Text

Periodic Analysis Scheduling Program Procedure Number 30025-C, Rev. 53.1
	ML061000453
Person / Time
Site:	Vogtle
Issue date:	12/08/2005
From:	Sundaram S; Southern Nuclear Operating Co
To:	; Office of Nuclear Reactor Regulation
References
	30025-C Rev 53.1
	Download: ML061000453 (29)
	v • d • e

Approved By . Procedure Number Rev SlVan Sundaram ; ogtle Electric Generating Plant 30025-c 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Nudecr 12/08/2005 1 of 29 PERIODIC ANALYSIS SCHEDULING PROGRAM PROCEDURE USAGE REQUIREMENTS- SECTIONS Continuous Use: Procedure must be open and readily available at the work NONE location. Follow procedure step by step unless otherwise directed.

Reference Use: Procedure or applicable section(s) available at the work NONE location for ready reference by person performing steps.

Information Use: Available on plant site for reference as needed. ALL Printed March 16, 2006 at 10: 11

Approved By Gene.ating - Procedure Number Rev Shan Sundaram IVogle Electric Generating Plant 30025-A 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 2 of 29 INFORMATION USE 1.0 PURPOSE This procedure specifies the frequencies for routine repetitive sampling and status checks of various plant systems. The subsequent scheduling of the samples and status checks is also addressed by this procedure via the establishment of a Tickler Card File or a Computerized Scheduling System. Some of the analyses scheduled by this procedure are required by Technical Specifications, Technical requirements, or the ODCM.

2.0 DEFINITIONS None 3.0 RESPONSIBILITIES The Chemistry Manager is responsible for implementing and maintaining this procedure.

4.0 PROCEDURE 4.1 PERIODIC ANALYSIS SCHEDULING 4.1.1 Sampling and analysis of systems should be carried out in accordance with Table 1, Schedules for Periodic Tests.

4.1.2 Frequency nomenclature used in Table 1:

S - at least once per 12 hours1.388889e-4 days 0.00333 hours 1.984127e-5 weeks 4.566e-6 months D - at least once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months W - at least once per 7 days M - at least once per 31 days Q - at least once per 92 days SA - at least once per 184 days R - at least once per 18 months Printed March 16. '2006at 10:11

Approved By . Procedure Number Rev Shan Sundaram - Vogtle Electric Generating Plant - 30025-c 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 3 of 29 S/U - prior to each reactor startup P - prior to each effluent release 1/4 hrs - once per 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months .

XT - once per 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months .

2W - once per 14 (lays.

A/R - as required C - continuous (on line analyzer available)

Y - yearly Y/3 - once per 3 years 2M - two per month TW - twice weekly THW - thrice weekly, normally Mon., Wed., Fri., but interval should not exceed the frequency for 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months as defined in Technical Specification section 1.4 4.1.3 Surveillance's required by Technical Specifications, Technical Requirements, or the ODCM have a maximum allowable extension beyond the scheduled completion date of 25% of the surveillance interval. If a Tech Spec Surveillance is performed early, the interval used to schedule the next due date is the normal interval assigned that Tech Spec/ODCM.

4.1.4 Action Statements do not have extension periods and must be completed within the time limit specified by Tech Specs/ODCM.

4.1.5 To comply with Technical Specification surveillance 3.0.4 surveillance's which are applicable in particular modes must be completed satisfactory within the stated surveillance interval BEFORE ENTRY into the applicable mode.

4.1.6 Analyses not required by Technical Specifications, Technical Requirement Manual, and ODCM may be extended beyond their completion dates as necessary, upon Chemistry supervision's approval.

Printed March 16, 2006 at 10:1 1

Approved By ApprvedBy 0 ;~T ~ *4IProcedure Vogdle Electric Generating Plant A. Pocir~me Numnber Rev e

Shan Sundfiram votereti eeaigratI30025-C 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 4 of 29 4.1.7 All analyses required by Technical Specifications, Technical requirements, or the 0DCM have their frequency assignment in parenthesis and in bold print on Table 1.

4.1.8 Any item may be performed more often than scheduled.

4.1.9 Additional sampling requirements identified may be added to the tickler card files or computerized scheduling system, following supervisory approval. Any permanent requirements added will then be incorporated into a revision of this procedure at a later date.

4.1.10 Any Technical Specifications, Technical requirements, or the ODCM analysis scheduled less often than once per week will be entered in the "Surveillance Test Program",

Procedure 00404-C, for scheduling and tracking in conjunction with the Normal Scheduling System.

4.2 TICKLER CARD FILE 4.2.1 Tickler card files are located in all the chemistry laboratories, each covering the samples and analyses for that specific lab. Tile tickler card provides the informnation necessary to schedule the sampling and analyses of various plant systems. The parameter limits section of the card should be filled out from the applicable system chemistry procedure.

4.2.2 Each day the slot for that day of the month shall be checked and all cards distributed for completion. Following completion, appropriate entries to reschedule the analysis are then entered on the card and it is refiled in the Card File slot corresponding to the day of the month or month of the year next due.

4.2.3 When a card is completely filled in, a new card is established and the completed card filed in accordance with Chemistry Procedure 31045-C, "Chemistry Logkeeping, 'Filing, and Record Storage".

4.2.4 Cards for analyses not being performed (i.e., wet layup during plant operation) should be stored in an inactive file until needed. When activated, the cards should be placed in the proper day or month file.

4.2.5 Tickler cards that are blue are used for all non Technical Specifications, Technical requirements, or the ODCM analysis scheduling. Pink tickler cards are used for scheduling Technical Specifications, Technical requirements, or the ODCM analysis such that these most important analyses are readily identifiable.

4.2.6 A Computerized Scheduling System may be used in conjunction with or in lieu of the Tickler Card File System.

Printed March 16,2006 at 10:1 1

Approved By T1 Procedure Number Rev Shan Sundaram Vogtle Electric Generating Plant A 30025-C 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM PageNumber 12/08/2005 5 of 29

5.0 REFERENCES

5.1 VEGP Unit I and Unit 2 Technical Specifications 5.2 VEGP Technical Requirement Manual 5.3 VEGP ODCM 5.4 VEGP Final Safety Analysis Report 5.5 30000 Series Chemistry Procedures 5.6 EPRI Primary Water Chemistry Guidelines 5.7 EPRI PWR Secondary Water Chemistry Guidelines END OF PROCEDURE TEXT PNintcd March 16, 2006 at 10:11

C-Approved ByVoteEetiGeeangPn f

A Pmcedure Number Rev Shait Sundlaran l Vogtle Electr~c GencratingPlant A 30025-C 53.1 Date APproj'd PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 6 of 29 TAUlT. 1 SCHEDULE FOR PERIODIC TESTS PRIMARY RELATED SYSTEMS Spc C, t

_S,.s. . Dis Di. . Al . 0 Spec. Cat. Susp. Diss. Diss. Al SI02 pH Cond.

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-II Rx Coolant System W C/D (THW) (THW) W No 3 XT (THW) (THW) Q NO 16c, No 2 Power Operations (THW) 18 Rx Coolant System W W (XT) (XT) W No 3 No 5 W No 4 NO 14 NO 13 Shutdown (RHR) _ (XT) (XT) Q Q PZR Liquid A/R A/R A/R A/R A/R A/R A/R Boron Thermal A/R A/R A/R Regen. Demin. Eff. .. _

Volume Control TK (Gas Space)_

Boric Acid Storage W W (W) Q Tank Safety Injection Sys. M M No 6 (Accumulators) _ _ _M)

Safety Injection Sys I_(Spray Add Tank) _ _

Refueling Water No 8 No 8 No 8 No 11 (W) l Q StorageTank M I M M M I ISpent Fuel Pool W W W W W No 7 M

_ I _ _ Q Refueling Canal No 5, and Cavity 15 I _ _ _I__ _I (X T) I _ _ _ _ __ _ _ _

Rx Make-upWater W W W W W M W No9 Q

_Storaqge Tank _ Q ICVCS Mixed Bed M____

lDF _ .

Printed March 16, 2006 at 10: II

Approved By r C-Pmcedure Number Snan Sundaram I'Iogtle Electric Gencraflng Plan 30025-C Rev 53.1 Date Approved 12/08/2005 L PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 7 of 29 TARTY, 1(CI nt'dl SCHEDULE FOR PERIODIC TESTS PRIMARY RELATED SYSTEMS ECCS Crud TRITIUM 100! Dose H2 Gross T.S. Sulfate Sr-89 Fe-55 Iron Zinc Nickel Recirc. fluid Activity E-Bar Equiv 02 Activity Gross & 90 pH control 1-131 N2 Specific sys. TSP Percent Activity Basket Surveillance Rx Coolant System W (SA) (SA) NO 1, W W (SA) (SA) NO 16, NO 16, Power Operations 10 17,18 (2W) D 2W lRxCoolant System W W Shutdown (RHR) I NO 12 i PZR Liquid _

BoronThermal A/R Regen. Demin. Eff. _ _ _ I __ I_.

ll Volume ControlTK A/R (GasSpace) __ _ l

_____ l l _ ._ l ll BoricAcid Storage6 M Tank -_.

Safety Injection Sys.

11(Accumulators) __ _ _ _ _ __l __

Refueling Water M M

__Storage Tank Spent Fuel Pool _ !-- _ __M I_ I w _ M 11Refueling Canal .

llRx Make-up WatrlWr W M Storage Tank _

11ECCS pH Baskets l () ll CVCSMixed Bed DF l _ _ _ M ContainmentSA ll A tm osphere __ _ __ _ _ __ __ _ __ __ _ __ _ _ __ __ __ __ _ __ _ III _ IIIl Printed March 16,12006 at 10:11

Approved By Procedurc Number Rev Shan Sundiram Vogtle Electric Generating Plant 30025-C 53.1 Date Approved PERIODIC ANALYSIS SChEDULING PROGRAM Page Numcer 12/08/2005 8 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS PRIMARY RELATED SYSTEMS NO = Note NOTE 1 a) Once per 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months , if RCS Dose Equivalent l-131 exceeds I jCi/gm.

b) Within 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months , if RCS gross activity exceeds 100/E-Bar pCi/gm.

c) Between 2 and 6 hours6.944444e-5 days 0.00167 hours 9.920635e-6 weeks 2.283e-6 months following a net change of reactor thermal power exceeding 15% of rated thermal power within a I hr. period.

d) Between 2 and 6 hours6.944444e-5 days 0.00167 hours 9.920635e-6 weeks 2.283e-6 months following a reactor shutdown.

e) Between 2 and 6 hours6.944444e-5 days 0.00167 hours 9.920635e-6 weeks 2.283e-6 months after Mode I entry, following a shutdown.

f) Take an extra sample between 2 and 6 hours6.944444e-5 days 0.00167 hours 9.920635e-6 weeks 2.283e-6 months after criticality for start-up after a refueling outage.

NOTE 2 Monitor ammonia daily after hydrazine additions until ammonia concentration decreases to less than 0.8 ppm.

NOTE 3 Technical Requirement limit applicable with RCS Tave. greater than 2500 F.

NOTE 4 Monitor shutdown RCS for hydrogen concentration daily if hydrogen is added.

NOTE 5 Once per 12 hours1.388889e-4 days 0.00333 hours 1.984127e-5 weeks 4.566e-6 months during refueling operations (Mode 6 when canal is flooded) whenever both of the two minimum required source range neutron flux monitors are inoperab e or not operating.

NOTE 6 Also, within 6 hours6.944444e-5 days 0.00167 hours 9.920635e-6 weeks 2.283e-6 months of each solution volume increase greater than or equal to 1% of tank volume.

NOTE 7 Analyze SFP for calcium and magnesium once per week during fuel movement.

NOTE 8 Increase to weekly during during reactor cavity flooding.

NOTE 9 Also sodium monthly and potassium quarterly.

NOTE 10 Also, calculate the 1-131/133 ratio at this frequency.

NOTE 11 Also prior to transferring water to the refueling canal to check for resin beads/fines.

Printed March 16,2006 at 10:1I I

Approved By i Procedure Number Rev Shan Sundaram vogti Electric Generating Plant z 30025-C 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Numtner 12/08/2005 9 of 29 TABLE I (CONT'D.)

SCHEDULE FOR PERIODIC TESTS PRIMARY RELATED SYSTEMS NOTE 12 Technical Specification surveillance required only when RCS Tave at 5000 F or greater.

NOTE 13 Daily sampling for silica during and after filling RCS fill and vent operations, and if required once every 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months if conditions warrant increased attention. RCS fill and vent shall be defined as entry into MODE 5 startup. Daily sampling shall continue until silica reaches <1000 ppb or if plant conditions warrant Chemistry Manager may relax sampling frequency.

NOTE 14 Weekly sampling for aluminum during and after RCS fill and vent operations. RCS fill and vent shall be defined as entry into MODE 5 startup. Weekly sampling shall continue until aluminum reaches <5 ppb or if plant conditions warrant Chemistry Manager may relax sampling frequency.

NOTE 15 Once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months when notified that non-borated water is being used during cavity operations and the cavity level is at or above 194' elevation.

0.I NOTE 16 a) Required only during periods of zinc addition to the RCS in Mode 1. i'i I

b) The RCS sample point is the preferred sample point. When the RCS sample point is 'II not available the CVCS Downstream of Letdown Heat Exchanger may be used.

c) During initial stages of zinc addition, more frequent sampling may be necessary.

Frequency Before detection of zinc-RCS RCS Zn analysis daily RCS Ni analysis daily.

Before stabilization RCS Zn analysis shiftly.

RCS Ni analysis daily After stabilization RCS Zn analysis daily.

RCS Ni analysis weekly.

Two months after stabilization RCS Zn analysis daily.

RCS Ni analysis Biweekly NOTE 17 Also, after adding a newv zinc acetate batch to the zinc addition tank, two RCS samples must be pulled and analyzed after the addition. These samples must be taken al least 8 hours9.259259e-5 days 0.00222 hours 1.322751e-5 weeks 3.044e-6 months apart and within 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months after the addition. Ii NOTE 18 Zinc Addition may not resume until two samples at least 2 days apart are < 6 ppb Ni and l.

< 1000 ppb SiO2 (the average of the 2 values).

Printed March 16,2006 at 10:11

Approved By i c Generating P Procedure Number Rev Siian Sundaram Date Approved

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Vogue l~ecte enrain Pillt A

30025-C 53.1 PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 _ . 10 of 29 TARIF. 1 (CONT'l.)

SCHEDULE FOR PERIODIC TESTS SECONDARY RELATED SYSTEMS l Specific Cation _ Dissolved MPA Stem G ._ r L21 Conductivity Conductivity Chloride Turbidity Hydrazine Ammonia Silica Oxygen Poerm Operatios No 6 No 8 No. 14 Power Operations _C/D _ _C __ C/D _ D A/R THW l Steam Generators S S S S Heatup/Hot Standby __ __

Steam Generators No 5 _ __ _ _, __ __ NoW5 NoW__ 5 _

Wet Lay-up W W W No 3 No 13 Feedwater C/D C/D C/D C/D D C!D D No 3 No3 No1 No3 No1 No2 Main Steam W W IC AIR W A/R ondensate C/D C/D C/D D C/D eater Drain Pump scharge I AIR earn Generator owdown W C/D C/D W W rocessin QC )ndensate No 9 No 9 olisher __ l_ C/D C C/D _

ondensate No 11 W Storage Tanks W W l A/R

-Ctondensate/Feedrl

, ) ys Wet Lay-up W W W Printed March 16,2006 at 10:11

C C Approved By - ` tl Tltr Generaling Plant A Procedure Number Rev Shan Sundaramg 30025-C 53.1 Dae, Approved

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PELRIODIC ANALYSIS SCHEDULING PROGRAMS Pate Number 12/08/2005 _ I. 11 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS SECONDARY RELATED SYSTEMS Dose Equiv Nitrogen Gamma sodium Phosphiate fran Copper Sulfates 1-i 31 over Activity pressure Steam Generators Power Note 12 No 7 (M)

Operations C/D D D No 4 (M)

Steam Generators S Note 12 _ S No 4 IM) No 7 (M)

Heatup/Hot Standby D .

Steam Generators Wet No 5 Note 5 No 5 No 4 No 5 No 7 Lay-up W W W (M) W (M) lFeedwater No1No 10

__ _ _._. C W Q No 1 No 1 Main Steam C ._._ _ AR No 1 .

Condensate IC/D AjR Heater Drain Pump No 1 Discharge C A/R Steam Generator Blowdown Processing W _ A/R Condensate Polisher N-ToAte 9

_ ___ _C/D A /R__ _ __ _ _ _ _ _ _ _ _

Condensate Storage Tanks ICondensate/Feed SysWet-Lay-up l l _ ______ __ W Printed March 16,2006 at 10:11

Approved By Procedure Number Rev Shall Sundaram Vogdle Electric Generating Plant 30025-C 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 12 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS SECONDARY RELATED SYSTEMS NO = Note NOTE 1 Analysis required when cation conductivity exceeds 0.5 jimhos/cm or steam generator water is outside of normal limits.

NOTE 2 Analysis required only if condensate dissolved oxygen is in action level 2.

NOTE 3 Perform pH - specific conductivity - ammonia data correlation. This data correlation is normally automatically perfonned by SMART ChemWorks. In the event that SMART ChemWorks is out of service, the data correlation and input into OPENCDM must be done manually.

NOTE 4 Secondary coolant dose equivalent I-131 shall be measured in Modes 1, 2, 3, and 4.

NOTE 5 Every other day until stable, then weekly.

NOTE 6 Scan an aliquot of cation resin for gamma activity prior to disposal.

NOTE 7 May be used to confirm absence of a primary-to-secondary leak per ODCM Table3-3, note b. This sample is not required during periods when the condenser air ejector and steam packing exhaust is not in operation, such as during refueling.

NOTE 8 Analyze daily when steam generators arc in action levels.

NOTE 9 Analysis required only when a precoat is applied.

NOTE 10 Increase sampling is required during startup.

NOTE 11 Daily when SG silica is above normal.

NOTE 12 Daily until values are less than 1.0 ppb for five days, then monthly as long as values remain below 1.0 ppb.

NOTE 13 Daily when MPA is being utilized as pH control agent NOTE 14 During normal steady state operation, only one steam generator per unit needs be analyzed. The 72 hour8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months restriction in step 4.1.2 for the definition of THW does not apply to silica.

Prnked March 16.2006 at 10:11

Approved By C V ogterProcedure C- C Number Rev Shan

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SSundararn

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[Vg-fl . _ _ ,..,...t Ect--GnrtgPatALI 30025-C 53.11 Datc Appmvid PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 _. 13 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS COOLING SYSTEMS Total Gross Oil and pH Chlorine, Speciflc Dissolved T cmperature Alkalinity Hardness Activity Grease Residual Conductivity Solids 4 I .1- 4 Nuclear Service No. 1 No. 3 No. 5 No. 1 No. 1 No. 1 No. 1 No. 4M Cooling Water A/R D D A/R A/R A/R A/R

_~

Circ. Water No. 1 No. 3 __

No. 1 No. 1 No. 1 lNo. 1 A/R D WN A AR I AR NAR

_ I __

River Water A/R Make-up I.

Dechlorination A/R i 1-System

____ ______ !..---- & 4- 4 Cooling fower Blowdown t 1 4 Waste Water Retention Basin 2/M Blowdown Tower 2/M Blowdown Sump Overflow No - Note Note 1 As required to support Ryznar stability index calculation Note 2 Calcium may be substituted for silica analysis as the cycle indicator.

Note 3 During periods of chlorination, sample at the manway when the Dechlorination system is in service or sample the NSCW tower when Dechlorination system is not in service.

Note 4 When Radioactivity is detected within the Component Cooling water and/or Aux. Component Cooling water, excluding Na-24.

Note 5 Dailv for these annivsye is Monday through Fridnv and can go as long as 4 {lays between analyses.

Printed March 16, 2006 at 10:11

r C C, Approved Shan Slindnamar lly I

Yngt' F'ectr. Generating Plant A Procedure Number Rev

-_ - 130025-C 53.1 Date Approved j-PERIODIC, ANALYSIS SCIIEIDULI-NC-GPRO;GRAN,%I _Pagc Number 12/08/2005 A d _ . _-- _

- - - _ I..--,. _ - . -. .__ = _ - _ _ ..... _ F a . _ I ._ ...... . . ..- - _

14 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS COOLING SYSTEMS Ch rc:miml - Ofa ChIlori , Chlorine, Copper Total Ryznnr Cyclc of TTA Hydrazine Zinc/ Suspended Free Total Bacteria Stability Concentration Total P04 Solids . Index

_ -L 4- 4 No. 2 M Nuclear Service A/R A/R W W Cooling Water No. 6 No. 2 Circ. Water W AIR A/R 2/M W

~

- - ~

I _ - !---

-- ------ + 4 River Water Make-up

-. L .4- 4 Dechlorination System Cooling Tower No 5 Blowdown Q W W

- 1 4 + 1-Waste Water I Retention Basin 2/M Blowdown Tower W W No 4 Blowdown Sump Overflow No - Note Note I As required to support Ryznar stability index calculation Note 2 Calcium may be substituted for silica analysis as the cycle indicator.

Note 3 During periods of chlorination.

Note 4 Sample to be collected as required by Ga. EPD. Sample to be collected during periods representative of hydrazine use and discharge.

Note 5 Chromium may be analyzed annually (as authorized in the current NPDES permit) as long as chromium is not a component of cooling tower maintenance chemicals.

Note 6 Required for Total Phosphate only.

Printed March 16,2006 at 10:1 1

VC lPmcdlure Number C Rev Apvued.X~aBy. E/cg-t~e ETectr*c Gynernting Plant l 30025-C 53.1 Datc Appvcd PERIODIC ANALYSIS SCHEDULING PROGRAMNI 1 Pl-aagerNumber 12/08/2005 . .__. _

TABLE 1 (Cont'd)

SCHEDULE FOR PERIODIC TESTS CLOSED COOLING SYSTEMS pH Nitribe Conductivity Molybdate TTA l Chloride Fluoride ATP

-_(Note4) (4)) (Note4))l_ (Note4) (Note ) M Auxiliary Cokmponent WV W W n/a W _ M M Cooling Walter (ACCW)

Tier 1 Component Cooling No 2 No. 2 No.2 2 Water (CCV N) W W W M M Tier 1 Normal Chil lled Water M M M n/a M M n/a M Tier 2 Essential Clhiiled Water No 2 No 2 No.2 n/a W M n/a M Tier 1 W W W Turbine Plai ,t Closed W n/a W W W M n/a M Cooling Walter Tier 1 BTRS Chillc No2 No2 No.2 n/a M No 2 No 2 M Tier I Inter mittent M M M M M Diesel GenEerator W W W n/a l W M n/a M Cooling Water Tier 1 CAS Chiller M M M n/a M M n/a M Tier 2 OTSC Chiliher M M M n/a M M n/a M Tier 2 n Watr Stator Cooli ing- Wter l n/I n/a na n/a M

M I n n/a n/a n/a n/a n/a Printed March 16,2006 at 10:11

C r ApprovedI By I-rk ezt Gnr hgPat Procedure Number Rev Shia Sitndarani r Vfnle-er--. Gn .- P .-- A 3002-5-C' 5 3.1 Date AppmvcdL PERIODIC ANALYSIS SCHEDULING PROGRAM,%1 Page Number 12/08/2005 16 of 29 TABLE I (Cont'd)

SCHEDULE FOR PERIODIC TESTS CLOSED COOLING SYSTEMS (Cont.)

Gross Iron Sulfate Copper Nitrate Oxygen Ammonia Activity M. 4 4 4 4--

Auxiliary Component Q M M M n/a M Cooling Water (ACCW)

Tier 1 _

II-------- I.I&

Component Cooling No. 2 Mv M M M n/a M Water (CCW) Q Tier 1 Normal Chilled Water n/a M M M M n/a M Tier 2 4 1 4- 4 Essential Chilled Water n/a M M M M n/a M Tier 1 Turbine Plant Closed No.1 Ni M M n/a n/a n/a Cooling Water Tier 1 BTRS Chiller No.2 M M M M n/a M Tier 1 Intermittent Q

-. ________ 4- 4 Diesel Generator Cooling No.3 M M M M n/a M Water Tier 1 CAS Chiller n/a M_ n/a M Tier 2 oTSc Chiller n/a M n/a M Tier 2 Stator Cooling Water n/a n/a na naW n/a Pinted March 16, 2006 at 10:11

Approved By Procedure Number Rev Sln Sundarani Date Approved

. Vogtlc Electric Generating Plant IPERIOI)IC A

ANALYSIS SCHEDULING PROGRAMPage Number 12/08/2005 17 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS CLOSED COOLING SYSTEMS No -Note Note 1 As required during periods of confirmed primary to secondary leaks.

Note 2 When systems are available for sampling. Analysis may be deferred when systems are shutdown. However at least once per quarter have operations re-circulate the system and sample while on re-circ. BTRS system samples may be deferred when the opposite unit is in service to support an outage.

Note 3 Check for radioactivity as required when the corresponding NSCW train becomes radioactive, and check for visible oil approximately once a month.

Note 4 For pH, nitrite, conductivity, molybdate, and TTA monitoring should be weekly for Tier I systems but can be monthly if the system has exhibited steady state conditions fir one quarter.

Printcd March 16,2006 at 10:11

C C-

'%I-Appmved By Slaii Stridiaramn l VG otle Hcctr. GeneratingPlant r A Procedurc Number Rev 30025-C 53.1 Da.c Approved PERIODIC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 . _ . 18 of 29 TALEF 1 (CONT'f.A SCHEDULE FOR PERIODIC TESTS MISCELLANEOUS SYSTEMS

_ l . .

Biologic Pb/Cu lOCs, pH Chlorine I Turbidity Coliform Dissolved al Oxy Settleable Total Alkalinity Nitrates/ VOCs, Oxygen Demand Solids Phoshate Nitrites TTHM,

/Ortho HAA5-

- -4.

_ ---*1-Phoshate Plant Potable Water D Q TW TW y Y No. 5 4-4 Yl3 Plant Raw Water W No 4 A/R Training Center No.1 No. 1 Q TW TW y SA No. 5

=

Potable Water D _

D . _ Yl3

. I Training Center Raw W Water _ . _. _

I _ ____ 4 Training Center Tank No 1 No11 Outlet D D .1. -I. 1 .1 4 Plant Wilson No 3 No 3 W W Recreation Center No 1 D No 1 I___ y Potable Water ._

_D ____

1- 4 Recreation Center W NoI _____

Raw Water 4 + 4-Sewage Treatment AIR2, Pit Final Effluent D 1 3 Sewage Treatment Pit Aeration Comp

.i., _,.

W -w--- ---- I I No - Note I Printed March 16, 2006 at 10:11

Appraved By Procedurc slumber Rev ShVn Sundaram Togtle Electric Generating Plant 30025-C 53.1 D.atc Approved PERIOI)IC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 119 of 29 TABLE 1 (CONTD.)

SCHEDULE FOR PERIODIC TESTS MISCELLANEOUS SYSTEMS Note I Daily for these analyses is Monday through Friday and can go as long as 4 days between analyses. Also should be perfonned approximately at same time each day.

Note 2 This sample is only taken when there is a discharge to the Savannah River.

Note 3 This sample only required when Plant Wilson is being supplied from the Training Center well.

Note 4 When requested by Operations to place Makeup Well #2 back in service, refer to 35570-C for the specification Note 5 Inorganic contaminants (lOCs) once every three years or as required by EPD, Volatile organic contaminants (VOC) analysis once every three years or as required by EPD, Total Trihalomethanes (TTHMs) once every three years or as required by EPD, and Haloacetic Acids (HAA5) once every three years or as required by EPD Printed March 16,2006 at 10:11

C I App~'edBy r *&

Ne-1'ncedure Number Rev SpiparSundaram ByVogfie Date Approved Fhectric Gencr:ting Plant PERIODIC ANALYSIS SCHIEDULILNG PROGRAM A 30025-C 53.1 Page Number 12/08/2005 l 20 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS DIESEL SYSTEMS JPetific/ Clear and Viscosity F;ash Point Table 1 Particulate Water t Wear Metals Neutralization API Gravity Bright ASTM Contamin. content (Spectro.) No.

1-D975-81 I 4-Diesel Generator No 1 No I No 1 No 1 No 2 No 1 Fuel Oil ____

I _ I Diesel Fire Pump No 5 No 5 Q Q bDiesel Generator M M 1- t - - -

(Q)

Lub Oil Diesel Gen Fuel Oil (M) (M) (Q)

Stor Tanks Fuel 4 +

Electrohydraulic No 4 No 4 No 4 No4 No 4 No 4

.Control Fluid A _ . .

A _ _

A _ _ _J _ _ _ I A_ _ _ _ _ _

A_ _ _ _

A No - Note Lode I Sample each truck of new diesel fuel and analyze for this parameter prior to adding the new fuel to the diesel fuel oil storage tank.

Note 2 Analyscs not performed on-site. A sample is taken for shipment to a qualified off-site laboratory for analysis. New fuel may be discharged to the diesel fuel oil storage tank prior to sample shipment.

Note 3 Sample each truck of new diesel fuel and analyze for mercaptan prior to adding the new fuel to the diesel fuel oil storage tank. New fuel may be added to the diesel fuel oil storage tank without mercaptan analysis if both conditions below are satisfied.

a. The diesel fuel oil storage tank has been analyzed for mercaptan, and the value is less than 0.007%.

b. Once per 92 days, the amount of new fuel added to the diesel fuel oil storage tank, plus the current amount of new fuel to be added, is less than 15,000 gallons since the mercaptan analysis referenced in (a) above.

Note 4 This is done annually.

Note 5 Sample each truck of diesel fuel and analyze for this parameter or sample storage tank within 24 to 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months after fuel addition.

Printed March 16,2006 at 10:11

4? r Procedure Number Approved By Vitle E ctrr^5cnierating Plarn ,-> Rev Shaii un dhEDUING - OGRI 130025-C 53.1 Date Approved l PERIODIC ANALYSIS SCHEDULING PItOGRAiNI Page Number 12/08/2005 21 of 29 TARTE 1 CONT'n.)

SCHEDULE FOR PERIODIC TESTS DIESEL SYSTEMS l Pour Auto Ignition Chlorine Mercaptan Sulfur Pointl Temp Content Conductivity Color Fire Point Ferrography Diese I Generator No 3 Fuel C Diese Ii __ _ _ , ,__ ___ _ _

Pump _ _ _ _ __ _ _ _ _

I_ _ _ __ _ _ _ _ _ _ _ _

Diese eI Generator (Q)

LubO Diese Gen Fuel Oil (Q) ----

Stor Tanks Fuel l l l Electraohydraulic _ l N4No4 l No 4 No 4 No 4 No 4 I C'ontrioi Flud I _ _

A A A A A A No - No te No0te I Sample each truck of new diesel fuel and analyze for this parameter prior to adding the new fuel to the diesel fuel oil storage tank.

Note 2 ,ALallyscs not performed on-site. A sample is taken for shipment to a qualified off-site laboratory for analysis. New fuel may be discharged to the diesel fucl oil storage tank prior to sample shipment.

Note 3 Sample each truck of new diesel fuul and annals for mercaptan prior to adding the new fuel to the diesel fuel oil storage tank. New fuel may be added to the diesel fuel oil storage tank without mercaptan analysis if both conditions below are satisfied.

a. The diesel fuel oil storage tank has been analyzed for mercaptan, and the value is less than 0.007%.

b. Once per 92 days, the amount of new fuel added to the diesel fuel oil storage tank, plus the current amount of new fuel to be added, is less than 15,000 gallons since the mercaptan analysis referenced in (a) above.

Note 4 This is done annually.

Note 5 Sample each truck of diesel fuel and analyze for this parameter or sample storage tank within 24 to 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months after fuel addition.

Printed March 16, 2006 at 10:11

r r IC A ppixved By Date Approved I

S"In t~'likiranlI v

'V,,r:t?e :t.,~CtrTz Gencr-tfnf PERIODIC ANALYSIS SCHEDULING PROGRAM Plart A 4 Procedure Number 130025-C Rcv

53. 1 PaVe Number 12/08/2005

_- _- - _ .Is'- -- -. _ -L -_. _ ........... - ----- ' -- ' :.-- _ . _ - 1 22 of 29

_ '=--- .

TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS LIQUID RADWASTE SYSTEMS Principle 1-131 DislEnt Tritium Gross Alpha Sr-89, Fe-55 pH TSS Oil & Monitor Gammn Casess (Composite) (C~ompi&^) Sr-90 (Como-site, :reasc Operations Emmiters (Gamma (Composite)

_ _ --- I ;

Emit)!- + lI l Wasste Monitor (P) (P) (M) (N.) (M) (Q) (Q) No No No 7 Tanl kS No 9 7 7 Drai nageof (P) (P) ((M j (M) I (Q Syst ems (Not

___ j r (M)I (Q__-

Waste Water No 2 No 2 No 2 No 2 No 2 No 2 No 2 R-.t Basins (M)

(W) (M) (M) (M) (Q) (Q)

(Note 3) -.-

Outside No 5

~ , -+-- 1 .I I.

No 5 Temporary (W) (W)

Storage Tanks _I i£ _I I I I I I Aux Bldg No 6 clean Water p Sump _ -

I t F WWRB No 8 Sample W Compositor Steam Gen No 4 Blowdown Effluent-Act 38 Turbine Bldg No 4 Floor Dr Sump Eff-Act 38 _

Nuc Serv (S)

Cooling Water Eff-Act 38 Printed March 16, 2006 at I0:11

Approved By Voge Electric Generating Plant Procedure Number Re%

Shart Suxidaram IvgiEecrcelran r I1 30025-C 53.1 Date Approved PERIODIC ANALYSIS SCHEDULING PROGRAMI Page Number 12/08/2005 _ 23 of 29 TABLE I (CONT'D.)

SCHEDULE FOR PERIODIC TESTS LIQUID RAD WASTE SYSTEMS TNiO = Note NOTE 1 Drainage of systems confirmed to contain radioactivity levels exceeding the MDC of Table 2-3 of ODCM or the analysis used whichever is most restrictive.

NOTE 2 Not required until confirmed primary to secondary leakage.

NOTE 3 Composite sample collected proportional to effluent flow stream.

N'OTE 4 Once per 12 hours1.388889e-4 days 0.00333 hours 1.984127e-5 weeks 4.566e-6 months wvhen secondary coolant > 0.01 pCi/gm DEQ I-131, once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months when secondary coolant is < 0.01 pCingm DEQ 1-1 31.

NOTE 5 When radioactive material is being added to the tank.

NOTE 6 If activity is present, route to liquid radwaste system.

NOTE 7 Refer to 36001 -C, for type of analysis required. Sample required once per quarter from a tank discharged from each unit. Use Unit I Tanks 9 and 10 and common tanks 12 and 13 for Unit I sample; use Unit 2 Tanks 9 and 10 and common tanks 12 and 13 for Unit 2. If no tank is being discharged on day sample is due, take sample from next availabl. tank for that unit. pH is measured at final discharge, not at each tank.

NOTE 8 When confirmed primary to secondary leakage exists.

NOTE 9 Once a month perform a monthly composite for tritium.

PNintd March 16,2006 at 10: 11

C I f-Approved By Sh2aii Sundarani "l!-tc E; ectr-c sentr, ting Plint A. -

_Procdure Number 130025-C Rev 53.1 Date Approved PERIODIC ANALYSIS SCIIEDULIN PROGRAM I-Page Number 12/08/2005 24 of 29 TABLE I (CONT'D.)

SCHEDULE FOR PERIODIC TESTS GASEOUS RADWASTE SYSTEMS Principle Tritium Gross Alpha Sr-89, Sr-90 Prin I Gamma Prin Noble Gas Prin Particulate Gamma (Composite) (Composite) Emit (1-131) Gamma Emit Gamma Emit Emitters 4 4- 4 WVaste Gas Decay Tank (Note 1) _ _ _ _ _ - - - I Waste Gas Decay Tank Release _ (P)

-. ----- 4- 4 + - - _________________

Plant Vent RE-12442 (,-,I) No 3 (M1) (0) (Q) (W0) No 3 (M) (AV)

Plant Vcnt RE-12444 (It ) No 3 (M) (m) (0) (WV) No 3 (C) (XV) 4--

I . -i-Plant Vent RE-12444 Backup RPF RE-16980A (XV) 4 -4 4 -

Containment Atomos. (RE2562) (P) No 3 No 3 (P)

'---(-P -- I ----------(ND)

'---------i---------------------------I -. 4 I-- 4 Condenser Air Ejec'or&a Steam __ NO 6 __ . NO 6 NO 6 NO 6 NO 6 NO 6 NO 6 Packing Exhlaust (RE12839) _(M1)__. (MN) (Q)__ (Q) (NV) (M) (CV)

Containment Purge (RE2565) 4 Plant vent noble gas activity No 9 monitor-Action 47 (S)

Plant vent flow rate monitor -

Action 46

__ _ 4>

Plant vent sampler flow rate monitor - Action 46 4 4 .4 Gaseous Waste Processing Hydrogen Monitor-Act 50 t 1- 4 Gaseous Waste Processing Oxygen Monitors-Act 49AC -I 4 4 4 4 Air Ejector & Steam Packing No 9 Exhaust Noble Gas monitor- (S)

Action 47 _ -

_ I _ 4-Air Ejector & Steam Packing Exhaust Flow Rate Monitor-Action 46 Air Ejector & Steam Packing Exhaust Sampler & Flow Rate l l l l l l Monitor - Action 46l IIll Printed March 16,2006 at 10:1 1

Approved By C C C, Shan ;3uxita.ii-n I V#gtte FectrGenc.r athn'7 Plant _A Procedure Nuimber Rev

-t. . . - . - . _- . ......... . - ,. ... 30025-C 53.1 Datc Approved PERIODIC ANALYSIS SCHEDULING PROGRAMNI _Page Number 12/08/2005 .1 _ . _.- ,,,_ ,- _-- _ ,- - ._, ,-- _ ,_ , _ _ . _,, > !_,, _ 1 25 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS GASEOUS RADWASTE SYSTEMS Total Act Oxygen Estimate FloW Part Filter Iodine Filter Gain Fact Press (Equiv Xenon) Gas Chngout Chngout Correction (Note 10)

(Note 10)

Waste Gas Decay Tank (Note 1) . ,

(D)

_ ., _- _ I _ _-

Waste Gas Decay Tank Release Plant V -12442 (A/R) (NV). W

-- . , -t I Plant Vent RE-12444 Nol l (NV) No 11 (W) W Plant Vent RE-12444 Backup MV M RRPF RE-16980A. (WV) _

Containment Atmos. (RE2562)

Condenser Air Ejector & Steam

-I- --- .--- -- -

__ A/R A/R l No 11 Noll W Packing Exhaust (RE12939)

_ (NW) M(NV)

Containment Purge (RE2565) IM I W Plant vent noble gas activity monitor-Action 47 -4

______ + 1-Plant vent flow rate monitor - (1/4 hr)

Action 46 Plant vent sampler flow rate (1/4 hr) monitor - Action 46 4 4 +

Gaseous Waste Processing No7

_Hydrogen Monitor-Act 50 l-- . 4 Gaseous Waste Processing N _8 Oxygen Monitors-Act 49AC Air Ejector & Steam Packing Exhaust Noble Gas monitor-Action 47 I. I Air Ejector & Steam Packing (1/4 hr)

Exhaust Flow Rate Monitor-Action 46 __.

Air Ejector & Steam Packing (1/4 hr)

Exhaust Samplcr & Flow Rate Monitor - Action 46 I _________________ 2. 1 ___________________ 1 1 Printed March 16, 2006 at 10:11

Approved By : G a Procedure Number Rev Shan Sundaram Vogtle Electric Generating Plant 30025-C 53.1 Dite Approved PERIOI)IC ANALYSIS SCHEDULING PROGRAM Page Number 12/08/2005 26 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS GASEOUS RAD WASTE SYSTEMS NO = Note NOTE I When radioactive materials have been added to any tank during the previous 24 hou:s.

NOTE 3 Sample plant vent and containment for tritium and principal Gamma emitters per following schedule. A sample from either RE-12442 or RE-12444 sample stream will meet this requirement for the Plant Vent:

a) Monthly, if no conditions listed below exist.

b) Once per 7 days for tritium only in Unit I plant vent only.

c) Once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months for plant vent only when that unit's refueling canal is flooded (when the water level in the Lower Reactor Cavity is at an elevation greater than I

188ft.)

4 d) Following a start-up, shutdown, or net thermal power change of greater than 15%

i of rated thermal power in one hour if either of the followving conditions exist:

1) RCS dose equivalent iodine increases by more than a factor of 3.

2) The plant vent noble gas monitor shows that the effluent activity has increased by more than a factor of 3.

NOTE 6 When confirmed primary to secondary leakage exists, (>20% above background on steam generator liquid) or as directed by supervision.

NOTE 7 Once per 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months when degassing, once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months during other operations.

I NOTE 8 With outlet oxygen monitor inoperable once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months , when both oxygen monitors inoperable or inlet oxygen and inlet hydrogen monitors both inoperable sample once per 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months during degassing or once per 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months during other waste gas system operations.

[ NOTE 9 Samples must be analyzed within 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months .

NOTE 10 May be performed in conjunction with required particulate and iodine sampling.

NOTE 11 Change daily for 7 days, and analyze within 48 hours5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months of changeout, following each start-up, shutdown, or net thermal power change of greater than 15% of rated thcrmal power in one hour if either condition d(l) or d(2) of Note 3 are met. Neither weekly nor daily changeout is required by Tech Spec for condenser air ejector and steam packing exhaust unless a confirmed primary-to-secondary leak exists per criteria of Note 6), but routine monthly changeout is an administrative requirement. Requirement applies to RE-12442 or Temp. sample skid if RE-12444 is unavailable.

Pri'ed March 16, 2006 at 10:1 1

Ap;nc'oved By Procedure Number Rev hapii Sudara By; Vogtle Electric Generating Plant 3(i025-'C 53.1 Dx.e Approved PEF.IOI)IC ANAIYSIS SCHEDULING PROGRANI Page Number 12/08/2005 27 of 29 TABLE I (CONT'D.)

SCHEDULE FOR PERIODIC TESTS SOLID RAD WASTE SYSTEMS Prin Gamma Emitters Condensate Polisher P Resin Waste (Note 1)

Blowdown Demin P Resin Waste (Note 1) _

1 t t I

4. 4. f 4 Note I Prior to shipment to resin waste offsite.

II i!

i Ij i:

JI l

Printed Mardc 16, 2006 at 10:11

Approved IBy C C VCr Procedure Number Rev S'ilain Sunuclraiani V'ogtfe Mectr.. Gencrating Plant g 130025-C 53.1 Date Approved 12/08/2005 I PERIODIC ANALYSIS SCHEDULING PROGRAM I

Page Number 28 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS METEOROLOGICAL DATA COLLECTION CENTER Enter Arrival Time, EST.

Hardware Inspection W Data Comparison W Plastic Rainfall Cup A/R Check Printed March 16, 2006 at 10:1 1

(7j Ad IApproved nyvl Procedure Number Rev Shlaltii iranl l ltngt *.-tr - G~cretring PI atI 30025-C 53.1 Datc Appioved PERIODIC ANALYSIS SCIIEDULING PROGRAIM Pagc Number 12/08/2005 I 29 of 29 TABLE 1 (CONT'D.)

SCHEDULE FOR PERIODIC TESTS WATER TREATMENT PLANT S AM. LE NAME IAMP LUNG Conductivity .s1odium Silica Dissolved Chlorides Fluorides TOC I LOCATION . -I Oxygen -I I4 _--

Final Filter Final Filter Effluent Line D D D A/R A/R A/R Effluent at WTP Lab Sink I _ I .1 .

DST Demin Water Storage W AR AR W A/R A/R A/R Tank at WTP Sample Sink

_ _ , ,l Nlote I Sampling frequency may be increased at the Laboratory Supervisions discretion.

Note 2 Inline monitors may be used instead of grab samples.

Note 3 IF Demin is shutdown, no sampling is required. This note does not apply to the DST PrnntedMarch 1620al 6,2006 at 10:11 0:I

ML061000453

Text

5.0 REFERENCES

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