ML20151X135

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Rept of Irradiation & DBA Testing
ML20151X135
Person / Time
Site: Braidwood Constellation icon.png
Issue date: 10/28/1983
From: Laing W
OAK RIDGE NATIONAL LABORATORY
To:
Shared Package
ML20151W894 List:
References
NUDOCS 8602120307
Download: ML20151X135 (24)
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Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory St. Louis, M0 Date: 10/27/83 REPORT OF IRRADIATION AND DBA TESTING The irradiation test is conducted in accordance with Ameri.can Society for Testing and Materials (ASTM) Standard Method D4082-83. The design basis accident (DBA) test is performed in accordance with ASTM Standard Method 03911-80. The tests are designed to meet specifications set in both ANSI report N101.2-1972, Protective Coatings (Paints) for Light Water Nuclear Reactor Containment Facilities, and N5.12-1974, Protective Coatings (Paints) for the Nuclear Industry. The DBA test spray solution was distilled water.

The test conditions are listed in Table 1. After both the DBA and irradiation tests, coatings are examined for signs of chalking, blistering,

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cracking, peeling, delamination, and flaking, according to ASTM standards 3 where applicable. All test panels are returned to the coating manufacturer.

The irradiation tests are run using a spent fuel assembly, removed from the High-Flux Isotope Reactor at ORNL, as the source of radiation. These fuel assemblies are stored under 20 ft of demineralized water. The fuel is 93% enriched U-235 as U 03 8 combined with aluminum. The spent fuel as-semblies are removed after each .23-megawatt-day period. Irradiation is done using the gamma energy from accumulated mixed fission products. This more readily simulates conditions around a reactor than does a cobalt source.

Also, the higher ganna activity affords shorter irradiation time to achieve accumulated doses. The doge rate four days after removal of a fuel assembly from the reactor is 1 x 10o rad /h.

The fuel assembly is 20 in, high. A 20-f t-long, 3-1/2-i n. -diamete r pipe, with one end capped, is used for air irradiation tests. The capped end is lowered into a 4-in. opening at the center of the fuel assembly. The open end, above water level, is covered with an 0-ring-sealed flange to which is attached a steel cable and an air outlet hose. The air inlet is located at the bottom of the pipe. Test specimens are connected to the bottom of the cable and lowered i nto the radiation field. Also at the center of the fuel assembly is a stainless steel-clad cadmium tube used as a neutron absorber. This prevents contamination of the test specimens by induced radiation.

k Evaluated / d Approved [

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.' Manufacturer: Carboline Analytical Chemistry Division Oak' Ridge National Laboratory St. Louis, M0 Date: 10/23/83 ORNL Log Book No. A9675, A10/20/3 Table 1. DBA test conditions Temperature Pressure Time (*F) (psig) Comments Start 170 Autoclave preheated.

20 s 340 70 (10 s) Steam injected.

5 min 50 s 340 70 Steam turned off.

6h 340 70 Pressure maintained by relief valve.

20 s 220 30 Spray solution added at 75*F.

15 min 220-250 30 Pressure adjusted with N2-4d 250 30 20 s 180 -15 Fresh spray solution added at 75*F after draining autoclave.

10 min 180-200 10 3d 200 10 End of test 7 / /

Evaluated //h.r -dd;f.[L Approved h I

~ . . - . . . - - . _

Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory -

St. Louis, M0 Date: 10/27/83

. Carboline Testing Project #02182

-SYSTEM IDENTIFICATION x Steel panel Concrete block Ic Carbo Zinc 11 RADIATION TOLERANCE TEST ORNL' Master Analytical Manual Method No. 2 0921; ASTM Standard Method D4082-83; ORNL Log Book No. A9675, A10-13-3.

Initial dose rate: 1.35 x 107 rad /h Test conducted in: x air water Dry Film thickness Sanple No. (mils)* Cumulative dose Test results 1 2. 5 1.0 x 109 rads Coating intact, no defects.

2 2.6 1.0 x 109 rads Coating intact, no defects.

3 2. 8 1.0 x 109 rads Coating intact, no defects.

4 2.8 1.0 x 109 rads Coating intact, no '

defects.

9 3.8 1.0 x 109 rads Coating intact, no defects.

10 4.3 1.0 x 109 rads Coating intact, no defects.

11 4.5 1.0 x 109 rads Coating intact, no defects.

12 3.8 1.0 x 109 rads Coating Intact, no defects.

  • Dry film thickness values provided by Carboline Evaluated M. dt / d' Approved i

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Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory.

St. Louis, M0 Date: 10/27/83 Carboline Testing Project #02182 SYSTEM IDENTIFICATION x Steel panel Concrete block

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Ic Carbo Zinc 11 RADIATION TOLERANCE TEST ORNL Master Analytical Manual Method No. 2 0921; ASTM Standard Method D4082-83; ORNL Log Book No. A9675, A10-13-3.

Initial dose rate: 1.35 x 107 rad /h Test conducted in: x air water Dry Film thickness Sample No. (mils)* Cumulative dose Test results 17 5.8 1.0 x 109 rads Coating intact, no defects.

18 5.5 1.0 x 109 rads Coating intact, no

' defects.

19 6.0 1.0 x 109 rads Coating intact, no defects.

-20 5.8 1.0 x 109 rads Coating intact, no defects.

  • Dry film thickness values provided by Carboline Evaluated [/2dTT .he Approved 4 I

Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory St. Louis, M0 Date: 10/27/83 Carboline Testing Project #02182 SYSTEM IDENTIFICATION x Steel panel Concrete block 2c Carbo Zinc 11 RADIATION TOLERANCE TEST ORNL Master Analytical Manual Method No. 2 0921; ASTM Standard Method D4082-83; ORNL Log Book No. A9675, A10-13-3.

Initial dose rate: 1.35 x 107 rad /h Test conducted in: x air water Dry Film thickness- '

Sample No. (mils)* Cumulative dose Test results 25 2.1/3.1 1.0 x 109 rads Coating intact, no defects.

26 2.3/3.2 1.0 x 109 rads Coating intact, no defects.

27 2.4/3.4 1.0 x 109 rads Coating intact, no ~

defects.

28 2.4/2.9 1.0 x 109 rads Coating intact, no defects. "

33 3.0/2.3 1.0 x 109 rads Coating intact, no defects.

34 3.0/2.0 1.0 x 109 rads Coating intact, no defects.

35 3.0/2.7 1.0 x 109 rads Coating intact, no defects.

36 3.0/2.7 1.0 x 109 rads Coating intact, no defects.

  • 0ry film thickness values provided by Carboline Evaluated / / d d r r,, h Approved 4

Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory

. St. Louis, M0 Date: 10/27/83 Carboline Testing Project #02182 SYSTEM IDENTIFICATION x Steel panel Concrete block Ic Carbo Zinc 11 DBA TEST ORNL Master Analytical Manual Method No. 2 0922.

ORNL Log Book No. A9675, A10-20-3.

Dry Film Thickness Sample No. (mils)* DBA phase Test results

    • 1 2.5 Spray Coating intact, no defects

.except discoloration

    • 2 2.6 Spray Coating intact, no defects except discoloration
    • 3 2.8 Spray Coating intact, no defects except discoloration
    • 4 2.8 Spray Coating intact, no defects except discoloration 5 2.7 Spray Coating intact, no defects except discoloration 6 2.3 Spray Coating intact, no detects except discoloration 7 2.5 Spray Coating intact, no defects except discoloration 8 2.6 Spray Coating intact, no defects except discoloration
  • Dry film thickness values provided by Carboline
    • Irradiated Evaluated.tM/>N a' Approved M i

Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory St. Louis, M0 Date: 10/27/83 Carboline Testing Project #02182 SYSTEM IDENTIFICATION x Steel panel Concrete block ic Carbo Zinc 11 DBA TEST ORNL Master Analytical Manual Method No. 2 0922.

ORNL Log Book No. A9675, A10-20-3.

Dry Film Thickness Sanple No. (mils)* DBA phase Test results

    • 9 3.8 Spray Coating intact, no defects except discoloration
    • 10 4.3 Spray Coating intact, no defects except discoloration
    • 11 4.5 Spray Coating intact, no defects except discoloration
    • 12 3.8 Spray Coating intact, no defects except discoloration 13 4.3 Spray Coating intact, no defects except discoloration 14 3.8 Spray Coating intact, no defects except discoloration 15 3.8 Spray Coating intact, no defects except discoloration 16 3.8 Spray Coating intact, no defects except discoloration
  • Dry film thickness values provided by Carboline
    • Irradiated Evaluated /jb'br '

Approved / f i

Manufacturer: Carboline' Analytical Chemistry Division

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Oak Ridge National Laboratory St. Louis, M0 Date: 10/27/83 Carboline Testing Project #02182 SYSTEM IDENTIFICATION x Steel panel Concrete block

-Ic Carbo Zinc 11 DBA TEST ORNL Haster Analytical Manual Method No. 2 0922.

ORNL Log Book No. A9675, A10-20-3.

Dry Film Thickness Sample No. (mils)* DBA phase Test results

    • 17 5.8 Spray Coating intact, no defects except discoloration-
    • 18 5.5 Spray Coating intact, no defects except discoloration
    • 19 6.0 Soray Coating intact, no defects except discoloration

~ **20 5.8 Spray Coating intact, no defects except-discoloration 21- 5.8 Spray Coating intact, no defects except discoloration 22 6.0 Spray Coating intact, no defects except discoloration

-23 5.5 Spray Coating intact, no defects except discoloration 24 5.8 Spray Coating intact, no defects except discoloration

  • Dry film thickness values provided by Carboline
    • Irradiated Evaluated MIE, 6 Approved [ tA,

Manufacturer: Carboline Analytical' Chemistry Division Oak Ridge National Laboratory St. Louis,'M0 Date: 10/27/83 Carboline Testing Project #02182 4

SYSTEM IDENTIFICATION x Steel panel Concrete block 2c Carbo Zinc 11-DBA TEST ORNL Master Analytical Manual Method No. 2 0922.

~ORNL Log Book No. A9675, A10-20-3.

e Dry Film Thickness Sample No. (mils)* DBA phase Test results

    • 25 2.1/3.1 Spray Coating intact, no defects except discoloration
    • 26 2.3/3.2 Spray Coating intact, no defects except discoloration
    • 27' 2.4/3.4 Spray Chalking, discoloration
    • 28 2.4/2.9 Spray ~ Coating intact, no defects except discoloration

.29 2.3/3.2 Spray Chalking, discoloration 30 2.4/3.1 Spray Coating intact, no defects except discoloration 31 2.3/3.5 Spray Coating intact, no defects except discoloration 32 2.4/3.1 Spray Coating intact, no defects except discoloration

  • Dry film thickness values provided by Carboline
    • Irradiated Evaluated / 7/k uI(

Approved I

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' Manuf acturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory St. Louis, M0 Date: 10/27/83 Carboline Testing Project #02182 SYSTEM IDENTIFICATION x Steel panel Concrete block 2c Carbo Zinc 11 DBA TEST

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ORNL Haster Analytical Manual Method No. 2 0922.

ORNL Log Book No. A9675, A10-20-3.

Dry Film Thickness Sample No. (mils)* DBA phase Test results

    • 33 3.0/2.3 Spray Chalking, discoloration
    • 34 3.0/2.0 Spray Chalking, discoloration
    • 35 3.0/2.7 Spray Coating intact, no defects except discoloration
    • 36 3.0/2.7 Spray Coating intact, no defects except discoloration 37 3.0/2.3 Spray Coating intact, no defects except discoloration 38 3.0/2.3 Spray Coating intact, no defects except discoloration 39 3.0/3.0 Spray Coating intact, no defects except discoloration 40 2.8/2.5 Spray- Coating intact, no defects except discoloration
  • Dry film thickness values provided by Carboline
    • Irradiated Evaluated /kMc .

Approved l

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TEST PANEL PREPARATION DATA Testing Project #02182 Coating System: Ic Carbo Zine 11 Substrate Type: Steel, certified STI Surface Prep.: SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical Other:

I. Coating System Ic Carbo Zine 11 at 2.0-3.0 Mils DFT at Mils DFT at Mils DFT at Hils DFT at Mils DFT Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F5182Z Product Part A Part B Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Specimen Date Method *F  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 1 CZ11 A 8/18/83 Spray 78* 75 2.5 2.5 2 B 2.6 2.6 3 A 2.8 2.8 4 B 2.8 2.8 5 A 2.7 2.7 6 B 2.3 2.3 7 A 2.5 2.5 8 B 2.6 2.6 Issued: November 1, 1983 Submitted by: *

  • 'I

Title:

Supervisor, Testing Dept.

Sheet 1 of 7 jas/110183 test panel prep data 02182

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TEST PANEL PREPARATION DATA Testing Project #02182 Coating System: Ic Carbo Zine 11 Substrate Type: Steel, Certified STI Surface Prep.: SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical Other:

I. Coating System Ic Carbo Zine 11 at 3.0-5.0 Mils DFT at Mils DFT at Mils DFT at Mils DFT

s. at Mils DFT Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F5182Z Product Part A Part B Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Specimen Date Method *F  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 9 CZ11 A 8/17/83 Spray 86* 50 3.8 3.8 10 B 4.3 4.3 11 A 4.5 4.5 12 B 3.8 3.8 13 A 4.3 4.3 14 B 3.8 3.8 15 A 3.8 3.8 16 B 3.8 3.8 Issued: November 1, 1983 Submitted by: I!

Title:

Supervisor, Testing Dept.

Sheet 2 of 7 jas/110183 test panel prep data 02182

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TEST PANEL PREPARATION DATA Testing Project #02182 Coating System: Ic Carbo Zine 11 Substrate Type: Steel, Certified STI Surface Prep. : SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical Other:

I. Coating System Ic Carbo Zine 11 at 5.0-7.0 Mils DFT at Mils DFT at Hils DFT at Mils DFT at Mils DFT 3- Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F51822 Product Part A Part B Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Specimen Date Method 'F  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 17 CZ11 A 8/18/83 Spray 78' 75 5.8 5.8 18 B 5.5 5.5 19 A 6.0 6.0 20 B 5.8 5.8 21 A 5.8 5.8 22 B 6.0 6.0 23 A 5.5 5.5 24 B 5.8 5.8

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Issued: November 1, 1983 Submitted by: * -

Title:

Supervisor, Testing Dept.

Sheet 3 of 7 jas/110183 test panel prep data 02182

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TEST PANEL PREPARATION DATA Testing Project #02182 Coating System: 2c Carbo Zine 11 Substrate Type: Steel, Certified STI Surface Prep.: SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical Other:

I. Coating System 1st coat Carbo Zine 11 at 2.1-2.4 Mils DFT 2nd coat Carbo Zinc 11 at 2.9-3.5 Mils DFT at Mils DFT at Mils DFT at Mils DFT Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F5182Z Product CZ 11 Part A 3C0841M Part B 3F5182Z Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Specimen Date Method 'F  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 25 CZ11 A 8/18/83 Spray 78* 75 2.1 2.1 26 B 2.3 2.3 27 A 2.4 2.4 28 B 2.4 2.4 25 CZ11 A 8/19/83 Spray 86 54 3.1 5.2 26 B 3.2 5.5 27 A 3.4 5.8 28 B 2.9 5.3 Issued: November 1, 1983 Submitted by: 4 l'

Title:

Supervisor, Testing Dept.

Sheet 4 of 7 l

jas/110183 test panel prep data 02182 l

arboIIne, ate =eami. e(Am'% U. 5' .mA ma3 tama.

TEST PANEL PREPARATION DATA Testing Project #02182 Coating System: 2e Carbo Zine 11 Substrate Type: Steel, Certified STI Surface Prep.: SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical Other:

I. Coating System Ist coat Carbo Zine 11 at 2.1-2.4 Mils DFT 2n,d coat Carbo Zine 11 at 2.9-3.5 Mils DFT at Mils DFT at Mils DFT at Mils DFT Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F5182Z Product CZ 11 Part A 3C0841M Part B 3F5182Z Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Specimen Date Method 'F  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 29 CZ11 A 8/18/83 Spray 78 75 2.3 2.3 30 B 2.4 2.4 31 A 2.3 2.3 32 B 2.4 2.4 29 CZ11 A 8/19/83 Spray 86 54 3.2 5.5 30 B 3.1 5.5 31 A 3.5 5.8 32 B 3.1 5.5 Issued: November 1, 1983 Submitted by: ,

W

Title:

Supervisor, Tisting Dept.

Sheet 5 of 7 jas/110183 test panel prep data 02182

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Testing Project #02182 Coating System: 2e Carbo Zine 11 Substrate Type: Steel, Certified ST1 Surface Prep.: SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical Other:

I. Coating System ist coat Carbo Zine 11 at 2.8-3.0 Mils DFT 2nd coat Carbo Zine 11 at 2.0-3.0 Mils DFT at Mils DFT at Mils DFT at Mils DFT Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F51822 Product CZ 11 Part A 3C0841M Part B 3F5182Z Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Specimen Date Method 'F  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 33 CZ11 A 8/17/83 Spray 86 50 3.0 3.0 34 B 3.0 3.0 35 A 3.0 3.0 36 B 3.0 3.0 33 CZ11 A 8/19/83 Spray 86 54 2.3 5.3 34 B 2.0 5.0 35 A 2.7 5.7 36 B 2.7 5.7 Issued: November 1, 1983 Submitted by: [

Title:

Supervisor, Testing Dept.

Sheet 6 of 7 jas/110183 test panel prep data 02182 l

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TEST PANEL PREPARATION DATA Testing Project #02182 Coating System: 2c Carbo Zine 11 Substrate Type: Steel, Certified STI Surface Prep.: SSPC-SP10-63 For: DBA x Radiation x Decon Physical Chemical ___ Other:

I. Coating System 1st coat Carbo Zine 11 at 2.8-3.0 Mils DFT 2nd coat Carbo Zine 11 at 2.0-3.0 Mils DFT at Mils DFT at Mils DFT at Hils DFT Total Mils DFT II. Batch Numbers Product CZ 11 Part A 3C0841M Part B 3F5182Z Product CZ 11 Part A 3C0841M Part B 3F5182Z Product Part A Part B Product Part A Part B Product Part A Part B III. Application Criteria Actual Sprcfmen Date Method 'T  % Dry Film Thickness Number Product Side Applied Applied Temp. Rel. Hum. DFT/ Coat Total DFT 37 CZ11 A 8/17/83 Spray 86 50 3.0 3.0 38 B 3.0 3.0 39 A 3.0 3.0 40 B 2.8 2.8 37 CZ11 A 8/19/83 Spray 86 54 2.3 5.3 38 B 2.3 5.3 39 A 3.0 6.0 40 B 2.5 5.3 Issued: November 1, 1983 Submitted by: [ N7'

Title:

Supervisor, Testing Dept.

Sheet 7 of 7 jas/110183 test panel prep data 02182

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SURFACE PREP AND CURE DATA FOR TESTING PROJECT 02182 2"x4"xk" certified ASTM A36 Steel Surface Preparation: gritblasted to SSPC-SP10-82 with a 2.0-3.0 mil profile Abrasive Medium: 50/50 mir of GFH #40 grit and S230 shot.

CURE DATA Cure Temperature Humidity Coatings Time Range Range Ic CZ 11 @ 2.0-3.0 mils 30 days 80*F (27*C) 80%

Ic CZ 11 @ 3.0-5.0 mils 30 days 80*F (27'C) 80%

< Ic CZ 11 @ 5.0-7.0 mils 30 days 80*F (27'C) 80%

2c CZ 11 @ 2.0/3.0 mils First Coat:

24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 74-86'F (23-30*C) 53-78%

- 2nd Coat:

30 days 80'F (27'C) 80%

2c CZ 11 @ 3.0/2.0 mils First Coat:

48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> 74-86'F (23-30*C) 50-78%

2nd Coat:

30 days 80*F (27'C) 80%

All CZ11 panels were cured in Thermotron Environmental Chamber at 80*F, 80%

R.H. In addition, panels remained in ambient room conditions a few days at Carboline plus additional time at ORNL prior to testing.

jas/042784 Su-face Prep / Cure Data TP02182

l '~# UO PRODUCT IDENTIFICATION Product Name Carbo Zine Product Number 11 Generic Description Inorganic Zine Primer 5./ y.1 Green Weight Per Gallon Part A Base Range From 8.6 To 9.0 Grey Part B Zine Range From N/A To N/A Part C N/A Range From N/A To N/A Viscosity Brookfield. Part A - Range From 100 To 300 cps (list method) 75 1 2*F Part B - Range From N/A To N/Ar Part C - Range From N/A To N/A Total Solids Part A - 35 1 3 % Weight N/A  % Volume j' Part B - 100  % Weight 100  % Volume Part C- N/A  % Weight N/A  % Volume Flash Point D-93-73 ASTM Part A - 56 *F Part B -

Powder 'F Part C -

N,/A *r Mixed Components -

N/A *F Mixing Ratio Part A 100 By Weight N/A By Volume Part B 220 By Weight N/A By Volume Part C N/A By Weight N/A By Volume Recoat Time at 40*F 36 hra. Full Cure Time 36 hrs. At 40 *F at 50% R.H. ~

at 50*F 24 hrs. 24 hrs. At 50 *F at 70*F 12 hrs. 12 hrs. At 70 *F at 90*F 8 hrs. 8 hrs. At 90 *F Service Temperature Limits Maximum 110** *F Wet 750 *F Dry Minimum -60 *F Wet -60 *F Dry Storage Life 12 Months Pot Life - @ 50*F 16 hrs @70*F 8 hrs @90*F 4 hrs Compressive strength ASTM C-579-68 7 days @ 70*F N/A Tensile strength ASTM C-307-61 7 days @ 73*F N/A Modulus of Elasticity ASTM C-580-74 7 days @ 73*F N/A Flexural strength ASTM C-580-74 7 days @ 73*F N/A Initial set time ASTM C-308-71 @ 73*F N/A

    • Continuous Immersion Service Date- 8/W Ehl Approved [ ([ & L.L4__ , Test Report No.

TS- 06376-2

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~.~.-- PN IEN'ITW NO %"IY ASSUPANCE RFIFICATICN RECDRD PUIqmASER M/2,, bm '

CUS'IQ1ER P.O. #

s p goa CARBOLINE INVOICE # / "/'S y f/

. @ BESS M O M db j of Nle'. .& 63/W AmmICNEa O NME OF PR$JfCr STATARD E"u!

Bat & Nurter N/A 30 O[4t/prJ Data of Manufacture N/A M /Qf3 Shelf Life 12 Months 3 - 74. Exp . Da t.,

Weight Per Gallon (FIMS 141a.4;84) 8.5-5.3 Ibs. J. 94* A E Viscosity - Method Broukfie1d M *rfd' 5 Viscosity 150-250 ces /$9 h 3 l .c Tirperature 75 2 2 r os' *r U Cblor - Visual Decends on Order G f EEA/

y Ntster N/A D300 5

N l8 mtsBateTestedBy--Initial /Datep.f 4h7/f3 Mixing Ratio by Weight 100 Parts Base to 220 Parts Zinc 1000 mil sq.ft./ gal.

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THEORETICAL COVERAGr Pot Life 8 (minimum) Hours at 75 _' F 50  % E..

Flash Point-Pensky-Martans Closed N Cup (MTIM D-93) CIhis Ctrponent Only) 56 *F g

  • s R.H Tack rree Time 1/2 (minimum) neurs at 75 r s0

$ Itacoat Tice 12(minimum) Iburs at 75 'F g 4 R.H 16 Final Dry Time 12 (minimum) Hours at

  1. ,33 or v21 75 'F 50  % R l!

OE Specified Carboline Thinner kb Innocr.tnended Dry Film Thekness pee tbat_ 2-3 Mils g

g mis product is harmby certified as manufactured in accordance with the l8 Carboline Quality Assurance Program. When mixed in accorda:we with Carbolire g printed instructions, it is within tranufacturing tolerances of the batches originally tasted in accordance with ANSI N101.2, ANSI N101.4 and ASSI 512.

' .8 u Q.A./Q.C. Supervisor Signature:

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/dbj Date: (-3 -83

( /I i Production Services h .t--Signature: w. , hb _ ~ m

Title:

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d S- V-/3 l rarm Data. 6 h7/70 m -

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_,,,_,,,, PRCIIIT N AND CUALI7Y ASSURANCE ua<rinCATICN REEDRD PUREASER ffhdg!6 h CUSTOER P.O. # -

" SKIP Kf / CARBOLDE DEICE # 3/7 W AtcRess M D / k h a/f/al.cf 6} 4wS / fe. 63l'/V ATIENTICE ShM M9,4Whl NA>E OF PluTILT STANDARD . BAIUI a Batch Nurtar N/A .3 F5'/ FS Z Data of Manufacture WA Om /98?

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Shelf Life 24 .h ths "0/4 - 2::p . ::,

Color - Visual _ Meta 11ic crw h///LZb

, Sieve Analysis 325 mesh 5% Maximum Retained / T N r hz/d (OCT4 127) 100 mesh 99.9% Minimum Through /SB N /.

o f This Batch Testad h Initial / Data / / 7-/f-N 5 o Mixing Ratio: See I.iquid Ca:ponant Product Identity Certificaticns or Application Instructions.

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g This product is hereby certified as manufactured in accordance with the

,, Carboline Quality Assurance Program. When used in accortlance with Cartolit.e e g printed instructions, it is within manufacturing toleran:cs of the batch.s

[ criginally tested in acmrdance with ANSI N101.2, ANSI N101.4 and ANSI 512.

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Q.A./Q.C h bihUt / ndb m Data: 9-/ V- #1 Prtriuction Services Departrent-Signatures W. 4. # ,

Title:

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QB 42881-1

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OAK RIDGE NATIONAL LABORATORY eost once so =

oasaatto ev manra maa<m ewaar sysnus. ac May 2, 1984 Mr. Tom Aldinger M&QS Bechtel Group, Inc.

50 Beale Street P. O. Box 3965 San Francisco, CA 94119

Dear Tom:

This is in response to my phone conversations with fir. Yuly Korobov and yourself concerning Carboline Testing Project #02182 and your request for clarification of our coments on samples 27, 29, 33 and 34 The coments read " chalking, discoloration". The discoloration occurred on all samples in this test; the color changed from green to dark gray. The chalking as reported for the above samples was not excessive and indicates that some material could be removed from the samples by wiping kith a cloth.

If there are any questions or we can be of further service, please call on us.

Sincerely, fb R. D. Brooksbank Chemist RDB:1p ,

cc: Yuly Korobov -

a TESTING PROJECT: 02182 Sample No. DFT Before DFT After 1 2.5 2.5 2 2.6 2.6 3 2 .' 8 2.8 4 2.8 2.8 5 2.7 2.3 6- 2.3 3.0 7 2.5 2.9 8 2.6 2.3 9 3.8 3.4 10 4.3 3.3 11 4.5 3.3 12 3.8 3.3 13 4.3 2.9 14 3.8 3.3 15 3.8 3.1 16 3.8 3.5 17 5.8 7.0 18 5.5 8.0 19 6.0 7.2 20 5.8 8.0 21 5.8 6.7 22 -

6.0 7.1 23 5.5 8.0 24 5.8 7.8 25 5.2 5.6 26 5.5 7.4 27 5.8 6.0 28 5.3 6.0 29 5.5 5.8 30 5.5 6.3 31 5.8 6.6 32 5.5 6.2 33 5.3 6.3 34 5.0 6.3 35 5.7 6.3 36 5.7 7.2 37 5.3 6.3 38 5.3 6.6 39 6.0 6.2 40 5.3 6.5

. . . . .. l d

OAK RIDGE NATIONAL LABORATORY omanarso av UNION CARSIDE CORPORATION NUCLEAR DIVl110N Polf 0FFICE SOE X O

OAK RIDGE. TENNE 55EE 37830 October 28, 1983 Mr. Yuly Korobov Supervisor, Testing Department Carboline 350 Hanley Industrial Court St. Louis, Missouri 63144 i*

Dear Yuly:

i Enclosed are the results of radiation tolerance and DBA testing on your panels for Carboline's testing project numbers 02182 an&OH04.

If there any questions, or we can be of further service, please call on us.

Sincerely.

l W. R. Laing, Sectibn Head Analytical Chemistry Division Enclosure i

l i

l i

l L

ES[

, 3BA-CURRENiQUALIFYIN

~

Manufacturer: Carboline Analytical Ch ~ir ry Division St* Louis, M0 Oak Nge ?.a tnal Ucoratoy '

Date: Aug. 16, 1978 *

  1. 01269  !

Report of Irradiation, Decontamination, and DBA Testing l The irradiation, decontamination, and design basis accident (DBA) tests are conducted, respectively, in accordance with Bechtel Corp. Standa d_

Specification Coatings for iluclear Power Plants, spec. flos. CP-951. CP-952, i I

and CP-956 (or with modifications as noted in Table 2, DBA test conditions).

The tests are designed also to meet the specifications set in both A.fl.S.I. 3 report.N 101.2-1972, Protective Coatings (Paints) for Light Water fluclear Reactor Containment Facilities, and il 5.12-1974 Protective Coatings (Daints) for the fluclear Industry. The DBA test spray solution and the test conditions .

are listed in Tables 1 and 2. After both the DBA and the irradiation tests, the coatings are examired for signs of chalking, bitstering, cracking, peeling, t

delamination, and flaking, according to ASTM standards where applicable. All except the decontamination test panels are returned to the coating manufac- l turer. ,

The irradiation tests are run using a spent fuel assembly, removed from i the High Flux Isotope Reactor (HFIR) at ORitt, as tre source of radiation. i These fuel _ assemblies are stored under 20 feet of mineralized water. Tne fuel is 934 enriched U23$ as U30, combined with aluminum. The spent fuel i i

assemblies are removed af ter each 23-megawatt day ::eriod. Irradiation is i done using the garra energy from the accumulated mixed fission products.

This more readily simulates conditions around a reactor than does a cobalt I source. Also, the higher gamma activity affords shorter irradiation tir e -

to achieve accumulated doses. The' dose rate fcur days af ter removal of a  ;

fuel assembly from the reactor is 1 x 10' rads / hour. .

The fuel assembly is 20 inches high. A 20-foot long, 3-1/2 inch diameter pipe, with one end capped, is used for the air irradiation tests.

The capped end is lowered into the four-Inen opening of the center of the fuel assembly. The open end, above the water level, is covered with an "0" ring sealed flange to which is attached a steel cable and an air outlet t hose. TheaIrinletislocatedatthebottomofthepipe. The test spect-mens are connected to the botton of the cable and Icwered into the [

Evtluated k Q-Approved /. ' _/

, s t '7 j,--- . '

f 2s~Ji n o25/-  !

i

r ______ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

. g-Manufacturer: Carboline Analytical Chemistry Division St. Louis, M0 Oak Ridge National Laboratory Date: Aug. 16. 1978 radiation field. Also at the center of the fuel assembly is a stainless steel clad cadmium tube used as a neutron absorber. This prevents contami-nation of the test specimens by induced radiation.

The decontamination procedure is as follows: a mixture of fission product nuclides (aged greater than 90 days and less than three years) is neutralized to pH 4 and insnediately applied to the test specimens. The specimens are previously degreased in alcohol. After the contaminated spot is air dried, the activities of four of the nuclides are measured by counting with a Ge(Li) detector and a nultichannel pulse height analyzer. The speci-mens are then suspended in a beaker of water at 25'C and washed by stirring for 10 minutes. The specimens are removed, the backs rinsed in water, air dried, and counted as above. The ratios of the activities before. to those af ter the decontamination are reported as decontamiration factors for water.

The decontamination and counting steps in 25'C and 80'C acids are repeated, and the respective decontamination factors calculated. The " total overall D.F." is calculated as the ratio of the total activity at the beginning of the test to the total activity at the completion of the three washing steps.

All activities are corrected for decay between counts. A computer has been programmed to do all the calculations.

Evaluated _

dtQ Q 'A / j Q Approved .N 'r, f .

s,.

Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory St. Louis. M0 Date: Aug. 16, 1978 Decontamination Test Results:

These tests perforined according to ORNL Master Analytical Manual Method No. 2 0920 and Bechtel Corp. Spec. CP-952. .

ORNL Log Book No. A 7562; A7-17-8-I Pe nt of Decontamination Factor (DF)

Sample Water Acid Acid Activity Number Contaminant 925'C 925'C 980'C Overall Removedi S3-200 Ce-144 50 2.1 6.9 710 (193LF/191HB) Ru-106 16 1.7 1.5 40 Cs-137 -

>2300 >1.5 >1.2 >4100 Zr-95 17 1.8 1.1 34 TOTAL 40 1.9 2.4 180 99.4 S5-203 Ce-144 82 3.8 4.2 1300 (CZ11/288HB) Ru-106 31 1.9 1.8 110 Cs-137 4200 >1.0 >1.5 >6400 Zr-95 14 7.7 7.4 51 TOTAL 57 2.7 2.0 300 99.7 57-204 Ce-144 660 1.9 1.0 1300 (CZ11/305HB) Ru-106 18 3.3 3.6 210 Cs-137 >3000 >1.6 >1.0 >4800 1.4 Zr-95 7.1 ~2.3 23 TOTAL 61 2.7 1.7 280 99.6 Ce-144 Ru-106 Cs-137 Zr-95 TOTAL Ce-144 Ru-106 Cs-137 Zr-95 TOTAL IPercent of total activity removed = (1 - h) x 100.

Approved I,[

G QMDms.

=

. E.

~

l; . .

Manufacturer: Carboline Analytical Chemistry Division Oak Ridge National Laboratory St. Louis, Missouri Date: Auaust 26. 1980 ORNL Log Book No. A 7562; A7-17-8 Table 1. DBA solution composition, distilled water' Reagent Concentration Boric acid, H B03 3 0.28 M Sodiun thiosulfate, Na2 50 2 3 5H 2O 0.064 M Sodium hydroxide, NaOH Required to adjust pH to 9.5 -

Table 2. DBA test conditions" Temperature Pressure Time ('F) (psig) Coments Start 130 -

10 s 307 60 Steam injection.

2 h 47 min- 307 60 ,

5 min 307-280 60-30 Injected cold spray.

20 min 280-250 30 Adjusted pressure.

4 days 250 30 3 min 250-230 10 Drained; injected cold spray.

-15 min 23F200 10 Adjusted pressure.

3 days 200 10 End of test "These data are taken from recorder charts on permanent file at ORNL.

Evaluated __/s/ G. Goldberg Approved __/,(('h,f,b.-

PAGE 7

.  : s .-

Manufacturer: Carboline- Analytical Chemistry Division St. Louis, M0 Oak Ridge National Laboratory Date: Aug. 16. 1978 System Identification: x Steel Concrete Block CZil/305 Finish DBA Test Results:

ORNL Master Analytical Manual Method No. 2 0922; ORNL' Log Book No'. A 7562; A7-17-8 Sample No. DBA Phase Comments **

S6-105- spray (SA) Few blisters, #6, sides A, B.56-108 spray (SA) Side A: few blisters #6, Side B: coatings intact, no defects.

56-110- scrav (SA) Coatinas intact. no defects. sides A. B.56-112 sora v (SA) Coatinas intact, no defects. sides A. B.56-115 scrav (GR) Coatinas intact, no defects, sides A. B.56-116 spray (GR) Coatinas intact no defects. sides A. B.56-119 spray fjHj Coatinas intact. no defects. Sides A. B.56-120 sorav (SH) Coatinas intact. no defects. sides A. B.

  • lrradiated. **(SA) = sand blast; (SH) = shot blast; (GR) = grit blast.

Evaluated e.it Approved .

s -. -

i p .$.

..~ -

Manufacturer: Carboline Analytical Chemistry Division St. Louis,'M0 Oak Ridge National Laboratory Date: Aug. 16, 1978 e

System Identification: x Steel Concrete Block CZll/305 Finish' DBA Test Results:

ORNL Master Analytical Manual Method No. 2 0922; ORNL Log Book No. A 7562; A7-17-8

)" . Sample No.' DBA Phase Comments **

  • S6-101 spray- (SA) Toccoat blistered, cracked, sides A B.
  • S6-102 spray (SA) Topcoat blistered, cracked, sides A, B.

' Irradiated. **(SA) = sand blast; (SH) = shot blast; (GR) = grit blast.

Evaluated m

bv4m Approved _

\

Analytical Chemistry Division

~

Manufacturer: Carboline Oak Ridge National Laboratory St. Louis, M0 Aug. 16, 1978 Date:

System Identification: x Steel Concrete Block CZil/305HB T DBA Test Results:

ORNL Master Analytical Manual Method No. 2 0922; ORNL Log Book No. A 7562; A7-17-8 Sample No. DBA Phase Comments **

  • S7-122 sorav _(SA) Few to medium blisters. #8. sides A. B.
  • S7-123 spray (SA) Few to medium blisters, #8, sides A, B.

S7-127 sorav (SA) Side A: coatinas intact no defects. Side B:

medium blistering, 84, cracked.57-128 soray (SA) Side A: coatings intact, no defects. Side B:

medium blisterina. *4. cracked.

S7-129 spray (SA) Topcoat blistered, cracked, delaminated, sides A, B.

S7-132 spray JSA) Topcoat blistered, cracked, delaminated, sides A, B.

S7-134 spray (GR) Coatinos intact, no defects, sides A, B.

S7-135 spray (GR) Coatinas intact, no defects, sides A, B.57-137 sorav (SH) Coatinas intact no defects, sides A. B.57-140 soray (SH) Coatinas intact no defects sides A. B.

  • Irradiated. **(SA) = sand blast; (SH) = shot blast; (GR) = grit blast.

Evaluated - Approved 4 /_

m .

s' Actual (Theoretical)

Carboline Master PWR II. ,

DFTs Steel' System Blast Panel Number. Side CZ11 305 Finish

~

S6 Sand 101 A 2.4(2.25-2.75) 3.6(3.5-4.5)

B 2.2 3.6 102 A 2.4 3.8 B 2.3. 3.6 103 A 2.5 4.2' B 2.5 3.7 104 A 2.5 3.2 B 2.3 3.6 105 A 1.9(1.0-2.0) 3.8(3.5-4.5)

B 1.8 3.4 106 A 1.8 3.6 B 1.8 3.1 107 A 1.9 3.4 B 1.7 3.2 -

108 A 1.9 3.5 B 1.7 3.5 109 A 3.2(2.5-3.5) 1.3(1.5-2.5)

B 2.8 1.6 110 A 2.9 1.6 B 2.9 1.5 111 A 2.4 1.5 B 2.8 1.4 112 A 2.6 1.8 B 2.5 1.5 Grit 113 A. 2.4(1.5-2.5) 1.7(2.5-3.5)

B 1.8 1.7 114 A 2.3 2.1 B 2.0 2.3 115 A 2.0 2.5 ,

B 1.8 2.3 116 A 2.2 2.6 B 2.1 2.3 Shot 117 A 2.3(1.5-2.5) 2.l(2.5-3.5)

B 2.1 2.0 118 A 2.3 2.2 B 2.1 2.0 119 A 2.4 2.3 B 2.2 2.2 120 A 2.1 2.5 B 2.3 2.6

?. . .

Actual (Theoretical)

Carbolite Master PWR II. DFTs Steel

~Systes Blast Panel Number Side CZ11 305 HB ,

305 HB g S7 Sand 121 A 1.7(2.25-2.75) 4.1(3.5-4.5) 4.2(3.5-4.5)

B 1.8 4.4 122 A 1.9 4.1 B 2.1 4.4 123 A 1.8 4.1 B 1.9 4.3 124 A 1.7 4.8 B 2.2 3.8 4.3(3.5-4.5) 125 A 2.0(1.0-2.0) 3.4(1.5-2.5)

B 1.6 4.0(3.5-4.5) 3.9 126 A 1.8 3.0(1.5-2.5)

B 1.9 3.7(3.5-4.5) 3.3 127 A 2.0 2.6(1.5-2.5)

B 1.8 3.5(3.5-4.5) 4.7 128 A 2.2 2.6(1.5-2.5)

B 1.8 3.5(3.5-4.5) 4.2 129 A 6.5(5.5-6.5) 2.2(1.5-2.5)

B 5.9 2.9(3.5-4.5) 3.5 130 A 6.3 2.3(1.5-2.5)

B 6.1 2.7(3.5-4.5) 3.8 131 A 5.6 2.6(1.5-2.5)

B 5.8 3.l(3.5-4.5) 2.8 132 A 6.5 1.6(1.5-2.5)

B 6.0 2.7(3.5-4.5) 3.8 204 A 1.9(2.25-2.75) 4.9(3.5-4.5)

B 2.3 5.3 205 A 2.0 4.4 B 2.1 4.4 Grit 133 A 2.6(2.25-2.75) 4.3(3.5-4.5)

B 2.6 4.3 134 A 2.5 4.6 B 2.6 4.3 135 A 2.4 4.6 B 2.5 4.8 136 A 2.4 4.5 B 2.4 5.1 Shot 137 A 2.3(2.25-2.75) 4.8(3.5-4.5)

B 2.6 4.8 138 A 2.5 5.0 B 2.8 5.1 139 A 2.3 4.6 B 2.3 5.0 140 A 2.2 5.2 B 2.3 4.9

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