ML050870565
| ML050870565 | |
| Person / Time | |
|---|---|
| Site: | Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png |
| Issue date: | 02/17/2005 |
| From: | Keyes C, Wager J Connecticut Yankee Atomic Power Co |
| To: | Document Control Desk, NRC/FSME |
| References | |
| CY-05-040 9535-0001 | |
| Download: ML050870565 (144) | |
Text
0 I'I i
E~~IU Final Status Survey Final Report Phase 11 Appendix Al 0 Survey Unit Release Record 9535-0001, Southeast Landfill) Irea I
5(i February 2005 I
CYAPCO FINAL STATUS SURVEY RELEASE RECORD SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 Prepared I gineer Date:
'1g; l t -Iru Date:
9-rSl :b Date:
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD TABLE OF CONTENTS
- 1.
SURVEY UNIT DESCRIPTION.................................................... 3
- 2.
CLASSIFICATION BASIS......................
.............................. 3
- 3.
DATA QUALITY OBJECTIVES (DQOs)............................................. 6
- 4.
SURVEY DESIGN.................................................... 8
- 5.
SURVEY IMPLEMENTATION...................................................
12
- 6.
SURVEY RESULTS................................................... 13
- 7.
QUALITY CONTROL................
................................... 15
- 8.
INVESTIGATIONS AND RESULTS.................................................. 15
- 9.
REMEDIATION AND RESULTS...................................................
15
- 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN.16
- 11. DATA QUALITY ASSESSMENT (DQA).16
- 12. ANOMALIES.17
- 13. CONCLUSION.17
- 14. ATTACHMENTS.17 14.1 Attachment 1 - Figures (6 pages including cover) 14.2 Attachment 2-Sample and Statistical Data (118 pages including covers)
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD
- 1. SURVEY UNIT DESCRIPTION Survey Unit (SU) 9535-0001, (Southeast Landfill Area) is designated as Final Status Survey (FSS) Class I and consists of approximately 1,860 m2 (0.46 acres) of uninhabited, undeveloped land located 0.81 miles from the center of the Haddam Neck Plant (HNP) Containment Building (see Attachment 1, Figure 1).
A Class 3 survey unit (9524-0000) encompasses the Survey Area 9535 in whole.
Survey Area 9535 is divided east to west into two survey units. The northern section is SU 9535-0002 a Class 2 survey unit. The southern parcel is SU 9535-0001. The Survey Area 9535 is located north of the pistol range, and between Dibble Creek and the Salmon River. It is 45 meters upgrade from and east of the creek and is separated from the Salmon River by a tall, sandy, tree-lined ridge.
The topography of the area has changed considerably as a result of material and spoils removal from the area. The area was graded at the conclusion of remedial actions. Most of the area is sand, although trenching identified some large rock masses.
The reference coordinates associated with SU 9535-0001 are E048 through E052 by S130 through S134 (refer to License Termination Plan Section 5.4.4). The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit.
The boundary of the survey unit-was defined using a Global Positioning System (GPS).
The historic files indicate that, in the past, vehicle barriers were used to restrict public access to the land space of Suivey Area 9535. The landfill, due to its proximity to the road and relatively level surface, was a convenient place to dispose truckloads of construction materials and debris during plant construction and operation. Occasionally small amounts of miscellaneous material were mixed in with fill material. The area has a rhomboid shape that was fenced and posted, "Caution, Radioactive Materials", after the discovery of radioactive soil there.
Following the remedial action and remedial action surveys, the fence and posting were no longer necessary and removed (refer to HP Technical Support Document (TSD) CY-HP-0154).
Non-radiological remediation was performed in the landfill area in 2003 using cleanup criteria specified by the Regulatory Affairs group (refer to memorandum RA-CY-03-058, CY). The scope for this project was the physical investigation and cleanup of the landfill to include the removal of all manmade materials, other than unpainted concrete, from the area. Blast rock also remained in the area.
- 2. CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10, "Survey Unit Classification. " The historical information and scoping analyses results provide sufficient data to designate SU 9535-0001 as Class 1 in April 2004.
The "ClassifIcation Basis Summary" conducted for SU 9535-0001 consisted of:
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD a) A review of the 10CFR50.75 (g)(1) database, b) A review of the "Initial Characterization Report" and "Historic Site Assessment Supplement, "
c) Historic and current survey records review, d) Personal interviews, e) Visual inspections and a "walk down."
A review of the 10CFR50.75 (g)(1) database identified several radiological events pertinent to the classification of this survey unit.
a) ACR 97-0450, 7/17/1997 - Contaminated material found outside the protected area. As part of the Site Characterization Survey, contaminated material and soil were identified in the rifle area. During the implementation of a scoping survey, elevated activity was detected in the landfill adjacent to the rifle range.
A subsequent investigation identified two locations of fixed contamination, insulation material and a concrete block.
b) ACR 97-0785, 9/24/1997 - Follow-up to ACR 97-0450. An assessment of the soil indicates that the amount of radioactivity counted in the soil may exceed the limits of IOCFR20.2203(a)(3)(ii).
c) Results of Scoping Suirvey, 9/1/1998 - Results of scoping surveys performed for decommissioning characterization data.
d) Duratek Shooting Range, 12/7/1999 - Characterization survey to determine the extent and magnitude of plant related radionuclides within the Shooting Range Landfill.
Review of the 10CFR50.75(g)(1) database concluded that the fundamental event was the identification of radioactive material in July, 1997. The remaining items reflect subsequent characterization findings and a couple of non-radiological material discoveries (e.g., asbestos and hydraulic oil).
A review of the "Initial and Supplemental Characterization Reports, " "Historic Site Assessment Supplement," as well as the previous "Classification Basis Summaries" provided no additional information pertinent to classification.
A survey plan was initiated and executed in late 1997 to determine existing conditions and obtain radiological data for scoping. Radiological results from the initial scoping surveys indicated the presence of both Co-60 and Cs-137 in soil. The site characterization group performed radiological surveys of the landfill area with confirmatory surveys conducted by Oak Ridge Institute for Science and Engineering (ORISE).
The initial characterization surveys were completed in 1997. Two (2) distinct areas of elevated radioactivity were identified during this characterization study (refer to Attachment A, Figure 2). Results of the radiological survey and ground penetrating radar survey established the size of the landfill area to be approximately 5,000 square meters and an approximate depth of 3 meters. Some contaminated materials were identified during the scoping survey and were removed.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD A characterization study was performed in 1999 to determine the extent and magnitude of the plant-related radionuclides in the area.' The maximum reported concentrations were 2.9 pCi/g and 31.4 pCi/g for Co-60 and Cs-137 respectively. One composite sample comprised of media from the three locations exhibiting the highest contamination levels was processed for 10 CFR 61 analyses at an off-site laboratory.
Co-60 and Cs-137 were the only plant-related radionuclides reported for the off-site analysis results.
A remedial action plan was developed and implemented starting July 30, 2003, and completed October 21, 2003, based on the final results of the radiation survey and the sample results. Remedial action work was performed under Work Plan and Inspection Record (WP&IR) N2. 24265-000-GEN-9535-1002-000. Soil remediation was followed by remedial action surveys conducted under survey and sampling work plan BCY-SSWP-03-07-003 and subsequent addendums. Soil was removed by an excavator and placed in containers for eventual transport and disposition.
About forty (40) B-25 containers of soil (approximately. 4000 fR3) were removed from the area.
Items removed from the pit (e.g., blocks of concrete) were surveyed for contamination in accordance with health physics procedures. No materials were found to exceed the radiological release criteria for unrestricted use Three (3) samples collected during the remedial action were analyzed off-site for the full suite of Easy-to-Detect and Hard-to-Detect (HTD) radionuclides.
The gamma spectroscopy results reported Cs-137 at 52.9 pCi/g and Co-60 at 2.21 pCi/g. The HTD analyses identified Sr-90, Ni-63 and C-14 as well. Radiation surveys in the remediation area did not identify elevated areas of activity.
Samples collected and analyzed following remediation did not identify plant-related radioactivity other than low-levels of Cs-137. The six (6) soil sample results for Cs-137 and Co-60 from the final remedial action survey are provided in Table 1.
Table 1 - Basic Statistical Quantities for Cesium-137 and Cobalt-60 Derived from Final Remedial Action Data Set.
Parameter Cs-137 (pCilg)^
Co-60 (pCi/g)
Minimum Value:
0.0835 0.00149 Maximum Value:
0.408 0.0156 Mean:
0.211 0.00715 Median:
0.182 0.00487 Standard Deviation:
0.121 0.00615 Measurement standard deviation of 0.0727 the weighted sum('):
0.0727 (1) MARSSIM1 Section 1.113 eq. (1-17) describes the use of the measurement standard deviation of the weighted sum when measured concentrations of the various radionuclides are assumed to be uncorrelated (i.e., there is no fixed ratio between the concentrations).
Shooting Range Landfill Characterization Survey Report; December 1999.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD A review of the soil relocation files shows that soil and spoils were transported to the general vicinity of the shooting range as early as 1976. Specific details relevant to date or time period and exact location of placement were not available.
Recent excavation and trenching were performed in this survey unit for the purposes of removing materials and spoils (e.g., concrete, asphalt, metal, etc.). Radiological surveys for contamination have not identified radioactive material on these items.
Personnel interviews with HNP veteran personnel were conducted during the historical site assessment to ascertain the history of the Southeast Landfill.
Individuals responding to the questionnaire stated that spoils originating from construction activities such as new building construction, addition to existing buildings and general site maintenance and repairs were brought to the shooting range landfill.
A Final Status Survey Engineer (FSSE) performed a visual inspection and "walkdown" in April 2004. The visual inspection and walkdown did not conclude any observations impacting the classification of the survey unit.
At the time of FSS, the dose impact from groundwater contamination was not considered. Characterization analyses results provide sufficient data to conclude that FSS sample results will be a small fraction of the 25 mrem/year Derived Concentration Guideline Level (DCGL). However, the past use of the shooting range area for the deposition of materials and spoils, the uncertainty of location where these items were placed and the remedial action performed in this survey unit warrants the Class I designation which is consistent with procedural guidance.
- 3. DATA QUALITY OBJECTIVES (DQOs)
The primary objective of the Final Status Survey Plan (FSSP) was to demonstrate that the level of residual radioactivity in SU 9535-0001 did not exceed the release criteria specified in the License Termination Plan (LTP), was below the 10 mrem/yr Administrative Level DCGLs and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).
FSS design and planning endorsed the use of the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1-11, "Preparation of Final Status Survey Plans" and the "Multi-Agency Radiation Survey and Site Investigation Manual," (MARSSIM).
A summary of the main features of the DQO process is provided herein.
The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition.
The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true Revision 1 6
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would satisfy the release criteria objective of the FSS.
The DQO process determined that Cs-137, Co-60, Sr-90, Ni-63 and C-14 would be the radionuclides of concern during the FSS process for SU 9535-0001. To provide conservatism, the Base Case DCGLs for radionuclides in soil were reduced by 60% to establish the Administrative Level DCGLs. As described by the LTP, Equations 5-9, a surrogate relationship was developed for HTD radionuclides (Sr-90, Ni-63 and C-
- 14) to Cs-137.
In the computation of the surrogate DCGL the 95% upper bound surrogate ratios was used to account for the variability and level of uncertainty in the data. Given multiple radionuclides were assumed to be present the "unity rule" or "sum of the fractions" as described by LTP, Equation 5-32, was used to show compliance with the release criteria.
Instrument DQOs included a verification of the ability of the survey instrument to detect the radiation(s) of interest relative to the DCGL. Survey instrument response checks were performed before issue and after the instrument had been used. Control and accountability of survey instruments were maintained to assure the quality and prevent the loss of data.
Laboratory DQOs and analysis results were reported as actual calculated results.
Results reported as less than Minimum Detectable Concentration (<MDC) would not be accepted for FSS.
Sample report summaries included unique sample identification, analytical method, radionuclide, result and uncertainty of two standard deviations (2a), laboratory data qualifiers, units and the required and observed MDC (Table 2).
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Tnhlp 2 - FIRS DrC.T Vn1,wq iind Renniirptd Minimiim Detpetnhlp rnn~eprtratinniq Radionuclide Base Case Soil Administrative Level Required MDC DCGL (pClig) (
DCGL (pCi/g) (2)
(pCi/g) (3)
H-3 4.12E+02 1.65E+02 1.65E+0l C-14 5.66E+00 2.26E+00 2.26E-01 Mn-54 1.74E+01 6.96E+00 6.96E-0 1 Fe-55 2.74E+04 1.1OE+04 1.1OE+03 Co-60 3.81 E+00 1.52E+00 1.52E-01 Ag-108m 7.14E+00 2.86E+00 2.86E-01 Ni-63 7.23E+02 2.89E+02 2.89E+01 Sr-90 1.551E+00 6.20E-01 6.20E-02 Nb-94 7.12E+00 2.85E+00 2.85E-01 Tc-99 1.26E+01 5.04E+00 5.04E-01 Cs-134 4.67E+00 1.87E+00 1.87E-01 Cs-137 7.911E+00 3.16E+00 3.16E-01 Eu-152 1.O1E+01 4.04E+00 4.04E-01 Eu-154 9.29E+00 3.72E+00 3.72E-01 Eu-155 3.92E+02 1.57E+02 1.57E+01 Pu-238 2.96E+01 1.18E+01 1.18E+O0 Pu-239/240 2.67E+01 1.07E+01 1.07E+O0 Pu-241 8.70E+02 3.48E+02 3.48E+01 Am-241 2.58E+01 1.03E+01 1.03E+O0 Cm-243/244 2.90E+01 1.16E+01 1.16E+O0 S
(1) - The Base Case DCGLs for soil are specified by the LTP in Chapter 6.
(2) - The Administrative Level DCGL was 40% of the Base Case DCGL.
(3) - The Required MDC was 10% of the Administrative Level DCGL.
- 4. SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. To assist the FSSE when preparing survey plans for FSS, guidance is provided in Procedure RPM 5.1-11. By design, the FSSP meets the ALARA criteria for soils as specified in Chapter 4 of the LTP.
The LTP specifies a scan survey coverage of 100% for outdoor Class 1 land areas.
The survey design specified that 100% of the total area will receive a scan survey.
Six (6) data points were used to determine the radiological concentration variability in this survey unit. The population data set were from soil samples that were located within the boundaries of this survey unit.
Radionuclide-specific analyses of soil samples collected from this survey unit have identified radionuclides Cs-137, Co-60, Sr-90, Ni-63 and C-14 to be present. The Revision 1 8
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD data collected prior to FSS indicated that the remaining fifteen (15) radionuclides listed in Table 2 would not be present in quantities greater than 5% of the applicable "Base Case" DCGL in this survey unit at the time of FSS. It was unlikely that the aggregate concentration of the remaining radionuclides would exceed 10%; therefore, only Cs-137, Co-60, Sr-90, Ni-63 and C-14 were used in the survey planning of SU 9535-0001. The use of the 5% and 10% rule is consistent with the development of surrogate ratio DCGLs as described in the LTP.
Since multiple radionuclides were assumed to be present, the "unity rule" or "sum of the fractions" was used to demonstrate compliance with the release criteria.
Therefore, the Operational DCGL is considered to be "1."
Surrogate relationships will be used to relate Easy-to-Detect concentrations to Sr-90, C-14 and Ni-63. Cesium-137 will be the surrogate for the three HTDs radionuclides.
Cobalt-60 was considered as a surrogate for the activation products C-14 and Ni-63.
However, the remedial action data indicates that Co-60 will likely be reported at concentrations below the minimum detection criteria and will not provide a meaningful relationship. Therefore, Cs-137 is considered acceptable as the surrogate since it is likely to be the only Easy-to-Detect radionuclide of concern present in sufficient quantities at the time of FSS. The surrogate ratios were determined from data obtained during the remedial action of the landfill.
The reduced Cs-137 Surrogate DCGL was 2.82 pCi/g.
In a Class 1 area. a DCGL Elevated Measurement Comparison (DCGLEMC) is calculated. The DCGLEMC represents the dose to an individual from a small area of residual contamination. The calculated DCGLEmC was 7.16 pCi/g for Cs-137 and 1.98 pCi/g for Co-60.
The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation. This approach was conservative since it included background Cs-137 as part of the sample set.
The number of surface soil samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determination of the Number of Surface Samples for FSS."
In accordance with Procedure RPM 5.1-11 the Lower Boundary of the Gray Region (LBGR) was adjusted from 0.5 to 0.91 to maintain the relative shift (A/c;) in the range of 1 to 3. The Sign Test was used for non-parametric statistical testing. The sample design required fifteen (15) surface soil samples.
The survey unit was evaluated to assess the need for additional measurements based on the potential for small areas of elevated activity. This assessment, referred to as the Elevated Measurement Comparison (EMC), compared the MDC of the scanning technique to the DCGLEMC for the survey unit.
The adequacy of the scanning technique was adequate; therefore no additional samples were required.
This assessment transpired in accordance with procedure RPM 5.1-12.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD For the FSS, four (4) biased soil SMLs were incorporated in the survey design. The basis for this professional judgment decision was historical documentation review and process knowledge.
Although Procedure RPM 5.1-11 only specified that 5% of the samples be selected for HTD analysis, three (3) soil samples or 20% were randomly selected for HTD radionuclide analysis by the offsite laboratory by using the Microsoft Excel "RANDBETWEEN" function. Each sample would receive a full suite analysis of the radionuclides specified in the LTP, Table 2-12, "Radionuclides Potentially Present at Haddam Neck Plant."
The implementation of survey specific quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey", included the collection of two (2) soil samples for "split sample" analysis by the offsite laboratory.
These locations were selected randomly using the Microsoft Excel "RANDBETWEEN" function.
The number of quality control samples was determined to be 14% of fifteen samples, rounded up to the next whole number.
The location of the soil samples was determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying and Marking Surface Sample Locations for FSS." Pacific Northwest National Laboratory (PNNL) created VSP for the United States Department of Energy. Input parameters included a systematic grid spacing consisting of a triangular pitch pattern, and a random starting point which is appropriate for a Class 1 survey unit.
The sample locations and scan areas were identified using AutoCAD-LtD, a commercially available plotting software, with coordinates consistent with the Connecticut State Plane Coordinate System. The FSSP specified the use of a GPS to locate SMLs and scan area locations in the field. The GPS coordinates for the fifteen (15) SMLs designed for the non-parametric statistical testing are provided in Table 3.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Table 3 - Sample Measurement Locations (S L) with Associated GPS Coordinates.
Designation Northing Easting 9535-0001-00IF 236163.1177 673176.5849 9535-0001-002F 236129.1607 673078.5596 9535-0001-003F 236129.1607 673117.7697 9535-0001-004F 236129.1607 673156.9798 9535-0001-OOSF 236095.2037 673019.7444 9535-0001 -006F 236095.2037 673058.9545 9535-0001-007F 236095.2037 673098.1647 9535-0001-008F 236095.2037 673137.3748 9535-0001-009F 236095.2037 673176.5849 9535-0001-OIOF 236061.2468 673039.3495 9535-0001-01 IF 236061.2468 673078.5596 9535-0001-012F 236061.2468 673117.7697 9535-0001-013F 236061.2468 673156.9798 9535-0001-014F 236027.2898 673098.1647 9535-0001-O1SF 236027.2898 673137.3748 In a Class 1 survey unit the Investigation Level is a measurement greater than the DCGLEMc. In Accordance with the LTP, Table 5.8 this equates to 12,000 cpm for radiation scan surveys.
In a Class 1 survey unit the median concentration is not expected to exceed the LBGR.
A prospective power curve was generated using COMPASS, a software package developed under the sponsorship of the United States Nuclear Regulatory Commission for implementation of the MARSSIM in support of the decommissioning license termination rule (10 CFR 20, Subpart E). The prospective power curve showed adequate power for the survey design. The final remedial action survey data of this survey unit indicated the mean concentrations of Co-60 and Cs-137 is below the LBGR. Table 4 provides a synopsis of the ESS design.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Table 4 - Synopsis of the Survey Design Feature Design Criteria Basis Based on AutoCAD and Survey Unit Size 1,860 rn2 Visual Sample Plan calculations Type I (a) and Type II (O) errors were 0.05, Number of Measurements 15 relative shift (A/c) set at 2 by procedure, the LBGR was 0.91 Grid Spacing 12.0 m Based on triangular grid Interval Spacing 10.4 in Based on triangular grid DCGL 1
Operational DCGL applied to field data '
Scan Survey Coverage 1860 m Class I survey unit Based on achieving the Scan Investigation Level
>12,000 cprn DCGLEmc (I) The Operational DCGL was based on achieving an administrative level that was 40% of the soil DCGL and assuming no impact from radioactive contamination in groundwater or from buried concrete debris.
- 5. SURVEY IMPLEMENTATION Final status survey field activities were conducted under Work Plan and Inspection Record (WP&IR) 24265-000-GEN-9535-01017-000. The WP&IR package included a detailed FSSP, job safety analysis, job planning checklist and related procedures to be used for reference. Daily briefings were conducted to discuss the expectations for job performance and the -safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.
Survey activities occurred between April 19 and April 27, 2004.
Using the GPS, the scan area and SMLs were identified and marked with surveyor's flags.
A 100% scan survey of SU 9535-0001 was performed and evaluated for elevated readings.
See Attachment 2 for Scan Area results. Scan surveys were performed with an Eberline E-600 using a SPA-3 2"x2" sodium iodide detector. The E-600 was operated in the rate meter mode and used with audio response. The probe was positioned as close to the ground as possible and was moved at a scan speed of about 0.5 meters per second.
The fifteen (15) surface soil samples were collected and packaged in accordance with Procedure RPM 5.1-3, "Collection of Surface and Subsurface Soil, Shoreline Sediment, Asphalt and Liquid Samples for Scoping, Characterization and Final Status Survey" and the FSS design. Samples collected were controlled, transported, stored, and transferred to the offsite laboratory using Chain-of-Custody (COC) protocol in Revision I 12 Revision 1 12
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD accordance with Procedure RPM 5.1-5, "Chain of Custody for Scoping, Characterization and Final Status Survey Samples."
Three (3) samples, 9535-0001-002F, 006F and 016F, were selected and sent to the off-site laboratory for gamma spectroscopy and HTD radionuclide analysis.
Four (4) judgmental samples were collected, 9535-0001-016F through 019F, and sent to the off-site laboratory for gamma spectroscopy analysis. See Attachment 1, Figure 5 for a visual depiction.
Two (2) 'split samples', 9535-0001-004F/FS and 008F/FS, were collected for analysis by the off site laboratory.
- 6. SURVEY RESULTS No scan survey results were in excess of the Investigation Level. No investigations or additional soil samples were required. See Table 5 for a summary of the scan survey results. All scan area results area provided in Attachment 2.
Table 5 - Scan Area Results Scan Area Investigation Range of Logged Elevated Reading Level (cpm)
Readin (cpm)
Identification Scan Strips 1-71 12,000 5,460-8,330 None The off site laboratory employed for the radiological analyses of samples was General Engineering Laboratories, LLC (GEL), Charleston, South Carolina. The laboratory processed and analyzed the fifteen (15) samples taken for non-parametric statistical testing, the associated duplicates and judgmental samples using gamma spectroscopy.
Gamma spectroscopy analysis was performed to the required MDC. The results of gamma spectrometry analysis for all of the samples indicated Cs-137 at levels consistent with concentrations of Cs-137 found in soil at offsite locations within the vicinity of the HNP (Health Physics TSD BYC-HP-0063). A summary of the sample results is provided in Table 6.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Table 6-Summary of Soil Sample Results Sample Number Cs-137 Co-60 f-DCGL(')
9535-0001-001 0.071 0.007 0.030 9535-0001-002 0.099
-0.007 0.031 9535-0001-003 0.103
-0.001 0.036 9535-0001-004 0.097
-0.005 0.031 9535-0001-005 0.313 0.004 0.113 9535-0001-006 0.127
-0.002 0.043 9535-0001-007 0.089
-0.009 0.026 9535-0001-008 0.085 0.003 0.032 9535-0001-009 0.062 0.003 0.024 9535-0001-010 0.093
-0.002 0.032 9535-0001-011 0.138 0.009 0.055 9535-0001-012 0.041
-0.007 0.010 9535-0001-013 0.058
-0.002 0.020 9535-0001-014 0.073 0.002 0.027 9535-0001-015 0.039 0.002 0.015 (1) f-DCGL-fraction of the Operation DCGL.
The offsite laboratory processed three (3) samples, 9535-0001-002F, 006F and 016F, for HTD analyses as required by the sample plan. Depending on the radionuclide and the measurement method, the requested analyses included alpha spectroscopy, gas proportional counting and liquid scintillation. The only HTD radionuclide resulting in an identifiable quantity were Sr-90 and Ni-63, in sample 9535-0001-006F (see Table 7). Sample analysis results did not-exceed the Investigation Level; therefore, no further actions or investigations were required.
Table 7 - Hard-to-Detect Sample Results in pCilg Sample Number.
DCGL l f-DCGLR' I
and Result'.
DCL fCG "
9535-0001-006F Sr!90 l
0.072 0.620 0.116 9535-0001-006F Ni-63 15.80 289.000 0.055 (I) f-DCGL - fraction of the Administrative Level DCGL.
Four (4) biased samples, 9535-0001-016F through 019F, were analyzed by gamma spectroscopy at the off site laboratory. The analysis was performed to the required MDCs. Sample results were approximately 2% of the Operational DCGL, well below the investigation level. No further actions or investigations were required. Results are summarized in Table 8.
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SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Table 8 - Biased Sample Results Sample Number -
Cs-137 pCi/g Co-60 pCi/g f-DCGL 9535-0001-016F 0.054 0.006 0.023 9535-0001-017F 0.102
-0.001 0.035 9535-0001-018F 0.065 0.005 0.026 9535-0001-019F 0.041 0.015 0.025 Radionuclide analyses results identified some radionuclides meeting the accepted criteria for detection (i.e., a result greater than both, the two standard deviations uncertainty and the actual MDC). The maximum reported f-DCGL for any individual soil sample was 17%. Validation/verification of the survey data, a Data Quality Assessment (DQA) and the Sign Test were performed.
The data passed the Sign Test. Refer to Attachment 2 for data and DQA results.
- 7. QUALITY CONTROL The off site laboratory processed the split soil samples and performed gamma spectroscopy analysis. Thirteen percent (13%) of the soil samples were selected for analysis which exceeds the 5% minimum required by the LTP. The data were evaluated using the United States Nuclear regulatory Commission (USNRC) acceptance criteria specified in Inspection Procedure 84750 as detailed in Procedure RPM 5.1-24.
There was acceptable agreement between field split results.
The sample analysis vendor, STL-Richland, maintains quality assurance and quality control plans as part of normal operation. Refer to Attachment 2 for data and data quality analysis results.
- 8. INVESTIGATIONS AND RESULTS No investigations were performed in this survey unit. All soil sample and scan survey measurements were below the Investigation Levels.
- 9. REMEDIATION AND RESULTS No remediation was performed in this survey unit as a result of FSS.
Prior to FSS, remedial action and Remedial Action Surveys were conducted.
Soil remediation was followed by Remedial Action Surveys conducted under survey and sampling work plan BCY-SSWP-03-07-003 and subsequent two addendums. Soil was removed by an excavator and placed in containers for eventual transport and disposition. About forty (40) B-25 containers of soil (approximately 4000 f13) were removed from the area. Items removed from the pit (e.g., blocks of concrete) were surveyed for contamination in accordance with health physics procedures.
The materials were found to exceed the radiological release criteria for unrestricted use.
Table 9 provides the before and after remediation basic statistical quantities for Cs-137 and Co-60.
Revision 1 15 Revision 1 15
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Table 9 - Pre and Post Remedial Action Soil Sample Results Pre Cs-137 Post Cs-137 Pre Co-60 Post Co-60 Parameter (pCi/g)
(pCi/g)
(pCi/g)
Ci Minimum Value:
0.081 0.084 0.002 0.001 Maximum Value:
15.900 0.408 1.900 0.016 Mean:
3.290 0.211 0.273 0.007 Median:
2.790 0.182 0.115 0.005 Standard Deviation:
3.780 0.121 0.518 0.006
- 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN There were no changes from the FSSP. No FSSP Addendums were created.
- 11. DATA QUALITY ASSESSMENT (DQA)
The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment," for completeness and consistency. The sampling design had adequate power as indicated by the Retrospective Power Curve.
The Retrospective Power Curve was generated using COMPASS.
The Sign Test was performed on the data and compared the results with the original assumptions of the DQOs. All soil sample results were less than the release criteria. Therefore, the Sign Test shows that the survey unit passes ESS.
Documentation was complete and legible.
Surveys and sample collection were consistent with the DQOs and were sufficient to ensure the survey unit was properly designated as Class 1.
The preliminary data review consisted of converting the data into units relative to the release criteria (i.e., pCi/g) and calculating basic statistical quantities (e.g., mean, median, standard deviation).
The Cs-137 range of the data is about 4.2 standard deviations. Excluding the highest Cs-137 result (3.13E-01 pCi/g) the range of the data is about 1.51.
Statistical analyses reveal three positive outliers. This could be attributed to natural variations of environmental soil sampling with inductions from topographical and geological features. The total range of the sample results is consistent with concentrations of Cs-137 found in soil at offsite locations within the vicinity of the HNP. The maximum result is less than the required MDCCs-137 of 3.16E-01 pCi/g. None of the samples exceeded 12% of the Surrogate DCGLc,. 1 37.
The Co-60 range of data was about 3.46 standard deviations. The histogram of the data showed a normal distribution around the mean. None of the samples exceeded 1% of the DCGLck6o.
The average level of contamination in SU 9535-0001 is less than the release criteria as defined by the Operational DCGL. Evaluation of soil sample results using the DCGLEMC is not required as by default all results would be less than the DCGLEMC.
Revision 1 16
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD The Sign Test was performed on the data and compared the results with the original assumptions of the DQOs.
All samples were less than the Operational DCGL.
Therefore, the Sign Test shows that the survey unit passes FSS.
This survey unit is not considered impacted by radioactive contamination in groundwater based on location, topography and current hydro-geologic sampling data as referenced in Health Physics Technical Support Document (TSD) CY-HP-0193, "Assessment of Existing Groundwater Dose for Phase II Release Areas of the Final Status Survey Report."
- 12. ANOMALIES Soil sample 9535-0001-006F yielded a positive identification of Ni-63 and Sr-90 at 2% and 5% of the Base Case DCGL, respectively. The Ni-63 ratio of sample result to MDC was 15.8:15.3 or 1.03:1.0. Sample data associated with the Offsite Material recovery Program (OMRP) identified two (2) HTD radionuclides meeting the accepted criteria for detection (i.e., a result greater than 2 standard deviations uncertainty and the actual MDC). However, the reported concentrations of Ni-63 and Fe-55 were a very low fraction of the applicable Base Case DCGL for soil (<1%).
The combined fraction of the Base Case DCGL including the Ni-63 and Sr-90 results is <13%. The Sr-90 and Ni-63 result did not impact the proper release of SU 9535-0001.
- 13. CONCLUSION Survey Unit 9535-0001 has met the DQOs of the FSS. For this survey unit, the ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved.
The sample data passed the Sign Test. The null hypothesis was rejected. Evaluation of the data shows that none of the FSS design radionuclides or HTD soil concentration values exceeded the Operational DCGL of "I" or unity. The Elevated Measurement Comparison test was not required. No large anomalies were observed in the graphical representation of the data. The survey unit was properly designated as Class 1. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved.
This survey unit is not considered impacted by radioactive contamination in groundwater based on location, topography and current hydro-geologic sampling data as referenced in Health Physics TSD CY-HP-0193, "Assessment of Existing Groundwater Dose for Phase II Release Areas of the Final Status Survey Report".
- 14. ATTACHMENTS 14.1 - Figures 14.2 - Sample and Statistical Data Revision 1 17
CYAPCO FINAL STATUS SURVEY RELEASE RECORD SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 Prepared By:
Date:
FSS Engineer Reviewed By:
Date:
FSS Engineer Approved By:
Date:
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD TABLE OF CONTENTS
- 1.
SURVEY UNIT DESCRIPTION.................................................... 3
- 2.
CLASSIFICATION BASIS....................................................
3
- 3.
DATA QUALITY OBJECTIVES (DQOs)............................................. 6
- 4.
SURVEY DESIGN.................................................... 8
- 5.
SURVEY IMPLEMENTATION...................................................
12
- 6.
SURVEY RESULTS................................................... 13
- 7.
QUALITY CONTROL.................
.................................. 15
- 8.
INVESTIGATIONS AND RESULTS.................................................. 15
- 9.
REMEDIATION AND RESULTS...................................................
15
- 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN.16
- 11. DATA QUALITY ASSESSMENT (DQA).16
- 12. ANOM ALIES........................................................................................ 17
- 13. CONCLUSION.17
- 14. ATTACHMENTS.17 14.1 Attachment 1 - Figures (6 pages including cover) 14.2 Attachment 2-Sample and Statistical Data (118 pages including covers)
Revision 1
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Figures (5 Pages)
I
Mm m
m m
m m
m m
m m
m m
9535-Notes Or Connecticut Yankee Atomic Power Company 9535-0001 Filal Status Survey
m M
m m
m m
m m
m m
m M
M M
M M
M M
3
= Samle Locaon 0
7 2
acon aWa of eleated radioacduity 6
Notes 11 5
@4
- 10 0 14 A&
9 w
- 8 Yankee Atomic Power Company 9535-0001 Final Status Survey Design 0 O 2?
m m
m m
m m
m m
m m
m m
o.103
- =SoVleLOC 0O 0.127 S
Nofts 0.313 0.0929 o.1-38 Gs-137rsutmin pcar 0.0849 Connecticut Yankee Atomic Power Company 9535-0001 Final Status Survey Design Cesium-137 Posting Plot
M m
M m
m m
m m
m m
m m
m 0
=SaMpleLocation 0
O.oo852 Notes 0
0.00379 Co-60 msuJ Am Pad9 0.1 0
0.00230 Negaive Valuesnot Shown 0
0.00315 0
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Connecticut Yankee Atomic Power Company 9535-0001 Final Status Survey Cobalt-60 Crt
m m
M m
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= Judmen Sample Locaon Notes
@1 Connecticut Yankee Atomic Power Company 9535-0001 FSS Judgmental
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD Sample and Statistical Data (118 pages including covers)
I
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD a Gamma Spectroscopy Data (87 Pages)
Table of Contents Case Narrative
............................................. 1 Chain of Custody..............................................
4 Cooler Receipt Checklist 8
Radiological Analysis
............................................. 1 1 Sample Data Summary..............................................
28 Quality Control Data......................
74
CASE NARRATIVE 1
CASE NARRATIVE For Project: Soils PO# 002332 Work Order: 113282 SDG: MSR#04-1559 June 17, 2004 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address:
P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address:
2040 Savage Road Charleston, South Carolina 29407 Telephone Number:
(843) 556-8171 Summary:
Sample receipt The samples for the Soil Project for work order 113282 arrived at General Engineering Laboratories, LLC, (GEL) in Charleston, South Carolina May 19, 2004 for environmental analysis. All sample containers arrived without any visible signs of tampering or breakage. The chain of custody contained the proper documentation and signatures.
The laboratory received the following samples:
9535-0001-008F 9535-0001-009F 9535-0001-008FS 9535-0001-012F 9535-0001-OOIF 9535-0001-013F 9535-0001-018F 9535-0001-014F 9535-0001-OOIF 9535-0001-015F 9535-0001-003F 9535-0001-017F 9535-0001-004F 9535-0001-019F 9535-0001-004FS 9535-0001-002F 9535-0001-005F 9535-0001-006F 9535-0001-007F 9535-0001-016F.
9535-0001-OlOF GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP INC.-
RO. Box 30712
- Charleston, SC 29417
- 2040 Savage Road (29407)
Phone (843) 556-8171
- FJ (843) 766-1178
- www.gel.com
Items of Note:
There are not items to note.
Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analvtical Request:
Eighteen soil samples were analyzed forFSSGAM, and three soil samples were analyzed for FSS ALL.
Internal Chain of Custody:
Custody was maintained for all of these samples.
Data Package:
The enclosed data package contains the following sections: Case Narrative, Chain of Custody, Cooler Receipt Checklist, Laboratory Certifications, and Radiochemistry.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP. INC.
P.O. Box 30712
- Charleston, SC 29417 - 2040 Savage Road (29407)
Phone (843) 55648171
- Fax (843) 766-1178
- www.gel.com 3
CHAIN OF CUSTODY 4
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Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00I Major U1 Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2004-00066 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested use Contact Name & Phone:
C__nmfe:ts:
Media Sample Container Jack McCarthy 860-267-2556 Ext. 3024 aCode Tye e.
Analytical Lab (Name, City, State Code
&Type General Engineering Laboratories Code 2040 Savage Road V Charleston, SC 29407 (843-556-8171)
Sarah Kozlik tz
- C; Priority
- El 30 D. 0 14 D. E 7 D..
Other:
Sample Designation Date Time Comment, Preservation Lab Sanpie iD 9535-0001-008F 4/22/2004 1544 TS G
BP X
9535-0001-OO8FS 4/22/2004 1544 TS G
BP X
9535-0001-O1IF 4/22/2004 1526 TS G
BP X
9535-0001-018F 4/22/2004 1531 TS G
BP X
NOTES: PO#: 002332 MSR#:
04-1559 Z LTP QA D Radwaste QA 2 Non QA Samples Shipped Via:
.. e.Contamier 0 Fed Ex Temp.3 bDeg C Hand I
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- 2) i By Date/Time
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- 5) Relinquished By Date/Time
- 6) Received By Date/Time
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Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2004-00064 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556
//
S z
Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone:
Comments:
Jack McCarthy 860-267-2556 Ext. 3024 Media Sample Container Code Type Size-Analytical Lab (Name, City, State Code
&Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 (843-556.8171)G o
V Sarah Kozlik c
Priority: 030 D.
14 D.0 7 D.
Other:
Sample Designation Date Time Cornment, Preservation Lab Sampile ID.
a) 9535-0001-OOIF 4/22/2004 1435 TS G
BP X
=
9535-0001-002F 4/22/2004 1501 TS G
BP X
9535-0001-003F 4/22/2004 1453 TS G
BP X
9535-0001-004F 4/22/2004 1447 TS G
BP X
9535-0001-004FS 4/22/2004 1447 TS G
BP X
9535-0001-005F 4/22/2004 1513 TS G
BP X
,6P 9535-0001-006F 4/22/2004 1507 TS G
BP X
9535-0001-007F 4/22/2004 1535 TS G
BP X
9535-0001-OIOF 4/22/2004 1520 TS G
BP X
NOTES: PO#:
002332 MSR #: 04-1559 0 LTP QA C Radwaste QA C Non QA Samples Shipped Via:
Internal Container NOTE Do not dry sample until sufficient sample media has been obtained for volatile Hard To Detect analyses are 0 Fed Ex TePp.:
Deg. C complete.
UPS OC Hand Cistody Sealed?
edB DateJime
- 2) ceivd By /
Date/Time Custody Seal Intact?
~keinquisvh R dyed/?
By 6~lc l
G CEJ Other N
RelinquishedBy Date/Time 4 )Rv B
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- 6) Received By Date/Time C'
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V Health Physics Procedure GPP-GGGR-R5104-003-AttachmentB-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2004-00065 362 Ihjun Hollow Road, East Hampton, CT 06424 860-267-2556 L/
Use 0 Project Name: Haddam Neck Decommissioning Analyses Requested
,Lab Use Onl y;:;-
Contact Name & Phone:
Media Sample Container
~~
Jack McCarthy 860-267-2556 Ext. 3024 Code Type Size r Analytical Lab (Name, City, State Code
&Typc General Engineering Laboratories 2040 Savage Road Charleston, SC 29407 (843-556-8171)
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Sarah Kozlik co e
La v
Priority: J 30 D.-
14 D.
7 D.
Other:_________
Sample Designation Date Time Comment, Preservation tkaple',-.'~
9535-0001-009F 4/27n2004 0848 TS G
BP X
- T4 dS A
9535-0001-012F 4/27/2004 0818 TS G
BP X
=
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9535-0001-013F 4127/2004 0838 TS G
BP X
=
9535-0001-014F 4127/2004 0810 TS G
BP X
9535-0001-0151F 4127/2004 0834 TS G
BP X
W 9535-0001-01VF 412712004 0826 TS G
BP
=
X
=__________________
9535-0001-017F 412712004 0843 TS G
BP X
___=__________
9535-0001-019F 4127n2004 0805 TS G
BP X
NOTES: P0 #:
002332 MSR 4#: 04-1559 I
LTP QA El Radwaste QA E5 Non QA Samples Shipped Via:
J tener NOTE Do not dry sample until sufficient sample media has been obtained for volatile Hard To Detect analyses are O
Fed E m
U complete.
~Uss.
a3 Hand ttoy Seald V
- 1) Re in edBy 2)Daei ve 2
By C
,- Date/Time oy SelIntact?
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- kelinqui ed By Date/Time Re ived By Date/Time 744k ;-3-2-7?3 N O Bill of Lading #'
- 5) Relinquished By Date/Time
- 6) Received By Date/Time
~~~.
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOw-00 1 Figure 1. Sample Check-in List Date/Time Received:
b IV.
O SDGtf: %S Wh Work Order Number:
Shipping Container ID.
]
1
)
qS35 19&Chain of Custody #_
- 1.
Custody Seals on shipping container intact?
- 2.
Custody Seals dated and signed?
- 3.
Chain-of-Custody record present?
- 4.
Cooler temperature
- 5.
Vermiculite/packing materials is:
- 6.
Number of samples in shipping container:
I
- 7.
Sample holding times exceeded?
a 4 _.
ca a4 _ds Yes [ ] No Yes [lNo [1-Yes [-]--No [ ]
Wet [ ] Dry [ ]
Yes [ ] No [ ]
- 8. Samples have:
tape hazard labels custody seals appropriate sample labels
- 9. Samples are:
_____in good condition leaking broken have air bubbles
- 10.
Were any anomalies identified in sample receipt?
Yes [] No [-
II.
Description of anomalies (include sample numbers):
Samnle CustodianlLahbratorv:
Dn Date:
5 (1 Telephoned to:
On By_
9
SAMPLE RECEIPT & REVIEW FORM PM use only SDG/AkCO(ork Order, Dat e
Receive vRenew
(
re no-conor'ng
-DatenRecelIliiii iis rcires6led pnoPr to silgring).
Received By:
Sample Receipt Criteria z
E CoumnentslQualifiers (Required for Non-Conrorning Items) 1 ing containers received intactCircle Applicable: seals broken damaged container leaking container other (describe) and se d?
Samples re ng cold ice bags blue ice dry ice none other(describe) 2 preservation wit (4+/-2 C)?
Record preservation hod.
Chain of custody documen included with shipment?
\\
Sample containers intact and Circle Applicable: seals broken damaged container leaking container other (describe)
_ sealed?
Samples requiring chemical Sample JEs, containers affected and observed pH:
5 reservation at proper pH?
VOA vials free of headspace s and containers affected:
6 (defined as < 6mm bubble)?
7Samples received within holding IUs and tests af e time?
Sample ID's on COC match ID's on Sample ls and containers bottles?
9 Date & time on COC match date S ample flDs affected:
time on bottles?
Number of containers received Sample IlDs affected:
10 match number indicated on COC?
_ COC form is properly signed in 11 relinquished/received sections?
12 Air Bill &Tracking #'s X',
Wma FE.-Cz11,_
r 1r j~aciact 1rJes~s~V:~
i.?~.
~
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RADIOLOG ICAL ANALYS IS 11
Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)
SDG MSR#04-1559 Mlethod/Analysis Information Product:
Alphaspec Am241, Cm, Solid ALL FSS Analytical Method:
DOE EML HIASL-300, Am-05-RC Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-02 I Method:
Dry Soil Prep Analytical Batch Number:
338561 Prep Batch Number:
334895 Dry Soil Prep GL-RAD-A-021 Batch Number:
334885 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 113282021 9535-0001-016F 1200637713 Method Blank (MB) 1200637716 Laboratory Control Sample (LCS) 1200637714 1 13282019(9535-0001-002F) Sample Duplicate (DUP) 1200637715 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 II REV# 13.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information 12
All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Sample 113282020 (9535-0001-006F) was recounted due to poor resolution.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis In formation Product:
Alphaspec Pu, Solid-ALL FSS Analytical Method:
DOE EML IIASL-300, Pu-I A-RC Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:
Dry Soil Prep Analytical Batch Number:
338562 Prep Batch Number:
334895 Dry Soil Prep GL-RAD-A-021 Batch Number:
334885 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 113282021 9535-0001-016F 1200637717 Method Blank (MB) 1200637720 Laboratory Control Sample (LCS) 1200637718 113282019(9535-0001-002F) Sample Duplicate (DUP) 1200637719 1 13282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 13.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
13
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
11olding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
qualifier information Manual qualifiers were not required.
Mlethod/Analvsis Information Product:
Liquid Scint Pu241, Solid-ALL FSS Analytical Method:
DOE EML HIASL-300, Pu-I l-RC Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:
Dry Soil Prep Analytical Batch Number:
338563 Prep Batch Number:
334895 Dry Soil Prep GL-RAD-A-021 Batch Number:
334885 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 113282021 9535-0001-016F 1200637721 Method Blank (MB) 1200637724 Laboratory Control Sample (LCS) 1200637722 113282019(9535-0001-002F) Sample Duplicate (DUP) 1200637723 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 5.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
14
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
qualifier information Manual qualifiers were not required.
Method/Analvsis Information Product:
Gammaspec, Gamma, Solid-FSS GAM & ALL FSS Analytical Method:
EML HASL 300, 4.5.2.3 Prep Method:
Dry Soil Prep Analytical Batch Number:
335643 Prep Batch Number:
334885 Sample ID Client ID 113282021 9535-0001-016F 1200630675 Method Blank (MB) 1200630677 Laboratory Control Sample (LCS) 1200630676 113280002(3100-0000-186-C-IC-02) Sample Duplicate (DUP)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 13 REV# 10.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
15
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample vas used for QC: 113280002 (3100-0000-186-C-IC-02).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:
NCR 118232 was generated due to Non-Rad samples being analyzed with Rad Samples. Sample 113282021, which is non-rad, was analyzed with rad samples. The sample was prepared for gamma analysis independent of Rad samples. The batch results were reviewed and verified that no cross contamination is evident in the non-rad sample.
The results are being reported.
Qualifler information Qualifier l
Reason l
Analyte l
Sample Ul Data rejected due to low abundance.
Cesium-134 1200630676 U
l Data rejected due to no valid peak.
Thallium-208 1200630675 Method/Analysis Information Product:
Gammaspec, Gamma, Solid-FSS GAM & ALL FSS Analytical Method:
EML HASL 300, 4.5.2.3 Prep Method:
Dry Soil Prep Analytical Batch Number:
335651 Prep Batch Number:
334885 Sample ID Client ID 113282001 9535-0001-008F 113282002 9535-0001-008FS 16
113282003 9535-0001-OO1F 113282004 9535-0001-018F 113282005 9535-0001-OOIF 113282006 9535-0001-003F 113282007 9535-0001-004F 113282008 9535-0001-004FS 113282009 9535-0001-005F 113282010 9535-0001-007F 113282011 9535-0001-OIOF 113282012 9535-0001-009F 113282013 9535-0001-012F 113282014 9535-0001-013F 113282015 9535-0001-014F 113282016 9535-0001-015F 113282017 9535-0001-017F 113282018 9535-0001-019F 113282019 9535-0001-002F 113282020 9535-0001-006F 1200630700 Method Blank (MB) 1200630702 Laboratory Control Sample (LCS) 1200630701 113282001(9535-0001-008F) Sample Duplicate (DUP)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 13 REV# 10.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282001 (9535-0001-008F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
17
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR wvas not generated for this SDG.
Ounlifier information Qualifier Reason Analyte Sample UI Data rejected due to interference.
Europium-155 113282003 113282005 113282006 Manganese-54 113282011 U!
Data rejected due to low abundance.
Americium-241 113282008 Cesium-134 113282002 113282003 113282005 113282007 113282008 113282010 113282014 113282017 113282018 Ul Data rejected due to no valid peak.
Niobium-94 113282018 Potassium-40 1200630700 Method/Analysis Information Product:
Analytical Method:
Prep Method:
Dry Soil Prep GL-RAD-A-021 Method:
Analytical Batch Number:
Prep Batch Number:
Dry Soil Prep GL-RAD-A-021 Batch Number:
GFPC, Sr90, solid-ALL FSS EPA 905.0 Modified Ash Soil Prep Dry Soil Prep 335956 334895 334885 Sample ID 113282019 113282020 113282021 1200631487 1200631490 1200631488 1200631489 Client ID 9535-0001 -002F 9535-0001 -006F 9535-0001-016F Method Blank (MB)
Laboratory Control Sample (LCS) 113282019(9535-0001-002F) Sample Duplicate (DUP) 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 8.
Calibration Information:
18
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Gcometry All counting sources vere prepared in the same geometry as the calibration standards.
Oualitv Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Additional Comments Samples 113282020 (9535-0001-006F), 1200631487 (MB) and 1200631488 (9535-0001-002F) were verified by recounting at least five days from the initial count date.
qualifier Information Manual qualifiers were not required.
Miethod/Analysis Information Product:
Liquid Scint Tc99, Solid-ALL FSS Analytical Method:
DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number:
339685 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 19
113282021 9535-0001-016F 1200640376 Method Blank (MB) 1200640379 Laboratory Control Sample (LCS) 1200640377 113282019(9535-0001-002F) Sample Duplicate (DUP) 1200640378 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 11.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prepfRe-analysis None of the samples in this sample set required reprep or reanalysis.
Mliscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:
NCR 121134 was generated due to Failure to maintain Custody. 1. The analyst did not scan the samples (113282019, 113282020,113282021,113283017,113283018) into the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on proper scanning procedures. 1. Reporting results.
Oualifier Information Manual qualifiers were not required.
20
Niethod/Analysis Information Product:
Analytical Method:
Prep Method:
Dry Soil Prep GL-RAD-A-02 I Method:
Analytical Batch Number:
Prep Batch Number:
Dry Soil Prep GL-RAD-A-02 I Batch Number:
Liquid Scint Fe55, Solid-ALL FSS DOE RESL Fe-I, Modified Ash Soil Prep Dry Soil Prep 342541 334895 334885 Sample ID 113282019 113282020 113282021 1200647440 1200647443 1200647441 1200647442 Client ID 9535-0001 -002F 9535-0001 -006F 9535-0001-016F Method Blank (MB)
Laboratory Control Sample (LCS) 113282019(9535-0001-002F) Sample Duplicate (DUP) 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 2.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-preplRe-analysis 21
Samples 113282020 (9535-0001-006F), 113282021 (9535-0001-016F), 1200647440 (MB) and 1200647441 (9535-000 t-002F) were recounted due to a negative result greater than three times the error.
Samples were reprepped due to low/high recovery.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Additional Comments The absolute value of sample activity 1200647440 (MB) is greater than three times the one sigma total propagated uncertainty due to subtraction of the cross talk from the Iron-59 tracer.
Qualifier Information Manual qualifiers were not required.
Method/Analvsis Information Product:
Liquid Scint Ni63, Solid-ALL FSS Analytical Method:
DOE RESL Ni-l, Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:
Dry Soil Prep Analytical Batch Number:
339689 Prep Batch Number:
334895 Dry Soil Prep GLRAD-A-021 Batch Number:
334885 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 113282021 9535-0001-016F 1200640384 Method Blank (MB) 1200640387 Laboratory Control Sample (LCS) 1200640385 113282019(9535-0001-002F) Sample Duplicate (DUP) 1200640386 1 13282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 6.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (WC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
22
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prepfRe-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product:
LSC, Tritium Dist, Solid-IITD2,ALL FSS Analytical Method:
EPA 906.0 Modified Analytical Batch Number:
339628 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 113282021 9535-0001-016F 1200640251 Method Blank (MB) 1200640254 Laboratory Control Sample (LCS) 1200640252 113282019(9535-0001-002F) Sample Duplicate (DUP) 1200640253 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 9.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry 23
All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP. or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product:
Liquid Scint C14, Solid FSS Analytical Method:
EPA EERF C-0 I Modified Analytical Batch Number:
342387 Sample ID Client ID 113282019 9535-0001-002F 113282020 9535-0001-006F 113282021 9535-0001-016F 1200647032 Method Blank (MB) 1200647035 Laboratory Control Sample (LCS) 1200647033 113282020(9535-0001-006F) Sample Duplicate (DUP) 1200647034 113282020(9535-0001-006F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GLRAD-A-003 REV# 7.
Calibration Information:
24
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282020 (9535-0001-006F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Samples 1200647032 (MB) and 1200647033 (9535-0001-006F) were recounted due to high MDAs.
Samples were reprepped due to low/high recovery.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier Information Manual qualifiers were not required.
Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.
The following data validator verified the information presented In this case narrative:
g+Q(QeWtk~.(~lj c u Reviewer:
25
General Engineering Laboratories Form GEL-XXX Rev. 06102 NCR Report No.:
118232 Revision No.: I COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.
Division:
Type:
10-JUN-04 Radiochemistry Process Instrument Type:
Quality Criteria:
Client Code:
GAMMA SPECTROMETER Specifications YANK Test I Method:
Matrix Type:
Batch ID:
Sample Numbers:
EML HASL 300,4.5.2.3 Solid 335643 See Below Potentially affected work order(s)(SDG): 113280(MSR#0441488),113282(MSR#04-1559)
Application Issues:
Non-Rad samples analyzed with Rad Samples Specification and Requirements NRG Disposition:
Nonconformance
Description:
Sample 113282021, which is non-rad, was analyzed with rad samples.
Sample was prepared for gamma analysis independant of Rad samples.
The batch results were reviewed and verification that no cross contamination is evident In the non-rad sample. Reporting results.
Originatores Name:
michael hilton Quality Review:
I_
Lonnie Morris Director:
10-JUN-04 Data Validator/Group Leader:
Scott Baskett 10-JUN-04 Corrective Action:
11-JUN-04 Corrective Action ID and Complete Date:
Page 1 26
General Engineering Laboratories Form GEL-XXX Rev. 06102 NCR Report No.:
121134 Revision No.:
COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.
Division:
Type:
21-JUN-04 Radiochemistry Process Instrument Type:
Quality Criteria:
Client Code:
LSC Specifications YANK Test I Method:
Matrix Type:
Batch ID:
Sample Numbers:
DOE EMIL HASL-300, Tc-02-RC Solid 339685 See Below
-Modif cd Potentially affected work order(s)(SDG): 113282(MSR#04.1559),113283(MSR#04-1558)
Application Issues:
Failure to maintain Custody Specification and Requirements NRG Disposition:
Nonconformance
Description:
- 1. The analyst did not scan the samples(1 13282019.
- 1. Reporting results.
113282020.113282021,113283017,11328301 8)into the batch prior to analysis, however the samples did remain in their custody at all times.
The error has been corrected and the analyst has been Instructed on proper scanning procedures.
Originatoes Name:
Jimmy Hartley Quality Review:
21-JUN-04 Data ValidatorlGroup Leader Joseph Jones 21-JUN-04 Corrective Action:
Director:
Corrective Action ID and Complete Date:
Page 1 27
SAMPLE DATA
SUMMARY
28
IS I
I GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Datc: June 24.2004 Page I of 2 Client Sample ID:
95354001-008F Ngetcv YANK00504 Sample ID:
I 1 282001 Vlc YANRC00 Matrix:
Sol]
Vol. Resv.:
Collect Date:
22-APR-04 Receive Date:
19-MAY-04 Collector:
Client Moisture:
3.41%
Parameter Qualifer Result Unceltainty LC TPU MDA Units DF AnalysDate Time Batch Mtd.
Rad Gamm Spec alysts Gamma:pec. GammA. Solid-FSS GAY & AL FSS Actinium-228 0.531 4I0.105 0.0287
+0.103 Amnercium-241 U
-0.016
+1-.0416 0.0368./.0.0408 Bismuth-212 0.292
/10.149 0.0622
.- 0.146 Bismuth-214 0.466
+/-0.0591 0.0144 +/-0.0579 Cesium-134 U
0.0196 4/-0.0166 0.0103 +/-0.0162 Cesium-137 0.0849
+1-0.0188 0.00832 +/-0.0185 Cobalk-60 U
0.00329
+/-0.0106 0.00914 +/-0.0104 Europium-152 U
0.00861
+1-0.0265 0.023
./-0.026 Eiropium-154 U
-0.0363
+.-0.033 0.026 +1-.0323 Europium-lSS U
0.0229
+W-0.0259 0.025 +1-0.0254 Lead-212 0.460
+/-0.0486 0.0137 +1-00476 Lead-214 0502
+/.062S 0.0164 +/0.0612 Manganese-54 U
-0.00366
+1-0.0102 0.00847
+1-0.010 Niobium-94 U
0.00155
+1-0.008S4 0.0074 +1-0.00837 Potassium.40 12.2 40.972 0.0688
+1-0.953 Radium-226 0.466
+/-0.0591 0.0144 +10.0579 Silver-108m U
0.00367
+1-0.00871 0.00744+/-OD0853 Thallium-208 0.159
+1-0.0277 0.00851 +4-0.0272 0.060 0.0749 0.129 0.0299 0.0214 0.0173 0.0193 0.0472 0.0547 0.0509 0.0279 0.0336 0.0176 0.0153 0.147 0.0299 0.0153 0.0176 pCL/g pC1g pcOIg pCi/g pCi/g pClIg pCi/g pCil/g pCi/g pCVg pi0/g pCVg pcWg pC99 pCig pCirg PCl/g SRB 06/07/04 1942 335651 1 The foUowlng Prep Methods were pertonmed Method Description Analyst Date Time PrepBatel DrySollPrep DrySoilPrepGL-RAD-A-021 MIMI 05/20/D4 1441 334885 The following Analytcal Methods were prformed Method Description I
EML HASL 3004.523 Notes:
lhe Qualifiers in th report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tracer recoveri.
E Concentration of the target analyte exceeds the instrument calibration range-29
-GE ER E
I' GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.geLcom Certificate of Analysis Company: Connecticut Yankee Atomnic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424
Contact:
Mr. Pete ilollenbeck Report Date: Junc 24,2004 Page 2 of 2 Project:
Soils Po# 002332 Client Sample ID:
Sample 10:
9535-0001-008F 113282001 Proiect:
YANK00504 Client M;.
YANK00 Vol. Recv.:
Parameter Qualifier Resnlt Uncertlnty LC TPU MDA Units DF Analystate rime Bateb Mtd.
H Analytical holding time exceeded.
1 Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
U1 Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier please sec case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
R tevCie (A we b t cyQ Reviewed by 30
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 558-8171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Petw Hollenbeck Project:
Soils PON 002332 Report Date: June 24,2004 Page 1 of 2 Client Sample ID:
Sample ED:
Matnx:
Collect Date:
Receive Date:
Collector:
Moisture:
9535-0001-OO8FS 113282002 Soil 22-APR-04 19-MAY-04 Client 3.57%
Api~ect YANK00504 Vol.
YANK00 Vol. Recv.:
Pmnmeter Qualifier Result Uncertainty LC TPU MDA Unilts DF AnalystDte Time Batch Mitd.
Rad Gamma Spec Analysis Gammajpec, Gamma. Solid-FSS GAM& ALA FSS Acdnium-228 0.524
+1-0.091 0.0259 t/-0.0892 Arnericium-241 U
-0.00613
+/-0.0393 0.034 +/-0.0385 Bismulh-212 0.326
+/-0.127 0.0522
+/-0.125 Bismuth-214 0.446
+1-0.0612 0.0134 t{-0.060 Cesium-134 U
0.00 4/-0.0168 0.0104 +1-0.0165 Ul Cesium-137 0.172
.1-0.0222 0.00769 +1-0.0217 Cobalt-60 U
0.00842
+1-0.00966 0.00847+140.00946 Europium-152 U
0.00254
+1-0.0214 0.0193
+/-0.021 Europium-154 U
0.0515
+.-0.0341 0.0257 +/4-0.0334 Europiun-ISS U
0.0444
+14.0366 0.0221 +t40.0358 Lead-212 0.510
+1-.0466 0.0113 4-0.0457 Lcad-214 0.454
+1-0.0529 0.0141 O1-0.0519 Manganese-54 U
0.00935 4-0.0125 0.00794 +0.0123 Nlobium-94 U
-0.00345
+t-0.00784 0.00646+1-0.00768 Potassium-40 11.0
+/ 0.824 0.0673
+4.808 Radium-226 0.446
+14.0612 0.0134
+/-0.060 Silver-lOSm U
-0.0067
+1-0.00749 0.00641 +14.00734 Thallium-208 0.159
+1-0.0245 Q00801
+/-0.024 0.054 0.0692 0.109 0.0277 0.0215 0.0159 0.0178 0.0397 0.0537 0.045 0.023 0.029 0.0165 0.0134 0.143 0.0277 0.0132 0.0165 pCi4 pCl`/g PCVg pCVg pCi/g pCi/g pCiVg pCi/g PUS/
pCitz pCI/g pollg pelVg PCI/g p0l/g pCi/g pCits pC11g SRB 06
/7104 1942 335651 1 The following Prep Methods were performed Method Dacriptlion Analyst Date Time Prep Batch Dry Soil Prep DrySoilPrepGL-RAD-A-021 Mimi 05t2CQ'04 1441 334885 Tbh following Anaiyical Methods were perfonned Method Description I
BML HASL 300,4.52.3 Notes:
The Qualifiers In this report are defined as follows:
B Target analyte was detected in the sample as well as the assodated blank.
BD FagforrcswtseMlowtheMraflagfoa ow tracerrcovery.
E Concearaidon of the target analyte exceeds the insbtment calibration nge.
31
GENERAL ENGINEERING LABORATORIES, LLG GENERAL ENGINEERING LABORATORIES., LLC 2040 Savage Road Charleston SC 29407 - (843) 555-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
iHaddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck ProJect Soils PON 002332 Report Date: June 24,2004 Page 2 of 2 Client Sample 1D:
Sample ID:
9535-0001-008FS 113282002 Pric: YANK00504 ClicntD:
YANKO01 Vol. Recv.:
Parameter Qualifier Result Uncertainty LC TPU MDA UDItS DF AnalystDate TMbe Batch Mtd.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting linit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozilk Jkc{
C S tt Reviewed by 32
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 6568-171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
lladdam Neck Plant 362 Injun Hollow Road East Hampton. Conneticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24.200 Page I of 2 Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
Moisture:
9535-0001-OOIF 113282003 Soil 22-APR-04 19-MAY-04 Client 4.2%
Proiec:
YANKOOS04 Cent 10:
YANKOOI Vol. Recv.:
Parameter Qualifier Result Uncertalnty LC TPU MDA Unltts DF AnaystDate Time BatchMtdI Rad Gamma Spec Analysis Gammaspec, Ganma. Solid-FSS CAM & ALL FSS Actinium-228 0.568 Americium-241 U
0.0143 Bismuth-212 0.456 Bismuth-214 0.720 Cesium-134 U
0.00 Ul Ceslunt-137 0.138 Cobalt-60 U
0.00852 Europiun-152 U
-0.0014 Europlum-154 U
0.00212 Europium-155 U
0.00 Ul Lead-212 0.606 Lead-214 0.855 Manganese-54 U
-0.0056 Niobium-94 U
0.00697 Potmlum-40 11.7 Radium-226 0.720 SIlver-lam U
0.00125
+
Thallium-208 0203
+1-0.104 0.0269
+1-.102
+1-0.0378 0.0333 W-0.0371
+1-0.124 0.0578
+/-0.122
+1.0.0752 0.0139 +/-0.0737
+1-0.0162 0.0101 +1-0.0159
+1-0.0185 0.00757 +/-0.0181
+1.0.0104 0.009 +1-0.0102
+1-0.0239 0.0201 +/4.0235
+1-0.0556 0.0267 +/-0.0545
+1-0.0337 0.0205
+/.0033
+/O0.0537 0.0116 +/-0.0526 4-0.0857 0.0137
+/-0.064
+/-0.0106 0.00849 +1.0104
+/-0.0086 0.00745 /400.843
+J-0.891 0.0687
+/-0.B73
+-10.0152 0.0139 +140737
-0.03759 0.00674 +1 0.00744
+/4-0.0286 0.00743
+4-0.028 0.056 0.0677 0.120 0.0286 0.0208 0.0157 0.0189 0.0411 0.0557 0.0418 0.0236 0.0281 0.0176 0.0154 0.146 0.0286 0.0139 0.0153 pCilg pCilg pCi/g pCUg pCi/g pCUg yCV9 pCi/g pCi/g pCi/g pC/g pCi/8 pCVg PCUS pCVg pCi/g pCi/g SRB 06107104 1943 335651 1 Tne following Prep Methods were performed Method Description Analyxt Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A4021 MiMI os02nY04 1441 334885 The following Analytical Methods were performed Method Description I
EML HASL 300.4.513 Notes:
The Qualifiers in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blan.
BD Flag formsults below the M)Coraflag for low tracerrecovey.
33
GENRA EGIEEIN LA O-ATOR-ES--
LC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 558-8171 - www.gel.com Certificate of Analysis I
I' Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hanpton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page 2 of 2 Client Sample ID:
Sample ID:
9535-OO0t-OOIF 113282003 8piect:
YANK00504 treni ID; YANKOOI Vol. Recv.:
Parameter Qualler Result Uncertainty LC TPU MDA Unit DF AnalystDate 71me Batch Mtd.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
J Indicates an estimated value. Tbe result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain Identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative. data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
hk(.
Reviewed by 34
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Proect:
Soils PO# 002332 Report Date: June24, 2004 Page I of 2 Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
9535-0001-018F 113282004 Soil 22-APR-04 19-MAY-04 Client 4.63%
PCpiect:
YANK00504 C
tD. YANKRc Vol. Recv.:
PvUMae.tor Cualln.r RuTtl Un."nv IAT1 M
A tf.It.
n?
A I4It4.e TL..R.
t t
- .*Lg~**
AA..
LA
- rI AWIv
. Rad Gamma Spec Analyasi Gammapec. GCamA Solid-FSS GAM & ALL FSS Actinium-228 0.549
+1-0.0881 0.0245 44-0.0863 0.0514 Amaiclum-241 U
0.0154 t-0.0323 0.0314 +/-0.0317 0.0639 Bismuth-212 0365
+1-0.118 0.0521
- /-0.115 0.109 Bismuth-214 0.527
+f-0.058 0.0127 +4-0.0568 0.0263 Cesium-134 U
0.0161
+1-0.0167 0.0094 +1-0.0164 0.0195 Cesium-137 0.102
+1-0.0172 0.00725 +14.0169 0.01SI Cobalth6 U
-0.00111
+./0.0107 0.00793 +1-0.0105 0.0168
£uropium-152 U
-0.011
+/-0.0225 0.0189 41-0.0221 0.0389 Europium-154 U
0.0258
+/-0.0287 0.0247 +/-0.0281 0.0518 Europlum-1SS U
0.0309
+1-0.0333 0.021 +/-0.0327 0.0428 Lead-212 0.548
+/,0.0494 0.0112 +1-0.0484 0.0229 Lea214 0.578
+/-0.0635 0.0132 +/.00622 0.0272 Manganc-54 U
0.00191
+1-0.00863 0.00741+/-0.00846 0.0155 Niobium-94 U
0.00715
+/-0.00744 0.00669 W4.00729 0.0139 Potassium-40 113
./-0.848 0.0769
/4.831 0.163 Radium-226 0.527
+1-0.058 0.0127 *1.0.0568 0.0263 Silvcr-108m U
-0.0045
+/-0.0073 0.00593 +/.0.00715 0.0123 TZslli0.208 Q160
+4.0233 0.007 -W-0.0229 0.0145
^U0 A.a rJ DN ALUM DAUVM&.
pCitg pCUg pCig pCtg pCVg pCi/g pCi/g pCUg pci/g PCW5 pCi/g pCVg pCi/g pCi/g palg pcig pCitg pCi/g SRB 0607/04 2022 33S651 1 Tne fo!!onog Prep Methods were performed Method DesripUon Analyst Date T7ne Prep Batch Dry Soil Prep Dry Soil Prep GL.RAD-A-021 MJMi 05/204 1441 334885 The following Analytc Methods were performed Method Decription I
EML HASL 300.4.5:23 Notes:
The Qualifiers in this report are defined as follows:
B Target analyto was deteced in the sample as well as the associted blank BD Flag for results below the MDC or a flag for low tracer rccovcey.
E Concentadon of the taret analyte exceeds the instnmet calibtion rang 35
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savago Road Charleston SC 29407 - (843) 656-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 InJun Hollow Road East HlImpton. Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PON 002332 Client Sample ID:
Sample 1ID.
Report Date: Junc 24,2004 Page 2 of 2 9535D00l1-OIBF 1 13282004 Wplect YANKOOS04 Volnt.I:
YANK001 Vol. Recv.:
Psrameter Qualifier Result Uncertainty LC TPU MDA Units DF AnalystData llme Bath Mtd.
J Indicates an estimated value. The result was greaser than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limiL UT Uncertainidentificationforgamnmaspectoscopy.
X lb-specific qualifier-please see case naruative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozilc Reviewed by a
I 36
GENERAL ENGiNEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5565171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Hiddam Neck Plant 362 Injun Hollow Road East Hampton. Connecicut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Client Sample D.
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
Report Date: June 24,2004 Pagc I of 2 9535-O0IOOIF 113282005 Soil 22-APR.04 19-MAY-04 Client 2.78%
Psinect YANK00504 c YANKOOI Vol. Recm.:
Parameter Qua-lflcr Result Uncertainty LC TPU MDA units DF AnalystDate Thue Batch Mtd.
Rad Gamma Spec Anlysts Gammpec, Gawmm4 Solid-FSS CAM & AU FSS Actinium-228 0.689 4/-0.113 0.0252
/.0.1l Americium-241 U
0.00691
+4-0.069 0.0563 +1.0616 Bismuth-212 0.508
+f-0.131 0.0556
+10.128 Bismnuth-214 0.535
+/-0.0599 0.0133 +14.0587 Cesium-134 U
0.00
+/-0.0165 0.010 +1-0.0162 Cesium-137 Cobalt-60 Europium-152 Europlum-S4 Europlum-ISS Lead-212 Lcad-214 Manganese.54 Niobium-94 Potasium40 Radium-226 Silver-lOSm Thalilum-208 U'
U LI U
U U'l 0.070S
+/-0.0154 0.00685 +1-0.0151 0.007
+t-0.0134 0.0082 +/-0.0131
-0.0187
+t0.0229 0.019 +t4.0224 0.00848 10.028 0.0243 +1-0.0275 0.00
+0.0428 0.024 +1-0.0419 0.0525 0115 0.115 0.0275 0.0M06 0.0142 0.0172 0.0391 0.0507 0.0488 0.0264 0.029 0.0145 0.0145 0.139 0.0275 0.0137 0.0149 Pci/g pCi/g pCVg pCi/g pC~g pCi/g PCV8 pCi/g pCi/g pCl/9 pci/g pCIg SRB 06/07/04 2023 335651 1 0.715
.1-0.0679 0.0129 +/-0.0665 0.612 4/-0.0666 0.0141
.4.0.0652 U
0.00782
+1/0.0137 0.00698
+/-0.0135 U
0.00621
+t-0.00794 0.00703 +/.0.00778 11.7
+1-1.03 0.0651
./-1.01 0.535
+/4.0599 0.0133 +t.0.05B7 U
0.00137
+t-0.00733 0.00665+t-0.00718 0.219
+/-0.0267 0.00719.-0.0262 The folowing Pren Methods were performed Method Description Analyt Date Thme PFep Batch Dry Sail Prep Dry Soil Prep GL-RAD-A-021 MJMI 05/2004 1441 334885 The following AnRlyical Methods were performed Method DeseriptIOD 1
ML HASL 300,452.3 Notes:
The Qualifiers in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tacer recoveiy.
37
I GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (848) 55668171 -www.gel.com Certificate of Analrsis Company: Connicut Yankee Atomic Power Address:
'Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Client Sample ID:
Sample ID:
Report Date: June 24,2004 Page 2 of 2 9535-0001-OOIF 113282005 Ptct YAN'KO0S04 CPientnD:
YANK005 Vol. Recv.:
Parmeter Qualtr Result Uncertainty LC TPU MDA Units DF AnalystDate Tlme Batch Mtd.
E Concentration of the target analyte exceeds the instrument calibration range.
I1 Analytical holding time exceeded.
1 Indicates an estimated value. The resuit was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Reviewed by 38
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 656-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Pmject:
Soils PON 002332 Repon Date: lone 24,2004 Page I of 2 Client Sample ID Samnple ID:
Matnx:
Collect Date:
Receive Date:
Collector Moisture:
9535-0001-003F 113282006 Soil 22-APR-04 19-MAYA04 Client 4.22%
Vpoi.cvn.D:
Vol. Rcv.:
YANKOOSO4 YANKOOI Paruneter Qualifier Reult Uncerainty LC TPU MDA Units DF AnalytDate Trme Batch Mtd.
Rad Gain Sp Analysis GaOmmm
U
-0.00513 Bismuth-212 0316 Blsmutb.214 0596 Cesium-134 U
0.0195 Ccsium-137 0.103 Cobalt-60 U
-0.000693 Europium-152 U
0.00902 Europhum-154 U
-0.00962 Europium-1SS U
0.00 UT I sd-212 0.534 Lcad-214 0.598 Mangancse-54 U
0.0035 Niobium-94 U
0.00947
+
Potassium-40 11.6 Radium-226 0.596 Silver-108m U
0.00218
+
Thallium-208 0.172
",-00994
+/4.0134 WJ-0.162
+/-0.0733
.41-0.0183
+1-0.0208
+1-0.0113 41-0.0238
+14.0334
+1-.0334
+/-0.0532
+/-0.0689
./-0.0142
/-0.00962
+/0.U49 t.-0.0733 0.00861 41-0.0284 0.0318 0.0124 0.0736 0.0168 0.0114 0.00868 0.00967 0.0213 0.0283 0.019
+I400974
./.00131
+1/0.159
+/10.0718 4-0.0179
/-0.0204
+I-.0111 t1-0.0234 4/-0.0328
+/-0.0327 0.0665 0.0252 0.153 0.0347 0.0237 0.018 0.0204 0.0437 0.0594 0.0385 0.026 0.0321 0.0187 0.018 0.172 0.0347 0.0154 0.019 pUS/
pCi/g pCVg pcLk pCi/g pCi/g pC11g pCI/g pCVg pC119 pCiJ/g pC119 pcilg pCl/9 pci/g PQ/g SRB 06/07/04 2026 335651 1 0.0127 +1-0.0521 0.0156 +/-0.0675 0.0895 +40.0139 0.00872 +/-0.00943 0.0807
+1-0.832 0.0168 +1-0.0718 0.00747 4/0.00843 0.00916 +1-0.0278 The followig Prep Methods were performed Method Description Analyst Date 71me Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 MiMI 05/20/04 1441 334S85 The followln Analytical Methods were performed Method Description I
EML HASL 300,4.5.2.3 Notes:
Mie Qualifiers in this report are defined as follows:
B Target analyte was detected io the sample as wel as tbe associated blank BD Flag for resuts below the MDC or a flag for low tracr rcovery.
E Concentration of the target analyte exceeds the instrument calibration range.
39
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5B6-8171 - www-gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PON 002332 Report Date: June 24,2004 Page 2 of 2 Client Sample ID:
Sample ID:
95354001-003F 113282006 rpyiec:
YANK00504 lent ID:
YANKOOl Vol. Recv.:
Parmeter Qualifer Result Uncetlainty LC TPU MDA Units DF AnalystDate lme BIatcbMtd.
f H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit U
Indicates the target analyte was analyzed for but not detected above the detection limit UI Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summay package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your ProJect Manager. Sarah Kozlik.
l Reviewed by 40
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES., LLC 2040 Savage Road Charleston SC 29407- (843) 558-8171 - www.gel.com Certificate of Analysis IL Company: Connecticut Yankee Atomic Power Address:
Haddasn Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24. 2004 Page I of 2 Client Sample ID:
Saunele ID:
Matrlx:
Collect Date:
Receive Date:
Collector Moisture:
9535-001-004F 113282007 Soil 22-APR-04 19-MAY-04 Client 4.58%
8r9iect YANKOOS04 Lltent ID:
YANKOOI Vol. Recv.:
Poameter Qualifier Result Uncertainty LC TPU MDA Un'ts DF AnalystDate Time Batd, Mtd.
Rad Gamra Spec Analyzb I
Gammwpec, Gmnua Solid-FSS GAM & AL FSS Actiaium-228 0.487
+-0.0965 Alrncicium-241 U
-0.0199
+1-0.0363 Bismuth-212 0354
+".1-68 Bismuth-214 0.567
+1-0.0659 Cesium-134 U
0.00
+140161 Ul Cesiuro-137 0.0973
.1-0.0193 Cobalt-60 U
-0.00465
+-0.00919 Europium-152 U
-0.00685
+1.0223 Europlui-154 U
0.0001Q 5
+-0.029 Europium-lSS U
0.0247
+/.0.0235 Lead-212 0.578
./-0.0533 Lead-214 0.542
.1-0.0625 Manganese-54 U
0.00894
+1-0.0184 Nioblum-94 U
0.00373
+/-0.00796 Potassium-40 12.3 t.-0.992 Radium-226 0.567 41-0.0659 Silver-108m U
0.00789
.1-0.00845 Iballum-208 0.180
+/-0.0248 0.0262 +/-0.0946 0.0332.1-0.0355 0.0579
+140.164 0.0133 +1-.0646 0.00992 +0.0158 0.00756 +100189 O.00739 4-0.00901 0.0196 +/-0.0218 0.0243 +".00284 0.0234
+4/.023 0.0116 +1-0.0522 0.0139 +14.0612 0.0079 +/-0.0181 0.0068 +1-0.0078 0.0645 +1-0.972 0.0133 41-0.0646 0.00676 +1-0.00828 0.00739 +/-0.0243 0.0546 0.0675 0.120 0.0275 0.0205 0.0156 0.0156 0.0402 0.0507 0.0475 0.0237 0.0285 0.0164 0.0141 0.137 0.0275 0.0139 0.0153 P019 pCi/g pCilg pCi~g pC~g pC~fg pCi/g pC1/g pCi/g pCVg pCi/g PCI,'
pCl/g pCilg pCUg pcllg pCVg PC14 SRB 06W/704 2041 335651 1 Ihe royig Prep Methods were performed Method Descriptlon Analst Date 7ltme Pp Bath Dry Soil Prep Dry Soil Prep G-BPAD-A-021 MIMI 05120(04 1441 334885 The folowing Anyical Methods were performed Method Descriptio I
EML HASL 300 4.523 Notes:
The Qualffiers in this report we defined as follows:
B Target analyte was detected in the sample as wel1 as the associated blank.
BD Flag for reults below the MDC or a flag for low tracer recovesy.
E Concentradon of the target analyte exceeds the iasttument calibration range.
41
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 566-8171 -www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424 I-Contact Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page 2 of 2 Client Sample ID:
Sample ID:
9535-000I-004F 113282007 PMiDct YANKOOS04 Cl C YANK0 Vol. R-ecy.:
Parameter Qualiler Result Uncertahity LC TPU MDA Units DF Analystate hane Batch Mtd.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting lirnit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification for amuma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any quesdons to your Project Manager. Sarah KozlikL 4ht ssK (S0 tcdckD Reviewed by 42.
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556.8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Iladdam Nock Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page I of 2 Client Sample ID:
Samplc ID:
Matrix:
Collect Date:
Receive Date:
Collector.
Moisturc:
9535 000-41FS 113282008 Soil 22-APR-04 19-MAY-04 Client 4.31%
troiecr YANCOOS()4 CltentID:
YANKOOI Vol. Recv.:
Paraneter Quatlter Result Uncertainty LC TPU MDA Units DF AnalystDat ltme Batch Mtd.
Rad Gamma Spec Analysi Gammatpec, Ganmmi Solid-FSS GAM & ALU FSS Actinium-228 05S2
+/-O.102 0.026 +1-0.0999 Amnercium-241 U
0.00
+/40.384 0.0336 +/-0.0376 Ul Bismuth-212 0.395
+1-.148 0.0588
+1-0.146 Bismuth-214 0.585
+t-0.065 0.0138 +/40637 Ceuium-134 U
0.00
+/.0.0143 0.00983
+/-0.014 UT Cesium-137 0.0971
+/-0.0174 0.00838
+.0.017 Cobalt-60 U
0.00915
+/4.00986 0.00875 +M.00966 Europium-52 U
40.00345
+/0.0238 0.0209 +/4.0233 Europium-154 U
-0.0294
+-0.0313 o.m52 +/-0.0307 Europium-155 U
0.00908
+1.0.026 0.0237 +1-0.0255 LcSd-212 0.547
./-0.0514 0.0126 +/-0.0503 Lead-214 0.620
+1-0.066 0.0147 +/-0.0647 Muangnese-54 U 9.660E-05
+1-0.010 0.00855 +1-.00984 Niobium-94 U -0.000439
.140081 0.00701 +/-0.00793 Potassium40 11.5
+/4.887 0.0667
+/4.69 Radium-226 0.585
+1-0.065 0.0138 +/.0637 Silver-108m U
0.00184
+4.00785 0.00682+/-0.00769 Tba~lium-208 0.170
+1-0.0241 0.00794 +1-0.0236 0.0541 0.0682 0.122 0.0285 0.0203 0.0173 0.0183 0.0427 0.0526 0.0482 0.0256 0.30 0.0177 0.0145 0.142 0.0285 0.014 0.0164 pCi/g pC1/g pitg pCi/g pCi/g PUS/
pCi/8 PCi/g PCi/9 pC11g pCijg pCO1g PCi/9 pC11g SRB 060710 2123 335651 1 The fio!iag Prep Methods were performed Method Description Analyst Date llme Prep Batch Dyr Soil Prep Dry Soil Prep G1-RAD-A-21 MiMI 0S/O204 1441 334885 The followin Analytical Methods were performed Method DeserptlOn I
EML HASL 300.452.3 Notes:
The Qualifiers In this rport are defed as follows:
B Target analyte was detected In the sample as well as the associated blanL.
BD Flag for results below the MDC or a flag for low tracer rcovery.
43
GENERAL ENGINEERiNG LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 558-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
lladdamn Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck ProNect:
Soils POP 002332 Report Date: June 24, 2004 Page 2 of 2 Client Sample ID:
Sample lID:
9535-0001-004FS 113282008 Proiect:
YANK00504 CLent iD:
YANK001 Vol. Recv.:
Parametcr Qualifer Result Unertainty LC TPU MDA Units DF AnalystDatt Mm Batch Mtd.
E Concentration of the target analyte exceeds the instunent calibration range.
H1 Analytical holding time exceeded.
1 Indicates an estimated valueG The result was greater than the detection limit, but less tman the reporting liit.
U Indicates he target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
Ihe above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Reviewed by 44
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gelcom Certificate of AnalYsis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. PetM Hollenbcck Project:
Soils PO# 002332 Report Date: Junc 24,2004 Page I of 2 Client Sample ID:
Sample ID:
Matix:
Collect Date:
Receive Date Collector:
Moisture:
9535-0001-OOSF 113282009 Soil 22-APR-04 19-MAY-04 Client 6.4%
Proec:
YANK00504 ole.
YANKRC Vol. Recv.:
Parameter QuaWlfier Result Uncertainty LC TPU Rid Gamma Spec Analysis Gammaspec. Gamrma Sold.FSS CGA
& ALL FSS Actinlum-228 0.512
+1-0.0971 0.0258 +1.0.0952 Americium-241 U
-0.00397
+1-0.0521 0.0439 +/-.0511 Bismuth-212 0.380 14-0.142 0.0562
+"10.139 Bismuth-214 0.594 04.0654 0.0133 +t-0.0641 Cesiumn-134 U
0.018
+t-0.0168 0.00964 +40.0164 Ccsium-137 0.313
+/40288 0.00715 40.0282 Cobak-60 U
0.00379
+t-0.00997 0.0083440.00977 Europium-152 U
-0.00278
/4.0222 0.0198 W-0.0218 Europium-1S4 U
0.00143
+4-0.0292 0.0245 41-0.0286 Europium-15S U
0.0258
+1-0.0253 0.0233 +140248 Lead-212 0.592
+-0.0587 0.0113 /-0.0575 Lead-214 0.589
+/.0.0634 0.0138 +0.0621 Manganese-54 U
0.00719
+t-0.0101 0.00752 -0.00989 Nlobium-94 U
0.000164 41-0.00861 0.006344+14.00844 Potasshun40 11.9
+410.989 0.0589
+14.970 Radium-226 0.594
+/-0.0654 0.0133 tl-0.0641 SUver-108m U
0.00227 l4.00744 0.0066 4-0.00729 Thallium-208 0.167 t./0245 0.00702
/4.0Z4 MDA Units DF AnalysUte Time Batch Mtd.
0.0537 0.0893 0.117 0.0274 0.0199 0.0148 0.0179 0.0406 0.0513 0.0475 0.0231 0.0283 0.0156 0.0131 0.126 0.0274 0.0136 0.0145 pOi/g pCVS pCi/g pCilg Pci/g PCilg PCI/g pCl/9 pCi/i pCV8 PCVg pCi/g pCl/g pCI/g PCi/g PCUg PUS' PCi/g SRB 0617/04 2124 33S651 1 me following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Sol Prep Dry Soil Prep GJRAD-A-21 MiMI 05/20IG4 1441 33488S The foLlowEng Analytcal Methods were perfoared Method Description I
EhL HASL 300,4.5.Z3 Notes:
Ihe Qualifiers in this report arm defined as follows:
B Target analytc was detected in the sample as well as the associated blanl.
13D Flag for results below he MDC or a flag for low tracer recovery.
E Concentration of tbe target analyte exceeds the instrsnent calibation nmge.
45
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 55688171 - www.gel com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Ionju Hollow Road East Hampton. Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Sails PO# 002332 Client Sample ID:
Sample ID; Report Date: June 24,2004 Page 2 of 2 9535-400-005F 113282009 proiect:
YANK00504 Client tD:
YANKOOl Vol. Recv.:
Parameter Qualer Resutt Uncertainty LC TPU MDA Units DF AnalystDate Time RatclMtd.
H Analytical bolding time exceeded.
I Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates tbe target analyte was analyzed for but not detect above the detection limdt.
U1 Uncertain Identification for gamma spectroscopy.
X Lab-specific qualifier-please wee case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozdlk.
Reviecwb (y
Reviewved by 46
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556.8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Addrss:
Haddam Neck Plant 362 Injun Hollow Road East Hanpton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils P0# 002332 ReportDate: June24, 2004 Page I of 2 Client Sample ID:
Sample ID:
Matrwx:
CoUect Date:
Receive Date:
Collector.
Moisture:
9535-OO0-007F 113282010 Soil 22-APR.04 19-MAY-04 Client 4.8%
Afiec:
YANK00504 Went SD:
YANK001 Vol. Rccv.:
Parameter Qualier Result Uncertainty LC TPU MDA units DF AnalystDate Tnme Batch Mtd.
Rad Gamma Spec Anaysis Gnmawpec, Gamma, Solld-FSS GAM & ALL FSS Actinium-228 0,437
+/40958 0.0259 +4-10939 Americium-241 U
- 0.00235
+1-0.0503 0.0442 +140.0493 Bismuth-212 0.273
+1-0.121 0.0536 41.119 Bismuth-214 0.481
- -0.0596 0.0132 14-0.0584 Ccsiun-134 U
0.00
+1.0.014 0.00963 +1-0.0138 Ul Cesium-137 0.0894
+-0.0216 0.00733 +1-0.0212 Cobait-60 U
-0.00943 W1-000898 0.00692 +/-0.0o88 Eumpium-152 U
4.0157
+1-0.0237 0.0196 +1-0.0232 Europium-154 U
0.015 M0.0306 0.0266 +10.0301 Europium-155 U
0.0334
+0.0329 0.0228 +J-.0323 Lead-212 0.496
+1-0.057 0.0124 +1-0.0558 Lead-214 0.592
+1-0.0677 0.0138 4/-0.0664 Manganese-54 U
0.0101
+-0.0097 0.0048 +1.00951 Niobium-94 U
0.00724
+1/0.00787 0.00696+4-0.00771 Potassium-40 12.0
+/-0.964 0.0633
/-0.944 Radium-226 0.481
+1-0.0596 0.0132 +1-0.0S84 Silve-108m U
0.000791
+/4.00728 0.00653./0.00713 Thallium-208 0.158
+/-0.025 0.00713 +/4.0245 0.0541 0.0902 0.112 Q0273 0.0199 0.0152 0.0148 0.0404 0.0557 0.0464 0.0253 0.0285 0.0176 0.0144 0.136 0.0273 0.0135 0.0148 pidg pCI/g pci/g pCi/g pCig pCl/g pCUg PCI'S pCL'g xC/g pcifg pCi/g pC g PUS pCVg pC1g pci/g SRB 06107/04 2205 335651 I The following Prep Methods were performed Method Descdption Ana"s Date Time Prep Batch Dry Soil Prep Dry Soil Prep OL-RAD-A.021 MiMI 05/20/04 1441 334885 The following Analytical Methods were performed Method Description 1
EML HASL 300, 4.523 Notes:
The Qualiers In this report au defined as follows:
B Target ana'yte was detected in fhe sample as well as te asociated blan.
BD Flag for results below the MDC or a flag for low tracr recovery.
E Concentration of the target analyte exceeds the insutenrt calibration range.
47
L GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIESt LLC 2040 Savage Road Charleston SC 29407 - (843) 550-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete flollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page 2 of 2 Client Sample ID)
Sample ID:
9535-O001-007F 113282010 LiCCt YANK00S04 Vol. ReCv.:
Parameter Qualifier Result Uncertainty LC ITU MDA Units DF AnalystDate Tize Batch Mtd.
11 Analytical holding time exceeded.
1 Indicates an estlmated value. The result was greater than the detection limit, but less than the reporting limiL U
Indicates thetaget analyte was analyzed for but not detected above the dtection 1iMi Ul Uncertain Identification for gamma spectroscopy.
X Lab-specific qualifieraplease see case narrative, data summary package or contact your project manager for details.
h Sample prepzration or preservation holding time exceeded.
The above samplf Is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Reviewed by 48
G GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
lladdam Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424
Contact:
Mr. Pete follenbeck Project:
Soils PO# 002332 Report Date: Junc74,42004 Page I of 2 Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
Paramcter Quater Result Uncertainty Rad GCuma Spec AnalysiS Gammapec, Gamma, Sitd-FSS CAM & ALL FSS Actdnium-228 0.663
+t-0.130 Amciddum-24 l U
-0.0011
+./0.0639 Bismuth-212 0.431
+1-0.273 Bismuth-214 0.462
+1-0.0761 Ceslum-134 U
0.0271
+1.0.0299 Cesium-137 0.0929 4-0.0261 Cobalt-60 U
-0.00222
+/-0.0132 Europium-152 U
-0.00975
.1-0.0355 Europlum-154 U
0.0165 41-0.0549 Europlurni-SS U
0.0359
+1-0.0502 Lead-212 0.525 F10.0589 Lead-214 0-539
+/-0.0857 Manganese-54 U
0.00 M-0.0346 IT Niobium-94 U
0.00273
+1-0.0129 Potassiurn40 13.5
+1-1.17 Radium-226 0.462
./-0.0761 Silver-08m 0.00898
+1-0.0131 TWllium-208 0.175 t.10.0347 9S35-0001-OIOF 113282011 Soil 22-APR-04 19-MAY-04 Client 3.19%
I LC TFU MDA Units DF AnalystDate llme Batcb Mtd.
0.0476
+t/0.127 0.0555 +1-0.0626 0.0983
+/-0.267 0.0228 4"-0.0746 0.0169 +0.0293 0.0118 +".0256 0.0111
+t-0.013 0.0298 4/-0.0348 0.0461 +.-0.0538 0.0375 +. 0.0492 0.0194 4/.0577 0.0212 +t4.084 0.0132.10.0339 0.0114 1-0.0127 0.103
+/-1.14 0.0228 +1-0.0746 0.0115 +J-0.0128 0.013
+1-0.034 0.102 0.115 0.210 0.0484 0.0359 0.0252 0.0249 0.0627 0.0994 0.0775 0.0402 0.0446 0.0283 0.0242 0.233 0.0484 0.0242 0.0276 pCitg pC-Vg pCilg pCl/g pCilg pClg pC0g pCi/g pCVIg pCitg PCUS pC1tg SRB 0610St04 0946 335651 1 1pinct YANK00504 tlentw:
YANKOOI Vol. Remv.:
pCi/g PCI/9 pCUg pCi/g pCi/g Tbe following Prep Methods were performed Metbod Description Analyst Date lime Prtp Bateb Dry Soil Prep Dry Soil Prep GlRAD-A-021 Mmi 05/204 1441 334885 The following Analytical Methods were performed Method Description I
EML IHASL 300,4.52.3 Notes:
The Qualifiers in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results blow the MDC or a flag for low tracr recovery.
E Concentration of the target analyte exceeds the instrment calibiation range.
49
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chaleston SO 29407 - (843) 656-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankce Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424
Contact:
Mr. Pete Hoflenbeck Report Date: Junc 24, 2004 Page 2 of 2 Prolcst Soils POA 002332 Client Sample ID:
Sample ID:
9535-0001-O010 113282011 Zroiecte YANKOO504 Client ID:
YANKOOI Vol. Recv.:
Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analystlate Time Ratb Mtd.
11 Analytical holding time exceeded.
1 Indicates an estimated value. The result was greater than the detction lmit, but less than the reporting limit.
U Indicates thc target analyte was analyzed for but not detcted above the detection limriL Ul Uncertain Identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative. data swmmary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik Reviewed by 50
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analys I
Company: Connecticut Yankee Atomic Power Address:
Haddan Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils MgO#D02332 Repoit Date: June 24,2004 Page I of 2 I
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Colloctor:
Moiswre:
9535-0001 O-9F 113282012 Soil 27-APR-04 19-MAY-04 Client 9.48%
Clet-YANK00504 Cent
- YANKOI Vol. Recv.:
Parameter QualiNer Result Uncertainty LC TPIU MDA Units DF AnTlystDate fme batdi Mat.
Rad Gamma Spec Analysis Gammaiptc. Gamma, Solid-FSS GAU A ALL FSS Actinlum-228 0.524
+/-0.132 0.0455 4-0.129 0.097 Americium-241 U
0.0641 4/-0.0761 0.0742 +40.0746 0.153 Bismuth-212 0.195
+/-0.141 0.0839
+1-0.138 0.10 Bismuth-214 0.557
+/-0.075 0.0236 +/0.0735 0.0496 Cesium-134 U
0.0221
+/40.0193 0.015 +t4.0189 0.0318 Cesium.137 0.062
+1/0.0243 0.0121 +/-0.0238 0.0257 Cobalt:60 U
0.00315
+10.0169 0.0144 +/-0.0165 0.0312 Europium-152 U
-0.00603
+140.0344 0.0307 4/40337 0.0643 Europlum-154 U
4.0159 tJ4.0435 0.0395 +/-0.0475 0.0854 Europlum-15S U
-0.00393 4/40405 0.0371 +J.0.0397 0.0765 Lead-212 0.494
+".0611 0.0199 41-0.0599 0.0412 Lead-214 0.536
+4-0.079 0.022 +/-0.077S 0.0459 Mangmnese-54 U
-0.00291 1-0.0149 0.0121 J-0.0146 0.0259 Niobium-94 U
0.00149
+/-0.0128 0.0109 +/.0126 0.0232 Potassium-40 129
+/ 1.23 0.102
.1-1.20 0.228 Radiumn-226 0557 "14.075 0.0236 +1-0.0735 0.0496 Silver-lOSm U
0.0109
+"-0.0107 0.0103 +1.0104 0.0216 lballium-208 0.189
+/-0.0306 0.012
+1.0.030 0.0253 pCi/g pCltg pCi/g pCi/s pCi/g pCi19 pCVg pCi/Z pCVg pC118 pCilg pCVg pcifs pCi/g pCi/g pCV8 PC1g SRB 06/0V04 0947 335651 I The following Prep Methods were performed Method Desiption Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 mIMI OS/20/04 1441 334885 The following Analytical Methods were performed Method Description I
EML HASL 300,4-5.53 Notes:
'Me Qualifiers in this report are defined as follows:
B Target analyte was detected In the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
51
a F
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 558-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete llollenbeck Project:
Soils PON 002332 I
Report Date: Junc 24,2004 Page 2 of 2 Client Saunple ID.
Sample ID:
9535.0001-009F 113282012 Af icctD:
YAN0050.4 Vo.ent ID:
YANKOOI Vol. Recv.:
Parameter Quaifer Result Uncertainty LC TPU MDA UnWts DF AnalysDate Time Batch Mtd.
H Analytical holding time exceeded.
J Indicatus an estimated value. The result was greatr than the detection limit, but less than the reporting limit.
U Indicates the arget analyte was analyzed for but not detcwted abovr the detection limit.
UI Uncertain identification for ganna spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for detalls.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data repon has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
- k~%W22(, u Reviewed by 52
GN LA-ORATORIE----L-a GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of AnalLysis Company:
Connecticut Yankee Atomic Power Address:
Hladdam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project Saits PO# 002332 Client Sample ID.
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
Report Date: June 24.2004 Page I of 2 9535-0001-012F Proiect:
YANK00504 113282013 Client ID:,
YANKOO1 Soil Vol. Recv.:
27-APR-04 19-MAY-04 Client 125%
Proneter Qualifier Rmesut Unceriainty LC TPU MDA Units DF Anae Timc Btch Mtd.
Rad Ganma Spec Analyds Gammxpec. GCamm Solid FSS GAM A ALL FSS Acdnium-228 0.471
+1-0.130 0.0468
/1-0.127 Americium-241 U
0.00555
+1-0.0618 0.0539 +/-0.0605 Bistnutb-212 0.494 40.217 0.0998
+/-0.213 Bismuth-214 0569
+1-0.0829 0.0224 +1-0.0812 Cesium-134 U
0.00479
+1-0.0182 0.0154 +/10.0178 Ccium-137 0.0412
+/-0.0227 0.0139 +/-0.0222 Cobaltu60 U
-0.00668
+"-.017 O.134 1-0.0167 Europium-152 U
0.0254
+/10.0373 0.0325 4/-0.0365 Europium-154 U
0.0239
+/-0.0621 0.0469 +/.0608 Europium-1SS U
0.0133
+1.0.0375 0.0352 +4.0368 Lead-212 0.527
+/4.0589 0.0192 +4.0577 Lad-214 0.571
+4.0832 0.0226 +/-0.0815 Manganese-U4 U
-0.00404
+-O.012 0.0147./14.0178 Niobium-94 U
0.00392
+14.0137 0.0118 +/-0.0135 Potassium40 13.1 4-1.16 0.122
+1-.14 Radium-226 0.569
+14.0829 0.0224 +-0.0812 Silver- 08m U
-0.00373
+1-0.0121 0.0104 +/-0.0119 Thallium-208 0.179 1-0.0388 0Q013
+1-0.038 0.100 0.111 0.213 0.0476 0.0327 0.029S 0.0294 0.0681 0.101 Q0726 0.0398 0.0473 0.0312 0.025 0.270 0.0476 0.022 0.0275 pCi/g pCi/g pC't pCi/g pCi/g pCi/g pC11g pCI/g pCI/g pCilg pCI/g pCi/g pCI/g pCi/g PCi,:
pCift pC/g pCUg SR.B 060184 0948 335651 1 The folowing Prep Methods were performed Method Description Analyst Date Time Prep Batch DrySoilPrep DwySoilPrepG ltRAD-A-021 MIMI os0oi/04 1441 334885 Tbe following Analytcal Methods were performed Method Destription I
EML HASL 300,4.5.2.3 Notes:
The Qualifiers in this report are defined as follows:
B Target analyte was detected In the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tracer recovety.
E Concentradon of the target analyte exceeds the instrument calibtadon mnge.
53
I' I'
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chadloston SC 29407 - (843) 555.8171 -www.gel.com Certificate of Analysis Company: Connecticut Yanke" Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampxon, Connecticut 06424
Contact:
Mr. Pete Holleabeck Project:
Soils PO# 002332 Report Date: Junc 24,2004 Page 2 of 2 Client Sample ID:
Sample ID:
953S-001-012F 113282013 Csioict YANKOO504 Colcntv1.):
YANKOO1 Vol. Rccv.:
Parameter Qualifier Result Uncertainty LC TPU MDA Units DF AnalystDate _lme Batch Mtd.
H Analytical holding time exceeded.
3 Indicates an estimated value. The result was greater than the detection limit, but ICs than the reporting limit.
U Indicates the target analyte was analyzed for but not deeced above the detection limit.
Ul Uncertain identificadon for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summazy package or contact your project manager for details.
h Sample prparation er preservation holding time excceded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
AQK~cLL (m C Reviewed by 54
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Hladdam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PON 002332 Report Date: lune 24.2004 Page I of 2 Client Sample: liD:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
9535-0001-013F ProiecD:
YANKOOS04 113282014 Clienty:
YANKO01 Soil Vol. ReOv.:
27-APR-04 19-MAY-04 Client 12%
Parameter Qualifier Result Uncertainty LC TPU MDA Units DF AnalystDate 1ime Batch Mtd.
Rad Gamma Spec Analysts Gammarpe4 GCamm Solid FSS GA A ALL FSS Actinlum-228 0.734 4-0.156 0.0436 4-0.153 Americlum-241 U
0.0224
+1-0.0713 0.0603 4-0.0698 Bismuth-212 0.593
+t-0.240 0.103
+/-0.235 Bismuth-214 0.573
+1-0.0881 0.0236 +1-.0863 Cesium-134 U
0.00
+/-0.0293 0.0193 +1-0.0287 Ul Cesium-137 0.0579
+1-0.0263 0.013 +1-.0258 Cobalt-60 U
-0.00151 t/-0.0177 0.0126 +140.0174 Europium-152 U -0.000172
+/-0.0398 0.0355
+./0.039 Europium-154 U
-0.00278 4J-0.046 0.0383 +1-.0451 Europium-ISS U3 0.0106
+1-0.0457 0.0416 +1-0.0448 Lead-212 0.761
+/-0.077S 0.0212
+/10.076 LSad-214 0.657
+/-0.0949 0.0246 +14.0931 Manganese-54 U
0.00112
+4-0.0157 0.0138.1-0.0154 Nioblum-94 U
0.0138
+/-0.0141 0.0126 +1-0.0138 Potassium-40 11.4
/-1.08 0.127
./-1.06 Radium-226 0.573
+1-0.0881 0.0236 1-0.0863 Silver-108m U
0.0036B
+I-0.0135 0.012 +t-0.0133 Thallium-208 0.238
+1-0.038 0.0141 +/-0.0372 0.0935 0.124 0.217 0.0497 0.0404 0.0276 0.0276 0.074 0.0831 0.0855 0.0437 0.0513 0.0293 0.0266 om7 0.0497 0.0252 0.0296 pCI/g pCi/8 pCi/g pCilg pC11g pCig pC11g pCl/g pCig pCiig pCi1g pCMg pCi/g pCitg pci/8 pC3g pCl/g pCi/g SRB 0600804 0949 335651 1 TAe following Prep Methods were performed Method Description Analyst Date lime p Batch Dry Soil Prep Dry Soil Prep CLRAD-A-021 MlMI 05/204 1441 334885 The foo!wing 6nutkal Methods were performed Method Description I
EML HASL 300. 45.23 Notes:
The Qualifiers In this report are defined as follows:
13 Target analyte was detected in the sample as well as Ie associated blank BD Flag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target analyte cxcceds the instrument calibradon range.
55
GNALEGNEIN LAOAOISTL GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Hladdamn Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PM 002332 Report Date: Junc 24.2004 Page 2 of 2 niect:
YANKO0504 shent ID:
YANKOO0 Vol. Recv.:
Client Sample 11):
Sample ID:
9535-0001-013F 113282014 Prmeter Qualifer Reslt Uncertainty LC TPU MDA Units DF AnalysDate Tlne Batch Mtd.
11 Analytical holding time exceeded.
J Indicates an estimated valtm The result was greater than the detection limit, but less than the reporting limit.
U Indicatcs the target analytc was analyzed for but not detected abovc the detection limit.
VI Uncertain identificadon for gamma spectroscopy.
X ab-specific qualifier-please see case narrative, data summnary package or contact your project manager for details.
h Sample preparation or preservation holding timn exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Reviewed by 56
I GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Soils PON 002332 Report Date: June24. 2004 Page I of 2 Client Sample ID:
Sample ID:
Matrut:
Collect Date:
Receive Date.
Collector Moisture:
953S-001l014F 113282015 Soil 27-APR.04 19-MAY-04 Client 8.6%
Proiect:
YANK00504 Clent ID:
YANK001 Vol. Recv.:
Pareter Qusaifer Result Uncertalnty LC TPU MDA Units DP AnalyslDate Time Batch Mtd.
ad GmmaSpecAnalysi Gammapec. Gamma. Sotld-FSS CA A ALL FSS Actinium-228 0,530
+1-0.187 0.062
+J-0.184 0.131 Americiun-241 U
-0.0135
+1-0.0297 0.0233 /-0.0292 0.0478 Blamuth-2t2 0.499
+/10.301 0.133
+1-0295 0280 Bismuth-214 0504
+14.0954 0.0327 +/-0.0935 0.0681 Ceslum-134 U
0.0358 W1-0.0301 0.0217 +1-0.0295 0.0453 Cesium-137 0.0726
+1-0.0313 0.0181 +1-0.0306 0.0379 Cobalt.60 U
0.0023
+4-0.0218 0.018 +1-0.0214 0.0386 Europium-152 U
Q0.0158
+/-0.0451 0.0398 +/.0.0442 0.0826 Europiuum-154 U
0.0082
+1-0.0694 0.0575
+/-0.068 0,122 Europium-155 U
0.080
+1-0.0436 0.0422 +J.0.0428 0.0864 Lead-212 0.528
+140.0682 0.0235 +/-0.0669 0.0485 L1d-214 0.569
+1-0.094 0.0292 +4.0921 0.0605 Manganese-54 U
0.024
.1.0.0234 0.0194 +1-0.0229 0.0406 Niobium-94 U
0.00698
+1-0.0193 0.0164 +1-0.0189 0.0342 Potassium40 12.0
+/-1.14 0.14S
./-1.12 0316 Radium-226 0504
+1-0.0954 0.032 +/-0.0935 0.0681 Silver-108m U
0.00275
+1-0.0165 00145 +1-0.0161 0.0303 Thaliium-208 0.196
+1-0.0426 0.013 +/4.0418 0.0382 pC1g pCi/g pCI/g pCYg pCVg pC/g pCUg pCifg pCi/g pCi/g pC1,g pCi/g pCUg pCLg pCUg pCVg pC/g palg SRB 06108104 0949 335651 1 Tbe following Prep Methods were performed Method Desciption Analst Date Time Prep Batch Dry Soil Prep Dry Soil Prep 0IL-RAD-A.021 MlMI 05/2(04 1441 334885 The following Analyntial Methods were performed Method Description I
EML UASL 300, 4.5.23 NoteS:
Thc Qualifiers In this report are defined as follows:
B Target analytc was detected in the sample as well as the associated blanL BD Flag for results below the MDC or a flag for low tsace recovesy.
E Concentration of the target analyte exceeds fte instttment calibration range.
57
GENERAL ENGINEERiNG LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chadeston SC 29407 - (843) 5568171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Datc: Junc 24.2004 Page 2 of 2 Clicnt Sample ID:
Sample MD:
9535-O001-014F 113282015 riec:
YANKOO504.
dLent W:
YANKOOI Vol. Recv.:
Paramder Qualifter Result Uncertainty LC TPU MDA Units DF AnalystDate 7lme Ratch Mtd.
H Analytical holding time exceeded.
I Indicates an estimated value. Mic result was greater than the detection limit, but less Oa thea reporting limit U
Indicate the target analyte was analyzed for but not detected above the detection limiL UI Uncertain Identification for gamma spectroscopy.
X Lab-specific qualifier-pleasee case narrtive, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceede.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Pleasc direct any questions to your Project Manager, Sarah Kozlik.
-Fcaci-4-c CcQtr o
Reviewed by 58
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5568171 -www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page I of 2 Client Sarnple ID:
Sample ID:
Matrix:
Collect Date:
Receive Datc.
Collector.
Moisture:
9535-0001-O15F 113282016 Soil 27-APR-04 19-MAY-04 Client 11.3%
Project:
YANKOOS04 Client I):
YANKOOI Vol. Recv.:
Parameter Qualier Result Uncertalnty LC TPU MDA Units DF Analysete 71me Batch Mtd.
Rad Gamma Spec Amalys Gammapec, GCmmuk So)id-FSS GAM & ALL FSS Actinlum-228 0.613
+/-0.159 0.0444
+1-0.156 0.0953 Atnericlum-241 U -
0.00576
+/-0.110 0.0894 1-0.108 0.185 Bismuth-212 0.398 41-0.200 0.0881
+4.196 0.189 Bismutb-214 0.438
./-0.0703 0.0231 4/.0.0689 0.0488 Cesium-134 U
0.0341
+/-0.0244 0.0169
+1.0.024 0.0356 Cesiunt-137 0.0391
+"-0.0342 0.0126 +1.0.0335
.0268 Cobalt.60 U
0.00223
.1-0.0159 0.0136 +1/0.0155 0.0298 Europlum-152 U
-0.0151
+/-0.0388 0.0323
+/10.038 0.0677 Europlum-154 U
0.015
+1-0.0444 0.039 +/-0.0435 0.085 Europlum-155 U
0.0062
+/-0.0423 0.0399 41-0.0414 0.0825 Ld-212 0.590
+/.0.068 0.0228 +1-0.0666 0.0472 Ltad-214 0500
./-0.0807 0.024 4-0.0791 0.0503 Manganesc-54 U
0.00948
- I-0.0154 0.0136 4J-.0151 0.029 Niobium-94 U
0.00423
+/-0.0132 0.0116 +1-0.0129 0.0246 PotassiumA40 10.4
./-1.10 0.124
.1-1.08 0.273 Radium-226 0.438
+/-0.0703 0.0231 +1-0.0689 0.0488 Silver-108m U
-0.00371
+1-0.0124 0.0109 +10.0121 0.023 Thallium-208 0.192
+.-0.0337 0.0122
+/40.033 0.0259 pCr pcilg pC0g pCi/g pci4g pCilg KCill pCI/g pCi/9 pCVg pCi/g pCI/g pCiJg pCVg pCi/g PCi,8 pci/g SRB 06/0M4 0950 335651 1 Tho following Pre Methods were peronned Method Descriptfon Avalyst Date TIme Prep Batch Dry Soil Prep DrySoilPrep0L-RAD-A-021 MiMI 052W04 1441 334885 The followig Anatical Methods wre performed Method Description I
EML HASL 300.4.5.23 Notes:
Tbe Qualificrs in tlls report are defiled as follows:
B Target analyte was detected in the sample as well as Ihe associated blank.
BD FlagforlrosWbelowthe flDCorafagforlo wtracer Ovety.
E Concentration of the target analyte exceeds the instrument calibration range.
59
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 558-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Nock Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete HoUctbeck ProjcaL Soils PO 002332 Report ate: June 24.2004 Page 2 of 2 Client Sample ID:
Sample ID:
9535-0001415F 113282016 xicc:
YANK00504 Rent ID:
YANK001 Vol. Recv.:
Prameter Qualter Result Uncertainty LC TPU MDA Units DF AnalystDate Tine Batch Mtd.
I H
Analytical holding time exceeded.
1 Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification for gamma spectroscopy.
X Lab-specific qualifler-plae sce case namrdve, data summay package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlk.
4cvi s(9f by Reviewed by 60
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) S588171 - www.gel.com Certificate of Analysis Company: Conneaticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Pwject:
Soils PO# 002332 Client Sample ED:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collectori Moisture:
ReportDate: June24,2004 Page I of 2 9535-00-017 ProAect:
YANK00504 113282017 Cient ID:
YANK001 Sail Vol. Recm.:
27-APR-04 19-MAY-04 Client 10.9%
ar1ameter Qualiner Reult Uncertainty LC TPU MDA Units DF Analystate lime Batch)Mtd.
Rad Gamma Spec Analysis Gammaspec, Gamma, Sofid-FSS GAU & AU FSS Actinium-228 0.610
+/-.186 0.0625
+/-0.182 Americium-241 U
-0.00549 41-0.0245 0.0225 41-0.024 Blsmuth-212 0.583
+/-0.238 0.130 41-0.233 Bismuth-214 0.669
+1-0.112 0.0286
+40.109 Cesium-134 U
0.00
+1-0.0343 O.0227 +1-0.0336 Ul Cesium-137 0.0651
+1-0.0382 0.0175 +1-0.0374 Coblt-60 U
0.00508
+1-0.0236 0.0206 +/-0.0231 Europium-152 U
-0.0148 41-0.0433 0.0373./-.0425 Europium-154 U
0.0138
+1-0.064 0.0561 +10.0627 EuropiuM-155 U
0.0337
+1-0.0411 0.0375 +1-0.0402 Lead-212 0.710 41.0792 0.0232 +4/-0.0776 LI -214 0.569 4/.0929 0.0265 W-0.091 Manganese-54 U
-0.00372
+/-0.0208 0.0115 +-0.0204 Niobium-94 U
0.00281 41-0.0172 0.0152 +1-0.0169 Potassiwn.40 15.6
+1-1.33 0.134
+/-130 Radium-226 0.669
+1 0.112 0.0286
+/-0.109 Siiver-108m U
-0.0107
+/-0.0149 0.0121 +1-0.0146 Ihallium-208 0.230
+1-0.0432 0.0173 +/-0.0423 0.134 0.0463 0.276 0.0606 0.048 0.0371 0.0444 0.0783 0.121 0.0774 0.0481 0.0556 0.0374 0.0322 0301 0.0606 0.0256 0.0365 pCi/g pCi/g PCI/8 pCi/g pC/g pCi`g pCilg pCi/9 pCilk Kcits pCVg pCVg pC1g pCl/g pCVg pCWg pc01 SRB3 06&104 0951 33S651 1 bTe floUwgPw Methods were performed Method Desciptlon Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep IL-RAD-A-021 MimI 05/2W04 1441 334885 The following Anayical Methods were performed Method Description I
EML HASL 300,45.2.3 Notes:
The Qualifiers In this report ae defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target snalyte exceeds the Lnstrument calibrition range.
61
I, G
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddamn Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck ProJect:
Soils PO# 002332 Report Date: June 4,.2004 Page 2 of 2 Client Sample ID:
Sample ID:
9535S0001-017F 113282017
!roicct:
YANIC00504 C
t D:
YANK00I Vol. Recv.:
Parameter Qualitier Result Uncertainty LC TPU MDA Units DF AnabystDate Tine BatrbMtd.
11 Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identificadon forgamma spectmscopy.
X Lab-specific qualificr-please see case narrative, data sunmnary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
lhe above sample is reported on a dry weight basis.
Whis data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Riew'C cby Reviewed by 62
IN-EERING L GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 656-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck PioJect Soils PO# 002332 Report Date: June 24.2004 Page I of 2 Client Sample ID:
Sample ID:
Matix:
Collect Date:
Receive Date:
Collector.
Moisture:
95354001l-019F 113282018 SoB 27-APR-04 19-MAY-04 Client 10.6%
Priec :
YANK00504 Client ID:
YANK001 Vol. Recv.:
Pnameter Qualifier Result uwcrtainly LC TPU MDA Units IDF Analystatt Thne Batch Mtd.
Rad Gamma Spft Andydss Gammaspec, Gamm4 Solid-FSS GAM & ALL FSS Actinium-228 0.499
/-0.111 0.0304
/4.109 Ameicium-241 U
40.0372
+14.0413 0.035 +40.0405 Bl3mutb-212 0318
+1-0.130 0.0666
+/4.128 Bismuth-214 0.451
+t0.0699 0.0172 +/-0.068S Cesium-134 U
0.00
+/1.0226 0.0123./-0.0222 Ul Ceslum-137 0.0413
+/-0.0153 0.00978
+1-0.015 Cobalt-60 U
0.0152
+/-0.0173 0.010 +/-0.0169 Europium152 U
-0.0218
+.-0.0279 0.024 +/-0.0273 Europium-154 U
-0.0162
.- 0.0364 0.0298 +1-0.0357 EaopluM-155 U
0.0495
+1-0.0335 0.0326 +/-0.0328 Lead-212 0529
+1-0.0527 0.015 +1-0.0517 Lead-214 0.548
.1-0.0617 0.0175 tl4.0605 Manganese-54 U
0.0115
+/-0.00942 0.00894%+-0.00923 Nloblun-94 U
0.00
+1,015 0.00818 +/4-0.0147 Potaslum-40 11.8
+1.0.946 0.0711
+1-0.927 Radium-226 0.451
+/-0.0699 0.0172 +1-0.0685 Silver-S08m U
0.00138
+1-0.0096 0.0043 +t.0.00941 nallitum-208 0.165
+1.029 0.00868 +t-.0284 0.0642 0.0719 0.140 0.0358 0.0257 0.0204 0.0214 0.0499 0.0631 0.0667 0.0309 0.0362 0.0189 0.0171 0.155 0.0358 0.0175 0.0182 pCl~g Pag pCi/g pCl/g pCUg pCi/g pcvgk pC~g pCils pCig pCIZ pCi/g pa/C pClg pfig pCilk pCag pCi/g SRB 06WM04 0951 33565 1 The following PKP Methods were performed Method Description Anal"st Date Time Prep Batch DrySoilPrep DrySoilPrep 0L.RAD-A-021 MJMI 05/W104 1441 334885 The followtng Analytical Medhods were perfobmed Method DesCeption 1
IEML HASL 300,4.523 Notes:
The Qualifiers In this report are defined as followss:
B Target analyte was detected in the sample as well as the assocated blank.
ED Flag for results below the MDC or a flag for low tracer recovety.
63
I]
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 55688171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
lladdam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contacc Mr. Pete Hollenbeck Prtoject:
Soils PO 002332 Report Date: June 24,2004 Page 2 of 2 Client Sample ID:
Sample ID:
9535-001-019F 113282018 PrOeC~tZ YANKOOSO4 CiCnt ID:
YANK000 Vol. Racv.:
Parumeter Qualifier Result Uncertainty LC TM MDA units DF AnalysDate llmc Batch Mtd.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time excceded.
J Indicates an etimated value. The result was greater than the detection limit, but less than the reporting limit U
Indicates the target analyte was analyzed for but not detected above the detection limit.
Ur Uncertain identification forgamma spectroscopy.
X Lab-specific qualifier pleas zsee case naative, data sunmma package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
TeU above sample is reported on a dry weight basis.
This data repoat has been prepared and reviewed in accordance with General Engineering Laboratories. LLC standard operatng procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
44QQ&(A
"-( C' @ct "
Reviewed by 64
GENRA E L
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5568171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Soils P00PD2332 Report Date: June Z4,2004 Page I of 3 Client Sample ID:
Sample 1ID:
Matx:
Collect Date:
Receive Date:
Collector.
Moisture:
9535-000 -002F 113282019 Soil 22-APR-04 19-MAY-04 Client 3.37%
?rPiC~t:
YANIC00504 eItentWID:
YANKOO1 Vol. RecY.:
Parameter Qualifder Result Uncertainty LC TPU MDA Units DF Anastyate MIme Batch MIdL Rad Alpha Spec Analysis AlphaspecAm241, Cm, Solid ALU FSS Amcdcium-241 U
0.00 4/4.0487 0.00 +4-0.04S7 Curium-242 U
0.00
+14.0601 0O.
+1-0.0601 Curlium-243/744 U
0.019
+1-0.0503 0.02S4 +/-.0504 A iphaspec Pu Solid-ALL FSS Plutonium-238 U
-0.0175
+t-0.0515 0.0479 +1-0.0515 Plutonium-239/240 U
0.00581
+/-0.0488 0.0276.1-0.0489 Liquid ScW Pu241, Solid-ALL FSS Plutonium-241 U
3.38
+t-6.01 4.94
+1-6.02 Rad Gam Spec Analysis nammaspec. Camma. Solid FSSC3AM & ALL FSS Actinium-228 0504
/4.175 0.0601
+1-0.171 Americium-241 U
-0.0123
./-0.0516 0.0425 +1-0.0506 Blsmuth-212 0.726
+-0.401 0.152
+/4.393 Bismuth-214 0.566 4-0.108 0.0349
+/-0.106 Cesium-134 U
0.015
+1-0.0491 0.025 +./4.0482 Cesium-137 0.0989
+t-0.0529 0.0199 +.OS118 Cobalt-60 U
-0.00653
+t-0.0238 0.019 +/4.0233 Europium-1S2 U
0.0139
+/-0.0569 0.0513 +1-0.0553 Furopium-154 U
0.00412
+/0.0707 0.0593 +1.0.0693 Europium-155 U
0.0067S
+/-0.0582 0.0526
./.0.057 Lead-212 0.466
+1-0.0724 0.0278
+1.0.071 Lead-214 0.553
+W-0.113 0.0358
+1-0.111 Manganese-S4 U
0.0247 t4.0241 0.0225 +1-0.0236 Niobium-94 U
-0.00451
+t-0.0223 0.0183 +4.0218 Potasslwn-40 10.5
+/-1.19 0.153
+t-1.16 Radium-226 0.566
+1-0.108 0.0349
+ 0.106 Silver-108m U
-0.0147 t-0.0195 0.0161 +t-0.0191 Tlhallium-208 0.218
+10.0557 0.0179 +P0.0546 Rad Gs Flow Proportloza Coumtng GFPC, Sr90, solid-ALL FSS Strontiin-90 U
0.00426
+/-0.0179 0.0183./-0.0179 Rad Liquid Sdntlatlbon Analsis LSCZ Trftm D14 Solid-HMD2ALL FSS Tritium U
-3.19
+1-4.96 4.39
+/.4.97 0.0673 0.0831 0.125 0.161 0.121 pV04 pCi/g pCVg pC01 pCLg 10.2 pCi/g 0.131 0.0872 0.325 0.0741 0.053 0.0422 0.042 0.107 0.129 0.108 0.0575 0.074S 0.048 0.0388 0.345 0.0741 0.034 0.0382 0.0387 8.78 pCi/g pC0/g pCVg pCiJg pCUg pCilg PCi/g pctlk pC11g pCitg pC1g pCl/g pCitg pci/g pCi~g Pa/g pCi/g JASI 06/WIC04 0943 3385611 JASI 06/10/04 0944 338562 2 JASI 06/11/04 0213 338563 3 SRB 06)W04 0952 335651 4 HOBI O60304 1844 335956 5 JLB&I06/11I04 2101 3396286 Vquid Scint Cl4, Solid FSS 65
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) &55-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddami Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Suils PO# 002332 Report Date: June 24,2004 Page 2 of 3 Client Sample ID, Sample ID:
9535-0001-002F 113282019 MrpieU..
YANKOOS04 Clleni ID; YANKOOI Vol. Recv.:
Parameter Qualifer Result Uncertainty LC TPU MDA Units DF Analystbsle TIme Batth Mltd.
Rad Liquid Schitillation Analysis Liqidd Scnt CI4, Solid FSS Carbon-14 U
LiquidScint Fe5 Solid-AU FSS Iron-55 U
Livid Scint NW63, Solid-AUL FSS Nickel-63 U
Liquid Scing Tc99. Solid-ALL FSS Technetium-99 U
0.0289
+"-0.119 0.0984
+t-0.I 19 0.204 pCI/g 35.3 pCi/g 11.7 paitg
-31A
+1/41A 16.9 4141.4 4.54
+1-6.93 5.74 4-6.93 MWX 06/2U04 0158 342387 7 JLB I 06W2204 1919 3423419 JLBI 06/12/04 0400 339689 12 DAl]
06t18/04 2137 339685 13 0270
+/-0.242 0.199
+/-0.242 0.404 pCi/8 The foflowing Prep Methods tre performed Method Description Analyst Date Thie Prep Batch Ash Soil Prep Ash Soil Prep. GL-RAl)-A.1ziB API 05/21/04 1445 334895 Dry SoU Prep Dry Soil Prcp CLRAD-A-021 MiMI 0S120104 1441 334885 The foUowing Analytical Methods were performed Method Desciption l
DOE EML HASL-300, Am-0S-RC Modified 2
DOE EML HASL-300, Pu-l I-RC Modified 3
DOE EML HASI,300, Pu-I I-RC Modified 4
EML HASL 300.4.523 5
EPA 905.0 Modified 6
EPA 906.0 Modified 7
EPA EERP C-01 Modified 8
EPA EERF C-OI Modified 9
DOE RESL Fe-I. Modified 10 DOE RESL Fe-I, Modified 1
DOE RESL Fe-, Modifled 12 DOE RESL Ni-I, Modified 13 DOE EML HASL-300, Tc-MRC Modified Surroptdrracerrecovtry Test Recovery%
Acceptable Limits Ametcium-243 Alphaspec Am241, Cm Solid ALL 84 (25%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 89 66
GEEA NIERN AOAOIS I
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5568171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424 Contact Mr. Pete Hollenbeck ReportDate: June 24,2004 Page 3 of 3 Project Soils PO# 002332 Client Sample ID:
Sample ID:
9535-000l.002F 113282019 Priet:
YANKOOS04 ol.entD:
YANRK01 Vol. Recv.:
Parameter Qualer Resuht Uncerlainty LC TPV MDA Units DF AnalWy ate lime Batch Mtd.
Carriefrracer Recovery Canierfrracer Recovery Canler/Tracer Recovery Cariettracer Recovery Carrierniacer Recovery Liquid Scint Pu241, Solid-ALL FS GPPC, Sr9O, solid-ALL FSS Liquid Scint Fe55. Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 100 96 87 74 51 (25%4125%)
Notes:
The Qualifier in this report are defined as fo11ows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results below the MDC or a flag forlow tacer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not dtected above the detection limit.
Vl UnccrtaIn idendfication for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Samplc preparation or preservation holding time exceeded.
TMe above sample is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Reviewed by 67
L GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charbeston SC 29407 - (843) 5S6-8171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils P4M002332 Report Date: Junc 24,2004 Page I of 3 Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date Collector Moisture:
9535-0001-006F 113282020 Soil 22-APR-04 l9-MAY.04 Client 4.66%
Mect:
YANK00504 Vol. Rwcv.:
Parameter Qualifier Result Uncerbainty LC TPU MDA Units DF AnalystDste Time Batd2 MId.
Rad Alpha Spec Aahsh AlphapecAm241, Gn, Solid AL FSS Ameciclum-241 U
0.0488
.t-0.128 0.110
+1-0.128 Curium-242 U
0.0318
+/-0.139 0.129
+/-0.139 Curium-2431244 U
0.156
+/-0.232 0.201
+/-0.233 AlphaspecPut Solid ALL FSS Plutonium-238 U
0.0142
+1.0.076 0.0707 +/-0.0761 Plutonium-2391240 U
0.00
+/-0.0496 0.00 +/4.0496 Lquid ScintPu24O, Solid-ALL FSS Plutoniunm-241 U
-0.559
+/-6.63 5.59
+.-6.63 Rad Gamma Spec Avalysis Gammapec, Camma. Solld-FSS CAM & ALL FSS Actinium-228 0.474
+/-0.138 0.0439 +.-0.135 Amerlcium-241 U
0.00339
+/-0.0863 0.0575 +/1-.046 Bismuth-212 0.407
+1-0.186 0.103
+t-0.182 Bismuth-214 0.564
+/4.0793 0.0222 +/.-0(77 Cesium-134 U
O.Q213
+/-0.0264 0.0172 +/.0.0258 Cesium-137 0.127
+J-0.0272 0.0127 +/-0.0266 Cobalt-60 U
-0.00247 1-0.017 0.0141 4t-0.0167 Europlum-152 U
0.0164
+14.0424 0.0378 -/.0.0415 Europium-i54 U
.0.0227
/0.0514 0.0417 +1-0.0504 Europium-155 U
0.0392
+/-0.0449 0.0415
+/-0.044 Lead-212 0.552
+/-0.0636 0.0208 +/4.0624 Lud-214 0.616
./-0.0925 0.02S2 W/0.0907 Manganese-54 U
40.0057
+1.0.0182 0.0151 +/40.0178 Niobium-94 U -0.000592
+/-0.0136 0.0117 +40.0133 Potassim-40 11.2
+/-1.08 0.127 4-1.06 Radium-226 0.564
+/10.0793 0.0222 +/-0.077 Silver-108m U
0.0033
+/-0.0154 0.0118 +1-0.0151 Thallium-208 0.170
+/-0.0364 0.0133 +1-0.0357 Rad Gas Flow Proportional Counting GFPC Sr9O, jolid-ALL FSS Strontium-90 0.0722
+1-0.0182 0.0114
+/-0.024 Rad Liquld Sintillatlon Analysis LSC, Trtiwu DiuM Solid-f TfD2,ALL FSS Ttidum U
-32
+/4.29 3.83
+14.30 Liqud Scint C14, Solid FSS 0.303 0.361 0.4S4 0.210 0.0686 11.5 0.0942 0.118 0.220 0.0471 0.0363 0.0271 0.0308 0.0786
.0902 0.0852 0.0431 0.0526 0.032 0.0248 0280 0.0471 0.0247 0.0282 0.0249 7.67 pCi/g pCVg PCIVS pCi/g pCVg pCI/g PCi':
pCi/g pCi/g pci/g pcilz pCi~g pCi/g pCug pCi/g pCifg pCi/g pCi/g Pais pCI'g pCi/g PCi1e JASI 06/1104 1323 338561 1 JASI 06/It004 0944 338562 2 JASI 06/111/04 0245 338563 3 SRB 06/08104 0953 3356514 HOBI 06/0304 1844 3359565 1LBI 06/111/04 2133 339628 6 68
I I
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I GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvw.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddain Ncck Plant 362 Injun Hollow Road East Vampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Datc: June 24,2004 Page 2 of 3 Client Saniple ID:
Sample ID:
9535-0001-006F 113282020 Prtjec:
YANKOOS04 Client ID:
YANK00O Vol. Recv.:
Parameter Qualifier Result Uncertlainty LC TFU MDA Units DF Analytte Tnie Batcb Mtd.
Rad LUqtM Sdntlatilon Analysis Liquid Scit C14, Solid FSS Carbon-14 U
Liquid Scnt FWSS, Solid-AUL FSS Iron-SS U
liquid Scnt N163. Solid-AL FSS Nickel-63 Liquid Scbit Tc99, Solid-ALL FSS Tecicium-99 U
-0.0219
./-0.115 0.0976
+1-0.115
-49.7
+1-41.9 16.7
+-W41.9 15.8
.1-9.30 7.54
+/-9.30 0.203 34.8 pCi1g pci/t MWX 0W20104 0901 342387 7 JLBI 06J23/04 1430 342541 9 JLBI 06/12/04 0531 339689 12 DAJ1 06/1804 2312 339685 13 15.3 pCi/g 1351 PUCig 0.319
+1-0.212 0.173
+1-0.212 t
lbe follo!ing Prep Methods were performed Method Description Analyst Date Time PrepBatch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B API 05/21/04 1445 334895 DryySoilPrep DrySoUlPrepGL-RAD-A-021 MiMi 05flW04 1441 334S85 MIm following Analythcd Methods were performed Mehod Descriptlon I
)DOB EML HASL-300, Am.05-RC Modified 2
DOE EM! HASL300, Pu-I I-RC Modified 3
DOE EML IIASL-300. Pu-I -RC Modified 4
EML HASL300, 45.23 5
PA 9QS.0 Modlfied 6
EPA 906.0 Modified 7
EPAEERFC-01 Modified 8
EPA EERP C-01 Modified 9
DOE RESLFe-.l Modlfied 10 DOE RESL Fc-l, Modifled II DOE RESL Fc-I, Modified 12 DOE RESL Ni-W, Modified 13 DOE EMC HASL-300. Tc-02-RC Modified Surrogptel1rcer recovery Test Recovery%
Acceptable Limits Americium-243 Aiphaspec Am241, Crn, Solid ALL 77 (25%-125%)
Plutonium-242 Alpbaspec Pu. Solid-ALL FSS 85 69
GNRLEiNEIGLARTOESLL r
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5568171 - www.el.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Prject:
Solis PO# 002332 Report Date: June 24,2004 Page 3 of 3 Client Samplc ID:
Sample ID:
95350001
-006F 113282020 P9aject:
YANK00504 Cient &D: YANKO0I Vol. Recv.:
Parameter Qualifer Result Uncerainty LC TPU MDA Units DF AnalystDate l11me Batch Mtd.
CAnirtf1racCr Recovery Carrierfracer Recovery Carrietrlracer Recovery Carrier!Trcer Recovery Carriertfracer Recovery Liquid Scint Pu241, Solid-ALL PS GFPC, Sr9O, solid-AIl FSS Liquid Stint FeSS, Solid-ALL FS Liquid Scint Ni63. Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 88 103 89 69 60 (25%-125%)
Notes:
The Qualifiers In this report ar defrned as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for trsults below the MDC or a flag for low tracer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
It Analytical holding time exceeded.
1 Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not deected above the detection limit Ul Uncertain Identification forganuna spctroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Simple preparation or preservation holding time exceeded.
The' above sample is reportd on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager. Sarah Kozlik Reve(Qwd byQ Reviewed by 70
I I
I I
R I
GENERAL ENGINEERING LABORATORIES, LLC 2040 SaVage Road Charleston SC 29407 - (843) 555-8171 - www.gel.com Certificate of Analys Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton. Connectlict 06424 Contact Mr. Pete Hollenbeck Project:
Soils PON 002332 ReportDate: Junc24,2004 Page I of 3 Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
9535-0001-016F Poiect:
YANK00504 113282021 Vl
.entI: YANKOOI Soil Vol. Rccv.:
27-APR-04 19-MAY-04 Client 11.5%
Parameter Qual(iler Result UncertaInty LC TPU MDA Units DF AnalystUate Time Batch Mtd.
Rnd Alpbs Spec A15is AlphaspecAM241, Cn, SolidAUFSS Amcricium-241 U
0.0335
+1-0.0755 0.0516 +.0.0756 0.174 Curnum-242 U
0.0316
/40.0619 0.00 4/40.062 0.0855 Curium-243/244 U
-0.0126
+40.0175 0.0423 1-0.0175 0.156 Alphaspec Pu. Solid-ALL FSS Plutonium-238 U
0.0345
+1-0.142 0.135 +/-0.142 0.351 Plutonlum-239/240 U
-0.0332 4t0.0965 0.122 +1.0.0965 0.324 Liui{dScintPO24, Solid-ALL FSS Plutonium-241 U
2.61
+1-6.70 5.54
+1-6.70 IIA Rad Gamma Spec Analysis Gammpec. Gamma, Solid-FSS CAM & ALL FSS Actinlin-228 0535
+10.119 0.0344
+/-0.117 0.0725 Americlum-241 U
-0.0168
+/-0.0755 0.061
+/4.074 0.125 Bismutb-212 0.306
+.10.167 0.07S7
+J-0.163 0.165 Bismuth-214 0.442
+J0.062 0.0195 +1-0.0608 0.0406 Cesium.134 U
0.0198
+1-0.0246 0.0138 +14.0241 0.0286 Ceslumn-137 0.0544
+/-0.0266 0.0109 +1-0.0261 0.0227 Cobalt-60 U
0.007 t/-.0118 0.0104 +-0.0116 0.0222 Europium-152 U
-0.00602
+1-0.0319 0.0274 +-0.0312 0.0569 Europium-154 U
-0.0185
+1J0.0348 0.0282 +1-0.0341 0.0604 Europium-ISS U
0.0536
+1-0.0418 0.0384 41.00409 0.0787 Lead-212 0.538
+J-0.0562 0.0172
.f-O.055 0.0353 Lead-214 0.569
+/-0.0702 0.018 +4-0.0683 0.0375 Manganese-S4 U
0.00357
+/-0.0131 0.0112 +/-0.0128 0.023S Nioblum-94 U
-0.00122
+1-0.0111 0.00948 +/-0.0109 0.0198 Potassium-40 11.3
+1-0.987 0.0814
+4/0.967 0.177 Radium-226 0.442
+/-0.062 0.0195 +1.0.0608 0.0406 Silvea-l08m U -0.000399
/-.0112 O.00954
+/-0.011 0.0198 lhallium-208 0.155
+1-0.0282 0.0102 +1-0.0276 0.0213 Rad Gas Flow Proportional Couning GFPC Sr9f solid-AL FSS Strontitim-90 U
0.0257
+/-0.0159 0.0138 +l-0.0169 0.0297 Rad Uquld Scintillation Analysis pCUg pCUg pCi/g pClg pCUg pCvg PCi/g pCg pCi/g pCitg pCi/g pC11g pcUg pCKg pCirg pCUg pCi/g pClg pCirg pCi/g pG/i pCUg pCiug pCUg pCIJg pC1`g IASI 06/10(04 0943 338561 1 IASI 06/1QW 0943 338562 2 JASI 06/11/04 0316 338563 3 SRB 06'0V4 1203 335643 4 HOBI 061104 1843 335956 5 JLBI1 06/11104 2206 339628 6 LSC, Tridum DMi. Solid-HT
- 2. FSS Tridum U
LiquidScint C14, Solid FSS
.2.28
.1-3.80 3.35
+1-3.80 6.70 71
GENERAL ENGINERINC3 LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 656-8171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Ifollenbeck Project:
Solls PO# 002332 Report Date: June 24,2004 Page 2 of 3 Client Sample 1D:
Sample ID:
9535-001-016F 113282021 Proicct..
YANKOOS04 Client W:
YANK00I Vol. Recv.:
Pa1ameter Qualifier Realt Uncertainty Rad Lqud Sdntllatlon Analysis LC TPU MDA Units DF AnalystDate Ttme Batch Mtd.
Liquid Scuwt C14, Solid FSS Carbon-14 U
-0.0695
+-0.103 0.0895
+1-0.103 Liquid Sc' t FeS, Solid-ALL FSS Iron-55 U
-63
+142.4 17.5
+142.5 Liquid Scin Ni63, Solid-AUl FSS Nickel-63 U
14.1
+1-14.0 11.6
+1-14.0 Lquid Scint TMc% Solid-ALL FSS Technetium-99 U
0383
+1.0.254 0.208
+1-0.254 0.186 pC1ig 36.5 23.5 0.422 pCi/g PCiVg pC11g MWX 060204 1003 342387 7 JLBI 06r23/04 1502 342541 9 JLBI 06,12104 0703 339689 12 DAI1 06/19/04 0046 339685 13 Tbe following Prep Meftod were performed Method Description Analyst Date Thme Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B API o0521/04 1445 334895 Dry Soil Prep Dry Soil FPep 1L-RAD-A-021 MiMI os m04 1441 334885 The following AnalytA Methods were performed Method Description I
DOE EML HASL,300, Am-05-RC Modified 2
DOE EML HASL-300. Pu 11 RC Modified 3
DOE EML HASL-300. Pu-I I-RC Modified 4
EML IJASL 300,4.5.2.3 S
EPA 905.0 Modified 6
EPA 906.0 Modified 7
EPAE" C-C Modified 8
EPA EERF C-01 Modified 9
DOERESLFe-1.Modified 10 DOE RBSL Pc-1 Modified 11 DOERESLFe-l.Modified 12 DOE RESL Ni-I. Modified 13 DOE EML ASL-300, Tc-02-RC Modified Surroptewrrcer recovery Test Rceovery%
Acceptable Linits Areridurn.243 Alphtssec Am241. Cm. Solid ALL 79 (25%-125%)
Plutonium-242 Alphaspoc Pu, Solid-ALL FSS 80 72
EIN Ir GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5568171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Addrss:
Haddam Neck Plant 362 Injun Hollow Road East amnpton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page 3 of 3 Client Sample ID:
Sample ID:
9535-0001-016F 113282021 jilec:
YANK00504
. teW:
YANK00I Vol. Recv.:
Parameter Qualifier Resut Uncertainty LC TWr MDA Units DF Analyatbte Time Batch Mtd.
Carier/tracer Recovery Carder/Tracer Recovery CarrerrTracer Recovery Carrictraccr Recery Caurier/Tracer Recovery Uiquld Scint Pu241. Solid-ALL FS GFPC, Sr9O, solid-AlU FSS Liquid Scint FcS5, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 90 100 82 49 49 (25%-125%)
Notes:
lhe Qualifiers in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Plag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection llmit.
Ul Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozilk.
_ ffi. & e cju t2 Reviewed by 73
II I
QUALITY CONTROL DATA 74
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Client:
.Contact:
Connecticut Yankee Atomic Power lladdam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut Air. Pete llollenbeck ReDort Date: June 24,2004 Page 1 of 12 Workorder:
113282 Parmname
~-- Rad Alpha Spec Batch NONI Sample Oual OC Units RPD%
REC%
Range AnIst Date Time 338561 i
QC1200637714 Amcricium-241 113282019 DUP Curium-242 Curium-243/244 U
0.00 Unccrt:
+/-0.0487 TPU:
+/-0.0487 U
0.00 Uncert:
+l-0.0601 TPU:
+/-0.0601 U
0.019 Unccrl:
+1-0.0503 TPU:
+/-0.0504 QC1200637716 Americium-241 LCS Curium-242
- Curium-243fl44 10.7 Unccrt:
TPU:
Unccrt:
TPU:
13.8 Unccrt:
TPU:
U 0.0786
+/-0.096 4/-0.0965 U
0.0154
+/-0.0612
+/-0.0612 U
0.00674
+1-0.0511
+1-0.0511 10.9
+/-0.957
+/-1.60 U
0.0169
+/-0.0447
+/-0.0448 12.9
+/-1.04
+/-1.85 U
0.014
+/-0.0555
+/-0.0556 U
-0.00653
+/-0.0128
+/-0.0128 U
0.00
+/-0.0526
+/-0.0526 pCi/g 200 pCi/g 200 pCi/g 95 pCi/g (0% -100%) JAS I (0%- 100%)
(0%- 100h/0) 102 (75%-125%)
06/10/04 09:44 pCi/g pCi/g 94 (75%-125%)
h... Amcricium-241 Curiumi-242
. Curium-243/244 QC1200637715 Amcricium-241 MB 113282019 MS pCilg 06/10/04 09:43 Uncert:
TPU:
Uncert:
TPU:
Unccrt:
TPU:
pCilg pCi/g 20.9 Unccrt:
TPU Curium-242 Curium-243/244 Unccrt:
TPU:
27.0 Uncert:
TPU:
U 0.00
+/-0.0487
+/-0.0487 U
0.00
+/-0.0601
+/-0.0601 U
0.019
+/-0.0503
+/-0.0504 U
23.4
+/-2.14
+/-3.75 0.048
+/-0.127
+/-0.127 29.3
+/-2.41
+/-4.55 pCi/g 112 (75%-125%)
06/10104 09:44 pCi/g pCi/g Batch 338562 108 (75%-125%)
(0% - 100%) JASI 06/10/04 12:50 QC1200637718 113282019 DUP Plutonium-238 U
-0.0175 U
0.000883 pCi/g NIA 75
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:
113282 Page 2 of 12 Parmname NONI Sample Qual QC Units RPD%
REC%
Range Anist Date Time Rad Alpha Spec Batch 338562 Plutonium-2391240 QC1200637720 LCS Plutonium-238 Plutonium-239/240 QC1200637717 MB Plutonium-238 Plutonium-2391240 QC1200637719 113282019 MS Plutonium-238 Plutonium-239/240 Uncert:
+1-0.0515 TPU:
+/-0.05 15 U
-0.0058 1 Uneert:
+/-0.0488 TPU:
+/-0.0489 Unccrt:
TPU:
9.56 Uneert:
TPU:
Uncert:
TPU:
Uncert:
TPU:
+/-0.048
+/-0.048 U
0.0168
+/-0.0444
+/-0.0445 U
-0.00584
+/-0.049
+/-0.0491 10.7
+/-0.999
+/-1.60 U
0.0122
+/-0.0486
+/-0.0486 U
0.047
+/-0.0651
+/-0.0653 pCi/g N/A (0%- 100%M/)
pCi/g pCi/g 112 pCi/g PCi/g U
-0.0175 Uncert:
+/-0.0515 TPU:
+/-0.0515 18.6 U
-0.00581 Uncert:
+/-0.0488 TPU:
+/-0.0489 U
0.146
+/-0.193
+/-0.194 21.4
+/-1.98
+/-3.33 pCi/g 115 Batch 338563 QC1200637722 Plutonium-241 QC1200637724 Plutonium-241 QC1200637721
- Plutonium-241 113282019 DUP U
3.38 Uncert:
+/-6.01 TPU:
+1-6.02 U
0.604
+/-6.33
+1-6.33 pCi/g 0
(0% - 1 00%) JASI 06/11/04 05:22 L.CS 142 Uneert:
TPU:
128
+/-14.4
+1-19.7 pCi/g 90 (75%-125%)
MB Uncert:
TPU:
U 3.04
+/-7.35
+1-7.35 pCilg 06t11/04 06:24 06/11/04 04:50 06/11/04 05:53 QC1200637723 113282019 MS Plutonium-241 237 U
Uncert:
TPU:
3.38
+1-6.01
+1-6.02 211
+/-17.7
+/-25.8 pCi/g 88 (75%-125%)
Rad Gamma Spec Batch 335643 L
QC1200630676 113280002 DUP Actinium-228 0.490 Uneert:
+/-0.0971 0.534
+/-0.152
+/-0.149 pCi/g 9
(0% - 100%)
SRB 06/07/04 14:16
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:
113282 Page 3of 12 AC!
IJnhI
IIPIJ'Y, KI(:'v.
Kafl!e AnISI
iare iim
A
.b___^
wNnp1 C-1.
nl.^
t.
- Ulf, 11nift up I II/.
HIKU%
M211PC Anist Date lime rarinnami:
I Rad Gamma Spec
_ Batch 335643 Amcricium-241 Bimth21
~Bismuth-212
.Ccsium-134
. Ccsiumi-137 Cobalt-60 Europium-152
-1Europium-154 TPU:
+/-0.0952 U
0.0171 U
-0.00508 Uncert:
+/-0.0464
+1-0.0245 TPU:
+1-0.0455
+/-0.024 0.270 0.355 Uncert:
+/-0.142
+/-0.321 TPU:
+/-0.139
+/-0.314 0.462 0.449 Unccrt:
+/-0.0641
+/-0.0894 TPU:
+1-0.0629
+/-0.0876 Wul 0.00 UUI 0.00 Unccrt:
+/-0.018
+/-0.0342 TPU:
+/-0.0176
+/-0.0335 1.59 1.64 Unccrt:
+/-0.112
+/-0.162 TPU:
+/-0.1 10
+/-0.158 U
0.011 U
0.0176 Uncert:
+/-0.0121
+/-0.0226 TPU:
+1-0.0119
+/-0.0221 U
-0.0109 U
-0.00321 Uneert:
+/-0.0336
+/-0.0472 TPU:
+/-0.0329
+/-0.0463 U
-0.0253 U
-0.0119 Unccrt:
+/-0.0318
+/-0.0621 TPU:
+/-0.0312
+/-0.0609 U
-0.00384 U
-0.016 Uncert:
+/-0.0294
+/-0.0405 TPU:
+/-0.0288
+/-0.0397 0.488 0.490 Uncert:
+/-0.0554
+/-0.0636 TPU:
+/-0.0543
+/-0.0624 0.525 0.449 Uncert:
+/-0.0717
+/-0.0788 TPU:
+/-0.0703
+/-0.0772 U
0.00134 U
0.00951 Unccrt:
+/-0.0108
+/-0.0202 TPU:
+/-0.0106
+/-0.0198 U
0.00543 U
0.0163 Unccrt:
+/-0.00968
+/-0.0355 TPU:
+/-0.00949
+/-0.0348 8.27 8.05 Uncert:
+/-0.744
+/-0.870 TPU:
+/-0.729
+/-0.852 0.462 0.449 Uncert:
+/-0.0641
+/-0.0894 TPU:
+/-0.0629
+/-0.0876 U
-0.0113 U
-0.0028 Uncert:
+/-0.0115
+/-0.0183 pCi/g N/A pCi/g 27 pCi/g 3
pCi/g 62 pCi/g 3
pCi/g 46 pCi/g N/A pCi/g N/A pCilg N/A pCi/g 0
(0%- 100%)
(0%- 100%)
(0%- 100%)
(0%- 100%)
(0% - 100%)
(0%-/o 100%)
(0% - 100%)
(0% - I 00%)
(0%- 100%)
(0% - 100%)
I Europium-155 Lcad-212 L-Lead-214 Mangancse-54 pCi/g 16
- Niobium-94 Potassium-40 R~adium-226 pCi/g 150 pCi/g 100 pCi/g 3
pCi/g 3
pCi/g N/A (0%/O-100%)
(0%- 100%)
(0% - 20%)
(0%- 100%)
(0%- 100%)
Silver-I 08m 77
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com QC Summary
. Workorder:
113282 Page 4of 12 Parmname NOMI Sample QUDl QC Units RPD%
REC%
Range Anlst Date Time Rad Gamma Spec Batch 335643 Thallium-208 TPU:
+/-0.0113 0.170 Unccrt:
+/4-0.0287 TPU:
+/-0.0281
+/-0.018 0.178
+/-0.0396
+/-0.0388 pCi/g 4
(0% - 100%)
QC1200630677 Actinium-228 Amcricium-241 Bismuth-212 Bismuth-214 Cesium-134 I
Cesium-137 Cobalt-60 Europium-152 Europium-154 LCS Uncert:
TPU:
23.4 Unccrt:
TPU:
Uncert:
TPU:
Unccrt:
TPU:
Uncert:
TPU:
9.25 Uncert:
TPU:
14.4 Uncert:
TPU:
Unccrt:
TPU:
Uneert:
TPU:
U
-0.121
+/-0.605
+/-0.593 23.9
+1-2.53
+1-2A8 U
0.130
+1-1.05
+/-1.03 U
-0.0372
+1-0.260
+/-0.254 U
0.0528
+/-0.177
+/-0.174 10.0
+1-0.794
+1-0.778 15.3
+1-1.18
+/-1.16 U
-0.162
+/-0.317
+/-0.311 U
-0.166
+/-0.341
+/-0.334 U
-0.154
+1-0.363
+1-0.355 U
-0.0395
+/-0.171
+1-0.168 U
-0.0111
+/-0.230
+1-0.225 U
0.0255
+1-0.144
+1-0.141 U
0.00158
+1-0.128
+1-0.126 U
0.255 pCi/g 06/07/04 14:48 pCi/g 102 (75%-125%)
PCi/g PCi/g Pcitg pCi/g Pci/g 108 (75%-125%)
106 (75%- 125%)
Europium-155 Uncert:
TPU:
Lead-212 Uncert:
TPU:
pCi/g pCilg pCi/g pCi/g Pci/g PCi/g pCi/g pCLig Lead-214 Uncert:
TPU:
Mangancsc-54 Uneert:
TPU:
Niobium-94 Uncert:
TPU:
Potassium-40 78
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:
113282 Page 5 of 12 Parmname NOM Sample Qual QC Units RPD%
REC%
Range Anist Date Time Rad Gamma Spec Batch 335643 Radium-226 Silver-108m Th11llium-208 QC1200630675 NMB Actinium-228 Amcricium-241 Bismuth-212 Uncert:
TPU:
Uncert:
TPU:
Unccrt:
TPU:
Unccrt:
TPU:
Uncert:
TPU:
Bismuth-214 Uncert:
TPU:
Uncert:
TPU:
Unccrt:
TPU:
Uncert:
TPU:
+/-1.27
+/-1.24 U
-0.0372
+/-0.260
+/-0.254 U
-0.0412
+/-0.121
+/-0.119 U
0.0261
+1-0.134
+/-0.131 U
0.0129
+1-0.0917
+1-0.0899 U
0.00835
+1-0.0367
+/-0.0359 U
0.0543
+/-0.0954
+/-0.0935 U
0.0275
+/-0.0314
+/-0.0308 U
-0.0115
+/-0.0137
+/-0.0134 U
-0.000339
+/-0.0124
+/-0.0122 U
-0.0114
+/-0.0144
+/-0.0141 U
0.0317
+/-0.0373
+/-0.0365 U
0.0151
+1-0.0435
+1-0.0427 U
0.0124
+/-0.0367
+1-0.036 U
0.0191
+1-0.0395
+/-0.0388 U
0.0168
+/-0.0275
+/-0.027 pCi/g 06/07/04 11:17 pCi/g
- Cesium-134 pCi/g pCi/g (75%-125%)
Cesium-1 37 Uncert:
TPU:
_ Cobalt-60 pCilg PCilg PCilg pCi/g pcilg PCilg pCilg PCilg pCi/g pcilg pCilg Uncert:
TPU:
.I'Europium-152 Uncert:
TPU:
Europium-154 Uncert:
TPU:
Europium-155 Uneert:
TPU:
Lead-212
\\N Lead-214 Uneert:
TPU:
Uneert:
TPU:
79
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:
113282 Page 60r 12 Parmname NOM Sample Qual QC Units RPD%
REC%
Range Anist Date Time Rad Gamma Spec
_ Batch 335643 Mangancsc-54 I~ -Niobium-94 Uncert:
TPU:
Uncert:
TPU:
Potassium-40 Uncert:
TPU:
U 0.00156
+/-0.012
+/-0.0118 U
-0.00659
+/-0.0129
+/-0.0127 U
0.0486
+/-0.249
+1-0.244 U
0.0275
+/-0.0314
+/-0.0308 U
-0.0074
+/-0.0121
+1-0.0119 UU1 0.00
+/-0.0227
+/-0.0223 pCi/g Pci/g PCilg pCilg PCi/g
.. Radium-226 Unccrt:
TPU:
Silvcr-lOSm Uncert:
TPU:
Thallium-208 Uncert:
TPU:
Batch 335651 QC1200630701 Actinium-228 113282001 DUP Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 i
Europium-154
. Europium-155 0.531 Unccrt:
+/-0.105 TPU:
+/-0.103 U
-0.016 Uncert:
+/-0.0416 TPU:
+/-0.0408 0.292 Unccrt:
+/-0.149 TPU:
+/-0.146 0.466 Unccrt:
+/-0.0591 TPU:
+/-0.0579 U
0.0196 Uneert:
+1-0.0166 TPU:
+/-0.0162 0.0849 Uncert:
+/-0.0188 TPU:
+/-0.0185 U
0.00329 Uncert:
+/-0.0106 TPU:
+/-0.0104 U
0.00861 Uncert:
+/-0.0265 TPU:
+/-0.026 U
-0.0363 Uncet:
+/-0.033 TPU:
+/-0.0323 U
0.0229 0.401
+/-0.127
+/-0.125 U
-0.105
+/-0.0925
+/-0.0907 0.227
+/-0.167
+/-0.163 0.460
+/-0.0711
+/-0.0696 U
0.00314
+/-0.017
+1-0.0166 0.0814
+/-0.0204
+/-0.020 U
0.00382
+1-0.0154
+1-0.0151 U
-0.0225
+/-0.0381
+/-0.0374 U
-0.00504
+1-0.0505
+/-0.0495 U
-0.00636 pCi/g pCi/g N/A pCi/g 25 pCi/g I
pCi/g 145 pCi/g 4
pCilg 15 pCilg N/A pCi/g N/A 28 (0%h-100%)
SRB 06/08/04 10:56 (0%- 100%)
(0% - 100%)
(0% - 1 00%)
(00 h/- 100%)
(0%- 100%)
(0%h-100%)
(0%- 100%)
(0%- 100%)
pCilg N/A (0%- 100%)
80
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:
113282 Page 7of 12 Parmname NOM Sample Qual QC Units RPD%
REC%
Range Anist Date Time Rad Gamma Spec Batch 335651 Lad-212 Lead-214 Mangancsc-54 Niobium-94 I Potassium-40 Radium-226 Silver-108m Thallium-208 Uncert:
+/-0.0259 TPU:
+/-0.0254 0.460 Unccrt:
+/-0.0486 TPU:
+/-0.0476 0.502 Uncert:
+/-0.0625 TPU:
+/-0.0612 U
-0.00366 Unecrt:
+/-0.0102 TPU:
+/-0.010 u
0.00155 Uncert:
+/-0.00854 TPU:
+/-0.00837 12.2 Uncert:
+/-0.972 TPU:
+/-0.953 0.466 Uncert:
+/-0.0591 TPU:
+/-0.0579 U
0.00367 Uncert:
+/-0.00871 TPU:
+/-0.00853 0.159 Uncert:
+/-0.0277 TPU:
+/-0.0272
+/-0.0415
+/-0.0406 0.493
+/-0.0669
+/-0.0655 0.500
+/-0.0752
+/-0.0737 U
0.019
+/-0.0166
+/-0.0163 U
0.0153
+/-0.0126
+/-0.0123 12.3
+/-1.16
+/-1.14 0.460
+/-0.0711
+/-0.0696 U
-0.002
+/-0.0116
+/-0.0114 0.139
+/-0.0306
+/-0.030 pCi/g 7
(0%- 100%)
pCi/g 0
pCi/g N/A pCi/g 163 pCi/g I
pCilg I
pCi/g N/A pCi/g 14 (0%/o-100%)
(0%- 100%)
(0%/ -20%)
(0% - I 00%)
(0%- 100%)
(0%- 100%)
Actinium-228 Americium-241 Bismuth-212 Bismuth-2 14 LCS Uncert:
TPU:
23.4 Unecrt:
TPU:
Uneert:
TPU:
Unccrt:
TPU:
U 0.127
+/-0.538
+/-0.527 24.2
+/-2.93
+/-2.87 U
-0.0518
+/-1.07
+/-1.05 U
0.00698
+/-0.250
+/-0.245 U
-0.0422
+/-0.141
+/-0.138 9.66
+/-0.791
+/-0.775 15.0
+/-1.25
+/-1.22 pCi/g pCi/g 103 (75%-125%)
PCi/g PCilg pCilg 06108/04 13:18 Ccsium-134
-.. Ccsium-137 I__- Cobalt-60 Uncert:
TPU:
9.25 Uncert:
TPU:
14.4 Unccrt:
TPU:
pCi/g pci/g 104 (75%-125%)
104 (75%-125%)
81
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com QC Summary WVorkorder:
113282 Page 8of 12 Parmname NOM Sample Qual QC Units RPD%
REC%
Range Anist Dale Time Rad Gamma Spee Batch 335651 Europium-152 Uncert:
TPU:
Europium-154 Uncert:
TPU:
Europium-155 Uncert:
TPU:
Lead-212 Lead-214 Uncert:
TPU:
Uncert:
TPU:
Manganese-54 Uncert:
TPU:
Niobium-94 Uncert:
TPU:
Potassium-40 Uncert:
TPU:
U 0.184
+1-0.324
+/-0.317 U
-0.103
+/-0.312
+/-0.306 U
0.121
+/-0.335
+/-0.328 U
0.0649
+/-0.178
+/-0.174 U
-0.0605
+/-0.239
+/-0.234 U
0.0267
+/-0.141
+/-0.139 U
-0.00218
+/-0.123
+/-0.121 U
1.06
+/-1.37
+/-1.34 U
0.00698
+/-0.250
+/-0.245 U
-0.0801
+/-0.133
+/-0.131 U
0.0829
+/-0.122
+/-0.120 U
0.057
+/-0.135
+/-0.133 U
-0.0612
+/-0.0856
+/-0.0839 U
0.00539
+/-0.152
+/-0.149 U
0.0655
+/-0.049
+/-0.048 U
0.00286
+/-0.0211 pCi/g pCi/g pCi/g pCi/g PUB/
pCilg pCi/g pCilg Radium-226 pCi/g (75°/6-125%)
Uncert:
TPU:
Silver-108m Uncert:
TPU:
pCi/g pCi/g Thallium-208 Unccrt:
TPU:
QC1200630700 Actinium-228 MB pCi/g 06/08/04 15:38 Uneert:
TPU:
Americium-241 Uncert:
TPU:
Bismuth-212 Bismuth-214 Uncert:
TPU:
pCi/g pCi/g pCi/g pCi/g Uncert:
TPU:
Cesium-134 Uncert:
R2
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com QC Summary A~ kr~!
1R
.1 -
.-- ssPage 9of 12 Parmname NONM Sample Qual QC Units RPD%
RECM Range AnIst Date Time Rad Gamma Spec Batch 335651 TPU:
Cesium-137 Unccrt:
TPU:
Cobalt-60 Unccrt:
TPU:
Europium-152 Unccrt:
TPU:
Europium-154 Uncert:
TPU:
Europium-155 Uncert:
TPU Lead-212 Lead-214 Uncert:
TPU:
+/-0.0207 U
0.016
+/-0.0193
+/-0.019 U
0.00882
+/-0.032
+/-0.0314 U
-0.0213
+/-0.0606
+/-0.0594 U
-0.00826
+/-0.0665
+/-0.0652 U
-0.00895
+/-0.0505
+/-0.0495 U
0.0536
+/-0.0362
+/-0.0354 U
0.0749
+/-0.0475
+/-0.0466 U
-0.00208
+/-0.0208
+/-0.0204 U
-0.00377
+/-0.0189
+/-0.0185 UUW 0.00
+1-0.363
+/-0.356 U
0.0655
+/-0.049
+/-0.048 U
-0.0101
+/-0.0192
+/4.0188 U
0.00652
+/-0.0421
+/-0.0413 pCi/g pCi/g pCilg pCi/g pCilg PCilg PCilg pCilg pCilg pCilg PCilg pCi/g pCilg Uncert:
TPU:
_ Mangancsc-54 Uncer:
TPU:
I Niobium-94 Uncert:
TPU:
-. Potassium-40 Uncert:
TPU:
Radium-226 Uncert:
TPU:
Silvcr-108m Uncert:
TPU:
Thallium-208 Uncert:
TPU:
j ' Rad Gas Flow
- Batch 335956 QC1200631488 113282019 DUP I Strontium-90 QC1200631490 LCS
-- Strontium-90 U
0.00426 Uncert:
+/-0.0 179 TPU:
+/-0.0179 0.0433
+/-0.0167
+1-0.019 pCi/g 0
(0% - 100%) HOBI 06/03/04 19:12 2.64 2.42 pCi/g 92 (75%-125%/)
06/03/04 17:42
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chaleston SC 29407 - (843) 556-8171 -www.gel.com QC Summary Workorder:
113282 Page 1 oor 12 Parmname NONI Sample Qual QC Units RPD%
REC%
Range Anist Date Time f
Rad Gas Flow
- Batch 335956 Unccrt
TPU:
+/-0.126
+/-0.539 f
QC1200631487 MB Strontium-90 QC1200631489 113282019 NIS Strontium-90 Rad Liquid Sdntillation Batch 339628 QC1200640252 113282019 DUP Tritium Unccrt:
TPU:
0.0485
+/-0.0152
+1-0.0187 pCi/g 06/03/04 19:12 5.94 U
Uncert:
TPU:
0.00426
+1-0.0179
+1-0.0179 5.26
+/-0.276
+1-1.14 pCi/g 89 (75%-125%)
06/03/04 17:42 U
-3.19 Uncert:
+1-4.96 TPU:
+/-4.97 U
-1.94
+/-3.23
+1-3.23 pCi/g N/A (0% - 100%/6) JLBI 06/12/04 01:21 QC1200640254 LCS Tritium QC1200640251 MB Tritium QC1200640253 113282019 MS
' 'Tritium 57.7 Uncert:
TPU:
57.9
+/4-.54
+1-8.14 pCi/g 100 (75%-125%)
Uncert:
TPU:
U
-2.26
+/-3.03
+/-3.03 pCi/g 0612/04 02:26 06/12/04 00:48 06/12/04 01:54 80.9 U
Uncert:
TPU:
-3.19
+1-4.96
+1-4.97 70.7
+1-8.79
+1-10.6 pCilg 87 (75%-125%)
Batch 339685 QC1200640377 113282019 DUP Tcchnctium-99 QC1200640379 LCS T
Tcchnctium-99 QC1200640376 MB Technetium-99 t
i -
QC1200640378 113282019 MS Technetium-99 U
0.270 Uncert:
+/-0.242 TPU:
+/-0.242 U
0.244
+1-0.268
+1-0.269 pCi/g 0
(0%- 100%) DAJ1 06/19104 07:05 16.3 Uncert:
TPU:
18.7
+1-0.614
+1-0.895 pCi/g 114 (75%-125%)
Uncert:
TPU:
U 0.172
+1-0.192
+1-0.192 pCi/g 06/19/04 09:51 06/19/04 05:30 06119/04 09:18 16.7 U
Unccrt:
TPU:
0.270
+/-0.242
+1-0.242 18.6
+/-0.790
+1-1.02 pCi/g 109 (75%-125%)
B t
- , Batch 339689 QC1200640385 113282019 DUP
. Nickel-63 l
I U
4.54 U
7.25 pCilg 0
(0% - 100%) JLB I 06/12/0413:1 1 84
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Workorder:
113282 Parmname Rad Liquid Scintillation Batch 339689 QC1200640387 LCS Nickce-63 QC1200640384 MB Nickel-63 QC1200640386 113282019 NIS Nickel-63 Batch 342387 QC1200647033 113282020 DUP Carbon-l 4 QC1200647035 LCS Carbon-14 QC1200647032 MB Carbon-i 4 QC1200647034 113282020 MS Carbon-14 Batch 342541 QC1200647441 113282019 DUP Iron-55 QC1200647443 LCS Iron-55 QCI 200647440 MB Iron-55 QC1200647442 113282019 NIS Iron-55 NONI Uncert:
TPU:
353 Unccrt:
TPU Unccrt:
TPU:
538 Uncert:
TPU:
Uncert:
TPU:
8.21 Unccrt:
TPU:
Unccrt:
TPU:
8.15 Uncert:
TPU:
Unecrt:
TPU:
1170 Unecrt:
TPU:
Uneert:
TPU:
1510 Uncert:
TPU:
+1-6.93
+/-7.82
+1-6.93
+1-7.83 345
+/-10.2
+/-12.3 U
2.73
+/-5.67
+/-5.67 U
4.54 524
+/-6.93
+/-17.3
+/-6.93
+/-20.2 U
-0.0219 U
0.0321
+/-0.1 15
+/-0.155
+/-0.115
+/-0.155 7.60
+1-0.541
+/-0.554 U
0.122
+/-0.184
+/-0.184 U
-0.0219 7.75
+/-0.1 15
+/-0.614
+/-0.115
+/-0.626 U
-31.4 U
45.5
+/-41 A
+/40.7
+/-41.4
+/40.8 1110
+1-58.2
+/-75.4 U
-73.1
+/-37.1
+/-37.2 U
-31.4 1450
+/-41.4
+/-53.5
+/-41.4
+/-82.4 Page 1 hor 12 Units RPD%
REC%
Range Anist Date Time pCi/g pCi/g pCi/g 98 (75%-125%)
97 (75%-125%)
pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g N/A (0% - 100%) MWX 93 (75%-125%)
06/12/04 16:15 06/1204 11:39 06/1204 14:43 0612204 01:09 06/20/04 17:23 06/21/04 22:36 06/20104 16:51 06/23/04 17:41 06/23/04 00:37 06/23/04 17:09 06/23/04 00:05 95 (75%-125%)
N/A (0% - I00%) JLB I 95 (75%-125%)
96 (75%-125%)
B5
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary W
Workorder:
113282 Page 12of 12 Parminame NOM Sample Qua]
QC Units RPD%
REC%
Range Anist Date Time Notes:
The Qualificrs in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target analytc exceeds the instrument calibration range.
H Analytical holding time exceeded.
1J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-pleasc see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more.
- Indicates analyte is a surrogate compound.
A The Relative Percent Differencc (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.
For PS, PSD, and SDILT results, the values listed arc the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Sutumary.
86
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD b Hard-To-Detect Data (Pages 9)
i B
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: -Haddam Nock Plant 362 Injun Hollow Road East Hamptn, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date:
June 24.2004 Page I of 3 Client Sample ID:
Samnple ID, Matnrx:
Collect Date:
Receive Date:
Collector:
Moisture:
9535-0001-02F 113282019 Soil 22-APR-04 19-MAY-04 Client 3.37%
Pect; YANCOOSW4 C tent IP:
YANKOOI Vol. Recv.:
Paraenter Quallflcr Result Uncertainty LC TPU MDA Units DF AnalystDate Ttme Batch Mtd.
Rad Alpha Spec Analysis AlphapecAm241. Om Solid All FSS Amcdicium-241 U
0o.
+1-0.0487 0.00 +/-0.0487 0.0673 Curium-242 U
0.00
+t4.0601 0.00 +1-0.0601 0.0831 Curlun-2431Z44 U
0.019
+4.0503 0.02S4 +/4.0504 0.125 Alphaspec Pb Solid-AlL FSS Plutonium-238 U
0.0175
+1-0.0515 0.0479 +1-0.0515 0.16i Plutoniom-239/240 U
-0.00581
+/-0.0488 00276 +1-0.0489 0.121 lquiddScint Pu24t, Solid-ALL FSS Plutonium-241 U
3.38
+1-6.01 4.94
+1-6.02 10.2 Rad Gamma Spec Analysis Gammanec. Gamma, Solid-FSS CAM & ALL FSS Actinium-228 0S504
.1-0.175 0.0601
+t4.171 0.131 Amreicium-241 U
.0.0123
+1.0516 0.0425 +t-0.0506 0.0872 Blsmuth-212 0.726
+1-0.401 0.152 +10393 0325 Bismuth-214 0566
.140.108 0.0349
+10.106 0.0741 Cesium-134 U
0.015
+t-0.0491 0.025.1-0.0482 0.053 Cesium-137 0.0989
+1-0.0529 0.0199 14.0S18 0.0422 Cobalt-60 U
40.00653
+14.0238 0.019./40233 0.042 Europiue-152 U
0.0139
+/-0.0569 0.0513 +610558 0.107 Europium-154 U
0.00412
+M-0.0707 0.0593 +t4.0693 0.129 Europium-155 U
0.00675
+/-0.0582 0.0526 40.057 0.108 Lcad-212 0.466
+t-0.0724 0.0278 4/4071 0.0575 Lead-214 0553
+t-0.113 0.0358 41-0.111 0.0748 Manganese-54 U
0.0247 4/-0.0241 0.0225 +t-0.0236 0.048 Niobium-94 U
- 0.00451
+t4.0223 0.0183 +t-0.0218 0.0388 Potassuiun40 10.5
+1-1.19 0.153 41-1.16 0.345 Radium-226 0566 41-0.108 0.0349
+/-0.106 0.0741 Silver-108m U
-0.0147
+1-.0195 0.0161 +10.0191 0.034 Thallium-208 0.218
+1.0.0557 0.0179 +t0.0546 0.0382 Rad Gas Flow Proportional Counting pCVg pCi/g pciCg pCi/g pi/Cg pCi/g pitg pCi/g pCig pCi/i%
pCi/9 pci/g pC/g pCilg PCi/8 PCUg pCI/g pCi/s pCUg pCUg pCI/g JAS I 06/10104 0943 338561 1 JASI 06J10/04 0944 338562 2 JASI 06/11/04 0213 3385633 SRB 06/08104 0952 335651 4 HOB I O6/0304 1844 335956 5 JLB I 06/11104 2101 339628 6 GFPC; Sr90, solid-AL FSS Strontiam-90 U
0.0 Rad Liquid Scintlation Analysis LsL Tritium Dist Solid -H 2,ALL FSS Tritium U
Liquid Sciht C14, SoLid FSS 0426
+/-0.0179 0.0183 +/-0.0179 0.0387
.3.19
.1-4.96 4.39
+14.97 8.78
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddarn Neck Plant 362 Injun Hollow Road East Haampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils P0# 002332 Report Date: June 24,2004 Page 2 of 3 Client Sample ID:
Sample ID:
9S35-0001-002F 113282019 ProNect:
YANKOO504 Client ID:
YANK001 Vol. Recv.:
Parameter Qualifier Result Uncertailty LC TPU MDA Units DF Analysts Time Bateh Mtd.
Rad liquid Scintillation Analysis LlquldScint C14. Solid FSS Carbon-14 U
E qWdSclnt FeSS, Solid-ALL FSS Iron-5 U
lUqid Scin N63, Solid-ALL FSS Nickel-63 U
LUquid Sc TMc99. Soeid-ALL FSS Techntlurm-99 U
0.0289
+.! ts19 0.0984
+1-0.119 0.204 pCi/g
-31A 44-41A 16.9
+441.4 35.3 pC0g MWX 0&20/04 0758 342387 7 ILBI 06r22/04 1919 342541 9 LBI 06112104 0400 339689 12 DAlI 06118104 2137 339685 13 4.54
+1-6.93 5.74
+/-6.93 11.7 pCi/g 0.270
+1-0.242 0.199
+/-0.242 0.404 pCI/g M
The following Prep Methods were performed__
Method Description Analyst Date Tme Prep Batch Ash Soil Prep Ash Soil Prep. GL-RAD-A-02IB API 05/21J04 1445 334895 Dry Sonl Prep Dry Soil Prep OL-RAD-A-021 MJMI 05It04 1441 334885 The foUowing Analytical Metbods were performed Method Description I
DOE EML HASL-300, Am-0S-RC Modified 2
DOE EML HASL-300, Pu-I -RC Modified 3
DOE EML HASL300. Pu-I I-RC Modified 4
EML HASL 300.4.5.2.3 5
EPA 905.0 Modified 6
EPA 906.0 Modified 7
EPA EERF C-Ol Modified 8
EPA EERFC-01 Modified 9
DOE RESLFe-I, Modified 10 DOE RESL Fe-1, Modified 11 DOE RESL Fe-, Modifled 12 DOE RESL Ni-I, Modified 13
)OE EbML HASL-300, Tc02-RC Modified Surrogapftlraterreovcry Test Reaover%
Acceptable limits Amitierim.241 Alohasorc Am241. Cm. Solid ALU 84 (25%-125%)
Plutonium-242 Alphaspec Pit, Solid-ALL FSS 89
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com Certificate of Analys Company: Connecticut Yankee Atomic Power Address:
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Contact:
Mr. Pete 1lollenbeck Project:
Soils PO# 002332 Report Date: June 24.2004 Page 3 of 3 Client Sample ID:
Sample ID:
9535-400-002F 113282019 Minet YANK00504 CUent ID:
YANKOOI Vol. Recv.:
Parameter Quallfer Result Urertalnty LC TPU MDA Units DF AnalystDate hime DatkhMtd.
Carricrfrracer Recovery CarrierrTracer Recovery Canrierfrracer Recovery Cam/ierirhce Recovery CarrierfTracer Recovery Liquid Scint Pu241. Solid-ALL FS GFPC, SflO, solid-ALL FSS Liquid Scint Fc5S. Solid-ALL FS Liquid Scint Ni63, Solid-ALLFS Liquid Scint Tc99, Solid-ALLFS 100 96 87 74 St (25%-125%)
Noteg.:
Thc Qualifiers in this report are defined as follows:
B Target analyte was detected In the sample as well as the associated blankl BD Flag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection Imit Ill Uncertin identificadon for gamma spectroscopy.
X Lab-specific qualifier-plcals sce casc narative, data sulmary package or contact your project manager for details.
h Sample preparation or prescrvation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with General Engineeing Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlilk I
M -Q C o-Ow Reviewed by
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gei.com Certificate of Analysi Company:
Connecticut Yank1e Atomic Power Address:
Haddamn Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact hMr. Pete Hollenbeck Report Date: June 24,2004 Page 1 of 3 Project:
Soils PO# 002332 Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
Moisture:
9535-0001-006F 113282020 Soil 22-APR-04 19-MAY-04 Client 4.66%
Proiect:_
YANK00504 Client ev:
YANKOOI Vol. Recv.:
Parameter Qualiler Result Uncertainty LC TU MDA Units DF AMblsv)ate Trme Batch MWL Rnd Alpha Spec Analysbs Alphaipec Am241. Ch SolidAU FSS Amaiclumn-241 U
0.0483 Curium-242 U
0.0318 Curium-243VW44 U
0.156 Aiphxapec P Solid-AL FSS Plutonium-238 U
0.0142 Plutonium-239WA0 U
0.00 UquldScintPu241. Solid-AL FSS Plutonium-241 U
-0.559 Rad Gamma Spc Analysis CGmnaspec, Gamma Solid FSS CAM & ALL FSS Actiwn-228 0.474 Ameticdum-241 U
0.00339 Bismuth-212 0.407 Bmnauth-214 0,564 Cesium-134 U
0.0273 Ceslum-137 0.127 Cobalt-60 U
-0.00247 Europlum-IS2 U
0.0164 Europium-I54 U
-0.0227 Europium-55 U
0.0392 Lad-212 0552 Lued-214 0.616 Manganese,54 U
-0.0057 Nilobium-94 U -0.000592 Potasslum-40 11.2 Radium-226 0.564 Slivcr-108m U
0.0033 ThaIlium-208 0.170 Bad Gas Mlow Proportional Counting GFPa Sr9o..olid-ALL FSS Strontium-90 0.0722 Rad uIquid Scintillation Analysis LSC dtbium Dirt Soli-D2,AU FSS Tritium U
-3.2 LiquddScnt CJ4, Solid FSS
./-0.128
+1-0.139 W-0.232 0.110
+/-0.128 0.129
+1-.139 0.201
+/4.233 0.303 pCVg 0.361 pCI/g 0.484 pCi/g iJ-0.076 0.0707 +/-0.0761 t1-0.0496 0.00 +/-0.0496
+/-6.63 5.59
+/-6.63 0.210 0.0686 pCI/g 11.5 pCVg
+/-0.138
+1-0.0863
+/-0.186
/-0.0793
+/-.0264
./-0.0272
./-0.017
+1-0.0424 4/-0.0514
./-0.0449
+/-0.0636
+/-0.0925
+/-0.0182 4-0.0136
+/-1.08
+4.0793
+/4.0154
.1-0.0364 0.0439
+1-0.135 0.0575 +/0.0846 0.103 1-0.182 0.0222 +J,0777 0.0172 +.-.0258 0.0127 +40.0266 0.0141 +1-0.0167 0.0378 +/-0.0415 0.0417 +1-0,0504 0.0415
+/-0.044 0.020S +/-.0624 0.0252
.400907 0.0151 +1-0.0178 0.0117 +/-0.0133 0.127
+/-1.06 0.0222 +/-0.CT77 0.0118 +t-0.0151 0.0133 +1.0.0357 0.0942 0.118 0.220 0.0471 0.0363 0.0271 0.0308 0.0786 0.0902 0.0852 0.0431 0.0526 0.032 0.0248 0280 0.0471 0.0247
.0282 0.0249 pCi/:
pCi/g pCg pCi/g pCilg pCilg pCi/g pCi/g pCI/g pCUg pC~g pCi/g pCitg pC'g pCi/g pC01g JASI 06t11/04 1323 338561 1 JAS&I61O04 0944 338562 2 JASI 06/11104 0245 338563 3 SRB 06tOS/0 0953 335651 4 HOB I 06(04 1844 335956 5 JLBI 06111/04 2133 339628 6
+1-0.0182 0.01 14
+1-.024 414.29 3.83
+t4.30 7.67 pCitg
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 555-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Repor Date: June 24,2004 Page 2 of 3 Client Sample ID:
Sample ID:
9535-0001-006F 113282020 Prpiect:
YANKOOS04 ol.t YANK001 Vol. Recv.:
Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst~te TIme Bateb ldUL Rad Liquid Sdntfilhtlon Analysi Liquld Scint C14, Solid FSS Carbon-14 U
Liquid ScinL FeSS. Solid-ALL FSS Jron-SS U
Uquid S&Ni63, Solid-ALL FSS Nickl-63 iUquddSca Tc99, Solid-ALL FSS Toccletium-99 U
-0.0219
+h-.115 0.0976
+/-0.115 0.203 pCi/g
-49.7
+/-41.9 16.7
+1-41.9 34.8 pCits MWX 0W20(4 0901 342387 7 JLBI 06123/04 1430 342541 9 JLBI 06/12/04 0531 339689 12 DA1I 06/18104 2312 339685 13 15.8
+1-930 7.54
.1-930 15.3 pCiYg 0.319
+.-0.212 0.173
+/-0.212 0.351 pCilg be following Prep Methods were performed Method DesaiptIon Analyst Date lime PrepBatch Ash Soil Prep Ash Soil Prep, GL.RAD-AI2B API 0321/04 1445 334895 DrySoilPrep DrySoUlPrepGL-RAD-A-02I Mimi 05/20(04 1441 334885 Tbe following Analytical Methods were performed Mehod Description I
DOE EML HASL-300, Am4-5-RC Modified 2
DOEEML IASI,300, Pu-l I-RC Modified 3
DOE EML IHASL-300, Pu-lI-RC Modified 4
EML HASL 300,445.23 S
EPA 905.0 Modified 6
EPA 906.0 Modified 7
EPA EERF C-0 Modified 8
EPA EERF C-01 Modified 9
DOE RESL.Fe-I, Modified 10 DOERESLIFe-1,Modifled 11 DOE RESLFe-l, Modified 12 DOE RESL Ni-I, Modified 13 DOE EML HASLA300, Tc-02-RC Modified Swuogattoliracer rcovery Test Recovery%
Acceptable Imts Amercium-243 Alphaspec Am241, Cm, Solid AU 77 (25%-125%)
Plutonium-242 Alpbaspec Pu, Solid-ALL FSS 85
I II GEEAININEIGLBRAOISIL GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 558-8171 - www.gol.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Hladdam NeckPlant 362 Injun Hollow Road East Hanpton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: Junc 24, 2004 Page 3 of 3 Client Sample ID:
Sample ID:
9535-0001-006F 113282020 Chent IDW Vol. Recv.:
YANK00504 YANK001 Parameter Quallfer Result Uncertahity LC TPU MDA Vnits DP Anaytalte lime Batch Mtd.
Camerd'facer Recovery CarierTrracer Recovery Carierfrracer Recovery Carricrlrracer Recovery Carri/rTracer Recovery Liquid Scint Pu241, Solid-ALL FS GFPC, Sr9u, solid-ALL FSS Liquld Scint PeSS, Solid-ALL FS Liquid Scint Ni63. Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 88 103 9
69 60 (25%-125%)
Notes:
The Qualifiers in this report ame defined as foliows:
B Target analyte was detected in the sample as well as the associated blank.
BD Flag for results below the MDC or a flag for low tracer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
1 Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyto was analyzed for but not detected above the detection limit.
Ul Uncertain Identification forgarma spectroscopy.
X Lab-specific qualificr-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with Genetral Engineering Laboratories. LLC standard operating procedures. Please direct any questions to your Project Manager. Sarah Kozlik v Ci b
(Qy cAQ Reviewed by
I GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LBORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Anal y Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton. Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Dawc: lune 24, 2004 Page I of 3 Client Sample ID:
Sample ID:
Mat=x:
Colicct Date:
Receive Date:
Collector, Moistur=:
9535-0001-016F 113282021 Soil 27-APR-04 19-MAY-04 Client 11.5%
Proiect:
YANK00504 Client ID:
YANKOOI Vol. RecY.:
Parameter Qualifer Result Uncertalnty LC WU
?4DA Units DF AnalystDate Time Batch Mtd.
Rad Alpba Spec Analys AlphampecAmZW4. On. Solid ALL FSS Aricium-241 U
0.0335
+1-0.0735 0.0516
-10.0756 0.174 Curium-242 U
0.0316 4140619 0.00
+1-0.062 0.0855 Curium-243/244 U
-0.0126 tt-0.0175 0.0423 +1-040175 0.156 Alphaspec Pu. Solid-ALL FSS Plutonium-238 U
0.0345 W-0.142 0.13S
+1-0.142 0.351 Plutonlum-239/240 U
40.0332
+/-0.0965 0.122 +/-0.0965 0.324 Lqid Scit PU24M
. Solid-ALL FSS Plutonium-241 U
2.61
+/-6.70 5.54
./-.70 11.
Rxd Gamma Spec Analysis GamapecC, Gammn4 Solld-FSS CAM & ALL FSS Actinlum-228 0.535 41-0.119 0.0344
.1.0.117 Q072S Azericium-241 U
-0.0168 40.0755 0.061
+1-0.074 0.125 Bismutdi212 0.306 4(4167 0.0787
+140.163 0.165 Bismuti-214 0.442 40.062 0.0195 +1-0.0608 0.0406 Cesium-134 U
0.0198
+1-0.0246 0.0138 +1-0.0241 0.0286 Cesium-137 0.0544
+/-0.0266 0.0109./.0261 0.022 Cobaltc60 U
0.0057
+W-0.0118 0.0104 +/4.0116 0.0222 Europium-152 U
.0.00602 410.0319 0.0274 +-0.0312 0.0569 Europium-154 U
.0.0185
- 0.0348 0.0282 +1-0.0341 0.0604 Europium-lS5 U
0.0536
+4-0.0418 0.0384 f/10.0409 0.0787 Lead-212 0.538 4-0.0562 0.0172
+140.055 0.0353 Laad-214 0.569
./-0.0702 0.018 +/-0.0688 0.0375 ManganescS4 U
0.00357
+1-0.0131 0.0112 +1-0.0128 0.0235 Nioblum-94 U
-O.OOl22
+1-0.0111 0.00948 +140.0109 0.0198 PotassiumO 113 4-0.987 0.0814
.1.0.967 0.177 Radium-226 0.442 40.062 0.0195 4/4.0608 0.0406 Silvr-108m U -0,000399
./-0.0112 0.00954 41-0.011 0.0198 ballium-208 0.155 40.0282 0.0102 W.0.0276 0.0213 Rid Gas Flow Proportional CountIng pClg pCilk pCi/g PCL'g pCi/g pa/g pCi/g pCag po/g pCCUg pCi1g pcvg pCgll pCilg pCilg pCi~g pCL'g pCilg pCl/g P0B pCllg pci/e JASI 06/10/04 0943 338561 1 JASI 06110104 0943 3385622 IASI 06/11/04 0316 338563 3 SRB 06/0804 1203 335643 4 IIOBI 06/03104 1843 335956 5 JLB 1 06/11/04 2206 339628 6 CFPC, Sr0. olid-ALL FSS Stronitium-90 U
0.
Rad IUquld Sdntillation Analysis LSC; Tiium Di.t. SolidM 2ALL FSS Tzitium U
Liquid SCent CIA4 Solid FSS 0257
+/-0.0159 0.0138 +./0.0169 0.0297 2.28
+4-3.80 3.35 4-3.80 6.70 pCIg
I I.
I GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charloston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddamn Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
SoIls PO# 002332 Report Date: June 24,2004 Page 2 of 3 Client Sample ID:
Sample ID:
9535-0001.016F 113282021 Progect:
YANK00504 Vol. Recv.:
Parameter Qualifier Result Uncertainty LC TPU MDA Units DF AnalystDate lhne BakhbMtd.
Rad Liquid Sdntillatlon Analysis UquldScint CU4, Solid FSS Carbon14 U
Liquid Schi Ft5, Solid-ALL FSS ron-.5 U
Liquid Sc:t NW63, Solid-ALL FSS Nickel-63 U
Liquid S Tc99, Solid-ALL FSS Technetium-99 U
-0.0695
+1-0.103 0.0895
+1-0.103
-63
+142.4 17.5
+W-425 14.1
+1-14.0 11.6 W-14.0 0.186 365 23.5 0.422 pCig pCi/9 pCi/g MWX 0612(Y04 1003 342387 7 lLBI 06/23104 1502 342541 9 JLBI 06/12104 0703 339689 12 DAII 06/19/04 0046 339685 13 0383
+40.254 0.208
+/.0.254 Toe following Prep Methods were performed Method Desription Anal Date Time Prep Batch Ash Soil Prep Ash Soil Prep. OL-RAD-A-021B AFI 0521/04 1445 334895 Dry Soil Prep Dry Soil Prep IL-RAD-A-021 MiMI 0es20/04 1441 3348S85 The followig Analytcal Methods were performed Method Description I
DOE EML HASL-300, Am-05-RC Modified 2
DOE EML HJASL.W300, Pu-l I -RC Modified 3
DOE EML HASL-300. Pu-lI-RC Modified 4
EML HIASL 300,4.5.2.3 5
EPA 905.0 Modified 6
EPA 906.0 Modified 7
EPA EERF C-01 Modified 8
EPA EERF C-0l Modified 9
DOERESLFc-l.Modified 10 DOERESLUC-I.Modified 11 lDOERESLFe-l.Modiried 12 DOE RESL Ni-I, Modifled 13 DOE EML HASL-300, Tc.02-RC Modified SurmWgaterncw recoe1uy Test Recovery%
Acceptable limits Amc icium-.2M Alohasoec An241. CCm. Solid AL 79 (25%-125%)
Plutonium-242 Alpbapec Pu, Solid-ALL FSS 80
I I
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407. (843) 556-8171 - ww.gel.com F.
Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddan Neck Plant 362 Injun Hollow Road East Haxpton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PO# 002332 Report Date: June 24,2004 Page 3 of 3 Client Sample ID:
Sample ID:
9535-001-016F 113282021 rpiec:
YANK00504 l ent I:YANKOOI Vol. Recv.:
arameter Qulifier Result Uncertainty LC 7Tf MDA Units DF Analwytate lime Batch Mtd.
CarderfrracerRecovery Liquid Scint Pu241, Solid-ALLFS 90 Carrierfrracer Recovery CaericTracer Recovecy Carrierfrscer Recovery Canierfrracer Recovery GFPC, Sr9O, solid-ALLFSS Liquid Scint FeS5, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS
-Liquid Scint Tc99, Solid-ALL FS 10D 82 49 49 (25%-125%)
Notes:
Ibe Qualifiers in this report are defined as follows:
B Target analyte was dtected in the sample as well as the associated blankc BD ag for rets below the MDC or a flag for low traer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed forbut not detected above the detection limiL U1 Uncertain idendficadon for gauma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlik.
Reviewed by
l SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 1
RELEASE RECORD c Sample and Scan Area Data (2 Pages)
Survey Release Record Scan Area Results Survey Unit 9535-0001 Survey Unit 9535-0001 I
earn 9535-01-001-BC-001 9535-01-001-BC-001 9535-01-001-BC-002 9535-01-001-BC-002 9535-01-001-BC-003 9535-01-001-BC-003 9535-01-001-SC-001 9535-01-001-SC-002 9535-01-001 -SC-003 9535-01-001-SC-004 9535-01-001-SC-005 9535-01-001-SC-006 9535-01-001-SC-007 9535-01-001 -SC-008 9535-01-001-SC-009 9535-01-001-SC-010 9535-01-001-SC-011 9535-01-001-SC-012 9535-01-001-SC-013 9535-01-001-SC-014 9535-01-001-SC-015 9535-01-001-SC-016 9535-01-001-SC-017 9535-01-001-SC-018 9535-01-001-SC-019 9535-01-001-SC-020 9535-01-001-SC-021 9535-01-001-SC-022 9535-01-001-SC-023 9535-01-001-SC-024 9535-01-001-SC-025 9535-01-001-SC-026 9535-01-001-SC-027 9535-01-001-SC-028 9535-01-001-SC-029 9535-01-001-SC-030 9535-01-001-SC-031 9535-01-001-SC-032 9535-01-001-SC-033 9535-01-001-SC-034 9535-01-001-SC-035 9535-01-001-SC-036 9535-01-001-SC-037 6,890 8,540 7,910 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6,890 6 890 6,890 6,890 6,890 6,890 7210 7210 7210 7210 8,540 8,540 8 540 8,540 8,540 8,540 8,540 8,540 8,540 8,540 8.540 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12000 12000 12000 12000 12000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12,000 12.000 12,000 7,910 7210 6,790 6,420 7,210 7,230 6,360 6,390 7,160 6,800 7,100 8,060 6,1 80 7,120 7,230 6,070 6,970 6,790 7,420 7,670 7,330 7,670 7040 6380 6590 6860 8,120 8,590 7,340 6,980 7,710 7,830 7,100 7,290 7,380 7,440 8,370 6,700 8.470 6,890 4/21/2004_
5460 4122/2004_
8,540 4/21/2004_
7160 4/2212004_
4/21/2004 4/21/2004 4/21/2004 4/21/2004
_4/21/2004_
4/2112004 4/21/2004 4/21/2004
_4/21/2004_
_4/2/2004
_4/21/2004_
_412112004
_4/21/2004_
4/21/2004 4 121/2004
_4/21/2004_
_4/2112004
_4/2112004_
_4/21/2004_
4/22/2004_
_4t2moo4
_4/2212004_
_4/221/2004_
_412112004_
_4/2112004_
_4Q122004_
_4Q122004_
_4r~moo4_
_412112004_
_4t~moo4_
412112004
_412112004_
4/211204
_4t~moo4_
41212004 4121/2004 4121/2004 412112004 8:17 9:53 8:26 8:53 12:53 14:03 8:37 8:43 8:52 8:58 9:03 9:08 9:16 9:21 9:27 9:32 9:37 9:44 9:50 9:56 10:01 10:06 10:12 13:00 13:06 13:10 14:09 14:12 14:16 14:21 10:07 10:02 9:56 9:48 9:40 9:34 9:27 9:20 9:13 9:06 9:00 8:53 8:46 1109 1112 1110 1109 1109 1112 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1109 1112 1112 1112 1112 1110 1110 1110 1110 1110 1110 1110 1110 1110 1110 1110 1 1109 11109 1009 1005 1007 1009 1009 1005 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1009 1005 1005 1005 1005 1007 1007 1007 1007 1007 1007 1007 1007 1007 1007 1007 1007 1007 l
I I
I
Survey Release Record Scan Area Results Survey Unit 9535-0001 Survey Unit 9535-0001 cont' 9535-01-001-SC-038 8,540 12,000 8,930 4/21/2004 8:38 1110 1007 9535-01-001-SC-039 7,910 12,000 7,240 412112004 13:24 1109 1009 9535-01-001-SC-040 7,910 12,000 8,010 4121/2004 13:32 1109 1009 9535-01-001-SC-041 7,910
-12000 7 550 4/21/2004 13:38 1109 1009 9535-01-001-SC-042 7,910 12,000 7,500 4121/2004 13:43 1109 1009 9535-01-001-SC-043 7,910 12,000 7,780 4/21/2004 13:47 1109 1009 9535-01-001-SC-044 7,910 12,000 7,360 4/21/2004 13:51 1109 1009 9535-01-001-SC-045 7,910 12,000 8,010 4121/2004 13:55 1109 1009 9535-01-001-SC-046 7,910 12,000 7,580 4/21/2004 14:00 1109 1009 9535-01-001-SC-046 7,910 12,000 7,610 4/2112004 14:01 1109 1009 9535-01-001-SC-047 7,910 12,000 7,910 4/21/2004 14:04 1109 1009 9535-01-001-SC-048 7,910 12,000 7,270 4/21/2004 14:07 1109 1009 9535-01-001-SC-049 7,910 12,000 7,940 4121/2004 14:12 1109 1009 9535-01-001-SC-050 7910 12*000 7,350 4/21/2004 14:15 1109 1009 9535-01-001-SC-051 7,910 12,000 7,380 4/21/2004 14:18 1109 1009 9535-01-001-SC-052 7,910 12,000 7,290 4/21/2004 14:22 1109 1009 9535-01-001-SC-053 5460 12000 6910 4122/2004 10:06 1112 1005 9535-01-001-SC-054 7160 12000 6960 4122/2004 9:07 1109 1009 9535-01-001-SC-055 5460 12000 6780 4/22/2004 10:14 1112 1005 9535-01-001-SC-056 7160 12000 7450 4122/2004 9:14 1109 1009 9535-01-001-SC-057 5460 12000 6900 4/22/2004 10:25 1112 1005 9535-01-001-SC-057 5460 12000 6280 4/22/2004 10:33 1112 1005 9535-01-001-SC-058 7160 12000 7690 4122/2004 9:26 1109 1009 9535-01-001-SC-059 5460 12000 6880 4122/2004 11:06 1112 1005 9535-01-001-SC-060 7160 12000 6850 4122/2004 9:34 1109 1009 9535-01-001-SC-061 5460 12000 6980 4/22/2004 10:43 1112 1005 9535-01-001-SC-062 7160 12000 7970 412212004 9:44 1109 1009 9535-01-001-SC-063 5460 12000 6470 4122/2004 10:49 1112 1005 9535-01-001-SC-064 7160 12000 6760 4/22/2004 9:49 1109 1009 9535-01-001-SC-065 5460 12000 7630 4122/2004 10:54 1112 1005 9535-01-001-SC-066 7160 12000 8330 4122/2004 9:54 1109 1009 9535-01-001-SC-067 5460 12000 7320 4/22/2004 10:59 1112 1005 9535-01-001-SC-068 7160 12000 6770 4/22/2004 9:59 1109 1009 9535-01-001-SC-069 5460 12000 7380 4122/2004 11:03 1112 1005 9535-01-001-SC-070 7160 12000 6660 412212004 10:03 1109 1009 9535-01-001-SC-071 7160 12000 6090 4122/2004 10:09 1109 1009
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD d Split Sample Assessment Forms (2 Pages)
Connecticut Yankee Decommissioning Project Health Physics Procedure 24265-000-GPR-GGGR-R5124-000 Attachment A Split Sample Assessment Form Survey Survey Survey Unit Area#:
Unit #:
0001 Name:
Southeast Landfill Sample Plan or WVPIR#: 24265-000-GEN-9535-01017-000 SML #: 9535-0001-008 Sample
Description:
Comparison of split samples collected from sample measurement location #08 and analyzed using gamma spectroscopy by an off-site vendor laboratory. The standard sample was 9535-0001 008F. the comparison sample was 9535-0001-008FS.
STANDARD COMPARI SON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (YIN)
Value Error Range Value Error Ratio Cs-137 8.49E-02 9.40E-03 9
0.6 1.66 1.72E-01 1.1 IE-02 2.03 N
K-40 1.22E+01 4.86E-01 25 0.75 1.33 1.1OE+01 4.12E-01 0.90 Y
Ra-226 4.66E-01 2.96E-02 16 0.75 1.33 4.46E-0I 3.06E-02 0.96 Y
Comments/Corrective Actions: Reported cesium-137 Table is provided to show acceptance criteria used concentrations were too low to effectively perform comparison. to assess split samples.
Performed split sample comparison using potassium-40 (K-40) and radium-226 (Ra-226). Potassium-40 and radium-226 Resolution Agreement Range comparisons satisfactory.
4 7
0.50 2.00 8
15 0.60 1.66 16 50 0.75 1.33 51 200 0.80 1.25
> 200 0.85 1.18 Performed By:
Date:
Reviewed By:
Date:
Ct
___c_
6 WNVR'-\\Vork Phnr4nd Inspection Record SML - Sample Measurement Location designation
/
Connecticut Yankee Decommissioning Project Health Physics Procedure 24265-000-GPR-GGGR-R5 124-000 Attachment A Split Sample Assessment Form Survey Survey Survey Unit Area#:
9535 Unit #:
0001 Name:
Southeast Landfill Sample Plan or WPIR#: 24265-000-GEN-9535-01017-000 SML #: 9535-0001-004 Sample
Description:
Comparison of split samples collected from sample measurement location #04 and analyzed using gamma spectroscopy by an off-site vendor laboratory. The standard sample was 9535-0001 004F, the comparison sample was 9535-0001-004FS.
STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)
Value Error Range Value Error Ratio Cs-137 9.73E-02 9.65E-03 10 0.6 1.66 9.711E-02 8.70E-03 1.00 Y
Comments/Corrective Actions: N/A Table is provided to show acceptance criteria used to assess split samples.
Resolution Agreement Range 4
7 0.50 2.00 8
15 0.60 1.66 16 50 0.75 1.33 51 200 0.80 1.25
> 200 0.85 1.18 Perforrned By:
Date:
ReviewedB Date:
q1f S
YAS21 o\\z /o WPIR - Work Plan and Inspection Record SML - Sample Measurement Location designation
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD e Preliminary Data Review Form (1 Page)
Health Physics Procedure 2426S-000-GPP-GGGR-R5123-000-Rev.CY-000 Attachment B Health Physics Procedure 24265-000-GPP-GGGR-R5 1 23-000-Rev.CY-000 Attachment B Preliminary Data Review Form - Samples for the Sign Test Survey Unit:
9535- 0001 Survey Unit Name:
Southeast Landfill Classification:
I Survey Media:
Soil Type of Survey:
Final Status Survey Type of Measurement:
Radionuclide Specific Number of Measurements:
15 Operational DCGL:
I BASIC STATISTICAL QUANTITIES Cs-137 Co-60 Minimum Value:
3.91E-02
-9.43E-03 Maximum Value:
3.13E-01 8.52E-03 Mean:
9.92E-02
-2.60E-04 Median:
8.94E-02
-6.93E-04 Standard Deviation:
6.54E-02 5.19E-03 Measurement standard deviation 2.35E-02 of the weighted sumd'):
NUMBER 9535-0001-OO1F 9535-0001 -002F 9535-0001 -003F 9535-0001-004F 9535-0001 -00SF 9535-0001-006F 9535-0001-007F 9535-0001 -008F 9535-0001-009F 9535-0001-OIOF 9535-0001-01 IF 9535-0001-012F 9535-0001-013F 9535-0001-014F 9535-0001-01SF RADIONUCLIDE CONCENTRATION (pCi/g)
Cs-137 Identified?
Co-60 Identified?
7.05E-02 Y
7.OOE-03 N
9.89E-02 Y
-6.53E-03 N
1.03E-01 Y
-6.93E-04 N
9.73E-02 Y
-4.65E-03 N
3.13E-01 Y
3.79E-03 N
1.27E-01 Y
-2.47E-03 N
8.94E-02 Y
-9.43E-03 N
8.49E-02 Y
3.29E-03 N
6.20E-02 Y
3.15E-03 N
9.29E-02 Y
-2.22E-03 N
1.38E-01 Y
8.52E-03 N
4.12E-02 Y
-6.68E-03 N
5.79E-02 Y
-1.51 E-03 N
7.26E-02 Y
2.30E-03 N
3.91 E-02 Y
2.23E-03 N
(1) MARSSIM Section I.11.3 eq. (I-17) describes the use of the measurement standard deviation of the weighted sum when measured concentrations of the various radionuclides are assumed to be uncorrelated (i.e., there is not a fixed ratio between the concentrations)
Performed By:
Independent Review:
7 Date:
Date:
- 11716P4
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD f Graphical Representation of Data (4 Pages)
I
Health Physics Procedure 24265-000-GPP-GGGR-R5123-Rev.CY-000 Attachment C Quantile Plot For Cesium - 137 Survey Unit: 9535-0001 Survey Unit Name: Southeast Landfill Mean: 9.92E-02 pCi/g 0.35* -
~0.
3 0_-
%o.25
.2 0.20 6
8 100 Prt0.15
-(%)
o0.10
00)0.05 0.00 r 0
20 40 60 80 100 Percentage (%)
Cs-1 37 Rank Percentage 3.91E-02 1
3 %
4.12E-02 2
10 %
5.79E-02 3
17 %
6.20E-02 4
23 %
7.05E-02 5
30 %
7.26E-02 6
37 %
8.49E-02 7
43 %
8.94E-02 8
50 %
9.29E-02 9
57 %
9.73E-02 10 63 %
9.89E-02 11 70 %
1.03E-01 12 77 %
1.27E-01 13 83 %
1.38E-01 14 90 %
3.13E-01 15 97 %
Prepared By:
21/,
Reviewed By Date:
Z 7
-5 Date:
2 6
Health Physics Procedure 24265-000-GPP-GGGR-R5123-Rev.CY-000 Attachment C Health Physics Procedure 24265-000-GPP-GGGR-R5 1 23-Rev.CY-000 Attachment C Quantile Plot For Cobalt - 60 Survey Unit: 9535-0001 Survey Unit Name: Southeast Landfill Mean: -2.60E-04 pCi/g 0.01 I I I
0.01 0.01 0.00
- 0. 0.00
-~*
.20.00 0.00
-2040608010 Pe0.00
~-0.01-00-0.01
-0.01 A
-0.01 0
20 40 60 80 100 Percentage (%)
Co-60 Rank Percentage
-9.43E-03 1
3 %
-6.68E-03 2
10 %
-6.53E-03 3
17 %
-4.65E-03 4
23 %
-2.47E-03 5
30 %
-2.22E-03 6
37 %
-1.51E-03 7
43 %
-6.93E-04 8
50 %
2.23E-03 9
57 %
2.30E-03 10 63 %
3.15E-03 11 70 %
3.29E-03 12 77 %
3.79E-03 13 83 %
7.OOE-03 14 90 %
8.52E-03 15 97 %
Prepared By:
Z/g Date:
Z -fi C Reviewed BDate:y Date:
a /t 7 Z; 4--
I
Health Physics Procedure 24265-000-GPP-GGGR-R5123-Rev.CY-000 Attachment C Frequency Plot For Cesium - 137 Survey Unit: 9535-0001 Survey Unit Name: Southeast Landfill Mean: 9.9188E-02 pCi/g 10-0-
r
-6 L
0.00 0.05 0.10 0.15 0.20 0.25 0.30 Upper End Value (pCilg)
Upper End Observation Observation Value Frequency Frequency 0.00 0
0%
0.05 2
13%
0.10 9
60%
0.15 3
20%
0.20 0
0%
0.25 0
0%
0.30 0
0%
0.35 1
7%
Total 15 100%
Prepared By:
6-b-
Date:
Reviewed By:
Date:
7 117/24 7//V 7
Health Physics Procedure 24265-000-GPP-GGGR-R5123-Rev.CY-000 Attachment C Frequency Plot For Cobalt - 60 Survey Unit: 9535-0001 Survey Unit Name: Southeast Landfill Mean: -2.602E-04 pCi/g 6
0-CD 2
0 0
IU p, per End Valu (pt
/
Upper End Value (pCi/g)
b Z
Q
T, Q ,
Upper End Observation Observation Value Frequency Frequency
-0.015 0
0%
-0.010 0
0%
-0.005 3
20%
0.000 5
33%
0.005 5
33%
0.010 2
13%
0.015 0
0%
0.020 0
0%
Total 15 100%
1 1---------
Prepared By:
Date:
Reviewed By:
Date:
9 b/6'
Reviewed By:
Date:
/5/-,,a 6 RYE.
LZ/
V
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD g Sign Test Calculation (1 Page)
Health Physics Procedure 24265-000-GPP-GGGR-R5121-000-Rev.CY-000 Attachment B Health Physics Procedure 24265-000-GPP-GGGR-R5 121-000-Rev.CY-000 Attachment B Sign Test Calculation Sheet For Multiple Radionuclisdes Survey Unit Number:
9535-0001 Survey Unit Name: Southeast Landfill WP&IR#: 24265-000-GEN-9535-01017-000 Classification:
I TYPE I (a error):0.05 l TYPE I(P error):0.05 l Radionuclides:
Cs-137 Co-60 Unity Survey Design DCGL (pCilg):
2.82 1.52 II1 is Results Cs-137 Results Co-60 Ws I-Ws Sign 7.05E-02 7.00E-03 2.96E-02 9.70E-01 I
9.89E-02
-6.53E-03 3.08E-02.
9.69E-01 1
1.03E-01
-6.93E-04 3.61E-02 9.64E-01 1
9.73E-02
-4.65E-03 3.14E-02 9.69E-01 I
3.13E-01 3.79E-03 1.13E-01 8.87E-01 1
1.27E-01
-2.47E-03 4.34E-02 9.57E-01 1
8.94E-02
-9.43E-03 2.55E-02 9.75E-01 1
8.49E-02 3.29E-03 3.23E-02 9.68E-01 I
6.20E-02 3.15E-03 2.41E-02 9.76E-01 1
9.29E-02
-2.22E-03 3.15E-02 9.69E-01 1
1.38E-01 8.52E-03 5.45E-02 9.45E-01 I
4.12E-02
-6.68E-03 1.02E-02 9.90E-01 1
5.79E-02
-1.51E-03 I.95E-02 9.80E-01 1
7.26E-02 2.30E-03 2.73E-02 9.73E-01 1
3.91E-02 2.23E-03 1.53E-02 9.85E-01 1
Number of Positive Differences (S+):
15 Critical Value:
11 Survey Unit:
Meets Acceptance Criterion 4, ,-f 1-5z<
Performed By:
Independent Review:
Date: Z-7-G5 Date: 2 /17 O
r --J1 Page 1 of 1
SOUTHEAST LANDFILL SURVEY UNIT 9535-0001 RELEASE RECORD h COMPASS DQA Surface Soil Report With Retrospective Power Curve (3 Pages)
DQA Surface Soil Report Assessment Summary Site:
Planner(s):
Survey Unit Name:
Report Number:
Survey Unit Samples:
Reference Area Samples:
Test Performed:
Judgmental Samples:
Assessment
Conclusion:
050207 FSS Cs 2.82 Co 1.52 Eric S Keyes SU 9535-0001 1
15 0
Sign Test Result:
0 EMC Result:
Reject Null Hypothesis (Survey Unit PASSES)
Not Performed Not Performed Retrospective Power Curve I
I I
I I
I I
I i
1 Ea 0
,- =0.8
'- 0.7 ic.
t; 0.6 W!0.5 G'
= 0.4
- E03 0.2 b0.1 X
0 I
I
.1
! 1
=
in
__--4
_--It I_
_i
__--_4 II-I_
I=
0.0 0.2 0.4 0.S 0.8 1.0 UTity Rule Swof-Ralls, inchd backgxuwid Prospectlve Power 1-beta Actual Power L8GR Estimated Power DCGL Retrospectlve Power 1.2 CCo
DQA Surface Soil Report Survey Unit Data NOTE:
Type = 'S" indicates survey unit sample.
Type = 'R" indicates reference area sample.
Sample Number 9535-0001-OOIF 9535-0001-002F 9535-0001-003F 9535-0001-004F 9535-0001-005F 9535-000I-006F 9535-0001-007F 9535-001-008F 9535-0001-009F 9535-0001-OlOF 9535-0001-01 IF 9535-0001-012F 9535-0001-013F 9535-0001414F 9535-0001-015F Type S
S S
S S
S S
S S
S S
S S
S S
Co-60 (PCl/g) 0.01
-0.01 0
0 0
0
-0.01 0
0 0
0.01
-0.01 0
0 0
Cs-137 (pCLg) 0.07 0.1 0.1 0.1 0.31 0.13 0.09 0.08 0.06 0.09 0.14 0.04 0.06 0.07 0.04 Modified Data (Unity Rule SOR)
NOTE:
Type = "S' indicates survey unit sample.
Type - "R' indicates reference area sample.
Sample Number 9535-0001-OOIF 9535-0001-002F 9535-0001-003F 9535-0001-004F 9535-0001-005F 9535-0001-006F 9535-0001-007F 9535-0001-008F 9535-0001-009F 9535-001-OIOF 95350001-01 IF 9535-0001-012F 9535-0001413F 9535-0001-014F 9535-0001-015F Type S
S S
S S
S S
S S
S S
S S
S S
Sum-of-Ratios (SOR) 0.03 0.03 0.04 0.03 0.11 0.04 0.03 0.03 0.02 0.03 0.05 0.01 0.02 0.03 0.02
/>'
Z >
AOMPASS
t1.0.0 Page 2 21712005 Page 2
I(
DQA Surface Soil Report Basic Statistical Quantities Summary Statistic Sample Number Mean (SOR)
Median (SOR)
Std Dev (SOR)
High Value (SOR)
Low Value (SOR)
/Asv vi h1AS.0.0 Survey Unit 15 0.03 0.03 0.02 0.11 0.01
Background
N/A N/A N/A N/A N/A N/A DQO Results N=15 0.08 N/A 0.04 N/A N/A 2i7fl005 Page 3 1//
2n7/2005 Page 3