3F0413-08, Submittal of 2012 Annual Radiological Environmental Operating Report

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Submittal of 2012 Annual Radiological Environmental Operating Report
ML13128A008
Person / Time
Site: Crystal River Duke Energy icon.png
Issue date: 04/25/2013
From: Wunderly B
Duke Energy Corp, Florida Power & Light Co
To:
Document Control Desk, Office of Nuclear Reactor Regulation
References
3F0413-08
Download: ML13128A008 (86)


Text

kDuke aEnergy@

Crystal River Nuclear Plant Docket No. 50-302 Operating License No. DPR-72 Ref: ITS 5.7.1.1 (b)

April 25, 2013 3F0413-08 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, DC 20555-0001

Subject:

Crystal River Unit 3 - 2012 Annual Radiological Environmental Operating Report

Dear Sir:

Florida Power Corporation hereby submits the 2012 Annual Radiological Environmental Operating Report for Crystal River Unit 3 (CR-3) in accordance with the CR-3 Improved Technical Specifications, Section 5.7.1.1(b) and Section 6.6 of the Offsite Dose Calculation Manual (ODCM). The data provided in the attached report is consistent with the objectives outlined in the ODCM, and includes all radiological environmental samples taken during the report period from January 1, 2012 through December 31, 2012.

No new regulatory commitments are made in this letter.

If you have any questions regarding this submittal, please contact Mr. Dan Westcott, Licensing Supervisor at (352) 563-4796.

Sincerely, Blair P. Wunderly Plant Manager Crystal River Nuclear Plant BPW/ff

Attachment:

2012 Annual Radiological Environmental Operating Report xc: Regional Administrator, Region II Senior Resident Inspector NRR Project Manager Crystal River Nuclear Plant 15760 W. Power Line Street Crystal River, FL 34428

FLORIDA POWER CORPORATION DOCKET NUMBER 50 - 302 / LICENSE NUMBER DPR- 72 ATTACHMENT 2012 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT

ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 2012 PROGRESS ENERGY FLORIDA, INC.

CRYSTAL RIVER UNIT 3 Prepared By: Rudy Pinner 04/17/2013 Sr. Nuclear Plant Chemistry Specialist

TABLE OF CONTENTS In tro d u ctio n ............................................................................................................ ii Summary Description of the Radiological Environmental Monitoring Program ........................................................................................... 1 II. Land-Use Census .......................................................................................... 11 Ill. Interlaboratory Comparison Program .............................................................. 12 IV. Analytical Results ................................................................................................. 14 A. Airborne Pathway ..................................................................................... 14 Statistical Sum mary ................................................................................. 15 B. Direct Radiation ........................................................................................ 26 Statistical Sum mary ................................................................................. 27 C. Waterborne Pathway ................................................................................. 30

1. Seawater ............................................................................................. 30 Statistical Sum mary ................................................................................ 33
2. Ground Water .................................................................................... 30 Statistical Sum mary ........................................................................ . 37
3. Site Ground Water ............................................................................ 30 Statistical Summary ............................................................................ 40
4. Site Ground Water Non-REM P ........................................................... 31 Statistical Sum mary ................................................................................ 56
5. Drinking Water ................................................................................... 31 Statistical Sum mary ............................................................................ 61
6. Shoreline Sediment ............................................................................ 31 Statistical Sum mary ................................................................................ 64
7. Site Settling Ponds ........................................................................... 32 Site Settling Pond Supplemental Data ............................................... 67
8. NEI 07-07 Evaluation ........................................................................ 32 D. Ingestion Pathway ................................................................................... 68
1. Carnivorous Fish ................................................................................. 68 Statistical Sum mary ............................................................................ 70
2. Oysters ............................................................................................... 68 Statistical Sum mary ............................................................................ 73
3. Broad Leaf Vegetation ....................................................................... 68 Statistical Sum mary ............................................................................ 76
4. Watermelon and Citrus ....................................................................... 69 Statistical Sum mary ................................................................................ 80 i

INTRODUCTION This report is submitted as required by Technical Specification 5.7.1.1 (b) to the Crystal River Facility Operating License No. DPR-72, and Section 6.6 of the Offsite Dose Calculation Manual.

The following information is required to be included in this report:

- Data Summaries

- Interpretations

- Unachievable LLDs

- An analysis of trends

- An assessment of any observed impact of plant operation on the environment NOTE: If harmful effects or evidence of irreversible damage are detected by the monitoring, the report shall provide an analysis of the problem and a planned course of action to correct it.

- Summarized and tabulated results of all radiological environmental samples taken during the report period, in the format of Radiological Assessment Branch Technical Position, Revision 1, November, 1979.

NOTE: If some results are not available for inclusion, the report shall note and explain the reason for the missing results. The missing results shall be submitted as soon as possible in a supplementary report.

- A summary description of the Radiological Environmental Monitoring Program.

- A map of all sampling locations keyed to a table giving distances and directions from the reactor.

- Land-use census results.

- Interlaboratory Comparison Program results.

- A discussion of airborne sample station availability.

- Results of any unplanned release or spill of radioactive material that could have the potential to contaminate the groundwater as reported to maintain compliance with the groundwater protection initiative (NEI 07-07).

I.

SUMMARY

DESCRIPTION OF THE RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM The analytical results of the Crystal River Unit 3 (CR-3) operational Radiological Environmental Monitoring Program (REMP) for 2012 are contained in this report. The operational program began on January 1, 1977 just prior to initial criticality, which was achieved on January 14, 1977.

Sampling of the facility environs is performed by the State of Florida Department of Health, Bureau of Radiation Control. The State also performs the required analyses, participates in the Interlaboratory Comparison Program, and performs the annual land-use census. Prior to 1990, the program was split between the Department of Health and the University of Florida. The transition to the State performing all of the program's sampling and analyses in 1990 is evident in several of the trend graphs, most notably oysters and carnivorous fish, and is due to the State using less sensitive measurement techniques for several of the pathways which were formerly evaluated by the University of Florida.

Sample station locations are given in Table I-1 and Figures 1-2, 1-3, 1-4, and 1-5. Sample frequency and analysis type may be determined from Table 1-2. Figure I-1 illustrates the relevant exposure pathways.

Regarding waterborne pathways, the groundwater area of the Crystal River site is too saline to be used as a source of drinking water, hence there is no credible drinking water uptake pathway. Additionally, the Florida aquifer groundwater flows in a west-southwest direction across the site toward the Gulf of Mexico and since the locale of the site is along the coast, there is no downstream public impact regarding groundwater.

Except for air sample gross beta results and direct radiation measurements, most of the analytical results are below the lower limit of detection (LLD) of the sample. Sample LLDs are generally much lower than the required "a priori" LLD. When measurable results are reported, the values are also usually less than the required "a priori" LLD.

In 2011 there were positively measured results of iodine and cesium airborne concentrations during the period of March 22 through April 12 th for almost all sampling stations including the control station. These measurements are a direct result of the earthquake and tsunami event at the Dai-lchi, Fukushima following the March 11, 2011 Tohoku event in Japan. These measurements are not related to Crystal River Unit 3 activities. The Japanese event also affected broad leaf vegetation sample media throughout the year as long-lived radionuclides (Cs-1 37) were released at Fukushima multiple times. The vegetation measurements in 2012 are still affected by the Fukushima event due to the long-lived radionuclides deposited.

The results of the 2012 REMP have been compared to previous years' results. This comparison, in part illustrated by the trend graphs of Section IV,shows no evidence of consistent long-term increasing trends in any of the sample media. However, radioactive material is routinely quantified in sediment samples which are taken in the discharge canal near the liquid release discharge point. In general, these results verify the effectiveness of in-plant measures for controlling radioactive releases.

Trend graphs illustrate the mean measured concentration of a particular radionuclide for the year. When measurable results are not obtained, the highest sample LLD is plotted. LLD and measured values are plotted on the same line to best illustrate any trend. As shown on each graph's legend, any measured value is noted by a text box, unless all values trended are measured values for that particular parameter.

Statistical summary pages are provided for each medium or pathway. Measured values are reported in terms of a mean and range. In addition, the number of measured values versus samples obtained is reported. For example, in the following entry; 15 (249/256)

(4- 35) the "All Indicator Locations" column would be interpreted as indicating a mean measured value of 15, with measured values ranging from 4 to 35. (249/256) means that out of 256 samples, 249 were measured values.

I

TABLE I-1 PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 SAMPLE STATION LOCATIONS SAMPLE MEDIA STATION ID DIRECTION APPROX. DISTANCE (Miles)

TLD - on-site C60 N 0.88 C61 NNE 0.92 C62 NE 1.17 C63 ENE 0.87 C64 E 0.80 C65 ESE 0.33 C66 SE 0.36 C67 SSE 0.33 C68 S 0.27 C69 SSW 0.31 C41 SW 0.43 C70 WSW 0.74 C71 WNW 0.58 C72 NW 0.30 C73 NNW 0.74 C27 W 0.41 TLD - off-site C18 N 5.3 C03 NNE 4.89 C04 NE 5.95 C74 ENE 5.13 C75 E 3.99 C76 ESE 5.61 C08 SE 5.66 C77 SSE 3.39 C09 S 3.23 C78 WSW 4.59 C14G W 2.53 C01 NW 4.8 C79 NNW 4.97 C47-Control ESE 78 C07* ESE 7.67 C40* E 3.48 C46* N 0.37

  • TLDs not required by ODCM. Deployed at air sample locations.

TABLE I-1 (CONT'D)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 SAMPLE STATION LOCATIONS SAMPLE MEDIA STATION ID DIRECTION DISTANCE (Miles)

AIR C07 ESE 7.7 C18 N 5.3 C40 E 3.5 C41 SW 0.4 C46 N 0.4 C47-Control ESE 78 SEAWATER C14H NW 0.1 C14G W 2.5 C13-Control WSW 4.6 GROUND WATER C40-Control E 3.6 SITE GROUND WATER CR3-2 E 0.1 CR3-4 SSE 0.086 CR3-5 SSW 0.051 CR3-6S W 0.038 CR3-61D W 0.038 CR3-7 WNW 0.060 CR3-8 WNW 0.073 CR3-9 NW 0.1 CR3-10 NNE 0.1 DRINKING WATER C07-Control ESE 7.4 C 10-Control ESE 6.0 C18-Control N 5.3 SHORELINE SEDIMENT C09-Control S 3.2 C14H NW 0.1 C14M W 1.2 C14G W 2.5 FISH & OYSTERS C29 W 2.5 C30-Control WSW 3.4 BROAD LEAF VEGETATION C48A N 0.4 C48B ENE 0.9 C47-Control ESE 78 WATERMELON C04 NE 13 CITRUS C19 ENE 9.6 3

TABLE 1-2 PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 SAMPLING AND ANALYSIS PROGRAM SAMPLE MEDIA # OF STATIONS FREQUENCY ANALYSIS LLD 1 TI f ,nr* ( erlt ,I' ---

Weekly Air Iodine 6 1-131 0. 0 7 g pCi/m3 Weekly Air Particulate 6 Gross IB 0.01 Quarterly y*Spec: Cs-1 34 0.05e Cs-1 37 0.06e Seawater 3 Monthly Tritium 2 0 00 b pCi/L Monthly y Spec: Mn-54 15 Fe-59 30 Co-58 15 Co-60 15 Zn-65 30 Zr-Nb-95 15c 1-131 1t Cs-134 15 Cs-137 18 Ba-La-140 15c Ground Water 1 Semiannual Tritium 2000b pCi/L 2 2 Semiannual y*Spec:

Site Ground Waterb 9 Quarterly Tritium 2 0 00 b pCi/L 2 2 Quarterly 7Spec:

Drinking Water 3 Quarterly Tritium 2000b pCi/L 2

Quarterly y Spec:

Shoreline Sediment 4 Semiannual -ySpec: Cs-1 34 150 pCi/kg Cs-137 180

  • Includes 3 stations which are not required by the ODCM 1

The maximum "a priori" LLD 2

Same as Seawater y Spec 6

Additional 2 stations reported that are not required by the ODCM bLLD for drinking water. If no drinking water pathway exists, a value of 3000 pCi/L may be used CThe specified LLD is for an equilibrium mixture of parent and daughter nuclides which contain 15 pCi/L of the parent nuclide eLLDs apply only to quarterly composite gamma spectral analysis, not to analyses of single particulate filters fLLD for drinking water. If no drinking water pathway exists, the LLD of the gamma isotopic analysis may be used gLLD for 1-131 applies to a single weekly filter 4

TABLE 1-2 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 SAMPLING AND ANALYSIS PROGRAM 1

SAMPLE MEDIA # OF STATIONS FREQUENCY ANALYSIS LLD Carnivorous Fish 2 Quarterly y Spec: Mn-54 130 pCi/kg and Oysters Fe-59 260 Co-58 130 Co-60 130 Zn-65 260 Cs-134 130 Cs-137 150 Broad Leaf 3 Monthly:3 y Spec: 1-131 60 pCi/kg Vegetation Cs-134 60 Cs-137 80 Watermelon 1 Annual4 y Spec:

Citrus 1 Annual4 ySpec 1

3The maximum "a priori" LLD When available 4

During harvest 5

Same as broad leaf vegetation 5

FIGURE I-1: Environmental Media and Exposure Pathways C18 LAKE ROUSSEAU C04 CROSS-FLORIDA BARGE CANAL us 19 C19 C48A C48B PE PROPERTY C13 C30 CIo CRYSTAL RIVER C09 BAY FIGURE 1-2: Environmental Monitoring Sample Stations (non-TLDs) 7

C14

  • a 0

0*4 3: 0 04 44S 2 ~00 004 ~ 00 0 '0 -d 0 z 0 00 00 4

zz 400 0 0Q 00 FIGURE~ 1-:EvrnetlMntrn<L ~

oain o ie

C18 C03 LAKE ROUSSEAU CO1 C04 CROSS-FLORIDA BARGE CANAL 19 C74 C75 C76 CRYSTAL RIVER C07 C09 C08 KING'S BAY FIGURE 1-4: Environmental Monitoring TLD Locations (off site) 9

Figure 1-5: CR3 Groundwater Monitoring Well Locations Deep Wells Are Also Installed at #'s 1, 3, 6 Wells # 1 & 3 are not routinely sampled by the REMP 10

II. LAND-USE CENSUS A land-use census was conducted during June through August. The purpose of this census is to identify the nearest residences, vegetable gardens, and potential milk-producing animals within a five mile radius of the nuclear plant. The distance in miles and bearing in degrees for each receptor type in each of the sixteen sectors is summarized below.

T RESIDENCE NEAREST NEAREST GARDEN (A)

NEAREST MILK ANIMAL N 4.5 @ 20 NNE 4.6 @ 150 NE 3.8 @ 540 ENE 3.4 @ 600 4.4 @ 63' E 2.4 @ 920 ESE 4.2 @ 1020 4.7 @ 1030 SE 4.9 @ 1330 SSE 3.5 @ 1490 S

SSW 0vv WSW W

VIN VV NW 4.8 @ 3210 NNW 4.6 @ 3390 (A) - Only gardens with an estimated total area of 500 square feet, or more, and producing green leafy vegetables are considered.

  • No suitable sites were located within 5 miles.

II

Ill. FLORIDA DEPARTMENT OF HEALTH - INTERLABORATORY COMPARISON PROGRAM DATA The EPA crosscheck program ceased operation at the end of 1998. To meet the requirements for a crosscheck program, the Florida Department of Health participates in the Department of Energy's Mixed-Analyte Performance Evaluation Program (MAPEP). The following units are used for each of the four media:

Air Filters: Bq/sample Soil: Bq/Kg Vegetation: Bq/sample Water: Bq/L Analytical performance is based on historical analytical capabilities for individual analyte/matrix pairs.

Acceptable performance is designated by an "A".

Acceptable with warning is designated by a "W".

Performance which is not acceptable is designated by an "N".

Results for April 2012:

Media Nuclide Result  % Bias Acceptance Range Flag Air Cs-134 2.12 -10.9 1.67-3.09 A Air Cs-137 1.93 7.8 1.25-2.33 A Air Mn-54 3.66 13.0 2.27-4.21 A Air Zn-65 3.43 14.7 2.09 - 3.89 A Air Co-60 2.18 -0.1 1.527 - 2.837 A Soil K-40 1558.35 4.5 1044-1938 A Soil Mn-54 602.87 8.0 391 - 725 A Soil Cs-134 847.22 2.3 580-1076 A Soil Zn-65 712.63 11.0 449-835 A Soil Co-57 1201.03 1.9 825-1533 A Vegetation Co-57 10.40 -13.1 6.96-12.92 A Vegetation Co-60 5.24 -13.4 4.24-7.87 A Vegetation Cs-1 34 7.91 -6.2 5.90-10.96 A Vegetation Zn-65 8.14 -8.5 6.23-11.57 A Water H-3 446.30 2.1 306-568 A Water Mn-54 33.49 5.3 22.3-41.3 A Water Cs-137 40.37 1.2 27.9-51.9 A Water Co-57 30.56 -7.1 23.0-30.84 A Water Co-60 24.19 2.0 16.60 - 30.84 A 12

FLORIDA DEPARTMENT OF HEALTH - INTERLABORATORY COMPARISON PROGRAM DATA, cont'd Results for August 2012:

Media Nuclide Result  % Bias Acceptance Range Flag Air Cs-134 2.49 -9.1 1.92-3.56 A Air Mn-54 2.56 8.5 1.65-3.07 A Air Co-57 1.81 -5.2 1.34-2.48 A Air Co-60 1.70 -1.6 1.21 -2.246 A Soil Mn-54 960.09 4.4 644-1196 A Soil Co-60 550.54 1.8 372-690 A Soil Co-57 1317.05 0.1 921 -1711 A Soil Zn-65 657.47 8.5 424 - 788 A Soil Cs-134 940.11 0.1 657-1221 A Soil Cs-137 1158.87 0.8 805-1495 A Vegetation Mn-54 2.99 -8.6 2.29-4.25 A Vegetation Co-57 5.28 -6.7 3.96 - 7.36 A Vegetation Co-60 4.63 -9.6 3.58 - 6.66 A Vegetation Cs-1 34 6.27 -3.7 4.56 - 8.46 A Vegetation Cs-137 3.96 -9.6 3.07-5.69 A Water H-3 371.05 11.1 234-4.34 A Water Co-57 28.33 -3.3 20.5 - 38.1 A Water Cs-137 17.16 2.8 11.7-21.7 A Water Cs-134 23.18 -0.1 16.2-30.2 A Water Zn-65 28.79 11.2 18.1 -33.7 A Water Mn-54 19.01 6.8 12.5-23.1 A 13

IV-A. AIRBORNE PATHWAY Air samples are taken at five locations in the vicinity of the plant. The control location is 78 miles ESE of the plant, at the Department of Health, State Bureau of Radiation Control in Orlando.

Table IV-A.1 provides a statistical summary of the analytical results for 312 gross beta samples and 312 iodine samples.

Tables IV-A.2 and IV-A.3 provide the results for each weekly air sample.

In 2012, three hundred twelve particulate samples were analyzed for gross beta activity, all of which had measurable activity. The average indicator concentration was 18 pCi/1 000 m3 with a range of 6 to 44 pCi/1000 mi3 . The average indicator concentration since 1996 was in the range of 14 to 20 pCi/1 000 M3 . The control location concentration for 2012 averaged 17 pCi/1 000 M3 , with a range of 9 to 36 pCi/1000 M3 .

In 2012, three hundred twelve samples were analyzed for iodine activity, with none having measurable activity.

The highest iodine LLD was 0.04 pCi/m 3. There were no anomalies with the iodine samples for the year.

Quarterly composite data are summarized in Table IV-A.4. In 2012, measurable quantities of cesium were not identified in any particulate filter sample. The highest cesium LLD was 1.7 pCi/1 000 m3 for cesium 134.

The 2012 airborne sample data is comparable with previous year's sample data with exception of samples collected in 2011 during the March and April time frame where airborne particulate and iodine samples were affected by the Fukushima earthquake and tsunami event that occurred on March 11, 2011. Those sample data were thoroughly discussed in the 2011 Annual Radiological Environmental Operating Report submitted for Crystal River Unit 3.

There were no instances of non-collected airborne samples for the year 2012, but there were several instances of air sampler partial run times as follows:

1. In July station C-07 was down for 18.4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br /> due to a failed vacuum pump.
2. In August station C-07 was down for 66.7 hours8.101852e-5 days <br />0.00194 hours <br />1.157407e-5 weeks <br />2.6635e-6 months <br /> due to a power outage as a result of a failed lightening arrestor.
3. In September station C-1 8 was down for 41.2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> due to a failed vacuum pump.
4. In December station C-18 was down for 25.7 hours8.101852e-5 days <br />0.00194 hours <br />1.157407e-5 weeks <br />2.6635e-6 months <br /> due to an unknown power outage.

The remaining 4 sample stations were in service 100% of the time, with exception of filter changes and air pump/gas meter replacements. The percentages of down times for the 2 stations are as follows:

C07 0.97%

C18 0.76%

The air sample station's down times are documented in the plant Corrective Action Program (CAP) under Condition Reports (CRs) 557809 and 561970.

These run times are below the threshold reporting criteria of 30 hours3.472222e-4 days <br />0.00833 hours <br />4.960317e-5 weeks <br />1.1415e-5 months <br /> of continuous lost run time during a sample period.

14

TABLE IV-A.1 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED OF ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS AIRBORNE y Spec 312 IODINE (pCi/me) 1-131 0.04 <LLD -- <LLD <LLD 0 AIRBORNE Gross 11312 6.0 18 (260/260) C18 19(52/52) 17 (52/52) 0 PARTICULATES (6-44) 5.3 @ 00 (8-38) (6-36) 3 (pCi/1000m for y Spec 24 Gross I, 3

pCi/1000m for Cs-1 34 1.7 <LLD -- <LLD 0 y Spec)

Cs-137 1.5 <LLD <LLD 0 1

The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

15

TABLE IV-A.2 PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/m 3 IODINE - 131 INAIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 03-Jan-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 10-Jan-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 17-Jan-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 24-Jan-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 31-Jan-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 07-Feb-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 14-Feb-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 21-Feb-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 28-Feb-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 06-Mar-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 13-Mar-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 20-Mar-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 26-Mar-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 16

TABLE IV-A.2 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/m 3 IODINE - 131 IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 02-Apr-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 10-Apr- 12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 17-Apr-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 24-Apr-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 01-May-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 08-May-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 15-May-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 22-May-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 29-May-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 05-Jun-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 11-Jun-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 19-Jun-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 26-Jun-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 17

TABLE IV-A.2 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/m 3 IODINE - 131 IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 03-Jul-12 <0.02(A) <0.02 <0.02 <0.02 <0.02 <0.02 11-Jul-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 17-Jul-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 24-Jul-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 30-Jul-1 2 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 07-Aug-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 14-Aug-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 21-Aug-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 27-Aug-1 2 <0.02(B) <0.04 <0.04 <0.04 <0.04 <0.03 04-Sep-1 2 <0.02 <0.03(C) <0.02 <0.02 <0.02 <0.02 11 -Sep-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 18-Sep-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 26-Sep- 12 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 (A) Pump failed and was replaced. Estimated run time 151.3 out of 169.7 hours8.101852e-5 days <br />0.00194 hours <br />1.157407e-5 weeks <br />2.6635e-6 months <br />.

(B) No power to sample hut. Estimated run time 83.7 out of 150.4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br />.

(C) Pump failed and was replaced. Estimated run time 149.6 out of 190.8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />.

18

TABLE IV-A.2 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/m 3 IODINE - 131 IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 02-Oct-12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 10-Oct-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 17-Oct-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 23-Oct-1 2 <0.03 <0.02 <0.03 <0.03 <0.03 <0.03 31-Oct-12 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 06-Nov- 12 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 13-Nov-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 19-Nov-12 <0.03 <0.02 <0.03 <0.03 <0.03 <0.02 27-Nov-1 2 <0.02 <0.01 <0.02 <0.02 <0.02 <0.02 04-Dec-1 2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 11 -Dec-12 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 19-Dec-12 <0.03 <0.03(A) <0.03 <0.03 <0.03 <0.03 26-Dec-1 2 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 (A) Estimated run time 165.6 out of 191.3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />. Unknown reason for lower run time.

19

TABLE IV-A.3 PROGRESS ENERGY FLORIDA, INC. -CR3 - 2012 pCi/1000m3 GROSS Il IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 03-Jan-1 2 25 32 32 27 27 26 10-Jan-12 23 35 26 16 23 22 17-Jan-12 19 27 25 26 25 20 24-Jan-12 19 24 27 21 25 15 31-Jan-12 15 19 19 15 12 15 07-Feb- 12 14 20 17 14 14 14 14-Feb-12 22 23 18 16 27 23 21-Feb-12 9 13 13 12 14 11 28-Feb-12 14 19 19 14 18 16 06-Mar-1 2 13 15 10 13 12 14 13-Mar-12 14 17 11 15 13 14 20-Mar-1 2 8 18 6 9 11 11 26-Mar-12 21 19 17 20 16 19 Average: 17 22 18 17 18 17 20

TABLE IV-A.3 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/1000m 3 GROSS Il IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 02-Apr- 12 20 25 21 20 18 17 10-Apr-12 17 17 17 15 17 18 17-Apr-1 2 24 30 27 25 29 24 24-Apr- 12 14 15 18 19 18 15 01-May-12 19 23 17 22 17 17 08-May-1 2 15 16 15 16 15 13 15-May-1 2 21 25 21 23 18 20 22-May-12 21 14 19 17 18 13 29-May-1 2 13 27 24 18 17 13 05-Jun-12 18 21 18 17 16 17 11 -Jun-12 13 13 12 16 11 12 19-Jun-12 13 15 14 11 11 12 26-Jun-12 8 8 8 8 8 12 Average: 17 19 18 17 16 16 21

TABLE IV-A.3 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi1O000m 3 GROSS 9 IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 03-Jul-12 17(A) 14 19 14 18 22 11-Jul-12 14 15 16 16 13 12 17-Jul-1 2 9 6 11 6 7 9 24-Jul-12 9 11 6 8 11 11 30-Jul-1 2 10 9 9 9 11 16 07-Aug-1 2 14 16 12 13 10 13 14-Aug-12 18 16 16 12 16 10 21-Aug-12 10 9 10 7 9 9 27-Aug- 12 11(B) 10 8 14 8 11 04-Sep-1 2 18 23(C) 7 18 16 17 11-Sep-12 18 15 18 18 16 14 18-Sep-12 9 8 12 13 8 12 26-Sep-12 22 21 18 14 17 19 Average: 14 13 12 12 12 13 (A) Pump failed and was replaced. Estimated run time 151.3 out of 169.7 hours8.101852e-5 days <br />0.00194 hours <br />1.157407e-5 weeks <br />2.6635e-6 months <br />.

(B) No power to sample hut. Estimated run time 83.7 out of 150.4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br />.

(C) Pump failed and was replaced. Estimated run time 149.6 out of 190.8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />.

22

TABLE IV-A.3 (Cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/1000m3 GROSS 9 IN AIR SAMPLE SITE Collection Date C07 C18 C40 C41 C46 C47 02-Oct-1 2 11 11 12 17 8 7 10-Oct-1 2 10 9 9 11 7 6 17-Oct-12 29 31 34 29 25 32 23-Oct-1 2 28 23 26 25 22 23 31-Oct-12 24 24 28 25 19 24 06-Nov-12 39 36 36 36 34 36 13-Nov-12 31 35 32 29 26 29 19-Nov-12 16 19 16 17 18 18 27-Nov-12 33 38 28 32 33 28 04-Dec-1 2 44 25 24 28 22 26 11 -Dec-12 11 18 15 11 11 9 19-Dec-12 12 15(A) 16 13 14 10 26-Dec-12 16 25 19 22 18 18 Average: 23 24 23 23 20 20 (A) Estimated run time 165.6 out of 191.3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />. Unknown reason for lower run time.

23

TABLE IV-A.4 PROGRESS ENERGY FLORIDA, INC. - CR3 -2012 PCi/1000m 3 y EMITTERS IN QUARTERLY COMPOSITES OF AIR PARTICULATES STATION NUCLIDE FIRST QUARTER SECOND QUARTER THIRD QUARTER FOURTH QUARTER C07 Be-7 182 148 104 129 K-40 <9.0 <28 <18 <15 Cs-1 34 <1.1 <1.3 <1.5 <1.1 Cs-1 37 <1.0 <1.2 <1.3 <1.0 C18 Be-7 150 149 110 114 K-40 <15 <25 <15 <18 Cs-1 34 <1.0 <1.1 <1.3 <1.2 Cs-1 37 <0.7 <1.2 <1.0 <1.0 C40 Be-7 196 128 93 120 K-40 <26 <16 <19 <17 Cs-1 34 <1.5 <1.6 <1.3 <1.3 Cs-1 37 <0.8 <1.5 <1.1 <1.3 C41 Be-7 181 152 109 121 K-40 <31 <19 <19 <14 Cs-1 34 <1.3 <1.7 <1.1 <1.2 CS-137 <1.2 <1.4 <0.9 <1.1 C46 Be-7 172 161 119 105 K-40 <17 <23 <19 <12 Cs-1 34 <1.7 <1.6 <0.9 <1.3 Cs-1 37 <1.5 <1.3 <0.9 <1.0 C47 Be-7 177 150 142 117 K-40 <17 <20 <15 <15 Cs-1 34 <1.7 <1.7 <0.7 <1.4 Cs-1 37 <1.5 <1.3 <0.9 <1.0 24

Airborne (highest values plotted) 2011 Measured Values due to Fukushima Event I 1

0.1 E

0.01 C-a.

0-001 0 0001 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 I--- *--- 1-131 LLD ---1--- CS-137 LLD I 25

IV-B. DIRECT RADIATION Direct radiation measurements (using TLDs) were taken at seventeen locations (stations C60 through C73 and station C27) within one mile of the plant, at fifteen locations ranging from 2.8 to 6.3 miles from the plant, and at one control location 78 miles from the site. One-hundred and thirty-two TLDs were collected during 2012.

Table IV-B provides a statistical summary of the analytical results for 132 TLDs sampled throughout the year.

Table IV-B. 1 provides the results of the individual TLD measurements.

The highest on-site dose was 72 mrem/yr at station C71 (WNW at 3600 feet). Station C71 was relocated in 1992 due to construction of the helper cooling towers on the former site. The new location has a higher background radiation level due to being closer to the storage pond for Units 4 & 5 fly ash, which produces a higher external radiation component than normal levels of natural background. The second highest on-site dose was 56 mrem/yr at station C65 (ESE at 1584 feet).

The highest off-site dose was 51 mrem/yr at station C40 (east at 3.5 miles). The control station (C47) average dose was 51 mrem/yr. The average for all stations (except control) was 41 mrem/yr for 2012, 46 mrem/yr for 2011, and 49 mrem/yr for 2010. Direct radiation results are similar to previous years and show no change of significance.

There were no missing or unanalyzed TLDs during this evaluation period.

26

TABLE IV-B RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER LOWER LIMIT ALL INDICATOR LOCATION WITH HIGHEST MEAN CONTROL NONROUTINE SAMPLED OF ANALYSES OF DETECTION LOCATIONS MEAN NAME MEAN LOCATION REPORTED (UNITS) PERFORMED (LLD) RANGE DISTANCE & BEARING RANGE MEAN MEASUREMENTS RANGE DIRECT y DOSE, 132 15 41 (128/128) C71 65 (4/4) 51(4/4) 0 RADIATION (29- 72) 0.6 @ 2960 (60- 72) (43- 57)

(mrem/yr) 27

TABLE IV-B.1 PROGRESS ENERGY FLORIDA, INC. - CR 2012 mrem/yr y Dose TLD STATION Quarter 1 2 3 4 Co1 47 39 32 31 C03 35 39 34 32 C04 32 39 31 31 C07* 31 37 32 31 C08 29 36 31 30 C09 31 39 32 30 C14G 39 45 40 37 C18 37 42 34 35 C27 45 53 46 42 C40* 46 51 44 43 C41 43 50 42 40 C46* 41 48 41 40 C47 (CONTROL) 50 57 53 43 C60 40 47 39 37 C61 41 49 44 40 C62 49 53 47 46 C63 43 50 42 40 C64 40 47 40 38 C65 47 56 48 46 C66 42 48 43 42 C67 46 51 43 44 C68 41 48 42 41 C69 44 51 43 43 C70 46 51 44 44 C71 66 72 61 60 C72 42 49 43 44 C73 40 45 39 38 C74 30 36 31 30 C75 40 46 38 35 C76 36 42 36 34 C77 37 42 37 36 C78 32 37 31 30 C79 36 42 35 35

  • TLDs not required by the ODCM.

28

Direct Radiation 100 E

E 1988198919901991 19921993199419951996199719981999200020012002 2003200420052006 200720082009201020112012

-B- TLD Average of All Stations 29

IV-C. WATERBORNE PATHWAY To evaluate the waterborne pathway, samples are taken of seawater, ground water, drinking water, and shoreline sediment.

1. Monthly seawater grab samples are taken at two locations in the discharge canal (C14G and C14H) and at one control location (Cl 3) near the mouth of the intake canal.

In 2012, of twenty-four indicator samples, six had measurable tritium at an average concentration of 125 pCi/L, with a range of 118 to 152 pCi/L. The sample with the highest concentration of tritium was obtained in December at station C14H near the beginning of the discharge canal. The seawater tritium activity is consistent with the concentration of tritium in the liquid waste stream and the release times of waste tanks.

CR-3 was in Refuel 16 outage at the time of sampling with reduced dilution due to no circulating water pumps running. Plant raw water pumps were providing the dilution flow. In 2012 three control station samples had measurable tritium concentrations at an average of 107 pCi/l.

In 2011, five of twenty four indicator samples contained measurable tritium with an average concentration of 190 pCi/L. The 2011 control station samples had measurable tritium concentrations at an average of168 pCi/L.

Gamma spectral analysis was performed on thirty-six samples, none of which showed measurable amounts of the gamma emitters of interest.

Table IV-C. 1 provides a statistical summary of the seawater tritium and gamma spectroscopy results.

Table IV-C.1 .a provides the results of the monthly samples.

2. Semiannual ground water samples are taken at one location, station C40, located approximately 3.5 miles east of CR-3. Gamma spectral and tritium analyses are performed on both samples.

In 2012, all results were less than the detection limits. Since plant startup, all results, except for the results of one 1985 tritium analysis, have been less than LLD. The required sensitivity for measuring tritium in ground water is 2000 pCi/L. Analysis of ground water in the vicinity of CR-3 is done at a sensitivity of approximately 150 pCi/L for tritium and less than 10 pCi/L for select gamma emitters. Additionally, Potassium-40, a natural product, was detected in the first sample collected in 2012. In the second sample collected, K-40 was <LLD.

Table IV-C.2 provides a statistical summary of the groundwater tritium and gamma spectroscopy results.

Table IV-C.2.a provides the results of the semi-annual samples.

3. Quarterly site ground water samples are taken at nine locations surrounding the perimeter of the CR-3 protected area. Periodically five of these ground water wells have shown indications of very low levels of tritium on the west-southwest side of the plant. It is believed that this tritium is the result of a leak in the Station Drain Tank (SDT-1) to the settling pond discharge line that occurred in 1998. This discharge line has recently been leak tested and it is leak free. There are no other know leaking plant components.

In 2012 the wells that have shown measurable amounts of tritium range from 72 to 619 pCi/L. These wells have been sampled additionally on a monthly basis to develop trend data. This increased sampling information is shown as supplemental data. Along with these wells, two other wells that are not presently part of the REMP have been sampled that are on either side of the plant settling ponds (percolation ponds).

In 2012 these two wells are showing measurable amounts of tritium in the range of 95 to 182 pCi/L, which are a result of plant discharges from the SDT-1. These discharges are being minimized through operational focus. The positively measured tritium values are below the reporting criteria of the ODCM and the NEI 07-07 Ground Water Protection Initiative Guidelines. There have been no measurable amounts of gamma emitting radionuclides in any of these wells. There have been no measurable amounts of hard-to-detect (HTD) radionuclides in any of these wells with exception of trace levels of gross alpha, which is expected, given the naturally occurring limestone strata that surrounds the Florida aquifer. It should be noted that site ground water flows in a west-southwest direction toward the Gulf of Mexico. This flow was re-verified in 2006 with a new ground water flow study performed by a certified hydro-geologist as part of the NEI Ground Water Protection Initiative. In 2012 another groundwater flow study was performed to evaluate groundwater flow post installation of CR Units 4 & 5 clean air scrubber system. This scrubber system utilizes significant groundwater from the Florida aquifer. The flow study confirmed that the groundwater flow, and direction of flow, has not been altered due to the installation and operation of the clean air scrubber system.

30

IV-C. WATERBORNE PATHWAY Cont'd Additionally, the groundwater at the CR3 site is too saline for use as a potable water source, hence there is no drinking water uptake pathway at the Crystal River site.

Table IV-C.3. provides a statistical summary of the groundwater tritium and gamma spectroscopy results.

Table IV-C.3.a.1 provides the results of the quarterly samples.

Table IV-C.3.a.2 provides the results of the monthly supplemental samples.

4. Monthly non-REMP required well samples were collected as discussed in item #3 above. Two wells were sampled. These two wells are located on the north side and the south side of the site percolation ponds.

The information is discussed above. Both of these wells showed no measurable amounts of any other radionuclides of interest. The tritium concentration in these wells, discussed in item #3 above, have decreased significantly due to a focused reduction in the number of discharges from the station drain tank (SDT-1) to the site settling ponds (percolation ponds).

Table IV-C.4 provides a statistical summary of the groundwater tritium and gamma spectroscopy results.

Table IV-C.4.a. provides the results of the monthly supplemental non-REMP required samples.

5. Quarterly drinking water samples are drawn from three locations: the Crystal River City Hall (C07), the Days Inn Motel (C10), and the Yankeetown City Well (C18). All samples were collected and analyzed for gamma emitters and tritium.

In 2012, none of the samples yielded measurable activities of tritium or the required gamma emitters. The measurement sensitivity for drinking water samples are the same as those for ground water samples. Note that one sample collected at station C07 yielded a statistically positive-measured tritium concentration of 77 pCi/L, which is well below the LLD of 150 pCi/L. This sample set (all three stations) was split with an independent lab to run tritium analyses. The independent lab tritium results of all three samples indicated

<LLD of 150 pCi/L. It is felt that the one sample measurement of 77 pCi/L is an outlier and is of no consequence.

Since the beginning of sampling, the drinking water samples have not had any other positive-measured radionuclides of interest detected.

Table IV-C.5 provides a statistical summary of the drinking water tritium and gamma spectroscopy results.

Table IV-C.5.a provides the results of the quarterly samples.

6. Semiannual shoreline sediment samples are taken at three indicator locations in the discharge canal (C14H, C14M, C14G) and one control location (C09) at Fort Island Gulf Beach. The plant discharge canal is the primary liquid effluent release pathway from CR-3.

In 2012, of the six indicator samples, three had measurable amounts of cesium-137 with an average concentration of 28 pCi/kg and a range of 19 to 35 pCi/kg and three had measurable amounts of cobalt-60 with a concentration range of 14 to 24 pCi/kg.

In 2011 two samples had measurable amounts of cesium-1 37 with an average of 26 pCi/kg and a range of 14 to 37 pCi/kg. Also there were three samples with measurable amounts of cobalt-60 with a concentration range of 11 to 65 pCi/kg.

In 2010 the average cesium-137 concentration at the indicator locations was 19 pCi/kg.

In 2009, the average cesium-1 37 concentration at the indicator locations was 24 pCi/kg.

In 2008, the average cesium-1 37 concentration at the indicator locations was 25 pCi/kg.

The average cobalt-60 concentration at the indicator locations ranged from 30 to 389 pCi/kg from 1998 through 2007.

The 2012 results are similar to previous years' results. None of the samples taken at Fort Island Gulf Beach, the control location station C09, indicated measurable amounts of cobalt or cesium.

31

Table IV-C.6 provides a statistical summary of the shoreline sediment gamma spectroscopy results.

Table IV-C.6.a provides the results of the semi-annual samples.

7. Additional samples taken in 2012 but not required by the ODCM:

Annual sediment samples were collected at four locations in the site settling ponds. Cs-1 37 was detected in two of the four samples in concentrations ranging from 10 to 16 pCi/kg. There were no measurable amounts of Co-60 or Cs-1 34 in any of the samples.

Annual surface water samples were collected at two locations in the site settling ponds. The tritium concentration was < LLD of 152 pCi/L in three of four samples. One sample in the northeast quadrant has a measurable amount of tritium at a concentration of 233 pCi/L. All of the samples showed no measurable amounts of any other radionuclides of interest. Note that two of the four surface water samples were collected in January of 2013 due to the settling ponds being drained for maintenance in December of 2012.

Table IV-C.7 provides the results of the settling pond samples.

8. There were no unmonitored spills or releases of radioactive material in 2012 that could have the potential to contaminate the ground water per the guidelines of the Nuclear Energy Institute Ground Water Protection Initiative - Final Guidance Document 07-07. As such, there were no communiques issued to state, local, or regulatory agencies.

32

TABLE IV-C.1 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS SEAWATER Tritium, 36 148 125(6/24) C14H 152 (4/12) 107(3/12) 0 (pCi/L) (118-152) 0.1 @ 00 (<LLD-152) (92-132) y Spec, 36 Mn-54 5 <LLD <LLD 0 Fe-59 12 <LLD <LLD 0 Co-58 6 <LLD <LLD 0 Co-60 7 <LLD <LLD 0 Zn-65 12 <LLD <LLD 0 Zr-Nb-95 10 <LLD <LLD 0 1-131 8 <LLD <LLD 0 Cs-134 6 <LLD <LLD 0 Cs-137 5 <LLD <LLD 0 Ba-La-140 15 <LLD <LLD 0 1

The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

33

TABLE IV-C.l.a PROGRESS ENERGY FLORIDA, INC. - CR3 -2012 pCi/L y EMITTERS AND TRITIUM IN SEAWATER STATION MONTH H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C13 JAN <147 331+/-32 <4 <3 <7 <5 <7 <6 <5 <5 <5 <9 FEB <147 359+/-31 <4 <3 <8 <6 <9 <9 <5 <5 <5 <8 MAR <148 341+/-38 <4 <4 <10 <7 <11 <7 <4 <5 <5 <15 APR <140 167+/-18 <3 <4 <8 <4 <8 <7 <5 <4 <4 <7 MAY 98+/-44 361+/-33 <4 <3 <6 <4 <7 <7 <5 <5 <5 <6 JUN <146 251+/-13 <2 <2 <5 <2 <5 <4 <2 <2 <2 <8 JUL 92+/-43 367+/-34 <3 <4 <7 <5 <6 <7 <5 <4 <4 <10 AUG <139 199+/-95 <3 <3 <6 <4 <7 <5 <3 <3 <3 <11 SEP <141 361+/-24 <3 <3 <7 <3 <8 <6 <4 <4 <4 <7 OCT 132+/-45 186+/-21 <3 <3 <6 <3 <6 <6 <3 <3 <3 <9 NOV <137 314+/-33 <4 <4 <8 <4 <7 <7 <6 <5 <5 <5 DEC <128 296+/-30 <4 <4 <6 <4 <9 <6 <5 <4 <4 <5 C14G JAN <147 270+/-31 <4 <4 <6 <4 <7 <7 <6 <5 <4 <8 FEB <147 222+/-16 <3 <4 <7 <3 <10 <6 <4 <4 <4 <6 MAR <148 223+/-16 <3 <3 <7 <4 <7 <6 <3 <4 <3 <10 APR <140 382+/-34 <3 <4 <7 <4 <8 <7 <6 <4 <4 <7 MAY 93+/-44 233+/-77 <3 <3 <8 <4 <8 <6 <4 <4 <4 <6 JUN <146 345+/-36 <4 <4 <8 <6 <9 <7 <4 <4 <5 <14 JUL <132 195+/-48 <5 <6 <12 <7 <12 <9 <6 <6 <5 <11 AUG <139 301+/-33 <3 <4 <8 <4 <9 <6 <4 <4 <4 <12 SEP <145 294+/-32 <4 <3 <8 <4 <8 <5 <4 <3 <3 <7 OCT <135 296+/-33 <3 <3 <9 <4 <8 <7 <5 <5 <4 <9 NOV <137 295+/-31 <4 <2 <8 <5 <9 <7 <7 <4 <4 <5 DEC 133+/-43 310+/-34 <3 <3 <7 <4 <8 <5 <5 <4 <3 <8 34

TABLE IV-C.la (CONT'D)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN SEAWATER STATION MONTH H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C14H JAN <147 308+/-17 <2 <2 <3 <2 <4 <3 <2 <2 <2 <3 FEB 124+/-48 362+/-33 <4 <3 <6 <4 <8 <6 <5 <4 <4 <7 MAR <148 348+/-34 <3 <4 <6 <6 <8 <6 <5 <5 <4 <12 APR <140 292+/-30 <4 <3 <8 <4 <8 <6 <4 <4 <3 <6 MAY 118+/-45 380+/-30 <3 <4 <8 <5 <8 <8 <6 <5 <3 <6 JUN <146 327+/-29 <4 <4 <7 <4 <8 <7 <4 <4 <4 <12 JUL 129+/-44 158+/-19 <4 <4 <8 <5 <7 <6 <5 <4 <3 <7 AUG <139 161+/-35 <5 <4 <7 <5 <10 <10 <5 <6 <5 <15 SEP <141 207+/-26 <3 <4 <8 <4 <9 <6 <4 <4 <4 <7 OCT <138 263+/-27 <3 <3 <7 <4 <7 <5 <4 <3 <4 <4 NOV <137 298+/-30 <4 <3 <8 <4 <8 <6 <8 <5 <4 <6 DEC 152+/-43 329+/-37 <4 <3 <7 <5 <8 <6 <5 <6 <4 <9 35

Seawater 10000 1000

-a 100 U I2 0.

- - a -v - - w --

10 1

1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 1 A-H-3 ---4----Cs-134LLD ---!W---Cs-137LLD I 36

TABLE IV-C.2 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED 1

(UNITS) PERFORMED (LLD) RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS GROUND Tritium, 2 150 <LLD <LLD 0 2

WATER (pCi/L) Y Spec, 2 Mn-54 4 <LLD .... <LLD 0 Fe-59 7 <LLD .... <LLD 0 Co-58 4 <LLD .... <LLD 0 Co-60 4 <LLD .... <LLD 0 Zn-65 14 <LLD .... <LLD 0 Zr-Nb-95 7 <LLD .... <LLD 0 1-131 5 <LLD .... <LLD 0 Cs-134 5 <LLD .... <LLD 0 Cs-137 5 <LLD .... <LLD 0 Ba-La-140 9 <LLD .... <LLD 0

'The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

2 There is no drinking water uptake pathway at the Crystal River site.

37

TABLE IV-C.2.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN GROUND WATER STATION NUCLIDE FIRST HALF SECOND HALF C40 H-3 <150 <139 Mn-54 <4 <4 Fe-59 <7 <7 Co-58 <3 <4 Co-60 <4 <4 Zn-65 <7 <14 Zr-Nb-95 <7 <7 1-131 <5 <5 Cs-134 <5 <4 Cs-137 <5 <4 Ba-La-140 <9 <9 K-40 66+/-19 <39 38

Ground Water 1000 100

,I 0I.

10

1. "1 .... *f. U ""

1 I I I I I I t 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 S--- H-3LLD ---*--- Cs-137 LLDI 39

TABLE IV-C.3 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL (NUMBER) 2 LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED (UNITS) OF ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED 1

PERFORMED (LLD) RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS CR3 SITE Tritium 76 150 228 (47/76) CR3-5 517(12/12) CR3-2 0 GROUND WATER (77-619) 0.051 mi.@225° (363-619) <LLD (pCi/L) y Spec 76 Mn-54 5 <LLD .... <LLD 0 Fe-59 12 <LLD .... <LLD 0 Co-58 5 <LLD .... <LLD 0 Co-60 6 <LLD .... <LLD 0 Zn-65 18 <LLD .... <LLD 0 Zr-Nb-95 11 <LLD .... <LLD 0 1-131 9 <LLD .... <LLD 0 Cs-134 8 <LLD .... <LLD 0 Cs-137 6 <LLD .... <LLD 0 Ba-La-140 15 <LLD .... <LLD 0 1

The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

2 Includes extra samples collected for data trending.

40

TABLE IV-C.3.a.1 PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C3-2 01-04 <147 <85 <5 <5 <10 <4 <8 <10 <9 <6 <5 <5 04-03 <140 83+/-16 <4 <4 <8 <3 <9 <8 <8 <4 <5 <8 07-05 <132 <48 <5 <5 <9 <4 <19 <8 <8 <5 <5 <8.

10-01 <135 <61 <4 <3 <7 <5 <10 <7 <7 <4 <5 <6 C3-4 01-04 <147 <52 <4 <4 <9 <4 <13 <8 <6 <4 <4 <7 04-03 75+/-26 55+/-18 <3 <3 <8 <3 <8 <7 <8 <5 <5 <6 07-05 <132 <61 <3 <4 <7 <4 <6 <6 <6 <4 <4 <7 10-01 <138 62+/-11 <2 <2 <5 <3 <5 <4 <4 <3 <3 <4 C3-5 01-04 548+/-58 <83 <5 <5 <10 <3 <8 <8 <8 <5 <4 <8 04-03 619+/-58 87+/-13 <2 <2 <5 <3 <5 <4 <4 <3 <3 <4 07-05 468+/-55 <67 <4 <4 <8 <4 <9 <6 <4 <5 <4 <11 10-01 363+/-51 82+/-21 <3 <4 <8 <5 <7 <7 <6 <4 <4 <7 41

TABLE IV-C.3.a.l(cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C3-6S 01-04 <147 <53 <4 <4 <7 <4 <14 <7 <5 <4 <5 <9 04-03 146+/-46 <45 <4 <4 <7 <4 <13 <5 <5 <4 <4 <6 07-05 102+/-43 <88 <5 <5 <12 <5 <12 <9 <8 <8 <5 <9 10-01 91+/-44 <75 <4 <4 <8 <4 <10 <5 <6 <5 <4 <7 C3-6D 01-04 <147 140+/-15 <4 <4 <8 <4 <12 <7 <6 <4 <4 <7 04-03 98+/-26 251+/-19 <3 <2 <5 <3 <6 <5 <4 <3 <3 <4 07-05 <144 259+/-26 <4 <4 <6 <5 <6 <7 <6 <4 <4 <6 10-01 <135 <28 <4 <4 <7 <4 <11 <6 <5 <4 <4 <6 C3-7 01-04 177+/-49 <47 <3 <3 <7 <3 <8 <6 <7 <3 <3 <5 04-03 139+/-46 32+/-8 <4 <4 <9 <4 <11 <7 <5 <4 <4 <7 07-05 130+/-27 <40 <3 <4 <7 <3 <9 <6 <5 <4 <3 <5 10-01 192+/-46 19+/-5 <2 <2 <5 <2 <7 <4 <3 <2 <2 <4 42

TABLE IV-C.3.a.l(cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C3-8 01-04 <147 <83 <5 <5 <10 <7 <12 <11 <9 <6 <5 <10 04-03 132+/-46 128+/-22 <4 <4 <6 <5 <8 <7 <5 <4 <4 <7 07-05 169+/-45 <62 <4 <4 <10 <3 <8 <7 <6 <4 <4 <8 10-02 158+/-46 <52 <5 <4 <8 <4 <15 <7 <5 <4 <5 <8 C3-9 01-04 <147 <52 <4 <5 <7 <4 <16 <7 <5 <4 <5 <10 04-03 103+/-26 31+/-7 <4 <4 <7 <4 <13 <6 <5 <4 <4 <7 07-05 92+/-43 32+/-5 <3 <3 <5 <3 <9 <4 <3 <3 <3 <8 10-02 <150 29+/-7 <1 <1 <2 <1 <2 <1 <3 <1 <1 <2 C3-10 01-04 <147 <53 <4 <5 <8 <5 <14 <7 <7 <5 <4 <7 04-03 78+/-26 <39 <4 <3 <8 <4 <9 <6 <6 <4 <3 <6 07-05 112+/-43 <54 <4 <5 <9 <5 <18 <8 <8 <5 <5 <8 10-02 <138 <47 <4 <4 <7 <4 <14 <7 <5 <4 <4 <7 43

TABLE IV-C.3.a.2 PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER (SUPPLEMENTAL DATA)

STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C3-5 02-01 521+/-58 <62 <5 <5 <11 <6 <12 <8 <5 <4 <6 <12 03-07 580+/-59 <65 <4 <4 <7 <5 <8 <7 <4 <5 <4 <13 05-08 568+/-56 <20 <4 <4 <7 <4 <14 <6 <4 <4 <4 <13 06-06 482+/-56 <34 <3 <3 <5 <3 <10 <4 <3 <3 <3 <8 08-06 531+/-55 <51 <4 <4 <8 <4 <14 <6 <5 <4 <4 <9 09-05 551+/-56 <76 <3 <4 <9 <5 <6 <6 <7 <5 <4 <6 11-07 442+/-53 <44 <2 <2 <6 <2 <5 <5 <5 <2 <3 <4 12-04 532+/-53 132+/-22 <4 <4 <8 <3 <9 <7 <5 <6 <4 <10 C3-6S 02-01 <150 <49 <4 <5 <8 <4 <15 <7 <5 <4 <4 <10 03-07 <148 <84 <4 <4 <11 <6 <11 <9 <5 <6 <6 <15 05-08 115+/-45 120+/-18 <4 <4 <7 <5 <8 <6 <4 <5 <5 <13 06-06 <146 25+/-7 <5 <4 <7 <4 <14 <7 <4 <4 <4 <13 08-06 <139 97+/-20 <3 <3 <7 <3 <6 <6 <4 <4 <3 <7 09-05 <141 <51 <4 <4 <8 <4 <14 <7 <4 <4 <4 <13 11-07 115+/-45 <37 <2 <2 <5 <3 <5 <4 <4 <3 <3 <4 12-04 77+/-25 <75 <4 <4 <8 <4 <9 <7 <6 <6 <5 <10 44

TABLE IV-C.3.a.2(cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCilL y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER (SUPPLEMENTAL DATA)

STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C3-7 02-01 139+/-49 125+/-16 <3 <4 <8 <3 <7 <6 <5 <4 <4 <9 03-07 140+/-49 <79 <5 <5 <9 <6 <10 <8 <6 <6 <6 <12 05-08 162+/-46 114+/-18 <4 <3 <6 <3 <6 <6 <5 <4 <4 <15 06-06 138+/-48 99+/-15 <3 <3 <5 <3 <6 <4 <6 <4 <3 <4 08-06 96+/-45 <71 <4 <4 <7 <4 <8 <7 <5 <5 <4 <7 09-05 219+/-49 <45 <4 <4 <6 <4 <11 <6 <4 <4 <3 <8 11-07 238+/-48 <35 <3 <3 <5 <3 <6 <4 <4 <2 <3 <4 12-04 169+/-44 <40 <3 <3 <6 <3 <5 <5 <4 <3 <3 <8 C3-8 02-01 <150 <57 <4 <4 <9 <5 <9 <6 <5 <4 <4 <9 03-07 <148 111+/-14 <3 <3 <6 <3 <6 <6 <5 <4 <4 <12 05-08 152+/-46 <19 <4 <4 <8 <4 <17 <6 <4 <4 <4 <14 06-06 103+/-47 41+/-7 <4 <4 <7 <4 <15 <6 <4 <4 <4 <10 08-06 110+/-45 16+/-5 <4 <4 <7 <3 <14 <6 <4 <4 <4 <7 09-05 113+/-45 <56 <4 <5 <9 <4 <17 <7 <6 <5 <5 <10 11-07 153+/-46 <39 <3 <3 <6 <3 <6 <5 <5 <2 <3 <5 12-04 113+/-42 <53 <5 <5 <9 <5 <18 <8 <6 <5 <5 <9 45

TABLE IV-C.3.a.2(cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER (SUPPLEMENTAL DATA)

STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C3-9 02-01 <150 44+/-10 <4 <5 <9 <4 <16 <8 <6 <5 <5 <11 03-07 <148 <49 <4 <4 <7 <4 <14 <7 <4 <4 <4 <14 05-08 <138 36+/-8 <4 <4 <7 <4 <16 <6 <4 <4 <4 <15 06-06 <146 152+/-18 <3 <3 <5 <3 <6 <5 <4 <3 <3 <9 08-06 <139 <73 <4 <4 <8 <4 <7 <7 <5 <4 <4 <7 09-05 <141 19+/-6 <3 <3 <7 <4 <10 <6 <6 <4 <4 <5 11-07 98+/-44 <36 <3 <2 <5 <2 <5 <4 <5 <3 <2 <4 12-04 79+/-25 <19 <3 <3 <6 <3 <6 <5 <4 <3 <3 <6 46

Tritium Measurement GW Well # CR3-2 All results are < LLD unless noted 180 160 I

140 120 100 a

80-60 -

40 -

20 -

0-10/10/06 2122/08 7/6/09 11/18/10 411/12 8/14/13 47

Tritium Measurement GW Well # CR3-4 All results are < LLD unless noted 180 160 140 120 100

+ Measurement C

0.

80 60 40 20 0

10110/06 2/22/08 7/6109 11/18/10 4/11/12 8/14/13 48

Tritium Measurement GW Well # CR3-5 2500 2000 1500 CL 1000 500 7EFT-2 Isolated 1/24/12 0

10110/06 02/22/08 07/06/09 11/18/10 04/01/12 08/14/13 49

Tritium Measurement GW Well # CR3-6S All results are < LLD unless noted 200 -

180 160 140 120 I~~ I Vl}

0.

100 + measurement 80 x uremen1Zt

+ measurement

+ measurement +-measurement 60 40 20 0

10/10/06 02/22/08 07/06/09 11/18/10 04/01/12 08/14/13 50

Tritium Measurements GW Well # CR3-6D All results are < LLD unless noted 160 140 120 100 + measurements 80 60 40 20 0

10/10/06 2/22/08 7/6/09 11/18110 411/12 8/14/13 51

Tritium Measurements GW Well # CR3-7 800O 700 600 -__

500 -

0400 -

300 - - _

200 100 < LL 0

10/10/06 02/22/08 07/06/09 11/18/10 04/01/12 08/14/13 52

Tritium Measurements GW Well # CR3-8 250 200 150 100 50 0

10/10106 02/22/08 07106109 11/18/10 04/01/12 08114113 53

Tritium Measurements GW Well # CR3-9 All results are < LLD unless noted 200 180 160 140 120 00 +Emeasurement___

+ measurmn 80 60 - + meaureen 40 -

20 0

10/10/06 02/22/08 07/06/09 11/18/10 04/01/12 08/14/13 54

Tritium Measurements GW Well # CR3-10 All results are < LLD unless noted 180 160 '1 140 120 100 1000n C.

80 4* + measurement 60 40 20 01 10/10/06 2/22/08 7/6/09 11/18/10 411/12 8/14/13 55

TABLE IV-C.4 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN LOCATION REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE MEAN MEASUREMENTS RANGE

  • CR3 SITE Tritium 24 150 125 (9/24) MWC-IF2 125 (7/12) CR3-2 D GROUND WATER (95-182) 0.30 mi.@266° (<LLD-182) <LLD (pCi/L) * - Spec 24 Mn-54 4 <LLD <LLD 0 Fe-59 9 <LLD <LLD 0 Co-58 5 <LLD <LLD 0 Co-60 6 <LLD <LLD 0 Zn-65 16 <LLD <LLD 0 Zr-Nb-95 8 <LLD <LLD 0 1-131 8 <LLD <LLD 0 Cs-134 6 <LLD <LLD 0 Cs-137 6 <LLD <LLD 0 Ba-La-140 14 <LLD <LLD 0 The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.
  • Non-REMP required samples 56

TABLE IV-C.4.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER (SUPPLEMENTAL DATA)

STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 MWC-27* 01-04 <147 <20 <2 <2 <3 <2 <6 <3 <2 <2 <2 <4 02-01 <150 <36 <3 <3 <6 <3 <12 <5 <4 <4 <4 <7 03-07 <148 <46 <4 <4 <7 <4 <16 <6 <4 <4 <5 <14 04-03 <140 68+/-22 <3 <3 <7 <5 <9 <7 <8 <4 <3 <6 05-08 142+/-46 62+/-16 <4 <4 <8 <4 <10 <7 <6 <6 <5 <13 06-06 <146 <85 <5 <4 <9 <6 <9 <8 <5 <6 <5 <13 07-05 <144 62+/-9 <4 <4 <7 <3 <12 <7 <6 <4 <4 <7 08-06 <139 <32 <3 <3 <5 <3 <10 <5 <4 <3 <3 <7 09-05 <141 <48 <4 <4 <8 <4 <16 <6 <5 <4 <5 <9 10-02 <135 <21 <4 <4 <8 <4 <14 <6 <5 <4 <4 <6 11-07 <137 79+/-19 <4 <4 <8 <5 <8 <7 <8 <4 <4 <6 12-04 108+/-42 15+/-4 <2 <2 <4 <2 <4 <3 <2 <2 <2 <4

  • = These wells are not officially included in the REMP and are located on either side of the site percolation ponds.

57

TABLE IV-C.4.a(cont'd)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN CR3 SITE GROUND WATER (SUPPLEMENTAL DATA)

STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 MWC-IF2* 01-04 <147 <76 <5 <5 <9 <5 <10 <8 <8 <5 <6 <6 02-01 103+/-48 <44 <4 <4 <8 <4 <14 <6 <5 <4 <4 <9 03-07 109+/-48 104+/-1E <3 <3 <6 <4 <8 <5 <5 <4 <4 <14 04-03 97+/-45 <55 <4 <4 <9 <4 <14 <7 <5 <5 <5 <8 05-08 115+/-45 <64 <3 <3 <7 <4 <7 <6 <5 <4 <4 <14 06-06 <146 105+/-17 <4 <4 <8 <5 <9 <7 <4 <5 <5 <14 07-05 <144 <67 <4 <3 <9 <3 <6 <8 <6 <5 <4 <5 08-06 <139 113+/-1ý <3 <4 <6 <3 <7 <6 <5 <4 <4 <8 09-05 <141 <28 <2 <2 <4 <2 <8 <4 <3 <2 <2 <7 10-02 182+/-46 <46 <4 <4 <6 <4 <12 <6 <4 <4 <4 <7 11-07 95+/-44 <38 <2 <2 <6 <3 <6 <4 <4 <2 <2 <3 12-04 174+/-44 <38 <3 <3 <6 <3 <6 <5 <3 <3 <3 <7

  • = These wells are not officially included in the REMP and are located on either side of the site percolation ponds.

58

Tritium Measurements GW Well # MWC-27 1400 1200 1000 800 C.

600 400 V

200 I 0

10110/06 02*22/08 07/06/09 11/18/10 04/01/12 08/14/13 59

Tritium Measurements GW Well # MWC4F2 600 500 400 0300 C.L 200 100 0 -

10/10/06 02/22/08 07/06/09 11/18110 04/01/12 08/14/13 60

TABLE IV-C.5 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS DRINKING Tritium 12 150 <LLD - <LLD 0 WATER (pCi/L) y Spec 12 Mn-54 5 <LLD - <LLD 0 Fe-59 11 <LLD - <LLD 0 Co-58 5 <LLD - <LLD 0 Co-60 7 <LLD - <LLD 0 Zn-65 12 <LLD - <LLD 0 Zr-Nb-95 11 <LLD - <LLD 0 1-131 8 <LLD - <LLD 0 Cs-134 8 <LLD - <LLD 0 Cs-1 37 7 <LLD - <LLD 0 Ba-La-140 11 <LLD - <LLD 0 The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

61

TABLE IV-C.5.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN DRINKING WATER STATION DATE H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zn-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 C07 01-10 <146 <39 <3 <3 <6 <3 <9 <6 <3 <3 <3 <11 04-02 <140 <23 <2 <2 <4 <2 <5 <3 <2 <2 <2 <4 07-03 <132 <39 <3 <4 <7 <3 <8 <6 <4 <4 <4 <6 10-01 77+/-32 <34 <3 <3 <5 <3 <6 <5 <4 <3 <3 <5 C1o 01-10 <146 <23 <2 <2 <4 <2 <5 <3 <2 <2 <2 <6 04-02 <146 <96 <5 <5 <11 <5 <11 <10 <8 <7 <6 <10 07-03 <143 <71 <4 <4 <8 <4 <9 <7 <6 <5 <4 <10 10-01 <138 <59 <4 <3 <8 <3 <8 <7 <5 <4 <3 <8 C18 01-10 <146 <61 <4 <3 <6 <4 <7 <6 <5 <4 <5 <7 04-02 <146 <89 <5 <4 <8 <7 <12 <11 <6 <7 <7 <8 07-03 <143 <93 <5 <5 <10 <5 <11 <7 <6 <8 <6 <8 10-01 <138 <46 <4 <3 <6 <3 <8 <6 <5 <3 <4 <5 This sample was split with an independent lab. The independent lab's result was <LLD of 150 pCi/l.

62

Drinking Water 1000 100 L-10 a.

1 0-1 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 I - H-3 LLD ---U--- Cs-137 LLD 63

TABLE IV-C.6 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION LOCATIONS MEAN NAME MEAN MEAN REPORTED 1

(UNITS) PERFORMED (LLD) RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS SHORELINE y Spec 8 SEDIMENT (pCi/kg) Cs-1 34 20 <LLD - - <LLD 0 Cs-137 20 28(3/6) C14G 35 (1/2) <LLD 0 (19-35) 2.5 @ 2700 (<LLD-35) 1 The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

64

TABLE IV-C.6.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/kg y EMITTERS IN SHORELINE SEDIMENT STATION PERIOD Co-58 Co-60 Cs-134 Cs-137 K-40 Ra-226 C09 First Half <9 <9 <14 <10 488+/-59 941+163 Second Half <9 <9 <10 <8 213+26 217+/-50 C14H First Half <18 <17 <20 <20 862+58 1473+202 Second Half <6 <9 <14 <11 <216 601+134 C14M First Half <14 24+/-2 <16 31+/-3 1290+72 1278+153 Second Half <15 14+/-2 <15 19+/-3 637+50 <200 C14G First Half <10 17+/-3 <20 35+/-5 469+/-62 1473+202 Second Half <12 <11 <12 <12 335+61 2063+217 C09 is the control station at Ft. Island Beach. C14H, C14M, & C14G are discharge canal stations.

65

Shoreline Sedimnt 1000 100 E

CL 10 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 20002001 2002 2003 2004 2005 2006 2007 2008 20092010 2011 2012 1 6 Cs-134 LLD ---fa--- Cs-137 I 66

TABLE IV-C.7 SUPPLEMENTAL DATA PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/L y EMITTERS AND TRITIUM IN SITE SETTLING PONDS SURFACE WATER STATION MONTH H-3 K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Zr-Nb-95 1-131 Cs-134 Cs-137 Ba-La-140 31NE DEC 233+/-48 N/A <2 <2 <4 <2 <5 <4 <3 <2 <2 <8 31NE JAN <152 N/A <4 <3 <8 <4 <7 <7 <5 <5 <5 <10 32NE DEC <138 N/A <3 <3 <7 <4 <8 <5 <4 <3 <4 <3 32NE JAN <152 N/A <3 <4 <7 <3 <10 <5 <4 <3 <3 <3

  • Samples actually collected in 2013 due to maintenance being performed on ponds causing them to be not in use in late December 2012.

pCilkg y EMITTERS IN SITE SETTLING PONDS SEDIMENT STATION MONTH Co-58 Co-60 Cs-134 Cs-137 K-40 Ra-226 31NE DEC <10 <9 <12 <14 768+/-68 1413+/-149 31NW DEC <12 <12 <11 16+3 1488+/-77 2365+/-222 32NE DEC <8 <7 <10 <9 <132 1120+/-137 32NW DEC <8 <8 <7 10+2 252+/-29 462+/-108 67

IV-D. INGESTION PATHWAY To evaluate the ingestion pathway, samples are taken of fish, oysters, broad leaf vegetation, citrus, and watermelon.

1. Quarterly carnivorous fish samples were taken at two locations: C29 at the end of the discharge canal, and C30, the control location, near the mouth of the intake canal.

In 2012, none of the required radionuclides were found in measurable quantities. The highest cesium-1 37 LLD for station C29 was 32 pCi/kg. Naturally occurring potassium-40 was quantified in all eight samples at an average concentration of 2659 pCi/kg.

In 2011, none of the radionuclides of interest were identified in measurable quantities.

In 2010, none of the radionuclides of interest were identified in measurable quantities.

In 2009, none of the radionuclides of interest were identified in measurable quantities.

Table IV-D.1 provides a statistical summary of the carnivorous fish gamma spectroscopy results.

Table IV-D.1 .a provides the results of the quarterly samples.

2. Quarterly oyster samples were taken at the same locations as fish samples, C29 and C30.

In 2012, of the isotopes required to be evaluated, one sample from station C29 indicated measurable amounts of cesium-1 37 at a concentration of 22 pCi/L. This value was statistically positive, but is in the range of the analytical LLD. Additionally, silver-11Om was not quantified in any sample.

In 2011, silver-i 1Om was quantified in two samples at C29 with an average concentration of 19 pCi/kg and a range of 14 to 23 pCi/kg. There were no other radionuclides of interest identified in any oyster samples in 2011.

In 2010, silver-1 I Om was not quantified in any oyster samples collected. There were no other radionuclides of interest identified in any oyster samples in 2010.

In 2009, silver-i 1Om was quantified in one sample at location C29 near the end of the discharge canal, at a concentration of 20 pCi/kg. There were no other radionuclides of interest identified in any oyster samples in 2009.

Table IV-D.2 provides a statistical summary of the oyster gamma spectroscopy results.

Table IV-D.2.a provides the results of the quarterly samples.

3. Monthly broad leaf vegetation samples were taken at two indicator locations, C48A and C48B, and one control location, C47.

In 2012, thirteen of twenty four indicator samples had measurable amounts of cesium-1 37 with an average concentration of 86 pCi/kg and a range of 18 to 172 pCi/kg. The control station (C47) located in Orlando, Fl. also had measurable amounts of cesium-1 37. In eight of twelve control station samples there were measurable amounts of cesium-1 37 at an average concentration of 57 pCi/kg and a range of 16 to 201 pCi/kg. The cesium-137 values are similar in concentration as compared to samples collected in 2011 which experienced radionuclide deposition as a result of the Fukushima earthquake event and are not a result of the operation of CR3.

In 2011, eighteen of twenty four indicator samples had measurable amounts of cesium-1 37 with an average concentration of 76 pCi/kg and a range of 6 to 233 pCi/kg. Two of twenty four indicator samples also had measurable amounts of iodine-1 31 with an average of 232 pCi/kg and a range of 195-269 pCi/kg. The control station also had measurable amounts of iodine-131 and cesium-1 37.

In seven of twenty one control station samples, there was measurable 1-131 at an average concentration of 324 pCi/kg and a range of 13-1397 pCi/kg. In seventeen of twenty one control station samples there was measurable cesium-1 37 at an average concentration of 61 pCi/kg and a range of 7 to 182 pCi/kg. Nine extra control samples were collected at the Orlando station location.

68

These positive-measured radionuclides were a result of the Fukushima earthquake and tsunami event that occurred in 2011 and were not from the operation of CR3.

In 2010, five of twenty-four indicator samples had measurable amounts of cesium-1 37 with an average concentration of 66 pCi/kg and a range of 9 to 153 pCi/kg. This is higher than the levels found in 2009, but lower than in 2007 and 2008. It is believed the 2007 and 2008 spike was due to possible collection of wire grass mixed into the sample, which has a greater uptake rate of cesium as compared to other broad-leafed media. Additionally in 2010, eight of twelve control station samples had measurable amounts of cesium-1 37 with an average concentration of 21 pCi/kg and a range of 9 to 31 pCi/kg. During 2009 due to construction activities at the Crystal River Unit 4 & 5 site, the area where broad leaf vegetation was being collected at station C48A was removed. A new location in the same north sector was located near the air sample station C46. During 2010, also due to construction activities at the Crystal River Units 4 & 5 site, the area where broadleaf vegetation was being collected at station C48B became inaccessible. A new location in the ENE sector was located near the transmission power line corridor right of way, just NE of the mariculture center. This sector has the same D/Q value as the N and NNE sectors and is allowed by the ODCM.

Table IV-D.3 provides a statistical summary of the broad leaf vegetation gamma spectroscopy results.

Table IV-D.3.a provides the results of the monthly samples.

4. In 2012 one watermelon sample was collected at station C04. This sample had no measurable quantities of radionuclides of interest. Citrus samples were taken at station C1 9. There were no measurable quantities of radionuclides of interest in the citrus samples.

In 2011 two watermelon samples were collected at station C04. One sample had a measurable amount of cesium-1 37 at a concentration of 14 pCi/kg. All other radionuclides of interest were

< LLD. Citrus samples were taken at station C19. There were no measurable quantities of radionuclides of interest in the citrus samples.

In 2010 watermelon samples were collected at station C04. None of the required radionuclides were found in measurable quantities. Citrus samples were taken at station C19. None of the required radionuclides were found in measurable quantities in the citrus samples with exception of Cs-1 37 at a concentration of 71 pCi/kg.

In 2008 and again in 2009, there were no watermelon samples available at station C04. In these 2 years, due to crop rotation, there were no locally grown watermelons found in any areas nearby the facility and no local commercial harvest performed.

Table IV-D.4 provides a statistical summary of the watermelon and citrus gamma spectroscopy results.

Table IV-D.4.a provides the results of the semi-annual samples.

69

TABLE IV-D.1 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS CARNIVOROUS y Spec 8 FISH (pCi/kg) Mn-54 27 <LLD - <LLD 0 Fe-59 60 <LLD - <LLD 0 Co-58 27 <LLD - <LLD 0 Co-60 38 <LLD - <LLD 0 Zn-65 77 <LLD - <LLD 0 Cs-134 39 <LLD - <LLD 0 Cs-1 37 32 <LLD - <LLD 0 1

The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

70

TABLE IV-D.I.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/kg y EMITTERS IN CARNIVOROUS FISH STATION QUARTER Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 K-40 C29 1 <27 <27 <56 <28 <62 <33 <27 2349+/-167 2 <25 <25 <60 <38 <77 <39 <32 2382+/-243 3 <17 <21 <40 <25 <47 <22 <19 3066+/-251 4 <20 <19 <41 <22 <51 <25 <19 2354+/-200 C30 1 <20 <20 <46 <20 <44 <28 <23 3012+/-226 2 <19 <16 <41 <27 <50 <26 <23 2333+/-217 3 <21 <20 <35 <23 <47 <23 <25 2866+/-221 4 <22 <20 <53 <24 <35 <24 <22 2913+/-213 71

Carnivorous Fish 100 E

o 10 1

1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012

TABLE IV-D.2 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS OYSTERS ' Spec 8 (pCi/kg)

Mn-54 28 <LLD - <LLD 0 Fe-59 64 <LLD - - <LLD 0 Co-58 32 <LLD - - <LLD 0 Co-60 35 <LLD - - <LLD 0 Zn-65 69 <LLD - - <LLD 0 Cs-1 34 30 <LLD - - <LLD 0 Cs-1 37 32 22(1/8) C29 22(1/8) <LLD 0 (LLD - 22) 20@270- (LLD - 22) iThe "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

73

TABLE IV-D.2.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/kg y EMITTERS IN OYSTERS STATION QUARTER Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137 K-40 C29 1 <14 <17 <45 <21 <43 <24 <19 1086+/-156 2 <18 <21 <36 <24 <39 <20 22+/-5 1698+/-141 3 <26 <27 <58 <25 <56 <29 <26 488+/-83 4 <23 <18 <46 <21 <41 <24 <22 782+/-1123 C30 1 <19 <19 <46 <17 <48 <20 <22 1236+/-145 2 <28 <26 <62 <25 <50 <30 <26 892+/-111 3 <31 <32 <64 <35 <69 <27 <32 756+/-205 4 <21 <20 <44 <26 <37 <22 <21 919+/-153 74

Oysters 1000 E

o 100 C.)

Value

=Measured 10 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 1-i-- Cs-137 LLD

  • Cs-134 LLD1

! I 75

TABLE IV-D.3 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED (UNITS) OF ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED 1

PERFORMED (LLD) RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS BROAD LEAF VEGETATION y Spec 36 (pCi/kg) 1-131 30 <LLD <LLD 0 Cs-134 21 <LLD <LLD 0 Cs-1372 23 86 (13/24) C48B 92(12/12) 57 (8/12) 0 (18-172) 0.9 @ 730 (27-172) (16-201) 1 The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 ODCM.

2 The elevated Cs-137 values are not associated with the operation of CR3 and are a direct result of the Fukushima earthquake and tsunami event that occurred in 2011.

76

TABLE IV-D.3.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/kg OF y EMITTERS IN BROAD LEAF VEGETATION STATION MONTH 1-131 Cs-134 Cs-137 K-40 C47 JAN <26 <18 30+/-7 3552+/-195 FEB <30 <16 84+/-9 3083+/-191 MAR <11 <13 33+/-8 3963+/-178 APR <18 <13 <13 4111+/-167 MAY <12 <13 201+/-10 2901+/-119 JUN <11 <15 <15 4350+/-157 JUL <22 <15 25+/-6 3407+/-185 AUG <17 <11 <13 2772+/-201 SEP <11 <11 16+/-2 2707+/-184 OCT <17 <10 <11 2328+/-167 NOV <23 <13 24+/-5 3086+/-138 DEC <19 <14 40+/-6 4276+/-156 C48A JAN <19 <21 <20 2023+/-159 FEB <12 <11 <10 1941+/-169 MAR <12 <12 <10 2195+/-118 APR <17 <17 18+/-8 4605+/-232 MAY <10 <10 <12 2749+/-211 JUN <13 <21 <18 4237+/-198 JUL <16 <11 <10 2338+/-112 AUG <10 <13 <13 2187+/-141 SEP <16 <20 <17 4002+/-220 OCT <24 <11 <12 2307+/-125 NOV <14 <7 <7 2487+/-182 DEC <10 <10 <11 1881+/-104 77

TABLE IV-D.3.a (CONT'D)

PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/kg OF y EMITTERS IN BROAD LEAF VEGETATION STATION MONTH 1-131 Cs-1 34 Cs-1 37 K-40 C48B JAN <16 <17 107+/-10 2435+/-150 FEB <17 <16 94+/-9 3006+/-167 MAR <10 <10 174+/-6 2047+/-182 APR <20 <18 105+/-12 3504+/-191 MAY <16 <16 172+/-14 3439+/-183 JUN <15 <14 97+/-11 3529+/-186 JUL <25 <13 85+/-7 3617+/-150 AUG <15 <15 38+/-8 3837+/-188 SEP <15 <21 27+/-6 3571+/-200 OCT <20 <11 102+/-5 2898+/-203 NOV <21 <11 53+/-7 4328+/-159 DEC <7 <7 45+/-3 3435+/-214 The elevated Cs-1 37 values are a direct result of the Fukushima earthquake and tsunami event that occurred in 2011 and are not associated with CR-3 operation.

78

Broad Leaf Vegetation 1000 E

0100 10 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 S---I-131LLD ---t3---Cs-137 - Cs-134LLDI 79

TABLE IV-D.4 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

CRYSTAL RIVER UNIT 3 DOCKET NO. 50-302 CITRUS COUNTY, FLORIDA JANUARY 1 TO DECEMBER 31, 2012 MEDIUM OR ANALYSIS AND NUMBER OF PATHWAY TOTAL NUMBER OF LOWER LIMIT ALL INDICATOR LOCATIONS LOCATION WITH HIGHEST MEAN CONTROL LOCATION NONROUTINE SAMPLED ANALYSES OF DETECTION MEAN NAME MEAN MEAN REPORTED (UNITS) PERFORMED (LLD) 1 RANGE DISTANCE & BEARING RANGE RANGE MEASUREMENTS WATERMELON y Spec 1 (pCi/kg) 1-131 5 < LLD None 0 Cs-134 6 < LLD None 0 Cs-137 6 < LLD None 0 CITRUS y Spec 1 (pCi/kg) 1-131 9 <LLD None 0 Cs-134 10 <LLD None 0 Cs-137 10 <LLD None 0 1

The "a priori" LLD which meets or exceeds the requirements of Table 2-9 of the CR-3 0DCM.

80

TABLE IV-D.4.a PROGRESS ENERGY FLORIDA, INC. - CR3 - 2012 pCi/kg OF y EMITTERS IN WATERMELON AND CITRUS STATION MONTH 1-131 Cs-134 Cs-137 K-40 C04 - Watermelon June <5 <6 <6 1106+/-60 C 19 - Citrus January <9 <10 <10 1415+/-93 81