ML072890735

Final Status Survey Final Report Phase V, Appendix A4, Survey Unit Release Record 9520-0004, Southwest Site Storage Area

ML072890735
Person / Time
Site:	Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png
Issue date:	12/31/2006
From:	Mccarthy J Connecticut Yankee Atomic Power Co
To:	NRC/FSME
References
9520-0004
Download: ML072890735 (184)

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Final Status Survey Final Report Phase V

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December 2006

CYAPCO FINAL STATUS SURVEY RELEASE RECORD SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 3e Prepared By:

FSS Engineei Reviewed Byr:

tIS S Engine r Approved By: Lkd 4 Technical Support Manager Date: -/11/13166 Date:"

1-oG Date:_____

Revision 0

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD TABLE OF CONTENTS

1.

SURVEY UNIT DESCRIPTION 3..................................

3

2.

CLA SSIFICATION BA SIS..............................................................

.. 3

3.

DATA QUALITY OBJECTIVES (DQO)..........................................

5

4.

SURVEY DESIGN........................................................................ 7

5.

SURVEY IMPLEMENTATION.......................................................

10

6.

SU RV EY RESU LTS........................................................................

11

7.

QUALITY CON TROL....................................................................

14

8.

INVESTIGATIONS AND RESULTS.............................................

14

9.

REMEDIATION AND RESULTS...................................................

15

10. CHANGES FROM THE FINAL STATUS SURVEY PLAN......... 15

11. DATA QUALITY ASSESSMENT (DQA).......................................

15

12. A N O M A L IE S...................................................................................

15

13. C O N C LU SIO N.................................................................................

16

14. A TTA CH M EN TS.............................................................................

16 14.1 - Figures (6 pages including cover) 14.2 Attachment 2 - Scan Results (4 pages including cover) 14.3 Attachment 3 - Laboratory Data (144 pages including cover) 14.4 Attachment 4 - DQA Results (13 pages including covers)

TOTAL 183 Revision I

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD SURVEYUNIT DESCRIPTION Survey Unit 9520-0004 (Southwest Site Storage Area) is designated as Final Status Survey (FSS) Class I and consists of 1985 m2 (0.5 acres) of uninhabited open land located approximately 1,860 feet from the reference coordinate system benchmark used at Haddam Neck Plant (HNP) (see Attachment 1). The survey unit is bounded by Survey Unit 9520-0003. The survey unit is relatively level open space in the middle of the peninsula.

The restoration of the peninsula for FSS has removed most of the surface interference in the survey unit.

The reference coordinates associated with this survey unit are E005 through EO 11 by S086 through S091 (refer to License Termination Plan (LTP) Section 5.4.4).

The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit.

The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Connecticut State Plane System North American Datum (NAD) 1927.

2.

CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10, "Survey Unit Classification."

The "Classification Basis Summary" conducted for Survey Unit 9520-0004 consisted of:

a) A review of the IOCFR50.75 (g) (1) database, b) A review of the "Initial Characterization Report" and the "Historic Site Assessment Supplement, "

c) Historic and current survey records review, d) Visual inspections and a "walkdown."

A review of the 10CFR50.75(g)(1) database report and historical files shows a documented history of the use of this survey unit as a radioactive materials storage area. Examples of some of the major events are provided below.

a) Plant Incident Report (PIR) 80-37 reported the discovery of three (3) discrete sources of elevated activity on the Southeast Site Storage area in March 1980, along with other areas around the site.

The three (3) discrete sources were identified within adjacent Survey Units 9520-0001 and 9520-0002.

The elevated areas were removed upon detection according to the report.

b) Health Physics surveys performed in 1983 and 1985 document the discovery of radioactive material (strainers, bolts, wood pallets, sections of pipe, etc.) on the peninsula.

The 1985 survey documents the discovery of contaminated dirt under a pallet.

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD c) Condition Report (CR) 05-0314: Documents the discovery of excavation spoils, intended for backfill, above the radiological criteria for use as backfill. These spoils were likely located in Survey Units 9520-0003 and 9520-0004 on review of the documentation. According to the CR closure documentation, the affected spoils were removed and packaged for disposal. Follow-up survey and sampling was performed and the results were below established action. levels.

A review of the "Initial and Supplemental Characterization Reports" as well as the previous "Classification Basis Summaries" was performed.

Survey Unit 9520-0004 was initially included in Survey Unit 9520-0003, a Class 2 survey unit. However, in March of 2006, Co-60 and Cs-I 37 were identified in subsurface soils in sufficient quantities to warrant radiological remediation.

Radiological remediation was performed in July 2006. A new Class I survey unit, Survey Unit 9520-0004, was established to bound the area of remediation.

Characterization was performed in August 2006 to support final classification and FSS planning.

Statistical quantities (mean, median and standard deviation) from the 2006 characterization survey conducted under SSWP 06-07-006 are provided in Table 1.

TableI -1 hBasci Statisticaliur

-tit6sfr CsA37-fom tfe 2006 Claracterizatmnx l Minimum Observed Concentration (pCi/g):

1.86E-02 Maximum Observed Concentration (pCi/g):

4.80E-04 Mean (pCi/g):

1.62E-01 Median (pCi/g):

6.12E-02 Standard Deviation (pCi/g):

5.88E-02

-The FSS Engineer performed a visual inspection and walk-down during September 2006 to assess the physical condition of the survey unit, evaluate access points and travel paths and identify potentially hazardous conditions.

This survey area is affected by existing groundwater (reference CY memo ISC 06-024) which will be a source of dose from residual radioactivity, as discussed in Section 3 under the Data Quality Objectives.

Based upon the identification of radioactive material above the Derived Concentration Guideline Levels (DCGLs), and the need for radiological remediation, it was concluded that there was some probability for residual radioactivity in concentrations greater than the DCGLs, justifying a final survey unit classification of Class I (refer to Section 3).

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD

3.

DATA QUALITY OBJECTIVES (DQO)

FSS design and planning used the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1-11, "Preparation of Final Status Survey Plan, " and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM). A summary of the main features of the DQO process are provided herein.

The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would indicate that residual activity within the survey unit does not exceed the release criteria. Therefore, the survey unit does satisfy the primary objective of the FSS plan.

The primary objective of the FSS plan was to demonstrate that the level of residual radioactivity in Survey Unit 9520-0004 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).

A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity. This is done through the development of DCGLs. The DCGLs represent average levels of radioactivity above background levels and are presented in terms of surface or mass activity concentrations. Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soil (called Base Case Soil DCGL), existing groundwater radioactivity and future groundwater radioactivity that will be contributed by building basements and footings.

The DCGLs presented in Chapter 6 of the LTP were developed for exposures from three (3) components, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the bulrial of concrete foundations or footings from site buildings containing residual radioactivity.

Equation I shows the mathematical relationship between the three (3) components and the total dose.

Equation I HTotal =Hsoin++/-HExistingGW +HFut,'mreGW The total dose under the LTP criteria is twenty-five (25) mrem/yr TEDE from all three (3) components.

The allowable total dose under the Connecticut Department of Environmental Protection (CTDEP) radiological remediation Revision 0 5

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD standard for CY is nineteen (19) mrem/yr TEDE. To satisfy both the LTP and CY CTDEP criteria, the dose from soil must be reduced when using the existing and future groundwater dose values discussed above.

This survey area is affected by existing groundwater (reference CY memo ISC 06-024).

Therefore, the dose contribution from existing groundwater is bounded by two (2) mrem/yr TEDE.

This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no buried concrete foundations or footings containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contribution from future groundwater, the third dose component is, therefore, zero (0) mrem/yr TEDE.

Equation 2 19 mrem/yrTotl0

= 17 mrem/yrsoil + 2 mrem/yrExisting GW+ 0 mrelT'/yrFu(ureGW The allowable dose for soil in this survey unit is seventeen (17) mrem/yr TEDE as shown by Equation 2 above.

The concentration of residual radioactivity resulting in seventeen (17) mrem/yr TEDE is designated as the Operational DCGL, and has been established for the radionuclides of concern as provided in Table 2.

Table 2 Radbui"-roqi, Casi se- ~61 DC-GL, Qpe~rafioral:DCGLCI+-51 anfd RequirWed nft iniuinvietecble.-Coneentraions::,ý-1f, Radion udid e

b.

Basease'S-1 I

g, SQ 6eratio"beDCGL' 1.ReiiiMDO!

K. ~DP L~

)A~ ~. A~ 3(,C jg) 9 i~d}~)

H-3 4.12E+02 2.80E+02 1.65E+0OI C-14 5.66E+00 3.85E+00 2.26E-01 Mn-54 1.74E+O1 1.18E+OI 6.96E-01 Fe-55 2.74E+04 1.86E+04 1.1OE+03 Co-60 3.81E+00 2.59E+00 1.52E-01 Ni-63 7.23E+02 4.92E+02 2.89E+0 I Sr-90 1.55E+00 1.05E+00 6.20E-02 Nb-94 7.12E+00 4.84E+00 2.85E-01 Te-99 1.26E+1O 8.57E+00 5.04E-0I Ag-108m 7.14E+00 4.86E+00 2.86E-01 Cs-134 4.67E+00 3.18E+00 1.87E-01 Cs-137 7.91EE+00 5.38E+00 3.16E-01 Eu-152 1.01E+01 6.87E+00 4.04E-0I Eu-154 9.29E+00 6.32E+00 3.72E-0 I Eu-155 3.92E+02 2.67E+02 1.57E+01 Revision 0 6

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD SaTable2' DdmnullteSefi*Baseat Pu-238 2.96E+01 2.01 E+O 1 1.1 8E+00 Pu-239/240 2.67E+01 1.82E+01 1.07E+00 Pu-241 8.70E+02 5.92E+02 3.48E+01 Am-241")

2.58E+01 1.75E+01 1.03E+00 Cm-243/244 2.90E+O1 1.97E+01 1.16E+00 (1) Bold indicates those radionuclides considered to be Hard-to-Detect (HTD)

(2) The Base Case Soil DCGLs for soil are specified by the LTP in Chapter 6 and are equivalent to 25 mrem/yr TEDE (3) The Operational DCGL is equivalent to 17 mrem/yr TEDE (4) The required MDC is equivalent to I mrem/yr TEDE (5) Americium-241 can be analyzed by gamma and alpha spectroscopy and is considered to be Easy to Detect (ETD); the preferred result is the alpha spectroscopy's when both analyses are performed Another important facet of the DQO process is to identify the radionuclides of concern and determine the concentration variability.

Soil samples were collected in 2006 to establish the radiological condition of Survey Unit 9520-0004 for FSS. Cs-137 was the only gamma emitting radionuclide reported in concentrations with the potential for exceeding the screening criteria.

The characterization data were used for the survey design and are provided in Table 1.

Instrument DQOs included a verification of the ability of the survey instrument to detect the radiation(s) of interest relative to the DCGL. Survey instrument response checks were required prior to issue and after the instrument had been used. Control and accountability of survey instruments was required to assure the quality and prevent the loss of data.

As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. Results reported as less than Minimum Detectable Concentration (MDC) were not accepted for FSS. Sample report summaries included unique sample identification, analytical

method, radionuclide, result, and uncertainty to two (2) standard deviations, laboratory data qualifiers, units, and the required and observed MDC.

4.

SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. Guidance for preparing FSS plans is provided in Procedure RPM 5.1-11, "Preparation of Final Status Survey Plans". The FSS plan uses an integrated sample design that combines scanning surveys and sampling which can be either random or biased.

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD The DQO process determined that Cs-137 would be the radionuclide of concern in Survey Unit 9520-0004 (refer to Section 3). Other radionuclides identified during this FSS would be evaluated to ensure adequate survey design.

Surrogate DCGLs were not required for this survey unit based the previous FSS of this survey unit and via screening under LTP Section 5.4.7.2, "Gross Activity DCGLs".

Radionuclide screening or de-selection is a process where an individual radionuclide or aggregates may be considered insignificant and eliminated from the FSS. The criteria for de-selection are concentrations less than 5% for individual radionuclides and less than 10% for aggregates.

The Elevated Measurement Comparison (EMC) did apply to this survey unit since it is a Class 1 area and discrete, elevated areas of contamination were expected.

The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation.

This approach was conservative since it included background Cs-137 as part of the sample set.

The number of soil samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determination of the Number of Surface Samples for Final Status Survey." The Lower Bound of the Gray Region (LBGR) was set in accordance with Procedure RPM 5.1-11 to 5.27 to maintain the relative shift (A/a) in the range of 1 and 3. The resulting Adjusted Relative Shift was 2.0. A Prospective Power Curve was generated using COMPASS, a software package developed under the sponsorship of the United States Nuclear Regulatory Commission (USNRC) for implementation of the MARSSIM in support of the decommissioning license termination rule (10 CFR 20, Subpart E). The result of the COMPASS computer run showed adequate power for the survey design.

The survey design specified fifteen (15) surface soil samples for non-parametric statistical testing.

The grid pattern and locations of the soil samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying, and Marking Surface Sample Locations for Final Status Survey."

Visual Sample Plan was created by Pacific Northwest National Laboratory (PNNL) for the United States Department of Energy. A systematic triangular grid pattern with a random starting point was selected for sample design, which is appropriate for a Class I area.

Sample locations were identified using AutoCAD-LT, a commercially available plotting software package with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample locations in the field. Sample Measurement Locations for the design are listed with the GPS coordinates in Table 3.

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD Rn 9520-0004-001F 235584.13 669733.34 9520-0004-002F 235619.22 669753.61 9520-0004-003F 235654.32 669773.87 9520-0004-004F 235619.22 669794.13 9520-0004-005F 235584.13 669773.87 9520-0004-006F 235549.03 669753.61 9520-0004-007F 235549.03 669794.13 9520-0004-008F 235584.13 669814.39 9520-0004-009F 235619.22 669834.65 9520-0004-01 OF 235584.13 669854.91 9520-0004-01 IF 235549.03 669834.65 9520-0004-012F 235513.94 669814.39 9520-0004-013F 235513.94 669854.91 9520-0004-014F 235549.03 669875.18 9520-0004-015F 235584.13 669895.44 Procedure RPM 5.1-11 specifies that 5% of the samples are required to be selected for HTD analysis. Two (2) soil samples, or about 10% of the number of samples that would be used for non-parametric statistical testing were randomly selected for HTD radionuclide analysis using the Microsoft Excel "RANDBETWEEN" function. Each sample was sent off-site for a full suite analysis of the HTD radionuclides specified in the LTP, Table 2-12, "Radionuclides Potentially Present al 'Haddam Neck Plant" and as provided in Table 2.

The implementation of quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey," included the collection of two (2) soil samples for "split sample" analysis by the off-site laboratory. These locations were selected randomly using the Microsoft Excel "RANDBETWEEN" function. The number of quality control soil samples was about 10% of fifteen (15) samples.

The LTP specifies a required scanning coverage of 100% for outdoor Class I areas.

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD For this Class 1 survey unit, the "Investigation Level" for area scanning and soil sample measurement results are those levels specified in LTP, Table 5-8. Table 4 provides a synopsis of the survey design.

15 (15 systematic grid)

Type 1 and Type 2 errors were 0.05, sigma was 0.055 pCi/g, the LBGR was adjusted to 5.27 to maintain Relative Shift in the range of I and 3 Grid Spacing 12.4 m Based on triangular grid Operational DCGL 5.38 pCi/g Cs-137 Administratively set to achieve 17 mrem/yr TEDE ()

The Operational DCGL Soil Investigation Level 5.38 pCi/g Cs-137 conservatively meets the LTP criteria for a Class I survey unit Scan Survey Area Approximately The LTP requires 100% area SC veyrae 100%

coverage for Class I survey Coverage of the area units An instrument Based upon a Minimum Detectable Count Rate (MDCR)

Scan Investigation Level response gre of 1,597 cpm and a than 3,108 cpm o

,9 p

n above background corresponding DCGLEMC of 13.3 pCi/gt2)

(1) The allowable dose for soil in this survey unit is 17 mnrem/yr TEDE as the bounding dose from existing and future groundwater has been established based on field data (reference CY memo ISC 06-024)

(2) The Area Factor is 2.54 and the instrument conversion factor for Cs-137 is 228 cpm/pCi/g

5.

SURVEY IMPLEMENTATION FSS field activities were conducted under Work Plan and Inspection Record (WP&IR) 2006-0038. The WP&IR package included a detailed FSS plan, job safety analysis, job planning checklist and related procedures for reference.

Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.

A single scan area was established that constituted approximately 100% of the surface area of Survey Unit 9520-0004.

Grid lines, one meter wide, were painted on the ground of the scan area. A background survey was performed around the survey unit and it was determined that, using an Eberline E-600 with a SPA-3 sodium iodide detector, background ranged from 4,950 counts per minute (cpm) up to 7,230 cpm.

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD The scan area was established and scanned for elevated readings (see for all scan results). Scanning was performed with an Eberline E-600 using a SPA-3 sodium iodide detector. The E-600 was operated in the rate-meter mode and used with audio response. The probe was positioned as close to the ground as possible and was moved at a scan speed of about 0.5 meters per second. Approximately 100% of the survey unit was scanned.

Measurement locations were identified in North American Datum (NAD) 1927 coordinates using GPS coordinates; sample locations were identified and marked with a surveyor's flag or paint for identification.

At each sample location, a one (1) meter radius around the sample flag or paint mark was scanned for elevated radiation levels.

Seventeen (17) surface soil samples were collected and packaged in accordance with Haddam Neck Plant (HNNP) Procedure RPM 5.1-3, "Collection of Sample Media for Final Status Survey" and FSS design.

Samples were controlled, transported, stored, and transferred to the off-site laboratory using Chain-of-Custody (COC) protocol in accordance with Procedure RPM 5.1-5, "Chain of Custody for Final Status Survey Samples."

Two (2) samples (9520-0004-0111F and 9520-0004-014F) were randomly selected for HTD radionuclide analysis.

The implementation of survey specific quality control -measures included the collection of two (2) samples (9520-0004-004F and 9520-0004-012F) for "split sample" analysis.

6.

SURVEY RESULTS All field survey activities were conducted between October 13, 2006 and October 23, 2006.

Table 5 provides an overview of the scan results for sample measurement locations. Scan results are provided in Attachment 2.

Table 5-S~nRsitfrSnf~auiin bications`;

SaniPle, AihetLikjged

.Mesureniint Reading cin ee Actiont LevelAF Loaton(kPm)tikom 1

4.73 5.29 NO 2

5.39 5.37 YES 3

6.65 7.64 NO 4

5.89 6.42 NO 5

4.52 5.47 NO 6

5.05 5.57 NO Revision 0 ItI

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD 8

640

.71..

Loc~jkii?

tng i 7

6.59 6.55 YES 8

6.40 7.71 NO 9

6.78 6.58 YES 10 5.13 6.69 NO 11 5.46 6.91 NO 12 6.72 7.64 NO 13 6.42 8.17 NO 14

.. 7.44 6.76 YES 15 7.39 8.08 NO (1) The action level is based on a measurement above ambient background in accordance with the FSS plan The scan areas, that comprised approximately 100% of the total surface area for the survey unit, were scanned for elevated radiation levels. The survey unit was scanned in accordance with the FSS plan on October 17, 2006 through October 23, 2006.

Two elevated measurement locations were identified during scanning. Table 6 provides an overview of the scan area survey. Scan results are provided in Attachment 2.

- ~

~

x 2.Tbe6-Stap Aire esults,ý,

C, B-Hi1fest w-Scan n

2 ged.

Actio'n'Level '

l"aed

-Investigatio.-

~.ra Reaii

~p)

Readin~g--

Sml

~

Ietiflcation

.9520-04-ER-O01 -

95004-16 9520-0004-016F 1

27.1 7.88 26-1 04-ER 9520-004-017F P__ _ _ _31-1 (1) The action level is based on a measurement above ambient background (2) ER is an abbreviation associated with the barcodes used in the field where ER stands for Elevated Reading The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories, LLC. The laboratory analyzed the fifteen (15) samples collected for non-parametric statistical testing, the associated field splits, and the two (2) confirmatory samples using gamma spectroscopy.

Gamma spectroscopy analysis was performed to the required MDCs. Gamma spectroscopy results identified some radionuclides meeting the accepted criteria Revision 0 12

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD for detection (i.e., a result greater than two standard deviations uncertainty).

However, Cs-137 was the only radionuclide reported in concentrations exceeding the de-selection criteria.

Cs-137 was identified in thirteen (13) of the fifteen (15) samples collected for non-parametric statistical testing.

Cs-137 was the primary radionuclide confirming the DQOs. The mean of the gamma spectroscopic analysis results for the sample population indicated that Cs-137 was present at levels lower than the concentration of Cs-137 found in soil at off-site locations within the vicinity of the HNP as presented in the Health Physics TSD BCY-HP-0063.

A summary of the fifteen (15) samples collected for non-parametric statistical testing results is provided in Table 7.

• . abbe* 7-

"i§ A'-i

.,.<.I.-

-, t

,tt-ti-al Sample am 1,

4isfif7 SampW~uniL&-.s-1-3~7.

F:.

Prtibn ofiecr 9520-0004-001 F 3.19E-02 0.033 9520-0004-002F 2.85E-02 0.025 9520-0004-003F 3.94E-02 0.023 9520-0004-004F 5.92E-02 0.026 9520-0004-005F 3.15E-02 0.027 9520-0004-006F

-9.59E-03 0.016 9520-0004-007F 3.22E-02 0.028 9520-0004-008F 5.20E-02 0.026 9520-0004-009F 4.11E-02 0.023 9520-0004-OIOF 3.46E-02 0.029 9520-0004-01 IF 5.69E-02 0.040 9520-0004-012F 1.20E-01 0.037 9520-0004-013F 7.37E-02 0.022 9520-0004-014F 4.71E-02 0.020 9520-0004-015F 5.71E-02 0.024 (1) The Operational DCGL from Table 2 is 5.38 pCi/g for Cs-137 to achieve 17 mrem/yr TEDE The off-site laboratory also processed two (2) samples for HTD analysis as required by the sample plan.

The requested analyses included alpha spectroscopy, gas proportional counting, and liquid scintillation depending on the radionuclide and the measurement method. All analyses met the required MDC.

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SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD As previously stated in Section 4 of this report, the criteria for de-selection of a radionuclide is a concentration that is less than 5% of the Operational DCGL for individual radionuclides and less than 10% of the Operational DCGLs for aggregates.

H-3 was the only HTD, which by analysis, met the criteria for detection (i.e., a result greater than two standard deviations uncertainty). The highest result for H-3 was at 4% of the Operational DCGL.

9520-0004-01 IF 9.05E+00 0.032 9520-0004-014F 9.45E+00 0.034 (1) The Operational DCGL from Table 2 is 280 pCi/g for H-3 to achieve 17 mrem/yr TEDE

7.

QUALITY CONTROL The off-site laboratory processed the split samples and performed gamma spectroscopy analysis.

Ten percent (10%) of the samples were selected for analysis, which exceeds the 5% minimum required by the LTP. The data were evaluated using USNRC acceptance criteria specified in Inspection Procedure 84750 as detailed in HNP Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey". Cs-137 was not detected in sufficient quantities in the field split results at location 9520-0004-004 to evaluate in accordance with procedure. Evaluation using the reported results for K-40 resulted in acceptable agreement between the field split result at this location. There was acceptable agreement between the field split results at location 9520-0004-012.

The sample analysis vendor, General Engineering Laboratories, LLC, maintains quality control and quality assurance plans as part of normal operation. Refer to for data and data quality analysis results.

8.

INVESTIGATIONS AND RESULTS Two confirmatory samples were collected at the locations exhibiting elevated scan readings. The samples are denoted as shown in Table 6, with the sample results shown in Table 9 below.

Sample 1i -,Cs437q $hf'tl Frctonof 9520-0004-016F 1.25E-01 0.023 9520-0004-017F 1.68E-01 0.031 (1) The Operational DCGL from Table 2"is 5.38 pCi/g for Cs-13 7 to achieve 17 mrem/yr TEDE Revision 0 14 Revision 0 14

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD

9.

REMEDIATION AND RESULTS Radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit prior to FSS. The results for Cs-137 following remediation were well below the Operational DCGL provided in Table 2.

Cs-137 was not identified in any of the samples. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey, " determined that remediation beyond that required to meet the release criteria is unnecessary and that the remaining residual radioactivity in soil was ALARA.

10.

CHANGES FROM THE FINAL STATUS SURVEY PLAN No changes were made to the FSS plan.

11.

DATA QUALITY ASSESSMENT (DQA)

The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment, " for completeness and consistency.

The sampling design had adequate power as indicated by the Retrospective Power Curve. The Sign Test was performed on the data and compared to the original assumptions of the DQOs.

The evaluation of the Sign Test results demonstrates that the survey unit passes the unrestricted release criteria, thus, the null hypothesis is rejected.

Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 1.

The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation). The mean and median values are well below the Operational DCGL. Also, the retrospective power curve shows that a sufficient number of samples were collected to achieve the desired power.

Therefore, the survey unit meets the unrestricted release criteria with adequate power as required by the DQOs.

For Cs-137, the range of the data, about five (5) standard deviations, was not an overly large variation considering that the levels were essentially at existing environmental levels where such variation is to be expected. The difference between the mean and median was about 20% of the standard deviation which indicates slight skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot indicates positive skewness as confirmed by the calculated skew of 0.88.

All data, assessments, and graphical representations are provided in Attachment 4.

12.

ANOMALIES No anomalies were noted.

Revision 0 15 Revision 0 15

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD

13.

CONCLUSION Survey Unit 9520-0004 has met the final DQOs of the FSS plan. The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved following remedial action. Elevated Measurement Comparison was not required.

Cs-137 was used for statistical testing to determine the adequacy of the survey unit for FSS.

The sample data passed the Sign Test. The null hypothesis was rejected. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved. The survey unit is properly designated as Class 1.

The dose contribution from soil is less than 1 mrem/yr TEDE based on the average concentration of the samples used for non-parametric statistical sampling.

This survey area is affected by existing groundwater (reference CY memo ISC 06-024); therefore the dose contribution from existing groundwater is bounded at two (2) mrem/yr TEDE.

This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no underground structures, systems or components containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024); therefore, the dose contribution from future groundwater is zero (0) mrem/yr TEDE.

The average total dose from residual radioactivity in this survey unit, including exposures from the three (3) components as described in Section 3, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity, will not exceed 3 mrem/yr TEDE.

Therefore, Survey Unit 9520-0004 is acceptable for unrestricted release.

14.

ATTACHMENTS 14.1 Attachment 1 - Figures 14.2 Attachment 2 - Scan Results 14.3 Attachment 3 - Laboratory Results 14.4 Attachment 4 - DQA Results Revision 1 16

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 1 (FIGURES)

~0 Refewec CoordInate Sp.tem BenchmOa*

Norhing - 236594.38 / Eoating -

668136.14 I//I

'c:.

J-CONNfCTICUrT RIVER-J Connecticut Yankee Atomic Power Company C

• Site Map With Reference To Survey Unit 9520-0004

Legend 0,f:

Sample Point 0

20 40 iF.1 5,,

Connecticut Yankee Atomic Power Company Survey Unit 9520-0004 Final Status Survey Design

Legend 20 40 0.04 0.06 Notes 0.05 Reported Concentrations in pCIg 0.03 0.06 0.03 0.08 0.03 0.03 Connecticut Yankee Atomic Power Company Survey Unit 9520-0004 Final Status Survey Cs-137 Posting Plot

Legend

= Scan Area 0

20 40 Id Feet Notes Background ranged from 5.0 kcpm to 72 kcpm as detenrined by an E-600 with SPA-3 Probe Refer to Table 6 for scan area results Connecticut Yankee Atomic Power Company Date By Survey Unit 9520-0004 Final Status Survey Scan Areas November2006 J. McCarthy

= Scan Aran 0= Sample Point 0

20 40 IFet 6

Notes Refer to Table 9 for confirmator sample results Connecticut Yankee Atomic Power Company Survey Unit 9520-0004 Final Status Survey Confirmatory Samples

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 2 (SCAN RESULTS)

Survey Release Record Sample Location Scan Results Survey Unit 9520-0004 Sample Name 9520-04-SL-00-011-0 9520-04-SL-00-02-0 9520-04-SL-00-03-0 9520-04-SL-00-04-0 9520-04-SL-00-05-0 9520-04-SL-00-06-0 9520-04-SL-00-07-0 9520-04-.SL-00-08-0 9520-04-SL-00-09-0 9520-04-SL-00-1 0-0 9520-04-SL-00-1 1-0 9520-04-SL-00-12-0

• 9520-04-SL-00-13-0 9520-04-SL-00-14-0 9520-04-SL-00-1 5-0

Background

1CPM) 4.35E+03 4.42E+03 6.49E+03 5.37E+03 4.51E+03 4.60E+03 5.49E+03 6.55E+03 5.52E+03 5.62E+03 5.82E+03 6.49E+03 6.98E+03 5.68E+03 6.89E+03 Action Level Results Above (cPm)

AL Log Date Log Time E600 S/N Probe S/N 5.29E+03 5.37E+03 7.64E+03 6.42E+03 5.47E+03 5.57E+03 6.55E+03 7.71 E+03 6.58E+03 6.69E+03 6.91 E+03 7.64E+03 8.17E+03 6.76E+03 8.08E+03 4.73E+03 5.39E+03 6.65E+03 5.89E+03 4.52E+03 5.05E+03 6.59E+03 6.40E+03 6.78E+03 5.13E+03 5.46E+03 6.72E+03 6.42E+03 7.44E+03 7.39E+03 10/13/2006

+

10/13/2006 10/13/2006 10/13/2006 10/13/2006 10/13/2006

+

10/13/2006 10/13/2006

+

10/13/2006 10/13/2006 10/13/2006 10/13/2006 10/13/2006

+

10/13/2006 10/13/2006 8:15:00 9:29:00 9:37:00 9:46:00 10:02:00 10:15:00 10:27:00 10:53:00 11:04:00 12:52:00 13:02:00 13:14:00 13:33:00 13:54:00 13:58:00 1105 1105 1105 1105 1105 1105 1105 1105 1105 1105 1105 1105 1105 1105 1105 1012 1012 1012 1012 1012 1012 1012 1012 1012 1012 1012 1012 1012 1012 1012 AL - Action Level

Survey Release Record Scan Area Results Survey Unit 9520-0004 9520-0004 SCAN AREA 1 Sample Name 9520-04-SC-01-01-0 9520-04-SC-01-02-0 9520-04-SC-01-03-0 9520-04-SC-01-04-0 9520-04-SC-01-05-0 9520-04-SC-01-06-0 9520-04-SC-01-07-0 9520-04-SC-01-08-0 9520-04-SC-01-09-0 9520-04-SC-01-10-0 9520-04-SC-01-11-0 9520-04-SC-01-12-0 9520-04-SC-01-13-0 9520-04-SC-Cl114-0 9520-04-SC-01-15-0 9520-04-SC-01-16-0 9520-04-SC-01-17-0 9520-04-SC-0C1-18-0 9520-04-SC-01-19-0 9520-04-SC-01-20-0 9520-04-SC-01-21-0 9520-04-SC-01-22-0 9520-04-SC-01-23-0 9520-04-SC-01-24-0 9520-04-SC-01-25-0 9520-04-SC-01-26-0 9520-04-ER-01-26-1 9520-04-SC-01-27-0 9520-04-SC-01-28-0

Background

(cPM) 5.96E+03 7.17E+03 5.74E+03 6.38E+03 6.61 E+03 6.49E+03 6.24E+03 6.06E+03 6.40E+03 5.26E+03 5.70E+03 7.13E+03 6.89E+03 6.70E+03 7.12E+03 6.31 E+03 7.23E+03 5.83E+03 6.48E+03 6.37E+03 5.10E+03 5.30E+03 4.95E+03 5.15E+03 5.59E+03 6.39E+03 6.39E+03 6.65E+03 6.57E+03 Action Level IcM.m) 7.06E+03 8.38E+03 6.82E+03 7.52E+03 7.77E+03 7.64E+03 7.37E+03 7.17E+03 7.54E+03 6.30E+03 6.78E+03 8.34E+03 8.08E+03 7.87E+03 8.32E+03 7.44E+03 8.44E+03 6.92E+03 7.63E+03 7.51 E+03 6.12E+03 6.34E+03 5.95E+03 6.17E+03 6.66E+03 7.53E+03 7.53E+03 7.81 E+03 7.73E+03 Results Above (cpm)

AL Log Date Log Time E600 S/N Probe S/N 6.64E+03 5.43E+03 6.45E+03 6.82E+03 6.19E+03 6.86E+03 5.63E+03 6.68E+03 5.48E+03 5.96E+03 6.32E+03 6.11E+03 5.61 E+03 6.37E+03 5.77E+03 6.46E+03 6.68E+03 6.13E+03 6.45E+03 5.94E+03 5.59E+03 5.05E+03 4.75E+03 5.03E+03 5.16E+03 5.26E+03 2.34E+04 5.06E+03 5.11E+03 10/17/2006 10/17/2006 10/17/2006 10/19/2006 10/19/2006 10/19/2006 10/19/2006 10119/2006 10/19/2006 10/19/2006 10/23/2006 10/23/2006 10/19/2006 10/19/2006 10/19/2006 10/23/2006 10/23/2006 10/19/2006 10/19/2006 10/19/2006 10/18/2006 10/18/2006 10/18/2006 10/18/2006 10/18/2006 10/18/2006

+

10/19/2006 10/18/2006 10/18/2006 14:05:00 14:10:00 14:13:00 13:30:00 13:36:00 13:42:00 13:46:00 13:52:00 13:57:00 14:04:00 8:14:00 8:18:00 14:07:00 14:11:00 14:14:00 8:21:00 8:24:00 14:21:00 14:24:00 14:29:00 14:34:00 14:30:00 14:24: 00 14:22:00 14:16:00 14:11:00 7:37:00 14:05:00 13:55:00 1112 1112 1112 1105 1105 1105 1105 1105 1105 1105 1117 1117 1105 1105 1105 1117 1117 1105 1105 1105 1114 1114 1114 1114 1114 1114 1105 1114 1114 1013 1013 1013 1012 1012 1012 1012 1012 1012 1012 1001 1001 1012 1012 1012 1001 1012 1012 1012 1.014 1014 1014 1014 1014 1014 1012 1014 1014 AL - Action Level

Survey Release Record Scan Area Results Survey Unit 9520-0004 9520-04-SC-01-29-0 9520-04-SC-01-30-0 9520-04-SC-01-31-0 9520-04-ER-01-31-1 9520-04-SC-01-32-0 9520-04-SC-01-33-0 9520-04-SC-01-34-0 9520-04-SC-01-35-0 6.67E+03 6.23E+03 6.71 E+03 6.71 E+03 6.78E+03 6.24E+03 6.66E+03 6.46E+03 7.84E+03 7.36E+03 7.88E+03 7.88E+03 7.96E+03 7.37E+03 7.83E+03 7.61 E+03 5.68E+03 5.67E+03 5.43E+03 2.71 E+04 5.50E+03 5.19E+03 5.22E+03 6.50E+03 10/18/2006 10/18/2006 10/18/2006

+

10/19/2006 10/18/2006 10/18/2006 10/18/2006 10/18/2006 13:48:00 13:44:00 13:39:00 7:38:00 13:35:00 13:25:00 13:21:00 13:16:00 1114 1114 1114 1105 1114 1114 1114 1114 1014 1014 1014 1012 1014 1014 1014 1014 AL - Action Level

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 3 (LABORATORY DATA)

General Narrative 1

General Narrative for Connecticut Yankee Atomic Power Co.

Work Order: 174346 SDG: MSR#06-1375 October 24, 2006 Laboratory Identification:

General Engineering Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 Summary Sample receipt The samples arrived at General Engineering Laboratories, LLC, Charleston, South Carolina on October 18, 2006 for analysis. Shipping container temperatures were checked, documented, and within specifications. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any Visible signs of tampering or breakage.

Sample Identification The laboratory received the following samples:

Laboratory Identification 174346001 174346002 174346003 174346004 174346005 174346006 174346007 174346008 174346009 174346010 174346011 174346012 174346013 174346014 174346015 174346016 174346017 Sample Description 9520-0004-001 F 9520-0004-002F 9520-0004-003F 9520-0004-004F 9520-0004-004FS 9520-0004-005F 9520-0004-006F 9520-0004-007F 9520-0004-008F 9520-0004-009F 9520-0004-OIOF 9520-0004-012F 9520-0004-012FS 9520-0004-013F 9520-0004-015F 9520-0004-01IF 9520-0004-014F Items of Note There are no items to note.

Case Narrative GENERAL ENGINEERING LABORATORIES, LLC a Member o0 THE GEL GROUP, INC.

P.O. BOX 30712 Charleston, SC 29417

• 2040 Savage Road (29407)

Phone (843) 556-6171

• Faxa43) 766-1178 vvww.gel.com

Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL)

Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package.

Analytical Request Fifteen soil samples were analyzed for FSSGAM. Two soil samples were analyzed for FSSALL.

Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, Data Review Qualifier Definitions, and data from the following fractions: Radiochemistry.

I certify that this data package is in compliance with the SOW, both technically and for completeness, for other thdi the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.

ChPect Manage Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.

P.O. BOX 30712 Charleston, SC 29417

• 2040 Savage Road (29407)

Phone (843) 556-8171, Fax343) 766-1178 www.gel.com

List of current GEL Certifications as of 24 October 2006 State Certification Alaska UST-062 Arizona AZ0668 Arkansas 88-0651 CLIA 42D0904046 California 01151CA Colorado GenEngLabs Connecticut PH-0169 Dept. of Navy NFESC 413 EPA WG-15J Florida/NELAP E87156 Georgia E87156 (FLJNELAP)

Hawaii N/A Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas E-a10332 Kentucky 90129 Louisiana 03046 Maryland 270 Massachusetts M-SC012 Michigan 9903 Nevada SC12 New Jersey SC002 New Mexico FL NELAP E87156 New York 11501 North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-00485 South Carolina 10120001/10585001/10120002 Tennessee 02934 Texas TX213-2006A Texas NELAP T104704235-06-TX U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah 8037697376 GEL Vermont VT87156 Virginia 00151 Washington C 1641 4

Chain of Custody and Supporting Documentation 5

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00630 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested L2abUsesOhly:

Contact Name & Phone:

Comments::

Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)

General Engineering Laboratories

.4 2040 Savage Road. Charleston SC. 29407 0

843 556 8171. Attn. Cheryl Jones V)

Priority: [1 30 D. [] 14 D. Z 7 D. El 3 D.

Sapl o...e Sample Size-1 Sample Designation Date Time Media Type

&Type Comment, Preservation Lab Sample ID Code Code Code 9520-0004-001F 10/13/06 0817 TS G

BP X

9520-0004-002F 10/13/06 0932 T.S G

BP X

9520-0004-003F 10/13/06 0941 TS G

BP X

9520-0004-004F 10/13/06 0949 TS G

BP X

9520-0004-004FS 10/13/06 0949 TS G

BP X

9520-0004-005F 10/13/06 1005 TS G

BP X

9520-0004-006F 10/13/06 1018 TS G

BP X

9520-0004-007F 10/13/06 1030 TS G

BP X

9520-0004-008F 10/13/06 1055 TS G

BP X

9520-0004-009F 10/13/06 1107 TS G

BP X

NOTES: PO #: 002332 MSR #: 06-1 375 SSWP# NA Z LTP QA Ei Radwaste QA Li Non QA

1) Relinqui d By Date/Time

2) Received By Date/Time

3) 1i6nquis[Ked By Date/Time

4) Received By Date/Time Samples Shipped-Via:

[

Fed Ex Li UPS Li Hand L-Other 17 ?9

.9o.2 WO06 Bill of Lading #

Internal Container Temp.:

Deg.

C Custody:Sealed?

Custody Seal..

ntac**:.n

"".t?

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Chain of Custody Form N.20-03 Connecticut Yankee Atomic Power Company No. 2006-00631 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab UgeiOhly...

Contact Name & Phone:

Comments:

Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority: F-1 30 D. E] 14 D. Z 7 D. l 3 D.

Container Sample Size-Sample Designation Date Time Media Type

&Type Comment, Preservation Lab Saiple ID Code Code Code 9520-0004-OIOF 10/13/06 1255 TS G

BP X

9520-0004-01IF 10/13/06 1305 TS G

BP X

9520-0004-012F 10/13/06 1317 TS G

BP X

9520-0004-012FS 10/13/06 1317 TS G

BP X

9520-0004-013F 10/13/06 1336 TS G

BP X

9520-0004-014F 10/13/06 1357 TS G

BP X

9520-0004-015F 10/13/06 1402 TS G

BP X

NOTES: PO #: 002332 MSR #: 06-1375 SSWP#NA Z LTPQA F1 Radwaste QA F-Non QA

1) Relin Date/Time

2) Received By Date/Time 13yDai 4)o 113 v ive 736

3) Reli6 ished By Date/Time

4) Received By Date/Time' Samples Shipped Via:

0 Fed Ex El ups E] Hand El Other 79O,.1?. 9A-Bill of Lading #

Internal.Container

• Te-m p.:

Deg.

C Custody.:Sealed?

Y Er-N F.1 Custody Seal:

Intact?.

Y *.

.N

Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-O01 Figure 1. Sample Check-in List.

Date/Time Received: /A- / - A" SDG#:-

b2Lo

,1ý6 Work Order Number:

V 4-l k

-3' I

Shipping Container ID: 271o 1

eVG2 j/. a Chain of Custody #,bO* -

'O.&30. oO Q-3/1 606-3.i I.

Custody Seals oti shipping container intact?..

Yes No

2.

Custody Seals dated and, signed?

Yes* [

No [..

3.

Chain-of-Custo.y record present?

Yes [91o [

4.

Cooler temperature

5.

Vermiculite/packing materials is:

Wet [

Dry [, ]

6.'

Number of samples in shipping container:

4'

7.

Sample holding times exceeded?

Yes [] No [

8. Samples have.

-tap

-hazard labels

_Custody seals

-appropriate sample labels

.9. Samples are:

it.

in good condition leaking

-broken

-have air bubbles

10.

Were any anomalies identified in sample receipt?

Yes [ ] No 1..

• Description of anomalies (include sample numbers):

Sample* Custodian/Laboratory:

.0 Date:

b/ -"'

Telephoned to:

On By__

Data Review Qualifier Definitions 9

Data Review Qualifier Definitions Qualifier Explanation A quality control analyte recovery is outside of specified acceptance criteria Analyte is a surrogate compound Result is less than value reported a

Result is greater than value reported RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank B

Metals-Either presence of analyte detected in the associated blank, or.

MDL/IDL < sample value < PQL BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample d

5-day BOD-The 2:1 depletion requirement was not met for this sample E

Organics-Concentration of the target analyte exceeds the instrument calibration range E

Metals-%difference of sample and SD is

>10%.

Sample concentration must meet flagging criteria H

Analytical holding time was exceeded h

Preparation or preservation holding time was exceeded J

Value is estimated N

Metals-The Matrix spike sample recovery is not within specified control limits N

Organics-Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC).

Quantitation is based on nearest internal standard response factor N/A Spike recovery limits do not apply.

Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the reporting limit UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound Z

Paint Filter Test-Particulates passed through the filter, however no free liquids were observed.

GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, NC.

P.O. BOX 30712 Charleston, SC 29417

• 2040 Savage Road (29407)

Phone (843) 556-8171

• Fae1t3) 766-1178 www.gel.com

RADIOLOGICAL ANALYSIS 11

Radiochemistry Case Narrative Connecticut Yankee Atomic Power.Co. (YANK)

Work Order 174346 Method/Analysis Information

• Product:

Alphaspec Am241, Cm, Solid ALL FSS Analytical Method:

DOE EML HASL-300, Am-05-RC Modified Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 580396 580482 580480 Sample ID 174346016 174346017 1201210037 1201210038 1201210039 1201210040 Client ID 9520-0004-01 IF 9520-0004-014F Method Blank (ME!)

174224006(9520-0002-008F) Sample Duplicate (DUP) 174224006(9520-0002-008F) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

12

Quality Control (00 Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174224006 (9520-0002-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 174346016 (9520-0004-01 IF) was recounted due to a negative result greater than three times the error.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:

NCR 374838 was generated due to Container scanning event for custody missed. 1. The analyst did not scan the samples into the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on proper scanning procedures. 1. Reporting results.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information 13

Product-Alphaspec Pu, Solid-ALL FSS Analytical Method:

Prep Method:

DOE EML HASL-300, Pu-I -RC Modified Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 580398 580482 580480 Sample ID 174346016 174346017 1201210045 1201210046 1201210047 1201210048 Client ED 9520-0004-01 IF 9520-0004-014F Method Blank (MB) 174224006(9520-0002-008F) Sample Duplicate (DUP) 174224006(9520-0002-008F) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174224006 (9520-0002-008F).

QC Information All of the QC samples met the required acceptance limits.

14

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:.

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:

NCR 374219 was generated due to Container scanning event for custody missed. 1. The analyst did not scan the samples into the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on proper scanning procedures. 1. Reporting results.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Pu241, Solid-ALL FSS Analytical Method:

DOE EML HASL-300, Pu-I 1-RC Modified Prep Method:

Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:

Dry Soil Prep Analytical Batch Number:

580400 Prep Batch Number:

580482 Dry Soil Prep GL-RAD-A-021 Batch Number:

580480 15

Sample ID Client ID 174346016 9520-0004-011F 174346017 9520-0004-014F 1201210053 Method Blank (MB) 1201210054 174224006(9520-0002-008F) Sample Duplicate (DUP) 1201210055 174224006(9520-0002-008F) Matrix Spike (MS) 1201210056 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174224006 (9520-0002-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prepfRe-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 16

referenced SOP or contractual documents. The following NCR was generated for this SDG:

NCR 374454 was generated due to Container scanning event for custody missed. 1. Samples 174346 016,017 were scanned. There is an error with AlphaLIMS making it appear that they were not. 1.

Reporting results and investigating cause of error.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method:

EML HASL 300, 4.5.2.3 Prep Method:

Dry Soil Prep Analytical Batch Number:

581675 Prep Batch Number:

580480 17

Sample ID 174346001 174346002 174346003 174346004 174346005 174346006 174346007 174346008 174346009 174346010 174346011 174346012 174346013 174346014 174346015 174346016 174346017 1201213157 1201213158 1201213159 Client ED 9520-0004-001 F 9520-0004-002F 9520-0004-003F 9520-0004-004F 9520-0004-004FS 9520-0004-005F 9520-0004-006F 9520-0004-007F 9520-0004-008F 9520-0004-009F 9520-0004-01 OF 9520-0004-012F 9520-0004-012FS 9520-0004-013F 9520-0004-015F 9520-0004-01 IF 9520-0004-014F Method Blank (MB) 174346001(9520-0004-OOF) Sample Duplicate (DUP)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard'solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174346001 (9520-0004-OOF).

QC Information All of the QC samples met the required acceptance limits.

18

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Qualifier Reason Analyte U1 U'

U' Data rejected due to high counting uncertainty.

Bismuth-212 Potassium-40 Sample 174346013 1201213157 Data rejected due to interference.

Data rejected due to low abundance.

Cesium-134 174346008 Europium-155 174346016 Cesium-134 174346001 174346002 174346003 174346009 174346011 174346014 174346015 Method/Analysis Information 19

Product:

GFPC, Sr90, solid-ALL FSS Analytical Method:

EPA 905.0 Modified Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 580488 580482 580480 Sample ID 174346016 174346017 1201210298 1201210299 1201210300 1201210301 Client ID 9520-0004-01IF 9520-0004-014F Method Blank (MB) 174224006(9520-0002-008F) Sample Duplicate (DUP) 174224006(9520-0002-008F) Matrix Spike (MS)

Laboratory Control Sample (LCS),

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

0uality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174224006 (9520-0002-008F).

QC Information All of the QC samples met the required acceptance limits.

20

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 1201210299 (9520-0002-008F) was recounted due to high MDA.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:

NCR 375263 was generated due to Container scanning event for custody missed. 1. Samples 174346016 and 174346017 were scanned into the batch prior to analysis, but the event did not save due to a computer network error. Custody of the samples was maintained at all times. 1. Reporting results.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Tc99, Solid-ALL FSS Analytical Method:

DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number:

580727 Sample ID Client ID 174346016 9520-0004-01 IF 174346017 9520-0004-014F 1201210846 Method Blank (MB) 1201210847 174346016(9520-0004-01 IF) Sample Duplicate (DUP) 1201210848 174346016(9520-0004-01 IF) Matrix Spike (MS) 1201210849 Laboratory Control Sample (LCS) 21

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174346016 (9520-0004-01 IF).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:

NCR 375329 was generated due to Container scanning event for custody missed. 1. The analyst did not scan the samples 174346016 and 174346017 into the batch prior to analysis, however the samples did remain in their custody at all times. 1. The error has been corrected and the analyst has been instructed on the proper scanning procedures. Reporting results.

Additional Comments Additional comments were not required for this sample set.

22

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Fe55, Solid-ALL FSS DOE RESL Fe-1, Modified Analytical Method:

Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 580395 580482 580480 Sample ID 174346016 174346017 1201210033 1201210034 1201210035 1201210036 Client ID 9520-0004-01 IF 9520-0004-014F Method Blank (MB) 174224006(9520-0002-008F) Sample Duplicate (DUP) 174224006(9520-0002-008F) Matrix Spike (MS)

Laboratory ControlSample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting souices were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

23

Designated QC The following sample was used for QC: 174224006 (9520-0002-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Ni63, Solid-ALL FSS DOE RESL Ni-1, Modified Analytical Method:

Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 580397 580482 580480 24

Sample ID Client ID 174346016 9520-0004-01 IF 174346017 9520-0004-014F 1201210041 Method Blank (MB) 1201210042 174224021(9520-0002-015F) Sample Duplicate (DUP) 1201210043 174224021(9520-0002-015F) Matrix Spike (MS) 1201210044 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s):

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174224021 (9520-0002-015F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 25

referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Analytical Method:

Analytical Batch Number:

Sample ID 174346016 174346017 1201210854 1201210855 1201210856 1201210857 LSC, Tritium Dist, Solid-HTD2,ALL FSS

.EPA 906.0 Modified 580729 Client ID 9520-0004-01 IF 9520-0004-014F Method Blank (MB) 174346016(9520-0004-01 IF) Sample Duplicate (DUP) 174346016(9520-0004-01 IF) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the ekpiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (0C) Information:

Blank Information The blank volume is.representative of the sample volumes in this batch.

26

Designated QC The following sample was used for QC: 174346016 (9520-0004-01 IF).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples were recounted due to low/high recovery.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint C14, Solid AII,FSS Analytical Method:

Analytical Batch Number:

Sample ID 174346016 174346017 1201210858 1201210859 1201210860 1201210861 EPA EERF C-01 Modified 580730 Client ID 9520-0004-01 IF 9520-0004-014F Method Blank (MB) 174346016(9520-0004-01 IF) Sample Duplicate (DUP) 174346016(9520-0004-01 IF) Matrix Spike (MS)

Laboratory Control Sample (LCS) 27

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174346016 (9520-0004-01 IF).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses..

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nornconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

28

Qualifier information Manual qualifiers were not required.

Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.

Review Validation:

GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.

The following data validator verified the information presented in this case narrative:

Reviewer/Date:

I-29

General Engineering Laboratories Form GEL-NCR Rev. 06/05 NCR Report No.:

374219 Revision No.:

1 COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.

Division:

Quality Criteria:

Type:

21 -OCT-06 Radiochemistry Specifications Process Instrument Type:

Test I Method:

Matrix Type:

Client Code:

ALPHA SPECTROMETER DOE EML HASL-300, Pu-11-RC Solid YANK

.Vl0difi*

d Batch ID:

Sample Numbers:

580398 See Below Potentially affected work order(s)(SDG): 174224(MSR#06-1371),174228(MSR#06-1370),174346(MSR#06-1375)

Application Issues:

Container scanning event for custody missed Specification and Requirements NRG Disposition:

Nonconformance

Description:

1. The analyst did not scan the samples into the batch prior to analysis,

1. Reporting results.

however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on proper scanning procedures.

Originator's Name:

Eric Brimstin Quality Review:

Data Validator/Group Leader:

Lesley Anderson 22-OCT-06 21 -OCT-06 Director:

Page 1 30

General Engineering Laboratories Form GEL-NCR Rev. 06/05 NCR Report No.:

374454 Revision No.:

COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.

Division:

Quality Criteria:

Type:

23-OCT-06 Radiochemistry Specifications Process Instrument Type:

Test / Method:

Matrix Type:

Client Code:

LSC DOE EML HASL-300, Pu-1 IoRC Solid YANK

-- Modflaed Batch ID:

Sample Numbers:

580400 Se6 Below Potentially affected work order(s)(SDG)" 174224(MSR#06-1371),174228(MSR#06-1370),174346(MSR#06-1375)

Application Issues:

Container scanning event for custody missed Specification and Requirements NRG Disposition:

Nonconformance

Description:

1. Samples 174346 016,017 were scanned. There is an error with

1. Reporting results and investigating cause of error.

AlphaLIMS making it appear that they were not.

Originator's Name:

Amy Scott Quality Review:

Data Validator/Group Leader:

Lesley Anderson 23-OCT-06 23-OCT-O6 Director:

Page 1 31

General Engineering Laboratories Form GEL-NCR Rev. 06/05 NCR Report No.:

374838 Revision No.:

COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.

Division:

Quality Criteria:

Type:

23-OCT-06 Radiochemistry Specifications Process Instrument Type:

Test / Method:

Matrix Type:

Client Code:

ALPHA SPECTROMETER DOE EML HASL-300, Am-05-RC Solid YANK

-Modffted-Batch ID:

Sample Numbers:

580396 See Below Potentially affected work order(s)(SDG): 174224(MSR#06-1371),174228(MSR#06-1370),174346(MSR#06-1375)

Application Issues:

Container scanning event for custody missed Specification and Requirements NRG Disposition:

Nonconformance

Description:

1. The analyst did not scan the samples into the batch prior to analysis,

1. Reporting results.

however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on proper scanning procedures.

Originator's Name:

Jessica Downey Quality Review:

Data Validator/Group Leader:

Melanie Aycock 24-OCT-06 23-OCT-06 Director:

Page 1 32

General Engineering Laboratories Form GEL-NCR Rev. 06105 NCR Report No.:

375263 Revision No.:

1 COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.

Division:

Quality Criteria:

Type:

24-OCT-06 Radiochemistry Specifications Process Instrument Type:

Test / Method:

Matrix Type:

Client Code:

GFPC EPA 905.0 Modified Solid YANK Batch ID:

Sample Numbers:

580488 See Below Potentially affected work order(s)(SDG): 174224(MSR#06-1371),174346(MSR#06-1375)

Application Issues:

Container scanning event for custody missed Specification and Requirements NRG Disposition:

Nonconformance

Description:

1. Samples 174346016 and 174346017 were scanned into the batch prior

1. Reporting results.

to analysis, but the event did not save due to a computer network error.

Custody of the samples was maintained at all times.

Originator's Name:

John Parker Quality Review:

Data Validator/Group Leader:

Lesley Anderson 25-OCT-06 24-OCT-06 Director:

Page 1 33

General Engineering Laboratories Form GEL-NCR Rev. 06/05 NCR Report No.:

375329 Revision No.:

COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.

Division:

Quality Criteria:

Type:

24-OCT-06 Radiochemistry Specifications Process Instrument Type:

Test / Method:

Matrix Type:

Client Code:

LSC DOE EML HASL-300, Tc-02-RC Solid YANK Modfed Batch ID:

Sample Numbers:

580727 See Below Potentially affected work order(s)(SDG): 174346(MSR#06-1375)

Application Issues:

Container scanning event for custody missed Specification and Requirements NRG Disposition:

Nonconformance

Description:

1. The analyst did not scan the samples 174346016 and 174346017 into

1. The error has been corrected and the analyst has been instructed on the batch prior to analysis, however the samples did remain in their the proper scanning procedures. Reporting results.

custody at all times.

Originator's Name:

Melanie Aycock Quality Review:

Data Validator/Group Leader:

Lesley Anderson 25-OCT-06 24-OCT-06 Director:

Page 1 34

SAMPLE DATA

SUMMARY

35

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANK001 Connecticut Yankee Atomic Power Co.

Client SDG: MSR#06-1375 GEL Work Order: 174346 The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Analyte is a surrogate compound

.U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the detection limit.

The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.

This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones.

Reviewed by 36

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date:

October 26, 2006:

Client Sample ID:

9520-0004-OOIF Proiect:

YANK01204 SamplelD:

174346001 Client ID:

YANK001 Matrix:

Soil Vol. Recv.:

Collect Date:

13-OCT-06 Receive Date:

18-OCT-06 Collector:

Client Moisture:

7.09%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gammna,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.739

+/-0.156 Americium-241 U -0.00139

+/-0.0236 Bismuth-212 0.368

+/-0.265 Bismuth-214 0.442

+/-0.0807 Cesium-134 UI 0.00

+/-0.0441 Cesium-137 U

0.0319

+/-0.0333 Cobalt-60 U -0.00636

+/-0.0198 Europium-152 U

0.00386

+/-0.0449 Europium-154 U

0.0267

+/-0.0569 Europium-155 U

0.0194

+/-0.0412 Lead-212 0.412

+/-0.0541 Lead-214 0.499

+/-0.0827 Manganese-54 U

0.00185

+/-0.0195 Niobium-94 U -0.00452

+/-0.0184.

Potassium-40 6.70

+/-0.609 Radium-226 0.442

+/-0.0807 Silver-tO0m U

0.00712

+/-0.0152 Thallium-208 0.183

+/-0.0403 0.0576 0.0218 0.125 0.0313 0.0205 0.0169 0.0162 0.0394 0.0505 0.0371 0.0308 0.0277 0.0166 0.0158 0.134 0.0313 0.0142 0.0157

+/-0.156

+/-0.0236

+/-0.265

+/-0.0807

+/-0.0441

+/-0.0333

+/-0.0198

+/-0.0449

+/-0.0569

+/-0.0412

+/-0.0541

+/-0.0827

+/-0.0195

+/-0.0184

+/-0.609

+/-0.0807

+/-0.0152

+/-0.0403 0.122 0.0449 0.263 0.0656 0.043 0.0355 0.035 0.082 0.108 0.0763 0.063 0.0577 0.0351 0.0331 0.295 0.0656 0.0297 0.033 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 0558 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 37

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-00IF Project:

YANKO 1204 Sample ID:

174346001 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

38

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis j ------

Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-002F 174346002 Soil 13-OCT-06 18-OCT-06 Client 11.3%

Proiect:

Client ID:

Vol..Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gatnma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.705

+1-0.115 Americium-241 U -0.00449

+/-0.0191 Bismuth-212 0.415

+/-0.202 Bismuth-214 0.516

+/-0.0683 Cesium-134 UI 0.00

+/-0.0252 Cesium-137 0.0285

+/-0.0248 Cobalt-60 U

0.00116

+/-0.0165 Europium-152 U

-0.0116

+/-0.0374 Europium-154 U

0.0159

+/-0.0528 Europium-155 U

0.0474

+/-0.0465 Lead-212 0.602

+/-0.0423 Lead-214 0.514

+/-0.0599 Manganese-54 U

-0.0113

+/-0.0161 Niobium-94 U -0.00754

+/-0.0148 Potassium-40 10.1

+/-0.710 Radium-226 0.516

+/-0.0683 Silver-108m U

-0.0114

+/-0.0123 Thallium-208 0.228

+/-0.0372 0.0446 0.0171 0.0987 0.0233 0.0186 0.013 0.014 0.0316 0.046 0.0285 0.0183 0.0222 0.0128 0.0122 0.111 0.0233 0.0105 0.0121

+/-0.115

+/-0.0191

+/-0.202

+/-0.0683

+/-0.0252

+/-0.0248

+/-0.0165

+/-0.0374

+/-0.0528

+/-0.0465

+/-0.0423

+/-0.0599

+/-0.0161

+/-0.0148

+/-0.710

+/-0.0683

+/-0.0123

+/-0.0372 0.0958 0.0351 0.210 0.0493 0.0392 0.0277 0.0306 0.0662 0.099 0.0588 0.038 0.0465 0.0273 0.0259 0.248 0.0493 0.0221 0.0256 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJ1H1 10/25/06 0558 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description EML HASL 300,4.5.2.3 Notes:

The Qualifiers in this report are defined as follows A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 39

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Cornnecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-002F Project:

YANK01204 Sample ID:

174346002 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

40

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-003F 174346003 Soil 13-OCT-06 18-OCT-06 Client 9.6%

Proiect:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 0.620 U

0.0292 0.431 0.555 UI 0.00 0.0394 U

0.00486 U

-0.0173 U

0.0481 U

0.0561 0.686 0.586 U

0.010 U

0.0064 11.5 0.555 U 0.000306 0.235

+/-0.118

+/-0.0425

+/-0.219

+/-0.075

+/-0.0317

+/-0.0234

+/-0.0149

+/-0.0331

+/-0.0474

+/-0.0466

+/-0.0666

+/-0.0796

+/-0.0147

+/1-0.0126

+/-0.967

+/-0.075

• +/-0.011

+/-0.0374 0.0419 0.0395 0.0753 0.0217 0.0166 0.0117 0.0133 0.0279 0.0375 0.0327 0.0192 0.0202 0.0132 0.0114 0.0792 0.0217 0.0094 0.0116

+/-0.11I

+/-0.0425

+/-0.219

+/-0.075

+/-0.0317

+/-0.0234

+/-0.0149

+/-0.0331

+/-0.0474

+/-0.0466

+/-0.0666

+/-0.0796

+/-0.0147

+/-0.0126

+/-0.967

+/-0.075

+/-0.011

+/-0.0374 0.0897 0.0813 0.162 0.0459 0.0349 0.0248 0.0288 0.0587 0.0811 0.0675 0.0396 0.0424 0.028 0.0242 0.181 0.0459 0.0199 0.0245 pCi/g pci/cg pCi/g pCilg pci/g pCilg pCi/g pCi/g pCi/g pci/g pci/g pCilg pci/g pCilg pCi/g pci/g pCilg pCi/g MJHI 10/25/06 0559 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description 1

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 41

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-003F Protect:

YANK01204 Sample ID:

174346003 ClientID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GCiMS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply-Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL

• h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

42

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address :

362 lnjun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client SamnpleID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-004F 174346004 Soil 13-OCT-06 18-OCT-06 Client 10.8%

Project:

YANKO1204 Client ID:

YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Ganuna,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.788

+/-0.149 Americium-241 U -0.00523

+/-0.0272 Bismuth-212 0:768

+/-0.257 Bismuth-214 0.618

+/-0.104 Cesium-134 U

0.0503

+1-0.0402 Cesium-137 0.0592

+/-0.0259 Cobalt-60 U

0.00448

+/-0.0223 Europium-152 U

0.0389

+/-0.0493 Europiurn-154 U

0.00465

+/-0.0747 Europiurn-155 U

-0.0157

+/-0.0502 Lead-212 0.715

+/-0.053 Lead-214 0.634

+/-0.0789 Manganese-54 U

0.00405

+/-0.021 Niobium-94 U

-0.0127

+/-0.0199 Potassium-40 12.0

+/-0.844 Radium-226 0.618

+/-0.104 Silver-108m U -0.00335

+/-0.0201 Thallium-208 0.187

+/-0.0449 0.0662 0.0257 0.135 0.0335 0.0243 0.0175 0.0194 0.0464 0.064 0.0407 0.0232 0.0302 0.0179 0.0161 0.137 0.0335 0.0155 0.0199

+/-0.149

+/-0.0272

+/-0.257

+/-0.104

+/-0.0402

+/-0.0259

+/-0.0223

+/-0.0493

+/-0.0747

+/-0.0502

+/-0.053

+/-0.0789

+/-0.021

+/-0.0199

+/-0.844

+/-0.104

+/-0.0201

+/-0.0449 0.142 0.0527 0.288 0.0709 0.0512 0.0373 0.0423 0.0969 0.138 0.0839 0.0483 0.0633 0.0383 0.0343 0.310 0.0709 0.0327 0.0418 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 0559 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 43

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date:

October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-004F Project:

YANK01204 Sample ID:

174346004 Client ID:

yANKO01 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank HD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample I-I Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

44

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

Parameter Qualifier Result U.

Rad Gamma Spec Analysis Gafnma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.768 Americium-241 U

0.0871 Bismuth-212 0.296 Bismuth-214 0.563 Cesium-134 U

0.0308 Cesium-137 U

0.0276 Cobalt-60 U -0.0166 Europium-152 U

0.0267 Europium-154 U -0.0305 Europium-155 U

0.0289 Lead-212 0.656 Lead-214 0.574 Manganese-54 U 0.00962 Niobium-94 U

0.0124 Potassium-40 11.8 Radium-226 0.563 Silver-108m U 0.00248 Thallium-208 0.253 9520-0004-004FS 174346005 Soil 13-OCT-06 18-OCT-06 Client 10.4%

Proiect:

YANK01204 Client ID:

YANK001 Vol. Recv.:

ncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd

+/-0.154

+/-0.0747

+/-0.241

+/-0.0819

+/-0.0227

+/-0,0305

+/-0.0205

+/-0.0737

+/-0.0534

+/-0.0567

+/-0.0732

+/-0.0867

+/-0.0179

+/-0.0154

+1-0.986

+/-0.0819

+/-0.0173

+/-0.0365 0.0486 0.0616 0.103 0.0277 0.0178 0.0154 0.0145 0.0404 0.0431 0.0429 0.0228 0.028 0.0163 0.0138 0.124 0.0277 0.0134 0.0129

+/-0.154

+/-0.0747

+/-0.241

+/-0.0819

+/-0.0227

+/-0.0305

+/-0.0205

+/-0.0737

+/-0.0534

+/-0.0567

+/-0.0732

+/-0.0867

+/-0.0179

+/-0.0154

+/-0.986

+/-0.0819

+/-0.0173

+/-0.0365 0.0971 0.123 0.206 0.0553 0.0356 0.0308 0.029 0.0808 0.0861 0.0857 0.0456 0.0559 0.0326 0.0276 0.247 0.0553 0.0268 0.0258 pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCilg pCi/g pcilg pCilg pCi/g pCi/g pCi/g pCi/g MJHI 10/25/060615 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description 1

EML HASL 300, 4.5.2.3.

Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 45

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-004FS Proiect:

YANK01204 Sample ID:

174346005 Client ID:

YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamnna Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

46

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-005F 174346006 Soil 13-OCT-06 18-OCT-06 Client 5.69%

Proiect:

Client ID:

Vol. Recv.:

YANK01204 YANKOO I Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.583

+/-0.159 Americium-241 U

0.0239

+/-0.0257 Bismuth-212 0.516

+/-0.216 Bismuth-214 0.346

+/-0.0895 Cesium-134 U

0.0141

+/-0.021 Cesium-137 0.0315

+/-0.0271 Cobalt-60 U -0.00296

+1-0.0225 Europium-152 U

-0.0245

+/-0.0611 Europium-154 U -0.00234

+/-0.0554 Europium-155 U -0.00765

+/-0.0393 Lead-212 0.415

+/-0.0569 Lead-214 0.394

+/-0.0777 Manganese-54 U -0.00317

+/-0.0198 Niobium-94 U -0.00408

+/-0.0183 Potassium-40 5.67

+/-0.740 Radium-226 0.346

+/-0.0895 Silver-108m U

-0.0201

+1-0.0177 Thallium-208 0.134

+/-0.0452 0.0558 0.0216 0.135 0.0284 0.0194 0.014 0.0185 0.0392 0.0463 0.0349 0.0226 0.0289 0.017 0.0159 0.186 0.0284 0.0143 0.017

+/-0.159

+/-0.0257

+/-0.216

+/-0.0895

+/-0.021

+/-0.0271

+/-0.0225

+/-0.0611

+/-0.0554

+/-0.0393

+/-0.0569

+/-0.0777

+/-0.0198

+/-0.0183

+/-0.740

+/-0.0895

+/-0,0177

+/-0.0452 0.112 0.0431 0.269 0.0568 0.0389 0.0279 0.037 0.0784 0.0925 0.0698 0.0451 0.0577 0.034 0.0317 0.371 0.0568 0.0285 0.0341 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCilg pCilg pCi/g MJH1 10/25/06 0617 581675 1

The following Prep Methods Were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description 1

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 47

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date:

October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-005F Project:

YANK01204 Sample ID:

174346006 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds 'spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

48

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-006F 174346007 Soil 13-OCT-06 18-OCT-06 Client 6.74%

Project:

YANK01204 Client ID:

YANK001

'Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth

'Waived Actinium-228 0.201

+/-0.111 Americium-241 U

0.0098

+/-0.018 Bismuth-212 0.400

+/-0.208 Bismuth-214 0.172

+/-0.0787 Cesium-134 U

0.0225

+/-0.0168 Cesium-137 U -0.00959

+/-0.0156 Cobalt-60 U

0.0128

+I-0.0173 Europium-152 U

-0.0385

+/-0.0352 Europium-154 U 0.000208

+/-0.040 Europium-155 U

0.0122

+/-0.0329 Lead-212 0.290

+/-0.045 Lead-214 0.295

+/-0.0602 Manganese-54 U

-0.009

+/-0.0145 Niobium-94 U -0.00189

+/-0.0142 Potassium-40 5.07

+/-0.565 Radium-226 0.172

+/-0.0787 Silver-108m U

0.00924

+/-0.0133 Thallium-208 0.0915

+/-0.0285 0.0431 0.0172 0.104 0.0267 0.016 0.0126 0.016 0.0295 0.0342 0.0305 0.0214 0.0236 0.0113 0.012 0.117 0.0267 0.0123 0.0142

+/-0.111

+/-0.018

+/-0.208

+/-0.0787

+/-0.0168

+1-0.0156

+/-0.0173

+/-0.0352

+/-0.040

+/-0.0329

+/-0.045

+/-0.0602

+/-0.0145

+/-0.0142

+/-0.565

+/-0.0787

+/-0.0133

+/-0.0285 0.0945 0.0356 0.225 0.0568 0.0345 0.0273 0.0352 0.0627 0.077 0.0632 0.0444 0.0499 0.0248 0.0257 0.265 0.0568 0.0261 0.0303 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCilg pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1008 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 49

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-006F Proiect:

YANK01204 Sample ID:

174346007 Client ID:

YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Ganuna Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

50

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-007F 174346008 Soil 13-OCT-06 18-OCT-06 Client 6.68%

Proiect:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gainma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.594

+/-0.155 Americium-241 U

-0.0438

+/-0.0864 Bismuth-212 0.308

+/-0.213 Bismuth-214 0.482

+/-0.0862 Cesium-134 UI 0.00

+/-0.0298 Cesium-137 U

0.0322

+/-0.0276 Cobalt-60 0.0742

+/-0.0396 Europium-152 U

-0.0126

+/-0.0541 Europium-154 U

0.0227

+1-0.0514 Europium-155 U

0.0643

+/-0.0718 Lead-212 0.534

+/-0.0555 Lead-214 0.515

+/-0.0809 Manganese-54 U

0.00797

+/-0.0188 Niobium-94 U

0.00862

+/-0.0173 Potassium-40 8.81

+/-0.744 Radium-226 0.482

+/-0.0862 Silver-108m U

0.0158

+/-0.0164 Thallium-208 0.194

+/-0.0365 0.052 0.0676 0.104 0.0298 0.0158

• 0.0159 0.0139 0.0457 0.0465 0.0408 0.0265 0.0308 0.0165 0.0155 0.158 0.0298 0.0147 0.0149

+/-0.155

+/-0.0864

+/-0.213

+/-0.0862

+1-0.0298

+/-0.0276

+/-0.0396

+/-0.0541

+/-0.0514

+/-0.0718

+/-0.0555

+/-0.0809

+/-0.0188

+/-0.0173

+/-0.744

+/-0.0862

+/-0.0164

+/-0.0365 0.113 0.140 0.226 0.0632 0.0341 0.0339 0.0311 0.0955 0.102 0.0845 0.0548 0.0646 0.0353 0.0329 0.350 0.0632 0.031 0.0317 pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1009 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods Were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 51

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October,26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-007F Project:

YANKO 1204 Sample ID:

174346008 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UT Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL It Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

52

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd

Contact:

Project:

East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-008F 174346009 Soil 13-OCT-06 18-OCT-06 Client 9.52%

Proiect:

YANKO 1204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad.Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 0.682 U

0.0423 0.247 0.536 Ul 0.00 0.052 U 0.000583 U

-0.0226 U

0.00152 U

0.0216 0.661 0.647 U

0.00618 U

0.00581 10.2 0.536 U

0.00526 0.240

+/-0.113

+/-0.0766

+/-0.169

+/-0.0639

+/-0.0246

+/-0.0256

+/-0.0157

+/-0.0399

+/-0.0502

+/-0.0431

+/-0.046

+/-0.0698

+/-0.0161

+/-0.0143

+/-0.674

+/-0.0639

+/-0.0129

+/-0.0343 0.0383 0.064 0.112 0.0236 0.0153 0.0141 0.0134 0.0331 0.0375 0.0414 0.0186 0.0252 0.0141 0.0128 0.104 0.0236 0.0119 0.0132

+/-0.113

+/-0.0766

+/-0.169

+/-0.0639

+/-0.0246

+/-0.0256

+/-0.0157

+/-0.0399

+/-0.0502

+/-0.0431

+/-0.046

+/-0.0698

+/-0.0161

+/-0.0143

+/-0.674

+/-0.0639

+/-0.0129

+/-0.0343 0.0834 0.132 0.237 0.0502 0.0327 0.0299 0.0295 0.0693 0.0822 0.0853 0.0387 0.0527 0.030 0.027 0.234 0.0502 0.0251 0.028 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1010 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 53

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-008F Project:

YANK01204 Sample ID:

174346009 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

54

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

Parameter Qualifier Result U]

• Rad Gamma Spec Analysis Gamna.Sohid-FSS CAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.719 Americium-241 U

0.0133 Bismuth-212 0.376 Bismuth-214 0.458 Cesium-134 U

0.0229 Cesium-137 0.0411 Cobalt-60 U 0.00299 Europium-152 U -0.0231 Europium-154 U -0.0303 Europium-155 U

0.0252 Lead-212 0.619 Lead-214 0.509 Manganese-54 U

0.00382 Niobium-94 U

0.0054 Potassium-40 10.4 Radium-226 0.458 Silver-108m U-0.000387 Thallium-208 0.205 9520-0004-009F 174346010 Soil 13-OCT-06 18-OCT-06 Client 11.9%

Project:

YANK01204 Client ID:

YANK001 Vol. Recv.:

ncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd

+/-0.130

+/-0.0632

+/-0.187

+/-0.0625

+/-0.0199

+/-0.0229

+/-0.0133

+/-0.038

+/-0.0517

+1-0.0567

+/-0.0481

+/-0.0661

+/-0.0145

+/-0.0149

+/-0.664

+/-0.0625

+/-0.0132

+/-0.0331 0.0454 0.061 0.0979 0.0257 0.0164 0.0117 0.0116 0.0335 0.0414 0.0397 0.0202 0.0261 0.0131 0.013 0.128 0.0257 0.0117 0.0148

+/-0.130

+/-0.0632

+/-0.187

+/-0.0625

+/-0.0199

+/-0.0229

+/-0.0133

+/-0.038

+/-0.0517

+/-0.0567

+/-0.0481

+/-0.0661

+/-0.0145

+/-0.0149

+/-0.664

+/-0.0625

+/-0.0132

+/-0.0331 0.0972 0.126 0.208 0.054 0.0346 0.0249 0.0255 0.070 0.0894 0.0817 0.0418 0.0544 0.0279 0.0274 0.281 0.054 0.0246 0.031 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1011 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EIEML HASL 300,4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 55

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd EastHampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-009F Proiect:

YANK01204 Sample ID:

174346010 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

56

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -. (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd

Contact:

Project:

East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date:

October 26, 2006 Client Sample ID:

9520-0004-OIOF Proiect:

YANK01204 Sample ID:

174346011 Client ID:

YANyK001 Matrix:

Soil Vol. Recv.:

Collect Date:

13-OCT-06 Receive Date:

18-OCT-06 Colector:

Client Moisture:

-10.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.655

+/-0.134 Americium-241 U

-0.0109

+/-0.115 Bismuth-212 0.487

+/-0.196 Bismuth-214 0.609

+/-0.0907 Cesium-134 UI 0.00

+/-0.0259 Cesiurn-137 0.0346

+/-0.0285 Cobalt-60 U

-0.0151

+/-0.0179 Europium-152 U

-0.0136

+/-0.0429 Europium-154 U

-0.0331

+/-0.0518 Europium-155 U

0.0469

+/-0.0531 Lead-212 0.685

+/-0.0727 Lead-214 0.624

+/-0.0913 Manganese-54 U

0.0222

+/-0.0232 Niobium-94 U

0.0081

+/-0.0151 Potassium-40 11.2

+/-1.03 Radiumn-226 0.609

+/-0.0907 Silver-108m U. 0.00352

+/-0.0145 Thallium-208 0.236

+/-0.0392 0.0451 0.0936 0.112 0.0262 0.0175 0.0148 0.0142 0.0372 0.0423 0.0486 0.0223 0.0264 0.0144 0.0137 0.119 0.0262 0.0127 0.0139

+/-0.134

+/-0.115

+/-0.196

+/-0.0907

+/-0.0259

+/-0.0285

+/-0.0179

+/-0.0429

+/-0.0518

+/-0.0531

+/-0.0727

+/-0.0913

+/-0.0232

+/-0.0151

+/-1.03

+/-0.0907

+/-0.0145

+/-0.0392 0.0968 0.192 0.236 0.0552 0.037 0.0313 0.0309 0.0776 0.0915 0.0995 0.0461 0.0551 0.0306 0.0289 0.264 0.0552 0.0266 0.0294 pCi/g pCilg pCilg pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 10/25/06 1012 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 57

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut.06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-O1OF Proiect:

YANK01204 Sample ID:

174346011 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confimied by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Sununary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

58

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Mni~tinre' 9520-0004-012F 174346012 Soil 13-OCT-06 18-OCT-06 Client 1') At7,,

Project:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Garnma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.744

+/-0.130 Americium-241 U

-0.0169

+/-0.0928 Bismuth-212 0.601

+/-0.245 Bismuth-214 0.509

+/-0.0855 Cesium-134 U

0.0405

+/-0.0248 Cesium-137 0.120

+/-0.0368 Cobalt-60 U

0.00371

+/-0.0185 Europium-152 U -0.00568

+/-0.0505 Europium-154 U -0.00834

+/-0.0586 Europium-155 U

0.0318

+/-0.0533 Lead-212 0.820

+/-0.0556 Lead-214 0.560

+/-0.0789 Manganese-54 U

0.00744

+/-0.0165 Niobium-94 U-0.000455

+/-0.0164 Potassium-40 11.7

+/-0.752 Radium-226 0.509

+/-0.0855 Silver-108m U -0.00461

+/-0.0176 Thallium-208 0.261

+/-0.0365 0.0557 0.0759 0.115 0.0298 0.0205 0.0168 0.0156 0.0431 0.0479 0.0494 0.026 0.0306 0.0151 0.0142 0.127 0.0298 0.0146 0.0164

+/-0.130'

+/-0.0928

+/-0.245

+/-0.0855

+/-0.0248

+/-0.0368

+/-0.0185

+/-0.0505

+/-0.0586

+/-0.0533

+/-0.0556

+/-0.0789

+/-0.0165

+/-0.0164

+/-0.752

+/-0.0855

+/-0.0176

+/-0.0365 0.119 0.155 0.245 0.0626 0.043 0.0355 0.0341 0.0896 0.104 0.102 0.0535 0.0638 0.0321 0.030 0.283 0.0626 0.0306 0.0345 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1013 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as f6llows" A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 59

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

.:Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-012F Proiect:

YANK01204 Sample ID:

174346012 ClientID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mid Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

60

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company :

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date:

October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-0 I2FS 174346013 Soil 13-OCT-06 18-OCT-06 Client 14.3%

Project:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gammnoa,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.813

+/-0.208 Americium-241 U

0.0152

+1-0.0441 Bismuth-212 UI 0.00

+/-0.409 Bismuth-214 0.589

+/-0.114 Cesium-134 U

0.0308

+/-0.0368 Cesium-137 0.155

+/-0.0471 Cobalt-60 U

0.00188

+/-0.0314 Europium-152 U

0.0408

+/-0.0718 Europium-154 U

0.0205

+/-0.0863

• Europium-155 U

0.0557

+/-0.0623 Lead-212 0.670

+/-0.0889 Lead-214 0.609

+/-0.107 Manganese-54 U

0.0278

+/-0.0302 Niobium-94 U

-0.0271

+/-0.0286 Potassium-40 12.6

+/-0.969 Radium-226 0.589

+1-0.114 Silver-108m U -0.00641

+/-0.0239 Thallium-208 0.285

+/-0.0664 0.0841 0.0316 0.188 0.0456 0.0319 0.028 0.0261 0.0608 0.0733 0.0523 0.0425 0.0439 0.0264 0.0223 0.234 0.0456 0.0204 0.0231

+/-0.208

+/-0.0441

+/-0.409

+1-0.114

+/-0.0368

+/-0.0471

+/-0.0314

+/-0.0718

+/-0.0863

+/-0.0623

+/-0.0889

+/-0.107

+/-0.0302

+/-0.0286

+/-0.969

+/-0.114

+/-0.0239

+/-0.0664 0.179 0.0648 0.396 0.0957 0.0669 0.0585 0.0562 0.127 0.158 0.108 0.0871 0.0913 0.0555 0.047 0.509 0.0957 0.0427 0.0486 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g.

pCi/g pCi/g pCi/g pCi/g pCilg pCi/g pCi/g MJHl 10/25/06 1014 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description 1

.EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 61

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-012FS Project:

YANK01204 Sample ID:

174346013 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

62

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-013F 174346014 Soil 13-OCT-06 18-OCT-06 Client 12.4%

Project:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamnnia,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.794

+/-0.135 Americium-241 U

0.00918

+1-0.0219 Bismuth-212 0.739

+/-0.260 Bismuth-214 0.671

+/-0.070 Cesium-134 UI 0.00

+/-0.0267 Cesium-137 0.0737

+/-0.0222 Cobalt-60 U

0.00633

+/-0.0186 Europium-152 U

0.00313

+/-0.0424 Europium-154 U -0.00984

+1-0.0545 Europium-155 U

0.0304

+/-0.0325 Lead-212 0.798

+/-0.046 Lead-214 0.734

+/-0.0676 Manganese-54 U

0.00425

+/-0.0163 Niobium-94 U -0.00114

+/-0.015 Potassium-40 12.4

+/-0.735 Radium-226 0.671

+/-0.070 Silver-108m U

0.0115

+/-0.0131 Thallium-208 0.265

+/-0.0356 0.0528 0.0199 0.103 0.0241 0.0196 0.014 0.0162 0.0365 0.0453 0.0318 0.018 0.0241 0.014 0.0128 0.119 0.0241 0.0116 0.0129

+/-0.135

+/-0.0219

+/-0.260

+/-0.070,

+/-0.0267

+/-0.0222

+/-0.0186

+/-0.0424

+/-0.0545

+/-0.0325

+/-0.046

+/-0.0676

+/-0.0163

+/-0.015

+/-0.735

+/-0.070

+/-0.0131

+/-0.0356 0.112 0.0407 0.218 0.051 0.0411 0.0296 0.035 0.0759 0.0976 0.0653 0.0373 0.0504 0.0298 0.0271 0.265 0.051 0.0244 0.0273 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1015 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 63

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-013F Project:

YANK01204 Sample ID:

174346014 Client lID:

YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

64

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

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Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date:

October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-015F 174346015 Soil 13-OCT-06 18-OCT-06 Client 11%

Project:

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Vol. Recv.:

YANK01204 YANKOOI Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.622

+/-0.132 Americium-241 U

-0.0107

+/-0.046 Bismuth-212 0.410

+/-0.233 Bismuth-214 0.620

+/-0.0854 Cesium-134 UI 0.00

+/-0.0291 Cesium-137 0.0571

+/-0.0242 Cobalt-60 U

0.00144

+/-0.0144 Europium-152 U -0.00125

+/-0.0358 Europium-154 U

0.0208

+/-0.044 Europium-155 U

0.0414

+/-0.039 Lead-212 0.791

+/-0.0746 Lead-214 0.618

+/-0.0803 Manganese-54 U

-0.01

+/-0.0152 Niobium-94 U

0.00883

+/-0.0161 Potassium-40 11.3

+/-0.949 Radium-226 0.620

+/-0.0854 Silver-108m U

0.00184

+/-0.0127 Thallium-208 0.221

+/-0.0376 0.043 0.0409 0.0902 0.0219 0.018 0.0118 0.0125 0.0311 0.0397 0.0351 0.0177 0.0218 0.0124 0.0117 0.113 0.0219 0.0109 0.0119

+/-0.132

+/-0.046

+/-0.233

+/-0.0854

+/-0.0291

+/-0.0242

+/-0.0144

+/-0.0358

+1-0.044

+/-0.039

+/-0.0746

+/-0.0803

+/-0.0152

+/-0.0161

+/-0.949

+/-0.0854

+/-0.0127

+/-0.0376 0.092 0.0841 0.192 0.0463 0.0378 0.025 0.0273 0.0651 0.0856 0.0723 0.0367 0.0457 0.0263 0.0247 0.248 0.0463 0.023 0.0252 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 10/25/06 1016 581675 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 65

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: October 26, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-015F Project:

YANK01204 Sample ID:

174346015 Client ID:

YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sanrple is reported on a dry weight basis.

66

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-0111F 174346016 Soil 13-OCT-06 18-OCT-06 Client 12.7%

Project:

Client ID:

Vol. Recv.:

YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.00633

+/-0.0183 Curium-242 Curium-243/244 Alphaspec Pu. Solid-ALL FSS Plutonium-238 U

0.00

' +/-0.063 U

-0.0148

+/-0.0637 U

-0.0277

+/-0.0713 0.0276 +/-0.0183 0.00

+/-0.063 0.039 +/-0.0637 0.0763 +/-0.0713 0.081

+/-0.043 0.139 0.0871 0.161 0.234 0.243 11.5 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MXA 10/23/06 1039 580396 1

Plutonium-239/240 U

-0.065 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U

-4.84

+/-0.0424 MXA 10/20/06 0813 580398 3

10/21/06 1753 580400 4

+/-6.28 5.48

+/-6.28 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.656

+/-0.161 Americium-241 U

0.00419

+/-0.0293 Bismuth-212 0.534

+/-0.200 Bismuth-214 0.611

+/-0.0923 Cesium-134 U

0.0223

+/-0.033 Cesium-137 0.0569

+/-0.0404 Cobalt-60 U

0.00854

+/-0.021 Europium-152 U

0.00571

+1-0.0432 Europium-154 U

-0.0175

+/-0.0617 Europium-155 UI 0.00

+/-0.0582 Lead-212 0.723

+/-0.0499 Lead-214 0.566

+/-0.0755 Manganese-54 U

0.0103

+/-0.0203 Niobium-94 U

0.00709

+/-0.0197 Potassium-40 11.1

+/-0.828 Radium-226 0.611

+/-0.0923 Silver-108m U

0.00105

+/-0.016 Thallium-208 0.208

+1-0.0441 Rad Gas Flow Proportional Counting 0.0626 0.0256 0.135 0.0305 0.022 0.0184 0.0187 0.0399 0.0512 0.0377 0.0213 0.0309 0.0179 0.0174 0.135 0.0305 0.0145 0.0179

+/-0.161

+/-0.0293

+/-0.200

+/-0.0923

+/-0.033

+/-0.0404

+/-0.021

+/-0.0432

+/-0.0617

+/-0.0582

+/-0.0499

+/-0.0755

+/-0.0203

+/-0.0197

+/-0.828

+!-0.0923

+/-0.016

+/-0.0441 0.134 0.0526 0.286 0.0645 0.0465 0.0388 0.0406 0.0835 0.111 0.0776 0.0442 0.0644 0.0381 0.0366 0.303 0.0645 0.0304 0.0377 0.0366 pCi/g pCilg pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJiHI 10/25/06 1017 581675 5

GFPC, Sr90, solid-ALL FSS Strontium-90 Rad Liquid Scintillation Analysis U

0.00719

+/-0.020 0.0158

+/-0.020 KSDI 10/20/06 1940 580488 6

67

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address :

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Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006.

Client Sample ID:

Sample ID:

9520-0004-01 IF 174346016 Proiect:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier R

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U

Liquid Scint C14, Solid AII,FSS Carbon-14 U

-0 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U

Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U

Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U

esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 9.05

+/-6.30 4.74

+/-6.30

.0717

+/-0.110 0.0937

+/-0.110

-8.85

+/-31.2 23.2

+/-31.2

-4.14

+/-13.7 l1.7

+/-13.7 10.2 pCi/g 0.191 pCi/g 48.8 pCi/g 24.5 pCi/g DFAI 10/24/06 r251 580729 7

AXD2 10/20/06 0318 580730 9

MXP1 10/23/06 0139 580395 10 MXPI 10/22/06 2125 580397 11 KXRl 10/24/06 1107 580727 12 0.146

+/-0.233 0.201

+/-0.233 0.418 pCi/g The following Prep Methods'were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description I

DOE EML HASL-300, Am-05-RC Modified 2

DOE EML HASL-300, Am-05-RC Modified 3

DOE EML HASL-300, Pu-II-RC Modified 4

DOE EML HASL-300, Pu-I 1-RC Modified 5

EML HASL 300, 4.5.2.3 6

EPA 905.0 Modified 7

EPA 906.0 Modified 8

EPA 906.0 Modified 9

EPA EERF C-01 Modified 10 DOE RESL Fe-1, Modified II DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery %

Acceptable Limits Americium-243 Plutonium-242 Plutonium-241 Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS 93 102 98 (15%-125%)

(1517-125%)

(25%-125%)

68

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

9520-0004-01IF 174346016 Proiect:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Strontium-90 Carrier/Tracer Recovery Iron-55 Nickel-63 Carrier/Tracer Recovery Technetium-99 Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 85 85 61 61 61 79 79 (25%-125%)

(25%-125%)

(15%-125%)

(25%-125%)

(25%-125%)

(15%-125%)

(15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RE. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

69

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certifirate nf Annlv.i.r.

Company : Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006:

Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-014F 174346017 Soil 13-OCT-06 18-OCT-06 Client 9.82%

Project:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U

0.123

+/-0.161 0.0922

+/-0.162 Curium-242 Curium-243/244 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U

0.00979

+/-0.0929 0.0726 +/-0.0929 U

-0.0463

+/-0.118 0.116

+/-0.118 U

0.0173

+/-0.107 0.082

+/-0.107 0.265 0.228 0.312 0.242 0.225 pCi/g pci/g pCi/g pCilg pCi/g MXA 10/20/06 0813 580396 1

1 MXA 10/20/06 0813 580398 2

1 MXA 10/21/06 1809 580400 3

Plutonium-239/240 U

0.00231 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U

-5.17

+/-0.0889 0.0734 +/-0.0889

+/-6.25 5.47

+/-6.25 11.5 pCi/g Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.783 Americium-241 U

0.0117 Bismuth-212 0.426 Bismuth-214 0.558 Cesium-134 U

0.0239 Cesium-137 0.0471 Cobalt-60 U-0.000675 Europium-152 U

0.00107 Europium-154 U -0.00476 Europium-155 U-0.000381 Lead-212 0.752 Lead-214 0.631 Manganese-54 U

0.0126 Niobium-94 U -0.00147 Potassium-40 11.0 Radium-226 0.558 Silver-108m U -0.00898 Thallium-208 0.226 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U

0.0072 Rad Liquid Scintillation Analysis

+/-0.107

+/-0.0475

+/-0.171

+/-0.0582

+/-0.0146

+/-0.0196

+/-0.0125

+/-0.0311

+/-0.0315

+/-0.040

+/-0.0417

+/-0.0656

+/-0.0154

+/-0.0107

+/-0.543

+/-0.0582

+/-0.0103

+/-0.0287

+/-0.0161 0.0339 0.0455 0.0788 0.0184 0.0122 0.0104 0.0104 0.028 0.026 0.0367 0.0166 0.020 0.0101 0.00942 0.0833 0.0184 0.00867 0.00984

+/-0.107

+/-0.0475

+/-0.171

+/-0.0582

+/-0.0146

+/-0.0196

+/-0.0125

+/-0.0311

+/-0.0315

+/-0.040

+/-0.0417

+/-0.0656

+/-0.0154

+/-0.0107

+/-0.543

+/-0.0582

+/-0.0103

+/-0.0287 0.0717 0.0931 0.165 0.0384 0.0255 0.0218 0.0222 0.0581 0.056 0.0752 0.0341 0.0415 0.0213 0.0197 0.181 0.0384 0.0181 0.0206 0.0295 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/25/06 1017 581675 4

KSD1 10/21/06 0850 580488 5

0.0123 +/-0.0161 70

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company :

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

9520-0004-014F 174346017 Proiect:

Client ID:

Vol. Recv.:

YANKO01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Liquid Scintillation Analysis LSC. Tritiun Dist, Solid-HTD2,ALL FSS Tritium U

9.45

+/-8.24 6.34

+/-8.24 13.6 pCi/g Liquid Scint C14, Solid AllFSS Carbon-14 1

Liquid Scint Fe55, Solid-ALL FSS ITon-55 1I

-0.167

+/-0.111 0.0957

+/-0.111 0.195 pCi/g 20.9

+/-33.6 24.1

+/-33.7 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U

-9.29 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U

-0.0833 50.6 pCi/g 16.3 pCi/g DFAl 10/24/06 1308 580729 6

AXD2 10/20/06 0558 580730 8

MXP1 10/23/060155 580395 9

MXP1 10/22/06 2141 580397 10 KXR1 10/24/06 1123 580727 11

+/-8.76 7.77

+/-8.76

+/-0.253 0.215

+/-0.253 0.447 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 10/18/06 1634 580480 The following Analytical Methods were performed Method Description 1

DOE EML HASL-300, Am-05-RC Modified 2

DOE EML HASL-300, Pu-Il -RC Modified 3

DOE EML HASL-300, Pu-Il I-RC Modified 4

EML HASL 300,4.5.2.3 5

EPA 905.0 Modified 6

EPA 906.0 Modified 7

EPA 906.0 Modified 8

EPA EERF C-01 Modified 9

DOE RESL Fe-I, Modified 10 DOE RESL Ni-1, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%

Acceptable Limits Americium-243 Plutonium-242 Plutonium-241 Strontium-90 Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241. Solid-ALL F5 GFPC, Sr90, solid-ALL FSS 91 105 99 88 (15%-125%)

(15%-125%)

71

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com rprtifIt'sttpnf Ainqlvri Company : Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: October 26, 2006 Client Sample ID:

Sample ID:

9520-0004-014F 174346017 Proiect:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery Iron-55 Nickel-63 Carrier/Tracer Recovery Technetium-99 Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 88 57 92 92 75 75 (25%-125%)

(15%-125%)

(25%-125%)

(25%-125%)

(15%-125%)

(15%-125%)

Notes:

The Qualifiers in this report are defined as follows A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported' from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

.RPD of sample and duplicate evaluated using +!-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

72

QUALITY CONTROL DATA I

73

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn QC Summary Client :

Connecticut Yankee Atomic Power 362 Injun Hollow Rd Report Date: October 26, 2006 Page 1 of 9 East Hampton, Connecticut

Contact:

Mr. Jack McCarthy Workorder:

174346 Parmname NOM Sample Qual QC Units RPD%

REC%

Range AnIst Date Time Rad Alpha Spec Batch 580396 QC1201210038 Arnericium-241 174224006 DUP Curium-242 U

-0.00901 Uncert:

+/-0.0461 TPU:

+/-0.0461 U

0.00 Uncert:

+/-0.0812 TPU:

+/-0.0812 U

0.00 Uncert:

+/-0.0764 TPU:

+/-0.0764 Curium-243/244 Arnericium-24]

Curiurn-242 Curium-243/244 2.72 Uncert:

TPU:

Uncert:

TPU:

3.27 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

U

-0.0356

+/-0.035

+/-0.0352 U

-0.0155

+/-0.0215

+/-0.0216 U

-0.0556

+1-0.123

+/-0.123 2.33

+/-0.266

+/-0.392 U

0.00823

+/-0.0232

+/-0.0232 3.55

+/-0.330

+/-0.549 U

2.200E-05

+/-0.0261

+/-0.0261 U

0.00

+/-0.0134

+/-0.0134 U

-0.00919

+/-0.0222

+/-0.0222 pCi/g 119 pCi/g 200 pCi/g 200 (0% - 100%) vIXAI (0%-100%)

(0%- 100%)

QC 1201210037 Americium-241 MB 10/20/06 08:13 Curium-242 Curium-243/244 QC1201210039 174224006 MS Americium-241 Curium-242 Curium-243/244 PCi/g pCi/g PCi/g PCi/g pCilg pCi/g pCi/g pCi/g pCi/g 86 (75%-125%)

10/20/06 08:13 10/20/06 08:13 109 (75%-125%)

Uncert:

TPU:

13.3 U

-0.00901 Unfert:

+/-0.0461 TPU:

+/-0.0461 U

0.00 Uncert:

+/-0.0812 TPU:

+/-0.0812 16.1 U

0.00 Uncert:

+/-0.0764 TPU:

+/-0.0764 U

13.9

+/-1.44

+/-2.27 0.0808

+/-0.112

+/-0.112 18.4

+/-1.66

+/-2.87 105 (75%-125%)

10/20/06 08:13 114 (75%-125%)

Batch 580398 QC1201210046 174224006 DUP Plutonium-238 U

0.00905 U

0.0116 pCi/g 25 (0%- 100%) IXAI 10/20/06 08:13 74

GENERAL ENGINEERING LABORATORIES, LLC

.2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174346 Page 2 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range AnIst Date Time Rad Alpha Spec Batch 580398 Plutonlium-239/246 QC1201210048 LCS Plutonium-238 Plutonium-239/240 QC 1201210045 MB Plutonium-238 Plutonium-239/240 QC1201210047 174224006 MS Plutonium-238 Uncert:

+/-0.086 TPU:

+/-0.086 U

-0.0532 Uncert:

+/-0.0721 TPU:

+/-0.0723 U ncert:

TPU:

2.51 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

u 0.00905 Uncert:

+/-0.086 TPU:

+/-0.086 12.3 U

-0.0532 Uncert:

+/-0.0721 TPU:

+/-0.0723 U

-4.06 Uncert:

+/-7.84 TPU:

+/-7.84 U

+/-0.121 4/-0.121 0.0814

+/-0.112

+/-0.112 pCi/g 955 (0%- 100%)

U

-0.00419

+/-0.0143

+/-0.0143 2.38

+/-0.238

+/-0.332 U

-0.0118

+/-0.018

+/-0.018 U

-0.00516

+/-0.00584

+/-0.00586 pCi/g PCu/g PCi/g pCi/g pCi/g (75%-125%)

10/20/06 08:13 95 (75%-125%)

10/20/06 08:13 U

-0.0482

+/-0.0653

+/-0.0654 15.4

+/-1.23

+/-1.94 (75%-125%)

Plutonium-239/240 125 (75%-125%)

Batch 580400 QC1201210054 174224006 DUP Plutonium-241 QC1201210056 LCS Plutonium-241 QC1201210053 MB Plutonium-241 QC1201210055 174224006 MS Plutonium-24 I Rad Gamma Spec Batch 581675 QC1201213158 174346001 DUP Actinium-228 U

-1.47

+/-6.92

+/-6.92 35.5

+/-3.19

+/-4.69 pCi/g 0

(0%- 100%).IXAI 35.9 Uncert:

TPU:

Uncert:

TPU:

143 U

Uncert:

TPU:

U

-0.233

+/-1.77

+/-1.77 pcilg pCi/g PCilg 99 (75%-125%)

10/21/06 18:42 10/21/06 19:14 10/21/06 18:26 10/21/06 18:58

-4.06

+/-7.84

+/-7.84 124

+/-11.4

+/-16.4 86 (75%-125%)

0.739 Uncert:

+/-0.156 0.528

+/-0.123

+1-0.123 pCi/g 33 (0% - 100%) MJHI 10/25/06 11:04 75

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174346 Page 3 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time Rad Gamma Spec Batch 581675 Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 TPU:

41-0. 156

• U

-0.00139 U

0.0268 Unceift:

+/-0.0236

+/-0.0262 TPU:

+/-0.0236

+/-0.0262 0.368 0.431 Uncert:

+/-0.265

+/-0.250 TPU:

+/-0.265

+/-0.250 0.442 0.468 Uncert:

+/-0.0807

+/-0.0892 TPU:

+/-0.0807

+/-0.0892 UI 0.00 U

0.0283.

Uncert:

+/-0.0441

+/-0.0245 TPU:

+/-0.0441

+/-0.0245 u

0.0319 0.0366 Uncert:

+/-0.0333

+/-0.0293 TPU:

+/-0.0333

+/-0.0293 u

-0.00636 U

0.020 Uncert:

+/-0.0198

+/-0.0248 TPU:

+/-0.0198

+/-0.0248 U

0.00386 U

0.00827 Uncert:

+/-0.0449

+/-0.0545 TPU:

+/-0.0449

+/-0.0545 U

0.0267 U

0.0258 Uncert:

+/-0.0569

+/-0.0664 TPU:

+/-0.0569

+/-0.0664 U

0.0194 U

0.0266 Uncert:

+/-0.0412

+/-0.0399 TPU:

+/-0.0412

+/-0.0399

• 0.412 0.485 Uncert:

+/-0.0541

+/-0.0603 TPU:

+/-0.0541

+/-0.0603 0.499 0.530 Uncert:

+/-0.0827

+/-0.0836 TPU:

+/-0.0827

+/-0.0836 U

0.00185 U

0.0212 Uncert:

+/-0.0195

+/-0.0239 TPU:

+/-0.0195

+/-0.0239 U

-0.00452 U

0.0106 Uncert:

+/-0.0184

+/-0.0182 TPU:

+/-0.0184

+/-0.0182 6.70 7.13 Uncert:

+/-0.609

+/-0.710 TPU:

+/-0.609

+/-0.710 0.442 0.468 Uncert:

+/-0.0807

+/-0.0892 TPU:

+/-0.0807

+/-0.0892 U

0.00712 U

-0.00779 Uncert:

+/-0.0152

+/-0.0154 pCi/g.

222 pCi/g 16 pCi/g 6

pCig 75 pCi/g 14 pCi/g 387 pCi/g 73 pCi/g 3

pCi/g 31 pCi/g 16 pCi/g 6

pCi/g 168 pCi/g 496 pCi/g 6

pCi/g 6

pCi/g 4430 (0% - 100%)

(0% - 100%)

(0% - 100%)

(0%- 100%)

(0%- 100%)

(0%- 100%)

(0% - 100%)

(0% - 100%)

(0%- 100%)

(0%- 100%)

(0%-20%)

(0% - 100%)

(0%- 100%)

(0% - 20%)

(0%- 100%)

(0%- 100%)

Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m 76

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -.www.gel.com QC Summary Workorder:

174346 Page 4 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range AnIst Date Time Rad Gamma Spec Batch 581675 Thallium-208 QC1201213159 Actinium-228 Americium-241 Bismuth-212 Bismuth-214 TPU:

+/-0.0152 0.183 Uncert:

+/-0.0403 TPU:

+/-0.0403 LCS Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Uncert:

TPU:

23.4 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

9.55 Uncert:

TPU:

14.2 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

+/-0.0154

. 0.186

+/-0.0412

+/-0.0412 U

0.743

+/-0.554

+/-0.554 24.4

+/-1.27

+/-1.27 U

-0.111

+/-1.11

+1-1.11 U

0.247

+/-0.204

+/-0.204 U

0.0584

+/-0.143

+/-0.143 9.67

+/-0.437

+/-0.437 14.6

• +/-0.633

+/-0.633 U

0.219

+/-0.293

+/-0.293 U

-0.0828

+/-0.303

+/-0.303 U

0.164

+1-0.307

+/-0.307 U

0.0745

+/-0.163

+/-0.163 U

0.247

+/-0.350

+/-0.350 U

0.00541

+/-0.137

+/-0.137 U

-0.0757

+1-0.181

+/-0.111 U

-0.178 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 10/25/06 07:15 pCi/g 2

104 (75%-125%)

(0%- 100%)

101 (75%-125%)

102 (75%-125%)

Lead-212 Lead-214 Manganese-54 Niobium-94 Potassiwn-40 77

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Wnorkorder, P1d2AA Page 5 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range AnIst Date Time Rad Gamma Spec Batch 581675 Radium-226 Silver-108m Thallium-208 QC1201213157 Actinium-228 A mericium-24 I Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

+/-0.986

+/-0.986 U

0.247

+/-0.204

+/-0.204 U

0.0371

+/-0.113

+/-0.113 U

0.0403

+/-0.114

+/-0.114 U

0.0547

+/-0.0339

+/-0.0339 U

0.035

+/-0.0503

+/-0.0503 U

0.0861

+/-0.0721

+/-0.0721 U

0.0234

+/-0.0389

+/-0.0389 U

0.00174

+/-0.00859

+/-0.00859 U

-0.00489

+/-0.00879

-/-0.00879 U

-0.00292

+/-0.00844

+/-0.00844 U

-0.0124

+/-0.0226

+/-0.0226 U

-0.0125

+/-0.0235

+/-0.0235 U

-0.00752

+/-0.027

+/-0.027 U

0.00708

+/-0.0292

+/-0.0292 U

0.0307

+/-0.032

+/-0.032 pCi/g pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCilg pCi/g pCi/g 10/25/06 10:33 (75%-125%)

Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 78

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Workorder:

174346 Parmname QC Summary Page 6 of 9 NOM Samole Oual OC Units RPD%

REC%

Ranpe Anist Date Time Rad Gamrna Spec Batch 581675 Marngarcsc-54 Nliobi~urn-94 Putassiuin-40 Radiumn-22f:

'h afl"Muni-208 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

U

-0.003

+/-0.00927

+/-0.00927 U

0.0088

+/-0.00881

+/-0.00881 UI 0.00

+/-0.169

+/-0.169 U

0.0234

+/-0.0389

+/-0.0389 U

-0.00204

+/-0.00779

+/-0.00779 U

0.00488

+/-0.0168

+/-0.0168 pCi/g pCilg pCi/g pCi/g pCi/g pcilg Rad Gas Ftoýs Batch 580488 QC1201210299 174224006 DUP Sixondum-90 u

0.0274 Uncert:

+/-0.0243 TPU:

+/-0.0243 U

QC120121CJ301 st~roatiunt-90 LCS 0.019

+/-0.0165

+/-0.0165 1.21

+/-0.0826

+/-0.0897 pCi/g 0

(0% - 100%) KSDI QC:1201m21021 MAB strrjntiinil-.90 QC1201210300 174224006 MVS Strontiun-90 Rad Liquid Scintillation tBatch 580395 QC1201210034 174224006 DUP Iron-55 QC1201210036 L1CS Ironi-55 QMi01210033.MB3 Iron-55 1.48 Uncert:

TPU:

Uncert:

TPU:

U

-0.000851

+/-0.0154

+/-0.0154 pCi/g pCi/g pC'lg 82 (75%-125%)

10/23/06 14:39 10/21/06 08:50 10/21/06 08:50 10/21/06 08:50 3.12 U

Uncert:

TPU:

0.0274

+/-0.0243

+/-0.0243 2.73

+/-0.188

+/-0.204 88 (75%-125%)

U 2.10 Uncert:

+/-28.7 TPU:

+/-28.7 607 Uncert:

TPU:

U 6.20

+/-29.1.

+/-29.1 623

+/-52.8

+/-73.5 pCi/g 0

(0% -100%) AMP pCi/g 103 (75%-125%)

10/23/06 02:29 10/23/06 03:02 10/23/06 02:12 U

2.58 pCi/g 79

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174346 Page 7 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time Rad Liquid Scintillation Batch 580395 Uncert:

TPU:

QC1201210035 174224006 MS Iron-55 666 U

Uncert:

TPU:

2.10

+/-28.7

+/-28.7 Batch 580397 QC1201210042 174224021 DUP Nickel-63 QC1201210044 LCS Nickel-63

+/-32.0

+/-32.0 631

+/-52.7

+/-73.8

-5.26

+/-8.14

+/-8.14 158

+/-7.84

+1-8.98 pCi/g 95 (75%-125%)

10/23/06 02:45 U

-2.58 Uncert:

+/-9.45 TPU:

+/-9.45 U

pCi/g 0

(0% -100%) AXP1 QC 12012100 Nickel-63 QC12012100 Nickel-63 Batch 41 MB 43 174224021 MS 580727 180 Uncert:

TPU:

Uncert:

TPU:

U 0.00

+/-2.82

+1-2.82 pCi/g pCi/g pCi/g 88 (75%-125%)

10/22/06 22:13 10/22/06 22:46 10/22/06 21:57 10/22/06 22:30 577 U

Uncert:

TPU:

-2.58

+/-9.45

+/-9.45 QC1201210847 174346016 DUP Technetium-99 QC1201210849 LCS Technetium-99 QC1201210846 MB Technetium-99 QC1201210848 174346016 MS Technetium-99 U

-0.146 Uncert:

+/-0.233 TPU:

+/-0.233 U

446

+/-21.3

+/-26.8

-0.172

+/-0.265

+/-0.265 12.1

+/-0.535

+/-0.614 77 (75%-125%)

pCi/g 0

(0% - 100%) KXRI 13.1 Uncert:

TPU:

Uncert:

TPU:

12.9 U

Uncert:

TPU:

U 0.0139

+/-0.214

+/-0.214 pCi/g pCi/g pCi/g 92 (75%-125%)

10/24/06 11:56 10/24/06 12:29 10/24/06 11:40 10/24/06 12:12

-0.146

+/-0.233

+/-0.233 11.5

+/-0.584

+/-0.651 89 (75%-125%)

Batch 580729 QC1201210855 174346016 DUP Tritium QC1201210857 LCS Tritium U

9.05 Uncert:

+/-6.30 TPU:

+/-6.30 45.8 Uncert:

TPU:

U

-1.8

+/-4.98

+/-4.98 46.0

+/-7.99

+/-8.03 pCi/g 0

(0% - 100%) DFAI 10/24/06 13:41 10/24/06 14:15 pCi/g 100 (75%-125%)

80

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174346 Page 8 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time Rad Liquid Scintillation Batch 580729 QC1201210854 MB Tritium QC1201210856 174346016 MS Tritium Uncert:

TPU:

U

-1.27

+/-5.32

+/-5.32 pCi/g pCi/g 10/24/06 13.:24 10/24/06 13:58 51.2 U

Uncert:

TPU:

9.05

+/-6.30

+/-6.30 Batch 580730 QC1201210859 174346016 DUP Carbon-1 4 U

-0.0717 Uncert:

+/-0.110 TPU:

+/-0.110 U

39.8

+/-8.21

+/-8.24

-0.0607

+/-0.114

+/-0.114 6.73

+/-0.206

+/-0.231 78 (75%-125%)

pCi/g 0

(0% - 100%) AXD2 10/20/06 08:03 QC1201210861 Carbon-14 QC1201210858 Carbon-14 LCS MB 6.86 Uncert:

TPU:

Uncert:

TPU:

6.93 U

Uncert:

TPU:

U

-0.107

+/-0.110

+/-0.110 pCi/g pCi/g pCi/g 98 (75%-125%)

10/20/06 10:09 10/20/06 07:00 10/20/06 09:06 QC1201210860 174346016 MS Carbon-14

-0.0717

+/-0.110

+/-0.110 6.92

+/-0.209

+/-0.235 100 (75%-125%)

Notes:

The Qualifiers in this report are defined as follows:

A B

BD C

D H

J N/A R

U UI X

Y A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported The TIC is a suspected aldol-condensation product Target analyte was detected in the associated blank Results are either below the MDC or tracer recovery is low Analyte has been confirmed by GC/MS analysis Results are reported from a diluted aliquot of the sample Analytical holding time was exceeded Value is estimated Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Gamma Spectroscopy--Uncertain identification Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier QC Samples were not spiked with this compound RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL 81

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174346 Page 9 of 9 Parmnarne NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time A

h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.

" Indicates analyte is a surrogate compound.

^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.

For PS, PSD, and SDLLT results, the values listed are the measured amounts, not final concentrations.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.

82

General Narrative 1

General Narrative for Connecticut Yankee Atomic Power Co.

Work Order: 174936 SDG: MSR#06-1407 October 30, 2006 Laboratory Identification:

General Engineering Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 Summary Sample receipt The samples arrived at General Engineering Laboratories, LLC, Charleston, South Carolina on October 26, 2006 for analysis. Shipping container temperatures were checked,.documented, and within specifications. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any visible signs of tampering or breakage.

Sample Identification The laboratory received the following samples:

Laboratory Identification 174936001 174936002 174936003 174936004 174936005 174936006 174936007 Sample Description 9522-01-005C 9522-01-007C 9520-0004-016F 9520-0004-017F 9504-0-01OC 9504-0-013C 9520-0005-019F Items of Note There are no items to note.

Case Narrative Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL)

Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package.

Analytical Request Four soil samples were analyzed for CHALL. Three soil samples were analyzed for FSSGAM.

Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, Data Review Qualifier Definitions, and data from the following fractions: Radiochemistry.

GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.

P.O. BOX 30712 Charleston, SC 29417 - 2040 Savage Road (29407)

Phone (843) 556-8171 - Fax243) 766-1178 www.gel.com

I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.

Cheryl J nes Project Manager GENERAL ENGINEERING LABORATORIES. LLC a Member of THE GEL GROUP, INC.

P.O. BOX 30712 Charleston, SC 29417

• 2040 Savage Road (29407)

Phone (843) 556-8171 - Fax,43) 766-1178 wwwgel.com

List of current GEL Certifications as of 30 October 2006 State Certification Alaska UST-062 Arizona AZ0668 Arkansas 88-0651 CLIA 42D0904046 California 0115 CA Colorado GenEngLabs Connecticut PH-0169 Dept. of Navy NFESC 413 EPA WG-15J Florida/NELAP E87156 Georgia E87156 (FL/NELAP)

Hawaii N/A Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas E-10332 Kentucky 90129 Louisiana 03046 Maryland 270 Massachusetts M-SCO12 Michigan 9903 Nevada SC]2 New Jersey SCO02 New Mexico FL NELAP E87156 New York 11501 North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-00485 South Carolina 10120001/10585001/10120002 Tennessee 02934 Texas TX213-2006A Texas NELAP T104704235-06-TX U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah 8037697376 GEL Vermont VT87156 Virginia 00151 Washington C1641 4

Chain of Custody and Supporting Documentation 5

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major

)

~Chain of Custody Form N.20-03 Connecticut Yankee Atomic Power Company No. 2006-00637 362 Injun Hollow Road, East Hampton, CT 06424-860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone:

Comments:

860-267-3924 Media Sample Container Jack McCarthy Code Type Size-Analytical Lab (Name, City, State):

Code

&Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones (843-556-8171)

Priority: L 30 D. E 14 D. Z 7 D.

Other:

Sample Designation Date Time

, Comment. Preservation Lab Sample ID.

9522-01-005C 1o~'*u.

3

.5 TS G

BP X

"t39.,-ol-Co,*ic Lo-19b-or, t-LI te NOTES: P0 #: 002332 MSR #: OG-1 H07 Z

LTP QA

[I Radwaste QA F-1 Non: QA Samples Shipped Via:

IntemaI,(qntainer Z

Fed Ex Temp.:

Deg.C Dl Hand Custody Sealed?

1)

Relin uis a

Date/Time

2) Recie yaeTm Custo~j Seal Intact?

r4ýEl Other V-36.

jCxWý Nt 6.O

3) Ro quishecrBy Date/Time

4) Received By I___ateTim__7__6_._____f_3_52__X N 01

Bill of Lading #

5) Relinquished By Date/Time

6) Received By Date/Time

Health Physics Procedure G PP-GGG R-R5104-003 -Attach ment B-CY-001 Major Health Physics Procedure G PP-GGGR-RS I 04-003-Attachment B-CY-O0 I Major Chain of Custody Form No. 2006-00638 Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Contact Name & Phone:

Jack McCarthy 860-267-3924 Analyses Requested LaD use Only.

4 Comments:

Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 817 1. Attn. Cheryl Jones Priority: 0 30 D. [] 14 D. Z 7 D. F] 3 D.

0 r.i' 22 (I) r~d~

Sample Designation Date Time Media Code Sample Type Code Container Size-

&Type.

Code.

Comment. Preservation 9520-0004-016F Ll/~/

TS C

BP 9520-0004-017F

/I //

DL C,ý L/7y TS G

BP X

I J______

______I_____I_____

_____Ir I____

.... 1___________F____

NOTES: PO #: 002332 MSR #: 06-1407 SSWP# NA Z LTP QA

[E Radwaste QA

[] Non QA Samples Shipped Via:

Z Fed Ex IZ UPS F-1 Hand D Other 77 V-z-3y 32s2-z Bill of Lading #

Internal ntainer Temp.*-

Deg.

C" CustodySealed?

y *N i I Custody Seal Intact?

Yý N J

) Relnq W

ed B Date/Time 2

eived By Date/Tirne

3) linqui ed By Date/Time

4) Received By Date/Time

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00639 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Analyses Requested Lab Use Only Decommissioning Contact Name & Phone:

Comments:

Jack McCarthy 860-267-3924 Media Sample Container Code Type Size-.

Analytical Lab (Name, City, State):

Code

&Type AnalyicalCode General Engineering Laboratories 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones (843-556-8171)

Priority: El 30 D. El 14 D. [

7 D.

Other:

Sample Designation Date Time Comment, Preservation Lab Sample ID 9504-0-01OC 10/10/06 1035 TS G

BP X

9504-0-013C 10/10/06 0820 TS G

BP X

NOTES: PO : 002332 MSR #: OG LTP QA "

Radwaste.QA.

E Non QA Samples Shipped Via:

Internal Container.

Fed Ex Temp.:

0 Deg. C E[ ups Hl H-and Cx*sody Sealed?

• ,N5-N 0]

1) Reli Uisjd By Date/Time

2) R d By Date/Time Cusod. Seal Intact?

A-~--

S -4 A a~i El,0,o 9"

Other

3) Reiquished1By

'Date/Time

4) Received By Date/Time 79ýBl 7"-63 #Y.-4.-f -

N5ý--

N n Bill of Lading #

5) Relinquished By Date/Time

6) Received By Date/Time

GPP-CiG'GR-R5104-003-Attacihment B-CY-00 I Major Health Physics Procedure i

,iw."-

'Chain of Custody.Form "No.

2006-00640 Connecticut Yankee Atomic Power Company CN 362 Iniun Hollow Road, East Hampton. CT 06424 860-267-2556 Ani-alyses Requested Lab Use Only Project Name: Hadd'am Neck"Decom missioning"

,alssRqetdLb./eOy

~Comments:

Contact Name & Phone:

Commnts Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0

843 556 8171. Attn. Cheryl Jones Priority: [E 30 D. E' 14 D. N 7 D. l 3 D.

Contajiitr Sample S~iLe-Sample Designation Date Time Mcdia Type

&Type Comment, Preservation Lab Sample ID Code Code Code 9520-0005-0t9F 101/23/06 TS G

BP X

.ii

.. i

%0 NOTES: PO #: 002332 MSR 1: 06-14&4 I t4O-7 SSWP# NA Z LTP QA El Radwaste. QA 7l Non QA Samples Shipped. Via:

0 Fed Ex LI uPs E

Hand LI Other Bill of Lading 9 Internal Container Temp.: L Deg.

Cuty Sealed?

\\-

NrI ustKody Seal hlnacl?

Y' N. 1

1) Relin Byuis y

Date/Time 2

'vedBy Date/Time 6Ree

4) R e B0

3) Roquished iy DatefTinie

4) Rece.ived By Date/Time

Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List.

Date/Time Received:

). 'it)

[

.:4 Q Li SDG#:.M

-~A~'

Work Order Number:

V

", L Shipping Container ID:

Chain of Custody#a j33 --

MO 0 (O-.

1.

Custody Seals osishipping container intact?.

Yes,

'No []

2.

Custody Seals dated and signed?

Yes No 1

3.

Chain-of-Custody reerd pre.sent?

Yes

• No [II

4.

Cooler temperature_

5.

Vermiculite/packing materials is:

Wet [( Dry

6.

.. *Number of samples in shipping container:.

7.

Sample holding times exc'eeded?

Yes [ ] No

8. Samples have:

-hazard labels custody seals appropriate sample labels 9.Samples arci i($in good condition

-leaking

_broken

-have air bubbles 0

10.

Were any anomalies identified in sample receipt?

1....Description of anomalies,(include sample numbers):

Yes No** f Sarnple Custodian/Laboratory:

I Dat a

4

,(

Telephoned to:

-On By

• 10-

• Data Review Qualifier Definitions 11

Data Review Qualifier Definitions Qualifier Explanation A quality control analyte recovery is outside of specified acceptance criteria Analyte is a surrogate compound c

Result is less than value reported Result is greater than value reported RPD of sample and duplicate evaluated using +/-RL. Concentrations are <SX the RL A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank B

Metals-Either presence of analyte detected in the associated blank, or MDL/IDL < sample value < PQL BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample d

5-day BOD-The 2:1 depletion requirement was not met for this sample E

Organics-Concentration of the target analyte exceeds the instrument calibration range E

Metals-%difference of sample and SD is

>10%.

Sample concentration must meet flagging criteria H

Analytical holding time was exceeded h

Preparation or preservation holding time was exceeded J

Value is estimated N

Metals-The Matrix spike sample recovery is not within specified control limits N

Organics-Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC).

Quantitation is based on nearest internal standard response factor N/A Spike recovery limits do not apply.

Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the reporting limit UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound Z

Paint Filter Test-Particulates passed through the filter, however no free liquids were observed.

GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.

P.O. BOX 30712 Charleston, SC 29417 - 2040 Savage Road (29407)

Phone (843) 556-8171 - FaJ2fl3) 766-1178 vww.gel.com

RADIOLOGICAL ANALYSIS 13

Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)

Work Order 174936 Method/Analysis Information Product:

Alphaspec Am241, Cm, Solid ALL FSS Analytical Method:

DOE EML HASL-300, Am-05-RC Modified Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 583311 583211 583196 Sample ID 174936001 174936002 174936005 174936006 1201216888 1201216890 1201216891 1201217370 Client ID 9522-01-005C 9522-01-007C 9504-0-01 OC 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS) 174936001(9522-01-005C) Sample Duplicate (DUP)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources Were prepared in the same geometry as the calibration standards.

14

Ouality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments The blank, 1201216888 (MB), did not meet the detection limit due to keeping the blank volume consistent with the other sample aliquots. All other samples met the detection limits.

Oualifier information Manual qualifiers were not required.

Method/Analysis Information 15

Product:

Alphaspec Pu, Solid-ALL FSS DOE EML HASL-300, Pu-II -RC Modified Analytical Method:

Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 583312 583211 583196 Sample ID 174936001 174936002 174936005 174936006 1201216892 1201216893 1201216894 1201216895 Client ID 9522-01-005C 9522-01-007C 9504-0-01OC 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0l I REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable andused before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information 16

All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Pu241, Solid-ALL FSS Analytical Method:

DOE EML HASL-300, Pu-11-RC Modified Prep Method:

Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:

Dry Soil Prep Analytical Batch Number:

583313 Prep Batch Number:

583211 Dry Soil Prep GL-RAD-A-021 Batch Number:

583196 17

Sample ID 174936001 174936002 174936005 174936006 1201216896 1201216897 1201216898 1201216899 Client ID 9522-01-005C 9522-01-007C 9504-0-01 0C 9504-0-01 3C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis The batch was recounted due to a low LCS recovery.

18

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments' Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method:

Prep Method:

EML HASL 300, 4.5.2.3 Dry Soil Prep Analytical Batch Number:

583389 Prep Batch Number:

583196 Sample ID 174936001 174936002 174936003 174936004 174936005 174936006 174936007 1201217095 1201217096 1201217097 Client lD 9522-01-005C 9522-01-007C 9520-0004-016F 9520-0004-017F 9504-0-01 OC 9504-0-013C 9520-0005-019F Method Blank (MB) 174911001(9801-0-RI01-SFCC-01-C1 (0-2in)) Sample Duplicate (DUP)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 13.

19

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174911001 (9801-0-RI01-SFCC-01-C1 (0-2in)).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information 20

Qualifier UI UI UI Reason Data rejected due to high counting uncertainty.

Data rejected due to high peak-width.

Data rejected due to interference.

Data rejected due to low abundance.

Analyte Sample Bismuth-212 1201217096 Cesium-134 1201217095 Europium-155 174936002 Manganese-54 174936002 174936005 Cesium-134 174936001 174936002 174936005 174936007 1201217096 Lead-214 1201217095 UI Method/Analysis Information Product:

Analytical Method:

Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

GFPC, Sr90, solid-ALL FSS EPA 905.0 Modified Ash Soil Prep Dry Soil Prep 583243 583211 583196 Sample ID 174936001 174936002 174936005 174936006 1201216717 1201216718 1201216719 1201216720 Client ID 9522-01-005C 9522-01-007C 9504-0-010C 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS) 21

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volumes in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples were recounted due to being originally counted on detectors with expired calibrations.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments The blank result for 1201216717 (MB) is greater than the MDA but less than the detection limit.

22

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Tc99, Solid-ALL FSS Analytical Method:

Analytical Batch Number:

Sample ID 174936001 174936002 174936005 174936006 1201216689 1201216690 1201216691 1201216692 DOE EML HASL-300, Tc-02-RC Modified 583233.

Client ID 9522-01-005C 9522-01-007C 9504-0-01 0C 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information 23

All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 174936001 (9522-01-005C) and 174936002 (9522-01-007C) were recounted due to spectral interference.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments The result for sample 174936006 (9504-0-013C) is biased high due to spectral interference.

Qualifier information Qualifier Reason Analyte Sample x

Sample result biased high due to spectral interference.

Technetium-99 174936006 Method/Analysis Information Product:

Liquid Scint Fe55, Solid-ALL FSS DOE RESL Fe-1, Modified Analytical Method:

Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 583239 583211 583196 24

Sample ID 174936001 174936002 174936005 174936006 1201216709 1201216710 1201216711 1201216712 Client ID 9522-01-005C 9522-01-007C 9504-0-01OC 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

25

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint Ni63, Solid-ALL FSS Analytical Method:

DOE RESL Ni-1, Modified Prep Method:

Dry Soil Prep GL-RAD-A-021 Method:

Analytical Batch Number:*

Prep Batch Number:

Dry Soil Prep GL-RAD-A-021 Batch Number:

Ash Soil Prep Dry Soil Prep 583241 583211 583196 Sample ID 174936001 174936002 174936005 174936006 1201216713 1201216714 1201216715 1201216716 Client ID 9522-01-005C 9522-01-007C 9504-0-01 OC 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.

Calibration Information:

Calibration Information 26

All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Oualifier information Manual qualifiers were not required.

Method/Analysis Information 27

Product:

Analytical Method:

Analytical Batch Number:

Sample ID 174936001 174936002 174936005 174936006 1201216693 1201216694 1201216695 1201216696 LSC, Tritium Dist, Solid-HTD2,ALL FSS EPA 906.0 Modified 583234 Client ID 9522-01-005C 9522-01-007C 9504-0-01 OC 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

28

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 174936005 (9504-0-010C) was recounted due to high MDA.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG..:

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product:

Liquid Scint C14, Solid All,FSS Analytical Method:

Analytical Batch Number:

Sample ID 174936001 174936002 174936005 174936006 1201216701 1201216702 1201216703 1201216704 EPA EERF C-01 Modified 583236 Client ID 9522-01-005C 9522-01-007C 9504-0-010C 9504-0-013C Method Blank (MB) 174936001(9522-01-005C) Sample Duplicate (DUP) 174936001(9522-01-005C) Matrix Spike (MS)

Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

29

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 174936001 (9522-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.

Review Validation:

30

GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for.CLP or CLP-like packaging will receive a third level validation upon completion of the data package.

The following data validator verified the information presented in this case narrative:

Reviewer/Date:

A4 31

SAMPLE DATA

SUMMARY

32

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANK001 Connecticut Yankee Atomic Power Co.

Client SDG: MSR#06-1407 GEL Work Order: 174936 The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Analyte is a surrogate compound U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier ND The analyte concentration is not detected above the detection limit.

The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.

This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones.

Reviewed by 33

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Report Date:

November 2, 2006 Project:

Soils PO# 002332 Client Sample ID:

9522-01-005C Project:

YANK01204 Sample ID:

174936001 Client ID:

YANK001 Matrix:

TS Vol. Recv.:

Collect Date:

18-OCT-06 Receive Date:

26-OCT-06 Collector:

Client Moisture:

37.8%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Gn, Solid ALL FSS Americium-241 U

0.00136

+/-0.138 0.115

+/-0.138 Curium-242 Curium-243/244 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U

0.0391

+/-0.110 0.0674

+/-0.110 U

-0.0385

+/-0.139 0.132

+/-0.140 U

-0.104

+/-0.112 0.133

+/-0.113 0.327 0.237 0.361 0.352 0.326 pCi/g pCi/g pCi/g pCi/g pCi/g MXA 10/30/06 1058 583311 1

Plutonium-239/240 U

-0.137

+/-0.0631 0.120 +/-0.0652 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U

-5.01 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.942 Americium-241 0.232 Bismuth-212 1.25 Bismuth-214 1.01 Cesium-134 UI 0.00 Cesium-137 1.58 Cobalt-60 U

0.0278 Europium-152 U

-0.0437 Europium-154 U

0.0164 Europium-155 U

0.0621 Lead-212 1.10 Lead-214 0.962 Manganese-54 U -0.00466 Niobium-94 U

-0.0112

.Potassium-40 12.1 Radium-226 1.01 Silver-108m U3.670E-05 Thallium-208 0.306 Rad Gas Flow Proportional Counting

+/-7.31 6.36

+/-7.31 13.4 pCi/g

+/-0.216

+/-0.147

+/-0.452

+/-0.155

+/-0.0505

+/-0.100

+/-0.0308

+/-0.0735

+/-0.0885

+/-0.0836

+/-0.0891

+/-0.132

+/-0.0271

+/-0.0232

+/-1.00

+/-0.155

+/-0.026

+/-0.0549 0.0684 0.0857 0.152 0.0431 0.0289 0.0221 0.0272 0.0588 0.0637 0.0693 0.0406 0.044 0.0223 0.0188 0.191 0.0431 0.0213 0.0218

+/-0.216

+/-0.147

+/-0.452

+/-0.155

+/-0.0505

+/-0.100

+/-0.0308

+/-0.0735

+/-0.0885

+/-0.0836

+/-0.0891

+/-0.132

+/-0.0271

+/-0.0232

+/-1.00

+/-0.155

+/-0.026

+/-0.0549 0.148 0.177 0.326 0.091 0.061 0.0469 0.0585 0.123 0.139 10.143 0.0838 0.0921 0.0474 0.0401 0.423 0.091 0.0446 0.0461 0.0172 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MXA 10/30/06 1058 583312 2

1 MXA 11/02/060824 583313 3

1 MJHI 10/31/06 0910 583389 5

KSDI 11/01/06 2100 583243 6

GFPC, Sr90, solid-ALL FSS Strontium-90 0.0263

+/-0.0109 0.00825

+/-0.011 34

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date:

November 2, 2006 Client Sample ID:

Sample ID:

9522-01-005C 174936001 Project:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier R

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U

Liquid Scint C14, Solid AII,FSS Carbon-14 U

Liquid Scint Fe55, Solid-ALL FSS Iron-55 U

Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U

Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U

esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 3.72

+/-5.94 4.71

+/-5.94 10.2 0.184

+/-0.112 0.0898

+/-0.112 pCi/g pCi/g pCi/g 14.2

+/-19.7 12.8

+1-19.7 27.0 DFAI 10/28/06 0650 583234 7

AXD2 10/27/062110 583236 8

MXPI 11/01/06 1809 583239 9

MXPI 11/01/06 1536 583241 1(

KXRI 10/31/06 2145 583233 11

+/-7.83 6.60

+/-7.83 13.8 pCi/g 0.320

+/-0.221 0.181

+/-0.221 0.367 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLI 10/26/06 1442 583196 The following Analytical Methods were performed Method Description I

DOE EML HASL-300, Am-05-RC Modified 2

DOE EML HASL-300, Pu-I1-RC Modified 3

DOE EML HASL-300, Pu-11-RC Modified 4

DOE EML HASL-300, Pu-11-RC Modified 5

EML HASL 300, 4.5.2.3 6

EPA 905.0 Modified 7

EPA 906.0 Modified 8

EPA EERF C-01 Modified 9

DOE RESL Fe-1, Modified 10 DOE RESL Ni-l, Modified II DOE EML HASL-300, Tc-02-RC Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery %

Acceptable Limits Ainericium-243 Plutonium-242 Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS 92 93 (15%-125%)

(15%-125%)

35

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

9522-01-005C 174936001 Proeect:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Plutonium-241 Strontium-90 Carrier/Tracer Recovery lron-55 Nickel-63 Carrier/Tracer Recovery Technetium-99 Carrier/Tracer Recovery Liquid Scint Pu24L, Solid-ALL FS GFPC, Sr90, solid-ALL FSS GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 88 76 76.

83 88 88 50 50 (25%-125%)

(25%- 125%)

(25%-125%)

(15%-125%)

(25%-125%)

(25%-125%)

(15%-125%)

(15%-125%)

Notes:

The Qualifiers in this report are defimed as follows:

A quality control analyte recovery Js outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

36

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

AA 9522-01-007C 174936002 TS 18-OCT-06 26-OCT-06 Client Proiect:

YANK01204 Client ID:

YANK001 Vol. Recv.:

oviuja LUI

s.

10 /0 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Atn241, Cm, Solid ALL FSS Amnericium-241 U

0.0547

+/-0.122 0.0789

+/-0.123 Curium-242 Curium-243/244 Alphaspec Pu, Solid-ALL FSS Plutonium-238 Plutonium-239/240 Liquid Scint Pu241, Solid-ALL F Plutonium-241 U

0.0395

+/-0.0893 0.048 +/-0.0894 U

-0.0258

+/-0.0943 0.0912 +/-0.0944 0.237 0.180 0.262 0.252 0.269 pCi/g pCi/g pCi/g pCi/g pCi/g U

-0.0671

+/-0.0439 U

0.0733

+/-0.145 0.0837 +/-0.0444 0.0925

+/-0.145 MXA I

MXA I

MXA I

10/30/06 1058 583311 1

10/30106 1058 583312 2

11/02/06 0840 583313 3

4.10

+/-7.32 5.96

+/-7.33 12.5 pCi/g Rad Gamma Spec Analysis Ga~mna,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 4.39

+/-0.204 Americium-241 U

-0.147

+/-0.0988 Bismuth-212 2.99

+/-0.322 Bismuth-214 1.41

+/-0.0972 Cesium-134 UI 0.00

+/-0.0358 Cesium-137 2.55

+/-0.0752 Cobalt-60 U

0.0262

+/-0.0175 Europium-152 U

-0.03

+/-0.059 Europium-154 U

0.0248

+/-0.0468 Europium-155

. U]

0.00

+/-0.0881 Lead-212 4.38

+/-0.0865 Lead-214 1.56

+/-0.100 Manganese-54 UI 0.00

+/-0.0272 Niobium-94 U

0.0109

+/-0.0182 Potassium-40 2.51

+/-0.375 Radium-226 1.41

+/-0.0972 Silver-108m U -0.00514

+/-0.0191 Thallium-208 1.40

+/-0.0595 Rad Gas Flow Proportional Counting 0.0457 0.0841 0.128 0.0296 0.0276 0.0187 0.0166 0.0503 0.0422 0.056 0.0288 0.0346 0.0159 0.0162 0.124 0.0296 0.0173 0.0174

+/-0.204

+/-0.0988

+/-0.322

+/-0.0972

+/-0.0358

+/-0.0752

+/-0.0175

+/-0.059

+1-0.0468

+/-0.0881

+/-0.0865

+/-0.100

+/-0.0272

+/-0.0182

+/-0.375

+/-0.0972

+/-0.0191

+/-0.0595 0.0959 0.170 0.264 0.0611 0.0564 0.0386 0.0351 0.103 0.0893 0.114 0.0585 0.0707 0.0331 0.0335 0.266 0.0611 0.0353 0.0359 0.0128 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g PpCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 10/31/06 0925 583389 5

KSD1 11/01/062100 583243 6

GFPC, Sr9O, solid-ALL FSS Strontium-90 Rad Liquid Scintillation Analysis 0.0327

+/-0.00864 0.00613 +/-0.00866 37

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www~gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

9522-01-007C 174936002 Project:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier I

Rad Liquid Scintillation Analysis LSC, Tritiun Dist, Solid-HTD2,ALL FSý Tritium U

Liquid Scint C14, Solid All, FSS Carbon-14 U

(

Liquid Scint Fe55, Solid-ALL FSS Iron-55 U

Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U

Liquid Scint Tc99, Solid-ALL FSS Technetium-99 Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 3.14

+/-7.71 6.23

+/-7.71

).0254

+/-0.113 0.0944

+/-0.113 8.48

+/-18.0 11.8

+/-18.0 2.80

+/-7.02 5.78

+/-7.02 0.321

+/-0.163 0.126

+/-0.163 13.5 0.194 24.9 pCi/g DFAI 10/28/06 0706 583234 7

pCi/g pCi/g AXD2 10/27/06 2158 583236 8

MXPI 11/01/06 1825 583239 9

MXPI ] 1/01/06 1558 583241 l(

KXR1 10/31/062246 583233 11 12.1 pCi/g 0.262 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLI 10/26/06 1442 583196 The following Analytical Methods were performed Method Description I

DOE EML HASL-300, Am-05-RC Modified 2

DOE EML HASL-300, Pu-11-RC Modified 3

DOE EML HASL-300, Pu-1-RC Modified 4

DOE EML HASL-300, Pu-11-RC Modified 5

EML HASL 300, 4.5.2.3 6

EPA 905.0 Modified 7

EPA 906.0 Modified 8

EPA EERF C-01 Modified 9

DOE RESL Fe-l, Modified 10 DOE RESL Ni-I, Modified I I DOE EML HASL-300, Tc-02-RC Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery %

Acceptable Limits Americium-243 Plutonium-242 Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS 93 91 (15%-125%)

(15%-125%)

38

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticui 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

9522-01-007C 174936002 Project:

YANK01204 Client ID:

YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Plutonium-241 Strontium-90 Carrier/Tracer Recovery Iron-55 Nickel-63 Carrier/Tracer Recovery Technetium-99 Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FE GFPC, Sr90, solid-ALL FSS GFPC, Sr9O, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 94 100 100 86 90 90 113 113 (25%-o125%)

(25%-1-25%)

(25%-125%)

(15%-125%)

(25%-125%)

(25%-1 25%)

(15%-125%)

(15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UT Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

39

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 0023321 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

"N,'n* ch p-9520-0004-016F 174936003 TS 19-OCT-06 26-OCT-06 Client 1r AOM' Proeect:

YANK01204 Client ID:

YANKO01 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.747

+/-0.134 Americium-241 U

0.0504

+/-0.105 Bismuth-212 0.654

+/-0.242 Bismuth-214 0.970

+/-0.0713 Cesium-134 U

0.0184

+/-0.0256 Cesium-137 0.125

+/-0.0228 Cobalt-60 U -0.00778

+/-0.0166 Europium-152 U

0.00444

+/-0.044 Europium-154 U

-0.0216

+/-0.0534 Europium-155 U

0.0674

+/-0.0698 Lead-212 0.838

+/-0.0517 Lead-214 1.12

+/-0.0838 Manganese-54 U

0.0154

+/-0.0174 Niobium-94 U -0.00323

+/-0.015 Potassium-40 12.1

+/-0.758 Radium-226 0.970

+/-0.0713 Silver-108m U -0.00181

+/-0.0144 Thallium-208 0.238

+/-0.0369 0.0498 0.0823 0.105 0.026 0.0177 0.0129 0.0131 0.0366 0.0432 0.0415 0.0219 0.0267 0.0152 0.0124 0.140 0.026 0.0125 0.013

+/-0.134

+/-0.105

+/-0.242

+/-0.0713

+/-0.0256

+/-0.0228

+/-0.0166

+/-0.044

+/-0.0534

+/-0.0698

+/-0.0517

+/-0.0838

+/-0.0174

+/-0.015

+/-0.758

+/-0.0713

+/-0.0144

+/-0.0369 0.105 0.169 0.221 0.0544 0.0372 0.0273 0.0286 0.076 0.0927 0.0852 0.045 0.0553 0.032 0.026 0.303 0.0544 0.0261 0.0273 pCi/g pCi/g pCi/g pci/g pCi/g pCi/a pCi/g pCi/g pci/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHl 10/31/060927 583389 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1443 583196 The following Analytical Methods were performed Method Description I

.EML HASL 300,4.5.2.3 Notes:

The Qualifiers in this report are defined as follows A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 40

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date' November 2, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-016F Project:

YANK01204 Sample ID:

174936003 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol--condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GCiMS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

41

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date:

November 2, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0004-017F 174936004 TS 19-OCT-06 26-OCT-06 Client 18.7%

Project:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamnina,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.492

+/-0.157 Americium-241 U

-0.0222

+/-0.0995 Bismuth-212 0.424

+/-0.289 Bismuth-214 0.778

+/-0.115 Cesium-134 U

0.00206

+/-0.0338 Cesium-137 0.168

+/-0.0358 Cobalt-60 U

-0.0183

+/-0.024 Europium-152 U -0.00147

+/-0.061 Europium-154 U

-0.0213

+/-0.0645 Europium-155 U

0.00598

+/-0.0551 Lead-212 0.616

+/-0.0645 Lead-214 0.926

+/-0.0913 Manganese-54 U

0.0215

+/-0.0229 Niobium-94 U

0.00767

+/-0.0209 Potassium-40 9.31

+/-0.909 Radium-226 0.778

+/-0.115 Silver-108m U -0.00183

+/-0.0211 Thallium-208 0.222

+/-0.0438 0.0658 0.0726 0.143 0.0326 0.0207 0.0171 0.0187 0.0498 0.0528 0.0479 0.0293 0.0374 0.0202 0.0179 0.166 0.0326 0.0168 0.0192

+/-0.157

+/-0.0995

+/-0.289

+/-0.115

+/-0.0338

+/-0.0358

+/-0.024

+/-0.061

+/-0.0645

+/-0.0551

+/-0.0645

+/-0.0913

+/-0.0229

+/-0.0209

+/-0.909

+/-0.115

+/-0.0211

+/-0.0438 0.140 0.149 0.303 0.0688 0.0438 0.0363 0.0408 0.103 0.115 0.0986 0.0603 0.0776 0.0426 0.0376 0.366 0.0688 0.0352 0.0402 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCilg pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/31/06 0927 583389 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1444 583196 The following Analytical Methods were performed Method Description I

EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 42

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date:

November 2, 2006

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0004-017F Proiect:

YANK01204 Sample ID:

174936004 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or prieservation holding time was exceeded The above sample is reported on a dry weight basis.

43

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

Moisture:

9504-0-OIOC 174936005 TS 10-OCT-06 26-OCT-06 Client 43.4%

Project:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec An241, Cm, Solid ALL FSS Americium-241 U

0.0682

+/-0.103 0.0315

+/-0.103 Curium-242 Curium-243/244 Alphaspec Pu, Solid-ALL FSS Plutonium-238 Plutonium-239/240 Liquid Scint Pu241, Solid-ALL F Plutonium-241

-0.046

+/-0.0403 0.0769 +/-0.0408

-0.10

+/-0.0956 0.126 +/-0.0966 0.0235

+/-0.087 0.0589

+/-0.087 U

0.0235

+/-0.0869 0.0588

+/-0.087 0.00

+/-6.56 5.51

+/-6.56 Rad Gamma Spec Analysis Gainma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 U

Bismuth-212 B ismuth-214 Cesium-134 UTI Cesium-137 Cobalt-60 U

Europium-152 U

Europium-154 U -

Europium-155 U

Lead-212 Lead-214 Manganese-54 111 Niobium-94 U

Potassium-40 Radium-226 Silver-108m U

Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 Rad Liquid Scintillation Analysis 0.635 0.0432 0.532 0.566 0.00 0.402 0.00339 0.00635

-0.00961 0.0463 0.655 0.611 0.00

-0.0145 10.0 0.566

-0.0205 0.223

+/-0.167

+/-0.109

+/-0.302

+/-0.113

+/-0.0454

+/-0.057

+/-0.0231

+/-0.0624

+/-0.0889

+/-0.0667

+/-0.0666

+/-0.108

+/-0.0682

+/-0.0248

+/-1.01

+/-0.113

+/-0.0201

+/-0.0488 0.0577 0.0836 0.151 0.0405 0.0264 0.0194 0.0198 0.0514 0.0634 0.0601 0.0278 0.038 0.0185 0.0196 0.181 0.0405 0.0159 0.0181

+/-0.167

+/-0.109

+/-0.302

+/-0.113

+/-0.0454

+/-0.057

+/-0.0231

+/-0.0624

+/-0.0889

+/-0.0667

+/-0.0666

+/-0.108

+/-0.0682

+/-0.0248

+/-1.01

+/-0.113

+/-0.0201

+/-0.0488 0.158 0.258 0.348 0.197 0.197 11.6 0.129 0.174 0.329 0.0866 0.0566 0.042 0.0448 0.109 0.141 0.125 0.0584 0.0804 0.0405 0.0421 0.414 0.0866 0.0342 0.0392 0.0126 pCi/g pCilg pCi/g pCi/g pCi/g pCi/g MXA I

MXA MXA I

10/30/06 1058 583311 1

10/30/06 1058 583312 2

11/02/06 0856 583313 3

pCi/g pCi/g pCilg pCilg pCilg pCi/ýg pCilg pCilg pCilg pCi/g pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 10/31/06 0928 583389 5

KSD1 11/01/06 2100 583243 6

0.0342

+/-0.00877 0.00599 +/-0.0088 44

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

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Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

9504-0-010C 174936005 Project:

YANK01204 Client ID:

YANKOOI Vol. Recv.:

Parameter Qualifier Result Rad Liquid Scintillation Analysis LSC, Trithin Dist, Solid-HTD2,ALL FSS Tritium U

-0.632 Liquid Scint C14, Solid AIIFSS Carbon-14 U

0.0868 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U

2.22 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U

-4.66 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U

0.475 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd

+/-6.79 5.72

+/-6.79

+/-0.115 0.0942

+/-0.115

+/-18.6 12.4

+/-18.6

+/-6.33 5.51

+/-6.33

+/-0.296 0.236

+/-0.296 11.9 0.193 26.3 11.5 0.486 pCi/g pCi/g pCi/g pCi/g pCi/g DFA1 11/01/06 0800 583234 8

AXD2 10/27/06 2245 583236 9

MXP1 11/01/06 1842 583239 10 MXPI 11/01/06 1619 583241 11 KXR1 10/31/06 0310 583233 12 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXL1 10/26/06 1444 583196 The following Analytical Methods were performed Method Description I

DOE EML HASL-300, Am-05-RC Modified 2

DOE EML HASL-300, Pu-1 I-RC Modified 3

DOE EML HASL-300, Pu-I 1-RC Modified 4

DOE EML HASL-300, Pu-I -RC Modified 5

EML HASL 300, 4.5.2.3 6

EPA 905.0 Modified 7

EPA 905.0 Modified 8

EPA 906.0 Modified 9

EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Ni-l, Modified

12.

DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery %

Acceptable Limits Americium-243 Plutonium-242 Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS 85 95 (15%-125%)

(15%-125%)

45

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

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Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date:

November 2, 2006 Client Sample ID:

Sample ID:

9504-0-01OC 174936005 Project:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Plutonium-241 Strontium-90 Carrier/Tracer Recovery Iron-55 Nickel-63 Carrier/Tracer Recovery Technetium-99 Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL F5 GFPC, Sr9O, solid-ALL FSS GFPC, Sr9O, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 102 84 84 82 93 93 78 78 (25%-125%)

(25%-1 25%)

(25%-125%)

(15%-125%)

(25%-125%)

(25%-125%)

(15%-125%)

(15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been conftrmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

46

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis

[

Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

Matrix:

Collect Date:

Receive Date:

Collector:

?jA'tCimrp' 9504-0-013C 174936006 TS I 0-OCT-06 26-OCT-06 Client AQ9 1Z M Proiect:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd IlD A.

1*.

Q An-l]join Jxutxlta p at, p

-ec ys Sz Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U

-0.0277

+/-0.0621 0.0513 +/-0.0621 Curium-242 U

Curium-243/244 U

Alphaspec Pu, Solid-ALL FSS Plutonium-238 U

Plutoniurn-239/240 U

Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U

0.0786

+/-0.108 0.0396

+/-0.108

-0.109

+/-0.0823 0.115 +/-0.0836

-0.00331

+/-0.105 0.0892

+/-0.105 0.180 0.164 0.307 0.253 0.239 pCi/g pCi/g pCi/g pCi/g pCi/g 0.120

+/-0.149 0.082

+/-0.150

-0.741

+/-6.61 5.58

+/-6.61 11.7 pCi/g Rad Gamma Spec Analysis Gaimna,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.506 Americium-241 U -0.00807 Bismuth-212 0.519 Bismuth-214 0.717 Cesium-134 U

0.00314 Cesium-137 0.684 Cobalt-60 U-0.000581 Europium-152 U

-0.0282 Europium-154 U

0.0313 Europium-155 U

0.0397 Lead-212 0.596 Lead-214 0.676 Manganese-54 U

0.0203 Niobium-94 U -0.00724 Potassium-40 5.95 Radium-226 0.717 Silver-108m U

0.00332 Thallium-208 0.180 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 0.178 Rad Liquid Scintillation Analysis

+/-0.193

+/-0.113

+/-0.319

+/-0.116

+/-0.029

+/-0.076

+/-0.0261

+/-0.0661

+/-0.076

+/-0.0774

+/-0.0656

+/-0. 107

+/-0.0251

+/-0.0293

+/-0.804

+/-0.116

+/-0.0405

+/-0.0485

+/-0.0136 0.0706 0.0819 0.151 0.0427 0.0232 0.0208 0.0212 0.0534 0.0646 0.0508 0.0366 0.0383 0.0222 0.0199 0.187 0.0427 0.0182 0.0208

+/-0.193

+/-0.113

+1-0.319

+/-0.116

+/-0.029

+/-0.076

+/10.0261

+/-0.0661

+/-0.076

+/-0.0774

+/-0.0656

+/-0.107

+/-0.0251

+/-0.0293

+/-0.804

+/-0.116

+/-0.0405

+/-0.0485 0.151 0.169 0.322 0.0896 0.0493 0.044 0.0462 0.111 0.140 0.105 0.0753 0.0799 0.047 0.042 0.412 0.0896 0.0383 0.0439 0.0131 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MXA 10/30/06 1058 583311 1

MXA 10/30/06 1058 583312 2

MXA 11/02/060913 583313 3

1 MJH1 10/31/06 0929 583389 5

KSDI 11/01/06 2100 583243 6

0.00626 +/-0.0145 47

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd.......

East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

9504-0-013C 174936006 Project:

YANK01204 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Rad Liquid Scintillation Analysis LSC, Tritiun Dist, Solid-HTD2,ALL FSS Tritium U

-1.43 Liquid Scint C14, Solid AII,FSS Carbon-14 U

0.190 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U

4.58 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U

-3.51 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 X

1.20 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd

+/-6.02 5.17

+/-6.02

+/-0.121 0.0969

+/-0.121

+/-18.8 12.4

+/-18.8

+/-7.96 6.83

+/-7.96

+/-0.319 0.237

+/-0.320 11.2 0.199 26.2 14.3 0.489 pCi/g pCi/g pCi/g pCi/g pCi/g DFAI 10/28/06 0738 583234 8

AXD2 10/27/06 2332 583236 9

MXPI 11/01/06 1858 583239 IC MXPI 11/01/06 1641 583241 11 KXR1 10/31/06 0327 583233 12 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLI 10/26/06 1445 583196 The following Analytical Methods were performed Method Description 1

DOE EML HASL-300, Am-05-RC Modified 2

DOE EML HASL-300, Pu-I 1-RC Modified 3

DOE EML HASL-300, Pu-I 1-RC Modified 4

DOE EML HASL-300, Pu-I l-RC Modified 5

EML HASL 300,4.5.2.3 6

EPA 905.0 Modified 7

EPA 905.0 Modified 8

EPA 906.0 Modified 9

EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Ni-i, Modified 12 DOE EML HASL-300, Tc-02-RC Modified 13 DOE EML HASL-300, Tc-02-RC Modified 14 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery %

Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 98 (15%-125%)

48

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address :

362 Injun Hollow Rd......

East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 Report Date: November 2, 2006 Client Sample ID:

Sample ID:

9504-0-013C 174936006 Proiect:

YANK01204 Client ID:

YANKOOI Vol. Recv.:

' Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Plutonium-242 Plutonium-241 Strontium-90 Carrier/Tracer Recovery bron-55 Nickel-63 Carrier/Tracer Recovery Technetium-99 Carrier/Tracer Recovery Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS GFPC, Sr9O, solid-ALL FSS GFPC, Sr9O, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 99 101 95 95 88 86 86 79 79 (15%-125%)

(25%-125%)

(25%-125%)

(25%-125%)

(15%-125%)

(25%-125%)

(25%-125%)

(15%-125%)

(15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GCIMS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

49

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

ConnecticutYankee Atomic Power Address :

• 362 Injun Hollow Rd East Hampton, Connecticut 06424

Contact:

Mr. Jack McCarthy Project:

Soils PO# 002332 R~port Date:

November 2, 2006 Client Sample ID:

Sample ID:

Mat-ix:

Collect Date:

Receive Date:

Collector:

Moisture:

9520-0005-019F 174936007 TS 23-OCT-06 26-OCT-06 Client 8.59%

Project:

Client ID:

Vol. Recv.:

YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gammna,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actiniiim-228 0.956

+/-0.140 Americium-241 U

-0.0344

+/-0.0932 BismuLh-212 0.469

+/-0.323 Bismuth-214 0.547

+/-0.0937 Cesium-134 Ut 0.00

+/-0.0287 Cesium-137

.0.128

+/-0.041 Cobalt-60 U

0.0143

+/-0.0233 Europium-152 U

-0.0255

+/-0.0562 Europium-154 U -0.0349

+/-0.0722 Europium-155 U

0.0307

+/-0.0645 Lead-212 0.754

+/-0.0632 Lead-214 0.623

+/-0.085 Manganese-54 U

0.0044

+/-0.0225 Niobium-94 U

0.00264

+/-0.0188 Potassium-40 11.2

+/-0.971 Radium-226 0.547

+/-0.0937 Silver-108m U

0.0078

+/-0.0199 Thallium-208 0.265

+/-0.044 0.0577 0.0853 0.150 0.0337 0.0245 0.0183 0.0193 0.0466 0.0565 0.0594 0.029 0.0372 0.0196 0.0164 0.126 0.0337 0.0172 0.0179

+/-0.140

+/-0.0932

+/-0.323

+/-0.0937

+/-0.0287

+/-0.041

+/-0.0233

+/-0.0562

+/-0.0722

+/-0.0645

+/-0.0632

+/-0.085

+/-0.0225

+/-0.0188

+/-0.971

+/-0.0937

+/-0.0199

+/-0.044 0.125 0.176 0.320 0.0717 0.0518 0.0391 0.0426 0.0979 0.123 0.122 0.0601 0.0779 0.0417 0.0351 0.290 0.0717 0.0363 0.038 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 10/31/06 0930 583389 1

The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 WXLI 10/26/06 1.445 583196 The following Analytical Methods were performed Method Description I

EMIL HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are def'med as follows A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported 50

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company:

Connecticut Yankee Atomic Power Address:

362 Injun HollowRd East Hampton, Connecticut 06424 Report Date:

November 2, 2006

Contact:

Mr, Jack McCarthy Project:

Soils PO# 002332 Client Sample ID:

9520-0005-019F Project:

YANK01204 Sample ID:

- 174936007 Client ID:

YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GCIMS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded J

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy-Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h

Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

51

QUALITY CONTROL DATA 52

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Client :

Connecticut Yankee Atomic Power 362 Injun Hollow Rd Report Date: November 2, 2006 Page 1 of 9 East Hampton, Connecticut

Contact:

Mr. Jack McCarthy Workorder:

174936 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time Rad Alpha Spec Batch 583311 QC1201217370 174936001 DUP Arnericium-241 Curium-242 Curium-243/244 U

0.00136 Uncert:

+/-0.138 TPU:

+/-0.138 U

0.0391 Uncert:

+/-0.110 TPU:

+/-0.110 U

-0.0385 Uncert:

+/-0.139 TPU:

+/-0.140 QC 1201216891 Arnericium-241 Curium-242 Curium-243/244 QC1201216888 Arnericium-241 Curiurn-242 Curium-243/244 QC1201216890 Americium-241 LCS MB 2.69 Uncert:

TPU:

Uncert:

TPU:

3.24 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

U

-0.0141

+1-0.0635

+/-0.0635 U

-0.0144

+/-0.020

+/-0.020 U

0.0308

+/-0.104

+/-0.104 2.51

+/-0.236

+/-0.371 U

-0.00394

+/-0.0135

+/-0.0135 2.95

+/-0.256

+/-0.422 U

-0.0169

+/-0.0283

+/-0.0284 U

0.0056

.+/-0.030

+/-0.030 U

0.0146

+/-0.0557

+/-0.0557 pCi/g 243 pCi/g 433 pCi/g 1800 pCilg peilg pCifg pCilg pCilg pCi/g pCi/g pci/g 93 (75%-125%)

10/30/06 10:58 (0% - 100%) AXAI (0%- 100%)

(0%- 100%)

91 (75%-125%)

10/30106 10:58 10/30/06 10:58 174936001 MS Curium-242 13.7 Uncert:

TPU Uncert:

TPU 16.5 Uncert:

TPU U

0.00136

+/-0.138

+/-0.138 U

0.0391

+/-0.110

+/-0.110 U

-0.0385

+/-0.139

+/-0.140 U

13.4

+/-1.31

+/-2.08 0.0528

+/-0.0991

+/-0.0993 16.0

+/-1.43

+/-2.41 98 (75%-125%)

10/30/06 10:58 Curium-243/244 97 (75%-125%)

Batch 583312 QC1201216893 174936001 DUP Plutonium-238 U

-0.104 U

-0.0623 pCi/g 50 (0% - 100%) IXAI 10/30/06 10:58 53

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174936 Page 2 of 9 Pa rrnnme NAM Samnle Anal 0C Units RPD%

REC%

Range Anilst Date Time Parynname NOM Sample Qual Rad Alpha Spec Batch 583312 Plutonium-239/240 QC1201216895 LCS Plutonium-238 Plutonium-239/240 QC1201216892 MB Plutonium-238 Plutonium-239/240 QC1201216894 174936001 MS Plutonium-238 Plutonium-239/240 Uncert:

+/-0.112 TPU:

+/-0.113 u

-0.137 Uncert:

+/-0.0631 TPU:

+/-0.0652 Uncert:

TPU:

2.49 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

U

-0.104 Uncert:

+/-0.112 TPU:

+/-0.113 12.6 U

-0.137 Uncert:

+/-0.0631 TPU:

+/-0.0652 U

-5.01 Uncert:

+/-7.31 TPU:

+/-7.31 U

+/-0.114

+/-0.114

-0.0217

+/-0.108

+/-0.108 pCi/g 145 (0%- 100%)

(75%- 125%)

U 0.00501

+/-0.0185

+/-0.0186 2.37

+/-0.239

+/-0.334 U

-0.0011

+/-0.0122

+/-0.0122 U

0.000219

+/-0.0119

+/-0.0119 PCi/g PCilg pCilg pCi/g pCi/g 10/30/06 10:58 95 (75%-125%)

10/30/06 10:58 U

0.0643

+/-0.142

+/-0.142 12.8

+/-1.22

+/-1.79 (75%-125%)

10/30/06 10:58 102 (75%-125%)

Batch 583313 QC1201216897 174936001 DUP Plutonium-24 1.

QC1201216899 LCS Plutonium-241 QC1201216896 MB Plutonium-241 QC1201216898 174936001 MS Plutonium-241 Rad Gamma Spec Batch 583389 QC1201217096 174911001 DUP Actinium-228 U

1.93

+/-8.93

+/-8.93 pCi/g 0

(0%- 100%) IXAI 35.9 Uncert:

TPU:

Uncert:

TPU:

141 U

Uncert:

TPU:

27.9

+/-2.66

+/-3.77 U

4.08

+/-8.97

+/-9.01 pCi/g pCi/g PCi/g 78 (75%-125%)

11/02/06 09:45 11/02/06 10:18 11/02/06 09:29 11/02/06 10:01

-5.01

+/-7.31

+/-7.31

• 124

+/-11.4

+/-16.5 88 (75%-125%)

0.325

+/-0.119 Uncert:

0.320

+/-0.135

+/-0.135 pCilg 2

(0% - 100%) MJHI 10/31/06 10:33 54

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

" 174936 Page 3 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time Rad Gamma Spec Batch 583389 Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europiumn-152 Europium-154 Europium-155 TPU:

+/-0.119 u

0.018 Uncert:

+/-0.0921 TPU:

+/-0.0921 0.274 Uncert:

+/-0.157 TPU:

+/-0.157 0.423 Uncert:

+/-0.070 TPU:

+/-0.070 UI 0.00 Uncert:

+/-0.033 TPU:

+/-0.033 UI 0.00 Uncert:

+/-0.0281 TPU:

+/-0.0281 u

-0.013 Uncert:

+/-0.0169 TPU:

+/-0.0169 u

0.024 Uncert:

+/-0.041 TPU:

+/-0.041 U

0.00185 Uncert:

+/-0.0495 TPU:

+/-0.0495 u

0.0651 Uncert:

+/-0.0432 TPU:

+/-0.0432 0.285 Uncert:

+/-0.0477 TPU:

+/-0.0477 0.402 Uncert:

+/-0.0695 TPU:

+/-0.0695 U

0.000309 Uncert:

+/-0.0169 TPU:

+/-0.0169 u

0.00718 Uncert:

+/-0.0145 TPU:

+/-0.0145 7.04 Uncert:

+/-0.674 TPU:

+/-0.674 0.423 Uncert:

+/-0.070 TPU:

+/-0.070 U

0.00582 Uncert:

+/-0.0134 U

0.0192

+/-0.058

+/-0.058 UI 0.00

+/-0.192

+/-0.192 0.448

+/-0.0781

+/-0.0781 U!

0.00

+/-0.0327

+/-0.0327 U

-0.00065

+/-0.0206

+/-0.0206 U

0.00792

+/-0.0186

+/-0.0186 U

0.0167

+/-0.0509

+/-0.0509 U

-0.0485

+/-0.0647

+/-0.0647 U

-0.033

+/-0.0473

+/-0.0473 0.346

+/-0.0549

+/-0.0549 0.419

+/-0.0777

+/-0.0777 U

0.014

+/-0.0173

+/-0.0173 U

0.0089

+/-0.0158

+1-0.0158 7.61

+/-0.836

+/-0.836 0.448

+/-0.0781

+/-0.0781 U

-0.00782

+/-0.0162 pCi/g 6

pCi/g 36 pCi/g 6

pCi/g 16 pCi/g 208 pCi/g 827 pCi/g 36 (0%- 100%)

(0%- 100%)

(0%- 100%)

(0%o-100%)

(0%- 100%)

(0%- 100%)

(0%- 100%)

pCi/g 216 (0%-100%)

Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m pCilg 612 pCi/g 19 pCi/g 4

pCi/g 191 pCi/g 21 pCi/g 8

pCi/g 6

pCi/g 1360 (0%- 100%)

(0% - 100%)

(0%- 100%)

(0% - 100%)

(0%- 100%)

(0% - 20%)

(0%- 100%)

(0%- 100%)

55

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174936 Page 4 of 9 Parmname NOM Sample Qua]

QC Units RPD%

REC%

Range AnIst Date Time Rad Gamma Spec Batch 583389 e

Thallium-208 TPU:

+/-0.0134 0.107 Uncert:

+/-0.031 TPU:

+/-0.031

+/-0.0162 0.108

+/-0.036

+/-0.036 pCilg 2

(0%- 100%)

QC 1201217097 Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europi urt-154 Europiunv-155 LCS Uncert:

TPU:

23.4 Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

9.54 Uncert:

TPU:

14.2 Uncert:

TPU:

Uncert:

TPU:

U ncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

u 0.166

+/-0.579

+/-0.579 25.2

+/-1.33

+/-1.33 U

0.169

+/-0.989

+/-0.989 u

0.208

+/-0.235

+/-0.235 U

0.0196

+/-0.149

+/-0.149 10.1

+/-0.474

+/-0.474 14.4

+/-0.640

+/-0.640 U

-0.0221

+/-0.301

+/-0.301 U

-0.0891

+/-0.300

+/-0.300 U

0.246

+/-0.296

+/-0.296 U

0.0927

+/-0.160

+/-0.160 U

-0.0668

+/-0.216

+/-0.216 U

0.0637

+/-0.141

+/-0.141 U

-0.0941

+/-0.131

+/-0.131 U

0.512 pCilg pCi/g pCilg PCilg pCi/g pCi/g pCi/g pcilg pCilg

.pCi/g pCi/g PCilg pCilg pCi/g PCilg 10/31/06 10:56 108 (75%-125%)

106 (75%-125%)

101 (75%-125%)

Lead-212 Lead-214 Manganese-54 Niobium-94 Potassiurn-40 Uncert:

TPU:

Uncert:

TPU:

56

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www gel.com QC Summary Workorder:

174936 Page 5 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time Rad Gamma Spec Batch 583389 Radium-226 Silver-I08m Thalliumn-208 QC1201217095 Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium-I 34 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 MB Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

+/-I.01

+/- 1.01I U

0.208

+1-0.235

+/-0.235 U

0.00145

+/-0.116

+/-0.116 U

0.109

+/-0.124

+/-0.124 U

0.017

+1-0.0424

+/-0.0424 U

0.00734

+/-0.0106

+1-0.0106 U

0.000324

+/-0.0883

+/-0.0883 U

0.0233

+/-0.033

+/-0.033 UT 0.00

+/-0.0377

+/-0.0377 U

-0.00239

+/-0.0102

+/-0.0102 U

0.0115

+/-0.0112

+/-0.0112 U

-0.00208

+/-0.0274

+/-0.0274 U

0.0176

+/-0.030

+/-0.030 U

0.00314

+/-0.0186

+/-0.0186 U

0.0227

+/-0.0166

+/-0.0166 Ul 0.00

+/-0.0396

+/-0.0396 pCi/g pCi/g pCi/g pCi/g pCilg pCi/g pCi/g pCilg pCi/g PCilg pCi/g pCilg (75%-125%)

10/31/06 09:31 Lead-212 Lead-2I4 57

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - www.gel com QC Summary Workorder:

174936 Page 6 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anist Date Time kad Gamma Spec Batchh

.583389 e

Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 Rad Gas Flow Batch Uncert:

TPU:

Uncert:

. TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

Uncert:

TPU:

U

-0.00543

+/-0.0113

+/-0.0113 U

0.00493

+/-0.0109

+/-0.0109 U

0.356

+/-0.179

+/-0.179 U

0.0233

+/-0.033

+/-0.033 U

-0.00346

+/-0.00831

+/-0.00831.

U 0.0108

+/-0.0183

+/-0.0183 pCi/g pCi/g pCi/g pCilg pCi/g PCi/g 583243 QC1201216718 174936001 DUP Strontium-90 QC1201216720 LCS Strontium-90 QC1201216717 MB Strontium-90 QC1201216719 174936001 MS Strontium-90 Rad Liquid Scintillation Batch 583233 QC1201216690 174936001 DUP Technetium-99 QC1201216692 LCS Technetium-99 QC1201216689 MB Technetium-99 0.0263 Uncert:

+/-0.0109 TPU:

+/-0.011 1.64 Uncert:

TPU:

Uncert:

TPU:

5.18 Uncert:

TPU:

0.0557

+/-0.019

+/-0.019 1.34

+/-0.0863

+/-0.0946 0.0333

+/-0.0137

+/-0.0137 4.66

+/-0.304

+/-0.330 pCi/g 72 (0% - 100%) KSD1 PCi/g PCi/g pCi/g 82 (75%-125%)

11/02/06 09:35 11/02/06 09:35 11/02/06 09:35 11/02/06 09:35 0.0263

+/-0.0109

+/-0.011 89 (75%-125%)

U 0.320 Uncert:

+/-0.221 TPU:

+/-0.221 U

0.321

+/-0.291

+/-0.291 12.9

+1-0.501

+/-0.601 pCi/g 0

(0% - 100%) KXRI 13.0 Uncert:

TPU:

pCi/g 99 (75%-125%)

10/31/06 04:00 10/31/06 04:32 10/31/06 03:43 U

• 0.047 pCi/g 58

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Workorder:

174936 Parmname Rad Liquid Scintillation Batch 583233

. QC1201216691 174936001 MS Technetium-99 Batch 583234 QC1201216694 174936001 DUP Tritium QC1201216696 LCS Tritium QC1201216693 MB Tritium QCI201216695 174936001 MS Tritium Batch 583236 QC1201216702 174936001 DUP Carbon-14 QC1201216704 LCS Carbon-14 QC1201216701 MB Carbon-14 QC1201216703 174936001 MS Carbon-14 Batch 583239 QC1201216710 174936001 DUP Iron-55 QC1201216712 LCS Iron-55 QC Summary NOM Sample Qua]

QC Uncert:

+/-0.238 TPU:

+/-0.238 13.1 U

0.320 12.5 Uncert:

+/-0.221

+/-0.543 TPU:

+/-0.221

+/-0.631 U

3.72 U

-6.31 Uncert:

+/-5.94

+/-6.86 TPU:

+/-5.94

+/-6.86 51.5 45.3 Uncert:

+/-8.97 TPU:

+/-9.01 U

-0.82 Uncert:

+/-5.74 TPU:

+/-5.74 60.3 U

3.72 48.1 Uncert:

+/-5.94

+/-10.1 TPU:

+/-5.94

+/-10.1 U

0.179 U

0.0712 Uncert:

+/-0.112

+/-0.108 TPU:

+/-0:112

+/-0.108 6.78 6.63 Uncert:

+/-0.229 TPU:

+/-0.251 U

0.0836 Uncert:

+/-0.109 TPU:

+/-0.109 7.17 U

0.179 6.59 Uncert:

+/-0.112

+/-0.237 TPU:

+/-0.112

+/-0.258 U

14.2 U

-3.35 Uncert:

+/-19.7

+/-19.4 TPU:

+1-19.7

+/-19.4 57.2 54.5 Uncert:

+/-3.71 TPU:

+/-5.38 Page 7 of 9 Units RPD%

REC%

Ranpe Anist Date Time pCi/g 96 (75%-125%)

(0% - 100%) DFAI 88 (75%-125%)

pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCt/g pCi/g 0

80 (75%-125%)

10/31/06 04:16 10/28/06 08:10 10/28/06 08:42 10/28/06 07:54 10/28/06 08:26 10/28/06 01:06 10/28/06 02:40 10/28/06 00:19 10/28/06 01:53 11/01/06 19:15 11/01/06 19:47 0

(0% - 100%),XD2 98 (75%-125%)

92 (75%-125%)

0 (0% - 100%) VIXPI 95 (75%-125%)

59

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174936 Page 8 of 9 OC Units RPD %

REC%

Range Anist Parmname Rad Liquid Scintillation Batch

.583239 QC1 201216709 MB Iron-55 NOM Sample Oual Date Time QC1201216711 174936001 MS Iron-55 Uncert:

TPU:

611 U

Uncert:

TPU:

U

-0.337

+/-1.02

+/-1.02 pCi/g

• pCi/g 11/01/06 16951 11/01/06 19:31 14.2

+1-19.7

+/-19.7 Batch 583241 QC1201216714 Nickel-63 174936001 DUP U

-0.799 Uncert:

+/-7.83 TPU:

+/-7.83 U

593

+/-37.3

+/-58.7 0.571

+/-7.52

+/-7.52 160

+/-6.78

+/-8.10 pCi/g 0

(0% - 100%) V1XPI QC1201216716 LCS Nickel-63 QC1201216713 MB Nickel-63 QC1201216715 174936001 MS Nickel-63 97 (75%-125%)

179 Uncert:

TPU:

Uncert:

TPU:

535 U

Uncert:

TPU:

U 1.12

+/-2.38

+/-2.38 pCi/g pCi/g pCi/g 90 (75%-125%)

11/01/06 17:24 11/01/06 18:07 11/01/06 17:02 11/01/06 17:45

-0.799

+/-7.83

+/-7.83 448

+/-19.0

+/-24.7 84 (75%-125%)

Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A

The TIC is a suspected aldol-condensation product B

Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C

Analyte has been confirmed by GC/MS analysis D

Results are reported from a diluted aliquot of the sample H

Analytical holding time was exceeded 3

Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R

Sample results are rejected U

Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y

QC Samples were not spiked with this compound RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL 60

GENERAL ENGINEERING LABORATORIES, LLC 2040. Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder:

174936 Page 9 of 9 Parmname NOM Sample Qual QC Units RPD%

REC%

Range Anlst Date Time A

h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.

• • Indicates analyte is a surrogate compound.

^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.

For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.

61

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 4 (DQA RESULTS)

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 4A (PRELIMINARY DATA REVIEW)

PRELIMINARY DATA REVIEW FORM Survey Unit:

9520-0004 Survey Unit Name:

Southwest Site Storage area Classification :

I Survey Media:

Soil Type of Survey:

Final Status Survey Type of Measurement:

Radionuclide Specific lumber of Measurements :

15 BASIC.STATISTICAL QUANTITIES Cs-137 Target Level (pCi/g)

• 5.38E+00 Minimum Value:

-9.59E-03 Maximum Value:

1.20E-01 Mean 4.64E-02 Median :

4.11 E-02 Standard Deviation :

2.79E-02 Sample Identification 9520-0004-001F 9520-0004-002F 9520-0004-003F 9520-0004-004F 9520-0004-005F 9520-0004-006F 9520-0004-007F 9520-0004-008F 9520-0004-009F 9520-0004-01 OF 9520-0004-01 IF 9520-0004-012F 9520-0004-013F 9520-0004-014F 9520-0004-015F Reported Results Cs-137 Concentration (pCi/g) 3.19E-02 2.85E-02 3.94E-02 5.92E-02 3.15E-02

-9.59E-03 3.22E-02 5.20E-02 4.11 E-02 3.46E-02 5.69E-02 1.20E-01 7.37E-02 4.71 E-02 5.7 1E-02 Fraction of Target Detect?

Level 0.006

+

0.005

+

0.007

+

0.011

+

0.006

+

0.006

+

0.010

+

0.008

+

0.006

+

0.011

+

0.022

+

0.014

+

0.009

+

0.011 Submitted by/Date J 1o1 1 of 1

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 4B (GRAPHICAL REPRESENTATION OF DATA)

FREQUENCY PLOT FOR CESIUM-137 Survey Unit: 9520-0004 Survey Unit Name: Southwest Site Storage Area Mean: 4.64E-02 pCi/g Frequency Plot For Cs-137 C

LL 8

6 4

2 0

-9.59E-03 2,04E-02 5.04E-02 8.04E-02 1.10E-01 1.40E-01 Upper End Value (pCilg)

Upper End Observation Observation Value Frequency Frequency

-9.59E-03 1

7%

2.04,-02

• 0 0%

5.04E-02 8

53%

8.04E-02 5

33%

. 10E-01

• 0 0%

1.40E-01 1

7%

Total:

15 100%

J Submitted by/Date/

Reviewed by/Date 1 of 1

QUANTILE PLOT FOR CESIUM-137 Survey Unit:

9520-0004 Survey; Unit Name: Southwest Site Storage Area Mean:

4.64E-02 pCi/g Quantile Plot For Cs-137 1.40E-01 1.20E-01 1.O0E-01 C 8.OOE-02 0

6.OOE-02 0

U 0 4.00E-02 2.OOE-02 0.00E+00 I "

1~*

I U[-_

i i.....

.i.......

!* ~ l

..i m -.... *..

..........i

-i..

i

,N I,1

• M Iaia"

=

i 100 0

20 40 60 80 Percentage Cs-1 37 Rank Percentage

-9.59E-03 1

3%

2.85E-02 2

10%

3.15E.-02 3

17%

3.19E-02 4

23%

3.22_E-02 5

30%

3.46E-02.

6 37%

3.94E-02 7

43%

4.1. I.E-02 8

50%

4.71.E-02 9

57%

5.20E-02 10 63%

5.69E-02 11 70%

5.71E-02 12 77%

5.92E-02 "

3 83%

7.3)7E-02) 14 90%

1.2015-01 15 97%

~1*

Submitted by/Date Reviewed by/Date

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 4C (SIGN TEST)

Connecticut Yankee Decommissioning Project Health Physics Procedure GPP-GGGR-R5]121-001 Attachment A, Rev CY-001 MAJOR Sign Test Calculation Sheet For A Single Radionuclide or Gross Activity Measurements Survey Area Number: 9520.

Survey Unit Number: 0004 Survey Area Name: Southwest Site Storage Area WPIIR#: 2006-0038 Classification: I Type.I (ax error): 0.05 (N): 15 Radionuclide: Cs-137 DCGL: 5.38 Results (pCi/g)

DCGL - Results Sign 3.19E-02 5.35E+00 I

2.85E-02 5.35E+00 1

3.94E-02 5.34E+00 I

5.92E-02 5.32E+00 3.15E-02 5.35E+00 I

-9.59E-03 5.39E+00 3.22E-02 5.35E+00 I

5.20E-02 5.33E+00 1

4.11E-02 5.34E+00 1

3.46E-02 5.35E+00 I

5.69E-02 5.32E+00 I

1.20E-01 5.26E+00 7.37E-02 5.31E+00 1

4.71 E-02 5.33E+00 5.71E-02 5.32E+00 Number of positive differences (S+): 15 Critical Value: 11 Performed by:

~~c 6

-,11t 1-41 Independent Review b P

Survey Unit Meets Acceptance Criterion Date:

./

Date:

'l laO(

aie 1 of 1

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 4D (QC SPLIT RESULTS)

Health Physics Procedure 24265,-000-GPP-GGGR-R5124-000-Rev.CY-000 Attachment A Health Physics Procedure 24265-000-GPP-GGGR-R5 I 24-000-Rev.CY-000 Attachment A Split Sample Assessment Form Survey Area#: 9520 Survey Unit #: 0004 Survey Unit name: Southwest Site Storage Area Sample Plan or WPIR#: 2005-0038 SML#: 9520-0002-004 Sample

Description:

Comparison of split samples collected from sample measurement location #4 and analyzed using gamma spectroscopy by off-site Vendor Laboratory. The standard sample was 9520-0004-004F, the comparison sample was 9520-0004-004FS.

STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable Value Error Range Value Error Ratio (YIN)

K-40 12.0 4.22E-1 28 0.75-1.33 11.8 4.93E-1 0.98 Y

0.U~~lt,~O t.U I0

,,IV. +;

~

l.IO A

'NTJ+

t4

tJfLI, 3

0 1

V

'11it.I~p

+V

~i,U I

I Y

A +i.tit.

LI

+LII evaluate used to assess split samples.

Resolution 4-7 8-15 16 -50 51 -200

>200 Agreement Range 0.5 -2.0 0.6-1.66 0.75 - 1.33 0.80- 1.25 0.85 - 1.18 6-)

Page 1 of 1

Health Physics Procedure 24ý65-000-GPP-GGGR-R5]24-000-Rev.CY-000 Attachment A Health Physics Procedure 24265-000-GPP-GGGR-R5 I 24-000-Rev.CY-000 Attachment A Split Sample Assessment Form Survey Area#: 9520 Survey Unit #: 0004 Survey Unit name: Southwest Site Storage Area Sample Plan or WPIR#: 2005-0038 SML#: 9520-0004-012 Sample

Description:

Comparison of split samples collected from sample measurement location #12 and analyzed using gamma spectroscopy by off-site Vendor Laboratory. The standard sample was 9520-0004-012F, the comparison sample was 9520-0004,012FS.

STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison I Acceptable Value Error Range Value Error Ratio (YIN)

Cs-137 1.20E-1 1.I84E-.2 7

0.5-2.0 1.55E-1 2.36E-2 1.29 Y

+

+

+

+

4

+

+

+

+

+

+

+

+

+

+

+

+

+

4

+

+

Comments/Corrective Actions: N/A Table is provided to show acceptance criteria used to assess split samples.

Resolution 4-7 8 -15 16-50 51 -200

>200 Agreement Range 0.5 -2.0 0.6 - 1.66 0.75 - 1.33 0.80-1.25 0.85-1.18 Performed By:

Date e!v d

y Da :

/9oL Page 1 of I

SOUTHWEST SITE STORAGE AREA SURVEY UNIT 9520-0004 RELEASE RECORD ATTACHMENT 4E (COMPASS DQA WITH POWER CURVE)

S DQA Surface Soil Report Assessment Summary Site:

Planner(s}:

Survey Unit Name:

Report Number:

Survey Unit Samples:

Reference Area Samples:

Test Performed:

Judgmental Samples:

Assessment

Conclusion:

9520-0004 FSS McCarthy

.,\\J Southwest Site Storage Area 1

15 0

Sign Test Result:

Not Performed 0

EMC Result:

Not Performed Reject Null Hypothesis (Survey Unit PASSES)

Retrospective Power Curve Gt1 S0.9 0.8 0.7 0.6

(. 0.5 0.4 0.3 0.2 0.1

- 0 I I d 01 2

3 4

5 Soil Concentration (pCihg), including* *kground Prospective Power M

I-beta Actual Power LBGR

-= Estimated Power D(-GL Retrospective Power 11O912006 6

COMPASS vlý0.0 Page I