ML20246L087

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Semiannual Effluent Release Rept for Jan-June 1989. No Changes Made to ODCM
ML20246L087
Person / Time
Site: Maine Yankee
Issue date: 06/30/1989
From: Whittier G
Maine Yankee
To:
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I)
References
GDW-89-284, MN-89-111, NUDOCS 8909060221
Download: ML20246L087 (14)


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'MaineYankee atuxea tacinornon uame suce im j+-

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6i +i August 29, 1989 MN-89-111 GDH-89-284 Region I UNITED STATES NUCLEAR REGULATORY COMMISSION

' 475 Allendale Road .

King of Prussia, Pennsylvania 19406 -

Attention: Mr. William T. Russell, Regional Administrator ,

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References:

(a) License No. DPR-36 (Docket No. 50-309) h-Gentlemen: ~.

Subject:

Semiannual Effluent Release Report

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Enclosed is the Maine Yankee Semiannual Effluent Release Report for the period January 1,1989 to June 30, 1989. There were no changes to the ~

Off-Site Dose Calculation Manual. These reports are submitted in accordance with Technical Specifications 5.9.1.6, 4.13, 3.28, 3.16 and 3.17.

Very truly yours, MAINE YANKEE

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G. D. Whittier, Manager Nuclear Engineering and Licensing GDH:HSD _

Enclosure -

c: Mr. Richard H. Hessman Mr. Eric J. Leeds Mr. Cornelius F. Holden

, Document Control. Desk 1

Mr. Donald Hoxie - DHE Mr. Allan Prysunka - DEP - Oil & Hazardous Haste .

! American Nuclear Insurers

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SEMIANNUAL EFFLUENT RELEASE REPORT

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1.0 INTRODUCTION

l Tables 1 through 4 list the recorded radioactive liquid and gaseous -

effluents and solid waste for the first six months of the year, with data -

i summarized on a quarterly basis, i

Appendices A through 0 indicate the status of reportable items per the requirements of Technical Specifications 3.16.C, 3.17.0, 3.28. A. 3.28.8, 4.8.A, 4.13 and 5.9.1.6. -

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Effluent and Waste Discosal Semiannual Reoort '

' ', 7ITT' First and Second Ouarters. 1989 j;, l _. ' ' ,, Gaseous Effluents - Summation of All Releases ~

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Est. Total

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av 3;qf P-j iA. Fission add Activation Gases

1. Total release Ci 4.29 E-01 2.18 E-01 2.50 E+01
2. Averace release rate for oeriod UCi/ set 5.45 E-02 2.78 E-02. -

- 3. Percent of reculatory limit  % 1.64 E-04 9.04 E-05 B. Iodines .

1. Total Iodine-131 Ci 9.38 E-06 5.39 E-06 2.50 E+01 -
2. Averaae release rate for oeriod UCi/sec 1.19 E-06 6.84 E-07
3. Percent of reculatory limit  % 1.05 E-05 6.00 E-06_

C. Particulate _ . .

1. Particulate with T-1/224 8 davs Ci 1.46 E-06 1.57 E-07 2.50 E+01
2. Averaae release rate for oeriod UCi/sec 1.85 E-07 1.99 E-08
3. Percent of reculatory limit  % 4.57 E-07 5.81 E-08 ,
4. Gross aloha radioactivity C1 1.84 E-07 8.18 E-08 l

D. Tritium

1. Total release C1 1.20 E+00 2.12 E+00 2.50 E+01 l 2. Averace release rate for oeriod UCi/sec 1.53 E-01 2.70 E-01
3. Percent of reaulatory limit  % 6.69 E-04 1.18 E-03 1

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Continuous Mode Batch Mode 01#3.d7.'""

f :;MGQ Nuclides Released Unit Quarter Quarter Quarter Quarter Q Z ' ,. >

1st 2nd 1st 2nd _,_

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[ 7 T 1. Fission Gases Krvoton-85 Ci N/D* N/D* N/D* N/D* __

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, Krvoton-85m Ci N/D* N/D* N/D* 3.59 E-04__

N/D* N/D*

L Krvaton-07 Ci N/D* N/D* --

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L Krvoton-88 Ci N/D* N/D* N/D* N/D*

Xenon-133 Ci N/D* N/D* 4.26 E-01 2.09 E-01 Xenon-135 Ci N/D* N/D* 1.45 E-04 8.72 F,,Q3._

Xenon-135m Ci N/D* N/D* N/D* N/D*

Xenon-138 Ci N/D* N/D* N/D* N/D* .

Xenon-133m Ci N/D* N/D* 2.38 E-03 7.13 E-06.

Xenon-131m Ci N/D* N/D* N/D* N/D*

Arcon-41 Ci N/D* N/D* N/D* N/D*  ;

Unidentified Ci N/D* N/D* N/D* N/D* l Total for oeriod Ci N/D* N/D* 4.29 E-01 2.18 E-01l* i 1

2. Iodines Iodine-131 Ci 9.34 E-06 3.85 E-06 3.93 E-08 1.54 E Iodine-133 C1 1.04 E-05 1.47 E-05 5.21 E-08 3.39 E-06 Iodine-135 Ci N/D* N/D* 2.02 E-08 1.60 E-06 Total for neriod C1 1.97 E-05 1.86 E-05 1.12 E-07 6.53 E-06 l
3. Particulate Strontium-89 Ci N/D* N/D* N/D* N/D* l Strontium-90 Ci N/D* N/D* N/D* N/D*

Cesium-134 Ci N/D* N/D* N/D* N/D*

Cesium-137 Ci 5.73 E-07 N/D* N/D* 1.32 E Barium-Lanthanum-140 Ci N/D* N/D* N/D* N/D' Zinc-65 Ci N/D* N/D* N/D* N/D*  !

Cobalt-58 Ci N/D* N/D* N/D* N/D*

Cobalt-60 Ci 8.83 E-07 1.55 E-07 N/D* 8.80 E-10 Others Ci N/D* N/D* N/D* N/D*

  • N/D - Not Detected .

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- Effluent and Waste Disnosal Semiannual Renort '

First and Second Ouarters 1989 Gaseous Effluents - Ground Level Releases

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Maine Yankee Atomic Pombt Station Effluent and Haste Disogsal Semiannual Reoort

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First and Second Ouarters. 1989

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,,; iA.' Fission and Activation Products

~1. Total release (not including tritium. aases. aloha) Ci 1.01 E-01 1.49 E-02 1.50 E+01

2. Average diluted concentration ,

durina ceriod uti/ml 5.05 E-10 7.16 E-11

3. Percent of aoolicable limit  % 7.65 E-03 1.61 E-03 B. Tritium -
1. Total release Ci 3.52 E+01 9.59 E+01 1.50 E+01
2. Average diluted concentration durina ceriod UCi/mi 1.76 E-07 4.61 E-07
3. Percent of acolicable limit  % 5.87 E-03 1.54 E-02 C'

C. Dissolved and Entrained Gases _.

1. Total release Ci 6.74 E-03 8.38 E-02 1.50 E+01
2. Average diluted concentration durina Deriod UCi/ml 3.37 E-11 a.03 E-10 ,
3. Percent of anolicable limit  % 1.69 E-05 2.01 E-04 D. Gross Alpha Radioactivity
1. Total release Ci 2.89 E-05 N/D* 1.50 E+01
2. Average diluted concentration durina ceriod UCi/ml 1.45 E-13 N/D*

E. Volume of waste released (prior to dilution) _

liters 1.54 E+07 7.76 E+06 1.00 E+01 F. Volume of dilution water used durina ceriod liters 2.00 E+11 2.08 E+11 1.00 E+01 h

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'j' _- Effluent and Haste DisDosal Semiannual ReDort

, first and Second Ouarters. 1989 y

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, -'.' Nuclides Released Unit Quarter Quarter Quarter Quarter

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Strontium-89 Ci N/D* N/D* 2.50 E-04 N/D*

Strontium-90 Ci N/D* N/D* N/D* N/D*

Cesium-134 Ci N/D* N/D* 2.65 E-03 9.01 E-05 Cesium-137 Ci 1.23 E-05 4.81 E-05 8.52 E-03 5.78 E-04 .'

Icdine-131 Ci N/D* N/D* 3.37 E-03 8.94 E-04_

Cobalt-58 Ci N/D* N/D* ].42 E-02 2.04 E-03 -

Cobalt-60 Ci 1.40 E-04 1.51 E-04 1.52 E-02 4.20 E-03 Iron-59 Ci N/D* N/D* N/D* N/D*

Zi nc-65 Ci N/D* 9.39 E-08 N/D* N/D*

Mancanese-54 Ci N/D* 1.23 E-08 1.22 E-03 3.79 E-04 Chromium-51 Ci N/D* N/D* 4.27 E-04 N/D* L' Zi rconium-Niobium-9S Ci N/D* 5.08 E-07 1.05 E-05 .N/D* _

Holybdenum-99 Ci N/D* N/D* 1.57 E-04 1.15 E-05 Technetium-99m Ci N/D* N/D* 3.73 E-04 9.35 E-06 l Barium-tanthanum-140 Ci N/D* 9.31 E-07 1.30 E-04 1.21 E-04 Ceri um-141 Ci N/D* N/D* N/D* N/D*

Others Iron-55 Ci N/D* N/D* 6.85 E-03 2.55 E-03 Silver-110m Ci N/D* N/D* 1.94 E-03 1.22 E-04 Iodine-133 Ci N/D* 4.74 E-07 9.62 E-04 N/D*

Antimonv-124 Ci N/D* N/D* 2.79 E-02 1.85 E-03 Antimony-125 Ci N/D* 1.36 E-05 1.67 E-02 1.82 E-03 Ruthenium-103 Ci N/D* 2.28 E-08 N/D* N/D*

Cobalt-57 Ci N/D* N/3* 4.51 E-06 N/D*

Tin-113 Ci N/D* 3.85 E-07 2.63 E-05 2.49 E-05

_MDj denti fi ed Ci H/D* N/D* N/D* N/D*

Total for Deriod (above)(1)Ci 1.52 E-04 2.15 E-04 1.01 E-01 1.47 E-02 Xenon-133 C1 1.05 E-04 1.96 E-05 6.53 E-03 8.24 E-02 Xenon-135 Ci N/D* 2.30 E-06 1.02 E-04 3.36 E-04 Xenon-131m Ci N/D* N/D* N/D* 2.76 E-04 Xenon-133m Ci N/D* N/D* N/D* 7.49 E-04 Krvoton-85m -

Ci N/D* 2.11 E-06 N/D* N/D*

KrvDton-88 C1 N/D* 1.33 E-06 N/D* N/D*

( N/D* - Not Detected (1) - Total for period does not include unidentified in this summation but is included in Table 2A, Item A1.

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TABLE 3

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Maine Yankee Atomic Power Station fl D uent and Haste D1900111 Semiannual Reoort First and Second Ouarters.19fd Solid Maste and Irradiated Fuel Shioments

.A. Solid Haste Shipped Off-Site for Burial or Disposal (Not Irradiated Fuel)*

Unit 6-Month Est. Total

___fsri od Error. %

1. Type of Haste
a. Spent resins, filter sludges, evaporator m3 3.4 i 10 bottoms. etc. - LSA container **.+ w Ci 55.72-
b. Dry. compressible waste, contaminated m3 84.1 i 10 eauioment. etc. - LSA container +.++ C1 1.5
c. Irradiated components, control rods, .a3 0 etc. Ci 0
d. m3 Ci
e. m3 C1
2. Estimate of Major Nuclide Composition (By Type of Haste)***
a. Fe-55 35% elus' or minus 10% __

Ni-63. 31% olus or minus 10%

Co-60 22% olus or minus 10%

Cs-137 2% olus or minus 10%

l Ba-137M 2% olus or minus 10%

Sb-125 1% olts or minus 10%

b. Cs-137 10% olus or minus 10%

Co-60 22% olus or minus 10%

Co-58 11% olus or minus 10%

Cs-134 3% olus or minus 10%

Ni-63 14% olus or minus 10%

Fe-55 26% olus or minus 10%

Zr-95 5% olus or minus 10%

Sb-125 2% olus or minus 10%

3. Solid Haste Disposition ,

Number of Shioments Mode of Transportation Destination From Maine Yankee 5 Trucking over Highway Chem-Nuclear, Barnwell, S.C.

From SEG # 31 Trucking over Highway Chem-Nuclear, Barnwell, S.C.

B. Irradiated Fuel Shipments (Disposition)

+ Contain?r volume equal to 55 gal ons (drums).

++ Contalair volume equal to 110 f t (boxes).

m Contal' ar volume equal to 170 ft (liners) (HIC)

  • Solid waste is Class A, as defined in 10CFR61.55. 84.1 m3, 1.5 Ci
  • Solid waste is Class B, as defined in 10CFR61.55 0.8 m3, 6.76 Ci
  • Solid waste is Class C, as defined in 10CFR61.55 2.6 m3, 48.96 Ci
    • Solidification agent is cement.
      • Excluding nuclides with half-lives less than 12.8 days.
  1. SEG performs super compacting of DAH.

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i 1. . Reaulatory Limits .

Maximum Permissible Concentration ]

a. Fission and activation gases: 10CFR20; Appendix B. Table 2, Column 1

. b. Iodines: 10CFR20; Appendix B. Table 2, Column 1 .

c. Particulate, (with half. . .., .

lives greater than 8 days) 10CFR20; Appendix B. Table 2, Column 1

d. Liquid effluents: 10CFR20; Appendix B, Table 2 Column 1
e. Total noble gas concentration 2E-04 uC1/mi ,

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2. Averace Eneray - Not Aeolit.able
3. Measurements and Anoroximations of Radioactivity
a. Fission and Activation Cases [-

Continuous Discharge - Vent stack samples are analyzed monthly. Activity l

1evels determined are assumed constant for the surveillance interval. The continuous vent stack monitor reading is used as a basis for increasing periodic sample frequency. 0~ l L ~

Batch Discharges - Direct measurements of the waste gas hold-up drums are taken prior to discharge. Containment vents and purges are analyzed by direct measurement of the containment atmosphere at periodic intervals during discharge. .

b. Icdines .

l Primary vent stack iodine totals are taken from a minimum of weekly measurements of an in-line charcoal filter.

c. Particulate Primary vent stack particulate totals are taken from a minimum of weekly measurements of an in-line particulate filter.
d. Licuid Effluents Samples of secondary systems' liquid effluents are analyzed weekly for gross beta-gamma, alpha, tritium, dissolved gases, and gamma emitting isotopes.

Each batch release fs analyzed for gross beta-gamma, alpha, tritium, di_ssolved gases, and gamma emitting isotopes prior to discharge.

Composite samples are made of secondary and primary system liquid effluents for a quarterly analysis of Strontium-90 and Strontium-89.

Primary system liquid effluents are also analyzed quarterly for Iron-55.

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@N . TABLE 4 .a -

(( , ~. (Continued) j$' - 4. Batch Releases e

a. Liouio's .,
1. Number of batch releases: 57
2. Total time period for batch releases: 187 hours0.00216 days <br />0.0519 hours <br />3.091931e-4 weeks <br />7.11535e-5 months <br />, 50 mirastes
3. Maximum time period for a batch release: 31 hours3.587963e-4 days <br />0.00861 hours <br />5.125661e-5 weeks <br />1.17955e-5 months <br />. 5 minutes
4. Average time period for batch releases: 3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />, 18 minutes
5. Minimum time period for a batch release: 15 minutes
6. Average stream flow during periods of release of effluents into a flowing stream: N/A
7. Maximum gross release concentration (uCi/ml): 1.71 2-07 ~.

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b. Gaseous .
1. Number of batch releases: 12
2. Total time period for batch releases: 104 hours0.0012 days <br />0.0289 hours <br />1.719577e-4 weeks <br />3.9572e-5 months <br />, 53 minutes '
3. Maximum time period for a batch release: 90 hours0.00104 days <br />0.025 hours <br />1.488095e-4 weeks <br />3.4245e-5 months <br />, 22 minutes
4. Average time period for b&tch releases: 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />, 44 minutes

, 5. Minimum time period for a batch release: 15 minutes

6. Maximum gross release rate (uC1/sec): 1.13 E+03 ..
5. Abnormal Releases --
a. Licuid .

There were no abnormal liquid releases during the reporting period. .

b. Gaseous There were no abnormal gaseous releases during the reporting period.
6. On-line Containment Purae On-line containment purge was not employed during the reporting period.

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APPENDIX A 3 Radioactive Effluent Henitorina Instrumentation Recoirement: Radioactive effluent monitoring instrumentation channels are required to be operable in accordance with Technical Specificat'ons 3.28.A &

B. With less than the minimum number of channels operable and reasonable efforts to return the instrument (s) to operable status within 30 days being unsuccessful. Technical Specifications 3.28.A &

B requires an explanation for the delay in correcting the inoperability in the next Semiannual Effluent Release Report.

Resoonse: The requirements of Technical Specifications 3.28.A and 3.28.B. -

governing operability of radioactive effluent monitoring instrumentation, were met for this reporting period, and no report is required.

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R'eauirement: With radioactive liquid waste being discharged without treatment with i~

estimated doses in excess of the limits in Technical Specification i

3.17.C.1, a report must be submitted to--the Commission in the

- Semiannual Effluent Release Report for the period. - -

a; Resoonse:- The requirements of Technical Specification 3.17.C.1 were met during

- this period and, therefore, no report is required. ,

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APPENDIX C Gaseous Radwaste Treatment System Requirement: Mith radioactive gaseous waste being discharged without treatment with doses in excess of the limits in Technical Specifications 3.18.D.1, a report must be submitted to the Commission in the Semiannual Effluent Release Report for the period.

Resnonse: The requirements of Technical Specification 3.18.D.1 were met during this period and, therefore, no report is required.

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APPENDIX D

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ii- Lower Limit of Detection for Radiological Analyses Requirement:' Technical Specification 4.13 requires that when unusual circumstances result in LLDs higher than required, the reasons shall be documented in the Semiannual Radiaattive Effluent Release Report.

Resoonse: Analyses were performed in such a manner that the stated LLD's were achievable under routine conditions. On occasion, with liquid samples, however, the presence of detected higher energy isotopes l caused a compton background elevation. This interference was sufficient to make some of the specified LLD's in those liquid samples unattainable. This occurred in four (4) of the samples for I Zinc-65, and one (1) for Iron-59. All other isotope LLD's were met.

On all occassions, the specified LLD's were attained on the gaseous samples.

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