ML24121A239

From kanterella
Jump to navigation Jump to search
Annual Radiological Environmental Operating Report
ML24121A239
Person / Time
Site: Callaway  Ameren icon.png
Issue date: 04/30/2024
From:
Ameren Missouri, Microbac Labs, Union Electric Co
To:
Office of Nuclear Reactor Regulation
Shared Package
ML24121A237 List:
References
PROJ08036
Download: ML24121A239 (1)


Text

Amerefl Callaway MISSOURI h

Energy Center AMEREN MISSOURI CALLAWAY ENERGY CENTER FULTON, MISSOURI Docket Numbers 50-483 and 72-1045 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT to THE UNITED STATES NUCLEAR REGULATORY COMMISSION Part I January 1 to December 31

, 2023 Prepared by Microbac Laboratories

- Northbrook and Ameren Missouri Callaway Energy Center Submitted by UNION ELECTRIC CO.

dba Ameren Missouri Project No. 8036

PREFACE This Annual Radiological Environmental Operating Report (AREOR) describes the Ameren Missouri Callaway Energy Center Radiological Environmental Monitoring Program (REMP), and the program results for the calendar year 2023. It is submitted in accordance with section 5.6.2 of the Callaway Energy Center Technical Specifications.

Staff members of Microbac Laboratories

- Northbrook were responsible for the acquisition of data presented in this report. Environmental samples were collected by Ameren Missouri personnel or contractors to Ameren Missouri and shipped to Microbac Laboratories

- Northbrook and Stanford Dosimetry, LLC, for analysis.

The report was prepared by Microbac Laboratories Northbrook and the Ameren Missouri Callaway Energy Center.

TABLE OF CONTENTS No.

PREFACE ii List of Tables v

List of Figures vi

1.0 INTRODUCTION

1 2.0

SUMMARY

2 3.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM 3

3.1 Program Design and Data Interpretation 3

3.2 Program Description 4

3.3 Program Execution 5

3.4 Laboratory Procedures 6

3.5 Program Modifications 6

3.6 Detection and Reporting Limits 6

3.7 Land Use Census 7

3.8 Errata from previous AREORs 7

4.0 RESULTS AND DISCUSSION 8

4.1 Atmospheric Nuclear Detonations and Nuclear Accidents 8

4.2 Program Findings 8

5.0 TABLES ii

6.0 REFERENCES

CITED 23 APPENDICES A

Interlaboratory Comparison Program Results A-i B

Data Reporting Conventions B-i C

Non-Radiological Monitoring Program C-i D

Sampling Location Maps D-i

TABLE OF CONTENTS (continued)

PART II Data Tabulations and Analyses iv

LIST OF TABLES No.

5.1 Sampling Locations, Ameren Missouri, Callaway Energy Center.

14 5.2 Collection Frequencies and Required Analyses 18 5.3 Minimum Required Detection Capabilities for REMP Sample Analysis 19 5.4 Results of the Land Use Census.

20 5.5 Missed Collections and Analyses.

21 5.6 Radiological Environmental Monitoring Program Summary 22 5.7 Direct Radiation Dose (mrem/90 days) for the Period 2000-2022 24 In addition, the following tables are in the Appendices:

Appendix A Attachment A: Acceptance criteria for spiked samples A-2 A-i Interlaboratory Comparison Crosscheck Program, Environmental Resource Associates RAD study (substitute program for EPA)

A-3 A-3 In-house Spiked Samples A-6 A-4 In-house Blank Samples A-8 A-5 In-house Duplicate Samples A-b A-6 Department of Energy MAPEP comparison results A-b 3 A-f Interlaboratory Comparison Crosscheck Program, Environmental Resource Associates MRAD study (substitute program for EML)

A-b 6 V

LIST OF FIGURES Appendix D No.

D-1 Radiological Environmental Sampling Locations 1, 2, 3 mile radius from site location D-2 D-2 Radiological Environmental Sampling Locations 3, 4, 5, 6 mile radius from site location D-3 D-3 Radiological Environmental Sampling Locations 5, 10, 15 mile radius from site location D-4 D-4 Non-Potable Groundwater Monitoring Wells, 600 ft radius D-5 D-5 Non-Potable Groundwater Monitoring Wells Collection D-6 vi

1.0 INTRODUCTION

This report presents an analysis of the results of the Radiological Environmental Monitoring Program (REMP) conducted during 2023 for the Union Electric Company (dba Ameren Missouri) Callaway Energy Center.

The objectives of the REMP are to monitor potential critical pathways of radioactive effluent to man and determine the radiological impact on the environment caused by operation of the Callaway Energy Center. The Radiological Environmental Monitoring Program was initiated in April 1982.

The Callaway Energy Center consists of one 3565 MWt pressurized water reactor, which achieved initial criticality on October 2, 1 984. The plant is located on a plateau approximately ten miles southeast of the City of Fulton in Callaway County, Missouri and approximately eighty miles west of the St. Louis metropolitan area. The Missouri River flows by the site in an easterly direction approximately five miles south of the site at its closest point.

Tabulation of the individual analyses for the year 2023 is included in Part II of this report.

2.0

SUMMARY

The Radiological Environmental Monitoring Program, as required by the U.S. Nuclear Regulatory Commission (NRC) Technical Specifications for the Callaway Energy Center is described herein.

Results for the year 2023 are summarized and discussed.

For the year, the Callaway Energy Center was operated in compliance with Offsite Dose Calculation Manual (ODCM) and Radiological Effluent Controls (REC) requirements. Results from the REMP indicate the Callaway Energy Center has had no significant radiological impact on the health and safety of the public or on the environment.

2

3.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM 31 Program Design and Data Interpretation The purpose of the Radiological Environmental Monitoring Program at the Callaway Energy Center is to assess the impact of the plant on its environment.

For this purpose, samples are collected from waterborne, airborne, ingestion and terrestrial pathways and analyzed for radioactive content.

Direct radiation levels are monitored by thermoluminescent dosimeters (TLD5).

Sources of environmental radiation can include the following:

(1 )

Natural background radiation arising from cosmic rays and primordial radionuclides; (2)

Fallout from atmospheric nuclear detonations; (3)

Releases from nuclear power plants, planned or accidental; and (4)

Industrial and medical radioactive waste.

Effects due to operation of the Callaway Energy Center must be distinguished from those due to other sources in interpreting the data.

The indicator-control concept is a major interpretive aid; where feasible the design of the Callaway Energy Center program has both indicator and control stations. Most types of samples are collected at indicator locations (nearby, downwind, or downstream) and at control locations (distant, upwind, or upstream). A station effect would be indicated if the radiation level at an indicator location was significantly larger than that at the control location. The difference would have to be greater than could be accounted for by typical fluctuations in radiation levels arising from other sources.

The monitoring program includes analyses for iodine-i 31

, a fission product, and tritium, which is produced by cosmic rays, atmospheric nuclear detonations, and also by nuclear power plants.

Most samples are analyzed for gamma-emitting isotopes, with results for the following groups quantified: zirconium-95, cesium-i 37, and cerium-i 44. These three gamma-emitting isotopes are selected as radiological impact indicators because of the different characteristic proportions in which they appear in the fission product mix produced by a nuclear reactor and that produced by a nuclear detonation.

Each of the three isotopes is produced in roughly equivalent amounts by a reactor: each constitutes about i 0% of the total activity of fission products ten days after reactor shutdown. On the other hand, ten days after a nuclear explosion, the contributions of zirconium-95, cerium-i44, and cesium-i37 to the activity of the resulting debris are in the approximate ratio 4:i :0.03 (Eisenbud,i963).

The other group quantified consists of niobium-95, ruthenium-i03 and -i06, cesium-i34, barium-lanthanum-i 40, and cerium-i 4i

. These isotopes are released in small quantities by nuclear power plants, but to date their major source of injection into the general environment has been atmospheric nuclear testing.

Nuclides of the next group, manganese-54, cobalt-58 and-60, and zinc-65, are activation products and arise from activation of corrosion products. They are typical components of nuclear power plant effluents but are not produced in significant quantities by nuclear detonation.

Nuclides of the final group, beryllium-7, which is of cosmogenic origin, and potassium-40, a naturally-occurring isotope, were chosen as analytical monitors and should not be considered radiological impact indicators.

Other means of distinguishing sources of environmental radiation can be employed in interpreting the data. Current radiation levels can be compared with previous levels, including pre-operational data.

Results of the monitoring program can be related to those obtained in other parts of the world.

Finally, results can be related to events known to cause elevated levels of radiation in the environment, e.g., a nuclear accident.

3

3.2 Program Description The sampling and analysis schedules for the environmental radiological monitoring program at the Callaway Energy Center are summarized in Tables 5.1 and 5.2 and briefly reviewed below. Table 5.1 identifies sampling locations and specifies as to type (indicator or control) and its distance, and direction relative to the reactor site.

The types of samples collected at each location, required analyses and the frequency of collections are presented in Table 5.2.

To monitor the air environment, airborne particulate and airborne iodine samples are collected by continuous pumping, at six locations. The airborne particulates are collected on glass fiber filters and the airborne iodine through activated charcoal cartridges. Both filters and cartridges are exchanged weekly. Airborne particulates are analyzed for gamma-emitting isotopes. Charcoal cartridges are analyzed for iodine-131.

The ingestion pathway is monitored by sampling of milk (if available), fish and green leafy vegetation.

Milk samples are collected semimonthly when animals are on pasture and monthly the rest of the year. There were no milk indicator or control stations identified by the Land Use Census for the subject year.

Milk samples are analyzed for iodine-131 and gamma-emitting isotopes when available.

Monthly during the growing season, edible green leafy vegetation is collected from both indicator and control locations. Vegetation samples typically consist of mustard greens, turnip greens, cabbage, lettuce, collards, radish greens, swiss chard, broccoli and poke. Other edible broad leaf vegetation is collected if primary varieties are not available. The samples are analyzed for iodine-1 31 and other gamma-emitting isotopes.

The waterborne pathway is monitored by sampling surface water, groundwater and drinking water, and shoreline sediments. Water samples are analyzed for tritium and gamma-emitting isotopes, and sediments are analyzed for gamma-emitting isotopes.

The waterborne pathway is also monitored by upstream and downstream semiannual collections of fish. The five most abundant recreational or commercial fish species are collected. The edible portions of the samples are analyzed for gamma-emitting isotopes.

Monthly composite samples of surface water from the Missouri River are collected from one indicator location (S02) and from one control location (SOl ). The surface water samples are composites of daily collections by automatic river samplers.

Onsite surface water from ponds is analyzed for tritium and gamma-emitting isotopes. The collection frequencies are semiannually.

To monitor possible sources of ground water contamination due to plant operations, non-potable ground water samples were collected monthly or quarterly from well locations both onsite and along the discharge pipeline. The samples were analyzed for tritium and gamma-emitting isotopes.

Potable well water samples are collected quarterly from the plant drinking water supply and neighboring property owners.

The samples were analyzed for tritium and gamma-emiffing isotopes.

Shoreline sediment is collected semiannually at the plants intake (A) and discharge (C). These samples are collected within two feet of the edge of the water. The samples are analyzed for gamma-emitting isotopes.

4

3.2 Program Description (continued)

The direct ambient gamma radiation pathway is also considered. This exposure is monitored by thermoluminescent dosimeters (TLDs) at forty-four locations in and around the Callaway site. The TLDs are placed in 16 sectors around the plant as specified in the ODCM-RECS. Five of the TLD stations have neutron monitoring capability and three locations are designated as controls. TLDs are exchanged and analyzed quarterly.

Soil is collected annually from seven indicator locations (F2, F6, PR3, PRZ, W2, W5 and W6) and two control locations (M9, WY) to monitor the terrestrial environment. The samples are analyzed for gamma-emitting isotopes.

3.3 Program Execution The program was executed as described in the preceding section with the following exceptions.

(1) Food Products-Leafy Green Vegetables:

There were no viable samples available for collection in April 2023 at any of the sampling locations, CA-FPL-V9, CA-FPL-V1 6, CA-FPL-V1 9 and CA-FPL-V20 due to it being too early in the growing season (CR#202302405).

Sample location CA-FPL-V9 was unable to provide a vegetation sample in May 2023 due growing conditions (CR#202303264).

(2) Non-potable Wells:

The well sample scheduled to be collected 2/24/23 at location CA-WWA-UY MW-47 could not be collected due to a dry well (CR#202301 282).

The well sample scheduled to be collected 5/31/23 at well location CA-WWA-U1 MW-47 could not be collected due to a dry well (CR#202303703).

The well samples scheduled to be collected 1 1/73/23 at well locations CA-WWA-U1 MW-004, CA-WWA-U1 -MW-005, CA-VVWA-U1 MW-47 could not be collected due to dry well conditions (CR#202308663).

(3) Direct Radiation:

During the quarterly changeout of TLDs from first to second quarter the TLD at location CA-IDM-1 0 was found to be missing (CR#202302537).

(4) Surface Water:

River Samplers Out of Service Time:

Sampler SOY, the upstream sampler located in the plant water intake structure about 550 feet upstream of the discharge, was out of service for approximately 0 days (0.0% of the year) during 2023.

Sampler 502, the downstream sampler located at the end of the mixing zone in Portland, MO, was out of service for approximately 1 3 days (3.56% of the year) during 2023.

Functioning 96.44% of 2023. Portland pump noise issue 6 days without automatic sampling (CR 202208509). Portland River sampler vault flooded 7 additional days without automatic sampling (CR 202305288).

During those out of service times, daily grab samples are collected as required per Callaways procedures.

5

3.4 Laboratory Procedures Gamma-spectroscopic analyses were performed with HPGe detectors.

Levels of iodine-i 31 in vegetation and concentrations of airborne iodine-i 31 in charcoal samples were also determined by gamma spectroscopy.

Iritium was measured by liquid scintillation.

ATI Environmental Inc. Midwest Laboratory was acquired by Microbac Laboratories, Inc. effective June 1, 2023.

The Northbrook Illinois laboratory now operates within the Microbac network of laboratories at the same location and with the same personnel as they did while part of ATI. Inc.

Analytical procedures used by Microbac Laboratories, Inc. are on file at the laboratory and are available for inspection.

Procedures are based on those prescribed by the Health and Safety Laboratory of the U.S. Dept of Energy, Edition 28, 1 997, U.S. Environmental Protection Agency for Measurement of Radioactivity in Drinking Water, 1980, and the U.S. Environmental Protection Agency, EERF, Radiochemical Procedures Manual, 1984.

Microbac Laboratories, Inc.

Northbrook has a comprehensive quality control/quality assurance program designed to assure the reliability of data obtained.

Details of the QA Program are presented elsewhere (Microbac Laboratories, Inc.

- Northbrook, 2023). The QA Program includes participation in Interlaboratory Comparison (crosscheck) Programs.

Results obtained through Quality control samples and crosscheck program results are presented in Appendix A.

Environmental TLDs are processed by Environmental Dosimetry Company, affiliated with Stanford Dosimetry, LLC.

3.5 Program Modifications Food Products Leafy Green Vegetables Collection and Analysis was modified by removing the previous control location Vi 2 due to individual no longer wanting to participate in program. The new control location is V20, Nathaniel Kline.

3.6 Detection and Reporting Limits Table 5.3 gives the minimum required detection limits for radiological environmental sample analysis. For each sample type, the table lists the detection level for each isotope. The lower limit of detection (LLD) used in this report is described in NRC Regulatory Guide 4.1 Rev. 1, Program for Monitoring Radioactivity in the Environs of Nuclear Power Plants and the NRC Radiological Assessment Branch Technical Position, Rev.

1, November 1 979, An Acceptable Radiological Environmental Monitoring Program.

6

3.7 Land Use Census The Land Use Census is performed annually during the growing season.

In 2023 the field inspection of the sectors was conducted September 27, 2023, within a five-mile radius of the Callaway Energy Center. The area around the plant was divided into 1 6 meteorological sectors.

The locations of the nearest resident, nearest milk animal, and nearest garden of greater than 500 square feet producing broadleaf vegetation were identified.

The results of the census are presented in Table 5.4.

The table includes radial direction and distance from the Callaway Energy Center for each location. The bearings listed in Table 5.4 were measured from the Callaway Plant to the sample location.

There are no changes to the closest residents in 2023.

A potential new garden was identified in sector R. No milking animals were located during the survey however one resident stated that they are in the process of acquiring cows and anticipate having goats milking sometime in 2024. We intend to update ODCM and Land Use as required once we are notified of the actual start of milking and usage.

All residents included in the summary were verified by the Callaway County Assessors GIS aerial photography.

The Missouri Department of Natural Resources has not identified any new water wells along the Mud Creek or Logan Creek corridors.

The US Army Corps of Engineers was contacted and they confirmed that no new drinking water intakes have been located along the Missouri River within ten (1 0) river miles downstream from the Callaway Plant.

In addition, no irrigation uses of the Missouri River were identified between the discharge point and Portland, MO during the survey.

3.8 Errata from previous Annual Radioloalcal Environmental Operating Reports None.

7

4.0 RESULTS AND DISCUSSION All collections and analyses were made as scheduled, except for those listed in Table 5.5.

Results are summarized in Table 5.6 as recommended by the Nuclear Regulatory Commission.

For each type of analysis and sample medium, the table lists the mean and range of all indicator and control locations, as well as that location with the highest mean and range.

The tabulated results of all measurements are not included in this section, although references to these results will be made in the discussion. A complete tabulation of results for 2023 is contained in Part II of the Annual Report on the Radiological Environmental Monitoring Program for the Callaway Energy Center.

4.1 Atmospheric Nuclear Detonations and Nuclear Accidents The Fukushima Dalichi nuclear accident occurred March 1 1, 201 1

. There were no reported accidents involving significant release to the environment at nuclear reactor facilities in 2023. The last reported atmospheric test was conducted on October 1 6, 1 980, by the Peoples Republic of China. There were no reported atmospheric nuclear tests in 2023.

4.2 Program Findings Airborne Particulates and Iodine No gamma-emitting isotopes were identified other than naturally occurring Be-f. There was no I-i 31 activity detected in any of the charcoal canister samples.

Air sampling for 2023 indicates no radiological effects of plant operation.

Direct Radiation (TLD5)

Forty-four gamma sensitive TLDs were placed in 1 6 sectors around the Callaway site each quarter.

Measurements from forty-one indicator locations averaged 1 5.0 mrem/quarter and the three control locations averaged 14.1 mrem/quarter. Readings ranged from 9.8 to 17.5 mrem /quarter, with the highest quarterly average from the indicator location CA-IDM-10, averaging 16.7 mrem/quarter.

The TLD readings were consistent with the results for the years 2000 through 2022 as detailed in table 5.7.

Five neutron sensitive TLDs were placed in locations at the Site Boundary closest to the Independent Spent Fuel Storage Facility Installation (ISFSI) and at a control location approximately 14 miles from the site. There was no significant measurable neutron dose and there was no effect from the ISFSI in 2023.

Milk Sampling has been discontinued since 201 8 because there are not enough sampling locations to fulfill the milk sampling requirement.

No milking animals were located during the 2023 Land Use Census. Leafy green (broadleaf) vegetation sampling was performed in lieu of milk sampling.

8

4.2 Program Findings (continued)

Broadleaf Vegetation There was no I-i 31 activity detected in broadleaf vegetation samples. No gamma-emitting isotopes were detected in broadleaf vegetation samples except for naturally occurring potassium-40.

Vegetation data for 2023 show no radiological effects of plant operation.

Fish Edible portions of fish were analyzed by gamma spectroscopy. No gamma-emitting isotopes, except for naturally occurring potassium-40, were detected in fish.

Soil Cesium-i 37 activity was detected at six of the seven indicator sample locations at an average concentration of 1 71 pCi/kg dry. The cesium-i 37 activity is consistent with levels observed from 1 999 through 2022; these levels are attributable to the deposition of fallout from previous decades.

Surtace Water Tritium was detected in nine out of the thirteen samples tested in 2023 at the downstream location 502 ranging from 205 pCi/L to 1 1 63 pCl/L.

No gamma-emitting isotopes were detected in any of the samples taken in 2023.

Surface Water, Ponds No tritium or gamma activity was detected in any of the twelve pond samples analyzed in 2023.

Drinking Water Wells (potable water)

Sixty-four samples from sixteen different locations were analyzed for tritium and gamma-emitting isotopes in 2023. No tritium or gamma-emitting isotopes were detected.

Wells and Ponds (non-potable water)

Eight groundwater samples from deep wells F-05 and F-15 were analyzed for tritium and gamma-emitting isotopes. No tritium or gamma emitting isotopes detected form any of the deep well samples taken in 2023.

Twenty-six samples from the wells that were part of the limited site investigation (LSI) in 201 4 were analyzed for tritium in 2023 including Wells CA-WWA-Ui MW-031

, CA-WWA-Ui MW-034, CA-WWA-Ui MW-036, CA-WWA-Ui MW-039, CA-WWA-Ui MW-047, CA-WWA-Ui MW-058 and CA-WWA-Ui MW-059.

Fourteen were positive ranging from 1 95 to 370 pCi/L with an average concentration of 253 pCi/L. These levels were a slight decline from 2022 and show that the natural attenuation described in previous AREORs is continuing.

Wells, CA-WWA-Ui MW-GWS, CA-WWA-Ui MW-937B, CA-WWA-Ui MW-937D, CA-WWA Ui MW-939R, CA-WWA-Ui MW-940, CA-WWA-Ui MW-941 and CA-WWA-Ui MW-IFSFI (sump) are in the Plant Protected Area adjacent to the power block. As described in previous AREORs, the tritium activity in the wells within the power block are believed to be the result of washout from gaseous effluents. The 2023 results are consistent with the results from 201 5 through 2022 and demonstrate the continued decline from previous years due to natural attenuation.

9

4.2 Program Findings (continued)

Sediments Two samples of shoreline sediments were collected in May and again in September of 2023 at both an indicator and a control location and analyzed for gamma-emitting isotopes. Cesium-i 37 was detected at both the indicator and control location for the September collection at a level of 52.0 and 53.4 pCi/kg dry respectively; these levels are attributable to the deposition of fallout from previous decades. No other gamma-emitting isotopes were detected excepting naturally occurring potassium-40 in any of the sediment samples.

10

5.0 TABLES 11

Table 5.1. Sampling Locations. (TLDs) Update with additions (it any) and deletions la 10.8 mi. 3100 NW 1DM 3

1.2mL3O8° NW 1DM 5

1.3mi79°ENE 1DM 6

2.Omi.274°W 1DM 7

1.4m1.184°S 1DM 9

3.8mL183°S 1DM 10 3.9 mi. 159° SSE 1DM ha 4.7mL139°SE 1DM 14 4.9m1.122°ESE 1DM 17 3Jmi.88°E 1DM 18a 3.Zmi.67°ENE 1DM 20 47mi.46°NE 1DM 21 3.8 mi. 23° NNE 1DM 22a O.9mi1O°NNE 1DM 23 6.6 mi. 15° NNE 1DM 26 11.7mL82°E 1DM 27 9.3mi114°ESE 1DM 30a 4.4m1.206°SSW 1DM 31a 7.8mi.224°SW 1DM 32 5.4mi.250°WSW 1DM 32a 5.Omi.243°WSW 1DM 33 7.4mL272°W 1DM 34 9.5 mi. 292° WNW 1DM 35 5.8 mi. 34O NNW 1DM 36 4.9mi.7°N 1DM 37 O.5mL195°SSW 1DM 38 4.6mi.334°NNW 1DM 39 5.4m1312°NW 1DM 39a 5.0 mi. 308° NW 1DM 40 4.2m1.292°WNW 1DM 41 5.2 mi. 277° W 1DM 42 4.4m1.231°SW 1DM 43 O.5mL223°SW 1DM 44 1.7m1.254°WSW 1DM 45 1.0 mi. 285 ° WNW 1DM 46 1.5mL328°NNW 1DM 47 1.OmLlO°N 1DM 48 0.4 mi.

NE 1DM 49 1.6mi.95°E 1DM 50 0.9 mi. 168° SSE 1DM 51a O.3mL15O°SE 1DM 52 0.4 ml. 1 1 1 ° ESE 1DM 6O 13.5mL224°SW 1DM Location Distance I Sample Code Direction Description Types 2 City of Fulton on Hwy Z, 0.65 mi. E of Bus. 54, W of Campus Apartments 0.1 mi. West of Hwy CC on Gravel RU., 0.8 mi. South Hwy 0 Meteorological Tower Cty Rd. 428, 1.2 mi. West of Hwy CC Cty Rd. 459, 2.6 mi. North of Hwy 94 NW Side of the Cty Rd. 459 and Hwy 94 Junction Hwy 94, 1.8 mi. East of Cty Rd. 459 City of Portland SE Side of Intersection Hwy D and Hwy 94 Cty Rd. 4053, 0.3 mi. E of Hwy 94 East side of Hwy D, 0.5 mi. South of Hwy 0 City of Readsville Cty Rd. 1 55, 1.9 mi. North of Hwy 0 Cty Rd 448, 0.9 mi south of HWY 0, co-located with air station A8 City of Yucatan Town of Americus Town of Bluifton City of Steedman, N side of Belgian Dr., 1 50 ft. East of Hwy CC City of Mokane, Jct. Hwy C and Cty Rd. 400, 0.9 mi. N. of Hwy 94 Hwy VV, 0.6 mi. west of Cty Rd. 447 Cty Rd. 447 City of Hams Prairie, SE of Hwy C and Hwy AD Junction NE Side of Hwy C and Cty Rd. 408 Junction City of Toledo Cty Rd. 155, 0.8 mi. South of Cty Rd. 132 Cty Rd. 459, 0.9 mi. South of Hwy CC Cty Rd. 133, 1.5 mi. South of Hwy UU Cty Rd. 111 Cty Rd. 111 NE Side of Cty Rd. 1 1 2 and Hwy 0 Junction Hwy AD, 2.5 mi. East of Hwy C Cty Rd. 447, 2.6 mi. North of Cty Rd. 463 Cty Rd. 459, 0.7 mi. South of Hwy CC Hwy CC, 1.0 mi. South of Cty Rd. 459 Cty Rd. 428, 0.1 mi. West of Hwy CC NE Side of Hwy CC and Cty Rd. 466 Intersection Cty Rd. 448, 0.9 mi. South of Hwy 0 Cty Rd. 448, 1.5 mi. South of Hwy 0, Plant Security Sign Post Cty Rd. 448, Reform Wildlife Mgmt. Parking Area, Gate Post.

Cty Rd. 459, 3.3 ml. North of Hwy 94 Owner Control Fence, SE of the Water Treatment Plant Light Pole Near the East Plant Security Fence Just iast Tebbetts City skin 12

Table 5.1. Sampling Locations. (TLDs, continued)

Location Distance I D

t Sample Code Direction escrip ion Types 2 60N3 13.5 mi 224°SW Co-located with location 60 1DM 61 1.9 mi 334 ° NNW Community of Reform, Corner of CC and 0 1DM 61 N 1.9 mi 334 ° NNW Co-located with location 61 1DM 62N 1.2 mi. 308 ° NW Co-located with location 3 1DM 63N 0.9 mi. 1O NNE Co-located with air station A8 and location 22a 1DM 64N 1.0 ml. 285 ° WNW Co-located with location 45 1DM Table 5.1. Sampling Locations (Airborne Radioiodine and Particulate samples, Surface Ponds, Potable Water)

Al 1.3 mi. 79 ° ENE Meteorological Tower APT, AlO A7 9.5 mi. 312° NW C. Bartley Farm, Fulton, MO APT, AlO A8 0.9 mi. 1O NNE County Road 448, 0.9 miles South of Hwy 0 APT, AlO A9 1.9 mi. 334 ° NNW Community of Reform APT, AlO A10 0.89 mi 276°W EOF Parking lot APT, AlO Al 1 0.71 mi 1 66 ° SSE Sludge lagoons lift pumps area APT, AlO 3

2.9 mi. 1 68 ° SSE Potable water, County Road 448 Ward Residence DWA 4

2.6 mi. 1 58 ° SSE Potable water, County Road 448 Miller Residence DWA 5

2.5 mi. 1 53 ° SSE Potable water, County Road 448 Brucker Brothers Farm DWA 7

2.1 mi. 108° ESE Potable water, County Road 448 S. Kriete Residence DWA 8

3.4 mi. 1 93 ° 55W Potable water, County Road 457 Curry Residence DWA 9

2.9 mi. 204 ° SSW Potable water, County Road 457 Clardy Residence DWA 1 0 2.7 mi. 208 ° 55W Potable water, County Road 457 T. Dillon Residence DWA 1 2 3.6 mi. 165 ° SSE Potable water, County Road 464 J. Dillon Residence DWA 21 2.4 mi. 1 20 0 ESE Potable water, County Road 469 Baumgarth Residence DWA 22 4.8 mi. 140 ° SE Potable water, State Road 94 Plummer Residence DWA 23 5.6 mi. 142° SE Potable water, County Road 466 Curdt Residence DWA 24 2.9 mi. 203 ° 55W Potable water, County Road 457 Farley Residence DWA 25 1.89 mi. 79 ° E Potable water, County Road 448 M. Kriete Residence DWA Vl 6 1.64 mi. 255 ° WSW Potable water, Hwy CC Wallendorf Farm, Steedman, MO DWA Vl 9 3.28 Ml. 1 62 0 SSE Potable water, Dillon Drive, Dillon Farm, Portland, MO DWA PW1 Callaway Cafeteria, Potable water, Unit 1 Construction well #3 open from 400-1400 DWA 0.13 mi. 234° SW PondOl O.6mi.264°W FishingPond SWA PondO2 O.Zmi.232°SW FishingPond SWA Outfall 010 0.6 mi. 42° NE Stormwater Run-Oft Pond SWA Wetlands 01 0.6 mi. 1 52 ° SSE Wetlands Pond #1 SWA Wetlands 02 0.7 mi. 1 60 ° SSE Wetlands Pond #2 SWA Sludge Lagoon 0.8 mi. 1 53 ° In-service Sludge Lagoon SWA 501 4.8 mi. 1 50 ° SSE 555 feet Upstream of Discharge North Bank SWA 502 4.9 mi. 138° SE 1.1 River Miles Downstream of Discharge North Bank SWA 13

Table 5.1. Sampling Locations, Non-potable Groundwater Wells Location Distance I Sample Code Direction Description Types 2 Plant Peninsula Area, Ui MW-937B Monitoring Well, West of the Turbine Bldg.

WWA 0.04 ml. 209 ° SSW Plant Peninsula Area, U1MW-937D Monitoring Well, North of Discharge Monitor Tanks WWA 0.1 mi. 92° E Plant Peninsula Area, Ui MW-939R Monitoring Well, East of the Fuel Bldg.

WWA O.O5mi. 109°ESE Plant Peninsula Area, Ui MW-940 Monitoring Well, West of the Radwaste Bldg.

WWA 0.05 mi. 78° ENE Plant Peninsula Area, Ui MW-941 Monitoring Well, West of the Radwaste Bldg.

WWA 0.07 mi. 81 ° E Plant Peninsula Area, U1MW-GWS Ground Water Sump, West of Reactor Bldg. and Fuel Bldg.

WWA O.O2mi. 135° SE ISFSI sump, Near SF51 pad WWA Ui MW-ISFSI 0.08 mi. 21 ° NNE Ui MW-004 3.7 mi. 1 65 ° SSE South of Dillon residence, Groundwater Monitoring Well WWA South of Brownlee I Hudson residence, Groundwater Monitoring WWA UYMW-005 3.8 mi. 160° SSE Well Ui MW-006 3.0 mi. 1 71 ° S South of Ward Residence, Groundwater Monitoring Well WWA UYMW-O1O 3.1 mi. 173° S Old Pipeline Bed, Groundwater Monitoring Well WWA U1MW-013 0.8 mi. 159° SSE Pipeline Corridor, south of sludge ponds WWA U1MW-014 3.7 mi. 171 ° S Pipeline Corridor, near manhole 6B WWA UYMW-015 3.9 mi. 162° SSE Pipeline Corridor, North of HWY 94.

WWA UYMW-016 4.5 mi. 151 ° SSE Pipeline Corridor, near heavy haul road at intake structure WWA U1MW-O1Z 3.68 mi. 171 ° S Pipeline Corridor, near manhole 6B WWA U1MW-018 3.75 mi. 172° 5 Pipeline Corridor, near manhole 6B WWA UYMW-019 3.71 mi.172° S Pipeline Corridor, near manhole 5 WWA UYMW-020 3.88 mi.164° SSE Pipeline Corridor, near manhole 3B WWA UYMW-031 0.18 mi. 78° ENE 1m from manhole 86-2 & lm from HDPE discharge pipeline WWA UYMW-034 0.21 mi. 98° E 13Om from manhole 86-2, HDPE discharge line bedding WWA 3OOm from MH 86-2, HDPE discharge line bedding at cross WWA U1MW-036 0.26 mi. 122° ESE connection pipe 1 lOOm from manhole 86-2, HDPE discharge line bedding U1MW-039 0.61 mi. 168° SSE WWA outside OCA Ui MW-047 4.56 mi. 151 ° SSE Upstream side of HDPE gate valve vault at intake structure inside WWA HDPE pipeline bedding U1MW-058 0.31 mi. 132° SE 4OOm from manhole 86-2, Techite discharge line bedding WWA 1 700m from MH86-2, Techite discharge line bedding outside U1MW-059 1.O4mi.166°SSE WWA OCA U2 MW 25 1.8 mi. 5 ° N Located on the periphery of the plateau WWA U2 MW 5S 1.1 mi. 261

° W Located on the periphery of the plateau WWA U2 MW 8 0.4 mi. 1 2 ° NNE Located radially outward from central part of the plateau WWA Located along Mud Creek, Farley Property, screened for CJC U2 MW 1 6 2.9 mi. 203 ° 55W WWA aquifer F05 0.9 mi. 1 69 ° S CJC aquifer monitoring well WWA Outside OCA fence in center portion of plateau, screened for CJC F15 0.4 mi. 29° NNE WWA aauifer 14

Table 5.1. Sampling Locations, Soil, Food Products, Milk, Fish, and Sediments.

Location Distance I Descri tion Sample Code Direction1 p

Types2 F2 1.0 ml. 235 ° SW Callaway Plant Forest Ecology Plot F2.

SQL F6 1.6 ml. 51 ° NE Callaway Plant Forest Ecology Plot F6.

SQL PR3 0.95 mi. 1 08 ° ESE Callaway Plant Forest Ecology Plot PR3.

SQL PR7 0.46 mi. 320 ° NNW Callaway Plant Forest Ecology Plot PR7.

SQL WY 0.52 mi. 1500 SSE Callaway Plant Wetlands #1, High Ground.

SQL W2 0.55 mi. 155° SSE Callaway Plant Wetlands #1, Inlet Area.

SQL W5 O.8 mi. 153° SSE5 In-service Sludge Lagoon.

SQL W6 0.67 mi. 154 ° SSE Callaway Plant Wetlands #2, inlet area SQL 93 1 3 mi. 228 ° SW Ferguson Farm, Tebbetts, MQ.

SQL V9 1.9 mi. 294 ° WNW Meehan Farm, Steedman, MQ FPL vi 6 1.64 mi. 255 ° WSW Wallendorf Farm, Steedman, MQ FPL V19 3.28 mi. 162°SSE Richard and Amy Dillon Farm FPL V20 17.73 mi. 238°WSW Nathaniel Kline, 3651 State Road AA, Holts Summit, MQ FPL A 3,6

-4.8 mi. 150 ° SSE 0.6 and 10.0 river miles upstream of the plant AQF A

-4.8 mi. 1 50 ° SSE Upstream of the plant intake.

AQS Downstream, of the plant discharge, between the C 6 4.9 mi. 138° SE confluence ofthe Missouri River and Logan Creekand the AQF Portland boat ramp C

4.9 mi. 1 38 ° SE Vicinity of Portland north bank AQS 1 Distances are measured from the midpoint of the two reactors as described in Final Safety Analysis Report (FSAR) Sec.

2.1.1.1.

2 AIQ = Air Iodine, APT = Air Particulate, AQF = Fish, AQS = Sediment, FPL = Leafy Green Vegetables, FC = Food Crops, 1DM = ILD, MLK = Milk, SQL = Soil, SWA = Suriace Water, DWA = Drinking Water, WWA = Ground Water.

3 Control Location.

4 Property ownership changed from Brandt to Curry in 2022.

5 The coordinates of the in-service sludge lagoon are determined at the time of sampling in accordance with HTP-ZZ-07101 -

DTI-REMP-SMPL-SCHED.

6 The expanded collection areas provide sufficient habitat to collect the required number of species, see HTP-ZZ-071 01 -DTI REMP-SMPL-SCHED.

15

Table 5.2. Collection Frequencies and Required Analyses (January 1 through December 31, 2023)

Sample Type Collection Frequency Required Analyses Gamma dose for each sample.

Direct radiation 1DM Quarterly Neutron dose for the samples monitoring ISFSI direct radiation.

Airborne iodine AlO Weekly 1311 Air particulate APT Weekly PGE3 each sample Surface water (river)

SWA Monthly composite PGE and 3H S rface ter tonsite PGE and 3H.

If contaminated with ond&

SWA Semiannually gamma emitting nuclides of plant p

origin, analyze for HTD4 nuclides.

PGE and 3H.

If contaminated with Groundwater (not potable)

WWA Quarterly5 gamma emitting nuclides of plant origin, analyze for HTD4 nuclides. 6 PGE and 3H.

If contaminated with Well water-potable DWA Quarterly gamma emitting nuclides of plant origin, analyze for HTD4 nuclides.

Shoreline sediment AQS Semiannually PGE Sludge pond sediment SQL Annually PGE Soil SQL Annually PGE Semimonthly when Milk animal MLK animals are on pasture, PGE and 1311 monthly other times Leafy green vegetables FPL Monthly when available 2 PGE and 1311 Fish AQF Semiannually PGE on edible portion 1 Samples required by ODCM unless specified otherwise.

2 The growing season is defined as the months April 1 - November 1 but will vary according to weather conditions.

3 Principal Gamma Emitters (PGE) are defined as 54Mn, 59Fe, 58Co, 60Co, 65Zn, 95Zr/Nb, 134Cs, 137Cs, 140B&La and other gamma-emitting nuclides that may be identified during the gamma spectroscopy analysis.

4 Hard to Detect (HID) nuclides are defined as 89Sr, 90Sr, 55Fe, 63Ni, 237Np, 238Pu, 9/240Pu, 241Pu, 241Am, 242Cm and 243/244Cm.

5 Monthly for locations Ui MW-937B, Ui MW-937D, Ui MW-939R, Ui MW-940, Ui MW-941 and Ui MW-GWS.

6Wells ISFSI Sump, UYMW-18, U1MW-19, U1MW-20, U1MW-31, U1MW-34, U1MW-36, U1MW-39, U1MW-47, Ui MW-58, Ui MW-59, U2MW-2S, U2MW-5S, U2MW-8, and U2MW-1 6 are analyzed for tritium only.

16

Table 5.3.

Minimum Required Detection Capabilities for REMP Sample Analysis1 Food Non-Food Soil and Water Airborne Fish Milk Analysis (pCUL)

(pCUm3)

(pCi/kg wet)

(pCi/L)

Products Products Sediment (pCi/kg wet)

(pCi/kg wet)

(pCi/kg dry)

H-3 3OOO/2OOO 3000 Mn-54 15 130 Fe-59 30 260 Co-58/60 15 130 Zn-65 30 260 Zr-Nb-952 15 1-131 1000/1 0.07 1

60 Cs-134 15 0.05 130 15 60 60 150 Cs-137 18 0.06 150 18 80 80 180 Ba-La-1402 15 15 1 This list does not mean only these nuclides will be detected and reported. Other peaks which are measurable and identifiable will be reported.

2 Total activity, parent plus daughter activity.

3 LLDs for Surface and Drinking I Ground water are the same, with the exception of H-3 and -131. The Drinking I Ground water LLDs for H-3 and -131 are 2000 and 1 pCi/liter respectively.

17

Table 5.4 2023 Land Use Census Results.

Closest Receptor in Miles Sector Residence Garden j

2 N(A) 2.37 NI NI NNE(B) 2.16 2.97 NI NE(C) 2.26 NI NI ENE(D) 2.86 NI NI E(E) 3.51 NI NI ESE(F) 2.11 4.47 NI SE(G) 2.72 NI NI SSE(H) 3.11 3.28 NI S(J) 2.86 NI NI SSW(K) 2.38 NI NI SW(L) 2.63 2.72 NI WSW(M) 1.20 1.96 NI W(N) 1.56 3.55 NI WNW(P) 1.93 1.93 NI NW(Q) 2.07 NI NI NNW(R) 1.81 NI NI 1

NI = None Identified.

2 Broadleaf Vegetation 18

Table 5.5. Missed Collections and Analyses, Callaway Energy Center Sample Collection Date Type Analysis Location(s) or Period Comments WWA H-3 CA-VWA-UYMW-47 02/24/2023 No water due to dry well (CR#202301282).

(CA-FPL-V9, CA-FPL-V16, No viable vegetable samples available CA-FPL-V1 9, April 2023 (CR#202302405).

FPL Gamma CA-FPL-V20)

Unable to collect vegetables due to growing FPL Gamma CA-FPL-V9 May 2023 conditions (CR#202303264).

WWA H-3 CA-WWA-U1 MW-47 05/31/2023 No water due to dry well (CR#202303703).

1DM Gamma CA-IDM-1O 2 Quarter 23 TLD missing in field (CR#202302537).

CA-WWA-U1 MW-004 WWA H-3 CA-WWA-U1 MW-005 1 1/13/2023 No water due to dry well (CR#202308663).

CA-WWA-U1 MW-047 19

Table 5.6 Radiological Environmental Monitoring Program Summary Number Indicator Location with Highest Control Non-Sample Type and Locations Annual Mean Locations Routine Reqd

Mean, Mean, Results(e)

Type Number of LLD(b)

Fraction, Mean,
Fraction, (Units)

Analyses(a)

Range (c)

Location (U)

Fraction, Range (c)

I__Range_(c)

Waterborne Pathway 579(9/13)

Surface Water H-3 25 3000 (205-1163)

ND 0

(pCi/L)

GS 25 (b)

ND ND 0

Surface Water, H-3 12 3000 ND None 0

Ponds (pCi/L)

CS 12 (b)

ND None 0

H-3 64 2000 ND ND 0

Potable Wells (pCi/L)

CS 64 (b)

ND ND 0

Wells 460 (61/172)

CA-WWA-GWS 858 (12/13)

None 0

H-3 172 3000 (non-potable)

(178-2410) 0.02 mi. 135°! SE (194-2410)

(pCi/L)

CS 116 (b)

ND None 0

Cs-134 4

150 ND ND 0

Sediments (pCi/kg) dry Cs-137 4

180 0

52(1/2) 53(1/2)

Airborne Pathway Airborne Particulates CS 312 (b)

ND None 0

(pCi/m3)

Airborne 1-131 312 0.07 ND None 0

Iodine (pCi/m3)

Soil Cs-134 9

150 ND ND 0

Soil (pCi/kg) dry Cs-137 9

180 171 (6/7)

F-006 281 (1/1) 0 (47-281) 1.Smi.51°/NE ND 20

Table 5.6 Radioloaical Environmental Monitorina Proaram Summary Indicator Location with Highest Control Sample Type and Locations Annual Mean Locations Number Type Number of Reqd Mean Non-

Mean, LLD(b)
Fraction, Location (d)

J

Mean, Fraction, Routine (Units)

Analyses(a)

Results(e)

Range (c)

Fraction, Range (c)

Range_(c)

Ingestion Pathway Food Products LeafyGreen GS 70 (b)

ND ND 0

Vegetables (pCi/kg wet)

Fish Edible Flesh GS 20 (b)

ND ND 0

(pCi/kg) wet 1-131 0

1 none ND 0

Milk (pCi/L)

GS 0

(b) none ND 0

Direct Radiation (Quarterly 15.0 (163/163)

CA-IDM-1O 16.7 (3/3) 14.1 (12/12) o TLDs)

Gamma 175 (10.2-172) 3.9m1. 159°SSE (16.2-17.2)

(9.8-17.5)

(mrem/Qtr)

Neutron 20 ND ND 0

(a) GS = gamma spectroscopy.

(b) LLD = nominal lower limit of detection based on a 4.66 sigma counting error for background sample. LLDs for gamma spectroscopy are in Table 5.3.

(c) Mean and range are based on detectable measurements only. Fraction of detectable measurements at specified locations is indicated in parentheses (F). ND= not detected.

(d) Locations are specified by station code (Table 5.2) and distance (miles) and direction relative to reactor site.

(e) Non-routine results are those which exceed ten times the control station value.

If no control station value is available, the result is considered non-routine if it exceeds ten times the preoperational value for the location.

(f) Units: pCi/L.

21

Table 5.7 Direct Radiation Dose (mrem/90 days) for the Period 2000-2022.

Station Code Mean 3a Mean ÷ 3a Max CA-IDM-YA 15.8 2.8 18.6 18.0 CAIDM3*

16.8 2.8 19.6 20.0 CA-IDM-5 14.2 2.7 16.9 17.1 CA-IDM-6 16.2 3.5 19.7 19.0 CA-IDM-7 16.0 3.1 19.1 19.0 CA-IDM-9 14.9 2.5 17.4 17.0 CA-IDM-10 16.9 2.7 19.6 19.3 CA-IDM-11A 16.9 3.0 19.9 19.3 CA-IDM-14 15.8 2.7 18.5 18.7 CA-IDM-17 15.9 3.1 18.9 18.3 CA-IDM-18A 16.0 4.4 20.4 18.9 CA-IDM-20 16.4 2.8 19.3 19.3 CA-IDM-21 16.2 3.4 19.6 19.0 CAIDM22A*

14.2 5.3 19.5 18.0 CA-IDM-23 16.5 2.6 19.1 19.0 CA-IDM-26(C) 11.3 2.3 13.6 13.1 CA-IDM-27(C) 17.1 2.9 19.9 20.0 CA-IDM-30A 15.6 2.7 18.3 18.2 CA-IDM-31A 16.8 2.7 19.5 19.0 CA-IDM-32 16.6 2.8 19.4 19.0 CA-IDM-32A 15.9 3.9 19.8 20.0 CA-IDM-33 15.9 2.7 18.5 18.0 CA-IDM-34 15.3 2.8 18.1 18.0 CA-IDM-35 14.7 2.6 17.2 17.3 CA-IDM-36 15.2 3.5 18.7 18.7 CA-IDM-37 15.7 2.8 18.5 18.0 CA-IDM-38 11.3 2.2 13.6 13.9 CA-IDM-39 15.6 3.2 18.8 19.0 CA-IDM-39A 16.2 3.4 19.6 19.0 CA-IDM-40 16.7 3.4 20.1 19.2 CA-IDM-41 15.6 3.2 18.8 19.0 CA-IDM-42 13.6 2.5 16.1 16.2 CA-IDM-43 15.8 2.9 18.7 18.7 CA-IDM-44 16.1 3.3 19.4 19.0 CAIDM45*

14.7 3.2 17.9 20.0 CA-IDM-46 16.3 2.7 19.0 19.9 CA-IDM-47 15.5 2.8 18.3 18.0 CA-IDM-48 16.4 2.9 19.3 19.0 CA-IDM-49 15.2 3.2 18.4 18.0 CA-IDM-50 16.1 3.0 19.1 20.0 CA-IDM-51A 16.9 2.7 19.6 19.8 CA-IDM-52 16.5 2.8 19.3 19.1 CAIDM60(C)*

j59 2.7 18.6 18.0 CAIDM61*

14.1 4.1 18.2 15.7

  • ISFSI monitoring (C) Control location 22

6.0 REFERENCES

Arnold, J. R. and H. A. Al-Salih. 1955. Beryllium-7 Produced by Cosmic Rays. Science 121: 451-453.

Eisenbud, M. 1963. Environmental Radioactivity, McGraw-Hill, New York, New York, pp. 213, 275-276.

Environmental, Inc., Midwest Laboratory. 2001

- 2020. Environmental Radiological Monitoring Program for the Callaway Energy Center, Annual Report

- Part II, Data Tabulations and Analyses, January

- December, 2000 2022 2022.

Quality Manual, Rev. 8, 1 7 October 2022.

2022.

Quality Control Procedures Manual, Rev. 5, 9 May 2022.

2012.

Quality Assurance Program Manual, Rev. 3, 14 November 2012.

2009.

Quality Control Program, Rev. 2, 12 November 2009.

Microbac Laboratories-Northbrook (Before June 1, 2023 Environmental Inc.)

2023.

Quality Manual, Rev. 9, 25 August 2023..

Gold, S., H. W. Barkhau, B. Shlein, and B. Kahn, 1 964. Measurement of Naturally Occurring Radionuclides in Air, in the Natural Environment, University of Chicago Press, Chicago, Illinois, 369-382.

Hammer, Gregory R.,Climate of Missouri, monograph available from the National Climatic Data Center (NCDC) of the National Oceanic and Atmospheric Administration (NOAA). January, 2006.

National Center for Radiological Health, 1 968. Radiological Health and Data Reports, Vol. 9, Number 1 2, 730-746.

Stanford Dosimetry, LLC, 24 March 2023.

Environmental Dosimetry Company, Annual Quality Assurance Status Report, January-December, 2023.

Teledyne Brown Engineering Environmental Services, Midwest Laboratory. 1 999

- 2000. Environmental Radiological Monitoring Program for the Callaway Plant, Annual Report

- Part II, Data Tabulations and Analyses, January

- December, 1998

- 1999.

U.S. Environmental Protection Agency, 2007.

RadNet, formerly Environmental Radiation Ambient Monitoring System, Gross Beta in Air (MO) 1 981 2006, Gross Beta in Drinking Water (MO) 1 982 2004.

Wilson, D. W., G. M. Ward and J. E. Johnson.

1969.

Environmental Contamination by Radioactive Materials, International Atomic Energy Agency. p.125.

23

(MICROBAC 700 Landwehr Road

  • Northbrook, IL 60062-2310 phone (847) 564-0700
  • fax (847) 564-4517 APPENDIX A INTERLABORATORY AND INTRALABORATORY COMPARISON PROGRAM RESULTS NOTE:

Appendix A is updated four times a year. The complete appendix is included in March, June, September and December monthly progress reports only.

January, 2023 through December, 2023

ADiendix A Interlaboratorv/ Intralaboratory Comparison Program Results Microbac Laboratories

- Northbrook (previously Environmental Inc.) has participated in interlaboratory comparison (crosscheck) programs since the formulation of its quality program in December 1971.

These programs are operated by agencies and/or companies which supply environmental sample types containing concentrations of radionuclides known to the issuing entity but not to participant laboratories.

The purpose of such a program is to provide an independent check on a laboratorys analytical procedures and to alert it of any possible problems.

Participant laboratories measure the concentration of specified radionuclides and report them to the issuing agency. Several months later, the agency reports the known values to the participant laboratories and specifies control limits.

Results consistently higher or lower than the known values or outside the control limits indicate a need to check the instruments or procedures used.

Results in Table A-I were obtained through participation in the RAD PT Study Proficiency Testing Program administered by Environmental Resource Associates, serving as a replacement for studies conducted previously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada.

Table A-2 lists results for thermoluminescent dosimeters (TLD5), via irradiation and evaluation by the University of Wisconsin-Madison Radiation Calibration Laboratory at the University of Wisconsin Medical Radiation Research Center.

Table A-3 lists results of the analyses on intralaboratory spiked samples for the past twelve months. All samples are prepared using NIST traceable sources. Data for previous years available upon request.

Table A-4 lists results of the analyses on intralaboratory blank samples for the past twelve months. Data for previous years available upon request.

Table A-5 lists analytical results from the intralaboratory duplicate program for the past twelve months. Acceptance is based on each result being within 25% of the mean of the two results or the two sigma uncertainties of each result overlap.

The results in Table A-6 were obtained through participation in the Mixed Analyte Performance Evaluation Program.

Results in Table A-f were obtained through participation in the MRAD PT Study Proficiency Testing Program administered by Environmental Resource Associates, serving as a replacement for studies conducted previously by the Environmental Measurement Laboratory Quality Assessment Program (EML).

Attachment A lists the laboratory acceptance criteria for various analyses.

Out-of-limit results are explained directly below the result.

A-i

Attachment A ACCEPTANCE CRITERIA FOR INTRALABORATORY SPIKED SAMPLES Analysis Ratio of lab result to known value.

Gamma Emitters 0.8 to I.2 Strontium-89, 0.8 to 1.2 Strontium-90 Potassium-40 O.8to 1.2 Gross alpha 0.5 to I.5 Gross beta 0.8 to I.2 Tritium O8tol.2 Radium-226, O.Zto 1.3 Radium-228 Plutonium O.8to 1.2 Iodine-129, O.8to 1.2 Iodine-I 31 Nickel-63, O.Zto 1.3 Technetium-99, Uranium-238 lron-55 O.8toI.2 Other Analyses 0.8 to I.2 A-2

TABLE A-I Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.

RAD study Concentration (pCi/L)

Lab Code Date Analysis Laboratory ERA Acceptance Result Value Limits Acceptance RAD-1 32 Study RAD-134 Study a Resufts obtained by Microbac Laboratories Inc.

- Northbrook as a parbcpant in the crosscheck program for proficiency testing in drinking water conducted by Environmental Resource Associates (ERA).

b The Cobalt-60 result did not meet ERA acceptance criteria. The sample was reanalyzed and passed for all analytes.

(Co-60 reanalysis result was 21.2 +/- 3.0 pCi/L). No cause for the earlier failure could be determined.

ERDW-162 2/23/2023 Ba-133 33.0 +/- 3.5 30.5 24.2

- 34.6 Pass ERDW-1 62 2/23/2023 Cs-I 34 30.7 +/- 3.0 28.2 21.9

- 31

. 1 Pass ERDW-162 2/23/2023 Cs-137 191 +/-7 190 171 -211 Pass ERDW-162 2/23/2023 Co-60 1 10 +/- 4 1 10 99.0

- 123 Pass ERDW-1 62 2/23/2023 Zn-65 1 09 +/- 8 1 05 94.5

- I 25 Pass ERDW-162 2/23/2023 Gr. Alpha 25.3 +/- 0.2 30.0 15.3

- 39.2 Pass ERDW-162 2/23/2023 G. Beta 15.0 +/- 0.1 16.5 9.25

- 24.8 Pass ERDW-162 2/23/2023 Ra-226 7.58 +/- 0.52 8.26 6.21

- 9.71 Pass ERDW-162 2/23/2023 Ra-228 7.44+/-1.53 7.17 4.51 -9.20 Pass ERDW-162 2/23/2023 H-3 22600 +/- 467 21 600 18,900

- 23,800 Pass ERDW-1956 7/10/2023 Ba-133 64.1 +/- 4.7 66.5 55.4

- 73.2 Pass ERDW-1 956 7/1 0/2023 Cs-I 34 97.0 +/- 4.8 90.8 74.5

- 99.9 Pass ERDW-1956 7/10/2023 Cs-137 179 +/- 8 163 147

- 181 Pass ERDW-1956 7/10/2023 Co-60 26.6 +/- 2.9 20.7 17.5

- 25.6 Fail b ERDW-1956 7/10/2023 Zn-65 318 +/- 12 290 261

- 339 Pass ERDW-50167 7/10/2023 Gr. Alpha 34.3 +/- 1.9 47.9 24.9

- 60.3 Pass ERDW-50167 7/10/2023 G. Beta 27.4 +/- 1.2 28.6 18.2

- 36.4 Pass ERDW-50171 7/10/2023 Ra-226 19.3 +/- 0.9 17.4 12.9

- 19.9 Pass ERDW-50171 7/10/2023 Ra-228 7.11 +/- 1.59 7.16 4.50

- 9.18 Pass ERDW-50173 7/10/2023 H-3 10,500 +/- 326 9,860 8,570

- 10,800 Pass ERDW-50169 7/10/2023

-131 23.9 +/- 1.2 24.4 20.2

- 28.9 Pass A-3

THIS PAGE INTENTIONALLY LEFT BLANK.

A-4

THIS PAGE INTENTIONALLY LEFT BLANK.

A-5

TABLE A-3. Intralaboratory Spiked Samples Concentrationa Lab Codeb Date Analysis Laboratory results Known Control Ratio 2s, n=1C Activity Limitsd Acceptance Lab/Known SPDW-26 1/5/2023 Ra-228 11.8 +/- 1.9 13.4 9.4

- 17.4 Pass 0.88 SPDW-50002 1/1 1/2023 H-3 21 747 +/- 452 22,100 17,680

- 26520 Pass 0.98 SPDW-50004 1/20/2023 H-3 21,861 +/-458 22,100 17,680 -26,520 Pass 0.99 SPDW-50006 1/5/2023 Ra-226 11.3 +/- 0.3 12.3 8.6

- 16.0 Pass 0.92 SPDW-50034 1/27/2023 Ra-226 12.6 +/- 0.4 12.3 8.6

- 16.0 Pass 1.02 LCS-SO-012723 8/1/2020 Cs-134 17.1 +/- 0.2 19.2 15.4

- 23.0 Pass 0.89 LCS-SO-012723 8/1/2020 Zn-65 13.8 +/- 1.7 14.1 11.3

- 16.9 Pass 0.98 LCS-SO-012723 8/1/2020 Co-60 26.4 +/- 0.2 27.0 21.6

- 32.4 Pass 0.98 LCS-SO-012723 8/1/2020 Co-57 30.7 +/- 0.1 30.9 24.7

- 37.1 Pass 0.99 LCS-SO-012723 8/1/2020 Mn-54 17.7 +/- 0.8 16.5 13.2

- 19.8 Pass 1.07 LCS-SO-012723 8/1/2020 K-40 18.4 +/- 0.7 16.8 13.4

- 20.2 Pass 1.10 SPDW-50010 1/31/2023 Ra-228 9.7 +/- 1.3 13.4 9.4

- 17.4 Pass 0.72 SPDW-50008 2/3/2023 H-3 21,961 +/- 459 22,100 17,680

- 26,520 Pass 0.99 SPDW-50016 2/10/2023 H-3 22137 +/-462 22100 17,680 -26,520 Pass 1.00 SPDW-50012 2/24/2023 Sr-90 18.6 +/- 1.2 17.1 13.7

- 20.5 Pass 1.09 SPDW-50032 2/16/2023 Ra-228 13.1 +/- 1.9 13.4 9.4

- 17.4 Pass 0.98 SPDW-50018 2/16/2023 Gr. Alpha 19.1 +/- 1.3 23.5 11.8

- 28.2 Pass 0.81 SPDW-50018 2/16/2023 Gr.Beta 133+/-2 141 112-169 Pass 0.94 SPDW-50021 2/17/2023 H-3 21,843 +/- 459 22,100 17,680

- 26,520 Pass 0.99 SPDW-50047 2/24/2023 Ra-226 12.8 +/- 0.4 12.3 8.6

- 16.0 Pass 1.04 SPDW-50049 3/17/2023 H-3 22,120 +/- 465 22,100 17,680

- 26,520 Pass 1.00 SPDW-50056 3/24/2023 H-3 21,911 +/- 463 22,100 17,680

- 26,520 Pass 0.99 SPDW-50060 3/16/2023 Ra-226 12.9 +/- 0.4 12.3 8.6

- 16.0 Pass 1.05 SPDW-50097 4/13/2023 Ra-226 11.7 +/- 0.5 12.3 8.6

- 16.0 Pass 0.95 SPDW-50068 4/14/2023 H-3 22,656 +/- 482 22,100 17,680

- 26,520 Pass 1.03 SPDW-50081 4/25/2023 H-3 21,594 +/- 461 22,100 17,680

- 26,520 Pass 0.98 SPDW-50131 5/3/2023 Ra-226 11.4 +/- 0.3 12.3 8.6

- 16.0 Pass 0.93 SPDW-50104 5/12/2023 H-3 21,513 462 22,100 17,680

- 26,520 Pass 0.97 SPDW-50117 5/26/2023 H-3 22,069 468 22,100 17,680 -26,520 Pass 1.00 SPDW-50182 6/8/2023 Ra-226 10.4 +/- 0.3 12.3 8.6

- 16.0 Pass 0.85 SPDW-50137 6/12/2023 H-3 21,898 +/- 456 22,100 17,680

- 26520 Pass 0.99 SPDW-501 38 6/1 2/2023 H-3 21 898 +/- 456 22, 1 00 1 7,680

- 26,520 Pass 0.99 SPDW-50153 6/26/2023 H-3 21,672 +/- 456 22,100 17,680

- 26,520 Pass 0.98 SPDW-50153 6/26/2023 H-3 21,672 +/- 456 22,100 17,680

- 26,520 Pass 0.98 SPDW-50259 7/19/2023 Ra-226 10.5 +/- 0.3 12.3 8.6

- 16.0 Pass 0.85 SPDW-50219 8/15/2023 Sr-90 17.5+/-1.1 17.1 13.7-20.5 Pass 1.02 SPDW-50291 8/28/2023 Ra-226 11.0 +/- 0.3 12.3 8.6

- 16.0 Pass 0.89 SPDW-50249 8/22/2023 Gr. Alpha 16.7 +/- 1.4 23.5 11.8

- 28.2 Pass 0.71 SPDW-50249 8/22/2023 Gr. Beta 128 +/- 2 141 1 12

- 169 Pass 0.91 SPDW-50252 8/18/2023 H-3 21628 +/- 459 22,100 17,680

- 26520 Pass 0.98 SPDW-50257 8/25/2023 H-3 22,152 +/-469 22,100 17,680 -26,520 Pass 1.00 a Liquid sample results are reported in pCi/Liter, air filters ( pCi/m3), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).

b Laboratory codes : W & SPW (Water), Ml (milk), AP (air filter), SO (soil), VE (vegetation), CH (charcoal canister), F (fish), U (urine).

C Results are based on single determinations.

d Acceptance criteria are listed in Attachment A ofthis report.

A-6

TABLE A-3. Intralaboratory Spiked Samples Concentrationa Lab Codeb Date Analysis Laboratory results Known Control Ratio 2s, n=1C Activity Limitsd Acceptance Lab/Known LCS-09/12123 8/1/2020 Cs-134 17,533 +/- 346 19,170 15,336

- 23,004 Pass 0.91 LCS-09/12/23 8/1/2020 Co-60 27,480 +/- 347 26,055 20,844

- 31,266 Pass 1.05 LCS-09112/23 8/1/2020 K-40 20,183 1268 18,468 14,774

- 22,162 Pass 1.09 SPDW-50270 9/6/2023 H-3 22,287 +/- 469 22,100 17,680

- 26,520 Pass 1.01 SPDW-50283 9/25/2023 H-3 21,062 +/- 444 22,100 17,680

- 26,520 Pass 0.95 SPDW-50291 8/28/2023 Ra-226 11.0+/-0 12.3 8.6-16.0 Pass 0.89 SPDW-50316 10/3/2023 H-3 21,406 +/- 454 22,100 17,680

- 26,520 Pass 0.97 SPW-50330 11/17/2023 H-3 21,143 +/-543 22,100 17,680 -26,520 Pass 0.96 LCS-SO-112823 8/1/2020 Cs-134 17.2 +/-0.2 19.2 15.4 -23.0 Pass 0.90 LCS-SO-112823 8/1/2020 Zn-65 14.9 +/- 3.1 14.1 11.3

- 16.9 Pass 1.06 LCS-SO-112823 8/1/2020 Co-60 26.0 +/- 0.3 27.0 21.6

- 32.4 Pass 0.96 LCS-SO-112823 8/1/2020 Co-57 29.3 +/- 0.9 30.9 24.7

- 37.1 Pass 0.95 LCS-SO-112823 8/1/2020 Mn-54 17.5 +/- 1.3 16.5 13.2

- 19.8 Pass 1.06 LCS-SO-112823 8/1/2020 K-40 18.0 +/- 0.7 16.8 13.4

- 20.2 Pass 1.07 SPW-3908 12/18/2023 Nl-63 2,032 +/-27 1,788 1,430 -2,146 Pass 1.14 SPW-3910 12/18/2023 Fe-55 269 +/-24 232 186 -278 Pass 1.16 SPDW-50378 12/19/2023 H-3 21,102 +/-452 22,100 17,680

- 26,520 Pass 0.95 SPDW-50388 12/28/2023 H-3 20,540 +/-445 22,100 17,680 -26,520 Pass 0.93 SPDW-50393 12/19/2023 Ra-226 11.6 +/- 0.3 12.3 8.6

- 16.0 Pass 0.94 a Liquid sample results are reported in pCi/Liter, air filters ( pCi/m3), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).

b Laboratory codes : W & SPW (Water), Ml (milk), AP (air filter), SO (soil), VE (vegetation), CH (charcoal canister), F (fish), U (urine).

C Results are based on single determinations.

U Acceptance criteria are listed in Attachment A ofthis report.

A-7

TABLE A-4. Intralaboratory Blank Samples a Liquid sample results are reported in pCi/Liter, air filters ( pCi/m3), charcoal (pCi/charcoal canister), and solid samples (pCi/g).

b Laboratory codes W & SPW (Water), Ml (milk), AP (air filter), SO (soil), VE (vegetation), CH (charcoal canister), F (fish), U (urine).

C 1-131(G); iodine-131 as analyzed by gamma spectroscopy.

d Activity reported is a net activity result.

A8 Concentrationa Lab Codeb Sample Date Analysisc Laboratory results (4.66cr)

Acceptance Type LLD Activityd Criteria (4.66 c)

SPW-25 Water 1/5/2023 Ra-228 0.98 0.74 +/- 0.54 2

SPDW-50000 Water 1/6/2023

-131 0.36

-0.10 +/- 0.16 1

SPDW-50001 Water 1/1 1/2023 H-3 157 13 +/- 74 200 SPDW-50003 Water 1/20/2023 H-3 161 98 +/- 85 200 SPDW-50005 Water 1/5/2023 Ra-226 0.02 0.00 +/- 0.03 2

SPDW-50033 Water 1/27/2023 Ra-226 0.03

-0.01 +/- 0.03 2

SPDW-50009 Water 1/31/2023 Ra-228 1.40 0.69 +/- 0.75 2

SPDW-50007 Water 2/3/2023 H-3 160 17 +/-80 200 SPDW-50015 Water 2/10/2023 H-3 159 91 +/- 84 200 SPDW-5001 1 Water 2/9/2023 Sr-89 062 0.24 +/- 0.49 5

SPDW-5001 I Water 2/9/2023 Sr-90 0.66

-0.02 +/- 0.30 1

SPDW-50018 Water 2/16/2023 Gr. Alpha 0.62 0.01 +/- 0.44 2

SPDW-50018 Water 2/16/2023 Gr. Beta 0.78

-0.10 +/- 0.54 4

SPDW-50020 Water 2/17/2023 H-3 154 122 +/- 80 200 SPDW-50031 Water 2/16/2023 Ra-228 0.82 0.42 +/- 0.43 2

SPDW-50046 Water 2/24/2023 Ra-226 0.03 0.05 +/- 004 2

SPDW-50044 Water 3/13/2023

-131 0.15

-0.06 +/-008 1

SPDW-50048 Water 3/17/2023 H-3 163 80 +/- 80 200 SPDW-50055 Water 3/24/2023 H-3 169 63 +/- 82 200 SPDW-50059 Water 3/16/2023 Ra-226 0.04

-0.02 +/- 0.03 2

SPDW-50063 Water 3/28/2023 Ra-226 0.06

-0.01 +/- 0.05 2

SPDW-50067 Water 4/14/2023 H-3 173 92 +/- 87 200 SPDW-50069 Water 4/17/2023

-131 011

-0.05 +/- 0.08 1

SPDW-50102 Water 5/15/2023

-131 0.15

-0.01 +/- 0.08 1

SPDW-50103 Water 5/12/2023 H-3 161 67 +/- 80 200 SPDW-50116 Water 5/26/2023 H-3 161 122 +/-87 200 SPDW-50137 Water 6/12/2023 H-3 157 125 +/- 80 200 SPDW-50154 Water 6/26/2023 H-3 157 105 +/- 80 200 SPDW-50181 Water 6/8/2023 Ra-226 0.04

-0.07 +/- 003 2

SPDW-50218 Water 8/15/2023 Sr-89 0.66

-0.07 +/- 0.48 5

SPDW-50218 Water 8/15/2023 Sr-90 0.55 0.02 +/-0.26 1

SPDW-50248 Water 8/22/2023 Gr. Alpha 0.57

-0.03 +/- 0.40 2

SPDW-50248 Water 8/22/2023 Gr. Beta 0.70 0.28 +/- 050 4

SPDW-50256 Water 8/25/2023 H-3 161 75 +/- 84 200 SPDW-50258 Water 7/1 9/2023 Ra-226 0.06

-0.25 +/- 0.04 2

SPDW-50270 Water 9/6/2023 H-3 160 90 +/- 81 200 SPDW-50282 Water 9/25/2023 H-3 163 53 +/- 79 200 SPDW-50290 Water 8/28/2023 Ra-226 0.05 0.00 +/- 0.04 2

TABLE A-4. Intralaboratory Blank Samples a Liquid sample results are reported in pCi/Liter, air filters ( pCiIm3), charcoal (pCi/charcoal canister), and solid samples (pCilg).

b Laboratory codes : W & SPW (Water), MI (milk), AP (air filter), SO (soil), VE (vegetation), CH (charcoal canister), F (fish), U (urine).

C 1-131(G); iodine-131 as analyzed by gamma spectroscopy.

d Activity reported is a net activity result.

Concentrationa Lab Codeb Sample Date Analysisc Laboratory results (4.66a)

Acceptance Type LLD Activityd Criteria (4.66 a)

SPDW-5031 I Water 10/16/2023

-131 0.25 0.06 +/- 0.14 1

SPDW-50312 Water 10/3/2023 Ra-226 0.04 0.06 +/- 0.09 2

SPDW-503J5 Water 10/27/2023 H-3 169 5 +/- 79 200 SPDW-50329 Water 11/17/2023 H-3 170 51 +/- 82 200 SPDW-50379 Water 11/17/2023 Ra-226 0.05 0.09 +/- 0.04 2

SPDW-50346 Water 12/5/2023 H-3 0.10

-0.12 +/- 0.07 1

SPDW-50347 Water 12/5/2023 Ra-228 I.27

-0.07 +/- 0.62 2

SPW-3907 Water 12/18/2023 Ni-63 149 0 +/- 91 200 SPW-3909 Water 12/18/2023 Fe-55 435 7 +/- 265 2000 SPDW-50377 Water 12/19/2023 H-3 173

-42 +/- 78 200 SPDW-50387 Water 12/28/2023 H-3 171

-21 +/- 79 200 A-9

TABLE A-5. Intralaboratory Duplicate Samples Concentrationa Averaged Lab Codeb Date Analysis First Result Second Result Result Acceptance WW-65,66 1/10/2023 Cr. Beta 15.4 +/- 2.0 17.2 +/- 2.1 16.3 +/- 1.5 Pass WW-107,108 1/18/2023 H-3 153 +/- 88 132 +/- 87 143 +/- 62 Pass SG-187,188 1/30/2023 Gr. Alpha 28.1 +/- 3.9 22.0 +/- 3.5 25.1 +/- 2.6 Pass SG-187,188 1/30/2023 Cr. Beta 22.3 +/- 1.8 22.2 +/- 1.8 22.3 +/- 1.3 Pass SG-187,188 1/30/2023 Pb-214 4.08 +/- 0.16 3.38 +/- 0.09 3.73 +/- 0.09 Pass SG-187,188 1/30/2023 Ac-228 3.88 +/- 0.28 3.98 +/- 0.14 3.93 +/- 0.16 Pass SWU-201,202 1/31/2023 H-3 171 +/- 89 234 +/- 92 203 +/- 64 Pass SW-243,244 2/7/2023 H-3 358 +/- 98 262 +/- 93 310 +/- 68 Pass PW-266,267 2/6/2023 Ra-226 0.61 +/- 0.18 0.37 +/- 0.20 0.49 +/- 0.13 Pass DW-50028.50029 2/27/2023 Ra-226 0.68 +/- 0.13 0.76 +/- 0.13 0.72 +/- 0.09 Pass DW-50028.50029 2/27/2023 Ra-228 2.26 +/- 0.65 1.20 +/- 0.65 1.73 +/- 0.46 Pass DW-50052,50053 2/27/2023 Ra-228 0.48 +/- 0.57 1.19 +/- 0.65 0.84 +/- 0.43 Pass DW-50035,50036 2/28/2023 Cr. Alpha 3.68 +/- I 42 4.00 +/- I.29 3.84 +/- 0.96 Pass DW-50035,50036 2/28/2023 Cr. Beta 2.50 +/- 0.64 1.99 +/- 0.64 2.25 +/- 0.45 Pass LW-518,519 3/8/2023 Cr. Beta 1.71 +/- 0.64 1.38 +/- 0.64 1.55 +/- 0.45 Pass SC-571,572 3/8/2023 Pb-214 7.80 +/- 0.46 8.20 +/- 0.35 8.00 +/- 0.29 Pass SC-571,572 3/8/2023 Ac-228 11.9+/-0.8 11.4+/-0.6 11.7+/-0.5 Pass SC-571.572 3/8/2023 Cr. Alpha 86.5 +/- 10.6 89.6 +/- 11.0 88.1 +/- 7.6 Pass DW-50052,50053 3/17/2023 Cr.Alpha 9.16+/-1.02 14.7+/-1.2 11.9+/-0.8 Pass DW-50052,50053 3/17/2023 Cr. Beta 6.03 +/- 0.71 7.58 +/- 0.75 6.81 +/- 0.52 Pass CF-700,701 3/22/2023 K-40 2.91 +/- 0.32 3.30 +/- 0.36 3.11 +/- 0.24 Pass SW-679,680 3/27/2023 H-3 14,480 +/- 389 14,487 +/- 389 14,484 +/- 275 Pass SC-974,975 4/4/2023 Cr. Alpha 12.0 +/- 2.1 12.1 +/- 2.1 12.1 +/- 1.5 Pass DW-50074,50075 4/21/2023 Ra-226 1.63 +/- 0.22 1.56 +/- 0.28 1.60 +/- 0.18 Pass DW-50074,50075 4/21/2023 Ra-228 3.41 +/- 0.98 2.14 +/- 0.80 2.78 +/- 0.63 Pass U-1038,1039 4/20/2023 Cr. Beta 6.14 +/- 1.71 6.46 +/- 2.19 6.30 +/- 1.39 Pass

\\MN-1 101,1 102 4/25/2023 H-3 358 +/- 96 334 +/- 95 346 +/- 68 Pass DW-50092,50093 5/1/2023 Ra-226 I.00 +/- 0.22 1.46 +/- 0.19 1.23 +/- 0.15 Pass DW-50092,50093 5/1/2023 Ra-228 1.11 +/- 0.73 1.57 +/- 0.82 1.34 +/- 0.55 Pass Am-1 122,1 123 5/2/2023 H-3 307 +/- 93 229 +/- 89 268 +/- 64 Pass VVVV-1269,1270 5/17/2023 H-3 366 +/- 100 214 +/- 92 290 +/- 68 Pass DW-50110,50111 5/29/2023 Ra-226 6.27+/-0.40 4.77+/-0.26 5.52+/-0.24 Pass DW-50110,50111 5/29/2023 Ra-228 2.81 +/- 0.97 3.53 +/- 0.98 3.17 +/- 0.69 Pass SW-1356,1357 5/30/2023 H-3 380 +/- 94 257 +/- 88 319 +/- 64 Pass WW-1398,1399 5/24/2023 H-3 571 +/- 103 613 +/- 105 592 +/- 74 Pass SC-1377,1378 5/30/2023 Pb-214 I.07 +/- 0.14 1.19 +/- 0.15 1.13 +/- 0.10 Pass SC-1377,J378 5/30/2023 Ac-228 1.23 +/- 0.28 1.11 +/- 0.23 1.17 +/- 0.18 Pass A-1O

TABLE A-5. Intralaboratory DupIicate Samples Concentrationa Averaged Lab Codeb Date Analysis First Result Second Result Result Acceptance DW-50124,50125 6/5/2023 Ra-226 0.25+/-0.08 0.24+/-0.09 0.25+/-0.06 Pass AP-060523NB 6/5/2023 Cr. Beta 0.023 +/- 0.003 0.0236 +/- 0.003 0.023 +/- 0.002 Pass DW-50126,50127 6/5/2023 Gr. Alpha 2.50 +/- 1.17 387 +/- 1 39 3.19 +/- 0.91 Pass WW-1441,1442 6/6/2023 Gr.Beta 2.55+/-0.64 1.91 +/-0.67 2.23+/-0.46 Pass SW-1483,1484 6/8/2023 H-3 281 +/-90 281 +/-90 281 +/-64 Pass CF-1546,1547 6/12/2023 K-40 7.77 +/- 034 7.48 +/- 048 7.63 +/- 0.29 Pass AP-061223NB 6/12/2023 Gr. Beta 0.031 +/- 0.005 0.030 +/- 0.005 0.031 +/- 0.004 Pass 5-1567,1568 6/14/2023 K-40 9.75 +/- 0.71 9.80 +/- 0.77 9.78 +/- 052 Pass WVV-1630,1631 6/6/2023 H-3 319 +/- 93 236 +/- 89 278 +/- 64 Pass F-1945,1946 6/26/2023 K-40 3.81 +/- 0.34 322 +/- 0.54 3.52 +/- 0.32 Pass DW-501 57,501 58 6/26/2023 Cr. Beta 0.93 +/- 0.59 1.09 +/- 0.06 1.01 +/- 0.30 Pass AP-062823NB 6/28/2023 Cr. Beta 0.026 +/- 0.004 0.021 +/- 0.003 0.024 +/- 0.003 Pass AP-070323NB 7/3/2023 Cr. Beta 0.028 +/- 0.003 0.026 +/- 0.003 0.027 +/- 0.002 Pass DW-50160,50161 7/5/2023 Ra-226 2.63 +/- 0.32 2.77 +/- 0.27 2.70 +/- 0.21 Pass DW-50160,50161 7/5/2023 Ra-228 2.46 +/- 0.78 2.51 +/- 0.81 2.49 +/- 0.56 Pass AP-07J 123NB 7/1 1/2023 Cr. Beta 0.025 +/- 0.003 0.027 +/- 0.003 0.026 +/- 0.002 Pass DW-50188,50189 7/21/2023 Ra-226 3.07 +/- 0.30 2.63 +/- 0.20 2.85 +/- 0.18 Pass DW-50J88,50189 7/21/2023 Ra-228 5.28 +/- 0.92 5.08 +/- 0.90 5.18 +/- 0.64 Pass DW-50197,50198 7/24/2023 Cr.Alpha 5.82+/-1.50 5.78+/-1.30 5.80+/-0.99 Pass DW-50200,50201 7/24/2023 Ra-226 2.51 +/- 0.24 4.07 +/- 0.29 3.29 +/- 0.19 Pass DW-50200,50201 7/24/2023 Ra-228 7.04 +/- 1.13 6.55 +/- 1.09 6.80 +/- 0.79 Pass SC-2199,2200 7/25/2023 Pb-214 1.18 +/- 0.22 1.03 +/- 0.19 1.11 +/- 0.15 Pass SC-21 99,2200 7/25/2023 Ac-228 I.74 +/- 0.32 1.86 +/- 0.42 1.80 +/- 0.26 Pass AP-072623NB 7/26/2023 Cr. Beta 0.021 +/- 0.003 0.021 +/- 0.003 0.021 +/- 0.002 Pass AP-080223NB 8/2/2023 Cr. Beta 0.015 +/- 0.003 0.016 +/- 0.003 0.016 +/- 0.002 Pass SC-2315,2316 8/3/2023 Cr. Alpha 59.5 +/- 6.7 48.2 +/- 6.1 53.9 +/- 4.5 Pass SC-2315,2316 8/3/2023 Cr. Beta 39.8 +/- 2.9 34.4 +/- 2.6 37.1 +/- 1.9 Pass AP-080723NB 8/7/2023 Cr. Beta 0.025 +/- 0.005 0.025 +/- 0.005 0.025 +/- 0.004 Pass DW-50200,50201 8/9/2023 Ra-228 I.88 +/- 0.71 1.29 +/- 0.70 1.59 +/- 0.50 Pass AP-081423NB 8/14/2023 Cr. Beta 0.030 +/- 0.003 0.028 +/- 0.003 0.029 +/- 0.002 Pass AP-082123NB 8/21/2023 Cr. Beta 0.020 +/- 0.003 0.022 +/- 0.003 0.021 +/- 0.002 Pass DW-50262,50263 8/24/2023 Ra-228 2.62 +/- 0.87 1.46 +/- 0.52 2.04 +/- 0.51 Pass DW-50262,50263 8/24/2023 Ra-228 2.62 +/- 0.87 2.80 +/- 0.67 2.71 +/- 0.55 Pass AP-082823NB 8/28/2023 Cr. Beta 0.023 +/- 0.003 0.028 +/- 0.003 0.026 +/- 0.002 Pass DW-50268,50269 8/29/2023 Cr. Alpha 0.87 +/- 0.69 0.97 +/- 0.81 0.92 +/- 0.53 Pass SC-2660,2661 9/4/2023 Cr. Alpha 68.5 +/- 7.1 51.0 +/- 6.3 59.8 +/- 4.7 Pass SC-2660,2661 9/4/2023 Pb-214 13.7 +/- 0.5 14.2 +/- 0.5 14.0 +/- 0.4 Pass SC-2660,2661 9/4/2023 Ac-228 14.4 +/- 0.8 14.3 +/- 0.9 14.4 +/- 0.6 Pass AP-090523NB 9/5/2023 Cr. Beta 0.023 +/- 0.003 0.023 +/- 0.003 0.023 +/- 0.002 Pass AP-091223NB 9/12/2023 Cr. Beta 0.024 +/- 0.002 0.025 +/- 0.002 0.025 +/- 0.001 Pass A-il

TABLE A-5. Intralaboratory Duplicate Samples Concentrationa Averaged Lab Codeb Date Analysis First Result Second Result Result Acceptance W-2776,2777 9/18/2023 Gr. Alpha 1.86 +/- 1.73 0.99 +/- 1.64 1.43 +/- 119 Pass W-2776,2777 9/18/2023 Ra-226 0.43 +/- 0.10 0.55 +/- 0.27 0.49 +/- 0.14 Pass W-2776,2777 9/18/2023 Ra-228 171 +/- 1.07 3.33 +/- 1.12 252 +/- 0.77 Pass AP-092023NB 9/20/2023 Gr. Beta 0.039 +/- 0.004 0.042 +/- 0.004 0.041 +/- 0.003 Pass DW-50296,50297 9/27/2023 Ra-226 0.51 +/- 0.09 0.54 +/- 0.20 0.53 +/- 0.1 1 Pass AP-092823NB 9/28/2023 Gr. Beta 0.030 +/- 0.004 0.034 +/- 0.004 0.032 +/- 0.003 Pass 5-3136,3137 10/11/2023 Pb-214 193+/-0.06 1.84+/-0.08 1.89+/-0.05 Pass 5-3135,3136 10/11/2023 Ac-228 4.06+/-0.17 3.84+/-0.19 3.95+/-0.13 Pass SG-3511,3512 10/10/2023 GrAlpha 59.0 +/-6.2 68.5 +/-6.6 63.8 +/-4.5 Pass SG-3511,3512 10/10/2023 Gr. Beta 52.1 +/-2.9 54.6 +/-3.0 53.4 +/-2.1 Pass SG-3511,3512 10/10/2023 Pb-214 967 +/- 0.25 9.57 +/- 0.29 9.62 +/- 0.19 Pass SG-3511,3512 10/10/2023 Ac-228 8.99 +/- 0.43 8.79 +/- 0.53 8.89 +/- 0.34 Pass SG-3521,3522 11/8/2023 Gr. Alpha 57.3 +/- 7.3 70.9 +/- 7.6 64.1 +/- 5.3 Pass SG-3521,3522 11/8/2023 Pb-214 11.2+/-0.2 11.7+/-0.2 11.5+/-0.1 Pass SG-3521,3522 11/8/2023 Ac-228 13.0 +/- 0.4 13.4 +/- 0.5 13.2 +/- 0.3 Pass DW-50335,50336 I I/l 7/2023 Gr. Alpha 3.70 +/- I.00 3.46 +/- 0.90 3.58 +/- 0.67 Pass DW-50335,50336 11/17/2023 Gr. Beta 1.73 +/- 0.63 2.07 +/- 0.06 190 +/- 0.32 Pass W-3647,3648 11/20/2023 H-3 2,815 +/- 181 2,829 +/- 182 2,822 +/- 128 Pass DW-50358,50359 12/4/2023 Gr. Beta 2.53 +/- 0.61 1.66 +/- 0.62 2.10 +/- 0.43 Pass DW-50349,50350 12/4/2023 Ra-226 0.04 +/- 0.1 1 0.32 +/- 0.10 0.18 +/- 0.07 Pass DW-50349,50350 12/4/2023 Ra-228 1.37 +/- 0.48 1.57 +/- 0.47 1.47 +/- 0.34 Pass DW-50365,50366 12/1 1/2023 Gr. Alpha I.4 +/- 0.79 1.95 +/- 091 1.675 +/- 0.60 Pass DW-50365,50366 12/1 1/2023 Gr. Beta 3.18 +/- 062 3.18 +/- 0.66 3.18 +/- 0.45 Pass DW-50374,50375 12/13/2023 Gr. Alpha 0.89 +/- 0.60 0.54 +/- 0.67 0.715 +/- 0.45 Pass W-4035.4036 12/31/2023 H-3 157,638 +/- I 218 159,848 +/- I 227 158,743 +/- 864 Pass W-4035.4036 12/31/2023 Ni-63 2,410 +/- 78 2,337 +/- 78 2,373 +/- 55 Pass W-4035.4036 12/31/2023 Sr-90 49.8 +/- 5.2 42.7 +/- 4.8 46.3 +/- 3.5 Pass A-12

TABLE A-6. Department of Energys Mixed Analyte Performance Evaluation Program (MAPEP).

Concentrationa Reference Known Acceptance Lab Code b Date Analysis Laboratory result Activity Range C

Acceptance MAAP-544 2/1/2023 Gross Alpha I.23 +/- 0. 1 0 0.97 0.29

- 1.65 Pass MAAP-544 2/1/2023 Gross Beta 1.67 +/- 0.06 1.49 0.75

- 2.24 Pass MADW-543 2/1/2023 Gross Alpha 0.843 +/- 0.074 1.19 0.36

- 2.02 Pass MADW-543 2/1/2023 Gross Beta 0.578 +/- 0.093 5.94 2.97

- 8.91 Fail MASO-540 2/1/2023 Cs-134 2.33 +/- 2.77 0

NA C

Pass MASO-540 2/1/2023 Cs-137 I.22 +/- 2.41 0

NA C

Pass MASO-540 2/1/2023 Co-57 585 +/- 4 698 489

- 907 Pass MASO-540 2/1/2023 Co-60 727 +/- 8 795 557

- 1034 Pass MASO-540 2/1/2023 Mn-54 1 180 +/- 1 0 1230 861

- 1599 Pass MASO-540 2/1/2023 Zn-65 846 +/- I 1 990 693

- I 287 Pass MASO-540 2/1/2023 K-40 526 +/- 23 574 402

- 746 Pass MADW-545 2/1/2023 Cs-134 9.17 +/- 0.17 9.6 6.7

- 12.5 Pass MADW-545 2/1/2023 Cs-137 9.38 +/- 0.29 8.7 6.1

- 11.3 Pass MADW-545 2/1/2023 Co-57

-0.01 +/- 0.08 0.0 NA C

Pass MADW-545 2/1/2023 Co-60 7.47 +/- 0.18 7.24 5.07

- 9.41 Pass MADW-545 2/1/2023 Mn-54 12.3 +/- 0.3 1 1.3 7.9

- 14.7 Pass MADW-545 2/1/2023 Zn-65 15.7 +/- 0.5 15.3 10.7

- 19.9 Pass MADW-545 2/1/2023 K-40 I.23 +/- 1.52 0

NA Pass MADW-545 2/1/2023 Sr-90

-0.0035 +/- 0.0172 0

NA C

Pass MAAP-538 2/1/2023 Cs-134 I.12 +/- 0.04 1.52 1.06

- I.98 Pass MAAP-538 2/1/2023 Cs-137 0.56 +/- 0.07 0.630 0.441

- 0.819 Pass MAAP-538 2/1/2023 Co-57 0.62 +/- 0.30 0.661 0.463

- 0.859 Pass MAAP-538 2/1/2023 Co-60 0.89 +/- 0.07 1.05 0.74

- 1.37 Pass MAAP-538 2/1/2023 Mn-54 2.02 +/- 0.09 2.14 1.50

- 2.78 Pass MAAP-538 2/1 /2023 Zn-65

2. 1 3 +/- 0. 1 4 2.25 1.58

- 2.93 Pass MAAP-538 2/1/2023 Sr-90 0.004 +/- 0.061 0

NA C

Pass MASO-540 2/1/2023 Cs-134 2.33 +/- 2.77 0

NA C

Pass MASO-540 2/1/2023 Cs-137 I.22 +/- 2.41 0

NA C

Pass MASO-540 2/1/2023 Co-57 585 +/- 4 698 489

- 907 Pass MASO-540 2/1/2023 Co-60 727 +/- 8 795 557

- I 034 Pass MASO-540 2/1/2023 Mn-54 I I 80 +/- I 0 1 230 861

- I 599 Pass MASO-540 2/1/2023 Zn-65 846 +/- I I 990 693

- 1287 Pass MASO-540 2/1/2023 K-40 526 +/- 23 574 402

- 746 Pass A-13

TABLE A-6. Department of Energys Mixed Analyte Performance Evaluation Program (MAPEP).

Concentrationa Reference Known Acceptance Lab Code b Date Analysis Laboratory result Activity Range C

Acceptance MADW-2753 8/1/2023 MADW-2753 8/1/2023 GrossAlpha 1.20 +/- 0.06 Gross Beta 14.7 +/- 0.1 9.17 +/- 0.17 9.38 +/- 0.29

-0.01 +/- 0.08 7.47 +/- 0.18 12.3 +/-0.3 15.7 +/-0.5 1.23 +/- 1.52

-0.0035 +/- 0.0172 9.6 8.7 0.0 7.24 11.3 15.3 0

0 MADW-545 MADW-545 MADW-545 MADW-545 MADW-545 MADW-545 MADW-545 MADW-545 MAAP-538 MAAP-538 MAAP-538 MAAP-538 MAAP-538 MAAP-538 MAAP-538 MAVE-545 MAVE-545 MAVE-545 MAVE-545 MAVE-545 MAVE-545 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 2/1/2023 Cs-i 34 Cs-i 37 Co-57 Co-60 Mn-54 Zn-65 K-40 Sr-90 Cs-I 34 Cs-137 Co-57 Co-60 Mn-54 Zn-65 Sr-90 Cs-i 34 Cs-i 37 Co-57 Co-60 Mn-54 Zn-65 1.12+/-0.04 1.52 0.56 +/-0.07 0.630 0.62 +/- 0.30 0.661 0.89 +/-0.07 1.05 2.02+/-0.09 2.14 2.13+/-0.14 2.25 0.004+/-0.061 0

7.45 +/- 0.39 7.60 0.010 +/-0.084 0

6.83+/-0.17 6.93 6.89 +/- 0.17 6.51 9.08 +/- 0.28 8.03 7.83 +/- 0.39 7.43 6.7

- 12.5 6.1 -11.3 NA C

5.07

- 9.41 7.9

- 14.7 10.7

- 19.9 NA C

NA C

1.06

- 1.98 0.441 -0.819 0.463

- 0.859 0.74

- 1.37 1.50 -2.78 1.58 -2.93 NA C

5.32

- 9.88 NA C

4.85

- 9.01 4.56 -8.46 5.62

- 10.44 5.20

- 9.66 0.077

- 0.434 0.464

- 1.391 0.48 -2.70 8.14 -24.41 485 -901 1267 -2353 742

- 1378 629

- 1167 NA C

812

- 1508 402

- 746 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass MAAP-276i 8/1/2023 Gross Alpha 0.16 +/- 0.04 MAAP-276i 8/1/2023 Gross Beta I.16 +/- 0.07 MASO-2757 8/i /2023 MASO-2757 8/i /2023 MASO-2757 8/1/2023 MASO-2757 8/i /2023 MASO-2757 8/i /2023 MASO-2757 8/i /2023 MASO-2757 8/i /2023 Cs-i 34 Cs-i37 Co-57 Co-60 Mn-54 Zn-65 K-40 0.255 0.927 1.59 16.27 693 1810 1060 898 0

1160 574 612+/-8 1900 +/-20 1020 +/-20 901 +/-10 6.53 +/- 3.22 1270 +/-30 702 +/- 54 A-14

TABLE A-6. Department of Energys Mixed Analyte Performance Evaluation Program (MAPEP).

Concentrationa Reference Known Acceptance Lab Code b Date Analysis Laboratory result Activity Range C

Acceptance MADW-2751 8/1/2023 Cs-134 8.88 +/- 0.18 1 1.3 7.9

- 14.7 Pass MADW-2751 8/1/2023 Cs-137 7.95 +/- 0.30 8.7 6.1

- 11.3 Pass MADW-2751 8/1/2023 Co-57 16.5 +/- 0.3 19.3 13.5

- 25.1 Pass MADW-2751 8/1/2023 Co-60 0.09 +/- 0.06 0

NA C

Pass MADW-2751 8/1/2023 Mn-54 I I.6 +/- 0.3 12.7 8.9

- 16.5 Pass MADW-2751 8/1/2023 Zn-65 17.9 +/- 0.6 19.1 13.4

- 24.8 Pass MADW-2751 8/1/2023 K-40 1.56 +/- 1.60 0

NA C

Pass MAAP-2755 8/1/2023 Cs-134 1.30 +/- 0.10 1.60 1.12

- 2.08 Pass MAAP-2755 8/1/2023 Cs-137 0.04 +/- 0.03 0

NA C

Pass MAAP-2755 8/1/2023 Co-57 1.47 +/- 0.05 1.63 1.14

- 2.12 Pass MAAP-2755 8/1/2023 Co-60 0.04 +/- 0.09 0

NA C

Pass MAAP-2755 8/1/2023 Mn-54 1.59 +/- 0.09 1.57 1.10

- 2.04 Pass MAAP-2755 8/1/2023 Zn-65 1.71 +/- 0.14 1.89 1.32

- 2.46 Pass MAAP-2755 8/1/2023 Sr-90 0.533 +/- 0.040 0.614 0.430

- 0.796 Pass MAVE-2759 8/1/2023 Cs-134 4.25 +/- 0.14 4.96 3.49

- 6.47 Pass MAVE-2759 8/1/2023 Cs-137 0.025 +/- 0.050 0

NA C

Pass MAVE-2759 8/1/2023 Co-57 4.28 +/- 0.13 4.24 2.97

- 5.51 Pass MAVE-2759 8/1/2023 Co-60 2.49 +/- 0.11 2.79 1.95

- 3.63 Pass MAVE-2759 8/1/2023 Mn-54 2.45 +/- 0.16 2.6 1.8

- 3.3 Pass MAVE-2759 8/1/2023 Zn-65 0.058

- 0.107 0

NA Pass a Results are reported in units of Sq/kg (soil), Bq/L (water) or Sq/total sample (filters, vegetation).

b Laboratory codes as follows: MAW (water), MADW (water), MAAP (air filter), MASO (soil) and MAVE (vegetation).

C MAPEP results are presented as the known values and expected laboratory precision (1 sigma, I determination) and control limits as defined by the MAPEP. A known value of zero indicates an analysis was included in the testing series as a false positive. MAPEP does not provide an acceptance range.

d A decimal point was misplaced in a unit conversion. If the conversion was was done properly the result: 5.78 +/- 0.93 Bq/L woud have been within MAPEPs acceptance range.

A45

TABLE A-7. Interlaboratory Comparison Crosscheck Program, Environmental Resource Associates (ERA)a.

MRAD-38 Study Concentration a Lab Code b Date Analysis Laboratory ERA Acceptance Result Value Limits Acceptance ERAP-599 3/20/2023 Cs-134 139 153 99

- 188 Pass ERAP-599 3/20/2023 Cs-i 37 970 892 733

- I I 70 Pass ERAP-599 3/20/2023 Co-60 474 467 397

- 593 Pass ERAP-599 3/20/2023 Mn-54

< 3.3

< 35.0 0.00

- 35.0 Pass ERAP-599 3/20/2023 Zn-65 I 280 1 1 1 0 91 0

- I 700 Pass ERAP-599 3/20/2023 Sr-90 143 137 87

- 187 Pass ERAP-598 3/20/2023 Gross Alpha 72.7 76.8 40.1

- 127 Pass ERAP-598 3/20/2023 Gross Beta 35.0 32.8 19.9

- 49.6 Pass a Results obtained by Microbac Laboratories

- Northbrook as a participant in the crosscheck program for proficiency testing administered by Environmental Resource Associates, serving as a replacement for studies conducted previously by the Environmental Measurements Laboratory Quality Assessment Program (EML).

b Laboratory code ERAP (air filter). Results are reported in units of (pCi/Filter).

C The ERA Assigned values for the air filter standards are equal to I 00% ofthe parameter present in the standard as determined by the gravimetric and/or volumetric measurements made during standard preparation as applicable.

d The acceptance limits are established per the guidelines contained in the Department of Energy (DOE) report EML-564, Analysis of Environmental Measurements Laboratory (EML) Quality Assessment Program (QAP)

Data Determination of Operational Criteria and Control Limits for Performance Evaluation Purposes or ERAs SOP for the generation of Performance Acceptance Limits.

A-16

(MICROBAC 700 Landwehr Road

  • Northbrook, IL 60062-2310 phone (847) 564-0700
  • fax (847) 564-4517 Appendix B Data Reporting Conventions

APPENDIX B.

DATA REPORTING CONVENTIONS Data Reporting Conventions I.0. All activities, except gross alpha and gross beta, are decay corrected to collection time or the end olthe collection period.

2.0.

Single Measurements Each single measurement is reported as follows:

x +/- s where:

x = value ofthe measurement; 5 = 2a counting uncertainty (corresponding to the 95% confidence level).

In cases where the activity is less than the lower limit of detection L, it is reported as:

< L, where L = the lower limit of detection based on 4.66a uncertainty for a background sample.

3.0. Duplicate analyses If duplicate analyses are reported, the convention is as follows.

3. 1 Individual results:

For two analysis results; x1 +/- s and x2 +/- 2 Reported result:

x +/- s; where x = (1/2) (x1 + x2) and s = (1/2) -Js +

3.2.

Individual results:

< L1

< L2 Rerorted result: < L, where L = lower of L1 and L2 3.3.

Individual results:

x +/- s, < L Reported result:

x +/- s if x L; < L otherwise.

4.0. Computation ofAverages and Standard Deviations 4.1 Averages and standard deviations listed in the tables are computed from all of the individual measurements over the period averaged; for example, an annual standard deviation would not be the average of quarterly standard deviations. The average x and standard deviation s of a set of n numbers x1, x2

. x are defined as follows:

x=Zx 5=

4.2 Values below the highest lower limit of detection are not included in the average.

4.3 If all values in the averaging group are less than the highest LLD, the highest LLD is reported.

4.4 If all but one of the values are less than the highest LLD, the single value x and associated two sigma error is reported.

4.5 In rounding off, the following rules are followed:

4.5.1.

If the number following those to be retained is less than 5, the number is dropped, and the retained numbers are kept unchanged. As an example, 11.443 is rounded oftto 11.44.

4.5.2.

If the number following those to be retained is equal to or greater than 5, the number is dropped and the last retained number is raised by 1

. As an example, 1 1.445 is rounded off to I I.45.

B-I

Appendix C. NON-RADIOLOGICAL MONITORING PROGRAM 1.0. Introduction Union Electric Company Callaway Plant, d.b.a. Ameren Missouri Callaway Energy Center, in accordance with federal regulations and a desire to maintain the quality of the local environment around Callaway Plant has implemented an Environmental Protection Plan, (EPP) contained in Appendix B of the Callaway Plant Operating License.

The objective of the EPP is to provide for protection of non-radiological environmental values during operation of the Callaway Plant.

This report describes the conduct of the EPP for the Callaway Plant during 2023.

2.0. Unusual or Important Events No unusual or important events reportable under the EPP Section 4.1 were identified during 2023.

3.0. EPP Non-compliances During 2023, there was zero non-compliance with the EPP.

4.0. Nonroutine Reports There were no nonroutine reports submitted in accordance with the EPP, Section 5.4.2 in 2023.

5.0. Plant Design and Operation Environmental Evaluations.

This section lists all changes in the plant design, operation, tests or experiments installed during 2023, which could have involved a potentially significant unreviewed environmental question in accordance with section 3.1 ofAppendix B.

During 2023, no major plant changes were completed that could have involved a potentially significant unreviewed environmental question.

c-I

APPENDIX D Sampling Location Maps D-1

Figure Dl. Radiological Environmental Sampling Locations 1, 2, 3, mile radius from site location.

mapping:

I D-2

Figure D-2. Radiological Environmental Sampling Locations 3, 4, 5, 6 mile radius from site location.

,9A (5 miles)

I

- *..___ii) 20 44.7 miles) \\\\

I I

I

,\\

61N (1.9 miles)

\\

1 40 (4.2 miles) 61(4TW 7jIrniles)

\\

18A (3.7 miles)

I 41 (4.9 miLes) 62N (1.2 miles),,7J/,4),,7,71

\\

j I

(1 miles)

/

5.4ils)

\\

I

(1.64 miles,J___J

)

L (3.8 miles)

\\

I

\\

\\

F05 (0.9 miles)

I

\\

1 S

I

/

-çç).%//-

,1 32 (6.4 miles)

\\

q S

. 14 (4.9 miles 32A(5miles)

S D

S

_5S V19 (3.28 miles) 42 (4.4 miles)

V19\\3.22 miles) hA (4.7 miles)

SSS%ss555 S

(3.4 miles)

D 72 S02 4.9 miles)

\\

30A (4AThil D

9 (3 miles)

AQF-C (4.9,miles)

  • 55

S 9

AQS.C,(4.9 miles)

-S S S5 I

Mokane N

0 0.5 1 A 4/

Radiological EnvIronmental Sampling LocatIons 3,4,5,6 mile radius from Site location WAmeren Callaway MISSOURI Energy Center Drinking Well Water Non-Potable Groundwater Wells

. Fish and Sediment 0

Soil

. Farm Crops 0

Surface Water (Ponds) 0 Food Products-Leafy Green Vegetables 0

Surface Water (River)

D-3

Figure D-3. Radiological Environmental Sampling Locations 5, 10, 15 mile radius from site location.

D-4

Figure D-4. Non-Potable Groundwater Monitoring Wells, 600 ft radius from Site.

D-5

Figure D-5. Non-Potable Groundwater Monitoring Wells Collection.

Radiological Environmental Sampling Locations Non-Potable Groundwater Wells Collection Discharge Pipeline D-6

(MtCROBACR 700 Landwehr Road

  • Northbrook, IL 60062-2310 phone (847) 564-0700

, 2023 Prepared by Microbac Laboratories

- Northbrook Submitted by Union Electric Co.

dba Ameren Missouri Project No. 8036

TABLE OF CONTENTS Section ListofTables iii 1.0 Introduction iv 2.0 DataTables v

LIST OF TABLES No.

Title Page I

Airborne particulates and charcoal cartridges, analysis for gamma-emitting isotopes, and iodine-131 1-1 2

Milk, analysis for iodine-131 and gamma emitting isotopes.

2-1 3

Vegetation, analysis for iodine-131 and gamma emitting isotopes.

3-1 4

Soil, analysis for gamma-emitting isotopes.

4-1 5

Surface water, analysis for tritium and gamma-emitting isotopes.

5-1 6

Surface water (Ponds), analysis for tritium and gamma-emitting isotopes 6-1 7

Drinking water, analysis for tritium and gamma-emitting isotopes.

7-1 8

Wells (non-potable water), analysis for tritium and gamma-emitting isotopes.

8-1 8a Wells (non-potable water), analyses for hard-to-detect isotopes 8-9 9.

Shoreline sediment, analysis for gamma-emitting isotopes.

9-1 I 0 Fish, analysis for gamma-emitting isotopes.

I 0-1 I 1 Direct Radiation ha.

Gamma dose 11-1 lIb.

Neutrondose 11-2

1.0 INTRODUCTION

The following constitutes a supplement to the Annual Report for the Radiological Environmental Monitoring Program conducted at the Ameren Missouri, Callaway Energy Center, Fulton, Missouri in 2023. Results of completed analyses are presented in the attached tables.

For information regarding sampling locations, type and frequency of collection, and sample codes, referto Part I, Tables 5.1

- 5.2 and the figures in Appendix D.

Analyses results from additional sampling may be found in Appendix A.

iv

2.0 DATA TABLES V

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emifting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-OO1 7Be 58Co 60Co 95Zr Cs 137Cs 140BaLa 44Ce Required LLDs 0.050 0.060 Date Collected Vol.

01-05-23 277

< 0.14

< 0.012

< 0.003

< 0.023

< 0.009

< 0.004

< 0.040

< 0.048 01-12-23 282

< 0.11

<0.008

<0.008

<0.019

<0.007

<0.008

<0.045

<0.039 01-19-23 282

< 0.08

<0.011

<0.007

<0.020

<0.005

<0.008

<0.035

<0.047 01-26-23 262

< 0.08

< 0.003

< 0.004

< 0.016

< 0.010

< 0.007

< 0.060

< 0.039 02-02-23 260

< 0.11

<0.009

<0.007

<0.014

<0.011

<0.007

<0.030

<0.056 02-09-23 265 0.17

+/- 0.09

<0.006

<0.006

<0.011

<0.009

<0.009

<0.014

<0.049 02-16-23 261 0.15

+/- 0.06

< 0.009

< 0.019

< 0.015

< 0.010

< 0.014

< 0.018

< 0.052 02-23-23 255 0.17

+/- 0.09

< 0.007

< 0.009

< 0.015

< 0.009

< 0.008

< 0.016

< 0.037 03-02-23 258

< 0.07

<0.008

<0.009

<0.013

<0.011

<0.007

<0.009

<0.038 03-09-23 258

< 0.16

< 0.007

< 0.022

< 0.036

< 0.01 1

< 0.018

< 0.132

< 0.073 03-16-23 256

< 0.06

< 0.006

< 0.005

< 0.01 1

< 0.004

< 0.003

< 0.047

< 0.020 03-23-23 260

<0.17

<0.019

<0.013

<0.025

<0.015

<0.011

<0.054

<0.051 03-30-23 258

< 0.11

<0.011

<0.019

<0.020

<0.011

<0.016

<0.033

<0.057 04-06-23 257

<0.17

<0.011

<0.010

<0.022

<0.012

<0.011

<0.018

<0.048 04-13-23 262

< 0.16

< 0.008

< 0.014

< 0.027

< 0.015

< 0.015

< 0.033

< 0.069 04-20-23 259 0.24

+/- 0.12

< 0.007

< 0.022

< 0.018

< 0.012

< 0.018

< 0.015

< 0.053 04-27-23 267 0.19

+/- 0.10

<0.012

<0.007

<0.020

<0.011

<0.004

<0.007

<0.051 05-04-23 262 0.23

+/- 0.09

< 0.005

< 0.018

< 0.016

< 0.008

< 0.016

< 0.013

< 0.053 05-11-23 260 0.19

+/- 0.09

<0.005

<0.005

<0.011

<0.007

<0.008

<0.012

<0.042 05-18-23 260 0.24

+/- 0.09

< 0.009

< 0.015

< 0.012

< 0.007

< 0.012

< 0.017

< 0.038 05-25-23 262 0.17

+/- 0.09

< 0.009

< 0.008

< 0.015

< 0.007

< 0.006

< 0.027

< 0.037 06-01-23 264 0.18

+/- 0.10

< 0.008

< 0.009

< 0.017

< 0.009

< 0.009

< 0.013

< 0.036 06-08-23 267 0.35

+/- 0.13

< 0.010

< 0.009

< 0.022

< 0.010

< 0.007

< 0.047

< 0.041 06-15-23 259 0.21

+/- 0.12

< 0.006

< 0.003

< 0.018

< 0.008

< 0.004

< 0.018

< 0.039 06-22-23 271 0.18

+/- 0.09

<0.008

<0.011

<0.019

<0.007

<0.005

<0.014

<0.035 06-29-23 271 0.22

+/- 0.10

< 0.007

< 0.008

< 0.017

< 0.005

< 0.007

< 0.045

< 0.039 a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

11

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emifting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-AOO1 (cont.)

7Be 58Co 60Co 95Zr 134Cs 137Cs 40BaLa 1Ce Required LLDs 0.050 0.060 Date Collected Vol.

07-06-23 266

< 0.10

<0.010 07-13-23 270

< 0.12

<0.010 07-20-23 265

< 0.10

< 0.006 07-27-23 269 0.26

+/- 0.14

< 0.008 08-03-23 270

< 0.10

<0.010 08-10-23 262

<0.12

<0.006 08-17-23 269

<0.10

<0.006 08-24-23 269 0.14

+/- 0.08

< 0.008 08-31-23 266

< 0.08

< 0.008 09-07-23 272

< 0.09

< 0.009 09-14-23 274

< 0.08

< 0.009 09-21-23 275 0.19 +/-0.10

<0.008 09-28-23 273

< 0.07

< 0.008 10-05-23 275 0.18 +/- 0.08

< 0.005 10-12-23 281

< 0.06

< 0.009 10-19-23 278 0.15 +/-0.07

<0.006 10-26-23 280 0.13

+/- 0.07

< 0.008 1 1-02-23 275

< 0.07

< 0.006 11-08-23 324 0.19

+/- 0.10

<0.004 11-16-23 312 0.13 +/-0.07

<0.005 11-22-23 232

< 0.08

<0.007 11-30-23 314 0.14 +/-0.06

<0.007 12-07-23 271

< 0.07

< 0.009 12-14-23 273

< 0.06

< 0.008 12-20-23 239

< 0.09

< 0.009 12-28-23 307 0.19

+/- 0.08

< 0.008 a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

<0.005

<0.024

<0.009

<0.007

<0.137

<0.045

< 0.008

< 0.017

< 0.008

< 0.008

< 0.068

< 0.039

< 0.005

< 0.022

< 0.01 1

< 0.005

< 0.049

< 0.042

< 0.019

< 0.018

< 0.010

<0.013

< 0.055

< 0.029

< 0.005

< 0.022

< 0.01 1

< 0.008

< 0.050

< 0.040

<0.009

<0.016

<0.010

<0.007

<0.022

<0.041

< 0.009

< 0.017

< 0.009

< 0.008

< 0.046

< 0.041

< 0.005

< 0.015

< 0.007

< 0.006

< 0.019

< 0.039

<0.004

<0.015

<0.011

<0.008

<0.033

<0.039

< 0.009

< 0.017

< 0.009

< 0.009

< 0.038

< 0.037

<0.006

<0.012

<0.010

<0.006

<0.023

<0.041

<0.011

<0.013

<0.008

<0.006

<0.020

<0.038

<0.012

<0.015

<0.011

<0.006

<0.011

<0.034

<0.015

<0.012

<0.007

<0.012

<0.030

<0.027

<0.007

<0.013

<0.007

<0.006

<0.031

<0.038

<0.008

<0.015

<0.011

<0.007

<0.029

<0.035

< 0.009

< 0.016

< 0.010

< 0.006

< 0.012

< 0.037

< 0.009

< 0.013

< 0.010

< 0.004

< 0.014

< 0.033

< 0.004

< 0.008

< 0.009

< 0.006

< 0.006

< 0.027

< 0.003

< 0.013

< 0.009

< 0.005

< 0.027

< 0.031

< 0.009

< 0.018

< 0.012

< 0.005

< 0.035

< 0.049

< 0.006

< 0.013

< 0.007

< 0.005

< 0.020

< 0.032

< 0.008

< 0.016

< 0.008

< 0.007

< 0.039

< 0.025

< 0.006

< 0.020

< 0.012

< 0.007

< 0.016

< 0.034

< 0.004

< 0.009

< 0.012

< 0.007

< 0.060

< 0.043

< 0.009

< 0.01 1

< 0.009

< 0.006

< 0.058

< 0.033 I -2

Table I. Air particulates and charcoal cartridges, analyses for gamma-emitting isotopes and -131 a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-007 7Be 58Co 60Co 95Zr 1Cs 137Cs 140BaLa 144Ce Required LLDs 0.050 0.060 Date Collected Vol.

01-05-23 240

< 0.14

< 0.009 01-12-23 244

< 0.14

< 0.007 01-19-23 240

< 0.11

< 0.007 01-26-23 244

< 0.10

< 0.009 02-02-23 243

< 0.15

< 0.006 02-09-23 243 0.18

+/- 0.07

< 0.015 02-16-23 240

< 0.12

< 0.007 02-23-23 232

< 0.09

< 0.008 03-01-23 234

< 0.13

< 0.010 03-09-23 232

< 0.19

< 0.021 03-16-23 230 0.09

+/- 0.04

< 0.006 03-23-23 270

< 0.10

< 0.010 03-30-23 267

< 0.15

< 0.007 04-06-23 262

< 0.13

< 0.010 04-13-23 268

< 0.14

< 0.014 04-20-23 269 0.17

+/- 0.05

< 0.003 04-27-23 273 0.18

+/- 0.10

< 0.006 05-04-23 267 0.25

+/- 0.11

< 0.010 05-11-23 271

< 0.04

<0.007 05-18-23 264 0.19

+/- 0.09

< 0.007 05-25-23 265 0.21

+/- 0.11

< 0.006 06-01-23 241 0.16 +/-0.08

<0.011 06-08-23 267 0.27

+/- 0.1 1

< 0.011 06-15-23 241 0.17

+/- 0.10

< 0.010 06-22-23 241 0.17

+/- 0.09

< 0.006 06-29-23 237 0.20

+/- 0.12

< 0.008 a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

< 0.010

< 0.027

< 0.012

< 0.006

< 0.067

< 0.055

< 0.012

< 0.014

< 0.010

< 0.011

< 0.045

< 0.058

< 0.005

< 0.023

< 0.012

< 0.006

< 0.083

< 0.044

< 0.020

< 0.023

< 0.009

< 0.017

< 0.057

< 0.039

< 0.009

< 0.012

< 0.012

< 0.010

< 0.040

< 0.072

< 0.01 1

< 0.01 1

< 0.01 1

< 0.009

< 0.038

< 0.057

< 0.007

< 0.017

< 0.010

< 0.010

< 0.016

< 0.057

< 0.010

< 0.019

< 0.012

< 0.010

< 0.031

< 0.046

<0.006

<0.017

<0.009

<0.011

<0.014

<0.042

< 0.014

< 0.036

< 0.015

< 0.013

< 0.156

< 0.069

< 0.005

< 0.010

< 0.005

< 0.003

< 0.044

< 0.023

<0.012

<0.019

<0.010

<0.011

<0.075

<0.051

< 0.007

< 0.020

< 0.012

< 0.006

< 0.025

< 0.047

< 0.020

< 0.014

< 0.011

< 0.016

< 0.042

< 0.062

< 0.022

< 0.027

< 0.012

< 0.019

< 0.032

< 0.047

<0.004

<0.007

<0.004

<0.003

<0.003

<0.020

< 0.009

< 0.020

< 0.012

< 0.007

< 0.009

< 0.038

< 0.007

< 0.010

< 0.010

< 0.007

< 0.025

< 0.039

< 0.017

< 0.015

< 0.007

< 0.013

< 0.017

< 0.042

<0.005

<0.014

<0.008

<0.005

<0.011

<0.026

< 0.005

< 0.012

< 0.006

< 0.008

< 0.027

< 0.040

< 0.009

< 0.020

< 0.006

< 0.006

< 0.015

< 0.045

< 0.009

< 0.019

< 0.011

< 0.006

< 0.030

< 0.044

<0.008

<0.015

<0.006

<0.009

<0.041

<0.044

< 0.004

< 0.021

< 0.010

< 0.007

< 0.019

< 0.035

< 0.007

< 0.022

< 0.013

< 0.007

< 0.079

< 0.044 I -3

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emitting isotopes and lJ31a.

Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-007 (cont.)

7Be 58Co 60Co 95Zr 134Cs 137Cs 140BaLa 1Ce Required LLDs 0.050 0.060 Date Collected Vol.

a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

07-06-23 236

< 0.10

<0.011

<0.005

<0.026

<0.009

<0.009

<0.126

<0.044 07-13-23 233

< 0.16

<0.011

<0.008

<0.022

<0.012

<0.009

<0.079

<0.047 07-20-23 272

< 0.09

< 0.007

< 0.009

< 0.018

< 0.010

< 0.005

< 0.083

< 0.038 07-27-23 276

< 0.14

<0.009

<0.004

<0.022

<0.011

<0.010

<0.044

<0.034 08-03-23 277

< 0.09

< 0.006

< 0.006

< 0.015

< 0.010

< 0.008

< 0.049

< 0.036 08-10-23 254

< 0.08

< 0.008

< 0.008

< 0.016

< 0.010

< 0.009

< 0.028

< 0.037 08-17-23 243

< 0.08

< 0.010

< 0.007

< 0.018

< 0.012

< 0.006

< 0.024

< 0.042 08-24-23 293 0.13

+/- 0.07

<0.008

<0.006

<0.012

<0.009

<0.006

<0.030

<0.032 08-31-23 266

< 0.08

< 0.007

< 0.010

< 0.015

< 0.010

< 0.010

< 0.016

< 0.040 09-07-23 272

< 0.06

< 0.008

< 0.008

< 0.018

< 0.010

< 0.006

< 0.061

< 0.037 09-14-23 273 0.18

+/- 0.09

<0.010

<0.011

<0.017

<0.009

<0.009

<0.040

<0.038 09-21-23 276 0.17

+/- 0.10

< 0.009

< 0.005

< 0.016

< 0.008

< 0.007

< 0.023

< 0.036 09-28-23 279

< 0.06

< 0.006

< 0.005

< 0.012

< 0.009

< 0.007

< 0.009

< 0.035 10-05-23 278

< 0.10

< 0.006

< 0.004

< 0.016

< 0.008

< 0.008

< 0.033

< 0.029 10-12-23 282

< 0.08

<0.007

<0.007

<0.014

<0.011

<0.008

<0.022

<0.037 10-19-23 282 0.14

+/- 0.08

< 0.007

< 0.007

< 0.015

< 0.010

< 0.008

< 0.014

< 0.039 10-26-23 277 0.14

+/- 0.08

< 0.006

< 0.010

< 0.015

< 0.010

< 0.006

< 0.020

< 0.035 I 1-02-23 279

< 0.07

< 0.006

< 0.006

< 0.012

< 0.008

< 0.008

< 0.014

< 0.038 11-08-23 235

< 0.12

<0.008

<0.006

<0.016

<0.012

<0.006

<0.007

<0.049 11-16-23 316

< 0.07

<0.007

<0.004

<0.012

<0.005

<0.006

<0.022

<0.033 11-22-23 235

< 0.11

<0.009

<0.009

<0.018

<0.012

<0.008

<0.041

<0.046 11-30-23 317 0.14

+/- 0.06

<0.007

<0.005

<0.013

<0.007

<0.005

<0.020

<0.031 12-07-23 273

< 0.10

<0.012

<0.007

<0.017

<0.011

<0.006

<0.087

<0.039 12-14-23 276

<0.09

<0.010

<0.005

<0.018

<0.011

<0.007

<0.059

<0.040 12-20-23 241

<0.08

<0.011

<0.010

<0.017

<0.012

<0.006

<0.042

<0.041 12-28-23 309 0.17

+/- 0.09

<0.007

<0.004

<0.011

<0.010

<0.006

<0.015

<0.031 I -4

Table 1. Air particulates and charcoal cartridges, analyses for gamma-emitting isotopes and l131a.

Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-008 7Be 58Co 60Co 95Zr 134Cs 137Cs 140BaLa 144Ce Required LLDs 0.050 0.060 Date Collected Vol.

a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

01-05-23 278

< 0.1 1

< 0.007

< 0.005

< 0.020

< 0.007

< 0.007

< 0.022

< 0.026 01-12-23 285

< 0.12

<0.006

<0.019

<0.017

<0.010

<0.015

<0.036

<0.054 01-19-23 281

< 0.09

<0.006

<0.010

<0.019

<0.010

<0.007

<0.051

<0.034 01-26-23 284

< 0.12

<0.011

<0.011

<0.013

<0.008

<0.004

<0.021

<0.033 02-02-23 284

< 0.12

<0.008

<0.019

<0.019

<0.010

<0.014

<0.035

<0.044 02-09-23 282 0.13

+/- 0.05

<0.004

<0.004

<0.005

<0.004

<0.004

<0.008

<0.027 02-16-23 283

< 0.10

< 0.004

< 0.009

< 0.012

< 0.008

< 0.008

< 0.017

< 0.039 02-23-23 276 0.19

+/- 0.08

<0.008

<0.003

<0.015

<0.010

<0.008

<0.073

<0.040 03-02-23 266

< 0.09

< 0.007

< 0.007

< 0.013

< 0.007

< 0.005

< 0.079

< 0.035 03-09-23 265

< 0.15

<0.014

<0.017

<0.025

<0.011

<0.007

<0.744

<0.040 03-16-23 264

< 0.13

<0.006

<0.017

<0.012

<0.009

<0.012

<0.069

<0.040 03-23-23 265

< 0.12

< 0.012

< 0.019

< 0.077

< 0.009

< 0.014

< 0.077

< 0.032 03-30-23 262

<0.13

<0.012

<0.011

<0.075

<0.011

<0.011

<0.051

<0.041 04-06-23 259

< 0.14

< 0.009

< 0.007

< 0.023

< 0.012

< 0.008

< 0.041

< 0.056 04-13-23 260

< 0.15

<0.011

<0.009

<0.013

<0.012

<0.008

<0.016

<0.076 04-20-23 253 0.14

+/- 0.04

<0.004

<0.005

<0.004

<0.004

<0.003

<0.011

<0.023 04-27-23 251

< 0.10

<0.012

<0.012

<0.025

<0.011

<0.006

<0.015

<0.039 05-04-23 243 0.35 +/-0.14

<0.010

<0.006

<0.018

<0.011

<0.008

<0.016

<0.047 05-11-23 245 0.31

+/-0.16

<0.008

<0.007

<0.017

<0.010

<0.008

<0.023

<0.053 05-18-23 244

< 0.12

< 0.006

< 0.005

< 0.010

< 0.009

< 0.005

< 0.027

< 0.048 05-25-23 244

< 0.08

< 0.010

< 0.009

< 0.022

< 0.010

< 0.006

< 0.046

< 0.041 06-01-23 242

< 0.09

< 0.007

< 0.005

< 0.020

< 0.010

< 0.007

< 0.021

< 0.042 06-08-23 242 0.24

+/- 0.13

<0.011

<0.010

<0.025

<0.011

<0.008

<0.088

<0.039 06-15-23 239 0.16

+/- 0.09

< 0.007

< 0.009

< 0.016

< 0.013

< 0.008

< 0.041

< 0.042 06-22-23 242

< 0.08

<0.009

<0.011

<0.020

<0.012

<0.006

<0.020

<0.041 06-29-23 241

< 0.12

< 0.009

< 0.008

< 0.022

< 0.012

< 0.007

< 0.030

< 0.039 I -5

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emifting isotopes and I131a.

Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-GOB (cont.)

7Be 58Co 60Co 95Zr 1Cs 137Cs 40BaLa 144Ce Required LLDs 0.050 0.060 Date Collected Vol.

a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

07-06-23 234

< 0.1 1

< 0.009

< 0.009

< 0.022

< 0.01 1

< 0.008

< 0.251

< 0.048 07-13-23 239

< 0.13

<0.014

<0.007

<0.025

<0.011

<0.006

<0.173

<0.045 07-20-23 234

< 0.11

<0.018

<0.009

<0.023

<0.012

<0.009

<0.058

<0.047 07-27-23 238

< 0.15

< 0.009

< 0.005

< 0.020

< 0.014

< 0.008

< 0.047

< 0.041 08-03-23 236

< 0.09

<0.011

<0.009

<0.020

<0.009

<0.010

<0.082

<0.042 08-10-23 234

< 0.12

< 0.010

< 0.009

< 0.022

< 0.012

< 0.007

< 0.028

< 0.045 08-17-23 232

< 0.10

< 0.008

< 0.006

< 0.020

< 0.015

< 0.008

< 0.054

< 0.043 08-24-23 258

< 0.08

< 0.003

< 0.007

< 0.013

< 0.010

< 0.009

< 0.031

< 0.040 08-31-23 249

< 0.08

< 0.008

< 0.007

< 0.016

< 0.008

< 0.008

< 0.015

< 0.042 09-07-23 258 0.25

+/- 0.12

< 0.007

< 0.004

< 0.013

< 0.013

< 0.008

< 0.077

< 0.042 09-14-23 259 0.18 +/-0.09

<0.009

<0.007

<0.018

<0.011

<0.006

<0.034

<0.043 09-21-23 255

< 0.10

< 0.009

< 0.005

< 0.015

< 0.010

< 0.005

< 0.025

< 0.042 09-28-23 260 0.20

+/- 0.09

< 0.006

< 0.007

< 0.018

< 0.010

< 0.006

< 0.010

< 0.042 10-05-23 286 0.19

+/- 0.10

<0.011

<0.003

<0.018

<0.007

<0.008

<0.031

<0.036 10-12-23 321

< 0.07

< 0.006

< 0.005

< 0.012

< 0.009

< 0.007

< 0.016

< 0.031 10-19-23 348 0.14

+/- 0.07

< 0.005

< 0.002

< 0.012

< 0.008

< 0.006

< 0.027

< 0.028 10-26-23 272 0.14

+/- 0.08

< 0.006

< 0.008

< 0.014

< 0.009

< 0.008

< 0.012

< 0.038 11-02-23 273

< 0.05

<0.009

<0.010

<0.017

<0.010

<0.006

<0.018

<0.038 1 1-08-23 234 0.14

+/- 0.08

< 0.004

< 0.006

< 0.01 1

< 0.007

< 0.006

< 0.007

< 0.042 1 1-16-23 313 0.19

+/- 0.09

< 0.007

< 0.008

< 0.012

< 0.006

< 0.007

< 0.016

< 0.028 11-22-23 233

< 0.09

<0.008

<0.012

<0.019

<0.011

<0.006

<0.058

<0.056 11-30-23 315 0.16 +/-0.10

<0.006

<0.008

<0.013

<0.008

<0.005

<0.025

<0.034 12-07-23 272

< 0.10

< 0.009

< 0.006

< 0.017

< 0.012

< 0.008

< 0.064

< 0.040 12-14-23 276

< 0.09

< 0.006

< 0.009

< 0.016

< 0.010

< 0.008

< 0.069

< 0.035 12-20-23 240

<0.10

<0.010

<0.005

<0.017

<0.012

<0.006

<0.060

<0.041 12-28-23 307 0.17

+/- 0.08

< 0.007

< 0.009

< 0.010

< 0.009

< 0.006

< 0.038

< 0.033 1-6

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emifting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-009 7Be 58Co 60Co 95Zr 1Cs 137Cs 140BaLa 1Ce Required LLDs 0.050 0.060 Date Collected Vol.

01-05-23 262

< 0.10 01-12-23 268

< 0.09 01-19-23 266

< 0.09 01-26-23 268

< 0.13 02-02-23 269

< 0.13 02-09-23 266 0.15

+/- 0.04 02-16-23 268 0.12

+/- 0.04 02-23-23 261

< 0.08 03-02-23 269

< 0.09 03-09-23 267

< 0.17 03-16-23 267

< 0.11 03-23-23 268

< 0.19 03-30-23 266

< 0.14 04-06-23 263

< 0.14 04-13-23 268 0.23

+/- 0.13 04-20-23 260

< 0.11 04-27-23 261 0.19

+/- 0.10 05-04-23 256

< 0.12 05-11-23 259

< 0.13 05-18-23 261

< 0.14 05-25-23 261 0.18

+/- 0.09 06-01-23 260 0.28

+/- 0.13 06-08-23 258 0.22

+/- 0.13 06-15-23 255 0.20

+/- 0.09 06-22-23 260 0.15

+/- 0.09 06-29-23 258 0.15

+/- 0.09 lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

< 0.005

< 0.009

< 0.019

< 0.008

< 0.007

< 0.049

< 0.053

< 0.010

< 0.007

< 0.024

< 0.009

< 0.009

< 0.016

< 0.042

<0.010

<0.008

<0.019

<0.010

<0.007

<0.066

<0.036

< 0.010

< 0.007

< 0.015

< 0.009

< 0.009

< 0.045

< 0.043

< 0.008

< 0.006

< 0.016

< 0.009

< 0.005

< 0.014

< 0.050

< 0.004

< 0.005

< 0.007

< 0.004

< 0.003

< 0.013

< 0.019

< 0.004

< 0.003

< 0.006

< 0.004

< 0.005

< 0.006

< 0.015

< 0.005

< 0.007

< 0.012

< 0.01 1

< 0.009

< 0.028

< 0.039

< 0.009

< 0.008

< 0.018

< 0.008

< 0.006

< 0.078

< 0.034

< 0.009

< 0.005

< 0.021

< 0.01 1

< 0.006

< 0.054

< 0.056

< 0.010

< 0.008

< 0.022

< 0.009

< 0.007

< 0.070

< 0.046

<0.017

<0.008

<0.026

<0.014

<0.014

<0.110

<0.066

< 0.013

< 0.020

< 0.019

< 0.010

< 0.016

< 0.049

< 0.051

< 0.009

< 0.009

< 0.016

< 0.013

< 0.005

< 0.038

< 0.045

<0.012

<0.013

<0.012

<0.014

<0.008

<0.031

<0.056

< 0.008

< 0.020

< 0.020

< 0.010

< 0.018

< 0.016

< 0.053

< 0.009

< 0.010

< 0.010

< 0.010

< 0.008

< 0.008

< 0.055

<0.011

<0.008

<0.012

<0.011

<0.008

<0.030

<0.038

<0.009

<0.011

<0.022

<0.009

<0.006

<0.018

<0.029

<0.009

<0.009

<0.026

<0.011

<0.009

<0.015

<0.035

<0.007

<0.008

<0.019

<0.011

<0.008

<0.033

<0.039

<0.007

<0.007

<0.019

<0.011

<0.005

<0.072

<0.040

< 0.009

< 0.006

< 0.012

< 0.010

< 0.007

< 0.044

< 0.039

< 0.009

< 0.009

< 0.015

< 0.010

< 0.007

< 0.032

< 0.035

< 0.009

< 0.007

< 0.020

< 0.010

< 0.009

< 0.032

< 0.035

< 0.006

< 0.005

< 0.019

< 0.006

< 0.007

< 0.061

< 0.038 I-f

Table 1. Air particulates and charcoal cartridges, analyses for gamma-emitting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-009 (cont.)

7Be 58Co 60Co 95Zr 1Cs 137Cs 40BaLa 44Ce Required LLDs 0.050 0.060 Date Collected Vol.

a lodine-131 concenttations ate < 0.07 pCi/rn3 unless noted otherwise.

07-06-23 257

<0.11

<0.014

<0.012

<0.028

<0.012

<0.005

<0.103

<0.039 07-13-23 260

< 0.14

<0.012

<0.007

<0.077

<0.012

<0.007

<0.101

<0.040 07-20-23 255 0.30

+/- 0.17

<0.010

<0.007

<0.021

<0.012

<0.009

<0.059

<0.044 07-27-23 260

<0.11

<0.009

<0.010

<0.019

<0.012

<0.008

<0.043

<0.034 08-03-23 260 0.22

+/- 0.12

< 0.007

< 0.007

< 0.018

< 0.009

< 0.006

< 0.037

< 0.042 08-10-23 257

< 0.10

< 0.010

< 0.009

< 0.019

< 0.009

< 0.008

< 0.036

< 0.037 08-17-23 257

< 0.08

< 0.009

< 0.007

< 0.018

< 0.009

< 0.008

< 0.023

< 0.042 08-24-23 261

< 0.09

< 0.009

< 0.005

< 0.01 1

< 0.009

< 0.009

< 0.023

< 0.039 08-31-23 256

< 0.08

< 0.007

< 0.007

< 0.015

< 0.012

< 0.008

< 0.025

< 0.040 09-07-23 259

< 0.10

< 0.009

< 0.008

< 0.023

< 0.010

< 0.006

< 0.104

< 0.041 09-14-23 258

< 0.09

< 0.007

< 0.008

< 0.016

< 0.009

< 0.008

< 0.049

< 0.042 09-21-23 257 0.22 +/-0.11

<0.008

<0.008

<0.017

<0.010

<0.009

<0.017

<0.040 09-28-23 259 0.16 +/-0.08

<0.012

<0.007

<0.017

<0.011

<0.008

<0.012

<0.038 10-05-23 258

< 0.11

<0.008

<0.009

<0.021

<0.006

<0.005

<0.060

<0.041 10-12-23 254

< 0.08

< 0.009

< 0.005

< 0.017

< 0.01 1

< 0.009

< 0.025

< 0.040 10-19-23 253

< 0.09

< 0.009

< 0.009

< 0.018

< 0.010

< 0.009

< 0.015

< 0.040 10-26-23 253

< 0.08

< 0.009

< 0.009

< 0.021

< 0.012

< 0.009

< 0.022

< 0.040 11-02-23 258

<0.06

<0.007

<0.012

<0.015

<0.011

<0.008

<0.015

<0.039 11-08-23 217

< 0.20

<0.009

<0.008

<0.012

<0.013

<0.009

<0.049

<0.050 11-16-23 293

<0.07

<0.006

<0.004

<0.014

<0.005

<0.007

<0.014

<0.031 11-22-23 217

<0.10

<0.009

<0.008

<0.026

<0.011

<0.007

<0.063

<0.047 1 1-30-23 293 0.20

+/- 0.12

< 0.006

< 0.018

< 0.018

< 0.010

< 0.014

< 0.024

< 0.047 12-07-23 252

< 0.06

< 0.009

< 0.009

< 0.014

< 0.01 1

< 0.009

< 0.043

< 0.044 12-14-23 254

< 0.13

<0.009

<0.010

<0.023

<0.011

<0.008

<0.075

<0.039 12-20-23 239

<0.09

<0.011

<0.007

<0.018

<0.012

<0.007

<0.025

<0.046 12-28-23 306 0.17 +/-0.09

<0.007

<0.004

<0.011

<0.010

<0.006

<0.015

<0.031 1-8

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emifting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-O1 0 7Be wCo 60Co 95Zr 34Cs 137Cs 140BaLa 1Ce Requited LLDs 0.050 0.060 Date Collected Vol.

01-05-23 274

< 0.11

<0.008 01-12-23 264

< 0.08

<0.008 01-19-23 264

<0.09

<0.011 01-26-23 271

< 0.08

< 0.007 02-02-23 273

< 0.13

< 0.010 02-09-23 273 0.16

+/- 0.09

< 0.007 02-16-23 273 0.14

+/- 0.04

< 0.003 02-23-23 274 0.21

+/- 0.09

< 0.007 03-02-23 278

< 0.08

< 0.005 03-09-23 279 0.12

+/- 0.05

< 0.006 03-16-23 278

<0.13

<0.011 03-23-23 279

< 0.13

< 0.009 03-30-23 278

<0.15

<0.013 04-06-23 275 0.27

+/- 0.16

<0.011 04-13-23 280 0.34

+/- 0.14

< 0.006 04-20-23 276 0.21

+/- 0.10

< 0.010 04-27-23 283 0.18

+/- 0.09

< 0.008 05-04-23 277 0.19

+/- 0.11

< 0.005 05-11-23 279 0.24 +/-0.11

<0.011 05-18-23 279

< 0.10

<0.008 05-25-23 279 0.17

+/- 0.10

< 0.006 06-01-23 279 0.32

+/- 0.14

< 0.009 06-08-23 278 0.39

+/- 0.13

< 0.008 06-15-23 274 0.27 +/-0.12

<0.008 06-22-23 277 0.20

+/- 0.10

< 0.010 06-29-23 273

< 0.08

< 0.004 a lodine-131 concenttations ate < 0.07 pCi/rn3 unless noted otherwise.

< 0.009

< 0.012

< 0.009

< 0.007

< 0.045

< 0.047

< 0.005

< 0.021

< 0.012

< 0.007

< 0.043

< 0.045

< 0.008

< 0.019

< 0.010

< 0.008

< 0.031

< 0.036

< 0.006

< 0.022

< 0.010

< 0.006

< 0.060

< 0.034

<0.007

<0.010

<0.011

<0.012

<0.030

<0.037

< 0.008

< 0.013

< 0.007

< 0.006

< 0.018

< 0.024

< 0.005

< 0.007

< 0.004

< 0.004

< 0.009

< 0.017

< 0.009

< 0.018

< 0.007

< 0.006

< 0.013

< 0.033

< 0.006

< 0.012

< 0.009

< 0.006

< 0.068

< 0.032

< 0.005

< 0.009

< 0.004

< 0.005

< 0.048

< 0.016

<0.008

<0.014

<0.009

<0.008

<0.057

<0.044

< 0.020

< 0.015

< 0.009

< 0.014

< 0.048

< 0.037

< 0.005

< 0.013

< 0.010

< 0.006

< 0.022

< 0.058

< 0.014

< 0.019

< 0.012

< 0.012

< 0.035

< 0.042

<0.010

<0.017

<0.013

<0.014

<0.022

<0.064

< 0.006

< 0.023

< 0.01 1

< 0.01 1

< 0.008

< 0.046

< 0.005

< 0.014

< 0.009

< 0.007

< 0.017

< 0.048

< 0.006

< 0.016

< 0.009

< 0.008

< 0.019

< 0.048

<0.006

<0.015

<0.009

<0.004

<0.016

<0.043

< 0.004

< 0.015

< 0.009

< 0.006

< 0.014

< 0.036

< 0.009

< 0.018

< 0.010

< 0.006

< 0.058

< 0.038

< 0.006

< 0.017

< 0.008

< 0.009

< 0.027

< 0.037

<0.007

<0.013

<0.010

<0.007

<0.029

<0.037

< 0.008

< 0.018

< 0.008

< 0.008

< 0.023

< 0.039

< 0.005

< 0.015

< 0.009

< 0.003

< 0.045

< 0.037

< 0.004

< 0.016

< 0.009

< 0.006

< 0.047

< 0.033 I -9

Table 1. Air particulates and charcoal cartridges, analyses for gamma-emitting isotopes and li3f a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-OW (cont.)

7Be 58Co 60Co 95Zr 134Cs 137Cs 140BaLa 144Ce Required LLDs 0.050 0.060 Date Collected Vol.

07-06-23 272

< 0.12 07-13-23 277

< 0.10 07-30-23 270

< 0.11 07-27-23 272

< 0.09 08-03-23 267 0.16

+/- 0.09 08-10-23 263

< 0.13 08-17-23 261

< 0.07 08-24-23 258

< 0.08 08-31-23 254

< 0.08 09-07-23 261 0.17

+/- 0.10 09-14-23 266 0.24

+/- 0.11 09-21-23 266 0.21

+/- 0.11 09-28-23 266 0.15

+/- 0.08 10-05-23 267 0.22

+/- 0.13 10-12-23 267

< 0.12 10-19-23 269

< 0.07 10-26-23 266 0.19

+/- 0.10 11-02-23 271

< 0.07 11-08-23 246

< 0.13 11-16-23 330 0.15

+/- 0.09 11-22-23 268

< 0.08 1 1-30-23 338

< 0.08 12-07-23 291

< 0.08 12-14-23 292

< 0.08 12-20-23 256

< 0.07 12-28-23 326 0.16

+/- 0.09

< 0.008

< 0.009

< 0.021

< 0.009

< 0.006

<0.008

<0.005

<0.021

<0.011

<0.006

<0.007

<0.010

<0.023

<0.010

<0.006

<0.009

<0.009

<0.015

<0.009

<0.006

<0.009

<0.010

<0.017

<0.007

<0.007

< 0.010

< 0.025

< 0.018

< 0.013

< 0.018

<0.007

<0.013

<0.019

<0.010

<0.007

<0.009

<0.011

<0.018

<0.007

<0.006

<0.008

<0.007

<0.019

<0.011

<0.007

<0.010

<0.008

<0.022

<0.011

<0.005

<0.006

<0.010

<0.016

<0.012

<0.007

< 0.007

< 0.010

< 0.017

< 0.010

< 0.008

<0.006

<0.008

<0.015

<0.011

<0.007

<0.008

<0.009

<0.019

<0.009

<0.007

<0.011

<0.006

<0.019

<0.010

<0.009

<0.010

<0.009

<0.017

<0.010

<0.008

<0.007

<0.011

<0.018

<0.012

<0.006

< 0.008

< 0.009

< 0.012

< 0.010

< 0.007

<0.008

<0.007

<0.024

<0.011

<0.010

<0.004

<0.009

<0.013

<0.007

<0.005

<0.009

<0.006

<0.020

<0.012

<0.007

< 0.006

< 0.006

< 0.012

< 0.008

< 0.005

< 0.008

< 0.007

< 0.015

< 0.008

< 0.006

<0.009

<0.006

<0.012

<0.011

<0.006

<0.010

<0.008

<0.016

<0.014

<0.008

< 0.008

< 0.004

< 0.010

< 0.008

< 0.006 a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

< 0.140

< 0.096

< 0.051

< 0.051

< 0.052

< 0.021

< 0.056

< 0.019

< 0.026

< 0.049

< 0.048

< 0.034

< 0.010

< 0.028

< 0.025

< 0.031

< 0.015

< 0.015

< 0.043

< 0.031

< 0.036

< 0.014

< 0.043

< 0.066

< 0.040

< 0.026

< 0.042

< 0.040

< 0.038

< 0.039

< 0.038

< 0.046

< 0.038

< 0.037

< 0.036

< 0.041

< 0.040

< 0.044

< 0.039

< 0.040

< 0.062

< 0.035

< 0.040

< 0.036

< 0.043

< 0.028

< 0.038

< 0.030

< 0.034

< 0.041

< 0.039

< 0.032 I -10

Table 1. Air particulates and charcoal cartridges, analyses forgamma-emifting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-O1 I 7Be 58Co 60Co 95Zr 134Cs 37Cs 140BaLa 144Ce Required LLDs 0.050 0.060 Date Collected Vol.

01-05-23 303

< 0.11 01-12-23 309

< 0.07 01-19-23 289

< 0.08 01-26-23 289

< 0.09 02-02-23 289

< 0.10 02-09-23 292 0.17

+/- 0.09 02-16-23 295 0.22

+/- 0.11 02-23-23 287

< 0.07 03-02-23 288

< 0.08 03-09-23 283 0.10

+/- 0.04 03-16-23 274

< 0.15 03-23-23 277

< 0.11 03-30-23 280

< 0.14 04-06-23 278

< 0.12 04-13-23 286

< 0.14 04-20-23 242 0.27

+/- 0.13 04-27-23 230 0.18

+/- 0.11 05-04-23 220 0.20

+/- 0.10 05-11-23 272 0.17

+/- 0.08 05-18-23 278 0.17

+/- 0.09 05-25-23 285

< 0.08 06-01-23 294 0.34

+/- 0.09 06-08-23 300 0.21

+/- 0.10 06-15-23 306 0.22

+/- 0.09 06-22-23 317 0.21

+/- 0.09 06-29-23 323 0.18

+/- 0.11 a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

<0.006

<0.006

<0.019

<0.008

<0.006

<0.047

<0.041

< 0.009

< 0.007

< 0.012

< 0.009

< 0.007

< 0.047

< 0.032

< 0.009

< 0.006

< 0.015

< 0.006

< 0.006

< 0.050

< 0.031

< 0.006

< 0.018

< 0.013

< 0.008

< 0.014

< 0.037

< 0.048

< 0.004

< 0.016

< 0.009

< 0.008

< 0.012

< 0.025

< 0.039

< 0.005

< 0.007

< 0.014

< 0.007

< 0.004

< 0.023

< 0.041

<0.008

<0.006

<0.012

<0.010

<0.005

<0.041

<0.036

< 0.007

< 0.008

< 0014

< 0.010

< 0.008

< 0.021

< 0.034

< 0.007

< 0.006

< 0.013

< 0.010

< 0.004

< 0.033

< 0.031

< 0.005

< 0.007

< 0.007

< 0.003

< 0.005

< 0.033

< 0.016

<0.012

<0.010

<0.021

<0.010

<0.009

<0.130

<0.048

< 0.009

< 0.004

< 0.01 1

< 0.008

< 0.008

< 0.029

< 0.036

<0.011

<0.010

<0.024

<0.009

<0.010

<0.051

<0.053

<0.010

<0.020

<0.016

<0.010

<0.017

<0.028

<0.041

<0.015

<0.009

<0.016

<0.012

<0.006

<0.027

<0.043

<0.009

<0.009

<0.015

<0.011

<0.013

<0.017

<0.055

<0.007

<0.007

<0.019

<0.009

<0.007

<0.017

<0.031

<0.011

<0.009

<0.018

<0.011

<0.009

<0.012

<0.054

< 0.005

< 0.005

< 0.009

< 0.007

< 0.008

< 0.021

< 0.034

< 0.010

< 0.008

< 0.017

< 0.009

< 0.007

< 0.058

< 0.037

<0.007

<0.009

<0.017

<0.007

<0.007

<0.018

<0.032

< 0.007

< 0.006

< 0.016

< 0.010

< 0.008

< 0.032

< 0.033

< 0.007

< 0.005

< 0.01 1

< 0.007

< 0.007

< 0.039

< 0.033

< 0.009

< 0.009

< 0.015

< 0.006

< 0.007

< 0.030

< 0.034

< 0.007

< 0.007

< 0.017

< 0.008

< 0.006

< 0.028

< 0.031

< 0.007

< 0.008

< 0.014

< 0.007

< 0.005

< 0.040

< 0.030 111

Table 1. Air particulates and charcoal cartridges, analyses for gamma-emitting isotopes and 131a Collection:

Continuous, weekly exchange.

Units:

pCi/rn3 Location CA-A-Oil (cont.)

7Be 58Co 60Co 95Zr 134Cs 37Cs 140BaLa 1Ce Required LLDs 0.050 0.060 Date Collected Vol.

07-06-23 329 0.30

+/- 0.1 1 07-13-23 339 0.20

+/- 0.10 07-20-23 315 0.26

+/- 0.13 07-27-23 326

< 0.07 08-03-23 334 0.16

+/- 0.09 08-10-23 332 0.23

+/- 0.10 08-17-23 337

< 0.07 08-24-23 315 0.19

+/- 0.08 08-31-23 319

< 0.08 09-07-23 331

< 0.10 09-14-23 336 0.15

+/- 0.09 09-21-23 336 0.18

+/- 0.07 09-28-23 270 0.21

+/- 0.09 10-05-23 286 0.24

+/- 0.13 10-12-23 300

< 0.06 10-19-23 312 0.14

+/- 0.07 10-26-23 317

< 0.06 1 1-02-23 333

< 0.05 11-08-23 286

< 0.08 11-16-23 339 0.14

+/- 0.08 11-22-23 225 0.20

+/- 0.12 11-30-23 309 0.19

+/- 0.10 12-07-23 269

< 0.07 1 2-1 4-23 271

< 0.07 12-20-23 238

< 0.09 12-28-23 301 0.19

+/- 0.08 a lodine-131 concentrations are < 0.07 pCi/rn3 unless noted otherwise.

< 0.120

< 0.046

< 0.076

< 0.061

< 0.066

< 0.015

< 0.022

< 0.039

< 0.022

< 0.039

< 0.019

< 0.019

< 0.012

< 0.050

< 0.039

< 0.027

< 0.028

< 0.019

< 0.027

< 0.012

< 0.031

< 0.012

< 0.018

< 0.035

< 0.031

< 0.039

< 0.032

< 0.032

< 0.029

< 0.031

< 0.029

< 0.056

< 0.029

< 0.031

< 0.032

< 0.033

< 0.032

< 0.031

< 0.035

< 0.041

< 0.034

< 0.032

< 0.033

< 0.026

< 0.040

< 0.030

< 0.041

< 0.031

< 0.035

< 0.037

< 0.041

< 0.035

<0.006

<0.006

<0.019

<0.009

<0.006

<0.007

<0.004

<0.017

<0.007

<0.004

<0.010

<0.016

<0.011

<0.007

<0.012

< 0.009

< 0.008

< 0.016

< 0.005

< 0.007

< 0.005

< 0.004

< 0.013

< 0.008

< 0.007

< 0.012

< 0.006

< 0.010

< 0.012

< 0.009

< 0.006

< 0.004

< 0.016

< 0.006

< 0.005

< 0.005

< 0.006

< 0.013

< 0.008

< 0.005

< 0.007

< 0.004

< 0.013

< 0.009

< 0.005

< 0.008

< 0.010

< 0.013

< 0.007

< 0.005

< 0.006

< 0.006

< 0.013

< 0.007

< 0.006

< 0.004

< 0.010

< 0.014

< 0.007

< 0.007

<0.008

<0.009

<0.011

<0.010

<0.007

<0.008

<0.007

<0.021

<0.011

<0.007

< 0.007

< 0.009

< 0.014

< 0.006

< 0.005

<0.006

<0.007

<0.011

<0.009

<0.004

< 0.008

< 0.010

< 0.015

< 0.008

< 0.006

< 0.005

< 0.004

< 0.013

< 0.005

< 0.006

< 0.008

< 0.006

< 0.012

< 0.010

< 0.008

< 0.006

< 0.003

< 0.01 1

< 0.007

< 0.005

< 0.009

< 0.009

< 0.019

< 0.012

< 0.009

< 0.005

< 0.008

< 0.012

< 0.007

< 0.005

<0.006

<0.008

<0.013

<0.013

<0.008

< 0.009

< 0.006

< 0.006

< 0.009

< 0.007

<0.009

<0.011

<0.014

<0.013

<0.011

< 0.006

< 0.007

< 0.012

< 0.008

< 0.006 1-12

Table 2. Milk, analyses for iodine-131 and gamma-emitting isotopes.

Collection:

Semimonthly during grazing season, monthly otherwise.

Units:

pCi/L Location CA-MLK-M9 Date Lab Concentration (pCiIL)

Collected Code

-131 K-40 Zn-65 Cs-134 Cs-137 Ba-La-140 Required LLDs I

15 18 15 Collection discontinued.a a Milk sampling discontined in 2018.

2-1

Table 3. Vegetation, analyses for iodine-131 and gamma-emitting isotopes.

Collection:

Monthly, dung growing season Units:

pCi/kg wet Collection Concentration (pCi/kg wet)

Lab Code Date Sample Type 40K 54Mn 58Co 60Co 1311 34Cs 137Cs Location: CA-FPL-V9 April 23 NSa May 23 NSb CAVE-1510 6/6/2023 Kale 4644

+/- 371

< 8.2

< 8.9

< 23.3

< 36.8

< 12.8

< 19.8 CAVE-1511 6/6/2023 Collard Greens 5840

+/- 639

< 27.7

< 29.7

< 19.2

< 47.3

< 25.6

< 22.2 CAVE-1512 6/6/2023 Spinach 8675

+/- 479

< 11.8

< 16.5

< 12.5

< 19.2

< 12.0

< 13.4 CAVE-1513 6/6/2023 Swiss Chard 5990

+/- 258

< 9.1

< 6.9

< 16.0

< 28.3

< 7.9

< 11.8 CAVE-1514 6/6/2023 Lettuce 4358 +/-417

<14.6

<8.4

<7.4

<25.5

<13.9

<11.2 CAVE-1515 6/6/2023 Turnip Greens 4625

+/- 550

< 26.6

< 26.2

< 15.3

< 32.4

< 20.6

< 18.7 CAVE-1516 6/6/2023 Mustard Greens 4908

+/- 330

< 10.0

< 7.0

< 19.7

< 16.3

< 10.7

< 15.3 CAVE-1517 6/6/2023 Cabbage 4144

+/- 291

< 6.0

< 5.5

< 19.3

< 13.2

< 9.3

< 16.3 CAVE-1800 7/5/2023 Cabbage 5298

+/- 542

< 22.1

< 24.5

< 22.5

< 27.5

< 22.4

< 13.4 CAVE-1801 7/5/2023 Swiss Chard 9141

+/- 439

< 12.6

< 11.4

< 22.5

< 14.1

< 12.1

< 18.6 CAVE-1802 7/5/2023 Collard Greens 4937

+/- 586

< 22.9

< 19.8

< 15.5

< 20.5

< 18.3

< 13.4 CAVE-1803 7/5/2023 Lettuce 8199

+/- 455

< 14.1

< 13.1

< 22.2

< 22.5

< 11.4

< 18.8 CAVE-1804 7/5/2023 Kale 5791

+/- 574

< 16.2

< 27.6

< 20.8

< 25.4

< 18.7

< 16.8 CAVE-2283 8/1/2023 Turnip Greens 4714

+/- 496

< 11.1

< 11.2

< 26.5

< 36.3

< 19.3

< 23.9 CAVE-2285 8/1/2023 Swiss Chard 4210

+/- 317

< 8.1

< 10.3

< 17.1

< 19.9

< 11.0

< 13.7 CAVE-2286 8/1/2023 Cabbage 4703

+/- 596

< 18.0

< 10.4

< 32.5

< 47.6

< 20.6

< 23.0 CAVE-2287 8/1/2023 Kale 4167

+/- 373

< 13.9

< 13.0

< 21.6

< 26.2

< 12.5

< 19.0 CAVE-2288 8/1/2023 Collard Greens 3764

+/- 288

< 6.4

< 10.8

< 17.9

< 15.6

< 10.1

< 15.5 CAVE-2625 9/6/2023 Kale 5550

+/- 816

< 25.6

< 24.3

< 27.5

< 20.8

< 37.1

< 31.2 CAVE-2626 9/6/2023 Collard Greens 5532

+/- 491

< 11.2

< 8.1

< 25.5

< 14.3

< 17.1

< 24.6 CAVE-2627 9/6/2023 Swiss Chard 5126

+/- 639

< 20.5

< 23.3

< 13.5

< 20.2

< 22.2

< 22.2 CAVE-2998 10/3/2023 Collard Greens 4567

+/- 693

< 28.2

< 23.2

< 12.3

< 22.9

< 24.7

< 27.6 CAVE-2999 10/3/2023 Kale 5960

+/- 484

< 14.3

< 15.1

< 21.6

< 18.5

< 15.3

< 22.5 CAVE-3000 10/3/2023 Swiss Chard 7821

+/- 753

< 13.4

< 14.1

< 30.0

< 23.2

< 17.6

< 30.6 CAVE-3001 10/3/2023 Mustard Greens 5476

+/- 852

< 24.6

< 22.1

< 26.8

< 20.0

< 34.8

< 25.5 CAVE-3002 10/3/2023 Lettuce 4679

+/- 737

< 19.5

< 17.7

< 12.9

< 13.9

< 24.3

< 16.8 a NS = No sample; see Part I Table 5.5 Missed Collections and Analyses (CR#202320405).

b NS = No sample; see Part I Table 5.5 Missed Collections and Analyses (CR#202303264).

3-1

Table 3. Vegetation, analyses for iodine-f31 and gamma-emitting isotopes.

Collection:

Monthly, dung growing season Units:

pCi/kg wet Collection Concentration (pCi/kg wet)

Lab Code Date Sample Type 40K 54Mn 58Co 60Co 1311 1Cs 137Cs Location: CA-FPL-V1 6 April 23 NS2 CAVE-1184 5/9/2023 Kale 4712 +/- 500

< 13.5

< 12.5

< 12.7

<20.4

< 15.4

< 18.0 CAVE-1185 5/9/2023 Chinese Lettuce 3644 +/- 267

< 9.6

< 7.3

< 6.7

< 8.1

< 9.6

< 6.0 CAVE-1187 5/9/2023 Lettuce 3791 +/- 392

<19.5

<11.7

<8.6

<22.2

<15.4

<15.6 CAVE-1518 6/5/2023 Kale 6208

+/- 625

< 20.8

< 28.9

< 17.7

< 48.7

< 24.4

< 15.7 CAVE-1519 6/5/2023 Swiss Chard 5924

+/- 557

< 21.0

< 15.9

< 17.4

< 22.4

< 19.6

< 23.7 CAVE-1520 6/5/2023 Cabbage 5833

+/- 369

< 12.4

< 7.4

< 3.5

< 14.0

< 77.3

< 9.0 CAVE-1805 7/4/2023 Cabbage 5747 +/-651

<14.1

<11.9

<77.9

<50.1

<22.3

<32.3 CAVE-I 806 7/4/2023 Swiss Chard 7061

+/- 420

< 6.9

< 6.0

< 20.9

< 20.5

< 1 1.6

< 19.9 CAVE-1807 7/4/2023 Kale 6225

+/- 449

< 13.0

< 18.1

<27.7

<20.4

< 16.8

<21.7 CAVE-2289 7/31/2023 Chinese Cabbage 4603

+/- 479

< 16.8

< 13.3

< 31.9

< 58.6

< 17.4

< 28.7 CAVE-2290 7/31/2023 Swiss Chard 4757

+/- 407

< 12.8

< 12.4

< 24.2

< 19.1

< 13.7

< 20.4 CAVE-2291 7/31/2023 Kale 4902

+/- 546

< 12.8

< 10.3

< 30.8

< 40.8

< 17.2

< 24.5 CAVE-2628 9/6/2023 Swiss Chard 5630

+/- 848

< 24.4

< 18.9

< 37.1

< 19.9

< 28.3

< 31.7 CAVE-2629 9/6/2023 Kale 4406

+/- 838

< 44.2

< 19.1

< 22.5

< 25.7

< 35.6

< 32.5 CAVE-3003 10/2/2023 Swiss Chard 7356

+/- 892

< 35.2

< 45.3

< 19.4

< 38.9

< 30.3

< 29.6 Location: CA-FPL-V1 9 April 23 NSa CAVE-1188 5/8/2023 Lettuce 4886

+/- 483

< 20.7

< 9.1

< 21.5

< 21.9

< 18.1

< 24.1 CAVE-7521 6/6/2023 Lettuce 7456

+/- 394

< 14.6

< 12.2

< 28.7

< 58.7

< 15.6

< 22.7 CAVE-1808 7/5/2023 Cabbage 3655

+/- 329

<7.1

< 10.8

< 18.7

<20.8

< 11.0

< 17.3 CAVE-2292 7/31/2023 Cabbage 2704 +/-328

<6.0

<10.0

<21.3

<16.0

<13.1

<15.5 CAVE-2624 9/5/2023 Lettuce 6124

+/- 324

< 11.1

< 10.9

< 12.2

< 12.8

< 16.4

< 11.9 CAVE-2997 10/3/2023 Lettuce 5032 +/-597

<23.5

<19.7

<51.1

<44.8

<24.6

<40.3 a NS = No sample; see Part I Table 5.5 Missed Collections and Analyses (CR#202320405).

3-2

Table 3. Vegetation, analyses for iodine-131 and gamma-emitting isotopes.

Collection:

Monthly, dung growing season Units:

pCi/kg wet Collection Concentration (pCi/kg wet)

Lab Code Date Sample Type 40K 54Mn 58Co 60Co 1311 134Cs 137Cs Location: CA-FPL-V20 April 23 NSa CAVE-1789 5/8/2023 Mustard Greens 3002

+/- 327

< 10.7

< 8.0

< 5.6

< 23.3

< 13.0

< 14.1 CAVE-1522 6/6/2023 Kale 3022

+/- 274

< 9.0

< 10.7

< 20.5

< 15.3

< 10.3

< 19.1 CAVE-1523 6/6/2023 Cabbage 2592

+/- 304

< 9.6

< 10.3

< 6.9

< 17.8

< 14.2

< 11.5 CAVE-1524 6/6/2023 Mustard Greens 6334

+/- 458

< 18.2

< 12.8

< 6.7

< 24.7

< 14.3

< 11.2 CAVE-1525 6/6/2023 Swiss Chard 4516

+/- 514

< 24.6

< 19.3

< 13.0

< 31.6

< 20.9

< 25.6 CAVE-1527 6/6/2023 Lettuce 4283

+/- 408

< 18.9

< 10.5

< 17.3

< 17.9

< 16.2

< 17.5 CAVE-1809 7/5/2023 Kale 4146

+/- 377

< 16.0

< 9.9

< 24.7

< 19.6

< 13.8

< 25.1 CAVE-1810 7/5/2023 Swiss Chard 4074

+/- 340

< 7.5

< 10.5

< 19.1

< 20.8

< 12.4

< 16.7 CAVE-1811 7/5/2023 Cabbage 2510

+/- 402

< 18.0

< 11.9

< 12.0

< 16.6

< 16.8

< 16.8 CAVE-1812 7/5/2023 Lettuce 6155

+/- 426

< 12.0

< 11.2

< 24.0

< 14.2

< 14.5

< 23.1 CAVE-1813 7/5/2023 Mustard Greens 5409

+/- 485

< 23.1

< 23.5

< 15.9

< 28.6

< 19.0

< 17.9 CAVE-2293 7/31/2023 Cabbage 1738 +/-279

<8.1

<11.7

<21.6

<28.7

<14.4

<19.6 CAVE-2294 7/31/2023 Collard Greens 1938

+/- 356

< 18.7

< 17.1

< 20.1

< 41.6

< 20.4

< 25.8 CAVE-2295 7/31/2023 Kale 5582

+/- 726

< 23.3

< 23.1

< 16.3

< 29.2

< 27.4

< 28.5 CAVE-2296 7/31/2023 Swiss Chard 4942

+/- 477

< 9.9

< 13.7

< 25.3

< 21.3

< 16.7

< 22.1 CAVE-2630 9/3/2023 Swiss Chard 7288

+/- 672

< 17.5

< 18.0

< 32.7

< 22.2

< 20.0

< 31.8 CAVE-2631 9/6/2023 Collard Greens 5304

+/- 663

< 24.3

< 13.1

< 41.7

< 21.7

< 23.0

< 37.5 CAVE-2632 9/5/2023 Poke 9876

+/- 1054

< 22.9

< 20.1

< 22.1

< 20.1

< 34.4

< 21.5 CAVE-2633 9/6/2023 Cabbage 2481

+/- 583

< 31.5

< 27.5

< 17.2

< 22.6

< 27.6

< 25.2 CAVE-2634 9/6/2023 Kale 6375

+/- 116

< 25.6

< 27.4

< 26.7

< 30.6

< 38.1

< 41.8 CAVE-3004 10/3/2023 Kale 4387

+/- 572

< 10.6

< 8.4

< 31.6

< 35.8

< 23.0

< 34.4 CAVE-3005 10/3/2023 Poke 9544

+/- 1039

< 42.7

< 29.9

< 29.2

< 43.2

< 38.0

< 21.9 CAVE-3006 10/3/2023 Collard Greens 2882

+/- 395

< 11.9

< 10.7

< 25.4

< 16.6

< 16.8

< 21.6 a NS = No sample; see Part I Table 5.5 Missed Collections and Analyses (CR#202320405).

3-3

Table 4.

Soil, analyses for gamma-emitting isotopes.

Collection:

Annually Collection Concentration (pCi/kg dry)

Lab Code Date 40K 54Mn 59Fe 58Co 60Co 95ZrNb 134Cs 37Cs 140BaLa Location: SOL-F-002 CASO-3932 12/13/2023 11786

+/- 285

< 12.4

< 29.7

< 14.0

< 16.2

< 26.8

< 11.4 187 +/- 17

< 105.0 Location: SOL-F-006 CASO-3933 12/13/2023 10426 +/-276

<12.2

<34.0

<13.3

<10.4

<28.0

<9.7 281 +/- 13

<110.6 Location: SOL-PR-003 CASO-3934 12/13/2023 10381

+/-282

<12.1

<31.3

<14.0

<11.2

<22.9

<9.3 255+/- 12

<109.2 Location: SOL-PR-007 CASO-3935 12/13/2023 10350

+/- 729

<29.0

<46.7

<41.8

<44.6

<69.0

<29.0 163 +/- 45

< 186.8 Location: SOL-M-009 CASO-3939 12/13/2023 10618

+/- 633

< 30.5

< 73.7

< 34.4

< 37.1

< 59.4

< 25.4

< 31.0

< 165.7 Location: SOL-W-001 CASO-3936 12/15/2023 8332

+/- 627

< 24.3

< 40.6

< 20.7

< 17.1

< 44.7

< 21.4

< 26.8

< 105.5 Location: SOL-W-002 CASO-3937 12/15/2023 14870

+/- 673

< 28.9

< 76.5

< 42.4

< 32.2

< 66.0

< 25.4

< 28.9

< 315.8 Location: SOL-W-005 CASO-3938 12/15/2023 15748

+/- 753

< 25.2

< 72.3

< 28.0

< 26.7

< 55.3

< 24.4 47 +/- 25

< 256.0 Location: SOL-W-006 CASO-3940 12/13/2023 13047

+/- 623

< 25.0

< 72.4

< 28.5

< 12.6

< 54.4

< 19.6 92 +/- 19

< 136.2 4-1

Table 5.

Surface water, analyses for tritium and gamma-emitting isotopes.

Collection:

Monthly Location:

CA-SWA-SOl Units:

pCi/L Lab Code Requited CASW-21 1 CASW-407 CASW-694 CASW-I 005 Date Collected LLD 01-31-23 02-27-23 03-28-23 04-25-23 H-3 3000

< 160

< 163

< 174

< 167 Mn-54 15

< 0.9

< 5.0

< 3.2

< 2.8 Fe-59 30

< 2.2 11.6

< 7.5 3.4 Co-58 15

< 0.9 5.1

< 4.9

< 2.6 Co-60 15 1.1

< 4.0

< 2.2

< 5.6 Zn-65 30

< 2.6 5.5 8.1

< 6.2 Zt-Nb-95 15 1.2 3.5

< 6.0

< 3.0

-131 1000 1.3 5.0

< 4.9

< 7.0 Cs-134 15 1.0

< 5.2

< 4.3

< 3.0 Cs-137 18 1.0

< 3.2

< 4.2

< 4.7 Ba-La-140 15 1.3

< 3.4

< 5.5

< 4.7 Lab Code Requited CASW-1355 CASW-1748 CASW-2220 CASW-2600 Date Collected LLD 05-30-23 06-27-23 07-25-23 08-29-23 H-3 3000

< 157

< 158

< 161

< 160 Mn-54 15

< 3.5 3.0

< 2.4

< 6.3 Fe-59 30 5.1

< 3.7

< 2.9 10.0 Co-58 15

< 2.2 3.3

< 2.9

< 6.3 Co-60 15

< 6.5

< 6.8

< 6.7

< 5.8 Zn-65 30

< 2.4

< 2.9

< 3.3

< 6.9 Zt-Nb-95 15

< 2.5 3.1

< 3.5

< 6.0 1-131 1000

< 3.8

< 4.2

< 8.2

< 8.3 Cs-134 15

< 3.8 3.5 3.1

< 8.4 Cs-137 18

< 5.8 5.6

< 5.4

< 5.3 Ba-La-140 15

< 3.4

< 3.0

< 4.1

< 6.3 Lab Code Requited CASW-2885 CASW-3400 CASW-3749 CASW-3966 Date Collected LLD 09-26-23 10-31-23 11-28-23 12-26-23 H-3 3000

< 167

< 171

< 173

< 171 Mn-54 15

< 2.0 3.2

< 2.8

< 5.9 Fe-59 30

< 3.9

< 4.8

< 3.6 5.1 Co-58 15

< 2.7 1.9

< 2.2

< 4.7 Co-60 15

< 6.1 3.1

< 6.2

< 4.5 Zn-65 30

< 3.9 3.9

< 7.5 12.1 Zt-Nb-95 15

< 3.4

< 2.0

< 5.7

< 3.7

-131 1000

< 3.5

< 3.0

< 6.7

< 5.9 Cs-134 15

< 2.8

< 2.4

< 4.6

< 5.5 Cs-137 18

< 6.0

< 2.5

< 6.8

< 5.0 Ba-La-140 15

< 3.4

< 2.9

< 2.2

< 4.2 5-1

Table 5.

Surface water, analyses for tritium and gamma-emitting isotopes.

Collection:

Monthly Location:

CA-SWA-S02 Units:

pCi/L Lab Code Required CASW-212 CASW-408 CASW-695 CASW-1006 Date Collected LLD 01-31-23 02-27-23 03-28-23 04-25-23 H-3 3000

< 160

< 163

< 174 469 +/- 107 Mn-54 15

< 0.8

< 2.4 1.3

< 2.9 Fe-59 30

< 2.9

< 7.5

< 2.3

< 4.4 Co-58 15 1.4

< 2.8

< 0.8

< 2.5 Co-60 15

< 2.8 1.8 1.3

< 7.6 Zn-65 30

< 2.8

< 3.4

< 2.4

< 5.0 Zr-Nb-95 15 1.4 1.7 1.5

< 2.1 1-131 1000

< 2.2

< 2.5 1.7 11.1 Cs-134 15 1.3

< 3.4 1.0

< 3.4 Cs-137 18

< 2.5

< 2.9 1.2

< 5.9 Ba-La-140 15 1.2

< 4.3 1.4

< 4.7 Lab Code Required CASW-1356 CASW-1749 CASW-2222 CASW-2601 Date Collected LLD 05-30-23 06-27-23 07-25-23 08-29-23 H-3 3000 380 +/-94 b

641 +/- 107 562 +/- 105 1163 +/- 130 Mn-54 15

< 2.5

< 5.7

< 6.7

< 2.7 Fe-59 30

< 4.4

< 4.9

< 9.7

< 4.9 Co-58 15 1.6 3.1

< 4.5

< 4.3 Co-60 15

< 2.0

< 5.2

< 4.1 9.1 Zn-65 30

< 4.6

< 7.8

< 4.7

< 6.7 Zr-Nb-95 15

< 2.3

< 5.2

< 5.2

< 4.6

-131 1000

< 2.7

< 4.4

< 9.9

< 4.7 Cs-134 15

< 2.6

< 5.5

< 6.2

< 5.5 Cs-137 18

< 2.8

< 6.2

< 4.9

< 7.7 Ba-La-140 15 1.3

< 3.9

< 3.6

< 5.4 Lab Code Required CASW-2773 U

CASW-2886 CASW-3401 CASW-3750 Date Collected LLD 08-29-23 09-26-23 10-31-23 1 1-28-23 H-3 3000 925 +/- 120 471 +/- 101 395 +/- 100 205 +/- 92 Mn-54 15 1.1

< 5.5

< 2.5

< 3.3 Fe-59 30

< 2.8

< 9.3

< 4.3

< 4.4 Co-58 15 1.2

< 6.1 1.5

< 2.4 Co-60 15

< 2.6

< 4.5

< 2.2

< 2.1 Zn-65 30

< 2.1

< 7.8

< 3.9

< 5.2 Zr-Nb-95 15 1.2

< 6.6

< 2.6

< 2.3 1-131 1000

< 5.7

< 8.4

< 2.9

< 6.1 Cs-134 15 1.4

< 6.5

< 2.4

< 2.2 Cs-137 18

< 2.3

< 3.9

< 2.9

< 3.6 Ba-La-140 15

< 3.9

< 8.4

< 2.3

< 4.2 a Recount = 418 +/- 108 pCi/L.

C Recount = I 166 +/- 136 pCi/L. Reanalysis 1062 +/- 132 pCi/L.

b Duplicate = 257 +/- 88 pCi/L.

d Backup sample 5-2

Table 5.

SurIace water, analyses for tritium and gamma-emitting isotopes.

Collection:

Monthly Location:

CA-SWA-S02 Units:

pCi/L Lab Code Required CASW-3967 Date Collected LLD 12-26-23 H-3 3000

< 171 Mn-54 15

< 2.5 Fe-59 30

< 5.2 Co-58 15

< 2.5 Co-60 15

< 2.0 Zn-65 30

< 4.8 Zr-Nb-95 15

< 2.5

-131 1000

< 4.6 Cs-134 15

< 2.7 Cs-137 18

< 2.2 Ba-La-140 15

< 4.0 5-3

6. Surface Water (Ponds), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H 54Mn 59Fe 58Co 60Co 65Zn 95ZrNb 34Cs 137Cs 140BaLa Location: CA-SWA-POND 01 CASW-656 03/27/23

< 174

< 2.2

< 5.3

< 2.2

< 1.9

< 5.5

< 2.0

< 3.1

< 3.8

< 1.5 CASW-2670 09/05/23

< 163

< 7.7

< 8.2

< 8.3

< 4.8

< 17.0

< 74

< 8.1

< 4.4

< 7.1 Location: CA-SWA-POND 02 CASW-657 03/27/23

< 174

< 3.3

< 6.2

< 3.4

< 7.4

< 4.4

< 3.8

< 3.9

< 6.2

< 2.8 CASW-2671 09/05/23

< 163

< 5.3

< 11.6

< 4.6

< 4.2

< 10.8

< 6.3

< 6.3

< 7.2

< 3.2 Location: CA-SWA-SLU DGE LAGOON #5 CASW-662 03/27/23

<174

<1.2

<2.5

<1.5

<2.9

<2.3

<1.7

<1.4

<2.3

<1.2 CASW-2675 09/05/23

< 163

< 3.9

< 3.2

< 3.9

< 7.2

< 4.5

< 3.1

< 4.0

< 6.9

< 5.9 Location: CA-SWA-OUTFALL 010 CASW-658 03/27/23

< 174

< 2.2

< 5.3

< 2.2

< 1.9

< 5.5

< 2.0

< 3.1

< 3.8

< 1.5 CASW-2674 9/5/2023

< 163

< 7.7

< 15.8

< 5.8

< 4.7

< 8.4

< 8.0

< 8.2

< 9.9

< 6.1 Location: CA-SWA-WETLANDS 01 CASW-660 03/27/23

< 174

< 4.2

< 2.7

< 4.9

< 1.9

< 4.0

< 2.1

< 4.7

< 3.1

< 4.2 CASW-2672 9/5/2023

< 163

< 2.4

< 4.8

< 3.2

< 7.0

< 6.4

< 4.3

< 3.6

< 5.6

< 3.5 Location: CA-SWA-WETLANDS 02 CASW-661 03/27/23

< 174

< 4.1

< 4.2

< 2.2

< 7.5

< 6.1

< 2.5

< 3.5

< 6.8

< 2.6 CASW-2673 9/5/2023

< 163

< 3.0

< 3.8

< 3.9

< 8.6

< 6.5

< 3.6

< 5.1

< 7.7

< 3.1 6-1

Table 7.

Drinking Water Wells, analysis for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H 54Mn 59Fe 58Co 60Co 65Zn 95ZrNb 134Cs 137Cs 140BaLa CA-DWA-003 (Ward)

CADW-306 2/6/2023

< 154

< 1.2

< 4.1

< 2.2

< 1.8

< 4.7

< 37

< 2.4

< 2.5

< 2.3 CADW-I 133 5/2/2023

< 162

< 2.9

< 3.2

< 2.0

< 2.2

< 7.2

< 3.3

< 3.9

< 2.5

< 4.8 CADW-2223 7/25/2023

< 159

< 2.2

< 2.4

< 1.6

< 8.0

< 4.3

< 3.9

< 4.9

< 6.3

< 4.7 CADW-3483 11/7/2023

< 171

<2.0

<4.4

< 1.7

<3.5

<4.9

<2.5

<2.7

<2.9

<3.6 CA-DWA-004 (Miller)

CADW-319 2/7/2023

< 160

< 1.7

< 3.6

< 1.5

< 0.8

< 2.5

< 1.2

< 1.5

< 1.7

< 2.1 CADW-1132 5/2/2023

< 162

< 2.0

< 5.8

< 1.5

< 1.7

< 4.8

< 3.1

< 3.0

< 3.3

< 2.1 CADW-2236 7/26/2023

< 159

< 4.2

< 3.1

< 2.9

< 7.1

< 5.2

< 2.7

< 3.6

< 7.3

< 4.0 CADW-3484 11/6/2023

< 171

<2.3

<4.4

< 1.9

<5.5

<6.0

<5.2

<3.4

<5.1

<2.6 CA-DWA-005 (Brucker Bros.)

CADW-307 2/6/2023

< 154

< 2.8

< 3.7

< 2.2

< 2.8

< 5.4

< 2.5

< 2.0

< 2.3

< 3.0 CADW-1145 4/25/2023

< 162

<2.4

<4.4

< 1.9

<2.0

<5.0

<3.6

<2.3

<3.0

<2.9 CADW-2224 7/25/2023

< 159

< 6.1

< 5.9

< 5.9

< 5.2

< 6.5

< 4.4

< 7.4

< 3.9

< 6.7 CADW-3485 11/6/2023

< 171

< 1.6

< 4.3

< 2.7

< 2.8

< 1.4

< 2.1

< 2.5

< 2.6

< 3.5 CA-DWA-007 (Kriete)

CADW-308 2/6/2023

< I 54

< 2.6

< 5.5

< 2.3

< 2.5

< 5.2

< 3.9

< 2.5

< 3.0

< 1.9 CADW-I 130 5/2/2023

< 162

< 2.1

< 4.3

< 4.0

< 7.5

< 4.5

< 2.9

< 3.3

< 6.2

< 3.7 CADW-2225 7/25/2023

< 159

<3.8

<6.1

< 1.9

<7.7

<7.0

<4.2

<4.2

<7.0

<2.9 CADW-3486 1 1/7/2023

< I 71

< I.8

< 3.9

< 1.6

< 4.7

< 5.4

< 3.7

< 3.0

< 4.6

< 3.1 CA-DWA-008 (Curry)

CADW-321 2/6/2023

< 154

< 3.2

< 4.1

< 1.9

< 2.5

< 5.3

< 2.1

< 3.4

< 3.6

< 4.5 CADW-1134 5/2/2023

< 162

<2.5

<4.5

<3.0

<5.7

<4.6

<3.2

<3.1

<4.8

<2.4 CADW-2237 7/26/2023

< 159

< 5.5

< 7.2

< 5.0

< 3.6

< 3.8

< 4.9

< 5.3

< 5.5

< 5.0 CADW-3487 11/7/2023

< 171

< 1.9

< 4.0

< 1.7

< 3.2

< 4.8

< 3.5

< 2.4

< 2.7

< 3.4 7-1

Table 7.

Drinking Water Wells, analysis for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H Mn Fe Co Co Zn ZrNb 4Cs 1Cs 14BaLa CA-DWA-009 (Clardy)

CADW-310 2/6/2023

< 154

< 2.6

< 7.0

< 3.6

< 6.3

< 4.8

< 2.3

< 3.3

< 5.4

< 3.7 CADW-I 136 5/2/2023

< 162

< 2.5

< 2.6

< 1.8

< 6.3

< 5.9

< 2.8

< 2.9

< 5.0

< 2.7 CADW-2226 7/25/2023

< 159

< 7.2

< 12.3

< 6.1

< 4.2

< 4.8

< 6.3

< 7.2

< 4.7

< 5.7 CADW-3488 11/7/2023

< 171

< 2.5

< 3.8

< 2.2

< 1.3

< 4.2

< 2.8

< 2.7

< 2.3

< 3.0 CA-DWA-010 (Dillon, Susan)

CADW-311 2/6/2023

<154

<1.9

<4.2

<2.9

<6.6

<5.2

<2.8

<3.4

<5.1

<3.6 CADW-I 137 5/2/2023

< 162

< 3.5

< 5.6

< 2.6

< 3.9

< 8.9

< 5.3

< 4.2

< 3.5

< 6.6 CADW-2227 7/25/2023

< I 59

< 1.7

< 2.4

< 2.6

< 6.2

< 3.0

< 2.7

< 3.2

< 4.9

< 2.2 CADW-3489 11/7/2023

< 171

<3.1

<4.5

<2.6

<4.5

<3.7

<2.5

<2.4

<4.8

<2.1 CA-DWA-012 (Dillon, Joe)

CADW-312 2/6/2023

< 154

< 0.9

< 2.2

< 1.0

< 1.3

< 2.6

< 1.6

< 1.1

< 1.3

< 1.9 CADW-1 138 5/2/2023

< 162

< 2.6

< 2.3

< 2.8

< 6.7

< 4.8

< 3.1

< 3.0

< 5.1

< 4.7 CADW-2228 7/25/2023

< 159

< 5.1

< 8.8

< 5.5

< 4.2

< 6.4

< 5.8

< 5.0

< 4.0

< 3.7 CADW-3490 11/7/2023

< 171

< 1.5

<4.0

< 1.4

< 1.3

<4.3

<2.8

<2.4

<2.4

<3.6 CA-DWA-21 CADW-314 2/6/2023

< 154

< 1.9

< 4.7

< 2.6

< 2.5

< 2.7

< 3.4

< 2.1

< 1.7

< 2.0 CADW-1 131 5/2/2023

< 162

< 3.5

< 4.0

< 2.7

< 6.6

< 4.2

< 2.4

< 3.2

< 5.7

< 2.3 CADW-2229 7/25/2023

< 159

< 3.0

< 3.5

< 2.7

< 7.0

< 3.7

< 3.5

< 3.8

< 6.0

< 5.1 CADW-3491 11/7/2023

< 171

<2.0

<4.3

<2.7

<3.2

<3.1

<2.0

<2.1

<2.8

<3.8 CA-DWA-022 (Pummer)

CADW-315 2/6/2023

< 154

<2.7

<5.5

<2.2

< 1.3

<2.6

<4.5

<4.1

<3.1

<5.3 CADW-1139 5/2/2023

< 162

< 4.2

< 4.1

< 4.1

< 1.5

< 6.0

< 2.3

< 3.6

< 3.1

< 4.8 CADW-2230 7/25/2023

< 159

< 7.3

< 9.6

< 4.2

< 4.6

< 8.6

< 8.5

< 6.2

< 5.2

< 4.3 CADW-3492 11/7/2023

< 171

<3.0

<6.6

<3.0

<3.9

<3.9

<4.6

<3.5

<3.5

<5.2 7-2

Table 7.

Drinking Water Wells, analysis for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H Mn 59Fe 58Co 60Co 65Zn 95ZrNb 14Cs 131Cs 140BaLa CA-DWA-PW1 (Plant Cafeteria)

CADW-320 2/7/2023

< 160

< 3.7

< 5.3

< 3.4

< 3.6

< 3.0

< 3.7

< 3.5

< 3.9

< 4.3 CADW-1143 5/2/2023

< 162

<3.2

<2.2

< 1.5

<5.9

<4.8

<2.9

<2.8

<4.9

<2.3 CADW-2238 7/26/2023

< 159

< 2.1

< 4.2

< 3.3

< 6.8

< 5.7

< 3.9

< 4.0

< 5.6

< 3.8 CADW-3498 1 1/7/2023

< 171

< 2.6

< 3.4

< 2.6

< 5.4

< 2.9

< 2.2

< 2.9

< 4.3

< 2.8 CA-DWA-V1 6 CADW-318 2/7/2023

< 154

< 6.0

< 6.9

< 3.2

< 4.0

< 8.8

< 3.9

< 5.9

< 5.7

< 3.9 CADW-1 142 5/2/2023

< 162

< 2.4

< 3.8

< 2.2

< 4.5

< 4.2

< 2.6

< 2.3

< 4.0

< 3.2 CADW-2234 7/25/2023

< 159

< 3.5

< 3.7

< 2.2

< 7.2

< 5.8

< 4.5

< 4.1

< 5.8

< 4.5 CADW-3496 11/7/2023

< 171

< 2.6

< 3.2

< 2.6

< 2.0

< 3.8

< 3.1

< 2.5

< 3.0

< 3.5 CA-DWA-D23 CADW-316 2/6/2023

< 154

< 3.6

< 8.2

< 1.9

< 1.9

< 5.6

< 2.5

< 3.9

< 3.1

< 5.0 CADW-1140 5/2/2023

<162

<2.0

<3.3

<3.5

<6.7

<3.0

<1.8

<3.1

<5.1

<3.1 CADW-2231 7/25/2023

< 159

< 2.2

< 3.9

< 1.5

< 4.9

< 4.6

< 2.9

< 2.8

< 4.5

< 3.1 CADW-3493 1 1/7/2023

< 171

< 4.4

< 4.0

< 3.5

< 4.0

< 5.1

< 4.8

< 4.2

< 4.4

< 3.1 CA-DWA-024 CADW-317 2/6/2023

< 154

< 2.8

< 3.4

< 1.2

< 6.4

< 2.4

< 3.5

< 3.0

< 5.0

< 3.6 CADW-1135 5/2/2023

< 162

< 2.4

< 4.1

< 2.7

< 2.5

< 4.8

< 2.6

< 2.5

< 2.5

< 1.7 CADW-2232 7/25/2023

< 159

< 5.5

< 5.4

< 3.8

< 4.2

< 9.3

< 3.1

< 4.9

< 2.7

< 5.2 CADW-3494 11/7/2023

< 171

< 1.3

< 3.9

< 1.4

< 1.5

< 5.5

< 1.8

< 2.3

< 2.2

< 3.1 CA-DWA-025 CADW-322 2/9/2023

< 160

< 6.6

< 5.9

< 6.0

< 3.6

< 8.5

< 3.6

< 6.2

< 5.3

< 8.8 CADW-1129 5/2/2023

< 162

< 2.3

< 4.3

< 2.5

< 4.9

< 5.3

< 3.2

< 2.5

< 3.7

< 2.0 CADW-2233 7/25/2023

< 159

< 2.5

< 6.9

< 3.8

< 8.2

< 5.7

< 4.4

< 4.7

< 7.2

< 7.1 CADW-3495 11/7/2023

< 171

< 2.0

< 4.6

< 1.7

< 2.6

< 3.3

< 1.8

< 2.1

< 2.7

< 3.6 CA-DWA-V19 (Dillon, Amy)

CADW-313 2/6/2023

<154

<6.3

<8.8

<5.3

<5.3

<11.6

<5.5

<5.7

<4.9

<7.1 CADW-1 141 5/2/2023

< 162

< 2.7

< 2.8

< 2.9

< 2.8

< 4.8

< 3.7

< 3.4

< 3.7

< 6.2 CADW-2235 7/25/2023

< 159

< 5.6

< 5.6

< 5.3

< 5.8

< 8.0

< 10.0

< 7.3

< 5.1

< 5.0 CADW-3497 11/7/2023

< 171

< 2.6

< 5.2

< 1.5

< 2.8

< 2.9

< 2.4

< 2.1

< 3.3

< 4.0 7-3

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCiIL)

Lab Code Date 3H 54Mn 59Fe 58Co 60Co 65Zn 95ZrNb 134Cs 137Cs 140BaLa Location: CA-WWA-937B CAWW-53 1/9/2023

< 161

< 1.7

< 2.5

< 1.3

< 1.4

< 3.2

< 1.6

< 1.5

< 1.8

< 1.9 CAWW-350 2/13/2023

< 160

< 1.9

< 2.5

< 1.4

< 0.8

< 3.4

< 2.0

< 1.6

< 1.6

< 2.8 CAWW-589 3/15/2023

< 164

< 2.3

< 3.7

< 2.0

< 5.4

< 4.3

< 1.9

< 2.8

< 4.7

< 2.9 CAWW-888 4/11/2023

< 161

< 2.8

< 6.4

< 4.2

< 1.9

< 8.1

< 3.2

< 3.5

< 2.0

< 4.6 CAWW-1293 5/15/2023

< 161

< 1.0

< 1.9

< 1.3

< 0.9

< 2.6

< 1.5

< 1.0

< 1.3

< 2.4 CAWW-1616 6/12/2023

< 162

< 6.1

< 12.5

< 5.4

< 2.8

< 3.7

< 3.8

< 5.0

< 4.7

< 7.9 CAWW-2001 7/12/2023

< 163

< 5.8

< 6.4

< 4.0

< 5.6

< 8.7

< 7.3

< 6.5

< 7.2

< 7.7 CAWW-2471 8/14/2023

< 158

< 8.2

< 7.9

< 4.7

< 8.1

< 7.5

< 7.5

< 7.5

< 3.9

< 5.2 CAWW-2719 9/11/2023

< 163

< 2.8

< 5.0

< 2.4

< 9.3

< 6.2

< 5.2

< 6.7

< 9.4

< 4.9 CAWW-3255 10/17/2023

< 169

< 6.2

< 5.1

< 4.2

< 4.5

< 12.0

< 7.4

< 9.4

< 6.2

< 4.5 CAWW-3590 11/14/2023

< 172

< 1.6

< 7.0

< 2.9

< 2.9

< 2.4

< 2.2

< 3.3

< 3.5

< 5.2 CAWW-3905 12/11/2023

< 171

< 3.8

< 5.2

< 3.1

< 1.6

< 6.8

< 3.7

< 4.2

< 4.0

< 3.1 Location: CA-WWA-937D CAWW-54 1/9/2023 210 +/- 91

< 2.3

< 3.2

< 2.0

< 1.7

< 4.3

< 2.2

< 2.2

< 2.5

< 4.1 CAWW-355 2/13/2023 242 +/- 92

< 0.7

< 2.6

< 1.1

< 1.1

< 2.7

< 1.4

< I.1

< I.4

< 0.9 CAWW-587 3/15/2023 294 +/- 95

< 2.8

< 3.7

< 2.3

< 2.4

< 5.9

< 3.0

< 2.4

< 2.6

< 1.7 CAWW-889 4/11/2023 242 +/-89

<2.2

<4.2

<2.9

<7.0

<5.1

<3.2

<3.6

<6.0

<4.1 CAWW-1294 5/15/2023 233 +/- 93

< 1.1

< 2.2

< 1.6

< 2.8

< 2.2

< 1.5

< 1.3

< 2.2

< 1.9 CAWW-1617 6/12/2023 302 +/- 101

< 2.2

< 5.1

< I.4

< 5.0

< 3.6

< 2.3

< 2.5

< 4.1

< 3.6 CAWW-2002 7/12/2023 179 +/- 86

< 5.7

< 11.1

< 5.1

< 4.0

< 5.1

< 5.8

< 4.7

< 5.0

< 8.4 CAWW-2473 8/14/2023 21 1 +/- 88

< 5.9

< I I.4

< 5.4

< 7.1

< 7.6

< 6.6

< 7.1

< 6.8

< 3.5 CAWW-2717 9/11/2023

< 163

< 3.8

< 4.9

< 2.4

< 8.3

< 4.1

< 4.0

< 4.3

< 7.0

< 3.2 CAWW-3256 10/17/2023

<169

<3.1

<4.1

<2.2

<7.8

<3.4

<4.3

<5.1

<7.1

<2.9 CAWW-3591 11/14/2013

< 172

< 2.2

< 6.1

< 2.1

< 5.6

< 5.5

< 3.6

< 3.4

< 5.1

< 3.2 CAWW-3900 12/11/2023

< 171

< 3.2

< 5.8

< 3.6

< 3.3

< 3.5

< 4.0

< 3.5

< 3.7

< 4.2 8-1

Table 8. Wells (non-potable). analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCiIL)

Lab Code Date 3H Mn 5Fe Co bCo bbZn ZrNb 1Cs 1Cs 1°BaLa Location: CA-WWA-939R CAWW-55 1/10/2023 622+/-JJO

<0.9

<2.5

<1.0

<1.1

<27

<1.6

<1.1

<1.2

<1.2 CAWW-356 2/14/2023 378 +/- 94

< I.2

< 2.8

< I.4

< 2.7

< 2.9

< I.6

< 1.4

< 2.3

< I.6 CAWW-588 3/15/2023 1109 +/- 129

< 3.2

< 4.5

< 2.5

< 2.6

< 7.5

< 4.1

< 3.4

< 3.3

< 4.4 CAWW-884 4/11/2023 817 +/- 116

< 1.9

< 3.5

< IA

< 0.7

< 2.7

< 1.8

< 1.6

< 1.4

< 1.9 CAWW-1295 5/1512D23 708 +/- 115

< 2.4

< 3.6

< 2.1

< 1.8

< 5.9

< 2.1

< 2.5

< 2.8

< 4.3 CAWW-1618 6/12/2023 760 +/- 121

< 1.2

< 2.8

< 1.1

< 2.8

< 2.7

< 1.0

< 1.3

< 2.3

< 1.5 CAWW-2003 7/12/2023 791 +/- I 15

< 2.9

< 3.5

< 3.3

< 5.9

< 4.6

< 3.0

< 3.1

< 5.3

< 3.4 CAWW-2474 8/14/2023 947 +/- 122

< 2.1

< 4.2

< 3.2

< 9.3

< 3.8

< 3.9

< 4.6

< 7.7

< 2.7 CAWW-2718 9/1 1/2023 768 +/- 1 13

< 8.7

< 8.4

< 6.8

< 5.9

< 1 1.8

< 4.7

< 8.1

< 6.0

< 4.1 CAWW-3257 10/17/2023 614 +/- 109

< 6.7

< 6.5

< 8.6

< 5.0

< 8.8

< 10.4

< 9.2

< 6.8

< 5.7 CAWW-3592 11/14/2023 526 +/- 108

< 2.6

< 5.3

< 1.7

< 1.8

< 4.5

< 2.6

< 2.6

< 2.0

< 3.9 CAWW-3902 12/11/2023 859 +/- 120

< 2.9

< S.D

< 1.9

< 2.6

< 4.4

< 2.1

< 4.6

< 3.2

< 3.D Location: CA-WWA-94D CAWW-52 1/9/2D23 222 +/- 92

< I.D

< 2.2

< D.9

< 2.8

< 2.3

< I.8

< I.4

< 2.3

< D.9 CAWW-353 2/13/2D23 221 +/- 86

< 5.3

< 6.9

< 5.4

< 3.5

< 9.3

< 6.6

< 6.1

< 3.7

< 5.2 CAWW-591 3/15/2D23 218 +/- 91

< 2.7

< 4.4

< 2.9

< 2.9

< 6.2

< 5.7

< 3.D

< 4.2

< 4.7 CAWW-886 4/1 1/2D23 2D6 +/- 87

< 3.4

< 5.1

< 3.8

< I.6

< 4.6

< 3.7

< 4.D

< 3.D

< 4.3 CAWW-1296 5/15/2D23 178 +/- 9D

< 2.D

< S.D

< 3.7

< 6.6

< 5.1

< 2.9

< 3.2

< 5.1

< 4.D CAWW-1619 6/12/2D23 223 +/- 97

< 5.8

< 6.8

< 5.2

< 4.9

< 4.5

< 4.1

< 5.1

< 4.7

< 4.4 CAWW-2DD4 7/12/2D23 271 +/- 91

< 6.9

< 6.9

< 4.2

< 5.1

< 7.9

< 6.4

< 6.D

< 3.8

< 5.4 CAWW-2475 8/14/2D23 23D +/- 89

< 7.5

< 1D.5

< 7.2

< 6.2

< 6.7

< 5.7

< 6.3

< 5.3

< 7.7 CAWW-2721 9/11/2D23

< 163

< 2.1

< 3.5

< 3.3

< 7.3

< 5.1

< 3.7

< 3.7

< 6.8

< 3.7 CAWW-3258 ID/17/2D23

< 169

< 2.3

< 3.5

< 3.1

< 6.6

< 4.3

< 6.D

< 4.3

< 6.8

< 3.3 CAWW-3593 11/14/2D23

< 172

< 1.8

< 5.6

< 2.5

< 5.6

< 5.8

< 3.5

< 3.4

< 5.3

< 3.4 CAWW-39D3 12/11/2D23

< 171

<2.1

<4.D

< 1.1

<4.4

<7.9

<4.3

<2.7

<3.9

<4.1 Location: CA-WWA-941 CAWW-51 1/9/2D23

< 161

<2.4

<2.5

<2.D

<2.5

<5.3

<3.2

<2.4

< 1.7

< 1.8 CAWW-354 2/13/2D23

< 154

< 1.7

< 3.4

< 3.2

< 2.8

< 4.9

< 4.1

< 2.6

< 3.3

< I.6 CAWW-592 3/1S/2D23

< 164

< 2.3

< 4.1

< 2.1

< 6.7

< 5.4

< 3.9

< 3.5

< 5.1

< 3.6 CAWW-887 4/11/2D23

< 161

< 1.8

< 5.9

< 2.3

< 2.7

< 5.1

< 2.8

< 2.5

< 1.9

< 1.6 CAWW-1297 S/15/2D23

< 175

< 5.6

< ID.4

< 4.7

< 3.8

< 7.8

< 4.4

< 5.5

< 5.6

< 8.3 CAWW-162D 6/12/2D23

< 162

< 3.2

< 5.2

< 3.8

< 7.3

< 4.2

< 3.3

< 3.1

< 5.5

< 8.6 CAWW-2005 7/12/2D23

< 163

< 2.D

< 6.5

< 3.2

< 6.7

< 4.1

< 3.4

< 3.4

< 5.7

< 3.9 CAWW-2476 8/14/2D23

< 158

< 5.2

< 4.1

< 3.6

< 8.9

< 6.1

< 2.6

< 5.6

< 8.4

< 4.3 CAWW-2722 9/11/2D23

< 163

< 7.7

< 12.5

< 4.1

< 4.D

< 12.D

< 4.6

< 7.5

< 5.6

< 4.7 CAWW-3259 ID/17/2D23

< 169

< 7.1

< 12.5

< 7.D

< 6.9

< 9.8

< 7.4

< 7.5

< 8.4

< 8.7 CAWW-3594 11/14/2D23

< 172

<2.7

<5.5

< 1.9

< 1.6

<4.7

<3.D

<3.1

<2.6

<5.1 CAWW-39D4 12/11/2D23

< 171

< 3.8

< 3.1

< 1.9

< 7.9

< 6.1

< 2.6

< 4.2

< 8.D

< 3.D 8-2

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H Mn 5Fe Co 5°Co Zn ZrNb 1Cs 11Cs 1°BaLa Location: CA-WWA-GWS CAWW-56 1/10/2023 194 +/- 90

< 0.9

< 3.8

< 2.6

< 2.3

< 5.6

< 2.6

< 2.1

< 3.0

< 3.4 CAWW-352 2/13/2023

< 154

< 2.9

< 4.0

< 3.0

< 6.1

< 5.0

< 4.2

< 3.6

< 5.0

< 2.6 CAWW-590 3/15/2023 230 +/- 92

< 2.9

< 4.9

< 2.1

< 2.3

< 4.5

< 2.1

< 2.9

< 3.0

< 3.8 CAWW-885 4/1112023 257 +/- 90

< 5.0

< 5.6

< 3.3

< 3.5

< 5.6

< 5.7

< 6.9

< 3.4

< 6.3 CAWW-1298 5/16/2023 359 +/- 99

< 3.8

< 3.5

< 2.7

< 3.0

< 4.1

< 5.4

< 3.7

< 2.6

< 5.7 CAVVW-1621 a

6/12/2023 2410 +/- 169

< 5.0

< 10.3

< 6.7

< 3.3

< 6.7

< 8.5

< 5.8

< 3.6

< 8.6 CAWW-2170 b

6/12/2023 2352 +/- 168

< 2.5

< 6.8

< 3.9

< 6.1

< 5.2

< 4.8

< 3.5

< 5.8

< 25.2 CAWW-2006 7/12/2023 1423 +/- 138

< 5.8

< 12.4

< 6.1

< 4.9

< 7.2

< 6.3

< 5.7

< 4.7

< 4.3 CAWW-2477 8/14/2023 575 +/- 106

< 8.5

< 7.3

< 3.9

< 5.3

< 13.4

< 7.2

< 10.8

< 5.1

< 6.7 CAWW-2720 9/11/2023 296 +/- 92

< 7.0

< 10.0

< 6.2

< 6.2

< 14.6

< 8.1

< 11.2

< 5.4

< 9.6 CAWW-3260 10/17/2023 1567 +/- 144

< 3.4

< 5.2

< 2.0

< 2.4

< 4.8

< 4.0

< 3.1

< 2.9

< 3.3 CAWW-3595 11/14/2023 367 +/- 101

< 3.1

< 4.6

< 3.0

< 2.8

< 4.7

< 3.6

< 2.8

< 2.5

< 5.2 CAWW-3906 12/1 1/2023 262 +/- 94

< 5.7

< 5.7

< I.9

< 3.0

< 7.5

< 3.7

< 4.3

< 4.1

< 4.1 a Recount = 2171 +/- 168 pCi/L. Reanalysis ; 2448 +/- 176 pCi/L.

b Backup sample. Unable to meet LLD due to late arrival.

C Reanalysis = 1337 +/- 144 pCi/L.

ISFSI Sump CAWW-448 2/13/2023 214 +/- 88 CAWW-1406 5/26/2023 206 +/- 85 CAWW-2553 8/16/2023

< 160 CAWW-3659 11/14/2023

< 172 Location: CA-WWA-U1 MW-004 CAWW-449 2/15/2023

< 164

< 1.4

< 2.6

< 1.4

< 1.0

< 2.5

< 1.9

< 1.1

< 1.3

< 1.5 CAWW-1362 5/23/2023

< 157

< 1.4

< 2.4

< 1.2

< 2.7

< 2.9

< 1.8

< 1.4

< 2.2

< 2.2 CAWW-2574 8/16/2023

< 160

< 7.1

< 8.9

< 6.8

< 5.6

< 8.7

< 4.7

< 6.9

< 7.2

< 5.4 8-3

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date H

Mn

$e Co Co Zn ZrNb Cs Cs BaLa Location: CA-WWA-U1 MW-005 CAWW-450 2/15/2023

< 164

< 1.5

< 3.0

< 1.6

< 2.8

< 2.2

< 1.8

< 1.4

< 24

< 2.9 CAWW-1363 5/25/2023

< 157

< 2.4

< 5.0

< 2.6

< 2.4

< 5.3

< I.6

< 2.3

< 2.1

< 3.4 CAWW-2575 8/16/2023

< 160

< 1.7

< 5.1

< 2.7

< 6.0

< 2.8

< 2.4

< 3.4

< 5.8

< 3.5 Location: CA-WWA-U1 MW-006 CAWW-451 2/21/2023

< 163

< 2.5

< 6.2

< 2.7

< 2.1

< 4.5

< 3.3

< 2.5

< 2.3

< 3.1 CAWW-1364 5/24/2023

< 157

< 1.7

< 3.7

< 1.6

< 1.5

< 2.5

< 1.6

< 1.6

< 1.4

< 3.3 CAWW-2569 8/21/2023

< 160

< 2.4

< 4.4

< 3.2

< 9.1

< 6.5

< 3.6

< 4.5

< 6.5

< 3.1 CAWW-3652 11/15/2023

< 172

< 1.4

< 4.4

< 2.1

< 4.0

< 4.6

< 3.6

< 2.4

< 3.7

< 2.4 Location: CA-WWA-U1 MW-O1O CAWW-452 2/21/2023

< 163

< 1.6

< 2.3

< 1.7

< 1.7

< 3.2

< 1.9

< 1.5

< 1.0

< 2.4 CAWW-1365 5/22/2023

< 157

< 4.4

< 6.2

< 5.8

< 4.5

< 5.6

< 6.1

< 5.6

< 4.0

< 3.2 CAWW-2568 8/21/2023

< 160

< 6.4

< 6.5

< 4.8

< 3.6

< 5.0

< 5.1

< 6.1

< 4.0

< 4.1 CAWW-3653 11/15/2023

< 172

< 4.6

< 8.2

< 5.3

< 4.9

< 6.2

< 4.7

< 4.2

< 3.5

< 4.3 Location: CA-WWA-U1 MW-013 (New Location)

CAWW-453 2/15/2023

<164

<3.1

<6.7

<2.1

<6.2

<6.2

<4.0

<3.3

<5.8

<9.4 CAWW-1366 5/22/2023

< 157

< 2.6

< 5.9

< 4.0

< 2.5

< 6.2

< 4.3

< 3.5

< 3.4

< 4.2 CAWW-2572 8/22/2023

< 160

< 5.6

< 6.7

< 4.6

< 5.1

< 7.5

< 6.3

< 7.3

< 6.0

< 5.1 CAWW-3654 11/15/2023

< 172

<2.1

<3.2

<2.0

<2.1

<4.2

<2.5

< 1.9

<2.2

<3.9 Location: CA-WWA-U1 MW-014 CAWW-454 2/24/2023 238 +/- 89

< 4.6

< 7.1

< 4.7

< 4.0

< 7.6

< 3.9

< 5.7

< 6.3

< 4.5 CAWW-1367 5/23/2023 288 +/- 89

< I.1

< 2.2

< 0.7

< 1.2

< 2.3

< 1.7

< 1.0

< 1.2

< I.8 CAWW-2570 8/21/2023 252 +/- 90

< 6.4

< 9.4

< 5.4

< 4.6

< 8.2

< 10.2

< 8.6

< 5.5

< 5.9 CAWW-3655 11/9/2023

< 172

< 3.1

< 34

< 3.2

< 5.7

< 7.4

< 6.0

< 3.6

< 5.4

< 8.9 Location: CA-WWA-U1 MW-015 CAWW-455 2/15/2023

< 164

< 2.4

< 8.1

< 3.4

< 1.9

< 5.0

< 4.5

< 3.5

< 3.9

< 7.1 CAWW-1368 5/22/2023

< 157

< 1.6

< I.5

< I.1

< 2.8

< 2.7

< 1.3

< I.4

< 2.2

< 1.8 CAWW-2573 8/22/2023

< 160

< 3.4

< 5.8

< 3.3

< 7.5

< 5.1

< 3.5

< 4.7

< 5.9

< 3.8 CAWW-3656 11/13/2023

< 172

< 1.9

< 4.1

< 3.8

< 2.4

< 6.5

< 3.2

< 3.0

< 2.0

< 9.2 8-4

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H Mn Fe Co Co b5Zn S5ZrNb 1Cs Cs 1°BaLa Location: CA-WWA-U1 MW-O1 6 CAWW-457 2/15/2023 234 +/- 89

< 5.3

< 5.6

< 4.5

< 3.2

< 9.0

< 7.2

< 4.4

< 4.0

< 7.9 CAWW-1369 5/24/2023

<157

<2.6

<2.2

<2.4

<1.8

<2.2

<3.1

<2.1

<2.6

<3.3 CAWW-2576 8/16/2023

< 160

< 4.6

< 4.8

< 6.1

< 5.0

< 9.1

< 6.0

< 5.5

< 4.5

< 5.0 CAWW-3657 11/13/2023

< 172

< 1.9

< 6.2

< 2.0

< 3.1

< 6.6

< 5.5

< 3.2

< 3.5

< 8.6 Location: CA-WWA-U1 MW-If CAWW-458 2/21/2023

< 163

< 2.2

< 4.3

< IA

< 2.2

< 4.1

< 2.5

< 2.2

< 2.9

< 2.3 CAWW-1370 5/23/2023

< 157

< 1.8

< 3.7

< 1.3

< 0.9

< 3.3

< 1.7

< 1.5

< 1.8

< 2.5 CAWW-2571 8/21/2023

< 160

< 3.0

< 5.1

< 3.5

< 6.7

< 5.0

< 2.8

< 3.7

< 5.0

< 3.6 CAWW-3658 11/9/2023

< 172

< 1.1

< 2.7

< 1.3

< 1.3

< 2.2

< 1.9

< 1.0

< 1.1

< 4.5 Location: CA-WWA-UI MW-18 CAWW-434 2/21/2023 233 +/- 89 a

CAWW-1407 5/23/2023

< 157 CAWW-2565 8/21/2023

< 160 CAWW-3660 11/9/2023

< 172 a Duplicate 169 +/- 86 pCi/L.

Location: CA-WWA-U1 MW-19 CAVVW-436 2/23/2023

< 163 CAWW-1 408 5/23/2023

< I 57 CAWW-2564 8/21/2023

< 163 CAWW-3661 11/9/2023

< 172 Location: CA-WWA-U1 MW-20 CAWW-437 2/24/2023

< 163 CAWW-I 409 5/25/2023

< 157 CAWW-2563 8/21/2023

< 160 CAWW-3662 11/9/2023

< 172 Location: CA-WWA-U1 MW-31 CAWW-438 2/10/2023 356 +/- 96 CAWW-1410 5/17/2023 311 +/-91 CAWW-2557 8/15/2023 277 +/- 91 CAWW-3663 11/17/2023 195 +/-91 8-5

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H Mn Fe Co Co Zn ZrNb 1Cs 1Cs 1°BaLa Location: CA-WWA-U1 MW-34 CAWW-439 2/15/2023 370 +/- 96 CAWW-1411 5/1912023 221 +/-86 CAWW-2561 8/15/2023 262 +/- 91 CAWW-3664 1 1 /1 7/2023 261 +/- 95 Location: CA-WWA-U1 MW-36 CAWW-440 2/15/2023 234 +/- 89 CAWW-1412 5/19/2023 221 +/-86 CAWW-2558 8/15/2023 214 +/- 88 CAWW-3665 11/17/2023

< 172 Location: CA-WWA-U1 MW-39 CAWW-441 2/10/2023

< 164 CAWW-1413 5/19/2023

< 158 CAWW-2552 8/1 6/2023

< I 60 CAWW-3275 10/23/2023

< 166

< 3.4

< 4.4

< 2.6

< 5.3

< 5.1

< 4.2

< 3.2

< 4.7

< 1.8 CAWW-3666 11/15/2023

< 172 8-6

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCiIL)

Lab Code Date 3H 54Mn 59Fe 58Co 60Co 65Zn 95ZrNb 34Cs 137Cs 140BaLa Location: CA-WWA-U1 MW-47 2/24/2023 NDa 5/31/2023 NDa CAWW-2554 8/1 6/2023

< I 61 11/13/2023 ND Location: CA-WWA-U1 MW-58 CAWW-442 2/1 5/2023 21 0 +/- 88 CAWW-1414 5/17/2023 202 +/- 85 CAWW-2559 8/16/2023 209 +/- 88 CAWW-3667 11/17/2023

< 172 Location: CA-WWA-U1 MW-59 CAWW-443 2/21/2023

< 163 CAWW-1415 5/19/2023

< 158 CAWW-2562 8/21/2023

< 160 CAWW-3668 11/17/2023

< 172 a ND = No data, see Table 2.0, Listing of Missed Samples.

8-7

Table 8. Wells (non-potable), analyses for tritium and gamma-emitting isotopes.

Collection Concentration (pCi/L)

Lab Code Date 3H 54Mn 59Fe 58Co 60Co 65Zn 95ZrNb Cs 137Cs 1°BaLa Location: CA-WWA-U2MW-2S CAWW-444 2/23/2023

< 163 CAWW-1416 5/26/2023

< 157 CAWW-2567 8/22/2023

< 160 CAWW-3678 11/15/2023

< 172 Location: CA-WWA-U2MW-5S CAWW-445 2/16/2023

< 163 CAWW-1417 5/26/2023

< 157 CAWW-2555 8/16/2023

< 160 CAWW-3679 11/15/2023

< 172 Location: CA-WWA-U2MW-8 CAWW-446 2/10/2023

< 164 CAWW-1418 5/17/2023

< 158 CAWW-2560 8/15/2023

< 160 CAWW-3680 11/15/2023

< 172 Location: CA-WWA-U2MW-1 6 CAWW-447 2/24/2023

< 163 CAWW-1419 5/24/2023

< 157 CAWW-2566 8/22/2023

< 160 CAWW-3681 11/17/2023

< 172 Location: CA-WWA-F-005 CAWW-115 1/17/2023

<160

<2.0

<4.7

<2.4

<2.1

<5.0

<3.0

<2.4

<2.6

<2.4 CAWW-777 4/3/2023

< I 73

< 2.1

< 3.7

< 1.1

< 2.3

< 4.5

< 2.5

< 1.9

< 2.0

< I.9 CAWW-2008 7/11/2023

< 163

< 4.6

< 10.4

< 3.4

< 2.9

< 3.7

< 4.1

< 3.8

< 4.2

< 3.2 CAWW-3043 10/6/2023

< 170

< 5.2

< 6.1

< 6.1

< 4.4

< 6.5

< 4.4

< 7.6

< 5.5

< 4.0 Location: CA-WWA-F-01 5 CAWW-116 1/17/2023

<160

<0.8

<1.8

<12

<1.3

<2.3

<1.5

<1.1

<1.2

<0.8 CAWW-778 4/3/2023

< 173

< 3.3

< 5.6

< 3.0

< 2.0

< 4.5

< 3.2

< 2.8

< I.8

< 3.8 CAWW-2007 7/10/2023

< 163

< 6.1

< 6.3

< 6.0

< 4.7

< 14.2

< 5.7

< 5.6

< 6.4

< 4.0 CAWW-3042 10/6/2023

< 170

< 2.5

< 4.6

< 2.1

< 6.0

< 5.4

< 2.3

< 3.5

< 5.8

< 2.4 8-8

Table 9. Shoreline sediments, analyses for gamma-emitting isotopes.

Collection:

Semiannually Units:

pCi/kg dry Location CA-AQS-A Lab Code Req. LLD CASS-1252 CASS-2944 Date Collected 05-10-23 09-28-23 K-40 11820 +/- 633 13909 +/- 689 Mn-54

< 22.3 19.9 Fe-59

< 71.6

< 47.1 Co-58

< 22.0

< 21.9 Co-60

< 15.7 18.7 Zr-Nb-95

< 38.9

< 25.1 Cs-134 150

< 17.0

< 20.5 Cs-137 180

< 13.8 53.4 +/- 21.3 Ba-La-140

< 186.1

< 62.5 Location CA-AQS-C Lab Code Req. LLD CASS-1253 CASS-2945 Date Collected 05-1 0-23 09-28-23 K-40 13238 +/- 720 13466 +/-

710 Mn-54

< 28.9

< 27.4 Fe-59

< 75.3

< 51.0 Co-58

< 35.3

< 32.1 Co-60

< 20.1 17.8 Zr-Nb-95

< 52.2

< 27.4 Cs-134 150

< 22.5

< 21.4 Cs-137 180

< 17.4 52.0 +/- 20.4 Ba-La-140

< 256.7

< 74.0 a Recount = 42.4 +/- 7 pCi/kg.

b Recount = 48.3 +/- 7 pCi/kg.

9-1

Table 10. Fish, analyses for gamma-emitting isotopes.

Collection:

Semiannually Units:

pCi/kg wet Location CA-AQF-A Lab Code Req. LLD CAF-1241 CAF-1242 CAF-1243 CAF-1244 CAF-1245 Date Collected 05-10-23 05-10-23 05-10-23 05-10-23 05-10-23 Sample Type Rivet Catpsucket Smallmouth Buffalo Fteshwatet Dtum Common Catp CC RC Silvet Catp SC SB RD K-40 3083 +/- 349 3198 +/- 373 2750 +/- 307 3190 +/- 379 3535 +/- 402 Mn-54 130

< 11.7

< 15.6

< 9.1

< 11.9

< 10.1 Fe-59 260

< 51.4

< 70.7

< 57.4

< 74.6

< 72.8 Co-58 130

< 19.1

< 18.1

< 17.5

< 20.6

< 13.9 Co-60 130

< 8.5

< 11.1

< 3.8

< 10.9

< 7.0 Zn-65 260

< 19.5

< 28.0

< 25.4

< 25.5

< 26.7 Cs-134 130

< 14.7

< 7.7

< 13.7

< 14.8

< 12.3 Cs-137 150

< 10.0

< 9.7

< 9.7

< 8.9

< 13.6 Location CA-AQF-A Lab Code Req. LLD CAF-2934 CAF-2935 CAF-2936 CAF-2937 CAF-2938 Date Collected 09-28-23 09-28-23 09-28-23 09-28-23 09-28-23 Sample Type Rivet Catpsucket Smallmouth Buffalo Fteshwatet Dtum Common Catp CC RC Silvet Catp SC SB RD K-40 3028 +/- 526 3105 +/- 427 3335 +/- 552 2966 +/- 390 2467 +/- 590 Mn-54 130

< 19.7

< 13.7

< 23.3

< 9.2

< 25.8 Fe-59 260

< 65.7

< 52.0

< 36.4

< 30.6

< 52.3 Co-58 130

< 15.3

< 13.4

< 19.7

< 17.8

< 17.2 Co-60 130

< 26.5

< 32.6

< 20.3

< 34.5

< 15.8 Zn-65 260

< 66.9

< 23.2

< 20.1

< 23.0

< 58.5 Cs-134 130

< 24.8

< 17.4

< 24.4

< 18.7

< 23.3 Cs-137 150

< 25.9

< 26.8

< 15.9

< 25.8

< 18.5 I 0-1

Table 10. Fish, analyses for gamma-emitting isotopes.

Collection:

Semiannually Units:

pCi/kg wet Location CA-AQF-C Lab Code Req. LLD CAF-1246 CAF-1247 CAF-1248 CAF-1250 CAF-1251 Date Collected 05-10-23 05-10-23 05-10-23 05-10-23 05-10-23 Sample Type Rivet Catpsucket Smalimouth Buffalo Fteshwatet Dtum Common Catp CC RC Silvet Catp SC SB RD K-40 3538 +/- 381 3261 +/- 379 3123 +/- 386 3149 +/- 375 3476 +/- 398 Mn-54 130

< 8.5

< 13.3

< 9.6

< 8.4

< 11.2 Fe-59 260

< 49.9

< 59.6

< 66.4

< 64.4

< 67.8 Co-58 130

< 17.1

< 19.9

< 14.4

< 17.1

< 10.4 Co-60 130

< 10.5

< 8.8

< 10.0

< 16.7

< 9.1 Zn-65 260

< 20.0

< 22.5

< 23.4

< 19.9

< 32.0 Cs-134 130

< 17.0

< 10.7

< 14.5

< 15.4

< 11.8 Cs-137 150

< 10.2

< 13.8

< 10.2

< 11.6

< 8.3 Location CA-AQF-C Lab Code Req. LLD CAF-2939 CAF-2940 CAF-2941 CAF-2942 CAF-2943 Date Collected 09-28-23 09-28-23 09-28-23 09-28-23 09-28-23 Sample Type Rivet Catpsucket Smallmouth Buffalo Fteshwatet Dtum Common Catp CC RC Silvet Catp SC SB RD K-40 3124 +/- 509 3389 +/- 635 3259 +/- 421 3444 +/- 442 3798 +/- 470 Mn-54 130

< 31.4

< 32.6

< 10.4

< 9.6

< 15.4 Fe-59 260

< 52.6

< 88.3

< 38.7

< 27.6

< 59.9 Co-58 130

< 20.5

< 14.6

< 17.7

< 19.3

< 16.5 Co-60 130

< 7.3

< 22.4

< 9.1

< 12.2

< 37.4 Zn-65 260

< 76.8

< 38.8

< 15.3

< 27.7

< 19.1 Cs-134 130

< 25.9

< 26.1

< 17.7

< 14.3

< 15.5 Cs-137 150

< 23.9

< 23.8

< 12.0

< 17.0

< 31.0 I 0-2

Table ha. Direct Radiation (quarterly exposure)

Location Gamma Dose (mreml9O days)

QTR I QTR 2 QTR 3 QTR 4 CA-IDM-IA J55J 15.51 15.33 15.80 CA-IDM-3 16.44 15.91 15.80 17.18 CA-IDM-5 13.53 14.98 12.75 13.69 CA-IDM-6 15.53 14.62 1449 15.31 CA-IDM-7 15.43 14.25 15.32 15.13 CA-IDM-9 14.42 14.61 14.35 14.08 CA-IDM-10 NSa 16.67 16.18 17.20 CA-IDM-IIA 16.15 15.79 15.86 16.62 CA-IDM-14 15.63 14.86 15.36 15.41 CA-IDM-17 15.23 15.09 14.39 15.45 CA-IDM-18A 15.89 15.35 15.91 15.43 CA-IDM-20 15.54 14.94 15.62 15.35 CA-IDM-21 15.80 14.54 15.22 15.43 CA-IDM-22A 13.52 11.96 11.73 12.66 CA-IDM-23 16.29 16.93 15.90 16.24 CA-IDM-26(C) 11.51 9.89 9.79 10.54 CA-IDM-27 (C) 17.47 15.82 15.71 16.83 CA-IDM-30A 15.11 14.88 14.63 15.21 CA-IDM-31A 16.34 16.05 16.69 16.69 CA-IDM-32 15.68 16.90 15.49 16.70 CA-IDM-32A 14.69 15.53 14.22 14.85 CA-IDM-33 14.77 16.19 14.50 15.48 CA-IDM-34 14.35 14.25 15.00 15.09 CA-IDM-35 14.12 14.09 13.43 13.55 CA-IDM-36 14.22 13.48 12.77 14.59 CA-IDM-37 15.16 15.30 15.00 15.47 CA-IDM-38 10.90 10.20 10.82 10.68 CA-IDM-39 14.07 14.90 14.42 15.00 CA-IDM-39A 15.31 15.53 14.33 15.22 CA-IDM-40 15.50 15.98 15.24 16.25 CA-IDM-41 14.12 15.29 14.45 14.97 CA-IDM-42 13.83 14.21 12.82 13.32 CA-IDM-43 14.86 15.63 15.13 15.38 CA-IDM-44 14.92 15.33 1545 15.56 CA-IDM-45 13.87 13.83 13.66 14.30 CA-IDM-46 16.51 14.95 14.70 16.38 CA-IDM-47 14.69 14.66 14.54 14.85 CA-IDM-48 15.57 15.50 15.88 16.62 CA-IDM-49 14.46 14.67 13.83 14.38 CA-IDM-50 15.35 15.26 15.11 15.42 CA-IDM-51A 16.68 16.37 15.75 17.20 CA-IDM-52 15.75 15.19 15.65 16.44 CA-IDM-60(C) 14.78 15.76 15.21 15.70 CA-IDM-61 14.25 14.26 14.28 14.59 a NS = No sample; see Table 2.0, Listing of Missed Samples.

111

Table I I b. Direct Radiation Neutron (quarterly exposure)

Location Neutron Dose (mrem/90 days)

QTR 1 QTR 2 QTR 3 QTR 4 CA-IDM-60N (C) 0.0 +/-

1.0 0.0 +/-

1.7 0.0 +/-

1.7 0.0 +/-

1.1 CA-IDM-61N 0.0 +/-

2.4 0.0 +/-

1.6 0.0 +/-

0.8 0.0 +/-

1.0 CA-IDM-62N 0.0 +/-

2.3 0.0 +/-

1.8 0.0 +/-

0.8 0.0 +/-

1.6 CA-IDM-63N 0.0 +/-

1.7 0.0 +/-

1.8 0.0 +/-

1.2 0.0 +/-

1.4 CA-IDM-64N 0.0 +/-

0.6 0.0 +/-

1.5 0.0 +/-

1.0 0.0 +/-

1.4 I 1-2