.54 354.66 +/- 107.84 405.03 +/- 77.57 Pass CF-6261, 6262 10/14/2013 Be-7 1.97 +/- 0.24 2.06 +/- 0.22 2.01 +/- 0.16 Pass CF-6261, 6262 10/14/2013 K-40 11.55 +/- 0.56 12.06 +/- 0.61 11.80 +/- 0.41 Pass MI-6303, 6304 10/14/2013 K-40 1507.30 +/- 110.80 1482.40 +/- 110.00 1494.85 +/- 78.07 Pass VE-6534, 6535 10/17/2013 K-40 15.96 +/- 0.17 16.16 +/- 0.36 16.06 +/- 0.20 Pass S-6471, 6472 10/18/2013 Ac-228 0.94 +/- 0.19 0.78 +/- 0.18 0.86 +/- 0.13 Pass S-6471, 6472 10/18/2013 K-40 12.82 +/- 1.05 12.90 +/- 1.17 12.86 +/- 0.79 Pass S-6471, 6472 10/18/2013 Pb-214 0.88 +/- 0.11 0.72 +/- 0.12 0.80 +/- 0.08 Pass VE-6597, 6598 10/22/2013 K-40 2.46 +/- 0.22 2.58 +/- 0.20 2.52 +/- 0.15 Pass WW-6576, 6577 10/22/2013 H-3 745.60 +/- 110.70 663.30 +/- 107.60 704.45 +/- 77.19 Pass LW-6681, 6682 10/29/2013 Gr. Beta 2.00 +/- 0.92 2.17 +/- 0.98 2.09 +/- 0.67 Pass SWU-6765, 6766 10/29/2013 Gr. Beta 3.07 +/- 0.61 2.90 +/- 0.65 2.99 +/- 0.45 Pass WW-6849, 6850 10/29/2013 H-3 863.00 +/- 113.80 826.60 +/- 112.50 844.80 +/- 80.01 Pass MI-6786, 6787 10/30/2013 K-40 1370.60 +/- 109.60 1449.20 +/- 105.50 1409.90 +/- 76.06 Pass SO-6744, 6745 10/30/2013 Ac-228 0.46 +/- 0.11 0.51 +/- 0.11 0.48 +/- 0.08 Pass SO-6744, 6745 10/30/2013 Bi-214 0.48 +/- 0.10 0.30 +/- 0.10 0.39+/- 0.07 Pass SO-6744, 6745 10/30/2013 Cs-1 37 0.21 +/- 0.04 0.24 +/- 0.04 0.23 +/- 0.03 Pass SO-6744, 6745 10/30/2013 Gr. Beta 27.40 +/- 1.14 27.44 +/- 1.11 27.42 +/- 0.80 Pass SO-6744, 6745 10/30/2013 K-40 14.93 +/- 0.88 15.20 +/- 0.90 15.07 +/- 0.63 Pass SO-6744, 6745 10/30/2013 Pb-212 0.43 +/- 0.04 0.40 +/- 0.05 0.42 +/- 0.03 Pass SO-6744, 6745 10/30/2013 Ra-226 1.47 +/- 0.35 1.31 +/- 0.36 1.39 +/- 0.25 Pass SO-6744, 6745 10/30/2013 TI-208 0.16 +/- 0.04 0.16 +/- 0.04 0.16 +/- 0.03 Pass A5-5
TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance DW-40238, 40239 10/31/2013 Ra-228 0.94 +/- 0.41 1.60 +/- 0.55 1.27 +/- 0.34 Pass WW-7018, 7019 -11/1/2013 H-3 593.09 +/- 104.72 648.69 +/- 106.89 620.89 +/- 74.82 Pass CF-6870, 6871 11/4/2013 K-40 12.67 +/- 0.49 13.30 +/- 0.47 12.98 +/- 0.34 Pass XW-6828, 6829 11/4/2013 K-40 97.99 +/- 55.33 160.21 +/- 74.99 129.10 +/- 46.60 Pass BS-6891, 6892 11/5/2013 Cs-137 0.018 +/- 0.010 0.018 +/- 0.009 0.018 +/- 0.007 Pass BS-6891, 6892 11/5/2013 Gr. Beta 12.41 +/- 1.74 9.97 +/- 1.57 11.19 +/- 1.17 Pass BS-6891, 6892 11/5/2013 K-40 6.49 +/- 0.33 6.28 +/- 0.40 6.39 +/- 0.26 Pass WW-6912, 6913 11/5/2013 Gr. Alpha 2.87 +/- 1.30 4.46 +/- 1.47 3.67 +/- 0.98 Pass WW-6912, 6913 11/5/2013 Gr. Beta 3.18 +/- 0.87 3.18 +/- 0.87 3.18 +/- 0.62 Pass WW-6912, 6913 11/5/2013 H-3 349.01 +/- 101.42 430.14 +/- 98.06 389.58 +/- 70.54 Pass SO-6954, 6955 11/6/2013 Cs-137 0.14 +/- 0.03 0.12 +/- 0.02 0.13 +/- 0.02 Pass SO-6954, 6955 11/6/2013 K-40 15.16 +/- 0.72 14.11 +/- 0.64 14.64 +/- 0.48 Pass S-6976, 6977 11/13/2013 K-40 22.36 +/- 0.69 22.62 +/- 0.72 22.49 +/- 0.50 Pass DW-40246, 40247 11/15/2013 Gr. Alpha 15.00 +/- 3.41 20.31 +/- 4.00 17.65 +/- 2.63 Pass CF-7102, 7103 11/18/2013 Be-7 17.79 +/- 0.51 18.09 +/- 0.80 17.94 +/- 0.48 Pass DW-40250, 40251 11/18/2013 Ra-226 27.77 +/- 2.84 26.15 +/- 2.67 26.96 +/- 1.95 Pass DW-40250, 40251 11/18/2013 Ra-228 7.91 +/- 0.94 6.32 +/- 0.84 7.12 +/- 0.63 Pass WW-7164, 7165 11/19/2013 H-3 266.90 +/- 91.10 268.90 +/- 91.20 267.90 +/- 64.45 Pass SS-7334, 7335 11/20/2013 K-40 15.51 +/- 0.72 14.14 +/- 0.80 14.83 +/- 0.54 Pass WW-7558, 7559 11/22/2013 H-3 229.86 +/- 83.89 191.77 +/- 82.05 210.82 +/- 58.67 Pass LW-7292, 7293 11/26/2013 Gr. Beta 1.92 +/- 0.75 2.38 +/- 0.77 2.15 +/- 0.54 Pass W-7229, 7230 12/1/2013 Ra-226 0.87 +/- 0.23 0.88 +/- 0.25 0.88 +/- 0.17 Pass W-7229, 7230 12/1/2013 Ra-228 3.00 +/- 0.98 3.27 +/- 1.16 3.14 +/- 0.76 Pass SG-7313, 7314 12/2/2013 Ac-228 6.33 +/- 0.23 6.69 +/- 0.30 6.51 +/- 0.19 Pass SG-7313, 7314 12/2/2013 K-40 5.47 +/- 0.61 6.24 +/- 0.74 5.86 +/- 0.48 Pass SG-7313, 7314 12/2/2013 Pb-214 5.60 +/- 0.14 5.37 +/- 0.16 5.49 +/- 0.11 Pass W-7432, 7433 12/4/2013 Gr. Beta 5.35 +/- 1.20 3.89 +/- 1.23 4.62 +/- 0.86 Pass WW-7516, 7517 12/10/2013 H-3 369.30 +/- 95.64 269.22 +/- 91.35 319.26 +/- 66.13 Pass SG-7579, 7580 12/20/2013 Ra-226 3.72 +/- 0.11 3.85 +/- 0.30 3.79 +/- 0.16 Pass SG-7579, 7580 12/20/2013 Ra-228 2.38 +/- 0.18 2.77 +/- 0.44 2.58 +/- 0.24 Pass LW-7684, 7685 12/23/2013 Gr. Beta 0.84 +/- 0.51 1.96 +/- 0.61 1.40 +/- 0.40 Pass DW-40261, 40262 12/27/2013 Ra-226 0.54 +/- 0.10 0.67 +/- 0.10 0.61 +/- 0.07 Pass DW-40261, 40262 12/27/2013 Ra-228 1.09 +/- 0.51 1.12 +/- 0.43 1.11 +/- 0.33 Pass SWU-7663, 7664 12/30/2013 Gr. Beta 2.85 +/- 0.71 3.88 +/- 0.77 3.37 +/- 0.52 Pass Note: Duplicate analyses are performed on every twentieth sample received in-house. Results are not listed for those analyses with activities that measure below the LLD.
a Results are reported in units of pCi/L, except for air filters (pCi/Filter), food products, vegetation, soil, sediment (pCi/g).
A5-6
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP).
Concentration a Known Control Lab Code b Date Analysis Laboratory result Activity Limits c Acceptance MAAP-738 02/01/13 Am-241 0.10 +/- 0.02 0.10 0.07 -0.14 Pass MAAP-738 02/01/13 Co-57 2.58 +/- 0.06 2.36 1.65-3.07 Pass MAAP-738 02/01/13 Co-60 0.01 +/- 0.03 0.00 NA r Pass MAAP-738 02/01/13 Cs-134 1.82 +/- 0.13 1.78 1.25 - 2.31 Pass MAAP-738 02/01/13 Cs-137 2.93 +/- 0.10 2.60 1.82 -3.38 Pass MAAP-738 02/01/13 Mn-54 4.87 +/- 0.13 4.26 2.98 - 5.54 Pass MAAP-738 02/01/13 Pu-238 0.12 +/- 0.02 0.13 0.09 -0.17 Pass MAAP-738 02/01/13 Pu-239/40 0.11 +/- 0.02 0.12 0.09 -0.16 Pass MAAP-738 02/01/13 Sr-90 1.39 +/- 0.14 1.49 1.04-1.94 Pass MAAP-738 02/01/13 U-233/4 0.03 +/- 0.01 0.03 0.02 - 0.04 Pass MAAP-738 02/01/13 U-238 0.23 +/- 0.03 0.23 0.16 - 0.30 Pass MAAP-738 02/01/13 "Zn-65 3.84 +/- 0.20 3.13 2.19 -4.07 Pass MAAP-738 e 02/01/13 Gr. Alpha 0.14 +/- 0.03 1.20 0.36 - 2.04 Fail MAAP-738 02/01/13 Gr. Beta 0.93 +/- 0.06 0.85 0.43 - 1.28 Pass MAW-806 02/01/13 Am-241 0.71 +/- 0.08 0.69 0.48 - 0.90 Pass MAW-806 02/01/13 Co-57 31.20 +/- 0.40 30.90 21.&0 -40.20 Pass MAW-806 02/01/13 Co-60 19.70 +/- 0.30 16.56 13.69 - 25.43 Pass MAW-806 02/01/13 Cs-134 23.20 +/- 0.50 24.40 17.10 - 31.70 Pass MAW-806 02/01/13 Cs-137 0.03 +/- 0.12 0.00 NA Pass MAW-806 02/01/13 Fe-55 34.00 +/- 3.30 44.00 30.80 - 57.20 Pass MAW-806 02/01/13 H-3 511.60 +/- 12.50 507.00 355.00 - 659.00 Pass MAW-806 02/01/13 K-40 2.20 +/- 0.90 0.00 NA - Pass MAW-806 02/01/13 Mn-54 27.60 +/- 0.50 27.40 19.20 - 35.60 Pass MAW-806' 02/01/13 Ni-63 34.30 +/- 2.80 33.40 23.40 - 43.40 Pass MAW-806 02/01/13 Pu-238 0.83 +/- 0.10 0.88 0.62-1.15 Pass MAW-806 02/01/13 Pu-239/40 0.02 +/- 0.02 0.01 NA d Pass MAW-806 02/01/13 Sr-90 9.30 +/- 0.80 10.50 7.40 - 13.70 Pass MAW-806 02/01/13 Tc-99 10.25 +/- 0.40 13.10 9.20 - 17.00 Pass MAW-806 02/01/13 U-233/4 0.31 +/- 0.05 0.32 0.22 - 0.41 Pass MAW-806 02/01/13 U-238 1.91 +/- 0.13 1.95 1.37 -2.54 Pass MAW-806 02/01/13 Zn-65 31.60 +/- 0.80 30.40 21.30 -39.50 Pass MAW-811 02/01/13 Gr. Alpha 1.87 +/- 0.09 2.31 0.69 - 3.93 Pass MAW-811 02/01/13 Gr. Beta 13.04 +/- 0.13 13.00 6.50 - 19.50 Pass MAW-811 02/01/13 1-129 4.60 +/- 0.19 6.06 4.24 - 7.88 Pass A6-1
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP).
a Concentration Known Control Lab Code b Date Analysis Laboratory result Activity Limits C Acceptance MASO-739 02/01/13 Am-241 106.90 +/- 11.40 113.00 79.00 - 147.00 Pass MASO-739 02/01/13 Co-57 0.60 +/- 0.50 0.00 NA c Pass MASO-739 02/01/13 Co-60 739.20 +/- 28.50 691.00 484.00 - 898.00 Pass MASO-739 02/01/13 Cs-1 34 863.30 +/- 34.10 887.00 621.00 -1153.00 Pass MASO-739 02/01/13 Cs-1 37 661.80 +/- 25.70 587.00 411.00 -763.00 Pass MASO-739 02/01/13 K-40 745.80 +/- 33.30 625.30 437.70 - 812.90 Pass MASO-739 02/01/13 Mn-54 1.10 +/- 1.00 0.00 NA c Pass MASO-739 02/01/13 Zn-65 1109.60 +/- 44.10 995.00 697.00 - 1294.00 Pass MASO-744 02/01/13 Ni-63 682.60 +/- 16.80 670.00 469.00 -871.00 Pass MASO-744 02/01/13 Pu-238 0.20 +/- 0.90 0.52 NA d Pass MASO-744 02/01/13 Pu-239/40 88.30 +/- 9.00 79.50 55.70 -103.40 Pass MASO-744 f 02/01/13 Sr-90 408.40 +/- 14.00 628.00 440.00 -816.00 Fail MASO-744 02/01/13 Tc-99 380.50 +/- 16.80 444.00 311.00 -577.00 Pass MASO-744 02/01/13 U-233/4 53.20 +/- 4.80 62.50 43.80 -81.30 Pass MASO-744 02/01/13 U-238 242.10 +/- 10.20 281.00 197.00 -365.00 Pass MAVE-747 02/01/13 Co-57 10.37 +/- 0.17 8.68 6.08 -11.28 Pass MAVE-747 02/01/13 Co-60 6.48 +/- 0.17 5.85 4.10 -7.61 Pass MAVE-747 02/01/13 Cs-1 34 0.02 +/- 0.04 0.00 NA c Pass MAVE-747 02/01/13 Cs-1 37 7.79 +/- 0.21 6.87 4.81 -8.93 Pass MAVE-747 02/01/13 Mn-54 0.00 +/- 0.05 0.00 NA' Pass MAVE-747 02/01/13 Zn-65 7.29 +/- 0.33 6.25 4.38 -8.13 Pass MASO-5043 08/01/13 Am-241 1.40 +/- 1.70 0.00 NA' Pass MASO-5043 g 08/01/13 Co-57 699.60 +/- 3.90 0.00 NA 0 Fail MASO-5043 08/01/13 Cs-1 34 1191.70 +/- 23.00 1172.00 820.00 -1524.00 Pass MASO-5043 08/01/13 Cs-1 37 1072.00 +/- 5.10 977.00 684.00 - 1270.00 Pass MASO-5043 08/01/13 K-40 760.00 +/- 16.20 633.00 443.00 -823.00 Pass MASO-5043 08/01/13 Mn-54 753.80 +/- 4.90 674.00 472.00 -876.00 Pass MASO-5043 08/01/13 Ni-63 560.00 +/- 23.70 571.00 400.00 - 742.00 Pass MASO-5043 08/01/13 Pu-238 68.40 +/- 7.50 61.50 43.10 -80.00 Pass MASO-5043 08/01/13 Pu-239/40 0.40 +/- 0.80 0.36 NA d Pass MASO-5043 08/01/13 Sr-90 383.90 +/- 14.50 460.00 322.00 - 598.00 Pass MASO-5043 08/01/13 Tc-99 -1.00 +/- 10.50 0.00 NA c Pass MASO-5043 08/01/13 U-233/4 23.80 +/- 3.30 30.00 21.00 - 39.00 Pass MASO-5043 08/01/13 U-238 26.80 +/- 3.50 34.00 23.80 - 44.20 Pass MASO-5043 08/01/13 Zn-65 -351.50 +/- 5.50 0.00 NAc Pass A6-2
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP).
Concentration 2 Known Control Lab Code b Date Analysis Laboratory result Activity Limits c Acceptance MAW-5052 08/01/13 1-129 2.75 +/- 0.20 3.79 2.65 -4.93 Pass MAW-5094 08/01/13 Am-241 0.00 +/- 0.01 0.00 NA c Pass MAW-5094 08/01/13 Co-57 0.01 +/- 0.09 0.00 NAC Pass MAW-5094 08/01/13 Co-60 23.20 +/- 0.32 23.58 16.51 - 30.65 Pass MAW-5094 08/01/13 Cs-134 27.60 +/- 0.58 30.40 21.00 - 39.00 Pass MAW-5094 08/01/13 Cs-137 32.31 +/- 0.52 31.60 22.10 - 41.10 Pass MAW-5094 08/01/13 Fe-55 39.20 +/- 3.50 53.30 37.30 - 69.30 Pass MAW-5094 08/01/13 Gr. Alpha 0.54 +/- 0.05 0.70 0.21 - 1.19 Pass MAW-5094 08/01/13 Gr. Beta 5.85 +/- 0.09 5.94 2.97 -8.91 Pass MAW-5094 08/01/13 H-3 1.20 +/- 3.00 0.00 NA c Pass MAW-5094 08/01/13 K-40 2.22 +/- 0.90 0.00 NA c Pass MAW-5094 08/01/13 Mn-54 0.01 +/- 0.11 0.00 NA c Pass MAW-5094 08/01/13 Ni-63 21.80 +/- 3.30 26.40 18.50 - 34.30 Pass MAW-5094 08/01/13 Pu-238 1.30 +/- 0.11 1.22 0.85 -1.58 Pass MAW-5094 08/01/13 Pu-239/40 0.98 +/- 0.09 1.00 0.70 - 1.30 Pass MAW-5094 08/01/13 Sr-90 6.40 +/- 0.60 7.22 5.05 -9.39 Pass MAW-5094 08/01/13 Tc-99 13.10 +/- 0.70 16.20 11.30 - 21.10 Pass MAW-5094 08/01/13 U-233/4 0.08 +/- 0.02 0.07 NA d Pass MA\N-5094 08/01/13 U-238 0.03 +/- 0.01 0.03 NA d Pass MAW-5094 08/01/13 Zn-65 35.30 +/- 0.90 34.60 24.20 - 45.00 Pass MAVE-5046 08/01/13 Co-57 0.01 +/- 0.03 0.00 NA c Pass MAVE-5046 08/01/13 Co-60 0.00 +/- 0.04 0.00 NA c Pass MAVE-5046 08/01/13 Cs-134 5.71 +/- 0.23 5.20 3.64 -6.76 Pass MAVE-5046 08/01/13 Cs-137 7.64 +/- 0.20 6.60 4.62 -8.58 Pass MAVE-5046 08/01/13 Mn-54 9.08 +/- 0.24 7.88 5.52 - 10.24 Pass MAVE-5046 08/01/13 Zn-65 2.92 +/- 0.25 2.63 1.84 -3.42 Pass A6-3
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP).
Concentration a Known Control Lab Code b Date Analysis Laboratory result Activity Limits c Acceptance MAAP-5046 08/01/13 Am-241 0.01
- 0.02 0.00 NA c Pass MAAP-5046 08/01/13 Co-57 3.48 +/- 0.14 3.40 1.90 -3.50 Pass MAAP-5046 08/01/13 Co-60 2.44 +/- 0.08 3.40 1.60 -3.00 Pass MAAP-5046 08/01/13 Cs-134 0.01 +/- 0.03 0.00 NA c Pass MAAP-5046 08/01/13 Cs-137 3.09 +/- 0.13 2.70 .1.90 -3.50 Pass MAAP-5046 08/01/13 Gr. Alpha 0.28 +/- 0.04 0.90 0.27 - 1.53 Pass MAAP-5046 08/01/13 Gr. Beta 1.90 +/- 0.08 1.63 0.82 -2.45 Pass MAAP-5046 08/01/13 Mn-54 3.95 +/- 0.12 3.50 2.50 -4.60 Pass MAAP-5046 08/01/13 Pu-238 0.14 +/- 0.028 0.12 0.087 -0.16 Pass MAAP-5046 08/01/13 Pu-239/40 0.10 +/- 0.022 0.092 0.064 - 0.12 Pass MAAP-5046 08/01/13 Sr-90 1.69 +/- 4.10 1.81 1.27 -2.35 Pass MAAP-5046 h 08/01/13 U-233/4 0.04 +/- 0.01 0.03 0.02 -0.04 Fail MAAP-5046 08/01/13 U-238 0.19 +/- 0.027 0.21 0.14 -0.27 Pass MAAP-5046 08/01/13 Zn-65 3.27 +/- 0.18 2.70 2.50 -4.60 Pass Results are reported in units of Bq/kg (soil), Bq/L (water) or Bq/total sample (filters, vegetation).
bLaboratory codes as follows: MAW (water), MAAP (air filter), MASO (soil), MAVE (vegetation).
c MAPEP results are presented as the known values and expected laboratory precision (1 sigma, 1 determination) and control limits as defined by the MAPEP. A known value of "zero" indicates an analysis was included in the testing series as a "false positive". MAPEP does not provide control limits.
d Provided in the series for "sensitivity evaluation". MAPEP does not provide control limits.
e'The filter was recounted ovemight, no significant alpha activity could be detected.
fThe sample was reanalyzed using additional fuming nitric separations. Result of reanalysis: 574.4 +/- 35.2 Bq/kg.
g Interference from Eu-1 52 resulted in misidentification of Co-57.
h Result of repeat analysis: 0.031 +/- 0.013 pCi/filter.
A6-4
TABLE A-7. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.
Concentration (pCi/L) b Lab Code b Date Analysis Laboratory ERA Control Result c Result d Limits Acceptance ERAP-1 174 03/18/13 Am-241 65.2 +/- 4.4 66.8 41.2 -90.4 Pass ERAP-1 174 03/18/13 Co-60 226.5 +/- 4.1 214.0 166.0 - 267.0 Pass ERAP-1 174 03/18/13 Cs-I 34 1101.2-+/- 23.6 1110.0 706.0 - 1380.0 Pass ERAP-1174 03/18/13 Cs-1 37 1065.6 +/- 21.4 940.0 706.0 - 1230.0 Pass ERAP-1174 03/18/13 Fe-55 178.8 +/- 88.0 225.0 69.8 - 440.0 Pass ERAP-1 174 03/18/13 Mn-54 <3.1 0.0 0.0 - 50.0 Pass ERAP-1 174 03/18/13 Pu-238 50.0 +/- 3.0 51.1 34.3 - 65.9 Pass ERAP-1 174 03/18/13 Pu-239/40 65.7 +/- 2.6 65.2 47.2 - 85.2 Pass ERAP-1 174 03/18/13 U-233/4 54.0 +/- 2.5 59.4 36.8 - 89.6 Pass ERAP-1 174 03/18/13 U-238 55.6 +/- 2.6 58.9 38.1 -81.4 Pass ERAP-1 174 03/18/13 Uranium 112.0 +/-5.6 121.0 67.0 - 184.0 Pass ERAP-1 174 03/18/13 Zn-65 236.6 +/- 13.8 199.0 142.0 - 275.0 Pass ERAP-1175 03/18/13 Gr. Alpha 52.3 +/- 2.8 42.3 14.2 - 65.7 Pass ERAP-1175 03/18/13 Gir. Beta 36.2 +/- 2.0 25.1 15.9 -36.6 Pass ERSO-1 176 03/18/13 Am-241 293.1 +/- 97.4 229.0 134.0 - 297.0 Pass ERSO-1 176 03/18/13 Pu-238 909.0 +/- 180.0 788.0 474.0 - 1090.0 Pass ERSO-1 176 03/18/13 Pu-239/40 432.0 +/- 120.0 366.0 239.0 - 506.0 Pass ERSO-1 176 03/18/13 Sr-90 8050.8 +/- 376.0 8530.0 3250.0 - 13500.0 Pass ERSO-1 176 03/18/13 U-233/4 1662.6 +/- 150.0 1920.0 1170.0 - 2460.0 Pass ERSO-1 176 03/18/13 U-238 1682.8 +/- 160.0 1900.0 1180.0 - 2410.0 Pass ERSO-1176 03/18/13 Uranium 3404.0 +/- 330.5 3920.0 2130.0 - 5170.0 Pass ERSO-1 176 03/18/13 Ac-228 1335.0 +/- 132.0 1240.0 795.0 - 1720.0 Pass ERSO-1 176 03/18/13 Bi-212 1420.0 +/- 311.0 1240.0 330.0 - 1820.0 Pass ERSO-1 176 03/18/13 Bi-214 2626.0 +/- 60.0 3660.0 2200.0 - 5270.0 Pass ERSO-1 176 03/18/13 Co-60 7951.0 +/- 45.4 7920.0 5360.0 - 10900.0 Pass ERSO-1 176 03/18/13 Cs-1 34 5785.0 +/- 51.0 6370.0 4160.0 - 7650.0 Pass ERSO-1 176 03/18/13 Cs-1 37 6106.0 +/- 47.9 6120.0 4690.0 - 7870.0 Pass ERSO-1 176 03/18/13 K-40 11756.0 +/- 284.3 10300.0 7520.0 - 13800.0 Pass ERSO-1 176 03/18/13 Mn-54 < 28.0 0.0 0.0 - 1000.0 Pass ERSO-1 176 03/18/13 Pb-212 1096.0 +/- 29.1 1240.0 812.0 - 1730.0 Pass ERSO-1 176 03/18/13 Pb-214 2875.0 +/- 60.0 3660.0 2140.0 - 5460.0 Pass ERSO-1 176 03/18/13 Th-234 2404.0 +/- 218.3 1900.0 601.0 - 3570.0 Pass ERSO-1 176 03/18/13 Zn-65 1542.0 +/- 56.4 1400.0 1110.0 - 1860.0 Pass A7-1
TABLE A-7. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.
Concentration (pCi/L) b Lab Code b Date Analysis Laboratory ERA Control Result c Result d Limits Acceptance ERVE-1 180 03/18/13 Am-241 569.8 +/- 81.7 553.0 338.0 - 735.0 Pass ERVE-1 180 03/18/13 Cm-244 1260.9 +/- 107.3 1340.0 657.0 -2090.0 Pass ERVE-1 180 03/18/13 Co-60 2130.5 +/- 48.0 1920.0 1320.0 -2680.0 Pass ERVE-1 180 03/18/13 Cs-134 1296.5 +/- 68.0 1240.0 797.0 - 1610.0 Pass ERVE-1 180 03/18/13 Cs-137 600.1 +/- 34.3 544.0 394.0 - 757.0 Pass ERVE-1 180 03/18/13 K-40 34078.0 +/- 787.0 31900.0 23000.0 -44800.0 Pass ERVE-1 180 03/18/13 Mn-54 < 28.7 0.0 0.0 - 300.0 Pass ERVE-1 180 03/18/13 Pu-238 2476.5 +/- 259.4 1980.0 1180.0 -2710.0 Pass ERVE-1 180 03/18/13 Pu-239/40 2659.3 +/- 273.2 2260.0 1390.0 - 3110.0 Pass ERVE-1 180 03/18/13 Sr-90 3809.7 +/- 420.5 3840.0 2190.0 - 5090.0 Pass ERVE-1 180 03/18/13 U-233/4 2460.6 +/- 205.0 2460.0 1620.0 - 3160.0 Pass ERVE-1 180 03/18/13 U-238 2319.1 +/- 189.6 2440.0 1630.0 - 3100.0 Pass ERVE-1 180 03/18/13 Uranium 4866.3 +/- 375.6 5010.0 3390.0 - 6230.0 Pass ERVE-1 180 03/18/13 Zn-65 1052.5 +/- 82.1 878.0 633.0 - 1230.0 Pass ERW-1184 03/18/13 Am-241 114.5 +/-8.1 118.0 79.5 -158.0 Pass ERW-1184 03/18/13 Co-60 2221.8 +/- 17.0 2270.0 1970.0 -2660.0 Pass ERW-1184 03/18/13 Cs-134 1309.4 +/- 58.4 .1400.0 1030.0 - 1610.0 Pass ERW-1184 03/18/13 Cs-1 37 1865.9 +/- 22.0 1880.0 1600.0 -2250.0 Pass ERW-1184 03/18/13 Fe-55 503.1 +/- 105.0 712.0 424.0 -966:0 Pass ERW-1 184 03/18/13 Mn-54 < 9.4 0.0 0.0 - 100.0 Pass ERW-1184 03/18/13 Pu-238 98.4 +/- 5.6 98.8 73.1 - 123.0 Pass ERW-1184 03/18/13 Pu-239/40 184.5 +/- 7.7 185.0 144.0 - 233.0 Pass ERW-1 184 03/18/13 Sr-90 125.7 +/-6.0 137.0 89.2 - 181.0 Pass ERW-1184 03/18/13 U-233/4 44.9 +/- 3.4 48.8 36.7 - 62.9 Pass ERW-1 184 03/18/13 U-238 46.5 +/- 3.5 48.4 36.9 - 59.4 Pass ERW-1184 03/18/13 Uranium 93.3 +/- 7.1 99.5 73.1 - 129.0 Pass ERW-1184 03/18/13 Zn-65 412.8 +/- 32.0 384.0 320.0 - 484.0 Pass ERW-1186 03/18/13 Gr. Alpha 109.1 +/- 5.7 130.0 46.2 -201.0 Pass ERW-1186 03/18/13 Gr. Beta 74.5 +/- 6.4 78.9 45.2 -117.0 Pass ERW-1188 03/18/13 H-3 12279.0 +/- 319.0 12300.0 8240.0 - 17500.0 Pass a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency testing administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the Environmental Measurements Laboratory Quality Assessment Program (EML).
b Laboratory codes as follows: ERW (water), ERAP (air filter), ERSO (soil), ERVE (vegetation). Results are reported in units of pCi/L, except for air filters (pCi/Filter), vegetation and soil (pCi/kg).
c Unless otherwise indicated, the laboratory result is given as the mean +/- standard deviation for three determinations.
d Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits as provided by ERA. A known value of "zero" indicates an analysis was included in the testing series as a "false positive". Control limits are not provided.
A7-2
APPENDIX B. DATA REPORTING CONVENTIONS Data Reporting Conventions 1.0. All activities, except gross alpha and gross beta, are decay corrected to collection time or the end of the collection period.
1.0. Single Measurements Each single measurement is reported as follows: x+/- s where: x = value of the measurement; s = 2a counting uncertainty (corresponding to the 95% confidence level).
In cases where the activity is less than the lower limit of detection L, it is reported as: < L, where L = the lower limit of detection based on 4.66a uncertainty for a background sample.
3.0. Duplicate analyses If duplicate analyses are reported, the convention is as follows.
3.1 Individual results: For two analysis results; x1 +/- si and x2 +/- s 2 Reported result: x +/- s; where x = (1/2) (x1 + x2) and s = (1/2) + s+
3.2. Individual results: < L1 , < L2 Reported result: < L, where L = lower of Li and L2 3.3. Individual results: x +/- s, < L Reported result: x +/- s if x > L; < L otherwise.
4.0. Computation of Averages and Standard Deviations 4.1 Averages and standard deviations listed in the tables are computed from all of the individual measurements over the period averaged; for example, an annual standard deviation would not be the average of quarterly standard deviations. The average x and standard deviation "s" of a set of n numbers xi, x2 ... xn are defined as follows:
- 1 x-)
x=n I-x s= n-4.2 Values below the highest lower limit of detection are not included in the average.
4.3 If all values in the averaging group are less than the highest LLD, the highest LLD is reported.
4.4 If all but one of the values are less than the highest LLD, the single value x and associated two sigma error is reported.
4.5 In rounding off, the following rules are followed:
4.5.1. If the number following those to be retained is less than 5, the number is dropped, and the retained numbers are kept unchanged. As an example, 11.443 is rounded off to 11.44.
4.5.2. If the number following those to be retained is equal to or greater than 5, the number is dropped and the last retained number is raised by 1. As an example, 11.445 is rounded off to 11.45.
B-1
APPENDIX C Table C-1. Maximum permissible concentrations of radioactivity in air and water above natural background in unrestricted areasa Air (pCi/mr) Water (pCi/L)
-3 Gross alpha 1 x 10 Strontium-89 8,000 Gross beta I Strontium-90 500 b -1 Iodine-1 31 2.8 x 10 Cesium-1 37 1,000 Barium-140 8,000 lodine-I31 1,000 Potassium-40 4,000 Gross alpha 2 Gross beta 10 6
JTritium 1 X 10 a
Taken from Table 2 of Appendix B to Code of Federal Regulations Title 10, Part 20, and appropriate footnotes.
Concentrations may be averaged over a period not greater than one year.
b Value adjusted by a factor of 700 to reduce the dose resulting from the air-grass-cow-milk-child pathway.
C A natural radionuclide.
C-1
APPENDIX D Sampling Location Maps D-1
Figure D-1, Sample Collection and Analysis Program: TLD locations, Inner Ring. (Table 5.2)
D-2
LI-ic~i I~L T~i a-L U-51 rt-0 U.'
Figure D-2, Sample Collection and Analysis Program: TLD locations, Outer Ring. (Table 5.2)
D-3
41v8l CL Figure D-3, Sample Collection and Analysis Program: TLD locations, Controls. (Table 5.2)
D-4
- 435: : CoR.* r, " 5 _-_;' d MIf.
..-.. t*-.-_..
- -- " ' 'i.: '-n PH ....-....-0
. . . i.s 7--
- ,A,
/4 a
'41R
.. -%ci;o d-- w Figure D-4, Sa mple Collection and Analysis Program: Radiological Environmental Monitoning Program, Milk Sampling locations. (Table 5.2)
D-5
Figure D-5, Sample Collection and Analysis Program: Radiological Environmental Monitoring Program, Sludge, Ground Water and Shoreline sampling locations. (Table 5.2)
D-6
APPENDIX E Ground Water Monitorinq Well Samples
1.0 INTRODUCTION
This appendix to the Radiological Environmental Monitoring Program Annual Report to the United States Nuclear Regulatory Commission summarizes and interprets results of the Ground Water Monitoring Program samples taken at the Monticello Nuclear Plant, Monticello, Minnesota, during the period January
- December 2013. This sampling program was established in October of 2006 following the industry initiative on ground water monitoring.
Complete data tables for each period and sampling location, are provided in a reference document, (Environmental, Inc., Midwest Laboratory, "Complete Analyses Data Tables, January - December, 2013")
available at the Monticello Nuclear Generating Plant, Chemistry and Radiation Protection Department.
E-2
2.0
SUMMARY
The Ground Water Sampling Program was established following industry events where tritium was discovered in ground water surrounding commercial nuclear facilities. This program is described and the results for 2013 are summarized and discussed.
Program findings for 2013 detected low levels of tritium in monitoring wells located on the plant property.
With the exception of monitoring wells MW-9A and MW-1 3A, tritium measured at or near expected natural background levels. No tritium was detected in four samples of storm water runoff samples collected from the sanitary sewer and the sewer lift station. The 2013 sample results (excluding MW-9A and MW-13A) all measured below the required limit of 500 pCi/L. Measurements for 2013 were below the Environmental Protection Agency's drinking water standard of 20,000 pCi/L and present no harm to members of the public.
None of the samples monitored for gamma-emitting isotopes showed activity greater than the LLD.
A summation of the analytical data for both ground water monitoring wells and storm water runoff samples is provided in Table E-3.
E-3
3.0 Ground Water Sampling Program 3.1 Program Design and Data Interpretation The purpose of this sampling program is to assess the impact of any tritium leaching into the environment (ground water system) from MNGP. For this purpose, water samples are collected and analyzed for tritium content.
3.2 Program Description The sampling and analysis schedule for the Ground Water Monitoring Program is summarized in Table E-1 and briefly reviewed below. Table E-2 defines the additional sample locations and codes for the Ground Water Sampling Program.
Sampling from the groundwater monitoring wells was conducted monthly at fourteen locations and quarterly for five locations.
3.3 Program Execution The Program was executed as described with the following exceptions:
Additional analyses for gamma emitting isotopes were performed on samples from each of the nineteen monitoring wells. The results are summarized in Table E-3. Results of individual analyses are reported in Tables E-4 and E-5.
3.4 Pro-gram Modifications There were no additional on-site monitoring wells added to the ground water program in 2013.
E-4
3.5 Results and Discussions Sampling points in North America have shown tritium concentrations in precipitation may range from 5 pCi/L to 157 pCi/L (Environmental Isotope Data No. 10; World Survey of Isotope Concentration in Precipitation (1988-1991). Results obtained show tritium in ground water samples at or near expected natural background levels, with the exception of monitoring wells, MW-9A and MW-1 3A.
Excluding the data from wells MW-9A and MW-13A, 2013 sample results all measured below an LLD level of 500 pCi/L, and were similar to averages measured in 2012.
The tritium activity at location MW-9A was higher than previous measurements from 2010 to 2012. A spike in activity seemed to occur from July through September, 2013, but declined significantly in October, and dropped throughout the rest of the year. Activity ranged from a high of 15,124 to less than 500 pCi/L. Previous investigations have concluded the activity may be due to a 1981 spill from the Condensate Storage Tanks that had infiltrated the surface and migrated towards MW-9.
One sample collected from MW-9A was tested for hard to detect isotopes. Results for gross alpha, iron-55, nickel-63 and strontium-89 and strontium-90 all measured below detection limits.
1,The tritium activity measured in samples collected from monitoring well MW-13A was highest in October and November, 2013, suggesting migration from MW-9A. Activity ranged from a high of 729 to less than 500 pCi/L.
None of the groundwater samples analyzed for gamma-emitting isotopes showed activity greater than LLD.
E-5
Table E-1. Sample Collection and Analysis Program, Ground Water.
Medium Number Sample Codes Collection type Analysis Type Ground Water 35 MW-1, MW-2, MW-3, MW-4, Grab H-3 Quarterly MW-9B, MW-11, MW-12A, MW-12B, Ground Water 79 MW-9A, MW-10, MW-13A, Grab H-3 Monthly MW-138, MW-14, MW-15A MW-1 58, Ground Water 79 MW-5, MW-6, MW-7, MW-8 Grab H-3 Annual Table E-2. Sampling locations for Ground Water Monitoring Wells.
Sample Type Vendor Well Distance from Compass Sector Code Number Stack (miles) Heading from Stack Ground Water M-33 MW-1 0.11 299 WNW Ground Water M-34 MW-2 0.14 301 WNW Ground Water M-35 MW-3 0.15 305 NW Ground Water M-36 MW-4 0.1 25 NNE Ground Water M-37 MW-5 0.1 253 WSW Ground Water M-38 MW-6 229 Feet 228 SW Ground Water M-39 MW-7 0.2 66 ENE Ground Water M-40 MW-8 0.3 150 SSE Ground Water M-44 MW-9A 0.1 310 NW Ground Water M-51 MW-9B 0.1 310 NW Ground Water M-45 MW-10 0.1 292 WNW Ground Water M-46 MW-11 0.1 283 WNW Ground Water M-47 MW-12A 0.1 330 NW Ground Water M-48 MW-12B 0.1 326 NW Ground Water M-49 MW-13A 0.12 316 NW Ground Water M-50 MW-13B 0.12 316 NW Ground Water M-52 MW-14 0.17 306 NW Ground Water M-53 MW-15A 0.14 14 NNE Ground Water M-54 MW-15B 0.14. 14 NNE E-6
Table E-3. Ground Water Monitoring Program Summary.
Name of Facility Monticello Nuclear Generating Plant Docket No. 50-263 Location of Facility Wright, Minnesota Reporting Period January-December, 2013
( County, State )
Indicator Location with Highest Control Number Sample Type and Locations Annual Mean Locations Non-Type Number of LLDb Mean (F)c Mean (F)c Mean (F)c Routine (Units) Analysesa Rangec Locationd Rangec Rangec Resultse Groundwater H-3 114 500 1182 (11/114) MW-9A, Onsije, 5457 (9/12) none 3 Monitoring Wells (566-15124) 0.1 mi @ 310°/NW (879-15124)
(pCi/L) GS 62 Mn-54 10 < LLD - - none 0 Fe-59 30 < LLD - - none 0 Co-58 10 < LLD - - none 0 Co-60 10 < LLD - - none 0 Zn-65 30 < LLD - - none 0 Zr-Nb-95 15 < LLD - - none 0 1-131 30 < LLD - - none 0 Cs-134 10 < LLD - - none 0 Cs-137 10 < LLD - - none 0 Ba-La-140 15 < LLD - - none 0 Ce-144 50 < LLD - - none 0 Stormwater H-3 4 500 < LLD - - none 0 Runoff (pCi/L) GS 4 Mn-54 10 < LLD - - none 0 Fe-59 30 < LLD - - none 0 Co-58 10 < LLD - - none 0 Co-60 10 < LLD - - none 0 Zn-65 30 < LLD - - none 0 Zr-Nb-95 15 < LLD - - none 0 1-131 30 < LLD - - none 0 Cs-134 10 < LLD - - none 0 Cs-137 10 < LLD - - none 0 Ba-La-140 15 < LLD - - none 0 Ce-144 43 < LLD - - none 0 GB = gross beta, GS = gamma scan.
b LLD = nominal lower limit of detection based on a 4.66 sigma counting error for background sample.
c Mean and range are based on detectable measurements only. Fraction of detectable measurements at specified locations is indicated in parentheses (F).
d Locations are specified: (1) by name, and/or station code and (2) by distance (miles) and direction relative to reactor site.
Non-routine results are those which exceed ten times the control station value. If no control station value is available, the result is considered non-routine if it exceeds ten time the typical preoperational value for the medium or location.
E-7
MISSISSIPPI RIVER 2009) 904.40 (September 09, Figure E-1. Sample collection and analysis program: Ground water, On-site monitoring well locations.
E-8
Table E-4. Ground water, analyses for tritium and gamma-emitting isotopes.
Collection Concentration (pCi/L) 3 1 1 Lab Code Date H 54Mn "Fe "Co "Co 65Zn 9-ZrNb 134CS 137Cs 4°BaLa 44Ce Monitoring Well #1 (M-33)
MWW- 699 02/21/13 <143 <10 <30 <10 <10 <30 <15 <10 <10 <15 <45 MWW- 2775 05/23/13 <148 <10 <30 <10 <10 <30 <15 <10 <10 <15 <17 MWW- 5160 08/22/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <25 MWW- 7160 11/19/13 <156 <10 < 30 <10 <10 <30 <15 <10 <10 <15 <26 Monitoring Well #2 (M-34)
MWW-700 02/21/13 263+/-84 <10 <30 <10 <10 <30 <15 <10 <10 <15 <46 MWW-2776 05/23/13 262+/-101 <10 <30 <10 <10 <30 <15 <10 <10 <15 <23 MWW-5161 08/22/13 165+/-80 <10 <30 <10 <10 <30 <15 <10 <10 <15 <20 MWW-7161 11/19/13 211 +/-86 <10 <30 <10 <10 <30 <15 <10 <10 <15 <39 Monitoring Well #3 (M-35)
MWW-701 02/21113 219+/-82 <10 <30 <10 <10 <30 <15 <10 <10 <15 <43 MWW- 2778 05/23/13 322 +/-103 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 MWW-5162 08/22/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <20 MWW-7162 11/19/13 224+/-86 <10 <30 <10 <10 <30 <15 <10( <10 <15 <30 Monitoring Well #4 (M-36)
NDa MWW-2779 05/23/13 270 +/-101 <10 <30 <10 <10 <30 <15 <10 <10 <15 <19 MWW- 5561 .09/17/13 <151 <10 <30 <10 <10 <30 <15 <10 <10 <15 <31 MWW-7163 11/20/13 <156 <10 <30 <10 <10 <30 <15 <10 <10 <15 <28 Monitoring Well #5 (M-37)
MWW- 5163 08/20/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <21 Monitoring Well #6 (M-38)
MWW-5164 08/22/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <25 Monitoring Well #7 (M-39)
MWW-5165 08/22/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <21 Monitoring Well #8 (M-40)
MWW- 5166 08/22/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <25 a ND = No Data; Sample not collected.
E-9
Table E-4. Ground water, analyses for tritium and gamma-emitting isotopes.
Collection Concentration (pCi/L) 3 9 140 144 Lab Code Date H 54Mn 59Fe 58C0 60C0 65Zn ZrNb 1340S 137Cs BaLa Ce Monitoring Well #9A (M-44)
MWW- 475 01/30/13 < 136 - - - - - - - - - -
MWW-702 02/19/13 371 +/-88 <10 <30 <10 <10 <30 <15 <10 <10 <15 <17 MWW- 1330 03/26/13 4717 +/- 206 - - - - - - - - - -
MWW- 2175 04/26/13 < 142 - - - - - - - - - -
MWW-V2818 05/23/13 999+/-126 <10 <30 <10 <10 <30 <15 <10 <10 <15 <43 MWW- 3451 06/18/13 879 +/- 133 - - - - - -
MWW- 4213 07/16/13 12868 +/- 337 - - - - -
MWW-5008 08/20/13 15124+/-352 <10 <30 <10 <10 <30 <15 <10 <10 <15 <18 MWW- 5790 09/27/13 10378 +/- 297 - - - - -
MWW- 6817 10/31/13 1785 +/- 147 - - - - -
MWW-7177 11/19/13 1147+/-123 <10 <30 <10 <10 <30 <15 <10 <10 <15 <15 MWW- 7594 12/17/13 1214 +/- 137 - - - - - - - - - -
Monitoring Well #9B (M-51)
MWW-703 02/19/13 <143 <10 <30 <10 <10 <30 <15 <10 <10 <15 <33 MWW--2820 05/23/13 <148 <10 <30 <10 <10 <30 <15 <10 <10 <15 <27 MWW-5168 08/20/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <18 MWW-7178 11/19/13 <156 <10 <30 <10 <10 <30 <15 <10 <10 <15 <16 Monitoring Well #10 (M-45)
MWW- 476 01/29/13 343 +/- 88 -
ND a MWW- 1331 03/27/13 356 +/- 93 -
MWW- 2176 04126113 346 +/- 91 -
MWW-2780 05/23/13 390 +/-106 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 MWW- 3452 06/18/13 215 +/- 112 - - - - - - - - - -
MWW- 4132 07/15/13 < 185 - - - - - - - - - -
MWW- 5169 08/23/13 305 +/-89 <10 <30 <10 <10 <30 <15 <10 <10 <15 <17 MWW- 5562 09/17/13 318 +/- 90 - - - - - - - - - -
MWW- 6818 10/31/13 359 +/- 105 - - - - - - - - - -
MWW-7164 11/19/13 364+/-93 <10 <30 <10 <10 <30 <15 <10 <10 <15 <25 MWW- 7588 12/18/13 301 +/- 87 - - - - - - - - - -
Monitoring Well #11 (M-46)
MWW- 704 02/21/13 <146 <10 <30 <10 <10 <30 <15 <10 <10 <15 <16 MWW-2781 05/23/13 <188 <10 <30 <10 <10 <30 <15 <10 <10 <15 <18 MWW- 5563 09/17/13 <151 <10 <30 <10 <10 <30 <15 <10 <10 <15 <33 MWW-7166 11/19/13 <156 <10 <30 <10 <10 <30 <15 <10 <10 <15 <19 Monitoring Well #12A (M-47)
MWW- 914 02/20113 <144 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 MWW-2782 05/23/13 <188 <10 <30 <10 <10 <30 <15 <10 <10 <15 <25 MWW- 5170 08/23/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <31 MWW- 7167 11/21/13 <156 <10 <30 <10 <10 <30 <15 <10 <10 <15 <23 a ND = No Data; Sample not collected.
E-10
Table E-4. Ground water, analyses for tritium and gamma-emitting isotopes.
Collection Concentration (pCi/L) 58 60 95 1 14 0 Lab Code Date 3H 54Mn 59Fe Co Co 65Zn ZrNb 34Cs 137CS BaLa 144Ce Monitoring Well #12B (M-48)
MWW- 915 02/20/13 <144 <10 <30 <10 <10 <30 <15 <10 <10 .<15 <27 MWW- 2783 05/23/13 <188 <10 <30 <10 <10 <30 <15 <10 <10 <15 <29 MWW-5171 08/23/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <34 MWW- 7168 11/21/13 <156 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 Monitorinq Well #1 3A (M-49)
MWW- 477 01/29/13 < 149 - - - - - - - - - -
MWW- 705 .02/21/13 182 +/-78 <10 <30 <10 <10 <30 <15 <10 <10 <15 <18 MWW- 1332 03/27/13 249 +/- 89 - - - - - - - - - -
MWW- 2177 04/26/13 277 +/- 88 - - - - - - - - - -
MWW-2784 05/23/13 340+/-104 <10 <30 <10 <10 <30 <15 <10 <10 <15 <19 ND a MWW- 4133 07/16/13 < 185 - - - - - - - - - -
MWW-5172 08/22/13 234+/-86 <10 <30 <10 <10 <30 <15 <10 <10 <15 <17 MWW- 5564 09/18/13 432 +/- 95 - - - - - - - - - -
MWW- 6819 10/31/13 566 +/- 112 - - - - - - - - - -
MWW- 7169 11/20/13 729 +/-108 <10 <30 <10 <10 <30 <15 <10 <10 <15 <21 Monitoring Well #13B (M-50)
MWW- 478 01/29/13 331 +/- 88 - - - - - - - - - -
MWW- 706 02/21/13 292 +/-84 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 MWW- 1333 03/27/13 185 +/- 86 - - - - - -
MWW- 2178 04/26/13 299 +/- 89 - - - - - -
MWW- 2785 05/23/13 357 +/-104 <10 <30 <10 <10 <30 <15 <10 <10 <15 <15 ND a MWW- 4134 07/16/13 316 +/- 124 - - - - - - - - - -
MWW-5173 08/23/13 173+/-83 <10 <30 <10 <10 <30 <15 <10 <10 <15 <21 MWW- 5565 09/18/13 170 +/- 83 - - - - - - - - -
MWW- 6820 10/31/13 197 +/-+103 - - - - - - - - -
MWW-7170 11/20/13 240+/-87 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 Monitoring Well #14 (M-52)
MWW- 479 01/29/13 < 149 - -
MWW-707 02/21/13 238+/-81 <10 <30 <10 <10 <30 <15 <10 <10 <15 <18 MWW- 1334 03/27/13 < 147 - - - - - - - - - -
MWW- 2179 04/25/13 < 142 - - -
MWW-2786 05/23/13 <148 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 MWW- 3453 06/18/13 < 198 - - - - - - - - - -
MWW- 4136 07/15/13 < 185 - - - - - - - - - -
MWW-5174 08/20/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <20 MWW- 5566 09/16/13 < 151 - - - - - - - - - -
MWW- 6821 10/29/13 < 184 - - - - - - - - - -
MWW-7179 11/18/13 <156 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 MWW- 7589 12/17/13 < 145 - - - - - - - - - -
ND = No Data; Sample not collected.
E-11
Table E-4. Ground water, analyses for tritium and gamma-emitting isotopes.
Collection Concentration (pCi/L) 3 60 1 137 14 144 Lab Code Date H 54Mn 59Fe 5"Co*> Co 65Zn 95ZrNb 34Cs Cs (BaLa Ce Monitoring Well #15A (M-53)
MWW- 480 01/29/13 < 149 - - - - - - - - - -
MWW- 916 02/20/13 <146 <10 <30 <10 <10 <30 <15 <10 <10 <15 <23 MWW- 1335 03/27/13 < 147 - -,. - - -
MWW- 2180 04/25/13 < 144 -- - -
MWW-2787 05/23/13 <148 <10 <30 <10 <10 <30 <15 <10 <10 <15 <28 MWW- 3454 06/18/13 < 198 - - - - - - - - - -
MWW- 4137 07/15/13 < 185 - - - - - - - - - -
MWW- 5175 08/23/13 <150 <10 <30 <10 <10 <30 <15 <10 <10 <15 <29 MWW- 5567 09/17/13 < 151 - - - - - -
MWW- 6822 10/31/13 < 184 - - - - - -
MWW-7171 11/21/13 188+/-84 <10 <30 <10 <10 <30 <15 <10 <10 <15 <19 MWW- 7590 12/18/13 < 146 - - - - - - - - - -
Monitorinq Well #15B (M-54)
MWW- 481 01/29/13 402 +/- 91 - - - - - - - - -
MWW-917 02/20/13 335+/-91 <10 <30 <10 <10 <30 <15 <10 <10 <15 <23 MWW- 1336 03/27/13 199 +/- 87 - - - - - - - - - -
MW\W- 2181 04/25/13 291 +/- 89 - - - - - - - - - -
MWW-2788 05/23/13 240+/-100 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 MWW- 3455 06/18/13 < 198 - - - - - - - - - -
MWW- 4138 07/15/13 < 185 - - - - - - - - - -
MWW-5176 08/23/13 195+/-81 <10 <30. <10 <10 <30 <15 <10 <10 <15 <17 MWW- 5568 09/17/13 275 +/- 88 - - - - - - - - - -
MWW- 6823 10/31/13 < 182 - - - - - - - - - -
MWW-7172 11/21/13 242+/-87 <10 <30 <10 <10 <30 <15 <10 <10 <15 <50 MWW- 7591 12/18/13 185 +/- 81 - - - - - - - - - -
Storm Water Run-off (SD-006)
MXW-3450 06/12/13 <198 <10 <30 <10 <10 <30 <15 <10 <10 <15 <43 MXW- 5560 09/09/13 <151 <10 <30 <10 <10 <30 <15 <10 <10 <15 <26 MXW- 6460 10/03/13 <147 <10 <30 <10 <10 <30 <15 <10 <10 <15 <10 Storm Water Run-off (Sewer Lift Station)
MXW- 7355 12/03/13 <151 <10 <30 <10 <10 <30 <15 <10 <10 <15 <17 Table E-5. Ground water, analyses for hard to detect isotopes.
Collection Concentration (pCi/L) 9 Lab Code Date Location Gross Alpha 8 Sr goSr 55Fe 63Ni MWW- 5008 08/20/13 MW-9A < 1.2 < 0.6 < 0.5 < 768 < 98 E-12
f ATI Environmental, Inc.
4ATMidwest Labo~r'atory 700 Landwehr phone Road . .Northbrook.
(847) 564-0700 IL 60062-2310 fax (847) 564-4517 FINAL REPORT TO XCEL ENERGY CORPORATION RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP)
MONTICELLO NUCLEAR GENERATING PLANT DOCKET NO. 50-263 LICENSE NO. DPR-22 COMPLETE ANALYSES DATA TABLES January - December, 2013 Prepared under contract by ENVIRONMENTAL, INC.
MIDWEST LABORATORY PROJECT NO. 8010 Reviewed and Approved E- (3 -.20 (ý L atory Manager
MNGP TABLE OF CONTENTS Section Page List o f T a b le s ................................................................................................................... iii
1.0 INTRODUCTION
............................................................................................................. iv 2.0 LISTING OF MISSED SAM PLES .................................................................................. . v 3.0 DATA TABLES ................................................................................................................ vi ii
MNGP LIST OF TABLES No. Title Paqe 1 Ambient radiation as measured by thermoluminescent dosimeters (TLDs) ................ 1-1 2 Airborne particulates and iodine collected at Location M-1(C), analysis for gross beta a nd iod ine -13 1 .............................................................................................................. 2 -1 3 Airborne particulates and iodine collected at Location M-2, analysis for gross beta and iod ine -13 1 ...................................................................................................................... 3 -1 4 Airborne particulates and iodine collected at Location M-3, analysis for gross beta and iod ine -13 1 ...................................................................................................................... 4 -1 5 Airborne particulates and iodine collected at Location M-4, analysis for gross beta and iod ine -13 1 ...................................................................................................................... 5 -1 6 Airborne particulates and iodine collected at Location M-5, analysis for gross beta and iod ine -13 1 ...................................................................................................................... 6 -1 7 Airborne particulates, analysis for gross beta, monthly averages ................................................ 7-1 8 Airborne particulate samples, quarterly composites from each location, analysis for gam ma-em itting isotopes .............................................................................................. 8-1 9 Pasture Grass, vegetation, analysis for iodine-131 and gamma emitting isotopes ...................... 9-1 10 River water, upstream, M-8 (C) and M-9, analysis of monthly composites for gamma-e mitting isoto pes ........................................................................................................... 10-1 11 Drinking water, City of Minneapolis, M-14, analysis of monthly composites for gross beta, iodine-131 and gamma-emitting isotopes ............................................................. 11-1 12 River water and drinking water, analysis of quarterly composites for tritium ................................ 12-1 13 Well water, analysis for tritium and gamma-emitting isotopes ..................................................... 13-1 14 Fish, analysis of edible portions for gamma-emitting isotopes ..................................................... 14-1 15 Algae or aquatic insects, analysis for gamma-emitting isotopes .................................................. 15-1 16 Edible cultivated (irrigated) crops, analysis for iodine-131 and gamma-emitting iso to pe s .......................................................................................................................... 16 -1 17 Shoreline sediments, analysis for gamma-emitting isotopes ....................................................... 17-1 iii
1.0 INTRODUCTION
The following constitutes the final 2013 report for the Environmental Radiological Monitoring Program conducted at the Monticello Nuclear Generating Plant in Monticello, Minnesota.
Results of completed analyses are presented in the attached tables.
All concentrations, except gross beta, are decay corrected to the time of collection.
All samples were collected within the scheduled period unless noted otherwise in the Listing of Missed Samples.
iv
MNGP 2.0. LISTING of MISSED SAMPLES All required samples were collected and analyzed as scheduled with the following exceptions:
Collection Reason for not Sample Analysis Location Date or conducting REMP Plans for Preventing Type Period as required Recurrence WW Gamma, H-3 M-014 1/13/2013 Sample damaged in shipment. None required.
AP/AI Beta, 1-131 M-01 1/16/2013 Pump found off. Sampler restarted.
SW Gamma M-008 Jan. 2013 Water frozen entire month; None required.
no composite.
WW Gamma, H-3 M-027 1/23/2013 Residence vacant, None required.
water turned off.
SW Gamma M-008 Feb. 2013 Water frozen entire month; None required.
no composite.
SW Gamma M-008 Mar. 2013 Water frozen entire month; None required.
no composite.
SW H-3 M-008 Ist Qtr '13 Water frozen entire quarter; None required.
no composite.
AP/Al Beta, 1-131 M-01 5/1/2013 Pump found off. Sampler pump replaced.
WW Gamma, H-3 M-014 5/7/2013 Sample damaged in shipment. None required.
AP/AI Beta, 1-131 M-01 5/8/2013 Pump failure. Sampler pump replaced.
AP/AI Beta, 1-131 M-02 11/27/2013 Filter misaligned in holder; Technician coached on light particulate collected, verification practices.
WW Gamma, H-3 M-014 11/27/2013 No sample taken. Technician coached on proper turnover.
SW Gamma M-008 Dec. 2013 Water frozen entire month; None required.
no composite.
V
MNGP 3.0 DATA TABLES vi
MNGP Table 1. Ambient gamma radiation as measured by thermoluminescent dosimeters (TLD's).
Previous mRem/91 days Cumulative Annual Location 1st Qtr. 2nd Qtr. 3rd Qtr. 4th Qtr. Average Average Indicators (Inner Ring., General Area of Site Boundary)
M-OIA 12.1 +/- 1.2 15.5 +/- 1.3 13.8 +/- 1.0 16.0 +/- 1.4 14.4 14.0 M-02A 15.3 +/- 1.1 15.6 +/- 1.2 17.1 +/- 0.8 14.8 +/- 0.9 15.7 16.2 M-03A 15.0 +/- 1.4 14.2 +/- 1.7 16.1 +/- 1.5 13.0 +/- 1.1 14.6 15.9 M-04A 12.9 +/- 1.1 17.0 +/- 1.0 12.5 +/- 0.9 16.8 +/- 0.9 14.8 15.7 M-05A 11.1 +/- 1.0 14.0 +/- 0.8 13.3 +/- 1.1 13.0 +/- 0.9 12.9 16.1 M-06A 12.5 +/- 1.0 15.4 +/- 0.9 14.8 +/- 0.9 15.2 +/- 0.7 14.5 16.8 M-07A 13.5 +/- 1.0 13.4 +/- 0.9 13.1 +/- 0.6 15.7 +/- 0.8 13.9 16.6 M-08A 12.8 +/- 0.9 15.3 +/- 0.8 15.1 +/- 0.8 15.2 +/- 1.3 14.6 17.4 M-09A 13.8 +/- 1.2 13.1 +/- 1.0 15.1 +/- 0.8 13.3 +/- 0.7 13.8 16.6 M-10A 14.0 +/- 1.1 14.4 +/- 0.8 15.8 +/- 0.9 14.0 +/- 0.9 14.6 16.8 M-11A 10.9 +/- 0.9 15.4 +/- 0.8 13.6 +/- 0.6 14.3 +/- 1.0 13.6 17.8 M-12A 12.3 +/- 1.0 13.4 +/- 0.8 14.6 +/- 0.6 12.6 +/- 0.6 13.2 17.1 M-13A 13.5 +/- 1.1 18.3 +/- 1.1 15.3 +/- 0.9 17.3 +/- 1.0 16.1 14.5 M-14A 15.0 +/- 0.8 13.0 +/- 0.8 18.6 +/- 0.7 13.6 +/- 0.7 15.1 16.2 Mean +/- s.d. 13.2 +/- 1.4 14.9 +/- 1.5 14.9 +/- 1.7 14.6 +/- 1.5 14.4 16.3 Indicators (Outer Ring, 4-5 Miles Distant)
M-01B 12.7 +/- 0.9 14.9 +/- 1.4 15.7 +/- 1.0 14.0 +/- 1.4 14.3 15.7 M-02B 12.7 +/- 1.0 16.3+/- 0.8 15.1 +/- 0.8 15.7 +/- 0.7 15.0 15.3 M-03B 10.4 +/- 0.9 12.8 +/- 1.0 13.0 +/- 0.8 12.1 +/- 1.0 12.1 12.8 M-04B 12.8 +/- 0.8 13.6 +/- 0.9 15.4 +/- 0.6 12.5 +/- 0.7 13.6 14.5 M-05B 13.6 +/-+0.7 13.3 +/- 1.0 15.0 +/- 0.5 14.2 +/- 0.9 14.0 15.7 M-06B 12.7 +/- 0.8 15.7 +/- 1.0 15.9 +/- 1.1 14.5 +/- 1.0 14.7 15.8 M-07B 11.1 +/-1.0 14.0 +/- 1.2 14.0 +/- 1.0 13.4 +/- 1.0 13.1 16.9 M-08B 13.4 +/- 0.7 16.8 +/- 1.2 14.8 +/- 0.8 16.0 +/- 0.9 15.3 15.0 M-09B 11.8 +/-0.8 15.6 +/- 0.9 15.8 +/- 0.6 14.8 +/- 0.9 14.5 17.2 M-10B 14.9 +/- 1.2 15.4 +/- 1.1 19.1 +/- 1.7 13.6 +/- 1.0 15.8 16.9 M-11B 11.7 +/- 1.1 14.9 +/- 1.1 16.6 +/- 1.3 14.6 +/- 1.0 14.5 16.7 M-12B 12.9 +/- 1.4 13.6 +/- 0.8 16.1 +/- 0.9 14.9 +/- 0.8 14.4 16.2 M-13B 12.3 +/- 1.0 13.8 +/- 1.1 13.7 +/- 1.0 13.0 +/- 0.9 13.2 14.8 M-14B 11.7 +/-0.9 14.9 +/- 0.8 14.6 +/- 1.3 13.9 +/- 0.8 13.8 16.5 M-15B 11.4 +/-0.9 13.8 +/- 1.1 15.3 +/- 1.0 13.0 +/- 0.9 13.4 15.2 M-16B 11.9 +/-0.8 14.1 +/- 1.4 14.3 +/- 0.6 12.1 +/- 1.0 13.1 13.4 Mean +/- s.d. 12.4 +/- 1.1 14.6 +/- 1.1 15.3 +/- 1.4 13.9 +/- 1.2 14.0 15.5 1-1
MNGP Table 1. Ambient gamma radiation as measured by thermoluminescent dosimeters (TLD's),
(continued).
Previous mRem/91 days Cumulative Annual Location 1st Qtr. 2nd Qtr. 3rd Qtr. 4th Qtr. Average Average Control M-01C 13.9 +/- 1.4 18.3 +/- 1.2 14.5 +/- 1.0 18.8 +/- 1.1 16.4 16.0 M-02C 11.8 +/- 1.3 13.8 +/- 1.0 16.2 +/- 1.2 14.0 +/- 0.9 14.0 17.0 M-03C 15.5 +/- 0.8 16.6 +/- 0.9 16.8 +/- 0.6 16.7 +/- 0.6 16.4 18.2 M-04C 12.8 +/- 0.7 15.7 +/- 0.8 16.3 +/- 0.6 15.6 +/- 0.8 15.1 16.6
- Mean +/- s.d. 13.5 +/- 1.6 16.1 +/- 1.9 16.0 +/- 1.0 16.3 +/- 2.0 15.5 16.9 Indicators (Special Interest Areas)
M-01S 10.9 +/- 1.1 11.4 +/-0.8 13.3 +/- 1.2 10.8 +/-0.6 11.6 13.8 M-02S 14.2 +/- 0.9 11.4 +/- 0.9 17.4 +/- 0.9 10.9 +/- 0.9 13.5 12.9 M-03S 11.8 +/- 1.1 15.5 +/- 1.1 16.5 +/-0.6 14.8 +/-0.9 14.7 15.4 M-04S 11.9 +/- 1.0 13.4 +/- 1.0 15.0 +/- 1.2 13.4 +/-0.8 13.4 15.7 M-05S 12.6 +/- 0.8 13.8 +/- 1.1 15.1 +/- 0.7 13.6 +/- 0.8 13.8 14.4 M-06S 17.1 +/- 1.4 16.7 +/- 1.0 17.8 +/- 0.9 16.8 +/- 0.8 17.1 17.6 Mean +/- s.d. 13.1 +/- 2.3 13.7 +/- 2.1 15.9 +/- 1.7 13.4 +/- 2.3 14.0 15.0 Special TLDs M-I-01 89.7 +/- 2.6 17.3 +/- 1.1 106.0 +/- 3.2 43.3 +/- 1.9 64.1 100.5 M-I-02 53.8 +/- 2.1 16.9 +/- 0.8 63.3 +/- 1.7 38.4 +/- 1.3 43.1 83.5 M-1-03 42.3 +/- 2.1 17.3 +/- 1.0 52.5 +/- 3.1 33.0 +/- 1.4 36.3 57.2 M-1-04 29.5 +/- 1.8 18.2 +/- 1.3 33.7 +/- 2.2 42.4 +/- 2.6 31.0 40.4 M-1-05 43.0 +/- 1.7 34.5 +/- 1.4 95.3 +/- 6.5 99.0 +/- 1.9 68.0 53.0 M-1-06 23.1 +/- 1.6 20.9 +/- 0.8 27.4 +/- 1.7 28.0 +/- 2.1 24.9 31.6 M-I-07 30.2 +/- 1.2 22.6 +/- 1.2 34.0 +/- 1.4 35.0 +/- 2.1 30.5 36.5 M-I-08 30.3 +/- 2.3 18.4 +/- 1.3 33.5 +/- 2.2 32.1 +/- 2.9 28.6 33.7 M-I-09 56.1 +/- 1.7 44.5 +/- 1.8 138.4 +/- 3.9 216.7 +/- 3.7 113.9 63.5 M-I-10 32.0 +/- 1.2 20.5 +/- 1.2 45.1 +/- 1.7 39.5 +/- 1.9 34.3 54.0 M-1-11 14.4 +/- 1.3 13.8 +/-0.9 15.3 +/- 1.1 13.8 +/-0.7 14.3 17.2 M-1-12 14.0 +/- 0.7 15.8 +/- 1.0 16.7 +/- 0.7 16.3 +/- 0.8 15.7 17.0 M-1-13 16.1 +/- 2.0 13.7 +/- 1.3 18.9 +/- 1.8 14.3 +/- 1.3 15.8 18.2 Mean +/-s.d. 36.5 +/- 21.1 21.1 +/- 8.8 52.3 +/- 38.4 50.1 +/- 54.4 40.0 46.6 1-2
MNGP Table 2. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-1 31 a.
Location: M-13 (C)
Units: pCi/m Collection: Continuous, weekly exchange.
Date Volume Date Volume Collected (m3) Gross Beta Collected (mi) Gross Beta Required LLD 0.010 Required LLD 0.010 01-09-13 353 0.063 +/- 0.004 07-10-13 380 0.028 +/- 0.003 01-16-13 NDb 07-17-13 385 0.029 +/- 0.003 01-23-13 322 0.043 +/- 0.004 07-24-13 380 0.021 +/- 0.003 01-30-13 295 0.061 +/- 0.005 07-31-13 353 0.016 +/- 0.003 02-06-13 294 0.070 +/- 0.005 08-06-13 304 0.023 +/- 0.003 02-13-13 323 0.032 +/- 0.004 08-14-13 405 0.020 +/- 0.003 02-20-13 323 0.039 +/- 0.004 08-21-13 315 0.052 +/- 0.005 02-27-13 324 0.038 +/- 0.004 08-28-13 323 0.041 +/- 0.004 03-06-13 322 0.028 +/- 0.004 09-04-13 320 0.022 +/- 0.003 03-13-13 321 0.032 +/- 0.004 09-11-13 322 0.043 +/- 0.004 03-20-13 325 0.034 +/- 0.004 09-18-13 355 0.022 +/- 0.003 03-27-13 322 0.024 +/- 0.003 09-25-13 293 0.027 +/- 0.004 04-03-13 324 0.029 +/- 0.003 10-02-13 295 0.036 +/- 0.004 1st Quarter Mean +/- s.d. 0.041 +/- 0.015 3rd Quarter Mean +/- s.d. 0.029 +/- 0.011 04-10-13 329 0.029 +/- 0.003 10-09-13 293 0.021 +/- 0.003 04-17-13 319 0.011 +/- 0.003 10-16-13 296 0.029 +/- 0.004 04-24-13 324 0.026 +/- 0.003 10-23-13 290 0.015 +/- 0.004 05-01-13 55 NDb 10-30-13 294 0.015 +/- 0.003 05-08-13 129 NDb 11-06-13 356 0.032 +/- 0.004 05-15-13 343 0.024 +/- 0.003 11-13-13 353 0.028 +/- 0.003 05-22-13 348 0.015 +/- 0.003 11-21-13 337 0.047 +/- 0.004 05-29-13 352 0.017 +/- 0.003 11-27-13 302 0.030 +/- 0.004 12-03-13 254 0.070 +/- 0.006 06-05-13 354 0.018 +/- 0.003 06-12-13 352 0.023 +/- 0.003 12-10-13 293 0.053 +/- 0.005 06-19-13 361 0.016 +/- 0.003 12-18-13 335 0.052 +/- 0.004 06-26-13 345 0.022 +/- 0.003 12-26-13 337 0.052 +/- 0.004 07-03-13 353 0.017 +/- 0.003 01-02-14 293 0.056 +/- 0.005 2nd Quarter Mean +/- s.d. 0.020 +/- 0.005 4th Quarter Mean +/- s.d. 0.038 +/- 0.017 Cumulative Average 0.032 Previous Annual Averaae 0.031 a Iodine-131 concentrations are < 0.03 pCi/m 3 unless otherwise noted.
bND = No data; see Table 2.0, Listing of Missed Samples.
2-1
MNGP Table 3. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-131a.
Location: M-2 Units: pCi/m3 Collection: Continuous, weekly exchange.
Date Volume Date Volume Collected (m3) Gross Beta Collected (mi) Gross Beta Required LLD 0.010 0.010 01-09-13 339 0.063 +/- 0.005 07-10-13 381 0.027 +/- 0.003 01-16-13 327 0.038 +/- 0.004 07-17-13 384 0.024 +/- 0.003 01-23-13 329 0.044 +/- 0.004 07-24-13 381 0.018 +/- 0.003 01-30-13 351 0.048 +/- 0.004 07-31-13 353 0.015 +/- 0.003
- 02-06-13 352 0.074 +/- 0.005 08-06-13 332 0.019 +/- 0.003 02-13-13 353 0.031 +/- 0.003 08-14-13 403 0.016 +/- 0.003 02-20-13 353 0.033 +/- 0.003 08-21-13 347 0.043 +/- 0.004 02-27-13 353 0.034 +/- 0.003 08-28-13 354 0.036 +/- 0.004 03-06-13 343 0.023 +/- 0.003 09-04-13 353 0.022 +/- 0.003 03-14-13 401 0.026 +/- 0.003 09-11-13 351 0.040 +/- 0.004 03-20-13 304 0.034 +/- 0.004 09-18-13 355 0.018 +/- 0.003 03-27-13 352 0.017 +/- 0.003 09-25-13 351 0.025 +/- 0.004 04-03-13 325 0.025 +/- 0.003 10-02-13 353 0.031 +/- 0.004 1st Quarter Mean +/- s.d. 0.038 +/- 0.016 3rd Quarter Mean +/- s.d. 0.026 +/- 0.009 04-10-13 329 0.025 +/- 0.003 10-09-13 352 0.018 +/- 0.003 04-17-13 349 0.007 +/- 0.002 10-16-13 332 0.023 +/- 0.003 04-24-13 356 0.019 +/- 0.003 10-23-13 321 0.014 +/- 0.003 05-01-13 413 0.023 +/- 0.003 10-30-13 325 0.016 +/- 0.003 05-08-13 414 0.011 +/- 0.002 11-06-13 356 0.029 +/- 0.003 05-15-13 405 0.022 +/- 0.003 11-13-13 352 0.029 +/- 0.003 05-22-13 284 0.016 +/- 0.003 11-21-13 404 0.035 +/- 0.003 05-29-13 382 0.016 +/- 0.003 11-27-13 302 NDb 12-03-13 305 0.059 +/- 0.005 06-05-13 385 0.014 +/- 0.003 06-12-13 387 0.019 +/- 0.003 12-10-13 352 0.044 +/- 0.004 06-19-13 405 0.014 +/- 0.003 12-18-13 370 0.047 +/- 0.004 06-26-13 355 0.020 +/- 0.003 12-26-13 373 0.043 +/- 0.004 07-03-13 411 0.015 +/- 0.003 01-02-14 332 0.048 +/- 0.004 2nd Quarter Mean +/- s.d. 0.017 +/- 0.005 4th Quarter Mean +/- s.d. 0.034 +/- 0.015 Cumulative Average 0.028 Previous Annual Averagqe 0.031 3w a Iodine-131 concentrations are < 0.03 pCi/m3 unless otherwise noted.
b ND = No data; see Table 2.0, Listing of Missed Samples.
3-1
MNGP Table 4. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-131a.
Location: M-3 3 Units: pCi/m Collection: Continuous, weekly exchange.
Date Volume Date Volume Collected (mi) Gross Beta Collected (mi) Gross Beta Required LLD 0.010 0.010 01-09-13 326 0.074 +/- 0.005 07-10-13 353 0.033 +/- 0.004 01-16-13 326 0.042 +/- 0.004 07-17-13 384 0.026 +/- 0.003 01-23-13 329 0.043 +/- 0.004 07-24-13 322 0.020 +/- 0.003 01-30-13 351 0.045 +/- 0.004 07-31-13 353 0.014 +/- 0.003 02-06-13 352 0.048 +/- 0.004 08-06-13 334 0.019 +/- 0.003 02-13-13 353 0.029 +/- 0.003 08-14-13 403 0.018 +/- 0.003 02-20-13 353 0.034 +/- 0.003 08-21-13 348 0.045 +/- 0.004 02-27-13 353 0.031 +/- 0.003 08-28-13 354 0.032 +/- 0.004 03-06-13 352 0.021 +/- 0.003 09-04-13 353 0.019 +/- 0.003 03-13-13 350 0.025 +/- 0.003 09-11-13 381 0.038 +/- 0.004 03-20-13 354 0.032 +/- 0.003 09-18-13 355 0.019 +/- 0.003 03-27-13 351 0.020 +/- 0.003 09-25-13 352 0.022 +/- 0.003 04-03-13 354 0.025 +/- 0.003 10-02-13 383 0.028 +/- 0.003 1st Quarter Mean +/- s.d. 0.036 +/- 0.015 3rd Quarter Mean +/- s.d. 0.026 +/- 0.009 04-10-13 359 0.025 +/- 0.003 10-09-13 352 0.017 +/- 0.003 04-17-13 378 0.007 +/- 0.002 10-16-13 360 0.023 +/- 0.003 04-24-13 357 0.023 +/- 0.003 10-23-13 348 0.015 +/- 0.003 05-01-13 383 0.020 +/- 0.003 10-30-13 352 0.013 +/- 0.003 05-08-13 385 0.011 +/- 0.002 11-06-13 356 0.031 +/- 0.003 05-15-13 375 0.021 +/- 0.003 11-13-13 352 0.028 +/- 0.003 05-22-13 .354 0.014 +/- 0.003 11-21-13 439 0.031 +/- 0.003 05-29-13 350 0.014 +/- 0.003 11-27-13 302 0.024 +/- 0.003 12-03-13 305 0.056 +/- 0.005 06-05-13 356 0.014 +/- 0.003 06-12-13 357 0.019 +/- 0.003 12-10-13 352 0.041 +/- 0.004 06-19-13 376 0.014 +/- 0.003 12-18-13 401 0.039 +/- 0.003 06-26-13 444 0.017 +/- 0.002 12-26-13 370 0.046 +/- 0.004 07-03-13 353 0.021 +/- 0.003 01-02-14 352 0.044 +/- 0.004 2nd Quarter Mean +/- s.d. 0.017 +/- 0.005 4th Quarter Mean +/- s.d. 0.031 +/- 0.013 Cumulative Average 0.027 Previous Annual Averaae 0.031 a Iodine-131 concentrations are < 0.03 pCi/m3 unless otherwise noted.
4-1
MNGP Table 5. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-131a.
Location: M-4 3 Units: pCi/m Collection: Continuous, weekly exchange.
Date Volume Date Volume 3 3 Collected (M ) Gross Beta Collected (M ) Gross Beta Required LLD 0.010 0.010 01-09-13 353 0.065 +/- 0.005 07-10-13 369 0.034 +/- 0.003 01-16-13 327 .0O39 +/- 0.004 07-17-13 408 0.029 +/- 0.003 01-23-13 356 0.040 +/- 0.004 07-24-13 438 0.021 +/- 0.003 01-30-13 321 0.049 +/- 0.004 07-31-13 383 0.017 +/- 0.003 02-06-13 353 0&051 +/- 0.004 08-06-13 308 0.022 +/- 0.003 02-13-13 353 0.029 +/- 0.003 08-14-13 403 0.019 +/- 0.003 02-20-13 353 0.040 +/- 0.004 08-21-13 348 0.040 +/- 0.004 02-27-13 382 0.034 +/- 0.003 08-28-13 354 0.034 +/- 0.004 03-06-13 381 0.024 +/- 0.003 09-04-13 353 0.018 +/- 0.003 03-13-13 379 0.024 +/- 0.003 09-11-13 351 0.036 +/- 0.004 03-20-13 354 0.043 +/- 0.004 09-18-13 355 0.017 +/- 0.003 03-27-13 320 0.027 +/- 0.003 09-25-13 322 0.023 +/- 0.004 04-03-13 383 0.026 +/- 0.003 10-02-13 383 0.028 +/- 0.003 1st Quarter Mean +/- s.d. 0.038 +/- 0.012 3rd Quarter Mean +/- s.d. 0.026 +/- 0.008 04-10-13 389 0.030 +/- 0.003 10-09-13 323 0.020 +/- 0.003 04-17-13 406 0.010 +/- 0.002 10-16-13 329 0.022 +/- 0.003 04a24-13 354 0.025 +/- 0.003 10-23-13 319 0.014 +/- 0.003 05-01-13 445 0.022 +/- 0.003 10-30-13 323 0.012 +/- 0.003 05-08-13 473 0.012 +/- 0.002 11-06-13 356 0.031 +/- 0.003 05-15-13 435 0.020 +/- 0.003 11-13-13 352 0.027 +/- 0.003 05-22-13 440 0.012 +/- 0.002 11-21-13 371 0.033 +/- 0.003 05-29-13 469 0.015 +/- 0.002 11-27-13 302 0.024 +/- 0.003 12-03-13 331 0.047 +/- 0.004 06-05-13 472 0.014 +/- 0.002 06-12-13 478 0.017 +/- 0.002 12-10-13 323 0.049 +/- 0.004 06-19-13 462 0.013 +/- 0.002 12-18-13 402 0.038 +/- 0.003 06-26-13 385 0.024 +/- 0.003 12-26-13 370 0.043 +/- 0.004 07-03-13 470 0.011 +/- 0.002 01-02-14 323 0.050 +/- 0.004 2nd Quarter Mean +/- s.d. 0.017 +/- 0.006 4th Quarter Mean +/- s.d. 0.032 +/- 0.013 Cumulative Average 0.028 Previous Annual Average 0.033 a Iodine-131 concentrations are < 0.03 pCi/m3 unless otherwise noted.
5-1
MNGP Table 6. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-131a.
Location: M-53 Units: pCi/m Collection: Continuous, weekly exchange.
Date Volume Date Volume Collected (ms) Gross Beta Collected (mi) Gross Beta Required LLD 0.010 0.010 01-09-13 324 0.074. +/- 0.005 07-10-13 323 0.034 +/- 0.004 01-16-13 295 0.046 +/- 0.004 07-17-13 325 0.028 +/- 0.004 01-23-13 352 0.040 +/- 0.004 07-24-13 318 0.024 +/- 0.003 01-30-13 295 0.053 +/- 0.005 07-31-13 357 0.014 +/- 0.003 02-06-13 294 0.065 +/- 0.005 08-06-13 308 0.022 +/- 0.003 02-13-13 323 0.035 +/- 0.004 08-14-13 403 0.018 +/- 0.003 02-20-13 323 0.037 +/- 0.004 08-21-13 348 0.041 +/- 0.004 02-27-13 324 0.036 +/- 0.004 08-28-13 354 0.034 +/- 0.004 03-06-13 322 0.024 +/- 0.003 09-04-13 353 0.019 +/- 0.003 03-13-13 306 0.027 +/- 0.004 09-11-13 352 0.040 +/- 0.004 03-20-13 295 0.044 +/- 0.004 09-18-13 355 0.018 +/- 0.003 03-27-13 322 0.026 +/- 0.003 09-25-13 322 0.025 +/- 0.004 04-03-13 295 0.031 +/- 0.004 10-02-13 324 0.034 +/- 0.004 1st Quarter Mean +/- s.d. 0.041 +/- 0.015 3rd Quarter Mean +/- s.d. 0.027 +/- 0.009 04-10-13 329 0.030 +/- 0.003 10-09-13 322 0.019 +/- 0.003 04-17-13 290 0.010 +/- 0.003 10-16-13 329 0.023 +/- 0.003 04-24-13 324 0.023 +/- 0.003 10-23-13 318 0.016 +/- 0.003 05-01-13 327 0.026 +/- 0.003 10-30-13 324 0.018 +/- 0.003 05-08-13 354 0.013 +/- 0.003 11-06-13 356 0.031 +/- 0.003 05-15-13 319 0.025 +/- 0.004 11-13-13 352 0.028 +/- 0.003 05-22-13 324 0.015 +/- 0.003 11-21-13 337 0.050 +/- 0.004 05-29-13 322 0.019 +/- 0.003 11-27-13 302 0.026 +/- 0.004 12-03-13 302 0.058 +/- 0.005 06-05-13 355 0.016 +/- 0.003 06-12-13 328 0.019 +/- 0.003 12-10-13 325 0.055 +/- 0.005 06-19-13 318 0.017 +/- 0.003 12-18-13 368 0.047 +/- 0.004 06-26-13 355 0.022 +/- 0.003 12-26-13 370 0.047 +/- 0.004 07-03-13 323 0.018 +/- 0.003 01-02-14 323 0.050 +/- 0.004 2nd Quarter Mean +/- s.d. 0.019 +/- 0.006 4th Quarter Mean +/- s.d. 0.036 +/- 0.015 Cumulative Average 0.031 Previous Annual Average 0.032
' Iodine-131 concentrations are < 0.03 pCi/m 3 unless otherwise noted.
6-1
MNGP Table 7. Airborne particulate data, gross beta analyses, monthly averages, minima and maxima.
January April Location Average Minima Maxima Location Average Minima Maxima Control 0.056 0.043 0.063 Control 0.022 0.011 0.029 M-1 0.056 0.043 0.063 . M-1 0.022 0.011 0.029 Indicators 0.050 0.038 0.074 Indicators 0.020 0.007 0.030 M-2 0.048 .0.038 0.063 M-2 0.018 0.007 0.025 M-3 0.051 0.042 0.074 M-3 0.019 0.007 0.025 M-4 0.048 0.039 0.065 M-4 0.022 0.010 0.030 M-5 0.053 0.040 0.074 M-5 0.022 0.010 0.030 February May Location Average Minima Maxima Location Average Minima Maxima Control 0.045 0.032 0.070 Control 0.019 0.015 0.024 M-1 0.045 0.032 0.070 M-1 0.019 0.015 0.024 Indicators 0.040 0.029 0.074 Indicators 0.016 0.011 0.025 M-2 0.043 0.031 0.074 M-2 0.016 0.011 0.022 M-3 0.036 0.029 0.048 M-3 0.015 0.011 0.021 M-4 0.039 0.029 0.051 M-4 0.015 0.012 0.020 M-5 0.043 0.035 0.065 M-5 0.018 0.013 0.025 March June Location Average Minima Maxima Location Average Minima Maxima Control 0.029 0.024 0.034 Control 0.019 0.016 0.023 M-1 0.029 0.024 0.034 M-1 0.019 0.016 0.023 Indicators 0.027 0.017 0.044 Indicators 0.017 0.011 0.024 M-2 0.025 0.017 0.034 M-2 0.016 0.014 0.020 M-3 0.024 0.020 0.032 M-3 0.017 0.014 0.021 M-4 0.029 0.024 0.043 M-4 0.016 0.011 0.024 M-5 0.030 0.024 0.044 M-5 0.018 0.016 0.022 Note: unless otherwise specified, samples collected on the first, second or third day of the month are grouped With data of the previous month.
7-1
MNGP Table 7. Airborne particulate data, gross beta analyses, monthly averages, minima and maxima.
July October Location Average Minima Maxima Location Average Minima Maxima Control 0.023 0.016 0.029 Control 0.020 0.015 0.029 M-1 0.023 0.016 0.029 M-1 0.020 0.015 0.029 Indicators 0.024 0.014 0.034 Indicators 0.018 0.012 0.023 M-2 0.021 0.015 0.027 M-2 0.018 0.014 0.023 M-3 0.023 0.014 0.033 M-3 0.017 0.013 0.023 M-4 0.025 0.017 0.034 M-4 0.017 0.012 0.022 M-5 0.025 0.014 0.029 M-5 0.019 0.016 0.023 August November Location Average Minima Maxima Location Average Minima Maxima Control 0.034 0.020 0.052 Control 0.041 0.028 0.070 M-1 0.034 0.020 0.052 M-1 0.041 0.028 0.070 Indicators 0.029 0.016 0.045 Indicators 0.034 0.024 0.058 M-2 0.028 0.016 0.043 M-2 0.031 0.029 0.035 M-3 0.029 0.018 0.045 M-3 0.034 0.024 0.056 M-4 0.029 0.019 0.040 M-4 0.032 0.024 0.047 M-5 0.029 0.018 0.041 M-5 0.039 0.026 0.058 September December Location Average Minima Maxima Location Average Minima Maxima Control 0.030 0.022 0.043 Control 0.053 0.052 0.056 M-1 0.030 0.022 0.043 M-1 0.053 0.052 0.056 Indicators 0.026 0.017 0.040 Indicators 0.046 0.038 0.059 M-2 0.027 0.018 0.040 M-2 0.048 0.043 0.059 M-3 0.025 0.019 0.038 M-3 0.042 0.039 0.046 M-4 0.024 0.017 0.036 M-4 0.045 0.038 0.050 MW5 0.027 0.018 0.040 M-5 0.050 0.047 0.055 Note: unless otherwise specified, samples collected on the first, second or third day of the month are grouped with data of the previous month.
7-2
MNGP Table 8. Airborne particulates, quarterly composites from each location, analysis for gamma-emitting isotopes.
Activity (pCi/m 3 )
Cumulative Previous 1st Qtr. 2nd Qtr. 3rd Qtr. 4th Qtr. Average Average M-1 (C)
Lab Code MAP- 2050 MAP- 4068 MAP- 6372 MAP- 7860 3
Volume(m ) 3848 3963 4429 4032 Be-7 0.092 +/- 0.010 0.078 +/- 0.014 0.065 +/- 0.012 0.046 +/- 0.011 0.067 0.064 Mn-54 < 0.0003 < 0.0007 < 0.0009 < 0.0005 <0.0009 <0.0007 Co-58 < 0.0004 < 0.0006 < 0.0006 < 0.0003 <0.0006 <0.0007 Co-60 < 0.0003 < 0.0007 < 0.0007 < 0.0003 <0.0007 <0.0009 Zn-65 < 0.0004 < 0.0011 < 0.0015 < 0.0005 <0.0015 <0.0009 Zr-Nb-95 < 0.0007 < 0.0012 < 0.0008 < 0.0006 <0.0012 <0.0011 Ru-103 < 0.0006 < 0.0007 < 0.0007 < 0.0010 <0.0007 <0.0010 Ru-1 06 < 0.0042 < 0.0091 < 0.0075 < 0.0026 <0.0091 <0.0056 Cs-1 34 < 0.0005 < 0.0005 < 0.0008 < 0.0007 <0.0008 <0.0006 Cs-1 37 < 0.0004 < 0.0010 < 0.0007 < 0.0005 <0.0010 <0.0008 Ba-La-140 < 0.0013 < 0.0019 < 0.0022 < 0.0019 <0.0022 <0.0011 Ce-141 < 0.0012 < 0.0015 < 0.0016 < 0.0014 <0.0016 <0.0014 Ce-1 44 < 0.0025 < 0.0044 < 0.0050 < 0.0037 <0.0050 <0.0037 M-2 Lab Code MAP- 2051 MAP- 4069 MAP- 6373 MAP- 7861 Volume(m 3) 4479 4874 4697 4475 Be-7 0.064 +/- 0.011 0.080 +/- 0.012 0.078 +/- 0.013 0.046 +/- 0.012 0.062 0.064 Mn-54 < 0.0008 < 0.0005 < 0.0007 < 0.0008 <0.0008 <0.0006 Co-58 < 0.0007 < 0.0006 < 0.0004 < 0.0005 <0.0007 <0.0006 Co-60 < 0.0005 < 0.0004 < 0.0008 < 0.0006 <0.0008 <0.0005 Zn-65 < 0.0009 < 0.0004 < 0.0004 < 0.0013 <0.0009 <0.0008 Zr-Nb-95 < 0.0011 < 0.0006 < 0.0009 < 0.0008 <0.0011 <0.0007 Ru-103 < 0.0008 < 0.0007 < 0.0006 < 0.0009 <0.0008 <0.0009 Ru-1 06 < 0.0052 < 0.0059 < 0.0061 < 0.0070 <0.0061 <0.0056 Cs-1 34 < 0.0006 < 0.0007 < 0.0007 < 0.0008 <0.0007 <0.0007 Cs-1 37 < 0.0006 < 0.0006 < 0.0005 < 0.0007 <0.0006 <0.0006 Ba-La-140 < 0.0019 < 0.0009 < 0.0020 < 0.0015 <0.0020 <0.0012 Ce-141 < 0.0010 < 0.0012 < 0.0014 < 0.0010 <0.0014 <0.0012 Ce-144 < 0.0032 < 0.0040 < 0.0041 < 0.0032 <0.0041 <0.0040 8-1
MNGP Table 8. Airborne particulates, quarterly composites from each location, analysis for gamma-emitting isotopes.
Activity (pCi/m 3 )
Cumulative Previous 1st Qtr. 2nd Qtr. 3rd Qtr. 4th Qtr. Average Average M-3 Lab Code MAP- 2052 MAP- 4070 MAP- 6374 MAP- 7862 3
Volume(m ) 4503 4826 4673 4641 Be-7 0.068 +/- 0.016 0.067 +/- 0.010 0.066 +/- 0.011 0.042 +/- 0.010 0.059 0.065 Mn-54 < 0.0007 < 0.0003 < 0.0005 < 0.0004 <0.0007 <0.0007 Co-58 < 0.0006 < 0.0005 < 0.0005 < 0.0004 <0.0006 <0.0006 Co-60 < 0.0003 < 0.0003 < 0.0005 < 0.0005 <0.0005 <0.0007 Zn-65 < 0.0006 < 0.0013 < 0.0010 < 0.0007 <0.0013 <0.0010 Zr-Nb-95 < 0.0006 < 0.0008 < 0.0011 < 0.0007 <0.0011 <0.0008 Ru-1 03 < 0.0007 < 0.0006 < 0.0008 < 0.0006 <0.0008 <0.0009 Ru-1 06 < 0.0024 < 0.0037 < 0.0057 < 0.0027 <0.0057 <0.0057 Cs-134 < 0.0004 < 0.0003 < 0.0007 < 0.0006 0.0013 0.0013 Cs-1 37 < 0.0005 < 0.0005 < 0.0006 < 0.0007 0.0014 0.0014 Ba-La-140 < 0.0019 < 0.0009 < 0.0011 < 0.0018 <0.0019 <0.0018 Ce-141 < 0.0018 < 0.0008 < 0.0014 < 0.0010 <0.0018 <0.0013 Ce-144 < 0.0038 < 0.0027 < 0.0034 < 0.0031 <0.0038 <0.0036 M-4 Lab Code MAP- 2053 MAP- 4071 MAP- 6375 MAP- 7863 3
Volume(m ) 4613 5679 4776 4423 Be-7 0.069 +/- 0.015 0.066 +/- 0.009 0.074 +/- 0.012 0.045 +/- 0.010 0.063 0.068 Mn-54 < 0.0007 < 0.0004 < 0.0005 < 0.0005 <0.0007 <0.0007 Co-58 < 0.0005 < 0.0004 < 0.0005 < 0.0005 <0.0005 <0.0005 Co-60 < 0.0004 < 0.0004 < 0.0003 < 0.0008 <0.0004 <0.0006 Zn-65 < 0.0006 < 0.0006 < 0.0006 < 0.0006 <0.0006 <0.0010 Zr-Nb-95 < 0.0007 < 0.0005 < 0.0006 < 0.0007 <0.0007 <0.0010 Ru-103 < 0.0006 < 0.0007 < 0.0006 < 0.0004 <0.0007 <0.0011 Ru-1 06 < 0.0038 < 0.0035 < 0.0066 < 0.0060 <0.0066 <0.0067 Cs-1 34 < 0.0004 < 0.0004 < 0.0006 < 0.0006 <0.0006 <0.0008 Cs-1 37 < 0.0003 < 0.0005 < 0.0003 < 0.0003 <0.0005 <0.0008 Ba-La-140 < 0.0019 < 0.0008 < 0.0014 < 0.0012 <0.0019 <0.0022 Ce-141 < 0.0012 < 0.0010 < 0.0009 < 0.0011 <0.0012 <0.0012 Ce-144 < 0.0034 < 0.0026 < 0.0033 < 0.0026 <0.0034 <0.0045 8-2
MNGP Table 8. Airborne particulates, quarterly composites from each location, analysis for gamma-emitting isotopes.
Activity (pCi/m 3 )
Cumulative Previous 1st Qtr. 2nd Qtr. 3rd Qtr. 4th Qtr. Average Average M-5 Lab Code MAP- 2054 MAP- 4073 MAP- 6376 MAP- 7864 Volume(m 3) 4071 4268 4441 4330 Be-7 0.088 +/- 0.013 0.074 +/- 0.017 0.081 +/- 0.012 0.047 +/- 0.012 0.072 0.068 Mn-54 < 0.0008 < 0.0011 < 0.0006 < 0.0007 <0.0011 <0.0009 Co-58 < 0.0003 < 0.0007 < 0.0009 < 0.0006 <0.0009 <0.0007 Co-60 < 0.0005 < 0.0007 < 0.0003 < 0.0007 <0.0007 <0.0007 Zn-65 < 0.0009 < 0.0012 < 0.0005 < 0.0014 <0.0012 <0.0015 Zr-Nb-95 < 0.0010 < 0.0008 < 0.0008 < 0.0013 <0.0010 <0.0013 Ru-103 < 0.0012 < 0.0007 < 0.0008 < 0.0009 <0.0012 <0.0009 Ru-1 06 < 0.0054 < 0.0044 < 0.0056 < 0.0066 <0.0056 <0.0068 Cs-1 34 < 0.0006 < 0.0006 < 0.0006 < 0.0008 <0.0006 <0.0007 Cs-1 37 < 0.0004 < 0.0006 < 0.0003 < 0.0007 <0.0006 <0.0007 Ba-La-140 < 0.0013 < 0.0018 < 0.0015 < 0.0011 <0.0018 <0.0013 Ce-141 < 0.0010 < 0.0019 < 0.0013 < 0.0016 <0.0019 <0.0013 Ce-144 < 0.0038 < 0.0048 < 0.0027 < 0.0033 <0.0048 <0.0038 8-3
MNGP Table 9. Pasture grass, vegetation, analysis for gamma-emitting isotopes.
Collection: 3x per year Previous Sample Description and Concentration (pCi/g wet) Annual Annual Average Average Location: M-41 (Training Center)
Date Collected 07-24-13 08-14-13 09-27-13 Lab Code MVE- 4234 MVE- 4830 MVE- 5758 Mn-54 < 0.008 < 0.010 < 0.007 < 0.010 < 0.009 Fe-59 < 0.018 < 0.026 < 0.014 < 0026 < 0.027 Co-58 < 0.011 < 0.007 < 0.008 < 0.011 < 0.008 Co-60 < 0.009. < 0.011 < 0.006 < 0.011 < 0.011 Zn-65 < 0.020 < 0.026 < 0.018 < 0.026 < 0.025 Nb-95 < 0.017 < 0.019 < 0.009 < 0.019 < 0.014 1-131 < 0.025 < 0.022 < 0.034 < 0.034 < 0.044 Cs-134 < 0.009 < 0.011 < 0.008 <0.011 <0.010 Cs-137 < 0.017 < 0.016 < 0.011 <0.017 <0.010 Location: M-42 (Biology Station Road)
Date Collected 07-24-13 08-14-13 09-27-13 Lab Code MVE- 4235 MVE- 4831 MVE- 5759 Mn-54 < 0.014 < 0.009 < 0.009 <0.014 <0.011 Fe-59 < 0.019 < 0.022 < 0.022 < 0.022 < 0.023 Co-58 < 0.012 < 0.013 < 0.009 < 0.013 < 0.010 Co-60 < 0.014 < 0.012 < 0.009 < 0.014 < 0.010 Zn-65 < 0.031 < 0.022 < 0.012 < 0.031 < 0.022 Nb-95 < 0.014 < 0.017 < 0.011 <0.017 <0.011 1-131 < 0.034 < 0.030 < 0.028 < 0.034 < 0.034 Cs-134 < 0.016 < 0.011 < 0.009 <0.016 <0.009 Cs-137 < 0.017 < 0.017 < 0.010 <0.017 <0.014 Location: M-43 (Imholte Farm, Control)
Date Collected 07-24-13 08-14-13 09-27-13 Lab Code MVE- 4236 MVE- 4832 MVE- 5760 Mn-54 < 0.009 < 0.016 < 0.009 < 0.016 < 0.010 Fe-59 < 0.017 < 0.018 < 0.016 < 0.018 < 0.031 Co-58 < 0.011 < 0.014 < 0.008 < 0.014 < 0.008 Co-60 < 0.010 < 0.011 < 0.007 <0.011 <0.012 Zn-65 < 0.022 < 0.021 < 0.012 < 0.022 < 0.030 Nb-95 < 0.010 < 0.015 < 0.015 <0.015 <0.011 1-131 < 0.021 < 0.026 < 0.031 < 0.031 < 0.031 Cs-134 < 0.010 < 0.016 < 0.010 <0.016 <0.009 Cs-137 < 0.012 < 0.016 < 0.009 <0.016 <0.013 9-1
MNGP' Table 10. River water, analysis of monthly composites for gamma-emitting isotopes.
Location: M-8 (C)
Collection: Weekly Sample Description and Concentration (pCi/L)
Period Collected January February March April May Lab Code NSa NSa NSa MSW-2519 MSW-3271 Mn-54 <10 <10 Fe-59 < 30 < 30 Co-58 <10 <10 Co-60 <10 <10 Zn-65 < 30 < 30 Zr-Nb-95 <15 <15 Cs-1 34 <10 <10 Cs-1 37 <10 <10 Ba-La-140 <15 <15 Ce-144 <14 <21 Period Collected June July August September October Lab Code MSW-3889 MSW-4907 MSW-5153 MSW-6174 MSW-6961 Mn-54 <10 <10 <10 <10 <10 Fe-59 < 30 < 30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 <10 Co-60 <10 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 <15 <15 Cs-1 34 <10 <10 <10 <10 <10 Cs-137 <10 <10 <10 <10 <10 Ba-La-140 <15 <15 <15 <15 <15 Ce-144 <14 < 20 < 23 < 26 < 23 Previous b
Period Collected November December Cumulative Annual Lab Code MSW-7532 NSa Average Average Mn-54 <10 <10 <10 Fe-59 < 30 < 30 < 30 Co-58 <10 <10 <10 Co-60 <10 <10 <10 Zn-65 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 Cs-1 34 <10 <10 <10 Cs-137 <10 <10 <10 Ba-La-140 <15 <15 <15 Ce-144 <10 < 26 < 24 a "NS" = No sample; see Table 2.0, Listing of Missed Samples.
b Composite of three samples for month; water frozen on 11-27-13.
10-1
MNGP Table 10. River water, analysis of monthly composites for gamma-emitting isotopes.
Location: M-9 Collection: Weekly Sample Description and Concentration (pCi/L)
Period Collected January February March April May Lab Code MSW-583 MSW-1234 MSW-1577 MSW-2520 MSW-3272 Mn-54 <10 <10 <10 <10 <10 Fe-59 < 30 < 30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 <10 Co-60 <10 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 <15 <15 Cs-1 34 <10 <10 <10 <10 <10 Cs-1 37 <10 <10 <10 <10 <10 Ba-La-140 <15 <15 <15 <15 <15 Ce-144 <21 < 28 <17 < 24 <17 Period Collected June July August September October Lab Code MSW-3890 MSW-4908 MSW-5154 MSW-6175 MSW-6962 Mn-54 <10 <10 <10 < 10 < 10 Fe-59 < 30 <30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 < 10 Co-60 <10 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 < 15 < 15 Cs-134 <10 <10 <10 <10 <10 Cs-137 <10 <10 <10 < 10 <10 Ba-La-140 <15 <15 <15 <15 <15 Ce-144 <13 < 22 < 20 < 29 < 23 Previous Period Collected November December Cumulative Annual Lab Code MSW-7533 MSW-7694 Average Average Mn-54 <10 <10 <10 <10 Fe-59 < 30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 Co-60 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 <15 Cs-134 <10 <10 <10 <10 Cs-137 <10 <10 <10 <10 Ba-La-140 <15 <15 <15 <15 Ce-144 <16 < 25 < 29 <31 10-2
MNGP Table 11. Drinking water, City of Minneapolis, M-14, analysis of monthly composites for gross beta, iodine-131, and gamma-emitting isotopes.
Collection: Weekly Sample Description and Concentration (pCi/L)
Period Collected January a February March April May Lab Code MDW-483 MDW-1053 MDW-1573 MDW-2295 MDW-2865 Gross beta 2.7 +/- 0.8 2.7 +/- 0.8 b 2.3 +/- 0.9 2.7 +/- 0.7 3.0 +/- 1.0 1-131 < 1.0 <1.0 < 1.0 <1.0 < 1.0 Mn-54 <10 <10 <10 <10 <10 Fe-59 < 30 < 30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 <10 Co-60 <10 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 <15 <15 Cs-1 34 <10 <10 <10 <10 <10 Cs-1 37 <10 <10 <10 <10 <10 Ba-La-140 <15 <15 <15 <15 <15 Ce-144 < 23 <19 <14 < 25 < 51 Period Collected October June July August September Lab Code MDW-3894 MDW-4537 MDW-5329 MDW-5703 MDW-6918 Gross beta 2.5 +/- 1.0 2.9 +/- 1.0 1.5 +/- 0.6 2.1 +/-0.8 2.0 +/- 0.6 1-131 < 1.0 <1.0 < 1.0 < 1.0 < 1.0 Mn-54 <10 <10 <10 <10 <10 Fe-59 < 30 < 30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 <10 Co-60 <10 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 <15 <15 Cs-1 34 <10 <10 <10 <10 <10 Cs-1 37 <10 <10 <10 <10 <10 Ba-La-140 <15 <15 <15 <15 <15 Ce-144 < 28 <15 < 35 < 27 < 47 Cumulative Previous Period Collected November c December Lab Code MDW-7354 MDW-7695 Average Average Gross beta 3.2 +/- 0.8 2.6 +/- 1.0 2.6 2.2 1-131 < 1.0 < 1.0 <1.0 < 1.0 Mn-54 <10 <10 <10 <10 Fe-59 < 30 < 30 < 30 < 30 Co-58 <10 <10 <10 <10 Co-60 <10 <10 <10 <10 Zn-65 < 30 < 30 < 30 < 30 Zr-Nb-95 <15 <15 <15 <15 Cs-134 <10 <10 <10 <10 Cs-137 <10 <10 <10 <10 Ba-La-140 <15 <15 <15 <15 Ce-144 <31 < 29 < 51 < 36 a Composite of three samples for month; 01-21-13 sample lost in transit; container torn.
D Gross beta reanalyzed; previous result = 0.9+/-0.5 pCi/L.
c Composite of three samples for month; sample not obtained on 11-18-13.
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MNGP Table 12. River water and drinking water, analysis of quarterly composites for tritium.
Collection: Quarterly composites of weekly collections.
Sample Type, Location and Concentration (pCi/L)
Collection Period Lab Code H-3 River Water Upstream, M-8 (C) 1st Quarter NDa 2nd Quarter MSW - 3895 < 500 < 153 3rd Quarter MSW - 6180 < 500 < 155 4th Quarter MSW - 7696 < 500 < 150 Cumulative Average < 500 < 153 Previous Annual Average < 500 < 147 River Water Downstream, M-9 1st Quarter MSW -1578 < 500 < 182 2nd Quarter MSW - 3896 < 500 < 153 3rd Quarter MSW -6181 < 500 < 155 4th Quarter MSW - 7697 < 500 < 149 Cumulative Average < 500 < 160 Previous Annual Average < 500 < 147 Drinkinq Water Minneapolis, M-14 1st Quarter MDW - 1580 < 500 < 182 2nd Quarter MDW - 3897 < 500 < 153 3rd Quarter MDW - 6182 < 500 < 155 4th Quarter MDW - 7698 < 500 < 149 Cumulative Average < 500 < 160 Previous Annual Average < 500 < 147 a"ND"= No data; see Table 2.0, Listing of Missed Samples.
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MNGP Table 13. Well water, analysis for tritium and gamma-emitting isotopes.
Sample Description and Concentration (pCi/L)
O LO-Date H-3 - o o LO .* ý2 o2 9 L? L? C (0 z -
0 0 1 U U) C6 G Collected Lab Code (< 500 pCi/L) 2 uL 0 0 N N 0 0 M 0 Monticello (M-11) 1/23/2013 MWW-252 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 5/1/2013 MWW-2291 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 7/24/2013 MWW-4320 < 179 < 10 < 30 < 10 < 10 < 30 < 15 < 10 < 10 < 15 < 29 10/16/2013 MWW-6456 <147 <10 <30 <10 <10 <30 <15 <10 <10 <15 <18 Cumulative Averages <500 <10 -<30 <10 <10 <30 <15 <10 <10 <15 <29 Plant Well No. 1 (M-12) 1/23/2013 MWW-253 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 5/2/2013 MWW-2292 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <27 7/24/2013 MWW-4321 <179 <10 <30 <10 <10 <30 <15 <10 <10 <15 <20 10/16/2013 MWW-6457 <147 <10 <30 <10 <10 <30 <15 <10 <10 <15 <33 Cumulative Averages <500 <10 <30 <10 <10 <30 <15 <10 <10 <15 <33 Wise (M-27) 1/23/2013 NSa 5/2/2013 MWW-2293 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <16 7/24/2013 MWW-4322 <179 <10 <30 <10 <10 <30 <15 <10 <10 <15 <21 10/16/2013 MWW-6458 <147 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 Cumulative Averages <500 <10 <30 <10 <10 <30 <15 <10 <10 <15 <22 Imholte (M-43) Control 1/23/2013 MWW-254 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <21 5/1/2013 MWW-2294 <139 <10 <30 <10 <10 <30 <15 <10 <10 <15 <24 7/24/2013 MWW-4323 < 179 < 10 < 30 < 10 < 10 < 30 < 15 < 10 < 10 < 15 < 33 10/16/2013 MWW-6459 <147 <10 <30 <10 <10 <30 <15 <10 <10 <15 <57 Cumulative Averages <500 <10 <30 <10 <10 <30 <15 <10 <10 <15 <57 a "NS" = No sample, see Table 2.0, Listing of Missed Samples.
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MNGP Table 14. Fish, analysis of edible portions for gamma-emitting isotopes.
Collection: Semiannually Sample Description and Concentration (pCi/g wet) Cumulative Previous Average Average Upstream 1000' M-8 (C)
Date Collected 05-28-13 09-11-13 Lab Code MF- 2773 MF- 5475 Sample Type Carp K-40 2.99 +/- 0.40 3.38 +/- 0.38 3.19 3.36 Mn-54 < 0.013 < 0.010 < 0.013 < 0.018 Fe-59 < 0.034 < 0.037 < 0.037 < 0.055 Co-58 < 0.008 < 0.010 < 0.010 < 0.023 Co-60 < 0.013 < 0.009 < 0.013 < 0.022 Zn-65 < 0.011 < 0.030 < 0.030 < 0.037 Nb-95 < 0.010 < 0.030 < 0.030 < 0.027 Zr-95 < 0.026 < 0.036 < 0.036 < 0.035 Cs-1 34 < 0.006 < 0.015 < 0.015 < 0.018 Cs-I 37 < 0.012 < 0.015 < 0.015 < 0.020 Ba-La-140 < 0.019 < 0.089 < 0.089 < 0.067 Ce-144 < 0.091 < 0.060 < 0.091 < 0.107 Downstream 1000' M-9 Date Collected 05-28-13 09-11-13 Lab Code MF- 2774 MF- 5476 Sample Type Catfish K-40 2.91 +/- 0.37 3.64 +/- 0.47 3.27 3.34 Mn-54 < 0.012 < 0.016 < 0.016 < 0.017 Fe-59 < 0.026 < 0.078 < 0.078 < 0.052 Co-58 < 0.009 < 0.013 < 0.013 <:0.023 Co-60 < 0.013 < 0.019 < 0.019 < 0.013 Zn-65 < 0.017 < 0.026 < 0.026 < 0.030 Nb-95 < 0.012 < 0.042 < 0.042 < 0.021 Zr-95 < 0.019 < 0.033 < 0.033 < 0.039 Cs-134 < 0.005 < 0.018 < 0.018 < 0.014 Cs-137 < 0.013 < 0.021 < 0.021 < 0.017 Ba-La-140 < 0.018 < 0:168 < 0.168 < 0.043 Ce-144 < 0.078 < 0.090 < 0.090 < 0.100 14-1
MNGP Table 15. Algae or aquatic insects, analysis for gamma-emitting isotopes.
Collection: Semiannually Sample Description and Concentration (pCi/g wet) Cumulative Previous Average Average Upstream 1000' M-8 (C)a Date Collected 08-05-13 10-10-13 Lab Code MBO- 4493 MBO- 6147 Be-7 < 0.40 < 0.84 < 0.84 < 0.58 K-40 < 0.75 2.30 +/- 0.97 2.30 < 1.08 Mn-54 < 0.037 < 0.067 < 0.067 < 0.048 Fe-59 < 0.14 < 0.13 < 0.14 < 0.12 Co-58 < 0.053 < 0.073 < 0.073 < 0.068 Co-60 < 0.017 < 0.043 < 0.043 < 0.052 Zn-65 < 0.067 < 0.12 < 0.125 < 0.10 Zr-Nb-95 < 0.089 < 0.13 < 0.133 < 0.12 Ru-103 < 0.064 < 0.092 < 0.092 < 0.091 Ru-106 < 0.35 < 0.56 < 0.56 < 0.34 Cs-134 < 0.027 < 0.059 < 0.059 < 0.045 Cs-137 < 0.040 < 0.057 < 0.057 < 0.042 Ba-La-1 40 < 0.31 < 0.23 < 0.31 < 0.39 Ce-144 < 0.17 < 0.35 < 0.35 < 0.30 Downstream 1000' M-9 Date Collected 08-05-13 10-10-13 Lab Code MBO- 4494 MBO- 6148 Be-7 < 0.35 < 0.65 < 0.65 < 0.48 K-40 < 0.68 < 1.04 < 1.04 < 0.97 Mn-54 < 0.030 < 0.057 < 0.057 < 0.051 Fe-59 < 0.10 < 0.18 < 0.18 < 0.17 Co-58 < 0.050 < 0.074 < 0.074 < 0.072 Co-60 < 0.029 < 0.048 < 0.048 < 0.022 Zn-65 < 0.063 < 0.092 < 0.092 < 0.094 Zr-Nb-95 < 0.073 < 0.093 < 0.093 < 0.086 Ru-103 < 0.054 < 0.070 < 0.070 < 0.053 Ru-106 < 0.24 < 0.48 < 0.48 < 0.39 Cs-134 < 0.028 < 0.052 < 0.052 < 0.046 Cs-137 < 0.025 < 0.065 < 0.065 < 0.055 Ba-La-140 < 0.37 < 0.31 < 0.37 < 0.25 Ce-144 < 0.12 < 0.21 < 0.21 < 0.25 15-1
MNGP Table 16. Broadleaf vegetation, analysis for iodine-1 31.
Collection: Annually Sample Description and Concentration (pCi/g wet)
Location: Control (Cabbage)
Date Collected Lab Code NDa Mn-54 Fe-59 Co-58 Co-60 Zn-65 Nb-95 1-131 Cs-134 Cs-137 Location: M-27 (Cabbage)
Date Collected Lab Code ND a Mn-54 Fe-59 Co-58 Co-60 Zn-65 Nb-95 1-131 Cs-134 Cs-137 a ND = No data; sample not collected. No river irrigated crops within 5 mile radius.
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MNGP Table 17. Shoreline (SS) sediments, analysis for gamma-emitting isotopes.
Collection: Semiannually Sample Description and Concentration (pCi/g dry) Cumulative Previous Average Average Upstream 1000' M-8 (C)
Date Collected 08-05-13 10-10-13 Lab Code MSS- 4495 MSS- 6149 Be-7 < 0.23 < 0.15 < 0.23 <0.18 K-40 10.21 +/- 0.49 9.71 +/- 0.49 9.96 10.02 Mn-54 < 0.013 < 0.01.4 < 0.014 < 0.013 Fe-59 < 0.022 < 0.043 < 0.043 < 0.031 Co-58 < 0.017 < 0.015 < 0.017 < 0.016 Co-60 < 0.007 < 0.012 < 0.012 < 0.015 Zn-65 < 0.040 < 0.029 < 0.040 < 0.025 Nb-95 < 0.018 < 0.019 < 0.019 < 0.028 Zr-95 < 0.026 < 0.040 < 0.040 < 0.023 Ru-103 < 0.021 < 0.015 < 0.021 < 0.013 Ru-106 < 0.12 < 0.12 <0.12 < 0.06 Cs-1 34 < 0.011 < 0.011 < 0.011 < 0.010 Cs-137 < 0.016 < 0.014 < 0.016 < 0.014 Ba-La-140 < 0.078 < 0.068 < 0.078 < 0.044 Ce-144 < 0.071 < 0.088 < 0.088 <0.10 Downstream 1000' M-9 Date Collected 08-05-13 10-10-13 Lab Code MSS- 4496 MSS- 6150 Be-7 < 0.13 0.42 +/- 0.25 0.42 0.33 K-40 8.62 +/- 0.51 10.05 +/- 0.55 9.33 8.85 Mn-54 < 0.020 < 0.017 < 0.020 < 0.017 Fe-59 < 0.024 < 0.061 < 0.061 < 0.042 Co-58 < 0.017 < 0.024 < 0.024 < 0.019 Co-60 < 0.007 < 0.010 < 0.010 < 0.013 Zn-65 < 0.032 < 0.053 < 0.053 < 0.030 Nb-95 < 0.016 < 0.026 < 0.026 < 0.032 Zr-95 < 0.057 < 0.036 < 0.057 < 0.014 Ru-103 < 0.028 < 0.015 < 0.028 < 0.017 Ru-106 < 0.098 < 0.12 < 0.120 < 0.06 Cs-1 34 < 0.015 < 0.015 < 0.015 < 0.011 Cs-1 37 < 0.018 < 0.019 < 0.019 < 0.013 Ba-La-140 < 0.059 < 0.053 < 0.059 < 0.043 Ce-144 < 0.10 < 0.11 <0.11 < 0.081 17-1
MNGP Table 17. Shoreline (SS) sediments, analysis for gamma-emitting isotopes (continued).
Sample Description and Concentration (pCi/g dry) Cumulative Cumulative Average Average Montissippi Park M-15 Date Collected 08-05-13 10-10-13 Lab Code MSS- 4497 MSS- 6151 Be-7 < 0.24 0.27 +/- 0.16 0.27 1.09 K-40 10.92 +/- 0.56 10.23 +/- 0.51 10.58 10.82 Mn-54 < 0.012 < 0.017 <0.017 <0.020 Fe-59 < 0.040 < 0.041 <0.041 <0.030 Co-58 < 0.018 < 0.022 <0.022 <0.026 Co-60 < 0.007 < 0.012 <0.012 <0.016 Zn-65 < 0.035 < 0.036 <0.036 <0.035 Nb-95 < 0.025 < 0.028 <0.028 <0.026 Zr-95 < 0.019 < 0.029 <0.029 <0.020 Ru-103 < 0.024 < 0.023 <0.024 <0.027 Ru-106 < 0.083 < 0.13 < 0.126 < 0.14 Cs-134 < 0.014 < 0.011 <0.014 <0.014 Cs-1 37 0.049 +/- 0.025 0.022 +/- 0.013 0.035 0.081 Ba-La-140 < 0.11 < 0.084 < 0.11 <0.059 Ce-144 < 0.070 < 0.13 <0.13 < 0.12 17-2