Text

Radioactive Effluent Release Report
	ML061240069
Person / Time
Site:	Crystal River
Issue date:	04/20/2006
From:	Pinner R; Progress Energy Florida
To:	; Office of Nuclear Reactor Regulation
References
	3F0406-05
	Download: ML061240069 (17)
	v • d • e

PROGRESS ENERGY FLORIDA, INC.

CRYSTAL RIVER UNIT 3 DOCKET NUMBER 50-302 / LICENSE NUMBER DPR-72 ATTACHMENT A RADIOACTIVE EFFLUENT RELEASE REPORT 2005

RADIOACTIVE EFFILUENT RELEASE REPORT 2005 PROGRESS ENERGY FLORIDA, INC.

CRYSTAL RIVER UNIT 3 Facility Operating License No. DPR-72 Docket No. 50-302 Prepared By:

Sr. Science Znd Lab Services Specialist Approved By: 402& A l n Superintendent Chernistry Date: &i x-,b° 6

CONTENTS Introduction 1

...............................................................................................

Tabular Data Summaries Gaseous Effluents - Quarters I & 2 . ....................................................... 2 Gaseous Effluents - Quarters 3 & 4 . ....................................................... 4 Liquid Effluents - Quarters 1 & 2 .......................................................... 6 Liquid Effluents - Quarters 3 & 4 .......................................................... 9 Radwaste Shipments ................................................................ 12 Unplanned Releases...................................................................................... 13 Radioactive Waste Treatment Systems ................................................................ 13 Annual Land Use Census ....................... ........................................ 13 Effluent Monitor Instrument Operability ............................................................. 13 ODCM & PCP Changes ........................ ........................................ 13 Emergency Feed Pump 2 ............................................................... 13 Appendix I Dose Summary ............................. ................................... 14

INTRODUCTION This report is submitted as required by the Offsite Dose Calculation Manual, section 6.5, and Technical Specfications 5.6.2.3.3 and 5.7.l.1.c.

The scope of this report includes:

A summary of the quantities of radioactive liquid and gaseous effluents and solid waste released from the plant.

Quarterly and annual dose summaries.

A list and description of unplanned releases to unrestricted areas.

A description of any changes to the:

Process Control Program (PCP), and Offsite Dose Calculation Manual (ODCM).

Significant changes to any radioactive waste treatment system.

A list of new dose calculation location changes identified by the annual land-use census.

Information relating to effluent monitors or required supporting instrumentation being inoperable for 30 or more days.

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TABLE 1 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Unit I Quarter I Quarter I Est. Total I I 1 2 Error %

A. Fission and activation gases

1. Total release Ci 5.61E+00 5.09E+OD 30il

2. Average release rate for period gCi/sec 7.21E-01 6.48E-01

3. Percent of technical specification limit % 7.89E-03 6.20E-03 B. Iodines

1. Total lodine-131 J Ci 9.65E-07 J O.OOE+00 J 30jl

2. Average release rate for period juCi/sec: 1.24E-07 J O.OOE+00

3. Percent of technical specification limit l % 1.12E-02 O.OOE+00 ]

C. Particulates*

1. Particulates with half-lives > 8 days Ci l 4.53E-O l 2.56E-08 J 30Il

2. Average release rate for period pCi/sec 5.83E-06 3.25E-09

3. Percent of technical specification limit % 1.12E02 2.611-03

4. Gross alpha radioactivity Ci 2.37E-10 1.12E.08 D. Tritium I1. Total release l 2. Average release rate for period l 3. Percent of technical specification limit

.

The sum of the particulates reported on thi particulates, while this table includes only i half-lives greater than 8 days.

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TABLE 2 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 GASEOUS EFFLUENTS - GROUND LEVEL RELEASES A. Fission gases Argon-41 Ci Krypton-85 Ci 3.95E+00 2.63E1+00 Krypton-85m Ci Krypton-87 Ci Krypton-88 Ci Xenon-131m Ci 1.70E-02 Xenon-133 Ci 4.55E-01 2.38E+00 Xenon-133m Ci 1.20E+00_ _ 1.17E-04 Xenon-135 Ci 1.51E-03 7.O1E-02 Xenon-135m Ci Xenon-138 Ci Total for period Ci 1.20E1+00 O.OOE +00 4.41E+00 5.09E1+00 B. lodines Iodine-131 Ci 9.65E-07 Iodine-132 Ci l lodine-133 Ci 5.65E-07 1.26E-06 _

Iodine-135 Ci Total for period Ci 1.53E-06 1.26E-06 O.OOE+00 O.OOE+00 C. Particulates Zinc-72 Ci l Cobalt-58* Ci Cobalt-60* Ci Strontium-89* Ci Strontium-90* Ci Niobium-95m Ci Technicium-99m Ci Tellurium-132 Ci Cesiun-134* Ci Cesium-137* Ci 2.20E-47 2.56E-08 Cesium-138 Ci Barium-139 Ci Lanthanum-142 Ci Cerium-141* Ci _

Cerium-143* Ci Rhenium-188 Ci Total for period Ci 2.20E-07 O.OOE+00 O.OOE+00 2.56E-08

> 8 day half-life 3

TABLE 3 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Unit Quarter Quarter Est. Total I I 1 3 1 4 l Error %

A. Fission and activation gases

1. Total release Ci 6.34E+00 3.02E+Ol 30

2. Average release rate for period sCi/sec 7.98E-01 3.80E+00

3. Percent of technical specification limit 6.83E-03 2.85E-02 B. Iodines

1. Total Iodine-131 Ci O.OOE+00 9.97E-06 30 l

2. Average release rate for period *Ci/sec O.OOE+00 1.25E-06

3. Percent of technical specification limit % O.OOE+00 9.84E-02 C. Particulates*

1. Particulates with half-lives > 8 days Ci 1.49E-07 2.19E-06 l 30 l

2. Average release rate for period pCi/sec 1.87E-08 2.76E-07

3. Percent of technical specification limit % 5.22E-03 9.84E-02

4. Gross alpha radioactivity Ci O.OOE+00 1.11E1-7 D. Tritium

1. Total release Ci 1.60E+oo 4.34E+00 O 301 1l

2. Average release rate for period I pCi/sec 2.02E1-1 5.46E-01 I

3. Percent of technical specification limit I I 5.22E-03 9.84E-02

The sum of the particulates reported on this page may be less than the sum from Table 4, as Table 4 includes all particulates, while this table includes only those with half-lives greater than 8 days.

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TABLE4 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 GASEOUS EFFLUENTS - GROUND LEVEL RELEASES A. Fission gases A rgon _ _ _ __ _ _ __ _ _ _ _ _ __ _ _ ___41_ _ _ __ _ _ __ _ __ _ _ __ _ _ _ 1 .75E-01

______________ 2.081E+00 4.02E+00 Xenon_ ___ ___ ___m__ __ _ _ _ _ _ _ _ _ __8.39E3-03 3.65E-02 Xenon-133 Ci 8.75E3-01 1.50E3+01 3.321E+00 1.03E+01 Xeno_13m__ _______ ___5.32E-03 3.63E-01 Xen___5_C __ _ _ _ _ _ _ _5.48E-02 3.96E-01

_ _ _ _ _ _ _ _

Xenon-138 Ci _ _ _ _ _ _ _ _ _ __

Total for period Ci 8.75E-01 1.50E+01 5.47E+00 1.53E+0l B. lodines Iodine-131 JCi __________J 9.541-06 _________ 4.30E-07 Iodine-132 Iodine-133 Ci Ci

_ _ _ _ _ _ _ _ _

} _

_

_ f _

_

_ _ _ _ _ _ _ _ _ _

Iodine-135 Total for period j Ci Ci

_ _ _ _

O.OOE+01

_ _ _ _ _

J _ _ _ _

9.54E-06

_ _ _ _ _ _

[ _ _ _ _ _

.OOE3+01

_ _ _ _ _ _ _ _

4.30E-U7

_ _ _ _ _

C. Particulates Zinc-72 Ci _ _ _ _ _ _ _

Cobalt-58* Ci 9.03E-07 _________

Chromiumn-51* Ci 7.55E-07 _______

Strontium-89* Ci

_ _ _

Strontium -90* Ci _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Niobium -95* Ci _ _ _ _ _ _ _ _ 1.89E-07 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

_ _ _ _ _ _ _ _ _ _ _ _

Tin-113* Cx _ _ _ _ _ _

_ _ _ _ _ _ _ _ _ _ _ _

Indium -113m Ci __ _ _ _ _ _ _ _ __ _ _ _ _ _

Cerium-137 Ci 1.49E __ _ _ .4E0 _ _ __ _ __ _

_ _ _ _ _ _ _ _ _

Clesium-138 Ci _ _ _ _ _ _ _ _ _

Totalmfor peidCi 3.9-0

.419-07 .O+OOOEO

> 8 day half-life 5

TABLE 5 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES Unit Quarter Quarter Est. Total I 1 2 Error%

A. Fission and activation products

1. Total release (not including tritium, gases, alpha) Ci 4.79E-04 3.59E-03 l i25i l

2. Average diluted concentration during period pACi/ml 8.88E-13 6.39E-12

3. Percent of applicable limit % 1.84E-04 6.16E-04 B. Tritium

1. Total release Ci 1.30E+02 2.38E+02 30i ]

2. Average diluted concentration during period pCilml 2.41E-07 4.24E-07

3. Percent of applicable limit % 2.35E-01 4.38E-01 C. Dissolved and entrained gases

1. Total release Ci 3.63E-02 1.12E-02 lj 25 l]

2. Average diluted concentration during period jCi/ml 6.73E-11 1.99E-1I

3. Percent of applicable limit % 3.29E-03 1.03E-03 D. Gross alpha radioactivity

1. Total release Ci O.OOE+00 6.31E-05 30 E. Volume of waste released (prior to dilution)

1. Batch and continuous modes Liters S.97E+06 7.01E+06 10 F. Volume of dilution water used during period

1. Batchandcontinuousmodes Liters 5.39E+I1 5.62E+11 10 6

TABLE 6 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Fission and activation products Unit Quarter 1 Quarter 2 Quarter 1 Quarter 2 Sodium-24 Ci Chromium-SI Ci Manganese-54 Ci 1.IE-06 Manganese-56 Ci Iron-55 Ci 3.O9E-05 Iron-59 Ci .

Cobalt-57 Ci Cobalt-58 Ci Cobalt-60 Ci 9.80E-06 1.89E-04 Zinc-69 Ci Strontium-85 Ci Strontium-89 Ci Strontium-90 Ci Yttrium-91m Ci Yurium-92 Ci _ 7.26E-06 Yttrium-93 Ci Niobium-95 Ci 1.02E-06 Niobium-95m Ci 5.56E-06 Niobium-97 Ci Zirconium-95 Ci Zirconium-97 Ci Molybdinum-99 Ci Technetium-99m Ci Technetium-101 Ci 2.36E-05 3.61E-06 Ruthenium-103 Ci Ruthenium-106 Ci Silver- lOin Ci I .19E-04 Tin-113 Ci _

Indium-113m Ci Antimony-122 Ci 3.52E-06 Antimony-124 Ci Antimony-125 Ci 1.51E-05 Tellurium-129 Ci 1.22E-04 Tellurium-132 Ci I .17E-06 Iodine-131 Ci lodine-133 Ci Iodine-135 Ci _

Cesium-134 Ci 1.1OE-04 1.22E-03 Cesium-137 Ci 1.78E-04 2.OOE-03 Cesium-138 Ci Barium-133m Ci _ _ 1.31E-05 Barium-140 Ci Lanthanum-140 Ci Cerium-141 Ci 4.64E-06 Cerium-143 Ci _ _ _ __ _ 1.22E-05 Neodymium-147 Ci Tungsten-187 Ci Neptunium--239 Ci Total for period Ci O.OOE+00 O.OOE+00 4.79E-04 3.59E-03 7

TABLE 6 (CONTINUED)

EFFLUENT AND WASTE DISPOSAL REPORT - 2005 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Dissolved and entrained gases unit Quarter 1 Quarter 2 Quarter 1 Quarter 2

_ _ _ _ _ _ _ _ _ _ _ _

A rgon-41 Ci _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Krypton-85 Ci __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1 .45E-02 6.89E-03 Krypton-85m Ci _ _____

Krypton-87 Ci __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1.25E-0S 2.33E-06

_ _ _

Krypton-88 Ci _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Xenon-131m Ci 1.40E-04 _______

Xenon-133 Ci ________ 2.11E-02 4.21E-03 Xenon-133m Ci 2.26E-04 ________

Xenon-135 Ci 2.601E-04 7.07E-05 Xenon-135m Ci Total for period Ci O.OOE+00 O.OOE5+00 3.63E-02 1.12E-2 Tritium Ci O.OOE+00 O.OOE3+00 1.30E+02 2.38E0 8

TABLE 7 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES I Unit I Quarter I Quarter I Estr Tor, l ll 3 l 4 l Error % l A. Fission and activation products

.

LIKI

.

1. Total release (not including tritium, gases, alpha) Ci 8.46E-02 1.55E-02

2. Average diluted concentration during period _ Ci/ml 1.44E-10 2.97E-1I

3. Percent of applicable limit _ 5.19E-02 I 39-0 B. Tritium

1. Total release

2. Average diluted concentration during period

3. Percent of applicable limit C. Dissolved and entrained gases D. Gross alpha radioactivity I Ci I 1.36E-04 I 1.36E-04 l 30 l I 1. Total release E. Volume of waste released (prior to dilution)

I Liters I 8.68E+06 I 8.83E+06 I 10 I I1. Batch and continuous modes F. Volume of dilution water used during period I Liters I 5.86E+11 I 5.22E+11 I 10 I I1. Batch and continuous modes 9

TABLE S EFFLUENT AND WASTE DISPOSAL REPORT - 2005 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Fission and activation products Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Sodium-24 Ci Chromium-51 Ci Manganese-54 Ci 4.74E-04 4.17E-05 Mangarese-56 Ci Iron-55 Ci 1.25E-04 4.76E-04 Iron-59 Ci 3.25E-05 Cobalt-57 Ci 3.98E-06 Cobalt-58 Ci 4.02E-05 _ 1.02E-03 Cobalt-60 Ci _ 4.21E-02 3.21E-03 Zinc-69 Ci Zinc-72 Ci Strontium-85 Ci Strontium-89 Ci Strontium-90 Ci _ 7.53E-05 Strontium-92 Ci Yttrium-91 Ci Yttrium-92 Ci Yttrium-93 Ci Rubidium-88 Ci Niobium-95 Ci 3.25E-05 Niobium-95m Ci Zirconium-95 Ci 3.51E-05 Molybdinum-99 Ci Technetium-99m Ci Technetium-101 Ci Ruthenium-106 Ci 1.35E-03 1.35E-04 Silver-lOmn Ci 2.81E-02 8.29E-03 Tin-113 Ci Mdium-113m Ci Antimony-122 Ci 1.063-05 9.08E-06 Antimony-124 Ci Antimony-125 Ci _ 1.49E-03 1.26E-03 Tellurium-129 Ci Tellurium-132 Ci Iodine-131 Ci 9.36E-07 1.23E-04 Iodine-132 Ci Iodine-133 Ci 2.73E-07 Iodine-135 Ci _

Cesium-134 Ci 3.94E-03 2.01E-04 Cesium-136 Ci Cesium-137 Ci 7.70E-05 6.833-03 3.68E-04 Barium-133m Ci Barium-139 Ci 1.29E-05 Barium-140 Ci Lanthanum-140 Ci Cerium-144 Ci 1.41E-04 4.33E-05 Cerium-143 Ci 9.791-06 5.44E-06 Praseodymium-144 Ci Neodymium-147 Ci Rhenium-188 Ci Total for period Ci O.OOE+01 1.17E-04 8.45E-02 1.54E-02 10

TABLE 8 (CONTINUED)

EFFLUENT AND WASTE DISPOSAL REPORT - 2005 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Dissolved and entrained gases Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Argon-41 Ci Krypton-85 Ci 7.68E-03 Krypon-85m Ci Krypton-87 Ci 3.02E-06 Krypton-88 Ci Xenon-131m Ci 5.75E-04 Xenon-133 Ci 1.09E-02 2.03E-02 Xenon-133m Ci 1. 18E-04 Xenon-135 Ci 3.44E-05 2.14E-04 Xenon-135m Ci Total for period Ci O.OOE+00 O.OOE+00 1.09E-02 2.88E-02 Tritium Ci O.OOE+0O 5.70E-02 l 2.59E+02 6.72E+01 11

TABLE 9 EFFLUENT AND WASTE DISPOSAL REPORT - 2005 SOLID WASTE AND IRRADIATED FUEL SHIPMENTS A. SOLID WASTE SHIPPED OFFSITE FOR PROCESSING OR BURIAL (Non-irradiated fuel)

L Type of waste Unit 12 month period Est. Total Error %

a. Spent resins, filter sludges, evaporator bottoms, etc. _ Ci 136E+01 25 m3 5.06E+02 2

b. Dry compressible waste, contaminated equipment, etc. Ci 8.29E01 25

c. Irradiated components, control rods, etc. Ci O.OOE+00 25

d. Other (describe): Combined DAW package m3 1.70E+01 25 1i.59E+00

2. Estimate of major nuclide composition (by type of waste in %)*

Co-60 11.9 Cs-134 16.3

a. Cs-137 55.5 Fe-55 5.3 Ni-63 10.9 Fe-55 31.9 Cs-137 2.2 Cs-134 1.7

b. Ni-63 27.8 Sb-125 1.2 C-14 13.0

c. Co-60 20.1 Ag-ilOm 1.4 C.

Fe-55 5.7 Ni-63 1.3

d. Co-60 7.9 Cs-134 21.3 Cs-137 44.0 Nb-95 16.3 Curie values and principle radionuclides are estimates based on a combination of direct and indirect methods.

3. Solid Waste Disposition Number of Shipments Mode of Transportation

Destination 7 Hittman Duratek (TN) 5 Hittman Studsvik Processing Facility (TN)

All exclusive use trucks B. IRRADIATED FUEL SHIPMENTS (Disposition)

Number of Shipments Mode of Transportation Destination 0 N/A N/A 12

Unplanned Releases There were no unplanned releases in 2005.

Radioactive Waste Treatment Systems There were no significant changes to the radioactive waste treatment systems.

Annual Land Use Census The 2005 land-use census did not identify any new dose calculation locations.

Effluent Monitor Instrument Operability Required effluent monitor instrumentation was not out of service for more than 30 days during 2005.

ODCM & PCP Changes The ODCM was revised in 2005 to correct and clarify locations for REMP sample station locations. Affected pages are 140, 141, and 142. Reference NCRs 130223 & 164046.

The PCP was not revised in 2005.

Emergency Feed Pump 2 & Steam Releases Emergency Feed Pump 2 (EFP-2) overspeed testing is performed quarterly using steam from CR-3's steam generators. Due to a small primary to secondary leak, an evaluation was performed to estimate the quantity of radioactive material which was released during 2005 due to operation of this pump. In addition, radioactive releases due to other steam releases have been estimated and included. The results are given below in units of Curies/year.

Xe-133 6.40E-07 1-131 1.68E-08 Cs-134 2.96E-08 Xe-135 3.20E-06 1-133 8.00E-08 Cs-137 2.32E-08 H-3 4.00E-06 These values are not included in Tables 1 through 4.

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2005 Appendix I Dose Summary Maximum Hypothetical Individual Liquid Effluent Dose Limits Total Body: 1.5 mremlquarter, 3 mrem/year Any Organ: 5 mrem/quarter, 10 mrem/year Liquid Effluent Dose Summary Quarter 1 Quarter 2 Quarter 3 Quarter 4 Annual Total Total Body Dose (mrem) 2.76E-06 9.24E-06 5.33E-05 2.1 1E-06 8.64E-05 Maximum Organ Dose (mrem) 2.53E-06 1.48E-05 2.60E-03 6.94E-04 3.31E-03 Maximum Organ was GI Gaseous Effluent Dose Limits Gamma Air Dose: 5 mradlquarter, 10 mradlyear Beta Air Dose: 10 mrad/quarter, 20 mradlyear Any Organ: 7.5 mrem/quarter, 15 mrem/year Gaseous Release Dose Summary Quarter 1 Quarter 2 Quarter 3 Quarter 4 Annual Total Gamma Air Dose (mrad) 4.94E-05 8.11E-05 1.29E-04 7.83E-04 1.04E-03 Beta Air Dose (mrad) 7.89E-04 6.20E-04 6.83E-04 2.85E-03 4.94E-03 Total Body Dose (mrem) 2.23E-04 1.88E-04 3.86E-04 1.05E-03 1.36E-03 Maximum Organ Dose (mrem) 8.39E-04 1.95E-04 3.86E-04 7.38E-03 8.80E-03 Maximum Organ was Thyroid 14

ML061240069

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