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On behalf of.STP, we are submitting the. enclosed permit renewal with major amendment application for the above referenced Texas Pollutant Discharge Elimination System (TPDES) permit. Enclosed you will find one original and three complete copies for your approval. | On behalf of.STP, we are submitting the. enclosed permit renewal with major amendment application for the above referenced Texas Pollutant Discharge Elimination System (TPDES) permit. Enclosed you will find one original and three complete copies for your approval. | ||
The application fee has.been submitted directly to the Financial Administration Division under separate cover, however, a copy of the fee submitta9l is presented in Attachment A.If you have any questions concerning this ýappl!tation, please contact me at 512-326-5859... We look forward to working with. you In prooessing this application. | The application fee has.been submitted directly to the Financial Administration Division under separate cover, however, a copy of the fee submitta9l is presented in Attachment A.If you have any questions concerning this ýappl!tation, please contact me at 512-326-5859... We look forward to working with. you In prooessing this application. | ||
Thank you for your consideration, Sincerely, Tres Koenings Senior Consultant I UnIted States IlCan~ada.l0razi I UK I.lIr~land I N~etherlands Austealla A.91a.Pbocflo I Rusela I Middle East I Africa Atnon ebir of RPS. Groulp P/C Attachment NOC-AE-14003142 Page 3 of 155 TABLE OF CONTENTS TCEQ Industrial Wastewater Permit Application TPDES Permit No. WQ0001908000 Submission Checklist Industrial Administrative Report 1.0 Industrial Administrative Report 1.1 Supplemental Permit Information Form Industrial Technical Report 1.0 Worksheet 1.0 EPA Effluent Guidelines Worksheet | Thank you for your consideration, Sincerely, Tres Koenings Senior Consultant I UnIted States IlCan~ada.l0razi I UK I.lIr~land I N~etherlands Austealla A.91a.Pbocflo I Rusela I Middle East I Africa Atnon ebir of RPS. Groulp P/C Attachment NOC-AE-14003142 Page 3 of 155 TABLE OF CONTENTS TCEQ Industrial Wastewater Permit Application TPDES Permit No. WQ0001908000 Submission Checklist Industrial Administrative Report 1.0 Industrial Administrative Report 1.1 Supplemental Permit Information Form Industrial Technical Report 1.0 Worksheet 1.0 EPA Effluent Guidelines Worksheet 2.0 Pollutant Analyses Requirements Worksheet 4.0 Receiving Waters Worksheet 5.0 Sewage Sludge Management and Disposal Worksheet 7.0 Storm Water Runoff Attachment A Copy of Application Fee (Submission Checklist, Pg.. 1)Attachment B USGS Map (Admin Report 1.0 -8.m., Pg. 12)Attachment C Affected Landowners (Admin Report 1.1 -l.a. & b., Pg. 15)Attachment D Original Photographs (Admin Report 1.1- 2., Pg. 12)Attachment E USGS Map (SPIF, Item 8)Attachment F Wastewater Generating Process (Tech Report 1.0 1 .c., Pg. 1)Attachment G Facility Plot Plan (Tech Report 1.0 -I.e., Pg. 2)Attachment H Flow Schematic Diagrams (Tech Report 1.0 -2.b., Pg. 3)Attachment I Water Treatment Chemicals (Tech Report 1.0 -5.c., Pg. 8)Attachment J Requested Permit Amendments (Admin Report 1.0, Pg. 1; Tech Report 1.0 -12., Pg. 11)Attachment K Treatment System (Tech Report, Item 2. a., Pg. 3)J:\Projects\STP Nuclear\Application\STP Nuclear Amendment with Renewal Application~doc Attachment NOC-AE-14003142 Page 4 of 155 Submission Checklist Attachment NOC-AE-14003142 Page 5 of 155 TEXAS COMMISSION ON ENVIRONMENTAL QUALITY TCEQ INDUSTRIAL WASTEWATER PERMIT APPLICATION INDUSTRIAL ADMINISTRATiVE REPORT Submit this checklist with the application. | ||
Analyses Requirements Worksheet | |||
Waters Worksheet | |||
Sludge Management and Disposal Worksheet | |||
Water Runoff Attachment A Copy of Application Fee (Submission Checklist, Pg.. 1)Attachment B USGS Map (Admin Report 1.0 -8.m., Pg. 12)Attachment C Affected Landowners (Admin Report 1.1 -l.a. & b., Pg. 15)Attachment D Original Photographs (Admin Report 1.1- 2., Pg. 12)Attachment E USGS Map (SPIF, Item 8)Attachment F Wastewater Generating Process (Tech Report 1.0 1 .c., Pg. 1)Attachment G Facility Plot Plan (Tech Report 1.0 -I.e., Pg. 2)Attachment H Flow Schematic Diagrams (Tech Report 1.0 -2.b., Pg. 3)Attachment I Water Treatment Chemicals (Tech Report 1.0 -5.c., Pg. 8)Attachment J Requested Permit Amendments (Admin Report 1.0, Pg. 1; Tech Report 1.0 -12., Pg. 11)Attachment K Treatment System (Tech Report, Item 2. a., Pg. 3)J:\Projects\STP Nuclear\Application\STP Nuclear Amendment with Renewal Application~doc Attachment NOC-AE-14003142 Page 4 of 155 Submission Checklist Attachment NOC-AE-14003142 Page 5 of 155 TEXAS COMMISSION ON ENVIRONMENTAL QUALITY TCEQ INDUSTRIAL WASTEWATER PERMIT APPLICATION INDUSTRIAL ADMINISTRATiVE REPORT Submit this checklist with the application. | |||
Do not submit the instructions with the application. | Do not submit the instructions with the application. | ||
Indicate if thefollowing are included in the application. | Indicate if thefollowing are included in the application. | ||
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X~~l6S M6~d eaire~dw fpo See Flow diagrams, Attachment H to~V1fen e- 9ti~K~ "p.-t t nea pg4~ .r S Process E .PA Guidleline Date Process/PIart Subp .art Construction. | X~~l6S M6~d eaire~dw fpo See Flow diagrams, Attachment H to~V1fen e- 9ti~K~ "p.-t t nea pg4~ .r S Process E .PA Guidleline Date Process/PIart Subp .art Construction. | ||
P. olmmenced Units I and 2 423 N/A 1975 Units 3 and 4 423. N/A Near future TCEQ-1 0055 (05116/2012) | P. olmmenced Units I and 2 423 N/A 1975 Units 3 and 4 423. N/A Near future TCEQ-1 0055 (05116/2012) | ||
Industrial Wastewater Permit Application Technical Report Page 14 of 66 Attachment NOC-AE-14003142 Page 46 of 155 Worksheet | Industrial Wastewater Permit Application Technical Report Page 14 of 66 Attachment NOC-AE-14003142 Page 46 of 155 Worksheet 2.0 Pollutant Analyses Requirements Attachment NOC-AE-14003142 Page 47 of 155 Worksheet 2.0 Notes and Additional Information Outfall 001: There has not been a discharge from Outfall 001 since 1997, therefore, the required effluent samples for the application could not be collected. | ||
Analyses Requirements Attachment NOC-AE-14003142 Page 47 of 155 Worksheet | |||
and Additional Information Outfall 001: There has not been a discharge from Outfall 001 since 1997, therefore, the required effluent samples for the application could not be collected. | |||
STP will collect the required samples for the application upon the next available discharge via Outfall 001 and submit the results to the TCEQ for review.Outfalls 002-006: Effluent data is currently being collected by the facility for these outfalls. | STP will collect the required samples for the application upon the next available discharge via Outfall 001 and submit the results to the TCEQ for review.Outfalls 002-006: Effluent data is currently being collected by the facility for these outfalls. | ||
The sample result will be submitted at a later date under separate cover. | The sample result will be submitted at a later date under separate cover. | ||
Attachment NOC-AE-14003142 Page 48 of 155 WORKSHEET | Attachment NOC-AE-14003142 Page 48 of 155 WORKSHEET 2.0 POLLUTANT ANALYSES REQUIREMENTS | ||
ANALYSES REQUIREMENTS | |||
* there has not been a discharge via Outfall 001 since 1997.REQUIRED FOR APPLICATIONS SUBMITTED FOR A TPDES PERMIT. NOT REQUIRED FOR APPLICATIONS FOR A PERMIT TO DISPOSE OF ALL WASTEWATER BY LAND DISPOSAL OR FOR DISCHARGES SOLELY OF STORM-WATER RUNOFF. (General Requirements: | * there has not been a discharge via Outfall 001 since 1997.REQUIRED FOR APPLICATIONS SUBMITTED FOR A TPDES PERMIT. NOT REQUIRED FOR APPLICATIONS FOR A PERMIT TO DISPOSE OF ALL WASTEWATER BY LAND DISPOSAL OR FOR DISCHARGES SOLELY OF STORM-WATER RUNOFF. (General Requirements: | ||
Instructions, Pages 49-51)!Outfall LD IC G 0 .. (tc6n e tain( gl.: | Instructions, Pages 49-51)!Outfall LD IC G 0 .. (tc6n e tain( gl.: | ||
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E] Yes [Z No If yes, provide the appropriate testing results."CEQ-10056 (05115/2012) | E] Yes [Z No If yes, provide the appropriate testing results."CEQ-10056 (05115/2012) | ||
Industrial Wastewater Permit Application Technical Report Page 18 of 66 Attachment NOC-AE-14003142 Page 52 of 155 D ; EX ... :, ý.tr f-.' 01)OIitfall No.ý ZCE ~ ~ f~ihQfoMaln4I | Industrial Wastewater Permit Application Technical Report Page 18 of 66 Attachment NOC-AE-14003142 Page 52 of 155 D ; EX ... :, ý.tr f-.' 01)OIitfall No.ý ZCE ~ ~ f~ihQfoMaln4I | ||
*) A Pdltht.', Saffib.rI SaMp. 2; Ship. 3 Sanip. 4.A:. ' (091I)'Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D 10 Danitol 4,4-DDD 0.1 4,4'-DDE 0.1 4,4'-DDT 0.1 Demeton 0.2 Diazlnon 0.6 Dloofol 20 Dieldrin 0.1 Diuron 0.09 Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate 0.1 Endrln 0.1 Gamma -Hexachlorocyolohexane (Lindane) 0,05 Guthlon 0.10 Heptachlor 0.05 Heptachlor Epoxide 1,0 Hexachlorophene 10 Malathlon 0.10 Methoxychlor | *) A Pdltht.', Saffib.rI SaMp. 2; Ship. 3 Sanip. 4.A:. ' (091I)'Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D 10 Danitol 4,4-DDD 0.1 4,4'-DDE 0.1 4,4'-DDT 0.1 Demeton 0.2 Diazlnon 0.6 Dloofol 20 Dieldrin 0.1 Diuron 0.09 Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate 0.1 Endrln 0.1 Gamma -Hexachlorocyolohexane (Lindane) 0,05 Guthlon 0.10 Heptachlor 0.05 Heptachlor Epoxide 1,0 Hexachlorophene 10 Malathlon 0.10 Methoxychlor 2.0 Mirex 0.2 Parathion 0.1 Toxaphene 5 2,4,5-TP (SIlvex) 2* Indicate trnits if different from mg/L.TCEQ-10055 (05/15/2012) | ||
0.2 Parathion | |||
5 2,4,5-TP (SIlvex) 2* Indicate trnits if different from mg/L.TCEQ-10055 (05/15/2012) | |||
Industrial Wastewater Permit Application Technical Report Page 19 of 66 Attachment NOC-AE-14003142 Page 53 of 155 Complete table required for all external outfalls. | Industrial Wastewater Permit Application Technical Report Page 19 of 66 Attachment NOC-AE-14003142 Page 53 of 155 Complete table required for all external outfalls. | ||
Not required for internal outfalls.(Instructions, Page 52)OUtfaII No' : nC oiG B616eIIVd b'ICOGn-, , Verage Mtaxlrimum NOf oSafibe§Bromide Color(PCU) | Not required for internal outfalls.(Instructions, Page 52)OUtfaII No' : nC oiG B616eIIVd b'ICOGn-, , Verage Mtaxlrimum NOf oSafibe§Bromide Color(PCU) | ||
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CAS-N_________d_________ | CAS-N_________d_________ | ||
1- 4 4-I 4- 4 4 t .4- 4 .4 I *4-* .4 4-t +/- 4 +TCEQ-1 0055 (05/1512012) | 1- 4 4-I 4- 4 4 t .4- 4 .4 I *4-* .4 4-t +/- 4 +TCEQ-1 0055 (05/1512012) | ||
Industrial Wastewater Permit Application Technical Report Page 26 of 66 Attachment NOC-AE-14003142 Page 60 of 155 Worksheet | Industrial Wastewater Permit Application Technical Report Page 26 of 66 Attachment NOC-AE-14003142 Page 60 of 155 Worksheet 4.0 Receiving Waters Attachment NOC-AE-14003142 Page 61 of 155 WORKSHEET 4.0 RECEIVING WATERS THE FOLLOWING IS REQUIRED FOR ALL TPDES PERMIT APPLICATIONS Is t here a surface water intake for domestic drinking water supply I ocated within 5 (five) miles downstream from the point/proposed point of discharge? | ||
Waters Attachment NOC-AE-14003142 Page 61 of 155 WORKSHEET | |||
WATERS THE FOLLOWING IS REQUIRED FOR ALL TPDES PERMIT APPLICATIONS Is t here a surface water intake for domestic drinking water supply I ocated within 5 (five) miles downstream from the point/proposed point of discharge? | |||
ElYes WNo If yes, identify owner of the drinking water supply, the distance and direction to the Intake, and locate and identify the intake on the USGS map. Indicate by a check mark that the requested information is provided: | ElYes WNo If yes, identify owner of the drinking water supply, the distance and direction to the Intake, and locate and identify the intake on the USGS map. Indicate by a check mark that the requested information is provided: | ||
D]a. Width of the receiving water at the outfall? ~300 feet b. Are there oyster reefs in the vicinity of the discharge? | D]a. Width of the receiving water at the outfall? ~300 feet b. Are there oyster reefs in the vicinity of the discharge? | ||
Line 492: | Line 452: | ||
water clarity discolored Li Common Setting: not offensive, developed but uncluttered; water may be colored or turbid Li Offensive: | water clarity discolored Li Common Setting: not offensive, developed but uncluttered; water may be colored or turbid Li Offensive: | ||
stream does not enhance aesthetics; cluttered; highly developed; dumping areas; water discolored TCEQ-10055 (0511512012) | stream does not enhance aesthetics; cluttered; highly developed; dumping areas; water discolored TCEQ-10055 (0511512012) | ||
Industrial Wastewater Permit Application Technical Report Page 41 of 66 Attachment NOC-AE-14003142 Page 64 of 155 Worksheet | Industrial Wastewater Permit Application Technical Report Page 41 of 66 Attachment NOC-AE-14003142 Page 64 of 155 Worksheet 5.0 Sewage Sludge Management and Disposal Attachment NOC-AE-14003142 Page 65 of 155 WORKSHEET 5.o SEWAGE SLUDGE MANAGEMENT AND DISPOSAL THE FO ILOWING I S R EQUIRED FO R A LL T PDES PER MIT A PPLICATIONS THAT M EET T HE CONDITIONS AS OUTLINED I N T ECHNICAL REPORT 1.o, ITEM NO. 7.a. Is this a new permit application or an amendment permit application? | ||
Sludge Management and Disposal Attachment NOC-AE-14003142 Page 65 of 155 WORKSHEET 5.o SEWAGE SLUDGE MANAGEMENT AND DISPOSAL THE FO ILOWING I S R EQUIRED FO R A LL T PDES PER MIT A PPLICATIONS THAT M EET T HE CONDITIONS AS OUTLINED I N T ECHNICAL REPORT 1.o, ITEM NO. 7.a. Is this a new permit application or an amendment permit application? | |||
0 Yes E] No *The amendment requests will not change the sludge handling process at the facility.b. Does the facility discharge in the Lake Houston watershed? | 0 Yes E] No *The amendment requests will not change the sludge handling process at the facility.b. Does the facility discharge in the Lake Houston watershed? | ||
R Yes 0 No If yes to either item a or b, Indicate by a check mark that a solids management plan was provided with the application. | R Yes 0 No If yes to either item a or b, Indicate by a check mark that a solids management plan was provided with the application. | ||
Line 502: | Line 459: | ||
: d. If the existing permit contains authorization for sludge land application, composting, marketing and distribution of sludge, and/or sludge lagoons and authorization t o renew t he activity is being s ought in t he application, t he appropriate s ections o f t he Sludge Technical Report must be provided.TCEQ-1 0055 (05/15/2012) | : d. If the existing permit contains authorization for sludge land application, composting, marketing and distribution of sludge, and/or sludge lagoons and authorization t o renew t he activity is being s ought in t he application, t he appropriate s ections o f t he Sludge Technical Report must be provided.TCEQ-1 0055 (05/15/2012) | ||
Industrial Wastewater Permit Application Technical Report Page 45 of 66 Attachment NOC-AE-14003142 Page 66 of 155~~Ag S WJouA xMo S ~TD'GEPR'S-SOSAL A hcio '4s,7a~5~Are you requesting new authorization to beneficially land apply sewage sludge at this site or a site under your direct control?Mi Yes 0 No Are you requesting new authorization to market and distribute sewage sludge at this facility or a facility under your direct control?[] Yes W1 No Are you requesting new authorization to compost sewage sludge?[D1 Yes IZ No Are you requesting new authorization to surface dispose sewage sludge at this site or site under your direct control?M Yes IZ No Are you requesting new authorization t o in cinerate sewage sludge at t his site o r site under your direct control?ElYes WZINo If yes to any of the above it ems, provide the information required in the S LUDGE TECHNICAL REPORT.New authorization for beneficial land application, incineration, and sludge lagoons in the TPDES or TLAP permits requires a major a mendmentto t he p ermit. New authorization for composting may require a major amendment to the permit. See the instructions for an explanation whether a major amendment Is required or if authorization for composting can be added through the renewal process.TCEQ-1 0055 (05/15/2012) | Industrial Wastewater Permit Application Technical Report Page 45 of 66 Attachment NOC-AE-14003142 Page 66 of 155~~Ag S WJouA xMo S ~TD'GEPR'S-SOSAL A hcio '4s,7a~5~Are you requesting new authorization to beneficially land apply sewage sludge at this site or a site under your direct control?Mi Yes 0 No Are you requesting new authorization to market and distribute sewage sludge at this facility or a facility under your direct control?[] Yes W1 No Are you requesting new authorization to compost sewage sludge?[D1 Yes IZ No Are you requesting new authorization to surface dispose sewage sludge at this site or site under your direct control?M Yes IZ No Are you requesting new authorization t o in cinerate sewage sludge at t his site o r site under your direct control?ElYes WZINo If yes to any of the above it ems, provide the information required in the S LUDGE TECHNICAL REPORT.New authorization for beneficial land application, incineration, and sludge lagoons in the TPDES or TLAP permits requires a major a mendmentto t he p ermit. New authorization for composting may require a major amendment to the permit. See the instructions for an explanation whether a major amendment Is required or if authorization for composting can be added through the renewal process.TCEQ-1 0055 (05/15/2012) | ||
Industrial Wastewater Permit Application Technical Report Page 46 of 66 Attachment NOC-AE-14003142 Page 67 of 155 Worksheet | Industrial Wastewater Permit Application Technical Report Page 46 of 66 Attachment NOC-AE-14003142 Page 67 of 155 Worksheet 7.0 Storm Water Runoff Attachment NOC-AE-14003142 Page 68 of 155 WORICSHEET 7.0 STORMWATER RUNOFF WORIKSHEET REQUIRED FOR ALL TPDES PERMIT APPLICATIONS APPLYING FOR INDIVIDUAL PERMIT COVERAGE FOR DISCHARGES OF STORM WATER RUNOFF.1. Do discharges from a ny of the p roposed or e xisting outfalls consist of stormw ater runoff only o r s tormwater runoff and any of the l isted n on-stormwater discharges?(See Instructions, Page 79)W-Yes IZINo If yes, proceed as directed. | ||
Water Runoff Attachment NOC-AE-14003142 Page 68 of 155 WORICSHEET | |||
RUNOFF WORIKSHEET REQUIRED FOR ALL TPDES PERMIT APPLICATIONS APPLYING FOR INDIVIDUAL PERMIT COVERAGE FOR DISCHARGES OF STORM WATER RUNOFF.1. Do discharges from a ny of the p roposed or e xisting outfalls consist of stormw ater runoff only o r s tormwater runoff and any of the l isted n on-stormwater discharges?(See Instructions, Page 79)W-Yes IZINo If yes, proceed as directed. | |||
If no, stop here.2. Indicate by a check mark which type of authorization covers or is proposed to cover discharges from each stormwater outfall. (See Instructions, Page 79)outfallI coverage Coverqag U'nde .r oulI coverbkoe coverage Under-UdrMGP Indiv"idual. | If no, stop here.2. Indicate by a check mark which type of authorization covers or is proposed to cover discharges from each stormwater outfall. (See Instructions, Page 79)outfallI coverage Coverqag U'nde .r oulI coverbkoe coverage Under-UdrMGP Indiv"idual. | ||
Permit utar Under MSGI' In'dividual Pelrnitý | Permit utar Under MSGI' In'dividual Pelrnitý | ||
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OUTFALL 601 DIGESTER Aerobic Digestion I. to Main Cooling Reservoir sludge tolandfill SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC | OUTFALL 601 DIGESTER Aerobic Digestion I. to Main Cooling Reservoir sludge tolandfill SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC | ||
-OUTFALL 601 DRAWN RY: SD LSON SCALE: PROJ. 2014TPDES CHECKED BY: T KOEINGS So.. batb scar FILE NO. STNFl, FIS-ll,.E,. | -OUTFALL 601 DRAWN RY: SD LSON SCALE: PROJ. 2014TPDES CHECKED BY: T KOEINGS So.. batb scar FILE NO. STNFl, FIS-ll,.E,. | ||
APPROVED RY: -DATE PR1NTE: DATE: 0. 201"TA IML AI 20 a Attachment NOC-AE-14003142 Page 107 of 155 Attachment I Water Treatment Chemicals Tech Report 1.0- 5.c., Pg. 8 Attachment NOC-AE-14003142 Page 108 of 155 Treatment Chemicals Product Manufacturer Use Components Listed in CAS Frequency of Toxicity Product Name MSDS Use Data Concentration In MSDS Sodium ypolorite 7681 3 times per day LiquichSor Univar :Biocidt for 20 minutes to Yes 0.15-0.6 ppm total 1310e73- unit's cooling residual chlorine Sodium Hydroxide 2 water Sodium nitrite 7632 As needed to 0.25 oz per gallon of 1359 Plus Nalco Corrosion inhibitor 0 maintain No closed cooling system 7775-19-Sodium nictaborate concentration water 1 19H Nalco Oxygen scavenger Hydrazine 302-011-2 Continuous Yes 0.1 ppm to feedwater Sodium Nitrite 7632 As needed to LCS-60 Nalco Corrosion inhibitor 0 maintain No 500-1500 ppm sodium Sodium Tetraborate 1330 concentration nitrite concentration | APPROVED RY: -DATE PR1NTE: DATE: 0. 201"TA IML AI 20 a Attachment NOC-AE-14003142 Page 107 of 155 Attachment I Water Treatment Chemicals Tech Report 1.0- 5.c., Pg. 8 Attachment NOC-AE-14003142 Page 108 of 155 Treatment Chemicals Product Manufacturer Use Components Listed in CAS Frequency of Toxicity Product Name MSDS Use Data Concentration In MSDS Sodium ypolorite 7681 3 times per day LiquichSor Univar :Biocidt for 20 minutes to Yes 0.15-0.6 ppm total 1310e73- unit's cooling residual chlorine Sodium Hydroxide 2 water Sodium nitrite 7632 As needed to 0.25 oz per gallon of 1359 Plus Nalco Corrosion inhibitor 0 maintain No closed cooling system 7775-19-Sodium nictaborate concentration water 1 19H Nalco Oxygen scavenger Hydrazine 302-011-2 Continuous Yes 0.1 ppm to feedwater Sodium Nitrite 7632 As needed to LCS-60 Nalco Corrosion inhibitor 0 maintain No 500-1500 ppm sodium Sodium Tetraborate 1330 concentration nitrite concentration 4.1 Scale Polyacrylic Acid N/A Continuous 935cNlcoNo 0.25 ppm federate as inhibitor/dispersant product 3 times per day ACTI-BROM Nalco Biocide Sodium bromide 7647 for 20 minutes to Yes 0.15-0.6 ppm total.131.8 6 unit's cooling residual chlorine water B-2200 Varichem. | ||
Polyacrylic Acid N/A Continuous 935cNlcoNo 0.25 ppm federate as inhibitor/dispersant product 3 times per day ACTI-BROM Nalco Biocide Sodium bromide 7647 for 20 minutes to Yes 0.15-0.6 ppm total.131.8 6 unit's cooling residual chlorine water B-2200 Varichem. | |||
Algaecide Ethyl Alcohol 64-17-S Batch treated as No 5 ppm needed B-2206 Varichem Biocide Broimochloro-5.5-N/A Continuous No 0.5-2 ppm diniethylydantoin Scale and SC-23 10 Varichen coaroaiondinibitor None listed N/A Continuous No 80-120 ppm Attachment NOC-AE-14003142 Page 109 of 155 Didecyl-Dimethyl-7173 4 ppm as product (2.5 H-130M Nalco Biocide Ammonium chloride 52/Yr. Yes ppm. as active) to aux.Ethanol 64-17-5 cooling system for 8-hours twice per year.Magnesium Salt N/A 2-Methyl-4-Isothiazolin 2682 Batch treated as 77352NA Nalco Isothiazolin one 4 needed Yes 300 ppm 5-Chloro-2-Methyl 26172-_ 1 _sothiazolin-3-one 55-4 _ 1 Attachment NOC-AE-14003142 Page 110 of 155 UnIVAR@Univar USA Inc Material Safety Data Sheet MSDS No: Version No: 010 2014-03-18 Order No; I ZI Univar USA Inc., 17425 NE Union Hill Rd., Redmond WA 98052 (425) 889 3400 Emergency Assistance For emergency assistance involving chemicals call Chemtrec -(800) 424-9300 Attachment NOC-AE-14003142 Page 111 of 155 UNIVAR USA INC.ISSUE DATE:2011-12-21 Annotation: | Algaecide Ethyl Alcohol 64-17-S Batch treated as No 5 ppm needed B-2206 Varichem Biocide Broimochloro-5.5-N/A Continuous No 0.5-2 ppm diniethylydantoin Scale and SC-23 10 Varichen coaroaiondinibitor None listed N/A Continuous No 80-120 ppm Attachment NOC-AE-14003142 Page 109 of 155 Didecyl-Dimethyl-7173 4 ppm as product (2.5 H-130M Nalco Biocide Ammonium chloride 52/Yr. Yes ppm. as active) to aux.Ethanol 64-17-5 cooling system for 8-hours twice per year.Magnesium Salt N/A 2-Methyl-4-Isothiazolin 2682 Batch treated as 77352NA Nalco Isothiazolin one 4 needed Yes 300 ppm 5-Chloro-2-Methyl 26172-_ 1 _sothiazolin-3-one 55-4 _ 1 Attachment NOC-AE-14003142 Page 110 of 155 UnIVAR@Univar USA Inc Material Safety Data Sheet MSDS No: Version No: 010 2014-03-18 Order No; I ZI Univar USA Inc., 17425 NE Union Hill Rd., Redmond WA 98052 (425) 889 3400 Emergency Assistance For emergency assistance involving chemicals call Chemtrec -(800) 424-9300 Attachment NOC-AE-14003142 Page 111 of 155 UNIVAR USA INC.ISSUE DATE:2011-12-21 Annotation: | ||
MSDS NO:OX76685 VERSION:010 2014-03-18 COMPANY IDENTITY: | MSDS NO:OX76685 VERSION:010 2014-03-18 COMPANY IDENTITY: |
Revision as of 11:44, 11 May 2019
ML14168A268 | |
Person / Time | |
---|---|
Site: | South Texas ![]() |
Issue date: | 05/01/2014 |
From: | RPS Group Plc, South Texas |
To: | Office of Nuclear Reactor Regulation |
Shared Package | |
ML14168A266 | List: |
References | |
Download: ML14168A268 (153) | |
Text
Attachment NOC-AE-14003142 Page 1 of 155 4180 Delaware Street, Ste 402, Beaumont, Texas 77706, USA T +1 409 838 4400 F +1 409 838 9056 W www.rpsgroup.com Texas Pollutant Discharge Elimination System Major Amendment with Renewal Application for a Major Facility TPDES Permit No. WQ0001908000 Prepared For: STP Nuclear Operating.
Company South Texas Project Electric Generating Station Bay City, Texas May 2014 (.United States I Canada I Brazil I UK I Ireland I Netherlands Australia Asia Pacific I Russia I Middle East I Africa Attachment NOC-AE-14003142 Page 2 of 155 41A0 Delaware Street, Ste 402', BeauMont, Texas 77706, USA T +1 40.9 838 4400. P 4.1 ,409 938 9056 W www,rpsgroup.com May 29, 2014 Executive Director Applications Review and Processing.Team (MC148)Texas Commission on Environmental OLrIality 12100 Park 35 Circle Austin, TX 78753 MAY 2 9 2014 vi~Erf' QUALITy DIVISION RE: ApplicatIon for the Renewal with Major Amendment of TPDES Permit No.WQ000.1908000 South: Texas Project Nuclear Operating Company (STP)
Dear Sir:
On behalf of.STP, we are submitting the. enclosed permit renewal with major amendment application for the above referenced Texas Pollutant Discharge Elimination System (TPDES) permit. Enclosed you will find one original and three complete copies for your approval.
The application fee has.been submitted directly to the Financial Administration Division under separate cover, however, a copy of the fee submitta9l is presented in Attachment A.If you have any questions concerning this ýappl!tation, please contact me at 512-326-5859... We look forward to working with. you In prooessing this application.
Thank you for your consideration, Sincerely, Tres Koenings Senior Consultant I UnIted States IlCan~ada.l0razi I UK I.lIr~land I N~etherlands Austealla A.91a.Pbocflo I Rusela I Middle East I Africa Atnon ebir of RPS. Groulp P/C Attachment NOC-AE-14003142 Page 3 of 155 TABLE OF CONTENTS TCEQ Industrial Wastewater Permit Application TPDES Permit No. WQ0001908000 Submission Checklist Industrial Administrative Report 1.0 Industrial Administrative Report 1.1 Supplemental Permit Information Form Industrial Technical Report 1.0 Worksheet 1.0 EPA Effluent Guidelines Worksheet 2.0 Pollutant Analyses Requirements Worksheet 4.0 Receiving Waters Worksheet 5.0 Sewage Sludge Management and Disposal Worksheet 7.0 Storm Water Runoff Attachment A Copy of Application Fee (Submission Checklist, Pg.. 1)Attachment B USGS Map (Admin Report 1.0 -8.m., Pg. 12)Attachment C Affected Landowners (Admin Report 1.1 -l.a. & b., Pg. 15)Attachment D Original Photographs (Admin Report 1.1- 2., Pg. 12)Attachment E USGS Map (SPIF, Item 8)Attachment F Wastewater Generating Process (Tech Report 1.0 1 .c., Pg. 1)Attachment G Facility Plot Plan (Tech Report 1.0 -I.e., Pg. 2)Attachment H Flow Schematic Diagrams (Tech Report 1.0 -2.b., Pg. 3)Attachment I Water Treatment Chemicals (Tech Report 1.0 -5.c., Pg. 8)Attachment J Requested Permit Amendments (Admin Report 1.0, Pg. 1; Tech Report 1.0 -12., Pg. 11)Attachment K Treatment System (Tech Report, Item 2. a., Pg. 3)J:\Projects\STP Nuclear\Application\STP Nuclear Amendment with Renewal Application~doc Attachment NOC-AE-14003142 Page 4 of 155 Submission Checklist Attachment NOC-AE-14003142 Page 5 of 155 TEXAS COMMISSION ON ENVIRONMENTAL QUALITY TCEQ INDUSTRIAL WASTEWATER PERMIT APPLICATION INDUSTRIAL ADMINISTRATiVE REPORT Submit this checklist with the application.
Do not submit the instructions with the application.
Indicate if thefollowing are included in the application.
Applicant STP Nuclear Operating Company Permit Number WQ0001 908000 Administrative Report 1.o W Worksheet 7.0 W E Administrative Report 1.1 F7f JF Worksheet 8.0 F71 -SPIF i [7] Worksheet 9.o 17 Li Technical Report 1.0 .Worksheet 0o.o0] [Worksheet 1.o OF] .original USGS Map El Worksheet 2.0 -[-I. Affected Landowners Map .-Worksheet 3.0 EL i:Y Landowner Disk or Labels , -] I1 Worksheet 3.1 1- [] Copy of Application Fee Check. V 01 Worksheet3.2 F-/ " All fees owed TCEQ are paid Z DI Worksheet 3.3 [] [] Flow Diagram Worksheet 4.0 [ , _ Site Drawing Worksheet 4.11 Original Photographs
.._Worksheet 5.0 i _, Solids Management Plan FE] I Worksheet 6.0 ].- L2] Water Balance 0J rV tted for the application fee: See Attachment A Please indicate by a check mark the amount submi-ajoo elld...: ".:...or&med. ..Mnor.PA dassificatori New Rwieid ond Withut.Qnl
/-M 0d.Minor facility not subject to categorical standards
____$350 -___$350 ____$315 -___$150 promulgated by the EPA (40 CFR Part 4oo-471)Minor facility subject to categorical standards
____$1,250
-___$1250
____$12-15
____$150 promulgated by the EPA (40 CFR Part 400-471) ______Major facility N/A * ..$2,050
__ _$2-,015 -$450'~All facilities are designated as minors until formally classified as a major by EPA.-For C~fifimissioim Use 'Only-Se.ge'nieit Nunbr:bt:, ICuny § prtlnDte:_______
Troposed/Currentlr I'emt N~ub&': __________ei I TCEQ-1 0411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 1 of 18 Attachment NOC-AE-14003142 Page 6 of 155 Industrial Administrative Report 1.0 Attachment NOC-AE-14003142 Page 7 of 155 INDUSTRIAL ADMINISTRATIE REPORT 1.O The following is requiredfor all applications--Renewal, New, And Amendment Type of application:
B NewTPDES j NewTLAP Major amendment with Renewal Major Amendment without Renewal' Renewal of existing permit EJ Stormwater only discharge M Minor amendment to permit 0 Minor modification to permit If applying for an amendment to a permit, please describe the request in detail. See Attachment J-The applicant Is requesting the removal of effluent limitations and monitoring requirements for Outfalls 002-006, Relief Well Monitoring Ouffalls.-The applicant Is requesting the removal of pH monitoring requirements at Internal Outfalls 101, 201, and 501.a. Facility Owner (Owner of the facility must apply for the permit.)What is the Legal Name of the entity (applicant) applying for this permit?STP Nuclear Operating Company (The legal name must be spelled exactly as filed with the Texas Secretary of State, County, or in the legal document forming the entity.)If the applicant is currently a customer with TCEQ, what is the Customer Number (CN)? Search for your CN at: http:/!wwwV2.tceq.texas.gov/crpub/index.cfm?fuseaction=cust.CustSearch CN601658669 What is the name and title of the person signing the application?(The person must be an executive official meeting signatory requirements in TAC 305.43(a).)
Prefix (Mr. Ms, Miss): Mr.First/Last Name: Michael P. Murray Suffix: Title: Manager, Regulatory Affairs Credential:
What is the applicant's mailing address as recognized by the US Postal Service?You may verify the address at: http://zip4.usps.com/zip4/welcome.Isp Organization Name: STP Nuclear Operating Company Mailing Address: P.O. Box 289 Internal Routing (Mail Code, Etc.): N6016 City: Wadsworth State: Xx ZIP Code: 77483 Mailing Information if outside USA Territory:
Country Code: Postal Code: Phone No.: (361) 072-8164 Extension:_
Fax No.: E-mail Address: TCEQ-10411 (911/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 2 of 18 Attachment NOC-AE-14003142 Page 8 of 155 Indicate the type of Customer:[ Individual
[ Limited Partnership
[ Trust[ Federal Government C County Government C Other Government El Sole Proprietorship-D.B.A.
El Corporation C3 Estate El State Government Cj City Government ED Other: Independent entity E Yes E] No (If governmental entity; subsidiary, or part of a larger coiporation)
Number of Empio es: E0-20; [ 21-100;o 101-250;Lj 251-500; or 7 501 or higher Customer Business Tax and Filing Numbers (Not applicable to individuals, governments, general partnerships or sole proprietors.
REQUIRED for corporations and limited partnerships)
State Franchise Tax ID Number: 1-76-0517597-9 TX SOS Charter (filing) Number: 1459553-01 Federal Tax ID: DUNS Number (if known): b. Co-Permittee information (complete only if the operator must be a co-permittee)
What is the Legal Name of the entity (operator) applying for this permit?Operator N/A (The legal name must be spelled exactly as filed with the Texas Secretary of State, County, or in the legal document forming the entity.)If the operator is currently a customer with TCEQ, what is the Customer Number (CN)? Search for your CN at: http://www12.tceq.texas.gov/crpub/index.cfm?fLiseaction=cust.CustSearch CN.What is the name and title of the person signing the application?(The person must be an executive official meeting signatory requirements in TAC 305.43(a).)
Prefix (Mr. Ms, Miss): First/Last Name: Suffix: Title: Credential:
What is the applicant's mailing address as recognized by the US Postal Service?You may verify the address at: http: //zip4.usps.com/zip4/welcome.jsD TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 3 of `18 Attachment NOC-AE-14003142 Page 9 of 155 Organization Name: Mailing Address: Internal Routing (Mail Code, Etc.):__City: State: ZIP Code: Mailing Information if outside USA Territory:
Country Code: _Postal Code., Phone No.: ____ Extension:
Fax No., E-mail Address: Indicate the type of Customer: E] Individual
[ Sole Proprietorship-D.B.A.
El Limited Partnership D Corporation l Trust t Estate D Federal Government E State GovernmentCounty Government fl City GovernmentOther Government l Other: Independent entity 0 Yes E3 No (If governmental entity, subsidiary, or part of a larger corporation)
Number of Employees:
0-20;21-100; E 101-250; 0 251-500; or E 501 or higher Customer Business Tax and Filing Numbers (Not applicable to individuals, governments, general partnerships or sole proprietors.
REQUIRED for corporations and limited partnerships)
State Franchise Tax ID Number: TX SOS Charter (filing) Number: Federal Tax ID: DUNS Number (if known): Provide a brief description of the need for a co-permittee:
TCEQ-10411.
(9/1/2010)
Industrial Wastewater Permit Application -Administrative Report Page 4 of 18 Attachment NOC-AE-14003142 Page 10 of 155 c. Individual information (complete only if thefacility owner or co-permittee is an individual)
What is the Legal Name of the owner/co-permittee applying for this permit?N/A If the owner/co-permittee is currently a customer with TCEQ, what is the Customer Number (CN)? Search for your CN at: http:!/wwwl2.tceg.texas.gov/crpub/index.cfm?fuseaction=cust.CustSearch CN What is the name and title of the person signing the application?(The person must be the individual.
See signatoly requirements in TAC 305.43(a).)
Prefix (Mr. Ms, Miss):.First/Last Name: Suffix: State Identification Number: Date of Birth: Assumed business or professional name: Business name: What is the applicant's mailing address as recognized by the US Postal Service?You may verify the address at: http://zip4.usps.com/ziP4/welcome.'sm Mailing Address: Internal Routing (Mail Code, Etc.): City: State: TX ZIP Code:.Mailing Information if outside USA Territory:
Country Code: _Postal Code: Phone No.: Extension:
Fax No.: E-mail Address: a. Billing Contact and Address Information The permittee is responsible for paying the annual fee. The annual fee will be assessed to permits active on September 1 of each year. TCEQ will send a bill to the address provided in this section. The permittee is responsible for terminating the permit when it is no longer needed.Is the billing address the same as the permittee or co-permittee?
E] Permittee
[ Co-permittee l No, fill out this section Prefix (Mr, Ms, Miss): Mr.First/Last Name: John Hoffman Suffix: Title: Staff Environmental Consultant Credential:_
Organization Name: STP Nuclear Operating Company Billing Mailing Address: P.O. Box 289 TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 6 of 18 Attachment NOC-AE-14003142 Page 11 of 155 Internal Routing (Mail Code, Etc.): N2019 City: Wadsworth State: TX ZIP Code: 77483 Mailing Information if outside USA.Territory:.
Country Code: Postal Code: Phone No.: (361) 972-4507 Extension:
Fax No.: E-mail Address: jphoffman@stpegs.eom If TCEQ needs additional information regarding this application, who should be contacted?
- a. Application Contact Prefix (Mr. Ms, Miss): Mr.First/Last Name: John Hoffman Suffix: Title: Staff Environmental Consultant Credential:
Organization Name: STP Nuclear Operating Company Mailing Address: P.O. Box 289 Internal Routing (Mail Code, Etc.): N201 9 City: Wadsworth State: TX ZIP Code: 77483 Mailing Information if outside USA.Territory:
Country Code: Postal Code: Phone No.: (361) 972-4507 Extension:
Fax No.: E-mail Address: Jphoffman@stpegs.com Check one or both: F Administrative contact n/ Technical Contact b. Application Contact Prefix (Mr. Ms, Miss): Mr.First/Last Name: Tres Koenings Suffix: Title:. Senior Consultant Credential:
Organization Name: RPS Mailing Address: 4801 Southwest Parkway, Parkway 2, Suite 150 Internal Routing (Mail Code, Etc.): City: Austin State: TX ZIP Code: 78735 Mailing Information if outside USA.Territory:
Country Code: Postal Code: Phone No.: (512) 326-56L9 Extension:
Fax No.: E-mail Address: tres.koenlngs@rpsgroup.com Check one or both: : F Administrative contact 0 Technical Contact TCEQ-1 0411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 6 of 18 Attachment NOC-AE-14003142 Page 12 of 155% '?. .. ........ ',¢
........ i": '='.; " i"... "......."...
..... ..... ....... ... .... .... .. ... .....-,'ii:
~ Contact Responsible for Discharge Monitoring Reports (EPA 3320-1) Provide the name of the person and their complete mailing address delegated to receive and submit Discharge Monitoring Report Forms.Prefix (Mr. Ms, Miss): Mr.First/Last Name: John Hoffman Suffix: Title: Staff Environmental Consultant Credential:
Organization Name:, STP Nuclear Operating Company Mailing Address: pKo. Box 289 Internal Routing (Mail Code, Etc.): N2019 City: Wadsworth State: TX ZIP Code: 77843 Mailing Information if outside USA.Territory:
Country Code: Postal Code: Phone No.: (361) 972-4507 Extension:
Fax No. E-mail Addre-ss jphoffman stpegs.com letl-zb Did you know you can submit DMR data on line?Go to Sign up now at: https: /!www6.tceq.texas.gov/steers/
Establish an electronic reporting account when you get your permit number.Provide two names of individuals that can be contacted throughout the permit term.Prefix (Mr. Ms, Miss): Mr.First/Last Name: John Hoffman Q, , ATIA4 ."UXLAA, Title: Staff Environmental Consultant Credei Organization Name: STP Nuclear Operating Company Mailing Add'ess: P.O. Box 289 Internal Routing (Mail Code, Etc.): N2019 City: Wadsworth State: TX ZIP Code: 77843 Mailing Information if outside USA.Territory:
Country Code: Postal Code: Phone No.: (361) 972-4507 Extension:
Fax No.: E-mail Address: Jphoffman@stpegs.com TCEQ-10411 (911/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 7 of 18 Attachment NOC-AE-14003142 Page 13 of 155 Prefix (Mr. Ms, Miss): Ms.First/Last Name: P.L. Travis Suffix: Title: Environmental Supervisor Credential:
Organization Name: STP Nuclear Operating Company Mailing Address: P.O. Box 289 Internal Routing (Mail Code, Etc.): N2019 City: Wadsworth State: TX ZIP Code: 77843 Mailing Information if outside USA.Territory:
Country Code: Postal Code: Phone No.: (361) 972-8573 Extension:
Fax No.: E-mail Address: pltravls@stpegs.com
- a. Individual publishing the notices Prefix (Mr. Ms, Miss): Mr.First/Last Name: John Hoffman Suffix: Title: Staff Environmental Consultant Credential:__
Organization Name: STP Nuclear Operating Company Mailing Address: P.O. Box 289 Internal Routing (Mail Code, Etc.): N2019 City: Wadsworth .State: TX ZIP Code: 77843 Mailing Information if outside USA.Territory:
Country Code: Postal Code:_Phone No.: (361) 972-4507 Extension:
Fax No.: E-mail Address: jphoffman@stpegscom
- b. Method for receiving Notice of Receipt and Intent to Obtain a Water Quality Permit Package Indicate by a check mark the preferred method for receiving the first notice and instructions:
[21 E-mail Address: Jphoffman@stpegs.com
[] Fax No.: El Overnight/Priority mail: (self addressed, prepaid envelope required)[] Regular Mail: Mailing Address: Internal Routing (Mail Code, Etc.):_City: State: TX ZIP Code: c. Contact in the Notice TCEQ-10411 (911/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 8 of 18 Attachment NOC-AE-14003142 Page 14 of 155 Prefix (Mr. Ms, Miss): Mr.First/Last Name: John Hoffman Suffix: Title: Staff Environmental Consultant Credential:
Organization Name: STP Nuclear Operating Company Phone No.: (361) 972-4507 Extension:
- d. Public Place Information If thefacility and/or outfall are located in more than one county, a public viewing place for each county must be provided.Public Building name: Matagorda County Courthouse Location within the building:
County Clerks Office Physical address of building:
1700 7th Street City: Bay City County: Matagorda Contact Name: Janet Hlckl Phone No.: (970) 244-7680 Extension:
- e. Bilingual Notice Requirements:
For new permit, major amendment and renewal applications.
Not applicable for minor amendment or minor modification applications.
Please call the bllingual/ESL coordinator at the nearest elementary and middle schools and obtain the following Information to determine if an alternative language notice is required: 1. Is a bilingual education program required by the Texas Education Code at the nearest elementary or middle school to the facility or proposed facility?n- Yes nN No (If No, alternative language notice publication is not required; skip to item 7. SITE INFORMATION.)
- 2. Are the students who attend either the elementary school or the middle school enrolled in a bilingual education program at that school?0 Yes [3 No 3. Do the students at these schools attend a bilingual education program at another location?0 Yes [] No 4. Would the school be required to provide a bilingual education program but the school has waived out of this requirement under 19 TAC §89.1205(g)?
[7 Yes 0 No 5. If the answer is yes to 1, 2, 3, or 4, public notice in an alternative language is required.
Which language is required by the bilingual program?This section of the application is only used to determine if alternative language notice will be needed. Complete instructions on publishing the alternative language notice will be in your public notice package.TCEQ-1 0411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 9 of 18 Attachment NOC-AE-14003142 Page 15 of 155 If the site of your business is part of a larger business site, a Regulated Entity Number (RN) may already be assigned for the larger sitt. Use the RN assigned for the larger site. Search TCEQ's Central Registry to see if the larger site may already be registered as a regulated site at: http: //wwwl2.tceeq.texas.gov/crpub/index.cfm?ftseaction=regent.RNSearch If the site is found, provide the assigned Regulated Entity Reference Number and provide the information for the site to be authorized through this application below.The site information for this authorization may vary from the larger site information.
TCEQ issued RE Reference Number (RN): RN 102395654 a. State/TPDES Permit No.: WQ0001908000 Expiration date: 12/01/2014 EPA Identification No. (TPDES Permits only): TX 0 0 6 4 9 4 7 b. Name of project or site (the name kmown by the community where located): South Texas Project Electric Generating Station c. Is the facility located in Bexar Comal Hays, Kinney, Medina, Travis, Uvalde, or Williamson County? l Yes lNo (If Yes, additional Information concerning protection of the Edwards Aquifer may be required.)
- d. Is the location of the facility used in the existing permit correct? ED Yes ONo e. Does the site have a physical address?If Yes, complete Section A for a physical address.If No (the location description is not accurate or this is a new permit application, complete), complete Section B for site location information.
Se~ction, A; E addre~s for thg~le, :' ,,: -,. ' - Verify the address with USPS. If the address is not recognized as a delivery address, provide the address as identified for overnight mail delivery, 911 emergencies, or other online map tool to confirm an address.Physical Address of Project or Site: Street Number: 12090 Street Name: Farm-to-Market Road 521 City: Wadsworth ZIP Code: 77483 Seck~ns~ ute t e ri~-~cto iomatln, If no physical address (Street Number & Street Name), provide a written location access description to the site: I (Ex.: located 2 miles west from intersection of Hwy 29o & IH35 accessible on Hwy 29o South)TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 10 of 18 Attachment NOC-AE-14003142 Page 16 of 155 f. City where the site is located or, if not in a city, what is the nearest city: Wadsworth g. ZIP Code where the site is located: 77483 h. County where the site is located Matagorda i. Latitude:
28' 47' 50" N Longitude:
96' 03' 10" W j. In your own words, briefly describe the primary business of the Regulated Entity: (Do not repeat the SIC and NAICS code)FSteam Electric Generating Facility k. Owner of treatment facility:
STP Nuclear Operating Company Ownership of Facility:
E Public 1-/ Private ] Both lZLFederal
- 1. Owner of land where treatment facility is/will be: STP Nuclear Operating Company (If not the same as the facility owner, there must be a long term lease agreement in effect for at least six years. In some cases, a lease may not suffice -see instructions.)
- m. Owner of effluent disposal site: N/A (If not the same as the facility owner, there must be a long term lease agreement in effect for at least six years.)n. Owner of sewage sludge disposal site: N/A (Required only If authorization is sought in the permit for sludge disposal on property owned/controlled by the applicant.)
- a. Is the point of discharge and discharge route in the existing permit correct?V1 Yes 0 No If no, or a new or amendment permit application, please give an accurate description.
N/A b. City or Town in which the outfall(s) is or will be located Near Bay City c. County the outfall(s) is located: Matagorda d. Ogtfate atitud 001:280 44' 48"N Longitude:
001: 960 00' 02"W eee-low foredditional outfalls, e. For all applications involving an average daily discharge of 5 million gallons per day or more, provide the names of all counties located within loo statute miles downstream of the point(s) of discharge.
N/A*Oultfall 002: 28°46'29"N 950 59' 53" W; Outfall 003: 28°44'49"N 96 0 00'40"W; Outfall 004:28"44'57"N 96001'03";
Outfall 005: 28 0 44'32"N 96 0 02'42"W; Outfall 006: 28 0 44'31"N 96 0 03'36"W TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 11 of 18 Attachment NOC-AE-14003142 Page 17 of 155 f. If a TLAP, is the location of the effluent disposal site in the existing permit accurate?[ Yes Eu No If no, or a new or amendment permit application, please give an accurate description.
N/A g. City or Town in which the disposal site is or willbe located N/A h. County the disposal site is located: N/A i. Disposal Site Latitude:
N/A Longitude:
N/A j. If a TLAP, describe the routing of effluent from the treatment facility to the effluent disposal site: N/A k. For TLAP applications please identify the nearest watercourse to the disposal site to which rainfall runoff might flow if not contained:
N/A 1. Is the location of the sewage sludge disposal site in the existing permit accurate?-Yes r No If no, or a new permit application, please give an accurate description.
N/A m. Provide an original full size USGS Topographic Map with all required information.
Indicate by a check mark that the information is provided.
See Attachment B j Applicant's property boundary D Treatment facility boundaries nN Labeled point of discharge and highlighted discharge route[-] Sewage sludge disposal site-] Effluent disposal site boundaries
[j New and future construction on i mile radius and 3 miles downstream information V All ponds n. Is/will the treated wastewater discharge to a city, county, or state highway right-of-way, or a flood control district drainage ditch? LI Yes [] No If Yes, indicate by a check mark if: N/A[- Authorization granted [I Authorization pending (For new and amendments, provide copies of letters that show proof of contact and the approval letter upon receipt.)TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application -Administrative Report Page 12 of 18 Attachment NOC-AE-14003142 Page 18 of 155 o. Is the facility located on or does the treated effluent cross American Indian Land?DYes MY No a. List each person formerly employed by the TCEQ who represented your company and was paid for service regarding the application:
Tres Koenings, Jamie Saladiner b. Do you owe fees to the TCEQ? EL Yes 70 No If yes, please provide: Account number: Amount past due: c. Do you owe any penalties to the TCEQ? F] Yes [] No If yes, please provide: Enforcement order number Amount past due TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 13 of 18 Attachment NOC-AE-14003142 Page 19 of 155 Permit Number: WQ0001908000 Applicant; STP Nuclear Operating Company Certification:
I, Michael P. Murray Manager, Regulatory Affairs Typed or printed name Title certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.
Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete.
I am aware there are significant penalties for submitting false information, including thepossibility of fine and imprisonment for knowing violations.
I further certify that I am authorized under 30 Texas Administrative Code §305.44 to sign and submit this document, and can provide documentation in proof'of such authorization upon request.Signature:
Date: 2 (Use l"e k)Subscribed and Sworn to before me by the said- ýA c\ c\ \ Ctu on this dayof ,20 o2 My commission expires on the LAh- day of I ,2o )WL\ ~ [SEAL]Notary Public County, Texas tf co-permittees are necessary, each entity must submit an original, separate signature page.TCEQ-1041 i (9/1/2010)
Industrial Wastewater Permit Application -Administrative Report Page 14 of 18 Attachment NOC-AE-14003142 Page 20 of 155 Industrial Administrative Report 1.1 Attachment NOC-AE-14003142 Page 21 of 155 INDUSTRIAL ADMINISTRATIVE REPORT 1.1 The following is requir'edfor new and amendment applications.
See Attachment C a. Indicate by a check mark that the landowners map or drawing, with scale, includes the following, as applicable.
[A The applicant's property boundaries
[El The facility site boundaries within the applicant's property boundaries FD The distance the buffer zone falls into adjacent properties and the property boundaries of the landowners located within the buffer zone[E The property boundaries of all landowners surrounding the applicant's property[ The point(s) of discharge and highlighted discharge route clearly shown for one mile downstream
- The property boundaries of the landowners located on both sides of the discharge route for one full stream mile downstream of the point of discharge[E The property boundaries of the landowners along the watercourse for a one-half mile radius from the point of discharge if the point of discharge is into a lake, bay estuary, or affected by tides F The boundaries of the effluent disposal site (for example, irrigation area or subsurface drainfield site), all evaporation/holding ponds within the applicant's property El The property boundaries of all landowners surrounding the applicant's property boundaries where the effluent disposal site is located El The boundaries of the sludge land application site (for land application of sewage sludge for beneficial use) and the property boundaries of landowners surrounding the applicant's property boundaries where the sewage sludge land application site is located E The property boundaries of landowners within one-half mile in all directions from the applicant's property boundaries where the sewage sludge disposal site (for example, sludge surface disposal site or sludge monofill) is located b. Indicate by a check mark in which format the landowners list is submitted:
[N Read/Writeable CD or Disk [-l 4 sets of labels c. Indicate by a check mark that a separate list with the landowners' names and mailing address cross-referenced to the landowners map has been provided.
[E d. Provide the source of the landowners' names and mailing addresses.
Matagorda County Appraisal District, 2014 Parcel Boundary & 2013 Tax Roll TCEQ-1 0411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 15 of 18 Attachment NOC-AE-14003142 Page 22 of 155 c. As required by Texas Water Code §5.115, is any permanent school fund land affected by this application?
[] Yes [] No If yes, provide the location and foreseeable impacts and effects this application has on the land(s)..... ..~ ~ ~ ~ ~~ ~ ~~~ ~~~...... ......:
.i.?! `Provide original ground level photographs.
Indicate by checking that the following information is provided.
See Attachment D El At least one original photograph of the new or expanded treatment unit location[ At least two photographs of the existing/proposed point of discharge and as much area downstream (photo i) and upstream (photo 2) as can be captured.F- If the discharge is to an open water body (e.g., lake, bay), the point of discharge should be in the right or left edge of each photograph showing the open water and with as much area on each respective side of the discharge as can be captured, El At least one photograph of the existing/proposed effluent disposal site AJ A plot plan or map showing the location and direction of each photograph TCEQ-1 0411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 16 of IS Attachment NOC-AE-14003142 Page 23 of 155 Supplemental Permit Information Form Attachment NOC-AE-14003142 Page 24 of 155 TEXAS COMMISSION ON ENVIRONMENTAL QUALITY SUPPLEMENTAL PERMIT INFORMATION FORM (SPIF)FOR AGENCIES REVIEWING INDUSTRIAL TPDES WASTEWATER PERMIT APPLICATIONS T-CJQ VSE ONLY: -APPlieat~i6n~type., 'iiRenewal Majot Amnendment Minor Amendrtient -New cýOtnty:_
Segment Number -_Admin Com~plete Date:_______
Agency Receiving SPIV:___Texas H-istorical commfns~ion-US Fish and WAildlife This form applies to TPDES permit applications only. (Instructions, Page 34)The SPIF must be completed as a separate document.
The TCEQ will mail a copy of the SPIF to each agency as required by the TCEQ agreement with EPA. If any of the items are not completely addressed and/or further information is needed, you will be contacted to provide the information before the permit Is issued. Each item must be completely addressed.
Do not refer to a response of any item in the permit application form. Each attachment must be provided with this form separately from the administrative report of the application.
The application will not be declared administratively complete without this form being completed in its entirety including all attachments.
The following applies to all applications:
- 1. Permlttee:
STP Nuclear Operating Company 2. Permit No. WQoo 0 1 9 0 8 0 0 0 (EPA ID No.) TX 0 0 6 4 9 4 7 3. Address of the project (location description that includes street/highway, ity/vicinity, & county)12090 Farm-to-Market Road 521, Wadsworth, Texas 77483 4. Provide the name, address, phone and fax number of an individual that can be contacted to answer specific questions about the property.Name: John Hoffman Company: STP Nuclear Operating Company Phone number: (361) 972-4507 Fax number: Street No.: Street name: Street type: P.O. Box, 289 City: Wadsworth State: TX ZIP code: 7 7 4 8 3 Email: jphoffman@stpegs.com TCEQ-10411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 17 of 18 Attachment NOC-AE-14003142 Page 25 of 155 5. List the county in which the facility is located:.Matagorda
- 6. If the property is publicly owned and the owner is different than the permittee/applicant, please list the owner of the property.N/A 7. Provide a description of the effluent discharge route. The discharge route must follow the flow of effluent from the point of discharge to the nearest major watercourse (from the point of discharge to a classified segment as defined in 30 TAC Chapter 307). If known, please identify the Segment Number.L 'a Ot directh, lo Co0oraao Rlver t12al; via M2e tome Plant.area Drainage Dto, then tO'Coorado Tidal; via 002 to an unnamed oitch, loe n 1 an unnamed trbutar of West Branh of Colorado River, then to West Branch of Colorado River, then to Mategorda Bay/Powderhomr Lake: via 004 to en unnamed ditch then to Colorado RiverI Tidal In Segment No. 1401 of Colorado River Baon; via 005 to East Fork Little RobbinaSlough, then to Robbins Slough, then to Robbins Lake, than to Robbins Slough, I then to Crab Lake, then to Crab Bayou, then to Gulf Intercoastal Waterway, then to Metagorda Bay/Powderhorn Lake; and via 006 to Little Robbing Slough, then to an-'M O _ H.. .. .... ....... ...... .... .. ...to m- .. ..i '. W ks.
- to In ' .'.. ...I .' , ...ft e Intercoastal Waterway, .hen to Matagorda Bey/Powderhom Lka In Segment No. 2451 of theBays and vatuarles 8. Please provide a separate 7.5 minute USGS quadrangle map with the project boundaries plotted and a general location map showing the project area. Please highlight the discharge route from the point of discharge for a distance of one mile downstream. (This map is required in addition to the map in the administrative report). See Attachment E 9. Provide original photographs of any structures 50 years or older on the property.io. Does your project involve any of the following?
Check all that apply.n] a. Proposed access roads, utility lines, construction easements D1 b. Visual effects that could damage or detract from a historic property's integrity H c. Vibration effects during construction or as a result of project design d. Additional phases of development that are planned for the future e. Sealing caves, fractures, sinkholes, other karst features f. Disturbance of vegetation or wetlands ii. List proposed construction impact (surface acres to be impacted, depth of excavation, sealing of caves, or other karst features).
- 12. Describe existing disturbances, vegetation and land use.THIE FOLLO;W.-NG ITEMS-` POPLYO L QAPI'IN O E TPES PEIIMTTSý AD MAJOQ"-R ;AMENDMENTS TO PDE 1MfS 13. List construction dates of all buildings and structures on the property..NN/A 14. Provide a brief history of the property, and name of the architect/builder, if known.TCEQ-1 0411 (9/1/2010)
Industrial Wastewater Permit Application
-Administrative Report Page 18 of 18 Attachment NOC-AE-14003142 Page 26 of 155 Industrial Technical Report 1.0 (
Attachment NOC-AE-14003142 Page 27 of 155 TECHNICAL REPORT 1.o INDUSTRIAL THE FOLLOWING IS REQUIRED FOR ALL APPLICATIONS RENEWAL, NEW, AND AMENDMENT a. Describe the type of activity and general nature of your business.South Texas (STP) Electric Generating Station is a nuclear fueled, steam-electric generating facility.
Electricity is generated from steam driven turbines.b. SIC Code(s) 4911 , , NAICS Code(s) 221113 , , c. Describe the wastewater generating processes.
See Attachment F d. Provide a list of raw materials, major intermediates, and products handled at your facility.Raw Materials Intermediate Products Final Products Nuclear Fuel (7440-61-1)
Steam Electricity TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page I of 66 Attachment NOC-AE-14003142 Page 28 of 155 e. Indicate by a check mark that an attached facility map with the following information was provided with the application:
[1 Production areas, maintenance areas, materials handling areas, and waste disposal areas.[71 The location of each unit of the wastewater treatment plant including the location of wastewater collection sumps and impoundments.
Attachment
- G f. Is this a new permit application for an existing facility?If yes, provide background discussion below.ED Yes IZ No N/A g. Is the treatment facility/disposal site located above the 1oo-year frequency flood level?fZYes F No List source(s) used to determine 1oo-year frequency flood plain: FIRM 485489037C, March 18, 1985 If no, provide the elevation of the 1o0-year frequency flood plain and describe what protective measures are in use or planned to be used to prevent flooding of the treatment facility/disposal area.N/A h. For new or amendment permit applications, will there be discharge of fill material into a water in the state for construction of the proposed outfall structure?
El Yes W1 No If no, proceed to Item No. 2. If yes, has the a plicant applied for a U.S. Corps of Engineers 404 Dredge and Fill permit? [_Yes LI No If yes, provide the permit number: If no, provide the approximate date you anticipate submitting your application to the Corps.TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 2 of 66 Attachment NOC-AE-14003142 Page 29 of 155 a. List any physical, chemical, an/or biological treatment process that y ou use f or the treatm ent of wastewater at your facility.
Include a description of each treatment process starting with initial treatment and finishing with the discharge point.See Attachment K b. [] Indicate by a check mark t hat an attached flow schematic with a water balance was provided with the applications showing each treatment unit and all sources of wastewater flow into the treatment plant and to each outfall/point of disposal.Attachment
- H Do you use or plan to use any wastewater lagoons, ponds, or impoundments 71 YesR No If yes, complete item 3(a) for existing impoundments and items 3(a)-3(t) for new or proposed impoundments.
If no, proceed to Item No. 4.a. Provide the following information in the table provided: Dcsignation:
Indicate t he appropriate u se designation for each p ond [ Treatment (T), Disposal (D), Containment (C), or Evaporation (E)]Discharge Point: If a discharge occurs from the Impoundments, designate the outfall associated with the impoundment.
Liner I nformation:
If the impoundments are lined to comply with specifications outlined for t) a c ompacted clay liner (C), 2) an in-situ clay l iner (I), or 3) a synthetic/plastic/rubber liner (S), indicate the liner type with the appropriate letter designation (see instructions for further detail on liner specifications).
If not, provide a reference to the attachment that provides a description of the alternate liner and any additional technical information necessary for an evaluation.
Dimensions:
Provide t he dimensions(s), f reeboard, surface area, an d storage volume capacity of the impoundments.
For impoundments with irregular shapes, submit surface area (instead of length an d width), the average depth, an d the maximum depth b elow natural ground level.TCEQ-1 0055 (0511612012)
Industrial Wastewater Permit Application Technical Report Page 3 of 66 Attachment NOC-AE-14003142 Page 30 of 155 Pond# 1 Pond# 2 Pond J Pond# 4 Pond# 6 Designation (T) (D) (C) or (E) T T T T Discharge Point j.Outfall Number 501 501 101 001 none Liner Information Liner Type (C) (I) or (S) reinforce concrete reinforce concrete reinforce concrete soil and concrete none Alt. Liner Attachment Reference n/a n/a n/a n/a n/a Dimensions Length (feet) 100 ft 25 ft 136 ft .nia ft 150,ft Width (feet) 5o0 ft 25 ft 42 ft n/a ft 70 ft Depth from Water Surface 17.5 ft 13.3 ft 10 ft 20 ft 4 ft Depth from Nat. Ground Level .avg 0 max o avg oymax o2avg omax __o avg. o max 0 avg -2Lmax Freeboard (feet) '0 ft >2 ft >2 ft 2, ft '2 ft Surface Area (acres) o.io acres O.Ol acres 0.13 acres 7,000 acres 024 acres Storage Capacity (gallons) 1,000.000 gal 50,000 gal 600,000 gal " 6.6e0 gal 31.4,160 gal Pond # P_ ond# Pond# Pond## Pond#-Designation (T) (D) (C) or (E) C Discharge Point Outfall Number None Liner Informati-on-Liner Type (C) (I) or (S) soil and concrete Alt. Liner Attachment Reference n/a Dimensions Length (feet) .ft Width (feet) .1,0oo ft .ft _ .ft ft ft Depth from Water Surface 8 ft ft ft _ ft ft Depth from Nat. Ground Level (avg/max) (feet) 0 .0 I .I .Freeboard (feet) '2 ft ft _ _ft _ ft ft Surface Area (acres) 47 acres acres _ acres 'acres .acres Storage Capacity (gallons) 1.3ea gal gal _ gal _ .gal _ gal TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 4 of 66 Attachment NOC-AE-14003142 Page 31 of 155 THE FO LLOWING I TEMS A RE R EQUIRED 0 NLY FO R N EW 0 R PR OPOSED IMPOUNDMENTS.
- b. Indicate by a check mark if any of the following data was provided with the application:
Li Synthetic/plastic/rubber liner data LI In-situ clay liner data Not Applicable Attachment
- _c. Are there any leak detection systems or ground water monitoring wells in place or planned? Li Yes ni No Not Applicable Li If yes, indicate by a check mark that a separate attachment was provided with the leak detection system information for each pond and/or gr ound water monitoring well data.Attachment
- d. Is t he b ottom of the p ond a bove t he s easonal high water t able in t he shallowest water bearing zone?Li Yes Li No Not Applicable Li If no, indicate by a check m ark that additional information was provided describing the depth of the seasonal high water table in the shallowest water bearing zone in relation to the depth of the bottom of the new or proposed impoundment and how this may or may not impact groundwater.
- e. Indicate by a check mark that the following information was provided:
Not Applicable L] A USGS quadrangle map or a color copy of original quality and scale which accurately locates and identifies water supply wells and/or monitor wells within 1/2 mile radius of the impoundments.
Li Copies of State Water Well Reports (driller's logs, completion data), and data on depths to g round water for water supply w ells in cluding a d escription o f how t he d epths t o ground water were obtained.For TLAP permit applications:
Not Applicable Li Indicate by a check mark t hat t he new or proposed impoundment(s) and the land application disposal area are located in the same general area and the information for this item is provided in Worksheet 3.0 (item 8).Not Applicable
- f. i- Indicate by a check mark id any data was provided with the application pertaining to the ground water, soils, geology, etc. used to assess the potential for migration of wastes from the impoundments and/or the potential for contamination of ground water or surface water.Complete the following tables to describe the location and wastewater discharge or disposal operations for each outfall for discharge operations and for each point of disposal for TLAP operations.
For TLAP permit applications:
Indicate the disposal method and each individual lirigation area (i), evaporation pond ( E), or subsurface drainage system (S) by providing the appropriate letter designation for the disposal method followed by a numerical designation for each disposal area (e.g. evaporation pond, application area) in the space provided for "Outfall" designation e.g. "E'" for ev oration pond 1 "12" for irrigation area No. 2, etc.).TCEO-. 0055 (05A/517012)
Industrial Wasttegater Permit Application Technical Report Page of 66 Attachment NOC-AE-14003142 Page 32 of 155 OUTFALL: 001-Latitude .' -Longitude*-
Location Des.riptloh 8 44 96 00 .02 At a point in the blowdown line prior to entering the(MGD) Pirposed Fl",op(MD), Colorado River Dly Avg Dly MaVix. Dly Avg, -fy 3 3/4 1schar ge; I.tration 144 200 144 200 ** (hrs./day)
- (days/mo.)
- _(mo./year)
X PumpedGravlty Measurement Device: Estimate X Intermittent
_ Seasonal Continuous
,:.: *:..h..... ting W4te0trAfis:-
6 -Volme (MOD) Oz/f to'ta low Recirculated cooling water n/a** n/a**Cooling reservoir blowdown Previously monitored effluent Stormwater Makeup water from the Colorado River Uncontaminated groundwater
- At spillway.
At blowdown at the river: 28' 44' 46" N, 96' 00' 02" W"*There has been no discharge from the outfall since March 4, 1997 OUTFALL: 002 La- tte Ul.et :. Location Doscription
, 468I 29 95 II 59 II 53 Prior to entering the plant drainage ditch Pemte PoG) Proposed, IIW o.(M.Gb)Pi vg Dy Max IJyAg. -D~Ma se t harge burat onj n/a n/a n/a n/a n/a (hrs./day)
!la (days/mo.)
/a (nmo./year)
Pumped _L Gravity Measurement Device: estimate X Intermittent -Seasonal
_ Continuous Reservoir relief well effluent (wells 1-125) Intermittent Demlneralized water from instrumentation Intermittent
.., ..-t *11*p *.11.TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 6 of 66 Attachment NOC-AE-14003142 Page 33 of 155 OUTFALL: 003 Latituide'.
Longf1tude Lorato ecrption 28 44 49 96 700 J40 At the discharge of flowing relief wells prior to mixing 1Permiitted FloW.(MGi)
Wl- ooe P (MGO with the West Branch of Colorado River Ply Ag pDly Max. ...ly"Av .., D1miD Max 0 , .-..bscharge a i ratlon d n/a n/a n/a n/a (hrs./day) (days/mo.)
.. (mo.Iyear)
Pumped Gravity Measurement Device: Estmlate X Intermittent -Seasonal Continuous Cnrbuting Wý~testrqamn
.Vo GeMD) *Of Total Co.Reservoir Relief Well effluent (wells 138-195) Intermittent 100 OUTFALL: 004 Latitudle, Longitude Location ýDeicri ption 28 44 57 96 01 03 Ata point in the MCR Spillway Channel after commingling of spillway ThiT IIEEgate leakage and relief well water, and prior to mixing with other waters P e rmnitte".d
- FloW" (kO) Prposed Flow (MGD)-i~li~g. DbiMa yDAvg, -.~ i~ak Kqshag urat~ion j n/a n/a n/a n/a , _ _(hrs,/day)
.(days/mo.)
.(mo./year)
Pumped X Gravity Measurement Device: Estimate Xintermittent -Seasonal
__Continuous Rebutlng Relief Well effMODuent(well Flow Reservoir Relief Well effluent (wells 196-268) Intermittent 100 ii. a 4'41 ii 4'r II JI TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 7 of 66 Attachment NOC-AE-14003142 Page 34 of 155 OUTFALL: 005 Latitude Longitud6'.-'.'".
Locat.i. Descr.ptlon"-
28 44 32 96 02 4 At the discharge of flowing relief wells, prior to mixing i'trmltteddFoib MG6). Proposed i low (!GiiDGt) with the East Fork Little Robbins Slough D~y Ag Dl Max ~y Ag OlyMax isc ~baeDuration n/a n/a n/a n/a _ (hrs./day)
_ (days/mo.)
_ (mo./year)
Pumped X Gravity Measurement Device: Estimate X Intermittent -seasonal
___Continuous RontaibrtI re Wate aief Wele Vowele (MG64) .nttal F Reservoir Relief Well effluent (wells 269-483) Intermittent 100 It it It It tI II.11 ii OUTFALL: 006 Latitud ~ Longitude;:.. .ocapn-,-14 31 _96 03I 36 At the discharge of flowing relief wells, prior to mixing I~'~r~m~!t~ted 1 l M dFl* (MGD)ji with Little Robbins Slough Dl~v ~l;a)< blý- lMax ishrbutdn n/a n/a n/a n/a (hrs./day) (days/mo.)
,(mo./year)-Pumped X Gravity Measurement Device: Estimate , X Intermittent
____Seasonal
____Continuous.on ;. .' iii,; .-.. .""'. ",.".:...'.,.,'...
V i n e M b ".. ., ". ,>Reservoir Relief Well effluent (wells 483-670) Intermittent 100-e a-ft It-t It II H-e II -I TCEQ-10055 (0511612012)
Industrial Wastewater Permit Application Technical Report Page 7b of 66 Attachment NOC-AE-14003142 Page 35 of 155 OUTFALL: 101.Lattude -ongltude' Location Description 2Where low volume waste sources commingled with previously monitored: l i .; effluents are discharged from the neutralization beslns prior to mixing with other Permitted Flodw (MGD) Proposed lF1oW (MGO) waste stream DyAvg OlyMax' A Dly Max on n/a n/a n/a n/a n/a_ (hrs./day) n/a (days/mo.)
n/a (mo,/year)
X Pumped -Gravity Measurement Device: totalizer X Intermittent Seasonal Continuous t at~ras Volume (MOP) % ifll No1W Low volume waste sources commingled with 0.25** 100 previously monitored effluents from the metal cleaning waste system discharge Stormwater
- At discharge into the MCR**Total outfall flow, average Sep 12 -Apr 14 OUTFALL: 201-Latitude'I -Lngtud.* .ILocatfon Descrfiiption 28 47 3 96 03 07 Where low volume waste sources are discharged from the oily waste.( GD) treatment system prior to mixing with any other waste stream-Permtited FloW ropose d F'V(M D 9~g t)ya D~Avg Diy Max ishageJuat na n/a n/a n/a fl/a (r.dy a (days/mo.)
.2/a (mo./year~.Pumped_
Gravity Measurement Device:_totalizer X Intermittent
____,Seasonal
___Continuous CotiuigWasteitraams:
s- Volm I MD OA 6hf Toailo Low volume waste sources from the oily waste O.019** 100 treatment system_________
_________Stormwater
- At discharge into theMCR _________**Total outfall flow, average Sep 12 -Apr 14 TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Reportg Page 7c of 66 Attachment NOC-AE-14003142 Page 36 of 155 OUTFALL: 401-Latltude*
Longltude' Locatloh bes Srlotion 28 47"' 35 ""96""-03j
ý7 At discharge from the sewage treatment plant (West Sanitary Waste P ..a.i ýWtted Flow (MGD) Proposed Flow (MGD) Treatment System) prior to mixing with any other waste stream Oly AV g Dly Max Dly AVO PlMY rpchrx D ation, n/a n/a n/a n/a n/a (hrs,/day) n/a (days/mo.)
n/a (mo./year)
X pumpedGravlty Measurement.Device:
ultrasonic X Intermittent
__Seasonal Continuous Treated sanitary sewage commingled with car 0.021* 100 wash water and air conditioning condensate Stormwater
- At discharge into the MCR**Total outfall flow, average Sep 12- Apr 14 OUTFALL: 501 Latltucie*
Longitude$'..
Lo'batidoh bes;rp n, 28 47 39 96 02 52 Where metal cleaning wastes are discharged prior toproposed Flow (MGD) mixing with any other waste stream~O~~v~ WyMa Wyvg JliMax .> Diýcage Durftnori, n/a n/a n/a n/a n/a (hrs./day) n/a (days/mo.)
2/a (mo,/year)
X PumpedGravlty Measurement Device: estimate X Intermittent
___Seasonal Continuous 777 7 7 .....Cd.-r ,-t..ri -. .u.ti.ng :-: W t
-;. .. ..
.; .V -..GD of O ai~ W Metal cleaning waste n/a** R/a**Stormwater
- Prior to mixing with Outfall_101
"*There has been no discharge from this outfall since Dec 1992 TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 7d of 66 Attachment NOC-AE-14003142 Page 37 of 155 OUTFALL: 601 Latitude " Longitude
- Location.Descriptnon 28 I47 I15 96 02 [10 At discharge from the sewage treatment plant (Training Sanitary.eritt..ed"low."(MD)i P.rop, d! FlOw (M".. Waste Treatment Facility) prior to mixing with any other waste stream Diy.:0' bI j , lM'ax:'by'i~
D OyWMax Dilscharge'ltiral n/a n/a n/a n/a rna (hrs./day) n/a (days/mo.)
_.a_(mo./year)
X Pumped Gravity Measurement Device: ultrasonic
-X Intermittent
_ Seasonal _ Continuous Contribuit ing ast btr~ams -Vollume d(MG 13 .13) To TotalF oW.Treated sanitary sewage commingled with air 0.018"* 100 conditioning condensate and HVAC cooling tower blowdown Stormwater
- At discharge into the MCR**Total outfall flow, average Sep 12 -Apr 14 OUTFALL: Latitude Longitude .LctnDeriion el Iow GO) Proposed Flow (MGD)I'y Avg Dly Max D!yAV9j :~Max~ i'~~i~Drtion'(hrs./day) (days/mo.)
_.(mo./year)
-Pumped Gravity Measurement Device:_, Intermittent -Seasonal
____continuous Contributing Wastestreams: -oiu i' MGb) .of iofM :7?'r It II ii 41. 41 it. II L .41 TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 7e of 66 Attachment NOC-AE-14003142 Page 38 of 155 a. Does y our facility use any coolingtowers or boilers that discharge blowdown or other wastestreams to the outfall(s)?
ELI Yes El No b. Does your facility discharge once-through cooling water to the outfall(s)?
LiYes FII No c. If yes to either item a or b, indicate with a check mark that the appropriate MSDS with the following information for each chemical additive was submitted with the application.
71 Manufacturers Product Identification Number.7] Product use. (e.g., biocide, fungicide, corrosion inhibitor, etc.)P1 Chemical Composition including Chemical Abstracts System (CAS) number for each ingredient.
LI Classify product as non-persistent, persistent, or bloaccumulative.
H Product or active ingredient half-life.
71 Frequency of product use (e.g., 2 hr/day once every two weeks).RV Product toxicity data specific to fish and aquatic invertebrate organisms.
71 Concentration of whole product in wastestream (if above item is for whole product)E] Concentration of active ingredient in wastestream (if above item is for active ingredient)
Please provide a summary of this information in a ddition to the submittal o f the M SDS for each specific w astestream an d the associated ch emical a dditives and specify which outfalls are affected.
Attachment:
I d. Cooling Towers and Boilers Number of Units Daily Avg. Blowdown Dally Max Blowdown Cooling Towers 1 cooling towers Dally Avg: 7,200 gallons/day Dally Max: 17,280 gallons/day Boilers 1 boilers Daily Avg:
- gallons/day Dally Max:
- gallons/day
.*4,022 rox matl d¥s e1 ear Are there any existing or proposed outfalls which discharge stormwater runoff commingled with other wastestreams?
[0 Yes FH No. If yes, provide the following information.
If no, proceed to Item No. 7.a. Provide a brief n arrative description of the industrial processes and a ctivities t hat occur outdoors or in some manner that may result in exposure of the materials to precipitation or runoff in areas where runoff is generated.
Storm water drainage from production and non-production areas Is discharged through permitted outfalls or under the TPDES Storm Water General Permit. For production areas, at least the first flush of stormwater runoff from SPOC sources and production equipment areas is collected and treated by the Oily Waste Treatment Systems (Outfall 201). Secondary containment is provided for chemical and other storage tank areas.TCEQ-10055 (0511612012)
Industrial Wastewater Permit Application Technical Report Page 8 of 66 Attachment NOC-AE-14003142 Page 39 of 155 D7 EOXM4RTICS SWAGE~ SWAXf MIIGE A 4D/RSPAT?
MANA1M~'7 ANN PVSA(~ SEPTAa~4~
V, WAGPA a. Please check the appropriate method(s) of domestic sewage and domestic sewage sludge treatment/disposal and complete Attachment F if directed.[] Domestic sewage is not generated on-site. PROCEED TO ITEM NO. 8.-Both do mestic and industrial treatment sludge ARE commingled prior to use or disposal.
PROCEED TO ITEM NO. 8.121 Industrial wastewater and domestic sewage are treated separately and the respective sludge IS NOT commingled prior to sludge use or disposal COMPLETE WORKSHEET 5.0 OF THIS APPLICATION.
[] If your facility is a POTW, COMPLETE WORKSHEET 5.0 OF THIS APPLICATION.
F] Facility is connected t o a wastewater treatment plant permitted t o receive domestic sewage, or the domestic sewage is transported off-site to a permitted facility for treatment and/or disposal.
COMPLETE ITEM NO. 7.11.n Domestic sewage is disposed of by an on-site septic tank. COMPLETE ITEM 7.B.T- Other: Please provide a detailed description below.b. Provide t he name and TC EQ, NPDES, and/or TPDES Permit N o. of t he waste disposal facility which receives the domestic sewage/septage.
If hauled by motorized vehicle, provide the name and TCEQ Registration No. of the hauler.N/A Is the p ermittee currently required t o meet any implementation schedule for compliance or enforcement?
E] Yes W] No If yes, provide a brief summary of the requirements and a status update.TCEQ-10055 (05115/2012)
Industrial Wastewater Permit Application Technical Report Page 1) of 66 Attachment NOC-AE-14003142 Page 40 of 155 Have any biological tests for acute or chronic toxicity been made on any of your discharges or.on a receiving water in relation to your discharge within the last three (3) years?El Yes l] No If yes, identify the tests and describe their purposes below. Please attach a copy of all tests performed that have not been previously sent to the TCEQ and/or EPA.There has been no discharge via Outfall 001 since 1997. The facility will perform the required testing when discharges occur.P ~~a YOPSIETfI V.A%~~ (1-ftcii, pge )Do you receive wastes from off-site sources for treatment in your facility, disposal on-site via land. application, and/or discharge via a permitted outfall El Yes V No If no, proceed to Item No. ii. If yes, proceed as directed.a. Indicate with a check mark that a detailed attachment with the following information was provided with the application:
F-1 List of wastes received Identified sources of wastes received-- Characterization of wastes receivedH Name and addresses of generators 8 Volumes of each waste received Description of the relationship of Info. on compatibility with on-site wastes waste source(s) with your facility's activities.
Attachlnent:
- b. Is wastewater from a TCEQ, NPDES, and/or TPDES permitted facility commingled with your wastewater after your final treatment and prior to discharge via your final outfall/point of disposal?
E] Yes n- No If yes, provide the name, address, and TCEQ, NPDES, and/or TPDES permit number of the co ntributing facility an d a copy of any agreements an d/or contracts r elating t o t his activity.c. Is your facility a Publicly Owned Treatment Works (POTW) that accepts process wastewater from any Significant Industrial User (SIU) and has or is required to have an approved pretreatment program under the NPDES/TPDES program? El Yes 11 No If yes, complete Worksheet 6.o of this application.
Are radioactive materials mined, used, stored, or processed at this facility?
2 Yes [] No If yes, Provide alist of the materials and the r esults of one analysis of your effluent in picocuries per liter (pCi/L) for all radioactive parameters which may be present.Radioactive Materials Conc. (pCi/L)Nuclear fuel (CAS no. 7440-61-1)
---**There has been no discharge via Outfall 001 since 1997.TCEQ-10055 (05/10/2012)
Industrial Wastewater Permit Application Technical Report Page 10 of 66 Attachment NOC-AE-14003142 Page 41 of 155 THE FO LLOWING ITEMS ARE ONLY REQUIRED FOR EXISTING PERMITTED FACILITIES.
Are you requesting a major amendment of an existing permit? 71 Yes F] No If yes, list each specific request and provide discussion on the scope of any requested permit changes.See Attachment J If necessary, provide supplemental information or additional data that will support the request.Are you requesting any minor modifications to the permit? RV Yes E- No Note: see the instructions for an exclusive list of changes considered as minor modifications.
If yes, list and discuss the requested changes.Please revise the definition for "total residual chlorine" provided In Other Requirement No. 4 to be consistent with the current definition for "total residual chlorine" in 40 CFR 423 that reads as follows: "The term total residual chlorine (or total residual oxidants for Intake water with bromides) means the value obtained using any of the "chlorine-total residual" methods in Table IB in 40 CFR 136.3(a), or other methods approved by the permitting authority." Are you requesting any minor amendments to the permit? ___Yes , No If yes, list and discuss the requested changes.TCEQ-1 0055 (05115/2012)
IndustrIal Wastewater Permit Application Technical Report Page I1I of 66 Attachment NOC-AE-14003142 Page 42 of 155 WORKSHEETS TO THE INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT Please review the worksheet requirements in the instructions and indicate by checking either yes or no which worksheets are required, completed, and submitted with the technical report.Worksheets that are not applicable do not need to be submitted with the technical report.COMPLETED AND SUMI'JTED WITF ,WORKSHJEET I THET CHNIt RIEPORT:-YES NO 1.0: EPA EFFLUENT CATEGORICAL GUIDELINES
[]1 F]1 2.0: POLLUTANT ANALYSES REQUIREMENTS
[ElF 3.0: LAND DISPOSAL OF EFFLUENT[7[]
3-1 SURFACE LAND DISPOSAL OF EFFLUENT [ 7 3.2: SUBSURFACE LAND DISPOSAL OF EFFLUENT [I] R(]3-3 SUBSURFACE AREA DRIP DISPERSAL SYSTEM LAND E7] o7 DISPOSAL OF EFFLUENT 4.0: RECEIVING WATERS [7 F]4.1: STREAM PHYSICAL CHARACTERISTICS WORKSHEET Di 7]5.0: SEWAGE SLUDGE MANAGEMENT AND DISPOSAL [71 [E]6.0: INDUSTRIAL WASTE CONTRIBUTION
[7 [7 7.0: STORM WATER RUNOFF Z~7 El 8.o: AQUACULTURE[]
7 9.0: CLASS V INJECTION WELL I]7 10.0: QUARRIES IN THE JOHN GRAVES SCENIC RIVERWAY 7 7 TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 12 of 66 Attachment NOC-AE-14003142 Page 43 of 155 Worksheet 1.0 EPA Effluent Categorical Guidelines Attachment NOC-AE-14003142 Page 44 of 155 WORKSHEET 1.o EPA EFFLUENT CATEGORICAL GUIDELINES REQUIRED FOR ALL APPLICATIONS FOR TPDES PERMITS FOR DISCHARGES OF WASTEWATERS SUBJECT TO EPA EFFLUENT LIMITATION GUIDELINES.
Is your facility subject to any of the 40 CFR effluent guidelines outlined in Table I?E-I Yes n.No If yes, provide the appropriate information in the table below. I f no, this worksheet is not required.IndustryCFR Steam Electric Generating Station 423 a. Production data: Provide the appropriate data for effluent guidelines with production based effluent limitations.
Sub:ategory Uc.... D.. .. .... Units-: i QuanUttY/Day N/A b. Organic Chemicals, P lastics, and S ynthetic Fibers Ma nufacturing Data (40 CFR Part 414): Provide each appropriate subpart and the percent of total production.
Also provide the appropriate data for metal bearing wastestreams as required in 40 CFR Part 414, Appendices A and B.N0 Aof totallApendixA andB Suctgr productio.iMtl rcs NIA _ _ _ _ _ _ _ _TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 13 of 66 Attachment NOC-AE-14003142 Page 45 of 155 c. Refineries (40 CFR Part 419): Provide the applicable subcategory and a brief justification for each.N/A 0OCES NOW~&ESWS.
X~~l6S M6~d eaire~dw fpo See Flow diagrams, Attachment H to~V1fen e- 9ti~K~ "p.-t t nea pg4~ .r S Process E .PA Guidleline Date Process/PIart Subp .art Construction.
P. olmmenced Units I and 2 423 N/A 1975 Units 3 and 4 423. N/A Near future TCEQ-1 0055 (05116/2012)
Industrial Wastewater Permit Application Technical Report Page 14 of 66 Attachment NOC-AE-14003142 Page 46 of 155 Worksheet 2.0 Pollutant Analyses Requirements Attachment NOC-AE-14003142 Page 47 of 155 Worksheet 2.0 Notes and Additional Information Outfall 001: There has not been a discharge from Outfall 001 since 1997, therefore, the required effluent samples for the application could not be collected.
STP will collect the required samples for the application upon the next available discharge via Outfall 001 and submit the results to the TCEQ for review.Outfalls 002-006: Effluent data is currently being collected by the facility for these outfalls.
The sample result will be submitted at a later date under separate cover.
Attachment NOC-AE-14003142 Page 48 of 155 WORKSHEET 2.0 POLLUTANT ANALYSES REQUIREMENTS
- there has not been a discharge via Outfall 001 since 1997.REQUIRED FOR APPLICATIONS SUBMITTED FOR A TPDES PERMIT. NOT REQUIRED FOR APPLICATIONS FOR A PERMIT TO DISPOSE OF ALL WASTEWATER BY LAND DISPOSAL OR FOR DISCHARGES SOLELY OF STORM-WATER RUNOFF. (General Requirements:
Instructions, Pages 49-51)!Outfall LD IC G 0 .. (tc6n e tain( gl.:
'lP6Ilutarnts iV>!
- }Samp !iSam p.,
>.Average~
BOD.(5-day)
.....CBOD (5-day)Chemical Oxygen Demand Total Organic Carbon r_.,, _r_Dissolved Oxygen Ammonia Nitrogen Total Suspended Solids Nitrate Nitrogen .Total Organic Nitrogen Total Phosphorus Oil and Grease Total Residual Chlorine Total Dissolved Solids Sulfate Chloride Fluoride IiiIl Temperature (OF)pH (Standard Units;min/max)_*fl tC',,r ;n (gI~. .., .",. MA.Total Aluminum 30 Total Antimony 30 Total Arsenic 10 Total Barium 10 Total Beryllium 5 Total* Cadmium 1 Total Chromium 10 Trivalent Chromium .N/A Hexavalent Chromilum 10 Total.Copper 10 Cyanide ,20 Total Lead .5 Total Mercury 0.2 Total Nickel 10 Total Selenium 10 Total Silver 2.0 Total Thallium _10 Total Zinc 5 TCEQ-10055 (05/16/2012)
Industrial Wastewater Permit Application Technical Report Page 15 of 66 Attachment NOC-AE-14003142 Page 49 of 155 Complete table required for all external outfalls which discharge process wastewater.
Partial table required for all external outfalls with n onprocess wastewater discharges.
Stormwater runoff discharges commingled with other wastestreams shall complete the table as instructed (Instructions, Pages 49-51). , There has not been a discharge via Outfall 001 since 1997.Dutfall No.: ncC IO fletCnetatoi.pI)(1.Pol.utan
/....SAMp':.
2 Samp 3.. S.h.S 4 ".Ayerage M.AL (Pg/I.Benzene 10 Benzidine 50 Benzo(a)anthracene
_10 Benzo(a)pyrene 10 Carbon Tetrachloride 10 Chlorobenzene 10 Chloroform 10 Chrysene 10 Cresols (*2)Dibromochloromethane
_10 1,2-Dibromoethane
ý2 1,4-Dichloro benzene 10 1,2:.Dlchloroethane 1G0 1,1-Diohloroethylene 10 Fluoride .600 Hexachlorobenzene 10 Hexachlorobutadlene 10 Hexachloroethane 20 Methyl Ethyl Ketone .50 Nitrobenzene 10 n-Nitrosodlethylamlne 20 n-Nltroso-di-n-Butylamlne 20 PCB's, Total (*3) 1 Pentachlorobenzene 20 Pentachlorophenol 50 Phenanthrene
_10 Pyrldlne 20 1,2,4,5-Tetrachlorobenzene 20 Tetrachloroethylene 10 Trichloroethylene 10 1,1,1.-Trlchloroethane
"_10 2,4,6-Trlchlorophenol 50 TTHM (Total Trihalmethanes) 10 Vinyl Chloride 10 (*1)(*2)(*3)Indicates units if different from pg/l.MAL's for Cresols: p-Chloro-m-Creso 10 pg/1; 4,6-Dinitro-o-Cresol 50 pg/i; p-Cresol o0 pg/l.Total PCB-1242, PCB-1254, PCB-1221, PCB-1232, PCB-1248, PCB-126o, PCB-ioi6.TCEQ-1 0055 (05/16/2012)
Industrial Wastewater Permit Application Technical Report Page 16 of 66 Attachment NOC-AE-14003142 Page 50 of 155 a. LABORATORY ACCREDITATION:
Effective July 1, 2oo8, all laboratory tests performed must meet the requirements of 3o TAC Chapter 25, Environmental Testing Laboratory Accreditation and Certification with the following general exemptions:
- i. The laboratory is an in-house laboratory and is: 1. periodically inspected by the TCEQ; or 2. located in another state and is accredited or inspected by that state; or 3. performing work for another company with a unit located in the same site; or 4. performing pro bono work for a governmental agency or charitable organization.
ii. The laboratory is accredited under federal law.iii. The data are needed for emergency-response activities, and a laboratory accredited under the Texas Laboratory Accreditation Program is not available.
iv. The laboratory supplies data for which the TCEQ does not offer accreditation.
The applicant should review 3 o T AC Chapter 2 5 for specific requirements.
The following certification statement shall be signed and submitted with very application.
See Instructions, Page 30, for a list of designated representatives who may sign the certification.
I, Michael P. Murray certify that all laboratory tests submittedwith this application meet the requirements of 3o TAC Chapter 25, Environmental Testing Laboratory Accreditation and Certification.
Partial table (only those pollutants which are required by the conditions specified for each outfall where the pollutant is believed to be present) required for each external outfall where the source is identified.
Not required for internal outfalls.* (Instructions, Page 51)a. TRIBUTYLTIN:
Is your facility or will your proposed facility be an industrial/commercial facility which directly disposes of wastewater from the types of operations listed below or a domestic facility which receive wastewater from the types of industrial/commercial operations listed below? DI Yes 0 No If yes, Indicate with a check mark all of the following criteria which apply and provide the appropriate testing results in the table below.M anufacturers and formulators of tributyltin or related compounds.
Painting of ships, boats and marine structures.
Lj Ship and boat building and repairing, H Ship and boat cleaning, salvage, wrecldng and scaling.Operation and maintenance of marine cargo handling facilities and marinas Facilities engaged in wood preserving LI Any other industrial/commercial facility for which tributyltin is known to be present, or for which there is any reason to believe that tributyltin may be present in the effluent.I TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 17 of 66 Attachment NOC-AE-14003142 Page 51 of 155 b. ENTEROCOCCI Does your facility or will your proposed facility discharge directly into saltwater receiving waters and: Enterococci bacteria Is expected to be present?Z]Yes 0INo Is domestic wastewater discharged?
W Yes M-No If yes to either question, provide the appropriate testing results in the table below.c. E. coli Does your facility or will your proposed facility discharge directly into fresh water receiving waters and: ElU~l] acteria is expected to be present?VIjYes L1No Is domestic wastewater discharged?
ED Yes [Z No If yes to either question, provide the appropriate testing results in the table below.TABLUE A.:::....Outfall No.: oC oG Effluent Concentration Pollutants Samp. 1 Samp. 2 Samp. 3 Samp. 4 Averagc MAL Tributyltin (gg/1) 0.010 Enterococci (CFU or MPN/1oo ml) N/A E. coli (CFU or MPN/ioo ml) N/A Complete table r equired f or all external outfalls which discharge process wastewater and other wastewaters, which way contain pesticides or herbicides, from a facility which manufactures or formulates pesticides or herbicides.
Not required for internal outfalls.Does your facility manufacture or formulate pesticides or herbicides?
E] Yes [Z No If yes, provide the appropriate testing results."CEQ-10056 (05115/2012)
Industrial Wastewater Permit Application Technical Report Page 18 of 66 Attachment NOC-AE-14003142 Page 52 of 155 D ; EX ... :, ý.tr f-.' 01)OIitfall No.ý ZCE ~ ~ f~ihQfoMaln4I
- ) A Pdltht.', Saffib.rI SaMp. 2; Ship. 3 Sanip. 4.A:. ' (091I)'Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D 10 Danitol 4,4-DDD 0.1 4,4'-DDE 0.1 4,4'-DDT 0.1 Demeton 0.2 Diazlnon 0.6 Dloofol 20 Dieldrin 0.1 Diuron 0.09 Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate 0.1 Endrln 0.1 Gamma -Hexachlorocyolohexane (Lindane) 0,05 Guthlon 0.10 Heptachlor 0.05 Heptachlor Epoxide 1,0 Hexachlorophene 10 Malathlon 0.10 Methoxychlor 2.0 Mirex 0.2 Parathion 0.1 Toxaphene 5 2,4,5-TP (SIlvex) 2* Indicate trnits if different from mg/L.TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 19 of 66 Attachment NOC-AE-14003142 Page 53 of 155 Complete table required for all external outfalls.
Not required for internal outfalls.(Instructions, Page 52)OUtfaII No' : nC oiG B616eIIVd b'ICOGn-, , Verage Mtaxlrimum NOf oSafibe§Bromide Color(PCU)
Nitrate-Nttrite(as N)Sulfide(as S)Sulfite(as SO 3)Surfactants Total Antimony Total Beryllium Total Boron Total Cobalt Total Iron Total Magnesium Total Molybdenum Total Manganese Total Thallium Total Tin Total Titanium TCEQ-10055.
(05/15/2012)
Industrial Wastewater PermIt Application Technical Report Page 20 of 66 Attachment NOC-AE-14003142 Page 54 of 155 Indicate with a check mark any of the industrial caategories applicable t o y our facility.
If testing is required, indicate with a check mark in the box provided that the testing results for the appropriate parameters in Table B-7 a re p rovided with t he application. (Instructions, Page 52-53)N/Ak .CiA ,etl4~dle Volatile Acid Oase/Neutral Pesticides Adhesives and Sealants Yes [] Yes El Yes El No Aluminum Forming Yes El Yes ED Yes El No Auto and Other Laundries Yes El Yes E) Yes El Yes El Battery Manufacturing Yes E] No Yes El No Coal Mining No No No No Coll Coating Yes D Yes El Yes El No Copper Forming Yes C- Yes El Yes El No__ Electric and Electronic Components Yes El Yes El Yes El Yes El Electroplating Yes Dl Yes El Yes El No Explosives Manufacturing No Yes El Yes El No Foundries Yes El Yes ED Yes El No Gum and Wood Chemicals_____Subparts AB,C,E Yes El Yes El No No Subparts D,F Yes El Yes Ul Yes El No Inorganic Chemicals Yes [l Yes El Yes [ No Iron and Steel Manufacturing Yes El Yes El Yes El No Leather Tanning/Finishing Yes El Yes El Yes El No Mechanical Products Manufacturing Yes El Yes El Yes El No__ Nonferrous Metals Mfg. Yes El Yes El Yes El Yes El Ore Mining(Subpart B) No Yes El No No Organic Chemicals, Plastics, and Synthetic Fibers Yes El Yea El Yes LJ Yes El Paint and Ink Formulation Yes El Yes El Yes El No Pesticides Yes El Yes El Yes El Yes D Petroleum Refining Yes El No No No Pharmaceutical Preparations Yes El Yes El Yes EL No Photographic Equipment and Supplies Yes El Yes El Yes El No Plastic and Synthetic Materials Manufacturing Yes El Yes El Yes El Yes El Plastic Processing Yes El No No No Porcelain Enameling No No No No Printing and Publishing Yes El Yes El Yes El Yes El-Pulp and Paperboard Mills___.Subparts A *E ] Yes l *l Yes U_ Subparts B, C, D, R
- El Yes l *El *El____Subparts F, G, H, 1, K, L, M. N, O, P Yes El Yes El
- El
- El Subparts E, Q, S, T Yes El Yes l *El Yes [Subparts J, U YesEl Yes El Yes El
- El-Rubber Processing Yes El Yes El Yes El No Soap and Detergent Manufacturing Yes El Yes El Yes El No V Steam Electric Power Plants Yes El Yes El No No Textile Mills (Not Subpart C). Yes El Yes El Yes El No Timber Products Processing Yes El Yes El Yes El Yes El* Test if "believed present" TCEQ-10055 (05116/2012)
Industrial Wastewater Permit Application Technical Report Page 21 of 66 Attachment NOC-AE-14003142 Page 55 of 155 Please complete as directed and only for those parameters specified in Table 6 Required for all external outfalls which contain process wastewater.
N ot required for internal outfalls.
Testing may be required for types of industry not specified in Table 6 for specific parameters if believed present (Instructions, Page 53).TAIILE t... ,. ., ..} .,:. ..
'.. ' : !,: 7 ' , L' ~ '* llll lrR ll ll, llrl;" .. .. ... ..,.{. ., ., .:...i, .... ,. ..i .*ll ., i ..,.. ,... ..:...,,.SS VOLATIlLE COMPOUNDS, ', ~pp Acrolein 50 Acrylonltrile 50 Benzene 10 Bromoform 10 Carbon Tetrachloride 10 Chlorobenzene 10 Chlorodibromomethane 10 Chloroethane 50 2-Chloroethylvinyl Ether 10 Chloroform 10 Dichlorobromomethane 10 1,1-Dlchloroethane 10 1,2-Dichloroethane 10 1,1-Dichloroethylene 10 1,2-Dichloropropane 10 1,3-Dlchloropropylene 10 Ethylbenzene 10 Methyl Bromide 50 Methyl Chloride 50 Methylene Chloride 20 1,1,2,2-Tetrachloroethane 10 Tetrachloroethylene 10 Toluene 10 1,2-Trans-Dlchloroethylene 10 1,11,11-TrIchloroethane 10 1,1,2-Trichloroethane 10 Trichloroethylene 10 Vinyl Chloride 10 TCEQ-1 0055 (05/16/2012)
Industrial Wastewater Permit Application Technical Report Page 22 of 66 Attachment NOC-AE-14003142 Page 56 of 155 Effluent Concentration (pg/I)*Average Maximum MAL (pg/o)' -. I-Samples ACID COMPOUNDS V 2-Chlorophenol 10 2 , 4-Dlchlorophenol 10 2,4-Dimethylphenol 10 4,6-Dinltro-o-Cresol 50 2,4-Dinitrophenol 50 2-Nitrophenol 20 4-Nitrophenol 50 P-Chloro-m-Cresol 10 Pentalchlorophenol 50 Phenol 10 2,4,6-Trichlorophenol 10 BASEINEUTRAL COMPOUNDS Acenaphthene 10 Acenaphthylene 10 Anthracene 10 Benzldine 50 Benzo(a)Anthracene 10 Benzo(a)Pyrene 10 3,4-Benzofluoranthene 10 Benzo(ghl)Perylene 20 Benzo(k)Fluo.ranthene 10 Bis(2-Chloroethoxy)
Me~thane 10 Bis(2-Chloroethyl)Eter
..10 B.s(2-Chlorolsopropyl).Eth~er 10 Bis(2-Ethylhexyl)Phthlarte 1.0 4-Bromophenyl Phenyl Ether 10 Butylbenzyl Phthalate 10 2-chloronaphthalene 10 4-chorophenyl phenyl ether 10 Chrysene 10 Dlbenzo(a,h)Anthracene 20 1.,2-Dlchlorobenzene 10 1,3_.Dchlorbenzene 10 1,4-Dlchlorobenzene 10 3,3-Dlchlorobenzldine 50 Dl~ethyl Phthalate 110 Dlmethyl Phthalate 10 DI-n-Butyl Phthalate 10 2,4-Dlnitrotoluene 10 2,6-Dinltroluene 10 DI-n-Octyl Phthalate 10 TCEQ-1 0055 (05115/2012)
Industrial Wastewater Permit Application Technical Report Page 23 of 66 Attachment NOC-AE-14003142 Page 57 of 155
- .
nt Concentration (pgll)*
- Pollutants Average Maximum !No. of Samples MAL (pg/I)BASEINEUTRAL COMPOUNDS (cont.)
1,2-Dlphenyl Hydrazine (as Azobenzene) 20 Fluoranthene 1'0 Fluorene 10 Hexachlarobenzene 10 Hexachlorobutadiene 10 Hexachlorocyclopentadlene 10 Hexachloroethane 20 Indeno(1,2,3-cd)pyrene 20 Isophorone 10 Naphthalene 10 Nitrobenzene 10 N-Nltrosodlmethylamlne 50 N-Nitrosodl-n-Propylamlne 20 N-Nitrosodiphenylamlne 20.Phenanthrehe 10 Pyrene 10 1,2,4-Trichlorobe nzene 10 PESTICIDES Aldrin 0.05 alpha-BHC 0.05 beta-BHC 0.05 gamma-BHC 0.05 delta-BHC 0,05 Chlordane 0.15 4,4-DDT 0.1 4,4-DDE 0.1 Dleldrin 0.1 alpha-Endosulfan 0.1 beta-Endosulfan 0,1 Endosulfan Sulfate 0,1 Endrln 0.1 Endrln Aldehyde 0.1 Heptachlor 0.05 Heptachlor Epoxide PCB-1 264 1.0 PCB-1 221 1.0 PCB-1242 PCB-1 232 1,0 PCB-1248 1.0 PCB-1 260 1.0 PCB-1016 1.0 Toxaphene 5.0....... .... ...I M, , ... .. .-.. ... ......, , .TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 24 of 66 Attachment NOC-AE-14003142 Page 58 of 155 8 TABL3 IS (MOXINS/ RA WOiUDS Please complete as directed.
Not required for internal outfalls. (Instructions, Pages 53-54)a. Are any of the following compounds manufactured and/or u sed in a process at t he facility?
Fj Yes 0 No If yes, i ndicate with a ch eck mark the compound(s) which apply and provide a brief description of the conditions of its/their presence at the facility.Ml 2,4,5-trichlorophenoxy acetic acid (2,4,5-T)
CAS #93-76-5 E- 2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex, 2,4,5-TP)
CAS #93-72-1 n- 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon) CAS #136-25-4[] o,o-dimethyl o-(2,4,5-trichlorophenyl) phosphorothioate (Ronnel) CAS #P-99-84-3 E] 2,4,5-trichlorophenol (TCP) CAS #95-95-4 E] Hexachlorophene (HCP) CAS #70-30-4 b. Do you know or have any reason to believe that 2,3,7,8 Te trachlorodibenzo-P-Dioxin (TCDD) or any congeners of TCDD may be present in your effluent?
[] Yes [] No If yes, provide a brief description of the conditions for its presence.C.If your responded yes to either item a or b, complete Table 8 as instructed.
VAB TE 8 Outfall No. -C [G u:7 ,wte.:EMIulvent Concentration EqivalV~ents Concelitratiori EqUlValentSt MAL (ppq)_onip6Und QAýýrs~~(p)
..P? (PptM (ppt))2,3,7,8-TCDD 1 10.0 1,2,3,7,8-PeCDD 0.5 50.0 2,3,7,8-HxCDDs 0.1 50.0 2,3,7,8-TCDF 0.1 10.0 1,2,3,7,8-PeCDF 0.05 50.0 2,3,4,7,8-PeCDF 0,5 50.0 2,3,7,8-HxCDFs 0.1 50.0 Total TCEQ-1 0055 (05115/2012)
Industrial Wastewater Permit Application Technical Report Page 26 of 66 Attachment NOC-AE-14003142 Page 59 of 155~9.J'flJE9HAAt V1J S STAN~ES: Proceed complete as directed.
Not required for internal outfalls. (Instructions, Pages 55)a. Are there any pollutants listed In the instructions (page 55) believed present in the discharge?
LlYes INo b. Are there pollutants listed in Item No. i.d. on Page No. i of this technical report which are believed present in the discharge and have not been analytically quantified elsewhere in this application?
[]Yes O7No If your responded yes to either item, complete Table 9 as instructed.
TALit<~Arae 0px~niiI 'N6. of, 1'Atialytio~I
_______________________________
CAS-N_________d_________
1- 4 4-I 4- 4 4 t .4- 4 .4 I *4-* .4 4-t +/- 4 +TCEQ-1 0055 (05/1512012)
Industrial Wastewater Permit Application Technical Report Page 26 of 66 Attachment NOC-AE-14003142 Page 60 of 155 Worksheet 4.0 Receiving Waters Attachment NOC-AE-14003142 Page 61 of 155 WORKSHEET 4.0 RECEIVING WATERS THE FOLLOWING IS REQUIRED FOR ALL TPDES PERMIT APPLICATIONS Is t here a surface water intake for domestic drinking water supply I ocated within 5 (five) miles downstream from the point/proposed point of discharge?
ElYes WNo If yes, identify owner of the drinking water supply, the distance and direction to the Intake, and locate and identify the intake on the USGS map. Indicate by a check mark that the requested information is provided:
D]a. Width of the receiving water at the outfall? ~300 feet b. Are there oyster reefs in the vicinity of the discharge?
[] Yes [No If yes, Indicate approximate distance and direction from outfall(s):
- c. Are there any sea grasses within the vicinity of the point of discharge?
D Yes []No If yes, provide the distance and direction to the grasses: Is the discharge directly into (or within 300 feet of) a classified segment?V Yes -No If yes , stop here. It is not necessary to complete items 4 and 5 and it is n ot necessary to complete Worksheet 2.1. If no, complete items 4 and 5.Name of the immediate receiving waters: a. Check the appropriate description of the receiving waters H Man-made Channel or Ditch E Stream or creek n] Lake or Pond Surface area _ .acres Average depth of the entire water body -feet Average depth of water body within a 5oo-foot radius or the discharge point -feet E] Freshwater Swamp or Marsh T idal Stream, Bayou, or Marsh Open Bay[] Other: If a man-made channel, ditch or stream was checked above, provide the following:
TCEQ-10055 (05/1612012)
Industrial Wastewater Permit Application Technical Report Page 39 of 66 Attachment NOC-AE-14003142 Page 62 of 155 b. Check one of the following that best characterizes the area upstream of the discharge.
For new discharges, characterize the area downstream of the discharge (check one).-' Intermittent (dry for at least one week during most years)L] Intermittent with Perennial Pools (enduring p ools c ontaining s ufficlent habitat t o maintain significant aquatic life uses)F] Perennial (normally flowing)Check t he method used t o c haracterize t he a rea u pstream (or d ownstream for n ew dischargers):
FI USGS flow records DI personal observation LI historical observation by adjacent landowner(s)
[] others, specify: C. List t he n ame(s) o f all p erennial streams t hat j oin t he r eceiving water within three miles downstream of the discharge point: d. Do the receiving water characteristics change within three miles downstream of t he discharge? (e.g., natural or man-made dams, ponds, reservoirs, etc Dl Yes E]No If yes, discuss how: e. Provide general obser vations of the water body during normal dry weather conditions:
Date and time of observation:
Was water body influenced by stormwater runoff during observations?
n Yes [-No a. Is the receiving water upstream of the discharges or proposed discharge site influenced by (check as appropriate):
RI oil field activities LI urban runoff L-] agricultural runoff LI septic tanks E] upstream discharges LI others, specify below TCEQ-10055 (05/115/2012)
Industrial Wastewater Permit Application Technical Report Page 40 of 66 Attachment NOC-AE-14003142 Page 63 of 155 b. Uses of water body observed or evidences of (check as appropriate):.
[ livestock watering El contact recreation ED irrigation withdrawal Li non contact recreation El fishing E- navigation El domestic water supply Li industrial water supply Ri picnic park activities El others, specify below c. Check one of the following to best describe the aesthetics of the receiving water and the surrounding area: LI Wilderness:
outstanding natural beauty; usually wooded or unpastured area: water clarity exceptional Li Natural Area: trees and/or native vegetation common; some development evident (from fields, pastures,dwellings);
water clarity discolored Li Common Setting: not offensive, developed but uncluttered; water may be colored or turbid Li Offensive:
stream does not enhance aesthetics; cluttered; highly developed; dumping areas; water discolored TCEQ-10055 (0511512012)
Industrial Wastewater Permit Application Technical Report Page 41 of 66 Attachment NOC-AE-14003142 Page 64 of 155 Worksheet 5.0 Sewage Sludge Management and Disposal Attachment NOC-AE-14003142 Page 65 of 155 WORKSHEET 5.o SEWAGE SLUDGE MANAGEMENT AND DISPOSAL THE FO ILOWING I S R EQUIRED FO R A LL T PDES PER MIT A PPLICATIONS THAT M EET T HE CONDITIONS AS OUTLINED I N T ECHNICAL REPORT 1.o, ITEM NO. 7.a. Is this a new permit application or an amendment permit application?
0 Yes E] No *The amendment requests will not change the sludge handling process at the facility.b. Does the facility discharge in the Lake Houston watershed?
R Yes 0 No If yes to either item a or b, Indicate by a check mark that a solids management plan was provided with the application.
E-] N/A, see note above.NAiL P 4AE~~~A4 QA~(ntcl;~e 4).a. Please check t he current sludge disposal m ethod(s).
More t han one method can b e checked.[] Permitted landfill[] Marketing and distribution by the permittee-- Registered land application site n-] Composted by the permittee[ Surface disposal site (sludge monofill)D Transported to another WWTP (written statement or contractual agreement required)[] Beneficial land application as authorized in the existing permit b. Disposal site name: Blue Ridge Landfill, TCEQ Permit/Registration Number: 1505 County where disposal site is located: Fort Bend County C. Method of Transportation (truck, train, pipe, other): Truck Hauler Registration Number: Aqua Zyme Services, Reg.. No. 21480 Transported in: FI liquid E semi-liquid F-1 semi-solid Z] solid state Land application for: EL Reclamation R Soil Conditioning
- d. If the existing permit contains authorization for sludge land application, composting, marketing and distribution of sludge, and/or sludge lagoons and authorization t o renew t he activity is being s ought in t he application, t he appropriate s ections o f t he Sludge Technical Report must be provided.TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 45 of 66 Attachment NOC-AE-14003142 Page 66 of 155~~Ag S WJouA xMo S ~TD'GEPR'S-SOSAL A hcio '4s,7a~5~Are you requesting new authorization to beneficially land apply sewage sludge at this site or a site under your direct control?Mi Yes 0 No Are you requesting new authorization to market and distribute sewage sludge at this facility or a facility under your direct control?[] Yes W1 No Are you requesting new authorization to compost sewage sludge?[D1 Yes IZ No Are you requesting new authorization to surface dispose sewage sludge at this site or site under your direct control?M Yes IZ No Are you requesting new authorization t o in cinerate sewage sludge at t his site o r site under your direct control?ElYes WZINo If yes to any of the above it ems, provide the information required in the S LUDGE TECHNICAL REPORT.New authorization for beneficial land application, incineration, and sludge lagoons in the TPDES or TLAP permits requires a major a mendmentto t he p ermit. New authorization for composting may require a major amendment to the permit. See the instructions for an explanation whether a major amendment Is required or if authorization for composting can be added through the renewal process.TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 46 of 66 Attachment NOC-AE-14003142 Page 67 of 155 Worksheet 7.0 Storm Water Runoff Attachment NOC-AE-14003142 Page 68 of 155 WORICSHEET 7.0 STORMWATER RUNOFF WORIKSHEET REQUIRED FOR ALL TPDES PERMIT APPLICATIONS APPLYING FOR INDIVIDUAL PERMIT COVERAGE FOR DISCHARGES OF STORM WATER RUNOFF.1. Do discharges from a ny of the p roposed or e xisting outfalls consist of stormw ater runoff only o r s tormwater runoff and any of the l isted n on-stormwater discharges?(See Instructions, Page 79)W-Yes IZINo If yes, proceed as directed.
If no, stop here.2. Indicate by a check mark which type of authorization covers or is proposed to cover discharges from each stormwater outfall. (See Instructions, Page 79)outfallI coverage Coverqag U'nde .r oulI coverbkoe coverage Under-UdrMGP Indiv"idual.
Permit utar Under MSGI' In'dividual Pelrnitý
- . ...., u a.... .. ....,-4. 4. .11 4 L 4 -4* -II -I-J. .11 A -L If you have indicated that all existing or proposed stormwater outfalls are covered under the MSGP, stop here. If you have indicated that you are seeking authorization under an individual permit, proceed as directed.TH OU~0* GVrM ARE !EQ.~~)F R ]IAC obTFAtlHA.
..DISCH GES StOIMWATERANDT OR WT6IIfY`OtJARESEEKICN(~N WýMALftTO1UZATON UNDER MlIfS PERMIT APPLICATION.
Indicate by a check mark that a site map(s) of the entire facility has been provided with the following information.
H the location of each stormwater outfall to be covered by the permit;an outline of the drainage area that is within the facility's boundary and that LI nI nI El contributes storm water to each outfall to be covered by the permit;connections or discharge points to municipal separate storm sewer systems;locations of all structures (e.g. buildings, garages, storage tanks);structural control devices that are designed to reduce pollution In storm water runoff;process wastewater treatment units (including ponds);bag house and other air treatment units exposed to precipitation or runoff;landfills; scrapyards; surface water bodies (including wetlands);
TCEQ-1 0055 (0511512012)
Industrial Wastewater Permit Application Technical Report Page 51 of 66 Attachment NOC-AE-14003142 Page 69 of 155 E vehicle and equipment maintenance areas;ED physical features of the site that may influence stormwater runoff or contribute a dry weather flow;D locations where spills or leaks of reportable quality (as defined in 3o TAC §327.4)have occurred during the three years b efore this application w as submitted t o obtain coverage under an individual permit; and ED processing areas, storage area, material loading/unloading areas, and other locations where significant materials are exposed to precipitation or runoff.a. Provide an inventory, or list, of materials currently handled at the facility that may be exposed to precipitation.
- b. Provide narrative descriptions of the industrial p rocesses and activities involving the materials in the above-listed inventory that occur outdoors or in some manner that may result in exposure of the materials to precipitation or runoff.TCEQ-1 0055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 52 of 66 Attachment NOC-AE-14003142 Page 70 of 155 c. Describe any best management practices and controls that you are using to prevent or effectively reduce pollution in stormwater discharges from the facility.TCEQ-1 0055 (05/16/2012)
Industrial Wastewater Permit Application Technical Report Page 53 of 66 Attachment NOC-AE-14003142 Page 71 of 155 poJVA4 4-t1$ ~ ti gs800)a. TABLE i-SW: Please complete the table as directed.Outfall ____MXUM~VAL~
nflYA ~ ~ ~ ~/.Grab "lw Grab Plow Number 'of Sml Weighted Sample Weighted Storm M1AL Composipotie
~~ 116tI~~rn Sample 7 Sampled pH (Standard Units) (min) (max) (min) (max) .....Total Suspended Solids Chemical Oxygen Demand Total Organic Carbon OIl and Grease Total Arsenic 0.010 Total Barium 0.010 Total Cadmium 0.001 Total Chromium '0.010 Trivalent Chromium Hexavalent Chromium 0..010 Total Copper 0.010 Total Lead 0.005 Total Mercury ...0.0002 Total Nickel 0.010 Total Selenium 0.010 Total Silver 0.002 Total Zinc 0.005 TCEQ-10055 (05/15/2012)
Industrial Wastewater Permit Application Technical Report Page 64 of 66 Attachment NOC-AE-14003142 Page 72 of 155 b. TABLE 2-SW: Please complete the table as directed. (Instructions, Pages 8o)STR EE~TO K(t"q~ Pag.Please provide the following data for the storm event(s) which resulted in the maximum values for the analytical data submitted:
a.b.C.d.e.g.Date of storm event: Duration of storm event (in minutes): Total rainfall during storm event (in inches): Number of hours between beginning of storm measured and end of previous measurable rain event: hours Maximum flow rate during rain event (gallons/minute):
Total stormwater flow from rain event (in gallons): Provide a description of the method of flow measurement or estimate: TCEQ-1 0055 (05115/2012)
Industrial Wastewater Permit Application Technical Report Page 55 of 66 Attachment NOC-AE-14003142 Page 73 of 155 Attachment A Copy of Application Fee 4 Submission Checklist, Pg. 1 Attachment NOC-AE-14003142 Page 76 of 155 Attachment B USGS Maps (Admin Report 1.0 -8.m., Pg. 12 Attachment NOC-AE-14003142 Page 77 of 155 THIS PAGE IS AN OVERSIZED DRAWING OR FIGURE, THAT CAN BE VIEWED AT THE RECORD TITLED: BLESSING SE, TX DMA 6741 I SE-SERIES V882 Attachment B 1USGS MAP WITHIN THIS PACKAGE...
02D01 THIS PAGE IS AN OVERSIZED DRAWING OR FIGURE, THAT CAN BE VIEWED AT THE RECORD TITLED:PALACIOS NE, TX, DMA 674111 NE-SERIES V882 Attachment B USGS MAP WITHIN THIS PACKAGE...
02D02 THIS PAGE IS AN OVERSIZED DRAWING OR FIGURE, THAT CAN BE VIEWED AT THE RECORD TITLED :IM[ATAGORDA,TEX, AMS 6841 III NW-SERIES V882 Attachment B USGS MAP WITHIN THIS PACKAGE...
02D03 THIS PAGE IS AN OVERSIZED DRAWING OR FIGURE, THAT CAN BE VIEWED AT THE RECORD TITLED: WADWORTH,TEX, AMS 6841 IV NW-SERIES V882 Attachment B USGS MAP WITHIN THIS PACKAGE...
02D04X Attachment NOC-AE-14003142 Page 82 of 155 Attachment C Affected Landowners Admin Report 1.1 -I.a. & b., Pg. 15 Attachment NOC-AE-14003142 Page 83 of 155 LEGEND_____ South Toxas Nucear Plant-Adjacent Landowners A Outfial Location* kntenl Monwfto Points Upstreanrvownstrea Markers-- Disharge Route a 200 4X SOUTH TEXAS NUCLEAR PLANT MATAGOR.DA COUN~TY. 7EXAS ATTACHIENT C AFFECITE LANOWES AP-It my tt *sin wj. ao.T4 O.Cs'b Vts , Um PLS Attachment NOC-AE-14003142 Page 84 of 155 MAPIl 3 2 3 4 5 6 7 0 N 10 11 12 13 14 15 16 17 1i 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 33 39 40 41 42 43 44 45 45 47 40 49 51 52 53 54 55 56 57 so 59 60 61 62 63 64 65 66 67 68 69 7n 71 7Z 73 74 75 76 77 78 70 81 83 64 05 07 8R 00 91 02 RIle...otn AARON REVOCABLE TRUST ABER WILLIAM M 1R & LAURA A ABER ADAMS ALLEN M ALKIRE WILULAM & LYNN O'BRIEN ALLEN MAREE L & EDITH M LANIER PRU ITT ARNIM A H 5 CARYN BARTON GARY R & DEANNA M BARTON SEAN E & BETH A BENNETT TIMOTHY T & CONNIE I BLACK MICHAELW & ALUSON BOWERS V Y BRANIFF JOHN R JR & MELISSA BROWN DIANA L BROWN TRACE PROPERTIES LTD BURDITTTOMMIE W & JUDY L & TROY W JO A CANTRELL JAMES S CARROLL JOHNNIE LEE CARROLL WAYNE & SUE CHANCE FARM CHAPPELL COLEY & LOREE ELTON CHERYL WIITE INC COLUER BILL & RUBY COR0RON ALLEN ROY COX JANE M COX THOMAS BRENT &TERRI LYNN CRAIN GARY & KAREN COANEJOE M CULVER RAY M JR DAVIS CLYDE I DAVIS JEFF R & BETTY S DAY JEREMY DEFEHR KEITH D & BARBARA DENHAM ALFRED B DORR FRANK D DZIUK ROBERT J/HELEN/JEFFERY&
STACYATTAWAY ELYJAMESE ESTES DANIEL EDWARD III & TAMMY RESEE EXOTIC ISLE HOMEOWNERS ASSOC FALTYSEK NATHAN RAY & KERA FLORE5 JAMES W & THOMAS 0 FLOYD CHARLES R ESTATE FREEMAN FAMILYTRUST GAERTNER DEAN R & MARY BESH GAERTNER GATELY FRANCIS & JOY D GAVENDER M E & ROSALIE GAVENDER RONALD F GILLILAND ANGELA M GOODMAN LESLIE L GREGORY JAM ES F GROTH ALISON E GST EXEMPT DE3CENDANTS TRUST GROTH CARL E & KATHY D HANSEN DORIS BUNGE FAMILY TRUST 2012 HARRISON GEORGE R & DONNA CORNELIUS HENDERSON ROBERT K JR HICKS MICHAEL & CHARLENE HINOTE RUSSELL E & DIANE HOWAATON MARION L & VWCKIE E HUBBARD PROPERTIES LTD HUGHEYJOHN R IVY DONALD D & JOYCE JANISE NATHAN S & PAMELA S JOHNSON DIRK 19 KIM8RA K JONES JEANNIE R KEY MARTIN L & DONNA L KIENTZ CALVIN W KIRBY BRENTT & SUE W KNAPP DEBBIE KIRE SOSTESSAUDER HARRY 8 & SHERYE. L SZEINBACH KRENEK LARRYJ & DEANNA H LANDERS JOHN S SR & JANE C LEDWIG JULIUS H RR & SCOTT D LEDWIG LEISSNER DAYTON LANE LESLIE JESSICA LIGUMS JOHN E & IENNIFER H LOYACANO RAY DALE & FRANCES MARTIN JERRY L & KATHRYN MASSEY DAVE & NANCY SPEICH MATHERNE TERRY A & SUSAN K MCELMURRAY ELI HENRY MCGEE CLAUDE & BARBARA PRESLEY MCKINLEYJESSE G ETAL MILER SEAN GORDON MILLER RONNIE LAVELLE MOBLEY LARRY W & CAROL I MOFFITT REAL ESTATE I LLC MONTGOMERY JACK C & BARBARA I MORRIS STEVE I NIELSEN DONALD & MARY JEAN OCONNEILL PATRICK I OWEN BESSIE MAE PAJESTKA BLANCHE PETRVALSEK GERALD& MARGARET ELLEN PETRVALSKY addrjine2 SB ENGUSH OAK 1640 CR243 1610 CR 243 372 CR 243 18350 FENSKE BRB EXOTIC ISLE 4708 WELFORD DRIVE 471 USNDEN 2700 CYPRESS SPRINGS LN 1618 CR243 P G BOX 799 6230 LYNBROOK 2076 CR 243 3606 YVENUE F 5924 HOMESTEAD 302 EMPRESS LANE 1071 CR 385 352 CR 243 P F BOX 0265 2010 CR 243 607 SALERNO H61 CALADIUM COURT 625 GREEN DEWITT RD 1540 CR 243 550 CR 243 SELKIRK RD 1190 CR 243 (SELKIRS RD)2909 OAK DR 306 PRIVATE ROAD 608 1320 CR 243 SELKIRK RD P 0 BOX 3196 10684 CRf303 P 0 BOX 126 P G BOX 1792 17603 WESYTLEIGH DR 1824 SUNSET DR 1700 GOLDEN AVE RI100 P0 BOX 27 1322 BETEEL 2021 HIAMILTON DRIVE J1B3 WILLOW STREET 1700 :COUNTY ROAD 243 P G BOX 789 27002 MESA VERDE DRIVE 1802 CR 243 1990 CR 243 PG EOX 372 R20TW 3TH ST 18100FFPP 411 S BELKNAP ST SSSS SAN FELIPE STE 200 2811 GOLDEN LARCH DR 7282 1'M 521 2486 CR 222 535 AZALEADELL DR 20822 RIVA FUDGE 2315 OAKVIEW DR 720 CR 243 PO BOX 2&3 59 EXOTIC ISLE DRIVE 2058 CR 243 592 CR 243 3313 ASPENBEROOK COURT 726 S PRAIRIE RD 9810SPINGFIELD RIDGE DR 3669 FM 2268 P 0 BOX 32 PG BOOX 4179 P0 BOX 211101 32653 PECAN HILL 2014 COUNTY ROAD 243 P G BOX 190 5619 CR 112 110 CANYON DRIVE 3736 KNOLLWOOGST 448 CR 243 1R78 CR 243 4021 BYRON 4841 BRAIRBEND DRIVE 1718 CR 243 700 AVENUE F NORTH 12522 CAMPSITE TRAIL P0BOX669 2404 AVENUE H 1810 CR243 13002 KLUGE RD 435 FOX BRIAR LANE 5151 EDLOE APT9107 1910 C R 243 10101 SOUTHWEST FWY STE 100 15318 ARHWOOD DR P 0 BOX 105 6717 COTTON add_dRW LAKE JACKSON BAY CITY SAY CITY BAY CITY CYPRESS BAY CITY BELLAIRE BELLAIRE CYPRESS BAYCITY PALACIOS HOUSTON RAY CITY BAY CITY ROSENBERG LEAGUE CITY PALACIOS BAY CITY WICHITA FALLS SAY CITY SUGAR LAND LAKE JACKSON CUERO BAY CITY BAY CITY BAY CITY BAY CITY BAYCITY BAY CITY PORTLAVACA PLANTERSVILLE WADSWORTH RAY CITY HOUSTON BAY CITY RAY CRY EL MATON HOUSTON ROSENBERG BAY CITY BAY CITY BROOKSHIRE MAGNOLIA BAY ERY BAY CITY WADSWORTH HOUSTON PASADENA SUGARLAND HOUSTON KATY PALAClOS BAY CITY HOUSTON FAIR OAKS RANCH MISSOURI CIE BAY CITY VAN VLECK BAY CITY DAY CRIY BAY CITY PEARLAND NEW LENOX KATY BAYICRY WADSWORTH HOUSTON COLUMBUS BROOKSHIRE BAY CTY BLESSING VAN VLECK SAN ANTONIO HOUSTON BAYCETY BAY CITY HOUSTON HOUSTON BAY CIE BAY CITY CYPRESS 8AY CERY BAY CETY BAY CITY CYPRESS SUGAR LAND HOUSTON RAY CITY HOUSTON SUGARLAND HOLLAND HOUSTON addr..%ate"TX Tx Tx"TX TX Tx TX TX TX TX TX TX Tx Tx TX 0X TX TY TX TX TX TX 03 0X T3 TX T3 TX T3 TX TX T1 03 TX TX Tx Tx TX TX T0 0X 03 T5 T3 TY 03 T3 T3 03 TX 03 T3"X 03(IL T3 TX T0 TX OH TX TX TX TX TX TX T3 TX T3 T3 T3 TX T3 T3 0X T1 IL TX T3 TX TR TX zip 77566 77414 77414 77414 73433 77114 77401*77401 77433 77414 77465 77037 77414 77414 77471 77573 77465 77414 76307 77414 77478 77566 77954 77414 77414 77414 77414 77414 77414 77979 77363 77483 77404 77077 77414 77414 77440 77055 77471 77414 77414 77423 77355 77414 77414 77483 77018 77502 77478 77056 77494 77465 77414 77018 78015 774159 77114 77.00 77414 77414 77414 77581 60,151 77494 77414 71413 77210 43221 77423 77414 77419 77402 78209 77019 77414 77414 7700S 77035 77414 77414 77429 77404 77414 77414 77429 77478 7700D 77414 77074 7747B 76534 77092 Attachment NOC-AE-14003142 Page 85 of 155 PHILLIPS BRIAN M & PAMELA A PLUMMER CHIEDRENS' TRUST PLUMMER MATTHEW W JR TRUSTEE POPP CEDRIC E &JOANN POSTER WARTREUR 1999 REVOCABLE POSWAY JOHN P & ELISSA PURYEAR MARILYN ANN PYATTE JOSEPH B QUINNEY JOSEPH F RADITE TRAVIS WILUAM & NICOLE P REUSE RUSSELL P & ALYCE J RICHARDSON JERRY & BARBARA ROBERTS PAUL D & LINDA I ROY CHRIS A & KELLIE D RUNNELLS CLIVE III RUNNELLS CLIVE IV SAHA JOHN BYRON & AMANDA KAY SALAZAR RUBEN SAMS CLEO LESTER & MARY K SAVAGE JOHIN MORRIS SAVAGE KEN & CINDY SCHEPS BRENT SCHWARTZ SIDNEY TRUSTEE SELKIRK ISLAND IMPROVEMENT COMMITTEE SHEPPARD IIENRY C SHERRILL KAREN SILLERS CYNTHIA B REV TRUST SILVERTHORNE KENNETH W SNYDER JAMES EUGENE & CAROLYN L SPECK FAMILY LIVING TRUST SPROTT HANNAH ASHIEY SPROTT SHERRY L CULVER STEFFEK KEITH A & JONNIE E SZEINBACH SANDY A TALASEK MELVIN B TALASEK MICHAEL M & KARSE J TALASEK THE SCHINDLER UVING TRUST THOMAS HARRY R 1R & DIANA TILLER DAVE GUY I11 & TALBOTT FAMILY LIVING TRUST TRACY TRENT N TRAHAN RONALD L & GAIL E TURNER GERALD DALBERT A IR & ANNETTE L VANCE JOAHN T III & ELIZABETH VAUGHAN WATTS RARD & PATSY KAYE VAUGHA N VAVRA JARRETT &TAMMY VAVRA MILTON JR WALKER TED L & LORT I WARR KENNETH H JR & CHRISTIAN SWINBANK WEDEMEIER THOMAS M WENZEL CHARLES E & MARIELLEN WESTMORELAND GREG B WIKOFP LEE E A KERRI WINTERS JOSEPH P & DOLORES YOUNG ROBERTAUSTIN ZABOROSKI EUGENE & SELPHINE ZARRANSKY MICHAEL C & RUTH 5EW HIGHWAY 36 N 2101 CRAWFORD ST STE 302 2101 CRAWFORD SUITE 204 4612 CR 410 RD 4408 LONG CHAMP DR APT S8 6903 ELM TRACE DR 334 CR 243 / SELKIRK RD 1070 CR 243 P 0 6X.71 E13 TWIN PINES DR 30702 MCKINNEY DR P B BOX 911 2901 7TH 1TR363 P C BOX 926 P 0 EOX 5097 P 0 EOX 5097 2E95 CR 391 4702 MIMOSA CIR 2(B CR243 4797 FM 2853 1652 CR 243 550 COLLEGE 1940 AVENUE G 1650CR243 5207 MARBLE GATE 11707 CEDAR POI NT COURT 5555 45TH ST 1574 CR 243 1930 CR 243 SELKIRK RD 11D2 SYCAMORE RD 9479 LIGH.SEY LN 9479 LIGHTSEY LN 7601 SWANSON DR 1054 CR 243 P 0 BOX 397 P 0 B DX 278 1LS WEST EVANS 2108 CR 243 2613 TUPELO P 0 BOX 350 2704 CR 243 33Z7 EAST OVERDALE 7402 FP 361 3100 AVENUE H 1493 CR 243 3458 CR 384 415 CR 353 402 MAIN 9TH FLOOR P 0 BOX 1127 1420R5243 2701 PARKWAY 18 VALHALLA DR 1650 CA 243 252 CR 243 P0.BOX632 184 LCR 743 A 6529 MERLIN BELLVILLE HOUSTON HOUSTON ELCAIMPO AUSnN SUGARLAND BAY CITY BAY CITY MARKHAM FRENDSWOC)D TOMBALL WADSWORTH BAY CITY SANTE FE AUSTIN AUSTIN PALACIOS RICHMOND BAY CITY PALACICS DAY CITY BELLAIRE BAY CITY BAY CITY HOUSTON HOUSTON MOORHEAD BAY CITY BAY CITY RICHMOND COLLEGE STATION COLLEGE STATION RICHMOND DAY CITY WADSWORTH MATAGORDA WHARTON BAY CITY BAY CITY WADSWORTH BAY CITY PEARLAND RICHMOND BAY CITY BAY CTTY PALACIOS PALACIOS HOUTO N FULSHEAR BAY CITY ROSENBERG BAY CITY BAY CETY BAY CIT" MATAGORDA THORNTON HOUSTON 77418 77002 77002 77437 78746 77479 77414 77414 77456 77546 77375 77483 77414 77517 78703 79763 77465 77406 77454 77465 77414 77401 77414 77414 77069 77070 65160 77414 77414 77469 77540 774G6 77414 77463 77457 77488 77414 77414 77483 77414 77584 77469 77414 77414 77465 77465 77002 77441 77414 77471 77414 77414 77414 77457 76687 77055 f\.,. /
Attachment NOC-AE-14003142 Page 86 of 155 Attachment D Original Photographs Admin Report 1.1 -2., Pg. 12 Attachment NOC-AE-14003142 Page 87 of 155 RPS Attachment NOC-AE-14003142 Page 88 of 155 Attachment D -Outfall Photos Photo1 -Outfall 002 Photo 2 -Outfall 001, Looking downstream Attachment NOC-AE-14003142 Page 89 of 155 Photo 3 -Outfall 001 looking out Photo 4 -Outfall 003 Attachment NOC-AE-14003142 Page 90 of 155 Photo 5 -Outfall 004 Photo 6 -Outfall 005 Attachment NOC-AE-14003142 Page 91 of 155 Photo 7 -Outfall 006 Attachment NOC-AE-14003142 Page 92 of 155 Attachment E USGS Map SPIF, Item 8 Attachment NOC-AE-14003142 Page 93 of 155 Downstream of OutOfll 003 1WIMile Doitam of Downstream Outf 00 1 & 004 O u t fa U l 0 0 53 W a I s h o n n the. FullSze"W SouthTexn ud....lan Map as required.Imile radius N A outfall Location 0 2,500 5%ODO* Intemal Monitoring Points FEET Ad War WMR Locations (TWDB) 4 -C = =rw, DRAWN SY: SB WIVLSON SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS APPROVED BY: T KOEIN PROJECT NO: 2014 TPDES ATTACHMENT E FILE NO. STNSPIF MAP.m,.SPIF USGS MAP DATE. MAY2014 A; = W sz: M M-9ml, ý win a ' I ý -
Attachment NOC-AE-14003142 Page 94 of 155 Attachment F Wastewater Generating Process Tech Report 1.0 1.c., Pg. 1 Attachment NOC-AE-14003142 Page 95 of 155 Attachment F -Wastewater Generating Process Main Cooling Reservoir
-- Outfall 001 Outfall 001 is the discharge point for the 7,000-acre main cooling reservoir.
This reservoir is part of the main recirculating cooling water loop used to remove heat from the steam-electric generating units.There has not been a discharge from Outfall 001 since March 1997 otherthan minor permitted leakage through the closed spillway gates and relief wells. If a discharge were to occur, blowdown from the main cooling reservoir would make up the largest percentage of wastewater.
A discharge from Outfall 001 would flow to the Colorado River (Colorado River Tidal in Segment 1401 of the Colorado River Basin).All internal outfalls (Outfalls 101, 201, 401, and 601) discharge to the main cooling reservoir.
Outfall 501 would also discharge to the reservoir via Outfall 101, but has not discharge since 1992.Low Volume Wastewater (Outfalls 101 and 201)Low volume wastewater results from water treatment operations, boiler blowdown, HVAC blowdown, floor drains, SPCC sources and their associated oily water treatment system discharges, and other miscellaneous sources. Boiler blowdown is from one auxiliary steam boiler, released to reduce impurities in the water that can cause corrosion and boiler tube failure. Service water is demineralized and regeneration of the demineralizer resin beds produces an acidic and caustic wastewater that is treated at the neutralization basins along with boiler blowdown.
The floor drain system captures condensate and water from production and maintenance areas that may contain oil or grease, which is then transported to the oily waste treatment system where the oil is separated from the water. The first flush of stormwater from some production and storage areas is also treated in the oily waste system. Other non-processstormwater flow is directed through designated stormwater outfalls.Treated Domestic Wastewater (Outfalls 401 and 601)Domestic wastewater is treated onsite in two package treatment systems consisting of aeration, clarification, and disinfection.
Car wash water, air conditioning condensate, HVAC cooling tower blowdown, and stormwater are commingled with the domestic wastewater prior to treatment.
Metal Cleaning Waste (Outfall 501)Metal cleaning waste has not been discharged since 1992. Metal cleaning using chemical or non-chemical liquids produces a waste that would be discharged through Outfall 501 to the neutralization basins (Outfall 101). Stormwater may also be discharge through Outfall 501.Main Cooling Reservoir (MCR) Relief Well Effluent (Outfolls 002-006)MCR relief well effluent is collected from the perimeter of the MCR and discharge via Outfall 002-006 without treatment.
Outfall 002 is also authorized to discharge demineralized water from Instrumentation.
Attachment NOC-AE-14003142 Page 96 of 155 Attachment G Facility Plot Plan Tech Report 1.0- I.e., Pg. 2 Attachment NOC-AE-14003142 Page 97 of 155 I h ii II LEGEND Soulh T~*as I*,dsor Pft LUnfts I £2 A OujhILocaflbn 0 knesiAo MwV cib t) k qiýATTACNMNTO FACOfrYS MTAP mo w tsvamo so&&US1~~m T~ S l~.r 3m IWA0U IIIM ILDUIA;LrAi PLA"I MATAGAM COUNIY. 7EXAýw mm MET IS-w~'=1 rn-U-----
Attachment NOC-AE-14003142 Page 98 of 155 Attachment H Flow Schematic Diagrams Tech Report 1.0- 2.b., Pg. 3 Attachment NOC-AE-14003142 Page 99 of 155 Colorado River Notes: Outfall has not discharged since March 4, 1997.** Outfall has not discharged since December 1992.SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 001 DRAW,/N BY SSW"LSOD I SCALE! PROJ. 2014TDOES CHECKED BY: T KOENINGS De. b sRRI F[LE NO. STNoFI.. D.o0r,,e..wg APPROVED BY: DATE PRINTED DATE: U, 12, 231 A-t S, £.dA a Attachment NOC-AE-14003142 Page 100 of 155 Effluent from Relief Wells W1.W125 Plant drainage ditch to Colorado River, Tidal OUTFALL 002 Am -w Demineralized Water from Instrumentation SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 002 DRAWAN BY: S,3VLSON SCALE: PROJ. 201 4TPDES CHECKED BY:T KOE WJINDS Z.. b., -le FILE NO. SRJI4 Osa APPROVED BY: -DATE PRINTED: DATE: M.,t 2.2014[ 7Rý 7PS ]t~M 0.,* R*01,g 57 R.3. 100 2050 C*Ol.1 tl Ta,.. H~5W*II S0011 01,140 r.n, 7,745 010.51 1.7145 I Attachment NOC-AE-14003142..
Page 101 of 155 OUTFALL 003 I Effluent from Relief Wells WI 38-W195 I West Branch of the W Colorado River OUTFALL 004 Effluent from Relief Wells W196-W268 Main Cooling Reservoir Spillway W OUTFALL 005 AI East Fork Little Robbins Effluent from Relief Wells W269-W483 w SloughI OUTFALL 006 Effluent from Relief Wells W483-W670 Little Robbins Slough i -a-SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 003, 004, 005, 006 DRAM BYA: SSWMLSON SCALE: PROJ. 2014WMES CHECKED8Y:TKOENINGB Se 'br oIP FILENO. ' LL...l, APPROVEDI BY DAE PRINTED: DATE: 14 0 CIA 0 RpýS DV, On. BI44~g2'.
DVi 000 0404 Cot.S.VTIa.JVOA.,.o.
S~4A A4t 70,08 10740 d(2041.7MD b
Attachment NOC-AE-14003142 Page 102 of 155 LOW VOLUME WASTEWATER including wastewater from the following operations and sources:.* demineralizer regenerant wastewater;
- condenser polishing regenerant wastewater;
- boiler blowdown;* boiler drainage;.
- laboratory, instrument, and sampling sources;* well water filter backwash;* water softener regenerate;
- floor drains in chemical storage containment areas;* rinse water from triple rinsing empty chemical drums;, fuel handling building HVAC blowdown; and* miscellaneous low volume wastewater.
recirculation line--------------------
I -NEUTRALIZATION BASINS Neutralization*
Mixing*Sedimentation OUTFALL101 to Main Cooling Reservoir sludge to landfill Metal Cleaning Waste Effluent (Outfall 501"*)Storm Water Notes: 'Treatment may be used based on influent quality-Outfall 501 has not discharged since December 1992.SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 101 DRAMI BY: SSWILSON SCALE. PR04, 2514TPOES CHECKED BY:KOENINOS Be*ba 5cl. ,t FILE NO0. GNJS.Y.*Stl,,t APPROVED B:jS 22 DAT PRINTYED DATE: I Attachment NOC-AE-14003142 Page 103 of 1556 sludge to incineration and/or landfill----w- filter media to landfill SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS Notes:*** Treatment process may be used based on influent characteristics.
ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 201 SS=tLSON SCAL.E: PROJ. 2E14TPDES"KOENINGS1 See Sa' cIe FILE NO. NFSw ,-DATE PRINTED: IýýM r RPSI 01.5 C..t. A.iObOR S,,*bIX 1210 C~ftI~4 ShVft~.o 00051 70043 P~T0O Attachment NOC-AE-14003142.
Page 104 of 155 AERATION TANKS Activated Sludge Foam Suppression Screening L -----------------
OUTFALL 401 DIGESTER Sludge to landfill ---Aerobic Digestion to Main Cooling Reservoir SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 401 DRAMN BY: SSVVILSON SCALE: PROJ. 2014ITPDES CHECKED BY: T KOENINOS S50 b.-.1 FS~ ILE NO. DThYoa APPROVE BYOR DATE PRINTED: DATE:-~~2 1~- H5,-,.S1 O monommomwjbý Attachment NOC-AE-14003142 Page 105 of 155 Metal Cleaning Wastetwater Inorganic Basin-- Coagulation' Chemical Precipitation*
Sedimentation to Outfall 101 OUTFALL 501 (no discharge since 1992)Storm Water SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 501 DRAWN BY: SSW1LSON SCALE PROJ. 2014TPOES CHECKED BY; T KOEtNO1 S U0 bar ato j FRLE NO. ST._Fl R- ,.g APPROVED BY: -DATE PRINTED;DATE; Ua. 12. 20114 Notes:* Treatment process may be used based on influent characteristics.
I RPS]23* Card,.. B.do23I 23,4?. 2300 42350 CR232323 at 31,50 N00fl. Stat,*a,1431 Faa.. 00746 i Attachment NOC-AE-14003142 Page 106 of 155'AERATION TANKS Activated Sludge Foam Suppression Screening-------------------
OUTFALL 601 DIGESTER Aerobic Digestion I. to Main Cooling Reservoir sludge tolandfill SOUTH TEXAS NUCLEAR PLANT MATAGORDA COUNTY, TEXAS ATTACHMENT H FLOW SCHEMATIC
-OUTFALL 601 DRAWN RY: SD LSON SCALE: PROJ. 2014TPDES CHECKED BY: T KOEINGS So.. batb scar FILE NO. STNFl, FIS-ll,.E,.
APPROVED RY: -DATE PR1NTE: DATE: 0. 201"TA IML AI 20 a Attachment NOC-AE-14003142 Page 107 of 155 Attachment I Water Treatment Chemicals Tech Report 1.0- 5.c., Pg. 8 Attachment NOC-AE-14003142 Page 108 of 155 Treatment Chemicals Product Manufacturer Use Components Listed in CAS Frequency of Toxicity Product Name MSDS Use Data Concentration In MSDS Sodium ypolorite 7681 3 times per day LiquichSor Univar :Biocidt for 20 minutes to Yes 0.15-0.6 ppm total 1310e73- unit's cooling residual chlorine Sodium Hydroxide 2 water Sodium nitrite 7632 As needed to 0.25 oz per gallon of 1359 Plus Nalco Corrosion inhibitor 0 maintain No closed cooling system 7775-19-Sodium nictaborate concentration water 1 19H Nalco Oxygen scavenger Hydrazine 302-011-2 Continuous Yes 0.1 ppm to feedwater Sodium Nitrite 7632 As needed to LCS-60 Nalco Corrosion inhibitor 0 maintain No 500-1500 ppm sodium Sodium Tetraborate 1330 concentration nitrite concentration 4.1 Scale Polyacrylic Acid N/A Continuous 935cNlcoNo 0.25 ppm federate as inhibitor/dispersant product 3 times per day ACTI-BROM Nalco Biocide Sodium bromide 7647 for 20 minutes to Yes 0.15-0.6 ppm total.131.8 6 unit's cooling residual chlorine water B-2200 Varichem.
Algaecide Ethyl Alcohol 64-17-S Batch treated as No 5 ppm needed B-2206 Varichem Biocide Broimochloro-5.5-N/A Continuous No 0.5-2 ppm diniethylydantoin Scale and SC-23 10 Varichen coaroaiondinibitor None listed N/A Continuous No 80-120 ppm Attachment NOC-AE-14003142 Page 109 of 155 Didecyl-Dimethyl-7173 4 ppm as product (2.5 H-130M Nalco Biocide Ammonium chloride 52/Yr. Yes ppm. as active) to aux.Ethanol 64-17-5 cooling system for 8-hours twice per year.Magnesium Salt N/A 2-Methyl-4-Isothiazolin 2682 Batch treated as 77352NA Nalco Isothiazolin one 4 needed Yes 300 ppm 5-Chloro-2-Methyl 26172-_ 1 _sothiazolin-3-one 55-4 _ 1 Attachment NOC-AE-14003142 Page 110 of 155 UnIVAR@Univar USA Inc Material Safety Data Sheet MSDS No: Version No: 010 2014-03-18 Order No; I ZI Univar USA Inc., 17425 NE Union Hill Rd., Redmond WA 98052 (425) 889 3400 Emergency Assistance For emergency assistance involving chemicals call Chemtrec -(800) 424-9300 Attachment NOC-AE-14003142 Page 111 of 155 UNIVAR USA INC.ISSUE DATE:2011-12-21 Annotation:
MSDS NO:OX76685 VERSION:010 2014-03-18 COMPANY IDENTITY:
Univar PRODUCT IDENTITY:
Liquichiso 10-16% (Sodium Hypochsorite 10-16%)DATE: 12/21/11 PAGE: 1 OF 8 SAFETY DATA SHEET This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements and the International Chemical Safety Cards of the Global Harmonizing System.THIS SOS COMPLIES WITH 29 CFR 1910,1200 (HAZARD COMMUNICATION STANDARD)IMPORTANT:
Read this SOS before handling & disposing of this product.Pass this information on to employees, customers, & users of this product.SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER PRODUCT IDENTITY: SDS NUMBER: NEW MSDS DATE: COMPANY IDENTITY: COM1PANY ADDRESS: COMPANY CITYýCOMPANY PHONE: EMERGENCY PHONES: Liquichlor 10-16% (Sodium Hypochlorite 10-16%)OX76685 12/21/2011 Univar 17425 NE Union Hill Road Redmond, WA 98052 1-425-889-3406 CHEMTREC:
1-800-424-9300 (USA)CANUTEC: 1-613-996-6666 (CANADA)SECTION 2. HAZARDS IDENTIFICATION DANGERI!EXPOSURE PREVENTION:
STRICT HYGIENEI AVOID ALL CONTACTI RISK STATEMENTS:
R35 Causes severe burns.RS Very toxic to aquatic organisms.
SAFETY STATEMENTS:
51/2 Keep locked up-and.out of the reach of children....
.........2 4 / 2 5 -ý ....-A v di d c o n ta ~ t '` w t ' ii n f1' -d_ y le n ..........
".... ... ....... ........S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
526 In case of contact With eyes, rinse immediately with plenty of water and seek medical advice.S28 After contact with skin, wash immediately with plenty of water.S45 In case of accident, or if you feel unwell, seek medical advice immediately. (Show the label where possible).
561 Avoid release to the environment.
Refer to special instructions/safety data sheet.SECTION 3. COM1POSITION/INFORMAATION ON INGREDIENTS MATERIAL Water Sodium Hypochlorite Sodium Hydroxide CAS#7732-18ý5 7681-52-9 1310-73-2 EINECS#231-791-2 WT %84-98*c 16<= 1.75 Trace components:
Trace ingredients (if any) are present in 4 1% concentration, (c 0.1% for potential carcinogens, reproductive toxins, respiratory tract mutagens, and sensitizers).
None of the trace ingredients contribute significant additional hazards at the concentrations present in this product. All pertinent hazard information has been provided in this document, per the requirements of the Federal Occupational Safety and Health Administration Standard (29 CFR 193.6.1200), U.S. State equivalents, and Canadian Hazardous Materials Identification System Standard (CPR 4).SEE SECTIONS 8, 11 8 12 FOR TOXICOLOGICAL INFORMATION.
Attachment NOC-AE-14003142 Page 112 of 155 UNIVAR USA INC. MSDS NO:OX76685 ISSUE DATE:2011-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
Liquichlor 10-16% (Sodium Hypochlorite 10-16%) PAGE: 2 OF 8 SECTION 4. FIRST AID MEASURES EYE CONTACT: If. this product enters the eyes, open eyes while under gently running water. Use sufficient force: to open eyelids. "Roll" eyes to expose more surface. Minimum flushing is for 15 minutes. Seek immediate medical attention.
SKIN CONTACT: If the product contaminates the skin, immediately begin decontamination with running water. Minimum flushing is for 15 minutes. Remove contaminated clothing, taking care not to contaminate eyes. If skin becomes irritated and irritation persists.
medical attention-iffi-e -n--e-f9s-. i discard c0ntaminatid shoes, INHALATION:
After high vapor exposure, remove to fresh air. If it is suspected that fumes, are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.
Keep person warm and at rest. breathing is difficult, give oxygen. If breathing has stopped, trained personnel should immediately begin artificial respiration.
It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
If unconscious, place in recovery position and get medical attention immediately..
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
If the heart has stopped, trained personnel should immediately begin cardiopulmonary resuscitation (CPR). Seek immediate medical attention.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br />.SWALLOWING:
If swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION.
If professional advice is not available, give two glasses of water to drink. DO NOT INDUCE VOMITING.
Never induce yomiting or give liquids to someone who is unconscious, having convulsions, or unable to swallow. Seek immediate medical attention.
NOTES TO PHYSICIAN:
There is no specific antidote.
Treatment of overexposure should be directed at the control..m...ri.....
.....o..f-.sympdtrs.-andthe.,clinica.ondiionf-thezpatient.
Anymatleriaaspirated.!u
...in g vomiting may cause lung injury. Therefore, emesis :should not be induced mechanically or pharmacologically.
If it is considered necessary to evacuate the stomachlcontents, this should be done by means least likely to cause aspiration (such as: Gastric lavage after endotracheal intubation).
Victims of chemical exposure must be taken for medical attention.
Rescuers should be taken for medical attention, if necessary.
Take a copy of label and SDS to physician or health professional with victim.SECTION 5. FIRE FIGHTING MEASURES FIRE & EXPLOSION PREVENTIVE MEASURES Not Applicable.
EXTINGUISHING MEDIA Use dry powder, foam, carbon dioxide, water spray, halon, or any "ABC" Class extinguisher.
SPECIAL FIRE FIGHTING PROCEDURES Water spray may be ineffective on fire but can protect fire-fighters
& cool closed containers.
Use fog nozzles if water is used.Do not enter confined fire-space without full bunker gear.(Helmet with face shield, bunker coats, gloves & rubber boots).Use NIOSH approved positive-pressure self-contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES Noncombustible.
Isolate from reducers, acids, wood, organic materials, and most metals.Oxidizer fumes damage lungs. Symptoms may be delayed. Do not breathe fumes.
Attachment NOC-AE-14003142 Page 113 of 155 UNIVAR USA INC. MSDS NO:OX76685 ISSUE DATE:2011-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
Liquichlor 10-16% (Sodium Hypochlorite 10-16%) PAGE: 3 OF 8 SECTION 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE AND ENVIRONMENTAL PRECAUTIONS:
Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and respond with trained personnel.
PERSONAL PROTECTIVE EQUIPMENT The proper personal protective equipment for incidental releases (such as: I Liter of the product released in a well-ventilated area), use impermeable gloves (triple-gloves (rubber gloves and nitrile gloves, over latex gloves), goggles, face shield, and appropriate body-ent-o"--arge-4elea se-use-impermeab1e-flve~s-spec-iic-for-the material handled, chemically resistant suit and boots, and hard hat. Self-Contained Breathing Apparatus or respirator may be required where engineering controls are not adequate or conditions for potential exposure exist. When respirators are required, select NIOSH/MSHA approved based on actual or potential airborne concentrations in accordance with latest OSHA and/or ANSI recommendations.
ENVIRONMENTAL PRECAUTIONS:
Stop spill at source. Construct temporary dikes of dirt, sand, or any appropriate readily available material to prevent spreading of the material.
Close or cap valves and/or block or plug hole in leaking container and transfer to another container.
Keep from entering storm sewers and ditches which lead to waterways, and if necessary, call the local fire or police department for immediate emergency assistance.
CONTAINMENT AND CLEAN-UP MEASURES: Absorb spilled liquid with polypads or other suitable absorbent materials.
if necessary,'
neutralize using suitable buffering material, (acid with soda ash or base with phosphoric acid), and test area with litmus paper to confirm neutralization.
Clean up with non-combustible absorbent (suchas: sand, soil, and so on). Shovel up and place all spill residue in suitable containers, dispose of at an appropriate waste disposal facility according to current applicable laws and regulations and product characteristics at time of disposal (see Section 13 -Disposal Considerations).
SECTION 7. HANDLING AND STORAGE HANDLING Use only with adequate ventilation.
Do not get in eyes, on skin or clothing.Wear OSHA Standard full face shield. Consult Safety Equipment Supplier.
Wear goggles, face shield, gloves, apron & footwear impervious to material.
Wash clothing before reuse, NEVER pour water into this substance.
When dissolving or diluting, always add it slowly to the water.To minimize static discharge when transferring, ensure electrical continuity by bonding and grounding all equipment.
Use an inlet line diameter of at least 3.5 inches (8.9 centimeters) with a maximum flow rate of I meter/second.
STORAGE Keep separated from strong oxidants, strong acids, combustible
& reducing substances, metals, food & feedstuffs.
Keep cool. Keep dry. Keep in the dark. See: Section 10, (Materials to Avoid>. Do not store above 49 C/120 F. Keep container tightly closed& upright when not in use to prevent leakage.Wear full face shield, gloves & full protective clothing when opening or handling.When empty, drain completely, replace bungs securely.NONBULK: CONTAINERS:
Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible.
Material should be stored in secondary containers or in a -diked area, as appropriate.
Store containers away from incompatible chemicals (see Section 10, Stability and Reactivity).
Post warning and "NO SMOKING" signs in storage and use areas, as appropriate.
Empty containers should be handled with care. Never store food, feed, or drinking water in containers which held this product.BULK CONTAINERS:
All tanks and pipelines which contain this material must be labeled. Perform routine maintenance on tanks or pipelines which contain this product. Report all leaks immediately to the proper personnel.
Attachment NOC-AE-14003142 Page 114 of 155 UNIVAR USA INC. MSDS NO:OX76685 ISSUE DATE:2011-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
Liquichlor 10-16% (Sodium Hypochlorite 10-16%) PAGE: 4 OF 8 SECTION 7. HANDLING AND STORAGE (CONTINUED)
TANK CAR SHIPMENTS:
Tank cars carrying this product should be loaded and unloaded in strict accordance with tank-car manufacturer's recommendation and all established on-site safety procedures.
Appropriate personal protective equipment must be used (see Section 8, Engineering Controls and Personal Protective Equipment.).
All loading and unloading equipment must be inspected, prior to each use. Loading and unloading operations must be attended, at all times. Tank cares must be level, brakes must be set or wheels must be locked or blocked prior to loading or unloading.
Tank car (for loading) or storage tanks (for unloading) must be verified to be correct for receiving this product and be properly prepared,------
n-ch--ppe t positions, before starting transfer operations.
A sample (if required) must be taken and verified (if required) prior to starting transfer operations.
All lines must be blown-down and purged before disconnecting them from the tank car or vessel.PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT:
Follow practices indicated in Section 6 (Accidental Release Measures).
Make certain application equipment is locked and tagged-out safely. Always use this product in areas where adequate ventilation is provided.
Collect all rinsates and dispose of according to applicable Federal, State, or local procedures.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION MATERIAL CAS# EINECS# TWA (OSHA) TLV (ACGIH)Water 7732-18-5 231-791-2 None Known None Known Sodium Hydroxide 1310-73-2
-2 mg/m3 None known Sodium Hypochlorite 7681-52-9
-None Known None Known MATERIAL CAS# EINECS# CEILING STEL(OSHA/ACGIH)
HAP Sodium Hydroxide 1310-73-2
-2 mg/m3 None Known No This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1%.RESPIRATORY EXPOSURE CONTROLS b l&ti 65ý00'su-re lmits ..i Ven 51Y6Ve- .-I respiratory protection is needed, use only protection authorized in 29 CFR 1910.134, European Standard EN 149, or applicable State regulations.
If adequate ventilation is not available or there is potential for airborne exposure above the exposure limits, a respirator may be worn up to the respirator exposure limitations, check with respirator equipment manufacturer's recommendations/limitations.
For a higher level of protection, use positive pressure supplied air respiration protection or Self Contained Breathing Apparatus or if oxygen levels are below i9.5% or are unknown.EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS Positive pressure, full-face piece Self Contained Breathing Apparatus; or positive pressure, full-face piece Salf Contained Breathing Apparatus with an auxilliary positive pressure Self Contained Breathing Apparatus..
VENTILATION LOCAL EXHAUST: Necessary MECHANICAL (GENERAL):
Necessary SPECIAL: None OTHER: None Please refer to ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most. recent edition, for detailsi EYE PROTECTION:-Splash goggles or safety glasses. Face-shields are recommended when the operation can generate splashes, sprays or mists.HAND PROTECTION:
Wear appropriate impervious gloves for routine industrial use. Use impervious gloves for spill response, as stated in Section 6 of this SDS (Accidental Release Measures).
Attachment NOC-AE-14003142 Page 115 of 155 UNIVAR USA INC. MSDS NO:OX76685 ISSUE DATE:2011-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
Liquichlor 10-16% (Sodium Hypochlorite 10-16%) PAGE: 5 OF 8 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED)
NOTICE: The selection of a specific glove for a particular application and duration of use in a. workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.BODY PROTECTION:
Use body protection appropriate for task. Cover-all, rubber aprons, or chemical protective.clothing made from impervious materials are generally acceptable, depending on the task.WORK & HYGIENIC PRACTICES:
Provide readily accesslble eye wash stations &"'safety showers.Wash at end of each workshift
& before eating, smoking or using the toilet.Promptly remove clothing that becomes contaminated.
Destroy contaminated leather articles.
Launder or discard contaminated clothing.SECTION 9. PHYSICAL & CHEMICAL PROPERTIES APPEARANCE:
Liquid, Clear, Yellow to Yellow-Green ODOR: Chlorine-like, Pungent ODOR THRESHOLD:
0.3 ppm (detection), for Chlorine pH (Neutrality):
12 -14 (1%.Solution)_
MELTING POINT/FREEZING POINT: -27 C / -17 F BOILING RANGE (IBP,5.0%,Dry Point): 140 C / 284 F FLASH POINT .(TEST METHOD): Not Applicable EVAPORATION RATE (n-BUTYL ACETATE=I):
Not Applicable FLAMMABILITY CLASSIFICATION:
Non-Combustible LOWER FLAYUMABLE LIMIT IN AIR (% by vol): Not Applicable UPPER FLA&MABLE LIMIT IN AIR (% by vol): Not Available VAPOR PRESSURE (mm of Hg)@20 C 12 (12.5% Solution)VAPOR DENSITY (air=l): .0.670 GRAVITY @ 68/68 F / 20/20 C: SPECIFIC GRAVITY (Water=l):
1.17 -1,22 POUNDS/GALLON:
9.75 -10.20 PARTITION COEFFICIENT (n-Octane/Water):
Not Available AUTO IGNITION TEMPERATURE:
Not Applicable DECOMPOSITION TEMPERATURE:
Not Available VOC'S (>e,44 Lbs/Sq In) : 0.0 Vol% /0.0 g/L / 0.000 Lbs/Gal TOTAL VOC'S (TVOC)*: 0.0 Vol% /0.0 g/L / 0.000 Lbs/Gal NONEXEMPT VOC'S (CVOC)*: 0.0 Vol% /0.0 g/L / 0.000 Lbs/Gal HAZARDOUS AIR POLLUTANTS (HAPS): 8.8 Wt9 /0.0 g/L / 0.000 Lbs/Gal NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg Q 20 C) 0.0 Using California South Coast Air Quality Management District (SCAQMD) Rule 443.1.SECTION 10. STABILITY
& REACTIVITY STABILITY Stable under normal conditions.
CONDITIONS TO AVOID Isolate from extreme temperatures and incompatible chemicals.
MATERIALS TO AVOID Reacts violently with fire extinguishers containing water. The substance is a strong base, reacts violently with acids and is corrosive.
Decomposes on heating and on contact with strong acids, (such as sulfuric acid) producing, toxic & corrosive fumes including, chlorine, phosgene, & hydrogen chloride.
The. substance is a strong oxidant & reacts violently with combustible
& reducing materials.
Reacts with water generating sufficient heat to ignite combustible materials.
Reacts violently with strong acids, causing fire &explosion hazard. Attacks many plastics, rubber, coatings, many metals, such as aluminum,.zinc, tin, & lead. forming flammable/explosive gas (hydrogen).
Reacts with ammonium salts to produce ammonia & causing fire hazard.Rapidly absorbs carbon dioxide & water from the air.
Attachment NOC-AE-14003142 Page 116 of 155 UNIVAR USA INC. MSDS NO:OX76685 ISSUE DATE:2011-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
Liquichlor 10-16% (Sodium Hypochlorite 10-16%) PAGE: 6 OF 8 SECTION 10. STABILITY
& REACTIVITY (CONTINUED)
HAZARDOUS DECOMPOSITION PRODUCTS Hydrogen Chloride, Phosgene, Sodium Oxide & Hydroxide from heating.HAZARDOUS POLYMERIZATION Will not occur.SECTION 11. TOXICOLOGICAL INFORMATION ACUTE HAZARDS EYE & K-FKN--CON'TA-T:
Severe burns to skin, defatting, dermatitis.
Severe burns to eyes, redness, tearing, blurred vision.Liquid can cause severe skin & eye burns. Wash thoroughly after handling.INHALATION:
Severe respiratory tract irritation may occur. Vapor harmful. The applicable occupational exposure limit value should not be exceeded during any part of the working exposure.SWALLCWING:
Harmful or fatal if swallowed.
SUBCHRONIC HAZARDS/CONDITIONS AGGRAVATED CONDITIONS AGGRAVATED:
Sodiumn Hypochlorite, a component of this product, is a sensitizer.
Prolonged or repeated skin contact can result in the development of rashes, welts, and other allergy-like symptoms.CHRONIC HAZARDS CANCER, REPRODUCTIVE
& OTHER CHRONIC HAZARDS: This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA or ACGIH, as of this date,..gpreeater rqual to 0.1%. ...MUTAGENICITY:
This product is not reported to produce mutagenic effects in humans.Human mutation data are available for Sodium Hypochlorite (a component of this product);these data were obtained during clinical studies involving specific tissues exposed to relatively high concentrations of this substance.
Mutation data, obtained during clinical studies on test animal tissues or micro-organisms are available for Potassium Hydroxide.
EMBRYOTOXICITY:
This product is not reported to produce embryotoxic effects in humans.TERATOGENICITY:
This product is not reported to produce teratogenic effects in humans.REPRODUCTIVE TOXICITY:
This product is not reported to cause reproductive effects in humans.A mutaen is a chemical which causes permanent changes "to genetic material (DNA) such that the changes will propagate through generational lines. An embrvotoxin is a chemical which causes damage to a developing embryo (such as: within the eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does no-tpropagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process.MAMMALIAN TOXICITY INFORMATION SODIUM HYDROXIDE:
Eye irritancy (monkey):
1%, 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> (severe)Eye irritancy (rabbit):
500 ml, 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> (severe)Eye irritancy (rabbit):
1% solution (severe)Eye irrItancy (rabbit):
I .mg, 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> (severe)Cytogenic analysis system (grasshopper parenteral):
20 mg LD50 (interperoneal, mouse): 48 mg/kg LDLo (oral, rabbit): 500 mg/kg Attachment NOC-AE-14003142 Page 117 of 155 UNIVAR USA INC. MSDS NO:OX76685 ISSUE DATE:2011-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
Liquichlor 10-16% (Sodium Hypochlorite l1-16%) PAGE: 7 OF 8 SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED).
MAMMALIAN TOXICITY INFORMATION (CONTINUED)
SODIUM HYPOCHLORITE:
Eye effects (Adult Rabbit): Moderate irritation effects.Microsomal Mutageniticity Assay (Salmonella typhimunium):
1 mg/plate Cytogenetic Analysis (Human): Lymphocyte, ie0 ppm/24 hours.TDLo, Oral (woman): I g/kg, Central nervous system effects, blood pressure effects TDLo, Intravenous (Man): 45 mg/kg, Pulmonary system , LD50 (Oral, Mouse): 5800 mg/kg.--.--.--S -SECT1ON-12E COLOGICAL-INFORt4AT-ION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
EFFECT OF MATERIAL ON PLANTS OR ANIMALS: This product may be harmful or fatal to plant and animal life if released into the environment.
Refer to Section 11 (Toxicological Information) for further data on the effects of this product's components on test animals.EFFECT OF MATERIAL ON AQUATIC LIFE: LCSB (Bluegill sunfish):
2.90 mg/L/96 hours LC50 (Pimephales promelas):
1.40 mg/L/96 hours LCS5 (Oncorhynchus mykiss): 0.90 mg/L/0.5 hours5.787037e-5 days <br />0.00139 hours <br />8.267196e-6 weeks <br />1.9025e-6 months <br /> The substance is toxic to aquatic organisms.
The substance may be hazardous in the environment, Special attention should be given to water organisms.
MOBILITY IN SOIL Mobility of this material has not been determined.
DEGRADABILITY This product is completely biodegradable.-ACCUMULAT ION -................
........ ................
...... ---------Bloaccumulation of this product has not been determined.
SECTION 13. DISPOSAL CONSIDERATIONS Processing, use or contamination may change the waste management options.Recycle / dispose of observing national, regional, state, provincial and local health, safety & pollution laws. If in doubt, contact appropriate agencies.SECTION 14. TRANSPORT INFORMATION IF > 625 LB / 284 KG OF. THIS PRODUCT IN I CONTAINER, IT EXCEEDS THE "RQ" OF SODIUM HYPOCHLORITE.
DOT SHIPPING NAME: UN1791, Hypochlorite Solutions, B, PG-Irl DRUM LABEL: (CORROSIVE)
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 154 Attachment NOC-AE-14003142 Page 118 of 155 UNIVAR USA I NC. MSDS NO:OX76685 ISSUE DATE:201 1-12-21 VERSION:010 2014-03-18 Annotation:
COMPANY IDENTITY:
Univar DATE: 12/21/11 PRODUCT IDENTITY:
OX76685 PAGE: 8 OF 8 SECTION 15. REGULATORY INFORMATION EPA REGULATION:
SARA SECTION 311/312 HAZARDS: Acute Health All components of this product are on the TSCA list, This material contains no known products restricted under SARA Title III, Section 313 in amounts greater or equal to 1%.SARA TITLE III INGREDIENTS CAS# EINECS# WT% (REG.SECTION)
RQ(LBS)Sodiun Hypochlorite 7681-52-9
-<,16 (311,312) lee Sodium Hydroxide 1310-73-2
-. __.. ..> 625 LB / 284 KG OF THIS PRODUCT IN 1 CONTAINER EXCEEDS THE "RQ' OF SODIUM HYPOCHLORITE.
Any release equal to or exceeding the RQ must be reported to the National Response Center (800-424-8802) and appropriate state and local regulatory agencies as described in 40 CFR 302.6 and 40 CFR 355..40 respectively.
Failure to report may result in substantial civil and criminal penalties, State & local regulations may be more restrictive than federal regulations, STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: This product contains no chemicals known to the State of California to cause cancer & reproductive toxicity.U.S. STATE REGULATED COMPONENTS: (HAZARDOUS SUBSTANCE LISTS)::OMPONENT AK CA F.L IL KS MA HI MN Sodium Hypochlorlte No No No Yes No No No No Sodium Hydroxide Yes Yes Yes Yes Yes Yes Yes Yes:OMPONENT MO NJ ND PA RI TX WV WI Sodium Hypochlorite No Yes Yes No No No No No Sodium Hydroxide Yes Yes Yes Yes Yes Yes Yes Yes INTERNATIONAL REGULATIONS The components of this product are listed on the chemical inventories of the... .Qllowngcountries.:.,-...-
...... ... ...........
Australia (AICS), Canada (DSL, NDSL), China (IECSC), Europe (EINECS, ELINCS)J Japan (METI/CSCL, MHLW/ISHL), South Korea (KECI), New Zealand (NZIoC), Philippines (PICCS), Switzerland (SWISS), Taiwan (NECSI), USA (TSCA).CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)*C: Oxidizing Material.D2B: Irritating to skin / eyes.E: Corrosive Material.SECTION 16. OTHER INFORMATION HAZARD RATINGS: HEALTH .(NFPA): 3, HEALTH (HMIS): 3, FLAMMABILITY:
8, REACTIVITY:
1 (Personal Protection Rating to be supplied by user based on use conditions.)
This information is intended solely for the use of individuals trained in the NFPA & HMIS hazard rating systems.EMPLOYEE TRAINING See Section 2 for Risk & Safety Statements.
Employees should be made aware of all hazards of this material (as stated in this SDS) before handling it.
Attachment NOC-AE-14003142 Page 119 of 155 Univar USA Inc Material Safety Data Sheet For Additional Information contact. MSDS Coordinator during business hours, Pacific time: (425) 889-3400 Notice Univar USA Inc. ("Univar")
expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein, and shall under no circumstances be liable for Incidental or consequential damages.Do not use ingredient information and/or ingredient percentages In this MSDS as a product specification.
For product specification Information refer to a product specification sheet and/or a certificate of analysis.
These can be obtained from your local Univar sales office.All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the Information is believed to be accurate, Univar makes no representations as to its accuracy or sufficiency.
Conditions of use are beyond Univar's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, Information contained herein.This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process Attachment NOC-AE-14003142 Page 120 of 155.P4LCO SAFETY DATA SHEET , -/b (PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300(24 Hours) CHEMTREC I 1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: APPLICATION
- NALCO 1359 PLUS CORROSION INHIBITOR COMPANY IDENTIFICATION:
Nalco Company 1601 W. Diehl Road Naoerville.
Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):
(800) 424-9300 (24 Hours) CHEMTREC NFPA 704MIHMIS RATING HEALTH: 313 FLAMMABILITY:
0/0 INSTABILITY:
010 OTHER: 0 = Insignificant 1 =Slight. 2 =Moderate 3 =High 4 =Extreme * =Chronic Health Hazard I 2. .I COMPOSITIONIINFORMATION ON INGREDIENTS I I Our hazard evaluation has Identified the following chemical substance(s) as hazardous.
Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s)
Sodium Nitrite Sodium Metaborate CAS NO 7632-00-0 7775-19-1% (w/w)10.0- 30.0 5.0- 10.0 13..HA.ADS...N I C.T......
.. --.~EMERGENCY OVERVIEW" DANGER Toxic if swallowed.
Irritating to eyes and skin. Contains sodium nitrite. Substances In the product can lead to the formation of methemoglobin.
Unborn children are particularly sensitive to methemoglobinemia.
Do not get in eyes, on skin, on clothing.
Do not take internally.
Use with adequate ventilation.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash Immediately with plenty of water.Wear suitable protective clothing.Not flammable or combustible.
May evolve oxides of nitrogen (NOx) under fire conditions.
If product is allowed to dry, the sodium nitrite is an oxidizing agent and can Initiate the combustion of other materials.
PRIMARY ROUTES OF EXPOSURE: Eye, Skin HUMAN HEALTH HAZARDS -ACUTE: EYE CONTACT: .Irritating, and may injure eye tissue if not removed promptly.Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit wwv.nalco.com and request access.1110 I Attachment NOC-AE-14003142 Page 121 of 155 SNALCO SKiN CONTACT::Can cause mild Irritation.
SAFETY DATA SHEET NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300(24 Hours) CHENTREC INGESTION:
Not a likely route of exposure.
Large exposures may be fatal. Ingestion of sodium nitrite can cause methemoglobinemia which can lead to cyanosis and possible death. Pregnant women and their fetuses are particularly sensitive to the effects of methemoglobinemia.
IN HALATIO N : --_-U -_ ___ ___ ____ ___ ___ __r Not alikely route otexposure.
Aeri6tsoTs r t-6ra6cf til nTa-fle t"pe pT ct.SYMPTOMS OF EXPOSURE: Acute : A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic A review of available data does not identify any symptoms from exposure not previously mentioned, AGGRAVATION OF EXISTING CONDITIONS:
Sodium Nitrite. Pregnant women are particularly sensitive to methemoglobinemia.
HUMAN HEALTH HAZARDS -CHRONIC: Repeated ingestion of small amounts of sodium nitritecauses drops In blood pressure, rapid pulse, headaches and visual disturbances.
It may also reactwith organic amines in the body to form carcinogenic nitrosamines.
- 14. 1FIRST AID MEASURES EYE CONTACT: Immediately flush eye with water for at least 15 minutes while ho!ding eyelids open. If irritation persists, repeat.. ... .. ....fl ush ln gT-G thid t la thdoi. .. .... ......a ..............
...... ... .. .. ............................
.. .. .... .:... ... '.. .. ..SKINCONTACT:
Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician, INGESTION:
Do not induce vomiting without medical advice. If conscious, washout noutlh and give water to drink. Get Immediate medical attention.
INHALATION:
Remove to fresh air, treat symptomatically.
If symptoms develop, seek medical advice.NOTE TO PHYSICIAN:
Based an the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
Measures against circulatory shock, respiratory depression and convulsions may be needed.Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198-(630)305.1000 For additional copies of an MSDS visit www.nalco.com and request access.2110 Attachment NOC-AE-14003142 Page 122 of 155-ýtNImA LCO `SAFETY DATA SHEET PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)1800) 424-9300 (24 Hours) CHEMTREC I S. I FIRE FIGHTING MEASURES I 15. 1 FIRE FIGHTING MEASURES I FLASH POINT: None EXTINGUISHING MEDIA: Not expected to bum. Use extinguishing media appropriate for surrounding fire.FIRE AND EXPLOSION HAZARD:.Not flammable or combustibNI7 May evolve oxides.of nitrogen (NOx) under tire conditions.
If product is allowed to dry, the sodium nitrite Is an.oxidizing agent and can initiate the combustion of other materials.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: In case of fire, wear a full face positive-pressure.self contained breathing apparatus and protective suit.16. 1 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operationsi are complete.
Ensure clean-up it conducted by trained personnel only. Ventilate spill area if possible.
Do not touch spilled material.
Stop or reduce anyleaks if It is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Personal Protection).
Notify appropriate government, occupational health and safetyand environmental authorities.
METHODS FOR CLEANING UP: SMALL SPILLS:. Soakup spill with absorbent material, Place residues in a suitable, covered, properly labeled container.
Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim Into recovery or salvage drums or tank truck for proper disposal.
Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material.
Dispose of material in..... ... ....................
6MP It66WMiiia hii i -ed di-S i6- 13-(D -e tikoi .............
ENVIRONMENTAL PRECAUTIONS:
Do not contaminate surface.water.
7i HANDLING ANDSTORAGE HANDLING: Do not get in eyes, on sklnj on clothing.
Do not take internally.
Use with adequate ventilation.
Do not breathe vapors/gases/dust.
Keep the containers closed when not In use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Ensure all containers are labeled.STORAGE CONDITIONS:
Store the containers tghUy closed. Store in suitable labeled containers, Store separately from acids. Store separately from reducing agents.1 8. 1 EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: This product does not contain any substance that has an established exposure limit.Nalco Company 1601 W. Diehl Road 'Naperville, Illinois 60563-1198, (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.3110 Attachment NOC-AE-14003142 Page 123 of 155 NANALCO SAFETY DATA SHEET PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(B00) 424-$300 (24 Hours) CHEMTREC ENGINEERING MEASURES: General ventilation is recommended.
RESPIRATORY PROTECTION:
Respiratory protection is not normally needed.HAND PROTECTION:
......
work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from Neoprene PVC or nitrite Gloves should be replaced immediately If signs of degradation are observed.
'Breakthrough time not determined as preparation, consult PPE manufacturers.
SKIN PROTECTION:
When handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended.
A full slicker suit Is recommendedif gross exposure is possible.EYE PROTECTION:
Wear chemical splash goggles.HYGIENE RECOMMENDATIONS:
Use good work and personal hygiene practices to avoid exposure.
Keep an eye wash fountain available.
Keep a safety shower available, If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse, Always wash thoroughly after handling chemicals, When handling this product never eat, drink or smoke.HUMAN EXPOSURE CHARACTERIZATION:
Based on our recommended product application and personal protective eq.uipment the potentialhuman exposure Is:.S...Mod edrte --.. .'........
- 19. 1 PHYSICAL AND CHEMICAL PROPERTIES.PHYSICAL STATE APPEARANCE Liquid Light yellow ODOR SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER pH (100 %)VISCOSITY FREEZING POINT VAPOR PRESSURE 1.305 @ 72 -F 122.2 -C 10.84 lb/gal Complete>= 11.4 Max 7 cps @ 73 °F 122.8 *C<.-50 OF 1-45.5 QC Same as water Note: These physical properties are typical values for this product and are subject to change.Nalco Company 1601 W. Diehl Road
- Napervltle, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.4/10 Attachment NOC-AE-14003142 Page 124 of 155 N NALC0 10. STABILITY AND REACTIVITY STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION; Hazardous polymerization will not occur.SAFETY DATA SHEET PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(800) 424.9300(24 Hours) CHEMTREC*CONDIrONSWTO-AvOlD.
Freezing temperattres.
Do not allow product to evaporate to dryness. Dried product residue can act as an oxidizer.MATERIALS TO AVOID: Contact with reducing agents (e.g. hydrazine, sulfites, sulfide, aluminum or magnesium dust) may generate heat, fires, explosions and tOXic vapors. Do not mix with amines, Sodium nitrite can react with certain amines to produce N-nitrosamines, Many of which are cancer-causing agents to laboratory animals. Contact with strong acids (e.g.sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonlc) may generate heat, splattering or boiling and toxic vapors.HAZARDOUS DE(OOMPOSITION PRODUCTS :.Under fire conditiolis:
Oxides of nitrogen 11. 1 ToXI-_LOGICAL INFORMATION No toxicity studies have been conducted on this product.SENSITIZATION
- This product Is not expected to be a sensitizer.
None of the substances In this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the Nationcl Toxicology Program (NTP) or the American Conference of Governmental Industrial.
Hygienists (ACGIH)..HUMAN HAZARD CHARACTERIZATION:
Based on bur hazard characterization, the potential human hazard is: High 12. 1 ECOL-GICAL INFORMATION ECOTOXICOLOGICAL EFFECTS: No toxicity studies have been-conducted on this product.MOBILITY: The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program ineace) Suite TM, provided by the US EPA. The Model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the .defined media. The informtation provided is intended to give th user a general estimate of the environmental fate of this productunder the defined conditions of the models, NA0o Co'mpany 1601 W. Diehl Road Naperville, Illinois 60563.1198
' (630)305-1000 For additional copies of an MSDS visit wvw.nalco.com and request access.5110 Attachment NOC-AE-14003142 Page 125 of 155) 4 NOA LL'0 SAFETY DATA SHEET PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC If released Into the environment this material Is expected to distribute to the.air, water and scil/sediment in the approximate respective percentages; Air WtrSoil/Sediment
<5% 30-50% 50-70%The portion in water is expected to be soluble or dispersible.
ENVIRONMENTA.-TAZ'AR DAN 1EXPO SURE-CH AP,-TER IZAT-10 Based on our hazard characterization, the potential environmental hazard is: Moderate Based on our recommended product application and the product's characteristics, the potential environmental exposure Is: High If released Into the environment, see CERCLA/SUPERFUND in Section 15.I 13. I DISPOSAL CONSIDERATIONS I If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, Before disposal, It should be determined If the waste meets the criteria of a hazardous waste, Hazardous Waste: D002 Hazardous wastes must be transported by e licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility.
Consult local, state, and federal regulations for specific requirements.
i RTRANSPORTINFORMATION
.- .."----.-The Information In this section is for reference only and should not take the place of a shipping paper (bill of lading)specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, and mode of transportation.
Typical Proper Shipping Names oe this product are as follows.LAND TRANSPORT:
Proper Shipping Name: Technical Name(s): UN/ID No: Hazard Class -Primary: Hazard Class -Secondary:
Packing Group: Flash Point: Reportable Quantity (per package): RQ Component:
AIR TRANSPORT (ICAOIIATA):
Proper Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S SODIUM NITRITE UN 2922 8 6.1 III None 430 lbs SODIUM NITRITE CORROSIVE LIQUID. TOXIC, NO.S Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
(-630)305-1000 For additional copies of an MSDS visit www, nalco.com and request access.6110 Attachment NOC-AE-14003142 Page 126 of 155~N A LUC= 0 SAFETY DATA SHEET PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300(24 Hours) CHEMTREC Technical Name(s): UNIID No: Hazard Class -Primary: Hazard Class -. Secondary:
Packing Group: Reportable Quantity (per package): RQ Component:
MARINE TRANSPORT (IMDG/IMO):
SODIUM NITRITE UN 2922 8 6.1 III 430 lbs SODIUM NITRITE P-operShipping-Name
- Technical Name(s): UNIID No: Hazard Class -Primary: Hazard Class -Secondary:
Packing Group:-CORROSIVE-LIQUID;-TOXIG,-.G-.S SODIUM NITRITE UN 2922 8 6.1 III I 15. I REGULATORY INFORMATION I This section contains additional Information that may have relevance to regulatory compliance.
The information in this section is for reference only. It Is not exhaustive, and should no' be relied Upon to take the place of an individualized compliance or hazard assessment.
Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA: OSHA HAZARD COMMUNICATION RULE, .29 CFR 1910.1200:
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) islare shown below.So.Ndium.Nt.te
..:-TargtO.Qrga-Enffe L-;.I.doey,Target-Organ:Effect ,Nervous~systemTarget:Organ.Effect:.,:-loodI.;
Sodium Metaborate.:
Irritant CERCLA!SUPERFUNDO 40 CFR 302: This product contains the following Reportable Quantity (RO) Substance.
Also listed is the RO for the product.*RO.Substance Sodium Nitrte B2q 430 Ibis SARANSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) -SECTIONS 302, 311, 312t AND 313: SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 -MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous.
The product should be reported under the following indicated EPA hazard categories:
X Immediate. (Acute) Health HaZard Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visil vvw.nalco.com and request access.7110 Attachment NOC-AE-14003142 Page 127 of 155ýq N'AALC(eO%
SAFETY DATA SHEET PIRODUCT 7'NALCO 1359 PLUS EMERGENCY TELEPHONE NUMSER(S)(800) 424-9300 (24 Hours) CHEMTREC X Delayed (Chronic)
Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals, The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
_-SECLQFj_3J2,_._.L'O.FTQXJC..
HEM.CALS_..CER,371)
" This product contains the following substance(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals Hazardous Substance(s)
CAS NO Sodium Nitrite 7632-00-0 10.0- 30.0 TOXIC SUBSTANCES CONTROL ACT (TSCA): The substances in this preparation are Included on or exempted from. the TSCA 8(b) Inventory (40 CFR 710)FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401A 5 /formerly Sec, 307,40 CFR 116.4 Iformerly Sec. 311: This product contains the following substances listed in the regulation.
Additional components may be unintentionally present at trace levels.Substance(s) s Citations" Sodium Nitrite Sec. 311" Sodium Hydroxide 11 Ozone Depleting Substances)
- Substances listed under this regulation are not Intentionally added or expected to be present In this product. Listed components may be present at trace levels.CALIFORNIA PROPOSITION 65: Substances listedunder California Proposition 65 are not Intentionally added or expected to be present In this product.MICHIGAN CRITICAL MATERIALS:
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.STATE RIGHT TO KNOW LAWS The following substances are disclosed for compliance with State Right to Know Laws: Sodium Nitrite 7632-00-0 Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.8110 Attachment NOC-AE-14003142 Page 128 of 155 SNALCO SAFETY DATA SHEET.PRODUCT NALCO 1359 PLUS EMERGENCY TELEPHONE NUMBER(S)(800) 424-9;300 (24 Hours) CHEMTREC Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Arlel InsightTU CD-ROM Version), Arnel Research Corp., Bethesda, MD.Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS"" CD-ROM Version), Micromedex, Inc., Englewood, CO.IARC Monographs on the Evaluation of [he Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organl tio-rlilet to--A- e-c Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPSTm CD-ROM Version), Micromedex, Inc., Englewood, CO.Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and HumanServices, Public Health Service.Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances.
Occupational Safety and Health Administration (OSHA), (Arlel Insightm CD-ROM Version), Ariel Research Corp., Bethesda, MD.Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS T M CD-ROM Version), Micromedex, Inc., Englewood, CO.Ariel InsightTu (An integrated guide to industrial chemicals covered under major regulatory and advisory programs), North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel.........
C o~q r p ._- --- w ..... ...... ...........
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPSTM CD-ROM Version), Micromedex, Inc., Englewood, CO.Prepared By: Product Safety Department Date Issued: 03/0112012 Version Number: 2.2 Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit wvw.nalco.com and request access.10/10 Attachment NOC-AE-14003142 Page 129 of 155 A4.NALCU`ý SAFETY DATA SHEET PRODUCT NALCO 1359 PLUS.EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC INTERNATIONAL CHEMICAL CONTROL LAWS: CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations, AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification
& Assessment Scheme (NICNAS).EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.
JAPAN All substances In this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the.Existing and New Chemical Substances list (ENCS).KOREA All substances In this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)PHILIPPINES All substances In this product comply with the RepublicAct 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals
& Chemical Substances (PICGS).116. 1 OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures sef te a si -p r6--.Kwvb
.- c.general risk. This Information should provide assistance for your own risk management practices.
We have evaluated our product's risk as follows: 'The human risk Is: Moderate* The environmental risk Is: Moderate Any use inconsistent with our recommendations may affect the risk characterization.
Our sales representative will assist you to determine if your product application Is consistent with our recommendations.
Together we can Implement an appropriate risk management process.This product material safety data sheet provides health and safety information.
The product Is to be used in applications consistent with our product literature.
Individuals handling this product should be informed of the recommended safety precautions and should have access to this Information.
For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to Insure safe workplace operations.
Please consult your local sales representative for any further information.
REFERENCES Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.9/10 Attachment NOC-AE-14003142 Page 130 of 155 AWNALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC 11. 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: NALCO 19H APPLICATION:
COMPANY IDENTIFICATION:
OXYGEN SCAVENGER Nalco Company 1601 W. Diehl Road 60563-1198 EMERGENCY TELEPHONE NUMBER(S):
(800) 424-9300 (24 Hours) CHEMTREC NFPA 704MIHMIS RATING HEALTH: 2/2' FLAMMABILITY:
III INSTABILITY:
0/0 OTHER: 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme Chronic Health Hazard 12. 1 COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has Identified the following chemical substance(s) as hazardous.
Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s)
CAS NO:302-01-2% (w/w)30.0- 60.0 Hydrazine--j-1HAZARDS IDENTIFICATION--
........ ...................
.. ...... .... ... .. ........**EMERGENCY OVERVIEW**
DANGER This product contains hydrazine which is a suspect carcinogen.
Extreme health hazard. Toxic by inhalation, in contact with skin and if swallowed.
Irritating toskin. Risk of serious damage to eyes. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do not get in eyes, on skin, on clothing.
Do not take internally.
Use with adequate ventilation.
Keep container tightly closed and in a well-ventilated place. If respiratory symptoms develop, remove to fresh air, rest, treat symptomatically.
Get medical attention.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Use a mild soap if available.
Wear a face shield, Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.Hydrazine can ignite spontaneously in air in contact with wood, cloth, earth, or other organic materials.
Heat or contact with strong acid can result In the generation of flammable hydrogen gas. May evolve oxides of nitrogen (NOx)under fire conditions.
May evolve ammonia under fire conditions.
May evolve toxic gases or fumes under fire conditions.
Empty product. containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition.
Contact with reactive metals (e.g. aluminum) may result In the generation of flammable hydrogen gas.Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit wAw.nalco.com and request access.1/13 Attachment NOC-AE-14003142 Page 131 of 155 AVNALCO PRIMARY ROUTES OF EXPOSURE: Eye, Skin HUMAN HEALTH HAZARDS -ACUTE: SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC EYE CONTACT: Severe!y irritating.
If not removed promptly, will Injure eye tissue and may result in permanent eye damage.SKIN CONTACT: Prolonged or frequently repeated skin contact may cause. allergic reactions in some individuals.
Toxic in contact wilh skin. May causesevereit-on or tissue damage depending on the length of exposure and the type of first aid administered.
INGESTION:
Not a likely route of exposure.
Toxic if swallowed.
May cause mucosal damage.INHALATION:
Not a likely route of exposure.
Toxic by inhalation.
Vapors extremely Irritating to eyes and respiratory tract. Can cause pulmonary edema. May cause liver and kidney disorder andlor damage.SYMPTOMS OF EXPOSURE: Acute: A review of available data does not Identify any symptoms frorm exposure not previously mentioned.
Chronic: A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
Preexisting eye, skin, and respiratory conditions may be aggravated.
HUMAN HEALTH HAZARDS -CHRONIC: This product contains hydrazine.
The International Agency for Research on Cancer(IARC) has evaluated hydrazine, and found it to be a possible human carcinogen (Group 28) based on sufficient animal data and inadequate human data. Oral administration of hydrazine has produced lung and liver tumors in mice and rats and mammary tumors in mice. Inhalation of hydrazine has produced nasal tumors in rats.14. 1 FIRST AID MEASURES EYE CONTACT: Get immediate medical attention.
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open.SKIN CONTACT: Get Immediate medical attention.
Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing.
Wash off affected area immediately with plenty of water.Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.2/13 Attachment NOC-AE-14003142 Page 132 of 155 PWNALCO SAFETY DATA SHEET PRODUCT NALCOO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC INGESTION:
DO NOT INDUCE VOMITING.
If conscious, washout mouth and give water to drink. Get immediate medical attention.
INHALATION:
Remove to fresh air, treat symptomatically.
Get medical attention.
NOTE TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
- 5. FIRE FIGHTING MEASURES FLASH POINT: > 230 F/1 > 110 'C (PMCC)EXTINGUISHING MEDIA: Not expected to bum. Use extinguishing media appropriate for surrounding fire.FIRE AND EXPLOSION HAZARD: Hydrazine can ignite spontaneously in air in contact with wood, cloth, earth, or other organicmaterials.
Heat or contact with strong acid can result in the generation of flammable hydrogen gas, May evolve oxides of nitrogen (NOx) under fire conditions.
May evolve ammonia under fire conditions.
May evolve toxic gases or fumes under fire conditions.
Empty product containers may contain product residue. Do not pressurize, cut, heat., weld, or expose containers to flame or other sources of ignition.
Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas.SPECIAL:PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete.
Use personal, protective equipment recommended In Section 8 (Exposure Controls/Personal Protection).
Stop or reduce any leaks if it is safe to do so.Ventilate spill area if possible.
Remove sources of ignition.
Ensure clean-up is conducted by trained personnel only.Do not touch spilled material.
Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP.SMALL SPILLS: Do not clean up spills with sawdust, cotton waste or other combustible absorbent materials.
Create a dike or trench to contain material.
Dilute spilled material to about 10% hydrazine with water. Neutralize the diluted hydrazineby slowly adding a 5-8% calcium hypochlorite or sodium hypochlorite (bleach) solution until all the hydrazine has been reacted. Steam and nitrogen gas will be evolved. DO NOT ADD DRY CALCIUM OR SODIUM HYPOCHLORITE TO A HYDRAZINE SPILL. A VIOLENT REACTION MAY RESULT. The neutralized material may be absorbed using clay, sand or commercial absorbent.
Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal, Refer to CERCLA Section 15. Contact of the unneutralized product with certain clays may lead to hydrazine decomposition and release of ammonia. Contact an approved waste hauler for disposal of contaminated Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.3/13 Attachment NOC-AE-14003142 Page 133 of 155 N4 NALC0 SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC recovered material.
LARGE SPILLS: Dike to prevent further movement.
Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
Do not contaminate surface water.17. 1 HANDLING AND STORAGE HANDLING: Do not get In eyes, on skin, on clothing.
Do not take internally.
Use with adequate ventilation.
Do not breathe vaporsigasesldust.
Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Ensure all containers are labeled. Do not mix with acids. Do not use, store, spill or pour near heat, sparks or open flame. Handle the material under an inert atmosphere of nitrogen or argon.STORAGE CONDITIONS:
Store the containers tightly closed. Store separately from oxidizers.
Store away from organic materials.
Store in suitable labeled containers.
Store away from heat and sources of ignition.
Keep away from light, direct sunlight.Empty spaces in tanks must be filled by inert atmosphere.
SUITABLE CONSTRUCTION MATERIAL: Polypropylene, Polyethylene, Stainless Steel 304, Stainless Steel 316L, Compatibility with Plastic Materials can vary;we therefore recommend that compatibility is tested prior to use.UNSUITABLE CONSTRUCTION MATERIAL: Copper, Brass, Aluminum Ef8--iEXPOSURE
......OCCUPATIONAL EXPOSURE LIMITS: Exposure guidelines have not been established for this, product, Available exposure limits for the substance(s) are:shown below.Substance(s)
Hydrazine CatagofV: ACGIHITWA ACGII-tSkln' OSHA ZI/PEL 0SHA Z1/SkhV*ppm 0.01 1 Unit 1.3* Can be absorbed through the skin.ENGINEERING MEASURES: General ventilation Is recommended.
Use local exhaust ventilation If necessary to control airborne mist and vapor.Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.4113 Attachment NOC-AE-14003142 Page 134 of 155~N ALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300(24 Hours) CHEMTREC RESPIRATORY PROTECTION:
Where concentrations in air may exceed the limits given in this section or when significant mists, vapors, aerosols, or dusts are generated, an approved air purifying respirator equippedwith suitable filter cartridges Is recommended.
consult the respirator
/ cartridge manufacturer data to verify the suitability of specific devices. In event of emergency of planned entry Into unknown concentrations a positive pressurefull-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
When handling this product, the use of chemical gloves is recommended.
The choice of work glove depends on work conditionsand what chemicals are handled. Please contact the PPE manufacturer fo" advice on what type of glove material may be suitable.
Gloves should be replaced immediately if signs of degradation are observed.SKIN PROTECTION:
Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible.EYE PROTECTION:
Wear a face shield with chemical splash goggles.HYGIENE RECOMMENDATIONS:
Use good work and personal hygiene practices to avoid exposure.
Keep an eye wash fountain available.
Keep a safety shower available.
If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals.
When handling this product never eat, drink or smoke.I 9. I PHYSICAL AND CHEMICAL PROPERTIES I.....APPEARANCE ODOR Colorless Ammonlacal SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER pH (100/%)pH (1 %)VISCOSITY FREEZING POINT BOILING POINT VAPOR PRESSURE 1.03 @ 60 F115.6 -C 8.56 Ib/gal Complete 12.5 10.1.- 10.7 2.0 cps @ 60 =F 115.6 *C-85 IF -65 'C 228 OF / 108.9 OC 22mmHg @ 77°F125°C Note: These physical properties are typical values for this product and are subject to change.Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.coni and request access.5/13 Attachment NOC-AE-14003142 Page 135 of 155 P NALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300,(24 Hours) CHEMTREC 11. 1STABILITY AND REACTIVITY__
STABILITY:
Stable if kept under conditions specified in Section 7, HANDLING AND STORAGE.HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.____C_ ONJ0[SJDcLTO_
lD-Q 1-___Extremes of temperature Heat and sources of ignition Including static discharges.
Keep at temperature not exceeding 123 TF MATERIALS TO AVOID: Acids Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, suffonic) may generate heat, splattering or boiling and toxic vapors. Contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Organic materials Gives off hydrogen by reaction with metals. Avoid contact with metal oxides such as those of iron, copper, lead, manganese and molybdenum.
Such contact may lead to decomposition.
HAZARDOUS DECOMPOSITION PRODUCTS: Under fire conditions:
Oxides of nitrogen, ammonia, Flammable gases/vapors
- 11. TOXICOLOGICAL INFORMATION The following results are for the product...................C .IE.Q L _TOXl Q. LTY z *.Species:
a LD50: 185 mg/kg Test Descriptor:
Product ACUTE DERMAL TOXICITY: Species: Rabbit LD50: 420 mg/kg Test Descriptor:
Product ACUTE INHALATION TOXICITY: Species: Rat LC50: 2.1 mg/I (4 hrs)Test Descriptor; Product SENSITIZATION:
May cause sensitization by skin contact.Nalco Company 1601 W. Diehl Road Napervilie, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit vvww.nalco.com and request access.6/13 Attachment NOC-AE-14003142 Page 136 of 155 r-4NA LCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY.TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC CARCINOGENICITY:
This product contains hydrazine, The International Agency for Research on Cancer(IARC) has evaluated hydrazine, and found it to be a possible human carcinogen (Group 2B) based on sufficient animal data and inadequate human data, MUTAGENICITY:
An ingredient in this product has shown positive results in a screening test for mutagenicity.
-4IHUMAN-,AZARD-CHARACTERIZAT4.0N Based on our hazard characterization, the potential human hazard is: High 112. 1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS: The following results are for the product.Acute Fish Results _Species Exposure Test Type Value Test Descriptor Bluegill Sunfish 96 hrs LC50 4.2 mg/I Product Rainbow Trout 96 hrs LC50 4.3 mg/I Product Gold Orfe 96 hrs LC50 0.75 mg l Product ACUTE INVERTEBRATE RESULTS: Species Exposure Test Type Value Test Descriptor Daphnia magna 48 hrs LC50 0.46 mg/1 Product PERSISTENCY AND DEGRADATION:
The organic portion of this preparation is expected to be readily biodegradable.
MOBILITY: The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface)
Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level lIlImodel does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.If released Into the environment this material Is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air W ater. Soil/Sediment 30 -50% 50- 70%The portion in water is expected to be soluble or dispersible.
Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access, 7/13 Attachment NOC-AE-14003142 Page 137 of 155 NNALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC BIOACCUMULATION POTENTIAL This preparation or material Is not expected to bloaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: High If released Into the environment, see CERCLA/SUPERFUND in Section 15.I 13. I DISPOSAL CONSIDERATIONS I If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, Before disposal, it should be determined if the waste meets the criteria of a hazardous waste.Hazardous Waste: D002, U133 Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal.
or recycling facility.
Consult local, state, and federal regulations for specific requirements.
Contact of the unneutralized product with certain clays may lead to hydrazine decomposition and release of ammonia.I 4. I TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, and mode of transportation.
Typical Proper Shipping Names for this product are as follows.7--:r.-Thee pres-ence-uaanyR.Q -mmp-nedepoe:uant UtShEPkand
- D(),imthLsproduct-cause s-lttoe regulated with an additional description of RO for road, or as a class 9 for road and air, ONLY when the net weight in the package exceeds the calculated RQ for the product.LAND TRANSPORT:
Proper Shipping Name: Technical Name(s): UN/ID No: Hazard Class -Primary: Packing Group: Flash Point: Reportable Quantity (per package): RQ Component:
HYDRAZINE, AQUEOUS SOLUTION UN 3293 6.1 III> 110'°C /,> 230 °F 3 lbs HYDRAZINE I AIR TRANSPORT (ICAO!IATA):
Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.8113 Attachment NOC-AE-14003142 Page 138 of 155"'NALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC The presence of an RQ component (Reportable Quantity for U.S. EPA and DOT) In this product causes it to be regulated with an additional description of RO for road, or as a class 9 for road and air, ONLY when the net weight in.the package exceeds the calculated RQ'for the product.Proper Shipping Name: Technical Name(s): UN/ID No: Hazard Class -Primary: Packing Group: HYDRAZINE, AQUEOUS SOLUTION UN 3293.6.1 Ill[ifJ RQ Component:
MARINE TRANSPORT (IMDG/IMO):
HYDRAZINE Proper Shipping Name: Technical Name(s): UN/ID No: Hazard Class -Primary: Packing Group: Marine Pollutant:
HYDRAZINE, AQUEOUS SOLUTION UN 3293 6,1 IHI HYDRAZINE*Note: This product is regulated as a Marine Pollutant when shipped by Rail, Highway (in bulk quantities), or Air (if no other hazard class applies), and when shipped by water in all quantities.
I 15. 1 REGULATORY INFORMATION I.. ...... -,.--.T~his~section..contalns.additional~inforrnaUon~that-nmy-ay erlvnd~o ]a(y z-bnom p-nh..... is or It is not exhaustive, and should not be relied upon to take the place of an Individualized compliance or hazard assessment.
Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA: OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
- Based on our hazard evaluation, the following substance(s) in this product isWare hazardous and the reason(s) islare.shown below.Hydrazine
- Cancer suspect agent (refer to Section 3), Corrosive, Dermal Sensitizer CERCLA/SUPERFUND, 40 CFR 302:*This product contains the following Reportable Quantity (RQ) Substance.
Also listed is the RQ for the product. If a reportable quantity of product is released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D.C. (1-800-424-8802).
RQ Substance Hydrazine 3 lbs Nalco Company 1601 W. Diehl Road .Naperville, Illinois 60563-1198-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.9/13 Attachment NOC-AE-14003142 Page 139 of 155 N"NALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(SY (800) 424-9300 (24 Hours) CHEMTREC I I I I SARAISUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE t11) -SECTIONS 302, 311, 312, AND 313: SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product contains the following substance(s) which is listed in Appendix A and B as an Extremely Hazardous Substance.
Listed below are the statutory Threshold Planning Quantity (TPQ) for the substance(s) and the Reportable Quantity (RO) of the product. If a reportable quantity of product is released, it requires notification to your State Fmerg ny-Response-Commisso--Y-ou-may-also-be-require:l~o-notifythe.Naona .Response.Center.See CERCLAISUPERFUND, above.Extremely Hazardous Substance TPQ R.Q Hydrazine 1,000 lbs 3 lbs SECTIONS 311 AND 312 -MATERIAL SAFETYDATA SHEET REQUIREMENTS (40 CFR 3701': Our hazard evaluation has found this product to be hazardous.
The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard X Delayed (Chronic)
Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 -LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following substance(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals Hazardous Substance(s)
CAS NO Hydrazine 302-01-2 30.0-60.0 TOXIC SUBSTANCES CONTROL ACT (TSCA): The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act: When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 Boiler Water Additives The following limitations apply: Maximum dosage Limitation ZERO PPM as product in the steam Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563w1198
- (630)305-1000 For additional copies of an MSDS visit wvwv.nalco.com and request access.10113 Attachment NOC-AE-14003142 Page 140 of 155 r 4 NALCO SAFETY DATA SHEET PRODUCT ii NALCOR 19.H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC Steam produced may be used in contact with any food type, defined under 21 CFR 170.3, which includes milk or milk products.NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances
&Non-Food Compounds)
- NSF Registration number for this product is : 062465 This product is acceptable for treating boilers or steam lines where steam produced may contact edible products and/or cooling systems where the treated water may not contact edible products in and around food processing areas FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4/ formerly Sec. 311 : Substances.listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances)
- This product contains the following substances listed in the regulation.
Additional components may be unintentionally present at trace, levels.Substance(s)
Citations.Hydrazine Sec. 112:CALIFORNIA PROPOSITION 65: This product contains the following substances which require warnin, 9 under California Proposition
- 65. Additional
.........
- componentsr may b- h-ffie-f -lypresenteattracetlevels
.............
...le.ve Substance(s)
Concentration EFFECTS* Hydrazine
<60% Causes Cancer MICHIGAN CRITICAL MATERIALS:
This product contains the following substances listed in the regulation.
Additional components may be unintentionally present at trace levels.Hydrazine STATE RIGHT TO KNOW LAWS: The following substances are disclosed for compliance with Stale Right to Know Laws: Hydrazine 302-01-2 Nalco Company 1601 W. Diehl Road .Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.11/13 Attachment NOC-AE-14003142 Page 141 of 155 NNALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC INTERNATIONAL CHEMICAL CONTROL LAWS: CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): The substance(s) in this preparation are included In or exempted from the Domestic Substance List (DSL).AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification
& Assessment Scheme (NICNAS)., .CHINA All substances In this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN All substances in this product comply with the Law Regulating the Manufacture and importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory 16. OTHER INFORMATION This product material safety data sheet provides health and safety information.
The product Is to be used in applications consistent with our product literature.
Individuals handling this product should be informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations.
Please consult your local sales representative for any further information.
REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Arlel InsightTM CD-ROM Version), Ariel Research Corp., Bethesda, MD.Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS'm CD-ROM Version), Micromedex, Inc., Englewood, CO.Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS. visit www.nalco.com and request access.12/13 Attachment NOC-AE-14003142 Page 142 of 155 N"NALCO SAFETY DATA SHEET PRODUCT NALCO 19H EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC IARC Monographs on the Evaluation of the Carcinogenic Risk- of Chemicals to Man, Geneva: World Health Organi.za.tion, Iternaional Agency for Research on.Cancer...........................
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPSTM CD-ROM Version), Micromedex, Inc., Englewood, CO.Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel InsightThM CD-ROM Version), Ariel Research Corp., Bethesda, MD.Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPSTM CD-ROM Version), Micromedex, Inc., Englewood, CO, AAdel InsightTM (An integrated guide to industrial chemicals covered under major regulatory and advisory programs), North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight T M CD-ROM Version), Ariel Research Corp., Bethesda, MD.The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPSTM CD-ROM Version), Micromedex, Inc., Englewood, CO...Prepared-By-mr -.. ..... ............
....Date issued : 06127/2012 Version Number: 4.2 Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
.(630)305-1000 For additional copies of an MSDS visit www:nalco.com and request access.13/13 Attachment NOC-AE-14003142 Page 143 of 155 (C'age 2 of 13)_______SAFETY DATA SHEET A4 PRODUCT LCS-60 EMERGENCY TELEPHONE NUMBER(S)(800) 424-300 (24 Hours) CHEMTREC 1: CHIEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: LCS-_0 APPLICATION:
WATER TREATMENT COMPANY IDENTIFICATION:
Nalco Company 161-WT~ieni Roacd Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):
(800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 2/2 FLAMMABILITY:
0/0 INSTABILITY:
010 OTHER:------- O-=-tnsignificant--l-
--Slight ---
- 12. 1 COMPOSITIONIINFORMATION ON INGREDIENTS Our hazard evaluation has Identified the following chemical substance(s) as hazardous.
Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s)
CAS NO % (wlw)Sodium Nitrite 7632-00-0 5.0- 10.0 Sodium Tetraborate 1330-43-4 1.0 -5,0....... .. ....3 .! z A 0 -" i ..... ..... .. ..........
.. ...........
...........
.... ..........
.... ... ...13. 1HAZ-ARDS IDENTIFICATION
Unborn children are particularly sensitive to methemoglobinemia.
Do not get in eyes, on skin, on clothing.
Do not take Internally.
Use with adequate ventilation.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.Wear suitable protective clothing.May evolve oxides of nitrogen (NOx) under fire conditions.
If product is allowed to dry, the sodium nitrite is an oxidizing agent and can initiate the combustion of other materials, Not flammable or combustible.
P RIMARY'ROUTESOFEXPOSUR.:
Eye, Skin HUMAN HEALTH HAZARDS -ACUTE: EYE CONTACT: Can cause mild to moderate irritation.
Nalco Company 1601 W. Diehl Road' Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalcocom and request access.1/10 9 Attachment NOC-AE-14003142 Page 144 of 155 i~age 3 :! 13)____ ___ SAFETY DATA SHEET -_PRODUCT~NALCO LS6 EMERGENCY TELEPHONE NUMBER(S)(BO)424-9300 (24 Hours) CHEMTREC SKIN CONTACT: May cause Irritation with prolonged contact INGESTION:
Not a likely route of exposure.
Large exposures may be fatal. Ingestion of sodium nitrile can cause methemoglobinemia which can lead to cyanosis and possible death. Pregnant women and their fetuses are parIcuray methemoglobinemia.
INHALATION:
Not a likely route of exposure.
Aerosols or product mist may irritate the upper respiratory tract.AGGRAVATION OFEXISTING CONDITIONS:
Sodium Nitrite. Pregnant women are particularly sensitive to methernoglobinemia.
HUMAN HEALTH HAZARDS -CHRONIC.: Repeated ingestion of small amounts of sodium nitrite causes drops in blood pressure, rapid pulse, headaches and visual disturbances.
It may also react with organic amines In the body to form carcinogenic nitrosamines.
- 14. 1 FIRST AID MEASURES SKIN CONTACT: Immediately flush with plenty of water for at least 15 minutes. If symptoms develop, seek medical advice.INGESTION:
Get Immediate medical attention.
Do not Induce vomiting without medical advice. If conscious, washout mouth and-give--wat-er-to.drink;.......
.... ..INHALATION:
Remove to fresh air, treat symptomatically.
Get medical attention.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
Measures against circulatory shock, respiratory depression and convulsions may be needed.15. 1 FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA : Not expected to burn. Use extinguishing media appropriate for surrounding fire.FIRE AND EXPLOSION HAZARD : May evolve oxides of nitrogen (NOx) under fire conditions.
If product is allowed todry, the sodium nitrite is an oxidizing agent and can initiate the combustion of other materials.
Not flammable or combustible.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.Nalco Company 1601 W. Dihl Road
- Naperville.
Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.2110 Attachment NOC-AE-14003142 Page 145 of 155 (Page 4 of 13)SAFETY DATA SHEET.N04 PRODUCT*- LCS-60 EMERGENCY TELEPHONE NUMBER(S)(800)424-9300 (24 Hours) CHEMTREC 6. 'ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
Stop or reduce any leaks If it is safe to do so.Keep people away from and upwind of spill/leak.
Ventilate spill area if possible.
Ensure clean-up Is conducted by trained personnel only. Do not touchIoLfediateidaLtJaiwemnegency-equipmenL(for.fires~spillsr.eaksretc.)-readily available, Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP: SMALL SPILLS: Soak up spill with absorbent material.
Place residues in a suitable, covered, property labeled-----container.-Wash-afected-aa.-LARGE-SP-LLS:--Contain liquid-using absorbent-material'-by-digginig~tenches~orby
-diking. Reclaim into recovery or salvage drums or tank truck for proper disposal.
Wash site of spillage thoroughly with water. Contact an aoproved waste hauler fordisposal of contaminated recovered material.
D.ipose of material in compliance with regulations Indicated in Section 13 (Disposal Considerations).
Do not allow product to evaporate to dryness.ENVIRONMENTAL PRECAUTIONS:
Prevent material from entering sewers or waterways., Spilled product may pose a risk to the aquatic ecosystem if released., If drains, streams, sil or sewers become contaminated, notify local authority.
- 17. HANDLING AND STORAGE HANDLING: Do not take internally.
Use with adequate ventilation.
Do not breathe vapors/gases/dust.
Do not get in eyes, on skin, on.clothing, Have emergency equmeT (for fires, spills eaks. etc.) readily sur4alLcgnjes ar..STORAGE CONDITIONS:
Store In suitable labeled containers.
Store the containers tightly closed. Store away from organic chemicals and other oxidizable materials, reducing agents, acids and alkalis.SUITABLE CONSTRUCTION MATERIAL: Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use.18. EXPOSURE CONTROLSIPERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.Substance(s)
Category; ppm mg/m3 Non-Standard Unit Borates, Tetra, Sodium Salts -Anhydrous (Inhalable ACGIHITWA 2 fraction.)
ACGIH/STEL 6 Nalco Company 1601 W. Diehl. Road
- Naperville.
Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access: 3/10 Attachment NOC-AE-14003142 Page 146 of 155 (Page 5 of 13)..NALCO SAFETY DATA SHEET!PRODUCT.iLCs-60 EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC ENGINEERING MEASURES: General ventilation Is recommended.-RESPIRATORY PROTECTION:
Resplratorv protection is not normally needed. Where o eithis~seio_
or when significant mists, vapors, aerosols, or dusts are generated, an approved air purifying respirator equipped with suitablefilter cartridges is recommended.
Consult the respirator
/ cartridge manufacturer data to verify the suitability of specific devices. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection Is required, institute a complete.
respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
When handling this product, the use of chemical gloves Is recommended.
The choice of work glove depends on work conditions and what chemicals are handled. Please contact the PPE manufacturer for advice on what type of glove material may be suitable.
Gloves should be replaced Immediately if signs of degradation are observed.SKIN PROTECTION:
Wear standard protective clothing.EYE PROTECTION:
Wear chemical splash goggles.HYGIENE RECOMMENDATIONS:
.U -se-g-od-work-and-persoral-h.ygiene-prat-ces-to-avod-exposure--Keepr-rreye--ashfour-ain-aaitableKeep
.............
conta minatod-clothing:before-reuse.-Always-wash thoroughly-aafter-handling-chemicals-When-handling.this-product never.eatj drinkeor smoke.I 9. I PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE APPEARANCE ODOR SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER pH (100 %)VAPOR PRESSURE VOC CONTENT Liquid Clear Light yellow None 1.076. @ 77 "F / 25 "C 8.96 lb/gal Complete 8-9 Same as water 0.0 % EPA Method 24___Note:Ihese-chysicaboro~ertiesArelyicaLvalues-for-hisrcwductand-are-sublcieo-tchanne.
Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.4/10 Attachment NOC-AE-14003142 Page 147 of 155 (2g of 13)7NALCO SAFETY DATA SHEET PRODUCT LCS-60 I II i i I II ', EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHIEMTREC 110. I STABILITY AND REACTIVITY I STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.CONDITIONS TO AVOID: Freezing temperatures.
MATERIALS-TO-AVOID4 Contact with reducing agents (e.g. hydrazine, sulfites, sulfide, aluminum or magnesium dust) may generate heat, fires, explosions and toxic vapors. Do not mix with amines. Sodium nitrite can react with certain amines to produce N-nitrosamines, many of which are cancer-causing agents to laboratory animals. Contact with strong acids (e.g.sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors.HAZARDOUS DECOMPOSITION PRODUCTS: Under fire conditions:
Oxides of nitrogen, Oxides of sodium 11. 1 TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product.SENSITIZATION:
This product is not expected to be a sensitizer.
-.-CA -CR RCINO'GENI C t'- C : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists'(ACGIH).TERATOGENICITY AND EMBRYOTOXICITY:
Experimental animal studies with sodium nitrite have shown reproductive effects in the offspring of treated parents.These effects are not transmissible.
112. I ECOLOGICAL INFORMATION I ECOTOXICOLOGICAL EFFECTS: The following results are for the product.ACUTE FISH RESULTS: s1cies Exposure LC50 Test Descriptor Rainbow Trout 96 hrs 20 m ACUTE INVERTEBRATE RESULTS: Species Exposure LC50 I EC50 I Test Descriptor Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198
-(630)305-1000 For additional copies. of an MSDS visit www.nalco.com and request access.5/10 Attachment NOC-AE-14003142 Page 148 of 155 (page 7 of 13)NANALCO EMERGENCY lELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHEMTREC Daphnia magna 48 hrs 340m 2t0m mI MOBILITY: The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface)
Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The Information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.If released into the environment this material is expected to distribute to the air. water and soillsediment in the approximate respective percentages;
<5% 30,-50% 50 -70%_The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL This preparation or materal Is not expected to bloaccumulate.
If released Into the environment, see CERCLA/SUPERFUND in Section 15.13. 1 DISPOSAL CONSIDERATIONS Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart 0..............
A"-a -of-sb5]Fcf-1-o-TT:!--aElg~a 6nh nsl tate-o r-lct rgu toa ..................
handling, treatment or disposal requirements.
For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.114. 1 TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties.
and mode of transportation.
Typical Proper Shipping Names for this product areas follows.The presence of an RO component (Reportable Quantity for U.S. EPA and DOT) in this product causes'it lobe regulated vAth an additional description of RO for road, or as a clars 9 for road and air, ONLY when the net weight in the package exceeds the calculated RO for the product.LAND TRANSPORT:
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.Technical Name(s): SODIUM NITRITE UN!ID No: UN 3082 Hazard Class -Primary: 9 Packing Group: III Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSOS visit www.nalcocom and request access.6110 Attachment NOC-AE-14003142 Page 149 of 155 (Page 8 of 13)~NALCO SAFETY DATA SHEET PRODUCT LCS-60 , EMERGENCY TELEPHONE NUMBER(S)(800) 424-9300 (24 Hours) CHIEMTREC Flash Point: .......Reportable Quantity (per package): RQ Component:
N6ne .......1,050 lbs SODIUM NITRITE AIR TRANSPORT (ICAO/IATA):
The presence of an RQ component (Reportable Quantity for U.S. EPA and DOT) in this product causes it to be regulated with an additional description of RO for road, or as a class 9 for road and air, ONLY when the net weight in--the-pockag-xceeds-the-cafcuated'RQ-foth-ro-dar
-Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.Technical Name(s): SODIUM NITRITE UNJID No: UN 3082 Hazard Class -Primary: 9 Packing Group: III Reportable Quantity (per package):
1,050 lbs RO Component:
SODIUM NITRITE MAR1 NE-TTRSORPORT7IMY G'IMO) : Proper Shipping Name: _PRODUCT IS NOT REGULATED DURING PO-RTATIUON 115S. I REGULATORY INFORMATION I I This section contains additional information that may have relevance to regulatory compliance.
The information in this... m-piane-for hazard assessment.
Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA: OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
ased-on-our-hazard-evaluat~onTthe-follovving-substance(s)-irrt his prodact-is/are-hazardowsand-thr-mason(s)l s/are-shown below.Sodium Nitrite: Target Organ Effect -Kidney, Target OrganEffect
-Nervous system, Target Organ Effect -Blood Sodium Tetraborate:
Exposure Limit CERCLA/SUPERFUND, 40 CFR 302: This product contains the following Reportable Quantity (RO) Substance.
Also listed is the RO for the product. If a reportable quantity of product is released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D.C. (1-800-424-8802).
RO Substance Sodium Nitrite RQ 1,050 Ibs Nalco Company 1601 W. DiehlI Road- Naperville.
Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.7/10 Attachment NOC-AE-14003142 Page 150 of 155 (Page 9 of 13).*NALCO SAFETY DATA SHEET PRODUCT LCS-60 EMERGENCY TELEPHONE NUMBER(S)(800)424-9300(24 Hours) CHEMTREC SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) -SECTIONS 302, 311, 312, AND 313: SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 -MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazar -e-5---t-0-51ion-nas found this product to be hazardous.
Theproduct should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard flDrhvp~d fChronink Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 -LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following substance(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals_'1 "-'M ,.f-Nt. ____________-___-
Sodium Nitdte 7632-00-0 5.0-10.0"TOXIC-SUBSTANCES CONTROLA-,CT-(TSCA)
_3 ....The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT. 40 CFRA401.15
/ formerly Sec. 307.40 CFR 116.4/ formerly Sec. 311 : This product contains the following substances listed in the regulation.
Additional components may be unintentionally present at trace levels.I Substance(s)
I Citations.Sodium Nitdte Sec. 311 CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):
Substances listed under this regulation are not Intentionally added or expected to be present in this product. Listed components may be present at trace levels.CALIFORNIA PROPOSITION 65: Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product.Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.8/10 Attachment NOC-AE-14003142 Page 151 of 155 1tl 1o of 13)SAFETY DATA SHEET A4 PRODUCT.~NALCO ~4. --EMERGENCY TELEPHONE NUMBER(S).(800) 424-9300 (24 Hours) CHEMTREC MICHIGAN CRITICAL MATERIALS:
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.STATE RIGHT TO KNOW LAWS: The following substances are disclosed for compliance with State Right to Know Laws: Sodium Nitrite 7632-00.0 Sodium Tetraborate 1330-43-4 Water 7732-18-5 CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): The substances In this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been repoited in accordance with the New Substances Notification Regulations.
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification
& Assessment Scheme (NICNAS).CHINA All substances In this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed onthe Inventory of Existing Chemical Substances China (IECSC).EU ROPE _________The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals Ust (ECL)PHILIPPINES All substances In this product comply with the Republic Act 8969 (RA 6969) and are listed on the Philippines Inventory of Chemicals
& Chemical Substances (PICCS).16. 1 OTHER INFORMATION This product material safety data sheet provides health and safety information.
The product Is to be used in applications consistent with our product literature.
Individuals handling this product should be Informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should Nalco Company 1601 W. Diehl Road -Napervil!e, Illinois 60563-1198
-(630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.9/10 Attachment NOC-AE-14003142 Page 152 of 155 Attachment J Requested Permit Amendments Admin Report 1. 0, Pg. 1; Tech Report 1.0 -12., Pg. 11 Attachment NOC-AE-14003142 Page 153 of 155 Attachment J -Amendment Requests Request to remove pH monitoring requirements from Internal Outfolls 101, 201, and 501. STP Nuclear respectfully requests the removal of pH limitations and monitoring requirements from its internal monitoring locations.
STP feels the requirement to monitor for pH at internal monitoring locations prior to wastewater entering its own cooling reservoir is overly burdensome and has little to no positive environmental impact. In fact, due to efforts by the plant to ensure the pH limits are met, STP must chemically treat these individual wastestreams prior to sampling at the internal monitoring locations.
pH treatment would not be necessary to meet the effluent limits at the external Outfall 001 due to natural pH balancing that occurs in the cooling reservoir.
Request to remove effluent limits and monitoring requirements for relief well discharges at Outfalls 002, 003, 004, 005, and 006 and all associated permit requirements having to do with relief well monitoring.
STP requests the removal of the monitoring requirements for relief well discharges, placed in the previous TPDES permit draft. The water being discharged is predominantly groundwater that is seeping up to the surface from under the reservoir.
The water is not pumped to the surface for discharge.
STP has been conducting routine monitoring of its relief well discharges in compliance with its TPDES*permit since the permit was issued on April 5, 2012. STP has collected over two years'worth of data in that time. None of the data collected from the relief well monitoring program has exceeded an established effluent limit in the TPDES permit.
Attachment NOC-AE-14003142 Page 154 of 155 Attachment K Treatment System Tech Report, Item 2. a., Pg. 3 Attachment NOC-AE-14003142 Page 155 of 155 Wastewater Treatment System Treatment System Outfall Unit Dimensions Treatment Processes Main Cooling Reservoir 001 7,000 acre pond (irregular)
Heat Dissipation
' Reuse/Rlecvcle Low Volume Waste 2-Neutralization Basins Neutralization' Metal Cleaning Wastes** 101 (300,000 gallons each) Mixing*Neutralization Basin 68' x 42'x 16' Sedimentation Gross Oil Separator (API) Equalization Flotation 13,000 gallons Skimming*24.".x 8'x 7'Skmig Low Volume Waste 201 Sedimentation Oily Waste Treatment System Tricellorator (DAF) 3,800 gallons Dissolved air flotation S9'die x 8' CoaquIaton*
Effluent Tank 850 gallons Multi-media Filtration 5' dia x 6'2-Aeration Basins Screening 63" x 12" x 11 '6' Activated Sludge 2 Clarifiers 16' dia x 11 '6" Sedimentation West Sanitary Waste Treatment Primary Chlorine Contact 401 Chamber Disinfecton..
System*~ 6" x 12' x 1 '6" Secondary Chlorine Contact Chamber Disinfection~'*
I 4'dia x 4'3" Organic Basin Equalization Approx. 1,000,000 gallons Mixing*1 00'x 80'x 17'6" Aeration*Metal Cleaning Waste- 501 Inorganic Basin Coagulation' Approx. 50,000 gallons Chemical Precipitation*
25' x 25' x 13'3" Sedimentation Treatment Tanks (possible future Not-determined at this use) time.2-Aeration Basins Screening 54'6" x 12:' x 3'3" Activated Sludge Training Sanitary Waste Treatment 601 1 -Clarifier System** 6 2,0'. da x 133" Sedimentation Chlorine Contact Chamber Disinfection"-" Note: Chlorine may be used intermittently to control algae growth in treatment units.Treatment process may be used based on influent characteristics.
Outfall 501 is routed to Outfall 101. There have been no discharges from Outfall 501 since December 1992.The West Plant is currently rated at 110,000 gallons per day (gpd) and the Training Plant at 66,000 gpd.Sanitary wastewater will increase beginning with the construction of two new electric generating units (3 and 4)and an increase in construction personnel.
The physical locations of the treatment systems and Outfalls 401 and 601 may change; however, the outfall descriptions in the permit would remain the same (i.e., monitoring at the discharge from the sewage treatment plant).Disinfection may include sodium hypochlorite or calcium hypochlorite.
Technical Report 1.0 Page 3a