ML041280125

Radioactive Effluent Release Report 2003

ML041280125
Person / Time
Site:	Crystal River
Issue date:	12/31/2003
From:	Ezell P Progress Energy Florida
To:	Office of Nuclear Reactor Regulation
Shared Package
ML041280104	List: 3F0404-07, 2003 Radioactive Effluent Release Report ML041280125 ML041280134
References
Download: ML041280125 (17)

Text

PROGRESS ENERGY FLORIDA, INC.

CRYSTAL RIVER UNIT 3 DOCKET NUMBER 50-302 / LICENSE NUMBER DPR-72 ATTACHMENT A RADIOACTIVE EFFLUENT RELEASE REPORT 2003

RADIOACTIVE EFFLUENT RELEASE REPORT 2003 PROGRESS ENERGY FLORIDA, INC.

CRYSTAL RIVER UNIT 3 Facility Operating License No. DPR-72 Docket No. 50-302 Prepared By:_ <P\tz;? (--

Sr. Environmental Specialist Approved By: _ AI UM HAjMW)

Superintendent Environmental and Chemistry Date: _12_1_IC,_ _

I.

CONTENTS I n t r o d u c t io n............................................................................................... 1 Tabular Data Summaries Gaseous Effluents - uarters 1 & 2 ......................................................... 2 Gaseous Effluents - Quarters 3 & 4 ........................................................ 4 L iquid Effluents - uarters 1 & 2 ........................................................... 6 Liquid Effluents - Quarters 3 & 4 .......................................................... 9 Radwaste Shipments ............................................................. 12 Unplanned Releases ............................................................. 13 Radioactive Waste Treatment Systems ............................................................. 13 Annual Land Use Census .................... ......................................... 13 Effluent Monitor Instrument Operability ............................................................. 13 ODCM & PCP Changes ................... .......................................... 13 Emergency Feed Pump 2 ............................................................. 13 Appendix I Dose Summary ....................... ...................................... 14

INTRODUCTION This report is submitted as required by the Offsite Dose Calculation Manual, section 6.5, and Technical Specfications 5.6.2.3.3 and 5.7.1.l.c.

The scope of this report includes:

• A sugmary of the quantities of radioactive liquid and gaseous effluents and solid waste released from the plant.

• Quarterly and annual dose summaries.

• A list and description of unplanned releases to unrestricted areas.

• A description of any changes to the:

Process Control Program (PCP), and Offsite Dose Calculation Manual (ODCM).

• Significant changes to any radioactive waste treatment system.

• A list of new dose calculation location changes identified by the annual land-use census.

• Information relating to effluent monitors or required supporting instrumentation being inoperable for 30 or more days.

1

TABLE 1 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES I Unit I Quarter I Quarter I Est. Total l 1 2 Error %

A. Fission and activation gases

1. Total release i 4.16E+oo 8.09E+00 30

2. Average release rate for period PCi/sec 5.35E-01 1.03E+O0

3. Percent of technical specification limit  % 5.30E-03 7.98E-03 B. lodines

1. Total Iodine-131 Ci 1.21E-06 5.47E-07 30j j

2. Average release rate for period j Ci/sec 1.55E-07 6.96E-08

3. Percent of technical specification limit  % 1.20E-02 8.57E-03 C. Particulates*

1. Particulates with half-lives > 8 days Ci l O.OOE+01 1.63E-07 l 30 l

2. Average release rate for period pCi/sec O.OOE+01 2.08E-08

3. Percent of technical specification limit O.OOE+01 8.57E-3

4. Gross alpha radioactivity Ci O.OOE+01 O.OOE+01 D. Tritium L. Total release Ci 5.37E01 1.23E+00 30 l

2. Average release rate for period pCi/sec 6.90E-02 1.56E-01

3. Percent of technical specification limit 1  % I 1.20E-2 8.57E-3

• The sum of the particulates reported on this page may be less than the sum from Table 2, as Table 2 includes all particulates, while this table includes only those with half-lives greater than 8 days.

2

TABLE 2 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 GASEOUS EFFLUENTS - GROUND LEVEL RELEASES CONTMIUOUS MODE BATCH MODE l Nuclides Released Unit Quarter 1 Quarter 2 Quarter I Quarter 2 A. Fission gases Argon41. Ci _ _ _ _

Krypton-85 Ci 2.37E+00 1.45E+00 Krypton-85m Ci Kryp8on-87 Ci KrM=ton-88 Ci Xenon-131m Ci 4.17E+oo 4.93E-03 1.52E-02 Xenon-133 Ci 1.30E +Oo 1.87E+00 3.52E-01 5.95E-01 Xenon-133m Ci 1.77E-03 1.61E-03 Xenon-135 Ci 1.31E-01 2.23E-04 4.23E-04 Xenon-135m Ci Xenon-138 Ci Total for period Ci 1.43E+00 6.04E+oo 2.72E+00 2.06E+00 B. Iodines Iodine-131 Ci 1.21E-06 5.47E-07 Iodine-132 Ci Iodine-133 Ci Iodine-135 Ci Total for period Ci 1.21E-06 5.47E-07 O.OOE+00 O.OOE+00 C. Particulates Zinc-72 Ci Cobalt-S8* Ci Cobalt 60* Ci Surontium-89* Ci Strondium-90* Ci Niobium-95m Ci Technicium-99m Ci Tellurium-132 Ci Cesium-134* Ci Cesium-137* Ci 9.16E-08 Cesium-138 Ci Barium-139 Ci Landwrium-142 Ci Cerium-141* Ci 7.17E-08 Cerium-144* Ci Rhenium-188 Ci Total for period Ci O.OOE+00 1.63E-07 O.OOE+00 O.OOE+00

• > 8 day half-life 3

TABLE 3 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES I Unit I Quarter I Quarter I Est. Total l 3 4 Error %

A. Fission and activation gases

1. Total release Ci 8.24E+01 6.88E+01 i 30il

2. Average release rate for period #Ci/sec 1.04E+01 8.65E+OO

3. Percent of technical specification limit  % 1.16E-01 6.59E-02 B. lodines

1. Total Iodine-131 l _Ci l O.OOE+OO 2.20E-05 lI30i l

2. Average release rate for period -Cisec O.OOE+OO 2.76E-06

3. Percent of technical specification limit  % O.OOE+OO 1.98E-O1 C. Particulates*

1. Particulates with half-lives > 8 days Ci 2.66E-10 5.94E-8 30l

2. Average release rate for period ACi/sec 3.34E-11 7.48E-09

3. Percent of technical specification limit  % 5.71E-03 1.98E-O1

4. Gross alpha radioactivity Ci 2.05E-08 O.OOE+OO D. Tritium

1. Total release Ci 1.78E+00 3.72E+00

2. Average release rate for period 5 iCi/sec 2.24E-01 4.68E-01

3. Percent of technical specification limit I.71E-03 I 1.98E-01

• The sum of the particulates reported on this page may be less than the sum from Table 4, as Table 4 includes all particulates. while this table includes only those with half-lives greater than 8 days.

4

TABLE 4 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 GASEOUS EFFLUENTS - GROUND LEVEL RELEASES CONTIUOUS MODE BATCH MODE Nucides Released Unit l Quar 3 l Quater 4 l Quater 3 l Quter 4 A. Fission gases Argon-41 Ci Krypton-85 Ci 6.37E+01 2.S1E1+00 1.13E+O1 Krypton-8Sm Ci 1.91E-03 1.43E-03 Krypton-87 Ci Krypton-88 Ci 1.81E-03 Xenon-131m Ci 2.17E+00 8.91E-02 5.71E-O1 Xenon-133 Ci 1.31E+00 4.65E+01 1.24E+01 9.47E+OO Xenon-133m Ci 6.71E-01 1.77E-01 9.14E-03 Xenon-135 Ci 2.21E-01 1.07E-01 9.1OE-02 Xenon-135m Ci Xenon-138 Ci Total for period Ci 6.71E+01 4.74E+O1 1.53E+01 2.14E+01 B. lodines Iodine-131 Ci 2.14E-05 5.74E4-07 Iodine-132 Ci Iodine-133 Ci 2.00E-07 Iodine-135 Ci _

Total for period Ci O.OOE+OO 2.14E-O5 O.OOE+OO 7.74E-07 C. Particulates Zinc-72 Ci Cobalt-57* Ci 5.94E-08 2.66E-10 Chromium-51* Ci .

Strontium-89* Ci Strontium-90* Ci Niobium-95m Ci Tin-113* Ci Indium-113m Ci Barium-133m Ci Cesium-137* Ci Cesium-138 Ci Barium-139 Ci _ _ _

Lanthanum-142 Ci Cerium-141 Ci Cerium-143 Ci Cerium-144* Ci Rhenium-188 Ci Total for period Ci O.OOE+OO S.940E-08 2.66E-10 O.OOE+OO

• > 8 day half-life 5

TABLE 5 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 LIQUID) EFFLUENTS - SUMMATION OF ALL RELEASES I Unit I Quarter I Quarter Est. Total 1 2 l Error%

A. Fission and activation products L Total release (not including tritium, gases, alpha) Ci 9.88E204 I.2E-021

2. Average diluted concentration during period jCi/ml 1.74E-12 2.56E-11

3. Percent of applicable linit  % 5.68E-04 4.22E-04 B. Tritum

1. Total release Ci 2.04E+02 3.13E+02 l 30

2. Average diluted concentration during period l Cilml 3.59E-07 5.27E-07

3. Percent of applicable limit  % 2.93E-02 4.61E-02 C. Dissolved and entrained gases

1. Total release Ci 1.25E-02 2.81E-02 21

2. Average diluted concentration during period 1Ci/ml 2.20E-11 4.73E-ll

3. Percent of applicable limit 1.87E-04 4.56E-04 D. Gross alpha radioactivity

1. Total release Ci 1.86E-0 l 6.62E-0 l 30 E. Volume of waste released (prior to dilution)

1. Batch and continuous modes Liters 6.75E+06 6.31E+06 l 10: l F. Volume of dilution water used during period

1. Batch and continuous modes Liters 5.67E+11 5.94E+11 10 6

TABLE 6 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Fission and activation products Unit Quarter 1 Quarter 2 Quarter 1 Quarter 2 Sodium-24 Ci Chromium-Sl Ci 7.90E-06 Manganese-54 Ci 1.79E-04 Manganese-56 Ci Iron-55 Ci 2.61E-04 3.08E-04 Iron-59 Ci Cobalt-S7 = Ci =

Cobalt-58 Ci 5.96E-07 1.43E-05 Cobalt___ Ci 1.93E-04 2.44E-03 ZinC-72 C Strontium-85 Ci Stroninum-89 Ci Stroniium-90 Ci Yttrium-91m Ci Yttrium-92 Ci Ytrium-93 Ci Niobium-95 Ci S.39E406 Niobium-95m Ci Nibimum-97 Ci Zirconium-9S Ci Zirconium-97 Ci Molybdinum-99 Ci Teehneiium-99m Ci 2.37E_6 Technetium-101 Ci Ruthenium-103 Ci Ruthenium-106 Ci Silver-11l0m Ci 4.1l9E-05 1.07E402 Tin-113 Ci Indium-113m Ci Animony-122 Ci 1 .33E-07 Antimony-124 Ci Antimony-12 Ci 2.68E404 1.S4E-03 Tellurium-129 Ci Tellurium-132 Ci Iodine-131 Ci 1.62E46 1 .61E-06 Iodine-133 Ci 1 .39E46 7.24E-07 Iodine-135 Ci Cesium-134 Ci 3.14E-06 9.01E-07 Cesium-137 Ci 2.02E-04 2.63E-05 Cesium-138 Ci Barium-139 Ci 5.14E-06 9.63E_06 Barium-140 Ci Lanthanum-140 Ci Cerium-143 Ci Cerium-144 Ci Neodymium-147 Ci 1.OSE-06 Tungsten-187 Ci Nepmnium--239 Ci Total for period Ci O.OOE+OO 0.00+00 9.88E-04 1.52E-02 7

TABLE 6 (CONTINUED)

EFFLUENT AND WASTE DISPOSAL REPORT - 2003 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Dissolved and entrained gases Unit Quarter I Quarter 2 Quarter I Quarter 2 Argon-41 Ci Krypton-85 Ci 4.61E-03 1.87E-03 Krypion-85m Ci Krypton-87 Ci Krypton-88 Ci Xenon-131m Ci 5.OOE-05 5.73E-O5 Xenon-133 Ci 7.61E-03 2.S7E-02 Xenon-133m Ci 5.51E-05 9.81E-05 Xenon-135 Ci 1.99E-04 3.82E-04 Xenon-135m Ci Total for period Ci O.OOE+OO O.OOE+OO 1.25E-02 2.81E-02 Tritium Ci I O.OOE+OO I O.OOE+OO I 2.04E+02 3.13E+02 8

TABLE 7 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES Unit Quarter I Quarter I Est. Total I I l 3 4 Error %

A. Fission and activation products

1. Total release (not including tritium, gases, alpha) Ci 1.15E-02 6.1SE13 Z0Z

2. Average diluted concentration during period pCi/ml 1.84E-11 1.07E-11

3. Percent of applicable limit  % 3.32E-04 5.20E-04 B. Tritium

1. Total releasei 1.51E+02 3.28E+01 l 30

2. Average diluted concentration during period pCi/ml 2.42E-07 5.71E-07

3. Percent of applicable limit  % 3.96E-01 2.71E-01 C. Dissolved and entrained gases

1. Total release Ci 1.26E-01 8.78E-01 __1 11

2. Average diluted concentration during period j Cilml 2.02E-10 1.53E.09

3. Percent of applicable limit j 1.63E-03 1.68E-03 D. Gross alpha radioactivity

1. Total release Ci 2.27E-04 1.98E-04 30 E. Volume of waste released (prior to dilution)

1. Batch and continuous modes l Liters 7.451E+06 9.43E+06 10 F. Volume of dilution water used during period

1. Batch and continuous modes Liters 6.23E+11 5.74E+11 10 9

TABLE 8 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Fission and activation products Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Sodium-24 Ci Chromium-S1 Ci 8.70E-4S 5.28E405 Manganese-54 Ci S.SOE-06 2.53E-06 Manganese-56 Ci Iron-55 Ci 7.35E404 6.40E-04 Iron-59 Ci Cobalt-57 Ci Cobalt-58 Ci 7.79E-45 1.39E-03 Cobalt-60 Ci _ 3.92E-04 1.40E-04 Zinc-69 Ci _ _ _ _

Zinc-72 Ci Strontium-85 Ci Strodium-89 Ci Strontium-90 Ci Strontium-92 Ci _ _ _ = =_ _

Yttrium-91 Ci Yttrium-92 Ci Ytrium-93 Ci Rubidium-88 Ci Niobium-95 Ci 1.36E-06 2.83E-05 Zirconium-95 Ci S5.33E-06 1.9lE46 Zirconium-97 Ci Molybdinum-99 Ci Technetium-99m Ci 6 .43E46 Technetium-101 Ci Rutbenium-106 Ci 3 .75E_0 1.SOE4S Silver-11Om Ci 9.96E404 3.79E 04 Tin-113 Ci Ibdium-113m Ci Antimony-122 Ci Antimony-124 Ci 2.41E-06 Antimony-125 Ci 8.94E-3 3.32E-03 Tellurium-129 Ci Tellurium-132 Ci Iodine-131 Ci 2.52E-4S 6.97E-45 4.66E-45 Iodine-132 Ci _ _ _ _

Iodine-133 Ci 3.32E-45 3.15E-06 Iodine-135 Ci Cesium-134 Ci = = _ _ _ 2.99E-07 3.74E-06 Cesium-136 Ci Cesium-137 Ci 1.66E-OS 2.89E-4S Barium-133m Ci 3.53E-05 Barium-139 Ci 3.26E-4S 4.09E-05 Barium-140 Ci Lantbanum-140 Ci Cerium-141 Ci 1.54E-OS 2.63E-47 Cerium-144 Ci Praseodymium-144 Ci Neodymium-147 Ci Rhenium-188 Ci Total for period Ci O.OOE+OO 2.52E-05 1.15E-02 6.13E-03 10

TABLE 8 (CONTINUED)

EFFLUENT AND WASTE DISPOSAL REPORT - 2003 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Dissolved and entrained gases Unit Quarter 3 Quarter 4 Quarter 3 Quarter 4 Argon-41 Ci Krypton-85 Ci 1.ISE-02 7.21E-03 7.84E02 Krypton-85m Ci 2.23E-06 1.66E-07 Krypton-7 Ci 1.93E-05 Krypton-88 Ci Xenon-131m Ci 2.08E-43 2.34E-02 Xenon-133 Ci I .14E-41 7.58E-01 Xenon-133m Ci 1.05E43 5.49E-03 Xenon-135 Ci . 1.61E-03 9.72E-04 Xenon-135m Ci Total for period Ci O.OOE+00 1.15E-42 1.26E4-1 8.66E401 Tritium Ci O.OOE+00 2.05E-42 1.51E+02 3.28E+01 11

TABLE 9 EFFLUENT AND WASTE DISPOSAL REPORT - 2003 SOLID WASTE AND IRRADIATED FUEL SHIPMENTS A. SOLID WASTE SHIPPED OFFSITE FOR PROCESSING OR BURIAL (Non-irradiated fuel)

1. Type of waste Unit 12 month period Est. Total Error %

a. Spent resins, filter sludges, evaporator bottoms, etc. m3 4.63E+02 25 m3 1.63E+02 2

b. Dry compressible waste, contaminated equipment, etc. Ci32.98E+02 25

c. Irradiated components, control rods, etc. m3C 0.0E++00 25 m3 5.83E+00 25

d. Other (describe): Liquid Radwaste Resins Ci 6.99E+00

2. Estimate of major nuclide composition (by type of waste in %)=

Ni-63 24.4 Cs-134 16.2

a. Cs-137 26.9 Fe-55 16.9 Co-60 13.6 Fe-S5 23.5 Cs-137 15.1 Cs-134 3.5

b. Ni-63 11.6 Sb-125 4.9 H-3 4.1 Co-60 21.4 Ag-1O1m 10.5 c.

Fe-55 31.8 Ni-63 34.9

d. Co-60 8.5 Cs-134 7.8 Cs-137 10.7 Sb-125 3.0

- Curie values and principle radionuclides are estimates based on a combination or direct anm inurect metods.

3. Solid Waste Disposition Number of Shipments Mode of Transportation

• Destination 1 Hittman Barnwell Waste Mngmt (SC) 4 Hittman Duratek (TN) 1 Tri-State Motor Transit Duratek (TN) 2 Southern Pines Trucking Envirocare (UT) 1 Hittman Studsvik Processing Facility CN) 1 TAG Transport Studsvik Processing Facility (TN)

• All exclusive use trucks B. IRRADIATED FUEL SHIPMENTS (Disposition)

Number of Shipments Mode of Transportation Destination 0 NIA N/A 12

Unplanned Releases There were no unplanned releases in 2003.

Radioactive Waste Treatment Systems There were no significant changes to the radioactive waste treatment systems.

Annual Land Use Census The 2003 land-use census did not identify any new dose calculation locations.

Effluent Monitor Instrumnent Operability Required effluent monitor instrumentation was not out of service for more than 30 days during 2003.

ODCM & PCP Changes The ODCM was revised during 2003. The primary reason for the change was to make the ODCM consistent with ITS in regards to operability of RM-Al (containment purge effluent monitor). A complete copy of the ODCM is being submitted with this report.

The PCP was not revised during 2003.

Emergency Feed Pump 2 Emergency Feed Pump 2 (EFP-2) overspeed testing is performed quarterly using steam from CR-3's steam generators. Due to a small primary to secondary leak, an evaluation was performed to estimate the quantity of radioactive material which was released during 2003 due to operation of this pump. The results of this evaluation are given below in units of Curies/year.

Xe-133 9.OOE-07 I-131 6.OOE-08 Cs-134 6.OOE-08 Xe-135 3.00E07 1-133 9.OOE-08 Cs-137 3.00e-08 H-3 2.4E-06 These values are not included in Tables 1 through 4.

ErrorsIn Past Reports The ODCM previously required that 'container type' be included as part of the information compiled for solid radwaste shipments. This information was omitted in effluent reports for 1998 through 2002 (ref. NCR 100631). The following data is being submitted as supplements to those reports.

1998: Type a wastes were shipped in liners.

Type b wastes were shipped in strong tight containers.

1999: Type a wastes were shipped in liners and strong tight containers.

Type b and d wastes were shipped in strong tight containers.

2000: Type a wastes were shipped in liners and strong tight containers.

Type b, c, and d wastes were shipped in strong tight containers.

2001: Type a wastes were shipped in liners and strong tight containers.

Type b wastes were shipped in strong tight containers.

2002: Type a wastes were shipped in liners and strong tight containers.

Type b and d wastes were shipped in strong tight containers.

13

2003 Appendix I Dose Summary Maximum Hypothetical Individual Liquid Effluent Dose Limits Total Body: 1.5 mrenilquarter, 3 mrem/year Any Organ: 5 mrem/quarter, 10 mrern/year Liquid Effluent Dose Summary Quarter 1 Quarter 2 Quarter 3 Quarter 4 Annual Total Total Body Dose (rnrem) 8.51E-06 6.33E-06 4.98E-06 2.67E-06 2.25E-05 Maximum Organ Dose (mrem) 5.58E-06 3.35E-04 6.08E-05 2.60E-05 4.28E-04 Maximum Organ was GI Gaseous Effluent Dose Limits Ganmia Air Dose: 5 mrad/quarter, 10 mrad/year Beta Air Dose: 10 mrad/quarter, 20 mrad/year Any Organ: 7.5 mrem/quarter, 15 mrem/year Gaseous Release Dose Summary Quarter 1 Quarter 2 Quarter 3 Quarter 4 Annual Total Gamma Air Dose (mrad) 6.95E-05 1.23E-04 5.23E-04 1.65E-03 2.37E-03 Beta Air Dose (mrad) 5.30E-04 7.98E-04 1.16E(-02 6.60E-03 1.95E-02 Total Body Dose (mremr) 1.30E-04 3.00E-04 4.30E-04 9.12E-04 1.77E-03 Maximum Organ Dose (mrem) 8.97E-04 6.43E-04 4.28E-04 1.49E-02 1.68E-02 Maximum Organ was Thyroid 14