L-2002-056, Annual Radioactive Effluent Release Report

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Annual Radioactive Effluent Release Report
ML020860598
Person / Time
Site: Turkey Point  NextEra Energy icon.png
Issue date: 03/22/2002
From: Mcelwain J
Florida Power & Light Co
To:
Document Control Desk, Office of Nuclear Reactor Regulation
References
L-2002-056
Download: ML020860598 (52)


Text

FPL L MAR 2 2 ?0U L-2002-056 10 CFR 50.36a(a)(2)

U. S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, D.C. 20555 Re: Turkey Point Units 3 and 4 Docket Nos. 50-250 and 50-251 Annual Radioactive Effluent Release Report Attached is the Radioactive Effluent Release Report for the period of January 1, 2001, through December 31, 2001, for Turkey Point Units 3 and 4, as required by Technical Specification 6.9.1.4 and 10 CFR 50.36a (a)(2).

Should there be any questions or comments regarding this information, please contact Walter Parker at (305) 246-6632.

Very truly yours,

ýJohnP.M lwi Vice President Turkey Point Plant JPM/DRL Attachment cc: NRC Regulatory Issue Summary 2001-05 waived the requirements that multiple copies of documents be submitted to the NRC.

an FPL Group company

TURKEY POINT PLANT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT Executive Summary Liquid effluent releases at Turkey Point did not exceed the concentrations specified in 10 CFR 20, Appendix B, Table II, Column 2. The limits for dissolved and entrained noble gases were not exceeded.

The dose or dose commitment limits per reactor to a member of the public from liquid effluents were not exceeded.

Dose rate limits due to radioactive materials in the gaseous effluents were not exceeded.

The dose limits per reactor to a member of the public due to 1-131, 1-133, tritium, and particulates with half-lives greater than 8 days were not exceeded.

All liquid and airborne discharges to the environment were analyzed in accordance with the Technical Specifications and Regulatory Guide 1.21.

There were no unplanned liquid releases for either unit during this period.

There was one unplanned gas release reported for Unit 3 however, no limits were exceeded.

Visitor dose limits were calculated and included in this report for both adult and children at the Satellite School.

Turkey Point Plant Units 3 and 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT January 2001 through December 2001 Submitted by:

NUCLEAR CHEMISTRY DEPARTMENT FLORIDA POWER AND LIGHT COMPANY G en a, Radiochemistry Supervisor Cir Connelly, hemistry Supervisor M. D. Lacal, Operations Manager T. 0. , P-lant General Manager

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 Table Of Contents 1.0 REGULATORY LIMITS .......................................................................................................... 3 2.0 EFFLUENT CONCENTRATION ................................................................................................ 4 3.0 A V ERA G E EN ER G Y ...................................................................................................................... 4 4.0 MEASUREMENTS AND APPROXIMATIONS OF TOTAL ACTIVITY ................................. 4 5.0 B A TC H RE LEA SE S........................................................................................................................ 7 6.0 UNPLANNED RELEASES ........................................................................................................ 8 7.0 REACTOR COOLANT ACTIVITY .............................................................................................. 8 8.0 SITE RADIATION DOSE ........................................................................................................ 8 9.0 OFFSITE DOSE CALCULATION MANUAL (ODCM) REVISIONS ........................................ 9 10.0 SOLID WASTE AND IRRADIATED FUEL SHIPMENTS ........................................................ 9 11.0 PROCESS CONTROL PROGRAM REVISIONS ....................................................................... 9 12.0 INOPERABLE EFFLUENT MONITORING INSTRUMENTATION ........................................ 9 UNIT 3 TABLES 1 THROUGH 5............................................................................... 10 UNIT 4 TABLES 1 THROUGH 5 ................................................................................. 15 SITE DOSE SUMMATION TABLE 5 ......................................................................... 20 SOLID WASTE AND IRRADIATED FUEL SHIPMENTS TABLE 6 .................................... 21 APPENDIX A 2

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 1.0 REGULATORY LIMITS 1.1 Liquid Effluent (a) The concentration of radioactive material released in liquid effluents to unrestricted areas shall not exceed ten times the concentration specified in 10CFR20 Appendix B, Table 2, Column 2 for radionuclides other than dissolved or entrained gases. For dissolved or entrained noble gases, the concentration shall not exceed 2.OE-04 micro-curies per milliliter total activity.

(b) The dose or dose commitment per reactor to a member of the public from any radioactive materials in liquid effluents released to unrestricted areas shall be limited as follows:

> During any calendar quarter, to less than or equal to 1.5 mrem to the total body and less than or equal to 5 mrem to any organ.

> During any calendar year, to less than or equal to 3.0 mrem to the total body and less than or equal to 10 mrem to any organ.

1.2 Gaseous Effluent (a) The dose rate due to radioactive materials released in gaseous effluent from the site to areas at and beyond the site boundary shall be limited to the following:

> Less than or equal to 500 mrem per year to the total body and less than or equal to 3000 mrem per year to the skin due to noble gases.

> Less than or equal to 1500 mrem per year to any organ due to 1-131, 1-133, tritium, and for all radioactive materials in particulate form with half-lives greater than 8 days.

(b) The air dose per reactor to areas at and beyond the site boundary due to noble gases released in gaseous effluents shall be limited to:

> During any calendar quarter, to less than or equal to 5 mrad for gamma radiation and less than or equal to 10 mrad for beta radiation.

> During any calendar year, to less than or equal to 10 mrad for gamma radiation and less than or equal to 20 mrad for beta radiation.

(c) The dose per reactor to a member of the public, due to 1-131, 1-133, tritium, and all radionuclides in particulate form with half-lives greater than 8 days in gaseous effluent released to areas at and beyond the site boundary shall not exceed 7.5 mrem to any organ during any calendar quarter and shall not exceed 15 mrem to any organ during any calendar year.

3

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 2.0 EFFLUENT CONCENTRATION Water: In accordance with 10CFR20, Appendix B, Table 2, Column 2, and for entrained or dissolved noble gases as described in 1.1 .a of this report.

Air  : Release concentrations are limited to dose rate limits described in 1.2.a of this report.

3.0 AVERAGE ENERGY The average energy of fission and activation gases in effluents is not applicable.

4.0 MEASUREMENTS AND APPROXIMATIONS OF TOTAL ACTIVITY All liquid and airborne discharges to the environment during this period were analyzed in accordance with Technical Specification requirements. The minimum frequency of analysis as required by Regulatory Guide 1.21 was met or exceeded.

When alpha, tritium and named nuclides are shown as "- -" curies on the following tables, this should be interpreted as 'no activity' was detected on the samples using the Plant Technical Specification analysis techniques to achieve the required Lower Limit of Detection ("LLD")

sensitivity for radioactive effluents.

4.1 Liquid Effluents Aliquots of representative pre-release samples, from the waste disposal system, were isotopically analyzed for gamma emitting isotopes on a multichannel analyzer.

Frequent periodic sampling and analysis were used to conservatively determine if any radioactivity was being released via the steam generator blowdown system and the storm drain system.

Monthly and quarterly composite samples for the waste disposal system were prepared to give proportional weight to each liquid release made during the designated period of accumulation.

The monthly composite was analyzed for tritium and gross alpha radioactivity. Tritium was determined by use of liquid scintillation techniques, and gross alpha radioactivity was determined by use of a solid state scintillation system. The quarterly composite was analyzed for Sr-89, Sr-90, Ni-63, and Fe-55 by chemical separation.

4

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 All radioactivity concentrations determined from sample analysis of a pre-release composite were multiplied by the total represented volume of the liquid waste released to determine the total quantity of each isotope and of gross alpha activity released during the compositing period.

Aliquots of representative samples from the waste disposal system were analyzed on a pre release basis by gamma spectrum analysis. The resulting isotope concentrations were multiplied by the total volume released in order to estimate the total dissolved gases released.

The liquid waste treatment system is shared by both units at the site and generally all liquid releases are allocated on a 50/50 basis to each unit respectively.

There were no continuous liquid effluent releases above the lower limit of detection for either Unit 3 or Unit 4 during this reporting period and therefore these have been omitted from Table 2 of this report.

5

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 4.2 Gaseous Effluents Airborne releases to the atmosphere occurred from the following sources:

- Gas Decay Tanks

- Containment Purges

- Releases incidental to operation of the plant.

The techniques employed in determining the radioactivity in airborne releases are:

a) Gamma spectrum analysis for fission and activation gases, b) Removal of particulate material by filtration and subsequent gamma spectrum analysis, Sr 89, Sr-90 determination, and gross alpha determination, c) Absorption of halogen radionuclides on a charcoal filter and subsequent gamma spectral analysis, and d) Analysis of water vapor in a gas sample for tritium using liquid scintillation techniques.

All gaseous releases from the plant which were not accounted for by the above methods were conservatively estimated as curies of Xe- 133 by use of the SPING-4 radiation monitors and the Plant Vent process monitor recorder chart using the current calibration curve for that process monitor.

Both units share portions of the gaseous waste treatment system and generally all gaseous releases from the shared system are allocated on a 50/50 basis to each unit.

Meteorological data for the period January 2001 through December 2001, in the form of Joint Frequency Distribution Tables, are maintained on site.

6

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 4.3 Estimation of Errors a) Sampling Error The error associated with volume measurement devices, flow measuring devices, etc.,

based on calibration data and design tolerances has been conservatively estimated to be collectively less than +/- 10%.

b) Analytical Error Our quarterly Q.C. Cross-Check Program involves counting unknown samples provided by an independent external lab. The errors associated with our analysis of these unknown samples, reported to us by the independent lab, were used as the basis for deriving the following analytical error terms:

NUCLIDE TYPE AVERAGE ERROR MAXIMUM ERROR Liquid

  • 5.9% :1 11.0%

Gaseous + 2.7% 4- 11.0%

5.0 BATCH RELEASES 5.1 LIQUID Unit 3 Unit 4 a) Number of releases 9.OOE+01 9.OOE+01 b) Total time period of batch releases, minutes 8.70E+03 8.70E+03 c) Maximum time period for a batch release, minutes 1.35E+02 1.35E+02 d) Average time period for a batch release, minutes 9.67E+01 9.67E+01 e) Minimum time for a batch release, minutes 4.50E+01 4.50E+01 f) Average stream flow during period of release of effluent into a flowing stream, liters-per-minute 5.91E+06 5.91E+06 5.1 GASEOUS Unit 3 Unit 4 a) Number of releases 1.80E+01 1.80E+01 b) Total time period of batch releases, minutes 6.60E+02 6.60E+02 c) Maximum time period for a batch release, minutes 1.89E+01 1.89E+01 d) Average time period for a batch release, minutes 3.80E+01 3.80E+01 e) Minimum time for a batch release, minutes 1.50E+01 1.50E+01 7

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 6.0 UNPLANNED RELEASES 6.1 Liqui There were no unplanned liquid releases this period for either Unit 3 or Unit 4.

6.2 Gaseous There was one unplanned released during this reporting period. On 10/19/2001 The "C" Gas Decay Tank (GDT) was released through the Unit 3 Reactor Coolant Drain Tank (RCDT) into the containment building. The "C" GDT was sampled, a permit was prepared and no limits were exceeded.

7.0 REACTOR COOLANT ACTIVITY 7.1 Unit3 Reactor coolant activity limits of 100/E-Bar and 1.0 uCi/gram Dose Equivalent 1-131 were not exceeded.

7.2 Unit 4 Reactor coolant activity limits of 100/E-Bar and 1.0 uCi/gram Dose Equivalent 1-131 were not exceeded.

8.0 SITE RADIATION DOSE The assessment of radiation dose from radioactive effluents to the general public due to their activities inside the site boundary assumes a visitor was at the child development center/fitness center for ten hours a day, five days each week for fifty weeks of the year, receiving exposure from both Unit 3 and Unit 4 at Turkey Point. The child development center/fitness center is located approximately 1.75 miles WNW of the plant. Specific activities used in these calculations are the sum of the activities listed in Unit 3 Table 3 and Unit 4 Table 3. The following dose calculations were made using historical, meteorological data:

11 Adult Inhalation Child Inhalation Bone (mrem) 1.45E-10 2.61E-10 Liver (mrem) 2.85E-06 2.OOE-06 Thyroid (mrem) 2.92E-06 2.09E-06 Kidney (mrem) 2.85E-06 1.32E-06 Lung (mrem) 2.85E1-06 2.00E-06 GI-LLI (mrem) 2.85E1-06 2.00E-06 Total Body (mrem) 2.85E-06 2.OOE-06 Gamma Air Dose (mrad) 2.58E-06 Beta Air Dose (mrad) 5.24E-06 8

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 9.0 OFFSITE DOSE CALCULATION MANUAL (ODCM) REVISIONS The ODCM was revised once during this reporting period. The changes are included in Appendix A.

10.0 SOLID WASTE AND IRRADIATED FUEL SHIPMENTS No irradiated fuel shipments were made from the site. Common solid waste from Turkey Point Units 3 and 4 was shipped jointly. A summation of these shipments is given in Table 6 of this report.

11.0 PROCESS CONTROL PROGRAM REVISIONS There were no revisions to the process control program during this reporting period 12.0 INOPERABLE EFFLUENT MONITORING INSTRUMENTATION There was no inoperable effluent monitoring instrumentation requiring reportability during this period.

9

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 LIQUID EFFLUENTS

SUMMARY

UNIT 3i TABLE I A. FISSION AND ACTIVATION PRODUCTS I UNITS Qtr I I Qtr2 I Qtr3 I Qtr4 Est. Error (%)

1. Total Release (not including tritium,gases, alpha)

.Average diluted concentration during the period I UNITS Ci uCi/ml 1.

7.66E-04 1.10E-1 0 2.57E-03 4.72E-10 1.37E-02 5.35E-10 2.63E-02 1.g5E-09 9.08E-02 3.44 3Percent of applicable limit  % 1 .04E-02 I 3.17E-02 2.65E-02 I I 1 04E-02 B. TRITIUM UNITS Otr 1 1 Qtr2 I Qtr3 1 Qtr 4 Est. Error (%)

Ci 1.18E+02 I 1.34E+02 2.62E+02 6.34E+01 2.50

1. Total Release ci V Average diluted concentration during the period uCi/ml 1.70E-05 I 2.45E-05 1.03E-05 4.70E-06 limit  % 1.70E+00 2.45E+00 1.03E+00 4.70E-01

.Percent of applicable

~~~ I 1 70E+00  ::; : ; ; :; . .. .

.. i i¸ [ [ I i~~~ . . .I=I I I C. DISSOLVED AND ENTRAINED GASES UNITS Qtr I 1 Qtr2 I Qtr3 Qtr 4 Est. Error (%)

Ci 1.89E-05 0.00E+00 3.63E-04 1.16E-04 3.44 III ci I I 1.Averane diluted concentration during the period Total Release uCi/mI 2.72E-12 I 0.00E+00 1.42E-11 8.58E-12 Percent of applicable limit  % 1.36E-06 0.00E+00 7.1OE-06 4.29E-06 D. GROSS ALPHA RADIOACTIVITY I UNITS Qtr 1 I Qtr2 I Qtr3 I Qtr4 I Est. Error (%) I

11. Total Release ci -" "- -- -

E. LIQUID VOLUMES UNITS Qtr I Qtr 2 Qtr 3 Qtr 4 Est. Error (%)

1 -Batch waste released, prior to dilution LITERS 2.94E+05 2.90E+05 1.04E+06 6.43E+05 10.00

2. Continuous waste released, prior to dilution LITERS - I -
3. Dilution water used during period LITERS 6.95E+09 5.45E+09 2.56E+10 1.35E+10 I 10

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 LIQUID EFFLUENTS

SUMMARY

UNIT 3 TABLE 2 NUCLIDES UNITS BATCH MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Fe-55 Ci 2.85E-04 1.23E-04 4.17E-04 2.13E-03 Ni-63 Ci - - 3.31 E-04 5.06E-03 1.78E-02 Sr-89 Ci ..-.-...

Sr-90 Ci ........

Na-24 Ci ........

Cr-51 Ci - - 1.68E-05 1.26E-04 1.47E-05 Mn-54 Ci 8.75E-07 1.01 E-06 1.73E-04 6.46E-04 Co-57 Ci ..-- 4.47E-06 3.66E-05 Co-58 Ci 1.43E-04 1.44E-04 3.43E-04 1.33E-03 Fe-59 Ci -.-.....

Co-60 Ci 1.01 E-04 2.48E-04 7.86E-04 1.84E-03 Zn-65 Ci ........

Nb-95 Ci 2.38E-06 1.35E-06 - - 2.04E-06

_r-9 5 Ci . .. .. .. .

Mo-99 Ci ........

Ru-1 06 Ci ........

,g-1 10 Ci 2.04E-05 9.37E-05 5.59E-05 2.14E-05 Sn-113 Ci ........

Sn-i 17 Ci ...... 8.43E-06 Sb-1 24 Ci - - 2.02E-06 8.OOE-06 1.57E-06 Sb-125 Ci 1.94E-04 1.60E-03 6.59E-03 2.19E-03 1-13 1 Ci . .. .. .. .

1-133 Ci ........

1-134 Ci .... 7.15E-07 8.05E-07 Cs-1 34 Ci ... 1.1 4E-05 3.90E-06 1-135 Ci . .. .. .. .

Cs-i 37 Ci I..85E-05 9.36E-06 9.52E-05 2.42E-04 La-140 Ci ........

Ce-141 Ci ........

Ce-144 Ci ........

W -187 Ci ........

Np-239 Ci ........

TOTAL FOR PERIOD ] Ci ] 7.66E-04 [ 2.57E-03 1.37E-02 I 2.63E-02 LIQUID EFFLUENTS - DISSOLVED GAS

SUMMARY

NUCLIDES UNITS BATCH MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4

,r-4 1 Ci . .. .. .. .

Kr-85m Ci ........

Kr-85 Ci .... 1.46E-04 -

Xe-133 Ci 1.89E-05 -- 2.17E-04 1.16E-04 Xe-i 33m Ci ........

Xe-135 Ci ........

Xe-138 Ci ........

TOTAL FOR PERIOD Ci [ 1.89E-05 ] 0.OOE+00 [ 3.63E-04 11.16E-04 LIQUID EFFLUENTS - DOSE SUMMATION ge group: Teenager ocation : Cooling Canal Shoreline Deposition Dose (mrem)  % of Annual Limit TOTAL BODY 1.84E-04 6.13E-03 11

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 GASEOUS EFFLUENTS

SUMMARY

UNIT 3 TABLE 3 A. FISSION AND ACTIVATION PRODUCTS UNITS Qtr 1 Qtr 2 Qtr 3 Qtr 4 Est. Error (%)

91

1. Total Release Ci 1.86E-01 3.64E-02 2.10E-01 I 1.16E-01 2.79 12.Averaae release rate for the Deriod uCi/sec 2.40E-02 4.63E-03 2.64E-02 1.50E-02 *i!

iii'iii~iiii~

ii~iiiii~

iiiiiiiiiiiiiii II 1..... ... . .re ..e s.. . . f. . the

. r. .. .. . . .

3. Percent of Technical Secification Limit  % 3.1OE-13 2.96E-14 9.82E-12 3.81 E-13 B. IODINES I UNITS Qtr 1 Qtr 2 Qtr 3 Qtr 4 Est. Errora% I
1. Total Release Ci .... - .... 3.44
2. Average release rate for the period uCi/sec -------
3. Percent of Technical Specification Limit  %, -........

C. PARTICULATES UNITS Qtr 1 Qtr 2 Qtr 3 Qtr 4 Est. Error %

1. Particulates with half-life >8 days Ci ........ 2.50
2. Average release rate for the period uCi/sec ........
3. Percent of Technical Specification Limit 0% ........
4. Gross Alpha Radioactivity Ci ........

D. TRITIUM I UNITS Qtr I Qtr 2 Qtr 3 Qtr 4 Est. Error (%)

1. Total Release Ci .... 2.61 E-01 7.28E-01 2.50
2. Average release rate for the period uCi/sec .... 3.28E-02 9.36E-02!
3. Percent of Technical Specification Limit  % .... 1.96E-06 5.47E-06 12

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 GASEOUS EFFLUENTS

SUMMARY

UNIT 3 TABLE 4 A. FISSION GASES NUCLIDES UNITS BATCH MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4

,r-41 Ci .... 7.29E-02 -

Kr-85 Ci 1.24E-01 3.20E-02 7.OOE-02 3.33E-02 Kr-85m Ci 1.44E-05 - - 750E-05 -

Ke-1 31 m Ci 5.51 E-04 - - 7.97E-05 5.80E-04 Xe-133 Ci 6.05E-02 4.29E-03 6.49E-02 8.11E-02 Xe-1 33m Ci 5.37E-04 4.25E-05 5.28E-04 1.07E-03 Xe-135 Ci 6.27E-04 1.29E-04 1.26E-03 -

tOTAL FOR PERIOD I Ci ] 1.86E-01 I 3.64E-02 ] 2.10E-01 1.16E-01 NUCLIDES UNITS CONTINUOUS MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 A r-41 Ci ........

Kr-85 Ci ........

Kr-85m Ci ........

Kr-87 Ci ........

Kr-88 Ci ........

Xe-131 m Ci ........

Xe-133 Ci ........

Xe-1 33m Ci ........

Xe-135 Ci ........

Xe-135m Ci ........

Xe-138 Ci ........

TOTAL FOR PERIOD [ Ci -- . -- I -- I -

B. IODINES NUCLIDES UNITS CONTINUOUS MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Br-82 Ci ....

1-131 Ci ...... 2.13E-06 1-133 ci ... .. .. .

TOTAL FOR PERIOD Ci I -- -- - I 2.13E-06 C. PARTICULATES NUCLIDES UNITS CONTINUOUS MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Co-58 Ci ........

Co-60 Ci ........

Mn-54 Ci ........

C r-51 Ci ........

[rOTAL FOR PERIOD Ci I -- -- I -- -

13

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 DOSES DUE TO IODINE, TRITIUM, AND PARTICULATES ITABLE 51 PATHWAY BONE LIVER THYROID KIDNEY LUNG G.-LLI SKIN TOTAL BODY l ow milk - Infant (mrem) 8.77E-08 7.53E-06 4.11 E-05 3.29E-06 7.43E-06 7.43E-06 -- 7.49E-06 l=ruit &Veg Fresh (torero) 4.20E-09 7.79E-07 2.17E-06 5.14E-07 7.74E-07 7.75E-07 -- 7.78E-07

! round Plane (mrem) 5.83E-10 5.83E-10 5.83E-10 5.83E-10 5.83E-10 5.83E-10 7.08E-10 5.83E-10 inhalation - Adult (mrem) 1.70E-10 3.35E-06 3.43E-06 3.36E-06 3.35E-06 3.35E-06 -- 3.35E-06 TOTAL (mrem) 9.27E-08 1.17E-05 4.67E-05 7.16E-06 1.16E-05 1.16E-05 708E-1 0 1.16E-05

% of Annual Limit I 6.18E-07 7.78E-05 3.11E-04 4.77E-05 7.71E-05 7.71E-05 4.72E-09 7.75E-05 DOSE DUE TO NOBLE GASES I mrad %of Anual Limit Gamma Air Dose 1.38E-05 I 1.38E-04 Beta Air Dose 1.78E-05 8.89E-05 14

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 LIQUID EFFLUENTS

SUMMARY

UNIT4 TABLE 1 A. FISSION AND ACTIVATION PRODUCTS IUNITS Qtrl1 Qtr 2 Qtr33 Qtr4 Est. Error (%)

UNITS Qtr 1 Qtr 2 2.63E-02

1. Total Release (not including tritium,gases, alpha) Ci 7.66E-04 2.57E-03 1.37E-02 uCi/ml 1.10E-10 4.72E-1 0 5.35E-1 0 1.95E-09

. Average diluted concentration during the period SI I I 3.Percent of applicable limit  % 1.04E-02 3.17E-02 2.65E-02 9.08E-02 B. TRITIUM UNITS I Qtr 1 Qtr 2 Qtr3 I Qtr 4 Est. Error(%

Qtr I I1.Total Release Ci 1.18E+02 1.34E+02 2.62E+02 6.34E+01 2.50 1 .70E-05

". Average diluted concentration during the period uCi/ml 170E-05 2.45E-05 1.03E-05 4.70E-06

3. Percent of applicable limit

% 1.70E+00 2.45E+00 1.03E+00 4.70E-01 ----

C. DISSOLVED AND ENTRAINED GASES IUNITS Otri1 I Qtr 2 Qtr3 I Qtr 4 Est. Error (%)

UNITS Qtr 1 I.Total Release Ci 1.89E-05 3.63E-04 1.16E-04 3.44

. Average diluted concentration during the period Iu . Ci/mi 2.72E-12I 1.42E-11 8.58E-1 2

. .. . I . .. .- I I 3.Percent of apolicable limit  % 1.36E-06 7.1OE-06 4.29E-06 D. GROSS ALPHA RADIOACTIVITY t UNITS QOtr1 I Qtr2 Qtr3 I Qtr4 I Est. Error (%) I 11.Total Release Ci - - - - - 51-E. LIQUID VOLUMES I Qtr I Qtr2 I Qtr 3 Qtr 4 Est. Error (%)

1.Batch waste released, prior to dilution LITERS 2.94E+05 2.90E+05 1.04E+06 6.43E+05 10.00 Ii

2. Continuous waste released, prior to dilution LITERS .E...E.E 2.56E+10 1.35E+10
3. Dilution water used during period LITERS 6.95E+09 5.45E+09 15

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 LIQUID EFFLUENTS

SUMMARY

UNIT 4 TABLE 2 NUCLIDES UNITS BATCH MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Fe-55 Ci 2.85E-04 1.23E-04 4.17E-04 2.13E-03 Ni-63 Ci - - 3.31 E-04 5.06E-03 1.78E-02 Sr-89 Ci ....-.-.

Sr-90 Ci ........

Na-24 Ci ........

Cr-51 Ci -- 1.68E-05 1.26E-04 1.47E-05 Mn-54 Ci 8.75E-07 1.01 E-06 1.73E-04 6.46E-04 Co-57 Ci ..-- 4.47E-06 3.66E-05 Co-58 Ci 1.43E-04 1.44E-04 3.43E-04 1.33E-03 Fe-59 Ci --......

Co-60 Ci 1.01 E-04 2.48E-04 7.86E-04 1.84E-03 7n-65 Ci --......

Nb-95 Ci 2.38E-06 1.35E-06 - - 2.04E-06 Zr-95 Ci ........

Mo-99 Ci ........

Ru-1 06 Ci ........

,g-1 10 Ci 2.04E-05 9.37E-05 5.59E-05 2.14E-05 Sn-113 Ci ........

Sn-117 Ci .. -.. 8.43E-06 Sb-i 24 Ci - - 2.02E-06 8.OOE-06 1.57E-06 Sb-125 Ci 1.94E-04 1.60E-03 6.59E-03 2.19E-03 1-131 Ci ........

1-133 Ci ........

1-134 Ci .... 7.15E-07 8.05E-07 Cs-134 Ci .... 1.14E-05 3.90E-06 1-135 Ci ........

Cs-1 37 Ci 1.85E-05 9.36E-06 9.52E-05 2.42E-04 La-140 Ci ........

Ce-141 Ci ........

Ce-144 Ci ........

W-187 Ci ........

Np-239 Ci ........

OAL FORPERIOD ICi 7.66E-04 2.57E-03 1 1.37E-02 3 2.63E-02 LIQUID EFFLUENTS - DISSOLVED GAS

SUMMARY

NUCLIDES UNITS BATCH MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4

,r-41 Ci ........

Kr-85m Ci ........

Kr-85 Ci .... 1.46E-04 -

Xe-131 m Ci ........

Xe-133 Ci 1.89E-05 - - 2.17E-04 1.16E-04 Xe-133m Ci ........

Xe-135 Ci ........

Xe-138 Ci ........

"TOTAL FOR PERIOD Ci i 1.89E-05 3 -" I 3.63E-04 1.16E-04 LIQUID EFFLUENTS - DOSE SUMMATION e group: Teenager ocation : Cooling Canal khoreline Deposition Dose (mrem)  % of Annual Limit

ýTOTAL BODY 1.84E-04 6.13E-03 16

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 GASEOUS EFFLUENTS

SUMMARY

UNIT 4i TABLE 3 A. FISSION AND ACTIVATION PRODUCTS I UNITS Qtr 1 Qtr 2 Qtr 3 Qtr 4 Est. Error %

. Total Release Ci 1.91 E-01 3.64E-02 1.14E-01 1.16E-01 2.79

2. Average release rate for the period uCi/sec 2.46E-02 4.63E-03 1.44E-02 1.50E-02
3. Percent of Technical Specification Limit  % 3.31 E-1 3 2.96E-1 4 2.61 E-1 3 3.81 E-1 3 B. IODINES I UNITS I Qtr1 Qtr2 Qtr3 I Qtr4 1 Est. Error(%) %
1. Total Release
2. Average release rate for the period
3. Percent of Technical Specification Limit Ci uCi/sec 3.44 I L

C. PARTICULATES I UNITS I Qtrl Qtr2 Qtr3 Qtr4 Est. Error %

1. Particulates with half-life >8 days Ci ........ 2.50
2. Average release rate for the period uCi/sec -------
3. Percent of Technical Specification Limit  %-........
4. Gross Alpha Radioactivity Ci ........ i D. TRITIUM UNITS Qtr I Qtr 2 Qtr 3 Qtr 4 Est. Error (%)
1. Total Release ci ........ 2.50
2. Average release rate for the period uCi/sec ........
3. Percent of Technical Specification Limit  %-........

17

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 GASEOUS EFFLUENTS

SUMMARY

UNIT 4 TABLE 4 A. FISSION GASES NUCLIDES UNITS BATCH MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Ar-41 Ci .... 6.93E-05 -

Kr-85 Ci 1.24E-01 3.20E-02 7.OOE-02 3.33E-02 Kr-85m Ci 1.44E-05 - - 7.50E-05 -

Xe-1 31 m Ci 5.51 E-04 - - 3.38E-04 5.80E-04 Xe-133 Ci 6.53E-02 4.29E-03 4.18E-02 8.11 E-02 Xe-1 33m Ci 5.37E-04 4.25E-05 5.28E-04 1.07E-03 Xe-1 35 Ci 6.27E-04 1.29E-04 1.26E-03 -

Xe-1 35m Ci -- 3.96E-04 TOTAL FOR PERIOD Ci ] 1.91 E-01 [ 3.64E-02 1.14E-01 1.16E-01 NUCLIDES UNITS CONTINUOUS MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Ar-41 Ci ........

Kr-85 Ci ........

Kr-85m Ci ........

Kr-87 Ci ........

Kr-88 Ci ........

Xe-131 m Ci ........

Xe-133 Ci ........

Xe-133m Ci ........

Xe-135 Ci ........

Xe-1 35m Ci ........

Xe-138 Ci ........

[TOTAL FOR PERIOD Ci I -" - I -- I -

B. IODINES NUCLIDES UNITS CONTINUOUS MODE RELEASED Qtr 1 Qtr 2 Qtr 3 Qtr 4 Br-82 Ci ...

1-13 1 Ci . .. .. .. .

1-133 Ci ........

[TOTAL FOR PERIOD Ci .. -....

C. PARTICULATES NUCLIDES UNITS CONTINUOUS MODE RLAE Qt Qtr 2 Qtr 3 I Qtr 4 Co-58 Ci....

Co-60 Ci ....

jMn-54 Ci ....

1Cr-51 Ci ....

TOTAL FOR PERIOD Ci -- I- -I-18

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 DOSES DUE TO IODINE, TRITIUM, AND PARTICULATES UNIT4 TABLE 5 PATHWAY BONE LIVER THYROID KIDNEY LUNG G'-LLI SKIN TOTALBODY Cow milk - Infant (mrem) ...............

Fruit & Veg Fresh (mrem) ...............

Ground Plane (mrem) ................

Inhalation - Adult (mrem) ..............

TO TA L (m re m ) ...............

h. of AnnualI Limit ......

DOSES DUE TO NOBLE GASES I mrad  % of Annual Limit aa Air Dose 1.46E-06 1.46E-05 JBeta Air Dose 1.32E-05 6.61 E-05 1 19

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 DOSES DUE TO IODINE,TRITIUM, AND PARTICULATES Summation Table 5 PATHWAY BONE LIVER THYROID KIDNEY LUNG GI-LLI SKIN TOTAL BODY Cow milk-Infant 8.77E-08 7.53E-06 4.11 E-05 3.29E-06 7.43E-06 7.43E-06 -- 7.49E-06 Fruit & Veg Fresh 4.20E-09 7.79E-07 2.17E-06 5.14E-07 7.74E-07 7.75E-07 -- 7.78E-07 Ground Plane 5.83E-10 5.83E-10 5.83E-10 5.83E-10 5.83E-10 5.83E-10 7.08E-10 5.83E-10

'Inhalation - Adult 1.70E-10 3.35E-06 3.43E-06 3.36E-06 3.35E-06 3.35E-06 -- 3.35E-06 TOTAL (mrem) 9.27E-08 1.17E-05 4.67E-05 7.16E-06 1.16E-05 1.16E-05 7.08E-10 1.16E-05

% of Annual Limit 6.18E-07 7.78E-05 3.11 E-04 4.77E-05 7.71 E-05 7.71E-05 4.72E-09 7.75E-05 DOSES DUE TO NOBLE GASES mrad  % of Annual Limit o1-53E-05 1.53E-04 IBeta Air Dose 3.10E-05 1.55E-04 20

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 TABLE 6 SOLID WASTE AND IRRADIATED FUEL SHIPMENTS A. SOLID WASTE SHIPPED OFFSITE FOR BURIAL OR DISPOSAL

1. TYPE OF WASTE UNITS 12 MONTH PERIOD  % ERROR
a. Spent resin, filters, sludge, m3 9.23E+00 2.OOE+00 evaporator bottoms, etc. Ci 5.66E+01
b. Dry compressible waste (Note 1) m3 2.44E+01 2.OOE+00 Ci 3.OOE+00
c. Irradiated components, control m3 (None shipped) rods, etc. Ci
d. Other: m3 (None shipped) 2.OOE+00 (non-compressible waste) Ci
2. ESTIMATE OF MAJOR NUCLIDE COMPOSITION (by type of waste)
a. NUCLIDE UNITS VALUE Cr-51  % 7.OOE+00 Mn-54  % 3.OOE+00 Fe-55  % 2.40E+01 Co-58  % 3.OOE+01 Co-60  % 1.OOE+01 Ni-63  % 2.40E+01 Nb-95  % 2.OOE+00
b. NUCLIDE UNITS VALUE C-14  % 1.OOE+00 Cr-51  % 4.OOE+00 Mn-54  % 1.OOE+00 Fe-55  % 4.50E+01 Co-58  % 2.60E+01 Co-60  % 7.OOE+00 Ni-63  % 8.OOE+00 Nb-95  % 4.OOE+00 Zr-95  % 2.OOE+00 Ag-110m  % 1.OOE+00 Sb-125  % 1.OOE+00 21

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 TABLE 6

c. (None shipped)
d. (None shipped)
3. SOLID WASTE DISPOSITION Number of Shipments Mode of Transportation Destination 3 (Note 2) Sole use truck Oak Ridge, TN 3 (Note 2) Sole use truck Barnwell, SC B. IRRADIATED FUEL SHIPMENTS (Disposition)

None 22

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 TABLE 6 SOLID WASTE SHIPMENTS Waste Total Volume (Note 3) Total (Note 4) (Note 5) R.G. 1.21 (Note 6)

Classification Cubic Feet Curies Principal Type of Waste Category 'I ype of Container Radionuclides 3.OOE+00 None Compressible 1 .b. Strong Tight Class A 5.80E+03 Waste 4.02E+01 None Dewatered Resin L.a. Cask Class B 1.20E+02 1.64E+01 None Dewatered Filters 1.a. Cask Class A 2.06E+02 No solidification or absorbing agents were used or needed in the shipment of these waste types 23

TURKEY POINT UNITS 3 AND 4 ANNUAL RADIOACTIVE EFFLUENT RELEASE REPORT JANUARY 2001 THROUGH DECEMBER 2001 TABLE 6 NOTE 1: Dry compressible waste volume indicates volume shipped to a burial site following reduction by a waste processing facility was 1.86E+01 Cubic Meters.

NOTE 2: Material transported to Oak Ridge Tennessee was consigned to licensed processing facilities for volume reduction and decontamination activities. The material remaining after processing was transported by the processor to Barnwell South Carolina or Clive Utah in accordance with the appropriate burial license activity limits. The material shipped directly to Barnwell was processed by CNSI / Duratek Inc. and buried.

NOTE 3: The total curie quantity and radionuclide composition of solid waste shipped from the Turkey Point Plant Units 3 and 4 are determined using a combination of qualitative and quantitative techniques. The Turkey Point Plant follows the guidelines in the Low Level Waste Licensing Branch Technical Position on Radioactive Waste Classification (5/11/83) for these determinations.

The most frequently used techniques for determining the total activity in a package are the dose to curie method and inference from specific activity and mass or activity concentration and volume. Activation analysis may be applied when it is appropriate. The total activity determination by any of these methods is considered to be an estimate.

The composition of radionuclides in the waste is determined by periodic off-site analysis for difficult to measure isotopes. Off-site analysis are used to establish scaling factors or other estimates for difficult to measure isotopes and principle Gamma emitters.

NOTE 4: Principle radionuclide refers to those radionuclides contained in the waste in concentrations greater than 0.01 times the concentration of the nuclide listed in Table 1 or 0.01 times the smallest concentration of the nuclide listed in Table 2 of 10 CFR 61.55.

NOTE 5: Type of waste is specified as described in NUREG 0782, Draft Environment Impact Statement on 10 CFR 61 "Licensing Requirements for Land Disposal of Radioactive Waste".

NOTE 6: Type of container refers to the transport package.

24

APPENDIX A ODCM CHANGES 2001

APPENDIX A REVISION OF TURKEY POINT ODCM 2001 Chapter 1

1. Offsite Dose Calculation Manual front page:

Change: Revision "8" to "9" and change date will be the Plant General Manager approval date.

Bases: Control 1.1, ODCM review and approval, Section 1.1.1 Responsibility for Review; requires an annual review of the ODCM.

2. List of affective Pages:

Change: Revision dates for the entire ODCM, not only for the pages that have been revised, will change to the date the review is approved by the Plant General Manager.

Bases: The clerical responsibilities for changes to the ODCM have been transferred to Document Control. Changing the revision date to the entire document will mark this date. Previously, the Chemistry Department performed this function. From this day forward, changes to the ODCM will follow the same process as any other procedure.

2

APPENDIX A REVISION OF TURKEY POINT ODCM 2001 Chapter 2 No changes 3

APPENDIX A REVISION OF TURKEY POINT ODCM 2001 Chapter 3

1. Page 3-25 Dated 02/14/96, Example Calculation:

Change: Table 3.1-5 to Table 3.1-3 Bases: The table was incorrectly referenced.

2. Page 3-54 Dated 02/14/96, description of Qi*

Change: INSERT "a single analysis, K, pCi" Bases: The definition of Qik was incomplete.

4

APPENDIX A REVISION OF TURKEY POINT ODCM 2001 Chapter 4 No Changes 5

APPENDIX A REVISION OF TURKEY POINT ODCM 2001 Chapter 5

1. Page 5-6 Dated 02/14/96 Table 5.1-2 (Reporting Levels), Column header for "Fish":

Change: Units of measure current pCi/kg, dry, change to "pCi/kg, wet" Bases: Prior versions of the ODCM, NUREG-0472, and the reported results by the State Lab the units are pCi/kg, wet.

2. Page 5-7 Dated 02/14/96 Table 5.1-3, In the 'Airborne Particulate" column:

Change: DELETE the "0.01 " from the "H-3" row and INSERT "0.01" in the "Gross Beta" row.

Basis: This is an administrative change. The "0.01" dose apply to Gross Beta; H 3 analysis is not required or performed on air particulate filters. The "0.01" was a typographical error during one of the revisions and was not found /

corrected during proofreading.

3. Page 5-9 Dated 02/14/96 1st paragraph of METHOD 5.1:

Change: DELETE ".. and Rehabilitative Services" and INSERT "of Health (DOH)"

Basis: HRS was reorganized a few years ago. The department within the State that performs the REMP is now named Department of Health, (DOH).

4. Page 5-12 Dated 02/14/96 1st row of table:

Change: "Location" column CHANGE "SW-1" to "SSE-I". "Description" CHANGE to On site South East side of cooling canals at "Turtle Point".

"Direction Sector" column, CHANGE "SW" to "SSE".

Bases: During a prior revision, location SW-I was duplicated in the table, (page 5 11), and location SSE-1 was left out; this was missed during proofreading.

5. Page 5-13 Dated 02/14/96, location description for Airborne site T-57:

Change: DELETE "Tree nursery 31 6 th Street" INSERT "Siren pole 27, intersection ofSW 112th Ave and SW 304th St.

Bases: The sample site was relocated 5-19-99. The existing site became unusable; access became hindered by degrading path (not even a road) conditions, continued molestation, and wild dogs. The new site, about 3/4 mile away from the prior site, continues to comply with the NUREG-0472, Rev 3 guidance for location (e.g. in the direction of a major population center and most conservative X/Q considering reasonable access).

6

APPENDIX A REVISION OF TURKEY POINT ODCM 2001 Chapter 5 (continued)

6. Page 5-15 Dated 02/14/96, Location for Broad leaf vegetation sample T40:

Change: INSERT 'WNW" to the Direction Sector to read "W / WNW" Bases: The State used a GPS during one of their sample collection runs and they reported the actual sector to be WNW, the ODCM states "W." Adding the adjacent sector will satisfy the correctness of the location and still allow operational flexibility. If the sample is taken one hundred feet further south, then the sample sector would be W.

7. Page 5A-1 Dated 02/14/96, Turkey Point Supplemental REMP Sampling:

Change: DELETE "Department of Health and Rehabilitative Services." INSERT "Department of Health".

Bases: HRS was reorganized a few years ago. The department within the State that performs the REMP is now named Department of Health, (DOH).

8. Page 5A-4 Dated 02/14/96, Pathway: Ingestion, milk:

Change: T99: DELETE ">" from the Distance and change description to read "1 8 3rd block of SW 2 62 nd St." Alt: Change Distance to 10 and Description to read "1I 3 4 th block of SW 224 th St."

Bases: This is a supplemental sampling matrix that is not required by ODCM. The locations will vary as supplies of milk change. These new locations appear to be viable for the next few years.

7

OFFSITE DOSE CALCULATION MANUAL FOR GASEOUS AND LIQUID EFFLUENTS FROM THE TURKEY POINT PLANT UNITS 3 AND 4 REVISION 9 CHANGE DATED 03/26/01 Florida Power and Light Company

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL LIST OF EFFECTIVE PAGES Offsite Dose Calculation Manual Revision Revision Revision Page Date Paqe Date Page Date i 3/26/01 2-13 2/14/96 3-15 2/14/96 ii 3/26/01 2-14 2/14/96 3-16 2/14/96 iii 3/26/01 2-15 2/14/96 3-17 2/14/96 iv 3/26/01 2-16 2/14/96 3-18 2/14/96 v 3/26/01 2-17 2/14/96 3-19 2/14/96 vi 3/26/01 2-18 2/14/96 3-20 2/14/96 vii 3/26/01 2-19 2/14/96 3-21 1/30/98 viii 3/26/01 2-20 2/14/96 3-22 2/14/96 1-1 2/14/96 2-21 2/14/96 3-23 2/14/96 1-2 2/14/96 2-22 2/14/96 3-24 2/14/96 1-3 2/14/96 2-23 2/14/96 3-25 3/26/01 1-4 2/14/96 2-24 2/14/96 3-26 2/14/96 1-5 2/14/96 2-25 2/14/96 3-26 2/14/96 1-6 2/14/96 2-26 2/14/96 3-28 2/14/96 1-7 2/14/96 2-27 2/14/96 3-29 2/14/96 1-8 2/14/96 2-28 1/30/98 3-30 2/14/96 1-9 2/14/96 2-29 2/14/96 3-31 2/14/96 1-10 2/14/96 2-30 2/14/96 3-32 2/14/96 1-11 2/14/96 2-31 2/14/96 3-33 2/14/96 1-12 2/14/96 2-32 2/14/96 3-34 2/14/96 1-13 2/14/96 2-33 2/14/96 3-35 2/14/96 1-14 2/14/96 2-34 2/14/96 3-36 2/14/96 1-15 2/14/96 3-1 2/14/96 3-37 2/14/96 1-16 2/14/96 3-2 1/30/98 3-38 2/14/96 2-1 2/14/96 3-3 2/14/96 3-39 2/14/96 2-2 2/14/96 3-4 2/14/96 3-40 2/14/96 2-3 2/14/96 3-5 2/14/96 3-41 2/14/96 2-4 2/14/96 3-6 2/14/96 3-42 2/14/96 2-5 2/14/96 3-7 2/14/96 3-43 2/14/96 2-6 2/14/96 3-8 2/14/96 3-44 2/14/96 2-7 1/30/98 3-9 2/14/96 3-45 2/14/96 2-8 2/14/96 3-10 2/14/96 3-46 2/14/96 2-9 2/14/96 3-11 2/14/96 3-47 2/14/96 2-10 2/14/96 3-12 2/14/96 3-48 2/14/96 2-11 2/14/96 3-13 2/14/96 3-49 2/14/96 2-12 2/14/96 3-14 2/14/96 3-50 2/14/96 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL LIST OF EFFECTIVE PAGES Offsite Dose Calculation Manual Revision Revision Revision Page Date Page Date Page Date 3-51 2/14/96 5-12 3/26/01 313-17 2/14/96 3-52 2/14/96 5-13 3/26/01 3B-18 2/14/96 3-53 2/14/96 5-14 2/14/96 3B-19 2/14/96 3-53 2/14/96 5-15 3/26/01 3B-20 2/14/96 3-54 3/26/01 5-16 2/14/96 3B-21 2/14/96 3-55 2/14/96 5-17 2/14/96 3B-22 2/14/96 3-56 2/14/96 5-18 2/14/96 38-23 2/14/96 3-57 2/14/96 5-19 2/14/96 3B-24 2/14/96 3-58 2/14/96 5-20 2/14/96 3B-25 2/14/96 3-59 2/14/96 5-21 3/02/99 31B-26 2/14/96 3-60 2/14/96 5-22 3/02/99 3B-27 2/14/96 3-61 2/14/96 5-23 3/02/99 3B-28 2/14/96 3-62 2/14/96 5-24 3/02/99 3B-29 2/14/96 3-63 2/14/96 2A-1 2/14/96 3B-30 2/14/96 3-64 2/14/96 2A-2 2/14/96 3B-31 2/14/96 3-65 2/14/96 2A-3 2/14/96 3B-32 2/14/96 3-67 2/14/96 2A-4 2/14/96 3B-33 2/14/96 3-68 2/14/96 3A-1 2/14/96 3B-34 2/14/96 3-69 2/14/96 3A-2 2/14/96 3B-35 2/14/96 3-70 2/14/96 3A-3 2/14/96 3B-36 2/14/96 4-1 2/14/96 3A-4 2/14/96 3B-37 2/14/96 4-2 2/14/96 3A-5 2/14/96 3B-38 2/14/96 4-3 2/14/96 3A-6 2/14/96 3B-39 2/14/96 4-4 2/14/96 3A-7 2/14/96 3B-40 2/14/96 4-5 2/14/96 38-1 2/14/96 38-41 2/14/96 4-6 2/14/96 38-2 2/14/96 38-42 2/14/96 4-7 2/14/96 38-3 2/14/96 38-43 2/14/96 4-8 2/14/96 3B-4 2/14/96 3B-44 2/14/96 4-9 2/14/96 38-5 2/14/96 3B-45 2/14/96 5-1 2/14/96 38-6 2/14/96 38-46 2/14/96 5-2 2/14/96 313-7 2/14/96 38-47 2/14/96 5-3 2/14/96 3B-8 2/14/96 3B-48 2/14/96 5-4 2/14/96 3B-9 2/14/96 38-49 2/14/96 5-5 2/14/96 3B-10 2/14/96 38-50 2/14/96 5-6 3/26/01 38-11 2/14/96 38-51 2/14/96 5-7 3/26/01 3B-12 2/14/96 3B-52 2/14/96 5-8 2/14/96 38-13 2/14/96 38-53 2/14/96 5-9 3/26/01 38-14 2/14/96 3B-54 2/14/96 5-10 2/14/96 38-15 2/14/96 38-55 2/14/96 5-11 2/14/96 3B-16 2/14/96 3B-56 2/14/96 ii 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL LIST OF EFFECTIVE PAGES Offsite Dose Calculation Manual Paqe Date 3B-57 2/14/96 3C-1 2/14/96 3C-2 2/14/96 3C-3 2/14/96 5A-1 3/26/01 5A-2 2/14/96 5A-3 2/14/96 5A-4 3/26/01 iii 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL TABLE OF CONTENTS Introduction vii 1.0 Administrative Controls 1-1 Control 1.1 ODCM Review and Approval .......................................................

Control 1.2 Major Changes to Liquid and Gaseous Radwaste Treatment 1-2 S yste m s .........................................................................................

1-3 Control 1.3 Annual Radioactive Release Report .............................................

1-5 Control 1.4 Annual Radiological Environmental Operating Report .................

1-6 Control 1.5 Definitions .....................................................................................

1 -14 Control 1.6 Applicability of Controls ................................................................

1 -15 Control 1.7 Surveillance Requirements .........................................................

1 -12 Figure 1.5-1 Site Area Map .............................................................................

1 -13 Figure 1.5-2 Plant Area Map ............................................................................

2.0 Liquid Effluents 2.0 Liquid Effluent System Description .............................................................. 2-1 2-5 Control 2.1 Radioactive Liquid Effluent Monitoring Instrumentation .............

2-14 Control 2.2 Liquid Effluent Concentration ....................................................

2 - 25 Control 2.3 Dose From Liquid Effluents .......................................................

Control 2.4 Requirements For Use Of Liquid Radwaste 2 - 32 Treatm ent System ......................................................................

2-4 Figure 2 - 1 Radioactive Liquid W aste ............................................................

2A- 1 Appendix 2A Radioactive Liquid Waste Pathway dose Transfer Factors ..........

iv 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL TABLE OF CONTENTS (continued) 3.0 Gaseous Effluents 3.0 Gaseous Effluent System Description ................................................. 3-1 Control 3.1 Radioactive Gaseous Effluent Monitoring Instrumentation 3-10 Control 3.2 Dose Rate From Gaseous Effluents ................................. 3 - 27 Control 3.3 Dose From Noble Gas In Gaseous Effluents .................... 3 -44 Control 3.4 Dose From Iodine-131, Iodine-133, Tritium, and Radioactive Material in Particulate Form ............................................... 3 - 52 Control 3.5 Requirements For Use Of Gaseous Radwaste Treatment System ............................................................ 3 - 67 Figure 3 - 1 Radioactive Gaseous Waste ........................................... 3-8 Figure 3 - 2 Locations of Airborne Effluent Dose Calculations ............. 3-9 Appendix 3A Reference Meteorology Annual Atmospheric Dispersion F a cto rs ............................................................................. 3A- 1 Appendix 3B Pathway Dose Transfer Factors ...................................... 3B - 1 Appendix 3C Technical basis for Aeff ...................................................... 3C - 1

4. Total Dose Control 4.1 Annual Dose From the Uranium Fuel Cycle ...................... 4-1 V 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL TABLE OF CONTENTS (continued

5. Radiological Environmental Monitoring Program Control 5.1 Sampling and Analysis Program ......................................... 5 - 1 Control 5.2 Land Use Census .............................................................. 5 - 19 Control 5.3 Interlaboratory Comparison Program ................................. 5 - 21 Figure 5.1-1 Near Site sampling Locations ............................................ 5 - 17 Figure 5.1-2 Distant REMP sampling Locations .................................... 5 - 18 Appendix 5A Supplemental Radiological Environmental Sampling Program 5A - 1 vi 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL INTRODUCTION PURPOSE This manual describes methods which are acceptable for calculating radioactivity concentrations in the environment and potential offsite doses associated with liquid and gaseous effluents from the Turkey Point Nuclear Units. These calculations are performed to satisfy Technical Specifications and to ensure that the radioactive dose or dose commitment to any member of the public is not exceeded.

The radioactivity concentration calculations and dose estimates in this manual are used to demonstrate compliance with the Technical Specifications required by 10 CFR 50.36. The methods used are acceptable for demonstrating operational compliance with 10 CFR 20.1302, 10CFR50 Appendix I, and 40CFR190. Only the doses attributable to Turkey Point Units 3 and 4 are determined in demonstrating compliance with 40CFR190 since there are no other nuclear facilities within 50 miles of the plant. Monthly calculations are performed to verify that potential offsite releases do not exceed Technical Specifications and to provide guidance for the management of radioactive effluents. The dose receptor is described such that the exposure of any member of the public is not likely to be substantially underestimated.

Quarterly and annual calculations of committed dose are also performed to verify compliance with regulatory limits of offsite dose. For these calculations, the dose receptor is chosen on the basis of applicable exposure pathways identified in a land use survey and the maximum ground level atmospheric dispersion factor (X/Q) at a residence, or on the basis of more conservative conditions such that the dose to any resident near the plant is not likely to be underestimated.

The radioactive effluent controls set forth in this ODCM are designed to allow operational flexibility but still maintain releases and doses "as low as is reasonably achievable"; that is, within the objectives of Appendix 1,10 CFR Part 50 and comply with the limits in 10 CFR 20.1302.

The methods specified in the OFFSITE DOSE CALCULATION MANUAL (ODCM) for calculating doses due to planned or actual releases are consistent with the guidance and methods provided in:

Regulatory Guide 1.109, "Calculation of Annual Doses to Man from Routine Releases of Reactor Effluents for the Purpose of Evaluating Compliance with 10 CFR Part 50, Appendix I,"

Revision 1. October 1977.

Regulatory Guide 1.111, "Methods for Estimating Atmospheric Transport and Dispersion of Gaseous Effluents in Routine Releases from Light-Water Cooled Reactors," Revision 1, July 1977.

vii 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL INTRODUCTION, (continued)

Regulatory Guide 1.113, "Estimating Aquatic Dispersion of Effluents from Accidental and Routine Reactor Releases for the Purpose of Implementing Appendix I," April 1977.

The required detection capabilities for radioactive materials in liquid and gaseous waste samples are tabulated in terms of the lower limits of detection (LDD's). Detailed discussion of the LLD and other detection limits, can be found in Currie, L. A., "Lower Limit of Detection: Definition and Elaboration of a Proposed Position for Radiological Effluent and Environmental Measurements,"

NUREG/CR-4077 (September 1984), in HASL Procedures Manual, HASL300 and in Hartwell, J. K.,

"Detection Limits for Radioanalytical Counting Techniques," Atlantic Richfield Hanford Company Report ARH-SA-215 (June 1975).

viii 3/26/01 Rev 9

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 3.0 RADIOACTIVE GASEOUS EFFLUENT CONTROL 3.1 : Radioactive Gaseous Effluent Monitoring Instrumentation; Operability and Alarm/Trip Setpoints, (continued)

METHOD 3.1.2: ESTABLISHING GASEOUS EFFLUENT MONITOR ALARM AND TRIP SETPOINTS, (continued)

EXAMPLE CALCULATION: Determining the Noble Gas Monitor Alarm Setpoint, (continued)

DF = factor for exposure to a semi-infinite cloud of noble gas mrem see Table 3.1-3. 3)

(yr-trCiim Ci = concentration of radionuclide, i, in gaseous effluent (LCi/cc).

Bkg = monitoring instrument background (cpm).

Example:

The measured concentration of noble gases to be discharged to the atmosphere are:

Radionuclide CALCUCC)

Kr-85m 3.6 x 10-5 Kr-85 2.8 x 10-4 Kr-87 2.5 x 10e Kr-88 1.4 x 10-5 1.0 x 102 Xe-131m Xe-133 4.3 x 10-2 Xe-135 6.0 x 10' Ar-41 7.7 x 10. 5 Determine the alarm setpoint, S (cpm) when:

h = 2.5x10 8 prn jICi/cc F = 8.0 x 104 ft3 min X/Q = 5.8 x 10-7 sec m3 Sf = 0.6 Bkg = 600 cpm 3-25 03/26/01

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 3.0 RADIOACTIVE GASEOUS EFFLUENTS CONTROL 3.4: DOSE - IODINE-131, IODINE-133. TRITIUM, AND RADIOACTIVE MATERIAL IN PARTICULATE FORM, (continued)

METHOD 3.4.1: DOSE DUE TO IODINE, TRITIUM, AND PARTICULATES IN GASEOUS EFFLUENTS A. Determining the Quantity of Iodine, Tritium, and Particulates Radionuclides, other than noble gases, in gaseous effluents that are measured by the radioactive gaseous waste sampling and analysis program, described in ODCM Table 3.2-1, are used as the release term in dose calculations. Airborne releases are discharged either via a stack above the top of the containment building or via other vents and are treated as a mixed mode release from a single location. Releases of steam from the secondary system concurrent with primary to secondary leakage will also result in the release of activity to the atmosphere. For steam generator blowdown, using a blowdown sample analysis, it is assumed that 5% of the 1-131 and 1-133 and 33% of the tritium in the blowdown stream become airborne with the remainder staying in the liquid phase. For other unmonitored releases, the quantity of airborne releases may be determined by performing a steam mass balance. For each of these release combinations, samples are analyzed weekly, monthly, quarterly, or for each batch releases according to Table 3.2-1 Each sample provides a measure of the concentration of specific radionuclides, C1 , in gaseous effluent discharged at flow, F, during a time increment, t. Thus, each release is quantified according to the relation Qk = CkA Y Fj 0 tj Eqn 3.4-1 where:

Qik = the quantity of radionuclide i released in a given effluent stream based on a single analysis, k, (ýtCi)

Cik = concentration of radionuclide i in a gaseous effluent identified by analysis, k, (pCi/cc)

Fj = effluent stream discharge rate during time increment, tj, (cc/sec) tj = time increment, t, during which radionuclide i at concentration Cik is being discharged, (sec).

3 - 54 03/26/01

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL l*t3 r- F RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

.CONTROL 5.1 : CONDUCT OF SAMPLING AND ANALYSIS (continued)

TABLE 5.1-2 REPORTING LEVELS FOR RADIOACTIVITY CONCENTRATIONS IN ENVIRONMENTAL SAMPLES ANALYSIS WATER AIRBORNE FISH MILK FOOD PRODUCTS (pCi/I) PARTICULATE (pCi/kg, wet) 3 OR GASES (pCi/m )

H-3 30,000*

Mn-54 1,000 30,000 Fe-59 400 10,000 Co-58 1,000 30,000 Co-60 300 10,000 Zn-65 300 20,000 Zr-Nb-95 400 1-131 2 0.9 3 100 Cs-134 30 10 1,000 60 1,000 Cs-1 37 50 20 2,000 70 2,000 Ba-La-140 200 300 Since no drinking water pathway exists, a value of 30,000 pCi/I is used. For drinking water samples a value of 20,000 pCi/I is used.

This is 40 CFR Part 141 value.

    • Applies to drinking water An equalibrium mixture of the parent and daughter isotopes which corresponds to the reporting value of the parent isotope 5-6 03/26/01 1

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM CONTROL 5.1 CONDUCT OF SAMPLING AND ANALYSIS (continued)

TABLE 5.1-3 1

DETECTION CAPABILITIES FOR ENVIRONMENTAL SAMPLE ANALYSIS( )

LOWER LIMIT OF DETECTION (LLD)

(2)(3)

ANALYSIS WATER AIRBORNE PARTICULATE FISH SEDIMENT MILK FOOD PRODUCTS (pCi/I) OR GASES (pCi/m 3) (pCi/kg, wet) (pCi/kg, dry) (pCi/I) (pCi/kg, wet)

Gross Beta 4 0.01 H-3 3,000 Mn-54 15 130 Fe-59 30 260 Co-58 15 130 Co-60 15 130 Zn-65 30 260 Zr-Nb-95*** 15(5) 1-131 1(4) 0.07 1 60 15 0.05 130 150 15 60 Cs-134 18 0.06 150 180 18 80 Cs-137 Ba-La-140*** 15() 5

  • Since no drinking water pathway exists, a value of 3,000 pCi/I is used. For drinking water samples a value of 2,000 pCi/I is used.

5-7 03/26/01

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM CONTROL 5.1 : CONDUCT OF SAMPLING AND ANALYSIS (continued)

TABLE NOTATIONS (continued) - TABLE 5.1-3 (continued)

(3) The LLD is defined (continued)

It should be recognized that the LLD is defined as an a priori (before the fact) limit representing the capability of a measurement system and not as an a posteriori (after the fact) limit for a particular measurement. Analyses shall be performed in such a manner that the stated LLDs will be achieved under routine conditions. Occasionally background fluctuations, unavoidable small sample sizes, the presence of interfering nuclides, or other uncontrollable circumstances may render these LLDs unachievable.

In such cases, the contributing factors shall be identified and described in the Annual Radiological Environmental Operating Report pursuant to Control 1.4.

(4) LLD for drinking water samples. If no drinking water pathway exists, the LLD of gamma isotopic analysis may be used.

(5) An equilibrium mixture of the parent and daughter isotopes which corresponds to 15 pCi/I of the parent isotope.

METHOD 5.1: RADIOLOGICAL ENVIRONMENTAL SURVEILLANCE - TURKEY POINT PLANT It is the policy of Florida Power and Light Company (FPL) that the Turkey Point 3 and 4, Radiological Environmental Monitoring Programs, (REMP), are conducted by the State of Florida Department of Health (DOH), pursuant to an Agreement between FPL and DOH. The policy also states that the coordination of the REMP with DOH and compliance with the REMP requirements are the responsibility of the Nuclear Division Health Physics/Chemistry Staff.

The following pages describe the actual sampling and analysis program implemented to satisfy ODCM Table 5.1-1.

5-9 03/26/01I

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM CONTROL 5.1: CONDUCT OF SAMPLING AND ANALYSIS (continued)

RADIOLOGICAL ENVIRONMENTAL SURVEILLANCE Key to Sample Locations Pathway Location Description Samples Sample Approx.Distan Direction Collected Collection ce (miles) Sector Frequency Direct SSE-1 On site South East side of TLD Quarterly 1 SSE Radiation coolinq canals at "Turtle Point" Direct SW-8 Card Sound Rd. 5 mi. SSE TLD Quarterly 8 SW Radiation of US 1 at entrance to Navy facility.

Direct SSW-5 On site, southwest corner TLD Quarterly 5 SSW Radiation of cooling canals Direct SSW-10 At Card Sound TLD Quarterly 10 SSW Radiation Bridge on siren pole.

S-5 On site, south east end of TLD Quarterly 5 S Direct Radiation cooling canals.

S-10 Card Sound Road at TLD Quarterly 10 S Direct Radiation Steamboat Creek.

5-12 03/26/01 1

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM CONTROL 5.1 CONDUCT OF SAMPLING AND ANALYSIS (continued)

RADIOLOGICAL ENVIRONMENTAL SURVEILLANCE Key to Sample Locations Pathway Location Description Samples Sample Approx. Direction Collected Collection Distance Sector Frequency (miles)

Direct SSE-10 Ocean Reef TLD Quarterly 10 SSE Radiation Direct Radiation NNE-22* Natoma Substation TLD Quarterly 22 NNE Airborne T51 Entrance to Homestead Radioiodine Weekly 2 NNW Bayfront Park and Particulate Airborne T71 Red Barn / Beach Area Radioiodine Weekly 0.5 NNE (Alternate to T51) and Particulate Airborne T57 Siren pole 27, intersection of Radioiodine Weekly 4 NW SW 112 t h Ave and SW 3 04th and St. Particulate Airborne T52 Florida City Radioiodine Weekly 7 W (Alternate to Substation and T57) Particulate Airborne T58 Turkey Point Radioiodine Weekly 1 NW Entrance Rd and Particulate

  • Denotes control sample 5-13 03/26/01 I

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM CONTROL 5.1: CONDUCT OF SAMPLING AND ANALYSIS (continued)

RADIOLOGICAL ENVIRONMENTAL SURVEILLANCE Key to Sample Locations Description Samples Sample Approx. Direction Pathway Location Sector Collected Collection Distance Frequency (miles)

Biscayne Bay, vicinity of Crustacea Semi- 13-18 N,NNE Food T67*

Cutler north to Park PlantHammock annually Products Matheson Fish Semi annually Card Sound near mouth of Crustacea Semi- 6 S Food T81 Products old Discharge Canal. annually Fish Semi annually South of Palm Dr. on SW Broad Monthly 3 W/ WNW Food T40 Products 117th St extension leaf vegetation Palm Dr. West of FPL Broad Monthly 2 WNW Food Products T41 wellness center near the site leaf boundary vegetation Near Biscayne Bay, Vicinity Broad Monthly 13 - 18 N, NNE Food Products T67*

of Cutler Plant North to leaf Matheson Hammock Park vegetation

  • Denotes control sample.

5-15 30/26/01 I

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM Turkey Point Supplemental REMP Sampling The sampling and analysis program outlined in this appendix is performed in addition to the sample and analysis program required by Control 5.1. The sample sites, frequency, and analyses have been agreed upon by the State of Florida Department of Health and Florida Power and Light Co. These samples are not required to be performed, but based on this agreement, are performed to provide a broader data base for the Radiological Environmental Monitoring Program.

5A - 1 03/26/01 I

TURKEY POINT UNIT 3 & 4 OFFSITE DOSE CALCULATION MANUAL 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM Turkey Point Supplemental REMP Sampling Pathway: Ingestion, Milk Sampling and Collection Frequency: Semiannual collection and Gamma- I Spec analysis Name Sector Distance Description T99 WNW 12 183d block of SW 262nd St.

(alt) W 10 134th block of SW 224e St.

Pathway: Ingestion, Fish Sampling and Collection Frequency: semi-annual collection and Gamma Spec analysis Pathway: Ingestion, Food Crop Sampling and Collection Frequency: Annual collection (@ harvest) and Gamma-Spec analysis Sector Distance j Description Various locations: Various locations : 'truck farm' point of sale N thru NW to W grownig fields, miscellaneous other sources of locally typically 2 to 10 miles grown food crops (e.g., corn, potato, sugar cane, greens, from plant etc)

  1. Although the Name remains the same, the locations can vary with sample availability.
  • Approximate Distance from plant in miles 5A - 4 03/26/01 I