ML20209J398
| ML20209J398 | |
| Person / Time | |
|---|---|
| Site: | Summer  |
| Issue date: | 08/30/1985 |
| From: | Baehr W, Cox J, Gowdy G SOUTH CAROLINA ELECTRIC & GAS CO. |
| To: | |
| References | |
| NUDOCS 8511110469 | |
| Download: ML20209J398 (114) | |
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39s/D samengRL EFFLLEEAND'WASPE DISPOSAL REPORT FOR THE TERATING PERIOD ganuary;1',1l1985XJune' 30J1985 m August 30, 1985 ES b
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V. C. SUMMER NUCLEAR STATION SOUTII CAROLINA ELECTRIC AND GAS COMPANY Prepared bf:
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G. M. pwdy, Staff Health Physicist S
Reviewed by: Ibviewed bf:
j Y1 hi {_
l W. R. Ibehr, Manager J. Cox,~Jr.,'pc.Mgr.
Physics l Corporate Health Physics Iba and Environmental Prograns i
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8511110469 850830 2 E 25 PDR ADOCK 05000395 R PDR
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. . b SEMIANN[AL EFFLLENP AND WASTE DISPOSAL REPCRT Jantary - June,1985 Virgil C. Stumer Nuclear Station South Carolina Electric & Gas his report is being subnitted as a sumary of the quantities of radio-active liquid and gaseous effluents and solid waste released from the Virgil C.
Sumer Nuclear Station. %is r@ ort satisfies the raInirenents in Sections 6.9.1.8 and 6.9.1.9 of Technical Epecifications and 10CFR50.36(a). Also included is an assessnent of radiation doses fran plant releases.
A brief discussion of the supplenental Infonnation and Tables 1 and 3 through 7 is presented in Sections A through D. An evaluation of the radio-logical inpact on man due to operation of the Virgil C. Stmner Wclear Station is presented in Section E and Table 2. Changes made to the Process Control Program are presented in Section F. Cbrrections to the previous report are given in Section G.
A. Stpplemental Information aegulatory limits for doses and maxinum permissible concentrations presented in Stpplenental Information _are from the V_irgil C. Sunmer mclear Station Technical Specifications. Average energy (E) is not applicable to the method for &termining release rate limits for fission and activation gaseous effluents; therefore, it has been onitted.
B. Gaseous Effltents Gaseous effluents released from ground level are stmmerized in Tables 3 and 4. An elevated release pathway does not exist at Virgil C. Stmner mclear Station. Cumulative doses are discussal in Section E.
te errors for gaseous effluent totals are given as the sIuare root of the sizn of squares of counting errors and flow or volume measurenent errors. A systematic error of 15% has been added to estimate total error.
C. Liquid Effluents Liquid effluents are sumarized in Tables 5 and 6. Estimated total errors are eg ressed as in Section B above.
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SEMIANNIAL EFFLLENT AND WASTE DISPOSAL REPORT January - June,1985 Virgil C. Stmner mclear Station South Carolina Electric & Gas D. Solid % ste Shipments Solid waste shipnents are summarized in Table 7. '1he thirteen (13) shipents during this r@orting period are described in Table 1.
Table 1 SOLID WASTE SHIPENTS DATE WASTE TYPE
'01-04-85 104 55-gallon drums and 6 B-25 boxes, Class A, dry active waste; Radioactive Material-LSA.
- 01-09-85 2 carton steel liners containing solidified evaporator bottom, Class A waste; Radioactive Material-LSA.
- 01-09-85 2 carton steel liners containing solidified evaporator bottom, Class A waste; Radioactive Material-LSA.
- 01-09-85 2 carbon steel liners containing solidifed evaporator bottans, Class A waste; Radioactive mterial-LSA.
- 01-30-85 2 cartun steel liners containing solidified evaporator bottans, Class A waste; Radioactive Material-LSA
- 01-30-85 2 carbon steel liners containing solidified evaporator bottoms, Class A waste; Radioactive Material-LSA .
03-06-85 2 carbon steel liners containing solidified evaporator bottams, Class A waste; Radioactive Material-LSA 03-14-85 70 55-gallon drum dry active waste and 1 carbon steel liner containing solidified evaporator bottats, Class A waste; Radioactive mterial-LSA 03-20-85 2 carbon steel liners containing solidified evaporator bottoms, Class A waste; Radioactive mterial-LSA
- 04-23-85 2 carbon steel liners containing solidified evaporator inttoms, Class. A waste; Radioactive mterial-LSA
- 04-23-85 2 carbon steel liners containing solidified evaporator tuttoms, Class A waste; Radioactive mterial-LSA 06-04-85 2 carbon steel liners containing solidified evaporator bottoms, Class A waste; Radioactive eterial-LSA 06-28-85 77 55-gallon drum and 9 B-25 boxes, Class A, dry active waste; Radioactive mterial-LSA
- Separate shipnents.
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SD4IANNIAL EFFLLENP AND WASTE DISPOSAL REPORT January - June,1985 Virgil C. Sumer M2 clear Station South Carolina Electric & Gas We conservative nethod for curie content determination is insed on con-tact dose rates measured around the perimeter of the respective packages.
We estinated total error is datennined to be the sun of a 15% systematic error and a 20% photon response error for the detector used.
E. Radiological Inpact on Man Potential doses to the maxinum exposed individual in the unrestricted area wre calculated using neasured plant gaseous effluent and neteorologi-
- cal data in accordance with the Oifsite Dose Calculation Manual. Included in the source term were one (1) wsste gas batch release, one (1) contaiment purge and a contintous six month main plant vent release. We total curies released are presented in Tables 3 and 4. ' Air doses to an individml due to noble gas were 3.08E-3 and 8.18E-3 mrad for gansna and beta respectively.
We maxinun organ dose attributed to the releases was 1.19E-5 arem for the six month period.
Measured plant liquid effluent data was used to calculate estimates of doses to individuals in accordance with the Offsite Dose Calculation 1%nual.
We source term consisted of the isotopic contents of each of the 168 liquid effluent batch releases from waste nonitor tanks, steam generator blowdowns, condensate denineralizer backwash, and a continuous turbine building sunp ,
release. %e total radioactivity released is described in Tables 5 and 6.
The total body dose to an exposed individual due to the radioactive liquid released was 1.77E-2 nrem. We maxinun organ dose was 2.20E-2 nrem to the Gastrointestinal Tract and Lower Large Intestine (GI-LLI).
Radiation cbses.from radioactive effluents to workers at the Fairfield Hydro Station were detecnined to be 4.20E-4 and 1.12E-3 mrad for gamma and beta, respectively.
Radiation doses from nearbf uranium fuel cycle sources were not asses-sed. 'Ibchnical Specifimtions, Section 3/4.11.4, page B 3/411-6 establishes a five (5) mile limit beyond which doses fran nearby plants are insignifi-cant. %ere are no uraniun fuel cycle plants within a five (5) mile radius of Virgil C. Sununer Nuclear Station.
Accumulated doses due to gaseous and liquid effluents and respective
'Iuchnical Specification limits are sumarized on the following page.
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SEMIMDRAL EFFIDENT AND WASTE DISPOSAL REPORT January - June,1985 Virgil C. Sumer Nuclear Station South Chrolina Electric & Gas
! Table 2 i
GASECUS AND LIQUID DOSES First Quarter, 1985 Second Quarter, 1985 Tech Spec Percent Percent Sectim Gaseous Limits Actual of Limit Actual of Limit 4
3.ll.2.2a,b 5 mead gama/qtr. 4.34E-4 mead 8.6 8E-3 2.65E-3 mrad 5.29E-2 10 mral gama/yr. 4.34E-3 3.0 8E-2*
3.ll.2.2a,b 10 mead beta /qtr. 1.29E-3 mrad 1.29E-2 6.89E-3 mrad 6.89E-2 20 mrad beta /yr. 6.45E-3 4.09E-2*
3.ll.2.3a,b 7.5 meen/ organ /qtr.1.01E-5 mrem 1.35E-4 1.79E-6 mren 2.3 8E-5 15 mrervorgan/yr. 6.74E-5 7.93E-5*
r Liquid Limits 3.ll.l.2a,b 1.5 mren/qtr. 4.80E-4 mren 3.20E-2 1.72E-2 mren 1.15E+0 3.0 meem/yr. 1.60E-2 5.8 9E-l*
3.ll.l.2a,b 5 mren/ organ /qtr. 3.74E-3 mren 7.48E-2 1.82E-2 mren 3.64E-1 10 mren/ organ /yr. 3.74E-2 2.20E-l*
- Includes contribution fran previous quarter.
Dose rates and concentraticns were below the limits specified in Supplenental Information, Section 2a, b and c during all the effluent releases.
'Ihe Virgil C. Sumer Nuclear Station (VCSNS) Process Control Program (PCP) was modified in March,1985 (Bevision 4) and June,1985 (Bevision 4, Change A) to reflect current revisions to Chen Nuclear (CNSI) procedures and make provision for the dewatering of 76 inch diameter pressure denineralimr vessels. 'Ihe overall conformance of the solidified waste product to existing criteria for solid wastes has not been adversely affected by the changes incorporated in the VCSNS PCP. Per Technical' Specification requirenent 6.13.2.1.c, the PSRC has reviewed and apprcved the revisions which are enclosed as Attachment I. See pages 1 and 2, Procedure Developnent Form - A,
! Section VII, for the PSRC approval signatures.
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SEMIANNLAL EFFLLENT AND WASTE DISPOSAL REPORT January - June,1985 Virgil C. Sumer M2 clear Station South Carolina Electric & Gas G. Previous Report Errata Errata fran the previous report (July - December,1984) are as follow:
- 1) Section E: Radiological Inpact on mn (page 3)
(a) Paragraph 1, line 6; " Tables 1 and 2" should read " Tables 3 and 4".
(b) Paragraph 2, line 6; " Tables 3 and 4" should read " Tables 5 and 6".
- 2) Table 3: Gaseous Ef fluents - Summation of All Releases (page 10)-
Footnote *
(a) Line 2: "3.52E-2%" should be "3.6 4E-2%"
(b) Line 3: "2.45E-2%" should be "2.52E-2%"
(c) Line 5: "3.60E-2%" should be "3.72E-2%"
(d) Line 6: "2.55E-2%" should be "2.62E-2%"
- 3) Table 3: Gaseous Ef fluents - Sunmation of All Releases (page 10) -
h tnote **
Line 2: "9.52E-4%" should be "9.51E-4%"
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SD4IANNLI4L EFFUENP AND WASTE DISPOSAL REPWT Janmry - June,1985 Virgil C. Sumner Nuclear Station South Carolina Electric & Gas Supplemental Information
- 1. Regulatory Limits:
- a. Fission and Activation Gases:
he air dose to an individual due to noble gases released in gasecus efflmnts shall be limited to less than or equal to 5 mrad for gama radiation and 10 mrad for beta radiation during any calendar quarter and 10 mrad for gaarna radiation and 20 mrad for beta radiation during any calendar year (Technical Specifications, Section 3.11.2.2) .
- b. Iodines, Particulates (half-lives > 8 days) and Tritiun:
he dose to an individual fran radiciodines, tritium and radioactive materials in particulate form with half-lives greater than 8 days in gaseous effluents shall be limited to less than or equal to 7.5 mrem to any organ during any calendar qmrter and 15 nrem to any organ during any calendar year (Technical Specifications, Section 3.11.2.3) .
- c. Liquid Effluents:
We dose or dose cannitment to an individual fran radioactive materials in liquid effluents released shall be limited to less than or equal to 1.5 mrem to the total body and 5 mren to any orcpn during any calendar quarter and 3 nrem to the total body and 10 arem to any organ during any calendar year (Technical Specifications, Section 3.11.1.2) .
- 2. Miximum Permissible (bncentrations:
- a. Pission and Activation Gases:
The dose rate in unrestricted areas due to radioactive materials released in gaseous eff1mnts shall te limited to less than or qual to 500 mrem / year to the total body and less than or qual to 3000 mren/ year to the skin (Technical Specifications, Section 3.11.2.1).
- b. Iodines, Particulates (half-lives > 8 days) and Tritium:
We dose rate in unrestricted areas due to radioactive materials in effluents should be limited to less than or equal to 1500 nrem/ year to any organ ('Ibchnical Ebecifications, Section 3.11.2.1) .
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SEMIANNUAL EFFLLENT AND WASTE DISPOSAL REPGRT January - June,1985 Virgil C. Sunmr Nuclear Station South Carolina Electric & Gis Stpplemental Infornation
- c. Liquid Effluents:
'Ibe concentration of radimetive materials released fran the site shall be limited to the concentrations specified in 10 CFR 20, Appendix B, Table II, Colum 2 for radionuclides other than dissolved or entrained noble gases. Ebr dissolved or entrained ncble gases, the concentration shall be limited to 2E-4 tCi/ml total activity (Technical Specifications, Section 3.11.1.1).
- 3. Average Energy:
Not Applicable
- 4. Maasurements and Approximations of Total Radioactivity:
- a. Fission and activation gases: Gamma spectromatry (GeLi or FFGe)
- b. Iodines: Gamna spectronetry (GeLi or liPGe)
- c. Particulates: Gantna spectrcxTetry (GeLi or IPGe), beta proportional counting, alpha proportiomi counting
- d. Tritiun: Liquid scintillation
- e. Liquid effluents: Gamma spectronetry (GeLi or HPGe), liquid scintillation (11-3), beta proportional ccunting, alpha prq>ortiomi counting
- 5. Bitch Releases:
- a. Liquid:
- 1. Namber of batch releases:
95 for first qtarter,1985 73 for second quarter,1985
- 2. Total tine period for tatch releases:
6299 min. for first quarter,1985 4390 min for second quarter,1985 Page 7 J
SEMIANNIAL EFFLI.F.Nr AND 1@STE DISPOSAL REPORT January - June,1985 Virgil C. StLuer Nuclear Station South Carolina Electric & Gas Stpplemental Infornation
- 3. Maxinum tim period for a batch release:
160 min. for first qmrter,1985 105 min. for second quarter,1985
- 4. Average tim period for tatch releases:
66 min. for first quarter,1985 60 min. for second qmrter,1985
- 5. Mininum time period for a batch release:
35 min. for first qmrter,1985 26 min, for second quarter,1985
- 6. Average stream flow during periods of release of effluent into a flowing stream:
4.60E4 gpm for first quarter,1985 5.03EM gpm for second qmrter,1985
- b. Gaseous:
- 1. NLmber of batch reJeases: 2
- 2. Ibtal time period for batch releases: 8425 min.
-3. Maxinum time period for a batch release: 8070 min.
- 4. Average time period for a batch release: 4213 min.
- 5. Minimum time period for a batch release: 355 min.
- 6. Abnornal Releases:
- a. Liquid:
- 1. NLmber of releases: 0
, 2. Ibtal activity released: 0 i Page 8 i
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r SEMIANNIRL EFFLLENT AND WASTE DISPOSAL REPORT Jantury - June,1985 Virgil C. Stumer Nuclear Station South Carolina Electric & Gas
- b. Gaseous:
- 1. Mmber of releases: 0
- 2. 'Ibtal activity released: 0 l
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r _.a SEMIANNUAL EFFWENT AND WASTE DISPOSAL REPORT January - June,1985 Table 3 GASEQJS EFFLUENTS-StPNATION OF ALL RELEASES First Seccnd Est. Total Quarter Quarter Error, %
A. Fission & activation gases
- 1. Ibtal release Ci 7.32E+0 3.62E+1 1.90E+1 l
- 2. Average release rate for period uCi/sec 9.41E-1 4.61E&O
- 3. Percent of technical specification limit % *
- B. Iodines
- 1. Total iodine-131 Ci 5.06E-7 0 6.75E+1 l
- 2. Average release rate for period uC1/sec 6.51E-8 0
- 3. Percent of technical specification limit % ** **
C. Particulates
- 1. Particulates with half-lives > 8 days Ci 0 0 N/A I
- 2. Average release rate for period uC1/sec 0 0
- 3. Percent of technical specification limit % ** **
- 4. Gross alpha radioactivity Ci 0 0 D. Tritim
- 1. Total release Ci 0 3.39E-3 4.08E+1 l
- 2. Average release rate for period uCi/sec 0 4.31E-4
- 3. Percent of technical specificatico limit % ** **
Calculated as a percent of: dose limits found in Suppisumtal Information, Section la.
First quarter values were 8.68E-3% and 4.34E-3% of the arterly and cunulative annual gamma dose limits, respectively and 1.29E-2% and 6.45E-3% of the qmrterly and caulative annual beta dose limits, respectively. Second quarter values were 5.29E-2%
and 3.08E-2% of the quarterly and cumulative annual ganma cbse limits, respectively, and 6.89E-2% and 4.09E-2% of the quarterly and cuculative annual beta dose limits, respectively.
Calculated as a percent of dose limits fcund in Supplemental Informaticm, Section lb.
The se of these values for first quarter was 1.35E-4% and 6.74E-5% of the qmrterly and cunulative annual organ dose limits, respectively. The sum of these values for second quarter was 2.38E-5% and 7.93E-5% of the quarterly and cumulative annual organ dose limits, respectively.
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SEMIANNLAL EFFLLENP AND WASTE DISPOSAL REPORP Jantary - June,1985 Table 4 GASEOUS EFFLLENPS-GROUND-LEVEL RELEASES Continuous Mode Batch Mode First Second First Second Nuclides Released Unit Quarter Quarter Quarter Quarter
- 1. Fission gases Ci 0 0 0 0 krypton-85 Ci 0 0 0 0 krypton-85m krypton-87 Ci 0 0 0 0 krypton-88 Ci 0 0 0 0 xenon-133 Ci 7.32E+0 6.02E+0 0 2.77E+1 xenon-135 Ci 0 0 0 1.90E+0 Ci 0 0 0 0 xenon-135m Ci 0 0 0 0 xenon-138 Others: Xe-133m Ci 0 0 0 5.85E-1 Xe-131m Ci 0 0 0 2.50E-4 Ci 0 0 0 unidentified 0 Total for period Ci 7.32E+0 6.02E+0 0 3.02E+1
- 2. Iodines iodine-131 Ci 5.06E-7 0 0 0 iodine-133 Ci 2.30E-6 0 0 0 inli ne-135 Ci 0 0 0 0 Total for period Ci 2.81E-6 0 0 0
- 3. Particulates strontitzn-89 Ci 0 0 0 0 strontitzn-90 Ci 0 0 0 0 cesian-134 Ci 0 0 0 0 cesitan-137 Ci 0 0 0 0 baritzn-lanthanum-140 Ci 0 0 0 0 Others: Ci 0 0 0 0 unidentified Ci 0 0 0 0
'Ibtal for period Ci 0 0 0 0 I
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SEMIANNUAL EFFWENT AND WASTE DISPOSAL REPORP January - June,1985 Table 5 LIQUID EFFWENIS-StM1ATION OF ALL RELEASES First Seccnd Est. Total Unit Quarter Quarter Error, %
A. Fission & activation products
- 1. Total release (not including tritium, gases, alpha) Ci 1.60E-1 1.21E-l 1.81E+1
- 2. Average diluted ccncentration during period uC1/ml 4.66E-10 3.81E-10
- 3. Percent of applicable limit % *
- B. Tritium
- 1. 'Ibtal release Ci 1.79E+1 5.98E+1 1.80E+1 l
- 2. Average diluted concentraticn during period uC1/ml 5.21E-8 1.89E-7
- 3. Percent of apolicable limit % *
- C. Dissolved and strained gases
- 1. Total release Ci 1.59E-3 3.27E-5 4.92E+1 l l
- 2. Average diluted ccncentrati<n during period uCi/ml 4.65E-12 1.03E-13
- 3. Percent of applicable limit % *
- D. Gross alpha radioactivity l 1. Total release l Ci I O l 0 i N/A l E. Volume of waste released (prior to diluticn) liters 1.60E+8 6.56E+7 3.00E+0 F. Volume of dilution water used during period liters 3.43E+11 3.17E+11 4.30E+0
- See following page.
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SEMIANNLRL EFFUENP AND WASTE DISPOSAL REPORT 1 >
Jan mry - June, 1985 6
Table 5 i
I LIQUID 1.FFLIENTS-SLM4ATION OF ALL RELEASES
- Calculated as a percent of dose limits found in Supplanental Information, Section Ic.
' We sun of these valms for first qmrter was 3.20E-2% and 1.60E-2% of the respective quarterly and etmulative annual whole body dose limits and 7.48E-2% and 3.74E-2% of the
. respective quarterly and cumulative annel organ dose limits. We sun of these valms j for the second quarter was 1.15% and 5.89E-l% of the respective quarterly and ;
cumulative annual whole body dose limits and 3.64E-l% and 2.20E-l% of the respective
> quarterly and cumulative annual organ dose limits. Dose to the GI-LLI was the most '
limiting organ dose for first and second qmrters.
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SEMIANNERL EFFILENT AND WASTE DISPOSAL REPORT
' January - June, 1985 Table 6
- LIQUID EFFLLENTS Continuoue, Mxle Batch Mode First Second First Second l Nuclides Released i Unit Quarter Quarter Quarter Quarter strontium-89 Ci 0 0 0 5.67E-5
' ~
Ci 0 0 0 0 strontiun-90 Ci 0 0 1.02E-5 0 4 cesiun-134 Ci 0 0 0 0 cesiun-137 iodine-131 Ci 8.51E-5 5.57E-4 2.03E-4 5.39E-4 mh=1 t-58 Ci 1.14E-3 1.38E-3 7.48E-2 5.llE-2 cobalt-60 Ci 0 0 5.40E-2 2.25E-2 >
iron-59 Ci 0 0 6.33E-5 1.05E-4 zinc-65 Ci 0 0 1.17E-5 0 manganese-54 Ci 1.10E-3 0 1.29E-2 6.94E-3 chrcmium-51 Ci 0 1.95E-3 2.97E-4 1.83E-3 zirconiun-niobium-95 Ci 0 0 1.02E-3 3.36E-4 molybdenun-99 Ci 0 0 1.84E-6 6.87E-5 technetian-99m Ci 0 2.25E-6 7.23E-5 1.58E-4 l barium-lanthanun-140 Ci 0 0 0 5.96E-5 ceriun-141 Ci 0 0 0 0 Other: Na-24 Ci 2.83E-3 1.12E-2 5.32E-3 3.42E-3 Fe-55 Ci 0 0 4.05E-3 1.22E-2
- Ni Ci 0 0 2.19E-8 0 '
- Cc>-57 Ci 0 0 5.12E-4 1.08E-4
! Cu-64 Ci 0 0 0 8.52E-5 Zn-69m Ci 0 0 0 2.15E-5 Zr-97 Ci 0 0 2.55E-6 0 Aq-110m Ci 0 0 5.21E-6 1.99E-5
- Sb-122 Ci 0 0 0 1.14E-5 4
- Sb-124 Ci 0 0 3.63E-5 4.26E-4
- Sb-125 Ci 0 0 4.27E-4 1.28E-3 I-132 Ci 0 6.46E-4 0 0 I-133 Ci 2.88E-4 1.99E-3 3.02E-4 5.63E-4 I-134 Ci 0 7.94E-4 0 0 3
I-135 Ci 0 3.22E-4 2.50E-5 0 Ce-144 Ci 0 0 2.21E-5 0 W-187 Ci 0 0 0 9.37E-5 I Total for period (above) I Ci l 5.43E-3 l 1.89E-2 l 1.54E-1 l 1.02E-1 l Page 14
__ . , _ _ , . _ _ . _ _ . . . - _ _ ., ~ . . _ . , _ _ , _ . . _ _ . _ - _ _ . . . . , _ _ . _ . _ . , _ . . . , _
SEMIANNLAL EFFwENP AND WASTE DISIOSAL REPORT 3- January - June,1985 Table 6 (Continued)
LIQUID EFFWINTS Ccmtinuous Mode Batch Mode
- j. First Secmd First Second ,
Nuclide Released Unit Quarter Quarter Quarter Quarter j xenon-133 Ci 0 5.41E-6 1.45E-3 7.24E-6 xencm-135 C1 0 0 1.16E-4 2.00E-5
_ Other: Xe-133m Ci 0 0 1 3.09E-5 0 i
t Tritiur . included. See Table 5 for tritium nunbers.
- Dose factors for these trace radionuclides are not includal in the ODCM or Regulatory Guide 1.109, ccmsequently the cunulative dose attributed to these isotcpes is not reported. 'Ihe quantity of these isotopes ccmprised only 5.39E-3%
and 3.19E-3% of the total curies released (including tritium) during first and second quarter, respectively.
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SEMIANNUAL EFFWENT AND WASTE DISPOSAL REPORT January - June,1985 Table 7 SOLID WASTE AND IRRADIATED WEL SHIPBENTS A. Solid Waste Shipped Offsite for Burial or Disposal (Not irraliated fuel) i
- 1. Type of waste Unit 6-month Est. Total i
Period Error, % '
- a. Spent resins, filter sludges, evaporator m 3 1.19E+2 bottans, etc. Ci 1.28E+1 3.50E+1
- b. Dry ccupressible waste, ccntaminated m3 9.49E+1 equip., etc. C1 2.02E+0 3.50E+1
- c. Irradiated ccuponents, control m3 0 rods, etc. Ci 0 N/A 1
- d. Other m3 0 Ci O N/A a
2.- Estimate of major nuclide conposition (by type of waste)*
- a. H-3 % 9.52E+1 i Co-58 % 1.70E+0 l CcMi0 % 9.68E-1
- b. Fe-55 % 3.82E+1
} Co-58 %- 3.07E+1 i Co-60 % 1.58E+1 i
Pet-54 % 6.26E+0 Ni-63 % 3.41E+0 Nb-95 + Fe-59 + Cr-51 + Zr-95 % 4.51E+0 Zn-65 + Sb-125 t Co-57 + Cs-137 + H-3 % 1.07E+0
- c. NCNE % N/A
- d. N GiB % N/A-i
- All nuclides are listed in descending order by activity level.
All nuclides with ccmcentrations above 0.10% are listed.
- 3. Solid Waste Disposition Number of Shipnents Mode of Transportaticm Destination I 13 Truck Barnwell, S.C.
B. Irradiated Fuel Shipnents (Disposition)
Niznber of Shipnents Mode of Transportation Destination NOIE
! Page 16 1
F e
ATIPCIBENT I V. C. StMER NUCLEAR STATION PROCESS CONTROL PROGlWM I
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- 11. CE50RIPTION: ( See Section 6.1. 2.4)3 iGj W,2 g, 7. . t. . - J .,, c - e ,: c . cf>. c 2 :. ,( c ., j g.,gy Z Ac,s l -a d. . ., s k .* c. - 2 .e4 i: c, . y). p z 3 , g g s. A (c, ;)
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'Yes .o
. 1 Pecresent a change to procedures as described in the FSAR' (O. 59 r ev ie w) /
- 2. #ecresent a change to the facility as described in the FSAR? (50. 59 reviewi -
- 3. Pecresent a test er experiment not described in the FSAR? (50. 59 rev ie w? -
A. D ecuire a change to Technical Specifications' (50. 59 review)
$. Result in si:;nificant increased persennel radiation exposure' ( ALARA review? a
_/
- 6. esult in a release of effluents to the Environment? g SLPt'ARY J)STIFICATICN: (List epc11 cable FSAR S T.S. References.) ( Attach additional peges as required.)
'If s'y question i throtqh 6 is ensered "yes*, re fer to Section 2.3 of procedure. **"-rs Pt'xa ouri < 1
, 7,w.;fe .> r >st r"J a A 1.:r v . u o s. 5 n r. . s S;.r.e
., t, . i ]
j
[ T'
^~ c f / J .,~ ,g t' Cr ic e'at e r )
0 ?%w~W (Ev aleatec hv Ciscialine Sucervisor)
/ ?! / .* .,$'
'Cata' t # .
I V. IDF(RARY APPROYAL
- FINAL APPR04AL REGJIRED BY Cate CUALITIED reb 1EaER Cate SS AFPRC6AL Cate Cate MCR/MOS Telecon By V. FE L MEO GE%1En AND CMENT v1. FINAL C.A itEvita ( As Spi tcaole)
' SA P l OfrER
( ) Cps (WGR ( H P) A
()mt (4 -S ^'"T*- rJ. i> Con 6rrenc e Date
( ) IS (4 y c.... /',( . .- /. se ., , , e
( ) SS () 3, ,, , ,, ,, u
() ( ) CA ,s FINAL APPROVAL:
() - ()
,,7f, ... . . / 7;,s .
.n, , , , . . . . .
, ( ) RC () / Responsible In ivgual C E TS PESOL ED: ~
Discipline ipervisor
./ h 'Appr ov al/ Concur rence w- [ / ')M5~~~
1 i*
Dete ' Cate Vll. PSRC r'Evlid A. Rev e.e- S '
B. PSR; Coments Resolved MC b) l O,)-
/ "V Dat e ' /
~
PSRC CMITtMAN /
Ccnraents Yes No / MAV CER Date
/
PSRC CHAI9 MAN Date
(
JUN241985
, c' EMBEEHD cm.....Cl'P'Y~"' -
F SAP-139 ATTACmENT IV PROCEDURE DEWLOPMENT FORM - A PAT 1 & 3 REVISION 4
(~ .. DATE: /- y - 9 5 PROC. # /cp-00/ REV. f V CHC. -
TITLEt A cc s i & r.< = / % s . .. f.< A 4 r>: e ./ 3 t w/ Co d n ,- n < i . ,s -- g
- ~ "
NEW PROC SAFEIY RELATED g REVISION /_ .
QUALITY RELATED
- CHANCE PER TNT RESTRICTED FROM 10 NON SAFETY RELATED TWO EAR FulEW ,
II. DESCRIPTION: 7# ' d.
- re. 4 t"' ' ^"' " #-~~*'-'- * - ^
- v. s um G o /s (See s;Section a.<o 6.1. 2. 4) AF
,e E a ./ . *b*
o r J* r*
a - **
.' *) '
r l. der. o. L < Jr fE and;CNSI r% . .l < s-e O-oo' co s .t<< < .s s -, t. .p ../ av
- s. sy;r J r., , u', .a . ,, c 1. vy si ,A '
ot .;/ *. < arrn k n e., e r n rA c er s g ' , w , ; ,, ,,,. n . p. n , g,, 4
- .l. ps ,. e v rr*J -e " ;r . -u s ,. 3 x p, n s ,, . ; g .o p . , , 3 g , ,,, p REASGN FOR CMNCEt Vpjaws h r' . w v.- as-//a , . .< a e s- n e s . o,s; r, s. ,.s3 ;- p as , a .; J r es, brasese f. ', -l s'
- f. t e < .-J s . , ,, a , 4, 7 4 , . s ,,. .s f., s r 4,. ./ g .,r..r.. y ,, f 74 j, , ,,. rs . r p r. si s 5',..<.a e /e s s - ,s., sj s% .
111. nlLL 1HIS RLVISION/CrdNGE/NEW PROCEDURE? *Yes No
- 1. Perresent a enange to procedures as described in the FSAR? (50.59 review) s
- 2. Represent a change to the facility as described in the FSAR? (50.59 review) -
- 3. Represent a test er experiment not described in the FSAR? (50.59 review) s 4 Geouire a cha ge to Technical Specifications? (50.59 review) 2
- 5. Result in significant increased persornel radiation exposure? ( ALARA review) -
- 6. Result in a release of effitents to the Environment? /
S'Je%RY .USTIFICATION: (List applicable FSAR & T.S. References.) ( Attach additional pages as required.)
- !f any question 1 t5totch 6 is answered "yes", refer to Section 2.3 of procedure.
c j s ") e et J s . v . . e f/ / a / fc. L o op 's a Jes r es e sJ e e -%. _ Q RMM' l,Wes-
- ( Or ig lest er ) (Ev aIunted by Discipline Supervisor) (Date)
(
I V. TD r W ARY APPROVAL. FlidL APPROVAL REQJIRED BY Date QUALIFIED eD1 EWER Date SS AFPROVAL Date MCR/MDS Date Telecon By V. REGJIRED PDIEW A'O CGe4LN1 VI. FINAL QA REVIEW ( As Appilcabit)
SAP OrNER
( ) Ops t ) G5t ( )
( ) +t (4 r3 wor /: rm.> Concurrence Date
( $ TS ( 4 p. , n . , t% = a J. "^'
( )SS () Au" FJ a' '
( 1 CA ( ) QA wiv./ /s** FINAL APPROVAL:
( ) QC () rc ,'a . n r. -
( ) RC () Responsible I ivi ual C T RESOL : y/n S k N$c . 3N-Discipline Supervisor Date Approv al/ Concur rence Date VII. PSRC REVILW A. B. PSRC Comments Resolved:
PSQtWIR%b4 / % Dap / /
f MANAGER Date Comments Yes No y
/
PSRC CttAIRMAN Date A ,.
( %
, i SOUTH CAROLINA ELECTRIC AND GAS COMPANY
/' s VIRGIL C. SUMMER NUCLEAR STATION
~ '
NUCLEAR OPSRATIONS a
PROCESS CONTROL PROGRAM PCP-001 PROCESS CONTROL PROGRAM FOR PACKAGIN3 0F LOW-LEVEL RADI0 ACTIVE WASTE f REVISION 4 JANUARY 16,.1985 SAFETY RELATED f
%)
'J O
\ . W('_ _
3 G 8[
3,
, DISCIPLINE SUPERVISOR Date t
h' k / c_ .
3-b- W
- j A-PPROVAL AUTH0ilITY Date
.3 l MAR 8 GS5 j
DAIE ISSUED i
RECORD OF CHANGES CHANGE TYPE DATE DATE CHANG 8 . TYPE DAfE DATE NO. CHANGE APPROVED CANCELLED NO. CHANGE APPROVED CANCELLED A P L kG Xs
(*v .Y b
i
Q y
tf ;
PCP-001 PAGE i
' -s REVISION 4 s 1/16/85
- \-< TABLE OF CONTENTS PAGE T
I List of Effective Pages i
- 1. 0 PURPOSE 1 4
- 2. 0 SCOPE 1 i
. 3. 0 REFERENCES 1
] 4. 0 LIMITS AND PRECAUTIONS 2 j 50 PROCEDURE 3 6.0 RECORDS 4 ATTACHMENTS ATTACHMENT I -
Chem-Nuclear Systems, Inc.
Ecodex Precoat/Powdex/Solka-Floc / Diatomaceous
/S',
Earth Dewatering Procedure for CNSI 14-195 or Smaller Liners
( !'
%d' ATTACHMENT II - Chem-Nuclear Systems, Inc.
Bead Dewatering Procedure for CNSI 14-195 or Smaller Liners
,, ATTACHMENT III - Chem-Nuclear Systems, Inc.
, Process Control Program for CNSI Cement Solidification Units j
?
ATTACHMENT IV - Chem-Nuclear Systems, Inc.
Operating Guidelines for Use of j Polyethylene High Integrity Containers
- 1 1 ATTACHMENT V -
Chem-Muclear Systems, Inc.
l j
Dewatering Procedure for the 24-inch Diameter Pressure Demineralizer Vessel Containing Activated Carbon 0 5% -
j Free Standing Water.
t ATTACHMENT VI - Chem-Nuclear Systems, Inc.
)l Dewatering Procedure for the 24-inch Diameter Pressure fj Demineralizer Vessel Containing Ion Exchange Resins -
1 0.5%/
] ATTACHMENT VII- Chem-Nuclear Systems, Inc.'
]: Dewatering Procedure for the CNSI 76-inch Diameter
/C. Pressure Demineralizer containing Ion - Exchange Resins V
h a
l 4
}
[ _ _ -_ . . _ . _ . . _ _ . . . _ _ _ . . . _ _ . - - _ - - -
- ~ ,
PCP-001
} REVISION 4 1
1/16/85 O(_,/)
- 1.0 PURPOSE 1.1 The purpose of this Process Control Program for the Virgil C. Summer Nuclear Station is to establish a set of process parameters which provide reasonable assurance that the packaged radioactive wastes meet applicable Department cf Transportation (DOT), Nuclear Regulatory Commission (NRC), and South Carolina State regulations for shipment and offsite burial at an approved site. Additionally, reasonable assurance is provided that the acceptance criteria of said burial facility are met.
2.0 SCOPE
, 2.1 This Process Control Program shall be used by all !
personnel for the packaging of low level radioactive wastes. This program includes Chem-Nuclear Systems Incorporated (CNSI) personnel operating CNSI supplied equipment.
2.2 This' Process Control Program is applicable to all " Wet Wastes" (such as evaporator concentrates, spent resins, etc.) and all wastes classified as Class B and Class C (in accordance with 10 CFR61) which are to be disposed of i
- s. in a radioactive vaste land disposal site.
30 REPERENCES 31 Virgil C. Summer Nuclear Station Final Safety Analysis Report, Chapter 10 and 11, FS AR Questions 321.17, through 321.23
, 32 SCE&G Corporate ALARA Plan.
6 33 Virgil C. Summer Nuclear Station Technical Specification 3/4 11 3
[? 34 Virgil C. Summer Nuclear Station Quality Assurance j Program.
2, 35 CNSI Quality Assurance Program, QA-AD-001, and CNSI Process Control Program, in 4313-01354-01. ,
i 36 CNSI Operating Procedures for Cement Sol'idification and *
. Dewatering Units, as applicable SD-0P-036 nnd PO-OP-003
_i ll.
l .-~
I
['N it V j'# PAGE 1 OP 4 i'
1 -
b,
. ~ .._._ _ _ . _ . _ . - ..
PCP-001 REVISION 4 1/16/85 s .s
) 37 CNSI Topical Report, 4313-01354-01.
38 NUREG 0472, Radiological Effluent Technical Specifiestions for PWR.
39 Branch Technical Position-EST3 11-3, Design Guidance for Solid Radioactive Waste Management Systems Installed in Light-Water-Cooled Nuclear Power Reactor Plants.
3 10 ANSI 199, Liquid Radioactive Waste Processing Systems for Pressurized Water Reactor Plants.
3 11 NRC Regulatory Guide 1.143, Design Guides for Radioactive Waste Management Systems, Structures, and Components Installed in Light-Cooled Nuclear Power Plants.
, 3 12 SRP 11.4 Rev. 2 July, 1981 " Solid Waste Management Systems".
3 13 10 CFR 50, Appendix A.
3 14 10 CFR 61, " Licensing Requirements for Land Disposal of Radioactive Waste".
3 15 10 CFR 20 311, " Standards for Protection Against
_. Radiation".
)-) 3 16 U.S. N.R.C. , Branch Technical Position, " Final Was'te classification and Waste Form Technical Position Papers",
dated May 11, 1983 3 17 CNSI-DW-11118-01-NP, " Dewatering Topical, Chem-Nuclear
. Systems, Inc.".
3 18 ' CNSI-VF-C-01 -NP , " Title 10 CFR 61, Vaste Form
. Certification -- Cement" by Chem-Nuclear Syatems, Inc.
4 3 19 CNSI-HIC-14571-01-NP, " Topical Report, Polyethylene High l Integrity Containers" by Chem-Nuclear Systems, Inc.
d 3 20 V.C. Summer Nuclear Station, Technical Specifications, j Sections 6 5 1.6,0, 6.8.1.g and 6.13 2.
.1 4
3 40 LIMITS AND PRECAUTIONS 9
i 4.1 Ensure that applicable Radiological Controls are
} established when sampling or processing Radioactive Waste.
~.,
i.
4.2 Only a CNSI operator with a release to <ork from QA, may operate CNSI solidification and dewatering equipnent at
-} ,
this station.
's / PAGE 2 OP 4 1 -
(
L
{ ..
PCP-001 i REVISION 4 j 1/16/85
! \ # 43 Working copies of the .'CP must be verified against the
, Master Control Copy of PCP-001 prior to beginning work.
50 PROCEDURE 51 For each batch of " Wet Waste" or Class B or C waste, Heslth Physics shall determine the most appropriate method of processing to meet 10 CPR 61 waste form criteria, 52 Normally acceptable waate processing methods and
- associated waste streams are
5 2.1 Cement Solidification for:
t
! a. Waste Evaporator Concentrates
- b. Filter Sludges
- c. Oils & Chsmicals 5 2.2 Dewatering in steel liners for:
- a. Powdex or Bead Type Resins with specific
_ activity < 1 ui/cc
. p( ) _
523 Dewatering in High Integrity containers for:
- a. Powdex or Bead T
. activity > 1 ui/ype cc Resins with specifi'
' 524 Draining of any " free standing water" and dispos 11 in a high integrity container for:
- i ,
- a. Proceos filter cartridges 53 cement solidification shall be accomplished in accordance with Attachment III.
l ,
5 .,4 Dewatering of Band Type Recina abould be accomplished in accordance with Attachment II.
j 5 5 . Dewatering of Ecodex, Powdex or Diatomaceous Earth should q be accomplished in accordance with Attachment I.
u.
j-56 Whenever High Integrity Containero are used, Attachment IV chould be followed to ensure that the container retains
]j its ability to meet 10 CFR 61 waste form requirements, f
'I <%
s)
H) PAGE 3 OP 4 e , , .. + . ,-
L_.__.__________________..________.- __._______.-_________._m.__.
PCP-001 REVISION 4 1/16/83
../ 57 Dewatering of 24" diameter pressure domineralizer vessels j
should be accomplished in accordance with Attachment V or VI, as applicable.
58 Dewatering of 76" diameter pressure demineralizer vessels should be accomplished in accordance with Attachment VII.
3
- . 6.0 RECORDS
, 6.1 All records generated in accordance with this procedure i
shall be included with the shipping papers as outlined in HPP-703
- 6.2 Copies of the shipping papers will be maintained by Health 4
' Physics for subsequent transmittal to Documents for retention.
I i
-4
}, I 4
$' b il
<.i i'
i-i
.b .
1 G PAGE 4 0F 4
(
- _ _ _ _ _ _ _ _ _ _ _ _ - _ _ . _ _ _ _ _. . _ . _ . . _ . _ , . _ _ _ _ . _ . _ . __ _ - , _ ~ . .__ _._-_________-___
!"[' - -.-..- -..._.-- ..--.- - -
'l -
i
{! ' -
PCP-001 Attachment i Revision D,~.,
4, Chg. A
~
i af to
{ MEVi$10NS '
SR3 APPROVAL aav, osscnierios oars iO M,,,t.
(Je,a. kWlf. meta A a uscES ,Eg. o uxcE eE2:ESr o.0..o22 01 4-+ rv
< ass aff, gov g o, r otANGES PER ORNGE REQUEST Fo-CP 022-02 INM/ ,
)N/A y g, I e *
/
't c .
.; ,4 c
a Db ' L -
CNSI SAFEiY REVIEW FERO?Ri ARY F0RVAE0h BOAR . A VAL BY .3 g- THIS COCUMENT CONTAINS PROPRIETARY INrcRMATION AND IS NOT TO BE RELEASED OR
, pf, ~ ,f/g /g COPIED WITHOUT THE WRITTEN PERMISSION
.; / f _ OF CHEM NUCLEAR SYSTEMS, INC.
.i
.y REVISION STATUS <
8"'87 1 2 3 4 5 6 7
[: 8 9 10 na v. B B B B B B B B B -
B
! SHEET . -
Re v.
.; P RipA,Aj O DA rt 4 '
y,gg;s ffff; CHEM - NUCLEAR SYSTEMS, INC.
CMECagO ygygg
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//b-B e .
ECODEX PHICOAT/POGEX/SOLKA-FLOC /DIATQtACECUS EAR 11
[N "# g.g~g DEWATERING PROCEDURE FCR
- QUAtsfy C'S! 14195 OR SSRLLER LINERS (V *' ,
0 $1lb!At //-/7-53
~
- #"UIO MD ,
00CUMaNT NO. R g v. SHggT f'W&$t7hsYbw G l
.' ( / -
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. _ _ . ~ . _ . . _ , . . . . . . _ _ . _ ~
.1 .
i9
, . - PC P-001 Attachment i Revision ti, Chg. A p,nn , nf to 7
\
b)%%') TABLE OF CONTENTS I
j PAGE NO l 1.0 SCOPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 l 1.1 Purpose ..................,,,,, 3
.j 1.2 Appifcabfifty ............., ,,,,, 3 1
2.0 REFERENCES
......................... 3 3.0 REQUIREMENTS
........................ 3 3.1 Prerequisites 3.2 ....................
Equipi.ient and Interfaces . . . . . . . 3 3.3 4 Safety . . . . . . . . . . . . . . . . . . . . . . . .
3.4 ........ 5 Acceptance Criteria
................. 6 4.0 CETAILED PROCEl>URE
..................... 6 4.1 j 4.2 Installation Procedure . . . . . . . . . . . . . . . . 6 Transfer /Dewatertnw Procedure ............ 7 -
I 5.0 I % RECORDS . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 s .) FIGURE I - Dewatering Cor.rpletion Recoru
.............. 19 i
. I
' l, I
fj
-l
'l
.j .
's
't
- n L.
t* 1 f
,j (
- 00CutesNT A S V.
seeggy FO-OP-022 B L 2 t' J C8eSQ 1992/S.M
- ~ w .e.%.+,e*+a+e ,e, *e* " * ** * " ' *
.m--._______-___-._.=*m**_ _ _ _ _ . . _ - . _ _ _ _ _._ . . _ _ _ _ _ _ _ _ _ _ _ _
q - ._ .
,j, PCP-001 Attachment i g Revisi,on n,.~ or 4, in Chg. A l
Nb 3
{D 1.0 SCOPE I
-t 1.1 Purpose l ,
i
, Tnis operatin3 procedure is for cewatering only Ecouex-Precoat/
Powdex/Solka-Floc /Diatoraaceous earth or equivalent base forms in l
CNSI 14-195 or saaller liners. The prvcedure h45 veen I satisfactorily tested per the referenced CNSI docuuents for I certification in meetiny the darnwell Site Disposal Critdia ano 1 Hanford site criteria for free-standin, liquids.
f 1.2 Applicabliity This procedure applies only to the dewaterin3 of Ecouex/Powdex/-
1 Solka-Fluc/Diatocaceous ' earth or equivalent base forms in 14-195 or smaller liners fabricated to the referenceu ChSI urawin, nuubers with less than 4l* oil.
2.0 REFERENCES
2.1 CNSI Procedure, CN-AD-003, " Procedure for Docuuent Prepar4 tion" 2.2 CNSI Procedure, CN-AD-001,
- Equipuent" " Control of Measurin3 anu Test ~
! 2.3 CNSI Procedure, CN-AU-013. " Test Control" 2.4 CNSI Procedure QA-AD-001, " Quality Assurance Prograa" 2.5
.~ CNSI Drawin3, 372-E-0003, "Cewater Internals Precuat Liners Weldaent" 2.6 i CNSI Drawin s , 372-E-0001, "cewater Internals Precoat Liners Ll4-195/Pil4195/Pil4195R/PLl4170R/PL7100/PL7100R" 2.7 I
CNSI crawing, B-340-b-0002, "Powdex Resin Uewaterin , Header #3" a 2.8 Engineerfte Project ho.11110. Test Data and Procedures 3.0 REQUIREMENTS i
3.1 Prerequisites
?1 3.1.1 M. Obtain e Radiation kor< Peruit (RWP), or equivalent, d frora the utility's Health Phys ics Department uefore
.g enterin3 the process area.
1 3.1.2 The utility's Health Physics personnel shall perform i
1 radiation level and surface contaufnation survejs.
Frequency of the survey is to be cetermined by the utility. Results of these surveys shall ue recorueu on 4 the Daily Operations Log as a permanent record.
(
M occunesser g FO-0P-022 nay, ggggy y e 8 3
} .
A CNSQ 1002/s 79
)
K. . . - - .- 2 ..... . - .- .. .,
a '
y - -
4
.; ' PC P-001
,i Attachment i l Revision 4. Chg. A
- m
"= y w iN ' 3.1.3 Note the completion of prerequisites in the Daily Oper-t ations Log.
3.2 Equipment and Interfaces -
3.2.1 The following equipment will be required for dewatering
, operations:
3.2.1.1 One ai r-driven diaphragm 1-1/2" pump with 1-1/2" FNPT connections, 1/2" FNPT air inlet or equivalent, 3.2.1.2 1-1/2" manifold with four 3/4" valved inlet connections and a 1-1/2" outlet connection and. vacuum gauges on each' inlet connection.
1 3.2.1.3 Connecting Hoses (1-1/2" non-collapsible) 3.2.1.3.1 Outlet hose for the dewater pump (Para. 3.2.1).
3.2.1.3.2 Suction hose to connect between.
the pump inlet and the manifold connection. -
3.2.1.4 Service air hose (3/4", 150 psi) with cou-9 pler to connect to the dewater pump and a t (V 6 3/4",150 psi coupler to connect to the ser-vice air supply.
3.2.1.5 Liner level indication and control system.
3.2.1.6 Dewatering container, as per referenced CNSI drawing numbers.
4 3.2.1.7 Utility supplied waste transfer line (quip-
- l ped with 1-1/2" female camlock connector.
- f. 3.2.1.E j Four non-collapsible 3/4" hoses to connect between the four inlet valves on the mant-d' fold and each of the four filter levels in the liner.
o NOTE: HOSE LENGTHS SHALL BE SUFFICIENT TO 0 ALLOW COYENIENT SET-UP IN THE UTIL-4 ITY'S DESIGNATED DEWATERING AREA.
ij 3.2.2 q The following utility interfaces are required to sup-port dewatering operations:
f-3.2.2.1 Service Air: 20 SCFM at 80 +20 -10 psig l L '
r1 -
3.2.2.2 Electricity: 120 VAC, Single Phase, 5 AMPS
] ,IK}
occumsNT f (.) ,
nav.
- swast
- FO-CP-0:2 B 4
- s.- >
esesQ 1002M N w - - -.- - -- - - - --
F.l q . .
i,
.] PC P-001 I Attachrnent !
[ Revision 4, Chg. A i(~f
- V J. -
r Page 5 of 10 3
3.2.2.3 Flushing capability on waste transfer lines 3.3 Safet/
3.3.1 Industrial Safety Requireuents t
CAUTION:
'; HOSES AND OTHER PFESSURE RtTAINING ' 'muNEaTS HAY BE PRESSURIZED. FACE SHI" . It % W/RC-PRIATE PROTECTIVE CLOTHING bi dE munu UM-ING DISASSEMBLY OF THIS EQUIPHENT.
3.3.1.1 Strong oxidiziny av ents sucn as nitric acia, when contact with organic ion-excnan J rial and in the presence of air, ua,,eprouuce mate-a s113 htly degraded resin in an exotiieruic reaction, 'ap to an explosion.
3.3.1.2 The CnSI technician (s) sh411 inspect anu use, as appro i safety glasse>prcheufcal ate, protective splash 3o33 clotnin v.
fes, face shield, nord hat, snoes, 31oves and/or -
- respirator wnfle wor 4ing within rive feet uf j the process equipment. Know where the "
.i closest eje wasu and safety shower are and
' ' \[_ s, now to use theu. vu 3.3.1.3 If a strai,ht laduer is used, it uust be tieu at the top ana/or held at the bottou by a co-worker. 3.3.2 Radiological Safety i 3.3.2.1 The CHSI technician (s) snail follow proper
- radiological precautions at all times to
- ulnfmize tne spread of contaraination enu tu j Ilmit personal exposure to radiation. ionizin3
]Lt 3.3.2.2 The CllSI technician (s) saall wear cos metry
?
?j equipuent and protective clothing as speci-fled by the Rautation Work Peruit or equivo-
- lent during all operations of the process e equipuent.
h a 3.4 Acceptance Criteria d q Three pumping cycles with a minicuu of ef3 nt incurs puupin, tiue D. and a minimum of sixteen liours waiting period eetween each puup-ing cycle shall be the acceptance criteria. (y NOTE: THE FINAL TRANSFER / DEWATERING CYCLE SHALL BE COUNTED AS THE FIRST PUMP!hG CYCLE IF AFTER THE TRANSFER IS COM-c 7 %.] [Q/ PLETED ALL THE LEVELS IN THE LINER ARE DEWATERED AS PER THIS PROCEDURE. h h occuass=r n ay, .g.,7 F0-UP-022 8 5 ,e_ t , J casso soovoas
, gs psm a. ? GF-4Q*'*** - - - . - - - - - - -
*+.+
i PC P-001
. Attachment i 4
Revision 4, Chg. A g' r Pace 6 of 10
.vt 3 x .-
4.0 UETAILED PROCEDURE
}
4.1 Installation Procedure t 4.1.1 Estabil>h or verify that the vessel is in a level gusi-tion (visual deteruination). 4.1.2 d Connect 3/4" hoses between the wonifold anu each of tne filter levels in the liner. The valves on the uanifold ak snall be nuubered 1 throu3h 4 with Huuoer I corre-j spending to tne bottom filters and 4 the hi 3hest. The hoses snail ce connected accoruin31 /. NOTE: 1
' IF USING A 6-80 LINER THERE ARE ONLY THREE FIL-TER LEVELS, THUS VALVE #4 IS NOT USED AND SHALL BE LEFT SHUT.
4.1.3 Connect the dewater puup suction hose (Para. 3.2.1.3) to tne outlet connection on tne valved manifold (Para. 3.2.1.1) and to the inlet of the uewater guug (Para. 3.2.1.1). .
; 4.1.4 *
! Connect one end of tiie cutlet hose (Para. 3.2.1.H to 3, 7 the outlet of the dewater puup (Para. 3.2.1), and oi-
), rect the otner end to the radwaste system.
V.. 4.1.5 Connect the service air hose (Para. 3.2.1.4) to the service air supply (Para. 3.2.2) and tne uewater pump (Para. 3.2.1). 4.1.6 Connect the liner level indication and control systeu
. (Para. 3.2.1.5) to the Ifner outlet Jacx and plug the panel into the uttifty supplied power source (Para. , 3.2.2).
4.1.7 Check that valves I, 2, 3, and 4 are closec. With the 9, - dewatering pump running, the vacuum reading shoula ce 3 20" Hg, or 3reater. A r 4.2 Transfer / Dewatering Procedure ns CAUTION: STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID, WHEN IN CONTACT WITH d" ORGANIC ION-EXCHANGE MATERIAL, MAY
)
7 PRODUCE A SLIGHTLY DEGRADED RESIN IN AN EXOTHERMIC REACTION, UP TO AN EXPLOSION. THE FIRST INDICATION OF
?i AN EXOTHERMIC REACTION DUE TO THE PRESENCE OF li OXIDIZING AGENTS IS SOME FUMING AND A SLIGHT RISE IN j TEMPERATURE ON THE OUTSIDE OF THE CONTAINER. IF THIS d CONDITION IS FOUND WHEN DEWATERING A VESSEL. THE j , IMMEDIATE ACTION TO BE TAXEN IS TO REFILL THE VESSEL h WITH WATER. THIS WILL DISSIPATE THE MAJORITY OF THE -i f3 HEAT, RETURNING THE TEMPERATURE OF THE YESSEL TO AMBIENT. THIS IS A STABLE CCNDITION. THEN, YOUR "I
h 'u'h IMMEDIATE SUPERVISOR MUST BE NOTIFIED. fP oocu e r a av. mur FO-UP-022 B L 6 c J creso toc 2/e 7e
. . _ . . - ~ -_
q__ _ _ , _ _ . _ _ _ _ . _ . - _ . _ - ~ - ~ ~ - I'i . g . . i t PC P-001 r Attachment I d " , . ,,C A Page 7 of 10
'it N)') NOTE:
WHEN RECEIVING WASTE SLURRY, DEWATERING IS REQUIRED IN l ORDER TO COMPACT THE RESIN IN THE LINER FOR PROPER
; DEWATERING AND IN ORDER TO PREVENT CHANNELING.
4.2.1 Be v in transferrin 3 the waste starry to the cewaterin, liner. 4.2.2. When the slurry level in the dewatering ifner is over
' ]l- the top of the second filter level, ensure that the ue-1 waterin3 pump is running and open valve nuuuers 1 and 2. ], NOTE: IF THE PCWDEX/ DIATOMACEOUS EARTH WASTE SLURRY i HAS A LOW SOLIDS CONTENT WHICH REQUIRES SEVERAL 3
CYCLES TO FILL THE LINER, VALVE NUH3ER I MAY BE q LEFT CLOSED TO PREVENT BLINDING OF THE FIRST FILTER LEVEL. NOTE: IF USING A 6-80 LINER THERE ARE ONLY 3 FILTER LEVELS, THUS VALVE #4 IS NOT USED AND SHALL BE LEFT SHUT. 4.2.3 Continue the waste slurry. As trie slurry level covers . i
.i the third and fourth filter levels, as indicated by the 3 level indication panel, open valve nuuuers 3 and 4. re -
g spectively (open #3 ff using a 6-80 liner). J!' (dj ~% 4.2.4 When the high level raonitur activates, stop the slurry transfer icuediately by calling the radwaste operator in the radwaste control rocu to have the slurry pump secured.
~
CAUTION: WASTE ADDED ABOYE THE HIGHEST FILTER LEVEL O WILL CAUSE THE WASTE LEVEL TO RISE AT AN IN-q CREASING RATE. EXTREME CAUTION HUST BE EX-ERCISED DURING FINAL WASTE ADDITION.
~
NOTE: DURING DEWATERING. THE WASTE SLURRY LEVEL
. WILL DECREASE, WHICH MAY REQUIRE RECEIVING 9 ADDITIONAL SLURRY TO CBTAIN THE DESIRED LEVEL. /} IT MAY TAXE AS LONG AS 8 HOURS TO M COMPLETELY FILL THE LINER DEFENDING ON THE h CRUD SATURATION LEVEL OF THE WASTE. DURING ij THE DEWATER CYCLE PRIOR TO REFILL. THE SOLIDS y LEVEL IN THE LINER SHOULD NOT BE UNCOVERED WITH WATER.
y IF COMPLETE FILLING REQUIRES MORE THAN 8 HOURS THE FILL CYCLE MAY BE }y HALTED PROVIDING THE SOLIO LEVEL IN THE CONTAINER IS LEFT COVERED WITH WATER. I j 4.2.5 Allow the cewater pump to run until there is enou3h room in the liner to receive a waste ifner flush, then flush the waste transfer ifne. See CAUTION and NUTE l]dl<~- iunediately above. ] d () occuess=T il F0-CP-022-mav. B swear 9 L _7 $j J 4 c,..a mm.= n
- - - - - ~ - * - - ~ ~ ~ ' ' ' ~ ~ ' ' ~ ~ ~ ~ ' '
f.' - _ _ _ . _- . . _ . . - . . . _ _ _ _ h-I
. L c
PCP-001 Attachment i rm Revision 4, Chg. A Pace 8 of 10
; v ')
t 4.2.6 Af ter a minimua pumping time of 30 minutes and the { vacuum readiny for level 4 drops below 4" H,
; 3 shut valve 4 (valve .3 f f using a 6-80 liner).
4.2.7 Repeat Step 4.2.6 for valve numbers 3 and 2 tvalve #2 ff using a 6-80 liner). 4.2.8 Repeat Step 4.2.6 for valve number 1, or a miniuuu of a
- hours total pumping time for all 4 levels (3 levels if
.i usin3 a G-80 liner), wnichever is greater. Secure tne dewatering pump, close valve 1.
h 4.2.9 Allow the container to stand for a uinimum of 16 hours. i 4.2.10 Reestablish service air to the dewaterin3 pump (Valves
#4, 3, 2 and 1 shall be shut). With the dewatering pump running, the master vacuum reading should be 20" Hg or greater.
4.2.11 Dewater with all four valves open (three if usin3 a g 6-80 liner) for a miniaun of 8 additional hours, per" 5 Steps 4.2.6 throu3h 4.2.8. .
, , 4.2.12 Repeat Step 4.2.9.
; 4.2.13 i<epeat Step 4.2.10.
4.2.14 Repeat Step 4.2.11. 4.2.15 Secure the cewaterin3 pump. 4.2.16 Jisconnect the waste transfer line, the 3/4" dewater
.j hoses and the level indication panel Jacx on the liner.
o 4.2.17 Close and seal the liner. 5.0 RECORDS J q Confiru that the Dewatering Completion Record is accurate and in coa-y pliance with the dewatering procedure, then forward the orfyinal to the utility's Rauwaste Surgervisor. The technician shall retain a copy for l4, their records.
- l -
r; J d ' n h F 4; j g j j, (U * % DOCUedENT 4.. F0-0P-022 "') 8 J a
, , . , , ~ , -
,_ , , . . . . . . . ~ . . - - - - - - - - - - - - - * " ' ~ ' ' ~ ~ * ~ * ~ ~ ~ ^ ' ~' '
. I PC P-001 Attachment i Revision 4, Chg. A r a ,, , in n . -.
m FIGURE 1 Dewatering Comaletion Record i Ecodex Precoat/Powdex/ Diatomaceous Earth Dewaterin9 Procedure i For 14-195 or Smaller Liners Containers j Customer: Plant: Liner Serial Number:
-f
~
NOTE: i IF USING A 6-80 LINER THERE ARE ONLY 3 FILTER LEVELS, THUS VALVE f4 IS NOT USED AND WILL BE LEFT SHUT.
) F0-0P-022 l Proc. Step Deseription D4te 't "H9 Tice CitSI Operator
{ 4.2.2 Start Dewatering Pump
; 4.2.6 Close Valve #4 4.2.7 Close Valve #3
~
Close Valve #2
.s
(" 4.2.8 Close Valve il (total pumpin3 time must be a minimum of 8 hours) 4.2.10 Start Dewatering Puup
')
(after minimum 16 hours stand) l 4.2.11
,d Close Valve #4
- - t 3 Close Valve #3 31 .
Close Valve #2 1 Close Valve #1 (total pumping time must p(.] be a minimum of 8 hours) s 4.2.13 Start Dewatering Pump r (after minimum 16 hours stand) 3 3 4 li^
}m L-ti v kj oocuusNT 0 mav.
FO-0P-022 sussT L B 9 J casso tocam 7s S ________.__________._________________.__.____._____________.____.________.___._________._______._________________________._m_____.. _ _ _ _ _ _ _ _ . _ _ . _ _
! ., , . . . . .11 I
i PCP-001 j Attachment I
; K, r Revision 4, Chg. A Page auor au 3 l % ..]
I FIGURE 1 (Continued) 4 Dewatering Completion Record Ecodex Precoat/Powdex/ Diatomaceous Earth Cewatering Procedure For 14-195 or Smaller Liners Containers
)
1 Customer: Plant: i .j Liner Serial Number: NOTE: IF USING A'6-80 LINER TliERE ARE ONLY 3 FILTER LEVELS, THUS VALVE
#4 IS NOT USED AND WILL BE LEFT SHUT.
i it FO-0P-022
'l, Proc. Step Description "Hs _ Date Time CNSI Operator 4.2.14 Close Valve #4 Close Valve #3 .-j .
Close Yalve f2 Close Valve #1 (total pumping time must j be a minimum of 8 hours) , Cotr,ents:
)
i
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'._l s 3
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) }. . PCP-001 i
1 Attachment il _ . . . , aw t m r a Evisio~s Page 1 Of 9
# l
)' DATE
- \ SRB APPROVA] A E V. DESCRIPTION . - - APPROVED i
' ~
h3 % 3* ,A OLWES ?E" CU.WF "U"W IS=0WW !', ? O , 1 2 j 1 j . j
'%)m
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. ras n .m e rn:('Ru-- A 9Y I\FCE:.~:U.~Cu'l CNSI SAFET( REVIEW , , 7: f '; COCUMEN T Cr)NTQN3 p - ?
dCARD APPROV6I_ N, i i
- , w 710N /NG i : cor to E.. E SY /f.[/',DO/fla;) . ,
COFl.0 WITHOUT TH2 WRITT1: . ,_, g,;: . o.: '
..,i DATE ;A ' 9 '-8)/ OF CHEM. NUCLE /R SYSTEMS, a40.
Hi aEnsOistarus a jj sa:E7 I 2 3 4 5 6 7 8 9 t
'j REV. A A A A .\ A A A A ] sHEtt
- )
R E v. ? PREPARED CATE loi .. th y y CHEM - NUCLEAR SYSTEMS, ING. d ***a++ 4u/di rittE
, ' MN *T4 ' ' //Iy/f /
! ~,' E m
, i B1MD DlMATI: RING PROCE111HJI FOR g
C/ / , QUALITY 7Y ' CNSI 14-195 OR S4tl. LIM l.INERS l 4N'Y!!A I-M-91 q 2[ /4(- 3Y [ . m S [>."n h 4 i
1
!* PC P-001 i
Attachment 11 r a v i a 'u i- I y Pa9e 2 of 9' C!'"q ^ I I " - 4 TABLE OF CONTENTS PAGE NO. i 1.0 SCCPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 I.1 Purpose . . ..................... 3 j 1.2 Applicability .................... 3 1
2.0 REFERENCES
. . . . ..................... 3
)
- 3.0 REQUIREMENTS . . . ..................... 3 e
i 3.1 . Prerequisites .................... 3
~j-3.2 Equipment and Interfaces . . . . . . . . . . . . . . . .
3 3.3 Safety . . . . . . . . . . . . . . . . . . . . . . . . . 4 4.0 ACCEPTANCE CRITERIA . . . . . . . . . . . . . . . . . . . . . 5 4.1 1% Free-Standing Water or Less . . . . . . . . . . . . 5 i 4.2 0.5% Free-Standing Water or Less . . . . . . . . . . . 5 - 1 1 i 5.0 CPER ATING PROCEDURE . . . . . . . . . . . . . . . . . . . . . 5 4' M 5.1 Installation Procedure . . . . . . . . . . . . . . . .
- !(d/ \ 5.2 Transfer / Dewatering Procedure . . . . . . . . . . . .
5 6 6.0 RECORDS . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 FIGURE I - Dewatering Completion Record . . . . . . . . . . . . . . 9 a,
)
i r u-a l .1 h w' 5 1 Rj .--* l c) q j . i [%. 1; h) '3 . y A / Je '
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- j oocwur n a v. meer F0-0P-023 A 2
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'] ; PC P-001 j Attachment 11
- l. ' Revision 14, Chg. A r
Page 3 of 9 3 g i 1.0 SCOPE i 1.I Purpose
]
Inis operating procedure is for dewatering only bead resin in CNSI 14-195 or smaller liners. The procedure has been tested per the referenced documents for certification in ceet in.j the
; Barnwell Site Disposal Criteria and Hanford Site Criteria for
- free-standing liquids.
i. j 1.2 Appl icab ility
} Ine instructions contained in this procedure apply to cewaterin3 3 CNSI's 14-195 or smaller liners containing bead-type ion ex-j change resins with less than 1% oil.
2.0 REFERENCES
~
2.1 CHSI Procedure, CN-AD-003, " Procedure for Document Preparation" 2.2 CNSI Procedure, CN-AD-019. " Chem-Nuclear (CNSI) ALARA Policy" , j 2.3 ChSI Procedure, EN-AD-002, " Design Control Procedure" -
'l l s g 2.4 CNSI Procedure, QA-AD-001, " Quality Assurance Prograu a b'
2.5 Ct.SI Drawin9, B-371-E-0001, " Bead Resin Dewater HIC / Steel Liner i Assercly" l 2.6 State of South Carolina Radioactive ltaterial License No. 097 2.7 Test Data and Procedures for Engineering Project No.11118
'i 2 3.0 REQUIREMENTS 'l 3.1 , Prerequisites L 3.I.1 Obtain a Radiation Work Permit (or equivalent) from the y .
utility's Health Physics Department before entering the [ _ process area. k I 3.1.2 j The utility's Health Physics personnel snali perforu radiation level and surface con'tamination surveys. 1 Frequency of the survey is to be deterwined by the j utility. Results of these surveys shall be recorded on
- p. the Daily Operations Log as a permanent record.
. .I
'a j 3.1.3 Note the completion of ' prerequisites in the Daily
~
ij . Operations Log. j A 3.2 Equipment and Interfaces
~
L 3.2.1 The following equipment will be required for' dewatering - operations: - 2 DOCUMENT RE V. l- F0-0P-023 A SHEET 3
~ ,. - -. - - . _ - - ~ . ~ ~ . , . , . . , . . . , ,2._.... . . -
T..._.. i _i_ 1._ Z, i .j . Ci
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4 PC P-001 Attachment 11 onorann 4. Cho.A 4 , F Page 4 of 9 3 i- . 3.2.1.1 One air driven diaphra3m I-1/2" puop with j 1-1/2" FnPT connections, 1/2" FhPT air inlet l or equivalent.
; 3.2.1.2 Connecting Hoses (1-1/2" non-collapsible) f 3.2.1.2.1 Outlet hose for the dewater pump j (Para. 3.2.1.1).
1 3 3.2.1.2.2 Suction hose to connect between
, the pump inlet and liner outlet "1 connection (1-1/2" male quick 3
connect). (i , 3.2.1.3 Service air hose (1/2", 150 psi) with hose
, claup to connect to the dewater puup (Para.
.i. - 3.2.1.4) and 3/4", .150 psi coupler to con-nect to the service air supply. 3.2.1.4 Service Air: 20 SCFM at 80 +20 -10 PSIG. l
;. 3.3 Safety H '
3.3.1 Industrial Safety Requirements CAUTION: HOSES AND OTHER PRESSURE RETAINING COPPO-3 NENTS MAY BE PRESSURIZED. FACE SHIELDS AND APPROPRIATE PROTECTIVE CLOTHING MUST BE WORN DURING DISASSEMBLY OF THIS EQUIPMENT. 3.3.1.1 Strong oxidizing agents such as nitric acid, 1 when in contact with organic ion-exchange 3 caterial, may produce a slightly degraded 1 resin in an exothermic reaction, up to an d explosion. 4 8 3.3.1.2 The CNSI technician (s) shall inspect and
- j. use, as appropriate, protective clothing, M safety glasses,- chemical splash goggles, y face shield, hard hat, shoes, gloves and/or respirator while working within five feet of-
- ')i the process equipment. Know wnere the Fi closest eye wash and safety sho-er are~and how to use them.
4 5 3.3.1.3 When using a straight ladder it must be tied h at the top and/or held at the - bottom by a co-worker. $y . 1.~ FA
'i j /N x
V( - ft - 1 i, DOCWENT R E V. SHEET 7 F0-0P-023 A 4 b J
_ _ _ _. .__.__._._.m_. _ _ _ _ _ . _ PCP-001 r Attachment 11 _ K ev t = w" ', m Page 5 of 9
.( t-3.3.2 Radiological Safety 3.3.2.1 The CNSI technician (s) shall follow proper radiological precautions at all times to e minimize the spread of contauination and to limit personal exposure to ionizing radiation.
i 3.3.2.2 ^l The CNSI technician (s) shall wear dosimetry 4 equipment and protective clothing as spect-i fied by the Radiation Work Permit or equiva-lent during all operations of the process equipment. 4.0 ACCEPTANCE CRITERIA 1
]: 4.1 1% Free-Standing Water or Less After a minimum of two pumpin9 cycles, a measured volume of less than five (5) gallons on the next eight (8) hours of pumping shal: be the acceptance criteria. If five (S) gallons or more are collected, th~e waiting / pumping cycle shall be repeated until less than five (S) gallons are collected. -
4.2 0.5% Free-standing Water or Less ~
.] (q) After a minimum of five pumping cycles, a ceasured volume of q v[
1 less than two. (2) gallons on the next eight (8) hours of pumping shall be the acceptance criteria. If two (2) gallons or more 3 are collected, the waiting / pumping cycle shall be repeated until less than two (2) sallons are collected. NOTE: j THE FINAL TRANSFER / DEWATERING CYCLE SHALL BE COUNTED AS
.l THE FIRST PUMPING CYCLE IF AFTER THE TRANSFER IS COM-PLETED THE LINER IS DEWATERED AS PER THIS PROCEDURE.
5.0
],
OPERATING PROCEDURE
,1
;l CAUTION:SURIZED.HOSES AND OTHER PRESSURE RETAINING COMPONENTS MAY BE PRES-FACE SHIELDS AND APPROPRIATE PROTECTIVE CLOTHING
~
SHALL BE WORN DURING DISASSEMBLY OF THIS EQUIPMENT. CAUTION: THE RESINS CONTAINED IN THE LINER WILL BE RADI0 ACTIVE AND THE
]y VESSEL MAY BE CONTAMINATED. THE OPERATOR SHALL FOLLOW PROPER c RADIOLOGICAL PRECAUTIONS WHILE MAKING HOSE CCNNECTIONS AND DEWATERING THE VESSEL.
6 Y CAUTION: STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID, WHEN IN CONTACT
$ WITH ORGANIC ION-EXCHANGE MATERIAL, MAY PRODUCE A SLIGHTLY 1 DEGRADED RESIN IN AN EXOTHERMIC REACTION, UP TO AN EXPLOSION.
o
; 5.1 Installation Procedure
[ NOTE: INSTALLATION SHALL BE SITE SPECIFIC EXCEPT AS FOLLOWS: q.j DOCUWN T FO-0P-023 " d 5 t
)
*~~'~,
-~~ . - - - - . - - -. - -.-. . - - . - - - -...- .
- PCP-001
} Attachment ll F R nvkion 4, Chq. A Page 6 of 9 3
,\(
l8 ' 5.1.1
' Establish or verify that the liner is in a level posi-tion (visual deternination).
5.1.2 Connec t the suction hose (Para. 3.2.1.2.2) to the ou tlet connec ti or, in the liner and to the suction of the positive-displacement pums (Para. 3.2.1.1). NOTE: IF SECONDARY DEWATERING OUTLET IS PROVIDED, i i ENSURE THAT IT IS CAPPED PRIOR TO DEWATERING i THE LINER. 5.1.3 Connect one end of the outlet hose (Para. 3.2.1.2.1) to the discharge of the positive-displacement pump (Para. 3.2.1.1), and direct the other end as instructed by the utility. o a S.1.4 Connect the service air hose (Para. 3.2.1.3) to the service air supply (Para. 3.2.1.4) and the tositive-displ acement pump (Para. 3. 2.1.1 ). q 5.1.5 Make the necessary valve lineups to guarantee a free, j path to the liner. ~ m j 5.2 Transfer / Dewatering Procedure j (d' CAUTION: STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID, WHEN IN CONTACT WITH ORGANIC ION-EXCHANGE MATERIAL, MAY PRO-DUCE A SLIGHTLY DEGRADED RESIN IN Ak EXOTHERMIC REAC-TION, UP TO AN EXPLOSION. THE FIRST INDICATION OF AN EXOTHERMIC REACTION DUE TO THE PRESENCE OF OXIDIZING
! AGENTS IS SOME FUMING AND A SLIGHT RISE- IN TEMPERA-4 TURE ON THE OUTSIDE OF THE CONTAINER. IF THIS CONDI-TION IS FOUND WHEN DEWATERING A VESSEL, THE IMMEDIATE ACTION TO BE TAXEN IS TO REFILL THE VESSEL WITH WA-l TER. THIS WILL DISSIPATE THE MAJORITY OF THE HEAT, '; RETURNING THE TEMPERATURE OF THE VESSEL TO '9BIENT.
W THEN YOUR IMMEDIATE SUPERVISOR OR MANAGER MUST BE NOTIFIED. d.
'? 5.2.1 Establish service air to the pump. Adj us t the pump air supply valve to establish a minimum pumping rate of 2 strokes per second and en ter the time in the operating log and the Dewatering Completion Record (Figure 1),
ij NOTE: VERIFY THAT THE PUMP IS PUMPING WATER
;;.j 1 THROUGH THE USE OF THE PRESSURE GAUGE ON VE DISCHARGE SIDE OF THE PUMP OR OTHER APFko-PRIATE MEANS.
L 3 5.2.2 If applicable, begin transferring the bead resin
,t slurry to the dewatering liner. If not, proceed to ,?
( () v Step 5.2.7 . [4 H [ DOCUMENT REV. SHEET 1) FO-0P-023 A 6 s %
4
.. = -. - W - . - . . . - - . - . - . . . . .
j ' i, ' i PCP-001
] Attachment 11 i
F o m w ., ,1 rhn A
}g- '
, t P'a'ge 7 of 9 i (Q{ ./
r 5.2.3 When the high level monitor activates, stop the
) slurry transfer immediately.
' 5.2.4 Continue dewatering until the level alarm has cleared or until visual observa tion can be made to ensure that more resin can be received.
5.2.5 If more resin can be transferred to the liner, repeat steps 5.2.2 through 5.2.4 1 5.2.6 After the liner has been . filled with resin and the alarm has cleared or visual observation verifies that there is room for a flush, flush all trans fer lines j and continue dewatering per steps 5.2.7 through 5,2,13
' 5.2.7 Continue pumping for a minimum of eight (8) hours, then shut off the pump. Enter the shut-off time in the operating log and the Dewatering Completion Record.
- 5. 2. 8 Let the vessel stand for a minimum of eight (8) hours. .
q 5.2.9 Repeat Steps 5.2.1 and 5.2.7 1 1 V),) 5.2.10
. Let the vessel stand for a minimum of eight (8) hours.
NOTE: IF SECONDARY DEVATERING OUTLET IS PROVIDED, DISCONNECT THE SUCTION HOSE FROM THE PRIMARY DEWATERING OUTLET AND CONNECT THE HOSE TO THE SECONDARY DEWATERING OUTLET. Ek NOTE:
<I ENSURE THAT THE PRIMARY DEWATERING OUTLET IS CAPPED BEFORE PROCEEDING WITH THE. DEWATERING - OPERATION.
3 5.2.11 Secure the pump discharge hose to a bucket or 55-gal- ,] lon drum. q 5.2.12 Start the dewatering pump per Step 5.2.1, 3 5.2.13 j~ Pump for a minimum of eight (8) hours and measure the water collected. If acceptable to the applicable acceptance criteria, proceed with Step 5.2.14 If not acceptable to the applicable acceptance criteria, let the vessel stand for a minimum of eight (8) hour ( and repeat Steps 5.2.11 through 5.2.13. R' NOTE: b AFTER THE FINAL PUMPING CYCLE IT IS NOT lp NECESSARY TO LET THE LINER SIT FOR EIGHT (8) HOURS PRIOR TO PROCEEDING WITH STEP 5.2.14 1)0)1
%d
/ ,
F D f DOCUMENT 1, REV. SHEET FO-OP-023 A 7
y- ,~ . . -. -- - - . - - - . - . - . .. -
'{ ,
PC P-001 g- Attachnient 11
) Keviswa +, Ciib . .k i
} } Page 8 of 9 5.2.14 Disconnect the suction hose from connection of the liner.
the outlet ! a 5.2.15 Close and seal the liner. a l' 6.0 4 L RECORDS r i (
.; Confirm that the completed Dewatering Completion Record is accurate and 11 in compliance to with the dewatering the utility's Radwaste Supervisor. procedure, then forward the original ;
for his records. The operator shall retain a copy
.i
.t
'l
'6 .
i 5 # h i
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t P 4 i q a 6 4 b' y q s .Lj y : i p . t t n . L occu o.1 '? FO-0P-023 aiv. ar A 8
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.i PC P- 001 j . Attachment 11
; ( %;p., y e hg A i( ^ TT Page 9 of 9 iVJ FIGURE 1
.t 4 -
! Bead Dewatering Procedure for CNSI 14-195 or Smaller Liners Customer:
Plant: Vessel Serial Number: Yessel Type: 1 FO-0P-023
.i Proc. Step Description Date Time Ocera tor 5.2.1 Start Dewatering Pump - ! 5.2.7 Secure Dewatering Pump Total Pumping Time
- 5.2.8 Let Vessel Stand for a minimum of 8 Hours
- 5. 2. 9 Start Dewatering Pump Secure Dewatering Pump l Total Pumping Time *
- l g) 5.2.10 Let Vessel Stand for a minimum of 8 Hours (b NOTE: INDICATE IF SECONDARY DEVATERING LEG EMPLOYED Yes No 5.2.12 Start Dewatering Pump Secure Dewatering Pump Total Pumping Tine
- S 5.2.13 Volume of ' dater j
Collected gals ** q I l, Let Vessel Stand for a Minimum of 8 Hours 3 Dewatered to 0.St, / 1.01, ~] frfrcle One) b j Comments: U PUMPING TIME MUST BE A MINIHLN OF 8 HOURS l- ** If gallons collected exceed acceptance criteria repeat 5.2.11 through
.. s_) t 5.2.13 and record data on back side of this form.
O f[j oocuveur n a y. gaggy $5. .-] t FO-09-023 A 9 ^. - . - - . . - . 7 ,- - - ~ , , ,.
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f,' . . PCP-001 REVISION 4 3; .. ( ATTACHMENT III . mevisiones PAGE 1 0F 28 gg, 4pqq R E V. DE ECasPficae DATE l l an,404to
}
A Cot-elete Reurite 6 /2I. f 61 .l B Incorporate Channes 9/11/81 h [s l Comclete Fevrite O/dh O C 9/29/81 M, Incorporate Ch..nre Far Cl.ance 10/20/91 ^^ .3 - ' MI o n...... r er.nv.ne,.nn i E Inctn porate Chanen Per Change Request , 1/08/S2 8 -
*SD-& -00: W ., / !!
F Incorperate Chantes Per Change J/z h/f k 3. *6 h I I
= _ . - . . . - esne.nn1 ns -, t G C-A . 5 7.: C-w:. E S. 033-06
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FOR INFORMATION ONL1 PAGE 2 0F 28 TABLE OF CDNTENTS REVISION .4 PACE NO.
10 S CO P E . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.1 Purpose . . ... .................. 3 1.2 Applicability . ................... 3 2.0 RITEREN CIS ......................... 3
. . ................... 4 3.0 SYSTIM DESCRIPTION Process Description ................. 4 3.1 4
3.2 Process Para =eters . . . . . . . . . . . . . . . . . . 4 3.3 Solidifi.ation Unit Descriptica ........... 3.4 System Operation . . . . . . . . . . . . . . . . . . . 5 6 4.0 RE CUIR EMENTS FOR S AMPLE TESTING . . . . . . . . . . . . . . . 4.1 General Precautions ................. 6 6 l' 4.2 Radicic;ical Pre:auti::: . ............., 4.3 Prer equisi t e s ..... . .............. 6 4.4 Sample Acceptance Crit eria . . . . . . . . . . . . . . 8 4.5 Require =ents For Sa=ple Verification . . . . . . . . . 8 5.0 TIST DOCUMENTATION . . ................... 8 6.0 ADMIN IS TRATIVE PRO CEOCRIS . . . . . . . . . . . . . . . . . . 9 TA2LI 1 - Equipment Reect= ended Per Testing Sa=ple . ........ 10 !'
):
FIGURE 1 - PCP Solidification of 3eric Acid Concentrates (N-24, Cement, L1=e Sequence for FWR Waste) . . . . . . ... 11 l' t FICORE 1-A - PCP Selidificatien of 3eric Acid Concentrates (Lise, Cese nt Sequence fer PVR Vaste) . . . . . . . . . . . . 13 FIGURE 2 - PCP Solidification of Particulate Vastes (Resin Beads Powdex and Dist::accous Earth Slurries) ....... 16 FIGURE 3 - PCP Solidification of Sulf ate Cencentrates (BVR Vastes . .......................... 18 . PIGURE 4 - PCP Solidification of Miscellaneous Aqueous
- Wastes . .......................... 20 PIGURE 5 - Liner and Cask Calcula tions . . . . . . . . . . . . . . . 22 FIGURE 6 - PCF for Preparation of Fluid Mixture for In-Situ Solidifications . . . . . . . . . . . . . .'. . . . . . . . . 23 00ctaasW7 #8 V. De8ET SD-OP-003 N 2 J
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10 segPE i 1.1 Purpose l The purpose of the Process Control Program for CNSI ig Coment idification Units is to establish processing conditions assu resins, concentrated 1 l aafe and effectiveliquids and slurries includingProduced by PWR and tive vaste liquids, and the various filter aludge8 utilities. 1.2 Appliesbility This Process Control Program shall beThis used by all ispersonnel o procedure erating the CNSI Cement Solidifiestion Unit. h 21-300. applicsble to all liners listed on Figure 5 except t e
2.0 REFERENCES
CNSI Procedure, CA-AD-001, " quality Assurance Program 21 " 22 CNSI Procedure, CN-AD-019,
- Chem-Nuclear (CNSI) A1.AEA P f'
i CNSI Procedure EN-AD-002, " Design Control Procedure" $
- 2. 3 Solidification Units, as :
2.4 CNSI Operating Procedures for Cement applicable for i Technical Specifications 2.5 NUREC-0472, " Radiological Ef fluent PWR" for Technical Specificatices 2.6 .NUREC-0473, *Radielegical Ef fluent 3*="A ~ Selid 3 ranch Technical Pesitice-ESI3 11-3, " Design Installed cuidance for in Light-Water-2.7 Waste hausgesent Systems Radioactive Cooled Nuclear Power Reactor Plants" 2.8 ANSI N199, *I.f quid Radioactive Waste Processing System fo surized Water Reactor Plants" ANSI N197, "I.1guid Radioactive Water Processing Syste=s Ter 2.9 Boiling Water Reactor Plants
- 2.10 NRC Regulatory Guide 1.143, " Design Guides Installed for Radioactiv in Management Syste=s, Structures, and Components
- Light-Water-Cooled Nuclear Power Plants 12th Edition, Portland 2.11 Design and Control of Concrete Mixtures, Cement Association.
AEV. meEST 3 N J 9 0E M asart 50-0P-003
- esano tassa a I . . _ _ -
j . .. . g i . r PCP-001
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3.0 SYSTZN DESCRIPTIFi \ INFORMATION ONLY REVISION 4 EEc 3.1 Process Description _ The CNSI Cesent Solidification Unit is specifically designed to facilitate solidification of various radioactive vastes includ-ing evaporator bottons and ion exchange resin slurries and aludges. Ismobilization of the vaste is accomplished using readily avail- 4 able Portland I Cement in conjunction with hydrated line and particular process additives. Other Fortland Cements, Types II ; and III, may be employed for specific waste handling conditions The requiring controlled modifications of cement activity. vaste is solidified in a disposable liner which say already con-tain some of the required conditioning chemicals. Pre-installed j sixer blades pe r=it continuous agitation until a thick cement paste has formed that will set to a hard, uniform, water-f ree matrix. The end product is a true cement ettucture formed in accord with established principles of concrete technology. i' 3.2 Process Parameters I. , Portland Type I Cement combines with water througn several in- < termediate reactions to form stable hydrates from chemically combined mixtures of calcium, silicon, aluminum, and iron ox- 1 ides. These reactions are axothenaic (heat producing) and do not progress rapidly unless a strongly alkaline pH (11-12) is maintained. L'a s t e stres=s may contain certain metallic radio-nuclides that are chemically bonded (and not leached) in the-ce ent structure without loss of product strength. Other con-stituents can significantly accelerate or retard cement set, and must be contrelled by the addition of selected che:ical agents. Judicious control of total cement content eaxi=1res vaste volu e ef ficiency and minimites heat deve'opment for large volu=e s c 1=- idifications. Preferred vaste to additive solidification ratios have been deter _ iced by the CNSI Research and Development Pro-l gra=, but it is recognized that vaste streat eczpositten and l ' density are varistle, and that verification of the solidifica-tion forcula is necessary for each new lot of vaste 11guld. i This ieportant consideration is detailed by waste form in Fig-ures 1 through I.. 1 . l > 3.3 Solidifiestion t' eft Des cription 3 3.1 Ihe CNSI Cement solidification Unit is a porta ble sys-tem coetsining all pip'ing , support, control and soni-toring equipment necessary to solidify radioactive 11-quid waste using the cement process. O t s
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ED-CP-003 , N L sesoc vanas to n , ~ _
Fon INFORMATION ONQ PCP-001 3 [ r ATTACHMENT III PAGE 5 CF 28 REVISION 4 g 332 The unit is composed of several processing subsystems, each controlling a specific function of the cement pro-casa. The subsystems include vasts transfer, chemical addition, cement conveyor, vent, and dewater systems. Control functions for the unit are incorporated into the pneumatic and main cootrols panels. Service sup- , plies are provided by the utility and distributed through the service air, water, and electrical distri- ; bution systess. 3.3.3 Most of the unit components are arranged on portable frameworks (skids) to provide flexibility of operations for either indoor or outdoor use. The cadent conveyor, control panel, pu=p skid , hydraulic skid sed fillhead contain =ost of the major elensets of the mobile unit. 3.3.6 A closed-circuit television system is en integrsi part of the unit and allows the operator to monitor the sol-idification process. 3.4 Systec 0;eration 3.4 1 Before leginning any vaste processi:t vith the Cement Solidificatier Unit, the CNSI operator shall complete a j successful sa:ple solidificatice in accordance with the ! I Sa=ple Verification Procedure of Section 5.0. 3.4.2 The sasple solidification infer:ation is recorded on a CNSI Solidification Worksheet, and is used in conjuc- , tion with Figures 4 through 5 t= calculate full scale ' values.
'3.4.3 Actual vaste solidifications shall then be conducted in accordance with the Crerating Procedures (Ref. 2.4) using full scale fer ulas as calculated on CNSI Sclidi-fication Ucrksheets.
3.4.4 Sequeece ef Operation
'The conditiening che=1cals may be preloaded, in so=e cases, inte the liner or added to the vaste while mix- -
ing. 75e addition of che: cals or vaste usually =ay be interrupted without ill effect. The mixer may also be secured during vaste or che:ical addition with no ef-feet on the process, but sust remain in operation dur-ing these additions necessary for proper solidification. l J esv. mess 7 assament SD-CP-OO3 p 5 J L sasse stat 1B M ~_ .- . , , - 1- - -
,NFORnliATION ONLY l
yJR 3 F PCP-001 ATTACHMENT III PAGE 6 0F 23 3.4.5 We s t e-t o-C,sent Ratio _(by volume) REVISION 4 The normal volume ratio of vaste to eclidification con-penents will be approximately 2 to I up to 3 to 1 for evaporator concentrates and other liquids and 2.5 to 1 f or resins, powder and other solids. If recommended ratios are exceeded, cure time say be delayed and there may be residual f ree-standing liquid in the vessel af-cer solidification. 3 4.E Cure ~1me Cure time will usually be 12 to 36 hours as shown by a continuing temperatura rise. The liner should be ven-tilated until temperature begins to decrease indicating safe coupletion of the solidification process. 4.0 RE ct!RDdENTS FOR SAw?LE TESTING 4.1 Ceneral Precautiens 4.1 1 Ite chemicals and cement used are considered non-toxic . and safe to Land 1= , *w.e ver, care sn:ul: be =ted :: avoid breathing dust. If a liquid caustic is used for special applicatiens, follow the safety precautions outlined in th,e appropriate operating procedure, Ref.
' 2.4. lt f '
NC3: 17 ^ DIFFICULTIIS ARI INCDCNTIRED WITH ANY
- FART OF THIS VERITICATICN PROCZDTRE CR ChTX-PECTED RESU'TS ARI OgTAINED. CONTACT THE l SOLIt!TICATION MANAGER OR SCpERVISOR. j 4.2 Radielce! cal Precautiens I 4.2.1 "he C55 operater shall be subject tc the applicable : ;
Health Physics and safety precautions of the facility 1 providing the radicactive waste. 4.2.2 'La bora t ory g",c ve s , face shield and an apron shall be , wcrn while handling, collecting and testing of all sa:- l i ples. ! 4.2.3 The CNSI operator shall ensure that radiologically clean and contasiested zones are established in the e ' sample process ares to prevent the pessible spread of c=ntamination. I 4.3 Prerequisites t i
- 4. 3.1 Waste Recirculation 4.3 1.1 Due to the importance of obtaining a repre-I sentative sasple for use in the Asw. setET gets.aases7 SD-CP-003 N 6 L J <
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( PCP-001' PAGE 7 0F 22 ATTACHMENT III REVISION 4 verification procedure, the waste generating ,
, facility personnel shall confirm that the contents cf the waste storage tank have
#s either been recirculated for a minimum of three volume turnovers or are adequately a1xed to achieve a homo,geneous mixture.
- 4. 3.1. 2 Any number of sechanical operations of the waste storage tank may negate the effects of previous recirculation / agitation period.
These operations would include the fellowing: 4.3.1.2.1 Introduction of additional vaste into the storage tank after re-circulation has commenced. 4.3.1.2.2 Securing of recirculation while dravicg the verification sample.
- 4. 3.1. 2. 3 Shifting from a recircultaion mode to a transfer mode.
. . 4.3.1.3 If any of the situatiene listed ekva occur, ,
it will be necessary to repeat the recircu-lation process and sample verification pro- , cedure of Section 5.0 in order to re-estab-lish the solidification process parameters. 4.3.2 L'a s t e Id ee ti fi ca tion
- 4. 3. 2.1 The utility supplying waste shall provide vaste coupesition and properties. The CNSI ,
operator may confirm vaste Jensity and pH as necessary. Non: WASTE CYEING OIL ABOVI ONE PERCENT BY TOLDfE SEALL NOT BE SOLIDITIED RY THIS PCP. 4.3.3 Equip ent Iquipeent required to use durica the sample verifica- l tion precedure is listed 1u Table 1. The ta ble indi- - cate the recom= ended quantity to begic a verificarica , procedure. De CNSI operator shall ensure that all nece s sa ry ) equipment is available or edequate substitutes are i a vaila ble. The CNSI operator shall essure that additives received
. comply with the chemical composition necessary for this j process. !
. l
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- ATTACHMENT III J E 8 0F 28 4.4 Sample Acceptance criteria REVISION 4 De sample verification is performed by examination of lab com-positions containing actual vaste saterial. De test confirms the correct process constituents. The acceptacce criteria for a good product are as follows:
4.4.1 visual inspection of the end product af ter solidifica-
.h tion indicates a uniform, dry, free-standing monolith.
-v' ne end product resits penetration when probed with a
;.a 4.4.2 spatuala or other firm object.
4.5 tequirements fer Sample verification q (3 4.5.1 Verify that all materials listed in Table 1 are avail-
- able and ready to use in the area selected by the util-b- ity for solidification testing.
T 4.5.2 3e prepared to complete the test procedures outlined yigures 1 through 4, as applicable, when conducting 7% F- sample verifications. I Q . 4.5.3 Sa=;Ie Require =ents 2O
- 4.5.3.1 A sa=ple shall be solidified prior to full scale solidification of waste. If there is D no change in the che:ieal composition of the O
14, waste as verified by the utility, 4.3.1) test results and full scale solidifi-(Ref. cations will be considered reproducible. Thereafter, a sa:ple solidificatien will be conducted prior to the tenth ba t ch solidi-fied f roc the sa=e source of vaste. 4.5.3.2 ne CNSI operator shall ensure, as =uch as possible, that the test sample is represen-tative (i.e., thcroughly mixed) and that the sample line has been properly purged prior to drawing the PCP sa=ple. 5.0 SST DOC *.?.ENTATION 5.1 Calculate and record the required test information on the CNSI Solidification 'Jorksheets for all waste sa=ple verifications. 5.2 Use the appropriate figure (1 through 5) for test instructions and documentation for the various waste for=s to be solidified. OS goctassest Es V. messT SD-CP-003 N 8 J L sense senz.s a m
I i . . . PCP-001
' i r
ATTACHMENT III
! PAGE 9 0F 28 REVISION 4
. 6.0 ADMINISTR.ATIVE PROCEDERIS 6.1 De CNSI operator shall forward a copy of each completed CNSI Soldification Workaheet to the Manager, Solidification Services for review following coupletion of liner solidification.
6.2 De CNSI Solidification Worksheets and related instruction sheets are considered as proprietary information and not to be distributed outside of Chem-Nuclear Systems, Inc. Ea ch CNSI operator shall maintain a controlled file of these documents for his own reference. i i i q\0N OMd FOR \NE i 1 O % per? ASV. DestT SDH)P-003 II 9 i J esseetests M
j , t 3 r- PCP-001 ATTACHMENT III A 0 0F 28 TABLE 1 REVISION 4 ECUI? MENT RECD'?.INDED TOR TESTINC SAMPLE 250 ML Flastie Beakers With tids (12) ' Solidification chemicals should 600-1000 XL Plastic Centainers (12) be the same as used in full Wide Blade Spatula (2) scale operation and should be 0,2120 Tahrenheit Therneseters (3) stored in capped containers. pH Paper: Vide Range (0 To,9.0) Marrow Range (9.0 to 13.0) , 0-600 or 0-1000 gu Triple Beam Balance Hydreseters, Range 1.000 - 1.200 and 1.200 - 1.400, or egluivalent Hot Plate, variable Te=perature Control Pyrex Beakers, 600 ML Capacity (12) ' Marking Pen Sample Eesting Oven, Thermostatically Controlled Tron'1000 F to 1800 F. (See NOTE) Graduated Cylinders, 250 ml (2) NOTE: WASTE SOLIDITIED VITH CEMENT ON A SMALL S CA1.E AT AMBIENT TIMPERATURE WILL SET MUCH MORE SLOWLY DUE TO RDIOVAL OF E20-THERMIC HEAT. SAMPLE CDNDITIONDC IN A TEMPERATURE-CONTROL-LED OVEN PERMITS MORE MEANINCFUL EVALUATION OF SOLIDIFICATION KE::UI.IS I;; t-24 f!00RS AS SPECIFIED FOR THE WAS~E FORM, OR AS . p ESTABLISEED BY EIPERIINCE AT A PARTICUIJR UTILITY. l r t i FOR ;NFORMATION ONLY
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1 . . i. PC;g ,,l FOR LNFORIVK 10N ONLYPAGE 11 OF 28 l TICURE 1 REVISION 4 PCP SOLIIDITICATION OF BORIC ACID CDNCENTRATES (N-24, CEMENT, LIME SECL'ENCE FOR FVR WASTE) I 1.0 SAMPLE TERIFICATION i l NOTE: TIE CEEMICAL ADDITIVES USED POR PCP PREPARATION SECLD BE .i f TBOSE ACTUALLY CSED IN FULL-SCALE SOLIDIP1 CATION AND SEULD 3E STORID IN CAPPE.D CENTAINERS. 1.1 Trea past experience and the analysis supplied by the utility, determine the appropriate PCP solidification formula using the table below. Note that boric acid waste that has been pa rtly neutralized un-intentionally or to reduce storage temperature may require different or additional solidification agents and result in less efficient vaste handling. Vaste temperature must also be considered in determining the preferred PCP for=ula and full-scale material requirements. Table
..... e...,3; 3 erie Acid v..r. *w; of CNSI WI of CNSI Weight of Weight of
(;pe) Equiva lee t volume Agent N-24 8 ent N-50 ument ue 0- 6,900 0-4% 200-21C ML 5 O! 0-5 Qt 170-210 2 60-80 GM 7,000- 21,000 4-12I 210-240 ML 10 Of 0-10 Of 130-180 Of 60-80 Q: Above 21,000 Above 12 220-250 ML 15 Of 0-15 Qt 120-170 of 60-80 Qt
- Typical Acount Or As Required 17 Test Results 12 Notify the utility that preparations for verification testing are. complete and that a sa=ple is required.
1.3 If vaste sample has crystallized and is con-unifor=, the entire sa=ple must be- heated to 1400 F or above until crystals have re-di s s olved . Then measure outvaste volume required in 250 ml graduate and iz=ediately transfer to a 600 al pyrex beaker. 1.4 If sample is less than 1600 T, heat sample to 1600 F on the hot plate using a glass red to occasionally stir contents. Then remove beak er from the hot plate and, when temperature is just 1600 F, i=nediately add required weight of OiSI Ag ent N-24 Stir vigorously to disperse powder in hot liquid and to deter-mine if foaming may occur in the full scale solidification, and note maximum temperature reached during the 30 seconds of stir-ring and after addition. Record temperature on CNSI Solidifica- ' tion Worksheet I, Ites (b). If tesperature does not increase by about 6-100 T, it may be necessary to add CNSI Agent
- N-50 to l
l assure desired solidification. l e ! SD-cP-003 N 11 J emme sesam 7e __. _ m_ . . . _ . _ _ _ _ _ m
w:- PCP-001 PAGE 12 0F 28 C{- ATTACHMENT III REVISION 4 s NOTE: IF ANT FOAM IS MEATED DOE M TIE ACITATION OF TEE WASTE, THEN SMALL @ANTITIES OF A (IR0iERCIALLT AVAIL-ABLE ANTIFOAM SEALL BE ADDED (LESS TBAN OR E@AL M 1 NL) VBIU AGITATDC TEE SAMPU. TIE TOTAL AMOUNT CF ANTIFOAM ADDED To SUBSIDE THE FOAM SBALL NOT UCEZD 2I OF TIE TOTAL WASII 10LIliE WITHOUT FRIOR AFFROVAL FROM . TIE STPERVISOR 01 MANACER OF SOLIDIFICATION SERVICES. 1.5 Add immediately the required weight of CNSI Agent N-50 and ce-ment, and disperse thoroughly with spatula. Use minimum cement weight in accordance with experience, and add CNSI Agent N-50, as necessary. 1.6 Proceed directly with line addition and using minimum weight for i first line addition, or if experience with the particular vaste form indicates that the required pH will be schieved with a quantity of line different than the minimum indicated on the table, that quantity may be used for the first lime addition. 111x with spatula and check pH with litzus paper to confir: a value of 11 or above. Add more line if pH is lov or if six is too watery. 1.7 Transfer entire sa=ple to a 250 al container using spatuls. l t Attach lid finly and place sample in oven at 165 + $0 F. 18 Maintain sealed sa=ple in oven for 6-24 hours according to past experience at that particular utility. Then remove sa=ple from ; oven and allow to cool for at least 2 hours before unsealing and evaluating solidification results according to guidelines of . Paragraph 4.4. i N0!I: TE 2-BOUR COOLING PERIOD CAN BE DELETID IF EIPERIENCE WITH TE15 PARTICULAR VASTE $ 3EAM INDICATES THAT NO VATIR IS STANDINC ON TE SAMPLI AND IT MEETS THE RE-
@!1DiEhm 0F PARACRAPH 4.4. I f
- 2. 0 Full Scale Calculations .
2.1 Deter =ine the volu=e (cubic feet) of vaste to be received by ce=pleting CNSI Solidification Worksheet II or according to past experience at the particular utility. 2.2 Be sure that total solidification weight and vaste radiation level is consistent with allevable d ansportation regulations and requirements. F0R 1NF0WAT ON ONL'( nov. ,emiet , secunsaT N 12 I SD-OP-003 _J Cason 'esas n
t l . FOR NF07Mrrina #' ' r, w -
' ' ' 1-PCP-001
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ATTACHMENT II] PACE 13 0F 28 FICURE 1-A REVISION 4 PCP SOLIDITICATION OT BORIC ACID CDNCEhTRATES (LIME, CD!ENT SE(LINCE FOR PVR WASTE) 1.0 SAMPLI VERITICATION . NOTE: THE CHZMICAL EDITIVES USED FOR PCP FREPARATION SBOULD BE TEDSE ACTUALLY CSED IN FULL SCALE SOLIDIFICATION AND SBDULD BE STORID IN CAPPED CDNTAIhTRS. CEART I Calcium *CNSI
- Sodium Boric Acid Moderator 8ydroxide Equivalent Cement time Chloride Boron Content (gms) (gus) S-4 (gts) (50: Solu.)
of Waste (FPM) (By Weight) (g=s) 10-20 3. 0 10 2.5 m1** 0- 3,500 0-2 19C-240 2.5 m1** 20-30 3. 0 10 , 3,500 - 7,000 2-4: 18C-230 10 2.5 m1** 7,00C - 10,000 4-6: 170-220 30-40 3.0 40-50 3.0 10 2.5 m1** 10,500 - 14,000 6-8: 16C-210
?.5 sI** ,
~150-200 45-60 3.0 10 .
14,000 - 17,500 -1:::: 2.5 m1*= 145-190 50-70 3.0 10 L7,500 - 21,00C>+ 10-12:+
Typical Amounts Of As Required, If Any, By Test Results.
** Or 5 ML OF 25: Solution. /
1.2 Notify the utility that preparations for verification testing have been ce=;Ieted and request that a sa:ple be taken. 1.3 Freshly screen sufficient li=e and ce=ent in separate containers to avoid undispersed lu=;ing in the sa=ples. 1.4 Add calcium chloride, CNSI Moderator S-4, and li=e (as indicated in Chart 1) to a 600-100C al container. 1.5 Insure that the vaste sample is uniform by heating to 1400 F or more, if, necessary, and then add 200 31 to each container. Vigorously agitste to determine if foaming may occur in the full scale solidification and then check the pH of each sa:ple with narrow range paper and record results on CNSI Solidification Worksheet I. The pH at this point should be at least 10.5. Continue sixing and retesting if the pH is low, and ' add more line if necessary. Record weight of line added co CNSI Solidi-fication Worksheet I. NOTE: LIME AND BORIC ACID WASTE DO NOT REACT (NICKLT TDCETB-ER, DE SURE TO MIX TEROUCELY FOR AT LEAST 3 MINUTES BETORI DECIDDiG TO ADD MORE LIME BASED UFON CDNTIEMING
- TBAT TEE pH IS STILL LOW.
nav. asessT secunssert 4 13 S D-CP-003 J
' caso seess ve
I I . . FCF-001 FACE 14 0F 28 7 r
. ATTACHMENT III REVISION 4 NOTE: IF ANT FOAM IS CRIATED DUE TO THE ACITATION OF TIE g
WASTE, THEN SMALL @ANTITIES OF A CDMMERCIALLY AVAIL-ARLE ANTIFCAM SHALL BE ADDED (LESS TEAN OR E@AL TO 1 TEE TOTAL AMOUNT OF ML) VEIU ACITATING THE SAMP3. ANTIFOAM ADDED TO SUBSIDE THE FC.4M SHALL 30T EXCEED 2I 0F TEE TOTAL WASTE VOLUKE WITBOUT FRIOR AFFROVAL FROM THE SCFERVISOR OR MANAGER OF SOLIDIFICATION SERVICES. . 1.6 Add the appropriate amount of cement to the container (s) while continuing mixing with spatula. Bland mixture (s) thoroughly. 1.7 Csing a pipet, add the sodium hydroxide solution, if required, and mix thoroughly. Till to approx-1.8 Transfer sa=ple cixture(s) to 250 al beaker (s). imately 1/4" of the top. 1.9 Flace lids securely on sa:ples and immediately transfer to oven controlled at 1350 F y, 50 F. Then cure for 6-24 hours, ac-cording to experience at that particular utility. 1.10 Remove the sa ples from the oven, and allev to cool for at least ' I hout. 1=Nr* recovin; the lid (s) and cvalunting solidifiestien . results accordicg to guidelines of Paragraph 4.4. j THE 2-BOUR CDOLING PERIOD CAN BE DELETED IF EIFERIENCE l DOTE: WITH TEIS FARTICULAR WASTE STRIAM S90VS THAT IT IS NOT NECESSARI TO EVALCATE THE SAMPLE. OBTAINING A FIRM, DRT PCF FRODUCI AT 130 0 F WILL NOR-NCTE: MALLY ASSURE TEAT A TEST FORMLU VILL PROVDE A RAFID AND ACCEPTAE!.E FTLL-SCA1.E SOLIDIFICATION VITH A CLEARLY e MEASCRAELI ZICTEEEM. TO DDt0NSTRA*I ONLY THE EIPECIED FINAL FRODTCT HARDNISS, TEE SEALED SAMPLI S BOCLD BE l CCRID AT 170 + So F FOR 18-24 BOURS ID (IF.PLETE TEE l EARDENING RIACTIONS. I 2.0 FL*LL SCALE CALCCLATIONS (Borie Acid Concentrates) 2.1 Deter =ine the volu=e (cubic feet) of waste to be received in the liner. Refer to the table in Figure 5 for usable liner volu=es and also consider past experience and allevable cask payloads. . ; I 2.2 The amounts of ce=ent and line required are deter =ined by using j the information in the table below. The ratio of ce=ent to line varies according to the analyzed level of boric acid in the waste (to be supplied by the utility). ONLY
- FORINFORt@ M- .
sSW. DetET agmammT SD-OF-003 N 14 l L smee tema M e
..4,. _ . , , . - . . . , _ - . - _ . __ _, ,
7 PCP-001 PAGE 15 0F 28
,{ ATTACI@fENT III REVISION 4 lWasteAnalysis Equivalent
- Weight of Line
- Weight of Cement Per Baron Acid Content Per Cu. Ft. of Vaste Cu. Ft. of Waste FFM Boron 3,500 0-2% 4.0 - 8.0 lbs. 59.4 - 75.0 Lbs.
0-3,500 - 7,000 2-4% 6.4 - 9.5 Lbe. 56. 2 - 71. 8 Lbs . 7,000 - 10,500 4-6% 9. 5 - 12. 7 Lbs . 53.1 - 68.7 Lbs. 12.7 - 15.8 Lbs. 10,500 - 14,000 6-8% 50.0 - 65.6 Lbs. 14,000 - 17,500 8-10: 14.1 - 19.0 Lbs. 46.8 - 62.4 Lbs. 17,500 - 21,00% 10-12 + 15.8 - 22.1 Lbs. 45.2 - 59.2 Lbs.
*Line and Cement Factors Selected are based on Boron Analysis, PCP Results ,
and Past Experience.
- 2. 3 Determine the full scale formula and level alarm settings by ec=pleting CNSI Solidification Worksheet II for PWR wastes.
2.4 The volume of caustic required, if any, for full scale solidifi-cation is dependent c: a number of variables, such as vaste com-position and ambient conditions. The maximum volume of caustic is 10 gallons of 25: concentration or 5 gallons of 50% concen-tration. These aucunts are not to be exceeded without super- , a r.scr's appreval. I i i l l
~
i l I t i i i Ii COR NEORMATION ONLY e t l Asv. SpeBET pommaserf . 15
$D4P-003 N {
'~ # **
I 1
~
FOR NFORMAT ON ON _Y , 3
'PCP-001 PAGE 16 0F 28 f ATTACHMENT III REVISION 4 l FIGURE 2 PCP Solidification of Particulate Vastes (Resin Reeds. Powdex And Distomaceous Earth Slurries) 1.0 Sample veriffeation l NOTE: THE CIEMICAL ADDITIVES USED POR PCP PREPARATICN SEULD BE TIESE ACTUALLY CSED D FULL SCALE SOLIDIPICATION AND SEULD BE STORID IN CAPPED CONTAINERS.
1.1 Arrange with the utility to assign a special test area which contains adequate protection f rom the anticipated higher radia-tion levels of bead resins. 1.2 Notify the utility that the preparations for verification test-ing have been completed and request that a vaste sample be sup-plied. 1.3 Transfer 100 al of resin from the sample container to a 250 ml
- disposable beaker and allow solids to settle. Typically, there i vill be a icyer of veter en top of the rasic beads. -atrifug '
powdex vill show no separation of liquid. POTE: WHEN RADIATICN LEVIIS ARE EXCESSIVE D ACCDRDANCE WITH - THE ETILITY CUIDELINES, THE SAMPLE AMOUNT MAY BE RE-DUCED TO AS LITTLE AS 15 ML. BE SCRI TO REDUCE OTHER ADDITIVES RT THE S AMI RATIO. 1.4 Measure and record on GSI Solidification Workaheet the vaste pH ; using the wide range pH paper. Add line (Ca(OH)2) in 2 gm increments until a pH of 10.5 to 11.5 is reached by a narrow g (9-13) range pH paper. Stir thoroughly af ter each addition of lize and add 3 more grams after the desired pH range is reached. Record the total amount of line added on CNSI Solidi-fication Worksheet I for particulate vastes. Alternate Method: Where line is not acceptable (i.e., cannot be added to the slurry) substitute 50 percent sodium hydroxide so-lution for line in Step 1.4 and add in one al increments until a pH of 11 to 11.5 is resched before proceeding with Steps 1.5 I through 1.7. NOTE: LIME IS THE PRETIRRID ACENT POR PRE-TRZAIMENT OF ION-EXCBANCE TYPE WASTES, SINCE IT IS MORE GMPATIBLE WITH CIMENT RIACIONS AND PORMS A MORI STAgLE END PEODUCT. 1.5 Add cement slowly while stirring until a smooth bosogeneous six is obtained. The amount added for a 100 al waste sample may be to to 150 ses depending on resin type, quantity of line added and amount of water in the slurry. Record amount of cement added on the CNSI Solidification Workabeet. l new. magg7 ammassrf 5 14 SD4F-003
- - . ~ -- - - - '.-.
r m I.
. PCP-001 PAGE 17 0F 28 ATTACHMENT III REVISION 4 l 1.6 Flace the lid over the beaker and store the sealed mix in an oven controlled at 120-1300 F for 18-24 hours. Then allow sample to cool for at least 2 hours before removing lid and evaluating solidification.
,1.7 Evaluate the sample using the guidelines of Paragraph 4.4. If the sample does not meet the acceptance criteria, contact Super-visor, Solidification Services for possible formula modifica-tions.
2.0 FULI. SCAI.E CA1.CULATIONS (BEAD-TYPE OR PARTICULATE WASTES) 2.1 Deter =ine the velu=e of vaste material to be received and the amounta of ce=ent and lize or sodium hydroxide solution required by completing the CSSI Solidification Worksheet for bead-type or particulate vastes. Reduce the calculated amounts as necessary to coeply with weight and radiation limitations imposed by waste activity and shielding require =ents.
~
I FOR LNFORMM l l a 1 l l 90chmeNT Re v. messT 1 I SD-CP-003 N 17 g .J emne tes&S 7e
. FOR INFORViAT ON ONLY _
- 3 r PCP-001 FAGE 18 0F 28 ATTACEMENT III REVISION 4
~'
FIGURE 3 FCF Solidification of Sulf ate Concentrates (BUR Wastes) 4 l 1.0 Sample verification NOTE: TIE CEIMICAL ADDITIVES USED FOR FCF FREFARATION SEUD BE TBOSE ACTUALLY USD IN FULL SCALE SOLDIFICATION AND SEULD .
- BE STORZD_ D CAFFED CENTAINERS.
1.1 Notify the utility that preparations for verification testing have been completed and request that a saapple be provided. 1.2 Add 15-30 gas of line, 15-25 gas of GSI Agent M-5, and 0-2 gas of boric acid to a 600-1000 al container. NOTE: DORIC ACID IS USED TO RITARD m CHEMICAL REACTION WEICE DEC3ZASES THE E20 THERM. NORMALLY 1 CRM OF BORIC ACID WILL BE ADDD. TIE AMOUNT OF BORIC ACE RE@IRZD WILL VARY WITE WASTE TIMPERATURZ AND pI. A IICEER WASTE TIMPERATURE AND A IIGHER pH WILL RE@Ig1 MORZ DORIC ACE. AS EIFERIENCE WITE A PARTICULAR WASTE STREM THE BORIC ACE MAY BE DELETED OR DCREASD TO 2 CRMS MAZIMW. . 1.3 Add 200 al of radwaste to the container and vigorously agitate to determine if foaning may occur in the full scale solidifica-tion. Check the pH and record on CNSI Solidification Worksheet I. If pH is less than 11.5, add more line as necessary and re-test. NOTE: IF ANT FOM IS CRZATED DUI TO TEE ACITATION OF M WASTE, THEN SMALL @ANTITIES OF A CDe'IRCIALLY AVAIL-AELE ANTIFOAM SHALL BE ADDED (LESS THAN 01 E@AL TO 1 THE TCTAL MOCNT OF ML) WEILE ACITATING THE SAMPLE. ANTITOM ADDED TO SUBSEE THE FOM SEALL NOT CICEID 22 l 0F THE TOTAL WASTE TOLCME WITECT FRIOR AFFROVAL FROM I
- THE SCFERVISOR CR MANAGER OF SOLDIFICATION SERVICES.
1.4 Gradually add 135-175 gas of cement over a 5 minute period while continuing mixing. 31en thoroughly unit mixture is homogeneous. I NOTE: HICH DENSITY OR SOLDS CENTENT OF THE WASTE MAY NECES-i SITATE A RDUCTION D THE MOUNT OF CEMENT RE@ IRED M i ACHIEVE A WORIABLE PASTE. MDlIMIZE CZEENT USACE CON- l SISTINT WITH ORTAINDC A FIRM, DET ACCEPTABLE FRODUCT. 1.5 Transf er (pour) san;1e sixture into a 250 al beaker, filling to within 1/4 inch of the top. 1.6 Place the lid over the container and store in an approved radio-active materials storage area in the oven provided. The sealed sample should be kept at 140-1500 F for 16-24 hours. nav. messT l secuasswt N 18 ' SD-4F-003 J enen seeste te
) t PCP-001 PAGE 19 0F 28 !
F I ATTACHMENT III REVISION 4 NOTE: UNEEATED SAMFLZ MIITURES DO NOT ATTAIN TIE SOLIDITICA-TION TEHFERATURES CENERATED D TEE LINER AND MAY NOT INDICATE A CDLPARABLE DEGREE OF SET DURDG TEE S AME TIME PERIOD. SAMPLES ALIDVID TO SET WITEUT REATING MAY EIBIBIT MORE BLEED LI@ID AND BE LESS UNIFOIM THAN THE FULL-SCALE WASTE SOLIDIFICATION FRODUCT. 1.7 Af ter cooling for at least 2 hours outside of the oven, remove cap and evaluate the sample using the guidelines of Paragraph 4.4. sam-18 Contact the Supervisor, Solidification Services if the test pie fails to meet solidification requirements. 2.0 FO L-SCALE CALCULATIONS 2.1 In determining the volu=e (cubic feet) of vaste to be received, refer to the table in Figure 5 for usable liner volu=es and also censider past experience and allowable cask payloads. 200 2.2 "he typical a=ounts of sclidification agents required to set be-al of representive vaste liquid are indicated in the table ! Icv. Varichle s=cene of undissolved solids in the vaste neces-
- sitate modifying the cement content accordingly. .Make up two I
(2) cr more test mixes at the same time to determine the best ! cenent value consistent with maximizing vaste volume while cb- l taining a unifor=, fir = product. l Ce=ent Typical Agent M-5 Specific Cravity Weight of '*aste Veicht Li=e Vt . 135-15 5 g=s 30 g=s 15 g=s 1.20 or Above 20 g=s 1.12 1.19 144-155 g=s 25 g=s 15C-170 g=s 20 g=s 20 g=s 1.04 - 1.11 25 g=s I. ass ~han 1.04 155-175 g=s 15 g=s
- VARIABLE ACCCROING TC VASTE pH AND SPECIFIC CRAVITY 2.3 Oeter=ine the full scale formula cud level alar = settings by co=pleting the full scale CNSI Solidification Worksheet II for BVR wastes.
I FOR INFORMATION ONLY A8v. epassT Doc &assesT 19 SD-CP-003 N J L sessc sesa.s M t.
f - l t
~
i FOR IN FOHM A i .Uik 0 %-k aTTXCHMENT III PAGE 20 0F 28 s FIGURE A REVISION 4 FCF Solidification of Miscellaneous Aqueous Vastes (Not Representing Typical BWR or PWR Concentrates) 1.0 SAMPH YERITICATION EDTE: TIE CIEMICAL ADDITIVES USED FOR PCP TESTDC SBOULD BE TESE ACTUALLY USED D FULL SCALE SOLIDIFICATICS AND SEULD BE SIORED D CAPPD CDNTAINERS. 1.1 Notify the waste generator that preparations for verification testing have been completed and that a sample is required. 1.2 Measure out 200 31 of radvaste sample in a 600-1000 al dispos-able container. Then vigorously agitate to determine if foaming may occur in the full scale solidification. NOTE: IF ANT FOAM IS OLEATED DUE TO TEE ACITATION OF THE WASTE, THEN SMALL @ANTITIES OF A C:MMERCIALLY AVAIL-ABLE ANTIFCAM SHALL BE ADDED (USS THAN OR E@AL M 1 ML) WHILE AGITATDC THE SAMPU. THE TOTAL AMOUNT OF l j ANTIF0AM ADDED TO SCESIDE THE FOAM SEALL NOT EXCEED 22 u . OF TEI MTAL WASTE VOLCME WITHOUT P110R APPkOVAL ROH THE SUPERVISOR OR MANAGE 1 OF SOLIDIFICATION SERVICES. Add 120 to 140 3 rams of Portland Cement and six well with j 13 spatula. : f Add 80 to 100 grams of line and mix well with spatula. 1.4 1 NOTE: ON A NIV WASTE SAMPLE, START WITH MINIMEM @ANTITIES OF
, CEMENT AND LIME TO FORM A SMOOTE MIX NOT PRODUCING El- l CESSIVE BLEED LI@ID.
I 1.5 Transfer (pour) sample mixture into 250 31 plastic beaker, fil-ling to within 1/4 inch of the top. i f 1.6 Press lid tightly over sample container and store in an approved i constant-t emperature oven. The sealed sample should be held at j 120-1300 F for 18-24 hours. NOTE: IT IS NICESSARY TO E LD SAMPLE MIITURES AT ELEVATE I TD!PERADIS 70 SINCLATE SOLIDIFICATION (DNDITIONS OF j FULL 5CALE OPERATIONS
- 1.7 Remove saspie f ree even and allow to cool for at least 2 hours '
before unsesling. Evalua t e solidification using guidelines of Paragraph 4.4. ,, b Contact the Supervisor Solidifiestion Services if the test sam- : 1.8 ple containing maximum amounts of cement and line still fails to l meet solidifiestion requirements. A significant change in typi-l
" cal cement to line ratio or reformulation with an approved addi- j tive may be necessary.
nav. messT ensussut SD-cP-003 N 20 J enseites C s
l i, PCP-001 { ATTACHMENT III PAGE 21 0F 28 12.0 FCI.L SCALE CALCULATIONS REVISION 4 2.1 Determine the volume (cubic feet) of waste to be received, re- . ferring to the table in Figure 5 for usable liner voluaes. 2.2 Complete the CNSI Solidification Worksheet Il for Miscellaneous Aqueous Wastes to determine actual chemical requirements and . level control settings. FOR INFORMAT10ji_03,{ . nav. seest occunsamt SD-0P-003 N 21 J l g CBSo 9 M 1 M
7 r- PCP-001 _ ATTACIDENT III PAGE 22 0F 28 FICURE 5 , REVISION 4 Liner and ik calculations Liner L21-300 L21-235 L14-195 L14-170 L8-120 L7-100 L6-80 Diameter 82- 82- 76- 74- 61- 74.5* 58" - Reight 104.5- 79- 75.5" 69.37- 71 .5- 37- 54-Total Volume, 317 241 196 174 120 93 82 Ft3 tsable Volume, Ft (2 Safety 235 190 169 116 88 79 Factor) 31 1 Ft 3/In.
=f Enight 3.05 3.05 2.62 2.52 1.69 2.52 1.53 Weight, Lbs. 2400 1800 1650 1550 1100 1250 950 3sk Payload, Lbs. (including 27250 27250 17700 14000 20000 13000 7500 Licer Weight)
FOR INFORMATION ONLY . t gD-CP-003 N 22 J k emmoseeam n
,i s l FOR INFORB/ATION ONLY . 3 - I FCF-001 FAGE 23 0F 28 , I AITACHMENT III REVISION 4 FICORE 6 FCP FOR FREFARATION OF FLUID MIME FOR IN-SITU SOLIDITICATIONS 1.0 SMFLZ VERIFICATION NOTZ: TEZ CHEMICAL ADDITIVES FOR PCF FREFARATION SiOUD BE TIESE ACTUALLT USD D FULL-S CALI SOLEIFICATIONS AND SiOULD BE STORID IN CAPPD CONTAINERS. 1.1 Secure representative sa:ples of all components to be used in the actual solidification. i 1.2 To a 600-1000 31 plastic beaker, weigh in the dry materials lis-ted and record values on CNSI Solidification Vorksheet (for In-Situ Solidifications). Sodiu= Sulfate, Anhydrous 16.0 gm 40.0 ga Li=e, Rydrated Boric Acid, Cranular 2.0 gm
, 1.3 Fro = a graduate, add 200 ml of water to the dry ingredients and bleed thoroughly with statula. Check pu wi th narrow sanae--cacer j to confirm that the mixture is 11.5 or greater.
l' 1.4 Add in 190-220 grams of Portland Cement and mix well with spat-ula to assure uniformity. Control the flow characteristics of I the mix to a smooth, fluid consistency. l I po;g: THE REqCIRmENT FOR IN-SITU SOLEIFICATION IS A CEENT CCKFOSI* ION THAT CAN 3E FCMFD AS A FLUID, BUT WILL SET ; EARD WI E LII"TLE OR NO BLEID LIquD AFTER FLACm ENT. j
. THE FROPER CONS ISTENCY IS REST DISC 1DD AS A *EIAVY l CKZAM 70 A SOFT ICE C1ZAM* TEITURI. ADJUST Cm ENT ,
WEIGHT AS NZCISSARY TO OBTAD DESIRD TEITURI. ; i 1.5 Af ter confir=ing the proper weight of cement needed to control I the flow characteristics of the mix, note this value on the Sol- I idification Worksheet (for In-Situ Solidifications). Transf er fluid cement mixture to a 250 31 container to about 1/4 1.6 inch of the top, and then attach lid firmly. ll i , 1.7 Flace sealed container in an oven controlled at a bou t 130-1400 i l F for 18-24 hours. Then remove the container and allow to cool ' l before unsealing. Examine product and record approxi= ate volume l of free liquid, if any, and the apparent relative hardness. l IF AN OVIN IS NOT AVAILABLE, THE TEST SOLEIFICATION i f NOTE: MAY BE CDiFLITED AT VAIM 100( TEMPERATUEZ (75-858 F). l BUT WILL NOT NICESSARILY GIVE THE SAMI KISCLT5 CVER THE
. SAME TIME PERIOD. EMALL SAMPLES D0 h01 RITAIN TEE NOR-MAL 12DTEER)f!C EEAT OF CDtDi EERATION TEAT ACCELER-ATIS RARDDDC 0F BU12 MIITURZS. ,
t new. swasT l eacusss=v 8D-07-003 N 23
/ \
L -- - suso isens vs I
. . l
. 3 ;
r- PCP-001 .PAGE 24 OF 26 j ATTACHMENT III REVISION 4 1 2.0 Determine the volume of waste material to be received and the amounts of cement, line, sodium sulf ate, and boric acid required by coupleting ; Chemical l CNSI Solidification Worksheet for In-Situ Solidifications. amounts may be changed with supervisor approval as necessary to comply with weight and radiation limitations imposed by waste activity and shielding requirements. i I I I l k k gg goaMM0M i i i 4
. j RSV. DISET MIf7 N 2' l 3D-CP-003 ;
* , esse.n g
t-t . i . . . N h P-001 PAGE 25 of 28 ATTACHMENT III REVISION '), I 1 CNSI. SOLIDIFICATION WORKSHEET I (PCP Solidification Of PWR Wastes) m 14(yIT: MIS INIGMATION IS CINSIDERED PROPRIETARY AND IS Nt7f TO BE RELEASE CE CDPIE WI'nt0UT WRITTDi PERMISSICE OF OHENUCLEAR STSIDAS INC. NUTE: THIS WORKmmt IS TO BE USE %4 OtNJUNCTION WIni SDOP-003. Waste Identification Date: Operator: Utility:_ Boron Content opn or Boric Acid Cbotent
- Specific Gravity PH Temperature CF ( In Waste Tank )
Physical Appearance (color, clarity, sediment) S""'"*"" FOR INFORMATION ONLY ! (a) Volt.ne Of Waste: ml ' (b) Weignt Of N-24: gm ( i OF) I (c) Weignt Of N-50: g:n
- i 6
(d) Weight Of Cement gm (e) Weight Of Lime: gm : s pH After Mixing In Li.m ! i (f) Mditional Lire Added, If Any: g::
;il Af ter Mixing In Lire I Oven Te@6rature At Start Of Test CF l Ti.e Sa.gle In Oven (Sealed) hrs. l i
Oven Tegerature When Sam le Her:cved , CF i Time Outside Oven Before Unsealing i hrs. I Solidification Results Free Liquid, If Any: ml (Approximate) Helative Set (Very Hard, Firm, Soft) :
+
Unusual Appearance (color, foam, stratification) SW-PWR-I 3/14/83 i---
IUN llN r U Mvin i ivii Viv L 6
, . GSI SOLIDIFICATICH MJRKSHEET I (PCP Solidification Of PtR Wastes)
(To be used with Figure 1-A) N(7FE: Dils INEMMATIm IS CDiSIDERE HIOERIETARY APO IS NCTF 10 BE REIZASED E CDPIED WITHOLTI WRITTEN PERMISSICH OF GEM-NDCLEAR SYSTEMS, INC.
.s waste Identification DLte: Operator:
l I
!brun (batent ppn or Ibric Acid Content %
Specific Gravity , PH . Ter :perature CF ( In Waste Tank ) i R:ysical Appearance (color, clarity, sediment) 1 Sa::ple Preparation
~
(a) Volune Of Waste: ml gns '- (b) Illeight Of Lime: ,_ (c) Weight Of QLicitm Chloride: g-s (d) CSSI ibderster S-4. If used: 99 ' I
;H Af ter Mixing For 3 Minutes i I
(e) Additiocal Lime Added, If Any: p:s f Final ;H (If hbre Lime Paquired) (f) Weight Of Cs ent: gs (g) Voltne Of Sodiun Hydroxide, If any: ml % NaCH ! (Indicate Strength. 25 or 50%) Oven Temperatt:re At Start Of Test CF Time Sa=ple In Oven (Sealed) hrs. Oven Temperature Wen Sample Pemovat CF Time Outside Oven fiefore Unsealing hrs. Solidification Results Free Liq. tid, If Any: ml (Approximate) Palative Set (Very Hard, Tim, Sof t) Unusual Appearance (color, fcan, stratification) PCP-001 ATTACHMENT III 3-82
= 2 * " 28 RIVISION 4 OR IN FORM AT ON ONLY SW-PWR-I -
L
I . . i .
- 1 t
, OSI SOLIDIFICATION WORKSHEET II (Full Scalo in 14-195 Solidification or larger liner Of PWR Wastes)
I, NDTE: MIS INFORMATIW IS (IMSIDERED HIOPRIETARY AIO IS NOT TO BE Rn.EL9m og COPIED WITHOUT WRITIM PEEKISSION OF GEM-MX2E.AR N. INC. PCP-001 s NOTE: MIS WGIESHEET IS 10 BE USED IN CIEJUNCTICH WITH M. ATTACHME!rr III Volume InformLtion PAGE 26 of 28 REVISION 4 Waste Identification (a) Usable Liner Volume (Fig. 5) Ft3 Type: (b) Liner Pt 3/ Inch Of Height (Fig. 5) Ft 3/ Inch Date: Operator: (c) Waste Voltane To Be Solidified Ft3 (See Note) NDTE: MAYNUW WASTE 9%. (Pf 3 )= + 200 x (a) x .632 (ROUND OFF TO NEXT I4 WEST KP Waste Vol. Usable Vol. , 5 Fr3 IIVEL) SW-I, Item (a) l Weight Calculations (To 7he Nearest Pound) (d) Weight Of N-24 = (c) x & x 62.4 = Lbs (Waste Vol.) PCP WT. Of Add. KP waste Vol. SW-I, Item (b) SW-I, Item (a) (e) ' weight Of N-50 = (c) x + x 62.4 = Lbs J (Waste Vol.) EP WT. Of Add. PCP waste Vol. SW-I, Item (c) SW-I, Item (a) ',
~-
(f) Weight Of Cement = (c) x + x 62.4 = Lbs (W.sw Vvl. ) EP Cement T. KP er. to Vol. SW-I, Item (d) SW-I, Item (a) (g) Weight Of LLate = (c) x + x 62.4 = Lbs (waste Vol.) PCP Lime WT. KP Waste Vol. SW-I, Item (e) SW-I, Item (a) . NCTTE: ACD AGINT N-24 OR N-5010 THE NEAREST 50 POUNDS. (h) Weight Of Waste = (c) x 62.4 x 1.02* = Lbs. ! (waste Vol.)
- Average Waste Specific Gravity For Calculation Purpose.
(1) Estimated Total WT. To Be Added = (d)+(e)+(f)+(g)+(h)= Lbs. Imvel Heights (To The Nearest 0.1 Inch) (j) Waste Height = (c) + (b) = Inches (Waste Vol.) (V/H Ratio) (k) Cement Height = ( f ) + 173" + (b) = Inches l I (Cement aT.) , (V/d Ratio)
" Typical True Cement Density, Lbs./Ft3 (1) Cement Level = (j) + (k) = Inches (m) Lime Height = (g) + 137* " + (b) =
Inches (Lime 4T.) (V/H Ratio) (n) Lime I4 vel (Estimated) = (1) + (m) = Inches
"%ical True Lime Density, Lbs./Ft3 s"-a-" 3/"/83
- O R N FORM AT10i1 ON LY
OISI SOLIDIFICATIM WCRKSHEET II (Phil Scalo Solidification Of PWR Wasten) in 14-195 or larger liner l (To be used with Figure 1-A) , NOTE: MIS INFWMATICN IS CINSIDERE PROHtIETARY AIO IS NCrr to BE RELEASE m I
.. CDPIE VITHWf WRITTEN PERMISSIW OF QEM-NIXIZAR SYSTDdS, INC. /'
voltane Infonration Waste Identification (a) Lisable Liner Voltrae (Fig. 4) Pt3 TYPE: (b) Liner Ft 3/ Inch Of Height (Fig. 4) Pt 3/ Inch Ihte: (c) hate Voltrae Tb Be Solidified Pt3 NOTE: BE SIRE THAT VOI.DfE (c) IS IISS THAN 68% OF V0GME (a). Weight Calculations (Ib The Nearest Found) l (d) hight Of Lime = (c) x = Its. { (Waste Vol.) (Lime, Table 2.2) (e) hight Of Osment = (c) x = 1.bs . (Waste Vol.) (Cenent Table 2.2) (f) Wight Of 41citra C11oride = (e) x 0.015 = Lbs. (Cenent Wt.) '
~l' (g) WT. Of CNSI bbderator S-4,
*] If Nee.!el - (e) .: 0.045 (Cament WT.)
= Lbs.
7 O scrrE: Ato CAtcIm GI.fRIDE AND GSI WCDERAICR S-410 i THE NEAR5r HI:NDRSXEIGHT.
~7 !
(h) Weight Of Waste = (c) x 62.4 x 1.02*
]3, (waste Vol.)
= Lb s.
;_1 g ' Average Waste Specific Gravity Fbr 01culation Parpose.
.E (1) Tbtal WT. After Oment Addition = (d)+(e)+(f)+(g)+(h)= lbs.
q' , Alam Heights (To 'lhe Nearest 0.1 Inch)
}} ,
(j) Li..e Height = (d) + 400 I.bs./In. = Inches Z
- (Lime Wt.) j i
NOTE: FW 21-235 & 21-300 LINERS, DSE 450 !.BS./IN. O LL., (k) *ste Height = <e) + (d) - Inches (Waste Vol.) (V/H Ratio) (1) kste Alam Ht.=(j)+(k) (If li.m.e is preloaded) = Inches Or =(k) (If line is added after waste) = Inches - (m) Ce,en t = (e ) + 173" + (b) = Inches Height Cement Wt.) (V/H Batio)
**Iypical True Genent Density, I.bs./Ft3 (n) Canent Alar n Height = (j) + (k) + (m) = Imhes PCP-001 -
1 ATTACHMENT III-PAGE 26A of 28 SW-PWR-II 4-82 REVISION 4
I .
. PCP-001 PAGE 27 of 28. f ATTACHMENT III REVISION 4 e TYPICAL SAMPLE CAlfULATIONS KR WORKSHEET II (PWR WASTES) i N(7FE: MS INFORMATIm IS CIESIDE2HD MOPRIETARY AIO IS NDr '!O BE REIEASED CR COPIED WI'IBOLT WRI'ITEN PERMISSICE OP QEM-NUCII.AR SYSTEMS. INC.
NCfrE: MS WORKSHEET IS '!O BE USED IN CDNJUNCTION WITH SMP-003. 120 cubic feet of waste at 1700 F containing 125 un-neutralized boric acid is to be solidified in a 14-195 liner. A satisfactory D test was - cor@leted using 240 mi of hot waste,10 p of N-24,130 gm of cement and 70 gm of lime. (a) Usable Liner Voltre (Figure 4) = 190 Ft3 , (b) Liner Volume / Height Ratio (Figure 4) = 2.62 Ft3 /In (c) Voltrne Of waste To Be Received = 140 Ft3 i NCTTE: MAXIMUM WASTE VOLUME = 240 + 200 x-190 x .632 = 144.1 Fr3 (BOUND OFF % 140 7:3) (d) '#eight Of c.ccit;te N 140 x 10 + Mu x 62.4 = 3C4 bs.* (f) Weight Of Cement = 140 x 130 + 240 x 62.4 = 4,7~2 Lbs. - (g) weight Of Li:ne = 140 x 70 + 240 x 62.4 = 2,548 Os. (b) Weight Of Waste = 140 x 62.4 x 1.02 = 8,911 bs. (1) Esti:nated Total Weight To Be Added =16,541 bs. (j) Waste Height = 140 + 2.62 = 53.4 Inches (k) Cement Height = 4332 + 173 + 2.62 = 10.4 Inches - (1) Cement I.evel = 53.4 + 10.4 = 63.8 Inches (m) Li:ne Height = 2548 + 137 + 2.,62 = 7.1 Inches ! (n) Li:ne I.evel (Estiented) = 63.8 + 7.1 = 70.9 Inches
- Hound Off To 350.
p a LNFORMAT10N OQ z SW-II-PWR 3/14/83 (Sample Calc.)
p - t i es , TYPICAL SAMPLE CALCULATIONS KR WORKSHEET II (PWR WASIES) ! (To be used with Figure 1-A) NorE: THIS DOUndATICE IS CIESIDERED HIGRIETARY AND IS NCTr 10 BE RE12ASED GL C)PIID VITHOUT WRITTIN PERMISSICN OF GD6-NUC2 EAR SYSTDIS, INC. 120 cubic feet of aste at 170*F. containing 95 Boric Acid is to be sclidified in a L14-196 Liner that is pre-itaded with li:ne at j 16.0 lbs. per Ft of mste, and CESI Moderator S-4 is required in the normal amount. Based og ICP and ;mst experience the carnent factor is 54.0 lbs, per Ft of m ste. . l (a) Usable Liner Volune (Figure 4) = 190 Ft3 l (b) Liner Volune/ Height Batio (Figure 4) = 2.62 Ft3 /In ! l (c) Volune Of Waste To Be Beceived
= 120 Ft3 NOTE: (c)/(a) x 100 = 635 (Inss than 685)
(d) Weight of Li:ne = 120 x 16.0 = 1,920 Ibs. I e (e) Weight Of Cement = 120 x 54.0 = 6,480 lbs. (f) Weight Of Odeiun C11cride = S480 x 0.015 = 100 lbs . * (g) Irr. Of CGI Moderator S-4 = 6480 x 0.045 = 300 lbs.*
- Expressed To Nearest Hundredweight (h) Weight Of Waste = 120 x 62.4 x 1.02 = 7,638 lbs.
{ (i) Total Weight After Canent Addition = 16,438 Ibs. (j) Lime Height = 1920 + 400 = 4.8 Inches (k) Waste Height = 120 + 2.62 = 45.8 Inches (1) Waste Ala: n Height = 4.8 + 45.8 = 50.6 Inches (m) Curwnt Height = 6480 + 173 + 2.62 = 14.3 Inches I (n) Cement Alarm Height = 4.8 + 45.8 + 14.3 = St.9 Inches I, I t PCP-001 l ATTACHMENT III PAGE 27A of 2B REVISION 4 FOR l\lFO R MAT [0FONLY g "I
, SW-pWR-II 4-82
(- . . . .
~ m y g 1 C1SI SQUDIFICATICN WmKSHEET III W O1 ! (Process Surararv - PWR wastee) ATTACHMENT III ;, , Skb!I
!qDIg: MIS DOURi&TICH IS CI2(SIDRED PRDERIETART AIO IS ICI '!O g mrid cm (X) PIED WI1BDLrt WRITTEN PEWWICM CF QE36 MnKAR SYNIDS, INC.
- ~
. Ntris: MIS EGirwrRT IS '!O BE USED IN CINJUNCTICH WITH SN.
l Utility Operator Waste Tank l
- 1. Waste Mded:
Start Time Date -l Estimated Finish Time Date Weignt* lbs. ! i
*From WS-II, Item (g) i
- 2. Temperatum Mter Waste Mded: 0F l
- 3. Agents Added: Time Date Weight (M-24)
Weight (M-50)
- 4. Teeperature Mter N-24 Mded: 0F
- 5. Coment Added: -
Start Ti. e Date Finisn Tire Date Weight 159 ti. Tecperature Mter Mixing In Cement: 0F
- 7. Lime Mded: ;
, Hydraulic Start li T1. e Date Pressure rmi
>f 2
nish Time Date Hydraulic Pressure 1:61 Weignt Lbs. ; 8. 0 4 7e perature Mter All Lime Mded: 0F
- 9. ZJg Ltation, Stepped:
Time Date Hydraulic i _l Pressure esi ;
- 10. } -Ih! .tial Ter:peratum Mter Agitation Stopped 0F '
[p .$ours IAter (From Chart Pecorder) 0F ' 312 Hours LAter (From Chart Pecorder) 0F ! Hours later (From Chart Pecorder) , OF '
- 11. li-Peak Temp.: Ti e Cate 0F Z '
t
- 12. % rp. Under 1600 F Ti e Date i i
- 13. thead Pamoved: T1, e Date 3
14, LII.tn er Capped: Ti. e Date
- 15. Oteervations, Additional Coments:
ggg SW-WR-III 3/14/83 FACE 28 0F 28 REVISION 3
OEST 3(LIDIFICAUCN luCRX5 Herr aI (Process Sumsry - PWR wastes) N(yII: DiIS INFQWATIW IS Nb NMkbi N IS NUr TO BE Pet msn a e,PIID WITHOtff IRLIT2f Utility Operator ,
- r. muisstm oF omucuM SYSMS, DC. hate Ank
- 1. Lime Added*
Sta.rt Time - Data Finish Time this hight lbs.
- 2. Chiciun Chloride And CNSI Moderator S-4 Added:
. Time Date h ight Ibs.(GC12 )
h ight Lbs.(S-4) ;
- 3. fleceive hate:
Start Time Date { Estimated i Time Date hight
- lbs. !
Finish l
*Fresa Worksheet II, Iten (h)
- 4. Tur:perature After Mixing In Este: oP
~
- 5. Genent Added:
Start Time Date Finish Time Date hight 1bs. f oF
- 6. ge::perature Af ter All Cewt Added:
- 7. dius Hydroxide Solution, if any: gal. % (25 or 50%)
4 '._. itation Stepped: Time Date 8.Q
- itial Temperat'.:re Af ter Agitation Stopped oF -
9g C , biburs LAter (Frcra Chart fiscorder) oP -
!12 Hours IAter (Frem Chart ilecorder) oF -
t Wi [ f 24 Hours IAter (Frcrn C: art flecorder) oF [ n..
,' First peak Temp. : Time Date oF hl.! f Secorx1 peak Temp.: Time Date oF i/ Temp. Under 1600 F T1: e Date :
! CD , Fi.lltend fienoved: Tim.e Date , jy Liner Capped: hee Date
- 15. Cbservations, Additional C:rnents:
PCP-001 SW-pWR.III 3-82 -- ATTAC10ENT III ' l PAGE 28A of 28 REVISION 4
i r ; nav,3 ous 3 !,
!k , , ;,,;g gg,C,gl, nay, l DESCAIPTICn OATE Apengygg l A? CHANGE PER CHANGE REQiEST NLMER 70-AD-002-01
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FO-AD-002-02 l C CHANCE PER CHANGE REQUEST NLMER /6/ ' / #/ c.e.,~ ' '. <'. le FO=AD-002-03 - . m e-j U CHANGE PER CHA'.;GE REQUEST NLMER FC-AD-002-04
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PCP-001 ATTAC10 S T IV PAGE 1 0F 15 REVISION 4
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. 1 I PCP-001 !
ATTA3 XElir IV PAGE 2 0F 15 Q . ., , REVISION 4 l A.- 2{. . TABLE OF COMBTS 1 h-a . PAGE t,0. 1 1.0 SCOPE . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 3 1.1 Purpose . . . . ................... 3
.l 3, 1 1.2 Applicability . .................... l ._1 -
I 3
'f !
2.0 REF M :CES . . . . . . ................... 4 4 3.0 EETAILED GUIDELI?25 . . . . . . . . . . . . . . . . . . . . . 4, 3.1 General Storage and Handling . . . . . . . . . . . . . 4 i 3.2 Preliminary Inspection . . . . . . . . . . . . . . . . 6 , 6
- , 3.3~ Process Controls . . . . . . . . . . . . . . . . . . .
7 3.4 Post-Cperaticnal G2idelines . . . . . . . . ..... 7 4.0 MECdR!ICAL FILTIT. STCRACE NO DISPOSAL
~ .
I.
'. '; 5.0 RECCRCS N D REPCRTS . . . . .l . . . . . . . . . . . . . . . . 8 l y{ TA3LE 1 - ifaterials Not Cocpatible with Polyetnylene liigh Integrity Centaine rs . . . . . . . . . . . . . . . . . . . 9 i.
j v_., h APPECIX A - User's Checklist ..................... 10 , l k j . APPECIX B - Polyethylene High Integrity Certification State ent . . 11 APPECIX C - Certificatien Statenent for Disposal of liigh ,
- 12 j
[' Integrity Centaine r . . . . . . . . . . . . . . . . . . g s
- r. ' ' l 3: 1
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(9 : '1 g i- ; massNT m av, seest l . P0.AD.002 n . 2 ; l [ c,.....,. 4
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F PCP-Col i gy ATTACmEN' I7 i. ( ,.
%fj} '
) 2,,n PAGE 3 0F 15 REVISION 4
,l 1.0 SCCFE yy.g
? 1.1 Purpose
-l This procedure provides guidelines for the utili:atica ci poly. e thylene High Integrity Containers for GS1 resin transfers, denineralization processes, and other identified, uses by Chen-thelear Systecs, Inc . (GSI). Ainerence to these ' guidelines serves to protect the integrity of the polyethylene d; centainer and ensure the container meets the requirements oi Clea-?Oclear's Quality Assurar.ce Prcgran denoted in Scuta . Carolina's Cepartcent of health and Envirencental Ccatrol's ! Certificate of Ccepilance.
, l 1.2
- i A; piicabilt ty 11 1.2.1 This precedure applies to all C:SI persennel ar.c CSSI custou rs handling, using, or shipping polyethylene liigh Integrity Cantainers for radioactive waste disposal.
I 1.2.2 This procedure is to be considerec as an adder.dtr to a ' l specific operating and cask procecure for a s].ecific Et - utility or si't e as cenignated by the CGI i an.:,er, Solidification Services or }nnager, reminerali:ation Services, and Director, Transportation. j (Pg( / Prerecuisites .i"' 1.3 ' s i 1.3.1 Each user will have on file with Oles-?belear Systens, Inc. Qastecer Ccepliance Depart: ent a "klyetnylene High Integrity Container Certification S tat et.ent" (Appendix B). d' !?
; i Li : 2.0 .PueBCES <
CSI Operating Procedures for Solidification trocesses as spect-T p 2.1 ' d fled by the C;SI Rnager, Solidification Services. g: ' 2.2 CIGI Cperating Procedures for Deminerali:ation Processes as specified by the C;SI knager, Icaineralization Services, i N 2.3 CSI Operating Procedures for teuatering Processes as specifico ' Sy the OSI .4 nager, temineralization Services. 2.4 C;!{ Precedure, 3-OP C03, "Fandling Procedure for Oneu-!.uclear Systecs, .Inc. (CSi) Transport Cask GS 8-120, )cdel hber [t
- U.-50-100, Certificate of Compliance Ruder 6o01."
2.5 C SI Procedure, U-CP-005, " Handling Procedure for Transport y Cask !beber CG 7-100. Certificate of Coop 11ance M.t.er 9113." 1 S l(u) - .~, FO AD-002 H 3 J CreSQ 500L t.78 ,
~ ~' - **
- - :. ~ -
~ ~ ^~ -%~. - _ _ . _ . . - . _ . _ _ _ . . _ . . _ ., , , , ,_ , _
s t . 1 . IO' r PCP-001 PAGE 4 0F 15 i
. i (. ATTACHMENT IV REVISICN 4
- 'Q, ,
e GSI Procedure, TR-CP-00 6, "htncling Procedure for Transport { . 2.6 l Cask Number C;S 14-19511, Certificate of Coupliance ths.ber Wu." I 2.7 CNSI Procedure, TR-CP-010 " handling Procedure for Transport Cask !beber CG 6-30-2, Certificate of C:c:pliance !Leber 9111." 2.8 CiSI Procedure, TR-CP-011. " handling Procedure for Cteu-Itclear Systecs, Inc. (C:51) Transport Cask ltc.ber 21-300, Certirica te i of Compliance it ber 9096." l 2.9 C;SI Procedure, TR-CP-022, " Handling Procedure fer Cteu-!bclear ' Systems, Inc. (C;SI) Transport Cask !t:ber C.S 14-170, terti-ficate of Compliance !beber 9079." , i
}
f 3.0 DETAII.ED GUIDEI.INES i The CGI Solidification /Ieminerali:ation tecnnician or utility repre- I' sentative shall ec=plete the User Cnecklist (;;pendix A) to ascertain ,
' ccepliance with Secticns 3.1 tnrough 3.4. It is tne tecnnician/ ,.
' representative's respcusibility to sign, date, and return tne checi. list to CGI with the shipeent. The utility's representative shall ensure i the waste strean is ccepatible with applicable secticas of tnis ~
procedure. l( 4 j )! 3.1 General Sterage and HandlinC 3.1.1 High Integrity Containers s1.211 act be secree, on ur f near sharp objects or protrustens that coule scrat.e, , cut, or puncture tne container. i
; 3.1.2 Each centainer snail be storec on a flat, sccoth, sup-
], portive surface having at least the sane surf ace area . as the base of the container. I i cl 3.1.3 As cuch as practical, the containers shoulc ce kept out of direct sunlight to prevent ultraviolet lid.t degra-
' datien. Unless the fellcwing conditions are r,.et, eaca i d' High Integrity Container cust be useo and disposed of l (buried) within one (1) year of the uanufacturing date. .
d I q 3.1.3.1 tio High Integrity Container shall be stored ! f in direct sunlight for a perico greatet t. tan i j ene (1) year. n , C At .the utility's request, CSSI sna11 supply 8 3.1.3.2 t a statement indicating the c.axt:n:. length ot i time ene container r.ay be exposed to otrect f i sunlight. This will be calculated by sub- + 4 tracting the nuuber of days the Hiyt i Integrity Container is exposed to sunlight l' [ bet' een the date of manuf acture and the date [? it is shipped from 365 days. Y(v
"'" A EV. SMEET l h
FO-AD-002 11 4 , } ( k
-- - - - - --.... . __. _, __ j
~ .
PCP-001 PAGE 5 CF 15 lc ATTACICtE!rf IV REVISION 4 i~ l l} i 2
'I .i' ' . 3.1.3.3 hhen the centainer is ready for disposal shipment, the utility raust enter en use
!" User's Ctecklist (A;;endix A) the nu:.ber et .
days the container was storea in direct 1 'l sunlight. This nut.ter =ust not exceed the 1 maximun time span allotted for the container. 9 3.1.4 Exposure of the High Integrity Containers to chmicals ; l- ' listed in Table 1 cust couply with the felicking: l 3.1.4.1 No surface centact with organic solvents or i l
' oils including gasoline. If centact shoula occur, wasa centainer wiut wa rr. , soapy water, rinse with copius as. cunts of clean :
J water and notify Cail, i '] . l
> 3.1.4.2 !;o exposure to sensible (detectacle by nut 4n ;
senses) vapors of the organic solvents. l 3.1.4.3 No 1cng tern exposure (greater tnan one week) in roccs with any centainers of or-4 ganic solvents (open or sealed). . .l; Care shall be taken when Icading and transporting use 3.1.5 J 'l centainers with a forklift to prevent scuffing or
, I, N puncturing .
. /
3.1.6 Only ny1:n, heap, or other scf t pliable L.aterials saall i be used for lif ting, moving, or tying ccwn tne con- I tainers. ?.e canufactured =etal lifting slings are acceptable, but other metal caoles, enains, or wire , I
, ropes shall not be used.
ar ( , 3.1.7 A fillhead or CNSI-approved itecs are the only objects ' i to be placed or stored on the centainer, witn tne ex . t ceptien of Step 3.1.6. , I i 3.1.8 Wo eepty centainers e.ay be stacked for storage pro-
' .' vided the bottom container is the diaceter of tne top
. centainer.
t j 3.1.9 No objects or caterials sna11 oe placed into the coa- I tainer for ultimate disposal tnat c.ay cause chettc.1 , j 3
; (see Table 1) or physical carage to tne container, ,
F - 3.1.10 All due care anu caution shculd be taken upon physical f i 8 entry or in handiing of tnese containers to enst.re tnat S tne container is not dataged. 4 ,t .r rey O R E V. SHEET , t FO AD-002 H 5
, l CteSQ 10010 78
.f.p: f;
- . . . - . - . . ~ . . ~. - . - . - , . . - . . . . - . ..~
lI ' E '
.r i 3
PCP-001
,. 3 4 ATTACHMEFT IV E I PAGE 6 0F 15 RIVISION 4 k[ . .,
- 3 3.2 m. Prelictinary Inspection 4
! Prior to using the container, tne CNSI technici n or utttity
- q representative shall: ;
3.2.1 Perfor::, a visual inspection of centainer internals where taasible to verify c:mponent parts are intact. The propr installation of internals is examined by CGI QA .nspection at the time of shipoent and the i appropriate QA inspection sticker / tag is placed upon '
' the vessel at that time.
3.2.2 Perform a visual inspection of centainer exterr.als for - fobviousflawsordefects. 3.2.3 Record container serial nuzter on attacneu User's n G ecklist (Appendix A). 3.2.4 Assure lifting sling with cables attached .'.s fitteu into the grooves of the container witn all couponenta
,' intact. ;
. 3.2.5 A:sure container lid closing tool and sealant, 'If re-i! quired,, are available foi- lid installation after
~< ra jj processing.
l 3.2.6 Inspect lid tool for sharp edges /2cese fittings prtur to use. ' 3.3 Process Centrols 3.3.1 Waste s treae,s snait not contain materials listeo in Table 1 except as noted. If such zaterials are noted, _, contact CGI Regulatory Affairs prior to procevotng, i, . (document CiSI contact on User's Cecklist)
]
- 3.3.2 The waste stream temperature should be kept as icw as practical. The maximum measured acceptable teuperature fl, e < is 2000F.
.]. & 3.3.3 Complete operation per keferences 2.1, 2.2, or 2.3, if j appitcable, h
- NOTE: REHR TO OPERATCR'S DEild.CTIchS FCR PRCPER USE Q _ 0F HAMJAL OR RBIOTE CIMJtE T001..
[ 9L 3.3.4 If 1/4" fine, square-threaded lid is used, apply sealant to sealant grove and install lid.
- .l 1 ! .
[b 'y ""8M R E V. 3>t47 , j ?
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1.t N , g (%. PCP-001 PAGE 7 0F 15 l k - ATTACIDENT IV REVISION 4
.a
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3.3.4.1 Tighten lid with closure tool, ensurins con-J ' '"" tact between sealant and lid. J, )~ - 3.3.5 If 3/4" quick turn, coarse, square-tnreaded lia is used 1 install the pus 11 plate with gasket attacnea (gasxet 1 side dowT1). i 3.3.5.1 Install the lid and tighten the' lid until d the lid match eark is aligned witn tne 10" -
;1 1 are catch mark. -q ] ;3 3.3.6 If buttress-threaded lid is used install lid witn uaten carks aligned.
l , Tighten lid one . full turn (3600) until j 3.3.6.1 - i match uarks ere aligned again. ! 3.4 Post-operatienal 02idelines , 3.4.1 A* loaded centainer shall not be lifted or coved unct1: 4 3.4.1.1 7.e external surface temperature is 1700F. s! 3.4.1.2 The internal teeperature of tne contents is
%6,{
i 1700F.
, r 3.4.2 lead container into cask per References 2.4 enroup 2.9. I 3.4.3 Cecplete User's Ciecklist (Appendix A). l 3- , ;j - 4.0 MEGMIICAL fit.TER STORACE MQ DISPOSAL il!
E.' 4 Users of the liigh Integrity Containers may utiltre tne containers for mechanical filter storage and disposal under the conditions described Q1 ' h below:
!" 4.1 Notify CNSI Liner Operations ) tanager of the proposed use ot. the container for filter storage. .
il 4.2 Supply CNSI Liner Operations banager with pertinent details at the filter assemblies as requested. Lese details will incluce the dimensions and weignt as a minimum. My details /ctL.eastoso /l on sharp edges or protrusions will also be suppliec. A sketen a
- may be required.
)
i.
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- FO AD-002 11 7 4 J L
- j. . . . . . , .
t. I PCP-001 PAGE 8 CF 15 ! ATTACHMENT IV RIVISICN 4 1
' *- 4.3 CNSI will, if possible, design tne intersts of a centainer to i accernodate the applicable filters.
l
.I 4.4 2e shipper is respcnsible for ensuring that mechanical filters or other hardware is adequately stabili:ed to prevent dange to '
the vessel during shipping and disposal.
-i-
,l 4.5 Ceeplete Steps 3.3.4 and 3.3.5, or 3.3.6 as appropriate. ; l, a Ej 5.0 RICCRDS AND REPCRTS
; 5.1 The user has en file with CSSI Custecer Cen.;11ance Leprtt ent a -
" Polyethylene High Integrity Centainer Certificatien State:ent"
. ,t (Appendix B). . S.2 The user has completed and submitted wits the sni .ent coca.ents a "Certificatica Statement for Disposal of hil,h Intehrity l,
}
Container" (Appendix C).
? 5.3 The user has cocpleted the " User's Checklist" (Appendix A).
' I.
it l 5 .,'
.: 4 d!
m I:[ ! 7: 1 L4' [-ig
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i ff qy Q occument F0-AD-002 n av. h suser a
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-. .c . - , . . .g. . - - - . , , - . . -.,-, , . . - - , , . . , . - . , . . .
if. .. . t C PCP-001 I k, ~ ATTACICfENT IV ( ; PAGE 9 0F 15 i REVISICN 4 Y, , TABLE 1 14aterials Not Cecratible With Polyethylene Hign Integrity Centainers ketone Ibrfural i 4 M yl Acetate Purfuryl Alcohol - kyl Q1eride Puel 011 *
,j Jgua Regia Gasoline Ben:ene Hydroflouric Mid (Concentrated) q -1 Bromine Liquid Iodine ~I Canphor 011 ! ethyl Brocide Carbon Disulphide liethyl Chloride Carben Tetrachloride lhthyl Ethyl Ketone (!H)
Ciloride Liquid hethylene Chloride hitric Acid (Ccncentrated) } )bist C11erine Gas Chloroben:ene Nitrobenzene Octyl Cresol
, Clioreforn C11erosulfonic Acid Oleic Acid Cyclohexanene Oleu::t
. Dinethylanine Petroleu::t Ether Ethyl ketate Ehenol
- , Ethyl Sutyrate Propylene Dichloride Ethyl C:loride Fulfuric Acid (1600
- Ethyl Ether Tetrahydrofurae f Titanita Tetracaloride n Ethylene Ciloride Ethylene Chlorchydrin Toluene
; (% 'd ; Ethylene Eichloride Trienioroe thylene Xylene
+ Fluorine Birpentine Tetralin
- - NOTE: PEIRO CFBICALS (OIL, CASCLINE, ETC.) ARE ACCEPTABLE IN TEACE
- i. l *.
! QJAhTITIES ( 0.5%). ,
H! Q.
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d,, 5 i t occwent n av. swear t FO-AD-002 11 9 ; cr.so icotste } ~ ~ - - ,-
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, PAGE 10 0F 15
/.)
- REVISION 4 i
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l d APPENDIX A
} USER'S CHEGLIST
) (1 FAGE) ~
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ei - PCP-001 3 ATTACHMENT IV
~ PAGE 11 op 15 d s. ISION 4 l
, ?{N USER'S GECXLIST Section Iten Reference Initials lhte l'
! 1. Centainers Stored Properly (3.1.1-3.1.4) i 2. Proper Lifting Devices Used (3.1.6)
- 3. Internals Inspected (where feasible) (3.2.1) i
- 4. Externals Inspected (3.2.2) ,
S. Centainer Serial !beber (3.2.3) l
- 6. Lifting Sling Preperly Fittec (3.2.4) ;
,-! 7. Lid Tool 6 Sealant Available (3.2.5)
- 8. Lid Tool Acceptable (3.2.6)
'} Waste Stream Sacple OK (3.3.1)
; 9.
- 10. Waste Strean Tecperature Reading 0F (3.3.2) ,
- 11. )hchanical Filters or Other Hardware l
! Stabili:ed, if Applicable (4.4)
- 12. If 1/4" Fine, Square-ttread Lid is Used ,
Step 3.3.4 is Cecplete
- 13. If 3/4" Quick n:rn Lid is Used, Step 3.3.5 is Cceplete If Euttress-tiread Lid is Used.
1.t .
"j Step 3.3.6 is Ceeplete ~j. 15. Centainer Surface Tecperature ,
ji Reading _FO (3.4.1.1) yD 16. Centents Less Ihan 1700F (3.4.1.2) l[(_ f 17. Centainer Icaded In Cask (3.4.2)
- 18. Total Cuculative Days of Sunlidit .
(W) Exposure (3.1.3.3) j' 19. Fhnufacturer Date of High Integrity Container
- I OPEMTION CCELETir c,
i 3 l 5ignature Late 3 D : 5 p CQ t Th'TS: 53 k Cceplete forn and forward with snipuent to: ' h y 0:ec-tbclear Systens, Inc. 6 P. O. Iox 726
'% !arnwell SC 29812 AITINTIO!1: Q:ality Assurance Eepartpent
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. . _ _ . _ RE7ISION 4 w.
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.t APPEhi)IX B
;i Pct.YFTFYT.D;E HIG{ INTEG.ITY C0f.TAIhu CERTIFluTIch STATHOT 1: 1
+ s- l '. (1 PAGE) 4; I : - j .- .s I 'l I f .i i g., .I , y..
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1 a * PCP-001 ATTAC10ENT IV
' j ], ,Di PAGE 13 CF 15 ~
1 M. REVISION 4 i
@7y. POLYEIhYLENE HIGH IhTEGRITY C0t7AIhTR j CETIFICATION STATDIENT
.t
-' (" Company") hereby certifies tnat 4
j for each High Integrity Container purchased directly or indirectly freu Chen-Welear Systens, Inc. ("CNSI"), and for which disposal is proposed, acteuptea,
]
$ or completed at the Barnwell, South Carolina, low-level radioactive waste bur-( gi ial facility, or for which any use in connection with the collection, storage, processing, or transportation of low-level radioactive vaste is proposed, at-tempted, or completed, it has read and will comply with: (1) the Certificate of Compliance issued April 83 1983, Amendment B, by the South Carolina kpart- l sent of Health and Rivironmental Control, bureau of Radiological healtn, No. . l IEEC-HIC-PL-001, and all amendments thereto, (the "C of C") and (2) the Souta j i Carolina Radioactive haterials License No. 097. In orcer to comply with the ( ]i
- ] !
user quality assurance require enF(Ttez 5) of the C of C, the Coupany certi ' fies that it either has a quality assurance program approved by tue U.S. f
/ Nclear Regulatory Commission under 10 C.F.R. Part 50, App. 3, (which applies ,
j to its proposed use and handling of High Integrity Containers)', has a quality centrol program operated under the specifications of the Naval Reactors Pro-
;, gram, or that it has allowed CNSI to audit and approve ot' its existing quality d2 assurance program for High Integrity Containers. Cocpany further certifies di that it will not make any modification or change in the Hign Integrity Con- ;
(l[ tainer design, materials, or usage from the design, materials, and usage de- l 41 ~ scribed' in the C of C without prior approval of the Souta Carolina Department I (4Ej of Health and Bsvironmental Control and without. prior written notice to CNSI. Company understands that the High Integrity Containers purchasec either di- l
^
rectly or indirectly from CNSI will be maintained, stored, transported, and j used irt accordance with each of the above requiree:ents. hhen the High Inte-I grity Container is disposed at the Barnwell, South Carolina, Low-level radio-
~
active waste burial facility, Ceepany will sign the attacnea certification (Addendun ) prior to such disposal. !
, i c +
M DATE: l b n
. CCHPANY: ,
9 BY: IIS: i Rev. ,11/14/83 5
* * * * * * " " " * * * - **w- . G ,
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, PCP-001 ATTACEMErr IV
,/ PAGE 14 CF 15 j RE7ISION 4 '
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APPEDIX C I
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< - CUTTFICATICh STATE 1NT FCR EISPGSAL OF
- c. H16h INTEGIU COhTAIIL '
(1 PAGE)
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- l PCP-001 V IV ATTAC10iE.I FACE 15 0F 15 i (~s.) .. -
REVISION 4 l %' . CERTIFICATI0H STATDST FCR DISNSAL
't op .
POLYEIhTLENE U,.
- HIGH IhT4GRITY CDNTAINEd 7 "
4 For the High Integrity Container Ove1 Tack to be disposed of at Cleu-lbclear's ' (I 3alwell, South Carolina, Iow-level radioactive waste burial facility and [ by serial ntubers , 31 identified hereby certifies that its use (Company) of such containers has cocplied with the certain Certificate of Cecpliance M 3 issued April 8,1983, Amendment B, by the South Carolina Department of Health
;;j and Environmental Control, Bureau of Radiological. Health, No. EfEC-HIC-FL-001, 9 and all amendments thereto.
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Rev. , 11/14/33 y . 5 . .
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A '.CRANGIS PER CHANGE REQUIST 1/13/82 FO-OP-001-01 B Ch5 PER CEEE RErt.uf ETMP-001-02 6 .27, P3
. t-/4-Al % 4 __
, , _ _ Q# _ -
C CHANGES PER CEANCE REQUEST FO-OP-001-03 PCP-001 l Attach =ent V
, Revision 4 i Page 1 of 8 l J
1 i i ' j 9, i .
; . l j- - NOTE: THIS IN70RMATICN IS CONSIDERED PROPRIETARY AND IS NOT TO
. BE REI. EASED OR COPIED WITHOUT WRITTEN PERMISSION OF CHEM- '
3
- NUCLEAR SYSTEMS, INC.
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PR EPA AE QATE CHEM - NUCLEAR SYSTEMS, INC. I
, g ef,gg ca*Nao t/ tm.s j 7 -s4 Av CEWATERING PROCEDURE FCR THE 24. INCH DIAMETER PRESSURE DEMINERAt.IZER VE55E1.
escussep p i A g .? / - CONTAINING ACTIVATEn cAAnnu
- 0. 5%.-FREE-STANDING WATER g ;j ovaty .
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La , . Attachment V FCP-001
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g Revision 4.
#3* 2 *f 8 "f .it . ."
e.yp TAnfI OF ENITNTS
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! 4.0 OPE 4ATIR; PROCELE_
6 6.0 REX.u(DS 7 FIGURE 1 a Dewatering Capletion Record
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FCP-Oct Attachment V l Revision 4 7 i Page 3 of j ! a w) , 1*0 W p.:% . w docunent contains the instructions for dewatering CNSI's 24-This 1.1 and Fiber- i inch- diameter pressure demineralicer vessel (Ref. 2.4) 'j , (ERP) High Integrity Container Pressure glass Heinforced Plastic filled with activated carbon. The pro-j nomineralizer (Ref. 2.7)
~'
cedum and the vessel have been tested for ocrrpliance in deuter-f ing less- than 0.57 FSW as mquimd by CNSI's State Of South Caro-
-j lica Radioactive Waterial License No. 097.
m1y to dews-1.2 'Ihe instructions contained in this procedure apply tering the 24-inch diameter pressure demineralizer vessel and Fiber-glass Reinforced Plastic (FRP) High Integrity Container Pressure j . Domineralizer Vessel filled with activated carbon. J '
- 2.0 REFDOCZS d C6-AD-003, CNSI Precedum For Doceent Preparation A 2.1 7
2.2 CN-AD 019, CNSI A1 ARA Policv l, 2.3 QA-AD-001, Quality Assursace Program *
- i. '
1 2.4 CNSI Orawing No. 334-0200-D01, Pmssure Demineralizer 0 1; --- Test Procedure And Data, Field Operations Project No.13003
~
d 'j ! 2.5 Al s i 2.6 C6-AD 013, Test, Control l I C4SI Drawing No. C-334-D 0005, Fiberglass Righ Integrity Container, LJ , 2.7
" 24" Pressure Vessel
- s 2.8 FO-OP-014, Operating Procedure For Installing Clesure Cans On 24-1-
I Inch Diameter Fiberglass Reinforced Plastic high Integrity Container 4 1 w 4 3.0 kBJUIN'rS
- O, i -
Prerequisites
"' 3.1
& ~ Prior to dewatering the vessel, the O dI operator shall: 1 ."h I y Octain a Hadiation Work Pemit (or equivalent) from the 3.1.1 ]
- utility's Health Physics uepartment before entering the 4' ' process area.
M t e; 3.1.2 The utility's Health Physics personnel shall perfom Frequency md-h iation level and surface contamination surveys. of the survey is to be determined by the utility. Results N
- 9 of these surveys shall be mcorded on the Daily Operations d .
' Log as a per nanent mcord.
f , 3.1.3 Note 'tte corpletion of prwrequisites in the Daily Opera- } . tions 14g. 3.2 Eauipment and Services 3.2.1 - Warren hupp Sandpiper 1-1/2" Puno with 1-1/2" FNPT con-I,[ _,/ nections, 1/2" FNPT air inlet. !N i
' nav. ausst occumsssv 3 F C i W ~Cui >
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s . PCP-001 3
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1 j Revision 4 . 3,2.2 Connecting Hoses (1-1/2") Page,4 og 3 3.2.1). } ( Outlet booe for the Sandpiper Puno (Para. 3.2.2.1 I
[~k !'
Suction hose to connect between the p.:mp inlet and 3.2.2.2 the liner outlet connection (1-1/2" male quick econect). .
. i 150 psi) with proper connection to 3.2.3 Service air hose (3/4", connect to the Sandpiper Pump (Para. 3
couple to connect to the service air supply.
20 3CFM at 100 + 20 psig. l 3.2.4 Service Air: _ l l J 3.3 L a tions and Limitations _ RGCNDfTS MAY BE PEESSURIZ2D DUhLW ! d CAUTIW: IRJSES DI1assnintT. AM.) OTHER 3RE:SSIRE RETAINING 0: FACE S WGIN DURING DISASSEMBLY OF TliIS EQUIBGNT. /
)! 3.3.1 Stzung oxidizing agents such as nitric acid, when in con
,f tact with organic ion-exchange material and ill the fresence of air, 'may produce a slightly degraded resin in an exo- -
i thez-nic reaction, up to an explosion. l The CGI technician (s)* shall wear safety glasses and/cr fullpressu 3.3.2 f ace shields while working within 5 feet of l ll
! equipnent.
T J *
' 3.3.3 The CGI technician (s) shall wear safety glasses while per-forming his duties in the process area.
+
Acceptance Criteria f, 3.4 - final pucping step i1 3.4.1 A volune measured of < $00 mis ce theIf not 1500 mis, the
.l E shall be the acceptance criteria.
Al waiting / pumping cycle shsll be repeated until 1500 mis is collected.
]#. .
LM EATING IEOCEDURE N; 4.0 THE OPERATCE SHAIL PCL-a. CAUTIW: 3 Tite PlasenR DENINERALIZER MAY BE QNTA WATERING ThiE YESSEL.
! 4.1 Installation Precedure 4.
n 4.1.1 Establish or verify that the vessel is in a level position h . (visual determination). . 4.1.2 Connect the suction hose (Para. 3.2.2.2) to the ou-let con-nection on 'the vessel and to the suction of the Sandpiper c 1 Pump (Para. 3.2.1). h 4.1.3 Connect one end of the outlet hose (Para. 3.2.2.1) to the g discharge of the Sandpiper ptep (Para. 3.2.1), and direct the d4 other end to a drain connected with the plant radwaste A V ' {J < system. 9485T h REV. occamem? 4 C j g K)-cP-Oui case 10B0
-~ . . _ . . . _ _ _ , , - .. .
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F 4.1.4 Connect the service air hoes (Para'. 3.2.3) to the service air supply (Para. 3.2.4) and the Sandpiper pcy. cot Puno (Para. 4 SfE. . 3.2.1). Actach= enc V i M9F Revision 4 1 4.2 Doestering h -- l N N b WITH ' SDK3G OIIDIEING AGDCS 303 AS NIIRIC ACID, WBE CaltrI W : GIGANIC IQ6 MANGE MATERIAL APO IN ME RtESDiCE GF AIR, MAY PHO i 003 A SLIGff DSGRADED RESIN IN AN E203fDtMIC R EIPWSIW .
')
i M PRESEN3 OF OIIDIZING AGDfISIFIS HIS3001 CDOITICN FQtDo AIO A j IN MPERAttRE W SE OUTSIDE OF ME CWrIADGE. a ~~ IS TO REFIIL M YESSEL WITH WATSt.INGREDID Ma.X3LITT OF M HEAT, REITENING THE TMPERATM OF THE YE AMBIDff. TEIS IS A STABLE (I2OITIW,
" BE NOTIF1ED.
4.2.1 Establish service air to the pump. 4.2.2 Adjust the pump air supply valve to establish a minicun
- ptsping rate of 2 stmkes per second and enter the .
f - pletion Hecord. f
' d .; ,
4.2.3 Continue pucping for a mininsa of 8 hours, then shut off
)i ,'
the pucp. Enter the time into the Daily Operations Lcq and on the Dewatering Completion Record. 4.2.4 Lat the vessel stand overnight (a mininun of 14 hours). I', Hopeat Steps 4.2.1 thmugh 4.2.3. 4.2.6 j' ist the vessel stand for a mininum of 14 hoitrs.
- 4.2.6 (1$ ^* 4.2.7 Repwat Steps 4.2.1 through 4.2.3.
.y 4.2.8 Lat the vessel stand for a minicum of 14 hours.
[
#f Direct the devater pump discharge bose to a bucket or 4.2.9 h anotner container, 3
tg' 4.2.10 Hopeat Steps 4.2.1 through 4.2.3. g c 4.2.11 Measum the water collected with a gradtated cylinder. S h i 4.2.12 I.et the vessel stand for a mini.um of 14 hours. ai 4.2.13 Hepeat Steps 4.2.1 through 4.2.3. L') - 4.2.14 Measure the water collected with a graduated cylinder.
,1 4.2.15 Lat tne vessel stand for a mininum of 14 hours.
4.2.16 Hepeat Steps 4.2.1 through 4.2.3. < b . 4.2.17 Haasure the water collected with a gmduated evlinder. r mav. anasr occamsNT { - C 5 j t h M)P Oui C880 2**** 78
~ ^ ~ ' ~ ~ - - _ _ _ . . , , , ,
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PCP-00I s- 1-6 . .. Revision 4 7 (% r- Page 6 of 8 ( .< dk.,lt.- If greater than 500 mis are collected and measured in i V - 1 -j$y the previous step, let the vessel stand for a =inint.:n Continue of
% 16 hours and repeat Steps 4.2.1 thzeugh 4.2.3.
} I to repeat the waiting /punping cycle until less than 500 mis are collected during the pumping steps. ,
i = 1
- 4.2.19 Discennect the suction bose frcm the outlet connecticn of the vessel.
LI
- 4.2.20 If a 24-inch pressure vescel is being dewatered, install
}] the 1-1/2" quick connect caps with which the vessel was j delivered en the vescsl connections and safety wire .a shut.
If a FEP pressure deminerslizer is being dewater-ed, seal the vessel per Hef. 2.8. I d 5.0 R1DAWS
) .
Coglete the Dewatering Ccr@letion Recced, making certain that theFor- re-cord is accurate and in cocpliance with this Dewatericg Procedure. ward the original copy of the record to the CCSI wa-ager, Deminerali-
/.- zation Services. The operater shall retain a ecpy for his records.
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PCP-001 Attac! mint V d, llevision 4~ 3 r Page 7 of g [,,m\ FIGURE 1 (gjD AY 24-Inch Dia:neter Pressure Demineralizer Cantaining Activated Carben l- Devatering Q:cpletion Heocrd - 0.5% FSW
'(
_1 - Plant: - Customer: l]i
'l Vessel Serial Ntraer:
PM]P-001 Date Time CNSI Oeerator Proc. Steo Description f o 4.2.1 Start Dewatering Ptrp 4.2.3 Secure Dewatering Pump 4 Total Ptr:p TLme* 4.2.4 let Vessel Stand For 114 Hours
' 4.2.5 Start Desatering P.:p .
").
Secure Dewatering Ptrp
],: _
Total Ptr: ping Time
- E1 !
1 l 4.2.6 Let Vessel Stand For 114 Hours 5 #! 4.2.7 Start Dewatering Ptrp 1 Secure Dewatering Ptep Total Ptzping Time
- S. : .
4: 2i 4.2.8 Ist Vessel Stana for 114 Hours s.' fI i i 4.2.10 Start Dewatering Ptzp Secu:e Dewatering Pump , y
.[ Total Ptrrping Time
- c.1 :
Volune Of Water Collected mis /j . 4.2.11 a $ 4.2.12 Let Vessel Stand for 114 Hours 4.2.13 Start Dewatering Pt.- p ry Secure Dewatering Ptrp M A Total Ptreping Tirne* b Volune of water Collected mis p 4.2.14
'Pteping Time wust se 18 aours nav. aussT occunnesef A 7 RM)P-UU1 J L cusc ico2/s-7e
~
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PCP-001 Att.tcheent y Revision 4 3 Page 8 of 8 3=< ; .)
. FIGQG 1 (Cbot'd)
[ MP-001 Date Time _ CiSI Ooerator Proc. Step Descriptica
! 4.2.25 Let Vessel Stand For > 14 Hours 1
4.1 16 Start Dewatering Ptrnp
+
Secure Desatering Ptep
~
Total Ptaping Time = t, mis 4 4.2.17 Volune Of Water Collected Lat Vessel Stand For ?_14 Hours
' .2, (If Nmessary) Start Dewatering Ptep Secure Dewatering R=p
~i' Total Pttping Tire *
;}i ' 1, mis Volune of Water Collected
./I 8
*Pttping Time hst Be ),8 Hours
- us.s ,
I Ccements: I
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-stv.
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A COMPLETE REWRITE 1/13/% Md%
) d F3 g -_- _
1
? l B CHAMES PER CFACE RKtEST NP-004-02 C 03RCES PER CFREE REQCESI EO-OP-004-03 f-V-#3 f / M- .
D CHANGES PER CHANGE REQUEST FO-OP-004-04 f..L7-93 g gac6. m - ( PCP-001 Attachment VI i
! Revision 4 Page 1 of 6 d -
1 - a
.1 'I NA i -
f - 35 :
,j ! 8 NOTE: '
THIS INFORMATION IS COA'3IDERED PROPRIETARY AND ** IS j iq NOT TO DE RELEASED OR COPIED itITHOUT WRITTEN j PERMISSION OF CHEM-NUCLEAR SYSEFS, INC.
- j L
' ~
CNSI SA .4i REVEW
-; EG.33D APPN'! J , .
8-
- SY $12 '
-: . / .
DATE a // f>l 4
// - navision sva ,us .
1 aussT 1 2 3 4 5 6 l. 1.'s i~ new. D A C D D A e j
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- m. 1 j PREP 4ASD DATE CHEM -- NUCLEAR SYSTEMS, INC, 5.6.%% g.2e.e cHe TiTLs l'
DEWATERING PROCEDURE FOR THE 24-INCH 88G'N88a DIAMETER PRESSURE DEMINERALIIER VESSEL l.'., & f[3gdl CONTAINING. ION EXCHANGE RESINS l 9 - 6.5%/ l
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PCP-001 Attachment VI Revision 4 7 i Ogr a TABLE OF ODNTDrrs Page 2 of 6 l 4 Paae
~j l' ^
! I 3
l I 1.0 SOJPE i 2.0 REFER!N.TS
,3 I: 3 3.0 REX;UIRDDTS 4
4.0 OPERATLNG PHOC"EDURE
.c.
a 5 5.0 RhnRDS (i FIGt.T.E 1 - Desatering Cocpletica Pecord 6 .
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N "Y nav. susst . FO-OP-004 A 2 J L, CMac 10034 75
, _ _ _ . . . . _ . __.. _.___ _ _ . . _ _ . - . ~ . _ _ .____ _ _.. __.
PCP-001
- Accacncent a 3 r Revision 4 rage 3 og 6
.,J
~
~~'
l.1 Mis docunent contains the instructions for dewatering CNSI's carbon steel 24-inch diameter pressun demineralizer (Pef. 2.6) and Fiberglass Heinforced Polyester (ERP) High Integrity Contain-er P, essure Denineralizer (Hef. 2.7) containing ion-exchange l]j resi.. .te procedure and vessel configuration have txen tested for empliance in dewatering to less than 0.5% free-
- trading J' wr.cer as required by Chem-Nuclear Systens. Inc.'s State of South Carolina Radwsste Material License No. 097.
9~ l.2 he instructions contained in this procedure apply only to dewn-
'{ taring the carbon steel 24-inch diameter pressure demine.alizer q
' and Fiberglass Heinforced Polyester High Integrity Container 4
filled with ion-exchange resin.
+
2.0 REFERENCES
. 2.1 CN-AD-003, CNSI Procedure For Docunent Preparation
> 2.2 QA-AIMX)l, Quality Assurance Program 2.3 CN-AD-Ol9, CNSI ALARA Eblicy
. c CN-AD-Ol3, Test Control 2.4
$1.; I 2.5 Test Data, Engineering Project No.11475 g
c 2.6 CNSI Drawing.No. 334-0200 001, Pressure Cemineralizer 3 i 2.7 CNSI Drawing No. C-334-0-0005, Fiberglass High Integrity Ccn-tainer, 24" Pressu m Vessel 3.0 REVJIkhMY. JS i . 5 3.1 Prerequisites
- r. -
- Prior to dewatering the vessel, the CNSI operator shall: .
3
- 41 w-o Obtain a Hadiation Work Permit (or equivalent) from the 6 i 3.1.1 utility's Health Physics Department before entering the p:;8 process area.
9 'he utility's Health Physics personnel shall perform 3.1.2 - y/ radiation level and surface contamination survevs. Fre-i quency of the survey is to be detennined by the utilitv.
. Results of these surveys shall be recorded on the Daily Operations log as a permanent record.
3.1.3 Note the corrpletion of prerequisites in the Daily Opera-tions Icg.
. 3.2 Equiprrent
- p. {&'
?j m. 3.2.1 Warren Hupp Sandpiper 1-1/2" Pump with 1-1/2" FNPr con-nections, 1/2" FNFr air inlet. ( oesmaseT nev. suasT Y , t ' g P0-09-004 - C 3 cueoscowste e ,
- - ~ ~ -- - . . . . . . . _ . _ ,
f ~ . n m.
-}*w-w---e -.._.u_, ____
N . PCP-001
- _ - Attach .., v7 N r 3.2.2 Connectu1g Moses (1-1/2") Revision 4 3 Page 4 of 6
, Cs 3.2.2.1 Outlet hoses for the Sandpiper Purp (Para.
( 3.2.1) 3.2.2.2 Suction hose to connect between the pimp inlet
.lj ' and the msin liner dewatering connection (cule j quick connect).
3.2. 3 ' Service Air Hose (3/4", 150 psi) with proper connections I to mnnect to the Sandpiper Pu.mp (Para. 3.2.1) and a 3/4", 150 psi mupler to connect to the service air supply. p 3.2.4 Service Air: 20 SCW at 100 + 20 psig ,
.]
f{ 3.3 Precautions and Limitations il CAUTIW: H0613 AND OIEER RtESSULE RE. T AINING CIXpWDrtS MAY BE IRESSURIZID 1 DURING DISASSDELY. FACE SHIIIDS AND AP590RLIATE IBOTEX:TIVE Cloni-ING WST BE WCEN DURING DISASSDEIX OF DiIS EXaUIRENT. rh
, 3.3.1 Strong oxidizing agents such as nitric acid, when in con-tact with organic ion-exchange material and in the presence of air, may produce a slightly degraded msin in an exo-thennic maction, up to an explosion. . ' - 3.3.2 The CSSI technh.ian(s) shall wear safety glasses and/or .i: l, -- full face shields while working within 5 feet of pres- ?.I : 6 surized equipment.
3 p' ' The CGI technician (s) shall wear safety glasses while per-
. 3.3.3 ]j ,
forming his duties in the process area. 3.4 Accentance Criteria j 3.4.1 A volume measured of 1500 mis on the final- pumping'steo
- shall be the aceptance criteria. If not 1500 mis, the
- )j.
[ ,: , waiting / pumping cycle shall be repeated until 1500 mis is pm .
. collected.
- d.
- 4.0 UPhhATLNG WOCE1ERE CalfrIW: dis PREESURE DfMINHLALIZER MAY BE CINTAMINATED. DIE TBCHNICIAN
$g{..
a SHALL FOLIDI IBOPER RADIGLGICAL PRECAlfrIONS WHILE MAKING HOSE CCN-
- NECTIONS AND DEWATHLING die VESSEL.
l 4.1 Installation Precedure 4.1.1 Estaclish or verify that the msin liner is in a level position (visual determination). ,, {; . 4.1.2 Connect the suction hose (Para. 3.2.2.2) to the dewstering - connection on the resin liner and to the inlet of the Sand-
.. piper Pump (Para. 3.2.1).
1 4.1.3 Connect one end of the outlet hose (Para. 3.2.2.1) to the outlet of the Sandpiper pump (Para. 3.2.1) and direct the Oem ' other end to a drain that mturns to the radwaste system. 00cuassNT nev. SHEET j kU-UW UO4 D 4 ~ G cuea 1 eave n
,- --- - a. . . . - . . . . , _ _ , , , , _,
~
~ ~ ~.-. . _ . . , _ ~ _ . ,
3 ~ . -- ~ -
- - - - - - - - - - - A PCP-001. Attach =ang yr Revision 4 oc- 5 of 6 r 4.1.4 Connect the service air hose (Para. 3.2.3) to the service air supply (Para. 3.2.4) and the Sandpiper Pump (Para. 3.2.1).
4.2 Dewatering CAUTI W : SDK2G OXIDIZING AGDf!S SUG AS NI3IC ACID, WifEN IN (IlfrACT WITH CR-GANIC ICN-DOfANGE MATERIAL AND IN THE RESENCE OF AIR, MAY E00LG A SLIGfHJ DBGRADED RESIN IN AN EXU1ME?JdIC REACTICN, UP M AN EIMDSICtf. ME FIRST INDICATION OF AN E%DIMERMIC REACTICH DUE M DIE PRESENCE OP , , OXIDIZING AGERIS IS SCNE FLNING AND A SLIGHT RISE IN TEMPERXITRE (N DE
;j OLfrSIDE OF ME CINTAINER. IF WIS CINDITICNIS POUND THIN DEWATERING A 2
VESSEL, WE DeGDIATE ACTICN M BE TAKEN IS M REFILL M YESSEL WIE VATER. MIS WIIL EIMINATE CNE OF THE INGRIDIENIS NEX'ESSARY FCR WE RE i d ' AcrICH (AIR) AND WIIL DISSIPATE WE MAJCRITY OP WE HEAT, REITRNLNG UE " T1 TEMPERAn:RE CF ME VN M AMBIENT. WIS IS A STABLE (XFDITICN. EEN ' l YOUR DeGDIATE SUPERVISOR MUST BE NOTIFIID. d
] 4.2.1 Establish service air to the pump. 't ] 4.2.2 Adjust the pump air supply valve to establish a minimum pp-ping rate of 2 strokes per second. Enter the time into the '
5] Daily Operations log and the Dewatering Completien Record. i 4.2.3 Continue pumping for a mininun of 4 hours, then shut off the , pump. Enter the time into the Daily Operations Irg and the -
, Dewatering Cocpletion Record. ,j j~ 4.2.4 Direct the dewatering pump discharge hose to a bucket or other container.
j
* ] ,
4.2.5 Wait a rninie =n of 24 hours after securing the p:mp, then re-start the pr p. Enter the time into the Daily Operations 14G ;
* . and the Devatering Cmpletion Pecord.
4.2.6 Adjust the pump air supply to establish a mininun putnping y rate of 2 strokes per second. ,
.f nj 4.2.7 Contintu pumping for a minimum of 1 hour, then secure the j; pump. Enter the time into the Daily Operations I.og and the g} , 'M Dewatering Cornpletion Hecord.
j.p.g 4.2.8 heasure the water collected with a graduated cylinder. Q 4.2.9 Hepeat Steps 4.2.5 through 4.2.8.
, 4.2.10 If nere than 500 mis are collect' d e and measured in the pre-vious step, let the vessel stand for a minimum of 24 hours ;
and repeat Steps 4.2.5 through 4.2.8. Continue to repeat the waiting /purnping cycle until less than 500 mis are col-lected during the pumping steps. 5.0 REDJKUS k Complete the Dewatering Completion Record, making certain that the record is ) accurate and in compliance with this Dewatering Procedure. Forward the ori- '- ginal copy of the record to the utility's radwaste manager and transmit a g copy to the OSI Manager, Demineralization Services. 'lhe operator . tall re-g tain a copy for his records. s' u ' F0 09-004 D 5 L > C88841002/5 78 j
\
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- r. . Attacn= enc VL 7
. Revision 4 Page 6 of 6 1
(O FIGURE 1 l . 'V dSI 24-INCH DIAEITR ERESSURE DENINERALIZER l Q]NTAINING ION-EXCHANGE RESINS ' DEWATERING CDMFf.EfICN RECGD - 0.5% FSW l Cus e r: Plant: 'd' s
- e. . Vessel Serial Nxber* ;
PO-OP-001 Proc. Step Description Date Time CISI Operator L
'4 ,4 d 4.2.1 Start Dewatering Ptzrp d
j 4.2.3 - Securie Dewatering Pump
? .
Totsi Pxping Tm* (Must Be 2, 4 lburs) lh ' 4.2.5 Start Cewatering Punp
'l: {
. (After },,24 Hours) .
4.2.7 Stop Dewatering Pmp
,l' I %, l,, -
-.l " Total Pumping Tirse - d (Wust Be > 1 Hour)
.)
! 4.2.8 Water Femwed '
(During 2nd Dewatering) mis (l' d, 4.2.9 Start Dewatering Pucp , j (After > 24 Hours) . s
,t Stop Dewatering Purry
.4
- Tbtal Ptmping Time (Wust Be 2,1 lbur)
Water Bemoved mis
- (During 3rd Dewatering)
.. Cb ments:
g k . r.. z ! @DCCutsefsf 81EV. SMEET ', RMP-004 A 6 ; . < caso ioess m g . . - . - . . - - . . ..,.. -_. ...__,a.___,
-- . -- src -* - -e -e w -ween,- - ee - s- ~ . . .--n. ,
[ -- .- .--
; . = PCP-001
. Actachment VII Revision 4 f Pace 1 of 8 atvmoNs '
/ SRB APPROVAL R Ev. DESCRIPT:oN DATE
( [w) A CITcCES FER QLtCC EX. Unit IMP-009-01 APPR OV E D B o? -/6 - E 3 //d ~_% 79 A Jdhim. C CHANCES PER CHANCE REQt'EST FO-OP-009-02 OlGGES PER OIANCE REQlIEST FO-OP-009-03 4 4 5 4r3
///(/gi/
Mdd//,4'E
. v 70 /
'?
;3 4
i
}
i: i 1 ir (" CNSI SAFETY REVIEW N^ ! . TWEc DAIK ebt et. ' gg.eno COPY 8 " 4 - l WJrE: j
. 4 ,-
VIIS INITEMATIOi IS GNSIDERED HiOHlIETARY AND IS fur TO BE RELEASD P CDPIED WIV101.TT WRITIEN PDlMISSION OF OIDI-NUCLEAR SYSTD'.S. INC. ?,
'}i AEVISION STAT'JS 5+.sr7
[. f 1 2 3 4 5 6 7 l *- C C C C C C C Q wggr -
- a ne v.
DA TE ( dPREh 3.S.g CHEM - NUCLEAR SYSTEMS, INC. f' rkoNetR < gj;q f.2p b IDATWING RtOCE!X1HE FIH VIK r 5 CNSI 76-1101 DIAMETat HIESSURE DWINDIALIZFR Q i. n.'j.g,e 71 ^ QNTAINItiG 1(W-EXCHANGE RESINS QUALITt " s AA'$ q WJ~$9 APPR E ' CONTRACT No. DocuutuT No. RE v. swear h t t F04P6 C 1 j . c~.n .na.,. ,.
.___._.___..m . i. . __. -_J Attachment VII Revisica 4 l p Page 2 of 8 r
\
TABLE OF CONTENTS i PAGE NO. 1.0 SCOPE
........................... 3 '
1.1 Purpose a} 1.2 ....................... Applicability 3
- e,
.................... 3
;f)
2.0 REFERENCES
1-
......................... 3 3.0 REQUIREMENTS
........................ 3 3.1 Prerequisites 3.2 Equip;nent ..................... 3 d.
3.3 . ...................... Precautions and Limitations 4 1 3.4 Acceptance Criteria ..... ............. 4
'n ..
........... 5
! 4.0 1 OPERATING PROCEDURE . . . . . . . . . . . . . . . . . . . . . 5 4.1 4.2 Installation Procedure . . . . . . . . . . . . . . . 5 Dewatering Procedure . . . . . . . . .. ...... 5 5.0 0i .
RECORDS.. . . . . . . . . . . . . . . . . . . . . . . . . . . 6
- j. .3
. APPENDIX A - Dewatering Completion Record
............. 7 1Cp, . -
4 t L4,*
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M > CNSO 1003M N m.m .- _ . . . . _ . . . _ _ ~.. l---- +
.' PCP-001
. . Attachment VII Revision 4 Page 3 of 8 r
3 vs 1.0 SCOPE 1.1 Purpose o j This document contains an operating procedure for dewatering
-t CNSI's 76-inch Diameter Pressure Demineralizer. l 1.2 Applicability i
l
,i The instructions contained in this procedure apply only to i dewatering bead-type resins in CNSI's 76-inch Diameter Pressure q Demitieralizer, fabricated to the referenced CNSI drawing numbers, fj
2.0 REFERENCES
A 2.1 CNSI Procedure, CN-AD-003, " Procedure For Document Preparation" 2.2 CNSI Procedure, CN-AD-019 ALARA Policy" " Chem-Nuclear System Inc. (CNSI) 2.3 CNSI Procedure QA-AD-C01, " Quality Assurance Program" 2.4
, CNSI Drawing, General 334-3305-E01, "76-Inch Pressure Demineralizer, Arrangement" 3
Y, , 2.5 CNSI Drawing, 334-3306-E01, "76-Inch Pressure Demineralizer,
'i (p.7P- Weldment Sub-Assembly"
*O 2.6 .
CNSI Drawing, 334-3307-E01, "76-Inch Pressure Demineralizer
- Upper And Lower Sparger Sub-Assemblies" 2.7 CNSI Procedure, CN-AD-013 " Test Control"
' l 2.8 CNSI Procedure, NS-TP-001, " Dewatering Certification
..$l Program" Test I!
;i 2.9 CNSI Procedure, NS-TP-001-A, " Test Instruction for Determination cf Moisture Content in Dewatered Test Samples" N' 2.10
{ CNSI Procedure, DN-TP-001, " Test Instruction for Dewatering
' Pressure Demineralizers-Zero FSW" 2.11 CWSI Procedure, DN-TP-001-A, " Test Pressure Demineralizers-Zero FSW."
Report for Dewatering ~~d 3.0 EOUIREMENTS s 3.1 Prerequisites
~
Prior to dewatering the vessel, the CNSI, operator shall: 3.1.1 Obtain a Radiation Work Permit (or equivalent) from the I-process Health utility's area. Physics Department before entering the / f y _._ F0-OP-009 e C 3 J ca.so toove m . 4 . _ . . _ , _ , . _ - _ . - . - . -
l:
- PCP-001
; .,* Attachment VII Revision 4 y Page 4 of 8
- r- 3
,; ~
VJ 3.1.2 The utility's Health Physics personnel shall perfonn radiation level and surface contamination surveys. Frequency of the survey is to be determined by the ( utility. Results of these surveys shall be recorded on g) the Daily Operations Log as a pennanent record, j
; 3.1.3 Note the completion of prerequisites in the Daily j Operations Log.
M pm 3.2 Equipment c 3.2.1 Positive displacement diaphragm (1 -1/2" or 2") pump
;4 with 1-1/2" male quick-connect fittings on inlet and l fi outlet and 1/2" FNPT air inlet. ;i
[q 3.2.2 Connecting Hoses (1-1/2")
?)5 3.2.2.1 Outlet hose with a 1-1/2" female j quick-connect fitting to connect to the diaphragm pump (Para. 3.2.1). ):
jj 3.2.2.2 Suction hose with 1 -1/2" female quick-connect fittings to connect between Sj j --- the pump suction and the resin liner
/jt dewatering connection 1 (1-1/2" male jf ;
, w~
. quick-connect, Para. 3.2.2.1).
3, 3.2.3 Service air hose (3/4", 150 psi) with hose clamp to j- connect to the Sandpiper pump (Para. 3.2.1) and a 3/4", q 150 psi coupler to connect to the service air supply. 4 .
} 3.2.4 Service Air: 40 + 10 SCFM at 80 + 20 psig. ]' 3.3 Precautions And Limitations y'
pi i CAUTION: HOSES AND OTHER PRESSURE RETAINING COMPONENTS MAY BE ii PRESSURIZED. FACE SHIELDS AD APPROPRIATE PROTECTIVE Li - CLOTHING MIST BE WORN DURING DISASSEMBLY OF THIS 1.- EQUIPMENT. (g f ,- 3.3.1 s Strong oxidizing agents such as nitric acid, when in T. contact with organic ion-exchange material, may produce y - a slightly degraded resin in an exothermic reaction, up ' E to an explosion. s] 3.3.2 Inspect and use a appropriate, protective clothing, $ safety glasses, chemical splash goggles, face shield,
- hard hat, safety shoes, gloves and respirator. Know 3 where the nearest eyewash and safety shower are and how to use them.
7
- 3.3.3 If a straight ladder is used, it must be tied at the top and/or held at the bottom by a co-worker.
(Q oocunes=T nav. annar h F0-OP-009 . C 4
- w a casotoovsas M
---- ^
[ .,.
, e' Attachment VII Revision 4 sPage 5 of 8 r
3 3.4 Acceptance Criteria A volume me2s'urements of less than or equal t'o 4 If ters on the final pump?nk step shall be the acceptance criteria. If not les.s than or equal to 4 liters, the waiting / pumping cycle shall be repeated until less than or equal to 4 liters is collected. I 4.0 OPERATING PROCEDURE
\ .l M ', g 'j . CAUTION:
THE RESINS CONTAINED IN THE DEMINERALIIER YESSELS MAY BE 1 RADI0 ACTIVE ANJ THE VESSEL MAY BE CONTAMINATED. THE nl TECHNICIAN SHALL TAXE PRCPER RADIOLOGICAL . PRECAUTION q WHILE MAXING HOSE CONNECTIONS AND DEWATERING THE VESSEL i 4.1 Installation Procedure i 4.1.1 Establish or verify that[the Ifner is in a level d l position (visual detennination). j} , i' s, 4.1.2 Establish or verify tha t the vessel intet and vent 1, connections are open.
+
'g 4.1.3 Connect the t suction hose (Para. 3.2.2) to the f )
quick-connect fitting of the vessel outlet connection i and to the suction of the Sandpiper pump (Para. 3.2.1). 4 4.1.4 d($//. 1 Connect one end of the outlet hose (Para. 3.2.2) to the discharge of the Sandpiper pump (Para. 3.2.1), and j\# direct
.I radwastethe other end to a drain that returns to the system.
4.1.5
.i Connect the service air hose (Para. 3.2.3) to the *j service air supply (Para. 3.2.4) and the Sandpiper pump (Para. 3.2.1).
$' 4.2 Dewatering Procedure 1. ?i CAUTION: ?. STRONG OXIDIZIdG AGENTS SUCH AS k'IfRIC ACID, WHEN I'N F- CONTACT WITN ORGANIC ION-EXCHANGE' MATERIAL, PRODUCE t - A SLIGHT DEGRADED RESIN IN AN EXOTNRMIC REACTION, UP TO AN EXPLOSION. g- THE FIRST INDICATION OF AN % EXOTHERMIC MACTION DUE TO THE PRESENCE OF OXIDIZING AGENTS IS' SOME FUMING AWO A ~ SLIGHT RISE IN ' TEMPERATURE ON THE OUTSIDE OF THE CONTAINER. IF THIS CONDITION IS FOUND WHEN DEWATERING A VESSEL, THE IMEDIATE ACTION TO BE TAKEN IS TO REFILL THE VES3EL WITH WATER. THIS WILL DISSIPATE THE MAJORITY g OF THE HEAT, RETURNING THE TEMPERATURE OF THE VESSEL g TO AMBIENT. THIS IS A STABLE CONDITION. THEN, YOUR
. DNEDIATE SUPERVISOR MUST BE NOTIFIED.
k > g . . + ' i. i
- > occwswr new. y F
1 w F0-0P-009 C 5 h I J Cse841002/948
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~ rcy-uul Attachment VII
_ , .' .- Revision 4 Page 6 of 8 r r { 4.2.1 Establish service air to the pump. r 4.2.2 Adjust the pump air supply valve to establish a I pumping rate of approximately 2 strokes per second and enter the time into the Daily Operations Log and the Dewatering Completion Record (Figure 1). 4.2.3 Continue pumping until pump suction is lost as indicated by a significant increase in the pump stroke rate, then shut off ' the pump. Enter the shut-off time in the Daily Operations Log and the l3 Dewaterfng Completion Record. h 4.2.4 Disconnect the suction hose from the vessel outlet
] 1 connection.
n 4.2.5 Connect dewateringthe suction hose (Para. 3.2.2) to the vessel connection. 4.2.6 Establish service air to the pump.
- d. 4.2.7 Adjust the pump air supply valve to establish a
-{
- 1 pumping rate of 2 strokes per second minimum and enter the time' in the Daily Operations and the Dewater'ing Completion Record.
I 4.2.8 Continue pumping for a minimum of 8 hours, then shut p
) ;(g3 off the pump. Enter the shut-off time in the Daily Aj- Operations Log and the Dewatering Completion Record.
4.2.9 Let the vessel stand for a minimum of 8 hours. 4.2.10 Repeat . Steps 4.2.6, 4.2.7, 4.2.8, 4.2.9 for a minimum of 5 dewatering cycles. 4.2.11 Prior to the last pumping cycle, direct the f , i discharge hose to a bucket or any suitable container, l' 4.2.12 L -; Measure the water collected on the last pumping p cycle with a graduated cylinder. If less than or equal to 4 liters is collected, repeat Steps 4.2.6 through 4.2.8 until the volume collected is less g than or equal to.4 liters. - - i ? 4.2.13 Disconnect the suction hose from h the vessel dewatering connection. 5.0 RECORDS ? W Confirm that the completed Dewatering Completion Record is accurate and
- in compliance with the dewatering pro to the utility's Radwaste Supervisor.cedure, then forward the ori inal e W
copy for the ff eld unf t records, The technician shall ret na fc + k
'=
DocuesENT
. REV. SHEET F0-OP-009 C' 6 0 cNeo soo2/sas n .- . - .- . . ... - . - - - . -. ..
f [1,7 y --w, -
, ,. - . , , , qw %,y -
PCP-001
- Attachment VII 1
*Q R,evision
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APPENDIX A DEWATERING COMPLETION RECORD
..l .. (1 PAGE)
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.. e Attachment VII
=)
Revision 4
' Page 8 of 8
]'l 3 g- r
'n DEWATERING COMPLETION RECORD i
Customer: Plant: Vessel Type: Media: Serial # Technician's Name: Date: N d Technician's Procedure Step Description Date Time Initial s ,
.j
! Start Pumping Cycle 1 k Complete Pumping Cycle 1 y
i Start Pumping Cycle 2 - t
] Complete Pumping Cycle 2 Start Pumping Cycle 3 f
) Complete Pumping Cycle 3
-'s Start Pumping Cycle 4
~'
7 Complete Pumping Cycle 4 Start Pumping Cycle 5
~
l Complete Pumping Cycle 5
.l' Start Pumping Cycle 6 j
Complete Pumping Cycle 6 _ Start Pumping Cycle 7
-}
Li - ' Complete Pumping Cycle 7 {} Yolume Collected on last Pumping cycle mi s. (1 I: 4 M NOTE: IF THE VOLUME COLLECTED DURING LAST PUMPING CYCLE EXCEEDS j: ' ~ THE ACCEPTANCE CRITERIA ADDITIONAL CYCLES MUST BE COMPLETED UNTIL ACCEPTANCE CRITERIA IS MET. RECORD DATA ON BACK OF 0 THIS PAGE. ENTER "N/A" FOR CYCLES NOT REQUIRED. @ 4 b V DOCUMENT R E V. SHEET FO-0P-009 C 8 J h ( CNSQ 1002/8 75 ~ 1 _}}